National Library of Energy BETA

Sample records for rechargeable electronics dehumidifiers

  1. Water-heating dehumidifier

    DOE Patents [OSTI]

    Tomlinson, John J.

    2006-04-18

    A water-heating dehumidifier includes a refrigerant loop including a compressor, at least one condenser, an expansion device and an evaporator including an evaporator fan. The condenser includes a water inlet and a water outlet for flowing water therethrough or proximate thereto, or is affixed to the tank or immersed into the tank to effect water heating without flowing water. The immersed condenser design includes a self-insulated capillary tube expansion device for simplicity and high efficiency. In a water heating mode air is drawn by the evaporator fan across the evaporator to produce cooled and dehumidified air and heat taken from the air is absorbed by the refrigerant at the evaporator and is pumped to the condenser, where water is heated. When the tank of water heater is full of hot water or a humidistat set point is reached, the water-heating dehumidifier can switch to run as a dehumidifier.

  2. Solar powered dehumidifier apparatus

    DOE Patents [OSTI]

    Jebens, Robert W.

    1980-12-30

    A thermally insulated light transmitting housing forms a chamber containing a desiccant and having a first gas port open to the ambient and a second gas port connected by a two way valve to a volume to be dried. Solar energy transmitted through the housing heats and dries the desiccant. The increased air pressure due to the heating of the volume to be dried causes the air from the volume to be expelled through the valve into the chamber. The desiccant is then cooled by shielding it from solar energy before the volume cools thereby increasing its moisture absorbing capacity. Then the volume is allowed to cool drawing dehumidified air through the desiccant and the valve into the volume to be dried. This cycle is then repeated.

  3. Water-Heating Dehumidifier - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Water-Heating Dehumidifier Oak Ridge National ... developed at ORNL dehumidifies air and then recycles heat to warm water in a water heater. ...

  4. Dehumidifying Heat Pipes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dehumidifying Heat Pipes Dehumidifying Heat Pipes In order to make a room comfortable in hot, humid climates, an air conditioner must lower the indoor humidity level as well as the air temperature. If an air conditioner fails to lower the humidity adequately, the air will be cool, but will feel uncomfortably damp. Inappropriately sized air conditioners are prone to this problem; large units quickly cool the air, but cycle off before they can properly dehumidify it. In extremely humid climates,

  5. NREL Tests Dehumidifiers, Defines Simplified Simulation Model...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    residential dehumidifiers results in practical performance curves for use in ... To help energy professionals more easily evaluate this technology for the market, National ...

  6. A Combined Water Heater, Dehumidifier, and Cooler (WHDC) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Combined Water Heater, Dehumidifier, and Cooler (WHDC) A Combined Water Heater, Dehumidifier, and Cooler (WHDC) Figure 1: The system model for the combined Water heater, ...

  7. Dehumidifiers

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) develops standardized data templates for reporting the results of tests conducted in accordance with current DOE test procedures. Templates may be used by third-party laboratories under contract with DOE that conduct testing in support of ENERGY STAR® verification, DOE rulemakings, and enforcement of the federal energy conservation standards.

  8. Measured Performance of Residential Dehumidifiers Under Cyclic Operation

    SciTech Connect (OSTI)

    Winkler, J.; Christensen, D.; Tomerlin, J.

    2014-01-01

    Residential construction practices are progressing toward higher levels of energy efficiency. A proven strategy to save energy is to simultaneously increase building insulation levels and reduce outdoor air infiltration. Overall, this strategy results in a shift in the mix of latent and sensible space conditioning loads, requiring proportionally more moisture to be removed compared to standard homes. In this project, researchers at the National Renewable Energy Laboratory (NREL) developed steady state performance maps to predict dehumidifier performance at a variety of indoor conditions. However, installed heating, ventilating, and air-conditioning (HVAC) equipment rarely operates at steady state. Part load performance testing of residential dehumidifiers is not mandated by current test standards. Therefore, the team tested the part load performance of four residential dehumidifiers in NRELs Advanced HVAC Systems Laboratory . The part load efficiency of each dehumidifier was measured under 13 cycling scenarios, and combined with NREL field data to develop part load fraction (PLF) performance curves under realistic cycling scenarios.

  9. A Combined Water Heater Dehumidifier and Cooler (WHDC)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combined Water Heater Dehumidifier and Cooler (WHDC) 2016 Building Technologies Office ... Project Outcome: - Develop a low-cost gas-fired water heat pump to meet the DOE MYPP 2020 ...

  10. Measured Performance of Residential Dehumidifiers Under Cyclic Operation

    SciTech Connect (OSTI)

    Winkler, J.; Christensen, D.; Tomerlin, J.

    2014-01-01

    Residential construction practices are progressing toward higher levels of energy efficiency. A proven strategy to save energy is to simultaneously increase building insulation levels and reduce outdoor air infiltration. Tight homes require intentional mechanical ventilation to ensure healthy indoor air. Overall, this strategy results in a shift in the mix of latent and sensible space conditioning loads, requiring proportionally more moisture to be removed compared to standard homes. There is currently not sufficient information available at a wide enough range of operating points to design dehumidification systems for high performance homes in hot-humid climates. The only industry information available on dehumidifier moisture removal and energy consumption are performance ratings conducted at a single test condition, which does not provide a full representation of dehumidifier operation under real-world conditions. Winkler et al. (2011) developed steady state performance maps to predict dehumidifier performance at a variety of indoor conditions. However, installed heating, ventilating, and air-conditioning (HVAC) equipment rarely operates at steady state. Part load performance testing of residential dehumidifiers is not mandated by current test standards. Therefore, we tested the part load performance of four residential dehumidifiers in the National Renewable Energy Laboratory's (NREL) Advanced HVAC Systems Laboratory . The part load efficiency of each dehumidifier was measured under 13 cycling scenarios, and combined with NREL field data to develop part load fraction (PLF) performance curves under realistic cycling scenarios.

  11. DOE Publishes Notice of Proposed Rulemaking Regarding the Compliance Date for the Dehumidifier Test Procedure

    Broader source: Energy.gov [DOE]

    The Department of Energy has published a notice of proposed rulemaking regarding the compliance date for the dehumidifier test procedure.

  12. ISSUANCE 2015-05-14: Energy Conservation Program: Energy Conservation Standards for Residential Dehumidifiers Notice of Proposed Rulemaking

    Office of Energy Efficiency and Renewable Energy (EERE)

    Energy Conservation Program: Energy Conservation Standards for Residential Dehumidifiers Notice of Proposed Rulemaking

  13. ISSUANCE 2015-01-27: Energy Conservation Program: Test Procedures for Dehumidifiers Supplemental Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Test Procedures for Dehumidifiers Supplemental Notice of Proposed Rulemaking

  14. Webinar: Energy Conservation Standards for Dehumidifiers; Availability of the Preliminary Technical Support Document

    Broader source: Energy.gov [DOE]

    DOE is conducting a public meeting and webinar for the availability of the preliminary technical support document regarding energy conservation standards for residential dehumidifiers. 79 FR 29380 ...

  15. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M.

    1980-01-01

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  16. Performance predictions of silica-gel desiccant dehumidifiers. Technical report No. 3

    SciTech Connect (OSTI)

    Mathiprakasam, B.; Lavan, Z.

    1980-01-01

    The analysis of a cross-cooled desiccant dehumidifier using silica gel in the form of sheets is described. This unit is the principal component of solar powered desiccant air conditioning system. The mathematical model has first been formulated describing the dynamics of the dehumidifier. The model leads to a system of nonlinear coupled heat and mass transfer equations for the sorption processes and linear heat transfer equations for the purging processes. The model accounts for the gas film resistance and for the moisture diffusion in the desiccant. The governing equations are solved by a finite difference scheme to obtain periodic steady state solutions. The accuracy of the theoretical predictions is ascertained by comparing them with the experimental results. The performance of the dehumidifier, for a chosen set of initial conditions and dehumidifier parameters, has also been given.

  17. Performance of dehumidifying heat exchangers with and without wetting coatings

    SciTech Connect (OSTI)

    Hong, K.; Webb, R.L.

    1999-11-01

    Limited previous work has shown that use of special hydrophilic coatings will provide lower air pressure drop in finned tube heat exchangers operated under dehumidifying conditions. However, no detailed work has been reported on the effect of different coating types, or different fin surface geometries on the wet pressure drop. In this study, wind tunnel tests were performed on three different fin geometries (wavy, lanced, and louver) under wet and dry conditions. All dehumidification tests were done for fully wet surface conditions. For each geometry, the tests were performed on uncoated and coated heat exchangers. For all three fin geometries, the wet-to-dry pressure drop ratio was 1.2 at 2.5 m/s frontal air velocity. The coatings have no influence on the wet or dry heat transfer coefficient. However, the wet surface heat transfer coefficient was 10 to 30% less than the dry heat transfer coefficient, depending on the particular fin geometry. The effect of the fin press oil on wet pressure drop was also studied. If the oil contains a surfactant, good temporary wetting can be obtained on an uncoated surface; however, this effect is quickly degraded as the oil is washed from the surface during wet operation. This work also provides a critical assessment of data reduction methods for wet surface operation, including calculation of the fin efficiency.

  18. Whole-Home Dehumidifiers: Field-Monitoring Study

    SciTech Connect (OSTI)

    Burke, Tom; Willem, Henry; Ni, Chun Chun; Stratton, Hannah; Whitehead, Camilla Dunham; Johnson, Russell

    2014-09-23

    Lawrence Berkeley National Laboratory (LBNL) initiated a WHD field-metering study to expand current knowledge of and obtain data on WHD operation and energy consumption in real-world applications. The field study collected real-time data on WHD energy consumption, along with information regarding housing characteristics, consumer behavior, and various outdoor conditions expected to affect WHD performance and efficiency. Although the metering study collected similar data regarding air conditioner operation, this report discusses only WHDs. The primary objectives of the LBNL field-metering study are to (1) expand knowledge of the configurations, energy consumption profiles, consumer patterns of use (e.g., relative humidity [RH] settings), and environmental parameters of whole-home dehumidification systems; and (2) develop distributions of hours of dehumidifier operation in four operating modes: off, standby, fan-only, and compressor (also called dehumidification mode). Profiling energy consumption entails documenting the power consumption, duration of power consumption in different modes, condensate generation, and properties of output air of an installed system under field conditions of varying inlet air temperature and RH, as well as system configuration. This profiling provides a more detailed and deeper understanding of WHD operation and its complexities. This report describes LBNL’s whole-home dehumidification field-metering study conducted at four homes in Wisconsin and Florida. The initial phase of the WHD field-metering study was conducted on one home in Madison, Wisconsin, from June to December of 2013. During a second phase, three Florida homes were metered from June to October of 2014. This report presents and examines data from the Wisconsin site and from the three Florida sites.

  19. FLUIDIC: Metal Air Recharged

    ScienceCinema (OSTI)

    Friesen, Cody

    2014-04-02

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  20. FLUIDIC: Metal Air Recharged

    SciTech Connect (OSTI)

    Friesen, Cody

    2014-03-07

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  1. 2014-05-05 Issuance: Test Procedures for Dehumidifiers; Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register notice of proposed rulemaking regarding test procedures for dehumidifiers, as issued by the Deputy Assistant Secretary for Energy Efficiency on May 2, 2014. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document.

  2. Rechargeable Heat Battery's Secret Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rechargeable Heat Battery Rechargeable Heat Battery's Secret Revealed Solar energy capture ... Contact: John Hules, JAHules@lbl.gov, +1 510 486 6008 2011-01-11-Heat-Battery.jpg A ...

  3. SERI Desiccant Cooling Test Facility. Status report. Preliminary data on the performance of a rotary parallel-passage silica-gel dehumidifier

    SciTech Connect (OSTI)

    Schultz, K.J.

    1986-04-01

    This report describes the SERI Desiccant Cooling Test Facility. The facility can test bench-scale rotary dehumidifiers over a wide range of controlled conditions. We constructed and installed in the test loop a prototype parallel-passage rotary dehumidifier that has spirally wound polyester tape coated with silica gel. The initial tests gave satisfactory results indicating that approximately 90% of the silica gel was active and the overall Lewis number of the wheel was near unity. The facility has several minor difficulties including an inability to control humidity satisfactorily and nonuniform and highly turbulent inlet velocities. To completely validate the facility requires a range of dehumidifier designs. Several choices are available including constructing a second parallel-passage dehumidifier with the passage spacing more uniform.

  4. Assessing Consumer Values and the Supply-Chain Market for the Integrated Water Heater/Dehumidifier

    SciTech Connect (OSTI)

    Ashdown, BG

    2005-01-11

    This paper presents a case study of the potential market for the dual-service residential integrated water heater/dehumidifier (WHD). Its principal purpose is to evaluate the extent to which this integrated appliance might penetrate the residential market sector, given current market trends, producer and consumer attributes, and technical parameters. The report's secondary purpose is to gather background information leading to a generic framework for conducting market analyses of technologies. This framework can be used to assess market readiness as well as factor preferred product attributes into the design to drive consumer demand for this product. This study also supports analysis for prototype design. A full market analysis for potential commercialization should be conducted after prototype development. The integrated WHD is essentially a heat-pump water heater (HPWH) with components and controls that allow dedicated dehumidification. Adequate residential humidity control is a growing issue for newly constructed residential homes, which are insulated so well that mechanical ventilation may be necessary to meet fresh air requirements. Leveraging its successful experience with the energy-efficient design improvement for the residential HPWH, the Oak Ridge National Laboratory's (ORNL's) Engineering Science and Technology Division's (ESTD's) Building Equipment Group designed a water-heating appliance that combines HPWH efficiency with dedicated dehumidification. This integrated appliance could be a low-cost solution for dehumidification and efficient electric water heating. ORNL is partnering with Western Carolina University, Asheville-Buncombe Technical Community College, American Carolina Stamping Company, and Clemson University to develop this appliance and assess its market potential. For practical purposes, consumers are indifferent to how water is heated but are very interested in product attributes such as initial first cost, operating cost, performance

  5. Technology Solutions Case Study: Improving Comfort in Hot-Humid Climates with a Whole-House Dehumidifier

    SciTech Connect (OSTI)

    2013-11-01

    In order to quantify the performance of a combined whole-house dehumidifier (WHD) AC system, researchers from the Consortium of Advanced Residential Buildings (CARB) team monitored the operation of two Lennox AC systems coupled with a Honeywell DH150 TrueDRY whole-house dehumidifier for a six-month period. By using a WHD to control moisture levels (latent cooling) and optimizing a central AC to control temperature (sensible cooling), improvements in comfort can be achieved while reducing utility costs. Indoor comfort for this study was defined as maintaining indoor conditions at below 60% RH and a humidity ratio of 0.012 lbm/lbm while at common dry bulb set point temperatures of 74-80F. In addition to enhanced comfort, controlling moisture to these levels can reduce the risk of other potential issues such as mold growth, pests, and building component degradation. Because a standard AC must also reduce dry bulb air temperature in order to remove moisture, a WHD is typically needed to support these latent loads when sensible heat removal is not desired.

  6. High Performance Binderless Electrodes for Rechargeable Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Performance Binderless Electrodes for Rechargeable Lithium Batteries National ... Electrode for fast-charging Lithium Ion Batteries, Accelerating Innovation Webinar ...

  7. Rechargeable Aluminum-Ion Batteries

    SciTech Connect (OSTI)

    Paranthaman, Mariappan Parans; Liu, Hansan; Sun, Xiao-Guang; Dai, Sheng; Brown, Gilbert M

    2015-01-01

    This chapter reports on the development of rechargeable aluminum-ion batteries. A possible concept of rechargeable aluminum/aluminum-ion battery based on low-cost, earth-abundant Al anode, ionic liquid EMImCl:AlCl3 (1-ethyl-3-methyl imidazolium chloroaluminate) electrolytes and MnO2 cathode has been proposed. Al anode has been reported to show good reversibility in acid melts. However, due to the problems in demonstrating the reversibility in cathodes, alternate battery cathodes and battery concepts have also been presented. New ionic liquid electrolytes for reversible Al dissolution and deposition are needed in the future for replacing corrosive EMImCl:AlCl3 electrolytes.

  8. Recharge Data for Hawaii Island

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Recharge data for Hawaii Island in shapefile format. The data are from the following sources: Whittier, R.B and A.I. El-Kadi. 2014. Human Health and Environmental Risk Ranking of On-Site Sewage Disposal systems for the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final, Prepared for Hawaii Dept. of Health, Safe Drinking Water Branch by the University of Hawaii, Dept. of Geology and Geophysics. Oki, D. S. 1999. Geohydrology and Numerical Simulation of the Ground-Water Flow System of Kona, Island of Hawaii. U.S. Water-Resources Investigation Report: 99-4073. Oki, D. S. 2002. Reassessment of Ground-water Recharge and Simulated Ground-Water Availability for the Hawi Area of North Kohala, Hawaii. U.S. Geological Survey Water-Resources Investigation report 02-4006.

  9. Improving Comfort in Hot-Humid Climates with a Whole-House Dehumidifier, Windermere, Florida (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-11-01

    Maintaining comfort in a home can be challenging in hot-humid climates. At the common summer temperature set point of 75 degrees F, the perceived air temperature can vary by 11 degrees F because higher indoor humidity reduces comfort. Often the air conditioner (AC) thermostat set point is lower than the desirable cooling level to try to increase moisture removal so that the interior air is not humid or "muggy." However, this method is not always effective in maintaining indoor relative humidity (RH) or comfort. In order to quantify the performance of a combined whole-house dehumidifier (WHD) AC system, researchers from the U.S. Department of Energy's Building America team Consortium of Advanced Residential Buildings (CARB) monitored the operation of two Lennox AC systems coupled with a Honeywell DH150 TrueDRY whole-house dehumidifier for a six-month period. By using a WHD to control moisture levels (latent cooling) and optimizing a central AC to control temperature (sensible cooling), improvements in comfort can be achieved while reducing utility costs. Indoor comfort for this study was defined as maintaining indoor conditions at below 60% RH and a humidity ratio of 0.012 lbm/lbm while at common dry bulb set point temperatures of 74 degrees -80 degrees F. In addition to enhanced comfort, controlling moisture to these levels can reduce the risk of other potential issues such as mold growth, pests, and building component degradation. Because a standard AC must also reduce dry bulb air temperature in order to remove moisture, a WHD is typically needed to support these latent loads when sensible heat removal is not desired.

  10. Understanding the Ultimate Battery Chemistry: Rechargeable Lithium/Air |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility The electronic charge density of a lithium oxide (Li2O) nanoparticle consists of 1500 atoms obtained from Density Functional Theory simulation. Kah Chun Lau (MSD, ANL), Aaron Knoll (MCS, ANL), Larry A Curtiss (MSD/CNM, ANL). Understanding the Ultimate Battery Chemistry: Rechargeable Lithium/Air PI Name: Jack Wells PI Email: wellsjc@ornl.gov Institution: Oak Ridge National Laboratory Allocation Program: INCITE Allocation Hours at ALCF: 25 Million Year:

  11. Rechargeable Nanoelectrofuels for Flow Batteries | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rechargeable Nanoelectrofuels for Flow Batteries Four-page general brochure describing a groundbreaking energy storage concept that may revolutionize the world of batteries PDF...

  12. Evapotranspiration Dynamics and Effects on Groundwater Recharge...

    Office of Scientific and Technical Information (OSTI)

    Vegetation type and health had a significant effect on the site water balance. Plant cover ... Heavy grazing increased groundwater recharge (PPT > ET over the 13-year period). ...

  13. GC GUIDANCE ON ELECTRIC VEHICLE RECHARGING STATIONS

    Office of Energy Efficiency and Renewable Energy (EERE)

    Several National Laboratory contractors have asked whether appropriated funds may be used to reimburse cost of installing electric vehicle recharging stations and to pay electricity bill costs...

  14. Self-Regulating, Nonflamable Rechargeable Lithium Batteries ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Batteries Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryRechargeable lithium batteries are superior to ...

  15. Open cycle liquid desiccant dehumidifier and hybrid solar/electric absorption refrigeration system. Annual report, January 1993--December 1993. Calendar year 1993

    SciTech Connect (OSTI)

    Nimmo, B.G.; Thornbloom, M.D.

    1995-04-01

    This annual report presents work performed during calendar year 1993 by the Florida Solar Energy Center under contract to the US Department of Energy. Two distinctively different solar powered indoor climate control systems were analyzed: the open cycle liquid desiccant dehumidifier, and an improved efficiency absorption system which may be fired by flat plate solar collectors. Both tasks represent new directions relative to prior FSEC research in Solar Cooling and Dehumidification.

  16. Recharge at the Hanford Site: Status report

    SciTech Connect (OSTI)

    Gee, G.W.

    1987-11-01

    A variety of field programs designed to evaluate recharge and other water balance components including precipitation, infiltration, evaporation, and water storage changes, have been carried out at the Hanford Site since 1970. Data from these programs have indicated that a wide range of recharge rates can occur depending upon specific site conditions. Present evidence suggests that minimum recharge occurs where soils are fine-textured and surfaces are vegetated with deep-rooted plants. Maximum recharge occurs where coarse soils or gravels exist at the surface and soils are kept bare. Recharge can occur in areas where shallow-rooted plants dominate the surface, particularly where soils are coarse-textured. Recharge estimates have been made for the site using simulation models. A US Geological Survey model that attempts to account for climate variability, soil storage parameters, and plant factors has calculated recharge values ranging from near zero to an average of about 1 cm/yr for the Hanford Site. UNSAT-H, a deterministic model developed for the site, appears to be the best code available for estimating recharge on a site-specific basis. Appendix I contains precipitation data from January 1979 to June 1987. 42 refs., 11 figs., 11 tabs.

  17. Transformer Recharging with Alpha Channeling in Tokamaks

    SciTech Connect (OSTI)

    N.J. Fisch

    2009-12-21

    Transformer recharging with lower hybrid waves in tokamaks can give low average auxiliary power if the resistivity is kept high enough during the radio frequency (rf) recharging stage. At the same time, operation in the hot ion mode via alpha channeling increases the effective fusion reactivity. This paper will address the extent to which these two large cost saving steps are compatible. __________________________________________________

  18. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur...

    Office of Scientific and Technical Information (OSTI)

    Title: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur ...

  19. Key Parameters Governing the Energy Density of Rechargeable Li...

    Office of Scientific and Technical Information (OSTI)

    of Rechargeable LiS Batteries Citation Details In-Document Search Title: Key Parameters Governing the Energy Density of Rechargeable LiS Batteries Authors: Gao, Jie ; ...

  20. Rechargeable Aluminum Batteries with Conducting Polymers as Positive...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Rechargeable Aluminum Batteries with Conducting Polymers as Positive Electrodes. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with ...

  1. Rechargeable aluminum batteries with conducting polymers as positive...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Rechargeable aluminum batteries with conducting polymers as positive electrodes. Citation Details In-Document Search Title: Rechargeable aluminum batteries with ...

  2. Rechargeable Aluminum Batteries with Conducting Polymers as Active...

    Office of Scientific and Technical Information (OSTI)

    Conference: Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with ...

  3. Lithium Metal Anodes for Rechargeable Batteries - Joint Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 3, 2014, Research Highlights Lithium Metal Anodes for Rechargeable Batteries (a) ... Li metal is an ideal anode material for rechargeable batteries beyond Li ion The review ...

  4. Rechargeable lithium-ion cell

    DOE Patents [OSTI]

    Bechtold, Dieter; Bartke, Dietrich; Kramer, Peter; Kretzschmar, Reiner; Vollbert, Jurgen

    1999-01-01

    The invention relates to a rechargeable lithium-ion cell, a method for its manufacture, and its application. The cell is distinguished by the fact that it has a metallic housing (21) which is electrically insulated internally by two half shells (15), which cover electrode plates (8) and main output tabs (7) and are composed of a non-conductive material, where the metallic housing is electrically insulated externally by means of an insulation coating. The cell also has a bursting membrane (4) which, in its normal position, is located above the electrolyte level of the cell (1). In addition, the cell has a twisting protection (6) which extends over the entire surface of the cover (2) and provides centering and assembly functions for the electrode package, which comprises the electrode plates (8).

  5. GC GUIDANCE ON ELECTRIC VEHICLE RECHARGING STATIONS

    Broader source: Energy.gov (indexed) [DOE]

    Third, once an electric vehicle recharging station is installed, a lab can use that ... Id. To qualify as a necessary expense (1) there must be a reasonable relationship between ...

  6. Self-Regulating, Nonflamable Rechargeable Lithium Batteries

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2010-06-23

    Rechargeable lithium batteries are superior to other rechargeable batteries due to their ability to store more energy per unit size and weight and to operate at higher voltages. The performance of lithium ion batteries available today, however, has been compromised by their tendency to overheat during operation. This condition, called “thermal runaway,” can melt the battery’s lithium metal and, in the most serious cases, result in explosive chemical reactions....

  7. Rechargeable thin film battery and method for making the same

    DOE Patents [OSTI]

    Goldner, Ronald B.; Liu, Te-Yang; Goldner, Mark A.; Gerouki, Alexandra; Haas, Terry E.

    2006-01-03

    A rechargeable, stackable, thin film, solid-state lithium electrochemical cell, thin film lithium battery and method for making the same is disclosed. The cell and battery provide for a variety configurations, voltage and current capacities. An innovative low temperature ion beam assisted deposition method for fabricating thin film, solid-state anodes, cathodes and electrolytes is disclosed wherein a source of energetic ions and evaporants combine to form thin film cell components having preferred crystallinity, structure and orientation. The disclosed batteries are particularly useful as power sources for portable electronic devices and electric vehicle applications where high energy density, high reversible charge capacity, high discharge current and long battery lifetimes are required.

  8. Estimated recharge rates at the Hanford Site

    SciTech Connect (OSTI)

    Fayer, M.J.; Walters, T.B.

    1995-02-01

    The Ground-Water Surveillance Project monitors the distribution of contaminants in ground water at the Hanford Site for the U.S. Department of Energy. A subtask called {open_quotes}Water Budget at Hanford{close_quotes} was initiated in FY 1994. The objective of this subtask was to produce a defensible map of estimated recharge rates across the Hanford Site. Methods that have been used to estimate recharge rates at the Hanford Site include measurements (of drainage, water contents, and tracers) and computer modeling. For the simulations of 12 soil-vegetation combinations, the annual rates varied from 0.05 mm/yr for the Ephrata sandy loam with bunchgrass to 85.2 mm/yr for the same soil without vegetation. Water content data from the Grass Site in the 300 Area indicated that annual rates varied from 3.0 to 143.5 mm/yr during an 8-year period. The annual volume of estimated recharge was calculated to be 8.47 {times} 10{sup 9} L for the potential future Hanford Site (i.e., the portion of the current Site bounded by Highway 240 and the Columbia River). This total volume is similar to earlier estimates of natural recharge and is 2 to 10x higher than estimates of runoff and ground-water flow from higher elevations. Not only is the volume of natural recharge significant in comparison to other ground-water inputs, the distribution of estimated recharge is highly skewed to the disturbed sandy soils (i.e., the 200 Areas, where most contaminants originate). The lack of good estimates of the means and variances of the supporting data (i.e., the soil map, the vegetation/land use map, the model parameters) translates into large uncertainties in the recharge estimates. When combined, the significant quantity of estimated recharge, its high sensitivity to disturbance, and the unquantified uncertainty of the data and model parameters suggest that the defensibility of the recharge estimates should be improved.

  9. Design and simulation of lithium rechargeable batteries

    SciTech Connect (OSTI)

    Doyle, C.M.

    1995-08-01

    Lithium -based rechargeable batteries that utilize insertion electrodes are being considered for electric-vehicle applications because of their high energy density and inherent reversibility. General mathematical models are developed that apply to a wide range of lithium-based systems, including the recently commercialized lithium-ion cell. The modeling approach is macroscopic, using porous electrode theory to treat the composite insertion electrodes and concentrated solution theory to describe the transport processes in the solution phase. The insertion process itself is treated with a charge-transfer process at the surface obeying Butler-Volmer kinetics, followed by diffusion of the lithium ion into the host structure. These models are used to explore the phenomena that occur inside of lithium cells under conditions of discharge, charge, and during periods of relaxation. Also, in order to understand the phenomena that limit the high-rate discharge of these systems, we focus on the modeling of a particular system with well-characterized material properties and system parameters. The system chosen is a lithium-ion cell produced by Bellcore in Red Bank, NJ, consisting of a lithium-carbon negative electrode, a plasticized polymer electrolyte, and a lithium-manganese-oxide spinel positive electrode. This battery is being marketed for consumer electronic applications. The system is characterized experimentally in terms of its transport and thermodynamic properties, followed by detailed comparisons of simulation results with experimental discharge curves. Next, the optimization of this system for particular applications is explored based on Ragone plots of the specific energy versus average specific power provided by various designs.

  10. Methods of Using Alpha Channeling Together with Transformer Recharging...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods of Using Alpha Channeling Together with Transformer Recharging A tokamak current can be sustained using rf waves for transformer recharging at low density and high-Z with...

  11. Alloys of clathrate allotropes for rechargeable batteries

    DOE Patents [OSTI]

    Chan, Candace K; Miller, Michael A; Chan, Kwai S

    2014-12-09

    The present disclosure is directed at an electrode for a battery wherein the electrode comprises clathrate alloys of silicon, germanium or tin. In method form, the present disclosure is directed at methods of forming clathrate alloys of silicon, germanium or tin which methods lead to the formation of empty cage structures suitable for use as electrodes in rechargeable type batteries.

  12. Rechargeable solid polymer electrolyte battery cell

    DOE Patents [OSTI]

    Skotheim, Terji

    1985-01-01

    A rechargeable battery cell comprising first and second electrodes sandwiching a solid polymer electrolyte comprising a layer of a polymer blend of a highly conductive polymer and a solid polymer electrolyte adjacent said polymer blend and a layer of dry solid polymer electrolyte adjacent said layer of polymer blend and said second electrode.

  13. Anodes for Rechargeable Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Xu, Wu; Lu, Dongping; Xiao, Jie; Zhang, Jiguang

    2015-04-10

    In this work, we will review the recent developments on the protection of Li metal anode in Li-S batteries. Various strategies used to minimize the corrosion of Li anode and reducing its impedance increase will be analyzed. Other potential anodes used in sulfur based rechargeable batteries will also be discussed.

  14. Dehumidifiers | Open Energy Information

    Open Energy Info (EERE)

    Contact needs updating Image needs updating Reference needed Missing content Broken link Other Additional Comments Cancel Submit Category: Articles with outstanding TODO tasks...

  15. Inorganic rechargeable non-aqueous cell

    DOE Patents [OSTI]

    Bowden, William L. (Nashua, NH); Dey, Arabinda N. (Needham, MA)

    1985-05-07

    A totally inorganic non-aqueous rechargeable cell having an alkali or alkaline earth metal anode such as of lithium, a sulfur dioxide containing electrolyte and a discharging metal halide cathode, such as of CuCl.sub.2, CuBr.sub.2 and the like with said metal halide being substantially totally insoluble in SO.sub.2 and admixed with a conductive carbon material.

  16. Electroactive Materials for Rechargeable Batteries | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Electroactive Materials for Rechargeable Batteries Technology available for licensing: Positive electrodes for secondary batteries containing lithium source material Method to compensate anode for initial irreversible capacity loss Enables lithium- deficient cathode materials through lithium source IN-12-086 US 9012091B2 Availability: Technology available for license to organizations with commercial interest. Collaborative research is available under a Cooperative Research and

  17. Electrolyte additive for lithium rechargeable organic electrolyte battery

    DOE Patents [OSTI]

    Behl, Wishvender K.; Chin, Der-Tau

    1989-01-01

    A large excess of lithium iodide in solution is used as an electrolyte adive to provide overcharge protection for a lithium rechargeable organic electrolyte battery.

  18. Making Li-air batteries rechargeable: material challenges

    SciTech Connect (OSTI)

    Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

    2013-02-25

    A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

  19. ETA-HTP08 Rechargeable Energy Storage System (RESS) Charging...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ETA-HTP08 Revision 1 Effective October 1, 2004 Rechargeable Energy Storage System (RESS) Charging Prepared by Electric Transportation Applications Prepared by: ...

  20. Electrolyte additive for lithium rechargeable organic electrolyte battery

    DOE Patents [OSTI]

    Behl, Wishvender K.; Chin, Der-Tau

    1989-02-07

    A large excess of lithium iodide in solution is used as an electrolyte adive to provide overcharge protection for a lithium rechargeable organic electrolyte battery.

  1. Electrode Materials for Rechargeable Li-ion Batteries: a New...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrode Materials for Rechargeable Li-ion Batteries: a New Synthetic Approach ... multiple cycles which enables Li-ion batteries with exceptionally high-power.

    This ...

  2. Organic Cathode Materials for Rechargeable Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Qian, Jiangfeng; Zhang, Jiguang; Xu, Wu

    2015-06-28

    This chapter will primarily focus on the advances made in recent years and specify the development of organic electrode materials for their applications in rechargeable lithium batteries, sodium batteries and redox flow batteries. Four various organic cathode materials, including conjugated carbonyl compounds, conducting polymers, organosulfides and free radical polymers, are introduced in terms of their electrochemical performances in these three battery systems. Fundamental issues related to the synthesis-structure-activity correlations, involved work principles in energy storage systems, and capacity fading mechanisms are also discussed.

  3. Thin-film Rechargeable Lithium Batteries

    DOE R&D Accomplishments [OSTI]

    Dudney, N. J.; Bates, J. B.; Lubben, D.

    1995-06-01

    Thin film rechargeable lithium batteries using ceramic electrolyte and cathode materials have been fabricated by physical deposition techniques. The lithium phosphorous oxynitride electrolyte has exceptional electrochemical stability and a good lithium conductivity. The lithium insertion reaction of several different intercalation materials, amorphous V{sub 2}O{sub 5}, amorphous LiMn{sub 2}O{sub 4}, and crystalline LiMn{sub 2}O{sub 4} films, have been investigated using the completed cathode/electrolyte/lithium thin film battery.

  4. Lithium Metal Anodes for Rechargeable Batteries

    SciTech Connect (OSTI)

    Xu, Wu; Wang, Jiulin; Ding, Fei; Chen, Xilin; Nasybulin, Eduard N.; Zhang, Yaohui; Zhang, Jiguang

    2013-10-29

    Rechargeable lithium metal batteries have much higher energy density than those of lithium ion batteries using graphite anode. Unfortunately, uncontrollable dendritic lithium growth inherent in these batteries (upon repeated charge/discharge cycling) and limited Coulombic efficiency during lithium deposition/striping has prevented their practical application over the past 40 years. With the emerging of post Li-ion batteries, safe and efficient operation of lithium metal anode has become an enabling technology which may determine the fate of several promising candidates for the next generation of energy storage systems, including rechargeable Li-air battery, Li-S battery, and Li metal battery which utilize lithium intercalation compounds as cathode. In this work, various factors which affect the morphology and Coulombic efficiency of lithium anode will be analyzed. Technologies used to characterize the morphology of lithium deposition and the results obtained by modeling of lithium dendrite growth will also be reviewed. At last, recent development in this filed and urgent need in this field will also be discussed.

  5. Rechargeable Thin-film Lithium Batteries

    DOE R&D Accomplishments [OSTI]

    Bates, J. B.; Gruzalski, G. R.; Dudney, N. J.; Luck, C. F.; Yu, Xiaohua

    1993-08-01

    Rechargeable thin film batteries consisting of lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have recently been developed. The batteries, which are typically less than 6 {mu}m thick, can be fabricated to any specified size, large or small, onto a variety of substrates including ceramics, semiconductors, and plastics. The cells that have been investigated include Li TiS{sub 2}, Li V{sub 2}O{sub 5}, and Li Li{sub x}Mn{sub 2}O{sub 4}, with open circuit voltages at full charge of about 2.5, 3.6, and 4.2, respectively. The development of these batteries would not have been possible without the discovery of a new thin film lithium electrolyte, lithium phosphorus oxynitride, that is stable in contact with metallic lithium at these potentials. Deposited by rf magnetron sputtering of Li{sub 3}PO{sub 4} in N{sub 2}, this material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25{degrees}C of 2 {mu}S/cm. The maximum practical current density obtained from the thin film cells is limited to about 100 {mu}A/cm{sup 2} due to a low diffusivity of Li{sup +} ions in the cathodes. In this work, the authors present a short review of their work on rechargeable thin film lithium batteries.

  6. New Imaging Technique Shows Nanoscale Workings of Rechargeable Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Imaging Technique Shows Nanoscale Workings of Rechargeable Batteries There's a new tool in the push to engineer rechargeable batteries that last longer and charge more quickly. An X-ray microscopy technique recently developed at Advanced Light Source has given scientists the ability to image nanoscale changes inside lithium-ion battery particles as they charge and discharge. ← Previous Next →

  7. The First Ca-ion Rechargeable Battery - Joint Center for Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 24, 2015, Research Highlights The First Ca-ion Rechargeable Battery Schematic ... We have demonstrated the first ever rechargeable battery utilizing calcium as the working ...

  8. A New Tool to Probe the Inner Workings of Rechargeable Batteries...

    Office of Science (SC) Website

    1 A New Tool to Probe the Inner Workings of Rechargeable Batteries Basic Energy ... A New Tool to Probe the Inner Workings of Rechargeable Batteries A new spectroscopic ...

  9. Electrolyte additive for lithium rechargeable organic electrolyte battery

    SciTech Connect (OSTI)

    Behl, W.K.; Chin, D.T.

    1988-02-08

    This invention relates in general to a rechargeable lithium organic electrolyte battery and, in particular, to an electrolyte additive for such a battery that provides overcharge protection. Rechargeable lithium-organic electrolyte batteries are being developed to provide low-cost, high-energy-density power sources for communication, night vision and various other Army applications. Typically, a rechargeable lithium organic electrolyte battery includes a lithium anode, a cathode including compounds such as titanium disulfide, molybdenum oxide, molybdenum sulfide, vanadium oxide, vanadium sulfide, chromium oxide, etc an electrolyte solution including an inorganic lithium salt such as lithium hexafluoroarsenate, lithium perchlorate, etc.

  10. Electron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    density measurement by differential interferometry W. X. Ding, D. L. Brower, B. H. Deng, and T. Yates Electrical Engineering Department, University of California-Los Angeles, Los Angeles, California 90095 ͑Received 5 May 2006; presented on 10 May 2006; accepted 16 June 2006; published online 26 September 2006͒ A novel differential interferometer is being developed to measure the electron density gradient and its fluctuations. Two separate laser beams with slight spatial offset and frequency

  11. Improved zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, P.N. Jr.

    1988-06-21

    The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

  12. DOE Issues Guidance on Electric Vehicle Recharging Stations

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy recently issued guidance to its national laboratory management and operating (M&O) contractors on the installation and operation of electric vehicle recharging...

  13. Graphite fiber as a positive electrode of rechargeable lithium cells

    SciTech Connect (OSTI)

    Matsuda, Y.; Katsuma, H.; Morita, M.

    1984-01-01

    Graphite compounds have gained interest as possible positive electrodes for rechargeable lithium cells. Their charge-discharge characteristics have been studied in organic electrolytic solutions such as sulfolane dimethylsulfite, and propylene carbonate.

  14. New York's Energy Storage System Gets Recharged | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    York's Energy Storage System Gets Recharged New York's Energy Storage System Gets Recharged August 2, 2010 - 1:18pm Addthis Matt Rogers, Senior Advisor to Secretary Chu, explain why grid frequency regulation matters Jonathan Silver Jonathan Silver Executive Director of the Loan Programs Office What does this mean for me? AES Storage in New York got a $17.1M conditional loan guarantee to provide a more stable transmission grid. When thinking of clean technologies, energy storage might not be the

  15. Soil Water Balance and Recharge Monitoring at the Hanford Site – FY 2010 Status Report

    SciTech Connect (OSTI)

    Fayer, Michael J.; Saunders, Danielle L.; Herrington, Ricky S.; Felmy, Diana

    2010-10-27

    This report summarizes the recharge data collected in FY 2010 at five locations on the Hanford Site in southeastern Washington State. Average monthly precipitation and temperature conditions in FY 2010 were near normal and did not present an opportunity for increased recharge. The recharge monitoring data confirmed those conditions, showing normal behavior in water content, matric head, and recharge rates. Also provided in this report is a strategy for recharge estimation for the next 5 years.

  16. Rechargeable Magnesium Batteries: Low-Cost Rechargeable Magnesium Batteries with High Energy Density

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Pellion Technologies is developing rechargeable magnesium batteries that would enable an EV to travel 3 times farther than it could using Li-ion batteries. Prototype magnesium batteries demonstrate excellent electrochemical behavior; delivering thousands of charge cycles with very little fade. Nevertheless, these prototypes have always stored too little energy to be commercially viable. Pellion Technologies is working to overcome this challenge by rapidly screening potential storage materials using proprietary, high-throughput computer models. To date, 12,000 materials have been identified and analyzed. The resulting best materials have been electrochemically tested, yielding several very promising candidates.

  17. Rechargeable thin-film lithium batteries

    SciTech Connect (OSTI)

    Bates, J.B.; Gruzalski, G.R.; Dudney, N.J.; Luck, C.F.; Yu, X.

    1993-09-01

    Rechargeable thin-film batteries consisting of lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. These include Li-TiS{sub 2}, Li-V{sub 2}O{sub 5}, and Li-Li{sub x}Mn{sub 2}O{sub 4} cells with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The realization of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46}and a conductivity at 25 C of 2 {mu}S/cm. The thin-film cells have been cycled at 100% depth of discharge using current densities of 5 to 100 {mu}A/cm{sup 2}. Over most of the charge-discharge range, the internal resistance appears to be dominated by the cathode, and the major source of the resistance is the diffusion of Li{sup +} ions from the electrolyte into the cathode. Chemical diffusion coefficients were determined from ac impedance measurements.

  18. Thin-film Rechargeable Lithium Batteries

    DOE R&D Accomplishments [OSTI]

    Bates, J. B.; Gruzalski, G. R.; Dudney, N. J.; Luck, C. F.; Yu, X.

    1993-11-01

    Rechargeable thin films batteries with lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. The cathodes include TiS{sub 2}, the {omega} phase of V{sub 2}O{sub 5}, and the cubic spinel Li{sub x}Mn{sub 2}O{sub 4} with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The development of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25 C of 2 {mu}S/cm. Thin film cells have been cycled at 100% depth of discharge using current densities of 2 to 100 {mu}A/cm{sup 2}. The polarization resistance of the cells is due to the slow insertion rate of Li{sup +} ions into the cathode. Chemical diffusion coefficients for Li{sup +} ions in the three types of cathodes have been estimated from the analysis of ac impedance measurements.

  19. Electron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron thermal transport within magnetic islands in the reversed-field pinch a... H. D. Stephens, 1,b͒ D. J. Den Hartog, 1,3 C. C. Hegna, 1,2 and J. A. Reusch 1 1 Department of Physics, University of Wisconsin-Madison, 1150 University Ave., Madison, Wisconsin 53706, USA 2 Department of Engineering Physics, University of Wisconsin-Madison, 1500 Engineering Drive, Madison, Wisconsin 53706, USA 3 Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas, University of

  20. Groundwater recharge from Long Lake, Indiana Dunes National Lakeshore

    SciTech Connect (OSTI)

    Isiorho, S.A.; Beeching, F.M. (Indiana Univ., Fort Wayne, IN (United States). Geosciences Dept.); Whitman, R.L.; Stewart, P.M. (National Park Services, Porter, IN (United States). Indiana Dunes National Lakeshore); Gentleman, M.A.

    1992-01-01

    Long Lake, located between Lake Michigan and the Dune-complexes of Indiana Dunes, was formed during Pleistocene and Holocene epochs. The lake is currently being studied to understand the detailed hydrology. One of the objective of the study is to understand the hydrologic relationship between the lake and a water treatment holding pond to the northeast. Understanding the water movement between the two bodies of water, if any, would be very important in the management and protection of nature preserves in the area. Seepage measurement and minipiezometric tests indicate groundwater recharge from Long Lake. The groundwater recharge rate is approximately 1.40 to 22.28 x 10[sup [minus]4] m/day. An estimate of the amount of recharge of 7.0 x 10[sup 6] m[sup 3]/y may be significant in terms of groundwater recharge of the upper aquifer system of the Dunes area. The water chemistry of the two bodies of water appears to be similar, however, the pH of the holding pond is slightly alkaline (8.5) while that of Long Lake is less alkaline (7.7). There appears to be no direct contact between the two bodies of water (separated by approximately six meters of clay rich sediment). The geology of the area indicates a surficial aquifer underlying Long Lake. The lake should be regarded as a recharge area and should be protected from pollutants as the degradation of the lake would contaminate the underlying aquifer.

  1. Zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, Jr., Philip N.

    1989-01-01

    An improved zinc electrode is disclosed for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed which utilizes the improved zinc electrode and further includes an alkaline electrolyte within said battery circulating through the passageways in the zinc electrode and an external electrolyte circulation means which has an electrolyte reservoir external to the battery case including filter means to filter solids out of the electrolyte as it circulates to the external reservoir and pump means for recirculating electrolyte from the external reservoir to the zinc electrode.

  2. Novel electrolyte chemistries for Mg-Ni rechargeable batteries.

    SciTech Connect (OSTI)

    Garcia-Diaz, Brenda; Kane, Marie; Au, Ming

    2010-10-01

    Commercial hybrid electric vehicles (HEV) and battery electric vehicles (BEV) serve as means to reduce the nation's dependence on oil. Current electric vehicles use relatively heavy nickel metal hydride (Ni-MH) rechargeable batteries. Li-ion rechargeable batteries have been developed extensively as the replacement; however, the high cost and safety concerns are still issues to be resolved before large-scale production. In this study, we propose a new highly conductive solid polymer electrolyte for Mg-Ni high electrochemical capacity batteries. The traditional corrosive alkaline aqueous electrolyte (KOH) is replaced with a dry polymer with conductivity on the order of 10{sup -2} S/cm, as measured by impedance spectroscopy. Several potential novel polymer and polymer composite candidates are presented with the best-performing electrolyte results for full cell testing and cycling.

  3. Evaluation of Recharge Potential at Crater U5a (WISHBONE)

    SciTech Connect (OSTI)

    Richard H. French; Samuel L. Hokett

    1998-11-01

    Radionuclides are present both below and above the water table at the Nevada Test Site (NTS), as the result of underground nuclear testing. Mobilization and transport of radionuclides from the vadose zone is a complex process that is influenced by the solubility and sorption characteristics of the individual radionuclides, as well as the soil water flux. On the NTS, subsidence craters resulting from testing underground nuclear weapons are numerous, and many intercept surface water flows. Because craters collect surface water above the sub-surface point of device detonation, these craters may provide a mechanism for surface water to recharge the groundwater aquifer system underlying the NTS. Given this situation, there is a potential for the captured water to introduce contaminants into the groundwater system. Crater U5a (WISHBONE), located in Frenchman Flat, was selected for study because of its potentially large drainage area, and significant erosional features, which suggested that it has captured more runoff than other craters in the Frenchman Flat area. Recharge conditions were studied in subsidence crater U5a by first drilling boreholes and analyzing the collected soil cores to determine the soil properties and moisture conditions. This information, coupled with a 32-year precipitation record, was used to conduct surface and vaodse zone modeling. Surface water modeling predicted that approximately 13 ponding events had occurred during the life of the crater. Vadose zone modeling indicated that since the crater's formation approximately 5,900 m3 of water were captured by the crater. Of this total, approximately 5,200 m3 of potential recahrge may have occurred, and the best estimates of annual average potential recharge rates lie between 36 and 188 cm of water per year. The term potential is used here to indicate that the water is not technically recharged because it has not yet reached the water table.

  4. John B. Goodenough, Cathode Materials, and Rechargeable Lithium-ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries John B. Goodenough, Cathode Materials, and Rechargeable Lithium-ion Batteries Resources with Additional Information * Awards * Patents John B. Goodenough Photo Credit: Courtesy of The University of Texas at Austin Cockrell School of Engineering On September 17, 2009, U.S. Energy Secretary Steven Chu named John B. Goodenough as a winner of the Enrico Fermi Award ' in recognition for his lasting contributions to materials science and technology, especially the science underlying

  5. Soil Water Balance and Recharge Monitoring at the Hanford Site - FY09 Status Report

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Saunders, Danielle L.; Strickland, Christopher E.; Waichler, Scott R.; Clayton, Ray E.

    2009-09-28

    Recharge provides the primary driving force for transporting contaminants from the vadose zone to underlying aquifer systems. Quantification of recharge rates is important for assessing contaminant transport and fate and for evaluating remediation alternatives. This report describes the status of soil water balance and recharge monitoring performed by Pacific Northwest National Laboratory at the Hanford Site for Fiscal Year 2009. Previously reported data for Fiscal Years 2004 - 2008 are updated with data collected in Fiscal Year 2009 and summarized.

  6. Polymer considerations in rechargeable lithium ion plastic batteries

    SciTech Connect (OSTI)

    Gozdz, A.S.; Tarascon, J.M.; Schmutz, C.N.; Warren, P.C.; Gebizlioglu, O.S.; Shokoohi, F.

    1995-07-01

    A series of polymers have been investigated in order to determine their suitability as ionically conductive binders of the active electrode materials and as hybrid electrolyte matrices in plastic lithium ion rechargeable batteries. Hybrid electrolyte films used in this study have been prepared by solvent casting using a 1:1 w/w mixture of the matrix polymer with 1 M LiPF{sub 6} in EC/PC. Based on electrochemical stability, mechanical strength, liquid electrolyte retention, and softening temperature, random copolymers of vinylidene fluoride containing ca. 12 mole % of hexafluoropropylene have been selected for this application.

  7. Composite Electrodes for Rechargeable Lithium-Ion Batteries | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Electrodes for Rechargeable Lithium-Ion Batteries Technology available for licensing: Electrodes having composite xLi2M'O3*(1-x)LiMO2 structures in which an electrochemically inactive Li2M'O3 component is integrated with an electrochemically active LiMO2 component to provide improved structural and electrochemical stability. Has superior cost features compared with current state-of-the-art LiCoO2 electrodes. Offers high rate of charge/discharge and structural stability

  8. Reconnaissance Estimates of Recharge Based on an Elevation-dependent Chloride Mass-balance Approach

    SciTech Connect (OSTI)

    Charles E. Russell; Tim Minor

    2002-08-31

    Significant uncertainty is associated with efforts to quantity recharge in arid regions such as southern Nevada. However, accurate estimates of groundwater recharge are necessary to understanding the long-term sustainability of groundwater resources and predictions of groundwater flow rates and directions. Currently, the most widely accepted method for estimating recharge in southern Nevada is the Maxey and Eakin method. This method has been applied to most basins within Nevada and has been independently verified as a reconnaissance-level estimate of recharge through several studies. Recharge estimates derived from the Maxey and Eakin and other recharge methodologies ultimately based upon measures or estimates of groundwater discharge (outflow methods) should be augmented by a tracer-based aquifer-response method. The objective of this study was to improve an existing aquifer-response method that was based on the chloride mass-balance approach. Improvements were designed to incorporate spatial variability within recharge areas (rather than recharge as a lumped parameter), develop a more defendable lower limit of recharge, and differentiate local recharge from recharge emanating as interbasin flux. Seventeen springs, located in the Sheep Range, Spring Mountains, and on the Nevada Test Site were sampled during the course of this study and their discharge was measured. The chloride and bromide concentrations of the springs were determined. Discharge and chloride concentrations from these springs were compared to estimates provided by previously published reports. A literature search yielded previously published estimates of chloride flux to the land surface. {sup 36}Cl/Cl ratios and discharge rates of the three largest springs in the Amargosa Springs discharge area were compiled from various sources. This information was utilized to determine an effective chloride concentration for recharging precipitation and its associated uncertainty via Monte Carlo simulations

  9. Layered cathode materials for lithium ion rechargeable batteries

    DOE Patents [OSTI]

    Kang, Sun-Ho; Amine, Khalil

    2007-04-17

    A number of materials with the composition Li.sub.1+xNi.sub..alpha.Mn.sub..beta.Co.sub..gamma.M'.sub..delta.O.sub.2-- zF.sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, .alpha. is between about 0.2 and 0.6, .beta. is between about 0.2 and 0.6, .gamma. is between about 0 and 0.3, .delta. is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling.

  10. Resilient design of recharging station networks for electric transportation vehicles

    SciTech Connect (OSTI)

    Kris Villez; Akshya Gupta; Venkat Venkatasubramanian

    2011-08-01

    As societies shift to 'greener' means of transportation using electricity-driven vehicles one critical challenge we face is the creation of a robust and resilient infrastructure of recharging stations. A particular issue here is the optimal location of service stations. In this work, we consider the placement of battery replacing service station in a city network for which the normal traffic flow is known. For such known traffic flow, the service stations are placed such that the expected performance is maximized without changing the traffic flow. This is done for different scenarios in which roads, road junctions and service stations can fail with a given probability. To account for such failure probabilities, the previously developed facility interception model is extended. Results show that service station failures have a minimal impact on the performance following robust placement while road and road junction failures have larger impacts which are not mitigated easily by robust placement.

  11. Iron-Air Rechargeable Battery: A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage

    SciTech Connect (OSTI)

    2010-10-01

    GRIDS Project: USC is developing an iron-air rechargeable battery for large-scale energy storage that could help integrate renewable energy sources into the electric grid. Iron-air batteries have the potential to store large amounts of energy at low cost—iron is inexpensive and abundant, while oxygen is freely obtained from the air we breathe. However, current iron-air battery technologies have suffered from low efficiency and short life spans. USC is working to dramatically increase the efficiency of the battery by placing chemical additives on the battery’s iron-based electrode and restructuring the catalysts at the molecular level on the battery’s air-based electrode. This can help the battery resist degradation and increase life span. The goal of the project is to develop a prototype iron-air battery at significantly cost lower than today’s best commercial batteries.

  12. Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems

    SciTech Connect (OSTI)

    Tuffner, Francis K.; Kintner-Meyer, Michael C. W.; Hammerstrom, Donald J.; Pratt, Richard M.

    2012-05-22

    Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems. According to one aspect, a battery charging control method includes accessing information regarding a presence of at least one of a surplus and a deficiency of electrical energy upon an electrical power distribution system at a plurality of different moments in time, and using the information, controlling an adjustment of an amount of the electrical energy provided from the electrical power distribution system to a rechargeable battery to charge the rechargeable battery.

  13. In situ and ex situ spectroelectrochemical and X-ray absorption studies on rechargeable, chemically-modified and other MnO{sub 2} materials

    SciTech Connect (OSTI)

    Conway, B.E.; Qu, D.; McBreen, J. |

    1992-12-31

    A combined series of in situ and ex situ UV spectroelectrochemical and X-ray absorption studies have been made on MnO{sub 2}, chemically-modified by small amounts of Bi(III), and comparatively on other MnO{sub 2} materials such as a blank (Bi-free) and {gamma}-MnO{sub 2}. These procedures are applied in order to follow the oxidation-states of Bi and of Mn during the course of discharge and recharge of MnO{sub 2} as a battery cathode material, and the extents of rechargeability that can be achieved with such materials. Presence of Bi appears to provide a preferred ``heterogeneous`` discharge/recharge pathway involving a soluble Mn(III) intermediate, over the alternative ``electron-proton`` hopping, solid-state mechanism. From XAS results, it is concluded that presence of Bi, although not affecting the O-coordination, does influence the Mn-Mn coordination, determining the way the MnO{sub 2} coordination octahedra are connected.

  14. An overviewFunctional nanomaterials for lithium rechargeable batteries, supercapacitors, hydrogen storage, and fuel cells

    SciTech Connect (OSTI)

    Liu, Hua Kun

    2013-12-15

    Graphical abstract: Nanomaterials play important role in lithium ion batteries, supercapacitors, hydrogen storage and fuel cells. - Highlights: Nanomaterials play important role for lithium rechargeable batteries. Nanostructured materials increase the capacitance of supercapacitors. Nanostructure improves the hydrogenation/dehydrogenation of hydrogen storage materials. Nanomaterials enhance the electrocatalytic activity of the catalysts in fuel cells. - Abstract: There is tremendous worldwide interest in functional nanostructured materials, which are the advanced nanotechnology materials with internal or external dimensions on the order of nanometers. Their extremely small dimensions make these materials unique and promising for clean energy applications such as lithium ion batteries, supercapacitors, hydrogen storage, fuel cells, and other applications. This paper will highlight the development of new approaches to study the relationships between the structure and the physical, chemical, and electrochemical properties of functional nanostructured materials. The Energy Materials Research Programme at the Institute for Superconducting and Electronic Materials, the University of Wollongong, has been focused on the synthesis, characterization, and applications of functional nanomaterials, including nanoparticles, nanotubes, nanowires, nanoporous materials, and nanocomposites. The emphases are placed on advanced nanotechnology, design, and control of the composition, morphology, nanostructure, and functionality of the nanomaterials, and on the subsequent applications of these materials to areas including lithium ion batteries, supercapacitors, hydrogen storage, and fuel cells.

  15. Facile synthesis of lithium sulfide nanocrystals for use in advanced rechargeable batteries

    SciTech Connect (OSTI)

    Li, Xuemin; Wolden, Colin A.; Ban, Chunmei; Yang, Yongan

    2015-12-03

    This work reports a new method of synthesizing anhydrous lithium sulfide (Li2S) nanocrystals and demonstrates their potential as cathode materials for advanced rechargeable batteries. Li2S is synthesized by reacting hydrogen sulfide (H2S) with lithium naphthalenide (Li-NAP), a thermodynamically spontaneous reaction that proceeds to completion rapidly at ambient temperature and pressure. The process completely removes H2S, a major industrial waste, while cogenerating 1,4-dihydronaphthalene, itself a value-added chemical that can be used as liquid fuel. The phase purity, morphology, and homogeneity of the resulting nanopowders were confirmed by X-ray diffraction and scanning electron microscopy. The synthesized Li2S nanoparticles (100 nm) were assembled into cathodes, and their performance was compared to that of cathodes fabricated using commercial Li2S micropowders (1–5 μm). As a result, electrochemical analyses demonstrated that the synthesized Li2S were superior in terms of (dis)charge capacity, cycling stability, output voltage, and voltage efficiency.

  16. Facile synthesis of lithium sulfide nanocrystals for use in advanced rechargeable batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xuemin; Wolden, Colin A.; Ban, Chunmei; Yang, Yongan

    2015-12-03

    This work reports a new method of synthesizing anhydrous lithium sulfide (Li2S) nanocrystals and demonstrates their potential as cathode materials for advanced rechargeable batteries. Li2S is synthesized by reacting hydrogen sulfide (H2S) with lithium naphthalenide (Li-NAP), a thermodynamically spontaneous reaction that proceeds to completion rapidly at ambient temperature and pressure. The process completely removes H2S, a major industrial waste, while cogenerating 1,4-dihydronaphthalene, itself a value-added chemical that can be used as liquid fuel. The phase purity, morphology, and homogeneity of the resulting nanopowders were confirmed by X-ray diffraction and scanning electron microscopy. The synthesized Li2S nanoparticles (100 nm) were assembledmore » into cathodes, and their performance was compared to that of cathodes fabricated using commercial Li2S micropowders (1–5 μm). As a result, electrochemical analyses demonstrated that the synthesized Li2S were superior in terms of (dis)charge capacity, cycling stability, output voltage, and voltage efficiency.« less

  17. Electrically recharged battery employing a packed/spouted bed metal particle electrode

    DOE Patents [OSTI]

    Siu, Stanley C.; Evans, James W.; Salas-Morales, Juan

    1995-01-01

    A secondary metal air cell, employing a spouted/packed metal particle bed and an air electrode. More specifically a zinc air cell well suited for use in electric vehicles which is capable of being either electrically or hydraulically recharged.

  18. Recharge Data Package for the 2005 Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Fayer, Michael J.; Szecsody, Jim E.

    2004-06-30

    Pacific Northwest National Laboratory assisted CH2M Hill Hanford Group, Inc., (CHG) by providing estimates of recharge rates for current conditions and long-term scenarios involving disposal in the Integrated Disposal Facility (IDF). The IDF will be located in the 200 East Area at the Hanford Site and will receive several types of waste including immobilized low-activity waste. The recharge estimates for each scenario were derived from lysimeter and tracer data collected by the IDF PA Project and from modeling studies conducted for the project. Recharge estimates were provided for three specific site features (the surface barrier; possible barrier side slopes; and the surrounding soil) and four specific time periods (pre-Hanford; Hanford operations; surface barrier design life; post-barrier design life). CHG plans to conduct a performance assessment of the latest IDF design and call it the IDF 2005 PA; this recharge data package supports the upcoming IDF 2005 PA.

  19. Vehicle Technologies Office Merit Review 2016: Efficient Rechargeable Li/O2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Batteries Utilizing Stable Inorganic Molten Salt Electrolytes | Department of Energy Efficient Rechargeable Li/O2 Batteries Utilizing Stable Inorganic Molten Salt Electrolytes Vehicle Technologies Office Merit Review 2016: Efficient Rechargeable Li/O2 Batteries Utilizing Stable Inorganic Molten Salt Electrolytes Presentation given by Liox at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  20. Electrode Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Approach | Argonne National Laboratory Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic Approach Technology available for licensing: New high-energy cathode materials for use in rechargeable lithium-ion cells and batteries synthesized by using a novel alternative approach Lowers battery pack cost. Layered cathode material contains low-cost manganese, which operates at high rate and high voltage and results in a high-energy-density battery with improved stability. PDF icon

  1. Team devises new way for stabilizing battery recharge > EMC2 News > The

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Materials Center at Cornell Team devises new way for stabilizing battery recharge July 15th, 2016 › By Tom Fleischman Lynden Archer/Provided An illustration of the electrolyte inside a rechargeable battery, with the large blue spheres representing the immobile anions tethered to a solid matrix. The small red and green spheres represent the positive and negative ions, respectively; at left are dendrites, whose growth is limited by the immobilized anions. It seems like fairly simple

  2. Materials issues in lithium ion rechargeable battery technology

    SciTech Connect (OSTI)

    Doughty, D.H.

    1995-07-01

    Lithium ion rechargeable batteries are predicted to replace Ni/Cd as the workhorse consumer battery. The pace of development of this battery system is determined in large part by the availability of materials and the understanding of interfacial reactions between materials. Lithium ion technology is based on the use of two lithium intercalating electrodes. Carbon is the most commonly used anode material, while the cathode materials of choice have been layered lithium metal chalcogenides (LiMX{sub 2}) and lithium spinel-type compounds. Electrolytes may be either organic liquids or polymers. Although the first practical use of graphite intercalation compounds as battery anodes was reported in 1981 for molten salt cells and in 1983 for ambient temperature systems, it was not until Sony Energytech announced a new lithium ion intercalating carbon anode in 1990, that interest peaked. The reason for this heightened interest is that these electrochemical cells have the high energy density, high voltage and light weight of metallic lithium, but without the disadvantages of dendrite formation on charge, improving their safety and cycle life.

  3. Compendium of Data for the Hanford Site (Fiscal Years 2004 to 2008) Applicable to Estimation of Recharge Rates

    SciTech Connect (OSTI)

    Nichols, William E.; Rockhold, Mark L.; Downs, Janelle L.

    2008-09-24

    This report is a compendium of recharge data collected in Fiscal Years 2004 through 2008 at various soil and surface covers found and planned in the 200 West and 200 East Areas of the U.S. Department of Energys Hanford Site in southeast Washington State. The addition of these new data to previously published recharge data will support improved estimates of recharge with respect to location and soil cover helpful to evaluations and risk assessments of radioactive and chemical wastes at this site. Also presented are evaluations of the associated uncertainties, limitations, and data gaps in the existing knowledge base for recharge at the Hanford Site.

  4. Optimization of Acetylene Black Conductive Additive andPolyvinylidene Difluoride Composition for High Power RechargeableLithium-Ion Cells

    SciTech Connect (OSTI)

    Liu, G.; Zheng, H.; Battaglia, V.S.; Simens, A.S.; Minor, A.M.; Song, X.

    2007-07-01

    Fundamental electrochemical methods were applied to study the effect of the acetylene black (AB) and the polyvinylidene difluoride (PVDF) polymer binder on the performance of high-power designed rechargeable lithium ion cells. A systematic study of the AB/PVDF long-range electronic conductivity at different weight ratios is performed using four-probe direct current tests and the results reported. There is a wide range of AB/PVDF ratios that satisfy the long-range electronic conductivity requirement of the lithium-ion cathode electrode; however, a significant cell power performance improvement is observed at small AB/PVDF composition ratios that are far from the long-range conductivity optimum of 1 to 1.25. Electrochemical impedance spectroscopy (EIS) tests indicate that the interfacial impedance decreases significantly with increase in binder content. The hybrid power pulse characterization results agree with the EIS tests and also show improvement for cells with a high PVDF content. The AB to PVDF composition plays a significant role in the interfacial resistance. We believe the higher binder contents lead to a more cohesive conductive carbon particle network that results in better overall all local electronic conductivity on the active material surface and hence reduced charge transfer impedance.

  5. Development and In Situ Characterization of New Electrolyte and Electrode materials for Rechargeable Lithium Batteries

    SciTech Connect (OSTI)

    Yang, X -Q; Xing, X K; Daroux, M

    2000-01-03

    The object of this project is to develop new electrolyte and cathode materials for rechargeable lithium batteries, especially for lithium ion and lithium polymer batteries. Enhancing performance, reducing cost, and replacing toxic materials by environmentally benign materials, are strategic goals of DOE in lithium battery research. This proposed project will address these goals on two important material studies, namely the new electrolytes and new cathode materials. For the new electrolyte materials, aza based anion receptors as additives, organic lithium salts and plasticizers which have been developed by BNL team under Energy Research programs of DOE, will be evaluated by Gould for potential use in commercial battery cells. All of these three types of compounds are aimed to enhance the conductivity and lithium transference number of lithium battery electrolytes and reduce the use of toxic salts in these electrolytes. BNL group will be working closely with Gould to further develop these compounds for commercialization. For the cathode material studies, BNL efforts wi U be focused on developing new superior characterization methclds, especially in situ techniques utilize the unique user facility of DOE at BNL, namely the National Synchrotrons Light Source (NSLS). In situ x-ray absorption and x-ray diftlaction spectroscopy will be used to study the relationship between performance and the electronic and structural characteristics of intercalation compounds such as LiNi02, LiCo02, and LiMn204 spinel. The study will be focused on LiMn204 spinel materials. Gould team will contribute their expertise in choosing the most promising compounds, providing overall performance requirements, and will use the results of this study to guide their procedure for quality control. The knowledge gained through this project will not only benefit Gould and BNL, but will be very valuable to the scientific community in

  6. Recharge Data Package for Hanford Single-Shell Tank Waste Management Areas

    SciTech Connect (OSTI)

    Fayer, Michael J.; Keller, Jason M.

    2007-09-24

    Pacific Northwest National Laboratory (PNNL) assists CH2M HILL Hanford Group, Inc., in its preparation of the Resource Conservation and Recovery Act (RCRA) Facility Investigation report. One of the PNNL tasks is to use existing information to estimate recharge rates for past and current conditions as well as future scenarios involving cleanup and closure of tank farms. The existing information includes recharge-relevant data collected during activities associated with a host of projects, including those of RCRA, the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), the CH2M HILL Tank Farm Vadose Zone Project, and the PNNL Remediation and Closure Science Project. As new information is published, the report contents can be updated. The objective of this data package was to use published data to provide recharge estimates for the scenarios being considered in the RCRA Facility Investigation. Recharge rates were estimated for areas that remain natural and undisturbed, areas where the vegetation has been disturbed, areas where both the vegetation and the soil have been disturbed, and areas that are engineered (e.g., surface barrier). The recharge estimates supplement the estimates provided by PNNL researchers in 2006 for the Hanford Site using additional field measurements and model analysis using weather data through 2006.

  7. Dehumidifying Heat Pipes | Department of Energy

    Energy Savers [EERE]

    claims that your thermostat can be set higher with the low humidity air, allowing a net energy savings. Related Information Home Cooling Systems Air Conditioning Heat Pump Systems...

  8. List of Dehumidifiers Incentives | Open Energy Information

    Open Energy Info (EERE)

    Municipal Solid Waste Renewable Fuels Small Hydroelectric Wind Fuel Cells using Renewable Fuels Yes Alternative and Clean Energy State Grant Program (Pennsylvania) State Grant...

  9. Apparatus and method for recharging a string a avalanche transistors within a pulse generator

    DOE Patents [OSTI]

    Fulkerson, E. Stephen

    2000-01-01

    An apparatus and method for recharging a string of avalanche transistors within a pulse generator is disclosed. A plurality of amplification stages are connected in series. Each stage includes an avalanche transistor and a capacitor. A trigger signal, causes the apparatus to generate a very high voltage pulse of a very brief duration which discharges the capacitors. Charge resistors inject current into the string of avalanche transistors at various points, recharging the capacitors. The method of the present invention includes the steps of supplying current to charge resistors from a power supply; using the charge resistors to charge capacitors connected to a set of serially connected avalanche transistors; triggering the avalanche transistors; generating a high-voltage pulse from the charge stored in the capacitors; and recharging the capacitors through the charge resistors.

  10. A Polyanthraquinone-based Organic Cathode for High-performance Rechargeable

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magnesium-ion Batteries - Joint Center for Energy Storage Research May 9, 2016, Research Highlights A Polyanthraquinone-based Organic Cathode for High-performance Rechargeable Magnesium-ion Batteries Scientific Achievement A series of anthraquinonyl-based polymers (PAQS, 14PAQ, and 26PAQ) have been prepared and evaluated as high-performance organic cathodes for rechargeable Mg-ion batteries. Mg-14PAQ system shows the best cycling stability among the series: at the current rate of 0.5C, 104.9

  11. A validation of the [sup 3]H/[sup 3]He method for determining groundwater recharge

    SciTech Connect (OSTI)

    Solomon, D.K. ); Schiff, S.L. ); Poreda, R.J. ); Clarke, W.B. )

    1993-09-01

    Tritium and He isotopes have been measured at a site where groundwater flow is nearly vertical for a travel time of 100 years and where recharge rates are spatially variable. Because the mid-1960s [sup 3]H peak (arising from aboveground testing of thermonuclear devices) is well-defined, the vertical groundwater velocity is known with unusual accuracy at this site. Utilizing [sup 3]H and its stable daughter [sup 3]He to determine groundwater ages, we compute a recharge rate of 0.16 m/yr, which agrees to within about 5% of the value based on the depth of the [sup 3]H peak (measured both in 1986 and 1991) and two-dimensional modeling in an area of high recharge. Zero [sup 3]H/[sup 3]He age occurs at a depth that is approximately equal to the average depth of the annual low water table, even though the capillary fringe extends to land surface during most of the year at the study site. In an area of low recharge (0.05 m/yr) where the [sup 3]H peak (and hence the vertical velocity) is also well-defined, the [sup 3]H/[sup 3]He results could not be used to compute recharge because samples were not collected sufficiently far above the [sup 3]H peak; however, modeling indicates that the [sup 3]H/[sup 3]He age gradient near the water table is an accurate measure of vertical velocities in the low-recharge area. Because [sup 3]H and [sup 3]He have different diffusion coefficients, and because the amount of mechanical mixing is different in the area of high recharge than in the low-recharge area, we have separated the dispersive effects of mechanical mixing from molecular diffusion. We estimate a longitudinal dispersivity of 0.07 m and effective diffusion coefficients for [sup 3]H ([sup 3]HHO) and [sup 3]He of 2.4 x 10[sup [minus]5] and 1.3 x 10[sup [minus]4] m[sup 2]/day, respectively. 26 refs., 8 figs., 1 tab.

  12. Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    SciTech Connect (OSTI)

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

    2015-04-07

    A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

  13. 2,5-Dimethoxy-1,4-Benzoquinone (DMBQ) as Organic Cathode for Rechargeable

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magnesium-Ion Batteries - Joint Center for Energy Storage Research January 13, 2016, Research Highlights 2,5-Dimethoxy-1,4-Benzoquinone (DMBQ) as Organic Cathode for Rechargeable Magnesium-Ion Batteries Image for Organic Cathode Scientific Achievement 2,5-dimethoxyl-1,4-benzoquinone (DMBQ) was investigated as 2 V (vs Mg/Mg2+) organic cathode material for non-aqueous rechargeable magnesium-ion batteries Significance and Impact Mg-DMBQ batteries were demonstrated to work with a discharge

  14. Rechargeable Lithium-Air Batteries: Development of Ultra High Specific Energy Rechargeable Lithium-Air Batteries Based on Protected Lithium Metal Electrodes

    SciTech Connect (OSTI)

    2010-07-01

    BEEST Project: PolyPlus is developing the worlds first commercially available rechargeable lithium-air (Li-Air) battery. Li-Air batteries are better than the Li-Ion batteries used in most EVs today because they breathe in air from the atmosphere for use as an active material in the battery, which greatly decreases its weight. Li-Air batteries also store nearly 700% as much energy as traditional Li-Ion batteries. A lighter battery would improve the range of EVs dramatically. Polyplus is on track to making a critical breakthrough: the first manufacturable protective membrane between its lithiumbased negative electrode and the reaction chamber where it reacts with oxygen from the air. This gives the battery the unique ability to recharge by moving lithium in and out of the batterys reaction chamber for storage until the battery needs to discharge once again. Until now, engineers had been unable to create the complex packaging and air-breathing components required to turn Li-Air batteries into rechargeable systems.

  15. Anode Materials for Rechargeable Li-Ion Batteries

    SciTech Connect (OSTI)

    Fultz, B.

    2001-01-12

    This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

  16. Structural micro-porous carbon anode for rechargeable lithium-ion batteries

    DOE Patents [OSTI]

    Delnick, F.M.; Even, W.R. Jr.; Sylwester, A.P.; Wang, J.C.F.; Zifer, T.

    1995-06-20

    A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc. 6 figs.

  17. Structural micro-porous carbon anode for rechargeable lithium-ion batteries

    DOE Patents [OSTI]

    Delnick, Frank M.; Even, Jr., William R.; Sylwester, Alan P.; Wang, James C. F.; Zifer, Thomas

    1995-01-01

    A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc.

  18. Electrically recharged battery employing a packed/spouted bed metal particle electrode

    DOE Patents [OSTI]

    Siu, S.C.; Evans, J.W.; Salas-Morales, J.

    1995-08-15

    A secondary metal air cell, employing a spouted/packed metal particle bed and an air electrode, is described. More specifically a zinc air cell well suited for use in electric vehicles which is capable of being either electrically or hydraulically recharged. 5 figs.

  19. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    DOE Patents [OSTI]

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

    2014-06-17

    Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

  20. Recharge Data Package for the Immobilized Low-Activity Waste 2001 Performance Assessment

    SciTech Connect (OSTI)

    MJ Fayer; EM Murphy; JL Downs; FO Khan; CW Lindenmeier; BN Bjornstad

    2000-01-18

    Lockheed Martin Hanford Company (LMHC) is designing and assessing the performance of disposal facilities to receive radioactive wastes that are currently stored in single- and double-shell tanks at the Hanford Site. The preferred method of disposing of the portion that is classified as immobilized low-activity waste (ILAW) is to vitrify the waste and place the product in near-surface, shallow-land burial facilities. The LMHC project to assess the performance of these disposal facilities is known as the Hanford ILAW Performance Assessment (PA) Activity, hereafter called the ILAW PA project. The goal of this project is to provide a reasonable expectation that the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require predictions of contaminant migration from the facility. To make such predictions will require estimates of the fluxes of water moving through the sediments within the vadose zone around and beneath the disposal facility. These fluxes, loosely called recharge rates, are the primary mechanism for transporting contaminants to the groundwater. Pacific Northwest National Laboratory (PNNL) assists LMHC in their performance assessment activities. One of the PNNL tasks is to provide estimates of recharge rates for current conditions and long-term scenarios involving the shallow-land disposal of ILAW. Specifically, recharge estimates are needed for a filly functional surface cover; the cover sideslope, and the immediately surrounding terrain. In addition, recharge estimates are needed for degraded cover conditions. The temporal scope of the analysis is 10,000 years, but could be longer if some contaminant peaks occur after 10,000 years. The elements of this report compose the Recharge Data Package, which provides estimates of recharge rates for the scenarios being considered in the 2001 PA. Table S.1 identifies the surface features and

  1. Vehicle Technologies Office Merit Review 2015: Efficient Rechargeable Li/O2 Batteries Utilizing Stable Inorganic Molten Salt Electrolytes

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Liox at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about efficient rechargeable Li/O2 batteries...

  2. A Study Plan for Determining Recharge Rates at the Hanford Site Using Environmental Tracers

    SciTech Connect (OSTI)

    Murphy,, E. M.; Szecsody,, J. E.; Phillips,, S. J.

    1991-02-01

    This report presents a study plan tor estimating recharge at the Hanford Site using environmental tracers. Past operations at the Hanford Site have led to both soil and groundwater contamination, and recharge is one of the primary mechanisms for transporting contaminants through the vadose zone and into the groundwater. The prediction of contaminant movement or transport is one aspect of performance assessment and an important step in the remedial investigation/feasibility study (RI/FS) process. In the past, recharge has been characterized by collecting lysimeter data. Although lysimeters can generate important and reliable data, their limitations include 1) fixed location, 2) fixed sediment contents, 3) edge effects, 4) low rates, and 5) relatively short duration of measurement. These limitations impact the ability to characterize the spatial distribution of recharge at the Hanford Site, and thus the ability to predict contaminant movement in the vadose zone. An alternative to using fixed lysimeters for determining recharge rates in the vadose zone is to use environmental tracers. Tracers that have been used to study water movement in the vadose zone include total chloride, {sup 36}CI, {sup 3}H, and {sup 2}H/{sup 18}O. Atmospheric levels of {sup 36}CI and {sup 3}H increased during nuclear bomb testing in the Pacific, and the resulting "bomb pulse" or peak concentration can be measured in the soil profile. Locally, past operations at the Hanford Site have resu~ed in the atmospheric release of numerous chemical and isotopic tracers, including nitrate, {sup 129}I, and {sup 99}Tc. The radionuclides, in particular, reached a well-defined atmospheric peak in 1945. Atmospheric releases of {sup 129}I and {sup 99}Tc were greatly reduced by mid-1946, but nitrogen oxides continued to be released from the uranium separations facilities. As a result, the nitrate concentrations probably peaked in the mid-1950s, when the greatest number of separations facilities were operating

  3. Method of preparation of carbon materials for use as electrodes in rechargeable batteries

    DOE Patents [OSTI]

    Doddapaneni, Narayan; Wang, James C. F.; Crocker, Robert W.; Ingersoll, David; Firsich, David W.

    1999-01-01

    A method of producing carbon materials for use as electrodes in rechargeable batteries. Electrodes prepared from these carbon materials exhibit intercalation efficiencies of .apprxeq.80% for lithium, low irreversible loss of lithium, long cycle life, are capable of sustaining a high rates of discharge and are cheap and easy to manufacture. The method comprises a novel two-step stabilization process in which polymeric precursor materials are stabilized by first heating in an inert atmosphere and subsequently heating in air. During the stabilization process, the polymeric precursor material can be agitated to reduce particle fusion and promote mass transfer of oxygen and water vapor. The stabilized, polymeric precursor materials can then be converted to a synthetic carbon, suitable for fabricating electrodes for use in rechargeable batteries, by heating to a high temperature in a flowing inert atmosphere.

  4. Method of preparation of carbon materials for use as electrodes in rechargeable batteries

    DOE Patents [OSTI]

    Doddapaneni, N.; Wang, J.C.F.; Crocker, R.W.; Ingersoll, D.; Firsich, D.W.

    1999-03-16

    A method is described for producing carbon materials for use as electrodes in rechargeable batteries. Electrodes prepared from these carbon materials exhibit intercalation efficiencies of {approx_equal} 80% for lithium, low irreversible loss of lithium, long cycle life, are capable of sustaining a high rates of discharge and are cheap and easy to manufacture. The method comprises a novel two-step stabilization process in which polymeric precursor materials are stabilized by first heating in an inert atmosphere and subsequently heating in air. During the stabilization process, the polymeric precursor material can be agitated to reduce particle fusion and promote mass transfer of oxygen and water vapor. The stabilized, polymeric precursor materials can then be converted to a synthetic carbon, suitable for fabricating electrodes for use in rechargeable batteries, by heating to a high temperature in a flowing inert atmosphere. 4 figs.

  5. NANOSTRUCTURED METAL OXIDES FOR ANODES OF LI-ION RECHARGEABLE BATTERIES

    SciTech Connect (OSTI)

    Au, M.

    2009-12-04

    The aligned nanorods of Co{sub 3}O{sub 4} and nanoporous hollow spheres (NHS) of SnO{sub 2} and Mn{sub 2}O{sub 3} were investigated as the anodes for Li-ion rechargeable batteries. The Co{sub 3}O{sub 4} nanorods demonstrated 1433 mAh/g reversible capacity. The NHS of SnO{sub 2} and Mn{sub 2}O{sub 3} delivered 400 mAh/g and 250 mAh/g capacities respectively in multiple galvonastatic discharge-charge cycles. It was found that high capacity of NHS of metal oxides is sustainable attributed to their unique structure that maintains material integrity during cycling. The nanostructured metal oxides exhibit great potential as the new anode materials for Li-ion rechargeable batteries with high energy density, low cost and inherent safety.

  6. Computational studies of solid-state alkali conduction in rechargeable alkali-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deng, Zhi; Mo, Yifei; Ong, Shyue Ping

    2016-03-25

    The facile conduction of alkali ions in a crystal host is of crucial importance in rechargeable alkali-ion batteries, the dominant form of energy storage today. In this review, we provide a comprehensive survey of computational approaches to study solid-state alkali diffusion. We demonstrate how these methods have provided useful insights into the design of materials that form the main components of a rechargeable alkali-ion battery, namely the electrodes, superionic conductor solid electrolytes and interfaces. We will also provide a perspective on future challenges and directions. Here, the scope of this review includes the monovalent lithium- and sodium-ion chemistries that aremore » currently of the most commercial interest.« less

  7. The impact of a shallow biobarrier on water recharge patterns in a semi-arid environment

    SciTech Connect (OSTI)

    Laundre, J.W.

    1997-12-31

    This study attempted to measure the effect of a shallow biobarrier of gravel and cobble on water flow patterns during spring snow melt and recharge. The design consisted of 30 metal culverts 3 m in diameter and 1.6 m long, positioned on end. Test culverts contained 50-cm biobarrier of gravel or cobble and then an additional 50 cm of soil placed above the barrier layer. A neutron probe was used to measure soil moisture above and below the barrier. Measurements were made in the fall and again immediately after snow melt in the spring. During recharge, the biobarriers provided a capillary break which resulted in a pooling of water above the barrier layer. With sufficient snowmelt, the water can penetrate the break and possibly penetrate deeper than in the absence of the barrier layer.

  8. Santa Rosa Geysers Recharge Project: GEO-98-001. Final Report

    SciTech Connect (OSTI)

    Brauner, Edwin Jr.; Carlson, Daniel C.

    2002-10-01

    The Geysers steamfields in northern Sonoma County have produced reliable ''green'' power for many years. An impediment to long-term continued production has been the ability to provide a reliable source of injection water to replace water extracted and lost in the form of steam. The steamfield operators have historcially used cooling towers to recycle a small portion of the steam and have collected water during the winter months using stream extraction. These two sources, however, could not by themselves sustain the steamfield in the long term. The Lake County Reclaimed Water Project (SEGEP) was inititated in 1997 and provides another source of steamfield replenishment water. The Santa Rosa Geysers Recharge Project provides another significant step in replenishing the steamfield. In addition, the Santa Rosa Geysers Recharge Project has been built with capacity to potentially meet virtually all injection water requirements, when combined with these other sources. Figure 2.1 graphically depicts the combination of injection sources.

  9. Effects of the electrolyte composition on the electrode characteristics of rechargeable lithium batteries

    SciTech Connect (OSTI)

    Morita, Masayuki; Ishikawa, Masashi; Matsuda, Yoshiharu

    1995-12-31

    A variety of organic solvent-based electrolytes have been studied for ambient temperature, rechargeable lithium (ion) batteries. The ionic behavior of the electrolyte system was investigated through conductivity measurements. The electrochemical characteristics of carbon-based materials (carbon fiber and graphite) as the negative electrode were examined in different compositions of the organic electrolytes. The electrolyte composition as well as the structure of the electrode material greatly influenced the charge/discharge profiles of the electrode.

  10. New Materials for High-Energy, Long-Life Rechargeable Batteries | U.S. DOE

    Office of Science (SC) Website

    Office of Science (SC) New Materials for High-Energy, Long-Life Rechargeable Batteries Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 07.01.13

  11. Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method

    SciTech Connect (OSTI)

    Cooper, Clay A; Hershey, Ronald L; Healey, John M; Lyles, Brad F

    2013-07-01

    Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

  12. "Electrolyte Balloons" Make Rechargeable Batteries Safer | U.S. DOE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Science (SC) "Electrolyte Balloons" Make Rechargeable Batteries Safer Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information »

  13. Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries

    SciTech Connect (OSTI)

    Sun, Xiao -Guang; Fang, Youxing; Jiang, Xueguang; Yoshii, Kazuki; Tsuda, Tetsuya; Dai, Sheng

    2015-10-22

    Polymer gel electrolyte using AlCl3 complexed acrylamide as functional monomer and ionic liquids based on acidic mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and AlCl3 as plasticizer has been successfully prepared for the first time by free radical polymerization. Aluminum deposition is successfully obtained with a polymer gel membrane contianing 80 wt% ionic liquid. As a result, the polymer gel membranes are also good candidates for rechargeable aluminum ion batteries.

  14. Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Xiao -Guang; Fang, Youxing; Jiang, Xueguang; Yoshii, Kazuki; Tsuda, Tetsuya; Dai, Sheng

    2015-10-22

    Polymer gel electrolyte using AlCl3 complexed acrylamide as functional monomer and ionic liquids based on acidic mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and AlCl3 as plasticizer has been successfully prepared for the first time by free radical polymerization. Aluminum deposition is successfully obtained with a polymer gel membrane contianing 80 wt% ionic liquid. As a result, the polymer gel membranes are also good candidates for rechargeable aluminum ion batteries.

  15. X-ray diffraction and EXAFS analysis of materials for lithium-based rechargeable batteries

    SciTech Connect (OSTI)

    Sharkov, M. D., E-mail: mischar@mail.ioffe.ru; Boiko, M. E.; Bobyl, A. V.; Ershenko, E. M.; Terukov, E. I. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Zubavichus, Y. V. [National Research Centre Kurchatov Institute (Russian Federation)

    2013-12-15

    Lithium iron phosphate LiFePO{sub 4} (triphylite) and lithium titanate Li{sub 4}Ti{sub 5}O{sub 12} are used as components of a number of active materials in modern rechargeable batteries. Samples of these materials are studied by X-ray diffraction and extended X-ray absorption fine structure (EXAFS) spectroscopy. Hypotheses about the phase composition of the analyzed samples are formulated.

  16. Natural Recharge to the Unconfined Aquifer System on the Hanford Site from the Greater Cold Creek Watershed: Progress Report 2004

    SciTech Connect (OSTI)

    Waichler, Scott R.; Wigmosta, Mark S.; Coleman, Andre M.

    2004-09-14

    Movement of contaminants in groundwater at the Hanford Site is heavily dependent on recharge to the unconfined aquifer. As the effects of past artificial discharges dissipate, the water table is expected to return to more natural conditions, and natural recharge will become the driving force when evaluating future groundwater flow conditions and related contaminant transport. Previous work on the relationship of natural recharge to groundwater movement at the Hanford Site has focused on direct recharge from infiltrating rainfall and snowmelt within the area represented by the Sitewide Groundwater Model (SGM) domain. However, part of the groundwater recharge at Hanford is provided by flow from Greater Cold Creek watershed (GCC), a large drainage area on the western boundary of the Hanford Site that includes Cold Creek Valley, Dry Creek Valley, and the Hanford side of Rattlesnake Mountain. This study was undertaken to estimate the recharge from GCC, which is believed to enter the unconfined aquifer as both infiltrating streamflow and shallow subsurface flow. To estimate recharge, the Distributed Hydrology-Soil-Vegetation Model (DHSVM) was used to simulate a detailed water balance of GCC from 1956 to 2001 at a spatial resolution of 200~m and a temporal resolution of one hour. For estimating natural recharge to Hanford from watersheds along its western and southwestern boundaries, the most important aspects that need to be considered are 1)~distribution and relative magnitude of precipitation and evapotranspiration over the watershed, 2)~streamflow generation at upper elevations and infiltration at lower elevations during rare runoff events, and 3)~permeability of the basalt bedrock surface underlying the soil mantle.

  17. A High-Performance Rechargeable Iron Electrode for Large-Scale Battery-Based Energy Storage

    SciTech Connect (OSTI)

    Manohar, AK; Malkhandi, S; Yang, B; Yang, C; Prakash, GKS; Narayanan, SR

    2012-01-01

    Inexpensive, robust and efficient large-scale electrical energy storage systems are vital to the utilization of electricity generated from solar and wind resources. In this regard, the low cost, robustness, and eco-friendliness of aqueous iron-based rechargeable batteries are particularly attractive and compelling. However, wasteful evolution of hydrogen during charging and the inability to discharge at high rates have limited the deployment of iron-based aqueous batteries. We report here new chemical formulations of the rechargeable iron battery electrode to achieve a ten-fold reduction in the hydrogen evolution rate, an unprecedented charging efficiency of 96%, a high specific capacity of 0.3 Ah/g, and a twenty-fold increase in discharge rate capability. We show that modifying high-purity carbonyl iron by in situ electro-deposition of bismuth leads to substantial inhibition of the kinetics of the hydrogen evolution reaction. The in situ formation of conductive iron sulfides mitigates the passivation by iron hydroxide thereby allowing high discharge rates and high specific capacity to be simultaneously achieved. These major performance improvements are crucial to advancing the prospect of a sustainable large-scale energy storage solution based on aqueous iron-based rechargeable batteries. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.034208jes] All rights reserved.

  18. Estimation of natural ground water recharge for the performance assessment of a low-level waste disposal facility at the Hanford Site

    SciTech Connect (OSTI)

    Rockhold, M.L.; Fayer, M.J.; Kincaid, C.T.; Gee, G.W.

    1995-03-01

    In 1994, the Pacific Northwest Laboratory (PNL) initiated the Recharge Task, under the PNL Vitrification Technology Development (PVTD) project, to assist Westinghouse Hanford Company (WHC) in designing and assessing the performance of a low-level waste (LLW) disposal facility for the US Department of Energy (DOE). The Recharge Task was established to address the issue of ground water recharge in and around the LLW facility and throughout the Hanford Site as it affects the unconfined aquifer under the facility. The objectives of this report are to summarize the current knowledge of natural ground water recharge at the Hanford Site and to outline the work that must be completed in order to provide defensible estimates of recharge for use in the performance assessment of this LLW disposal facility. Recharge studies at the Hanford Site indicate that recharge rates are highly variable, ranging from nearly zero to greater than 100 mm/yr depending on precipitation, vegetative cover, and soil types. Coarse-textured soils without plants yielded the greatest recharge. Finer-textured soils, with or without plants, yielded the least. Lysimeters provided accurate, short-term measurements of recharge as well as water-balance data for the soil-atmosphere interface and root zone. Tracers provided estimates of longer-term average recharge rates in undisturbed settings. Numerical models demonstrated the sensitivity of recharge rates to different processes and forecast recharge rates for different conditions. All of these tools (lysimetry, tracers, and numerical models) are considered vital to the development of defensible estimates of natural ground water recharge rates for the performance assessment of a LLW disposal facility at the Hanford Site.

  19. Photoinduced absolute negative current in a symmetric molecular electronic bridge

    SciTech Connect (OSTI)

    Prociuk, Alexander; Dunietz, Barry D

    2010-09-28

    The study of current induced by photoradiating a molecular-based device under bias is of fundamental importance to the improvement of photoconductors and photovoltaics. In this technology, electron pumps generate an uphill current that opposes a potential drop and thereby recharges a fuel cell. While the modeled molecular electron pump is completely symmetric, the sign of the photocurrent is solely determined by the existing bias and the nature of photoinduced electronic excitations. The photoradiation induces nonequilibrium population of the electrode-coupled system. The dependence of the photocurrent on electrode coupling, photoradiation field strength, and applied bias are studied at a basic model level.

  20. Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries

    SciTech Connect (OSTI)

    Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

    2009-01-19

    Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

  1. High voltage rechargeable magnesium batteries having a non-aqueous electrolyte

    DOE Patents [OSTI]

    Doe, Robert Ellis; Lane, George Hamilton; Jilek, Robert E.; Hwang, Jaehee

    2016-03-22

    A rechargable magnesium battery having an non-aqueous electrolyte is provided. The properties of the electrolyte include high conductivity, high Coulombic efficiency, and an electrochemical window that can exceed 3.5 V vs. Mg/Mg.sup.+2. The use of the electrolyte promotes the electrochemical deposition and dissolution of Mg without the use of any Grignard reagents, other organometallic materials, tetraphenyl borate, or tetrachloroaluminate derived anions. Other Mg-containing electrolyte systems that are expected to be suitable for use in secondary batteries are also described.

  2. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, Thomas C.; McLarnon, Frank R.; Cairns, Elton J.

    1994-01-01

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

  3. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, T.C.; McLarnon, F.R.; Cairns, E.J.

    1994-04-12

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K[sub 2]CO[sub 3] salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics. 8 figures.

  4. Anodes for Rechargeable Lithium-Sulfur Batteries - Joint Center for Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Research 0, 2015, Research Highlights Anodes for Rechargeable Lithium-Sulfur Batteries Recent developments on the protection of the Li metal anode in Li-S batteries are reviewed. Scientific Achievement Recent developments on the protection of the Li metal anode in Li-S batteries are reviewed. The degradation mechanism of Li metal anode in Li-S batteries were analyzed and discussed. Various strategies used to minimize the corrosion of the Li anode and to mitigate the effect of the

  5. Stable isotope and groundwater flow dynamics of agricultural irrigation recharge into groundwater resources of the Central Valley, California

    SciTech Connect (OSTI)

    Davisson, M.L.; Criss, R.E.

    1995-01-01

    Intensive agricultural irrigation and overdraft of groundwater in the Central Valley of California profoundly affect the regional quality and availability of shallow groundwater resources. In the natural state, the {delta}{sup 18}O values of groundwater were relatively homogeneous (mostly -7.0 {+-} 0.5{per_thousand}), reflecting local meteoric recharge that slowly (1-3m/yr) flowed toward the valley axis. Today, on the west side of the valley, the isotope distribution is dominated by high {sup 18}O enclosures formed by recharge of evaporated irrigation waters, while the east side has bands of low {sup 18}O groundwater indicating induced recharge from rivers draining the Sierra Nevada mountains. Changes in {delta}{sup 18}O values caused by the agricultural recharge strongly correlate with elevated nitrate concentrations (5 to >100 mg/L) that form pervasive, non-point source pollutants. Small, west-side cities dependent solely on groundwater resources have experienced increases of >1.0 mg/L per year of nitrate for 10-30 years. The resultant high nitrates threaten the economical use of the groundwater for domestic purposes, and have forced some well shut-downs. Furthermore, since >80% of modern recharge is now derived from agricultural irrigation, and because modern recharge rates are {approximately}10 times those of the natural state, agricultural land retirement by urbanization will severely curtail the current safe-yields and promote overdraft pumping. Such overdrafting has occurred in the Sacramento metropolitan area for {approximately}40 years, creating cones of depression {approximately}25m deep. Today, groundwater withdrawal in Sacramento is approximately matched by infiltration of low {sup 18}O water (-11.0{per_thousand}) away from the Sacramento and American Rivers, which is estimated to occur at 100-300m/year from the sharp {sup 18}O gradients in our groundwater isotope map.

  6. Quantifying groundwater travel time near managed recharge operations using 35S as an intrinsic tracer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urióstegui, Stephanie H.; Bibby, Richard K.; Esser, Bradley K.; Clark, Jordan F.

    2016-04-23

    By identifying groundwater retention times near managed aquifer recharge (MAR) facilities is a high priority for managing water quality, especially for operations that incorporate recycled wastewater. In order to protect public health, California guidelines for Groundwater Replenishment Reuse Projects require a minimum 2–6 month subsurface retention time for recycled water depending on the level of disinfection, which highlights the importance of quantifying groundwater travel times on short time scales. This study developed and evaluated a new intrinsic tracer method using the naturally occurring radioisotope sulfur-35 (35S). The 87.5 day half-life of 35S is ideal for investigating groundwater travel times onmore » the <1 year timescale of interest to MAR managers. Natural concentrations of 35S found in water as dissolved sulfate (35SO4) were measured in source waters and groundwater at the Rio Hondo Spreading Grounds in Los Angeles County, CA, and Orange County Groundwater Recharge Facilities in Orange County, CA. 35SO4 travel times are comparable to travel times determined by well-established deliberate tracer studies. The study also revealed that 35SO4 in MAR source water can vary seasonally and therefore careful characterization of 35SO4 is needed to accurately quantify groundwater travel time. But, more data is needed to fully assess whether or not this tracer could become a valuable tool for managers.« less

  7. Electron radiography

    DOE Patents [OSTI]

    Merrill, Frank E.; Morris, Christopher

    2005-05-17

    A system capable of performing radiography using a beam of electrons. Diffuser means receive a beam of electrons and diffuse the electrons before they enter first matching quadrupoles where the diffused electrons are focused prior to the diffused electrons entering an object. First imaging quadrupoles receive the focused diffused electrons after the focused diffused electrons have been scattered by the object for focusing the scattered electrons. Collimator means receive the scattered electrons and remove scattered electrons that have scattered to large angles. Second imaging quadrupoles receive the collimated scattered electrons and refocus the collimated scattered electrons and map the focused collimated scattered electrons to transverse locations on an image plane representative of the electrons' positions in the object.

  8. Rechargeable lithium battery for use in applications requiring a low to high power output

    DOE Patents [OSTI]

    Bates, John B.

    1997-01-01

    Rechargeable lithium batteries which employ characteristics of thin-film batteries can be used to satisfy power requirements within a relatively broad range. Thin-film battery cells utilizing a film of anode material, a film of cathode material and an electrolyte of an amorphous lithium phosphorus oxynitride can be connected in series or parallel relationship for the purpose of withdrawing electrical power simultaneously from the cells. In addition, such battery cells which employ a lithium intercalation compound as its cathode material can be connected in a manner suitable for supplying power for the operation of an electric vehicle. Still further, by incorporating within the battery cell a relatively thick cathode of a lithium intercalation compound, a relatively thick anode of lithium and an electrolyte film of lithium phosphorus oxynitride, the battery cell is rendered capable of supplying power for any of a number of consumer products, such as a laptop computer or a cellular telephone.

  9. Rechargeable lithium battery for use in applications requiring a low to high power output

    DOE Patents [OSTI]

    Bates, John B.

    1996-01-01

    Rechargeable lithium batteries which employ characteristics of thin-film batteries can be used to satisfy power requirements within a relatively broad range. Thin-film battery cells utilizing a film of anode material, a film of cathode material and an electrolyte of an amorphorus lithium phosphorus oxynitride can be connected in series or parallel relationship for the purpose of withdrawing electrical power simultaneously from the cells. In addition, such battery cells which employ a lithium intercalation compound as its cathode material can be connected in a manner suitable for supplying power for the operation of an electric vehicle. Still further, by incorporating within the battery cell a relatively thick cathode of a lithium intercalation compound, a relatively thick anode of lithium and an electrolyte film of lithium phosphorus oxynitride, the battery cell is rendered capable of supplying power for any of a number of consumer products, such as a laptop computer or a cellular telephone.

  10. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, Thomas C.; McLarnon, Frank R.; Cairns, Elton J.

    1995-01-01

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing one or more hydroxides having the formula M(OH), one or more fluorides having the formula MF, and one or more carbonates having the formula M.sub.2 CO.sub.3, where M is a metal selected from the group consisting of alkali metals. The electrolyte inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

  11. Layer cathode methods of manufacturing and materials for Li-ion rechargeable batteries

    DOE Patents [OSTI]

    Kang, Sun-Ho; Amine, Khalil

    2008-01-01

    A positive electrode active material for lithium-ion rechargeable batteries of general formula Li.sub.1+xNi.sub..alpha.Mn.sub..beta.A.sub..gamma.O.sub.2 and further wherein A is Mg, Zn, Al, Co, Ga, B, Zr, or Ti and 0

  12. High power rechargeable thermal battery. Final report, 1 September 1996-31 July 1997

    SciTech Connect (OSTI)

    Kaun, T.D.

    1997-08-15

    Report developed under STTR contract; a proof of concept for a portable, rechargeable thermal battery (RTB). Including a superinsulated case, a lightweight (10 lb) RTB can provide 250W for 2-6h at 140 Wh/kg with days of activation between recharging. It can also provide 1 kW pulses (30s) throughout its capacity. The RTB at 10 lbs 250W fills a gap in power supply capability for ARMY field operations under which motor generators cannot be down-sized (about 40 lbs). Three accomplishments have lead to the portable RTB. (1) Increased specific energy by way of high rate, thick electrode LiAl/FeS2 with CuFeS2 cells. (No Ni or Co content) (2) A vacuum-insulated case enables versitility (3W heat loss for days of operation, no heat signature) (3) High durability under abusive field conditions (safety discharge to 0 volts, no overheating at full power). Durability and safety are key features of the Phase I demonstration. A 4-cell battery RTB was operated for 140 cycles under full capacity, constant power discharges. More than twenty thermal cycles, some deactivations during charging or discharging, showed no ill effects. (It uses MgO powder separator). Overcharging and overdischarging posed no safety problems. The RTB has inherent battery charge/discharge balancing which remains a problem for Li-ion, Li/polymer batteries. Also RTB has no organic or Ni/Co compounds which avoids toxicity and explosion hazards. Improved RTB design gives prospect for low cost commercial battery applications. The elevated operating temperature of RTB provides a unique symbiotic-type technology with cheap getters (gas absorbers) forming/sustaining the vacuum insulated housing and dramatically-extending the operating life for 2-3 days after activation. It is immune to hot/cold ambient temperatures, and can be operated continuously with periodic charging. A 25 year shelf life can be anticipated.

  13. Within-Day Recharge of Plug-In Hybrid Electric Vehicles: Energy Impact of Public Charging Infrastructure

    SciTech Connect (OSTI)

    Dong, Jing; Lin, Zhenhong

    2012-01-01

    This paper studies the role of public charging infrastructure in increasing PHEV s share of driving on electricity and the resulting petroleum use reduction. Using vehicle activity data obtained from the GPS-tracking household travel survey in Austin, Texas, gasoline and electricity consumptions of PHEVs in real world driving context are estimated. Driver s within-day recharging behavior, constrained by travel activities and public charger network, is modeled as a boundedly rational decision and incorporated in the energy use estimation. The key findings from the Austin dataset include: (1) public charging infrastructure makes PHEV a competitive vehicle choice for consumers without a home charger; (2) providing sufficient public charging service is expected to significantly reduce petroleum consumption of PHEVs; and (3) public charging opportunities offer greater benefits for PHEVs with a smaller battery pack, as within-day recharges compensate battery capacity.

  14. Within-Day Recharge of Plug-In Hybrid Electric Vehicles: Energy Impact of Public Charging Infrastructure

    SciTech Connect (OSTI)

    Dong, Jing; Lin, Zhenhong

    2012-01-01

    This paper examines the role of public charging infrastructure in increasing the share of driving on electricity that plug-in hybrid electric vehicles might exhibit, thus reducing their gasoline consumption. Vehicle activity data obtained from a global positioning system tracked household travel survey in Austin, Texas, is used to estimate gasoline and electricity consumptions of plug-in hybrid electric vehicles. Drivers within-day recharging behavior, constrained by travel activities and public charger availability, is modeled. It is found that public charging offers greater fuel savings for hybrid electric vehicles s equipped with smaller batteries, by encouraging within-day recharge, and providing an extensive public charging service is expected to reduce plug-in hybrid electric vehicles gasoline consumption by more than 30% and energy cost by 10%, compared to the scenario of home charging only.

  15. Self-Assembled Monolayers of n-Alkanethiols Suppress Hydrogen Evolution and Increase the Efficiency of Rechargeable Iron Battery Electrodes

    SciTech Connect (OSTI)

    Malkhandi, S; Yang, B; Manohar, AK; Prakash, GKS; Narayanan, SR

    2013-01-09

    Iron-based rechargeable batteries, because of their low cost, eco-friendliness, and durability, are extremely attractive for large-scale energy storage. A principal challenge in the deployment of these batteries is their relatively low electrical efficiency. The low efficiency is due to parasitic hydrogen evolution that occurs on the iron electrode during charging and idle stand. In this study, we demonstrate for the first time that linear alkanethiols are very effective in suppressing hydrogen evolution on alkaline iron battery electrodes. The alkanethiols form self-assembled monolayers on the iron electrodes. The degree of suppression of hydrogen evolution by the alkanethiols was found to be greater than 90%, and the effectiveness of the alkanethiol increased with the chain length. Through steady-state potentiostatic polarization studies and impedance measurements on high-purity iron disk electrodes, we show that the self-assembly of alkanethiols suppressed the parasitic reaction by reducing the interfacial area available for the electrochemical reaction. We have modeled the effect of chain length of the alkanethiol on the surface coverage, charge-transfer resistance, and double-layer capacitance of the interface using a simple model that also yields a value for the interchain interaction energy. We have verified the improvement in charging efficiency resulting from the use of the alkanethiols in practical rechargeable iron battery electrodes. The results of battery tests indicate that alkanethiols yield among the highest faradaic efficiencies reported for the rechargeable iron electrodes, enabling the prospect of a large-scale energy storage solution based on low-cost iron-based rechargeable batteries.

  16. Novel stable, non-complexing anions for rechargeable lithium batteries. Phase 1

    SciTech Connect (OSTI)

    Dominey, L.A.

    1987-09-05

    The project was initiated to synthesize two new lithium salts, LiN(CF3SO2)2 and LiSbF6, and to investigate the use of these salts in ambient temperature rechargeable Li/TiS2 laboratory cells. Systematic investigations were carried out on their synthesis, purification, chemical and electrochemical stability, conductivity, and cycleability in various aprotic organic solvents. Quantitative (>98%) preparation of LiN(CF3SO2)2 was achieved with ease, but recrystallization from dioxane failed to produce salt of higher purity. Nevertheless, open circuit stability tests in several organic solvents were better than those obtained with commercially available LiAsF6-based electrolyte. Conductivities of the new salts in THF, 1,3-dioxolane, and sulfolane were all sufficient to permit cycling studies. Electrochemical investigation indicated that LiN(CF3SO2)2 was stable over a wide potential range, i.e., from 4V to 0.5V vs Li at a glassy carbon working electrode. These characteristics probably contribute to high Li/TiS2 full cell cycle numbers in dioxolane and sulfolane when compared to LiAsF6 in the same solvents. Because of the reactivity of LiSbF6, no cycling studies were carried out on this salt.

  17. Recharge Data for the Islands of Kauai, Lanai and Molokai, Hawaii

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Recharge data for the islands of Kauai, Lanai and Molokai in shapefile format. These data are from the following sources: Whittier, R.B and A.I. El-Kadi. 2014. Human Health and Environmental Risk Ranking of On-Site Sewage Disposal systems for the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final, Prepared for Hawaii Dept. of Health, Safe Drinking Water Branch by the University of Hawaii, Dept. of Geology and Geophysics. (for Kauai, Lanai, Molokai). Shade, P.J., 1995, Water Budget for the Island of Kauai, Hawaii, USGS Water-Resources Investigations Report 95-4128, 25 p. (for Kauai). Izuka, S.K. and D.S. Oki, 2002 Numerical simulation of ground-water withdrawals in the Southern Lihue Basin, Kauai, Hawaii, U.S. Geologic Survey Water-Resources Investigations Report 01-4200, 52 pgs. (for Kauai). Hardy, W.R., 1996, A Numerical Groundwater Model for the Island of Lanai, Hawaii - CWRM Report No., CWRM-1, Commission on Water Resources Management, Department of Natural Resources, State of Hawaii, Honolulu, HI. (for Lanai). Oki, D.S., 1997, Geohydrology and numerical Simulation of the Ground-Water Flow System of Molokai, Hawaii, USGS Water-Resources Investigations Report 97-4176, 62 p. (for Molokai).

  18. Understanding the Factors Affecting the Formation of Carbonyl Iron Electrodes in Rechargeable Alkaline Iron Batteries

    SciTech Connect (OSTI)

    Manohar, AK; Yang, CG; Malkhandi, S; Yang, B; Prakash, GKS; Narayanan, SR

    2012-01-01

    Rechargeable iron-based alkaline batteries such as iron - air and nickel - iron batteries are attractive for large-scale electrical energy storage because iron is inexpensive, globally-abundant and environmentally-friendly. Further, the iron electrode is known for its robustness to repeated charge/discharge cycling. During manufacturing these batteries are charged and discharged 20 to 50 times during which the discharge capacity of the iron electrode increases gradually and attains a stable value. This process of achieving stable capacity is called formation. In this study we have focused our efforts on understanding the effect of electrode design on formation. We have investigated the role of wetting agent, pore-former additive, and sulfide additive on the formation of carbonyl iron electrodes. The wetting agent increased the rate of formation while the pore-former additive increased the final capacity. Sodium sulfide added to the electrolyte worked as a de-passivation agent and increased the final discharge capacity. We have proposed a phenomenological model for the formation process that predicts the rate of formation and final discharge capacity given the design parameters for the electrode. The understanding gained here will be useful in reducing the time lost in formation and in maximizing the utilization of the iron electrode. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.021301jes] All rights reserved.

  19. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte

    SciTech Connect (OSTI)

    Xiao, Jie; Hu, Jian Z.; Wang, Deyu; Hu, Dehong; Xu, Wu; Graff, Gordon L.; Nie, Zimin; Liu, Jun; Zhang, Jiguang

    2011-07-01

    In order to understand the nature of the limited cycle life and poor energy efficiency associated with the secondary Li-O2 batteries the discharge products of primary Li-O2 cells at different depth of discharge (DOD) are systematically analyzed in this work. It is revealed that if discharged to 2.0 V a small amount of Li2O2 coexist with Li2CO3 and RO-(C=O)-OLi) in alkyl carbonate-based electrolyte. Further discharging the air electrodes to below 2.0 V the amount of Li2CO3 and LiRCO3 increases significantly due to the severe electrolyte decomposition. There is no Li2O detected in this alkyl carbonate electrolyte regardless of DOD. It is also found that the alkyl carbonate based electrolyte begins to decompose at 4.0 V during charging under the combined influences from the high surface area carbon, the nickel metal current collector and the oxygen atmosphere. Accordingly the impedance of the Li-O2 cell continues to increase after each discharge and recharge process indicating a repeated plating of insoluble lithium salts on the carbon surface. Therefore the whole carbon electrode becomes completely insulated only after a few cycles and loses the function of providing active tri-phase regions for the Li-oxygen batteries.

  20. Electron Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Pierre Kennepohl1,2 and Edward Solomon1* 1Department of Chemistry, Stanford University, Stanford, CA 94305 Electron transfer, or the act of moving an electron from one place to another, is amongst the simplest of chemical processes, yet certainly one of the most critical. The process of efficiently and controllably moving electrons around is one of the primary regulation mechanisms in biology. Without stringent control of electrons in living organisms, life could simply not exist. For example,

  1. Final cost reduction study for the Geysers Recharge Alternative. Volume 1

    SciTech Connect (OSTI)

    1997-11-01

    The purpose of this study is to determine whether or not cost reduction opportunities exist for the Geysers Recharge Alternative as defined in the Santa Rosa Subregional Long-Term Wastewater Project EIR/EIS. The City of Santa Rosa has been directed to have a plan for reclaimed water disposal in place by 1999 which will meet future capacity needs under all weather conditions. A Draft EIR/EIS released in July 1996 and a Final EIR certified in June 1997 examine four primary alternatives plus the No Action Alternative. Two of the primary alternatives involve agricultural irrigation with reclaimed water, either in western or southern Sonoma County. Another involves increased discharge of reclaimed water into the Russian River. The fourth involves using reclaimed water to replenish the geothermal reservoir at the Geysers. The addition of this water source would enable the Geysers operators to produce more steam from the geothermal area and thereby prolong the life and economic production level of the steamfield and the geothermal power plants supplied by the steamfield. This study provides additional refined cost estimates for new scenarios which utilize an alternative pipeline alignment and a range of reclaimed water flows, which deliver less water to the Geysers than proposed in the EIR/EIS (by distributing flow to other project components). Also, electrical power rates were revised to reflect the recent changes in costs associated with deregulation of the power industry. In addition, this report provides information on sources of potential public and private funding available and future environmental documentation required if the cost reduction scenarios were to be selected by the City as part of their preferred alternative.

  2. Webinar: Test Procedures for Dehumidifiers; Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    DOE is conducting a public meeting and webinar for the notice of proposed rulemaking regarding test procedures for residential dehumifiers. 79 FR 29271 (May 22, 2014). For more information, please...

  3. Consumer Electronics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Events Expand News & Events Skip navigation links Residential Residential Lighting Energy Star Appliances Consumer Electronics Heat Pump Water Heaters Electric Storage Water...

  4. Underground Test Area Subproject Phase I Data Analysis Task. Volume III - Groundwater Recharge and Discharge Data Documentation Package

    SciTech Connect (OSTI)

    1996-10-01

    Volume III of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the data covering groundwater recharge and discharge. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.

  5. Chemically and compositionally modified solid solution disordered multiphase nickel hydroxide positive electrode for alkaline rechargeable electrochemical cells

    DOE Patents [OSTI]

    Ovshinsky, Stanford R.; Corrigan, Dennis; Venkatesan, Srini; Young, Rosa; Fierro, Christian; Fetcenko, Michael A.

    1994-01-01

    A high capacity, long cycle life positive electrode for use in an alkaline rechargeable electrochemical cell comprising: a solid solution nickel hydroxide material having a multiphase structure that comprises at least one polycrystalline .gamma.-phase including a polycrystalline .gamma.-phase unit cell comprising spacedly disposed plates with at least one chemical modifier incorporated around the plates, the plates having a range of stable intersheet distances corresponding to a 2.sup.+ oxidation state and a 3.5.sup.+, or greater, oxidation state; and at least one compositional modifier incorporated into the solid solution nickel hydroxide material to promote the multiphase structure.

  6. Enhancing the Performance of the Rechargeable Iron Electrode in Alkaline Batteries with Bismuth Oxide and Iron Sulfide Additives

    SciTech Connect (OSTI)

    Manohar, AK; Yang, CG; Malkhandi, S; Prakash, GKS; Narayanan, SR

    2013-09-07

    Iron-based alkaline rechargeable batteries have the potential of meeting the needs of large-scale electrical energy storage because of their low-cost, robustness and eco-friendliness. However, the widespread commercial deployment of iron-based batteries has been limited by the low charging efficiency and the poor discharge rate capability of the iron electrode. In this study, we have demonstrated iron electrodes containing bismuth oxide and iron sulfide with a charging efficiency of 92% and capable of being discharged at the 3C rate. Such a high value of charging efficiency combined with the ability to discharge at high rates is being reported for the first time. The bismuth oxide additive led to the in situ formation of elemental bismuth and a consequent increase in the overpotential for the hydrogen evolution reaction leading to an increase in the charging efficiency. We observed that the sulfide ions added to the electrolyte and iron sulfide added to the electrode mitigated-electrode passivation and allowed for continuous discharge at high rates. At the 3C discharge rate, a utilization of 0.2 Ah/g was achieved. The performance level of the rechargeable iron electrode demonstrated here is attractive for designing economically-viable large-scale energy storage systems based on alkaline nickel-iron and iron-air batteries. (C) 2013 The Electrochemical Society. All rights reserved.

  7. Electron tube

    DOE Patents [OSTI]

    Suyama, Motohiro; Fukasawa, Atsuhito; Arisaka, Katsushi; Wang, Hanguo

    2011-12-20

    An electron tube of the present invention includes: a vacuum vessel including a face plate portion made of synthetic silica and having a surface on which a photoelectric surface is provided, a stem portion arranged facing the photoelectric surface and made of synthetic silica, and a side tube portion having one end connected to the face plate portion and the other end connected to the stem portion and made of synthetic silica; a projection portion arranged in the vacuum vessel, extending from the stem portion toward the photoelectric surface, and made of synthetic silica; and an electron detector arranged on the projection portion, for detecting electrons from the photoelectric surface, and made of silicon.

  8. Electronic Coupling Dependence of Ultrafast Interfacial Electron...

    Office of Scientific and Technical Information (OSTI)

    Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer on Nanocrystalline Thin Films and Single Crystal Citation Details In-Document Search Title: Electronic ...

  9. Electronic system

    DOE Patents [OSTI]

    Robison, G H; Dickson, J F

    1960-11-15

    An electronic system is designed for indicating the occurrence of a plurality of electrically detectable events within predetermined time intervals. The system comprises separate input means electrically associated with the events under observation an electronic channel associated with each input means, including control means and indicating means; timing means adapted to apply a signal from the input means after a predetermined time to the control means to deactivate each of the channels; and means for resetting the system to its initial condition after the observation of each group of events. (D.L.C.)

  10. ELECTRONIC SYSTEM

    DOE Patents [OSTI]

    Robison, G.H. et al.

    1960-11-15

    An electronic system is described for indicating the occurrence of a plurality of electrically detectable events within predetermined time intervals. It is comprised of separate input means electrically associated with the events under observation: an electronic channel associated with each input means including control means and indicating means; timing means associated with each of the input means and the control means and adapted to derive a signal from the input means and apply it after a predetermined time to the control means to effect deactivation of each of the channels; and means for resetting the system to its initial condition after observation of each group of events.

  11. Determining flow, recharge, and vadose zonedrainage in anunconfined aquifer from groundwater strontium isotope measurements, PascoBasin, WA

    SciTech Connect (OSTI)

    mjsingleton@lbl.gov

    2004-06-29

    Strontium isotope compositions (87Sr/86Sr) measured in groundwater samples from 273 wells in the Pasco Basin unconfined aquifer below the Hanford Site show large and systematic variations that provide constraints on groundwater recharge, weathering rates of the aquifer host rocks, communication between unconfined and deeper confined aquifers, and vadose zone-groundwater interaction. The impact of millions of cubic meters of wastewater discharged to the vadose zone (103-105 times higher than ambient drainage) shows up strikingly on maps of groundwater 87Sr/86Sr. Extensive access through the many groundwater monitoring wells at the site allows for an unprecedented opportunity to evaluate the strontium geochemistry of a major aquifer, hosted primarily in unconsolidated sediments, and relate it to both long term properties and recent disturbances. Groundwater 87Sr/86Sr increases systematically from 0.707 to 0.712 from west to east across the Hanford Site, in the general direction of groundwater flow, as a result of addition of Sr from the weathering of aquifer sediments and from diffuse drainage through the vadose zone. The lower 87Sr/86Sr groundwater reflects recharge waters that have acquired Sr from Columbia River Basalts. Based on a steady-state model of Sr reactive transport and drainage, there is an average natural drainage flux of 0-1.4 mm/yr near the western margin of the Hanford Site, and ambient drainage may be up to 30 mm/yr in the center of the site assuming an average bulk rock weathering rate of 10-7.5 g/g/yr.

  12. Rechargeability and economic aspects of alkaline zinc-manganese dioxide cells for electrical storage and load leveling

    SciTech Connect (OSTI)

    Ingale, ND; Gallaway, JW; Nyce, M; Couzis, A; Banerjee, S

    2015-02-15

    Batteries based on manganese dioxide (MnO2) cathodes are good candidates for grid-scale electrical energy storage, as MnO2 is low-cost, relatively energy dense, safe, water-compatible, and non-toxic. Alkaline Zn-MnO2 cells, if cycled at reduced depth of discharge (DOD), have been found to achieve substantial cycle life with battery costs projected to be in the range of $100 to 150 per kWh (delivered). Commercialization of rechargeable Zn-MnO2 batteries has in the past been hampered due to poor cycle life. In view of this, the work reported here focuses on the long-term rechargeability of prismatic MnO2 cathodes at reduced DOD when exposed to the effects of Zn anodes and with no additives or specialty materials. Over 3000 cycles is shown to be obtainable at 10% DOD with energy efficiency >80%. The causes of capacity fade during long-term cycling are also investigated and appear to be mainly due to the formation of irreversible manganese oxides in the cathode. Analysis of the data indicates that capacity loss is rapid in the first 250 cycles, followed by a regime of stability that can last for thousands of cycles. A model has been developed that captures the behavior of the cells investigated using measured state of charge (SOC) data as input. An approximate economic analysis is also presented to evaluate the economic viability of Zn-MnO2 batteries based on the experiments reported here. (C) 2014 Elsevier B.V. All rights reserved.

  13. ELECTRONIC MULTIPLIER

    DOE Patents [OSTI]

    Collier, D.M.; Meeks, L.A.; Palmer, J.P.

    1961-01-31

    S>An electronic multiplier is described for use in analog computers. Two electrical input signals are received; one controls the slope of a saw-tooth voltage wave while the other controls the time duration of the wave. A condenser and diode clamps are provided to sustain the crest voltage reached by the wave, and for storing that voltage to provide an output signal which is a steady d-c voltage.

  14. Electron Bernstein

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bernstein wave emission from an overdense reversed field pinch plasma P. K. Chattopadhyay, J. K. Anderson, T. M. Biewer, D. Craig, and C. B. Forest a) Department of Physics, University of Wisconsin, Madison, Wisconsin 53706 R. W. Harvey CompX, Del Mar, California 92014 A. P. Smirnov Moscow State University, Moscow, Russia ͑Received 11 October 2001; accepted 20 November 2001͒ Blackbody levels of emission in the electron cyclotron range of frequencies have been observed from an overdense (␻ pe

  15. ELECTRON GUN

    DOE Patents [OSTI]

    Christofilos, N.C.; Ehlers, K.W.

    1960-04-01

    A pulsed electron gun capable of delivering pulses at voltages of the order of 1 mv and currents of the order of 100 amperes is described. The principal novelty resides in a transformer construction which is disposed in the same vacuum housing as the electron source and accelerating electrode structure of the gun to supply the accelerating potential thereto. The transformer is provided by a plurality of magnetic cores disposed in circumferentially spaced relation and having a plurality of primary windings each inductively coupled to a different one of the cores, and a helical secondary winding which is disposed coaxially of the cores and passes therethrough in circumferential succession. Additional novelty resides in the disposition of the electron source cathode filament input leads interiorly of the transformer secondary winding which is hollow, as well as in the employment of a half-wave filament supply which is synchronously operated with the transformer supply such that the transformer is pulsed during the zero current portions of the half-wave cycle.

  16. Electronic Coupling Dependence of Ultrafast Interfacial Electron...

    Office of Scientific and Technical Information (OSTI)

    Electron Transfer on Nanocrystalline Thin Films and Single Crystal Lian, Tianquan 14 SOLAR ENERGY The long-term goal of the proposed research is to understand electron transfer...

  17. Flow-Assisted Alkaline Battery: Low-Cost Grid-Scale Electrical Storage using a Flow-Assisted Rechargeable Zinc-Manganese Dioxide Battery

    SciTech Connect (OSTI)

    2010-09-15

    GRIDS Project: Traditional consumer-grade disposable batteries are made of Zinc and Manganese, 2 inexpensive, abundant, and non-toxic metals. But these disposable batteries can only be used once. If they are recharged, the Zinc in the battery develops filaments called dendrites that grow haphazardly and disrupt battery performance, while the Manganese quickly loses its ability to store energy. CUNY Energy Institute is working to tame dendrite formation and to enhance the lifetime of Manganese in order to create a long-lasting, fully rechargeable battery for grid-scale energy storage. CUNY Energy Institute is also working to reduce dendrite formation by pumping fluid through the battery, enabling researchers to fix the dendrites as theyre forming. The team has already tested its Zinc battery through 3,000 recharge cycles (and counting). CUNY Energy Institute aims to demonstrate a better cycle life than lithium-ion batteries, which can be up to 20 times more expensive than Zinc-based batteries.

  18. A Fundamental Study on the [(?-Cl)3Mg2(THF)6]+ Dimer Electrolytes for Rechargeable Mg Batteries

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Cox, Jonathan T.; Hu, Dehong; Deng, Xuchu; Hu, Jian Z.; Hu, Mary Y.; Xiao, Jie; Shao, Yuyan; Tang, Keqi; Liu, Jun

    2015-01-01

    We present a fundamental study on [(?-Cl)3Mg2(THF)6]+dimer electrolytes using various physical methods including Subambient Pressure Ionization with Nanoelectrospray Mass spectrometry (SPIN-MS), Raman spectroscopy, 25Mg{1H} NMR, 27Al{1H} NMR and electrochemical analysis. For the first time, long time sought THF solvated [MgCl]+ species was experimentally characterized by SPIN mass spectrometry in the solution of the Mgdimer containing electrolyte, confirming the mono-Cl- abstraction reaction between MgCl2 and an Al Lewis acid. Solvated MgCl2 in the electrolyte was confirmed by Raman spectroscopy. The experimental results establish the previously proposed dimerization equilibrium of solvated [MgCl]+ and MgCl2 with [(?-Cl)3Mg2(THF)6]+. 25Mg{1H} NMR, 27Al{1H} NMR and electrochemical analysis on chloration reaction of [(?-Cl)3Mg2(THF)6]AlPh3Cl with external Cl- led to further insights on the coordination chemistry of the dimer electrolyte. Finally, a comprehensive mechanism is proposed for the reversible electrochemical Mg deposition and stripping and Mg2+ and Cl- ion transports of the Mg dimer electrolytes in rechargeable Mg batteries.

  19. Conversion of Russian Defense Enterprises to the production of rechargeable batteries and battery packs. Volume 1. Export trade information

    SciTech Connect (OSTI)

    1996-06-01

    This report, prepared by E-Tech, Inc., was funded by the U.S. Trade and Development Agency on behalf of the International Integration Association of Moscow, Russia. It presents the results of a study which was conducted to assess the economic and technical feasibility of converting the facilities of three Russian defense enterprises to the production of rechargeable batteries and battery packs for sale to the Russian domestic market and to international commercial markets. The three issues that are addressed in the report include: (1) Whether or not a project of this nature can be successful in present-day Russia; (2) Are the Russian enterprises identified for this study are capable of executing the project; and (3) Whether a U.S. company with extensive battery manufacturing experience can carry out a project in Russia. The report is divided into the following sections: (1) Executive Summary; (2) Introduction; (3) Background; (4) Technical Overview; (5) Market Overview; (6) Project Description; (7) Socioeconomic Benefits; (8) Legal Structure; (9) Appendices.

  20. A fundamental study on the [(μ-Cl)3 Mg2 (THF)6 ]+ dimer electrolytes for rechargeable Mg batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Tianbiao; Cox, Jonathan T.; Hu, Dehong; Deng, Xuchu; Hu, Jianzhi; Hu, Mary Y.; Xiao, Jie; Shao, Yuyan; Tang, Keqi; Liu, Jun

    2015-01-05

    We present a fundamental study on [(μ-Cl)3 Mg2 (THF)6 ]+ dimer electrolytes using various physical methods including Subambient Pressure Ionization with Nanoelectrospray Mass spectrometry (SPIN-MS), Raman spectroscopy, 25Mg{1H} NMR, 27Al{1H} NMR and electrochemical analysis. For the first time, long time sought THF solvated [MgCl]+ species was experimentally characterized by SPIN mass spectrometry in the solution of the Mgdimer containing electrolyte, confirming the mono-Cl- abstraction reaction between MgCl2 and an Al Lewis acid. Solvated MgCl2 in the electrolyte was confirmed by Raman spectroscopy. The experimental results establish the previously proposed dimerization equilibrium of solvated [MgCl]+ and MgCl2 with [(μ-Cl)3Mg2(THF)6]+.more » 25Mg{1H} NMR, 27Al{1H} NMR and electrochemical analysis on chloration reaction of [(μ-Cl)3Mg2(THF)6]AlPh3Cl with external Cl- led to further insights on the coordination chemistry of the dimer electrolyte. Finally, a comprehensive mechanism is proposed for the reversible electrochemical Mg deposition and stripping and Mg2+ and Cl- ion transports of the Mg dimer electrolytes in rechargeable Mg batteries.« less

  1. Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries

    DOE Patents [OSTI]

    Kang, Sun-Ho; Amine, Khalil

    2008-10-14

    A number of materials with the composition Li.sub.1+xNi.sub..alpha.Mn.sub..beta.Co.sub..gamma.M'.sub..delta.O.sub.2-- zF.sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, .alpha. is between about 0.2 and 0.6, .beta. is between about 0.2 and 0.6, .gamma. is between about 0 and 0.3, .delta. is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li.sub.1+xNi.sub..alpha.Co.sub..beta.Mn.sub..gamma.M'.sub..delta.O.sub.yF- .sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti), where the x is between 0 and 0.2, the .alpha. between 0 and 1, the .beta. between 0 and 1, the .gamma. between 0 and 2, the .delta. between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.

  2. Energy Systems Based on Polyacetylene: Rechargeable Batteries and Schottky Barrier Solar Cells. Final Report, March 1, 1981-February 29, 1984

    DOE R&D Accomplishments [OSTI]

    MacDiarmid, A. G.

    1984-02-01

    The chief thrust of the research has been directed towards the evaluation of polyacetylene (CH){sub x}, the prototype conducting polymer as an electrode- active material in novel, rechargeable batteries employing nonaqueous electrolytes. The p-doped material, [(CH{sup +y})A{sub y}{sup -}]{sub x}, (where A{sup -} is an anion) in conjunction with a Li anode, shows excellent discharge characteristics, e.g., very little change in discharge voltage with change in discharge current and a high power density. Its energy density is also good but it shows poor shelf life. When (CH){sub x} is used as a cathode (Li anode), which results in the formation of the n-doped polymer, [Li{sub y} {sup +}(CH/sup -y/)]{sub x}, during discharge, good discharge plateaus and power densities are obtained together with excellent shelf life and good recyclability. The energy density is, however only moderate. Cells employing an [M{sub y}{sup +}(CH/sup -y/)]{sub x} (where M = Li, Na) anode and a TiS{sub 2} cathode show very good discharge and recycling characteristics but their energy density is poor.

  3. Characterization of Cathode Materials for Rechargeable Lithium Batteries using Synchrotron Based In Situ X-ray Techniques

    SciTech Connect (OSTI)

    Yang, Xiao-Qing

    2007-05-23

    The emergence of portable telecommunication, computer equipment and ultimately hybrid electric vehicles has created a substantial interest in manufacturing rechargeable batteries that are less expensive, non-toxic, operate for longer time, small in size and weigh less. Li-ion batteries are taking an increasing share of the rechargeable battery market. The present commercial battery is based on a layered LiCoO{sub 2} cathode and a graphitized carbon anode. LiCoO{sub 2} is expensive but it has the advantage being easily manufactured in a reproducible manner. Other low cost layered compounds such as LiNiO{sub 2}, LiNi{sub 0.85}Co{sub 0.15}O{sub 2} or cubic spinels such as LiMn{sub 2}O{sub 4} have been considered. However, these suffer from cycle life and thermal stability problems. Recently, some battery companies have demonstrated a new concept of mixing two different types of insertion compounds to make a composite cathode, aimed at reducing cost and improving self-discharge. Reports clearly showed that this blending technique can prevent the decline in ·capacity caused by cycling or storage at elevated temperatures. However, not much work has been reported on the charge-discharge characteristics and phase transitions for these composite cathodes. Understanding the structure and structural changes of electrode materials during the electrochemical cycling is the key to develop better .lithium ion batteries. The successful commercialization of the· lithium-ion battery is mainly built on the advances in solid state chemistry of the intercalation compounds. Most of the progress in understanding the lithium ion battery materials has been obtained from x-ray diffraction studies. Up to now, most XRD studies on lithium-ion battery materials have been done ex situ. Although these ex situ XRD studies have provided important information· about the structures of battery materials, they do face three major problems. First of all, the pre-selected charge (discharge) states may

  4. Electron beam generation in Tevatron electron lenses

    SciTech Connect (OSTI)

    Kamerdzhiev, V.; Kuznetsov, G.; Shiltsev, V.; Solyak, N.; Tiunov, M.; /Novosibirsk, IYF

    2006-08-01

    New type of high perveance electron guns with convex cathode has been developed. Three guns described in this article are built to provide transverse electron current density distributions needed for Electron Lenses for beam-beam compensation in the Tevatron collider. The current distribution can be controlled either by the gun geometry or by voltage on a special control electrode located near cathode. We present the designs of the guns and report results of beam measurements on the test bench. Because of their high current density and low transverse temperature of electrons, electron guns of this type can be used in electron cooling and beam-beam compensation devices.

  5. Optically pulsed electron accelerator

    DOE Patents [OSTI]

    Fraser, J.S.; Sheffield, R.L.

    1985-05-20

    An optically pulsed electron accelerator can be used as an injector for a free electron laser and comprises a pulsed light source, such as a laser, for providing discrete incident light pulses. A photoemissive electron source emits electron bursts having the same duration as the incident light pulses when impinged upon by same. The photoemissive electron source is located on an inside wall of a radiofrequency-powered accelerator cell which accelerates the electron burst emitted by the photoemissive electron source.

  6. Optically pulsed electron accelerator

    DOE Patents [OSTI]

    Fraser, John S.; Sheffield, Richard L.

    1987-01-01

    An optically pulsed electron accelerator can be used as an injector for a free electron laser and comprises a pulsed light source, such as a laser, for providing discrete incident light pulses. A photoemissive electron source emits electron bursts having the same duration as the incident light pulses when impinged upon by same. The photoemissive electron source is located on an inside wall of a radio frequency powered accelerator cell which accelerates the electron burst emitted by the photoemissive electron source.

  7. Tips: Home Office and Electronics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    chargers when the batteries are fully charged or the chargers are not in use. Use rechargeable batteries for products like cordless phones and digital cameras. Studies have shown...

  8. Integrated Dynamic Electron Solutions, Inc. | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    method for building tiny chemical structures to greatly improve the performance of lithium-ion batteries. Lithium-ion batteries are rechargeable batteries that are widely used...

  9. A Community of Electrons

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plutonium's missing magnetism also provides a groundbreaking insight into the overall nature of matter. November 20, 2015 A Community of Electrons With electronic correlations,...

  10. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in...

  11. Electron Microscopy Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Microscopy Center Argonne Home > EMC > EMC Home Electron Microscopy Center Web Site has moved This page has moved to http:www.anl.govcnmgroupelectron-microscopy-cente...

  12. Electronic Transitions in f-electron Metals at High Pressures...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Electronic Transitions in f-electron Metals at High Pressures: Citation Details In-Document Search Title: Electronic Transitions in f-electron Metals at High ...

  13. RHIC electron lenses upgrades

    SciTech Connect (OSTI)

    Gu, X.; Altinbas, Z.; Bruno, D.; Binello, S.; Costanzo, M.; Drees, A.; Fischer, W.; Gassner, D. M.; Hock, J.; Hock, K.; Harvey, M.; Luo, Y.; Marusic, A.; Mi, C.; Mernick, K.; Minty, M.; Michnoff, R.; Miller, T. A.; Pikin, A. I.; Robert-Demolaize, G.; Samms, T.; Shrey, T. C.; Schoefer, V.; Tan, Y.; Than, R.; Thieberger, P.; White, S. M.

    2015-05-03

    In the Relativistic Heavy Ion Collider (RHIC) 100 GeV polarized proton run in 2015, two electron lenses were used to partially compensate for the head-on beam-beam effect for the first time. Here, we describe the design of the current electron lens, detailing the hardware modifications made after the 2014 commissioning run with heavy ions. A new electron gun with 15-mm diameter cathode is characterized. The electron beam transverse profile was measured using a YAG screen and fitted with a Gaussian distribution. During operation, the overlap of the electron and proton beams was achieved using the electron backscattering detector in conjunction with an automated orbit control program.

  14. Catalac free electron laser

    DOE Patents [OSTI]

    Brau, Charles A. (Los Alamos, NM); Swenson, Donald A. (Los Alamos, NM); Boyd, Jr., Thomas J. (Los Alamos, NM)

    1982-01-01

    A catalac free electron laser using a rf linac (catalac) which acts as a catalyst to accelerate an electron beam in an initial pass through the catalac and decelerate the electron beam during a second pass through the catalac. During the second pass through the catalac, energy is extracted from the electron beam and transformed to energy of the accelerating fields of the catalac to increase efficiency of the device. Various embodiments disclose the use of post linacs to add electron beam energy extracted by the wiggler and the use of supplementary catalacs to extract energy at various energy peaks produced by the free electron laser wiggler to further enhance efficiency of the catalac free electron laser. The catalac free electron laser can be used in conjunction with a simple resonator, a ring resonator or as an amplifier in conjunction with a master oscillator laser.

  15. Relativistic electron beam generator

    DOE Patents [OSTI]

    Mooney, L.J.; Hyatt, H.M.

    1975-11-11

    A relativistic electron beam generator for laser media excitation is described. The device employs a diode type relativistic electron beam source having a cathode shape which provides a rectangular output beam with uniform current density.

  16. Catalac free electron laser

    DOE Patents [OSTI]

    Brau, C.A.; Swenson, D.A.; Boyd, T.J. Jr.

    1979-12-12

    A catalac free electron laser using a rf linac (catalac) which acts as a catalyst to accelerate an electron beam in an initial pass through the catalac and decelerate the electron beam during a second pass through the catalac is described. During the second pass through the catalac, energy is extracted from the electron beam and transformed to energy of the accelerating fields of the catalac to increase efficiency of the device. Various embodiments disclose the use of post linacs to add electron beam energy extracted by the wiggler and the use of supplementary catalacs to extract energy at various energy peaks produced by the free electron laser wiggler to further enhance efficiency of the catalac free electron laser. The catalac free electron laser can be used in conjunction with a simple resonator, a ring resonator, or as an amplifier in conjunction with a master oscillator laser.

  17. Power Electronics Block Set

    Energy Science and Technology Software Center (OSTI)

    2008-12-31

    The software consists of code that will allow rapid prototyping of advanced power electronics for use in renewable energy systems.

  18. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in ultrafast electronic transistors. It exhibits high conductivity and an anomalous quantum Hall effect (a phenomenon exhibited by certain semiconductor devices at low temperatures and high magnetic fields). Among its novel properties, graphene's electrical charge carriers (electrons and holes) move through a solid with

  19. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in ultrafast electronic transistors. It exhibits high conductivity and an anomalous quantum Hall effect (a phenomenon exhibited by certain semiconductor devices at low temperatures and high magnetic fields). Among its novel properties, graphene's electrical charge carriers (electrons and holes) move through a solid with

  20. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in ultrafast electronic transistors. It exhibits high conductivity and an anomalous quantum Hall effect (a phenomenon exhibited by certain semiconductor devices at low temperatures and high magnetic fields). Among its novel properties, graphene's electrical charge carriers (electrons and holes) move through a solid with

  1. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in ultrafast electronic transistors. It exhibits high conductivity and an anomalous quantum Hall effect (a phenomenon exhibited by certain semiconductor devices at low temperatures and high magnetic fields). Among its novel properties, graphene's electrical charge carriers (electrons and holes) move through a solid with

  2. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in ultrafast electronic transistors. It exhibits high conductivity and an anomalous quantum Hall effect (a phenomenon exhibited by certain semiconductor devices at low temperatures and high magnetic fields). Among its novel properties, graphene's electrical charge carriers (electrons and holes) move through a solid with

  3. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in ultrafast electronic transistors. It exhibits high conductivity and an anomalous quantum Hall effect (a phenomenon exhibited by certain semiconductor devices at low temperatures and high magnetic fields). Among its novel properties, graphene's electrical charge carriers (electrons and holes) move through a solid with

  4. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Controlling Graphene's Electronic Structure Print Wednesday, 25 April 2007 00:00 Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has enormous potential for use in ultrafast electronic transistors. It exhibits high conductivity and an anomalous quantum Hall effect (a phenomenon exhibited by certain semiconductor devices at low temperatures and high magnetic fields). Among its novel properties, graphene's

  5. Electronics Stewardship | Department of Energy

    Office of Environmental Management (EM)

    Electronics Stewardship Electronics Stewardship Mission The team promotes sustainable management of LM's electronic equipment, as deemed appropriate for LM operations and approved ...

  6. Electron emitting filaments for electron discharge devices

    DOE Patents [OSTI]

    Leung, K.N.; Pincosy, P.A.; Ehlers, K.W.

    1983-06-10

    Electrons are copiously emitted by a device comprising a loop-shaped filament made of lanthanum hexaboride. The filament is directly heated by an electrical current produced along the filament by a power supply connected to the terminal legs of the filament. To produce a filament, a diamond saw or the like is used to cut a slice from a bar made of lanthanum hexaboride. The diamond saw is then used to cut the slice into the shape of a loop which may be generally rectangular, U-shaped, hairpin-shaped, zigzag-shaped, or generally circular. The filaments provide high electron emission at a relatively low operating temperature, such as 1600/sup 0/C. To achieve uniform heating, the filament is formed with a cross section which is tapered between the opposite ends of the filament to compensate for nonuniform current distribution along the filament due to the emission of electrons from the filament.

  7. Electron emitting filaments for electron discharge devices

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Pincosy, Philip A.; Ehlers, Kenneth W.

    1988-01-01

    Electrons are copiously emitted by a device comprising a loop-shaped filament made of lanthanum hexaboride. The filament is directly heated by an electrical current produced along the filament by a power supply connected to the terminal legs of the filament. To produce a filament, a diamond saw or the like is used to cut a slice from a bar made of lanthanum hexaboride. The diamond saw is then used to cut the slice into the shape of a loop which may be generally rectangular, U-shaped, hairpin-shaped, zigzag-shaped, or generally circular. The filaments provide high electron emission at a relatively low operating temperature, such as 1600.degree. C. To achieve uniform heating, the filament is formed with a cross section which is tapered between the opposite ends of the filament to compensate for non-uniform current distribution along the filament due to the emission of electrons from the filament.

  8. Ceramic Electron Multiplier

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Comby, G.

    1996-10-01

    The Ceramic Electron Multipliers (CEM) is a compact, robust, linear and fast multi-channel electron multiplier. The Multi Layer Ceramic Technique (MLCT) allows to build metallic dynodes inside a compact ceramic block. The activation of the metallic dynodes enhances their secondary electron emission (SEE). The CEM can be used in multi-channel photomultipliers, multi-channel light intensifiers, ion detection, spectroscopy, analysis of time of flight events, particle detection or Cherenkov imaging detectors. (auth)

  9. Electronic Recordkeeping System Questionnaire

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 (04/2015) U.S. DEPARTMENT OF ENERGY Electronic Recordkeeping System Questionnaire INSTRUCTIONS: System owners should work in consultation with their organization's records contacts to ensure the accurate completion of a separate questionnaire for each electronic recordkeeping system. Federal regulations require proper address of recordkeeping requirements and disposition before approving new electronic information systems (EIS) or enhancements to existing EISes. OMB Circular A-130 requires

  10. Field emission electron source

    DOE Patents [OSTI]

    Zettl, Alexander Karlwalter; Cohen, Marvin Lou

    2000-01-01

    A novel field emitter material, field emission electron source, and commercially feasible fabrication method is described. The inventive field emission electron source produces reliable electron currents of up to 400 mA/cm.sup.2 at 200 volts. The emitter is robust and the current it produces is not sensitive to variability of vacuum or the distance between the emitter tip and the cathode. The novel emitter has a sharp turn-on near 100 volts.

  11. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spectroscopy (ARPES) at ALS Beamline 7.0.1, a team of scientists from the ALS and Germany characterized the electronic band structure and successfully controlled the gap...

  12. Electronic Mail Analysis Capability

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-01-08

    Establishes the pilot program to test the Department of Energy (DOE) Electronic Mail Analysis Capability (EMAC), which will be used to monitor and analyze outgoing and incoming electronic mail (e-mail) from the National Nuclear Security Administration (NNSA) and DOE laboratories that are engaged in nuclear weapons design or work involving special nuclear material. No cancellation.

  13. High brightness electron accelerator

    DOE Patents [OSTI]

    Sheffield, Richard L.; Carlsten, Bruce E.; Young, Lloyd M.

    1994-01-01

    A compact high brightness linear accelerator is provided for use, e.g., in a free electron laser. The accelerator has a first plurality of acclerating cavities having end walls with four coupling slots for accelerating electrons to high velocities in the absence of quadrupole fields. A second plurality of cavities receives the high velocity electrons for further acceleration, where each of the second cavities has end walls with two coupling slots for acceleration in the absence of dipole fields. The accelerator also includes a first cavity with an extended length to provide for phase matching the electron beam along the accelerating cavities. A solenoid is provided about the photocathode that emits the electons, where the solenoid is configured to provide a substantially uniform magnetic field over the photocathode surface to minimize emittance of the electons as the electrons enter the first cavity.

  14. Electron: Cluster interactions

    SciTech Connect (OSTI)

    Scheidemann, A.A.; Kresin, V.V.; Knight, W.D.

    1994-02-01

    Beam depletion spectroscopy has been used to measure absolute total inelastic electron-sodium cluster collision cross sections in the energy range from E {approximately} 0.1 to E {approximately} 6 eV. The investigation focused on the closed shell clusters Na{sub 8}, Na{sub 20}, Na{sub 40}. The measured cross sections show an increase for the lowest collision energies where electron attachment is the primary scattering channel. The electron attachment cross section can be understood in terms of Langevin scattering, connecting this measurement with the polarizability of the cluster. For energies above the dissociation energy the measured electron-cluster cross section is energy independent, thus defining an electron-cluster interaction range. This interaction range increases with the cluster size.

  15. Electrons and Mirror Symmetry

    ScienceCinema (OSTI)

    Kumar, Krishna

    2009-09-01

    The neutral weak force between an electron and a target particle, mediated by the Z boson, can be isolated by measuring the fractional change under a mirror reflection of the scattering probability of relativistic longitudinally polarized electrons off unpolarized targets. This technique yields neutral weak force measurements at a length scale of 1 femtometer, in contrast to high energy collider measurements that probe much smaller length scales. Study of the variation of the weak force over a range of length scales provides a stringent test of theory, complementing collider measurements. We describe a recent measurement of the neutral weak force between two electrons by the E158 experiment at the Stanford Linear Accelerator Center. While the weak force between an electron and positron has been extensively studied, that between two electrons had never directly been measured. We conclude by discussing prospects for even more precise measurements at future facilities.

  16. Electrons and Mirror Symmetry

    SciTech Connect (OSTI)

    Kumar, Krishna

    2007-04-04

    The neutral weak force between an electron and a target particle, mediated by the Z boson, can be isolated by measuring the fractional change under a mirror reflection of the scattering probability of relativistic longitudinally polarized electrons off unpolarized targets. This technique yields neutral weak force measurements at a length scale of 1 femtometer, in contrast to high energy collider measurements that probe much smaller length scales. Study of the variation of the weak force over a range of length scales provides a stringent test of theory, complementing collider measurements. We describe a recent measurement of the neutral weak force between two electrons by the E158 experiment at the Stanford Linear Accelerator Center. While the weak force between an electron and positron has been extensively studied, that between two electrons had never directly been measured. We conclude by discussing prospects for even more precise measurements at future facilities.

  17. Simulations of Gaussian electron guns for RHIC electron lens

    SciTech Connect (OSTI)

    Pikin, A.

    2014-02-28

    Simulations of two versions of the electron gun for RHIC electron lens are presented. The electron guns have to generate an electron beam with Gaussian radial profile of the electron beam density. To achieve the Gaussian electron emission profile on the cathode we used a combination of the gun electrodes and shaping of the cathode surface. Dependence of electron gun performance parameters on the geometry of electrodes and the margins for electrodes positioning are presented.

  18. Aerogels for electronics

    SciTech Connect (OSTI)

    Hrubesh, L.W.

    1994-10-01

    In addition to their other exceptional properties, aerogels also exhibit unusual dielectric and electronic properties due to their nano-sized structures and high porosities. For example, aerogels have the lowest dielectric constants measured for a solid material (having values approaching 1.0); they have exceptionally high dielectric resistivities and strengths (i.e., ability to insulate very high voltages); they exhibit low dielectric loss at microwave frequencies; and some aerogels are electrically conductive and photoconductive. These properties are being exploited to provide the next generation of materials for energy storage, low power consumption, and ultra-fast electronics. We are working toward adapting these unusual materials for microelectronic applications, particularly, making thin aerogel films for dielectric substrates and for energy storage devices such as supercapacitors. Measurements are presented in this paper for the dielectric and electronic properties of aerogels, including the dielectric constant, loss factor, dielectric and electrical conductivity, volume resistivity, and dielectric strength. We also describe methods to form and characterize thin aerogel films which are being developed for numerous electronic applications. Finally, some of the electronic applications proposed for aerogels are presented. Commercialization of aerogels for electronics must await further feasibility, prototype development, and cost studies, but they are one of the key materials and are sure to have a major impact on future electronics.

  19. Coherent electron cooling

    SciTech Connect (OSTI)

    Litvinenko,V.

    2009-05-04

    Cooling intense high-energy hadron beams remains a major challenge in modern accelerator physics. Synchrotron radiation is still too feeble, while the efficiency of two other cooling methods, stochastic and electron, falls rapidly either at high bunch intensities (i.e. stochastic of protons) or at high energies (e-cooling). In this talk a specific scheme of a unique cooling technique, Coherent Electron Cooling, will be discussed. The idea of coherent electron cooling using electron beam instabilities was suggested by Derbenev in the early 1980s, but the scheme presented in this talk, with cooling times under an hour for 7 TeV protons in the LHC, would be possible only with present-day accelerator technology. This talk will discuss the principles and the main limitations of the Coherent Electron Cooling process. The talk will describe the main system components, based on a high-gain free electron laser driven by an energy recovery linac, and will present some numerical examples for ions and protons in RHIC and the LHC and for electron-hadron options for these colliders. BNL plans a demonstration of the idea in the near future.

  20. Wide Bandgap Power Electronics

    Office of Environmental Management (EM)

    ... coal power plant. 463 In addition to power savings, an important benefit of using high frequency GaN electronics is that the 464 adapter size can be reduced by 10x. Consumers ...

  1. Electron Microscope Facility

    ScienceCinema (OSTI)

    None

    2010-01-08

    Brookhaven Lab is home to one of only a few Scanning Transmision Electron Microscope (STEM) machines in the world and one of the few that can image single heavy atoms.

  2. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    momentum because the electrons are restricted to motion in a two-dimensional plane. The Dirac crossing points are at energy ED. 2D Perfection in a 3D World Graphene, a perfect...

  3. Electron Heat Transport Measured

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heat Transport Measured in a Stochastic Magnetic Field T. M. Biewer, * C. B. Forest, ... limit of s &29; 1, RR assumed the electron heat flux to be diffusive, obeying Fourier's ...

  4. 2014-05-14 Issuance: Energy Conservation Standards for Residential Dehumidifiers; Availability of the Preliminary TSD

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register notice of public meeting and availability of the preliminary technical support document, as issued by the Deputy Assistant Secretary for Energy Efficiency on May 14, 2014. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document.

  5. Free electron laser

    DOE Patents [OSTI]

    Villa, Francesco

    1990-01-01

    A high gain, single-pass free electron laser formed of a high brilliance electron injector source, a linear accelerator which imparts high energy to the electron beam, and an undulator capable of extremely high magnetic fields, yet with a very short period. The electron injector source is the first stage (gap) of the linear accelerator or a radial line transformer driven by fast circular switch. The linear accelerator is formed of a plurality of accelerating gaps arranged in series. These gaps are energized in sequence by releasing a single pulse of energy which propagates simultaneously along a plurality of transmission lines, each of which feeds the gaps. The transmission lines are graduated in length so that pulse power is present at each gap as the accelerated electrons pass therethrough. The transmission lines for each gap are open circuited at their ends. The undualtor has a structure similar to the accelerator, except that the transmission lines for each gap are substantially short circuited at their ends, thus converting the electric field into magnetic field. A small amount of resistance is retained in order to generate a small electric field for replenishing the electron bunch with the energy lost as it traverses through the undulator structure.

  6. Electronics Stewardship | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electronics Stewardship Electronics Stewardship DOE is committed to responsible environmental stewardship of its electronics, including computers, displays, printers and cell phones. In order to comply with Executive Order 13693, Planning for Federal Sustainability in the Next Decade, and other statutory requirements, DOE policy and actions support the following principles of electronic stewardship: procuring environmentally sustainable electronics, including EPEAT-registered, ENERGY STAR

  7. Few Electron Quantum Dot coupling to Donor Implanted Electron...

    Office of Scientific and Technical Information (OSTI)

    Title: Few Electron Quantum Dot coupling to Donor Implanted Electron Spins. Abstract not provided. Authors: Rudolph, Martin ; Patrick Harvey-Collard ; Nielsen, Erik ; Gamble, John ...

  8. Energy Storage & Power Electronics 2008 Peer Review - Power Electronic...

    Office of Environmental Management (EM)

    Power Electronics (PE) Systems Presentations Energy Storage & Power Electronics 2008 Peer ... Compact SiC-Based Power Converter System - Timothy Lin, Aegis.pdf (370.13 KB) ...

  9. A battery-operated, stabilized, high-energy pulsed electron gun for the production of rare gas excimers

    SciTech Connect (OSTI)

    Barcellan, L.; Carugno, G.; Berto, E.; Galet, G.; Galeazzi, G.; Borghesani, A. F.

    2011-09-15

    We report on the design of a new type of hot-filament electron gun delivering fairly high current (a few hundreds of {mu} A) at high voltage (up to 100 kV) in continuous or pulsed mode. Its novel features are that the filament is heated by means of a pack of rechargeable batteries floated atop the high-voltage power supply in order to get rid of bulky isolation transformers, and that the filament current and, hence, the electron gun current, is controlled by a feedback circuit including a superluminescent diode decoupled from the high voltage by means of an optical fiber. This electron gun is intended for general purposes, although we have especially developed it to meet the needs of our experiment on the infrared emission spectroscopy of rare gas excimers. Our experiment requires that the charge injection into the sample is pulsed and constant and stable in time. The new electron gun can deliver several tens of nC per pulse of electrons of energy up to 100 keV into the sample cell. The new design also eliminates ripples in the emission current and ensures up to 12 h of stable performance.

  10. Cooling system for electronic components

    DOE Patents [OSTI]

    Anderl, William James; Colgan, Evan George; Gerken, James Dorance; Marroquin, Christopher Michael; Tian, Shurong

    2015-12-15

    Embodiments of the present invention provide for non interruptive fluid cooling of an electronic enclosure. One or more electronic component packages may be removable from a circuit card having a fluid flow system. When installed, the electronic component packages are coincident to and in a thermal relationship with the fluid flow system. If a particular electronic component package becomes non-functional, it may be removed from the electronic enclosure without affecting either the fluid flow system or other neighboring electronic component packages.

  11. Electron microscope phase enhancement

    DOE Patents [OSTI]

    Jin, Jian; Glaeser, Robert M.

    2010-06-15

    A microfabricated electron phase shift element is used for modifying the phase characteristics of an electron beam passing though its center aperture, while not affecting the more divergent portion of an incident beam to selectively provide a ninety-degree phase shift to the unscattered beam in the back focal plan of the objective lens, in order to realize Zernike-type, in-focus phase contrast in an electron microscope. One application of the element is to increase the contrast of an electron microscope for viewing weakly scattering samples while in focus. Typical weakly scattering samples include biological samples such as macromolecules, or perhaps cells. Preliminary experimental images demonstrate that these devices do apply a ninety degree phase shift as expected. Electrostatic calculations have been used to determine that fringing fields in the region of the scattered electron beams will cause a negligible phase shift as long as the ratio of electrode length to the transverse feature-size aperture is about 5:1. Calculations are underway to determine the feasibility of aspect smaller aspect ratios of about 3:1 and about 2:1.

  12. Tim Kuneli, Electronics Maintenance Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tim Kuneli, Electronics Maintenance Group Print The recent ALS power supply failure was one of the most challenging projects that Electronics Engineer Technical Superintendent Tim...

  13. Manasa Electronics | Open Energy Information

    Open Energy Info (EERE)

    Manasa Electronics Jump to: navigation, search Name: Manasa Electronics Place: Ghaziabad, Uttar Pradesh, India Zip: 201 005 Sector: Solar Product: Ghaziabad-based manufacturer of...

  14. Electron Trapping by Molecular Vibration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Trapping by Molecular Vibration Print In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally...

  15. Circular free-electron laser

    DOE Patents [OSTI]

    Brau, Charles A.; Kurnit, Norman A.; Cooper, Richard K.

    1984-01-01

    A high efficiency, free electron laser utilizing a circular relativistic electron beam accelerator and a circular whispering mode optical waveguide for guiding optical energy in a circular path in the circular relativistic electron beam accelerator such that the circular relativistic electron beam and the optical energy are spatially contiguous in a resonant condition for free electron laser operation. Both a betatron and synchrotron are disclosed for use in the present invention. A free electron laser wiggler is disposed around the circular relativistic electron beam accelerator for generating a periodic magnetic field to transform energy from the circular relativistic electron beam to optical energy.

  16. Tokyo Electron | Open Energy Information

    Open Energy Info (EERE)

    Electron Jump to: navigation, search Name: Tokyo Electron Place: Tokyo, Tokyo, Japan Zip: 107-8481 Product: As a leading global supplier of semiconductor production equipment,...

  17. The Future of Electron Microscopy

    SciTech Connect (OSTI)

    Zheng, Haimei

    2015-05-06

    Berkeley Lab scientist Haimei Zheng discusses the future of electron microscopy and her breakthrough research into examining liquids using an electron microscope.

  18. Electron launching voltage monitor

    DOE Patents [OSTI]

    Mendel, C.W.; Savage, M.E.

    1992-03-17

    An electron launching voltage monitor measures MITL voltage using a relationship between anode electric field and electron current launched from a cathode-mounted perturbation. An electron launching probe extends through and is spaced from the edge of an opening in a first MITL conductor, one end of the launching probe being in the gap between the MITL conductor, the other end being adjacent a first side of the first conductor away from the second conductor. A housing surrounds the launching probe and electrically connects the first side of the first conductor to the other end of the launching probe. A detector detects the current passing through the housing to the launching probe, the detected current being representative of the voltage between the conductors. 5 figs.

  19. Foil Electron Multiplier

    DOE Patents [OSTI]

    Funsten, Herbert O.; Baldonado, Juan R.; Dors, Eric E.; Harper, Ronnie W.; Skoug, Ruth M.

    2006-03-28

    An apparatus for electron multiplication by transmission that is designed with at least one foil having a front side for receiving incident particles and a back side for transmitting secondary electrons that are produced from the incident particles transiting through the foil. The foil thickness enables the incident particles to travel through the foil and continue on to an anode or to a next foil in series with the first foil. The foil, or foils, and anode are contained within a supporting structure that is attached within an evacuated enclosure. An electrical power supply is connected to the foil, or foils, and the anode to provide an electrical field gradient effective to accelerate negatively charged incident particles and the generated secondary electrons through the foil, or foils, to the anode for collection.

  20. ELECTRON EMISSION REGULATING MEANS

    DOE Patents [OSTI]

    Brenholdt, I.R.

    1957-11-19

    >An electronic regulating system is described for controlling the electron emission of a cathode, for example, the cathode in a mass spectrometer. The system incorporates a transformer having a first secondary winding for the above-mentioned cathode and a second secondary winding for the above-mentioned cathode and a second secondary winding load by grid controlled vacuum tubes. A portion of the electron current emitted by the cathode is passed through a network which develops a feedback signal. The system arrangement is completed by using the feedback signal to control the vacuum tubes in the second secondary winding through a regulator tube. When a change in cathode emission occurs, the feedback signal acts to correct this change by adjusting the load on the transformer.

  1. Electron launching voltage monitor

    DOE Patents [OSTI]

    Mendel, Clifford W.; Savage, Mark E.

    1992-01-01

    An electron launching voltage monitor measures MITL voltage using a relationship between anode electric field and electron current launched from a cathode-mounted perturbation. An electron launching probe extends through and is spaced from the edge of an opening in a first MITL conductor, one end of the launching probe being in the gap between the MITL conductor, the other end being adjacent a first side of the first conductor away from the second conductor. A housing surrounds the launching probe and electrically connects the first side of the first conductor to the other end of the launching probe. A detector detects the current passing through the housing to the launching probe, the detected current being representative of the voltage between the conductors.

  2. Precision electron polarimetry

    SciTech Connect (OSTI)

    Chudakov, Eugene A.

    2013-11-01

    A new generation of precise Parity-Violating experiments will require a sub-percent accuracy of electron beam polarimetry. Compton polarimetry can provide such accuracy at high energies, but at a few hundred MeV the small analyzing power limits the sensitivity. M{\\o}ller polarimetry provides a high analyzing power independent on the beam energy, but is limited by the properties of the polarized targets commonly used. Options for precision polarimetry at ~300 MeV will be discussed, in particular a proposal to use ultra-cold atomic hydrogen traps to provide a 100\\%-polarized electron target for M{\\o}ller polarimetry.

  3. Electronic Recordkeeping System Questionnaire

    Energy Savers [EERE]

    Electronic Docket Room (e-Docket Room) Electronic Docket Room (e-Docket Room) E-Docket -- Browse Searchable Database of Current and Historical Applications Submitted to DOE (click SHOW for drop down menu) Authorizations/Orders Granted by the Department -- NOTE: 1977 thru 2016 will take you to an external link. 1977 1978 1979 1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013

  4. Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer

    Office of Scientific and Technical Information (OSTI)

    on Nanocrystalline Thin Films and Single Crystal (Technical Report) | SciTech Connect Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer on Nanocrystalline Thin Films and Single Crystal Citation Details In-Document Search Title: Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer on Nanocrystalline Thin Films and Single Crystal The long-term goal of the proposed research is to understand electron transfer dynamics in nanoparticle/liquid interface.

  5. Electron correlation effects on the magnetostructural transition...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 75 CONDENSED MATTER ... ELECTRON CORRELATION; ELECTRONIC STRUCTURE; ELECTRONS; ENTROPY; EXCHANGE ...

  6. Electron beam cutting

    DOE Patents [OSTI]

    Mochel, M.E.; Humphreys, C.J.

    1985-04-02

    A method for the cutting of holes 20 Angstroms in diameter, or lines 20 Angstroms wide in a material having positive ionic conduction by the use of a focused electron probe is described. The holes and lines are stable under ambient conditions. 2 figs.

  7. ELECTRONIC DIGITAL COMPUTER

    DOE Patents [OSTI]

    Stone, J.J. Jr.; Bettis, E.S.; Mann, E.R.

    1957-10-01

    The electronic digital computer is designed to solve systems involving a plurality of simultaneous linear equations. The computer can solve a system which converges rather rapidly when using Von Seidel's method of approximation and performs the summations required for solving for the unknown terms by a method of successive approximations.

  8. MEIC electron cooling program

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Derbenev, Yaroslav S.; Zhang, Yuhong

    2014-12-01

    Cooling of proton and ion beams is essential for achieving high luminosities (up to above 1034 cm-2s-1) for MEIC, a Medium energy Electron-Ion Collider envisioned at JLab [1] for advanced nuclear science research. In the present conceptual design, we utilize the conventional election cooling method and adopted a multi-staged cooling scheme for reduction of and maintaining low beam emittances [2,3,4]. Two electron cooling facilities are required to support the scheme: one is a low energy (up to 2 MeV) DC cooler installed in the MEIC ion pre-booster (with the proton kinetic energy up to 3 GeV); the other is amore » high electron energy (up to 55 MeV) cooler in the collider ring (with the proton kinetic energy from 25 to 100 GeV). The high energy cooler, which is based on the ERL technology and a circulator ring, utilizes a bunched electron beam to cool bunched proton or ion beams. To complete the MEIC cooling concept and a technical design of the ERL cooler as well as to develop supporting technologies, an R&D program has been initiated at Jefferson Lab and significant progresses have been made since then. In this study, we present a brief description of the cooler design and a summary of the progress in this cooling R&D.« less

  9. Electron beam cutting

    DOE Patents [OSTI]

    Mochel, Margaret E.; Humphreys, Colin J.

    1985-04-02

    A method for the cutting of holes 20 Angstroms in diameter, or lines 20 Angstroms wide in a material having positive ionic conduction by the use of a focused electron probe is described. The holes and lines are stable under ambient conditions.

  10. Diamondoid monolayers as electron emitters

    DOE Patents [OSTI]

    Yang, Wanli; Fabbri, Jason D.; Melosh, Nicholas A.; Hussain, Zahid; Shen, Zhi-Xun

    2012-04-10

    Provided are electron emitters based upon diamondoid monolayers, preferably self-assembled higher diamondoid monolayers. High intensity electron emission has been demonstrated employing such diamondoid monolayers, particularly when the monolayers are comprised of higher diamondoids. The application of such diamondoid monolayers can alter the band structure of substrates, as well as emit monochromatic electrons, and the high intensity electron emissions can also greatly improve the efficiency of field-effect electron emitters as applied to industrial and commercial applications.