National Library of Energy BETA

Sample records for recycled fresh catalytic

  1. Catalytic Reforming Downstream Processing of Fresh Feed Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Process Area Sep-15 Oct-15 Nov-15 Dec-15 Jan-16 Feb-16 View History U.S. 2,837 2,690 2,748 2,812 2,668 2,629 2010-2016 PADD 1 160 185 192 172 192 183 2010-2016 East Coast 144 171 176 155 175 167

  2. ,"Catalytic Reforming Downstream Processing of Fresh Feed Input"

    U.S. Energy Information Administration (EIA) Indexed Site

    Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","2/2016","1/15/2010" ,"Release Date:","4/29/2016" ,"Next Release

  3. Catalytic coal liquefaction with treated solvent and SRC recycle

    DOE Patents [OSTI]

    Garg, Diwakar; Givens, Edwin N.; Schweighardt, Frank K.

    1986-01-01

    A process for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal.

  4. Catalytic coal liquefaction with treated solvent and SRC recycle

    DOE Patents [OSTI]

    Garg, D.; Givens, E.N.; Schweighardt, F.K.

    1986-12-09

    A process is described for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal. 2 figs.

  5. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

    1989-10-17

    A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

  6. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, James B.; Comolli, Alfred G.; McLean, Joseph B.

    1989-01-01

    A process for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600.degree.-750.degree. F. to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650.degree. F. and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-90 lb/hr per ft.sup.3 catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760.degree.-860.degree. F. temperature for further hydrogenation and hydroconversion reactions. A 600.degree.-750.degree. F..sup.+ fraction containing 0-20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials.

  7. Recycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recycling Recycling Reducing our impact requires big and small behavioral changes, from printing pages double-sided to separating metals during multi-million-dollar building projects. April 12, 2012 LANL's progress toward recycling goals: 2008 - 2012. LANL's progress toward recycling goals. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email In FY 2012, our overall recycling rate was 81 percent. Recycling goals Engaging in

  8. Recycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    recycle LANL innovates recycling paths for various materials. Aerosol cans Asphalt Batteries Cardboard Concrete Light bulbs Metal Pallets Paper Tires Toner cartridges Vegetation...

  9. Recycle

    SciTech Connect (OSTI)

    1988-10-01

    ;Contents: The Problem; What`s In Our Trash; Where Does Trash Go; Where Does Our Trash Go; The Solution; What Is Recycling; Why Should We Recycle; A National Goal of 25%; What Can We Recycle; What Do We Do With Our Recyclables.

  10. recycling

    National Nuclear Security Administration (NNSA)

    6%2A en Y-12's rough roads smoothed over with 23,000 tons of recycled asphalt http:nnsa.energy.govblogy%E2%80%9112%E2%80%99s-rough-roads-smoothed-over-23000-tons-recycled-asph...

  11. An integrated approach for the verification of fresh mixed oxide fuel (MOX) assemblies at light water reactor MOX recycle reactors

    SciTech Connect (OSTI)

    Menlove, Howard O; Lee, Sang - Yoon

    2009-01-01

    This paper presents an integrated approach for the verification of mixed oxide (MOX) fuel assemblies prior to their being loaded into the reactor. There is a coupling of the verification approach that starts at the fuel fabrication plant and stops with the transfer of the assemblies into the thermal reactor. The key measurement points are at the output of the fuel fabrication plant, the receipt at the reactor site, and the storage in the water pool as fresh fuel. The IAEA currently has the capability to measure the MOX fuel assemblies at the output of the fuel fabrication plants using a passive neutron coincidence counting systems of the passive neutron collar (PNCL) type. Also. at the MOX reactor pool, the underwater coincidence counter (UWCC) has been developed to measure the MOX assemblies in the water. The UWCC measurement requires that the fuel assembly be lifted about two meters up in the storage rack to avoid interference from the fuel that is stored in the rack. This paper presents a new method to verify the MOX fuel assemblies that are in the storage rack without the necessity of moving the fuel. The detector system is called the Underwater MOX Verification System (UMVS). The integration and relationship of the three measurements systems is described.

  12. Chemical Recycling | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Recycling Chemical Recycling

  13. Recycling Programs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recycling Programs Recycling Programs The Office of Administration manages many recycling activities at DOE Headquarters that significantly impact energy and the environment. The ...

  14. Super recycled water: quenching computers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Super recycled water: quenching computers Super recycled water: quenching computers New facility and methods support conserving water and creating recycled products. Using reverse ...

  15. Recycling | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recycling Recycling In support of the Department's goal of implementing environmental sustainability practices across the complex, all DOE employees and contractors should incorporate the three "R's" of wise resource use as a core principle of their daily activities: reduce, reuse, and recycle. The Department's recycling program at Headquarters earns monetary credits from the GSA which is then credited to the Sheila Jo Watkins Memorial Child Development Centers for tuition assistance

  16. Catalytic reactor

    DOE Patents [OSTI]

    Aaron, Timothy Mark; Shah, Minish Mahendra; Jibb, Richard John

    2009-03-10

    A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

  17. Raney nickel catalytic device

    DOE Patents [OSTI]

    O'Hare, Stephen A.

    1978-01-01

    A catalytic device for use in a conventional coal gasification process which includes a tubular substrate having secured to its inside surface by expansion a catalytic material. The catalytic device is made by inserting a tubular catalytic element, such as a tubular element of a nickel-aluminum alloy, into a tubular substrate and heat-treating the resulting composite to cause the tubular catalytic element to irreversibly expand against the inside surface of the substrate.

  18. Benchmarking survey for recycling.

    SciTech Connect (OSTI)

    Marley, Margie Charlotte; Mizner, Jack Harry

    2005-06-01

    This report describes the methodology, analysis and conclusions of a comparison survey of recycling programs at ten Department of Energy sites including Sandia National Laboratories/New Mexico (SNL/NM). The goal of the survey was to compare SNL/NM's recycling performance with that of other federal facilities, and to identify activities and programs that could be implemented at SNL/NM to improve recycling performance.

  19. Recycling, Source Reduction,

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Recovery and Electricity Generation" "(d)","Relative to National Average Landfill" "GREENHOUSE GAS EFFECTS OF RECYCLING, SOURCE REDUCING, AND COMPOSTING VARIOUS WASTE MATERIALS ...

  20. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  1. Recycling Programs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recycling Programs Recycling Programs The Office of Administration manages many recycling activities at DOE Headquarters that significantly impact energy and the environment. The Department of Energy Headquarters has instituted several recycling programs, starting with standard, solid waste recycling in 1991, and has expanded to include batteries, toner cartridges, carpeting and cell phones. Follow this link for a detailed listing of the products that DOE Headquarters recycles, and where to

  2. Recycle plastics into feedstocks

    SciTech Connect (OSTI)

    Kastner, H.; Kaminsky, W.

    1995-05-01

    Thermal cracking of mixed-plastics wastes with a fluidized-bed reactor can be a viable and cost-effective means to meet mandatory recycling laws. Strict worldwide environmental statutes require the hydrocarbon processing industry (HPI) to develop and implement product applications and technologies that reuse post-consumer mixed-plastics waste. Recycling or reuse of plastics waste has a broad definition. Recycling entails more than mechanical regranulation and remelting of polymers for film and molding applications. A European consortium of academia and refiners have investigated if it is possible and profitable to thermally crack plastics into feedstocks for refining and petrochemical applications. Development and demonstration of pyrolysis methods show promising possibilities of converting landfill garbage into valuable feedstocks such as ethylene, propylene, BTX, etc. Fluidized-bed reactor technologies offer HPI operators a possible avenue to meet recycling laws, conserve raw materials and yield a profit. The paper describes thermal cracking for feedstocks and pyrolysis of polyolefins.

  3. Recycling Magnets | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recycling Magnets Recycling Magnets July 15, 2013 The cost of a nuclear or particle physics experiment can be enormous, several hundred million dollars for the Large Hadron Collider Experiments, ATLAS and CMS at CERN, several tens of millions of dollars for an experiment like our GlueX experiment in Hall D, being built as part of our upgrade project. Among the expensive components of many experiments is a large magnet or sometimes more than one magnet. Sometimes the magnets have interesting

  4. Variable Definitions

    Gasoline and Diesel Fuel Update (EIA)

    Day) Process: Vacuum Distillation Thermal Cracking Thermal Cracking: Coking Thermal Cracking: Delayed Coking Thermal Cracking: Fluid Coking Thermal Cracking: Visbreaking Thermal Cracking: Other/Gas Oil Thermal Cracking: Coking (Barrels/Calendar Day) Catalytic Cracking Fresh Feed Catalytic Cracking Fresh Feed (Barrels/Calendar Day) Catalytic Cracking Recycled Feed Catalytic Hydrocracking Catalytic Hydrocracking: Distillate Catalytic Hydrocracking: Gas Oil Catalytic Hydrocracking: Residual Fuel

  5. Rich catalytic injection

    DOE Patents [OSTI]

    Veninger, Albert (Coventry, CT)

    2008-12-30

    A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

  6. Pollution Prevention, Waste Reduction, and Recycling | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pollution Prevention, Waste Reduction, and Recycling Pollution Prevention, Waste Reduction, and Recycling The DOE Pollution Prevention, Waste Reduction and Recycling Program ...

  7. Bayshore Recycling Solar Project | Open Energy Information

    Open Energy Info (EERE)

    Bayshore Recycling Solar Project Jump to: navigation, search Name Bayshore Recycling Solar Project Facility Bayshore Recycling Solar Project Sector Solar Facility Type Roof-mount...

  8. Who owns the recyclables

    SciTech Connect (OSTI)

    Parker, B.

    1994-05-01

    On March 31, the California Supreme Court decided the much awaited Rancho Mirage'' case (Waste Management of the Desert, Inc., and the City of Rancho Mirage v. Palm Springs Recycling Center, Inc.), and held that the California Integrated Waste Management Act of 1989 does not allow an exclusive franchise for the collection of recyclables not discarded by their owner.'' This ends a three-year slugfest between secondary materials processors in the state and municipalities and their franchised garbage haulers who also collect and process recyclables as part of their exclusive arrangement. Central to this nationally-watched litigation is a most fundamental question in waste management: at what point in time do articles in the solid waste stream become actual or potentially valuable secondary materials

  9. Catalytic cracking process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A.; Baker, Richard W.

    2001-01-01

    Processes and apparatus for providing improved catalytic cracking, specifically improved recovery of olefins, LPG or hydrogen from catalytic crackers. The improvement is achieved by passing part of the wet gas stream across membranes selective in favor of light hydrocarbons over hydrogen.

  10. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.

    1984-01-01

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  11. Super recycled water: quenching computers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Super recycled water: quenching computers Super recycled water: quenching computers New facility and methods support conserving water and creating recycled products. Using reverse osmosis to "super purify" water allows the system to reuse water and cool down our powerful yet thirsty computers. January 30, 2014 Super recycled water: quenching computers LANL's Sanitary Effluent Reclamation Facility, key to reducing the Lab's discharge of liquid. Millions of gallons of industrial

  12. Recycling Data | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recycling Data The Ames Laboratory is committed to pollution prevention and waste minimization. One of the many programs in place to fulfill that commitment is our recycling program. The following chart displays our efforts in recycling over the past five years.

  13. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1982-06-22

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  14. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  15. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1984-04-17

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  16. CNEA Fresh Fuel Plate Characterization Summary Report

    SciTech Connect (OSTI)

    D. Keiser; F. Rice

    2012-02-01

    Characterization summary report outlining the findings of the fresh fuel examinations of the plates received from CNEA.

  17. recycling | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Home recycling Y-12's rough roads smoothed over with 23,000 tons of recycled asphalt Some 23,000 tons of asphalt removed during this summer's UPF site work have been put to use throughout the site. Potholes and gravel roads are now "paved" with the recycled asphalt that has been ground into a material called base course. Unlike gravel, the material tends to rebind into a solid...

  18. Catalytic nanoporous membranes

    DOE Patents [OSTI]

    Pellin, Michael J; Hryn, John N; Elam, Jeffrey W

    2013-08-27

    A nanoporous catalytic membrane which displays several unique features Including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity. Also provided is a method for producing a catalytic membrane having flow-through pores and discreet catalytic clusters adhering to the inside surfaces of the pores.

  19. Emulsified industrial oils recycling

    SciTech Connect (OSTI)

    Gabris, T.

    1982-04-01

    The industrial lubricant market has been analyzed with emphasis on current and/or developing recycling and re-refining technologies. This task has been performed for the United States and other industrialized countries, specifically France, West Germany, Italy and Japan. Attention has been focused at emulsion-type fluids regardless of the industrial application involved. It was found that emulsion-type fluids in the United States represent a much higher percentage of the total fluids used than in other industrialized countries. While recycling is an active matter explored by the industry, re-refining is rather a result of other issues than the mere fact that oil can be regenerated from a used industrial emulsion. To extend the longevity of an emulsion is a logical step to keep expenses down by using the emulsion as long as possible. There is, however, another important factor influencing this issue: regulations governing the disposal of such fluids. The ecological question, the respect for nature and the natural balances, is often seen now as everybody's task. Regulations forbid dumping used emulsions in the environment without prior treatment of the water phase and separation of the oil phase. This is a costly procedure, so recycling is attractive since it postpones the problem. It is questionable whether re-refining of these emulsions - as a business - could stand on its own if these emulsions did not have to be taken apart for disposal purposes. Once the emulsion is separated into a water and an oil phase, however, re-refining of the oil does become economical.

  20. Recycler barrier RF buckets

    SciTech Connect (OSTI)

    Bhat, C.M.; /Fermilab

    2011-03-01

    The Recycler Ring at Fermilab uses a barrier rf systems for all of its rf manipulations. In this paper, I will give an overview of historical perspective on barrier rf system, the longitudinal beam dynamics issues, aspects of rf linearization to produce long flat bunches and methods used for emittance measurements of the beam in the RR barrier rf buckets. Current rf manipulation schemes used for antiproton beam stacking and longitudinal momentum mining of the RR beam for the Tevatron collider operation are explained along with their importance in spectacular success of the Tevatron luminosity performance.

  1. Nuclear recycling | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear recycling Pyroprocessing facilities 1 of 8 Pyroprocessing facilities Frances Dozier conducts pyroprocessing research inside a glovebox at Argonne National Laboratory....

  2. Recycling Energy Yields Super Savings

    Broader source: Energy.gov [DOE]

    One company is actually recycling energy that has already been used to power manufacturing plants, which is helping facilities cut their energy expenses by up to 20 percent.

  3. Catalytic hydrotreating process

    DOE Patents [OSTI]

    Karr, Jr., Clarence; McCaskill, Kenneth B.

    1978-01-01

    Carbonaceous liquids boiling above about 300.degree. C such as tars, petroleum residuals, shale oils and coal-derived liquids are catalytically hydrotreated by introducing the carbonaceous liquid into a reaction zone at a temperature in the range of 300.degree. to 450.degree. C and a pressure in the range of 300 to 4000 psig for effecting contact between the carbonaceous liquid and a catalytic transition metal sulfide in the reaction zone as a layer on a hydrogen permeable transition metal substrate and then introducing hydrogen into the reaction zone by diffusing the hydrogen through the substrate to effect the hydrogenation of the carbonaceous liquid in the presence of the catalytic sulfide layer.

  4. Garbage project on recycling behavior

    SciTech Connect (OSTI)

    McGuire, R.H.; Hughes, W.W.; Rathje, W.L.

    1982-02-01

    Results are presented of a study undertaken to determine the factors which are most effective in motivating different socio-economic groups to change their recycling behaviors and participate in recycling programs. Four types of data were collected and analyzed in Tucson: (1) purchase data from local recyclers, (2) traditional interview-survey data on recycling behavior, (3) long-term and short-term household refuse data, and (4) combined interview-garbage data. Findings reveal that disposal patterns for newspapers and aluminum cans are tuse data, and (4) combined interview-garbage data. Findings reveal that disposal patterns for newspapers and aluminum cans are the same across census tracts with significantly different socio-economic characteristics. Further, analysis of interview and garbage data matched by household reaffirm that what people say about recycling and how they dispose of recyclable materials are two different things. Thus, interview reports of newspaper recycling correlate with higher income informants, but their interview reports do not correlate with what is thrown into their garbage cans. Money is concluded to be the most powerful incentive toward recycling.

  5. http://nevadarecycles.gov/main/recyclables.htm

    National Nuclear Security Administration (NNSA)

    in Nevada National Recycling Web Resources Earth911.com provides a listing of recycling resources to help you find a way to reuse or recycle much of your solid waste items. ...

  6. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, D.; Sunder, S.

    1986-12-02

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  7. Catalytic conversion of LPG

    SciTech Connect (OSTI)

    Pujado, P.R.; Vora, B.V.; Mowry, J.R.; Anderson, R.F.

    1986-01-01

    The low reactivity of light paraffins has long hindered their utilization as petrochemical feedstocks. Except for their use in ethylene crackers, LPG fractions have traditionally been consumed as fuel. New catalytic processes now being commercialized open new avenues for the utilization of LPG as sources of valuable petrochemical intermediates. This paper discusses processes for the dehydrogenation and aromatization of LPG.

  8. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

    1986-01-01

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

  9. Is recycling worth the trouble

    SciTech Connect (OSTI)

    Boltz, C.M.

    1995-03-01

    A panel of waste industry experts met recently at a Washington, DC, conference to discuss and debate the costs, benefits, and economics of recycling solid waste. The nearly unanimous conclusion from some of the speakers--that recycling, as it is implemented today, has costs that far outweigh its benefits--is evidence of a growing backlash among solid waste officials against a recycling movement they feel has been grossly over-inflated by environmental groups as a solution to a non-existent problem known as the garbage crisis. The public should not place such a strong emphasis on recycling as a cure-all for environmental problems, according to the panel of four waste management policy analysts at The State of Garbage'' session held in mid-January at the 1995 US/Canadian Federation Solid Waste Management Conference. Moreover, some panel members said, recycling should take place only if it makes economic sense.

  10. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  11. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  12. rare earth recycling | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rare earth recycling Meet CMI Researcher David Reed CMI researcher David Reed is the principal investigator for the CMI project bioleaching for recovery of recycled rare earth...

  13. Xcel Energy - Appliance Recycling Rebate Program | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Program Rebate Amount 40appliance Summary The Appliance Recycling Program offers free pick up and recycling of old, inefficient, working refrigerators and freezers....

  14. LANL exceeds Early Recovery Act recycling goals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANL exceeds Early Recovery Act recycling goals LANL exceeds Early Recovery Act recycling goals Lab demolition projects under the American Recovery and Reinvestment Act have...

  15. Future Bottlenecks for Industrial Water Recycling. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Future Bottlenecks for Industrial Water Recycling. Citation Details In-Document Search Title: Future Bottlenecks for Industrial Water Recycling. Authors: Brady, Patrick V....

  16. A Photosynthetic Hydrogel for Catalytic Hydrogen Production ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production...

  17. Sustained Recycle in Light Water and Sodium-Cooled Reactors

    SciTech Connect (OSTI)

    Steven J. Piet; Samuel E. Bays; Michael A. Pope; Gilles J. Youinou

    2010-11-01

    From a physics standpoint, it is feasible to sustain recycle of used fuel in either thermal or fast reactors. This paper examines multi-recycle potential performance by considering three recycling approaches and calculating several fuel cycle parameters, including heat, gamma, and neutron emission of fresh fuel; radiotoxicity of waste; and uranium utilization. The first recycle approach is homogeneous mixed oxide (MOX) fuel assemblies in a light water reactor (LWR). The transuranic portion of the MOX was varied among Pu, NpPu, NpPuAm, or all-TRU. (All-TRU means all isotopes through Cf-252.) The Pu case was allowed to go to 10% Pu in fresh fuel, but when the minor actinides were included, the transuranic enrichment was kept below 8% to satisfy the expected void reactivity constraint. The uranium portion of the MOX was enriched uranium. That enrichment was increased (to as much as 6.5%) to keep the fuel critical for a typical LWR irradiation. The second approach uses heterogeneous inert matrix fuel (IMF) assemblies in an LWR - a mix of IMF and traditional UOX pins. The uranium-free IMF fuel pins were Pu, NpPu, NpPuAm, or all-TRU. The UOX pins were limited to 4.95% U-235 enrichment. The number of IMF pins was set so that the amount of TRU in discharged fuel from recycle N (from both IMF and UOX pins) was made into the new IMF pins for recycle N+1. Up to 60 of the 264 pins in a fuel assembly were IMF. The assembly-average TRU content was 1-6%. The third approach uses fast reactor oxide fuel in a sodium-cooled fast reactor with transuranic conversion ratio of 0.50 and 1.00. The transuranic conversion ratio is the production of transuranics divided by destruction of transuranics. The FR at CR=0.50 is similar to the CR for the MOX case. The fast reactor cases had a transuranic content of 33-38%, higher than IMF or MOX.

  18. Coal liquefaction with preasphaltene recycle

    DOE Patents [OSTI]

    Weimer, Robert F.; Miller, Robert N.

    1986-01-01

    A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

  19. Concentric catalytic combustor

    DOE Patents [OSTI]

    Bruck, Gerald J.; Laster, Walter R.

    2009-03-24

    A catalytic combustor (28) includes a tubular pressure boundary element (90) having a longitudinal flow axis (e.g., 56) separating a first portion (94) of a first fluid flow (e.g., 24) from a second portion (95) of the first fluid flow. The pressure boundary element includes a wall (96) having a plurality of separate longitudinally oriented flow paths (98) annularly disposed within the wall and conducting respective portions (100, 101) of a second fluid flow (e.g., 26) therethrough. A catalytic material (32) is disposed on a surface (e.g., 102, 103) of the pressure boundary element exposed to at least one of the first and second portions of the first fluid flow.

  20. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A.; Campbell, Christian X.; Subramanian, Ramesh

    2009-06-02

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  1. Catalytic nanoporous membranes

    DOE Patents [OSTI]

    Pellin, Michael J.; Hryn, John N.; Elam, Jeffrey W.

    2009-12-01

    A nanoporous catalytic membrane which displays several unique features including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity.

  2. Progress reported in PET recycling

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    The Goodyear Polyester Division has demonstrated its ability to break down polyethylene terephthalate (PET) from recycled plastic soft drink bottles and remanufacture the material into PET suitable for containers. Most people are familiar with PET in the form of lightweight, shatter resistant beverage bottles. About 20 percent of these beverage containers currently are being recycled. The recycled PET is currently used in many applications such as carpeting, pillow stuffing, sleeping bag filling, insulation for water heaters and non-food containers. This is the first step of Goodyear's increased efforts to recycle PET from containers into a material suitable for food packing. The project is extremely complex, involving sophisticated understanding of the chemical reactions involved, PET production and the technology testing protocols necessary to design a process that addresses all the technical, safety, and regulatory concerns. The research conducted so far indicated that additional processing beyond simply cleaning the shredded material, called flake, will be required to assure a quality polymer.

  3. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F-fly ash. Some developed technologies have similar potential in the longer term. (3) Laboratory studies have been completed that indicate that much higher amounts of fly ash could be added in cement-concrete applications under some circumstances. This could significantly increase use of fly ash in cement-concrete applications. (4) A study of the long-term environmental effects of structural fills in a surface mine in Indiana was completed. This study has provided much sought after data for permitting large-volume management options in both beneficial as well as non-beneficial use settings. (5) The impact of CBRC on CCBs utilization trends is difficult to quantify. However it is fair to say that the CBRC program had a significant positive impact on increased utilization of CCBs in every region of the USA. Today, the overall utilization of CCBs is over 43%. (6) CBRC-developed knowledge base led to a large number of other projects completed with support from other sources of funding. (7) CBRC research has also had a large impact on CCBs management across the globe. Information transfer activities and visitors from leading coal producing countries such as South Africa, Australia, England, India, China, Poland, Czech Republic and Japan are truly noteworthy. (8) Overall, the CBRC has been a truly successful, cooperative research program. It has brought together researchers, industry, government, and regulators to deal with a major problem facing the USA and other coal producing countries in the world.

  4. Catalytic two-stage coal hydrogenation and hydroconversion process

    DOE Patents [OSTI]

    MacArthur, James B.; McLean, Joseph B.; Comolli, Alfred G.

    1989-01-01

    A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F. temperature for further hydrogenation and thermal hydroconversion reactions. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, which results in significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of undesirable residuum and unconverted coal and hydrocarbon gases, with use of less energy to obtain the low molecular weight products, while catalyst life is substantially increased.

  5. Catalytic reforming methods

    DOE Patents [OSTI]

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  6. Novel Catalytic Membrane Reactors

    SciTech Connect (OSTI)

    Stuart Nemser, PhD

    2010-10-01

    There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

  7. What can recycling in thermal reactors accomplish?

    SciTech Connect (OSTI)

    Piet, Steven J.; Matthern, Gretchen E.; Jacobson, Jacob J.

    2007-07-01

    Thermal recycle provides several potential benefits when used as stop-gap, mixed, or backup recycling to recycling in fast reactors. These three roles involve a mixture of thermal and fast recycling; fast reactors are required to some degree at some time. Stop-gap uses thermal reactors only until fast reactors are adequately deployed and until any thermal-recycle-only facilities have met their economic lifetime. Mixed uses thermal and fast reactors symbiotically for an extended period of time. Backup uses thermal reactors only if problems later develop in the fast reactor portion of a recycling system. Thermal recycle can also provide benefits when used as pure thermal recycling, with no intention to use fast reactors. However, long term, the pure thermal recycling approach is inadequate to meet several objectives. (authors)

  8. A Ceramic membrane to Recycle Caustic | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Ceramic membrane to Recycle Caustic A Ceramic membrane to Recycle Caustic PDF icon A Ceramic membrane to Recycle Caustic More Documents & Publications Caustic Recovery Technology ...

  9. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J.; Daniels, Edward J.; Bonsignore, Patrick V.

    2001-01-01

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  10. Recycling of used perfluorosulfonic acid membranes

    DOE Patents [OSTI]

    Grot, Stephen; Grot, Walther

    2007-08-14

    A method for recovering and recycling catalyst coated fuel cell membranes includes dissolving the used membranes in water and solvent, heating the dissolved membranes under pressure and separating the components. Active membranes are produced from the recycled materials.

  11. Howard Waste Recycling Ltd | Open Energy Information

    Open Energy Info (EERE)

    Waste Recycling Ltd Jump to: navigation, search Name: Howard Waste Recycling Ltd Place: London, England, United Kingdom Zip: N18 3PU Sector: Biomass Product: London-based project...

  12. Think Again! A Fresh Look at Home Performance Business Models...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Think Again A Fresh Look at Home Performance Business Models and Service Offerings (301) Think Again A Fresh Look at Home Performance Business Models and Service Offerings (301) ...

  13. Catalytic Solutions Inc CSI | Open Energy Information

    Open Energy Info (EERE)

    Place: Oxnard, California Zip: 93033 Product: Developer of the breakthrough catalytic coating technology and the Mixed Phase Catalyst (MPCTM), and also manufacturer of catalytic...

  14. Degradation Mechanisms of Urea Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Degradation Mechanisms of Urea Selective Catalytic Reduction Technology Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials

  15. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants...

  16. Ames Lab 101: Rare-Earth Recycling

    ScienceCinema (OSTI)

    Ryan Ott

    2013-06-05

    Recycling keeps paper, plastics, and even jeans out of landfills. Could recycling rare-earth magnets do the same? Perhaps, if the recycling process can be improved. Scientists at the U.S. Department of Energy's Ames Laboratory are working to more effectively remove the neodymium, a rare earth, from the mix of other materials in a magnet.

  17. Improving Reuse & Recycling | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improving Reuse & Recycling series of images of recycling: trash heap, light bulbs, circuit boards diagram for focus area three, improving reuse and recycling (A click on the org chart image will lead to a pdf version that includes hotlinks for the e-mail addresses of the leaders.)

  18. Stabilization of gene expression and cell morphology after explant recycling during fin explant culture in goldfish

    SciTech Connect (OSTI)

    Chenais, Nathalie; Lareyre, Jean-Jacques; Le Bail, Pierre-Yves; Labbe, Catherine

    2015-07-01

    The development of fin primary cell cultures for in vitro cellular and physiological studies is hampered by slow cell outgrowth, low proliferation rate, poor viability, and sparse cell characterization. Here, we investigated whether the recycling of fresh explants after a first conventional culture could improve physiological stability and sustainability of the culture. The recycled explants were able to give a supplementary cell culture showing faster outgrowth, cleaner cell layers and higher net cell production. The cells exhibited a highly stabilized profile for marker gene expression including a low cytokeratin 49 (epithelial marker) and a high collagen 1a1 (mesenchymal marker) expression. Added to the cell spindle-shaped morphology, motility behavior, and actin organization, this suggests that the cells bore stable mesenchymal characteristics. This contrast with the time-evolving expression pattern observed in the control fresh explants during the first 2 weeks of culture: a sharp decrease in cytokeratin 49 expression was concomitant with a gradual increase in col1a1. We surmise that such loss of epithelial features for the benefit of mesenchymal ones was triggered by an epithelial to mesenchymal transition (EMT) process or by way of a progressive population replacement process. Overall, our findings provide a comprehensive characterization of this new primary culture model bearing mesenchymal features and whose stability over culture time makes those cells good candidates for cell reprogramming prior to nuclear transfer, in a context of fish genome preservation. - Highlights: • Recycled fin explants outgrow cells bearing stable mesenchymal traits. • Cell production and quality is enhanced in the recycled explant culture system. • Fresh fin primary culture is highly variable and loose epithelial traits over time.

  19. Vanadium recycling for fusion reactors

    SciTech Connect (OSTI)

    Dolan, T.J.; Butterworth, G.J.

    1994-04-01

    Very stringent purity specifications must be applied to low activation vanadium alloys, in order to meet recycling goals requiring low residual dose rates after 50--100 years. Methods of vanadium production and purification which might meet these limits are described. Following a suitable cooling period after their use, the vanadium alloy components can be melted in a controlled atmosphere to remove volatile radioisotopes. The aim of the melting and decontamination process will be the achievement of dose rates low enough for ``hands-on`` refabrication of new reactor components from the reclaimed metal. The processes required to permit hands-on recycling appear to be technically feasible, and demonstration experiments are recommended. Background information relevant to the use of vanadium alloys in fusion reactors, including health hazards, resources, and economics, is provided.

  20. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

    DOE Patents [OSTI]

    Comolli, Alfred G.; Lee, Lap-Keung

    2001-01-01

    A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

  1. INEEL Lead Recycling in a Moratorium Environment

    SciTech Connect (OSTI)

    Kooda, K. E.; Galloway, K.; McCray, C. W.; Aitken, D. W.

    2003-02-26

    Since 1999, the Idaho National Engineering and Environmental Laboratory (INEEL) Lead Project successfully recycled over 700,000 pounds of excess INEEL lead to the private sector. On February 14, 2000, the Secretary of Energy, Bill Richardson, formalized the January 12, 2000, moratorium on recycling radioactive scrap metal that prevented the unrestricted release of recycled scrap metals to the private sector. This moratorium created significant problems for the INEEL lead recycling program and associated plans; however, through the cooperative efforts of the INEEL and Idaho State University as well as innovative planning and creative thinking the recycling issues were resolved. This collaboration has recycled over 160,000 pounds of excess lead to Idaho State University with a cost savings of over $.5M.

  2. INEEL Lead Recycling in a Moratorium Environment

    SciTech Connect (OSTI)

    Kooda, Kevin Evan; Mc Cray, Casey William; Aitken, Darren William; Galloway, Kelly

    2003-02-01

    Since 1999, the Idaho National Engineering and Environmental Laboratory (INEEL) Lead Project successfully recycled over 700,000 pounds of excess INEEL lead to the private sector. On February 14, 2000, the Secretary of Energy, Bill Richardson, formalized the January 12, 2000, moratorium on recycling radioactive scrap metal that prevented the unrestricted release of recycled scrap metals to the private sector. This moratorium created significant problems for the INEEL lead recycling program and associated plans; however, through the cooperative efforts of the INEEL and Idaho State University as well as innovative planning and creative thinking the recycling issues were resolved. This collaboration has recycled over 160,000 pounds of excess lead to Idaho State University with a cost savings of over $.5M.

  3. Recommendation 221: Recommendation Regarding Recycling of Metals...

    Office of Environmental Management (EM)

    recycling program to address radiologically contaminated metals and equipment for free-release. PDF icon Recommendation 221 PDF icon Responseto221.pdf More Documents &...

  4. Major Nutrient Recycling for Sustained Algal Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... * Conversion of cellular nitrogen by protein fermentation * Return of recycled ... milestones and generates all reports * Synthesis of results into publication and ...

  5. Request for Information on Photovoltaic Module Recycling

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy SunShot Initiative requests feedback from industry, academia, research laboratories, government agencies, and other stakeholders on issues related to photovoltaic (PV) module recycling technology. SunShot intends to understand the current state of recycling technology and the areas of research that could lead to impactful recycling technologies to support the developing PV industry. The intent of this request for information is to generate discussion related to planning for the end of life of photovoltaic modules and to create a list of high impact research topics in photovoltaics recycling.

  6. More Recycling Means Less Waste for Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recycling Means Less Waste for Complex What do batteries, lead bricks, and mineral oil have in common? They are all on the list of recently recycled materials at the Nevada National Security Site (NNSS). The goal of these recycling efforts is to minimize waste volumes at the site and encourage the repurposing of materials across the U.S. Department of Energy (DOE) Complex. In September 2011, a total of 33,000 pounds of lead was shipped from the NNSS to the recycling company, Toxco Inc. A portion

  7. Recycled Energy Development | Open Energy Information

    Open Energy Info (EERE)

    search Name: Recycled Energy Development Place: Westmont, Illinois Zip: 60559 Product: RED acquires industrial utility plants and then builds and installs waste energy capture...

  8. Energy return on investment of used nuclear fuel recycling

    Energy Science and Technology Software Center (OSTI)

    2011-08-31

    N-EROI calculates energy return on investment (EROI) for recycling of used nublear fuel in four scenarios: one-pass recycle in light water reactors; two-pass recycle in light water reactors; mulit-pass recycle in burner fast reactora; one-pass recycle in breeder fast reactors.

  9. Integrated Recycling Test Fuel Fabrication

    SciTech Connect (OSTI)

    R.S. Fielding; K.H. Kim; B. Grover; J. Smith; J. King; K. Wendt; D. Chapman; L. Zirker

    2013-03-01

    The Integrated Recycling Test is a collaborative irradiation test that will electrochemically recycle used light water reactor fuel into metallic fuel feedstock. The feedstock will be fabricated into a metallic fast reactor type fuel that will be irradiation tested in a drop in capsule test in the Advanced Test Reactor on the Idaho National Laboratory site. This paper will summarize the fuel fabrication activities and design efforts. Casting development will include developing a casting process and system. The closure welding system will be based on the gas tungsten arc burst welding process. The settler/bonder system has been designed to be a simple system which provides heating and controllable impact energy to ensure wetting between the fuel and cladding. The final major pieces of equipment to be designed are the weld and sodium bond inspection system. Both x-radiography and ultrasonic inspection techniques have been examine experimentally and found to be feasible, however the final remote system has not been designed. Conceptual designs for radiography and an ultrasonic system have been made.

  10. FreshTracks Capital LP | Open Energy Information

    Open Energy Info (EERE)

    FreshTracks Capital LP Jump to: navigation, search Name: FreshTracks Capital LP Address: 29 Harbor Road, Suite 200 Place: Shelburne, New Hampshire Zip: 05482 Product: Venture...

  11. Argonne National Laboratory's Recycling Pilot Plant

    ScienceCinema (OSTI)

    Spangenberger, Jeff; Jody, Sam;

    2013-04-19

    Argonne has a Recycling Pilot Plant designed to save the non-metal portions of junked cars. Here, program managers demonstrate how plastic shredder residue can be recycled. (Currently these automotive leftovers are sent to landfills.) For more information, visit Argonne's Transportation Technology R&D Center Web site at http://www.transportation.anl.gov.

  12. Argonne National Laboratory's Recycling Pilot Plant

    SciTech Connect (OSTI)

    Spangenberger, Jeff; Jody, Sam;

    2009-01-01

    Argonne has a Recycling Pilot Plant designed to save the non-metal portions of junked cars. Here, program managers demonstrate how plastic shredder residue can be recycled. (Currently these automotive leftovers are sent to landfills.) For more information, visit Argonne's Transportation Technology R&D Center Web site at http://www.transportation.anl.gov.

  13. Molecular catalytic hydrogenation of aromatic hydrocarbons and...

    Office of Scientific and Technical Information (OSTI)

    catalysts for the hydrogenation of monocyclic aromatic hydrocarbons under mild conditions. ... NAPHTHALENE; CHRYSENE; ORGANOMETALLIC COMPOUNDS; CATALYTIC EFFECTS; RHODIUM COMPOUNDS; ...

  14. Solid waste recycling programs at Rocky Flats

    SciTech Connect (OSTI)

    Millette, R.L.; Blackman, T.E.; Shepard, M.D.

    1994-12-31

    The Rocky Flats (RFP) recycling programs for solid waste materials have been in place for over ten years. Within the last three years, the programs were centralized under the direction of the Rocky Flats Waste Minimization department, with the assistance of various plant organizations (e.g., Trucking, Building Services, Regulated Waste Operations, property Utilization and Disposal and Security). Waste Minimization designs collection and transportation systems for recyclable materials and evaluates recycling markets for opportunities to add new commodities to the existing programs. The Waste Minimization department also promotes employee participation in the Rocky Flats Recycling Programs, and collects all recycling data for publication. A description of the program status as of January 1994 is given.

  15. Preconceptual Design Description for Caustic Recycle Facility

    SciTech Connect (OSTI)

    Sevigny, Gary J.; Poloski, Adam P.; Fountain, Matthew S.; Kurath, Dean E.

    2008-04-12

    The U.S. Department of Energy plans to vitrify both high-level and low-activity waste at the Hanford Site in southeastern Washington State. One aspect of the planning includes a need for a caustic recycle process to separate sodium hydroxide for recycle. Sodium is already a major limitation to the waste-oxide loading in the low-activity waste glass to be vitrified at the Waste Treatment Plant, and additional sodium hydroxide will be added to remove aluminum and to control precipitation in the process equipment. Aluminum is being removed from the high level sludge to reduce the number of high level waste canisters produced. A sodium recycle process would reduce the volume of low-activity waste glass produced and minimize the need to purchase new sodium hydroxide, so there is a renewed interest in investigating sodium recycle. This document describes an electrochemical facility for recycling sodium for the WTP.

  16. Issues in recycling galvanized scrap

    SciTech Connect (OSTI)

    Koros, P.J.; Hellickson, D.A.; Dudek, F.J.

    1995-02-10

    The quality of the steel used for most galvanizing (and tinplate) applications makes scrap derived from their production and use a premier solid charge material for steelmaking. In 1989 the AISI created a Task Force to define the issues and to recommend technologically and economically sound approaches to assure continued, unhindered recyclability of the growing volume of galvanized scrap. The AISI program addressed the treatment of full-sized industrial bales of scrap. The current, on-going MRI (US)--Argonne National Laboratory program is focused on ``loose`` scrap from industrial and post-consumer sources. Results from these programs, issues of scrap management from source to steel melting, the choices for handling zinc in iron and steelmaking and the benefits/costs for removal of zinc (and lead) from scrap prior to melting in BOF and foundry operations are reviewed in this paper.

  17. Heterogeneous Recycling in Fast Reactors

    SciTech Connect (OSTI)

    Forget, Benoit; Pope, Michael; Piet, Steven J.; Driscoll, Michael

    2012-07-30

    Current sodium fast reactor (SFR) designs have avoided the use of depleted uranium blankets over concerns of creating weapons grade plutonium. While reducing proliferation risks, this restrains the reactor design space considerably. This project will analyze various blanket and transmutation target configurations that could broaden the design space while still addressing the non-proliferation issues. The blanket designs will be assessed based on the transmutation efficiency of key minor actinide (MA) isotopes and also on mitigation of associated proliferation risks. This study will also evaluate SFR core performance under different scenarios in which depleted uranium blankets are modified to include minor actinides with or without moderators (e.g. BeO, MgO, B4C, and hydrides). This will be done in an effort to increase the sustainability of the reactor and increase its power density while still offering a proliferation resistant design with the capability of burning MA waste produced from light water reactors (LWRs). Researchers will also analyze the use of recycled (as opposed to depleted) uranium in the blankets. The various designs will compare MA transmutation efficiency, plutonium breeding characteristics, proliferation risk, shutdown margins and reactivity coefficients with a current reference sodium fast reactor design employing homogeneous recycling. The team will also evaluate the out-of-core accumulation and/or burn-down rates of MAs and plutonium isotopes on a cycle-by-cycle basis. This cycle-by-cycle information will be produced in a format readily usable by the fuel cycle systems analysis code, VISION, for assessment of the sustainability of the deployment scenarios.

  18. FY 2009 Progress Report for Lightweighting Materials - 11. Recycling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1. Recycling FY 2009 Progress Report for Lightweighting Materials - 11. Recycling The primary Lightweight Materials activity goal is to validate a cost-effective weight reduction ...

  19. Massive Hanford Test Reactor Removed - Plutonium Recycle Test...

    Office of Environmental Management (EM)

    Massive Hanford Test Reactor Removed - Plutonium Recycle Test Reactor removed from Hanford's 300 Area Massive Hanford Test Reactor Removed - Plutonium Recycle Test Reactor removed ...

  20. Conversion Process for Aqueous Based Reprocessing and Recycling...

    Office of Scientific and Technical Information (OSTI)

    Based Reprocessing and Recycling: Denitration Citation Details In-Document Search Title: Conversion Process for Aqueous Based Reprocessing and Recycling: Denitration Authors: ...

  1. A High-Performance Recycling Solution for PolystyreneAchieved...

    Office of Scientific and Technical Information (OSTI)

    A High-Performance Recycling Solution for PolystyreneAchieved by the Synthesis of ... Citation Details In-Document Search Title: A High-Performance Recycling Solution for ...

  2. Sandia Algae Researchers Cut Costs with Improved Nutrient Recycling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sandia Algae Researchers Cut Costs with Improved Nutrient Recycling Sandia Algae Researchers Cut Costs with Improved Nutrient Recycling October 5, 2015 - 12:16pm Addthis Ryan Davis ...

  3. China Recycling Energy Corp CREG | Open Energy Information

    Open Energy Info (EERE)

    Recycling Energy Corp CREG Jump to: navigation, search Name: China Recycling Energy Corp (CREG) Place: Reno, Nevada Zip: 89511 Product: A US-incorporated company that develops...

  4. CMI Webinar: Recycling of Rare Earth Elements: A Microbiological...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recycling of Rare Earth Elements: A Microbiological Approach The CMI Webinar series includes a presentation CMI Webinar: Recycling of Rare Earth Elements: A Microbiological...

  5. Tribune carries magnet recycling story | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tribune carries magnet recycling story Ames Tribune staff writer Julie Ferrell talked recently with Ames Laboratory researcher Ikenna Nlebedim about his work in recycling...

  6. Bioflame Mid UK Recycling JV | Open Energy Information

    Open Energy Info (EERE)

    search Name: Bioflame & Mid-UK Recycling JV Place: England, United Kingdom Product: Joint Venture between Bioflame and Mid-UK Recycling References: Bioflame & Mid-UK...

  7. Can Automotive Battery Recycling Help Meet Lithium Demand? |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Can Automotive Battery Recycling Help Meet Lithium Demand? Title Can Automotive Battery Recycling Help Meet Lithium Demand? Publication Type Presentation Year of Publication 2013...

  8. The Future of Automobile Battery Recycling | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Future of Automobile Battery Recycling Title The Future of Automobile Battery Recycling Publication Type Presentation Year of Publication 2014 Authors Gaines, LL Abstract...

  9. Enabling Future Li-Ion Battery Recycling | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Future Li-Ion Battery Recycling Title Enabling Future Li-Ion Battery Recycling Publication Type Presentation Year of Publication 2014 Authors Gaines, LL Abstract Presentation made...

  10. FUEL CYCLE ISOTOPE EVOLUTION BY TRANSMUTATION DYNAMICS OVER MULTIPLE RECYCLES

    SciTech Connect (OSTI)

    Samuel Bays; Steven Piet; Amaury Dumontier

    2010-06-01

    Because all actinides have the ability to fission appreciably in a fast neutron spectrum, these types of reactor systems are usually not associated with the buildup of higher mass actinides: curium, berkelium and californium. These higher actinides have high specific decay heat power, gamma and neutron source strengths, and are usually considered as a complication to the fuel manufacturing and transportation of fresh recycled transuranic fuel. This buildup issue has been studied widely for thermal reactor fuels. However, recent studies have shown that the transmutation physics associated with "gateway isotopes" dictates Cm-Bk-Cf buildup, even in fast burner reactors. Assuming a symbiotic fuel relationship with light water reactors (LWR), Pu-242 and Am-243 are formed in the LWRs and then are externally fed to the fast reactor as part of its overall transuranic fuel supply. These isotopes are created much more readily in a thermal than in fast spectrum systems due to the differences in the fast fission (i.e., above the fission threshold for non-fissile actinides) contribution. In a strictly breeding fast reactor this dependency on LWR transuranics would not exist, and thus avoids the introduction of LWR derived gateway isotopes into the fast reactor system. However in a transuranic burning fast reactor, the external supply of these gateway isotopes behaves as an external driving force towards the creation and build-up of Cm-Bk-Cf in the fuel cycle. It was found that though the Cm-Bk-Cf concentration in the equilibrium fuel cycle is dictated by the fast neutron spectrum, the time required to reach that equilibrium concentration is dictated by recycle, transmutation and decay storage dynamics.

  11. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reactors provide a highly recyclable, scalable, and efficient setup that enhances the sustainability and performance of catalysts. However, the synthesis of pharmaceutical...

  12. Synthesis and characterization of NiFe{sub 2}O{sub 4}–Pd magnetically recyclable catalyst for hydrogenation reaction

    SciTech Connect (OSTI)

    Karao?lu, E.; Özel, U.; Caner, C.; Baykal, A.; Summak, M.M.; Sözeri, H.

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? Novel superparamagnetic NiFe{sub 2}O{sub 4}–Pd magnetically recyclable catalyst was fabricated through co-precipitation. ? It could be reused several times without significant loss in catalytic activity for hydrogenation reaction. ? No further modification of the NiFe{sub 2}O{sub 4}–Pd magnetically recyclable catalyst is necessary for utilization as catalyst. -- Abstract: Herein we report the fabrication and characterization magnetically recyclable catalysts of NiFe{sub 2}O{sub 4}–Pd nanocomposite as highly effective catalysts for reduction reactions in liquid phase. The reduction Pd{sup 2+} was accomplished with polyethylene glycol 400 (PEG-400) instead of sodium borohydride (NaBH{sub 4}) and NiFe{sub 2}O{sub 4} nanoparticles was prepared by sonochemically using FeCI{sub 3}·6H{sub 2}O and NiCl{sub 2}. The chemical characterization of the product was done with X-ray diffractometry, Infrared spectroscopy, transmission electron microscopy, UV–Vis spectroscopy, thermal gravimetry and inductively coupled plasma. Thus formed NiFe{sub 2}O{sub 4}–Pd MRCs showed a very high activity in reduction reactions of 4-nitro aniline and 1,3-dinitrobenzene in liquid phase. It was found out that the catalytic activity of NiFe{sub 2}O{sub 4}–Pd MRCs on the reduction of 4-nitro aniline and 1,3-dinitrobenzene in liquid phase are between 99–93% and 98–93%, respectively. Magnetic character of this system allowed recovery and multiple use without significant loss of its catalytic activity. It is found that NiFe{sub 2}O{sub 4}–Pd MRCs showed very efficient catalytic activity and multiple usability.

  13. Waste tire recycling by pyrolysis

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    This project examines the City of New Orleans' waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans' waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city's limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city's waste tire problem. Pending state legislation could improve the city's ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

  14. Loveland Water & Power- Refrigerator Recycling Program

    Broader source: Energy.gov [DOE]

    Loveland Water & Power is providing an incentive for customers to recycle older, working refrigerators. Interested customers can call the utility to arrange a time to pick up the old...

  15. Evaluation of radioactive scrap metal recycling

    SciTech Connect (OSTI)

    Nieves, L.A.; Chen, S.Y.; Kohout, E.J.; Nabelssi, B.; Tilbrook, R.W.; Wilson, S.E.

    1995-12-01

    This report evaluates the human health risks and environmental and socio-political impacts of options for recycling radioactive scrap metal (RSM) or disposing of and replacing it. Argonne National Laboratory (ANL) is assisting the US Department of Energy (DOE), Office of Environmental Restoration and Waste Management, Oak Ridge Programs Division, in assessing the implications of RSM management alternatives. This study is intended to support the DOE contribution to a study of metal recycling being conducted by the Task Group on Recycling and Reuse of the Organization for Economic Cooperation and Development. The focus is on evaluating the justification for the practice of recycling RSM, and the case of iron and steel scrap is used as an example in assessing the impacts. To conduct the evaluation, a considerable set of data was compiled and developed. Much of this information is included in this document to provide a source book of information.

  16. BWR Assembly Optimization for Minor Actinide Recycling

    SciTech Connect (OSTI)

    G. Ivan Maldonado; John M. Christenson; J.P. Renier; T.F. Marcille; J. Casal

    2010-03-22

    The Primary objective of the proposed project is to apply and extend the latest advancements in LWR fuel management optimization to the design of advanced boiling water reactor (BWR) fuel assemblies specifically for the recycling of minor actinides (MAs).

  17. Design and Optimization of Photovoltaics Recycling Infrastructure

    SciTech Connect (OSTI)

    Choi, J.K.; Fthenakis, V.

    2010-10-01

    With the growing production and installation of photovoltaics (PV) around the world constrained by the limited availability of resources, end-of-life management of PV is becoming very important. A few major PV manufacturers currently are operating several PV recycling technologies at the process level. The management of the total recycling infrastructure, including reverse-logistics planning, is being started in Europe. In this paper, we overview the current status of photovoltaics recycling planning and discuss our mathematic modeling of the economic feasibility and the environmental viability of several PV recycling infrastructure scenarios in Germany; our findings suggest the optimum locations of the anticipated PV take-back centers. Short-term 5-10 year planning for PV manufacturing scraps is the focus of this article. Although we discuss the German situation, we expect the generic model will be applicable to any region, such as the whole of Europe and the United States.

  18. Renewable, Recycled and Conserved Energy Objective | Department...

    Broader source: Energy.gov (indexed) [DOE]

    an objective that 10% of all retail electricity sales in the state be obtained from renewable and recycled energy by 2015. In March 2009, this policy was modified by allowing...

  19. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Processing of Fresh Feed Input Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Catalytic Cracking The refining process of breaking down the larger, heavier, and more complex hydrocarbon molecules into simpler and lighter molecules. Catalytic cracking is accomplished by the use of a catalytic agent and is an effective process for increasing the yield of gasoline from crude oil. Catalytic cracking processes fresh feeds and recycled feeds. Catalytic Hydrocracking

  20. Economic Feasibility of Recycling Photovoltaic Modules

    SciTech Connect (OSTI)

    Choi, J.K.; Fthenakis, V.

    2010-12-01

    The market for photovoltaic (PV) electricity generation has boomed over the last decade, and its expansion is expected to continue with the development of new technologies. Taking into consideration the usage of valuable resources and the generation of emissions in the life cycle of photovoltaic technologies dictates proactive planning for a sound PV recycling infrastructure to ensure its sustainability. PV is expected to be a 'green' technology, and properly planning for recycling will offer the opportunity to make it a 'double-green' technology - that is, enhancing life cycle environmental quality. In addition, economic feasibility and a sufficient level of value-added opportunity must be ensured, to stimulate a recycling industry. In this article, we survey mathematical models of the infrastructure of recycling processes of other products and identify the challenges for setting up an efficient one for PV. Then we present an operational model for an actual recycling process of a thin-film PV technology. We found that for the case examined with our model, some of the scenarios indicate profitable recycling, whereas in other scenarios it is unprofitable. Scenario SC4, which represents the most favorable scenario by considering the lower bounds of all costs and the upper bound of all revenues, produces a monthly profit of $107,000, whereas the least favorable scenario incurs a monthly loss of $151,000. Our intent is to extend the model as a foundation for developing a framework for building a generalized model for current-PV and future-PV technologies.

  1. Catalytic membranes for fuel cells

    DOE Patents [OSTI]

    Liu, Di-Jia; Yang, Junbing; Wang, Xiaoping

    2011-04-19

    A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

  2. Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    for Solar Power Yellowstone Park Recycles Vehicle Batteries for Solar Power to someone by E-mail Share Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries for Solar Power on Facebook Tweet about Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries for Solar Power on Twitter Bookmark Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries for Solar Power on Google Bookmark Alternative Fuels Data Center: Yellowstone Park Recycles

  3. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Infrared Mapping Helps Optimize Catalytic Reactions Print Wednesday, 20 August 2014 07:59 A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ

  4. Waste tire recycling by pyrolysis

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    This project examines the City of New Orleans` waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans` waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city`s limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city`s waste tire problem. Pending state legislation could improve the city`s ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

  5. A Fresh Take on Groundwater at Amargosa Valley Open House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 25, 2012 A Fresh Take on Groundwater at Amargosa Valley Open House From drilling ... Interactive stations on Monitoring, Drilling, Sampling, Modeling, Protection and ...

  6. Plasma-assisted catalytic reduction system

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1998-01-27

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  7. Catalytic Device International LLC | Open Energy Information

    Open Energy Info (EERE)

    Pleasanton, California Product: California-based, firm focused on portable, heat-on-demand products. References: Catalytic Device International LLC1 This article is a stub....

  8. BioCatalytics | Open Energy Information

    Open Energy Info (EERE)

    Biomass Product: BioCatalytics Inc. provides a broadest range of enzymes for chemical synthesis, especially biomass to biofuel enzymes along with the resources and technology to...

  9. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems

  10. Plasma-assisted catalytic reduction system

    DOE Patents [OSTI]

    Vogtlin, George E.; Merritt, Bernard T.; Hsiao, Mark C.; Wallman, P. Henrik; Penetrante, Bernardino M.

    1998-01-01

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO.sub.x reduction in oxygen-rich vehicle engine exhausts.

  11. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 You are accessing...

  12. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 In this Quarter, the...

  13. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report In this Quarter, the research was focused continually on the two...

  14. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report You are accessing a document from the Department of...

  15. Molecular catalytic hydrogenation of aromatic hydrocarbons and

    Office of Scientific and Technical Information (OSTI)

    catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. 01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; COAL LIQUIDS;...

  16. Microchannel Reactor System for Catalytic Hydrogenation

    SciTech Connect (OSTI)

    2004-07-01

    Energy-Efficient Catalytic Hydrogenation Reactions. Hydrogenation reactions are very versatile and account for 10% to 20% of all reactions in the pharmaceutical industry.

  17. Catalytic oxidizers and Title V requirements

    SciTech Connect (OSTI)

    Uberoi, M.; Rach, S.E.

    1999-07-01

    Catalytic oxidizers have been used to reduce VOC emissions from various industries including printing, chemical, paint, coatings, etc. A catalytic oxidizer uses a catalyst to reduce the operating temperature for combustion to approximately 600 F, which is substantially lower than thermal oxidation unit. Title V requirements have renewed the debate on the best methods to assure compliance of catalytic oxidizers, with some suggesting the need for continuous emission monitoring equipment. This paper will discuss the various aspects of catalytic oxidation and consider options such as monitoring inlet/outlet temperatures, delta T across the catalyst, periodic laboratory testing of catalyst samples, and preventive maintenance procedures as means of assuring continuous compliance.

  18. U.S. Downstream Processing of Fresh Feed Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Catalytic Cracking 4,873 4,952 4,901 4,811 4,885 4,834 1987-2015 Catalytic Hydrocracking 1,422 1,467 1,529 1,670 1,663 1,700 1987-2015 Delayed and Fluid Coking 1,996 2,094 2,177 ...

  19. Plutonium Recycle Test Reactor 309 B-Roll | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plutonium Recycle Test Reactor 309 B-Roll Plutonium Recycle Test Reactor 309 B-Roll Addthis Description Plutonium Recycle Test Reactor 309 B-Roll

  20. Non-catalytic recuperative reformer

    DOE Patents [OSTI]

    Khinkis, Mark J.; Kozlov, Aleksandr P.; Kurek, Harry

    2015-12-22

    A non-catalytic recuperative reformer has a flue gas flow path for conducting hot flue gas from a thermal process and a reforming mixture flow path for conducting a reforming mixture. At least a portion of the reforming mixture flow path is embedded in the flue gas flow path to permit heat transfer from the hot flue gas to the reforming mixture. The reforming mixture flow path contains substantially no material commonly used as a catalyst for reforming hydrocarbon fuel (e.g., nickel oxide, platinum group elements or rhenium), but instead the reforming mixture is reformed into a higher calorific fuel via reactions due to the heat transfer and residence time. In a preferred embodiment, extended surfaces of metal material such as stainless steel or metal alloy that are high in nickel content are included within at least a portion of the reforming mixture flow path.

  1. APPARATUS FOR CATALYTICALLY COMBINING GASES

    DOE Patents [OSTI]

    Busey, H.M.

    1958-08-12

    A convection type recombiner is described for catalytically recombining hydrogen and oxygen which have been radiolytically decomposed in an aqueous homogeneous nuclear reactor. The device is so designed that the energy of recombination is used to circulate the gas mixture over the catalyst. The device consists of a vertical cylinder having baffles at its lower enda above these coarse screens having platinum and alumina pellets cemented thereon, and an annular passage for the return of recombined, condensed water to the reactor moderator system. This devicea having no moving parts, provides a simple and efficient means of removing the danger of accumulated hot radioactive, explosive gases, and restoring them to the moderator system for reuse.

  2. Catalytic reactor with improved burner

    DOE Patents [OSTI]

    Faitani, Joseph J.; Austin, George W.; Chase, Terry J.; Suljak, George T.; Misage, Robert J.

    1981-01-01

    To more uniformly distribute heat to the plurality of catalyst tubes in a catalytic reaction furnace, the burner disposed in the furnace above the tops of the tubes includes concentric primary and secondary annular fuel and air outlets. The fuel-air mixture from the primary outlet is directed towards the tubes adjacent the furnace wall, and the burning secondary fuel-air mixture is directed horizontally from the secondary outlet and a portion thereof is deflected downwardly by a slotted baffle toward the tubes in the center of the furnace while the remaining portion passes through the slotted baffle to another baffle disposed radially outwardly therefrom which deflects it downwardly in the vicinity of the tubes between those in the center and those near the wall of the furnace.

  3. Method of fabricating a catalytic structure

    DOE Patents [OSTI]

    Rollins, Harry W.; Petkovic, Lucia M.; Ginosar, Daniel M.

    2009-09-22

    A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.

  4. New developments in RTR fuel recycling

    SciTech Connect (OSTI)

    Lelievre, F.; Brueziere, J.; Domingo, X.; Valery, J.F.; Leroy, J.F.; Tribout-Maurizi, A.

    2013-07-01

    As most utilities in the world, Research and Test Reactors (RTR) operators are currently facing two challenges regarding the fuel, in order to comply with local safety and waste management requirements as well as global non-proliferation obligation: - How to manage used fuel today, and - How fuel design changes that are currently under development will influence used fuel management. AREVA-La-Hague plant has a large experience in used fuel recycling, including traditional RTR fuel (UAl). Based on that experience and deep knowledge of RTR fuel manufacturing, AREVA is currently examining possible options to cope with both challenges. This paper describes the current experience of AREVA-La-Hague in UAl used fuels recycling and its plan to propose recycling for various types of fuels such as U{sub 3}Si{sub 2} fuel or UMo fuel on an industrial scale. (authors)

  5. Scrap uranium recycling via electron beam melting

    SciTech Connect (OSTI)

    McKoon, R.

    1993-11-01

    A program is underway at the Lawrence Livermore National Laboratory (LLNL) to recycle scrap uranium metal. Currently, much of the material from forging and machining processes is considered radioactive waste and is disposed of by oxidation and encapsulation at significant cost. In the recycling process, uranium and uranium alloys in various forms will be processed by electron beam melting and continuously cast into ingots meeting applicable specifications for virgin material. Existing vacuum processing facilities at LLNL are in compliance with all current federal and state environmental, safety and health regulations for the electron beam melting and vaporization of uranium metal. One of these facilities has been retrofitted with an auxiliary electron beam gun system, water-cooled hearth, crucible and ingot puller to create an electron beam melt furnace. In this furnace, basic process R&D on uranium recycling will be performed with the goal of eventual transfer of this technology to a production facility.

  6. Characterization of DWPF recycle condensate materials

    SciTech Connect (OSTI)

    Bannochie, C. J.; Adamson, D. J.; King, W. D.

    2015-04-01

    A Defense Waste Processing Facility (DWPF) Recycle Condensate Tank (RCT) sample was delivered to the Savannah River National Laboratory (SRNL) for characterization with particular interest in the concentration of I-129, U-233, U-235, total U, and total Pu. Since a portion of Salt Batch 8 will contain DWPF recycle materials, the concentration of I-129 is important to understand for salt batch planning purposes. The chemical and physical characterizations are also needed as input to the interpretation of future work aimed at determining the propensity of the RCT material to foam, and methods to remediate any foaming potential. According to DWPF the Tank Farm 2H evaporator has experienced foaming while processing DWPF recycle materials. The characterization work on the RCT samples has been completed and is reported here.

  7. Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids

    SciTech Connect (OSTI)

    Oyama, Ted; Agblevor, Foster; Battaglia, Francine; Klein, Michael

    2013-01-18

    The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

  8. Enhanced Photon Recycling in Multijunction Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Recycling in Multijunction Solar Cells Work w as p erformed a t U IUC a nd B erkeley X. Sheng, M.H. Yun, C. Zhang, A.M. Al---Okaily, M. Masouraki, L. Shen, S. Wang, W.L. Wilson, J.Y. Kim, P. Ferreira, X. Li, E. Yablonovitch, a nd J .A. R ogers, " Device A rchitectures f or E nhanced Photon Recycling in Thin---Film MulQjuncQon Solar Cells." Adv. Energy M ater. (2014). DOI: 1 0.1002/aenm.201400919 Scientific Achievement We demonstrate improved mul1junc1on (MJ) solar cell

  9. Methanation process utilizing split cold gas recycle

    DOE Patents [OSTI]

    Tajbl, Daniel G.; Lee, Bernard S.; Schora, Jr., Frank C.; Lam, Henry W.

    1976-07-06

    In the methanation of feed gas comprising carbon monoxide and hydrogen in multiple stages, the feed gas, cold recycle gas and hot product gas is mixed in such proportions that the mixture is at a temperature sufficiently high to avoid carbonyl formation and to initiate the reaction and, so that upon complete reaction of the carbon monoxide and hydrogen, an excessive adiabatic temperature will not be reached. Catalyst damage by high or low temperatures is thereby avoided with a process that utilizes extraordinarily low recycle ratios and a minimum of investment in operating costs.

  10. The value of recycling on water conservation.

    SciTech Connect (OSTI)

    Ludi-Herrera, Katlyn D.

    2013-07-01

    Sandia National Laboratories (SNL) is working to conserve water through recycling. This report will focus on the water conservation that has been accumulated through the recycling of paper, ceiling tiles, compost, and plastic. It will be discussed the use of water in the process of manufacturing these materials and the amount of water that is used. The way that water is conserved will be reviewed. From the stand point of SNL it will be discussed the amount of material that has been accumulated from 2010 to the first two quarters of 2013 and how much water this material has saved.

  11. Nanoporous carbon catalytic membranes and method for making the same

    DOE Patents [OSTI]

    Foley, Henry C. (Hockessin, DE); Strano, Michael (Wilmington, DE); Acharya, Madhav (New Castle, DE); Raich, Brenda A. (Houston, TX)

    2002-01-01

    Catalytic membranes comprising highly-dispersed, catalytically-active metals in nanoporous carbon membranes and a novel single-phase process to produce the membranes.

  12. Improvement of catalytic activity in selective oxidation of styrene...

    Office of Scientific and Technical Information (OSTI)

    Improvement of catalytic activity in selective oxidation of styrene with Hsub 2Osub 2 ... Title: Improvement of catalytic activity in selective oxidation of styrene with Hsub ...

  13. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Office of Scientific and Technical Information (OSTI)

    Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway Citation Details In-Document Search Title: Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway This ...

  14. Comparison of Water-Hydrogen Catalytic Exchange Processes Versus...

    Office of Environmental Management (EM)

    Comparison of Water-Hydrogen Catalytic Exchange Processes Versus Water Distillation for Water Detritiation Comparison of Water-Hydrogen Catalytic Exchange Processes Versus Water ...

  15. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants 2005 Diesel Engine ...

  16. New Developments in Titania-Based Catalysts for Selective Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx New Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx Presentation ...

  17. Breakout Session: Getting in the Loop: PV Hardware Recycling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Getting in the Loop: PV Hardware Recycling and Sustainability Breakout Session: Getting in the Loop: PV Hardware Recycling and Sustainability May 21, 2014 6:30PM to 7:30PM PDT ...

  18. London Waste and Recycling Board | Open Energy Information

    Open Energy Info (EERE)

    Waste and Recycling Board Jump to: navigation, search Name: London Waste and Recycling Board Place: London, England, United Kingdom Zip: SE1 0AL Sector: Services Product: UK-based...

  19. REGULATIONS ON PHOTOVOLTAIC MODULE DISPOSAL AND RECYCLING.

    SciTech Connect (OSTI)

    FTHENAKIS,V.

    2001-01-29

    Environmental regulations can have a significant impact on product use, disposal, and recycling. This report summarizes the basic aspects of current federal, state and international regulations which apply to end-of-life photovoltaic (PV) modules and PV manufacturing scrap destined for disposal or recycling. It also discusses proposed regulations for electronics that may set the ground of what is to be expected in this area in the near future. In the US, several states have started programs to support the recycling of electronic equipment, and materials destined for recycling often are excepted from solid waste regulations during the collection, transfer, storage and processing stages. California regulations are described separately because they are different from those of most other states. International agreements on the movement of waste between different countries may pose barriers to cross-border shipments. Currently waste moves freely among country members of the Organization of Economic Cooperation and Development (OECD), and between the US and the four countries with which the US has bilateral agreements. However, it is expected, that the US will adopt the rules of the Basel Convention (an agreement which currently applies to 128 countries but not the US) and that the Convection's waste classification system will influence the current OECD waste-handling system. Some countries adopting the Basel Convention consider end-of-life electronics to be hazardous waste, whereas the OECD countries consider them to be non-hazardous. Also, waste management regulations potentially affecting electronics in Germany and Japan are mentioned in this report.

  20. Selective purge for hydrogenation reactor recycle loop

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.

    2001-01-01

    Processes and apparatus for providing improved contaminant removal and hydrogen recovery in hydrogenation reactors, particularly in refineries and petrochemical plants. The improved contaminant removal is achieved by selective purging, by passing gases in the hydrogenation reactor recycle loop or purge stream across membranes selective in favor of the contaminant over hydrogen.

  1. WINCO Metal Recycle annual report, FY 1993

    SciTech Connect (OSTI)

    Bechtold, T.E.

    1993-12-01

    This report is a summary of the first year progress of the WINCO Metal Recycle Program. Efforts were directed towards assessment of radioactive scrap metal inventories, economics and concepts for recycling, technology development, and transfer of technology to the private sector. Seven DOE laboratories worked together to develop a means for characterizing scrap metal. Radioactive scrap metal generation rates were established for several of these laboratories. Initial cost estimates indicate that recycle may be preferable over burial if sufficient decontamination factors can be achieved during melt refining. Radiation levels of resulting ingots must be minimized in order to keep fabrication costs low. Industry has much of the expertise and capability to execute the recycling of radioactive scrap metal. While no single company can sort, melt, refine, roll and fabricate, a combination of two to three can complete this operation. The one process which requires development is in melt refining for removal of radionuclides other than uranium. WINCO is developing this capability in conjunction with academia and industry. This work will continue into FY-94.

  2. Woody biomass production in waste recycling systems

    SciTech Connect (OSTI)

    Rockwood, D.L.; Snyder, G.H.; Sprinkle, R.R.

    1994-12-31

    Combining woody biomass production with waste recycling offers many mutual advantages, including increased tree growth and nutrient and water reclamation. Three biomass/recycling studies collectively involving Eucalyptus amplifolia, E. camaldulensis, and E. grandis, rapidly growing species potentially tolerant of high water and nutrient levels, are (1) evaluating general potential for water/nutrient recycling systems to enhance woody biomass production and to recycle water and nutrients, (2) documenting Eucalyptus growth, water use, and nutrient uptake patterns, and (3) identifying Eucalyptus superior for water and nutrient uptake in central and southern Florida. In a 1992-93 study assessing the three Eucalyptus species planted on the outside berms of sewage effluent holding ponds, position on the berms (top to bottom) and genotypes influenced tree size. The potential of the trees to reduce effluent levels in the ponds was assessed. In a stormwater holding pond planted in 1993, these Eucalyptus genotypes varied significantly for tree size but not for survival. E. camaldulensis appears generally superior when flooded with industrial stormwater. Potential sizes of ponds needed for different stormwater applications were estimated. Prolonged flooding of 4- and 5-year-old E. camaldulensis with agricultural irrigation runoff has had no observable effects on tree growth or survival. Younger E. camaldulensis, E. amplifolia, and E. grandis were assessed for water use and nutrient uptake during a Summer 1994 flooding.

  3. GNEP Element:Demonstrate More Proliferation-Resistant Recycling |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy GNEP Element:Demonstrate More Proliferation-Resistant Recycling GNEP Element:Demonstrate More Proliferation-Resistant Recycling An article describing GNEP element of recycling. PDF icon GNEP Element:Demonstrate More Proliferation-Resistant Recycling More Documents & Publications GNEP Element:Develop Enhanced Nuclear Safeguards Global Nuclear Energy Partnership Fact Sheet - Develop Enhanced Nuclear Safeguards Global Nuclear Energy Partnership Fact Sheet - Demonstrate

  4. Sandia National Laboratories: Due Diligence on Lead Acid Battery Recycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Due Diligence on Lead Acid Battery Recycling March 23, 2011 Lead Acid Batteries on secondary containment pallet Lead Acid Batteries on secondary containment pallet In 2004, the US Geological Survey estimated that 95% of lead in the United States is recycled, primarily from used lead acid batteries. A broader 2009 European study estimated that globally about 52% of lead is recycled, and a 2008 Asian study estimated a global recycle rate of 68%. Unfortunately, many incidents over the past decade

  5. Material Recycle and Recovery | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recycle and ... Material Recycle and Recovery Y-12 recycles and recovers enriched uranium from retired weapons and other excess or salvage materials, including some retired fuel elements and nuclear materials from other countries. This mission ensures that excess materials from Y-12 and other parts of the world are processed to a safer form for long-term storage or reuse. Recycled material is used for such things as feedstock for the Naval Reactors Program or for research reactors that produce

  6. Vacuum-insulated catalytic converter

    DOE Patents [OSTI]

    Benson, David K.

    2001-01-01

    A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

  7. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and optimization of the catalytic reaction. Research conducted by: E. Gross, X.-Z. Shu, S. Alayoglu, F.D. Toste, and G.A. Somorjai (Univ. of California, Berkeley), and H.A....

  8. Catalytic converter for automotive exhaust system

    SciTech Connect (OSTI)

    Merry, R.P.

    1986-10-14

    This patent describes a catalytic converter having a metallic casing, a unitary, solid ceramic catalytic element disposed within the casing, and resilient means disposed between the catalytic element and the metallic casing for positioning the catalytic element and for absorbing mechanical and thermal shock. The improvement described here comprises: the resilient means being a flexible intumescent planar sheet corrugated with a generally sinusoidal wave pattern along both its lengthwise edges. The corrugations are generally parallel and regular and are comprised of substantially equal ridges and hollows having a perimeter to frequency ratio in a range of 2.44 to 4.88 and amplitude in a range of 12 to 50% of the width of the sheet.

  9. Fresh Air That's as Good as Gold | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fresh Air That's as Good as Gold Fresh Air That's as Good as Gold July 8, 2013 - 5:25pm Addthis Brookhaven Lab physicists Peter Sutter, Eli Sutter,and Xiao Tong (left to right) with one of the Center for Functional Nanomaterials instruments used to characterize the new nanoparticle structures. | Photo courtesy of Brookhaven National Lab. Brookhaven Lab physicists Peter Sutter, Eli Sutter,and Xiao Tong (left to right) with one of the Center for Functional Nanomaterials instruments used to

  10. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  11. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  12. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  13. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  14. Innovative Catalytic Converter Wins National Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative Catalytic Converter Wins National Award For more information contact: e:mail: Public Affairs Golden, Colo., July 25, 1996—A new catalytic converter design that could dramatically reduce automobile emissions and urban air pollution has been named one of the years most important technological breakthroughs. Research and Development Magazine selected the converter—developed by the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) and Benteler Industries Inc. of

  15. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  16. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  17. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  18. Department of Chemistry | Center for Catalytic Hydrocarbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages

    Functionalization Department of Chemistry Faculty & Research Outreach Programs Graduate Studies Events & Seminars Undergraduate Studies Contact Us Faculty & Research > Research Centers & Programs > Center for Catalytic Hydrocarbon Functionalization CCHF Center for Catalytic Hydrocarbon Functionalization Catalysts are central to the efficient and clean utilization of energy resources, and they impact all aspects of the energy sector. With the University of Virginia as

  19. Catalytic Upgrading Sugars To Hydrocarbons | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sugars To Hydrocarbons Catalytic Upgrading Sugars To Hydrocarbons PDF on catalytic bioenergy process PDF icon Catalytic Upgrading Sugars To Hydrocarbons More Documents & Publications Biological Conversion of Sugars To Hydrocarbons Technology Pathway Selection Effort Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

  20. Model institutional infrastructures for recycling of photovoltaic modules

    SciTech Connect (OSTI)

    Reaven, S.J.; Moskowitz, P.D.; Fthenakis, V.

    1996-01-01

    How will photovoltaic modules (PVMS) be recycled at the end of their service lives? This question has technological and institutional components (Reaven, 1994a). The technological aspect concerns the physical means of recycling: what advantages and disadvantages of the several existing and emerging mechanical, thermal, and chemical recycling processes and facilities merit consideration? The institutional dimension refers to the arrangements for recycling: what are the operational and financial roles of the parties with an interest in PVM recycling? These parties include PVM manufacturers, trade organizations; distributors, and retailers; residential, commercial, and utility PVM users; waste collectors, transporters, reclaimers, and reclaimers; and governments.

  1. Heavy oil catalytic cracking apparatus (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Heavy oil catalytic cracking apparatus Citation Details In-Document Search Title: Heavy oil catalytic cracking apparatus This patent describes an apparatus for the fluidized catalytic cracking of a heavy hydrocarbon feed comprising hydrocarbons having a boiling point above about 650{degrees} F to lighter products by contact the feed with catalytic cracking catalyst. It comprises a catalytic cracking reactor means; a separation means connective with the reactor outlet; a primary stripping means

  2. Argonne explains nuclear recycling in 4 minutes

    SciTech Connect (OSTI)

    2012-01-01

    Currently, when using nuclear energy only about five percent of the uranium used in a fuel rod gets fissioned for energy; after that, the rods are taken out of the reactor and put into permanent storage. There is a way, however, to use almost all of the uranium in a fuel rod. Recycling used nuclear fuel could produce hundreds of years of energy from just the uranium we've already mined, all of it carbon-free. Problems with older technology put a halt to recycling used nuclear fuel in the United States, but new techniques developed by scientists at Argonne National Laboratory address many of those issues. For more information, visit http://www.anl.gov/energy/nuclear-energy.

  3. Probe for contamination detection in recyclable materials

    DOE Patents [OSTI]

    Taleyarkhan, Rusi

    2003-08-05

    A neutron detection system for detection of contaminants contained within a bulk material during recycling includes at least one neutron generator for neutron bombardment of the bulk material, and at least one gamma ray detector for detection of gamma rays emitted by contaminants within the bulk material. A structure for analyzing gamma ray data is communicably connected to the gamma ray detector, the structure for analyzing gamma ray data adapted. The identity and concentration of contaminants in a bulk material can also be determined. By scanning the neutron beam, discrete locations within the bulk material having contaminants can be identified. A method for recycling bulk material having unknown levels of contaminants includes the steps of providing at least one neutron generator, at least one gamma ray detector, and structure for analyzing gamma ray data, irradiating the bulk material with neutrons, and then determining the presence of at least one contaminant in the bulk material from gamma rays emitted from the bulk material.

  4. Argonne explains nuclear recycling in 4 minutes

    ScienceCinema (OSTI)

    None

    2013-04-19

    Currently, when using nuclear energy only about five percent of the uranium used in a fuel rod gets fissioned for energy; after that, the rods are taken out of the reactor and put into permanent storage. There is a way, however, to use almost all of the uranium in a fuel rod. Recycling used nuclear fuel could produce hundreds of years of energy from just the uranium we've already mined, all of it carbon-free. Problems with older technology put a halt to recycling used nuclear fuel in the United States, but new techniques developed by scientists at Argonne National Laboratory address many of those issues. For more information, visit http://www.anl.gov/energy/nuclear-energy.

  5. Ferrite insertion at Recycler Flying Wire System

    SciTech Connect (OSTI)

    K.Y. Ng

    2004-02-27

    Ferrite rods are installed inside the flying-wire cavity of the Recycler Ring and at entrance and exit beam pipes in order to absorb high-frequency electromagnetic waves excited by the beam. However, these rods may also deteriorate the vacuum pressure of the ring. An investigation is made to analyze the necessity of the ferrite rods at the entrance and exit beam pipes.

  6. Recycling Technology Validation | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon lm_30_pomykala.pdf More Documents & Publications Overview of Recycling Technology R&D Post-Shred Materials Recovery Technology Development and Demonstration Cool Trends on Campus: A Survey of Thermal Energy Storage Use in Campus District Energy Systems, May 2005

  7. Regional cooperative marketing of recyclable materials

    SciTech Connect (OSTI)

    Prete, P.J. )

    1993-01-01

    This paper discusses cooperative marketing and its role in recycling programs. The first section of the paper presents a snapshot of cooperative marketing, describes trends, and analyzes driving forces. The maturing recycling industry is examined to speculate on why cooperative marketing is emerging at this time, in certain areas, and in specific subsets of the industry. The second section provides analytical tools to help waste management personnel evaluate cooperative marketing alternatives. Criteria are presented to help evaluate programs to determine if and when cooperative marketing is practical and advantageous for rural, low budget, or new programs. Situations driven by special problems with local recyclable materials markets will be discussed. The last section focuses on steps for putting cooperative marketing programs in place. Attendees are given insight that should enable them to initiate the process of pursuing cooperative marketing. Strategies addressed range from developing program objectives compatible with other community programs and arranging necessary communications, to assessing markets, determining resource needs, predicting material quantities, and optimizing materials supplies to meet market requirements.

  8. Expanded recycling at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Betschart, J.F.; Malinauskas, L.; Burns, M.

    1996-07-01

    The Pollution Prevention Program Office has increased recycling activities, reuse, and options to reduce the solid waste streams through streamlining efforts that applied best management practices. The program has prioritized efforts based on volume and economic considerations and has greatly increased Los Alamos National Laboratory`s (LANL`s) recycle volumes. The Pollution Prevention Program established and chairs a Solid Waste Management Solutions Group to specifically address and solve problems in nonradioactive, Resource Conservation and Recovery Act (RCRA), state-regulated, and sanitary and industrial waste streams (henceforth referred to as sanitary waste in this paper). By identifying materials with recycling potential, identifying best management practices and pathways to return materials for reuse, and introducing the concept and practice of {open_quotes}asset management,{open_quotes} the Group will divert much of the current waste stream from disposal. This Group is developing procedures, agreements, and contracts to stage, collect, sort, segregate, transport and process materials, and is also garnering support for the program through the involvement of upper management, facility managers, and generators.

  9. Recycling efficiency: The shape of things to come

    SciTech Connect (OSTI)

    Miller, C.

    1995-09-01

    In the mid-`70s, curbside recycling was easy. Virtually all the programs collected only newspaper at the curbside. They were placed in a rack beneath the garbage truck or in a trailer behind the truck. Of course, the rack might fill up too soon, but that was a minor problem, usually resolved by offloading sites for the newspaper. Today, curbside recycling is much more complicated. Curbside programs can collect a bewildering array of materials, including plastics, mixed paper, and even textiles. The simple rack is in the Smithsonian, replaced by highly sophisticated vehicles. Some can automatically collect recyclables without the driver ever getting out of the cab. Simplicity, it seems, has given way to complexity as recycling rates have skyrocketed. The recycling industry has been buffeted recently by a slew of anti-recycling articles in the popular press, yet, ironically, it has been enjoying the best markets has blunted the anti-recyclers. However, bull markets are not forever. Recyclers cannot afford to adopt a ``What, me worry?`` attitude towards the business of recycling. As collectors become increasingly skilled in collecting recyclables, they can translating these skills into more efficient programs.

  10. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    Laster, W. R.; Anoshkina, E.

    2008-01-31

    Under the sponsorship of the U. S. Department of Energy’s National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1- Implementation Plan, Phase 2- Validation Testing and Phase 3 – Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

  11. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    W. R. Laster; E. Anoshkina

    2008-01-31

    Under the sponsorship of the U. S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1 - Implementation Plan, Phase 2 - Validation Testing and Phase 3 - Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

  12. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  13. U.S. Downstream Processing of Fresh Feed Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Sep-15 Oct-15 Nov-15 Dec-15 Jan-16 Feb-16 View History Catalytic Reforming 2,837 2,690 2,748 2,812 2,668 2,629 2010-2016 Catalytic Cracking 5,000 4,572 4,831 4,892 4,989 4,767 1987-2016 Catalytic Hydrocracking 1,723 1,721 1,806 1,864 1,639 1,697 1987-2016 Delayed and Fluid Coking 2,333 2,293 2,509 2,537 2,393 2,378 1987-2016 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: Totals may not equal sum of components due

  14. Hot Showers, Fresh Laundry, Clean Dishes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Showers, Fresh Laundry, Clean Dishes Hot Showers, Fresh Laundry, Clean Dishes March 5, 2013 - 11:17am Addthis The GE GeoSpring™ Electric Heat Pump Water Heater is readily integrated into new and existing home designs. Taking up the same footprint as a traditional 50-gallon tank water heater, the Electric Heat Pump Water Heater uses the existing water heater's plumbing and electrical connections. Credit: GE The GE GeoSpring(tm) Electric Heat Pump Water Heater is readily integrated into

  15. Fresh nuclear fuel measurements at Ukrainian nuclear power plants

    SciTech Connect (OSTI)

    Kuzminski, Jozef; Ewing, Tom; Dickman, Debbie; Gavrilyuk, Victor; Drapey, Sergey; Kirischuk, Vladimir; Strilchuk, Nikolay

    2009-01-01

    In 2005, the Provisions on Nuclear Material Measurement System was enacted in Ukraine as an important regulatory driver to support international obligations in nuclear safeguards and nonproliferation. It defines key provisions and requirements for material measurement and measurement control programs to ensure the quality and reliability of measurement data within the framework of the State MC&A System. Implementing the Provisions requires establishing a number of measurement techniques for both fresh and spent nuclear fuel for various types of Ukrainian reactors. Our first efforts focused on measurements of fresh nuclear fuel from a WWR-1000 power reactor.

  16. Catalytic reactive separation system for energy-efficient production of cumene

    DOE Patents [OSTI]

    Buelna, Genoveva; Nenoff, Tina M.

    2009-07-28

    The present invention relates to an atmospheric pressure, reactive separation column packed with a solid acid zeolite catalyst for producing cumene from the reaction of benzene with propylene. Use of this un-pressurized column, where simultaneous reaction and partial separation occur during cumene production, allow separation of un-reacted, excess benzene from other products as they form. This high-yielding, energy-efficient system allows for one-step processing of cumene, with reduced need for product purification. Reacting propylene and benzene in the presence of beta zeolite catalysts generated a selectivity greater than 85% for catalytic separation reactions at a reaction temperature of 115 degrees C and at ambient pressure. Simultaneously, up to 76% of un-reacted benzene was separated from the product; which could be recycled back to the reactor for re-use.

  17. FA 3: Improving Reuse and Recycling | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3: Improving Reuse and Recycling Focus Area 3 - Peterson, Jones CMI Org Chart with Hotlinks: Focus Area 3 File: Read more about CMI Org Chart with Hotlinks: Focus Area 3 CMI Org Chart with Hotlinks: Research Overview File: Read more about CMI Org Chart with Hotlinks: Research Overview Photo montage: recycling File: Read more about Photo montage: recycling CMI org chart for research with hotlinks (pdf) File: Read more about CMI org chart for research with hotlinks (pdf) Critical Materials

  18. FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER

    Office of Scientific and Technical Information (OSTI)

    REACTORS USING HYDRIDE FUEL (Technical Report) | SciTech Connect FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL Citation Details In-Document Search Title: FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL The objective of this DOE NERI program sponsored project was to assess the feasibility of improving the plutonium (Pu) and minor actinide (MA) recycling capabilities of pressurized water

  19. Way to recycle, BES Technologies | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program / Way to recycle, BES ... Way to recycle, BES Technologies Posted: July 29, 2015 - 10:31am At right, Brian Quinley, Chief Operations Officer for BES Technologies, LLC, gives Rep. John Duncan a tour of the laundry facility at East Tennessee Technology Park. BES Technologies, LLC, a service-disabled veteran-owned small business, has reached a major milestone by recycling 1 million gallons of radiological waste water through its laundry operations located at the East Tennessee Technology

  20. Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Wastewater | Department of Energy Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling, and Wastewater Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling, and Wastewater Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste Feedstocks Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling, and Wastewater Jordi Perez, Scientist, SRI International PDF icon

  1. Integrating catalytic coal gasifiers with solid oxide fuel cells

    SciTech Connect (OSTI)

    Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

    2010-01-01

    A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

  2. FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT...

    Office of Scientific and Technical Information (OSTI)

    IN LIGHT WATER REACTORS USING HYDRIDE FUEL Citation Details In-Document Search Title: FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING ...

  3. Integration of Nutrient and Water Recycling for Sustainable Algal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nutrient and Water Recycling for Sustainable Algal Biorefineries 03252015 ALGAE TECHNOLOGY AREA Presenters: (1) Sridhar Viamajala, The University of Toledo; (2) Brent Peyton, ...

  4. Recycling and computerized garbage tracking cut city's costs

    SciTech Connect (OSTI)

    Norris, J.L. )

    1994-02-01

    This article describes Athens, Ohio efforts to encourage recycling and minimizing of landfilled garbage by a sliding rate system for garbage collection that accommodates the highly transient nature of this college community. Residential waste going to the landfill has been reduced by as much as 50 percent. Recycling is scheduled the same day as garbage collection. Recycling crews sort all items and package them for sale. Yard wastes are also recycled and are co-mingled with digested municipal sludge generated at the waste-water treatment plant and applied on agricultural fields as a soil conditioner.

  5. FY 2008 Progress Report for Lightweighting Materials - 11. Recycling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FY 2008 Progress Report for Lightweighting Materials - 11. Recycling Lightweighting Materials focuses on the development and validation of advanced materials and manufacturing ...

  6. Pennsylvania to require statewide recycling of solid wastes

    SciTech Connect (OSTI)

    Not Available

    1988-11-01

    The new law, requiring trash recycling in 407 communities affecting 7.8 million Pennsylvanians, is a key component of the Casey administration's comprehensive environmental clean up plant. The new recycling law requires municipalities with more than 10,000 residents to start curb-side recycling programs within two years. Communities with 5000 to 10,000 residents must start recycling in three years. The goal is to reduce the state's volume of solid waste by 25 percent by 1997. Nine million tons of trash are generated each year in Pennsylvania, with 95 percent of it landfilled and only one percent recycled. Much of the state's solid waste must be transported over increasing distances at increasing costs to be disposed of. Average trash disposal costs have increased 150 percent in the past three years. The new law requires communities to recycle three of eight materials, including glass, colored glass, aluminum, steel and bimetallic cans, high-grade office paper, newsprint, corrugated paper and plastics. All communities must recycle leaf waste. The legislation shifts responsibility for planning solid waste disposal from municipalities to counties, reimbursing counties 80 percent of the cost of developing comprehensive recycling plans and 50 percent of the cost of hiring a recycling coordinator. The program will be self-supporting through a $2-per-ton fee on all garbage going to landfills and resource recovery.

  7. Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids U.S ... Petersburg City Project Manager Eron Jacobson, PE Brown and Caldwell Gas Upgrade Systems ...

  8. Future Bottlenecks for Industrial Water Recycling. Brady, Patrick...

    Office of Scientific and Technical Information (OSTI)

    Future Bottlenecks for Industrial Water Recycling. Brady, Patrick V. Abstract Not Provided Sandia National Laboratories USDOE National Nuclear Security Administration (NNSA) United...

  9. Recycling and processing of several typical crosslinked polymer...

    Office of Scientific and Technical Information (OSTI)

    Recycling and processing of several typical crosslinked polymer scraps with enhanced mechanical properties based on solid-state mechanochemical milling Citation Details In-Document...

  10. Performance characterization of a hydrogen catalytic heater.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Kanouff, Michael P.

    2010-04-01

    This report describes the performance of a high efficiency, compact heater that uses the catalytic oxidation of hydrogen to provide heat to the GM Hydrogen Storage Demonstration System. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to a circulating heat transfer fluid. The fluid then transfers the heat to one or more of the four hydrogen storage modules that make up the Demonstration System to drive off the chemically bound hydrogen. The heater consists of three main parts: (1) the reactor, (2) the gas heat recuperator, and (3) oil and gas flow distribution manifolds. The reactor and recuperator are integrated, compact, finned-plate heat exchangers to maximize heat transfer efficiency and minimize mass and volume. Detailed, three-dimensional, multi-physics computational models were used to design and optimize the system. At full power the heater was able to catalytically combust a 10% hydrogen/air mixture flowing at over 80 cubic feet per minute and transfer 30 kW of heat to a 30 gallon per minute flow of oil over a temperature range from 100 C to 220 C. The total efficiency of the catalytic heater, defined as the heat transferred to the oil divided by the inlet hydrogen chemical energy, was characterized and methods for improvement were investigated.

  11. Method of making a catalytic converter

    SciTech Connect (OSTI)

    Bailey, C.H.; De Palma, T.V.; Dillon, J.E.

    1982-08-10

    Arrangement for resiliently mounting a ceramic monolithic type catalytic converter element in a metal housing with a blanket of knit wire mesh material includes at least one circumferential band of high temperature intumescent material containing ceramic fibers positioned within the wire mesh blanket which prevents virtually all bypass leakage around the element and substantially reduces the temperature of the wire mesh.

  12. Production of LPG olefins by catalytic dehydrogenation

    SciTech Connect (OSTI)

    Pujado, P.R.; Vora, B.V.

    1984-09-01

    Catalytic dehydrogenation allows for the production of specific olefins thus avoiding the large capital and operating expenses associated with the recovery and processing of the many by-products from pyrolysis units. The chemistry of the process is discussed along with the process economics.

  13. Process for catalytically oxidizing cycloolefins, particularly cyclohexene

    DOE Patents [OSTI]

    Mizuno, Noritaka (Sapporo, JP); Lyon, David K. (Bend, OR); Finke, Richard G. (Eugene, OR)

    1993-01-01

    This invention is a process for catalytically oxidizing cycloolefins, particularly cyclohexenes, to form a variety of oxygenates. The catalyst used in the process is a covalently bonded iridium-heteropolyanion species. The process uses the catalyst in conjunction with a gaseous oxygen containing gas to form 2-cyclohexen-1-ol and also 2-cyclohexen-1-one.

  14. A Photosynthetic Hydrogel for Catalytic Hydrogen Production | ANSER Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Argonne-Northwestern National Laboratory A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production

  15. Reducing cold-start emissions by catalytic converter thermal management

    SciTech Connect (OSTI)

    Burch, S D; Potter, T F; Keyser, M A; Brady, M J; Michaels, K F

    1995-01-01

    Vacuum insulation and phase-change thermal storage have been used to enhance the heat retention of a prototype catalytic converter. Storing heat in the converter between trips allows exhaust gases to be converted more quickly, significantly reducing cold-start emissions. Using a small metal hydride, the thermal conductance of the vacuum insulation can be varied continuously between 0.49 and 27 W/m{sup 2}K (R-12 to R-0.2 insulation) to prevent overheating of the catalyst. A prototype was installed in a Dodge Neon with a 2.0-liter engine. Following a standard preconditioning and a 23-hour cold soak, an FTP (Federal Test Procedure) emissions test was performed. Although exhaust temperatures during the preconditioning were not hot enough to melt the phase-change material, the vacuum insulation performed well, resulting in a converter temperature of 146{degrees}C after the 23-hour cold soak at 27{degrees}C. Compared to the same converter at ambient conditions, overall emissions of CO and HC were reduced by 52 % and 29 %, to 0.27 and 0.037 g/mile, respectively. The maximum converter temperature during the FTP cycle was 720{degrees}C. This limited testing was performed with a nearly-fresh palladium-only catalyst, but demonstrates the potential of this vacuum insulation approach for emissions reduction and thermal control. Further testing is ongoing. An initial assessment of several production issues is made, including high-volume fabrication challenges, durability, and cost.

  16. Taiwan`s experience with municipal waste recycling

    SciTech Connect (OSTI)

    Lee, C.H.

    1998-12-31

    Currently, each person on the average produces 1.15 kg of the municipal waste per day and a total of 9 million metric tons were generated annually in Taiwan. The disposal of such a huge amount of waste presents tremendous challenge for the island due to the scarcity of landfills and incineration facilities available locally. EPA of Taiwan, R.O.C. thus takes an active role in promoting waste recycling to reduce the garbage produced in municipalities. In order to efficiently utilize the government`s human and financial resources used in recycling, started from January 31, 1989, EPA has mandated the producer responsibility recycling program for several designated post-consumer products such as PET, PVC bottles, scrap tires, scrap motor vehicles, etc. Producer responsibility recycling program specifies that the manufacturers, importers and sellers of these designated products have the responsibility to retrieve their products and recycle them properly. Several negative effects have been encountered while the implementation of this producer responsibility recycling program in Taiwan which resulted in a modification of this recycling program recently. This paper presents the encountered experiences on the implementation of municipal waste recycling program in Taiwan.

  17. New Choctaw Nation Recycling Center Posts Quick Results

    Broader source: Energy.gov [DOE]

    “If you build it, they will come" ...to recycle. That line from the 1989 film Field of Dreams is as good a way as any to describe how the Choctaw Nation of Oklahoma’s new regional recycling center is being received.

  18. Waste stream recycling: Its effect on water quality

    SciTech Connect (OSTI)

    Cornwell, D.A. ); Lee, R.G. )

    1994-11-01

    Waste streams recycled to the influent of a water treatment plant typically contain contaminants at concentrations that are of concern. These contaminants may include giardia and Cryptosporidium, trihalomethanes, manganese, and assimilable organic carbon. This research shows that proper management--treatment, equalization, and monitoring--of the waste streams can render them suitable for recycling in many situations.

  19. Cleaning Out? Don't Forget to Recycle! | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cleaning Out? Don't Forget to Recycle Cleaning Out? Don't Forget to Recycle January 24, 2013 - 5:30pm Addthis Recycling your old electronics is easy and good for the environment. ...

  20. Elimination Of Catalytic Hydrogen Generation In Defense Waste Processing Facility Slurries

    SciTech Connect (OSTI)

    Koopman, D. C.

    2013-01-22

    Based on lab-scale simulations of Defense Waste Processing Facility (DWPF) slurry chemistry, the addition of sodium nitrite and sodium hydroxide to waste slurries at concentrations sufficient to take the aqueous phase into the alkaline region (pH > 7) with approximately 500 mg nitrite ion/kg slurry (assuming <25 wt% total solids, or equivalently 2,000 mg nitrite/kg total solids) is sufficient to effectively deactivate the noble metal catalysts at temperatures between room temperature and boiling. This is a potential strategy for eliminating catalytic hydrogen generation from the list of concerns for sludge carried over into the DWPF Slurry Mix Evaporator Condensate Tank (SMECT) or Recycle Collection Tank (RCT). These conclusions are drawn in large part from the various phases of the DWPF catalytic hydrogen generation program conducted between 2005 and 2009. The findings could apply to various situations, including a solids carry-over from either the Sludge Receipt and Adjustment Tank (SRAT) or Slurry Mix Evaporator (SME) into the SMECT with subsequent transfer to the RCT, as well as a spill of formic acid into the sump system and transfer into an RCT that already contains sludge solids. There are other potential mitigating factors for the SMECT and RCT, since these vessels are typically operated at temperatures close to the minimum temperatures that catalytic hydrogen has been observed to occur in either the SRAT or SME (pure slurry case), and these vessels are also likely to be considerably more dilute in both noble metals and formate ion (the two essential components to catalytic hydrogen generation) than the two primary process vessels. Rhodium certainly, and ruthenium likely, are present as metal-ligand complexes that are favored under certain concentrations of the surrounding species. Therefore, in the SMECT or RCT, where a small volume of SRAT or SME material would be significantly diluted, conditions would be less optimal for forming or sustaining the catalytic ligand species. Such conditions are likely to adversely impact the ability of the transferred mass to produce hydrogen at the same rate (per unit mass SRAT or SME slurry) as in the SRAT or SME vessels.

  1. Innovative Fresh Water Production Process for Fossil Fuel Plants

    SciTech Connect (OSTI)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight; Venugopal Jogi

    2005-09-01

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A dynamic analysis of heat and mass transfer demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3 Hg. The optimum operating condition for the DDD process with a high temperature of 50 C and sink temperature of 25 C has an air mass flux of 1.5 kg/m{sup 2}-s, air to feed water mass flow ratio of 1 in the diffusion tower, and a fresh water to air mass flow ratio of 2 in the condenser. Operating at these conditions yields a fresh water production efficiency (m{sub fW}/m{sub L}) of 0.031 and electric energy consumption rate of 0.0023 kW-hr/kg{sub fW}. Throughout the past year, the main focus of the desalination process has been on the direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. The analyses agree quite well with the current data. Recently, it has been recognized that the fresh water production efficiency can be significantly enhanced with air heating. This type of configuration is well suited for power plants utilizing air-cooled condensers. The experimental DDD facility has been modified with an air heating section, and temperature and humidity data have been collected over a range of flow and thermal conditions. It has been experimentally observed that the fresh water production rate is enhanced when air is heated prior to entering the diffusion tower. Further analytical analysis is required to predict the thermal and mass transport with the air heating configuration.

  2. Transport from the Recycler Ring to the Antiproton Source Beamlines

    SciTech Connect (OSTI)

    Xiao, M.; /Fermilab

    2012-05-14

    In the post-NOvA era, the protons are directly transported from the Booster ring to the Recycler ring rather than the Main Injector. For Mu2e and g-2 project, the Debuncher ring will be modified into a Delivery ring to deliver the protons to both Mu2e and g-2 experiments. Therefore, it requires the transport of protons from the Recycler Ring to the Delivery ring. A new transfer line from the Recycler ring to the P1 beamline will be constructed to transport proton beam from the Recycler Ring to existing Antiproton Source beamlines. This new beamline provides a way to deliver 8 GeV kinetic energy protons from the Booster to the Delivery ring, via the Recycler, using existing beam transport lines, and without the need for new civil construction. This paper presents the Conceptual Design of this new beamline.

  3. NRC's 13th Annual Congress highlights the mainstream of recycling

    SciTech Connect (OSTI)

    White, K.M.

    1994-12-01

    The theme of the National Recycling Coalition's (NRC, Washington, DC) recent 13th Annual Congress and Exposition in Portland, OR, was ''Jump into the Mainstream: Recycle,'' which is an action organizers of the show set out to prove is currently happening across this country. Indeed, this year's congress was designed to demonstrate how far recycling has jumped into the mainstream of American life, and show attendees what it will take to make recycling succeed in the future. Lending testament to recycling's increasing visibility, the most dominant topic at this year's show was the creation of national recycling policy. Through this agenda, and other programs that surfaced at the congress, NRC is hoping to move closer to its goal of making recycling as mainstream as taking out the garbage. NRC's board of directors unanimously voted to adopt a draft advocacy message that promotes recycling initiatives at the national level, but rejected a proposed demand-side initiative that would have established post-consumer-content recycling rates for certain materials, with product-specific, minimum-content standards as an alternative method of compliance. The initiative had called for glass, metal, paper, plastic, and wood used in primary and secondary packaging to achieve a 50% post-consumer recycling rate by the year 2000. As an alternative method of compliance, individual companies could meet the following post-consumer, minimum-content standards for products: glass, metal, paper, plastic, and wood packaging: 40% by 2000; newsprint and tissue paper: 50% by 2000; and printing and writing papers: 25% by 2000.

  4. Recycling technologies and market opportunities: Proceedings

    SciTech Connect (OSTI)

    Goland, A.N.; Petrakis, L.

    1993-09-20

    These proceedings are the result of our collective effort to meet that challenge. They reflect the dedication and commitment of many people in government, academia, the private sector and national laboratories to finding practical solutions to one of the most pressing problems of our time -- how to deal effectively with the growing waste s that is the product of our affluent industrial society. The Conference was successful in providing a clear picture of the scope of the problem and of the great potential that recycling holds for enhancing economic development while at the same time, having a significant positive impact on the waste management problem. That success was due in large measure to the enthusiastic response of our panelists to our invitation to participate and share their expertise with us.

  5. Montenay recyclable trash improvements (RTI) project

    SciTech Connect (OSTI)

    Smith, D.M.; Smith, E.F.

    1998-07-01

    Municipal trash is converted to a solid fuel for an off-site boiler installation. Existing Miami-Dade Resources Recovery Facilities were modified and new processing facilities were added at a cost of $26 million dollars. This major recycling project was developed over three years, was built in 1996 and was successfully commissioned in 1997. Process machinery includes three modified shredders with a final throughput capacity of 110 tons per hour, conveyors, trommels, and raw product separation equipment. The RTI process makes commercial grade biomass fuel and two soil products. A discussion of process design and testing is presented. Other bulk material handling issues such as delivery contracts for raw trash ad remote site fuel delivery is included. Elements of the plant designs for truck tipping, rejects separation, process and storage buildings are also discussed.

  6. Method and apparatus for a catalytic firebox reactor

    DOE Patents [OSTI]

    Smith, Lance L.; Etemad, Shahrokh; Ulkarim, Hasan; Castaldi, Marco J.; Pfefferle, William C.

    2001-01-01

    A catalytic firebox reactor employing an exothermic catalytic reaction channel and multiple cooling conduits for creating a partially reacted fuel/oxidant mixture. An oxidation catalyst is deposited on the walls forming the boundary between the multiple cooling conduits and the exothermic catalytic reaction channel, on the side of the walls facing the exothermic catalytic reaction channel. This configuration allows the oxidation catalyst to be backside cooled by any fluid passing through the cooling conduits. The heat of reaction is added to both the fluid in the exothermic catalytic reaction channel and the fluid passing through the cooling conduits. After discharge of the fluids from the exothermic catalytic reaction channel, the fluids mix to create a single combined flow. A further innovation in the reactor incorporates geometric changes in the exothermic catalytic reaction channel to provide streamwise variation of the velocity of the fluids in the reactor.

  7. A Fresh Take on Groundwater at Amargosa Valley Open House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 25, 2012 A Fresh Take on Groundwater at Amargosa Valley Open House From drilling to sampling, groundwater was the topic on everyone's mind at a recent open house in Amargosa Valley, Nevada. On September 18, 2012, residents of Beatty, Amargosa Valley, Pahrump and other neighboring communities gathered at the Amargosa Community Center for the 4th Annual Groundwater Open House. The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office conducts the annual

  8. Catalytic fast pyrolysis of lignocellulosic biomass

    SciTech Connect (OSTI)

    Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

    2014-11-21

    Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuel—bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

  9. Control of a catalytic fluid cracker

    SciTech Connect (OSTI)

    Arbel, A.; Huang, Z.; Rinard, I.; Shinnar, R.

    1993-12-13

    Control offers an important tool for savings in refineries, mainly by integration of process models into on-line control. This paper is part of a research effort to better understand problems of partial control; control of a Fluid Catalytic Cracker (FCC) is used as example. Goal is to understand better the control problems of an FCC in context of model based control of a refinery, and to understand the general problem of designing partial control systems.

  10. Pulsating catalytic combustion of gaseous fuels

    SciTech Connect (OSTI)

    Gal-Ed, R.

    1988-01-01

    This study investigated the feasibility of operating catalytic combustors under pulsating conditions and the circumstances under which acoustic pulsations increase the combustion efficiencies and output of catalytic combustors. An experimental catalytic combustor was developed, and a theoretical model of acoustic motions in non-isothermal, low match number, duct flow was used to predict the acoustic behavior of the combustor. The effects of pulsations were determined by comparing temperature and species concentration data measured during operation with pulsations at different frequencies and pressure amplitudes to similar data measured during non-pulsating combustion. Experiments conducted with lean mixtures of methane or propane with air revealed that acoustic pulsations affected the temperature distribution along the combustor at flow Reynolds numbers less than 17,500. Excitation of pulsations during methane combustion caused shifts in the location of the combustion, and sometimes the onset of extinction of gas phase reactions. This occurred when several catalyst segments were located in the combustion section between an upstream pressure node and a downstream velocity node, defined here as an in phase location. Propane mixtures were used to investigate possible improvements in combustor's performance. Burning propane mixtures on a single catalyst segment at an in phase location showed that the excitation of acoustic pulsations increased the combustion efficiency by 10 to 50%. The changes in the operation of catalytic combustors caused by acoustic waves are explained by acoustic streaming. When the catalyst surfaces are at an in phase location, rotational flows caused by acoustic streaming enhance the reactants and products diffusion rate to and from the catalyst surfaces, respectively, improving combustion efficiency.

  11. Catalytic extraction processing of contaminated scrap metal

    SciTech Connect (OSTI)

    Griffin, T.P.; Johnston, J.E.; Payea, B.M.; Zeitoon, B.M.

    1995-12-01

    Molten Metal Technology was awarded a contract to demonstrate the applicability of the Catalytic Extraction Process, a proprietary process that could be applied to US DOE`s inventory of low level mixed waste. This paper is a description of that technology, and included within this document are discussions of: (1) Program objectives, (2) Overall technology review, (3) Organic feed conversion to synthetic gas, (4) Metal, halogen, and transuranic recovery, (5) Demonstrations, (6) Design of the prototype facility, and (7) Results.

  12. Preface: Challenges for Catalytic Exhaust Aftertreatment

    SciTech Connect (OSTI)

    Nova, Isabella; Epling, Bill; Peden, Charles HF

    2014-03-31

    This special issue of Catalysis Today continues the tradition established since the 18th NAM in Cancun, 2003, of publishing the highlights coming from these catalytic after-treatment technologies sessions, where this volume contains 18 papers based on oral and poster presentations of the 23rd NAM, 2013. The guest editors would like to thank all of the catalyst scientists and engineers who presented in the "Emission control" sessions, and especially the authors who contributed to this special issue of Catalysis Today.

  13. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2004-09-01

    An innovative Diffusion Driven Desalination (DDD) process was recently described where evaporation of mineralized water is driven by diffusion within a packed bed. The energy source to drive the process is derived from low pressure condensing steam within the main condenser of a steam power generating plant. Since waste heat is used to drive the process, the main cost of fresh water production is attributed to the energy cost of pumping air and water through the packed bed. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A combined thermodynamic and dynamic analysis demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3'' Hg. Throughout the past year, the main focus of the desalination process has been on the diffusion tower and direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. An experimental DDD facility has been fabricated, and temperature and humidity data have been collected over a range of flow and thermal conditions. The analyses agree quite well with the current data and the information available in the literature. Direct contact condensers with and without packing have been investigated. It has been experimentally observed that the fresh water production rate is significantly enhanced when packing is added to the direct contact condensers.

  14. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    James F. Klausner; Renwei Mei; Yi Li; Mohamed Darwish; Diego Acevedo; Jessica Knight

    2003-09-01

    This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system, which is powered by the waste heat from low pressure condensing steam in power plants. The desalination is driven by water vapor saturating dry air flowing through a diffusion tower. Liquid water is condensed out of the air/vapor mixture in a direct contact condenser. A thermodynamic analysis demonstrates that the DDD process can yield a fresh water production efficiency of 4.5% based on a feed water inlet temperature of only 50 C. An example is discussed in which the DDD process utilizes waste heat from a 100 MW steam power plant to produce 1.51 million gallons of fresh water per day. The main focus of the initial development of the desalination process has been on the diffusion tower. A detailed mathematical model for the diffusion tower has been described, and its numerical implementation has been used to characterize its performance and provide guidance for design. The analysis has been used to design a laboratory scale diffusion tower, which has been thoroughly instrumented to allow detailed measurements of heat and mass transfer coefficient, as well as fresh water production efficiency. The experimental facility has been described in detail.

  15. Catalytic Upgrading of Sugars Presentation for BETO 2015 Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Compare their performance to the currently used Ptsilica-alumina catalyst to identify ... preliminary TEA and sensitivity analyses based on product yield, selectivity, and recycle. ...

  16. Recycle of contaminated scrap metal, Volume 2. Semi-annual report, September 1993--January 1996

    SciTech Connect (OSTI)

    1996-07-01

    Catalytic Extraction Processing (CEP) has been demonstrated to be a robust, one-step process that is relatively insensitive to wide variations in waste composition and is applicable to a broad spectrum of DOE wastes. Catalytic Processing Unit (CPU) design models have been validated through experimentation to provide a high degree of confidence in our ability to design a bulk solids CPU for processing DOE wastes. Two commercial CEP facilities have been placed in commission and are currently processing mixed low level wastes. These facilities provide a compelling indication of the maturity, regulatory acceptance, and commercial viability of CEP. In concert with the DOE, Nolten Metal Technology designed a program which would challenge preconceptions of the limitations of waste processing technologies: demonstrate the recycling of ferrous and non-ferrous metals--to establish that radioactively contaminated scrap metal could be converted to high-grade, ferrous and non-ferrous alloys which can be reused by DOE or reintroduced into commerce; immobilize radionuclides--that CEP would concentrate the radionuclides in a durable vitreous phase, minimize secondary waste generation and stabilize and reduce waste volume; destroy hazardous organics--that CEP would convert hazardous organics to valuable industrial gases, which could be used as an energy source; recover volatile heavy metals--that CEP`s off-gas treatment system would capture volatile heavy metals, such as mercury and lead; and establish that CEP is economical for processing contaminated scrap metal in the DOE inventory. The execution of this program resulted in all objectives being met. Volume II contains: Task 1.4, optimization of the vitreous phase for stabilization of radioactive species; Task 1.5, experimental testing of Resource Conservation and Recovery Act (RCRA) wastes; and Task 1.6, conceptual design of a CEP facility.

  17. Recycle of contaminated scrap metal, Volume 1. Semi-annual report, September 1993--January 1996

    SciTech Connect (OSTI)

    1996-07-01

    Catalytic Extraction Processing (CEP) has been demonstrated to be a robust, one-step process that is relatively insensitive to wide variations in waste composition and is applicable to a broad spectrum of DOE wastes. Catalytic Processing Unit (CPU) design models have been validated through experimentation to provide a high degree of confidence in our ability to design a bulk solids CPU for processing DOE wastes. Two commercial CEP facilities have been placed in commission and are currently processing mixed low level wastes. These facilities provide a compelling indication of the maturity, regulatory acceptance, and commercial viability of CEP. In concert with the DOE, Nolten Metal Technology designed a program which would challenge preconceptions of the limitations of waste processing technologies: demonstrate the recycling of ferrous and non-ferrous metals--to establish that radioactively contaminated scrap metal could be converted to high-grade, ferrous and non-ferrous alloys which can be reused by DOE or reintroduced into commerce; immobilize radionuclides--that CEP would concentrate the radionuclides in a durable vitreous phase, minimize secondary waste generation and stabilize and reduce waste volume; destroy hazardous organics--that CEP would convert hazardous organics to valuable industrial gases, which could be used as an energy source; recover volatile heavy metals--that CEP`s off-gas treatment system would capture volatile heavy metals, such as mercury and lead; establish that CEP is economical for processing contaminated scrap metal in the DOE inventory. The execution of this program resulted in all objectives being met. Volume I covers: executive summary; task 1.1 design CEP system; Task 1.2 experimental test plan; Task 1.3 experimental testing.

  18. Heavy oil catalytic cracking process and apparatus (Patent) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Heavy oil catalytic cracking process and apparatus Citation Details In-Document Search Title: Heavy oil catalytic cracking process and apparatus This paper describes a fluidized catalytic cracking process for catalytic cracking of a feed comprising hydrocarbons having a boiling point about 750 F. It comprises: a catalytically cracking the feed in a catalytic cracking zone riser reactor having a height in excess of 30 meters at catalytic cracking conditions by contacting the feed with

  19. Recyclable organic solar cells on substrates comprising cellulose nanocrystals (CNC)

    DOE Patents [OSTI]

    Kippelen, Bernard; Fuentes-Hernandez, Canek; Zhou, Yinhua; Moon, Robert; Youngblood, Jeffrey P

    2015-12-01

    Recyclable organic solar cells are disclosed herein. Systems and methods are further disclosed for producing, improving performance, and for recycling the solar cells. In certain example embodiments, the recyclable organic solar cells disclosed herein include: a first electrode; a second electrode; a photoactive layer disposed between the first electrode and the second electrode; an interlayer comprising a Lewis basic oligomer or polymer disposed between the photoactive layer and at least a portion of the first electrode or the second electrode; and a substrate disposed adjacent to the first electrode or the second electrode. The interlayer reduces the work function associated with the first or second electrode. In certain example embodiments, the substrate comprises cellulose nanocrystals that can be recycled. In certain example embodiments, one or more of the first electrode, the photoactive layer, and the second electrode may be applied by a film transfer lamination method.

  20. A High-Performance Recycling Solution for PolystyreneAchieved...

    Office of Scientific and Technical Information (OSTI)

    A High-Performance Recycling Solution for PolystyreneAchieved by the Synthesis of Renewable Poly(thioether) Networks Derived from D -Limonene Citation Details In-Document Search ...

  1. DOE, Washington Closure complete recycling project at Hanford

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – The U.S. Department of Energy (DOE) recently teamed with contractor Washington Closure Hanford to complete a major recycling effort during cleanup of the Hanford Site in southeastern Washington State.

  2. Demolitions Produce Recyclable Materials for Organization Promoting Economic Activity

    Broader source: Energy.gov [DOE]

    Demolitions have helped generate more than 8 million pounds of metal at the Piketon site for recycling, further promoting economic activity in the region thanks to the American Recovery and...

  3. Vehicle Technologies Office Merit Review 2014: Advanced Battery Recycling

    Broader source: Energy.gov [DOE]

    Presentation given by OnTo Technology LLC at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced battery recycling.

  4. A Goldilocks Catalyst: Nanocluster 'just right' for Recycling...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon dioxide (CO2) emissions from fossil fuel combustion are major contributors to global warming. Since CO2 comes from fuel, why can't we recycle it back into fuel rather...

  5. Ramsey County commercial, industrial, institutional waste reduction and recycling program

    SciTech Connect (OSTI)

    Lyman-Onkka, C.

    1995-09-01

    The Ramsey County Commercial, Industrial, Institutional Waste Reduction and Recycling Program was developed (1) to raise awareness of waste reduction and recycling opportunities for businesses, (2) to make information available to businesses, (3) to provide technical assistance to small and medium sized businesses on waste reduction and recycling, and (4) to raise awareness of Ramsey County as a technical resource. Ramsey County was founded in 1849 and is named for Alexander Ramsey, the first governor of the Minnesota Territory. Ramsey County is the smallest, most urban of all 87 counties in Minnesota. With 170 square miles and a 1990 population of 485,000, Ramsey has the most people per square mile of any county in Minnesota. There are 19 cities within the County, the largest is Saint Paul with a 1990 population of 272,000. There are no unincorporated areas in Ramsey County. This report describes the efforts directed towards raising the awareness of the county waste management, recycling program.

  6. Renewable and Recycled Energy Objective | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    an objective that 10% of all retail electricity sold in the state be obtained from renewable energy and recycled energy by 2015. The objective must be measured by qualifying...

  7. Site Recycles Millions of Pounds of Metal | Department of Energy

    Energy Savers [EERE]

    Site Recycles Millions of Pounds of Metal Site Recycles Millions of Pounds of Metal May 30, 2013 - 12:00pm Addthis The Portsmouth site worked with two regional companies and local law enforcement to arrange transportation of 10 massive synchronous condensers as part of an asset recovery effort. The Portsmouth site worked with two regional companies and local law enforcement to arrange transportation of 10 massive synchronous condensers as part of an asset recovery effort. PIKETON, Ohio - The EM

  8. Method of recycling lithium borate to lithium borohydride through diborane

    DOE Patents [OSTI]

    Filby, Evan E.

    1976-01-01

    This invention provides a method for the recycling of lithium borate to lithium borohydride which can be reacted with water to generate hydrogen for utilization as a fuel. The lithium borate by-product of the hydrogen generation reaction is reacted with hydrogen chloride and water to produce boric acid and lithium chloride. The boric acid and lithium chloride are converted to lithium borohydride through a diborane intermediate to complete the recycle scheme.

  9. Radiotoxicity Characterization of Multi-Recycled Thorium Fuel - 12394

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Radiotoxicity Characterization of Multi-Recycled Thorium Fuel - 12394 Citation Details In-Document Search Title: Radiotoxicity Characterization of Multi-Recycled Thorium Fuel - 12394 As described in companion papers, Westinghouse is proposing the implementation of a thorium based fuel cycle to burn the transuranic (TRU) contained in the used nuclear fuel. The potential of thorium as a TRU burner is described in another paper presented at this conference. This

  10. Recycler Medium Energy Elctron Coolinig Experiment (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Technical Report: Recycler Medium Energy Elctron Coolinig Experiment Citation Details In-Document Search Title: Recycler Medium Energy Elctron Coolinig Experiment No abstract prepared. Authors: MacLachlan, Jim ; Schmidt, Chuck ; Assadi, Saeed ; Kroc, Tom ; Jackson, Gerald P. ; Nagaisev, Sergei ; Warner, Arden A. ; Hurth, Patrick G. ; /Fermilab ; Burov, Alexi ; / ; Lee, S.Y. /Indiana U. ; Peng, Wei ; /BEPC Publication Date: 1997-11-14 OSTI

  11. Conversion Process for Aqueous Based Reprocessing and Recycling:

    Office of Scientific and Technical Information (OSTI)

    Denitration (Book) | SciTech Connect Book: Conversion Process for Aqueous Based Reprocessing and Recycling: Denitration Citation Details In-Document Search Title: Conversion Process for Aqueous Based Reprocessing and Recycling: Denitration Authors: Collins, Emory D [1] + Show Author Affiliations ORNL Publication Date: 2015-01-01 OSTI Identifier: 1185400 DOE Contract Number: DE-AC05-00OR22725 Resource Type: Book Publisher: Elsevier Ltd, Cambridge, United Kingdom Research Org: Oak Ridge

  12. Massive Hanford Test Reactor Removed - Plutonium Recycle Test Reactor

    Office of Environmental Management (EM)

    removed from Hanford's 300 Area | Department of Energy Massive Hanford Test Reactor Removed - Plutonium Recycle Test Reactor removed from Hanford's 300 Area Massive Hanford Test Reactor Removed - Plutonium Recycle Test Reactor removed from Hanford's 300 Area January 22, 2014 - 12:00pm Addthis Media Contacts Cameron Hardy, DOE 509-376-5365 Cameron.Hardy@re.doe.gov Mark McKenna, Washington Closure 509-372-9032 media@wch-rcc.com RICHLAND, WA - Hanford's River Corridor contractor, Washington

  13. Technical specifications for mechanical recycling of agricultural plastic waste

    SciTech Connect (OSTI)

    Briassoulis, D. Hiskakis, M.; Babou, E.

    2013-06-15

    Highlights: • Technical specifications for agricultural plastic wastes (APWs) recycling proposed. • Specifications are the base for best economical and environmental APW valorisation. • Analysis of APW reveals inherent characteristics and constraints of APW streams. • Thorough survey on mechanical recycling processes and industry as it applies to APW. • Specifications for APW recycling tested, adjusted and verified through pilot trials. - Abstract: Technical specifications appropriate for the recycling of agricultural plastic wastes (APWs), widely accepted by the recycling industry were developed. The specifications establish quality standards to be met by the agricultural plastics producers, users and the agricultural plastic waste management chain. They constitute the base for the best economical and environmental valorisation of the APW. The analysis of the APW streams conducted across Europe in the framework of the European project “LabelAgriWaste” revealed the inherent characteristics of the APW streams and the inherent constraints (technical or economical) of the APW. The APW stream properties related to its recycling potential and measured during pilot trials are presented and a subsequent universally accepted simplified and expanded list of APW recycling technical specifications is proposed and justified. The list includes two sets of specifications, applied to two different quality categories of recyclable APW: one for pellet production process (“Quality I”) and another one for plastic profile production process (“Quality II”). Parameters that are taken into consideration in the specifications include the APW physical characteristics, contamination, composition and degradation. The proposed specifications are focused on polyethylene based APW that represents the vast majority of the APW stream. However, the specifications can be adjusted to cover also APW of different materials (e.g. PP or PVC) that are found in very small quantities in protected cultivations in Europe. The adoption of the proposed specifications could transform this waste stream into a labelled commodity traded freely in the market and will constitute the base for the best economical and environmental valorisation of the APW.

  14. 'Recycling' Grid Energy with Flywheel Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    'Recycling' Grid Energy with Flywheel Technology 'Recycling' Grid Energy with Flywheel Technology September 30, 2010 - 5:03pm Addthis Seven-foot tall cylinders equipped with flywheel technology (shown above) will make up Beacon Power’s energy storage plant in Stephentown, N.Y. The company received a $43 million loan guarantee from the Energy Department to build the plant. | Photo courtesy of Beacon Power Corporation Seven-foot tall cylinders equipped with flywheel technology (shown above)

  15. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy of Sugars to Hydrocarbons Technology Pathway Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway

  16. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Ex-Situ Catalytic Fast Pyrolysis Technology Pathway Citation Details In-Document Search Title: Ex-Situ Catalytic Fast Pyrolysis Technology Pathway This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have

  17. In-Situ Catalytic Fast Pyrolysis Technology Pathway (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect In-Situ Catalytic Fast Pyrolysis Technology Pathway Citation Details In-Document Search Title: In-Situ Catalytic Fast Pyrolysis Technology Pathway This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have

  18. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway Citation Details In-Document Search Title: Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs

  19. 15.02.10 RH Transparent Catalytic - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent Catalytic Nickel Oxide Protecting Films for Photoanodes Sun, K. et al. Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films. PNAS 112 ( 12), 3612-3617, DOI: 10.1073/ pnas . 1423034112 (2015). Scientific Achievement Reactively sputtered NiOx layer provides a transparent, anti-reflective, conductive, chemically stable, inherently catalytic coating that stabilizes many efficient and technologically important

  20. Degradation Mechanisms of Urea Selective Catalytic Reduction Technology |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep_02_peden.pdf More Documents & Publications Degradation Mechanisms of Urea Selective Catalytic Reduction Technology Degradation Mechanisms of Urea Selective Catalytic Reduction Technology Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials

  1. Sustainable recycling of municipal solid waste in developing countries

    SciTech Connect (OSTI)

    Troschinetz, Alexis M. Mihelcic, James R.

    2009-02-15

    This research focuses on recycling in developing countries as one form of sustainable municipal solid waste management (MSWM). Twenty-three case studies provided municipal solid waste (MSW) generation and recovery rates and composition for compilation and assessment. The average MSW generation rate was 0.77 kg/person/day, with recovery rates from 5-40%. The waste streams of 19 of these case studies consisted of 0-70% recyclables and 17-80% organics. Qualitative analysis of all 23 case studies identified barriers or incentives to recycling, which resulted in the development of factors influencing recycling of MSW in developing countries. The factors are government policy, government finances, waste characterization, waste collection and segregation, household education, household economics, MSWM (municipal solid waste management) administration, MSWM personnel education, MSWM plan, local recycled-material market, technological and human resources, and land availability. Necessary and beneficial relationships drawn among these factors revealed the collaborative nature of sustainable MSWM. The functionality of the factor relationships greatly influenced the success of sustainable MSWM. A correlation existed between stakeholder involvement and the three dimensions of sustainability: environment, society, and economy. The only factors driven by all three dimensions (waste collection and segregation, MSWM plan, and local recycled-material market) were those requiring the greatest collaboration with other factors.

  2. An economic analysis of a light and heavy water moderated reactor synergy: burning americium using recycled uranium

    SciTech Connect (OSTI)

    Wojtaszek, D.; Edwards, G.

    2013-07-01

    An economic analysis is presented for a proposed synergistic system between 2 nuclear utilities, one operating light water reactors (LWR) and another running a fleet of heavy water moderated reactors (HWR). Americium is partitioned from LWR spent nuclear fuel (SNF) to be transmuted in HWRs, with a consequent averted disposal cost to the LWR operator. In return, reprocessed uranium (RU) is supplied to the HWRs in sufficient quantities to support their operation both as power generators and americium burners. Two simplifying assumptions have been made. First, the economic value of RU is a linear function of the cost of fresh natural uranium (NU), and secondly, plutonium recycling for a third utility running a mixed oxide (MOX) fuelled reactor fleet has been already taking place, so that the extra cost of americium recycling is manageable. We conclude that, in order for this scenario to be economically attractive to the LWR operator, the averted disposal cost due to partitioning americium from LWR spent fuel must exceed 214 dollars per kg, comparable to estimates of the permanent disposal cost of the high level waste (HLW) from reprocessing spent LWR fuel. (authors)

  3. In-Situ Catalytic Fast Pyrolysis Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified. In-Situ Catalytic Fast Pyrolysis Technology Pathway...

  4. New Catalytic Approach Builds Molecules with Specific Functionality...

    Office of Science (SC) Website

    The Center for Catalytic Hydrocarbon Functionalization (CCHF), a DOE funded Energy Frontier Research Center, is developing efficient catalysts for conversion of hydrocarbons into ...

  5. Passive Catalytic Approach to Low Temperature NOx Emission Abatement

    Broader source: Energy.gov [DOE]

    Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle

  6. Piloted rich-catalytic lean-burn hybrid combustor

    DOE Patents [OSTI]

    Newburry, Donald Maurice

    2002-01-01

    A catalytic combustor assembly which includes, an air source, a fuel delivery means, a catalytic reactor assembly, a mixing chamber, and a means for igniting a fuel/air mixture. The catalytic reactor assembly is in fluid communication with the air source and fuel delivery means and has a fuel/air plenum which is coated with a catalytic material. The fuel/air plenum has cooling air conduits passing therethrough which have an upstream end. The upstream end of the cooling conduits is in fluid communication with the air source but not the fuel delivery means.

  7. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Office of Scientific and Technical Information (OSTI)

    Technical barriers and key research needs that should be pursued for the catalytic ... Country of Publication: United States Language: English Subject: 09 BIOMASS FUELS; 59 ...

  8. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to develop a unique, fuel-flexible catalytic combustor capable of enabling ultra-low emission, lean premixed combustion of a wide range of gaseous opportunity fuels. Fact...

  9. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, George E.; Merritt, Bernard T.; Hsiao, Mark C.; Wallman, P. Henrik; Penetrante, Bernardino M.

    1999-01-01

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO.sub.x reduction in oxygen-rich vehicle engine exhausts.

  10. Hydrogen-assisted catalytic ignition characteristics of different fuels

    SciTech Connect (OSTI)

    Zhong, Bei-Jing; Yang, Fan; Yang, Qing-Tao

    2010-10-15

    Hydrogen-assisted catalytic ignition characteristics of methane (CH{sub 4}), n-butane (n-C{sub 4}H{sub 10}) and dimethyl ether (DME) were studied experimentally in a Pt-coated monolith catalytic reactor. It is concluded that DME has the lowest catalytic ignition temperature and the least required H{sub 2} flow, while CH{sub 4} has the highest catalytic ignition temperature and the highest required H{sub 2} flow among the three fuels. (author)

  11. Covalent Organic Frameworks Comprising Cobalt Porphyrins for Catalytic CO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduction | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Covalent Organic Frameworks Comprising Cobalt Porphyrins for Catalytic CO2 Reduction

  12. Chemistry, phase formation, and catalytic activity of thinpalladium...

    Office of Scientific and Technical Information (OSTI)

    Title: Chemistry, phase formation, and catalytic activity of thin palladium-containing oxide films synthesized by plasma-assisted physical vapor deposition The chemistry, ...

  13. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... The off- gas composition should also be better characterized to verify its suitability as a hydrogen plant feedstock. * Establish optimum catalytic pyrolysis oil properties. A key ...

  14. DFT Investigation of the Catalytic Hydromethylation ofalpha-Olefins...

    Office of Scientific and Technical Information (OSTI)

    DFT Investigation of the Catalytic Hydromethylation ofalpha-Olefins bvy Metallocenes. 1. Difference betrween Scandium andLutetium in Propene Hydromethylation Citation Details ...

  15. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  16. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Next Generation Manufacturing Processes project to develop a unique, fuel-flexible catalytic combustor capable of enabling ultra-low emission, lean premixed combustion of a ...

  17. Catalytic reactor for low-Btu fuels

    DOE Patents [OSTI]

    Smith, Lance; Etemad, Shahrokh; Karim, Hasan; Pfefferle, William C.

    2009-04-21

    An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

  18. Recyclability assessment of nano-reinforced plastic packaging

    SciTech Connect (OSTI)

    Sánchez, C.; Hortal, M.; Aliaga, C.; Devis, A.; Cloquell-Ballester, V.A.

    2014-12-15

    Highlights: • The study compares the recyclability of polymers with and without nanoparticles. • Visual appearance, material quality and mechanical properties are evaluated. • Minor variations in mechanical properties in R-PE and R-PP with nanoparticles. • Slight degradation of R-PET which affect mechanical properties. • Colour deviations in recycled PE, PP and PET in ranges higher that 0.3 units. - Abstract: Packaging is expected to become the leading application for nano-composites by 2020 due to the great advantages on mechanical and active properties achieved with these substances. As novel materials, and although there are some current applications in the market, there is still unknown areas under development. One key issue to be addressed is to know more about the implications of the nano-composite packaging materials once they become waste. The present study evaluates the extrusion process of four nanomaterials (Layered silicate modified nanoclay (Nanoclay1), Calcium Carbonate (CaCO{sub 3}), Silver (Ag) and Zinc Oxide (ZnO) as part of different virgin polymer matrices of polyethylene (PE), Polypropylene (PP) and Polyethyleneterephtalate (PET). Thus, the following film plastic materials: (PE–Nanoclay1, PE–CaCO{sub 3}, PP–Ag, PET–ZnO, PET–Ag, PET–Nanoclay1) have been processed considering different recycling scenarios. Results on recyclability show that for PE and PP, in general terms and except for some minor variations in yellowness index, tensile modulus, tensile strength and tear strength (PE with Nanoclay1, PP with Ag), the introduction of nanomaterial in the recycling streams for plastic films does not affect the final recycled plastic material in terms of mechanical properties and material quality compared to conventional recycled plastic. Regarding PET, results show that the increasing addition of nanomaterial into the recycled PET matrix (especially PET–Ag) could influence important properties of the recycled material, due to a slight degradation of the polymer, such as increasing pinholes, degradation fumes and elongation at break. Moreover, it should be noted that colour deviations were visible in most of the samples (PE, PP and PET) in levels higher than 0.3 units (limit perceivable by the human eye). The acceptance of these changes in the properties of recycled PE, PP and PET will depend on the specific applications considered (e.g. packaging applications are more strict in material quality that urban furniture or construction products)

  19. Make the most of catalytic hydrogenations

    SciTech Connect (OSTI)

    Landert, J.P.; Scubla, T. [Biazzi S.A., Chailly-Montreux (Switzerland)

    1995-03-01

    Liquid-phase catalytic hydrogenation is one of the most useful and versatile reactions available for organic synthesis. Because it is environmentally clean, it has replaced other reduction processes, such as the Bechamp reaction, and zinc and sulfide reductions. Moreover, the economics are favorable, provided that raw materials free of catalyst poisons are used. The hydrogenation reaction is very selective with appropriate catalysts and can often be carried out without a solvent. Applications include reduction of unsaturated carbon compounds to saturated derivatives (for example, in vegetable-oil processing), carbonyl compounds to alcohols (such as sorbitol), and nitrocompounds to amines. the reactions are usually run in batch reactors to rapidly reach complete conversion and allow quick change-over of products. The paper describes the basics of hydrogenation; steering clear of process hazards; scale-up and optimization; and system design in practice.

  20. Catalytic cartridge SO.sub.3 decomposer

    DOE Patents [OSTI]

    Galloway, Terry R. (Berkeley, CA)

    1982-01-01

    A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO.sub.3 decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO.sub.3 gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO.sub.3 gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety.

  1. Catalytic cartridge SO.sub.3 decomposer

    DOE Patents [OSTI]

    Galloway, Terry R. (Berkeley, CA)

    1982-01-01

    A catalytic cartridge internally heated is utilized as a SO.sub.3 decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO.sub.3 gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube being internally heated. In the axial-flow cartridge, SO.sub.3 gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and being internally heated. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety.

  2. Biofuel from fast pyrolysis and catalytic hydrodeoxygenation.

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2015-09-04

    This review addresses recent developments in biomass fast pyrolysis bio-oil upgrading by catalytic hydrotreating. The research in the field has expanded dramatically in the past few years with numerous new research groups entering the field while existing efforts from others expand. The issues revolve around the catalyst formulation and operating conditions. Much work in batch reactor tests with precious metal catalysts needs further validation to verify long-term operability in continuous flow systems. The effect of the low level of sulfur in bio-oil needs more study to be better understood. Utilization of the upgraded bio-oil for feedstock to finished fuels is still in an early stage of understanding.

  3. Catalytic cartridge SO/sub 3/ decomposer

    DOE Patents [OSTI]

    Galloway, T.R.

    1980-11-18

    A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO/sub 3/ decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO/sub 3/ gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO/sub 3/ gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety. A fusion reactor may be used as the heat source.

  4. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  5. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M.

    1984-01-01

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  6. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M.

    1985-01-01

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  7. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  8. Global recycling services for short and long term risk reduction

    SciTech Connect (OSTI)

    Arslan, M.; Grygiel, J.M.; Drevon, C.; Lelievre, F.; Lesage, M.; Vincent, O.

    2013-07-01

    New schemes are being developed by AREVA in order to provide global solutions for safe and non-proliferating management of used fuels, thereby significantly contributing to overall risks reduction and sustainable nuclear development. Utilities are thereby provided with a service through which they will be able to send their used fuels and only get returned vitrified and compacted waste, the only waste remaining after reprocessing. This waste is stable, standard and has demonstrated capability for very long term interim storage. They are provided as well with associated facilities and all necessary services for storage in a demonstrated safely manner. Recycled fuels, in particular MOX, would be used either in existing LWRs or in a very limited number of full MOX reactors (like the EPR reactor), located in selected countries, that will recycle MOX so as to downgrade the isotopic quality of the Pu inventories in a significant manner. Reprocessed uranium also can be recycled. These schemes, on top of offering demonstrated operational advantages and a responsible approach, result into optimized economics for all shareholders of the scheme, as part of reactor financing (under Opex or Capex form) will be secured thanks to the value of the recycled flows. It also increases fuel cost predictability as recycled fuel is not subject to market fluctuations as much and allows, in a limited span of time, for clear risk mitigation. (authors)

  9. Particle and recycling control in translation, confinement, and sustainment upgrade

    SciTech Connect (OSTI)

    Grossnickle, J. A.; Vlases, G. C.; Hoffman, A. L.; Melnik, P. A.; Milroy, R. D.; Tankut, A.; Velas, K. M.

    2010-03-15

    Previous work in the translation, confinement, and sustainment upgrade (TCSU) device [H. Y. Guo et al., Phys. Plasmas 15, 056101 (2008)] demonstrated improved plasma parameters; higher temperature, higher poloidal magnetic field, increased current drive, and increased energy confinement, for rotating magnetic field (RMF) driven field reversed configurations (FRC) relative to the earlier TCS device. This was accomplished by improving vacuum conditions and using moderate wall heating (approx100 deg. C) and glow discharge cleaning for wall conditioning. Two new wall conditioning techniques, siliconization and titanium gettering, have been employed to further reduce impurities and control recycling. Both techniques reduced oxygen line radiation by an order of magnitude, and total radiated power by 50%, but led to little change in overall FRC performance, reinforcing the earlier conclusion that TCSU FRCs are not radiation dominated. Titanium gettering substantially reduced deuterium recycling, requiring a new method of fueling to be developed. This is the first time a FRC has been operated without using wall recycling as the primary method of fueling. The low-recycling FRCs, maintained by enhanced puff fueling, performed similarly to standard recycling fueled FRCs in terms of a key current drive parameter B{sub e}/B{sub o}mega, the ratio of maximum sustained poloidal field to applied RMF field, but better density control allowed for higher temperatures.

  10. Simulation of catalytic oxidation and selective catalytic NOx reduction in lean-exhaust hybrid vehicles

    SciTech Connect (OSTI)

    Gao, Zhiming; Daw, C Stuart; Chakravarthy, Veerathu K

    2012-01-01

    We utilize physically-based models for diesel exhaust catalytic oxidation and urea-based selective catalytic NOx reduction to study their impact on drive cycle performance of hypothetical light-duty diesel powered hybrid vehicles. The models have been implemented as highly flexible SIMULINK block modules that can be used to study multiple engine-aftertreatment system configurations. The parameters of the NOx reduction model have been adjusted to reflect the characteristics of Cu-zeolite catalysts, which are of widespread current interest. We demonstrate application of these models using the Powertrain System Analysis Toolkit (PSAT) software for vehicle simulations, along with a previously published methodology that accounts for emissions and temperature transients in the engine exhaust. Our results illustrate the potential impact of DOC and SCR interactions for lean hybrid electric and plug-in hybrid electric vehicles.

  11. Think Again! A Fresh Look at Home Performance Business Models and Service

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Offerings (301) | Department of Energy Think Again! A Fresh Look at Home Performance Business Models and Service Offerings (301) Think Again! A Fresh Look at Home Performance Business Models and Service Offerings (301) Better Buildings Residential Network Peer Exchange Call Series: Think Again! A Fresh Look at Home Performance Business Models and Service Offerings (301), call slides and discussion summary. PDF icon Call Slides and Discussion Summary More Documents & Publications The

  12. Recycled materials in geotechnical applications. Geotechnical special publication No. 79

    SciTech Connect (OSTI)

    Vipulanandan, C.; Elton, D.J.

    1998-07-01

    Recycled materials have the potential for use in a variety of geotechnical and geoenvironmental applications. This proceedings contains 15 papers on field applications and laboratory testing related to recycled materials. Papers cover: geotechnics of industrial by-products; paper mill sludge for landfill cover; mitigation of void development under bridge approach slabs using rubber tire chips; tire shreds as lightweight fill for embankments and retaining walls; performance of a highway embankment and hydraulic barriers constructed using waste foundry sand, and recycled materials; lagoon-stored lime for embankment; construction and demolition debris for base and subbase applications; fly ash for fill, pavement, earth structures and aggregate; compaction of contaminated soils-reuse as a road base material; and database on beneficial reuse of foundry by-products; and more.

  13. Industrial recycling of glass, plastic and wood materials

    SciTech Connect (OSTI)

    Caccavo, F.N.; Posusney, J.R.

    1998-12-31

    The intent of this paper is to discuss in detail the development and implementation of a recycling program encompassing these three residual waste streams at a major plant site of a large United States company. The paper will review the history of the program`s development, the vendor selection and recycling processes, the initial efforts to include failures and successes, and the cost recovery and profit that can be realized through a well-managed recycling program. The facility that is the subject of this paper is located approximately 20 lies north west of Philadelphia, Pa and supports a site population of over 6,200 employees working in three divisions of the parent company. The primary business of this firm is the manufacture, distribution, and sale of pharmaceutical drugs. This plant is the company`s largest facility engaging its employees in predominantly research and manufacturing operations. The manufacturing operations being the largest division encompassing the widest range of activities from the receipt of raw material through packaging and shipping operations. This site and the company it represents enjoy an excellent relationship within the community stemming in part to the commitment to environmental stewardship demonstrated by this successful program. The site retains its own internal waste management and disposal operations for the wide variety of refuse materials generated and it is this department which is responsible for the creation and maintenance of the site`s extensive recycling effort. The paper will review the ongoing development of these elements of this company`s growing recycling operations and attempt to demonstrate that extensive recycling can be both a productive and cost effective alternative to conventional disposal through incineration`s or landfill.

  14. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro; Passarini, Fabrizio; Vassura, Ivano; Serrano, David; Dufour, Javier

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  15. Dynamic Systems Analysis Report for Nuclear Fuel Recycle

    SciTech Connect (OSTI)

    Brent Dixon; Sonny Kim; David Shropshire; Steven Piet; Gretchen Matthern; Bill Halsey

    2008-12-01

    This report examines the time-dependent dynamics of transitioning from the current United States (U.S.) nuclear fuel cycle where used nuclear fuel is disposed in a repository to a closed fuel cycle where the used fuel is recycled and only fission products and waste are disposed. The report is intended to help inform policy developers, decision makers, and program managers of system-level options and constraints as they guide the formulation and implementation of advanced fuel cycle development and demonstration efforts and move toward deployment of nuclear fuel recycling infrastructure.

  16. Energy Return on Investment from Recycling Nuclear Fuel

    SciTech Connect (OSTI)

    2011-08-17

    This report presents an evaluation of the Energy Return on Investment (EROI) from recycling an initial batch of 800 t/y of used nuclear fuel (UNF) through a Recycle Center under a number of different fuel cycle scenarios. The study assumed that apart from the original 800 t of UNF only depleted uranium was available as a feed. Therefore for each subsequent scenario only fuel that was derived from the previous fuel cycle scenario was considered. The scenarios represent a good cross section of the options available and the results contained in this paper and associated appendices will allow for other fuel cycle options to be considered.

  17. Ideal solar cell equation in the presence of photon recycling

    SciTech Connect (OSTI)

    Lan, Dongchen Green, Martin A.

    2014-11-07

    Previous derivations of the ideal solar cell equation based on Shockley's p-n junction diode theory implicitly assume negligible effects of photon recycling. This paper derives the equation in the presence of photon recycling that modifies the values of dark saturation and light-generated currents, using an approach applicable to arbitrary three-dimensional geometries with arbitrary doping profile and variable band gap. The work also corrects an error in previous work and proves the validity of the reciprocity theorem for charge collection in such a more general case with the previously neglected junction depletion region included.

  18. A fresh look at coal-derived liquid fuels

    SciTech Connect (OSTI)

    Paul, A.D.

    2009-01-15

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  19. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P

    2012-09-18

    A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

  20. The role of ice nuclei recycling in the maintenance of cloud...

    Office of Scientific and Technical Information (OSTI)

    The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase stratocumulus Citation Details In-Document Search Title: The role of ice nuclei recycling in ...

  1. Fact #763: January 21, 2013 Eighty-four Percent of Scrapped Tires Are Recycled

    Broader source: Energy.gov [DOE]

    There were 263 million tires scrapped in 2009 (latest available data) which amounts to more than 4.7 million tons of waste. Fortunately, 84% of that waste was recycled. Most of the recycled tires...

  2. Fresh Water Generation from Aquifer-Pressured Carbon Storage

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Bourcier, W L; Wolfe, T; Haussmann, C

    2010-02-19

    Can we use the pressure associated with sequestration to make brine into fresh water? This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). Possible products are: Drinking water, Cooling water, and Extra aquifer space for CO{sub 2} storage. The conclusions are: (1) Many saline formation waters appear to be amenable to largely conventional RO treatment; (2) Thermodynamic modeling indicates that osmotic pressure is more limiting on water recovery than mineral scaling; (3) The use of thermodynamic modeling with Pitzer's equations (or Extended UNIQUAC) allows accurate estimation of osmotic pressure limits; (4) A general categorization of treatment feasibility is based on TDS has been proposed, in which brines with 10,000-85,000 mg/L are the most attractive targets; (5) Brines in this TDS range appear to be abundant (geographically and with depth) and could be targeted in planning future CCS operations (including site selection and choice of injection formation); and (6) The estimated cost of treating waters in the 10,000-85,000 mg/L TDS range is about half that for conventional seawater desalination, due to the anticipated pressure recovery.

  3. Catalytic Reactor For Oxidizing Mercury Vapor

    DOE Patents [OSTI]

    Helfritch, Dennis J.

    1998-07-28

    A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

  4. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christopher P; Boldingh, Edwin P

    2014-10-07

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  5. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christpher P; Boldingh, Edwin P

    2013-12-17

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  6. Process for gasifying carbonaceous material from a recycled condensate slurry

    DOE Patents [OSTI]

    Forney, Albert J.; Haynes, William P.

    1981-01-01

    Coal or other carbonaceous material is gasified by reaction with steam and oxygen in a manner to minimize the problems of effluent water stream disposal. The condensate water from the product gas is recycled to slurry the coal feed and the amount of additional water or steam added for cooling or heating is minimized and preferably kept to a level of about that required to react with the carbonaceous material in the gasification reaction. The gasification is performed in a pressurized fluidized bed with the coal fed in a water slurry and preheated or vaporized by indirect heat exchange contact with product gas and recycled steam. The carbonaceous material is conveyed in a gas-solid mixture from bottom to top of the pressurized fluidized bed gasifier with the solids removed from the product gas and recycled steam in a supported moving bed filter of the resulting carbonaceous char. Steam is condensed from the product gas and the condensate recycled to form a slurry with the feed coal carbonaceous particles.

  7. EA-1919: Recycle of Scrap Metals Originating from Radiological Areas

    Broader source: Energy.gov [DOE]

    This Programmatic EA evaluates alternatives for the management of scrap metal originating from DOE radiological control areas, including the proposed action to allow for the recycle of uncontaminated scrap metal that meets the requirements of DOE Order 458.1. (Metals with volumetric radioactive contamination are not included in the scope of this Programmatic EA.)

  8. The recycling of the coal fly ash in glass production

    SciTech Connect (OSTI)

    Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A.

    2006-09-15

    The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

  9. Fermilab Recycler Ring: Technical design report. Revision 1.1

    SciTech Connect (OSTI)

    Jackson, G.

    1996-07-01

    This report describes the technical design of the Fermilab Recycler Ring. The purpose of the Recycler is to augment the luminosity increase anticipated from the implementation of the Fermi III upgrade project, which has as its main component the Fermilab Main Injector construction project. The Recycler is a fixed 8 GeV kinetic energy storage ring. It is located in the Main Injector tunnel directly above the Main Injector beamline, near the ceiling. The construction schedule calls for the installation of the Recycler ring before the installation shutdown of the Main Injector. This aggressive construction schedule is made possible by the exclusive use of permanent magnets in the ring lattice, removing the need for expensive conventional iron/copper magnet construction along with the related power supplies, cooling water system, and electrical safety systems. The location, operating energy, and mode of construction are chosen to minimize operational impacts on both Fermilab`s ongoing High Energy Physics program and the Main Injector construction project.

  10. A Research Needs Assessment for waste plastics recycling: Volume 2, Project report. Final report

    SciTech Connect (OSTI)

    1994-12-01

    This second volume contains detailed information on a number of specific topics relevant to the recovery/recycling of plastics.

  11. Fractionation and Catalytic Upgrading of Bio-Oil Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office (BETO) 2015 Project Peer Review Fractionation and Catalytic Upgrading of Bio-Oil FY13 DE-FOA-000 CHASE March 2015 Technology Area Review PI: Daniel E. Resasco - co-PI: ...

  12. Bio-oil Quality Improvement and Catalytic Hydrotreating of Bio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2.3.1.302 Bio-oil Quality Improvement and Catalytic Hydrotreating of Bio-oils - PNNL March 24, 2015 Conversion R & D PI: Alan Zacher Presenter: Mariefel V. Olarte Pacific ...

  13. Printing 3D Catalytic Devices | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Printing 3D Catalytic Devices An error occurred. Try watching this video on www.youtube.com, or enable JavaScript if it is disabled in your browser. Ames Laboratory scientist Igor...

  14. Hydrogen permeable protective coating for a catalytic surface

    DOE Patents [OSTI]

    Liu, Ping; Tracy, C. Edwin; Pitts, J. Roland; Lee, Se-Hee

    2007-06-19

    A protective coating for a surface comprising a layer permeable to hydrogen, said coating being deposited on a catalyst layer; wherein the catalytic activity of the catalyst layer is preserved.

  15. Control of Substrate Access to the Active Site and Catalytic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control of Substrate Access to the Active Site and Catalytic Mechanism of Methane and Toluene Monooxygenases Friday, June 22, 2012 - 3:30pm SSRL Main Conference Room 137-322 Prof....

  16. Demo of below ground site that once held the Plutonium Recycle Test Reactor

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at Hanford | Department of Energy Demo of below ground site that once held the Plutonium Recycle Test Reactor at Hanford Demo of below ground site that once held the Plutonium Recycle Test Reactor at Hanford Addthis Description Demo of below ground site that once held the Plutonium Recycle Test Reactor at Hanford

  17. Cold bond agglomeration of waste oxides for recycling

    SciTech Connect (OSTI)

    D`Alessio, G.; Lu, W.K.

    1996-12-31

    Recycling of waste oxides has been an on-going challenge for integrated steel plants. The majority of these waste oxides are collected from the cleaning systems of ironmaking and steelmaking processes, and are usually in the form of fine particulates and slurries. In most cases, these waste materials are contaminated by oils and heavy metals and often require treatment at a considerable expense prior to landfill disposal. This contamination also limits the re-use or recycling potential of these oxides as secondary resources of reliable quality. However, recycling of some selected wastes in blast furnaces or steelmaking vessels is possible, but first requires agglomeration of the fine particulate by such methods as cold bond briquetting. Cold bond briquetting technology provides both mechanical compacting and bonding (with appropriate binders) of the particulates. This method of recycling has the potential to be economically viable and environmentally sustainable. The nature of the present study is cold bond briquetting of iron ore pellet fines with a molasses-cement-H{sub 2}O binder for recycling in a blast furnace. The inclusion of molasses is for its contribution to the green strength of briquettes. During the curing stage, significant gains in strength may be credited to molasses in the presence of cement. The interactions of cement (and its substitutes), water and molasses and their effects on the properties of the agglomerates during and after various curing conditions were investigated. Tensile strengths of briquettes made in the laboratory and subjected to experimental conditions which simulated the top part of a blast furnace shaft were also examined.

  18. Analysis of nuclear proliferation resistance reprocessing and recycling technologies

    SciTech Connect (OSTI)

    Patricia Paviet-Hartmann; Gary Cerefice; Marcela Stacey; Steven Bakhtiar

    2011-05-01

    The PUREX process has been progressively and continuously improved during the past three decades, and these improvements account for successful commercialization of reprocessing in a few countries. The renewed interest in nuclear energy and the international growth of nuclear electricity generation do not equate – and should not be equated -with increasing proliferation risks. Indeed, the nuclear renaissance presents a unique opportunity to enhance the culture of non-proliferation. With the recent revival of interest in nuclear technology, technical methods for prevention of nuclear proliferation are being revisited. Robust strategies to develop new advanced separation technologies are emerging worldwide for sustainability and advancement of nuclear energy with enhanced proliferation resistance. On the other hand, at this moment, there are no proliferation resistance advanced technologies. . Until now proliferation resistance as it applies to reprocessing has been focused on not separating a pure stream of weapons-usable plutonium. France, as an example, has proposed a variant of the PUREX process, the COEX TM process, which does not result on a pure plutonium product stream. A further step is to implement a process based on group extraction of actinides and fission products associated with a homogeneous recycling strategy (UNEX process in the US, GANEX process in France). Such scheme will most likely not be deployable on an industrial scale before 2030 or so because it requires intensive R&D and robust flowsheets. Finally, future generation recycling schemes will handle the used nuclear fuel in fast neutron reactors. This means that the plutonium throughput of the recycling process may increase. The need is obvious for advanced aqueous recycling technologies that are intrinsically more proliferation resistant than the commercial PUREX process. In this paper, we review the actual PUREX process along with the advanced recycling technologies that will enhance technical barriers, making plutonium diversion more difficult by not isolating plutonium or/and coexistence of fission products with plutonium.

  19. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of

    Office of Scientific and Technical Information (OSTI)

    mixed polymer waste streams to sequentially recover monomers or other high value products (Patent) | SciTech Connect Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products Citation Details In-Document Search Title: Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products A process of

  20. DFT Investigation of the Catalytic Hydromethylation ofalpha-Olefins bvy

    Office of Scientific and Technical Information (OSTI)

    Metallocenes. 1. Difference betrween Scandium andLutetium in Propene Hydromethylation (Journal Article) | SciTech Connect DFT Investigation of the Catalytic Hydromethylation ofalpha-Olefins bvy Metallocenes. 1. Difference betrween Scandium andLutetium in Propene Hydromethylation Citation Details In-Document Search Title: DFT Investigation of the Catalytic Hydromethylation ofalpha-Olefins bvy Metallocenes. 1. Difference betrween Scandium andLutetium in Propene Hydromethylation A DFT study of

  1. Catalytic Conversion of Bioethanol to Hydrocarbons - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Vehicles and Fuels Vehicles and Fuels Startup America Startup America Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Catalytic Conversion of Bioethanol to Hydrocarbons Oak Ridge National Laboratory Contact ORNL About This Technology Publications: PDF Document Publication 11-G00219_ID2414.pdf (629 KB) Technology Marketing SummaryA method for catalytically converting an alcohol to a hydrocarbon without requiring

  2. Northwestern University Facility for Clean Catalytic Process Research

    SciTech Connect (OSTI)

    Marks, Tobin Jay

    2013-05-08

    Northwestern University with DOE support created a Facility for Clean Catalytic Process Research. This facility is designed to further strengthen our already strong catalysis research capabilities and thus to address these National challenges. Thus, state-of-the art instrumentation and experimentation facility was commissioned to add far greater breadth, depth, and throughput to our ability to invent, test, and understand catalysts and catalytic processes, hence to improve them via knowledge-based design and evaluation approaches.

  3. Reactive and Catalytic Air Purification Materials - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Building Energy Efficiency Building Energy Efficiency Advanced Materials Advanced Materials Find More Like This Return to Search Reactive and Catalytic Air Purification Materials Naval Research Laboratory Contact NRL About This Technology Publications: PDF Document Publication AirPurification (546 KB) Technology Marketing SummarySorbents for the removal of toxic in-dustrial gases such as ammonia and phosgene. The materials offer reactive and/or catalytic sites within a high surface

  4. Briefly Bound to Activate: Transient Binding of a Second Catalytic

    Office of Scientific and Technical Information (OSTI)

    Magnesium Activates the Structure and Dynamics of CDK2 Kinase for Catalysis (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Briefly Bound to Activate: Transient Binding of a Second Catalytic Magnesium Activates the Structure and Dynamics of CDK2 Kinase for Catalysis Citation Details In-Document Search Title: Briefly Bound to Activate: Transient Binding of a Second Catalytic Magnesium Activates the Structure and Dynamics of CDK2 Kinase for Catalysis We have

  5. Bifunctional Catalysts for the Selective Catalytic Reduction of NO by

    Broader source: Energy.gov (indexed) [DOE]

    Hydrocarbons | Department of Energy 3 DEER Conference Presentation: Argonne National Laboratory PDF icon 2003_deer_marshall.pdf More Documents & Publications Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems

  6. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Broader source: Energy.gov (indexed) [DOE]

    Reduction Materials | Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_25_peden.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and

  7. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M.; Vogtlin, George E.; Merritt, Bernard T.; Brusasco, Raymond M.

    2000-01-01

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  8. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M.; Vogtlin, George E.; Merritt, Bernard T.; Brusasco, Raymond M.

    2002-01-01

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  9. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2001-06-01

    Disposal of high-level nuclear waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  10. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2000-06-01

    Disposal of high- level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid- liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  11. Economic Feasibility of Electrochemical Caustic Recycling at the Hanford Site

    SciTech Connect (OSTI)

    Poloski, Adam P.; Kurath, Dean E.; Holton, Langdon K.; Sevigny, Gary J.; Fountain, Matthew S.

    2009-03-01

    This report contains a review of potential cost benefits of NaSICON Ceramic membranes for the separation of sodium from Hanford tank waste. The primary application is for caustic recycle to the Waste Treatment and Immobilization Plant (WTP) pretreatment leaching operation. The report includes a description of the waste, the benefits and costs for a caustic-recycle facility, and Monte Carlo results obtained from a model of these costs and benefits. The use of existing cost information has been limited to publicly available sources. This study is intended to be an initial evaluation of the economic feasibility of a caustic recycle facility based on NaSICON technology. The current pretreatment flowsheet indicates that approximately 6,500 metric tons (MT) of Na will be added to the tank waste, primarily for removing Al from the high-level waste (HLW) sludge (Kirkbride et al. 2007). An assessment (Alexander et al. 2004) of the pretreatment flowsheet, equilibrium chemistry, and laboratory results indicates that the quantity of Na required for sludge leaching will increase by 6,000 to 12,000 MT in order to dissolve sufficient Al from the tank-waste sludge material to maintain the number of HLW canisters produced at 9,400 canisters as defined in the Office of River Protection (ORP) System Plan (Certa 2003). This additional Na will significantly increase the volume of LAW glass and extend the processing time of the Waste Treatment and Immobilization Plant (WTP). Future estimates on sodium requirements for caustic leaching are expected to significantly exceed the 12,000-MT value and approach 40,000-MT of total sodium addition for leaching (Gilbert, 2007). The cost benefit for caustic recycling is assumed to consist of four major contributions: 1) the cost savings realized by not producing additional immobilized low-activity waste (ILAW) glass, 2) caustic recycle capital investment, 3) caustic recycle operating and maintenance costs, and 4) research and technology costs needed to deploy the technology. In estimating costs for each of these components, several parameters are used as inputs. Due to uncertainty in assuming a singular value for each of these parameters, a range of possible values is assumed. A Monte Carlo simulation is then performed where the range of these parameters is exercised, and the resulting range of cost benefits is determined.

  12. Recycling in public housing: The Syracuse Housing Authority

    SciTech Connect (OSTI)

    Foote, K.C.; DeVoe, J.F.

    1997-01-01

    The mission of the Syracuse Housing Authority (SHA, Syracuse, N.Y.) is to provide clean, safe, and affordable housing for low-income citizens of the city of Syracuse. In doing so, it has worked to be innovative. SHA owns and manages 12 federally funded housing developments and one New York state-funded project, in addition to managing two buildings owned by the city. After nearly 60 years of success in providing affordable housing in the Syracuse area, the pioneering SHA took on another daunting mission in the 1990s: modernization of waste collection and recycling. By the beginning of 1990, SHA was facing two mandates: to initiate a recycling program by July 1, as mandated by Onondaga County law, and to reduce its trash bill significantly.

  13. One million served: Rhode Island`s recycling facility

    SciTech Connect (OSTI)

    Malloy, M.G.

    1997-11-01

    Rhode Island`s landfill and adjacent materials recovery facility (MRF) in Johnston, both owned by the quasi-public Rhode Island Resource Recovery Corp. (RIRRC, Johnston), serve the entire state. The $12-million recycling facility was built in 1989 next to the state`s sole landfill, the Central Landfill, which accepts only in-state trash. The MRF is operated for RIRRC by New England CRInc. (Hampton, N.H.), a unit of Waste Management, Inc. (WMI, Oak Brook, Ill.). It handles a wide variety of materials, from the usual newspaper, cardboard, and mixed containers to new streams such as wood waste, scrap metal, aseptic packaging (milk and juice boxes), and even textiles. State municipalities are in the process of adding many of these new recyclable streams into their curbside collection programs, all of which feed the facility.

  14. A Novel Charge Recycling Approach to Low-Power

    SciTech Connect (OSTI)

    Ulaganathan, Chandradevi; Britton Jr, Charles L; Holleman, Jeremy; Blalock, Benjamin

    2012-01-01

    A novel charge-recycling scheme has been designed and implemented to demonstrate the feasibility of operating digital circuits using the charge scavenged from the leakage and dynamic load currents inherent to digital logic. The proposed scheme uses capacitors to efficiently recover the ground-bound charge and to subsequently boost the capacitor voltage to power up the source circuit. This recycling methodology has been implemented on a 12-bit Gray-code counter within a 12-bit multichannel Wilkinson ADC. The circuit has been designed in 0.5 m BiCMOS and in 90nm CMOS processes. SPICE simulation results reveal a 46 53% average reduction in the energy consumption of the counter. The total energy savings including the control generation aggregates to an average of 26 34%.

  15. Sandia's Algae Nutrient Recycling Project Is a Triple Win

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Algae Nutrient Recycling Project Is a Triple Win - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  16. MOxST Magnesium Recycling Concept Definition Project Final Report

    Office of Scientific and Technical Information (OSTI)

    Report Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap DOE Award Number DE-EE0003454 Project Period: August 1, 2010 - December 31, 2011 Principal Investigator: Adam C. Powell, IV (781) 898-3430 apowell@moxst.com Recipient Organization: Metal Oxygen Separation Technologies, Inc. 11 Michigan Drive, Natick, MA 01760-1334 Other Project Team Members: MOxST: Soobhankar Pati, Steve Derezinski, John Strauss Boston University: Uday Pal, Peter Zink, Xiaofei Guan

  17. Better Biomass Conversion with Recyclable GVL Solvent - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Better Biomass Conversion with Recyclable GVL Solvent Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary To recover useful carbohydrates locked in biomass, molecular bonds must be broken while avoiding further reaction of the resulting glucose and xylose sugars. This is a challenge because glucose can degrade quicker than it is produced. Fast, hot reactions try to minimize such degradation, but are impractical. Expensive catalysts

  18. Recycling of nuclear spent fuel with AIROX processing

    SciTech Connect (OSTI)

    Majumdar, D.; Jahshan, S.N.; Allison, C.M.; Kuan, P.; Thomas, T.R.

    1992-12-01

    This report examines the concept of recycling light water reactor (LWR) fuel through use of a dry-processing technique known as the AIROX (Atomics International Reduction Oxidation) process. In this concept, the volatiles and the cladding from spent LWR fuel are separated from the fuel by the AIROX process. The fuel is then reenriched and made into new fuel pins with new cladding. The feasibility of the concept is studied from a technical and high level waste minimization perspective.

  19. Model of E-Cloud Instability in the Fermilab Recycler

    SciTech Connect (OSTI)

    Balbekov, V.

    2015-06-24

    Simple model of electron cloud is developed in the paper to explain e-cloud instability of bunched proton beam in the Fermilab Recycler. The cloud is presented as an immobile snake in strong vertical magnetic field. The instability is treated as an amplification of the bunch injection errors from the batch head to its tail. Nonlinearity of the e-cloud field is taken into account. Results of calculations are compared with experimental data demonstrating good correlation.

  20. Symbiotically integrated organic recycling/renewable energy systems

    SciTech Connect (OSTI)

    Hamburg, R.A.

    1983-06-01

    Two operating systems designed for the integrated recycling of organic materials and production of renewable energy are described. Both systems include the Chinese design, water-pressure biogas digesters, a solar greenhouse and algae/aquatic plant ponds, all in passive symbiotic relationships with a minimum of high technology sophistication. A discussion of fish ponds and fuel alcohol production is also included since they offer many possibilities for expanded integration.

  1. Direct Solid-State Conversion of Recyclable Metals and Alloys

    SciTech Connect (OSTI)

    Kiran Manchiraju

    2012-03-27

    Friction Stir Extrusion (FSE) is a novel energy-efficient solid-state material synthesis and recycling technology capable of producing large quantity of bulk nano-engineered materials with tailored, mechanical, and physical properties. The novelty of FSE is that it utilizes the frictional heating and extensive plastic deformation inherent to the process to stir, consolidate, mechanically alloy, and convert the powders, chips, and other recyclable feedstock materials directly into useable product forms of highly engineered materials in a single step (see Figure 1). Fundamentally, FSE shares the same deformation and metallurgical bonding principles as in the revolutionary friction stir welding process. Being a solid-state process, FSE eliminates the energy intensive melting and solidification steps, which are necessary in the conventional metal synthesis processes. Therefore, FSE is highly energy-efficient, practically zero emissions, and economically competitive. It represents a potentially transformational and pervasive sustainable manufacturing technology for metal recycling and synthesis. The goal of this project was to develop the technological basis and demonstrate the commercial viability of FSE technology to produce the next generation highly functional electric cables for electricity delivery infrastructure (a multi-billion dollar market). Specific focus of this project was to (1) establish the process and material parameters to synthesize novel alloys such as nano-engineered materials with enhanced mechanical, physical, and/or functional properties through the unique mechanical alloying capability of FSE, (2) verifying the expected major energy, environmental, and economic benefits of FSE technology for both the early stage 'showcase' electric cable market and the anticipated pervasive future multi-market applications across several industry sectors and material systems for metal recycling and sustainable manufacturing.

  2. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  3. Choosing among alternative recycling systems: An economic analysis

    SciTech Connect (OSTI)

    Stedge, G.D. . Dept. of Agricultural and Applied Economics); Halstead, J.M. . Dept. of Resource Economics and Development)

    1994-03-01

    Due to the increasing concern over the disposal of municipal solid waste, municipalities have begun searching for ways to recycle a larger percentage to their waste stream at a reasonable cost. This report examines bag-based recycling. This system, due to its efficient collection and separation method, and its convenience, should be able to capture a larger share of the waste stream at a lower cost per metric ton than conventional recycling programs. Using a case study approach, a bag-based program is compared with a curbside-sort program and a drop-off program. Using time/motion analysis, a garbage composition study, a household survey, and the recording of set-out rates of a sample of dwelling units, the efficiency of the three programs was defined and estimated. The efficiency of the bag-based system was also estimated for three areas with distinct household densities. Although the curbside-sort program was found to divert a larger percentage of the residential waste stream than the bag-based system, the cost per metric ton of the bag-based system is so much lower that it clearly is the most efficient of the three programs. The drop-off program had a very low cost per metric ton; however, if failed to divert the minimum acceptable level of the waste stream. The bag-based system proved to be more efficient in areas with higher household densities.

  4. AISI waste oxide recycling program. Final technical report

    SciTech Connect (OSTI)

    Aukrust, E.; Downing, K.B.; Sarma, B.

    1995-08-01

    In March 1995 AISI completed a five-year, $60 million collaborative development program on Direct Steelmaking cost-shared by DOE under the Metals Initiative. This program defined an energy-efficient and environmentally-friendly technology to produce hot metal for steelmaking directly from coal and iron ore pellets without incurring the high capital costs and environmental problems associated with traditional coke oven and blast furnace technology. As it becomes necessary to replace present capacity, this new technology will be favored because of reduced capital costs, higher energy efficiency, and lower operating costs. In April 1994, having failed to move forward with a demonstration plant for direct ironmaking, despite substantial efforts by both Stelco and Geneva Steel, an alternative opportunity was sought to commercialize this new technology without waiting until existing ironmaking capacity needed to be replaced. Recycling and resource recovery of steel plant waste oxides was considered an attractive possibility. This led to approval of a ten-month, $8.3 million joint program with DOE on recycling steel plant waste oxides utilizing this new smelting technology. This highly successful trial program was completed in December 1994. The results of the pilot plant work and a feasibility study for a recycling demonstration plant are presented in this final technical report.

  5. EDI as a Treatment Module in Recycling Spent Rinse Waters

    SciTech Connect (OSTI)

    Donovan, Robert P.; Morrison, Dennis J.

    1999-08-11

    Recycling of the spent rinse water discharged from the wet benches commonly used in semiconductor processing is one tactic for responding to the targets for water usage published in the 1997 National Technology Roadmap for Semiconductors (NTRS). Not only does the NTRS list a target that dramatically reduces total water usage/unit area of silicon manufactured by the industry in the future but for the years 2003 and beyond, the NTRS actually touts goals which would have semiconductor manufacturers drawing less water from a regional water supply per unit area of silicon manufactured than the quantity of ultrapure water (UPW) used in the production of that same silicon. Achieving this latter NTRS target strongly implies more widespread recycling of spent rinse waters at semiconductor manufacturing sites. In spite of the fact that, by most metrics, spent rinse waters are of much higher purity than incoming municipal waters, recycling of these spent rinse waters back into the UPW production plant is not a simple, straightforward task. The rub is that certain of the chemicals used in semiconductor manufacturing, and thus potentially present in trace concentrations (or more) in spent rinse waters, are not found in municipal water supplies and are not necessarily removed by the conventional UPW production sequence used by semiconductor manufacturers. Some of these contaminants, unique to spent rinse waters, may actually foul the resins and membranes of the UPW system, posing a threat to UPW production and potentially even causing a shutdown.

  6. In situ recycling of contaminated soil uses bioremediation

    SciTech Connect (OSTI)

    Shevlin, P.J.; Reel, D.A.

    1996-04-01

    OxyChem Pipeline Operations, primarily an ethylene and propylene products mover, has determined that substantial savings can be realized by adopting a bioremediation maintenance and recycling approach to hydrocarbon-contaminated soil. By this method, the soil can be recycled in situ, or in containers. To implement the soil-recycling program, OxyChem elected to use a soil remediator and natural absorbent product, Oil Snapper. This field maintenance material, based on an Enhanced Urea Technology, provides a diet to stimulate the growth of hydrocarbon-eating microbes. It works well either with indigenous soil microbes or with commercial microbes. The product is carried in field vehicles, which makes it immediately available when leaks or spills are discovered. Procedure for clean-up is to apply product and mix it into affected soil. Thus the contaminant is contained, preventing further migration; the contaminant is dispersed throughout the product, making it more accessible to the microbes; nutrients are immediately available to the microbes; and the material contributes aeration and moisture-retention properties.

  7. Trash processing and recycling using the zero landfill solution

    SciTech Connect (OSTI)

    Thompson, W.J.

    1994-12-31

    Each person in the US produces approximately one ton of trash per year. The environmentally friendly municipal trash processing and recycling complex used for illustrative purposes in this paper is designed and sized to handle trash from typical municipalities ranging from 500,000 to 750,000 populations. This translates into a nominal 2,000 ton per day (TPD) facility. A typical component breakdown of municipal solid waste is shown in appendix A. The layout of the complex is shown in appendix B. Today`s municipal trash processing and recycling center should be designed to serve the needs of the municipality for at least the next 20 to 30 years. It should also be designed in such a way as to allow any new technology advancements to be added easily and in a cost effective manner to extend the useful service life of the facility almost indefinitely. 100% of the trash will be recycled. There will be no need for a dump, landfill, or disposal site at all. No curbside separation is required.

  8. Recycling at naval shore installations: One means of curbing the garbage glut. Research report, August 1992-April 1993

    SciTech Connect (OSTI)

    Phillips, R.L.

    1993-04-01

    The document provides techniques and strategies to aid Federal recycling program managers. Highlights the major laws and regulations that stimulated recycling within the Department of Defense, discusses several benefits of recycling, and addressees start-up and operating costs associated with a recycling program. Briefly examines the Navy's current recycling efforts at shore activities; and contends that the real breakthrough in effective solid waste management will only come when intense recycling is combined with reducing waste at the source, expanding the use recycled materials, and investing in better research and development.

  9. Fresh-slice double-pulses X-ray Free Electron lasers | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Description The technique of fresh-slice allows generating intense ultra-short double pulses for pump-probe experiments with control over the delay, color separation and ...

  10. Development of Recycling Compatible Pressure-Sensitive Adhesives and Coatings

    SciTech Connect (OSTI)

    Steven J. Severtson

    2010-02-15

    The objective of this project was the design of new water-based pressure-sensitive adhesive (PSA) products and coatings engineered for enhanced removal during the processing of recycled fiber. Research included the formulation, characterization, and performance measurements of new screenable coatings, testing of modified paper and board substrates and the design of test methods to characterize the inhibition of adhesive and coating fragmentation and relative removal efficiencies of developed formulations. This project was operated under the requirements that included commercially viable approaches be the focus, that findings be published in the open literature and that new strategies could not require changes in the methods and equipment used to produce PSA and PS labels or in the recycling process. The industrial partners benefited through the building of expertise in their company that they would not, and likely could not, have pursued if it had not been for the partnership. Results of research on water-based PSAs clearly identifies which PSA and paper facestock properties govern the fragmentation of the adhesive and provide multiple strategies for making (pressure-sensitive) PS labels for which the PSA is removed at very high efficiencies from recycling operations. The application of these results has led to the identification of several commercial products in Franklin International’s (industrial partner) product line that are recycling compatible. Several new formulations were also designed and are currently being scaled-up. Work on recycling compatible barrier coatings for corrugated containers examined the reinforcement of coatings using a small amount of exfoliated organically modified montmorillonite (OMMT). These OMMT/paraffin wax nanocomposites demonstrated significantly improved mechanical properties. Paraffin waxes containing clay were found to have significantly higher Young’s moduli and yield stress relative to the wax matrix, but the most impressive finding was the impact of the clay on the elongation at break; a nearly 400% increase was observed for a clay concentration of 0.5 wt.%. These coatings also demonstrate a number of other property enhancements, which make them a good candidate for continued research. Another approach explored in this research was the use of structured and self-cleaning surfaces. If the amount of coating utilized can be significantly reduced, the environmental impact is diminished.

  11. Award-winning research takes a fresh look at Geothermal Energy | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Award-winning research takes a fresh look at Geothermal Energy Award-winning research takes a fresh look at Geothermal Energy June 5, 2015 - 2:00pm Addthis Geothermal energy, traditionally a baseload power source among renewables, is poised to emerge also as a flexible power source, balancing intermittent wind and solar power production and reducing variability in energy prices. Source: NREL Geothermal energy, traditionally a baseload power source among renewables, is poised to

  12. Fresh-slice double-pulses X-ray Free Electron lasers | Stanford Synchrotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fresh Air That's as Good as Gold Fresh Air That's as Good as Gold July 8, 2013 - 5:25pm Addthis Brookhaven Lab physicists Peter Sutter, Eli Sutter,and Xiao Tong (left to right) with one of the Center for Functional Nanomaterials instruments used to characterize the new nanoparticle structures. | Photo courtesy of Brookhaven National Lab. Brookhaven Lab physicists Peter Sutter, Eli Sutter,and Xiao Tong (left to right) with one of the Center for Functional Nanomaterials instruments used to

  13. Method for measuring recovery of catalytic elements from fuel cells

    DOE Patents [OSTI]

    Shore, Lawrence; Matlin, Ramail

    2011-03-08

    A method is provided for measuring the concentration of a catalytic clement in a fuel cell powder. The method includes depositing on a porous substrate at least one layer of a powder mixture comprising the fuel cell powder and an internal standard material, ablating a sample of the powder mixture using a laser, and vaporizing the sample using an inductively coupled plasma. A normalized concentration of catalytic element in the sample is determined by quantifying the intensity of a first signal correlated to the amount of catalytic element in the sample, quantifying the intensity of a second signal correlated to the amount of internal standard material in the sample, and using a ratio of the first signal intensity to the second signal intensity to cancel out the effects of sample size.

  14. Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications

    SciTech Connect (OSTI)

    Eteman, Shahrokh

    2013-06-30

    Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL®) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL® injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

  15. New process model proves accurate in tests on catalytic reformer

    SciTech Connect (OSTI)

    Aguilar-Rodriguez, E.; Ancheyta-Juarez, J. )

    1994-07-25

    A mathematical model has been devised to represent the process that takes place in a fixed-bed, tubular, adiabatic catalytic reforming reactor. Since its development, the model has been applied to the simulation of a commercial semiregenerative reformer. The development of mass and energy balances for this reformer led to a model that predicts both concentration and temperature profiles along the reactor. A comparison of the model's results with experimental data illustrates its accuracy at predicting product profiles. Simple steps show how the model can be applied to simulate any fixed-bed catalytic reformer.

  16. Recycling produced water for algal cultivation for biofuels

    SciTech Connect (OSTI)

    Neal, Justin N.; Sullivan, Enid J.; Dean, Cynthia A.; Steichen, Seth A.

    2012-08-09

    Algal growth demands a continuous source of water of appropriate salinity and nutritional content. Fresh water sources are scarce in the deserts of the Southwestern United States, hence, salt water algae species are being investigated as a renewable biofuel source. The use of produced water from oil wells (PW) could offset the demand for fresh water in cultivation. Produced water can contain various concentrations of dissolved solids, metals and organic contaminants and often requires treatment beyond oil/water separation to make it suitable for algae cultivation. The produced water used in this study was taken from an oil well in Jal, New Mexico. An F/2-Si (minus silica) growth media commonly used to cultivate Nannochloropsis salina 1776 (NS 1776) was prepared using the produced water (F/2-Si PW) taking into account the metals and salts already present in the water. NS 1776 was seeded into a bioreactor containing 5L of the (F/2-Si PW) media. After eleven days the optical density at 750 nm (an indicator of algal growth) increased from 0 to 2.52. These results indicate algae are able to grow, though inhibited when compared with non-PW media, in the complex chemical conditions found in produced water. Savings from using nutrients present in the PW, such as P, K, and HCO{sub 3}{sup -}, results in a 44.38% cost savings over fresh water to mix the F/2-Si media.

  17. Energy Return on Investment - Fuel Recycle (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Technical Report: Energy Return on Investment - Fuel Recycle Citation Details In-Document Search Title: Energy Return on Investment - Fuel Recycle This report provides a methodology and requisite data to assess the potential Energy Return On Investment (EROI) for nuclear fuel cycle alternatives, and applies that methodology to a limited set of used fuel recycle scenarios. This paper is based on a study by Lawrence Livermore National Laboratory and a parallel evaluation by AREVA

  18. Water soluble/dispersible and easy removable cationic adhesives and coating for paper recycling

    DOE Patents [OSTI]

    Deng, Yulin; Yan, Zegui

    2005-11-29

    The present invention is an adhesive or coating composition that is dispersible or dissolvable in water, making it useful in as a coating or adhesive in paper intended for recycling. The composition of the present invention is cationically charged thereby binding with the fibers of the paper slurry and thus, resulting in reduced deposition of adhesives on equipment during the recycling process. The presence of the composition of the present invention results in stronger interfiber bonding in products produced from the recycled fibers.

  19. St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wastewater Biosolids | Department of Energy St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids Breakout Session 3A-Conversion Technologies III: Energy from Our Waste (Will we Be Rich in Fuel or Knee Deep in Trash by 2025?) St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids William Eleazer, Supervising Engineer, Brown and

  20. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Broader source: Energy.gov [DOE]

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  1. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    Broader source: Energy.gov [DOE]

    This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  2. ULTRA LOW NOx CATALYTIC COMBUSTION FOR IGCC POWER PLANTS

    SciTech Connect (OSTI)

    Lance L. Smith

    2004-03-01

    Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using PCI's two-stage (catalytic / gas-phase) combustion process for syngas fuel. In this process, the first stage is a Rich-Catalytic Lean-burn (RCL{trademark}) catalytic reactor, wherein a fuel-rich mixture contacts the catalyst and reacts while final and excess combustion air cool the catalyst. The second stage is a gas-phase combustor, wherein the catalyst cooling air mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During the reporting period, PCI successfully achieved NOx = 0.011 lbs/MMBtu at 10 atm pressure (corresponding to 2.0 ppm NOx corrected to 15% O{sub 2} dry) with near-zero CO emissions, surpassing the project goal of < 0.03 lbs/MMBtu NOx. These emissions levels were achieved at scaled (10 atm, sub-scale) baseload conditions corresponding to Tampa Electric's Polk Power Station operation on 100% syngas (no co-firing of natural gas).

  3. The Source of Airborne Lead: Recycling Pb-Contaminated Soils

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Source of Airborne Lead: Recycling Pb-Contaminated Soils Starting in the 1970s, federal regulatory control and eventual elimination of lead-based "anti-knock" additives in gasoline decreased the level of airborne Pb in the USA by two orders-of-magnitude [1]. Blood lead levels of the USA figure 1 Figure 1. The good, the bad, and the ugly. Ambient airborne particulate matter captured on filters of woven silica fiber (large strips) and TeflonTM (round). Clean fiber filter at bottom

  4. Sodium Recycle Economics for Waste Treatment Plant Operations

    SciTech Connect (OSTI)

    Sevigny, Gary J.; Poloski, Adam P.; Fountain, Matthew S.

    2008-08-31

    Sodium recycle at the Hanford Waste Treatment Plant (WTP) would reduce the number of glass canisters produced, and has the potential to significantly reduce the cost to the U.S. Department of Energy (DOE) of treating the tank wastes by hundreds of millions of dollars. The sodium, added in the form of sodium hydroxide, was originally added to minimize corrosion of carbon-steel storage tanks from acidic reprocessing wastes. In the baseline Hanford treatment process, sodium hydroxide is required to leach gibbsite and boehmite from the high level waste (HLW) sludge. In turn, this reduces the amount of HLW glass produced. Currently, a significant amount of additional sodium hydroxide will be added to the process to maintain aluminate solubility at ambient temperatures during ion exchange of cesium. The vitrification of radioactive waste is limited by sodium content, and this additional sodium mass will increase low-activity waste-glass mass. An electrochemical salt-splitting process, based on sodium-ion selective ceramic membranes, is being developed to recover and recycle sodium hydroxide from high-salt radioactive tank wastes in DOE’s complex. The ceramic membranes are from a family of materials known as sodium (Na)—super-ionic conductors (NaSICON)—and the diffusion of sodium ions (Na+) is allowed, while blocking other positively charged ions. A cost/benefit evaluation was based on a strategy that involves a separate caustic-recycle facility based on the NaSICON technology, which would be located adjacent to the WTP facility. A Monte Carlo approach was taken, and several thousand scenarios were analyzed to determine likely economic results. The cost/benefit evaluation indicates that 10,000–50,000 metric tons (MT) of sodium could be recycled, and would allow for the reduction of glass production by 60,000–300,000 MT. The cost of the facility construction and operation was scaled to the low-activity waste (LAW) vitrification facility, showing cost would be roughly $150 million to $400 million for construction and $10 million to $40 million per year for operations. Depending on the level of aluminate supersaturation allowed in the storage tanks in the LAW Pretreatment Facility, these values indicate a return on investment of up to 25% to 60%.

  5. Water Recycling removal using temperature-sensitive hydronen

    SciTech Connect (OSTI)

    Rana B. Gupta

    2002-10-30

    The overall objective of this project was to study the proposed Water Recycling/Removal Using Temperature-Sensitive Hydrogels. The main element of this technology is the design of a suitable hydrogel that can perform needed water separation for pulp and paper industry. The specific topics studied are to answer following questions: (a) Can water be removed using hydrogel from large molecules such as lignin? (b) Can the rate of separation be made faster? (c) What are the molecular interactions with hydrogel surface? (d) Can a hydrogel be designed for a high ionic strength and high temperature? Summary of the specific results are given.

  6. EERE Success Story-North Dakota: EERE-Funded Project Recycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The modern, natural gas-fueled generators burn cleanly with "ultra-low" emissions ratings that exceed state and federal emissions standards. The "recycled energy" helps better ...

  7. Y-12 employees recycle electronics to be green and help others...

    National Nuclear Security Administration (NNSA)

    "It was great to see Y-12 employees and subcontractors recycle their home electronics," said Sustainability and Stewardship's Jan Jackson. "Employees brought in their old personal ...

  8. Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons

    DOE Patents [OSTI]

    Rollins, Harry W.; Petkovic, Lucia M.; Ginosar, Daniel M.

    2011-02-01

    Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

  9. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation...

    Office of Scientific and Technical Information (OSTI)

    Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Citation Details ... This content will become publicly available on September 21, 2016 Title: Complex catalytic ...

  10. The Catalytic Subunit of the SWR1 Remodeler Is a Histone Chaperone...

    Office of Scientific and Technical Information (OSTI)

    The Catalytic Subunit of the SWR1 Remodeler Is a Histone Chaperone for the H2A.Z-H2B Dimer Citation Details In-Document Search Title: The Catalytic Subunit of the SWR1 Remodeler Is ...

  11. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: ...

  12. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using ...

  13. Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are ...

  14. Industrial Gas Turbine Engine Catalytic Pilot Combustor-Prototype Testing

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep; Pfefferle, William

    2010-04-01

    PCI has developed and demonstrated its Rich Catalytic Lean-burn (RCL®) technology for industrial and utility gas turbines to meet DOE's goals of low single digit emissions. The technology offers stable combustion with extended turndown allowing ultra-low emissions without the cost of exhaust after-treatment and further increasing overall efficiency (avoidance of after-treatment losses). The objective of the work was to develop and demonstrate emission benefits of the catalytic technology to meet strict emissions regulations. Two different applications of the RCL® concept were demonstrated: RCL® catalytic pilot and Full RCL®. The RCL® catalytic pilot was designed to replace the existing pilot (a typical source of high NOx production) in the existing Dry Low NOx (DLN) injector, providing benefit of catalytic combustion while minimizing engine modification. This report discusses the development and single injector and engine testing of a set of T70 injectors equipped with RCL® pilots for natural gas applications. The overall (catalytic pilot plus main injector) program NOx target of less than 5 ppm (corrected to 15% oxygen) was achieved in the T70 engine for the complete set of conditions with engine CO emissions less than 10 ppm. Combustor acoustics were low (at or below 0.1 psi RMS) during testing. The RCL® catalytic pilot supported engine startup and shutdown process without major modification of existing engine controls. During high pressure testing, the catalytic pilot showed no incidence of flashback or autoignition while operating over a wide range of flame temperatures. In applications where lower NOx production is required (i.e. less than 3 ppm), in parallel, a Full RCL® combustor was developed that replaces the existing DLN injector providing potential for maximum emissions reduction. This concept was tested at industrial gas turbine conditions in a Solar Turbines, Incorporated high-pressure (17 atm.) combustion rig and in a modified Solar Turbines, Incorporated Saturn engine rig. High pressure single-injector rig and modified engine rig tests demonstrated NOx less than 2 ppm and CO less than 10 ppm over a wide flame temperature operating regime with low combustion noise (<0.15% peak-to-peak). Minimum NOx for the optimized engine retrofit Full RCL® designs was less than 1 ppm with CO emissions less than 10 ppm. Durability testing of the substrate and catalyst material was successfully demonstrated at pressure and temperature showing long term stable performance of the catalytic reactor element. Stable performance of the reactor element was achieved when subjected to durability tests (>5000 hours) at simulated engine conditions (P=15 atm, Tin=400C/750F.). Cyclic tests simulating engine trips was also demonstrated for catalyst reliability. In addition to catalyst tests, substrate oxidation testing was also performed for downselected substrate candidates for over 25,000 hours. At the end of the program, an RCL® catalytic pilot system has been developed and demonstrated to produce NOx emissions of less than 3 ppm (corrected to 15% O2) for 100% and 50% load operation in a production engine operating on natural gas. In addition, a Full RCL® combustor has been designed and demonstrated less than 2 ppm NOx (with potential to achieve 1 ppm) in single injector and modified engine testing. The catalyst/substrate combination has been shown to be stable up to 5500 hrs in simulated engine conditions.

  15. Selenium utilization in thioredoxin and catalytic advantage provided by selenocysteine

    SciTech Connect (OSTI)

    Kim, Moon-Jung; Lee, Byung Cheon; Hwang, Kwang Yeon; Gladyshev, Vadim N.; Kim, Hwa-Young

    2015-06-12

    Thioredoxin (Trx) is a major thiol-disulfide reductase that plays a role in many biological processes, including DNA replication and redox signaling. Although selenocysteine (Sec)-containing Trxs have been identified in certain bacteria, their enzymatic properties have not been characterized. In this study, we expressed a selenoprotein Trx from Treponema denticola, an oral spirochete, in Escherichia coli and characterized this selenoenzyme and its natural cysteine (Cys) homologue using E. coli Trx1 as a positive control. {sup 75}Se metabolic labeling and mutation analyses showed that the SECIS (Sec insertion sequence) of T. denticola selenoprotein Trx is functional in the E. coli Sec insertion system with specific selenium incorporation into the Sec residue. The selenoprotein Trx exhibited approximately 10-fold higher catalytic activity than the Sec-to-Cys version and natural Cys homologue and E. coli Trx1, suggesting that Sec confers higher catalytic activity on this thiol-disulfide reductase. Kinetic analysis also showed that the selenoprotein Trx had a 30-fold higher K{sub m} than Cys-containing homologues, suggesting that this selenoenzyme is adapted to work efficiently with high concentrations of substrate. Collectively, the results of this study support the hypothesis that selenium utilization in oxidoreductase systems is primarily due to the catalytic advantage provided by the rare amino acid, Sec. - Highlights: • The first characterization of a selenoprotein Trx is presented. • The selenoenzyme Trx exhibits 10-fold higher catalytic activity than Cys homologues. • Se utilization in Trx is primarily due to the catalytic advantage provided by Sec residue.

  16. Agglutination of single catalyst particles during fluid catalytic cracking as observed by X-ray nanotomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meirer, F.; Kalirai, S.; Weker, J. Nelson; Liu, Y.; Andrews, J. C.; Weckhuysen, B. M.

    2015-04-14

    Metal accumulation at the catalyst particle surface plays a role in particle agglutination during fluid catalytic cracking.

  17. Process and apparatus for preheating heavy feed to a catalytic cracking

    Office of Scientific and Technical Information (OSTI)

    unit (Patent) | SciTech Connect Process and apparatus for preheating heavy feed to a catalytic cracking unit Citation Details In-Document Search Title: Process and apparatus for preheating heavy feed to a catalytic cracking unit This patent describes an improvement in a catalytic cracking process wherein a heavy hydrocarbon feed comprising hydrocarbons having a boiling point above about 650{degrees}F is catalytically cracked to cracked products. It comprises preheating at least a portion of

  18. Status of LLNL Hot-Recycled-Solid oil shale retort

    SciTech Connect (OSTI)

    Baldwin, D.E.; Cena, R.J.

    1993-12-31

    We have investigated the technical and economic barriers facing the introduction of an oil shale industry and we have chosen Hot-Recycled-Solid (HRS) oil shale retorting as the primary advanced technology of interest. We are investigating this approach through fundamental research, operation of a 4 tonne-per-day, HRS pilot plant and development of an Oil Shale Process (OSP) mathematical model. Over the last three years, from June 1991 to June 1993, we completed a series of runs (H10--H27) using the 4-TPD pilot plant to demonstrate the technical feasibility of the HRS process and answer key scale-up questions. With our CRADA partners, we seek to further develop the HRS technology, maintain and enhance the knowledge base gained over the past two decades through research and development by Government and industry and determine the follow on steps needed to advance the technology towards commercialization. The LLNL Hot-Recycled-Solid process has the potential to improve existing oil shale technology. It processes oil shale in minutes instead of hours, reducing plant size. It processes all oil shale, including fines rejected by other processes. It provides controls to optimize product quality for different applications. It co-generates electricity to maximize useful energy output. And, it produces negligible SO{sub 2} and NO{sub x} emissions, a non-hazardous waste shale and uses minimal water.

  19. A Membrane Process for Recycling Die Lube from Wastewater Solutions

    SciTech Connect (OSTI)

    Eric S. Peterson; Jessica Trudeau; Bill Cleary; Michael Hackett; William A. Greene

    2003-04-01

    An active-surface membrane technology was used to separate a die lube manufacturing wastewater stream consisting of various oils, hydrocarbons, heavy metals, and silicones. The ultrafiltration membranes reduced organics from initial oil and grease contents by 20–25X, carbon oxygen demand (COD) by 1.5 to 2X, and total organic carbon (TOC) by 0.6, while the biological oxygen demand (BOD) remained constant. The active-surface membranes were not fouled as badly as non-active-surface systems and the active-surface membrane flux levels were consistently higher and more stable than those of the non-active-surface membranes tested. Field testing demonstrated that the rotary microfilter can concentrate the die lube, i.e. remove the glycerin component, and produce a die lube suitable for recycling. The recycling system operated for six weeks with only seven cleaning cycles and no mechanical or electrical failures. Test data and quality records indicate that the die casting scrap was reduced from 8.4 to 7.8%. There is no doubt that this test yielded tremendous results. This separation process presents significant opportunities that can be evaluated further.

  20. A Membrane Process for Recycling Die Lube from Wastewater Solutions

    SciTech Connect (OSTI)

    Peterson, E. S.; Trudeau, J.; Cleary, B.; Hackett, M.; Greene, W. A.

    2003-04-30

    An active-surface membrane technology was used to separate a die lube manufacturing wastewater stream consisting of various oils, hydrocarbons, heavy metals, and silicones. The ultrafiltration membranes reduced organics from initial oil and grease contents by 20-25X, carbon oxygen demand (COD) by 1.5 to 2X, and total organic carbon (TOC) by 0.6, while the biological oxygen demand (BOD) remained constant. The active-surface membranes were not fouled as badly as non-active-surface systems and the active-surface membrane flux levels were consistently higher and more stable than those of the non-active-surface membranes tested. Field testing demonstrated that the rotary microfilter can concentrate the die lube, i.e. remove the glycerin component, and produce a die lube suitable for recycling. The recycling system operated for six weeks with only seven cleaning cycles and no mechanical or electrical failures. Test data and quality records indicate that the die casting scrap was reduced from 8.4 to 7.8%. There is no doubt that this test yielded tremendous results. This separation process presents significant opportunities that can be evaluated further.

  1. Packaging, Transportation and Recycling of NPP Condenser Modules - 12262

    SciTech Connect (OSTI)

    Polley, G.M. [Perma-Fix Environmental Services, 575 Oak Ridge Turnpike, Oak Ridge, TN 37830 (United States)

    2012-07-01

    Perma-Fix was awarded contract from Energy Northwest for the packaging, transportation and disposition of the condenser modules, water boxes and miscellaneous metal, combustibles and water generated during the 2011 condenser replacement outage at the Columbia Generating Station. The work scope was to package the water boxes and condenser modules as they were removed from the facility and transfer them to the Perma-Fix Northwest facility for processing, recycle of metals and disposition. The condenser components were oversized and overweight (the condenser modules weighed ?102,058 kg [225,000 lb]) which required special equipment for loading and transport. Additional debris waste was packaged in inter-modals and IP-1 boxes for transport. A waste management plan was developed to minimize the generation of virtually any waste requiring landfill disposal. The Perma-Fix Northwest facility was modified to accommodate the ?15 m [50-ft] long condenser modules and equipment was designed and manufactured to complete the disassembly, decontamination and release survey. The condenser modules are currently undergoing processing for free release to a local metal recycler. Over three millions pounds of metal will be recycled and over 95% of the waste generated during this outage will not require land disposal. There were several elements of this project that needed to be addressed during the preparation for this outage and the subsequent packaging, transportation and processing. - Staffing the project to support 24/7 generation of large components and other wastes. - The design and manufacture of the soft-sided shipping containers for the condenser modules that measured ?15 m X 4 m X 3 m [50 ft X 13 ft X 10 ft] and weighed ?102,058 kg [225,000 lbs] - Developing a methodology for loading the modules into the shipping containers. - Obtaining a transport vehicle for the modules. - Designing and modifying the processing facility. - Movement of the modules at the processing facility. If any of these issues were not adequately resolved prior to the start of the outage, costly delays would result and the re-start of the power plant could be impacted. The main focus of this project was to find successful methods for keeping this material out of the landfills and preserving the natural resources. In addition, this operation provided a significant cost savings to the public utility by minimizing landfill disposal. The onsite portion of the project has been completed without impact to the overall outage schedule. By the date of presentation, the majority of the waste from the condenser replacement project will have been processed and recycled. The goals for this project included helping Energy Northwest maintain the outage schedule, package and characterize waste compliantly, perform transportation activities in compliance with 49CFR (Ref-1), and minimize the waste disposal volume. During this condenser replacement project, over three millions pounds of waste was generated, packaged, characterized and transported without injury or incident. It is anticipated that 95% of the waste generated during this project will not require landfill disposal. All of the waste is scheduled to be processed, decontaminated and recycled by June of 2012. (authors)

  2. Low-severity catalytic two-stage liquefaction process: Illinois coal conceptual commercial plant design and economics

    SciTech Connect (OSTI)

    Abrams, L.M.; Comolli, A.G.; Popper, G.A.; Wang, C.; Wilson, G.

    1988-09-01

    Hydrocarbon Research, Inc. (HRI) is conducting a program for the United States Department of Energy (DOE) to evaluate a Catalytic Two-Stage Liquefaction (CTSL) Process. This program which runs through 1987, is a continuation of an earlier DOE sponsored program (1983--1985) at HRI to develop a new technology concept for CTSL. The earlier program included bench-scale testing of improved operating conditions for the CTSL Process on Illinois No. 6 bituminous coal and Wyoming sub-bituminous coal, and engineering screening studies to identify the economic incentive for CTSL over the single-stage H-Coal/reg sign/ Process for Illinois No. 6 coal. In the current program these engineering screening studies are extended to deep-cleaned Illinois coal and use of heavy recycle. The results from this comparison will be used as a guide for future experiments with respect to selection of coal feedstocks and areas for further process optimization. A preliminary design for CTSL of Illinois deep-cleaned coal was developed based on demonstrated bench-scale performance in Run No. 227-47(I-27), and from HRI's design experience on the Breckinridge Project and H-Coal/reg sign/ Process pilot plant operations at Catlettsburg. Complete conceptual commercial plant designs were developed for a grassroots facility using HRI's Process Planning Model. Product costs were calculated and economic sensitivities analyzed. 14 refs., 11 figs., 49 tabs.

  3. Contribution of cooperative sector recycling to greenhouse gas emissions reduction: A case study of Ribeirão Pires, Brazil

    SciTech Connect (OSTI)

    King, Megan F.; Gutberlet, Jutta

    2013-12-15

    Highlights: • Cooperative recycling achieves environmental, economic and social objectives. • We calculate GHG emissions reduction for a recycling cooperative in São Paulo, Brazil. • The cooperative merits consideration as a Clean Development Mechanism (CDM) project. • A CDM project would enhance the achievements of the recycling cooperative. • National and local waste management policies support the recycling cooperative. - Abstract: Solid waste, including municipal waste and its management, is a major challenge for most cities and among the key contributors to climate change. Greenhouse gas emissions can be reduced through recovery and recycling of resources from the municipal solid waste stream. In São Paulo, Brazil, recycling cooperatives play a crucial role in providing recycling services including collection, separation, cleaning, stocking, and sale of recyclable resources. The present research attempts to measure the greenhouse gas emission reductions achieved by the recycling cooperative Cooperpires, as well as highlight its socioeconomic benefits. Methods include participant observation, structured interviews, questionnaire application, and greenhouse gas accounting of recycling using a Clean Development Mechanism methodology. The results show that recycling cooperatives can achieve important energy savings and reductions in greenhouse gas emissions, and suggest there is an opportunity for Cooperpires and other similar recycling groups to participate in the carbon credit market. Based on these findings, the authors created a simple greenhouse gas accounting calculator for recyclers to estimate their emissions reductions.

  4. Geothermal Systems are a Breath of Fresh Air for Illinois School District |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Systems are a Breath of Fresh Air for Illinois School District Geothermal Systems are a Breath of Fresh Air for Illinois School District May 24, 2010 - 11:01am Addthis Each classroom has a geothermal unit installed. Although large, the units blend into surroundings and don’t produce excess noise. | Photo Courtesy of Sterling Public Schools Each classroom has a geothermal unit installed. Although large, the units blend into surroundings and don't produce excess

  5. Promoting Offshore Wind Along the "Fresh Coast" | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Promoting Offshore Wind Along the "Fresh Coast" Promoting Offshore Wind Along the "Fresh Coast" October 12, 2010 - 12:18pm Addthis Chris Hart Offshore Wind Team Lead, Wind & Water Power Program When people think about offshore wind power, the first location that comes to mind probably isn't Cleveland, Ohio. Most of the offshore wind turbines installed around the world are operating in salt water, like Europe's North Sea and Baltic Sea, and most of the offshore wind

  6. Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pyrolysis | Department of Energy Ex-Situ Catalytic Fast Pyrolysis Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to produce biofuel blendstocks. PDF icon Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis More Documents & Publications Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis

  7. Method for recovering catalytic elements from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence; Matlin, Ramail; Heinz, Robert

    2012-06-26

    A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

  8. Battery resource assessment. Subtask II. 5. Battery manufacturing capability recycling of battery materials. Draft final report

    SciTech Connect (OSTI)

    Pemsler, P.

    1981-02-01

    Studies were conducted on the recycling of advanced battery system components for six different battery systems. These include: Nickel/Zinc, Nickel/Iron, Zinc/Chlorine, Zinc/Bromine, Sodium/Sulfur, and Lithium-Aluminum/Iron Sulfide. For each battery system, one or more processes has been developed which would permit recycling of the major or active materials. Each recycle process has been designed to produce a product material which can be used directly as a raw material by the battery manufacturer. Metal recoverabilities are in the range of 93 to 95% for all processes. In each case, capital and operating costs have been developed for a recycling plant which processes 100,000 electric vehicle batteries per year. These costs have been developed based on material and energy balances, equipment lists, factored installation costs, and manpower estimates. In general, there are no technological barriers for recycling in the Nickel/Zinc, Nickel/Iron, Zinc/Chlorine and Zinc/Bromine battery systems. The recycling processes are based on essentially conventional, demonstrate technology. The lead times required to build battery recycling plants based on these processes is comparable to that of any other new plant. The total elapsed time required from inception to plant operation is approximately 3 to 5 y. The recycling process for the sodium/sulfur and lithium-aluminum/sulfide battery systems are not based on conventional technology. In particular, mechanical systems for dismantling these batteries must be developed.

  9. Overview of reductants utilized in nuclear fuel reprocessing/recycling

    SciTech Connect (OSTI)

    Patricia Paviet-Hartmann; Catherine Riddle; Keri Campbell; Edward Mausolf

    2013-10-01

    Most of the aqueous processes developed, or under consideration worldwide for the recycling of used nuclear fuel (UNF) utilize the oxido-reduction properties of actinides to separate them from other radionuclides. Generally, after acid dissolution of the UNF, (essentially in nitric acid solution), actinides are separated from the raffinate by liquid-liquid extraction using specific solvents, associated along the process, with a particular reductant that will allow the separation to occur. For example, the industrial PUREX process utilizes hydroxylamine as a plutonium reductant. Hydroxylamine has numerous advantages: not only does it have the proper attributes to reduce Pu(IV) to Pu(III), but it is also a non-metallic chemical that is readily decomposed to innocuous products by heating. However, it has been observed that the presence of high nitric acid concentrations or impurities (such as metal ions) in hydroxylamine solutions increase the likelihood of the initiation of an autocatalytic reaction. Recently there has been some interest in the application of simple hydrophilic hydroxamic ligands such as acetohydroxamic acid (AHA) for the stripping of tetravalent actinides in the UREX process flowsheet. This approach is based on the high coordinating ability of hydroxamic acids with tetravalent actinides (Np and Pu) compared with hexavalent uranium. Thus, the use of AHA offers a route for controlling neptunium and plutonium in the UREX process by complexant based stripping of Np(IV) and Pu(IV) from the TBP solvent phase, while U(VI) ions are not affected by AHA and remain solvated in the TBP phase. In the European GANEX process, AHA is also used to form hydrophilic complexes with actinides and strip them from the organic phase into nitric acid. However, AHA does not decompose completely when treated with nitric acid and hampers nitric acid recycling. In lieu of using AHA in the UREX + process, formohydroxamic acid (FHA), although not commercially available, hold promises as a replacement for AHA. FHA undergoes hydrolysis to formic acid which is volatile, thus allowing the recycling of nitric acid. Unfortunately, FHA powder was not stable in the experiments we ran in our laboratory. In addition, AHA and FHA also decompose to hydroxylamine which may undergo an autocatalytic reaction. Other reductants are available and could be extremely useful for actinides separation. The review presents the current plutonium reductants used in used nuclear fuel reprocessing and will introduce innovative and novel reductants that could become reducers for future research on UNF separation.

  10. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, Richard S.; Slegeir, William A.; Foran, Michael T.

    1984-01-01

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150.degree.-260.degree. C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO.sub.4 and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect.

  11. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

    1984-01-06

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

  12. Role of surface generated radicals in catalytic combustion

    SciTech Connect (OSTI)

    Santavicca, D.A.; Stein, Y.; Royce, B.S.H.

    1984-04-01

    The role of surface generated OH radicals in determining the catalytic ignition characteristics for propane oxidation on platinum were studied. The experiments were conducted in a stacked-plate, catalyst bed. Transient measurements, during catalytic ignition, of the catalyst's axial temperature profile were made and the effect of equivalence ratio, inlet temperature and inlet velocity was investigated. These measurements will provide insights which will be useful in planning and interpreting to OH measurements. Attempts to measure OH concentration in the catalyst bed using resonance absorption spectroscopy were unsuccessful, indicating that OH concentrations are below 10 to the 16th power/cc but still possibly above equilibrium values. Measurements are currently underway using forward scatter laser induced fluorescence which should extend the OH detection limits several orders of magnitude below the equilibrium concentrations.

  13. Selective dehydrogenation of propane over novel catalytic materials

    SciTech Connect (OSTI)

    Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

    1998-02-01

    The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

  14. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  15. Catalytic effects of minerals on NOx emission from coal combustion

    SciTech Connect (OSTI)

    Yao, M.Y.; Che, D.F.

    2007-07-01

    The catalytic effects of inherent mineral matters on NOx emissions from coal combustion have been investigated by a thermo-gravimetric analyzer (TGA) equipped with a gas analyzer. The effect of demineralization and the individual effect of Na, K, Ca, Mg, and Fe on the formation of NOx are studied as well as the combined catalytic effects of Ca + Na and Ca + Ti. Demineralization causes more Fuel-N to retain in the char, and reduction of NOx mostly. But the mechanistic effect on NOx formation varies from coal to coal. Ca and Mg promote NOx emission. Na, K, Fe suppress NOx formation to different extents. The effect of transition element Fe is the most obvious. The combination of Ca + Na and Ca + Ti can realize the simultaneous control of sulfur dioxide and nitrogen oxides emissions.

  16. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Jones, Susanne B.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

  17. Catalytic destruction of groundwater contaminants in reactive extraction wells

    DOE Patents [OSTI]

    McNab, Jr., Walt W.; Reinhard, Martin

    2002-01-01

    A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

  18. Catalytic conversion of alcohols to hydrocarbons with low benzene content

    DOE Patents [OSTI]

    Narula, Chaitanya K.; Davison, Brian H.; Keller, Martin

    2016-03-08

    A method for converting an alcohol to a hydrocarbon fraction having a lowered benzene content, the method comprising: converting said alcohol to a hydrocarbon fraction by contacting said alcohol, under conditions suitable for converting said alcohol to said hydrocarbon fraction, with a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon fraction, and contacting said hydrocarbon fraction with a benzene alkylation catalyst, under conditions suitable for alkylating benzene, to form alkylated benzene product in said hydrocarbon fraction. Also described is a catalyst composition useful in the method, comprising a mixture of (i) a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon, and (ii) a benzene alkylation catalyst, in which (i) and (ii) may be in a mixed or separated state. A reactor for housing the catalyst and conducting the reaction is also described.

  19. The future of automotive lithium-ion battery recycling: Charting a sustainable course

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaines, Linda

    2014-12-01

    This paper looks ahead, beyond the projected large-scale market penetration of vehicles containing advanced batteries, to the time when the spent batteries will be ready for final disposition. It describes a working system for recycling, using lead–acid battery recycling as a model. Recycling of automotive lithium-ion (Li-ion) batteries is more complicated and not yet established because few end-of-life batteries will need recycling for another decade. There is thus the opportunity now to obviate some of the technical, economic, and institutional roadblocks that might arise. The paper considers what actions can be started now to avoid the impediments to recycling andmore »ensure that economical and sustainable options are available at the end of the batteries' useful life.« less

  20. Recent progress on preparation and properties of nanocomposites from recycled polymers: A review

    SciTech Connect (OSTI)

    Zare, Yasser

    2013-03-15

    Highlights: â–º The article determines the current status of nanotechnology in polymer recycling. â–º The addition of nanofillers to waste polymers, composites and blends is discussed. â–º The future challenges in polymer recycling using nanoparticles are explained. - Abstract: Currently, the growing consumption of polymer products creates the large quantities of waste materials resulting in public concern in the environment and people life. Nanotechnology is assumed the important technology in the current century. Recently, many researchers have tried to develop this new science for polymer recycling. In this article, the application of different nanofillers in the recycled polymers such as PET, PP, HDPE, PVC, etc. and the attributed composites and blends is studied. The morphological, mechanical, rheological and thermal properties of prepared nanocomposites as well as the future challenges are extensively discussed. The present article determines the current status of nanotechnology in the polymer recycling which guide the future studies in this attractive field.

  1. The future of automotive lithium-ion battery recycling: Charting a sustainable course

    SciTech Connect (OSTI)

    Gaines, Linda

    2014-12-01

    This paper looks ahead, beyond the projected large-scale market penetration of vehicles containing advanced batteries, to the time when the spent batteries will be ready for final disposition. It describes a working system for recycling, using lead–acid battery recycling as a model. Recycling of automotive lithium-ion (Li-ion) batteries is more complicated and not yet established because few end-of-life batteries will need recycling for another decade. There is thus the opportunity now to obviate some of the technical, economic, and institutional roadblocks that might arise. The paper considers what actions can be started now to avoid the impediments to recycling and ensure that economical and sustainable options are available at the end of the batteries' useful life.

  2. Solid oxide fuel cell power plant with an anode recycle loop turbocharger

    SciTech Connect (OSTI)

    Saito, Kazuo; Skiba, Tommy; Patel, Kirtikumar H.

    2015-07-14

    An anode exhaust recycle turbocharger (100) has a turbocharger turbine (102) secured in fluid communication with a compressed oxidant stream within an oxidant inlet line (218) downstream from a compressed oxidant supply (104), and the anode exhaust recycle turbocharger (100) also includes a turbocharger compressor (106) mechanically linked to the turbocharger turbine (102) and secured in fluid communication with a flow of anode exhaust passing through an anode exhaust recycle loop (238) of the solid oxide fuel cell power plant (200). All or a portion of compressed oxidant within an oxidant inlet line (218) drives the turbocharger turbine (102) to thereby compress the anode exhaust stream in the recycle loop (238). A high-temperature, automotive-type turbocharger (100) replaces a recycle loop blower-compressor (52).

  3. Converting sugars to sugar alcohols by aqueous phase catalytic hydrogenation

    DOE Patents [OSTI]

    Elliott, Douglas C.; Werpy, Todd A.; Wang, Yong; Frye, Jr., John G.

    2003-05-27

    The present invention provides a method of converting sugars to their corresponding sugar alcohols by catalytic hydrogenation in the aqueous phase. It has been found that surprisingly superior results can be obtained by utilizing a relatively low temperature (less than 120.degree. C.), selected hydrogenation conditions, and a hydrothermally stable catalyst. These results include excellent sugar conversion to the desired sugar alcohol, in combination with long life under hydrothermal conditions.

  4. CATALYTIC CONVERSION OF ORGANIC COMPOUNDS USING PENETRATING RADIATION

    DOE Patents [OSTI]

    Caffrey, J.M. Jr.

    1961-10-01

    A method of hydrogenating an olefinic hydrocarbon by irradiating a substrate catalyst and increasing its catalytic activity is described. Ferric oxide with about 0.005% by weight of at least one oxide of a metal selected from the group consisting of aluminum, magnesium, nickel, zirconium, and manganese incorporated therein is irradiated. Then an alkane is placed upon the surface of the catalyst and irradiated in an atmosphere of hydrogen. Any olefin produced from this radiolysis becomes hydrogenated. (AEC)

  5. Biological and Catalytic Conversion of Sugars and Lignin | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biological and Catalytic Conversion of Sugars and Lignin Our research group, comprised of staff scientists, postdoctoral associates, students, and technicians, develops biological and chemical catalysts for cost-effective production of fuels and chemicals from terrestrial biomass. Two side-by-side images. The left figure illustrates the domains of the synthase enzyme, represented as "surfaces" or "blobs," embedded in a lipid bilayer, represented as yellow multi-jointed

  6. Design and Synthesis of Catalytic Metal-Organic Framework Materials |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Design and Synthesis of Catalytic Metal-Organic Framework Materials May 17, 2016 11:00AM to 12:00PM Presenter Omar Farha, Northwestern University Location Building 200 Type Seminar Series CSE Seminar Abstract: Metal-organic frameworks (MOFs) are an emerging class of solid-state materials built up from metal-based nodes and organic linkers. They exhibit permanent porosity and unprecedented surface areas that can readily be tuned through coordination chemistry at

  7. Hybrid lean premixing catalytic combustion system for gas turbines

    DOE Patents [OSTI]

    Critchley, Ian L.

    2003-12-09

    A system and method of combusting a hydrocarbon fuel is disclosed. The system combines the accuracy and controllability of an air staging system with the ultra-low emissions achieved by catalytic combustion systems without the need for a pre-heater. The result is a system and method that is mechanically simple and offers ultra-low emissions over a wide range of power levels, fuel properties and ambient operating conditions.

  8. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOE’s) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  9. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Broader source: Energy.gov (indexed) [DOE]

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials | Department of Energy 11 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace055_peden_2011_o.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials Deactivation Mechanisms of Base Metal/Zeolite Urea

  10. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Broader source: Energy.gov (indexed) [DOE]

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials | Department of Energy 12 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace055_peden_2012_o.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials Deactivation Mechanisms of Base Metal/Zeolite

  11. New Catalytic DNA Biosensors for Radionuclides and Metal ions

    SciTech Connect (OSTI)

    Lu, Yi

    2003-06-01

    The goals of the project are to develop new catalytic DNA biosensors for simultaneous detection and quantification of bioavailable radionuclides and metal ions, and apply the sensors for on-site, real-time assessment of concentration, speciation and stability of the individual contaminants during and after bioremediation. A negative selection strategy was tested and validated. In vitro selection was shown to yield highly active and specific transition metal ion-dependent catalytic DNA/RNA. A fluorescence resonance energy transfer (FRET) study of in vitro selected DNA demonstrated that the trifluorophore labeled system is a simple and powerful tool in studying complex biomolecules structure and dynamics, and is capable of revealing new sophisticated structural changes. New fluorophore/quenchers in a single fluorosensor yielded improved signal to noise ratio in detection, identification and quantification of metal contaminants. Catalytic DNA fluorescent and colorimetric sensors were shown useful in sensing lead in lake water and in leaded paint. Project results were described in two papers and two patents, and won an international prize.

  12. New Catalytic DNA Biosensors for Radionuclides and Metal ions

    SciTech Connect (OSTI)

    Lu, Yi

    2002-06-01

    The goals of the project are to develop new catalytic DNA biosensors for simultaneous detection and quantification of bioavailable radionuclides and metal ions, and apply the sensors for on-site, real-time assessment of concentration, speciation and stability of the individual contaminants during and after bioremediation. A negative selection strategy was tested and validated. In vitro selection was shown to yield highly active and specific transition metal ion-dependent catalytic DNA/RNA. A fluorescence resonance energy transfer (FRET) study of in vitro selected DNA demonstrated that the trifluorophore labeled system is a simple and powerful tool in studying complex biomolecules structure and dynamics, and is capable of revealing new sophisticated structural changes. New fluorophore/quenchers in a single fluorosensor yielded improved signal to noise ratio in detection, identification and quantification of metal contaminants. Catalytic DNA fluorescent and colorimetric sensors were shown useful in sensing lead in lake water and in leaded paint. Project results were described in two papers and two patents, and won an international prize.

  13. Dedicated Beamline Facilities for Catalytic Research. Synchrotron Catalysis Consortium (SCC)

    SciTech Connect (OSTI)

    Chen, Jingguang; Frenkel, Anatoly; Rodriguez, Jose; Adzic, Radoslav; Bare, Simon R.; Hulbert, Steve L.; Karim, Ayman; Mullins, David R.; Overbury, Steve

    2015-03-04

    Synchrotron spectroscopies offer unique advantages over conventional techniques, including higher detection sensitivity and molecular specificity, faster detection rate, and more in-depth information regarding the structural, electronic and catalytic properties under in-situ reaction conditions. Despite these advantages, synchrotron techniques are often underutilized or unexplored by the catalysis community due to various perceived and real barriers, which will be addressed in the current proposal. Since its establishment in 2005, the Synchrotron Catalysis Consortium (SCC) has coordinated significant efforts to promote the utilization of cutting-edge catalytic research under in-situ conditions. The purpose of the current renewal proposal is aimed to provide assistance, and to develop new sciences/techniques, for the catalysis community through the following concerted efforts: Coordinating the implementation of a suite of beamlines for catalysis studies at the new NSLS-II synchrotron source; Providing assistance and coordination for catalysis users at an SSRL catalysis beamline during the initial period of NSLS to NSLS II transition; Designing in-situ reactors for a variety of catalytic and electrocatalytic studies; Assisting experimental set-up and data analysis by a dedicated research scientist; Offering training courses and help sessions by the PIs and co-PIs.

  14. Donor solvent coal liquefaction with bottoms recycle at elevated pressure

    DOE Patents [OSTI]

    Bauman, Richard F.; Taunton, John W.; Anderson, George H.; Trachte, Ken L.; Hsia, Steve J.

    1982-01-01

    An improved process for liquefying solid carbonaceous materials wherein increased naphtha yields are achieved by effecting the liquefaction at a pressure within the range from about 1750 to about 2800 psig in the presence of recycled bottoms and a hydrogen-donor solvent containing at least 0.8 wt % donatable hydrogen. The liquefaction is accomplished at a temperature within the range from about 700.degree. to about 950.degree. F. The coal:bottoms ratio in the feed to liquefaction will be within the range from about 1:1 to about 5:1 and the solvent or diluent to total solids ratio will be at least 1.5:1 and preferably within the range from about 1.6:1 to about 3:1. The yield of naphtha boiling range materials increases as the pressure increases but generally reaches a maximum at a pressure within the range from about 2000 to about 2500 psig.

  15. Making manufacturers responsible for recycling: Passing the garbage buck

    SciTech Connect (OSTI)

    Chilton, K.; Boerner, C.; Ansehl-Fellow, J.

    1995-09-01

    During a meeting with the Conference of Mayor and the National Association of Counties in April of 1993, Senator Max Baucus, then-Chairman of the Senate Environment and Public Works Committee, unveiled his solution to America`s {open_quotes}garbage crisis{close_quotes}. Modeled after Germany`s draconian {open_quotes}green dot{close_quotes} recycling program, the Senator`s solution rested on a principle which he called {open_quotes}manufacturers` responsibility for the life-cycle of a product.{close_quotes} {open_quotes}Anyone who sells a product,{close_quotes} Senator Baucus noted, {open_quotes}should also be responsible for the product when it becomes waste{close_quotes}. Other variations on this life-cycle stewardship concept were a central element of Congress`s failed attempts in 1992-1993 to reauthorize the Resource Conservation and Recovery Act (RCRA). Likewise, on July 11, 1994 the United States Conference of Mayors` Energy and Environment Committee passed a resolution calling on Congress to study the concept of {open_quotes}shared responsibility for waste reduction{close_quotes}. The committee cited the virtues of Western Europe`s systems of manufacturers` responsibility and claimed that a U.S. version would create jobs, promote new environmental technology and {open_quotes}result in the emergence of entire new industries{close_quotes}. This report describes a recycling program in Germany in which the manaufacturers are responsible for waste collection. The overall waste reduction benefits are described.

  16. Experimental benchmark of MCNPX calculations against self-interrogation neutron resonance densitometry (SINRD) fresh fuel measurements

    SciTech Connect (OSTI)

    Menlove, Howard O; Swinhoe, Martyn T; La Fleur, Adrienne M; Charlton, William S; Lee, S Y; Tobin, S J

    2010-01-01

    We have investigated the use of Self-Interrogation Neutron Resonance Densitometry (SINRD) to measure the {sup 235}U concentration in a PWR 15 x 15 fresh LEU fuel assembly in air. Different measurement configurations were simulated in Monte Carlo N-Particle eXtended transport code (MCNPX) and benchmarked against experimental results. The sensitivity of SINRD is based on using the same fissile materials in the fission chambers as are present in the fuel because the effect of resonance absorption lines in the transmitted flux is amplified by the corresponding (n,j) reaction peaks in fission chamber. Due to the low spontaneous fission rate of {sup 238}U (i.e. no curium in the fresh fuel), {sup 252}Cf sources were used to self-interrogate the fresh fuel pins. The resonance absorption of these neutrons in the fresh fuel pins can be measured using {sup 235}U fission chambers placed adjacent to the assembly. We used ratios of different fission chambers to reduce the number of unknowns we are trying measure because the neutron source strength and detector-fuel assembly coupling cancel in the ratios. The agreement between MCNPX results and experimental measurements confirms the accuracy of the MCNPX models used. The development of SINRD to measure the fissile content in spent fuel is important to the improvement of nuclear safeguards and material accountability. Future work includes the use of this technique to measure the fissile content in LWR spent fuel in water.

  17. Evaluation of sealed-tube neutron generators for the assay of fresh LWR fuel assemblies

    SciTech Connect (OSTI)

    Cutter, J.; Lee, D.; Lindquist, L.O.; Menlove, H.O.; Caldwell, J.T.; Atencio, J.D.; Kunz, W.E.

    1981-11-01

    The use of sealed-tube neutron generators for the active assay of fresh light-water reactor fuel assemblies has been investigated. The results of experimental tests of the Kaman 801 generator are presented. Neutron yields, source moderation, and transportability are discussed. A comparison is made with the AmLi neutron source for use in the Coincidence Collar.

  18. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Common catalysts typically used to crack the vapor are zeolite, doped zeolite, superacid, solid acid, or other catalyst types. Catalysts can be recycled or regenerated in a ...

  19. Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion

    DOE Patents [OSTI]

    Shen, Ming-Shing (Rocky Point, NY); Yang, Ralph T. (Middle Island, NY)

    1980-01-01

    Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

  20. Radiotoxicity Characterization of Multi-Recycled Thorium Fuel - 12394

    SciTech Connect (OSTI)

    Franceschini, F.; Wenner, M.; Fiorina, C.; Huang, M.; Petrovic, B.; Krepel, J.

    2012-07-01

    As described in companion papers, Westinghouse is proposing the implementation of a thorium based fuel cycle to burn the transuranic (TRU) contained in the used nuclear fuel. The potential of thorium as a TRU burner is described in another paper presented at this conference. This paper analyzes the long-term impact of thorium on the front-end and backend of the fuel cycle. This is accomplished by an assessment of the isotopic make-up of Th in a closed cycle and its impact on representative metrics, such as radiotoxicity, decay heat and gamma heat. The behavior in both thermal and fast neutron energy ranges has been investigated. Irradiation in a Th fuel PWR has been assumed as representative of the thermal range, while a Th fuel fast reactor (FR) has been employed to characterize the behavior in the high-energy range. A comparison with a U-fuel closed-cycle FR has been undertaken in an attempt of a more comprehensive evaluation of each cycle's long-term potential. As the Th fuel undergoes multiple cycles of irradiation, the isotopic composition of the recycled fuel changes. Minor Th isotopes are produced; U-232 and Pa-231 build up; the U vector gradually shifts towards increasing amounts of U-234, U-235 etc., eventually leading to the production of non negligible amounts of TRU isotopes, especially Pu-238. The impact of the recycled fuel isotopic makeup on the in-core behavior is mild, and for some aspects beneficial, i.e. the reactivity swing during irradiation is reduced as the fertile characteristics of the fuel increase. On the other hand, the front and the back-end of the fuel cycle are negatively affected due to the presence of Th-228 and U-232 and the build-up of higher actinides (Pu-238 etc.). The presence of U-232 can also be seen as advantageous as it represents an obstacle to potential proliferators. Notwithstanding the increase in the short-term radiotoxicity and decay heat in the multi-recycled fuel, the Th closed cycle has some potentially substantial advantages compared to the U cycle, such as the smaller actinide radiotoxicity and decay heat for up to 25,000 years after irradiation. In order for these benefits to materialize, the capability to reprocess and remotely manufacture industrial amounts of recycled fuel appears to be the key. Westinghouse is proposing the implementation of a thorium based fuel cycle to burn the TRU contained in the current UNF. The general approach and the potential of thorium as TRU burner is described in other papers presented at this conference. The focus of this paper is to analyze the long-term potential of thorium, once the legacy TRU has been exhausted and the thorium reactor system will become self-sufficient. Therefore, a comparison of Th closed cycle, in fast and thermal neutron energy ranges, vs. U closed cycle, in the fast energy range, has been undertaken. The results presented focus on selected backend and front-end metrics: isotopic actinide composition and potential implications on ingested radiotoxicity, decay heat and gamma heat. The evaluation confirms potential substantial improvements in the backend of the fuel cycle by transitioning to a thorium closed cycle. These benefits are the result of a much lower TRU content, in particular Pu-241, Am-241 and Pu-240, characterizing the Th vs. U actinide inventories, and the ensuing process waste to be disposed. On the other hand, the larger gamma activity of Th recycled fuel, consisting predominantly of hard gammas from U-232's decay products, is a significant challenge for fuel handling, transportation and manufacturing but can be claimed as beneficial for the proliferation resistance of the fuel. It is worth remembering that in our perspective the Th closed cycle and the U closed cycle will follow a transmutation phase which will likely take place over several decades and dictate the technologies required. These will likely include remote fuel manufacturing, regardless of the specific system adopted for the transmutation, which could then be inherited for the ensuing closed cycles. Finally, specific data related to the fuel manufacturing and separation technologies and their performance in the prospected industrial scale deployment, are key for further quantification of the potential merits of the options explored. Further studies in this direction should be warranted before making definitive conclusion. (authors)

  1. FY09 recycling opportunity assessment for Sandia National Laboratories/New Mexico.

    SciTech Connect (OSTI)

    McCord, Samuel Adam

    2010-07-01

    This Recycling Opportunity Assessment (ROA) is a revision and expansion of the FY04 ROA. The original 16 materials are updated through FY08, and then 56 material streams are examined through FY09 with action items for ongoing improvement listed for most. In addition to expanding the list of solid waste materials examined, two new sections have been added to cover hazardous waste materials. Appendices include energy equivalencies of materials recycled, trends and recycle data, and summary tables of high, medium, and low priority action items.

  2. Innovative technologies for recycling and reusing radioactively contaminated materials from DOE facilities

    SciTech Connect (OSTI)

    Bossart, S.J. ); Hyde, J. )

    1993-01-01

    Through award of ten contracts under the solicitation, DOE is continuing efforts to develop innovative technologies for decontamination and recycling or reusing of process equipment, scrap metal, and concrete. These ten technologies are describe briefly in this report. There is great economic incentive for recycling or reusing materials generated during D D of DOE's facilities. If successfully developed, these superior technologies will enable DOE to clean its facilities by 2019. These technologies will also generate a reusable or recyclable product, while achieving D D in less time at lower cost with reduced health and safety risks to the workers, the public and the environment.

  3. Innovative technologies for recycling and reusing radioactively contaminated materials from DOE facilities

    SciTech Connect (OSTI)

    Bossart, S.J.; Hyde, J.

    1993-06-01

    Through award of ten contracts under the solicitation, DOE is continuing efforts to develop innovative technologies for decontamination and recycling or reusing of process equipment, scrap metal, and concrete. These ten technologies are describe briefly in this report. There is great economic incentive for recycling or reusing materials generated during D&D of DOE`s facilities. If successfully developed, these superior technologies will enable DOE to clean its facilities by 2019. These technologies will also generate a reusable or recyclable product, while achieving D&D in less time at lower cost with reduced health and safety risks to the workers, the public and the environment.

  4. U.S. Postal Service BlueEarth Program - Personal Electronics Recycling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program | Department of Energy U.S. Postal Service BlueEarth Program - Personal Electronics Recycling Program U.S. Postal Service BlueEarth Program - Personal Electronics Recycling Program June 26, 2015 - 1:02pm Addthis Department of Energy (DOE) employees may use the U.S. Postal Service's BlueEarth program to mail-in their personally owned electronics and accessories for free recycling. Department of Energy (DOE) employees may use the U.S. Postal Service's BlueEarth program to mail-in their

  5. A rational minor actinide (MA) recycling concept based on innovative oxide fuel with high AM content

    SciTech Connect (OSTI)

    Tanaka, Kenya; Sato, Isamu; Ishii, Tetsuya; Yoshimochi, Hiroshi; Asaga, Takeo; Kurosaki, Ken

    2007-07-01

    A rational MA recycle concept based on high Am content fuel has been proposed. A design study of an Am- MOX fabrication plant, which is a key facility for the MA recycle concept, has been done and the facility concept was clarified from the viewpoint of basic process viability. Preliminary cost estimation suggested that the total construction cost of the MA recycle facilities including Am-MOX, Np-MOX and MA recovery could be comparable with that of the large scale LWR-MOX fabrication plant required for plutonium in LWR fuel cycle. (authors)

  6. Process for the production of ultrahigh purity silane with recycle from separation columns

    DOE Patents [OSTI]

    Coleman, Larry M.

    1982-07-20

    Tri- and dichlorosilanes formed by hydrogenation in the course of the reaction of metallurgical silicon, hydrogen and recycle silicon tetrachloride are employed as feed into a separation column arrangement of sequential separation columns and redistribution reactors which processes the feed into ultrahigh purity silane and recycle silicon tetrachloride. A slip stream is removed from the bottom of two sequential columns and added to the recycle silicon tetrachloride process stream causing impurities in the slip streams to be subjected to reactions in the hydrogenation step whereby waste materials can be formed and readily separated.

  7. End-of-life vehicle recycling : state of the art of resource recovery from shredder residue.

    SciTech Connect (OSTI)

    Jody, B. J.; Daniels, E. J.; Energy Systems

    2007-03-21

    Each year, more than 50 million vehicles reach the end of their service life throughout the world. More than 95% of these vehicles enter a comprehensive recycling infrastructure that includes auto parts recyclers/dismantlers, remanufacturers, and material recyclers (shredders). Today, about 75% of automotive materials are profitably recycled via (1) parts reuse and parts and components remanufacturing and (2) ultimately by the scrap processing (shredding) industry. The process by which the scrap processors recover metal scrap from automobiles involves shredding the obsolete automobiles, along with other obsolete metal-containing products (such as white goods, industrial scrap, and demolition debris), and recovering the metals from the shredded material. The single largest source of recycled ferrous scrap for the iron and steel industry is obsolete automobiles. The non-metallic fraction that remains after the metals are recovered from the shredded materials (about 25% of the weight of the vehicle)--commonly called shredder residue--is disposed of in landfills. Over the past 10 to 15 years, a significant amount of research and development has been undertaken to enhance the recycle rate of end-of-life vehicles (ELVs), including enhancing dismantling techniques and improving remanufacturing operations. However, most of the effort has focused on developing technology to recover materials, such as polymers, from shredder residue. To make future vehicles more energy efficient, more lighter-weight materials--primarily polymers and polymer composites--will be used in manufacturing these vehicles. These materials increase the percentage of shredder residue that must be disposed of, compared with the percentage of metals. Therefore, as the complexity of automotive materials and systems increases, new technologies will be required to sustain and maximize the ultimate recycling of these materials and systems at end-of-life. Argonne National Laboratory (Argonne), in cooperation with the Vehicle Recycling Partnership (VRP) and the American Plastics Council (APC), is working to develop technology for recycling materials from shredder residue. Several other organizations worldwide are also working on developing technology for recycling shredder residue. Without a commercially viable shredder industry, our nation may face greater environmental challenges and a decreased supply of quality scrap and be forced to turn to primary ores for the production of finished metals. This document presents a review of the state of the art in shredder residue recycling. Available technologies and emerging technologies for the recycling of materials from shredder residue are discussed.

  8. Incorporating photon recycling into the analytical drift-diffusion model of high efficiency solar cells

    SciTech Connect (OSTI)

    Lumb, Matthew P.; Steiner, Myles A.; Geisz, John F.; Walters, Robert J.

    2014-11-21

    The analytical drift-diffusion formalism is able to accurately simulate a wide range of solar cell architectures and was recently extended to include those with back surface reflectors. However, as solar cells approach the limits of material quality, photon recycling effects become increasingly important in predicting the behavior of these cells. In particular, the minority carrier diffusion length is significantly affected by the photon recycling, with consequences for the solar cell performance. In this paper, we outline an approach to account for photon recycling in the analytical Hovel model and compare analytical model predictions to GaAs-based experimental devices operating close to the fundamental efficiency limit.

  9. Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device

    DOE Patents [OSTI]

    Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

    2014-05-06

    A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

  10. Method for low temperature catalytic production of hydrogen

    DOE Patents [OSTI]

    Mahajan, Devinder

    2003-07-22

    The invention provides a process for the catalytic production of a hydrogen feed by exposing a hydrogen feed to a catalyst which promotes a base-catalyzed water-gas-shift reaction in a liquid phase. The hydrogen feed can be provided by any process known in the art of making hydrogen gas. It is preferably provided by a process that can produce a hydrogen feed for use in proton exchange membrane fuel cells. The step of exposing the hydrogen feed takes place preferably from about 80.degree. C. to about 150.degree. C.

  11. Fabrication of catalytic electrodes for molten carbonate fuel cells

    DOE Patents [OSTI]

    Smith, James L.

    1988-01-01

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

  12. Catalytic pyrolysis of plastic wastes - Towards an economically viable process

    SciTech Connect (OSTI)

    McIntosh, M.J.; Arzoumanidis, G.G.; Brockmeier, F.E.

    1996-07-01

    The ultimate goal of our project is an economically viable pyrolysis process to recover useful fuels and/or chemicals from plastics- containing wastes. This paper reports the effects of various promoted and unpromoted binary oxide catalysts on yields and compositions of liquid organic products, as measured in a small laboratory pyrolysis reactor. On the basis of these results, a commercial scale catalytic pyrolysis reactor was simulated by the Aspen software and rough costs were estimated. The results suggest that such a process has potential economic viability.

  13. Plasma-assisted catalytic ionization using porous nickel plate

    SciTech Connect (OSTI)

    Oohara, W.; Maeda, T.; Higuchi, T.

    2011-09-15

    Hydrogen atomic pair ions, i.e., H{sup +} and H{sup -} ions, are produced by plasma-assisted catalytic ionization using a porous nickel plate. Positive ions in a hydrogen plasma generated by dc arc discharge are irradiated to the porous plate, and pair ions are produced from the back of the irradiation plane. It becomes clear that the production quantity of pair ions mainly depends on the irradiation current of positive ions and the irradiation energy affects the production efficiency of H{sup -} ions.

  14. Recent Advances in Catalytic Conversion of Ethanol to Chemicals

    SciTech Connect (OSTI)

    Sun, Junming; Wang, Yong

    2014-04-30

    With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

  15. Method and apparatus for decoupled thermo-catalytic pollution control

    DOE Patents [OSTI]

    Tabatabaie-Raissi, Ali; Muradov, Nazim Z.; Martin, Eric

    2006-07-11

    A new method for design and scale-up of thermocatalytic processes is disclosed. The method is based on optimizing process energetics by decoupling of the process energetics from the DRE for target contaminants. The technique is applicable to high temperature thermocatalytic reactor design and scale-up. The method is based on the implementation of polymeric and other low-pressure drop support for thermocatalytic media as well as the multifunctional catalytic media in conjunction with a novel rotating fluidized particle bed reactor.

  16. Heavy oil catalytic cracking process and apparatus (Patent) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Heavy oil catalytic cracking process and apparatus Citation Details In-Document Search Title: Heavy oil catalytic cracking process and apparatus This patent describes a fluidized catalytic cracking process which operates with a hot stripper to improve stripping of spent catalyst from the FCC process. The catalyst from the hot stripper is cooled by direct contact heat exchange with a source or cooled regenerated catalyst. Cooled catalyst may contact hot, stripped catalyst in the base

  17. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-09-29

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase is dispersed.

  18. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels This fact sheet provides an overview of the Next Generation Manufacturing Processes project to develop a unique, fuel-flexible catalytic combustor capable of enabling ultra-low emission, lean premixed combustion of a wide range of gaseous opportunity fuels. PDF icon Fact sheet - Enabling Clean Consumption of Low Btu and Reactive Fuels

  19. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-03-17

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase id dispersed.

  20. Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic Activity |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Ames Laboratory Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic Activity Thanks to a groundbreaking new method, scientists have created the first 3D super-resolution maps of catalytic activity on an individual catalytic nanoparticle while reactions are occurring. Catalysts are used in manufacturing everything from stain remover to rocket fuel; they make production more efficient by facilitating chemical reactions. Each catalyst being studied is only about 200 nanometers in

  1. Enhanced thermal and gas flow performance in a three-way catalytic

    Broader source: Energy.gov (indexed) [DOE]

    converter through use of insulation within the ceramic monolith | Department of Energy Emissions performance comparison of conventional catalytic converter with multi-channel catalytic converter (ceramic fiber insulation layers introduced into ceramic monolith of three-way catalytic converter) PDF icon deer11_ley.pdf More Documents & Publications NH3 generation over commercial Three-Way Catalysts and Lean-NOx Traps Emissions Control for Lean Gasoline Engines Monolithic Metal Oxide based

  2. MODELING ASSUMPTIONS FOR THE ADVANCED TEST REACTOR FRESH FUEL SHIPPING CONTAINER

    SciTech Connect (OSTI)

    Rick J. Migliore

    2009-09-01

    The Advanced Test Reactor Fresh Fuel Shipping Container (ATR FFSC) is currently licensed per 10 CFR 71 to transport a fresh fuel element for either the Advanced Test Reactor, the University of Missouri Research Reactor (MURR), or the Massachusetts Institute of Technology Research Reactor (MITR-II). During the licensing process, the Nuclear Regulatory Commission (NRC) raised a number of issues relating to the criticality analysis, namely (1) lack of a tolerance study on the fuel and packaging, (2) moderation conditions during normal conditions of transport (NCT), (3) treatment of minor hydrogenous packaging materials, and (4) treatment of potential fuel damage under hypothetical accident conditions (HAC). These concerns were adequately addressed by modifying the criticality analysis. A tolerance study was added for both the packaging and fuel elements, full-moderation was included in the NCT models, minor hydrogenous packaging materials were included, and fuel element damage was considered for the MURR and MITR-II fuel types.

  3. Effects of simulated rare earth recycling wastewaters on biological nitrification

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fujita, Yoshiko; Barnes, Joni; Eslamimanesh, Ali; Lencka, Malgorzata M.; Anderko, Andrzej; Riman, Richard E.; Navrotsky, Alexandra

    2015-07-16

    Current efforts to increase domestic availability of rare-earth element (REE) supplies by recycling and expanded ore processing efforts will result in increased generation of associated wastewaters. In some cases disposal to a sewage treatment plant may be favored but plant performance must be maintained. To assess the potential effects of such wastewaters on biological wastewater treatment, model nitrifying organisms Nitrosomonas europaea and Nitrobacter winogradskyi were exposed to simulated wastewaters containing varying levels of yttrium or europium (10, 50 and 100 ppm), and the REE extractant tributyl phosphate (TBP, at 0.1 g/L). Y and Eu additions above 10 ppm inhibited N.more » europaea activity, even when initially virtually all of the REE was insoluble. The provision of TBP together with Eu increased inhibition of nitrite production by the N. europaea, although TBP alone did not substantially alter nitrifying activity N. winogradskyi was more sensitive to the stimulated wastewaters, with even 10 ppm Eu or Y inducing significant inhibition, and a complete shutdown of nitrifying activity occurred in the presence of the TBP. To analyze the availability of REEs in aqueous solutions, REE solubility has been calculated using the previously developed MSE (Mixed-Solvent Electrolyte) thermodynamic model. The model calculations reveal a strong pH dependence of solubility, which is typically controlled by the precipitation of REE hydroxides but may also be influenced by the formation of a phosphate phase.« less

  4. Hybrid permanent magnet quadrupoles for the Recycler Ring at Fermilab

    SciTech Connect (OSTI)

    Brown, B.C.; Pruss, S.M.; Foster, G.W.; Glass, H.D.; Harding, D.J.; Jackson, G.R.; May, M.R.; Nicol, T.H.; Ostiguy, J.-F.; Schlabach, R.; Volk, J.T.

    1997-10-01

    Hybrid Permanent Magnet Quadrupoles are used in several applications for the Fermilab Recycler Ring and associated beam transfer lines. Most of these magnets use a 0.6096 m long iron shell and provide integrated gradients up to 1.4 T-m/m with an iron pole tip radius of 41.6 mm. A 58.4 mm pole radius design is also required. Bricks of 25. 4 mm thick strontium ferrite supply the flux to the back of the pole to produce the desired gradients (0.6 to 2.75 T/m). For temperature compensation, Ni-Fe alloy strips are interspersed between ferrite bricks to subtract flux in a temperature dependent fashion. Adjustments of the permeance of each pole using iron between the pole and the flux return shell permits the matching of pole potentials. Magnetic potentials of the poles are adjusted to the desired value to achieve the prescribed strength and field uniformity based on rotating coil harmonic measurements. Procurement, fabrication, pole potential adjustment, and measured fields will be reported.

  5. Effects of simulated rare earth recycling wastewaters on biological nitrification

    SciTech Connect (OSTI)

    Fujita, Yoshiko; Barnes, Joni; Eslamimanesh, Ali; Lencka, Malgorzata M.; Anderko, Andrzej; Riman, Richard E.; Navrotsky, Alexandra

    2015-07-16

    Current efforts to increase domestic availability of rare-earth element (REE) supplies by recycling and expanded ore processing efforts will result in increased generation of associated wastewaters. In some cases disposal to a sewage treatment plant may be favored but plant performance must be maintained. To assess the potential effects of such wastewaters on biological wastewater treatment, model nitrifying organisms Nitrosomonas europaea and Nitrobacter winogradskyi were exposed to simulated wastewaters containing varying levels of yttrium or europium (10, 50 and 100 ppm), and the REE extractant tributyl phosphate (TBP, at 0.1 g/L). Y and Eu additions above 10 ppm inhibited N. europaea activity, even when initially virtually all of the REE was insoluble. The provision of TBP together with Eu increased inhibition of nitrite production by the N. europaea, although TBP alone did not substantially alter nitrifying activity N. winogradskyi was more sensitive to the stimulated wastewaters, with even 10 ppm Eu or Y inducing significant inhibition, and a complete shutdown of nitrifying activity occurred in the presence of the TBP. To analyze the availability of REEs in aqueous solutions, REE solubility has been calculated using the previously developed MSE (Mixed-Solvent Electrolyte) thermodynamic model. The model calculations reveal a strong pH dependence of solubility, which is typically controlled by the precipitation of REE hydroxides but may also be influenced by the formation of a phosphate phase.

  6. Circulating fluidized-bed boiler makes inroads for waste recycling

    SciTech Connect (OSTI)

    1995-09-01

    Circulating fluidized-bed (CFB) boilers have ben used for years in Scandinavia to burn refuse-derived fuel (RDF). Now, Foster Wheeler Power Systems, Inc., (Clinton, N.J.) is bringing the technology to the US. Touted as the world`s largest waste-to-energy plant to use CFB technology, the Robbins (III.) Resource Recovery Facility will have the capacity to process 1,600 tons/d of municipal solid waste (MSW) when it begins operation in early 1997. The facility will have two materials-separation and RDF-processing trains, each with dual trommel screens, magnetic and eddy current separators, and shredders. About 25% of the incoming MSW will be sorted and removed for recycling, while 75% of it will be turned into fuel, with a heat value of roughly 6,170 btu/lb. Once burned in the twin CFB boilers the resulting steam will be routed through a single turbine generator to produce 50,000 mW of electric power.

  7. Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them

    DOE Patents [OSTI]

    Schwartz, Michael; White, James H.; Sammells, Anthony F.

    2001-01-01

    A process for production of synthesis gas employing a catalytic membrane reactor wherein the membrane comprises a mixed metal oxide material.

  8. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pyrolysis | Department of Energy In-Situ Catalytic Fast Pyrolysis Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils, which can be used to produce biofuel blendstocks. PDF icon Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis More Documents & Publications Bioenergy Technologies Office R&D Pathways: Ex-Situ

  9. Hydrocarbon selective catalytic reduction catalyst for NO.sub.x emissions control

    DOE Patents [OSTI]

    Furbeck, Howard; Koermer, Gerald; Moini, Ahmad

    2016-04-12

    The present disclosure provides an AgBi catalyst over alumina suitable for performing hydrocarbon selective catalytic reduction (HC-SCR).

  10. Enhanced thermal and gas flow performance in a three-way catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhanced thermal and gas flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith Emissions performance comparison of conventional ...

  11. Measurement of diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol

    Broader source: Energy.gov [DOE]

    Evaluation and comparison of the measurements of diesel solid nanoparticle emissions using the European Particle Measurement Programme (PMP) system and catalytic stripper

  12. Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber ...

  13. Modulating resonance behaviors by noise recycling in bistable systems with time delay

    SciTech Connect (OSTI)

    Sun, Zhongkui Xu, Wei; Yang, Xiaoli; Xiao, Yuzhu

    2014-06-01

    In this paper, the impact of noise recycling on resonance behaviors is studied theoretically and numerically in a prototypical bistable system with delayed feedback. According to the interior cooperating and interacting activity of noise recycling, a theory has been proposed by reducing the non-Markovian problem into a two-state model, wherein both the master equation and the transition rates depend on not only the current state but also the earlier two states due to the recycling lag and the feedback delay. By virtue of this theory, the formulae of the power spectrum density and the linear response function have been found analytically. And the theoretical results are well verified by numerical simulations. It has been demonstrated that both the recycling lag and the feedback delay play a crucial role in the resonance behaviors. In addition, the results also suggest an alternative scheme to modulate or control the coherence or stochastic resonance in bistable systems with time delay.

  14. R&D Progress on Recovery/Recycle of Zirconium from Used Fuel...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Conference: R&D Progress on RecoveryRecycle of Zirconium from Used Fuel Cladding Citation Details In-Document Search Title: R&D Progress on ...

  15. Almost 20 years of recycling makes a big difference | Y-12 National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Almost 20 years of ... Almost 20 years of recycling makes a big difference Posted: January 16, 2013 - 2:00pm Thanks to a Y-12 National Security Complex aluminum beverage can ...

  16. EECBG Success Story: New Choctaw Nation Recycling Center Posts Quick Results

    Broader source: Energy.gov [DOE]

    The Choctaw Nation in Oklahoma used approximately $800,000 in Energy Efficiency and Conservation Block Grant funding to build a state-of-the-art recycling center and improve stewardship of the land and environment. Learn more.

  17. Flashlamp radiation recycling for enhanced pumping efficiency and reduced thermal load

    DOE Patents [OSTI]

    Jancaitis, Kenneth S.; Powell, Howard T.

    1989-01-01

    A method for recycling laser flashlamp radiation in selected wavelength ranges to decrease thermal loading of the solid state laser matrix while substantially maintaining the pumping efficiency of the flashlamp.

  18. Development of superior asphalt recycling agency: Phase 1, Technical feasibility. Technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Glover, C.J.; Davison, R.R.; Lin, Moon-Sun; Chaffin, J.; Liu, Meng; Eckhardt, C.

    1996-04-01

    About every 12 years, asphalt roads must be reworked, and this is usually done by placing thick layers (hot-mix overlays) of new material on top of failed material, resulting in considerable waste of material and use of new asphalt binder. A good recycling agent is needed, not only to reduce the viscosity of the aged material but also to restore compatibility. Objective is to establish the technical feasibility (Phase I) of determining the specifications and operating parameters for producing high quality recycling agents which will allow most/all the old asphalt-based road material to be recycled. It is expected that supercritical fractionation can be used. The advanced road aging simulation procedure will be used to study aging of blends of old asphalt and recycling agents.

  19. Hunting for Big Bang neutrinos that could provide fresh insight on the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    origin of the universe | Princeton Plasma Physics Lab Hunting for Big Bang neutrinos that could provide fresh insight on the origin of the universe Like "detecting a heartbeat in an arena" full of people By John Greenwald March 11, 2016 Tweet Widget Google Plus One Share on Facebook Princeton physicist Chris Tully in the PTOLEMY laboratory. Behind him are powerful superconducting magnets on either side of the vacuum chamber. (Photo by Elle Starkman/Office of Communications)

  20. Environmental Levels Of 129I Present In Bovine Thyroid And Fresh Water In Argentina

    SciTech Connect (OSTI)

    Negri, A. E.; Arazi, A.; Carnellia, P. F. F.; Barbara, E. de; Figueira, J. M.; Fimiani, L.; Heimanna, D. M.; Zalazara, L.; Fernandez Niello, J.; La Gamma, A. M.; Wallner, A.

    2010-08-04

    Concentrations of {sup 129}I in bovine thyroid and fresh water samples coming from all over Argentina were analyzed by Accelerator Mass Spectrometry (AMS) and total iodine present in samples by Gas Chromatography (GC) and Inductive Coupled Plasma Mass Spectrometry (ICP-MS), respectively. Once we complete this study, it will be the first set of data of this kind from an extended region of the south American subcontinent.

  1. Close-To-Practice Assessment Of Meat Freshness With Metal Oxide Sensor Microarray Electronic Nose

    SciTech Connect (OSTI)

    Musatov, V. Yu.; Sysoev, V. V.; Sommer, M.; Kiselev, I.

    2009-05-23

    In this report we estimate the ability of KAMINA e-nose, based on a metal oxide sensor (MOS) microarray and Linear Discriminant Analysis (LDA) pattern recognition, to evaluate meat freshness. The received results show that, 1) one or two exposures of standard meat samples to the e-nose are enough for the instrument to recognize the fresh meat prepared by the same supplier with 100% probability; 2) the meat samples of two kinds, stored at 4 deg. C and 25 deg. C, are mutually recognized at early stages of decay with the help of the LDA model built independently under the e-nose training to each kind of meat; 3) the 3-4 training cycles of exposure to meat from different suppliers are necessary for the e-nose to build a reliable LDA model accounting for the supplier factor. This study approves that the MOS e-nose is ready to be currently utilised in food industry for evaluation of product freshness. The e-nose performance is characterized by low training cost, a confident recognition power of various product decay conditions and easy adjustment to changing conditions.

  2. Continuation of Research, Commercialization, and Workforce Development in the Polymer/Electronics Recycling Industry

    SciTech Connect (OSTI)

    Mel Croucher; Rakesh Gupta; Hota GangaRao; Darran Cairns; Jinzing Wang; Xiaodong Shi; Jason Linnell; Karen Facemyer; Doug Ritchie; Jeff Tucker

    2009-09-30

    The MARCEE Project was established to understand the problems associated with electronics recycling and to develop solutions that would allow an electronics recycling industry to emerge. While not all of the activities have been funded by MARCEE, but through private investment, they would not have occurred had the MARCEE Project not been undertaken. The problems tackled and the results obtained using MARCEE funds are discussed in detail in this report.

  3. Recycling end-of-life vehicles of the future. Final CRADA report.

    SciTech Connect (OSTI)

    Jody, B. J.; Pomykala, J. A.; Spangenberger, J. S.; Daniels, E.; Energy Systems

    2010-01-14

    Argonne National Laboratory (the Contractor) entered into a Cooperative Research and Development Agreement (CRADA) with the following Participants: Vehicle Recycling Partnership, LLC (VRP, which consists of General Motors [GM], Ford, and Chrysler), and the American Chemistry Council - Plastics Division (ACC-PD). The purpose of this CRADA is to provide for the effective recycling of automotive materials. The long-term goals are to (1) enable the optimum recycling of automotive materials, thereby obviating the need for legislative mandates or directives; (2) enable the recovery of automotive materials in a cost-competitive manner while meeting the performance requirements of the applications and markets for the materials; and (3) remove recycling barriers/reasons, real or perceived, to the use of advanced lightweighting materials or systems in future vehicles. The issues, technical requirements, and cost and institutional considerations in achieving that goal are complex and will require a concerted, focused, and systematic analysis, together with a technology development program. The scope and tasks of this program are derived from 'A Roadmap for Recycling End-of-Life Vehicles of the Future,' prepared in May 2001 for the DOE Office of Energy, Efficiency, and Renewable Energy (EERE)-Vehicle Technologies Program. The objective of this research program is to enable the maximum recycling of automotive materials and obsolete vehicles through the development and commercialization of technologies for the separation and recovery of materials from end-of-life vehicles (ELVs). The long-term goals are to (1) enable the optimum recycling of automotive materials, thereby obviating the need for legislative mandates or directives; (2) enable the recovery of automotive materials in a cost-competitive manner while meeting the performance requirements of the applications and markets for the materials; and (3) remove recycling barriers/reasons, real or perceived, to the use of advanced lightweighting materials or systems in future vehicles.

  4. 2009-08 " Establish an Effective Policy and Funding for Recycling of

    Office of Environmental Management (EM)

    Valuable Materials from Environmental Restoration Work at DOE Sites" | Department of Energy 8 " Establish an Effective Policy and Funding for Recycling of Valuable Materials from Environmental Restoration Work at DOE Sites" 2009-08 " Establish an Effective Policy and Funding for Recycling of Valuable Materials from Environmental Restoration Work at DOE Sites" The intent of this Recommendation is to provide the United States with a policy to effectively utilize the

  5. A High-Performance Recycling Solution for PolystyreneAchieved by the

    Office of Scientific and Technical Information (OSTI)

    Synthesis of Renewable Poly(thioether) Networks Derived from D -Limonene (Journal Article) | SciTech Connect A High-Performance Recycling Solution for PolystyreneAchieved by the Synthesis of Renewable Poly(thioether) Networks Derived from D -Limonene Citation Details In-Document Search Title: A High-Performance Recycling Solution for PolystyreneAchieved by the Synthesis of Renewable Poly(thioether) Networks Derived from D -Limonene Authors: Hearon, M K ; Nash, L D ; Rodriguez, J N ;

  6. A new paradigm: near-complete recycling of spent fuel - A path to sustainable nuclear energy

    SciTech Connect (OSTI)

    Del Cul, Guillermo D.; Spencer, Barry B.; Collins, Emory D.

    2007-07-01

    Recent studies indicate that maximized recycling, where more than 95% of the components of spent nuclear fuel are reused, can be economically justified and can reduce the mass of waste products by a substantial amount. The potentially removable and reusable components include the uranium, zirconium from the cladding, structural hardware, certain noble metal fission products, and the transuranic radionuclides. The approach to maximizing recycle and minimizing emissions and wastes should improve public acceptance of nuclear energy. (authors)

  7. EERE Success Story-North Dakota: EERE-Funded Project Recycles Energy,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generates Electricity | Department of Energy North Dakota: EERE-Funded Project Recycles Energy, Generates Electricity EERE Success Story-North Dakota: EERE-Funded Project Recycles Energy, Generates Electricity June 17, 2014 - 2:58pm Addthis Blaise Energy Inc. is using a Renewable Energy Market Development grant, funded by EERE, to demonstrate the commercial viability of its Flare Gas Micro-turbine. The microturbine pilot project places generators at oil production well sites to transform

  8. Method of recycling lithium borate to lithium borohydride through methyl borate

    DOE Patents [OSTI]

    Filby, Evan E.

    1977-01-01

    This invention provides a method for the recycling of lithium borate to lithium borohydride which can be reacted with water to generate hydrogen for utilization as a fuel. The lithium borate by-product of the hydrogen generation reaction is reacted with hydrogen chloride and water to produce boric acid and lithium chloride. The boric acid and lithium chloride are converted to lithium borohydride through a methyl borate intermediate to complete the recycle scheme.

  9. Eco-efficient waste glass recycling: Integrated waste management and green product development through LCA

    SciTech Connect (OSTI)

    Blengini, Gian Andrea, E-mail: blengini@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); CNR-IGAG, Institute of Environmental Geology and Geo-Engineering, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Busto, Mirko, E-mail: mirko.busto@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fantoni, Moris, E-mail: moris.fantoni@polito.it [DITAG - Department of Land, Environment and Geo-Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fino, Debora, E-mail: debora.fino@polito.it [DISMIC - Department of Materials Science and Chemical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy)

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer A new eco-efficient recycling route for post-consumer waste glass was implemented. Black-Right-Pointing-Pointer Integrated waste management and industrial production are crucial to green products. Black-Right-Pointing-Pointer Most of the waste glass rejects are sent back to the glass industry. Black-Right-Pointing-Pointer Recovered co-products give more environmental gains than does avoided landfill. Black-Right-Pointing-Pointer Energy intensive recycling must be limited to waste that cannot be closed-loop recycled. - Abstract: As part of the EU Life + NOVEDI project, a new eco-efficient recycling route has been implemented to maximise resources and energy recovery from post-consumer waste glass, through integrated waste management and industrial production. Life cycle assessment (LCA) has been used to identify engineering solutions to sustainability during the development of green building products. The new process and the related LCA are framed within a meaningful case of industrial symbiosis, where multiple waste streams are utilised in a multi-output industrial process. The input is a mix of rejected waste glass from conventional container glass recycling and waste special glass such as monitor glass, bulbs and glass fibres. The green building product is a recycled foam glass (RFG) to be used in high efficiency thermally insulating and lightweight concrete. The environmental gains have been contrasted against induced impacts and improvements have been proposed. Recovered co-products, such as glass fragments/powders, plastics and metals, correspond to environmental gains that are higher than those related to landfill avoidance, whereas the latter is cancelled due to increased transportation distances. In accordance to an eco-efficiency principle, it has been highlighted that recourse to highly energy intensive recycling should be limited to waste that cannot be closed-loop recycled.

  10. LWR First Recycle of TRU with Thorium Oxide for Transmutation and Cross

    Office of Scientific and Technical Information (OSTI)

    Sections (Technical Report) | SciTech Connect LWR First Recycle of TRU with Thorium Oxide for Transmutation and Cross Sections Citation Details In-Document Search Title: LWR First Recycle of TRU with Thorium Oxide for Transmutation and Cross Sections Thorium has been considered as an option to uranium-based fuel, based on considerations of resource utilization (thorium is approximately three times more plentiful than uranium) and as a result of concerns about proliferation and waste

  11. LWR First Recycle of TRU with Thorium Oxide for Transmutation and Cross

    Office of Scientific and Technical Information (OSTI)

    Sections (Technical Report) | SciTech Connect LWR First Recycle of TRU with Thorium Oxide for Transmutation and Cross Sections Citation Details In-Document Search Title: LWR First Recycle of TRU with Thorium Oxide for Transmutation and Cross Sections Thorium has been considered as an option to uranium-based fuel, based on considerations of resource utilization (thorium is approximately three times more plentiful than uranium) and as a result of concerns about proliferation and waste

  12. Demonstration of Advanced Technologies for Multi-Load Washers in Hospitality and Healthcare -- Wastewater Recycling Technology

    SciTech Connect (OSTI)

    Boyd, Brian K.; Parker, Graham B.; Petersen, Joseph M.; Sullivan, Greg; Goetzler, W.; Foley, K. J.; Sutherland, T. A.

    2014-08-14

    The objective of this demonstration project was to evaluate market-ready retrofit technologies for reducing the energy and water use of multi-load washers in healthcare and hospitality facilities. Specifically, this project evaluated laundry wastewater recycling technology in the hospitality sector and ozone laundry technology in both the healthcare and hospitality sectors. This report documents the demonstration of a wastewater recycling system installed in the Grand Hyatt Seattle.

  13. Catalytic combustor for integrated gasification combined cycle power plant

    DOE Patents [OSTI]

    Bachovchin, Dennis M.; Lippert, Thomas E.

    2008-12-16

    A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

  14. Intensified Fischer-Tropsch Synthesis Process with Microchannel Catalytic Reactors

    SciTech Connect (OSTI)

    Cao, Chunshe; Hu, Jianli; Li, Shari; Wilcox, Wayne A.; Wang, Yong

    2009-02-28

    A microchannel catalytic reactor with improved heat and mass transport has been used for Fischer-Tropsch synthesis to produce fuels and chemicals. This type of novel reactor takes advantages of highly active and selective catalysts with increased site density so that the FT synthesis process can be intensified. It was demonstrated that this microchannel reactor based process can be carried out at gas hourly space velocity (GHSV) as high as 60,000 hr-1 to achieve greater than 60% of one-pass CO conversion while maintaining low methane selectivity (<10%) and high chain growth probability(>0.9). Such superior FT synthesis performance has not ever been reported in the prior open literatures. The overall productivity to heavy hydrocarbons has been significantly improved over the conventional reactor technology. In this study, performance data were obtained in a wide range of pressure (10atm-35atm) and hydrogen to carbon monoxide ratio (1-2.5). The catalytic system was characterized by BET, scanning electron microcopy (SEM), transmission electron microcopy(TEM), and H2 chemisorption. A three dimensional pseudo-homogeneous model were used to simulate temperature profiles in the exothermic reaction system in order to optimize the reactor design and intensify the synthesis process. Intraparticle non-isothermal characteristics are also analyzed for the FT synthesis catalyst.

  15. Still the same after all these years: Santa Rosa`s curbside recycling model

    SciTech Connect (OSTI)

    Egan, K.

    1997-10-01

    When Santa Rosa, located north of San Francisco, first began its recycling program in 1977, it was no different from the other fledgling curbside recycling programs in the state. Back then, residents collected recyclables in their homes and put them out on the curb each week next to the garbage cans in whatever container they could find, whether it was a paper grocery bag or a cardboard box. The city`s pre-bin recycling program had a participation rate of about 25%. Then in 1978, with the firm`s help, Empire officials came up with the idea of providing recycling bins to residents. The program planners asked residents to source-separate their recyclables and then put the metals (including steel, tin, and aluminum); all three glass colors (brown, green, and clear); and newspaper in three individual bins. A few weeks after city officials distributed the bins to residents, the program showed a participation rate of 77%, indicating to Clark that the bins were necessary to significantly increase public awareness of the program.

  16. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, W.Y.

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide to precipitate silicon constituents, the pH of the resultant solution is increased, preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  17. Short residence time coal liquefaction process including catalytic hydrogenation

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-05-18

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone, the hydrogen pressure in the preheating-reaction zone being at least 1,500 psig (105 kg/cm[sup 2]), reacting the slurry in the preheating-reaction zone at a temperature in the range of between about 455 and about 500 C to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid to substantially immediately reduce the temperature of the reaction effluent to below 425 C to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C[sub 5]-454 C is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent and recycled as process solvent. The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance. 6 figs.

  18. Short residence time coal liquefaction process including catalytic hydrogenation

    DOE Patents [OSTI]

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-05-18

    Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm.sup.2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455.degree. and about 500.degree. C. to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425.degree. C. to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C.sub.5 -454.degree. C. is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent (83) and recycled as process solvent (16). The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance.

  19. Recycling of non-metallic fractions from waste electrical and electronic equipment (WEEE): A review

    SciTech Connect (OSTI)

    Wang, Ruixue; Xu, Zhenming

    2014-08-15

    Highlights: • NMFs from WEEE were treated by incineration or land filling in the past. • Environmental risks such as heavy metals and BFRs will be the major problems during the NMFs recycling processes. • Methods and technologies of recycling the two types of NMFs from WEEE, plastics, glasses are reviewed. • More environmental impact assessment should be carried out to evaluate the environmental risks of the recycling products. - Abstract: The world’s waste electrical and electronic equipment (WEEE) consumption has increased incredibly in recent decades, which have drawn much attention from the public. However, the major economic driving force for recycling of WEEE is the value of the metallic fractions (MFs). The non-metallic fractions (NMFs), which take up a large proportion of E-wastes, were treated by incineration or landfill in the past. NMFs from WEEE contain heavy metals, brominated flame retardant (BFRs) and other toxic and hazardous substances. Combustion as well as landfill may cause serious environmental problems. Therefore, research on resource reutilization and safe disposal of the NMFs from WEEE has a great significance from the viewpoint of environmental protection. Among the enormous variety of NMFs from WEEE, some of them are quite easy to recycle while others are difficult, such as plastics, glass and NMFs from waste printed circuit boards (WPCBs). In this paper, we mainly focus on the intractable NMFs from WEEE. Methods and technologies of recycling the two types of NMFs from WEEE, plastics, glass are reviewed in this paper. For WEEE plastics, the pyrolysis technology has the lowest energy consumption and the pyrolysis oil could be obtained, but the containing of BFRs makes the pyrolysis recycling process problematic. Supercritical fluids (SCF) and gasification technology have a potentially smaller environmental impact than pyrolysis process, but the energy consumption is higher. With regard to WEEE glass, lead removing is requisite before the reutilization of the cathode ray tube (CRT) funnel glass, and the recycling of liquid crystal display (LCD) glass is economically viable for the containing of precious metals (indium and tin). However, the environmental assessment of the recycling process is essential and important before the industrialized production stage. For example, noise and dust should be evaluated during the glass cutting process. This study could contribute significantly to understanding the recycling methods of NMFs from WEEE and serve as guidance for the future technology research and development.

  20. Comparing urban solid waste recycling from the viewpoint of urban metabolism based on physical input-output model: A case of Suzhou in China

    SciTech Connect (OSTI)

    Liang Sai; Zhang Tianzhu

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer Impacts of solid waste recycling on Suzhou's urban metabolism in 2015 are analyzed. Black-Right-Pointing-Pointer Sludge recycling for biogas is regarded as an accepted method. Black-Right-Pointing-Pointer Technical levels of reusing scrap tires and food wastes should be improved. Black-Right-Pointing-Pointer Other fly ash utilization methods should be exploited. Black-Right-Pointing-Pointer Secondary wastes from reusing food wastes and sludge should be concerned. - Abstract: Investigating impacts of urban solid waste recycling on urban metabolism contributes to sustainable urban solid waste management and urban sustainability. Using a physical input-output model and scenario analysis, urban metabolism of Suzhou in 2015 is predicted and impacts of four categories of solid waste recycling on urban metabolism are illustrated: scrap tire recycling, food waste recycling, fly ash recycling and sludge recycling. Sludge recycling has positive effects on reducing all material flows. Thus, sludge recycling for biogas is regarded as an accepted method. Moreover, technical levels of scrap tire recycling and food waste recycling should be improved to produce positive effects on reducing more material flows. Fly ash recycling for cement production has negative effects on reducing all material flows except solid wastes. Thus, other fly ash utilization methods should be exploited. In addition, the utilization and treatment of secondary wastes from food waste recycling and sludge recycling should be concerned.

  1. MEMS-based fuel cells with integrated catalytic fuel processor and method thereof

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.; Upadhye, Ravindra S.; Havstad, Mark A.

    2011-08-09

    Described herein is a means to incorporate catalytic materials into the fuel flow field structures of MEMS-based fuel cells, which enable catalytic reforming of a hydrocarbon based fuel, such as methane, methanol, or butane. Methods of fabrication are also disclosed.

  2. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as

    Broader source: Energy.gov (indexed) [DOE]

    Reductants | Department of Energy 5 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_marshall.pdf More Documents & Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis

  3. Fabrication of fuel cell electrodes and other catalytic structures

    DOE Patents [OSTI]

    Smith, J.L.

    1987-02-11

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte. 1 fig.

  4. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  5. Selective catalytic synthesis of functional allenes, cyclopentenones and oxolenes

    SciTech Connect (OSTI)

    Darcel, C.; Bruneau, C.; Dixneuf, P.H.

    1995-12-31

    The most powerful method to produce allene derivatives consists in the selective activation of prop-2-yn-1-carbonates by a Pd(0) catalyst, via allenyl palladium(II) intermediate. This strategy has been used for the selective catalytic synthesis of derivatives. The alkynyl cyclic carbonates have the advantage to be readily prepared directly from CO{sub 2} and contain both propargylic and homopropargylic functionalities. Their activation, under mild conditions, by palladium(0) catalysts, associated with the suitable phosphine ligand, can be oriented to selectively prepare either alkynyl {alpha}-hydroxy allenes, 5-hydroxy alka-2,3-dienoates, functional cyclopentenones or oxolenes via cross coupling, mono-carbonylation, dicarbonylation and Heck-Type reactions respectively.

  6. Methods and apparatus for catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

    2012-08-14

    Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  7. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  8. Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels

    SciTech Connect (OSTI)

    Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

    2013-01-01

    Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

  9. Method For Selective Catalytic Reduction Of Nitrogen Oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L.; Gardner, Timothy J.; McLaughlin, Linda I.

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  10. Method for selective catalytic reduction of nitrogen oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L.; Gardner, Timothy J.; McLaughlin, Linda I.

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  11. Coal hydrogenation and deashing in ebullated bed catalytic reactor

    DOE Patents [OSTI]

    Huibers, Derk T. A.; Johanson, Edwin S.

    1983-01-01

    An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

  12. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2006-02-14

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  13. Collection and recycling of electronic scrap: A worldwide overview and comparison with the Brazilian situation

    SciTech Connect (OSTI)

    Reis de Oliveira, Camila; Moura Bernardes, Andrea; Gerbase, Annelise Engel

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer Review of the different e-waste collection systems and recycling processes. Black-Right-Pointing-Pointer We present the e-waste collection systems used in Europe and in the US. Black-Right-Pointing-Pointer We present e-waste collection systems used in Asia and Latin America. Black-Right-Pointing-Pointer E-waste management between developed and developing countries is very different. Black-Right-Pointing-Pointer We made a comparison of the world situation to the current Brazilian reality. - Abstract: Recycling and the related issue of sustainable development are increasing in importance around the world. In Brazil, the new National Policy on Solid Wastes has prompted discussion on the future of electronic waste (e-waste). Over the last 10 years, different e-waste collection systems and recycling processes have been applied globally. This paper presents the systems used in different countries and compares the world situation to the current Brazilian reality. To establish a recycling process, it is necessary to organize efficient collection management. The main difficulty associated with the implementation of e-waste recycling processes in Brazil is the collection system, as its efficiency depends not only on the education and cooperation of the people but also on cooperation among industrial waste generators, distributors and the government. Over half a million waste pickers have been reported in Brazil and they are responsible for the success of metal scrap collection in the country. The country also has close to 2400 companies and cooperatives involved in recycling and scrap trading. On the other hand, the collection and recycling of e-waste is still incipient because e-wastes are not seen as valuable in the informal sector. The Brazilian challenge is therefore to organize a system of e-waste management including the informal sector without neglecting environmentally sound management principles.

  14. Catalytic Synthesis of Oxygenates: Mechanisms, Catalysts and Controlling Characteristics

    SciTech Connect (OSTI)

    Klier, Kamil; Herman, Richard G

    2005-11-30

    This research focused on catalytic synthesis of unsymmetrical ethers as a part of a larger program involving oxygenated products in general, including alcohols, ethers, esters, carboxylic acids and their derivatives that link together environmentally compliant fuels, monomers, and high-value chemicals. The catalysts studied here were solid acids possessing strong Brnsted acid functionalities. The design of these catalysts involved anchoring the acid groups onto inorganic oxides, e.g. surface-grafted acid groups on zirconia, and a new class of mesoporous solid acids, i.e. propylsulfonic acid-derivatized SBA-15. The former catalysts consisted of a high surface concentration of sulfate groups on stable zirconia catalysts. The latter catalyst consists of high surface area, large pore propylsulfonic acid-derivatized silicas, specifically SBA-15. In both cases, the catalyst design and synthesis yielded high concentrations of acid sites in close proximity to one another. These materials have been well-characterization in terms of physical and chemical properties, as well as in regard to surface and bulk characteristics. Both types of catalysts were shown to exhibit high catalytic performance with respect to both activity and selectivity for the bifunctional coupling of alcohols to form ethers, which proceeds via an efficient SN2 reaction mechanism on the proximal acid sites. This commonality of the dual-site SN2 reaction mechanism over acid catalysts provides for maximum reaction rates and control of selectivity by reaction conditions, i.e. pressure, temperature, and reactant concentrations. This research provides the scientific groundwork for synthesis of ethers for energy applications. The synthesized environmentally acceptable ethers, in part derived from natural gas via alcohol intermediates, exhibit high cetane properties, e.g. methylisobutylether with cetane No. of 53 and dimethylether with cetane No. of 55-60, or high octane properties, e.g. diisopropylether with blending octane No. of 105, and can replace aromatics in liquid fuels.

  15. Catalytic gasification studies in a pressurized fluid-bed unit

    SciTech Connect (OSTI)

    Mudge, L.K.; Baker, E.G.; Mitchell, D.H.; Robertus, R.J.; Brown, M.D.

    1983-07-01

    The purpose of the project is to evaluate the technical and economic feasibility of producing specific gas products via the catalytic gasification of biomass. This report presents the results of research conducted from October 1980 to November 1982. In the laboratory scale studis, active catalysts were developed for generation of synthesis gases from wood by steam gasification. A trimetallic catalyst, Ni-Co-Mo on silica-alumina doped with 2 wt % Na, was found to retain activity indefinitely for generation of a methanol synthesis gas from wood at 1380/sup 0/F (750/sup 0/C) and 1 atm (100 kPa) absolute pressure. Catalysts for generation of a methane-rich gas were deactivated rapidly and could not be regenerated as required for economic application. Sodium carbonate and potassium carbonate were effective as catalysts for conversion of wood to synthesis gases and methane-rich gas and should be economically viable. Catalytic gasification conditions were found to be suitable for processing of alternative feedstocks: bagasse, alfalfa, rice hulls, and almond hulls. The PDU was operated successfully at absolute pressures of up to 10 atm (1000 kPa) and temperatures of up to 1380/sup 0/F (750/sup 0/C). Yields of synthesis gases at elevated pressure were greater than those used for previous economic evaluations. A trimetallic catalyst, Ni-Cu-Mo on silica-alumina, did not display a long life as did the doped trimetallic catalyst used in laboratory studies. A computer program for a Radio Shack TRS-80 Model I microcomputer was developed to evaluate rapidly the economics of producing either methane or methanol from wood. The program is based on economic evaluations reported in previous studies. Improved yields from the PDU studies were found to result in a reduction of about 9 cents/gal in methanol cost.

  16. Polycyclic aromatic hydrocarbons in fresh and smoked fish samples from three Nigerian cities

    SciTech Connect (OSTI)

    Akpan, V.; Lodovici, M.; Dolara, P. )

    1994-08-01

    Nigeria is a major producer of crude oil in sub-Saharan Africa. In-shore and off-shore wells are located in richly watered creeks in the southern part of the country. Although published data on environmental impact assessment of the petroleum industry in Nigeria are lacking, there is a growing concern about the possible contamination of estuarine and coastal waters and of marine species by polycyclic aromatic hydrocarbon (PAHs). PAHs are ubiquitous priority pollutants that occur naturally in crude oil, automobile exhaust emissions and smoke condensates from incomplete combustion of carbonaceous materials. PAHs with high molecular weight are less readily biodegraded by indigenous microorganisms in some regions, and given their marked hydrophobic characteristics, may persist in the aqueous environment, thus contaminating the food chain by bioaccumulating in aquatic species like fish and mussels. Major Nigerian oil wells are located in the vicinity of breeding and harvesting sites serving the fresh-water fishing industry. Large hauls of fresh fish are normally consumed cooked in soups or smoke cured in handcrafted traditional ovens using freshly cut red mangrove (Rhizophora racemosa) wood as fuel. Though smoke curing is economical and may ensure longer conservation of fish, it undoubtedly increases the burden of PAHs in finished products as a result of partial charring and from smoke condensates or mangroves that also contain PAHs in measurable quantities as reported by Asita et al. (1991). Apart from PAHs analyzed by Emerole (1980) in smoked food samples from Ibadan using simple analytical methods, those from industrial and other anthropogenic sources have rarely been analyzed in Nigeria. We tried therefore to update the data and address this discrepancy. 14 refs., 4 figs., 2 tabs.

  17. Recycling plastic scrap: Injection molding. (Latest citations from the Rubber and Plastics Research Association database). Published Search

    SciTech Connect (OSTI)

    NONE

    1997-02-01

    The bibliography contains citations concerning the recycling of scrap plastic produced in the injection molding process. Plastic pellets made from scrap, that are used in the injection molding process, are also discussed. Recycling equipment and automated recycling systems are described. The reuse of plastic scrap culled from junk automobiles and packaging materials is discussed, and waste byproducts from polyurethane production are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  18. Recycling plastic scrap: Injection molding. (Latest citations from the Rubber and Plastics Research Association database). Published Search

    SciTech Connect (OSTI)

    NONE

    1996-04-01

    The bibliography contains citations concerning the recycling of scrap plastic produced in the injection molding process. Plastic pellets made from scrap, that are used in the injection molding process, are also discussed. Recycling equipment and automated recycling systems are described. The reuse of plastic scrap culled from junk automobiles and packaging materials is discussed, and waste byproducts from polyurethane production are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  19. Assessing recycling versus incineration of key materials in municipal waste: The importance of efficient energy recovery and transport distances

    SciTech Connect (OSTI)

    Merrild, Hanna; Larsen, Anna W.; Christensen, Thomas H.

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer We model the environmental impact of recycling and incineration of household waste. Black-Right-Pointing-Pointer Recycling of paper, glass, steel and aluminium is better than incineration. Black-Right-Pointing-Pointer Recycling and incineration of cardboard and plastic can be equally good alternatives. Black-Right-Pointing-Pointer Recyclables can be transported long distances and still have environmental benefits. Black-Right-Pointing-Pointer Paper has a higher environmental benefit than recyclables found in smaller amounts. - Abstract: Recycling of materials from municipal solid waste is commonly considered to be superior to any other waste treatment alternative. For the material fractions with a significant energy content this might not be the case if the treatment alternative is a waste-to-energy plant with high energy recovery rates. The environmental impacts from recycling and from incineration of six material fractions in household waste have been compared through life cycle assessment assuming high-performance technologies for material recycling as well as for waste incineration. The results showed that there are environmental benefits when recycling paper, glass, steel and aluminium instead of incinerating it. For cardboard and plastic the results were more unclear, depending on the level of energy recovery at the incineration plant, the system boundaries chosen and which impact category was in focus. Further, the environmental impact potentials from collection, pre-treatment and transport was compared to the environmental benefit from recycling and this showed that with the right means of transport, recyclables can in most cases be transported long distances. However, the results also showed that recycling of some of the material fractions can only contribute marginally in improving the overall waste management system taking into consideration their limited content in average Danish household waste.

  20. Hunting for Big Bang neutrinos that could provide fresh insight on the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    origin of the universe | Princeton Plasma Physics Lab Hunting for Big Bang neutrinos that could provide fresh insight on the origin of the universe Like "detecting a heartbeat in an arena" full of people By John Greenwald March 14, 2016 Tweet Widget Google Plus One Share on Facebook Chris Tully in the PTOLEMY laboratory. Behind him are powerful superconducting magnets on either side of the vacuum chamber. (Photo by Elle Starkman/Office of Communications) Chris Tully in the PTOLEMY