National Library of Energy BETA

Sample records for refinery gas streams

  1. Inorganic Membranes for Refinery Gas Separations

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to push the performance limits of inorganic membranes for large-scale gas separations in refinery applications.

  2. Assuring Mechanical Integrity of Refinery Equipment Through Global ON-Stream Inspection

    SciTech Connect (OSTI)

    John W. Berthold

    2006-02-22

    The development of global on-stream inspection technology will have a dramatic effect on how refinery operations are managed in the U.S. in the future. Global on-stream inspection will provide assurance of the mechanical integrity of critical plant equipment and will allow refineries to operate more efficiently with less impact on our environment and with an increased margin of safety.

  3. ,"U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Refinery, Bulk Terminal, and Natural Gas ... 10:27:55 PM" "Back to Contents","Data 1: U.S. Refinery, Bulk Terminal, and Natural Gas ...

  4. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  5. U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Refinery Gas (Million Cubic Feet) U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10,243 11,231 12,001 12,021 8,782 13,405 12,734 14,373 14,999 14,661 1990's 14,973 18,055 16,732 16,724 8,935 7,568 9,354 9,746 10,900 6,781 2000's 8,684 13,085 3,817 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  6. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect (OSTI)

    2009-12-01

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  7. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Vacuum State/Refiner/Location Barrels per Atmospheric Crude Oil Distillation Capacity Barrels per Operating Idle Operating Idle Downstream Charge Capacity Thermal Cracking Delayed Fluid Coking Visbreaking Other/Gas Calendar Day Stream Day Distillation Coking Oil Table 3. Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) ......................................................... Alabama 131,675 0 140,500 0 47,000 32,000 0 0 0

  8. Apparatus for focusing flowing gas streams

    DOE Patents [OSTI]

    Nogar, N.S.; Keller, R.A.

    1985-05-20

    Apparatus for focusing gas streams. The principle of hydrodynamic focusing is applied to flowing gas streams in order to provide sample concentration for improved photon and sample utilization in resonance ionization mass spectrometric analysis. In a concentric nozzle system, gas samples introduced from the inner nozzle into the converging section of the outer nozzle are focused to streams 50-250-..mu..m in diameter. In some cases diameters of approximately 100-..mu..m are maintained over distances of several centimeters downstream from the exit orifice of the outer nozzle. The sheath gas employed has been observed to further provide a protective covering around the flowing gas sample, thereby isolating the flowing gas sample from possible unwanted reactions with nearby surfaces. A single nozzle variation of the apparatus for achieving hydrodynamic focusing of gas samples is also described.

  9. Mining machinery/equipment/parts/services. Oil and gas field equipment/machinery/parts/supplies (Ecuador). Refinery equipment, parts, and accessories, March 1991. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1991-03-01

    The petroleum sector in Ecuador brings in about 65 percent of the country's revenue. Three of the refineries are located in the coastal region. The other two, plus the Liquified Petroleum Gas Plant (LPG), are located in the Oriente region (Amazon jungle). The refineries operate at about 85% of their installation capacity. The Petroindustrial and Petropeninsula investment plan for 1991 comtemplates the expansion of the Esmeraldas refinery to 110,000 barrels a day, and the up-grading of the Shushufindi and Libertad refineries located near the city of Guayaquil. The United States is by far the largest supplier of refinery equipment, parts and accessories, controlling about 90% of the total market.

  10. Gas stream cleaning system and method

    DOE Patents [OSTI]

    Kunchal, S. Kumar; Erck, Louis J.; Harris, Harry A.

    1979-04-13

    An oil mist and solid particle laden gas from an oil shale retorting operation is initially treated with a temperature controlled oil spray and then by a coalescer to reduce the quantity of oil mist and remove most of the solid particle content of the gas stream and then finally treated by an electrostatic precipitator to essentially remove the oil mist remaining in the gas.

  11. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    DOE Patents [OSTI]

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  12. Conversion method for gas streams containing hydrocarbons

    DOE Patents [OSTI]

    Mallinson, Richard G.; Lobban, Lance; Liu, Chang-jun

    2000-01-01

    An apparatus and a method of using the apparatus are provided for converting a gas stream containing hydrocarbons to a reaction product containing effluent molecules having at least one carbon atom, having at least one interior surface and at least one exterior surface, a first electrode and a second electrode with the first and second electrodes being selectively movable in relation to each other and positioned within the housing so as to be spatially disposed a predetermined distance from each other, a plasma discharge generator between the first and second electrodes, gas stream introducer and a collector for collecting the reaction product effluent produced by the reaction of the gas stream containing hydrocarbons with the plasma discharge between the first and second electrodes.

  13. Refinery Capacity Report - Explanatory Notes

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration/Refinery Capacity Report 1 Explanatory Notes Survey Methodology Description of Survey Form The Form EIA-820, "Annual Refinery Report," is the primary source of data in the "Refinery Capacity Report" tables. The form collects data on the consumption of purchased steam, electricity, coal, and natural gas; refinery receipts of crude oil by method of transportation; operable capacity for atmospheric crude oil distillation units and downstream

  14. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Hyatt, David E.; Bustard, Cynthia Jean; Sjostrom, Sharon

    1998-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  15. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  16. ,"U.S. Downstream Charge Capacity of Operable Petroleum Refineries...

    U.S. Energy Information Administration (EIA) Indexed Site

    as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal Cracking Downstream Charge Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal ...

  17. ,"U.S. Production Capacity of Operable Petroleum Refineries"

    U.S. Energy Information Administration (EIA) Indexed Site

    Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Aromatics Production Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Asphalt and Road Oil ...

  18. Particulate hot gas stream cleanup technical issues

    SciTech Connect (OSTI)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  19. Method for removing particulate matter from a gas stream

    DOE Patents [OSTI]

    Postma, Arlin K.

    1984-01-01

    Particulate matter is removed from a stream of pressurized gas by directing the stream of gas upwardly through a bed of porous material, the porous bed being held in an open ended container and at least partially submerged in liquid. The passage of the gas through the porous bed sets up a circulation in the liquid which cleans the particulate matter from the bed.

  20. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1998-11-10

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  1. Methanation of gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C.

    1983-01-01

    Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

  2. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, Evan J.; Pennline, Henry W.

    2006-04-25

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  3. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels per Atmospheric Crude Oil Distillation Capacity Idle Operating Total Operable Refineries Number of State and PAD District a b b 9 9 0 1,277,500 1,245,500 32,000 1,353,000 1,318,000 35,000 ............................................................................................................................................... PAD District I 1 1 0 182,200 182,200 0 190,200 190,200 0

  4. Refinery Yield of Liquefied Refinery Gases

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Liquefied Refinery Gases Finished Motor Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Residual Fuel Oil Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Still Gas Miscellaneous Products Processing Gain(-) or Loss(+) Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources

  5. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect (OSTI)

    Holmgren, Jennifer; Arena, Blaise; Marinangelli, Richard; McCall, Michael; Marker, Terry; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2006-10-11

    a summary of our collaborative 2005 project Opportunities for Biorenewables in Petroleum Refineries at the Rio Oil and Gas Conference this September.

  6. Method for treating a nuclear process off-gas stream

    DOE Patents [OSTI]

    Pence, Dallas T.; Chou, Chun-Chao

    1984-01-01

    Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

  7. Reclamation of potable water from mixed gas streams

    DOE Patents [OSTI]

    Judkins, Roddie R; Bischoff, Brian L; Debusk, Melanie Moses; Narula, Chaitanya

    2013-08-20

    An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

  8. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. PDF icon Displacing Natural Gas Consumption and...

  9. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mary Biddy Sue Jones NREL PNNL This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Refinery Integration 4.1.1.31 NREL 4.1.1.51 PNNL Goal Statement GOALS: Model bio-intermediates insertion points to better define costs & ID opportunities, technical risks, information gaps, research needs Publish results Review with stakeholders 2 Leveraging existing refining infrastructure

  10. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Operable Date of Last Operation Date Shutdown Table 11. New, Shutdown and Reactivated Refineries During 2015 a b NEW PAD District III 71,250 Buckeye Texas Processing LLC Corpus Christi, TX 46,250 11/15 Petromax Refining Co LLC Houston, TX 25,000 07/15 SHUTDOWN PAD District III 0 12,000 Pelican Refining Company LLC Lake Charles, LA 0 12,000 12/14 01/15 a b bbl/cd=Barrels per calendar day. bbl/sd=Barrels per stream day. Sources: Energy Information Administration (EIA) Form EIA-810, "Monthly

  11. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    District and State Production Capacity Alkylates Aromatics Asphalt and Road Oil Isomers Lubricants Marketable Petroleum Coke Sulfur (short tons/day) Hydrogen (MMcfd) Table 2. Production Capacity of Operable Petroleum Refineries by PAD District and State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) a 83,429 10,111 26,500 92,765 21,045 21,120 69 1,159 PAD District I Delaware 11,729 5,191 0 6,000 0 13,620 40 596 New Jersey 29,200 0 70,000 4,000 12,000 7,500 26 280 Pennsylvania

  12. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    State/Refiner/Location Alkylates Aromatics Isobutane Lubricants Isomers Isopentane and Isohexane Asphalt and Road Oil Marketable Petroleum Coke Hydrogen (MMcfd) Sulfur (short tons per day) Table 4. Production Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) Isooctane a ..................................................................... Alabama 0 0 15,000 1,150 4,200 0 7,120 40 228 0 Hunt Refining Co 0 0 15,000 0 4,200 0 7,120

  13. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillation Crude Oil Atmospheric Distillation Vacuum Cracking Thermal Catalytic Cracking Fresh Recycled Catalytic Hydro- Cracking Catalytic Reforming Desulfurization Hydrotreating/ Fuels Solvent Deasphalting Downstream Charge Capacity Table 6. Operable Crude Oil and Downstream Charge Capacity of Petroleum Refineries, January 1, 1987 to (Thousand Barrels per Stream Day, Except Where Noted) January 1, 2016 JAN 1, 1987 16,460 6,935 1,928 5,251 466 1,189 3,805 9,083 230 JAN 1, 1988 16,825 7,198

  14. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1987 to January 1, 2016 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN 1, 1990 1,030 290 844 456 232 341 2,607 24,202

  15. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    capable of automatic, safe, reliable, efficient, and low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. ...

  16. ,"Finished Motor Gasoline Refinery, Bulk Terminal, and Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    and Natural Gas Plants (Thousand Barrels)","East Coast (PADD 1) Finished Motor Gasoline Stocks at Refineries, Bulk Terminals, and Natural Gas Plants (Thousand ...

  17. Removal of hydrogen sulfide and carbonyl sulfide from gas-streams

    SciTech Connect (OSTI)

    Deal, C.H.; Lieder, C.A.

    1982-06-01

    Hydrogen sulfide and carbonyl sulfide are removed from a gas stream in a staged procedure characterized by conversion of the hydrogen sulfide to produce sulfur in aqueous solution, hydrolysis of the carbonyl sulfide remaining in the gas stream to produce hydrogen sulfide and carbon dioxide, and removal of the hydrogen sulfide from the gas stream.

  18. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Huang, H.S.

    1999-05-04

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

  19. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, Marshall H.; Huang, Hann-Sheng

    1999-01-01

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

  20. Method of immobilizing carbon dioxide from gas streams

    DOE Patents [OSTI]

    Holladay, David W.; Haag, Gary L.

    1979-01-01

    This invention is a method for rapidly and continuously immobilizing carbon dioxide contained in various industrial off-gas streams, the carbon dioxide being immobilized as dry, stable, and substantially water-insoluble particulates. Briefly, the method comprises passing the gas stream through a fixed or fluidized bed of hydrated barium hydroxide to remove and immobilize the carbon dioxide by converting the bed to barium carbonate. The method has several important advantages: it can be conducted effectively at ambient temperature; it provides a very rapid reaction rate over a wide range of carbon dioxide concentrations; it provides high decontamination factors; and it has a high capacity for carbon dioxide. The invention is especially well suited for the removal of radioactive carbon dioxide from off-gases generated by nuclear-fuel reprocessing facilities and nuclear power plants.

  1. Control of gas contaminants in air streams through biofiltration

    SciTech Connect (OSTI)

    Holt, T.; Lackey, L.

    1996-11-01

    According to the National Institute for Occupational Safety and Health (NIOSH), the maximum styrene concentration allowed in the work place is 50 ppm for up to a 10-hour work day during a 40-hour work week. The US EPA has classified styrene as one of the 189 hazardous air pollutants listed under Title 3 of the Clean Air Act Amendments to be reduced by a factor of 90% by the year 2000. Significant quantities of styrene are emitted to the atmosphere each year by boat manufacturers. A typical fiberglass boat manufacturing facility can emit over 273 metric tons/year of styrene. The concentration of styrene in the industrial exhaust gas ranges from 20 to 100 ppmv. Such dilute, high volume organically tainted air streams can make conventional abatement technologies such as thermal incineration, adsorption, or absorption technically incompetent or prohibitively expensive. An efficient, innovative, and economical means of remediating styrene vapors would be of value to industries and to the environment. Biofilter technology depends on microorganisms that are immobilized on the packing material in a solid phase reactor to remove or degrade environmentally undesirable compounds contaminating gas streams. The technology is especially successful for treating large volumes of air containing low concentrations of contaminants. The objective of this study was to investigate the feasibility of using biofiltration to treat waste gas streams containing styrene and to determine the critical design and operating parameters for such a system.

  2. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Bustard, Cynthia Jean

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  3. Efficient gas-separation process to upgrade dilute methane stream for use as fuel

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Merkel, Timothy C.; Lin, Haiqing; Thompson, Scott; Daniels, Ramin

    2012-03-06

    A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

  4. Method For Enhanced Gas Monitoring In High Density Flow Streams

    DOE Patents [OSTI]

    Von Drasek, William A.; Mulderink, Kenneth A.; Marin, Ovidiu

    2005-09-13

    A method for conducting laser absorption measurements in high temperature process streams having high levels of particulate matter is disclosed. An impinger is positioned substantially parallel to a laser beam propagation path and at upstream position relative to the laser beam. Beam shielding pipes shield the beam from the surrounding environment. Measurement is conducted only in the gap between the two shielding pipes where the beam propagates through the process gas. The impinger facilitates reduced particle presence in the measurement beam, resulting in improved SNR (signal-to-noise) and improved sensitivity and dynamic range of the measurement.

  5. STREAM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    STREAM STREAM Description STREAM is a simple, synthetic benchmark designed to measure sustainable memory bandwidth (in MB/s) and a corresponding computation rate for four simple vector kernels. Download NERSC8-Stream tar file How to Build the Code The version of STREAM provided here is the latest STREAM OpenMP enabled benchmark. (see http://www.cs.virginia.edu/stream/ref.html) Optionally, for GPU architectures, you may choose to run the Scalable Heterogeneous Computing Benchmark Suite (SHOC)

  6. Method for directly recovering fluorine from gas streams

    DOE Patents [OSTI]

    Orlett, Michael J.; Saraceno, Anthony J.

    1981-01-01

    This invention is a process for the direct recovery of gaseous fluorine from waste-gas streams or the like. The process comprises passing the gas stream through a bed of anhydrous K.sub.3 NiF.sub.6 pellets to fluorinate the same to K.sub.3 NiF.sub.7 and subsequently desorbing the fluorine by heating the K.sub.3 NiF.sub.7 pellets to a temperature re-converting them to K.sub.3 NiF.sub.6. The efficiency of the fluorine-absorption step is maximized by operating in a selected and conveniently low temperature. The desorbed fluorine is highly pure and is at a pressure of several atmospheres. Preferably, the K.sub.3 NiF.sub.6 pellets are prepared by a method including the steps of forming agglomerates of hydrated K.sub.3 NiF.sub.5, sintering the agglomerates to form K.sub.3 NiF.sub.5 pellets of enhanced reactivity with respect to fluorine, and fluorinating the sintered pellets to K.sub.3 NiF.sub.6.

  7. Catalytic process for removing toxic gases from gas streams

    SciTech Connect (OSTI)

    Baglio, J.A.; Gaudet, G.G.; Palilla, F.C.

    1983-02-22

    A multi-stage process for reducing the content of sulfurcontaining gases-notably hydrogen sulfide, sulfur dioxide, carbonyl sulfide and carbon disulfide-in waste gas streams is provided. In the first stage, the gas stream is passed through a reaction zone at a temperature between about 150 and 350/sup 0/C in the presence of a pretreated novel catalyst of the formula xLn/sub 2/O/sub 3/ in which Ln is yttrium or a rare earth element and T is cobalt, iron or nickel, and each of x and y is independently a number from 0 to 3, said catalyst being substantially non-crystalline and having a surface area of from about 10 m/sup 2//g to about 40 m/sup 2//g. The preferred catalyst is one in which Ln is lanthanum, T is cobalt, and x and y range from 1 to 3, including non-integers. The first stage yields a product stream having a reduced content of sulfur-containing gases, including specifically, substantial reduction of carbonyl sulfide and virtual elimination of carbon disulfide. An intermediate stage is a claus reaction, which may take place in one or more reaction zones, at temperatures less than about 130/sup 0/ C, in the presence of known catalysts such as bauxite, alumina or cobalt molybdates. The final stage is the air oxidation of hydrogen sulfide at a temperature between about 150 and 300/sup 0/ C in the presence of a catalyst usable in first stage.

  8. Refinery Capacity Report

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 9 Shell Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 10...

  9. Saudi Aramco Mobile Refinery Company (SAMREF) | Open Energy Informatio...

    Open Energy Info (EERE)

    Company (SAMREF) Name: Saudi Aramco Mobile Refinery Company (SAMREF) Address: P.O. Box 30078 Place: Yanbu, Saudi Arabia Sector: Oil and Gas Product: Crude Oil Refining Phone...

  10. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Commodity PAD Districts I II III IV V United States Table 10a. Fuel Consumed at Refineries by PAD District, 2015 (Thousand Barrels, Except Where Noted) Crude Oil 0 0 0 0 0 0 Liquefied Petroleum Gases 0 1,834 309 20 846 3,009 Distillate Fuel Oil 0 26 220 8 110 364 Residual Fuel Oil 20 18 22 2 333 395 Still Gas 15,955 50,290 112,346 8,842 44,613 232,046 Marketable Petroleum Coke 0 0 0 520 90 610 Catalyst Petroleum Coke 8,229 17,001 43,013 2,876 10,891 82,010 Natural Gas (million cubic feet) 48,181

  11. Method of purifying a gas stream using 1,2,3-triazolium ionic liquids

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunald; Tang, Chau

    2014-12-09

    A method for separating a target gas from a gaseous mixture using 1,2,3-triazolium ionic liquids is presented. Industrial effluent streams may be cleaned by removing carbon dioxide from the stream by contacting the effluent stream with a 1,2,3-triazolium ionic liquid compound.

  12. LPG recovery from refinery flare by waste heat powered absorption refrigeration

    SciTech Connect (OSTI)

    Erickson, D.C.; Kelly, F.

    1998-07-01

    A waste heat powered ammonia Absorption Refrigeration Unit (ARU) has commenced operation at the Colorado Refining Company in Commerce City, Colorado. The ARU provides 85 tons of refrigeration at 30 F to refrigerate the net gas/treat gas stream, thereby recovering 65,000 barrels per year of LPG which formerly was flared or burned as fuel. The ARU is powered by the 290 F waste heat content of the reform reactor effluent. An additional 180 tons of refrigeration is available at the ARU to debottleneck the FCC plant wet gas compressors by cooling their inlet vapor. The ARU is directly integrated into the refinery processes, and uses enhanced, highly compact heat and mass exchange components. The refinery's investment will pay back in less than two years from increased recovery of salable product, and CO{sub 2} emissions are decreased by 10,000 tons per year in the Denver area.

  13. Apparatus and method for removing mercury vapor from a gas stream

    DOE Patents [OSTI]

    Ganesan, Kumar

    2008-01-01

    A metallic filter effectively removes mercury vapor from gas streams. The filter captures the mercury which then can be released and collected as product. The metallic filter is a copper mesh sponge plated with a six micrometer thickness of gold. The filter removes up to 90% of mercury vapor from a mercury contaminated gas stream.

  14. Method for combined removal of mercury and nitrogen oxides from off-gas streams

    DOE Patents [OSTI]

    Mendelsohn, Marshall H.; Livengood, C. David

    2006-10-10

    A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

  15. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  16. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, Thomas F.; Robin, Allen M.; Wolfenbarger, James K.; Suggitt, Robert M.

    1995-01-01

    A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.

  17. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, T.F.; Robin, A.M.; Wolfenbarger, J.K.; Suggitt, R.M.

    1995-03-28

    A partial oxidation process is described for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H{sub 2}, CO, CO{sub 2}, H{sub 2}O, CH{sub 4}, NH{sub 3}, HCl, HF, H{sub 2}S, COS, N{sub 2}, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N{sub 2} and H{sub 2}. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000 F. 1 figure.

  18. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Bustard, C.J.

    1999-04-13

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 5 figs.

  19. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Refinery Capacity Report With Data as of January 1, 2016 | Release Date: June 22, 2016 | Next Release Date: June 23, 2017 Previous Issues Year: 2016 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 prior issues Go Data series include fuel, electricity, and steam purchased for consumption at the refinery; refinery receipts of crude oil by method of transportation; and current and projected atmospheric crude oil distillation, downstream charge, and production capacities. Respondents are operators

  20. Optical backscatter probe for sensing particulate in a combustion gas stream

    DOE Patents [OSTI]

    Parks, James E; Partridge, William P

    2013-05-28

    A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

  1. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Former Corporation/Refiner Total Atmospheric Crude Oil Distillation Capacity (bbl/cd) New Corporation/Refiner Date of Sale Table 12. Refinery Sales During 2015 CHS Inc./CHS McPherson Refinery Inc. CHS Inc./NCRA 9/15 McPherson, KS 86,000 PBF Energy Co LLC/Chalmette Refining LLC Chalmette Refining LLC 11/15 Chalmette, LA 192,500 bbl/cd= Barrels per calendar day Sources: Energy Information Administration (EIA) Form EIA-810, "Monthly Refinery Report" and Form EIA-820, "Annual Refinery

  2. STREAM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description STREAM is a simple, synthetic benchmark designed to measure sustainable memory bandwidth (in MBs) and a corresponding computation rate for four simple vector...

  3. Apparatus for removal of particulate matter from gas streams

    DOE Patents [OSTI]

    Smith, Peyton L. (Baton Rouge, LA); Morse, John C. (Baton Rouge, LA)

    2000-01-01

    An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

  4. Method for removal and stabilization of mercury in mercury-containing gas streams

    DOE Patents [OSTI]

    Broderick, Thomas E.

    2005-09-13

    The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

  5. Method and apparatus for transport, introduction, atomization and excitation of emission spectrum for quantitative analysis of high temperature gas sample streams containing vapor and particulates without degradation of sample stream temperature

    DOE Patents [OSTI]

    Eckels, David E.; Hass, William J.

    1989-05-30

    A sample transport, sample introduction, and flame excitation system for spectrometric analysis of high temperature gas streams which eliminates degradation of the sample stream by condensation losses.

  6. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R. K.; Im, K. H.

    1996-01-01

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

  7. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R.K.; Im, K.H.

    1996-04-02

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

  8. Airfoil lance apparatus for homogeneous humidification and sorbent dispersion in a gas stream

    DOE Patents [OSTI]

    Myers, Robert B.; Yagiela, Anthony S.

    1990-12-25

    An apparatus for spraying an atomized mixture into a gas stream comprises a stream line airfoil member having a large radius leading edge and a small radius trailing edge. A nozzle assembly pierces the trailing edge of the airfoil member and is concentrically surrounded by a nacelle which directs shielding gas from the interior of the airfoil member around the nozzle assembly. Flowable medium to be atomized and atomizing gas for atomizing the medium are supplied in concentric conduits to the nozzle. A plurality of nozzles each surrounded by a nacelle are spaced along the trailing edge of the airfoil member.

  9. Airfoil lance apparatus for homogeneous humidification and sorbent dispersion in a gas stream

    DOE Patents [OSTI]

    Myers, R.B.; Yagiela, A.S.

    1990-12-25

    An apparatus for spraying an atomized mixture into a gas stream comprises a stream line airfoil member having a large radius leading edge and a small radius trailing edge. A nozzle assembly pierces the trailing edge of the airfoil member and is concentrically surrounded by a nacelle which directs shielding gas from the interior of the airfoil member around the nozzle assembly. Flowable medium to be atomized and atomizing gas for atomizing the medium are supplied in concentric conduits to the nozzle. A plurality of nozzles each surrounded by a nacelle are spaced along the trailing edge of the airfoil member. 3 figs.

  10. An integrated process for simultaneous desulfurization, dehydration, and recovery of hydrocarbon liquids from natural gas streams

    SciTech Connect (OSTI)

    Sciamanna, S.F. ); ))

    1988-01-01

    Conventional processing schemes for desulfurizing, drying, and separation of natural gas liquids from natural gas streams require treating the gas by a different process for each separation step. In a simpler process, based on the University of California, Berkeley Sulfur Recovery Process (UCBSRP) technology, hydrogen sulfide, propane and heavier hydrocarbons, and water are absorbed simultaneously by a polyglycol ether solvent containing a homogenous liquid phase catalyst. The catalyst promotes the subsequent reaction of hydrogen sulfide with added sulfur dioxide to produce a high quality sulfur product. Hydrocarbons are separated as two product streams with the split between propane and butane. This new process offers an overall reduction in both capital and energy costs.

  11. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, Arlin K.

    1986-01-01

    A method for separating gaseous samples from a contained atmosphere that includes aerosol particles uses the step of repelling particles from a gas permeable surface or membrane by heating the surface to a temperature greater than that of the surrounding atmosphere. The resulting thermophoretic forces maintain the gas permeable surface clear of aerosol particles. The disclosed apparatus utilizes a downwardly facing heated plate of gas permeable material to combine thermophoretic repulsion and gravity forces to prevent particles of any size from contacting the separating plate surfaces.

  12. Regenerable sorbents for CO.sub.2 capture from moderate and high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    2008-01-01

    A process for making a granular sorbent to capture carbon dioxide from gas streams comprising homogeneously mixing an alkali metal oxide, alkali metal hydroxide, alkaline earth metal oxide, alkaline earth metal hydroxide, alkali titanate, alkali zirconate, alkali silicate and combinations thereof with a binder selected from the group consisting of sodium ortho silicate, calcium sulfate dihydrate (CaSO.sub.4.2H.sub.2O), alkali silicates, calcium aluminate, bentonite, inorganic clays and organic clays and combinations thereof and water; drying the mixture and placing the sorbent in a container permeable to a gas stream.

  13. An optical gas temperature probe for high temperature fossil fuel process streams

    SciTech Connect (OSTI)

    Bauman, L.E.; Cook, R.L.; Lineberry, J.T.; Litchford, R.J.

    1995-12-31

    Reported here are the results of a feasibility study of a modular optical gas temperature probe for direct measurement of gas temperature in fossil-fueled combustion streams. A probe based upon the spectroscopic technique of line reversal would be superior to currently available gas temperature technology. The study concluded that a modular form of the line reversal optical temperature probe is feasible and, as such. the probe should be a commercially viable product with potential economic benefits from improved monitoring and control of utility furnaces. Such a probe will have the capability of making direct measurements of gas temperature in hot (>1500 K) process streams of coal combustion systems and large-scale power plant facilities.

  14. Texas Supplemental Supplies of Natural Gas

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Propane-Air 1981-2005 Refinery Gas 1981-2005 Other 1999-2005

  15. Removal of I, Rn, Xe and Kr from off gas streams using PTFE membranes

    DOE Patents [OSTI]

    Siemer, Darryl D.; Lewis, Leroy C.

    1990-08-07

    A process for removing I, R, Xe and Kr which involves the passage of the off gas stream through a tube-in-shell assembly, whereby the tubing is a PTFE membrane which permits the selective passages of the gases for removing and isolating the gases.

  16. Removal of I, Rn, Xe and Kr from off gas streams using PTFE membranes

    DOE Patents [OSTI]

    Siemer, Darryl D.; Lewis, Leroy C.

    1990-01-01

    A process for removing I, R, Xe and Kr which involves the passage of the off gas stream through a tube-in-shell assembly, whereby the tubing is a PTFE membrane which permits the selective passages of the gases for removing and isolating the gases.

  17. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels ... Catalytic Cracking Downstream Charge Capacity (Barrels per Stream Day) Cracking Thermal ...

  18. STREAM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coal demand seen below 1 billion tons in 2012 for fourth year in a row Coal consumption by U.S. power plants to generate electricity is expected to fall below 1 billion tons in 2012 for the fourth year in a row. Domestic coal consumption is on track to total 829 million tons this year. That's the lowest level since 1992, according to the U.S. Energy Information Administration's new monthly energy forecast. Utilities and power plant operators are choosing to burn more lower-priced natural gas

  19. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, A.K.

    1984-09-07

    This disclosure relates to separation of aerosol particles from gas samples withdrawn from within a contained atmosphere, such as containment vessels for nuclear reactors or other process equipment where remote gaseous sampling is required. It is specifically directed to separation of dense aerosols including particles of any size and at high mass loadings and high corrosivity. The United States Government has rights in this invention pursuant to Contract DE-AC06-76FF02170 between the US Department of Energy and Westinghouse Electric Corporation.

  20. Process for simultaneous removal of SO[sub 2] and NO[sub x] from gas streams

    DOE Patents [OSTI]

    Rosenberg, H.S.

    1987-02-03

    A process is described for simultaneous removal of SO[sub 2] and NO[sub x] from a gas stream that includes flowing the gas stream to a spray dryer and absorbing a portion of the SO[sub 2] content of the gas stream and a portion of the NO[sub x] content of the gas stream with ZnO by contacting the gas stream with a spray of an aqueous ZnO slurry; controlling the gas outlet temperature of the spray dryer to within the range of about a 0 to 125 F approach to the adiabatic saturation temperature; flowing the gas, unreacted ZnO and absorbed SO[sub 2] and NO[sub x] from the spray dryer to a fabric filter and collecting any solids therein and absorbing a portion of the SO[sub 2] remaining in the gas stream and a portion of the NO[sub x] remaining in the gas stream with ZnO; and controlling the ZnO content of the aqueous slurry so that sufficient unreacted ZnO is present in the solids collected in the fabric filter to react with SO[sub 2] and NO[sub x] as the gas passes through the fabric filter whereby the overall feed ratio of ZnO to SO[sub 2] plus NO[sub x] is about 1.0 to 4.0 moles of ZnO per of SO[sub 2] and about 0.5 to 2.0 moles of ZnO per mole of NO[sub x]. Particulates may be removed from the gas stream prior to treatment in the spray dryer. The process further allows regeneration of ZnO that has reacted to absorb SO[sub 2] and NO[sub x] from the gas stream and acid recovery. 4 figs.

  1. Process for simultaneous removal of SO.sub.2 and NO.sub.x from gas streams

    DOE Patents [OSTI]

    Rosenberg, Harvey S.

    1987-01-01

    A process for simultaneous removal of SO.sub.2 and NO.sub.x from a gas stream that includes flowing the gas stream to a spray dryer and absorbing a portion of the SO.sub.2 content of the gas stream and a portion of the NO.sub.x content of the gas stream with ZnO by contacting the gas stream with a spray of an aqueous ZnO slurry; controlling the gas outlet temperature of the spray dryer to within the range of about a 0.degree. to 125.degree. F. approach to the adiabatic saturation temperature; flowing the gas, unreacted ZnO and absorbed SO.sub.2 and NO.sub.x from the spray dryer to a fabric filter and collecting any solids therein and absorbing a portion of the SO.sub.2 remaining in the gas stream and a portion of the NO.sub.x remaining in the gas stream with ZnO; and controlling the ZnO content of the aqueous slurry so that sufficient unreacted ZnO is present in the solids collected in the fabric filter to react with SO.sub.2 and NO.sub.x as the gas passes through the fabric filter whereby the overall feed ratio of ZnO to SO.sub.2 plus NO.sub.x is about 1.0 to 4.0 moles of ZnO per of SO.sub.2 and about 0.5 to 2.0 moles of ZnO per mole of NO.sub.x. Particulates may be removed from the gas stream prior to treatment in the spray dryer. The process further allows regeneration of ZnO that has reacted to absorb SO.sub.2 and NO.sub.x from the gas stream and acid recovery.

  2. Iodine Pathways and Off-Gas Stream Characteristics for Aqueous Reprocessing Plants – A Literature Survey and Assessment

    SciTech Connect (OSTI)

    R. T. Jubin; D. M. Strachan; N. R. Soelberg

    2013-09-01

    Used nuclear fuel is currently being reprocessed in only a few countries, notably France, England, Japan, and Russia. The need to control emissions of the gaseous radionuclides to the air during nuclear fuel reprocessing has already been reported for the entire plant. But since the gaseous radionuclides can partition to various different reprocessing off-gas streams, for example, from the head end, dissolver, vessel, cell, and melter, an understanding of each of these streams is critical. These off-gas streams have different flow rates and compositions and could have different gaseous radionuclide control requirements, depending on how the gaseous radionuclides partition. This report reviews the available literature to summarize specific engineering data on the flow rates, forms of the volatile radionuclides in off-gas streams, distributions of these radionuclides in these streams, and temperatures of these streams. This document contains an extensive bibliography of the information contained in the open literature.

  3. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 2

    SciTech Connect (OSTI)

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J.

    1987-08-01

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster dsplays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume II covers papers presented at sessions 5 and 6 on system for the production of synthesis gas, and on system for the production of power. All papers have been processed for inclusion in the Energy Data Base.

  4. Gas stream clean-up filter and method for forming same

    DOE Patents [OSTI]

    Mei, Joseph S.; DeVault, James; Halow, John S.

    1993-01-01

    A gas cleaning filter is formed in-situ within a vessel containing a fluidizable bed of granular material of a relatively large size fraction. A filter membrane provided by a porous metal or ceramic body or such a body supported a perforated screen on one side thereof is coated in-situ with a layer of the granular material from the fluidized bed by serially passing a bed-fluidizing gas stream through the bed of granular material and the membrane. The layer of granular material provides the filtering medium for the combined membrane-granular layer filter. The filter is not blinded by the granular material and provides for the removal of virtually all of the particulates from a process gas stream. The granular material can be at least partially provided by a material capable of chemically reacting with and removing sulfur compounds from the process gas stream. Low level radioactive waste containing organic material may be incinerated in a fluidized bed in communication with the described filter for removing particulates from the gaseous combustion products.

  5. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 1

    SciTech Connect (OSTI)

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J.

    1987-08-01

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster displays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume I covers information presented at sessions 1 through 4 on systems for the production of Co-products and industrial fuel gas, environmental projects, and components and materials. Individual papers have been processed for the Energy Data Base.

  6. Hydrogen Generation for Refineries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ADVANCED MANUFACTURING OFFICE PEER REVIEW MEETING May 5-6, 2014 DE-FG02-08ER85135 Hydrogen Generation for Refineries DOE Phase II SBIR Dr. Girish Srinivas P.I. gsrinivas@tda.com 303-940-2321 Dr. Steven Gebhard, P.E. Dr. Robert Copeland Mr. Jeff Martin TDA Research Inc. 1 This presentation does not contain any proprietary, confidential, or otherwise restricted information This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Overview *

  7. Outlook for Refinery Outages and Available Refinery Capacity...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    level of refinery outages outlined in this report. This report does not consider the impacts of refined product logistics and distribution, which could affect the movement of...

  8. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C.

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  9. Total Number of Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  10. Refinery Upgrading of Hydropyrolysis Oil From Biomass

    SciTech Connect (OSTI)

    Roberts, Michael; Marker, Terry; Ortiz-Toral, Pedro; Linck, Martin; Felix, Larry; Wangerow, Jim; Swanson, Dan; McLeod, Celeste; Del Paggio, Alan; Urade, Vikrant; Rao, Madhusudhan; Narasimhan, Laxmi; Gephart, John; Starr, Jack; Hahn, John; Stover, Daniel; Parrish, Martin; Maxey, Carl; Shonnard, David; Handler, Robert; Fan, Jiquig

    2015-08-31

    Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located near biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed the

  11. Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Temperatures - Energy Innovation Portal Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication S-126827 (Organoclay Sorbent).pdf (292 KB) Technology Marketing Summary By incorporating amines inside clay containing quaternary ammonium salts (organoclay) minerals, this invention has created a way to prepare sorbents that capture carbon dioxide (CO2)

  12. Combined-cycle cogeneration to power oil refinery

    SciTech Connect (OSTI)

    Broeker, R.J.

    1986-11-01

    A cogeneration plant now under construction at an oil refinery in Martinez, California, is an example of how the energy industry has been responding to the fundamental economic and technological challenges it has been facing over the past ten years. The industry is re-examining cogeneration as one way of meeting the requirements of the Public Utilities Regulatory Policy Act. The new plant is located at Tosco Corporation's Avon Oil Refinery, 45 miles northeast of San Francisco. It was designed by Foster Wheeler to supply process steam for the refinery as well as for a water-treatment installation that will benefit the Contra Costa Water District. Electric power produced will be used primarily by the refinery, with the balance purchased by the Pacific Gas and Electric Company.

  13. Virginia Biodiesel Refinery | Open Energy Information

    Open Energy Info (EERE)

    Refinery Jump to: navigation, search Name: Virginia Biodiesel Refinery Place: West Point, Virginia Zip: 23180 Product: Biodiesel producer based in Virginia References: Virginia...

  14. ,"U.S. Refinery Net Input"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...petpnpinpt2dcnusmbbla.htm" ,"Source:","Energy Information Administration" ,"For Help, ... Barrels)","U.S. Refinery Net Input of Hydrogen (Thousand Barrels)","U.S. Refinery Net ...

  15. Storage tracking refinery trends

    SciTech Connect (OSTI)

    Saunders, J.

    1996-05-01

    Regulatory and marketplace shakeups have made the refining and petrochemical industries highly competitive. The fight to survive has forced refinery consolidations, upgrades and companywide restructurings. Bulk liquid storage terminals are following suit. This should generate a flurry of engineering and construction by the latter part of 1997. A growing petrochemical industry translates into rising storage needs. Industry followers forecasted flat petrochemical growth in 1996 due to excessive expansion in 1994 and 1995. But expansion is expected to continue throughout this year on the strength of several products.

  16. Refinery, petrochemical plant injuries decline

    SciTech Connect (OSTI)

    Not Available

    1994-07-25

    The National Petroleum Refiners Association (NPRA) reports a 7% reduction in workplace injury and illness incidence rates for refineries in 1993, and a 21% decrease for petrochemical plants. The report summarizes data from 135 of the 162 US member refineries, and 117 of the 172 US member petrochemical plants. This paper summarizes the report findings.

  17. Reformulated Gasoline Foreign Refinery Rules

    Gasoline and Diesel Fuel Update (EIA)

    Reformulated Gasoline Foreign Refinery Rules Contents * Introduction o Table 1. History of Foreign Refiner Regulations * Foreign Refinery Baseline * Monitoring Imported Conventional Gasoline * Endnotes Related EIA Short-Term Forecast Analysis Products * Areas Participating in the Reformulated Gasoline Program * Environmental Regulations and Changes in Petroleum Refining Operations * Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model * Refiners Switch to Reformulated

  18. Spray process for the recovery of CO.sub.2 from a gas stream and a related apparatus

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev; Perry, Robert James; Wood, Benjamin Rue; Genovese, Sarah Elizabeth

    2014-02-11

    A method for recovering carbon dioxide (CO.sub.2) from a gas stream is disclosed. The method includes the step of reacting CO.sub.2 in the gas stream with fine droplets of a liquid absorbent, so as to form a solid material in which the CO.sub.2 is bound. The solid material is then transported to a desorption site, where it is heated, to release substantially pure CO.sub.2 gas. The CO.sub.2 gas can then be collected and used or transported in any desired way. A related apparatus for recovering carbon dioxide (CO.sub.2) from a gas stream is also described herein.

  19. Means and method for the destruction of particles entrained in a gas stream

    DOE Patents [OSTI]

    Botts, Thomas E.; Powell, James R.

    1980-01-01

    An apparatus and method for the destruction of particles entrained in a gas stream are disclosed. Destruction in the context of the subject invention means the fragmentation and/or vaporization of particles above a certain size limit. The subject invention contemplates destroying such particles by exposing them to intense bursts of laser light, such light having a frequency approximately equal to or less than the mean size of such particles. This invention is particularly adopted to the protection of turbine blades in open cycle coal-fired turbine systems. Means for introducing various chemical species and activating them by exposure to laser light are also disclosed.

  20. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    of Last Operation Date Shutdown Table 13. Refineries Permanently Shutdown By PAD District Between January 1, 1990 and January 1, 2016 PAD District I 570,450 Primary Energy Corp Richmond, VA 6,100 0 a GNC Energy Corp Greensboro, NC 3,000 0 a Saint Mary's Refining Co Saint Mary's, WV 4,000 4,480 02/93 03/93 Cibro Refining Albany, NY 41,850 27,000 07/93 09/93 Calumet Lubricants Co LP Rouseville, PA 12,800 26,820 03/00 06/00 Young Refining Corp. Douglasville, GA 5,400 0 07/04 07/04 Sunoco Inc

  1. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Cokers Catalytic Crackers Hydrocrackers Capacity Inputs Capacity Inputs Capacity Inputs Table 8. Capacity and Fresh Feed Input to Selected Downstream Units at U.S. Refineries, 2014 - 2016 (Barrels per Calendar Day) Reformers Capacity Inputs 2014 2,686,917 5,616,015 2,034,689 2,337,425 4,884,975 1,662,603 2,591,992 3,419,407 74,900 475,800 41,500 47,633 407,342 29,849 PADD I 175,036 240,550 520,521 1,213,427 310,950 444,060 1,023,877 267,016 PADD II 645,874 837,754 1,479,496 2,916,764 1,118,239

  2. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Method PAD Districts I II III IV V United States Table 9. Refinery Receipts of Crude Oil by Method of Transportation by PAD District, 2015 (Thousand Barrels) a Pipeline 25,319 1,270,581 1,894,658 178,448 290,577 3,659,583 Domestic 2,766 679,552 1,624,647 86,978 222,419 2,616,362 Foreign 22,553 591,029 270,011 91,470 68,158 1,043,221 Tanker 305,663 0 941,152 0 513,584 1,760,399 Domestic 119,833 0 28,324 0 180,353 328,510 Foreign 185,830 0 912,828 0 333,231 1,431,889 Barge 22,367 4,569 227,383 0

  3. Process for CO.sub.2 capture using zeolites from high pressure and moderate temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.; Stevens, Robert W.

    2012-03-06

    A method for separating CO.sub.2 from a gas stream comprised of CO.sub.2 and other gaseous constituents using a zeolite sorbent in a swing-adsorption process, producing a high temperature CO.sub.2 stream at a higher CO.sub.2 pressure than the input gas stream. The method utilizes CO.sub.2 desorption in a CO.sub.2 atmosphere and effectively integrates heat transfers for optimizes overall efficiency. H.sub.2O adsorption does not preclude effective operation of the sorbent. The cycle may be incorporated in an IGCC for efficient pre-combustion CO.sub.2 capture. A particular application operates on shifted syngas at a temperature exceeding 200.degree. C. and produces a dry CO.sub.2 stream at low temperature and high CO.sub.2 pressure, greatly reducing any compression energy requirements which may be subsequently required.

  4. Grupo Maris Capital ethanol refinery | Open Energy Information

    Open Energy Info (EERE)

    Maris Capital ethanol refinery Jump to: navigation, search Name: Grupo Maris (Capital ethanol refinery) Place: Nuporanga, Brazil Product: 32,000 m3 ethanol refinery owner...

  5. Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2010-08-03

    Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

  6. Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device

    SciTech Connect (OSTI)

    Charles Mones

    2006-12-01

    application of this technology for removing elemental mercury from flue gas streams generated by utility boilers. On an absolute basis, the quantity of reagent required to accomplish the oxidation was small. For example, complete oxidation of mercury was accomplished using a 1% volume fraction of oxygen in a nitrogen stream. Overall, the tests with mercury validated the most useful aspect of the CR&E technology: Providing a method for elemental mercury removal from a gas phase by employing a specific plasma reagent to either increase reaction kinetics or promote reactions that would not have occurred under normal circumstances.

  7. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    11:34:24 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...NUS1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  8. ,"U.S. Refinery Net Input"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...RONUS1","MO9RONUS1","MBARONUS1" "Date","U.S. Refinery Net Input of Crude Oil and Petroleum Products (Thousand Barrels)","U.S. Refinery Net Input of Crude Oil (Thousand ...

  9. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    10:25:07 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...US1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  10. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    10:25:08 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...US1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  11. Silver-mordenite for radiologic gas capture from complex streams. Dual catalytic CH3I decomposition and I confinement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nenoff, Tina M.; Rodriguez, Mark A.; Soelberg, Nick R.; Chapman, Karena W.

    2014-05-09

    The selective capture of radiological iodine (129I) is a persistent concern for safe nuclear energy. In these nuclear fuel reprocessing scenarios, the gas streams to be treated are extremely complex, containing several distinct iodine-containing molecules amongst a large variety of other species. Silver-containing mordenite (MOR) is a longstanding benchmark for radioiodine capture, reacting with molecular iodine (I2) to form AgI. However the mechanisms for organoiodine capture is not well understood. Here we investigate the capture of methyl iodide from complex mixed gas streams by combining chemical analysis of the effluent gas stream with in depth characterization of the recovered sorbent.more » Tools applied include infrared spectroscopy, thermogravimetric analysis with mass spectrometry, micro X-ray fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. Moreover, the MOR zeolite catalyzes decomposition of the methyl iodide through formation of surface methoxy species (SMS), which subsequently reacts with water in the mixed gas stream to form methanol, and with methanol to form dimethyl ether, which are both detected downstream in the effluent. The liberated iodine reacts with Ag in the MOR pore to the form subnanometer AgI clusters, smaller than the MOR pores, suggesting that the iodine is both physically and chemically confined within the zeolite.« less

  12. Motiva Refinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Motiva Refinery May 18, 2006 - 10:45am Addthis Remarks Prepared for Energy Secretary Bodman Much of my time lately has been devoted to explaining why the price of gasoline has risen so sharply. President Bush understands the pinch this is creating for American consumers and has come forward with a variety of steps to address the problem. Rapid economic growth in emerging economies like China and India-and the growth here in the U.S.-have pushed up demand. Political unrest in some

  13. Solvent-refined-coal (SRC) process. Determination of trace hydrocarbon, sulfur, and nitrogen compounds in SRC-II process development Unit P-99 gas streams. [Impure hydrogen in recycle gas and low pressure gas processing

    SciTech Connect (OSTI)

    Gray, J.A.; Galli, R.D.; McCracken, J.H.

    1982-02-01

    A knowledge of the identity and concentration of trace hydrocarbon, sulfur, and nitrogen compounds in the various gas streams of the SRC-II Coal Liquefaction Process is needed in order to design the recycle gas purification and low pressure gas processing systems in large-scale plants. This report discusses the results of an experimental study to identify and quantify trace compounds in the various high and low pressure gas streams of SRC-II Process Development Unit P-99. A capillary column trace hydrocarbon analysis has been developed which can quantify 41 hydrocarbons from methane to xylenes in SRC-II gas streams. With more work a number of other hydrocarbons could be quantified. A fixed gas analysis was also developed which can be integrated with the hydrocarbon analysis to yield a complete stream analysis. A gas chromatographic procedure using a flame photometric detector was developed for trace sulfur compounds, and six sulfur compounds were identified and quantified. A chemiluminescence method was developed for determination of NO and NO/sub 2/ down to 10 ppB in concentration. A gas chromatographic procedure using an electron capture detector was developed for HCN analysis down to 5 ppM. Drager tube analyses gave semiquantitative data on HCl and NH/sub 3/ content of the gas streams.

  14. Coal-fired boiler for petroleum refinery

    SciTech Connect (OSTI)

    Ketterman, W.R.; Heinzmann, D.A.

    1982-01-01

    There has been a significant amount of interest in conversion from oil/gas fired boilers to coal-fired equipment since the Arab oil embargo of 1973. The CRA Incorporated Coffeyville Refinery decided in 1977 to proceed with the installation of a 86.183 Kg/h coal fired boiler to generate process steam at 650 psig (4,482 k Pa) 596/sup 0/F (313/sup 0/C). A significant portion of this steam is passed through steam turbines to obtain mechanical power. Building and operating a coal-fired steam plant is a ''Different Kettle of Fish'' from building and operating an oil/gas-fired steam plant. The intention of this paper is to deal with some of the ''Why's and Wherefores'' of the conversion to coal-fired equipment.

  15. U.S. Refinery

    U.S. Energy Information Administration (EIA) Indexed Site

    Leases Alaskan in Transit Bulk Terminal Pipeline Natural Gas Processing Plant Download ... Nov-15 Dec-15 Jan-16 Feb-16 Mar-16 Apr-16 View History Crude Oil and Petroleum Products ...

  16. Predicting properties of gas and solid streams by intrinsic kinetics of fast pyrolysis of wood

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Klinger, Jordan; Bar-Ziv, Ezra; Shonnard, David; Westover, Tyler; Emerson, Rachel

    2015-12-12

    Pyrolysis has the potential to create a biocrude oil from biomass sources that can be used as fuel or as feedstock for subsequent upgrading to hydrocarbon fuels or other chemicals. The product distribution/composition, however, is linked to the biomass source. This work investigates the products formed from pyrolysis of woody biomass with a previously developed chemical kinetics model. Different woody feedstocks reported in prior literature are placed on a common basis (moisture, ash, fixed carbon free) and normalized by initial elemental composition through ultimate analysis. Observed product distributions over the full devolatilization range are explored, reconstructed by the model, andmore » verified with independent experimental data collected with a microwave-assisted pyrolysis system. These trends include production of permanent gas (CO, CO2), char, and condensable (oil, water) species. Elementary compositions of these streams are also investigated. As a result, close agreement between literature data, model predictions, and independent experimental data indicate that the proposed model/method is able to predict the ideal distribution from fast pyrolysis given reaction temperature, residence time, and feedstock composition.« less

  17. Predicting properties of gas and solid streams by intrinsic kinetics of fast pyrolysis of wood

    SciTech Connect (OSTI)

    Klinger, Jordan; Bar-Ziv, Ezra; Shonnard, David; Westover, Tyler; Emerson, Rachel

    2015-12-12

    Pyrolysis has the potential to create a biocrude oil from biomass sources that can be used as fuel or as feedstock for subsequent upgrading to hydrocarbon fuels or other chemicals. The product distribution/composition, however, is linked to the biomass source. This work investigates the products formed from pyrolysis of woody biomass with a previously developed chemical kinetics model. Different woody feedstocks reported in prior literature are placed on a common basis (moisture, ash, fixed carbon free) and normalized by initial elemental composition through ultimate analysis. Observed product distributions over the full devolatilization range are explored, reconstructed by the model, and verified with independent experimental data collected with a microwave-assisted pyrolysis system. These trends include production of permanent gas (CO, CO2), char, and condensable (oil, water) species. Elementary compositions of these streams are also investigated. As a result, close agreement between literature data, model predictions, and independent experimental data indicate that the proposed model/method is able to predict the ideal distribution from fast pyrolysis given reaction temperature, residence time, and feedstock composition.

  18. Refinery Upgrading of Hydropyrolysis Oil from Biomass Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Upgrading of Hydropyrolysis Oil from Biomass March 25,2015 Technology Area Review PI - Terry Marker Gas Technology Institute This presentation does not contain any proprietary, confidential, or otherwise restricted information Goals * Develop a cost-effective route for converting biomass to transportation fuels by first converting biomass to hydropyrolysis oil and then upgrading the hydropyrolysis oil in existing refinery equipment - Study properties and corrosion characteristics of

  19. U.S. Refinery Yield

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquefied Refinery Gases 2.8 2.0 2.0 2.1 2.6 4.0 1993-2016 Finished Motor Gasoline 45.7 46.7 47.3 49.3 47.5 46.0 1993-2016 Finished Aviation Gasoline 0.1 0.1 0.1 0.0 0.1 0.1 ...

  20. Allocation of energy use in petroleum refineries to petroleum products : implications for life-cycle energy use and emission inventory of petroleum transportation fuels.

    SciTech Connect (OSTI)

    Wang, M.; Lee, H.; Molburg, J.

    2004-01-01

    Studies to evaluate the energy and emission impacts of vehicle/fuel systems have to address allocation of the energy use and emissions associated with petroleum refineries to various petroleum products because refineries produce multiple products. The allocation is needed in evaluating energy and emission effects of individual transportation fuels. Allocation methods used so far for petroleum-based fuels (e.g., gasoline, diesel, and liquefied petroleum gas [LPG]) are based primarily on mass, energy content, or market value shares of individual fuels from a given refinery. The aggregate approach at the refinery level is unable to account for the energy use and emission differences associated with producing individual fuels at the next sub-level: individual refining processes within a refinery. The approach ignores the fact that different refinery products go through different processes within a refinery. Allocation at the subprocess level (i.e., the refining process level) instead of at the aggregate process level (i.e., the refinery level) is advocated by the International Standard Organization. In this study, we seek a means of allocating total refinery energy use among various refinery products at the level of individual refinery processes. We present a petroleum refinery-process-based approach to allocating energy use in a petroleum refinery to petroleum refinery products according to mass, energy content, and market value share of final and intermediate petroleum products as they flow through refining processes within a refinery. The results from this study reveal that product-specific energy use based on the refinery process-level allocation differs considerably from that based on the refinery-level allocation. We calculated well-to-pump total energy use and greenhouse gas (GHG) emissions for gasoline, diesel, LPG, and naphtha with the refinery process-based allocation approach. For gasoline, the efficiency estimated from the refinery-level allocation

  1. Refinery & Blenders Net Input of Crude Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils,

  2. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  3. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect (OSTI)

    Holmgren, Jennifer; Marinangelli, Richard; Marker, Terry; McCall, Michael; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2007-02-01

    A presentation by UOP based on collaborative work from FY05 using some results from PNNL for upgrading biomass pyrolysis oil to petroleum refinery feedstock

  4. ,"Finished Motor Gasoline Refinery, Bulk Terminal, and Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    AM" "Back to Contents","Data 1: Finished Motor Gasoline Refinery, Bulk Terminal, and ... "Date","U.S. Finished Motor Gasoline Stocks at Refineries, Bulk ...

  5. NREL Refinery Process Shows Increased Effectiveness of Producing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae February 11, 2016 ...

  6. Potential Vulnerability of US Petroleum Refineries to Increasing...

    Energy Savers [EERE]

    Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature andor Reduced Water Availability Potential Vulnerability of US Petroleum Refineries to ...

  7. Refinery burner simulation design architecture summary.

    SciTech Connect (OSTI)

    Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.

    2011-10-01

    This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.

  8. Innovative filter polishes oil refinery wastewater

    SciTech Connect (OSTI)

    Irwin, J.; Finkler, M.

    1982-07-01

    Describes how, after extensive testing of 4 different treatment techniques, a Hydro Clear rapid sand filter was installed at the Sohio oil refinery in Toledo, Ohio. This filtration system has proven to be more cost-effective than conventional approaches. The system handles the refinery's wastewater flow of 10.3 mgd. With the aid of the polishing filter, readily meets the NPDES permit limitations. The Toledo refinery is a highly integrated petroleum processing complex. It processes 127,000 barrels per day of crude oil, including 40,000 barrels per day of sour crude. Tables give dissolved air flotation performance data; biological system performance data; filter performance data; and refinery waste treatment unit compared with NPDES-BPT limitations. Diagram shows the Sohio refinery wastewater treatment facility. Through a separate backwash treatment system complete control is brought to the suspended solids in the effluent which also tends to control chemical oxygen demand and oil/grease levels.

  9. Catalysts, systems and methods to reduce NOX in an exhaust gas stream

    DOE Patents [OSTI]

    Castellano, Christopher R.; Moini, Ahmad; Koermer, Gerald S.; Furbeck, Howard

    2010-07-20

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having an SCR catalyst comprising silver tungstate on an alumina support. The emissions treatment system may be used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines. An emissions treatment system may further comprise an injection device operative to dispense a hydrocarbon reducing agent upstream of the catalyst.

  10. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial

  11. DEVELOPMENT OF A HYDROGEN MORDENITE SORBENT FOR THE CAPTURE OF KRYPTON FROM USED NUCLEAR FUEL REPROCESSING OFF-GAS STREAMS

    SciTech Connect (OSTI)

    Mitchell Greenhalgh; Troy G. Garn; Jack D. Law

    2014-04-01

    A novel new sorbent for the separation of krypton from off-gas streams resulting from the reprocessing of used nuclear fuel has been developed and evaluated. A hydrogen mordenite powder was successfully incorporated into a macroporous polymer binder and formed into spherical beads. The engineered form sorbent retained the characteristic surface area and microporosity indicative of mordenite powder. The sorbent was evaluated for krypton adsorption capacities utilizing thermal swing operations achieving capacities of 100 mmol of krypton per kilogram of sorbent at a temperature of 191 K. A krypton adsorption isotherm was also obtained at 191 K with varying krypton feed gas concentrations. Adsorption/desorption cycling effects were also evaluated with results indicating that the sorbent experienced no decrease in krypton capacity throughout testing.

  12. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    2010-06-01

    Funded by the American Recovery and Reinvestment Act of 2009 ENVIRON International Corporation, in collaboration with Callidus Technologies by Honeywell and Shell Global Solutions, Inc., will develop and demonstrate a full-scale fuel blending and combustion system. This system will allow a broad range of opportunity fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas, to be safely, cost-effectively, and efficiently utilized while generating minimal emissions of criteria pollutants. The project will develop a commercial technology for application in refinery and chemical plant process heaters where opportunity fuels are used.

  13. Former Soviet refineries face modernization, restructuring

    SciTech Connect (OSTI)

    Not Available

    1993-11-29

    A massive modernization and restructuring program is under way in the refining sector of Russia and other former Soviet republics. Economic reforms and resulting economic dislocation following the collapse of the Soviet Union has left refineries in the region grappling with a steep decline and changes in product demand. At the same time, rising oil prices and an aging, dilapidated infrastructure promise a massive shakeout. Even as many refineries in the former Soviet Union (FSU) face possible closure because they are running at a fraction of capacity, a host of revamps, expansions, and grass roots refineries are planned or under way. The paper discusses plans.

  14. Microsoft PowerPoint - Tritium Gas Stream Scrubbing using In-situ Reactive Materials.pptx

    Office of Environmental Management (EM)

    Stream Scrubbing using In-situ Reactive Materials Paul Korinko, Simona Murph, and George Larsen Tritium Focus Group Meeting LANL Nov 3-5, 2015 SRNL-STI-2015-00597 Tritium Production and Extraction * Tritium Producing Burnable Absorber Rods (TPBARs) * Built to strict materials specifications * Coatings, ceramics, metals, processes * Meet NQA-1 requirements * Irradiated in a commercial light water reactor * Extracted at SRS in the Tritium Extraction Facility * Waste disposed on-site Contamination

  15. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Castellano, Christopher R.; Moini, Ahmad; Koermer, Gerald S.; Furbeck, Howard; Schmieg, Steven J.; Blint, Richard J.

    2011-05-17

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver and a platinum group metal on a particulate alumina support, the atomic fraction of the platinum group metal being less than or equal to about 0.25. Methods of manufacturing catalysts are described in which silver is impregnated on alumina particles.

  16. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Koermer, Gerald S.; Moini, Ahmad; Furbeck, Howard; Castellano, Christopher R.

    2012-05-08

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver on a particulate alumina support, the silver having a diameter of less than about 20 nm. Methods of manufacturing catalysts are described in which ionic silver is impregnated on particulate hydroxylated alumina particles.

  17. Process and apparatus for separation of components of a gas stream

    DOE Patents [OSTI]

    Bryan, Charles R; Torczynski, John R; Brady, Patrick V; Gallis, Michail; Brooks, Carlton F

    2013-09-17

    A process and apparatus for separating a gas mixture comprising providing a slot in a gas separation channel (conceptualized as a laterally elongated Clusius-Dickel column), having a length through which a net cross-flow of the gas mixture may be established; applying a higher temperature to one side of the channel and a lower temperature on an opposite side of the channel thereby causing thermal-diffusion and buoyant-convection flow to occur in the slot; and establishing a net cross-flow of a gas mixture comprising at least one higher density gas component and at least one lower density gas component along the length of the slot, wherein the cross-flow causes, in combination with the convection flow, a spiraling flow in the slot; and wherein the spiral flow causes an increasing amount of separation of the higher density gas from the lower density gas along the length of the channel. The process may use one or more slots and/or channels.

  18. Process and apparatus for separation of components of a gas stream

    DOE Patents [OSTI]

    Bryan, Charles R; Torczynski, John R; Brady, Patrick V; Gallis, Michail; Brooks, Carlton F

    2013-11-19

    A process and apparatus for separating a gas mixture comprising providing a slot in a gas separation channel (conceptualized as a laterally elongated Clusius-Dickel column), having a length through which a net cross-flow of the gas mixture may be established; applying a higher temperature to one side of the channel and a lower temperature on an opposite side of the channel thereby causing thermal-diffusion and buoyant-convection flow to occur in the slot; and establishing a net cross-flow of a gas mixture comprising at least one higher density gas component and at least one lower density gas component along the length of the slot, wherein the cross-flow causes, in combination with the convection flow, a spiraling flow in the slot; and wherein the spiral flow causes an increasing amount of separation of the higher density gas from the lower density gas along the length of the channel. The process may use one or more slots and/or channels.

  19. Process and apparatus for separation of components of a gas stream

    DOE Patents [OSTI]

    Bryan, Charles R.; Torczynski, John R.; Brady, Patrick V.; Gallis, Michail; Brooks, Carlton F.

    2014-06-17

    A process and apparatus for separating a gas mixture comprising providing a slot in a gas separation channel (conceptualized as a laterally elongated Clusius-Dickel column), having a length through which a net cross-flow of the gas mixture may be established; applying a higher temperature to one side of the channel and a lower temperature on an opposite side of the channel thereby causing thermal-diffusion and buoyant-convection flow to occur in the slot; and establishing a net cross-flow of a gas mixture comprising at least one higher density gas component and at least one lower density gas component along the length of the slot, wherein the cross-flow causes, in combination with the convection flow, a spiraling flow in the slot; and wherein the spiral flow causes an increasing amount of separation of the higher density gas from the lower density gas along the length of the channel. The process may use one or more slots and/or channels.

  20. From the Woods to the Refinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Woods to the Refinery CORRIM Life Cycle Analyses of Woody Feedstocks Dr. Steve Kelley ... composition, sugar types, residue fuel value * TC models are sensitive to MC, much less ...

  1. Motiva Enterprises Refinery Expansion Groundbreaking | Department...

    Office of Environmental Management (EM)

    of the preeminent refineries on the Gulf Coast will become the largest in the United States and one of the largest in ... help America meet its petroleum needs well into the future. ...

  2. From the Woods to the Refinery

    Broader source: Energy.gov [DOE]

    Breakout Session 2D—Building Market Confidence and Understanding II: Carbon Accounting and Woody Biofuels From the Woods to the Refinery Stephen S. Kelley, Principal and Department Head, Department of Forest Biomaterials, North Carolina State University

  3. Iran to build new refinery at Arak

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This paper reports Iranian plans to construct a grassroots 150,000-b/d refinery in Arak. The plant, to be completed in early 1993, will be capable of producing unleaded gasoline and other light products.

  4. Myriant Succinic Acid BioRefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or otherwise restricted information Myriant Succinic Acid BioRefinery DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Mark Shmorhun, Principal Investigator March 25, 2015 2 Goal Statement * Renewable Succinic Acid Production * A high value bio based chemical derived from renewable feedstocks * Validate proposed technology at a demonstration plant located in Lake Providence, LA. * Nameplate Capacity: 30 million lbs/year 3 Myriant's Succinic Acid BioRefinery (MySAB) Lake

  5. Refinery siting workbook: appendices A and B

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    The objective of this effort is to develop and provide basic refinery-related information for use by state and local government officials as a basis for establishing responsible refinery siting requirements and policies consistent with the federal clean air and water standards and socio-economic concerns. The report will be organized into two volumes. The main text comprises the basic topics of physical concerns, regulatory requirements, and permitting activities, while the second volume includes the detailed appendix materials such as the applicable laws, and the necessary permits, as available and a glossary of pertinent terms. As a means to this objective, three refinery sizes, 200,000, 100,000 and 30,000 barrels per day crude charge will be discussed in technical terms. Process unit configuration will be presented which will maximize either gasoline or heating oil production with either sweet or sour crude oil feedstocks. The major issues affecting the socio-economic impact of siting the refinery in a given locale will be presented. These data will review the factors affecting the human environment and the issues that must be addressed to assess the impact that a refinery will have on a community. The key federal registrations which impact upon a refinery siting decision shall be reviewed. Summaries of these regulations and a simplified decision diagram for the air and water acts shall be presented to assist both government and refinery officials in understanding the scope of regulatory impact. All pertinent procedures required for refinery permitting shall be reviewed under the generalized headings of air, water, health and safety, land use, and miscellaneous permits. This categorization at the federal, state and local levels of government shall be used as a basis for establishing degrees of emphasis.

  6. Selective catalytic reduction system and process for control of NO.sub.x emissions in a sulfur-containing gas stream

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly

    2015-08-11

    An exhaust gas treatment process, apparatus, and system for reducing the concentration of NOx, CO and hydrocarbons in a gas stream, such as an exhaust stream (29), via selective catalytic reduction with ammonia is provided. The process, apparatus and system include a catalytic bed (32) having a reducing only catalyst portion (34) and a downstream reducing-plus-oxidizing portion (36). Each portion (34, 36) includes an amount of tungsten. The reducing-plus-oxidizing catalyst portion (36) advantageously includes a greater amount of tungsten than the reducing catalyst portion (36) to markedly limit ammonia salt formation.

  7. Evaluating electric-resistance-welded tubing for refinery and chemical plant applications

    SciTech Connect (OSTI)

    Polk, C.J.; Hotaling, A.C. )

    1993-02-01

    A laboratory technique was developed to assess the potential for preferential attack along the longitudinal seam of electric-resistance-welded (ERW) carbon steel tubing exposed to refinery and chemical plant process streams. Used in conjunction with an evaluation of mill fabrication practices, the test procedure can identify high-quality ERW products that can be used in many applications in place of seamless components at significant cost savings.

  8. Heavy crude upgrading using remote natural gas

    SciTech Connect (OSTI)

    Grosboll, M.P.

    1991-12-03

    This paper describes a method of forming an upgraded crude. It comprises: forming hydrogen from methane gas for hydroconverting heavy crude to form a better crude and reduce its viscosity; hydrogenating under hydroconverting conditions of 650 degrees Fahrenheit ({degrees}F)-1000{degrees}F; and 500-3000 pounds per square inch gauge (psig) only a first portion of a crude oil stream less than the total crude oil stream to produce a light oil that has a lowered viscosity; admixing the light oil with the remainder of the crude oil stream not hydrogenated to produce a flowable crude; and transporting the flowable crude to a refinery including a substep of flowing the crude through a pipeline.

  9. U.S. Refinery Yield

    U.S. Energy Information Administration (EIA) Indexed Site

    2011 2012 2013 2014 2015 2016 View History Liquefied Refinery Gases 4.0 4.0 3.9 4.0 3.7 3.7 1993-2016 Finished Motor Gasoline 45.6 45.7 45.7 45.7 46.0 47.5 1993-2016 Finished Aviation Gasoline 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Kerosene-Type Jet Fuel 9.3 9.4 9.4 9.4 9.5 9.6 1993-2016 Kerosene 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Distillate Fuel Oil 28.6 28.7 29.1 29.5 29.4 28.1 1993-2016 Residual Fuel Oil 3.4 3.1 2.9 2.6 2.5 2.5 1993-2016 Naphtha for Petrochemical Feedstock Use 1.3 1.3 1.5 1.2 1.1

  10. Novel Application of Carbonate Fuel Cell for Capturing Carbon Dioxide from Flue Gas Streams

    SciTech Connect (OSTI)

    Jolly, Stephen; Ghezel-Ayagh, Hossein; Willman, Carl; Patel, Dilip; DiNitto, M.; Marina, Olga A.; Pederson, Larry R.; Steen, William A.

    2015-09-30

    To address concerns about climate change resulting from emission of CO2 by coal-fueled power plants, FuelCell Energy, Inc. has developed the Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept. The CEPACS system utilizes Electrochemical Membrane (ECM) technology derived from the Company’s Direct FuelCell® products. The system separates the CO2 from the flue gas of other plants and produces electric power using a supplementary fuel. FCE is currently evaluating the use of ECM to cost effectively separate CO2 from the flue gas of Pulverized Coal (PC) power plants under a U.S. Department of Energy contract. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from the flue gas with no more than 35% increase in the cost of electricity. The project activities include: 1) laboratory scale operational and performance tests of a membrane assembly, 2) performance tests of the membrane to evaluate the effects of impurities present in the coal plant flue gas, in collaboration with Pacific Northwest National Laboratory, 3) techno-economic analysis for an ECM-based CO2 capture system applied to a 550 MW existing PC plant, in partnership with URS Corporation, and 4) bench scale (11.7 m2 area) testing of an ECM-based CO2 separation and purification system.

  11. An industrial FT-IR process gas analyzer for stack gas cems analysis

    SciTech Connect (OSTI)

    Welch, G.M.; Herman, B.E.

    1995-12-31

    This paper describes utilizing Fourier Transform Infrared (FT-IR) technology to meet and exceed EPA requirements to Continuously Monitor Carbon Monoxide (CO) and Sulfur Dioxide (SO){sub 2} in an oil refinery. The application consists of Continuous Emission Monitoring (CEMS) of two stacks from a Fluid Catalytic Cracking unit (FCCU). The discussion will follow the project from initial specifications, installation, start-up, certification results (RATA, 7 day drift), Cylinder Gas Audit (CGA) and the required maintenance. FT-IR is a powerful analytical tool suitable for measurement of stack component gases required to meet CEMS regulations, and allows simultaneous multi-component analysis of complex stack gas streams with a continuous sample stream flow through the measurement cell. The Michelson Interferometer in a unique {open_quotes}Wishbone{close_quotes} design and with a special alignment control enables standardized configuration of the analyzer for flue gas analysis. Normal stack gas pollutants: NO{sub x}, SO{sub 2}, and CO; as well as water soluble pollutants such as NH{sub 3} and HCI may be accurately determined and reported even in the presence of 0-31 Vol % water vapor concentrations (hot and wet). This FT-IR analyzer has been operating with EPA Certification in an oil refinery environment since September 1994.

  12. Independent quality assurance of refinery fugitives testing by western states petroleum association. Final audit report

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    Research Triangle Institute (RTI) undertook this task for the U.S. Environmental Protection Agency's (EPA's) Office of Air Quality Planning and Standards to provide third-party Quality Assurance (QA) support to a Western States' Petroleum Association (WSPA) program to measure fugitive emissions at petroleum refineries. The primary objectives of the WSPA study were to determine the correlation between screening values and true mass emission rates and to develop a relationship between liquid and gas composition. EPA's QA effort, however, focused only on the correlation objective because the number of leaking components in the California refineries cannot be expected to be representative of refineries in general. The number of components leaking at a given screening value is used in conjunction with the mass correlations to derive the average emission factors.

  13. Effect of morphology of sulfurized materials in the retention of mercury from gas streams

    SciTech Connect (OSTI)

    Guijarro, M.I.; Mendioroz, S.; Munoz, V.

    1998-03-01

    Mercury pollution sources are chloralkali industries, metal sulfide ore smelting, gold refining, cement production, industrial applications of metals, and, especially, fossil fuel combustion and incineration of sewage sludge or municipal garbage. The retention of mercury vapor by sulfur supported on sepiolite has been studied, and the utility of sepiolite as a dispersant for the active phase, sulfur, has been thoroughly ascertained. Samples with 10% S supported on sepiolite of varying size and shape have been prepared from powders sulfurized by reaction/deposit, and their efficiency in depurating air streams with 95 ppm mercury has been tested in a dynamic system using a fixed-bed glass reactor and fluid velocities ranging from 3.1 to 18.9 cm/s. From breakthrough curves under various sets of conditions, the importance of mass transfer under the process conditions has been proven. The progress of the reaction is limited by the resistance to reactant diffusion inside the solid through the layer of product formed. Sulfur reaction to HgS is reduced to an external zone of the solid, giving rise to an egg-shell deposit whose extension is related to sulfur dispersion and porosity of the adsorbent. Then, conversion and capacity of the samples are related to their porosity and S/V ratio. The use of SEM helps to confirm those statements. The 10% S samples compare well with the more conventional S/activated carbon, with their use being advantageous for the low price and abundance of the substrate.

  14. Silver-mordenite for radiologic gas capture from complex streams. Dual catalytic CH3I decomposition and I confinement

    SciTech Connect (OSTI)

    Nenoff, Tina M.; Rodriguez, Mark A.; Soelberg, Nick R.; Chapman, Karena W.

    2014-05-09

    The selective capture of radiological iodine (129I) is a persistent concern for safe nuclear energy. In these nuclear fuel reprocessing scenarios, the gas streams to be treated are extremely complex, containing several distinct iodine-containing molecules amongst a large variety of other species. Silver-containing mordenite (MOR) is a longstanding benchmark for radioiodine capture, reacting with molecular iodine (I2) to form AgI. However the mechanisms for organoiodine capture is not well understood. Here we investigate the capture of methyl iodide from complex mixed gas streams by combining chemical analysis of the effluent gas stream with in depth characterization of the recovered sorbent. Tools applied include infrared spectroscopy, thermogravimetric analysis with mass spectrometry, micro X-ray fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. Moreover, the MOR zeolite catalyzes decomposition of the methyl iodide through formation of surface methoxy species (SMS), which subsequently reacts with water in the mixed gas stream to form methanol, and with methanol to form dimethyl ether, which are both detected downstream in the effluent. The liberated iodine reacts with Ag in the MOR pore to the form subnanometer AgI clusters, smaller than the MOR pores, suggesting that the iodine is both physically and chemically confined within the zeolite.

  15. Delaware Supplemental Supplies of Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    2 1 0 * * 6 1967-2014 Propane-Air 2 1 0 0 6 1980-2014 Refinery Gas 1980-2005 Other 0 1999-2014

  16. Indiana Supplemental Supplies of Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    1 5 1 6 69 1967-2014 Propane-Air 1 1 5 1 6 69 1980-2014 Refinery Gas 1980-2005

  17. Application of the carbon dioxide-barium hydroxide hydrate gas-solid reaction for the treatment of dilute carbon dioxide-bearing gas streams

    SciTech Connect (OSTI)

    Haag, G.L.

    1983-09-01

    The removal of trace components from gas streams via irreversible gas-solid reactions in an area of interest to the chemical engineering profession. This research effort addresses the use of fixed beds of Ba(OH)/sub 2/ hydrate flakes for the removal of an acid gas, CO/sub 2/, from air that contains approx. 330 ppM/sub v/ CO/sub 2/. Areas of investigation encompassed: (1) an extensive literature review of Ba(OH)/sub 2/ hydrate chemistry, (2) microscale studies on 0.150-g samples to develop a better understanding of the reaction, (3) process studies at the macroscale level with 10.2-cm-ID fixed-bed reactors, and (4) the development of a model for predicting fixed-bed performance. Experimental studies indicated fixed beds of commercial Ba(OH)/sub 2/.8H/sub 2/O flakes at ambient temperatures to be capable of high CO/sub 2/-removal efficiencies (effluent concentrations <100 ppB), high reactant utilization (>99%), and an acceptable pressure drop (1.8 kPa/m at a superficial gas velocity of 13 cm/s). Ba(OH)/sub 2/.8H/sub 2/O was determined to be more reactive toward CO/sub 2/ than either Ba(OH)/sub 2/.3H/sub 2/O or Ba(OH)/sub 2/.1H/sub 2/O. A key variable in the development of this fixed-bed process was relative humidity. Operation at conditions with effluent relative humidities >60% resulted in significant recrystallization and restructuring of the flake and subsequent pressure-drop problems.

  18. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  19. ,"U.S. Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Content (Weighted Average) of Crude Oil Input to Refineries (Percent)","U.S. API Gravity (Weighted Average) of Crude Oil Input to Refineries (Degrees)" 31062,0.88,32.64 ...

  20. ,"U.S. Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Content (Weighted Average) of Crude Oil Input to Refineries (Percent)","U.S. API Gravity (Weighted Average) of Crude Oil Input to Refineries (Degrees)" 31228,0.91,32.46 ...

  1. GreenHunter Biodiesel Refinery Grand Opening | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GreenHunter Biodiesel Refinery Grand Opening GreenHunter Biodiesel Refinery Grand Opening June 2, 2008 - 12:51pm Addthis Remarks as Prepared for (Acting) Deputy Secretary Kupfer ...

  2. Crude oil as refinery feed stock

    SciTech Connect (OSTI)

    Boduszynski, M.M.; Farrell, T.R.

    1995-12-31

    This paper gives a brief overview of the integrated oil refinery. It illustrates that crude oil refining involves {open_quotes}molecular tailoring,{close_quotes} where feed stock molecules are {open_quotes}tailored{close_quotes} through catalytic processing to make products with the most desirable composition. Chemical composition of crude oil as refinery feed stock is discussed. The emphasis is on the understanding of molecular transformations which occur in refinery processes to manufacture light transportation fuels. Diesel fuel manufacturing is used as an example. Recent environmental legislation in the United States has necessitated a significant upgrade in the quality of diesel fuel used for highway transportation. Examples are given to illustrate the impact that petroleum chemistry may have on the industry`s response to government regulations.

  3. Assessment of the potential for refinery applications of inorganic membrane technology: An identification and screening analysis. Final report

    SciTech Connect (OSTI)

    Johnson, H.E.; Schulman, B.L.

    1993-05-01

    Commercial application of membrane technology in the separation of gas, liquid, and solid streams has grown to a business with worldwide revenues exceeding $1 billion annually. Use of organic membranes for industrial gas separation, particularly in the refining industry, is one of the major growth areas. However, organic membranes based on polymeric separation barriers, are susceptible to damage by liquids, and careful precautions must be taken to retain the system integrity. Researchers are currently developing small pore sized inorganic membranes which may substantially increase the efficiency and economics in selected refinery separation applications. Expected advantages of these advanced inorganic membranes include high permeability, high selectivity, and low manufacturing cost. SFA Pacific conducted a screening analysis to identify applications for inorganic membrane technology in the petroleum refining industry and their potential cost advantages over competing separation systems. Two meetings were held in connection with this project. Copies of Viewgraphs presented by SFA Pacific at these meetings are attached in Appendices A and C. Potential high priority applications and market impacts of advanced inorganic membrane technology in the refining industry are addressed in this report, and include the following areas: Competitive separation technologies; application of those technologies; incentives for inorganic membranes; market benefits and impacts of inorganic membranes.

  4. Refinery Input by PADD - Petroleum Supply Annual (2004)

    SciTech Connect (OSTI)

    2009-01-18

    Table showing refinery input of crude oil and petroleum products by Petroleum Administration for Defense Districts (PADD).

  5. Solid sorbents for removal of carbon dioxide from gas streams at low temperatures

    DOE Patents [OSTI]

    Sirwardane, Ranjani V.

    2005-06-21

    New low-cost CO.sub.2 sorbents are provided that can be used in large-scale gas-solid processes. A new method is provided for making these sorbents that involves treating substrates with an amine and/or an ether so that the amine and/or ether comprise at least 50 wt. percent of the sorbent. The sorbent acts by capturing compounds contained in gaseous fluids via chemisorption and/or physisorption between the unit layers of the substrate's lattice where the polar amine liquids and solids and/or polar ether liquids and solids are located. The method eliminates the need for high surface area supports and polymeric materials for the preparation of CO.sub.2 capture systems, and provides sorbents with absorption capabilities that are independent of the sorbents' surface areas. The sorbents can be regenerated by heating at temperatures in excess of 35.degree. C.

  6. Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures

    SciTech Connect (OSTI)

    Sirwardane, Ranjani V.

    2005-06-21

    New low-cost CO2 sorbents are provided that can be used in large-scale gas-solid processes. A new method is provided for making these sorbents that involves treating substrates with an amine and/or an ether so that the amine and/or ether comprise at least 50 wt. percent of the sorbent. The sorbent acts by capturing compounds contained in gaseous fluids via chemisorption and/or physisorption between the unit layers of the substrate's lattice where the polar amine liquids and solids and/or polar ether liquids and solids are located. The method eliminates the need for high surface area supports and polymeric materials for the preparation of CO2 capture systems, and provides sorbents with absorption capabilities that are independent of the sorbents' surface areas. The sorbents can be regenerated by heating at temperatures in excess of 35 degrees C.

  7. Method and system for capturing carbon dioxide and/or sulfur dioxide from gas stream

    DOE Patents [OSTI]

    Chang, Shih-Ger; Li, Yang; Zhao, Xinglei

    2014-07-08

    The present invention provides a system for capturing CO.sub.2 and/or SO.sub.2, comprising: (a) a CO.sub.2 and/or SO.sub.2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO.sub.2 and/or SO.sub.2 to produce a CO.sub.2- and/or SO.sub.2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO.sub.2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO.sub.2 gas. The present invention also provides for a system for capturing SO.sub.2, comprising: (a) a SO.sub.2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO.sub.2 to produce an alkali metal sulfite/sulfate precipitate and CO.sub.2.

  8. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2003-01-01

    For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating

  9. Exergoeconomic analysis of a refinery`s utilities plant: Part II-improvement proposals

    SciTech Connect (OSTI)

    Rivero, R.; Hernandez, R.

    1996-12-31

    A crude oil refinery normally consumes a large amount of energy, not only in the form of the combustion of fossil fuels in the process units, but also in the associated Utilities Plant which produces process steam at different pressure levels and electricity. Energy losses of the utilities plant represent some 40 % of the total refinery`s energy losses. It is then extremely important to evaluate the performance of this plant and the costs to be assigned to the production of steam and electricity as a supplier of energy to the process units. This paper presents the improvement proposals generated by the application of an exergoeconomic analysis to the Utilities Plant of an existing 150,000 BPD crude oil refinery. 2 refs., 7 figs.

  10. Preparation of sorbent pellets with high integrity for sorption of CO.sub.2 from gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    2016-05-10

    Method for the production of a CO.sub.2 sorbent prepared by integrating a clay substrate, basic alkali salt, amine liquid, hydraulic binder, and a liquid binder. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay substrate and basic alkali salt may be combined in a solid-solid heterogeneous mixture and followed by introduction of the amine liquid. Alternatively, an alkaline solution may be blended with the amine solution prior to contacting the clay substrate. The clay-alkali-amine CO.sub.2 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a CO.sub.2 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air.

  11. Silver-Mordenite for Radiologic Gas Capture from Complex Streams: Dual Catalytic CH3I Decomposition and I Confinement

    SciTech Connect (OSTI)

    Tina M. Nenoff; Mark Rodriguez; Nick Soelberg; Karena W. Chapman

    2014-12-01

    The effective capture and storage of radiological iodine (129I) remains a strong concern for safe nuclear waste storage and safe nuclear energy. Silver-containing mordenite (MOR) is a longstanding benchmark for iodine capture. In nuclear fuel reprocessing scenarios, complex gas streams will be present and the need for high selectivity of all iodine containing compounds is of the utmost importance for safety and the environment. In particular, a molecular level understanding of the sorption of organic iodine compounds is not well understood. Here we probe the structure and distribution of methyl iodide sorbed by silver-containing MOR using a combination of crystallographic and materials characterization techniques including: infrared spectroscopy, thermogravimetric analysis with mass spectrometry, Micro-X-ray Fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. The iodine is captured inside the MOR pore in the form of AgI nanoparticles, that is consistent with the pores sizes of the MOR, indicating that the molecule is both physically and chemically captured in the Ag-MOR. The organic component is surface catalyzed by the zeolite via the formation of Surface Methoxy Species (SMS) that result in downstream organics of dimethyl ether and methanol formation.

  12. U.S. Refinery Net Production

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    12,813 12,516 12,287 12,009 12,148 11,916 2005-2014 Liquefied Refinery Gases 623 659 619 630 623 653 2005-2014 EthaneEthylene 19 20 20 18 7 6 2005-2014 Ethane 14 14 14 13 7 5...

  13. Refinery siting workbook: appendices C to O

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

  14. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  15. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  16. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  17. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  18. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1993-01-04

    Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

  19. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1993-01-04

    Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

  20. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1992-06-10

    Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

  1. Process studies for a new method of removing H/sub 2/S from industrial gas streams

    SciTech Connect (OSTI)

    Neumann, D.W.; Lynn, S.

    1986-07-01

    A process for the removal of hydrogen sulfide from coal-derived gas streams has been developed. The basis for the process is the absorption of H/sub 2/S into a polar organic solvent where it is reacted with dissolved sulfur dioxide to form elemental sulfur. After sulfur is crystallized from solution, the solvent is stripped to remove dissolved gases and water formed by the reaction. The SO/sub 2/ is generated by burning a portion of the sulfur in a furnace where the heat of combustion is used to generate high pressure steam. The SO/sub 2/ is absorbed into part of the lean solvent to form the solution necessary for the first step. The kinetics of the reaction between H/sub 2/S and SO/sub 2/ dissolved in mixtures of N,N-Dimethylaniline (DMA)/ Diethylene Glycol Monomethyl Ether and DMA/Triethylene Glycol Dimethyl Ether was studied by following the temperature rise in an adiabatic calorimeter. This irreversible reaction was found to be first-order in both H/sub 2/S and SO/sub 2/, with an approximates heat of reaction of 28 kcal/mole of SO/sub 2/. The sole products of the reaction appear to be elemental sulfur and water. The presence of DMA increases the value of the second-order rate constant by an order of magnitude over that obtained in the glycol ethers alone. Addition of other tertiary aromatic amines enhances the observed kinetics; heterocyclic amines (e.g., pyridine derivatives) have been found to be 10 to 100 times more effective as catalysts when compared to DMA.

  2. U.S. Refinery & Blender Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 545,351 529,373 583,548 564,902 593,799 590,222 1981-2016 Crude Oil 495,806 460,629 499,255 478,254 504,549 492,960 1981-2016 Natural Gas Plant Liquids and Liquefied Refinery Gases 20,717 16,455 15,101 13,489 13,196 12,892 1981-2016 Pentanes Plus 4,878 3,963 4,345 4,213 4,959 4,630 1981-2016 Liquefied Petroleum Gases 15,839 12,492 10,756 9,276 8,237 8,262 1981-2016 Ethane 1981-1992 Normal Butane 9,502 6,776 4,226 2,929 1,957 1,967

  3. U.S. Refinery & Blender Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 6,345,372 6,422,710 6,406,693 6,577,077 6,779,342 6,882,105 1981-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 5,915,532 1981-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 161,479 178,884 186,270 181,112 186,601 188,270 1981-2015 Pentanes Plus 56,686 63,385 63,596 60,394 56,037 53,404 1981-2015 Liquefied Petroleum Gases 104,793 115,499 122,674 120,718 130,564 134,866 1981-2015 Ethane 1981-1992 Normal Butane 43,802

  4. U.S. Refineries Competitive Positions

    U.S. Energy Information Administration (EIA) Indexed Site

    Refineries Competitive Positions 2014 EIA Energy Conference July 14, 2014 Joanne Shore American Fuel & Petrochemical Manufacturers Refiners competitive positions Function of optimizing feedstock costs, operating costs, and revenues through mix of products sold 2 Propane/butane Chemicals Gasoline Jet Fuel Diesel/heating oil Lubes Fuel for ships Asphalt FEEDSTOCKS Qualities: - Heavy/Light - Sweet/Sour Location (Distance) - Domestic - International PROCESSING Size Complexity Treating (sulfur)

  5. Opportunities for Biorenewables in Oil Refineries

    SciTech Connect (OSTI)

    Marker, T.L.

    2005-12-19

    Abstract: The purpose of this study was to evaluate the potential for using biorenewable feedstocks in oil refineries. Economic analyses were conducted, with support from process modeling and proof of principle experiments, to assess a variety of potential processes and configurations. The study considered two primary alternatives: the production of biodiesel and green diesel from vegetable oils and greases and opportunities for utilization of pyrolysis oil. The study identified a number of promising opportunities for biorenewables in existing or new refining operations.

  6. Ranking environmental liabilities at a petroleum refinery

    SciTech Connect (OSTI)

    Lupo, M.

    1995-12-31

    A new computer model is available to allow the management of a petroleum refinery to prioritize environmental action and construct a holistic approach to remediation. A large refinery may have numerous solid waste management units regulated by the Resource Conservation and Recovery Act (RCRA), as well as process units that emit hazardous chemicals into the environment. These sources can impact several environmental media, potentially including the air, the soil, the groundwater, the unsaturated zone water, and surface water. The number of chemicals of concern may be large. The new model is able to rank the sources by considering the impact of each chemical in each medium from each source in terms of concentration, release rate, and a weighted index based on toxicity. In addition to environmental impact, the sources can be ranked in three other ways: (1) by cost to remediate, (2) by environmental risk reduction caused by the remediation in terms of the decreases in release rate, concentration, and weighted index, and (3) by cost-benefit, which is the environmental risk reduction for each source divided by the cost of the remedy. Ranking each unit in the refinery allows management to use its limited environmental resources in a pro-active strategic manner that produces long-term results, rather than in reactive, narrowly focused, costly, regulatory-driven campaigns that produce only short-term results.

  7. Economic impact analysis for the petroleum refineries NESHAP. Final report

    SciTech Connect (OSTI)

    1995-08-01

    An economic analysis of the industries affected by the Petroleum Refineries National Emmissions Standard for Hazardous Air Pollutants (NESHAP) was completed in support of this standard. The industry for which economic impacts was computed was the petroleum refinery industry. Affected refineries must reduce HAP emissions by the level of control required in the standard. Several types of economic impacts, among them price product changes, output changes, job impacts, and effects on foriegn trade, were computed for the selected regulatory alternative.

  8. Integrating NABC bio-oil intermediates into the petroleum refinery |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Integrating NABC bio-oil intermediates into the petroleum refinery Integrating NABC bio-oil intermediates into the petroleum refinery Breakout Session 2: Frontiers and Horizons Session 2-D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Thomas Foust, Director, National Bioenergy Center, National Renewable Energy Laboratory biomass13_foust_2-d.pdf (713.06 KB) More Documents & Publications NABC Webinar Opportunities for Biomass-Based Fuels

  9. Texas Number and Capacity of Petroleum Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Idle 58,500 105,089 373,750 0 42,000 0 1982-2016 Operable (Barrels per Stream Day) ... Downstream Charge Capacity (Barrels per Stream Day) Vacuum Distillation 2,384,900 ...

  10. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    SciTech Connect (OSTI)

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

  11. Market Assessment of Refinery Outages Planned for October 2010...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    average values for 2002-2009 excluding months in 2005, 2006, and 2008 affected by hurricanes & refinery closures. Similarly, typical historical values are average planned...

  12. Refinery Outages: First-Half 2016

    U.S. Energy Information Administration (EIA) Indexed Site

    Outages: First-Half 2016 March 2016 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Refinery Outages: First-Half 2016 i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States

  13. Vanadium removal from petroleum refinery wastewater

    SciTech Connect (OSTI)

    Nurdogan, Y.; Meyer, C.L.

    1996-11-01

    Although a numerical effluent limit has not been proposed for vanadium, San Francisco Bay Area refineries have been investigating reasonable source control and treatment measures to limit the discharge of vanadium as part of their National Pollution Discharge Elimination System (NPDES) permit requirements because vanadium may contribute to aquatic toxicity. The NPDES permit issued for the Shell Martinez Manufacturing Complex (MMC) by the Regional Water Quality Control Board (CRWQCB) required that in the investigation of control strategies for vanadium, consideration must be given to source control measures that would reduce the discharge to the extent practicable. This paper summarizes the results of bench- and pilot-scale studies to remove vanadium from process effluent of the Shell MMC. This study has resulted in the following conclusions: vanadium in the Shell MMC refinery wastewater is generated by two major sources--the Flexicoker and Stretford processes; ferric and ferrous salts are both effective in removing vanadium from wastewaters; there are tradeoffs between the initial vanadium concentration, the final pH, and the final dissolved vanadium concentration, for both ferrous and ferric reagents; recycle of iron hydroxide sludge can reduce the amount of reagent needed to attain a given vanadium concentration; other things being equal, less ferric than ferrous reagent is required to produce the same removal of vanadium; the dewatered sludge from the pilot plant was tested for its hazardous waste characteristics; a high pH sludge regeneration and reuse process appears to be a promising method of cleaning up the hazardous iron sludge.

  14. Carbon nanocomposite sorbent and methods of using the same for separation of one or more materials from a gas stream

    DOE Patents [OSTI]

    Olson, Edwin S; Pavlish, John H

    2015-04-21

    The present invention relates to carbon nanocomposite sorbents. The present invention provides carbon nanocomposite sorbents, methods for making the same, and methods for separation of a pollutant from a gas that includes that pollutant. Various embodiments provide a method for reducing the mercury content of a mercury-containing gas.

  15. U.S. Refinery Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 337,235 321,406 357,855 343,444 362,961 360,498 2005-2016 Liquefied Refinery Gases 10,719 12,130 20,317 24,640 27,574 26,382 2005-2016 Ethane/Ethylene 165 114 141 146 170 25 2005-2016 Ethane 142 96 120 130 139 8 2005-2016 Ethylene 23 18 21 16 31 17 2005-2016 Propane/Propylene 17,998 16,402 18,157 17,729 18,884 17,690 2005-2016 Propane 8,571 8,208 9,095 9,011 10,066 9,549 2005-2016 Propylene 9,427 8,194 9,062 8,718 8,818 8,141 2005-2016

  16. Saber's heavy oil cracking refinery project

    SciTech Connect (OSTI)

    Benefield, C.S.; Glasscock, W.L.

    1983-03-01

    Perhaps more than any other industry, petroleum refining has been subjected to the radical swings in business and political climates of the past several decades. Because of the huge investments and long lead times to construct refining facilities, stable government policies, predictable petroleum prices, secure feedstock supplies and markets, and reliable cost estimates are necessary ingredients to effectively plan new refinery projects. However, over the past ten years the political and economic climates have provided anything but these conditions. Yet, refiners have demonstrated a willingness to undertake risks by continuing to expand and modernize their refineries. The refining business -- just as most businesses -- responds to economic incentives. These incentives, when present, result in new technology and capacity additions. In the 1940's, significant technology advances were commercialized to refine higher-octane motor gasolines. Such processes as continuous catalytic cracking (Houdry Process Corporation), fluid catalytic cracking (Standard Oil Development Company), HF alkylation (UOP and Phillips Petroleum Company), and catalytic reforming (UOP) began to supply a growing gasoline market, generated from the war effort and the ever increasing numbers of automobiles on the road. The post-war economy of the 1950's and 1960's further escalated demand for refined products, products which had to meet higher performance specifications and be produced from a wider range of raw materials. The refining industry met the challenge by introducing hydro-processing technology, such as hydrocracking developed in 1960. But, the era must be characterized by the large crude processing capacity additions, required to meet demand from the rapidly expanding U.S. economy. In 1950, refining capacity was 6.2 million BPD. By 1970, capacity had grown to 11.9 million BPD, an increase of 91%.

  17. Regulatory impact analysis for the petroleum refineries neshap. Draft report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The report analyzes the regulatory impacts of the Petroleum Refinery National Emission Standard for Hazardous Air Pollutants (NESHAP), which is being promulgated under Section 112 of the Clean Air Act Amendments of 1990 (CCA). This emission standard would regulate the emissions of certain hazardous air pollutants (HAPs) from petroleum refineries. The petroleum refineries industry group includes any facility engaged in the production of motor gasoline, naphthas, kerosene, jet fuels, distillate fuel oils, residual fuel oils, lubricants, or other products made from crude oil or unfinished petroleum derivatives. The report analyzes the impact that regulatory action is likely to have on the petroleum refining industry.

  18. Fuel-cell engine stream conditioning system

    DOE Patents [OSTI]

    DuBose, Ronald Arthur

    2002-01-01

    A stream conditioning system for a fuel cell gas management system or fuel cell engine. The stream conditioning system manages species potential in at least one fuel cell reactant stream. A species transfer device is located in the path of at least one reactant stream of a fuel cell's inlet or outlet, which transfer device conditions that stream to improve the efficiency of the fuel cell. The species transfer device incorporates an exchange media and a sorbent. The fuel cell gas management system can include a cathode loop with the stream conditioning system transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell related to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

  19. Effective Fouling Minimization Increases the Efficiency and Productivity of Refineries

    Broader source: Energy.gov [DOE]

    This factsheet details a project to improve operating procedures, including physical and chemical methods and the use of high-temperature coatings, to allow refineries to operate equipment below threshold fouling conditions and use the most effective minimization techniques.

  20. World Energy Projection System Plus Model Documentation: Refinery Model

    Reports and Publications (EIA)

    2016-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  1. World Energy Projection System Plus Model Documentation: Refinery Model

    Reports and Publications (EIA)

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  2. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA...

    Office of Scientific and Technical Information (OSTI)

    The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The ...

  3. Dry scrubber reduces SO sub 2 in calciner flue gas

    SciTech Connect (OSTI)

    Brown, G.W. ); Roderick, D. ); Nastri, A. )

    1991-02-18

    This paper discusses the installation of a dry sulfur dioxide scrubber for an existing petroleum coke calciner at its Fruita, Colo., refinery. The dry scrubbing process was developed by the power industry to help cope with the acid rain problem. It is the first application of the process in an oil refinery. The process could also remove SO{sub 2} from the flue gas of a fluid catalytic cracker, fluid coker, or other refinery sources.

  4. DOE - Office of Legacy Management -- International Rare Metals Refinery Inc

    Office of Legacy Management (LM)

    - NY 38 Rare Metals Refinery Inc - NY 38 Site ID (CSD Index Number): NY.38 Site Name: International Rare Metals Refinery, Inc. Site Summary: Site Link: External Site Link: Alternate Name(s): Canadian Radium and Uranium Corporation Alternate Name Documents: NY.38-1 Location: 69 Kisco Avenue, Mt. Kisco, New York Location Documents: NY.38-1 NY.38-3 Historical Operations (describe contaminants): Manufactured and distributed radium and polonium products. Historical Operations Documents: NY.38-5

  5. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis; Harvey, III, Albert Destrehan; Vinegar, Harold J.

    2012-04-03

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  6. Streaming Canvas

    Energy Science and Technology Software Center (OSTI)

    2015-05-14

    Streaming Canvas is an interactive data visualization tool for high dimensional data such as text documents. It allows the user to interactively analyze documents.

  7. U.S. Refinery Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 4,568,301 4,484,600 4,395,128 4,433,893 4,349,316 4,273,291 2005-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 223,448 2005-2015 Ethane/Ethylene 7,228 7,148 6,597 2,626 2,038 2,134 2005-2015 Ethane 5,200 5,105 4,835 2,439 1,777 1,835 2005-2015 Ethylene 2,028 2,043 1,762 187 261 299 2005-2015 Propane/Propylene 204,223 201,492 202,309 206,038 214,378 203,954 2005-2015 Propane 102,913 98,508 100,933 103,568 111,813 103,253

  8. Finished Motor Gasoline Refinery, Bulk Terminal, and Natural Gas Plant

    U.S. Energy Information Administration (EIA) Indexed Site

    Stocks Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S. 18,525 19,638 17,733 17,607 17,525 17,252 1993-2016 PAD District 1 2,242 2,546 1,550 1,573 1,593 1,969 1993-2016 Connecticut 1993-2005 Delaware 1993-2010 Florida 926 877 835 853 781 998 1993-2016 Georgia 175 221 158 163 190 268 1993-2016 Maine 1993-2014 Maryland 1993-2009 Massachusetts 4 4 4 4 6 8 1993-2016 New Hampshire 1993-2006 New Jersey 534 804 23 60 98 16 1993-2016 New York 14 23 18 11 25 16 1993-2016 North Carolina 170

  9. Pennsylvania Supplemental Supplies of Natural Gas

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    205 4 2 2 3 20 1967-2014 Synthetic 0 0 1980-2014 Propane-Air 205 4 2 2 3 20 1980-2014 Refinery Gas 1980-2005

  10. Massachusetts Supplemental Supplies of Natural Gas

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    0 * 0 * 3 8 1967-2014 Synthetic 0 1980-2014 Propane-Air 10 0 0 3 8 1980-2014 Refinery Gas 1980-2005 Other 0 2005

  11. Maryland Supplemental Supplies of Natural Gas

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    70 115 89 116 107 809 1967-2014 Synthetic 0 0 1980-2014 Propane-Air 170 115 89 116 107 809 1980-2014 Refinery Gas 1980-2005 Other 0 0 1980

  12. Pennsylvania Supplemental Supplies of Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    205 4 2 2 3 20 1967-2014 Synthetic 0 0 1980-2014 Propane-Air 205 4 2 2 3 20 1980-2014 Refinery Gas 1980-2005

  13. Maryland Supplemental Supplies of Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    70 115 89 116 107 809 1967-2014 Synthetic 0 0 1980-2014 Propane-Air 170 115 89 116 107 809 1980-2014 Refinery Gas 1980-2005 Other 0 0 1980

  14. Massachusetts Supplemental Supplies of Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    0 * 0 * 3 8 1967-2014 Synthetic 0 1980-2014 Propane-Air 10 0 0 3 8 1980-2014 Refinery Gas 1980-2005 Other 0 2005

  15. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2001-07-31

    Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H2 separation. These membranes consist of a thin ({approx}1 mm) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd{sub 60}Cu{sub 40} films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H2 separation, and resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd{sub 60}Cu{sub 4}0 alloy membranes on porous supports for H{sub 2} separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H{sub 2} flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H{sub 2} flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.

  16. Novel sorbent development and evaluation for the capture of krypton and xenon from nuclear fuel reprocessing off-gas stream

    SciTech Connect (OSTI)

    Garn, T.G.; Greenhalgh, M.R.; Law, J.D.

    2013-07-01

    The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, Idaho National Laboratory sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up. (authors)

  17. Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams

    SciTech Connect (OSTI)

    Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

    2013-10-01

    The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.

  18. Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams

    SciTech Connect (OSTI)

    Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

    2013-09-01

    The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.

  19. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  20. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  1. A Literature Survey to Identify Potentially Volatile Iodine-Bearing Species Present in Off-Gas Streams

    SciTech Connect (OSTI)

    Bruffey, S. H.; Spencer, B. B.; Strachan, D. M.; Jubin, R. T.; Soelberg, N. R.; Riley, B. J.

    2015-06-30

    Four radionuclides have been identified as being sufficiently volatile in the reprocessing of nuclear fuel that their gaseous release needs to be controlled to meet regulatory requirements (Jubin et al. 2011, 2012). These radionuclides are 3H, 14C, 85Kr, and 129I. Of these, 129I has the longest half-life and potentially high biological impact. Accordingly, control of the release of 129I is most critical with respect to the regulations for the release of radioactive material in stack emissions. It is estimated that current EPA regulations (EPA 2010) would require any reprocessing plant in the United States to limit 129I release to less than 0.05 Ci/MTIHM for a typical fuel burnup of 55 gigawatt days per metric tonne (GWd/t) (Jubin 2011). The study of inorganic iodide in off-gas systems has been almost exclusively limited to I2 and the focus of organic iodide studies has been CH3I. In this document, we provide the results of an examination of publically available literature that is relevant to the presence and sources of both inorganic and organic iodine-bearing species in reprocessing plants. We especially focus on those that have the potential to be poorly sequestered with traditional capture methodologies. Based on the results of the literature survey and some limited thermodynamic modeling, the inorganic iodine species hypoiodous acid (HOI) and iodine monochloride (ICl) were identified as potentially low-sorbing iodine species that could present in off-gas systems. Organic species of interest included both short chain alkyl iodides such as methyl iodide (CH3I) and longer alkyl iodides up to iodododecane (C10H21I). It was found that fuel dissolution may provide conditions conducive to HOI formation and has been shown to result in volatile long-chain alkyl iodides, though these may not volatilize until later in the reprocessing sequence. Solvent extraction processes were found to be significant sources of various organic iodine-bearing species; formation of these

  2. Olefin Recovery from Chemical Industry Waste Streams

    SciTech Connect (OSTI)

    A.R. Da Costa; R. Daniels; A. Jariwala; Z. He; A. Morisato; I. Pinnau; J.G. Wijmans

    2003-11-21

    The objective of this project was to develop a membrane process to separate olefins from paraffins in waste gas streams as an alternative to flaring or distillation. Flaring these streams wastes their chemical feedstock value; distillation is energy and capital cost intensive, particularly for small waste streams.

  3. EIA-820, Annual Refinery Report Page 1 U. S. ENERGY INFORMATION...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crude oil that first traveled 5,000 miles by tanker and then traveled 105 miles by pipeline to the refinery, report pipeline as the method of transportation. * If the refinery...

  4. Alternative multimedia regulatory programs for next-generation refineries

    SciTech Connect (OSTI)

    Elcock, D.; Gasper, J.; Arguerro, R.; Emerson, D.

    2000-06-22

    The 25-year-old command-and-control environmental regulatory structure in the US has resulted in significant environmental improvements. Recently, however, its limitations (e.g., rigid application regardless of site-specific conditions, disregard of cross-media and multimedia impacts, limited incentives for new technology development and use) have become increasingly apparent. New regulatory approaches that recognize current and anticipated economic constraints, new knowledge of environmental processes and impacts, and the benefits of new technologies are needed. Such approaches could be especially important for the US petroleum refining industry. This industry operates under thin profit margins, releases chemicals that can produce adverse health and environmental impacts, and must meet the technological challenges of producing more highly refined fuels from poorer quality feedstocks. Under a grant from the Environmental Technology Initiative (ETI), Argonne National Laboratory and its subcontractor, Analytical Services, Inc. developed two alternative environmental regulatory programs for next-generation petroleum refineries. (In this report, next-generation refineries refers to the refineries of today as they operate in the next 20 or more years rather than to fully reengineered future refineries.) The objective of the ETI refinery project was to develop future-oriented regulatory programs for next-generation refineries that will expand the use of innovative technologies, encourage pollution prevention, demonstrate environmental responsibility, and maintain refinery economic performance. Rather than suggesting targeted, short-term modifications to existing media-specific command-and-control regulations, the ETI project suggests the use of new approaches that are broader and more flexible. It recognizes that giving refineries flexibility in meeting environmental protection goals can stimulate new technology development and use. Unlike most US Environmental

  5. Mazheikiai refinery modernization study. Executive summary. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. The volume contains the Executive Summary.

  6. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  7. Monitoring near refineries or airborne chemicals on the SARA Title 3 section 313 list

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    In this volume, detailed procedures recommended for the measurement of selected petroleum refinery emissions in ambient air are presented.

  8. Monitoring near refineries or airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This volume identifies publications and databases that address ambient air concentrations measured near petroleum refineries for the selected target chemicals.

  9. Monitoring near refineries for airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This study provides an ambient air concentration perspective to the engineering estimates of petroleum refinery emissions required under SARA Title III Section 313. It presents and discusses ambient air concentrations of 25 selected target chemicals measured at and near the perimeter (fenceline) of three refineries. Measurements were made over three consecutive 24-hour sampling periods at each refinery. The extent to which the concentrations of the target chemicals were due to fugitive emissions from the refineries is estimated.

  10. Regulatory impact analysis for the petroleum refineries NESHAP. Final report

    SciTech Connect (OSTI)

    1995-08-01

    A regulatory impact analysis (RIA) of the industries affected by the Petroleum Refineries National Emissions Standard for Hazardous Air Pollutants (NESHAP) was completed in support of this regulation. This (RIA) was required because the proposal is economically significant according to Executive Order 12866. The industry for which these impacts was computed was the petroleum refinery industry. Several different impact analyses were included in total or summarized in different chapters in the document. Those analyses were: the compliance cost analysis, the economic impact analysis, and the benefits analysis. Benefits and costs were then compared and discussed in the document`s last chapter.

  11. Control of benzene waste NESHAP emissions from a petroleum refinery

    SciTech Connect (OSTI)

    Truelove, R.D. )

    1992-02-01

    This paper discusses the control of benzene emissions from a petroleum refinery as regulated by the National Emission Standards for Hazardous Air Pollutants (NESHAO) Subpart FF - National Standard for Benzene Waste Operations. This regulation is complex and confusing, but it provides flexibility to achieve compliance through various strategies to control benzene emissions. The first step to achieve compliance with the benzene waste NESHAP is understanding the regulation itself. Therefore, this paper summarizes the regulation to provide the reader with sufficient background to understand why specific controls are required for specific processes. The flexibility provided by the regulation to achieve compliance is not always readily apparent. This paper summarizes some of these subtleties. The author's involvement with an industry trade association in meetings with the Environmental Protection Agency during the development of the regulation allows some of EPA's expressions of their intent and internal interpretation to also be contained in the summary. The second step to achieve compliance with the benzene waste NESHAP is to actually design and operate a cost effective solution for a specific set of existing conditions within a refinery. This paper provides a case study of the equipment necessary to achieve compliance with the substantive requirements of the regulation at a large, integrated refinery. The retrofit requirements are very specific to the circumstances of this facility. Therefore, they will not be a universal, cost effective means of compliance for other refineries.

  12. Low temperature thermal treatment for petroleum refinery waste sludges

    SciTech Connect (OSTI)

    Ayen, R.J.; Swanstrom, C.P. )

    1992-05-01

    Treatment requirements for waste sludges generated by petroleum refinery operations and designated as waste codes K048, K049, K050, K051 and K052 under the Resource Conservation and Recovery Act (RCRA) became effective in November, 1990 under the Landban regulations. An experimental program evaluated low temperature thermal treatment of filter cakes produced from these sludges using laboratory and pilot-scale equipment. One set of experiments on waste samples from two different refineries demonstrated the effective removal of organics of concern from the sludges to meet the RCRA Best Demonstrated Available Technology (BDAT) treatment standards. Cyanides were also within the acceptable limit. Combined with stabilization of heavy metals in the treatment residues, low temperature thermal treatment therefore provides an effective and efficient means of treating refinery sludges, with most hydrocarbons recovered and recycled to the refinery. A milder thermal treatment was used to remove the bulk of the water from a previously filtered waste sludge, providing effective waste minimization through a 40% decrease in the mass of sludge to be disposed. The heating value of the sludge was increased simultaneously by one-third, thereby producing a residue of greater value in an alternative fuels program. A process based on this approach was successfully designed and commercialized.

  13. Energy Efficiency Roadmap for Petroleum Refineries in California

    SciTech Connect (OSTI)

    none,

    2004-04-01

    Through the California State IOF initiative, the California Energy Commission PIER Program developed a petroleum refining roadmap to identify energy issues and priorities unique to the refining industry in California and create a plan for future R&D that could help California refineries implement energy efficient technologies.

  14. Refinery Outages: Description and Potential Impact on Petroleum Product Prices

    Reports and Publications (EIA)

    2007-01-01

    This report responds to a July 13, 2006 request from Chairman Jeff Bingaman of the Senate Committee on Energy and Natural Resources requested that the Energy Information Administration conduct a study of the impact that refinery shutdowns have had on the price of oil and gasoline.

  15. Energy efficiency improvement and cost saving opportunities forpetroleum refineries

    SciTech Connect (OSTI)

    Worrell, Ernst; Galitsky, Christina

    2005-02-15

    The petroleum refining industry in the United States is the largest in the world, providing inputs to virtually any economic sector,including the transport sector and the chemical industry. The industry operates 146 refineries (as of January 2004) around the country,employing over 65,000 employees. The refining industry produces a mix of products with a total value exceeding $151 billion. Refineries spend typically 50 percent of cash operating costs (i.e., excluding capital costs and depreciation) on energy, making energy a major cost factor and also an important opportunity for cost reduction. Energy use is also a major source of emissions in the refinery industry making energy efficiency improvement an attractive opportunity to reduce emissions and operating costs. Voluntary government programs aim to assist industry to improve competitiveness through increased energy efficiency and reduced environmental impact. ENERGY STAR (R), a voluntary program managed by the U.S. Environmental Protection Agency, stresses the need for strong and strategic corporate energy management programs. ENERGY STAR provides energy management tools and strategies for successful corporate energy management programs. This Energy Guide describes research conducted to support ENERGY STAR and its work with the petroleum refining industry.This research provides information on potential energy efficiency opportunities for petroleum refineries. This Energy Guide introduces energy efficiency opportunities available for petroleum refineries. It begins with descriptions of the trends, structure, and production of the refining industry and the energy used in the refining and conversion processes. Specific energy savings for each energy efficiency measure based on case studies of plants and references to technical literature are provided. If available, typical payback periods are also listed. The Energy Guide draws upon the experiences with energy efficiency measures of petroleum refineries worldwide

  16. Gasification of refinery sludge in an updraft reactor for syngas production

    SciTech Connect (OSTI)

    Ahmed, Reem; Eldmerdash, Usama; Sinnathambi, Chandra M.

    2014-10-24

    The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H{sub 2}, CH{sub 4} compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO{sub 2}+C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm{sup −3} of, and 2.5 Nm{sup 3} kg{sup −1} respectively.

  17. Alternative future environmental regulatory approaches for petroleum refineries.

    SciTech Connect (OSTI)

    Elcock, D.; Gasper, J.; Moses, D. O.; Emerson, D.; Arguerro, R.; Environmental Assessment; DOE; Analytical Services, Inc.

    2000-01-01

    Recently, many industrial, regulatory, and community leaders have expressed concern that the current environmental regulatory structure disregards multimedia environmental impacts, provides few incentives to develop and use new technologies, and fails to consider site-specific conditions. For the US petroleum refining industry, faced with the need to produce higher-quality fuels from poorer-quality feedstocks, such criticisms are expected to increase. This article offers two alternative environmental regulatory approaches for existing petroleum refineries to use in the future. These alternative approaches are multimedia in scope, provide for new technology development and use, and allow flexibility in the means for meeting environmental goals. They have been reviewed and critiqued by various stakeholders, including industry representatives, regulators, and local and national community and environmental organizations. The integration of stakeholder comments and findings of ongoing national and international regulatory reinvention efforts in the development of these approaches positions them for potential use by other industries in addition to petroleum refineries.

  18. Congested site challenges designers of refinery IPP plant

    SciTech Connect (OSTI)

    Collins, S.

    1993-09-01

    This article describes a new IPP plant which has successfully met the challenges of an extremely congested site--including overcoming physical space constraints, meeting low air-emissions regulations, and minimizing water consumption--located next to a busy highway and near a major airport. The 650-MW Linden cogeneration plant is located on a 13.5-acre plot within the confines of Bayway Refinery Co's facility near Newark, NJ. Since starting operation one year ago, the plant has been reliably supplying steam for the refinery's process heating and mechanical drive needs and efficiently generating steam and electricity with minimal environmental impact. To achieve these goals, designers chose a combined-cycle configuration/generators, five supplementary-fired heat-recovery steam generators (HRSGs), and three 90-MW steam turbine/generators. Thus far, the facility has operated with an average availability above 90%.

  19. Martinez Refinery Completes Plant-Wide Energy Assessment

    SciTech Connect (OSTI)

    2002-11-01

    This OIT BestPractices Case Study describes how the Equilon Enterprises oil refinery in Martinez, California undertook a plant-wide energy assessment that focused on three key areas: waste minimization, process debottlenecking, and operations optimization. The assessment yielded recommendations, which, if implemented, can save more than 6,000,000 MMBtu per year and an estimated $52,000,000 per year, plus improve process control and reduce waste.

  20. Kidney cancer and hydrocarbon exposures among petroleum refinery workers

    SciTech Connect (OSTI)

    Poole, C.; Dreyer, N.A.; Satterfield, M.H.; Levin, L.

    1993-12-01

    To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

  1. Refinery & Blender Net Production of Total Finished Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Finished Petroleum Products Liquefied Refinery Gases Ethane/Ethylene Ethane Ethylene Propane/Propylene Propane Propylene Normal Butane/Butylene Normal Butane Butylene Isobutane/Isobutylene Isobutane Isobutylene Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Reformulated Other Gasoline Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Blended w/ Fuel Ethanol, Greater than

  2. Refinery Net Production of Total Finished Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Finished Petroleum Products Liquefied Refinery Gases Ethane/Ethylene Ethane Ethylene Propane/Propylene Propane Propylene Normal Butane/Butylene Normal Butane Butylene Isobutane/Isobutylene Isobutane Isobutylene Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Reformulated Other Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Blended w/ Fuel Ethanol, Greater than Ed55

  3. Renewable Fuels from Algae Boosted by NREL Refinery Process | Bioenergy |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Renewable Fuels from Algae Boosted by NREL Refinery Process February 9, 2016 A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) has proven to be significantly more effective at producing ethanol from algae than previous research. The process, dubbed Combined Algal Processing (CAP), is detailed in a new paper by NREL's Tao Dong, Eric Knoshaug, Ryan Davis, Lieve Laurens, Stefanie Van Wychen, Philip Pienkos, and Nick

  4. University of Maine Integrated Forest Product Refinery (IFPR) Technology Research

    SciTech Connect (OSTI)

    Pendse, Hemant P.

    2010-11-23

    This project supported research on science and technology that forms a basis for integrated forest product refinery for co-production of chemicals, fuels and materials using existing forest products industry infrastructure. Clear systems view of an Integrated Forest Product Refinery (IFPR) allowed development of a compelling business case for a small scale technology demonstration in Old Town ME for co-production of biofuels using cellulosic sugars along with pulp for the new owners of the facility resulting in an active project on Integrated Bio-Refinery (IBR) at the Old Town Fuel & Fiber. Work on production of advanced materials from woody biomass has led to active projects in bioplastics and carbon nanofibers. A lease for 40,000 sq. ft. high-bay space has been obtained to establish a Technology Research Center for IFPR technology validation on industrially relevant scale. UMaine forest bioproducts research initiative that began in April 2006 has led to establishment of a formal research institute beginning in March 2010.

  5. Application of x-ray imaging to oil refinery processes

    SciTech Connect (OSTI)

    Gamblin, B.R.; Newton, D.; Smith, G.B.

    1996-12-31

    X-ray imaging is a non-intrusive method of visualizing the flow patterns of rapidly changing multiphase systems and is based on the variation in the absorbance of X-rays by the different phases. BP has applied the X-ray technique to a variety of problems encountered within the oil and petrochemical industries in which two or three phases are present e.g. Fluid Catalytic Cracking (riser, stripper, regenerator) and three phase systems such as slurry bubble column reactors. In general, to obtain the maximum productivity from these units it is essential to optimize the contacting between a catalyst and a process fluid or fluids. This work reports on laboratory experimental work in which full scale refinery components were visualized in order to characterize the existing designs. Modified designs were then tested and evaluated before implementation on the refinery unit. Economic assessments of some of the benefits which can be realized in an oil refinery as a result of such design improvements are also presented. 3 refs., 1 fig.

  6. U.S. Refinery Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 4,178,588 4,091,601 4,007,375 4,037,265 3,954,862 3,894,471 2005-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 5,915,532 2005-2015 Natural Gas Plant Liquids 154,941 171,074 175,607 168,808 172,563 171,936 2005-2015 Pentanes Plus 54,697 61,059 59,432 56,153 52,853 50,850 2005-2015 Liquefied Petroleum Gases 100,244 110,015 116,175 112,655 119,710 121,086 2005-2015 Normal Butane 39,253 42,087 45,747 42,461 45,916 47,870 2005-2015

  7. Chevron: Refinery Identifies $4.4 Million in Annual Savings by Using Process Simulation Models to Perform Energy-Efficiency Assessment

    SciTech Connect (OSTI)

    2004-05-01

    In an energy-efficiency study at its refinery near Salt Lake City, Utah, Chevron focused on light hydrocarbons processing. The company found it could recover hydrocarbons from its fuel gas system and sell them. By using process simulation models of special distillation columns and associated reboilers and condensers, Chevron could predict the performance of potential equipment configuration changes and process modifications. More than 25,000 MMBtu in natural gas could be saved annually if a debutanizer upgrade project and a new saturated gas plant project were completed. Together, these projects would save $4.4 million annually.

  8. U.S. Number and Capacity of Petroleum Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    151,900 1982-2016 Operable (Barrels per Stream Day) 18,953,189 18,560,350 18,971,643 ... Downstream Charge Capacity (Barrels per Stream Day) Vacuum Distillation 8,650,243 ...

  9. U.S. Refinery Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 302,955 290,718 325,588 311,454 327,623 327,323 2005-2016 Crude Oil 495,806 460,629 499,255 478,254 504,549 492,960 2005-2016 Natural Gas Plant Liquids 18,673 14,924 13,318 12,174 12,857 12,478 2005-2016 Pentanes Plus 4,389 3,616 3,922 4,036 4,765 4,354 2005-2016 Liquefied Petroleum Gases 14,284 11,308 9,396 8,138 8,092 8,124 2005-2016 Normal Butane 7,947 5,592 2,866 1,791 1,812 1,829 2005-2016 Isobutane 6,337 5,716 6,530 6,347 6,280

  10. Table 5.9 Refinery Capacity and Utilization, 1949-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Energy Information Administration (EIA), Energy Data Reports, Petroleum Refineries in the United States, annual reports. * 1981-2005EIA, Petroleum Supply Annual (PSA), ...

  11. Initial Assessment of U.S. Refineries for Purposes of Potential...

    Office of Scientific and Technical Information (OSTI)

    U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Freeman, Charles J.; Jones, Susanne B.; Padmaperuma, Asanga B.; Santosa, Daniel M.; Valkenburg, Corinne; Shinn,...

  12. Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report discusses potential impacts of increased water temperature and reductions in water availability on petroleum refining and presents case studies related to refinery water use. Report...

  13. US DOE Refinery Water Study 01-19-16 PublicE_docx

    Office of Environmental Management (EM)

    Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature andor Reduced Water Availability Executive Summary of Final Report Prepared for US Department of ...

  14. Aspects of Holly Corporation's Acquisition of Sunoco Inc.'s Tulsa, Oklahoma Refinery

    Reports and Publications (EIA)

    2009-01-01

    The Energy Information Administration has produced a review of aspects of the Holly's acquisition of Sunoco's 85,000-barrels-per-day Tulsa refinery.

  15. Updated estimation of energy efficiencies of U.S. petroleum refineries.

    SciTech Connect (OSTI)

    Palou-Rivera, I.; Wang, M. Q.

    2010-12-08

    Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels such as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.

  16. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida; Del Paggio, Alan Anthony; Nair, Vijay; Roes, Augustinus Wilhelmus Maria

    2011-12-06

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  17. Hydrogen Selective Inorganic membranes for Gas Separations under High Pressure Intermediate Temperature Hydrocarbonic Envrionment

    SciTech Connect (OSTI)

    Rich Ciora; Paul KT Liu

    2012-06-27

    In this project, we have successfully developed a full scale commercially ready carbon molecular sieve (CMS) based membrane for applications in H{sub 2} recovery from refinery waste and other aggressive gas streams. Field tests at a refinery pilot plant and a coal gasification facility have successfully demonstrated its ability to recovery hydrogen from hydrotreating and raw syngas respectively. High purity H{sub 2} and excellent stability of the membrane permeance and selectivity were obtained in testing conducted over >500 hours at each site. The results from these field tests as well as laboratory testing conclude that the membranes can be operated at high pressures (up to 1,000 psig) and temperatures (up to 300 C) in presence of aggressive contaminants, such as sulfur and nitrogen containing species (H{sub 2}S, CO{sub 2}, NH{sub 3}, etc), condensable hydrocarbons, tar-like species, heavy metals, etc. with no observable effect on membrane performance. By comparison, similar operating conditions and/or environments would rapidly destroy competing membranes, such as polymeric, palladium, zeolitic, etc. Significant cost savings can be achieved through recovering H{sub 2} from refinery waste gas using this newly developed CMS membrane. Annual savings of $2 to 4MM/year (per 20,000 scfd of waste gas) can be realized by recovering the H{sub 2} for reuse (versus fuel). Projecting these values over the entire US market, potential H{sub 2} savings from refinery waste gases on the order of 750 to 1,000MM scfd and $750 to $1,000MM per year are possible. In addition to the cost savings, potential energy savings are projected to be ca. 150 to 220 tBTU/yr and CO{sub 2} gas emission reductions are projected to be ca. 5,000 to 6,500MMtons/year. The full scale membrane bundle developed as part of this project, i.e., 85 x 30 inch ceramic membrane tubes packaged into a full ceramic potting, is an important accomplishment. No comparable commercial scale product exists in the

  18. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    Benson, Charles; Wilson, Robert

    2014-04-30

    This project culminated in the demonstration of a full-scale industrial burner which allows a broad range of “opportunity” gaseous fuels to be cost-effectively and efficiently utilized while generating minimal emissions of criteria air pollutants. The burner is capable of maintaining a stable flame when the fuel composition changes rapidly. This enhanced stability will contribute significantly to improving the safety and reliability of burner operation in manufacturing sites. Process heating in the refining and chemicals sectors is the primary application for this burner. The refining and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion of this project, an enabling technology did not exist that would allow these energy-intensive industries to take full advantage of opportunity fuels and thereby reduce their natural gas consumption. Opportunity gaseous fuels include biogas (from animal and agricultural wastes, wastewater plants, and landfills) as well as syngas (from the gasification of biomass, municipal solid wastes, construction wastes, and refinery residuals). The primary challenge to using gaseous opportunity fuels is that their composition and combustion performance differ significantly from those of conventional fuels such as natural gas and refinery fuel gas. An effective fuel-flexible burner must accept fuels that range widely in quality and change in composition over time, often rapidly. In Phase 1 of this project, the team applied computational fluid dynamics analysis to optimize the prototype burner’s aerodynamic, combustion, heat transfer, and emissions performance. In Phase 2, full-scale testing and refinement of two prototype burners were conducted in test furnaces at Zeeco’s offices in Broken Arrow, OK. These tests demonstrated that the full range of conventional and opportunity fuels could be utilized by the project’s burner while achieving robust flame stability and very low levels of

  19. Process for the removal of acid gases from gaseous streams

    SciTech Connect (OSTI)

    Blytas, G.C.; Diaz, Z.

    1982-11-16

    Hydrogen sulfide, carbon dioxide, and carbonyl sulfide are removed from a gas stream in a staged procedure by: absorption of the CO/sub 2/ and COS; conversion of the hydrogen sulfide to produce sulfur in an absorbent mixture; hydrolysis of the carbonyl sulfide to produce a gas stream of hydrogen sulfide and carbon dioxide; and removal of the hydrogen sulfide from the gas stream.

  20. Evaluation audit report. Romanian petroleum refinery, Petrobrazi, Ploiesti. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Petrobrazi refinery which is located 12 kilometers southwest of Ploiesti, Romania. Other defined and specified goals of the study include a consideration of the refinery's operating flexibility; an evaluation of fuel switching including the use of coal as a substitute for energy supply; and an observation of the refinery's general condition and its maintenance practice for its effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and the capital requirements anticipated.

  1. Development of a Conceptual Process for Selective CO 2 Capture from Fuel Gas Streams Using [hmim][Tf 2 N] Ionic Liquid as a Physical Solvent

    SciTech Connect (OSTI)

    Basha, Omar M.; Keller, Murphy J.; Luebke, David R.; Resnik, Kevin P.; Morsi, Badie I.

    2013-06-04

    The Ionic Liquid (IL) [hmim][Tf2N] was used as a physical solvent in an Aspen Plus simulation, employing the Peng-Robinson Equation of State (P-R EOS) with Boston-Mathias (BM) alpha function and standard mixing rules, to develop a conceptual process for CO2 capture from a shifted warm fuel gas stream produced from Pittsburgh # 8 coal for a 400 MWe power plant. The physical properties of the IL, including density, viscosity, surface tension, vapor pressure and heat capacity were obtained from literature and modeled as a function of temperature. Also, available experimental solubility values for CO2, H2, H2S, CO, and CH4 in this IL were compiled and their binary interaction parameters (Δij and lij) were optimized and correlated as functions of temperature. The Span-Wager Equation-of-State EOS was also employed to generate CO2 solubilities in [hmim][Tf2N] at high pressures (up to 10 MPa) and temperatures (up to 510 K). The conceptual process developed consisted of 4 adiabatic absorbers (2.4 m ID, 30 m high) arranged in parallel and packed with Plastic Pall Rings of 0.025 m for CO2 capture; 3 flash drums arranged in series for solvent (IL) regeneration with the pressure-swing option; and a pressure-intercooling system for separating and pumping CO2 up to 153 bar to the sequestration sites. The compositions of all process streams, CO2 capture efficiency, and net power were calculated using Aspen Plus simulator. The results showed that, based on the composition of the inlet gas stream to the absorbers, 95.67 mol% of CO2 was captured and sent to sequestration sites; 99.5 mol% of H2 was separated and sent to turbines; the solvent exhibited a minimum loss of 0.31 mol%; and the net power balance of the entire system was 30.81 MW. These results indicated that [hmim][Tf2N] IL could be used as a physical

  2. Clean air amendments put big burden on refinery planners

    SciTech Connect (OSTI)

    Scherr, R.C.; Smalley, G.A. Jr.; Norman, M.E. )

    1991-06-10

    The Clean Air Act Amendments of 1990 will not only require the production of reformulated gasoline but also have significant impact on other refinery-related construction. This must be considered when developing sound planning strategy. The three titles of the Clean Air Act Amendments that will have the greatest effect on refining are: Title I: Nonattainment; Title III: Air toxics; Title V: Permitting. To understand the ramifications of these amendments, it is necessary to review the interactions of new requirements with the permitting and construction schedule shown.

  3. Economic impact analysis for the petroleum refineries NESHAP. Draft report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The purpose of this economic impact analysis (EIA) is to evaluate the effect of the control costs associated with the Petroleum Refining National Emission Standard for Hazardous Air Pollutants (NESHAP) on the behavior of the regulated petroleum refiners. The EIA was conducted based on the cost estimates for one hybrid regulatory option above the maximum achievable control technology (MACT) 'floor' (or minimum standard). This analysis compares the quantitative economic impacts of regulation to baseline industry conditions which would occur in the absence of regulation. The economic impacts of regulation are estimated for the industry, using costs which were supplied on both a national and a refinery level.

  4. Annual Energy Outlook 2015 - Appendix A

    Gasoline and Diesel Fuel Update (EIA)

    ... waste stream containing petroleum-derived plastics and ... Classification System code 22 or that have a ... to the grid. 8 Includes refinery gas and still gas. 9 ...

  5. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

  6. Falling microbead counter-flow process for separating gas mixtures

    DOE Patents [OSTI]

    Hornbostel, Marc D.; Krishnan, Gopala N.; Sanjurjo, Angel

    2015-10-27

    A method and reactor for removing a component from a gas stream is provided. In one embodiment, the method includes providing the gas stream containing the component that is to be removed and adsorbing the component out of the gas stream as the gas stream rises via microbeads of a sorbent falling down an adsorber section of a reactor.

  7. Falling microbead counter-flow process for separating gas mixtures

    DOE Patents [OSTI]

    Hornbostel, Marc D.; Krishnan, Gopala N.; Sanjurjo, Angel

    2015-07-07

    A method and reactor for removing a component from a gas stream is provided. In one embodiment, the method includes providing the gas stream containing the component that is to be removed and adsorbing the component out of the gas stream as the gas stream rises via microbeads of a sorbent falling down an adsorber section of a reactor.

  8. Biodegradation of oil refinery wastes under OPA and CERCLA

    SciTech Connect (OSTI)

    Gamblin, W.W.; Banipal, B.S.; Myers, J.M.

    1995-12-31

    Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).

  9. Short-Term Energy Outlook Model Documentation: Hydrocarbon Gas Liquids Supply and Demand

    Reports and Publications (EIA)

    2015-01-01

    The hydrocarbon gas liquids (ethane, propane, butanes, and natural gasoline) module of the Short-Term Energy Outlook (STEO) model is designed to provide forecasts of U.S. production, consumption, refinery inputs, net imports, and inventories.

  10. Gas venting system

    DOE Patents [OSTI]

    Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

    2010-06-29

    A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

  11. Methods of hydrotreating a liquid stream to remove clogging compounds

    DOE Patents [OSTI]

    Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

    2009-09-22

    A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

  12. Hydrogen Production: Natural Gas Reforming | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas Reforming Hydrogen Production: Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon the existing natural gas pipeline delivery infrastructure. Today, 95% of the hydrogen produced in the United States is made by natural gas reforming in large central plants. This is an important technology pathway for near-term hydrogen production. How Does It Work? Natural gas contains methane (CH4) that can be used to

  13. East Coast (PADD 1) Number and Capacity of Petroleum Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Idle 412,500 178,000 28,000 28,000 32,000 32,000 1982-2016 Operable (Barrels per Stream ... Downstream Charge Capacity (Barrels per Stream Day) Vacuum Distillation 677,900 560,400 ...

  14. Electricity Shortage in California: Issues for Petroleum and Natural Gas Supply

    Gasoline and Diesel Fuel Update (EIA)

    Electricity Shortage in California: Issues for Petroleum and Natural Gas Supply 1. Summary 2. Electricity Reliability Issues in California 3. Petroleum Refineries 4. Constraints Outside the Refinery Gate 5. Petroleum Product Prices and Supply Disruptions 6. Natural Gas 7. End Notes 8. Contacts 1. Summary Industry electric reliability organizations, the California Energy Commission, and the California Independent System Operator, expect California to be subject to rotating electricity outages in

  15. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 579,640 560,048 615,821 596,893 629,128 623,399 1981-2016 Liquefied Refinery Gases 10,719 12,130 20,317 24,640 27,574 26,382 1981-2016 Ethane/Ethylene 165 114 141 146 170 25 1981-2016 Ethane 142 96 120 130 139 8 1993-2016 Ethylene 23 18 21 16 31 17 1993-2016 Propane/Propylene 17,998 16,402 18,157 17,729 18,884 17,690 1981-2016 Propane 8,571 8,208 9,095 9,011 10,066 9,549 1995-2016 Propylene 9,427 8,194 9,062 8,718 8,818 8,141 1993-2016

  16. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 18,452 18,673 18,564 19,106 19,654 19,893 1983-2015 Liquefied Refinery Gases 659 619 630 623 653 612 1984-2015 Ethane/Ethylene 20 20 18 7 6 6 1985-2015 Ethane 14 14 13 7 5 5 1993-2015 Ethylene 6 6 5 1 1 1 1993-2015 Propane/Propylene 560 552 553 564 587 559 1985-2015 Propane 282 270 276 284 306 283 2004-2015 Propylene 278 282 277 281 281 276 1993-2015 Normal Butane/Butylene 83 48 56 57 70 55 1985-2015 Normal Butane 88 53 63 64 76 64 1993-2015

  17. Opportunities for Biomass-Based Fuels and Products in a Refinery |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Opportunities for Biomass-Based Fuels and Products in a Refinery Opportunities for Biomass-Based Fuels and Products in a Refinery Breakout Session 2: Frontiers and Horizons Session 2-D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Corinne Valkenburg, Staff Engineer, Pacific Northwest National Laboratory biomass13_male_2-d.pdf (891.45 KB) More Documents & Publications FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds 2013

  18. Improved oil refinery operations and cheaper crude oil to help reduce gasoline prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Improved oil refinery operations and cheaper crude oil to help reduce gasoline prices U.S. gasoline prices are expected to fall as more oil refineries come back on line and crude oil prices decline. In its new monthly forecast, the U.S. Energy Information Administration expects pump prices will average $3.38 a gallon during the second half of this year. That's down from the current weekly price of $3.50. A recovery in oil refinery fuel production, particularly from facilities that were temporary

  19. Integrated vacuum absorption steam cycle gas separation

    SciTech Connect (OSTI)

    Chen, Shiaguo; Lu, Yonggi; Rostam-Abadi, Massoud

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  20. Biofacts: Fueling a stronger economy. Renewable fuel solutions for petroleum refineries

    SciTech Connect (OSTI)

    1995-07-01

    The DOE Biofuels Program is investigating processes to condition synthesis gas (syngas) produced from the gasification of biomass, coke, waste oils, and other inexpensive feedstocks and low-cost by-products. Syngas technologies offer refiners economical, flexible solutions to the challenges presented by today`s market forces and regulatory environment, such as: increasingly stringent environmental regulations that dictate the composition of petroleum products; increasingly sour crudes; increased coke production and hydrogen use resulting from heavier crude; increased disposal cost for coke and residuals oils; and decreasing hydrogen supply resulting from decreased catalytic reforming severity--a necessity to comply with requirements for reduced aromatic content. Most importantly, refiners can use the DOE syngas processes to upgrade refinery residuals and coke, which minimizes environmental problems and maximizes profitability. DOE`s solution also offers refiners the flexibility to economically supplement petroleum feedstocks with a wide variety of locally available renewable feedstocks that can be fed into the gasifier--feedstocks such as energy crops, municipal solid wastes, many industrial wastes, and agricultural by-products.

  1. Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra; Kumar, Ravi; Mehlman, Stewart

    2010-06-21

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

  2. Valero: Houston Refinery Uses Plant-Wide Assessment to Develop an Energy Optimization and Management System

    SciTech Connect (OSTI)

    2005-08-01

    This Industrial Technologies Program case study describes an energy assessment team's recommendations for saving $5 million in energy, water, and other costs at an oil refinery in Houston, Texas.

  3. Waste minimization and recycling of listed hazardous wastes in petroleum refineries

    SciTech Connect (OSTI)

    Koopersmith, C.A.

    1995-09-01

    Refiners have many options available to optimize hazardous waste programs. The Scalfuel{trademark} process is one such program for effectively transforming various types of refinery oily sludges into a high solids content, high Btu, low water content waste-derived fuel. This waste-derived fuel is widely accepted by permitted cement kilns. Five hundred thirty four truckloads from eight refineries have been successfully recycled at seven different cement kilns.

  4. Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets

    Gasoline and Diesel Fuel Update (EIA)

    .PDF 1. TABLE1.PDF Table 1. U.S. Supply, Disposition, and Ending Stocks of Crude Oil and Petroleum Products, January 2014 (Thousand Barrels) Commodity Supply Disposition Ending Stocks Field Production Renewable Fuels and Oxygenate Plant Net Production Refinery and Blender Net Production Imports Adjust- ments 1 Stock Change 2 Refinery and Blender Net Inputs Exports Products Supplied 3 Crude Oil 4 ............................................................ 248,959 - - - - 235,269 8,443 10,330

  5. Evaluation audit report. Bulgarian petroleum refinery, Neftochim, Bourgas. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Adams, N.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Neftochim refinery in Bourgas, Bulgaria. Other defined and specified goals include a consideration of refinery operating flexibility, an observation of the plants general condition, and comments on maintenance practices for their effect on operations. It is a further objective to characterize modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated. The report details the results of an Evaluation and Audit Study performed on selected process units. The conclusions of the study are a series of recommendations.

  6. Evaluation audit report. Czechoslovakian petroleum refinery, Slovnaft, Bratislava. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Slovnaft refinery in Bratislava, Czechoslovakia. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. It is a further objective to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  7. Evaluation audit report. Polish petroleum refinery, Plock, Poland. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and the reduction of emissions for the Mazovian refinery in Plock, Poland. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of their maintenance practices with their effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of the effort and the capital requirements anticipated.

  8. Evaluation audit report. Polish petroleum refinery, Gdansk, Poland. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    The primary objective of the report is to present opportunities for energy improvement and reduction of emissions for the Gdansk Refinery. A secondary objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated. Other goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching, including the use of coal as a substitute energy supply, and an observation of the plant's general condition and of its maintenance practices for their effect on operations.

  9. Evaluation audit report. Czechoslovakian petroleum refinery, Chemopetrol, Litvinov. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Chemopetrol Refinery in Litvinov, CSFR. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, an observation of the plants' general condition and the effect of its maintenance practice on operations. It is a further objective to characterize modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  10. Evaluation audit report. Romanian petroleum refinery, Petrotel, Ploiesti. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Petrotel Refinery in Brazi near Ploiesti, Romania. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching opportunities, including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  11. Evaluation audit report. Czechoslovakian petroleum refinery, Kaucuk, Kralupy. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Kaucuk refinery in Kralupy, Czechoslovakia. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. It is a further objective to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  12. Emission factors for leaks in refinery components in heavy liquid service

    SciTech Connect (OSTI)

    Taback, H.; Godec, M.

    1996-12-31

    The objective of this program was to provide sufficient screening data so that EPA can develop an official set of emission factors (expressed in lb/hr/component) for refinery components (valves, flanged connectors, non-flanged connectors, pumps, open-ended lines, and other) in heavy liquid (BL) service. To accomplish this, 211,000 existing HL screening values from Southern California refineries were compiled and compared with 2,500 new HL screening measurements taken at two refineries in the state of Washington. Since Southern California is an area in extreme non-attainment of the National Ambient Air Quality Standards (NAAQS) and therefore has tight emission control regulations, it was felt that its screening data may not be representative of refineries without tight emission controls. Thus, the Southern California screening data were compared to screening measurements at refineries in an area that is in attainment of the NAAQS and without emissions control, which is the case for those refineries in Washington. It was found that statistically there was no significant difference in emission factors between the two areas and, therefore, there appears to be no difference in emissions from heavy liquid components in areas with and without leak detection and repair (LDAR) programs. The new emission factors range from 1/7 to 1/3 times the current EPA emission factors. This program was sponsored by the American Petroleum Institute (API) and an API report will soon be released providing complete details.

  13. The sublethal effects of petroleum refinery effluents: Mixed function oxygenase (MFO) induction in rainbow trout

    SciTech Connect (OSTI)

    Sherry, J.; Scott, B.; Parrott, J.; Hodson, P.; Rao, S.

    1995-12-31

    Canada uses a single biological parameter which is based on the ability of rainbow trout (Oncorhynchus mykiss) to survive a 24 hour exposure to assess and regulate the toxicity of refinery effluents. The acute toxicity of Canadian refinery effluents is generally well controlled. Long term exposures to sublethal toxicants, which are not covered by the current regulations, could have adverse ecological effects. Since PAHs, such as benzo(a)pyrene, can occur in refinery effluents, the authors tested the hypothesis that refinery effluents can induce mixed-function oxygenase measured as ethoxyresorufin-O-deethylase activity (EROD) activity in fish. Two end of pipe effluent samples were collected from each of four Ontario refineries. All effluents induced EROD activity in young trout in a dose dependent manner. The EROD parameter has potential as a bioindicator of exposure to refinery effluents. The samples were also tested for toxicity to fathead minnow (Pimephales promelas) larvae and to a fish cell line (Ictalurus nebulosus). Fathead minnow growth was significantly reduced by six out of eight samples, and larval survival was affected by one sample. The in vitro data were less consistent: weak toxicity was detected in some samples but the dose response relationship was poor. Direct acting mutagens were detected in two effluents using the Ames Fluctuation assay.

  14. Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

    SciTech Connect (OSTI)

    Goldberg, M.

    2013-12-31

    The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.

  15. Regex-Stream

    SciTech Connect (OSTI)

    Goodall, John

    2012-09-01

    Log files are typically semi-or un-structured. To be useable, they need to be parsed into a standard, structured format. Regex-Stream facilitates parsing text files into structured data (JSON) in streams of data.

  16. New Jersey Supplemental Supplies of Natural Gas

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    454 457 392 139 255 530 1967-2014 Synthetic 0 0 0 1980-2014 Propane-Air 0 0 1980-2014 Refinery Gas 1980-2005 Biomass 0 0 1993-2014 Other 454 457 392 139 255 530 1980-2014

  17. Illinois Supplemental Supplies of Natural Gas

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    20 17 1 1 * 63 1967-2014 Synthetic 0 0 1980-2014 Propane-Air 20 17 1 1 0 63 1980-2014 Refinery Gas 1980-2005 Biomass 0 0 1999-2014 Other 0 0 2005

  18. Illinois Supplemental Supplies of Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    20 17 1 1 * 63 1967-2014 Synthetic 0 0 1980-2014 Propane-Air 20 17 1 1 0 63 1980-2014 Refinery Gas 1980-2005 Biomass 0 0 1999-2014 Other 0 0 2005...

  19. New Jersey Supplemental Supplies of Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    454 457 392 139 255 530 1967-2014 Synthetic 0 0 0 1980-2014 Propane-Air 0 0 1980-2014 Refinery Gas 1980-2005 Biomass 0 0 1993-2014 Other 454 457 392 139 255 530 1980-2014...

  20. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 6,735,067 6,815,590 6,794,407 6,973,710 7,173,730 7,260,943 1981-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 223,448 1981-2015 Ethane/Ethylene 7,228 7,148 6,597 2,626 2,038 2,134 1981-2015 Ethane 5,200 5,105 4,835 2,439 1,777 1,835 1993-2015 Ethylene 2,028 2,043 1,762 187 261 299 1993-2015 Propane/Propylene 204,223 201,492 202,309 206,038 214,378 203,954 1981-2015 Propane 102,913 98,508 100,933 103,568 111,813 103,253

  1. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  2. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, Mitchell R.; Gal, Eli

    1993-01-01

    A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

  3. Enhanced membrane gas separations

    SciTech Connect (OSTI)

    Prasad, R.

    1993-07-13

    An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

  4. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett; Zielke, Clyde W.

    1981-01-01

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  5. Radiological health implications of lead-210 and polonium-210 accumulations in LPG refineries

    SciTech Connect (OSTI)

    Summerlin, J. Jr.; Prichard, H.M.

    1985-04-01

    Radon-222, a naturally occurring radioactive noble gas, is often a contaminant in natural gas. During fractionation at processing plants, Radon tends to be concentrated in the Liquified Petroleum Gas (LPG) product stream. Radon-222 decays into a number of radioactive metallic daughters which can plate out on the interior surfaces of plant machinery. The hazards associated with gamma-emitting short-lived radon daughters have been investigated previously. The present work reports an analysis of the hazards associated with the long-lived daughters; Pb-210, Bi-210, and Po-210. These nuclides do not emit appreciable penetrating radiation, and hence do not represent a hazard as long as they remain on the inside surfaces of equipment. However, when equipment that has had prolonged exposure to an LPG stream is disassembled for repair or routine maintenance, opportunities for exposure to radioactive materials can occur. A series of measurements made on an impeller taken from a pump in an LPG facility is reported. Alpha spectroscopy revealed the presence of Po-210, and further measurements showed that the amount on the impeller surface was well above the exempt quantity. Breathing zone measurements made in the course of cleaning the impeller showed that an inhalation exposure equivalent to breathing Po-210 at the Maximum Permissible Concentration (MPC) for 60 hours could be delivered in less than half an hour. It was concluded that maintenance and repair work on LPG and derivitive product stream equipment must be carried out with the realization that a potential radiological health problem exists.

  6. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA APACHE TRIBE

    SciTech Connect (OSTI)

    John D. Jones

    2004-10-01

    A feasibility study for a proposed petroleum refinery for the Jicarilla Apache Indian Reservation was performed. The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The proposed refinery will utilize a lower temperature, smaller crude fractionation unit. It will have a Naphtha Hydrodesulfurizer and Reformer to produce high octane gasoline. The surplus hydrogen from the reformer will be used in a specialized hydrocracker to convert the heavier crude oil fractions to ultra low sulfur gasoline and diesel fuel products. The proposed refinery will produce gasoline, jet fuel, diesel fuel, and a minimal amount of lube oil. The refinery will require about $86,700,000 to construct. It will have net annual pre-tax profit of about $17,000,000. The estimated return on investment is 20%. The feasibility is positive subject to confirmation of long term crude supply. The study also identified procedures for evaluating processing options as a means for American Indian Tribes and Native American Corporations to maximize the value of their crude oil production.

  7. Market Assessment of Refinery Outages Planned for October 2010...

    Gasoline and Diesel Fuel Update (EIA)

    2011 November 2010 Energy Information Administration Office of Petroleum, Gas, and Biofuels Analysis U.S. Department of Energy Washington, DC 20585 This report was prepared by...

  8. Probabilistic ecological risk assessment of selected PAH`s in sediments near a petroleum refinery

    SciTech Connect (OSTI)

    Arnold, W.R.; Biddinger, G.R.

    1995-12-31

    Sediment samples were collected and analyzed for a number of polynuclear aromatic hydrocarbons (PAHs) along a gradient from a petroleum refinery`s wastewater diffuser. These data were used to calculate the potential risk to aquatic organisms using probabilistic modeling and Monte Carlo sampling procedures. Sediment chemistry data were used in conjunction with estimates of Biota-Sediment Accumulation Factors and Non-Polar Narcosis Theory to predict potential risk to bivalves. Bivalves were the receptors of choice because of their lack of a well-developed enzymatic system for metabolizing PAHs. Thus, they represent a species of higher inherent risk of adverse impact. PAHs considered in this paper span a broad range of octanol-water partition coefficients. Results indicate negligible risk of narcotic effects from PAHs existing near the refinery wastewater discharge.

  9. Characterization study of Hungary's petroleum refinery industry: A sector in transition. Phase 1 final report

    SciTech Connect (OSTI)

    Not Available

    1991-08-01

    Part of a USAID effort to assist Hungary's oil refinery sector during a period of transition, the report reviews the sector, with emphasis on the two major refineries -- DKV and TIPO. Key findings are as follows: (1) DKV and TIPO staffs are superbly qualified and up to date and have aggressively promoted energy conservation for a decade. Environmental compliance lags considerably behind the West; (2) Refinery managers are facing serious problems as the country moves from a command to a market economy; (3) There is a need for new criteria for evaluating the best use of limited investment resources during the austere period of transition. Replacing petroleum hydrocarbon fuels with indigenous coal does not seem viable at present.

  10. Correcting systematic bias and instrument measurement drift with mzRefinery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-08-04

    Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. In conclusion, we report on availability; the mzRefinery tool is part of msConvert, availablemore » with the ProteoWizard open source package at http://proteowizard.sourceforge.net/« less

  11. Correcting systematic bias and instrument measurement drift with mzRefinery

    SciTech Connect (OSTI)

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-08-04

    Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. In conclusion, we report on availability; the mzRefinery tool is part of msConvert, available with the ProteoWizard open source package at http://proteowizard.sourceforge.net/

  12. Mazheikiai refinery modernization study. Final report. Volume 2. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 2 of the study.

  13. Mazheikiai refinery modernization study. Final report. Volume 3. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 3 of the study.

  14. Mazheikiai refinery modernization study. Final report. Volume 1. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 1 of the study.

  15. Correcting systematic bias and instrument measurement drift with mzRefinery

    SciTech Connect (OSTI)

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-12-01

    MOTIVATION: Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. RESULTS: We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. AVAILABILITY: The mzRefinery tool is part of msConvert, available with the ProteoWizard open source package at http://proteowizard.sourceforge.net/

  16. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","6/2016","1/15/1985" ,"Release Date:","8/31/2016" ,"Next Release

  17. Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based

    Office of Scientific and Technical Information (OSTI)

    Oil Insertions (Technical Report) | SciTech Connect Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Citation Details In-Document Search Title: Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions In order to meet U.S. biofuel objectives over the coming decade the conversion of a broad range of biomass feedstocks, using diverse processing options, will be required. Further, the production of both gasoline and diesel

  18. Side stream separator for boiler particulate emission control

    SciTech Connect (OSTI)

    Skiven, D.A.; Sortor, C.J.; Tessier, R.J.

    1982-02-09

    A device is disclosed for controlling the particulate emission from coal-fired boilers. A cyclone type primary separator between the boiler and the stack and a bag filter is coupled in side stream relation to the cyclone separator such as to shunt and departiculatize up to about 20% of the gas stream entering the cyclone. The shunted gas is drawn from below the tube sheet of the cyclone separator, filtered through the bags and returned to the stack. Means are provided to control the temperature of the shunted gas within defined limits corresponding to the acid dew point of the gas and the thermal degradation temperature of the filter media.

  19. Fuel cell gas management system

    DOE Patents [OSTI]

    DuBose, Ronald Arthur

    2000-01-11

    A fuel cell gas management system including a cathode humidification system for transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell equal to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

  20. FILTER FOR HIGH VELOCITY GAS STREAMS

    DOE Patents [OSTI]

    Heckman, R.A.; Warner, H.F.

    1963-11-01

    An air filter that is particularly useful in air-sampling rockets is presented. The filter comprises a cellulose fiber mat having an evenly disposed thin coating of stearic acid. Protective loose weave fabric covers are stitched to the front and back of the fiber mat, the stitching being in the form of a sine wave spiraled from the midpoint of the mat out to its periphery. (AEC)

  1. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    U.S. Energy Information Administration (EIA) Indexed Site

    Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues Release date: November 25, 2014 Executive summary Over the past five years, rapid growth in U.S. onshore natural gas and oil production has led to increased volumes of natural gas plant liquids (NGPL) and liquefied refinery gases (LRG). The increasing economic importance of these volumes, as a result of their significant growth in production, has revealed the need for better data accuracy and transparency to improve the quality of

  2. Twitter Stream Archiver

    Energy Science and Technology Software Center (OSTI)

    2014-07-01

    The Twitter Archiver system allows a user to enter their Twitter developer account credentials (obtained separately from the Twitter developer website) and read from the freely available Twitter sample stream. The Twitter sample stream provides a random sample of the overall volume of tweets that are contributed by users to the system. The Twitter Archiver system consumes the stream and serializes the information to text files at some predefined interval. A separate utility reads themore » text files and creates a searchable index using the open source Apache Lucene text indexing system.« less

  3. Twitter Stream Archiver

    SciTech Connect (OSTI)

    Steed, Chad Allen

    2014-07-01

    The Twitter Archiver system allows a user to enter their Twitter developer account credentials (obtained separately from the Twitter developer website) and read from the freely available Twitter sample stream. The Twitter sample stream provides a random sample of the overall volume of tweets that are contributed by users to the system. The Twitter Archiver system consumes the stream and serializes the information to text files at some predefined interval. A separate utility reads the text files and creates a searchable index using the open source Apache Lucene text indexing system.

  4. Improving energy usage at the Borger Refinery and NGL Process Center

    SciTech Connect (OSTI)

    Haage, P.R.

    1982-05-01

    The Phillips Petroleum Company's Borger Refinery and NGL Process Center energy conservation program began prior to the 1973 oil embargo and was greatly intensified after that event. This paper describes recent progress made in the reduction of energy use at the facility, with emphasis on the furnace and boiler efficiency control program, computer control of fractionation columns, and the steam-trap survey program.

  5. Process and system for removing impurities from a gas

    DOE Patents [OSTI]

    Henningsen, Gunnar; Knowlton, Teddy Merrill; Findlay, John George; Schlather, Jerry Neal; Turk, Brian S

    2014-04-15

    A fluidized reactor system for removing impurities from a gas and an associated process are provided. The system includes a fluidized absorber for contacting a feed gas with a sorbent stream to reduce the impurity content of the feed gas; a fluidized solids regenerator for contacting an impurity loaded sorbent stream with a regeneration gas to reduce the impurity content of the sorbent stream; a first non-mechanical gas seal forming solids transfer device adapted to receive an impurity loaded sorbent stream from the absorber and transport the impurity loaded sorbent stream to the regenerator at a controllable flow rate in response to an aeration gas; and a second non-mechanical gas seal forming solids transfer device adapted to receive a sorbent stream of reduced impurity content from the regenerator and transfer the sorbent stream of reduced impurity content to the absorber without changing the flow rate of the sorbent stream.

  6. Refining and end use study of coal liquids. Topical report: Petroleum Refinery; Linear Programming Model; and Design Basis

    SciTech Connect (OSTI)

    1995-03-01

    A model was developed for use in the Bechtel PIMS (Process Industry Modeling System) linear programming software to simulate a generic Midwest (PADD II) petroleum refinery of the future. This ``petroleum-only`` version of the model establishes the size and complexity of the refinery after the year 2000 and prior to the introduction of coal liquids. It should be noted that no assumption has been made on when a plant can be built to produce coal liquids except that it will be after the year 2000. The year 2000 was chosen because it is the latest year where fuel property and emission standards have been set by the Environmental Protection Agency. It assumes the refinery has been modified to accept crudes that are heavier in gravity and higher in sulfur than today`s average crude mix. In addition, the refinery has also been modified to produce a product slate of transportation fuels of the future (i.e. 40% reformulated gasolines). This model will be used as a basis for determining the optimum scheme for processing coal liquids in a petroleum refinery. This report summarizes the design basis for this ``petroleum only`` LP refinery model. A report detailing the refinery configuration when coal liquids are processed will be provided at a later date.

  7. Gas-separation process

    DOE Patents [OSTI]

    Toy, Lora G.; Pinnau, Ingo; Baker, Richard W.

    1994-01-01

    A process for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material.

  8. Replay-Stream

    Energy Science and Technology Software Center (OSTI)

    2012-12-01

    For testing and demonstration purposes, it is often necessary to replay saved network and log data. This library facilitates replaying these saved data streams. This module will take in a stream of JSON strings, read their specified timestamp field, and output according to the given criteria. This can include restricting output to a certain time range, and/or outputting the items with some delay based on their timestamp.

  9. Distillate Fuel Oil Refinery, Bulk Terminal, and Natural Gas Plant Stocks

    Gasoline and Diesel Fuel Update (EIA)

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S. 127,474 128,838 129,088 124,543 124,729 118,611 1993-2016 PAD District 1 51,825 50,096 46,859 46,285 48,217 49,317 1993-2016 Connecticut 4,530 4,100 3,672 4,048 4,040 4,547 1993-2016 Delaware 453 470 273 505 477 591 1993-2016 District of Columbia 1993-2004 Florida 1,929 1,940 1,905 2,131 2,902 2,243 1993-2016 Georgia 1,498 1,677 1,441 1,529 1,580 1,490 1993-2016 Maine 2,292 2,093 2,110 1,819 1,721 1,576 1993-2016 Maryland 2,963 2,142

  10. ,"U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 37271,118323,35153,83170,,,,4862,103932,,56214,47718,41242,41061 37302,113911,34459,79452,,,,4385,97433,,54465,42968,38817,31781 37330,107954,33441,74513,,,,3995,91...

  11. U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks of...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Area: U.S. PAD District 1 Connecticut Delaware District of Columbia Florida Georgia Maine Maryland Massachusetts New Hampshire New Jersey New York North Carolina Pennsylvania Rhode ...

  12. Spectrometer for measuring the concentration of components in a fluid stream and method for using same

    DOE Patents [OSTI]

    Durham, Michael D.; Stedman, Donald H.; Ebner, Timothy G.; Burkhardt, Mark R.

    1991-01-01

    A device and method for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated.

  13. Spectrometer for measuring the concentration of components in a fluid stream and method for using same

    DOE Patents [OSTI]

    Durham, M.D.; Stedman, D.H.; Ebner, T.G.; Burkhardt, M.R.

    1991-12-03

    A device and method are described for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in-situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated. 15 figures.

  14. Removing sulphur oxides from a fluid stream

    DOE Patents [OSTI]

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

    2014-04-08

    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  15. Carbon Capture and Sequestration (via Enhanced Oil Recovery) from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Stewart Mehlman

    2010-06-16

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE’s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

  16. Program development to identify and characterize potential emergency situations at a petroleum refinery and determination of industrial hygiene emergency responses

    SciTech Connect (OSTI)

    Oransky, J.J.; Delp, S.N.; Deppen, E.A.; Barrett, D.

    1995-12-31

    In the modern world the field of industrial hygiene continues to grow beyond the traditional definition of the profession. This case study documents the problem solving approach used to identify potential exposures and evaluate industrial hygiene preparedness to handle emergencies due to fire or major spill at a complex multi-process petroleum refinery. In the recent past an environmental engineer and industrial hygiene consulting firm was retained by a mature, multi-process petroleum refinery to assist in the program development to identify and characterize potential emergency situations due to a fire, major release, or spill. This study would assist the refinery in compliance with the process safety and emergency response standards and to protect refinery operations and fire fighting personnel by minimizing potential exposures and risk when responding to such a major incident.

  17. Evaluating the need and feasibility of cathodically protecting above ground storage tanks in a petroleum refinery

    SciTech Connect (OSTI)

    Barrien, P.; Solomon, I.

    1994-12-31

    Managing soil-side corrosion problems on Above Ground Storage Tanks (AGSTs) presents an important challenge to refinery corrosion engineers. Cathodic protection and periodic internal inspection are two methods of managing soil-side corrosion. Mobil Oil Australia conducted a study into the need and feasibility of cathodically protecting up to 120 tanks at its Altona refinery in Melbourne, Australia. The need was determined by assessing the corrosivity of the environment under the tanks from soil samples and inspection data, and the feasibility determined by conducting current drainage testing on representative tanks. Results indicated that the tanks can be cathodically protected at less than 10mA/m{sup 2} current density, using perimeter anodes. They also showed that there is little correlation between bulk foundation or surrounding soil properties, and soil-side corrosion. The paper also demonstrates how the extension of intervals between internal inspections can economically justify the application of cathodic protection.

  18. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect (OSTI)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  19. The Use of Oil Refinery Wastes as a Dust Suppression Surfactant for Use in Mining

    SciTech Connect (OSTI)

    Dixon-Hardy, D.W.; Beyhan, S.; Ediz, I.G.; Erarslan, K.

    2008-10-15

    In this research, the suitability of a selection of petroleum refinery wastes as a dust suppressant were examined. Dust is a significant problem in surface and underground mining mainly because of its adverse effects on human health and machinery. Hence, dust control and suppression is a vital part of mine planning for mining engineers. Water is the oldest and the cheapest suppressant in dealing with the mine dusts. However, surfactant use has recently been used for a wider range of applications in the mining industry. In order to carry out laboratory experiments, a dust chamber was designed and manufactured. The chamber has an inlet for coal dust entrance and a nozzle for spraying water and the oil refinery wastes. Water and the surfactants were mixed at various ratios and then sprayed onto the coal dusts within the cell. Dust concentration was measured systematically to determine the effects of surfactant containing solution on the coal dust and the data obtained by the measurements were analyzed. The results showed that the oil refinery wastes could be used as a dust suppressant, which may create an economical utilization for the wastes concerned.

  20. Meters Roads N Streams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Meters Roads N Streams o Openwells E3i APT Site *. TES Plants (1) E2J Other Set-Asides lEI Hydric Soils . 370 o 370 Soils Soil Series and Phase DBaB DBaC .Pk .TrB DTrC DTrD .TuE...

  1. Thief carbon catalyst for oxidation of mercury in effluent stream

    DOE Patents [OSTI]

    Granite, Evan J.; Pennline, Henry W.

    2011-12-06

    A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

  2. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M [Idaho Falls, ID; McKellar, Michael G [Idaho Falls, ID; Turner, Terry D [Ammon, ID; Carney, Francis H [Idaho Falls, ID

    2009-09-29

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream.

  3. Nigeria: after crude, the gas

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    Misinterpretation of the laws of the marketplace have already brought Nigeria to the brink of a catastrophe in 1978, when the government had built up heavy stocks expecting a substantial increase in price. When it did not materialize and the production had to be dropped to 50% of the previous rate, in a country where crude constitutes 90% of the export revenues, the system was changed. The new plan is intended to reduce the dependence of Nigeria on oil exports. The production rate is set at between 2.2 and 2.5 million bpd. Due to a significant increase in domestic demand, the 2 existing refineries cannot fill the gap; 2 more refineries are planned. There also are substantial gas reserves; the associated gas, now flared, is to be recovered. A gas liquefaction plant also is in operation, with one-half of the output going to Europe and one-half to the US. Some of the oil and gas is earmarked for local petrochemical plants.

  4. Tidal Stream | Open Energy Information

    Open Energy Info (EERE)

    Stream Jump to: navigation, search Name: Tidal Stream Address: 76 Dukes Ave Place: London Zip: W4 2 AK Region: United Kingdom Sector: Marine and Hydrokinetic Phone Number: 01926...

  5. Apparatus for the liquefaction of a gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D. [Idaho Falls, ID; Wilding, Bruce M. [Idaho Falls, ID; McKellar, Michael G. [Idaho Falls, ID

    2009-12-29

    Apparatuses and methods are provided for producing liquefied gas, such as liquefied natural gas. In one embodiment, a liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream may be sequentially pass through a compressor and an expander. The process stream may also pass through a compressor. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. A portion of the liquid gas may be used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line.

  6. Mercury sorbent delivery system for flue gas

    DOE Patents [OSTI]

    Klunder; ,Edgar B.

    2009-02-24

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  7. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D.; Wilding, Bruce M.; McKellar, Michael G.

    2009-09-22

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates a vapor from the liquid natural gas. A portion of the liquid gas is used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line or recirculation within the system for further processing.

  8. Method and apparatus for producing thermal vapor stream

    DOE Patents [OSTI]

    Cradeur, Robert R.; Sperry, John S.; Krajicek, Richard W.

    1979-01-01

    Method and apparatus for producing a thermal vapor stream for injecting into a subterranean formation for the recovery of liquefiable minerals therefrom, including a pressure vessel containing a high pressure combustion chamber for producing a heating gas for introduction into a heating gas injector. The heating gas injector is partly immersed in a steam generating section of the pressure vessel such that the heating gas is passed through the steam generating section to produce steam and combustion products which are directed between the pressure vessel and the combustion chamber for simultaneously cooling of the combustion chamber by further heating of the steam and combustion gases.

  9. The Phoenix stream: A cold stream in the southern hemisphere

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balbinot, E.

    2016-03-17

    In this study, we report the discovery of a stellar stream in the Dark Energy Survey (DES) Year 1 (Y1A1) data. The discovery was made through simple color-magnitude filters and visual inspection of the Y1A1 data. We refer to this new object as the Phoenix stream, after its resident constellation. After subtraction of the background stellar population we detect a clear signal of a simple stellar population. By fitting the ridge line of the stream in color-magnitude space, we find that a stellar population with agemore » $$\\tau=11.5\\pm0.5$$ Gyr and $[Fe/H]<-1.6$ located 17.5$$\\pm$$0.9 kpc from the Sun gives an adequate description of the stream stellar population. The stream is detected over an extension of 8$$^{\\circ}.$$1 (2.5 kpc) and has a width of $$\\sim$$54 pc assuming a Gaussian profile, indicating that a globular cluster is a probable progenitor. There is no known globular cluster within 5 kpc compatible with being the progenitor of the stream, assuming that the stream traces its orbit. We examined overdensities along the stream, however no obvious counterpart bound stellar system is visible in the coadded images. We also find overdensities along the stream that appear to be symmetrically distributed - consistent with the epicyclic overdensity scenario for the formation of cold streams - as well as a misalignment between the Northern and Southern part of stream. Despite the close proximity we find no evidence that this stream and the halo cluster NGC 1261 have a common accretion origin linked to the recently found EriPhe overdensity (Li et al. 2016).« less

  10. Waste Stream Approval - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stream Approval About Us Hanford Site Solid Waste Acceptance Program What's New Acceptance Criteria Acceptance Process Becoming a new Hanford Customer Annual Waste Forecast and Funding Arrangements Waste Stream Approval Waste Shipment Approval Waste Receipt Quality Assurance Program Waste Specification Records Tools Points of Contact Waste Stream Approval Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size After funding approval is in place, the next step is to

  11. Case history of a toxicity identification/reduction evaluation (TI/RE) at a petroleum refinery

    SciTech Connect (OSTI)

    Arnold, W.R.; Zaleski, R.T.; Biddinger, G.R.; Simmerman, J.J.; Stewart, J.D.

    1994-12-31

    During an operational turn-around at a high conversion petroleum refinery, the final wastewater effluent became toxic to three fish species used in continuous on-line flow-through acute toxicity tests. Discharge of effluent to the receiving bay was promptly halted. Wastewater treatment continued and the treated effluent was diverted to a series of holding ponds with limited capacity. A refinery team was formed to coordinate toxicity identification studies as well as to facilitate modifications of waste disposal practices and treatment operations. A test program was conducted, consisting of one rainbow trout Phase 1 TIE and 84 strategic acute toxicity tests. As a result, a treatment methodology was identified within three days and within eight days of first observing toxicity a cationic water treatment polymer was identified as the primary toxicant. The toxicity was due to increased bioavailability of the polymer when suspended solids loads dropped during turn-around. Use of the polymer was immediately stopped and discharge to the bay was resumed with 100% survival of all three monitoring species. The authors present an overview of the studies and decisions leading to the successful identification and management of this situation.

  12. Lead exposure in a petroleum refinery during maintenance and repair activities

    SciTech Connect (OSTI)

    Booher, L.E.; Zampello, F.C.

    1994-02-01

    Exposure to inorganic lead (Pb) may result in a petroleum refinery when paints that contain Pb are disturbed. Frequently performed activities that disturb paint include welding, burning, cutting, abrasive blasting, sanding, grinding, and needle gun chipping. The purpose of the study reported in this article was: to determine the Pb content of paint on metal surfaces in a petroleum refinery; to measure air Pb concentrations during abrasive blasting, torch cutting and burning, and power disk sanding/grinding on surfaces coated with Pb paint; and to evaluate the effectiveness of worker exposure controls by monitoring worker blood Pb (PbB) levels. Pb levels on representative metal surfaces were measured, and most painted surfaces were found to contain significant amounts of Pb. Personal air samples collected indicated that abrasive blasting and torch burning/cutting resulted in elevated air Pb levels, while short duration power disk sanding (less than 30 minutes duration) did not result in elevated air Pb levels as compared to the Occupational Safety and Health Administration permissible exposure limit. Despite these elevated air Pb levels, exposure controls including personal protective equipment, housekeeping, showering, work area isolation, and training effectively prevented elevated worker PbB levels. 6 refs., 4 figs., 3 tabs.

  13. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    SciTech Connect (OSTI)

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W.

    2012-05-15

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  14. The Orbit of the Orphan Stream

    SciTech Connect (OSTI)

    Newberg, Heidi Jo; Willett, Benjamin A.; Yanny, Brian; Xu, Yan

    2010-01-01

    We use recent SEGUE spectroscopy and SDSS and SEGUE imaging data to measure the sky position, distance, and radial velocities of stars in the tidal debris stream that is commonly referred to as the 'Orphan Stream.' We fit orbital parameters to the data, and find a prograde orbit with an apogalacticon, perigalacticon, and eccentricity of 90 kpc, 16.4 kpc and e = 0.7, respectively. Neither the dwarf galaxy UMa II nor the Complex A gas cloud have velocities consistent with a kinematic association with the Orphan Stream. It is possible that Segue-1 is associated with the Orphan Stream, but no other known Galactic clusters or dwarf galaxies in the Milky Way lie along its orbit. The detected portion of the stream ranges from 19 to 47 kpc from the Sun and is an indicator of the mass interior to these distances. There is a marked increase in the density of Orphan Stream stars near (l, b) = (253{sup o}; 49{sup o}), which could indicate the presence of the progenitor at the edge of the SDSS data. If this is the progenitor, then the detected portion of the Orphan Stream is a leading tidal tail. We find blue horizontal branch (BHB) stars and F turnoff stars associated with the Orphan Stream. The turnoff color is (g-r){sub 0} = 0.22. The BHB stars have a low metallicity of [Fe/H]{sub WBG} = -2.1. The orbit is best fit to a halo potential with a halo plus disk mass of about 2.6 x 10{sup 11} M{sub {circle_dot}}, integrated to 60 kpc from the Galactic center. Our fits are done to orbits rather than full N-body simulations; we show that if N-body simulations are used, the inferred mass of the galaxy would be slightly smaller. Our best fit is found with a logarithmic halo speed of v{sub halo} = 73 {+-} 24 km s{sup -1}, a disk+bulge mass of M(R < 60 kpc) = 1.3 x 10{sup 11} M{sub {circle_dot}}, and a halo mass of M(R < 60 kpc) = 1.4 x 10{sup 11} M{sub {circle_dot}}. However, we can find similar fits to the data that use an NFW halo profile, or that have smaller disk masses and

  15. 90 MW build/own/operate gas turbine combined cycle cogeneration project with sludge drying plant

    SciTech Connect (OSTI)

    Schroppe, J.T.

    1986-04-01

    This paper will discuss some of the unique aspects of a build/own/operate cogeneration project for an oil refinery in which Foster Wheeler is involved. The organization is constructing a 90 MW plant that will supply 55 MW and 160,000 lb/hr of 600 psi, 700F steam to the Tosco Corporation's 130,000 bd Avon Oil Refinery in Martinez, California. (The refinery is located about 45 miles northeast of San Francisco.) Surplus power production will be sold to the local utility, Pacific Gas and Electric Co. (PG and E). Many of the aspects of this project took on a different perspective, since the contractor would build, own and operate the plant.

  16. Automated gas chromatography

    DOE Patents [OSTI]

    Mowry, Curtis D.; Blair, Dianna S.; Rodacy, Philip J.; Reber, Stephen D.

    1999-01-01

    An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute.

  17. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mary Biddy Sue Jones NREL PNNL This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 ...

  18. FireHose Streaming Benchmarks

    SciTech Connect (OSTI)

    Karl Anderson, Steve Plimpton

    2015-01-27

    The FireHose Streaming Benchmarks are a suite of stream-processing benchmarks defined to enable comparison of streaming software and hardware, both quantitatively vis-a-vis the rate at which they can process data, and qualitatively by judging the effort involved to implement and run the benchmarks. Each benchmark has two parts. The first is a generator which produces and outputs datums at a high rate in a specific format. The second is an analytic which reads the stream of datums and is required to perform a well-defined calculation on the collection of datums, typically to find anomalous datums that have been created in the stream by the generator. The FireHose suite provides code for the generators, sample code for the analytics (which users are free to re-implement in their own custom frameworks), and a precise definition of each benchmark calculation.

  19. The Oil and Gas Journal databook, 1986 edition

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    This annual contains the following: Foreword by Gene Kinney; OGJ 400; Crude Oil Assays; Worldwide Petrochemical Survey; Midyear Forecast and Review; Worldwide Gas Processing Report; Ethylene Report; Sulfur Survey; International Refining; Catalyst Compilation; Pipeline Economics Report; Worldwide Production and Refining Report; Annual Refining Survey; Morgan Pipeline Cost Index, Oil and Gas; Nelson Cost Index; Hughes Rig Count; Smith Rig Count; OGJ Production Report and the API Refinery Reports. Also featured is the Oil and Gas Journal Index, which lists every article published in the Journal in 1985, referenced by article title or subject.

  20. Separation of petroleum refinery wastes from a landfill by liquid chromatography

    SciTech Connect (OSTI)

    Mazzocco, D.L.; Willis, W.V.

    1995-12-01

    Large amounts of acidic petroleum refinery wastes (PRW) have been buried in landfills during the period 1930-1950. Many of the compounds IN PRW have not identified. Organosulfur compounds constitute an important fraction of these wastes, and are significant in site closure planning and cleanup operations. Some are difficult analytes because they undergo facile conversions during standard methods of sample preparation and analysis. A mild liquid chromatographic method using cyanopropyl and octadecyl stationary phases and a modified hexane mobile phase was found to separate PRW into five major groups, two of which contain sulfur compounds. GC/MS analysis of collected HPLC fractions identified over 80% of the compounds present. Wastes from three different landfills used in the period 1940-1950 show major similarities, but differ in relative composition. Implications for remediation of PRW in these and similar landfills designated as Superfund sites are discussed.

  1. Reformulated Gasoline Foreign Refinery Rules (Released in the STEO January 1998)

    Reports and Publications (EIA)

    1998-01-01

    On August 27, 1997, the Environmental Protection Agency (EPA) promulgated revised the rules that allow foreign refiners to establish and use individual baselines, but it would not be mandatory (the optional use of an individual refinery baseline is not available to domestic refiners.) If a foreign refiner did not establish and use an individual baseline, the gasoline they export to the United States would be regulated through the importer, and subject to the importer's baseline (most likely the statutory baseline). Specific regulatory provisions are implemented to ensure that the option to use an individual baseline would not lead to adverse environmental impacts. This involves monitoring the average quality of imported gasoline, and if a specified benchmark is exceeded, remedial action would be taken by adjusting the requirements applicable to imported gasoline.

  2. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Bannister, R.L.

    1999-04-27

    A system and method are disclosed for efficiently generating power using a gas turbine, a steam generating system and a reformer. The gas turbine receives a reformed fuel stream and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer. The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine. 2 figs.

  3. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, Wen-Ching; Newby, Richard A.; Bannister, Ronald L.

    1999-01-01

    A system and method for efficiently generating power using a gas turbine, a steam generating system (20, 22, 78) and a reformer. The gas turbine receives a reformed fuel stream (74) and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer (18). The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine.

  4. Gas-separation process

    DOE Patents [OSTI]

    Toy, L.G.; Pinnau, I.; Baker, R.W.

    1994-01-25

    A process is described for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material. 6 figures.

  5. Stream Alteration Permits | Open Energy Information

    Open Energy Info (EERE)

    Permits Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Stream Alteration Permits Abstract Stream alteration permits regulate activities that take...

  6. Montana Stream Permitting Webpage | Open Energy Information

    Open Energy Info (EERE)

    Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Stream Permitting Webpage Abstract Provides access to Montana Stream Permitting guide....

  7. Method for removing impurities from an impurity-containing fluid stream

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.

    2010-04-06

    A method of removing at least one polar component from a fluid stream. The method comprises providing a fluid stream comprising at least one nonpolar component and at least one polar component. The fluid stream is contacted with a supercritical solvent to remove the at least one polar component. The at least one nonpolar component may be a fat or oil and the at least one polar component may be water, dirt, detergents, or mixtures thereof. The supercritical solvent may decrease solubility of the at least one polar component in the fluid stream. The supercritical solvent may function as a solvent or as a gas antisolvent. The supercritical solvent may dissolve the nonpolar components of the fluid stream, such as fats or oils, while the polar components may be substantially insoluble. Alternatively, the supercritical solvent may be used to increase the nonpolarity of the fluid stream.

  8. Oil and gas journal databook, 1987 edition

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    This book is an annual compendium of surveys and special reports reviewed by experts. The 1987 edition opens with a forward by Gene Kinney, co-publisher of the Oil and Gas Journal and includes the OGJ 400 Report, Crude Oil Assays, Worldwide Petrochemical Survey, the Midyear Forecast and Reviews, the Worldwide Gas Processing Report, the Ethylene Report, Sulfur Survey, the International Refining, Catalyst Compilation, Annual Refining Survey, Worldwide Construction Report, Pipeline Economics Report, Worldwide Production and Refining Report, the Morgan Pipeline Cost Index for Oil and Gas, the Nelson Cost Index, the Hughes Rig Count, the Smith Rig Count, the OGJ Production Report, the API Refinery Report, API Crude and Product Stocks, APU Imports of Crude and Products, and the complete Oil and Gas Journal 1986 Index of articles.

  9. FireHose Streaming Benchmarks

    Energy Science and Technology Software Center (OSTI)

    2015-01-27

    The FireHose Streaming Benchmarks are a suite of stream-processing benchmarks defined to enable comparison of streaming software and hardware, both quantitatively vis-a-vis the rate at which they can process data, and qualitatively by judging the effort involved to implement and run the benchmarks. Each benchmark has two parts. The first is a generator which produces and outputs datums at a high rate in a specific format. The second is an analytic which reads the streammore » of datums and is required to perform a well-defined calculation on the collection of datums, typically to find anomalous datums that have been created in the stream by the generator. The FireHose suite provides code for the generators, sample code for the analytics (which users are free to re-implement in their own custom frameworks), and a precise definition of each benchmark calculation.« less

  10. Natural gas to buoy Trinidad and Tobago petroleum sector

    SciTech Connect (OSTI)

    Not Available

    1993-03-01

    Trinidad and Tobago's petroleum sector remains at a crossroads. While heavily reliant on oil and gas for domestic energy consumption and hard currency export earnings, the small Caribbean island nation faces some tough choices in reviving its hydrocarbon sector in the 1990s. Exploration and production of crude oil have stagnated in recent years, and domestic refinery utilization remains low at 36%. However, substantial natural gas reserves in Trinidad and Tobago offer the promise of a burgeoning natural gas based economy with an eye to liquefied natural gas and gas based petrochemical exports. Any solutions will involve considerable outlays by the government as well as a sizable infusion of capital by foreign companies. Therein lie some of the hard choices. The article describes the roles of oil and gas, foreign investment prospects, refining status, refining problems, gas sector foreign investment, and outlook for the rest of the 1990's.

  11. Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

    DOE Patents [OSTI]

    Wijmans Johannes G.; Merkel, Timothy C.; Baker, Richard W.

    2012-05-15

    A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

  12. Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations Using a Davison Criculating Riser Presentatio for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations Using a Davison Circulating Riser (DCR) 2.4.2.402 March 25, 2015 Bio-Oil Technology Area Alan Zacher Pacific Northwest National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement Develop a process to produce sustainable bio-fuels through co- processing biomass into a petroleum refinery unit operation. There is a need to know: How much stabilization is

  13. Miscellaneous streams best management practices (BMP) report

    SciTech Connect (OSTI)

    Lueck, K.J., Westinghouse Hanford

    1996-07-24

    The Washington State Department of Ecology (Ecology) and U.S. Department of Energy Consent Order No. DE 91NM-177 (Consent Order) lists regulatory milestones for liquid effluent streams at the Hanford Site to comply with the permitting requirements of Washington Administrative Code (WAC) 173-216 (`State Waste Discharge Permit Program`) or WAC 173-218 (`Washington Underground Injection Control Program`) where applicable. Hanford Site liquid effluent streams discharging to the soil column are categorized as Phase I and Phase II Streams, and Miscellaneous Streams. There were originally 33 Phase I and Phase II Streams, however some of these streams have been eliminated. Miscellaneous Streams are those liquid effluent streams discharged to the ground that are not categorized as Phase I or Phase II Streams, and are subject to the requirements of several milestones identified in the Consent Order. The three criteria for identifying streams that are potentially affecting groundwater are: (1) streams discharging to surface contaminated areas (referred to as category `b` streams); (2) potentially contaminated streams (referred to as category `c` streams); and (3) streams discharging within 91 meters (300 feet) of a contaminated crib, ditch, or trench (referred to as category `d` streams). Miscellaneous Streams that meet any of these criteria must be evaluated for application of best management practices (BMP). The purpose of this report is to provide the best management practice preferred alternative. The list of BMP streams has been revised since the original submittal. Several streams from the original list of BMP streams have already been eliminated through facility upgrades, reduction of steam usage, and facility shutdowns. This document contains a description of the changes to the list of BMP streams, applicable definitions and regulatory requirements and possible alternatives, and a schedule for implementing the preferred alternatives.

  14. Composition for absorbing hydrogen from gas mixtures

    DOE Patents [OSTI]

    Heung, Leung K.; Wicks, George G.; Lee, Myung W.

    1999-01-01

    A hydrogen storage composition is provided which defines a physical sol-gel matrix having an average pore size of less than 3.5 angstroms which effectively excludes gaseous metal hydride poisons while permitting hydrogen gas to enter. The composition is useful for separating hydrogen gas from diverse gas streams which may have contaminants that would otherwise render the hydrogen absorbing material inactive.

  15. Synthesis gas method and apparatus

    DOE Patents [OSTI]

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie R.; Kosowski, Lawrence W.; Robinson, Charles

    2013-01-08

    A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

  16. Synthesis gas method and apparatus

    SciTech Connect (OSTI)

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie; Kosowski, Lawrence W; Robinson, Charles

    2015-11-06

    A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

  17. Radiochemical Analyses of Water Samples from Selected Streams

    Office of Legacy Management (LM)

    > : , - ' and Precipitation Collected in - Connection with Calibration-Test Flaring of Gas From Test Well, - I August 15-October 13, 197,0,, Project Rulison-8, 197 1 HGS 9 DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY Federal center, Denver, Colorado 80225 RADIOCHEMICAL ANALYSES OF WATER SAMPLES FROM SELECTED STREAMS AND PRECIPITATION

  18. Dynamic visualization of data streams

    DOE Patents [OSTI]

    Wong, Pak Chung; Foote, Harlan P.; Adams, Daniel R.; Cowley, Wendy E.; Thomas, James J.

    2009-07-07

    One embodiment of the present invention includes a data communication subsystem to receive a data stream, and a data processing subsystem responsive to the data communication subsystem to generate a visualization output based on a group of data vectors corresponding to a first portion of the data stream. The processing subsystem is further responsive to a change in rate of receipt of the data to modify the visualization output with one or more other data vectors corresponding to a second portion of the data stream as a function of eigenspace defined with the group of data vectors. The system further includes a display device responsive to the visualization output to provide a corresponding visualization.

  19. The oil and gas journal databook, 1991 edition

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This book provides the statistical year in review plus selected articles that cover significant events of the past year. In addition, the Data Book features the popular surveys and special reports that quantify industry activity throughout the year. This book contains information on Midyear forecast and review; Worldwide gas processing report; Ethylene report; Sulfur survey; International refining survey; Nelson cost index; Smith rig count; API refinery report; API imports of crude and products; The catalyst compilation; Annual refining survey; Worldwide construction report; Pipeline economics report; Worldwide production and refining report; Morgan pipeline cost index for oil and gas; Hughes rig count; OBJ production report.

  20. Texas Supplemental Supplies of Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    8-2014 From Gas Wells 36,820 27,421 23,791 15,953 13,650 10,924 1978-2014 From Oil Wells 991 1,153 0 552 386 299 1978-2014 From Shale Gas Wells 0 0 2012-2014 From Coalbed Wells 0 0 2012-2014 Repressuring 0 0 0 0 0 0 2003-2014 Vented and Flared 0 0 0 0 0 0 2003-2014 Nonhydrocarbon Gases Removed 0 0 0 0 0 0 2003-2014 Marketed Production 37,811 28,574 23,791 16,506 14,036 11,222 1992-2014 Dry Production 16,506 11,222 2012

    Propane-Air 1981-2005 Refinery Gas 1981-2005 Other 1999-2005

  1. Sensitivity of screening-level toxicity tests using soils from a former petroleum refinery

    SciTech Connect (OSTI)

    Pauwels, S.; Bureau, J.; Roy, Y.; Allen, B.; Robidoux, P.Y.; Soucy, M.

    1995-12-31

    The authors tested five composite soil samples from a former refinery. The samples included a reference soil (Mineral Oil and Grease, MO and G < 40 ppm), thermally-treated soil, biotreated soil, and two untreated soils. They evaluated toxicity using the earthworm E. foetida, lettuce, cress, barley, Microtox, green algae, fathead minnow, and D. magna. The endpoints measured were lethality, seed germination, root elongation, growth, and bioluminescence. Toxicity, as measured by the number of positive responses, increased as follows: biotreated soil < untreated soil No. 1 < reference soil < thermally-treated soil and untreated soil No. 2. The biotreated soil generated only one positive response, whereas the thermally-treated soil and untreated soil No. 2 generated five positive responses. The most sensitive and discriminant terrestrial endpoint was lettuce root elongation which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was barley seed germination for which no toxicity was detected. The most sensitive and discriminant aquatic endpoint was green algae growth which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was D. magna for which no toxicity was detected. Overall, soil and aqueous extract toxicity was spotty and no consistent patterns emerged to differentiate the five soils. Biotreatment significantly reduced the effects of the contamination. Aqueous toxicity was measured in the reference soil, probably because of the presence of unknown dissolved compounds in the aqueous extract. Finally, clear differences in sensitivity existed among the test species.

  2. Optimization of ferric hydroxide coprecipitation process for selenium removal from petroleum refinery stripped four water

    SciTech Connect (OSTI)

    Gerhardt, M.B.; Marrs, D.R.; Roehl, R.

    1996-12-31

    Iron coprecipitation was used in bench-scale tests to remove selenium from stripped sour water generated by two petroleum refineries. Chlorine dioxide and hydrogen peroxide were found to convert selenocyanate in the stripped sour water to selenite, which can be removed by iron coprecipitation. An iodometric titration procedure was developed to determine the required oxidant dose. Iron coprecipitation reduced selenium concentrations by 40 to 99 percent in stripped sour water after chlorine dioxide pretreatment Removal was less effective with hydrogen peroxide as the oxidant: total selenium concentrations were reduced by 28 to 92 percent in stripped sour water after hydrogen peroxide pretreatment. Highest removals were obtained at the highest oxidant and iron doses. Sludges produced in coprecipitation tests were hazardous under California regulations. Ozone oxidized selenocyanate but prevented ferric hydroxide precipitation or coagulation. Air was ineffective at selenocyanate oxidation. Repeatedly contacting iron hydroxide with stripped sour water pretreated with hydrogen peroxide, in a simulation of a countercurrent adsorption process, increased the selenium adsorbed on the solids from 32 to 147 pg selenium per mg of iron, but some of the adsorbed selenite was oxidized to selenate and desorbed back into solution.

  3. Identification of the cause of weak acute toxicity to rainbow trout at a petroleum refinery

    SciTech Connect (OSTI)

    Arnold, W.R.; Zaleski, R.T.; Biddinger, G.R.

    1995-12-31

    The refinery in question performs flow through acute toxicity tests on its effluent four times per month using three fish species: fathead minnows (Pimephales promelas), threespine sticklebacks (Gasterosteus oculeatus) and rainbow trout (Oncorhynchus mykiss). Several months of monitoring data indicated a transient low level acute toxicity to rainbow trout. In most cases, several days were required for mortality to occur in the flow through tests and numerous attempts to reproduce toxicity in static and static renewal tests were unsuccessful. A decision was made to manipulate the effluent in an attempt to enhance the toxic effect in the static mode so that conventional methods could be used to identify the cause. these tests indicated that toxicity was pH dependent. Additional testing, using EPA`s Phase 1 Toxicity Identification Evaluation methods suggested that the cause of toxicity was probably an organic acid. Experiments were subsequently begun to identify the specific cause and source of toxicity. This paper reviews the problems confronted during the various phases of the study and the decisions that were made that eventually led to an understanding of the basis of toxicity.

  4. A perimeter-based groundwater protection strategy for waste management units at a petroleum refinery

    SciTech Connect (OSTI)

    Wenzlau, R.K.

    1996-12-01

    This article presents a groundwater management strategy and its application to regulatory compliance for the Shell Oil Company Martinez Manufacturing Complex, a refinery located within northern California. The purpose of the strategy is to protect the beneficial uses of groundwater which are present beyond the facility boundary while recognizing the occurrence of limited degradation of groundwater upgradient of the perimeter. The strategy applies perimeter-based groundwater monitoring and control to two general sources of groundwater quality degradation: historic spill and leak sites and inactive waste management units. To regulate the groundwater contaminant plumes originating form historic spill and leak sites the California Regional Water Quality Control Board (Regional Board) has issued Site Cleanup Requirements (SCR). To satisfy the SCR Shell developed in 1989 a Basin Boundary Control Plan as the first implementation of the groundwater strategy. To regulate groundwater quality impacts from solid waste management units, the Regional Board issues Waste Discharge Requirements (WDR). In 1995 the Regional Board issued revised WDR that established consistency between waste management unit regulation and the facility groundwater management strategy. The Regional Board made two findings that allowed this consistency. The first finding was that the Points of Compliance for all 23 solid waste management units are at the down-gradient perimeter of the facility. The second finding was that all waste management units were within corrective action, regardless of whether a known release of waste constituents occurred from a given waste unit.

  5. Utilization and results of hazard and operability studies in a petroleum refinery

    SciTech Connect (OSTI)

    Pully, A.S. )

    1993-04-01

    The petroleum refining industry has been performing hazard analyses in process units to some extent since at least 1988 and in earnest since 1990, when the American Petroleum Institute published Recommended Practice No. 750, [open quotes]Process Hazards Management.[close quotes] The Hazard and Operability Study (HAZOPS) is the most widely used of the various analysis techniques available, in part because this highly structured technique is easy to teach and well-suited for continuous process units. The results of HAZOPS fall into two broad categories, tangible and intangible. The tangible results are obvious: worksheets which detail event scenarios for potential process deviations, and action items, or recommendations for changes to process equipment of procedures. In many cases, the action items address issues which have a purely economic impact or which are procedural in nature, involving little or no capital investment. The intangible results or products of a HAZOPS include: the training and knowledge gained by the team participants, and better utilization of limited capital funds resulting from more detailed up-front engineering when a HAZOPS is required prior to funding. An aggressive HAZOPS schedule also aids facilities in planning resources for process safety information updates where the necessary P ID's or PFD's are out-of-date. This paper details the experiences with HAZOPS at Chevron USA Products Company's Pascagoula, Mississippi Refinery. The manner in which HAZOPS are performed, the types of results obtained, and the benefits of the HAZOPS program are discussed. 8 refs., 1 fig., 1 tab.

  6. New process technology already existing in your refinery: Hydroprocessing-FCC Synergy

    SciTech Connect (OSTI)

    Stanger, C.W. Jr.; Fletcher, R.; Johnson, C.; Reid, T.

    1996-12-01

    New processing technology is now available to improve refinery operating margins. The cost of this technology is minor if a refiner has a VGO or Resid hydrotreater and an FCCU. The primary requirement is changing the way work is done. Addition of new capital can be an optional step. The New technology is Hydroprocessing-FCC Synergy. Redirecting the work effort to operate, optimize, and budget the FCC pretreater, the FCC and any FCC post-treaters as one unit can optimize margins. Calculating the unit operating margins on the difference of FCC final product value minus the pretreater and FCC operating costs highlights the new technology`s enhanced profitability. The synergy connectiveness is made through the hydrocarbon flow and properties. Selecting the proper conditions and catalyst to complement each other`s performance is the technical key. This paper discusses the techniques for catalyst and operating condition selection. The concept of changing formulations with processing age is discussed. Finally a case study comparing Hydroprocessing-FCC Synergy versus classical non-synergistic approaches is presented, including the effect of new Hydroprocessing and FCC catalysts on the profitability increase.

  7. Summary of the proceedings of the workshop on the refinery of the future

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This report on the Workshop on the Refinery of the Future has been prepared for participants to provide them with a succinct summary of the presentations, deliberations, and discussions. In preparing the summary, we have striven to capture the key findings (conclusions) and highlight the issues and concerns raised during the plenary and breakout sessions. The presentation of the summary of the proceedings follows the final workshop agenda, which is given in Section I; each section is tabbed to facilitate access to specific workshop topics. The material presented relies heavily on the outline summaries prepared and presented by the Plenary Session Chairman and the Facilitators for each breakout group. These summaries are included essentially as presented. In addition, individuals were assigned to take notes during each session; these notes were used to reconstruct critical issues that were discussed in more detail. The key comments made by the participants, which tended to represent the range of views expressed relative to the issues, are presented immediately following the facilitator`s summary outline in order to convey the flavor of the discussions. The comments are not attributed to individuals, since in many instances they represent a composite of several similar views expressed during the discussion. The facilitators were asked to review the writeups describing the outcomes of their sessions for accuracy and content; their suggested changes were incorporated. Every effort has thus been made to reconstruct the views expressed as accurately as possible; however, errors and/or misinterpretations undoubtedly have occurred.

  8. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P.; Novaresi, Mark A.; Cornelius, Charles C.

    2007-11-13

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  9. Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes

    DOE Patents [OSTI]

    Baker, Richard W.; Pinnau, Ingo; He, Zhenjie; Da Costa, Andre R.; Daniels, Ramin; Amo, Karl D.; Wijmans, Johannes G.

    2003-06-03

    A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

  10. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Miller, Christopher Francis (Macungie, PA)

    2008-09-16

    Method for gas purification comprising (a) obtaining a feed gas stream containing one or more contaminants selected from the group consisting of volatile metal oxy-hydroxides, volatile metal oxides, and volatile silicon hydroxide; (b) contacting the feed gas stream with a reactive solid material in a guard bed and reacting at least a portion of the contaminants with the reactive solid material to form a solid reaction product in the guard bed; and (c) withdrawing from the guard bed a purified gas stream.

  11. TidalStream | Open Energy Information

    Open Energy Info (EERE)

    TidalStream Jump to: navigation, search Name: TidalStream Place: Southam, United Kingdom Zip: CV47 0HF Product: UK-based developer of platforms for tidal turbines. Coordinates:...

  12. Automated gas chromatography

    DOE Patents [OSTI]

    Mowry, C.D.; Blair, D.S.; Rodacy, P.J.; Reber, S.D.

    1999-07-13

    An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute. 7 figs.

  13. Technical Evaluation of Side Stream Filtration for Cooling Towers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Evaluation of Side Stream Filtration for Cooling Towers Technical Evaluation of Side Stream Filtration for Cooling Towers Fact sheet provides an overview of side stream ...

  14. Utility-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop Summary of Revenue Streams from Breakout Sessions (11/20/11).

  15. Customer-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  16. Contractor-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  17. Financial Institution-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  18. Local Government-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  19. In-stream hydrokinetic power: Review and appraisal

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Van Zwieten, J.; McAnally, William; Ahmad, Jameel; Davis, Trey; Martin, James; Bevelhimer, Mark S.; Cribbs, Allison; Lippert, Renee; Hudon, Thomas; Trudeau, Matthew

    2015-09-01

    The objective of this paper is to provide a review of in-stream hydrokinetic power, which is defined as electric power generated by devices capturing the energy of naturally flowing water-stream, tidal, or open ocean flows-without impounding the water. North America has significant in-stream energy resources, and hydrokinetic electric power technologies to harness those resources have the potential to make a significant contribution to U.S. electricity needs by adding as much as 120 TWh/year from rivers alone to the present hydroelectric power generation capacity. Additionally, tidal and ocean current resources in the U.S. respectively contain 438 TWh/year and 163 TWh/year ofmore » extractable power. Among their attractive features, in-stream hydrokinetic operations do not contribute to greenhouse gas emissions or other air pollution and have less visual impact than wind turbines. Since these systems do no utilize dams the way traditional hydropower systems typically do, their impact on the environment will differ, and a small but growing number of studies support conclusions regarding those impacts. Furthermore, potential environmental impacts include altered water quality, altered sediment deposition, altered habitats, direct impact on biota, and navigability of waterways.« less

  20. In-stream hydrokinetic power: Review and appraisal

    SciTech Connect (OSTI)

    Van Zwieten, J.; McAnally, William; Ahmad, Jameel; Davis, Trey; Martin, James; Bevelhimer, Mark S.; Cribbs, Allison; Lippert, Renee; Hudon, Thomas; Trudeau, Matthew

    2015-09-01

    The objective of this paper is to provide a review of in-stream hydrokinetic power, which is defined as electric power generated by devices capturing the energy of naturally flowing water-stream, tidal, or open ocean flows-without impounding the water. North America has significant in-stream energy resources, and hydrokinetic electric power technologies to harness those resources have the potential to make a significant contribution to U.S. electricity needs by adding as much as 120 TWh/year from rivers alone to the present hydroelectric power generation capacity. Additionally, tidal and ocean current resources in the U.S. respectively contain 438 TWh/year and 163 TWh/year of extractable power. Among their attractive features, in-stream hydrokinetic operations do not contribute to greenhouse gas emissions or other air pollution and have less visual impact than wind turbines. Since these systems do no utilize dams the way traditional hydropower systems typically do, their impact on the environment will differ, and a small but growing number of studies support conclusions regarding those impacts. Furthermore, potential environmental impacts include altered water quality, altered sediment deposition, altered habitats, direct impact on biota, and navigability of waterways.

  1. Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities. [Task 1, Final report

    SciTech Connect (OSTI)

    Not Available

    1993-10-15

    The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco`s refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R&D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ``unit cost`` portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible` to estimate the likely future impacts, costs, and sources of oil spills.

  2. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond

    2012-08-07

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  3. Gas production apparatus

    DOE Patents [OSTI]

    Winsche, Warren E.; Miles, Francis T.; Powell, James R.

    1976-01-01

    This invention relates generally to the production of gases, and more particularly to the production of tritium gas in a reliable long operating lifetime systems that employs solid lithium to overcome the heretofore known problems of material compatibility and corrosion, etc., with liquid metals. The solid lithium is irradiated by neutrons inside low activity means containing a positive (+) pressure gas stream for removing and separating the tritium from the solid lithium, and these means are contained in a low activity shell containing a thermal insulator and a neutron moderator.

  4. Polycyclic aromatic hydrocarbons (PAHs): a possible cause of lung cancer mortality among nickel/copper smelter and refinery workers

    SciTech Connect (OSTI)

    Verma, D.K.; Julian, J.A.; Roberts, R.S.; Muir, D.C.; Jadon, N.; Shaw, D.S. )

    1992-05-01

    A retrospective industrial hygiene investigation was undertaken to explain the cause of a statistically significant excess lung cancer mortality observed in a subset of a large cohort of nickel workers involved in mining, smelting, and refining of nickel and copper in Ontario. The focus of this paper is to demonstrate how an industrial hygiene follow-up assessment of an epidemiologic finding can help to identify a likely cause. Polycyclic aromatic hydrocarbons (PAHs) alone or in association with particulate and gaseous contaminants (e.g., SO2) were likely the causative agents of the excess lung cancer observed among the lead welders, cranemen, and arc furnace workers of the copper refinery.

  5. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  6. Methods and apparatus for carbon dioxide removal from a fluid stream

    DOE Patents [OSTI]

    Wei, Wei; Ruud, James Anthony; Ku, Anthony Yu-Chung; Ramaswamy, Vidya; Liu, Ke

    2010-01-19

    An apparatus for producing hydrogen gas wherein the apparatus includes a reactor. In one embodiment, the reactor includes at least two conversion-removal portions. Each conversion-removal portion comprises a catalyst section configured to convert CO in the stream to CO.sub.2 and a membrane section located downstream of and in flow communication with the catalyst section. The membrane section is configured to selectively remove the CO.sub.2 from the stream and to be in flow communication with a sweep gas.

  7. Apparatus for preventing particle deposition from process streams on optical access windows

    DOE Patents [OSTI]

    Logan, Ronald G.; Grimm, Ulrich

    1993-01-01

    An electrostatic precipitator is disposed inside and around the periphery of the window of a viewing port communicating with a housing through which a particle-laden gas stream is being passed. The precipitator includes a pair of electrodes around the periphery of the window, spaced apart and connected to a unidirectional voltage source. Application of high voltage from the source to the electrodes causes air molecules in the gas stream to become ionized, attaching to solid particles and causing them to be deposited on a collector electrode. This prevents the particles from being deposited on the window and keeps the window clean for viewing and making optical measurements.

  8. Synthesis and development of processes for the recovery of sulfur from acid gases. Part 1, Development of a high-temperature process for removal of H{sub 2}S from coal gas using limestone -- thermodynamic and kinetic considerations; Part 2, Development of a zero-emissions process for recovery of sulfur from acid gas streams

    SciTech Connect (OSTI)

    Towler, G.P.; Lynn, S.

    1993-05-01

    Limestone can be used more effectively as a sorbent for H{sub 2}S in high-temperature gas-cleaning applications if it is prevented from undergoing calcination. Sorption of H{sub 2}S by limestone is impeded by sintering of the product CaS layer. Sintering of CaS is catalyzed by CO{sub 2}, but is not affected by N{sub 2} or H{sub 2}. The kinetics of CaS sintering was determined for the temperature range 750--900{degrees}C. When hydrogen sulfide is heated above 600{degrees}C in the presence of carbon dioxide elemental sulfur is formed. The rate-limiting step of elemental sulfur formation is thermal decomposition of H{sub 2}S. Part of the hydrogen thereby produced reacts with CO{sub 2}, forming CO via the water-gas-shift reaction. The equilibrium of H{sub 2}S decomposition is therefore shifted to favor the formation of elemental sulfur. The main byproduct is COS, formed by a reaction between CO{sub 2} and H{sub 2}S that is analogous to the water-gas-shift reaction. Smaller amounts of SO{sub 2} and CS{sub 2} also form. Molybdenum disulfide is a strong catalyst for H{sub 2}S decomposition in the presence of CO{sub 2}. A process for recovery of sulfur from H{sub 2}S using this chemistry is as follows: Hydrogen sulfide is heated in a high-temperature reactor in the presence of CO{sub 2} and a suitable catalyst. The primary products of the overall reaction are S{sub 2}, CO, H{sub 2} and H{sub 2}O. Rapid quenching of the reaction mixture to roughly 600{degrees}C prevents loss Of S{sub 2} during cooling. Carbonyl sulfide is removed from the product gas by hydrolysis back to CO{sub 2} and H{sub 2}S. Unreacted CO{sub 2} and H{sub 2}S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H{sub 2} and CO, which recovers the hydrogen value from the H{sub 2}S. This process is economically favorable compared to the existing sulfur-recovery technology and allows emissions of sulfur-containing gases to be controlled to very low levels.

  9. GLOBULAR CLUSTERS AND DARK SATELLITE GALAXIES THROUGH THE STREAM VELOCITY

    SciTech Connect (OSTI)

    Naoz, Smadar; Narayan, Ramesh

    2014-08-10

    The formation of purely baryonic globular clusters with no gravitationally bound dark matter is still a theoretical challenge. We show that these objects might form naturally whenever there is a relative stream velocity between baryons and dark matter. The stream velocity causes a phase shift between linear modes of baryonic and dark matter perturbations, which translates to a spatial offset between the two components when they collapse. For a 2σ (3σ) density fluctuation, baryonic clumps with masses in the range 10{sup 5}-2.5 × 10{sup 6} M {sub ☉} (10{sup 5}-4 × 10{sup 6} M {sub ☉}) collapse outside the virial radii of their counterpart dark matter halos. These objects could survive as long-lived, dark-matter-free objects and might conceivably become globular clusters. In addition, their dark matter counterparts, which were deprived of gas, might become dark satellite galaxies.

  10. Microsoft PowerPoint - Tritium Gas Stream Scrubbing using In...

    Office of Environmental Management (EM)

    ... Equipment Solid State Sintered Pellets * Mix elemental powders * Compact in 13 mm die * Sinter in Argon * Characterize Bronze Pellets Before and After Zinc Bottom Top First ...

  11. Sour Gas Streams Safe for Carbon Sequestration, DOE-Sponsored...

    Office of Environmental Management (EM)

    and storage (CCS), according to results from a field test completed by the Plains CO2 Reduction (PCOR) Partnership. The test by PCOR--one of seven members of the U.S. Department ...

  12. Method for removal of mercury from various gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2003-06-10

    The invention provides for a method for removing elemental mercury from a fluid, the method comprising irradiating the mercury with light having a wavelength of approximately 254 nm. The method is implemented in situ at various fuel combustion locations such as power plants and municipal incinerators.

  13. Tritium Gas Stream Scrubbing using In-situ Reactive Materials

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation from the 36th Tritium Focus Group Meeting held in Los Alamos, New Mexico, November 3-5, 2015.

  14. Silver-Mordenite for Radiologic Gas Capture from Complex Streams...

    Office of Scientific and Technical Information (OSTI)

    Resource Type: Journal Article Resource Relation: Journal Name: Microporous and Mesoporous Materials; Journal Volume: 200 Research Org: Idaho National Laboratory (INL) Sponsoring ...

  15. Metal oxide membranes for gas separation

    DOE Patents [OSTI]

    Anderson, M.A.; Webster, E.T.; Xu, Q.

    1994-08-30

    A method for formation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation. 4 figs.

  16. Metal oxide membranes for gas separation

    DOE Patents [OSTI]

    Anderson, Marc A.; Webster, Elizabeth T.; Xu, Qunyin

    1994-01-01

    A method for permformation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation.

  17. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, Charles L.; He, Bo X.

    1990-01-01

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from when it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel.

  18. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, C.L.; He, B.X.

    1990-11-13

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from where it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel. 4 figs.

  19. Excess fuel gas. Recover H/sub 2//LPG

    SciTech Connect (OSTI)

    Banks, R.; Isalski, W.H.

    1987-10-01

    Refiners have traditionally been isolated from low temperature cryogenic processing. Energy conservation measures can be complemented by highly efficient cryogenic turbo-expander technology to remove almost all C/sub 3/ and C/sub 4/ components from the fuel header in a separated modular gas processing plant. When appropriate, ethane and ethylene can be accommodated by this technology without the necessity for revamp of existing equipment. The wide experience of cryogenic technology worldwide makes it an excellent means of improving refinery efficiency.

  20. Advanced IGCC/Hydrogen Gas Turbine Development

    SciTech Connect (OSTI)

    York, William; Hughes, Michael; Berry, Jonathan; Russell, Tamara; Lau, Y. C.; Liu, Shan; Arnett, Michael; Peck, Arthur; Tralshawala, Nilesh; Weber, Joseph; Benjamin, Marc; Iduate, Michelle; Kittleson, Jacob; Garcia-Crespo, Andres; Delvaux, John; Casanova, Fernando; Lacy, Ben; Brzek, Brian; Wolfe, Chris; Palafox, Pepe; Ding, Ben; Badding, Bruce; McDuffie, Dwayne; Zemsky, Christine

    2015-07-30

    The objective of this program was to develop the technologies required for a fuel flexible (coal derived hydrogen or syngas) gas turbine for IGCC that met DOE turbine performance goals. The overall DOE Advanced Power System goal was to conduct the research and development (R&D) necessary to produce coal-based IGCC power systems with high efficiency, near-zero emissions, and competitive capital cost. To meet this goal, the DOE Fossil Energy Turbine Program had as an interim objective of 2 to 3 percentage points improvement in combined cycle (CC) efficiency. The final goal is 3 to 5 percentage points improvement in CC efficiency above the state of the art for CC turbines in IGCC applications at the time the program started. The efficiency goals were for NOx emissions of less than 2 ppm NOx (@15 % O2). As a result of the technologies developed under this program, the DOE goals were exceeded with a projected 8 point efficiency improvement. In addition, a new combustion technology was conceived of and developed to overcome the challenges of burning hydrogen and achieving the DOE’s NOx goal. This report also covers the developments under the ARRA-funded portion of the program that include gas turbine technology advancements for improvement in the efficiency, emissions, and cost performance of gas turbines for industrial applications with carbon capture and sequestration. Example applications could be cement plants, chemical plants, refineries, steel and aluminum plants, manufacturing facilities, etc. The DOE’s goal for more than 5 percentage point improvement in efficiency was met with cycle analyses performed for representative IGCC Steel Mill and IGCC Refinery applications. Technologies were developed in this program under the following areas: combustion, larger latter stage buckets, CMC and EBC, advanced materials and coatings, advanced configurations to reduce cooling, sealing and rotor purge flows, turbine aerodynamics, advanced sensors, advancements in first

  1. Use of ammonia to reduce the viscosity of bottoms streams produced in hydroconversion processes

    DOE Patents [OSTI]

    Zaczepinski, Sioma; Billimoria, Rustom M.; Tao, Frank; Lington, Christopher G.; Plumlee, Karl W.

    1984-01-01

    Coal, petroleum residuum and similar carbonaceous feed materials are subjected to hydroconversion in the presence of molecular hydrogen to produce a hydroconversion effluent which is then subjected to one or more separation steps to remove lower molecular weight liquids and produce a heavy bottoms stream containing high molecular weight liquids and unconverted carbonaceous material. The viscosity of the bottoms streams produced in the separation step or steps is prevented from increasing rapidly by treating the feed to the separation step or steps with ammonia gas prior to or during the separation step or steps. The viscosity of the heavy bottoms stream produced in the final separation step is also controlled by treating these bottoms with ammonia gas. In a preferred embodiment of the invention, the effluent from the hydroconversion reactor is subjected to an atmospheric distillation followed by a vacuum distillation and the feeds to these distillations are contacted with ammonia during the distillations.

  2. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M.; Bingham, Dennis N.; McKellar, Michael G.; Turner, Terry D.; Raterman, Kevin T.; Palmer, Gary L.; Klingler, Kerry M.; Vranicar, John J.

    2007-05-22

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO.sub.2) clean-up cycle.

  3. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M.; Bingham, Dennis N.; McKellar, Michael G.; Turner, Terry D.; Rateman, Kevin T.; Palmer, Gary L.; Klinger, Kerry M.; Vranicar, John J.

    2005-11-08

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.

  4. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M.; Bingham, Dennis N.; McKellar, Michael G.; Turner, Terry D.; Raterman, Kevin T.; Palmer, Gary L.; Klingler, Kerry M.; Vranicar, John J.

    2005-05-03

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.

  5. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M.; Bingham, Dennis N.; McKellar, Michael G.; Turner, Terry D.; Raterman, Kevin T.; Palmer, Gary L.; Klingler, Kerry M.; Vranicar, John J.

    2003-06-24

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO.sub.2) clean-up cycle.

  6. National emission standards for hazardous air pollutants petroleum refineries. Background information for final standards. Summary of public comments and responses. Final report

    SciTech Connect (OSTI)

    1995-07-01

    National emission standards for hazardous air pollutants (NESHAP) are promulgated for the petroleum refinery industry under authority of section 112 of the Clean Air Act. This background information document provides technical information and analyses used in the development of the final NESHAP and Agency reponses to public comments on the proposed rule.

  7. DeepStream Technologies | Open Energy Information

    Open Energy Info (EERE)

    Place: Bangor, United Kingdom Zip: LL57 4EZ Product: DeepStream Technologies produces digital sensors and controls that measure, monitor, and manage energy usage. References:...

  8. Solnechniy Potok Solar Stream | Open Energy Information

    Open Energy Info (EERE)

    Russian Federation Sector: Solar Product: Russia-based solar project developer and module manufacturer. References: Solnechniy Potok (Solar Stream)1 This article is a stub....

  9. Studies of charging stream trajectories and burden distribution in the blast furnace

    SciTech Connect (OSTI)

    McCarthy, M.J.; Mayfield, P.L.; Zulli, P.; Rex, A.J.; Tanzil, W.B.U.

    1993-01-01

    This work discusses the sensitivity of key blast furnace performance parameters to different gas flow distributions achieved by altering the burden distribution. The changes in burden distribution are brought about by different charging stream trajectories, and methods developed and evaluated for measuring the trajectories both on and off line are described.

  10. Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, WanWang

    2010-08-10

    The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

  11. Deposition of device quality, low hydrogen content, amorphous silicon films by hot filament technique using "safe" silicon source gas

    DOE Patents [OSTI]

    Mahan, Archie Harvin; Molenbroek, Edith C.; Nelson, Brent P.

    1998-01-01

    A method of producing hydrogenated amorphous silicon on a substrate by flowing a stream of safe (diluted to less than 1%) silane gas past a heated filament.

  12. Position sensitive radioactivity detection for gas and liquid chromatography

    DOE Patents [OSTI]

    Cochran, Joseph L.; McCarthy, John F.; Palumbo, Anthony V.; Phelps, Tommy J.

    2001-01-01

    A method and apparatus are provided for the position sensitive detection of radioactivity in a fluid stream, particularly in the effluent fluid stream from a gas or liquid chromatographic instrument. The invention represents a significant advance in efficiency and cost reduction compared with current efforts.

  13. Removing H/sub 2/S from natural gas using two-stage molecular sieves

    SciTech Connect (OSTI)

    Larson, H. A.; Boehme, M. F.; Sheets, J. W.

    1985-06-11

    An integrated process for removal of hydrogen sulfide and water from a natural gas stream by contacting a natural gas stream containing hydrogen sulfide, water, and CO/sub 2/ with molecular sieves that act both as an adsorbent for hydrogen sulfide and water and as a catalyst for the reaction for conversion of hydrogen sulfide and carbon dioxide to carbonyl sulfide. About 92 to about 95 volume percent of an inlet natural gas stream is passed into contact with molecular sieves to produce a salable gas. A portion of this salable gas is used as regeneration fluid for the molecular sieve contactors and the regeneration gas effluent from the regeneration process is diluted with the remainder of the inlet gas stream and subjected to further adsorption/conversion contact with molecular sieves to produce salable gas that is mixed with the first treated gas stream. Depending upon the degree of compression of the regeneration gas effluent from the regenration operation, the integrated system can be operated with two phases of adsorption or with a single phase of adsorption of mixed streams of inlet gas and regeneration gas.

  14. Removal of fluoride impurities from UF.sub.6 gas

    DOE Patents [OSTI]

    Beitz, James V.

    1985-01-01

    A method of purifying a UF.sub.6 gas stream containing one or more metal fluoride impurities composed of a transuranic metal, transition metal or mixtures thereof, is carried out by contacting the gas stream with a bed of UF.sub.5 in a reaction vessel under conditions where at least one impurity reacts with the UF.sub.5 to form a nongaseous product and a treated gas stream, and removing the treated gas stream from contact with the bed. The nongaseous products are subsequently removed in a reaction with an active fluorine affording agent to form a gaseous impurity which is removed from the reaction vessel. The bed of UF.sub.5 is formed by the reduction of UF.sub.6 in the presence of UV light. One embodiment of the reaction vessel includes a plurality of UV light sources as tubes on which UF.sub.5 is formed.

  15. Removal of fluoride impurities from UF/sub 6/ gas

    DOE Patents [OSTI]

    Beitz, J.V.

    1984-01-06

    A method of purifying a UF/sub 6/ gas stream containing one or more metal fluoride impurities composed of a transuranic metal, transition metal or mixtures thereof, is carried out by contacting the gas stream with a bed of UF/sub 5/ in a reaction vessel under conditions where at least one impurity reacts with the UF/sub 5/ to form a nongaseous product and a treated gas stream, and removing the treated gas stream from contact with the bed. The nongaseous products are subsequently removed in a reaction with an active fluorine affording agent to form a gaseous impurity which is removed from the reaction vessel. The bed of UF/sub 5/ is formed by the reduction of UF/sub 6/ in the presence of uv light. One embodiment of the reaction vessel includes a plurality of uv light sources as tubes on which UF/sub 5/ is formed. 2 figures.

  16. Safe welding and cutting practices in refineries, gasoline plants, and petrochemical plants

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    In this standard, suggested precautions are outlined for the protection of persons from injury and for the protection of property from damage by fire which might arise during the operation of gas and electric cutting and welding equipment in and around petroleum operations.

  17. Streams-C Scheduler and Library

    Energy Science and Technology Software Center (OSTI)

    2001-12-04

    The scheduler accepts a preprocessed C program with optional Streams-C extensions. It translates it to a normalized form with additional information for scheduling it on a reconfigurable architecture. The resulting file is accepted by the Streams-C VHDL generator, not part of this package.

  18. El Paso, TX Natural Gas Exports to Mexico

    Gasoline and Diesel Fuel Update (EIA)

    Administration (EIA) definitions English FranÇais Español A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Browse terms related to these categories: border crossing electricity border crossing gas border crossing liquid liquefied natural gas terminals natural gas processing plants power plants refineries See index of all terms A

    Referencia cruzada de definición English FranÇais Español A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Explorar los términos relacionados con las

  19. High temperature desulfurization of synthesis gas

    DOE Patents [OSTI]

    Najjar, Mitri S.; Robin, Allen M.

    1989-01-01

    The hot process gas stream from the partial oxidation of sulfur-containing heavy liquid hydrocarbonaceous fuel and/or sulfur-containing solid carbonaceous fuel comprising gaseous mixtures of H.sub.2 +CO, sulfur-containing gases, entrained particulate carbon, and molten slag is passed through the unobstructed central passage of a radiant cooler where the temperature is reduced to a temperature in the range of about 1800.degree. F. to 1200.degree. F. From about 0 to 95 wt. % of the molten slag and/or entrained material may be removed from the hot process gas stream prior to the radiant cooler with substantially no reduction in temperature of the process gas stream. In the radiant cooler, after substantially all of the molten slag has solidified, the sulfur-containing gases are contacted with a calcium-containing material to produce calcium sulfide. A partially cooled stream of synthesis gas, reducing gas, or fuel gas containing entrained calcium sulfide particulate matter, particulate carbon, and solidified slag leaves the radiant cooler containing a greatly reduced amount of sulfur-containing gases.

  20. Activation of catalysts for synthesizing methanol from synthesis gas

    DOE Patents [OSTI]

    Blum, David B.; Gelbein, Abraham P.

    1985-01-01

    A method for activating a methanol synthesis catalyst is disclosed. In this method, the catalyst is slurried in an inert liquid and is activated by a reducing gas stream. The activation step occurs in-situ. That is, it is conducted in the same reactor as is the subsequent step of synthesizing methanol from a methanol gas stream catalyzed by the activated catalyst still dispersed in a slurry.

  1. Total Supplemental Supply of Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Supplemental Supply Synthetic Propane-Air Refinery Gas Biomass Other Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History U.S. 64,575 60,088 61,366 54,650 59,528 58,555 1980-2015 Alabama 0 0 0 0 0 1967-2014 Alaska 0 0 0 0 0 2004-2014 Arizona 0 0 0 0 0 1967-2014 Arkansas 0 0 0 0 0 1967-2014 Colorado 5,148 4,268 4,412 4,077 4,120

  2. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha; Meyer, Howard S.; Lynn, Scott; Leppin, Dennis; Wangerow, James R.

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  3. Superconductor fiber elongation with a heated injected gas

    DOE Patents [OSTI]

    Zeigler, D.D.; Conrad, B.L.; Gleixner, R.A.

    1998-06-02

    An improved method and apparatus for producing flexible fibers of superconducting material includes a crucible for containing a charge of the superconducting material. The material is melted in the crucible and falls in a stream through a bottom hole in the crucible. The stream falls through a protecting collar which maintains the stream at high temperatures. The stream is then supplied through a downwardly directed nozzle where it is subjected to a high velocity of a heated gas which breaks the melted superconducting material into ligaments which solidify into the flexible fibers. The fibers are collected by directing them against a collection filter. 10 figs.

  4. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  5. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W.

    1981-01-01

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  6. Combustion of dense streams of coal particles. Final report, August 29, 1990--February 28, 1994

    SciTech Connect (OSTI)

    Annamalai, K.; Gopalakrishnan, C.; Du, X.

    1994-05-01

    The USA consumes almost 94 quads of energy (1 quad = 10{sup 15} BTU or 1.05 {times} 10{sup 15} KJ). The utilities account for about 30 quads of fossil energy where coal is predominantly used as energy source. The coal is ground to finer size and fired into the boiler as dense suspension. Under dense conditions, the particles burn at slower rate due to deficient oxygen within the interparticle spacing. Thus interactions exist amongst the particles for dense clouds. While the earlier literature dealt with combustion processes of isolated particles, the recent research focusses upon the interactive combustion. The interactive combustion studies include arrays consisting of a finite number of particles, and streams and clouds of a large number of particles. Particularly stream combustion models assume cylindrical geometry and predict the ignition and combustion characteristics. The models show that the ignition starts homogeneously for dense streams of coal particles and the ignition time show a minimum as the stream denseness is increased, and during combustion, there appears to be an inner flame within the stream and an outer flame outside the stream for a short period of time. The present experimental investigation is an attempt to verify the model predictions. The set-up consists of a flat flame burner for producing hot vitiated gases, a locally fluidizing feeder system for feeding coal particles, a particle collection probe for collecting particles and an image processing system for analyzing the flame structure. The particles are introduced as a stream into the hot gases and subsequently they ignite and burn. The ash % of fired and collected particles are determined and used to estimate the gasification efficiency or burnt fraction. The parametric studies include gas temperature, oxygen % in gases, residence time, and A:F ratio of the stream.

  7. Evaluation of Side Stream Filtration Technology at Oak Ridge National

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory | Department of Energy Evaluation of Side Stream Filtration Technology at Oak Ridge National Laboratory Evaluation of Side Stream Filtration Technology at Oak Ridge National Laboratory Document provides an in-depth look at side stream filtration at Oak Ridge National Laboratory. Download the Side Stream Filtration evaluation document. (1.48 MB) More Documents & Publications Side Stream Filtration for Cooling Towers Technical Evaluation of Side Stream Filtration for Cooling

  8. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, J. Richard

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  9. Time-Based Data Streams: Fundamental Concepts for a Data Resource for Streams

    SciTech Connect (OSTI)

    Beth A. Plale

    2009-10-10

    Real time data, which we call data streams, are readings from instruments, environmental, bodily or building sensors that are generated at regular intervals and often, due to their volume, need to be processed in real time. Often a single pass is all that can be made on the data, and a decision to discard or keep the instance is made on the spot. Too, the stream is for all practical purposes indefinite, so decisions must be made on incomplete knowledge. This notion of data streams has a different set of issues from a file, for instance, that is byte streamed to a reader. The file is finite, so the byte stream is becomes a processing convenience more than a fundamentally different kind of data. Through the duration of the project we examined three aspects of streaming data: the first, techniques to handle streaming data in a distributed system organized as a collection of web services, the second, the notion of the dashboard and real time controllable analysis constructs in the context of the Fermi Tevatron Beam Position Monitor, and third and finally, we examined provenance collection of stream processing such as might occur as raw observational data flows from the source and undergoes correction, cleaning, and quality control. The impact of this work is severalfold. We were one of the first to advocate that streams had little value unless aggregated, and that notion is now gaining general acceptance. We were one of the first groups to grapple with the notion of provenance of stream data also.

  10. MHK Technologies/Pulse Stream 100 | Open Energy Information

    Open Energy Info (EERE)

    database homepage Pulse Stream 100.jpg Technology Profile Primary Organization Pulse Tidal Ltd Project(s) where this technology is utilized *MHK ProjectsPulse Stream 100...

  11. Assessing Revenue Streams: What Is Right for Your Program? |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessing Revenue Streams: What Is Right for Your Program? Assessing Revenue Streams: What Is Right for Your Program? Program Sustainability Peer Exchange Call: Assessing Revenue ...

  12. Evaluation of Side Stream Filtration Technology at Oak Ridge...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of Side Stream Filtration Technology at Oak Ridge National Laboratory Evaluation of Side Stream Filtration Technology at Oak Ridge National Laboratory Document provides ...

  13. China Stream Fund Solar Energy JV | Open Energy Information

    Open Energy Info (EERE)

    Solar Energy JV Jump to: navigation, search Name: China Stream Fund Solar Energy JV Place: Changzhou, Jiangsu Province, China Zip: 213000 Product: JV between Stream High-Technology...

  14. Tracking and Using Data to Support Revenue Streams | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracking and Using Data to Support Revenue Streams Better Buildings Neighborhood Program Data and Evaluation Peer Exchange Call: Tracking and Using Data to Support Revenue Streams, ...

  15. VEBA-cracking-processes for upgrading heavy oils and refinery residues

    SciTech Connect (OSTI)

    Graeser, U.; Niemann, K.

    1983-03-01

    More than 20 different heavy oils and residues have been processed by the VEBA-Combi-Cracking and VEBA-LQ-Cracking high pressure hydrocracking processes, in a bench scale unit. Conversions up to 99 wt % of to a syncrude, consisting of naphtha middle distillate and vacuum gas oil were obtained. Conversions correlate with space velocity at a given temperature and product pattern depends upon degree of conversion. The VEBA-LQ-Cracking process produces a stable syncrude whereas the products of the VEBA-Combi process are very low in sulfur and nitrogen.

  16. Discharge source with gas curtain for protecting optics from particles

    DOE Patents [OSTI]

    Fornaciari, Neal R.; Kanouff, Michael P.

    2004-03-30

    A gas curtain device is employed to deflect debris that is generated by an extreme ultraviolet and soft x-ray radiation discharge source such as an electric discharge plasma source. The gas curtain device projects a stream of gas over the path of the radiation to deflect debris particles into a direction that is different from that of the path of the radiation. The gas curtain can be employed to prevent debris accumulation on the optics used in photolithography.

  17. Plentiful natural gas headed for big growth in Mideast

    SciTech Connect (OSTI)

    Hamid, S.H.; Aitani, A.M. )

    1995-01-23

    Natural gas is increasingly becoming a major contributor in the industrial development of most Middle Eastern countries. Demand there will rise steeply in coming years. This is because of the abundant and growing natural gas resources in the region, the economic benefits of using local resources, as well as increased emphasis on a cleaner environment. Today, proved reserves of natural gas in the Middle East are 45 trillion cu meters (tcm), or 1,488 trillion cu ft (tcf). This is over 30% of the world's natural gas reserves. A table presents data on reserves and production of natural gas in the region. About 20% of this gross production is rein-injecting for oil field pressure maintenance, 13% is flared or vented, and 7% is accounted as losses. The remaining 60% represents consumption in power generation, water desalination, petrochemicals and fertilizers production, aluminum and copper smelting, and fuel for refineries and other industries. The use of natural gas in these various industries is discussed. Thirteen tables present data on gas consumption by country and sector, power generation capacity, major chemicals derived from natural gas, and petrochemical plant capacities.

  18. A dynamically reconfigurable data stream processing system

    SciTech Connect (OSTI)

    Nogiec, J.M.; Trombly-Freytag, K.; /Fermilab

    2004-11-01

    This paper describes a component-based framework for data stream processing that allows for configuration, tailoring, and runtime system reconfiguration. The system's architecture is based on a pipes and filters pattern, where data is passed through routes between components. A network of pipes and filters can be dynamically reconfigured in response to a preplanned sequence of processing steps, operator intervention, or a change in one or more data streams. This framework provides several mechanisms supporting dynamic reconfiguration and can be used to build static data stream processing applications such as monitoring or data acquisition systems, as well as self-adjusting systems that can adapt their processing algorithm, presentation layer, or data persistency layer in response to changes in input data streams.

  19. Appendix F Stream Flow.xls

    Office of Legacy Management (LM)

    ... begins at T01-27. Noticably less flow than station Appendix F Stream Flow Measurement Results Since 2000 Collect Date Surface ID Calculated Flow (ft 3 sec) Comments 812001 ...

  20. Produce diesel from gas

    SciTech Connect (OSTI)

    Singleton, A.H.; Regier, S.

    1983-05-01

    The Gulf Badger process converts natural gas directly to hydrocarbon liquids by a catalytic chemical route. Fischer-Tropsch process--which is a carbon monoxide polymerization/ hydrogenation process--is used. Because the process is exothermal, heat removal by either tubular fixed bed, fluidized bed, or slurry are considered. A wax build up of high molecular weight material is removed by hydro-stripping two-bed system. The demonstration plant flow diagram shows the process to be: natural gas is compressed, recycled with CO/sub 2/, sulfur is removed in a zinc oxide drum, CO is removed in amine scrubbers, H/sub 2//CO ratio is adjusted to produce a hydrogen rich stream, and stabilization and distribution follow. A monitoring system using computers is part of the demonstration unit.

  1. Side Stream Filtration for Cooling Towers

    SciTech Connect (OSTI)

    2012-10-20

    This technology evaluation assesses side stream filtration options for cooling towers, with an objective to assess key attributes that optimize energy and water savings along with providing information on specific technology and implementation options. This information can be used to assist Federal sites to determine which options may be most appropriate for their applications. This evaluation provides an overview of the characterization of side stream filtration technology, describes typical applications, and details specific types of filtration technology.

  2. Apparatus for dispensing compressed natural gas and liquified natural gas to natural gas powered vehicles

    SciTech Connect (OSTI)

    Bingham, Dennis A.; Clark, Michael L.; Wilding, Bruce M.; Palmer, Gary L.

    2007-05-29

    A fueling facility and method for dispensing liquid natural gas (LNG), compressed natural gas (CNG) or both on-demand. The fueling facility may include a source of LNG, such as cryogenic storage vessel. A low volume high pressure pump is coupled to the source of LNG to produce a stream of pressurized LNG. The stream of pressurized LNG may be selectively directed through an LNG flow path or to a CNG flow path which includes a vaporizer configured to produce CNG from the pressurized LNG. A portion of the CNG may be drawn from the CNG flow path and introduced into the CNG flow path to control the temperature of LNG flowing therethrough. Similarly, a portion of the LNG may be drawn from the LNG flow path and introduced into the CNG flow path to control the temperature of CNG flowing therethrough.

  3. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    2008-12-01

    General Electric Global Research will define, develop, and test new fuel nozzle technology concepts for gas turbine operation on a wide spectrum of opportunity fuels and/or fuel blends. This will enable gas turbine operation on ultra-low Btu fuel streams such as very weak natural gas, highly-diluted industrial process gases, or gasified waste streams that are out of the capability range of current turbine systems.

  4. THE COS/UVES ABSORPTION SURVEY OF THE MAGELLANIC STREAM. II. EVIDENCE FOR A COMPLEX ENRICHMENT HISTORY OF THE STREAM FROM THE FAIRALL 9 SIGHTLINE

    SciTech Connect (OSTI)

    Richter, Philipp; Fechner, Cora [Institut fuer Physik und Astronomie, Universitaet Potsdam, Haus 28, Karl-Liebknecht-Str. 24/25, D-14476 Golm (Potsdam) (Germany); Fox, Andrew J. [Space Telescope Science Institute, Baltimore, MD 21218 (United States); Wakker, Bart P. [Department of Astronomy, University of Wisconsin-Madison, 475 North Charter Street, Madison, WI 53706 (United States); Lehner, Nicolas; Howk, J. Christopher [Department of Physics, University of Notre Dame, 225 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Bland-Hawthorn, Joss [Institute of Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Ben Bekhti, Nadya [Argelander-Institut fuer Astronomie, Universitaet Bonn, Auf dem Huegel 71, D-53121 Bonn (Germany)

    2013-08-01

    We present a multi-wavelength study of the Magellanic Stream (MS), a massive gaseous structure in the Local Group that is believed to represent material stripped from the Magellanic Clouds. We use ultraviolet, optical and radio data obtained with HST/COS, VLT/UVES, FUSE, GASS, and ATCA to study metal abundances and physical conditions in the Stream toward the quasar Fairall 9. Line absorption in the MS from a large number of metal ions and from molecular hydrogen is detected in up to seven absorption components, indicating the presence of multi-phase gas. From the analysis of unsaturated S II absorption, in combination with a detailed photoionization model, we obtain a surprisingly high {alpha} abundance in the Stream toward Fairall 9 of [S/H] = -0.30 {+-} 0.04 (0.50 solar). This value is five times higher than what is found along other MS sightlines based on similar COS/UVES data sets. In contrast, the measured nitrogen abundance is found to be substantially lower ([N/H] = -1.15 {+-} 0.06), implying a very low [N/{alpha}] ratio of -0.85 dex. The substantial differences in the chemical composition of MS toward Fairall 9 compared to other sightlines point toward a complex enrichment history of the Stream. We favor a scenario, in which the gas toward Fairall 9 was locally enriched with {alpha} elements by massive stars and then was separated from the Magellanic Clouds before the delayed nitrogen enrichment from intermediate-mass stars could set in. Our results support (but do not require) the idea that there is a metal-enriched filament in the Stream toward Fairall 9 that originates in the LMC.

  5. Influence of a combustion-driven oscillation on global mixing in the flame from a refinery flare

    SciTech Connect (OSTI)

    Langman, A.S.; Nathan, G.J.

    2011-01-15

    An assessment of the influence of strong combustion-driven oscillations on mixing rates and visible radiation in the flame from a full-scale refinery flare is reported. Importantly, the oscillations were generated naturally, with no external forcing, and at a high Reynolds number of 4 x 10{sup 6}. These conditions differentiate this study from those of previous investigations, which all involved some external forcing and were at a Re too low to ensure fully turbulent flow within the flame. A frame-by-frame analysis of video footage, providing good resolution of the instantaneous edge of each flame, was used to assess flame dimensions, and so to determine a global residence time. Since the flames are in the fast-chemistry regime, the visual imagers can be used to determine a global mixing rate. The analysis reveals a consistent picture that the combustion-driven oscillations do not result in a significant change to the global mixing rate, but do increase the visible radiation. This is in contrast to previous investigations, using externally forced jets, where forcing at the preferred mode has been found to increase mixing rates and reduce radiation. (author)

  6. Strategic planning for and implementation of reclaimed municipal waste water as make-up to a refinery cooling system

    SciTech Connect (OSTI)

    Francis, W.R.; Mazur, J.J.; Rao, N.M.

    1996-08-01

    This paper discusses the successful use of treated municipal plant waste water effluent (Title 22) in a refinery cooling water system. Conversion from well water to this make-up water source was preceded by developing a carefully crafted transition plan. Steps were taken to identify key system performance indicators, establish desired performance goals, and implement stringent monitoring and control protocols. In addition, all possible contingencies were considered and solutions developed. Treating Title 22 waters is very challenging and entails risks not associated with normal makeup waters. Several novel on-line monitoring and control tools are available which help minimize these risks while enhancing tower operation. Performance monitoring of critical system parameters is essential in order to provide early warning of problems so that corrective measures can be implemented. In addition, a high level of system automation enhances reliable operation. Corrosion, scaling and microbiological performance of the system with Title 22 water is discussed in comparison to previous well water make-up.

  7. Methanol production from eucalyptus wood chips. Attachment III. Florida's eucalyptus energy farm and methanol refinery: the background environment

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-04-01

    A wide array of general background information is presented on the Central Florida area in which the eucalyptus energy plantation and methanol refinery will be located. Five counties in Central Florida may be affected by the project, DeSoto, Hardee, Hillsborough, Manatee, and Polk. The human resources of the area are reviewed. Included are overviews of population demographic and economic trends. Land use patterns and the transportation are system described, and the region's archeological and recreational resources are evaluated. The region's air quality is emphasized. The overall climate is described along with noise and air shed properties. An analysis of the region's water resources is included. Ground water is discussed first followed by an analysis of surface water. Then the overall quality and water supply/demand balance for the area is evaluated. An overview of the region's biota is presented. Included here are discussions of the general ecosystems in Central Florida, and an analysis of areas with important biological significance. Finally, land resources are examined.

  8. Process for removing metal carbonyls from gaseous streams

    SciTech Connect (OSTI)

    Heyd, R.L.; Pignet, T.P.

    1988-04-26

    A process for removing metal carbonyl contaminates from a gaseous stream is described containing such contaminates and which is free from sulfur contaminates, which process comprises contacting the gaseous stream with a zinc sulfide absorbent to thereby remove metal carbonyl contaminates from the gaseous stream, and separating the gaseous stream from the zinc sulfide absorbent.

  9. Method of CO.sub.2 removal from a gasesous stream at reduced temperature

    DOE Patents [OSTI]

    Fisher, James C; Siriwardane, Ranjani V; Berry, David A; Richards, George A

    2014-11-18

    A method for the removal of H.sub.2O and CO.sub.2 from a gaseous stream comprising H.sub.2O and CO.sub.2, such as a flue gas. The method initially utilizes an H.sub.2O removal sorbent to remove some portion of the H.sub.2O, producing a dry gaseous stream and a wet H.sub.2O removal sorbent. The dry gaseous stream is subsequently contacted with a CO.sub.2 removal sorbent to remove some portion of the CO.sub.2, generating a dry CO.sub.2 reduced stream and a loaded CO.sub.2 removal sorbent. The loaded CO.sub.2 removal sorbent is subsequently heated to produce a heated CO.sub.2 stream. The wet H.sub.2O removal sorbent and the dry CO.sub.2 reduced stream are contacted in a first regeneration stage, generating a partially regenerated H.sub.2O removal sorbent, and the partially regenerated H.sub.2O removal sorbent and the heated CO.sub.2 stream are subsequently contacted in a second regeneration stage. The first and second stage regeneration typically act to retain an initial monolayer of moisture on the various removal sorbents and only remove moisture layers bound to the initial monolayer, allowing for relatively low temperature and pressure operation. Generally the applicable H.sub.2O sorption/desorption processes may be conducted at temperatures less than about 70.degree. C. and pressures less than 1.5 atmospheres, with certain operations conducted at temperatures less than about 50.degree. C.

  10. Method of controlling injection of oxygen into hydrogen-rich fuel cell feed stream

    DOE Patents [OSTI]

    Meltser, Mark Alexander; Gutowski, Stanley; Weisbrod, Kirk

    2001-01-01

    A method of operating a H.sub.2 --O.sub.2 fuel cell fueled by hydrogen-rich fuel stream containing CO. The CO content is reduced to acceptable levels by injecting oxygen into the fuel gas stream. The amount of oxygen injected is controlled in relation to the CO content of the fuel gas, by a control strategy that involves (a) determining the CO content of the fuel stream at a first injection rate, (b) increasing the O.sub.2 injection rate, (c) determining the CO content of the stream at the higher injection rate, (d) further increasing the O.sub.2 injection rate if the second measured CO content is lower than the first measured CO content or reducing the O.sub.2 injection rate if the second measured CO content is greater than the first measured CO content, and (e) repeating steps a-d as needed to optimize CO consumption and minimize H.sub.2 consumption.

  11. Nanocomposite thin films for optical gas sensing

    SciTech Connect (OSTI)

    Ohodnicki, Paul R; Brown, Thomas D

    2014-06-03

    The disclosure relates to a plasmon resonance-based method for gas sensing in a gas stream utilizing a gas sensing material. In an embodiment the gas stream has a temperature greater than about 500.degree. C. The gas sensing material is comprised of gold nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10.sup.-7 S/cm at a temperature of 700.degree. C. Exemplary inert matrix materials include SiO.sub.2, Al.sub.2O.sub.3, and Si.sub.3N.sub.4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. Changes in the chemical composition of the gas stream are detected by changes in the plasmon resonance peak. The method disclosed offers significant advantage over active and reducible matrix materials typically utilized, such as yttria-stabilized zirconia (YSZ) or TiO.sub.2.

  12. Gas venting

    DOE Patents [OSTI]

    Johnson, Edwin F.

    1976-01-01

    Improved gas venting from radioactive-material containers which utilizes the passageways between interbonded impervious laminae.

  13. Java Parallel Secure Stream for Grid Computing

    SciTech Connect (OSTI)

    Chen, Jie; Akers, Walter; Chen, Ying; Watson, William

    2001-09-01

    The emergence of high speed wide area networks makes grid computing a reality. However grid applications that need reliable data transfer still have difficulties to achieve optimal TCP performance due to network tuning of TCP window size to improve the bandwidth and to reduce latency on a high speed wide area network. This paper presents a pure Java package called JPARSS (Java Par-allel Secure Stream) that divides data into partitions that are sent over several parallel Java streams simultaneously and allows Java or Web applications to achieve optimal TCP performance in a gird environment without the necessity of tuning the TCP window size. Several experimental results are provided to show that using parallel stream is more effective than tuning TCP window size. In addi-tion X.509 certificate based single sign-on mechanism and SSL based connection establishment are integrated into this package. Finally a few applications using this package will be discussed.

  14. Programmable stream prefetch with resource optimization

    SciTech Connect (OSTI)

    Boyle, Peter; Christ, Norman; Gara, Alan; Mawhinney, Robert; Ohmacht, Martin; Sugavanam, Krishnan

    2013-01-08

    A stream prefetch engine performs data retrieval in a parallel computing system. The engine receives a load request from at least one processor. The engine evaluates whether a first memory address requested in the load request is present and valid in a table. The engine checks whether there exists valid data corresponding to the first memory address in an array if the first memory address is present and valid in the table. The engine increments a prefetching depth of a first stream that the first memory address belongs to and fetching a cache line associated with the first memory address from the at least one cache memory device if there is not yet valid data corresponding to the first memory address in the array. The engine determines whether prefetching of additional data is needed for the first stream within its prefetching depth. The engine prefetches the additional data if the prefetching is needed.

  15. A Review of Major Non-Power-Related Carbon Dioxide Stream Compositions

    SciTech Connect (OSTI)

    Last, George V.; Schmick, Mary T.

    2015-07-01

    A critical component in the assessment of long-term risk from geologic sequestration of carbon dioxide (CO2) is the ability to predict mineralogical and geochemical changes within storage reservoirs as a result of rock-brine-CO2 reactions. Impurities and/or other constituents in CO2 source streams selected for sequestration can affect both the chemical and physical (e.g., density, viscosity, interfacial tension) properties of CO2 in the deep subsurface. The nature and concentrations of these impurities are a function of both the industrial source(s) of CO2, as well as the carbon capture technology used to extract the CO2 and produce a concentrated stream for subsurface injection and geologic sequestration. This article reviews the relative concentrations of CO2 and other constituents in exhaust gases from major non-energy-related industrial sources of CO2. Assuming that carbon capture technology would remove most of the incondensable gases N2, O2, and Ar, leaving SO2 and NOx as the main impurities, the authors then summarize the relative proportions of the remaining impurities assumed to be present in CO2 source streams that could be targeted for geologic sequestration. The summary is presented relative to five potential sources of CO2: 1) Flue Gas with Flue Gas Desulfurization, 2) Combustion Stack from Coke Production, 3) Portland Cement Kilns, 4) Natural Gas Combustion, and 5) Lime Production.

  16. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; Summers, Cathy A.; Gerdemann, Steve; Oryshchyn, Danylo B.; Turner, Paul; Patrick, Brian R.

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  17. Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions

    DOE Patents [OSTI]

    Biruduganti, Munidhar S.; Gupta, Sreenath Borra; Sekar, R. Raj; McConnell, Steven S.

    2008-11-25

    A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

  18. Fire protection considerations for the design and operation of liquefied petroleum gas (LPG) storage facilities

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This standard addresses the design, operation, and maintenance of LPG storage facilities from the standpoint of prevention and control of releases, fire-protection design, and fire-control measures, as well as the history of LPG storage facility failure, facility design philosophy, operating and maintenance procedures, and various fire-protection and firefighting approaches and presentations. The storage facilities covered are LPG installations (storage vessels and associated loading/unloading/transfer systems) at marine and pipeline terminals, natural gas processing plants, refineries, petrochemical plants, and tank farms.

  19. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  20. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  1. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  2. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  3. Disc valve for sampling erosive process streams

    DOE Patents [OSTI]

    Mrochek, J.E.; Dinsmore, S.R.; Chandler, E.W.

    1984-08-16

    This is a patent for a disc-type, four-port sampling valve for service with erosive high temperature process streams. Inserts and liners of ..cap alpha..-silicon carbide respectively, in the faceplates and in the sampling cavities, limit erosion while providing lubricity for a smooth and precise operation. 1 fig.

  4. Recuperated atmospheric SOFC/gas turbine hybrid cycle

    DOE Patents [OSTI]

    Lundberg, Wayne

    2010-05-04

    A method of operating an atmospheric-pressure solid oxide fuel cell generator (6) in combination with a gas turbine comprising a compressor (1) and expander (2) where an inlet oxidant (20) is passed through the compressor (1) and exits as a first stream (60) and a second stream (62) the first stream passing through a flow control valve (56) to control flow and then through a heat exchanger (54) followed by mixing with the second stream (62) where the mixed streams are passed through a combustor (8) and expander (2) and the first heat exchanger for temperature control before entry into the solid oxide fuel cell generator (6), which generator (6) is also supplied with fuel (40).

  5. Recuperated atmosphere SOFC/gas turbine hybrid cycle

    DOE Patents [OSTI]

    Lundberg, Wayne

    2010-08-24

    A method of operating an atmospheric-pressure solid oxide fuel cell generator (6) in combination with a gas turbine comprising a compressor (1) and expander (2) where an inlet oxidant (20) is passed through the compressor (1) and exits as a first stream (60) and a second stream (62) the first stream passing through a flow control valve (56) to control flow and then through a heat exchanger (54) followed by mixing with the second stream (62) where the mixed streams are passed through a combustor (8) and expander (2) and the first heat exchanger for temperature control before entry into the solid oxide fuel cell generator (6), which generator (6) is also supplied with fuel (40).

  6. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  7. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z. [Newton, MA

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  8. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Plant Field Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Butylene (C4H8) An olefinic hydrocarbon recovered from refinery processes. Ethane (C2H6) A normally gaseous straight-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of -127.48º F. It is extracted from natural gas and refinery gas streams. Field Production Represents crude oil production on leases, natural gas liquids production at natural gas processing

  9. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Natural Gas Plant Net Stocks Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Butylene (C4H8) An olefinic hydrocarbon recovered from refinery processes. Ethane (C2H6) A normally gaseous straight-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of -127.48º F. It is extracted from natural gas and refinery gas streams. Isobutane (C4H10) A normally gaseous branch-chain hydrocarbon. It is a colorless paraffinic gas that boils at a

  10. Conceptual design assessment for the co-firing of bio-refinery supplied lignin project. Quarterly report, June 23--July 1, 2000

    SciTech Connect (OSTI)

    Berglund, T.; Ranney, J.T.; Babb, C.L.

    2000-07-27

    The Conceptual Design Assessment for the Co-Firing of Bio-Refinery Supplied Lignin Project was successfully kicked off on July 23, 2000 during a meeting at the TVA-PPI facility in Muscle Shoals, AL. An initial timeline for the study was distributed, issues of concern were identified and a priority actions list was developed. Next steps include meeting with NETL to discuss de-watering and lignin fuel testing, the development of the mass balance model and ethanol facility design criteria, providing TVA-Colbert with preliminary lignin fuel analysis and the procurement of representative feed materials for the pilot and bench scale testing of the hydrolysis process.

  11. Gas powered fluid gun with recoil mitigation

    DOE Patents [OSTI]

    Grubelich, Mark C; Yonas, Gerold

    2013-11-12

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  12. Gas powered fluid gun with recoil mitigation

    DOE Patents [OSTI]

    Grubelich, Mark C.; Yonas, Gerold

    2016-03-01

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  13. Laboratory optimization tests of technetium decontamination of Hanford Waste Treatment Plant low activity waste melter off-gas condensate simulant

    SciTech Connect (OSTI)

    Taylor-Pashow, Kathryn M.L.; McCabe, Daniel J.

    2015-11-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable simplified operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  14. Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

    2000-01-01

    A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

  15. THE COS/UVES ABSORPTION SURVEY OF THE MAGELLANIC STREAM. I. ONE-TENTH SOLAR ABUNDANCES ALONG THE BODY OF THE STREAM

    SciTech Connect (OSTI)

    Fox, Andrew J. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Richter, Philipp [Institut fuer Physik und Astronomie, Universitaet Potsdam, Haus 28, Karl-Liebknecht-Str. 24/25, D-14476 Potsdam (Germany); Wakker, Bart P. [Department of Astronomy, University of Wisconsin-Madison, 475 North Charter St., Madison, WI 53706 (United States); Lehner, Nicolas; Howk, J. Christopher [Department of Physics, University of Notre Dame, 225 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Ben Bekhti, Nadya [Argelander-Institut fuer Astronomie, Universitaet Bonn, Auf dem Huegel 71, D-53121 Bonn (Germany); Bland-Hawthorn, Joss [Institute of Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Lucas, Stephen, E-mail: afox@stsci.edu [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

    2013-08-01

    The Magellanic Stream (MS) is a massive and extended tail of multi-phase gas stripped out of the Magellanic Clouds and interacting with the Galactic halo. In this first paper of an ongoing program to study the Stream in absorption, we present a chemical abundance analysis based on HST/COS and VLT/UVES spectra of four active galactic nuclei (RBS 144, NGC 7714, PHL 2525, and HE 0056-3622) lying behind the MS. Two of these sightlines yield good MS metallicity measurements: toward RBS 144 we measure a low MS metallicity of [S/H] = [S II/H I] = -1.13 {+-} 0.16 while toward NGC 7714 we measure [O/H] = [O I/H I] = -1.24 {+-} 0.20. Taken together with the published MS metallicity toward NGC 7469, these measurements indicate a uniform abundance of Almost-Equal-To 0.1 solar along the main body of the Stream. This provides strong support to a scenario in which most of the Stream was tidally stripped from the SMC Almost-Equal-To 1.5-2.5 Gyr ago (a time at which the SMC had a metallicity of Almost-Equal-To 0.1 solar), as predicted by several N-body simulations. However, in Paper II of this series, we report a much higher metallicity (S/H = 0.5 solar) in the inner Stream toward Fairall 9, a direction sampling a filament of the MS that Nidever et al. claim can be traced kinematically to the Large Magellanic Cloud, not the Small Magellanic Cloud. This shows that the bifurcation of the Stream is evident in its metal enrichment, as well as its spatial extent and kinematics. Finally we measure a similar low metallicity [O/H] = [O I/H I] = -1.03 {+-} 0.18 in the v{sub LSR} = 150 km s{sup -1} cloud toward HE 0056-3622, which belongs to a population of anomalous velocity clouds near the south Galactic pole. This suggests these clouds are associated with the Stream or more distant structures (possibly the Sculptor Group, which lies in this direction at the same velocity), rather than tracing foreground Galactic material.

  16. HUNTING THE PARENT OF THE ORPHAN STREAM: IDENTIFYING STREAM MEMBERS FROM LOW-RESOLUTION SPECTROSCOPY

    SciTech Connect (OSTI)

    Casey, Andrew R.; Da Costa, Gary; Keller, Stefan C.; Maunder, Elizabeth

    2013-02-10

    We present candidate K-giant members in the Orphan Stream that have been identified from low-resolution data taken with the AAOmega spectrograph on the Anglo-Australian Telescope. From modest signal-to-noise spectra and independent cuts in photometry, kinematics, gravity, and metallicity we yield self-consistent, highly probable stream members. We find a revised stream distance of 22.5 {+-} 2.0 kpc near the celestial equator and our kinematic signature peaks at V {sub GSR} = 82.1 {+-} 1.4 km s{sup -1}. The observed velocity dispersion of our most probable members is consistent with arising from the velocity uncertainties alone. This indicates that at least along this line of sight, the Orphan Stream is kinematically cold. Our data indicate an overall stream metallicity of [Fe/H] = -1.63 {+-} 0.19 dex which is more metal-rich than previously found and unbiased by spectral type. Furthermore, the significant metallicity dispersion displayed by our most probable members, {sigma}([Fe/H]) = 0.56 dex, suggests that the unidentified Orphan Stream parent is a dSph satellite. We highlight likely members for high-resolution spectroscopic follow-up.

  17. Montana Stream Permitting Guide Webpage | Open Energy Information

    Open Energy Info (EERE)

    Guide Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Stream Permitting Guide Webpage Abstract Provides a guide to required stream...

  18. How to use streaming chart? | OpenEI Community

    Open Energy Info (EERE)

    use streaming chart? Home > Groups > Databus Hi, how do you use the built-in streaming chart? How do you form the URL for it? Thanks, Submitted by Hopcroft on 31 October, 2013 -...

  19. Montana Joint Application for Proposed Work in Streams, Lakes...

    Open Energy Info (EERE)

    Streams, Lakes and Wetlands Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Joint Application for Proposed Work in Streams, Lakes and...

  20. Gasoline from natural gas by sulfur processing

    SciTech Connect (OSTI)

    Erekson, E.J.; Miao, F.Q.

    1995-12-31

    The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process, called the HSM (Hydrogen Sulfide-Methane) Process, consists of two steps that each utilize a catalyst and sulfur-containing intermediates: (1) converting natural gas to CS{sub 2} and (2) converting CS{sub 2} to gasoline range liquids. Catalysts have been found that convert methane to carbon disulfide in yields up to 98%. This exceeds the target of 40% yields for the first step. The best rate for CS{sub 2} formation was 132 g CS{sub 2}/kg-cat-h. The best rate for hydrogen production is 220 L H{sub 2} /kg-cat-h. A preliminary economic study shows that in a refinery application hydrogen made by the HSM technology would cost $0.25-R1.00/1000 SCF. Experimental data will be generated to facilitate evaluation of the overall commercial viability of the process.