National Library of Energy BETA

Sample records for reduction scr selective

  1. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Using Cu-zeolite | Department of Energy Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Discusses the impact of Na in biodiesel on three emission control devices: the diesel particulate filter, diesel oxidation catalyst, and zeolyte-based SCR catalyst PDF icon deer11_toops.pdf More Documents & Publications Impacts of Biodiesel on Emission Control

  2. Clean coal technology: selective catalytic reduction (SCR) technology for the control of nitrogen oxide emissions from coal-fired boilers

    SciTech Connect (OSTI)

    2005-05-01

    The report discusses a project carried out under the US Clean Coal Technology (CCT) Demonstration Program which demonstrated selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulphur coal-fired boilers under typical boilers conditions in the United States. The project was conducted by Southern Company Services, Inc., who served as a co-funder and as the host at Gulf Power Company's Plant Crist. The SCR process consists of injecting ammonia (NH{sub 3}) into boiler flue gas and passing the flue gas through a catalyst bed where the Nox and NH{sub 3} react to form nitrogen and water vapor. The results of the CCTDP project confirmed the applicability of SCR for US coal-fired power plants. In part as a result of the success of this project, a significant number of commercial SCR units have been installed and are operating successfully in the United States. By 2007, the total installed SCR capacity on US coal-fired units will number about 200, representing about 100,000 MWe of electric generating capacity. This report summarizes the status of SCR technology. 21 refs., 3 figs., 2 tabs., 10 photos.

  3. HYBRID SELECTIVE NON-CATALYTIC REDUCTION (SNCR)/SELECTIVE CATALYTIC REDUCTION (SCR) DEMONSTRATION FOR THE REMOVAL OF NOx FROM BOILER FLUE GASES

    SciTech Connect (OSTI)

    Jerry B. Urbas

    1999-05-01

    The U. S. Department of Energy (DOE), Electric Power Research Institute (EPRI), Pennsylvania Electric Energy Research Council, (PEERC), New York State Electric and Gas and GPU Generation, Inc. jointly funded a demonstration to determine the capabilities for Hybrid SNCR/SCR (Selective Non-Catalytic Reduction/Selective Catalytic Reduction) technology. The demonstration site was GPU Generation's Seward Unit No.5 (147MW) located in Seward Pennsylvania. The demonstration began in October of 1997 and ended in December 1998. DOE funding was provided through Grant No. DE-FG22-96PC96256 with T. J. Feeley as the Project Manager. EPRI funding was provided through agreements TC4599-001-26999 and TC4599-002-26999 with E. Hughes as the Project Manager. This project demonstrated the operation of the Hybrid SNCR/SCR NO{sub x} control process on a full-scale coal fired utility boiler. The hybrid technology was expected to provide a cost-effective method of reducing NO{sub x} while balancing capital and operation costs. An existing urea based SNCR system was modified with an expanded-duct catalyst to provide increased NO{sub x} reduction efficiency from the SNCR while producing increased ammonia slip levels to the catalyst. The catalyst was sized to reduce the ammonia slip to the air heaters to less than 2 ppm while providing equivalent NO{sub x} reductions. The project goals were to demonstrate hybrid technology is capable of achieving at least a 55% reduction in NO{sub x} emissions while maintaining less than 2ppm ammonia slip to the air heaters, maintain flyash marketability, verify the cost benefit and applicability of Hybrid post combustion technology, and reduce forced outages due to ammonium bisulfate (ABS) fouling of the air heaters. Early system limitations, due to gas temperature stratification, restricted the Hybrid NO{sub x} reduction capabilities to 48% with an ammonia slip of 6.1 mg/Nm{sup 3} (8 ppm) at the catalyst inlet. After resolving the stratification problem, the catalyst did not have sufficient activity in order to continue the planned test program. Arsenic poisoning was found to be the cause of premature catalyst deactivation.

  4. Deactivation Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Deactivation Mechanisms of CuZeolite SCR Catalysts in Diesel Application Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials...

  5. Reductant Utilization in a LNT + SCR System

    Office of Energy Efficiency and Renewable Energy (EERE)

    Investigation of the potential synergies of LNT and SCR for treating NOx emissions from a diesel engine.

  6. Development of HC-SCR System Using Diesel Fuel as a Reductant | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy HC-SCR System Using Diesel Fuel as a Reductant Development of HC-SCR System Using Diesel Fuel as a Reductant Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-19_lee.pdf More Documents & Publications Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst

  7. Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of Nitrogen Oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, third and fourth quarters 1995

    SciTech Connect (OSTI)

    1996-05-01

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

  8. Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, third and fourth quarters 1994

    SciTech Connect (OSTI)

    1995-11-01

    The objective of this project is to demonstrate and evaluate commercially available selective catalytic reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. Coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and European gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida. The project is funded by the U.S. Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing al aspects of this project. 1 ref., 69 figs., 45 tabs.

  9. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems...

  10. SCR Technologies for NOx Reduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies for NOx Reduction SCR Technologies for NOx Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_hesser.pdf More Documents & Publications Injection System and Engine Strategies for Advanced Emission Standards Advanced Diesel Common Rail Injection System for Future Emission Legislation Powertrain Trends and Future Potential

  11. Innovative clean coal technology (ICCT): demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emission from high-sulfur, coal-fired boilers - economic evaluation of commercial-scale SCR applications for utility boilers

    SciTech Connect (OSTI)

    Healy, E.C.; Maxwell, J.D.; Hinton, W.S.

    1996-09-01

    This report presents the results of an economic evaluation produced as part of the Innovative Clean Coal Technology project, which demonstrated selective catalytic reduction (SCR) technology for reduction of NO{sub x} emissions from utility boilers burning U.S. high-sulfur coal. The document includes a commercial-scale capital and O&M cost evaluation of SCR technology applied to a new facility, coal-fired boiler utilizing high-sulfur U.S. coal. The base case presented herein determines the total capital requirement, fixed and variable operating costs, and levelized costs for a new 250-MW pulverized coal utility boiler operating with a 60-percent NO{sub x} removal. Sensitivity evaluations are included to demonstrate the variation in cost due to changes in process variables and assumptions. This report also presents the results of a study completed by SCS to determine the cost and technical feasibility of retrofitting SCR technology to selected coal-fired generating units within the Southern electric system.

  12. Investigation on continuous soot oxidation and NOx reduction by SCR coated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DPF | Department of Energy on continuous soot oxidation and NOx reduction by SCR coated DPF Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF Evaluation of CSI catalyst for NOx removal and soot oxidation. PDF icon deer09_iretskaya.pdf More Documents & Publications Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications Two Catalyst Formulations - One Solution for NOx After-treatment Systems SCR-DPF Integrations for Diesel

  13. Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engines | Department of Energy a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea SCR system was developed for marine diesel engines and showed a 50-percent reduction in NOx. PDF icon deer08_bedick.pdf More Documents & Publications Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Evaluation of 2010 Urea-SCR Technology for

  14. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using ...

  15. Deactivation Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrothermal Aging | Department of Energy Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive Hydrothermal Aging Deactivation Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive Hydrothermal Aging Better control for preventing catalyst deactivation resulted from study of and proposed mechanism for deactivation of Cu/zeolite under rich conditions. PDF icon deer08_huang.pdf More Documents & Publications Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel

  16. Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2003_deer_thomas.pdf More Documents & Publications Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Fuel-Borne Catalyst Assisted DPF regeneration on a Renault truck MD9 Engine Outfitted with SCR NOx Adsorber Regeneration Phenomena

  17. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst Study of effects of hydrocarbons on ammonia storage and NOx reduction over a commercial Fe-zeolite SCR catalyst to understand catalyst behaviors at low temperatures and improve NOx reduction performance and reduce system cost PDF icon deer10_lee.pdf More Documents & Publications Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite

  18. Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Focus is the heavy duty, US dynamometer certification using the Duramax 6.6 liter diesel PDF icon deer09_blint.pdf More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx

  19. Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems

    SciTech Connect (OSTI)

    Harold, Michael; Crocker, Mark; Balakotaiah, Vemuri; Luss, Dan; Choi, Jae-Soon; Dearth, Mark; McCabe, Bob; Theis, Joe

    2013-09-30

    Oxides of nitrogen in the form of nitric oxide (NO) and nitrogen dioxide (NO{sub 2}) commonly referred to as NO{sub x}, is one of the two chemical precursors that lead to ground-level ozone, a ubiquitous air pollutant in urban areas. A major source of NO{sub x} is generated by equipment and vehicles powered by diesel engines, which have a combustion exhaust that contains NO{sub x} in the presence of excess O{sub 2}. Catalytic abatement measures that are effective for gasoline-fueled engines such as the precious metal containing three-way catalytic converter (TWC) cannot be used to treat O2-laden exhaust containing NO{sub x}. Two catalytic technologies that have emerged as effective for NO{sub x} abatement are NO{sub x} storage and reduction (NSR) and selective catalytic reduction (SCR). NSR is similar to TWC but requires much larger quantities of expensive precious metals and sophisticated periodic switching operation, while SCR requires an on-board source of ammonia which serves as the chemical reductant of the NO{sub x}. The fact that NSR produces ammonia as a byproduct while SCR requires ammonia to work has led to interest in combining the two together to avoid the need for the cumbersome ammonia generation system. In this project a comprehensive study was carried out of the fundamental aspects and application feasibility of combined NSR/SCR. The project team, which included university, industry, and national lab researchers, investigated the kinetics and mechanistic features of the underlying chemistry in the lean NOx trap (LNT) wherein NSR was carried out, with particular focus on identifying the operating conditions such as temperature and catalytic properties which lead to the production of ammonia in the LNT. The performance features of SCR on both model and commercial catalysts focused on the synergy between the LNT and SCR converters in terms of utilizing the upstream-generated ammonia and alternative reductants such as propylene, representing the hydrocarbon component of diesel exhaust. First-principle models of the LNT and SCR converters, which utilized the mechanistic-based kinetics and realistic treatments of the flow and transport processes, in combination with bench-scale reactor experiments helped to identify the best designs for combining the NSR and SCR catalysts over a range of operating conditions encountered in practice. This included catalysts having multiple zones and layers and additives with the focus on determining the minimal precious metal component needed to meet emission abatement targets over a wide range of operating conditions. The findings from this study provide diesel vehicle and catalyst companies valuable information to develop more cost effective diesel emissions catalysts which helps to expand the use of more fuel efficient diesel power. The fundamental modeling and experimental tools and findings from this project can be applied to catalyst technologies used in the energy and chemical industries. Finally, the project also led to training of several doctoral students who were placed in research jobs in industry and academia.

  20. Hydrocarbon fouling of SCR during Premixed Charge Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Efficient Emissions Control for Multi-Mode Lean DI Engines Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using ...

  1. Development of a Stand-Alone Urea-SCR System for NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Evaluation of 2010 Urea-SCR Technology for Hybrid Vehicles using PSAT System Simulations ...

  2. Bifunctional Catalysts for the Selective Catalytic Reduction of NO by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons | Department of Energy 4 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Argonne National Laboratory PDF icon 2004_deer_marshall.pdf More Documents & Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction

  3. Impact of sulfation and desulfation on NOx reduction using Cu-chabazite SCR catalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brookshear, Daniel William; Nam, Jeong -Gil; Nguyen, Ke; Toops, Todd J.; Binder, Andrew J.

    2015-06-05

    This bench reactor study investigates the impact of gaseous sulfur on the NOx reduction activity of Cu-chabazite SCR (Cu-CHA) catalysts at SO2 concentrations representative of marine diesel engine exhaust. After two hours of 500 ppm SO2 exposure at 250 and 400 °C in the simulated diesel exhaust gases, the NOx reduction activity of the sulfated Cu-CHA SCR catalysts is severely degraded at evaluation temperatures below 250 °C; however, above 250 °C the impact of sulfur exposure is minimal. EPMA shows that sulfur is located throughout the washcoat and along the entire length of the sulfated samples. Interestingly, BET measurements revealmore » that the sulfated samples have a 20% decrease in surface area. Moreover, the sulfated samples show a decrease in NOx/nitrate absorption during NO exposure in a DRIFTS reactor which suggests that Cu sites in the catalyst are blocked by the presence of sulfur. SO2 exposure also results in an increase in NH3 storage capacity, possibly due to the formation of ammonium sulfate species in the sulfated samples. In all cases, lean thermal treatments as low as 500 °C reverse the effects of sulfur exposure and restore the NOx reduction activity of the Cu-CHA catalyst to that of the fresh condition.« less

  4. Impact of Sulfation and Desulfation on NOx Reduction Using Cu-Chabazite SCR Catalysts

    SciTech Connect (OSTI)

    Brookshear, Daniel W; Nam, Jeong-Gil; Nguyen, Ke; Toops, Todd J; Binder, Andrew J

    2015-01-01

    This bench reactor study investigates the impact of gaseous sulfur on the NOx reduction activity of Cu-chabazite SCR (Cu-CHA) catalysts at SO2 concentrations representative of marine diesel engine exhaust. After two hours of 500 ppm SO2 exposure at 250 and 400 C in the simulated diesel exhaust gases, the NOx reduction activity of the sulfated Cu-CHA SCR catalysts is severely degraded at evaluation temperatures below 250 C; however, above 250 C the impact of sulfur exposure is minimal. EPMA shows that sulfur is located throughout the washcoat and along the entire length of the sulfated samples. Interestingly, BET measurements reveal that the sulfated samples have a 20% decrease in surface area. Furthermore, the sulfated samples show a decrease in NOx/nitrate absorption during NO exposure in a DRIFTS reactor which suggests that Cu sites in the catalyst are blocked by the presence of sulfur. SO2 exposure also results in an increase in NH3 storage capacity, possibly due to the formation of ammonium sulfate species in the sulfated samples. In all cases, lean thermal treatments as low as 500 C reverse the effects of sulfur exposure and restore the NOx reduction activity of the Cu-CHA catalyst to that of the fresh condition.

  5. Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Hydrocarbon Poisoning of A Urea SCR Catalyst Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst Understanding what reactions and which catalytic functions are affected by hydrocarbons can lead to improved tolerances for selective catalytic reduction performance PDF icon deer09_toops.pdf More Documents & Publications Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst CLEERS Coordination &

  6. The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrothermal Agingon a Commercial Cu SCR Catalyst The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst Examines the effect of hydrothermal aging on the Nox reduction over a commercial Cu-zeolite SCR catalyst. PDF icon deer11_lee.pdf More Documents & Publications CLEERS Aftertreatment Modeling and Analysis Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon

  7. NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy -Selective Catalytic Reduction over Ag/Al2O3 Catalysts NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts DRIFT spectroscopy used together with flow reactor experiments to investigate the role of H2 for SCR over Ag/Al2O3 PDF icon deer12_tamm.pdf More Documents & Publications Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Experimental and Modelling Study of the Effect of Diffusional Limitations on the NH3 SCR Activity Development of Optimal Catalyst

  8. Method to monitor HC-SCR catalyst NOx reduction performance for lean exhaust applications

    DOE Patents [OSTI]

    Viola, Michael B. (Macomb Township, MI); Schmieg, Steven J. (Troy, MI); Sloane, Thompson M. (Oxford, MI); Hilden, David L. (Shelby Township, MI); Mulawa, Patricia A. (Clinton Township, MI); Lee, Jong H. (Rochester Hills, MI); Cheng, Shi-Wai S. (Troy, MI)

    2012-05-29

    A method for initiating a regeneration mode in selective catalytic reduction device utilizing hydrocarbons as a reductant includes monitoring a temperature within the aftertreatment system, monitoring a fuel dosing rate to the selective catalytic reduction device, monitoring an initial conversion efficiency, selecting a determined equation to estimate changes in a conversion efficiency of the selective catalytic reduction device based upon the monitored temperature and the monitored fuel dosing rate, estimating changes in the conversion efficiency based upon the determined equation and the initial conversion efficiency, and initiating a regeneration mode for the selective catalytic reduction device based upon the estimated changes in conversion efficiency.

  9. Bifunctional Catalysts for the Selective Catalytic Reduction of NO by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons | Department of Energy 3 DEER Conference Presentation: Argonne National Laboratory PDF icon 2003_deer_marshall.pdf More Documents & Publications Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems

  10. Deactivation of Accelerated Engine-Aged and Field-Aged SCR Catalysts and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Role of the DOC | Department of Energy of Accelerated Engine-Aged and Field-Aged SCR Catalysts and the Role of the DOC Deactivation of Accelerated Engine-Aged and Field-Aged SCR Catalysts and the Role of the DOC A technique for accelerated aging of SCR system (DOC -> SCR-> DPF) reveals two deactivation mechanisms and replicates field-aged effects PDF icon deer09_toops.pdf More Documents & Publications Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of

  11. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application PDF icon deer09_cheng.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite

  12. Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System | Department of Energy Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System effect and performance recovery studies at system level with typical diesel emission control consisting of diesel oxidation catalyst, catalyzed soot filter, and selective catalytic reduction PDF icon deer11_tang.pdf More Documents & Publications Investigation of Sulfur Deactivation on Cu/Zeolite SCR

  13. Laboratory Product Speciation Studies of the LNT + in situ SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Understanding the detailed chemistry of Nox Reduction across the combined LNT+SCR ...

  14. A Study and Comparison of SCR Reaction Kinetics from Reactor...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR...

  15. PILOT-SCALE EVALUATION OF THE IMPACT OF SELECTIVE CATALYTIC REDUCTION FOR NOx ON MERCURY SPECIATION

    SciTech Connect (OSTI)

    Dennis L. Laudal; John H. Pavlish; Kevin C. Galbreath; Jeffrey S. Thompson; Gregory F. Weber; Everett Sondreal

    2000-12-01

    Full-scale tests in Europe and bench-scale tests in the United States have indicated that the catalyst, normally vanadium/titanium metal oxide, used in the selective catalytic reduction (SCR) of NO{sub x}, may promote the formation of Hg{sup 2+} and/or particulate-bound mercury (Hg{sub p}). To investigate the impact of SCR on mercury speciation, pilot-scale screening tests were conducted at the Energy & Environmental Research Center. The primary research goal was to determine whether the catalyst or the injection of ammonia in a representative SCR system promotes the conversion of Hg{sup 0} to Hg{sup 2+} and/or Hg{sub p} and, if so, which coal types and parameters (e.g., rank and chemical composition) affect the degree of conversion. Four different coals, three eastern bituminous coals and a Powder River Basin (PRB) subbituminous coal, were tested. Three tests were conducted for each coal: (1) baseline, (2) NH{sub 3} injection, and (3) SCR of NO{sub x}. Speciated mercury, ammonia slip, SO{sub 3}, and chloride measurements were made to determine the effect the SCR reactor had on mercury speciation. It appears that the impact of SCR of NO{sub x} on mercury speciation is coal-dependent. Although there were several confounding factors such as temperature and ammonia concentrations in the flue gas, two of the eastern bituminous coals showed substantial increases in Hg{sub p} at the inlet to the ESP after passing through an SCR reactor. The PRB coal showed little if any change due to the presence of the SCR. Apparently, the effects of the SCR reactor are related to the chloride, sulfur and, possibly, the calcium content of the coal. It is clear that additional work needs to be done at the full-scale level.

  16. System and method for controlling an engine based on ammonia storage in multiple selective catalytic reduction catalysts

    DOE Patents [OSTI]

    Sun, MIn; Perry, Kevin L.

    2015-11-20

    A system according to the principles of the present disclosure includes a storage estimation module and an air/fuel ratio control module. The storage estimation module estimates a first amount of ammonia stored in a first selective catalytic reduction (SCR) catalyst and estimates a second amount of ammonia stored in a second SCR catalyst. The air/fuel ratio control module controls an air/fuel ratio of an engine based on the first amount, the second amount, and a temperature of a substrate disposed in the second SCR catalyst.

  17. Two in One: SCR on Filter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in One: SCR on Filter Two in One: SCR on Filter Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_dieterle.pdf More Documents & Publications SCR-DPF Integrations for Diesel ExhaustPerformance and Perspectives for High SCR Loadings Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF Combination and Integration of DPF-SCR Aftertreatment Technologies

  18. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and improve NOx reduction performance and reduce system cost PDF icon deer10lee.pdf More Documents & Publications Hydrocarbon Inhibition and HC Storage Modeling in...

  19. Lean NOx Reduction with Dual Layer LNT/SCR Catalysts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    out coupled ammonia generation and NOx reduction, achieving high NOx conversion with minimal ammonia slip PDF icon deer12harold.pdf More Documents & Publications Development of ...

  20. System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly; Rossin, Joseph A

    2014-04-08

    A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

  1. Selective catalytic reduction system and process using a pre-sulfated zirconia binder

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly; Rossin, Joseph A.

    2010-06-29

    A selective catalytic reduction (SCR) process with a palladium catalyst for reducing NOx in a gas, using hydrogen as a reducing agent is provided. The process comprises contacting the gas stream with a catalyst system, the catalyst system comprising (ZrO.sub.2)SO.sub.4, palladium, and a pre-sulfated zirconia binder. The inclusion of a pre-sulfated zirconia binder substantially increases the durability of a Pd-based SCR catalyst system. A system for implementing the disclosed process is further provided.

  2. Modeling Species Inhibition of NO Oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

    2011-04-20

    Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the Fe-zeolite SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data. Such inhibition models will improve the accuracy of model based control design for integrated DPF-SCR aftertreatment systems.

  3. Advanced Metal-Oxide based SCR Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal-Oxide based SCR Catalysts Advanced Metal-Oxide based SCR Catalysts SCR with ammonia as reductant is an effective strategy being utilized to reduce NOx emissions to meet regulated levels. PDF icon deer10_adelmann.pdf More Documents & Publications Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Looking From A Hilltop: Automotive Propulsion System Technology

  4. Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst

    SciTech Connect (OSTI)

    Pihl, Josh A; Toops, Todd J; Fisher, Galen; West, Brian H

    2014-01-01

    Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

  5. Non-uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysts | Department of Energy uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite SCR Catalysts Non-uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite SCR Catalysts Cu/Zeolite SCR catalysts aged for 50k miles on a Super Duty diesel truck PDF icon deer10_cheng.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials Deactivation

  6. NOx Aftertreatment Using Ethanol as Reductant | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment Using Ethanol as Reductant NOx Aftertreatment Using Ethanol as Reductant The hydrocarbon-SCR that was developed using ethanol and E85 as the reductant showed high NOx reduction, no need for thawing, use of existing infrastructure, and reduced system cost making it a viable alternative to urea-based SCR PDF icon deer10_diewald.pdf More Documents & Publications Selective ammonia slip catalyst enabling highly efficient NOx removal requirements of the future SCR-DPF Integrations

  7. Validated SCR Concept Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Validated SCR Concept Development Validated SCR Concept Development Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_kraemer.pdf More Documents & Publications SCR Technologies for NOx Reduction Development of a Dynamic DOE Calibration Model Vehicular Applications of

  8. Biodiesel + SCR Retrofit Testing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    + SCR Retrofit Testing Biodiesel + SCR Retrofit Testing This work retrofitted an in-use engine with urea SCR and measured NOx reductions versus blend levels of ULSD, B20, and B100 PDF icon deer09_robertson.pdf More Documents & Publications DPF Performance with Biodiesel Blends Impact of Biodiesel on the Near-term Performance and Long-term Durability of Advanced Aftertreatment Systems Vehicle Technologies Office: 2008-2009 Fuels Technologies R&D Progress Report

  9. Urea Decomposition and SCR Performance at Low Temperature | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Decomposition and SCR Performance at Low Temperature Urea Decomposition and SCR Performance at Low Temperature 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Oak Ridge National Laboratory PDF icon 2004_deer_sluder.pdf More Documents & Publications Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR Development of Optimal Catalyst Designs and Operating

  10. Modeling Species Inhibition of NO oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

    2010-09-15

    Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data.

  11. Improvement of Urea SCR Performance Using Wiremesh Thermolysis Mixer |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Improvement of Urea SCR Performance Using Wiremesh Thermolysis Mixer Improvement of Urea SCR Performance Using Wiremesh Thermolysis Mixer Wiremesh mixer development should bring harmony between injection, thermolysis, and mixing. PDF icon deer08_rajadurai.pdf More Documents & Publications Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx Reduction SCR Performance Optimization Through Advancements in Aftertreatment Packaging Urea Mixing

  12. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants...

  13. Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants 2004 Diesel Engine...

  14. Evaluation of NH3-SCR Catalyst Technology on a 250-kW Stationary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems...

  15. Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants

    Broader source: Energy.gov [DOE]

    2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Oak Ridge National Laboratory

  16. Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Parks, II, James E; Pihl, Josh A; Toops, Todd J

    2014-01-01

    A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

  17. The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application Selective catalytic reduction studies with ammonia/NO model gas mixtures were used to screen mixed FeVO4/titania powders for activity in both fresh and aged conditions; reaction of ammonia in the absence of NO was also used as measure of ammonia oxidation tendency at elevated reaction

  18. Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Concept | Department of Energy Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Laboratory Product Speciation Studies of the LNT + in situ SCR NOx Emission Control Concept Understanding the detailed chemistry of Nox Reduction across the combined LNT+SCR system. PDF icon deer10_crocker.pdf More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Lean NOx

  19. DEMONSTRATION OF POTENTIAL FOR SELECTIVE CATALYTIC REDUCTION AND DIESEL PARTICULATE FILTERS

    SciTech Connect (OSTI)

    McGILL,R; KHAIR, M; SHARP, C

    2003-08-24

    This project addresses the potential for Selective Catalytic Reduction (SCR) devices (using urea as reductant) together with Diesel Particulate Filters (DPF) and low-pressure loop exhaust gas recirculation (EGR) to achieve future stringent emissions standards for heavy-duty engines powering Class 8 vehicles. Two emission control systems consisting of the three technologies (EGR, SCR, and DPF) were calibrated on a Caterpillar C-12 heavy-duty diesel engine. Results of these calibrations showed good promise in meeting the 2010 heavy-duty emission standards as set forth by the Environmental Protection Agency (EPA). These two emission control systems were developed to evaluate a series of fuels that have similar formulations except for their sulfur content. Additionally, one fuel, code-named BP15, was also evaluated. This fuel was prepared by processing straight-run distillate stocks through a commercial, single stage hydrotreater employing high activity catalyst at maximum severity. An additional goal of this program is to provide data for an on-going EPA technology review that evaluates progress toward meeting 2007/2010 emission standards. These emissions levels were to be achieved not only on the transient test cycles but in other modes of operation such as the steady-state Euro-III style emission test known as the OICA (Organisation Internationale des Compagnies d'Automobiles) or the ESC (European Stationary Cycle). Additionally, hydrocarbon and carbon monoxide emissions standards are to be met.

  20. Mitigation of the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance | Department of Energy the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst Performance Mitigation of the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst Performance Investigates operating conditions under which PGM elements get volatilized and transferred onto the downstream SCR catalyst, resulting in loss of NOx reduction performance PDF icon deer12_chen.pdf More Documents & Publications The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst Function

  1. Development of SCR on Diesel Particulate Filter System for Heavy Duty

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy SCR on Diesel Particulate Filter System for Heavy Duty Applications Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications Evaluation of a system consisting of SCRDPF in comparison to a commercial 2010 CDPF system on an engine under high and low engine-out NOx conditions PDF icon deer12_naseri.pdf More Documents & Publications Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF SCR-DPF Integrations

  2. Development of a Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines Development of a Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Sandia National Laboratories PDF icon 2004_deer_pena.pdf More Documents & Publications Experimental and Modelling Study of the Effect of Diffusional Limitations on the NH3 SCR Activity Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5

  3. Evaluation of Mercury Emissions from Coal-Fired Facilities with SCR and FGD Systems

    SciTech Connect (OSTI)

    J. A. Withum; J. E. Locke

    2006-02-01

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NO{sub x}, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of SCR catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the tenth in a series of topical reports, describes the results and analysis of mercury sampling performed on two 468 MW units burning bituminous coal containing 1.3-1.7% sulfur. Unit 2 is equipped with an SCR, ESP, and wet FGD to control NO{sub x}, particulate, and SO{sub 2} emissions, respectively. Unit 1 is similar to Unit 2, except that Unit 1 has no SCR for NOx control. Four sampling tests were performed on both units in January 2005; flue gas mercury speciation and concentrations were determined at the economizer outlet, air heater outlet (ESP inlet), ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process samples for material balances were collected with the flue gas measurements. The results show that the SCR increased the oxidation of the mercury at the air heater outlet. At the exit of the air heater, a greater percentage of the mercury was in the oxidized and particulate forms on the unit equipped with an SCR compared to the unit without an SCR (97.4% vs 91%). This higher level of oxidation resulted in higher mercury removals in the scrubber. Total mercury removal averaged 97% on the unit with the SCR, and 87% on the unit without the SCR. The average mercury mass balance closure was 84% on Unit 1 and 103% on Unit 2.

  4. Simulation of catalytic oxidation and selective catalytic NOx reduction in lean-exhaust hybrid vehicles

    SciTech Connect (OSTI)

    Gao, Zhiming; Daw, C Stuart; Chakravarthy, Veerathu K

    2012-01-01

    We utilize physically-based models for diesel exhaust catalytic oxidation and urea-based selective catalytic NOx reduction to study their impact on drive cycle performance of hypothetical light-duty diesel powered hybrid vehicles. The models have been implemented as highly flexible SIMULINK block modules that can be used to study multiple engine-aftertreatment system configurations. The parameters of the NOx reduction model have been adjusted to reflect the characteristics of Cu-zeolite catalysts, which are of widespread current interest. We demonstrate application of these models using the Powertrain System Analysis Toolkit (PSAT) software for vehicle simulations, along with a previously published methodology that accounts for emissions and temperature transients in the engine exhaust. Our results illustrate the potential impact of DOC and SCR interactions for lean hybrid electric and plug-in hybrid electric vehicles.

  5. EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS

    SciTech Connect (OSTI)

    J.A. Withum

    2006-03-07

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), evaluated the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)-wet flue gas desulfurization (FGD) combination or a spray dyer absorber-fabric filter (SDA-FF) combination. In this program CONSOL determined mercury speciation and removal at 10 bituminous coal-fired facilities; at four of these facilities, additional tests were performed on units without SCR, or with the existing SCR bypassed. This project final report summarizes the results and discusses the findings of the body of work as a whole. Eleven Topical Reports were issued (prior to this report) that describe in great detail the sampling results at each of the ten power plants individually. The results showed that the SCR-FGD combination removed a substantial fraction of mercury from flue gas. The coal-to-stack mercury removals ranged from 65% to 97% for the units with SCR and from 53% to 87% for the units without SCR. There was no indication that any type of FGD system was more effective at mercury removal than others. The coal-to-stack mercury removal and the removal in the wet scrubber were both negatively correlated with the elemental mercury content of the flue gas and positively correlated with the scrubber liquid chloride concentration. The coal chlorine content was not a statistically significant factor in either case. Mercury removal in the ESP was positively correlated with the fly ash carbon content and negatively correlated with the flue gas temperature. At most of the units, a substantial fraction (>35%) of the flue gas mercury was in the elemental form at the boiler economizer outlet. After passing through the SCR-air heater combination very little of the total mercury (<10%) remained in the elemental form in the flue gas; this was true for all SCR catalyst types and sources. Although chlorine has been suggested as a factor affecting the mercury speciation in flue gas, coal chlorine was not a statistically significant factor affecting mercury speciation at the economizer exit or at the air heater exit. The only statistically significant factors were the coal ash CaO content and the fly ash carbon content; the fraction of mercury in the elemental form at the economizer exit was positively correlated with both factors. In a direct comparison at four SCR-equipped units vs. similar units at the same sites without SCR (or with the SCR bypassed), the elemental mercury fractions (measured at the ESP outlet) were lower, and the coal-to-stack mercury removals were higher, when the SCR was present and operating. The average coal-to-stack mercury removal at the four units without an operating SCR was 72%, whereas the average removal at the same sites with operating SCRs was 88%. The unit mercury mass balance (a gauge of the overall quality of the tests) at all of the units ranged from 81% to 113%, which were within our QA/QC criterion of 80-120%.

  6. Selective catalyst reduction light-off strategy

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-10-18

    An emissions control system includes a temperature determination module and an emissions control module. The temperature determination module determines a first temperature of a heater element of a diesel particulate filter (DPF) assembly in an exhaust system and determines a second temperature of a catalyst of the DPF assembly. The emissions control module selectively activates the heater element, selectively initiates a predefined combustion process in an engine based upon the first temperature, and selectively starts a reductant injection process based upon the second temperature.

  7. Mitigation of the Impact of Pt Contamination on Cu-Zeolite SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    get volatilized and transferred onto the downstream SCR catalyst, resulting in loss of NOx reduction performance PDF icon deer12chen.pdf More Documents & Publications The...

  8. Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Ford Motor Company PDF icon 2004deerhammerle.pdf More Documents & Publications Urea SCR and DPF System for...

  9. Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005deerlambert.pdf More Documents & Publications Urea SCR and DPF System for Diesel...

  10. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  11. Review of SCR Technologies for Diesel Emission Control: Euruopean

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experience and Worldwide Perspectives | Department of Energy SCR Technologies for Diesel Emission Control: Euruopean Experience and Worldwide Perspectives Review of SCR Technologies for Diesel Emission Control: Euruopean Experience and Worldwide Perspectives 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Aaquis and Aaquis PDF icon 2004_deer_joubert2.pdf More Documents & Publications A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles French

  12. Final Report of a CRADA Between Pacific Northwest National Laboratory and the General Motors Company (CRADA No. PNNL/271): Degradation Mechanisms of Urea Selective Catalytic Reduction Technology

    SciTech Connect (OSTI)

    Kim, Do Heui; Lee, Jong H.; Peden, Charles HF; Howden, Ken; Kim, Chang H.; Oh, Se H.; Schmieg, Steven J.; Wiebenga, Michelle H.

    2011-12-13

    Diesel engines can offer substantially higher fuel efficiency, good driving performance characteristics, and reduced carbon dioxide (CO2) emission compared to stoichiometric gasoline engines. Despite the increasing public demand for higher fuel economy and reduced dependency on imported oil, however, meeting the stringent emission standards with affordable methods has been a major challenge for the wide application of these fuel-efficient engines in the US market. The selective catalytic reduction of NOx by urea (urea-SCR) is one of the most promising technologies for NOx emission control for diesel engine exhausts. To ensure successful NOx emission control in the urea-SCR technology, both a diesel oxidation catalyst (DOC) and a urea-SCR catalyst with high activity and durability are critical for the emission control system. Because the use of this technology for light-duty diesel vehicle applications is new, the relative lack of experience makes it especially challenging to satisfy the durability requirements. Of particular concern is being able to realistically simulate actual field aging of the catalyst systems under laboratory conditions, which is necessary both as a rapid assessment tool for verifying improved performance and certifiability of new catalyst formulations. In addition, it is imperative to develop a good understanding of deactivation mechanisms to help develop improved catalyst materials. In this CRADA program, General Motors Company and PNNL have investigated fresh, laboratory- and vehicle-aged DOC and SCR catalysts. The studies have led to a better understanding of various aging factors that impact the long-term performance of catalysts used in the urea-SCR technology, and have improved the correlation between laboratory and vehicle aging for reduced development time and cost. This Final Report briefly highlights many of the technical accomplishments and documents the productivity of the program in terms of peer-reviewed scientific publications (2 total), reports (3 total including this Final Report), and presentations (5 total).

  13. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments...

  14. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies: Preprint

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-04-01

    An accelerated durability test method determined the potential impact of biodiesel ash impurities, including engine testing with multiple diesel particulate filter substrate types, as well as diesel oxidation catalyst and selective catalyst reduction catalysts. The results showed no significant degradation in the thermo-mechanical properties of a DPF after exposure to 150,000-mile equivalent biodiesel ash and thermal aging. However, exposure to 435,000-mile equivalent aging resulted in a 69% decrease in thermal shock resistance. A decrease in DOC activity was seen after exposure to 150,000-mile equivalent aging, resulting in higher hydrocarbon slip and a reduction in NO2 formation. The SCR catalyst experienced a slight loss in activity after exposure to 435,000-mile equivalent aging. The SCR catalyst, placed downstream of the DPF and exposed to B20 exhaust suffered a 5% reduction in overall NOx conversion activity over the HDDT test cycle. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. The results of this study suggest that long-term operation with B20 at the current specification limits for alkali and alkaline earth metal impurities will adversely impact the performance of DOC, DPF and SCR systems.

  15. Selective Catalytic Reduction and Exhaust Gas Recirculation Systems Optimization

    Broader source: Energy.gov [DOE]

    A patented EGR-SCR approach was shown to readily meet the 2010 EPA requirments for NOx and PM emisisons through independent testing programs.

  16. Study of On-Board Ammonia (NH3) Generation for SCR Operation | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Study of On-Board Ammonia (NH3) Generation for SCR Operation Study of On-Board Ammonia (NH3) Generation for SCR Operation The feasibility of on-board ammonia generation was examined using synthesized exhaust compositions PDF icon deer09_wong.pdf More Documents & Publications On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Delphi On-board Ammonia Generation (OAG) Reductant Utilization in a LNT + SCR System

  17. Effect of Unburned Methyl Esters on the NOx Conversion of Fe-Zeolite SCR Catalyst

    SciTech Connect (OSTI)

    Williams, A.; Ratcliff, M.; Pedersen, D.; McCormick, R.; Cavataio, G.; Ura, J.

    2010-03-01

    Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300 C. These stored HCs inhibit or block NO{sub x}-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NO{sub x} conversion begins at between 100 and 200 C. When exposure to unburned fuel occurs at higher temperatures (250-400 C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NO{sub x} conversion is inhibited until it is heated to 400 C. However, when masked with biodiesel, NO{sub x} conversion is observed to begin at temperatures as low as 200 C. Engine test results also show low-temperature recovery from HC storage. Engine tests indicate that, overall, the SCR system has a faster recovery from HC masking with biodiesel. This is at least partially due to a reduction in exhaust HCs, and thus total HC exposure with biodiesel.

  18. Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2013-09-06

    SAPO-34 molecular sieves are synthesized using various structure directing agents (SDAs). Cu-SAPO-34 catalysts are prepared via aqueous solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies. Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34 samples undergo different extent of structural damage via irreversible hydrolysis. Si content within the samples (i.e., Al-O-Si bond density) and framework stress are key factors that affect irreversible hydrolysis. Even using very dilute Cu acetate solutions, it is not possible to generate Cu-SAPO-34 samples with only isolated Cu2+ ions. Small amounts of CuOx species always coexist with isolated Cu2+ ions. Highly active and selective Cu-SAPO-34 catalysts for NH3-SCR are readily generated using this synthesis protocol, even for SAPO-34 samples that degrade substantially during solution ion exchange. High-temperature aging is found to improve the catalytic performance. This is likely due to reduction of intracrystalline mass-transfer limitations via formation of additional porosity in the highly defective SAPO-34 particles formed after ion exchange. The authors gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Office of Vehicle Technologies for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOEs Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute under contract number DE-AC05-76RL01830.

  19. Solid SCR Demonstration Truck Application | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SCR Demonstration Truck Application Solid SCR Demonstration Truck Application Demonstrate the feasibility and performance of the FEV Solid SCR (Ammonium Carbamate) Technology PDF...

  20. Modeling Study of SCR/PGM Interactions in NH3 Slip Catalysts | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Study of SCR/PGM Interactions in NH3 Slip Catalysts Modeling Study of SCR/PGM Interactions in NH3 Slip Catalysts The focus of this research is on the optimization of NH3 slip catalyst performance by simulating the behavior of different SCR/PGM configurations. PDF icon p-19_nova.pdf More Documents & Publications Experimental and Modelling Study of the Effect of Diffusional Limitations on the NH3 SCR Activity Selective ammonia slip catalyst enabling highly efficient NOx removal

  1. Selective Catalytic Reduction and Exhaust Gas Recirculation Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Strategies for Integrated Emission Control Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus State-of-the-Art and Emergin Truck Engine Technologies...

  2. SCR Performance Optimization Through Advancements in Aftertreatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance Optimization Through Advancements in Aftertreatment Packaging SCR Performance Optimization Through Advancements in Aftertreatment Packaging The impact of improved urea...

  3. Evaluation of NH3-SCR Catalyst Technology on a 250-kW Stationary Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Genset | Department of Energy NH3-SCR Catalyst Technology on a 250-kW Stationary Diesel Genset Evaluation of NH3-SCR Catalyst Technology on a 250-kW Stationary Diesel Genset 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_malyala.pdf More Documents & Publications Two Catalyst Formulations - One Solution for NOx After-treatment Systems Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Development of Optimal Catalyst

  4. Update on Progress of APBF-DEC EGR/DPF/SCR Demonstration Program at SwRI |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Progress of APBF-DEC EGR/DPF/SCR Demonstration Program at SwRI Update on Progress of APBF-DEC EGR/DPF/SCR Demonstration Program at SwRI 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Southwest Research Institute PDF icon 2004_deer_khair.pdf More Documents & Publications Final Update on APBF-DEC EGR/DPF/SCR Demonstration Project at SwRI Low Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A Progress Report Low Emisssions

  5. Economic Comparison of LNT Versus Urea SCR for Light-Duty Diesel Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in the U.S. Market | Department of Energy Comparison of LNT Versus Urea SCR for Light-Duty Diesel Vehicles in the U.S. Market Economic Comparison of LNT Versus Urea SCR for Light-Duty Diesel Vehicles in the U.S. Market 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Ford Motor Company PDF icon 2004_deer_hoard.pdf More Documents & Publications Laboratory and Vehicle Demonstration of a "2nd-Generation" LNT+in-situ SCR Diesel NOx Emission Control Concept NH3

  6. 15.04.14 R Selective Reduction - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selective Reduction of CO2 to Methane Luca, O. R., McCrory, C. C. L., Dalleska, N. F. & Koval, C. A. The Selective Electrochemical Conversion of Preactivated CO2 to Methane. Journal of The Electrochemical Society, 162(7), H473-476, DOI: 10.1149/2.0371507jes (2015). Scientific Achievement Demonstration of selective electrochemical reduction of CO2 to methane with Faradaic efficiency as high as 93%. Significance & impact CO2 is preactivated with an N-heterocyclic carbene, and in the

  7. Investigation on continuous soot oxidation and NOx reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on continuous soot oxidation and NOx reduction by SCR coated DPF Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF Evaluation of CSI catalyst for NOx...

  8. Ammonia Sensor for SCR NOX Reduction

    Broader source: Energy.gov [DOE]

    Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  9. SCR & DPF RETROFITS FOR MOBILE DIESEL ENGINES | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & DPF RETROFITS FOR MOBILE DIESEL ENGINES SCR & DPF RETROFITS FOR MOBILE DIESEL ENGINES 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_leprince.pdf More Documents & Publications Development of ADECS to Meet 2010 Emission Levels: Optimization of NOx, NH3 and Fuel Consumption Using High and Low Engine-Out NOx Calibrations Low Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A Progress Report The Development and

  10. Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bin 5 DOE and Ford Motor Company Advanced CIDI Emission Control System Development Program (DE-FC26-01NT41103) | Department of Energy 5 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_lambert.pdf More Documents & Publications Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 Urea SCR and DPF System for Tier 2 Diesel Light-Duty Trucks

  11. Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bin 5 DOE and Ford Motor Company Advanced CIDI Emission Control System Development Program (DE-FC26-01NT41103) | Department of Energy 4 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Ford Motor Company PDF icon 2004_deer_hammerle.pdf More Documents & Publications Urea SCR and DPF System for Deisel Sport Utility Vehicle Meeting Tier II Bin 5 Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5

  12. SCR Tech LLC | Open Energy Information

    Open Energy Info (EERE)

    Sector: Services Product: US-based provider of catalyst regeneration technologies and management services for SCR systems. Coordinates: 35.2225, -80.837539 Show Map Loading...

  13. Sinia Renovables SCR | Open Energy Information

    Open Energy Info (EERE)

    Name: Sinia Renovables SCR Place: Spain Sector: Renewable Energy Product: Investment arm of Banco Sabadell, involved in the financing of renewable energy projects. References:...

  14. Method of selective reduction of polyhalosilanes with alkyltin hydrides

    DOE Patents [OSTI]

    Sharp, Kenneth G.; D'Errico, John J.

    1989-01-01

    The invention relates to the selective and stepwise reduction of polyhalosilanes by reacting at room temperature or below with alkyltin hydrides without the use of free radical intermediates. Alkyltin hydrides selectively and stepwise reduce the Si--Br, Si--Cl, or Si--I bonds while leaving intact any Si--F bonds. When two or more different halogens are present on the polyhalosilane, the halogen with the highest atomic weight is preferentially reduced.

  15. Method of selective reduction of halodisilanes with alkyltin hydrides

    DOE Patents [OSTI]

    D'Errico, John J.; Sharp, Kenneth G.

    1989-01-01

    The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.

  16. Urea/Ammonia Distribution Optimization in an SCR Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ammonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis UreaAmmonia Distribution Optimization in an SCR Emission Control System...

  17. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite...

    Office of Scientific and Technical Information (OSTI)

    Book: Understanding NOx SCR Mechanism and Activity on CuChabazite Structures throughout the Catalyst Life Cycle Citation Details In-Document Search Title: Understanding NOx SCR...

  18. Application Experience with a Combined SCR and DPF Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experience with a Combined SCR and DPF Technology for Heavy Duty Diesel Retrofit Application Experience with a Combined SCR and DPF Technology for Heavy Duty Diesel Retrofit ...

  19. Combination & Integration of DPF-SCR Aftertreatment Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integration of DPF-SCR Aftertreatment Technologies Work is undertaken to examine the feasibility of integrating SCR and DPF technologies for the next generation of emission control...

  20. In-line localized monitoring of catalyst activity in selective catalytic NO.sub.x reduction systems

    DOE Patents [OSTI]

    Muzio, Lawrence J. (Laguna Niguel, CA); Smith, Randall A. (Huntington Beach, CA)

    2009-12-22

    Localized catalyst activity in an SCR unit for controlling emissions from a boiler, power plant, or any facility that generates NO.sub.x-containing flue gases is monitored by one or more modules that operate on-line without disrupting the normal operation of the facility. Each module is positioned over a designated lateral area of one of the catalyst beds in the SCR unit, and supplies ammonia, urea, or other suitable reductant to the catalyst in the designated area at a rate that produces an excess of the reductant over NO.sub.x on a molar basis through the designated area. Sampling probes upstream and downstream of the designated area draw samples of the gas stream for NO.sub.x analysis, and the catalyst activity is determined from the difference in NO.sub.x levels between the two probes.

  1. New Developments in Titania-Based Catalysts for Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction of NOx | Department of Energy Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx New Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_chapman.pdf More Documents & Publications The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR

  2. Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge...

  3. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  4. Thermolysis Characterization of Urea-SCR | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermolysis Characterization of Urea-SCR Thermolysis Characterization of Urea-SCR 2002 DEER Conference Presentation: Cummins Inc. PDF icon 2002_deer_fang.pdf More Documents & Publications Recent Advances and Future Challenges in the Modeling and Simulations of the injection of Urea-Water-Solution for Automotive SCR Systems An Experimental Study of PM Emission Characteristics of Commercial Diesel Engine with Urea-SCR System SCR Performance Optimization Through Advancements in Aftertreatment

  5. Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_seguelong.pdf More Documents & Publications Potential Effect of Pollutantn Emissions on Global Warming: First Comparisong Using External Costs on Urban Buses Vehicle Emissions Review - 2012 Comparative Study on

  6. Understanding the Deactivation Mechanisms of Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zeolite SCR Catalysts in Diesel Application To understand the durability of CuZeolite urea-SCR catalysts in diesel applications, the effects of engine and lab aging on catalyst...

  7. European Experience and Case study of SCR Passenger Car Integration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experience and Case study of SCR Passenger Car Integration European Experience and Case study of SCR Passenger Car Integration Presentation given at DEER 2006, August 20-24, 2006, ...

  8. Combination & Integration of DPF-SCR Aftertreatment Technologies |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Aftertreatment Technologies Combination & Integration of DPF-SCR Aftertreatment Technologies Work is undertaken to examine the feasibility of integrating SCR and DPF technologies for the next generation of emission control systems for on-road heavy-truck application PDF icon deer11_rappe.pdf More Documents & Publications Combination and Integration of DPF-SCR Aftertreatment Technologies Combination & Integration of DPF-SCR Aftertreatment

  9. Combination and Integration of DPF-SCR Aftertreatment Technologies |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace025_rappe_2012_o.pdf More Documents & Publications Combination and Integration of DPF-SCR Aftertreatment Technologies Combination & Integration of DPF-SCR Aftertreatment Technologies Combination & Integration of DPF-SCR Aftertreatment

  10. Combination and Integration of DPF-SCR Aftertreatment Technologies |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace025_rappe_2011_o.pdf More Documents & Publications Combination and Integration of DPF-SCR Aftertreatment Technologies Combination and Integration of DPF-SCR Aftertreatment Technologies Combination & Integration of DPF-SCR Aftertreatment Technologies

  11. Modeling Species Inhibition and Competitive Adsorption in Urea-SCR Catalysts

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Lee, Jong H.

    2012-04-16

    Although the urea-SCR technology exhibits high NOx reduction efficiency over a wide range of temperatures among the lean NOx reduction technologies, further improvement in low-temperature performance is required to meet the future emission standards and to lower the system cost. In order to improve the catalyst technologies and optimize the system performance, it is critical to understand the reaction mechanisms and catalyst behaviors with respect to operating conditions. Urea-SCR catalysts exhibit poor NOx reduction performance at low temperature operating conditions (T < 150 C). We postulate that the poor performance is either due to NH3 storage inhibition by species like hydrocarbons or due to competitive adsorption between NH3 and other adsorbates such as H2O and hydrocarbons in the exhaust stream. In this paper we attempt to develop one-dimensional models to characterize inhibition and competitive adsorption in Fe-zeolite based urea-SCR catalysts based on bench reactor experiments. We further use the competitive adsorption (CA) model to develop a standard SCR model based on previously identified kinetics. Simulation results indicate that the CA model predicts catalyst outlet NO and NH3 concentrations with minimal root mean square error.

  12. Integrated Removal of NOx with Carbon Monoxide as Reductant, and Capture of Mercury in a Low Temperature Selective Catalytic and Adsorptive Reactor

    SciTech Connect (OSTI)

    Neville Pinto; Panagiotis Smirniotis; Stephen Thiel

    2010-08-31

    Coal will likely continue to be a dominant component of power generation in the foreseeable future. This project addresses the issue of environmental compliance for two important pollutants: NO{sub x} and mercury. Integration of emission control units is in principle possible through a Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR) in which NO{sub x} removal is achieved in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The capture of mercury is integrated into the same process unit. Such an arrangement would reduce mercury removal costs significantly, and provide improved control for the ultimate disposal of mercury. The work completed in this project demonstrates that the use of CO as a reductant in LTSCR is technically feasible using supported manganese oxide catalysts, that the simultaneous warm-gas capture of elemental and oxidized mercury is technically feasible using both nanostructured chelating adsorbents and ceria-titania-based materials, and that integrated removal of mercury and NO{sub x} is technically feasible using ceria-titania-based materials.

  13. SCR-DPF Integrations for Diesel ExhaustPerformance and Perspectives for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High SCR Loadings | Department of Energy SCR-DPF Integrations for Diesel ExhaustPerformance and Perspectives for High SCR Loadings SCR-DPF Integrations for Diesel ExhaustPerformance and Perspectives for High SCR Loadings Presents laboratory and engine bench test results from integrating the SCR catalyst into the diesel filter as one multifunctional unit. PDF icon deer12_folic.pdf More Documents & Publications Development of SCR on Diesel Particulate Filter System for Heavy Duty

  14. Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (PCCI) combustion | Department of Energy fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion Analyzed the effects of higher hydrocarbon emissions from PCCI combustion on SCR catalysts in operating a light-duty 1.9-liter GM diesel engine in both PCCI and conventional combustion modes PDF icon deer11_parks.pdf More Documents & Publications Efficient Emissions Control for

  15. Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Life Requirements | Department of Energy Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements EAS performance results following 500 DeSOx CyclesMeets Off-Road Final Tier 4 and HD On-road Emission Standards PDF icon deer09_mccarthy.pdf More Documents & Publications Improved System Performance and Reduced Cost of a Fuel Reformer, LNT, and SCR Aftertreatment System

  16. Combination and Integration of DPF-SCR Aftertreatment Technologies |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace025_rappe_2010_o.pdf More Documents & Publications Combination and Integration of DPF-SCR Aftertreatment Technologies Combination and Integration of DPF-SCR Aftertreatment Technologies Combination & Integration of DPF-SCR Aftertreatment

  17. SCR Systems for Heavy Duty Trucks: Progress Towards Meeting Euro...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems for Heavy Duty Trucks: Progress Towards Meeting Euro 4 Emission Standards in 2005 SCR Systems for Heavy Duty Trucks: Progress Towards Meeting Euro 4 Emission Standards in ...

  18. Improvement of Urea SCR Performance Using Wiremesh Thermolysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improvement of Urea SCR Performance Using Wiremesh Thermolysis Mixer Wiremesh mixer development should bring harmony between injection, thermolysis, and mixing. PDF icon ...

  19. Passive Ammonia SCR for Lean Burn SIDI Engines

    Broader source: Energy.gov [DOE]

    Passive NH3 SCR has been demonstrated as a high efficiency and low cost alternative lean NOx aftertreatment technology for stratified gasoline engines.

  20. Experimental Studies for DPF and SCR Model, Control System, and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Diesel and Biodiesel Fuels Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels Combination and ...

  1. Experimental Studies for DPF and SCR Model, Control System, and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Diesel and Biodiesel Fuels Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels Measuring PM ...

  2. Experimental Studies for DPF and SCR Model, Control System, and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Diesel and Biodiesel Fuels Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels Advanced Engine...

  3. Components for Optimized SCR Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Optimized SCR Systems Components for Optimized SCR Systems Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_rice.pdf More Documents & Publications Design Potential of Metal Foil Substrates for Optimized DOC Performance Application of SCR and PM-METALIT for Non-Road Applications: SCRi Urea/Ammonia Distribution Optimization in an SCR Emission Control

  4. SCR Potential and Issues for Heavy-Duty Applications in the United States |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Potential and Issues for Heavy-Duty Applications in the United States SCR Potential and Issues for Heavy-Duty Applications in the United States 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Daimler Chrysler Detroit Diesel Corporation PDF icon 2004_deer_aneja.pdf More Documents & Publications Aftertreatment Modeling Status, Futur Potential, and Application Issues Integrated Engine and Aftertreatment Technology Roadmap for EPA 2010 Heavy-duty

  5. CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace022_daw_2010_o.pdf More Documents & Publications CLEERS Coordination & Development of Catalyst Process Kinetic Data CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR Functionality of Commercial NOx Storage-Reduction Catalysts and the Development of a Representative Model

  6. 3rd Generation SCR System Using Solid Ammonia Storage and Direct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct...

  7. Deactivation of Accelerated Engine-Aged and Field-Aged SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deactivation of Accelerated Engine-Aged and Field-Aged SCR Catalysts and the Role of the DOC A technique for accelerated aging of SCR system (DOC -> SCR-> DPF) reveals two ...

  8. SCR-DPF Integrations for Diesel ExhaustPerformance and Perspectives...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the SCR catalyst into the diesel filter as one multifunctional unit. PDF icon deer12folic.pdf More Documents & Publications Development of SCR on Diesel Particulate Filter...

  9. Evaluation of 2010 Urea-SCR Technology for Hybrid Vehicles using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2010 Urea-SCR Technology for Hybrid Vehicles using PSAT System Simulations Evaluation of 2010 Urea-SCR Technology for Hybrid Vehicles using PSAT System Simulations Results of ...

  10. Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device

    DOE Patents [OSTI]

    Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

    2014-05-06

    A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

  11. Method For Selective Catalytic Reduction Of Nitrogen Oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  12. Method for selective catalytic reduction of nitrogen oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  13. Method and system for SCR optimization

    DOE Patents [OSTI]

    Lefebvre, Wesley Curt (Boston, MA); Kohn, Daniel W. (Cambridge, MA)

    2009-03-10

    Methods and systems are provided for controlling SCR performance in a boiler. The boiler includes one or more generally cross sectional areas. Each cross sectional area can be characterized by one or more profiles of one or more conditions affecting SCR performance and be associated with one or more adjustable desired profiles of the one or more conditions during the operation of the boiler. The performance of the boiler can be characterized by boiler performance parameters. A system in accordance with one or more embodiments of the invention can include a controller input for receiving a performance goal for the boiler corresponding to at least one of the boiler performance parameters and for receiving data values corresponding to boiler control variables and to the boiler performance parameters. The boiler control variables include one or more current profiles of the one or more conditions. The system also includes a system model that relates one or more profiles of the one or more conditions in the boiler to the boiler performance parameters. The system also includes an indirect controller that determines one or more desired profiles of the one or more conditions to satisfy the performance goal for the boiler. The indirect controller uses the system model, the received data values and the received performance goal to determine the one or more desired profiles of the one or more conditions. The system model also includes a controller output that outputs the one or more desired profiles of the one or more conditions.

  14. Impact of Biodiesel-based Na on the Selective Catalytic Reduction...

    Office of Scientific and Technical Information (OSTI)

    of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Citation Details In-Document Search Title: Impact of Biodiesel-based Na on the ...

  15. Combination & Integration of DPF-SCR Aftertreatment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment Combination & Integration of DPF-SCR Aftertreatment Work focused on optimizing SCR washcoat within the DPF substrate, and maximizing the capacity for passive soot oxidation exhibited in the system PDF icon deer12_rappe.pdf More Documents & Publications Combination and Integration of DPF-SCR Aftertreatment Technologies Combination & Integration of DPF-SCR Aftertreatment Technologies

  16. TRIAC/SCR proportional control circuit

    DOE Patents [OSTI]

    Hughes, W.J.

    1999-04-06

    A power controller device is disclosed which uses a voltage-to-frequency converter in conjunction with a zero crossing detector to linearly and proportionally control AC power being supplied to a load. The output of the voltage-to frequency converter controls the ``reset`` input of a R-S flip flop, while an ``0`` crossing detector controls the ``set`` input. The output of the flip flop triggers a monostable multivibrator controlling the SCR or TRIAC firing circuit connected to the load. Logic gates prevent the direct triggering of the multivibrator in the rare instance where the ``reset`` and ``set`` inputs of the flip flop are in coincidence. The control circuit can be supplemented with a control loop, providing compensation for line voltage variations. 9 figs.

  17. TRIAC/SCR proportional control circuit

    DOE Patents [OSTI]

    Hughes, Wallace J. (Boston Lake, NY)

    1999-01-01

    A power controller device which uses a voltage-to-frequency converter in conjunction with a zero crossing detector to linearly and proportionally control AC power being supplied to a load. The output of the voltage-to frequency converter controls the "reset" input of a R-S flip flop, while an "0" crossing detector controls the "set" input. The output of the flip flop triggers a monostable multivibrator controlling the SCR or TRIAC firing circuit connected to the load. Logic gates prevent the direct triggering of the multivibrator in the rare instance where the "reset" and "set" inputs of the flip flop are in coincidence. The control circuit can be supplemented with a control loop, providing compensation for line voltage variations.

  18. European Experience and Case study of SCR Passenger Car Integration |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Experience and Case study of SCR Passenger Car Integration European Experience and Case study of SCR Passenger Car Integration Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_vanschaftingen.pdf More Documents & Publications SCR Systems for Heavy Duty Trucks: Progress Towards Meeting Euro 4 Emission Standards in 2005 Safe and

  19. Progress Update: Creating Mobile Emission Reduction Credits | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Update: Creating Mobile Emission Reduction Credits Progress Update: Creating Mobile Emission Reduction Credits 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Emission Reduction Specialists PDF icon 2004_deer_sloan.pdf More Documents & Publications Creating Mobile Emission Reduction Credits ADEC II Universal SCR Retrofit System for On-road and Off-road Diesel Engines SCR & DPF RETROFITS FOR MOBILE DIESEL ENGINES

  20. 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct ammonia gas dosing for optimal SCR performance with simplified and flexible exhaust layout. PDF icon deer12_johannessen.pdf More Documents & Publications Ammonia storage and delivery systems for NOx aftertreatment Safe and compact ammonia storage/delivery systems for SCR-DeNOX in automotive

  1. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials Sulfur Effect and Performance Recovery of a DOC...

  2. Selective reduction of NOx in oxygen rich environments with plasma-assisted

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    catalysis: Catalyst development and mechanistic studies | Department of Energy reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies 2003 DEER Conference Presentation: Pacific Northwest National Laboratory PDF icon 2003_deer_peden.pdf More Documents & Publications Plasma-Activated Lean NOx

  3. SCR Performance Optimization Through Advancements in Aftertreatment Packaging

    Broader source: Energy.gov [DOE]

    The impact of improved urea mixing designs on urea vaporization and ammonia distribution is presented, along with a comparison of single and dual walled packaging for SCR systems. Urea doser integration is also investigated.

  4. Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by

    Office of Scientific and Technical Information (OSTI)

    NH3 Over Cu-zeolite Catalysts (Journal Article) | SciTech Connect Journal Article: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Citation Details In-Document Search Title: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Authors: Brookshear, D. William [1] ; Nguyen, Ke [1] ; Toops, Todd J [2] ; Bunting, Bruce G [2] ; Rohr, William F [2] + Show Author Affiliations University of

  5. Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype confirms Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype

  6. MODELING COMPETITIVE ADSORPTION IN UREA-SCR CATALYSTS FOR EFFECTIVE LOW TEMPERATURE NOX CONTROL

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

    2010-09-17

    Although the SCR technology exhibits higher NOx reduction efficiency over a wider range of temperatures among the lean NOx reduction technologies, further improvement in low-temperature performance is required to meet the future emission standards and to lower the system cost. In order to improve the catalyst technologies and optimize the system performance, it is critical to understand the reaction mechanisms and catalyst behaviors with respect to operating conditions. For example, it is well known that the ammonia coverage on catalyst surface is critical for NOx reduction efficiency. However, the level of ammonia storage is influenced by competitive adsorption by other species, such as H2O and NO2. Moreover, hydrocarbon species that slip through the upstream DOC during the cold-start period can also inhibit the SCR performance, especially at low temperatures. Therefore, a one-dimensional detailed kinetic model that can account for the effects of such competitive adsorption has been developed based on steady state surface isotherm tests on a commercial Fe-zeolite catalyst. The model is developed as a C language S-function and implemented in Matlab/Simulink environment. Rate kinetics of adsorption and desorption of each of the adsorbents are determined from individual adsorption tests and validated for a set of test conditions that had all the adsorbents in the feed gas.

  7. Experimental Studies for CPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels

    SciTech Connect (OSTI)

    Johnson, John; Naber, Jeffrey; Parker, Gordon; Yang, Song-Lin; Stevens, Andrews; Pihl, Josh

    2013-04-30

    The research carried out on this project developed experimentally validated Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), and Selective Catalytic Reduction (SCR) high?fidelity models that served as the basis for the reduced order models used for internal state estimation. The high?fidelity and reduced order/estimator codes were evaluated by the industrial partners with feedback to MTU that improved the codes. Ammonia, particulate matter (PM) mass retained, PM concentration, and NOX sensors were evaluated and used in conjunction with the estimator codes. The data collected from PM experiments were used to develop the PM kinetics using the high?fidelity DPF code for both NO2 assisted oxidation and thermal oxidation for Ultra Low Sulfur Fuel (ULSF), and B10 and B20 biodiesel fuels. Nine SAE papers were presented and this technology transfer process should provide the basis for industry to improve the OBD and control of urea injection and fuel injection for active regeneration of the PM in the DPF using the computational techniques developed. This knowledge will provide industry the ability to reduce the emissions and fuel consumption from vehicles in the field. Four MS and three PhD Mechanical Engineering students were supported on this project and their thesis research provided them with expertise in experimental, modeling, and controls in aftertreatment systems.

  8. LNT or Urea SCR Technology: Which is the right technology for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or Urea SCR Technology: Which is the right technology for TIER 2 BIN 5 passenger vehicles? LNT or Urea SCR Technology: Which is the right technology for TIER 2 BIN 5 passenger...

  9. Economic Comparison of LNT Versus Urea SCR for Light-Duty Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Comparison of LNT Versus Urea SCR for Light-Duty Diesel Vehicles in the U.S. Market Economic Comparison of LNT Versus Urea SCR for Light-Duty Diesel Vehicles in the U.S. Market ...

  10. Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Lean-burn SIDI ...

  11. Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 2003 DEER ... Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 DOE and ...

  12. ADEC II Universal SCR Retrofit System for On-road and Off-road...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ADEC II Universal SCR Retrofit System for On-road and Off-road Diesel Engines ADEC II Universal SCR Retrofit System for On-road and Off-road Diesel Engines Presentation given at ...

  13. Low Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A Progress Report Low Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A Progress Report 2003...

  14. Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based Systems Approach Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based Systems Approach This...

  15. Creating Mobile Emission Reduction Credits | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Creating Mobile Emission Reduction Credits Creating Mobile Emission Reduction Credits 2002 DEER Conference Presentation: Emission Credit Brokers PDF icon 2002_deer_sloan.pdf More Documents & Publications Progress Update: Creating Mobile Emission Reduction Credits An Experimental Study of PM Emission Characteristics of Commercial Diesel Engine with Urea-SCR System Evaluation of NH3-SCR Catalyst Technology on a 250-kW Stationary Diesel Genset

  16. A Study and Comparison of SCR Reaction Kinetics from Reactor and Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experimental Data | Department of Energy A Study and Comparison of SCR Reaction Kinetics from Reactor and Engine Experimental Data A Study and Comparison of SCR Reaction Kinetics from Reactor and Engine Experimental Data Presents experimental study of a Cu-zeolite SCR in both reactor and engine test cell, and comparison of the model parameters between the SCR reactor and engine model PDF icon p-27_song.pdf More Documents & Publications Measurement and Modeling of Spatial NH3 Storage

  17. Impact of Honeycomb Ceramics Geometrical Cell Design on Urea SCR System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Honeycomb Ceramics Geometrical Cell Design on Urea SCR System Impact of Honeycomb Ceramics Geometrical Cell Design on Urea SCR System Honeycomb ceramic substrates with 3 cell geometries were performance tested for Nox conversion. Results provide suggestions for the best cell structure for SCR systems. PDF icon p-04_fujii.pdf More Documents & Publications Laboratory and Vehicle Demonstration of a "2nd-Generation" LNT+in-situ SCR Diesel NOx Emission Control

  18. Low Emisssions Potential of EGR-SCR-DPF and Advanced Fuel Formulations - A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Progress Report | Department of Energy Emisssions Potential of EGR-SCR-DPF and Advanced Fuel Formulations - A Progress Report Low Emisssions Potential of EGR-SCR-DPF and Advanced Fuel Formulations - A Progress Report 2002 DEER Conference Presentation: Southwest Research Insititute PDF icon 2002_deer_khair.pdf More Documents & Publications Low Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A Progress Report Update on Progress of APBF-DEC EGR/DPF/SCR Demonstration

  19. Nonroad SCR-Urea Study | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nonroad SCR-Urea Study Nonroad SCR-Urea Study Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_schubert.pdf More Documents & Publications Distributing Urea for the On-Road Vehicle Market Ensuring the Availability and Reliability of Urea Dosing For On-Road and Non-Road

  20. N2O Emissions From 2010 SCR Systems

    Broader source: Energy.gov [DOE]

    Reviews potential contribution to N2O formation of typical diesel exhaust aftertreatment system based on selective catalytic reduction depending on catalyst properties, and exhaust temperature and gas composition

  1. Synthesis and Evaluation of Cu/SAPO-34 Catalysts for NH3-SCR 2: Solid-state Ion Exchange and One-pot Synthesis

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2015-01-01

    Cu-SAPO-34 catalysts are synthesized using two methods: solid-state ion exchange (SSIE) and one-pot synthesis. SSIE is conducted by calcining SAPO-34/CuO mixtures at elevated temperatures. For the one-pot synthesis method, Cu-containing chemicals (CuO and CuSO4) are added during gel preparation. A high-temperature calcination step is also needed for this method. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies, and scanning electron microscopy (SEM). Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. In Cu-SAPO-34 samples formed using SSIE, Cu presents both as isolated Cu2+ ions and unreacted CuO. The former is highly active and selective in NH3-SCR, while the latter catalyzes a side reaction; notably, the non-selective oxidation of NH3 above 350 C. Using the one-pot method followed by a high-temperature aging treatment, it is possible to form Cu SAPO-34 samples with predominately isolated Cu2+ ions at low Cu loadings. However at much higher Cu loadings, isolated Cu2+ ions that bind weakly with the CHA framework and CuO clusters also form. These Cu moieties are very active in catalyzing non-selective NH3 oxidation above 350 C. Low-temperature reaction kinetics indicate that Cu-SAPO-34 samples formed using SSIE have core-shell structures where Cu is enriched in the shell layers; while Cu is more evenly distributed within the one-pot samples. Reaction kinetics also suggest that at low temperatures, the local environment next to Cu2+ ion centers plays little role on the overall catalytic properties. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOEs Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle under contract number DE-AC05-76RL01830. The authors also thank Shari Li (PNNL) for surface area/pore volume measurements, and Bruce W. Arey (PNNL) for SEM measurements. Discussions with Drs. A. Yezerets, K. Kamasamudram, J.H. Li, N. Currier and J.Y. Luo from Cummins, Inc. and H.Y. Chen and H. Hess from Johnson-Matthey are greatly appreciated.

  2. Urea SCR Durability Assessment for Tier 2 Light-Duty Truck | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Durability Assessment for Tier 2 Light-Duty Truck Urea SCR Durability Assessment for Tier 2 Light-Duty Truck Summarizes progress toward development of a durable urea SCR system to meet Tier 2 Bin 5 on 3780 lb light truck PDF icon deer08_dobson.pdf More Documents & Publications Laboratory and Vehicle Demonstration of a "2nd-Generation" LNT+in-situ SCR Diesel NOx Emission Control Concept Future Trends for DPFƒSCR On-Filter (SCRF) Combination and Integration of DPF-SCR

  3. Lower Freezing DEF For Higher NOx Reduction Attainment | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Freezing DEF For Higher NOx Reduction Attainment Lower Freezing DEF For Higher NOx Reduction Attainment NOx emissions data from bench-scale experiments and Class III truck operated using a low freezing point diesel exhaust fluid PDF icon deer11_highfield.pdf More Documents & Publications Urea Mixing Design -- Simulation and Test Investigation 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing Urea SCR and DPF System for Deisel Sport Utility Vehicle Meeting

  4. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-06-01

    It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. A decrease in DOC activity was seen after exposure to 150,000 mile equivalent aging, resulting in higher HC slip and a reduction in NO{sub 2} formation. The metal-zeolite SCR catalyst experienced a slight loss in activity after exposure to 435,000 mile equivalent aging. This catalyst, placed downstream of the DPF, showed a 5% reduction in overall NOx conversion activity over the HDDT test cycle.

  5. Metal-supported De-NOx SCR Catalysts Prepared by Room Temperature Aerosol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deposition for Potential Marine Applications | Department of Energy supported De-NOx SCR Catalysts Prepared by Room Temperature Aerosol Deposition for Potential Marine Applications Metal-supported De-NOx SCR Catalysts Prepared by Room Temperature Aerosol Deposition for Potential Marine Applications Presents preparation of SCR catalyst coatings on cost effective metallic substrates using aerosol deposition technique and their catalytic De-NOx performance PDF icon p-06_choi.pdf More Documents

  6. Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyst | Department of Energy Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_henry.pdf More Documents & Publications The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst Vehicle Technologies Office Merit

  7. Understanding the Deactivation Mechanisms of Cu/Zeolite SCR Catalysts in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Application | Department of Energy Deactivation Mechanisms of Cu/Zeolite SCR Catalysts in Diesel Application Understanding the Deactivation Mechanisms of Cu/Zeolite SCR Catalysts in Diesel Application To understand the durability of Cu/Zeolite urea-SCR catalysts in diesel applications, the effects of engine and lab aging on catalyst reactivity and material properties were investigated. PDF icon deer08_cheng.pdf More Documents & Publications Deactivation Mechanisms of Base

  8. Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aging Conditions | Department of Energy Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions Volatility of Vanadia from Vanadia-Based SCR Catalysts under Accelerated Aging Conditions TiO2-supported vanadia (and tungsta) can be stabillized by optimization of the catalyst support PDF icon p-03_chapman.pdf More Documents & Publications The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application New Developments in Titania-Based Catalysts

  9. Safe and compact ammonia storage/delivery systems for SCR-DeNOX...

    Broader source: Energy.gov (indexed) [DOE]

    johannessen.pdf More Documents & Publications Ammonia storage and delivery systems for NOx aftertreatment 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas...

  10. Low Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Progress Report | Department of Energy Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A Progress Report Low Emissions Potential of EGR-SCR-DPF and Advanced Fuel Formulation - A Progress Report 2003 DEER Conference Presentation: Southwest Research Institute PDF icon deer_2003_khair.pdf More Documents & Publications Final Update on APBF-DEC EGR/DPF/SCR Demonstration Project at SwRI Low Emisssions Potential of EGR-SCR-DPF and Advanced Fuel Formulations - A Progress

  11. Development of a Durable Low-Temperature Urea-SCR Catalyst for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of a Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines 2004 Diesel ... More Documents & Publications Experimental and Modelling Study of the Effect of ...

  12. Simplification of Diesel Emission Control System Packaging Using SCR Coated on DPF

    Broader source: Energy.gov [DOE]

    Study demonstrates high NOx conversion with SCR coated on DPF. Optimization of catalyst washcoat and coating process minimizes back-pressure while maintaining good performance.

  13. Evaluation of SCR and DOC/CPF Tech in Diesel Exhaust Emission Control to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meet U.S. Tier 2 Bin 5 | Department of Energy SCR and DOC/CPF Tech in Diesel Exhaust Emission Control to Meet U.S. Tier 2 Bin 5 Evaluation of SCR and DOC/CPF Tech in Diesel Exhaust Emission Control to Meet U.S. Tier 2 Bin 5 The continuous regeneration trap may cause irreversibly negative effects on the NOx removal efficiency of the SCR system. PDF icon deer08_choung.pdf More Documents & Publications Experimental Studies for DPF and SCR Model, Control System, and OBD Development for

  14. The PUREM SCR System with AdBlue | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The PUREM SCR System with AdBlue The PUREM SCR System with AdBlue Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_wilhelm.pdf More Documents & Publications SCR Systems for Heavy Duty Trucks: Progress Towards Meeting Euro 4 Emission Standards in 2005 BLUETEC - Heading for 50 State Diesel Safe and compact ammonia storage/delivery systems for SCR-DeNOX in

  15. Catalyst for reduction of nitrogen oxides

    DOE Patents [OSTI]

    Ott, Kevin C.

    2010-04-06

    A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

  16. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect (OSTI)

    Constance Senior

    2004-12-31

    The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

  17. Discovery of New NOx Reduction Catalysts for CIDI Engines Using Combinatorial Techniques

    SciTech Connect (OSTI)

    Blint, Richard J

    2005-08-15

    This project for the discovery of new lean reduction NOx catalysts was initiated on August 16th, 2002 and is now into its fourth year. Several materials have already been identified as NOx reduction catalysts for possible future application. NOx reduction catalysts are a critical need in the North American vehicle market since these catalysts are needed to enable both diesels and lean gasoline engines to meet the 2007-2010 emission standards. Hydrocarbon selective catalytic reduction (SCR) is a preferred technology since it requires no infrastructure changes (as may be expected for urea SCR) and most likely has the simplest engine control strategy of the three proposed NOx reduction approaches. The use of fast throughput techniques and informatics greatly enhances the possibility of discovering new NOx reduction catalysts. Using fast throughput techniques this project has already screened over 3000 new materials and evaluates hundreds of new materials a month. Evaluating such a high number of new materials puts this approach into a very different paradigm than previous discovery approaches for new NOx reduction catalysts. With so much data on materials it is necessary to use statistical techniques to identify the potential catalysts and these statistical techniques are needed to optimize compositions of the multi-component materials that are identified under the program as possible new lean NOx catalysts. Several new materials have conversions in excess of 80% at temperatures above 300 C. That is more than twice the activity of previous HC SCR materials. These materials are candidates for emission control on heavy-duty systems (i.e.; over 8500 pounds gross weight). Tests of one of the downselected materials on an engine dynamometer show NOx reductions greater than 80% under some conditions even though the net NOx reductions on the HWFET and the US06 cycles were relatively low. The program is scheduled to continue until the end of the 2006 calendar year. Work in the final year will focus on continued discovery and identity of candidate materials, and also on refining the engine operating strategies to increase NOx reduction over a full engine cycle.

  18. Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems Approach | Department of Energy Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based Systems Approach Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based Systems Approach This research points the way for developing a rapid aging cycle for SSCR-DPF systems. PDF icon deer08_bunting.pdf More Documents & Publications Deactivation of Accelerated Engine-Aged and Field-Aged SCR Catalysts and the Role of the DOC Catalyst Characterization

  19. Application of SCR and PM-METALIT for Non-Road Applications: SCRi |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy SCR and PM-METALIT for Non-Road Applications: SCRi Application of SCR and PM-METALIT for Non-Road Applications: SCRi Advantages of this new application of SCR and PM-METALIT for non-road applications include compact design, robustness, low backpressure, and cost PDF icon deer09_pfahl.pdf More Documents & Publications Ensuring the Availability and Reliability of Urea Dosing For On-Road and Non-Road Cleaning Up Non-Road Diesel Vehicles: A Public Health Imperative

  20. Post Mortem of 120k mi Light-Duty Urea SCR and DPF System | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Post Mortem of 120k mi Light-Duty Urea SCR and DPF System Post Mortem of 120k mi Light-Duty Urea SCR and DPF System Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_lambert.pdf More Documents & Publications Urea SCR and DPF System for Tier 2 Diesel Light-Duty Trucks

  1. SCReaming for Low NOx - SCR for the Light Duty Market | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy SCReaming for Low NOx - SCR for the Light Duty Market SCReaming for Low NOx - SCR for the Light Duty Market Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_traver.pdf More Documents & Publications Validated SCR Concept Development Simulation and Analysis of HP/LP EGR for Heavy-Duty Applications New Demands on Heavy Duty Engine Management

  2. Evaluation of 2010 Urea-SCR Technology for Hybrid Vehicles using PSAT

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Simulations | Department of Energy 2010 Urea-SCR Technology for Hybrid Vehicles using PSAT System Simulations Evaluation of 2010 Urea-SCR Technology for Hybrid Vehicles using PSAT System Simulations Results of simulations of LDD hybrid vehicle under hybrid drive cycle conditions in PSAT show the potential impact of urea-SCR NOx controls on HEVs and PHEVs powered by lean-burn engines. PDF icon p-05_gao.pdf More Documents & Publications Effect of Premixed Charge Compression Ignition

  3. Urea SCR and DPF System for Deisel Sport Utility Vehicle Meeting Tier II

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bin 5 | Department of Energy Deisel Sport Utility Vehicle Meeting Tier II Bin 5 Urea SCR and DPF System for Deisel Sport Utility Vehicle Meeting Tier II Bin 5 2002 DEER Conference Presentation: Ford Motor Company PDF icon 2002_deer_hammerle.pdf More Documents & Publications Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 DOE and Ford Motor Company Advanced CIDI Emission Control System Development Program (DE-FC26-01NT41103) Urea SCR and DPF System for

  4. Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bin 5 | Department of Energy Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 2003 DEER Conference Presentation: Ford Motor Company PDF icon 2003_deer_hammerle.pdf More Documents & Publications Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 DOE and Ford Motor Company Advanced CIDI Emission Control System Development Program (DE-FC26-01NT41103) Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 DOE

  5. Urea SCR and DPF System for Tier 2 Diesel Light-Duty Trucks | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Tier 2 Diesel Light-Duty Trucks Urea SCR and DPF System for Tier 2 Diesel Light-Duty Trucks Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_lambert.pdf More Documents & Publications Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 Urea SCR and DPF System for Diesel Sport Utility Vehicle Meeting Tier II Bin 5 DOE

  6. NO{sub x} reduction RACT compliance requires careful technology selection

    SciTech Connect (OSTI)

    Heckler, G.B.

    1996-05-01

    After the Clean Air Act Amendments passed in 1990, Title I (Attainment and Maintenance of Ambient Air Quality Standards) and Title IV (Acid Deposition Control) of the Act required power plants to submit and implement compliance plans for NO{sub x} and volatile organic compounds (VOC) emissions, among other pollutants. This legislation affected PECO Energy Co.`s Eddystone Generating Station, requiring the utility to comply with the Act under reasonably available control technology (RACT) rules established by the state of Pennsylvania. After carefully considering alternatives aligned with the RACT rules for Pennsylvania, PECO adopted a compliance strategy and submitted it to the Pennsylvania Department of Environmental Protection (PaDEP) for review and approval. Under the case-by-case RACT proposals, the proposed NO{sub x} reduction technology for Units 3 and 4 was to rehabilitate existing OFA ports which had been bricked over. Each of the four corners of these units was originally constructed with an OFA port located in the boiler side walls. Also under the case-by-case RACT proposals, the proposed NO{sub x} reduction technology for the A, B and C auxiliary boilers was to install low-NO{sub x} burners. Under presumptive RACT proposals, PECO proposed low-NO{sub x} burners with close-coupled OFA (CCOFA) and separated OFA (SOFA) as the proposed NO{sub x}-reduction technology for Units 1 and 2. For the combustion turbines PECO proposed to reduce NO{sub x} by limiting the annual capacity factor to 5 percent or less on a 12-month rolling basis. After considering technological and economic feasibility, the utility proposed no VOC reductions because none of the available VOC reduction technologies fell within RACT guidelines.

  7. Urea SCR and DPF System for Deisel Sport Utility Vehicle Meeting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deisel Sport Utility Vehicle Meeting Tier II Bin 5 Urea SCR and DPF System for Deisel Sport Utility Vehicle Meeting Tier II Bin 5 2002 DEER Conference Presentation: Ford Motor ...

  8. SCR Potential and Issues for Heavy-Duty Applications in the United...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Potential and Issues for Heavy-Duty Applications in the United States SCR Potential and Issues for Heavy-Duty Applications in the United States 2004 Diesel Engine Emissions ...

  9. Metal-supported De-NOx SCR Catalysts Prepared by Room Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presents preparation of SCR catalyst coatings on cost effective metallic substrates using aerosol deposition technique and their catalytic De-NOx performance PDF icon p-06choi.pdf ...

  10. Future Trends for DPFƒSCR On-Filter (SCRF) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Trends for DPFƒSCR On-Filter (SCRF) Future Trends for DPFƒSCR On-Filter (SCRF) Fundamental and application-relevant test data gathered on SCRF filters , along with coating distribution, NOx conversion, pressure drop data, and engine tests, will be discussed. PDF icon p-28_malanga.pdf More Documents & Publications Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel

  11. Experimental Studies for DPF and SCR Model, Control System, and OBD

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development for Engines Using Diesel and Biodiesel Fuels | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace028_johnson_2012_o.pdf More Documents & Publications Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using

  12. Experimental Studies for DPF and SCR Model, Control System, and OBD

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development for Engines Using Diesel and Biodiesel Fuels | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace028_johnson_2011_o.pdf More Documents & Publications Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and

  13. Experimental Studies for DPF and SCR Model, Control System, and OBD

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development for Engines Using Diesel and Biodiesel Fuels | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace028_johnson_2010_o.pdf More Documents & Publications Experimental Studies for DPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels Experimental Studies for DPF and SCR Model, Control System, and OBD Development for

  14. CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace022_daw_2011_o.pdf More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CLEERS Coordination & Development of Catalyst Process Kinetic Data CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR

  15. Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment System | Department of Energy Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Lean-burn SIDI engine technology offers improved fuel economy. PDF icon deer10_viola.pdf More Documents & Publications Emissions Control for Lean Gasoline Engines NH3 generation over commercial Three-Way Catalysts and Lean-NOx Traps Emissions Control for Lean Gasoline Engines

  16. Catalyst and method for reduction of nitrogen oxides

    DOE Patents [OSTI]

    Ott, Kevin C. (Los Alamos, NM)

    2008-08-19

    A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

  17. Catalyst and method for reduction of nitrogen oxides

    DOE Patents [OSTI]

    Ott, Kevin C. (Los Alamos, NM)

    2008-05-27

    A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

  18. Coverage Dependent Charge Reduction of Cationic Gold Clusters on Surfaces Prepared Using Soft Landing of Mass-selected Ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2012-11-29

    The ionic charge state of monodisperse cationic gold clusters on surfaces may be controlled by selecting the coverage of mass-selected ions soft landed onto a substrate. Polydisperse diphosphine-capped gold clusters were synthesized in solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine in the presence of 1,3-bis(diphenylphosphino)propane. The polydisperse gold clusters were introduced into the gas phase by electrospray ionization and mass selection was employed to select a multiply charged cationic cluster species (Au11L53+, m/z = 1409, L = 1,3-bis(diphenylphosphino)propane) which was delivered to the surfaces of four different self-assembled monolayers on gold (SAMs) at coverages of 1011 and 1012 clusters/mm2. Employing the spatial profiling capabilities of in-situ time-of-flight secondary ion mass spectrometry (TOF-SIMS) it is shown that, in addition to the chemical functionality of the monolayer (as demonstrated previously: ACS Nano, 2012, 6, 573) the coverage of cationic gold clusters on the surface may be used to control the distribution of ionic charge states of the soft-landed multiply charged clusters. In the case of a 1H,1H,2H,2H-perfluorodecanethiol SAM (FSAM) almost complete retention of charge by the deposited Au11L53+ clusters was observed at a lower coverage of 1011 clusters/mm2. In contrast, at a higher coverage of 1012 clusters/mm2, pronounced reduction of charge to Au11L52+ and Au11L5+ was observed on the FSAM. When soft landed onto 16- and 11-mercaptohexadecanoic acid surfaces on gold (16,11-COOH-SAMs), the mass-selected Au11L53+ clusters exhibited partial reduction of charge to Au11L52+ at lower coverage and additional reduction of charge to both Au11L52+ and Au11L5+ at higher coverage. The reduction of charge was found to be more pronounced on the surface of the shorter (thinner) C11 than the longer (thicker) C16-COOH-SAM. On the surface of the 1-dodecanethiol (HSAM) monolayer, the most abundant charge state was found to be Au11L52+ at lower coverage and Au11L5+ at higher coverage, respectively. A coverage-dependent electron tunneling mechanism is proposed to account for the observed reduction of charge of mass-selected multiply charged gold clusters soft landed on SAMs. The results demonstrate that one of the critical parameters that influence the chemical and physical properties of supported metal clusters, ionic charge state, may be controlled by selecting the coverage of charged species soft landed onto surfaces.

  19. Method for reduction of selected ion intensities in confined ion beams

    DOE Patents [OSTI]

    Eiden, G.C.; Barinaga, C.J.; Koppenaal, D.W.

    1998-06-16

    A method for producing an ion beam having an increased proportion of analyte ions compared to carrier gas ions is disclosed. Specifically, the method has the step of addition of a charge transfer gas to the carrier analyte combination that accepts charge from the carrier gas ions yet minimally accepts charge from the analyte ions thereby selectively neutralizing the carrier gas ions. Also disclosed is the method as employed in various analytical instruments including an inductively coupled plasma mass spectrometer. 7 figs.

  20. Apparatus for reduction of selected ion intensities in confined ion beams

    DOE Patents [OSTI]

    Eiden, Gregory C. (Richland, WA); Barinaga, Charles J. (Richland, WA); Koppenaal, David W. (Richland, WA)

    2001-01-01

    An apparatus for producing an ion beam having an increased proportion of analyte ions compared to carrier gas ions is disclosed. Specifically, the apparatus has an ion trap or a collision cell containing a reagent gas wherein the reagent gas accepts charge from the analyte ions thereby selectively neutralizing the carrier gas ions. Also disclosed is the collision cell as employed in various locations within analytical instruments including an inductively coupled plasma mass spectrometer.

  1. Method for reduction of selected ion intensities in confined ion beams

    DOE Patents [OSTI]

    Eiden, Gregory C. (Richland, WA); Barinaga, Charles J. (Richland, WA); Koppenaal, David W. (Richland, WA)

    1998-01-01

    A method for producing an ion beam having an increased proportion of analyte ions compared to carrier gas ions is disclosed. Specifically, the method has the step of addition of a charge transfer gas to the carrier analyte combination that accepts charge from the carrier gas ions yet minimally accepts charge from the analyte ions thereby selectively neutralizing the carrier gas ions. Also disclosed is the method as employed in various analytical instruments including an inductively coupled plasma mass spectrometer.

  2. Enhanced High Temperature Performance of NOx Reduction Catalyst Materials

    SciTech Connect (OSTI)

    Gao, Feng; Kim, Do Heui; Luo, Jinyong; Muntean, George G.; Peden, Charles HF; Howden, Ken; Currier, Neal; Kamasamudram, Krishna; Kumar, Ashok; Li, Junhui; Stafford, Randy; Yezerets, Aleksey; Castagnola, Mario; Chen, Hai Ying; Hess, Howard ..

    2012-12-31

    Two primary NOx after-treatment technologies have been recognized as the most promising approaches for meeting stringent NOx emission standards for diesel vehicles within the Environmental Protection Agencys (EPAs) 2007/2010 mandated limits, NOx Storage Reduction (NSR) and NH3 selective catalytic reduction (SCR); both are, in fact being commercialized for this application. However, in looking forward to 2015 and beyond with expected more stringent regulations, the continued viability of the NSR technology for controlling NOx emissions from lean-burn engines such as diesels will require at least two specific, significant and inter-related improvements. First, it is important to reduce system costs by, for example, minimizing the precious metal content while maintaining, even improving, performance and long-term stability. A second critical need for future NSR systems, as well as for NH3 SCR, will be significantly improved higher and lower temperature performance and stability. Furthermore, these critically needed improvements will contribute significantly to minimizing the impacts to fuel economy of incorporating these after-treatment technologies on lean-burn vehicles. To meet these objectives will require, at a minimum an improved scientific understanding of the following things: i) the various roles for the precious and coinage metals used in these catalysts; ii) the mechanisms for these various roles; iii) the effects of high temperatures on the active metal performance in their various roles; iv) mechanisms for higher temperature NOx storage performance for modified and/or alternative storage materials; v) the interactions between the precious metals and the storage materials in both optimum NOx storage performance and long term stability; vi) the sulfur adsorption and regeneration mechanisms for NOx reduction materials; vii) materials degradation mechanisms in CHA-based NH3 SCR catalysts. The objective of this CRADA project between PNNL and Cummins, Inc. is to develop a fundamental understanding of the above-listed issues. Model catalysts that are based on literature formulations are the focus of the work being carried out at PNNL. In addition, the performance and stability of more realistic high temperature NSR catalysts, supplied by JM, are being studied in order to provide baseline data for the model catalysts that are, again, based on formulations described in the open literature. For this short summary, we will primarily highlight representative results from our recent studies of the stability of candidate high temperature NSR materials.

  3. Occupational dose reduction at nuclear power plants: Annotated bibliography of selected readings in radiation protection and ALARA. Volume 7

    SciTech Connect (OSTI)

    Kaurin, D.G.; Khan, T.A.; Sullivan, S.G.; Baum, J.W.

    1993-07-01

    The ALARA Center at Brookhaven National Laboratory publishes a series of bibliographies of selected readings in radiation protection and ALARA in the continuing effort to collect and disseminate information on radiation dose reduction at nuclear power plants. This is volume 7 of the series. The abstracts in this bibliography were selected from proceedings of technical meetings and conferences, journals, research reports, and searches of the Energy Science and Technology database of the US Department of Energy. The subject material of these abstracts relates to radiation protection and dose reduction, and ranges from use of robotics to operational health physics, to water chemistry. Material on the design, planning, and management of nuclear power stations is included, as well as information on decommissioning and safe storage efforts. Volume 7 contains 293 abstract, an author index, and a subject index. The author index is specific for this volume. The subject index is cumulative and lists all abstract numbers from volumes 1 to 7. The numbers in boldface indicate the abstracts in this volume; the numbers not in boldface represent abstracts in previous volumes.

  4. Occupational dose reduction at nuclear power plants: Annotated bibliography of selected readings in radiation protection and ALARA. Volume 8

    SciTech Connect (OSTI)

    Sullivan, S.G.; Khan, T.A.; Xie, J.W.

    1995-05-01

    The ALARA Center at Brookhaven National Laboratory publishes a series of bibliographies of selected readings in radiation protection and ALARA in a continuing effort to collect and disseminate information on radiation dose reduction at nuclear power plants. This volume 8 of the series. The abstracts in this bibliography were selected form proceedings of technical meetings and conference journals, research reports, and searches of the Energy Science and Technology database of the US Department of Energy. The subject material of these abstracts relates to the many aspects of radiation protection and dose reduction, and ranges form use of robotics, to operational health physics, to water chemistry. Material on the design, planning, and management of nuclear power stations is included, as well as information on decommissioning and safe storage efforts. Volume 8 contains 232 abstracts, an author index, and a subject index. The author index is specific for this volume. The subject index is cumulative and lists all abstract numbers from volumes 1 to 8. The numbers in boldface indicate the abstracts in this volume; the numbers not in boldface represent abstracts in previous volumes.

  5. Occupational dose reduction at Department of Energy contractor facilities: Bibliography of selected readings in radiation protection and ALARA; Volume 5

    SciTech Connect (OSTI)

    Dionne, B.J.; Sullivan, S.G.; Baum, J.W.

    1994-01-01

    Promoting the exchange of information related to implementation of the As Low as Reasonably Achievable (ALARA) philosophy is a continuing objective for the Department of Energy (DOE). This report was prepared by the Brookhaven National Laboratory (BNL) ALARA Center for the DOE Office of Health. It contains the fifth in a series of bibliographies on dose reduction at DOE facilities. The BNL ALARA Center was originally established in 1983 under the sponsorship of the Nuclear Regulatory Commission to monitor dose-reduction research and ALARA activities at nuclear power plants. This effort was expanded in 1988 by the DOE`s Office of Environment, Safety and Health, to include DOE nuclear facilities. This bibliography contains abstracts relating to various aspects of ALARA program implementation and dose-reduction activities, with a specific focus on DOE facilities. Abstracts included in this bibliography were selected from proceedings of technical meetings, journals, research reports, searches of the DOE Energy, Science and Technology Database (in general, the citation and abstract information is presented as obtained from this database), and reprints of published articles provided by the authors. Facility types and activities covered in the scope of this report include: radioactive waste, uranium enrichment, fuel fabrication, spent fuel storage and reprocessing, facility decommissioning, hot laboratories, tritium production, research, test and production reactors, weapons fabrication and testing, fusion, uranium and plutonium processing, radiography, and accelerators. Information on improved shielding design, decontamination, containments, robotics, source prevention and control, job planning, improved operational and design techniques, as well as on other topics, has been included. In addition, DOE/EH reports not included in previous volumes of the bibliography are in this volume (abstracts 611 to 684). This volume (Volume 5 of the series) contains 217 abstracts.

  6. Hydrocarbon Effect on a Fe-zeolite Urea-SCR Catalyst: An Experimental and Modeling Study

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Herling, Darrell R.

    2010-04-14

    Synergies between various catalytic converters such as SCR and DPF are vital to the success of an integrated aftertreatment system for simultaneous NOx and particulate matter control in diesel engines. Several issues such as hydrocarbon poisoning, thermal aging and other coupled aftertreatment dynamics need to be addressed to develop an effective emission control system. This paper reports an experimental and modeling study to understand the effect of hydrocarbons on a Fe-zeolite urea-SCR bench reactor. Several bench-reactor tests to understand the inhibition of NOx oxidation, to characterize hydrocarbon storage and to investigate the impact of hydrocarbons on SCR reactions were conducted. Toluene was chosen as a representative hydrocarbon in diesel exhaust and various tests using toluene reveal its inhibition of NO oxidation at low temperatures and its oxidation to CO and CO2 at high temperatures. Surface isotherm tests were conducted to characterize the adsorption-desorption equilibrium of toluene through Langmuir isotherms. Using the rate parameters, a toluene storage model was developed and validated in simulation. With toluene in the stream, controlled SCR tests were run on the reactor and performance metrics such as NOx conversion and NH3 slip were compared to a set of previously run tests with no toluene in the stream. Tests indicate a significant effect of toluene on NOx and NH3 conversion efficiencies even at temperatures greater than 300oC. A kinetic model to address the toluene inhibition during NO oxidation reaction was developed and is reported in the paper. This work is significant especially in an integrated DPF-SCR aftertreatment scenario where the SCR catalyst on the filter substrate is exposed to un-burnt diesel hydrocarbons during active regeneration of the particulate filter.

  7. A New Approach in Urea Dosing to Improve Performance and Durability of SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems for the Use in Off-Road Applications to Fulfill Tier 4 Final | Department of Energy Approach in Urea Dosing to Improve Performance and Durability of SCR Systems for the Use in Off-Road Applications to Fulfill Tier 4 Final A New Approach in Urea Dosing to Improve Performance and Durability of SCR Systems for the Use in Off-Road Applications to Fulfill Tier 4 Final Evaluation of influence of spray quality on urea decomposition and catalyst performance leads to new approach in dosing,

  8. LNT or Urea SCR Technology: Which is the right technology for TIER 2 BIN 5

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    passenger vehicles? | Department of Energy or Urea SCR Technology: Which is the right technology for TIER 2 BIN 5 passenger vehicles? LNT or Urea SCR Technology: Which is the right technology for TIER 2 BIN 5 passenger vehicles? Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_dorenkamp.pdf More Documents & Publications The BMW Approach to Tier2 Bin5

  9. ADEC II Universal SCR Retrofit System for On-road and Off-road Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engines | Department of Energy ADEC II Universal SCR Retrofit System for On-road and Off-road Diesel Engines ADEC II Universal SCR Retrofit System for On-road and Off-road Diesel Engines Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_carlson.pdf More Documents & Publications DIesel Emission Control Technology Developments Cleaning Up Diesel Engines

  10. SCR Systems for Heavy Duty Trucks: Progress Towards Meeting Euro 4 Emission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Standards in 2005 | Department of Energy Systems for Heavy Duty Trucks: Progress Towards Meeting Euro 4 Emission Standards in 2005 SCR Systems for Heavy Duty Trucks: Progress Towards Meeting Euro 4 Emission Standards in 2005 2003 DEER Conference Presentation: PUREM PDF icon 2003_deer_frank.pdf More Documents & Publications The PUREM SCR System with AdBlue State-of-the-Art and Emergin Truck Engine Technologies Ensuring the Availability and Reliability of Urea Dosing For On-Road and

  11. Urea/Ammonia Distribution Optimization in an SCR Emission Control System

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Through the Use of CFD Analysis | Department of Energy Urea/Ammonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis Urea/Ammonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle

  12. Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and DPF | Department of Energy Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF In reference to legacy heavy-duty vehicles, emissions and fuel use are less closely related to immediate engine load than was the case without the use of aftertreatments. PDF icon p-05_covington.pdf More Documents & Publications Can We Accurately Measure In-Use Emissions from Heavy-Duty

  13. Safe and compact ammonia storage/delivery systems for SCR-DeNOX in

    Energy Savers [EERE]

    automotive units | Department of Energy Safe and compact ammonia storage/delivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storage/delivery systems for SCR-DeNOX in automotive units Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_johannessen.pdf More Documents & Publications Ammonia storage and delivery systems for NOx

  14. Stripping ethanol from ethanol-blended fuels for use in NO.sub.x SCR

    DOE Patents [OSTI]

    Kass, Michael Delos (Oak Ridge, TN); Graves, Ronald Lee (Knoxville, TN); Storey, John Morse Elliot (Oak Ridge, TN); Lewis, Sr., Samuel Arthur (Andersonville, TN); Sluder, Charles Scott (Knoxville, TN); Thomas, John Foster (Powell, TN)

    2007-08-21

    A method to use diesel fuel alchohol micro emulsions (E-diesel) to provide a source of reductant to lower NO.sub.x emissions using selective catalytic reduction. Ethanol is stripped from the micro emulsion and entered into the exhaust gasses upstream of the reducing catalyst. The method allows diesel (and other lean-burn) engines to meet new, lower emission standards without having to carry separate fuel and reductant tanks.

  15. Hydrothermally stable, low-temperature NO.sub.x reduction NH.sub.3-SCR catalyst

    DOE Patents [OSTI]

    Narula, Chaitanya K; Yang, Xiaofan

    2015-03-24

    A catalyst composition includes a heterobimetallic zeolite characterized by a chabazite structure loaded with copper ions and at least one trivalent metal ion other than Al.sup.3+. The catalyst composition decreases NO.sub.x emissions in diesel exhaust and is suitable for operation in a catalytic converter.

  16. bectno-selcat | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Southern Company Services, Pensacola, FL PROGRAM PUBLICATIONS Final Reports Innovative Clean Coal Technologies (ICCT) Demonstration of Selective Catalytic Reduction (SCR) ...

  17. Occupational dose reduction at Department of Energy contractor facilities: Bibliography of selected readings in radiation protection and ALARA

    SciTech Connect (OSTI)

    Dionne, B.J.; Sullivan, S.G.; Baum, J.W.

    1993-12-01

    This bibliography contains abstracts relating to various aspects of ALARA program implementation and dose reduction activities, with a focus on DOE facilities. Abstracts included in this bibliography were selected from proceedings of technical meetings, journals, research reports, searches of the DOE Energy, Science and Technology Database (in general, the citation and abstract information is presented as obtained from this database), and reprints of published articles provided by the authors. Facility types and activities covered in the scope of this report include: radioactive waste, uranium enrichment, fuel fabrication, spent fuel storage and reprocessing, facility decommissioning, hot laboratories, tritium production, research, test and production reactors, weapons fabrication and testing, fusion, uranium and plutonium processing, radiography, and aocelerators. Information on improved shielding design, decontamination, containments, robotics, source prevention and control, job planning, improved operational and design techniques, as well as on other topics, has been included. In addition, DOE/EH reports not included in previous volumes of the bibliography are in this volume (abstracts 611 to 684). This volume (Volume 5 of the series) contains 217 abstracts. An author index and a subject index are provided to facilitate use. Both indices contain the abstract numbers from previous volumes, as well as the current volume. Information that the reader feels might be included in the next volume of this bibliography should be submitted to the BNL ALARA Center.

  18. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite Structures throughout the Catalyst Life Cycle

    SciTech Connect (OSTI)

    Ribeiro, Fabio; Delgass, Nick; Gounder, Rajmani; Schneider, William F.; Miller, Jeff; Yezerets, Aleksey; McEwen, Jean-Sabin; Peden, Charles HF; Howden, Ken

    2014-12-09

    Oxides of nitrogen (NOx) compounds contribute to acid rain and photochemical smog and have been linked to respiratory ailments. NOx emissions regulations continue to tighten, driving the need for high performance, robust control strategies. The goal of this project is to develop a deep, molecular level understanding of the function of Cu-SSZ-13 and Cu-SAPO-34 materials that catalyze the SCR of NOx with NH3.

  19. CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace022_daw_2012_o.pdf More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR Emissions Control for Lean Gasoline Engines NH3 generation over commercial Three-Way Catalysts and Lean-NOx Traps

  20. Final Report of a CRADA Between Pacific Northwest National Laboratory and the Ford Motor Company (CRADA No. PNNL/265): Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials

    SciTech Connect (OSTI)

    Gao, Feng; Kwak, Ja Hun; Lee, Jong H.; Tran, Diana N.; Peden, Charles HF; Howden, Ken; Cheng, Yisun; Lupescu, Jason; Cavattaio, Giovanni; Lambert, Christine; McCabe, Robert W.

    2013-02-14

    Reducing NOx emissions and particulate matter (PM) are primary concerns for diesel vehicles required to meet current LEV II and future LEV III emission standards which require 90+% NOx conversion. Currently, urea SCR as the NOx reductant and a Catalyzed Diesel Particulate Filter (CDPF) are being used for emission control system components by Ford Motor Company for 2010 and beyond diesel vehicles. Because the use of this technology for vehicle applications is new, the relative lack of experience makes it especially challenging to satisfy durability requirements. Of particular concern is being able to realistically simulate actual field aging of the catalyst systems under laboratory conditions. This is necessary both as a rapid assessment tool for verifying improved performance and certifiability of new catalyst formulations, and to develop a good understanding of deactivation mechanisms that can be used to develop improved catalyst materials. In addition to NOx and PM, the hydrocarbon (HC) emission standards are expected to become much more stringent during the next few years. Meanwhile, the engine-out HC emissions are expected to increase and/or be more difficult to remove. Since HC can be removed only when the catalyst becomes warm enough for its oxidation, three-way catalyst (TWC) and diesel oxidation catalyst (DOC) formulations often contain proprietary zeolite materials to hold the HC produced during the cold start period until the catalyst reaches its operating temperature (e.g., >200C). Unfortunately, much of trapped HC tends to be released before the catalyst reaches the operating temperature. Among materials effective for trapping HC during the catalyst warm-up period, siliceous zeolites are commonly used because of their high surface area and high stability under typical operating conditions. However, there has been little research on the physical properties of these materials related to the adsorption and release of various hydrocarbon species found in the engine exhaust. For these reasons, automakers and engine manufacturers have difficulty improving their catalytic converters for meeting the stringent HC emission standards. In this collaborative program, scientists and engineers in the Institute for Integrated Catalysis at Pacific Northwest National Laboratory and at Ford Motor Company have investigated laboratory- and engine-aged SCR catalysts, containing mainly base metal zeolites. These studies are leading to a better understanding of various aging factors that impact the long-term performance of SCR catalysts and improve the correlation between laboratory and engine aging, saving experimental time and cost. We have also studied materials effective for the temporary storage of HC species during the cold-start period. In particular, we have examined the adsorption and desorption of various HC species produced during the combustion with different fuels (e.g., gasoline, E85, diesel) over potential HC adsorber materials, and measured the kinetic parameters to update Fords HC adsorption model. Since this CRADA has now been completed, in this final report we will provide brief summaries of most of the work carried out on this CRADA over the last several years.

  1. Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene-Isoquinoline Complex

    SciTech Connect (OSTI)

    Thoi, VanSara; Kornienko, Nick; Margarit, C; Yang, Peidong; Chang, Christopher

    2013-06-07

    The solar-driven reduction of carbon dioxide to value-added chemical fuels is a longstanding challenge in the fields of catalysis, energy science, and green chemistry. In order to develop effective CO2 fixation, several key considerations must be balanced, including (1) catalyst selectivity for promoting CO2 reduction over competing hydrogen generation from proton reduction, (2) visible-light harvesting that matches the solar spectrum, and (3) the use of cheap and earth-abundant catalytic components. In this report, we present the synthesis and characterization of a new family of earth-abundant nickel complexes supported by N-heterocyclic carbene amine ligands that exhibit high selectivity and activity for the electrocatalytic and photocatalytic conversion of CO2 to CO. Systematic changes in the carbene and amine donors of the ligand have been surveyed, and [Ni(Prbimiq1)]2+ (1c, where Prbimiq1 = bis(3-(imidazolyl)isoquinolinyl)propane) emerges as a catalyst for electrochemical reduction of CO2 with the lowest cathodic onset potential (Ecat = 1.2 V vs SCE). Using this earth-abundant catalyst with Ir(ppy)3 (where ppy = 2-phenylpyridine) and an electron donor, we have developed a visible-light photoredox system for the catalytic conversion of CO2 to CO that proceeds with high selectivity and activity and achieves turnover numbers and turnover frequencies reaching 98,000 and 3.9 s1, respectively. Further studies reveal that the overall efficiency of this solar-to-fuel cycle may be limited by the formation of the active Ni catalyst and/or the chemical reduction of CO2 to CO at the reduced nickel center and provide a starting point for improved photoredox systems for sustainable carbon-neutral energy conversion.

  2. Selective catalytic reduction system and process for treating NOx emissions using a palladium and rhodium or ruthenium catalyst

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly (Orlando, FL); Rossin, Joseph A. (Columbus, OH); Knapke, Michael J. (Columbus, OH)

    2011-07-12

    A process for the catalytic reduction of nitrogen oxides (NOx) in a gas stream (29) in the presence of H.sub.2 is provided. The process comprises contacting the gas stream with a catalyst system (38) comprising zirconia-silica washcoat particles (41), a pre-sulfated zirconia binder (44), and a catalyst combination (40) comprising palladium and at least one of rhodium, ruthenium, or a mixture of ruthenium and rhodium.

  3. Selective catalytic reduction system and process for control of NO.sub.x emissions in a sulfur-containing gas stream

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly

    2015-08-11

    An exhaust gas treatment process, apparatus, and system for reducing the concentration of NOx, CO and hydrocarbons in a gas stream, such as an exhaust stream (29), via selective catalytic reduction with ammonia is provided. The process, apparatus and system include a catalytic bed (32) having a reducing only catalyst portion (34) and a downstream reducing-plus-oxidizing portion (36). Each portion (34, 36) includes an amount of tungsten. The reducing-plus-oxidizing catalyst portion (36) advantageously includes a greater amount of tungsten than the reducing catalyst portion (36) to markedly limit ammonia salt formation.

  4. Selective CO{sub 2} reduction conjugated with H{sub 2}O oxidation utilizing semiconductor/metal-complex hybrid photocatalysts

    SciTech Connect (OSTI)

    Morikawa, T. Sato, S. Arai, T. Uemura, K. Yamanaka, K. I. Suzuki, T. M. Kajino, T. Motohiro, T.

    2013-12-10

    We developed a new hybrid photocatalyst for CO{sub 2} reduction, which is composed of a semiconductor and a metal complex. In the hybrid photocatalyst, ?G between the position of conduction band minimum (E{sub CBM}) of the semiconductor and the CO{sub 2} reduction potential of the complex is an essential factor for realizing fast electron transfer from the conduction band of semiconductor to metal complex leading to high photocatalytic activity. On the basis of this concept, the hybrid photocatalyst InP/Ru-complex, which functions in aqueous media, was developed. The photoreduction of CO{sub 2} to formate using water as an electron donor and a proton source was successfully achieved as a Z-scheme system by functionally conjugating the InP/Ru-complex photocatalyst for CO{sub 2} reduction with a TiO{sub 2} photocatalyst for water oxidation. The conversion efficiency from solar energy to chemical energy was ca. 0.04%, which approaches that for photosynthesis in a plant. Because this system can be applied to many other inorganic semiconductors and metal-complex catalysts, the efficiency and reaction selectivity can be enhanced by optimization of the electron transfer process including the energy-band configurations, conjugation conformations, and catalyst structures. This electrical-bias-free reaction is a huge leap forward for future practical applications of artificial photosynthesis under solar irradiation to produce organic species.

  5. HUBBLE SPACE TELESCOPE PROPER MOTION (HSTPROMO) CATALOGS OF GALACTIC GLOBULAR CLUSTERS. I. SAMPLE SELECTION, DATA REDUCTION, AND NGC7078 RESULTS

    SciTech Connect (OSTI)

    Bellini, A.; Anderson, J.; Van der Marel, R. P.; Watkins, L. L.; King, I. R.; Bianchini, P.; Chanam, J.; Chandar, R.; Cool, A. M.; Ferraro, F. R.; Massari, D.; Ford, H.

    2014-12-20

    We present the first study of high-precision internal proper motions (PMs) in a large sample of globular clusters, based on Hubble Space Telescope (HST) data obtained over the past decade with the ACS/WFC, ACS/HRC, and WFC3/UVIS instruments. We determine PMs for over 1.3 million stars in the central regions of 22 clusters, with a median number of ?60,000 stars per cluster. These PMs have the potential to significantly advance our understanding of the internal kinematics of globular clusters by extending past line-of-sight (LOS) velocity measurements to two- or three-dimensional velocities, lower stellar masses, and larger sample sizes. We describe the reduction pipeline that we developed to derive homogeneous PMs from the very heterogeneous archival data. We demonstrate the quality of the measurements through extensive Monte Carlo simulations. We also discuss the PM errors introduced by various systematic effects and the techniques that we have developed to correct or remove them to the extent possible. We provide in electronic form the catalog for NGC7078 (M 15), which consists of 77,837 stars in the central 2.'4. We validate the catalog by comparison with existing PM measurements and LOS velocities and use it to study the dependence of the velocity dispersion on radius, stellar magnitude (or mass) along the main sequence, and direction in the plane of the sky (radial or tangential). Subsequent papers in this series will explore a range of applications in globular-cluster science and will also present the PM catalogs for the other sample clusters.

  6. Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  7. Integrating low-NO{sub x} burners, overfire air, and selective non-catalytic reduction on a utility coal-fired boiler

    SciTech Connect (OSTI)

    Hunt, T.; Muzio, L.; Smith, R.

    1995-05-01

    Public Service Company of Colorado (PSCo), in cooperation with the US Department of Energy (DOE) and the Electric Power Research Institute (EPRI), is testing the Integrated Dry NO{sub x}/SO{sub 2} Emissions Control system. This system combines low-NO{sub x} burners, overfire air, selective non-catalytic reduction (SNCR), and dry sorbent injection with humidification to reduce by up to 70% both NO{sub x} and SO{sub 2} emissions from a 100 MW coal-fired utility boiler. The project is being conducted at PSCo`s Arapahoe Unit 4 located in Denver, Colorado as part of the DOE`s Clean Coal Technology Round 3 program. The urea-based SNCR system, supplied by Noell, Inc., was installed in late 1991 and was tested with the unmodified boiler in 1992. At full load, it reduced NO{sub x} emissions by about 35% with an associated ammonia slip limit of 10 ppm. Babcock & Wilcox XLS{reg_sign} burners and a dual-zone overfire air system were retrofit to the top-fired boiler in mid-1992 and demonstrated a NO{sub x} reduction of nearly 70% across the load range. Integrated testing of the combustion modifications and the SNCR system were conducted in 1993 and showed that the SNCR system could reduce NO{sub x} emissions by an additional 45% while maintaining 10 ppm of ammonia slip limit at full load. Lower than expect4ed flue-gas temperatures caused low-load operation to be less effective than at high loads. NO{sub x} reduction decreased to as low as 11% at 60 MWe at an ammonia slip limit of 10 ppm. An ammonia conversion system was installed to improve performance at low loads. Other improvements to increase NO{sub x} removal at low-loads are planned. The combined system of combustion modifications and SNCR reduced NO{sub x} emissions by over 80% from the original full-load baseline. 11 figs.

  8. Data Collection, Testing, and Analysis of Hybrid Electric Trucks...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    timing and exhaust gas recirculation rates), examine the composition of the selective catalytic reduction (SCR) feed gas (NO 2 to NO x ratio), and look at tailpipe constituents...

  9. QGESS: CO2 Impurity Design Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Health NOx Oxides of nitrogen SAS Saline aquifer sequestration SCR Selective catalytic reduction TWA Total Weighted Average National Energy Technology Laboratory Office of...

  10. Mechanistic Investigation of Ethanol SCR of NOx over Ag/Al2O3

    SciTech Connect (OSTI)

    Johnson, William L; Fisher, Galen; Toops, Todd J

    2012-01-01

    A 2 wt.% Ag/{gamma}-Al{sub 2}O{sub 3} catalyst was studied for the ethanol selective catalytic reduction of NO{sub x} from 200 to 550 C and space velocities between 30,000 h{sup -1} and 140,000 h{sup -1}. Peak NO{sub x} conversions reached 85% at 400 C, and an activation energy was determined to be 57 kJ/mol with a feed of ethanol to NO{sub x} or HC{sub 1}/NO{sub x} = 3. Up to 80% of the NO is oxidized to NO{sub 2} at 250 C, but overall NO{sub x} conversion is only 15%. Interestingly, ethanol oxidation occurs at much lower temperatures than NO{sub x} reduction; at 250 C, ethanol oxidation is 80% when flowing ethanol + NO + O{sub 2}. This increased reactivity, compared to only 15% when flowing only ethanol + O{sub 2}, combined with the observation that NO is not oxidized to NO{sub 2} in the absence of ethanol illustrates a synergistic relationship between the reactants. To further investigate this chemistry, a series of DRIFTS experiments were performed. To form nitrates/nitrites on the catalysts it was necessary to include ethanol in the feed with NO. These nitrates/nitrites were readily formed when flowing NO{sub 2} over the catalyst. It is proposed that ethanol adsorbs through an ethoxy-intermediate that results in atomic hydrogen on the surface. This hydrogen aids the release of NO{sub 2} from Ag to the gas-phase which, can be subsequently adsorbed at {gamma}-Al{sub 2}O{sub 3} sites away from Ag. The disappearance of these nitrates/nitrites at higher temperatures proceeds in parallel with the increase in NO{sub x} reduction reactivity between 300 and 350 C observed in the kinetic study. It is therefore proposed that the consumption of nitrates is involved in the rate determining step for this reaction.

  11. Plasma-assisted catalytic reduction system

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1998-01-27

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  12. On-Road and In-Laboratory Testing to Demonstrate Effects of ULSD, B20 and B99 on a Retrofit Urea-SCR Aftertreatment System

    SciTech Connect (OSTI)

    Walkowicz, K.; Na, K.; Robertson, W.; Sahay, K.; Bogdanoff, M.; Weaver, C.; Carlson, R.

    2010-03-01

    Emissions changes for a 2005 International tractor operating on low-sulfur diesel and biodiesel in Santa Monica were measured to demonstrate performance and impacts of selective catalytic reduction.

  13. Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon deer10rohart.pdf More Documents & Publications Lean NOx Reduction with Dual Layer LNTSCR Catalysts Development of Optimal Catalyst Designs and Operating...

  14. Update on Progress of APBF-DEC EGR/DPF/SCR Demonstration Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Progress of APBF-DEC EGRDPFSCR Demonstration Program at SwRI Update on Progress of APBF-DEC EGRDPFSCR Demonstration Program at SwRI 2004 Diesel Engine Emissions Reduction...

  15. Final Update on APBF-DEC EGR/DPF/SCR Demonstration Project at...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final Update on APBF-DEC EGRDPFSCR Demonstration Project at SwRI Final Update on APBF-DEC EGRDPFSCR Demonstration Project at SwRI 2005 Diesel Engine Emissions Reduction (DEER)...

  16. Demand Reduction

    Broader source: Energy.gov [DOE]

    Grantees may use funds to coordinate with electricity supply companies and utilities to reduce energy demands on their power systems. These demand reduction programs are usually coordinated through...

  17. A NEW REDUCTION OF THE BLANCO COSMOLOGY SURVEY: AN OPTICALLY SELECTED GALAXY CLUSTER CATALOG AND A PUBLIC RELEASE OF OPTICAL DATA PRODUCTS

    SciTech Connect (OSTI)

    Bleem, L. E.; Stalder, B.; Brodwin, M.; Busha, M. T.; Wechsler, R. H.; Gladders, M. D.; High, F. W.; Rest, A.

    2015-01-01

    The Blanco Cosmology Survey is a four-band (griz) optical-imaging survey of ?80deg{sup 2} of the southern sky. The survey consists of two fields centered approximately at (R.A., decl.) = (23{sup h}, 55) and (5{sup h}30{sup m}, 53) with imaging sufficient for the detection of L {sub *} galaxies at redshift z ? 1. In this paper, we present our reduction of the survey data and describe a new technique for the separation of stars and galaxies. We search the calibrated source catalogs for galaxy clusters at z ? 0.75 by identifying spatial over-densities of red-sequence galaxies and report the coordinates, redshifts, and optical richnesses, ?, for 764 galaxy clusters at z ? 0.75. This sample, >85% of which are new discoveries, has a median redshift of z = 0.52 and median richness ?(0.4 L {sub *}) = 16.4. Accompanying this paper we also release full survey data products including reduced images and calibrated source catalogs. These products are available at http://data.rcc.uchicago.edu/dataset/blanco-cosmology-survey.

  18. Zeolite-based SCR catalysts and their use in diesel engine emission treatment

    DOE Patents [OSTI]

    Narula, Chaitanya K; Yang, Xiaofan

    2015-03-24

    A catalyst comprising a zeolite loaded with copper ions and at least one trivalent metal ion other than Al.sup.+3, wherein the catalyst decreases NO.sub.x emissions in diesel exhaust. The trivalent metal ions are selected from, for example, trivalent transition metal ions, trivalent main group metal ions, and/or trivalent lanthanide metal ions. In particular embodiments, the catalysts are selected from Cu--Fe-ZSM5, Cu--La-ZSM-5, Fe--Cu--La-ZSM5, Cu--Sc-ZSM-5, and Cu--In-ZSM5. The catalysts are placed on refractory support materials and incorporated into catalytic converters.

  19. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (LNT) Materials Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction...

  20. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  1. New Developments in Titania-Based Catalysts for Selective Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx New Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx Presentation...

  2. Evaluation of Control Strategies to Effectively Meet 70-90% Mercury Reduction on an Eastern Bituminous Coal Cyclone Boiler with SCR

    SciTech Connect (OSTI)

    Tom Campbell

    2008-12-31

    This is the final site report for testing conducted at Public Service of New Hampshire's (PSNH) Merrimack Unit 2 (MK2). This project was funded through the DOE/NETL Innovations for Existing Plants program. It was a Phase III project with the goal to develop mercury control technologies that can achieve 50-70% mercury capture at costs 25-50% less than baseline estimates of $50,000-$70,000/lb of mercury removed. While results from testing at Merrimack indicate that the DOE goal was partially achieved, further improvements in the process are recommended. Merrimack burned a test blend of eastern bituminous and Venezuelan coals, for a target coal sulfur content of 1.2%, in its 335-MW Unit 2. The blend ratio is approximately a 50/50 split between the two coals. Various sorbent injection tests were conducted on the flue gas stream either in front of the air preheater (APH) or in between the two in-series ESPs. Initial mercury control evaluations indicated that, without SO3 control, the sorbent concentration required to achieve 50% control would not be feasible, either economically or within constraints specific to the maximum reasonable particle loading to the ESP. Subsequently, with SO{sub 3} control via trona injection upstream of the APH, economically feasible mercury removal rates could be achieved with PAC injection, excepting balance-of-plant concerns. The results are summarized along with the impacts of the dual injection process on the air heater, ESP operation, and particulate emissions.

  3. Selected Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    impact / selected publications

  4. Degradation Mechanisms of Urea Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace027peden2012...

  5. Degradation Mechanisms of Urea Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep02peden...

  6. Degradation Mechanisms of Urea Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace027peden2011...

  7. Degradation Mechanisms of Urea Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace027peden2010o...

  8. Selective ammonia slip catalyst enabling highly efficient NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to oxidize the ammonia that slips past the SCR catalyst to nitrogen. PDF icon deer10folic.pdf More Documents & Publications SCR-DPF Integrations for Diesel ExhaustPerformance...

  9. Nitrate reduction

    DOE Patents [OSTI]

    Dziewinski, Jacek J. (Los Alamos, NM); Marczak, Stanislaw (Los Alamos, NM)

    2000-01-01

    Nitrates are reduced to nitrogen gas by contacting the nitrates with a metal to reduce the nitrates to nitrites which are then contacted with an amide to produce nitrogen and carbon dioxide or acid anions which can be released to the atmosphere. Minor amounts of metal catalysts can be useful in the reduction of the nitrates to nitrites. Metal salts which are formed can be treated electrochemically to recover the metals.

  10. Comparative analyses for selected clean coal technologies in the international marketplace

    SciTech Connect (OSTI)

    Szpunar, C.B.; Gillette, J.L.

    1990-07-01

    Clean coal technologies (CCTs) are being demonstrated in research and development programs under public and private sponsorship. Many of these technologies could be marketed internationally. To explore the scope of these international opportunities and to match particular technologies with markets appearing to have high potential, a study was undertaken that focused on seven representative countries: Italy, Japan, Morocco, Turkey, Pakistan, the Peoples' Republic of China, and Poland. The results suggest that there are international markets for CCTs and that these technologies can be cost competitive with more conventional alternatives. The identified markets include construction of new plants and refurbishment of existing ones, especially when decision makers want to decrease dependence on imported oil. This report describes potential international market niches for U.S. CCTs and discusses the status and implications of ongoing CCT demonstration activities. Twelve technologies were selected as representative of technologies under development for use in new or refurbished industrial or electric utility applications. Included are the following: Two generic precombustion technologies: two-stage froth-flotation coal beneficiation and coal-water mixtures (CWMs); Four combustion technologies: slagging combustors, integrated-gasification combined-cycle (IGCC) systems, atmospheric fluidized-bed combustors (AFBCs), and pressurized fluidized-bed combustors (PFBCs); and Six postcombustion technologies: limestone-injection multistage burner (LIMB) systems, gas-reburning sorbent-injection (GRSI) systems, dual-alkali flue-gas desulfurization (FGD), spray-dryer FGD, the NOXSO process, and selective catalytic reduction (SCR) systems. Major chapters of this report have been processed separately for inclusion on the data base.

  11. Electrolytic oxide reduction system

    DOE Patents [OSTI]

    Wiedmeyer, Stanley G; Barnes, Laurel A; Williamson, Mark A; Willit, James L; Berger, John F

    2015-04-28

    An electrolytic oxide reduction system according to a non-limiting embodiment of the present invention may include a plurality of anode assemblies, a plurality of cathode assemblies, and a lift system configured to engage the anode and cathode assemblies. The cathode assemblies may be alternately arranged with the anode assemblies such that each cathode assembly is flanked by two anode assemblies. The lift system may be configured to selectively engage the anode and cathode assemblies so as to allow the simultaneous lifting of any combination of the anode and cathode assemblies (whether adjacent or non-adjacent).

  12. New operation strategy for driving the selectivity of NOx reduction to N2, NH3 or N2O during lean/rich cycling of a lean NOx trap catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mr?ek, David; Koci, Petr; Choi, Jae -Soon; Partridge, Jr., William P.

    2015-09-08

    Periodical regeneration of NOx storage catalyst (also known as lean NOx trap) by short rich pulses of CO, H2 and hydrocarbons is necessary for the reduction of nitrogen oxides adsorbed on the catalyst surface. Ideally, the stored NOx is converted into N2, but N2O and NH3 by-products can be formed as well, particularly at low-intermediate temperatures. The N2 and N2O products are formed concurrently in two peaks. The primary peaks appear immediately after the rich-phase inception, and tail off with the breakthrough of the reductant front accompanied by NH3 product. In addition, the secondary N2 and N2O peaks then appearmoreat the rich-to-lean transition as a result of reactions between surface-deposited reductants/intermediates (CO, HC, NH3, NCO) and residual stored NOx under increasingly lean conditions.less

  13. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials Deactivation Mechanisms of Base MetalZeolite Urea Selective...

  14. Application of hybrid coal reburning/SNCR processes for NOx reduction in a coal-fired boiler

    SciTech Connect (OSTI)

    Yang, W.J.; Zhou, Z.J.; Zhou, J.H.; Hongkun, L.V.; Liu, J.Z.; Cen, K.F.

    2009-07-01

    Boilers in Beijing Thermal Power Plant of Zhongdian Guohua Co. in China are coal-fired with natural circulation and tangential fired method, and the economical continuous rate is 410 ton per hour of steam. Hybrid coal reburning/SNCR technology was applied and it successfully reduced NOx to about 170 mg/Nm{sup 3} from about 540 mg/Nm{sup 3}, meanwhile ammonia slip was lower than 10 ppm at 450-210 t/h load and the total reduction efficiency was about 70%. Normal fineness pulverized coal from the bin was chosen as the reburning fuel and the nozzles of the upper primary air were retrofitted to be used as the reburning fuel nozzles. The reducing agent of SNCR was an urea solution, and it was injected by the four layer injectors after online dilution. At 410 t/h load, NOx emission was about 300 mg/Nm{sup 3} when the ratio of reburning fuel to the total fuel was 25.9%-33.4%. Controlling the oxygen content of the gas in the reversal chamber to less than 3.4% resulted in not only low NOx emission but also high combustion efficiency. Ammonia slip distribution in the down gas pass was uneven and ammonia slip was higher in the front of the down gas pass than in the rear of the down gas pass. NSR and NOx reduction were proportional to each other and usually resulted in more ammonia slip with reduction in NOx. About 100 mg/Nm{sup 3} NOx emission could be achieved with about 40 ppm NH{sub 3} slip at 300-450 t/h, and ammonia slip from the SNCR reactions could be used as reducing agent of SCR, which was favorable for the future SCR retrofit.

  15. Author Select

    Office of Scientific and Technical Information (OSTI)

    Authors Please use the pane on the left to start the selection process.

  16. Author Select

    Office of Scientific and Technical Information (OSTI)

    Selection List Select "add" or "add all", which appear after author's names in the middle pane, to add to the search strategy that appears in this pane. Return to Search >>...

  17. Reduction-in-Force

    Broader source: Energy.gov [DOE]

    Reduction in force (RIF) is a set of regulations and procedures that are used to determine whether an employee keeps his or her present position, or whether the employee has a right to another...

  18. Paperwork Reduction Act

    Broader source: Energy.gov [DOE]

    The Paperwork Reduction Act requires that all federal websites request permission from the Office of Management and Budget (OMB) before collecting information from 10 or more members of the public....

  19. NREL Funding Reductions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Funding Reductions to Further Impact Lab's Work Force For more information contact: Robert Noun 303-275-3062 Golden, Colo., December 22, 1995 -- The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) announced today that it will further reduce its work force as a result of continuing reductions of its fiscal year 1996 federal funding for renewable energy research and development. On November 2, the laboratory announced plans to reduce its 900 person regular work force

  20. Economic evaluation of volume reduction for Defense transuranic waste

    SciTech Connect (OSTI)

    Brown, C.M.

    1981-07-01

    This study evaluates the economics of volume reduction of retrievably stored and newly generated DOE transuranic waste by comparing the costs of reduction of the waste with the savings possible in transportation and disposal of the waste. The report develops a general approach to the comparison of TRU waste volume reduction costs and cost savings, establishes an initial set of cost data, and develops conclusions to support selecting technologies and facilities for the disposal of DOE transuranic waste. Section I outlines the analysis which considers seven types of volume reduction from incineration and compaction of combustibles to compaction, size reduction, shredding, melting, and decontamination of metals. The study considers the volume reduction of contact-handled newly generated, and retrievably stored DOE transuranic waste. Section II of this report describes the analytical approach, assumptions, and flow of waste material through sites. Section III presents the waste inventories, disposal, and transportation savings with volume reduction and the volume reduction techniques and savings.

  1. Development and application of optimal design capability for coal gasification systems - Task 1 (Volume 1, 2 and 3). Topical report, July 1995

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    Selective catalytic reduction (SCR) is a process for the post-combustion removal of NO{sub x} from the flue gas of fossil-fuel-fired power plants. SCR is capable of NO{sub x} reduction efficiencies of up to 80 or 90 percent. SCR technology has been applied for treatment of flue gases from a variety of emission sources, including natural gas- and oil-fired gas turbines, process steam boilers in refineries, and coal-fired power plants. SCR applications to coal-fired power plants have occurred in Japan and Germany. Full-scale SCR systems have not been applied to coal-fired power plants in the U.S., although there have been small-scale demonstration projects. SCR has become increasingly widely applied in the U.S. to natural-gas fired gas turbine combined cycle systems. In the remainder of this section, we review the applicability of SCR, as well as the need for post-combustion NO{sub x} control, for several power generation systems.

  2. Author Select

    Office of Scientific and Technical Information (OSTI)

    Author Select Last Name First Name search Type in a name, or the first few letters of a name, in one or both of appropriate search boxes above and select "Go". An attempt will be made to match authors that most closely relate to the text you typed.

  3. Catalyst for selective NO.sub.x reduction using hydrocarbons

    DOE Patents [OSTI]

    Marshall, Christopher L. (Naperville, IL); Neylon, Michael K. (Naperville, IL)

    2007-05-22

    A two phase catalyst is disclosed with one or more transition metals such as Cu, Co, Fe, Ag and Mo supported on a molecular sieve having a pore size not greater than 8 .ANG. along with a stabilizing oxide of one or more of the oxides of Zr, Mo, V, Nb or the rare earths coating the molecular sieve. A method of preparing the two phase catalyst and using same to remediate NO.sub.x in combustion gases is also described.

  4. Novel catalyst for selective NOx reduction using hydrocarbons...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Energy Efficiency Electricity Transmission Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar...

  5. Catalyst for selective NO.sub.x reduction using hydrocarbons...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic Solar Thermal Startup America Vehicles and Fuels Wind Energy Partners (27) Visual Patent...

  6. Degradation Mechanisms of Urea Selective Catalytic Reduction Technology |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace027_peden_2012

  7. Degradation Mechanisms of Urea Selective Catalytic Reduction Technology |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace027_peden_2011

  8. Degradation Mechanisms of Urea Selective Catalytic Reduction Technology |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace027_peden_2010_o

  9. Degradation Mechanisms of Urea Selective Catalytic Reduction Technology |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep_02_peden

  10. Electrolyte treatment for aluminum reduction

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA); Juric, Drago D. (Bulleen, AU)

    2002-01-01

    A method of treating an electrolyte for use in the electrolytic reduction of alumina to aluminum employing an anode and a cathode, the alumina dissolved in the electrolyte, the treating improving wetting of the cathode with molten aluminum during electrolysis. The method comprises the steps of providing a molten electrolyte comprised of ALF.sub.3 and at least one salt selected from the group consisting of NaF, KF and LiF, and treating the electrolyte by providing therein 0.004 to 0.2 wt. % of a transition metal or transition metal compound for improved wettability of the cathode with molten aluminum during subsequent electrolysis to reduce alumina to aluminum.

  11. Selective ammonia slip catalyst enabling highly efficient NOx removal requirements of the future

    Broader source: Energy.gov [DOE]

    A low precious metal loading ammonia-slip catalyst was developed that is able to oxidize the ammonia that slips past the SCR catalyst to nitrogen.

  12. REDUCTIONS WITHOUT REGRET: SUMMARY

    SciTech Connect (OSTI)

    Swegle, J.; Tincher, D.

    2013-09-16

    This paper briefly summarizes the series in which we consider the possibilities for losing, or compromising, key capabilities of the U.S. nuclear force in the face of modernization and reductions. The first of the three papers takes an historical perspective, considering capabilities that were eliminated in past force reductions. The second paper is our attempt to define the needed capabilities looking forward in the context of the current framework for force modernization and the current picture of the evolving challenges of deterrence and assurance. The third paper then provides an example for each of our undesirable outcomes: the creation of roach motels, box canyons, and wrong turns.

  13. Selection Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selection Process Selection Process Fellowships will be awarded based on academic excellence, relevance of candidate's research to the laboratory mission in fundamental nuclear science and relevance to Global Security or Science of Campaign missions. Contacts Director Albert Migliori Deputy Franz Freibert 505 667-6879 Email Professional Staff Assistant Susan Ramsay 505 665 0858 Email The Seaborg internal advisory committee will judge applications based on academic excellence, relevance of the

  14. Paperwork Reduction Act Forms

    Broader source: Energy.gov [DOE]

    You may need to fill out one or several of these forms depending on the nature of your survey or usability project. See the Paperwork Reduction Act Web page for more information about the process. Contact the Web Usability Coordinator if you have questions about which forms to complete.

  15. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon...

  16. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review...

  17. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbon AdsorberMaterials Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon...

  18. Investigation of the Effects of Biodiesel-based Na on Emissions Control Components

    SciTech Connect (OSTI)

    Brookshear, D. William; Nguyen, Ke; Toops, Todd J; Bunting, Bruce G; Howe, Janet E

    2012-01-01

    A single-cylinder diesel engine was used to investigate the impact of biodiesel-based Na on emissions control components using specially blended 20% biodiesel fuel (B20). The emissions control components investigated were a diesel oxidation catalyst (DOC), a Cu-zeolite-based NH{sub 3}-SCR (selective catalytic reduction) catalyst, and a diesel particulate filter (DPF). Both light-duty vehicle, DOC-SCR-DPF, and heavy-duty vehicle, DOC-DPF-SCR, emissions control configurations were employed. The accelerated Na aging is achieved by introducing elevated Na levels in the fuel, to represent full useful life exposure, and periodically increasing the exhaust temperature to replicate DPF regeneration. To assess the validity of the implemented accelerated Na aging protocol, engine-aged lean NO{sub x} traps (LNTs), DOCs and DPFs are also evaluated. To fully characterize the impact on the catalytic activity the LNT, DOC and SCR catalysts were evaluated using a bench flow reactor. The evaluation of the aged DOC samples and LNT show little to no deactivation as a result of Na contamination. However, the SCR in the light-duty configuration (DOC-SCR-DPF) was severely affected by Na contamination, especially when NO was the only fed NO{sub x} source. In the heavy-duty configuration (DOC-DPF-SCR), no impact is observed in the SCR NO{sub x} reduction activity. Electron probe micro-analysis (EPMA) reveals that Na contamination on the LNT, DOC, and SCR samples is present throughout the length of the catalysts with a higher concentration on the washcoat surface. In both the long-term engine-aged DPF and the accelerated Na-aged DPFs, there is significant Na ash present in the upstream channels; however, in the engine-aged sample lube oil-based ash is the predominant constituent.

  19. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect (OSTI)

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  20. Reduction/Transformation Operators

    Energy Science and Technology Software Center (OSTI)

    2006-09-01

    RTOp (reduction/transformation operators) is a collection of C++ software that provides the basic mechanism for implementinig vector operations in a flexible and efficient manner. This is the main interface utilized by Thyra to allow for the specification of specific vector reduction and/or transformation operations. The RTOp package contains three different types of software. (a) a small number of interoperability interfaces. (b) support software including code for the parallel SPMD mode based on only Teuchos::Comm(and notmore » MPl directly(, and (c) a library of pre-implemented RTOp subclasses for everything from simple AXPYs and norms, to more specialized vector operations. RTOp allows an algorithm developer to implement their own RTOp subclasses in a way that is independent from any specific serial, parallel, out-of-core or other type of vector implementation. RTOp is a required package by Thyra and MOOCHO. (c)« less

  1. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Goodnow, W.H.; Payne, J.R.

    1982-09-14

    The invention is directed to cathode modules comprised of refractory hard metal materials, such as TiB[sub 2], for an electrolytic cell for the reduction of alumina wherein the modules may be installed and replaced during operation of the cell and wherein the structure of the cathode modules is such that the refractory hard metal materials are not subjected to externally applied forces or rigid constraints. 9 figs.

  2. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Goodnow, Warren H. (Palo Alto, CA); Payne, John R. (Pleasanton, CA)

    1982-01-01

    The invention is directed to cathode modules comprised of refractory hard metal materials, such as TiB.sub.2, for an electrolytic cell for the reduction of alumina wherein the modules may be installed and replaced during operation of the cell and wherein the structure of the cathode modules is such that the refractory hard metal materials are not subjected to externally applied forces or rigid constraints.

  3. Global Threat Reduction Initiative

    Office of Environmental Management (EM)

    The Current Status of Gap and U.S.-Origin Nuclear Fuel Removals 2011 Jeff Galan, Deputy Project Manager U.S.-Origin Nuclear Remove Program National Nuclear Security Administration Global Threat Reduction Initiative Defense Nuclear Nonproliferation U.S. DEPARTMENT OF ENERGY 2 GTRI Mission and Goals GTRI is: A part of President Obama's comprehensive strategy to prevent nuclear terrorism; and The key organization responsible for implementing the U.S. HEU minimization policy. GTRI MISSION Reduce

  4. Uranium Reduction by Clostridia

    SciTech Connect (OSTI)

    Francis, A.J.; Dodge, Cleveland J.; Gillow, Jeffrey B.

    2006-04-05

    The FRC groundwater and sediment contain significant concentrations of U and Tc and are dominated by low pH, and high nitrate and Al concentrations where dissimilatory metal reducing bacterial activity may be limited. The presence of Clostridia in Area 3 at the FRC site has been confirmed and their ability to reduce uranium under site conditions will be determined. Although the phenomenon of uranium reduction by Clostridia has been firmly established, the molecular mechanisms underlying such a reaction are not very clear. The authors are exploring the hypothesis that U(VI) reduction occurs through hydrogenases and other enzymes (Matin and Francis). Fundamental knowledge of metal reduction using Clostridia will allow us to exploit naturally occurring processes to attenuate radionuclide and metal contaminants in situ in the subsurface. The outline for this report are as follows: (1) Growth of Clostridium sp. under normal culture conditions; (2) Fate of metals and radionuclides in the presence of Clostridia; (3) Bioreduction of uranium associated with nitrate, citrate, and lepidocrocite; and (4) Utilization of Clostridium sp. for immobilization of uranium at the FRC Area 3 site.

  5. Water Use Reduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Facilities Water Use Reduction Water Use Reduction Water Use Reduction Water Use Reduction The Federal Energy Management Program (FEMP) provides agencies with guidance and...

  6. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Payne, John R. (Pleasanton, CA)

    1983-09-20

    The invention is directed to an anode-cathode structure for an electrolytic cell for the reduction of alumina wherein the structure is comprised of a carbon anode assembly which straddles a wedge-shaped refractory hard metal cathode assembly having steeply sloped cathodic surfaces, each cathodic surface being paired in essentially parallel planar relationship with an anode surface. The anode-cathode structure not only takes into account the structural weakness of refractory hard metal materials but also permits the changing of the RHM assembly during operation of the cell. Further, the anode-cathode structure enhances the removal of anode gas from the interpolar gap between the anode and cathode surfaces.

  7. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Payne, J.R.

    1983-09-20

    The invention is directed to an anode-cathode structure for an electrolytic cell for the reduction of alumina wherein the structure is comprised of a carbon anode assembly which straddles a wedge-shaped refractory hard metal cathode assembly having steeply sloped cathodic surfaces, each cathodic surface being paired in essentially parallel planar relationship with an anode surface. The anode-cathode structure not only takes into account the structural weakness of refractory hard metal materials but also permits the changing of the RHM assembly during operation of the cell. Further, the anode-cathode structure enhances the removal of anode gas from the interpolar gap between the anode and cathode surfaces. 10 figs.

  8. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials | Department of Energy Materials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_25_peden.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber

  9. Idaho Petroleum Reduction Leadership Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt041_es_baird_2011_p.pdf More Documents & Publications Idaho Petroleum Reduction Leadership Project Idaho Petroleum Reduction Leadership Project North Central Texas Council of Governments&#8217; North Central Texas Alternative Fuel and Advanced Technology Investments initiative is one of 25 Area of Interest 4 Selections

  10. Enhanced High Temperature Performance of NOx Storage/Reduction (NSR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace026_peden_2010_o.pdf More Documents & Publications Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction

  11. Development of pollution reduction strategies for Mexico City: Estimating cost and ozone reduction effectiveness

    SciTech Connect (OSTI)

    Thayer, G.R.; Hardie, R.W.; Barrera-Roldan, A.

    1993-12-31

    This reports on the collection and preparation of data (costs and air quality improvement) for the strategic evaluation portion of the Mexico City Air Quality Research Initiative (MARI). Reports written for the Mexico City government by various international organizations were used to identify proposed options along with estimates of cost and emission reductions. Information from appropriate options identified by SCAQMD for Southem California were also used in the analysis. A linear optimization method was used to select a group of options or a strategy to be evaluated by decision analysis. However, the reduction of ozone levels is not a linear function of the reduction of hydrocarbon and NO{sub x} emissions. Therefore, a more detailed analysis was required for ozone. An equation for a plane on an isopleth calculated with a trajectory model was obtained using two endpoints that bracket the expected total ozone precursor reductions plus the starting concentrations for hydrocarbons and NO{sub x}. The relationship between ozone levels and the hydrocarbon and NO{sub x} concentrations was assumed to lie on this plane. This relationship was used in the linear optimization program to select the options comprising a strategy.

  12. Greenidge multi-pollutant project achieves emissions reduction goals

    SciTech Connect (OSTI)

    2008-07-01

    Performance testing at the Greenridge Multi-Pollutant Project has met or exceeded project goals, indicating that deep emission reduciton sin small, difficult-to-retrofit power plants can be achieved. The technology fitted at the 107 MWe AES Greenridge Unit 4 includes a hybrid selective non-catalytic reduction/selective catalytic reduction system for NOx control (NOxOUT CASCADE) and a Turbosorp circulating fluidized bed dry scrubber system for SO{sub 2}, mercury, SO{sub 3} HC and Hf control. 2 figs.

  13. PAPERWORK REDUCTION ACT OF 1995

    Energy Savers [EERE]

    the Chief Information Officer PAPERWORK REDUCTION ACT OF 1995 U. S. DEPARTMENT OF ENERGY INFORMATION COLLECTION MANAGEMENT PROGRAM Chris Rouleau, PRA Officer Records Management Division Office of the Associate Chief Information Officer for IT Planning, Architecture and E-Government Office of the Chief Information Officer Office of the Chief Information Officer 2/16/2010 2 TOPICS  Paperwork Reduction Act (PRA) of 1995 - Law  Paperwork Reduction Act - Overview  Information Collection

  14. Vehicle Technologies Office: National Idling Reduction Network...

    Office of Environmental Management (EM)

    Idling Reduction Network News Archives Vehicle Technologies Office: National Idling Reduction Network News Archives The National Idling Reduction Network brings together trucking...

  15. National Idling Reduction Network News- June 2009

    Office of Energy Efficiency and Renewable Energy (EERE)

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  16. National Idling Reduction Network News- October 2010

    Broader source: Energy.gov [DOE]

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  17. National Idling Reduction Network News- December 2009

    Broader source: Energy.gov [DOE]

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  18. National Idling Reduction Network News- August 2009

    Office of Energy Efficiency and Renewable Energy (EERE)

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  19. National Idling Reduction Network News- February 2012

    Broader source: Energy.gov [DOE]

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  20. National Idling Reduction Network News- January 2012

    Broader source: Energy.gov [DOE]

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  1. National Idling Reduction Network News- August 2010

    Broader source: Energy.gov [DOE]

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  2. National Idling Reduction Network News- October 2009

    Office of Energy Efficiency and Renewable Energy (EERE)

    Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events.

  3. Speciation of Energetic Materials on a Microcantilever Using Surface Reduction

    SciTech Connect (OSTI)

    Yi, Dechang; Senesac, Larry R; Thundat, Thomas George

    2008-01-01

    Although microcantilevers have been used to detect explosives with extremely high sensitivity using variations in adsorption-induced bending and resonance frequency, obtaining selectivity remains a challenge. Reversible chemoselectivity at ambient temperatures based on receptor-based detection provides only limited selectivity due to the generality of chemical interactions. The oxygen imbalance in secondary explosives presents a means to achieve receptor-free speciation of explosives using surface reduction of adsorbed molecules. We demonstrate highly selective and real-time detection of Trinitrotoluene (TNT) using a copper oxide-coated cantilever with a surface reduction approach. Not only can this technique exclusively differentiate explosives from nonexplosives, but also it has the potential to specify individual explosives such as TNT, pentaerythritol tetranitrate (PETN), and RDX. This technique together with receptor-based detection techniques provides a multimodal approach for achieving very high selectivity.

  4. Local Energy Assurance Planning Selected Cities

    Office of Environmental Management (EM)

    Selected Cities

  5. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

  6. Alternative Fuels Data Center: Idle Reduction

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Idle Reduction to someone by E-mail Share Alternative Fuels Data Center: Idle Reduction on Facebook Tweet about Alternative Fuels Data Center: Idle Reduction on Twitter Bookmark Alternative Fuels Data Center: Idle Reduction on Google Bookmark Alternative Fuels Data Center: Idle Reduction on Delicious Rank Alternative Fuels Data Center: Idle Reduction on Digg Find More places to share Alternative Fuels Data Center: Idle Reduction on AddThis.com... More in this section... Idle Reduction Benefits

  7. Accelerated cleanup risk reduction

    SciTech Connect (OSTI)

    Knapp, R.B.; Aines, R.M.; Blake, R.G.; Copeland, A.B.; Newmark, R.L.; Tompson, A.F.B.

    1998-02-01

    There is no proven technology for remediating contaminant plume source regions in a heterogeneous subsurface. This project is an interdisciplinary effort to develop the requisite new technologies so that will be rapidly accepted by the remediation community. Our technology focus is hydrous pyrolysis/oxidation (HPO) which is a novel in situ thermal technique. We have expanded this core technology to leverage the action of steam injection and place an in situ microbial filter downstream to intercept and destroy the accelerated movement of contaminated groundwater. Most contaminant plume source regions, including the chlorinated solvent plume at LLNL, are in subsurface media characterized by a wide range in hydraulic conductivity. At LLNL, the main conduits for contaminant transport are buried stream channels composed of gravels and sands; these have a hydraulic conductivity in the range of 10{sup -1} to 10{sup -2} cm/s. Clay and silt units with a hydraulic conductivity of 10{sup -1} to 10{sup -6} cm/s bound these buried channels; these are barriers to groundwater movement and contain the highest contaminant concentrations in the source region. New remediation technologies are required because the current ones preferentially access the high conductivity units. HPO is an innovative process for the in situ destruction of contaminants in the entire subsurface. It operates by the injection of steam. We have demonstrated in laboratory experiments that many contaminants rapidly oxidize to harmless compounds at temperatures easily achieved by injecting steam, provided sufficient dissolved oxygen is present. One important challenge in a heterogeneous source region is getting heat, contaminants, and an oxidizing agent in the same place at the same time. We have used the NUFT computer program to simulate the cyclic injection of steam into a contaminated aquifer for design of a field demonstration. We used an 8 hour, steam/oxygen injection cycle followed by a 56 hour relaxation period in which the well was `capped`. Our results show the formation of an inclined gas phase during injection and a fast collapse of the steam zone within an hour of terminating steam injection. The majority of destruction occurs during the collapse phase, when contaminant laden water is drawn back towards the well. Little to no noncondensible gasses are created in this process, removing any possibility of sparging processes interfering with contaminant destruction. Our models suggest that the thermal region should be as hot and as large as possible. To have HPO accepted, we need to demonstrate the in situ destruction of contaminants. This requires the ability to inexpensively sample at depth and under high temperatures. We proved the ability to implies monitoring points at depths exceeding 150 feet in highly heterogeneous soils by use of cone penetrometry. In addition, an extractive system has been developed for sampling fluids and measuring their chemistry under the range of extreme conditions expected. We conducted a collaborative field test of HPO at a Superfund site in southern California where the contaminant is mainly creosote and pentachlorophenol. Field results confirm the destruction of contaminants by HPO, validate our field design from simulations, demonstrate that accurate field measurements of the critical fluid parameters can be obtained using existing monitoring wells (and minimal capital cost) and yield reliable cost estimates for future commercial application. We also tested the in situ microbial filter technology as a means to intercept and destroy the accelerated flow of contaminants caused by the injection of steam. A series of laboratory and field tests revealed that the selected bacterial species effectively degrades trichloroethene in LLNL Groundwater and under LLNL site conditions. In addition, it was demonstrated that the bacteria effectively attach to the LLNL subsurface media. An in-well treatability study indicated that the bacteria initially degrade greater than 99% of the contaminant, to concentrations less than regulatory limit

  8. Catalyst Characterization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon pmp_19_watkins.pdf More Documents & Publications Catalyst Characterization Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based Systems Approach Degradation Mechanisms of Urea Selective Catalytic Reduction Technology

  9. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Towards N2O -- Similarities and Differences Between H2, CO and C3H6 Reductants Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and Differences Between H2,...

  10. bectno-selcat | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selective Catalytic Reduction Technology for the Control of NOx Emissions from High-Sulfur Coal-Fired Boilers - Project Brief [PDF-247KB] Southern Company Services, Pensacola, FL PROGRAM PUBLICATIONS Final Reports Innovative Clean Coal Technologies (ICCT) Demonstration of Selective Catalytic Reduction (SCR) Technology for the Control of Nitrogen Oxide (NOx) Emissions from High-Sulfur Coal-Fired Boilers Volume 1, Final Report [PDF-29MB] (Oct 1996) Volume 2, Appendices A-N [PDF-20.2MB] (Oct 1996)

  11. Combustion in a multiburner furnace with selective flow of oxygen

    DOE Patents [OSTI]

    Bool, III, Lawrence E.; Kobayashi, Hisashi

    2004-03-02

    Improved operational characteristics such as improved fuel efficiency, reduction of NOx formation, reduction of the amount of unburned carbon in the ash, and lessened tendency to corrosion at the tube wall, in a multi-burner furnace are obtained by reducing the flow rate of combustion air to the burners and selectively individually feeding oxidant to only some of the burners.

  12. High reduction transaxle for electric vehicle

    DOE Patents [OSTI]

    Kalns, Ilmars (Plymouth, MI)

    1987-01-01

    A drivetrain (12) includes a transaxle assembly (16) for driving ground engaging wheels of a land vehicle powered by an AC motor. The transaxle includes a ratio change section having planetary gear sets (24, 26) and brake assemblies (28, 30). Sun gears (60, 62) of the gear sets are directly and continuously connected to an input drive shaft (38) driven by the motor. A first drive (78a) directly and continuously connects a planetary gear carrier (78) of gear sets (24) with a ring gear (68) of gear set (26). A second drive (80a) directly and continuously connects a planetary gear carrier (80) of gear set (26) with a sun gear (64) of a final speed reduction gear set (34) having a planetary gear carrier directly and continuously connected to a differential (22). Brakes (28, 30) are selectively engageable to respectively ground a ring gear 66 of gear set 24 and ring gear 68 of gear set 26.

  13. Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressure gradient, analogous to particle pinches. 10 This effect is predicted by straightforward calculations using the quasi- linear transport approximation. This paper follows...

  14. Combination for electrolytic reduction of alumina

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Lynnwood, WA); Juric, Drago D. (Bulleen, AU)

    2002-04-30

    An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises molten electrolyte having the following ingredients: AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound is, a fluoride; oxide, or carbonate. The metal is nickel, iron, copper, cobalt, or molybdenum. The bath is employed in a combination including a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the instant bath during electrolytic reduction of alumina to aluminum improves the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode.

  15. Microbial reduction of iron ore

    DOE Patents [OSTI]

    Hoffmann, Michael R. (Pasadena, CA); Arnold, Robert G. (Pasadena, CA); Stephanopoulos, Gregory (Pasadena, CA)

    1989-01-01

    A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry.

  16. Microbial reduction of iron ore

    DOE Patents [OSTI]

    Hoffmann, M.R.; Arnold, R.G.; Stephanopoulos, G.

    1989-11-14

    A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry. 11 figs.

  17. Paperwork Reduction Act Form | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Form Paperwork Reduction Act Form Collection Discontinuation Form PDF icon Paperwork Reduction Act Form More Documents & Publications OMB83 D Discontinuance Form OMB 83 C Paperwork Reduction Act Submission (OMB 83-I)

  18. Uranium isotopes fingerprint biotic reduction

    SciTech Connect (OSTI)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-04-20

    Knowledge of paleo-redox conditions in the Earths history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U), i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earths crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.

  19. Uranium isotopes fingerprint biotic reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-04-20

    Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U),more » i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.« less

  20. Diesel Idling Reduction | Open Energy Information

    Open Energy Info (EERE)

    Idling Reduction Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Diesel Idling Reduction AgencyCompany Organization: US EPA, NY SERDA Focus Area: Fuels & Efficiency...

  1. Characterizing Test Methods and Emissions Reduction Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Test Methods and Emissions Reduction Performance of In-Use Diesel Retrofit Technologies from the National Clean Diesel Campaign Characterizing Test Methods and Emissions Reduction ...

  2. Economic Analysis of Commercial Idling Reduction Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Economic Analysis of Commercial Idling Reduction Technologies: Which idling reduction ... A Key Enabler of Expanded U.S. Trade and Economic Growth Comparing Emissions Benefits from ...

  3. Pollution Prevention - Environmental Impact Reduction Checklists...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pollution Prevention - Environmental Impact Reduction Checklists for NEPA309 Reviewers Pollution Prevention - Environmental Impact Reduction Checklists for NEPA309 Reviewers The ...

  4. Table3_EntityReductions.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Carbon Dioxide Equivalent) Reduction Type 1991 1992 1993 1994 1995 1996 1997 1998 1999 ... CONNECTIVITY SOLUTONS MANUFACTURING Inc. Reduction Type 1991 1992 1993 1994 1995 1996 1997 ...

  5. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19,...

  6. Long term experiences with HDD SCR Catalysts

    Broader source: Energy.gov [DOE]

    Test bench results and on-road experiences of more than 1 million km offer comparisons of fresh and used catalyst activity and NOx conversion capability using appropriate methods of catalyst analysis.

  7. Pump Selection Considerations

    SciTech Connect (OSTI)

    Not Available

    2005-10-01

    BestPractices Program tip sheet discussing pumping system efficiency with pumping selection considerations.

  8. Development of Optimal Catalyst Designs and Operating Strategies for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coupled LNT/SCR | Department of Energy Coupled LNT/SCR Development of Optimal Catalyst Designs and Operating Strategies for Coupled LNT/SCR We introduce a new bench-scale engine generator testing system for different diesel fuels, fuel blends, fuel additives, and evaluate their efficiency in Nox reduction. PDF icon p-06_harold.pdf More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Lean NOx

  9. Global Threat Reduction Initiative | Department of Energy

    Energy Savers [EERE]

    An overview of the Global Threat Reduction Initiative, U.S.-Origin Nuclear Fuel Removals.

  10. Idling Reduction for Personal Vehicles

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    - Idling Reduction for Personal Vehicles Idling your vehicle-running your engine when you're not driving it-truly gets you nowhere. Idling reduces your vehicle's fuel economy, costs you money, and creates pollution. Idling for more than 10 seconds uses more fuel and produces more emissions that contribute to smog and climate change than stopping and restarting your engine does. Researchers estimate that idling from heavy-duty and light- duty vehicles combined wastes about 6 billion gallons of

  11. The reduction of packaging waste

    SciTech Connect (OSTI)

    Raney, E.A.; Hogan, J.J.; McCollom, M.L.; Meyer, R.J.

    1994-04-01

    Nationwide, packaging waste comprises approximately one-third of the waste disposed in sanitary landfills. the US Department of Energy (DOE) generated close to 90,000 metric tons of sanitary waste. With roughly one-third of that being packaging waste, approximately 30,000 metric tons are generated per year. The purpose of the Reduction of Packaging Waste project was to investigate opportunities to reduce this packaging waste through source reduction and recycling. The project was divided into three areas: procurement, onsite packaging and distribution, and recycling. Waste minimization opportunities were identified and investigated within each area, several of which were chosen for further study and small-scale testing at the Hanford Site. Test results, were compiled into five ``how-to`` recipes for implementation at other sites. The subject of the recipes are as follows: (1) Vendor Participation Program; (2) Reusable Containers System; (3) Shrink-wrap System -- Plastic and Corrugated Cardboard Waste Reduction; (4) Cardboard Recycling ; and (5) Wood Recycling.

  12. Water Use Reduction Case Studies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Facilities Water Use Reduction Water Use Reduction Case Studies Water Use Reduction Case Studies These case studies offer examples of water use reduction projects implemented...

  13. Innovative Clean Coal Technology (ICCT). Technical progress report, second & third quarters, 1993, April 1993--June 1993, July 1993--September 1993

    SciTech Connect (OSTI)

    1995-09-01

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by constructing and operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida. The project is funded by the U.S. Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing all aspects of this project.

  14. EPA Source Reduction Assistance Grant Program

    Broader source: Energy.gov [DOE]

    The U.S. Environmental Protection Agency (EPA) is accepting applications for the Source Reduction Assistance Grant Program to support pollution prevention/source reduction and/or resource conservation projects that reduce or eliminate pollution at the source.

  15. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  16. Patent: Microbial reductive dehalogenation of vinyl chloride | DOEpatents

    Office of Scientific and Technical Information (OSTI)

    Microbial reductive dehalogenation of vinyl chloride Citation Details Title: Microbial reductive dehalogenation of vinyl chloride

  17. Pollution Prevention - Environmental Impact Reduction Checklists for

    Energy Savers [EERE]

    NEPA/309 Reviewers | Department of Energy Pollution Prevention - Environmental Impact Reduction Checklists for NEPA/309 Reviewers Pollution Prevention - Environmental Impact Reduction Checklists for NEPA/309 Reviewers The environmental review process under the National Environmental Policy Act (NEPA) provides a valuable opportunity for Federal agency NEPA/309 reviewers to incorporate pollution prevention and environmental impact reduction into actions (or projects). This Environmental

  18. Greenhouse Gas Reductions: SF6

    ScienceCinema (OSTI)

    Anderson, Diana

    2013-04-19

    Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas ? one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6 emissions. Argonne saves over 16,000 tons of SF6 from being emitted into the atmosphere each year, and by recycling the gas rather than purchasing it new, we save taxpayers over $208,000 each year.

  19. PLAINS CO2 REDUCTION PARTNERSHIP

    SciTech Connect (OSTI)

    Edward N. Steadman; John A. Harju; Erin M. O'Leary; James A. Sorensen; Daniel J. Daly; Melanie D. Jensen; Thea E. Reikoff

    2005-01-01

    The Plains CO{sub 2} Reduction (PCOR) Partnership continues to make great progress. Task 2 (Technology Deployment) focused on developing information regarding deployment issues to support Task 5 (Modeling and Phase II Action Plans) by providing information to be used to assess CO{sub 2} sequestration opportunities in the PCOR Partnership region. Task 3 (Public Outreach) focused on developing an informational video about CO{sub 2} sequestration. Progress in Task 4 (Sources, Sinks, and Infrastructure) included the continued collection of data regarding CO{sub 2} sources and sinks and data on the performance and costs for CO{sub 2} separation, capture, treatment, and compression for pipeline transportation. Task 5 focused on screening and qualitatively assessing sequestration options. Task 5 activities also continue to be useful in structuring data collection and other activities in Tasks 2, 3, and 5.

  20. Continuous reduction of uranium tetrafluoride

    SciTech Connect (OSTI)

    DeMint, A.L.; Maxey, A.W.

    1993-10-21

    Operation of a pilot-scale system for continuous metallothermic reduction of uranium tetrafluoride (UF{sub 4} or green salt) has been initiated. This activity is in support of the development of a cost- effective process to produce uranium-iron (U-Fe) alloy feed for the Uranium-Atomic Vapor Laser Isotope Separation (U-AVLIS) program. To date, five runs have been made to reduce green salt (UF{sub 4}) with magnesium. During this quarter, three runs were made to perfect the feeding system, examine feed rates, and determine the need for a crust breaker/stirrer. No material was drawn off in any of the runs; both product metal and by-product salt were allowed to accumulate in the reactor.

  1. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials | Department of Energy Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace055_peden_2011_o.pdf More

  2. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials | Department of Energy 3 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace055_peden_2013_o.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials Deactivation Mechanisms of Base Metal/Zeolite

  3. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace055_peden_2012_o.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials Deactivation Mechanisms of Base Metal/Zeolite

  4. Center for Nanophase Materials Sciences (CNMS) - Selective deuteration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selective deuteration

  5. Fellows' Nominations and Selections

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nominations and Selections Fellows' Nominations and Selections The Fellow appointment is an honor bestowed by the Director in recognition of unusual achievement by research and development (R&D) scientists and engineers. Fellows' nomination and selection process Definition The Fellow appointment is an honor bestowed by the Director in recognition of unusual achievement by research and development (R&D) scientists and engineers. It can be awarded to full-time R&D scientists, R&D

  6. Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and SCR | Department of Energy Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_atkinson.pdf More Documents & Publications Reductant Utilization in a LNT + SCR System Lean NOx Trap

  7. SOURCE SELECTION INFORMATION -

    Broader source: Energy.gov (indexed) [DOE]

    SOURCE SELECTION INFORMATION - SEE FEDERAL ACQUISITION REGULATION (FAR) 2.101 AND 3.104 Department of Energy Washington, DC 20585 (enter date here, centered revised template...

  8. Frequency selective infrared sensors

    DOE Patents [OSTI]

    Davids, Paul; Peters, David W

    2013-05-28

    A frequency selective infrared (IR) photodetector having a predetermined frequency band. The exemplary frequency selective photodetector includes: a dielectric IR absorber having a first surface and a second surface substantially parallel to the first surface; an electrode electrically coupled to the first surface of the dielectric IR absorber; and a frequency selective surface plasmonic (FSSP) structure formed on the second surface of the dielectric IR absorber. The FSSP structure is designed to selectively transmit radiation in the predetermined frequency band that is incident on the FSSP structure substantially independent of the angle of incidence of the incident radiation on the FSSP structure.

  9. Frequency selective infrared sensors

    DOE Patents [OSTI]

    Davids, Paul; Peters, David W

    2014-11-25

    A frequency selective infrared (IR) photodetector having a predetermined frequency band. The exemplary frequency selective photodetector includes: a dielectric IR absorber having a first surface and a second surface substantially parallel to the first surface; an electrode electrically coupled to the first surface of the dielectric IR absorber; and a frequency selective surface plasmonic (FSSP) structure formed on the second surface of the dielectric IR absorber. The FSSP structure is designed to selectively transmit radiation in the predetermined frequency band that is incident on the FSSP structure substantially independent of the angle of incidence of the incident radiation on the FSSP structure.

  10. All Selected Projects

    Energy Savers [EERE]

    Selected Projects Oct 23, 2009 (rev. Dec. 14, 2010) 99 Projects SMART GRID INVESTMENT GRANTS Type Advanced Metering Infrastructure Customer Systems Electric Systems Distribution...

  11. NOx reduction methods and apparatuses

    DOE Patents [OSTI]

    Tonkyn, Russell G.; Barlow, Stephan E.; Balmer, M. Lou; Maupin, Gary D.

    2004-10-26

    A NO.sub.x reduction method includes treating a first gas containing NO.sub.x, producing a second gas containing NO.sub.2, reducing a portion of the NO.sub.2 in the second gas to N.sub.2, and producing a third gas containing less NO.sub.x than the first gas, substantially all of the third gas NO.sub.x being NO. The method also includes treating the third gas, producing a fourth gas containing NO.sub.2, reducing a portion of the NO.sub.2 in the fourth gas to N.sub.2, and producing a fifth gas containing less NO.sub.x than the third gas, substantially all of the fifth gas NO.sub.x being NO. Treating the first and/or third gas can include treatment with a plasma. Reducing a portion of the NO.sub.2 in the second and/or fourth gas can include reducing with a catalyst. The method can further include controlling energy consumption of the plasmas independent of each other.

  12. PLAINS CO2 REDUCTION PARTNERSHIP

    SciTech Connect (OSTI)

    Edward N. Steadman; John A. Harju; Erin M. O'Leary; James A. Sorensen; Daniel J. Daly; Melanie D. Jensen; Thea E. Reikoff

    2005-04-01

    The Plains CO{sub 2} Reduction (PCOR) Partnership continues to make great progress. Task 2 (Technology Deployment) focused on developing information regarding deployment issues to support Task 5 (Modeling and Phase II Action Plans) and provided information to be used to assess CO{sub 2} sequestration opportunities in the PCOR Partnership region. Task 2 efforts also included preparation of a draft topical report entitled ''Deployment Issues Related to Geologic CO{sub 2} Sequestration in the PCOR Partnership Region'', which is nearing completion. Task 3 (Public Outreach) focused on developing an informational video about CO{sub 2} sequestration. The video will be completed and aired on Prairie Public Television in the next quarter. Progress in Task 4 (Sources, Sinks, and Infrastructure) included the continued collection of data regarding CO{sub 2} sources and sinks and data on the performance and costs for CO{sub 2} separation, capture, treatment, and compression for pipeline transportation. The addition of the Canadian province of Alberta to the PCOR Partnership region expanded the decision support system (DSS) geographic information system database. Task 5 screened and qualitatively assessed sequestration options. Task 5 activities also continue to be useful in structuring data collection and other activities in Tasks 2, 3, and 5.

  13. 2005_deer_habeger.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    habeger.pdf 2005_deer_habeger.pdf Compare the loss of NOx reduction performance over LNT and SCR catalysts due to phosphorus exposure using a laboratory diesel fuel burner PDF icon 2005_deer_habeger.pdf More Documents & Publications Lean NOx Reduction with Dual Layer LNT/SCR Catalysts Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in

  14. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Stability-Low-Cost Supports | Department of Energy Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 PDF icon adzic_bnl_kickoff.pdf More Documents & Publications Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

  15. Waste Characterization, Reduction, and Repackaging Facility ...

    Office of Environmental Management (EM)

    36, July 2012 More Documents & Publications Waste Characterization, Reduction, and Repackaging Facility (WCRRF) Waste Characterization Glovebox Operations, EP-WCRR-WO-DOP-0233...

  16. Waste Characterization, Reduction, and Repackaging Facility ...

    Office of Environmental Management (EM)

    Operations, EP-WCRR-WO-DOP-0233 Waste Characterization, Reduction, and Repackaging Facility (WCRRF) Waste Characterization Glovebox Operations, EP-WCRR-WO-DOP-0233 The documents ...

  17. Report: Technical Uncertainty and Risk Reduction

    Office of Environmental Management (EM)

    TECHNICAL UNCERTAINTY AND RISK REDUCTION Background In FY 2007 EMAB was tasked to assess EM's ability to reduce risk and technical uncertainty. Board members explored this topic...

  18. Hydrogen Compression, Storage, and Dispensing Cost Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report Storage - Challenges and Opportunities Hydro-Pac Inc., A High Pressure Company

  19. National Idling Reduction Network News - December 2009

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    http:www.climatetrust.orgapply.html Efficiency Maine Small Business Low ... Clean Diesel Program (including Locomotive Engine Idle Reduction Grant Sub- Program) 3.5 ...

  20. POLICY GUIDANCE MEMORANDUM #13 Reemployment Priority List Selections |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 3 Reemployment Priority List Selections POLICY GUIDANCE MEMORANDUM #13 Reemployment Priority List Selections The DOE RPL is designed to provide priority consideration to employees who have lost their jobs through reduction in force. or who have fully recovered from a compensable injury after more than 1 year. Employees may only receive priority consideration for positions that they fully qualify for and are in the local commuting area from which separated. Currently. the

  1. Selectable fragmentation warhead

    SciTech Connect (OSTI)

    Bryan, Courtney S.; Paisley, Dennis L.; Montoya, Nelson I.; Stahl, David B.

    1993-01-01

    A selectable fragmentation warhead capable of producing a predetermined number of fragments from a metal plate, and accelerating the fragments toward a target. A first explosive located adjacent to the plate is detonated at selected number of points by laser-driven slapper detonators. In one embodiment, a smoother-disk and a second explosive, located adjacent to the first explosive, serve to increase acceleration of the fragments toward a target. The ability to produce a selected number of fragments allows for effective destruction of a chosen target.

  2. Selectable fragmentation warhead

    SciTech Connect (OSTI)

    Bryan, C.S.; Paisley, D.L.; Montoya, N.I.; Stahl, D.B.

    1992-12-31

    This report discusses a selectable fragmentation warhead which is capable of producing a predetermined number of fragments from a metal plate, and accelerating the fragments toward a target. A first explosive located adjacent to the plate is detonated at selected number of points by laser-driven slapper detonators. In one embodiment, a smoother-disk and a second explosive, located adjacent to the first explosive, serve to increase acceleration of the fragments toward a target. The ability to produce a selected number of fragments allows for effective destruction of a chosen target.

  3. REDUCTIONS WITHOUT REGRET: HISTORICAL PERSPECTIVES

    SciTech Connect (OSTI)

    Swegle, J.; Tincher, D.

    2013-09-09

    This is the first of three papers (in addition to an introductory summary) aimed at providing a framework for evaluating future reductions or modifications of the U.S. nuclear force, first by considering previous instances in which nuclear-force capabilities were eliminated; second by looking forward into at least the foreseeable future at the features of global and regional deterrence (recognizing that new weapon systems currently projected will have expected lifetimes stretching beyond our ability to predict the future); and third by providing examples of past or possible undesirable outcomes in the shaping of the future nuclear force, as well as some closing thoughts for the future. This paper examines the circumstances and consequences of the elimination of ? The INF-range Pershing II ballistic missile and Gryphon Ground-Launched Cruise Missile (GLCM), deployed by NATO under a dual-track strategy to counter Soviet intermediate-range missiles while pursuing negotiations to limit or eliminate all of these missiles. ? The Short-Range Attack Missile (SRAM), which was actually a family of missiles including SRAM A, SRAM B (never deployed), and SRAM II and SRAM T, these last two cancelled during an over-budget/behind-schedule development phase as part of the Presidential Nuclear Initiatives of 1991 and 1992. ? The nuclear-armed version of the Tomahawk Land-Attack Cruise Missile (TLAM/N), first limited to shore-based storage by the PNIs, and finally eliminated in deliberations surrounding the 2010 Nuclear Posture Review Report. ? The Missile-X (MX), or Peacekeeper, a heavy MIRVed ICBM, deployed in fixed silos, rather than in an originally proposed mobile mode. Peacekeeper was likely intended as a bargaining chip to facilitate elimination of Russian heavy missiles. The plan failed when START II did not enter into force, and the missiles were eliminated at the end of their intended service life. ? The Small ICBM (SICBM), or Midgetman, a road-mobile, single-warhead missile for which per-unit costs were climbing when it was eliminated under the PNIs. Although there were liabilities associated with each of these systems, there were also unique capabilities; this paper lays out the pros and cons for each. Further, we articulate the capabilities that were eliminated with these systems.

  4. SOURCE SELECTION INFORMATION -

    Broader source: Energy.gov (indexed) [DOE]

    an action described in Section 311 of P.L. 112-74 in excess of 1,000,000. This information is source selection information related to the conduct of a Federal agency...

  5. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2003-10-14

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  6. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2004-08-31

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  7. Graduate Program Selection Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selection Process Graduate Program Selection Process Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive environment that is rich in intellectual vitality and opportunities for growth. Contact Student Programs (505) 665-0987 Email The student hiring process Thank you for your interest in Los Alamos National Laboratory's Student Programs. Once an application is submitted online, it is available for all interested Laboratory hiring officials to view.

  8. Undergraduate Program Selection Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selection Process Undergraduate Program Selection Process Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive environment that is rich in intellectual vitality and opportunities for growth. Contact Student Programs (505) 665-8899 Email Student hiring process Once an application is submitted online, it is made available for all interested Laboratory hiring officials to view. Hiring officials are Laboratory employees who have the funding and work

  9. Energy efficient residential new construction: market transformation. Spectral selective glass. Final project report

    SciTech Connect (OSTI)

    Hammon, Robert

    2000-12-18

    This final report describes the following tasks associated with this project: cost and availability of spectrally selective glass (SSG); window labeling problem and field verification of glass; availability of SSG replacement glass and tempered glass; HVAC load reduction due to spectrally selective glass; and comsumer appreciation of spectrally selective glass. Also included in the report are four attachments: builder and HVAC subcontractor presentation, sample advertisements, spectrally selective glass demonstration model, and invitation to SCE Glass mini trade-show.

  10. Theoretical minimum energies to produce steel for selected conditions

    SciTech Connect (OSTI)

    Fruehan, R. J.; Fortini, O.; Paxton, H. W.; Brindle, R.

    2000-03-01

    An ITP study has determined the theoretical minimum energy requirements for producing steel from ore, scrap, and direct reduced iron. Dr. Richard Fruehan's report, Theoretical Minimum Energies to Produce Steel for Selected Conditions, provides insight into the potential energy savings (and associated reductions in carbon dioxide emissions) for ironmaking, steelmaking, and rolling processes (PDF459 KB).

  11. Utah Clean Cities Transportation Sector Petroleum Reduction Technologi...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Utah Clean Cities Transportation Sector Petroleum Reduction Technologies Program Utah Clean Cities Transportation Sector Petroleum Reduction ...

  12. Nitrogen oxides emission control options for coal-fired electric utility boilers

    SciTech Connect (OSTI)

    Ravi K. Srivastava; Robert E. Hall; Sikander Khan; Kevin Culligan; Bruce W. Lani

    2005-09-01

    Recent regulations have required reductions in emissions of nitrogen oxides (NOx) from electric utility boilers. To comply with these regulatory requirements, it is increasingly important to implement state-of-the-art NOx control technologies on coal-fired utility boilers. This paper reviews NOx control options for these boilers. It discusses the established commercial primary and secondary control technologies and examines what is being done to use them more effectively. Furthermore, the paper discusses recent developments in NOx controls. The popular primary control technologies in use in the United States are low-NOx burners and overfire air. Data reflect that average NOx reductions for specific primary controls have ranged from 35% to 63% from 1995 emissions levels. The secondary NOx control technologies applied on U.S. coal-fired utility boilers include reburning, selective noncatalytic reduction (SNCR), and selective catalytic reduction (SCR). Thirty-six U.S. coal-fired utility boilers have installed SNCR, and reported NOx reductions achieved at these applications ranged from 15% to 66%. Recently, SCR has been installed at 150 U.S. coal-fired utility boilers. Data on the performance of 20 SCR systems operating in the United States with low-NOx emissions reflect that in 2003, these units achieved NOx emission rates between 0.04 and 0.07 lb/106 Btu. 106 refs., 6 figs., 6 tabs.

  13. Updating about reductions of air and blood lead concentrations in Turin, Italy, following reductions in the lead content of gasoline

    SciTech Connect (OSTI)

    Bono, R.; Pignata, C.; Gilli, G.

    1995-07-01

    Considering its well known toxicity and the chronic human exposure to lead, international lawmakers enforced some directives or laws calling for the reduction of lead content in gasoline. All of these legislative acts aimed to reduce health risks for the general population. The aim of this study was to consider the effectiveness of these laws on air lead levels and consequently on blood lead levels in a randomly selected urban Italian population. In particular, these markers were analyzed over the course of several years, corresponding to the periods just before and after enforcements of the reductions of lead in petrol. Data presented point out some considerations: (1) enforcement of legislative measures concerning the reduction of lead in petrol has reduced atmospheric levels of lead. This result demonstrates a major environmental success in primary prevention efforts. (2) This success is clear especially considering that the actual Pb-B levels can be extended to the urbanized populations. Pb-B levels were consistently higher for drinkers, for older adults and for males. The mean of Pb-B level for the present urbanized population is higher than the U.S. overall population (6.4 vs 3 {mu}g/dl). This difference can be also explained considering the different historical period of enforcement of the restriction laws. 10 refs., 3 figs., 3 tabs.

  14. AMMONIA-FREE NOx CONTROL SYSTEM

    SciTech Connect (OSTI)

    Song Wu; Zhen Fan; Andrew H. Seltzer; Richard G. Herman

    2006-06-01

    This report describes a novel NOx control system that has the potential to drastically reduce cost, and enhance performance, operation and safety of power plant NOx control. The new system optimizes the burner and the furnace to achieve very low NOx levels and to provide an adequate amount of CO, and uses the CO for reducing NO both in-furnace and over a downstream AFSCR (ammonia-free selective catalytic reduction) reactor. The AF-SCR combines the advantages of the highly successful SCR technology for power plants and the TWC (three-way catalytic converter) widely used on automobiles. Like the SCR, it works in oxidizing environment of combustion flue gas and uses only base metal catalysts. Like the TWC, the AF-SCR removes NO and excess CO simultaneously without using any external reagent, such as ammonia. This new process has been studied in a development program jointed funded by the US Department of Energy and Foster Wheeler. The report outlines the experimental catalyst work performed on a bench-scale reactor, including test procedure, operating conditions, and results of various catalyst formulations. Several candidate catalysts, prepared with readily available transition metal oxides and common substrate materials, have shown over 80-90% removal for both NO and CO in oxidizing gas mixtures and at elevated temperatures. A detailed combustion study of a 400 MWe coal-fired boiler, applying computational fluid dynamics techniques to model boiler and burner design, has been carried out to investigate ways to optimize the combustion process for the lowest NOx formation and optimum CO/NO ratios. Results of this boiler and burner optimization work are reported. The paper further discusses catalyst scale-up considerations and the conceptual design of a 400 MWe size AF-SCR reactor, as well as economics analysis indicating large cost savings of the ammonia-free NOx control process over the current SCR technology.

  15. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  16. PDSF Selected Announcements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selected Announcements PDSF Selected Announcements Exciting new PDSF developments February 25, 2014 I'm pleased to announce that PDSF successfully deployed new login nodes last week. Some of you may already have noticed that you are now landing on nodes named pdsf[6-8] when you ssh to pdsf.nersc.gov. Our new login nodes use the faster Mendel IB network and more modern hardware. We've gone from four nodes to three but, because each node has a higher core count, the processing power is staying the

  17. Suspension Hydrogen Reduction of Iron Oxide Concentrates

    SciTech Connect (OSTI)

    H.Y. Sohn

    2008-03-31

    The objective of the project is to develop a new ironmaking technology based on hydrogen and fine iron oxide concentrates in a suspension reduction process. The ultimate objective of the new technology is to replace the blast furnace and to drastically reduce CO2 emissions in the steel industry. The goals of this phase of development are; the performance of detailed material and energy balances, thermochemical and equilibrium calculations for sulfur and phosphorus impurities, the determination of the complete kinetics of hydrogen reduction and bench-scale testing of the suspension reduction process using a large laboratory flash reactor.

  18. Nox reduction system utilizing pulsed hydrocarbon injection

    DOE Patents [OSTI]

    Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

    2001-01-01

    Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

  19. Impacts of Biodiesel on Emission Control Devices | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel on Emission Control Devices Impacts of Biodiesel on Emission Control Devices Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_toops2.pdf More Documents & Publications Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies Non-Petroleum-Based Fuels: Effects on

  20. index | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced NOx Emissions Control DOE/NETL's NOx Emissions Control R&D Program - Bringing Advanced Technology to the Marketplace - April 2008 [PDF-346KB] Commercially available technologies for reducing nitrogen oxide (NOx) emissions from coal-fired boilers are enabling industry compliance with today's regulatory requirements. Low-NOx burners and selective catalytic reduction (SCR) technology have enabled hundreds of power plants to reach mandated emission levels. For a number of plants,

  1. Source Selection | Department of Energy

    Energy Savers [EERE]

    Source Selection Source Selection Source Selection/Source Selection Boards Source Evaluation Board (SEB) Monthly Status Reporting Requirement (pdf) Source Evaluation Board (SEB) Secretariat and Knowledge Manager - Acquisition Guide Chapter 1.4 (pdf) Acquisition Planning - Acquisition Guide Chapter 7.1 (pdf) Source Selection Practices - Acquisition Guide Chapter 15.1 (pdf) Headquarters Business Clearance Process - Acquisition Guide Chapter 71.1 Templates Source Selection Board Lessons Learned

  2. Energy Efficiency Interest Rate Reduction Program

    Broader source: Energy.gov [DOE]

    For new and existing home purchases that are rated 6 Star or 5 Star Plus, applicants are eligible for an interest rate reduction for the first $200,000 of the loan amount, with a blended interest...

  3. December 2015 National Idling Reduction Network News

    Broader source: Energy.gov [DOE]

    This is the December 2015 edition of the National Idling Reduction Network News, an e-newsletter that reports solicitations for funding, regulatory changes, awards and recognition, reports and other resources of interest, upcoming meetings and events, and manufacturers’ announcements.

  4. Extreme Balance of System Hardware Cost Reduction

    Broader source: Energy.gov [DOE]

    On September 1, 2011, DOE announced $42.4 million in funding over three years for the Extreme Balance of System Hardware Cost Reduction (BOS-X) funding opportunity. Part of the SunShot Systems...

  5. August 2015 National Idling Reduction Network News

    Broader source: Energy.gov [DOE]

    This is the August 2015 edition of the National Idling Reduction Network News, an e-newsletter that reports solicitations for funding, regulatory changes, awards and recognition, reports and other resources of interest, upcoming meetings and events, and manufacturers’ announcements.

  6. April 2015 National Idling Reduction Network News

    Broader source: Energy.gov [DOE]

    This is the April 2015 edition of the National Idling Reduction Network News, an e-newsletter that reports solicitations for funding, regulatory changes, awards and recognition, reports and other resources of interest, upcoming meetings and events, and manufacturers’ announcements.

  7. Select Solar | Open Energy Information

    Open Energy Info (EERE)

    Solar Jump to: navigation, search Logo: Select Solar Name: Select Solar Address: Unit 5 Blakehill Business Park Chelworth Road Cricklade SN6 6JD Place: Cricklade, United Kingdom...

  8. Reduction of metal oxides through mechanochemical processing

    DOE Patents [OSTI]

    Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Senkov, Oleg N. (Moscow, ID)

    2000-01-01

    The low temperature reduction of a metal oxide using mechanochemical processing techniques. The reduction reactions are induced mechanically by milling the reactants. In one embodiment of the invention, titanium oxide TiO.sub.2 is milled with CaH.sub.2 to produce TiH.sub.2. Low temperature heat treating, in the range of 400.degree. C. to 700.degree. C., can be used to remove the hydrogen in the titanium hydride.

  9. Engineering MulticomponentNanocatalystsfor Oxygen Reduction (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Engineering MulticomponentNanocatalystsfor Oxygen Reduction Citation Details In-Document Search Title: Engineering MulticomponentNanocatalystsfor Oxygen Reduction Authors: Guo, Shaojun [1] + Show Author Affiliations Los Alamos National Laboratory [Los Alamos National Laboratory Publication Date: 2014-03-27 OSTI Identifier: 1126640 Report Number(s): LA-UR-13-28233 DOE Contract Number: AC52-06NA25396 Resource Type: Conference Resource Relation: Conference: 247th ACS National

  10. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19, 2012, Fuel Cell Technologies Program webinar, "BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs)." PDF icon BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs) Webinar Slides More Documents & Publications Contiguous Platinum

  11. NNSA approves LANL workforce reduction plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NNSA approves LANL workforce reduction plan NNSA approves LANL workforce reduction plan Eligible employees may begin applying for voluntary separation on March 5. March 1, 2012 Aerial view of Los Alamos National Laboratory Aerial view of Los Alamos National Laboratory. Contact Fred deSousa Communications Office (505) 665-3430 Email Program opens March 5, ends April 5 LOS ALAMOS, New Mexico, March 1, 2012-A plan to reduce the Laboratory workforce by between 400 and 800 employees this spring

  12. NREL: Sustainable NREL - Greenhouse Gas Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Reduction A leader in federal greenhouse gas (GHG) management, NREL has conducted GHG inventories, developed reduction goals, and reported emissions since 2000. NREL was the first federal facility to become a partner in the Environmental Protection Agency's Climate Leaders program, and has played a critical support role in the development of federal guidelines for GHG accounting and reporting through DOE's Federal Energy Management Program. Carbon Neutrality NREL is committed to

  13. Lab announces plans for workforce reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plans for workforce reduction Lab announces plans for workforce reduction The Lab has submitted a plan to reduce its workforce by between 400 and 800 employees this spring through a voluntary separation program. February 21, 2012 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los

  14. Milestone Project Demonstrates Innovative Mercury Emissions Reduction

    Office of Environmental Management (EM)

    Technology | Department of Energy Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology January 12, 2010 - 12:00pm Addthis Washington, DC - An innovative technology that could potentially help some coal-based power generation facilities comply with anticipated new mercury emissions standards was successfully demonstrated in a recently concluded milestone project at a Michigan power

  15. Energy Reduction at HQ | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HQ Energy Reduction at HQ The Department of Energy (DOE) is setting an example for the entire Federal Government with aggressive but achievable goals for energy reduction at all DOE facilities, including its headquarters facilities in the Forrestal Building in downtown Washington, DC, and Germantown, MD. Tips for Saving Energy Employees at the Department's Headquarters facilities are advised to be aware of several actions that can add up to significant energy and monetary savings and help the

  16. Diesel Soot Filter Characterization and Modeling for Advanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals...

  17. CLEERS Coordination & Joint Development of Benchmark Kinetics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Catalyst Process Kinetic Data CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR Functionality of Commercial NOx Storage-Reduction Catalysts...

  18. Development of Optimal Catalyst Designs and Operating Strategies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Development of Optimal Catalyst Designs and Operating Strategies for ...

  19. Development of Optimal Catalyst Designs and Operating Strategies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Development of Optimal Catalyst Designs and Operating Strategies ...

  20. National Idling Reduction Network News - April 2010 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    April 2010 National Idling Reduction Network News - April 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon apr10_network_news.pdf More Documents & Publications National Idling Reduction Network News - July 2010 National Idling Reduction Network News - May 2010 National Idling Reduction Network News - October

  1. National Idling Reduction Network News - June 2009 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    June 2009 National Idling Reduction Network News - June 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon june09_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2009 National Idling Reduction Network News - Early Spring 2009 National Idling Reduction Network News - October

  2. National Idling Reduction Network News - June 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    June 2011 National Idling Reduction Network News - June 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon june11_network_news.pdf More Documents & Publications National Idling Reduction Network News - November 2011 National Idling Reduction Network News - October 2011 National Idling Reduction Network News - September 2012

  3. National Idling Reduction Network News - November 2010 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy November 2010 National Idling Reduction Network News - November 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon nov10_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2011 National Idling Reduction Network News - January 2009 National Idling Reduction

  4. National Idling Reduction Network News - October 2009 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy October 2009 National Idling Reduction Network News - October 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon oct09_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2009 National Idling Reduction Network News - November 2009 National Idling Reduction Network News - August

  5. National Idling Reduction Network News - April 2010 | Department of Energy

    Energy Savers [EERE]

    0 National Idling Reduction Network News - April 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon apr10_network_news.pdf More Documents & Publications National Idling Reduction Network News - May 2010 National Idling Reduction Network News - July 2010 National Idling Reduction Network News - Early Spring 2009

  6. National Idling Reduction Network News - April 2011 | Department of Energy

    Energy Savers [EERE]

    1 National Idling Reduction Network News - April 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon apr11_network_news.pdf More Documents & Publications National Idling Reduction Network News - August 2012 National Idling Reduction Network News - January 2013 National Idling Reduction Network News - April 2012

  7. National Idling Reduction Network News - April 2012 | Department of Energy

    Energy Savers [EERE]

    2 National Idling Reduction Network News - April 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon apr12_network_news.pdf More Documents & Publications National Idling Reduction Network News - February 2012 National Idling Reduction Network News - March 2012 National Idling Reduction Network News - October 2011

  8. National Idling Reduction Network News - April 2013 | Department of Energy

    Energy Savers [EERE]

    3 National Idling Reduction Network News - April 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon apr13_network_news.pdf More Documents & Publications National Idling Reduction Network News - October 2012 National Idling Reduction Network News - March 2014 National Idling Reduction Network News Compendium

  9. National Idling Reduction Network News - April 2014 | Department of Energy

    Energy Savers [EERE]

    4 National Idling Reduction Network News - April 2014 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon apr14_network_news.pdf More Documents & Publications National Idling Reduction Network News Compendium National Idling Reduction Network News - January 2014 National Idling Reduction Network News - December 2013

  10. National Idling Reduction Network News - August 2011 | Department of Energy

    Energy Savers [EERE]

    1 National Idling Reduction Network News - August 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon aug11_network_news.pdf More Documents & Publications National Idling Reduction Network News - March 2011 National Idling Reduction Network News - January 2011 National Idling Reduction Network News - May 2011

  11. National Idling Reduction Network News - August 2012 | Department of Energy

    Energy Savers [EERE]

    2 National Idling Reduction Network News - August 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon aug12_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2013 National Idling Reduction Network News - March 2012 National Idling Reduction Network News - June 2012

  12. National Idling Reduction Network News - August 2013 | Department of Energy

    Energy Savers [EERE]

    3 National Idling Reduction Network News - August 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon aug13_network_news.pdf More Documents & Publications National Idling Reduction Network News - October 2013 National Idling Reduction Network News - January 2013 National Idling Reduction Network News - August 2011

  13. National Idling Reduction Network News - December 2010 | Department of

    Energy Savers [EERE]

    Energy 0 National Idling Reduction Network News - December 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon dec10_network_news.pdf More Documents & Publications National Idling Reduction Network News - August 2011 National Idling Reduction Network News - May 2010 National Idling Reduction Network News - January 2013

  14. National Idling Reduction Network News - December 2011 | Department of

    Energy Savers [EERE]

    Energy 1 National Idling Reduction Network News - December 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon dec11_network_news.pdf More Documents & Publications National Idling Reduction Network News - October 2009 National Idling Reduction Network News - January 2013 National Idling Reduction Network News - June 2011

  15. National Idling Reduction Network News - December 2012 | Department of

    Energy Savers [EERE]

    Energy 2 National Idling Reduction Network News - December 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon dec12_network_news.pdf More Documents & Publications National Idling Reduction Network News - June 2011 National Idling Reduction Network News - April 2011 National Idling Reduction Network News - July 2010

  16. National Idling Reduction Network News - December 2013 | Department of

    Energy Savers [EERE]

    Energy 3 National Idling Reduction Network News - December 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon dec13_network_news.pdf More Documents & Publications National Idling Reduction Network News - June 2012 National Idling Reduction Network News Compendium National Idling Reduction Network News - March 2014

  17. National Idling Reduction Network News - Early Spring 2009 | Department of

    Energy Savers [EERE]

    Energy Early Spring 2009 National Idling Reduction Network News - Early Spring 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon early_spring09_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2009 National Idling Reduction Network News - August 2009 National Idling Reduction Network News

  18. National Idling Reduction Network News - February 2010 | Department of

    Energy Savers [EERE]

    Energy 0 National Idling Reduction Network News - February 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon feb10_network_news.pdf More Documents & Publications National Idling Reduction Network News - March 2012 National Idling Reduction Network News - May 2010 National Idling Reduction Network News - July 2010

  19. National Idling Reduction Network News - February 2011 | Department of

    Energy Savers [EERE]

    Energy 1 National Idling Reduction Network News - February 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon feb11_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2011 National Idling Reduction Network News - November 2010 National Idling Reduction Network News - December 2011

  20. National Idling Reduction Network News - February 2013 | Department of

    Energy Savers [EERE]

    Energy 3 National Idling Reduction Network News - February 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon feb13_network_news.pdf More Documents & Publications National Idling Reduction Network News - October 2013 National Idling Reduction Network News - April 2011 National Idling Reduction Network News Compendium

  1. National Idling Reduction Network News - February 2014 | Department of

    Energy Savers [EERE]

    Energy 4 National Idling Reduction Network News - February 2014 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon feb14_network_news.pdf More Documents & Publications National Idling Reduction Network News Compendium National Idling Reduction Network News - April 2014 National Idling Reduction Network News - July 2013

  2. National Idling Reduction Network News - January 2009 | Department of

    Energy Savers [EERE]

    Energy 09 National Idling Reduction Network News - January 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon jan09_network_news.pdf More Documents & Publications National Idling Reduction Network News - Early Spring 2009 National Idling Reduction Network News - October 2009 National Idling Reduction Network News - September 2009

  3. National Idling Reduction Network News - January 2010 | Department of

    Energy Savers [EERE]

    Energy 0 National Idling Reduction Network News - January 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon jan10_network_news.pdf More Documents & Publications National Idling Reduction Network News - February 2012 National Idling Reduction Network News - September 2010 National Idling Reduction Network News - March

  4. National Idling Reduction Network News - January 2011 | Department of

    Energy Savers [EERE]

    Energy 1 National Idling Reduction Network News - January 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon jan11_network_news.pdf More Documents & Publications National Idling Reduction Network News - February 2011 National Idling Reduction Network News - June 2011 National Idling Reduction Network News - August

  5. National Idling Reduction Network News - January 2013 | Department of

    Energy Savers [EERE]

    Energy 3 National Idling Reduction Network News - January 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon jan13_network_news.pdf More Documents & Publications National Idling Reduction Network News - February 2013 National Idling Reduction Network News - March 2013 National Idling Reduction Network News - August

  6. National Idling Reduction Network News - January 2014 | Department of

    Energy Savers [EERE]

    Energy 4 National Idling Reduction Network News - January 2014 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon jan14_network_news.pdf More Documents & Publications National Idling Reduction Network News Compendium National Idling Reduction Network News - June 2012 National Idling Reduction Network News - January 2009

  7. National Idling Reduction Network News - July 2009 | Department of Energy

    Energy Savers [EERE]

    09 National Idling Reduction Network News - July 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon july09_network_news.pdf More Documents & Publications National Idling Reduction Network News - May 2012 National Idling Reduction Network News - June 2011 National Idling Reduction Network News - November

  8. National Idling Reduction Network News - July 2010 | Department of Energy

    Energy Savers [EERE]

    0 National Idling Reduction Network News - July 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon july10_network_news.pdf More Documents & Publications National Idling Reduction Network News - Early Spring 2009 National Idling Reduction Network News - June 2010 National Idling Reduction Network News - June

  9. National Idling Reduction Network News - July 2011 | Department of Energy

    Energy Savers [EERE]

    1 National Idling Reduction Network News - July 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon july11_network_news.pdf More Documents & Publications National Idling Reduction Network News - June 2011 National Idling Reduction Network News - September 2009 National Idling Reduction Network News - April

  10. National Idling Reduction Network News - July 2012 | Department of Energy

    Energy Savers [EERE]

    2 National Idling Reduction Network News - July 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon july12_network_news.pdf More Documents & Publications National Idling Reduction Network News - May 2012 National Idling Reduction Network News - March 2011 National Idling Reduction Network News - October 2012

  11. National Idling Reduction Network News - July 2013 | Department of Energy

    Energy Savers [EERE]

    3 National Idling Reduction Network News - July 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon july13_network_news.pdf More Documents & Publications National Idling Reduction Network News - September 2012 National Idling Reduction Network News - June 2013 National Idling Reduction Network News - September 2013

  12. National Idling Reduction Network News - June 2010 | Department of Energy

    Energy Savers [EERE]

    10 National Idling Reduction Network News - June 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon june10_network_news.pdf More Documents & Publications National Idling Reduction Network News - July 2010 National Idling Reduction Network News - June 2011 National Idling Reduction Network News - Early Spring

  13. National Idling Reduction Network News - June 2011 | Department of Energy

    Energy Savers [EERE]

    1 National Idling Reduction Network News - June 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon june11_network_news.pdf More Documents & Publications National Idling Reduction Network News - November 2011 National Idling Reduction Network News - October 2011 National Idling Reduction Network News - December

  14. National Idling Reduction Network News - June 2012 | Department of Energy

    Energy Savers [EERE]

    2 National Idling Reduction Network News - June 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon june12_network_news.pdf More Documents & Publications National Idling Reduction Network News - December 2013 National Idling Reduction Network News Compendium National Idling Reduction Network News - November

  15. National Idling Reduction Network News - June 2013 | Department of Energy

    Energy Savers [EERE]

    3 National Idling Reduction Network News - June 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon june13_network_news.pdf More Documents & Publications National Idling Reduction Network News - July 2013 National Idling Reduction Network News - February 2014 National Idling Reduction Network News Compendium

  16. National Idling Reduction Network News - March 2010 | Department of Energy

    Energy Savers [EERE]

    0 National Idling Reduction Network News - March 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon mar10_network_news.pdf More Documents & Publications National Idling Reduction Network News - July 2010 National Idling Reduction Network News - Early Spring 2009 National Idling Reduction Network News - May 2010

  17. National Idling Reduction Network News - March 2011 | Department of Energy

    Energy Savers [EERE]

    1 National Idling Reduction Network News - March 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon mar11_network_news.pdf More Documents & Publications National Idling Reduction Network News - August 2011 National Idling Reduction Network News - June 2011 National Idling Reduction Network News - January 2011

  18. National Idling Reduction Network News - March 2012 | Department of Energy

    Energy Savers [EERE]

    2 National Idling Reduction Network News - March 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon mar12_network_news.pdf More Documents & Publications National Idling Reduction Network News Compendium National Idling Reduction Network News - May 2012 National Idling Reduction Network News - January 2013

  19. National Idling Reduction Network News - March 2013 | Department of Energy

    Energy Savers [EERE]

    3 National Idling Reduction Network News - March 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon mar13_network_news.pdf More Documents & Publications National Idling Reduction Network News - August 2011 National Idling Reduction Network News - March 2012 National Idling Reduction Network News - June 2011

  20. National Idling Reduction Network News - March 2014 | Department of Energy

    Energy Savers [EERE]

    4 National Idling Reduction Network News - March 2014 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon mar14_network_news.pdf More Documents & Publications National Idling Reduction Network News - December 2013 National Idling Reduction Network News Compendium National Idling Reduction Network News - June 2012

  1. National Idling Reduction Network News - May 2010 | Department of Energy

    Energy Savers [EERE]

    0 National Idling Reduction Network News - May 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon may10_network_news.pdf More Documents & Publications National Idling Reduction Network News - August 2011 National Idling Reduction Network News - December 2010 National Idling Reduction Network News - January 2013

  2. National Idling Reduction Network News - May 2011 | Department of Energy

    Energy Savers [EERE]

    1 National Idling Reduction Network News - May 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon may11_network_news.pdf More Documents & Publications National Idling Reduction Network News - October 2011 National Idling Reduction Network News - March 2012 National Idling Reduction Network News - February 2011

  3. National Idling Reduction Network News - May 2012 | Department of Energy

    Energy Savers [EERE]

    2 National Idling Reduction Network News - May 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon may12_network_news.pdf More Documents & Publications National Idling Reduction Network News - March 2014 National Idling Reduction Network News - January 2012 National Idling Reduction Network News Compendium

  4. National Idling Reduction Network News - May 2013 | Department of Energy

    Energy Savers [EERE]

    3 National Idling Reduction Network News - May 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon may13_network_news.pdf More Documents & Publications National Idling Reduction Network News - November 2012 National Idling Reduction Network News - November 2011 National Idling Reduction Network News - April 2013

  5. National Idling Reduction Network News - November 2009 | Department of

    Energy Savers [EERE]

    Energy 09 National Idling Reduction Network News - November 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon nov09_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2009 National Idling Reduction Network News - October 2009 National Idling Reduction Network News - Early Spring 2009

  6. National Idling Reduction Network News - November 2010 | Department of

    Energy Savers [EERE]

    Energy 0 National Idling Reduction Network News - November 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon nov10_network_news.pdf More Documents & Publications National Idling Reduction Network News - January 2011 National Idling Reduction Network News - January 2009 National Idling Reduction Network News Compendium

  7. National Idling Reduction Network News - November 2011 | Department of

    Energy Savers [EERE]

    Energy 1 National Idling Reduction Network News - November 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon nov11_network_news.pdf More Documents & Publications National Idling Reduction Network News - August 2011 National Idling Reduction Network News - December 2010 National Idling Reduction Network News - August 2010

  8. National Idling Reduction Network News - November 2012 | Department of

    Energy Savers [EERE]

    Energy 2 National Idling Reduction Network News - November 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon nov12_network_news.pdf More Documents & Publications National Idling Reduction Network News - June 2011 National Idling Reduction Network News - May 2012 National Idling Reduction Network News - Early Spring 2009

  9. National Idling Reduction Network News - November 2013 | Department of

    Energy Savers [EERE]

    Energy 3 National Idling Reduction Network News - November 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon nov13_network_news.pdf More Documents & Publications National Idling Reduction Network News Compendium National Idling Reduction Network News - January 2014 National Idling Reduction Network News - March 2014

  10. National Idling Reduction Network News - October 2011 | Department of

    Energy Savers [EERE]

    Energy 1 National Idling Reduction Network News - October 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon oct11_network_news.pdf More Documents & Publications National Idling Reduction Network News - May 2011 National Idling Reduction Network News - November 2011 National Idling Reduction Network News - August 2011

  11. National Idling Reduction Network News - October 2012 | Department of

    Energy Savers [EERE]

    Energy 2 National Idling Reduction Network News - October 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon oct12_network_news.pdf More Documents & Publications National Idling Reduction Network News - Early Spring 2009 National Idling Reduction Network News - June 2011 National Idling Reduction Network News - June 2009

  12. National Idling Reduction Network News - October 2013 | Department of

    Energy Savers [EERE]

    Energy 3 National Idling Reduction Network News - October 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon oct13_network_news.pdf More Documents & Publications National Idling Reduction Network News - February 2013 National Idling Reduction Network News - March 2013 National Idling Reduction Network News - May 2010

  13. National Idling Reduction Network News - September 2009 | Department of

    Energy Savers [EERE]

    Energy 09 National Idling Reduction Network News - September 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon sep09_network_news.pdf More Documents & Publications National Idling Reduction Network News - October 2009 National Idling Reduction Network News - November 2012 National Idling Reduction Network News - August 2009

  14. National Idling Reduction Network News - September 2010 | Department of

    Energy Savers [EERE]

    Energy 0 National Idling Reduction Network News - September 2010 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon sep10_network_news.pdf More Documents & Publications National Idling Reduction Network News - August 2010 National Idling Reduction Network News - May 2010 National Idling Reduction Network News - August 2011

  15. National Idling Reduction Network News - September 2011 | Department of

    Energy Savers [EERE]

    Energy 1 National Idling Reduction Network News - September 2011 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon sep11_network_news.pdf More Documents & Publications National Idling Reduction Network News - June 2011 National Idling Reduction Network News - July 2011 National Idling Reduction Network News - July 2010

  16. National Idling Reduction Network News - September 2012 | Department of

    Energy Savers [EERE]

    Energy 2 National Idling Reduction Network News - September 2012 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon sep12_network_news.pdf More Documents & Publications National Idling Reduction Network News - July 2013 National Idling Reduction Network News - February 2012 National Idling Reduction Network News - April

  17. National Idling Reduction Network News - September 2013 | Department of

    Energy Savers [EERE]

    Energy 3 National Idling Reduction Network News - September 2013 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon sep13_network_news.pdf More Documents & Publications National Idling Reduction Network News - July 2013 National Idling Reduction Network News - June 2013 National Idling Reduction Network News - March

  18. National Idling Reduction Network News Compendium | Department of Energy

    Energy Savers [EERE]

    Compendium National Idling Reduction Network News Compendium Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon idling_newsletter_portfolio.pdf More Documents & Publications National Idling Reduction Network News - January 2014 National Idling Reduction Network News - June 2012 National Idling Reduction Network News - December 2013

  19. Method and apparatus to selectively reduce NO.sub.x in an exhaust gas feedstream

    DOE Patents [OSTI]

    Schmieg, Steven J. (Troy, MI); Blint, Richard J. (Shelby Township, MI); Den, Ling (Sterling Heights, MI); Viola, Michael B. (Macomb Township, MI); Lee, Jong-Hwan (Rochester Hills, MI)

    2011-08-30

    A method and apparatus are described to selectively reduce NO.sub.x emissions of an internal combustion engine. An exhaust aftertreatment system includes an injection device operative to dispense a hydrocarbon reductant upstream of a silver-alumina catalytic reactor device. A control system determines a NO.sub.x concentration and hydrocarbon/NOx ratio based upon selected parameters of the exhaust gas feedstream and dispenses hydrocarbon reductant during lean engine operation. Included is a method to control elements of the feedstream during lean operation. The hydrocarbon reductant may include engine fuel.

  20. SOURCE SELECTION INFORMATION -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SOURCE SELECTION INFORMATION - SEE FEDERAL ACQUISITION REGULATION (FAR) 2.101 AND 3.104 Department of Energy Washington, DC 20585 (enter date here, centered revised template January 24, 2013) The Honorable Harold Rogers The Honorable Barbara A. Mikulski Chairman, Committee on Appropriations Chairwoman, Committee on Appropriations U.S. House of Representatives U.S. Senate Washington, DC 20515 Washington, DC 20510 The Honorable Rodney P. Frelinghuysen The Honorable Dianne Feinstein Chairman,

  1. Energy Department Selects Partners...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selects Partners to Bridge Old and New Corn Ethanol Technology Efforts For more information contact: e:mail: Public Affairs Golden, Colo., Feb. 24, 1999 — The U.S. Department of Energy (DOE) today announced grant recipients in its "Bridge to the Corn Ethanol Industry" initiative which will help connect the established corn ethanol industry and the newer technologies that produce ethanol from agricultural and forest wastes and other types of biomass. Six partnerships totaling $1

  2. Microsoft Word - Site Selection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selection One of the very first tasks of General Leslie Groves and the Manhattan Project in early 1943 was to locate and acquire sites in the United States where uranium and plutonium could be produced, as well as a site where the atomic bomb actually would be constructed. Production of uranium and plutonium required vast amounts of power. Thus, Oak Ridge, Tennessee, and Hanford, Washington, were chosen because of proximity to major rivers. Oak Ridge could draw on the power of the hydroelectric

  3. SOURCE SELECTION INFORMATION -

    Energy Savers [EERE]

    SOURCE SELECTION INFORMATION - SEE FEDERAL ACQUISITION REGULATION (FAR) 2.101 AND 3.104 Department of Energy Washington, DC 20585 (enter date here, centered revised template April 26, 2013) The Honorable Harold Rogers The Honorable Barbara A. Mikulski Chairman, Committee on Appropriations Chairwoman, Committee on Appropriations U.S. House of Representatives U.S. Senate Washington, DC 20515 Washington, DC 20510 The Honorable Rodney P. Frelinghuysen The Honorable Dianne Feinstein Chairman,

  4. Technology Pathway Selection Effort

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BIOMASS PROGRAM Technology Pathway Selection Effort Alicia Lindauer 27 November 2012 2 | Biomass Program eere.energy.gov * Setting R&D priorities * Benchmarking * Informing multi-sectoral analytical activities * Track Program R&D progress against goals * Identify technology process routes and prioritize funding * Program direction decisions: * Are we spending our money on the right technology pathways? * Within a pathway: Are we focusing our funding on the highest priority activities?

  5. Selective ion source

    DOE Patents [OSTI]

    Leung, K.N.

    1996-05-14

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P{sup +} from PH{sub 3}. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P{sup +}, As{sup +}, and B{sup +} without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices. 6 figs.

  6. Selective ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P.sup.+ from PH.sub.3. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P.sup.+, AS.sup.+, and B.sup.+ without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices.

  7. Paperwork Reduction Act Submission (OMB 83-I) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Submission (OMB 83-I) Paperwork Reduction Act Submission (OMB 83-I) Paperwork Reduction Act Submission (OMB 83-I) PDF icon Paperwork Reduction Act Submission (OMB 83-I) More Documents & Publications 83-I Paperwork Reduction Act Submission form Notice of OMB Action Approving DOE Submission to Extend Information Collection Request Title: OE Recovery Act Financial Assistance Grants Information Collection Requests/Paper Reduction Act

  8. Effects of dissimilatory sulfate reduction on iron (hydr)oxide reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and microbial community development | Argonne National Laboratory Effects of dissimilatory sulfate reduction on iron (hydr)oxide reduction and microbial community development May 14, 2014 Tweet EmailPrint Aquatic and terrestrial environments are dynamic systems where coupled microbiological, geochemical, and hydrological processes define the complex interactions that drive the biogeochemical cycling of the major and minor elements. For example, microbial iron and sulfate reduction profoundly

  9. Drag reduction in coal log pipelines

    SciTech Connect (OSTI)

    Marrero, T.R.; Liu, H.

    1996-12-31

    It is well-known that solutions of dissolved long-chain macromolecules produce lower friction or drag losses than with the solvent alone. In coal log pipeline (CLP), water is the conveying medium. Synthetic polymers such as poly(ethylene oxide) have been dissolved in water and tested for their extent of drag reduction as a function of concentration and other variables. Lab-scale experimental results for CLP indicate substantial drag reduction at low concentration levels of polymer. But, the macromolecules exhibit degradation under mechanical shear stresses. The large molecules break into smaller units. This degradation effect causes a loss of drag reduction. However, high levels of drag reduction can be maintained as follows: (1) by injecting polymer into the CLP at several locations along the pipeline, (2) by injecting polymer of different particle sizes, (3) by using more robust types of polymers, or (4) by using polymer-fiber mixtures. This report presents the value of drag-reducing agents in terms of pumping power net cost savings. In addition, this report outlines the environmental impact of drag reduction polymers, and end-of-pipeline water treatment processes. For an operating CLP, hundreds of miles in length, the use of poly(ethylene oxide) as a drag reducing agent provides significant pumping power cost savings at a minimal materials cost.

  10. Energy Savings from Industrial Water Reductions

    SciTech Connect (OSTI)

    Rao, Prakash; McKane, Aimee; de Fontaine, Andre

    2015-08-03

    Although it is widely recognized that reducing freshwater consumption is of critical importance, generating interest in industrial water reduction programs can be hindered for a variety of reasons. These include the low cost of water, greater focus on water use in other sectors such as the agriculture and residential sectors, high levels of unbilled and/or unregulated self-supplied water use in industry, and lack of water metering and tracking capabilities at industrial facilities. However, there are many additional components to the resource savings associated with reducing site water use beyond the water savings alone, such as reductions in energy consumption, greenhouse gas emissions, treatment chemicals, and impact on the local watershed. Understanding and quantifying these additional resource savings can expand the community of businesses, NGOs, government agencies, and researchers with a vested interest in water reduction. This paper will develop a methodology for evaluating the embedded energy consumption associated with water use at an industrial facility. The methodology developed will use available data and references to evaluate the energy consumption associated with water supply and wastewater treatment outside of a facility’s fence line for various water sources. It will also include a framework for evaluating the energy consumption associated with water use within a facility’s fence line. The methodology will develop a more complete picture of the total resource savings associated with water reduction efforts and allow industrial water reduction programs to assess the energy and CO2 savings associated with their efforts.

  11. Porosity reduction in Monterey Formation, California

    SciTech Connect (OSTI)

    Compton, J.S.

    1987-05-01

    Porosity and grain density were determined for different lithologies from throughout a 1.2-km thick section of the Monterey and Sisquoc formations in the Santa Maria basin area, California. Porosity reduction by physical and chemical compaction in the predominantly siliceous sediment is controlled largely by the bulk sediment composition and silica phase transformations. Physical compaction of sediment grains from increasing overburden pressure is responsible for most of the gradual porosity reduction with increasing burial depth in opal-A siliceous ooze and diatomite. The porous, incompressible diatom frustule maintains a high porosity relative to clayey and calcareous sediment. Therefore, a positive correlation exists between porosity and biogenic silica (diatom) content of the sediment. During the opal-A to opal-CT silica phase transformation, solution of the porous diatom frustule and precipitation of cryptocrystalline opal-CT results in a porosity reduction that roughly correlates with the biogenic silica content of the sediment. Local porosity reduction occurs in pore-filling dolomite and chert nodules. Dry bulk density as well as porosity reduction tend to increase with sediment depth. Dolomite and organic matter have the most significant influence on the bulk density because of their respective high and low density. The maximum burial depth of the uplifted and eroded section is estimated by overlapping the porosity-depth relation of average deep-sea siliceous ooze.

  12. Reduction in maximum time uncertainty of paired time signals

    DOE Patents [OSTI]

    Theodosiou, G.E.; Dawson, J.W.

    1981-02-11

    Reduction in the maximum time uncertainty (t/sub max/ - t/sub min/) of a series of paired time signals t/sub 1/ and t/sub 2/ varying between two input terminals and representative of a series of single events where t/sub 1/ less than or equal to t/sub 2/ and t/sub 1/ + t/sub 2/ equals a constant, is carried out with a circuit utilizing a combination of OR and AND gates as signal selecting means and one or more time delays to increase the minimum value (t/sub min/) of the first signal t/sub 1/ closer to t/sub max/ and thereby reduce the difference. The circuit may utilize a plurality of stages to reduce the uncertainty by factors of 20 to 800.

  13. Reduction in maximum time uncertainty of paired time signals

    DOE Patents [OSTI]

    Theodosiou, G.E.; Dawson, J.W.

    1983-10-04

    Reduction in the maximum time uncertainty (t[sub max]--t[sub min]) of a series of paired time signals t[sub 1] and t[sub 2] varying between two input terminals and representative of a series of single events where t[sub 1][<=]t[sub 2] and t[sub 1]+t[sub 2] equals a constant, is carried out with a circuit utilizing a combination of OR and AND gates as signal selecting means and one or more time delays to increase the minimum value (t[sub min]) of the first signal t[sub 1] closer to t[sub max] and thereby reduce the difference. The circuit may utilize a plurality of stages to reduce the uncertainty by factors of 20--800. 6 figs.

  14. Reduction in maximum time uncertainty of paired time signals

    DOE Patents [OSTI]

    Theodosiou, George E. (West Chicago, IL); Dawson, John W. (Clarendon Hills, IL)

    1983-01-01

    Reduction in the maximum time uncertainty (t.sub.max -t.sub.min) of a series of paired time signals t.sub.1 and t.sub.2 varying between two input terminals and representative of a series of single events where t.sub.1 .ltoreq.t.sub.2 and t.sub.1 +t.sub.2 equals a constant, is carried out with a circuit utilizing a combination of OR and AND gates as signal selecting means and one or more time delays to increase the minimum value (t.sub.min) of the first signal t.sub.1 closer to t.sub.max and thereby reduce the difference. The circuit may utilize a plurality of stages to reduce the uncertainty by factors of 20-800.

  15. Power Tower Technology Roadmap and cost reduction plan.

    SciTech Connect (OSTI)

    Mancini, Thomas R.; Gary, Jesse A.; Kolb, Gregory J.; Ho, Clifford Kuofei

    2011-04-01

    Concentrating solar power (CSP) technologies continue to mature and are being deployed worldwide. Power towers will likely play an essential role in the future development of CSP due to their potential to provide dispatchable solar electricity at a low cost. This Power Tower Technology Roadmap has been developed by the U.S. Department of Energy (DOE) to describe the current technology, the improvement opportunities that exist for the technology, and the specific activities needed to reach the DOE programmatic target of providing competitively-priced electricity in the intermediate and baseload power markets by 2020. As a first step in developing this roadmap, a Power Tower Roadmap Workshop that included the tower industry, national laboratories, and DOE was held in March 2010. A number of technology improvement opportunities (TIOs) were identified at this workshop and separated into four categories associated with power tower subsystems: solar collector field, solar receiver, thermal energy storage, and power block/balance of plant. In this roadmap, the TIOs associated with power tower technologies are identified along with their respective impacts on the cost of delivered electricity. In addition, development timelines and estimated budgets to achieve cost reduction goals are presented. The roadmap does not present a single path for achieving these goals, but rather provides a process for evaluating a set of options from which DOE and industry can select to accelerate power tower R&D, cost reductions, and commercial deployment.

  16. Bath for electrolytic reduction of alumina and method therefor

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Lynnwood, WA); Juric, Drago D. (Bulleen, AU)

    2002-11-26

    An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises a molten electrolyte having the following ingredients: (a) AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and (b) about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound may be, for example, a fluoride, oxide, or carbonate. The metal can be nickel, iron, copper, cobalt, or molybdenum. The bath can be employed in a combination that includes a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the bath of the present invention during electrolytic reduction of alumina to aluminum can improve the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode. Removing sulfur from the bath can also minimize cathode deposits. Aluminum formed on the cathode can be removed directly from the cathode.

  17. Bath for electrolytic reduction of alumina and method therefor

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Lynnwood, WA); Juric, Drago D. (Bulleen, AU)

    2001-07-10

    An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises a molten electrolyte having the following ingredients: (a) AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and (b) about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound may be, for example, a fluoride, oxide, or carbonate. The metal can be nickel, iron, copper, cobalt, or molybdenum. The bath can be employed in a combination that includes a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the bath of the present invention during electrolytic reduction of alumina to aluminum can improve the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode.

  18. Improved InGaN LED System Efficacy and Cost via Droop Reduction |

    Energy Savers [EERE]

    Department of Energy Improved InGaN LED System Efficacy and Cost via Droop Reduction Improved InGaN LED System Efficacy and Cost via Droop Reduction Lead Performer: Lumileds, LLC - San Jose, CA DOE Total Funding: $1,495,990 Cost Share: $374,000 Project Term: 9/1/2015 - 8/31/2017 Funding Opportunity: DOE Announces Selections for SSL Core Technology Research (Round 10), Product Development (Round 10), and U.S. Manufacturing (Round 6) Funding Opportunities Project Objective The overall

  19. Simplifying steam trap selection

    SciTech Connect (OSTI)

    Debat, R.J. )

    1994-01-01

    In the current economic world order, there is an obligation to eliminate waste and conserve economic and natural resources. One trap blowing 100-lb of steam through a 1/4-in. orifice can cost more than $12,000 a year in wasted energy. Richard J. Debat of Armstrong International, Inc. explains the operating principles of the four basic types of steam traps as the first step in simplifying the selection process so the right trap can be specified for a given application.

  20. Selecting chemical treatment programs

    SciTech Connect (OSTI)

    Miller, J.E. )

    1988-09-01

    Many process equipment performance and reliability problems can be solved economically by the proper selection and application of chemical treatment programs. It is important to choose an experienced chemical vendor and to work closely with the vendor to develop a good chemical treatment program. This requires devoting sufficient manpower to ensure that the treatment program development is thorough and timely. After the treatment program is installed, the system operation and performance should be routinely monitored to ensure that expected benefits are achieved and unexpected problems do not develop.

  1. Direct electrochemical reduction of metal-oxides

    DOE Patents [OSTI]

    Redey, Laszlo I.; Gourishankar, Karthick

    2003-01-01

    A method of controlling the direct electrolytic reduction of a metal oxide or mixtures of metal oxides to the corresponding metal or metals. A non-consumable anode and a cathode and a salt electrolyte with a first reference electrode near the non-consumable anode and a second reference electrode near the cathode are used. Oxygen gas is produced and removed from the cell. The anode potential is compared to the first reference electrode to prevent anode dissolution and gas evolution other than oxygen, and the cathode potential is compared to the second reference electrode to prevent production of reductant metal from ions in the electrolyte.

  2. Low-Cost Radon Reduction Pilot Study

    SciTech Connect (OSTI)

    Rose, William B.; Francisco, Paul W.; Merrin, Zachary

    2015-09-01

    The aim of the research was to conduct a primary scoping study on the impact of air sealing between the foundation and the living space on radon transport reduction across the foundation-living space floor assembly. Fifteen homes in the Champaign, Illinois area participated in the study. These homes were instrumented for hourly continuous radon measurements and simultaneous temperature and humidity the foundation was improved. However, this improved isolation did not lead to significant reductions in radon concentration in the living space. Other factors such as outdoor temperature were shown to have an impact on radon concentration.

  3. National Idling Reduction Network News - December 2009 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy December 2009 National Idling Reduction Network News - December 2009 Newsletter with information on idling reduction regulations, idling reduction grants, idling reduction general news, summary of state ani-idling regulations, and upcoming meetings and events. PDF icon dec09_network_news.pdf More Documents & Publications National Idling Reduction Network News - March 2011 National Idling Reduction Network News - October 2009 National Idling Reducti

  4. Alternative Fuels Data Center: Idle Reduction Benefits and Considerations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Idle Reduction Benefits and Considerations to someone by E-mail Share Alternative Fuels Data Center: Idle Reduction Benefits and Considerations on Facebook Tweet about Alternative Fuels Data Center: Idle Reduction Benefits and Considerations on Twitter Bookmark Alternative Fuels Data Center: Idle Reduction Benefits and Considerations on Google Bookmark Alternative Fuels Data Center: Idle Reduction Benefits and Considerations on Delicious Rank Alternative Fuels Data Center: Idle Reduction

  5. Alternative Fuels Data Center: Idle Reduction Research and Development

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Idle Reduction Research and Development to someone by E-mail Share Alternative Fuels Data Center: Idle Reduction Research and Development on Facebook Tweet about Alternative Fuels Data Center: Idle Reduction Research and Development on Twitter Bookmark Alternative Fuels Data Center: Idle Reduction Research and Development on Google Bookmark Alternative Fuels Data Center: Idle Reduction Research and Development on Delicious Rank Alternative Fuels Data Center: Idle Reduction Research and

  6. Alternative Fuels Data Center: School Bus Idle Reduction Strategies

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    School Bus Idle Reduction Strategies to someone by E-mail Share Alternative Fuels Data Center: School Bus Idle Reduction Strategies on Facebook Tweet about Alternative Fuels Data Center: School Bus Idle Reduction Strategies on Twitter Bookmark Alternative Fuels Data Center: School Bus Idle Reduction Strategies on Google Bookmark Alternative Fuels Data Center: School Bus Idle Reduction Strategies on Delicious Rank Alternative Fuels Data Center: School Bus Idle Reduction Strategies on Digg Find

  7. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, John P. (Boulder, CO); Way, J. Douglas (Boulder, CO)

    1997-01-01

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2. s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  8. Hydrogen-Selective Membrane

    DOE Patents [OSTI]

    Collins, John P. (Boulder, CO); Way, J. Douglas (Boulder, CO)

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2.s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  9. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2}s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  10. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1997-07-29

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2} s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  11. Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Investigation of a series of transition metal oxides and precious metal based catalysts for ammonia selective oxidation at low temperatures PDF icon deer12_thrun.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon

  12. Development of Optimal Catalyst Designs and Operating Strategies for Lean

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Reduction in Coupled LNT-SCR Systems | Department of Energy Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-05_harold.pdf More Documents & Publications Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems Development of Optimal Catalyst Designs and Operating Strategies for Coupled LNT/SCR

  13. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of Plasma-Catalyst for Diesel NOx Reduction Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction 2003 DEER Conference Presentation: Ford Motor Company PDF...

  14. International Carbon Reduction Offset Alliance ICROA | Open Energy...

    Open Energy Info (EERE)

    Carbon Reduction Offset Alliance ICROA Jump to: navigation, search Name: International Carbon Reduction & Offset Alliance (ICROA) Place: United Kingdom Sector: Carbon Product:...

  15. Emissions Reduction Experience with Johnson Matthey EGRT on Off...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Experience with Johnson Matthey EGRT on Off-Road Equipment Emissions Reduction Experience with Johnson Matthey EGRT on Off-Road Equipment Poster presentation at the 2007...

  16. Functionality of Commercial NOx Storage-Reduction Catalysts and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Functionality of Commercial NOx Storage-Reduction Catalysts and the Development of a Representative Model Functionality of Commercial NOx Storage-Reduction Catalysts and the...

  17. Enhanced High and Low Temperature Performance of NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells Program and...

  18. MOLECULAR MECHANISM OF MICROBIAL TECHNETIUM REDUCTION FINAL REPORT...

    Office of Scientific and Technical Information (OSTI)

    Title: MOLECULAR MECHANISM OF MICROBIAL TECHNETIUM REDUCTION FINAL REPORT Microbial Tc(VII) reduction is an attractive alternative strategy for bioremediation of...

  19. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High Temperature Performance of NOx StorageReduction (NSR) ...

  20. Low Temperature Combustion and Diesel Emission Reduction Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Diesel Emission Reduction Research Low Temperature Combustion and Diesel Emission Reduction Research Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. ...