Powered by Deep Web Technologies
Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Transitioning from Fuel Cells to Redox Flow Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Transitioning From Fuel Cells to Redox Transitioning From Fuel Cells to Redox Flow Cells T. Zawodzinski and Matt Mench University of Tennessee and ORNL Managed by UT-Battelle for the Department of Energy 2 Acknowledgments $$ DOE-OE EPRI GCEP NSF EPSCOR (TN SCORE) UTK Governor's Chair Fund Partner in Crime Matt Mench Managed by UT-Battelle for the Department of Energy 'Peeling the Onion' Personalized History of PEM Fuel Cells We May Recapitulate This for RFBs Catalysis Test System * Small Single Cell * Large Single Cell * Stack * System Layers of the Onion Hot Topic du Jour * Water Management, Membranes * Late '80's, early '90's * Reformate Tolerance, DMFC's * Mid '90's * High Temp Membranes * Late '90's * Durability * Early '00's Modeling * Membrane/ Water * Cathode * Impedance

2

Transitioning from Fuel Cells to Redox Flow Cells  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Tom Zawodzinski, University of Tennessee and Oak Ridge National Laboratory, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

3

Performance and cycling of the iron-ion/hydrogen redox flow cell with  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and cycling of the iron-ion/hydrogen redox flow cell with Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Title Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Publication Type Journal Article Year of Publication 2013 Authors Tucker, Michael C., Venkat Srinivasan, Philip N. Ross, and Adam Z. Weber Journal Journal of Applied Electrochemistry Volume 43 Issue 7 Pagination 637 - 644 Date Published 7/2013 ISSN 0021-891X Keywords battery, Flow battery, iron hydrogen cell, progress, redox flow cell Abstract A redox flow cell utilizing the Fe2+/Fe3+ and H-2/H+ couples is investigated as an energy storage device. A conventional polymer electrolyte fuel cell anode and membrane design is employed, with a cathode chamber containing a carbon felt flooded with aqueous acidic solution of iron salt. The maximum power densities achieved for iron sulfate, iron chloride, and iron nitrate are 148, 207, and 234 mW cm(-2), respectively. It is found that the capacity of the iron nitrate solution decreases rapidly during cycling. Stable cycling is observed for more than 100 h with iron chloride and iron sulfate solutions. Both iron sulfate and iron chloride solutions display moderate discharge polarization and poor charge polarization; therefore, voltage efficiency decreases dramatically with increasing current density. A small self-discharge current occurs when catholyte is circulating through the cathode chamber. As a result, a current density above 100 mA cm(-2) is required to achieve high Coulombic efficiency (> 0.9).

4

Cascade redox flow battery systems  

DOE Patents (OSTI)

A reduction/oxidation ("redox") flow battery system includes a series of electrochemical cells arranged in a cascade, whereby liquid electrolyte reacts in a first electrochemical cell (or group of cells) before being directed into a second cell (or group of cells) where it reacts before being directed to subsequent cells. The cascade includes 2 to n stages, each stage having one or more electrochemical cells. During a charge reaction, electrolyte entering a first stage will have a lower state-of-charge than electrolyte entering the nth stage. In some embodiments, cell components and/or characteristics may be configured based on a state-of-charge of electrolytes expected at each cascade stage. Such engineered cascades provide redox flow battery systems with higher energy efficiency over a broader range of current density than prior art arrangements.

Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.; Sha, Jay E.; Bose, Deepak

2014-07-22T23:59:59.000Z

5

A three-dimensional model for negative half cell of the vanadium redox flow battery  

Science Journals Connector (OSTI)

A stationary, isothermal, three-dimensional model for negative half cell of the vanadium redox flow battery is developed, which is based on the comprehensive conservation laws, such as charge, mass and momentum, together with a kinetic model for reaction involving vanadium species. The model is validated against the results calculated by the available two-dimensional model. With the given geometry of the negative half cell, the distributions of velocity, concentration, overpotential and transfer current density in the sections that are perpendicular and parallel to the applied current are studied. It is shown that the distribution of the electrolyte velocity in the electrode has significant impact on the distribution of concentration, overpotential and transfer current density. The lower velocity in the electrode will cause the higher overpotential, further result in the side reaction and corrosion of key materials locally. The development of the design of the vanadium redox flow battery is discussed, and the further research is proposed.

Xiangkun Ma; Huamin Zhang; Feng Xing

2011-01-01T23:59:59.000Z

6

Optimized Anion Exchange Membranes for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; anion exchange membrane; ion exchange capacity; cycling performance; power density ... All electrochemical measurements were conducted using a fully automated redox flow battery testing system (Scribner 857 Redox Flow Cell System). ... Characteristics of a new all-vanadium redox flow battery ...

Dongyang Chen; Michael A. Hickner; Ertan Agar; E. Caglan Kumbur

2013-06-25T23:59:59.000Z

7

Redox Flow Batteries, a Review  

SciTech Connect

Redox flow batteries are enjoying a renaissance due to their ability to store large amounts of electrical energy relatively cheaply and efficiently. In this review, we examine the components of redox flow batteries with a focus on understanding the underlying physical processes. The various transport and kinetic phenomena are discussed along with the most common redox couples.

U. Tennessee Knoxville; U. Texas Austin; McGill U; Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P.; Ross, Philip N.; Gostick, Jeffrey T.; Liu, Qinghua

2011-07-15T23:59:59.000Z

8

Rebalancing electrolytes in redox flow battery systems  

DOE Patents (OSTI)

Embodiments of redox flow battery rebalancing systems include a system for reacting an unbalanced flow battery electrolyte with a rebalance electrolyte in a first reaction cell. In some embodiments, the rebalance electrolyte may contain ferrous iron (Fe.sup.2+) which may be oxidized to ferric iron (Fe.sup.3+) in the first reaction cell. The reducing ability of the rebalance reactant may be restored in a second rebalance cell that is configured to reduce the ferric iron in the rebalance electrolyte back into ferrous iron through a reaction with metallic iron.

Chang, On Kok; Pham, Ai Quoc

2014-12-23T23:59:59.000Z

9

Redox Flow Batteries: An Engineering Perspective  

SciTech Connect

Redox flow batteries are well suited to provide modular and scalable energy storage systems for a wide range of energy storage applications. In this paper, we review the development of redox flow battery technology including recent advances in new redox active materials and systems. We discuss cost, performance, and reliability metrics that are critical for deployment of large flow battery systems. The technology, while relatively young, has the potential for significant improvement through reduced materials costs, improved energy and power efficiency, and significant reduction in the overall system cost.

Chalamala, Babu R.; Soundappan, Thiagarajan; Fisher, Graham R.; Anstey, Mitchell A.; Viswanathan, Vilayanur V.; Perry, Mike L.

2014-10-01T23:59:59.000Z

10

High energy density redox flow device  

DOE Patents (OSTI)

Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.

Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan Y; Duduta, Mihai; Limthongkul, Pimpa

2014-05-13T23:59:59.000Z

11

High energy density redox flow device  

DOE Patents (OSTI)

Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

Chiang, Yet-Ming; Carter, William Craig; Duduta, Mihai; Limthongkul, Pimpa

2014-05-13T23:59:59.000Z

12

Numerical modeling of an all vanadium redox flow battery.  

SciTech Connect

We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.

Clausen, Jonathan R.; Brunini, Victor E.; Moffat, Harry K.; Martinez, Mario J.

2014-01-01T23:59:59.000Z

13

Redox Flow Batteries, a Review  

E-Print Network (OSTI)

and water. For a fuel cell, hydrogen oxidizes at the anode5. 2.1.5 Hydrogen-based systems A fuel cell takes a fuel (

Weber, Adam Z.

2013-01-01T23:59:59.000Z

14

High-Energy Redox-Flow Batteries with Hybrid Metal Foam Electrodes  

Science Journals Connector (OSTI)

A nonaqueous redox-flow battery employing [Co(bpy)3]+/2+ and [Fe(bpy)3]2+/3+ redox couples is proposed for use in large-scale energy-storage applications. ... We successfully demonstrate a redox-flow battery with a practical operating voltage of over 2.1 V and an energy efficiency of 85% through a rational cell design. ... By utilizing carbon-coated Ni-FeCrAl and Cu metal foam electrodes, the electrochemical reactivity and stability of the nonaqueous redox-flow battery can be considerably enhanced. ...

Min-Sik Park; Nam-Jin Lee; Seung-Wook Lee; Ki Jae Kim; Duk-Jin Oh; Young-Jun Kim

2014-06-06T23:59:59.000Z

15

Scientists capture 'redox moments' in living cells | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Scientists capture 'redox moments' in living cells Scientists capture 'redox moments' in living cells Better understanding of hardy bacteria enhances tool for biofuel creation...

16

Shunt current loss of the vanadium redox flow battery  

Science Journals Connector (OSTI)

The shunt current loss is one of main factors to affect the performance of the vanadium redox flow battery, which will shorten the cycle life and decrease the energy transfer efficiency. In this paper, a stack-level model based on the circuit analog method is proposed to research the shunt current loss of the vanadium redox flow battery, in which the SOC (state of charge) of electrolyte is introduced. The distribution of shunt current is described in detail. The sensitive analysis of shunt current is reported. The shunt current loss in charge/discharge cycle is predicted with the given experimental data. The effect of charge/discharge pattern on the shunt current loss is studied. The result shows that the reduction of the number of single cells in series, the decrease of the resistances of manifold and channel and the increase of the power of single cell will be the further development for the VRFB stack.

Feng Xing; Huamin Zhang; Xiangkun Ma

2011-01-01T23:59:59.000Z

17

Advanced Redox Flow Batteries for Stationary Electrical Energy Storage  

SciTech Connect

This report describes the status of the advanced redox flow battery research being performed at Pacific Northwest National Laboratories for the U.S. Department of Energys Energy Storage Systems Program. The Quarter 1 of FY2012 Milestone was completed on time. The milestone entails completion of evaluation and optimization of single cell components for the two advanced redox flow battery electrolyte chemistries recently developed at the lab, the all vanadium (V) mixed acid and V-Fe mixed acid solutions. All the single cell components to be used in future kW-scale stacks have been identified and optimized in this quarter, which include solution electrolyte, membrane or separator; carbon felt electrode and bi-polar plate. Varied electrochemical, chemical and physical evaluations were carried out to assist the component screening and optimization. The mechanisms of the battery capacity fading behavior for the all vanadium redox flow and the Fe/V battery were discovered, which allowed us to optimize the related cell operation parameters and continuously operate the system for more than three months without any capacity decay.

Li, Liyu; Kim, Soowhan; Xia, Guanguang; Wang, Wei; Yang, Zhenguo

2012-03-19T23:59:59.000Z

18

Fe-V redox flow batteries  

DOE Patents (OSTI)

A redox flow battery having a supporting solution that includes Cl.sup.- anions is characterized by an anolyte having V.sup.2+ and V.sup.3+ in the supporting solution, a catholyte having Fe.sup.2+ and Fe.sup.3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO.sub.4.sup.2- and Cl.sup.- anions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-07-08T23:59:59.000Z

19

Fact Sheet: Vanadium Redox Flow Batteries (October 2012) | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vanadium Redox Flow Batteries (October 2012) Vanadium Redox Flow Batteries (October 2012) Fact Sheet: Vanadium Redox Flow Batteries (October 2012) DOE's Energy Storage Program is funding research to develop next-generation vanadium redox flow batteries (VRBs) that reduce costs by improving energy and power densities, widening the operating temperature window, and simplifying and optimizing stack/system designs. These efforts build on Pacific Northwest National Laboratory research that has developed new redox electrolytes that enable increased VRB operating temperatures and energy storage capabilities. Fact Sheet: Vanadium Redox Flow Batteries (October 2012) More Documents & Publications Energy Storage Systems 2012 Peer Review Presentations - Day 3, Session 2 Energy Storage Systems 2012 Peer Review Presentations - Poster Session 2

20

High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage Title High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage Publication Type Journal Article Year of Publication 2012 Authors Cho, Kyu Taek, Paul L. Ridgway, Adam Z. Weber, Sophia Haussener, Vincent S. Battaglia, and Venkat Srinivasan Journal Journal of the Electrochemical Society Volume 159 Issue 11 Pagination A1806 - A1815 Date Published 01/2012 ISSN 0013-4651 Keywords hydrogen/bromine, redox flow battery Abstract The electrochemical behavior of a promising hydrogen/bromine redox flow battery is investigated for grid-scale energy-storage application with some of the best redox-flow-battery performance results to date, including a peak power of 1.4 W/cm(2) and a 91% voltaic efficiency at 0.4 W/cm(2) constant-power operation. The kinetics of bromine on various materials is discussed, with both rotating-disk-electrode and cell studies demonstrating that a carbon porous electrode for the bromine reaction can conduct platinum-comparable performance as long as sufficient surface area is realized. The effect of flow-cell designs and operating temperature is examined, and ohmic and mass-transfer losses are decreased by utilizing a flow-through electrode design and increasing cell temperature. Charge/discharge and discharge-rate tests also reveal that this system has highly reversible behavior and good rate capability.

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Nitrogen-Doped Carbon Nanotube/Graphite Felts as Advanced Electrode Materials for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; nitrogen doping; carbon nanotubes; graphite felt ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ...

Shuangyin Wang; Xinsheng Zhao; Thomas Cochell; Arumugam Manthiram

2012-07-27T23:59:59.000Z

22

Redox flow batteries based on supporting solutions containing chloride  

DOE Patents (OSTI)

Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-01-14T23:59:59.000Z

23

Bismuth Nanoparticle Decorating Graphite Felt as a High-Performance Electrode for an All-Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Bismuth Nanoparticle Decorating Graphite Felt as a High-Performance Electrode for an All-Vanadium Redox Flow Battery ... Employing electrolytes containing Bi3+, bismuth nanoparticles are synchronously electrodeposited onto the surface of a graphite felt electrode during operation of an all-vanadium redox flow battery (VRFB). ... Energy storage; redox flow battery; electrode; catalyst; vanadium ...

Bin Li; Meng Gu; Zimin Nie; Yuyan Shao; Qingtao Luo; Xiaoliang Wei; Xiaolin Li; Jie Xiao; Chongmin Wang; Vincent Sprenkle; Wei Wang

2013-02-11T23:59:59.000Z

24

Influences of Permeation of Vanadium Ions through PVDF-g-PSSA Membranes on Performances of Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

The vanadium redox flow battery (VRB) proposed by Skyllas-Kazacos and co-workers1-3 in 1985 has received considerable attention due to its long cycle life, flexible design, fast response time, deep-discharge capability, and low cost in energy storage. ... Figure 1 Schematic illustration of a vanadium redox flow battery. ... Vanadium Redox Flow Battery Performance. ...

Xuanli Luo; Zhengzhong Lu; Jingyu Xi; Zenghua Wu; Wentao Zhu; Liquan Chen; Xinping Qiu

2005-10-08T23:59:59.000Z

25

SFTEL: Flow Cell | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Flow Cell EMSL's Subsurface Flow and Transport Experimental Laboratory offers several meter-scale flow cells and columns for research in saturated and unsaturated porous media....

26

Bio-mass derived mesoporous carbon as super electrode in all vanadium redox flow battery with multicouple reactions  

Science Journals Connector (OSTI)

Abstract We first report the multi-couple reaction in all vanadium redox flow batteries (VRFB) while using bio-mass (coconut shell) derived mesoporous carbon as electrode. The presence of V3+/V4+ redox couple certainly supplies the additional electrons for the electrochemical reaction and subsequently provides improved electrochemical performance of VRFB system. The efficient electro-catalytic activity of such coconut shell derived high surface area mesoporous carbon is believed for the improved cell performance. Extensive power and electrochemical studies are performed for VRFB application point of view and described in detail.

Mani Ulaganathan; Akshay Jain; Vanchiappan Aravindan; Sundaramurthy Jayaraman; Wong Chui Ling; Tuti Mariana Lim; M.P. Srinivasan; Qingyu Yan; Srinivasan Madhavi

2014-01-01T23:59:59.000Z

27

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries  

SciTech Connect

We will present a novel design lithium-organic non-aqueous redox flow battery based on a TEMPO catholyte. This RFB produced desired electrochemical performance exceeding most of the currently reported nonaqueous RFB systems.

Wei, Xiaoliang; Xu, Wu; Vijayakumar, M.; Cosimbescu, Lelia; Liu, Tianbiao L.; Sprenkle, Vincent L.; Wang, Wei

2014-12-03T23:59:59.000Z

28

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (III): Volumetric Properties of Aqueous VOSO4  

Science Journals Connector (OSTI)

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (III): Volumetric Properties of Aqueous VOSO4 ... The all-vanadium redox flow battery (VRFB) as an effective energy-storage system proposed by Skyllas-Kazacos et al. has been investigated extensively. ... Oriji, G.; Katayama, Y.; Miura, T.Investigation on V(IV)/V(V) species in a vanadium redox flow battery Electrochim. ...

Ye Qin; Jian-Guo Liu; Chuan-Wei Yan

2011-11-22T23:59:59.000Z

29

Redox and ATP control of photosynthetic cyclic electron flow in Chlamydomonas reinhardtii (I) aerobic conditions  

E-Print Network (OSTI)

Redox and ATP control of photosynthetic cyclic electron flow in Chlamydomonas reinhardtii (I, requires the production of ATP and NADPH in a ratio of 3:2. The oxygenic photosynthetic chain can function following two different modes: the linear electron flow which produces reducing power and ATP

30

Study of the Ce3+/Ce4+ Redox Couple in Mixed-Acid Media (CH3SO3H and H2SO4) for Redox Flow Battery Application  

Science Journals Connector (OSTI)

Study of the Ce3+/Ce4+ Redox Couple in Mixed-Acid Media (CH3SO3H and H2SO4) for Redox Flow Battery Application ... The present paper first reports a kind of supporting electrolyte, mixed-acid media (CH3SO3H and H2SO4), used in redox flow battery (RFB) technology. ... Redox flow battery (RFB) technology(1, 2) has received wide attention in the application for renewable energy storage systems. ...

Zhipeng Xie; Fengjiao Xiong; Debi Zhou

2011-04-19T23:59:59.000Z

31

Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ... A powerful low-cost electrocatalyst, nanorod Nb2O5, is synthesized using the hydrothermal method with monoclinic phases and simultaneously deposited on the surface of a graphite felt (GF) electrode in an all vanadium flow battery (VRB). ... Flow battery cyclic performance also demonstrates the excellent stability of the as prepared Nb2O5 catalyst enhanced electrode. ...

Bin Li; Meng Gu; Zimin Nie; Xiaoliang Wei; Chongmin Wang; Vincent Sprenkle; Wei Wang

2013-11-26T23:59:59.000Z

32

Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.  

SciTech Connect

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Chen, Z.; Liu, J.; Jansen, A. N.; Casteel, B.; Amine, K.; GirishKumar, G.; Air Products and Chemicals, Inc.

2010-01-01T23:59:59.000Z

33

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes  

E-Print Network (OSTI)

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes Alex and Aerospace Engineering Background Solid oxide fuel cells lose mechanical stability and functionality when oxidize (redox reaction) instead of the hydrogen fuel [2]. This conversion to NiO exerts a volumetric

Petta, Jason

34

ESS 2012 Peer Review - Acid Based Blend Membranes for Redox Flow Batteries - Alan Cisar, Lynntech  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Acid Based Blend Membranes for Redox Flow Batteries Acid Based Blend Membranes for Redox Flow Batteries DOE Grant No: DE-SC0006306 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX 77845 *E-mail: alan.cisar@lynntech.com, Phone: 979.764.2311 Prof. Arumugam Manthiram University of Texas, Austin, TX 78712 Prof. Fuqiang Liu University of Texas Arlington, Arlington, TX 76019 Conclusions Lynntech, in conjunction with the University of Texas and the University of Texas at Arlington, developed a new series of low-cost polymer blend membranes with high proton conductivity and ultralow vanadium ion permeability. The proton conductivity and physical properties of these membranes are tunable by adjusting the ratio of acid and base components. Membrane conductivity was found to be more critical to

35

ESS 2012 Peer Review - New Generation Aqueous Base Redox Flow Battery Component Development - Wei Wang, PNNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Generation Aqueous Base Redox Flow Generation Aqueous Base Redox Flow Battery Component Development Wei Wang, Qingtao Luo, Xiaoliang Wei, Bin Li, Zimin Nie, Baowei Chen, Yuyan Shao, Vijayakumar Murugesan, Amy Chen, Gordon, Xia, Liyu Li, Gary Z. Yang, Vincent Sprenkle Pacific Northwest National Laboratory 902 Battelle Boulevard P. O. Box 999 Richland, WA 99352, USA DOE Stationary Energy Storage Program Review, Washington, DC Sept. 26-28, 2012 Dr. Imre Gyuk 1 2 Review of previous work 2.5M, ~30Wh/L, -5~50 o C Mixed-acid VRB Double Energy Density Extend temperature window Charge Discharge Charge Discharge Charge Discharge Catholyte: VO 2+ + Cl - + H 2 O - e VO 2 Cl + 2H + ε co =1.0 V Anolyte: V 3+ + e V 2+ ε ao =-0.25 Overall: VO 2+ + Cl

36

Membrane Separator for Redox Flow Batteries that Utilize Anion Radical Mediators.  

SciTech Connect

A Na + ion conducting polyethylene oxide membrane is developed for an organic electrolyte redox flow battery that utilizes anion radical mediators. To achieve high specific ionic conductivity, tetraethyleneglycol dimethylether (TEGDME) is used as a plasticizer to reduce crystallinity and increase the free volume of the gel film. This membrane is physically and chemically stable in TEGDME electrolyte that contains highly reactive biphenyl anion radical mediators.

Delnick, Frank M.

2014-10-01T23:59:59.000Z

37

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (II): A Study on Low-Temperature Heat Capacities and Thermodynamic Properties of VOSO42.63H2O(s)  

Science Journals Connector (OSTI)

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (II): A Study on Low-Temperature Heat Capacities and Thermodynamic Properties of VOSO42.63H2O(s) ... The low-temperature heat capacities of VOSO42.63H2O(s) which is a key component in the electrolyte of the vanadium redox flow battery were measured by adiabatic calorimetry in the temperature range of (78 to 388) K, and the experimental values of the molar heat capacities in the temperature regions of (78 to 372) K were fitted to a polynomial equation. ... The vanadium redox flow battery (VRB) was first proposed and investigated by Skyllas-Kazacos et al.,(1, 2) in which the V(II)/V(III) and V(IV)/V(V) redox couples were successfully employed as the negative and positive half-cell electrolytes. ...

Ye Qin; Jian-Guo Liu; You-Ying Di; Chuan-Wei Yan; Chao-Liu Zeng; Jia-Zhen Yang

2009-12-17T23:59:59.000Z

38

ESS 2012 Peer Review - Highly Selective Proton-Conducting Composite Membranes for Redox Flow Batteries - Alan Cisar, Lynntech  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Membrane for Redox Flow Batteries Membrane for Redox Flow Batteries DOE Grant No: DE-SC0004516 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX 77845 *E-mail: alan.cisar@lynntech.com, Phone: 979.764.2311 Introduction * Redox flow batteries (RFBs) are a promising technology to store electrical energy from intermittent renewable sources such as solar and wind power. Although they offer many advantages, RFBs with reduced cost and improved performance (i.e., efficiency and durability) need to be developed to achieve broad market penetration. * Ion exchange membranes in RFBs separate two soluble redox couples should allow rapid proton transport and suppress transport of the reactive species between anode and cathode compartments. Nafion

39

Synergistic Effect of Carbon Nanofiber/Nanotube Composite Catalyst on Carbon Felt Electrode for High-Performance All-Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Synergistic Effect of Carbon Nanofiber/Nanotube Composite Catalyst on Carbon Felt Electrode for High-Performance All-Vanadium Redox Flow Battery ... Carbon nanofiber/nanotube (CNF/CNT) composite catalysts grown on carbon felt (CF), prepared from a simple way involving the thermal decomposition of acetylene gas over Ni catalysts, are studied as electrode materials in a vanadium redox flow battery. ... Energy storage; redox flow battery; electrode; carbon nanofiber; carbon nanotube; catalyst ...

Minjoon Park; Yang-jae Jung; Jungyun Kim; Ho il Lee; Jeaphil Cho

2013-09-11T23:59:59.000Z

40

In Situ X-ray Near-Edge Absorption Spectroscopy Investigation of the State of Charge of All-Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

all-vanadium flow battery; X-ray near-edge adsorption spectroscopy; synchrotron; in situ; state of charge; electrolyte ... Among different types of RFBs, the all-vanadium redox flow battery (VRB) displays excellent electrochemical activity and reversibility. ... To the best of our knowledge, this is the first report to use the in situ synchrotron techniques to study the redox flow battery. ...

Chuankun Jia; Qi Liu; Cheng-Jun Sun; Fan Yang; Yang Ren; Steve M. Heald; Yadong Liu; Zhe-Fei Li; Wenquan Lu; Jian Xie

2014-09-05T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Some Lessons Learned from 20 Years in RedOx Flow Battery R&d  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Steve Clarke, Applied Intellectual Capital, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

42

ESS 2012 Peer Review - Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries - Fei Wang, EIC Laboratories  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries Fei Wang, Dharmasena Peramunage, James M. Sylvia, and Monsy M. Jocob EIC Laboratories, Inc. 111 Downey Street, Norwood, MA 02062. www.eiclabs.com Identification of the Problem and Technical Approach Redox flow batteries (RFB) hold great promise for large scale electrochemical energy storage. A critical component of RFB is the membrane which separates anode and cathode compartments. The current state-of-the-art membrane, NAFION is too expensive, lacks selectivity, permitting leakage between anode and cathode electrolyte compartments. EIC is developing a novel bilayer, interpenetrating network membrane. Thin Nafion layer for anode side protection providing oxidative stability. The bulk part of the membrane consists of a block

43

In-situ Investigation of Vanadium Ion Transport in Redox Flow Battery  

SciTech Connect

We will show a new method to differentiate the vanadium transport from concentration gradient and that from electric field. Flow batteries with vanadium and iron redox couples as the electro-active species were employed to investigate the transport behavior of vanadium ions in the presence of electric field. It was shown that electric field accelerated the positive-to-negative and reduced the negative-to-positive vanadium ions transport in charge process and affected the vanadium ions transport in an opposite way in discharge process. In addition, a method was designed to differentiate the concentration gradient-driven vanadium ions diffusion and electric field-driven vanadium ions migration. Simplified mathematical model was established to simulate the vanadium ions transport in real charge-discharge operation of flow battery. The concentration gradient diffusion coefficients and electric-migration coefficients of V2+, V3+, VO2+, and VO2+ across Nafion membrane were obtained by fitting the experimental data.

Luo, Qingtao; Li, Liyu; Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Chen, Baowei; Yang, Zhenguo

2012-06-27T23:59:59.000Z

44

Dynamic electro-thermal modeling of all-vanadium redox flow battery with forced cooling strategies  

Science Journals Connector (OSTI)

Abstract The present study focuses on the dynamic electro-thermal modeling for the all-vanadium redox flow battery (VRB) with forced cooling strategies. The Foster network is adopted to dynamically model the heat dissipation of VRB with heat exchangers. The parameters of Foster network are extracted by fitting the step response of it to the results of linearized CFD model. Then a complete electro-thermal model is proposed by coupling the heat generation model, Foster network and electrical model. Results show that the established model has nearly the same accuracy with the nonlinear CFD model in electrolyte temperature prediction but drastically improves the computational efficiency. The modeled terminal voltage is also benchmarked with the experimental data under different current densities. The electrolyte temperature is found to be significantly influenced by the flow rate of coolant. As compared, although the electrolyte flow rate has unremarkable impact on electrolyte temperature, its effect on system pressure drop and battery efficiency is significant. Increasing the electrolyte flow rate improves the coulombic efficiency, voltage efficiency and energy efficiency simultaneously but at the expense of higher pump power demanded. An optimal flow rate exists for each operating condition to maximize the system efficiency.

Zhongbao Wei; Jiyun Zhao; Binyu Xiong

2014-01-01T23:59:59.000Z

45

Electrocapturing flow cell  

DOE Patents (OSTI)

A flow cell for electrophoretically-assisted capturing analytes from a flow. The flow cell includes a specimen chamber, a first membrane, a second membrane, a first electrode chamber, and a second electrode chamber. The specimen chamber may have a sample inlet and a sample outlet. A first portion of the first membrane may be coupled to a first portion of the specimen chamber. A first portion of the second membrane may be coupled to a second portion of the specimen chamber. The first electrode chamber may be configured to accept a charge. A portion of the first electrode chamber may be coupled to a second portion of the first membrane. A second electrode chamber may be configured to accept an opposite charge. A portion of the second electrode chamber may be coupled to a second portion of the second membrane.

Morozov, Victor (Manassas, VA)

2011-04-05T23:59:59.000Z

46

Development of a Novel Iodine-Vitamin C/Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Abstract A novel (I+/I2)/vitamin C vs. V4+/V5+ semi-vanadium redox flow battery (semi-VRFB) with iodine, vitamin C, and V4+/V5+ redox couples, using multiple electrodes was investigated. The electrodes, Ni-P/carbon paper and Ni-P/TiO2/carbon paper, were modified by the electroless plating method and sol-gel process. The electrochemical characteristics and the performance of the semi-VRFB were verified by the cyclic voltammetry method and a charge-discharge test. This study shows modified electrodes can improve the reversibility and symmetry of the oxidation-reduction reaction of the semi-VRFB system, and effectively raise its storage ability. The coulomb efficiency of the semi-VRFB system is close to 96%, which is higher than the all-VRFB. The semi-VRFB system can reduce the amount of vanadium salt, therefore, it is not only a reduction in cost, but also has a great potential for the development of energy storage systems.

Mei-Ling Chen; Shu-Ling Huang; Chin-Lung Hsieh; Jan- Yen Lee; Tz-Jiun Tsai

2014-01-01T23:59:59.000Z

47

Paper Offer #: 031CES-216 PlanarArray REDOX Cells and pH Sensors  

E-Print Network (OSTI)

, is below one pM which is needed for water quality measurements. The richness of the detectable speciesPaper Offer #: 031CES-216 PlanarArray REDOX Cells and pH Sensors for ISS Water Quality and Microbe which exposes these elements to steam at 121°C for 30 minutes. INTRODUCTION The goal of this effort

Kounaves, Samuel P.

48

Siliconized Triarylamines As Redox Mediator in Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

Siliconized Triarylamines As Redox Mediator in Dye-Sensitized Solar Cells ... We thank the Canadian Foundation for Innovation (CFI) and the Natural Sciences and Engineering Research Council of Canada (NSERC), York University (S.M.), and University of Toronto (T.P.B.) for their financial support. ...

Ali Sepehrifard; Brett A. Kamino; Timothy P. Bender; Sylvie Morin

2012-10-31T23:59:59.000Z

49

Some Lessons Learned from 20 Years in RedOx Flow Battery R&d  

NLE Websites -- All DOE Office Websites (Extended Search)

lessons learned from 20 years in lessons learned from 20 years in RedOx Flow Battery R&D Dr Steve Clarke, CEO Applied Intellectual Capital, Alameda CAc DOE Workshop Washington DC March 2012 www.apicap.com Contents ● AIC's involvement in RFB R&D ● Some key lessons learned ● Some remaining challenges to be overcome 2 Applied Intellectual Capital ● Technology consulting  Electrochemical and materials focus  Clients include leading industrials, VCs, DOE, DOD and EPA  33,000 ft. facility for laboratory, engineering, rapid prototyping and testing ● Technology venturing (own micro- fund)  IP generated by consulting and R&D  Leverages labs, facilities and consulting successes ● Combined resources  Proven business development team  Start-up to IPO

50

ESS 2012 Peer Review - Component Research for Redox Flow Batteries - Tom Zawodzinski, ORNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Battelle Battelle for the Department of Energy Component Research for Redox Flow Batteries Tom Zawodzinski and Che-Nan (Josh) Sun With help from Jamie Lawton, Zhijiang Tang, Doug Aaron, Alex Papandrew, Qinhua Liu, Matt Mench (UTK) Frank Delnick (SNL) Thanks to Imre Gyuk (OE) and team at UTK Managed by UT-Battelle for the Department of Energy Approach This project is a little different from many others in the portfolio We are not looking into alternative battery chemistries per se We are doing work to guide you in choices of materials and hardware designs to make all RFBs better! Focus on components, diagnostics to drive understanding how to improve Managed by UT-Battelle for the Department of Energy Goals and Tasks 1. Demonstrate improved performance of RFBs in pre-

51

ESS 2012 Peer Review - Single Substance Organic Redox Flow Battery - Paul Rasmussen, Vinazene  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Charging Mechanism Charging Mechanism The Z compound, as described in Vinazene Patent 8,080,327, undergoes the following half reactions during charging: Z Z + + e - E 0 = -1.3V Z + e -  Z - E 0 = -1.5V _____________________ 2Z  Z - + Z + E 0 = -2.8V A Single Substance Organic Redox Flow Battery -+- -+- Components Compound Z Tetraethylammonium Tetrafluoroborate (TEA-BF 4 ) Maintains Electroneutrality Acetonitrile (MeCN) Dielectric and Transport medium Abstract Abundant energy, in the exajoule range, is available everyday from solar and wind flux. However, green sources of this energy are subject to intermittent and/or periodic fluctuations. Mitigation of supply obstacles is possible through the use of cost effective and dispatchable energy storage methods. During Phase I of this SBIR

52

Development of carbon composite bipolar plate (BP) for vanadium redox flow battery (VRFB)  

Science Journals Connector (OSTI)

Abstract A vanadium redox flow battery (VRFB) is one of the most promising energy storage systems (ESSs) due to its safety, durability and scalability. However, high cost of its components has been obstacle for commercialization of VRFB. Especially, bipolar plates (BPs) which are the main components of VRFB, are fabricated using graphite, which increases not only its manufacturing cost, but also decreases the reliability of VFRB, especially for the large area BP due to the brittleness of graphite although the graphite has high electrical conductivity and chemical stability. In this work, a carbon composite BP for the VRFB has been developed optimally considering its electrical as well as chemical stabilities against strong acids. Charge/discharge tests of the VRFB using the developed carbon composite \\{BPs\\} were performed to observe its energy and voltage efficiencies, from which the durability of the composite BP was estimated.

Ki Hyun Kim; Bu Gi Kim; Dai Gil Lee

2014-01-01T23:59:59.000Z

53

Modeling a vanadium redox flow battery system for large scale applications  

Science Journals Connector (OSTI)

A simulation model of a vanadium redox flow battery (VRFB) system based on measurements with a kilowatt scale real life VRFB unit was developed. Various hourly charging and discharging cycles were performed for states of charge (SOC) of 75%, 60%, 40% and 20% at different power values ranging from 2kW to 10kW. The dependence of the overall system efficiency in a VRFB unit on the SOC was determined by considering the energy losses at stacks during the electrochemical conversion and by the auxiliary power consumption of the hydraulic circuits as well as the power conversion systems. Using the model, optimal number of modules for certain power levels during charging and discharging operations were estimated for megawatt scale operations.

Burak Turker; Sebastian Arroyo Klein; Eva-Maria Hammer; Bettina Lenz; Lidiya Komsiyska

2013-01-01T23:59:59.000Z

54

Flow Cells for Energy Storage Workshop Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Workshop Summary Report Workshop Summary Report Prepared for: U. S. Department of Energy Prepared by: Dr. Adam Z. Weber Lawrence Berkeley National Laboratory Organizing Committee: Michael Perry, UTRC Tom Zawodzinski, UTK and ORNL Ned Stetson, DOE EERE Mark Johnson, DOE ARPA-E Imre Gyuk, DOE OEDER i Executive Summary An essentially identical technology to a reversible fuel cell is that of a redox flow cell (RFC) or redox flow battery (RFB), where a RFC can be seen as merging the concepts of RFBs with recent improvements in fuel cells. To investigate how a RFC can be a grid-scale electrical- energy-storage (EES) system and the associated technological needs, this workshop was held. The specific objectives of the workshop were to understand the needs for applied research in RFCs; identify the grand challenges and prioritize R&D needs; and gather input for future

55

Redox instability, mechanical deformation, and heterogeneous damage accumulation in solid oxide fuel cell anodes  

Science Journals Connector (OSTI)

Mechanical integrity and damage tolerance represent two key challenges in the design of solid oxide fuel cells(SOFCs). In particular reduction and oxidation(redox) cycles and the associated large transformation strains have a notable impact on the mechanical stability and failure mode of SOFCanodes. In this study the deformation behavior under redox cycling is investigated computationally with an approach that provides a detailed microstructurally based view of heterogeneous damage accumulation behavior within an experimentally obtained nickel/yttria stabilized zirconia SOFCanode microstructure. Simulation results underscore the critical role that the microstructure plays in the mechanical deformation behavior of and failure within such materials.

F. Abdeljawad; G. J. Nelson; W. K. S. Chiu; M. Haataja

2012-01-01T23:59:59.000Z

56

Redox Flow Batteries for Grid-scale Energy Storage - Energy Innovation...  

NLE Websites -- All DOE Office Websites (Extended Search)

and could also improve the electric grid's reliability and help connect more wind turbines and solar panels to the grid. A schematic of an upgraded vanadium redox batter...

57

ESS 2012 Peer Review - Low-Cost, High-Performance Hybrid Membranes for Redox Flow Batteries - Hongxing Hu, Amsen Technologies  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DESIGN © 2008 DESIGN © 2008 www.PosterPresentations.com Low-Cost, High-Performance Hybrid Membranes for Redox Flow Batteries Hongxing Hu, Amsen Technologies LLC DOE SBIR Project, Program Manager at DOE: Dr. Imre Gyuk Objectives and Technical Approach Objectives: This SBIR project aims to develop low-cost, high performance hybrid polymeric PEMs for redox flow batteries (RFBs). Such membranes shall have high chemical stability in RFB electrolytes, high proton conductivity, low permeability of vanadium ions, along with high dimensional stability, high mechanical strength and durability, and lower cost than Nafion membranes. Approach: * Hybrid membranes of sulfonated polymers * Balance between different types of polymers for proton conductivity and chemical stability

58

ESS 2012 Peer Review - Estimation of Capital and Levelized Cost for Redox Flow Batteries - Vilayanur Viswanathan, PNNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Estimation of Capital and Levelized Estimation of Capital and Levelized Cost for Redox Flow Batteries V. Viswanathan, A. Crawford, L. Thaller 1 , D. Stephenson, S. Kim, W. Wang, G. Coffey, P. Balducci, Z. Gary Yang 2 , Liyu Li 2 , M. Kintner-Meyer, V. Sprenkle 1 Consultant 2 UniEnergy Technology September 28, 2012 USDOE-OE ESS Peer Review Washington, DC Dr. Imre Gyuk - Energy Storage Program Manager, Office of Electricity Delivery and Energy Reliability 1 What are we trying to accomplish? PNNL grid analytics team has established ESS cost targets for various applications PNNL cost/performance model estimates cost for redox flow battery systems of various chemistries drives research internally to focus on most important components/parameters/metrics for cost reduction and performance improvement

59

Properties Investigation of Sulfonated Poly(ether ether ketone)/Polyacrylonitrile AcidBase Blend Membrane for Vanadium Redox Flow Battery Application  

Science Journals Connector (OSTI)

Acidbase blend membrane prepared from sulfonated poly(ether ether ketone) (SPEEK) and polyacrylonitrile (PAN) was detailedly evaluated for vanadium redox flow battery (VRFB) application. SPEEK/PAN blend membrane exhibited dense and homogeneous cross-...

Zhaohua Li; Wenjing Dai; Lihong Yu; Le Liu; Jingyu Xi; Xinping Qiu; Liquan Chen

2014-10-15T23:59:59.000Z

60

Nanoporous Polytetrafluoroethylene/Silica Composite Separator as a High-Performance All-Vanadium Redox Flow Battery Membrane  

SciTech Connect

Driven by the motivation of searching for low-cost membrane alternatives, a novel nanoporous polytetrafluoroethylene/silica composite separator has been prepared and evaluated for its use in all-vanadium mixed-acid redox flow battery. This separator consisting of silica particles enmeshed in a polytetrafluoroethylene fibril matrix has no ion exchange capacity and is featured with unique nanoporous structures, which function as the ion transport channels in redox flow battery operation, with an average pore size of 38nm and a porosity of 48%. This separator has produced excellent electrochemical performance in the all-vanadium mixed-acid system with energy efficiency delivery comparable to Nafion membrane and superior rate capability and temperature tolerance. The separator also demonstrates an exceptional capacity retention capability over extended cycling, offering additional operational latitude towards conveniently mitigating the capacity decay that is inevitable for Nafion. Because of the inexpensive raw materials and simple preparation protocol, the separator is particularly low-cost, estimated to be at least an order of magnitude more inexpensive than Nafion. Plus the proven chemical stability due to the same backbone material as Nafion, this separator possesses a good combination of critical membrane requirements and shows great potential to promote market penetration of the all-vanadium redox flow battery by enabling significant reduction of capital and cycle costs.

Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Chen, Baowei; Simmons, Kevin L.; Sprenkle, Vincent L.; Wang, Wei

2013-09-02T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Microstructural coarsening effects on redox instability and mechanical damage in solid oxide fuel cell anodes  

Science Journals Connector (OSTI)

In state-of-the-art high temperature solid oxide fuel cells (SOFCs) a porous composite of nickel and yttria stabilized zirconia (Ni/YSZ) is employed as the anode. The rapid oxidation of Ni into NiO is regarded as the main cause of the so-called reduction-oxidation (redox) instability in Ni/YSZ anodes due to the presence of extensive bulk volume changes associated with this reaction. As a consequence the development of internal stresses can lead to performance degradation and/or structural failure. In this study we employ a recently developed continuum formalism to quantify the mechanical deformation behavior and evolution of internal stresses in Ni/YSZ porous anodes due to re-oxidation. In our approach a local failure criterion is coupled to the continuum framework in order to account for the heterogeneous damage accumulation in the YSZ phase. The hallmark of our approach is the ability to track the spatial evolution of mechanical damage and capture the interaction of YSZ damaged regions with the local microstructure. Simulation results highlight the importance of the microstructure characterized by Ni to YSZ particle size ratio on the redox behavior and damage accumulation in as-synthesized SOFC anode systems. Moreover a redox-strain-to-failure criterion is developed to quantify the degree by which coarsened anode microstructures become more susceptible to mechanical damage during re-oxidation.

F. Abdeljawad; M. Haataja

2013-01-01T23:59:59.000Z

62

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox...  

NLE Websites -- All DOE Office Websites (Extended Search)

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries. TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries. Abstract: We will...

63

Fuel Cell Technologies Office: Flow Cells for Energy Storage Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Flow Cells for Energy Flow Cells for Energy Storage Workshop to someone by E-mail Share Fuel Cell Technologies Office: Flow Cells for Energy Storage Workshop on Facebook Tweet about Fuel Cell Technologies Office: Flow Cells for Energy Storage Workshop on Twitter Bookmark Fuel Cell Technologies Office: Flow Cells for Energy Storage Workshop on Google Bookmark Fuel Cell Technologies Office: Flow Cells for Energy Storage Workshop on Delicious Rank Fuel Cell Technologies Office: Flow Cells for Energy Storage Workshop on Digg Find More places to share Fuel Cell Technologies Office: Flow Cells for Energy Storage Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Annual Merit Review Proceedings

64

Mirrored serpentine flow channels for fuel cell  

DOE Patents (OSTI)

A PEM fuel cell having serpentine flow field channels wherein the input/inlet legs of each channel border the input/inlet legs of the next adjacent channels in the same flow field, and the output/exit legs of each channel border the output/exit legs of the next adjacent channels in the same flow field. The serpentine fuel flow channels may be longer, and may contain more medial legs, than the serpentine oxidant flow channels.

Rock, Jeffrey Allan (Rochester, NY)

2000-08-08T23:59:59.000Z

65

Fuel cell with internal flow control  

SciTech Connect

A fuel cell stack is provided with a plurality of fuel cell cassettes where each fuel cell cassette has a fuel cell with an anode and cathode. The fuel cell stack includes an anode supply chimney for supplying fuel to the anode of each fuel cell cassette, an anode return chimney for removing anode exhaust from the anode of each fuel cell cassette, a cathode supply chimney for supplying oxidant to the cathode of each fuel cell cassette, and a cathode return chimney for removing cathode exhaust from the cathode of each fuel cell cassette. A first fuel cell cassette includes a flow control member disposed between the anode supply chimney and the anode return chimney or between the cathode supply chimney and the cathode return chimney such that the flow control member provides a flow restriction different from at least one other fuel cell cassettes.

Haltiner, Jr., Karl J. (Fairport, NY); Venkiteswaran, Arun (Karnataka, IN)

2012-06-12T23:59:59.000Z

66

Doped Yttrium Chromite-Ceria Composite as a Redox-Stable and Sulfur-Tolerant Anode for Solid Oxide Fuel Cells  

SciTech Connect

A Ca- and Co-doped yttrium chromite (YCCC) - samaria-doped ceria (SDC) composite was studied in relation to a potential use as a solid oxide fuel cell (SOFC) anode material. Tests performed using the yttria-stabilized zirconia (YSZ) electrolyte-supported cells revealed that the electrocatalytic activity of the YCCC-SDC anode towards hydrogen oxidation at 800 C was comparable to that of the Ni-YSZ anode. In addition, the YCCC-SDC anode exhibited superior sulfur tolerant characteristics showing less than 10% increase in a polarization resistance, fully reversible, upon exposure to 20 ppm H2S at 800 C. No performance degradation was observed during multiple reduction-oxidation (redox) cycles when the anode was intentionally exposed to the air environment followed by the reduction in hydrogen. The redox tolerance of the YCCC-SDC anode was attributed to the dimensional and chemical stability of the YCCC exhibiting minimal isothermal chemical expansion upon redox cycling.

Yoon, Kyung J.; Coyle, Christopher A.; Marina, Olga A.

2011-12-11T23:59:59.000Z

67

Ion Conducting Membranes for Fuel Cells and other Electrochemical Devices  

Science Journals Connector (OSTI)

ion conducting membrane; fuel cell; redox-flow battery; Li ion battery; proton; hydroxide; diffusion; conductivity; nanomorphology; hydration; visco-elastic constants; phosphate; polyelectrolyte; ionomer; block-copolymer; Nafion; Aquivion ... At this stage, however, they have an immediate potential for redox-flow battery applications, as will be discussed later. ... When the flow battery is charged or discharged, an equivalent amount of ionic charge has to cross the membrane, while the ions involved in the redox process have to be efficiently separated. ...

Klaus-Dieter Kreuer

2013-11-19T23:59:59.000Z

68

ESS 2012 Peer Review - Redox Flow Battery (RFB) with Low-cost Electrolyte and Membrane Technologies - Thomas Kodenkandath, ITN Energy Systems  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Innovative, high energy density Mn-V based RFB electrolytes as a Innovative, high energy density Mn-V based RFB electrolytes as a low-cost alternate to all-Vanadium systems * Low-cost membrane technology, based on renewable biopolymer Chitosan with improved proton conduction & chemical stability, adaptable to Mn-V system * Scale-up of electrolyte and membrane technologies in pursuit of ARPA-E's goal for a 2.5kW/10kWh RFB stack with integrated BoS at a total cost of ~$1000/unit and ~1.2 m 3 footprint ITN Energy Systems, Inc., Littleton, CO 2.5kW/10kWh Redox Flow Battery (RFB) with Low-cost Electrolyte and Membrane Technologies $2.1 M, 33-month program awarded by ARPA-E Sept 7, 2012 Dr. Thomas Kodenkandath High-Performance, Low-cost RFB through Electrolyte & Membrane Innovations Technology Summary

69

High speed flow cytometric separation of viable cells  

DOE Patents (OSTI)

Hematopoietic cell populations are separated to provide cell sets and subsets as viable cells with high purity and high yields, based on the number of original cells present in the mixture. High-speed flow cytometry is employed using light characteristics of the cells to separate the cells, where high flow speeds are used to reduce the sorting time.

Sasaki, D.T.; Van den Engh, G.J.; Buckie, A.M.

1995-11-14T23:59:59.000Z

70

High speed flow cytometric separation of viable cells  

DOE Patents (OSTI)

Hematopoietic cell populations are separated to provide cell sets and subsets as viable cells with high purity and high yields, based on the number of original cells present in the mixture. High-speed flow cytometry is employed using light characteristics of the cells to separate the cells, where high flow speeds are used to reduce the sorting time.

Sasaki, Dennis T. (Mountain View, CA); Van den Engh, Gerrit J. (Seattle, WA); Buckie, Anne-Marie (Margate, GB)

1995-01-01T23:59:59.000Z

71

Effects of interstitial flow on tumor cell migration  

E-Print Network (OSTI)

Interstitial flow is the convective transport of fluid through tissue extracellular matrix. This creeping fluid flow has been shown to affect the morphology and migration of cells such as fibroblasts, cancer cells, endothelial ...

Polacheck, William J. (William Joseph)

2010-01-01T23:59:59.000Z

72

Modulation of redox status and calcium handling by extremely low frequency electromagnetic fields in C2C12 muscle cells: A real-time, single-cell approach  

Science Journals Connector (OSTI)

The biological effects of electric and magnetic fields, which are ubiquitous in modern society, remain poorly understood. Here, we applied a single-cell approach to study the effects of short-term exposure to extremely low frequency electromagnetic fields (ELF-EMFs) on muscle cell differentiation and function using C2C12 cells as an in vitro model of the skeletal muscle phenotype. Our focus was on markers of oxidative stress and calcium (Ca2+) handling, two interrelated cellular processes previously shown to be affected by such radiation in other cell models. Collectively, our data reveal that ELF-EMFs (1) induced reactive oxygen species production in myoblasts and myotubes with a concomitant decrease in mitochondrial membrane potential; (2) activated the cellular detoxification system, increasing catalase and glutathione peroxidase activities; and (3) altered intracellular Ca2+homeostasis, increasing the spontaneous activity of myotubes and enhancing cellular reactivity to a depolarizing agent (KCl) or an agonist (caffeine) of intracellular store Ca2+channels. In conclusion, our data support a possible link between exposure to ELF-EMFs and modification of the cellular redox state, which could, in turn, increase the level of intracellular Ca2+and thus modulate the metabolic activity of C2C12 cells.

Caterina Morabito; Francesca Rovetta; Mariano Bizzarri; Giovanna Mazzoleni; Giorgio Fan; Maria A. Mariggi

2010-01-01T23:59:59.000Z

73

Flow Cells for Energy Storage Workshop Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Electricity Delivery Electricity Delivery & Energy Reliability Organized by: Energy Efficiency & Renewable Energy W i t h h e l p b y : Agenda Day/Time Speaker Subject Wednesday, March 07, 2012 8:45-9:00 Adam Weber, LBNL Welcome and workshop overview 9:00-9:30 Various, EERE, OFCT Background, approach, and reversible fuel cells 9:30-9:55 Michael Perry, UTRC Renaissance in flow cells: opportunities 9:55-10:20 Joe Eto, LBNL Energy storage requirements for the smart grid 10:20-10:35 AM Break 10:35-11:00 Robert Savinell, CWRU Revisiting flow-battery R&D 11:00-11:25 Stephen Clarke, Applied Intellectual Capital Lessons learned and yet to be learned from 20 years in RFB R&D 11:25-11:45 Imre Gyuk, DOE OE Research and deployment of stationary storage at DOE

74

Electron flow in multiheme bacterial cytochromes is a balancing act between heme electronic interaction and redox potentials  

Science Journals Connector (OSTI)

...substrates within the cell, but expanding...saturated by a dummy hydrogen atom and the axial...saturated with a hydrogen at the {beta...production in microbial fuel cells . Biosens Bioelectron...scheme for hybrid Car-Parrinello molecular...

Marian Breuer; Kevin M. Rosso; Jochen Blumberger

2014-01-01T23:59:59.000Z

75

Microfabricated Renewable Beads-Trapping/Releasing Flow Cell...  

NLE Websites -- All DOE Office Websites (Extended Search)

Microfabricated Renewable Beads-TrappingReleasing Flow Cell for Rapid Antigen-Antibody Reaction in Chemiluminescent Immunoassay Microfabricated Renewable Beads-TrappingReleasing...

76

Quantification of Cell Fusion by Flow Cytometry  

Science Journals Connector (OSTI)

Cells of different types can be induced to fuse by electroshock. Cells of one type are typically dominant and are able to ... the nuclei derived from cells of the other type, in fusion hybrids derived from one ce...

Stephen Sullivan; Martin Waterfall; Ed J. Gallagher; Jim McWhir

2006-01-01T23:59:59.000Z

77

Renaissance in Flow-Cell Technologies: Recent Advancements and...  

Office of Environmental Management (EM)

Presentation by Mike Perry, United Technologies Research Center, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC. flowcells2012perry.pdf...

78

Microfluidics for flow cytometric analysis of cells and particles  

Science Journals Connector (OSTI)

This review describes recent developments in microfabricated flow cytometers and related microfluidic devices that can detect, analyze, and sort cells or particles. The high-speed analytical capabilities of flow cytometry depend on the cooperative use of microfluidics, optics and electronics. Along with the improvement of other components, replacement of conventional glass capillary-based fluidics with microfluidic sample handling systems operating in microfabricated structures enables volume- and power-efficient, inexpensive and flexible analysis of particulate samples. In this review, we present various efforts that take advantage of novel microscale flow phenomena and microfabrication techniques to build microfluidic cell analysis systems.

Dongeun Huh; Wei Gu; Yoko Kamotani; James B Grotberg; Shuichi Takayama

2005-01-01T23:59:59.000Z

79

Fuel Cell Technologies Overview: 2012 Flow Cells for Energy Storage Workshop  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Sunita Satyapal and Dimitrios Papageorgopoulos, U.S. Department of Energy Fuel Cell Technologies Program, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

80

In situ redox cycle of a nickelYSZ fuel cell anode in an environmental transmission electron microscope  

E-Print Network (OSTI)

of a nickel/yttria-stabilized zirconia solid oxide fuel cell anode. The results reveal that the transfer transmission electron microscopy (ETEM); Solid oxide fuel cell (SOFC); Reduction; Oxidation; Density functional theory (DFT) 1. Introduction Solid oxide fuel cell (SOFC) technology is a promising energy conversion

Dunin-Borkowski, Rafal E.

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Flow cytometry aids basic cell biology research and drug discovery  

NLE Websites -- All DOE Office Websites (Extended Search)

Flow cytometry aids basic cell biology research and drug discovery Flow cytometry aids basic cell biology research and drug discovery Flow cytometry aids basic cell biology research and drug discovery Life Technologies Corporation and LANL have released the Attune® Acoustic Focusing Cytometer, featuring a reduced footprint, reduced consumables, and an affordable price. April 3, 2012 Attune® Acoustic Focusing Cytometer The Attune® Acoustic Focusing Cytometer achieves sample throughput at rates over 10 times faster than other cytometers-up to 1,000 μL per minute. In December 2009, Life Technologies Corporation announced the release of the Attune® Acoustic Focusing Cytometer, a first-of-its-kind cytometer system based on technology developed at Los Alamos National Laboratory (LANL). Examining cells has never been clearer with LANL's use of acoustic waves

82

Thermochemical treatments based on NH3/O2 for improved graphite-based fiber electrodes in vanadium redox flow batteries  

Science Journals Connector (OSTI)

Abstract Electrochemical behavior of the polyacrylonitrile (PAN)-based graphite as a low cost electrode material for vanadium based redox batteries (VFB) in sulfuric acid medium has been improved by means of the successful introduction of nitrogen and oxygen-containing groups at the graphite surface by thermal activation under NH3/O2 (1:1) atmosphere. Influence of the temperature and treatment duration times have been studied towards the positive reaction of VFB. The structure, composition, and electrochemical properties of the treated samples have been characterized with field emission scanning electron microscopy, X-ray photoelectron spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The estimation of electrochemical surface area has also been evaluated. The treatment of PAN graphite material at 773K for 24-h leads to electrode materials with the best electrochemical activity towards the VO 2 + /VO2+ redox couple. This method produces an increase of the nitrogen and oxygen content at the surface up to 8% and 32%, respectively, and is proved to be a straightforward and cost-effective methodology. This improvement of the electrochemical properties is attributed to the incorporation of the nitrogen and oxygen-containing groups that facilitate the electron transfer through the electrode/electrolyte interface for both oxidation and reduction processes.

Cristina Flox; Javier Rubio-Garca; Marcel Skoumal; Teresa Andreu; Juan Ramn Morante

2013-01-01T23:59:59.000Z

83

Enhanced reductive degradation of methyl orange in a microbial fuel cell through cathode modification with redox mediators  

Science Journals Connector (OSTI)

A model azo dye, methyl orange (MO), was reduced through in situ utilization of the electrons derived from the anaerobic conversion of organics in a microbial fuel cell (MFC). The MO reduction process could be...

Rong-Hua Liu; Guo-Ping Sheng; Min Sun

2011-01-01T23:59:59.000Z

84

Flow Cells for Energy Storage Workshop Summary Report  

Energy.gov (U.S. Department of Energy (DOE))

Workshop summary report from the Flow Cell Workshop held March 7-8, 2012, in Washington, D.C., to investigate how a redow flow cell (RFC) can be a grid-scale electricalenergy-storage system and the associated technological needs. The specific objectives of the workshop were to understand the needs for applied research in RFCs; identify the grand challenges and prioritize R&D needs; and gather input for future development of roadmaps and technical targets for RFCs for various applications.

85

Energy-Density Enhancement of Carbon-Nanotube-Based Supercapacitors with Redox Couple in Organic Electrolyte  

Science Journals Connector (OSTI)

Energy-Density Enhancement of Carbon-Nanotube-Based Supercapacitors with Redox Couple in Organic Electrolyte ... The redox molecule also contributes to increasing the cell capacitance by a faradaic redox reaction, and therefore the energy density of the supercapacitor can be significantly increased. ... More specifically, the addition of redox-active decamethylferrocene in an organic electrolyte results in an approximately 27-fold increase in the energy density of carbon-nanotube-based supercapacitors. ...

Jinwoo Park; Byungwoo Kim; Young-Eun Yoo; Haegeun Chung; Woong Kim

2014-11-16T23:59:59.000Z

86

Fuel cell with interdigitated porous flow-field  

DOE Patents (OSTI)

A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers. 9 figs.

Wilson, M.S.

1997-06-24T23:59:59.000Z

87

Fuel cell with interdigitated porous flow-field  

DOE Patents (OSTI)

A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers.

Wilson, Mahlon S. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

88

MODELING THE EFFECT OF FLOW FIELD DESIGN ON PEM FUEL CELL PERFORMANCE  

E-Print Network (OSTI)

MODELING THE EFFECT OF FLOW FIELD DESIGN ON PEM FUEL CELL PERFORMANCE Jeffrey Glandt, Sirivatch University of South Carolina Columbia, SC 29208 vanzee@engr.sc.edu Key words: PEM fuel cell, flow field or printed in its publications. #12;2 MODELING THE EFFECT OF FLOW FIELD DESIGN ON PEM FUEL CELL PERFORMANCE

Van Zee, John W.

89

Identifying the Active Site in Nitrogen-Doped Graphene for the VO2+/VO2+ Redox Reaction  

Science Journals Connector (OSTI)

Nitrogen-doped graphene sheets (NGS), synthesized by annealing graphite oxide (GO) with urea at 7001050 C, were studied as positive electrodes in a vanadium redox flow battery. ... graphene sheets; nitrogen doping; [VO]2+/[VO2]+ couple reaction; redox flow battery ... (7) Among these energy storage technologies, the vanadium redox flow battery (VRFB) has been considered as a competitive and promising grid energy storage system for renewable energy due to its low cost, high efficiency, and good cycling stability. ...

Jutao Jin; Xiaogang Fu; Qiao Liu; Yanru Liu; Zhiyang Wei; Kexing Niu; Junyan Zhang

2013-05-06T23:59:59.000Z

90

Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel  

E-Print Network (OSTI)

Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller Bachelors of Engineering, University in a polymer electrolyte fuel cell is a critical issue in ensuring high cell performance. The water production

Victoria, University of

91

ESS 2012 Peer Review - Painesville Municipal Electric Power Vanadium Redox Battery Demo Project - Jodi Startari, Ashlawn Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electric Power Electric Power Vanadium Redox Battery Demonstration Project Jodi Startari Ashlawn Energy LLC Briefing Overview * Painesville Municipal Electric Power Plant Project Synopsis * Vanadium Redox Flow Battery Technology * City of Painesville Municipal Electric Plant History * Project Multiple Objectives and Additional Detail * Project Risk Analysis presented at previous Peer Review * Project to date progress * Cost Distribution * Summary/Conclusions * Future Tasks * Questions US Produced Vanadium Redox Flow Battery for Bulk Storage, Peak Shaving * 8 MW Hour redox flow battery (1MW 8 hours) * To be installed at Painesville Municipal Electric Plant (PMEP), a 32 MW coal fired facility * Most efficient PMEP operation is steady state at 26 MW (lowest emissions, lowest operating cost)

92

The flow of red blood cells through a narrow spleen-like slit Jonathan B. Freund  

E-Print Network (OSTI)

The flow of red blood cells through a narrow spleen-like slit Jonathan B. Freund Citation: Phys OF FLUIDS 25, 110807 (2013) The flow of red blood cells through a narrow spleen-like slit Jonathan B are perhaps the smallest blood passages in the body, and red blood cells must deform significantly to pass

Freund, Jonathan B.

93

Electrochimica Acta 50 (2005) 53905398 Membraneless laminar flow-based micro fuel cells operating in alkaline,  

E-Print Network (OSTI)

Electrochimica Acta 50 (2005) 5390­5398 Membraneless laminar flow-based micro fuel cells operating) in membraneless, laminar flow-based micro fuel cells (LF-FCs) eliminates several PEM-related issues such as fuel the anode is in acidic media while the cathode is in alkali, or vice versa. Operating a fuel cell under

Kenis, Paul J. A.

94

Upgrading the Vanadium Redox Battery | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Upgrading the Vanadium Redox Battery Upgrading the Vanadium Redox Battery New electrolyte mix increases energy storage by 70 percent After developing a more effective...

95

An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions  

Open Energy Info (EERE)

Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Details Activities (0) Areas (0) Regions (0) Abstract: Reactive chemical transport occurs in a variety of geochemical environments, and over a broad range of space and time scales. Efficiency of the chemical speciation and water-rock-gas interaction calculations is important for modeling field-scale multidimensional reactive transport problems. An improved efficient model, REACT, for simulating water-rock-gas interaction under equilibrium and kinetic conditions, has been developed.

96

Renaissance in Flow-Cell Technologies: Recent Advancements and Future Opportunities  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Mike Perry, United Technologies Research Center, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

97

A NEW PEMFC FLOW FIELD PLATE OPTIMIZATION COMPARISON - ANSYS FLUENT FUEL-CELL SIMULATION.  

E-Print Network (OSTI)

??The performance of a new cathode flow field plate located on a PEM fuel cell was compared to an industry standard and optimal serpentine design (more)

Soueidan, Ahmed Yassin

2012-01-01T23:59:59.000Z

98

Natural Convection in a Horizontal Non-Flow-Through Reverse-Osmosis Cell  

Science Journals Connector (OSTI)

Features of the mass transfer in a horizontal non-flow-through reverse-osmosis cell are considered. It is concluded that...

N. B. Kirichenko

99

Humidity, Pressure, and Temperature Measurements in an Interdigitated-Flow PEM Hydrogen Fuel Cell  

Science Journals Connector (OSTI)

In situ measurements of humidity, temperature, and pressure are demonstrated for a polymer electrolyte membrane (PEM) fuel cell of interdigitated gas flow channel layout. Sensors are embedded at ...

S. Bell; G. Hinds; M. de Podesta; M. Stevens

2012-09-01T23:59:59.000Z

100

Original article Normal and sickle red blood cell dynamics under venular flow  

E-Print Network (OSTI)

1 Original article Normal and sickle red blood cell dynamics under venular flow C. Allayousa , A these notions are found in sickle cell disease where sickle red blood cells become more rigid, leading. Thus, normal and sickle red blood cells are classified into different sub-groups, showing

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Journal of Power Sources 128 (2004) 5460 Microfluidic fuel cell based on laminar flow  

E-Print Network (OSTI)

Journal of Power Sources 128 (2004) 54­60 Microfluidic fuel cell based on laminar flow Eric R a novel microfluidic fuel cell concept that utilizes the occurrence of multi-stream laminar flow of a Y-shaped microfluidic channel in which two liquid streams containing fuel and oxidant merge

Kenis, Paul J. A.

102

Double-band Electrode Channel Flow DEMS Cell > Research Highlights...  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance Alkaline Fuel Cell Membranes Improving Fuel Cell...

103

Redox shuttles for lithium ion batteries  

DOE Patents (OSTI)

Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.

Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

2014-11-04T23:59:59.000Z

104

A Lattice Boltzmann Fictitious Domain Method for Modeling Red Blood Cell Deformation and Multiple-Cell Hydrodynamic Interactions in Flow  

SciTech Connect

To model red blood cell (RBC) deformation in flow, the recently developed LBM-DLM/FD method ([Shi and Lim, 2007)29], derived from the lattice Boltzmann method and the distributed Lagrange multiplier/fictitious domain methodthe fictitious domain method, is extended to employ the mesoscopic network model for simulations of red blood cell deformation. The flow is simulated by the lattice Boltzmann method with an external force, while the network model is used for modeling red blood cell deformation and the fluid-RBC interaction is enforced by the Lagrange multiplier. To validate parameters of the RBC network model, sThe stretching numerical tests on both coarse and fine meshes are performed and compared with the corresponding experimental data to validate the parameters of the RBC network model. In addition, RBC deformation in pipe flow and in shear flow is simulated, revealing the capacity of the current method for modeling RBC deformation in various flows.

Shi, Xing; Lin, Guang; Zou, Jianfeng; Fedosov, Dmitry A.

2013-07-20T23:59:59.000Z

105

Modeling the influence of optic flow on grid cell firing in the absence of other cues1  

E-Print Network (OSTI)

Modeling the influence of optic flow on grid cell firing in the absence of other cues1 Florian affect the firing of grid cells recorded in entorhinal cortex of rats. Optic flow provides information and superimposed with noise in order to model the optic flow that would be available to the rat. This optic flow

Hasselmo, Michael

106

The backflow cell model of steady state flow reactors with axial dispersion  

E-Print Network (OSTI)

THE BACKFLOW CELL MODEL OF STEADY STATE FLOW REACTORS WITH AXIAL DISPERSION A Thesis By John Thomas Baldwin Submitted to the Graduate College of the Texas A/M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 1966 Major Subject;. Chemical Engineering THE BACKFLOW CELL MODEL OF STEADY STATE FLOW REACTORS WITH AXIAL DISPERSION A Thesis By John Thomas Baldwin Approved as to style and content by: C airman o ommittee ea o epartment (Member...

Baldwin, John Thomas

2012-06-07T23:59:59.000Z

107

Constructal flow structure for a PEM fuel cell J.V.C. Vargas a,*, J.C. Ordonez b  

E-Print Network (OSTI)

Constructal flow structure for a PEM fuel cell J.V.C. Vargas a,*, J.C. Ordonez b , A. Bejan c the internal structure (relative sizes, spacings) and external shape (aspect ratios) of a unit PEM fuel cell so) level of a fuel cell stack, i.e., the unit PEM fuel cell, which is modeled as a unidirectional flow

Ordonez, Juan C.

108

Cell cycle parameters of slowly growing Escherichia coli B/r studied by flow cytometry.  

Science Journals Connector (OSTI)

...A cells, the average rate of mass increase was 11...for B/r K cells the rate of mass increase was twice...and Department ofMedical Physics, The Norwegian Radium...with a decreasing growth rate and that the B period...laminar flow of water, pass one by one through the...

K Skarstad; H B Steen; E Boye

1983-05-01T23:59:59.000Z

109

Electro-osmotic flow control for living cell analysis in microfluidic Tomasz Glawdel, Carolyn L. Ren *  

E-Print Network (OSTI)

the problems associated with the use of high electric fields required for operating electro-osmotic pumps in living cell analysis. In particular, electroporation of cell mem- branes, Joule heating, electrolysis pressure-driven flow control systems. Futai et al. (2006) developed a recircu- lating perfusion platform

Le Roy, Robert J.

110

DETECTION OF EQUATORWARD MERIDIONAL FLOW AND EVIDENCE OF DOUBLE-CELL MERIDIONAL CIRCULATION INSIDE THE SUN  

SciTech Connect

Meridional flow in the solar interior plays an important role in redistributing angular momentum and transporting magnetic flux inside the Sun. Although it has long been recognized that the meridional flow is predominantly poleward at the Sun's surface and in its shallow interior, the location of the equatorward return flow and the meridional flow profile in the deeper interior remain unclear. Using the first 2 yr of continuous helioseismology observations from the Solar Dynamics Observatory/Helioseismic Magnetic Imager, we analyze travel times of acoustic waves that propagate through different depths of the solar interior carrying information about the solar interior dynamics. After removing a systematic center-to-limb effect in the helioseismic measurements and performing inversions for flow speed, we find that the poleward meridional flow of a speed of 15 m s{sup -1} extends in depth from the photosphere to about 0.91 R{sub Sun }. An equatorward flow of a speed of 10 m s{sup -1} is found between 0.82 and 0.91 R{sub Sun} in the middle of the convection zone. Our analysis also shows evidence of that the meridional flow turns poleward again below 0.82 R{sub Sun }, indicating an existence of a second meridional circulation cell below the shallower one. This double-cell meridional circulation profile with an equatorward flow shallower than previously thought suggests a rethinking of how magnetic field is generated and redistributed inside the Sun.

Zhao Junwei; Bogart, R. S.; Kosovichev, A. G.; Hartlep, Thomas [W. W. Hansen Experimental Physics Laboratory, Stanford University, Stanford, CA 94305-4085 (United States); Duvall, T. L. Jr. [Solar Physics Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2013-09-10T23:59:59.000Z

111

Redox Properties of Structural Fe in Clay Minerals. 1. Electrochemical Quantification of Electron-Donating and -Accepting Capacities of Smectites  

Science Journals Connector (OSTI)

The Fe2+/Fe3+ redox couple is an important redox buffer in the environment that affects biogeochemical element and nutrient cycling and controls the partitioning and redox transformations of organic and inorganic contaminants. ... (14-18) These changes can alter the fate and (bio)availability of redox-inactive contaminants and nutrients (e.g., K+, Ca2+)(18) as well as dictate the viability of clay minerals in engineered systems (e.g., clay mineral backfill in radioactive waste repositories). ... In this approach, an electrochemical cell containing a pH-buffered solution is set to a constant EH-value while the current is measured over time. ...

Christopher A. Gorski; Michael Aeschbacher; Daniela Soltermann; Andreas Voegelin; Bart Baeyens; Maria Marques Fernandes; Thomas B. Hofstetter; Michael Sander

2012-07-24T23:59:59.000Z

112

Manufacturing all-polymer laminar flow-based fuel cells A.S. Hollinger, P.J.A. Kenis*  

E-Print Network (OSTI)

Manufacturing all-polymer laminar flow-based fuel cells A.S. Hollinger, P.J.A. Kenis* Department laminar flow fuel cell. Bonding strategy eliminates the need for heavy metal plates and clamping. Developed a strategy to encapsulate fuel cell electrodes in Kapton windows. Designs can be scaled

Kenis, Paul J. A.

113

Development of a cell-based stream flow routing model  

E-Print Network (OSTI)

al. (1994) developed a 2.00x2.50 resolution river routing model for a number of World Rivers, coupled with an atmospheric-ocean model. The GCM of NASA/Goddard Institute for Space Studies (GISS) (Hansen et al., 1983) was used to calculate the runoff... resolution of 2.00 X 2.50 using the coarse river network developed by Miller et al. (1994). Input to each of the grid cell was derived from the improved GISS GCM (Hansen et al., 1983), which improved the model prediction of discharge. Costa and Foley (1997...

Raina, Rajeev

2005-08-29T23:59:59.000Z

114

Growth of Myxococcus xanthus in Continuous-Flow-Cell Bioreactors as a Method for Studying Development  

Science Journals Connector (OSTI)

...single-chamber flow cell was approximately 7.5 ml. Design files were generated using the computer-aided design program AutoCAD (Autodesk Inc., San Rafael, CA) and are available at http://microbiology.ucdavis.edu/singer/ for immediate download and...

Gregory T. Smaldone; Yujie Jin; Damion L. Whitfield; Andrew Y. Mu; Edward C. Wong; Stefan Wuertz; Mitchell Singer

2014-02-07T23:59:59.000Z

115

Highly conductive composites for fuel cell flow field plates and bipolar plates  

DOE Patents (OSTI)

This invention provides a fuel cell flow field plate or bipolar plate having flow channels on faces of the plate, comprising an electrically conductive polymer composite. The composite is composed of (A) at least 50% by weight of a conductive filler, comprising at least 5% by weight reinforcement fibers, expanded graphite platelets, graphitic nano-fibers, and/or carbon nano-tubes; (B) polymer matrix material at 1 to 49.9% by weight; and (C) a polymer binder at 0.1 to 10% by weight; wherein the sum of the conductive filler weight %, polymer matrix weight % and polymer binder weight % equals 100% and the bulk electrical conductivity of the flow field or bipolar plate is at least 100 S/cm. The invention also provides a continuous process for cost-effective mass production of the conductive composite-based flow field or bipolar plate.

Jang, Bor Z; Zhamu, Aruna; Song, Lulu

2014-10-21T23:59:59.000Z

116

Efficient Solar Energy Storage Using A TiO2/WO3 Tandem Photoelectrode in An All-vanadium Photoelectrochemical Cell  

Science Journals Connector (OSTI)

Abstract Using a photoelectrochemical (PEC) cell to convert solar energy to either electricity or chemical fuels has attracted much attention in the last four decades. However, two major obstacles that hinder wide-spread application of this approach lie in the relatively wide bandgap of chemically stable semiconducotrs, e.g., TiO2, and the rapid recombination of photogenerated charge carriers once they are generated within the semiconductors. We reported herein a method that utilized vanadium redox pairs, which are commonly used in vanadium redox-flow batteries (VRB), to mitigate charge carrier recombination and thus to improve photoresponse in regenerative solar energy storage for the first time. The results showed significant improvement in photocurrent during photo-charging of the all-vanadium PEC storage cell with the addition of a very low morlarity of vanadium redox species (0.01M) to the acid electrolytes. Additonally, the photocurrent was almost doubled even with a TiO2 electrode when two vanadium redox species were used in a full-cell configuration instead of a half-cell setup. To further enhance the light absorption, a TiO2/WO3 tandem electrode was studied and compared to the TiO2 electrode in various vanadium redox electrolytes. The tandem electrode showed higher photoresponse in all electrolytes investigated. Furthermore, the important role of vanadium redox species and WO3 have been discussed.

Dong Liu; Zi Wei; Chia-jen Hsu; Yi Shen; Fuqiang Liu

2014-01-01T23:59:59.000Z

117

Figure 1. Photolithography techniques are used to create microfluidic flow cells where biofouling can be studied for  

E-Print Network (OSTI)

Figure 1. Photolithography techniques are used to create microfluidic flow cells where biofouling and construct microfluidic flow cells for real-time observation of bacterial attachment and biofouling. He microfluidic devices, and computer multiphysics simulation with COMSOL. The student will also learn to work

Shor, Leslie McCabe

118

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared...  

NLE Websites -- All DOE Office Websites (Extended Search)

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft Landing. Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft...

119

Water management studies in PEM fuel cells, Part II: Ex situ investigation of flow maldistribution, pressure drop  

E-Print Network (OSTI)

by externally humidified air and hydrogen gas streams, must be present within the fuel cell to maintain 4 5 6 #12;a fuel cell blocks gas transport pathways in the catalyst layers, gas diffusion layersWater management studies in PEM fuel cells, Part II: Ex situ investigation of flow maldistribution

Kandlikar, Satish

120

An Inertial Cell Model for the Drag Force in Multi-phase Flow  

E-Print Network (OSTI)

A new model for the drag coefficient of a sphere in a concentrated system is described. It is based upon a cell-averaged model for the Stokes regime combined with a physically motivated extrapolation to arbitrary Reynolds number. It can be used as an alternative to the isolated particle drag coefficient in Euler-Lagrange modelling of solid-liquid multi-phase flow.The corresponding drag force also provides a dynamic bed equation for use in Euler-Euler modelling.

Tupper, Gary; Mainza, Aubrey

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

A microfluidics-based technique for automated and rapid labeling of cells for flow cytometry  

Science Journals Connector (OSTI)

Flow cytometry is a powerful technique capable of simultaneous multi-parametric analysis of heterogeneous cell populations for research and clinical applications. In recent years, the flow cytometer has been miniaturized and made portable for application in clinical- and resource-limited settings. The sample preparation procedure, i.e. labeling of cells with antibodies conjugated to fluorescent labels, is a time consuming (~45min) and labor-intensive procedure. Microfluidics provides enabling technologies to accomplish rapid and automated sample preparation. Using an integrated microfluidic device consisting of a labeling and washing module, we demonstrate a new protocol that can eliminate sample handling and accomplish sample and reagent metering, high-efficiency mixing, labeling and washing in rapid automated fashion. The labeling module consists of a long microfluidic channel with an integrated chaotic mixer. Samples and reagents are precisely metered into this device to accomplish rapid and high-efficiency mixing. The mixed sample and reagents are collected in a holding syringe and held for up to 8min following which the mixture is introduced into an inertial washing module to obtain 'analysis-ready' samples. The washing module consists of a high aspect ratio channel capable of focusing cells to equilibrium positions close to the channel walls. By introducing the cells and labeling reagents in a narrow stream at the center of the channel flanked on both sides by a wash buffer, the elution of cells into the wash buffer away from the free unbound antibodies is accomplished. After initial calibration experiments to determine appropriate 'holding time' to allow antibody binding, both modules were used in conjunction to label MOLT-3 cells (T lymphoblast cell line) with three different antibodies simultaneously. Results confirm no significant difference in mean fluorescence intensity values for all three antibodies labels (p

Phani K Patibandla; Rosendo Estrada; Manasaa Kannan; Palaniappan Sethu

2014-01-01T23:59:59.000Z

122

Flow distribution analyzing for the solid oxide fuel cell short stacks with rectangular and discrete cylindrical rib configurations  

Science Journals Connector (OSTI)

Abstract The commercial software Ansys is utilized to simulate and compare the fuel and air flow distribution characteristics within the specific 10-cell solid oxide fuel cell (SOFC) stacks with different rib configurations, such as the rectangular, discrete symmetric cylindrical and staggered cylindrical rib configurations, respectively. The stack flow uniformity index and the standard flow deviation index are used to properly represent the flow distribution qualities among the piled cell units at stack level and among the rib channels within each cell unit, respectively. Part of the result shows that for a 10-cell short stack, the influences of different rib configurations on the flow uniformity at stack level are negligible, which further approves that a short modular stack as 10-cells is a proper choice in establishing the large power supplied SOFC system. A typical 10-cell modular SOFC using the rectangular rib configuration to establish the fuel rib channels and using the discrete symmetric cylindrical rib configuration to construct the air rib channels is concluded to be proper designing in achieving a good stack performance, while carefully considers the produced current collecting, flow distribution over the electrode surface and the reaction species transporting within the composite electrode.

Shichuan Su; Huanhuan He; Daifen Chen; Wei Zhu; Yunxiong Wu; Wei Kong; Bo Wang; Liu Lu

2015-01-01T23:59:59.000Z

123

Dynamic states of cells adhering in shear flow: from slipping to rolling  

E-Print Network (OSTI)

Motivated by rolling adhesion of white blood cells in the vasculature, we study how cells move in linear shear flow above a wall to which they can adhere via specific receptor-ligand bonds. Our computer simulations are based on a Langevin equation accounting for hydrodynamic interactions, thermal fluctuations and adhesive interactions. In contrast to earlier approaches, our model not only includes stochastic rules for the formation and rupture of bonds, but also fully resolves both receptor and ligand positions. We identify five different dynamic states of motion in regard to the translational and angular velocities of the cell. The transitions between the different states are mapped out in a dynamic state diagram as a function of the rates for bond formation and rupture. For example, as the cell starts to adhere under the action of bonds, its translational and angular velocities become synchronized and the dynamic state changes from slipping to rolling. We also investigate the effect of non-molecular parameters. In particular, we find that an increase in viscosity of the medium leads to a characteristic expansion of the region of stable rolling to the expense of the region of firm adhesion, but not to the expense of the regions of free or transient motion. Our results can be used in an inverse approach to determine single bond parameters from flow chamber data on rolling adhesion.

C. B. Korn; U. S. Schwarz

2007-11-14T23:59:59.000Z

124

The plasma protein fibrinogen stabilizes clusters of red blood cells in microcapillary flows  

E-Print Network (OSTI)

The supply of oxygen and nutrients and the disposal of metabolic waste in the organs depend strongly on how blood, especially red blood cells, flow through the microvascular network. Macromolecular plasma proteins such as fibrinogen cause red blood cells to form large aggregates, called rouleaux, which are usually assumed to be disaggregated in the circulation due to the shear forces present in bulk flow. This leads to the assumption that rouleaux formation is only relevant in the venule network and in arterioles at low shear rates or stasis. Thanks to an excellent agreement between combined experimental and numerical approaches, we show that despite the large shear rates present in microcapillaries, the presence of either fibrinogen or the synthetic polymer dextran leads to an enhanced formation of robust clusters of red blood cells, even at haematocrits as low as 1%. Robust aggregates are shown to exist in microcapillaries even for fibrinogen concentrations within the healthy physiological range. These persistent aggregates should strongly affect cell distribution and blood perfusion in the microvasculature, with putative implications for blood disorders even within apparently asymptomatic subjects.

M. Brust; O. Aouane; M. Thiebaud; D. Flormann; C. Verdier; L. Kaestner; M. W. Laschke; H. Selmi; A. Benyoussef; T. Podgorski; G. Coupier; C. Misbah; C. Wagner

2014-02-25T23:59:59.000Z

125

Multireflection flow-cooling cell for IR spectroscopy of supercooled gases  

SciTech Connect

For the simplification of molecular spectra and for the increase of spectral line intensity the enclosive-flow cooling technique was developed. The vertical cell arrangement needs only one warm window and proved to be robust and easy to handle. Compared with supersonic jet cooling, the present method provides an absorption efficiency higher by several orders of magnitude. In this paper, an improved flow cooling cell including a multireflection optics is described. Compared to the prototype cell, the multireflection cell has only 50% of the mass. Optical paths up to 20 m for FTIR applications and up to 40 m for TDLAS applications can be chosen. The pressure range extends from below 0.001 mbar up to 3 bar. The temperature is adjustable from 65 to 350 K. The new cooling technique offers promising applications in trace gas analysis, in the generation and spectroscopy of molecular clusters, especially of water, and in the simulation of the conditions and processes that occur in the atmosphere of the Earth and other planets.

Bauerecker, S.; Taucher, F.; Weitkamp, C. [GKSS Forschungszentrum Geesthacht GmbH (Germany). Inst. fuer Physikalische und Chemische Analytik; Cammenga, H.K. [TU Braunschweig (Germany). Inst. fuer Physikalische und Theoretische Chemie

1996-12-31T23:59:59.000Z

126

To be published in IEEE Aerospace Conference Proceedings, 2003, Cat No. 0-7803-7651-X/03/$17.00 2003 IEEE Planar REDOX and Conductivity Sensors  

E-Print Network (OSTI)

/$17.00 © 2003 IEEE Planar REDOX and Conductivity Sensors for ISS Water Quality Measurements1 Martin G. Buehler REDOX and conductivity sensors that are used to detect ionic species in solution by measuring the electrochemical cell current as the voltage is scanned. The simplicity and robustness of these sensors allows

Kounaves, Samuel P.

127

characterization and visualization of two-phase flow properties of gas diffusion layers used in a PEM fuel cell  

E-Print Network (OSTI)

Due to the low-temperature operation of Polymer Electrolyte Membrane fuel cell (PEMFC), liquid water can build up in either flow channels or gas diffusion layers (GDL). Better understanding of the effect of two-phase ...

Gao, Yan

2011-04-26T23:59:59.000Z

128

Effects of geometry/dimensions of gas flow channels and operating conditions on high-temperature PEM fuel cells  

Science Journals Connector (OSTI)

In order to accomplish the objective of studying and optimizing the flow channel geometries and dimensions for high-temperature proton-exchange-membrane (PEM) fuel cells (with operating temperatures above 120C)...

Hong Liu; Peiwen Li; Alexandra Hartz

2014-11-01T23:59:59.000Z

129

Nucleic Acid Content and Nuclear Chromatin Structure of Human Bladder Cell Culture Lines as Studied by Flow Cytofluorometry  

Science Journals Connector (OSTI)

...characterizing tissue culture cell lines, as we have done home,and perhaps in distinguishing benign and malignant epithelial...Sharpless, T., and Darzynkiewicz, z. Urinary Cytology Automation. Preliminary Studies with Acridine Orange Stain and Flow-Through...

Myron R. Melamed; Zbigniew Darzynkiewicz; Frank Traganos; and Thomas K. Sharpless

1977-04-01T23:59:59.000Z

130

Fuel Cell Manufacturing Diagnostic Techniques: IR Thermography with Reactive Flow through Excitation  

SciTech Connect

While design and material considerations for PEMFCs have a large impact on cost, it is also necessary to consider a transition to high volume production of fuel cell systems, including MEA components, to enable economies of scale and reduce per unit cost. One of the critical manufacturing tasks is developing and deploying techniques to provide in?process measurement of fuel cell components for quality control. This effort requires a subsidiary task: The study of the effect of manufacturing defects on performance and durability with the objective to establish validated manufacturing tolerances for fuel cell components. This work focuses on the development of a potential quality control method for gas diffusion electrodes (GDEs). The method consists of infrared (IR) thermography combined with reactive flow through (RFT) excitation. Detection of catalyst loading reduction defects in GDE catalyst layers will be presented.

Manak, A. J.; Ulsh, M.; Bender, G.

2012-01-01T23:59:59.000Z

131

NOVEL COMPUTATIONAL SIMULATION OF REDOX REACTIONS WITHIN A METAL ELECTROSPRAY EMITTER  

SciTech Connect

To further both our fundamental understanding implications of the electrolytic nature of the electrospray and our understanding of the analytical ion source, in the context of electrospray mass spectrometry (ES-MS), a computational simulation of the oxidation of chemical species inside a metal emitter has been developed. The analysis code employs a boundary integral method for the solution of the Laplace equation for the electric potential and current, and incorporates standard activation and concentration polarization functions for the redox active species in the system to define the boundary conditions. The specific system modeled consisted of a 100 {mu}m i .d., inert metal capillary CHICN/H2O (90/10 V/V). ES emitter and a spray solution comprised of an analyte dissolved in Variable parameters included the concentration (i.e., 5, 10, 20, and 50 ~M) of the easily oxidized analyte ferrocene (Fe, dicyclopentadienyl iron) in the solution, and solution conductivities of 1.9, 3.8, and 7.6 x 107 Mho/cm. ES currents were on the order of 0.05 {mu}A and the flow rate was 5 @A_nin. Under these defined conditions, the two most prominent reactions at the emitter metakolution interface were assumed to be H20 oxidation (2H20 = 02 + 4H+ + 4e") and Fe oxidation (Fe = Fe' +e-). Using this model it was possible to predict the inter-facial potentials, as well as the current density for each of the reactions, as a function of axial position from the emitter spray tip back upstream, under the various operational conditions. Computational fluid dynamics (CFD) calculations showed that the imposed flow rate through the emitter was adequate to prevent significant back-diffusion of Fe+ into the emitter against the flow direction. The computational simulations predict the same behavior for the ES ion source as has been observed experimentally and is consistent with the controlled-current electrolytic cell analogy of Van Berkel and Zhou (Anal. Chem. 1995, 67,.2916-2923). Furthermore, the simulations demonstrate that the majority of the current involved in the redox reactions originated within a 200- 300 ~m region near the spray tip.

BULLOCK, J.S.IV; GILES, G.E.; GRAY, L.J.; VAN BERKEL, G.J.

1999-01-13T23:59:59.000Z

132

Air-Breathing Laminar Flow-Based Microfluidic Fuel Cell Ranga S. Jayashree, Lajos Gancs, Eric R. Choban,, Alex Primak, Dilip Natarajan,  

E-Print Network (OSTI)

Air-Breathing Laminar Flow-Based Microfluidic Fuel Cell Ranga S. Jayashree, Lajos Gancs, Eric R-based microfluidic fuel cell. Micro fuel cells have long been recognized as promising high energy density power,5 and microfluidic cells.6 Recent efforts have shown that the microfluidic transport phenomenon of laminar flow can

Kenis, Paul J. A.

133

MICROSCALE METABOLIC, REDOX AND ABIOTIC REACTIONS IN HANFORD 300 AREA SUBSURFACE SEDIMENTS  

SciTech Connect

The Hanford 300 Area is a unique site due to periodic hydrologic influence of river water resulting in changes in groundwater elevation and flow direction. This area is also highly subject to uranium remobilization, the source of which is currently believed to be the region at the base of the vadose zone that is subject to period saturation due to the changes in the water levels in the Columbia River. We found that microbial processes and redox and abiotic reactions which operate at the microscale were critical to understanding factors controlling the macroscopic fate and transport of contaminants in the subsurface. The combined laboratory and field research showed how microscale conditions control uranium mobility and how biotic, abiotic and redox reactions relate to each other. Our findings extended the current knowledge to examine U(VI) reduction and immobilization using natural 300 Area communities as well as selected model organisms on redox-sensitive and redox-insensitive minerals. Using innovative techniques developed specifically to probe biogeochemical processes at the microscale, our research expanded our current understanding of the roles played by mineral surfaces, bacterial competition, and local biotic, abiotic and redox reaction rates on the reduction and immobilization of uranium.

Beyenal, Haluk [WSU] [WSU; McLEan, Jeff [JCVI] [JCVI; Majors, Paul [PNNL] [PNNL; Fredrickson, Jim [PNNL] [PNNL

2013-11-14T23:59:59.000Z

134

ESS 2012 Peer Review - Flow Battery Membrane - David Ofer, Tiax  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Flow Battery Membrane Flow Battery Membrane Energy Storage Systems Program (ESS) Peer Review and Update Meeting 2012 Jack Treger treger.jack@tiaxllc.com Washington DC, September 27, 2012 Flow Battery Membrane Background and Purpose 1 Vanadium redox batteries (VRB) for energy storage require improved ion- selective membranes. * Vanadium permeation across current membranes leads to self-discharge and decreases cycling efficiency: - Negative half cell: V 2+ V 3+ + e - E o = -0.255V - Positive half cell: e - + VO 2 + + 2H + VO 2+ + H 2 O E o = 1.00V . * Current perfluorosulfonic acid polymer membranes are costly. * TIAX is developing a novel composite bipolar membrane: - Composite anionic membrane minimizes content of costly perfluorosulfonic acid polymer - Made bipolar by a cationic surface layer to improve selectivity for

135

Electrochemical characterization of a supercapacitor flow cell for power production from salinity gradients  

Science Journals Connector (OSTI)

Salinity gradients could be a great source of energy in the future. Capacitive energy extraction based on Donnan Potential (CDP) is a new technique to directly convert this energy into electricity. CDP uses a supercapacitor-like device combining ion exchange membranes and capacitive materials to adsorb and desorb ions with the Donnan Potential of the membranes as only driving force. The resulting current can be extracted through an external load. In this study, traditional electrochemical techniques: galvanostatic chargedischarge and cyclic voltammetry were used to investigate intrinsic properties of this open system. This study demonstrates the feasibility to characterize the capacitive behavior of the cell in low concentration (0.5M). Presence of membranes, as well as the possibility of having the electrolyte flowing through the cell was investigated. In the studied cell, the presence of membranes showed a limitation by the anion exchange membrane at low current densities but no effect at high current densities. The flow rate did not influence the capacitance of the system either.

Bruno B. Sales; Fei Liu; Olivier Schaetzle; Cees J.N. Buisman; Hubertus V.M. Hamelers

2012-01-01T23:59:59.000Z

136

Interpretation of kinetic rate data taken in a channel flow cell  

SciTech Connect

Nonuniform current distribution can complicate the interpretation of kinetic rate measurements. This paper shows explicitly how nonuniformities affect measurements in the flow-channel cell. Results are given for linear and Tafel kinetics and can be used to relate measurable electrochemical quantities to kinetic parameters. In addition to the appropriate polarization parameter, the interpretation of data requires knowledge of the ratio of the two characteristic lengths and the placement of the reference electrode. The analysis assumes that the ohmic potential drop is subtracted from the measurements by the interruption of current, and that concentration variations are negligible.

West, A.C.; Newman, J. (Materials and Chemical Sciences Div., Lawrence Berkeley Lab., and Dept. of Chemical Engineering, Univ. of California, Berkeley, CA (US))

1989-12-01T23:59:59.000Z

137

ET Kinetics of Bifunctional Redox Protein Maquettes  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetics of Bifunctional Redox Protein Maquettes Kinetics of Bifunctional Redox Protein Maquettes Mitchell W. Mutz, James F. Wishart and George L. McLendon Adv. Chem Ser. 254, Ch. 10, pp. 145-159 Abstract: We prepared three bifunctional redox protein maquettes based on 12-, 16-, and 20-mer three-helix bundles. In each case, the helix was capped with a Co(III) tris-bipyridyl electron acceptor and also functionalized with a C-terminal viologen (1-ethyl-1'-ethyl-4,4'-bipyridinium) donor. Electron transfer (ET) was initiated by pulse radiolysis and flash photolysis and followed spectrometrically to determined average, concentration-independent, first-order rates for the 16-mer and 20-mer maquettes. For the 16-mer bundle, the alpha-helical content was adjusted by the addition of urea or trifluoroethanol to solutions containing the metalloprotein. This

138

Prolonged effect of fluid flow stress on the proliferative activity of mesothelial cells after abrupt discontinuation of fluid streaming  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Late-onset peritoneal fibrosis leading to EPS remains to be elucidated. Black-Right-Pointing-Pointer Fluid streaming is a potent factor for peritoneal fibrosis in PD. Black-Right-Pointing-Pointer We focused on the prolonged effect of fluid streaming on mesothelial cell kinetics. Black-Right-Pointing-Pointer A history of fluid streaming exposure promoted mesothelial proliferative activity. Black-Right-Pointing-Pointer We have thus identified a potent new factor for late-onset peritoneal fibrosis. -- Abstract: Encapsulating peritoneal sclerosis (EPS) often develops after transfer to hemodialysis and transplantation. Both termination of peritoneal dialysis (PD) and transplantation-related factors are risks implicated in post-PD development of EPS, but the precise mechanism of this late-onset peritoneal fibrosis remains to be elucidated. We previously demonstrated that fluid flow stress induced mesothelial proliferation and epithelial-mesenchymal transition via mitogen-activated protein kinase (MAPK) signaling. Therefore, we speculated that the prolonged bioactive effect of fluid flow stress may affect mesothelial cell kinetics after cessation of fluid streaming. To investigate how long mesothelial cells stay under the bioactive effect brought on by fluid flow stress after removal of the stress, we initially cultured mesothelial cells under fluid flow stress and then cultured the cells under static conditions. Mesothelial cells exposed to fluid flow stress for a certain time showed significantly high proliferative activity compared with static conditions after stoppage of fluid streaming. The expression levels of protein phosphatase 2A, which dephosphorylates MAPK, in mesothelial cells changed with time and showed a biphasic pattern that was dependent on the duration of exposure to fluid flow stress. There were no differences in the fluid flow stress-related bioactive effects on mesothelial cells once a certain time had passed. The present findings show that fluid flow stress exerts a prolonged bioactive effect on mesothelial cells after termination of fluid streaming. These findings support the hypothesis that a history of PD for a certain period could serve as a trigger of EPS after stoppage of PD.

Aoki, Shigehisa, E-mail: aokis@cc.saga-u.ac.jp [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan)] [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan); Ikeda, Satoshi [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan)] [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan); Takezawa, Toshiaki [Transgenic Animal Research Center, National Institute of Agrobiological Sciences, Ibaraki (Japan)] [Transgenic Animal Research Center, National Institute of Agrobiological Sciences, Ibaraki (Japan); Kishi, Tomoya [Department of Internal Medicine, Saga University, Saga (Japan)] [Department of Internal Medicine, Saga University, Saga (Japan); Makino, Junichi [Makino Clinic, Saga (Japan)] [Makino Clinic, Saga (Japan); Uchihashi, Kazuyoshi; Matsunobu, Aki [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan)] [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan); Noguchi, Mitsuru [Department of Urology, Faculty of Medicine, Saga University, Saga (Japan)] [Department of Urology, Faculty of Medicine, Saga University, Saga (Japan); Sugihara, Hajime [Department of Physical Therapy, International University of Health and Welfare, Fukuoka (Japan)] [Department of Physical Therapy, International University of Health and Welfare, Fukuoka (Japan); Toda, Shuji [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan)] [Department of Pathology and Microbiology, Faculty of Medicine, Saga University, Saga (Japan)

2011-12-16T23:59:59.000Z

139

Computing Redox Potentials in Solution: Density Functional Theory as A Tool for Rational Design of Redox Agents  

E-Print Network (OSTI)

of Redox Agents Mu-Hyun Baik and Richard A. Friesner* Department of Chemistry and Center for Biomolecular in an industrial setting,8 lies in understanding and controlling the redox properties of the reactive species. Thus methods for predicting redox potentials in solution phase and give a systematic assessment of the required

Baik, Mu-Hyun

140

Influence of Solvent on Polymer Prequaternization toward Anion-Conductive Membrane Fabrication for All-Vanadium Flow Battery  

Science Journals Connector (OSTI)

Influence of Solvent on Polymer Prequaternization toward Anion-Conductive Membrane Fabrication for All-Vanadium Flow Battery ... The all-vanadium redox flow battery (VFB) can potentially circumvent the mismatch between the generation and end use of renewable but unsteady energies such as photovoltaics and wind turbines. ... 2.3 All-Vanadium Redox Flow Battery (VFB) Performance ...

Fengxiang Zhang; Huamin Zhang; Chao Qu

2012-07-09T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Integral manifolding structure for fuel cell core having parallel gas flow  

DOE Patents (OSTI)

Disclosed herein are manifolding means for directing the fuel and oxidant gases to parallel flow passageways in a fuel cell core. Each core passageway is defined by electrolyte and interconnect walls. Each electrolyte and interconnect wall consists respectively of anode and cathode materials layered on the opposite sides of electrolyte material, or on the opposite sides of interconnect material. A core wall projects beyond the open ends of the defined core passageways and is disposed approximately midway between and parallel to the adjacent overlaying and underlying interconnect walls to define manifold chambers therebetween on opposite sides of the wall. Each electrolyte wall defining the flow passageways is shaped to blend into and be connected to this wall in order to redirect the corresponding fuel and oxidant passageways to the respective manifold chambers either above or below this intermediate wall. Inlet and outlet connections are made to these separate manifold chambers respectively, for carrying the fuel and oxidant gases to the core, and for carrying their reaction products away from the core.

Herceg, Joseph E. (Naperville, IL)

1984-01-01T23:59:59.000Z

142

Integral manifolding structure for fuel cell core having parallel gas flow  

DOE Patents (OSTI)

Disclosed herein are manifolding means for directing the fuel and oxidant gases to parallel flow passageways in a fuel cell core. Each core passageway is defined by electrolyte and interconnect walls. Each electrolyte and interconnect wall consists respectively of anode and cathode materials layered on the opposite sides of electrolyte material, or on the opposite sides of interconnect material. A core wall projects beyond the open ends of the defined core passageways and is disposed approximately midway between and parallel to the adjacent overlaying and underlying interconnect walls to define manifold chambers therebetween on opposite sides of the wall. Each electrolyte wall defining the flow passageways is shaped to blend into and be connected to this wall in order to redirect the corresponding fuel and oxidant passageways to the respective manifold chambers either above or below this intermediate wall. Inlet and outlet connections are made to these separate manifold chambers respectively, for carrying the fuel and oxidant gases to the core, and for carrying their reaction products away from the core.

Herceg, J.E.

1983-10-12T23:59:59.000Z

143

Electrochemical photovoltaic cells. Project 65021 final technical progress report, April 15, 1979-April 17, 1980  

SciTech Connect

The overall goals of this program have been to experimentally identify semiconductor photoanode/redox couple systems that (a) show promise of meeting acceptable solar efficiencies using polycrystalline materials, and (b) have the potential for use in conjunction with a suitable cathode in which another redox species is available for reduction. Such an overall system allows for the convenient removal, storage, and later discharge of reaction products through the use of porous, flow-through redox electrodes. Increasing solar energy conversion efficiencies and identifying potentially long-life systems were emphasized. Semiconductor/redox couple systems were selected on the basis of the apparent positions of their conduction and valence band energy levels at the interface, together with the semiconductor decomposition potential. Selected redox couples should possess equilibrium potentials that lie negative of the semiconductor decomposition potential and positive of the semiconductor conduction band. Liquid-junction solar cells were characterized using n-MoSe/sub 2/, n-WSe/sub 2/, n-CdSe, and n-GaAs as photoanodes. Results are presented in detail. (WHK)

Ang, P.G.P.; Sammells, A.F.

1980-09-01T23:59:59.000Z

144

Fact Sheet: Vanadium Redox Flow Batteries (October 2012)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Breakthrough Breakthrough Researchers at Pacific Northwest National Laboratory have developed a new sulfate (SO 4 2- ) and chloride (Cl - ) mixed solution that is used as the electrolyte. Compared to pure sulfuric acid, the new solution can hold more than 70% more vanadium ions, increasing energy storage capacity by more than 70%. The use of Cl - in the new solution also increases the operating temperature window by 83%, so the battery

145

Effect of direct liquid water injection and interdigitated flow field on the performance of proton exchange membrane fuel cells  

E-Print Network (OSTI)

70-108B One Cyclotron Road Berkeley, California 94720 December 2, 1997 Key Words: Proton Exchange Membrane fuel cells, humidification, gas distribution, direct liquid water injection, interdigitated flow fields. * Corresponding... of the catalyst layers were made of waterproof, carbon fiber cloths. Liquid water was injected by two metering pumps into two heated stainless steel coils, where it was preheated to the cell operating temperatures, and then directly into the gas streams...

Wood, D. L.; Yi, Y. S.; Nguyen, Trung Van

1998-01-01T23:59:59.000Z

146

Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells  

SciTech Connect

Two-phase flow and transport of reactants and products in the air cathode of proton exchange membrane (PEM) fuel cells is studied analytically and numerically. Four regimes of water distribution and transport are classified by defining three threshold current densities and a maximum current density. They correspond to first appearance of liquid water at the membrane/cathode interface, extension of the gas-liquid two-phase zone to the cathode/channel interface, saturated moist air exiting the gas channel, and complete consumption of oxygen by the electrochemical reaction. When the cell operates above the first threshold current density, liquid water appears and a two-phase zone forms within the porous cathode. A two-phase, multi-component mixture model in conjunction with a finite-volume-based computational fluid dynamics (CFD) technique is applied to simulate the cathode operation in this regime. The model is able to handle the situation where a single-phase region co-exists with a two-phase zone in the air cathode. For the first time, the polarization curve as well as water and oxygen concentration distributions encompassing both single- and two-phase regimes of the air cathode are presented. Capillary action is found to be the dominant mechanism for water transport inside the two-phase zone. The liquid water saturation within the cathode is predicted to reach 6.3% at 1.4 A/cm{sup 2}.

WANG,Z.H.; WANG,C.Y.; CHEN,KEN S.

2000-03-20T23:59:59.000Z

147

Thin graphite bipolar plate with associated gaskets and carbon cloth flow-field for use in an ionomer membrane fuel cell  

DOE Patents (OSTI)

The present invention comprises a thin graphite plate with associated gaskets and pieces of carbon cloth that comprise a flow-field. The plate, gaskets and flow-field comprise a "plate and gasket assembly" for use in an ionomer membrane fuel cell, fuel cell stack or battery.

Marchetti, George A. (Western Springs, IL)

2003-01-03T23:59:59.000Z

148

Factors Controlling Redox Speciation of Plutonium and Neptunium in Extraction Separation Processes  

SciTech Connect

The objective of the project was to examine the factors controlling redox speciation of plutonium and neptunium in UREX+ extraction in terms of redox potentials, redox mechanism, kinetics and thermodynamics. Researchers employed redox-speciation extractions schemes in parallel to the spectroscopic experiments. The resulting distribution of redox species w studied uring spectroscopic, electrochemical, and spectro-electrochemical methods. This work reulted in collection of data on redox stability and distribution of redox couples in the nitric acid/nitrate electrolyte and the development of redox buffers to stabilize the desired oxidation state of separated radionuclides. The effects of temperature and concentrations on the redox behavior of neptunium were evaluated.

Paulenova, Alena [Principal Investigator; Vandegrift, III, George F. [Collaborator

2013-09-24T23:59:59.000Z

149

Simple and accurate correlation of experimental redox potentials...  

NLE Websites -- All DOE Office Websites (Extended Search)

redox potentials and DFT-calculated HOMOLUMO energies of polycyclic aromatic hydrocarbons Authors: Mndez-Hernndez, D.D,, Tarakeshwar, P., Gust, D,. Moore,T.A., Moore,...

150

Workshop on electrodes for flowing solution batteries. Summary report  

SciTech Connect

The electrochemical technology of aqueous secondary cells with flowing electrolyte solutions was the subject of a workshop sponsored by EPRI with the cooperation of DOE. The workshop was held in Tampa, Florida, 5-7 November 1979, and was attended by a select group drawn from advanced battery developers, government agencies, universities, and research organizations. The workshop general objectives were to look at the significant parameters believed to govern the performance of the two basic types of electrodes now in use; namely, a porous flow-through electrode (PFTE), and an impervious flow-by electrode. Progress, problems, and prospects were informally discussed. Brief critical reviews were given by session chairmen as a means of introducing each of the key topics (Current Distribution in FTPE, Conversion Efficiency, Segmented FTPE Studies, General Discussion on FTPF Parameters, Surface Activation, Application of FTPE to Waste Recovery, Exxon Zinc-Bromine Flow-By System, FTPE In NASA Redox Energy Storage, and Application of FTPE In Lockheed Zinc/Ferricyanide Redox System). The interaction of this diverse group of engineers and scientists was said by all to be of great benefit in widening understanding of the problems and possible future approaches to new work. The main needs for future work that were identified in the final discussion session among the participants were: (1) engineering analysis, (2) porous structures, (3) materials characteristics, and (4) chemical characteristics. In generally comparing flow-through to flow-by electrodes, there were some surprising differences arising from experimental results that did not fit conventional thinking.

Nanis, L.

1981-02-01T23:59:59.000Z

151

Modulation of ATP/ADP Concentration at the Endothelial Cell Surface by Flow: Effect of Cell Topography  

E-Print Network (OSTI)

Wall shear stress modulation of ATP/ADP concentration at theFlow modulation of agonist (ATP)-response (Ca 2+ ) couplingJ. Ando. Endogenously released ATP mediates shear stress-

Choi, Hyo Won; Barakat, Abdul I.

2009-01-01T23:59:59.000Z

152

Microstructure Change of SOFC Anode Caused by Electrochemical Redox Cycles  

E-Print Network (OSTI)

Microstructure Change of SOFC Anode Caused by Electrochemical Redox Cycles Norikazu Takagi@thtlab.t.u-tokyo.ac.jp Abstract During SOFC operation with typical Ni-YSZ anode, Ni is always subjected to the risk of oxidation the effect of redox cycles on anode performance has been intensively investigated, quantitative change

Kasagi, Nobuhide

153

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal  

E-Print Network (OSTI)

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal Interlinked Protein Folding.10.011 SUMMARY Disruption of protein folding in the endoplasmic reticulum (ER) causes unfolded proteins to accumu is active. Because ER redox po- tential is optimized for oxidative protein folding, we reasoned

Mullins, Dyche

154

E-Print Network 3.0 - altered redox homeostasis Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

redox cycling in hyper alkaline sediment-water systems. Ian Burke, Rob Mortimer and Doug Stewart (Civil Engineering) Summary: Biogeochemical redox cycling in hyper alkaline...

155

Membranes and separators for flowing electrolyte batteries-a review  

SciTech Connect

Flowing electrolyte batteries are rechargeable electrochemical storage devices in which externally stored electrolytes are circulated through the cell stack during charge or discharge. The potential advantages that flow batteries offer compared to other secondary batteries include: 1) ease of thermal and electrolyte management, 2) simple electrochemistry, 3) deep cycling capability, and 4) minimal loss of capacity with cycling. However, flow batteries are more complex than other secondary batteries and consequently may cost more and may be less reliable. Flow batteries are being developed for utility load leveling, electric vehicles, solar photovoltaic and wind turbine application. The status of flow batteries has recently been reviewed by Clark et al. The flowing electrolyte batteries place rigorous demands on the performance of separators and membranes. The operating characteristics of the iron/chromium redox battery were changed in order to accommodate the limitations in membrane performance. Low cost alternatives to the presently used membrane must be found before the zinc/ferricyanide battery can be economically feasible. The zinc/bromine battery's efficiency could be improved if a suitably selective membrane were available. It is anticipated that better and less costly membranes to meet these needs will be developed as more is learned about their preparation and performance.

Arnold, C.; Assink, R.A.

1983-01-01T23:59:59.000Z

156

Mixing Cell Model: A One-Dimensional Numerical Model for Assessment of Water Flow and Contaminant Transport in the Unsaturated Zone  

SciTech Connect

This report describes the Mixing Cell Model code, a one-dimensional model for water flow and solute transport in the unsaturated zone under steady-state or transient flow conditions. The model is based on the principles and assumptions underlying mixing cell model formulations. The unsaturated zone is discretized into a series of independent mixing cells. Each cell may have unique hydrologic, lithologic, and sorptive properties. Ordinary differential equations describe the material (water and solute) balance within each cell. Water flow equations are derived from the continuity equation assuming that unit-gradient conditions exist at all times in each cell. Pressure gradients are considered implicitly through model discretization. Unsaturated hydraulic conductivity and moisture contents are determined by the material-specific moisture characteristic curves. Solute transport processes include explicit treatment of advective processes, first-order chain decay, and linear sorption reactions. Dispersion is addressed through implicit and explicit dispersion. Implicit dispersion is an inherent feature of all mixing cell models and originates from the formulation of the problem in terms of mass balance around fully mixed volume elements. Expressions are provided that relate implicit dispersion to the physical dispersion of the system. Two FORTRAN codes were developed to solve the water flow and solute transport equations: (1) the Mixing-Cell Model for Flow (MCMF) solves transient water flow problems and (2) the Mixing Cell Model for Transport (MCMT) solves the solute transport problem. The transient water flow problem is typically solved first by estimating the water flux through each cell in the model domain as a function of time using the MCMF code. These data are stored in either ASCII or binary files that are later read by the solute transport code (MCMT). Code output includes solute pore water concentrations, water and solute inventories in each cell and at each specified output time, and water and solute fluxes through each cell and specified output time. Computer run times for coupled transient water flow and solute transport were typically several seconds on a 2 GHz Intel Pentium IV desktop computer. The model was benchmarked against analytical solutions and finite-element approximations to the partial differential equations (PDE) describing unsaturated flow and transport. Differences between the maximum solute flux estimated by the mixing-cell model and the PDE models were typically less than two percent.

A. S. Rood

2009-04-01T23:59:59.000Z

157

Mixing Cell Model: A One-Dimensional Numerical Model for Assessment of Water Flow and Contaminant Transport in the Unsaturated Zone  

SciTech Connect

This report describes the Mixing Cell Model code, a one-dimensional model for water flow and solute transport in the unsaturated zone under steady-state or transient flow conditions. The model is based on the principles and assumptions underlying mixing cell model formulations. The unsaturated zone is discretized into a series of independent mixing cells. Each cell may have unique hydrologic, lithologic, and sorptive properties. Ordinary differential equations describe the material (water and solute) balance within each cell. Water flow equations are derived from the continuity equation assuming that unit-gradient conditions exist at all times in each cell. Pressure gradients are considered implicitly through model discretization. Unsaturated hydraulic conductivity and moisture contents are determined by the material-specific moisture characteristic curves. Solute transport processes include explicit treatment of advective processes, first-order chain decay, and linear sorption reactions. Dispersion is addressed through implicit and explicit dispersion. Implicit dispersion is an inherent feature of all mixing cell models and originates from the formulation of the problem in terms of mass balance around fully mixed volume elements. Expressions are provided that relate implicit dispersion to the physical dispersion of the system. Two FORTRAN codes were developed to solve the water flow and solute transport equations: (1) the Mixing-Cell Model for Flow (MCMF) solves transient water flow problems and (2) the Mixing Cell Model for Transport (MCMT) solves the solute transport problem. The transient water flow problem is typically solved first by estimating the water flux through each cell in the model domain as a function of time using the MCMF code. These data are stored in either ASCII or binary files that are later read by the solute transport code (MCMT). Code output includes solute pore water concentrations, water and solute inventories in each cell and at each specified output time, and water and solute fluxes through each cell and specified output time. Computer run times for coupled transient water flow and solute transport were typically several seconds on a 2 GHz Intel Pentium IV desktop computer. The model was benchmarked against analytical solutions and finite-element approximations to the partial differential equations (PDE) describing unsaturated flow and transport. Differences between the maximum solute flux estimated by the mixing-cell model and the PDE models were typically less than two percent.

A. S. Rood

2010-10-01T23:59:59.000Z

158

Experimental and Modeling Studies of Two-Phase Flow in Porous Media and Its Effects on the Performance of a PEM Fuel Cell  

E-Print Network (OSTI)

An experimental investigation was conducted to study the two-phase flow properties of porous media used in proton exchange membrane (PEM) fuel cells. The liquid and gas phase relative permeability of porous media used in PEM fuel cells was measured...

Wang, Xuhai

2010-01-01T23:59:59.000Z

159

A Two Dimensional Model of a Direct Propane Fuel Cell with an Interdigitated Flow Field .  

E-Print Network (OSTI)

??Increasing environmental concerns as well as diminishing fossil fuel reserves call for a new generation of energy conversion technologies. Fuel cells, which convert the chemical (more)

Khakdaman, Hamidreza

2012-01-01T23:59:59.000Z

160

Lateral Current Density Variation in PEM Fuel Cells with Interdigitated Flow Fields.  

E-Print Network (OSTI)

??Proton exchange membrane (PEM) fuel cell is regarded as one of the most promising power systems for the future vehicles. When supplied with air and (more)

Luo, Song

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Iron Cycling and Redox Evolution in the Precambrian  

E-Print Network (OSTI)

Green, W.J. , 2002. Rare earth elements in the water columnVangaans, P. , 1988. Rare-Earth Element Distributions inRedox cycling of rare earth elements in the suboxic zone of

Planavsky, Noah John

2012-01-01T23:59:59.000Z

162

Redox Active Catalysts Utilizing Earth Abundant Metals | Center...  

NLE Websites -- All DOE Office Websites (Extended Search)

Redox Active Catalysts Utilizing Earth Abundant Metals 14 Mar 2014 Ryan Trovitch has recently joined the team of the BISfuel PIs. He is an Assistant Professor at the Department of...

163

A cell boundaryelement method for viscous laminar flow solutions  

Science Journals Connector (OSTI)

...Reynolds-number cases and they agree well with the patterns presented...figure 16. On the linear-log scale adopted in figure 16...carried out against a number of well-documented flow solutions...Huntsville, AL: University of Alabama Press. Peyret, R. & Taylor...

1999-01-01T23:59:59.000Z

164

Laminated exfoliated graphite composite-metal compositions for fuel cell flow field plate or bipolar plate applications  

DOE Patents (OSTI)

An electrically conductive laminate composition for fuel cell flow field plate or bipolar plate applications. The laminate composition comprises at least a thin metal sheet having two opposed exterior surfaces and a first exfoliated graphite composite sheet bonded to the first of the two exterior surfaces of the metal sheet wherein the exfoliated graphite composite sheet comprises: (a) expanded or exfoliated graphite and (b) a binder or matrix material to bond the expanded graphite for forming a cohered sheet, wherein the binder or matrix material is between 3% and 60% by weight based on the total weight of the first exfoliated graphite composite sheet. Preferably, the first exfoliated graphite composite sheet further comprises particles of non-expandable graphite or carbon in the amount of between 3% and 60% by weight based on the total weight of the non-expandable particles and the expanded graphite. Further preferably, the laminate comprises a second exfoliated graphite composite sheet bonded to the second surface of the metal sheet to form a three-layer laminate. Surface flow channels and other desired geometric features can be built onto the exterior surfaces of the laminate to form a flow field plate or bipolar plate. The resulting laminate has an exceptionally high thickness-direction conductivity and excellent resistance to gas permeation.

Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z

2014-05-20T23:59:59.000Z

165

Investigating Cell Adhesion via Parallel Disk Rotational Flow: A Biocompatibility Study  

E-Print Network (OSTI)

(methyl methacrylate) (PMMA), polycarbonate (PC), and on gold coated poly(vinylidene fluoride) (Au/PVDF). The critical shear stress for fibroblasts was the lowest for PC with 5.09 dynes/cm2 and highest for PMMA with 21.0 dynes/cm2. This four-fold difference is iv... mainly due to the chemical structure of PMMA which promotes higher cell adhesion when compared to PC. Neurons were cultured on poly-D-lysine coated glass to promote cell adhesion. The critical shear stress of neuron cells varied from 3.94 to 27...

Rocha, Aracely

2011-08-08T23:59:59.000Z

166

Hadley Cell Dynamics in a Primitive Equation Model. Part I: Axisymmetric Flow  

Science Journals Connector (OSTI)

A strategy is adopted that applies the mean meridional circulation (MMC) equation to two different steady states of a primitive equation model. This allows for the investigation of the mechanisms behind the sensitivity of the Hadley cell ...

Hyun-kyung Kim; Sukyoung Lee

2001-10-01T23:59:59.000Z

167

Hadley Cell Dynamics in a Primitive Equation Model. Part II: Nonaxisymmetric Flow  

Science Journals Connector (OSTI)

This paper investigates the effect of baroclinic eddies on the structure of the Hadley cell. Self-consistent calculations of both axisymmetric and nonaxisymmetric circulations allow an unambiguous estimate of baroclinic eddy effects on the ...

Hyun-kyung Kim; Sukyoung Lee

2001-10-01T23:59:59.000Z

168

Dye Regeneration Kinetics in Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

Nevertheless, the calculated diffusion limit provides a useful estimate of the maximum attainable regeneration rate. ... Design of Organic Dyes and Cobalt Polypyridine Redox Mediators for High-Efficiency Dye-Sensitized Solar Cells ... cells are discussed, considering the high photovoltaic efficiencies obtained for devices employing Ru bipyridyl sensitizer dyes in combination with iodide/tri-iodide based redox electrolytes. ...

Torben Daeneke; Attila J. Mozer; Yu Uemura; Satoshi Makuta; Monika Fekete; Yasuhiro Tachibana; Nagatoshi Koumura; Udo Bach; Leone Spiccia

2012-09-27T23:59:59.000Z

169

Numerical Analysis of Cell Deformation of Twophase Flow with Discontinuous Viscosity and Nonlinear Surface Tension  

E-Print Network (OSTI)

­linear Surface Tension Zhilin Li and Sharon Lubkin Center For Research in Scientific Computation & Department equations, cell deformation, non­linear surface tension, jump conditions, interface, discontinuous and non boundary separating two fluids that have equal or different viscosity and non­linear surface tension

170

Multiple Factors Affecting Cellular Redox Status and Energy Metabolism Modulate Hypoxia-Inducible Factor Prolyl Hydroxylase Activity In Vivo and In Vitro  

Science Journals Connector (OSTI)

...use of these cells allowed us to monitor GHO hydroxylation status without using proteasome inhibitors...found that MitoQ could not help us to distinguish between these...factors affecting cellular redox status and energy metabolism modulate hypoxia-inducible...

Yi Pan; Kyle D. Mansfield; Cara C. Bertozzi; Viktoriya Rudenko; Denise A. Chan; Amato J. Giaccia; M. Celeste Simon

2006-11-13T23:59:59.000Z

171

Redox reactions with empirical potentials: Atomistic battery discharge simulations  

E-Print Network (OSTI)

Batteries are pivotal components in overcoming some of today's greatest technological challenges. Yet to date there is no self-consistent atomistic description of a complete battery. We take first steps toward modeling of a battery as a whole microscopically. Our focus lies on phenomena occurring at the electrode-electrolyte interface which are not easily studied with other methods. We use the redox split-charge equilibration (redoxSQE) method that assigns a discrete ionization state to each atom. Along with exchanging partial charges across bonds, atoms can swap integer charges. With redoxSQE we study the discharge behavior of a nano-battery, and demonstrate that this reproduces the generic properties of a macroscopic battery qualitatively. Examples are the dependence of the battery's capacity on temperature and discharge rate, as well as performance degradation upon recharge.

Dapp, Wolf B

2013-01-01T23:59:59.000Z

172

A model for red blood cells in simulations of large-scale blood flows  

E-Print Network (OSTI)

Red blood cells (RBCs) are an essential component of blood. A method to include the particulate nature of blood is introduced here with the goal of studying circulation in large-scale realistic vessels. The method uses a combination of the Lattice Boltzmann method (LBM) to account for the plasma motion, and a modified Molecular Dynamics scheme for the cellular motion. Numerical results illustrate the quality of the model in reproducing known rheological properties of blood as much as revealing the effect of RBC structuring on the wall shear stress, with consequences on the development of cardiovascular diseases.

Simone Melchionna

2011-07-25T23:59:59.000Z

173

Tank Treading of Optically Trapped Red Blood Cells in Shear Flow Himanish Basu, Aditya K. Dharmadhikari, Jayashree A. Dharmadhikari, Shobhona Sharma,* and Deepak Mathur*  

E-Print Network (OSTI)

Tank Treading of Optically Trapped Red Blood Cells in Shear Flow Himanish Basu, Aditya K Research, Mumbai, India ABSTRACT Tank-treading (TT) motion is established in optically trapped, live red while undergoing tank-treading motion (13­17). In an RBC, the cytoskeleton and the plasma membrane form

Sharma, Shobhona

174

A Flow-Through High-Pressure Electrical Conductance Cell for Determining of Ion Association of Aqueous Electrolyte Solutions at High Temperature and Pressure  

SciTech Connect

A flow-through high-pressure electrical conductance cell was designed and constructed to measure limiting molar conductances and ion association constants of dilute aqueous solutions with high precision at high temperatures and pressures. The basic concept of the cell employs the principle developed at the University of Delaware in 1995, but overall targets higher temperatures (to 600 C) and pressures (to 300 MPa). At present the cell has been tested by measuring aqueous NaCl and LiOH solutions (10{sup {minus}3} to 10{sup {minus}5} mol.kg{sup {minus}1}) to 405 C and 33 MPa with good results.

Bianchi, H.; Ho, P.C.; Palmer, D.A.; Wood, R.H.

1999-09-12T23:59:59.000Z

175

Redox Properties of Cytochrome c Adsorbed on Self-Assembled Monolayers: A Probe for Protein  

E-Print Network (OSTI)

Redox Properties of Cytochrome c Adsorbed on Self-Assembled Monolayers: A Probe for Protein Received May 21, 2002 The redox behavior of cytochrome c (cyt c) adsorbed to gold electrodes modified) groups and from an aromatic thiol (6). The redox potentials of cyt c adsorbed on SAMs of 1 and 5

Prentiss, Mara

176

Redox Shuttle Additive, Wins 2014 R&D 100 Award  

Office of Energy Efficiency and Renewable Energy (EERE)

Sandia National Laboratory and the Argonne National Laboratory have developed a chemical solution, known as a redox shuttle additive, a chemical that prevents overcharging by electrochemically locking in a maximum voltage that is dependent on the chemical structure of the additive and the nature of the battery material.

177

Electrochemical biosensor based on immobilized enzymes and redox polymers  

DOE Patents (OSTI)

The present invention relates to an electrochemical enzyme biosensor for use in liquid mixtures of components for detecting the presence of, or measuring the amount of, one or more select components. The enzyme electrode of the present invention is comprised of an enzyme, an artificial redox compound covalently bound to a flexible polymer backbone and an electron collector.

Skotheim, Terje A. (Shoreham, NY); Okamoto, Yoshiyuki (Fort Lee, NJ); Hale, Paul D. (Northport, NY)

1992-01-01T23:59:59.000Z

178

Method of producing exfoliated graphite composite compositions for fuel cell flow field plates  

DOE Patents (OSTI)

A method of producing an electrically conductive composite composition, which is particularly useful for fuel cell bipolar plate applications. The method comprises: (a) providing a supply of expandable graphite powder; (b) providing a supply of a non-expandable powder component comprising a binder or matrix material; (c) blending the expandable graphite with the non-expandable powder component to form a powder mixture wherein the non-expandable powder component is in the amount of between 3% and 60% by weight based on the total weight of the powder mixture; (d) exposing the powder mixture to a temperature sufficient for exfoliating the expandable graphite to obtain a compressible mixture comprising expanded graphite worms and the non-expandable component; (e) compressing the compressible mixture at a pressure within the range of from about 5 psi to about 50,000 psi in predetermined directions into predetermined forms of cohered graphite composite compact; and (f) treating the so-formed cohered graphite composite to activate the binder or matrix material thereby promoting adhesion within the compact to produce the desired composite composition. Preferably, the non-expandable powder component further comprises an isotropy-promoting agent such as non-expandable graphite particles. Further preferably, step (e) comprises compressing the mixture in at least two directions. The method leads to composite plates with exceptionally high thickness-direction electrical conductivity.

Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z

2014-04-08T23:59:59.000Z

179

Redox-driven regulation of microbial community morphogenesis Chinweike Okegbe, Alexa Price-Whelan and Lars EP Dietrich  

E-Print Network (OSTI)

Redox-driven regulation of microbial community morphogenesis Chinweike Okegbe, Alexa Price that fuels life is derived from electron transfer (redox) reactions. Changes in electron availability alter- isms are also important during more subtle variations in redox potential. Redox balance -- the relative

Dietrich, Lars

180

Red blood cells and other non-spherical capsules in shear flow: oscillatory dynamics and the tank-treading-to-tumbling transition  

E-Print Network (OSTI)

We consider the motion of red blood cells and other non-spherical microcapsules dilutely suspended in a simple shear flow. Our analysis indicates that depending on the viscosity, membrane elasticity, geometry and shear rate, the particle exhibits either tumbling, tank-treading of the membrane about the viscous interior with periodic oscillations of the orientation angle, or intermittent behavior in which the two modes occur alternately. For red blood cells, we compute the complete phase diagram and identify a novel tank-treading-to-tumbling transition at low shear rates. Observations of such motions coupled with our theoretical framework may provide a sensitive means of assessing capsule properties.

J. M. Skotheim; T. W. Secomb

2006-05-26T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Influence of the operational parameters on the performance of polymer electrolyte membrane fuel cells with different flow fields  

Science Journals Connector (OSTI)

Before entering the cell, the reactant gases were humidified by passing through water contained in temperature-controlled metal bottles. The operational parameters of the cell,...22]. Except where indicated, the ...

A. de Souza; E. R. Gonzalez

2003-09-01T23:59:59.000Z

182

Ilmenite Activation during Consecutive Redox Cycles in Chemical-Looping Combustion  

Science Journals Connector (OSTI)

Ilmenite Activation during Consecutive Redox Cycles in Chemical-Looping Combustion ... Industrial & Engineering Chemistry Research2014 53 (42), 16341-16348 ...

Juan Adnez; Ana Cuadrat; Alberto Abad; Pilar Gayn; Luis F. de Diego; Francisco Garca-Labiano

2010-01-07T23:59:59.000Z

183

Flow-Through Microfluidic Device for High-Efficiency Transfection of Mammalian Cells through Combined Microelectroporation and Sonoporation  

E-Print Network (OSTI)

In this study we are presenting a proof-of-concept microfluidic device that simultaneously applies the conditions required for microelectroporation and micro-sonoporation in a flow-through fashion that allows for high throughput, high efficiency...

Longsine, Whitney Leigh

2012-07-16T23:59:59.000Z

184

Thermal-fluid and electrochemical modeling and performance study of a planar solid oxide electrolysis cell : analysis on SOEC resistances, size, and inlet flow conditions.  

SciTech Connect

Argonne National Laboratory and Idaho National Laboratory researchers are analyzing the electrochemical and thermal-fluid behavior of solid oxide electrolysis cells (SOECs) for high temperature steam electrolysis using computational fluid dynamics (CFD) techniques. The major challenges facing commercialization of steam electrolysis technology are related to efficiency, cost, and durability of the SOECs. The goal of this effort is to guide the design and optimization of performance for high temperature electrolysis (HTE) systems. An SOEC module developed by FLUENT Inc. as part of their general CFD code was used for the SOEC analysis by INL. ANL has developed an independent SOEC model that combines the governing electrochemical mechanisms based on first principals to the heat transfer and fluid dynamics in the operation of SOECs. The ANL model was embedded into the commercial STAR-CD CFD software, and is being used for the analysis of SOECs by ANL. The FY06 analysis performed by ANL and reported here covered the influence of electrochemical properties, SOEC component resistances and their contributing factors, SOEC size and inlet flow conditions, and SOEC flow configurations on the efficiency and expected durability of these systems. Some of the important findings from the ANL analysis are: (1) Increasing the inlet mass flux while going to larger cells can be a compromise to overcome increasing thermal and current density gradients while increasing the cell size. This approach could be beneficial for the economics of the SOECs; (2) The presence of excess hydrogen at the SOEC inlet to avoid Ni degradation can result in a sizeable decrease in the process efficiency; (3) A parallel-flow geometry for SOEC operation (if such a thing be achieved without sealing problems) yields smaller temperature gradients and current density gradients across the cell, which is favorable for the durability of the cells; (4) Contact resistances can significantly influence the total cell resistance and cell temperatures over a large range of operating potentials. Thus it is important to identify and avoid SOEC stack conditions leading to such high resistances due to poor contacts.

Yildiz, B.; Smith, J.; Sofu, T.; Nuclear Engineering Division

2008-06-25T23:59:59.000Z

185

The Application of Flow Cytometry to Examine Damage Clearance in Stem Cells From Whole-Body Irradiated Mice  

SciTech Connect

The bone marrow contains many types of cells. Approximately 1-2% of these cells are critical for life, these are the so-called bone marrow stem cells which divide indefinitely to produce platelets, red blood cells and white blood cells. Death of the bone marrow stem cells results in a diminished ability of the organism to make new blood cell components and can be fatal without medical intervention, such as a bone marrow transplant. Bone marrow stem cells are considered to be particularly sensitive to radiation injury. Therefore, it is important to understand how these cells response to total body radiation exposure and how these cells can be protected from radiation damage. The aim of this project was to determine if these critical cells in the bone marrow are susceptible to short-term and long-term injury after a whole-body exposure to a sub-lethal low dose of ionizing radiation. The overall aims were to determine if the extent of injury produced by the sub-lethal radiation exposure would be cleared from the stem cells and therefore present no long- term genetic risk to the organism, or if the radiation injury persisted and had an adverse long-term consequences for the cell genome. This research question is of interest in order to define the risks to exposed persons after occupational, accidental or terrorism-related sub-lethal low-dose radiation exposures. The novel aspect of this project was the methodology used to obtain the bone marrow stem cell-like cells and examining the outcomes of sub-lethal low-dose radiation in a mammalian animal model. Four radiation treatments were used: single treatments of 0.01Gy, 0.1 Gy, 1 Gy and ten treatments of 0.1 Gy given over 10 days. Bone marrow stem cell-like cells were then harvested 6 hours, 24 hours and 24 days later. The levels of radiation-induced cell death, damage to DNA and permanent changes to cellular DNA were measured in the isolated stem cell-like cells after each radiation treatment and time point and then the results were compared. As expected, the largest radiation dose produced the greatest level of damage but a linear relationship did not exist between cellular effects and radiation dose. The low dose exposures appeared to be more efficient at producing damage than the highest dose when normalized for the initial extent of damage. Additionally, immune stimulation given prior to radiation exposure appeared to protect the critical bone marrow stem cell population from radiation injury. The data suggest that the response of bone marrow stem-cell like cells to radiation injury is dependent on the extent of the initial levels of damage and the effects of total-body low-dose exposures can not be predicted by extrapolating from high dose exposures. This research has provided new information about the radiation sensitivity of bone marrow stem cell-like cells following total-body exposures, and suggests that these critical cells might be more sensitive to radiation than more mature cells in the bone marrow. Further work is need with intermediate radiation doses to confirm this conclusion.

Marples, Brian; Kovalchuk, Olga; McGonagle, Michele; Martinez, Alvaro; Wilson, George, D.

2010-02-26T23:59:59.000Z

186

Early diagenesis of carbohydrates and lignin in mangrove sediments subject to variable redox  

E-Print Network (OSTI)

Early diagenesis of carbohydrates and lignin in mangrove sediments subject to variable redox Abstract A comparative study of lignin and neutral carbohydrate compositions, combined with C, N and 13C and lignin in brackish to hypersaline fine-grained mangrove sediments characterized by great changes in redox

Paris-Sud XI, Université de

187

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta, Lital (San Diego, CA); Schultz, Peter G. (La Jolla, CA); Zhang, Zhiwen (Austin, TX)

2011-08-30T23:59:59.000Z

188

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta, Lital (San Diego, CA); Schultz, Peter G. (La Jolla, CA); Zhang, Zhiwen (San Diego, CA)

2009-02-24T23:59:59.000Z

189

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta; Lital (San Diego, CA), Schultz; Peter G. (La Jolla, CA), Zhang; Zhiwen (San Diego, CA)

2010-10-12T23:59:59.000Z

190

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta, Lital (San Diego, CA); Schultz, Peter G. (La Jolla, CA); Zhang, Zhiwen (San Diego, CA)

2012-02-14T23:59:59.000Z

191

A new flow field design for polymer electrolyte-based fuel cells C. Xu, T.S. Zhao *  

E-Print Network (OSTI)

of the PEMFC system, including the water management of the cathode, have been studied extensively [1 mass transport rates of reactants and products to and from the catalyst layer and reduces the amount (PEM)-based fuel cells, including hydrogen fed PEMFCs and direct liquid metha- nol fuel cells (DMFCs

Zhao, Tianshou

192

Flow Batteries: A Historical Perspective  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Robert Savinell, Case Western Reserve University, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

193

Highly conductive, multi-layer composite precursor composition to fuel cell flow field plate or bipolar plate  

DOE Patents (OSTI)

This invention provides a moldable, multiple-layer composite composition, which is a precursor to an electrically conductive composite flow field plate or bipolar plate. In one preferred embodiment, the composition comprises a plurality of conductive sheets and a plurality of mixture layers of a curable resin and conductive fillers, wherein (A) each conductive sheet is attached to at least one resin-filler mixture layer; (B) at least one of the conductive sheets comprises flexible graphite; and (C) at least one resin-filler mixture layer comprises a thermosetting resin and conductive fillers with the fillers being present in a sufficient quantity to render the resulting flow field plate or bipolar plate electrically conductive with a conductivity no less than 100 S/cm and thickness-direction areal conductivity no less than 200 S/cm.sup.2.

Jang, Bor Z. (Centerville, OH); Zhamu, Aruna (Centerville, OH); Guo, Jiusheng (Centerville, OH)

2011-02-15T23:59:59.000Z

194

Sorption of redox-sensitive elements: critical analysis  

SciTech Connect

The redox-sensitive elements (Tc, U, Np, Pu) discussed in this report are of interest to nuclear waste management due to their long-lived isotopes which have a potential radiotoxic effect on man. In their lower oxidation states these elements have been shown to be highly adsorbed by geologic materials occurring under reducing conditions. Experimental research conducted in recent years, especially through the Waste Isolation Safety Assessment Program (WISAP) and Waste/Rock Interaction Technology (WRIT) program, has provided extensive information on the mechanisms of retardation. In general, ion-exchange probably plays a minor role in the sorption behavior of cations of the above three actinide elements. Formation of anionic complexes of the oxidized states with common ligands (OH/sup -/, CO/sup - -//sub 3/) is expected to reduce adsorption by ion exchange further. Pertechnetate also exhibits little ion-exchange sorption by geologic media. In the reduced (IV) state, all of the elements are highly charged and it appears that they form a very insoluble compound (oxide, hydroxide, etc.) or undergo coprecipitation or are incorporated into minerals. The exact nature of the insoluble compounds and the effect of temperature, pH, pe, other chemical species, and other parameters are currently being investigated. Oxidation states other than Tc (IV,VII), U(IV,VI), Np(IV,V), and Pu(IV,V) are probably not important for the geologic repository environment expected, but should be considered especially when extreme conditions exist (radiation, temperature, etc.). Various experimental techniques such as oxidation-state analysis of tracer-level isotopes, redox potential measurement and control, pH measurement, and solid phase identification have been used to categorize the behavior of the various valence states.

Strickert, R.G.

1980-12-01T23:59:59.000Z

195

Vanadium redox-flow batteries Installation at Ris for characterisation measurements  

E-Print Network (OSTI)

in August 2007. Power systems with high penetration of Wind energy/Renewable energy Renewable energy technologies are being installed at an increasing rate in many countries and regions in order to increase the sustainability of the electricity supply. In some power systems is the level of penetration so high

196

Vanadium-redox flow and lithium-ion battery modelling and performance in wind energy applications.  

E-Print Network (OSTI)

??As wind energy penetration levels increase, there is a growing interest in using storage devices to aid in managing the fluctuations in wind turbine output (more)

Chahwan, John A.

2007-01-01T23:59:59.000Z

197

Cotton flow  

E-Print Network (OSTI)

Using the conformally invariant Cotton tensor, we define a geometric flow, the "Cotton flow", which is exclusive to three dimensions. This flow tends to evolve the initial metrics into conformally flat ones, and is somewhat orthogonal to the Yamabe flow, the latter being a flow within a conformal class. We define an entropy functional, and study the flow of nine homogeneous spaces both numerically and analytically. In particular, we show that the arbitrarily deformed homogeneous 3-sphere flows into the round 3-sphere. Two of the nine homogeneous geometries, which are degenerated by the Ricci flow, are left intact by the Cotton flow.

Ali Ulas Ozgur Kisisel; Ozgur Sarioglu; Bayram Tekin

2008-06-17T23:59:59.000Z

198

Redox states of Desulfovibrio vulgaris DsrC, a key protein in...  

NLE Websites -- All DOE Office Websites (Extended Search)

Venceslau SS, JR Cort, ES Baker, RK Chu, EW Robinson, C Dahl, LM Saraiva, and IA Pereira.2013."Redox states of Desulfovibrio vulgaris DsrC, a key protein in dissimilatory...

199

Molecular cloning and characterization of important stress and redox regulatory genes from Hydra vulgaris  

E-Print Network (OSTI)

In this research, important stress and redox regulatory genes present in Hydra vulgaris were isolated and characterized to facilitate our understanding of the evolution and mechanisms of stress response. H. vulgaris heat shock protein 70 (HvHSP70...

Dash, Bhagirathi

2007-04-25T23:59:59.000Z

200

Method of reduction of nitroaromatics by enzymatic reaction with redox enzymes  

DOE Patents (OSTI)

A method for the controlled reduction of nitroaromatic compounds such as nitrobenzene and 2,4,6-trinitrotoluene by enzymatic reaction with redox enzymes, such as Oxyrase (Trademark of Oxyrase, Inc., Mansfield, Ohio).

Shah, Manish M. (Richland, WA)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

The role of Ncb5or in fatty acid metabolism and redox homeostasis  

E-Print Network (OSTI)

The endoplasmic reticulum (ER)-associated NADH cytochrome b5 oxidoreductase (Ncb5or) is widely distributed in animal tissues. It contains two redox domains that are homologous to microsomal cytochrome b5 (Cyb5A) at the N ...

Xu, Ming

2011-12-31T23:59:59.000Z

202

Transcriptional Regulation of Central Carbon and Energy Metabolism in Bacteria by Redox-Responsive Repressor Rex  

Science Journals Connector (OSTI)

...experimental techniques allow us to identify these and...its orthologs allowed us to predict a conserved...key enzymes involved in energy metabolism and redox status balance. Conservation...functional categories: (i) energy metabolism, including...

Dmitry A. Ravcheev; Xiaoqing Li; Haythem Latif; Karsten Zengler; Semen A. Leyn; Yuri D. Korostelev; Alexey E. Kazakov; Pavel S. Novichkov; Andrei L. Osterman; Dmitry A. Rodionov

2011-12-30T23:59:59.000Z

203

Influence of Iron Redox Transformations on Plutonium Sorption to Sediments  

SciTech Connect

Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation state. A pH 6.3 vadose zone sediment containing iron oxides and iron-containing phyllosilicates was treated with various complexants (ammonium oxalate) and reductants (dithionite-citrate-bicarbonate) to selectively leach and/or reduce iron oxide and phyllosilicate phases. Mssbauer spectroscopy was used to identify initial iron mineral composition of the sediment and monitor dissolution and reduction of iron oxides. Sorption of Pu(V) was monitored over one week for each of six treated sediment fractions. Plutonium oxidation state speciation in the aqueous and solid phases was monitored using solvent extraction, coprecipitation, and XANES. Mssbauer spectroscopy showed that the sediment contained 25-30% hematite, 60-65% Al-goethite, and <10%Fe(III) in phyllosilicate; there was no detectable Fe(II). Upon reduction with a strong chemical reductant (dithionite-citrate buffer, DCB), much of the hematite and goethite disappeared and the Fe in the phyllosilicate reduced to Fe(II). The rate of sorption was found to correlate with the 1 fraction of Fe(II) remaining within each treated sediment phase. Pu(V) was the only oxidation state measured in the aqueous phase, irrespective of treatment, whereas Pu(IV) and much smaller amounts of Pu(V) and Pu(VI) were measured in the solid phase. Surface-mediated reduction of Pu(V) to Pu(IV) occurred in treated and untreated sediment samples; Pu(V) remained on untreated sediment surface for two days before reducing to Pu(IV). Similar to the sorption kinetics, the reduction rate was correlated with sediment Fe(II) concentration. The correlation between Fe(II) concentrations and Pu(V) reduction demonstrates the potential impact of changing iron mineralogy on plutonium subsurface transport through redox transition areas. These findings should influence the conceptual models of long-term stewardship of Pu contaminated sites that have fluctuating redox conditions, such as vadose zones or riparian zones.

Hixon, Amy E.; Hu, Yung-Jin; Kaplan, Daniel I.; Kukkadapu, Ravi K.; Nitsche, Heino; Qafoku, Odeta; Powell, Brian A.

2010-10-01T23:59:59.000Z

204

Redox-dependent solubility of technetium in low activity waste...  

NLE Websites -- All DOE Office Websites (Extended Search)

as H 3 BO 3 ), fused, and then crushed to a fine, free flowing powder in a tungsten carbide mill. The crushed glass is not particularly hygroscopic and does not generate gas...

205

Electromagnetic Borehole Flowmeter Surveys at Selected In Situ Redox Manipulation Barrier Wells, Zero-Valent Iron Site, Hanford, Washington  

SciTech Connect

Ambient (i.e., static) and dynamic (i.e., pumping-induced) electromagnetic borehole flowmeter (EBF) surveys were performed in 10 selected In Situ Redox Manipulation (ISRM) barrier wells to characterize the distribution of in-well vertical flow conditions and to infer the relative hydraulic conductivity distribution in the upper-part of the unconfined aquifer. These wells are located in two areas where the aquifer is targeted for testing of zero-valent iron injection to mend a failed portion of the ISRM barrier at the 100 D Area, Hanford Site. Each of these two areas consists of a group of five wells, one group to the southwest and one group to the northeast. The upper ~15 to 20 ft (~4.6 to 6.1 m) of the unconfined aquifer was characterized for in-well vertical flow conditions and vertical profile information regarding relative hydraulic conductivity. At some well site locations, the upper ~2 to 3 ft (~0.6 to 1 m) of the well-screen interval could not be characterized under pumping (dynamic) conditions because of the presence of the pump.

Newcomer, Darrell R.

2009-02-09T23:59:59.000Z

206

1: Redox chemistry of bimetallic fulvalene complexes; 2: Oligocyclopentadienyl complexes  

SciTech Connect

The electrochemistry of the heterobimetallic complexes (fulvalene)WFe(CO){sub 5} (30) and (fulvalene)WRu(CO){sub 5} (31) has been investigated. Compound 30 is reduced in two one-electron processes, and this behavior was exploited synthetically to prepare a tetranuclear dimer by selective metal reduction. Complex 31 displayed a distinction between the metals upon reoxidation of the dianion, allowing the formation of a dimer by selective metal anion oxidation. The redox behavior of 30 led to an investigation of the use of electrocatalysis to effect metal-specific ligand substitution. It was found that reduction of 30 with a catalytic amount of CpFe(C{sub 6}Me{sub 6}) (97) in the presence of excess P(OMe){sub 3} or PMe{sub 3} led to the formation of the zwitterions (fulvalene)[W(CO){sub 3}{sup {minus}}][Fe(CO)PR{sub 3}{sup +}] (107, R = P(OMe){sub 3}; 108, R = PMe{sub 3}). Compound 31 also displayed unique behavior with different reducing agents, as the monosubstituted zwitterion (fulvalene)[W(CO){sub 3}{sup {minus}}][Ru(CO){sub 2}(PMe{sub 3}){sup +}] was obtained when 97 was used while the disubstituted complex (fulvalene) [W(CO){sub 3}{sup {minus}}] [Ru(CO)(PMe{sub 3}){sub 2}{sup +}] was produced when Cp*Fe(C{sub 6}Me{sub 6}) was the catalyst. Potential synthetic routes to quatercyclopentadienyl complexes were also explored. Various attempts to couple heterobimetallic fulvalene compounds proved to be unsuccessful. 138 refs.

Brown, D.S. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Chemical Sciences Div.

1993-11-01T23:59:59.000Z

207

Resuspension studies in cylindrical microcosms: Effects of stirring velocity on the dynamics of redox sensitive elements in a coastal sediment  

Science Journals Connector (OSTI)

Effects of resuspension on the release of dissolved, redox sensitive ... At current velocities below the threshold velocity for resuspension (37 cm s-1), Mn release...

Mario Hose Calado Laima; Henning Matthiesen; Lars Chresten Lund-Hansen

1998-12-01T23:59:59.000Z

208

Poly(3,4-ethylenedioxypyrrole) Modified Emitter Electrode for Substitution of Homogeneous Redox Buffer Agent Hydroquinone in Electrospray Ionization Mass Spectrometry  

SciTech Connect

The electrolysis inherent to the operation of the electrospray ionization (ESI) source used with mass spectrometry (MS) is a well-known attendant effect of generating unipolar spray droplets and may affect the analysis of the analyte of interest. Undesirable electrolysis of an analyte may be prevented by limiting the emitter electrode current and/or the mass transport characteristics of the system. However, these ways to avoid analyte electrolysis may not be applcable in all ESI-MS experiments. For example, in the case of specific nanospray systems (e.g. the wire-in-a-capillary bulk-loaded or chip-based tip-loaded nanospray configurations), the solution flow rate is fixed in the 50-500 nL/min range and the electrode surface to volume ratio is large presenting a very effcient analyte to electrode mass transport configuration. In these situations, control over the interfacial potential of the working electrode via homogeneous or traditional heterogeneous (sacrificial metal) redox buffering is a possible way to prevent analyte electrolysis. However, byproducts of these redox buffering approaches can appear in the mass spectra and/or they can chemically alter the analyte. For example, the main reason for using hydroquinone as a homogeneous redox buffer, in addition to its relatively low oxidation potential, is that neither the original compound nor its oxidation product benzoquinone can be detected directly by ESI-MS. However, benzoquinone can alter analytes with thiol functional groups by reacting with those groups via a 1,4-Michael addition.

Peintler-Krivan, Emese [ORNL; Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL

2010-01-01T23:59:59.000Z

209

Pouring flows  

Science Journals Connector (OSTI)

Free surface flows of a liquid poured from a container are calculated numerically for various configurations of the lip. The flow is assumed to be steady two dimensional and irrotational; the liquid is treated as inviscid and incompressible; and gravity is taken into account. It is shown that there are jetlike flows with two free surfaces and other flows with one free surface which follow along the underside of the lip or spout. The latter flows occur in the well?known teapot effect which was treated previously without including gravity. Some of the results are applicable also to flows over weirs and spillways.

Jean?Marc Vanden?Broeck; Joseph B. Keller

1986-01-01T23:59:59.000Z

210

Redox Energetics and Kinetics of Uranyl Coordination Complexes in Aqueous Solution  

Science Journals Connector (OSTI)

The redox chemistry of uranium is remarkably rich and diverse as a consequence of the number of readily accessible oxidation states (III?VI) and the sensitivity of the redox potentials to the coordination environment around the metal. ... 1-3 In aqueous environments, the most stable oxidation state for uranium is the hexavalent state for which the dominant species is the uranyl ion, UO22+.1-3 The redox chemistry of uranyl has been extensively investigated and manipulated, particularly for separations and process chemistry relating to the nuclear fuel cycle and other defense-related applications. ... The aquo, carbonato, acetato, and chloro complexes of uranyl are all known or potentially relevant species in environmental groundwaters, and the hydroxo and carbonato complexes are relevant species in alkaline high-level radioactive waste storage tanks associated with nuclear fuel processing. ...

David E. Morris

2002-05-31T23:59:59.000Z

211

In Situ Redox Manipulation Field Injection Test Report - Hanford 100-H Area  

SciTech Connect

This report presents results of an In Situ Redox Manipulation (ISRM) Field Injection Withdrawal Test performed at the 100-H Area of the US. Department of Energy`s (DOE`s) Hanford Site in Washington State in Fiscal Year 1996 by researchers at Pacific Northwest National Laboratory (PNNL). The test is part of the overall ISRM project, the purpose of which is to determine the potential for remediating contaminated groundwater with a technology based on in situ manipulation of subsurface reduction-oxidation (redox) conditions. The ISRM technology would be used to treat subsurface contaminants in groundwater zones at DOE sites.

Fruchter, J.S.; Amonette, J.E.; Cole, C.R. [and others

1996-11-01T23:59:59.000Z

212

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial  

E-Print Network (OSTI)

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial cytochrome c oxidase, which makes copper an essential element for all aerobic organisms (Soloman and Lowery, 1993). However, the redox properties of copper can cause rapid generation

Grosell, Martin

213

Influence of uranyl speciation and iron oxides on uranium biogeochemical redox reactions  

SciTech Connect

Uranium is a pollutant of concern to both human and ecosystem health. Uranium's redox state often dictates its partitioning between the aqueous- and solid-phases, and thus controls its dissolved concentration and, coupled with groundwater flow, its migration within the environment. In anaerobic environments, the more oxidized and mobile form of uranium (UO{sub 2}{sup 2+} and associated species) may be reduced, directly or indirectly, by microorganisms to U(IV) with subsequent precipitation of UO{sub 2}. However, various factors within soils and sediments may limit biological reduction of U(VI), inclusive of alterations in U(VI) speciation and competitive electron acceptors. Here we elucidate the impact of U(VI) speciation on the extent and rate of reduction with specific emphasis on speciation changes induced by dissolved Ca, and we examine the impact of Fe(III) (hydr)oxides (ferrihydrite, goethite and hematite) varying in free energies of formation on U reduction. The amount of uranium removed from solution during 100 h of incubation with S. putrefaciens was 77% with no Ca or ferrihydrite present but only 24% (with ferrihydrite) and 14% (no ferrihydrite) were removed for systems with 0.8 mM Ca. Imparting an important criterion on uranium reduction, goethite and hematite decrease the dissolved concentration of calcium through adsorption and thus tend to diminish the effect of calcium on uranium reduction. Dissimilatory reduction of Fe(III) and U(VI) can proceed through different enzyme pathways, even within a single organism, thus providing a potential second means by which Fe(III) bearing minerals may impact U(VI) reduction. We quantify rate coefficients for simultaneous dissimilatory reduction of Fe(III) and U(VI) in systems varying in Ca concentration (0 to 0.8 mM), and using a mathematical construct implemented with the reactive transport code MIN3P, we reveal the predominant influence of uranyl speciation, specifically the formation of uranyl-calcium-carbonato complexes, and ferrihydrite on the rate and extent of uranium reduction in complex geochemical systems.

Stewart, B.D.; Amos, R.T.; Nico, P.S.; Fendorf, S.

2010-03-15T23:59:59.000Z

214

An Inner Membrane Cytochrome Required Only for Reduction of High Redox Potential Extracellular Electron Acceptors  

Science Journals Connector (OSTI)

...and offer different amounts of available energy. Despite this, metal-reducing bacteria...strategies to take advantage of these energy differences. Disruption of imcH, encoding...to generation of different amounts of energy for growth. The redox potentials that...

Caleb E. Levar; Chi Ho Chan; Misha G. Mehta-Kolte; Daniel R. Bond

2014-12-01T23:59:59.000Z

215

A Modular Approach to Redox-active Multimetallic Amphiphiles of Discotic Topology  

SciTech Connect

A new modular [Fe{sup II}(Fe{sup III}L{sup 2}){sub 3}](PF{sub 6}){sub 2} species with discoid (disk-like) topology exhibits redox and surfactant properties and points to a new approach for multimetallic Langmuir film precursors.

F Lesh; R Shanmugam; M Allard; M Lanznaster; M Hegg; M Rodgers; J Shearer; C Verani

2011-12-31T23:59:59.000Z

216

Redmond Red as a Redox Probe for the DNA-Mediated Detection of Abasic Sites  

Science Journals Connector (OSTI)

Redmond Red, a fluoropore containing a redox-active phenoxazine core, has been explored as a new electrochemical probe for the detection of abasic sites in double-stranded DNA. The electrochemical behavior of Redmond Red-modified DNA at gold surfaces ...

Marisa C. Buzzeo; Jacqueline K. Barton

2008-10-03T23:59:59.000Z

217

Redox Potentials and Acidity Constants from Density Functional Theory Based Molecular Dynamics  

E-Print Network (OSTI)

. If the solvent response is linear, as assumed in Marcus theory, ?O = ?R As a result eU? = 1/2(IPR + EAO). The redox level is midway between the ?IPR and ?EAO level. The FEP method converts vertical to adiabatic energies by a coupling parameter integral. The end...

Cheng, Jun; Liu, Xiandong; VandeVondele, Joost; Sulpizi, Marialore; Sprik, Michiel

2014-01-01T23:59:59.000Z

218

Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase  

E-Print Network (OSTI)

The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

Feng, Jian

2005-08-29T23:59:59.000Z

219

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus  

E-Print Network (OSTI)

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus and Frauke Gra, China ABSTRACT Mechanical force applied along a disulfide bond alters its rate of reduction. We here within proteins by point mutations. INTRODUCTION Similar to thermal or light energy, mechanical force can

Gräter, Frauke

220

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions  

E-Print Network (OSTI)

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions A novel coordination polymer of mixed-valence copper(I,II) with 4,4A-bipyridine and in situ oxidized and crystallographically char- acterized to be a laminated structure via weak copper(II)­ oxygen interactions. Extended

Li, Jing

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Flow chamber  

DOE Patents (OSTI)

A flow chamber having a vacuum chamber and a specimen chamber. The specimen chamber may have an opening through which a fluid may be introduced and an opening through which the fluid may exit. The vacuum chamber may have an opening through which contents of the vacuum chamber may be evacuated. A portion of the flow chamber may be flexible, and a vacuum may be used to hold the components of the flow chamber together.

Morozov, Victor (Manassas, VA)

2011-01-18T23:59:59.000Z

222

Gasliquid two-phase flow patterns in a miniature square channel with a gas permeable sidewall  

E-Print Network (OSTI)

methanol fuel cells. Flow patterns in both vertical upward and horizontal flows were identified using in vertical downward flows; and Kosterin [5] and Brigham et al. [6] discussed flow patterns in inclined-phase flow of air�water mixtures in horizontal pipes, the flow patterns and flow regime maps for five glass

Zhao, Tianshou

223

Effect of Reducing Groundwater on the Retardation of Redox-Sensitive Radionuclides  

SciTech Connect

Laboratory batch sorption experiments were used to investigate variations in the retardation behavior of redox-sensitive radionuclides. Water-rock compositions used during these experiments were designed to simulate subsurface conditions at the Nevada Test Site (NTS), where a suite of radionuclides were deposited as a result of underground nuclear testing. Experimental redox conditions were controlled by varying the oxygen content inside an enclosed glove box and by adding reductants into the testing solutions. Under atmospheric (oxidizing) conditions, the radionuclide distribution coefficients varied with the mineralogical composition of the sorbent and the water chemistry. Under reducing conditions, distribution coefficients showed marked increases for {sup 99}Tc and {sup 237}Np in devitrified tuff, but much smaller variations in alluvium, carbonate rock, and zeolitic tuff. This effect was particularly important for {sup 99}Tc, which tends to be mobile under oxidizing conditions. Unlike other redox-sensitive radionuclides, iodine sorption may decrease under reducing conditions when I{sup -} is the predominant species. Overall, sorption of U to alluvium, devitrified tuff, and zeolitic tuff under atmospheric conditions was less than in the glove-box tests. However, the mildly reducing conditions achieved here were not likely to result in substantial U(VI) reduction to U(IV). Sorption of Pu was not affected by the decreasing redox conditions achieved in this study, as the predominant sorbed Pu species in all conditions was expected to be the low-solubility and strongly sorbing Pu(OH){sub 4}. Depending on the aquifer lithology, the occurrence of reducing conditions along a groundwater flowpath could potentially contribute to the retardation of redox-sensitive radionuclides {sup 99}Tc and {sup 237}Np, which are commonly identified as long-term dose contributors in the risk assessment in various nuclear facilities.

Hu, Q; Zavarin, M; Rose, T P

2008-04-21T23:59:59.000Z

224

Redox-sensitive structural change in the A-domain of HMGB1 and its implication for the binding to cisplatin modified DNA  

SciTech Connect

Highlights: The structure of the oxidized A-domain of human HMGB1 was solved. Phe38 ring was flipped in the oxidized structure from that in the reduced form. The flipped ring disables the intercalation into the cisplatinated lesions. The functionally relevant redox-dependent structural change was described. -- Abstract: HMGB1 (high-mobility group B1) is a ubiquitously expressed bifunctional protein that acts as a nuclear protein in cells and also as an inflammatory mediator in the extracellular space. HMGB1 changes its functions according to the redox states in both intra- and extra-cellular environments. Two cysteines, Cys23 and Cys45, in the A-domain of HMGB1 form a disulfide bond under oxidative conditions. The A-domain with the disulfide bond shows reduced affinity to cisplatin modified DNA. We have solved the oxidized A-domain structure by NMR. In the structure, Phe38 has a flipped ring orientation from that found in the reduced form; the phenyl ring in the reduced form intercalates into the platinated lesion in DNA. The phenyl ring orientation in the oxidized form is stabilized through intramolecular hydrophobic contacts. The reorientation of the Phe38 ring by the disulfide bond in the A-domain may explain the reduced HMGB1 binding affinity towards cisplatinated DNA.

Wang, Jing [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan)] [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Tochio, Naoya [Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)] [Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan); Takeuchi, Aya [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan)] [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Uewaki, Jun-ichi [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan) [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan); Kobayashi, Naohiro [Protein Research Institute, Osaka University, 3-2 Yamadaoka, Suita 565-0871 (Japan)] [Protein Research Institute, Osaka University, 3-2 Yamadaoka, Suita 565-0871 (Japan); Tate, Shin-ichi, E-mail: tate@hiroshima-u.ac.jp [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan) [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

2013-11-29T23:59:59.000Z

225

Fuel Cell Technologies Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

4/3/2012 4/3/2012 eere.energy.gov Fuel Cell Technologies Overview Flow Cell Workshop Washington, DC Dr. Sunita Satyapal & Dr. Dimitrios Papageorgopoulos U.S. Department of Energy Fuel Cell Technologies Program 3/7/2011 Flow Cells for Energy Storage Workshop Purpose To understand the applied research and development needs and the grand challenges for the use of flow cells as energy-storage devices. Objectives 1. Understand the needs for applied research from stakeholders. 2. Gather input for future development of roadmaps and technical targets for flow cells for various applications. 3. Identify grand challenges and prioritize R&D needs. Flow cells combine the unique advantages of batteries and fuel cells and can offer benefits for multiple energy storage applications.

226

Investigation of Water Droplet Interaction with the Sidewalls of the Gas Channel in a PEM Fuel Cell in the Presence of Gas Flow  

E-Print Network (OSTI)

forms of hydrogen powered technologies exist and have been well-researched, fuel cells is considered efficiently in the fuel cells (4). Inefficient water removal results in flooding of the catalyst layerInvestigation of Water Droplet Interaction with the Sidewalls of the Gas Channel in a PEM Fuel Cell

Kandlikar, Satish

227

The Ascorbic Acid Redox State Controls Guard Cell Signaling and Stomatal Movement  

Science Journals Connector (OSTI)

...required to promote stomatal closure (Price et al., 1994; Pei et al., 2000...1996). Leaf abscission induced by ethylene in water-stressed intact seedlings of...promoters. Genetics 149, 405-415. Price, A.H., Taylor, A., Ripley, S...

Zhong Chen; Daniel R. Gallie

2004-04-14T23:59:59.000Z

228

Measuring Localized Redox Enzyme Electron Transfer in a Live Cell with Conducting Atomic Force Microscopy  

Science Journals Connector (OSTI)

Department of Bioengineering, ?Department of Aerospace and Mechanical Engineering, ?Materials Science Program, University of California San Diego, 9500 Gillman Dr., La Jolla, California 92093, United States ... Connelly, L.; Meckes, B.; Larkin, J.; Gillman, A. L.; Wanunu, M.; Lal, R. ACS Appl. ... Connelly, Laura S.; Meckes, Brian; Larkin, Joseph; Gillman, Alan L.; Wanunu, Meni; Lal, Ratnesh ...

Lital Alfonta; Brian Meckes; Liron Amir; Orr Schlesinger; Srinivasan Ramachandran; Ratnesh Lal

2014-06-30T23:59:59.000Z

229

Slug flow  

E-Print Network (OSTI)

Introduction: When two phases flow concurrently in a pipe, they can distribute themselves in a number of different configurations. The gas could be uniformly dispersed throughout the liquid in the form of small bubbles. ...

Griffith, P.

1959-01-01T23:59:59.000Z

230

A Mechanistic Study of the Influence of Proton Transfer Processes on the Behavior of Thiol/Disulfide Redox Couples  

Science Journals Connector (OSTI)

3 This facilitation of the DMcT redox process comprises an important finding, because, even though the thermodynamics of thiol/disulfide redox processes are quite attractive from the perspective of lithium cathode materials, their kinetics are typically very slow at room temperature. ... Because these elementary steps are thermodynamically interrelated, their equilibrium constants (for chemical reactions) and E values (for electrochemical reactions) cannot be varied independently, providing some constraints on the number of independent variables in the simulation. ...

Eiichi Shouji; Daniel A. Buttry

1999-03-06T23:59:59.000Z

231

Thermochemical Solar Energy Storage Via Redox Oxides: Materials and Reactor/Heat Exchanger Concepts  

Science Journals Connector (OSTI)

Abstract Thermochemical Storage of solar heat exploits the heat effects of reversible chemical reactions for the storage of solar energy. Among the possible reversible gas-solid chemical reactions, the utilization of a pair of redox reactions of multivalent solid oxides can be directly coupled to CSP plants employing air as the heat transfer fluid bypassing the need for a separate heat exchanger. The present work concerns the development of thermochemical storage systems based on such oxide-based redox materials and in particular on cobalt oxide; in the one hand by tailoring their heat storage/release capability and on the other hand via their incorporation in proper reactor/heat exchanger devices. In this respect the first stage of the work involved parametric testing of cobalt oxide compositions via Thermo-Gravimetric Analysis to comparatively investigate the temperature range for cyclic oxidation-reduction and optimize the cycle conditions for maximum reduction and re-oxidation extent. Subsequently, two reactor concepts for the coupling of solar energy to the redox reactions have been implemented and tested. These reactor concepts include in one hand structured ceramic reactors/heat exchangers based on redox-oxide-coated honeycombs and on the other hand powder-fed, solar-heated, rotary kiln reactors. The two reactor concepts were tested within non-solar-aided lab-scale and solar- aided campaigns, respectively. The feasibility of both concepts was shown and good chemical conversions were achieved. The experiments pointed out the challenging points related to the manufacture of pilot-scale reactors/heat exchangers with enhanced heat storage capacity. A numerical model using commercial CFD software is developed to define optimal geometrical characteristics and operating conditions and refine the pilot scale design in order to achieve efficient, long-term off-sun operation.

S. Tescari; C. Agrafiotis; S. Breuer; L. de Oliveira; M. Neises-von Puttkamer; M. Roeb; C. Sattler

2014-01-01T23:59:59.000Z

232

Impacts of Shallow Geothermal Energy Production on Redox Processes and Microbial Communities  

Science Journals Connector (OSTI)

Impacts of Shallow Geothermal Energy Production on Redox Processes and Microbial Communities ... Thermophilic sulfate reduction, however, had a higher activation energy (100160 kJ mol1) than mesophilic sulfate reduction (3060 kJ mol1), which might be due to a trade-off between enzyme stability and activity with thermostable enzymes being less efficient catalysts that require higher activation energies. ...

Matthijs Bonte; Wilfred F. M. Rling; Egija Zaura; Paul W. J. J. van der Wielen; Pieter J. Stuyfzand; Boris M. van Breukelen

2013-11-22T23:59:59.000Z

233

100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater: FY 1998 Year-End Report  

SciTech Connect

A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the US Department of Energy's Hanford, Washington 100D Area. The target contaminant was dissolved chromate [Cr(VI)] in groundwater. The ISRM technology involves creating a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron [Fe(III)] to ferrous iron [Fe(II)] within the aquifer sediments. This is accomplished by injecting aqueous sodium dithionite into the aquifer and withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in the spring of 1997. The first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998; the remaining four dithionite injections were carried out in May through July of 1998. These five injections created a reduced zone in the Hanford unconfined aquifer 150 feet in length (perpendicular to groundwater flow) by 50 feet wide. The reduced zone extended over the thickness of the unconfined zone, which is approximately 15 feet. Analysis of recent groundwater sampling events shows that the concentrations of chromate [Cr(VI)] in groundwater in the reduced zone have been decreased from starting concentrations of approximately 900 ppb to below analytical detection limits (<7 ppb). Chromate concentrations are also declining in some downgradient monitoring wells. Laboratory analysis of iron in the soil indicates that the barrier should remain in place for approximately 20 to 25 years. These measurements will be confirmed by analysis of sediment cores in FY 1999.

Williams, M.D.; Vermeul, V.R.; Szecsody, J.E.; Fruchter, J.S.; Cole, C.R.

1999-04-15T23:59:59.000Z

234

The first cell sorter  

NLE Websites -- All DOE Office Websites (Extended Search)

The first cell sorter The first cell sorter 1663 Los Alamos science and technology magazine Latest Issue:November 2013 All Issues » submit The first cell sorter About fifty years ago, a Los Alamos scientist invented a method-still important in cellular biology labs today-to separate out particular types of cells. November 25, 2013 The first cell sorter Flow cytometry (cell measurement) uses cell sorting to divert cells of a chosen type out of a mixed stream of cells, like the blood cells shown here, for collection and study. Los Alamos invented, and has regularly improved upon, the technology to isolate different kinds of cells. In the early-mid 1960s, Los Alamos physicist Mack Fulwyler invented a device to isolate different types of cells. His invention, still a vital aspect of flow cytometry (cell measurement) in biological laboratories

235

Control of flow and oxygen in a 3-D perfused micro-environment fosters balanced survival of hepatocyte-non-parenchymal cell co-cultures  

E-Print Network (OSTI)

Creating a physiologically relevant in vitro liver model requires reproducing the cellular heterogeneity of in vivo liver in a functional state. However differentiated sinusoidal endothelial cells (SECs), marked by SE-1 ...

Dash, Ajit

2007-01-01T23:59:59.000Z

236

Solid and liquid spectroscopic analysis (SALSA) - A soft x-ray spectroscopy end station with a novel flow-through liquid cell  

E-Print Network (OSTI)

ultra-high vacuum (UHV), which seems to be incompatible withof the liquid cell into UHV like any other (dry) solidintegrated into a standard UHV sample manipulator with XYZ-

Blum, M.

2010-01-01T23:59:59.000Z

237

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM  

E-Print Network (OSTI)

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel

Dunin-Borkowski, Rafal E.

238

A Glucose BioFuel Cell Implanted in Rats Philippe Cinquin1  

E-Print Network (OSTI)

A Glucose BioFuel Cell Implanted in Rats Philippe Cinquin1 *, Chantal Gondran2 , Fabien Giroud2 powerful ones, Glucose BioFuel Cells (GBFCs), are based on enzymes electrically wired by redox mediators applications. Citation: Cinquin P, Gondran C, Giroud F, Mazabrard S, Pellissier A, et al. (2010) A Glucose BioFuel

Paris-Sud XI, Université de

239

PEMFC R&D at the DOE Fuel Cell Technologies Program | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Meeting Hydrogen and Fuel Cell Activities: 5th International Conference on Polymer Batteries and Fuel Cells Fuel Cell Technologies Overview: 2012 Flow Cells for Energy...

240

Anoxic Plume Attenuation in a Fluctuating Water Table System: Impact of 100-D Area In Situ Redox Manipulation on Downgradient Dissolved Oxygen Concentrations  

SciTech Connect

Anoxic Plume Attenuation in a Fluctuating Water Table System: Impact of 100-D Area In Situ Redox Manipulation on Downgradient Dissolved Oxygen Concentrations

Williams, Mark D.; Vermeul, Vincent R.; Oostrom, Martinus; Evans, John C.; Fruchter, Jonathan S.; Istok, J. D.; Humphrey, M. D.; Lanigan, David C.; Szecsody, James E.; White, Mark D.; Wietsma, Thomas W.; Cole, Charles R.

1999-06-14T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

High-energy mechanical synthesis of nanophase fluorite-structured mixed oxide catalysts with a high redox activity  

SciTech Connect

A series of nanostructured, highly defective, ternary solid solutions containing CeO{sub 2}, ZrO{sub 2}, and MnO{sub 2} or CuO were prepared by high-energy mechanical milling of individual components. Morphological and redox properties were studied by XRD, HRTEM and temperature-programmed reduction techniques. It was shown that the introduction of small amounts of copper and manganese strongly promotes the redox behavior of cerium at lower temperatures in comparison with CeO{sub 2} and CeO{sub 2}-ZrO{sub 2}. High temperature treatment of up to 1,400 K was also shown to further promote overall redox capacity without affecting low-temperature redox behavior. Moreover, evidence is provided to show that Cu and Mn are dissolved within the CeO{sub 2} lattice structure. Addition of dopants enhances catalytic redox properties in the oxidation of CO at low temperatures, which is associated with the high concentration of oxygen vacancies that form on the introduction of aliovalent elements into the ceria-zirconia lattice.

Primavera, A.; Trovarelli, A.; Terribile, D.; Leitenburg, C. de; Dolcetti, G. [Univ. di Udine (Italy). Dipt. di Scienze e Tecnologie Chimiche; Llorca, J. [Univ. de Barcelona (Spain). Dept. de Quimica Inorganica

1997-12-31T23:59:59.000Z

242

BIOENERGY AND BIOFUELS Performance of a pilot-scale continuous flow microbial  

E-Print Network (OSTI)

BIOENERGY AND BIOFUELS Performance of a pilot-scale continuous flow microbial electrolysis cell fed performance. Keywords Biohydrogen . Biomethane . Bioelectricity. Microbial electrolysis cell . Bioenergy

243

Micro free-flow isoelectric focusing  

E-Print Network (OSTI)

To unravel the complexity of cellular systems, protein prefractionation tools can be used to reduce cell lysate complexity and increase assay sensitivity. Rapid free flow isoelectric focusing (FF-IEF) is achieved in a ...

Albrecht, Jacob William

2008-01-01T23:59:59.000Z

244

Development of the in vivo flow cytometer  

E-Print Network (OSTI)

An in vivo flow cytometer has been developed that allows the real-time detection and quantification of circulating cells containing fluorescent proteins or labeled with fluorochrome molecules in live animals, without the ...

Novak, John P. (John Peter), 1957-

2004-01-01T23:59:59.000Z

245

Molybdenum in Nuclear Waste Glasses -Incorporation and Redox state R.J. Short, R.J. Hand, N.C. Hyatt,  

E-Print Network (OSTI)

Molybdenum in Nuclear Waste Glasses - Incorporation and Redox state R.J. Short, R.J. Hand, N form in simulated high level nuclear waste (HLW) glass melts have been studied. It was found less attention has been paid to the effects of redox on nuclear waste glasses. One particular element

Sheffield, University of

246

Energy Management by Enhanced Glycolysis in G1-phase in Human Colon Cancer Cells In Vitro and In Vivo  

Science Journals Connector (OSTI)

...metabolites involved in energy and redox metabolism...mKO2 (red), mAG (green), and both mKO2 and...cell-cycle phase-dependent energy metabolism, possibly...G2-M phases both emitted green fluorescence, they could...cell-cycle-dependent changes in energy metabolism clearly...

Yan Bao; Kuniaki Mukai; Takako Hishiki; Akiko Kubo; Mitsuyo Ohmura; Yuki Sugiura; Tomomi Matsuura; Yoshiko Nagahata; Noriyo Hayakawa; Takehiro Yamamoto; Ryo Fukuda; Hideyuki Saya; Makoto Suematsu; and Yoji Andrew Minamishima

2013-09-01T23:59:59.000Z

247

Use of Dissolved H2 Concentrations To Determine Distribution of Microbially Catalyzed Redox Reactions in Anoxic Groundwater  

E-Print Network (OSTI)

similartothe HZconcentrationsthat havepreviously been reported for aquatic sedimentswith the same TEAPs. In two aquifers contaminated with petroleum products, it was impossible with standard geochemical analyses actuallyexist (i.e.,there arenofreeelectrons); (2) the redox status of most natural waters cannot be accurately

Lovley, Derek

248

Hyporheic Exchange and Fulvic Acid Redox Reactions in an Alpine Stream/Wetland Ecosystem, Colorado Front Range  

Science Journals Connector (OSTI)

Hyporheic Exchange and Fulvic Acid Redox Reactions in an Alpine Stream/Wetland Ecosystem, Colorado Front Range ... Fluxes of dissolved organic carbon (DOC) in mountain catchments of the western United States vary with hydrograph stage (1, 2) and inter-annual climate variation (3). ...

Matthew P. Miller; Diane M. McKnight; Rose M. Cory; Mark W. Williams; Robert L. Runkel

2006-08-23T23:59:59.000Z

249

Quercetin and Dietary Lipids Alter the Cellular Redox Environment of the Colonocyte in the Promotion Stage of Colon Carcinogenesis.  

E-Print Network (OSTI)

the beneficial effects of FO by counteracting FO effects on colonocyte redox status. To test this, we provided 40 rats with FO or CO (fiber = pectin) diets with Q being 0 or 0.45% of the diet for 10 wk. All rats were injected with azoxymethane (AOM) on d 21...

Paulhill, Kimberly Jones

2009-05-15T23:59:59.000Z

250

Redox-Responsive Magnetic Nanoparticle for Targeted Convection-Enhanced Delivery of O6-Benzylguanine to Brain Tumors  

Science Journals Connector (OSTI)

Redox-Responsive Magnetic Nanoparticle for Targeted Convection-Enhanced Delivery of O6-Benzylguanine to Brain Tumors ... In vivo, CED of NPCP-BG-CTX produced an excellent volume of distribution (Vd) within the brain of mice bearing orthotopic human primary GBM xenografts. ...

Zachary R. Stephen; Forrest M. Kievit; Omid Veiseh; Peter A. Chiarelli; Chen Fang; Kui Wang; Shelby J. Hatzinger; Richard G. Ellenbogen; John R. Silber; Miqin Zhang

2014-09-23T23:59:59.000Z

251

Mobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox conditions  

E-Print Network (OSTI)

). Typically, it comprises residual iron oxides, quartz, sodium aluminosilicates, titanium dioxide, calciumMobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox elements, including arsenic. Aerobic and anaer- obic batch experiments were prepared using soils from near

Burke, Ian

252

Research Program to Determine Redox Reactions and Their Effects on Speciation and Mobility of Plutonium in DOE Wastes  

SciTech Connect

Plutonium in geologic matrices undergoes a variety of complex reactions which complicate its environmental behavior. These complexities in plutonium chemistry whereby a large variety of precipitation, dissolution, adsorption/desorption, and redox reactions control plutonium speciation and concentrations, result in the need for a rather large amount of reliable, fundamental data to predict Pu behavior in geologic media. These data are also needed for evaluation of remediation strategies that involve removing most of the contaminants by selective methods, followed by in situ immobilization of residual contaminants. Two areas were studied during this project: (1) thermodynamic data for Th(IV) and Pu(IV) complexes of EDTA and for Pu(V) interactions with chloride; (2) kinetic data for redox reactions of Pu in the presence of common redox agents (e.g., H{sub 2}O{sub 2}, MnO{sub 2}, and NaOCl) encountered under waste disposal conditions. These studies are relevant to understanding Pu behavior in wastes disposed of in diverse geologic conditions (e.g., at the WIPP and YUCCA Mountain repositories and in contaminated sediments at many different DOE sites) and also for developing effective remediation strategies (e.g., processing of high level waste tanks). These studies have yielded data to address redox reactions of plutonium in the presence of environmentally important agents (e.g. organic and inorganic oxidants/reductants).

Choppin, G.R.; Rai, D.

2000-10-01T23:59:59.000Z

253

An Arabidopsis Glutathione Peroxidase Functions as Both a Redox Transducer and a Scavenger in Abscisic Acid and Drought Stress Responses  

Science Journals Connector (OSTI)

...Functions as Both a Redox Transducer and a Scavenger in Abscisic Acid and Drought Stress Responses [W] Yuchen Miao a b Dong Lv a Pengcheng Wang a Xue-Chen Wang b Jia Chen b Chen Miao a Chun-Peng Song a 1 1 To whom correspondence should be addressed. E-mail...

Yuchen Miao; Dong Lv; Pengcheng Wang; Xue-Chen Wang; Jia Chen; Chen Miao; Chun-Peng Song

2006-09-22T23:59:59.000Z

254

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science » Materials Science » Fuel Cells Fuel Cells Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Melissa Fox Applied Energy Email Catherine Padro Sensors & Electrochemical Devices Email Fernando Garzon Sensors & Electrochemical Devices Email Piotr Zelenay Sensors & Electrochemical Devices Email Rod Borup Sensors & Electrochemical Devices Email Karen E. Kippen Experimental Physical Sciences Email Like a battery, a fuel cell consists of two electrodes separated by an electrolyte-in polymer electrolyte fuel cells, the separator is made of a thin polymeric membrane. Unlike a battery, a fuel cell does not need recharging-it continues to produce electricity as long as fuel flows

255

Solar Thermochemical Fuels Production: Solar Fuels via Partial Redox Cycles with Heat Recovery  

SciTech Connect

HEATS Project: The University of Minnesota is developing a solar thermochemical reactor that will efficiently produce fuel from sunlight, using solar energy to produce heat to break chemical bonds. The University of Minnesota is envisioning producing the fuel by using partial redox cycles and ceria-based reactive materials. The team will achieve unprecedented solar-to-fuel conversion efficiencies of more than 10% (where current state-of-the-art efficiency is 1%) by combined efforts and innovations in material development, and reactor design with effective heat recovery mechanisms and demonstration. This new technology will allow for the effective use of vast domestic solar resources to produce precursors to synthetic fuels that could replace gasoline.

None

2011-12-19T23:59:59.000Z

256

Microfluidic Flow-Flash: Method for Investigating Protein Dynamics  

E-Print Network (OSTI)

Microfluidic Flow-Flash: Method for Investigating Protein Dynamics Michael W. Toepke, Scott H Institute, Troy, New York 12180 We report a new method, microfluidic flow-flash, for measuring protein reaction kinetics. The method couples a microscope imaging detection system with a microfluidic flow cell

Kenis, Paul J. A.

257

A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles  

Science Journals Connector (OSTI)

Abstract The high power density, ease of transportation and storage and many years of development of internal combustion engine technologies have put liquid hydrocarbon fuels at a privileged position in our energy mix. Therefore processes that use renewable energy sources to produce liquid hydrocarbon fuels from H2O and CO2 are of crucial importance. Concentrated Solar Power (CSP) can be employed as the only energy source for the renewable production of hydrogen from water either indirectly, e.g. by supplying the electricity for electrolysis, or directly by supplying the necessary heat for thermochemically producing hydrogen. Among the various thermochemical cycles tested so far for CSP-driven hydrogen production via water splitting (WS), those based on redox-pair oxide systems, are directly adaptable to carbon dioxide splitting (CDS) and/or combined CO2/H2O splitting for the production of CO or syngas, respectively. The acknowledgement of this fact has recently revived the interest of the scientific community on such technologies. The current article presents the development, evolution and current status of CSP-aided syngas production via such redox-pair-based thermochemical cycles. At first the various redox oxide material compositions tested for water/carbon dioxide splitting are presented and their redox chemistries are discussed. Then the selection of suitable solar reactors is addressed in conjunction with the boundary conditions imposed by the redox systems as well as the heat demands, technical peculiarities and requirements of the cycle steps. The various solar reactor concepts proposed and employed for such reactions and their current status of development are presented. Finally, topics where further work is needed for commercialization of the technology are identified and discussed.

Christos Agrafiotis; Martin Roeb; Christian Sattler

2015-01-01T23:59:59.000Z

258

Low volume flow meter  

DOE Patents (OSTI)

The low flow monitor provides a means for determining if a fluid flow meets a minimum threshold level of flow. The low flow monitor operates with a minimum of intrusion by the flow detection device into the flow. The electrical portion of the monitor is externally located with respect to the fluid stream which allows for repairs to the monitor without disrupting the flow. The electronics provide for the adjustment of the threshold level to meet the required conditions. The apparatus can be modified to provide an upper limit to the flow monitor by providing for a parallel electronic circuit which provides for a bracketing of the desired flow rate.

Meixler, Lewis D. (East Windsor, NJ)

1993-01-01T23:59:59.000Z

259

Amphiphilic mediated sample preparation for micro-flow cytometry  

DOE Patents (OSTI)

A flow cytometer includes a flow cell for detecting the sample, an oil phase in the flow cell, a water phase in the flow cell, an oil-water interface between the oil phase and the water phase, a detector for detecting the sample at the oil-water interface, and a hydrophobic unit operatively connected to the sample. The hydrophobic unit is attached to the sample. The sample and the hydrophobic unit are placed in an oil and water combination. The sample is detected at the interface between the oil phase and the water phase.

Clague, David S. (Livermore, CA); Wheeler, Elizabeth K. (Livermore, CA); Lee, Abraham P. (Irvine, CA)

2009-03-17T23:59:59.000Z

260

Amphiphilic mediated sample preparation for micro-flow cytometry  

DOE Patents (OSTI)

A flow cytometer includes a flow cell for detecting the sample, an oil phase in the flow cell, a water phase in the flow cell, an oil-water interface between the oil phase and the water phase, a detector for detecting the sample at the oil-water interface, and a hydrophobic unit operatively connected to the sample. The hydrophobic unit is attached to the sample. The sample and the hydrophobic unit are placed in an oil and water combination. The sample is detected at the interface between the oil phase and the water phase.

Clague, David S. (Livermore, CA); Wheeler, Elizabeth K. (Livermore, CA); Lee, Abraham P. (Irvine, CA)

2006-07-25T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Propeller Flow Meter  

E-Print Network (OSTI)

Propeller flow meters are commonly used to measure water flow rate. They can also be used to estimate irrigation water use. This publication explains how to select, install, read and maintain propeller flow meters....

Enciso, Juan; Santistevan, Dean; Hla, Aung K.

2007-10-01T23:59:59.000Z

262

Dispersed flow film boiling  

E-Print Network (OSTI)

Dispersed flow consists of small liquid droplets entrained in a flowing vapor. This flow regime can occur in cryogenic equipment, in steam generators, and during nuclear reactor loss of coolant accidents. A theoretical ...

Yoder, Graydon L.

1980-01-01T23:59:59.000Z

263

Bacteria in shear flow  

E-Print Network (OSTI)

Bacteria are ubiquitous and play a critical role in many contexts. Their environment is nearly always dynamic due to the prevalence of fluid flow: creeping flow in soil, highly sheared flow in bodily conduits, and turbulent ...

Marcos, Ph.D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

264

Cells having cathodes containing polycarbon disulfide materials  

DOE Patents (OSTI)

The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS.sub.x).sub.n, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode.

Okamoto, Yoshi (Fort Lee, NJ); Skotheim, Terje A. (Shoreham, NY); Lee, Hung S. (Rocky Point, NY)

1995-08-15T23:59:59.000Z

265

Cells having cathodes containing polycarbon disulfide materials  

DOE Patents (OSTI)

The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS{sub x}){sub n}, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode. 5 figs.

Okamoto, Y.; Skotheim, T.A.; Lee, H.S.

1995-08-15T23:59:59.000Z

266

Molecular Design and Performance of Hydroxylpyridium Sensitizers for Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

DSSCs have attracted more and more attention as an economical solar energy conversion device since ORegan and Grtzel reported them in 1991. ... In this work, comparisons of four dyes with the di(3-hexylthiophene), dihexyldithienosilole, dihexylcyclopentadithiophene and N-hexyldithienopyrrole linkers have revealed some general influences of ?-linker rigidification on the optoelectronic features of titania solar cells employing a cobalt(II/III) redox electrolyte, in terms of energetic and kinetic viewpoints. ... Even small structural changes of dyes result in significant changes in redox energies and adsorption manner of the dyes on TiO2 surface, affecting dramatically the performance of DSSCs based on these dyes. ...

Jianghua Zhao; Xichuan Yang; Ming Cheng; Shifeng Li; Licheng Sun

2013-05-21T23:59:59.000Z

267

Solar Cell Simulation  

K-12 Energy Lesson Plans and Activities Web site (EERE)

Students model the flow of energy from the sun as it enters a photovoltaic cell, moves along a wire and powers a load. The game-like atmosphere involves the younger students and helps them understand the continuous nature of the flow of energy. For a related lesson, please see the activity Solar Powered System (PDF 430 KB).

268

The effect of scaffold physical properties on endothelial cell function  

E-Print Network (OSTI)

Endothelial cells (EC) are ubiquitous - as vascular epithelial cells they line the inner surface of all vessels and are the contact surface with flowing blood. Macrovascular EC are the first line barrier between flowing ...

Murikipudi, Sylaja

2010-01-01T23:59:59.000Z

269

Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte  

Science Journals Connector (OSTI)

We report the design and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion membrane as the electrolyte. We studied the effect of cell resistance, hydrogen and oxygen flow rates, and electrolyte ...

Ranga S. Jayashree; Michael Mitchell; Dilip Natarajan; Larry J. Markoski; Paul J. A. Kenis

2007-05-19T23:59:59.000Z

270

Flow Distances on Open Flow Networks  

E-Print Network (OSTI)

Open flow network is a weighted directed graph with a source and a sink, depicting flux distributions on networks in the steady state of an open flow system. Energetic food webs, economic input-output networks, and international trade networks, are open flow network models of energy flows between species, money or value flows between industrial sectors, and goods flows between countries, respectively. Flow distances (first-passage or total) between any given two nodes $i$ and $j$ are defined as the average number of transition steps of a random walker along the network from $i$ to $j$ under some conditions. They apparently deviate from the conventional random walk distance on a closed directed graph because they consider the openness of the flow network. Flow distances are explicitly expressed by underlying Markov matrix of a flow system in this paper. With this novel theoretical conception, we can visualize open flow networks, calculating centrality of each node, and clustering nodes into groups. We apply fl...

Guo, Liangzhu; Shi, Peiteng; Wang, Jun; Huang, Xiaohan; Zhang, Jiang

2015-01-01T23:59:59.000Z

271

GEOC R Lee Penn Sunday, March 25, 2012 12 -Biogeochemical transformation of Fe-and Mn-along a redox gradient: Implications for carbon sequestration  

E-Print Network (OSTI)

a redox gradient: Implications for carbon sequestration within the Christina River Basin Critical Zone States Organic carbon (C)-mineral complexation mechanism is crucial in C sequestration. It is a function

Sparks, Donald L.

272

Methane-water redox reaction on A2SnO4 (A=Mg, Ca, Sr, Ba) oxide to produce C2 hydrocarbons  

Science Journals Connector (OSTI)

A2BO4...type oxides consisting of an alkali earth metal and tin showed high selectivity (>99%) and activity for the oxidative coupling of methane at 1023 K in a methane-water redox system where active oxygen spec...

K. Omata; T. Ehara; I. Kawai; M. Yamada

273

Probing Ligand Effects on the Redox Energies of [4Fe-4S] Clusters Using Broken-Symmetry Density Functional Theory  

SciTech Connect

A central issue in understanding redox properties of iron-sulfur proteins is determining the factors that tune the reduction potentials of the Fe-S clusters. Recently, Solomon and coworkers have shown that the Fe-S bond covalency of protein analogs measured by %L, the percent ligand character of the Fe 3d orbitals, from ligand K-edge X-ray absorption spectroscopy (XAS) correlates with the electrochemical redox potentials. Also, Wang and coworkers have measured electron detachment energies for iron-sulfur clusters without environmental perturbations by gas-phase photoelectron spectroscopy (PES). Here the correlations of the ligand character with redox energy and %L character are examined in [Fe?S?L?]2? clusters with different ligands by broken symmetry density functional theory (BS-DFT) calculations using the B3LYP functional together with PES and XAS experimental results. These gas-phase studies assess ligand effects independently of environmental perturbations and thus provide essential information for computational studies of iron-sulfur proteins. The B3LYP oxidation energies agree well with PES data, and the %L character obtained from natural bond orbital analysis correlates with XAS values, although it systematically underestimates them because of basis set effects. The results show that stronger electron-donating terminal ligands increase %Lt, the percent ligand character from terminal ligands, but decrease %Sb, the percent ligand character from the bridging sulfurs. Because the oxidized orbital has significant Fe-Lt antibonding character, the oxidation energy correlates well with %Lt. However, because the reduced orbital has varying contributions of both Fe-Lt and Fe-Sb antibonding character, the reduction energy does not correlate with either %Lt or %Sb. Overall, BSDFT calculations together with XAS and PES experiments can unravel the complex underlying factors in the redox energy and chemical bonding of the [4Fe-4S] clusters in iron-sulfur proteins.

Niu, Shuqiang; Ichiye, Toshiko

2009-05-14T23:59:59.000Z

274

Portable wastewater flow meter  

DOE Patents (OSTI)

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under fill pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1999-02-02T23:59:59.000Z

275

Portable wastewater flow meter  

DOE Patents (OSTI)

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under full pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1990-01-01T23:59:59.000Z

276

Effects of Protonation State on a Tyrosine?Histidine Bioinspired Redox Mediator  

SciTech Connect

The conversion of tyrosine to the corresponding tyrosyl radical in photosytem II (PSII) is an example of proton-coupled electron transfer. Although the tyrosine moiety (Tyr{sub Z}) is known to function as a redox mediator between the photo-oxidized primary donor (P680{sup +}) and the Mn-containing oxygen-evolving complex, the protonation states involved in the course of the reaction remain an active area of investigation. Herein, we report on the optical, structural, and electrochemical properties of tyrosine?histidine constructs, which model the function of their naturally occurring counterparts in PSII. Electrochemical studies show that the phenoxyl/phenol couple of the model is chemically reversible and thermodynamically capable of water oxidation. Studies under acidic and basic conditions provide clear evidence that an ionizable proton controls the electrochemical potential of the tyrosine?histidine mimic and that an exogenous base or acid can be used to generate a low-potential or high-potential mediator, respectively. The phenoxyl/phenoxide couple associated with the low-potential mediator is thermodynamically incapable of water oxidation, whereas the relay associated with the high-potential mediator is thermodynamically incapable of reducing an attached photoexcited porphyrin. These studies provide insight regarding the mechanistic role of the tyrosine?histidine complex in water oxidation and strategies for making use of hydrogen bonds to affect the coupling between proton and electron transfer in artificial photosynthetic systems.

Moore, Gary F.; Hambourger, Michael; Kodis, Gerdenis; Michl, Weston; Gust, Devens; Moore, Thomas A.; Moore, Ana L.

2010-01-01T23:59:59.000Z

277

Chelant extraction and REDOX manipulation for mobilization of heavy metals from contaminated soils  

SciTech Connect

Was the result of open burning and open detonation of chemical agents and munitions in the Toxic Burning Pits area at J-Field, located in the Edgewood Area of Aberdeen Proving Ground in Harford County, Maryland, soils have been contaminated with heavy metals. Simultaneous extraction is complicated because of the multitude of contaminant forms that exist. This paper uses data from a treatability study performed at Argonne National Laboratory to discuss and compare several treatment methods that were evaluated for remediating metals-contaminated soils. J-Field soils were subjected to a series of treatability experiments designed to determine the feasibility of using soil washing/soil flushing, enhancements to soil washing/soil flushing, solidification/stabilization, and electrokinetics for remediating soils contaminated with metals. Chelating and mobilizing agents evaluated included ammonium acetate, ethylenediaminetetraacetic acid, citric acid, Citranox, gluconic acid, phosphoric acid, oxalic acid, and nitrilotriacetic acid, in addition to pH-adjusted water. REDOX manipulation can maximize solubilities, increase desorption, and promote removal of heavy metal contaminants. Reducing agents that were studied included sodium borohydride, sodium metabisulfite, and thiourea dioxide. The oxidants studied included hydrogen peroxide, sodium percarbonate, sodium hypochlorite, and potassium permanganate. This paper summaries the results from the physical/chemical characterization, soil washing/soil flushing, and enhancements to soil washing/soil flushing portions of the study.

Brewster, M.D.; Peters, R.W.; Miller, G.A.; Patton, T.L.; Martino, L.E.

1994-12-01T23:59:59.000Z

278

Corrosion, Passivation, and the Effect of Water Addition on an n-GaAs(100)/Methanol Photoelectrochemical Cell  

E-Print Network (OSTI)

Corrosion, Passivation, and the Effect of Water Addition on an n-GaAs(100)/Methanol of corrosion of the cell on the PL-V profile is examined in detail. It is found that the inclusion of the redox couple gives some protection from corrosion, but the addition of a small amount of water

Richmond, Geraldine L.

279

Evaluating Charge Recombination Rate in Dye-Sensitized Solar Cells from Electronic Structure Calculations  

Science Journals Connector (OSTI)

Estimating the Maximum Attainable Efficiency in Dye-Sensitized Solar Cells ... Altogether, our study provides evidence that adsorption of the sensitizer via "three anchoring sites" is a key requisite to obtain high open-circuit potentials when employed in DSSC devices, thus paving the route to the design of new and more efficient sensitizers. ... cells are discussed, considering the high photovoltaic efficiencies obtained for devices employing Ru bipyridyl sensitizer dyes in combination with iodide/tri-iodide based redox electrolytes. ...

E. Maggio; N. Martsinovich; A. Troisi

2012-03-13T23:59:59.000Z

280

Optimization of channel geometry in a proton exchange membrane (PEM) fuel cell.  

E-Print Network (OSTI)

??Bipolar plates are the important components of the PEM fuel cell. The flow distribution inside the bipolar plate should be uniform. Non-uniform flow distribution inside (more)

Kasukurthi, Jephanya

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

How Fuel Cells Work  

NLE Websites -- All DOE Office Websites (Extended Search)

How Fuel Cells Work How Fuel Cells Work Diagram: How a PEM fuel cell works. 1. Hydrogen fuel is channeled through field flow plates to the anode on one side of the fuel cell, while oxygen from the air is channeled to the cathode on the other side of the cell. 2. At the anode, a platinum catalyst causes the hydrogen to split into positive hydrogen ions (protons) and negatively charged electrons. 3. The Polymer Electrolyte Membrane (PEM) allows only the positively charged ions to pass through it to the cathode. The negatively charged electrons must travel along an external circuit to the cathode, creating an electrical current. 4. At the cathode, the electrons and positively charged hydrogen ions combine with oxygen to form water, which flows out of the cell.

282

Cobalt(II/III) Redox Electrolyte in ZnO Nanowire-Based Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

Thus the present study opens new opportunities to improve energy conversion efficiency in ZnO-based DSCs. ... This allows the rational design and development of hierarchical ZnO nanostructures able to simultaneously optimize charge carrier path and dye loading. ... Finally, a series of Co(II)/Co(III) complexes are systematically investigated to gauge the impact of ligand substitution and of metal coordination (tris-bidentate vs. bis-tridentate) on the HS/LS energy difference and reorganization energies. ...

Jiandong Fan; Yan Hao; Andreu Cabot; Erik M. J. Johansson; Gerrit Boschloo; Anders Hagfeldt

2013-02-28T23:59:59.000Z

283

Cell Isolation and Systems Analysis | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

and Microfabrication Mass Spectrometry Microscopy Molecular Science Computing NMR and EPR Spectroscopy and Diffraction Subsurface Flow and Transport Cell Isolation and Systems...

284

Redox-active tyrosine residue in the microcin J25 molecule  

SciTech Connect

Research highlights: {yields} Cyclic voltammetry measurements showed irreversible oxidation of MccJ25 and MccJ25 (Y9F). {yields} Infrared spectroscopy studies showed that only Tyr9 could be deprotonated upon chemical oxidation. {yields} Formation of a long-lived tyrosyl radical in the native MccJ25 oxidized by H{sub 2}O{sub 2} was demonstrated. {yields} Tyr9 but not Tyr20 can be easily oxidized and form a tyrosyl radical. -- Abstract: Microcin J25 (MccJ25) is a 21 amino acid lasso-peptide antibiotic produced by Escherichia coli and composed of an 8-residues ring and a terminal 'tail' passing through the ring. We have previously reported two cellular targets for this antibiotic, bacterial RNA polymerase and the membrane respiratory chain, and shown that Tyr9 is essential for the effect on the membrane respiratory chain which leads to superoxide overproduction. In the present paper we investigated the redox behavior of MccJ25 and the mutant MccJ25 (Y9F). Cyclic voltammetry measurements showed irreversible oxidation of both Tyr9 and Tyr20 in MccJ25, but infrared spectroscopy studies demonstrated that only Tyr9 could be deprotonated upon chemical oxidation in solution. Formation of a long-lived tyrosyl radical in the native MccJ25 oxidized by H{sub 2}O{sub 2} was demonstrated by Electron Paramagnetic Resonance Spectroscopy; this radical was not detected when the reaction was carried out with the MccJ25 (Y9F) mutant. These results show that the essential Tyr9, but not Tyr20, can be easily oxidized and form a tyrosyl radical.

Chalon, Miriam C. [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)] [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina); Wilke, Natalia [CIQUIBIC, Dpto. de Quimica Biologica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Pabellon Argentina, Ciudad Universitaria, X5000HUA, Cordoba (Argentina)] [CIQUIBIC, Dpto. de Quimica Biologica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Pabellon Argentina, Ciudad Universitaria, X5000HUA, Cordoba (Argentina); Pedersen, Jens; Rufini, Stefano [Department of Biology, University of Rome Tor Vergata 00133, Rome (Italy)] [Department of Biology, University of Rome Tor Vergata 00133, Rome (Italy); Morero, Roberto D.; Cortez, Leonardo; Chehin, Rosana N.; Farias, Ricardo N. [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)] [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina); Vincent, Paula A., E-mail: pvincent@fbqf.unt.edu.ar [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)

2011-03-18T23:59:59.000Z

285

Characterization Studies of Materials and Devices used for Electrochemical Energy Storage  

E-Print Network (OSTI)

solar and wind energy requires some form of energy storage,solar cells, fuel cells, redox flow batteries and electrochemical energy storage.energy generation and storage technologies. Dye Sensitized Solar

Membreno, Daniel Eduardo

2014-01-01T23:59:59.000Z

286

Plastic Flow in Glass  

Science Journals Connector (OSTI)

...1964 research-article Plastic Flow in Glass D. M. Marsh The classical brittle fracture...account for the mechanical properties of glasses, but the widespread evidence of plastic flow in all glass fracture phenomena even at room temperature...

1964-01-01T23:59:59.000Z

287

Ultrasonic flow metering system  

DOE Patents (OSTI)

A system for determining the density, flow velocity, and mass flow of a fluid comprising at least one sing-around circuit that determines the velocity of a signal in the fluid and that is correlatable to a database for the fluid. A system for determining flow velocity uses two of the inventive circuits with directional transmitters and receivers, one of which is set at an angle to the direction of flow that is different from the others.

Gomm, Tyler J. (Meridian, ID); Kraft, Nancy C. (Idaho Falls, ID); Mauseth, Jason A. (Pocatello, ID); Phelps, Larry D. (Pocatello, ID); Taylor, Steven C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

288

Elbow mass flow meter  

DOE Patents (OSTI)

Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

1994-01-01T23:59:59.000Z

289

Thermodynamic Analysis of Syngas Production via the Solar Thermochemical Cerium Oxide Redox Cycle with Methane-Driven Reduction  

Science Journals Connector (OSTI)

Thermodynamic Analysis of Syngas Production via the Solar Thermochemical Cerium Oxide Redox Cycle with Methane-Driven Reduction ... Of particular interest is the storage of solar energy in chemical bonds via the splitting of water and carbon dioxide to produce hydrogen and carbon monoxide, referred to collectively as syngas. ... The coupled cycle produces high-quality syngas by the partial oxidation of methane in the ceria reduction step in addition to the carbon monoxide and hydrogen produced by splitting carbon dioxide and water in the oxidation step. ...

Peter T. Krenzke; Jane H. Davidson

2014-05-16T23:59:59.000Z

290

A New Approach to Computing Max Flows using Electrical Flows  

E-Print Network (OSTI)

A New Approach to Computing Max Flows using Electrical Flows Yin Tat Lee (MIT) Satish Rao (UC-Kelner-Madry-Spielman-Teng'11]: approximate flow in time Uses electrical flows. 7 #12;Electrical Flows 3 1 S t 8 #12;Electrical Flows Identify Graph with Resistor Network R(e)=1/w(e) 1/3 S t 1 9 #12;Electrical Flows Electrical flow

Rajamani, Sriram K.

291

Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries  

Energy.gov (U.S. Department of Energy (DOE))

Partnered with NETZSCH, the National Renewable Energy Laboratory (NREL) developed an Isothermal Battery Calorimeter (IBC) used to quantify heat flow in battery cells and modules.

292

E-Print Network 3.0 - altered blood flow Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

S. Popel, Marcos Intaglietta and Paul C. Johnson of red blood cells flowing... . Armstrong, H. J. Meiselman and O. K. Baskurt Graded alterations of RBC aggregation influence...

293

Low flow fume hood  

DOE Patents (OSTI)

A fume hood is provided having an adequate level of safety while reducing the amount of air exhausted from the hood. A displacement flow fume hood works on the principal of a displacement flow which displaces the volume currently present in the hood using a push-pull system. The displacement flow includes a plurality of air supplies which provide fresh air, preferably having laminar flow, to the fume hood. The displacement flow fume hood also includes an air exhaust which pulls air from the work chamber in a minimally turbulent manner. As the displacement flow produces a substantially consistent and minimally turbulent flow in the hood, inconsistent flow patterns associated with contaminant escape from the hood are minimized. The displacement flow fume hood largely reduces the need to exhaust large amounts of air from the hood. It has been shown that exhaust air flow reductions of up to 70% are possible without a decrease in the hood's containment performance. The fume hood also includes a number of structural adaptations which facilitate consistent and minimally turbulent flow within a fume hood.

Bell, Geoffrey C. (Pleasant Hill, CA); Feustel, Helmut E. (Albany, CA); Dickerhoff, Darryl J. (Berkeley, CA)

2002-01-01T23:59:59.000Z

294

Simulating Nonuniform Properties in Polymer-Electrolyte Fuel Cells  

E-Print Network (OSTI)

IN POLYMER-ELECTROLYTE FUEL CELLS A. Z. Weber and J. Newmanvapor flow throughout all of the fuel-cell sandwich layers,of the membrane thickness in fuel-cell water management. The

Weber, A.Z.; Newman, J.

2006-01-01T23:59:59.000Z

295

Brief Communications Optic Flow Stimuli Update Anterodorsal Thalamus Head  

E-Print Network (OSTI)

orientation in the yaw plane relative to environmental landmark cues. Head movements provoke optic field flow)istheonlyknownprojectionofheaddirectioninformationtoentorhinalgridcellsandhippocampalplacecells,yawplaneoptic flow signals likely influence representations in this spatial reference coordinate system to the body, independently of the ani- mal's ongoing behavior and of its spatial location. The HD cell system

Arleo, Angelo

296

A non-perturbative anemometric and flow visualization technique (~)  

E-Print Network (OSTI)

are based on the periodic injection Fig. 1. - In the Poiseuille flow cell (C) a thermal grating G is formed present a new visualization technique of an hydrodynamic flow using a thermal grid, « written not washed away the lines. The letter discusses a related technique - in which a thermal grid is « written

Boyer, Edmond

297

LM-MHD free-surface flow experiments in MTOR  

E-Print Network (OSTI)

LM-MHD free-surface flow experiments in MTOR Neil Morley for the APEX Participants VLT Conference concentrators · Free jet · Recirculating cell · Soaker Hose (not discussed here) Slide 5 #12;LM In LM Out #12;LM Jet test for NSTX module simulation · Jet flow is introduced into the high field region between

California at Los Angeles, University of

298

Structural, chemical, and electrochemical characteristics of LaSr2Fe2CrO9--based solid oxide fuel cell anodes  

E-Print Network (OSTI)

Available online 5 March 2012 Keywords: Solid oxide fuel cell Perovskite Oxide anode Redox Sulfur tolerance Solid oxide fuel cells with LaSr2Fe2CrO9-­Gd0.1Ce0.9O2- composite anodes were tested in H2, H2S-of-the-art solid oxide fuel cell (SOFC) anode is Ni-8-mole% yttria stabilized zirconia (YSZ), which performs very

Poeppelmeier, Kenneth R.

299

FLOW CONDITIONING DESIGN IN TURBULENT  

E-Print Network (OSTI)

for HYLIFE-II · Measure loss coefficient across the flow conditioner / nozzle assembly for different flow conditioner configurations #12;5 Flow Loop A Pump H 400 gal tank B Bypass line I Butterfly valve C Flow meter

300

ESS 2012 Peer Review - Advanced Materials for Flow Batteries - Travis Anderson, SNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Materials for Advanced Materials for Flow Batteries Friday, September 28, 2012 Travis M. Anderson and Harry D. Pratt III Sandia National Laboratories Ionic Liquid Flow Batteries MetIL - + MetIL * 59 mV/n separation (ideally n > 1) * Viscosity < 500 cP * Conductivity > 0.5 mS cm -1 * Open Circuit Potential > 1.5 V Problem: Getting high concentrations of redox active species. MetILs * Transition Metal Cation * Weakly Coordinating Anions * Alkanolamine Ligands * Negligible Vapor Pressure * Non-toxic 2 FY12 Milestones Approach: Design electrolytes with charge storage species as part of their chemical composition. Energy Density/Costs SNL APPROACH: Consider a compound CuL 2 BF 4 (L = methanolamine, MW = 47 g/mol), measured density 1.6 g/mL, formula weight,

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Effects of Dioxin on Clock, Melatonin Biosynthetic, and Redox Sensitive Genes on Chick Pinealocytes In Vitro  

E-Print Network (OSTI)

It has been speculated that dioxin treatment can modulate circadian rhythms. Cytochrome P4501A (CYP1A) is strongly induced by the xenobiotic dioxin via activation of arylhydrocarbon receptors within cells. Furthermore, regulation of CYP1A has been...

Hunt, Jayme

2006-07-11T23:59:59.000Z

302

Turbulent flow in graphene  

E-Print Network (OSTI)

We demonstrate the possibility of a turbulent flow of electrons in graphene in the hydrodynamic region, by calculating the corresponding turbulent probability density function. This is used to calculate the contribution of the turbulent flow to the conductivity within a quantum Boltzmann approach. The dependence of the conductivity on the system parameters arising from the turbulent flow is very different from that due to scattering.

Kumar S. Gupta; Siddhartha Sen

2009-11-03T23:59:59.000Z

303

High-resolution analysis with novel cell-surface markers identifies routes to iPS cells  

Science Journals Connector (OSTI)

... 10?days after cell sorting. All flow cytometry data were analysed using FlowJo (Tree Star). Immunofluorescence was carried out using confocal microscopy (Leica TSC SP2). RNA from ... fluorophore are summarized in Supplementary Table 9. Data were analysed using FlowJo software (Tree Star). Intact cells were identified based on forward and side light scatter, and subsequently ...

James OMalley; Stavroula Skylaki; Kumiko A. Iwabuchi; Eleni Chantzoura; Tyson Ruetz; Anna Johnsson; Simon R. Tomlinson; Sten Linnarsson; Keisuke Kaji

2013-06-02T23:59:59.000Z

304

Muffler Theory Considering Flow  

Science Journals Connector (OSTI)

The effect of a steady subsonic flow component upon the acoustical properties of pipes and of laminar and turbulent flow resistances is accounted for in an elementary fashion. The effect of the alternating or acoustic component upon the steady?flow properties is treated likewise. Acoustic transmission loss referred to the end radiation from a pipe is related to back pressure (increase in steady pressure due to the muffler). Equivalent circuits and diagrams of transmission loss vs back pressure are presented for some simple arrangements of pipes volumes irises and flow resistances.

Ewald Eichler

1962-01-01T23:59:59.000Z

305

Elbow mass flow meter  

DOE Patents (OSTI)

The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

1994-08-16T23:59:59.000Z

306

Instream Flow Project  

Energy.gov (U.S. Department of Energy (DOE))

As a part of the Department of Energys Water Power Program, the Instream Flow Project was carried out by Oak Ridge National Laboratory, Pacific Northwest National Laboratory, and Argonne National Laboratory to develop tools aimed at defining environmental flow needs for hydropower operations.

307

Productivity & Energy Flow  

E-Print Network (OSTI)

1 Productivity & Energy Flow Ecosystem approach, focuses: on flow of energy, water, and nutrients (capture) of energy by autotrophs Gross (total) Net (total ­ costs) Secondary productivity- capture of energy by herbivores http://sciencebitz.com/?page_id=204 What Controls the Primary Productivity

Mitchell, Randall J.

308

Development of electrochemical photovoltaic cells. Third technical progress report, November 1, 1979-January 31, 1980  

SciTech Connect

The development of stable, efficient, electrochemical photovoltaic cells based on silicon and gallium arsenide in non-aqueous electrolyte systems is being investigated. The effect of surface condition of silicon electrodes on electrochemical and physical characteristics has been studied. An electrode-supporting electrolyte interaction in acetonitrile has been identified which leads to etching of the surface. Improved performance can result, which has practical significance. Gallium arsenide electrodes have been electrochemically characterized in cells containing propylene carbonate with a ferrocene/ferricenium redox additive. Degradation of the ferricenium salt under illumination has been investigated. Other redox couples studied to date have not given promising results. Long-term stability experiments have been deferred while a better understanding of electrode behavior is being obtained.

Byker, H.J.; Schwerzel, R.E.; Wood, V.E.; Austin, A.E.; Brooman, E.W.

1980-03-07T23:59:59.000Z

309

Scalable High-Power Redox Capacitors with Aligned Nanoforests of Crystalline MnO2 Nanorods by High Voltage Electrophoretic Deposition  

Science Journals Connector (OSTI)

Scalable High-Power Redox Capacitors with Aligned Nanoforests of Crystalline MnO2 Nanorods by High Voltage Electrophoretic Deposition ... The scalable nanomanufacturing process is demonstrated by roll-printing an aligned forest of ?-MnO2 nanorods on a large flexible substrate (1 inch by 1 foot). ...

Sunand Santhanagopalan; Anirudh Balram; Dennis Desheng Meng

2013-02-01T23:59:59.000Z

310

Digital Deposition of Ultrathin Pd Films on Well-Defined Pt(111) Electrodes via Surface-Limited Redox Replacement Reaction: An Electron Spectroscopy-Electrochemistry Study  

E-Print Network (OSTI)

In this study, ultrathin (submonolayer to eight-monolayer) Pd films were deposited one layer at a time on well-defined Pt(111) surfaces via a process known as surface-limited redox replacement reaction (SLR^3). In this digital-deposition method, one...

Hossain, Mohammad

2010-12-04T23:59:59.000Z

311

Solar Syngas Production via H2O/CO2-Splitting Thermochemical Cycles with Zn/ZnO and FeO/Fe3O4 Redox Reactions  

Science Journals Connector (OSTI)

Solar Syngas Production via H2O/CO2-Splitting Thermochemical Cycles with Zn/ZnO and FeO/Fe3O4 Redox Reactions ... The first step, driven by concentrated solar radiation, is the endothermic thermolysis of ZnO producing a gaseous mixture of O2 and ... ...

A. Stamatiou; P. G. Loutzenhiser; A. Steinfeld

2009-08-28T23:59:59.000Z

312

Structural basis of inter-domain electron transfer in Ncb5or, a redox enzyme implicated in diabetes and lipid metabolism  

E-Print Network (OSTI)

NADH cytochrome b5 oxidoreductase (Ncb5or) is a multi-domain redox enzyme found in all animal tissues and associated with the endoplasmic reticulum (ER). Ncb5or contains (from N-terminus to C terminus) a novel N-terminal region, the b5 domain (Ncb5...

Deng, Bin

2011-12-31T23:59:59.000Z

313

Computational Biorheology of Human Blood Flow in Health and Disease DMITRY A. FEDOSOV,1  

E-Print Network (OSTI)

with results obtained using this computational framework for blood flow in malaria and sickle cell anemia. Keywords--Hematologic disorders, Dissipative particle dynamics, Coarse-graining, Malaria, Sickle cell in the later stages of the intra-cell parasite development.36 Sickle cell anemia is another blood disorder

Dao, Ming

314

Elliptic flow phenomenon at ATLAS  

E-Print Network (OSTI)

We summarize measurements of elliptic flow and higher order flow harmonics performed by the ATLAS experiment at the LHC. Results on event-averaged flow measurements and event-plane correlations in Pb+Pb collisions are discussed along with the event-by-event flow measurements. Further, we summarize results on flow in p+Pb collisions.

Martin Spousta

2014-06-20T23:59:59.000Z

315

Electron Flow in Multiheme Bacterial Cytochromes is a Balancing...  

NLE Websites -- All DOE Office Websites (Extended Search)

cofactors in the recently crystallized outer membrane cytochrome MtrF. The combination of electronic coupling matrix elements with free energy calculations of heme redox potentials...

316

Hydrogen Production via Chemical Looping Redox Cycles Using Atomic Layer Deposition-Synthesized Iron Oxide and Cobalt Ferrites  

Science Journals Connector (OSTI)

Hydrogen Production via Chemical Looping Redox Cycles Using Atomic Layer Deposition-Synthesized Iron Oxide and Cobalt Ferrites ... Unlike solution and line-of-sight methods used to synthesize metal-substituted ferrites, including solution combustion synthesis,(6) aerial oxidation of aqueous suspensions,(5) sol?gel process,(8) laser molecular beam epitaxy,(21) sputtering,(22) and chemical vapor deposition (CVD),(23) ALD can produce conformal thin films on porous materials. ... The drop in peak H2 production rate is accompanied by a ?55% decrease in the total amount of H2 produced (see Table 1) and a similar decrease in the time required to achieve 95% conversion, suggesting a loss of accessible iron in this material. ...

Jonathan R. Scheffe; Mark D. Allendorf; Eric N. Coker; Benjamin W. Jacobs; Anthony H. McDaniel; Alan W. Weimer

2011-03-24T23:59:59.000Z

317

Intermolecular Interactions in Dye-Sensitized Solar Cells: A Computational Modeling Perspective  

Science Journals Connector (OSTI)

(10-14) Fully organic sensitizers have been developed as metal-free dyes because of their increased molar extinction coefficient, compared to Ru(II) dyes, spectral tunability, and reduced environmental impact. ... The advantage of this new generation of solar cells is that they can be produced at low cost, i.e., potentially generated a high-efficiency (20-30% quantum efficiency) cathodic photocurrent and a significant photovoltaic effect in reversible Fe2+/Fe3+ redox soln. ...

Mariachiara Pastore; Filippo De Angelis

2013-02-28T23:59:59.000Z

318

Redox cycle stability of mixed oxides used for hydrogen generation in the cyclic water gas shift process  

SciTech Connect

Graphical abstract: - Highlights: Fe{sub 2}O{sub 3} modified with CaO, SiO{sub 2} and Al{sub 2}O{sub 3} was studied in cyclic water gas shift reactor. For the first time stability of such oxides were tested for 100 redox cycles. Optimally added oxides significantly improved the activity and the stability of Fe{sub 2}O{sub 3}. Increased stability was attributed to the impediment of neck formation. - Abstract: Repeated cycles of the reduction of Fe{sub 3}O{sub 4} with reductive gas, e.g. hydrogen and subsequent oxidation of the reduced iron material with water vapor can be harnessed as a process for the production of pure hydrogen. The redox behavior of iron oxide modified with various amounts of SiO{sub 2}, CaO and Al{sub 2}O{sub 3} was investigated in the present study. The total amount of the additional metal oxides was always below 15 wt%. The samples were prepared by co-precipitation using urea hydrolysis method. The influence of various metal oxides on the hydrogen production capacity and the material stability was studied in detail in terms of temperature-programmed reduction (TPR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET analysis. Furthermore, the activity and the stability of the samples were tested in repeated reduction with diluted H{sub 2} and re-oxidation cycles with H{sub 2}O. The results indicate that combination of several oxides as promoter increases the stability of the iron oxide material by mitigating the sintering process. The positive influence of the oxides in stabilizing the iron oxide material is attributed to the impediment of neck formation responsible for sintering.

Datta, Pradyot, E-mail: pradyot.datta@gmail.com

2013-10-15T23:59:59.000Z

319

Controlled Assembly of Heterobinuclear Sites on Mesoporous Silica: Visible Light Charge-Transfer Units with Selectable Redox Properties  

SciTech Connect

Mild synthetic methods are demonstrated for the selective assembly of oxo-bridged heterobinuclear units of the type TiOCrIII, TiOCoII, and TiOCeIII on mesoporous silica support MCM-41. One method takes advantage of the higher acidity and, hence, higher reactivity of titanol compared to silanol OH groups towards CeIII or CoII precursor. The procedure avoids the customary use of strong base. The controlled assembly of the TiOCr system exploits the selective redox reactivity of one metal towards another (TiIII precursor reacting with anchored CrVI centers). The observed selectivity for linking a metal precursor to an already anchored partner versus formation of isolated centers ranges from a factor of six (TiOCe) to complete (TiOCr, TiOCo). Evidence for oxo bridges and determination of the coordination environment of each metal centers is based on K-edge EXAFS (TiOCr), L-edge absorption spectroscopy (Ce), and XANES measurements (Co, Cr). EPR, optical, FT-Raman and FT-IR spectroscopy furnish additional details on oxidation state and coordination environment of donor and acceptor metal centers. In the case of TiOCr, the integrity of the anchored group upon calcination (350 oC) and cycling of the Cr oxidation state is demonstrated. The binuclear units possess metal-to-metal charge-transfer transitions that absorb deep in the visible region. The flexible synthetic method for assembling the units opens up the use of visible light charge transfer pumps featuring donor or acceptor metals with selectable redox potential.

Frei, Heinz; Han, Hongxian; Frei, Heinz

2008-06-04T23:59:59.000Z

320

Fuel Cells publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science » Materials Science » Fuel Cells » Fuel Cells Publications Fuel Cells publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Melissa Fox Applied Energy Email Catherine Padro Sensors & Electorchemical Devices Email Fernando Garzon Sensors & Electorchemical Devices Email Piotr Zelenay Sensors & Electorchemical Devices Email Rod Borup Sensors & Electorchemical Devices Email Karen E. Kippen Chemistry Communications Email Like a battery, a fuel cell consists of two electrodes separated by an electrolyte-in polymer electrolyte fuel cells, the separator is made of a thin polymeric membrane. Unlike a battery, a fuel cell does not need recharging-it continues to produce electricity as long as fuel flows

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Multiphase Flow Modeling Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Science Chris Guenther, Director Computational Science Division RUA Spring Meeting, Morgantown, WV March 2013 2 NETL's Multiphase Flow Science Team * The Multiphase Flow Science Team develops physics-based simulation models to conduct applied scientific research. - Development of new theory - Extensive on-site and collaborative V&V efforts and testing - Engages in technology transfer - Applies the models to industrial scale problems. 3 Why is Multiphase Flow Science Needed? * Industry is increasingly relying on multiphase technologies to produce clean and affordable energy with carbon capture. * Unfortunately, the presence of a solid phase reduces the operating capacity of a typical energy device from its original design on average by 40% [1].

322

Shroud leakage flow discouragers  

DOE Patents (OSTI)

A turbine assembly includes a plurality of rotor blades comprising a root portion, an airfoil having a pressure sidewall and a suction sidewall, and a top portion having a cap. An outer shroud is concentrically disposed about said rotor blades, said shroud in combination with said tip portions defining a clearance gap. At least one circumferential shroud leakage discourager is disposed within the shroud. The leakage discourager(s) increase the flow resistance and thus reduce the flow of hot gas flow leakage for a given pressure differential across the clearance gap to improve overall turbine efficiency.

Bailey, Jeremy Clyde (Middle Grove, NY); Bunker, Ronald Scott (Niskayuna, NY)

2002-01-01T23:59:59.000Z

323

Bypass Flow Study  

SciTech Connect

The purpose of the fluid dynamics experiments in the MIR (Matched Index of-Refraction) flow system at Idaho National Laboratory (INL) is to develop benchmark databases for the assessment of Computational Fluid Dynamics (CFD) solutions of the momentum equations, scalar mixing, and turbulence models for the flow ratios between coolant channels and bypass gaps in the interstitial regions of typical prismatic standard fuel element (SFE) or upper reflector block geometries of typical Modular High-temperature Gas-cooled Reactors (MHTGR) in the limiting case of negligible buoyancy and constant fluid properties. The experiments use Particle Image Velocimetry (PIV) to measure the velocity fields that will populate the bypass flow study database.

Richard Schultz

2011-09-01T23:59:59.000Z

324

Magnetically stimulated fluid flow patterns  

ScienceCinema (OSTI)

Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

Martin, Jim; Solis, Kyle

2014-08-06T23:59:59.000Z

325

A New Direction in Dye-Sensitized Solar Cells Redox Mediator Development: In Situ Fine-Tuning of the Cobalt(II)/(III) Redox Potential through Lewis Base Interactions  

Science Journals Connector (OSTI)

Representative orange or orange-red prismatic crystals of 2a, 3a, and 3b were mounted on an Oxford Gemini Ultra CCD diffractometer equipped with an Oxford Cryosystems 700 Cryostream and cooled to 123(1) K. Data were collected with Mo K? radiation (? = 0.71073 ) and processed with CrysAlisPro software; Lorentz, polarization, and absorption corrections (multiscan) were applied. ... Optimized nanostructure sensitized with MK-2 dye shows efficiency of 5.5% at 1 sun. ...

Muhammad K. Kashif; Jordan C. Axelson; Noel W. Duffy; Craig M. Forsyth; Christopher J. Chang; Jeffrey R. Long; Leone Spiccia; Udo Bach

2012-09-11T23:59:59.000Z

326

RMOTC - Testing - Flow Assurance  

NLE Websites -- All DOE Office Websites (Extended Search)

Flow Assurance Flow Assurance RMOTC Flow Loop Facility Layout Notice: As of July 15th 2013, the Department of Energy announced the intent to sell Naval Petroleum Reserve Number 3 (NPR3). The sale of NPR-3 will also include the sale of all equipment and materials onsite. A decision has been made by the Department of Energy to complete testing at RMOTC by July 1st, 2014. RMOTC will complete testing in the coming year with the currently scheduled testing partners. For more information on the sale of NPR-3 and sale of RMOTC equipment and materials please join our mailing list here. Over a decade ago, RMOTC began cooperatively building a full-scale facility to test new flow assurance technology, mainly in the areas of hydrates and paraffins. Today, RMOTC's test facility consists of five individual loop

327

Holographic supersymmetric membrane flows  

Science Journals Connector (OSTI)

The M-theory lift of SU(3) ? U(1)R-invariant RG flow via a combinatorical use of the four-dimensional flow and 11-dimensional EinsteinMaxwell equations was found previously. By taking the three internal coordinates differently and preserving only the SU(3) symmetry from the CP2 space, we find a new 11-dimensional solution of the SU(3)-invariant RG flow interpolating from the SO(8)-invariant UV fixed point to the SU(3) ? U(1)R-invariant IR fixed point in four dimensions. We describe how the corresponding three-dimensional superconformal ChernSimons matter theory deforms. By replacing the above CP2 space with the EinsteinKahler twofold, we also find out a new 11-dimensional solution of the SU(2) ? U(1)-invariant RG flow connecting the above two fixed points in four dimensions.

Changhyun Ahn; Kyungsung Woo

2010-01-01T23:59:59.000Z

328

Optical flow switching  

E-Print Network (OSTI)

Present-day networks are being challenged by dramatic increases in bandwidth demand of emerging applications. We will explore a new transport, ldquooptical flow switchingrdquo, that will enable significant growth and ...

Chan, Vincent W. S.

329

Olefin Autoxidation in Flow  

E-Print Network (OSTI)

Handling hazardous multiphase reactions in flow brings not only safety advantages but also significantly improved performance, due to better mass transfer characteristics. In this paper, we present a continuous microreactor ...

Neuenschwander, Ulrich

330

Energy Storage Systems 2014 Peer Review Presentations - Session...  

Energy Savers (EERE)

in PNNL's Mixed Acid Redox Flow Battery Stack - David Reed, PNNL Redox Flow Battery Optimization - Tom Zawodzinski, ORNL Ionic Liquid Flow Battery - Travis Anderson, Sandia...

331

Dissecting the regulatory microenvironment of a large animal model of non-Hodgkin lymphoma: evidence of a negative prognostic impact of FOXP3+ T cells in canine B cell lymphoma  

E-Print Network (OSTI)

, enlarged lymph node deposited into neat fetal bovine serum (PAA Laboratories Ltd, Yeovil, UK) for flow cytometry. Staining of cells for flow cytometry was performed within 48 hours of sample collection, followed by acquisition of the fixed cells within a...

Pinheiro, Dammy; Chang, Yu-Mei; Bryant, Hannah; Szladovits, Balazs; Dalessandri, Tim; Davison, Lucy J.; Yallop, Elizabeth; Mills, Emily; Leo, Chiara; Lara, Ana; Stell, Anneliese; Polton, Gerry; Garden, Oliver A.

2014-08-13T23:59:59.000Z

332

Multifunktionales Batteriespeichersystem  

Science Journals Connector (OSTI)

Die Pilotanlage besteht aus einer Vanadium-Redox-Flow-Batterie (VRF-Batterie) des Typs CellCube FB 10-100 mit einer Speicherkapazitt von...9]) (Abb.1). Abb.1. ...

Roland Sterrer; Wolfgang Prggler

2013-09-01T23:59:59.000Z

333

Dissipative flows of 2D foams  

E-Print Network (OSTI)

We analyze the flow of a liquid foam between two plates separated by a gap of the order of the bubble size (2D foam). We concentrate on the salient features of the flow that are induced by the presence, in an otherwise monodisperse foam, of a single large bubble whose size is one order of magnitude larger than the average size. We describe a model suited for numerical simulations of flows of 2D foams made up of a large number of bubbles. The numerical results are successfully compared to analytical predictions based on scaling arguments and on continuum medium approximations. When the foam is pushed inside the cell at a controlled rate, two basically different regimes occur: a plug flow is observed at low flux whereas, above a threshold, the large bubble migrates faster than the mean flow. The detailed characterization of the relative velocity of the large bubble is the essential aim of the present paper. The relative velocity values, predicted both from numerical and from analytical calculations that are discussed here in great detail, are found to be in fair agreement with experimental results.

Isabelle Cantat; Renaud Delannay

2005-07-21T23:59:59.000Z

334

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions  

SciTech Connect

The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of rechargeable lithium-air batteries. Here we employ a solid-state Li4+xTi5O12/LiPON/LixV2O5 cell and examine in situ the chemistry of Li-O2 reaction products on LixV2O5 as a function of applied voltage under ultra high vacuum (UHV) and near ambient-pressure of oxygen using X-ray photoelectron spectroscopy (APXPS). Oxygen reduction and evolution reactions take place on the surface of the mixed electronic and Li+ ionic conductor, LixV2O5, which eliminate parasitic reactions between oxygen reduction/evolution reaction intermediates and aprotic electrolytes used in Li-O2 batteries reported to date. Under UHV, reversible lithium intercalation and de-intercalation from LixV2O5 was noted, where the changes in the vanadium valence state revealed from XPS in this study were comparable to that reported previously from Li/LixV2O5 thin film batteries. In presence of oxygen near ambient pressure, the LixV2O5 surface was covered gradually by the reaction product of oxygen reduction, namely lithium peroxide (Li2O2) (approximately 1-2 unit cells) upon discharge. Interestingly, the LixV2O5 surface became re-exposed upon charging, and the oxidation of Li2O2 began at much lower overpotentials (~240 mV) than the charge overpotentials of Li-O2 cells (~1000 mV) with aprotic electrolytes, which can be attributed to subnanometer-thick Li2O2 with surfaces free of contaminants such as carbonate species. Our study provides first evidence of reversible lithium peroxide formation and decomposition in situ on an oxide surface using a solid-state cell, and new insights into the reaction mechanism of Li-O2 chemistry.

Lu, Yi-chun [Massachusetts Institute of Technology (MIT); Crumlin, Ethan [Massachusetts Institute of Technology (MIT); Veith, Gabriel M [ORNL; Harding, Jonathon [Massachusetts Institute of Technology (MIT); Dudney, Nancy J [ORNL; Liu, Zhi [Lawrence Berkeley National Laboratory (LBNL); Shao-Horn, Yang [Massachusetts Institute of Technology (MIT)

2012-01-01T23:59:59.000Z

335

Modeling the Process of Mining Silicon Through a Single Displacement/Redox Reaction  

K-12 Energy Lesson Plans and Activities Web site (EERE)

As the popularity of photovoltaic (PV) cells and integrated circuits (IC) increases, the need for silicon also increases. Silicon is one of the most used materials in these two industries. It is an inexpensive and abundant semiconductor. However, the process of producing pure silicon adds cost, and it is generally unknown to the public. One of the first steps in producing silicon is a process called carbon-thermic reduction. Silicon dioxide (SiO2) that is found in beach sand and quartz is melted down in a caldron at a temperature of 1450 degrees Celsius.

336

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry  

E-Print Network (OSTI)

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry using energy flow method Azimuthal angle distribution at Q2 >100 GeV2 Energy flow method.Ukleja on behalf of the ZEUS Collaboration #12; Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I

337

Multi-processor including data flow accelerator module  

DOE Patents (OSTI)

An accelerator module for a data flow computer includes an intelligent memory. The module is added to a multiprocessor arrangement and uses a shared tagged memory architecture in the data flow computer. The intelligent memory module assigns locations for holding data values in correspondence with arcs leading to a node in a data dependency graph. Each primitive computation is associated with a corresponding memory cell, including a number of slots for operands needed to execute a primitive computation, a primitive identifying pointer, and linking slots for distributing the result of the cell computation to other cells requiring that result as an operand. Circuitry is provided for utilizing tag bits to determine automatically when all operands required by a processor are available and for scheduling the primitive for execution in a queue. Each memory cell of the module may be associated with any of the primitives, and the particular primitive to be executed by the processor associated with the cell is identified by providing an index, such as the cell number for the primitive, to the primitive lookup table of starting addresses. The module thus serves to perform functions previously performed by a number of sections of data flow architectures and coexists with conventional shared memory therein. A multiprocessing system including the module operates in a hybrid mode, wherein the same processing modules are used to perform some processing in a sequential mode, under immediate control of an operating system, while performing other processing in a data flow mode.

Davidson, George S. (Albuquerque, NM); Pierce, Paul E. (Albuquerque, NM)

1990-01-01T23:59:59.000Z

338

Bipolar Plate-Supported Solid Oxide Fuel Cell J. D. Carter, T. Cruse, J. Ralph,  

E-Print Network (OSTI)

Bipolar Plate-Supported Solid Oxide Fuel Cell "TuffCell" J. D. Carter, T. Cruse, J. Ralph, R. Kumar, and D. Myers Argonne National Laboratory Argonne, IL 2003 Annual Review DOE Fuel Cells Program May 19;Metallic Bipolar-Plate-Supported SOFC Design (TuffCell) Fuel flow field (metal) Air flow field (metal

339

EE580 Solar Cells Todd J. Kaiser  

E-Print Network (OSTI)

7/21/2010 1 EE580 ­ Solar Cells Todd J. Kaiser · Lecture 02 Microfabrication ­ A combination · Photolithograpy · Depostion · Etching 1 Montana State University: Solar Cells Lecture 2: Microfabrication Flow Montana State University: Solar Cells Lecture 2: Microfabrication Questions · What is heat? · Heat

Kaiser, Todd J.

340

Two-phase flow studies  

SciTech Connect

The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow problems of relevance to the geothermal industry. An important feature of the facility is that it is dedicated to two-phase flow of a single substance (including evaporation and condensation) as opposed to the case of a two-component two-phase flow. This facility can be operated with horizontal or vertical test sections of constant diameter or with step changes in diameter to simulate a geothermal well profile.

Hanold, R.J.

1983-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Evaluation of flow hood measurements for residential register flows  

SciTech Connect

Flow measurement at residential registers using flow hoods is becoming more common. These measurements are used to determine if the HVAC system is providing adequate comfort, appropriate flow over heat exchangers and in estimates of system energy losses. These HVAC system performance metrics are determined by using register measurements to find out if individual rooms are getting the correct airflow, and in estimates of total air handler flow and duct air leakage. The work discussed in this paper shows that commercially available flow hoods are poor at measuring flows in residential systems. There is also evidence in this and other studies that flow hoods can have significant errors even when used on the non-residential systems they were originally developed for. The measurement uncertainties arise from poor calibrations and the sensitivity of exiting flow hoods to non-uniformity of flows entering the device. The errors are usually large--on the order of 20% of measured flow, which is unacceptably high for most applications. Active flow hoods that have flow measurement devices that are insensitive to the entering airflow pattern were found to be clearly superior to commercially available flow hoods. In addition, it is clear that current calibration procedures for flow hoods may not take into account any field application problems and a new flow hood measurement standard should be developed to address this issue.

Walker, I.S.; Wray, C.P.; Dickerhoff, D.J.; Sherman, M.H.

2001-09-01T23:59:59.000Z

342

Flow Test | Open Energy Information  

Open Energy Info (EERE)

Flow Test Flow Test Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Flow Test Details Activities (38) Areas (33) Regions (1) NEPA(3) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Testing Techniques Parent Exploration Technique: Well Testing Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Flow tests provide information on permeability, recharge rates, reservoir pressures, fluid chemistry, and scaling. Thermal: Flow tests can measure temperature variations with time to estimate characteristics about the heat source. Dictionary.png Flow Test: Flow tests are typically conducted shortly after a well has been drilled to test its productivity. The well is opened and fluids are released, the

343

NREL: Learning - Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Fuel cells and their ability to cleanly produce electricity from hydrogen and oxygen are what make hydrogen attractive as a "fuel" for transportation use particularly, but also as a general energy carrier for homes and other uses, and for storing and transporting otherwise intermittent renewable energy. Fuel cells function somewhat like a battery-with external fuel being supplied rather than stored electricity-to generate power by chemical reaction rather than combustion. Hydrogen fuel cells, for instance, feed hydrogen gas into an electrode that contains a catalyst, such as platinum, which helps to break up the hydrogen molecules into positively charged hydrogen ions and negatively charged electrons. The electrons flow from the electrode to a terminal that

344

In situ PEM fuel cell water measurements  

SciTech Connect

Efficient PEM fuel cell performance requires effective water management. The materials used, their durability, and the operating conditions under which fuel cells run, make efficient water management within a practical fuel cell system a primary challenge in developing commercially viable systems. We present experimental measurements of water content within operating fuel cells. in response to operational conditions, including transients and freezing conditions. To help understand the effect of components and operations, we examine water transport in operating fuel cells, measure the fuel cell water in situ and model the water transport within the fuel cell. High Frequency Resistance (HFR), AC Impedance and Neutron imaging (using NIST's facilities) were used to measure water content in operating fuel cells with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable GDL properties. Ice formation in freezing cells was also monitored both during operation and shut-down conditions.

Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendalow, Jacob S [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

345

Electron Transfer Dynamics in Efficient Molecular Solar Cells  

SciTech Connect

This research provided new mechanistic insights into surface mediated photochemical processes relevant to solar energy conversion. In this past three years our research has focused on oxidation photo-redox chemistry and on the role surface electric fields play on basic spectroscopic properties of molecular-semiconductor interfaces. Although this research as purely fundamental science, the results and their interpretation have relevance to applications in dye sensitized and photogalvanic solar cells as well as in the storage of solar energy in the form of chemical bonds.

Meyer, Gerald John

2014-10-01T23:59:59.000Z

346

The effects of water radiolysis on local redox conditions in the Oklo, Gabon, natural fission reactors 10 and 16  

SciTech Connect

In an underground nuclear waste repository, the chemical behavior of some stored fission products and actinides depends on the redox conditions during their long-term evolution. In this respect, radiolysis is an important phenomenon which can significantly modify the local redox conditions. The Oklo natural fission zones are good examples where the effect of radiolysis can be deduced from a mineralogical and geochemical study. Zones 10 and 16 were studied because they are located at depth of 270 m in an area devoid of any recent water circulation and not subject to the effect of the lateritic alteration occurring elsewhere in this area. In zone 10, there is a marked evolution of the U-Pb-Fe-S mineralogy from the center to the periphery of the reactor zone. In the center, uraninite shows silicification and coffinitisation with the formation of galena and native lead; the PbO content of uraninite can be as much as 20 wt%. In the periphery of the reactor zone, some radiogenic lead is present as minimum (Pb{sub 3}O{sub 4}) and in Pb-bearing calcite. In the surrounding sandstones, hematite is widespread. In zone 16, the mineral paragenesis is generally comparable with that of zone 10 but with some differences. Galena is the only Pb-bearing mineral associated with uraninite crystals. The PbO content of uraninite is always <7 wt%. In the periphery of the alteration zone, barite partly replaces quartz. In the reactor zone, hematite is sometimes replaced by pyrite. In an area where the fission zone 10 is in contact with sandstones devoid of organic matter, H{sub 2}O-H{sub 2} {+-} CH{sub 4} inclusions were observed in healed microcracks in the detrital quartz grains. Based on microthermometric measurements, the salinity of the aqueous solution ranges from 0.2 to 18 wt% eq. NaCl. Raman analysis of the gas phase indicates that the hydrogen to oxygen ratio differs from an inclusion to the other. 41 refs., 15 figs., 3 tabs.

Savary, V.; Pagel, M. [CREGU and G.R. CNRS-CREGU, Vandoeuvre-les-Nancy (France)] [CREGU and G.R. CNRS-CREGU, Vandoeuvre-les-Nancy (France)

1997-11-01T23:59:59.000Z

347

Reduction of pertechnetate [Tc(VII)] by aqueous Fe(II) and the nature of solid phase redox products  

Science Journals Connector (OSTI)

The subsurface behaviour of 99Tc, a contaminant resulting from nuclear fuels reprocessing, is dependent on its valence (e.g., IV or VII). Abiotic reduction of soluble Tc(VII) by Fe(II)(aq) in pH 68 solutions was investigated under strictly anoxic conditions using an oxygen trap (<7.5נ10?9atmO2). The reduction kinetics were strongly pH dependent. Complete and rapid reduction of Tc(VII) to a precipitated Fe/Tc(IV) form was observed when 11?mol/L of Tc(VII) was reacted with 0.4mmol/L Fe(II) at pH 7.0 and 8.0, while no significant reduction was observed over 1 month at pH 6.0. Experiments conducted at pH 7.0 with Fe(II)(aq)=0.050.8mmol/L further revealed that Tc(VII) reduction was a combination of homogeneous and heterogeneous reaction. Heterogeneous reduction predominated after approximately 0.01mmol/L of Fe(II) was oxidized. The heterogeneous reaction was more rapid, and was catalyzed by Fe(II) that adsorbed to the Fe/Tc(IV) redox product. Wet chemical and FeX-ray absorption near edge spectroscopy measurements (XANES) showed that Fe(II) and Fe(III) were present in the Fe/Tc(IV) redox products after reaction termination. 57Fe-Mssbauer, extended X-ray adsorption fine structure (EXAFS), and transmission electron microscopy (TEM) measurements revealed that the Fe/Tc(IV) solid phase was poorly ordered and dominated by Fe(II)-containing ferrihydrite with minor magnetite. Tc(IV) exhibited homogeneous spatial distribution within the precipitates. According to Tc-EXAFS measurements and structural modeling, its molecular environment was consistent with an octahedral Tc(IV) dimer bound in bidentate edge-sharing mode to octahedral Fe(III) associated with surface or vacancy sites in ferrihydrite. The precipitate maintained Tc(IV)aq concentrations that were slightly below those in equilibrium with amorphous Tc(IV)O2nH2O(s). The oxidation rate of sorbed Tc(IV) in the Fe/Tc precipitate was considerably slower than Tc(IV)O2nH2O(s) as a result of its intraparticle/intragrain residence. Precipitates of this nature may form in anoxic sediments or groundwaters, and the intraparticle residence of sorbed/precipitated Tc(IV) may limit 99Tc remobilization upon the return of oxidizing conditions.

John M. Zachara; Steve M. Heald; Byong-Hun Jeon; Ravi K. Kukkadapu; Chongxuan Liu; James P. McKinley; Alice C. Dohnalkova; Dean A. Moore

2007-01-01T23:59:59.000Z

348

Heme Ligand Identification and Redox Properties of the Cytochrome c Synthetase, CcmF  

Science Journals Connector (OSTI)

Completely conserved amino acids (red) were identified by individual protein alignments using CcmF ORFs from the following organisms: the alpha proteobacteria, Agrobacterium tumefaciens C58, Rhodobacter capsulatus, Caulobacter crescentus CB15, and Bradyrhizobium japonicum; the beta proteobacteria, Nitrospira mutliformis ATCC 25196 and Nitrosomonas europaea ATCC 19718; the gamma proteobacteria, Escherichia coli K-12 MG1655, Pseudomonas fluorescens Pf01, Shewanella oneidensis MR-1, and Vibrio parahemolyticus RIMD 2210633; the delta proteobacteria, Myxococcus xanthus and Desulfovibrio desulfuricans; and the deinococci, Deinococcus geothermalis and Thermus thermophilus. ... Cells were disrupted by repeated sonication for 30 s bursts on a Branson 250 sonicator (50% duty, 60% output) until clearing of the suspension was observed. ... Ray, G. B., Li, X. Y., Ibers, J. A., Sessler, J. L., and Spiro, T. G. ( 1994) How far can proteins bend the FeCO unit? ...

Brian San Francisco; Eric C. Bretsnyder; Kenton R. Rodgers; Robert G. Kranz

2011-11-08T23:59:59.000Z

349

Workshop on hypersonic flow  

SciTech Connect

An overview is given of research activity on the application of computational fluid dynamics (CDF) for hypersonic propulsion systems. After the initial consideration of the highly integrated nature of air-breathing hypersonic engines and airframe, attention is directed toward computations carried out for the components of the engine. A generic inlet configuration is considered in order to demonstrate the highly three dimensional viscous flow behavior occurring within rectangular inlets. Reacting flow computations for simple jet injection as well as for more complex combustion chambers are then discussed in order to show the capability of viscous finite rate chemical reaction computer simulations. Finally, the nozzle flow fields are demonstrated, showing the existence of complex shear layers and shock structure in the exhaust plume. The general issues associated with code validation as well as the specific issue associated with the use of CFD for design are discussed. A prognosis for the success of CFD in the design of future propulsion systems is offered.

Povinelli, L.A.

1990-01-01T23:59:59.000Z

350

Friction and the oscillatory motion of granular flows  

E-Print Network (OSTI)

This contribution reports on numerical simulations of 2D granular flows on erodible beds. The broad aim is to investigate whether simple flows of model granular matter exhibits spontaneous oscillatory motion in generic flow conditions, and in this case, whether the frictional properties of the contacts between grains may affect the existence or the characteristics of this oscillatory motion. The analysis of different series of simulations show that the flow develops an oscillatory motion with a well-defined frequency which increases like the inverse of the velocity's square root. We show that the oscillation is essentially a surface phenomena. The amplitude of the oscillation is higher for lower volume fractions, and can thus be related to the flow velocity and grains friction properties. The study of the influence of the periodic geometry of the simulation cell shows no significant effect. These results are discussed in relation to sonic sands.

Lydie Staron

2012-11-26T23:59:59.000Z

351

Multiphase cooling flows  

E-Print Network (OSTI)

I discuss the multiphase nature of the intracluster medium whose neglect can lead to overestimates of the baryon fraction of clusters by up to a factor of two. The multiphase form of the cooling flow equations are derived and reduced to a simple form for a wide class of self-similar density distributions. It is shown that steady-state cooling flows are \\emph{not} consistent with all possible emissivity profiles which can therefore be used as a test of the theory. In combination, they provide strong constraints on the mass distribution within the cooling radius.

Peter A. Thomas

1996-08-20T23:59:59.000Z

352

Time-resolved fluorescence decay measurements for flowing particles  

DOE Patents (OSTI)

Time-resolved fluorescence decay measurements for flowing particles. An apparatus and method for the measurement and analysis of fluorescence for individual cells and particles in flow are described, wherein the rapid measurement capabilities of flow cytometry and the robust measurement and analysis procedures of time-domain fluorescence lifetime spectroscopy are combined. A pulse-modulated cw laser is employed for excitation of the particles. The characteristics and the repetition rate of the excitation pulses can be readily adjusted to accommodate for fluorescence decays having a wide range of lifetimes.

Deka, Chiranjit (Miami, FL); Steinkamp, John A. (Los Alamos, NM)

1999-01-01T23:59:59.000Z

353

Time-resolved fluorescence decay measurements for flowing particles  

DOE Patents (OSTI)

Time-resolved fluorescence decay measurements are disclosed for flowing particles. An apparatus and method for the measurement and analysis of fluorescence for individual cells and particles in flow are described, wherein the rapid measurement capabilities of flow cytometry and the robust measurement and analysis procedures of time-domain fluorescence lifetime spectroscopy are combined. A pulse-modulated CW laser is employed for excitation of the particles. The characteristics and the repetition rate of the excitation pulses can be readily adjusted to accommodate for fluorescence decays having a wide range of lifetimes. 12 figs.

Deka, C.; Steinkamp, J.A.

1999-06-01T23:59:59.000Z

354

Liquid-Water Uptake and Removal in PEM Fuel-Cell Components  

E-Print Network (OSTI)

Uptake and Removal in PEM Fuel-Cell Components Prodip K. DasWater management in PEM fuel cells is critical for optimumof droplet dynamics in PEM fuel-cell gas flow channels has

Das, Prodip K.

2013-01-01T23:59:59.000Z

355

Brassinosteroid-induced CO{sub 2} assimilation is associated with increased stability of redox-sensitive photosynthetic enzymes in the chloroplasts in cucumber plants  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Activity of certain Calvin cycle enzymes and CO{sub 2} assimilation are induced by BRs. Black-Right-Pointing-Pointer BRs upregulate the activity of the ascorbate-glutathione cycle in the chloroplasts. Black-Right-Pointing-Pointer BRs increase the chloroplast thiol reduction state. Black-Right-Pointing-Pointer A BR-induced reducing environment increases the stability of photosynthetic enzymes. -- Abstract: Brassinosteroids (BRs) play important roles in plant growth, development, photosynthesis and stress tolerance; however, the mechanism underlying BR-enhanced photosynthesis is currently unclear. Here, we provide evidence that an increase in the BR level increased the quantum yield of PSII, activities of Rubisco activase (RCA) and fructose-1,6-bisphosphatase (FBPase), and CO{sub 2} assimilation. BRs upregulated the transcript levels of genes and activity of enzymes involved in the ascorbate-glutathione cycle in the chloroplasts, leading to an increased ratio of reduced (GSH) to oxidized (GSSG) glutathione in the chloroplasts. An increased GSH/GSSG ratio protected RCA from proteolytic digestion and increased the stability of redox-sensitive enzymes in the chloroplasts. These results strongly suggest that BRs are capable of regulating the glutathione redox state in the chloroplasts through the activation of the ascorbate-glutathione cycle. The resulting increase in the chloroplast thiol reduction state promotes CO{sub 2} assimilation, at least in part, by enhancing the stability and activity of redox-sensitive photosynthetic enzymes through post-translational modifications.

Jiang, Yu Ping; Cheng, Fei; Zhou, Yan Hong; Xia, Xiao Jian; Mao, Wei Hua; Shi, Kai [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China)] [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China); Chen, Zhi Xiang [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China) [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China); Department of Botany and Plant Pathology, Purdue University, West Lafayette, IN 47907-2054 (United States); Yu, Jing Quan, E-mail: jqyu@zju.edu.cn [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China); Key Laboratory of Horticultural Plants Growth, Development and Quality Improvement, Ministry of Agriculture of China, Yuhangtang Road 866, Hangzhou 310058 (China)

2012-09-28T23:59:59.000Z

356

The role of nanopores on U(VI) sorption and redox behavior in U(VI)-contaminated subsurface sediments  

SciTech Connect

Most reactive surfaces in clay-dominated sediments are present within nanopores (pores of nm dimension). The behavior of geological fluids and minerals in nanopores is significantly different from those in normal non-nanoporous environments. The effect of nanopore surfaces on U(VI) sorption/desorption and reduction is likely to be significant in clay-rich subsurface environments. Our research results from both model nanopore system and natural sediments from both model system (synthetic nanopore alumina) and sediments from the ORNL Field Research Center prove that U(VI) sorption on nanopore surfaces can be greatly enhanced by nanopore confinement environments. The results from the project provide advanced mechanistic, quantitative information on the physiochemical controls on uranium sorption and redox behavior in subsurface sediments. The influence of nanopore surfaces on coupled uranium sorption/desorption and reduction processes is significant in virtually all subsurface environments, because most reactive surfaces are in fact nanopore surfaces. The results will enhance transfer of our laboratory-based research to a major field research initiative where reductive uranium immobilization is being investigated. Our results will also provide the basic science for developing in-situ colloidal barrier of nanoporous alumina in support of environmental remediation and long term stewardship of DOE sites.

Xu, Huifang; Roden, Eric E.; Kemner, Kenneth M.; Jung, Hun-Bok; Konishi, Hiromi; Boyanov, Maxim; Sun, Yubing; Mishra, Bhoopesh

2013-10-16T23:59:59.000Z

357

Planetary heat flow measurements  

Science Journals Connector (OSTI)

...ESA's Rosetta mission towards comet Churyumov-Gerasimenko. It...Heat flow measurements on comets have a different motivation...penetrator is by no means limited to comets; it has also been tested in...measurement. Currently, a landing on Mercury within the framework...

2005-01-01T23:59:59.000Z

358

The Flow of Water  

Science Journals Connector (OSTI)

... for ice-covered streams become of very great importance wlieii a stream is required for hydroelectric power production. An appendix is attached of fifty - two well- selected problems relating ... The remaining chapters dealing with flow in pipes and channels and with centrifugal pumps and turbines call for no particular comment. It is of interest to find a chapter dealing ...

1927-12-31T23:59:59.000Z

359

ENERGY FLOWS CLIMATE CHANGE  

E-Print Network (OSTI)

absorption of solar radiation. #12;AEROSOLS AS SEEN FROM SPACE Fire plumes from southern Mexico transportedENERGY FLOWS FORCINGS CLIMATE CHANGE A REALLY TOUGH PROBLEM Stephen E. Schwartz, BNL, 7-20-11 www average temperature 15°C or 59°F #12;ATMOSPHERIC RADIATION Power per area Energy per time per area Unit

Schwartz, Stephen E.

360

US energy flow, 1991  

SciTech Connect

Trends in energy consumption and assessment of energy sources are discussed. Specific topics discussed include: energy flow charts; comparison of energy use with 1990 and earlier years; supply and demand of fossil fuels (oils, natural gas, coal); electrical supply and demand; and nuclear power.

Borg, I.Y.; Briggs, C.K.

1992-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Ikkepsilon regulates viral-induced interferon regulatory factor-3 activation via a redox-sensitive pathway  

SciTech Connect

Respiratory syncytial virus (RSV)-induced chemokine gene expression occurs through the activation of a subset of transcription factors, including Interferon Regulatory Factor (IRF)-3. In this study, we have investigated the signaling pathway leading to RSV-induced IRF-3 activation and whether it is mediated by intracellular reactive oxygen species (ROS) generation. Our results show that RSV infection induces expression and catalytic activity of IKK{epsilon}, a noncanonical IKK-like kinase. Expression of a kinase-inactive IKK{epsilon} blocks RSV-induced IRF-3 serine phosphorylation, nuclear translocation and DNA-binding, leading to inhibition of RANTES gene transcription, mRNA expression and protein synthesis. Treatment of alveolar epithelial cells with antioxidants or with NAD(P)H oxidase inhibitors abrogates RSV-induced chemokine secretion, IRF-3 phosphorylation and IKK{epsilon} induction, indicating that ROS generation plays a fundamental role in the signaling pathway leading to IRF-3 activation, therefore, identifying a novel molecular target for the development of strategies aimed to modify the inflammatory response associated with RSV infection of the lung.

Indukuri, Hemalatha [Department of Pediatrics, University of Texas Medical Branch, Galveston, TX (United States); Castro, Shawn M. [Department of Pediatrics, University of Texas Medical Branch, Galveston, TX (United States); Liao, S.-M. [Millennium Pharmaceuticals Inc, Cambridge, MA (United States); Feeney, Lee Ann [Millennium Pharmaceuticals Inc, Cambridge, MA (United States); Dorsch, Marion [Millennium Pharmaceuticals Inc, Cambridge, MA (United States); Coyle, Anthony J. [Millennium Pharmaceuticals Inc, Cambridge, MA (United States); Garofalo, Roberto P. [Department of Pediatrics, University of Texas Medical Branch, Galveston, TX (United States); Department of Microbiology and Immunology, University of Texas Medical Branch, Galveston, TX (United States); Sealy Center for Vaccine Development, University of Texas Medical Branch, Galveston, TX (United States); Brasier, Allan R. [Department of Internal Medicine, University of Texas Medical Branch, Galveston, TX (United States); Sealy Center for Molecular Sciences, University of Texas Medical Branch, Galveston, TX (United States); Casola, Antonella [Department of Pediatrics, University of Texas Medical Branch, Galveston, TX (United States) and Department of Microbiology and Immunology, University of Texas Medical Branch, Galveston, TX (United States) and Sealy Center for Vaccine Development, University of Texas Medical Branch, Galveston, TX (United States)]. E-mail: ancasola@utmb.edu

2006-09-15T23:59:59.000Z

362

Statement of the health problem or issue An inadequate blood flow to the heart muscle (termed cardiac ischemia) often causes  

E-Print Network (OSTI)

of the heart. Severe reductions in blood flow may cause a heart attack (termed myocardial infarction). Following a heart attack, the heart cells can be saved from dying by the restoration of blood flowStatement of the health problem or issue An inadequate blood flow to the heart muscle (termed

MacMillan, Andrew

363

Self-Organized Network Flows  

E-Print Network (OSTI)

A model for traffic flow in street networks or material flows in supply networks is presented, that takes into account the conservation of cars or materials and other significant features of traffic flows such as jam formation, spillovers, and load-dependent transportation times. Furthermore, conflicts or coordination problems of intersecting or merging flows are considered as well. Making assumptions regarding the permeability of the intersection as a function of the conflicting flows and the queue lengths, we find self-organized oscillations in the flows similar to the operation of traffic lights.

Helbing, D; Lmmer, S; Helbing, Dirk; Siegmeier, Jan; L\\"{a}mmer, Stefan

2007-01-01T23:59:59.000Z

364

SOFC seal and cell thermal management  

SciTech Connect

The solid oxide fuel cell module includes a manifold, a plate, a cathode electrode, a fuel cell and an anode electrode. The manifold includes an air or oxygen inlet in communication with divergent passages above the periphery of the cell which combine to flow the air or oxygen radially or inwardly for reception in the center of the cathode flow field. The latter has interconnects providing circuitous cooling passages in a generally radial outward direction cooling the fuel cell and which interconnects are formed of different thermal conductivity materials for a preferential cooling.

Potnis, Shailesh Vijay (Neenah, WI); Rehg, Timothy Joseph (Huntington Beach, CA)

2011-05-17T23:59:59.000Z

365

Fuel cell repeater unit including frame and separator plate  

DOE Patents (OSTI)

An example fuel cell repeater includes a separator plate and a frame establishing at least a portion of a flow path that is operative to communicate fuel to or from at least one fuel cell held by the frame relative to the separator plate. The flow path has a perimeter and any fuel within the perimeter flow across the at least one fuel cell in a first direction. The separator plate, the frame, or both establish at least one conduit positioned outside the flow path perimeter. The conduit is outside of the flow path perimeter and is configured to direct flow in a second, different direction. The conduit is fluidly coupled with the flow path.

Yamanis, Jean; Hawkes, Justin R; Chiapetta, Jr., Louis; Bird, Connie E; Sun, Ellen Y; Croteau, Paul F

2013-11-05T23:59:59.000Z

366

flow_loop.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

FLOW ASSURANCE TEST LOOP FLOW ASSURANCE TEST LOOP Objective O ver a decade ago, RMOTC began cooperatively building a full-scale facility to test new fl ow assurance technology, mainly in the areas of hydrates and paraffi ns. Today, RMOTC's test facility consists of fi ve individual loop sections, including chilling and heated pipe-in-pipe water sections, bare lines, and a mixing section. The facility was designed to represent typical deepwater production systems in order to simulate full-scale tests and apply the results to fl ow assurance fi eld applications and technology. The current facility design consists of a 6" x 3,600 maximum allowable operating pressure test pipeline in fi ve separate loops. The test loops begin and ter- minate at a central location just north

367

Structural power flow measurement  

SciTech Connect

Previous investigations of structural power flow through beam-like structures resulted in some unexplained anomalies in the calculated data. In order to develop structural power flow measurement as a viable technique for machine tool design, the causes of these anomalies needed to be found. Once found, techniques for eliminating the errors could be developed. Error sources were found in the experimental apparatus itself as well as in the instrumentation. Although flexural waves are the carriers of power in the experimental apparatus, at some frequencies longitudinal waves were excited which were picked up by the accelerometers and altered power measurements. Errors were found in the phase and gain response of the sensors and amplifiers used for measurement. A transfer function correction technique was employed to compensate for these instrumentation errors.

Falter, K.J.; Keltie, R.F.

1988-12-01T23:59:59.000Z

368

Modeling Turbulent Flow  

National Nuclear Security Administration (NNSA)

Turbulent Turbulent Flow with Implicit LES L.G. Margolin 1 Proceedings of the Joint Russian-American Five Laboratory Conference on Computational Mathematics/Physics 19-23 June, 2005 Vienna, Austria 1 Applied Physics Division, Los Alamos National Laboratory, Los Alamos, NM 87545, len@lanl.gov 1 Abstract Implicit large eddy simulation (ILES) is a methodology for modeling high Reynolds' num- ber flows that combines computational efficiency and ease of implementation with predictive calculations and flexible application. Although ILES has been used for more than fifteen years, it is only recently that significant effort has gone into providing a physical rationale that speaks to its capabilities and its limitations. In this talk, we will present new theoret- ical results aimed toward building a justification and discuss some remaining gaps in our understanding and our practical

369

Neutrino Factory Mercury Flow Loop  

E-Print Network (OSTI)

Neutrino Factory Mercury Flow Loop V. GravesV. Graves C. Caldwell IDS-NF Videoconference March 9, 2010 #12;Flow Loop Review · 1 cm dia nozzle, 20 m/s jet requires 1.57 liter/sec mercury flow (94 2 liter/min 24 9 gpm)mercury flow (94.2 liter/min, 24.9 gpm). · MERIT experiment showed that a pump

McDonald, Kirk

370

Orifice flow measurement uncertainty  

SciTech Connect

A computer program is now available from Union Carbide that evaluates the total flow uncertainty of orifice flowmeter systems. Tolerance values for every component in the system and the sensitivity of the measured flowrate to each component can be established using historical data and published hardware specifications. Knowing the tolerance and sensitivity values, a total measurement uncertainty can be estimated with a 95% confidence level. This computer program provides a powerful design tool to ensure correct component matching and total metering system optimization.

Samples, C.R.

1984-04-01T23:59:59.000Z

371

Convective heat flow probe  

DOE Patents (OSTI)

A convective heat flow probe device is provided which measures heat flow and fluid flow magnitude in the formation surrounding a borehole. The probe comprises an elongate housing adapted to be lowered down into the borehole; a plurality of heaters extending along the probe for heating the formation surrounding the borehole; a plurality of temperature sensors arranged around the periphery of the probe for measuring the temperature of the surrounding formation after heating thereof by the heater elements. The temperature sensors and heater elements are mounted in a plurality of separate heater pads which are supported by the housing and which are adapted to be radially expanded into firm engagement with the walls of the borehole. The heat supplied by the heater elements and the temperatures measured by the temperature sensors are monitored and used in providing the desired measurements. The outer peripheral surfaces of the heater pads are configured as segments of a cylinder and form a full cylinder when taken together. A plurality of temperature sensors are located on each pad so as to extend along the length and across the width thereof, with a heating element being located in each pad beneath the temperature sensors. An expansion mechanism driven by a clamping motor provides expansion and retraction of the heater pads and expandable packet-type seals are provided along the probe above and below the heater pads.

Dunn, J.C.; Hardee, H.C.; Striker, R.P.

1984-01-09T23:59:59.000Z

372

Numerical Investigations of Magnetohydrodynamic Hypersonic Flows.  

E-Print Network (OSTI)

??Numerical simulations of magnetohydrodynamic (MHD) hypersonic flow are presented for both laminar and turbulent flow over a cylinder and flow entering a scramjet inlet. ANSYS (more)

Guarendi, Andrew N

2013-01-01T23:59:59.000Z

373

Spectroscopic study of a Cu/CeO{sub 2} catalyst subjected to redox treatments in carbon monoxide and oxygen  

SciTech Connect

Redox processes induced by interaction of a calcined Cu/CeO{sub 2} catalyst with CO and reoxidation with O{sub 2} have been investigated by CO-TPR, EPR, FTIR of adsorbed CO, and XPS. The initial calcined samples shows the presence of dispersed Cu{sup 2+} species, which give rise in the EPR spectrum to signals due to isolated entities, a somewhat more aggregated Cu{sup 2+}-containing phase, and copper ionic pairs, in coexistence with an EPR-silent CuO-type phase, revealed by XPS. A significant reduction of copper is produced already by contact with CO at room temperature, EPR results suggesting that reducibility of Cu{sup 2+} species decreases with their aggregation degree. Simultaneously, the ceria surface is also reduced by this interaction, copper acting as a strong promoter of this process. A singular consequence of the synergistic reduction of both components is observed by subjecting the catalyst to CO at T{sub r} {ge} 473 K, at which the CO adsorption capability of copper is apparently suppressed, in view of the absence of copper carbonyls in the FTIR spectrum. This is attributed to the establishment of electronic interactions between reduced ceria and small metallic copper particles generated by the reduction process. Contact of the CO-reduced sample with O{sub 2} at room or higher temperature produces an important reoxidation of both copper and ceria, revealed by FTIR and EPR. The synergetic effects between copper and ceria in the reduction process and the easy reoxidation of deeply reduced ceria are thought to be crucial to explaining the high catalytic activity shown by this system for CO oxidation.

Martinez-Arias, A.; Fernandez-Garcia, M.; Soria, J.; Conesa, J.C. [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica] [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica

1999-03-10T23:59:59.000Z

374

Attractor Flows from Defect Lines  

E-Print Network (OSTI)

Deforming a two dimensional conformal field theory on one side of a trivial defect line gives rise to a defect separating the original theory from its deformation. The Casimir force between these defects and other defect lines or boundaries is used to construct flows on bulk moduli spaces of CFTs. It turns out, that these flows are constant reparametrizations of gradient flows of the g-functions of the chosen defect or boundary condition. The special flows associated to supersymmetric boundary conditions in N=(2,2) superconformal field theories agree with the attractor flows studied in the context of black holes in N=2 supergravity.

Ilka Brunner; Daniel Roggenkamp

2010-02-12T23:59:59.000Z

375

Generator configuration for solid oxide fuel cells  

DOE Patents (OSTI)

Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

Reichner, Philip (Plum Boro, PA)

1989-01-01T23:59:59.000Z

376

Three-Dimensional Structure of Tropical Cells in the Central Equatorial Pacific Ocean  

Science Journals Connector (OSTI)

The shallow tropical cells (TCs) in the central equatorial Pacific Ocean are characterized by strong equatorial upwelling, near-surface wind-driven poleward flow, downwelling near the cold tongue boundaries, and equatorward flow below the surface ...

Renellys C. Perez; William S. Kessler

2009-01-01T23:59:59.000Z

377

UZ Flow Models and Submodels  

SciTech Connect

The purpose of this report is to document the unsaturated zone (UZ) flow models and submodels, as well as the flow fields that have been generated using the UZ flow model(s) of Yucca Mountain, Nevada. In this report, the term ''UZ model'' refers to the UZ flow model and the several submodels, which include tracer transport, temperature or ambient geothermal, pneumatic or gas flow, and geochemistry (chloride, calcite, and strontium) submodels. The term UZ flow model refers to the three-dimensional models used for calibration and simulation of UZ flow fields. This work was planned in the ''Technical Work Plan (TWP) for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.7). The table of included Features, Events, and Processes (FEPs), Table 6.2-11, is different from the list of included FEPs assigned to this report in the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Table 2.1.5-1), as discussed in Section 6.2.6. The UZ model has revised, updated, and enhanced the previous UZ model (BSC 2001 [DIRS 158726]) by incorporating the repository design with new grids, recalibration of property sets, and more comprehensive validation effort. The flow fields describe fracture-fracture, matrix-matrix, and fracture-matrix liquid flow rates, and their spatial distributions as well as moisture conditions in the UZ system. These three-dimensional UZ flow fields are used directly by Total System Performance Assessment (TSPA). The model and submodels evaluate important hydrogeologic processes in the UZ as well as geochemistry and geothermal conditions. These provide the necessary framework to test hypotheses of flow and transport at different scales, and predict flow and transport behavior under a variety of climatic conditions. In addition, the limitations of the UZ model are discussed in Section 8.11.

Y. Wu

2004-11-01T23:59:59.000Z

378

FUEL CELLS SOLID OXIDE FUEL CELLS | Systems  

Science Journals Connector (OSTI)

In this article, some basic arrangements of solid oxide fuel cell (SOFC) systems are described, starting with atmospheric systems using a catalytic burner or a thermal burner and anode gas recycling. For illustrating the potential electrical efficiency of SOFC systems, their combination with a gas turbine and also with a steam turbine (ST) are described. To be able to evaluate the potential of the different systems, first the essential efficiencies relevant to fuel cell systems are defined and then the basics of calculating energy balance are illustrated. Equations are given to describe, for example, the effect of fuel recycling on system fuel utilization and of internal reforming on the necessary air flow for cooling the stack. It is obvious that electrical efficiency depends strongly on cell voltage and fuel utilization. In the case of cells that operate with a high fuel utilization at cell voltages of 800mV, a net electrical efficiency above 55% can be achieved. The combination in a pressurized system with a gas turbine enables efficiencies of up to 70% and combining this system with an additional ST allows efficiencies of up to 75%. However, an investigation into the size of these \\{STs\\} shows that such combined systems make sense only above a gas input of 10MW.

L. Blum; E. Riensche

2009-01-01T23:59:59.000Z

379

Enhanced performance of electrospun carbon fibers modified with carbon nanotubes: promising electrodes for enzymatic biofuel cells  

Science Journals Connector (OSTI)

New nanostructured electrodes, promising for the production of clean and renewable energy in biofuel cells, were developed with success. For this purpose, carbon nanofibers were produced by the electrospinning of polyacrylonitrile solution followed by convenient thermal treatments (stabilization followed by carbonization at 1000, 1200 and 1400 C), and carbon nanotubes were adsorbed on the surfaces of the fibers by a dipping method. The morphology of the developed electrodes was characterized by several techniques (SEM, Raman spectroscopy, electrical conductivity measurement). The electrochemical properties were evaluated through cyclic voltammetry, where the influence of the carbonization temperature of the fibers and the beneficial contribution of the carbon nanotubes were observed through the reversibility and size of the redox peaks of K3Fe(CN)6 versus Ag/AgCl. Subsequently, redox enzymes were immobilized on the electrodes and the electroreduction of oxygen to water was realized as a test of their efficiency as biocathodes. Due to the fibrous and porous structure of these new electrodes, and to the fact that carbon nanotubes may have the ability to promote electron transfer reactions of redox biomolecules, the new electrodes developed were capable of producing higher current densities than an electrode composed only of electrospun carbon fibers.

A Both Engel; A Cherifi; S Tingry; D Cornu; A Peigney; Ch Laurent

2013-01-01T23:59:59.000Z

380

Micromachined microbial and photosynthetic fuel cells  

Science Journals Connector (OSTI)

This paper presents two types of fuel cells: a miniature microbial fuel cell (MFC) and a miniature photosynthetic electrochemical cell (PEC). A bulk micromachining process is used to fabricate the fuel cells, and the prototype has an active proton exchange membrane area of 1 cm2. Two different micro-organisms are used as biocatalysts in the anode: (1) Saccharomyces cerevisiae (baker's yeast) is used to catalyze glucose and (2) Phylum Cyanophyta (blue-green algae) is used to produce electrons by a photosynthetic reaction under light. In the dark, the PEC continues to generate power using the glucose produced under light. In the cathode, potassium ferricyanide is used to accept electrons and electric power is produced by the overall redox reactions. The bio-electrical responses of MFCs and PECs are characterized with the open-circuit potential measured at an average value of 300500 mV. Under a 10 ohm load, the power density is measured as 2.3 nW cm?2 and 0.04 nW cm?2 for MFCs and PECs, respectively.

Mu Chiao; Kien B Lam; Liwei Lin

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Similarity of the Surface Reactivity of Hydrous Ferric Oxide and Hematite: Sorption and Redox of U(VI) and Fe(II)  

SciTech Connect

Hydrous Ferric Oxide (HFO) vs. Hematite--Thermodynamically distinctive bulk phases, but the surfaces could be similar due to hydration of the interface. Hypothesis--The surface of HFO is energetically similar to the surface of hematite. Objective--Compare the reactions of HFO and hematite with U(VI) and Fe(II). Experimental--The reactions of interests were (1) preparation of sub-micron hematite, (2) sorption of U(VI), and (3) redox of U(VI) and Fe(II) with HFO or hematite.

Je-Hun Jang; Dempsey, Brian A.; Burgos, William D.; Yeh, George; Roden, Eric

2004-03-17T23:59:59.000Z

382

Reversible Three-Electron Redox Behaviors of FeF3 Nanocrystals as High-Capacity Cathode-Active Materials for Li-Ion Batteries  

Science Journals Connector (OSTI)

Reversible Three-Electron Redox Behaviors of FeF3 Nanocrystals as High-Capacity Cathode-Active Materials for Li-Ion Batteries ... Three types of FeF3 nanocrystals were synthesized by different chemical routes and investigated as a cathode-active material for rechargeable lithium batteries. ... (1-3) Though many types of metal oxides and phosphates have been tested as alternative cathode materials,(4, 5) no real breakthrough has been achieved in capacity, especially for intercalation cathodes, the capacity-determining electrode in the present LIBs systems. ...

Ting Li; Lei Li; Yu L. Cao; Xin P. Ai; Han X. Yang

2010-01-28T23:59:59.000Z

383

Graphite coated with manganese oxide/multiwall carbon nanotubes composites as anodes in marine benthic microbial fuel cells  

Science Journals Connector (OSTI)

Abstract Improving anode performance is of great significance to scale up benthic microbial fuel cells (BMFCs) for its marine application to drive oceanography instruments. In this study, manganese oxide (MnO2)/multiwall carbon nanotubes (MWCNTs) composites are prepared to be as novel anodes in the \\{BMFCs\\} via a direct redox reaction between permanganate ions (MnO4?) and MWCNTs. The results indicate that the MnO2/MWCNTs anode has a better wettability, greater kinetic activity and higher power density than that of the plain graphite (PG) anode. It is noted that the MnO2 (50% weight percent)/MWCNTs anode shows the highest electrochemical performance among them and will be a promising material for improving bioelectricity production of the BMFCs. Finally, a synergistic mechanism of electron transfer shuttle of Mn ions and their redox reactions in the interface between modified anode and bacteria biofilm are proposed to explain its excellent electrochemical performance.

Yubin Fu; Jian Yu; Yelong Zhang; Yao Meng

2014-01-01T23:59:59.000Z

384

Red Sea heat flow  

Science Journals Connector (OSTI)

......measurements whereas Girdler estimated thermal conductivities from the literature...valuesinclude four for the Sudan coast and three for the Ethiopian...be associated with transient thermal effects such as slumping of...downgoinglimbs of a hydro- thermal convection cells. In general......

R. W. Girdler; T. R. Evans

1977-10-01T23:59:59.000Z

385

Annular flow diverter valve  

DOE Patents (OSTI)

A valve for diverting flow from the center of two concentric tubes to the annulus between the tubes or, operating in the reverse direction, for mixing fluids from concentric tubes into a common tube and for controlling the volume ratio of said flow consists of a toroidal baffle disposed in sliding engagement with the interior of the inner tube downstream of a plurality of ports in the inner tube, a plurality of gates in sliding engagement with the interior of the inner tube attached to the baffle for movement therewith, a servomotor having a bullet-shaped plug on the downstream end thereof, and drive rods connecting the servomotor to the toroidal baffle, the servomotor thereby being adapted to move the baffle into mating engagement with the bullet-shaped plug and simultaneously move the gates away from the ports in the inner tube and to move the baffle away from the bullet-shaped plug and simultaneously move the gates to cover the ports in the inner tube.

Rider, Robert L. (Walkersville, MD)

1980-01-01T23:59:59.000Z

386

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device are described comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips. 7 figures.

McKay, M.D.; Sweeney, C.E.; Spangler, B.S. Jr.

1993-11-30T23:59:59.000Z

387

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

McKay, Mark D. (1426 Socastee Dr., North Augusta, SC 29841); Sweeney, Chad E. (3600 Westhampton Dr., Martinez, GA 30907-3036); Spangler, Jr., B. Samuel (2715 Margate Dr., Augusta, GA 30909)

1993-01-01T23:59:59.000Z

388

Supersonic Magnetic Flows in the Quiet Sun  

E-Print Network (OSTI)

In this contribution we describe some recent observations of high-speed magnetized flows in the quiet Sun granulation. These observations were carried out with the Imaging Magnetograph eXperiment (IMaX) onboard the stratospheric balloon {\\sc Sunrise}, and possess an unprecedented spatial resolution and temporal cadence. These flows were identified as highly shifted circular polarization (Stokes $V$) signals. We estimate the LOS velocity responsible for these shifts to be larger than 6 km s$^{-1}$, and therefore we refer to them as {\\it supersonic magnetic flows}. The average lifetime of the detected events is 81.3 s and they occupy an average area of about 23\\,000 km$^2$. Most of the events occur within granular cells and correspond therefore to upflows. However some others occur in intergranular lanes or bear no clear relation to the convective velocity pattern. We analyze a number of representative examples and discuss them in terms of magnetic loops, reconnection events, and convective collapse.

Borrero, J M; Schlichenmaier, R; Schmidt, W; Berkefeld, T; Solanki, S K; Bonet, J A; Iniesta, J C del Toro; Domingo, V; Barthol, P; Gandorfer, A

2012-01-01T23:59:59.000Z

389

Reduction of a Redox-Active Ligand Drives Switching in a Cu(I) Pseudorotaxane by a Bimolecular Mechanism  

SciTech Connect

The reduction of a redox-active ligand is shown to drive reversible switching of a Cu(I) [2]pseudorotaxane ([2]PR{sup 2+}) into the reduced [3]pseudorotaxane ([3]PR{sup 2+}) by a bimolecular mechanism. The unreduced pseudorotaxanes [2]PR{sup 2+} and [3]PR{sup 2+} are initially self-assembled from the binucleating ligand, 3,6-bis(5-methyl-2-pyridine)-1,2,4,5-tetrazine (Me2BPTZ), and a preformed copper-macrocycle moiety (Cu-M{sup 2+}) based on 1,10-phenanthroline. X-ray crystallography revealed a syn geometry of the [3]PR{sup 2+}. The UV-vis-NIR spectra show low-energy metal-to-ligand charge-transfer transitions that red shift from 808 nm for [2]PR{sup 2+} to 1088 nm for [3]PR{sup 2+}. Quantitative analysis of the UV-vis-NIR titration shows the stepwise formation constants to be K{sub 1} = 8.9 x 10{sup 8} M{sup -1} and K{sub 2} = 3.1 x 10{sup 6} M{sup -1}, indicative of negative cooperativity. The cyclic voltammetry (CV) and coulometry of Me{sub 2}BPTZ, [2]PR{sup 2+}, and [3]PR{sup 2+} shows the one-electron reductions at E{sub 1/2} = -0.96, -0.65, and -0.285 V, respectively, to be stabilized in a stepwise manner by each Cu{sup 2+} ion. CVs of [2]PR{sup 2+} show changes with scan rate consistent with an EC mechanism of supramolecular disproportionation after reduction: [2]PR{sup 0} + [2]PR{sup 2+} = [3]PR{sup 2+} + Me{sub 2}BPTZ{sup 0} (K*{sub D}, k{sub d}). UV-vis-NIR spectroelectrochemistry was used to confirm the 1:1 product stoichiometry for [3]PR{sup 2+}:Me{sub 2}BPTZ. The driving force ({Delta}G*{sub D} = -5.1 kcal mol{sup -1}) for the reaction is based on the enhanced stability of the reduced [3]PR{sup 2+} over reduced [2]PR{sup 0} by 365 mV (8.4 kcal mol{sup -1}). Digital simulations of the CVs are consistent with a bimolecular pathway (k{sub d} = 12,000 s{sup -1} M{sup -1}). Confirmation of the mechanism provides a basis to extend this new switching modality to molecular machines.

McNitt, Kristy A.; Parimal, Kumar; Share, Andrew I.; Fahrenbach, Albert C.; Witlicki, Edward H.; Pink, Maren; Bediako, D. Kwabena; Plaisier, Christina L.; Le, Nga; Heeringa, Lee P.; Vander Griend, Douglas A.; Flood, Amar H.; (Calvin); (Indiana)

2009-04-02T23:59:59.000Z

390

A New Model for Electron Flow for Sulfate Reduction in Desulfovibrio alaskensis G20  

SciTech Connect

To understand the energy conversion activities of the anaerobic sulfate-reducing bacteria, it is necessary to identify the components involved in electron flow. The importance of the abundant type I tetraheme cytochrome c3 (TpIc3) as an electron carrier during sulfate respiration was questioned by the previous isolation of a null mutation in the encoding gene, cycA, in Desulfovibrio alaskensis G20. Whereas respiratory growth of the CycA mutant with lactate and sulfate was little affected, growth with pyruvate and sulfate was significantly impaired. We have explored the phenotype of the CycA mutant through physiological tests and transcriptomic and proteomic analyses. Data reported here show that electrons from pyruvate oxidation do not reach adenylyl sulfate reductase, the enzyme catalyzing the first redox reaction during sulfate reduction, in the absence of either CycAor the type I cytochrome c3:menaquinone oxidoreductase, QrcABCD transmembrane complex. In contrast to the wild type, neither CycA and QrcA mutants do not grow with H2 or formate and sulfate as electron acceptor. Transcriptomic and proteomic analyses of the CycA mutant showed that transcripts and enzymes for the pathway from pyruvate to succinate were strongly decreased in the CycA mutant regardless of growth mode. Neither the CycA nor the QrcA mutant grew on fumarate alone, consistent with the omics results and a redox regulation of gene expression. We conclude that TpIc3 and the Qrc complex are essential D. alaskensis components for transfer of electrons released in the periplasm to reach the cytoplasmic adenylyl sulfate reductase and present a model that may explain the CycA phenotype through confurcation of electrons.

Keller, Kimberly L [University of Missouri, Columbia] [University of Missouri, Columbia; Rapp-Giles, Barbara J [University of Missouri, Columbia] [University of Missouri, Columbia; Semkiw, Elizabeth M. [University of Missouri] [University of Missouri; Porat, Iris [ORNL] [ORNL; Brown, Steven D [ORNL] [ORNL; Wall, Judy D. [University of Missouri] [University of Missouri

2013-01-01T23:59:59.000Z

391

New Model for Electron Flow for Sulfate Reduction in Desulfovibrio alaskensis G20  

SciTech Connect

To understand the energy conversion activities of the anaerobic sulfate-reducing bacteria, it is necessary to identify the components involved in electron flow. The importance of the abundant type I tetraheme cytochrome c3 (TpIc3) as an electron carrier during sulfate respiration was questioned by the previous isolation of a null mutation in the gene encoding TpIc3, cycA, in Desulfovibrio alaskensis G20. Whereas respiratory growth of the CycA mutant with lactate and sulfate was little affected, growth with pyruvate and sulfate was significantly impaired. We have explored the phenotype of the CycA mutant through physiological tests and transcriptomic and proteomic analyses. Data reported here show that electrons from pyruvate oxidation do not reach adenylyl sulfate reductase, the enzyme catalyzing the first redox reaction during sulfate reduction, in the absence of either CycA or the type I cytochrome c3:menaquinone oxidoreductase transmembrane complex, QrcABCD. In contrast to the wild type, the CycA and QrcA mutants did not grow with H2 or formate and sulfate as the electron acceptor. Transcriptomic and proteomic analyses of the CycA mutant showed that transcripts and enzymes for the pathway from pyruvate to succinate were strongly decreased in the CycA mutant regardless of the growth mode. Neither the CycA nor the QrcA mutant grew on fumarate alone, consistent with the omics results and a redox regulation of gene expression. We conclude that TpIc3 and the Qrc complex are D. alaskensis components essential for the transfer of electrons released in the periplasm to reach the cytoplasmic adenylyl sulfate reductase and present a model that may explain the CycA phenotype through confurcation of electrons.

Rapp-Giles, Barbara J [University of Missouri, Columbia] [University of Missouri, Columbia; Keller, Kimberly L [University of Missouri, Columbia] [University of Missouri, Columbia; Porat, Iris [ORNL] [ORNL; Brown, Steven D [ORNL] [ORNL; Semkiw, Elizabeth M. [University of Missouri] [University of Missouri; Wall, Judy D. [University of Missouri] [University of Missouri

2014-01-01T23:59:59.000Z

392

Active combustion flow modulation valve  

DOE Patents (OSTI)

A flow modulation valve has a slidably translating hollow armature with at least one energizable coil wound around and fixably attached to the hollow armature. The energizable coil or coils are influenced by at least one permanent magnet surrounding the hollow armature and supported by an outer casing. Lorentz forces on the energizable coils which are translated to the hollow armature, increase or decrease the flow area to provide flow throttling action. The extent of hollow armature translation depends on the value of current supplied and the direction of translation depends on the direction of current flow. The compact nature of the flow modulation valve combined with the high forces afforded by the actuator design provide a flow modulation valve which is highly responsive to high-rate input control signals.

Hensel, John Peter; Black, Nathaniel; Thorton, Jimmy Dean; Vipperman, Jeffrey Stuart; Lambeth, David N; Clark, William W

2013-09-24T23:59:59.000Z

393

Das Redox-Potential  

Science Journals Connector (OSTI)

Da jeder Oxydationsvorgang in der Weise abluft, da ein Oxydationsmittel von einem Reduktionsmittel reduziert wird, also jede Oxydation prinzipiell mit einer Reduktion gekoppelt ist, spricht man allgemeiner von

Prof. Dr. W. Heimann; Dr. K. Wisser

1965-01-01T23:59:59.000Z

394

Differential probes aid flow measurement  

SciTech Connect

Nonconstricting differential pressure flow probes which help solve the problems of clogging, wear, and pressure loss at the Seawater Filtration Facility in Saudi Arabia are described. Treated seawater is pumped into oil-bearing formations for secondary recovery. Figures showing principle of operation for probes, installation schematic and long-term accuracy results (flow probes vs. orifice meters) are presented. The new diamond-shaped design flow sensor offers accurate flow measurement with low permanent pressure loss, which translates into cost savings for the operator.

Mesnard, D.R.

1982-07-01T23:59:59.000Z

395

Module bay with directed flow  

DOE Patents (OSTI)

A module bay requires less cleanroom airflow. A shaped gas inlet passage can allow cleanroom air into the module bay with flow velocity preferentially directed toward contaminant rich portions of a processing module in the module bay. Preferential gas flow direction can more efficiently purge contaminants from appropriate portions of the module bay, allowing a reduced cleanroom air flow rate for contaminant removal. A shelf extending from an air inlet slit in one wall of a module bay can direct air flowing therethrough toward contaminant-rich portions of the module bay, such as a junction between a lid and base of a processing module.

Torczynski, John R. (Albuquerque, NM)

2001-02-27T23:59:59.000Z

396

UZ Flow Models and Submodels  

SciTech Connect

The purpose of this Model Report is to document the unsaturated zone (UZ) fluid flow and tracer transport models and submodels as well as the flow fields generated utilizing the UZ Flow and Transport Model of Yucca Mountain (UZ Model), Nevada. This work was planned in ''Technical Work Plan (TWP) for: Performance Assessment Unsaturated Zone'' (BSC 2002 [160819], Section 1.10, Work Package AUZM06). The UZ Model has revised, updated, and enhanced the previous UZ Flow Model REV 00 ICN 01 (BSC 2001 [158726]) by incorporation of the conceptual repository design with new grids, recalibration of property sets, and more comprehensive validation effort. The flow fields describe fracture-fracture, matrix-matrix, and fracture-matrix liquid flow rates and their spatial distributions as well as moisture conditions in the UZ system. These 3-D UZ flow fields are used directly by Performance Assessment (PA). The model and submodels evaluate important hydrogeologic processes in the UZ as well as geochemistry and geothermal conditions. These provide the necessary framework to test conceptual hypotheses of flow and transport at different scales and predict flow and transport behavior under a variety of climatic conditions. In addition, this Model Report supports several PA activities, including abstractions, particle-tracking transport simulations, and the UZ Radionuclide Transport Model.

P. Dixon

2004-02-11T23:59:59.000Z

397

Flow Relationships in Reverse Osmosis  

Science Journals Connector (OSTI)

Flow Relationships in Reverse Osmosis ... Effects of Hydrolysis on Cellulose Acetate Reverse-Osmosis Transport Coefficients ... Effects of Hydrolysis on Cellulose Acetate Reverse-Osmosis Transport Coefficients ...

Ulrich Merten

1963-08-01T23:59:59.000Z

398

Financing Program Implementation Process Flow  

Energy.gov (U.S. Department of Energy (DOE))

The implementation process flow for financing with two models: a generic option for primary markets and a conceptual option for secondary markets.

399

Solid oxide fuel cell generator  

DOE Patents (OSTI)

A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

1993-01-01T23:59:59.000Z

400

Comparative Study on Redox Properties of Nanosized CeO2 and CuO/Ce2 Under CO/O2  

SciTech Connect

Nanosized CeO{sub 2} and CuO/CeO{sub 2} samples, active for CO-PROX or related processes were comparatively examined by O{sub 2} probe electron paramagnetic resonance and in situ Raman and X-ray diffraction techniques. Their behavior toward CO reduction, as well as the oxygen-handling properties of the CO-reduced samples, was explored. An appreciable reduction of the ceria bulk was detected on treatment under CO at 473 K. On the basis of the analysis of the evolution of different oxygen-derived species (superoxide, peroxide, O-) on low-temperature (77-300 K) oxygen chemisorption on the CO-reduced samples, a general picture of the redox properties of the samples is presented. Results demonstrate that the presence of copper promotes completion of the redox cycle under CO/O{sub 2} by favoring both ceria reduction and oxidation. This can be relevant to explaining the remarkable oxidation activity and synergetic effects observed for catalysts combining CuO and CeO{sub 2}.

Martinez-Arias,A.; Gamarra, D.; Fernandez-Garcia, M.; Wang, X.; Hanson, J.; Rodriguez, J.

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Effects of the iron content and redox state on the structure of sodium borosilicate glasses: A Raman, Moessbauer and boron K-edge XANES spectroscopy study  

SciTech Connect

The structure of iron-bearing sodium borosilicate glasses with up to 10 mol% FeO has been investigated in the range 0.15 ? Fe{sup 3+}/SFe ? 0.95. According to Moessbauer spectroscopy, Fe{sup 3+} and Fe{sup 2+} are mainly in tetrahedral and octahedral coordination, respectively, although other coordination states exist for both cations. From XANES experiments, we conclude that increasing Fe content and varying redox states have only a minor effect on the relative proportions of BO{sub 3} and BO{sub 4} units. In Raman spectra, a decrease of the proportion of BO{sub 4} species present in danburite-like units (Na{sub 2}O.B{sub 2}O{sub 3}.2SiO{sub 2}) is found upon increasing iron content and oxidizing state. Whereas the insensitivity of the overall boron speciation to iron content and redox state points to weak interactions between boron and iron, the changes affecting BO{sub 4} species do indicate a more subtle interplay between Fe{sup 3+} and the other tetrahedrally coordinated cations (Si,B) because of the competition between tetrahedral Fe{sup 3+} and B{sup 3+} for charge compensation by Na{sup +}. (authors)

Cochain, B. [CEA, DEN, SECM, LDMC, Bagnols Sur Ceze, (France); IPGP-CNRS, Universite Paris 7, Sorbonne Paris Cite Paris, (France); Geology Department, University of Toronto, Toronto, (Canada); Neuville, D.R.; Richet, P. [Univ Paris 07, IPGP CNRS, Paris, (France); Henderson, G.S. [Univ Toronto, Dept Geol, Toronto, ON, (Canada); McCammon, C.A. [Univ Bayreuth, Bayer Geoinst, Bayreuth, (Germany)

2012-03-15T23:59:59.000Z

402

Crystal Structures of the Reduced, Sulfenic Acid, and Mixed Disulfide Forms of SarZ, a Redox Active Global Regulator in Staphylococcus aureus  

SciTech Connect

SarZ is a global transcriptional regulator that uses a single cysteine residue, Cys{sup 13}, to sense peroxide stress and control metabolic switching and virulence in Staphylococcus aureus. SarZ belongs to the single-cysteine class of OhrR-MgrA proteins that play key roles in oxidative resistance and virulence regulation in various bacteria. We present the crystal structures of the reduced form, sulfenic acid form, and mixed disulfide form of SarZ. Both the sulfenic acid and mixed disulfide forms are structurally characterized for the first time for this class of proteins. The Cys{sup 13} sulfenic acid modification is stabilized through two hydrogen bonds with surrounding residues, and the overall DNA-binding conformation is retained. A further reaction of the Cys{sup 13} sulfenic acid with an external thiol leads to formation of a mixed disulfide bond, which results in an allosteric change in the DNA-binding domains, disrupting DNA binding. Thus, the crystal structures of SarZ in three different states provide molecular level pictures delineating the mechanism by which this class of redox active regulators undergoes activation. These structures help to understand redox-mediated virulence regulation in S. aureus and activation of the MarR family proteins in general.

Poor, Catherine B.; Chen, Peng R.; Duguid, Erica; Rice, Phoebe A.; He, Chuan; (UC)

2010-01-20T23:59:59.000Z

403

Viscoelastic transient of confined Red Blood Cells  

E-Print Network (OSTI)

The unique ability of a red blood cell to flow through extremely small microcapillaries depends on the viscoelastic properties of its membrane. Here, we study in vitro the response time upon flow startup exhibited by red blood cells confined into microchannels. We show that the characteristic transient time depends on the imposed flow strength, and that such a dependence gives access to both the effective viscosity and the elastic modulus controlling the temporal response of red cells. A simple theoretical analysis of our experimental data, validated by numerical simulations, further allows us to compute an estimate for the two-dimensional membrane viscosity of red blood cells, $\\eta_{mem}^{2D}\\sim 10^{-7}$ N$\\cdot$s$\\cdot$m$^{-1}$. By comparing our results with those from previous studies, we discuss and clarify the origin of the discrepancies found in the literature regarding the determination of $\\eta_{mem}^{2D}$, and reconcile seemingly conflicting conclusions from previous works.

Gal Prado; Alexander Farutin; Chaouqi Misbah; Lionel Bureau

2014-09-17T23:59:59.000Z

404

E-Print Network 3.0 - adult myogenic cells Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

OF WISCONSIN CURRICULUM VITAE Summary: , California Thesis title: Numerical Simulation of Sickle Cell Blood Flow in the Transverse Arteriole... ,048 (Direct) Invited Lectures and...

405

Compact, Rapid Cell Deformability Measurements Using Diode Laser Bar Optical Trapping in Microfluidics  

Science Journals Connector (OSTI)

We present a simple, compact, microfluidic system that easily facilitates diode laser bar optical trapping for cell stretching measurements and particle sorting within flowing...

Applegate Jr , Robert W; Squier, Jeff; Vestad, Tor; Oakey, John; Marr, David W

406

ESS 2012 Peer Review - Reducing the Costs of Manufacturing Flow Batteries - Dhruv Bhatnagar, SNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

the Costs of Manufacturing Flow Batteries the Costs of Manufacturing Flow Batteries Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND No. 2011-XXXXP Next Steps 1. Continued outreach with other with other manufacturers 2. Characterization of the flow battery manufacturing process and determination of process issues 3. Evaluation of the fuel cell, other battery and other industry manufacturing process to address issues identified 4. Coordination with PNNL flow battery component cost

407

High Average Power Laser Gain Medium With Low Optical Distortion Using A Transverse Flowing Liquid Host  

DOE Patents (OSTI)

A high average power, low optical distortion laser gain media is based on a flowing liquid media. A diode laser pumping device with tailored irradiance excites the laser active atom, ion or molecule within the liquid media. A laser active component of the liquid media exhibits energy storage times longer than or comparable to the thermal optical response time of the liquid. A circulation system that provides a closed loop for mixing and circulating the lasing liquid into and out of the optical cavity includes a pump, a diffuser, and a heat exchanger. A liquid flow gain cell includes flow straighteners and flow channel compression.

Comaskey, Brian J. (Walnut Creek, CA); Ault, Earl R. (Livermore, CA); Kuklo, Thomas C. (Oakdale, CA)

2005-07-05T23:59:59.000Z

408

Effect of flow fluctuations and nonflow on elliptic flow methods  

SciTech Connect

We discuss how the different estimates of elliptic flow are influenced by flow fluctuations and nonflow effects. It is explained why the event-plane method yields estimates between the two-particle correlation methods and the multiparticle correlation methods. It is argued that nonflow effects and fluctuations cannot be disentangled without other assumptions. However, we provide equations where, with reasonable assumptions about fluctuations and nonflow, all measured values of elliptic flow converge to a unique mean v_2,PP elliptic flow in the participant plane and, with a Gaussian assumption on eccentricity fluctuations, can be converted to the mean v_2,RP in the reaction plane. Thus, the 20percent spread in observed elliptic flow measurements from different analysis methods is no longer mysterious.

Ollitrault, Jean-Yves; Poskanzer, Arthur M.; Voloshin, Sergei A.

2009-04-16T23:59:59.000Z

409

An Arabidopsis Glutathione Peroxidase Functions as Both a Redox Transducer and a Scavenger in Abscisic Acid and Drought Stress Responses  

Science Journals Connector (OSTI)

...S., and Lee, Y. (1999). Oligogalacturonic acid and chitosan reduce stomatal aperture by inducing the evolution of reactive...receptor-associated factor 2 requires prior dissociation of the ASK1 inhibitor thioredoxin. Mol. Cell. Biol. 20, 2198-2208. Liu...

Yuchen Miao; Dong Lv; Pengcheng Wang; Xue-Chen Wang; Jia Chen; Chen Miao; Chun-Peng Song

2006-09-22T23:59:59.000Z

410

Magnetically insulated theory with both electron and ion flows  

SciTech Connect

Both the ion emission from anode surface and the electron emission from cathode surface may occur in the magnetically insulated transmission line (MITL) with a very high pulsed power and a very large current density. A model for the MITL with both electron and ion flow is developed. In this model, physical quantities (such as space-charge sheath thicknesses and flow currents) in the MITL are theoretically analyzed, and the specific expression for the voltage on the line by the terms of currents is derived. Furthermore, particle-in-cell simulations are carried out to verify the theoretical results.

Wang Huihui; Meng Lin; Liu Dagang; Liu Laqun; Yang Chao [School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China)

2012-10-15T23:59:59.000Z

411

Parallel Multiphysics Simulations of Charged Particles in Microfluidic Flows  

E-Print Network (OSTI)

The article describes parallel multiphysics simulations of charged particles in microfluidic flows with the waLBerla framework. To this end, three physical effects are coupled: rigid body dynamics, fluid flow modelled by a lattice Boltzmann algorithm, and electric potentials represented by a finite volume discretisation. For solving the finite volume discretisation for the electrostatic forces, a cell-centered multigrid algorithm is developed that conforms to the lattice Boltzmann meshes and the parallel communication structure of waLBerla. The new functionality is validated with suitable benchmark scenarios. Additionally, the parallel scaling and the numerical efficiency of the algorithms are analysed on an advanced supercomputer.

Bartuschat, Dominik

2014-01-01T23:59:59.000Z

412

Wavelet-based Adaptive Techniques Applied to Turbulent Hypersonic Scramjet Intake Flows  

E-Print Network (OSTI)

The simulation of hypersonic flows is computationally demanding due to large gradients of the flow variables caused by strong shock waves and thick boundary or shear layers. The resolution of those gradients imposes the use of extremely small cells in the respective regions. Taking turbulence into account intensives the variation in scales even more. Furthermore, hypersonic flows have been shown to be extremely grid sensitive. For the simulation of three-dimensional configurations of engineering applications, this results in a huge amount of cells and prohibitive computational time. Therefore, modern adaptive techniques can provide a gain with respect to computational costs and accuracy, allowing the generation of locally highly resolved flow regions where they are needed and retaining an otherwise smooth distribution. An h-adaptive technique based on wavelets is employed for the solution of hypersonic flows. The compressible Reynolds averaged Navier-Stokes equations are solved using a differential Reynolds s...

Frauholz, Sarah; Reinartz, Birgit U; Mller, Siegfried; Behr, Marek

2013-01-01T23:59:59.000Z

413

Capacitive and Solution Resistance Effects on Voltammetric Responses of a Thin Redox Layer Attached to Disk Microelectrodes  

Science Journals Connector (OSTI)

E*(r,t) is the effective potential across the interface between the metal conductor and its adjacent solution at the distance r from the electrode center: where E is the applied potential; di(r,?t) is the overall current through the elementary ring; dRe(r) is the resistance of the current tube associated with the same ring. ... It shows that the derivative of the overall current (with respect to time) flowing through an electrode surface element (being an infinitesimally thin ring for the disk electrode) is given by the difference between the increment of the capacitive current when the faradaic process is absent (dCdl(r)v) and that flowing (dicap(r,??t)) in the system, related to the elementary time constant (dRe(r)?dCdl(r)) of the surface element. ... Figure 4. Equivalent electric circuit. ...

Christian Amatore; Alexander Oleinick; Irina Svir

2008-10-01T23:59:59.000Z

414

FUEL CELLS SOLID OXIDE FUEL CELLS | Gas Distribution  

Science Journals Connector (OSTI)

A uniform distribution of the reactants over the total available electrode surfaces in solid oxide fuel cells (SOFCs) is a prerequisite for the proper operation of the fuel cell. The gas distribution plays a dominant role not only in the current density distribution but also in the temperature distribution over the cell areas and in the stack and modules. Several transport mechanisms for mass transport occurring in the SOFC are introduced and discussed. General flow configurations and structures for the gas distribution at three different levels, i.e., stack/module, cell/tube, and electrode/electrolyte, are discussed for both tubular and planar type cells and illustrated with examples of concentration and temperature profiles.

L.G.J. de Haart; M. Spiller

2009-01-01T23:59:59.000Z

415

Platinum-CatalyzedOxidations of Organic Compounds by Ferric Sulfate: Use of a Redox Fuel Cell to Mediate Complete Oxidation of  

E-Print Network (OSTI)

and complete oxidation of ethylene glycolto carbon dioxide under mild conditionsusing dioxy- gen operating with ethylene glycol as fuel (5, 10-12). METHODS Materials. Methanol, ethanol, and ethylene catalyst was determined to be 3.3 X mol/g Pt (6.44% dispersion) by alternating titration with hydrogen

Prentiss, Mara

416

Evaluation of Immobilized Enzyme in a High-Surface-Area Biofuel Cell Electrode Made of Redox-Polymer-Grafted Carbon Black  

Science Journals Connector (OSTI)

In recent years, nanocarbon materials like carbon black, carbon nanotubes, and carbon aerogel particles have been used by several groups to form three-dimensional electrodes. ... The TEM micrograph of the GOD-coated electrode was shown in Figure 2A. Figure 2B shows magnified image of the dotted frame in Figure 2A. The location of GOD and carbon black in Figure 2B was indicated in Figure 2C. A few tens of stained GOD, which were small black spots with a diameter of about 5 nm, were dispersed on each carbon black particle, which was a gray spot with a diameter of about 30 nm. ...

Takanori Tamaki; Atsushi Hiraide; Faizly B. Asmat; Hidenori Ohashi; Taichi Ito; Takeo Yamaguchi

2010-06-17T23:59:59.000Z

417

Lack of Respiratory Chain Complex I Impairs Alternative Oxidase Engagement and Modulates Redox Signaling during Elicitor-Induced Cell Death in Tobacco  

Science Journals Connector (OSTI)

...and CMSII leaves (arbitrary units [a.u.]). Protein gel...before and after addition of 1 unit of ascorbate oxidase was converted...throughout the experiment. All stocks were freshly prepared before...Ascorbate and glutathione: Keeping active oxygen under control...

Guillaume Vidal; Miquel Ribas-Carbo; Marie Garmier; Guy Dubertret; Allan G. Rasmusson; Chantal Mathieu; Christine H. Foyer; Rosine De Paepe

2007-02-02T23:59:59.000Z

418

Cytology Automation by Flow Cytometry  

Science Journals Connector (OSTI)

...measured individually at rates of several hundred/sec...sured individually at rates of several hundred/sec...individually by flow cytometry at rates of several hundred/sec...flow cytometer (Bio/ Physics Systems Cytofluono graf...instrument and are made to pass through a 250-@rn-diameter...

Myron R. Melamed; Zbigniew Darzynkiewicz; Frank Traganos; and Thomas Sharpless

1977-08-01T23:59:59.000Z

419

Earth's Crust: Heat Flow Relationships  

Science Journals Connector (OSTI)

... of heat flow through the Earth's surface at any point requires two measurements, the geothermal gradient itself and the thermal conductivity of the adjacent rocks. In the oceanic crust, ... variations in heat flow from point to point are governed essentially by variations in the geothermal gradient. In continents, however, the story is different. Correlation and regression analyses carried ...

Our Geomagnetism Correspondent

1970-07-11T23:59:59.000Z

420

Integrated Adaptive Numerical Methods for Transient Two-phase Flow in Heterogeneous Porous Media  

E-Print Network (OSTI)

remediation, magma flow in the earth crust and water management in porous electrodes of PEM fuel cells in fuel cells. This thesis presents a set of algorithms that are integrated efficiently to achieve the transport equations which elim- inates unnecessary and costly solution of the implicit pressure

Victoria, University of

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

A second-order coupled immersed boundary-SAMR construction for chemically reacting flow over a  

E-Print Network (OSTI)

is limited to a two-dimensional Cartesian grid-conforming solid. We validate the code using benchmark-order numerical method for simulations of reacting flow around heat-conducting immersed solid objects. The method the interior of the numerical domain; irrespective of whether it describes fluid or solid cells. Solid cells

Ray, Jaideep

422

MICROFLUIDIC DEVICE WITH INTEGRATED ANTIBODY ARRAYS FOR CELL SIGNALLING  

E-Print Network (OSTI)

MICROFLUIDIC DEVICE WITH INTEGRATED ANTIBODY ARRAYS FOR CELL SIGNALLING ANALYSIS J. El-Ali1 , S we present the integration of protein arrays with a microfluidic device for analysis of cell a microfluidic segmented flow device that could achieve rapid stimulus and lysis of cells [1][2]. The device had

423

Water Management in Polymer Electrolyte Membrane (PEM) Fuel Cells  

E-Print Network (OSTI)

Water Management in Polymer Electrolyte Membrane (PEM) Fuel Cells Catherine Chan & Lauren Isbell objectives Important variables that lead to results Conclusion #12;Basic Operation of a PEM Fuel Cell fuel cell? A flow channel? The importance of water management Experimental setup and methods Project

Petta, Jason

424

Flow Duration Curve Load Duration Curve  

E-Print Network (OSTI)

given flow and concentration data--select appropriate conversion factors 3. Develop Load Duration Curve 4. Plot observed data with Load Duration Curve #12;What are they? How do you make one? #12;DescribesRangeFlows LowFlows 40 % of the time there has been no flow at this site #12;Gather daily flow rate data Load

425

Solid oxide fuel cell with monolithic core  

DOE Patents (OSTI)

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

McPheeters, C.C.; Mrazek, F.C.

1988-08-02T23:59:59.000Z

426

Solid oxide fuel cell with monolithic core  

DOE Patents (OSTI)

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

McPheeters, Charles C. (Plainfield, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1988-01-01T23:59:59.000Z

427

Method for sensing and measuring a concentration or partial pressure of a reactant used in a redox reaction  

DOE Patents (OSTI)

A method for sensing or measuring the partial pressure or concentration of an electroactive species used in conjunction with an electrolyte, the method being characterized by providing a constant current between an anode and a cathode of an electrolyte-containing cell, while measuring changes in voltage that occur between either the anode and cathode or between a reference electrode and one of the main electrodes of the cell, thereby to determine the concentration or partial pressure of the electro-active species as a function of said measured voltage changes. The method of the invention can be practiced using either a cell having only an anode and a cathode, or using a cell having an anode and a cathode in combination with a reference electrode. Accurate measurements of small concentrations or partial pressures of electro-active species are obtainable with the method of the invention, by using constant currents of only a few microamperes between the anode and cathode of the cell, while the concentration-determining voltage is measured.

Findl, E.

1984-12-21T23:59:59.000Z

428

Investigation of the performance and water transport of a polymer electrolyte membrane (pem) fuel cell  

E-Print Network (OSTI)

Fuel cell performance was obtained as functions of the humidity at the anode and cathode sites, back pressure, flow rate, temperature, and channel depth. The fuel cell used in this work included a membrane and electrode assembly (MEA) which...

Park, Yong Hun

2009-05-15T23:59:59.000Z

429

A Study on Control of a Small Fuel Cell Power Supply System for Robots  

Science Journals Connector (OSTI)

A hydrogen fuel cell power supply system which includes pressure valve, solenoid valves, flow controllers, temperature sensors and Proton Exchange Membrane Fuel Cell ... is presented in the paper. The power supply

Kuo-Ching Tseng; Pao-Chuan Tseng; Shih-Hsien Yang

2011-01-01T23:59:59.000Z

430

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Hanford Site, USA  

SciTech Connect

Technetium is an important environmental contaminant introduced by the processing and disposal of irradiated nuclear fuel and atmospheric nuclear tests. Under oxic conditions technetium is soluble and exists as pertechnatate anion (TcO4-), while under anoxic conditions Tc is usually insoluble and exists as precipitated Tc(IV). Here we investigated abiotic Tc(VII) reduction in mineralogically heterogeneous, Fe(II)-containing sediments. The sediments were collected from a 55 m borehole that sampled a semi-confined aquifer at the Hanford Site, USA that contained a dramatic redox transition zone. One oxic facies (18.0-18.3 m) and five anoxic facies (18.3-18.6 m, 30.8-31.1 m, 39.0-39.3 m, 47.2-47.5 m and 51.5-51.8 m) were selected for this study. Chemical extractions, X-ray diffraction, electron microscopy, and Mssbauer spectroscopy were applied to characterize the Fe(II) mineral suite that included: Fe(II)-phyllosilicates, pyrite, magnetite and siderite. The Fe(II) mineral phase distribution differed between the sediments. Sediment suspensions were adjusted to the same 0.5 M HCl extracted Fe(II) concentration (0.6 mM) for Tc(VII) reduction experiments. Aqueous Fe was low in all sediment suspensions (<2 ?M) and below the Fe(II)aq detection limit (10 ?M). Technetium(VII) reduction occurred in all anoxic sediments at depths greater than 18.3 m and reaction time differed significantly between the sediments (8-219 d). Mssbauer analysis of the Tc-reacted, 30.8-31.1 m sediment confirmed that Tc(VII) was reduced by solid-phase Fe(II), with siderite and Fe(II)-containing phyllosilicates implicated as redox reactive phases. Technetium-XAS analysis demonstrated that Tc associated with sediments was in the Tc(IV) valence state and immobilized as clusters of a TcO2nH2O-like phase. The speciation of redox product Tc(IV) was not affected by reduction rate or Fe(II) mineralogy.

Peretyazhko, Tetyana; Zachara, John M.; Kukkadapu, Ravi K.; Heald, Steve M.; Kutnyakov, Igor V.; Resch, Charles T.; Arey, Bruce W.; Wang, Chong M.; Kovarik, Libor; Phillips, Jerry L.; Moore, Dean A.

2012-09-01T23:59:59.000Z

431

Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte Ranga S. Jayashree, Michael Mitchell, Dilip Natarajan, Larry J. Markoski, and  

E-Print Network (OSTI)

Letters Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte Ranga S. Jayashree, Michael and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion membrane as the electrolyte. We studied the effect of cell resistance, hydrogen and oxygen flow rates

Kenis, Paul J. A.

432

Progress with multigrid schemes for hypersonic flow problems  

SciTech Connect

Several multigrid schemes are considered for the numerical computation of viscous hypersonic flows. For each scheme, the basic solution algorithm employs upwind spatial discretization with explicit multistage time stepping. Two-level versions of the various multigrid algorithms are applied to the two-dimensional advection equation, and Fourier analysis is used to determine their damping properties. The capabilities of the multigrid methods are assessed by solving three different hypersonic flow problems. Some new multigrid schemes based on semicoarsening strategies are shown to be quite effective in relieving the stiffness caused by the high-aspect-ratio cells required to resolve high Reynolds number flows. These schemes exhibit good convergence rates for Reynolds numbers up to 200 X 10{sup 6} and Mach numbers up to 25. 32 refs., 31 figs., 1 tab.

Radespiel, R. [DLR, Braunschweig (Germany)] [DLR, Braunschweig (Germany); Swanson, R.C. [NASA Langley Research Center, Hampton, VA (United States)] [NASA Langley Research Center, Hampton, VA (United States)

1995-01-01T23:59:59.000Z

433

The transition from two phase bubble flow to slug flow  

E-Print Network (OSTI)

The process of transition from bubble to slug flow in a vertical pipe has been studied analytically and experimentally. An equation is presented which gives the agglomeration time as a function of void fraction, channel ...

Radovcich, Nick A.

1962-01-01T23:59:59.000Z

434

Journal of the Geological Society, London, Vol. 168, 2011, pp. 805815. doi: 10.1144/0016-76492010-132. Hydrothermal origin of elevated iron, manganese and redox-sensitive trace  

E-Print Network (OSTI)

.1144/0016-76492010-132. 805 Hydrothermal origin of elevated iron, manganese and redox-sensitive trace elements in the c. 635 Ma Doushantuo cap carbonate JING HUANG1,2 , XUELEI CHU1,2 *, GANQING JIANG3 , LIANJUN FENG1 & HUAJIN, including REE, concentrations of the Doushantuo cap carbonate (c. 635 Ma) in South China show enrichment

Jiang, Ganqing

435

Contact-mediated cell-assisted cell proliferation in a model eukaryotic single-cell organism: An explanation for the lag phase in shaken cell culture  

Science Journals Connector (OSTI)

In cell culture, when cells are inoculated into fresh media, there can be a period of slow (or lag phase) growth followed by a transition to exponential growth. This period of slow growth is usually attributed to the cells adaptation to a new environment. However, we argue that, based on observations of shaken suspension culture of Dictyostelium discoideum, a model single-cell eukaryote, this transition is due to a density effect. Attempts to demonstrate the existence of implicit cell signaling via long-range diffusible messengers (i.e., soluble growth factors) through cell-medium separation and microfluidic flow perturbation experiments produced negative results. This, in turn, led to the development of a signaling model based on direct cell-to-cell contacts. Employing a scaling argument for the collision rate due to fluid shear, we reasonably estimate the crossover density for the transition into the exponential phase and fit the observed growth kinetics.

Carl Franck; Wui Ip; Albert Bae; Nathan Franck; Elijah Bogart; Thanhbinh Thi Le

2008-04-11T23:59:59.000Z

436

Gas flow characterization of restrictive flow orifice devices  

SciTech Connect

A restrictive flow orifice (RFO) can be used to limit the uncontrolled release of system media upon component or line failure in a gas handling system and can thereby enhance the system safety. This report describes a new RFO product available from the Swagelok Companies and specifies the gas flow characteristics of this device. A family of four different sizes of RFO devices is documented.

Shrouf, R.G. [Sandia National Labs., Albuquerque, NM (United States). Safety Engineering Dept.; Page, S.R. [Albuquerque Valve and Fitting Co., NM (United States)

1997-07-01T23:59:59.000Z

437

Proper planning improves flow drilling  

SciTech Connect

Underbalanced operations reduce formation damage, especially in horizontal wells where zones are exposed to mud for longer time periods. Benefits, risks, well control concerns, equipment and issues associated with these operations are addressed in this paper. Flow drilling raises many concerns, but little has been published on horizontal well control and flow drilling operations. This article covers planning considerations for flow drilling, but does not address horizontal ''overbalanced'' drilling because considerations and equipment are the same as in vertical overbalanced drilling and many references address that subject. The difference in well control between vertical and horizontal overbalanced drilling is fluid influx behavior and how that behavior affects kill operations.

Collins, G.J. (Marathon Oil Co., Houston, TX (United States))

1994-10-01T23:59:59.000Z

438

Zonal flow as pattern formation  

SciTech Connect

Zonal flows are well known to arise spontaneously out of turbulence. We show that for statistically averaged equations of the stochastically forced generalized Hasegawa-Mima model, steady-state zonal flows, and inhomogeneous turbulence fit into the framework of pattern formation. There are many implications. First, the wavelength of the zonal flows is not unique. Indeed, in an idealized, infinite system, any wavelength within a certain continuous band corresponds to a solution. Second, of these wavelengths, only those within a smaller subband are linearly stable. Unstable wavelengths must evolve to reach a stable wavelength; this process manifests as merging jets.

Parker, Jeffrey B.; Krommes, John A. [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States)] [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States)

2013-10-15T23:59:59.000Z

439

Two phase flow in capillary tubes  

E-Print Network (OSTI)

The flow of two phases, gas and liquid, has been studied in horizontal tubes of capillary diameter. The flow has been primarily studied in the regime where the gas flows as long bubbles separated from the wall of the tube ...

Suo, Mikio

1963-01-01T23:59:59.000Z

440

MICRO/MACROSCOPIC FLUID FLOW IN OPEN CELL FIBROUS STRUCTURES  

E-Print Network (OSTI)

, which is a novel approach in Microfluidics. To verify the developed models, several testbeds have been

Bahrami, Majid

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

An algebraic model for a zinc/bromine flow cell  

E-Print Network (OSTI)

OF LITERATURE III. MODEL DEVELOPMENT IV. MODEL SOLUTION a. Steady-State b. Unsteady-State . c. Psuedo Steady-State V. DISCUSSION OF RESULTS . a. Steady-State b. Unsteady-State . c. Psuedo Steady-State VI. CONCLUSIONS VII. FUTURE WORK . LIST... adjacent to anode Early time response of potential adjacent to cathode Early time response of Zn+z adjacent to cathode Early time response of Brz adjacent to cathode Early time response of Brs adjacent to cathode Early time response of Br adjacent...

Simpson, Gary Don

2012-06-07T23:59:59.000Z

442

Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer,...

443

The lattice Boltzmann method for complex flows.  

E-Print Network (OSTI)

??This thesis presents the extension of the lattice Boltzmann equation (LBE) to several well-known flows. First, the flow over a cylinder is studied using the (more)

Reis, Tim

2007-01-01T23:59:59.000Z

444

COMMON SENSE REASONING ABOUT PETROLEUM FLOW  

E-Print Network (OSTI)

SENSE REASONING ABOUT . PETROLEUM FLOW Steven Rosenberg I 'Sense Reasoning about Petroleum Flow By Steven Rosenbergand reasoning in a petroleum resources domain. A basic model

Rosenberg, Steven

2014-01-01T23:59:59.000Z

445

Category:Flow Test | Open Energy Information  

Open Energy Info (EERE)

| Sign Up Search Category Edit History Facebook icon Twitter icon Category:Flow Test Jump to: navigation, search Geothermalpower.jpg Looking for the Flow Test page? For...

446

Acoustic concentration of particles in fluid flow  

SciTech Connect

An apparatus for acoustic concentration of particles in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. The fluid flow path is in fluid communication with a fluid source and a fluid outlet and the vibration generator is disposed adjacent the fluid flow path and is capable of producing an acoustic field in the fluid flow path. The acoustic field produces at least one pressure minima in the fluid flow path at a predetermined location within the fluid flow path and forces predetermined particles in the fluid flow path to the at least one pressure minima.

Ward, Michael D. (Los Alamos, NM); Kaduchak, Gregory (Los Alamos, NM)

2010-11-23T23:59:59.000Z

447

Acoustic Concentration Of Particles In Fluid Flow  

NLE Websites -- All DOE Office Websites (Extended Search)

in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. Available for thumbnail of...

448

Coal flows | OpenEI  

Open Energy Info (EERE)

Coal flows Coal flows Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 142, and contains only the reference case. The dataset uses million short tons. The data is broken down into steam coal exports to Europe, Asia and America. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords 2011 AEO Coal flows countries EIA exporting importing Data application/vnd.ms-excel icon AEO2011: World Steam Coal Flows By Importing Regions and Exporting Countries- Reference Case (xls, 103.7 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License

449

Multiscale modeling in granular flow  

E-Print Network (OSTI)

Granular materials are common in everyday experience, but have long-resisted a complete theoretical description. Here, we consider the regime of slow, dense granular flow, for which there is no general model, representing ...

Rycroft, Christopher Harley

2007-01-01T23:59:59.000Z

450

Studies of Flows in Plasmas  

SciTech Connect

Note a pdf document "DOE-flow-final-report' should be attached. If it somehow is not please notify Walter Gekelman (gekelman@physics.ucla.edu) who will e mail it directly

Gekelman, Walter; Morales, George; Maggs, James

2009-03-07T23:59:59.000Z

451

Fluid Flow Modeling in Fractures  

E-Print Network (OSTI)

In this paper we study fluid flow in fractures using numerical simulation and address the challenging issue of hydraulic property characterization in fractures. The methodology is based on Computational Fluid Dynamics, ...

Sarkar, Sudipta

2004-01-01T23:59:59.000Z

452

Capillary flows in flexible structures  

E-Print Network (OSTI)

Interactions between capillary and elastic effects are relevant to a variety of applications, from micro- and nano-scale manufacturing to biological systems. In this thesis, we investigate capillary flows in extremely ...

Hoberg, Theresa B. (Theresa Blinn)

2013-01-01T23:59:59.000Z

453

Flow assurance and multiphase pumping  

E-Print Network (OSTI)

. LITERATURE REVIEW???????????????????????????????????.. 5 Deepwater Oilfields???????????????????????????????????.. 7 Flow Assurance?????????????????????????????????????.. 9 Hydrate Management??????????????????????????????????. 11 Stranded Gas...???????????????????????????????????????.. 172 Management in Oil and Gas???????????????????????????????. 172 Constraints and Recent Advances????????????????????????????. 173 Optimization for Oilfield Management??????????????????????????. 174 Asset Management...

Nikhar, Hemant G.

2009-05-15T23:59:59.000Z

454

Energy flows, metabolism and translation  

Science Journals Connector (OSTI)

...L. , Pascal, R. 2011 Energy sources, self-organization...E. 1946 What's life. New York, NY: McMillan. 14 Lotka...nonequilibrium systems. New York, NY: Wiley. 17 Morowitz, H. , Smith, E. 2007 Energy flow and the organization...

2011-01-01T23:59:59.000Z

455

Equidistribution results for geodesic flows  

E-Print Network (OSTI)

Using the works of Ma\\~n\\'e \\cite{Ma} and Paternain \\cite{Pat} we study the distribution of geodesic arcs with respect to equilibrium states of the geodesic flow on a closed manifold, equipped with a $\\mathcal{C}^{\\infty}$ Riemannian metric. We prove large deviations lower and upper bounds and a contraction principle for the geodesic flow in the space of probability measures of the unit tangent bundle. We deduce a way of approximating equilibrium states for continuous potentials.

Abdelhamid Amroun

2011-09-15T23:59:59.000Z

456

Expert systems for flow cytometry data analysis: A preliminary report  

SciTech Connect

Flow Cytometry has become an accepted technique in the clinical laboratory for rapid immunophenotyping of patient blood samples. Multiple, fluorescent labeled monoclonal antibodies are used to tag the cells, which are then analyzed one at a time at rates of several thousand cells a second. Patient samples are processed through the flow cytometer at more than one a minute. Clinicians are being overwhelmed by the large amount of data that must be analyzed to provide the information needed to assist in disease diagnosis. An expert system is being developed to assist clinicians in analyzing this multivariate flow cytometry data. The data from each sample are processed by a clustering algorithm, which finds the means of the distinct cell subpopulations in a sample. These mean values of fluorescence are translated into words such as negative,'' dim'' and bright'' and the words are combined into patterns that are matched against the premises on the left hand side of the rules used to identify the disease categories. This is a report of work in progress. 13 refs., 4 figs.

Salzman, G.C. (Los Alamos National Lab., NM (USA)); Stewart, C.C. (Roswell Park Memorial Inst., Buffalo, NY (USA). Lab. of Flow Cytometry); Duque, R.E. (Norwood Clinic, Birmingham, AL (USA))

1990-01-01T23:59:59.000Z

457

Subcritical dynamos in shear flows  

E-Print Network (OSTI)

Identifying generic physical mechanisms responsible for the generation of magnetic fields and turbulence in differentially rotating flows is fundamental to understand the dynamics of astrophysical objects such as accretion disks and stars. In this paper, we discuss the concept of subcritical dynamo action and its hydrodynamic analogue exemplified by the process of nonlinear transition to turbulence in non-rotating wall-bounded shear flows. To illustrate this idea, we describe some recent results on nonlinear hydrodynamic transition to turbulence and nonlinear dynamo action in rotating shear flows pertaining to the problem of turbulent angular momentum transport in accretion disks. We argue that this concept is very generic and should be applicable to many astrophysical problems involving a shear flow and non-axisymmetric instabilities of shear-induced axisymmetric toroidal velocity or magnetic fields, such as Kelvin-Helmholtz, magnetorotational, Tayler or global magnetoshear instabilities. In the light of several recent numerical results, we finally suggest that, similarly to a standard linear instability, subcritical MHD dynamo processes in high-Reynolds number shear flows could act as a large-scale driving mechanism of turbulent flows that would in turn generate an independent small-scale dynamo.

F. Rincon; G. I. Ogilvie; M. R. E. Proctor; C. Cossu

2008-05-09T23:59:59.000Z

458

Pressure and flow characteristics of restrictive flow orifice devices.  

SciTech Connect

A Restrictive Flow Orifice (RFO) can be used to enhance the safe design of a pressure system in several ways. Pressure systems frequently incorporate a regulator and relief valve to protect the downstream equipment from accidental overpressure caused by regulator failure. Analysis frequently shows that in cases of high-flow regulator failure, the downstream pressure may rise significantly above the set pressure of the relief valve. This is due to limited flow capacity of the relief valve. A different regulator or relief valve may need to be selected. A more economical solution to this problem is to use an RFO to limit the maximum system flow to acceptable limits within the flow capacity of the relief valve, thereby enhancing the overpressure protection of laboratory equipment. An RFO can also be used to limit the uncontrolled release of system fluid (gas or liquid) upon component or line failure. As an example, potential asphyxiation hazards resultant from the release of large volumes of inert gas from a 'house' nitrogen system can be controlled by the use of an RFO. This report describes a versatile new Sandia-designed RFO available from the Swagelok Company and specifies the gas flow characteristics of this device. Two sizes, 0.010 and 0.020 inch diameter RFOs are available. These sizes will allow enhanced safety for many common applications. This new RFO design are now commercially available and provide advantages over existing RFOs: a high pressure rating (6600 psig); flow through the RFO is equal for either forward or reverse directions; they minimize the potential for leakage by incorporating the highest quality threaded connections; and can enhance the safety of pressure systems.

Shrouf, Roger D.

2003-06-01T23:59:59.000Z

459

Microstructured Hydrogen Fuel Cells  

Science Journals Connector (OSTI)

Micro fuel cells ; Polymer electrolyte membrane fuel cells ; Proton exchange membrane fuel cells ...

Luc G. Frechette

2014-05-01T23:59:59.000Z

460

Mechanotransduction of fluid stresses governs 3D cell migration  

E-Print Network (OSTI)

Solid tumors are characterized by high interstitial fluid pressure, which drives fluid efflux from the tumor core. Tumor-associated interstitial flow (IF) at a rate of ?3 m/s has been shown to induce cell migration in the ...

Polacheck, William J.

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Method for single-cell mass and electrophoretic mobility measurement  

E-Print Network (OSTI)

Analysis of single cells using flow cytometry techniques has created a wealth of knowledge about cellular phenomena that could not be obtained by population average measurements. As these techniques are integrated with ...

Dextras, Philip

2010-01-01T23:59:59.000Z

462

Regional neurohypophysial and hypothalamic blood flow in rats during hypercapnia  

SciTech Connect

Regional cerebral blood flow (rCBF) was measured in the neurohypophysis and hypothalamus in normocapnic and hypercapnic rats using (/sup 14/C)isopropyliodoamphetamine. Rats were surgically prepared using nitrous oxide and halothane and placed in plaster restraining casts. Hypercapnia was produced by increasing the fractional concentration of inspired CO/sub 2/ (FICO/sub 2/). rCBF in normocapnic rats was higher in the paraventricular nucleus, supraoptic nucleus, median eminence, and neural lobe than rates previously measured by use of diffusible tracers. During hypercapnia blood flow increased linearly with arterial PCO/sub 2/ (PACO/sub 2/) in all regions except the median eminence and neural lobe, which were not affected by hypercapnia. When rats were pretreated with phentolamine (1 mg/kg) to block the alpha-adrenergic receptors, blood flow in the median eminence and neural lobe increased significantly during hypercapnia. We conclude that blood flow in the cell bodies of the paraventricular nucleus and supraoptic nucleus is regulated differently during hypercapnia than blood flow in the nerve terminals in the median eminence and neural lobe. Furthermore, vasodilation produced by increased CO/sub 2/ is offset by alpha-receptor stimulation in the median eminence and neural lobe.

Bryan, R.M. Jr.; Myers, C.L.; Page, R.B.

1988-08-01T23:59:59.000Z

463

article  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and cycling of the iron ion hydrogen redox flow cell Performance and cycling of the iron ion hydrogen redox flow cell with various catholyte salts journal Journal of Applied Electrochemistry volume year month pages abstract p A redox flow cell utilizing the Fe2 Fe3 and H H couples is investigated as an energy storage device A conventional polymer electrolyte fuel cell anode and membrane design is employed with a cathode chamber containing a carbon felt flooded with aqueous acidic solution of iron salt The maximum power densities achieved for iron sulfate iron chloride and iron nitrate are and mW cm respectively It is found that the capacity of the iron nitrate solution decreases rapidly during cycling Stable cycling is observed for more than h with iron chloride and iron sulfate solutions Both iron sulfate and iron chloride

464

SHORT-TUBE SUBCRITICAL FLOW Enerag Division  

E-Print Network (OSTI)

#12;SHORT-TUBE SUBCRITICAL FLOW Y. C. Mei Enerag Division Oak Ridge National Laboratory Oak Ridge-tube subcritical flow. For short tubes used as refrigerant expansion devices, the orifice model is found inadequate-TUBE SUBCRITICAL FLOW INTRODUCTION Much theoretical and experimental work regarding short tube fluid flow has

Oak Ridge National Laboratory

465

Microbial Adhesion in Flow Displacement Systems  

Science Journals Connector (OSTI)

...surface in flow displacement systems...in a flow displacement system contributes...substratum surface, is the...is the contact angle between...established parabolic flow between parallel plates. FIG. 9...more than half the length...and right: After addition...rectangular flow displacement systems Configuration...liquid surface tension...degrees) , contact angle between...wall shear stress (N m2...

Henk J. Busscher; Henny C. van der Mei

2006-01-01T23:59:59.000Z

466

Stochastic models for turbulent reacting flows  

SciTech Connect

The goal of this program is to develop and apply stochastic models of various processes occurring within turbulent reacting flows in order to identify the fundamental mechanisms governing these flows, to support experimental studies of these flows, and to further the development of comprehensive turbulent reacting flow models.

Kerstein, A. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01T23:59:59.000Z

467

Mach flow angularity probes for scramjet engine flow path diagnostics  

SciTech Connect

Mach-flow angularity (MFA) probes were developed for use in scramjet flow path probe rakes. Prototype probes were fabricated to demonstrate the assembly processes (numerical control machining, furnace brazing, and electron beam welding). Tests of prototype probes confirmed the thermal durability margins and life cycle. Selected probes were calibrated in air at Mach numbers from 1.75 to 6.0. Acceptance criteria for the production probes stressed thermal durability and pressure (and, consequently, Mach number) measurement quality. This new water-cooled MFA probe has 0.397-cm shaft diameter and is capable of withstanding heat fluxes of 2.724 kW/sq cm.

Jalbert, P.A.; Hiers, R.S. Jr. [Sverdrup Technology, Inc., Arnold AFS, TN (United States)

1993-12-31T23:59:59.000Z

468

Annular feed air breathing fuel cell stack  

DOE Patents (OSTI)

A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. The fuel distribution manifold is formed from a hydrophilic-like material to redistribute water produced by fuel and oxygen reacting at the cathode. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

Wilson, Mahlon S. (Los Alamos, NM); Neutzler, Jay K. (Peoria, AZ)

1997-01-01T23:59:59.000Z

469

Renormalization Group and the Ricci flow  

E-Print Network (OSTI)

We discuss from a geometric point of view the connection between the renormalization group flow for non--linear sigma models and the Ricci flow. This offers new perspectives in providing a geometrical landscape for 2D quantum field theories. In particular we argue that the structure of Ricci flow singularities suggests a natural way for extending, beyond the weak coupling regime, the embedding of the Ricci flow into the renormalization group flow.

Mauro Carfora

2010-01-20T23:59:59.000Z

470

11 - Knowledge Flow in Universities  

Science Journals Connector (OSTI)

In this chapter, a typical American university is chosen as a model for the quantitative analysis for the flow of knowledge in a reasonably well-defined academic setting. Knowledge flow assumes quantifiable patterns and much like the flow and retention of rain water over a given terrain of land; the quality (of teaching) and quantity (number of credit hours) of knowledge retained by students is estimated on a qualitative and quantitative basis. The model presented in this chapter is entirely generic. It can be applied in any center of learning and during any period of training, residency in limited time frame, or even to the evolution of species as they gain survival skills, and build their knowledge potential to survive, another generation, calamity, meteor fall, a catastrophic disaster, or a global nuclear fall-out. Though the probability of outcome is not accurately known, it is still bounded by confidence limits.

Syed V. Ahamed

2014-01-01T23:59:59.000Z

471

Pressure compensated flow control valve  

DOE Patents (OSTI)

The invention is an air flow control valve which is capable of maintaining a constant flow at the outlet despite changes in the inlet or outlet pressure. The device consists of a shell assembly with an inlet chamber and outlet chamber separated by a separation plate. The chambers are connected by an orifice. Also located within the inlet chamber is a port controller assembly. The port controller assembly consists of a differential pressure plate and port cap affixed thereon. The cap is able to slide in and out of the orifice separating the inlet and outlet chambers. When the pressure differential is sufficient, the differential pressure plate rises or falls to maintain a constant air flow. Movement of the port controller assembly does not require the use of seals, diaphragms, tight tolerances, bushings, bearings, hinges, guides, or lubricants.

Minteer, Daniel J. (West Richland, WA)

1999-01-01T23:59:59.000Z

472

Flow optimization in diving helmets  

SciTech Connect

Improved carbon dioxide transport from the annular space between the head and helmet is necessary to reduce fresh gas flow and associated noise. This paper gives an overview of new techniques for investigating this transport, and for optimizing helmet flow to remove CO{sub 2}. An analytical model predicts inhaled carbon dioxide fraction in terms of helmet and respiration characteristics. Fundamental behavior over a wide range of helmet parameters is computed. An experimental model uses Reynolds scaling with water and dye to simulate fresh gas and carbon dioxide respectively. The water/dye model supports measurement of inhaled dye concentration, and flow visualization. Detailed behavior is investigated for one helmet with air/CO{sub 2} and water/dye experiments. Results support validity of the analytic and water models, provide new insight to CO{sub 2} transport mechanisms, and suggest directions for optimizing helmet design.

Camperman, J.M. [Naval Surface Warfare Center, Panama City, FL (United States). Coastal Systems Station; Tennant, J.S. [Florida Atlantic Univ., Boca Raton, FL (United States). Ocean Engineering Dept.

1996-09-01T23:59:59.000Z

473

ESS 2012 Peer Review - Flow Battery Solution for Smart Grid Renewable Energy Applications - Sheri Nevins, Raytheon & Ron Moss, EnerVault  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 1 Sheri Nevins Raytheon Ktech Ron Mosso EnerVault Corporation DEMONSTRATION OF ENERGY STORAGE USING A BREAKTHROUGH REDOX FLOW BATTERY TECHNOLOGY v. 1-0 Copyright ©2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 2 Disclaimer This material is partially based upon work supported by NYSERDA under PON1200 Project 15880 NYSERDA has not reviewed the information contained herein, and the opinions expressed in this report do not necessarily reflect those of NYSERDA or the State of New York. This material is partially based upon work supported by the Department of Energy under Award Number DE-OE0000225. This report was prepared as an account of work sponsored by an agency of the United States

474

Rheo-optical determination of flow birefringence and flow dichroism with the pulsed laser method  

E-Print Network (OSTI)

Rheo-optical determination of flow birefringence and flow dichroism with the pulsed laser method online 29 August 2006 Rheo-optical measurements of the flow birefringence, flow dichroism systems under flow. However, the standard setup of an optical train, using phase modulation for the rheo-optical

475

Nuclear reactor downcomer flow deflector  

DOE Patents (OSTI)

A nuclear reactor having a coolant flow deflector secured to a reactor core barrel in line with a coolant inlet nozzle. The flow deflector redirects incoming coolant down an annulus between the core barrel and the reactor vessel. The deflector has a main body with a front side facing the fluid inlet nozzle and a rear side facing the core barrel. The rear side of the main body has at least one protrusion secured to the core barrel so that a gap exists between the rear side of the main body adjacent the protrusion and the core barrel. Preferably, the protrusion is a relief that circumscribes the rear side of the main body.

Gilmore, Charles B. (Greensburg, PA); Altman, David A. (Pittsburgh, PA); Singleton, Norman R. (Murrysville, PA)

2011-02-15T23:59:59.000Z

476

Dynamo action in flows with  

E-Print Network (OSTI)

Dynamo action in flows with cat's eyes A l i c e C o u r v o i s i e r A n d r e w G i l b e r t Y of k for R = 500 and the flow (2.4) and (2.5). nts k = 2.5 and k = 5 are highlighted. Magnetic field). In (a) k = 2.5 and we have 0.5 max Bz (with max Bz 0.6 max |B|), and in (b) k = 5 and the levels .65 max

Li, Yi

477

Multi-stage fuel cell system method and apparatus  

DOE Patents (OSTI)

A high efficiency, multi-stage fuel cell system method and apparatus is provided. The fuel cell system is comprised of multiple fuel cell stages, whereby the temperatures of the fuel and oxidant gas streams and the percentage of fuel consumed in each stage are controlled to optimize fuel cell system efficiency. The stages are connected in a serial, flow-through arrangement such that the oxidant gas and fuel gas flowing through an upstream stage is conducted directly into the next adjacent downstream stage. The fuel cell stages are further arranged such that unspent fuel and oxidant laden gases too hot to continue within an upstream stage because of material constraints are conducted into a subsequent downstream stage which comprises a similar cell configuration, however, which is constructed from materials having a higher heat tolerance and designed to meet higher thermal demands. In addition, fuel is underutilized in each stage, resulting in a higher overall fuel cell system efficiency.

George, Thomas J. (Morgantown, WV); Smith, William C. (Morgantown, WV)

2000-01-01T23:59:59.000Z

478

Water injected fuel cell system compressor  

DOE Patents (OSTI)

A fuel cell system including a dry compressor for pressurizing air supplied to the cathode side of the fuel cell. An injector sprays a controlled amount of water on to the compressor's rotor(s) to improve the energy efficiency of the compressor. The amount of water sprayed out the rotor(s) is controlled relative to the mass flow rate of air inputted to the compressor.

Siepierski, James S. (Williamsville, NY); Moore, Barbara S. (Victor, NY); Hoch, Martin Monroe (Webster, NY)

2001-01-01T23:59:59.000Z

479

Topological Quantum Computation and Error Correction by Biological Cells  

E-Print Network (OSTI)

A Topological examination of phospholipid dynamics in the Far from Equilibrium state has demonstrated that metabolically active cells use waste heat to generate spatially patterned membrane flows by forced convection and shear. This paper explains the resemblance between this nonlinear membrane model and Witten Kitaev type Topological Quantum Computation systems, and demonstrates how this self-organising membrane enables biological cells to circumvent the decoherence problem, perform error correction procedures, and produce classical level output as shielded current flow through cytoskeletal protein conduit. Cellular outputs are shown to be Turing compatible as they are determined by computable in principle hydromagnetic fluid flows, and importantly, are Adaptive from an Evolutionary perspective.

J T Lofthouse

2005-02-02T23:59:59.000Z

480

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Converting chemical energy of hydrogenated fuels into electricity Project Description Invented in 1839, fuels cells powered the Gemini and Apollo space missions, as well as the space shuttle. Although fuel cells have been successfully used in such applications, they have proven difficult to make more cost-effective and durable for commercial applications, particularly for the rigors of daily transportation. Since the 1970s, scientists at Los Alamos have managed to make various scientific breakthroughs that have contributed to the development of modern fuel cell systems. Specific efforts include the following: * Finding alternative and more cost-effective catalysts than platinum. * Enhancing the durability of fuel cells by developing advanced materials and

Note: This page contains sample records for the topic "redox flow cell" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

RAFT: A simulator for ReActive Flow and Transport of groundwater contaminants  

SciTech Connect

This report documents the use of the simulator RAFT for the ReActive flow and Transport of groundwater contaminants. RAFT can be used as a predictive tool in the design and analysis of laboratory and field experiments or it can be used for the estimation of model/process parameters from experiments. RAFT simulates the reactive transport of groundwater contaminants in one, two-, or three-dimensions and it can model user specified source/link configurations and arbitrary injection strategies. A suite of solvers for transport, reactions and regression are employed so that a combination of numerical methods best suited for a problem can be chosen. User specified coupled equilibrium and kinetic reaction systems can be incorporated into RAFT. RAFT is integrated with a symbolic computational language MAPLE, to automate code generation for arbitrary reaction systems. RAFT is expected to be used as a simulator for engineering design for field experiments in groundwater remediation including bioremediation, reactive barriers and redox manipulation. As an integrated tool with both the predictive ability and the ability to analyze experimental data, RAFT can help in the development of remediation technologies, from laboratory to field.

Chilakapati, A.

1995-07-01T23:59:59.000Z

482

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of $175 per kW, and demonstrating lifetime performance degradation of less than 0.2 percent per

483

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust...

484

Comments on "Microscale flow visualization"  

E-Print Network (OSTI)

We make comments on the presentation of Sinton's paper (Microfluidics and Nanofluidics {\\bf 1}: 2, 2004) about the microscale flow visualization since the effects of the roughness along the microfabricated wall upon the current macroflow visualization methods could be significant and cannot be neglected in microdomain and even nanodomain.

A. Kwang-Hua Chu

2005-10-22T23:59:59.000Z

485

Rinse trough with improved flow  

DOE Patents (OSTI)

Novel rinse troughs accomplish thorough uniform rinsing. The troughs are suitable for one or more essentially planar objects having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs provide uniform rinse fluid flow over the objects` surfaces to accomplish a more thorough rinse than prior art troughs. 5 figs.

O`Hern, T.J.; Grasser, T.W.

1998-08-11T23:59:59.000Z

486

Shear instabilities in granular flows  

Science Journals Connector (OSTI)

... of sizes were also tested, but these never produced interfacial waves under any conditions. Roughening either side wall by attaching sandpaper had a minimal effect on the flow, indicating ... to 28. (The shear itself varied by less than 20%.) Second, we roughened the last 10?cm of the chute bottom, thus artificially retarding downstream particles and ...

David J. Goldfarb; Benjamin J. Glasser; Troy Shinbrot

2002-01-17T23:59:59.000Z

487

Superconducting flux flow digital circuits  

DOE Patents (OSTI)

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs) are disclosed. Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics. 8 figs.

Hietala, V.M.; Martens, J.S.; Zipperian, T.E.

1995-02-14T23:59:59.000Z

488

Data Flow Testing Neelam Gupta  

E-Print Network (OSTI)

Data Flow Testing Neelam Gupta The University of Arizona, Tucson, Arizona and Rajiv Gupta The University of Arizona, Tucson, Arizona Software testing techniques are designed to execute a program on a set of test cases that provide su?cient coverage under some speci#12;c well-de#12;ned test coverage criterion

Gupta, Rajiv

489

Hydroplaning of subaqueous debris flows  

Science Journals Connector (OSTI)

...contiguous deposit of a subaqueous flow may be fringed by discrete parcels of debris that appear to have separated from the toe of the...can be introduced at the start of the channel either from a conveyor belt or from a head tank. With the head-tank configuration...

490

Thermodynamics of urban population flows  

Science Journals Connector (OSTI)

Orderliness, reflected via mathematical laws, is encountered in different frameworks involving social groups. Here we show that a thermodynamics can be constructed that macroscopically describes urban population flows. Microscopic dynamic equations and simulations with random walkers underlie the macroscopic approach. Our results might be regarded, via suitable analogies, as a step towards building an explicit social thermodynamics.

A. Hernando and A. Plastino

2012-12-05T23:59:59.000Z

491

Superconducting flux flow digital circuits  

DOE Patents (OSTI)

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs). Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics.

Hietala, Vincent M. (Placitas, NM); Martens, Jon S. (Sunnyvale, CA); Zipperian, Thomas E. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

492

Sedimentation Field Flow Fractionation: Applications  

Science Journals Connector (OSTI)

...FIELD-FLOW FRACTIONATION OF ALKALI-LIBERATED NUCLEAR POLYHEDROSIS-VIRUS FROM GYPSY-MOTH...FRACTIONATION TO RADIOACTIVE-WASTE DISPOSAL, NUCLEAR TECHNOLOGY 51 : 147 ( 1980 ). SOBER...perThe SFFF separation in Fig. 9a was ic dispersant moarbitrarily concluded shortly after...

J. J. Kirkland; W. W. Yau

1982-10-08T23:59:59.000Z

493

Effect of radial transport on compressor tip clearance flow structures and enhancement of stable flow range  

E-Print Network (OSTI)

The relation between tip clearance flow structure and axial compressor stall is interrogated via numerical simulations, to determine how casing treatment can result in improved flow range. Both geometry changes and flow ...

Nolan, Sean Patrick Rock

2005-01-01T23:59:59.000Z

494

A Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow...  

Open Energy Info (EERE)

Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements And Heat-Flow Estimates From The Uk Geothermal Catalogue Jump to: navigation, search OpenEI Reference...

495

Local Nusselt number enhancement during gaseliquid Taylor bubble flow in a square mini-channel: An experimental study  

E-Print Network (OSTI)

- scale mass transfer process, fuel cells, etc. The unique and complex flow characteristics require under, Indian Institute of Technology Kanpur, Kanpur 208016, UP, India a r t i c l e i n f o Article history of the unit cell, i.e., the length of adjacent gas bubble and water plug. ? 2012 Elsevier Masson SAS. All

Khandekar, Sameer

496

Fuel Cell Basics | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Basics Basics Fuel Cell Basics August 14, 2013 - 2:09pm Addthis Photo of two hydrogen fuel cells. Fuel cells are an emerging technology that can provide heat and electricity for buildings and electrical power for vehicles and electronic devices. How Fuel Cells Work Fuel cells work like batteries, but they do not run down or need recharging. They produce electricity and heat as long as fuel is supplied. A fuel cell consists of two electrodes-a negative electrode (or anode) and a positive electrode (or cathode)-sandwiched around an electrolyte. A fuel, such as hydrogen, is fed to the anode, and air is fed to the cathode. Activated by a catalyst, hydrogen atoms separate into protons and electrons, which take different paths to the cathode. The electrons go through an external circuit, creating a flow of electricity. The protons

497

Of Microenvironments and Mammary Stem Cells  

SciTech Connect

In most adult tissues there reside pools of stem and progenitor cells inside specialized microenvironments referred to as niches. The niche protects the stem cells from inappropriate expansion and directs their critical functions. Thus guided, stem cells are able to maintain tissue homeostasis throughout the ebb and flow of metabolic and physical demands encountered over a lifetime. Indeed, a pool of stem cells maintains mammary gland structure throughout development, and responds to the physiological demands associated with pregnancy. This review discusses how stem cells were identified in both human and mouse mammary glands; each requiring different techniques that were determined by differing biological needs and ethical constraints. These studies together create a robust portrait of mammary gland biology and identify the location of the stem cell niche, elucidate a developmental hierarchy, and suggest how the niche might be manipulated for therapeutic benefit.

LaBarge, Mark A; Petersen, Ole W; Bissell, Mina J

2007-06-01T23:59:59.000Z

498

Liquid metal Flow Meter - Final Report  

SciTech Connect

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

499

Fuel cell flooding detection and correction  

DOE Patents (OSTI)

Method and apparatus for monitoring an H.sub.2 -O.sub.2 PEM fuel cells to detect and correct flooding. The pressure drop across a given H.sub.2 or O.sub.2 flow field is monitored and compared to predetermined thresholds of unacceptability. If the pressure drop exists a threshold of unacceptability corrective measures are automatically initiated.

DiPierno Bosco, Andrew (Rochester, NY); Fronk, Matthew Howard (Honeoye Falls, NY)

2000-08-15T23:59:59.000Z

500

Molecular Evolutionary Analysis of Cancer Cell Lines  

Science Journals Connector (OSTI)

...flow diagram of the DNA sequence analysis pipeline. For the cell lines we sequenced, comparisons...manner as a consequence of impaired DNA repair and apoptosis processes). Evolutionary...47-55. 49 Varley KE , Mitra RD. Nested Patch PCR enables highly multiplexed mutation...

Yan Zhang; Michael J. Italia; Kurt R. Auger; Wendy S. Halsey; Stephanie F. Van Horn; Ganesh M. Sathe; Michal Magid-Slav; James R. Brown; and Joanna D. Holbrook

2010-02-01T23:59:59.000Z