National Library of Energy BETA

Sample records for refinery gases pentanes

  1. Refinery Yield of Liquefied Refinery Gases

    U.S. Energy Information Administration (EIA) Indexed Site

    Refinery Yield (Percent) Product: Liquefied Refinery Gases Finished Motor Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Residual Fuel Oil Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Still Gas Miscellaneous Products Processing Gain(-) or Loss(+) Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes

  2. Refinery & Blenders Net Input of Crude Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished

  3. Refinery & Blender Net Production of Total Finished Petroleum...

    U.S. Energy Information Administration (EIA) Indexed Site

    & Blender Net Production Product: Total Finished Petroleum Products Liquefied Refinery Gases EthaneEthylene Ethane Ethylene PropanePropylene Propane Propylene Normal Butane...

  4. U.S. Refinery

    Gasoline and Diesel Fuel Update (EIA)

    Crude Oil and Petroleum Products 347,764 351,758 354,511 354,703 353,837 349,090 1993-2015 Crude Oil 99,146 101,838 102,678 105,923 101,530 100,805 1981-2015 All Oils (Excluding Crude Oil) 248,618 249,920 251,833 248,780 252,307 248,285 1993-2015 Pentanes Plus 877 682 778 711 1,018 718 1993-2015 Liquefied Petroleum Gases 16,246 18,334 18,650 18,308 16,631 14,329 1993-2015 Ethane/Ethylene 70 138 190 215 135 86 1993-2015 Propane/Propylene 3,949 4,665 4,567 4,837 5,033 4,107 1993-2015 Normal

  5. U.S. Refinery

    U.S. Energy Information Administration (EIA) Indexed Site

    Crude Oil and Petroleum Products 339,907 336,327 341,211 326,400 343,792 349,090 1993-2015 Crude Oil 88,982 90,640 88,781 85,114 95,794 100,805 1981-2015 All Oils (Excluding Crude Oil) 250,925 245,687 252,430 241,286 247,998 248,285 1993-2015 Pentanes Plus 971 895 884 564 580 718 1993-2015 Liquefied Petroleum Gases 14,896 14,429 15,934 11,693 15,100 14,329 1993-2015 Ethane/Ethylene 220 223 214 93 150 86 1993-2015 Propane/Propylene 4,278 4,087 4,574 2,831 4,652 4,107 1993-2015 Normal

  6. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mary Biddy Sue Jones NREL PNNL This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Refinery Integration 4.1.1.31 NREL 4.1.1.51 PNNL Goal Statement GOALS: Model bio-intermediates insertion points to better define costs & ID opportunities, technical risks, information gaps, research needs Publish results Review with stakeholders 2 Leveraging existing refining infrastructure

  7. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Commodity PAD Districts I II III IV V United States Table 10a. Fuel Consumed at Refineries by PAD District, 2014 (Thousand Barrels, Except Where Noted) Crude Oil 0 0 0 0 0 0 Liquefied Petroleum Gases 0 1,348 421 23 513 2,305 Distillate Fuel Oil 0 33 174 0 102 309 Residual Fuel Oil 3 23 28 13 346 413 Still Gas 15,174 48,972 110,958 8,749 46,065 229,918 Marketable Petroleum Coke 0 0 0 493 143 636 Catalyst Petroleum Coke 8,048 16,837 44,599 2,925 12,482 84,891 Natural Gas (million cubic feet)

  8. Refinery Capacity Report

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 9 Shell Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 10...

  9. Pentan isomers compound flame front structure

    SciTech Connect (OSTI)

    Mansurov, Z.A.; Mironenko, A.W.; Bodikov, D.U.; Rachmetkaliev, K.N.

    1995-08-13

    The fuels (hexane, pentane, diethyl ether) and conditions investigated in this study are relevant to engine knock in spark- ignition engines. A review is provided of the field of low temperature hydrocarbon oxidation. Studies were made of radical and stable intermediate distribution in the front of cool flames: Maximum concentrations of H atoms and peroxy radicals were observed in the luminous zone of the cool flame front. Peroxy radicals appear before the luminous zone at 430 K due to diffusion. H atoms were found in cool flames of butane and hexane. H atoms diffuses from the luminous zone to the side of the fresh mixture, and they penetrate into the fresh mixture to a small depth. Extension of action sphear of peroxy radicals in the fresh mixture is much greater than that of H atoms due to their small activity and high concentrations.

  10. U.S. Refinery Net Production

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    12,813 12,516 12,287 12,009 12,148 11,916 2005-2014 Liquefied Refinery Gases 623 659 619 630 623 653 2005-2014 EthaneEthylene 19 20 20 18 7 6 2005-2014 Ethane 14 14 14 13 7 5...

  11. Refinery Capacity Report

    Reports and Publications (EIA)

    2015-01-01

    Data series include fuel, electricity, and steam purchased for consumption at the refinery; refinery receipts of crude oil by method of transportation; and current and projected atmospheric crude oil distillation, downstream charge, and production capacities. Respondents are operators of all operating and idle petroleum refineries (including new refineries under construction) and refineries shut down during the previous year, located in the 50 states, the District of Columbia, Puerto Rico, the Virgin Islands, Guam, and other U.S. possessions. The Refinery Capacity Report does not contain working and shell storage capacity data. This data is now being collected twice a year as of March 31 and September 30 on the Form EIA-810, "Monthly Refinery Report", and is now released as a separate report Working and Net Available Shell Storage Capacity.

  12. Total Blender Net Input of Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Input Product: Total Input Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquid Petroleum Gases Normal Butane Isobutane Other Liquids OxygenatesRenewables ...

  13. Refinery Stocks of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    Product: Crude Oil and Petroleum Products Crude Oil Petroleum Products Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils

  14. U.S. Refinery Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 4,178,588 4,091,601 4,007,375 4,037,265 3,954,862 3,894,471 2005-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 5,915,532 2005-2015 Natural Gas Plant Liquids 154,941 171,074 175,607 168,808 172,563 171,936 2005-2015 Pentanes Plus 54,697 61,059 59,432 56,153 52,853 50,850 2005-2015 Liquefied Petroleum Gases 100,244 110,015 116,175 112,655 119,710 121,086 2005-2015 Normal Butane 39,253 42,087 45,747 42,461 45,916 47,870 2005-2015

  15. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    18,452 18,673 18,564 19,106 19,654 19,893 1983-2015 Liquefied Refinery Gases 659 619 630 623 653 612 1984-2015 EthaneEthylene 20 20 18 7 6 6 1985-2015 Ethane 14 14 13 7 5 5 ...

  16. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History Total 641,908 639,034 600,775 608,595 595,141 614,837 1981-2015 Liquefied Refinery Gases 26,335 25,920 17,388 13,536 9,912 ...

  17. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    6,735,067 6,815,590 6,794,407 6,973,710 7,173,730 7,260,943 1981-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 223,448 1981-2015 EthaneEthylene 7,228 7,148 ...

  18. Refinery Capacity Report

    Gasoline and Diesel Fuel Update (EIA)

    1 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels per Atmospheric Crude Oil Distillation Capacity Idle Operating Total Operable Refineries Number of State and PAD District a b b 14 10 4 1,617,500 1,205,000 412,500 1,708,500 1,273,500 435,000 ............................................................................................................................................... PAD District I 1 0 1 182,200 0 182,200 190,200 0 190,200

  19. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels per Atmospheric Crude Oil Distillation Capacity Idle Operating Total Operable Refineries Number of State and PAD District a b b 9 9 0 1,268,500 1,236,500 32,000 1,332,000 1,297,000 35,000 ............................................................................................................................................... PAD District I 1 1 0 182,200 182,200 0 190,200 190,200 0

  20. Hydrogen Generation for Refineries

    Office of Environmental Management (EM)

    ADVANCED MANUFACTURING OFFICE PEER REVIEW MEETING May 5-6, 2014 DE-FG02-08ER85135 Hydrogen Generation for Refineries DOE Phase II SBIR Dr. Girish Srinivas P.I. gsrinivas@tda.com 303-940-2321 Dr. Steven Gebhard, P.E. Dr. Robert Copeland Mr. Jeff Martin TDA Research Inc. 1 This presentation does not contain any proprietary, confidential, or otherwise restricted information This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Overview *

  1. Outlook for Refinery Outages and Available Refinery Capacity...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    level of refinery outages outlined in this report. This report does not consider the impacts of refined product logistics and distribution, which could affect the movement of...

  2. U.S. Refinery Yield

    Gasoline and Diesel Fuel Update (EIA)

    Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History Liquefied Refinery Gases 4.9 4.9 3.5 2.8 2.0 2.0 1993-2015 Finished Motor Gasoline 44.5 44.9 45.4 45.7 46.7 47.3 1993-2015 Finished Aviation Gasoline 0.1 0.1 0.1 0.1 0.1 0.1 1993-2015 Kerosene-Type Jet Fuel 9.7 9.4 9.3 9.8 9.8 10.1 1993-2015 Kerosene 0.1 0.1 0.1 0.1 0.1 0.2 1993-2015 Distillate Fuel Oil 29.2 29.6 29.9 30.0 30.3 29.6 1993-2015 Residual Fuel Oil 2.4 2.4 2.5 2.6 2.3 2.2 1993-2015 Naphtha for Petrochemical Feedstock Use 1.0 1.1

  3. U.S. Refinery Yield

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Liquefied Refinery Gases 4.3 4.0 4.1 3.9 4.0 3.7 1993-2015 Finished Motor Gasoline 45.7 44.9 45.0 45.0 45.0 45.3 1993-2015 Finished Aviation Gasoline 0.1 0.1 0.1 0.1 0.1 0.1 1993-2015 Kerosene-Type Jet Fuel 9.3 9.4 9.5 9.5 9.6 9.7 1993-2015 Kerosene 0.1 0.1 0.1 0.1 0.1 0.1 1993-2015 Distillate Fuel Oil 27.5 28.9 29.1 29.5 29.9 29.8 1993-2015 Residual Fuel Oil 3.8 3.4 3.2 2.9 2.7 2.5 1993-2015 Naphtha for Petrochemical Feedstock Use 1.4 1.3 1.3 1.5 1.3

  4. Total Number of Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  5. Storage tracking refinery trends

    SciTech Connect (OSTI)

    Saunders, J.

    1996-05-01

    Regulatory and marketplace shakeups have made the refining and petrochemical industries highly competitive. The fight to survive has forced refinery consolidations, upgrades and companywide restructurings. Bulk liquid storage terminals are following suit. This should generate a flurry of engineering and construction by the latter part of 1997. A growing petrochemical industry translates into rising storage needs. Industry followers forecasted flat petrochemical growth in 1996 due to excessive expansion in 1994 and 1995. But expansion is expected to continue throughout this year on the strength of several products.

  6. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Operable Date of Last Operation Date Shutdown Table 11. New, Shutdown and Reactivated Refineries During 2014 a b NEW PAD District II 19,000 Dakota Prairie Refining LLC Dickinson, ND 19,000 01/15 PAD District III 42,000 Kinder Morgan Crude & Condensate Galena Park, TX 42,000 01/15 SHUTDOWN PAD District I 28,000 0 Axeon Specialty Products LLC Savannah, GA 28,000 0 09/12 12/14 PAD District II 12,000 0 Ventura Refining & Transmission LLC Thomas, OK 12,000 0 10/10 12/14 PAD District III 0

  7. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Former Corporation/Refiner Total Atmospheric Crude Oil Distillation Capacity (bbl/cd) New Corporation/Refiner Date of Sale Table 12. Refinery Sales During 2014 Lindsay Goldberg LLC/Axeon Speciality Products LLC Nustar Asphalt LLC/Nustar Asphalt Refining LLC 2/14 Savannah, GA 28,000 Lindsay Goldberg LLC/Axeon Specialty Products LLC Nustar Asphalt LLC/Nustar Asphalt Refining LLC 2/14 Paulsboro, NJ 70,000 bbl/cd= Barrels per calendar day Sources: Energy Information Administration (EIA) Form

  8. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    District and State Production Capacity Alkylates Aromatics Asphalt and Road Oil Isomers Lubricants Marketable Petroleum Coke Sulfur (short tons/day) Hydrogen (MMcfd) Table 2. Production Capacity of Operable Petroleum Refineries by PAD District and State as of January 1, 2015 (Barrels per Stream Day, Except Where Noted) a 83,429 10,111 26,500 87,665 21,045 21,120 69 1,159 PAD District I Delaware 11,729 5,191 0 6,000 0 13,620 40 596 New Jersey 29,200 0 65,000 4,000 12,000 7,500 26 280 Pennsylvania

  9. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillation Crude Oil Atmospheric Distillation Vacuum Cracking Thermal Catalytic Cracking Fresh Recycled Catalytic Hydro- Cracking Catalytic Reforming Desulfurization Hydrotreating/ Fuels Solvent Deasphalting Downstream Charge Capacity Table 6. Operable Crude Oil and Downstream Charge Capacity of Petroleum Refineries, January 1, 1986 to (Thousand Barrels per Stream Day, Except Where Noted) January 1, 2015 JAN 1, 1986 16,346 6,892 1,880 5,214 463 1,125 3,744 8,791 NA JAN 1, 1987 16,460 6,935

  10. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1986 to January 1, 2015 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1986 941 276 804 258 246 356 2,357 NA JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN

  11. Virginia Biodiesel Refinery | Open Energy Information

    Open Energy Info (EERE)

    Refinery Jump to: navigation, search Name: Virginia Biodiesel Refinery Place: West Point, Virginia Zip: 23180 Product: Biodiesel producer based in Virginia References: Virginia...

  12. Refinery, petrochemical plant injuries decline

    SciTech Connect (OSTI)

    Not Available

    1994-07-25

    The National Petroleum Refiners Association (NPRA) reports a 7% reduction in workplace injury and illness incidence rates for refineries in 1993, and a 21% decrease for petrochemical plants. The report summarizes data from 135 of the 162 US member refineries, and 117 of the 172 US member petrochemical plants. This paper summarizes the report findings.

  13. Reformulated Gasoline Foreign Refinery Rules

    Gasoline and Diesel Fuel Update (EIA)

    Reformulated Gasoline Foreign Refinery Rules Contents * Introduction o Table 1. History of Foreign Refiner Regulations * Foreign Refinery Baseline * Monitoring Imported Conventional Gasoline * Endnotes Related EIA Short-Term Forecast Analysis Products * Areas Participating in the Reformulated Gasoline Program * Environmental Regulations and Changes in Petroleum Refining Operations * Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model * Refiners Switch to Reformulated

  14. Refinery Outages: First Half 2015

    Reports and Publications (EIA)

    2015-01-01

    This report examines refinery outages planned for the first half of 2015 and the potential implications for available refinery capacity, petroleum product markets and supply of gasoline, diesel fuel, and heating oil. The U.S. Energy Information Administration (EIA) believes that dissemination of such analyses can be beneficial to market participants that may otherwise be unable to access such information.

  15. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Cokers Catalytic Crackers Hydrocrackers Capacity Inputs Capacity Inputs Capacity Inputs Table 8. Capacity and Fresh Feed Input to Selected Downstream Units at U.S. Refineries, 2013 - 2015 (Barrels per Calendar Day) Reformers Capacity Inputs 2013 2,596,369 5,681,643 1,887,024 2,302,764 4,810,611 1,669,540 2,600,518 3,405,017 74,900 543,800 41,500 47,537 387,148 33,255 PADD I 162,249 240,550 450,093 1,196,952 303,000 414,732 1,028,003 263,238 PADD II 648,603 818,718 1,459,176 2,928,673 981,114

  16. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Method PAD Districts I II III IV V United States Table 9. Refinery Receipts of Crude Oil by Method of Transportation by PAD District, 2014 (Thousand Barrels) a Pipeline 22,596 1,266,015 1,685,817 168,347 298,886 3,441,661 Domestic 2,632 658,717 1,421,768 82,043 240,522 2,405,682 Foreign 19,964 607,298 264,049 86,304 58,364 1,035,979 Tanker 252,479 0 1,046,008 0 529,319 1,827,806 Domestic 81,055 0 45,006 0 181,307 307,368 Foreign 171,424 0 1,001,002 0 348,012 1,520,438 Barge 39,045 6,360 259,903

  17. Refinery Net Production of Total Finished Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Finished Petroleum Products Liquefied Refinery Gases Ethane/Ethylene Ethane Ethylene Propane/Propylene Propane Propylene Normal Butane/Butylene Normal Butane Butylene Isobutane/Isobutylene Isobutane Isobutylene Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Reformulated Other Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Blended w/ Fuel Ethanol, Greater than Ed55

  18. U.S. Refinery Net Production

    Gasoline and Diesel Fuel Update (EIA)

    Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History Total 379,398 376,546 352,148 350,299 353,077 362,368 2005-2015 Liquefied Refinery Gases 26,335 25,920 17,388 13,536 9,912 10,243 2005-2015 Ethane/Ethylene 188 127 158 202 196 226 2005-2015 Ethane 163 110 133 173 165 194 2005-2015 Ethylene 25 17 25 29 31 32 2005-2015 Propane/Propylene 18,010 17,811 15,869 16,121 16,574 17,905 2005-2015 Propane 8,767 8,530 7,955 7,965 8,303 8,831 2005-2015 Propylene 9,243 9,281 7,914 8,156 8,271 9,074

  19. Grupo Maris Capital ethanol refinery | Open Energy Information

    Open Energy Info (EERE)

    Maris Capital ethanol refinery Jump to: navigation, search Name: Grupo Maris (Capital ethanol refinery) Place: Nuporanga, Brazil Product: 32,000 m3 ethanol refinery owner...

  20. U.S. Refinery Net Input

    Gasoline and Diesel Fuel Update (EIA)

    Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History Total 346,773 340,480 321,878 318,765 321,561 328,213 2005-2015 Crude Oil 523,409 516,507 485,221 479,416 494,682 519,726 2005-2015 Natural Gas Plant Liquids 13,079 13,240 14,690 15,903 17,686 18,057 2005-2015 Pentanes Plus 4,606 4,453 4,693 4,431 3,897 3,932 2005-2015 Liquefied Petroleum Gases 8,473 8,787 9,997 11,472 13,789 14,125 2005-2015 Normal Butane 2,137 1,869 3,144 5,323 7,093 7,560 2005-2015 Isobutane 6,336 6,918 6,853 6,149 6,696

  1. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    7:16:49 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...US1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  2. Motiva Refinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Motiva Refinery May 18, 2006 - 10:45am Addthis Remarks Prepared for Energy Secretary Bodman Much of my time lately has been devoted to explaining why the price of gasoline has risen so sharply. President Bush understands the pinch this is creating for American consumers and has come forward with a variety of steps to address the problem. Rapid economic growth in emerging economies like China and India-and the growth here in the U.S.-have pushed up demand. Political unrest in some

  3. U.S. Refinery Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 4,568,301 4,484,600 4,395,128 4,433,893 4,349,316 4,273,291 2005-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 223,448 2005-2015 Ethane/Ethylene 7,228 7,148 6,597 2,626 2,038 2,134 2005-2015 Ethane 5,200 5,105 4,835 2,439 1,777 1,835 2005-2015 Ethylene 2,028 2,043 1,762 187 261 299 2005-2015 Propane/Propylene 204,223 201,492 202,309 206,038 214,378 203,954 2005-2015 Propane 102,913 98,508 100,933 103,568 111,813 103,253

  4. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect (OSTI)

    Holmgren, Jennifer; Arena, Blaise; Marinangelli, Richard; McCall, Michael; Marker, Terry; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2006-10-11

    a summary of our collaborative 2005 project “Opportunities for Biorenewables in Petroleum Refineries” at the Rio Oil and Gas Conference this September.

  5. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect (OSTI)

    Holmgren, Jennifer; Marinangelli, Richard; Marker, Terry; McCall, Michael; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2007-02-01

    A presentation by UOP based on collaborative work from FY05 using some results from PNNL for upgrading biomass pyrolysis oil to petroleum refinery feedstock

  6. Inorganic Membranes for Refinery Gas Separations

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to push the performance limits of inorganic membranes for large-scale gas separations in refinery applications.

  7. Integrating NABC bio-oil intermediates into the petroleum refinery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrating NABC bio-oil intermediates into the petroleum refinery Integrating NABC bio-oil intermediates into the petroleum refinery Breakout Session 2: Frontiers and Horizons ...

  8. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  9. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  10. Refinery burner simulation design architecture summary.

    SciTech Connect (OSTI)

    Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.

    2011-10-01

    This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.

  11. Innovative filter polishes oil refinery wastewater

    SciTech Connect (OSTI)

    Irwin, J.; Finkler, M.

    1982-07-01

    Describes how, after extensive testing of 4 different treatment techniques, a Hydro Clear rapid sand filter was installed at the Sohio oil refinery in Toledo, Ohio. This filtration system has proven to be more cost-effective than conventional approaches. The system handles the refinery's wastewater flow of 10.3 mgd. With the aid of the polishing filter, readily meets the NPDES permit limitations. The Toledo refinery is a highly integrated petroleum processing complex. It processes 127,000 barrels per day of crude oil, including 40,000 barrels per day of sour crude. Tables give dissolved air flotation performance data; biological system performance data; filter performance data; and refinery waste treatment unit compared with NPDES-BPT limitations. Diagram shows the Sohio refinery wastewater treatment facility. Through a separate backwash treatment system complete control is brought to the suspended solids in the effluent which also tends to control chemical oxygen demand and oil/grease levels.

  12. Former Soviet refineries face modernization, restructuring

    SciTech Connect (OSTI)

    Not Available

    1993-11-29

    A massive modernization and restructuring program is under way in the refining sector of Russia and other former Soviet republics. Economic reforms and resulting economic dislocation following the collapse of the Soviet Union has left refineries in the region grappling with a steep decline and changes in product demand. At the same time, rising oil prices and an aging, dilapidated infrastructure promise a massive shakeout. Even as many refineries in the former Soviet Union (FSU) face possible closure because they are running at a fraction of capacity, a host of revamps, expansions, and grass roots refineries are planned or under way. The paper discusses plans.

  13. From the Woods to the Refinery

    Broader source: Energy.gov [DOE]

    Breakout Session 2D—Building Market Confidence and Understanding II: Carbon Accounting and Woody Biofuels From the Woods to the Refinery Stephen S. Kelley, Principal and Department Head, Department of Forest Biomaterials, North Carolina State University

  14. Iran to build new refinery at Arak

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This paper reports Iranian plans to construct a grassroots 150,000-b/d refinery in Arak. The plant, to be completed in early 1993, will be capable of producing unleaded gasoline and other light products.

  15. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    586-8800",,,"10272015 12:31:05 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" "Sourcekey","MTTRXNUS1","MLPRXNUS1","METRXNUS1","MENRXNUS1","MEYRXNUS1","...

  16. Refinery siting workbook: appendices A and B

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    The objective of this effort is to develop and provide basic refinery-related information for use by state and local government officials as a basis for establishing responsible refinery siting requirements and policies consistent with the federal clean air and water standards and socio-economic concerns. The report will be organized into two volumes. The main text comprises the basic topics of physical concerns, regulatory requirements, and permitting activities, while the second volume includes the detailed appendix materials such as the applicable laws, and the necessary permits, as available and a glossary of pertinent terms. As a means to this objective, three refinery sizes, 200,000, 100,000 and 30,000 barrels per day crude charge will be discussed in technical terms. Process unit configuration will be presented which will maximize either gasoline or heating oil production with either sweet or sour crude oil feedstocks. The major issues affecting the socio-economic impact of siting the refinery in a given locale will be presented. These data will review the factors affecting the human environment and the issues that must be addressed to assess the impact that a refinery will have on a community. The key federal registrations which impact upon a refinery siting decision shall be reviewed. Summaries of these regulations and a simplified decision diagram for the air and water acts shall be presented to assist both government and refinery officials in understanding the scope of regulatory impact. All pertinent procedures required for refinery permitting shall be reviewed under the generalized headings of air, water, health and safety, land use, and miscellaneous permits. This categorization at the federal, state and local levels of government shall be used as a basis for establishing degrees of emphasis.

  17. Myriant Succinic Acid BioRefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    information Myriant Succinic Acid BioRefinery DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Mark Shmorhun, Principal Investigator March 25, 2015 2 Goal Statement * Renewable Succinic Acid Production * A high value bio based chemical derived from renewable feedstocks * Validate proposed technology at a demonstration plant located in Lake Providence, LA. * Nameplate Capacity: 30 million lbs/year 3 Myriant's Succinic Acid BioRefinery (MySAB) Lake Providence , LA 4 The Myriant

  18. A model-free temperature-dependent conformational study of n-pentane in nematic liquid crystals

    SciTech Connect (OSTI)

    Burnell, E. Elliott; Weber, Adrian C. J.; Dong, Ronald Y.; Meerts, W. Leo; Lange, Cornelis A. de

    2015-01-14

    The proton NMR spectra of n-pentane orientationally ordered in two nematic liquid-crystal solvents are studied over a wide temperature range and analysed using covariance matrix adaptation evolutionary strategy. Since alkanes possess small electrostatic moments, their anisotropic intermolecular interactions are dominated by short-range size-and-shape effects. As we assumed for n-butane, the anisotropic energy parameters of each n-pentane conformer are taken to be proportional to those of ethane and propane, independent of temperature. The observed temperature dependence of the n-pentane dipolar couplings allows a model-free separation between conformer degrees of order and conformer probabilities, which cannot be achieved at a single temperature. In this way for n-pentane 13 anisotropic energy parameters (two for trans trans, tt, five for trans gauche, tg, and three for each of gauche{sub +} gauche{sub +}, pp, and gauche{sub +} gauche{sub ?}, pm), the isotropic trans-gauche energy difference E{sub tg} and its temperature coefficient E{sub tg}{sup ?} are obtained. The value obtained for the extra energy associated with the proximity of the two methyl groups in the gauche{sub +} gauche{sub ?} conformers (the pentane effect) is sensitive to minute details of other assumptions and is thus fixed in the calculations. Conformer populations are affected by the environment. In particular, anisotropic interactions increase the trans probability in the ordered phase.

  19. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  20. Where do California's greenhouse gases come from?

    SciTech Connect (OSTI)

    Fischer, Marc

    2009-01-01

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  1. Improved oil refinery operations and cheaper crude oil to help...

    U.S. Energy Information Administration (EIA) Indexed Site

    Improved oil refinery operations and cheaper crude oil to help reduce gasoline prices U.S. gasoline prices are expected to fall as more oil refineries come back on line and crude ...

  2. Refinery Input by PADD - Petroleum Supply Annual (2004)

    SciTech Connect (OSTI)

    2009-01-18

    Table showing refinery input of crude oil and petroleum products by Petroleum Administration for Defense Districts (PADD).

  3. Exergoeconomic analysis of a refinery`s utilities plant: Part II-improvement proposals

    SciTech Connect (OSTI)

    Rivero, R.; Hernandez, R.

    1996-12-31

    A crude oil refinery normally consumes a large amount of energy, not only in the form of the combustion of fossil fuels in the process units, but also in the associated Utilities Plant which produces process steam at different pressure levels and electricity. Energy losses of the utilities plant represent some 40 % of the total refinery`s energy losses. It is then extremely important to evaluate the performance of this plant and the costs to be assigned to the production of steam and electricity as a supplier of energy to the process units. This paper presents the improvement proposals generated by the application of an exergoeconomic analysis to the Utilities Plant of an existing 150,000 BPD crude oil refinery. 2 refs., 7 figs.

  4. Refinery siting workbook: appendices C to O

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

  5. Opportunities for Biorenewables in Oil Refineries

    SciTech Connect (OSTI)

    Marker, T.L.

    2005-12-19

    Abstract: The purpose of this study was to evaluate the potential for using biorenewable feedstocks in oil refineries. Economic analyses were conducted, with support from process modeling and proof of principle experiments, to assess a variety of potential processes and configurations. The study considered two primary alternatives: the production of biodiesel and green diesel from vegetable oils and greases and opportunities for utilization of pyrolysis oil. The study identified a number of promising opportunities for biorenewables in existing or new refining operations.

  6. U.S. Refineries Competitive Positions

    Gasoline and Diesel Fuel Update (EIA)

    Refineries Competitive Positions 2014 EIA Energy Conference July 14, 2014 Joanne Shore American Fuel & Petrochemical Manufacturers Refiners competitive positions Function of optimizing feedstock costs, operating costs, and revenues through mix of products sold 2 Propane/butane Chemicals Gasoline Jet Fuel Diesel/heating oil Lubes Fuel for ships Asphalt FEEDSTOCKS Qualities: - Heavy/Light - Sweet/Sour Location (Distance) - Domestic - International PROCESSING Size Complexity Treating (sulfur)

  7. From the Woods to the Refinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Woods to the Refinery CORRIM Life Cycle Analyses of Woody Feedstocks Dr. Steve Kelley Dr. Elaine Oneil President, CORRIM Executive Director, CORRIM Professor North Carolina State Consortium for Research on Renewable Industrial Materials A non-profit corporation formed by 17 research institutions to conduct cradle to grave environmental studies of wood products * Seventeen years of LCI/LCA work on durable wood products * Biofuel LCI/LCA research support from: * Eight institutions/cooperators

  8. Economic impact analysis for the petroleum refineries NESHAP. Final report

    SciTech Connect (OSTI)

    1995-08-01

    An economic analysis of the industries affected by the Petroleum Refineries National Emmissions Standard for Hazardous Air Pollutants (NESHAP) was completed in support of this standard. The industry for which economic impacts was computed was the petroleum refinery industry. Affected refineries must reduce HAP emissions by the level of control required in the standard. Several types of economic impacts, among them price product changes, output changes, job impacts, and effects on foriegn trade, were computed for the selected regulatory alternative.

  9. Potential Vulnerability of US Petroleum Refineries to Increasing Water

    Energy Savers [EERE]

    Temperature and/or Reduced Water Availability | Department of Energy Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability This report discusses potential impacts of increased water temperature and reductions in water availability on petroleum refining and presents case studies related to refinery water use. Report

  10. Market Assessment of Refinery Outages Planned for October 2010...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    average values for 2002-2009 excluding months in 2005, 2006, and 2008 affected by hurricanes & refinery closures. Similarly, typical historical values are average planned...

  11. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. PDF icon Displacing Natural Gas Consumption and...

  12. Development of an Integrated Biofuel and Chemical Refinery Presentatio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of an Integrated Biofuel and Chemical Refinery John D. Trawick Research ... HT Screening In vivo assays Metabolic Engineering Tools HT Cloning Data LIMS Fermentation ...

  13. Saudi Aramco Mobile Refinery Company (SAMREF) | Open Energy Informatio...

    Open Energy Info (EERE)

    Company (SAMREF) Name: Saudi Aramco Mobile Refinery Company (SAMREF) Address: P.O. Box 30078 Place: Yanbu, Saudi Arabia Sector: Oil and Gas Product: Crude Oil Refining Phone...

  14. Regulatory impact analysis for the petroleum refineries neshap. Draft report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The report analyzes the regulatory impacts of the Petroleum Refinery National Emission Standard for Hazardous Air Pollutants (NESHAP), which is being promulgated under Section 112 of the Clean Air Act Amendments of 1990 (CCA). This emission standard would regulate the emissions of certain hazardous air pollutants (HAPs) from petroleum refineries. The petroleum refineries industry group includes any facility engaged in the production of motor gasoline, naphthas, kerosene, jet fuels, distillate fuel oils, residual fuel oils, lubricants, or other products made from crude oil or unfinished petroleum derivatives. The report analyzes the impact that regulatory action is likely to have on the petroleum refining industry.

  15. World Energy Projection System Plus Model Documentation: Refinery Model

    Reports and Publications (EIA)

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  16. Combined-cycle cogeneration to power oil refinery

    SciTech Connect (OSTI)

    Broeker, R.J.

    1986-11-01

    A cogeneration plant now under construction at an oil refinery in Martinez, California, is an example of how the energy industry has been responding to the fundamental economic and technological challenges it has been facing over the past ten years. The industry is re-examining cogeneration as one way of meeting the requirements of the Public Utilities Regulatory Policy Act. The new plant is located at Tosco Corporation's Avon Oil Refinery, 45 miles northeast of San Francisco. It was designed by Foster Wheeler to supply process steam for the refinery as well as for a water-treatment installation that will benefit the Contra Costa Water District. Electric power produced will be used primarily by the refinery, with the balance purchased by the Pacific Gas and Electric Company.

  17. ,"Finished Motor Gasoline Refinery, Bulk Terminal, and Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,"(202) 586-8800",,,"1252016 6:37:20 PM" "Back to Contents","Data 1: Finished Motor Gasoline Refinery, Bulk Terminal, and Natural Gas Plant Stocks" "Sourcekey","MGFSXUS1"...

  18. Effective Fouling Minimization Increases the Efficiency and Productivity of Refineries

    Broader source: Energy.gov [DOE]

    This factsheet details a project to improve operating procedures, including physical and chemical methods and the use of high-temperature coatings, to allow refineries to operate equipment below threshold fouling conditions and use the most effective minimization techniques.

  19. Secretary Bodman Tours Refinery and Calls for More Domestic Refining

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capacity | Department of Energy Refinery and Calls for More Domestic Refining Capacity Secretary Bodman Tours Refinery and Calls for More Domestic Refining Capacity May 18, 2006 - 10:43am Addthis Highlights President Bush's Four-Point Plan to Combat High Energy Prices PORT ARTHUR, TX - Secretary of Energy Samuel W. Bodman today renewed the call for expanded oil refining capacity in the United States and discussed additional steps the Department of Energy (DOE) is taking to prepare for the

  20. NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol

    Office of Environmental Management (EM)

    from Algae | Department of Energy NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae February 11, 2016 - 5:07pm Addthis A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) with funding from the U.S. Department of Energy's Bioenergy Technologies Office (BETO) has proven to be significantly more effective at

  1. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  2. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi; Kulkarni, Sudhir S.

    1986-01-01

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  3. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi

    1986-01-01

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  4. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  5. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  6. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  7. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO₂ conversion into carbon-neutral fuels and chemicals November 6, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Environmentalists have long lamented the destructive effects of greenhouse gases, with carbon dioxide (CO2) often accused of being the primary instigator of global climate change. As a result, numerous efforts are under way to find ways to prevent,

  8. U.S. Fuel Consumed at Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Barrels, Except Where Noted) Area: U.S. East Coast (PADD 1) Midwest (PADD 2) Gulf Coast (PADD 3) Rocky Mountain (PADD 4) West Coast (PADD 5) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2009 2010 2011 2012 2013 2014 View History Crude Oil 0 0 0 0 0 0 1986-2014 Liquefied Petroleum Gases 2,866 2,404 1,291 1,521 1,311 2,305 1986-2014 Distillate Fuel Oil 339 440 483 539 475 309 1986-2014

  9. Alternative multimedia regulatory programs for next-generation refineries

    SciTech Connect (OSTI)

    Elcock, D.; Gasper, J.; Arguerro, R.; Emerson, D.

    2000-06-22

    The 25-year-old command-and-control environmental regulatory structure in the US has resulted in significant environmental improvements. Recently, however, its limitations (e.g., rigid application regardless of site-specific conditions, disregard of cross-media and multimedia impacts, limited incentives for new technology development and use) have become increasingly apparent. New regulatory approaches that recognize current and anticipated economic constraints, new knowledge of environmental processes and impacts, and the benefits of new technologies are needed. Such approaches could be especially important for the US petroleum refining industry. This industry operates under thin profit margins, releases chemicals that can produce adverse health and environmental impacts, and must meet the technological challenges of producing more highly refined fuels from poorer quality feedstocks. Under a grant from the Environmental Technology Initiative (ETI), Argonne National Laboratory and its subcontractor, Analytical Services, Inc. developed two alternative environmental regulatory programs for next-generation petroleum refineries. (In this report, next-generation refineries refers to the refineries of today as they operate in the next 20 or more years rather than to fully reengineered future refineries.) The objective of the ETI refinery project was to develop future-oriented regulatory programs for next-generation refineries that will expand the use of innovative technologies, encourage pollution prevention, demonstrate environmental responsibility, and maintain refinery economic performance. Rather than suggesting targeted, short-term modifications to existing media-specific command-and-control regulations, the ETI project suggests the use of new approaches that are broader and more flexible. It recognizes that giving refineries flexibility in meeting environmental protection goals can stimulate new technology development and use. Unlike most US Environmental Protection Agency (EPA) reinvention efforts, which seek results in 12 to 18 months, this ETI effort assumes a time frame of 20 years or more. It also assumes that existing laws and regulations can be changed. An iterative and interactive process was used by the project team to develop the alternative approaches. Information and stakeholder input were integrated to provide for constant revision and improvement. First, guidelines and principles were established to bound the study and set parameters for developing the approaches. Next, existing and projected environmental laws and regulations affecting petroleum refineries were examined to identify areas needing change. Then, to understand future challenges and opportunities, the projected refinery operating environment was described in terms of feedstock, product, technology, and economics. Finally several goals and indicators for assessing and comparing the alternatives were identified. On the basis of this background information, more than 60 options that could efficiently and effectively protect human health and the environment were identified. These options ranged from fundamental changes in program philosophy to procedural improvements. After the options were evaluated against the goals and indicators, many of them were integrated into two separate thematic paradigms: a risk-based paradigm and a goal-based paradigm. Elements common to both approaches include the following: (1) Establish the baseline--In establishing the baseline, the refinery and the regulator jointly identify residuals for which release limits must be established; (2) Set residual release limits--The refinery and the regulator jointly specify release limits on a facility-wide rather than a source-specific basis. A facility-wide permit documents the release limits; and (3) Assure compliance--Incentives provide the basis for assuring compliance, and flexibility in the compliance method is encouraged. Penalties apply if releases exceed the limits, and reporting requirements are streamlined relative to current practices.

  10. Mazheikiai refinery modernization study. Executive summary. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. The volume contains the Executive Summary.

  11. EIA-820, Annual Refinery Report Page 1 U. S. ENERGY INFORMATION...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crude oil that first traveled 5,000 miles by tanker and then traveled 105 miles by pipeline to the refinery, report pipeline as the method of transportation. * If the refinery...

  12. U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Refinery Gas (Million Cubic Feet) U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9...

  13. Monitoring near refineries or airborne chemicals on the SARA Title 3 section 313 list

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    In this volume, detailed procedures recommended for the measurement of selected petroleum refinery emissions in ambient air are presented.

  14. Monitoring near refineries or airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This volume identifies publications and databases that address ambient air concentrations measured near petroleum refineries for the selected target chemicals.

  15. Monitoring near refineries for airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This study provides an ambient air concentration perspective to the engineering estimates of petroleum refinery emissions required under SARA Title III Section 313. It presents and discusses ambient air concentrations of 25 selected target chemicals measured at and near the perimeter (fenceline) of three refineries. Measurements were made over three consecutive 24-hour sampling periods at each refinery. The extent to which the concentrations of the target chemicals were due to fugitive emissions from the refineries is estimated.

  16. DOE - Office of Legacy Management -- International Rare Metals Refinery Inc

    Office of Legacy Management (LM)

    - NY 38 Rare Metals Refinery Inc - NY 38 FUSRAP Considered Sites Site: International Rare Metals Refinery, Inc. (NY.38 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Canadian Radium and Uranium Corporation NY.38-1 Location: 69 Kisko Avenue , Mt. Kisko , New York NY.38-1 NY.38-3 Evaluation Year: 1987 NY.38-4 Site Operations: Manufactured and distributed radium and polonium products. NY.38-5 Site Disposition: Eliminated - No Authority - Site was a

  17. Energy Efficiency Roadmap for Petroleum Refineries in California

    SciTech Connect (OSTI)

    none,

    2004-04-01

    Through the California State IOF initiative, the California Energy Commission PIER Program developed a petroleum refining roadmap to identify energy issues and priorities unique to the refining industry in California and create a plan for future R&D that could help California refineries implement energy efficient technologies.

  18. Refinery Outages: Description and Potential Impact on Petroleum Product Prices

    Reports and Publications (EIA)

    2007-01-01

    This report responds to a July 13, 2006 request from Chairman Jeff Bingaman of the Senate Committee on Energy and Natural Resources requested that the Energy Information Administration conduct a study of the impact that refinery shutdowns have had on the price of oil and gasoline.

  19. Energy efficiency improvement and cost saving opportunities forpetroleum refineries

    SciTech Connect (OSTI)

    Worrell, Ernst; Galitsky, Christina

    2005-02-15

    The petroleum refining industry in the United States is the largest in the world, providing inputs to virtually any economic sector,including the transport sector and the chemical industry. The industry operates 146 refineries (as of January 2004) around the country,employing over 65,000 employees. The refining industry produces a mix of products with a total value exceeding $151 billion. Refineries spend typically 50 percent of cash operating costs (i.e., excluding capital costs and depreciation) on energy, making energy a major cost factor and also an important opportunity for cost reduction. Energy use is also a major source of emissions in the refinery industry making energy efficiency improvement an attractive opportunity to reduce emissions and operating costs. Voluntary government programs aim to assist industry to improve competitiveness through increased energy efficiency and reduced environmental impact. ENERGY STAR (R), a voluntary program managed by the U.S. Environmental Protection Agency, stresses the need for strong and strategic corporate energy management programs. ENERGY STAR provides energy management tools and strategies for successful corporate energy management programs. This Energy Guide describes research conducted to support ENERGY STAR and its work with the petroleum refining industry.This research provides information on potential energy efficiency opportunities for petroleum refineries. This Energy Guide introduces energy efficiency opportunities available for petroleum refineries. It begins with descriptions of the trends, structure, and production of the refining industry and the energy used in the refining and conversion processes. Specific energy savings for each energy efficiency measure based on case studies of plants and references to technical literature are provided. If available, typical payback periods are also listed. The Energy Guide draws upon the experiences with energy efficiency measures of petroleum refineries worldwide. The findings suggest that given available resources and technology, there are opportunities to reduce energy consumption cost-effectively in the petroleum refining industry while maintaining the quality of the products manufactured. Further research on the economics of the measures, as well as the applicability of these to individual refineries, is needed to assess the feasibility of implementation of selected technologies at individual plants.

  20. Alternative future environmental regulatory approaches for petroleum refineries.

    SciTech Connect (OSTI)

    Elcock, D.; Gasper, J.; Moses, D. O.; Emerson, D.; Arguerro, R.; Environmental Assessment; DOE; Analytical Services, Inc.

    2000-01-01

    Recently, many industrial, regulatory, and community leaders have expressed concern that the current environmental regulatory structure disregards multimedia environmental impacts, provides few incentives to develop and use new technologies, and fails to consider site-specific conditions. For the US petroleum refining industry, faced with the need to produce higher-quality fuels from poorer-quality feedstocks, such criticisms are expected to increase. This article offers two alternative environmental regulatory approaches for existing petroleum refineries to use in the future. These alternative approaches are multimedia in scope, provide for new technology development and use, and allow flexibility in the means for meeting environmental goals. They have been reviewed and critiqued by various stakeholders, including industry representatives, regulators, and local and national community and environmental organizations. The integration of stakeholder comments and findings of ongoing national and international regulatory reinvention efforts in the development of these approaches positions them for potential use by other industries in addition to petroleum refineries.

  1. Congested site challenges designers of refinery IPP plant

    SciTech Connect (OSTI)

    Collins, S.

    1993-09-01

    This article describes a new IPP plant which has successfully met the challenges of an extremely congested site--including overcoming physical space constraints, meeting low air-emissions regulations, and minimizing water consumption--located next to a busy highway and near a major airport. The 650-MW Linden cogeneration plant is located on a 13.5-acre plot within the confines of Bayway Refinery Co's facility near Newark, NJ. Since starting operation one year ago, the plant has been reliably supplying steam for the refinery's process heating and mechanical drive needs and efficiently generating steam and electricity with minimal environmental impact. To achieve these goals, designers chose a combined-cycle configuration/generators, five supplementary-fired heat-recovery steam generators (HRSGs), and three 90-MW steam turbine/generators. Thus far, the facility has operated with an average availability above 90%.

  2. Martinez Refinery Completes Plant-Wide Energy Assessment

    SciTech Connect (OSTI)

    2002-11-01

    This OIT BestPractices Case Study describes how the Equilon Enterprises oil refinery in Martinez, California undertook a plant-wide energy assessment that focused on three key areas: waste minimization, process debottlenecking, and operations optimization. The assessment yielded recommendations, which, if implemented, can save more than 6,000,000 MMBtu per year and an estimated $52,000,000 per year, plus improve process control and reduce waste.

  3. University of Maine Integrated Forest Product Refinery (IFPR) Technology Research

    SciTech Connect (OSTI)

    Pendse, Hemant P.

    2010-11-23

    This project supported research on science and technology that forms a basis for integrated forest product refinery for co-production of chemicals, fuels and materials using existing forest products industry infrastructure. Clear systems view of an Integrated Forest Product Refinery (IFPR) allowed development of a compelling business case for a small scale technology demonstration in Old Town ME for co-production of biofuels using cellulosic sugars along with pulp for the new owners of the facility resulting in an active project on Integrated Bio-Refinery (IBR) at the Old Town Fuel & Fiber. Work on production of advanced materials from woody biomass has led to active projects in bioplastics and carbon nanofibers. A lease for 40,000 sq. ft. high-bay space has been obtained to establish a Technology Research Center for IFPR technology validation on industrially relevant scale. UMaine forest bioproducts research initiative that began in April 2006 has led to establishment of a formal research institute beginning in March 2010.

  4. Opportunities for Biomass-Based Fuels and Products in a Refinery |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Opportunities for Biomass-Based Fuels and Products in a Refinery Opportunities for Biomass-Based Fuels and Products in a Refinery Breakout Session 2: Frontiers and Horizons Session 2-D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Corinne Valkenburg, Staff Engineer, Pacific Northwest National Laboratory PDF icon biomass13_male_2-d.pdf More Documents & Publications FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds

  5. Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets

    Reports and Publications (EIA)

    2012-01-01

    Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets is an update to a previous Energy Information Administration (EIA) report, Reductions in Northeast Refining Activity: Potential Implications for Petroleum Product Markets, released in December 2011. This update analyzes possible market responses and impacts in the event Sunoco's Philadelphia refinery closes this summer, in addition to the recently idled refineries on the East Coast and in the U.S. Virgin Islands.

  6. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heaters - Fact Sheet 2014 | Department of Energy Flexible Combustion System for Refinery and Chemical Plant Process Heaters - Fact Sheet 2014 Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters - Fact Sheet 2014 The goal of this research effort was to develop and demonstrate a combustion system capable of automatic, safe, reliable, efficient, and low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery

  7. Aspects of Holly Corporation's Acquisition of Sunoco Inc.'s Tulsa, Oklahoma Refinery

    Reports and Publications (EIA)

    2009-01-01

    The Energy Information Administration has produced a review of aspects of the Holly's acquisition of Sunoco's 85,000-barrels-per-day Tulsa refinery.

  8. Initial Assessment of U.S. Refineries for Purposes of Potential...

    Office of Scientific and Technical Information (OSTI)

    U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Freeman, Charles J.; Jones, Susanne B.; Padmaperuma, Asanga B.; Santosa, Daniel M.; Valkenburg, Corinne; Shinn,...

  9. Updated estimation of energy efficiencies of U.S. petroleum refineries.

    SciTech Connect (OSTI)

    Palou-Rivera, I.; Wang, M. Q.

    2010-12-08

    Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels such as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.

  10. Greenhouse Gases Converted to Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gases Converted to Fuel Greenhouse Gases Converted to Fuel carbon-conversion-fig-1.jpg Key Challenges: An important strategy for reducing global CO2 emissions calls for...

  11. Carbon Bearing Trace Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Bearing Trace Gases A critical scientific and policy oriented question is what are the present day sources and sinks of carbon dioxide (CO2) in the natural environment and how will these sinks evolve under rising CO2 concentrations and expected climate change and ecosystem response. Sources and sinks of carbon dioxide impart their signature on the distribution, concentration, and isotopic composition of CO2. Spatial and temporal trends (variability) provide information on the net surface

  12. Clean air amendments put big burden on refinery planners

    SciTech Connect (OSTI)

    Scherr, R.C.; Smalley, G.A. Jr.; Norman, M.E. )

    1991-06-10

    The Clean Air Act Amendments of 1990 will not only require the production of reformulated gasoline but also have significant impact on other refinery-related construction. This must be considered when developing sound planning strategy. The three titles of the Clean Air Act Amendments that will have the greatest effect on refining are: Title I: Nonattainment; Title III: Air toxics; Title V: Permitting. To understand the ramifications of these amendments, it is necessary to review the interactions of new requirements with the permitting and construction schedule shown.

  13. Raman Scattering Sensor for On-Line Monitoring of Amines and Acid Gases

    SciTech Connect (OSTI)

    Uibel, Rory; Smith, Lee

    2010-05-20

    Sulfur and CO2 removal from hydrocarbon streams and power plant effluents are a major problem. The sulfur is normally in the form of H2S. These two acid gases are scrubbed using aqueous amine solutions that are difficult to control with conventional technology. Process Instruments Inc. developed Raman scattering technology for on-line, real-time monitoring of amine streams to improve their efficiency in scrubbing H2S and CO2 from hydrocarbon streams and power plant effluents. Improved control of amine and acid gas concentrations will allow refineries, natural gas processes and power plants to more efficiently scrub Sulfur and CO2, saving energy, time and financial resources.

  14. Page 1 EIA-810, Monthly Refinery Report U. S. DEPARTMENT OF ENERGY

    Gasoline and Diesel Fuel Update (EIA)

    EIA-810, Monthly Refinery Report U. S. DEPARTMENT OF ENERGY ENERGY INFORMATION ADMINISTRATION Washington, D. C. 20585 OMB No. 1905-0165 Expiration Date: 05/31/2016 (Revised 2013) EIA-810 MONTHLY REFINERY REPORT INSTRUCTIONS ................................................................................................................................................................ QUESTIONS If you have any questions about Form EIA-810 after reading the instructions, please contact the Survey

  15. EIA-800, Weekly Refinery and Fractionator Report Page 1 U. S. DEPARTMENT OF ENERGY

    Gasoline and Diesel Fuel Update (EIA)

    00, Weekly Refinery and Fractionator Report Page 1 U. S. DEPARTMENT OF ENERGY ENERGY INFORMATION ADMINISTRATION Washington, D. C. 20585 OMB No. 1905-0165 Expiration Date: 05/31/2016 (Revised 2013) EIA-800 WEEKLY REFINERY AND FRACTIONATOR REPORT INSTRUCTIONS ............................................................................................................................................................................................................ QUESTIONS If you have any questions

  16. EIA-820, Annual Refinery Report Page 1 U. S. DEPARTMENT OF ENERGY

    Gasoline and Diesel Fuel Update (EIA)

    20, Annual Refinery Report Page 1 U. S. DEPARTMENT OF ENERGY ENERGY INFORMATION ADMINISTRATION Washington, D. C. 20585 OMB No. 1905-0165 Expiration Date: 05/31/16 (Revised 2013) EIA-820 ANNUAL REFINERY REPORT INSTRUCTIONS .................................................................................................................................................................................... QUESTIONS If you have any questions about Form EIA-820 after reading the instructions, please

  17. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect (OSTI)

    2009-12-01

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  18. Total Crude Oil and Petroleum Products Exports

    Gasoline and Diesel Fuel Update (EIA)

    Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter

  19. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    SciTech Connect (OSTI)

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

  20. ARM - What are Greenhouse Gases?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What are Greenhouse Gases? Carbon Dioxide Methane Gas Oxides of Nitrogen Halocarbons Ozone Water Vapor Greenhouse gases are atmospheric gases that trap infrared radiation emitted from the earth, lower atmosphere, or clouds or aerosols and, as

  1. Investigating and Using Biomass Gases

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigating and Using Biomass Gases Grades: 9-12 Topic: Biomass Authors: Eric Benson and Melissa Highfill Owner: National Renewable Energy Laboratory This educational material is...

  2. House Passage of H.R. 5254 - The Refinery Permit Process Schedule Act |

    Energy Savers [EERE]

    Department of Energy Passage of H.R. 5254 - The Refinery Permit Process Schedule Act House Passage of H.R. 5254 - The Refinery Permit Process Schedule Act June 8, 2006 - 2:17pm Addthis Statement from Secretary Bodman WASHINGTON, DC - The following is a statement from the Secretary Samuel W. Bodman of the Department of Energy on the passage of House Resolution 5254, The Refinery Permit Process Schedule Act: "I commend the House of Representatives for their passage of this important piece

  3. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  4. Valero: Houston Refinery Uses Plant-Wide Assessment to Develop an Energy Optimization and Management System

    SciTech Connect (OSTI)

    2005-08-01

    This Industrial Technologies Program case study describes an energy assessment team's recommendations for saving $5 million in energy, water, and other costs at an oil refinery in Houston, Texas.

  5. Initial Assessment of U.S. Refineries for Purposes of Potential...

    Office of Scientific and Technical Information (OSTI)

    Potential Bio-Based Oil Insertions Citation Details In-Document Search Title: Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions You are ...

  6. Initial Assessment of U.S. Refineries for Purposes of Potential...

    Office of Scientific and Technical Information (OSTI)

    Potential Bio-Based Oil Insertions Citation Details In-Document Search Title: Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions This study ...

  7. Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations Using a Davison Circulating Riser (DCR) 2.4.2.402 March 25, 2015 Bio-Oil Technology Area Alan Zacher Pacific ...

  8. Assuring Mechanical Integrity of Refinery Equipment Through Global ON-Stream Inspection

    SciTech Connect (OSTI)

    John W. Berthold

    2006-02-22

    The development of global on-stream inspection technology will have a dramatic effect on how refinery operations are managed in the U.S. in the future. Global on-stream inspection will provide assurance of the mechanical integrity of critical plant equipment and will allow refineries to operate more efficiently with less impact on our environment and with an increased margin of safety.

  9. Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based

    Office of Scientific and Technical Information (OSTI)

    Oil Insertions (Technical Report) | SciTech Connect Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Citation Details In-Document Search Title: Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions This study examines how existing U.S. refining infrastructure matches in geography and processing capability with the needs projected from anticipated biofuels production. Key findings include:  a potential shortfall in

  10. US DOE Refinery Water Study 01-19-16 PublicE_docx

    Energy Savers [EERE]

    Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability Executive Summary of Final Report Prepared for US Department of Energy January 2016 For Jacobs Consultancy Laura E. Weaver Rob Henderson John Blieszner January 2016 Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability Prepared For US Department of Energy 525 West Monroe Chicago, Illinois 60661 Phone: +312.655.9207

  11. Refinery Upgrading of Hydropyrolysis Oil from Biomass Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Upgrading of Hydropyrolysis Oil from Biomass March 25,2015 Technology Area Review PI - Terry Marker Gas Technology Institute This presentation does not contain any proprietary, confidential, or otherwise restricted information Goals * Develop a cost-effective route for converting biomass to transportation fuels by first converting biomass to hydropyrolysis oil and then upgrading the hydropyrolysis oil in existing refinery equipment - Study properties and corrosion characteristics of

  12. Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

    SciTech Connect (OSTI)

    Goldberg, M.

    2013-12-31

    The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.

  13. Emission factors for leaks in refinery components in heavy liquid service

    SciTech Connect (OSTI)

    Taback, H.; Godec, M.

    1996-12-31

    The objective of this program was to provide sufficient screening data so that EPA can develop an official set of emission factors (expressed in lb/hr/component) for refinery components (valves, flanged connectors, non-flanged connectors, pumps, open-ended lines, and other) in heavy liquid (BL) service. To accomplish this, 211,000 existing HL screening values from Southern California refineries were compiled and compared with 2,500 new HL screening measurements taken at two refineries in the state of Washington. Since Southern California is an area in extreme non-attainment of the National Ambient Air Quality Standards (NAAQS) and therefore has tight emission control regulations, it was felt that its screening data may not be representative of refineries without tight emission controls. Thus, the Southern California screening data were compared to screening measurements at refineries in an area that is in attainment of the NAAQS and without emissions control, which is the case for those refineries in Washington. It was found that statistically there was no significant difference in emission factors between the two areas and, therefore, there appears to be no difference in emissions from heavy liquid components in areas with and without leak detection and repair (LDAR) programs. The new emission factors range from 1/7 to 1/3 times the current EPA emission factors. This program was sponsored by the American Petroleum Institute (API) and an API report will soon be released providing complete details.

  14. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  15. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA APACHE TRIBE

    SciTech Connect (OSTI)

    John D. Jones

    2004-10-01

    A feasibility study for a proposed petroleum refinery for the Jicarilla Apache Indian Reservation was performed. The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The proposed refinery will utilize a lower temperature, smaller crude fractionation unit. It will have a Naphtha Hydrodesulfurizer and Reformer to produce high octane gasoline. The surplus hydrogen from the reformer will be used in a specialized hydrocracker to convert the heavier crude oil fractions to ultra low sulfur gasoline and diesel fuel products. The proposed refinery will produce gasoline, jet fuel, diesel fuel, and a minimal amount of lube oil. The refinery will require about $86,700,000 to construct. It will have net annual pre-tax profit of about $17,000,000. The estimated return on investment is 20%. The feasibility is positive subject to confirmation of long term crude supply. The study also identified procedures for evaluating processing options as a means for American Indian Tribes and Native American Corporations to maximize the value of their crude oil production.

  16. U.S. Total Shell Storage Capacity at Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Area: U.S. East Coast (PADD 1) Midwest (PADD 2) Gulf Coast (PADD 3) Rocky Mountain (PADD 4) West Coast (PADD 5) Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History Total 710,413 -- -- -- -- -- 1982-2015 Crude Oil 180,846 -- -- -- -- -- 1985-2015 Liquefied Petroleum Gases 33,842 -- -- -- -- -- 1982-2015 Propane/Propylene 8,513 -- --

  17. U.S. Working Storage Capacity at Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Area: U.S. East Coast (PADD 1) Midwest (PADD 2) Gulf Coast (PADD 3) Rocky Mountain (PADD 4) West Coast (PADD 5) Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History Total 617,513 -- -- -- -- -- 1982-2015 Crude Oil 153,181 -- -- -- -- -- 1982-2015 Liquefied Petroleum Gases 30,852 -- -- -- -- -- 1982-2015 Propane/Propylene 8,150 -- --

  18. Investigating and Using Biomass Gases

    Broader source: Energy.gov [DOE]

    Students will be introduced to biomass gasification and will generate their own biomass gases. Students generate these everyday on their own and find it quite amusing, but this time they’ll do it by heating wood pellets or wood splints in a test tube. They will collect the resulting gases and use the gas to roast a marshmallow. Students will also evaluate which biomass fuel is the best according to their own criteria or by examining the volume of gas produced by each type of fuel.

  19. Table 5.9 Refinery Capacity and Utilization, 1949-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Refinery Capacity and Utilization, 1949-2011 Year Operable Refineries 1 Operable Refineries Capacity Gross Input to Distillation Units 3 Utilization 4 On January 1 Annual Average 2 Number Thousand Barrels per Calendar Day Thousand Barrels Percent 1949 336 6,231 NA 2,027,928 89.2 1950 320 6,223 NA 2,182,828 92.5 1951 325 6,702 NA 2,467,445 97.5 1952 327 7,161 NA 2,536,142 93.8 1953 315 7,620 NA 2,651,068 93.1 1954 308 7,984 NA 2,651,992 88.8 1955 296 8,386 NA 2,854,137 92.2 1956 317 8,583 NA

  20. Mazheikiai refinery modernization study. Final report. Volume 2. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 2 of the study.

  1. Mazheikiai refinery modernization study. Final report. Volume 3. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 3 of the study.

  2. Mazheikiai refinery modernization study. Final report. Volume 1. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 1 of the study.

  3. TABLE16.CHP:Corel VENTURA

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6. Refinery Input of Crude Oil and Petroleum Products by PAD and Refining Districts, January 1998 Crude Oil ................................................................... 44,047 2,783 46,830 70,320 12,891 21,794 105,005 Natural Gas Liquids ................................................. 252 0 252 2,613 131 1,076 3,820 Pentanes Plus ....................................................... 0 0 0 202 45 522 769 Liquefied Petroleum Gases ................................... 252 0 252 2,411 86

  4. TABLE18.CHP:Corel VENTURA

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    8. Refinery Stocks of Crude Oil and Petroleum Products by PAD and Refining Districts, January 1998 Crude Oil .................................................................... 14,835 511 15,346 8,591 1,779 2,386 12,756 Petroleum Products .................................................. 53,526 2,604 56,130 37,545 10,689 14,376 62,610 Pentanes Plus .......................................................... 0 0 0 4 209 225 438 Liquefied Petroleum Gases ......................................

  5. U.S. Crude Oil and Petroleum Products Stocks by Type

    Gasoline and Diesel Fuel Update (EIA)

    Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Ethylene Propane/Propylene Propylene (Nonfuel Use) Normal Butane/Butylene Refinery Grade Butane Isobutane/Butylene Other Hydrocarbons Oxygenates (excluding Fuel Ethanol) MTBE Other Oxygenates Renewables (including Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils Unfinished Oils, Naphthas & Lighter Unfinished Oils,

  6. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    2010-06-01

    Funded by the American Recovery and Reinvestment Act of 2009 ENVIRON International Corporation, in collaboration with Callidus Technologies by Honeywell and Shell Global Solutions, Inc., will develop and demonstrate a full-scale fuel blending and combustion system. This system will allow a broad range of opportunity fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas, to be safely, cost-effectively, and efficiently utilized while generating minimal emissions of criteria pollutants. The project will develop a commercial technology for application in refinery and chemical plant process heaters where opportunity fuels are used.

  7. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","12/2015","1/15/1985" ,"Release Date:","2/29/2016" ,"Next Release

  8. ,"U.S. Downstream Charge Capacity of Operable Petroleum Refineries"

    U.S. Energy Information Administration (EIA) Indexed Site

    Charge Capacity of Operable Petroleum Refineries" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Downstream Charge Capacity of Operable Petroleum Refineries",32,"Annual",2015,"6/30/1982" ,"Release Date:","6/19/2015" ,"Next Release Date:","6/30/2016"

  9. ,"U.S. Production Capacity of Operable Petroleum Refineries"

    U.S. Energy Information Administration (EIA) Indexed Site

    Production Capacity of Operable Petroleum Refineries" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Production Capacity of Operable Petroleum Refineries",11,"Annual",2015,"6/30/1982" ,"Release Date:","6/19/2015" ,"Next Release Date:","6/30/2016" ,"Excel

  10. ,"U.S. Total Shell Storage Capacity at Operable Refineries"

    U.S. Energy Information Administration (EIA) Indexed Site

    Shell Storage Capacity at Operable Refineries" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Total Shell Storage Capacity at Operable Refineries",28,"Annual",2015,"6/30/1982" ,"Release Date:","6/19/2015" ,"Next Release Date:","6/30/2016" ,"Excel File

  11. ,"U.S. Working Storage Capacity at Operable Refineries"

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Storage Capacity at Operable Refineries" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Working Storage Capacity at Operable Refineries",28,"Annual",2015,"6/30/1982" ,"Release Date:","6/19/2015" ,"Next Release Date:","6/30/2016" ,"Excel File

  12. Word Pro - Untitled1

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refinery Gas: See Still Gas. Refinery and Blender Net Inputs: Raw materials, unfinished ... Refinery and Blender Net Production: Liquefied refinery gases, and finished petroleum ...

  13. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coordination. Gases are stored either in the racks between buildings 6 and 7; toxic and corrosive gases are stored in Building 6, room 6C across the walkway from beamline...

  14. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the...

  15. Allocation of energy use in petroleum refineries to petroleum products : implications for life-cycle energy use and emission inventory of petroleum transportation fuels.

    SciTech Connect (OSTI)

    Wang, M.; Lee, H.; Molburg, J.

    2004-01-01

    Studies to evaluate the energy and emission impacts of vehicle/fuel systems have to address allocation of the energy use and emissions associated with petroleum refineries to various petroleum products because refineries produce multiple products. The allocation is needed in evaluating energy and emission effects of individual transportation fuels. Allocation methods used so far for petroleum-based fuels (e.g., gasoline, diesel, and liquefied petroleum gas [LPG]) are based primarily on mass, energy content, or market value shares of individual fuels from a given refinery. The aggregate approach at the refinery level is unable to account for the energy use and emission differences associated with producing individual fuels at the next sub-level: individual refining processes within a refinery. The approach ignores the fact that different refinery products go through different processes within a refinery. Allocation at the subprocess level (i.e., the refining process level) instead of at the aggregate process level (i.e., the refinery level) is advocated by the International Standard Organization. In this study, we seek a means of allocating total refinery energy use among various refinery products at the level of individual refinery processes. We present a petroleum refinery-process-based approach to allocating energy use in a petroleum refinery to petroleum refinery products according to mass, energy content, and market value share of final and intermediate petroleum products as they flow through refining processes within a refinery. The results from this study reveal that product-specific energy use based on the refinery process-level allocation differs considerably from that based on the refinery-level allocation. We calculated well-to-pump total energy use and greenhouse gas (GHG) emissions for gasoline, diesel, LPG, and naphtha with the refinery process-based allocation approach. For gasoline, the efficiency estimated from the refinery-level allocation underestimates gasoline energy use, relative to the process-level based gasoline efficiency. For diesel fuel, the well-to-pump energy use for the process-level allocations with the mass- and energy-content-based weighting factors is smaller than that predicted with the refinery-level allocations. However, the process-level allocation with the market-value-based weighting factors has results very close to those obtained by using the refinery-level allocations. For LPG, the refinery-level allocation significantly overestimates LPG energy use. For naphtha, the refinery-level allocation overestimates naphtha energy use. The GHG emission patterns for each of the fuels are similar to those of energy use.We presented a refining-process-level-based method that can be used to allocate energy use of individual refining processes to refinery products. The process-level-based method captures process-dependent characteristics of fuel production within a petroleum refinery. The method starts with the mass and energy flow chart of a refinery, tracks energy use by individual refining processes, and distributes energy use of a given refining process to products from the process. In allocating energy use to refinery products, the allocation method could rely on product mass, product energy contents, or product market values as weighting factors. While the mass- and energy-content-based allocation methods provide an engineering perspective of energy allocation within a refinery, the market-value-ased allocation method provides an economic perspective. The results from this study show that energy allocations at the aggregate refinery level and at the refining process level could make a difference in evaluating the energy use and emissions associated with individual petroleum products. Furthermore, for the refining-process-level allocation method, use of mass -- energy content- or market value share-based weighting factors could lead to different results for diesel fuels, LPG, and naphtha. We suggest that, when possible, energy use allocations should be made at the lowest subprocess level

  16. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  17. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  18. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  19. LPG recovery from refinery flare by waste heat powered absorption refrigeration

    SciTech Connect (OSTI)

    Erickson, D.C.; Kelly, F.

    1998-07-01

    A waste heat powered ammonia Absorption Refrigeration Unit (ARU) has commenced operation at the Colorado Refining Company in Commerce City, Colorado. The ARU provides 85 tons of refrigeration at 30 F to refrigerate the net gas/treat gas stream, thereby recovering 65,000 barrels per year of LPG which formerly was flared or burned as fuel. The ARU is powered by the 290 F waste heat content of the reform reactor effluent. An additional 180 tons of refrigeration is available at the ARU to debottleneck the FCC plant wet gas compressors by cooling their inlet vapor. The ARU is directly integrated into the refinery processes, and uses enhanced, highly compact heat and mass exchange components. The refinery's investment will pay back in less than two years from increased recovery of salable product, and CO{sub 2} emissions are decreased by 10,000 tons per year in the Denver area.

  20. Ammonia Absorption Refrigeration Unit Provides Environmentally-Friendly Profits for an Oil Refinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Motor Challenge Success Story MOTOR SYSTEM UPGRADES SMOOTH THE WAY TO SAVINGS OF $700,000 AT CHEVRON REFINERY BENEFITS * Reduced energy consumption by 1 million kWh per month * Resulted in cost savings of more than $700,000 annually * Eliminated demand charge on DHT's operation * Improved equipment reliability * Improved process control "We have had no mechanical failures since the drives went into service and vibration has dropped by a factor of 10," declares an obviously proud Mares.

  1. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

  2. Evaluating electric-resistance-welded tubing for refinery and chemical plant applications

    SciTech Connect (OSTI)

    Polk, C.J.; Hotaling, A.C. )

    1993-02-01

    A laboratory technique was developed to assess the potential for preferential attack along the longitudinal seam of electric-resistance-welded (ERW) carbon steel tubing exposed to refinery and chemical plant process streams. Used in conjunction with an evaluation of mill fabrication practices, the test procedure can identify high-quality ERW products that can be used in many applications in place of seamless components at significant cost savings.

  3. Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing July 30, 2014 Bryna Berendzen Technology Manager BETO Conversion Program 2 | Bioenergy Technologies Office Conversion Program FY13/14 Workshops * In the past year BETO has held 3 public workshops to engage stakeholders in discussions on the R&D needs within the various conversion technologies * Biochemical: o PRINCE - Process Integration and Carbon Efficiencies - June 11-12,

  4. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect (OSTI)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  5. The Use of Oil Refinery Wastes as a Dust Suppression Surfactant for Use in Mining

    SciTech Connect (OSTI)

    Dixon-Hardy, D.W.; Beyhan, S.; Ediz, I.G.; Erarslan, K.

    2008-10-15

    In this research, the suitability of a selection of petroleum refinery wastes as a dust suppressant were examined. Dust is a significant problem in surface and underground mining mainly because of its adverse effects on human health and machinery. Hence, dust control and suppression is a vital part of mine planning for mining engineers. Water is the oldest and the cheapest suppressant in dealing with the mine dusts. However, surfactant use has recently been used for a wider range of applications in the mining industry. In order to carry out laboratory experiments, a dust chamber was designed and manufactured. The chamber has an inlet for coal dust entrance and a nozzle for spraying water and the oil refinery wastes. Water and the surfactants were mixed at various ratios and then sprayed onto the coal dusts within the cell. Dust concentration was measured systematically to determine the effects of surfactant containing solution on the coal dust and the data obtained by the measurements were analyzed. The results showed that the oil refinery wastes could be used as a dust suppressant, which may create an economical utilization for the wastes concerned.

  6. ARM - Lesson Plans: Dissolved Gases in Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dissolved Gases in Water Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Lesson Plans: Dissolved Gases in Water Objective The objective of this activity is to prove that ocean water can absorb greenhouse gases and to demonstrate that what appears to be clear water is actually a complex

  7. Method of concurrently filtering particles and collecting gases

    DOE Patents [OSTI]

    Mitchell, Mark A; Meike, Annemarie; Anderson, Brian L

    2015-04-28

    A system for concurrently filtering particles and collecting gases. Materials are be added (e.g., via coating the ceramic substrate, use of loose powder(s), or other means) to a HEPA filter (ceramic, metal, or otherwise) to collect gases (e.g., radioactive gases such as iodine). The gases could be radioactive, hazardous, or valuable gases.

  8. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    350 27 3,748 1,617 3,858 102 154 3,693 239 5,616 Crude Oil 48 - - - - 702 387 102 37 1,145 56 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 302 0 14 59 -21 - - -21 48 49 277 Pentanes Plus 35 0 - - - 0 - - 1 3 1 29 Liquefied Petroleum Gases 267 - - 14 59 -20 - - -22 45 48 248 Ethane/Ethylene 102 - - 1 - -104 - - 1 - - -2 Propane/Propylene 112 - - 39 51 84 - - -12 - 39 259 Normal Butane/Butylene 38 - - -26 3 0 - - -12 32 9 -15 Isobutane/Isobutylene 15 - - 0 5 0 - - 0 13 0 6 Other

  9. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    2,576 962 4,466 2,693 -646 -330 113 4,240 396 4,972 Crude Oil 1,802 - - - - 2,581 -260 -368 63 3,661 29 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 775 -20 24 76 -69 - - -181 122 238 607 Pentanes Plus 90 -20 - - 0 175 - - 41 11 163 30 Liquefied Petroleum Gases 684 - - 24 76 -244 - - -222 111 75 577 Ethane/Ethylene 239 - - - - -56 - - 7 - 64 112 Propane/Propylene 292 - - 117 61 -188 - - -122 - 2 402 Normal Butane/Butylene 98 - - -88 6 -5 - - -106 63 9 45 Isobutane/Isobutylene 55 - -

  10. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    1,035 14 648 320 -731 57 36 615 23 669 Crude Oil 715 - - - - 296 -423 50 21 600 16 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 320 0 5 22 -293 - - -19 27 6 39 Pentanes Plus 56 0 - - - -44 - - -1 5 5 2 Liquefied Petroleum Gases 264 - - 5 22 -249 - - -18 22 2 37 Ethane/Ethylene 70 - - - - -74 - - 0 - - -4 Propane/Propylene 124 - - 9 21 -110 - - -6 - 0 50 Normal Butane/Butylene 51 - - -5 0 -40 - - -13 13 1 5 Isobutane/Isobutylene 20 - - 1 1 -25 - - 1 9 - -13 Other Liquids - - 14 - - 1

  11. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    1,158 20 2,921 1,258 550 42 -236 2,766 460 2,958 Crude Oil 1,092 - - - - 1,042 166 3 -59 2,362 0 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 67 0 -4 11 0 - - -60 82 36 16 Pentanes Plus 31 0 - - - - - - 0 26 0 4 Liquefied Petroleum Gases 36 - - -4 11 0 - - -60 56 35 13 Ethane/Ethylene 0 - - - - - - - - - - 0 Propane/Propylene 12 - - 29 11 - - - -28 - 31 49 Normal Butane/Butylene 14 - - -33 0 - - - -31 39 4 -31 Isobutane/Isobutylene 10 - - 1 0 0 - - -1 17 0 -5 Other Liquids - - 21 - -

  12. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    1,070 15 662 340 -704 -26 10 637 18 693 Crude Oil 746 - - - - 326 -421 -32 9 602 8 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 323 0 13 10 -297 - - 1 20 7 21 Pentanes Plus 55 0 - - - -45 - - 0 6 5 -1 Liquefied Petroleum Gases 268 - - 13 10 -252 - - 1 14 2 22 Ethane/Ethylene 77 - - - - -76 - - 0 - - 1 Propane/Propylene 122 - - 9 9 -110 - - 0 - 0 29 Normal Butane/Butylene 50 - - 3 0 -40 - - 1 7 2 5 Isobutane/Isobutylene 19 - - 0 1 -25 - - 0 7 0 -13 Other Liquids - - 15 - - 1 16 -12 1

  13. Green House Gases | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Green House Gases Did You Know? If it were not for naturally occurring greenhouse gases, the Earth would be too cold to support life as we know it. Without the greenhouse effect, the average temperature of the Earth would be about -2°F rather than the 57°F we currently experience. However, levels of several important greenhouse gases have increased by about 40% since industrialization began around 150 years ago. During the past 20 years, about three-quarters of human-caused (anthropogenic)

  14. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  15. Denitrification of combustion gases. [Patent application

    DOE Patents [OSTI]

    Yang, R.T.

    1980-10-09

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  16. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect (OSTI)

    1996-07-01

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  17. ,"U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks of Selected Petroleum Products"

    U.S. Energy Information Administration (EIA) Indexed Site

    Refinery, Bulk Terminal, and Natural Gas Plant Stocks of Selected Petroleum Products" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks of Selected Petroleum Products",13,"Monthly","12/2015","1/15/1993" ,"Release

  18. ARM - Danger of Increased Greenhouse Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ListDanger of Increased Greenhouse Gases Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Danger of Increased Greenhouse Gases As far back as Greek and Roman times, people built structures which created an indoor environment suited to growing plants throughout the year. This enabled the

  19. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2002-01-22

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  20. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    SciTech Connect (OSTI)

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W.

    2012-05-15

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  1. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... and to illustrate the economics and sustainability of ... agencies, and the general public" (Analysis and ... Milestone: Complete draft journal manuscript of ...

  2. TABLE17.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update (EIA)

    7. Refinery Net Production of Finished Petroleum Products by PAD and Refining Districts, January 1998 Liquefied Refinery Gases ... 576 -7...

  3. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking. Investigation of coal extraction as a method to produce RCO continues; the reactor modifications to filter the products hot and to do multi-stage extraction improve extraction yields from {approx}50 % to {approx}70%. Carbon characterization of co-cokes for use as various carbon artifacts continues.

  4. Reformulated Gasoline Foreign Refinery Rules (Released in the STEO January 1998)

    Reports and Publications (EIA)

    1998-01-01

    On August 27, 1997, the Environmental Protection Agency (EPA) promulgated revised the rules that allow foreign refiners to establish and use individual baselines, but it would not be mandatory (the optional use of an individual refinery baseline is not available to domestic refiners.) If a foreign refiner did not establish and use an individual baseline, the gasoline they export to the United States would be regulated through the importer, and subject to the importer's baseline (most likely the statutory baseline). Specific regulatory provisions are implemented to ensure that the option to use an individual baseline would not lead to adverse environmental impacts. This involves monitoring the average quality of imported gasoline, and if a specified benchmark is exceeded, remedial action would be taken by adjusting the requirements applicable to imported gasoline.

  5. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  6. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  7. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  8. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  9. Oxidation of ultrathin GaSe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  10. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  11. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  12. Oxidation of ultrathin GaSe

    SciTech Connect (OSTI)

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  13. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two different co-processed fuel oils were tested: one that had been partially hydrotreated, and the other a product of fractionation before hydrotreating. Task 5 focused on examining refining methods that would utilize coal and produce thermally stable jet fuel, included delayed coking and solvent extraction. Delayed coking was done on blends of decant oil and coal, with the goal to produce a premium carbon product and liquid fuels. Coking was done on bench scale and large laboratory scale cokers. Two coals were examined for co-coking, using Pittsburgh seam coal and Marfork coal product. Reactions in the large, laboratory scaled coker were reproducible in yields of products and in quality of products. While the co-coke produced from both coals was of sponge coke quality, minerals left in the coke made it unacceptable for use as anode or graphite grade filler.

  14. EIA-Voluntary Reporting of Greenhouse Gases Program - Greenhouse Gases and

    Gasoline and Diesel Fuel Update (EIA)

    Global lWarming Potentials (GWP) Greenhouse Gases and Global Warming Potentials (GWP) Voluntary Reporting of Greenhouse Gases Program Greenhouse Gases and Global Warming Potentials (GWP) (From Appendix E of the instructions to Form EIA-1605) GREENHOUSE GAS NAME GREENHOUSE GAS CODE FORMULA GWP TAR1 AR42 (1) Carbon Dioxide CO2 CO2 1 1 (2) Methane CH4 CH4 23 25 (3) Nitrous Oxide N2O N2O 296 298 (4) Hydroflourocarbons HFC-23 (trifluoromethane) 15 CHF3 12000 14800 HFC-32 (difluoromethane) 16

  15. Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra; Kumar, Ravi; Mehlman, Stewart

    2010-06-21

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities (associated with CO2 capture technologies and geologic sequestration MVA), and Environmental Information Volume. Specific accomplishments of this Phase include: 1. Finalization of the Project Management Plan 2. Development of engineering designs in sufficient detail for defining project performance and costs 3. Preparation of Environmental Information Volume 4. Completion of Hazard Identification Studies 5. Completion of control cost estimates and preparation of business plan During the Phase 1 detailed cost estimate, project costs increased substantially from the previous estimate. Furthermore, the detailed risk assessment identified integration risks associated with potentially impacting the steam methane reformer operation. While the Phase 1 work identified ways to mitigate these integration risks satisfactorily from an operational perspective, the associated costs and potential schedule impacts contributed to the decision not to proceed to Phase 2. We have concluded that the project costs and integration risks at Texas City are not commensurate with the potential benefits of the project at this time.

  16. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    Benson, Charles; Wilson, Robert

    2014-04-30

    This project culminated in the demonstration of a full-scale industrial burner which allows a broad range of “opportunity” gaseous fuels to be cost-effectively and efficiently utilized while generating minimal emissions of criteria air pollutants. The burner is capable of maintaining a stable flame when the fuel composition changes rapidly. This enhanced stability will contribute significantly to improving the safety and reliability of burner operation in manufacturing sites. Process heating in the refining and chemicals sectors is the primary application for this burner. The refining and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion of this project, an enabling technology did not exist that would allow these energy-intensive industries to take full advantage of opportunity fuels and thereby reduce their natural gas consumption. Opportunity gaseous fuels include biogas (from animal and agricultural wastes, wastewater plants, and landfills) as well as syngas (from the gasification of biomass, municipal solid wastes, construction wastes, and refinery residuals). The primary challenge to using gaseous opportunity fuels is that their composition and combustion performance differ significantly from those of conventional fuels such as natural gas and refinery fuel gas. An effective fuel-flexible burner must accept fuels that range widely in quality and change in composition over time, often rapidly. In Phase 1 of this project, the team applied computational fluid dynamics analysis to optimize the prototype burner’s aerodynamic, combustion, heat transfer, and emissions performance. In Phase 2, full-scale testing and refinement of two prototype burners were conducted in test furnaces at Zeeco’s offices in Broken Arrow, OK. These tests demonstrated that the full range of conventional and opportunity fuels could be utilized by the project’s burner while achieving robust flame stability and very low levels of air pollutant emissions. In Phase 3, the team retrofitted three fuel-flexible burners into a fired heater at a Shell plant and demonstrated the project’s technology over a 6-month period. The project burners performed well during this period. They remain in commercial service at the Shell plant. Through this work, an improved understanding of flame stabilization mechanisms was gained. Also, methods for accommodating a wide range of fuel compositions were developed. This knowledge facilitated the commercialization of a new generation of burners that are suitable for the fuels of the future.

  17. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, C.E.

    1997-06-10

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  18. EIA-Voluntary Reporting of Greenhouse Gases Program

    Gasoline and Diesel Fuel Update (EIA)

    of Greenhouse Gases Program Voluntary Reporting of Greenhouse Gases Program ***THE VOLUNTARY REPORTING OF GREENHOUSE GASES ("1605(b)") PROGRAM HAS BEEN SUSPENDED.*** This affects all survey respondents. Please visit the What's New page for full details. What Is the Voluntary Reporting Program? logo Established by Section 1605(b) of the Energy Policy Act of 1992, the Voluntary Reporting of Greenhouse Gases Program encourages corporations, government agencies, non-profit organizations,

  19. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  20. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  1. Method for introduction of gases into microspheres

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA); Koo, Jackson C. (San Ramon, CA); Rosencwaig, Allan (Danville, CA)

    1981-01-01

    A method for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500.mu. with both thin walls (0.5 to 4.mu.) and thick walls (5 to 20.mu.) that contain various fill gases, such as Ar, Kr, Xe, Br, DT, H.sub.2, D.sub.2, He, N.sub.2, Ne, CO.sub.2, etc. in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace. Almost any gas can be introduced into the inner cavity of a glass microsphere by this method during the formation of the microsphere provided that the gas is diffused into the gel membrane or microsphere prior to its transformation into glass. The process of this invention provides a significant savings of time and related expense of filling glass microspheres with various gases. For example, the time for filling a glass microballoon with 1 atmosphere of DT is reduced from about two hours to a few seconds.

  2. Petroleum Supply Monthly

    Gasoline and Diesel Fuel Update (EIA)

    8 December 2015 Table 37. Imports of Crude Oil and Petroleum Products by PAD District, December 2015 (Thousand Barrels, Except Where Noted) Commodity PAD Districts U.S. Total 1 2 3 4 5 Total Daily Average Crude Oil 1,2 ................................................................................. 22,763 73,575 107,941 8,401 32,235 244,915 7,900 Natural Gas Plant Liquids and Liquefied Refinery Gases ...... 1,822 2,364 368 670 356 5,580 180 Pentanes Plus

  3. Petroleum Supply Monthly

    Gasoline and Diesel Fuel Update (EIA)

    9 December 2015 Table 38. Year-to-Date Imports of Crude Oil and Petroleum Products by PAD District, January-December 2015 (Thousand Barrels) Commodity PAD Districts U.S. Total 1 2 3 4 5 Total Daily Average Crude Oil 1,2 ............................................................................. 239,627 769,198 1,158,483 103,991 411,647 2,682,946 7,351 Natural Gas Plant Liquids and Liquefied Refinery Gases .. 16,761 25,611 4,588 3,561 2,042 52,563 144 Pentanes Plus

  4. Petroleum Supply Monthly

    Gasoline and Diesel Fuel Update (EIA)

    1 December 2015 Table 50. Year-to-Date Exports of Crude Oil and Petroleum Products by PAD District, January-December 2015 (Thousand Barrels) Commodity PAD Districts U.S. Total 1 2 3 4 5 Total Daily Average Crude Oil 1 ............................................................ 28,908 28,849 103,522 3,070 2,909 167,258 458 Natural Gas Plant Liquids and Liquefied Refinery Gases ................................................... 16,573 92,412 228,253 2,691 13,086 353,016 967 Pentanes Plus

  5. untitled

    U.S. Energy Information Administration (EIA) Indexed Site

    Imports of Crude Oil and Petroleum Products by PAD District, 2014 (Thousand Barrels, Except Where Noted) Commodity PAD Districts U.S. Total 1 2 3 4 5 Total Daily Average Crude Oil 1,2 ................................................................................. 237,939 724,907 1,223,590 90,356 403,834 2,680,626 7,344 Natural Gas Plant Liquids and Liquefied Refinery Gases ...... 15,014 25,071 6,260 4,112 1,574 52,031 143 Pentanes Plus

  6. untitled

    U.S. Energy Information Administration (EIA) Indexed Site

    Exports of Crude Oil and Petroleum Products by PAD District, 2014 (Thousand Barrels) Commodity PAD Districts U.S. Total 1 2 3 4 5 Total Daily Average Crude Oil 1 ............................................................ 19,054 34,396 69,971 3,847 966 128,233 351 Natural Gas Plant Liquids and Liquefied Refinery Gases ................................................... 8,866 76,602 159,337 2,651 9,130 256,587 703 Pentanes Plus .................................................. 2,217 54,926 392

  7. Voluntary Reporting of Greenhouse Gases Program - Electricity Factors

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Voluntary Reporting Program > Coefficients Voluntary Reporting of Greenhouse Gases Program (Voluntary Reporting of Greenhouse Gases Program Fuel Carbon Dioxide Emission Coefficients) Voluntary Reporting of Greenhouse Gases Program Fuel Emission Coefficients Table 1: Carbon Dioxide Emission Factors for Stationary Combustion Table 2: Carbon Dioxide Emission Factors for Transportation Fuels Table 3: Generic Methane and Nitrous Oxide Emission Factors for Stationary Fuel Combustion Table 4:

  8. Summary of the proceedings of the workshop on the refinery of the future

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This report on the Workshop on the Refinery of the Future has been prepared for participants to provide them with a succinct summary of the presentations, deliberations, and discussions. In preparing the summary, we have striven to capture the key findings (conclusions) and highlight the issues and concerns raised during the plenary and breakout sessions. The presentation of the summary of the proceedings follows the final workshop agenda, which is given in Section I; each section is tabbed to facilitate access to specific workshop topics. The material presented relies heavily on the outline summaries prepared and presented by the Plenary Session Chairman and the Facilitators for each breakout group. These summaries are included essentially as presented. In addition, individuals were assigned to take notes during each session; these notes were used to reconstruct critical issues that were discussed in more detail. The key comments made by the participants, which tended to represent the range of views expressed relative to the issues, are presented immediately following the facilitator`s summary outline in order to convey the flavor of the discussions. The comments are not attributed to individuals, since in many instances they represent a composite of several similar views expressed during the discussion. The facilitators were asked to review the writeups describing the outcomes of their sessions for accuracy and content; their suggested changes were incorporated. Every effort has thus been made to reconstruct the views expressed as accurately as possible; however, errors and/or misinterpretations undoubtedly have occurred.

  9. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  10. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  11. Method for detecting trace impurities in gases

    DOE Patents [OSTI]

    Freund, Samuel M. (Santa Fe, NM); Maier, II, William B. (Los Alamos, NM); Holland, Redus F. (Los Alamos, NM); Beattie, Willard H. (Los Alamos, NM)

    1981-01-01

    A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (.about.2 ppm) present in commercial Xe and ppm levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.

  12. EIA-Voluntary Reporting of Greenhouse Gases Program - What are Greenhouse

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gases? What are Greenhouse Gases? Voluntary Reporting of Greenhouse Gases Program What are Greenhouse Gases? Many chemical compounds found in the Earth's atmosphere act as "greenhouse gases." These gases allow sunlight to enter the atmosphere freely. When sunlight strikes the Earth's surface, some of it is reflected back towards space as infrared radiation (heat). Greenhouse gases absorb this infrared radiation and trap the heat in the atmosphere. Many gases exhibit these

  13. Study of electron transport in hydrocarbon gases

    SciTech Connect (OSTI)

    Hasegawa, H.; Date, H.

    2015-04-07

    The drift velocity and the effective ionization coefficient of electrons in the organic gases, C{sub 2}H{sub 2}, C{sub 2}H{sub 4}, C{sub 2}H{sub 6}, CH{sub 3}OH, C{sub 2}H{sub 5}OH, C{sub 6}H{sub 6}, and C{sub 6}H{sub 5}CH{sub 3}, have been measured over relatively wide ranges of density-reduced electric fields (E/N) at room temperature (around 300?K). The drift velocity was measured, based on the arrival-time spectra of electrons by using a double-shutter drift tube over the E/N range from 300 to 2800 Td, and the effective ionization coefficient (?????) was determined by the steady-state Townsend method from 150 to 3000 Td. Whenever possible, these parameters were compared with those available in the literature. It has been shown that the swarm parameters for these gases have specific tendencies, depending on their molecular configurations.

  14. Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities. [Task 1, Final report

    SciTech Connect (OSTI)

    Not Available

    1993-10-15

    The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco`s refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R&D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ``unit cost`` portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible` to estimate the likely future impacts, costs, and sources of oil spills.

  15. Effect of Noble Gases on Sonoluminescence Temperatures during Multibubble

    Office of Scientific and Technical Information (OSTI)

    Cavitation (Journal Article) | SciTech Connect Effect of Noble Gases on Sonoluminescence Temperatures during Multibubble Cavitation Citation Details In-Document Search Title: Effect of Noble Gases on Sonoluminescence Temperatures during Multibubble Cavitation Sonoluminescence spectra were collected from Cr(CO){sub 6} solutions in octanol and dodecane saturated with various noble gases. The emission from excited-state metal atoms serves as an internal thermometer of cavitation. The intensity

  16. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  17. EIA-Voluntary Reporting of Greenhouse Gases Program - What's New

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environment > Voluntary Reporting Program > What's New Voluntary Reporting of Greenhouse Gases Program What's New Voluntary Reporting of Greenhouse Gases Program Suspended May 2011 The U.S. Energy Information Administration (EIA) Voluntary Reporting of Greenhouse Gases ("1605(b)") Program has been suspended. The suspension is due to recent reductions in budget appropriations and is effective immediately. Survey respondents may still submit data to the 1605(b) Program using the

  18. ARM - Amount of Greenhouse Gases in the Global Atmosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PlansAmount of Greenhouse Gases in the Global Atmosphere Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Amount of Greenhouse Gases in the Global Atmosphere Objective The objective is to feel the changes of the amounts of greenhouse gases in the global atmosphere. Materials Each group of

  19. Energetic Materials for EGS Well Stimulation (solids, liquids, gases) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) presentation at the April 2013 peer review meeting held in Denver, Colorado. PDF icon energetics_peer2013.pdf More Documents & Publications Controlled Rapid Pressurization Using Liquid Propellants for EGS Well Stimulation track 4: enhanced geothermal systems

  20. Deviation from the Knudsen law on quantum gases

    SciTech Connect (OSTI)

    Babac, Gulru

    2014-12-09

    Gas flow in micro/nano scale systems has been generally studied for the Maxwell gases. In the limits of very low temperature and very confined domains, the Maxwellian approximation can break down and the quantum character of the gases becomes important. In these cases, Knudsen law, which is one of the important equations to analyze rarefied gas flows is invalid and should be reanalyzed for quantum gases. In this work, the availability of quantum gas conditions in the high Knudsen number cases is discussed and Knudsen law is analyzed for quantum gases.

  1. Test Results For Physical Separation Of Tritium From Noble Gases...

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Test Results For Physical Separation ...

  2. EIA - Greenhouse Gas Emissions - High-GWP gases

    Gasoline and Diesel Fuel Update (EIA)

    5. High-GWP gases 5.1. Total emissions Greenhouse gases with high global warming potential (high-GWP gases) are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which together represented 3 percent of U.S. greenhouse gas emissions in 2009. Emissions estimates for the high-GWP gases are provided to EIA by the EPA's Office of Air and Radiation. The estimates for emissions of HFCs not related to industrial processes or electric transmission are derived from the EPA

  3. Effect of Noble Gases on Sonoluminescence Temperatures during...

    Office of Scientific and Technical Information (OSTI)

    Effect of Noble Gases on Sonoluminescence Temperatures during Multibubble Cavitation ... The intensity and temperature of sonoluminescence increases from He to Xe. The intensity ...

  4. BOC Lienhwa Industrial Gases BOCLH | Open Energy Information

    Open Energy Info (EERE)

    Lienhwa Industrial Gases (BOCLH) Place: Taipei, Taiwan Sector: Solar Product: BOCLH is a joint venture between the Lien Hwa Industrial Corporation and the BOC Group in the United...

  5. Removal of mercury from waste gases

    SciTech Connect (OSTI)

    Muster, U.; Marr, R.; Pichler, G.; Kremshofer, S.; Wilferl, R.; Draxler, J.

    1996-12-31

    Waste and process gases from thermal power, incineration and metallurgical plants or those from cement and alkali chloride industries contain metallic, inorganic and organic mercury. Widespread processes to remove the major amount of mercury are absorption and adsorption. Caused by the lowering of the emission limit from 200 to 50 {mu}g/m{sup 3} [STP] by national and European legislators, considerable efforts were made to enhance the efficiency of the main separation units of flue gas cleaning plants. Specially impregnated ceramic carriers can be used for the selective separation of metallic, inorganic and organic mercury. Using the ceramic reactor removal rates lower than 5 {mu}g/m{sup 3} [STP] of gaseous mercury and its compounds can be achieved. The ceramic reactor is active, regenerable and stable for a long term operation. 4 refs., 7 figs.

  6. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    1999-05-01

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  7. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL); Herman, Harold (Park Forest, IL)

    1989-01-01

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases absorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel.

  8. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  9. Perdido LF-Gase to Electricity | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Perdido LF-Gase to Electricity Perdido LF-Gase to Electricity This presentation was given at the July 17, 2012, Community Renewable Energy Deployment webinar on successful landfill gas-to-energy projects. PDF icon 20120717_perdido_presentation.pdf More Documents & Publications CX-001860: Categorical Exclusion Determination 7.4 Landfill Methane Utilization CX-002678: Categorical Exclusion Determination

  10. Single particle density of trapped interacting quantum gases

    SciTech Connect (OSTI)

    Bala, Renu; Bosse, J.; Pathak, K. N.

    2015-05-15

    An expression for single particle density for trapped interacting gases has been obtained in first order of interaction using Green’s function method. Results are easily simplified for homogeneous quantum gases and are found to agree with famous results obtained by Huang-Yang-Luttinger and Lee-Yang.

  11. EPA's Recent Advance Notice on Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EPA's Recent Advance Notice on Greenhouse Gases EPA's Recent Advance Notice on Greenhouse Gases Summary EPA's advanced notice of proposed rulemaking on mobile sources of greenhouse gas emissions. PDF icon deer08_charmley.pdf More Documents & Publications EPA Diesel Update Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews EPA Mobile Source Rule Update

  12. Regional respiratory tract absorption of inhaled reactive gases

    SciTech Connect (OSTI)

    Miller, F.J.; Overton, J.H.; Kimbell, J.S.; Russell, M.L.

    1992-06-29

    Highly reactive gases present unique problems due to the number of factors which must be taken into account to determine regional respiratory tract uptake. The authors reviewed some of the physical, chemical, and biological factors that affect dose and that must be understood to interpret toxicological data, to evaluate experimental dosimetry studies, and to develop dosimetry models. Selected dosimetry experiments involving laboratory animals and humans were discussed, showing the variability and uptake according to animal species and respiratory tract region for various reactive gases. New experimental dosimetry approaches, such as those involving isotope ratio mass spectroscopy and cyclotron generation reactive gases, were discussed that offer great promise for improving the ability to study regional respiratory tract absorption of reactive gases. Various dosimetry modeling applications were discussed which demonstrate: the importance of airflow patterns for site-specific dosimetry in the upper respiratory tract, the influence of the anatomical model used to make inter- and intraspecies dosimetric comparisons, the influence of tracheobronchial path length on predicted dose curves, and the implications of ventilatory unit structure and volume on dosimetry and response. Collectively, these examples illustrate important aspects of regional respiratory tract absorption of inhaled reactive gases. Given the complex nature of extent and pattern of injury in the respiratory tract from exposure to reactive gases, understanding interspecies differences in the absorption of reactive gases will continue to be an important area for study.

  13. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  14. EIA-Voluntary Reporting of Greenhouse Gases Program - Under Construction

    Gasoline and Diesel Fuel Update (EIA)

    Under Construction Voluntary Reporting of Greenhouse Gases Program This Page is Currently Under Construction Please check back at a later time For more information on the Voluntary Reporting of Greenhouse Gases Program, contact us via e-mail, phone, fax, or U.S. mail: E-Mail: InfoGHG@eia.doe.gov Phone: Toll-Free: 800-803-5182 Local: 202-586-0688 Fax: 202-586-3045 U.S. Mail: Voluntary Reporting of Greenhouse Gases Program Energy Information Administration, EI-81 U.S. Department of Energy 1000

  15. EIA-Voluntary Reporting of Greenhouse Gases Program - Contact

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact Voluntary Reporting of Greenhouse Gases Program Contact For more information on the Voluntary Reporting of Greenhouse Gases Program, contact us via e-mail, phone, fax, or U.S. mail: E-Mail: InfoGHG@eia.doe.gov Phone: Toll-Free: 800-803-5182 Local: 202-586-0688 Fax: 202-586-3045 U.S. Mail: Voluntary Reporting of Greenhouse Gases Program Energy Information Administration, EI-81 U.S. Department of Energy 1000 Independence Ave, SW Washington, DC 20585

  16. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.; Liu, D.K.

    1992-11-17

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  17. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, Shih-Ger; Liu, David K.

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  18. World Energy Projection System Plus Model Documentation: Greenhouse Gases Model

    Reports and Publications (EIA)

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Greenhouse Gases Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  19. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  20. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

    1989-01-01

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  1. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

    1988-01-01

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  2. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    isotope ratios in gases of thirty hot springs and geothermal wells and of five natural gas wells in the western United States show no relationship to regional conductive heat...

  3. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  4. Phase Imprinting in Equilibrating Fermi Gases: The Transience of Vortex

    Office of Scientific and Technical Information (OSTI)

    Rings and Other Defects (Journal Article) | DOE PAGES Phase Imprinting in Equilibrating Fermi Gases: The Transience of Vortex Rings and Other Defects « Prev Next » Title: Phase Imprinting in Equilibrating Fermi Gases: The Transience of Vortex Rings and Other Defects Authors: Scherpelz, Peter ; Padavić, Karmela ; Rançon, Adam ; Glatz, Andreas ; Aranson, Igor S. ; Levin, K. Publication Date: 2014-09-16 OSTI Identifier: 1180434 Type: Publisher's Accepted Manuscript Journal Name: Physical

  5. Phase Imprinting in Equilibrating Fermi Gases: The Transience of Vortex

    Office of Scientific and Technical Information (OSTI)

    Rings and Other Defects (Journal Article) | SciTech Connect Phase Imprinting in Equilibrating Fermi Gases: The Transience of Vortex Rings and Other Defects Citation Details In-Document Search Title: Phase Imprinting in Equilibrating Fermi Gases: The Transience of Vortex Rings and Other Defects Authors: Scherpelz, Peter ; Padavić, Karmela ; Rançon, Adam ; Glatz, Andreas ; Aranson, Igor S. ; Levin, K. Publication Date: 2014-09-16 OSTI Identifier: 1180434 Type: Publisher's Accepted Manuscript

  6. New model more accurately tracks gases for underground nuclear explosion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    detection Model tracks gases for underground nuclear explosion detection New model more accurately tracks gases for underground nuclear explosion detection Scientists have developed a new, more thorough method for detecting underground nuclear explosions by coupling two fundamental elements-seismic models with gas-flow models. December 17, 2015 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and

  7. Where Greenhouse Gases Come From | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Where Greenhouse Gases Come From In the United States, greenhouse gas emissions come primarily from the burning of fossil fuels in energy use. Carbon Dioxide Carbon Dioxide is the main greenhouse gas. In 2013, 82% of human-caused greenhouse gas emissions were carbon dioxide emissions, resulting from the burning of fossil fuels, solid waste, trees, wood, and other chemical reactions. Methane and Other Gases Another greenhouse gas, methane, comes from landfills, coal mines, oil and natural gas

  8. Flammability characteristics of combustible gases and vapors. [249 refs]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Technical Report) | SciTech Connect Flammability characteristics of combustible gases and vapors. [249 refs] Citation Details In-Document Search Title: Flammability characteristics of combustible gases and vapors. [249 refs] × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in

  9. EIA - Emissions of Greenhouse Gases in the United States 2009

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) This report-the eighteenth annual report-presents the U.S. Energy Information Administration's latest estimates of emissions for carbon dioxide, methane, nitrous oxide, and other greenhouse gases. Download the GHG Report Introduction For this report, activity data on coal and natural gas consumption and electricity sales and losses

  10. EIA-Voluntary Reporting of Greenhouse Gases Program - Getting Started

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Getting Started Voluntary Reporting of Greenhouse Gases Program Getting Started Form EIA-1605 may seem daunting at first, even for entities that have reported under the original program. That's why EIA has developed the Getting Started page to help entities take a systematic approach to reporting their emissions and reductions. The Voluntary Reporting of Greenhouse Gases Program suggests that prospective reporters familiarize themselves with the specific requirements for reporting their entity's

  11. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2000-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  12. Mitigation options for accidental releases of hazardous gases (Conference)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | SciTech Connect Mitigation options for accidental releases of hazardous gases Citation Details In-Document Search Title: Mitigation options for accidental releases of hazardous gases × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy

  13. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Markun, Francis (Joliet, IL); Zawadzki, Mary T. (South Bend, IN)

    1998-01-01

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  14. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  15. Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases

    SciTech Connect (OSTI)

    Beavon, D.K.; Mackles, M.

    1980-11-11

    Liquified hydrocarbon gases containing at least carbonyl sulfide as an impurity are purified by intimately mixing the liquified hydrocarbon gas with an aqueous absorbent for hydrogen sulfide in a hydrolysis zone maintained at a temperature and a pressure sufficient to maintain the liquified hydrocarbon gas in the liquid state and hydrolyze the carbonyl sulfide to hydrogen sulfide and carbon dioxide. The liquified hydrocarbon gas containing at least a portion of the formed carbonyl sulfide and carbon dioxide is separated from the liquid absorbent and passed to an absorption zone where it is contacted with a liquid hydrogen sulfide absorbent where at least the formed hydrogen sulfide is separated from the liquified petroleum gas. A stage of absorption of at least hydrogen sulfide may proceed mixing of the liquified hydrocarbon gas with the absorbent in the hydrolysis reaction zone. The absorbent employed does not combine irreversibly with carbonyl sulfide, hydrogen sulfide, and carbon dioxide, and preferably is an aqueous solution of diethanolamine.

  16. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  17. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min × 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  18. Carbon Capture and Sequestration (via Enhanced Oil Recovery) from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Stewart Mehlman

    2010-06-16

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE’s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities (associated with CO2 capture technologies and geologic sequestration MVA), and Environmental Information Volume. Specific accomplishments of this Phase include: 1. Finalization of the Project Management Plan 2. Development of engineering designs in sufficient detail for defining project performance and costs 3. Preparation of Environmental Information Volume 4. Completion of Hazard Identification Studies 5. Completion of control cost estimates and preparation of business plan During the Phase 1 detailed cost estimate, project costs increased substantially from the previous estimate. Furthermore, the detailed risk assessment identified integration risks associated with potentially impacting the steam methane reformer operation. While the Phase 1 work identified ways to mitigate these integration risks satisfactorily from an operational perspective, the associated costs and potential schedule impacts contributed to the decision not to proceed to Phase 2. We have concluded that the project costs and integration risks at Texas City are not commensurate with the potential benefits of the project at this time.

  19. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oils Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oils March 23-27, 2015 Thermochemical Conversion Principal Investigator: Santosh Gangwal Technical Leaders: August Meng and Kevin McCabe Southern Research January 5 th , 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement  Project Goal - Develop a mild thermochemical liquefaction process to convert woody biomass to stabilized

  20. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    2,637 1,124 19,833 9,726 12 -218 18,732 5,275 19,544 Crude Oil 9,262 - - - - 7,900 -200 -195 16,765 392 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 3,375 -22 330 180 - - -619 649 1,067 2,765 Pentanes Plus 409 -22 - - 10 - - 13 134 170 80 Liquefied Petroleum Gases 2,967 - - 330 170 - - -632 515 898 2,685 Ethane/Ethylene 1,210 - - 7 - - - 12 - 64 1,141 Propane/Propylene 1,134 - - 578 144 - - -251 - 751 1,356 Normal Butane/Butylene 314 - - -243 11 - - -379 304 78 79

  1. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    0,841 851 116,203 50,123 119,592 3,155 4,776 114,478 7,424 174,087 192,970 Crude Oil 1,479 - - - - 21,756 11,999 3,151 1,162 35,500 1,723 0 16,298 Natural Gas Plant Liquids and Liquefied Refinery Gases 9,362 -13 436 1,822 -645 - - -645 1,503 1,519 8,585 8,270 Pentanes Plus 1,085 -13 - - - -11 - - 40 95 30 896 209 Liquefied Petroleum Gases 8,277 - - 436 1,822 -634 - - -685 1,408 1,489 7,689 8,061 Ethane/Ethylene 3,174 - - 19 - -3,224 - - 31 - - -62 118 Propane/Propylene 3,478 - - 1,217 1,571

  2. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    79,865 29,815 138,431 83,487 -20,012 -10,222 3,510 131,448 12,261 154,146 334,507 Crude Oil 55,847 - - - - 80,007 -8,074 -11,409 1,967 113,496 908 0 150,472 Natural Gas Plant Liquids and Liquefied Refinery Gases 24,018 -627 734 2,364 -2,137 - - -5,617 3,788 7,366 18,815 54,687 Pentanes Plus 2,800 -627 - - 3 5,421 - - 1,269 352 5,048 928 9,997 Liquefied Petroleum Gases 21,218 - - 734 2,361 -7,558 - - -6,886 3,436 2,318 17,887 44,690 Ethane/Ethylene 7,423 - - - - -1,744 - - 207 - 1,985 3,487 5,180

  3. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    33,058 3,095 249,583 119,013 -93,957 4,343 -8,851 229,949 128,849 165,188 1,297,642 Crude Oil 173,801 - - - - 101,693 4,040 386 -8,031 278,900 9,051 0 931,007 Natural Gas Plant Liquids and Liquefied Refinery Gases 59,257 -18 9,027 368 11,884 - - -10,473 11,472 22,900 56,619 125,761 Pentanes Plus 6,105 -18 - - 315 -4,043 - - -893 2,739 28 485 9,983 Liquefied Petroleum Gases 53,152 - - 9,027 53 15,927 - - -9,580 8,733 22,872 56,134 115,778 Ethane/Ethylene 24,730 - - 207 - 7,276 - - 141 - - 32,072

  4. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    7,518 100 8,051 3,839 -3,031 140 -286 7,418 4,156 5,329 Crude Oil 5,606 - - - - 3,280 130 12 -259 8,997 292 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 1,912 -1 291 12 383 - - -338 370 739 1,826 Pentanes Plus 197 -1 - - 10 -130 - - -29 88 1 16 Liquefied Petroleum Gases 1,715 - - 291 2 514 - - -309 282 738 1,811 Ethane/Ethylene 798 - - 7 - 235 - - 5 - - 1,035 Propane/Propylene 593 - - 384 - 214 - - -83 - 678 596 Normal Butane/Butylene 114 - - -92 2 46 - - -218 157 54 76

  5. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    32,086 435 20,083 9,909 -22,661 1,779 1,127 19,054 723 20,728 45,547 Crude Oil 22,162 - - - - 9,162 -13,121 1,559 662 18,615 486 0 23,545 Natural Gas Plant Liquids and Liquefied Refinery Gases 9,924 -11 162 670 -9,094 - - -592 835 196 1,212 3,622 Pentanes Plus 1,725 -11 - - - -1,367 - - -21 159 143 66 310 Liquefied Petroleum Gases 8,199 - - 162 670 -7,727 - - -571 676 53 1,146 3,312 Ethane/Ethylene 2,176 - - - - -2,308 - - 2 - - -134 432 Propane/Propylene 3,830 - - 281 647 -3,411 - - -199 - 10

  6. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    35,912 633 90,537 38,985 17,037 1,301 -7,327 85,751 14,270 91,713 144,121 Crude Oil 33,844 - - - - 32,297 5,156 104 -1,814 73,215 0 0 55,165 Natural Gas Plant Liquids and Liquefied Refinery Gases 2,068 -13 -116 356 -8 - - -1,851 2,532 1,108 498 4,933 Pentanes Plus 951 -13 - - - - - - 5 810 13 110 44 Liquefied Petroleum Gases 1,117 - - -116 356 -8 - - -1,856 1,722 1,095 388 4,889 Ethane/Ethylene 3 - - - - - - - - - - 3 - Propane/Propylene 376 - - 890 346 - - - -862 - 961 1,513 1,492 Normal

  7. Supply and Disposition of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    391,762 34,830 614,837 301,517 358 -6,765 580,680 163,526 605,862 2,014,788 Crude Oil 287,133 - - - - 244,915 -6,209 -6,054 519,726 12,167 0 1,176,487 Natural Gas Plant Liquids and Liquefied Refinery Gases 104,629 -682 10,243 5,580 - - -19,178 20,130 33,089 85,729 197,273 Pentanes Plus 12,666 -682 - - 318 - - 400 4,155 5,261 2,486 20,543 Liquefied Petroleum Gases 91,963 - - 10,243 5,262 - - -19,578 15,975 27,827 83,244 176,730 Ethane/Ethylene 37,506 - - 226 - - - 381 - 1,985 35,366 33,928

  8. U.S. Exports of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    4,967 4,564 4,884 4,628 4,817 5,275 1973-2015 Crude Oil 526 461 409 500 320 392 1920-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 1,021 991 1,136 970 1,058 1,067 1981-2015 Pentanes Plus 200 197 234 153 201 170 1984-2015 Liquefied Petroleum Gases 821 794 903 817 857 898 1973-2015 Ethane/Ethylene 65 60 51 68 66 64 1981-2015 Propane/Propylene 624 597 739 622 676 751 1973-2015 Normal Butane/Butylene 125 128 107 116 109 78 1981-2015 Isobutane/Isobutylene 6 10 5 10 7 5 1984-2015 Other

  9. U.S. Imports of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    294,833 302,821 280,042 272,798 273,770 301,517 1981-2015 Crude Oil 227,255 236,785 216,669 220,747 221,117 244,915 1920-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 3,621 4,126 3,046 4,026 4,880 5,580 1981-2015 Pentanes Plus 4 325 2 316 647 318 1981-2015 Liquefied Petroleum Gases 3,617 3,801 3,044 3,710 4,233 5,262 1981-2015 Ethane 1993-2006 Ethylene 1993-2015 Propane 2,284 2,486 1,935 2,476 3,127 3,853 1995-2015 Propylene 668 724 433 344 383 608 1993-2015 Normal Butane 140 76

  10. U.S. Imports of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    9,511 9,768 9,335 8,800 9,126 9,726 1973-2015 Crude Oil 7,331 7,638 7,222 7,121 7,371 7,900 1920-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 117 133 102 130 163 180 1981-2015 Pentanes Plus 0 10 0 10 22 10 1981-2015 Liquefied Petroleum Gases 117 123 101 120 141 170 1973-2015 Ethane 1993-2006 Ethylene 1993-2015 Propane 74 80 65 80 104 124 1995-2015 Propylene 22 23 14 11 13 20 1993-2015 Normal Butane 5 2 6 17 10 7 1995-2015 Butylene 4 4 5 3 2 4 1993-2015 Isobutane 12 13 11 8 12 15

  11. U.S. Exports of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 858,685 1,089,848 1,172,965 1,321,787 1,524,170 1,733,771 1981-2015 Crude Oil 15,198 17,158 24,693 48,968 128,233 167,258 1870-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 59,842 90,968 115,054 170,941 256,587 353,016 1981-2015 Pentanes Plus 11,792 36,837 43,136 49,883 60,533 66,494 1984-2015 Liquefied Petroleum Gases 48,050 54,131 71,918 121,058 196,054 286,522 1981-2015 Ethane/Ethylene 0 0 0 13,820 23,655 1983-2015

  12. U.S. Imports of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 4,304,533 4,174,210 3,878,852 3,598,454 3,372,904 3,431,210 1981-2015 Crude Oil 3,362,856 3,261,422 3,120,755 2,821,480 2,680,626 2,682,946 1910-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 65,314 66,851 62,192 66,290 52,031 52,563 1981-2015 Pentanes Plus 9,498 17,681 10,680 12,241 5,186 4,027 1981-2015 Liquefied Petroleum Gases 55,816 49,170 51,512 54,049 46,845 48,536 1981-2015 Ethane 1993-2007 Ethylene 135 119 115 123 129 36

  13. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    4,636,597 399,635 7,260,943 3,431,210 125,155 158,333 6,882,105 1,733,771 7,079,331 2,014,788 Crude Oil 3,441,967 - - - - 2,682,946 49,690 91,814 5,915,532 167,258 0 1,176,487 Natural Gas Plant Liquids and Liquefied Refinery Gases 1,194,630 -7,655 223,448 52,563 - - 21,920 188,270 353,016 899,780 197,273 Pentanes Plus 156,568 -7,655 - - 4,027 - - -45 53,404 66,494 33,087 20,543 Liquefied Petroleum Gases 1,038,062 - - 223,448 48,536 - - 21,965 134,866 286,522 866,693 176,730 Ethane/Ethylene

  14. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    12,703 1,095 19,893 9,401 343 434 18,855 4,750 19,395 Crude Oil 9,430 - - - - 7,351 136 252 16,207 458 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 3,273 -21 612 144 - - 60 516 967 2,465 Pentanes Plus 429 -21 - - 11 - - 0 146 182 91 Liquefied Petroleum Gases 2,844 - - 612 133 - - 60 369 785 2,375 Ethane/Ethylene 1,108 - - 6 0 - - -3 - 65 1,051 Propane/Propylene 1,117 - - 559 112 - - 51 - 615 1,121 Normal Butane/Butylene 324 - - 55 10 - - 12 169 98 110 Isobutane/Isobutylene 296 - - -7

  15. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    19,253 10,299 1,386,705 615,305 1,360,603 35,684 35,012 1,368,120 90,331 2,034,387 192,970 Crude Oil 18,221 - - - - 227,582 159,200 34,394 1,159 409,330 28,908 0 16,298 Natural Gas Plant Liquids and Liquefied Refinery Gases 101,032 -191 14,223 16,761 -4,395 - - 937 12,599 16,573 97,321 8,270 Pentanes Plus 11,667 -191 - - 9 4 - - 99 583 706 10,101 209 Liquefied Petroleum Gases 89,365 - - 14,223 16,752 -4,399 - - 838 12,016 15,867 87,220 8,061 Ethane/Ethylene 30,795 - - 170 - -31,804 - - 30 - -

  16. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    327 28 3,799 1,686 3,728 98 96 3,748 247 5,574 Crude Oil 50 - - - - 624 436 94 3 1,121 79 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 277 -1 39 46 -12 - - 3 35 45 267 Pentanes Plus 32 -1 - - 0 0 - - 0 2 2 28 Liquefied Petroleum Gases 245 - - 39 46 -12 - - 2 33 43 239 Ethane/Ethylene 84 - - 0 - -87 - - 0 - - -2 Propane/Propylene 110 - - 37 41 76 - - 3 - 38 223 Normal Butane/Butylene 36 - - 2 1 0 - - -1 23 6 11 Isobutane/Isobutylene 14 - - -1 4 0 - - 0 10 0 7 Other Liquids - - 29 - -

  17. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    937,827 337,875 1,648,603 880,978 -208,936 11,625 45,559 1,573,850 158,221 1,830,342 334,507 Crude Oil 683,678 - - - - 841,415 -155,543 -908 39,872 1,299,921 28,849 0 150,472 Natural Gas Plant Liquids and Liquefied Refinery Gases 254,149 -6,980 40,909 25,611 -16,520 - - 2,143 33,456 92,412 169,158 54,687 Pentanes Plus 32,237 -6,980 - - 45 46,186 - - 857 6,692 62,712 1,227 9,997 Liquefied Petroleum Gases 221,912 - - 40,909 25,566 -62,706 - - 1,286 26,764 29,700 167,931 44,690 Ethane/Ethylene

  18. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    569 926 4,517 2,414 -572 32 125 4,312 433 5,015 Crude Oil 1,873 - - - - 2,305 -426 -2 109 3,561 79 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 696 -19 112 70 -45 - - 6 92 253 463 Pentanes Plus 88 -19 - - 0 127 - - 2 18 172 3 Liquefied Petroleum Gases 608 - - 112 70 -172 - - 4 73 81 460 Ethane/Ethylene 191 - - 0 0 -27 - - 2 - 65 98 Propane/Propylene 274 - - 112 57 -122 - - -2 - 4 318 Normal Butane/Butylene 94 - - 2 7 -26 - - 4 27 12 33 Isobutane/Isobutylene 48 - - -1 6 4 - - 0 46 0

  19. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    775,061 37,360 2,865,360 1,309,259 -1,085,305 47,996 70,483 2,650,249 1,331,308 1,897,691 1,297,642 Crude Oil 2,077,791 - - - - 1,085,333 93,174 2,762 41,650 3,113,888 103,522 0 931,007 Natural Gas Plant Liquids and Liquefied Refinery Gases 697,270 -207 145,337 4,588 129,222 - - 18,599 109,314 228,253 620,044 125,761 Pentanes Plus 81,397 -207 - - 3,955 -29,697 - - -991 34,994 439 21,006 9,983 Liquefied Petroleum Gases 615,873 - - 145,337 633 158,919 - - 19,590 74,320 227,814 599,038 115,778

  20. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    7,603 102 7,850 3,587 -2,973 131 193 7,261 3,647 5,199 Crude Oil 5,693 - - - - 2,974 255 8 114 8,531 284 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 1,910 -1 398 13 354 - - 51 299 625 1,699 Pentanes Plus 223 -1 - - 11 -81 - - -3 96 1 58 Liquefied Petroleum Gases 1,687 - - 398 2 435 - - 54 204 624 1,641 Ethane/Ethylene 755 - - 5 - 190 - - -4 - - 955 Propane/Propylene 599 - - 360 0 156 - - 52 - 551 512 Normal Butane/Butylene 131 - - 40 2 67 - - 6 86 66 81 Isobutane/Isobutylene 202 - -

  1. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    390,462 5,367 241,768 124,089 -256,827 -9,477 3,558 232,453 6,470 252,901 45,547 Crude Oil 272,469 - - - - 119,074 -153,672 -11,771 3,234 219,796 3,070 0 23,545 Natural Gas Plant Liquids and Liquefied Refinery Gases 117,993 -123 4,589 3,561 -108,299 - - 387 7,148 2,691 7,495 3,622 Pentanes Plus 20,168 -123 - - - -16,493 - - 20 2,045 1,914 -427 310 Liquefied Petroleum Gases 97,825 - - 4,589 3,561 -91,806 - - 367 5,103 777 7,922 3,312 Ethane/Ethylene 27,979 - - - - -27,855 - - -86 - - 210 432

  2. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    413,995 8,734 1,118,507 501,579 190,464 39,327 3,721 1,057,433 147,442 1,064,010 144,121 Crude Oil 389,809 - - - - 409,542 56,842 25,213 5,899 872,597 2,909 0 55,165 Natural Gas Plant Liquids and Liquefied Refinery Gases 24,186 -154 18,390 2,042 -8 - - -146 25,753 13,086 5,763 4,933 Pentanes Plus 11,099 -154 - - 18 - - - -30 9,090 723 1,180 44 Liquefied Petroleum Gases 13,087 - - 18,390 2,024 -8 - - -116 16,663 12,363 4,583 4,889 Ethane/Ethylene 35 - - - - - - - - - - 35 - Propane/Propylene

  3. Supply and Disposition of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    1,134 24 3,064 1,374 522 108 10 2,897 404 2,915 Crude Oil 1,068 - - - - 1,122 156 69 16 2,391 8 0 Natural Gas Plant Liquids and Liquefied Refinery Gases 66 0 50 6 0 - - 0 71 36 16 Pentanes Plus 30 0 - - 0 - - - 0 25 2 3 Liquefied Petroleum Gases 36 - - 50 6 0 - - 0 46 34 13 Ethane/Ethylene 0 - - - - - - - - - - 0 Propane/Propylene 12 - - 41 5 - - - -2 - 22 39 Normal Butane/Butylene 12 - - 7 0 - - - 2 25 12 -20 Isobutane/Isobutylene 11 - - 3 0 0 - - 0 21 0 -6 Other Liquids - - 24 - - 114 314 15 3

  4. TABLE29.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update (EIA)

    9. Refinery Net Production of Finished Petroleum Products by PAD and Refining Districts, July 2004 Liquefied Refinery Gases ... 2,082 70...

  5. Word Pro - Glossary

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refinery and Blender Net Inputs: Raw materials, unfin- ished oils, and blending components ... Refinery and Blender Net Production: Liquefied refin- ery gases, and finished petroleum ...

  6. “Hard probes” of strongly-interacting atomic gases

    SciTech Connect (OSTI)

    Nishida, Yusuke

    2012-06-18

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  7. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    1998-10-01

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  8. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  9. Radiolytic and thermal generation of gases from Hanford grout samples

    SciTech Connect (OSTI)

    Meisel, D.; Jonah, C.D.; Kapoor, S.; Matheson, M.S.; Mulac, W.A.

    1993-10-01

    Gamma irradiation of WHC-supplied samples of grouted Tank 102-AP simulated nonradioactive waste has been carried out at three dose rates, 0.25, 0.63, and 130 krad/hr. The low dose rate corresponds to that in the actual grout vaults; with the high dose rate, doses equivalent to more than 40 years in the grout vault were achieved. An average G(H{sub 2}) = 0.047 molecules/100 eV was found, independent of dose rate. The rate of H2 production decreases above 80 Mrad. For other gases, G(N{sub 2}) = 0.12, G(O{sub 2}) = 0.026, G(N{sub 2}O) = 0.011 and G(CO) = 0.0042 at 130 krad/hr were determined. At lower dose rates, N{sub 2} and O{sub 2} could not be measured because of interference by trapped air. The value of G(H{sub 2}) is higher than expected, suggesting segregation of water from nitrate and nitrite salts in the grout. The total pressure generated by the radiolysis at 130 krad/h has been independently measured, and total amounts of gases generated were calculated from this measurement. Good agreement between this measurement and the sum of all the gases that were independently determined was obtained. Therefore, the individual gas measurements account for most of the major components that are generated by the radiolysis. At 90 {degree}C, H{sub 2}, N{sub 2}, and N{sub 2}O were generated at a rate that could be described by exponential formation of each of the gases. Gases measured at the lower temperatures were probably residual trapped gases. An as yet unknown product interfered with oxygen determinations at temperatures above ambient. The thermal results do not affect the radiolytic findings.

  10. Methanol production from eucalyptus wood chips. Attachment III. Florida's eucalyptus energy farm and methanol refinery: the background environment

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-04-01

    A wide array of general background information is presented on the Central Florida area in which the eucalyptus energy plantation and methanol refinery will be located. Five counties in Central Florida may be affected by the project, DeSoto, Hardee, Hillsborough, Manatee, and Polk. The human resources of the area are reviewed. Included are overviews of population demographic and economic trends. Land use patterns and the transportation are system described, and the region's archeological and recreational resources are evaluated. The region's air quality is emphasized. The overall climate is described along with noise and air shed properties. An analysis of the region's water resources is included. Ground water is discussed first followed by an analysis of surface water. Then the overall quality and water supply/demand balance for the area is evaluated. An overview of the region's biota is presented. Included here are discussions of the general ecosystems in Central Florida, and an analysis of areas with important biological significance. Finally, land resources are examined.

  11. Influence of a combustion-driven oscillation on global mixing in the flame from a refinery flare

    SciTech Connect (OSTI)

    Langman, A.S.; Nathan, G.J.

    2011-01-15

    An assessment of the influence of strong combustion-driven oscillations on mixing rates and visible radiation in the flame from a full-scale refinery flare is reported. Importantly, the oscillations were generated naturally, with no external forcing, and at a high Reynolds number of 4 x 10{sup 6}. These conditions differentiate this study from those of previous investigations, which all involved some external forcing and were at a Re too low to ensure fully turbulent flow within the flame. A frame-by-frame analysis of video footage, providing good resolution of the instantaneous edge of each flame, was used to assess flame dimensions, and so to determine a global residence time. Since the flames are in the fast-chemistry regime, the visual imagers can be used to determine a global mixing rate. The analysis reveals a consistent picture that the combustion-driven oscillations do not result in a significant change to the global mixing rate, but do increase the visible radiation. This is in contrast to previous investigations, using externally forced jets, where forcing at the preferred mode has been found to increase mixing rates and reduce radiation. (author)

  12. Strategic planning for and implementation of reclaimed municipal waste water as make-up to a refinery cooling system

    SciTech Connect (OSTI)

    Francis, W.R.; Mazur, J.J.; Rao, N.M.

    1996-08-01

    This paper discusses the successful use of treated municipal plant waste water effluent (Title 22) in a refinery cooling water system. Conversion from well water to this make-up water source was preceded by developing a carefully crafted transition plan. Steps were taken to identify key system performance indicators, establish desired performance goals, and implement stringent monitoring and control protocols. In addition, all possible contingencies were considered and solutions developed. Treating Title 22 waters is very challenging and entails risks not associated with normal makeup waters. Several novel on-line monitoring and control tools are available which help minimize these risks while enhancing tower operation. Performance monitoring of critical system parameters is essential in order to provide early warning of problems so that corrective measures can be implemented. In addition, a high level of system automation enhances reliable operation. Corrosion, scaling and microbiological performance of the system with Title 22 water is discussed in comparison to previous well water make-up.

  13. Assessment of the potential for refinery applications of inorganic membrane technology: An identification and screening analysis. Final report

    SciTech Connect (OSTI)

    Johnson, H.E.; Schulman, B.L.

    1993-05-01

    Commercial application of membrane technology in the separation of gas, liquid, and solid streams has grown to a business with worldwide revenues exceeding $1 billion annually. Use of organic membranes for industrial gas separation, particularly in the refining industry, is one of the major growth areas. However, organic membranes based on polymeric separation barriers, are susceptible to damage by liquids, and careful precautions must be taken to retain the system integrity. Researchers are currently developing small pore sized inorganic membranes which may substantially increase the efficiency and economics in selected refinery separation applications. Expected advantages of these advanced inorganic membranes include high permeability, high selectivity, and low manufacturing cost. SFA Pacific conducted a screening analysis to identify applications for inorganic membrane technology in the petroleum refining industry and their potential cost advantages over competing separation systems. Two meetings were held in connection with this project. Copies of Viewgraphs presented by SFA Pacific at these meetings are attached in Appendices A and C. Potential high priority applications and market impacts of advanced inorganic membrane technology in the refining industry are addressed in this report, and include the following areas: Competitive separation technologies; application of those technologies; incentives for inorganic membranes; market benefits and impacts of inorganic membranes.

  14. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  15. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

    2012-04-17

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  16. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  17. Other States Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Other States Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 NA NA NA NA NA NA NA NA NA NA NA NA 1997 513 491 515 539 557 534 541 579 574 585 558 573 1998 578 536 591 581 517 456 486 486 471 477 457 468 1999 466 438 489 495 499 510 547 557 544 555 541 579 2000 587 539 605 587 615 570 653 629 591 627 609 611 2001 658 591 677 690 718 694 692 679

  18. Use of low temperature blowers for recirculation of hot gases

    DOE Patents [OSTI]

    Maru, H.C.; Forooque, M.

    1982-08-19

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  19. Crude Oil and Petroleum Products Total Stocks Stocks by Type

    U.S. Energy Information Administration (EIA) Indexed Site

    Stocks by Type Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases EthaneEthylene PropanePropylene Normal ...

  20. Conceptual design assessment for the co-firing of bio-refinery supplied lignin project. Quarterly report, June 23--July 1, 2000

    SciTech Connect (OSTI)

    Berglund, T.; Ranney, J.T.; Babb, C.L.

    2000-07-27

    The Conceptual Design Assessment for the Co-Firing of Bio-Refinery Supplied Lignin Project was successfully kicked off on July 23, 2000 during a meeting at the TVA-PPI facility in Muscle Shoals, AL. An initial timeline for the study was distributed, issues of concern were identified and a priority actions list was developed. Next steps include meeting with NETL to discuss de-watering and lignin fuel testing, the development of the mass balance model and ethanol facility design criteria, providing TVA-Colbert with preliminary lignin fuel analysis and the procurement of representative feed materials for the pilot and bench scale testing of the hydrolysis process.

  1. Chevron: Refinery Identifies $4.4 Million in Annual Savings by Using Process Simulation Models to Perform Energy-Efficiency Assessment

    SciTech Connect (OSTI)

    2004-05-01

    In an energy-efficiency study at its refinery near Salt Lake City, Utah, Chevron focused on light hydrocarbons processing. The company found it could recover hydrocarbons from its fuel gas system and sell them. By using process simulation models of special distillation columns and associated reboilers and condensers, Chevron could predict the performance of potential equipment configuration changes and process modifications. More than 25,000 MMBtu in natural gas could be saved annually if a debutanizer upgrade project and a new saturated gas plant project were completed. Together, these projects would save $4.4 million annually.

  2. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

    1997-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  3. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  4. Apparatus for hot-gas desulfurization of fuel gases

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV)

    1992-01-01

    An apparatus for removing sulfur values from a hot fuel gas stream in a fdized bed contactor containing particulate sorbent material by employing a riser tube regeneration arrangement. Sulfur-laden sorbent is continuously removed from the fluidized bed through a stand pipe to the riser tube and is rapidly regenerated in the riser tube during transport of the sorbent therethrough by employing an oxygen-containing sorbent regenerating gas stream. The riser tube extends from a location below the fluidized bed to an elevation above the fluidized bed where a gas-solid separating mechanism is utilized to separate the regenerated particulate sorbent from the regeneration gases and reaction gases so that the regenerated sorbent can be returned to the fluidized bed for reuse.

  5. Nanostructured carbon materials for adsorption of methane and other gases

    DOE Patents [OSTI]

    Stadie, Nicholas P.; Fultz, Brent T.; Ahn, Channing; Murialdo, Maxwell

    2015-06-30

    Provided are methods for storing gases on porous adsorbents, methods for optimizing the storage of gases on porous adsorbents, methods of making porous adsorbents, and methods of gas storage of optimized compositions, as in systems containing porous adsorbents and gas adsorbed on the surface of the porous adsorbent. The disclosed methods and systems feature a constant or increasing isosteric enthalpy of adsorption as a function of uptake of the gas onto the exposed surface of a porous adsorbent. Adsorbents with a porous geometry and surface dimensions suited to a particular adsorbate are exposed to the gas at elevated pressures in the specific regime where n/V (density) is larger than predicted by the ideal gas law by more than several percent.

  6. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, M.

    1995-02-07

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  7. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, Michael (Los Alamos, NM)

    1995-01-01

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  8. Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,813 3,440 3,591 7,549 6,265 8,763 9,872 18,776 13,652 9,971 1990's 9,981 - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  9. Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,813 3,440 3,591 7,549 6,265 8,763 9,872 18,776 13,652 9,971 1990's 9,981 - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  10. System for trapping and storing gases for subsequent chemical reduction to solids

    DOE Patents [OSTI]

    Vogel, John S.; Ognibene, Ted J.; Bench, Graham S.; Peaslee, Graham F.

    2009-11-03

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  11. MOFs Can Tune the Critical Point of Gases | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome MOFs Can Tune the Critical Point of Gases

  12. Extraction of uranium from spent fuels using liquefied gases

    SciTech Connect (OSTI)

    Sawada, Kayo; Hirabayashi, Daisuke; Enokida, Youichi

    2007-07-01

    For reprocessing of spent nuclear fuels, a novel method to extract actinides from spent fuel using highly compressed gases, nitrogen dioxide and carbon dioxide was proposed. As a fundamental study, the nitrate conversion with liquefied nitrogen dioxide and the nitrate extraction with supercritical carbon dioxide were demonstrated by using uranium dioxide powder, uranyl nitrate and tri-n-butylphosphate complex in the present study. (authors)

  13. EIA-Voluntary Reporting of Greenhouse Gases Program - Why Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Why Report Voluntary Reporting of Greenhouse Gases Program Why Report What Is the Purpose of Form EIA-1605? Form EIA-1605 provides the means for the voluntary reporting of greenhouse gas emissions, reductions, and sequestration under Section 1605(b) of the Energy Policy Act of 1992. The purpose of the Voluntary Reporting Program is to encourage corporations, government agencies, non-profit organizations, households, and other private and public entities to submit annual reports of their

  14. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    1997-10-01

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  15. Greenhouse gases mitigation options and strategies for Tanzania

    SciTech Connect (OSTI)

    Mwandosya, M.J.; Meena, H.E.

    1996-12-31

    Tanzania became a party to the United Nations Framework on Climate Change (UN FCCC) when she ratified the Convention in March, 1996. Now that Tanzania and other developing countries are Parties to the UN FCCC, compliance with its provisions is mandatory. The legal requirements therefore provide a basis for their participation in climate change studies and policy formulation. All parties to the Convention are required by Article 4.1 of the United Nations Convention on Climate Change (UN FCCC) to develop, periodically update, publish, and make available national inventories of anthropogenic emissions and removal of greenhouse gases that are not controlled by the Montreal Protocol. This study on possible options for the mitigation of greenhouse gases in Tanzania is a preliminary effort towards the fulfilment of the obligation. In order to fulfil their obligations under the UN FCCC and have a meaningful mitigation assessment, identification and quantification of anthropogenic sources of atmospheric emissions of greenhouse gases in the country was undertaken. In this respect, the study of anthropogenic emissions by source and removals by sink of GHGs in Tanzania was done with the main objective of increasing the quantity and quality of base-line data available in order to further scientific understanding of the relationship of greenhouse gas emissions to climate change. Furthermore, the study facilitated identification of national policy and technological options that could reduce the level of emissions in the country.

  16. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  17. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  18. Short-Term Energy Outlook Model Documentation: Petroleum Products Supply Module

    Reports and Publications (EIA)

    2013-01-01

    The Petroleum Products Supply Module of the Short-Term Energy Outlook (STEO) model provides forecasts of petroleum refinery inputs (crude oil, unfinished oils, pentanes plus, liquefied petroleum gas, motor gasoline blending components, and aviation gasoline blending components) and refinery outputs (motor gasoline, jet fuel, distillate fuel, residual fuel, liquefied petroleum gas, and other petroleum products).

  19. Plasma-chemical waste treatment of acid gases

    SciTech Connect (OSTI)

    Harkness, J.B.L.; Doctor, R.D.; Daniels, E.J.

    1993-09-01

    The research to date has shown that a H{sub 2}S waste-treatment process based on plasma-chemical dissociation technology is compatible with refinery and high-carbon-oxide acid-gas streams. The minor amounts of impurities produced in the plasma-chemical reactor should be treatable by an internal catalytic reduction step. Furthermore, the plasma-chemical technology appears to be more efficient and more economical than the current technology. The principal key to achieving high conversions with relatively low energies of dissociation is the concept of the high-velocity, cyclonic-flow pattern in the plasma reaction zone coupled with the recycling of unconverted hydrogen sulfide. Future work will include testing the effects of components that might be carried over to the plasma reactor by ``upset`` conditions in the amine purification system of a plant and testing the plasma-chemical process on other industrial wastes streams that contain potentially valuable chemical reagents. The strategy for the commercialization of this technology is to form a Cooperative Research and Development Agreement with the Institute of Hydrogen Energy and Plasma Technology of the Russian Scientific Center/Kurchatov Institute and with an American start-up company to develop an ``American`` version of the process and to build a commercial-scale demonstration unit in the United States. The timetable proposed would involve building a ``field test`` facility which would test the plasma-chemical reactor and sulfur recovery unit operations on an industrial hydrogen sulfide waste s at a scale large enough to obtain the energy and material balance data required for a final analysis of the commercial potential of this technology. The field test would then be followed by construction of a commercial demonstration unit in two to three years. The commercial demonstration unit would be a fully integrated plant consisting of one commercial-scale module.

  20. Hydrogen Generation for Refineries

    Broader source: Energy.gov (indexed) [DOE]

    crudes contains high sulfur and high molecular weight hydrocarbons This presentation ... of interest to DOE * Preliminary design of continuous system, process simulation, ...

  1. Refinery Capacity Report Historical

    Gasoline and Diesel Fuel Update (EIA)

  2. The ultimate biomass refinery

    SciTech Connect (OSTI)

    Bungay, H.R. )

    1988-01-01

    Bits and pieces of refining schemes and both old and new technology have been integrated into a complete biomass harvesting, processing, waste recycle, and marketing complex. These choices are justified with economic estimates and technology assessments.

  3. Refinery Outages: Fall 2014

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    some Libyan crude oil production to the market, and increasing U.S. crude production. Economic growth in 2014 outside of the United States has been slow, and some recent data...

  4. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    CORPORATION / Refiner / Location Table 5. Refiners' Total Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 2015 Calendar Day Barrels per CORPORATION / Refiner / Location Calendar Day Barrels per Companies with Capacity Over 100,000 bbl/cd .............................................................................................................................. VALERO ENERGY CORP 1,964,300 Valero Refining Co Texas LP

  5. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Year: 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 prior issues Go Data series include fuel, electricity, and ... 2015 Source --- Energy Information Administration (EIA), ...

  6. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Arcadia Refining & Mktg Lisbon, LA 7,350 6,700 0196 0296 Canal Refg Co. Chuch Point, LA 9,500 2,100 0795 0997 Gold Line Refining LTD Jennings, LA 12,000 0 0797 0198 Petrolite ...

  7. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Nonresponse follow-up procedures are employed to reduce the number of nonrespondents, and procedures employed to impute missing data, introduce a minimal amount of error, given the ...

  8. Refinery Outages: Fall 2014

    Gasoline and Diesel Fuel Update (EIA)

    gasoline supply in a particular region because pipeline infrastructure, geography and marine shipping regulations constrain the amount of product that can flow among the different...

  9. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Shell Oil Products US 12,500 0 0 0 15,000 0 9,000 ...... 189 413 Martinez 0 Tesoro Refining & Marketing Co 17,000 0 0 3,500 ...

  10. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Kenai ...... Arkansas 90,500 0 92,700 0 48,850 0 0 0 0 Cross Oil Refining & Marketing Inc 7,500 0 7,700 0 3,850 0 0 0 0 ...

  11. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, Raymond J. (Mt. Prospect, IL); Kurek, Paul R. (Schaumburg, IL)

    1988-01-01

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  12. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  13. Liquefaction and storage of thermal treatment off-gases

    SciTech Connect (OSTI)

    Stull, D.M. . Rocky Flats Plant); Golden, J.O. )

    1992-09-08

    A fluidized bed catalytic oxidation unit is being developed for use in the destruction of mixed waste at the Rocky Flats Plant. Cyclones, filters, in situ neutralization of acid gases, and a catalytic converter are used to meet emission standards. Because there is concern by the public that these measures may not be adequate, two off-gas capture systems were evaluated. Both systems involve liquefaction of carbon dioxide produced in the oxidation process. The carbon dioxide would be released only after analysis proved that all appropriate emission standards are met.

  14. Nonperturbative Predictions for Cold Atom Bose Gases with Tunable Interactions

    SciTech Connect (OSTI)

    Cooper, Fred; Chien, Chih-Chun; Mihaila, Bogdan; Timmermans, Eddy; Dawson, John F.

    2010-12-10

    We derive a theoretical description for dilute Bose gases as a loop expansion in terms of composite-field propagators by rewriting the Lagrangian in terms of auxiliary fields related to the normal and anomalous densities. We demonstrate that already in leading order this nonperturbative approach describes a large interval of coupling-constant values, satisfies Goldstone's theorem, yields a Bose-Einstein transition that is second order, and is consistent with the critical temperature predicted in the weak-coupling limit by the next-to-leading-order large-N expansion.

  15. PPPL wins Department of Energy award for reducing greenhouse gases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab wins Department of Energy award for reducing greenhouse gases By Jeanne Jackson DeVoe October 2, 2012 Tweet Widget Google Plus One Share on Facebook PPPL engineer Tim Stevenson checks for possible leaks of sulfur hexafluoride (SF6), the gas used to insulate electronic equipment that has the potential to cause global warming at many times the rate of carbon dioxide. PPPL reduced leaks of SF6 by 65 percent over three years - reducing overall greenhouse gas

  16. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  17. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    1996-10-01

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  18. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P.; Lynn, Scott

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  19. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J.; Berman, Samuel M.

    1988-01-01

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  20. EIA-Voluntary Reporting of Greenhouse Gases Program - Original 1605(b)

    Gasoline and Diesel Fuel Update (EIA)

    Program Program Calculation Tools Voluntary Reporting of Greenhouse Gases Program Original 1605(b) Program Calculation Tools The workbooks below were developed to assist participants in the original Voluntary Reporting of Greenhouse Gases Program to estimate the carbon sequestered by urban forestry activities and to estimate emissions reductions from recycling, source reduction, or composting activities, respectively. The original Voluntary Reporting of Greenhouse Gases Program was based on

  1. Detection And Discrimination Of Pure Gases And Binary Mixtures Using A

    Office of Scientific and Technical Information (OSTI)

    Single Microcantilever (Journal Article) | SciTech Connect Detection And Discrimination Of Pure Gases And Binary Mixtures Using A Single Microcantilever Citation Details In-Document Search Title: Detection And Discrimination Of Pure Gases And Binary Mixtures Using A Single Microcantilever A new method for detecting and discriminating pure gases and binary mixtures has been investigated. This approach combines two distinct physical mechanisms within a single piezoresistive microcantilever:

  2. EIA-Voluntary Reporting of Greenhouse Gases Program -Data and Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data and Reports Voluntary Reporting of Greenhouse Gases Program Data and Reports The first reporting cycle under the revised Voluntary Reporting of Greenhouse Gases Program closed in November 2010. Posted below is the most recent Public Use Database for the 2009 reporting year, as well as all previous versions of the Public Use Database. Also posted below is the Voluntary Reporting of Greenhouse Gases 2009: Summary Report. Links are also provided below to earlier versions on the Voluntary

  3. Ultracold Bose gases in time-dependent one-dimensional superlattices:

    Office of Scientific and Technical Information (OSTI)

    Response and quasimomentum structure (Journal Article) | SciTech Connect Ultracold Bose gases in time-dependent one-dimensional superlattices: Response and quasimomentum structure Citation Details In-Document Search Title: Ultracold Bose gases in time-dependent one-dimensional superlattices: Response and quasimomentum structure The response of ultracold atomic Bose gases in time-dependent optical lattices is discussed based on direct simulations of the time-evolution of the many-body state

  4. Wave speeds in the macroscopic extended model for ultrarelativistic gases

    SciTech Connect (OSTI)

    Borghero, F.; Demontis, F.; Pennisi, S.

    2013-11-15

    Equations determining wave speeds for a model of ultrarelativistic gases are investigated. This model is already present in literature; it deals with an arbitrary number of moments and it was proposed in the context of exact macroscopic approaches in Extended Thermodynamics. We find these results: the whole system for the determination of the wave speeds can be divided into independent subsystems which are expressed by linear combinations, through scalar coefficients, of tensors all of the same order; some wave speeds, but not all of them, are expressed by square roots of rational numbers; finally, we prove that these wave speeds for the macroscopic model are the same of those furnished by the kinetic model.

  5. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, Arthur W. (Schenectady, NY)

    1985-01-01

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  6. Nuclear magnetic resonance imaging with hyper-polarized noble gases

    SciTech Connect (OSTI)

    Schmidt, D.M.; George, J.S.; Penttila, S.I.; Caprihan, A.

    1997-10-01

    This is the final report of a six-month, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The nuclei of noble gases can be hyper polarized through a laser-driven spin exchange to a degree many orders of magnitude larger than that attainable by thermal polarization without requiring a strong magnetic field. The increased polarization from the laser pumping enables a good nuclear magnetic resonance (NMR) signal from a gas. The main goal of this project was to demonstrate diffusion-weighted imaging of such hyper-polarized noble gas with magnetic resonance imaging (MRI). Possible applications include characterizing porosity of materials and dynamically imaging pressure distributions in biological or acoustical systems.

  7. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, A.W.

    1983-10-12

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  8. Noble gases and cosmogenic radionuclides in the Eltanin Pacific meteorite

    SciTech Connect (OSTI)

    Bogard, D D; Garrison, D H; Caffee, M W; Kyte, F; Nishiizumi, K

    2000-01-14

    A 1.5 cm long, 1.2 g specimen of the Eltanin meteorite was found at 10.97 m depth in Polarstern piston core PS2704-1. The early studies indicated that the small fragments of the Eltanin meteorite was debris from a km-sized asteroid which impacted into the deep-ocean basin. In this study, the authors measured {sup 39}Ar-{sup 40}Ar age, noble gases, and cosmogenic radionuclides in splits of specimen as a part of consortium studies of Eltanin meteorite. They concluded that the specimen was about 3 m deep from the asteroid surface. The exposure age of the Eltanin asteroid was about 20 Myr.

  9. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect (OSTI)

    Lelas, K.; Seva, T.; Buljan, H.

    2011-12-15

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  10. Catalytic process for removing toxic gases from gas streams

    SciTech Connect (OSTI)

    Baglio, J.A.; Gaudet, G.G.; Palilla, F.C.

    1983-02-22

    A multi-stage process for reducing the content of sulfurcontaining gases-notably hydrogen sulfide, sulfur dioxide, carbonyl sulfide and carbon disulfide-in waste gas streams is provided. In the first stage, the gas stream is passed through a reaction zone at a temperature between about 150 and 350/sup 0/C in the presence of a pretreated novel catalyst of the formula xLn/sub 2/O/sub 3/ in which Ln is yttrium or a rare earth element and T is cobalt, iron or nickel, and each of x and y is independently a number from 0 to 3, said catalyst being substantially non-crystalline and having a surface area of from about 10 m/sup 2//g to about 40 m/sup 2//g. The preferred catalyst is one in which Ln is lanthanum, T is cobalt, and x and y range from 1 to 3, including non-integers. The first stage yields a product stream having a reduced content of sulfur-containing gases, including specifically, substantial reduction of carbonyl sulfide and virtual elimination of carbon disulfide. An intermediate stage is a claus reaction, which may take place in one or more reaction zones, at temperatures less than about 130/sup 0/ C, in the presence of known catalysts such as bauxite, alumina or cobalt molybdates. The final stage is the air oxidation of hydrogen sulfide at a temperature between about 150 and 300/sup 0/ C in the presence of a catalyst usable in first stage.

  11. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  12. Device for accurately measuring mass flow of gases

    DOE Patents [OSTI]

    Hylton, J.O.; Remenyik, C.J.

    1994-08-09

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure is disclosed. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel. 5 figs.

  13. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  14. Device for accurately measuring mass flow of gases

    DOE Patents [OSTI]

    Hylton, James O. (Clinton, TN); Remenyik, Carl J. (Knoxville, TN)

    1994-01-01

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel.

  15. On flame kernel formation and propagation in premixed gases

    SciTech Connect (OSTI)

    Eisazadeh-Far, Kian; Metghalchi, Hameed [Northeastern University, Mechanical and Industrial Engineering Department, Boston, MA 02115 (United States); Parsinejad, Farzan [Chevron Oronite Company LLC, Richmond, CA 94801 (United States); Keck, James C. [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

    2010-12-15

    Flame kernel formation and propagation in premixed gases have been studied experimentally and theoretically. The experiments have been carried out at constant pressure and temperature in a constant volume vessel located in a high speed shadowgraph system. The formation and propagation of the hot plasma kernel has been simulated for inert gas mixtures using a thermodynamic model. The effects of various parameters including the discharge energy, radiation losses, initial temperature and initial volume of the plasma have been studied in detail. The experiments have been extended to flame kernel formation and propagation of methane/air mixtures. The effect of energy terms including spark energy, chemical energy and energy losses on flame kernel formation and propagation have been investigated. The inputs for this model are the initial conditions of the mixture and experimental data for flame radii. It is concluded that these are the most important parameters effecting plasma kernel growth. The results of laminar burning speeds have been compared with previously published results and are in good agreement. (author)

  16. Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0

  17. Illinois Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0

  18. Glass surface deactivants for sulfur-containing gases

    SciTech Connect (OSTI)

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  19. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect (OSTI)

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  20. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  1. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  2. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxide Emission Standards, Model Years 2017-2025 | Department of Energy 5: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025 Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025 The Environmental Protection Agency finalized Tier 3 emission standards in a rule issued in March 2014. One effect of the rule is a decrease in the combined amount of non-methane organic gases

  3. Load Preheating Using Flue Gases from a Fuel-Fired Heating System

    Broader source: Energy.gov [DOE]

    This tip sheet discusses how the thermal efficiency of a process heating system can be improved significantly by using heat contained in furnace flue gases to preheat the furnace load.

  4. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Snow, N.J. Jr.

    1983-12-06

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a well-head; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; and separating LPG from gas vapors of the refrigerated natural gas. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for cooling the compressed gases therefrom; and a product separator downstream of the refrigeration unit for receiving cooled and compressed gases discharged from the refrigeration unit and separating LPG therein from gases remaining in vapor form.

  5. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOE Patents [OSTI]

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  6. Novel Material for Efficient and Low-Cost Separation of Gases for Fuels and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plastics | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Novel Material for Efficient and Low-Cost Separation of Gases for Fuels and Plastics

  7. Radon and helium in soil gases in the Phlegraean Fields, central Italy

    SciTech Connect (OSTI)

    Lombardi, S. ); Reimer, G.M. )

    1990-05-01

    The distribution and migration of radon and helium soil-gas concentrations in the Phlegraean Fields, Italy, are controlled by the tectonic features of the area. Radon is supplied from surficial sources and helium has both surficial and deep origins. There is no direct correlation between the two noble gases on a point-to-point basis but the areal distribution of both gases is similar, suggesting that the distribution is controlled primarily by fractures and movement of geothermal fluids.

  8. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, Krishnamurti (Naperville, IL)

    1992-01-01

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

  9. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  10. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  11. Emissions of Greenhouse Gases in the United States 2009, DOE/EIA-0573(2009)

    Gasoline and Diesel Fuel Update (EIA)

    March 2011 www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Emissions of Greenhouse Gases in the United States 2009 ii Contacts This report, Emissions of Greenhouse Gases in the United States 2009, was prepared under the general direction of John Conti, Assistant Administrator for Energy Analysis, and Paul Holtberg, Team Leader, Analysis Integration Team. General questions concerning the content of this report may be directed to the Office of

  12. Global and regional evolution of short-lived radiatively-active gases and

    Office of Scientific and Technical Information (OSTI)

    aerosols in the Representative Concentration Pathways (Journal Article) | SciTech Connect Global and regional evolution of short-lived radiatively-active gases and aerosols in the Representative Concentration Pathways Citation Details In-Document Search Title: Global and regional evolution of short-lived radiatively-active gases and aerosols in the Representative Concentration Pathways In this paper, we discuss the results of 2000-2100 simulations with a chemistry-climate model, focusing on

  13. EIA-Voluntary Reporting of Greenhouse Gases Program - About the 1605(b)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program About the 1605(b) Program Voluntary Reporting of Greenhouse Gases Program About the 1605(b) Program History Established by Section 1605(b) of the Energy Policy Act of 1992, the Voluntary Reporting of Greenhouse Gases Program (also known as the 1605(b) Program) encourages corporations, government agencies, non-profit organizations, households, and other private and public entities to submit annual reports of their greenhouse gas emissions, emission reductions, and sequestration

  14. EIA-Voluntary Reporting of Greenhouse Gases Program - Original 1605(b)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Original 1605(b) Program Voluntary Reporting of Greenhouse Gases Program Original 1605(b) Program Section 1605(b) of the Energy Policy Act of 1992 established the Voluntary Reporting of Greenhouse Gases Program. The Program operated under the original 1994 guidelines through the 2005 data year (for reports containing data through 2005). Reports containing data through 2007 and beyond submitted beginning in 2008 will be conducted under the revised General and Technical Guidelines

  15. Emissions of greenhouse gases in the United States, 1985--1990

    SciTech Connect (OSTI)

    Not Available

    1993-11-10

    The Earth`s capacity to support life depends on the moderating influences of gases that envelop the planet and warm its surface and protect it from harmful radiation. These gases are referred to as ``greenhouse gases.`` Their warming capacity, called ``the greenhouse effect,`` is essential to maintaining a climate hospitable to all plant, animal, and human life. In recent years, however, there has been increasing concern that human activity may be affecting the intricate balance between the Earth`s absorption of heat from the sun and its capacity to reradiate excess heat back into space. Emissions of greenhouse gases from human activities may be an important mechanism that affects global climate. Thus, research is intensifying to improve our understanding of the role human activities might play in influencing atmospheric concentrations of greenhouse gases. On the basis of scientific findings of the past few decades, the US Government and the international community at large are now taking steps toward stabilizing greenhouse gas emissions. This report contributes to that process. Mandated by Congress this report provides estimates of US emissions of the principal greenhouse gases--carbon dioxide, methane, nitrous oxide, chlorofluorcarbons, carbon monoxide, nitrogen oxides, and nonmethane volatile organic compounds. Estimates are for the period 1985 to 1990. Preliminary estimates for 1991 have also been included, whenever data were available.

  16. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  17. Steam-reforming of fossil fuels and wastes to produce energy and chemicals without greenhouse gases

    SciTech Connect (OSTI)

    Galloway, T.R.

    1998-07-01

    Worldwide concern has demanded a re-examination of the energy- and chemical-producing plants that use fossil fuel sources and release large quantities of greenhouse gases. Plant retrofits with steam-reformer/gasifiers will increase plant efficiencies, improve economics and avoid releasing troublesome amounts of greenhouse gases, such as carbon dioxide. In this paper, the authors describe and illustrate the several new steam-reforming/gasification plants that are processing waste streams and fossil fuels. These plants range in size from 1 ton/day to 2,000 tons/day. They are commercial and economically successful. These new concepts can be used to both upgrade fossil plants for improved economics while eliminating the release of greenhouse gases. By aggressively retrofitting old coal plants and sequestering CO{sub 2}, a 15% reduction in 1990 CO{sub 2} emissions can be met by the US by 2010.

  18. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J. (Bethel Park, PA)

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  19. Emission of biogenic sulfur gases from Chinese paddy soil and rice plant

    SciTech Connect (OSTI)

    Zhen Yang [Nanjing Univ. of Science and Technology (China); Li Kong [Nanjing Agricultural Univ. (China)

    1996-12-31

    Biogenic sulfur gases emitted from terrestrial ecosystem may play in important role in global sulfur cycle and have a profound influence on global climate change. But very little is known concerning emissions from paddy soil and rice plant, which are abundant in many parts of the world. As a big agricultural country, this is about 33 million hectare rice planted in China. With laboratory incubation and closed chamber method in the field, the biogenic sulfur gases emitted from Chinese paddy soil and rice plant were detected in both conditions: hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), methyl mercaptan (MSH), carbon disulfide (CS{sub 2}), dimethyl sulfide (DMS) and dimethyl disulfide (DMDS). Among which, DMS was predominant part of sulfur emission. Emission of sulfur gases from different paddy field exhibit high spatial and temporal variability. The application of fertilizer and organic manure, total sulfur content in wetland, air temperature were positively correlated to the emission of volatile sulfur gases from paddy soil. Diurnal and seasonal variation of total volatile sulfur gases and DMS indicate that their emissions were greatly influenced by the activity of the rice plant. The annual emission of total volatile sulfur gases, from Nanjing paddy field is ranged from 4.0 to 9.5 mg S m{sup -2}yr{sup -1}, that of DMS is ranged from 3.1 to 6.5 mg S m{sup -2}yr{sup -1}. Rice plant could absorb COS gas, that may be one of the sinks of COS.

  20. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E.; Jalan, Vinod M.

    1984-01-01

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  1. ,"Ohio Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Ohio Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)",1,"Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016" ,"Excel

  2. ,"Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)",1,"Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016"

  3. ,"South Dakota Natural Gas Nonhydrocarbon Gases Removed (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","South Dakota Natural Gas Nonhydrocarbon Gases Removed (MMcf)",1,"Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016" ,"Excel File

  4. ,"Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)",1,"Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016"

  5. ,"Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)",1,"Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016"

  6. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  7. ,"Indiana Natural Gas Nonhydrocarbon Gases Removed (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Indiana Natural Gas Nonhydrocarbon Gases Removed (MMcf)",1,"Monthly","12/2015" ,"Release Date:","2/29/2016" ,"Next Release Date:","3/31/2016" ,"Excel File

  8. ARM - PI Product - ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases Data from ccg-flasks are sampled at the ARM SGP site and analyzed by the NOAA Earth System Research Laboratory (ESRL) as part of the NOAA Cooperative Global Air Sampling Network. Surface samples are collected from a 60m tower at the SGP Central

  9. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  10. Three-body Recombination in Bose Gases with Large Scattering Length

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Three-body Recombination in Bose Gases with Large Scattering Length Citation Details In-Document Search Title: Three-body Recombination in Bose Gases with Large Scattering Length An effective field theory for the three-body system with large scattering length is applied to three-body recombination to a weakly bound s -wave state in a Bose gas. Our model independent analysis demonstrates that the three-body recombination constant {alpha} is not universal,

  11. Outlook for Refinery Outages and Available Refinery Capacity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of gasoline and distillate, and to include a more detailed consideration of the impact of unexpected outages on product supplies. This report reviews the potential...

  12. PSM implementation at a refinery

    SciTech Connect (OSTI)

    Nahale, T.

    1995-12-31

    Prior to the promulgation of the OSHA Standard on Process Safety Management (PSM), the petroleum industry had a precursor developed by the American Petroleum Institute titled Recommended Practice 750, Management of Process Hazards. This Recommended Practice, though not identical with the OSHA regulation, provided the industry with a voluntary standard prior to May, 1992, when PSM went into effect. In formulating a PSM implementation strategy, one of the first decisions encountered at a facility is whether to utilize a separate group dedicated full-time to PSM issues, or to develop the program using key individuals who continue to perform their regulator job duties. Although a PSM manager may prefer one strategy over the other, this staffing decisions is normally made by senior management at the facility.

  13. Integrated Forest Products Refinery (IFPR)

    SciTech Connect (OSTI)

    van Heiningen, Adriaan R. P.

    2010-05-29

    Pre-extraction–kraft studies of hardwoods showed that when extracting about 10% of the wood, the final kraft pulp yield and physical properties could only be maintained at a level similar to that of regular kraft pulp when the final extract pH was close to neutral. This so-called “near neutral” pre-extraction condition at a level of 10% wood dissolution was achieved by contacting the wood chips with green liquor (GL) at a charge of about 3% (as Na2O on wood) at 160 °C for almost 2 hours (or an H-factor of about 800 hrs.). During subsequent kraft cooking of the pre-extracted hardwood chips the effective alkali charge could be reduced by about 3% (as Na2O on wood) and the cooking time shortened relative to that during regular kraft cooking, while still producing the same bleachable grade kappa number as the kraft control pulp. For softwood, no extraction conditions were discovered in the present investigation whereby both the final kraft pulp yield and physical properties could be maintained at a level similar to that of regular softwood kraft pulp. Therefore for hardwoods the “near- neutral green liquor pre-extraction conditions do meet the requirements of the IFPR concept, while for softwood, no extraction conditions were discovered which do meet these requirements. Application of simulated industrial GL at an extraction H-factor of about 800 hrs and 3% GL charge in a recirculating digester produced an hardwood extract containing about 4% (on wood) of total anhydro-sugars, 2% of acetic acid, and 1.3% of lignin. Xylan comprised of 80% of the sugars of which about 85% is oligomeric. Since only polymeric hemicelluloses and lignin may be adsorbed on pulp (produced at a yield of about 50% from the original wood), the maximum theoretical yield increase due to adsorption may be estimated as 10% on pulp (or 5% on wood). However, direct application of raw GL hardwood extract for hemicelluloses adsorption onto hardwood kraft pulp led to a yield increase of only about 1% (on pulp). By using the wet-end retention aid guar gum during the adsorption process at a charge of 0.5% on pulp the yield gain may be increased to about 5%. Unfortunately, most of this yield increase is lost during subsequent alkaline treatments in the pulp bleach plant. It was found that by performing the adsorption at alkaline conditions the adsorption loss during alkaline treatment in the bleach plant is mostly avoided. Thus a permanent adsorption yield of about 3 and 1.5% (on pulp) was obtained with addition of guar gum at a charge of 0.5 and 0.1% respectively during adsorption of GL hardwood extract on pre-extracted kraft pulp at optimal conditions of pH 11.5, 90 C for 60 minutes at 5% consistency. The beatability of the adsorbed kraft pulps was improved. Also, significant physical strength improvements were achieved. Further study is needed to determine whether the improvements in pulp yield and paper properties make this an economic IFPR concept. Application of the wood solids of a hot water extract of Acer rubrum wood strands as a substitute for polystyrene used for production of SMC maintained the water adsorption properties of the final product. Further work on the physical properties of the hemicellulose containing SMCs need to be completed to determine the potential of wood extracts for the production of partially renewable SMCs. The discovery of the “near-neutral” green liquor extraction process for hardwood was formed the basis for a commercial Integrated Biorefinery that will extract hemicelluloses from wood chips to make biofuels and other specialty chemicals. The pulp production process will be maintained as is proposed in the present researched IFBR concept. This Integrated Biorefinery will be constructed by Red Shield Acquisition LLC (RSA) at the Old Town kraft pulp mill in Maine. RSA in collaboration with the University of Maine will develop and commercialize the hemicellulose extraction process, the conversion of the hemicellulose sugars into butanol by fermentation, and the separation of specialty chemicals such as acetic acid fr

  14. Refinery Outages: First Half 2015

    Gasoline and Diesel Fuel Update (EIA)

    to increase by 820,000 bbld in 2015. While global oil supply growth has been strong, economic growth outside of the United States has been slow, particularly in Russia and...

  15. Refinery Outages: First Half 2015

    Gasoline and Diesel Fuel Update (EIA)

    Analysis & Projections Glossary › FAQS › Overview Projection Data Monthly short-term forecasts to 2016 Annual projections to 2040 International projections All projections reports Analysis & Projections Major Topics Most popular Annual Energy Outlook related Congressional & other requests International Energy Outlook related Presentations Recurring Short-Term Outlook Related Special outlooks Testimony All reports Browse by Tag Alphabetical Frequency Tag Cloud Full report Previous

  16. U.S. Refinery Stocks

    U.S. Energy Information Administration (EIA) Indexed Site

    Area: U.S. PADD 1 East Coast Appalachian No. 1 PADD 2 Ind., Ill. and Ky. Minn., Wis., N. Dak., S. Dak. Okla., Kans., Mo. PADD 3 Texas Inland Texas Gulf Coast La. Gulf Coast N. La., Ark New Mexico PADD 4 PADD 5 Period-Units: Monthly-Thousand Barrels Annual-Thousand Barrels Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History Crude Oil and Petroleum

  17. Documentation for Emissions of Greenhouse Gases in the United States 2008

    Reports and Publications (EIA)

    2011-01-01

    The Energy Policy Act of 1992 required the U.S. Energy Information Administration (EIA) to prepare an inventory of aggregate U.S. national emissions of greenhouse gases for the period 1987-1990, with annual updates thereafter. This report documents the methodology for the seventeenth annual inventory, covering national emissions over the period 1990-2008.

  18. Greenhouse gases emission from municipal waste management: The role of separate collection

    SciTech Connect (OSTI)

    Calabro, Paolo S.

    2009-07-15

    The municipal solid waste management significantly contributes to the emission in the atmosphere of greenhouse gases (e.g. CO{sub 2}, CH{sub 4}, N{sub 2}O) and therefore the management process from collection to treatment and disposal has to be optimized in order to reduce these emissions. In this paper, starting from the average composition of undifferentiated municipal solid waste in Italy, the effect of separate collection on greenhouse gases emissions from municipal waste management has been assessed. Different combinations of separate collection scenarios and disposal options (i.e. landfilling and incineration) have been considered. The effect of energy recovery from waste both in landfills and incinerators has also been addressed. The results outline how a separate collection approach can have a significant effect on the emission of greenhouse gases and how wise municipal solid waste management, implying the adoption of Best Available Technologies (i.e. biogas recovery and exploitation system in landfills and energy recovery system in Waste to Energy plants), can not only significantly reduce greenhouse gases emissions but, in certain cases, can also make the overall process a carbon sink. Moreover it has been shown that separate collection of plastic is a major issue when dealing with global warming relevant emissions from municipal solid waste management.

  19. Comment on "Radiative forcings for 28 potential Archean greenhouse gases" by Byrne and Goldblatt (2014)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kochanov, R. V.; Gordon, I. E.; Rothman, L. S.; Sharpe, S. W.; Johnson, T. J.; Sams, R. L.

    2015-08-25

    In the recent article by Byrne and Goldblatt, "Radiative forcing for 28 potential Archean greenhouse gases", Clim. Past. 10, 1779–1801 (2014), the authors employ the HITRAN2012 spectroscopic database to evaluate the radiative forcing of 28 Archean gases. As part of the evaluation of the status of the spectroscopy of these gases in the selected spectral region (50–1800 cm-1), the cross sections generated from the HITRAN line-by-line parameters were compared with those of the PNNL database of experimental cross sections recorded at moderate resolution. The authors claimed that for NO2, HNO3, H2CO, H2O2, HCOOH, C2H4, CH3OH and CH3Br there exist largemore » or sometimes severe disagreements between the databases. In this work we show that for only three of these eight gases a modest discrepancy does exist between the two databases and we explain the origin of the differences. For the other five gases, the disagreements are not nearly at the scale suggested by the authors, while we explain some of the differences that do exist. In summary, the agreement between the HITRAN and PNNL databases is very good, although not perfect. Typically differences do not exceed 10 %, provided that HITRAN data exist for the bands/wavelengths of interest. It appears that a molecule-dependent combination of errors has affected the conclusions of the authors. In at least one case it appears that they did not take the correct file from PNNL (N2O4 (dimer)+ NO2 was used in place of the monomer). Finally, cross sections of HO2 from HITRAN (which do not have a PNNL counterpart) were not calculated correctly in BG, while in the case of HF misleading discussion was presented there based on the confusion by foreign or noise features in the experimental PNNL spectra.« less

  20. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOE Patents [OSTI]

    Judkins, R.R.; Burchell, T.D.

    1999-07-20

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known pressure swing adsorption'' technique utilizing the same sorption material. 1 fig.

  1. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOE Patents [OSTI]

    Judkins, Roddie R. (9917 Rainbow Dr., Knoxville, TN 37922); Burchell, Timothy D. (109 Greywood Pl., Oak Ridge, TN 37830)

    1999-01-01

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known "pressure swing adsorption" technique utilizing the same sorption material.

  2. untitled

    Gasoline and Diesel Fuel Update (EIA)

    - - - - - -6 - - - Natural Gas Liquids and LRGs 306 120 93 26 - 37 95 15 398 Pentanes Plus 33 0 1 22 - 0 43 4 10 Liquefied Petroleum Gases 273 120 92 4 - 37 52 11 388 Ethane...

  3. untitled

    Gasoline and Diesel Fuel Update (EIA)

    - - - - - 72 - - - Natural Gas Liquids and LRGs 240 66 147 149 - -293 176 8 710 Pentanes Plus 29 0 2 33 - -1 57 5 2 Liquefied Petroleum Gases 212 66 146 116 - -292 120 3 707...

  4. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    - - - - - 14 - - - Natural Gas Liquids and LRGs 298 103 102 50 - -4 115 14 428 Pentanes Plus 33 0 1 25 - 0 48 4 7 Liquefied Petroleum Gases 265 103 101 25 - -4 68 9 420 Ethane...

  5. untitled

    Gasoline and Diesel Fuel Update (EIA)

    - - - - - -68 - - - Natural Gas Liquids and LRGs 297 78 90 47 - -47 131 13 415 Pentanes Plus 37 0 1 26 - 0 58 3 4 Liquefied Petroleum Gases 260 78 89 20 - -47 74 10 411 Ethane...

  6. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    - - - - - 14 - - - Natural Gas Liquids and LRGs 298 105 110 47 - -5 118 14 433 Pentanes Plus 33 - 1 25 - 0 48 4 7 Liquefied Petroleum Gases 265 105 109 22 - -4 70 9 426 Ethane...

  7. U.S. Exports of Crude Oil and Petroleum Products

    Gasoline and Diesel Fuel Update (EIA)

    153,972 141,476 146,514 143,463 144,525 163,526 1981-2015 Crude Oil 16,312 14,293 12,273 15,501 9,596 12,167 1920-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 31,654 30,723 34,091 30,066 31,743 33,089 1981-2015 Pentanes Plus 6,200 6,116 7,006 4,753 6,020 5,261 1984-2015 Liquefied Petroleum Gases 25,454 24,607 27,085 25,312 25,723 27,827 1981-2015 Ethane/Ethylene 2,024 1,860 1,532 2,113 1,976 1,985 1981-2015 Propane/Propylene 19,359 18,494 22,171 19,292 20,268 23,266 1981-2015

  8. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

    1998-01-01

    Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

  9. A comprehensive study of different gases in inductively coupled plasma torch operating at one atmosphere

    SciTech Connect (OSTI)

    Punjabi, Sangeeta B.; Joshi, N. K.; Mangalvedekar, H. A.; Lande, B. K.; Das, A. K.; Kothari, D. C.

    2012-01-15

    A numerical study is done to understand the possible operating regimes of RF-ICP torch (3 MHz, 50 kW) using different gases for plasma formation at atmospheric pressure. A two dimensional numerical simulation of RF-ICP torch using argon, nitrogen, oxygen, and air as plasma gas has been investigated using computational fluid dynamic (CFD) software fluent{sup (c)}. The operating parameters varied here are central gas flow, sheath gas flow, RF-power dissipated in plasma, and plasma gas. The temperature contours, flow field, axial, and radial velocity profiles were investigated under different operating conditions. The plasma resistance, inductance of the torch, and the heat distribution for various plasma gases have also been investigated. The plasma impedance of ICP torch varies with different operating parameters and plays an important role for RF oscillator design and power coupling. These studies will be useful to decide the design criteria for ICP torches required for different material processing applications.

  10. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    1998-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  11. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, J.L.

    1998-09-15

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

  12. Membranes, methods of making membranes, and methods of separating gases using membranes

    DOE Patents [OSTI]

    Ho, W. S. Winston

    2012-10-02

    Membranes, methods of making membranes, and methods of separating gases using membranes are provided. The membranes can include at least one hydrophilic polymer, at least one cross-linking agent, at least one base, and at least one amino compound. The methods of separating gases using membranes can include contacting a gas stream containing at least one of CO.sub.2, H.sub.2S, and HCl with one side of a nonporous and at least one of CO.sub.2, H.sub.2S, and HCl selectively permeable membrane such that at least one of CO.sub.2, H.sub.2S, and HCl is selectively transported through the membrane.

  13. Methane activation using noble gases in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-08-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gases—He, Ne, and Ar—as additives. The empirical results obtained clearly indicate that methane activation is considerably affected by thy type of noble gas used. Through 0-D calculations, the discharge parameters inside the reactor, i.e., electron temperature and electron density, are estimated using experiment results. A comparison of the discharge characteristics and experimental results shows that the electron temperature is an important factor in achieving high methane activation and the mixture with Ar gas shows the highest methane conversion. These results are constructed using the mechanisms of energy and charge transfer from excited and ionized noble gas atoms to methane molecules, considering the number density of active atoms of noble gases. Finally, electron temperatures obtained for gas mixtures having different reactant compositions and concentrations are analyzed to estimate methane activation.

  14. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C.J.; Mackenzie, P.D.

    1982-09-03

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  15. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

    1985-01-01

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  16. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

    1998-01-13

    Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor. 2 figs.

  17. EIA-Voluntary Reporting of Greenhouse Gases Program - Emission Factors and

    Gasoline and Diesel Fuel Update (EIA)

    Global Warming Emission Factors Voluntary Reporting of Greenhouse Gases Program Emission Factors and Global Warming Potentials The greenhouse gas emission factors and global warming potentials (GWPs) presented on this page should be used for preparing emission inventories and calculating emission reductions submitted to U.S. Energy Information Administration (EIA) on Form EIA-1605(b). Fuel and Energy Emission Factors: Instructions | HTML | Tables Electricity Emission Factors: Instructions |

  18. Nonlinear spectroscopic effects in quantum gases induced by atom-atom interactions

    SciTech Connect (OSTI)

    Safonov, A. I. Safonova, I. I.; Yasnikov, I. S.

    2013-05-15

    We consider nonlinear spectroscopic effects-interaction-enhanced double resonance and spectrum instability-that appear in ultracold quantum gases owing to collisional frequency shift of atomic transitions and, consequently, due to the dependence of the frequencies on the population of various internal states of the particles. Special emphasis is put to two simplest cases, (a) the gas of two-level atoms and (b) double resonance in a gas of three-level bosons, in which the probe transition frequency remains constant.

  19. EIA-Voluntary Reporting of Greenhouse Gases Program - Original 1605(b)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Schedule Voluntary Reporting of Greenhouse Gases Program Revised Launch Schedule EIA will begin accepting both Start Year and Reporting Year reports using the Workbook Form on April 6, 2011. Please see the below reporting schedule for this data cycle: Launch Date: April 6, 2011 Self-Certified Reports Due: July 1, 2011 Third-Party Verified Reports Due: September 1, 2011 This schedule is subject to change and any changes will be communicated to reporters immediately. Please see the

  20. EIA-Voluntary Reporting of Greenhouse Gases Program - Section 1605 Text

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Section 1605 Text Voluntary Reporting of Greenhouse Gases Program Section 1605 Text Energy Policy Act of 1992 [Full Text] (a) NATIONAL INVENTORY.- Not later than 18 months after the date of the enactment of this Act, the Secretary, through the Energy Information Administration, shall develop, based on data available to, and obtained by, the Energy Information Administration, an inventory of the national aggregate emissions of each greenhouse gas for each calendar year of the baseline period of

  1. EVOLUTION OF SOME PARTICLE DETECTORS BASED ON THE DISCHARGE IN GASES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    61 - EVOLUTION OF SOME PARTICLE DETECTORS BASED ON THE DISCHARGE IN GASES G. Charpak CERN, Geneva, Switzerland. INTRODUCTION In this year 1969, if we look into the experimental techniques used around high-energy accelerators we observe the following situation: the bubble chamber is still an important tool, absorbing a large fraction of the activity of the community of experimentalists. Its evolution is directed towards a greater efficiency and rapidity in the automatic evalu- ation of pictures,

  2. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  3. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect (OSTI)

    1995-09-25

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  4. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  5. Petroleum Supply Monthly

    U.S. Energy Information Administration (EIA) Indexed Site

    ... North Louisiana, Arkansas New Mexico Total Liquefied Refinery Gases ......370 3,534 3,363 - - 7,267 13 57 9,074 Normal ButaneButylene ......

  6. Petroleum Supply Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    ... North Louisiana, Arkansas New Mexico Total Liquefied Refinery Gases ......416 3,228 3,170 - - 6,814 19 342 8,718 Normal ButaneButylene ......

  7. untitled

    U.S. Energy Information Administration (EIA) Indexed Site

    ... North Louisiana, Arkansas New Mexico Total Liquefied Refinery Gases ......38,612 126 - 80,904 197 3,607 102,565 Normal ButaneButylene ......

  8. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    change by sulfur content may not equal total residual fuel oil ending stocks and stock change. LRG Liquefied Refinery Gases. - Not Applicable. Notes: Totals may not equal...

  9. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distributionmore » functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.« less

  10. The Marginal Damage Costs of Different Greenhouse Gases: An Application of FUND

    SciTech Connect (OSTI)

    Waldhoff, Stephanie T.; Anthoff, David; Rose, Steven K.; Tol, Richard

    2014-01-01

    We use FUND 3.8 to estimate the social cost of four greenhouse gases: carbon dioxide, methane, nitrous oxide, and sulphur hexafluoride emissions. The damage potential for each gas—the ratio of the social cost of the non-carbon dioxide greenhouse gas to the social cost of carbon dioxide—is also estimated. The damage potentials are compared to several metrics, focusing in particular on the global warming potentials, which are frequently used to measure the trade-off between gases in the form of carbon dioxide equivalents. We find that damage potentials could be significantly higher than global warming potentials. This finding implies that previous papers have underestimated the relative importance of reducing non-carbon dioxide greenhouse gas emissions from an economic damage perspective. We show results for a range of sensitivity analyses: carbon dioxide fertilization on agriculture productivity, terrestrial feedbacks, climate sensitivity, discounting, equity weighting, and socioeconomic and emissions scenarios. The sensitivity of the results to carbon dioxide fertilization is a primary focus as it is an important element of climate change that has not been considered in much of the previous literature. We estimate that carbon dioxide fertilization has a large positive impact that reduces the social cost of carbon dioxide with a much smaller effect on the other greenhouse gases. As a result, our estimates of the damage potentials of methane and nitrous oxide are much higher compared to estimates that ignore carbon dioxide fertilization. As a result, our base estimates of the damage potential for methane and nitrous oxide that include carbon dioxide fertilization are twice their respective global warming potentials. Our base estimate of the damage potential of sulphur hexafluoride is similar to the one previous estimate, both almost three times the global warming potential.

  11. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    SciTech Connect (OSTI)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

  12. Unconventional states and geometric effects in mesoscopic systems of ultra-cold atomic Fermi gases

    SciTech Connect (OSTI)

    Bolech, C. J.

    2014-10-15

    During the last decade, experiments all over the world started to test the superconducting state of matter using a newly developed mesoscopic tunable system: trapped ultra-cold atomic gases. Theorists and experimentalists hand-in-hand are now able to advance our understanding of the superconducting state by asking new questions that probe further into the physical mechanisms underlying the phenomenon and the door is open to the exploration of exotic unconventional superconducting states. In particular, a series of experiments on systems of trapped cold atomic gases were aimed at studying the effects of polarization on superconducting pairing. Two different experimental groups encountered surprising qualitative and quantitative discrepancies which seemed to be a function of the confining geometry and the cooling protocol. Our numerical studies demonstrate a tendency towards metastability and suggest an explanation for the observed discrepancy. From our calculations, the most likely solution which is consistent with the experiments supports a state strikingly similar to the so called FFLO state (after Ferrell, Fulde, Larkin and Ovchinnikov), which had been theorized long ago but eluded detection so far. Moreover, the three-dimensional scenario described above is reminiscent of predictions for one-dimensional systems of dilute polarized attractive gases and another set of ultra-cold-atom experiments incorporates optical lattices to study this reduced-dimensionality setting. The measurements are in quantitative agreement with theoretical calculations (using a wide array of numerical and analytic techniques) in which a partially polarized phase is found to be the one-dimensional analogue of the FFLO state. Moreover, exploring the dimensional-crossover regime, our latest findings indicate that the mesoscopic nature of these quasi-one-dimensional systems favors the appearance of a new type of Mott phase transition involving an emergent pair-superfluid of equal-spin fermions.

  13. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  14. Molecular dynamics of gases and vapors in nanoporous solids. Final LDRD project report

    SciTech Connect (OSTI)

    Pohl, P.I.

    1996-08-01

    This report provides a study of gases in microporous solids using molecular modeling. The theory of gas transport in porous materials as well as the molecular modeling literature is briefly reviewed. Work complete is described and analyzed with retard to the prevailing theory. The work covers two simple subjects, construction of porous solid models and diffusion of He, H{sub 2}, Ar and CH{sub 4} down a pressure gradient across the material models as in typical membrane permeation experiments. The broader objective is to enhance our capability to efficiently and accurately develop, produce and apply microporous materials.

  15. Electric-field enhanced performance in catalysis and solid-state devices involving gases

    DOE Patents [OSTI]

    Blackburn, Bryan M.; Wachsman, Eric D.; Van Assche, IV, Frederick Martin

    2015-05-19

    Electrode configurations for electric-field enhanced performance in catalysis and solid-state devices involving gases are provided. According to an embodiment, electric-field electrodes can be incorporated in devices such as gas sensors and fuel cells to shape an electric field provided with respect to sensing electrodes for the gas sensors and surfaces of the fuel cells. The shaped electric fields can alter surface dynamics, system thermodynamics, reaction kinetics, and adsorption/desorption processes. In one embodiment, ring-shaped electric-field electrodes can be provided around sensing electrodes of a planar gas sensor.

  16. Enhancement of NMR and MRI in the presence of hyperpolarized noble gases

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2004-11-16

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  17. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect (OSTI)

    LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

    2000-07-21

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

  18. Sampling and analysis of hydrocarbons in combustion gases. Annual report, October 1979-September 1980

    SciTech Connect (OSTI)

    Johnson, I.; Myles, K.M.; Siczek, A.A.

    1981-04-01

    The purpose of these studies is to develop a method for the chemical analysis of ultratrace levels of polycyclic organic compounds in the flue gases from fluidized-bed combustors. Methods which have the potential for real time analysis have been studied. Two methods, double mass spectrometry and laser ionization mass spectrometry, appear to be promising. A brief review of current analytical methods has been made. A brief examination of fly ash from fluidized-bed combustion revealed no carcinogenic species although samples collected during fluidized-bed combustor startup were found to be mutagenic.

  19. Pressurized release of liquefied fuel gases (LNG and LPG). Topical report, May 1993-February 1996

    SciTech Connect (OSTI)

    Atallah, S.; Janardhan, A.

    1996-02-01

    This report is an important contribution to the behavior of pressurized liquefied gases when accidentally released into the atmosphere. LNG vehicle fueling stations and LPG storage facilities operate at elevated pressures. Accidental releases could result in rainout and the formation of an aerosol in the vapor cloud. These factors must be considered when estimating the extent of the hazard zone of the vapor cloud using a heavier-than-air gas dispersion model such as DEGADIS (or its Windows equivalent DEGATEC). The DOS program PREL has been incorporated in the Windows program LFGRISK.

  20. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  1. Fractionation of soil gases by diffusion of water vapor, gravitational settling, and thermal diffusion

    SciTech Connect (OSTI)

    Severinghaus, J.P.; Bender, M.L. [Univ. of Rhode Island, RI (United States)] [Univ. of Rhode Island, RI (United States); Keeling, R.F. [Scripps Institution of Oceanography, LaJolla, CA (United States)] [Scripps Institution of Oceanography, LaJolla, CA (United States); Broecker, W.S. [Lamont-Doherty Earth Observatory, Palisades, NY (United States)] [Lamont-Doherty Earth Observatory, Palisades, NY (United States)

    1996-03-01

    Air sampled from the moist unsaturated zone in a sand dune exhibits depletion in the heavy isotopes of N{sub 2} and O{sub 2}. We propose that the depletion is caused by a diffusive flux of water vapor out of the dune, which sweeps out the other gases, forcing them to diffuse back into the dune. The heavy isotopes of N{sub 2} and O{sub 2} diffuse back more slowly, resulting in a steady-state depletion of the heavy isotopesin the dune interior. We predict the effect`s magnitude with molecular diffusion theory and reproduce it in a laboratory simulation, finding good agreement between field, theory, and lab. The magnitude of the effect is governed by the ratio of the binary diffusivities against water vapor of a pair of gases, and increases {approximately} linearly with the difference between the water vapor mole fraction of the site and the advectively mixed reservoir with which it is in diffusive contact (in most cases the atmosphere). 32 refs., 1 fig., 3 tabs.

  2. Biexciton formation and exciton coherent coupling in layered GaSe

    SciTech Connect (OSTI)

    Dey, P.; Paul, J.; Stevens, C. E.; Glikin, N.; Karaiskaj, D.; Moody, G.; Kovalyuk, Z. D.; Kudrynskyi, Z. R.; Romero, A. H.; Cantarero, A.; Hilton, D. J.

    2015-06-07

    Nonlinear two-dimensional Fourier transform (2DFT) and linear absorption spectroscopy are used to study the electronic structure and optical properties of excitons in the layered semiconductor GaSe. At the 1s exciton resonance, two peaks are identified in the absorption spectra, which are assigned to splitting of the exciton ground state into the triplet and singlet states. 2DFT spectra acquired for co-linear polarization of the excitation pulses feature an additional peak originating from coherent energy transfer between the singlet and triplet. At cross-linear polarization of the excitation pulses, the 2DFT spectra expose a new peak likely originating from bound biexcitons. The polarization dependent 2DFT spectra are well reproduced by simulations using the optical Bloch equations for a four level system, where many-body effects are included phenomenologically. Although biexciton effects are thought to be strong in this material, only moderate contributions from bound biexciton creation can be observed. The biexciton binding energy of ?2 meV was estimated from the separation of the peaks in the 2DFT spectra. Temperature dependent absorption and 2DFT measurements, combined with “ab initio” theoretical calculations of the phonon spectra, indicate strong interaction with the A{sub 1}{sup ?} phonon mode. Excitation density dependent 2DFT measurements reveal excitation induced dephasing and provide a lower limit for the homogeneous linewidth of the excitons in the present GaSe crystal.

  3. The Effect of Diluent Gases In The Shock Tube and Rapid Compression Machine

    SciTech Connect (OSTI)

    Silke, E; W?rmel, J; O?Conaire, M; Simmie, J; Curran, H

    2007-02-09

    Studying the details of hydrocarbon chemistry in an internal combustion engine is not straightforward. A number of factors, including varying conditions of temperature and pressure, complex fluid motions, as well as variation in the composition of gasoline, render a meaningful characterization of the combusting system difficult. Some simplified experimental laboratory devices offer an alternative to complex engine environments: they remove some of the complexities that exist in real engines but retain the ability to work under engine-relevant conditions. The choice of simplified experimental devices is limited by the range of temperature and pressure at which they can operate; only the shock tube and rapid compression machine (RCM) can reach engine-relevant temperatures and pressures quickly enough and yet withstand the high pressures that occur after the ignition event. Both devices, however, suffer a common drawback: the use of inert diluent gases has been shown to affect the measured ignition delay time under some experimental conditions. Interestingly, this effect appears to be opposite in the shock tube and RCM: in the comparative study of the carrier gases argon and nitrogen, argon decreases the ignition delay time in the shock tube, but increases it in the RCM. This observation is investigated in more detail in this study.

  4. Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases. Final report

    SciTech Connect (OSTI)

    Prather, Michael J.; Hsu, Juno; Nicolau, Alex; Veidenbaum, Alex; Smith, Philip Cameron; Bergmann, Dan

    2014-11-07

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  5. Fluctuations of the number of particles within a given volume in cold quantum gases

    SciTech Connect (OSTI)

    Astrakharchik, G. E.; Combescot, R.; Pitaevskii, L. P.

    2007-12-15

    In ultracold gases many experiments use atom imaging as a basic observable. The resulting image is averaged over a number of realizations and mostly only this average is used. Only recently the noise has been measured to extract physical information. In the present paper we investigate the quantum noise arising in these gases at zero temperature. We restrict ourselves to the homogeneous situation and study the fluctuations in particle number found within a given volume in the gas, and more specifically inside a sphere of radius R. We show that zero-temperature fluctuations are not extensive and the leading term scales with sphere radius R as R{sup 2} ln R (or ln R) in three- (or one-) dimensional systems. We calculate systematically the next term beyond this leading order. We consider first the generic case of a compressible superfluid. Then we investigate the whole Bose-Einstein-condensation (BEC) -BCS crossover, and in particular the limiting cases of the weakly interacting Bose gas and of the free Fermi gas.

  6. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-09-30

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

  7. Voluntary reporting of greenhouse gases under Section 1605(b) of the Energy Policy Act of 1992

    SciTech Connect (OSTI)

    Holt, E. Jr.; Vernet, J.E. Jr.

    1994-12-31

    DOE is developing guidelines for the voluntary reporting of greenhouse gas emissions and their reductions, under Section 1605(b) of the Energy Policy Act of 1992. The establishment of this voluntary program should encourage the reduction of greenhouse gases while providing the opportunity to share innovative approaches to achieving such reductions. This social learning aspect is an important element of the program. In addition to greenhouse gas reductions achieved during a given year, reporters are encouraged to also report their actual emissions of such gases for 1987 through 1990. Due to the voluntary nature of this program, and the myriad differences among the potential reporting entities and possible uses for the data reported, the guidelines will need to be structured so as to maximize participation without compromising the usefulness of the data collected. Through a broad notice of inquiry, published in the Federal Register on July 27, 1993, the Department began seeking input into development of the guidelines. Subsequently, to gain a better understanding of the various sectors of the economy, six public workshops were held during the 1993. One workshop addressed institutional issues of potential interest to all sectors of the economy, with the other five workshops focusing more on matters of concern to specific sectors. These meetings were structured so as to provide broad representation from potential reporting entities along with public interest organizations. It is clear that there are significant variations among those reporting greenhouse information. Presently voluntary, the program will need flexibility to encourage broad participation.

  8. Radiolytic and radiolytically induced generation of gases from synthetic wastes. Final report

    SciTech Connect (OSTI)

    Meisel, D.; Jonah, C.D.; Kapoor, S.; Matheson, M.S.; Sauer, M.C. Jr.

    1993-10-01

    To better understand the processes leading to the generation and release of gases from waste tanks, the authors studied the radiolytic and thermal generation of H{sub 2}, N{sub 2}O, N{sub 2}, O{sub 2}, and NH{sub 3} in nonradioactive waste simulant solutions and slurries. The radiolytic sources for H{sub 2} are e{sub aq}{sup {minus}} and its predecessors and H atoms. Radiolysis of the water generates some H{sub 2} and an additional amount comes from the hydrogen abstraction reaction H + RH{yields}H{sub 2}+R{center_dot}. Nitrate scavenges e{sub aq}{sup {minus}} and its predecessors whereas nitrite is the major H-atom scavenger. Computer modeling shows that if [NO{sub 3}{sup {minus}}] is above 0.5 M, and [NO{sub 2}{sup {minus}}] is above 2M, the addition of other scavengers will have little effect on the yield of H{sub 2}. In the presence of organic molecules O{sub 2} is efficiently destroyed. Small yields of ammonia were measured and the yields increase linearly with dose. The nitrogen in NH{sub 3} comes from organic chelators. The yields of gases in solution depend only weakly on temperature. The rate of thermal generation of gases increases upon preirradiation, reaches a maximum, and then declines. The known radiolytic degradation products of chelators, NTA, IDA, glycolate, glyoxylate, formaldehyde, formate, oxalate, and hydroxylainine were examined for their roles in the thermal generation of H{sub 2} and N{sub 2}O at 60{degrees}C. In solution or slurry only radiolytically produced Pd intermediate strongly retains H{sub 2}. Radiolytic yields of N{sub 2}O are strongly reduced by Cr(III). In irradiated slurry, loose and tight gas were found. The loose gas could be removed by bubbling from the slurry, but the tight gas could be released only by dissolution of the slurry.

  9. Load Preheating Using Flue Gases from a Fuel-Fired Heating System; Industrial Technologies Program (ITP) Energy Tips - Process Heating Tip Sheet #9 (Fact Sheet).

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 * January 2006 Industrial Technologies Program Load Preheating Using Flue Gases from a Fuel-Fired Heating System The thermal efficiency of a heating system can be improved significantly by using heat contained in furnace flue gases to preheat the furnace load (material coming into the furnace). If exhaust gases leaving a fuel-fired furnace can be brought into contact with a relatively cool incoming load, heat will be transferred directly to the load. Since there is no intermediate step, like

  10. Method for determining the concentration of atomic species in gases and solids

    DOE Patents [OSTI]

    Loge, Gary W. (2998 Plaza Blanca, Santa Fe, NM 87505)

    1999-01-01

    Method for determining the concentration of atomic species in gases and solids. Measurement of at least two emission intensities from a species in a plasma containing the species after a sufficient time period has elapsed after the generation of the plasma and during a second time period, permits an instantaneous temperature to be established within the sample. The concentration of the atomic species to be determined is then derived from the known emission intensity of a predetermined concentration of that species in the sample at the measured temperature, a quantity which is measured prior to the determination of the unknown concentration, and the actual measured emission from the unknown species, or by this latter emission and the emission intensity of a species having known concentration within the sample.

  11. Analytical limits for cold-atom Bose gases with tunable interactions

    SciTech Connect (OSTI)

    Mihaila, Bogdan; Chien, Chih-Chun; Timmermans, Eddy; Cooper, Fred; Dawson, John F.

    2011-08-15

    We discuss the equilibrium properties of dilute Bose gases using a nonperturbative formalism based on auxiliary fields related to the normal and anomalous densities. We show analytically that for a dilute Bose gas of weakly interacting particles at zero temperature, the leading-order auxiliary field (LOAF) approximation leads to well-known analytical results. Close to the critical point the LOAF predictions are the same as those obtained using an effective field theory in the large-N approximation. We also report analytical approximations for the LOAF results in the unitarity limit, which compare favorably with our numerical results. LOAF predicts that the equation of state for the Bose gas in the unitarity limit is E/(pV)=1, unlike the case of the Fermi gas when E/(pV)=3/2.

  12. Differential total absorptivity solution to the radiative transfer equation for mixtures of combustion gases and soot

    SciTech Connect (OSTI)

    Bressloff, N.W.; Moss, J.B.; Rubini, P.A.

    1997-01-01

    The differential total absorptivity (DTA) solution to the radiative transfer equation, originally devised for combustion gases in the discrete transfer radiation model, is extended to mixtures of gaseous combustion products and soot. The method is compared to other solution techniques for representative mixtures across single lines of sight and across a layer bounded by solid walls. Intermediate soot loadings are considered such that the total radiance is not dominated by either the gaseous or soot components. The DTA solution is shown to yield excellent accuracy relative to a narrow-band solution, with a considerable saving in computational cost. Thus, explicit treatment of the source temperature dependence of absorption is successfully demonstrated without the need for spectral integration.

  13. Role of fourth-order phase-space moments in collective modes of trapped Fermi gases

    SciTech Connect (OSTI)

    Chiacchiera, Silvia; Lepers, Thomas; Davesne, Dany; Urban, Michael

    2011-10-15

    We study the transition from hydrodynamic to collisionless behavior in collective modes of ultracold trapped Fermi gases. To that end, we solve the Boltzmann equation for the trapped Fermi gas via the moments method. We showed previously that it is necessary to go beyond second-order moments if one wants to reproduce the results of a numerical solution of the Boltzmann equation. Here, we will give the detailed description of the method including fourth-order moments. We apply this method to the case of realistic parameters, and compare the results for the radial quadrupole and scissors modes at unitarity to experimental data obtained by the Innsbruck group. It turns out that the inclusion of fourth-order moments clearly improves the agreement with the experimental data. In particular, the fourth-order moments reduce the effect of collisions and therefore partially compensate the effect of the enhanced in-medium cross section at low temperatures.

  14. Method for determining the concentration of atomic species in gases and solids

    DOE Patents [OSTI]

    Loge, Gary W. (304 Cheryl Ave., Los Alamos, NM 87544)

    1998-01-01

    Method for determining the concentration of atomic species in gases and solids. Measurement of at least two emission intensities from a species in a sample that is excited by incident laser radiation. Which generates a plasma therein after a sufficient time period has elapsed and during a second time period, permits an instantaneous temperature to be established within the sample. The concentration of the atomic species to be determined is then derived from the known emission intensity of a predetermined concentration of that species in the sample at the measured temperature, a quantity which is measured prior to the determination of the unknown concentration, and the actual measured emission from the unknown species, or by this latter emission and the emission intensity of a species having known concentration within the sample such as nitrogen for gaseous air samples.

  15. Atom chip apparatus for experiments with ultracold rubidium and potassium gases

    SciTech Connect (OSTI)

    Ivory, M. K.; Ziltz, A. R.; Fancher, C. T.; Pyle, A. J.; Sensharma, A.; Chase, B.; Field, J. P.; Garcia, A.; Aubin, S.; Jervis, D.

    2014-04-15

    We present a dual chamber atom chip apparatus for generating ultracold {sup 87}Rb and {sup 39}K atomic gases. The apparatus produces quasi-pure Bose-Einstein condensates of 10{sup 4} {sup 87}Rb atoms in an atom chip trap that features a dimple and good optical access. We have also demonstrated production of ultracold {sup 39}K and subsequent loading into the chip trap. We describe the details of the dual chamber vacuum system, the cooling lasers, the magnetic trap, the multicoil magnetic transport system, the atom chip, and two optical dipole traps. Due in part to the use of light-induced atom desorption, the laser cooling chamber features a sufficiently good vacuum to also support optical dipole trap-based experiments. The apparatus is well suited for studies of atom-surface forces, quantum pumping and transport experiments, atom interferometry, novel chip-based traps, and studies of one-dimensional many-body systems.

  16. Process for coal liquefaction by separation of entrained gases from slurry exiting staged dissolvers

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Ying, David H. S. (Macungie, PA)

    1983-01-01

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a solvent, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals are separated from the condensed dissolver effluent. In accordance with the improved process, fresh hydrogen is fed to each dissolver and the entrained gas from each dissolver is separated from the slurry phase and removed from the reactor system before the condensed phase is passed to the next dissolver in the series. In accordance with another process, the feeds to the dissolvers are such that the top of each downstream dissolver is used as a gas-liquid separator.

  17. Low-dimensional weakly interacting Bose gases: Nonuniversal equations of state

    SciTech Connect (OSTI)

    Astrakharchik, G. E.; Boronat, J.; Mazzanti, F.; Kurbakov, I. L.; Lozovik, Yu. E.

    2010-01-15

    The zero-temperature equation of state is analyzed in low-dimensional bosonic systems. We propose to use the concept of energy-dependent s-wave scattering length for obtaining estimations of nonuniversal terms in the energy expansion. We test this approach by making a comparison to exactly solvable one-dimensional problems and find that the generated terms have the correct structure. The applicability to two-dimensional systems is analyzed by comparing with results of Monte Carlo simulations. The prediction for the nonuniversal behavior is qualitatively correct and the densities, at which the deviations from the universal equation of state become visible, are estimated properly. Finally, the possibility of observing the nonuniversal terms in experiments with trapped gases is also discussed.

  18. Electrochemical separation and concentration of sulfur containing gases from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

    1981-01-01

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  19. Carbonaceous material for production of hydrogen from low heating value fuel gases

    DOE Patents [OSTI]

    Koutsoukos, Elias P. (Los Angeles, CA)

    1989-01-01

    A process for the catalytic production of hydrogen, from a wide variety of low heating value fuel gases containing carbon monoxide, comprises circulating a carbonaceous material between two reactors--a carbon deposition reactor and a steaming reactor. In the carbon deposition reactor, carbon monoxide is removed from a fuel gas and is deposited on the carbonaceous material as an active carbon. In the steaming reactor, the reactive carbon reacts with steam to give hydrogen and carbon dioxide. The carbonaceous material contains a metal component comprising from about 75% to about 95% cobalt, from about 5% to about 15% iron, and up to about 10% chromium, and is effective in suppressing the production of methane in the steaming reactor.

  20. Mass-transport models to predict toxicity of inhaled gases in the upper respiratory tract

    SciTech Connect (OSTI)

    Hubal, E.A.C.; Fedkiw, P.S.; Kimbell, J.S. [North Carolina State Univ., Raleigh, NC (United States)

    1996-04-01

    Mass-transport (the movement of a chemical species) plays an important role in determining toxic responses of the upper respiratory tract (URT) to inhaled chemicals. Mathematical dosimetry models incorporate physical characteristics of mass transport and are used to predict quantitative uptake (absorption rate) and distribution of inhaled gases and vapors in the respiratory tract. Because knowledge of dose is an essential component of quantitative risk assessment, dosimetry modeling plays an important role in extrapolation of animal study results to humans. A survey of existing mathematical dosimetry models for the URT is presented, limitations of current models are discussed, and adaptations of existing models to produce a generally applicable model are suggested. Reviewed URT dosimetry models are categorized as early, lumped-parameter, and distributed-parameter models. Specific examples of other relevant modeling work are also presented. 35 refs., 11 figs., 1 tab.

  1. Renormalization group theory of condensable gases: General remarks and a discussion of water

    SciTech Connect (OSTI)

    White, J.A.

    1993-04-01

    The preceding talks by Tewari and by Zhang illustrates aspects of a renormalization group theory of condensable gases that appears to be capable of describing reduced volumetric properties of several rather different types of fluids to a reasonable approximation near the critical point using as input only a knowledge of the critical compressibility ratio Z{sub c}, and in a rather large extended neighborhood of the critical point by introducing only a small number of additional parameters. When an attempt is made to apply the same approach to an extended neighborhood of the critical point of water, it is found that at least one additional parameter is required beyond the minimal argon, ethane, and helium-4 over comparably large regions of density, temperature, and pressure.

  2. Production of stable, non-thermal atmospheric pressure rf capacitive plasmas using gases other than helium or neon

    DOE Patents [OSTI]

    Park, Jaeyoung; Henins, Ivars

    2005-06-21

    The present invention enables the production of stable, steady state, non-thermal atmospheric pressure rf capacitive .alpha.-mode plasmas using gases other than helium and neon. In particular, the current invention generates and maintains stable, steady-state, non-thermal atmospheric pressure rf .alpha.-mode plasmas using pure argon or argon with reactive gas mixtures, pure oxygen or air. By replacing rare and expensive helium with more readily available gases, this invention makes it more economical to use atmospheric pressure rf .alpha.-mode plasmas for various materials processing applications.

  3. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

    SciTech Connect (OSTI)

    DeLuchi, M.A.

    1993-11-01

    This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

  4. Understanding the contribution of non-carbon dioxide gases in deep mitigation scenarios

    SciTech Connect (OSTI)

    Gernaat, David; Calvin, Katherine V.; Lucas, Paul; Luderer, Gunnar; Otto, Sander; Rao, Shilpa; Strefler, Jessica; Van Vuuren, Detlef

    2015-07-01

    The combined 2010 emissions of methane (CH4), nitrous oxide (N2O) and the fluorinated gasses (F-gas) account for about 20-30% of total emissions and about 30% of radiative forcing. At the moment, most studies looking at reaching ambitious climate targets project the emission of carbon dioxide (CO2) to be reduced to zero (or less) by the end of the century. As for non-CO2 gases, the mitigation potential seem to be more constrained, we find that by the end of the century in the current deep mitigation scenarios non-CO2 emissions could form the lion’s share of remaining greenhouse gas emissions. In order to support effective climate policy strategies, in this paper we provide a more in-depth look at the role of non-CO2¬ emission sources (CH4, N2O and F-gases) in achieving deep mitigation targets (radiative forcing target of 2.8 W/m2 in 2100). Specifically, we look at the sectorial mitigation potential and the remaining non-CO2 emissions. By including a set of different models, we provide some insights into the associated uncertainty. Most of the remaining methane emissions in 2100 in the climate mitigation scenario come from the livestock sector. Strong reductions are seen in the energy supply sector across all models. For N2O, less reduction potential is seen compared to methane and the sectoral differences are larger between the models. The paper shows that the assumptions on remaining non-CO2 emissions are critical for the feasibility of reaching ambitious climate targets and the associated costs.

  5. Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases Fiscal Year 2000 Annual Report

    SciTech Connect (OSTI)

    Cushman, R.M.

    2001-11-15

    The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global change data and information analysis center of the U.S. Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has, since its inception in 1982, enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including concentrations of carbon dioxide (CO{sub 2}) and other radiatively active gases in the atmosphere; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; emissions of CO{sub 2} and other trace gases to the atmosphere; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea levels.

  6. A New Technique for Studying the Fano Factor And the Mean Energy Per Ion Pair in Counting Gases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Panksky, A.; Breskin, A.; Chechik, R.

    1996-04-01

    A new method is presented for deriving the Fano factor and the mean energy per ion pair in the ultrasoft x-ray energy range. It is based on counting electrons deposited by a photon in a low-pressure gas, and is applicable for all counting gases. The energy dependence of these parameters for several hydrocarbons and gas mixtures is presented.

  7. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R. (Littleton, CO); Weimer, Carl S. (Littleton, CO); Nelson, Loren D. (Evergreen, CO); O'Brien, Martin J. (Pine, CO)

    2003-01-01

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  8. High- and low-temperature-stable thermite composition for producing high-pressure, high-velocity gases

    DOE Patents [OSTI]

    Halcomb, Danny L. (Camden, OH); Mohler, Jonathan H. (Spring Valley, OH)

    1990-10-16

    A high- and low-temperature-stable thermite composition for producing high-pressure and high-velocity gases comprises an oxidizable metal, an oxidizing reagent, and a high-temperature-stable gas-producing additive selected from the group consisting of metal carbides and metal nitrides.

  9. Carbon dioxide Information Analysis Center and World Data Center: A for Atmospheric trace gases. Annual progress report, FY 1994

    SciTech Connect (OSTI)

    Burtis, M.D.; Cushman, R.M.; Boden, T.A.; Jones, S.B.; Nelson, T.R.; Stoss, F.W.

    1995-03-01

    This report summarizes the activities and accomplishments made by the Carbon Dioxide Information Analysis Center and World Data Center-A for Atmospheric Trace Gases during the fiscal year 1994. Topics discussed in this report include; organization and staff, user services, systems, communications, Collaborative efforts with China, networking, ocean data and activities of the World Data Center-A.

  10. CO.sub.2 separation from low-temperature flue gases

    DOE Patents [OSTI]

    Dilmore, Robert; Allen, Douglas; Soong, Yee; Hedges, Sheila

    2010-11-30

    Two methods are provide for the separation of carbon dioxide from the flue gases. The first method utilizes a phase-separating moiety dissolved in an aqueous solution of a basic moiety to capture carbon dioxide. The second method utilizes a phase-separating moiety as a suspended solid in an aqueous solution of a basic moiety to capture carbon dioxide. The first method takes advantage of the surface-independent nature of the CO.sub.2 absorption reactions in a homogeneous aqueous system. The second method also provides permanent sequestration of the carbon dioxide. Both methods incorporate the kinetic rate enhancements of amine-based scrubbing while eliminating the need to heat the entire amine solution (80% water) in order to regenerate and release CO.sub.2. Both methods also take advantage of the low-regeneration temperatures of CO.sub.2-bearing mineral systems such as Na.sub.2CO.sub.3/NaHCO.sub.3 and K.sub.2CO.sub.3/KHCO.sub.3.

  11. Highly concentrated nebular noble gases in porous nanocarbon separates from the Saratov (L4) meteorite

    SciTech Connect (OSTI)

    Amari, Sachiko; Matsuda, Jun-ichi; Stroud, Rhonda M.; Chisholm, Matthew F.

    2013-11-20

    The majority of heavy noble gases (Ar, Kr, and Xe) in primitive meteorites are stored in a poorly understood phase called Q. Although Q is thought to be carbonaceous, the full identity of the phase has remained elusive for almost four decades. In order to better characterize phase Q and, in turn, the early solar nebula, we separated carbon-rich fractions from the Saratov (L4) meteorite. We chose this meteorite because Q is most resistant in thermal alteration among carbonaceous noble gas carriers in meteorites and we hoped that, in this highly metamorphosed meteorite, Q would be present but not diamond: these two phases are very difficult to separate from each other. One of the fractions, AJ, has the highest {sup 132}Xe concentration of 2.1 × 10{sup –6} cm{sup 3} STP g{sup –1}, exceeding any Q-rich fractions that have yet been analyzed. Transmission electron microscopy studies of the fraction AJ and a less Q-rich fraction AI indicate that they both are primarily porous carbon that consists of domains with short-range graphene orders, with variable packing in three dimensions, but no long-range graphitic order. The relative abundance of Xe and C atoms (6:10{sup 9}) in the separates indicates that individual noble gas atoms are associated with only a minor component of the porous carbon, possibly one or more specific arrangements of the nanoparticulate graphene.

  12. Auxiliary field formalism for dilute fermionic atom gases with tunable interactions

    SciTech Connect (OSTI)

    Mihaila, Bogdan; Chien, Chih-Chun; Timmermans, Eddy; Dawson, John F.; Cooper, Fred

    2011-05-15

    We develop the auxiliary field formalism corresponding to a dilute system of spin-1/2 fermions. This theory represents the Fermi counterpart of the Bose-Einstein condensation (BEC) theory developed recently by F. Cooper et al. [Phys. Rev. Lett. 105, 240402 (2010)] to describe a dilute gas of Bose particles. Assuming tunable interactions, this formalism is appropriate for the study of the crossover from the regime of Bardeen-Cooper-Schriffer (BCS) pairing to the regime of BEC in ultracold fermionic atom gases. We show that when applied to the Fermi case at zero temperature, the leading-order auxiliary field (LOAF) approximation gives the same equations as obtained in the standard BCS variational picture. At finite temperature, LOAF leads to the theory discussed by Sa de Melo, Randeria, and Engelbrecht [Phys. Rev. Lett. 71, 3202 (1993); Phys. Rev. B 55, 15153 (1997)]. As such, LOAF provides a unified framework to study the interacting Fermi gas. The mean-field results discussed here can be systematically improved on by calculating the one-particle irreducible action corrections, order by order.

  13. Greenhouse gases, Regulated Emissions, and Energy use in Transportation fuel-cyl

    Energy Science and Technology Software Center (OSTI)

    2000-06-20

    The GREET model estimates the full fuel-cycle energy use and emissions associated with various transportation fuels and advanced vehile technologies applied to motor vehicles. GREET 1.5 includes the following cycles: petroleum to conventional gasoline, reformulated gasoline, conventional diesel, reformulated diesel, liquefied petroleum gas, and electricity via residual oil; natural gas to compressed natural gas, liquefied natural gas, liquefied petroleum gas, methanol, Fischer-Tropsch diesel, dimethyl ether, hydrogen, and electricity; coal to electricity; corn, woody biomass, andmore » herbaceous biomass to ethanol; soybeans to biodiesel; flared gas to methanol, Fischer-Tropsch diesel, and dimethyl ether; and landfill gases to methanol. For a given fuel/transportation technology combination, GREET 1.5 calculates (1) the fuel-cycle consumption of total energy (all energy sources), fossil fuels (petroleum, natural gas, and coal), and petroleum; (2) the fuel-cycle emissions of GHGs -- primarily carbon dioxide (CO2), methane (CH4), and nitrous oxide (N20); and (3) the fuel-cycle emissions of five criteria pollutants: volatile organic compounds (VOCs), carbon monoxide (C0), nitrogen oxides (N0x), sulfur oxides (S0x), and particulate matter with a diameter measuring 10 micrometers or less (PM10). The model is designed to readily allow researchers to input their own assumptions and generate fuel-cycle energy and emission results for specified fuel/technology combinations.« less

  14. Weak interactions between water and clathrate-forming gases at low pressures

    SciTech Connect (OSTI)

    Thuermer, Konrad; Yuan, Chunqing; Kimmel, Greg A.; Kay, Bruce D.; Smith, R. Scott

    2015-07-17

    Using scanning probe microscopy and temperature programed desorption we examined the interaction between water and two common clathrate-forming gases, methane and isobutane, at low temperature and low pressure. Water co-deposited with up to 10–1 mbar methane or 10–5 mbar isobutane at 140 K onto a Pt(111) substrate yielded pure crystalline ice, i.e., the exposure to up to ~ 107 gas molecules for each deposited water molecule did not have any detectable effect on the growing films. Exposing metastable, less than 2 molecular layers thick, water films to 10–5 mbar methane does not alter their morphology, suggesting that the presence of the Pt(111) surface is not a strong driver for hydrate formation. This weak water–gas interaction at low pressures is supported by our thermal desorption measurements from amorphous solid water and crystalline ice where 1 ML of methane desorbs near ~ 43 K and isobutane desorbs near ~ 100 K. As a result, similar desorption temperatures were observed for desorption from amorphous solid water.

  15. Mobility of singly-charged lanthanide cations in rare gases: Theoretical assessment of the state specificity

    SciTech Connect (OSTI)

    Buchachenko, Alexei A.; Viehland, Larry A.

    2014-03-21

    High quality, ab initio calculations are reported for the potential energy curves governing the interactions of four singly-charged lanthanide ions (Yb{sup +}, Eu{sup +}, Lu{sup +}, and Gd{sup +}) with the rare gases (RG = He–Xe). Scalar-relativistic coupled cluster calculations are used for the first three S-state ions, but for Gd{sup +}({sup 10}D°) it is necessary to take the interaction anisotropy into account with the help of the multi-reference technique. The potential energy curves are used to determine the ion mobility and other transport properties describing the motion of the ions through the dilute RG, both as functions of the temperature, T, in the low-field limit, and at fixed T as functions of the ratio of the electrostatic field strength to the gas number density, E/N. The calculated mobilities are in good agreement with the very limited experimental data that have become available recently. The calculations show a pronounced dependence of the transport properties on the electronic configuration of the ion, as well as a significant effect of the spin-orbit coupling on the transport properties of the Gd{sup +} ion, and predict that state-specific mobilities could be detectable in Gd{sup +}–RG experiments.

  16. Are Greenhouse Gases Changing ENSO Precursors in the Western North Pacific?

    SciTech Connect (OSTI)

    Wang, S-Y; Heureux, Michelle L.; Yoon, Jin-Ho

    2013-09-01

    Using multiple observational and modeling datasets, we document a strengthening relationship between boreal winter sea surface temperature anomalies (SSTA) in the western North Pacific (WNP) and the development of the El Nino-Southern Oscillation (ENSO) one year later. The increased WNP-ENSO association emerged in the mid 20th century and has grown through the present, reaching correlation coefficients as high as ~0.70 in recent decades. Fully coupled climate experiments with the Community Earth System Model (CESM) replicate the WNP-ENSO association and indicate that greenhouse gases (GHG) are largely responsible for the observed increase. We speculate that shifts in the location and amplitudes of positive SST trends in the subtropical-tropical western Pacific impacts the low-level circulation so that WNP variability is increasingly influencing the development of ENSO one year later. A strengthened GHG-driven relationship between the WNP and ENSO provides an example of how anthropogenic climate change can potentially improve the skill of intraseasonal-to-interannual climate prediction.

  17. Spatial shaping for generating arbitrary optical dipole traps for ultracold degenerate gases

    SciTech Connect (OSTI)

    Lee, Jeffrey G.; Hill, W. T.

    2014-10-15

    We present two spatial-shaping approaches – phase and amplitude – for creating two-dimensional optical dipole potentials for ultracold neutral atoms. When combined with an attractive or repulsive Gaussian sheet formed by an astigmatically focused beam, atoms are trapped in three dimensions resulting in planar confinement with an arbitrary network of potentials – a free-space atom chip. The first approach utilizes an adaptation of the generalized phase-contrast technique to convert a phase structure embedded in a beam after traversing a phase mask, to an identical intensity profile in the image plane. Phase masks, and a requisite phase-contrast filter, can be chemically etched into optical material (e.g., fused silica) or implemented with spatial light modulators; etching provides the highest quality while spatial light modulators enable prototyping and realtime structure modification. This approach was demonstrated on an ensemble of thermal atoms. Amplitude shaping is possible when the potential structure is made as an opaque mask in the path of a dipole trap beam, followed by imaging the shadow onto the plane of the atoms. While much more lossy, this very simple and inexpensive approach can produce dipole potentials suitable for containing degenerate gases. High-quality amplitude masks can be produced with standard photolithography techniques. Amplitude shaping was demonstrated on a Bose-Einstein condensate.

  18. Weak interactions between water and clathrate-forming gases at low pressures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thuermer, Konrad; Yuan, Chunqing; Kimmel, Greg A.; Kay, Bruce D.; Smith, R. Scott

    2015-07-17

    Using scanning probe microscopy and temperature programed desorption we examined the interaction between water and two common clathrate-forming gases, methane and isobutane, at low temperature and low pressure. Water co-deposited with up to 10–1 mbar methane or 10–5 mbar isobutane at 140 K onto a Pt(111) substrate yielded pure crystalline ice, i.e., the exposure to up to ~ 107 gas molecules for each deposited water molecule did not have any detectable effect on the growing films. Exposing metastable, less than 2 molecular layers thick, water films to 10–5 mbar methane does not alter their morphology, suggesting that the presence ofmore » the Pt(111) surface is not a strong driver for hydrate formation. This weak water–gas interaction at low pressures is supported by our thermal desorption measurements from amorphous solid water and crystalline ice where 1 ML of methane desorbs near ~ 43 K and isobutane desorbs near ~ 100 K. As a result, similar desorption temperatures were observed for desorption from amorphous solid water.« less

  19. Microscopic description of anisotropic low-density dipolar Bose gases in two dimensions

    SciTech Connect (OSTI)

    Macia, A.; Mazzanti, F.; Boronat, J.; Zillich, R. E.

    2011-09-15

    A microscopic description of the zero-energy two-body ground state and many-body static properties of anisotropic homogeneous gases of bosonic dipoles in two dimensions at low densities is presented and discussed. By changing the polarization angle with respect to the plane, we study the impact of the anisotropy, present in the dipole-dipole interaction, on the energy per particle, comparing the results with mean-field predictions. We restrict the analysis to the regime where the interaction is always repulsive, although the strength of the repulsion depends on the orientation with respect to the polarization field. We present a series expansion of the solution of the zero-energy two-body problem, which allows us to find the scattering length of the interaction and to build a suitable Jastrow factor that we use as a trial wave function for both a variational and diffusion Monte Carlo simulation of the infinite system. We find that the anisotropy has an almost negligible impact on the ground-state properties of the many-body system in the universal regime where the scattering length governs the physics of the system. We also show that scaling in the gas parameter persists in the dipolar case up to values where other isotropic interactions with the same scattering length yield different predictions.

  20. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2002-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condensing one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is hot liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  1. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2000-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condense one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is not liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  2. Federal Offshore--Gulf of Mexico Nonhydrocarbon Gases Removed from Natural

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas (Million Cubic Feet) Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0

  3. Van der Waals epitaxial growth of two-dimensional single-crystalline GaSe domains on graphene

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xufan; Basile, Leonardo; Huang, Bing; Ma, Cheng; Lee, Jaekwang; Vlassiouk, Ivan V.; Puretzky, Alexander A.; Lin, Ming -Wei; Chi, Miaofang; Idrobo Tapia, Juan Carlos; et al

    2015-07-22

    Two-dimensional (2D) van der Waals (vdW) heterostructures are a family of artificially-structured materials that promise tunable optoelectronic properties for devices with enhanced functionalities. Compared to stamping, direct epitaxy of vdW heterostructures is ideal for clean interlayer interfaces and scalable device fabrication. Here, we explore the synthesis and preferred orientations of 2D GaSe atomic layers on graphene (Gr) by vdW epitaxy. Guided by the wrinkles on graphene, GaSe nuclei form that share a predominant lattice orientation. Due to vdW epitaxial growth many nuclei grow as perfectly aligned crystals and coalesce to form large (tens of microns), single-crystal flakes. Through theoretical investigationsmore » of interlayer energetics, and measurements of preferred orientations by atomic-resolution STEM and electron diffraction, a 10.9 interlayer rotation of the GaSe lattice with respect to the underlying graphene is found to be the most energetically preferred vdW heterostructure with the largest binding energy and the longest-range ordering. These GaSe/Gr vdW heterostructures exhibit an enhanced Raman E21g band of monolayer GaSe along with highly-quenched photoluminescence due to strong charge transfer. Despite the very large lattice mismatch of GaSe/Gr through vdW epitaxy, the predominant orientation control and convergent formation of large single-crystal flakes demonstrated here is promising for the scalable synthesis of large-area vdW heterostructures for the development of new optical and optoelectronic devices.« less

  4. TEST PROCEDURE VALIDATION TEST OF A DISCRIMINATING TRITIUM MONITOR FOR MEASURING TRITIUM OXIDE IN THE PRESENCE OF NOBLE GASES

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Robert Goldstein, Ivan Mitev, Dell Williamson WE FACE A CHALLENGE At many nuclear facilities, Air and Stack monitors are required to measure: Multiple radio-active materials Separately and simultaneously With great accuracy and high sensitivity EVEN WHEN High concentrations of one material are likely to mask the signals from the low concentration of

  5. Van der Waals Epitaxial Growth of Single-Crystal Two-Dimensional GaSe on Graphene

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xufan; Basile, Leonardo; Huang, Bing; Ma, Cheng; Lee, Jaekwang; Vlassiouk, Ivan V.; Puretzky, Alexander A.; Lin, Ming-Wei; Chi, Miaofang; Idrobo Tapia, Juan Carlos; et al

    2015-07-22

    Two-dimensional (2D) van der Waals (vdW) heterostructures are a family of artificially-structured materials that promise tunable optoelectronic properties for devices with enhanced functionalities. Compared to stamping, direct epitaxy of vdW heterostructures is ideal for clean interlayer interfaces and scalable device fabrication. Here, we explore the synthesis and preferred orientations of 2D GaSe atomic layers on graphene (Gr) by vdW epitaxy. Guided by the wrinkles on graphene, GaSe nuclei form that share a predominant lattice orientation. Due to vdW epitaxial growth many nuclei grow as perfectly aligned crystals and coalesce to form large (tens of microns), single-crystal flakes. Through theoretical investigationsmore »of interlayer energetics, and measurements of preferred orientations by atomic-resolution STEM and electron diffraction, a 10.9 interlayer rotation of the GaSe lattice with respect to the underlying graphene is found to be the most energetically preferred vdW heterostructure with the largest binding energy and the longest-range ordering. These GaSe/Gr vdW heterostructures exhibit an enhanced Raman E21g band of monolayer GaSe along with highly-quenched photoluminescence due to strong charge transfer. Despite the very large lattice mismatch of GaSe/Gr through vdW epitaxy, the predominant orientation control and convergent formation of large single-crystal flakes demonstrated here is promising for the scalable synthesis of large-area vdW heterostructures for the development of new optical and optoelectronic devices.« less

  6. Van der Waals epitaxial growth of two-dimensional single-crystalline GaSe domains on graphene

    SciTech Connect (OSTI)

    Li, Xufan; Basile, Leonardo; Huang, Bing; Ma, Cheng; Lee, Jaekwang; Vlassiouk, Ivan V.; Puretzky, Alexander A.; Lin, Ming -Wei; Chi, Miaofang; Idrobo Tapia, Juan Carlos; Rouleau, Christopher M.; Sumpter, Bobby G.; Yoon, Mina; Geohegan, David B.; Xiao, Kai

    2015-07-22

    Two-dimensional (2D) van der Waals (vdW) heterostructures are a family of artificially-structured materials that promise tunable optoelectronic properties for devices with enhanced functionalities. Compared to stamping, direct epitaxy of vdW heterostructures is ideal for clean interlayer interfaces and scalable device fabrication. Here, we explore the synthesis and preferred orientations of 2D GaSe atomic layers on graphene (Gr) by vdW epitaxy. Guided by the wrinkles on graphene, GaSe nuclei form that share a predominant lattice orientation. Due to vdW epitaxial growth many nuclei grow as perfectly aligned crystals and coalesce to form large (tens of microns), single-crystal flakes. Through theoretical investigations of interlayer energetics, and measurements of preferred orientations by atomic-resolution STEM and electron diffraction, a 10.9 interlayer rotation of the GaSe lattice with respect to the underlying graphene is found to be the most energetically preferred vdW heterostructure with the largest binding energy and the longest-range ordering. These GaSe/Gr vdW heterostructures exhibit an enhanced Raman E21g band of monolayer GaSe along with highly-quenched photoluminescence due to strong charge transfer. Despite the very large lattice mismatch of GaSe/Gr through vdW epitaxy, the predominant orientation control and convergent formation of large single-crystal flakes demonstrated here is promising for the scalable synthesis of large-area vdW heterostructures for the development of new optical and optoelectronic devices.

  7. GASFLOW: A Computational Fluid Dynamics Code for Gases, Aerosols, and Combustion, Volume 2: User's Manual

    SciTech Connect (OSTI)

    B. D. Nichols; C. Müller; G. A. Necker; J. R. Travis; J. W. Spore; K. L. Lam; P. Royl; T. L. Wilson

    1998-10-01

    Los Alamos National Laboratory (LANL) and Forschungszentrum Karlsruhe (FzK) are developing GASFLOW, a three-dimensional (3D) fluid dynamics field code as a best-estimate tool to characterize local phenomena within a flow field. Examples of 3D phenomena include circulation patterns; flow stratification; hydrogen distribution mixing and stratification; combustion and flame propagation; effects of noncondensable gas distribution on local condensation and evaporation; and aerosol entrainment, transport, and deposition. An analysis with GASFLOW will result in a prediction of the gas composition and discrete particle distribution in space and time throughout the facility and the resulting pressure and temperature loadings on the walls and internal structures with or without combustion. A major application of GASFLOW is for predicting the transport, mixing, and combustion of hydrogen and other gases in nuclear reactor containment and other facilities. It has been applied to situations involving transporting and distributing combustible gas mixtures. It has been used to study gas dynamic behavior in low-speed, buoyancy-driven flows, as well as sonic flows or diffusion dominated flows; and during chemically reacting flows, including deflagrations. The effects of controlling such mixtures by safety systems can be analyzed. The code version described in this manual is designated GASFLOW 2.1, which combines previous versions of the United States Nuclear Regulatory Commission code HMS (for Hydrogen Mixing Studies) and the Department of Energy and FzK versions of GASFLOW. The code was written in standard Fortran 90. This manual comprises three volumes. Volume I describes the governing physical equations and computational model. Volume II describes how to use the code to set up a model geometry, specify gas species and material properties, define initial and boundary conditions, and specify different outputs, especially graphical displays. Sample problems are included. Volume III contains some of the assessments performed by LANL and FzK.

  8. Investigation of Tunable Diode Spectroscopy for Monitoring Gases in Geothermal Plants

    SciTech Connect (OSTI)

    J. K. Partin

    2006-08-01

    The results of an investigation directed at the development of instrument-tation for the real-time monitoring of gases, such as hydrogen sulfide (H2S) and chloride (HCl), in geothermal process streams is described. The geothermal power industry has an interest in the development of new low maintenance techniques since improved capabilities could lead to considerable cost savings through the optimization of various gas abatement processes. Tunable diode laser spectroscopy was identified as a candidate tech-nology for this application and a commercial instrument was specified and procured for testing. The measurement principle involved the use of solid state diode lasers and frequency modulation techniques. The gallium arsenide diode lasers employed emit light in the 0.7 to 2.0 micron region of the electromagnetic spectrum. This region contains the overtone and combination absorption bands of a number of species of industrial interest, including H2S and HCl. A particular device can be tuned over a small range to match the absorption line by changing its applied temperature and current. The diode current can also be sinusoidally modulated in frequency as it is tuned across the line. This modulation allows measurements to be conducted at frequencies where the laser intensity noise is minimal; and therefore, very high signal-to-noise measurements are possible. The feasibility of using this technology in various types of geothermal process streams has been explored. The results of laboratory and field studies are presented along with new advances in laser technology that could allow more sensitive and selective measurements to be performed.

  9. Theoretical investigation of the impact of grain boundaries and fission gases on UO2 thermal conductivity

    SciTech Connect (OSTI)

    Du, Shiyu; Andersson, Anders D.; Germann, Timothy C.; Stanek, Christopher R.

    2012-05-02

    Thermal conductivity is one of the most important metrics of nuclear fuel performance. Therefore, it is crucial to understand the impact of microstructure features on thermal conductivity, especially since the microstructure evolves with burn-up or time in the reactor. For example, UO{sub 2} fuels are polycrystalline and for high-burnup fuels the outer parts of the pellet experience grain sub-division leading to a very fine grain structure. This is known to impact important physical properties such as thermal conductivity as fission gas release. In a previous study, we calculated the effect of different types of {Sigma}5 grain boundaries on UO{sub 2} thermal conductivity and predicted the corresponding Kapitza resistances, i.e. the resistance of the grain boundary in relation to the bulk thermal resistance. There have been reports of pseudoanisotropic effects for the thermal conductivity in cubic polycrystalline materials, as obtained from molecular dynamics simulations, which means that the conductivity appears to be a function of the crystallographic direction of the temperature gradient. However, materials with cubic symmetry should have isotropic thermal conductivity. For this reason it is necessary to determine the cause of this apparent anisotropy and in this report we investigate this effect in context of our earlier simulations of UO{sub 2} Kapitza resistances. Another source of thermal resistance comes from fission products and fission gases. Xe is the main fission gas and when generated in sufficient quantity it dissolves from the lattice and forms gas bubbles inside the crystalline structure. We have performed studies of how Xe atoms dissolved in the UO{sub 2} matrix or precipitated as bubbles impact thermal conductivity, both in bulk UO{sub 2} and in the presence of grain boundaries.

  10. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  11. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  12. From SO{sub 2} to greenhouse gases: trends and events shaping future emissions trading programs in the United States

    SciTech Connect (OSTI)

    Joseph Kruger

    2005-06-15

    Cap-and-trade programs have become widely accepted for the control of conventional air pollution in the United States. However, there is still no political consensus to use these programs to address greenhouse gases. Meanwhile, in the wake of the success of the US SO{sub 2} and NOx trading programs, private companies, state governments, and the European Union are developing new trading programs or other initiatives that may set precedents for a future national US greenhouse gas trading scheme. This paper summarizes the literature on the 'lessons learned' from the SO{sub 2} trading program for greenhouse gas trading, including lessons about the potential differences in design that may be necessary because of the different sources, science, mitigation options, and economics inherent in greenhouse gases. The paper discusses how the programs and initiatives mentioned above have been shaped by lessons from past trading programs and whether they are making changes to the SO{sub 2} model to address greenhouse gases. It concludes with an assessment of the implications of these initiatives for a future US national greenhouse gas trading program. 91 refs., 2 tabs.

  13. Proceedings of the International Workshop on Sustainable ForestManagement: Monitoring and Verification of Greenhouse Gases

    SciTech Connect (OSTI)

    Sathaye , Jayant; Makundi , Willy; Goldberg ,Beth; Andrasko , Ken; Sanchez , Arturo

    1997-07-01

    The International Workshop on Sustainable Forest Management: Monitoring and Verification of Greenhouse Gases was held in San Jose, Costa Rica, July 29-31, 1996. The main objectives of the workshop were to: (1) assemble key practitioners of forestry greenhouse gas (GHG) or carbon offset projects, remote sensing of land cover change, guidelines development, and the forest products certification movement, to offer presentations and small group discussions on findings relevant to the crucial need for the development of guidelines for monitoring and verifying offset projects, and (2) disseminate the findings to interested carbon offset project developers and forestry and climate change policy makers, who need guidance and consistency of methods to reduce project transaction costs and increase probable reliability of carbon benefits, at appropriate venues. The workshop brought together about 45 participants from developed, developing, and transition countries. The participants included researchers, government officials, project developers, and staff from regional and international agencies. Each shared his or her perspectives based on experience in the development and use of methods for monitoring and verifying carbon flows from forest areas and projects. A shared sense among the participants was that methods for monitoring forestry projects are well established, and the techniques are known and used extensively, particularly in production forestry. Introducing climate change with its long-term perspective is often in conflict with the shorter-term perspective of most forestry projects and standard accounting principles. The resolution of these conflicts may require national and international agreements among the affected parties. The establishment of guidelines and protocols for better methods that are sensitive to regional issues will be an important first step to increase the credibility of forestry projects as viable mitigation options. The workshop deliberations led to three primary outputs: (1) a Workshop Statement in the JI Quarterly, September, 1996; (2) the publication of a series of selected peer-reviewed technical papers from the workshop in a report of the Lawrence Berkeley National Laboratory (LBNL. 40501); and (3) a special issue of the journal ''Mitigation and Adaptation Strategies for Global Change'', Kluwer Academic Publishers. The outputs will be distributed to practitioners in this field and to negotiators attending the Framework Convention on Climate Change (FCCC) deliberations leading up to the Third conference of Parties in Kyoto, in December 1997.

  14. Refinery Net Input of Renewable Diesel Fuel

    Gasoline and Diesel Fuel Update (EIA)

    662 633 670 564 582 488 2009-2015 PADD 1 23 20 23 15 89 9 2010-2015 East Coast 80 2014-2015 Appalachian No. 1 23 20 23 15 9 9 2010-2015 PADD 2 143 139 139 114 94 109 2009-2015 Ind., Ill. and Ky. 87 86 92 75 72 88 2011-2015 Minn., Wis., N. Dak., S. Dak. 40 41 35 24 17 13 2009-2015 Okla., Kans., Mo. 16 12 12 15 5 8 2011-2015 PADD 3 297 256 290 253 224 170 2011-2015 Texas Inland 68 67 68 61 57 28 2011-2015 Texas Gulf Coast 9 13 11 14 12 12 2012-2015 La. Gulf Coast 182 140 151 134 121 111 2012-2015

  15. Indiana, Illinois and Kentucky Refinery Yield

    Gasoline and Diesel Fuel Update (EIA)

    Miscellaneous Products 0.4 0.4 0.4 0.4 0.4 0.4 1993-2015 Processing Gain(-) or Loss(+) -6.0 -6.0 -5.5 -5.9 -5.8 -5.6 1993-2015 - No Data Reported; -- Not Applicable;...

  16. U.S. Refinery Utilization and Capacity

    Gasoline and Diesel Fuel Update (EIA)

    Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History Gross Input to Atmospheric Crude Oil Distillation Units 17,178 16,963 16,394 15,690 16,673 16,848 1985-2015 Operable Capacity (Calendar Day) 18,058 18,059 18,125 18,125 18,172 18,186 1985-2015 Operating 17,923 17,939 18,015 17,932 17,846 18,044 1985-2015 Idle 135 121 110 194 326 142 1985-2015 Operable Utilization Rate (%) 95.1 93.9 90.5 86.6 91.8 92.6 1985-2015 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  17. U.S. Refinery Utilization and Capacity

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Gross Input to Atmospheric Crude Oil Distillation Units 15,177 15,289 15,373 15,724 16,156 16,433 1985-2015 Operable Capacity (Calendar Day) 17,575 17,736 17,328 17,818 17,873 18,026 1985-2015 Operating 16,911 16,991 16,656 17,282 17,626 17,792 1985-2015 Idle 663 745 672 536 247 234 1985-2015 Operable Utilization Rate (%) 86.4 86.2 88.7 88.3 90.4 91.2 1985-2015 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  18. U.S. Refinery & Blender Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 6,345,372 6,422,710 6,406,693 6,577,077 6,779,342 6,882,105 1981-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 ...

  19. U.S. Refinery & Blender Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History Total 609,275 602,963 570,498 577,057 563,621 580,680 1981-2015 Crude Oil 523,409 516,507 485,221 479,416 494,682 519,726 ...

  20. Motiva Enterprises Refinery Expansion Groundbreaking | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In 1901 Texas wildcatters struck oil near here at a place called Spindletop, setting off the Texas Oil Boom. Like the California Gold Rush some 50 years before, the Texas Oil Boom ...