Sample records for refining byproducts aromatic

  1. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul chugh; James Hower

    2008-08-31T23:59:59.000Z

    This paper discusses the roles and responsibilities of each position within the Combustion Byproducts Recyclcing Consortium.

  2. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    -fired power plants derive energy by burning coal in their furnaces. These power plants generally use either. The by-product materials include coal combustion by-products, wood ash, pulp and paper industry by recycling and research needs are discussed. #12;3 2.0 MATERIALS 2.1 COAL-COMBUSTION BY-PRODUCTS Coal

  3. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31T23:59:59.000Z

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  4. Refiners get petchems help

    SciTech Connect (OSTI)

    Wood, A.; Cornitius, T.

    1997-06-11T23:59:59.000Z

    The U.S.Refining Industry is facing hard times. Slow growth, tough environmental regulations, and fierce competition - especially in retail gasoline - have squeezed margins and prompted a series of mergers and acquisitions. The trend has affected the smallest and largest players, and a series of transactions over the past two years has created a new industry lineup. Among the larger companies, Mobil and Amoco are the latest to consider a refining merger. That follows recent plans by Ashland and Marathon to merge their refining businesses, and the decision by Shell, Texaco, and Saudi Aramco to combine some U.S. operations. Many of the leading independent refiners have increased their scale by acquiring refinery capacity. With refining still in the doldrums, more independents are taking a closer look at boosting production of petrochemicals, which offer high growth and, usually, better margins. That is being helped by the shift to refinery processes that favor the increased production of light olefins for alkylation and the removal of aromatics, providing opportunity to extract these materials for the petrochemical market. 5 figs., 3 tabs.

  5. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    combustion by-products #12;3 generated by using both conventional and clean-coal technologies. A clean-coal that obtained from clean-coal technology, are not utilized in cast-concrete masonry products (bricks, blocksCenter for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik

  6. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    of coal fly ash, coal bottom ash, and used foundry sand in concrete, bricks, blocks, and8 paving stones, Wisconsin. She is involved in management,11 disposal, and sale of coal-combustion by-products. She alsoCenter for By-Products Utilization UNDER-UTILIZED COAL-COMBUSTION PRODUCTS IN PERMEABLE ROADWAY

  7. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    -first Century, Hyderabad, India, February 1999. Department of Civil EngineeringandMechanics College) of foundry by-products, including foundry sand and slag. Most of these by-products are landfilled, primarily due to non-availability of economically attractive use options. Landfilling is not a desirable option

  8. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    combustion by-products (such as clean-coal ash) from power plants. Maximum recycling of such by- products regulations and increasing use of low-grade coal, the number of coal-fired power plants with flue gasCenter for By-Products Utilization USE OF CLEAN-COAL ASH FOR MANAGING ASR By Zichao Wu and Tarun R

  9. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization CLEAN COAL BY-PRODUCTS UTILIZATION IN ROADWAY, EMBANKMENTS-fueled plants, particularly use of eastern coals, has lead to the use of clean coal and using advanced sulfur dioxide control technologies. Figure 1 shows clean coal technology benefits(2) . In 1977, the concept

  10. Rietveld Refinement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Obtain from refinement of calibrant (eg. LaB 6 ) Gives the initial values for the profile function (instrumental only parameters) Add screenshot for previous slide on...

  11. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization DRAFT REPORT CARBON DIOXIDE SEQUESTRATION IN CEMENTITIOUS-MILWAUKEE #12;CARBON DIOXIDE SEQUESTRATION IN CEMENTITIOUS PRODUCTS Progress Report by Tarun R. Naik, Rakesh of Carbon Dioxide Sequestration Technologies

  12. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31T23:59:59.000Z

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  13. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

    2008-08-31T23:59:59.000Z

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  14. Sudbury: Nickel Smelting and Refining Nickel Production

    E-Print Network [OSTI]

    Toohey, Darin W.

    Sudbury: Nickel Smelting and Refining Nickel Production o Toyota buys most of its nickel from Sudbury to produce its nickel- metal hydride batteries Used in cars such as the Toyota Prius SO2 Emissions o The smelting of nickel = large amount of SO2 released as byproduct 4 metric tons of SO2 per

  15. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    ash in concrete (structural grade concrete, compressive strength up to 4000 psi) and flowable slurry and performance specifications for structural concrete and flowable slurry products for every day construction use developed by UWM- CBU in the past for other by-products and sources of coal ash not meeting

  16. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    limestone quarry in Wisconsin generates over 125,000 tons of quarry fines and quarry bag-house dust each limestone quarry fines and quarry bag-house dust, to reduce costs, as well as to reduce the use of expensive be used in SCC. Use of quarry by-products in SCC will lead to economical and ecological benefits

  17. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    of Wisconsin-Milwaukee Submitted to the Electric Power Research Institute August 2009 UWM Center for By-Products-Strength Materials) for help in reducing global warming. Concrete mixtures having slump in the range of three to fourCenter for By-Products Utilization CARBON DIOXIDE SEQUESTRATION IN CEMENTITIOUS PRODUCTS By Tarun R

  18. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    clean coal technology, are not extensively utilized in the cast concrete masonry products (bricks both conventional and clean coal technologies. A clean coal ash is defined as the ash derived from SO2Center for By-Products Utilization USE OF CLASS F FLY ASH AND CLEAN-COAL ASH BLENDS FOR CAST

  19. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Issued to the Illinois Clean Coal Institute For Project 02-1/3.1D-2 Department of Civil Engineering of technology and market development for controlled low-strength material (CLSM) slurry using Illinois coal ashCenter for By-Products Utilization IMPLEMENTATION OF FLOWABLE SLURRY TECHNOLOGY IN ILLINOIS

  20. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization CARBON DIOXIDE SEQUESTRATION IN NO-FINES CONCRETE By Tarun R;CARBON DIOXIDE SEQUESTRATION IN NO-FINES CONCRETE ABSTRACT By Tarun, R. Naik, Yoon-moon Chun, Rudolph N. Kraus, and Fethullah Canpolat This paper presents a detailed experimental study on the sequestration

  1. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , compressive strength, concrete testing, fly ash, high-performance concrete, hot weather, permeability, silica Testing of Concrete", Committee 214, "Evaluation of Results of Strength Tests of Concrete", and CommitteeCenter for By-Products Utilization STRENGTH AND DURABILITY OF HIGH- PERFORMANCE CONCRETE SUBJECTED

  2. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Fellow at the UWM-CBU. His research interests include the use of coal fly ash, coal bottom ash, and used in management, disposal, and sale of coal-combustion by-Center for By-Products Utilization USE OF UNDER-UTILIZED COAL- COMBUSTION PRODUCTS IN PERMEABLE

  3. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    ash to solve the concerns associated with its disposal. Wood ash consists of two different types ash and coal fly ash for use in concrete, was used to determine general suitability of wood ashCenter for By-Products Utilization WOOD ASH: A NEW SOURCE OF POZZOLANIC MATERIAL By Tarun R. Naik

  4. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    the concerns associated with its disposal. Wood ash consists of two different types of materials: fly ash for use as construction materials. Therefore, ASTM C 618, developed for volcanic ash and coal fly ashCenter for By-Products Utilization WOOD ASH: A NEW SOURCE OF POZZOLANIC MATERIAL By Tarun R. Naik

  5. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    beneficial uses of wood ash to meet the challenges associated with its disposal. Wood ash consists of two C 618 [13] developed for volcanic ash and coal fly ash for use in concrete, was used to determineCenter for By-Products Utilization RECYCLING OF WOOD ASH IN CEMENT-BASED CONSTRUCTION MATERIALS

  6. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    -air entrained concrete without fly ash. Detailed results are presented. Keywords: carbon dioxide sequestrationCenter for By-Products Utilization CO2 SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE By Tarun R. Naik SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE ABSTRACT by Tarun, R. Naik, Yoon-moon Chun, Rudolph N. Kraus

  7. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization CO2 SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE By Tarun R. Naik and Applied Science THE UNIVERSITY OF WISCONSIN­MILWAUKEE #12;1 CO2 SEQUESTRATION IN NON-AIR ENTRAINED-moon Chun The objectives of this project were to sequester carbon dioxide (CO2) in concrete and study

  8. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization CO2 SEQUESTRATION IN NO-FINES CONCRETE By Tarun R. Naik, Timir C Science THE UNIVERSITY OF WISCONSIN­MILWAUKEE #12;1 CO2 SEQUESTRATION IN NO-FINES CONCRETE ABSTRACT of this project were to sequester carbon dioxide (CO2) in concrete and study the effects of carbonation

  9. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    wood with supplementary fuels such as coal, oil, natural gas, and coke by pulp and paper mills and wood, knots, chips, etc. with other supplementary fuels such as coal, oil, natural gas, and coke to generateCenter for By-Products Utilization DEVELOPMENT OF CLSM USING COAL ASH AND WOOD ASH, A SOURCE OF NEW

  10. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    in a combination with a number of fuels including coal, petroleum coke, natural gas, etc. In the mid 1990s, the unit was firing a combination of coal and petroleum coke to generate energy. It has been established;1 PROJECT 1 - COAL COMBUSTION BY-PRODUCTS: CHARACTERIZATION AND USE OPTIONS Introduction An AFBC system

  11. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization PROPERTIES OF CONCRETE CONTAINING SCRAP TIRE RUBBER in a variety of rubber and plastic products, thermal incineration of waste tires for production of electricity rubber in asphalt mixes, (ii) thermal incineration of worn-out tires for the production of electricity

  12. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization APPLICATION OF SCRAP TIRE RUBBER IN ASPHALTIC MATERIALS: STATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2. PRODUCING CRUMB RUBBER MODIFIER (CRM) FROM USED TIRES . . . . . 3 2.1 PRODUCTION OF CRM THE UNIVERSITY OF WISCONSIN - MILWAUKEE #12;APPLICATION OF SCRAP TIRE RUBBER IN ASPHALTIC MATERIALS: STATE

  13. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Presentationand Publicationat the CBIP International Conference onFly Ash Disposal & Utilization,New Delhi, India, January 1998 foundry sand and slag. Most of these by-products are landfilled, primarily due to non-availability of economically attractive use options. Landfilling is not a desirable option because it not only causes huge

  14. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    tires generated during the year 1990 - 1991 were reused, recycled, or recovered [4]. A number of usesCenter for By-Products Utilization CONSTRUCTION MATERIALS INCORPORATING DISCARDED TIRES By Tarun R - MILWAUKEE #12;CONSTRUCTION MATERIALS INCORPORATING DISCARDED TIRES* By Tarun R. Naik Director, Center for By

  15. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization USE OF CLASS F FLY ASH AND CLEAN-COAL ASH BLENDS FOR CAST OF CLASS F FLYASHAND CLEAN-COAL ASHBLENDS FOR CAST CONCRETE PRODUCTS Authors: TarunR.Naik, Director, Center,Illinois Clean Coal Institute RudolphN.Kraus, Research Associate, UWM Center forBy-Products Utilization Shiw S

  16. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization CHARACTERIZATION AND APPLICATION OF CLASSF FLY ASHCOAL AND CLEAN-COAL #12;-1- CHARACTERIZATION AND APPLICATION OF CLASSF FLYASHCOAL AND CLEAN-COAL ASHFOR CEMENT -Milwaukee (UWM) Daniel D.Banerjee, Project Manager,Illinois Clean Coal Institute RudolphN.Kraus, Research

  17. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique of HVFA Concrete Containing Clean-Coal Ash and Class F Fly Ash By Tarun R. Naik Director, UWM Center for By-Products Utilization and Francois Botha Project Manager, Illinois Clean Coal Institute Synopsis

  18. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    flue gas. Detailed results are presented. Keywords: carbon dioxide sequestration, carbonation, carbonCenter for By-Products Utilization CO2 SEQUESTRATION IN FOAMED CONTROLLED LOW STRENGTH MATERIALS #12;1 CO2 SEQUESTRATION IN FOAMED CONTROLLED LOW STRENGTH MATERIALS by Tarun R. Naik, Rudolph N. Kraus

  19. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    combustion by-products are generated due to the combustion of coal in coal-fired electric power plants as carbon from unburnt coal, fire polished sand, thin-walled hollow spheres and their fragments, magnetic of HVFA concrete to establish mixture proportions for commercial production. #12;INTRODUCTION Coal

  20. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    was produced by Wisconsin Electric's coal-fired power plants. The criteria for selecting these mixtures was to utilize minimal cost materials, such as coal combustion by-products (fly ash, bottom ash, etc coal combustion waste material (fly ash) to the maximum extent possible while minimizing costs (e

  1. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization USE OF COAL-COMBUSTION PRODUCTS IN PERMEABLE PAVEMNET BASE and Published at the Raymundo Rivera International Symposium on Durability of Concrete, Monterrey, N. L., Mexico THE UNIVERSITY OF WISCONSIN­MILWAUKEE #12;Use of Coal-Combustion Products in Permeable Pavement Base1 2 3 4 5 6 7

  2. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    plants are the major source of generation of electricity. Coal-fired power plants derive energy by burning coal in their furnaces. These power plants generally use either pulverized coal-fired furnaces. 2.0 MATERIALS 2.1 COAL-COMBUSTION BY-PRODUCTS In most of the countries coal- fired thermal power

  3. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R #12;1 HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R. Naik, Shiw S. Singh, and Bruce for manufacture of cement-based products using ashes generated from combustion of high-sulfur coals. A clean coal

  4. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization USE OF CLEAN COAL ASH AS SETTING TIME REGULATOR IN PORTLAND OF WISCONSIN ­ MILWAUKEE #12;2 Use of Clean Coal Ash as Setting Time Regulator in Portland Cement by Zichao Wu as setting time regulator for portland cement production. In this paper a source of clean coal ash (CCA

  5. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    of coal in conventional and/ or advanced clean coal technology combustors. These include fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) by-products from advanced clean coal technology clean coal technology combustors. Over 60% of the CCBs are generated as fly ash. An estimate

  6. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    and paper mills in concrete. INTRODUCTION Concrete is a porous solid that is created by combining four basicCenter for By-Products Utilization CURING TEMPERATURE EFFECTS ON HIGH-PERFORMANCE CONCRETE By Tarun For presentation and publication at the symposium entitled "High-Performance Concrete and Concrete for Marine

  7. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    . Naik, Rudolph N. Kraus, Shiw S. Singh, Lori- Lynn C. Pennock, and Bruce Ramme Report No. CBU-2001 with numerous projects on the use of by-product materials including utilization of used foundry sand and fly ash;2 INTRODUCTION Wood FA is generated due to combustion of wood for energy production at pulp and paper mills, saw

  8. By By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By By-Products Utilization THE ROLE OF FLOWABLE SLURRY IN SUSTAINABLE DEVELOPMENTS of Flowable Slurry in Sustainable Developments in Civil Engineering Tarun R. Naik and Rudolph N. Kraus Materials (CLSM) incorporating industrial by-products (coal fly ash, and used foundry sand). CLSM reference

  9. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31T23:59:59.000Z

    The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F-fly ash. Some developed technologies have similar potential in the longer term. (3) Laboratory studies have been completed that indicate that much higher amounts of fly ash could be added in cement-concrete applications under some circumstances. This could significantly increase use of fly ash in cement-concrete applications. (4) A study of the long-term environmental effects of structural fills in a surface mine in Indiana was completed. This study has provided much sought after data for permitting large-volume management options in both beneficial as well as non-beneficial use settings. (5) The impact of CBRC on CCBs utilization trends is difficult to quantify. However it is fair to say that the CBRC program had a significant positive impact on increased utilization of CCBs in every region of the USA. Today, the overall utilization of CCBs is over 43%. (6) CBRC-developed knowledge base led to a large number of other projects completed with support from other sources of funding. (7) CBRC research has also had a large impact on CCBs management across the globe. Information transfer activities and visitors from leading coal producing countries such as South Africa, Australia, England, India, China, Poland, Czech Republic and Japan are truly noteworthy. (8) Overall, the CBRC has been a truly successful, cooperative research program. It has brought together researchers, industry, government, and regulators to deal with a major problem facing the USA and other coal producing countries in the world.

  10. ITP Petroleum Refining: Profile of the Petroleum Refining Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Profile of the Petroleum Refining Industry in California: California Industries of the Future Program ITP Petroleum Refining: Profile of the Petroleum Refining Industry in...

  11. ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bandwidth for Petroleum Refining Processes ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes bandwidth.pdf More Documents & Publications ITP Petroleum...

  12. Refinement Modal Logic

    E-Print Network [OSTI]

    Bozzelli, Laura; French, Tim; Hales, James; Pinchinat, Sophie

    2012-01-01T23:59:59.000Z

    In this paper we present refinement modal logic. A refinement is like a bisimulation, except that from the three relational requirements only 'atoms' and 'back' need to be satisfied. Our logic contains a new operator 'forall' in additional to the standard modalities 'Box' for each agent. The operator 'forall' acts as a quantifier over the set of all refinements of a given model. We call it the refinement operator. As a variation on a bisimulation quantifier, it can be seen as a refinement quantifier over a variable not occurring in the formula bound by the operator. The logic combines the simplicity of multi-agent modal logic with some powers of monadic second order quantification. We present a sound and complete axiomatization of multiagent refinement modal logic. We also present an extension of the logic to the modal mu-calculus, and an axiomatization for the single-agent version of this logic. Examples and applications are also discussed: to software verification and design (the set of agents can also be s...

  13. Coal Combustion By-Products (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment is responsible for regulating fugitive air emissions from the transportation of coal combustion by-products and the permissible beneficial uses of these by...

  14. aromatic hydrocarbon components: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AROMATIC HYDROCARBONS 2005 April 19 ABSTRACT Interstellar polycyclic aromatic hydrocarbon (PAH) infrared emission features 26 Dehydrogenation of polycyclic aromatic...

  15. The Composition of Rice By-products.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1904-01-01T23:59:59.000Z

    to the rice. e products of this machine are rice bran, some flour, and clean rice. The final process consists in polishing the rice, which gives it a ter. The by-product from this process is rice. polish. The polished rice is sorted into different grades...*7 TEXAS AGRICULTURAL EXPERIMENT STATIONS BULLETIN NO. 73. The Composition of Rice By-Products. POSTOFFICE: COLLEGE STATION, BRAZOS COUNTY, TEXAS. 1904 THE BRYAN EAGLE BRYAN, TEXAS TEXAS AGRICULTURi - - OFFIGERS -- GOVERNING BOARD...

  16. Issues in adaptive mesh refinement

    SciTech Connect (OSTI)

    Dai, William Wenlong [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    In this paper, we present an approach for a patch-based adaptive mesh refinement (AMR) for multi-physics simulations. The approach consists of clustering, symmetry preserving, mesh continuity, flux correction, communications, and management of patches. Among the special features of this patch-based AMR are symmetry preserving, efficiency of refinement, special implementation offlux correction, and patch management in parallel computing environments. Here, higher efficiency of refinement means less unnecessarily refined cells for a given set of cells to be refined. To demonstrate the capability of the AMR framework, hydrodynamics simulations with many levels of refinement are shown in both two- and three-dimensions.

  17. Towards automated crystallographic structure refinement with phenix.refine

    SciTech Connect (OSTI)

    Afonine, Pavel V., E-mail: pafonine@lbl.gov; Grosse-Kunstleve, Ralf W.; Echols, Nathaniel; Headd, Jeffrey J.; Moriarty, Nigel W. [Lawrence Berkeley National Laboratory, One Cyclotron Road, MS64R0121, Berkeley, CA 94720 (United States); Mustyakimov, Marat; Terwilliger, Thomas C. [Los Alamos National Laboratory, M888, Los Alamos, NM 87545 (United States); Urzhumtsev, Alexandre [CNRS–INSERM–UdS, 1 Rue Laurent Fries, BP 10142, 67404 Illkirch (France); Université Henri Poincaré, Nancy 1, BP 239, 54506 Vandoeuvre-lès-Nancy (France); Zwart, Peter H. [Lawrence Berkeley National Laboratory, One Cyclotron Road, MS64R0121, Berkeley, CA 94720 (United States); Adams, Paul D. [Lawrence Berkeley National Laboratory, One Cyclotron Road, MS64R0121, Berkeley, CA 94720 (United States); University of California Berkeley, Berkeley, CA 94720 (United States)

    2012-04-01T23:59:59.000Z

    phenix.refine is a program within the PHENIX package that supports crystallographic structure refinement against experimental data with a wide range of upper resolution limits using a large repertoire of model parameterizations. This paper presents an overview of the major phenix.refine features, with extensive literature references for readers interested in more detailed discussions of the methods. phenix.refine is a program within the PHENIX package that supports crystallographic structure refinement against experimental data with a wide range of upper resolution limits using a large repertoire of model parameterizations. It has several automation features and is also highly flexible. Several hundred parameters enable extensive customizations for complex use cases. Multiple user-defined refinement strategies can be applied to specific parts of the model in a single refinement run. An intuitive graphical user interface is available to guide novice users and to assist advanced users in managing refinement projects. X-ray or neutron diffraction data can be used separately or jointly in refinement. phenix.refine is tightly integrated into the PHENIX suite, where it serves as a critical component in automated model building, final structure refinement, structure validation and deposition to the wwPDB. This paper presents an overview of the major phenix.refine features, with extensive literature references for readers interested in more detailed discussions of the methods.

  18. A Theory of Program Refinement 

    E-Print Network [OSTI]

    Denney, Ewen WKC

    We give a canonical program refinement calculus based on the lambda calculus and classical first-order predicate logic, and study its proof theory and semantics. The intention is to construct a metalanguage for refinement in which basic principles...

  19. Minimally refined biomass fuel

    DOE Patents [OSTI]

    Pearson, Richard K. (Pleasanton, CA); Hirschfeld, Tomas B. (Livermore, CA)

    1984-01-01T23:59:59.000Z

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  20. Refines Efficiency Improvement

    SciTech Connect (OSTI)

    WRI

    2002-05-15T23:59:59.000Z

    Refinery processes that convert heavy oils to lighter distillate fuels require heating for distillation, hydrogen addition or carbon rejection (coking). Efficiency is limited by the formation of insoluble carbon-rich coke deposits. Heat exchangers and other refinery units must be shut down for mechanical coke removal, resulting in a significant loss of output and revenue. When a residuum is heated above the temperature at which pyrolysis occurs (340 C, 650 F), there is typically an induction period before coke formation begins (Magaril and Aksenova 1968, Wiehe 1993). To avoid fouling, refiners often stop heating a residuum before coke formation begins, using arbitrary criteria. In many cases, this heating is stopped sooner than need be, resulting in less than maximum product yield. Western Research Institute (WRI) has developed innovative Coking Index concepts (patent pending) which can be used for process control by refiners to heat residua to the threshold, but not beyond the point at which coke formation begins when petroleum residua materials are heated at pyrolysis temperatures (Schabron et al. 2001). The development of this universal predictor solves a long standing problem in petroleum refining. These Coking Indexes have great potential value in improving the efficiency of distillation processes. The Coking Indexes were found to apply to residua in a universal manner, and the theoretical basis for the indexes has been established (Schabron et al. 2001a, 2001b, 2001c). For the first time, a few simple measurements indicates how close undesired coke formation is on the coke formation induction time line. The Coking Indexes can lead to new process controls that can improve refinery distillation efficiency by several percentage points. Petroleum residua consist of an ordered continuum of solvated polar materials usually referred to as asphaltenes dispersed in a lower polarity solvent phase held together by intermediate polarity materials usually referred to as resins. The Coking Indexes focus on the amount of these intermediate polarity species since coke formation begins when these are depleted. Currently the Coking Indexes are determined by either titration or solubility measurements which must be performed in a laboratory. In the current work, various spectral, microscopic, and thermal techniques possibly leading to on-line analysis were explored for measuring the Coking Indexes.

  1. A Novel, Green Technology for the Production of Aromatic Thiol from Aromatic Sulfonyl Chloride

    E-Print Network [OSTI]

    Atkinson, Bradley R.

    2010-01-16T23:59:59.000Z

    The hydrogenation of aromatic sulfonyl chloride to produce aromatic thiol is an important industrial reaction. The aromatic thiol is a critical intermediate in the production of many pharmaceuticals as well as several agrochemicals. Density...

  2. Crystal structure refinement with SHELXL

    SciTech Connect (OSTI)

    Sheldrick, George M., E-mail: gsheldr@shelx.uni-ac.gwdg.de [Department of Structural Chemistry, Georg-August Universität Göttingen, Tammannstraße 4, Göttingen 37077 (Germany)

    2015-01-01T23:59:59.000Z

    New features added to the refinement program SHELXL since 2008 are described and explained. The improvements in the crystal structure refinement program SHELXL have been closely coupled with the development and increasing importance of the CIF (Crystallographic Information Framework) format for validating and archiving crystal structures. An important simplification is that now only one file in CIF format (for convenience, referred to simply as ‘a CIF’) containing embedded reflection data and SHELXL instructions is needed for a complete structure archive; the program SHREDCIF can be used to extract the .hkl and .ins files required for further refinement with SHELXL. Recent developments in SHELXL facilitate refinement against neutron diffraction data, the treatment of H atoms, the determination of absolute structure, the input of partial structure factors and the refinement of twinned and disordered structures. SHELXL is available free to academics for the Windows, Linux and Mac OS X operating systems, and is particularly suitable for multiple-core processors.

  3. Coal ash by-product reutilization

    SciTech Connect (OSTI)

    Muncy, J. [Potomac Electric Power Co., Washington, DC (United States); Miller, B. [DYNA Corp., Upper Marlboro, MD (United States)

    1997-09-01T23:59:59.000Z

    Potomac Electric Power Company (PEPCO) has as part of its vision and value statement that, ``We are responsible stewards of environmental and corporate resources.`` With this moral imperative in mind, a project team was charged with initiating the Coal Pile Liner Project--installing a membrane liner under the existing coal storage pile at the Morgantown Generating Station. The existing coal yard facilities were constructed prior to the current environmental regulations, and it became necessary to upgrade the storage facilities to be environmentally friendly. The project team had two objectives in this project: (1) prevent coal pile leachate from entering the groundwater system; (2) test the viability of using coal ash by-products as an aggregate substitute for concrete applications. Both objectives were met, and two additional benefits were achieved as well: (1) the use of coal ash by-products as a coal liner produced significant cost savings to the project directly; (2) the use of coal ash by-products reduced plant operation and maintenance expenses.

  4. Aromaticity and Antiaromaticity in Transition-Metal Systems....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aromaticity and Antiaromaticity in Transition-Metal Systems. Aromaticity and Antiaromaticity in Transition-Metal Systems. Abstract: Aromaticity is an important concept in chemistry...

  5. Bacterial mutagenicity of polycyclic aromatic hydrocarbons in reconstituted mixtures and crude coal tar extracts and fractions 

    E-Print Network [OSTI]

    Onufrock, Amy Mildred

    1994-01-01T23:59:59.000Z

    7 8 Phenanthrene 8 9 2 6 3 5 4 Fluorene 7 6 Fluoranthene 3 10 I 9 H I, 8 7 I 6 Pyrene Il 2 111 Q 12 5 6 ltenzolclphenanthrene 2 I I 12 4 I H 5 8 7 6 Benz[ajanthracene 12 II 10 8 + ~ 5 7 6 Chrysene I 4 13 14 12 e... are associated with the coal utilization and petroleum refining industries. Polycyclic aromatic hydrocarbons can result as thermal degradative products of combustion, pyrolysis, and pyrosynthesis. They are also derived from a variety of petroleum refining...

  6. Preliminary assessment of future refining impacts of the Clean Air Act Amendments of 1990

    SciTech Connect (OSTI)

    Hadder, G.R.

    1991-09-01T23:59:59.000Z

    A preliminary assessment of the future refining impacts of the Clean Air Act Amendments of 1990 has been performed with the Navy Mobility Fuels Forecasting Systems. The assessment suggests that gasoline reformulation costs in domestic coastal and near-coastal refining regions in the year 2000 could be 3.5 to 5.6 cents per gallon (in terms of 1989 currency). For heating value equivalent to one gallon of conventional gasoline, the regional total added costs (including reformulation costs) for reformulated gasoline could be 5.9 to 8.0 cents. In blending reformulated gasolines, the reduction of butane for lower Reid vapor pressure and the reduction of reformate for lower aromatics are generally compensated by increased percentages of alkylate and/or straight run naphthas. Relatively larger refinery process capacity additions are required for butane isomerization, alkylation, aromatics recovery, and distillate hydrotreating. 21 refs., 3 figs., 18 tabs.

  7. The Use of Re-Refined Oil in Vehicle Fleets Copyright 1996 Society of Automotive Engineers, Inc.

    E-Print Network [OSTI]

    Timothy T. Maxwell; Glen Hagler; Jesse C. Jones; Raghu Narayan; Atila Ertas

    A literature search to identify deleterious effects of using re-refined oil did not disclose any validated occurrences. Significant engine testing using re-refined lubricating oil is reported and no cases were discovered in which engine operation was affected negatively by the use of re-refined oil. The American Petroleum Institute (AFT) allows the use of re-refined base stock oils in the blending of end use lubricants. Based on oil sample testing performed in this research as well as other authoritative sources, it was determined that no significant chemical or physical differences exist between rerefined and virgin oils. Differences noted in this research were related to higher levels of polynuclear aromatics (PNA’s) in the re-refined oil. PNA’s

  8. ITP Petroleum Refining: Energy and Environmental Profile of the...

    Energy Savers [EERE]

    Energy Bandwidth for Petroleum Refining Processes ITP Petroleum Refining: Technology Roadmap for the Petroleum Industry ITP Petroleum Refining: Profile of the Petroleum Refining...

  9. Detection of chlorinated aromatic compounds

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1996-02-06T23:59:59.000Z

    A method for making a composition for measuring the concentration of chlorinated aromatic compounds in aqueous fluids, and an optical probe for use with the method are disclosed. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis. 5 figs.

  10. Feasibility of producing jet fuel from GPGP (Great Plains Gasification Plant) by-products

    SciTech Connect (OSTI)

    Willson, W.G.; Knudson, C.L.; Rindt, J.R.

    1987-01-01T23:59:59.000Z

    The Great Plains Gasification Plant (GPGP) in Beulah, North Dakota, is in close proximity to several Air Force bases along our northern tier. This plant is producing over 137 million cubic feet per day of high-Btu Natural Gas from North Dakota lignite. In addition, the plant generates three liquid streams, naphtha, crude phenol, and tar oil. The naphtha may be directly marketable because of its low boiling point and high aromatic content. The other two streams, totalling about 4300 barrels per day, are available as potential sources of aviation fuel jet fuel for the Air Force. The overall objective of this project is to assess the technical and economic feasibility of producing aviation turbine fuel from the by-product streams of GPGP. These streams, as well as fractions, thereof, will be characterized and subsequently processed over a wide range of process conditions. The resulting turbine fuel products will be analyzed to determine their chemical and physical characteristics as compared to petroleum-based fuels to meet the military specification requirements. A second objective is to assess the conversion of the by-product streams into a new, higher-density aviation fuel. Since no performance specifications currently exist for a high-density jet fuel, reaction products and intermediates will only be characterized to indicate the feasibility of producing such a fuel. This report discusses the suitability of the tar oil stream. 5 refs., 20 figs., 15 tabs.

  11. Calculate the solubility of aromatics

    SciTech Connect (OSTI)

    Yaws, C.L.; Bu, L.; Nijhawan, S. (Lamar Univ., Beaumont, TX (United States))

    1995-02-01T23:59:59.000Z

    Like naphthenes and paraffins, aromatics are an important hydrocarbon component of fossil fuels. Their physical and thermodynamic property data are valuable to engineers in the chemical process industries. In particular, their solubility in water is becoming more important in engineering and environmental studies because of increasingly stringent regulations regarding health, safety and the environment. In this article the authors present water-solubility data and correlations for aromatics (benzenes) as a function of temperature. These results can be useful for engineers conducting various types of initial studies.

  12. Conformal refinement of unstructured quadrilateral meshes

    SciTech Connect (OSTI)

    Garmella, Rao [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    We present a multilevel adaptive refinement technique for unstructured quadrilateral meshes in which the mesh is kept conformal at all times. This means that the refined mesh, like the original, is formed of only quadrilateral elements that intersect strictly along edges or at vertices, i.e., vertices of one quadrilateral element do not lie in an edge of another quadrilateral. Elements are refined using templates based on 1:3 refinement of edges. We demonstrate that by careful design of the refinement and coarsening strategy, we can maintain high quality elements in the refined mesh. We demonstrate the method on a number of examples with dynamically changing refinement regions.

  13. Zone refining of plutonium metal

    SciTech Connect (OSTI)

    Blau, M.S.

    1994-08-01T23:59:59.000Z

    The zone refining process was applied to Pu metal containing known amounts of impurities. Rod specimens of plutonium metal were melted into and contained in tantalum boats, each of which was passed horizontally through a three-turn, high-frequency coil in such a manner as to cause a narrow molten zone to pass through the Pu metal rod 10 times. The impurity elements Co, Cr, Fe, Ni, Np, U were found to move in the same direction as the molten zone as predicted by binary phase diagrams. The elements Al, Am, and Ga moved in the opposite direction of the molten zone as predicted by binary phase diagrams. As the impurity alloy was zone refined, {delta}-phase plutonium metal crystals were produced. The first few zone refining passes were more effective than each later pass because an oxide layer formed on the rod surface. There was no clear evidence of better impurity movement at the slower zone refining speed. Also, constant or variable coil power appeared to have no effect on impurity movement during a single run (10 passes). This experiment was the first step to developing a zone refining process for plutonium metal.

  14. CONSTRUCTION MATERIALS MADE WITH COAL COMBUSTION BY-PRODUCTS

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    ash and bottom ash are produced as by-products of coal-fired electricity generation. In many countriesCONSTRUCTION MATERIALS MADE WITH COAL COMBUSTION BY-PRODUCTS Lihua Wei*, Tarun R. Naik**, and Dean-Milwaukee, is being conducted to develop new low-cost construction materials primarily using coal combustion

  15. ADVANCED GASIFICATION BY-PRODUCT UTILIZATION

    SciTech Connect (OSTI)

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; M. Mercedes Maroto-Valer; Zhe Lu; Harold Schobert

    2005-04-01T23:59:59.000Z

    The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2003 to August 31, 2004. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  16. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-09-07T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

  17. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1994-06-14T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  18. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Houston, TX)

    1989-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  19. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1993-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  20. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1994-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  1. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1989-07-18T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  2. Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

    E-Print Network [OSTI]

    VanVeller, Brett

    The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

  3. ITP Petroleum Refining: Impacts of Condition Assessment on Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ITP Petroleum Refining: Impacts of Condition Assessment on Energy Use: Selected Applications in Chemicals Processing and Petroleum Refining ITP Petroleum Refining: Impacts of...

  4. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig (Sunnyvale, CA); Mulholland, James A. (Chapel Hill, NC); Foster, Edward P. (Macungie, PA)

    1986-01-01T23:59:59.000Z

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  5. animal byproducts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik") UTILIZING CLEAN-COAL ASH 1 This project was for the...

  6. advanced byproduct recovery: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik") UTILIZING CLEAN-COAL ASH 1 This project was for the...

  7. Relaxations for Production Planning Problems with Increasing By-products

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Relaxations for Production Planning Problems with Increasing By-products Srikrishna Sridhar, Jeff, James Leudtke SILO Seminars: Feb 1, 2012 #12;One slide summary Problem Description Production process involves desirable & undesirable products. Srikrishna Sridhar, Jeff Linderoth, James Leudtke SILO Seminars

  8. Oxidation kinetics of by-product calcium sulfite

    E-Print Network [OSTI]

    Othman, Hasliza

    1992-01-01T23:59:59.000Z

    of Department) May 1992 ABSTRACT Oxidation Kinetics of By-product Calcium Sulfite. (May 1992) Hasliza Othman, B. S. , Texas A&M University Chair of Advisory Committee: Dr. Ahmed M. Gadalla The by-products obtained from the flue gas desulfurization (FGD..., suggestions and encouragement. TABLE OF CONTENTS CHAPTER Page I INTRODUCTION I I LITERATURE REVIEW A. Limestone Flue Gas Desulfurization Process . . . . . . . . . . . . B. Scaling Problem in the FGD Process...

  9. Grain Sorghum By-Product Feeds for Farm Animals.

    E-Print Network [OSTI]

    1951-01-01T23:59:59.000Z

    X3.AJ.N SORGHUM BY-PRODUCT FEEDS FOR FARM ANIMALS FEED FOR LIVESTOCK -. Grain sorghum is the leading feed grain produced in Texas and in the Southwest. Its importance as a feed fc farm animals is generally recognized. Recent developments... in Texas have made available 1 livestock producers and the feed industry a considerab tonnage of sorghum gluten meal and sorghum gluten fee as by-products in sorghum grain processing. The Texas Agricultural Experiment Station conduct( a series...

  10. Computer Simulations Reveal Multiple Functions for Aromatic

    E-Print Network [OSTI]

    Computer Simulations Reveal Multiple Functions for Aromatic Residues in Cellulase Enzymes NREL researchers use high-performance computing to demonstrate fundamental roles of aromatic residues in cellulase enzyme tunnels. National Renewable Energy Laboratory (NREL) computer simulations of a key indus- trial

  11. All-Boron Aromatic Clusters as Potential New Inorganic Ligands...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Boron Aromatic Clusters as Potential New Inorganic Ligands and Building Blocks in Chemistry. All-Boron Aromatic Clusters as Potential New Inorganic Ligands and Building Blocks in...

  12. Advanced Gasification By-Product Utilization

    SciTech Connect (OSTI)

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Harold Schobert

    2006-02-01T23:59:59.000Z

    With the recent passing of new legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2004 to August 31, 2005. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  13. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1993-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  14. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-01-05T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  15. Zone refining of plutonium metal

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The purpose of this study was to investigate zone refining techniques for the purification of plutonium metal. The redistribution of 10 impurity elements from zone melting was examined. Four tantalum boats were loaded with plutonium impurity alloy, placed in a vacuum furnace, heated to 700{degrees}C, and held at temperature for one hour. Ten passes were made with each boat. Metallographic and chemical analyses performed on the plutonium rods showed that, after 10 passes, moderate movement of certain elements were achieved. Molten zone speeds of 1 or 2 inches per hour had no effect on impurity element movement. Likewise, the application of constant or variable power had no effect on impurity movement. The study implies that development of a zone refining process to purify plutonium is feasible. Development of a process will be hampered by two factors: (1) the effect on impurity element redistribution of the oxide layer formed on the exposed surface of the material is not understood, and (2) the tantalum container material is not inert in the presence of plutonium. Cold boat studies are planned, with higher temperature and vacuum levels, to determine the effect on these factors. 5 refs., 1 tab., 5 figs.

  16. Reaping Energy Savings from Petroleum Refining

    E-Print Network [OSTI]

    Deng, A.; Cascone, R.

    2006-01-01T23:59:59.000Z

    REAPING ENERGY SAVINGS FROM PETROLEUM REFINING Alan Deng, Project Manager, San Francisco, CA, Ron Cascone, Project Manager, White Plains, NY, Nexant, Inc. ABSTRACT The refining industry is one of the largest energy users in Pacific Gas... years’ energy conservation and demand-side management program participation. The PG&E’s refinery energy efficiency program (REEP) is designed to address key market barriers and tap into the savings potential from energy-intensive refining processes...

  17. Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard reference material 1649a (urban dust) and

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard nitrated polycylic aromatic hydrocarbons (NPAHs) and 9 oxygenated polycylic aromatic hydrocarbons (OPAHs aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic

  18. Advanced Gasification By-Product Utilization

    SciTech Connect (OSTI)

    Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

    2006-08-31T23:59:59.000Z

    With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this collaborative effort between the University of Kentucky Center for Applied Energy Research (CAER), The Pennsylvania State University Energy Institute, and industry collaborators supplying gasifier char samples were to investigate the potential use of gasifier slag carbons as a source of low cost sorbent for Hg and NOX capture from combustion flue gas, concrete applications, polymer fillers and as a source of activated carbons. Primary objectives were to determine the relationship of surface area, pore size, pore size distribution, and mineral content on Hg storage of gasifier carbons and to define the site of Hg capture. The ability of gasifier slag carbon to capture NOX and the effect of NOX on Hg adsorption were goals. Secondary goals were the determination of the potential for use of the slags for cement and filler applications. Since gasifier chars have already gone through a devolatilization process in a reducing atmosphere in the gasifier, they only required to be activated to be used as activated carbons. Therefore, the principal objective of the work at PSU was to characterize and utilize gasification slag carbons for the production of activated carbons and other carbon fillers. Tests for the Hg and NOX adsorption potential of these activated gasifier carbons were performed at the CAER. During the course of this project, gasifier slag samples chemically and physically characterized at UK were supplied to PSU who also characterized the samples for sorption characteristics and independently tested for Hg-capture. At the CAER as-received slags were tested for Hg and NOX adsorption. The most promising of these were activated chemically. The PSU group applied thermal and steam activation to a representative group of the gasifier slag samples separated by particle sizes. The activated samples were tested at UK for Hg-sorption and NOX capture and the most promising Hg adsorbers were tested for Hg capture in a simulated flue gas. Both UK and PSU tested the use of the gasifier slag samples as fillers. The CAER analyzed the slags for possible use in cement applications

  19. Land application uses for dry FGD by-products

    SciTech Connect (OSTI)

    Bigham, J.; Dick, W.; Forster, L.; Hitzhusen, F.; McCoy, E.; Stehouwer, R.; Traina, S.; Wolfe, W. (Ohio State Univ., Columbus, OH (United States)); Haefner, R. (Geological Survey, Columbus, OH (United States). Water Resources Div.)

    1993-04-01T23:59:59.000Z

    The 1990 amendments to the Clean Air Act have spurred the development of flue gas desulfurization (FGD) processes, several of which produce a dry, solid by-product material consisting of excess sorbent, reaction products containing sulfates and sulfites, and coal fly ash. Presently FGD by-product materials are treated as solid wastes and must be landfilled. However, landfill sites are becoming more scarce and tipping fees are constantly increasing. It is, therefore, highly desirable to find beneficial reuses for these materials provided the environmental impacts are minimal and socially acceptable. Phase 1 results of a 4 and 1/2 year study to demonstrate large volume beneficial uses of FGD by-products are reported. The purpose of the Phase 1 portion of the project was to characterize the chemical, physical, mineralogical and engineering properties of the FGD by-product materials obtained from various FGD technologies being developed in the state of Ohio. Phase 1 also involved the collection of baseline economic data related to the beneficial reuse of these FGD materials. A total of 58 samples were collected and analyzed. In summary Phase 1 results revealed that FGD by-product materials are essentially coal fly ash materials diluted with unreacted sorbent and reaction products. High volume beneficial reuses will depend on the economics of their substituting for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mines). Environmental constraints to the beneficial reuse of dry FGD byproduct materials, based on laboratory and leachate studies, seem to be less than for coal fly ash.

  20. Toxicity Analysis of Polycyclic Aromatic Hydrocarbon Mixtures

    E-Print Network [OSTI]

    Naspinski, Christine S.

    2010-01-16T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are widely distributed in the environment and are generated by many sources. Though the potential of PAH-rich mixtures to cause health effects has been known for almost a century, there are still unanswered...

  1. Polynuclear aromatic hydrocarbons for fullerene synthesis in flames

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D.

    2006-12-19T23:59:59.000Z

    This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

  2. Center for By-Products Utilization High Durability Concrete Using

    E-Print Network [OSTI]

    Saldin, Dilano

    TESTING · Fresh Concrete Properties ·Unit Weight (ASTM C 138) ·Air Content (ASTM C 237) ·Slump (ASTM C 143Center for By-Products Utilization High Durability Concrete Using High-Carbon Fly Ash and Pulp Mill-Products Utilization Durable Concrete in Northern Climates · Producing durable concrete in a freezing and thawing

  3. Reducing Disinfection By-Products in Small Drinking Water Systems

    E-Print Network [OSTI]

    not decrease the residual TOC by 0.3 mg/L. #12;Guidelines: Coagulant dosages for water supplies where NOMReducing Disinfection By-Products in Small Drinking Water Systems by M. Robin Collins, James P. Malley, Jr, & Ethan Brooke Water Treatment Technology Assistance Center Department of Civil Engineering

  4. Center for By-Products Utilization CARBONATION: AN EFFICIENT

    E-Print Network [OSTI]

    Saldin, Dilano

    -based materials. #12;Center for By-Products Utilization Carbon Dioxide Sequestration in Cement-based Materials Early age carbonation curing for the sequestration of CO2 in cement-based products is most adopted. Recently a practical and easy way of carbon dioxide sequestration in cement-based materials has been

  5. Leaching of Phase II Mercury Control Technology By-Products

    SciTech Connect (OSTI)

    Hesbach, P.A.; Kachur, E.K.

    2007-07-01T23:59:59.000Z

    The U.S. EPA has issued a final regulation for control of mercury from coal-fired power plants. An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. These adulterated by-products, both ashes and FGD material, represent the greatest challenge to the DOE goal of increased utilization of by-products. The degree of stability of capture by-products and their potential for release of mercury can have a large economic impact on material sales or the approach to disposal. One of the considerations for mercury control technology is the potential trade-off between effective but temporary mercury capture and less effective but more permanent sequestration. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed aqueous leaching procedures on a select subset of the available sample pairs. This report describes batch leaching results for mercury, arsenic, and selenium.

  6. Center for By-Products Utilization CO2 SEQUESTRATION

    E-Print Network [OSTI]

    Saldin, Dilano

    climate change, reduced GHGs, improved air quality, CO2 reduction & sequestration, and carbon offsets. #12 for the development of a technology for the carbon dioxide (CO2) sequestration in non-air entrained concreteCenter for By-Products Utilization CO2 SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE By Tarun R. Naik

  7. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01T23:59:59.000Z

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  8. Remediation of Abandoned Mines Using Coal Combustion By-Products

    E-Print Network [OSTI]

    Aydilek, Ahmet

    . Maryland has about 450 coal mines out of which only 50 are active and about 150 mines produce AMD RafalkoRemediation of Abandoned Mines Using Coal Combustion By-Products Sowmya Bulusu1 ; Ahmet H. Aydilek that occurs when pyrite that is present in abandoned coal mines comes in contact with oxygen and water, which

  9. Oxidation of byproduct calcium sulfite hemihydrate from coal-fired power plant

    E-Print Network [OSTI]

    Bhatt, Sandeep

    1995-01-01T23:59:59.000Z

    The flue gas desulfurization by-product from the TU Electric Martin Lake power plant near Tatum, Texas was characterized using thermal analysis, x-ray diffraction, microprobe and infrared spectroscopy. The byproduct, called gypsite, consisted of a...

  10. Feasibility Analysis of Steam Reforming of Biodiesel by-product Glycerol to Make Hydrogen

    E-Print Network [OSTI]

    Joshi, Manoj

    2009-06-09T23:59:59.000Z

    Crude glycerol is the major byproduct from biodiesel industry. In general, for every 100 pounds of biodiesel produced, approximately 10 pounds of crude glycerol are produced as a by-product. As the biodiesel industry rapidly expands in the U...

  11. JASPERSE CHEM 341 TEST 4 VERSION 1 Conjugation, Diels-Alder, Aromaticity, Aromatic Reactions

    E-Print Network [OSTI]

    Jasperse, Craig P.

    byproducts). (21 points, 3 points each) SO3HHO HNO3, H 2SO4 O + 1. HNO3, H 2SO4 2. Cl2, AlCl 3 3. Fe, HCl 1

  12. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

    1990-05-15T23:59:59.000Z

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  13. North Dakota Refining Capacity Study

    SciTech Connect (OSTI)

    Dennis Hill; Kurt Swenson; Carl Tuura; Jim Simon; Robert Vermette; Gilberto Marcha; Steve Kelly; David Wells; Ed Palmer; Kuo Yu; Tram Nguyen; Juliam Migliavacca

    2011-01-05T23:59:59.000Z

    According to a 2008 report issued by the United States Geological Survey, North Dakota and Montana have an estimated 3.0 to 4.3 billion barrels of undiscovered, technically recoverable oil in an area known as the Bakken Formation. With the size and remoteness of the discovery, the question became 'can a business case be made for increasing refining capacity in North Dakota?' And, if so what is the impact to existing players in the region. To answer the question, a study committee comprised of leaders in the region's petroleum industry were brought together to define the scope of the study, hire a consulting firm and oversee the study. The study committee met frequently to provide input on the findings and modify the course of the study, as needed. The study concluded that the Petroleum Area Defense District II (PADD II) has an oversupply of gasoline. With that in mind, a niche market, naphtha, was identified. Naphtha is used as a diluent used for pipelining the bitumen (heavy crude) from Canada to crude markets. The study predicted there will continue to be an increase in the demand for naphtha through 2030. The study estimated the optimal configuration for the refinery at 34,000 barrels per day (BPD) producing 15,000 BPD of naphtha and a 52 percent refinery charge for jet and diesel yield. The financial modeling assumed the sponsor of a refinery would invest its own capital to pay for construction costs. With this assumption, the internal rate of return is 9.2 percent which is not sufficient to attract traditional investment given the risk factor of the project. With that in mind, those interested in pursuing this niche market will need to identify incentives to improve the rate of return.

  14. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gallons per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1995...

  15. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Gallons per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1997...

  16. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    Gasoline and Diesel Fuel Update (EIA)

    Gallons per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1996...

  17. Improving NMR Protein Structure Quality by Rosetta Refinement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR Protein Structure Quality by Rosetta Refinement: A Molecular Replacement Study. Improving NMR Protein Structure Quality by Rosetta Refinement: A Molecular Replacement Study....

  18. Experimental and modeling investigation of aromatic and polycyclic aromatic hydrocarbon formation in a premixed ethylene flame

    SciTech Connect (OSTI)

    Castaldi, M.J.; Marinov, N.M.; Melius, C.F. [and others

    1996-02-01T23:59:59.000Z

    Experimental and detailed chemical kinetic modeling has been performed to investigate aromatic and polyaromatic hydrocarbon formation pathways in a rich, sooting, ethylene-oxygen-argon premixed flame. An atmospheric pressure, laminar flat flame operated at an equivalence ratio of 2.5 was used to acquire experimental data for model validation. Gas composition analysis was conducted by an on-line gas chromatograph/mass spectrometer (GC/MS) technique. Measurements were made in the flame and post-flame zone for a number of low molecular weight species, aliphatics, aromatics and polycyclic aromatic hydrocarbons (PAHs) ranging from two to five-aromatic fused rings. The modeling results show the key reaction sequences leading to aromatic and polycyclic aromatic hydrocarbon growth involve the combination of resonantly stabilized radicals. In particular, propargyl and 1-methylallenyl combination reactions lead to benzene and methyl substituted benzene formation, while polycyclic aromatics are formed from cyclopentadienyl radicals and fused rings that have a shared C{sub 5} side structure. Naphthalene production through the reaction step of cyclopentadienyl self-combination and phenanthrene formation from indenyl and cyclopentadienyl combination were shown to be important in the flame modeling study. The removal of phenyl by O{sub 2} leading to cyclopentadienyl formation is expected to play a pivotal role in the PAH or soot precursor growth process under fuel-rich oxidation conditions.

  19. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two;2 Abstract The size distribution of polycyclic aromatic hydrocarbons (PAHs) and PAH derivatives of compounds. Keywords: Polycyclic aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated

  20. Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient air

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient of polycyclic aromatic hydrocarbons (PAHs) and of their oxidation products, such as nitrated and oxygenated PAHs hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons; Sampling

  1. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two aromatic hydrocarbons, 17 nitrated PAHs (NPAHs) and 8 oxygenated PAHs (OPAHs) were carried out during hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons

  2. Introducing Reference Semantics via Refinement Graeme Smith

    E-Print Network [OSTI]

    Smith, Graeme

    Introducing Reference Semantics via Refinement Graeme Smith Software Verification Research Centre, University of Queensland, Australia smith@svrc.uq.edu.au Abstract. Two types of semantics have been given

  3. Estimation method for the thermochemical properties of polycyclic aromatic molecules

    E-Print Network [OSTI]

    Yu, Joanna

    2005-01-01T23:59:59.000Z

    Polycyclic aromatic molecules, including polycyclic aromatic hydrocarbons (PAHs) have attracted considerable attention in the past few decades. They are formed during the incomplete combustion of hydrocarbon fuels and are ...

  4. Fluorescence method for enzyme analysis which couples aromatic amines with aromatic aldehydes

    DOE Patents [OSTI]

    Smith, R.E.; Dolbeare, F.A.

    1980-10-21T23:59:59.000Z

    Analysis of proteinases is accomplished using conventional amino acid containing aromatic amine substrates. Aromatic amines such as 4-methoxy-2-naphthylamine (4M2NA), 2-naphthylamine, aminoisophthalic acid dimethyl ester, p-nitroaniline, 4-methoxy-1-aminofluorene and coumarin derivatives resulting from enzymatic hydrolysis of the substrate couples with aromatic aldehydes such as 5-nitrosalicylaldehyde (5-NSA), benzaldehyde and p-nitrobenzaldehyde to produce Schiff-base complexes which are water insoluble. Certain Schiff-base complexes produce a shift from blue to orange-red (visible) fluorescence. Such complexes are useful in the assay of enzymes. No Drawings

  5. Fluorescence method for enzyme analysis which couples aromatic amines with aromatic aldehydes

    DOE Patents [OSTI]

    Smith, Robert E. [557 Escondido Cir., Livermore, CA 94550; Dolbeare, Frank A. [5178 Diane La., Livermore, CA 94550

    1980-10-21T23:59:59.000Z

    Analysis of proteinases is accomplished using conventional amino acid containing aromatic amine substrates. Aromatic amines such as 4-methoxy-2-naphthylamine (4M2NA), 2-naphthylamine, aminoisophthalic acid dimethyl ester, p-nitroaniline, 4-methoxy-1-aminofluorene and coumarin derivatives resulting from enzymatic hydrolysis of the substrate couples with aromatic aldehydes such as 5-nitrosalicylaldehyde (5-NSA), benzaldehyde and p-nitrobenzaldehyde to produce Schiff-base complexes which are water insoluble. Certain Schiff-base complexes produce a shift from blue to orange-red (visible) fluorescence. Such complexes are useful in the assay of enzymes.

  6. Utilization of by-product gypsum in construction 

    E-Print Network [OSTI]

    Stephenson, Angela Lorraine

    1987-01-01T23:59:59.000Z

    as a by-product (called phosphogypsum) during acidulation of phosphate rock in the manufacture phosphoric acid. The sulfate is produced in either a dihydrate or a hemihydrate form depending on the operating conditions. Phosphogypsum produced... by Mobil Chemi- cal Company (Pasadena, Texas) is in the dihydrate form and was previously studied. Phosphogypsum produced by Occidental Chemical Company (White Springs, Florida), on the other hand, is produced in a hemihydrate form and transforms...

  7. Aromaticity of Polycyclic Conjugated Hydrocarbons Milan Randic*

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    Aromaticity of Polycyclic Conjugated Hydrocarbons Milan RandicŽ* National Institute of Chemistry Chemistry 3462 G. Clar 6n Rule versus Hušckel 4n + 2 Rule 3464 H. Hydrocarbons versus Heteroatomic Systems Ordering 3476 VI. On Enumeration of Benzenoid Hydrocarbons 3477 VII. KekuleŽ Valence Structures Count 3479

  8. Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs) in snow and ice sampled at Colle designed, built and tested. Melt water from inner part of ice core section was pumped to an ICP-SFMS and ICP-OES. Melt water from outer section was on-line extracted by solid-phase cartridges for semi

  9. Green Petroleum Refining -Mathematical Models for Optimizing Petroleum Refining Under Emission Constraints

    E-Print Network [OSTI]

    Anderson, Charles H.

    Green Petroleum Refining - Mathematical Models for Optimizing Petroleum Refining Under Emission understand that my thesis may be made electronically available to the public. #12;iii Abstract Petroleum and treating options for petroleum refinery waste streams. The performance of the developed model

  10. An independent refiners approach to RFG

    SciTech Connect (OSTI)

    Czeskleba, M.

    1994-12-31T23:59:59.000Z

    This report was presented by Mike Czeskleba,Senior Business Analyst for Ashland Petroleum Company in Ashland, Kentucky. Ashland is one of the largest independent refiners and a leading marketer of gasoline and other petroleum products in the U.S. The issues addressed in this report concern the use of ethanol as a gasoline extender and renewable oxygenate, and its use in Reformulated Gasolines (RFG). The impact of Clean Air Act requirements for 1995 and beyond on petroleum refiners and producers is discussed. Some of the strategies which Ashland Petroleum Company is using to meet regulation requirements is also presented.

  11. Table 3.5 Selected Byproducts in Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are nowTotal" (Percent) Type: Sulfur Content API Gravity Period:Dakota" "megawatthours" ,"Entity","TypeWyoming"5 Selected Byproducts in Fuel

  12. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01T23:59:59.000Z

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  13. Transforming and Refining Abstract Constraint Specifications

    E-Print Network [OSTI]

    Walsh, Toby

    Transforming and Refining Abstract Constraint Specifications Alan M. Frisch1 , Brahim Hnich2 , Ian choose model transformations to reduce greatly the amount of effort that is required to solve a problem by systematic search. It is a consid- erable challenge to automate such transformations. A problem may be viewed

  14. Focus on Venezuelan heavy crude: refining margins

    SciTech Connect (OSTI)

    Not Available

    1984-01-25T23:59:59.000Z

    Of six crudes refined in the US Gulf Coast, heavy Venezuelan crude Lagunillas (15/sup 0/ API) provides the best margin per barrel. Data for end of December 1983 and the first three weeks of January show that margins on all crudes are on the rise in this market, due to a turnaround in product prices. The lighter crudes are showing the greatest increase in Gross Product Worth. This is having a modest shrinking effect on the margin differential between light and heavy crudes in this market. The domestic crude West Texas Intermediate, at 40/sup 0/ API, provides the highest GPW in this crude slate sample, over US $31 per barrel, compared to GPW of under US $28 per barrel for Lagunillas. Still, as Lagunillas cost about US $8 less than does WTI, refiners with sufficient residue conversion capacity can be earning about US $3.50 more in margin per barrel than they can with WTI. Although few refiners would be using a 15/sup 0/ API crude exclusively for any length of time, heavier oil's inclusion in modern refiners' diets is enhancing their competitive position more than any other single factor. This issue of Energy Detente presents the fuel price/tax series and industrial fuel prices for January 1984 for countries of the Western Hemisphere.

  15. Refining industry trends: Europe and surroundings

    SciTech Connect (OSTI)

    Guariguata, U.G.

    1997-05-01T23:59:59.000Z

    The European refining industry, along with its counterparts, is struggling with low profitability due to excess primary and conversion capacity, high operating costs and impending decisions of stringent environmental regulations that will require significant investments with hard to justify returns. This region was also faced in the early 1980s with excess capacity on the order of 4 MMb/d and satisfying the {open_quotes}at that point{close_quotes} demand by operating at very low utilization rates (60%). As was the case in the US, the rebalancing of the capacity led to the closure of some 51 refineries. Since the early 1990s, the increase in demand growth has essentially balanced the capacity threshold and utilization rates are settled around the 90% range. During the last two decades, the major oil companies have reduced their presence in the European refining sector, giving some state oil companies and producing countries the opportunity to gain access to the consumer market through the purchase of refining capacity in various countries-specifically, Kuwait in Italy; Libya and Venezuela in Germany; and Norway in other areas of Scandinavia. Although the market share for this new cast of characters remains small (4%) relative to participation by the majors (35%), their involvement in the European refining business set the foundation whereby US independent refiners relinquished control over assets that could not be operated profitably as part of a previous vertically integrated structure, unless access to the crude was ensured. The passage of time still seems to render this model valid.

  16. Real-time characterization of particle-bound polycyclic aromatic hydrocarbons in ambient aerosols and from motor-vehicle exhaust

    E-Print Network [OSTI]

    Polidori, A.; Hu, S.; Biswas, S.; Delfino, R. J; Sioutas, C.

    2008-01-01T23:59:59.000Z

    of polycyclic aromatic hydrocarbons in coupled out- door/polycyclic aromatic hydrocarbon concentration in combustionbound polycyclic aromatic hydrocarbons K. A. , Morris, J. ,

  17. Device for aqueous detection of nitro-aromatic compounds

    DOE Patents [OSTI]

    Reagen, William K. (Stillwater, MN); Schulz, Amber L. (Bremerton, WA); Ingram, Jani C. (Idaho Falls, ID); Lancaster, Gregory D. (Idaho Falls, ID); Grey, Alan E. (Idaho Falls, ID)

    1994-01-01T23:59:59.000Z

    This invention relates to a compact and portable detection apparatus for ro-aromatic based chemical compounds, such as nitrotoluenes, dinitrotoluenes, and trinitrotoluene (TNT). The apparatus is based upon the use of fiber optics using filtered light. The preferred process of the invention relies upon a reflective chemical sensor and optical and electronic components to monitor a decrease in fluorescence when the nitro-aromatic molecules in aqueous solution combine and react with a fluorescent polycyclic aromatic compound.

  18. aromatic aldehyde production: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    virtual product and production Lemurell, Stefan 291 Production of 18F-Labeled Radiopharmaceuticals Biology and Medicine Websites Summary: One carbon Two carbon Aromatic ...

  19. aromatic diamine curing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hawaii 96822 University. University of Hawai'i at Manoa. (1) Ramdahl, T.; Bjorseth, J. Handbook of Polycyclic Aromatic Kaiser, Ralf I. 178 Photofragmentation spectroscopy of...

  20. aromatic nitro compounds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the reactions of amines with aldehydes and with aromatic nitro - compounds in acetonitrile. Open Access Theses and Dissertations Summary: ??Kinetic and equilibrium studies of...

  1. aromatic hydrocarbon formation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Formation, Hamersley Group, and were collected in mines near Tom Price mature gas condensates. The aromatic fraction predominantly consists of unsubstituted two and...

  2. aromatic methoxy groups: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Formation, Hamersley Group, and were collected in mines near Tom Price mature gas condensates. The aromatic fraction predominantly consists of unsubstituted two and...

  3. aromatic hydrocarbon carcinogenesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Ecology Websites Summary: ), and there are oil refineries on the shore. In this environment, input of aromatic hydrocarbons from petroleum and the Yarra River Estuary J. David...

  4. aromatic hydrocarbon tracers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Ecology Websites Summary: ), and there are oil refineries on the shore. In this environment, input of aromatic hydrocarbons from petroleum and the Yarra River Estuary J. David...

  5. Grain Refinement of Permanent Mold Cast Copper Base Alloys

    SciTech Connect (OSTI)

    M.Sadayappan; J.P.Thomson; M.Elboujdaini; G.Ping Gu; M. Sahoo

    2005-04-01T23:59:59.000Z

    Grain refinement is a well established process for many cast and wrought alloys. The mechanical properties of various alloys could be enhanced by reducing the grain size. Refinement is also known to improve casting characteristics such as fluidity and hot tearing. Grain refinement of copper-base alloys is not widely used, especially in sand casting process. However, in permanent mold casting of copper alloys it is now common to use grain refinement to counteract the problem of severe hot tearing which also improves the pressure tightness of plumbing components. The mechanism of grain refinement in copper-base alloys is not well understood. The issues to be studied include the effect of minor alloy additions on the microstructure, their interaction with the grain refiner, effect of cooling rate, and loss of grain refinement (fading). In this investigation, efforts were made to explore and understand grain refinement of copper alloys, especially in permanent mold casting conditions.

  6. 5.841 Crystal Structure Refinement, Fall 2006

    E-Print Network [OSTI]

    Mueller, Peter

    This course in crystal structure refinement examines the practical aspects of crystal structure determination from data collection strategies to data reduction and basic and advanced refinement problems of organic and ...

  7. 5.067 Crystal Structure Refinement, Fall 2007

    E-Print Network [OSTI]

    Mueller, Peter

    This course in crystal structure refinement examines the practical aspects of crystal structure determination from data collection strategies to data reduction and basic and advanced refinement problems of organic and ...

  8. Synthetic aggregates prepared from flue gas desulfurization by-products using various binder materials

    SciTech Connect (OSTI)

    Bellucci, J.; Graham, U.M.; Hower, J.C.; Robl, T.L. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1994-12-31T23:59:59.000Z

    Flue Gas Desulfurization (FGD) by-products can be converted into environmentally safe and structurally stable aggregates. One type of synthetic aggregate was prepared using an optimum mixture of (FGD) by-products, fly ash, and water. Mineral reactions have been examined using X-ray diffraction and scanning electron microscope.

  9. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25T23:59:59.000Z

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  10. Dinosaurs can fly -- High performance refining

    SciTech Connect (OSTI)

    Treat, J.E. [Booz-Allen and Hamilton, Inc., San Francisco, CA (United States)

    1995-09-01T23:59:59.000Z

    High performance refining requires that one develop a winning strategy based on a clear understanding of one`s position in one`s company`s value chain; one`s competitive position in the products markets one serves; and the most likely drivers and direction of future market forces. The author discussed all three points, then described measuring performance of the company. To become a true high performance refiner often involves redesigning the organization as well as the business processes. The author discusses such redesigning. The paper summarizes ten rules to follow to achieve high performance: listen to the market; optimize; organize around asset or area teams; trust the operators; stay flexible; source strategically; all maintenance is not equal; energy is not free; build project discipline; and measure and reward performance. The paper then discusses the constraints to the implementation of change.

  11. Validating Process Refinement with Ontologies , Gerd Groener2

    E-Print Network [OSTI]

    Staab, Steffen

    Validating Process Refinement with Ontologies Yuan Ren1 , Gerd Groener2 , Jens Lemcke3 , Tirdad University of Koblenz-Landau, 3 SAP AG Abstract. A crucial task in process management is the validation of process refinements. A process refinement is a process description in a more fine-grained representation

  12. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    NONE

    2006-08-15T23:59:59.000Z

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  13. Aromatics oxidation and soot formation in flames

    SciTech Connect (OSTI)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)

    1993-12-01T23:59:59.000Z

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

  14. Treatability study on the use of by-product sulfur in Kazakhstan for the stabilization of hazardous and radioactive wastes

    SciTech Connect (OSTI)

    Kalb, P.D.; Milian, L.W. [Brookhaven National Lab., Upton, NY (United States). Environmental and Waste Technology Center; Yim, S.P. [Korea Atomic Energy Research Inst. (Korea, Republic of); Dyer, R.S.; Michaud, W.R. [Environmental Protection Agency (United States)

    1997-12-01T23:59:59.000Z

    The Republic of Kazakhstan generates significant quantities of excess elemental sulfur from the production and refining of petroleum reserves. In addition, the country also produces hazardous, and radioactive wastes which require treatment/stabilization. In an effort to find secondary uses for the elemental sulfur, and simultaneously produce a material which could be used to encapsulate, and reduce the dispersion of harmful contaminants into the environment, BNL evaluated the use of the sulfur polymer cement (SPC) produced from by-product sulfur in Kazakhstan. This thermoplastic binder material forms a durable waste form with low leaching properties and is compatible with a wide range of waste types. Several hundred kilograms of Kazakhstan sulfur were shipped to the US and converted to SPC (by reaction with 5 wt% organic modifiers) for use in this study. A phosphogypsum sand waste generated in Kazakhstan during the purification of phosphate fertilizer was selected for treatment. Waste loadings of 40 wt% were easily achieved. Waste form performance testing included compressive strength, water immersion, and Accelerated Leach Testing.

  15. Treatability study on the use of by-product sulfur in Kazakhstan for the stabilization of hazardous and radioactive wastes

    SciTech Connect (OSTI)

    Yim, Sung Paal; Kalb, P.D.; Milian, L.W.

    1997-08-01T23:59:59.000Z

    The Republic of Kazakhstan generates significant quantities of excess sulfur from the production and refining of petroleum reserves. In addition, the country also produces hazardous, and radioactive wastes which require treatment/stabilization. In an effort to find secondary uses for the elemental sulfur, and simultaneously produce a material which could be used to encapsulate, and reduce the dispersion of harmful contaminants into the environment, BNL evaluated the use of the sulfur polymer cement (SPC) produced from by-product sulfur in Kazakhstan. This thermoplastic binder material forms a durable waste form with low leaching properties and is compatible with a wide range of waste types. Several hundred kilograms of Kazakhstan sulfur were shipped to the U.S. and converted to SPC (by reaction with 5 wt% organic modifiers) for use in this study. A phosphogypsum sand waste generated in Kazakhstan during the purification of phosphate fertilizer was selected for treatment. Waste loading of 40 wt% were easily achieved. Waste form performance testing included compressive strength, water immersion, and Accelerated Leach Testing. 14 refs., 7 figs., 6 tabs.

  16. Aromatics oxidation and soot formation in flames

    SciTech Connect (OSTI)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T.

    1993-04-01T23:59:59.000Z

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify, and to confirm or determine rate constants for, the main benzene oxidation reactions in flames, and to characterize soot and fullerenes and their formation mechanisms and kinetics. Stable and radical species profiles in the aromatics oxidation study are measured using molecular beam sampling with on-line mass spectrometry. The rate of soot formation measured by conventional optical techniques is found to support the hypotheses that particle inception occurs through reactive coagulation of high molecular weight PAH in competition with destruction by OHattack, and that the subsequent growth of the soot mass occurs through addition reactions of PAH and C[sub 2]H[sub 2] with the soot particles. During the first year of this reporting period, fullerenes C[sub 60] and C[sub 70] in substantial quantities were found in the flames being studied. The fullerenes were recovered, purified and spectroscopically identified. The yields of C[sub 60] and C[sub 70] were then determined over ranges of conditions in low-pressure premixed flames of benzene and oxygen.

  17. Synthesis of Aliphatic-Aromatic Copolyesters by a High Temperature

    E-Print Network [OSTI]

    Khan, Saad A.

    -aromatic polyesters. #12;Full Paper: Reverse-selective polymer membranes exhibiting high CO2 affinity can be used for purification of H2 in industrial gasification processes. In this work, the phy- sical properties of CO2Synthesis of Aliphatic-Aromatic Copolyesters by a High Temperature Bulk Reaction Between Poly

  18. Nutritional Status of some Aromatic Plants Grown to Produce Volatile Oils under Treated Municipal Wastewater irrigation

    E-Print Network [OSTI]

    Khalifa, Ramadan Khalifa Mohamed

    2009-01-01T23:59:59.000Z

    used for growing aromatic plants in the arid area to produceoil for five aromatic plants , 2) evaluation of TMW assource for the tested plants and study its nutritional

  19. E-Print Network 3.0 - aromatic rings synthesis Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... - ent aromatic hydrocarbons (ZIKTO and CARSON 1970r NEFF and ANDERSON ... Source:...

  20. E-Print Network 3.0 - aromatic hydrocarbons resulting Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Summary: fuel. (d) Lubricating oil. - 300 400 Wavelength (nm) Results Concentrations of aromatic hydrocarbons... Aust. J....

  1. E-Print Network 3.0 - aromatic hydrocarbon concentrations Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Summary: fuel. (d) Lubricating oil. - 300 400 Wavelength (nm) Results Concentrations of aromatic hydrocarbons... Bay...

  2. E-Print Network 3.0 - aromatic hydrocarbons concentrations Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Summary: fuel. (d) Lubricating oil. - 300 400 Wavelength (nm) Results Concentrations of aromatic hydrocarbons... Bay...

  3. MECS 2006 - Petroleum Refining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomy andTermsDepartment1|Petroleum Refining MECS 2006 -

  4. Detoxification of aromatic pollutants by fungal enzymes

    SciTech Connect (OSTI)

    Bollag, J.M.; Dec, J. [Pennsylvania State Univ., University Park, PA (United States)

    1995-12-31T23:59:59.000Z

    Fungal enzymes, such as laccase, peroxidase, and tyrosinase, play a prominent role in catalyzing the transformation of various aromatic compounds in the environment. The enzyme-mediated oxidative coupling reaction results in covalent binding of chlorinated phenols and anilines to soil organic matter or polymerization of the substrates in aquatic systems. Both of these processes are accompanied by a detoxification effect. Therefore, it has been postulated that they be exploited for the treatment of polluted soil and water. The mechanism and efficiency of oxidative coupling in pollutant removal were studied by incubation of chlorinated phenols and anilines with various humic substances or soil and analysis of the reaction products by chromatography and mass and {sup 13}C nuclear magnetic resonance (NMR) spectrometry. The decontamination effect could be enhanced by optimization of the reaction conditions and immobilization of enzymes on solid materials. The results obtained strongly support the concept of using enzymes for control of environmental pollution.

  5. avoiding by-product formation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Engineering Websites Summary: Center for By-Products Utilization USE OF CLEAN-COAL ASH FOR MANAGING ASR By Zichao Wu and Tarun R College of Engineering and Applied...

  6. atmospheric oxidation by-products: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Engineering Websites Summary: Center for By-Products Utilization USE OF CLEAN-COAL ASH FOR MANAGING ASR By Zichao Wu and Tarun R College of Engineering and Applied...

  7. arc-induced toxic by-products: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Engineering Websites Summary: Center for By-Products Utilization USE OF CLEAN-COAL ASH FOR MANAGING ASR By Zichao Wu and Tarun R College of Engineering and Applied...

  8. animal protein by-products: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Engineering Websites Summary: Center for By-Products Utilization USE OF CLEAN-COAL ASH FOR MANAGING ASR By Zichao Wu and Tarun R College of Engineering and Applied...

  9. Case Study of Optimal Byproduct Gas Distribution in Integrated Steel Mill Using Multi-Period Optimization

    E-Print Network [OSTI]

    Makinen, K.; Kymalainen, T.; Junttila, J.

    2012-01-01T23:59:59.000Z

    byproduct gases at varying rates. The differences between gas generation and consumption rates are compensated with gas holders. However, under certain circumstances the imbalances can lead to the flaring of excessive gas or require the purchase...

  10. Electron beam skull melting and refining of secondary copper

    SciTech Connect (OSTI)

    Bychkov, Y.; Ladokhin, S. [Donetskvtortsvetmet, Donetsk (Ukraine)

    1995-12-31T23:59:59.000Z

    Electron Beam Melting is the most efficient technology for metals and alloys refining. For secondary metals processing the Electron Beam Skull Melting (EBSM) with the electromagnetic stirring (EMS) of melt in the crucible was shown to be the most appropriate. The copper produced by EBSM with EMS possesses higher density and electric conductivity in comparison with other refining methods. The details for high power electrical machines were cast of the copper waste refined by EBSM technology.

  11. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31T23:59:59.000Z

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  12. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    250 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  13. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    - - - - W W - - - - - - See footnotes at end of table. 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State 292 Energy...

  14. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    220 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  15. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    220 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  16. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Energy Information Administration Petroleum Marketing Annual 1995 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  17. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    134 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  18. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    220 Energy Information AdministrationPetroleum Marketing Annual 2000 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  19. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Energy Information Administration Petroleum Marketing Annual 1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  20. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Energy Information Administration Petroleum Marketing Annual 1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  1. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    250 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  2. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Energy Information Administration Petroleum Marketing Annual 1995 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  3. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    134 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  4. ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency Roadmap for Petroleum Refineries in California ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries in California refiningroadmap.pdf More...

  5. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1997...

  6. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1996...

  7. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Retail Volumes 1996 Annual Averages Motor Gasoline No. 2 Distillate Propane Kero-jet Residual Fuel Oil Other Energy Information Administration Petroleum Marketing Annual...

  8. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Retail Volumes 1997 Annual Averages Motor Gasoline No. 2 Distillate Propane Kero-jet Residual Fuel Oil Other Energy Information Administration Petroleum Marketing Annual...

  9. Adaptively refined large eddy simulations of clusters

    E-Print Network [OSTI]

    Maier, A; Schmidt, W; Niemeyer, J C

    2009-01-01T23:59:59.000Z

    We present a numerical scheme for modelling unresolved turbulence in cosmological adaptive mesh refinement codes. As a first application, we study the evolution of turbulence in the intra-cluster medium and in the core of a galaxy cluster. Simulations with and without subgrid scale model are compared in detail. Since the flow in the ICM is subsonic, the global turbulent energy contribution at the unresolved length scales is smaller than 1% of the internal energy. We find that the production of turbulence is closely correlated with merger events occurring in the cluster environment, and its dissipation locally affects the cluster energy budget. Because of this additional source of dissipation, the core temperature is larger and the density is smaller in the presence of subgrid scale turbulence than in the standard adiabatic run, resulting in a higher entropy core value.

  10. DEVELOPMENT OF ACTIVATED CARBONS FROM COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    Harold H. Schobert; M. Mercedes Maroto-Valer; Zhe Lu

    2003-09-30T23:59:59.000Z

    The increasing role of coal as a source of energy in the 21st century will demand environmental and cost-effective strategies for the use of coal combustion by-products (CCBPs), mainly unburned carbon in fly ash. Unburned carbon is nowadays regarded as a waste product and its fate is mainly disposal, due to the present lack of efficient routes for its utilization. However, unburned carbon is a potential precursor for the production of adsorbent carbons, since it has gone through a devolatilization process while in the combustor, and therefore, only requires to be activated. Accordingly, the principal objective of this work was to characterize and utilize the unburned carbon in fly ash for the production of activated carbons. The unburned carbon samples were collected from different combustion systems, including pulverized utility boilers, a utility cyclone, a stoker, and a fluidized bed combustor. LOI (loss-on-ignition), proximate, ultimate, and petrographic analyses were conducted, and the surface areas of the samples were characterized by N2 adsorption isotherms at 77K. The LOIs of the unburned carbon samples varied between 21.79-84.52%. The proximate analyses showed that all the samples had very low moisture contents (0.17 to 3.39 wt %), while the volatile matter contents varied between 0.45 to 24.82 wt%. The elemental analyses show that all the unburned carbon samples consist mainly of carbon with very little hydrogen, nitrogen, sulfur and oxygen In addition, the potential use of unburned carbon as precursor for activated carbon (AC) was investigated. Activated carbons with specific surface area up to 1075m{sup 2}/g were produced from the unburned carbon. The porosity of the resultant activated carbons was related to the properties of the unburned carbon feedstock and the activation conditions used. It was found that not all the unburned carbon samples are equally suited for activation, and furthermore, their potential as activated carbons precursors could be inferred from their physical and chemical properties. The developed porosity of the activated carbon was a function of the oxygen content, porosity and H/C ratio of the parent unburned carbon feedstock. It was observed that extended activation times and high activation temperatures increased the porosity of the produced activated carbon at the expense of the solid yield. The development of activated carbon from unburned carbon in fly ash has been proven to be a success by this study in terms of the higher surface areas of the resultant activated carbons, which are comparable with commercial activated carbons. However, unburned carbon samples obtained from coal-fired power plants as by-product have high ash content, which is unwanted for the production of activated carbons. Therefore, the separation of unburned carbon from the fly ash is expected to be beneficial for the utilization of unburned carbon to produce activated carbons with low ash content.

  11. Applications developed for byproduct /sup 85/Kr and tritium

    SciTech Connect (OSTI)

    Remini, W.C.; Case, F.N.; Haff, K.W.; Tiegs, S.M.

    1983-01-01T23:59:59.000Z

    The radionuclides, krypton-85 and tritium, both of which are gases under ordinary conditions, are used in many applications in industries and by the military forces. Krypton-85 is produced during the fissioning of uranium and is released during the dissolution of spent-fuel elements. It is a chemically inert gas that emits 0.695-MeV beta rays and a small yield of 0.54-MeV gammas over a half life of 10.3 years. Much of the /sup 85/Kr currently produced is released to the atmosphere; however, large-scale reprocessing of fuel will require collection of the gas and storage as a waste product. An alternative to storage is utilization, and since the chemical and radiation characteristics of /sup 85/Kr make this radionuclide a relatively low hazard from the standpoint of contamination and biological significance, a number of uses have been developed. Tritium is produced as a byproduct of the nuclear-weapons program, and it has a half life of 12.33 years. It has a 0.01861-MeV beta emission and no gamma emission. The absence of a gamma-ray energy eliminates the need for external shielding of the devices utilizing tritium, thus making them easily transportable. Many of the applications require only small quantities of /sup 85/Kr or tritium; however, these uses are important to the technology base of the nation. A significant development that has the potential for beneficial utilization of large quantities of /sup 85/Kr and of tritium involves their use in the production of low-level lighting devices. Since these lights are free from external fuel supplies, have a long half life (> 10 years), are maintenance-free, reliable, and easily deployed, both military and civilian airfield-lighting applications are being studied.

  12. aromatic hydrocarbon emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Detection of mid-infrared Aromatic Hydrocarbon Emission Features from the Small Magellanic Cloud Astrophysics...

  13. aromatic heterocyclic compounds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Infrared Spectroscopy of Matrix-Isolated Polycyclic Aromatic Compounds and Their Ions. 6....

  14. aromatic hydrocarbon cations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 NEAR-INFRARED SPECTROSCOPY OF NITROGENATED POLYCYCLIC AROMATIC HYDROCARBON CATIONS FROM 0.7 TO 2.5...

  15. aromatic hydrocarbon emission: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Detection of mid-infrared Aromatic Hydrocarbon Emission Features from the Small Magellanic Cloud Astrophysics...

  16. aromatic hydrocarbons exhibited: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 14 through March 7, 2014 Opening Reception: Friday, February 14, 5-8PM TRI-COUNTY HIGH Berdichevsky, Victor 443 The Behavior of the Aromatic Features in M101 HII...

  17. Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures

    E-Print Network [OSTI]

    Desai, Anuradha M.

    2007-04-25T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

  18. Modeling the biodegradability and physicochemical properties of polycyclic aromatic hydrocarbons

    E-Print Network [OSTI]

    Dimitriou-Christidis, Petros

    2006-10-30T23:59:59.000Z

    The biodegradability and physicochemical properties of unsubstituted and methylated polycyclic aromatic hydrocarbons (PAHs) were investigated. The focus was on the development of models expressing the influence of molecular structure and properties...

  19. Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures 

    E-Print Network [OSTI]

    Desai, Anuradha M.

    2007-04-25T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

  20. New correlation accurately calculates water solubilities of aromatics

    SciTech Connect (OSTI)

    Yaws, C.L.; Bu, L.; Nijhawan, S. (Lamar Univ., Beaumont, TX (United States))

    1994-08-29T23:59:59.000Z

    A new correlation calculates reliable aromatics solubilities in water down to very low concentrations. The correlation, based on boiling point, can be used for initial engineering studies. The importance of hydrocarbon solubility in water is increasing because of health, safety, and environmental issues. The paper begins with a discussion of the importance of solubility, even at low concentrations. The new correlation is described, aromatics are compared with paraffins, and the new correlation is compared with the API correlation.

  1. Catalytic hydrogenation of an aromatic sulfonyl chloride into thiophenol

    E-Print Network [OSTI]

    Rouckout, Nicolas Julien

    2009-05-15T23:59:59.000Z

    to the facile oxidation by air into disulfides [3]. Many aliphatic thiols are important starting materials for the synthesis of crop- protection agents, pharmaceuticals, agrochemicals and polysulfides. They are also widely used as polymerization regulators... for the preparation of pharmaceuticals, agrochemicals, dyes, pigments, rubber, plastics and metal finishing [3]. The current market volume for aromatic thiols was determined to be more than 10 million pounds per year [4]. Aromatic thiols are commonly synthesized...

  2. Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments

    E-Print Network [OSTI]

    Sandberg, William Allan

    1986-01-01T23:59:59.000Z

    POLYCYCLIC AROMATIC HYDROCARBON DISTRIBUTIONS IN MISSISSIPPI FAN SEDIMENTS A Thesis by WILLIAM ALLAN SANDBERG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE December 1986 Major Subject: Oceanography POLYCYCLIC AROMATIC HYDROCARBON DISTRIBUTIONS IN MISSISSIPPI FAN SEDIMENTS A Thesis by WILLIAM ALLAN SANDBERG Approved as to style and content by: James M. Brooks (Chairman of Committee) Leis M...

  3. Emission of polycyclic aromatic hydrocarbons in China

    SciTech Connect (OSTI)

    Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-02-01T23:59:59.000Z

    Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

  4. Parallel Triangular Decompositions of an Oil Refining Simulation Xiaodong Zhang

    E-Print Network [OSTI]

    Moreno Maza, Marc

    important process in oil refining is to separate the crude oil into various oil products. This process the composition of the various oil products in designed refining columns operated under a given set of conditions oil products. This process is called distilla- tion, which is a thermal separation method

  5. Specification and Refinement of a RealTime Control System

    E-Print Network [OSTI]

    Smith, Graeme

    such approach via the specification and refinement of the well­known Steam Boiler Control Problem. The case. These features, although not central to the Steam Boiler Control Problem, are typical of features which must­level (i.e., abstract) specification of the Steam Boiler Control Problem. This specification is refined

  6. Feasibility of Organizations -A Refinement of Chemical Organization Theory

    E-Print Network [OSTI]

    Hinze, Thomas

    Feasibility of Organizations - A Refinement of Chemical Organization Theory with Application to P a theorem providing a criteria for an unfeasible organization. This is a refinement of organization theory organization. Key words: reaction networks, constructive dynamical systems, chem- ical organization theory

  7. On Adaptive Mesh Refinement for Atmospheric Pollution Models

    E-Print Network [OSTI]

    Sandu, Adrian

    On Adaptive Mesh Refinement for Atmospheric Pollution Models Emil M. Constantinescu and Adrian res- olution system for modeling regional air pollution based on the chemical transport model STEM. Keywords: Air Pollution Modeling, Adaptive Mesh Refinement. 1 Introduction Inadequate grid resolution can

  8. Land application uses for dry FGD by-products. Phase 2 report

    SciTech Connect (OSTI)

    Stehouwer, R.; Dick, W.; Bigham, J. [Ohio State Univ., Columbus, OH (United States)] [and others

    1996-03-01T23:59:59.000Z

    A study was initiated in December 1990 to demonstrate large volume beneficial uses of flue gas desulfurization (FGD) by-products. A Phase 1 report provided results of an extensive characterization of chemical, physical, mineralogical and engineering properties of 58 dry FGD by-product samples. The Phase 1 report concluded that high volume beneficial reuses will depend on the economics related to their ability to substitute for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mine lands). Phase 2 objectives were (1) to conduct laboratory and greenhouse studies of FGD and soil (spoil) mixtures for agronomic and engineering applications, (2) to initiate field studies related to high volume agronomic and engineering uses, and (3) to develop the basic methodological framework for estimation of the financial and economic costs and benefits to society of several FGD reuse options and to make some preliminary runs of economic models. High volume beneficial reuses of dry FGD by-products have been successfully demonstrated. Adverse environmental impacts have been negligible. Although few sources of dry FGD by-products currently exist in Ohio and the United States there is potential for smaller coal-fired facilities to adopt S0{sub 2} scrubbing technologies that produce dry FGD material. Also much of what we have learned from studies on dry FGD by-products is applicable to the more prevalent wet FGD by-products. The adaptation of the technologies demonstrated in this project seem to be not only limited by economic constraints, but even more so, by the need to create awareness of the market potential of using these FGD by-products.

  9. Land application uses for dry FGD by-products, Phase 1 report

    SciTech Connect (OSTI)

    Bigham, J.; Dick, W.; Forster, L.; Hitzhusen, F.; McCoy, E.; Stehouwer, R.; Traina, S.; Wolfe, W.

    1993-04-01T23:59:59.000Z

    The 1990 amendments to the Clean Air Act have spurred the development of flue gas desulfurization (FGD) processes, several of which produce a dry, solid by-product material consisting of excess sorbent, reaction products containing sulfates and sulfites, and coal fly ash. FGD by-product materials are treated as solid wastes and must be landfilled. It is highly desirable to find beneficial reuses for these materials provided the environmental impacts are minimal and socially acceptable. Phase 1 results of a 4 and 1/2 year study to demonstrate large volume beneficial uses of FGD by-products are reported. The purpose of the Phase 1 portion of the project was to characterize the chemical, physical, mineralogical and engineering properties of the FGD by-product materials obtained from various FGD technologies being developed in the state of Ohio. Phase 1 also involved the collection of baseline economic data related to the beneficial reuse of these FGD materials. A total of 58 samples were collected and analyzed. The results indicated the chemical composition of the FGD by-product materials were dominated by Ca, S, Al, and Si. Many of the elements regulated by the US Environmental Protection Agency reside primarily in the fly ash. Phase 1 results revealed that FGD by-product materials are essentially coal fly ash materials diluted with unreacted sorbent and reaction products. High volume beneficial reuses will depend on the economics of their substituting for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mines). Environmental constraints to the beneficial reuse of dry FGD by-product materials, based on laboratory and leachate studies, seem to be less than for coal fly ash.

  10. Long-range transport of particulate polycyclic aromatic hydrocarbons at Cape Hedo remote island site in the East China Sea between 2005 and 2008

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    of polycyclic aromatic hydrocarbons (PAHs) for 2004. Atmos.of polynuclear aromatic hydrocarbons in ambient air throughpolycyclic aromatic hydrocarbons in urban air of Hong Kong.

  11. Changing System Interfaces Consistently: a New Refinement Strategy for CSP B

    E-Print Network [OSTI]

    Doran, Simon J.

    Changing System Interfaces Consistently: a New Refinement Strategy for CSP B Steve Schneider refinement in the context of CSP B. Our motivation to include this notion of refinement within the CSP B to change the events of a CSP process and the B machines when refining a system. Notions of refinement based

  12. Electron beam cold hearth refining in Vallejo

    SciTech Connect (OSTI)

    Lowe, J.H.C. [Axel Johnson Metals, Inc., Vallejo, CA (United States)

    1994-12-31T23:59:59.000Z

    Electron Beam Cold Hearth Refining Furnace (EBCHR) in Vallejo, California is alive, well, and girding itself for developing new markets. A brief review of the twelve years experience with EBCHR in Vallejo. Acquisition of the Vallejo facility by Axel Johnson Metals, Inc. paves the way for the development of new products and markets. A discussion of some of the new opportunities for the advancement of EBCHR technology. Discussed are advantages to the EBCHR process which include: extended surface area of molten metal exposed to higher vacuum; liberation of insoluble oxide particles to the surface of the melt; higher temperatures that allowed coarse solid particles like carbides and carbonitrides to be suspended in the fluid metal as fine micro-segregates, and enhanced removal of volatile trace impurities like lead, bismuth and cadmium. Future work for the company includes the continued recycling of alloys and also fabricating stainless steel for the piping of chip assembly plants. This is to prevent `killer defects` that ruin a memory chip.

  13. GRChombo : Numerical Relativity with Adaptive Mesh Refinement

    E-Print Network [OSTI]

    Katy Clough; Pau Figueras; Hal Finkel; Markus Kunesch; Eugene A. Lim; Saran Tunyasuvunakool

    2015-03-11T23:59:59.000Z

    Numerical relativity has undergone a revolution in the past decade. With a well-understood mathematical formalism, and full control over the gauge modes, it is now entering an era in which the science can be properly explored. In this work, we introduce GRChombo, a new numerical relativity code written to take full advantage of modern parallel computing techniques. GRChombo's features include full adaptive mesh refinement with block structured Berger-Rigoutsos grid generation which supports non-trivial "many-boxes-in-many-boxes" meshing hierarchies, and massive parallelism through the Message Passing Interface (MPI). GRChombo evolves the Einstein equation with the standard BSSN formalism, with an option to turn on CCZ4 constraint damping if required. We show that GRChombo passes all the standard "Apples-to-Apples" code comparison tests. We also show that it can stably and accurately evolve vacuum black hole spacetimes such as binary black hole mergers, and non-vacuum spacetimes such as scalar collapses into black holes. As an illustration of its AMR capability, we demonstrate the evolution of triple black hole merger, which can be set up trivially in GRChombo.

  14. GRChombo : Numerical Relativity with Adaptive Mesh Refinement

    E-Print Network [OSTI]

    Clough, Katy; Finkel, Hal; Kunesch, Markus; Lim, Eugene A; Tunyasuvunakool, Saran

    2015-01-01T23:59:59.000Z

    Numerical relativity has undergone a revolution in the past decade. With a well-understood mathematical formalism, and full control over the gauge modes, it is now entering an era in which the science can be properly explored. In this work, we introduce GRChombo, a new numerical relativity code written to take full advantage of modern parallel computing techniques. GRChombo's features include full adaptive mesh refinement with block structured Berger-Rigoutsos grid generation which supports non-trivial "many-boxes-in-many-boxes" meshing hierarchies, and massive parallelism through the Message Passing Interface (MPI). GRChombo evolves the Einstein equation with the standard BSSN formalism, with an option to turn on CCZ4 constraint damping if required. We show that GRChombo passes all the standard "Apples-to-Apples" code comparison tests. We also show that it can stably and accurately evolve vacuum black hole spacetimes such as binary black hole mergers, and non-vacuum spacetimes such as scalar collapses into b...

  15. Design manual for management of solid by-products from advanced coal technologies

    SciTech Connect (OSTI)

    NONE

    1994-10-01T23:59:59.000Z

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  16. Technical support for the Ohio Coal Technology Program. Volume 1, Baseline of knowledge concerning by-product characteristics: Final report

    SciTech Connect (OSTI)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

    1989-08-28T23:59:59.000Z

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LRl and comprises two volumes. Volume I presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume II consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  17. IGCC and PFBC By-Products: Generation, Characteristics, and Management Practices

    SciTech Connect (OSTI)

    Pflughoeft-Hassett, D.F.

    1997-09-01T23:59:59.000Z

    The following report is a compilation of data on by-products/wastes from clean coal technologies, specifically integrated gasification combined cycle (IGCC) and pressurized fluidized-bed combustion (PFBC). DOE had two objectives in providing this information to EPA: (1) to familiarize EPA with the DOE CCT program, CCT by-products, and the associated efforts by DOE contractors in the area of CCT by-product management and (2) to provide information that will facilitate EPA's effort by complementing similar reports from industry groups, including CIBO (Council of Industrial Boiler Owners) and EEI USWAG (Edison Electric Institute Utility Solid Waste Activities Group). The EERC cooperated and coordinated with DOE CCT contractors and industry groups to provide the most accurate and complete data on IGCC and PFBC by-products, although these technologies are only now being demonstrated on the commercial scale through the DOE CCT program.

  18. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect (OSTI)

    Gregory J. McCarthy; Dean G. Grier

    1998-09-01T23:59:59.000Z

    The goals of the project are two-fold: (1) to upgrade semi-quantitative X-ray diffraction (QXRD) methods presently used in analyzing complex coal combustion by-product (CCB) systems, with the quantitative Rietveld method, and (2) to apply this method to a set of by-product materials that have been disposed or utilized for a long period (5 years or more) in contact with the natural environment, to further study the nature of CCB diagenesis. The project is organized into three tasks to accomplish these two goals: (1) thorough characterization of a set of previously analyzed disposed by-product materials, (2) development of a set of CCB-specific protocols for Rietveld QXRD, and (3) characterization of an additional set of disposed CCB materials, including application of the protocols for Rietveld QXRD developed in Task 2.

  19. Hydrogen and Fuel Cells - Refining the Message Initiating a National Dialogue and Educational Agenda

    E-Print Network [OSTI]

    Eggert, Anthony; Kurani, Kenneth S; Turrentine, Tom; Ogden, Joan M; Sperling, Dan; Winston, Emily

    2005-01-01T23:59:59.000Z

    April 1, 2005 Hydrogen and Fuel Cells – Refining the MessageHydrogen and Fuel Cells – Refining the Message Initiating athe communication problem. Hydrogen and fuel cells have now

  20. E-Print Network 3.0 - amerya petroleum refining Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ) Petroleum Refining Efficiency: 150 ppm S RFG with MTBE: GBS (d) Petroleum Refining... Eficiency: ... Source: Argonne National Laboratory - GREET Model Project Collection:...

  1. Iterative model-building, structure refinement, and density modification with the PHENIX AutoBuild Wizard

    E-Print Network [OSTI]

    Terwilliger, T. C.; Los Alamos National Laboratory, Mailstop M888, Los Alamos, NM 87545, USA; Lawrence Berkeley National Laboratory, One Cyclotron Road, Building 64R0121, Berkeley, CA 94720, USA; Department of Haematology, University of Cambridge, Cambridge CB2 0XY, England

    2008-01-01T23:59:59.000Z

    Iterative model-building, structure refinement, and densitytool for iterative model- building, structure refinement andusing RESOLVE or TEXTAL model- building, RESOLVE statistical

  2. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    S O N D 0 10 20 30 40 50 60 70 1995 Cents per Gallon Excluding Taxes Retail < or 1% Wholesale < or 1% Retail > 1% Wholesale > 1% 7. U.S. Refiner Residual Fuel Oil Prices and...

  3. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    150.0 2,026.7 W W 234.5 161.7 - 396.3 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  4. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    253.2 2,222.4 W W 206.4 134.3 - 340.7 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  5. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    150.0 2,026.7 W W 234.5 161.7 - 396.3 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  6. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    253.2 2,222.4 W W 206.4 134.3 - 340.7 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  7. Consensus Clustering Algorithms: Comparison and Refinement Andrey Goder

    E-Print Network [OSTI]

    Filkov, Vladimir

    -deterministic clustering algorithms, e.g. K-means, are sensitive to the choice of the initial seed clusters; running K-meansConsensus Clustering Algorithms: Comparison and Refinement Andrey Goder Vladimir Filkov Computer

  8. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Retail Volumes 1995 Annual Averages Motor Gasoline No. 2 Distillate Propane Kero-jet Residual Fuel Oil Other 39.1% 17.4% 2.2% 32.0% 8.1% 1.1% Energy Information...

  9. Japan`s refiner/marketers headed for major shakeout

    SciTech Connect (OSTI)

    NONE

    1996-08-26T23:59:59.000Z

    Japan`s downstream oil industry is in a state of crisis and headed for a major shakeout. The major catalyst for this was a dramatic deregulation step during April 1996 that allowed refined petroleum product imports by non-refiners. The move, together with a sharp drop in refining margins, falling retail gasoline prices, and a service station sector on the brink of collapse, are all leading to massive changes in the way the country`s refiners and marketers do business. This paper reviews the collapse of corporate profits during this period of deregulation; the development of a new price system geared toward bringing the prices of gasoline, fuel oil, and kerosene into line with each other to offset the fall in gasoline prices; and industry restructuring including mergers, acquisitions, and marketing consolidation. The paper then makes predictions on the outcome of these changes on the Japanese oil industry.

  10. Polygons in Buildings and their Refined Side Lengths

    E-Print Network [OSTI]

    Kapovich, Michael; Leeb, Bernhard; Millson, John J.

    2009-01-01T23:59:59.000Z

    1999. [Bro] K. Brown, Buildings, Springer, 1989. [BuBI] D.AMS, 2001. [D] M. Davis, Buildings are CAT(0), in “Geometryat Springerlink.com POLYGONS IN BUILDINGS AND THEIR REFINED

  11. Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments by providing

    E-Print Network [OSTI]

    Lovley, Derek

    Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments to simulate the degradation of aromatic hydrocarbons in anaerobic contaminated sediments was investigated as the sole electron acceptor. Providing graphite electrodes as an electron acceptor in hydrocarbon

  12. UV RESONANCE W A N SPECTROSCOPY: A NEW TECHNIQUE FOR SPECIATION OF AROMATICS IN COMPLEX MATRICES.

    E-Print Network [OSTI]

    Asher, Sanford A.

    UV RESONANCE W A N SPECTROSCOPY: A NEW TECHNIQUE FOR SPECIATION OF AROMATICS IN COMPLEX MATRICES resonance Raman spectroscopy ( 1). appears to be uniquely suited for studies of aromatic species in fuels

  13. Steps taken at Malelane refinery to improve refined sugar quality

    E-Print Network [OSTI]

    M Moodley; Pm Schorn

    1997-01-01T23:59:59.000Z

    The refinery at Malelane has in the past produced refined sugar for the consumer market. A decision was taken by the management of Transvaal Sugar (TSB) to produce a quality of refined sugar that would also be acceptable to the industrial and the export markets. The processes that were evaluated and implemented at the Malelane refinery during the past three seasons to achieve this objective, are described.

  14. Development of genetically engineered bacteria for production of selected aromatic compounds

    DOE Patents [OSTI]

    Ward, Thomas E. (Idaho Falls, ID); Watkins, Carolyn S. (Idaho Falls, ID); Bulmer, Deborah K. (Henderson, NV); Johnson, Bruce F. (Scotia, NY); Amaratunga, Mohan (Clifton Park, NY)

    2001-01-01T23:59:59.000Z

    The cloning and expression of genes in the common aromatic pathway of E. coli are described. A compound for which chorismate, the final product of the common aromatic pathway, is an anabolic intermediate can be produced by cloning and expressing selected genes of the common aromatic pathway and the genes coding for enzymes necessary to convert chorismate to the selected compound. Plasmids carrying selected genes of the common aromatic pathway are also described.

  15. No-carrier-added (NCA) aryl ([sup 18]F) fluorides via the nucleophilic aromatic substitution of electron rich aromatic rings

    DOE Patents [OSTI]

    Yushin Ding; Fowler, J.S.; Wolf, A.P.

    1993-10-19T23:59:59.000Z

    A method for synthesizing no-carrier-added (NCA) aryl [.sup.18 F] fluoride substituted aromatic aldehyde compositions bearing an electron donating group is described. The method of the present invention includes the step of reacting aromatic nitro aldehydes having a suitably protected hydroxyl substitutent on an electron rich ring. The reaction is The U.S. Government has rights in this invention pursuant to Contract Number DE-AC02-76CH00016, between the U.S. Department of Energy and Associated Universities Inc.

  16. Succinic Acid Production with Reduced By-Product Formation in the

    E-Print Network [OSTI]

    Succinic Acid Production with Reduced By-Product Formation in the Fermentation; accepted 13 July 2000 Abstract: Succinic acid was produced by fermentation of Anaerobiospirillum-product acetic acid. The gram ratio of suc- cinic acid to acetic acid was 25.8:1, which is 6.5 times higher than

  17. Isomer discrimination of polycyclic aromatic hydrocarbons in the Murchison meteorite by resonant ionization

    E-Print Network [OSTI]

    de Vries, Mattanjah S.

    Isomer discrimination of polycyclic aromatic hydrocarbons in the Murchison meteorite by resonant between isomers of polycyclic aromatic hydrocarbons in the Murchison meteorite. We measured the 2C-R2PI: Resonant ionization; Jet cooling; Mass spectrometry; Polycyclic aromatic hydrocarbons; Murchison meteorite

  18. Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri

    E-Print Network [OSTI]

    McFall-Ngai, Margaret

    Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri So Polycyclic aromatic hydrocarbons a b s t r a c t Effects of individual petroleum hydrocarbons hydrocarbons, including benzene and its derivatives and polycyclic aromatic hydrocarbons (PAHs), were chosen

  19. Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model of solid polycyclic aromatic hydrocarbons in water. For this purpose, we first validate our methodology for fluid phase equilibria predictions of aromatic hydrocarbons and gas (CO2, C2H6) mixtures. Finally, we

  20. Aggregation Behavior of Two Asphaltenic Fractions in Aromatic Solvents

    E-Print Network [OSTI]

    Loh, Watson

    Aggregation Behavior of Two Asphaltenic Fractions in Aromatic Solvents Rahoma S. Mohamed* and Anto. The results indicated possible asphaltene aggregation as well as the probable existence of critical micelle fraction. Average molecular areas for asphaltenes adsorbed at different interfaces estimated from surface

  1. UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices

    E-Print Network [OSTI]

    . Clemett,3 Richard N. Zare3 Polycyclic aromatic hydrocarbons (PAHs) in water ice were exposed to ultra meteorites. Hydrogen and deu- terium atoms exchange readily between the PAHs and the ice, which may explain abundant and widespread class of carbon-car- rying gaseous species is believed to be PAHs (3­5). In dense

  2. Desorption Kinetics for Field-Aged Polycyclic Aromatic Hydrocarbons

    E-Print Network [OSTI]

    Rockne, Karl J.

    Harbor Estuary. Desorption kinetics for PAHs with a log octanol- water partition coefficient greater than This study considers desorption kinetics for 12 field-aged polycyclic aromatic hydrocarbons (PAHs) desorbing 6 were well- described by a one-domain diffusion model that assumes that PAHs are initially

  3. Biodegradation of Bicyclic and Polycyclic Aromatic Hydrocarbons in

    E-Print Network [OSTI]

    Rockne, Karl J.

    solubility of oxygen in water. Therefore, our present understanding of PAH degradation in aerobic polycyclic aromatic hydrocarbons (PAHs) are known to be biodegraded under aerobic conditions, most contaminated sediments are anaerobic. With recent results demonstrating that some bicyclics and PAHs can

  4. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31T23:59:59.000Z

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two

  5. Adaptive mesh refinement for shocks and material interfaces

    SciTech Connect (OSTI)

    Dai, William Wenlong [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    There are three kinds of adaptive mesh refinement (AMR) in structured meshes. Block-based AMR sometimes over refines meshes. Cell-based AMR treats cells cell by cell and thus loses the advantage of the nature of structured meshes. Patch-based AMR is intended to combine advantages of block- and cell-based AMR, i.e., the nature of structured meshes and sharp regions of refinement. But, patch-based AMR has its own difficulties. For example, patch-based AMR typically cannot preserve symmetries of physics problems. In this paper, we will present an approach for a patch-based AMR for hydrodynamics simulations. The approach consists of clustering, symmetry preserving, mesh continuity, flux correction, communications, management of patches, and load balance. The special features of this patch-based AMR include symmetry preserving, efficiency of refinement across shock fronts and material interfaces, special implementation of flux correction, and patch management in parallel computing environments. To demonstrate the capability of the AMR framework, we will show both two- and three-dimensional hydrodynamics simulations with many levels of refinement.

  6. US refiners choose variety of routes to MTBE

    SciTech Connect (OSTI)

    Rhodes, A.K.

    1992-09-07T23:59:59.000Z

    This paper reports that refiners and merchant manufacturers in the U.S. are gearing up to produce the large volumes of methyl tertiary butyl ether (MTBE) needed to comply with oxygenated gasoline requirements. The 1990 U.S. Clean Air Act Amendments specify that, as of the first of this coming November, gasoline containing a minimum of 2.7 wt % oxygen must be sold in 39 CO-nonattainment cities. Refiners and others are scurrying to bring MTBE capacity on line in time to meet this requirement. Many U.S. refiners already have some operating MTBE capacity, but this will not be nearly enough to meet the looming increase in demand. As a result, additional capacity is being constructed worldwide.

  7. Numerical solution of plasma fluid equations using locally refined grids

    SciTech Connect (OSTI)

    Colella, P., LLNL

    1997-01-26T23:59:59.000Z

    This paper describes a numerical method for the solution of plasma fluid equations on block-structured, locally refined grids. The plasma under consideration is typical of those used for the processing of semiconductors. The governing equations consist of a drift-diffusion model of the electrons and an isothermal model of the ions coupled by Poisson's equation. A discretization of the equations is given for a uniform spatial grid, and a time-split integration scheme is developed. The algorithm is then extended to accommodate locally refined grids. This extension involves the advancement of the discrete system on a hierarchy of levels, each of which represents a degree of refinement, together with synchronization steps to ensure consistency across levels. A brief discussion of a software implementation is followed by a presentation of numerical results.

  8. The US petroleum refining industry in the 1980's

    SciTech Connect (OSTI)

    Not Available

    1990-10-11T23:59:59.000Z

    As part of the EIA program on petroleum, The US Petroleum Refining Industry in the 1980's, presents a historical analysis of the changes that took place in the US petroleum refining industry during the 1980's. It is intended to be of interest to analysts in the petroleum industry, state and federal government officials, Congress, and the general public. The report consists of six chapters and four appendices. Included is a detailed description of the major events and factors that affected the domestic refining industry during this period. Some of the changes that took place in the 1980's are the result of events that started in the 1970's. The impact of these events on US refinery configuration, operations, economics, and company ownership are examined. 23 figs., 11 tabs.

  9. Ambient aromatic hydrocarbon measurements at Welgegund, South Africa

    SciTech Connect (OSTI)

    Jaars, K.; Beukes, J. P.; van Zyl, P. G.; Venter, A. D.; Josipovic, M.; Pienaar, J. J.; Vakkari, Ville; Aaltonen, H.; Laakso, H.; Kulmala, M.; Tiitta, P.; Guenther, Alex B.; Hellen, H.; Laakso, L.; Hakola, H.

    2014-07-11T23:59:59.000Z

    Aromatic hydrocarbons are associated with direct adverse human health effects and can have negative impacts on ecosystems due to their toxicity, as well as indirect negative effects through the formation of tropospheric ozone and secondary organic aerosol that affect human health, crop production and regional climate. Measurements were conducted at the Welgegund measurement station (South Africa) that is considered to be a regionally representative background site. However, the site is occasionally impacted by plumes from major anthropogenic source regions in the interior of South Africa, which include the western Bushveld Igneous Complex (e.g. platinum, base metal and ferrochrome smelters), the eastern Bushveld Igneous Complex (platinum and ferrochrome smelters), the Johannesburg-Pretoria metropolitan conurbation (>10 million people), the Vaal Triangle (e.g. petrochemical and industries), the Mpumalanga Highveld (e.g. coal-fired power plants and petrochemical industry) and also a region of anti-cyclonic recirculation of air mass over the interior of South Africa. The aromatic hydrocarbon measurements were conducted with an automated sampler on Tenax-TA and Carbopack-B adsorbent tubes with heated inlet for one year. Samples were collected twice a week for two hours during daytime and two hours 1 during night-time. A thermal desorption unit, connected to a gas chromatograph and a mass 2 selective detector was used for sample preparation and analysis. Results indicated that the 3 monthly median total aromatic hydrocarbon concentrations ranged between 0.01 to 3.1 ppb. 4 Benzene levels did not exceed local air quality standards. Toluene was the most abundant 5 species, with an annual median concentration of 0.63 ppb. No statistically significant 6 differences in the concentrations measured during daytime and night-time were found and no distinct seasonal patterns were observed. Air mass back trajectory analysis proved that the lack of seasonal cycles could be attributed to patterns determining the origin of the air masses sampled. Aromatic hydrocarbon concentrations were in general significantly higher in air masses that passed over anthropocentrically impacted regions. Interspecies correlations and ratios gave some indications of the possible sources for the different aromatic hydrocarbons in the source regions defined in the paper. The highest contribution of aromatic hydrocarbon concentrations to ozone formation potential was also observed in plumes passing over anthropocentrically impacted regions.

  10. Trends in heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II.

    1992-07-01T23:59:59.000Z

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10{degrees} to 20{degrees} API gravity) production in California has increased from 20% of the state's total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation's energy production and refining capability. California is the recipient and refines most of Alaska's 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources.

  11. Trends in heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II

    1992-07-01T23:59:59.000Z

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10{degrees} to 20{degrees} API gravity) production in California has increased from 20% of the state`s total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation`s energy production and refining capability. California is the recipient and refines most of Alaska`s 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources.

  12. Sulfur by-product formation in the Stretford process. Topical report

    SciTech Connect (OSTI)

    Trofe, T.W.; DeBerry, D.W.

    1993-09-01T23:59:59.000Z

    Liquid redox sulfur recovery processes remove H2S from sour gas streams and produce elemental sulfur for sale or disposal. The Stretford Process is one of the oldest commercial liquid redox processes and it is based on a vanadium and anthraquinone redox system. Improvements in the operability and reliability of the Stretford process would be beneficial to the process user. The report presents results of research focused on developing an understanding of the process parameters and factors that impact sulfur by-product formation (e.g., sodium thiosulfate and sodium sulfate) in the Stretford process. The information in the report can help current Stretford plant process users better understand the operations of their plants, especially with regards to sulfur by-product formation and control strategies.

  13. The utilization of flue gas desulfurization waste by-products in construction brick

    E-Print Network [OSTI]

    Berryman, Charles Wayne

    1992-01-01T23:59:59.000Z

    APPENDIX D. TEST PROCEDURES APPENDIX E. CONVERSION TABLES VITA 85 90 93 96 99 LIST OF FIGURES Figure Page Model for FGD Waste By-Product Research Unconfined Compressive Strength for Fly Ash Mixed with Various Inductions of Portland Cement 15... properties such as weight, durability, strength, density, etc. Varying mixes of bottom ash, fly ash, portland cement, and sand will be tested for possible enhancement of the hemihydrate. Also, a mix design that best utilizes all the waste by...

  14. THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS

    SciTech Connect (OSTI)

    Ricca, Alessandra [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Allamandola, Louis J., E-mail: Alessandra.Ricca-1@nasa.gov, E-mail: Charles.W.Bauschlicher@nasa.gov [Space Science Division, Mail Stop 245-6, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

    2013-10-10T23:59:59.000Z

    The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

  15. Analytic technique measures aromatics in soil and water

    SciTech Connect (OSTI)

    Roy, K.A.

    1990-12-01T23:59:59.000Z

    This paper reports on a technique for detecting aromatic compounds in soil and water. The technique traces its roots to a chemical reaction discovered in 1877. The reaction is an organic synthesis process that has been harnessed for the production of high-octane gasoline, synthetic rubber, plastics and synthetic detergents. More than a century later the same chemistry is used as the basis for an analytical technique that quantifies contamination caused by products.

  16. Long-Term Column Leaching of Phase II Mercury Control Technology By-Products

    SciTech Connect (OSTI)

    Schroeder, K.T.; Cardone, C.R.; White, Fredrick; Rohar, P.C.; Kim, A.G

    2007-07-01T23:59:59.000Z

    An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. The stability of mercury and any co-captured elements in the by-products could have a large economic impact if it reduced by-product sales or increasing their disposal costs. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed continuous leaching of a select subset of the available sample pairs using four leachants: water (pH=5.7), dilute sulfuric acid (pH=1.2), dilute acetic acid (pH=2.9), and sodium carbonate (pH=11.1). This report describes results obtained for mercury, arsenic, and selenium during the 5-month leaching experiments.

  17. CHARACTERIZATION OF COAL COMBUSTION BY-PRODUCTS FOR THE RE-EVOLUTION OF MERCURY INTO ECOSYSTEMS

    SciTech Connect (OSTI)

    J.A. Withum; R.M. Statnick

    2001-09-01T23:59:59.000Z

    EPA and state environmental agencies are suggesting that mercury (Hg) in coal combustion by-products is re-emitted into local ecosystems by additional processing to final products (i.e., wallboard, etc.), by dissolution into groundwater, or by reactions with anaerobic bacteria. This perception may limit the opportunities to use coal combustion by-products in recycle/reuse applications. In this program, CONSOL Energy is conducting a comprehensive sampling and analytical program to address this concern. If the results of this work demonstrate that re-emissions of Hg from waste disposal and by-product utilization are over-stated, additional regulations regarding coal combustion, waste disposal, and waste material utilization will not be required. This will result in continued low energy cost that is beneficial to the national economy and stability of local economies that are dependent on coal. In this quarter, laboratory equipment was assembled and blank test runs were made, manufactured aggregate and spray dryer ash samples were collected and leached, and fly ash and FGD slurry samples from an Ohio bituminous coal-fired utility were collected for leaching.

  18. Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation 

    E-Print Network [OSTI]

    Adegoke, Adesola Ayodeji

    2006-10-30T23:59:59.000Z

    The Gas-to-liquids (GTL) processes produce a large fraction of by-products whose disposal or handling ordinarily becomes a cost rather than benefit. As an alternative strategy to market stranded gas reserves, GTL...

  19. Time Critical Isosurface Refinement And Smoothing V. Pascucci

    E-Print Network [OSTI]

    Texas at Austin, University of

    the global geometry of the embedding (no self- intersections) of any approximated level of detail: (i) a progressive al- gorithm that builds a multi-resolution surface by successive refine- ments so of the U.S. Depart- ment of Energy by University of California Lawrence Livermore National Laboratory under

  20. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1996 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  1. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    Gasoline and Diesel Fuel Update (EIA)

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1995 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  2. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1997 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  3. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    71.8 W 70.5 78.9 W 76.0 83.6 W 69.2 75.2 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  4. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    W 68.4 70.8 W W 78.6 W 85.7 81.8 W 69.3 73.8 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  5. Refinement of the One-Copy Serializable Correctness Criterion

    E-Print Network [OSTI]

    Muńoz, Francesc

    Refinement of the One-Copy Serializable Correctness Criterion M. I. Ruiz-Fuertes, F. D. Mu~noz-Esco. Mu~noz-EscoŽi Instituto TecnolŽogico de InformŽatica Universidad PolitŽecnica de Valencia Camino de

  6. Electron beam melting and refining state of the art 1995

    SciTech Connect (OSTI)

    Bakish, R. [ed.

    1995-12-31T23:59:59.000Z

    This is the proceedings of the Electron Beam Melting and Refining - State of the Art 1995 Conference. It contains 23 of the 30 scheduled papers. Papers cover an array of electron beam melting applications, from industrial plating of metal strip, through government work on manufacturing and processing fissile alloys. Separate abstracts have been prepared for articles from this proceedings.

  7. Refining Hygienic Macros for Modules and Separate Compilation Matthias Blume

    E-Print Network [OSTI]

    Blume, Matthias

    Refining Hygienic Macros for Modules and Separate Compilation Matthias Blume Department of Computer of the assumptions hygienic macro systems are based on. We will investigate how these assumptions have to be changed, and the consequences for the construction of hygienic macro expanders. Macro expansion algorithms rely on their ability

  8. Note on refined topological vertex, Jack polynomials and instanton counting

    E-Print Network [OSTI]

    Jianfeng Wu

    2010-12-10T23:59:59.000Z

    In this article, we calculated the refined topological vertex for the one parameter case using the Jack symmetric functions. Also, we obtain the partition function for elliptic N=2 models, the results coincide with those of Nekrasov instanton counting partition functions for the $N=2^{\\ast}$ theories.

  9. #PRL --A Proof Refinement Calculus for Classical Reasoning

    E-Print Network [OSTI]

    Kreitz, Christoph

    #”PRL -- A Proof Refinement Calculus for Classical Reasoning in Computational Type Theory Nuria, 14482 Potsdam, Germany {brede,kreitz}@cs.uni­potsdam.de Abstract. We present a hybrid proof calculus #”PRL to con­ structive proofs and show that the restriction of #”PRL to ”­safe proof terms is sound

  10. PRL A Proof Refinement Calculus for Classical Reasoning

    E-Print Network [OSTI]

    Kreitz, Christoph

    ”PRL ­ A Proof Refinement Calculus for Classical Reasoning in Computational Type Theory Nuria Brede, Germany {brede,kreitz}@cs.uni-potsdam.de Abstract. We present a hybrid proof calculus ”PRL that combines and show that the restriction of ”PRL to ”-safe proof terms is sound and complete for intuitionistic

  11. Refining 31 P nuclear magnetic resonance spectroscopy for marine

    E-Print Network [OSTI]

    Paytan, Adina

    Refining 31 P nuclear magnetic resonance spectroscopy for marine particulate samples: Storage 31 P nuclear magnetic resonance (NMR) spectroscopy has recently been used to characterize phosphorus.e., no storage, refrigeration, freezing, and oven-drying and grinding) prior to extraction for solution 31 P

  12. Department of Computing Stepwise Refinement in Event-B||CSP

    E-Print Network [OSTI]

    Doran, Simon J.

    in Event-B||CSP Part 1: Safety Steve Schneider, Helen Treharne and Heike Wehrheim March 12th 2011 #12;Stepwise Refinement in Event-B CSP Part 1: Safety Steve Schneider1 Helen Treharne1 Heike Wehrheim2 1, 2011 Contents 1 Introduction 3 2 CSP 3 2.1 Notation

  13. An accuracy study of mesh refinement on mapped grids

    E-Print Network [OSTI]

    Calhoun, Donna

    An accuracy study of mesh refinement on mapped grids D. Calhoun and R. J. LeVeque, October, 2003 on a highly skewed portion of a mapped grid. Smooth and shock-wave solutions to the Euler equations are used interface. Key words: gas dynamics, finite-volume, finite-difference, Cartesian grid, mapped grids

  14. The use of Fourier reverse transforms in crystallographic phase refinement

    SciTech Connect (OSTI)

    Ringrose, S.

    1997-10-08T23:59:59.000Z

    Often a crystallographer obtains an electron density map which shows only part of the structure. In such cases, the phasing of the trial model is poor enough that the electron density map may show peaks in some of the atomic positions, but other atomic positions are not visible. There may also be extraneous peaks present which are not due to atomic positions. A method for determination of crystal structures that have resisted solution through normal crystallographic methods has been developed. PHASER is a series of FORTRAN programs which aids in the structure solution of poorly phased electron density maps by refining the crystallographic phases. It facilitates the refinement of such poorly phased electron density maps for difficult structures which might otherwise not be solvable. The trial model, which serves as the starting point for the phase refinement, may be acquired by several routes such as direct methods or Patterson methods. Modifications are made to the reverse transform process based on several assumptions. First, the starting electron density map is modified based on the fact that physically the electron density map must be non-negative at all points. In practice a small positive cutoff is used. A reverse Fourier transform is computed based on the modified electron density map. Secondly, the authors assume that a better electron density map will result by using the observed magnitudes of the structure factors combined with the phases calculated in the reverse transform. After convergence has been reached, more atomic positions and less extraneous peaks are observed in the refined electron density map. The starting model need not be very large to achieve success with PHASER; successful phase refinement has been achieved with a starting model that consists of only 5% of the total scattering power of the full molecule. The second part of the thesis discusses three crystal structure determinations.

  15. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  16. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  17. Reduction of Aromatic Hydrocarbons by Zero-Valent Iron and Palladium Catalyst

    SciTech Connect (OSTI)

    Kim, Young-Hun; Shin, Won Sik; Ko, Seok-Oh; Kim, Myung-Chul

    2004-03-31T23:59:59.000Z

    Permeable reactive barrier (PRB) is an alternative technology for soil and groundwater remediation. Zero valent iron, which is the most popular PRB material, is only applicable to halogenated aliphatic organics and some heavy metals. The objective of this study was to investigate reductive dechlorination of halogenated compounds and reduction of non-halogenated aromatic hydrocarbons using zero valent metals (ZVMs) and catalysts as reactive materials for PRBs. A group of small aromatic hydrocarbons such as monochlorophenols, phenol and benzene were readily reduced with palladium catalyst and zero valent iron. Poly-aromatic hydrocarbons (PAHs) were also tested with the catalysts and zero valent metal combinations. The aromatic rings were reduced and partly reduced PAHs were found as the daughter compounds. The current study demonstrates reduction of aromatic compounds by ZVMs and modified catalysts and implicates that PRB is applicable not only for halogenated organic compounds but nonhalogenated aromatic compounds such as PAHs.

  18. aromatic hydrocarbon-degrading marine: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aromatic Hydrocarbons in Soil Microcosms: A Review CiteSeer Summary: Copyright 2001 Kansas State University Key words: bioremediation, denitrification, PAHs, sulfidogenesis...

  19. E-Print Network 3.0 - aromatic compounds progress Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... . 271 12;Although the spectra only give a qualitative analysis of the major types...

  20. E-Print Network 3.0 - aromatic blending compounds Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ring aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... . 271 12;Although the spectra only give a qualitative analysis of the major...

  1. E-Print Network 3.0 - aromatic organic compounds Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... . 271 12;Although the spectra only give a qualitative analysis of the major types...

  2. E-Print Network 3.0 - aromatic compounds effects Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... . 271 12;Although the spectra only give a qualitative analysis of the major types...

  3. E-Print Network 3.0 - aqueous polar aromatic Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Society. 1155 Sixteenth Summary: is diffusion of the aqueous amine into the oil phase, then the polyurea formed early should be rich in aromatic... diisocyanate...

  4. E-Print Network 3.0 - aromatic compounds Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... . 271 12;Although the spectra only give a qualitative analysis of the major types...

  5. E-Print Network 3.0 - aromatic compounds part Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ring aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... . 271 12;Although the spectra only give a qualitative analysis of the major...

  6. E-Print Network 3.0 - aromatic compounds derived Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ring aromatic compounds. 500 265 500 265 500 265 WAVELENGTH (nm) ARABIAN CRUDE LUBRICATING OIL... . 271 12;Although the spectra only give a qualitative analysis of the major...

  7. Bimetallic cleavage of aromatic C-H bonds by rare-earth-metal complexes

    E-Print Network [OSTI]

    Huang, W; Huang, W; Dulong, F; Khan, SI; Cantat, T; Diaconescu, PL

    2014-01-01T23:59:59.000Z

    of Aromatic C-H Bonds by Rare Earth Metal Complexes Wenliangone week prior to use. Rare earth metal oxides (scandium,

  8. aromatic hydrocarbon water-soluble: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    naturally into the environment by (more) Bobak, Deanna M. 2010-01-01 12 Zero kinetic energy photoelectron spectroscopy of polycyclic aromatic hydrocarbons. Open Access Theses and...

  9. aromatic hydrocarbon-degrading bacteria: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of complex aromatic organic matter. While concerns remain as to the organic purity of the aerogel collection medium and the thermal effects associated 212 Conversion of polycyclic...

  10. aromatic amine 2-amino-3-methyl-9h-pyrido: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the reactions of amines with aldehydes and with aromatic nitro - compounds in acetonitrile. Open Access Theses and Dissertations Summary: ??Kinetic and equilibrium studies of...

  11. aromatic amine p-anilinoaniline: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the reactions of amines with aldehydes and with aromatic nitro - compounds in acetonitrile. Open Access Theses and Dissertations Summary: ??Kinetic and equilibrium studies of...

  12. Development of miscella refining process for cottonseed oil-isopropyl alcohol system: laboratory-scale evaluations

    E-Print Network [OSTI]

    Chau, Chi-Fai

    1994-01-01T23:59:59.000Z

    A technologically feasible cottonseed oil-isopropyl alcohol (IPA) miscella refining process was developed to produce high quality cottonseed oil. Individual steps necessary to refine cottonseed oil-IPA miscella were determined and improved...

  13. WELDABILITY OF GRAIN-REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Morris Jr., J.W.

    2013-01-01T23:59:59.000Z

    of the Cryogenic Nickel Steels, WRC Bull, 205, May, 1975.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.E.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.

  14. Protein extraction in the refinement of Coastal Bermudagrass

    E-Print Network [OSTI]

    De La Rosa Perez, Luis Bernardo

    1992-01-01T23:59:59.000Z

    , phosphoric acid, gaseous hydrochloric acid, anhydrous ammonia and ethylendiamine (Chang et aL, 1981; Wylie and Steen, 1988). Also the use of organic solvents such as hexane or cadoxen ([Cd(ethylendiamine)3](OH)2, cadmium ethylendiamine) (Ladisch et al... and lignin. Integrated conversion of the entire "barrel of biomass" (also referred to as biomass refining), is essential to obtain good system economics. This study evaluated the use of the Ammonia Fiber Explosion (AFEX) process in an integrated conversion...

  15. Occurrence of chlorinated polynuclear aromatic hydrocarbons in tap water

    SciTech Connect (OSTI)

    Shiraishi, H.; Pilkington, N.H.; Otsuki, A.; Fuwa, K.

    1985-07-01T23:59:59.000Z

    Organic compounds in tap waters were extracted by a modified continuous liquid-liquid extractor and analyzed by computerized gas chromatography/mass spectrometry using a fused silica capillary column. The results indicate the presence of monochlorinated derivatives of naphthalene, dibenzofuran, fluorene, fluorenone, phenanthrene, and fluoranthene and dichlorinated derivatives of naphthalene, phenanthrene, and fluoranthene. The parent polynuclear aromatic hydrocarbons (PAHs) and their oxygenated derivatives such as fluorenone and anthraquinone were also found. It was demonstrated that chlorinated PAHs (Cl-PAHs) were really present in tap waters at 10/sup -1/-10/sup -2/ ng/L levels.

  16. The relative reactivity of formic esters with aromatic amines

    E-Print Network [OSTI]

    Markley, Max C.

    1922-01-01T23:59:59.000Z

    .MARKLEY I Vies* S ma y c . l k f c V i M t s RDQOSS 38M30 PREFACE. The purpose of this thesis was to determine the relative reactivity between aromatic amines and the esters of formic acid.It was proposed to first: deter­ mine the reactivity... be given Br .Ray Q,.Brewster , the director of this work, for his help and directions for carrying out this work, and to Br.Prank B.Bains for his kind assistance in many ways. 1.Broil,Journal fur Practische Chemie,1875,vol. 12,page 208. ( 2 ) TABLE...

  17. University of Delaware | Catalysis Center for Energy Innovation | Aromatics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch Thrust Green Aromatics

  18. EWO Mee'ng September 2012 Petrobras Refining Decision-Making Design

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    & Algorithm Thesis Prospectus Mathematical Modeling for Strategic and Investment Planning in the Oil-Refining Industry Brenno C. Menezes, Lincoln F. Moro Refining Op7miza7on PETROBRAS Petróleo SEWO Mee'ng ­ September 2012 Petrobras Refining Decision-Making Design Thesis Formulation

  19. Refinement and verification of concurrent systems specified in ObjectZ and CSP

    E-Print Network [OSTI]

    Smith, Graeme

    Refinement and verification of concurrent systems specified in Object­Z and CSP Graeme Smith­Z and CSP. A common semantic basis for the two languages enables a unified method of refinement to be used, based upon CSP refinement. To enable state­based techniques to be used for the Object­Z components

  20. Refined similarity hypotheses in shell models of turbulence

    E-Print Network [OSTI]

    Emily S. C. Ching; H. Guo; T. S. Lo

    2008-04-16T23:59:59.000Z

    A major challenge in turbulence research is to understand from first principles the origin of anomalous scaling of the velocity fluctuations in high-Reynolds-number turbulent flows. One important idea was proposed by Kolmogorov [J. Fluid Mech. {\\bf 13}, 82 (1962)], which attributes the anomaly to the variations of the locally averaged energy dissipation rate. Kraichnan later pointed out [J. Fluid Mech. {\\bf 62}, 305 (1973)] that the locally averaged energy dissipation rate is not an inertial-range quantity and a proper inertial-range quantity would be the local energy transfer rate. As a result, Kraichnan's idea attributes the anomaly to the variations of the local energy transfer rate. These ideas, generally known as refined similarity hypotheses, can also be extended to study the anomalous scaling of fluctuations of an active scalar, like the temperature in turbulent convection. In this paper, we examine the validity of these refined similarity hypotheses and their extensions to an active scalar in shell models of turbulence. We find that Kraichnan's refined similarity hypothesis and its extension are valid.

  1. U. S. refiners move into another challenging technical era

    SciTech Connect (OSTI)

    Hall, J.R. (Ashland Oil Inc., Ashland, KY (US))

    1991-10-21T23:59:59.000Z

    With the transition to unleaded gasoline scarcely behind us, another new era is dawning for the U.S. refiner. No one yet knows the exact configuration of the refinery of the future and no two refineries are likely to adapt in exactly the same way. What is certain, however, is that by the year 2000, refineries will be more technologically advanced, their products will be more environmentally acceptable, and their operators will be more highly trained. The typical U.S. refinery in the year 2000 will be located at an existing refinery site because economic and environmental considerations will make it impossible to build new grassroots capacity. As a result of the Clean Air act, the refinery of tomorrow will produce cleaner fuels The entire U.S. gasoline pool will likely be reformulated. Most of the diesel fuel pool will consist of ultralow-sulfur product. And jet fuel-which is experiencing rapid demand growth-will be an increasingly important product. Many existing refining process will remain in use, but they will be more efficient and more technologically advanced. Energy efficiency will be a primary concern, as refiners seek to combat ever-increasing crude oil costs and refinery operating expenses. The refinery of the future also will be much more environmentally acceptable. The article is a closer look at the refinery of the future.

  2. CONSTRAINED-TRANSPORT MAGNETOHYDRODYNAMICS WITH ADAPTIVE MESH REFINEMENT IN CHARM

    SciTech Connect (OSTI)

    Miniati, Francesco [Physics Department, Wolfgang-Pauli-Strasse 27, ETH-Zuerich, CH-8093 Zuerich (Switzerland); Martin, Daniel F., E-mail: fm@phys.ethz.ch, E-mail: DFMartin@lbl.gov [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States)

    2011-07-01T23:59:59.000Z

    We present the implementation of a three-dimensional, second-order accurate Godunov-type algorithm for magnetohydrodynamics (MHD) in the adaptive-mesh-refinement (AMR) cosmological code CHARM. The algorithm is based on the full 12-solve spatially unsplit corner-transport-upwind (CTU) scheme. The fluid quantities are cell-centered and are updated using the piecewise-parabolic method (PPM), while the magnetic field variables are face-centered and are evolved through application of the Stokes theorem on cell edges via a constrained-transport (CT) method. The so-called multidimensional MHD source terms required in the predictor step for high-order accuracy are applied in a simplified form which reduces their complexity in three dimensions without loss of accuracy or robustness. The algorithm is implemented on an AMR framework which requires specific synchronization steps across refinement levels. These include face-centered restriction and prolongation operations and a reflux-curl operation, which maintains a solenoidal magnetic field across refinement boundaries. The code is tested against a large suite of test problems, including convergence tests in smooth flows, shock-tube tests, classical two- and three-dimensional MHD tests, a three-dimensional shock-cloud interaction problem, and the formation of a cluster of galaxies in a fully cosmological context. The magnetic field divergence is shown to remain negligible throughout.

  3. Potential for by-product recovery in geothermal energy operations issue paper

    SciTech Connect (OSTI)

    None

    1982-07-01T23:59:59.000Z

    This document identifies and discusses the significant issues raised by the idea of recovering useful by-products from wastes (primarily spent brine) generated during geothermal power production. The physical availability of numerous valuable materials in geothermal brines has captured the interest of geothermal resource developers and other parties ever since their presence was known. The prospects for utilizing huge volumes of highly-saline geothermal brines for electricity generation in the Imperial Valley of California have served to maintain this interest in both private sector and government circles.

  4. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J. [Magnitogorsk Integrated Iron and Steel Works, (Russian Federation); Gross, M. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  5. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10T23:59:59.000Z

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  6. LARGE ABUNDANCES OF POLYCYCLIC AROMATIC HYDROCARBONS IN TITAN'S UPPER ATMOSPHERE

    SciTech Connect (OSTI)

    Lopez-Puertas, M.; Funke, B.; Garcia-Comas, M. [Instituto de Astrofisica de Andalucia (CSIC), E-18080 Granada (Spain); Dinelli, B. M. [ISAC-CNR, I-40129 Bologna (Italy); Adriani, A.; D'Aversa, E. [IAPS-INAF, I-00133 Rome (Italy); Moriconi, M. L. [ISAC-CNR, I-00133 Rome (Italy); Boersma, C.; Allamandola, L. J., E-mail: puertas@iaa.es [NASA Ames Research Center, Moffett Field, CA 94035-1000 (United States)

    2013-06-20T23:59:59.000Z

    In this paper, we analyze the strong unidentified emission near 3.28 {mu}m in Titan's upper daytime atmosphere recently discovered by Dinelli et al. We have studied it by using the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbons (PAHs), after absorbing UV solar radiation, are able to emit strongly near 3.3 {mu}m. By using current models for the redistribution of the absorbed UV energy, we have explained the observed spectral feature and have derived the vertical distribution of PAH abundances in Titan's upper atmosphere. PAHs have been found to be present in large concentrations, about (2-3) Multiplication-Sign 10{sup 4} particles cm{sup -3}. The identified PAHs have 9-96 carbons, with a concentration-weighted average of 34 carbons. The mean mass is {approx}430 u; the mean area is about 0.53 nm{sup 2}; they are formed by 10-11 rings on average, and about one-third of them contain nitrogen atoms. Recently, benzene together with light aromatic species as well as small concentrations of heavy positive and negative ions have been detected in Titan's upper atmosphere. We suggest that the large concentrations of PAHs found here are the neutral counterpart of those positive and negative ions, which hence supports the theory that the origin of Titan main haze layer is located in the upper atmosphere.

  7. Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of

    E-Print Network [OSTI]

    Canberra, University of

    Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay of aromatic hydrocarbons in coastal waters, using solvent extraction and fluorescence emission analysis, shows and the Yarra River estuary. Introduction Pollution of the marine environment by petroleum hydrocarbons

  8. Synthesis of condensed phases containing polycyclic aromatic hydrocarbons fullerenes and nanotubes

    DOE Patents [OSTI]

    Reilly, Peter T. A.

    2004-10-19T23:59:59.000Z

    The invention relates to methods for producing polycyclic aromatic hydrocarbons, fullerenes, and nanotubes, comprising: a. heating at least one carbon-containing material to form a condensed phase comprising at least one polycyclic aromatic hydrocarbon; b. collecting at least some of the condensed phase; c. reacting the condensed phase to form fullerenes and/or nanotubes.

  9. Interfacial effects in a two-phase partitioning bioreactor: degradation of polycyclic aromatic hydrocarbons (PAHs)

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    Interfacial effects in a two-phase partitioning bioreactor: degradation of polycyclic aromatic) was examined in a two-phase partitioning bioreactor (TPPB). TPPBs are characterized by a cell Bioreactor; Hydrophobicity 1. Introduction Polycyclic aromatic hydrocarbons (PAHs), many of which possess

  10. Succinic Acid as a Byproduct in a Corn-based Ethanol Biorefinery

    SciTech Connect (OSTI)

    MBI International

    2007-12-31T23:59:59.000Z

    MBI endeavored to develop a process for succinic acid production suitable for integration into a corn-based ethanol biorefinery. The project investigated the fermentative production of succinic acid using byproducts of corn mill operations. The fermentation process was attuned to include raw starch, endosperm, as the sugar source. A clean-not-sterile process was established to treat the endosperm and release the monomeric sugars. We developed the fermentation process to utilize a byproduct of corn ethanol fermentations, thin stillage, as the source of complex nitrogen and vitamin components needed to support succinic acid production in A. succinogenes. Further supplementations were eliminated without lowering titers and yields and a productivity above 0.6 g l-1 hr-1was achieved. Strain development was accomplished through generation of a recombinant strain that increased yields of succinic acid production. Isolation of additional strains with improved features was also pursued and frozen stocks were prepared from enriched, characterized cultures. Two recovery processes were evaluated at pilot scale and data obtained was incorporated into our economic analyses.

  11. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  12. CHARACTERIZATION OF COAL COMBUSTION BY-PRODUCTS FOR THE RE-EVOLUTION OF MERCURY INTO ECOSYSTEMS

    SciTech Connect (OSTI)

    J.A. Withum; J.E. Locke; S.C. Tseng

    2005-03-01T23:59:59.000Z

    There is concern that mercury (Hg) in coal combustion by-products might be emitted into the environment during processing to other products or after the disposal/landfill of these by-products. This perception may limit the opportunities to use coal combustion by-products in recycle/reuse applications and may result in additional, costly disposal regulations. In this program, CONSOL conducted a comprehensive sampling and analytical program to include ash, flue gas desulfurization (FGD) sludge, and coal combustion by-products. This work is necessary to help identify potential problems and solutions important to energy production from fossil fuels. The program objective was to evaluate the potential for mercury emissions by leaching or volatilization, to determine if mercury enters the water surrounding an active FGD disposal site and an active fly ash slurry impoundment site, and to provide data that will allow a scientific assessment of the issue. Toxicity Characteristic Leaching Procedure (TCLP) test results showed that mercury did not leach from coal, bottom ash, fly ash, spray dryer/fabric filter ash or forced oxidation gypsum (FOG) in amounts leading to concentrations greater than the detection limit of the TCLP method (1.0 ng/mL). Mercury was detected at very low concentrations in acidic leachates from all of the fixated and more than half of the unfixated FGD sludge samples, and one of the synthetic aggregate samples. Mercury was not detected in leachates from any sample when deionized water (DI water) was the leaching solution. Mercury did not leach from electrostatic precipitator (ESP) fly ash samples collected during activated carbon injection for mercury control in amounts greater than the detection limit of the TCLP method (1.0 ng/mL). Volatilization tests could not detect mercury loss from fly ash, spray dryer/fabric filter ash, unfixated FGD sludge, or forced oxidation gypsum; the mercury concentration of these samples all increased, possibly due to absorption from ambient surroundings. Mercury loss of 18-26% was detected after 3 and 6 months at 100 F and 140 F from samples of the fixated FGD sludge. Water samples were collected from existing ground water monitoring wells around an active FGD disposal site (8 wells) and an active fly ash slurry impoundment (14 wells). These were wells that the plants have installed to comply with ground water monitoring requirements of their permits. Mercury was not detected in any of the water samples collected from monitoring wells at either site. A literature review concluded that coal combustion byproducts can be disposed of in properly designed landfills that minimize the potentially negative impacts of water intrusion that carries dissolved organic matter (DOM). Dissolved organic matter and sulfate-reducing bacteria can promote the transformation of elemental or oxidized mercury into methyl mercury. The landfill should be properly designed and capped with clays or similar materials to minimize the wet-dry cycles that promote the release of methylmercury.

  13. Land application uses for dry FGD by-products. Phase 1, [Annual report], December 1, 1991--November 30, 1992

    SciTech Connect (OSTI)

    Bigham, J.; Dick, W.; Forster, L.; Hitzhusen, F.; McCoy, E.; Stehouwer, R.; Traina, S.; Wolfe, W. [Ohio State Univ., Columbus, OH (United States); Haefner, R. [Geological Survey, Columbus, OH (United States). Water Resources Div.

    1993-04-01T23:59:59.000Z

    The 1990 amendments to the Clean Air Act have spurred the development of flue gas desulfurization (FGD) processes, several of which produce a dry, solid by-product material consisting of excess sorbent, reaction products containing sulfates and sulfites, and coal fly ash. Presently FGD by-product materials are treated as solid wastes and must be landfilled. However, landfill sites are becoming more scarce and tipping fees are constantly increasing. It is, therefore, highly desirable to find beneficial reuses for these materials provided the environmental impacts are minimal and socially acceptable. Phase 1 results of a 4 and 1/2 year study to demonstrate large volume beneficial uses of FGD by-products are reported. The purpose of the Phase 1 portion of the project was to characterize the chemical, physical, mineralogical and engineering properties of the FGD by-product materials obtained from various FGD technologies being developed in the state of Ohio. Phase 1 also involved the collection of baseline economic data related to the beneficial reuse of these FGD materials. A total of 58 samples were collected and analyzed. In summary Phase 1 results revealed that FGD by-product materials are essentially coal fly ash materials diluted with unreacted sorbent and reaction products. High volume beneficial reuses will depend on the economics of their substituting for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mines). Environmental constraints to the beneficial reuse of dry FGD byproduct materials, based on laboratory and leachate studies, seem to be less than for coal fly ash.

  14. Exact results on ABJ theory and the refined topological string

    E-Print Network [OSTI]

    Masazumi Honda; Kazumi Okuyama

    2014-07-22T23:59:59.000Z

    We study the partition function of the ABJ theory, which is the N=6 superconformal Chern-Simons matter theory with gauge group U(N)xU(N+M) and Chern-Simons levels (k,-k). We exactly compute the ABJ partition function on a three sphere for various k, M and N via the Fermi gas approach. By using these exact data, we show that the ABJ partition function is completely determined by the refined topological string on local P^1 x P^1, including membrane instanton effects in the M-theory dual.

  15. Minimally refined biomass fuel. [carbohydrate-water-alcohol mixture

    SciTech Connect (OSTI)

    Pearson, R.K.; Hirschfeld, T.B.

    1981-03-26T23:59:59.000Z

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water-solubilizes the carbohydrate; and the alcohol aids in the combustion of the carbohydrate and reduces the viscosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  16. Changing Trends in the Refining Industry (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    There have been some major changes in the U.S. refining industry recently, prompted in part by a significant decline in the quality of imported crude oil and by increasing restrictions on the quality of finished products. As a result, high-quality crudes, such as the West Texas Intermediate (WTI) crude that serves as a benchmark for oil futures on the New York Mercantile Exchange (NYMEX), have been trading at record premiums to the OPEC (Organization of the Petroleum Exporting Countries) Basket price.

  17. REFINING PROGRAM HELPS REENERGIZE NEBRASKA UPGRADES | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreakingMay 2015 < prevQuick Guide: Power PurchaseOwner's Role3REFINING PROGRAM

  18. Refining Bio-Oil alongside Petroleum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreakingMay 2015 < prevQuick Guide:U.N.JuneAs part of itsRefining Bio-Oil

  19. ITP Petroleum Refining: Petroleum Technology Vision 2020 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),Energy Petroleum Technology Vision 2020 ITP Petroleum Refining:

  20. Gas and Particulate Sampling of Airborne Polycyclic Aromatic Compounds

    SciTech Connect (OSTI)

    Lane, D.A.; Gundel, L.A.

    1995-10-01T23:59:59.000Z

    The denuder surfaces of the gas and particle (GAP) sampler (developed at the Atmospheric Environment Service of Environment Canada) have been modified by coating with XAD-4 resin, using techniques developed at Lawrence Berkeley National Laboratory (LBNL) for the lower capacity integrated organic vapor/particle sampler (IOVPS). The resulting high capacity integrated organic gas and particle sampler (IOGAPS) has been operated in ambient air at 16.7 L min{sup -1} for a 24-hour period in Berkeley, California, USA. Simultaneous measurements were made at the same collection rate with a conventional sampler that used a filter followed by two sorbent beds. Gas and particle partition measurements were determined for 13 polycyclic aromatic hydrocarbons (PAH) ranging from 2-ring to 6-ring species. The IOGAPS indicated a higher particle fraction of these compounds than did the conventional sampler, suggesting that the conventional sampler suffered from 'blow-off' losses from the particles collected on the filter.

  1. Simulated transport of polycyclic aromatic hydrocarbons in artificial streams

    SciTech Connect (OSTI)

    Bartell, S.M.; Landrum, P.F.; Giesy, J.P.; Leversee, G.J.

    1981-01-01T23:59:59.000Z

    A model was constructed to predict the pattern of flow and accumulation of three polycyclic aromatic hydrocarbons (PAH) (anthracene, naphthalene, and benzo(a)pyrene) in artificial streams located on the Savannah River Plant near Aiken, South Carolina. Predictions were based upon the premise that the fundamental chemistry of individual PAH contains useful information for predictive purposes. Model processes included volatilization, photolysis, sorption to sediments and particulates, and net accumulation by biota. Simulations of anthracene transport were compared to results of an experiment conducted in the streams. The model realistically predicted the concentration of dissolved anthracene through time and space. Photolytic degradation appeared to be a major pathway of anthracene flux from the streams.

  2. California refiners move smoothly into next phase of RFG

    SciTech Connect (OSTI)

    Schaffer, S. [ed.

    1996-05-01T23:59:59.000Z

    The California RFG program (CARB RFG) began at the refinery level in March, the terminal level in April and will begin being enforced at the retail level June 1. By all accounts, early implementation is proceeding smoothly, with prices for both gasoline and oxygenates remaining fairly steady. Analysts labeled the introduction of the world`s cleanest gasoline {open_quotes}a non-event{close_quotes}. By April 1, more than half of the retail gasoline stations in California had fully complying CARB RFG. With cumulative investments of more than $3 billion, California`s refiners will be looking to recapture as much of the cost in the marketplace as possible. The incremental cost of CARB RFG production over federal RFG is estimated by refiners to be about 10{cents}/gal, mainly due to the capital investments needed for hydrotreating to reduce sulfur levels. Early batches of fuel on the spot market sold for about 8{cents}/gal over conventional prices, about 4.5{cents}/gal above federal RFG, according to the Oil Price Information Service (OPIS).

  3. A refined model for characterizing x-ray multilayers

    SciTech Connect (OSTI)

    Oren, A.L.; Henke, B.L.

    1987-12-01T23:59:59.000Z

    The ability to quickly and accurately characterize arbitrary multilayers is very valuable for not only can we use the characterizations to predict the reflectivity of a multilayer for any soft x-ray wavelength, we also can generalize the results to apply to other multilayers of the same type. In addition, we can use the characterizations as a means of evaluating various sputtering environments and refining sputtering techniques to obtain better multilayers. In this report we have obtained improved characterizations for sample molybdenum-silicon and vanadium-silicon multilayers. However, we only examined five crystals overall, so the conclusions that we could draw about the structure of general multilayers is limited. Research involving many multilayers manufactured under the same sputtering conditions is clearly in order. In order to best understand multilayer structures it may be necessary to further refine our model, e.g., adopting a Gaussian form for the interface regions. With such improvements we can expect even better agreement with experimental values and continued concurrence with other characterization techniques. 18 refs., 30 figs., 7 tabs.

  4. Recovery of solvent and by-products from organosolv black liquor

    SciTech Connect (OSTI)

    Botello, J.I.; Gilarranz, M.A.; Rodriguez, F.; Oliet, M. [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica] [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica

    1999-09-01T23:59:59.000Z

    The recovery of alcohol and by-products from ethanol-water and methanol-water pulping liquors was studied. The recovery system proposed consists of three stages: black liquor flashing, lignin precipitation, and precipitation distillation of mother liquor. At the flash stage, 47 and 51% of the alcohol in the black liquor are recovered for ethanol and methanol processes, respectively. The lignin recovery yield at the precipitation stage is 67% for ethanol black liquor and 73% for methanol black liquor. The distillation of precipitation mother liquors enables recovery of 98% ethanol and 96% methanol from this stream as distillate, whereas the distillation residue contains significant amounts of sugars, furfural, and acetic acid that can be recovered. The study concludes with the overall mass balance for the recovery system proposed.

  5. Environmental chamber measurements of mercury flux from coal utilization by-products

    SciTech Connect (OSTI)

    Pekney, N.J.; Martello, D.V.; Schroeder, K.T.; Granite, E.J.

    2009-05-01T23:59:59.000Z

    An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7-day experiment averages ranging from -6.8 to 73 ng/m2 h for the fly ash samples and -5.2 to 335 ng/m2 h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

  6. The use of gypsum and a coal desulfurization by-product to ameliorate subsoil acidity for alfalfa growth

    E-Print Network [OSTI]

    Chessman, Dennis John

    2004-09-30T23:59:59.000Z

    the effectiveness of surface-applied gypsum and a flue gas desulfurization by-product for reducing the toxic effects of acid subsoils on alfalfa. The materials were applied at rates of 0, 5, 10, and 15 Mg ha-1. In addition, a glasshouse experiment was conducted...

  7. Task 1.13 - Data Collection and Database Development for Clean Coal Technology By-Product Characteristics and Management Practices

    SciTech Connect (OSTI)

    Debra F. Pflughoeft-Hassett

    1998-02-01T23:59:59.000Z

    U.S. Department of Energy Federal Energy Technology Center-Morgantown (DOE FETC) efforts in the areas of fossil fuels and clean coal technology (CCT) have included involvement with both conventional and advanced process coal conversion by-products. In 1993, DOE submitted a Report to Congress on "Barriers to the Increased Utilization of Coal Combustion Desulfurization Byproducts by Governmental and Commercial Sectors" that provided an outline of activities to remove the barriers identified in the report. DOE charged itself with participation in this process, and the work proposed in this document facilitates DOE's response to its own recommendations for action. The work reflects DOE's commitment to the coal combustion by-product (CCB) industry, to the advancement of clean coal technology, and to cooperation with other government agencies. Information from DOE projects and commercial endeavors in fluidized-bed combustion (FBC) and coal gasification is the focus of this task. The primary goal is to provide an easily accessible compilation of characterization information on the by-products from these processes to government agencies and industry to facilitate sound regulatory and management decisions. Additional written documentation will facilitate the preparation of an updated final version of background information collected for DOE in preparation of the Report to Congress on barriers to CCB utilization.

  8. Diesel fuel aromatic and cetane number effects on combustion and emissions from a prototype 1991 diesel engine

    SciTech Connect (OSTI)

    Sienicki, E.J.; Jass, R.E.; Slodowske, W.J.; McCarthy, C.I.; Krodel, A.L.

    1990-01-01T23:59:59.000Z

    This book reports on a prototype 1991-model diesel engine that was tested using EPA transient emissions procedures to determine the effect of fuel properties on combustion characteristics and exhaust emissions. The eleven test fuel set focused primarily on total aromatic content, multi-ring aromatic content, and cetane number, but other fuel variables were also studied. Hydrotreating was used to obtain reductions in fuel sulfur and aromatic content. Increasing cetane number and reducing aromatic content resulted in lower emissions of hydrocarbons and NO{sub x}. Particulate emission were best predicted by sulfur content, aromatic content and 90% distillation temperature. Multi-ring aromatics showed a greater significance that total aromatics on hydrocarbon and particulate emissions. combustion parameters were highly dependent on fuel cetane number.

  9. Influence of Alloy and Solidification Parameters on Grain Refinement in Aluminum Weld Metal due to Inoculation

    SciTech Connect (OSTI)

    Schempp, Philipp [BAM, Germany; Tang, Z. [BIAS, Germany; Cross, Carl E. [Los Alamos National Laboratory; Seefeld, T. [BIAS, Germany; Pittner, A. [BAM, Germany; Rethmeier, M. [BAM, Germany

    2012-06-28T23:59:59.000Z

    The goals are: (1) Establish how much Ti/B grain refiner is need to completely refine aluminum weld metal for different alloys and different welding conditions; (2) Characterize how alloy composition and solidification parameters affect weld metal grain refinement; and (3) Apply relevant theory to understand observed behavior. Conclusions are: (1) additions of Ti/B grain refiner to weld metal in Alloys 1050, 5083, and 6082 resulted in significant grain refinement; (2) grain refinement was more effective in GTAW than LBW, resulting in finer grains at lower Ti content - reason is limited time available for equiaxed grain growth in LBW (inability to occlude columnar grain growth); (3) welding travel speed did not markedly affect grain size within GTAW and LBW clusters; and (4) application of Hunt CET analysis showed experimental G to be on the order of the critical G{sub CET}; G{sub CET} was consistently higher for GTAW than for LBW.

  10. Impact of Environmental Compliance Costs on U.S. Refining Profitability 1995-2001

    Reports and Publications (EIA)

    2003-01-01T23:59:59.000Z

    This report assesses the effects of pollution abatement requirements on the financial performance of U.S. petroleum refining and marketing operations during the 1995 to 2001 period. This study is a follow-up to the October 1997 publication entitled The Impact of Environmental Compliance Costs on U.S. Refining Profitability, that focused on the financial impacts of U.S. refining pollution abatement investment requirements in the 1988 to1995 period.

  11. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type (Million Gallons per Day) - Continued Year...

  12. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 401 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  13. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Information Administration Petroleum Marketing Annual 1995 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  14. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information AdministrationPetroleum Marketing Annual 1999 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  15. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) Year Month...

  16. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information AdministrationPetroleum Marketing Annual 1998 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  17. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information AdministrationPetroleum Marketing Annual 1998 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type (Million Gallons per Day) - Continued Year...

  18. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  19. Table 2. U.S. Refiner Prices of Petroleum Products to End Users

    U.S. Energy Information Administration (EIA) Indexed Site

    fuel. Note: Motor gasoline averages and totals prior to October 1993 include leaded gasoline. Sources: Energy Information Administration Form EIA-782A, "Refiners'Gas Plant...

  20. RFA-14-0001 - In the Matter of Commonwealth Oil Refining Company...

    Broader source: Energy.gov (indexed) [DOE]

    both programs would reduce the dependence of Puerto Rican consumers on high cost imported oil and refined petroleum products and that, consequently, both programs were consistent...

  1. Refining and Extending the Business Model with Information Technology: Dell Computer Corporation

    E-Print Network [OSTI]

    Kraemer, Kenneth L; Dedrick, Jason; Yamashiro, Sandra

    1999-01-01T23:59:59.000Z

    of Dell’s Direct Business Model Fuels Fifteenth ConsecutiveAND EXTENDING THE REFINING AND EXTENDING THE BUSINESS MODELBUSINESS MODEL CENTER FOR RESEARCH ON INFORMATION TECHNOLOGY

  2. OPERATOR INTERACTION WITH MODEL-BASED PREDICTIVE CONTROLLERS IN PETROCHEMICAL REFINING

    E-Print Network [OSTI]

    Virginia, University of

    OPERATOR INTERACTION WITH MODEL-BASED PREDICTIVE CONTROLLERS IN PETROCHEMICAL REFINING Greg A success in the petrochemical industry, they have introduced new challenges for the operators and engineers

  3. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 421 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  4. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 467 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  5. Quantitative Methods for Strategic and Investment Planning in the Oil-Refining

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    by one refinery Refinery Opera*onal Planning - Simulate the Refining Scenarios Supply Chain Investments Planning - Test the refinery best scenarios

  6. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  7. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1995 337 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  8. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  9. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

  10. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    Administration Petroleum Marketing Annual 1995 Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  11. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    Administration Petroleum Marketing Annual 1995 Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  12. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    Administration Petroleum Marketing Annual 1995 Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type (Million Gallons per Day) - Continued Year...

  13. ENZO: AN ADAPTIVE MESH REFINEMENT CODE FOR ASTROPHYSICS

    SciTech Connect (OSTI)

    Bryan, Greg L.; Turk, Matthew J. [Columbia University, Department of Astronomy, New York, NY 10025 (United States); Norman, Michael L.; Bordner, James; Xu, Hao; Kritsuk, Alexei G. [CASS, University of California, San Diego, 9500 Gilman Drive La Jolla, CA 92093-0424 (United States); O'Shea, Brian W.; Smith, Britton [Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Abel, Tom; Wang, Peng; Skillman, Samuel W. [Kavli Institute for Particle Astrophysics and Cosmology, Stanford University, Menlo Park, CA 94025 (United States); Wise, John H. [Center for Relativistic Astrophysics, School of Physics, Georgia Institute of Technology, 837 State Street, Atlanta, GA (United States); Reynolds, Daniel R. [Department of Mathematics, Southern Methodist University, Box 750156, Dallas, TX 75205-0156 (United States); Collins, David C. [Department of Physics, Florida State University, Tallahassee, FL 32306 (United States); Harkness, Robert P. [NICS, Oak Ridge National Laboratory, 1 Bethel Valley Rd, Oak Ridge, TN 37831 (United States); Kim, Ji-hoon [Department of Astronomy and Astrophysics, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States); Kuhlen, Michael [Theoretical Astrophysics Center, University of California Berkeley, Hearst Field Annex, Berkeley, CA 94720 (United States); Goldbaum, Nathan [Institute for Astronomy, University of Edinburgh, Edinburgh EH9 3HJ (United Kingdom); Hummels, Cameron [Department of Astronomy/Steward Observatory, University of Arizona, 933 N. Cherry Ave., Tucson, AZ 85721 (United States); Tasker, Elizabeth [Physics Department, Faculty of Science, Hokkaido University, Kita-10 Nishi 8, Kita-ku, Sapporo 060-0810 (Japan); Collaboration: Enzo Collaboration; and others

    2014-04-01T23:59:59.000Z

    This paper describes the open-source code Enzo, which uses block-structured adaptive mesh refinement to provide high spatial and temporal resolution for modeling astrophysical fluid flows. The code is Cartesian, can be run in one, two, and three dimensions, and supports a wide variety of physics including hydrodynamics, ideal and non-ideal magnetohydrodynamics, N-body dynamics (and, more broadly, self-gravity of fluids and particles), primordial gas chemistry, optically thin radiative cooling of primordial and metal-enriched plasmas (as well as some optically-thick cooling models), radiation transport, cosmological expansion, and models for star formation and feedback in a cosmological context. In addition to explaining the algorithms implemented, we present solutions for a wide range of test problems, demonstrate the code's parallel performance, and discuss the Enzo collaboration's code development methodology.

  14. Refining and classifying finite-time Lyapunov exponent ridges

    E-Print Network [OSTI]

    Allshouse, Michael R

    2015-01-01T23:59:59.000Z

    While more rigorous and sophisticated methods for identifying Lagrangian based coherent structures exist, the finite-time Lyapunov exponent (FTLE) field remains a straightforward and popular method for gaining some insight into transport by complex, time-dependent two-dimensional flows. In light of its enduring appeal, and in support of good practice, we begin by investigating the effects of discretization and noise on two numerical approaches for calculating the FTLE field. A practical method to extract and refine FTLE ridges in two-dimensional flows, which builds on previous methods, is then presented. Seeking to better ascertain the role of an FTLE ridge in flow transport, we adapt an existing classification scheme and provide a thorough treatment of the challenges of classifying the types of deformation represented by an FTLE ridge. As a practical demonstration, the methods are applied to an ocean surface velocity field data set generated by a numerical model.

  15. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-11-22T23:59:59.000Z

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  16. Black carbon in marine sediments : quantification and implications for the sorption of polycyclic aromatic hydrocarbons

    E-Print Network [OSTI]

    Accardi-Dey, AmyMarie, 1976-

    2003-01-01T23:59:59.000Z

    Sorption is a key factor in determining the fate of polycyclic aromatic hydrocarbons (PAHs) in the environment. Here, PAH sorption is proposed as the sum of two mechanisms: absorption into a biogenic, organic carbon (OC) ...

  17. Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation

    E-Print Network [OSTI]

    Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N nature of the polyaromatic hydrocarbons (PAHs) they are mostly bound to the sludge and escape aerobic

  18. Photoinduced Hydrogen Abstraction from Phenols by Aromatic Ketones. A New Mechanism for Hydrogen Abstraction by

    E-Print Network [OSTI]

    Leigh, William J.

    Photoinduced Hydrogen Abstraction from Phenols by Aromatic Ketones. A New Mechanism for Hydrogen carried out of the kinetics of inter- and intramolecular phenolic hydrogen abstraction phenolic hydrogen, which yields the corresponding phenoxyl-hemipinacol biradical. The biradicals have also

  19. Chemisorption of Aromatic Compounds on Well-Defined Palladium Surfaces: Studies by Electron Spectroscopy and Electrochemistry

    E-Print Network [OSTI]

    Li, Ding

    2010-10-12T23:59:59.000Z

    The chemisorption of aromatic compounds, derivatized with different functional groups, on well-defined Pd(111) surfaces was studied by a combination of Auger electron spectroscopy (AES), low energy electron diffraction (LEED), high resolution...

  20. Bacterial mutagenicity of polycyclic aromatic hydrocarbons in reconstituted mixtures and crude coal tar extracts and fractions

    E-Print Network [OSTI]

    Onufrock, Amy Mildred

    1994-01-01T23:59:59.000Z

    , coal, and oil shale vary widely in the amount and nature of potentially carcinogenic polycyclic aromatic hydrocarbons. Thus, potential carcinogenicity varies widely between representative PAH fractions derived from complex mixtures. PAH fractions...

  1. Chemistry of Furan Conversion into Aromatics and Olefins over HZSM-5: A Model Biomass Conversion Reaction

    SciTech Connect (OSTI)

    Cheng, Yu-Ting [Univ. of Massachusetts, Amherst, MA (United States); Huber, George W. [Univ. of Massachusetts, Amherst, MA (United States)

    2011-06-03T23:59:59.000Z

    The conversion of furan (a model of cellulosic biomass) over HZSM-5 was investigated in a thermogravimetric analysis–mass spectrometry system, in situ Fourier transform infrared analysis, and in a continuous-flow fixed-bed reactor. Furan adsorbed as oligomers at room temperature with a 1.73 of adsorbed furan/Al ratio. These oligomers were polycyclic aromatic compounds that were converted to CO, CO?, aromatics, and olefins at temperatures from 400 to 600 °C. Aromatics (e.g., benzene, toluene, and naphthalene), oligomer isomers (e.g., benzofuran, 2,2-methylenebisfuran, and benzodioxane), and heavy oxygenates (C??{sub +} oligomers) were identified as intermediates formed inside HZSM-5 at different reaction temperatures. During furan conversion, graphite-type coke formed on the catalyst surface, which caused the aromatics and olefins formation to deactivate within the first 30 min of time on-stream. We have measured the effects of space velocity and temperature for furan conversion to help us understand the chemistry of biomass conversion inside zeolite catalysts. The major products for furan conversion included CO, CO?, allene, C?–C? olefins, benzene, toluene, styrene, benzofuran, indene, and naphthalene. The aromatics (benzene and toluene) and olefins (ethylene and propylene) selectivity decreased with increasing space velocity. Unsaturated hydrocarbons such as allene, cyclopentadiene, and aromatics selectivity increased with increasing space velocity. The product distribution was selective to olefins and CO at high temperatures (650 °C) but was selective to aromatics (benzene and toluene) at intermediate temperatures (450–600 °C). At low temperatures (450 °C), benzofuran and coke contributed 60% of the carbon selectivity. Several different reactions were occurring for furan conversion over zeolites. Some important reactions that we have identified in this study include Diels–Alder condensation (e.g., two furans form benzofuran and water), decarbonylation (e.g., furan forms CO and allene), oligomerization (allene forms olefins and aromatics plus hydrogen), and alkylation (e.g., furan plus olefins). The product distribution was far from thermodynamic equilibrium.

  2. Evidence of Reactive Aromatics As a Major Source of Peroxy Acetyl Nitrate over China

    SciTech Connect (OSTI)

    Liu, Zhen; Wang, Yuhang; Gu, Dasa; Zhao, Chun; Huey, L. G.; Stickel, Robert; Liao, Jin; Shao, Min; Zhu, T.; Zeng, Limin; Liu, Shaw C.; Chang, Chih-Chung; Amoroso, Antonio; Costabile, Francesa

    2010-09-15T23:59:59.000Z

    We analyze the observations of near-surface peroxy acetyl nitrate (PAN) and its precursors in Beijing, China in August of 2007. The levels of PAN are remarkably high (up to 14 ppbv), surpassing those measured over other urban regions in recent years. Analyses employing a 1-D version of a chemical transport model (Regional chEmical and trAnsport Model, REAM) indicate that aromatic non-methane hydrocarbons (NMHCs) are the dominant (55-75%) PAN source. The major oxidation product of aromatics that produces acetyl peroxy radicals is methylglyoxal (MGLY). PAN and O3 in the observations are correlated at daytime; aromatic NMHCs appear to play an important role in O3 photochemistry. Previous NMHC measurements indicate the presence of reactive aromatics at high levels over broad polluted regions of China. Aromatics are often ignored in global and (to a lesser degree) regional 3D photochemical transport models; their emissions over China as well as photochemistry are quite uncertain.Our findings suggest that critical assessments of aromatics emissions and chemistry (such as the yields of MGLY) are necessary to understand and assess ozone photochemistry and regional pollution export in China.

  3. Sugar-Based Ethanol Biorefinery: Ethanol, Succinic Acid and By-Product Production

    SciTech Connect (OSTI)

    Donal F. Day

    2009-03-31T23:59:59.000Z

    The work conducted in this project is an extension of the developments itemized in DE-FG-36-04GO14236. This program is designed to help the development of a biorefinery based around a raw sugar mill, which in Louisiana is an underutilized asset. Some technical questions were answered regarding the addition of a biomass to ethanol facility to existing sugar mills. The focus of this work is on developing technology to produce ethanol and valuable by-products from bagasse. Three major areas are addressed, feedstock storage, potential by-products and the technology for producing ethanol from dilute ammonia pre-treated bagasse. Sugar mills normally store bagasse in a simple pile. During the off season there is a natural degradation of the bagasse, due to the composting action of microorganisms in the pile. This has serious implications if bagasse must be stored to operate a bagasse/biorefinery for a 300+ day operating cycle. Deterioration of the fermentables in bagasse was found to be 6.5% per month, on pile storage. This indicates that long term storage of adequate amounts of bagasse for year-round operation is probably not feasible. Lignin from pretreatment seemed to offer a potential source of valuable by-products. Although a wide range of phenolic compounds were present in the effluent from dilute ammonia pretreatment, the concentrations of each (except for benzoic acid) were too low to consider for extraction. The cellulosic hydrolysis system was modified to produce commercially recoverable quantities of cellobiose, which has a small but growing market in the food process industries. A spin-off of this led to the production of a specific oligosaccharide which appears to have both medical and commercial implications as a fungal growth inhibitor. An alternate use of sugars produced from biomass hydrolysis would be to produce succinic acid as a chemical feedstock for other conversions. An organism was developed which can do this bioconversion, but the economics of succinic acid production were such that it could not compete with current commercial practice. To allow recovery of commercial amounts of ethanol from bagasse fermentation, research was conducted on high solids loading fermentations (using S. cerevisiae) with commercial cellulase on pretreated material. A combination of SHF/SSF treatment with fed-batch operation allowed fermentation at 30% solids loading. Supplementation of the fermentation with a small amount of black-strap molasses had results beyond expectation. There was an enhancement of conversion as well as production of ethanol levels above 6.0% w/w, which is required both for efficient distillation as well as contaminant repression. The focus of fermentation development was only on converting the cellulose to ethanol, as this yeast is not capable of fermenting both glucose and xylose (from hemicellulose). In anticipation of the future development of such an organism, we screened the commercially available xylanases to find the optimum mix for conversion of both cellulose and hemicellulose. A different mixture than the spezyme/novozyme mix used in our fermentation research was found to be more efficient at converting both cellulose and hemicellulose. Efforts were made to select a mutant of Pichia stipitis for ability to co-ferment glucose and xylose to ethanol. New mutation technology was developed, but an appropriate mutant has not yet been isolated. The ability to convert to stillage from biomass fermentations were determined to be suitable for anaerobic degradation and methane production. An economic model of a current sugar factory was developed in order to provide a baseline for the cost/benefit analysis of adding cellulosic ethanol production.

  4. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect (OSTI)

    Gregory J. McCarthy; Dean G. Grier

    2001-01-01T23:59:59.000Z

    Prior to the initiation of this study, understanding of the long-term behavior of environmentally-exposed Coal Combustion By-Products (CCBs) was lacking in (among others) two primary areas addressed in this work. First, no method had been successfully applied to achieve full quantitative analysis of the partitioning of chemical constituents into reactive or passive crystalline or noncrystalline compounds. Rather, only semi-quantitative methods were available, with large associated errors. Second, our understanding of the long-term behavior of various CCBs in contact with the natural environment was based on a relatively limited set of study materials. This study addressed these areas with two objectives, producing (1) a set of protocols for fully quantitative phase analysis using the Rietveld Quantitative X-ray Diffraction (RQXRD) method and (2) greater understanding of the hydrologic and geochemical nature of the long-term behavior of disposed and utilized CCBs. The RQXRD technique was initially tested using (1) mixtures of National Institute of Standards and Technology (NIST) crystalline standards, and (2) mixtures of synthetic reagents simulating various CCBs, to determine accuracy and precision of the method, and to determine the most favorable protocols to follow in order to efficiently quantify multi-phase mixtures. Four sets of borehole samples of disposed or utilized CCBs were retrieved and analyzed by RQXRD according to the protocols developed under the first objective. The first set of samples, from a Class F ash settling pond in Kentucky disposed for up to 20 years, showed little mineralogical alteration, as expected. The second set of samples, from an embankment in Indiana containing a mixture of chain-grate (stoker) furnace ash and fluidized bed combustion (FBC) residues, showed formation of the mineral thaumasite, as observed in previously studied exposed FBC materials. Two high-calcium CCBs studied, including a dry-process flue gas desulfurization (FGD) by-product disposed in the Midwest, and a mixture of Class C fly ash and wet process FGD by-product codisposed in North Dakota, appeared relatively unchanged mineralogically over the up to 5 and 17 years of emplacement, respectively. Each of these two materials contained mineralogies consistent with short-term hydration products of their respective starting (dry) materials. The hydration product ettringite persisted throughout the duration of emplacement at each site, and the diagenetic ash alteration product thaumasite did not form at either site. Explanations for the absence of thaumasite in these two sites include a lack of significant carbonate, sulfate, and alkalinity sources in the case of the North Dakota site, and a lack of sulfate, alkalinity, and sufficient moisture in the Midwest site. Potential for future thaumasite formation in these materials may exist if placed in contact with cold, wet materials containing the missing components listed above. In the presence of the sulfite scrubber mineral hannebachite, the ettringites formed had crystallographic unit cell dimensions smaller than those of pure sulfate ettringite, suggesting either incorporation of sulfite ions into the ettringite structure, or incorporation of silicon and carbonate ions, forming a solid solution towards thaumasite.

  5. Polycylcic Aromatic Hydrocarbons (PAH's) in dense cloud chemistry

    E-Print Network [OSTI]

    Valentine Wakelam; Eric Herbst

    2008-02-26T23:59:59.000Z

    Virtually all detailed gas-phase models of the chemistry of dense interstellar clouds exclude polycyclic aromatic hydrocarbons (PAH's). This omission is unfortunate because from the few studies that have been done on the subject, it is known that the inclusion of PAH's can affect the gas-phase chemistry strongly. We have added PAH's to our network to determine the role they play in the chemistry of cold dense cores. In the models presented here, we include radiative attachment to form PAH-, mutual neutralization between PAH anions and small positively-charged ions, and photodetachment. We also test the sensitivity of our results to changes in the size and abundance of the PAH's. Our results confirm that the inclusion of PAH's changes many of the calculated abundances of smaller species considerably. In TMC-1, the general agreement with observations is significantly improved contrary to L134N. This may indicate a difference in PAH properties between the two regions. With the inclusion of PAH's in dense cloud chemistry, high-metal elemental abundances give a satisfactory agreement with observations. As a result, we do not need to decrease the observed elemental abundances of all metals and we do not need to vary the elemental C/O ratio in order to produce large abundances of carbon species in TMC-1 (CP).

  6. A Multiscale Study of Polycyclic Aromatic Hydrocarbon Properties in Galaxies

    E-Print Network [OSTI]

    F. Galliano

    2008-02-16T23:59:59.000Z

    In the present contribution, I summarize a systematic study of ISO and Spitzer mid-IR spectra of Galactic regions and star forming galaxies. This study quantifies the relative variations of the main aromatic features inside spatially resolved objects as well as among the integrated spectra of 50 objects. Our analysis implies that the properties of the PAHs are remarkably universal throughout our sample and at different spatial scales. In addition, the relative variations of the band ratios, as large as one order of magnitude, are mainly controled by the fraction of ionized PAHs. In particular, I show that we can rule out both the modification of the PAH size distribution and the mid-IR extinction, as an explanation of these variations. High values of the I(6.2)/I(11.3) ratio are found to be associated with the far-UV illuminated surface of PDRs, at the scale of an interstellar cloud, and associated with star formation activity, at the scale of a galaxy. Using a few well-studied Galactic regions, we provide an empirical relation between the I(6.2)/I(11.3) ratio and the ionization/recombination ratio G0/ne. Finally, I show that these trends are consistent with the detailed modeling of the PAH emission within photodissociation regions, taking into account the radiative transfer, the stochastic heating and the charge exchange between gas and dust.

  7. Polycyclic aromatic compounds in fluidized bed combustion of coal

    SciTech Connect (OSTI)

    Walsh, P.M.; Beer, J.M.; Biermann, K.; Chiu, K.S.

    1983-08-01T23:59:59.000Z

    Polycyclic aromatic compounds (PAC) have been determined in the gas and particulate effluents from fluidized bed combustion of coal, lignite, and oil shale by a number of investigators. A bibliography of the reports of these investigations is contained in a paper by Chiu, Walsh, Beer, and Biemann (1983). The concentrations of PAC in the effluents are often quite low, but depend upon the combustor configuration and operating conditions. The goal of the present investigation is to develop a mechanism consistent with measured rates of formation and destruction of PAC in atmospheric pressure fluidized bed combustion (AFBC), so that a rational approach may be taken to adjustment of conditions for minimization of PAC in the effluents. PAC are determined in samples taken from the freeboard (space above the bed), rather than from the exhaust, to observe the evolution of the PAC distribution within the combustor. Mass fractions of the most abundant PAC observed in the freeboard during AFBC of high volatile bituminous coal were reported by Chiu, et al (1983). Some correlation of the rates of disappearance of PAC with particle concentration was noted by Dutta, Chiu, Walsh, Beer, and Biemann (1983). In the present paper theoretical estimates of the rates at which PAC might be consumed by heterogeneous reactions are compared with experimental rates estimated from PAC profiles determined by Chiu et al (1983).

  8. Wavelet Bi-frames with few Generators from Multivariate Refinable Functions

    E-Print Network [OSTI]

    Ehler, Martin

    Wavelet Bi-frames with few Generators from Multivariate Refinable Functions Martin Ehler Bin Han compactly supported wavelet bi-frames with few generators from almost any pair of compactly sup- ported multivariate refinable functions. In our examples, we focus on wavelet bi-frames whose primal and dual wavelets

  9. Refining k-means by Bootstrap and Data Depth Aurora Torrente and Juan Romo

    E-Print Network [OSTI]

    Romo, Juan

    Refining k-means by Bootstrap and Data Depth Aurora Torrente and Juan Romo Departamento de Estad two simple, computationally fast methods that allow the refinement of the initial points of k-means to cluster a given data set. They are based on alternating k-means and the search of the deepest (most

  10. Rapidly-Exploring Roadmaps: Weighing Exploration vs. Refinement in Optimal Motion Planning

    E-Print Network [OSTI]

    North Carolina at Chapel Hill, University of

    Rapidly-Exploring Roadmaps: Weighing Exploration vs. Refinement in Optimal Motion Planning Ron of already explored regions to find better paths. We present the rapidly- exploring roadmap (RRM), a new to explore further or to refine the explored space by adding edges to the current roadmap to find higher

  11. To appear in EPTCS. A CSP account of Event-B refinement

    E-Print Network [OSTI]

    Doran, Simon J.

    To appear in EPTCS. A CSP account of Event-B refinement Steve Schneider Department of Computing a CSP account of Event-B refinement, with a treatment for the first time of splitting events and of anticipated events. To this end, we define a CSP seman- tics for Event-B and show how the different forms

  12. FDR3 --A Modern Refinement Checker for CSP Thomas Gibson-Robinson, Philip Armstrong,

    E-Print Network [OSTI]

    Oxford, University of

    FDR3 -- A Modern Refinement Checker for CSP Thomas Gibson-Robinson, Philip Armstrong, Alexandre.roscoe}@cs.ox.ac.uk Abstract. FDR3 is a complete rewrite of the CSP refinement checker FDR2, incorporating a significant number describe the new algorithm that FDR3 uses to construct its internal representation of CSP processes

  13. FDR3 --A Modern Refinement Checker for CSP Thomas Gibson-Robinson, Philip Armstrong,

    E-Print Network [OSTI]

    Oxford, University of

    FDR3 -- A Modern Refinement Checker for CSP Thomas Gibson-Robinson, Philip Armstrong, Alexandre.roscoe}@cs.ox.ac.uk Abstract. FDR3 is a complete rewrite of the CSP refinement checker FDR2, incorporating a significant number describe the new algorithm that FDR3 uses to construct its in- ternal representation of CSP processes

  14. Don't care in SMT--Building flexible yet efficient abstraction/refinement solvers

    E-Print Network [OSTI]

    Leucker, Martin

    Don't care in SMT--Building flexible yet efficient abstraction/refinement solvers Andreas Bauer Satisfiability Modulo Theories (SMT) solver for a wide range of theories. Our method follows the abstrac- tion/refinement approach to simplify the implementation of custom SMT solvers. The expected performance penalty

  15. Don't care in SMT---Building flexible yet efficient abstraction/refinement solvers

    E-Print Network [OSTI]

    Leucker, Martin

    Don't care in SMT---Building flexible yet efficient abstraction/refinement solvers Andreas Bauer an efficient Satisfiability Modulo Theories (SMT) solver for a wide range of theories. Our method follows the abstrac­ tion/refinement approach to simplify the implementation of custom SMT solvers. The expected

  16. Aspects of Western Refining, Inc.'s Proposed Acquisition of Giant Industries, Inc.

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    Presentation of company-level, non-proprietary data and relevant aggregate data for U.S. refinery capacity and gasoline marketing of Western Refining and Giant Industries to inform discussions of Western Refining Inc.'s proposed acquisition of Giant Industries Inc. for a total of $1.5 billion, which was announced August 28, 2006.

  17. Comparative analysis of polycyclic aromatic sulfur heterocycles isolated from four shale oils. [Polycyclic aromatic sulfur heterocycles; thiophenes

    SciTech Connect (OSTI)

    Willey, C.; Pelroy, R.; Stewart, D.

    1981-12-01T23:59:59.000Z

    This report describes the isolation of sulfur heterocycle fractions from four shale oils (Paraho, Geokinetics, Occidental, and Rio Blanco), the use of capillary column gas chromatography and mass spectrometry for the identification of individual mixture components, and a reverse (Ames) and forward mutation assay with Salmonella typhimurium to screen for possible health hazards. The major components of the Polycyclic Aromatic Sulfur Heterocycles (PASH) fractions for all four shale oils were found to be two- to three-ringed parent and alkylated thiophene compounds. In all cases the PASH fractions showed no more specific mutagenic response than the neutral PAC fractions from which they were isolated. The only mutagenic response which was detected in the PASH fractions was for the Rio Blanco shale oil and showed specific mutagenic response similar to the neutral PAC fraction from which it was isolated. Finally, the forward mutation 8-azaguanine test was apparently more sensitive than the Ames histidine reversion test in detecting mutagenic activity for the chemical fractions from the shale oils.

  18. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.

    2003-09-12T23:59:59.000Z

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  19. Electrolysis byproduct D2O provides a third way to mitigate CO2

    SciTech Connect (OSTI)

    Schenewerk, William Ernest [self, Los Angeles, CA (United States)

    2009-09-01T23:59:59.000Z

    Rapid atomic power deployment may be possible without using fast breeder reactors or making undue demands on uranium resource. Using by-product D2O and thorium-U233 in CANDU and RBMK piles may circumvent need for either fast breeder reactors or seawater uranium. Atmospheric CO2 is presently increasing 2.25%/year in proportion to 2.25%/year exponential fossil fuel consumption increase. Roughly 1/3 anthropologic CO2 is removed by various CO2 sinks. CO2 removal is modelled as being proportional to 45-year-earlier CO2 amount above 280 ppm-C Water electrolysis produces roughly 0.1 kg-D20/kWe-y. Material balance assumes each electrolysis stage increases D2O bottoms concentration times 3. Except for first two electrolysis stages, all water from hydrogen consumption is returned to electrolysis. The unique characteristic of this process is the ability to economically burn all deuterium-enriched H2 in vehicles. Condensate from vehicles returns to appropriate electrolysis stage. Fuel cell condensate originally from reformed natural gas may augment second-sage feed. Atomic power expansion is 5%/year, giving 55000 GWe by 2100. World primary energy increases 2.25%/y, exceeding 4000 EJ/y by 2100. CO2 maximum is roughly 600 ppm-C around year 2085. CO2 declines back below 300 ppm-C by 2145 if the 45-year-delay seawater sink remains effective.

  20. FGD Additives to Segregate and Sequester Mercury in Solid Byproducts - Final Report

    SciTech Connect (OSTI)

    Searcy, K; Bltyhe, G M; Steen, W A

    2012-02-28T23:59:59.000Z

    Many mercury control strategies for U.S. coal-fired power generating plants involve co-benefit capture of oxidized mercury from flue gases treated by wet flue gas desulfurization (FGD) systems. For these processes to be effective at overall mercury control, the captured mercury must not be re-emitted to the atmosphere or into surface or ground water. The project sought to identify scrubber additives and FGD operating conditions under which mercury re-emissions would decrease and mercury would remain in the liquor and be blown down from the system in the chloride purge stream. After exiting the FGD system, mercury would react with precipitating agents to form stable solid byproducts and would be removed in a dewatering step. The FGD gypsum solids, free of most of the mercury, could then be disposed or processed for reuse as wallboard or in other beneficial reuse. The project comprised extensive bench-scale FGD scrubber tests in Phases I and II. During Phase II, the approaches developed at the bench scale were tested at the pilot scale. Laboratory wastewater treatment tests measured the performance of precipitating agents in removing mercury from the chloride purge stream. Finally, the economic viability of the approaches tested was evaluated.

  1. Cosmos++: Relativistic Magnetohydrodynamics on Unstructured Grids with Local Adaptive Refinement

    E-Print Network [OSTI]

    Peter Anninos; P. Chris Fragile; Jay D. Salmonson

    2005-09-09T23:59:59.000Z

    A new code and methodology are introduced for solving the general relativistic magnetohydrodynamic (GRMHD) equations in fixed background spacetimes using time-explicit, finite-volume discretization. The code has options for solving the GRMHD equations using traditional artificial-viscosity (AV) or non-oscillatory central difference (NOCD) methods, or a new extended AV (eAV) scheme using artificial-viscosity together with a dual energy-flux-conserving formulation. The dual energy approach allows for accurate modeling of highly relativistic flows at boost factors well beyond what has been achieved to date by standard artificial viscosity methods. It provides the benefit of Godunov methods in capturing high Lorentz boosted flows but without complicated Riemann solvers, and the advantages of traditional artificial viscosity methods in their speed and flexibility. Additionally, the GRMHD equations are solved on an unstructured grid that supports local adaptive mesh refinement using a fully threaded oct-tree (in three dimensions) network to traverse the grid hierarchy across levels and immediate neighbors. A number of tests are presented to demonstrate robustness of the numerical algorithms and adaptive mesh framework over a wide spectrum of problems, boosts, and astrophysical applications, including relativistic shock tubes, shock collisions, magnetosonic shocks, Alfven wave propagation, blast waves, magnetized Bondi flow, and the magneto-rotational instability in Kerr black hole spacetimes.

  2. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J. [and others

    1998-12-31T23:59:59.000Z

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  3. Mineralogical and physical considerations related to the separation and recovery of constituents from aluminum smelter by-products and wastes

    SciTech Connect (OSTI)

    Plumpton, A.J.; Wilhelmy, J.F.; Blackburn, D.; Caouette, J.L. [Centre de Recherches Minerales, Sainte-Foy, Quebec (Canada)

    1996-10-01T23:59:59.000Z

    Several by-products and waste products of aluminum smelting were characterized mineralogically and physically, in order to evaluate the potential for their decontamination or separation and recovery into valuable products using mineral processing techniques. The test samples were selected from among Bayer process red mud, bath-alumina mixture, cleaned anode butts, anode recycle residues, spent potlining, saltcake and fluorogypsum. Several of these materials were shown to be composed either of highly liberated, potentially separable mineral phases, or of locked minerals which could be partially liberated by grinding to smaller but practical particle sizes. An analysis of specific physical properties of the liberated constituent mineral phases was accompanied by preliminary experimental evaluation of their separability. An assessment was made of potential mineral processing techniques including size and form differentiation, gravitational and magnetic field separation, flotation, separation based on surface charging phenomena or work function, and pneumatic tabling. The results confirmed the suitability of low-cost physical separation techniques for the treatment of some by-products and wastes. This paper presents results of a preliminary evaluation of two smelter products. The conference paper will analyze and discuss in more detail the potential for the mineral processing of these and other smelter by-products and wastes.

  4. Economic Evaluation of By-Product Power/Co-Generation Systems for Industrial Plants with Fluidized-Bed Coal Burning Facilities

    E-Print Network [OSTI]

    Mesko, J. E.

    1980-01-01T23:59:59.000Z

    Economic analysis of the construction and operation of by-product electric power and steam/power cogeneration systems in coal fired fluidized-bed steam cycles, located at individual industrial sites analyzed by the author, is being presented...

  5. Kinetics and mechanisms of reactions involving small aromatic reactive intermediates

    SciTech Connect (OSTI)

    Lin, M.C. [Emory Univ., Atlanta, GA (United States)

    1993-12-01T23:59:59.000Z

    Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

  6. Sorption characteristics of polycyclic aromatic hydrocarbons in aluminum smelter residues

    SciTech Connect (OSTI)

    Gijs D. Breedveld; Emilien Pelletier; Richard St. Louis; Gerard Cornelissen [Norwegian Geotechnical Institute, Oslo (Norway)

    2007-04-01T23:59:59.000Z

    High temperature carbon oxidation in primary aluminum smelters results in the release of polycyclic aromatic hydrocarbons (PAH) into the environment. The main source of PAH are the anodes, which are composed of petroleum coke (black carbon, BC) and coal tar pitch. To elucidate the dominant carbonaceous phase controlling the environmental fate of PAH in aluminum smelter residues (coke BC and/or coal tar), the sorptive behavior of PAHs has been determined, using passive samplers and infinite-sink desorption methods. Samples directly from the wet scrubber were studied as well as ones from an adjacent 20-year old storage lagoon and roof dust from the smelter. Carbon-normalized distribution coefficients of native PAHs were 2 orders of magnitude higher than expected based on amorphous organic carbon (AOC)/water partitioning, which is in the same order of magnitude as reported literature values for soots and charcoals. Sorption isotherms of laboratory-spiked deuterated phenanthrene showed strong (about 100 times stronger than AOC) but nonetheless linear sorption in both fresh and aged aluminum smelter residues. The absence of nonlinear behavior typical for adsorption to BC indicates that PAH sorption in aluminum smelter residues is dominated by absorption into the semi-solid coal tar pitch matrix. Desorption experiments using Tenax showed that fresh smelter residues had a relatively large rapidly desorbing fraction of PAH (35-50%), whereas this fraction was strongly reduced (11-16%) in the lagoon and roof dust material. Weathering of the coal tar residue and/or redistribution of PAH between coal tar and BC phases could explain the reduced availability in aged samples. 38 refs., 5 figs., 1 tab.

  7. J4.3 LARGE-EDDY SIMULATION ACROSS A GRID REFINEMENT INTERFACE USING EXPLICIT FILTERING AND RECONSTRUCTION

    E-Print Network [OSTI]

    Chow, Fotini Katopodes

    reflect off grid refinement interfaces, specifically on the outflow boundary from a fine to a coarse grid reflection off grid refinement interfaces by forcing the filter-resolved scale on a fine grid to equal

  8. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1983-09-20T23:59:59.000Z

    A process is described for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 1 fig.

  9. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, John M. (Oak Ridge, TN); Napier, John M. (Oak Ridge, TN); Travaglini, Michael A. (Oliver Springs, TN)

    1983-01-01T23:59:59.000Z

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced.

  10. Strontium Isotope Study of Coal Untilization By-products Interacting with Environmental Waters

    SciTech Connect (OSTI)

    Spivak-Birndorf, Lev J; Stewart, Brian W; Capo, Rosemary C; Chapman, Elizabeth C; Schroeder, Karl T; Brubaker, Tonya M

    2011-09-01T23:59:59.000Z

    Sequential leaching experiments on coal utilization by-products (CUB) were coupled with chemical and strontium (Sr) isotopic analyses to better understand the influence of coal type and combustion processes on CUB properties and the release of elements during interaction with environmental waters during disposal. Class C fly ash tended to release the highest quantity of minor and trace elements—including alkaline earth elements, sodium, chromium, copper, manganese, lead, titanium, and zinc—during sequential extraction, with bottom ash yielding the lowest. Strontium isotope ratios ({sup 87}Sr/{sup 86}Sr) in bulk-CUB samples (total dissolution of CUB) are generally higher in class F ash than in class C ash. Bulk-CUB ratios appear to be controlled by the geologic source of the mineral matter in the feed coal, and by Sr added during desulfurization treatments. Leachates of the CUB generally have Sr isotope ratios that are different than the bulk value, demonstrating that Sr was not isotopically homogenized during combustion. Variations in the Sr isotopic composition of CUB leachates were correlated with mobility of several major and trace elements; the data suggest that arsenic and lead are held in phases that contain the more radiogenic (high-{sup 87}Sr/{sup 86}Sr) component. A changing Sr isotope ratio of CUB-interacting waters in a disposal environment could forecast the release of certain strongly bound elements of environmental concern. This study lays the groundwork for the application of Sr isotopes as an environmental tracer for CUB–water interaction.

  11. Conversion of high carbon refinery by-products. Quarterly report, January 1--March 31, 1996

    SciTech Connect (OSTI)

    Katta, S.; Henningsen, G.; Lin, Y.Y.; O`Donnell, J.

    1996-04-26T23:59:59.000Z

    The overall objective of the project is to demonstrate that a partial oxidation system, which utilizes a transport reactor, is a viable means of converting refinery wastes, byproducts, and other low value materials into valuable products. The primary product would be a high quality fuel gas, which could also be used as a source of hydrogen. The concept involves subjecting the hydrocarbon feed to pyrolysis and steam gasification in a circulating bed of solids. Carbon residue formed during pyrolysis, as well as metals in the feed, are captured by the circulating solids which are returned to the bottom of the transport reactor. Air or oxygen is introduced in this lower zone and sufficient carbon is burned, sub-stoichiometrically, to provide the necessary heat for the endothermic pyrolysis and gasification reactions. The hot solids and gases leaving this zone pass upward to contact the feed material and continue the gasification process. The Transport Reactor Test Unit (TRTU) was commissioned to conduct studies on pyrolysis of Rose Bottoms using spent FCC (Fluid Catalytic Cracker) catalyst as the circulating medium and gasification of this carbon over a temperature range of 1,600 to 1,700 F. The Rose Bottoms (Residuum Oil Supercritical Extraction) was produced in the Rose unit. Studies were done in the Bench Scale Reactor Unit (BRU) to develop suitable catalyst formulations and to study the steam reforming of methane and propane in support of the experiments to be conducted in the TRTU. Studies were also conducted on gasification of coke breeze, petroleum cokes and carbon deposited on FCC catalyst. The catalytic effect of potassium on gasification of these solids was studied. Studies were conducted in the CFS (cold flow simulator) to investigate flow problems experienced in the TRTU. Results from these studies are presented in this report.

  12. Effect of industrial by-products containing electron acceptors on mitigating methane emission during rice cultivation

    SciTech Connect (OSTI)

    Ali, Muhammad Aslam [Department of Environmental Science, Bangladesh Agricultural University, Mymensingh 2202 (Bangladesh); Lee, Chang Hoon [Functional Cereal Crop Research Division, National Institute of Crop Science, RDA, 1085, Naey-dong, Milyang (Korea, Republic of); Kim, Sang Yoon [Division of Applied Life Science, Graduate School (Brain Korea 21 Program), Gyeongsang National University, Jinju 660-701 (Korea, Republic of); Kim, Pil Joo [Division of Applied Life Science, Graduate School (Brain Korea 21 Program), Gyeongsang National University, Jinju 660-701 (Korea, Republic of); Institute of Agriculture and Life Sciences, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)], E-mail: pjkim@gnu.ac.kr

    2009-10-15T23:59:59.000Z

    Three industrial by-products (fly ash, phosphogypsum and blast furnace slag), were evaluated for their potential re-use as soil amendments to reduce methane (CH{sub 4}) emission resulting from rice cultivation. In laboratory incubations, CH{sub 4} production rates from anoxic soil slurries were significantly reduced at amendment levels of 0.5%, 1%, 2% and 5% (wt wt{sup -1}), while observed CO{sub 2} production rates were enhanced. The level of suppression in methane production was the highest for phosphogypsum, followed by blast slag and then fly ash. In the greenhouse experiment, CH{sub 4} emission rates from the rice planted potted soils significantly decreased with the increasing levels (2-20 Mg ha{sup -1}) of the selected amendments applied, while rice yield simultaneously increased compared to the control treatment. At 10 Mg ha{sup -1} application level of the amendments, total seasonal CH{sub 4} emissions were reduced by 20%, 27% and 25%, while rice grain yields were increased by 17%, 15% and 23% over the control with fly ash, phosphogypsum, and blast slag amendments, respectively. The suppression of CH{sub 4} production rates as well as total seasonal CH{sub 4} flux could be due to the increased concentrations of active iron, free iron, manganese oxides, and sulfate in the amended soil, which acted as electron acceptors and controlled methanogens' activity by limiting substrates availability. Among the amendments, blast furnace slag and fly ash contributed mainly to improve the soil nutrients balance and increased the soil pH level towards neutral point, but soil acidity was developed with phosphogypsum application. Conclusively, blast slag among the selected amendments would be a suitable soil amendment for reducing CH{sub 4} emissions as well as sustaining rice productivity.

  13. EVALUATION OF THE SACCHAROFLEX 2000 REFLECTANCE MEASURING INSTRUMENT FOR REFINED SUGAR COLOUR ESTIMATION AT HULETTS REFINERY

    E-Print Network [OSTI]

    M Moodley; N K Padayachee; V Govender

    Due to the successful use of the Saccharoflex 2000 reflectance measurement instrument on the estimation of refined sugar colour elsewhere in the world, it was decided by Tongaat-Hulett Sugar to evaluate the instrument at the refinery in Durban. Tests were carried out on first, second, third and fourth refined sugars, the results of which showed a good correlation between the ICUMSA colour measurement and the reflectance reading obtained from the Saccharoflex 2000. The instrument offers a number of advantages, the main one being that a refined sugar colour value can be obtained in less than a minute. The refinery has therefore purchased one for process control.

  14. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore [Singapore Institute of Manufacturing Technology; Cross, Carl E. [Los Alamos National Laboratory

    2012-06-28T23:59:59.000Z

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  15. RAM: a Relativistic Adaptive Mesh Refinement Hydrodynamics Code

    SciTech Connect (OSTI)

    Zhang, Wei-Qun; /KIPAC, Menlo Park; MacFadyen, Andrew I.; /Princeton, Inst. Advanced Study

    2005-06-06T23:59:59.000Z

    The authors have developed a new computer code, RAM, to solve the conservative equations of special relativistic hydrodynamics (SRHD) using adaptive mesh refinement (AMR) on parallel computers. They have implemented a characteristic-wise, finite difference, weighted essentially non-oscillatory (WENO) scheme using the full characteristic decomposition of the SRHD equations to achieve fifth-order accuracy in space. For time integration they use the method of lines with a third-order total variation diminishing (TVD) Runge-Kutta scheme. They have also implemented fourth and fifth order Runge-Kutta time integration schemes for comparison. The implementation of AMR and parallelization is based on the FLASH code. RAM is modular and includes the capability to easily swap hydrodynamics solvers, reconstruction methods and physics modules. In addition to WENO they have implemented a finite volume module with the piecewise parabolic method (PPM) for reconstruction and the modified Marquina approximate Riemann solver to work with TVD Runge-Kutta time integration. They examine the difficulty of accurately simulating shear flows in numerical relativistic hydrodynamics codes. They show that under-resolved simulations of simple test problems with transverse velocity components produce incorrect results and demonstrate the ability of RAM to correctly solve these problems. RAM has been tested in one, two and three dimensions and in Cartesian, cylindrical and spherical coordinates. they have demonstrated fifth-order accuracy for WENO in one and two dimensions and performed detailed comparison with other schemes for which they show significantly lower convergence rates. Extensive testing is presented demonstrating the ability of RAM to address challenging open questions in relativistic astrophysics.

  16. State of heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B. [BDM-Oklahoma, Inc., Bartlesville, OK (United States)

    1995-12-31T23:59:59.000Z

    California is unique in the United States because it has the largest heavy oil (10{degrees} to 20{degrees}API gravity) resource, estimated to be in excess of 40 billion barrels. Of the current 941,543 barrels/day of oil produced in California (14% of the U.S. total), 70% or 625,312 barrels/day is heavy oil. Heavy oil constituted only 20% of California`s oil production in the early 1940s, but development of thermal oil production technology in the 1960s allowed the heavy industry to grow and prosper to the point where by the mid-1980s, heavy oil constituted 70% of the state`s oil production. Similar to the rest of the United States, light oil production in the Los Angeles Basin, Coastal Region, and San Joaquin Valley peaked and then declined at different times throughout the past 30 years. Unlike other states, California developed a heavy oil industry that replaced declining light oil production and increased the states total oil production, despite low heavy oil prices, stringent environmental regulations and long and costly delays in developing known oil resources. California`s deep conversion refineries process the nation`s highest sulfur, lowest API gravity crude to make the cleanest transportation fuels available. More efficient vehicles burning cleaner reformulated fuels have significantly reduced the level of ozone precursors (the main contributor to California`s air pollution) and have improved air quality over the last 20 years. In a state where major oil companies dominate, the infrastructure is highly dependent on the 60% of ANS production being refined in California, and California`s own oil production. When this oil is combined with the small volume of imported crude, a local surplus of marketed oil exists that inhibits exploitation of California`s heavy oil resources. As ANS production declines, or if the export restrictions on ANS sales are lifted, a window of opportunity develops for increased heavy oil production.

  17. Evaluation of a new chromatographic method for aromatics in diesel fuels

    SciTech Connect (OSTI)

    Lee, S.W.; Fuhr, B.J.; Glavincevski, B.

    1987-01-01T23:59:59.000Z

    A new analytical method using supercritical fluid chromatography (SFC) with flame ionization detection (FID) was evaluated for the determination of the aromatics in diesel fuels. The method utilizes high performance liquid chromatography (HPLC) with a packed silica column and supercritical CO/sub 2/ as the carrier fluid. Performance evaluation was carried out using diesel fuels and secondary standards with a wide range of chemical composition. The aromatic content in the fuels was verified by the fluorescent indicator adsorption (FIA) and proton nuclear magnetic resonance (/sup 1/H NMR) methods. With the exception of initial moderate cost of the instrument, the method is simple, fast (less than 20 minutes per sample) and applicable to coloured samples and samples with final boiling points of about 450/sup 0/C. Aromatic concentrations in diesels showed good correlation with FIA data. It is well suited to petroleum refinery applications as an alternate for standard FIA methods.

  18. Dutch gas plant uses polymer process to treat aromatic-saturated water

    SciTech Connect (OSTI)

    NONE

    1998-11-02T23:59:59.000Z

    A gas-processing plant in Harlingen, The Netherlands, operated by Elf Petroland has been running a porous-polymer extraction process since 1994 to remove aromatic compounds from water associated with produced natural gas. In the period, the unit has removed dispersed and dissolved aromatic compounds to a concentration of <1 ppm with energy consumption of only 17% that of a steam stripper, according to Paul Brooks, general manager for Akzo Nobel`s Macro Porous Polymer-Extraction (MPPE) systems. The paper describes glycol treatment the MPPE separation process, and the service contract for the system.

  19. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    5.7 5.9 4.4 12.9 NA 17.3 See footnotes at end of table. 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade and Sales Type 18 Energy Information Administration ...

  20. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    98.0 98.0 86.6 75.0 - 80.1 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  1. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.3 3.4 7.9 3.3 W 11.3 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  2. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.4 92.1 83.7 74.1 W 80.9 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  3. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    87.4 86.9 78.3 68.5 W 70.8 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  4. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.8 92.5 84.0 72.5 W 80.7 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  5. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    88.4 87.8 80.1 70.0 NA 72.6 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  6. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    94.0 93.9 83.2 73.8 - 79.3 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  7. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.6 3.7 7.9 3.1 W 11.0 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  8. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    5.7 5.9 3.9 12.7 W 16.6 See footnotes at end of table. 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade and Sales Type 18 Energy Information Administration ...

  9. Process for solvent refining of coal using a denitrogenated and dephenolated solvent

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

    1984-01-01T23:59:59.000Z

    A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.

  10. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    U.S. Energy Information Administration (EIA) Indexed Site

    - W 73.5 See footnotes at end of table. A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present Energy Information Administration ...

  11. Economic impact of the European Union Emission Trading Scheme : evidence from the refining sector

    E-Print Network [OSTI]

    Lacombe, Romain H

    2008-01-01T23:59:59.000Z

    I study the economic impact of the European Union Emission Trading Scheme (EU ETS) on the refining industry in Europe. I contrast previous ex-ante studies with the lessons from a series of interviews I conducted with ...

  12. Using a conformation-dependent stereochemical library improves crystallographic refinement of proteins

    SciTech Connect (OSTI)

    Tronrud, Dale E.; Berkholz, Donald S.; Karplus, P. Andrew (Oregon State U.)

    2010-07-02T23:59:59.000Z

    The major macromolecular crystallographic refinement packages restrain models to ideal geometry targets defined as single values that are independent of molecular conformation. However, ultrahigh-resolution X-ray models of proteins are not consistent with this concept of ideality and have been used to develop a library of ideal main-chain bond lengths and angles that are parameterized by the {phi}/{psi} angle of the residue [Berkholz et al. (2009), Structure, 17, 1316-1325]. Here, it is first shown that the new conformation-dependent library does not suffer from poor agreement with ultrahigh-resolution structures, whereas current libraries have this problem. Using the TNT refinement package, it is then shown that protein structure refinement using this conformation-dependent library results in models that have much better agreement with library values of bond angles with little change in the R values. These tests support the value of revising refinement software to account for this new paradigm.

  13. A Concept-Driven Construction of the Mondex Protocol using Three Refinements

    E-Print Network [OSTI]

    Banach, Richard

    as closely as possible to the original, or by adapting the problem to fit the style of the tool, thereby, the proof is monolithic, consisting of a single refinement. Other authors, particularly [19] and [20], have

  14. A ConceptDriven Construction of the Mondex Protocol using Three Refinements

    E-Print Network [OSTI]

    Banach, Richard

    as closely as possible to the original, or by adapting the problem to fit the style of the tool, thereby, the proof is monolithic, consisting of a single refinement. Other authors, particularly [19] and [20], have

  15. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    132.9 1,418.3 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  16. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  17. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Gasoline and Diesel Fuel Update (EIA)

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  18. Optimized Execution of Action Chains through Subgoal Refinement Freek Stulp and Michael Beetz

    E-Print Network [OSTI]

    Cremers, Daniel

    Optimized Execution of Action Chains through Subgoal Refinement Freek Stulp and Michael Beetz, Germany {stulp,beetz}@in.tum.de Abstract In this paper we propose a novel computation model

  19. QSAR model of the phototoxicity of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro, Marcia Miguel Castro Ferreira*

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    QSAR model of the phototoxicity of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro of 67 polycyclic aromatic hydrocarbons (PAHs) is performed and a prediction rule for the phototoxicity be produced from saturated hydrocarbons under oxygen-deficient conditions. Hydrocarbons with very low

  20. Origin and significance of aromatic hydrocarbons in giant iron ore deposits of the late Archean Hamersley Basin,

    E-Print Network [OSTI]

    Brocks, Jochen J.

    Origin and significance of aromatic hydrocarbons in giant iron ore deposits of the late Archean extractable saturated and aromatic hydrocarbons. The host rocks belong to the $2.5 billion years (Ga) old Mt and Newman (Mt Whaleback). The saturated hydrocarbons in the rock extracts have the composition of highly

  1. Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [TpRh(CNneopentyl)] Complex

    E-Print Network [OSTI]

    Jones, William D.

    Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp activation of fluorinated aromatic hydrocarbons by [TpRh(CNneopentyl)] resulted in the formation of products of homogeneous transition-metal catalysts to activate and functionalize C-H bonds of hydrocarbons for industrial

  2. Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H-ZSM5

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H Co/H-ZSM5 catalyzes propane dehydrogenation and aromatization reactions. Initial product selectivities, product site-yields, and the 13C content and distribution in the products of 2-13C-propane show

  3. Rubbing-Induced Molecular Reorientation on an Alignment Surface of an Aromatic Polyimide Containing Cyanobiphenyl Side Chains

    E-Print Network [OSTI]

    Zhuang, Xiaowei

    Rubbing-Induced Molecular Reorientation on an Alignment Surface of an Aromatic Polyimide Containing to study the molecular orientation and conformation changes at a rubbed polyimide alignment-layer surface. This aromatic polyimide containing pendent cyanobiphenyl mesogens was synthesized via a polycondensation of 2

  4. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking. Investigation of coal extraction as a method to produce RCO continues; the reactor modifications to filter the products hot and to do multi-stage extraction improve extraction yields from {approx}50 % to {approx}70%. Carbon characterization of co-cokes for use as various carbon artifacts continues.

  5. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  6. Refinement trajectory and determination of eigenstates by a wavelet based adaptive method

    SciTech Connect (OSTI)

    Pipek, Janos; Nagy, Szilvia [Department of Theoretical Physics, Institute of Physics, Budapest University of Technology and Economics, H-1521 Budapest (Hungary); Department of Telecommunication, Jedlik Anyos Institute of Informatics, Electrical and Mechanical Engineering, Szechenyi Istvan University, H-9026 Gyor, Egyetem ter 1 (Hungary)

    2006-11-07T23:59:59.000Z

    The detail structure of the wave function is analyzed at various refinement levels using the methods of wavelet analysis. The eigenvalue problem of a model system is solved in granular Hilbert spaces, and the trajectory of the eigenstates is traced in terms of the resolution. An adaptive method is developed for identifying the fine structure localization regions, where further refinement of the wave function is necessary.

  7. Refine your search Select options from the menu on the left hand

    E-Print Network [OSTI]

    Yener, Aylin

    ://psu.summon.serialssolutions.comhttp://psu.summon.serialssolutions.com F I N A L LY : RESEARCH AS EASYAS 1-2-3 #12;1 Enter search term into search box. 2 Refine results relevant articles were published in that year. Include or Exclude subject terms from your searchRefine your search Select options from the menu on the left hand side of the results screen

  8. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

  9. Isomeric differentiation of polycyclic aromatic hydrocarbons using silver nitrate reactive desorption electrospray ionization

    E-Print Network [OSTI]

    Zare, Richard N.

    such as incomplete combustion of fossil fuels, oil refining, motor vehicle exhaust, coke production, and other industrial activities.[1] Because of their effect as carcinogens,[2] PAHs are included in the US

  10. Thickness-based adaptive mesh refinement methods for multi-phase flow simulations with thin regions

    SciTech Connect (OSTI)

    Chen, Xiaodong [The State Key Laboratory of Nonlinear Mechanics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190 (China); Yang, Vigor, E-mail: vigor.yang@aerospace.gatech.edu [School of Aerospace Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0150 (United States)

    2014-07-15T23:59:59.000Z

    In numerical simulations of multi-scale, multi-phase flows, grid refinement is required to resolve regions with small scales. A notable example is liquid-jet atomization and subsequent droplet dynamics. It is essential to characterize the detailed flow physics with variable length scales with high fidelity, in order to elucidate the underlying mechanisms. In this paper, two thickness-based mesh refinement schemes are developed based on distance- and topology-oriented criteria for thin regions with confining wall/plane of symmetry and in any situation, respectively. Both techniques are implemented in a general framework with a volume-of-fluid formulation and an adaptive-mesh-refinement capability. The distance-oriented technique compares against a critical value, the ratio of an interfacial cell size to the distance between the mass center of the cell and a reference plane. The topology-oriented technique is developed from digital topology theories to handle more general conditions. The requirement for interfacial mesh refinement can be detected swiftly, without the need of thickness information, equation solving, variable averaging or mesh repairing. The mesh refinement level increases smoothly on demand in thin regions. The schemes have been verified and validated against several benchmark cases to demonstrate their effectiveness and robustness. These include the dynamics of colliding droplets, droplet motions in a microchannel, and atomization of liquid impinging jets. Overall, the thickness-based refinement technique provides highly adaptive meshes for problems with thin regions in an efficient and fully automatic manner.

  11. Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton

    SciTech Connect (OSTI)

    David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

    2007-03-31T23:59:59.000Z

    The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being sorbed onto the CCB when exposed to ambient-temperature air. The environmental performance of the mercury captured on AC used as a sorbent for mercury emission control technologies indicated that current CCB management options will continue to be sufficiently protective of the environment, with the potential exception of exposure to elevated temperatures. The environmental performance of the other ATEs investigated indicated that current management options will be appropriate to the CCBs produced using AC in mercury emission controls.

  12. ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    Robert S. Weber

    1999-05-01T23:59:59.000Z

    Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

  13. AFCI Transmutation Fuel Processes and By-Products Planning: Interim Report

    SciTech Connect (OSTI)

    Eric L. Shaber

    2005-09-01T23:59:59.000Z

    The goals of the Advanced Fuel Cycle Initiative (AFCI) Program are to reduce high-level waste volume, reduce long-lived and radiotoxic elements, and reclaim valuable energy content of spent nuclear fuel. The AFCI chartered the Fuel Development Working Group (FDWG) to develop advanced fuels in support of the AFCI goals. The FDWG organized a phased strategy of fuel development that is designed to match the needs of the AFCI program: Phase 1 - High-burnup fuels for light-water reactors (LWRs) and tri-isotopic (TRISO) fuel for gas-cooled reactors Phase 2 – Mixed oxide fuels with minor actinides for LWRs, Am transmutation targets for LWRs, inert matrix fuels for LWRs, and TRISO fuel containing Pu and other transuranium for gas-cooled reactors Phase 3 – Fertile free or low-fertile metal, ceramic, ceramic dispersed in a metal matrix (CERMET), and ceramics dispersed in a ceramic matrix (CERCER) that would be used primarily in fast reactors. Development of advanced fuels requires the fabrication, assembly, and irradiation of prototypic fuel under bounding reactor conditions. At specialized national laboratory facilities small quantities of actinides are being fabricated into such fuel for irradiation tests. Fabrication of demonstration quantities of selected fuels for qualification testing is needed but not currently feasible, because existing manual glovebox fabrication approaches result in significant radiation exposures when larger quantities of actinides are involved. The earliest demonstration test fuels needed in the AFCI program are expected to be variants of commercial mixed oxide fuel for use in an LWR as lead test assemblies. Manufacture of such test assemblies will require isolated fabrication lines at a facility not currently available in the U.S. Such facilities are now being planned as part of an Advanced Fuel Cycle Facility (AFCF). Adequate planning for and specification of actinide fuel fabrication facilities capable of producing transmutation fuels dictates the need for detailed process flows, mass balances, batch size data, and radiological dose estimates. Full definition of the materials that will need to be handled in the facility as feed material inputs, in-process fuel, scrap recycle, scrap requiring recovery, and by-product wastes is required. The feed material for demonstrating transmutation fuel fabrication will need to come from the separations of actinides from spent nuclear fuel processed in the same AFCF.

  14. Land application uses of dry FGD by-products. [Quarterly] report, July 1, 1993--September 30, 1993

    SciTech Connect (OSTI)

    Dick, W.A.; Beeghly, J.H.

    1993-12-31T23:59:59.000Z

    Reclamation of mine-sites with acid overburden requires the use of alkaline amendments and represents a potential high-volume use of alkaline dry flue gas desulfurization (FGD) by products. In a greenhouse study, 25-cm columns of acid mine spoil were amended with two FGD by-products; lime injection multistage burners (LIMB) fly ash or pressurized fluidized bed (PFBC) fly ash at rates of 0, 4, 8, 16, and 32% by weight (0, 40, 80, 160, and 320 tons/acre). Amended spoil was covered with 20 cm of acid topsoil amended with the corresponding FGD by-product to pH 7. Column leachate pH increased with FGD amendment rate while leachate Fe, Mn, and Zn decreased, Leachate Ca, S, and Mg decreased with LIMB amendment rate and increased with PFBC amendment. Leachate concentrations of regulated metals were decreased or unaffected by FGD amendment except for Se which was increased by PFBC. Spoil pH was increased up to 8.9 by PFBC, and up to 9.2 by LIMB amendment. Spoil pH also increased with depth with FGD amendments of 16 and 32%, Yield of fescue was increased by FGD amendment of 4 to 8%. Plant tissue content of most elements was unaffected by FGD amendment rate, and no toxicity symptoms were observed. Plant Ca and Mg were increased by LIMB and PFBC respectively, while plant S, Mn and Sr were decreased. Plant Ca and B was increased by LIMB, and plant Mg and S by PFBC amendment. These results indicate dry FGD by-products are effective in ameliorating acid, spoils and have a low potential for creating adverse environmental impacts.

  15. Photochemistry of aromatic hydrocarbons: implications for ozone and secondary organic aerosol formation

    E-Print Network [OSTI]

    Suh, Inseon

    2006-08-16T23:59:59.000Z

    -toluene reaction. The branching ratios of OH addition to ortho, para, meta, and ipso positions are predicted to be 0.52, 0.34, 0.11, and 0.03, respectively, significantly different from a recent theoretical study of the same reaction system. Aromatic peroxy...

  16. Identification of Sediment Organic Carbon Location and Association with Polycyclic Aromatic Hydrocarbons (PAHs) in Contaminated Sediment

    E-Print Network [OSTI]

    Identification of Sediment Organic Carbon Location and Association with Polycyclic Aromatic is known about the mechanisms of PAH and other hydrophobic organic compound sequestration and aging microspectroscopy at the NSLS beamline U10B and ALS beamline 1.4 were used to identify organic carbon location

  17. Enumeration and phylogenetic analysis of polycyclic aromatic hydrocarbon-degrading marine bacteria from Puget Sound sediments

    SciTech Connect (OSTI)

    Geiselbrecht, A.D.; Herwig, R.P.; Deming, J.W.; Staley, J.T. [Univ. of Washington, Seattle, WA (United States)

    1996-09-01T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are primarily released into the environment through anthropomorphic sources. PAH degradation has been known to occur in marine sediments. This paper describes the enumeration, isolation, and preliminary characterization of PAH-degrading strains from Puget Sound sediments. 38 refs., 3 figs., 3 tabs.

  18. Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants

    E-Print Network [OSTI]

    are less hydro- phobic (log Kow 3­5) and more water soluble than the high Mm PAHs; thus, they are fairly1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants and their associated rhizosphere microbes can promote PAH dissipation, offering

  19. QSPR models of boiling point, octanolwater partition coefficient and retention time index of polycyclic aromatic hydrocarbons

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    QSPR models of boiling point, octanol­water partition coefficient and retention time index Structure­Property Relationship (QSPR) analysis and study of polycyclic aromatic hydrocarbons (PAHs (bp), octanol­ water partition coefficient đlog KowȚ and retention time index (RI) for reversed

  20. Elimination Rate Constants of 46 Polycyclic Aromatic Hydrocarbons in the Unionid Mussel, Elliptio complanata

    E-Print Network [OSTI]

    Cope, W. Gregory

    contaminants, such as PAHs (James 1989; Neff 1979), as well as the large quantity of water that mussels individual polycyclic aromatic hydrocar- bons (PAHs) including both parent and alkyl homologues, t1/2, and t95 values reported in the literature for PAHs and other classes of hydrophobic organic

  1. Tenax as sorption sink for in vitro bioaccessibility measurement of polycyclic aromatic hydrocarbons in soils

    E-Print Network [OSTI]

    Ma, Lena

    & Environment, Lanzhou University, Lanzhou 730000, China d Soil and Water Science Department, University and maintain the desorption gradient between soil and GI solution. Polycyclic aromatic hydrocarbons (PAHs) were method. Inclusion of Tenax in GI solution increased bioaccessibility of PAHs in five spiked soils from 8

  2. Amine a-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway

    E-Print Network [OSTI]

    MacMillan, David W. C.

    Amine a-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway accomplished via photoredox catalysis to generate valuable benzylic amine pharmacophores. A variety of five substitution (SNAr)3 or transi- tion metal-catalyzed approaches,4 have been extensively studied and applied

  3. Aromatic measurements of diesel fuel - A CRC round-robin study

    SciTech Connect (OSTI)

    Seizinger, D.E.; Hoekman, S.K.

    1984-01-01T23:59:59.000Z

    A round robin study to measure the aromatic levels in diesel fuels was conducted by the Chemical Characterization Panel of the Coordinating Research Council Air Pollution Research Advisory Committee (CRC-APRAC) In-house Program Group, CAPI-1-64. The fuels for this study consisted of a jet fuel, a No. 2 diesel reference fuel, and three fuels used in a CRC-sponsored diesel emission project (CAPE-32). These fuels had 90% distillation temperatures which ranged from 472/sup 0/ to 642/sup 0/ F and aromaticity levels from approximately 18 to 55% by volume. All participants used the American Society for Testing and Materials (ASTM) D1319 or modified D1319 methods to measure the aromatic levels in the selected fuels. Some participants concurrently analyzed the same fuels using other methods such as high-performance liquid chromatography, mass spectrometry, nuclear magnetic resonance spectrometry, and elution chromatography (ASTM D2549). One non-participating laboratory analyzed the fuels using supercritical fluid chromatography. The results of nine participants using the D1319 methodology and other methods showed good agreement for fuels with 90% distillation temperatures less than 600/sup 0/ F. However, this round robin study showed that: 1) there is no standard method to measure aromatic levels in full boiling range diesel fuels, and 2) there are inadequacies when using the D1319 and modified D1319 methods for fuels outside of the specified property ranges.

  4. Aromatic hydrocarbon metabolism by Rhodococcus sp. I24 : computational, biochemical and transcriptional analysis

    E-Print Network [OSTI]

    Parker, Jefferson A. (Jefferson Alexander), 1974-

    2004-01-01T23:59:59.000Z

    Rhodococcus sp. 124 is a Gram-positive soil bacterium being developed for the manufacture of (-)cis-(1S,2R)-1-aminoindan-2-ol, a key precursor in the production of the HIV-1 protease inhibitor CrixivanTM, from the aromatic ...

  5. Rediscovering the Wheel. Thermochemical Analysis of Energetics of the Aromatic Diazines

    E-Print Network [OSTI]

    Chickos, James S.

    calorimetry and vapor pressure measurements. The gas and condensed phase enthalpies of formation of the parent not the case for diazabenzenes. The previous comprehensive experimental study of both the condensed and gasRediscovering the Wheel. Thermochemical Analysis of Energetics of the Aromatic Diazines Sergey P

  6. J. Mol. Biol. (1988) 201, 751-754 Aromatic Rings Act as Hydrogen

    E-Print Network [OSTI]

    Levitt, Michael

    J. Mol. Biol. (1988) 201, 751-754 Aromatic Rings Act as Hydrogen Bond Acceptors Michael Levitt that there is a significant interaction between a hydrogen bond donor (like the > NH group) and the centre of a benzene ring, which acts as a hydrogen bond acceptor. This interaction, hvdrogen bond, which is about half as strong

  7. Low temperature formation of naphthalene and its role in the synthesis of PAHs (Polycyclic Aromatic

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Hydrocarbons) in the interstellar medium Dorian S. N. Parkera , Fangtong Zhanga , Y. Seol Kima , Ralf I, and approved October 26, 2011 (received for review August 24, 2011) Polycyclic aromatic hydrocarbons (PAHs finding challenges conventional wisdom that PAH-formation only occurs at high temperatures

  8. Technical support for the Ohio Clean Coal Technology Program. Volume 2, Baseline of knowledge concerning process modification opportunities, research needs, by-product market potential, and regulatory requirements: Final report

    SciTech Connect (OSTI)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

    1989-08-28T23:59:59.000Z

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LR1 and comprises two volumes. Volume 1 presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume 2 consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  9. The third, use of quantum mechanics to evaluate the molecular energy and forces, holds promise for future refinements when applied wholesale,

    E-Print Network [OSTI]

    Sali, Andrej

    for future refinements when applied wholesale, but is already capable of producing valuable insight when

  10. Kinetics of hydrogenation of aromatics determined by carbon-13 NMR for Athabasca bitumen-derived middle distillates

    SciTech Connect (OSTI)

    Yui, S.M.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, Alberta (Canada))

    1987-04-01T23:59:59.000Z

    High aromatics content in middle distillates is detrimental to fuel quality, as shown in such properties as smoke point of jet fuel and cetane number of diesel fuel. In the petroleum and petrochemical industries the yields from fluid catalytic cracking or steam cracking units are adversely affected by high aromatics content in the feedstock. Distillates obtained from oil sand bitumen, heavy oils, or coal liquefaction products are particularly high in aromatics. Reducing the concentration of this class of compounds is important. Aromatics hydrogenation (AHYD) is one option to achieve this result. In the current Syncrude operation a primary objective of hydrotreating is to reduce product sulfur and nitrogen contents; reducing aromatics content is an incidental result. However, the expansion plan currently under study by Syncrude includes further AHYD to improve cetane number. Predicting the product aromatics content is an important issue for this study. In the present study, hydrotreating of five Athabasca-bitumen-derived gas oils was conducted in pilot scale trickle-bed reactors using alumina-based commercial NiMo catalysts. Feedstocks originated from the distillation of virgin bitumen, and from distillates derived from treating bitumen in a fluid coker and hydrocracking pilot plant. Aromatics content was determined by the {sup 13}C NMR method. The previously developed rate equation for AHYD was modified by including power terms for space velocity and hydrogen partial pressure. The data were analyzed using the modified equation.

  11. Feasibility of Detecting Byproducts of Chemical Weapons Manufacturing in Environmental Media: A Preliminary Evaluation

    SciTech Connect (OSTI)

    Davisson, L; Reynolds, J G; Koester, C; Chinn, S C; Maxwell, R S; Love, A H; Viani, B E

    2003-03-01T23:59:59.000Z

    Quantitative information on the environmental transport and fate of organophosphorus nerve agents has been limited to studies conducted at high concentration representative of acute doses (Munroe et al. 1999). Nerve agents have relatively rapidly degradation rates at acute levels, and first order degradation pathways and half-lives have been characterized. However, similar knowledge is lacking in the open literature on the long-term environmental persistence of nerve agents, their manufacturing precursors and byproducts, and their degradation products, particularly at sub-acute or chronic health levels. Although many recent publications reflect low-level detection methods for chemical weapons signature compounds extracted from a variety of different media (e.g. D'Agostino et al., 2001; Kataoka et al., 2001), little of this work answers questions regarding their adsorptive character and chemical persistence. However, these questions are a central theme to both the detection of illegal chemical weapons manufacturing, as well as determining long-term cleanup needs and health risks associated with potential terrorist acts using such agents. Adsorption onto environmental surfaces can enhance the persistence of organophosphorus compounds, particularly with strong chelators like phosphonic acids. In particular, organophosphorus compound adsorption can lead to irreversible binding (e.g. Aubin and Smith, 1992), and current methods of chemical extraction and solid-state detection are challenged to detect them. This may be particularly true if the adsorbed compound is of a low initial concentration because it may be that the most preferred adsorption sites form the strongest bonds. This is particularly true in mixed media having various adsorption domains that adsorb at different rates (e.g. Weber and Huang, 1996). For high enough initial concentrations, sorption sites become saturated and solvent extraction has a relatively high efficiency. It is no surprise that many CW fate studies can report findings using traditional extraction or solid-state methods of detection, since release concentration exceed the capacity of environmental media to adsorb or degrade them. This report documents a test using solid-state {sup 31}P-NMR and GC/MS methods to delineate two adsorbed phosphonates on a uniform silica gel substrate at different concentrations. The test sought to determine the sensitivity of {sup 31}P-NMR detection, delineate adsorption character of the phosphonates, quantify their extraction efficiency using different solvents, and test the phosphonate mobility and photodegradability under short-term idealized conditions. The results show that solid-state detection at the experimental conditions can detect individual phosphonate species down to the 100 ppm level. Sensitivity could be further increased using larger samples and longer collection times. Solvent extraction of the phosphonates from the silica gel showed that a chlorinated solvent (methylene chloride) produced poor recovery for phosphonic acids from the silica gel, whereas methanol used as a solvent achieved high extraction efficiency. The phosphonates used showed strong aqueous mobility in a silica gel column experiment, with a small but significant amount left adsorbed to the substrate. A 96 hour photo-degradation experiment showed no degradation of the compounds.

  12. Polycyclic Aromatic Compounds, 1999, Vol. 13, pp. 191203 r 1999 OPA (Overseas Publishers Association) N.V. Reprints available directly from the publisher Published by license under

    E-Print Network [OSTI]

    Geest, Harm G. van der

    combustion of fossil fuels, in spills or effluents of several industrial activities, oil drilling, refining

  13. Need for refining capacity creates opportunities for producers in Middle East

    SciTech Connect (OSTI)

    Ali, M.S.S. (Bahrain National Oil Co., Awali (Bahrain))

    1994-07-11T23:59:59.000Z

    Oil industry interest in refining has revived in the past few years in response to rising oil consumption. The trend creates opportunities, for countries in the Middle East, which do not own refining assets nearly in proportion to their crude oil reserved. By closing this gap between reserves and refining capacity, the countries can ease some of the instability now characteristic of the oil market. Some major oil producing countries have begun to move downstream. During the 1980s, Venezuela, Kuwait, Saudi Arabia, Libya, and other members of the Organization of Petroleum Exporting Countries acquired refining assets through direct total purchase or joint ventures. Nevertheless, the oil industry remains largely unintegrated, with the Middle East holding two thirds of worldwide oil reserves but only a small share downstream. As worldwide refining capacity swings from a period of surplus toward one in which the need for new capacity will be built. The paper discusses background of the situation, shrinking surplus, investment requirements, sources of capital, and shipping concerns.

  14. Empirical examination of allegations of ''below-cost'' retail selling of gasoline by refiners: Research study No. 038

    SciTech Connect (OSTI)

    Hogarty, T.F.; Lindstrom, P.M.

    1986-10-01T23:59:59.000Z

    It is alleged by some dealers that (major) refiners consistently sell their gasoline through directly operated stations at retail prices below the prices charged to resellers. The results of this examination, involving more than 2000 price comparisons, failed to reveal a single instance where the average monthly retail price at refiner operated stations was below the price charged resellers by refiners. This result obtained not only for all gasoline sales by major refiners, but also for specific grades of gasoline sold by all refiners. Moreover, a large majority of the average monthly price differentials were greater than 6 cents per gallon, and exceeded 10 cents per gallon in a significant number of instances. Thus, the data do not support the allegation of widespread ''below-cost'' selling by refiners through outlets which they own and operate. Therefore, the rationale offered for legislation mandating retail divorcement, or prohibiting ''below-cost'' is not supported by the evidence. 3 figs., 5 tabs.

  15. Automating crystallographic structure solution and refinement of protein–ligand complexes

    SciTech Connect (OSTI)

    Echols, Nathaniel, E-mail: nechols@lbl.gov; Moriarty, Nigel W., E-mail: nechols@lbl.gov; Klei, Herbert E.; Afonine, Pavel V. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720-8235 (United States); Bunkóczi, Gábor [University of Cambridge, Cambridge Institute for Medical Research, Wellcome Trust/MRC Building, Cambridge CB2 0XY (United Kingdom); Headd, Jeffrey J. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720-8235 (United States); McCoy, Airlie J.; Oeffner, Robert D.; Read, Randy J. [University of Cambridge, Cambridge Institute for Medical Research, Wellcome Trust/MRC Building, Cambridge CB2 0XY (United Kingdom); Terwilliger, Thomas C. [Los Alamos National Laboratory, Los Alamos, NM 87545-0001 (United States); Adams, Paul D., E-mail: nechols@lbl.gov [Lawrence Berkeley National Laboratory, Berkeley, CA 94720-8235 (United States); University of California at Berkeley, Berkeley, CA 94720-1762 (United States)

    2014-01-01T23:59:59.000Z

    A software system for automated protein–ligand crystallography has been implemented in the Phenix suite. This significantly reduces the manual effort required in high-throughput crystallographic studies. High-throughput drug-discovery and mechanistic studies often require the determination of multiple related crystal structures that only differ in the bound ligands, point mutations in the protein sequence and minor conformational changes. If performed manually, solution and refinement requires extensive repetition of the same tasks for each structure. To accelerate this process and minimize manual effort, a pipeline encompassing all stages of ligand building and refinement, starting from integrated and scaled diffraction intensities, has been implemented in Phenix. The resulting system is able to successfully solve and refine large collections of structures in parallel without extensive user intervention prior to the final stages of model completion and validation.

  16. Free kick instead of cross-validation in maximum-likelihood refinement of macromolecular crystal structures

    SciTech Connect (OSTI)

    Pražnikar, Jure [Institute Jožef Stefan, Jamova 39, 1000 Ljubljana (Slovenia); University of Primorska, (Slovenia); Turk, Dušan, E-mail: dusan.turk@ijs.si [Institute Jožef Stefan, Jamova 39, 1000 Ljubljana (Slovenia); Center of Excellence for Integrated Approaches in Chemistry and Biology of Proteins, (Slovenia)

    2014-12-01T23:59:59.000Z

    The maximum-likelihood free-kick target, which calculates model error estimates from the work set and a randomly displaced model, proved superior in the accuracy and consistency of refinement of crystal structures compared with the maximum-likelihood cross-validation target, which calculates error estimates from the test set and the unperturbed model. The refinement of a molecular model is a computational procedure by which the atomic model is fitted to the diffraction data. The commonly used target in the refinement of macromolecular structures is the maximum-likelihood (ML) function, which relies on the assessment of model errors. The current ML functions rely on cross-validation. They utilize phase-error estimates that are calculated from a small fraction of diffraction data, called the test set, that are not used to fit the model. An approach has been developed that uses the work set to calculate the phase-error estimates in the ML refinement from simulating the model errors via the random displacement of atomic coordinates. It is called ML free-kick refinement as it uses the ML formulation of the target function and is based on the idea of freeing the model from the model bias imposed by the chemical energy restraints used in refinement. This approach for the calculation of error estimates is superior to the cross-validation approach: it reduces the phase error and increases the accuracy of molecular models, is more robust, provides clearer maps and may use a smaller portion of data for the test set for the calculation of R{sub free} or may leave it out completely.

  17. Studies on design of a process for organo-refining of coal to obtain super clean coal

    SciTech Connect (OSTI)

    Sharma, C.S.; Sharma, D.K. [Indian Inst. of Tech., New Delhi (India). Centre for Energy Studies

    1999-08-01T23:59:59.000Z

    Organo-refining of coal results in refining the coal to obtain super clean coal and residual coal. Super clean coal may be used to obtain value added chemicals, products, and cleaner fuels from coal. In the present work, studies on the design of a semicontinuous process for organo-refining of one ton of coal have been made. The results are reported. This is only a cursory attempt for the design, and further studies may be required for designing this process for use in the development of a scaled-up process of organo-refining of coal.

  18. ,"Motor Gasoline Sales to End Users, Total Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventional Gasoline Sales to End Users, Total Refiner Sales Volumes"forUsers, Total Refiner

  19. ,"U.S. Conventional Gasoline Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventional Gasoline Sales to End Users, Total Refiner SalesConventional Gasoline Refiner Sales

  20. ,"U.S. Conventional, Average Refiner Gasoline Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventional Gasoline Sales to End Users, Total Refiner SalesConventional Gasoline Refiner

  1. Long-Range Atmospheric Transport of Polycyclic Aromatic Hydrocarbons: A Global 3-D Model Analysis Including Evaluation of Arctic Sources

    E-Print Network [OSTI]

    Friedman, Carey

    We use the global 3-D chemical transport model GEOS-Chem to simulate long-range atmospheric transport of polycyclic aromatic hydrocarbons (PAHs). To evaluate the model’s ability to simulate PAHs with different volatilities, ...

  2. Effectiveness of in site biodegradation for the remediation of polycyclic aromatic hydrocarbons at a contaminated oil refinery, Port Arthur, Texas

    E-Print Network [OSTI]

    Moffit, Alfred Edward

    2000-01-01T23:59:59.000Z

    The effectiveness of bioremediation for the removal of polycyclic aromatic hydrocarbons (PAHs) from sediments contaminated with highly weathered petroleum was evaluated at a contaminated oil refinery. The sediments were chronically contaminated...

  3. Assessing the Influence of Secondary Organic versus Primary Carbonaceous Aerosols on Long-Range Atmospheric Polycyclic Aromatic Hydrocarbon Transport

    E-Print Network [OSTI]

    Pierce, J. R.

    We use the chemical transport model GEOS-Chem to evaluate the hypothesis that atmospheric polycyclic aromatic hydrocarbons (PAHs) are trapped in secondary organic aerosol (SOA) as it forms. We test the ability of three ...

  4. Estimated IR and phosphorescence emission fluxes for specific Polycyclic Aromatic Hydrocarbons in the Red Rectangle

    E-Print Network [OSTI]

    G. Mulas; G. Malloci; C. Joblin; D. Toublanc

    2005-09-20T23:59:59.000Z

    Following the tentative identification of the blue luminescence in the Red Rectangle by Vijh et al. (2005), we compute absolute fluxes for the vibrational IR emission and phosphorescence bands of three small polycyclic aromatic hydrocarbons. The calculated IR spectra are compared with available ISO observations. A subset of the emission bands are predicted to be observable using presently available facilities, and can be used for an immediate, independent, discriminating test on their alleged presence in this well-known astronomical object.

  5. New avenues in the directed deprotometallation of aromatics: recent advances in directed cupration

    E-Print Network [OSTI]

    Harford, Philip J.; Peel, Andrew J.; Chevallier, Floris; Takita, Ryo; Mongin, Florence; Uchiyama, Masanobu; Wheatley, Andrew E. H.

    2014-06-04T23:59:59.000Z

    )–Li interactions. #1; Figure 1 The first solid-state evidence for lithium cyanocuprate structures was revealed by ion-separated 5 and the polymer of 6. #1; Scheme 1 Formation of the dimer of Lipshutz bis(amido)cuprate 7. The issue of cyanide... by which to effect the regioselective functionalization of aromatics.#2; Historically, bases such as organolithiums and lithium dialkylamides have typically been employed for this purpose. However, either because they are highly polar or because...

  6. Phototoxicity of non-carcinogenic polycyclic aromatic hydrocarbons in aquatic organisms

    SciTech Connect (OSTI)

    Kagan, J.; Kagan, E.D.; Kagan, I.A.; Kagan, P.A.; Quigley, S.

    1985-01-01T23:59:59.000Z

    Anthracene, fluoranthene, and pyrene are phototoxic in Daphnia magna, Artemia salina, first instar larvae of Aedes aegypti, late embryonic forms of Rana pipiens, and fish (Pimephales promelas). Since polycyclic aromatic hydrocarbons are generated in the combustion processes held responsible for the damages of acid rain, and they are introduced into the environment through other means as well, the high phototoxicity of the major pollutants, which are not carcinogenic, suggests that greater attention must be given to their environmental significance.

  7. Broad specificity dioxygenase enzymes and the bioremediation of hazardous aromatic pollutants

    SciTech Connect (OSTI)

    Bonus, P.A.; Nies, L. [Purdue Univ., West Lafayette, IN (United States)

    1996-11-01T23:59:59.000Z

    The release of aromatic compounds to the environment is a major source of global pollution. In particular, the contamination of soil and groundwater with benzene, toluene, and xylenes (BTX) is the most ubiquitous form of aromatic pollution. The major source of BTX contamination is the release of gasoline and other petroleum products. This research focused on the improvement of bioremediation of BTX through a better understanding of broad specificity dioxygenase enzymes produced by soil and sediment bacteria. The investigation utilized pure bacterial strains isolated on biphenyl, naphthalene, or toluene. These isolated aerobic bacteria were then used to investigate the specificity of the initial enzymatic attack on aromatic compounds including BTX and polychlorinated biphenyls (PCBs). The enzymatic specificity and competency of the five isolates selected for study were determined through the use of growth tests and two rapid assay techniques. The growth tests were conducted on mineral agar plates or in liquid cultures, and they were used to determine substrate specificity. In addition, rapid assays for both BTX and PCBs were carried out using various growth substrates. These assays allowed further clarification of the specificity of the dioxygenase enzymes involved in aromatic degradation. Preliminary results of the PCB assay show that biphenyl and naphthalene isolated organisms grown on biphenyl, benzoate, naphthalene, and succinate maintain production of broad specificity dioxygenase enzymes able to degrade PCBs. Likewise, the BTX assay confirms that biphenyl and naphthalene selected organisms grown on their respective selection substrates completely degrade BTX including all three xylene isomers. In comparison, the toluene selected organism that was studied was unable to degrade PCBs, but it was able to degrade all BTX constituents.

  8. Catalytic oxidation of 2-aminophenols and ortho hydroxylation of aromatic amines by tyrosinase

    SciTech Connect (OSTI)

    Toussaint, O.; Lerch, K.

    1987-12-29T23:59:59.000Z

    The usual substrates of tyrosinase, a copper-containing monooxygenase (EC 1.14.18.1), are monophenols and o-diphenols which are both converted to o-quinones. In this paper, the authors studied the reaction of this enzyme with two new classes of substrates: aromatic amines and o-aminophenols, structural analogues of monophenols and o-diphenols, respectively. They undergo the same catalytic reactions (ortho hydroxylation and oxidation), as documented by product analysis and kinetic studies. In the presence of tyrosinase, arylamines and o-aminophenols are converted to o-quinone imines, which are isolated as quinone anils or phenoxazones. As an example, in the presence of tyrosinase, 2-amino-3-hydroxybenzoic acid (an o-aminophenol) is converted to cinnabarinic acid, a well-known phenoxazone, while p-aminotoluene (an aromatic amine) gives rise to the formation of 5-amino-2-methyl-1,4-benzoquinone 1-(4-methylanil). Kinetic studies using an oxygen electrode show that arylamines and the corresponding monophenols exhibit similar Michaelis constants. In contrast, the reaction rates observed for aromatic amines are relatively slow as compared to monophenols. The enzymatic conversion of arylamines by tryosinase is different from the typical ones: N-oxidation and ring hydroxylation without further oxidation. This difference originates from the regiospecific hydroxylation (ortho position) and subsequent oxidation of the intermediate o-aminophenol to the corresponding o-quinone imine. Finally, the well-know monooxygenase activity of tyrosinase was also confirmed for the aromatic amine p-aminotoluene, with /sup 18/O/sub 2/.

  9. Modification of the EIC hydrogen sulfide abatement process to produce valuable by-products. Final report, May 4, 1981-May 4, 1982

    SciTech Connect (OSTI)

    Offenhartz, P. O'D.

    1982-06-01T23:59:59.000Z

    A program of analytical and experimental studies has been carried out to develop modifications of the CUPROSUL process for the desulfurization of geothermal steam. The objective of the program was to devise practical means to manipulate the chemistry of the process so that the consumption of raw materials could be controlled and a variety of valuable by-products could be produced. The process had been demonstrated, at one-tenth commercial scale, for steam of the Geysers' average composition in a configuration which resulted in essentially complete oxidation of sulfide to sulfate. The ability to control the extent of oxidation would increase process flexibility and extend its range of applicability to steams of widely varying composition. Preliminary market surveys of raw materials required for the process and by-products which could be produced indicated that controlling the oxidation of sulfides to produce elemental sulfur would probably be the preferred process option. Use of lime to treat sulfate-containing purge streams to produce by-product gypsum and ammonia for recycle or sale could also be justified for certain steam compositions. Recovery of ammonium sulfate alone from the purge stream would not normally be justified unless corecovery of other valuable by-products, such as boric acid, was possible at incremental cost. It was found that ferric sulfate was a highly effective, selective oxidant for the controlled oxidation of copper sulfide solids to produce elemental sulfur for sale and copper sulfate for recycle.

  10. Federal/Industry Development of Energy-Conserving Technologies for the Chemical and Petroleum Refining Industries 

    E-Print Network [OSTI]

    Alston, T. G.; Humphrey, J. L.

    1981-01-01T23:59:59.000Z

    Argonne National Laboratory has started a program to identify future RD&D projects that (i) promise cost-effective savings of scarce fuels in the chemical and petroleum refining industries, (ii) are not likely to be pursued by industry alone...

  11. EIS-0069: Solvent Refined Coal-II Demonstration Project, Fort Martin, Monongalia County, West Virginia

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to assess the potential environmental, economic and social impacts associated with the construction and short-term operation of a 6,000-tons-per-stream-day-capacity facility that will demonstrate the technical operability, economic viability, and environmental acceptability of the solvent refined coal process at Fort Martin, West Virginia.

  12. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    35.2 213.6 9.5 9.8 12.9 16.6 NA 29.5 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  13. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    71.6 92.3 78.2 101.8 83.6 87.5 74.7 See footnotes at end of table. A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District, and State, 1984-Present 452 Energy Information...

  14. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.2 68.5 90.1 89.6 82.4 70.9 NA 75.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  15. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    - 4.9 0.4 0.4 0.3 0.4 - 0.7 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  16. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    61.5 67.3 89.8 89.5 82.2 69.4 71.1 74.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  17. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    33.9 215.8 9.7 10.0 12.1 16.3 0.0 28.4 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  18. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    W 5.6 0.5 0.5 0.5 0.4 - 0.9 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  19. The Nekrasov-Okounkov hook length formula: refinement, elementary proof, extension and applications

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2008/05/09 The Nekrasov-Okounkov hook length formula: refinement, elementary proof, extension and applications Guo-Niu HAN ABSTRACT. -- The paper is devoted to the derivation of the expan- sion formula function for t-cores. Several applications are derived, including the "marked hook formula". 1

  20. Three Dimensional Adaptive Mesh Refinement on a Spherical Shell for Atmospheric Models with Lagrangian Coordinates

    E-Print Network [OSTI]

    Jablonowski, Christiane

    Three Dimensional Adaptive Mesh Refinement on a Spherical Shell for Atmospheric Models for Atmospheric Research 1. Introduction One of the most important advances needed in global climate models of this project is a parallel adaptive grid library, which is currently under development at the University

  1. Tools for macromolecular model building and refinement into electron cryo-microscopy reconstructions

    SciTech Connect (OSTI)

    Brown, Alan; Long, Fei; Nicholls, Robert A.; Toots, Jaan; Emsley, Paul; Murshudov, Garib, E-mail: garib@mrc-lmb.cam.ac.uk [MRC Laboratory of Molecular Biology, Francis Crick Avenue, Cambridge CB2 0QH (United Kingdom)

    2015-01-01T23:59:59.000Z

    A description is given of new tools to facilitate model building and refinement into electron cryo-microscopy reconstructions. The recent rapid development of single-particle electron cryo-microscopy (cryo-EM) now allows structures to be solved by this method at resolutions close to 3 Ć. Here, a number of tools to facilitate the interpretation of EM reconstructions with stereochemically reasonable all-atom models are described. The BALBES database has been repurposed as a tool for identifying protein folds from density maps. Modifications to Coot, including new Jiggle Fit and morphing tools and improved handling of nucleic acids, enhance its functionality for interpreting EM maps. REFMAC has been modified for optimal fitting of atomic models into EM maps. As external structural information can enhance the reliability of the derived atomic models, stabilize refinement and reduce overfitting, ProSMART has been extended to generate interatomic distance restraints from nucleic acid reference structures, and a new tool, LIBG, has been developed to generate nucleic acid base-pair and parallel-plane restraints. Furthermore, restraint generation has been integrated with visualization and editing in Coot, and these restraints have been applied to both real-space refinement in Coot and reciprocal-space refinement in REFMAC.

  2. Grain refinement and texture development of cast bi90sb10 alloy via severe plastic deformation

    E-Print Network [OSTI]

    Im, Jae-taek

    2009-05-15T23:59:59.000Z

    The purpose of this work was to study learn about grain refinement mechanisms and texture development in cast n-type Bi90Sb10 alloy caused by severe plastic deformation. The practical objective is to produce a fine grained and textured...

  3. Proceedings of the conference on electron beam melting and refining - state of the art 1996

    SciTech Connect (OSTI)

    Bakish, R. [ed.

    1996-12-31T23:59:59.000Z

    This conference proceedings summarizes state-of-the-art work in the field of electron-beam melting and refining, as presented at the 1996 conference. Papers are grouped as follows: invited papers; tutorial papers; electron beam melting related fundamentals; electron beam evaporation papers; and miscellaneous papers. Separate abstracts have been submitted to the energy database for some contributions to this proceedings.

  4. REFINING AND MAINTAINING THE OPTIMAL PERFORMANCE OF THE CEBAF SRF SYSTEMS *

    E-Print Network [OSTI]

    REFINING AND MAINTAINING THE OPTIMAL PERFORMANCE OF THE CEBAF SRF SYSTEMS * C. Reece, J. Benesch CEBAF at Jefferson Lab is striving to achieve its maximum reliability at the maximum deliverable energy beam time when CEBAF is run near its maximum energy. Operation at increased rf power levels has

  5. Rocky Mountain area petroleum product availability with reduced PADD IV refining capacity

    SciTech Connect (OSTI)

    Hadder, G.R.; Chin, S.M.

    1994-02-01T23:59:59.000Z

    Studies of Rocky Mountain area petroleum product availability with reduced refining capacity in Petroleum Administration for Defense IV (PADD IV, part of the Rocky Mountain area) have been performed with the Oak Ridge National Laboratory Refinery Yield Model, a linear program which has been updated to blend gasolines to satisfy constraints on emissions of nitrogen oxides and winter toxic air pollutants. The studies do not predict refinery closures in PADD IV. Rather, the reduced refining capacities provide an analytical framework for probing the flexibility of petroleum refining and distribution for winter demand conditions in the year 2000. Industry analysts have estimated that, for worst case scenarios, 20 to 35 percent of PADD IV refining capacity could be shut-down as a result of clean air and energy tax legislation. Given these industry projections, the study scenarios provide the following conclusions: The Rocky Mountain area petroleum system would have the capability to satisfy winter product demand with PADD IV refinery capacity shut-downs in the middle of the range of industry projections, but not in the high end of the range of projections. PADD IV crude oil production can be maintained by re-routing crude released from PADD IV refinery demands to satisfy increased crude oil demands in PADDs II (Midwest), III (Gulf Coast), and Washington. Clean Air Act product quality regulations generally do not increase the difficulty of satisfying emissions reduction constraints in the scenarios.

  6. Protein NMR Structures Refined with Rosetta Have Higher Accuracy Relative to Corresponding Xray Crystal Structures

    E-Print Network [OSTI]

    Baker, David

    refinement of protein NMR structures was also compared with restrained CS-Rosetta calculations. For proteins spectroscopy (NMR). While X-ray crystal structures are derived from electron density data and are often dynamics and has the advantage of not requiring crystallization. Solution NMR structure determination

  7. Iterative model-building, structure refinement, and density modification with the PHENIX AutoBuild Wizard

    SciTech Connect (OSTI)

    Los Alamos National Laboratory, Mailstop M888, Los Alamos, NM 87545, USA; Lawrence Berkeley National Laboratory, One Cyclotron Road, Building 64R0121, Berkeley, CA 94720, USA; Department of Haematology, University of Cambridge, Cambridge CB2 0XY, England; Terwilliger, Thomas; Terwilliger, T.C.; Grosse-Kunstleve, Ralf Wilhelm; Afonine, P.V.; Moriarty, N.W.; Zwart, P.H.; Hung, L.-W.; Read, R.J.; Adams, P.D.

    2007-04-29T23:59:59.000Z

    The PHENIX AutoBuild Wizard is a highly automated tool for iterative model-building, structure refinement and density modification using RESOLVE or TEXTAL model-building, RESOLVE statistical density modification, and phenix.refine structure refinement. Recent advances in the AutoBuild Wizard and phenix.refine include automated detection and application of NCS from models as they are built, extensive model completion algorithms, and automated solvent molecule picking. Model completion algorithms in the AutoBuild Wizard include loop-building, crossovers between chains in different models of a structure, and side-chain optimization. The AutoBuild Wizard has been applied to a set of 48 structures at resolutions ranging from 1.1 {angstrom} to 3.2 {angstrom}, resulting in a mean R-factor of 0.24 and a mean free R factor of 0.29. The R-factor of the final model is dependent on the quality of the starting electron density, and relatively independent of resolution.

  8. Iterative model building, structure refinement and density modification with the PHENIX AutoBuild wizard

    SciTech Connect (OSTI)

    Terwilliger, Thomas C., E-mail: terwilliger@lanl.gov [Los Alamos National Laboratory, Mailstop M888, Los Alamos, NM 87545 (United States); Grosse-Kunstleve, Ralf W.; Afonine, Pavel V.; Moriarty, Nigel W.; Zwart, Peter H. [Lawrence Berkeley National Laboratory, One Cyclotron Road, Building 64R0121, Berkeley, CA 94720 (United States); Hung, Li-Wei [Los Alamos National Laboratory, Mailstop M888, Los Alamos, NM 87545 (United States); Read, Randy J. [Department of Haematology, University of Cambridge, Cambridge CB2 0XY (United Kingdom); Adams, Paul D., E-mail: terwilliger@lanl.gov [Lawrence Berkeley National Laboratory, One Cyclotron Road, Building 64R0121, Berkeley, CA 94720 (United States); Los Alamos National Laboratory, Mailstop M888, Los Alamos, NM 87545 (United States)

    2008-01-01T23:59:59.000Z

    The highly automated PHENIX AutoBuild wizard is described. The procedure can be applied equally well to phases derived from isomorphous/anomalous and molecular-replacement methods. The PHENIX AutoBuild wizard is a highly automated tool for iterative model building, structure refinement and density modification using RESOLVE model building, RESOLVE statistical density modification and phenix.refine structure refinement. Recent advances in the AutoBuild wizard and phenix.refine include automated detection and application of NCS from models as they are built, extensive model-completion algorithms and automated solvent-molecule picking. Model-completion algorithms in the AutoBuild wizard include loop building, crossovers between chains in different models of a structure and side-chain optimization. The AutoBuild wizard has been applied to a set of 48 structures at resolutions ranging from 1.1 to 3.2 Ć, resulting in a mean R factor of 0.24 and a mean free R factor of 0.29. The R factor of the final model is dependent on the quality of the starting electron density and is relatively independent of resolution.

  9. NWS Product Definition Document (PDD) for: Refinement of SPC Experimental Enhanced Resolution Thunderstorm Outlook

    E-Print Network [OSTI]

    NWS Product Definition Document (PDD) for: Refinement of SPC Experimental Enhanced Resolution replaces an existing PDD, whose evaluation period expired on 15 February 2008, and revises the current SPC will also evaluate changes in the distribution of SPC forecaster workload and the ability to maintain

  10. Most of the world's titanium output is refined into titanium dioxide (TiO2

    E-Print Network [OSTI]

    Torgersen, Christian

    Most of the world's titanium output is refined into titanium dioxide (TiO2 ), which is used to give.S. Geological Survey (USGS) supports science to understand · How and where titanium resources form and concentrate in the Earth's crust · How titanium resources interact with the environment to affect human

  11. Use of Lung Transplantation Survival Models to Refine Patient Selection in Cystic Fibrosis

    E-Print Network [OSTI]

    Adler, Fred

    Use of Lung Transplantation Survival Models to Refine Patient Selection in Cystic Fibrosis Theodore Angeles, California Lung transplantation in cystic fibrosis may improve survival for patients with low 5 and United Network for Organ Sharing data, we identified 845 lung transplant recipients from 1991

  12. Soundness and Separability of Workflow Nets in the Stepwise Refinement Approach

    E-Print Network [OSTI]

    Sidorova, Natalia

    Soundness and Separability of Workflow Nets in the Stepwise Refinement Approach Kees van Hee.sidorova@tue.nl, wsinmarc@win.tue.nl Abstract. Workflow nets are recognized as a modelling paradigm for the business process modelling. We introduce and investigate several cor- rectness notions for workflow nets, ranging from proper

  13. Soundness and Separability of Workflow Nets in the Stepwise Refinement Approach

    E-Print Network [OSTI]

    Sidorova, Natalia

    Soundness and Separability of Workflow Nets in the Stepwise Refinement Approach Kees van Hee.sidorova@tue.nl, wsinmarc@win.tue.nl Abstract. Workflow nets are recognized as a modelling paradigm for the business process modelling. We introduce and investigate several cor­ rectness notions for workflow nets, ranging from proper

  14. A Pareto-Optimal Refinement Method for Protein Design Lucas Gregorio Nivo n1.

    E-Print Network [OSTI]

    Baker, David

    Moretti1. , David Baker1,2 * 1 Department of Biochemistry, University of Washington, Seattle, Washington, United States of America, 2 Howard Hughes Medical Institute (HHMI), University of Washington, Seattle for functional site design. Citation: NivoŽn LG, Moretti R, Baker D (2013) A Pareto-Optimal Refinement Method

  15. Refinement of weed risk assessments for biofuels using Camelina sativa as a model species

    E-Print Network [OSTI]

    Peterson, Robert K. D.

    Refinement of weed risk assessments for biofuels using Camelina sativa as a model species Philip B and Environmental Sciences, Montana State University, PO Box 173120, Bozeman, MT 59717-3120, USA Summary 1. Biofuel. However, concerns have been raised on the invasiveness of biofuel feedstocks. Estimating invasion

  16. Nonrigid Motion Analysis Based on Dynamic Refinement of Finite Element Models

    E-Print Network [OSTI]

    Sarkar, Sudeep

    Nonrigid Motion Analysis Based on Dynamic Refinement of Finite Element Models Leonid V. Tsap finite element models. The method is based on the iterative analysis of the differences betweenÐPhysically-based vision, deformable models, nonrigid motion analysis, biomedical applications, finite element analysis. Ê

  17. Environmental Regulations and Changes in Petroleum Refining Operations (Released in the STEO June 1998)

    Reports and Publications (EIA)

    1998-01-01T23:59:59.000Z

    Changes in domestic refining operations are identified and related to the summer Reid vapor pressure (RVP) restrictions and oxygenate blending requirements. This analysis uses published Energy Information Administration survey data and linear regression equations from the Short-Term Integrated Forecasting System (STIFS). The STIFS model is used for producing forecasts appearing in the Short-Term Energy Outlook.

  18. A Characteristic Domain Decomposition and SpaceTime Local Refinement Method for

    E-Print Network [OSTI]

    Sharpley, Robert

    partial differential equations model the reactive transport of solutes in groundwater and surface water with other domain decomposition and local refinement schemes. 1 Introduction First­order linear hyperbolic interfaces that introduce extra difficulties. Physical interfaces arise, for example, in the modeling

  19. A Characteristic Domain Decomposition and SpaceTime Local Refinement Method for

    E-Print Network [OSTI]

    South Carolina, University of

    model the reactive transport of solutes in groundwater and surface water, the movement of aerosols and local refinement schemes. 1 Introduction First­order linear hyperbolic partial differential equations that introduce extra difficulties. Physical interfaces arise, for example, in the modeling of transport processes

  20. A Characteristic Domain Decomposition and Space Time Local Refinement Method for

    E-Print Network [OSTI]

    Sharpley, Robert

    cause severe numerical difficulties [1­5]. Conventional finite difference or finite element methods­Lagrangian methods; linear hyperbolic problems; local refinement techniques I. INTRODUCTION First-order linear hyperbolic partial differential equations model the reactive transport of solutes in groundwater and surface