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Sample records for readiness requires radical

  1. Ghana-REDD Readiness Requires Radical Reform | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages RecentPlant <Silver Peak AreaForestREDD Readiness

  2. DOE Zero Energy Ready Home National Program Requirements (Rev...

    Broader source: Energy.gov (indexed) [DOE]

    4) DOE Zero Energy Ready Home National Program Requirements Rev04.pdf More Documents & Publications DOE Zero Energy Ready Home National Program Requirements (Rev. 05) California...

  3. DOE Zero Energy Ready Home National Program Requirements (Rev...

    Broader source: Energy.gov (indexed) [DOE]

    5), May, 11, 2015. DOE Zero Energy Ready Home National Program Requirements Rev05 - Final.pdf More Documents & Publications California DOE ZERH Program Requiremets DOE Zero Energy...

  4. DOE Zero Energy Ready Home Solar Hot Water-Ready Checklist

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zero Energy Ready Home Solar Hot Water-Ready Checklist (Encouraged) DOE Zero Energy Ready Home National Program encourages, but does not require, consideration of this checklist....

  5. A Qualitative Readiness-Requirements Assessment Model for Enterprise Big-Data Infrastructure Investment

    SciTech Connect (OSTI)

    Olama, Mohammed M [ORNL] [ORNL; McNair, Wade [ORNL] [ORNL; Sukumar, Sreenivas R [ORNL] [ORNL; Nutaro, James J [ORNL] [ORNL

    2014-01-01

    In the last three decades, there has been an exponential growth in the area of information technology providing the information processing needs of data-driven businesses in government, science, and private industry in the form of capturing, staging, integrating, conveying, analyzing, and transferring data that will help knowledge workers and decision makers make sound business decisions. Data integration across enterprise warehouses is one of the most challenging steps in the big data analytics strategy. Several levels of data integration have been identified across enterprise warehouses: data accessibility, common data platform, and consolidated data model. Each level of integration has its own set of complexities that requires a certain amount of time, budget, and resources to implement. Such levels of integration are designed to address the technical challenges inherent in consolidating the disparate data sources. In this paper, we present a methodology based on industry best practices to measure the readiness of an organization and its data sets against the different levels of data integration. We introduce a new Integration Level Model (ILM) tool, which is used for quantifying an organization and data system s readiness to share data at a certain level of data integration. It is based largely on the established and accepted framework provided in the Data Management Association (DAMA-DMBOK). It comprises several key data management functions and supporting activities, together with several environmental elements that describe and apply to each function. The proposed model scores the maturity of a system s data governance processes and provides a pragmatic methodology for evaluating integration risks. The higher the computed scores, the better managed the source data system and the greater the likelihood that the data system can be brought in at a higher level of integration.

  6. Emergency Readiness Assurance Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1992-02-27

    To establish the requirements of the Emergency Readiness Assurance Program with a goal of assurting that the Department of Energy (DOE) Emergency Management System (EMS) is ready to respond promptly, efficiently, and effectively to any emergency involving DOE facilities or requiring DOE assistance. Cancels DOE O 5500.10 dated 4-30-91. Chg 1 dated 2-27-92. Change 1 canceled by DOE O 151.1 of 9-25-95.

  7. Readiness Review Training- Member

    Office of Energy Efficiency and Renewable Energy (EERE)

    Slides used for November 10, 2010 Readiness Review Member Training at the Idaho National Laboratory. Course provides tools and tips to be an effective readiness review team member.

  8. Ready, set...go!

    SciTech Connect (OSTI)

    Alexandre, Melanie

    2010-06-16

    The objectives of this paper are: (1) Discuss organizational readiness for changes in an ergonomics program or intervention; (2) Assessing organizational readiness; (3) Benefits and challenges of change; and (4) Case studies of ergonomic programs that were 'not ready' and 'ready'.

  9. Writing Career Objectives Ready Reference E-5

    E-Print Network [OSTI]

    Writing Career Objectives Ready Reference E-5 College of Engineering, Architecture & Technology in pharmaceutical research" #12;Oklahoma State University College of Engineering, Architecture & Technology Career your practical skills. Examples: -"A position in a large, high tech organization requiring network

  10. Readiness Review RM

    Office of Environmental Management (EM)

    the progress of tasks needed to attain operational readiness, conducting practice drills and evolutions, maintaining and reviewing evidence files, reviewing corrective...

  11. Technology Readiness Assessment Guide

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2011-09-15

    The Guide assists individuals and teams involved in conducting Technology Readiness Assessments (TRAs) and developing Technology Maturation Plans (TMPs) for the DOE capital asset projects subject to DOE O 413.3B. Supersedes DOE G 413.3-4.

  12. Readiness Review Training- Team Leader

    Office of Energy Efficiency and Renewable Energy (EERE)

    Slides used for November 10, 2010 Readiness Review Team Leader Training at the Idaho National Laboratory. Course provides tools and tips to be an effective readiness review team leader.

  13. Smart Grid Ready PV Inverters with Utility Communication

    Office of Energy Efficiency and Renewable Energy (EERE)

    Electric Power Research Institute (EPRI) will develop, implement, and demonstrate smart-grid ready inverters with grid support functionality and required communication links to capture the full...

  14. Ready, set, go . . . well maybe

    SciTech Connect (OSTI)

    Alexandre, Melanie M; Bartolome, Terri-Lynn C

    2011-02-28

    The agenda for this presentation is: (1) understand organizational readiness for changes; (2) review benefits and challenges of change; (3) share case studies of ergonomic programs that were 'not ready' and some that were 'ready'; and (4) provide some ideas for facilitating change.

  15. Lightning Arrestor Connectors Production Readiness

    SciTech Connect (OSTI)

    Marten, Steve; Linder, Kim; Emmons, Jim; Gomez, Antonio; Hasam, Dawud; Maurer, Michelle

    2008-10-20

    The Lightning Arrestor Connector (LAC), part “M”, presented opportunities to improve the processes used to fabricate LACs. The A## LACs were the first production LACs produced at the KCP, after the product was transferred from Pinnellas. The new LAC relied on the lessons learned from the A## LACs; however, additional improvements were needed to meet the required budget, yield, and schedule requirements. Improvement projects completed since 2001 include Hermetic Connector Sealing Improvement, Contact Assembly molding Improvement, development of a second vendor for LAC shells, general process improvement, tooling improvement, reduction of the LAC production cycle time, and documention of the LAC granule fabrication process. This report summarizes the accomplishments achieved in improving the LAC Production Readiness.

  16. Ready, set, go . . . well maybe

    E-Print Network [OSTI]

    Alexandre, Melanie M

    2011-01-01

    at the 2011 Applied Ergonomics Conference By Melaniesustainable? Case study of ergonomics program that was ‘ notwas not! Case study of ergonomics program that was ‘ready

  17. ARM - Ingest Readiness Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments? WeDatastreamstps DocumentationAtlanticENAField ParticipantsFieldFormsIngest Readiness Form Ingest Ingest

  18. Richmond Electric Vehicle Initiative Electric Vehicle Readiness...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Richmond Electric Vehicle Initiative Electric Vehicle Readiness Plan Richmond Electric Vehicle Initiative Electric Vehicle Readiness Plan The REVi plan addresses the electric...

  19. NGNP Infrastructure Readiness Assessment: Consolidation Report

    SciTech Connect (OSTI)

    Brian K Castle

    2011-02-01

    The Next Generation Nuclear Plant (NGNP) project supports the development, demonstration, and deployment of high temperature gas-cooled reactors (HTGRs). The NGNP project is being reviewed by the Nuclear Energy Advisory Council (NEAC) to provide input to the DOE, who will make a recommendation to the Secretary of Energy, whether or not to continue with Phase 2 of the NGNP project. The NEAC review will be based on, in part, the infrastructure readiness assessment, which is an assessment of industry's current ability to provide specified components for the FOAK NGNP, meet quality assurance requirements, transport components, have the necessary workforce in place, and have the necessary construction capabilities. AREVA and Westinghouse were contracted to perform independent assessments of industry's capabilities because of their experience with nuclear supply chains, which is a result of their experiences with the EPR and AP-1000 reactors. Both vendors produced infrastructure readiness assessment reports that identified key components and categorized these components into three groups based on their ability to be deployed in the FOAK plant. The NGNP project has several programs that are developing key components and capabilities. For these components, the NGNP project have provided input to properly assess the infrastructure readiness for these components.

  20. CLAS12 Software Readiness Review Jerry Gilfoyle (for the CLAS12 Software Group)

    E-Print Network [OSTI]

    Gilfoyle, Jerry

    CLAS12 Software Readiness Review Jerry Gilfoyle (for the CLAS12 Software Group) Physics Department, University of Richmond, Virginia Outline: 1. Introduction 2. Software Framework 3. Management 4. Requirements by a factor of ten over CLAS6 (L = 1035 cm-2s-1). Software Goal: Ready to analyze data at turn on (October

  1. DOE Zero Energy Ready Home: Durable Energy Builders, Houston...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Zero Energy Ready Home: Durable Energy Builders, Houston, Texas DOE Zero Energy Ready Home: Durable Energy Builders, Houston, Texas This DOE Zero Energy Ready Home features...

  2. Verification of Readiness to Start Up or Restart Nuclear Facilities

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-04-16

    The order establishes requirements for verifying readiness for startup of new Hazard Category 1, 2, and 3 nuclear facilities, activities, and operations, and for restart of existing Hazard Category 1, 2, and 3 nuclear facilities, activities, and operations that have been shut down. Adm Chg 1, dated 4-2-13, supersedes DOE O 425.1D.

  3. Verification of Readiness to Start Up or Restart Nuclear Facilities

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-04-16

    The order establishes requirements for verifying readiness for startup of new Hazard Category 1, 2, and 3 nuclear facilities, activities, and operations, and for restart of existing Hazard Category 1, 2, and 3 nuclear facilities, activities, and operations that have been shut down. Cancels DOE O 425.1C. Adm Chg 1, dated 4-2-13.

  4. Early Childhood Education and School Readiness: Conceptual

    E-Print Network [OSTI]

    Rau, Don C.

    Early Childhood Education and School Readiness: Conceptual Models, Constructs, and Measures and Evaluation. #12;Early Childhood Education and School Readiness Workshop, June 17-18, 2002 TABLE OF CONTENTS .................................................................................................................................................13 Language and Early Literacy

  5. Zero Energy Ready Home | Department of Energy

    Office of Environmental Management (EM)

    Home Zero Energy Ready Home Look for the Label Look for the Label The DOE Zero Energy Ready Home label is a symbol of excellence. Learn what's behind this new level of performance....

  6. Weather Ready Nation: A Vital Conversation on

    E-Print Network [OSTI]

    Weather Ready Nation: A Vital Conversation on Tornadoes and Severe Weather A Community Report March;WeatherReady Nation: A Vital Conversation on Tornadoes and Severe Weather Report from the December 2011

  7. EM Performs Tenth Technology Readiness Assessment

    Broader source: Energy.gov [DOE]

    WASHINGTON, D.C. – EM recently completed its tenth Technology Readiness Assessment (TRA) since piloting the TRA process in 2006.

  8. Mission and Readiness Assessment for Fusion Nuclear Facilities

    SciTech Connect (OSTI)

    G.H. Neilson, et. al.

    2012-12-12

    Magnetic fusion development toward DEMO will most likely require a number of fusion nuclear facilities (FNF), intermediate between ITER and DEMO, to test and validate plasma and nuclear technologies and to advance the level of system integration. The FNF mission space is wide, ranging from basic materials research to net electricity demonstration, so there is correspondingly a choice among machine options, scope, and risk in planning such a step. Readiness requirements to proceed with a DEMO are examined, and two FNF options are assessed in terms of the contributions they would make to closing DEMO readiness gaps, and their readiness to themselves proceed with engineering design about ten years from now. An advanced tokamak (AT) pilot plant with superconducting coils and a mission to demonstrate net electricity generation would go a long way toward DEMO. As a next step, however, a pilot plant would entail greater risk than a copper-coil FNSF-AT with its more focussed mission and technology requirements. The stellarator path to DEMO is briefly discussed. Regardless of the choice of FNF option, an accompanying science and technology development program, also aimed at DEMO readiness, is absolutely essential.

  9. Webinar: Ventilation and Filtration Strategies with Indoor airPLUS and Zero Energy Ready Homes

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy Zero Energy Ready Home (ZERH) Program represents a whole new level of home performance, with rigorous requirements that ensure outstanding levels of energy savings,...

  10. DOE Zero Ready Home Case Study: Green Extreme Homes & Carl Franklin...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    certifi ed to the high performance requirements of the U.S. Department of Energy's Zero Energy Ready Home program, thanks to a successful collaboration between the non-profi t...

  11. DOE Zero Energy Ready Home Going Green and Building Strong: Building...

    Broader source: Energy.gov (indexed) [DOE]

    require participation in the FORTIFIED Home program for certification under the DOE Zero Energy Ready Home program, we do strongly encourage it, and we think that there's a lot of...

  12. Solar Ready: An Overview of Implementation Practices

    SciTech Connect (OSTI)

    Watson, A.; Guidice, L.; Lisell, L.; Doris, L.; Busche, S.

    2012-01-01

    This report explores three mechanisms for encouraging solar ready building design and construction: solar ready legislation, certification programs for solar ready design and construction, and stakeholder education. These methods are not mutually exclusive, and all, if implemented well, could contribute to more solar ready construction. Solar ready itself does not reduce energy use or create clean energy. Nevertheless, solar ready building practices are needed to reach the full potential of solar deployment. Without forethought on incorporating solar into design, buildings may be incompatible with solar due to roof structure or excessive shading. In these cases, retrofitting the roof or removing shading elements is cost prohibitive. Furthermore, higher up-front costs due to structural adaptations and production losses caused by less than optimal roof orientation, roof equipment, or shading will lengthen payback periods, making solar more expensive. With millions of new buildings constructed each year in the United States, solar ready can remove installation barriers and increase the potential for widespread solar adoption. There are many approaches to promoting solar ready, including solar ready legislation, certification programs, and education of stakeholders. Federal, state, and local governments have the potential to implement programs that encourage solar ready and in turn reduce barriers to solar deployment. With the guidance in this document and the examples of jurisdictions and organizations already working to promote solar ready building practices, federal, state, and local governments can guide the market toward solar ready implementation.

  13. Operational Readiness Review: Savannah River Replacement Tritium Facility

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    The Operational Readiness Review (ORR) is one of several activities to be completed prior to introducing tritium into the Replacement Tritium Facility (RTF) at the Savannah River Site (SRS). The Secretary of Energy will rely in part on the results of this ORR in deciding whether the startup criteria for RTF have been met. The RTF is a new underground facility built to safely service the remaining nuclear weapons stockpile. At RTF, tritium will be unloaded from old components, purified and enriched, and loaded into new or reclaimed reservoirs. The RTF will replace an aging facility at SRS that has processed tritium for more than 35 years. RTF has completed construction and is undergoing facility startup testing. The final stages of this testing will require the introduction of limited amounts of tritium. The US Department of Energy (DOE) ORR was conducted January 19 to February 4, 1993, in accordance with an ORR review plan which was developed considering previous readiness reviews. The plan also considered the Defense Nuclear Facilities Safety Board (DNFSB) Recommendations 90-4 and 92-6, and the judgements of experienced senior experts. The review covered three major areas: (1) Plant and Equipment Readiness, (2) Personnel Readiness, and (3) Management Systems. The ORR Team was comprised of approximately 30 members consisting of a Team Leader, Senior Safety Experts, and Technical Experts. The ORR objectives and criteria were based on DOE Orders, industry standards, Institute of Nuclear Power Operations guidelines, recommendations of external oversight groups, and experience of the team members.

  14. Readiness review plan for the in situ vitrification demonstration of Seepage Pit 1 in Waste Area Grouping 7

    SciTech Connect (OSTI)

    NONE

    1995-05-01

    A treatability study is planned that encompasses the application of in situ vitrification (ISV) to at least two segments of the Oak Ridge National Laboratory Seepage Pit I during the third quarter of fiscal year 1995. Before the treatability study can be initiated, the proposed activity must be subjected to an Operational Readiness Review (ORR). ORR is a structured methodology of determining readiness to proceed as outlined in Martin Marietta Energy Systems, Inc. (Energy Systems), Environmental Restoration Waste Management Procedure ER/C-P1610, which provides Energy Systems organizations assurance that the work to be performed is consistent with management`s expectations and that the subject activity is ready to proceed safely. The readiness review plan provides details of the review plan overview and the scope of work to be performed. The plan also identifies individuals and position responsibilities for implementing the activity. The management appointed Readiness Review Board (RRB) has been identified. A Field Readiness Review Team (FRT), a management appointed multidisciplinary group, has been established (1) to evaluate the ISV treatability study, (2) to identify and assemble supporting objective evidences of the readiness to proceed, and (3) to assist the team leader in presenting the evidences to the RRB. A major component of RRB is the formulation of readiness review criteria months before the operation. A comprehensive readiness review tree (a positive logic tree) is included, which identifies the activities required for the development of the readiness criteria. The readiness review tree serves as a tool to prevent the omission of an item that could affect system performance. All deficiencies identified in the review will be determined as prestart findings and must be resolved before the project is permitted to proceed. The final approval of the readiness to proceed will be the decision of RRB.

  15. Technology Readiness Assessments | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    August 1, 2013 Technology Readiness Assessment (TRA)Technology Maturation Plan (TMP) Process Guide This document is a guide for those involved in conducting TRAs and developing...

  16. Internship Checklist Ready Reference C-3

    E-Print Network [OSTI]

    Internship Checklist Ready Reference C-3 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career Services Office

  17. Cover Letter Formula Ready Reference F-3

    E-Print Network [OSTI]

    Cover Letter Formula Ready Reference F-3 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career Services Office

  18. Letter of Refusal Ready Reference F-8

    E-Print Network [OSTI]

    Letter of Refusal Ready Reference F-8 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology Career

  19. Sample Withdrawal Letter Ready Reference F-11

    E-Print Network [OSTI]

    Sample Withdrawal Letter Ready Reference F-11 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  20. Sample Application Letter Ready Reference F-5

    E-Print Network [OSTI]

    Sample Application Letter Ready Reference F-5 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  1. Sample Networking Letter Ready Reference F-6

    E-Print Network [OSTI]

    Sample Networking Letter Ready Reference F-6 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  2. Sample Acceptance Letter Ready Reference F-10

    E-Print Network [OSTI]

    Sample Acceptance Letter Ready Reference F-10 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  3. Job Search Steps Ready Reference D-1

    E-Print Network [OSTI]

    Job Search Steps Ready Reference D-1 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career Services Office

  4. Preparing A Vita Ready Reference E-13

    E-Print Network [OSTI]

    Preparing A Vita Ready Reference E-13 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career Services Office

  5. Hydrogen Infrastructure Market Readiness: Opportunities and Potential...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities and Potential for Near-term Cost Reductions. Proceedings of the Hydrogen Infrastructure Market Readiness Workshop and Summary of Feedback Provided through the...

  6. Community Readiness Assessments | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Community Readiness Assessments, Call Slides and Discussion Summary, December 5, 2013. Call Slides and Discussion Summary More Documents & Publications Focus Series: Program Finds...

  7. Organizational Readiness in Specialty Mental Health Care

    E-Print Network [OSTI]

    Hamilton, Alison B.; Cohen, Amy N.; Young, Alexander S.

    2010-01-01

    readiness for change (ORC) measure, and key stake- holders43 clinical staff completed the ORC, and 38 key stakeholdersdeviations (SDs) of the ORC scores are also illuminating in

  8. ORISE: Asset Readiness Management System (ARMS)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Asset Readiness Management System (ARMS) Database tracks emergency response exercises and equipment to help DOE asses emergency preparedness Developed by the Oak Ridge Institute...

  9. Building a Weather-Ready Nation noaa.gov/wrn Weather-Ready Nation &

    E-Print Network [OSTI]

    Building a Weather-Ready Nation noaa.gov/wrn Welcome Weather-Ready Nation & America's PrepareAthon! Webinar April 1, 2015 "Whole Community Approach to Building National Resilience " #12;Building a Weather-Ready Nation A word from... noaa.gov/wrn Dr. Kathryn Sullivan NOAA Administrator #12;Building a Weather

  10. ZERH Webinar: Selling Zero Energy Ready Homes Made Easy: Tools...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ZERH Webinar: Selling Zero Energy Ready Homes Made Easy: Tools and Resources that Work ZERH Webinar: Selling Zero Energy Ready Homes Made Easy: Tools and Resources that Work...

  11. Designing and Building Houses that are Solar Ready | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    after initial construction is completed can save time and money by following new house Solar Ready design guidelines. Solar Ready houses are designed and built with integrated...

  12. DOE Zero Energy Ready Home Case Study: Greenhill Contracting...

    Energy Savers [EERE]

    Zero Energy Ready Home Case Study: Greenhill Contracting, Green Acres 20, 26, 28, New Paltz, NY DOE Zero Energy Ready Home Case Study: Greenhill Contracting, Green Acres 20,...

  13. Energy -- and Water -- Efficiency in the DOE Zero Energy Ready...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy -- and Water -- Efficiency in the DOE Zero Energy Ready Home Program Webinar (Text Version) Energy -- and Water -- Efficiency in the DOE Zero Energy Ready Home Program...

  14. Preliminary Technology Readiness Assessment (TRA) for the Calcine...

    Office of Environmental Management (EM)

    Preliminary Technology Readiness Assessment (TRA) for the Calcine Disposition Project Volume 1 (CDP) Preliminary Technology Readiness Assessment (TRA) for the Calcine Disposition...

  15. DOE Zero Energy Ready Home Case Study: Mandalay Homes, Prescott...

    Energy Savers [EERE]

    Homes, Prescott Valley, AZ DOE Zero Energy Ready Home Case Study: Mandalay Homes, Phoenix, AZ, Affordable DOE Zero Energy Ready Home Case Study: Mandalay Homes, Prescott...

  16. Advancing Technology Readiness: Wave Energy Testing and Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advancing Technology Readiness: Wave Energy Testing and Demonstration Advancing Technology Readiness: Wave Energy Testing and Demonstration March 6, 2014 - 1:23pm Addthis Northwest...

  17. Energy Department Emergency Response Team Ready to Respond to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emergency Response Team Ready to Respond to Hurricane Irene Energy Department Emergency Response Team Ready to Respond to Hurricane Irene August 26, 2011 - 12:15pm Addthis...

  18. Management assessment of tank waste remediation system contractor readiness to proceed with phase 1B privatization

    SciTech Connect (OSTI)

    Honeyman, J.O.

    1998-01-09

    This Management Assessment of Tank Waste Remediation System (TWRS) Contractor Readiness to Proceed With Phase 1B Privatization documents the processes used to determine readiness to proceed with tank waste treatment technologies from private industry, now known as TWRS privatization. An overall systems approach was applied to develop action plans to support the retrieval and disposal mission of the TWRS Project. The systems and infrastructure required to support the mission are known. Required systems are either in place or plans have been developed to ensure they exist when needed. Since October 1996 a robust system engineering approach to establishing integrated Technical Baselines, work breakdown structures, tank farms organizational structure and configurations, work scope, and costs has become part of the culture within the TWRS Project. An analysis of the programmatic, management, and technical activities necessary to declare readiness to proceed with execution of the mission demonstrates that the system, personnel, and hardware will be on-line and ready to support the private contractors. The systems approach included defining the retrieval and disposal mission requirements and evaluating the readiness of the Project Hanford Management Contract (PHMC) team to support initiation of waste processing by the private contractors in June 2002 and to receive immobilized waste shortly thereafter. The Phase 1 feed delivery requirements from the private contractor Requests for Proposal were reviewed. Transfer piping routes were mapped, existing systems were evaluated, and upgrade requirements were defined.

  19. Management assessment of tank waste remediation system contractor readiness to proceed with phase 1B privatization

    SciTech Connect (OSTI)

    Certa, P.J.

    1998-01-07

    Readiness to Proceed With Phase 1B Privatization documents the processes used to determine readiness to proceed with tank waste treatment technologies from private industry, now known as TWRS privatization. An overall systems approach was applied to develop action plans to support the retrieval and disposal mission of the TWRS Project. The systems and infrastructure required to support the mission are known. Required systems are either in place or plans have been developed to ensure they exist when needed. Since October 1996 a robust system engineering approach to establishing integrated Technical Baselines, work breakdown structures, tank farms organizational structure and configurations, work scope, and costs has become part of the culture within the TWRS Project. An analysis of the programmatic, management, and technical activities necessary to declare readiness to proceed with execution of the mission demonstrates that the system, personnel, and hardware will be on line and ready to support the private contractors. The systems approach included defining the retrieval and disposal mission requirements and evaluating the readiness of the Project Hanford Management Contract (PHMC) team to support initiation of waste processing by the private contractors in June 2002 and to receive immobilized waste shortly thereafter. The Phase 1 feed delivery requirements from the private contractor Requests for Proposal were reviewed. Transfer piping routes were mapped, existing systems were evaluated, and upgrade requirements were defined.

  20. TECHNOLOGY READINESS LEVELS A White Paper

    E-Print Network [OSTI]

    Rhoads, James

    028 TECHNOLOGY READINESS LEVELS A White Paper April 6, 1995 John C. Mankins Advanced Concepts Office Office of Space Access and Technology NASA Introduction Technology Readiness Levels (TRLs) are a systematic metric/measurement system that supports assessments of the maturity of a particular technology

  1. Roundtable on Sustainable Biofuels Certification Readiness Study

    E-Print Network [OSTI]

    Roundtable on Sustainable Biofuels Certification Readiness Study: Hawai`i Biofuel Projects Prepared 12.1 Deliverable Bioenergy Analyses Prepared by Hawai`i Biofuel Foundation And NCSI Americas Inc agency thereof. #12;1 RSB Certification Readiness Study: Hawaii Biofuel Projects Prepared For Hawaii

  2. Technology Readiness Levels for Advanced Nuclear Fuels and Materials Development

    SciTech Connect (OSTI)

    Jon Carmack

    2014-01-01

    The Technology Readiness Level (TRL) process is used to quantitatively assess the maturity of a given technology. The TRL process has been developed and successfully used by the Department of Defense (DOD) for development and deployment of new technology and systems for defense applications. In addition, NASA has also successfully used the TRL process to develop and deploy new systems for space applications. Advanced nuclear fuels and materials development is a critical technology needed for closing the nuclear fuel cycle. Because the deployment of a new nuclear fuel forms requires a lengthy and expensive research, development, and demonstration program, applying the TRL concept to the advanced fuel development program is very useful as a management and tracking tool. This report provides definition of the technology readiness level assessment process as defined for use in assessing nuclear fuel technology development for the Advanced Fuel Campaign (AFC).

  3. Salary Negotiation Ready ReferenceH-3

    E-Print Network [OSTI]

    Salary Negotiation Ready ReferenceH-3 College of Engineering, Architecture & Technology Career" salary on the top end of your range. Although this range may appear high because it is created from

  4. Superconducting Partnership with Readiness Review Update

    E-Print Network [OSTI]

    1 Superconducting Partnership with Industry: Readiness Review Update Mike Gouge, ORNL Steve Ashworth, LANL Paul Bakke, DOE-Golden DOE 2004 Superconductivity Peer Review July 27-29, 2004 #12;2 SPI

  5. Modeling Renewable Energy Readiness: The UAE Context

    E-Print Network [OSTI]

    Choucri, Nazli

    Modeling technology policy is becoming an increasingly important capability to steer states and societies toward sustainability. This paper presents a simulation-modeling approach to evaluate renewable energy readiness, ...

  6. Zero Energy Ready Home | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2-story, 1,650-ft2 cabin built by a custom home builder for his own family meets Passive House Standards with 5.5-in. ZERH Events ZERH Webinar: Selling Zero Energy Ready Homes...

  7. Experimental Studies of Hydroxyl Radical Initiated Tropospheric Oxidation of Unsaturated Hydrocarbons 

    E-Print Network [OSTI]

    Ghosh, Buddhadeb

    2011-10-21

    -1 EXPERIMENTAL STUDIES OF HYDROXYL RADICAL INITIATED TROPOSPHERIC OXIDATION OF UNSATURATED HYDROCARBONS A Dissertation by BUDDHADEB GHOSH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY August 2010 Major Subject: Chemistry EXPERIMENTAL STUDIES OF HYDROXYL RADICAL INITIATED TROPOSPHERIC OXIDATION OF UNSATURATED HYDROCARBONS A Dissertation...

  8. Hydroxyl Radical in the Troposphere

    E-Print Network [OSTI]

    Toohey, Darin W.

    1 Lecture 20 Hydroxyl Radical in the Troposphere ATOC/CHEM 5151 #12;2 Clarifications on Homework #4 s-1 Consequence: Diurnal variation in OH, since J 0 at night #12;16 Hydroxyl lifetime · Very short + 0.6P) OH = ? #12;17 Hydroxyl Lifetime ][ 1

  9. Readiness assessment plan for the Radioactive Mixed Waste Land Disposal Facility (Trench 31)

    SciTech Connect (OSTI)

    Irons, L.G.

    1994-11-22

    This document provides the Readiness Assessment Plan (RAP) for the Project W-025 (Radioactive Mixed Waste Land Disposal Facility) Readiness Assessment (RA). The RAP documents prerequisites to be met by the operating organization prior to the RA. The RAP is to be implemented by the RA Team identified in the RAP. The RA Team is to verify the facility`s compliance with criteria identified in the RAP. The criteria are based upon the {open_quotes}Core Requirements{close_quotes} listed in DOE Order 5480.31, {open_quotes}Startup and Restart of Nuclear Facilities{close_quotes}.

  10. Crystallization studies of 5'-deoxyadenosyl radical enzymes

    E-Print Network [OSTI]

    Phillips, Laura (Laura Anne)

    2007-01-01

    Both adenosylcobalamin- and S-adenosylmethionine-dependent radical enzymes use a 5'-deoxyadenosyl radical intermediate to abstract a hydrogen atom from their substrates. In the case of adenosylcobalamin-dependent enzymes, ...

  11. Technology Readiness and the Smart Grid

    SciTech Connect (OSTI)

    Kirkham, Harold; Marinovici, Maria C.

    2013-02-27

    Technology Readiness Levels (TRLs) originated as a way for the National Aeronautics and Space Administration (NASA) to monitor the development of systems being readied for space. The technique has found wide application as part of the more general topic of system engineering. In this paper, we consider the applicability of TRLs to systems being readied for the smart grid. We find that there are many useful parallels, and much to be gained by this application. However, TRLs were designed for a developer who was also a user. That is not usually the case for smart grid developments. We consider the matter from the point of view of the company responsible for implementation, typically a utility, and we find that there is a need for connecting the many standards in the industry. That connection is explored, and some new considerations are introduced.

  12. DOE Zero Energy Ready Home Newsletter February 2015 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zero Energy Ready Home Newsletter February 2015 DOE Zero Energy Ready Home Newsletter February 2015 Table of Contents A note from Sam Rashkin: "If you don't tell your story, you...

  13. ZERH Webinar: Sales and Value Recognition of Zero Energy Ready...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ZERH Webinar: Sales and Value Recognition of Zero Energy Ready Homes ZERH Webinar: Sales and Value Recognition of Zero Energy Ready Homes December 18, 2014 12:00PM to 1:15PM EST...

  14. Solar Ready Vets: Preparing Our Veterans to Join the Growing...

    Office of Environmental Management (EM)

    Solar Ready Vets: Preparing Our Veterans to Join the Growing Solar Workforce Solar Ready Vets: Preparing Our Veterans to Join the Growing Solar Workforce April 6, 2015 - 2:27pm...

  15. An assessment of the value of retail ready packaging

    E-Print Network [OSTI]

    Jackson, Kathleen Anne

    2008-01-01

    Use of retail-ready packaging reduces the costs of replenishing store shelves by eliminating the labor of removing packaging materials and stocking individual items on shelves. While reducing costs for retailers, retail-ready ...

  16. University of Michigan Gets Offshore Wind Ready for Winter on...

    Office of Environmental Management (EM)

    University of Michigan Gets Offshore Wind Ready for Winter on Lake Michigan University of Michigan Gets Offshore Wind Ready for Winter on Lake Michigan April 16, 2013 - 12:00am...

  17. Building America Top Innovations 2013 Profile - Zero Energy-Ready...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Top Innovations 2013 Profile - Zero Energy-Ready Single-Family Homes Building America Top Innovations 2013 Profile - Zero Energy-Ready Single-Family Homes Many...

  18. Building America Top Innovations 2013 Profile - Zero Energy-Ready...

    Energy Savers [EERE]

    Top Innovations 2013 Profile - Zero Energy-Ready Single-Family Homes Building America Top Innovations 2013 Profile - Zero Energy-Ready Single-Family Homes Many Building America...

  19. DOE Zero Energy Ready Home Case Study: Green Extreme Homes &...

    Energy Savers [EERE]

    Green Extreme Homes & Carl Franklin Homes, Garland, TX DOE Zero Energy Ready Home Case Study: Green Extreme Homes & Carl Franklin Homes, Garland, TX DOE Zero Energy Ready Home Case...

  20. Building America Zero Energy Ready Home Case Study: Imery Group...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zero Energy Ready Home Case Study: Imery Group, Proud Green Home, Serenbe GA Building America Zero Energy Ready Home Case Study: Imery Group, Proud Green Home, Serenbe GA Case...

  1. Energy Efficiency First, Zero Energy Ready Homes, and Solar PV...

    Office of Environmental Management (EM)

    Energy Efficiency First, Zero Energy Ready Homes, and Solar PV Updates Energy Efficiency First, Zero Energy Ready Homes, and Solar PV Updates April 29, 2015 11:00AM to 12:30PM MDT...

  2. DOE Zero Energy Ready Home Partner Central | Department of Energy

    Office of Environmental Management (EM)

    Central DOE Zero Energy Ready Home Partner Central The DOE Zero Energy Ready Home label is the symbol of excellence for new homes. Join the ranks of leading edge builders who...

  3. ENERGY STAR Webinar: Zero Energy Ready Home Program

    Broader source: Energy.gov [DOE]

    Once a home is as good as ENERGY STAR, the modest added “lift” to bring a home up to DOE’s Zero Energy Ready specs unleashes a wave of powerful value messages.  DOE Zero Energy Ready Homes live...

  4. NHI Component Technical Readiness Evaluation System

    SciTech Connect (OSTI)

    Steven R. Sherman; Dane F. Wilson; Steven J. Pawel

    2007-09-01

    A decision process for evaluating the technical readiness or maturity of components (i.e., heat exchangers, chemical reactors, valves, etc.) for use by the U.S. DOE Nuclear Hydrogen Initiative is described. This system is used by the DOE NHI to assess individual components in relation to their readiness for pilot-scale and larger-scale deployment and to drive the research and development work needed to attain technical maturity. A description of the evaluation system is provided, and examples are given to illustrate how it is used to assist in component R&D decisions.

  5. Fast Track Troubleshooting Using the SMART BoardTM 600 Series Interactive Whiteboard's Ready Light

    E-Print Network [OSTI]

    Matrajt, Graciela

    Fast Track Troubleshooting Using the SMART BoardTM 600 Series Interactive Whiteboard's Ready Light Start Is the Ready light on? Is the Ready light red or alternating red/green? Is the Ready light flashing green? Is the Ready light solid green? Is the Ready light amber? No Yes No No No Go to Flowchart 2

  6. Building a Weather-Ready Nation Fall Weather Safety

    E-Print Network [OSTI]

    Building a Weather-Ready Nation Fall Weather Safety www.weather.gov/safety Wildfire ­ Drought ­ Hurricanes ­ Wind ­ Early Season Winter ­ Flood #12;Building a Weather-Ready Nation Wildfire Safety smoking materials. weather.gov/wildfire www.weather.gov/safety #12;Building a Weather-Ready Nation

  7. A Chemically Competent Thiosulfuranyl Radical on the Escherichia coli Class III Ribonucleotide Reductase

    E-Print Network [OSTI]

    Wei, Yifeng

    The class III ribonucleotide reductases (RNRs) are glycyl radical (G•) enzymes that provide the balanced pool of deoxynucleotides required for DNA synthesis and repair in many facultative and obligate anaerobic bacteria ...

  8. Guam - Solar-Ready Residential Building Requirement | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to Tapping STD-1128-2013 April< BackGovernmenttheof< Back

  9. DOE Zero Energy Ready Home National Program Requirements (Rev. 04) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 2015 GATEWAY Takes 9.New TownHome Serenbe,

  10. DOE Zero Energy Ready Home National Program Requirements (Rev. 05) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 2015 GATEWAY Takes 9.New TownHome Serenbe,Department of

  11. Professional References Ready Reference E-11

    E-Print Network [OSTI]

    Professional References Ready Reference E-11 College of Engineering, Architecture & Technology College of Engineering, Architecture & Technology Career Services Office ATRC 109E Stillwater, OK 74078 requested to do so. Create a separate sheet entitled "References." Print it on the same high quality papers

  12. The Behavioral Interview Ready Reference G-7

    E-Print Network [OSTI]

    The Behavioral Interview Ready Reference G-7 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology in technical and high tech industries within the last 10 years. Behavioral interviews are designed to focus

  13. Questioning Yourself Ready Reference B-2

    E-Print Network [OSTI]

    Questioning Yourself Ready Reference B-2 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career Services Office set my own hours? Do I thrive in a high-stress atmosphere, or would I prefer something a bit more

  14. Roundtable on Sustainable Biofuels Certification Readiness Study

    E-Print Network [OSTI]

    Roundtable on Sustainable Biofuels Certification Readiness Study: Hawai`i Biofuel Projects Prepared 12.1 Deliverable (item 2) Bioenergy Analyses Prepared by Hawai`i Biofuel Foundation And NCSI Americas: Hawaii Biofuel Projects Prepared For Hawaii Natural Energy Institute School of Ocean Earth Sciences

  15. Human Resources Organizational Readiness Project: An Overview

    E-Print Network [OSTI]

    Finzi, Adrien

    and easily interface with SAP software Managed by a special Human Resources project team Will be undertaken in close coordination with the BUworks program team HR Organizational Readiness Project BUworks / SAP of SAP Enhanced data security within the new system Current job "system" is 30 years old ­ it must

  16. CRAD, Facility Safety- Readiness Review Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) that can be used for assessment of a contractor's Readiness Review Program.

  17. DOE Zero Energy Ready Home Case Study: Green Extreme Homes & Carl Franklin Homes — First DOE Zero Energy Ready Home Retrofit, Garland, TX

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This builder was honored with an Affordable Builder award in the 2014 Housing Innovation Awards, for the first retrofit home certified to the DOE Zero Energy Ready home requirements.The 60-year-old, three-bedroom ranch home is expected to save its homeowner more than $1,000 a year in utility bills compared to a home built to the current 2009 International Energy Conservation Code.

  18. Aromatic-radical oxidation chemistry

    SciTech Connect (OSTI)

    Glassman, I.; Brezinsky, K. [Princeton Univ., NJ (United States)

    1993-12-01

    The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

  19. Laser spectroscopy of hydrocarbon radicals

    SciTech Connect (OSTI)

    Chen, P.

    1993-12-01

    The author reports the application of supersonic jet flash pyrolysis to the specific preparation of a range of organic radicals, biradicals, and carbenes in a skimmed molecular beam. Each species was produced cleanly and specifically, with little or no secondary reactions by the thermal dissociation of appropriately designed and synthesized organic precursors. Photoelectron spectra of the three isomeric C{sub 3}H{sub 2} carbenes, ortho-benzyne, and the {alpha},3-dehydrotoluene biradical, were used to establish adiabatic ionization potentials for use in thermochemical determinations.

  20. Development of Technology Readiness Level (TRL) Metrics and Risk Measures

    SciTech Connect (OSTI)

    Engel, David W.; Dalton, Angela C.; Anderson, K. K.; Sivaramakrishnan, Chandrika; Lansing, Carina

    2012-10-01

    This is an internal project milestone report to document the CCSI Element 7 team's progress on developing Technology Readiness Level (TRL) metrics and risk measures. In this report, we provide a brief overview of the current technology readiness assessment research, document the development of technology readiness levels (TRLs) specific to carbon capture technologies, describe the risk measures and uncertainty quantification approaches used in our research, and conclude by discussing the next steps that the CCSI Task 7 team aims to accomplish.

  1. Roaming radical pathways for the decomposition of alkanes.

    SciTech Connect (OSTI)

    Harding, L. B.; Klippenstein, S. J.

    2010-01-01

    CASPT2 calculations predict the existence of roaming radical pathways for the decomposition of propane, n-butane, isobutane and neopentane. The roaming radical paths lead to the formation of an alkane and an alkene instead of the expected radical products. The predicted barriers for the roaming radical paths lie {approx}1 kcal/mol below the corresponding radical asymptotes.

  2. The hydroxyl radical initiated oxidation of unsaturated hydrocarbons in the troposphere: a theoretical and experimental approach 

    E-Print Network [OSTI]

    Tullos, Erin Elizabeth

    2009-05-15

    -1 THE HYDROXYL RADICAL INITIATED OXIDATION OF UNSATURATED HYDROCARBONS IN THE TROPOSPHERE: A THEORETICAL AND EXPERIMENTAL APPROACH A Dissertation by ERIN ELIZABETH TULLOS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY May 2007 Major Subject: Chemistry THE HYDROXYL RADICAL INITIATED OXIDATION OF UNSATURATED HYDROCARBONS IN THE TROPOSPHERE: A THEORETICAL AND EXPERIMENTAL APPROACH A Dissertation by ERIN ELIZABETH TULLOS...

  3. Technology Readiness Assessment (TRA)/Technology Maturation Plan...

    Energy Savers [EERE]

    (TRA)Technology Maturation Plan (TMP) Process Guide Technology Readiness Assessment (TRA)Technology Maturation Plan (TMP) Process Guide This document is a guide for those...

  4. Marketing and Sales Solutions for Zero Energy Ready Homes Webinar...

    Broader source: Energy.gov (indexed) [DOE]

    Below is the text version of the webinar, Marketing and Sales Solutions for Zero Energy Ready Homes, presented in June 2014. Lindsay Parker: ... the Department of Energy Zero...

  5. DOE Zero Energy Ready Home Second Production Builder Round Table

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solidify the Zero Energy Ready definition DOE will continue participating in the Net-Zero Energy coalition to secure a definition with all stakeholders. Expand DOE Challenge...

  6. Ten Steps for Career Success Ready Reference A-4

    E-Print Network [OSTI]

    Ten Steps for Career Success Ready Reference A-4 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career

  7. Sample Letter of Inquiry Ready Reference F-4

    E-Print Network [OSTI]

    Sample Letter of Inquiry Ready Reference F-4 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of Engineering, Architecture & Technology Career

  8. First Impressions on Job Interviews Ready Reference G-2

    E-Print Network [OSTI]

    & Technology Career Services Oklahoma State University College of Engineering, Architecture & TechnologyFirst Impressions on Job Interviews Ready Reference G-2 College of Engineering, Architecture

  9. Sample Status Inquiry Letter Ready Reference F-9

    E-Print Network [OSTI]

    Sample Status Inquiry Letter Ready Reference F-9 College of Engineering, Architecture & Technology Career Services Oklahoma State University College of College of Engineering, Architecture & Technology

  10. DOE Zero Energy Ready Home Webinar: Building Energy Optimization...

    Energy Savers [EERE]

    Webinar: Building Energy Optimization (BEopt) Software DOE Zero Energy Ready Home Webinar: Building Energy Optimization (BEopt) Software This webinar was presented on May 15, 2014...

  11. Smart-Grid Ready PV Inverter with Utility Communication

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    standards, operations center visibility and management, and optimized coordination of smart PV inverters with existing distribution control devices. Smart-Grid Ready PV Inverter...

  12. Smart-Grid Ready PV Inverters with Utility Communication

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    INTEGRATION Smart-Grid Ready PV Inverters with Utility Communication Electric Power Research Institute Brian Seal, Tom Key, Aminul Huque, Lindsey Rogers Technical Contact Brian...

  13. Module Embedded Microninverter Smart Grid Ready Residential Solar...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    including VoltVAR support Module Embedded Microninverter Smart Grid Ready Residential Solar Electric System RUI ZHOU GE GLOBAL RESEARCH Develop and demonstrate power electronics...

  14. DOE Zero Energy Ready Home: Lighting Efficiency Webinar (Text...

    Broader source: Energy.gov (indexed) [DOE]

    webinar, DOE Zero Energy Ready Home: Lighting Efficiency, presented in May 2015. Alex Krowka: Presentation cover slide: ... join us today for this session on LED lighting design...

  15. Readiness Review Training- Development of Criteria And Review Approach Documents

    Broader source: Energy.gov [DOE]

    Slides used for November 8-9, 2010 Readiness Review Training - Development of Criteria And Review Approach Documents at the Idaho National Laboratory.

  16. DOE ZERO ENERGY READY HOME UPDATE NEWSLETTER APRIL 2015 | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Awards: Lasting Legacies ZERH Update July 2015.pdf More Documents & Publications DOE ZERO ENERGY READY HOME UPDATE NEWSLETTER MAY 2015 Building America Building Science Translator...

  17. DOE Zero Energy Ready Home Case Study: Transformation Inc., Production...

    Energy Savers [EERE]

    spray foam on basement walls, triple-pane windows, and one mini-split ductless heat pump. BAZeroEnergyReadyTransformationProduction062414.pdf More Documents &...

  18. Accelerating the Electrification of U.S. Drive Trains: Ready...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Trains: Ready and Affordable Technology Solutions for Domestically Manufactured Advanced Batteries 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer...

  19. Accelerating the Electrification of U.S. Drive Trains: Ready...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ready and Affordable Technology Solutions for Domestically Manufactured Advanced Batteries Larry Atkins Exide Technologies June 7, 2010 Project ID ARRAVT004 This...

  20. ZERH Webinar: Selling Zero Energy Ready Homes Made Easy: Tools...

    Broader source: Energy.gov (indexed) [DOE]

    been watching closely, the Zero Energy Ready Home now has an impressive array of tools that can help builder partners effectively communicate the value of their certified...

  1. DOE Zero Energy Ready Home Resources | Department of Energy

    Office of Environmental Management (EM)

    look up their case studies in the Building America Program Publication and Product Library, or search the Building America Solution Center. DOE Zero Energy Ready Home Sales and...

  2. Independent Oversight Review of the NNSA Production Office Readiness...

    Energy Savers [EERE]

    Independent Oversight Review of the NNSA Production Office Readiness Review Program February 2014 Office of Safety and Emergency Management Evaluations Office of Enforcement and...

  3. Using ReadyTalk Teleconference Service (Audio and Web) Summary: Learn how to sign up for ReadyTalk teleconference service and how to set up a

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    Using ReadyTalk Teleconference Service (Audio and Web) Summary: Learn how to sign up for Ready guides. Services tab: #12; Brief descriptions of ReadyTalk's services. Note that prices on the Web siteTalk teleconference service and how to set up a conference call using ReadyTalk. Note: UC has signed a system

  4. Community Readiness Assessments | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartment ofCommercial Grade DedicationaOfficeto theifReadiness

  5. Readiness Review RM | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested PartiesBuildingBudget ||Department ofRequest7ofPlanEO-05-01:NationalReadiness

  6. ORISE: Asset Readiness Management System (ARMS)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEY UNIVERSE The 2014 surveyNuclearHowAsset Readiness Management

  7. Atom transfer radical polymerization of ionic liquid monomer...

    Office of Scientific and Technical Information (OSTI)

    Atom transfer radical polymerization of ionic liquid monomer: The influence of saltcounterion on polymerization Citation Details In-Document Search Title: Atom transfer radical...

  8. Capture-ready power plants : options, technologies and economics

    E-Print Network [OSTI]

    Bohm, Mark (Mark C.)

    2006-01-01

    A plant can be considered to be capture-ready if, at some point in the future it can be retrofitted for carbon capture and sequestration and still be economical to operate. The concept of capture-ready is not a specific ...

  9. Building a Weather-Ready Nation Winter Weather Safety

    E-Print Network [OSTI]

    Building a Weather-Ready Nation Winter Weather Safety NOAA/NWS Winter Weather Safety Seasonal Campaign www.weather.gov #12;Building a Weather-Ready Nation Winter Weather Hazards Winter Weather Safety www.weather.gov · Snow/Ice · Blizzards · Flooding · Cold Temperatures #12;Building a Weather

  10. DOE handbook: Guide to good practices for operational readiness reviews (ORR) team leader`s guide

    SciTech Connect (OSTI)

    1994-09-01

    This guidance section provides instructions, explanations and examples for the performance of all phases of an Operational Readiness Review (ORR). Details pertinent to the Team Leader (TL), Team Members (TM) and Review Coordinator (RC) are outlined. An appendix contains sample forms and correspondence which are typically used to initiate and perform the ORR. Although this document was written specifically for use by DOE ORR Team Leaders, its use may also be beneficial to contractor ORR Team Leaders. The handbook is also useful for Team Leaders of Readiness Assessments conducted in accordance with requirements of DOE O 425.1. Lessons learned, which are promulgated with this handbook, will benefit any line manager, particularly those preparing a facility or process for startup or restart.

  11. Fast beam studies of free radical photodissociation

    SciTech Connect (OSTI)

    Neumark, D.M. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    The authors have developed a novel technique for studying the photodissociation spectroscopy and dynamics of free radicals. In these experiments, radicals are generated by laser photodetachment of a fast (6-8 keV) mass-selected negative ion beam. The resulting radicals are photodissociated with a second laser, and the photofragments are collected and detected with high efficiency using a microchannel plate detector. The overall process is: ABC{sup -} {yields} ABC + e{sup -} {yields} A + BC, AB + C. Two types of fragment detection schemes are used. To map out the photodissociation cross-section of the radical, the photodissociation laser is scanned and the total photofragment yield is measured as a function of wavelength. In other experiments, the photodissociation frequency is fixed and the photofragment masses, kinetic energy release, and scattering angle is determined for each photodissociation event.

  12. Using ISMS Principles and Functions in Developing an ARRA Readiness Review Process

    Broader source: Energy.gov [DOE]

    Presenter: Linda K. Rogers, Assessments & Readiness Programs Manager, Bechtel Jacobs Company, LLC Track 8-8

  13. UVA-visible photo-excitation of guanine radical cations produces sugar radicals in DNA and

    E-Print Network [OSTI]

    Simons, Jack

    UVA-visible photo-excitation of guanine radical cations produces sugar radicals in DNA and model, 2005; Revised and Accepted September 6, 2005 ABSTRACT This work presents evidence that photo- nucleosides and deoxyribonucleotides. In dsDNA at low temperatures, formation of C10 is observed from photo

  14. Are Batteries Ready for Plug-in Hybrid Buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Kurani, Kenneth S; Burke, Andy

    2009-01-01

    higher power density batteries have reduced energy density,2008 UCD-ITS-WP-09-02 Are batteries ready for plug-in hybridprograms mischaracterize the batteries needed to start

  15. Are Batteries Ready for Plug-in Hybrid Buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

    2010-01-01

    237–253. Burke, A. , 2007. Batteries and ultracapacitors forresults with lithium-ion batteries. In: Proceedings (CD)locate/tranpol Are batteries ready for plug-in hybrid

  16. Are batteries ready for plug-in hybrid buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Kurani, Kenneth S.; Burke, Andrew

    2008-01-01

    higher power density batteries have reduced energy density,2008 UCD-ITS-WP-09-02 Are batteries ready for plug-in hybridprograms mischaracterize the batteries needed to start

  17. DOE Zero Energy Ready Home Webinar: Ducts in Conditioned Space

    Broader source: Energy.gov [DOE]

    DOE Challenge Home is a blueprint for zero energy ready homes.  When we make that statement – it’s impossible to justify huge thermal losses from ducts in unconditioned spaces.  That’s why one of...

  18. DOE Challenge Home (Now Zero Energy Ready Home) - Building America...

    Broader source: Energy.gov (indexed) [DOE]

    a much more rigorous set of guidelines that establish a national definition for Zero Net-Energy Ready performance. Read about this Top Innovation. See an example of a DOE...

  19. DOE Zero Energy Ready Home Ducts in Conditioned Space Webinar...

    Broader source: Energy.gov (indexed) [DOE]

    is design strategies for locating the ductwork within the conditioned envelope of the building. And this is sort of a must-have for zero energy ready homes, because if these homes...

  20. DOE Zero Energy Ready Home Case Study, Caldwell and Johnson,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exeter, RI, Custom Home Case study of a DOE Zero Energy Ready Home in Exeter, Rhode Island, that scored HERS 43 without PV. This 2,000 ft2 custom home has a spray- foamed...

  1. DOE Zero Energy Ready Home Case Study: Weiss Building & Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Ready Home in Downers Grove, IL, that scored HERS 35 without PV. This 3,600-square-foot custom home has advanced framed walls with R-23 dense-packed fiberglass plus R-13...

  2. DOE Zero Energy Ready Home Case Study: Weiss Building & Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a sealed attic with open-cell spray foam, a pier foundation, and 95% efficient gas furnace. BAZeroEnergyReadyWeissCustom062414.pdf More Documents & Publications DOE Zero...

  3. SRS Tank 48H Waste Treatment Project Technology Readiness Assessment

    Office of Environmental Management (EM)

    Savannah River Site Tank 48H Waste Treatment Project Technology Readiness Assessment Harry D. Harmon Joan B. Berkowitz John C. DeVine, Jr. Herbert G. Sutter Joan K. Young...

  4. DOE Zero Energy Ready Home Case Study: Evolutionary Home Builders...

    Energy Savers [EERE]

    vented attic with R-100 blown cellulose; wo air-to-air heat pumps SEER 14.1; HSPF 9.6; heat pump water heater. DOE Zero Energy Ready Home Case Study: Evolutionary Home Builders,...

  5. DOE Zero Energy Ready Home Case Study: Sunroc Builders, Bates...

    Office of Environmental Management (EM)

    8.25" SIP roof; uninsulated slab foundation; fresh air intake; SEER 16 ducted air source heat pump. DOE Zero Energy Ready Home Case Study: Sunroc Builders, Lakeland, FL More...

  6. DOE Zero Energy Ready Home Case Study: Manatee County Habitat...

    Energy Savers [EERE]

    has R-23 ICF walls, a spray-foamed sealed attic, solar hot water, and a ducted mini-split heat pump. BAZeroEnergyReadyManateeHabitatForHumanity062414.pdf More Documents &...

  7. DOE Zero Energy Ready Home Case Study: Charles Thomas Homes,...

    Energy Savers [EERE]

    under slab; a vented attic with R-100 blown cellulose; 95% AFUE furnace, 14 SEER AC, ERV; heat pump water heater. DOE Zero Energy Ready Home Case Study: Charles Thomas Homes,...

  8. DOE Zero Energy Ready Home Case Study: High Performance Homes...

    Energy Savers [EERE]

    R-15 unfaced batt on walls, sealed attic with R-49 ocsf under roof deck; ground source heat pump COP 4.4. DOE Zero Energy Ready Home Case Study: High Performance Homes,...

  9. DOE Zero Energy Ready Home Case Study: Amaris Homes, Fishers...

    Energy Savers [EERE]

    and around slab, a vented attic with with 2" ccsf plus R-15 blown cellulose, a central heat pump and HRV. DOE Zero Energy Ready Home Case Study: Amaris Homes, Vadnais Heights,...

  10. DOE Zero Energy Ready Home Case Study: Glastonbury Housesmith...

    Energy Savers [EERE]

    unvented attic with 5" ccsf and 6.5" blown fiberglass under the roof deck; ground source heat pump COP 4.4. DOE Zero Energy Ready Home Case Study: Glastonbury Housesmith, South...

  11. DOE Zero Energy Ready Home Case Study: Heirloom Design Build...

    Energy Savers [EERE]

    rigid foam under slab; sealed attic with R-28 ocsf under roof deck; 22.8 SEER; 12.5 HSPF heat pump. DOE Zero Energy Ready Home Case Study: Heirloom Design Build, Atlanta, GA More...

  12. DOE Zero Energy Ready Home Case Study: Addison Homes, Cobbler...

    Energy Savers [EERE]

    on inside with 2 inches poly iso, a vented attic with R-38 blown fiberglass, a central heat pump with fresh air intake. DOE Zero Energy Ready Home Case Study: Addison Homes,...

  13. EV Community Readiness projects: New York City and Lower Hudson...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EV Community Readiness projects: New York City and Lower Hudson Valley Clean Communities, Inc. (NY, MA, PA); NYSERDA (ME, NH, VT, MA, RI, CT, NY, NJ, PA, DE, MD, DC) EV Community...

  14. DOE Zero Energy Ready Home Case Study: Preferred Builders, Old...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R-13 closed-cell spray foam under the slab and on basement walls, an ERV, and a gas boiler for forced air and radiant floor heat. BAZeroEnergyReadyPreferredBuilders062414.pdf...

  15. DOE Zero Energy Ready Home Efficient Hot Water Distribution I...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    I -- What's At Stake Webinar (Text Version) DOE Zero Energy Ready Home Efficient Hot Water Distribution I -- What's At Stake Webinar (Text Version) Below is the text version of the...

  16. DOE Zero Energy Ready Home Case Study: Cobblestone Homes, Midland...

    Energy Savers [EERE]

    Case study of a DOE Zero Energy Ready home in Midland, MI, that scored HERS 49 without PV or HERS 44 with 1.4 kW of PV. The custom home served as a prototype and energy...

  17. DOE Zero Energy Ready Home Case Study: Sterling Brook Custom...

    Energy Savers [EERE]

    Zero Energy Ready home in Double Oak, TX, north of Dallas, that scored a HERS 44 without PV. The 3,752-ft2 two-story home served as an energy-efficient model home for the custom...

  18. DOE Zero Energy Ready Home Case Study: Southern Energy Homes...

    Energy Savers [EERE]

    Energy Ready Home standard. This manufactured home achieved a HERS score of 57 without PV. The home has been set up for side-by-side testing with an identical manufactured home...

  19. DOE Zero Energy Ready Home Case Study: Brookside Development...

    Broader source: Energy.gov (indexed) [DOE]

    of a DOE Zero Energy Ready home in Derby, CT, that achieves a HERS score of 45 without PV or HERS 26 with PV. The production home is one of a development of 7 two-story,...

  20. DOE Zero Energy Ready Home Case Study, Caldwell and Johnson,...

    Energy Savers [EERE]

    of a DOE Zero Energy Ready Home in Exeter, Rhode Island, that scored HERS 43 without PV. This 2,000 ft2 custom home has a spray- foamed attic and walls, plus rigid foam...

  1. Modeling and simulation technology readiness levels.

    SciTech Connect (OSTI)

    Clay, Robert L.; Shneider, Max S.; Marburger, S. J.; Trucano, Timothy Guy

    2006-01-01

    This report summarizes the results of an effort to establish a framework for assigning and communicating technology readiness levels (TRLs) for the modeling and simulation (ModSim) capabilities at Sandia National Laboratories. This effort was undertaken as a special assignment for the Weapon Simulation and Computing (WSC) program office led by Art Hale, and lasted from January to September 2006. This report summarizes the results, conclusions, and recommendations, and is intended to help guide the program office in their decisions about the future direction of this work. The work was broken out into several distinct phases, starting with establishing the scope and definition of the assignment. These are characterized in a set of key assertions provided in the body of this report. Fundamentally, the assignment involved establishing an intellectual framework for TRL assignments to Sandia's modeling and simulation capabilities, including the development and testing of a process to conduct the assignments. To that end, we proposed a methodology for both assigning and understanding the TRLs, and outlined some of the restrictions that need to be placed on this process and the expected use of the result. One of the first assumptions we overturned was the notion of a ''static'' TRL--rather we concluded that problem context was essential in any TRL assignment, and that leads to dynamic results (i.e., a ModSim tool's readiness level depends on how it is used, and by whom). While we leveraged the classic TRL results from NASA, DoD, and Sandia's NW program, we came up with a substantially revised version of the TRL definitions, maintaining consistency with the classic level definitions and the Predictive Capability Maturity Model (PCMM) approach. In fact, we substantially leveraged the foundation the PCMM team provided, and augmented that as needed. Given the modeling and simulation TRL definitions and our proposed assignment methodology, we conducted four ''field trials'' to examine how this would work in practice. The results varied substantially, but did indicate that establishing the capability dependencies and making the TRL assignments was manageable and not particularly time consuming. The key differences arose in perceptions of how this information might be used, and what value it would have (opinions ranged from negative to positive value). The use cases and field trial results are included in this report. Taken together, the results suggest that we can make reasonably reliable TRL assignments, but that using those without the context of the information that led to those results (i.e., examining the measures suggested by the PCMM table, and extended for ModSim TRL purposes) produces an oversimplified result--that is, you cannot really boil things down to just a scalar value without losing critical information.

  2. Resonance ionization detection of combustion radicals

    SciTech Connect (OSTI)

    Cool, T.A. [Cornell Univ., Ithaca, NY (United States)

    1993-12-01

    Fundamental research on the combustion of halogenated organic compounds with emphasis on reaction pathways leading to the formation of chlorinated aromatic compounds and the development of continuous emission monitoring methods will assist in DOE efforts in the management and disposal of hazardous chemical wastes. Selective laser ionization techniques are used in this laboratory for the measurement of concentration profiles of radical intermediates in the combustion of chlorinated hydrocarbon flames. A new ultrasensitive detection technique, made possible with the advent of tunable VUV laser sources, enables the selective near-threshold photoionization of all radical intermediates in premixed hydrocarbon and chlorinated hydrocarbon flames.

  3. LWRS ATR Irradiation Testing Readiness Status

    SciTech Connect (OSTI)

    Kristine Barrett

    2012-09-01

    The Light Water Reactor Sustainability (LWRS) Program was established by the U.S. Department of Energy Office of Nuclear Energy (DOE-NE) to develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors. The LWRS Program is divided into four R&D Pathways: (1) Materials Aging and Degradation; (2) Advanced Light Water Reactor Nuclear Fuels; (3) Advanced Instrumentation, Information and Control Systems; and (4) Risk-Informed Safety Margin Characterization. This report describes an irradiation testing readiness analysis in preparation of LWRS experiments for irradiation testing at the Idaho National Laboratory (INL) Advanced Test Reactor (ATR) under Pathway (2). The focus of the Advanced LWR Nuclear Fuels Pathway is to improve the scientific knowledge basis for understanding and predicting fundamental performance of advanced nuclear fuel and cladding in nuclear power plants during both nominal and off-nominal conditions. This information will be applied in the design and development of high-performance, high burn-up fuels with improved safety, cladding integrity, and improved nuclear fuel cycle economics

  4. Block Copolymer Electrolytes Synthesized by Atom Transfer Radical Polymerization for Solid-State, Thin-Film

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    Block Copolymer Electrolytes Synthesized by Atom Transfer Radical Polymerization for Solid, 2002. The ideal electrolyte material for a solid-state battery would have the ionic conductivity. To satisfy these rigorous performance requirements researchers have explored the design of solid electrolytes

  5. Ohio-Kentucky-Indiana Regional Council of Governments Solar Ready Construction Guidelines

    Broader source: Energy.gov [DOE]

    These voluntary guidelines are developed for the local governments of the OKI region to provide guidance for residential developers, home builders, and architects in the design and construction of new residential buildings. These guidelines are intended to guide a developer, architect, or other interested party through the components of building design required to prepare a building for future solar installation. These guidelines include best practices for solar-ready building design to minimize the costs of future solar installation while maximizing potential system efficiency and apply to site selection, building design, and building construction.

  6. Hydroxyl radical oxidation of phospholipid-coated NaCl particles.

    E-Print Network [OSTI]

    Dilbeck, Christopher W; Finlayson-Pitts, Barbara J

    2013-01-01

    Chem. Chem. Phys. , 2013, Hydroxyl radical oxidation ofsuch as ozone and hydroxyl (OH) radicals. Laboratory studiescalculated concentration of hydroxyl radicals, generated by

  7. NEAR DEGENERATE REARRANGEMENT BETWEEN THE RADICAL CATIONS OF FORMALDEHYDE AND HYDROXYMETHYLENE

    E-Print Network [OSTI]

    Osamura, Y.

    2010-01-01

    THE RADICAL CATIONS OF FORMALDEHYDE AND HYDROXYMETHYLENEthe Radical Cations of Formaldehyde and Hydroxymethylenethan the anticipated formaldehyde radical cation H CO+. This

  8. Free Radicals in Superfluid Liquid Helium Nanodroplets: A Pyrolysis Source for the Production of Propargyl Radical

    E-Print Network [OSTI]

    Küpper, J; Miller, R E; K\\"upper, Jochen; Merritt, Jeremy M.; Miller, Roger E.

    2002-01-01

    An effusive pyrolysis source is described for generating a continuous beam of radicals under conditions appropriate for the helium droplet pick-up method. Rotationally resolved spectra are reported for the $\

  9. New cyclisations of iminyl radicals generated by flash vacuum pyrolysis 

    E-Print Network [OSTI]

    Ieva, Maria

    2012-11-28

    The formation of iminyl radicals from a range of precursors, including hydrazone imines and oxime ethers, under FVP conditions is well documented in the literature.1 Once formed, the iminyl radical can undergo cyclisation ...

  10. Implementation plan for WRAP Module 1 operational readiness review

    SciTech Connect (OSTI)

    Irons, L.G.

    1994-11-04

    The Waste Receiving and Processing Module 1 (WRAP 1) will be used to receive, sample, treat, and ship contact-handled (CH) transuranic (TRU), low-level waste (LLW), and low-level mixed waste (LLMW) to storage and disposal sites both on the Hanford site and off-site. The primary mission of WRAP 1 is to characterize and certify CH waste in 55-gallon and 85-gallon drums; and its secondary function is to certify CH waste standard waste boxes (SWB) and boxes of similar size for disposal. The WRAP 1 will provide the capability for examination (including x-ray, visual, and contents sampling), limited treatment, repackaging, and certification of CH suspect-TRU waste in 55-gallon drums retrieved from storage, as well as newly generated CH LLW and CH TRU waste drums. The WRAP 1 will also provide examination (X-ray and visual only) and certification of CH LLW and CH TRU waste in small boxes. The decision to perform an Operational Readiness Review (ORR) was made in accordance with WHC-CM-5-34, Solid Waste Disposal Operations Administration, Section 1.4, Operational Readiness Activities. The ORR will ensure plant and equipment readiness, management and personnel readiness, and management programs readiness for the initial startup of the facility. This implementation plan is provided for defining the conduct of the WHC ORR.

  11. Hybrid radical energy storage device and method of making

    DOE Patents [OSTI]

    Gennett, Thomas; Ginley, David S; Braunecker, Wade; Ban, Chunmei; Owczarczyk, Zbyslaw

    2015-01-27

    Hybrid radical energy storage devices, such as batteries or electrochemical devices, and methods of use and making are disclosed. Also described herein are electrodes and electrolytes useful in energy storage devices, for example, radical polymer cathode materials and electrolytes for use in organic radical batteries.

  12. Footprinting proteinDNA complexes using the hydroxyl radical

    E-Print Network [OSTI]

    Tullius, Thomas D.

    Footprinting protein­DNA complexes using the hydroxyl radical Swapan S Jain & Thomas D Tullius.2008.72 Hydroxyl radical footprinting has been widely used for studying the structure of DNA and DNA­protein complexes. The high reactivity and lack of base specificity of the hydroxyl radical makes it an excellent

  13. DOE ZERH Webinar: Updates to the DOE Zero Energy Ready Home Specs- Rev05

    Broader source: Energy.gov [DOE]

    TitleUpdates to the DOE Zero Energy Ready Home Specs - Rev05DescriptionIn the year since DOE last updated the DOE Zero Energy Ready Home specs, we've continued to track our partner feedback and...

  14. Order Module--DOE O 425.1D, VERIFICATION OF READINESS TO START...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5.1D, VERIFICATION OF READINESS TO START UP OR RESTART NUCLEAR FACILITIES Order Module--DOE O 425.1D, VERIFICATION OF READINESS TO START UP OR RESTART NUCLEAR FACILITIES "The...

  15. Computer vs. Video Game System: Ready to Rumble in the #EnergyFaceoff...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer vs. Video Game System: Ready to Rumble in the EnergyFaceoff Jungle Computer vs. Video Game System: Ready to Rumble in the EnergyFaceoff Jungle November 4, 2014 - 10:20am...

  16. DOE Zero Energy Ready Home Case Study: BPC Green Builders, Danbury...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Danbury, CT DOE Zero Energy Ready Home Case Study: BPC Green Builders, Danbury, CT DOE Zero Energy Ready Home Case Study: BPC Green Builders, Danbury, CT Case study of a DOE Zero...

  17. DOE Zero Energy Ready Home Case Study: Carl Franklin Homes, L...

    Energy Savers [EERE]

    Zero Energy Ready Home Case Study: Carl Franklin Homes, L.C.Green Extreme Homes, CDC, McKinley Project, Garland TX DOE Zero Energy Ready Home Case Study: Carl Franklin Homes,...

  18. DOE Zero Energy Ready Home Case Study: BPC Green Builders, Danbury...

    Energy Savers [EERE]

    BPC Green Builders, Danbury, CT DOE Zero Energy Ready Home Case Study: BPC Green Builders, Danbury, CT DOE Zero Energy Ready Home Case Study: BPC Green Builders, Danbury, CT Case...

  19. What to Expect When Readying to Move Spent Nuclear Fuel from...

    Energy Savers [EERE]

    What to Expect When Readying to Move Spent Nuclear Fuel from Commercial Nuclear Power Plants What to Expect When Readying to Move Spent Nuclear Fuel from Commercial Nuclear Power...

  20. EMERGENCY READINESS ASSURANCE PLAN (ERAP) FOR FISCAL YEAR (FY) 2014

    SciTech Connect (OSTI)

    Bush, Shane

    2014-09-01

    This Emergency Readiness Assurance Plan (ERAP) for Fiscal Year (FY) 2014 in accordance with DOE O 151.1C, “Comprehensive Emergency Management System.” The ERAP documents the readiness of the INL Emergency Management Program using emergency response planning and preparedness activities as the basis. It describes emergency response planning and preparedness activities, and where applicable, summarizes and/or provides supporting information in tabular form for easy access to data. The ERAP also provides budget, personnel, and planning forecasts for FY-15. Specifically, the ERAP assures the Department of Energy Idaho Operations Office that stated emergency capabilities at INL are sufficient to implement PLN-114, “INL Emergency Plan/RCRA Contingency Plan.

  1. CCSI Technology Readiness Levels Likelihood Model (TRL-LM) User’s Guide

    SciTech Connect (OSTI)

    Engel, David W.; Dalton, Angela C.; Sivaramakrishnan, Chandrika; Lansing, Carina

    2013-03-26

    This is the manual for the Carbon Capture Simulation Initiative (CCSI) Technology Readiness Level Likelihood model based on PNNL velo.

  2. DOE Zero Energy Ready Home Case Study: Shore Road Project- Old Greenwich, Connecticut

    Broader source: Energy.gov [DOE]

    This case study describes the builder Murphy Brothers' first DOE Zero Energy Ready Home in Old Greenwich, CT.

  3. Text-Alternative Version: ENERGY STAR® for SSL: Getting Ready for September 30

    Office of Energy Efficiency and Renewable Energy (EERE)

    Below is the text-alternative version of the ENERGY STAR® for SSL: Getting Ready for September 30 webcast.

  4. Capture-Ready Power Plants -Options, Technologies and Economics Mark C. Bohm

    E-Print Network [OSTI]

    1 Capture-Ready Power Plants - Options, Technologies and Economics by Mark C. Bohm Bachelor and Policy Program #12;2 #12;3 Capture-ready Power Plants ­ Options, Technologies and Costs by Mark C. Bohm of a plant. Power plant owners and policymakers are interested in capture-ready plants because they may offer

  5. Mission and Readiness Assessment for Fusion Nuclear Facilities

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory 20th ANS Topical Meeting on the Technology of Fusion Energy Nashville, TN U.S.A. 28 August 2012 #12;Background and Motivation 2 · Increased attention to DEMO planning") ­ ReNeW 2009 ­ Technology Readiness Levels application (Tillack, et al., FS&T 2009) ­ FNS Pathways

  6. Creating a Professional Portfolio Ready ReferenceE-12

    E-Print Network [OSTI]

    Creating a Professional Portfolio Ready ReferenceE-12 College of Engineering, Architecture & Technology Career Services Portfolios aren't just for artists anymore. Long regarded as an essential job effort and time. The Low and High Tech Alternatives You may design a high tech or low tech portfolio

  7. Researching a Company Online Ready Reference D-13

    E-Print Network [OSTI]

    Researching a Company Online Ready Reference D-13 College of Engineering, Architecture & Technology information on over 50,000 public and private companies (www.hoovers.com). · CorpTech Database of High and private high-tech organizations (www.corptech.com). · Companies Online from Dun & Bradstreet and Lycos

  8. FEDERAL EMERGENCY MANAGEMENT AGENCY ARE YOU READY? 83

    E-Print Network [OSTI]

    Tullos, Desiree

    - rupted--electricity, telephone, natural gas, gasoline pumps, cash registers, ATM machines, and internetFEDERAL EMERGENCY MANAGEMENT AGENCY ARE YOU READY? 83 National Security Emergencies I n addition to the natural and tech- nological hazards described in this publication, Americans face threats posed by hostile

  9. TECHNICAL POLLUTION PREVENTION GUIDE FOR READY-MIXED CONCRETE OPERATIONS

    E-Print Network [OSTI]

    #12;TECHNICAL POLLUTION PREVENTION GUIDE FOR READY-MIXED CONCRETE OPERATIONS IN THE LOWER FRASER BASIN DOE FRAP 1997-13 Prepared for: Environment Canada Environmental Protection Fraser Pollution Action Plan through its Fraser Pollution Abatement Office. Environment Canada is not responsible

  10. U.S. Department of Energy Technology Readiness Assessment Guide

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2009-10-12

    This Guide assists individuals and teams involved in conducting Technology Readiness Assessments and developing Technology Maturation Plans for the DOE capital acquisition asset projects subject to DOE O 413.3A, Program and Project Management for the Acquisition of Capital Assets, dated 7-28-06. Canceled by DOE G 413.3-4A. Does not cancel other directives.

  11. Ready to eat breakfast cereals from food-grade sorghums 

    E-Print Network [OSTI]

    Cruz y Celis Ehlinger, Laura Penelope

    1993-01-01

    Two food-grade sorghum hybrids, ATx63 I *Tx436 (non waxy), and B.BON 34, (waxy), were micronized and evaluated for their potential use in ready to eat breakfast cereals (RTE-BC). Whole and decorticated grains were exposed to infra-red burners...

  12. IBM Watson Group Recruiting Event Ready to Work with Watson?

    E-Print Network [OSTI]

    IBM Watson Group Recruiting Event Ready to Work with Watson? Attend this session to learn about Watson opportunities INTERESTED YET? IBM is leading the real-world success of cognitive systems. Together and resources of IBM. Gates & Hillman 6115 LOCATION February, 18 2014 DATE 4PM - 7PM TIME WHO SHOULD ATTEND? 4

  13. Richard C. Ready Department of Agricultural Economics and Economics

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Richard C. Ready Department of Agricultural Economics and Economics Montana State University, University of Wisconsin, Madison: Agricultural Economics Major Field: Environmental and Resource Economics 2. M.A. - 1985, University of Wisconsin, Madison: Agricultural Economics 3. B.S - 1981, Cornell

  14. Energy Flow: A Multimodal `Ready' Indication For Electric Vehicles

    E-Print Network [OSTI]

    ]. The limited range of EVs implicates a new importance of information about stored energy, estimated rangeEnergy Flow: A Multimodal `Ready' Indication For Electric Vehicles Abstract The lack of sound compared to a conventional car with a combustion engine. Most EVs provide a visual feedback about

  15. NOAA's National Weather Service Building a Weather-Ready Nation

    E-Print Network [OSTI]

    NOAA's National Weather Service Building a Weather-Ready Nation For more information, please visit: www.noaa.gov and www.nws.noaa.gov NOAA's National Weather Service (NWS) is the Nation's official source for weather and water data, forecasts, and warnings. From information accessed on your smartphone

  16. DOE Zero Energy Ready Home Case Study: Greenhill Contracting...

    Broader source: Energy.gov (indexed) [DOE]

    a DOE Zero Energy Ready home in New Paltz, NY, that achieved a HERS score of 37 without PV or 7 with 7.5-kW PV. The two-story 2,288-ft2 home is one of 9 certified homes. All of...

  17. DOE Zero Energy Ready Home Case Study: John Hubert Associates...

    Broader source: Energy.gov (indexed) [DOE]

    of a DOE Zero Energy Ready home in North Cape May, NJ, that scored a HERS 46 without PV or HERS 9 with 6.5 kW of PV. The two-story, 1,871-ft2 home has advanced-framed...

  18. Key Facts About Hurricane Readiness Preparing for a Hurricane

    E-Print Network [OSTI]

    HURRICANES Key Facts About Hurricane Readiness Preparing for a Hurricane If you are under a hurricane watch or warning, here are some basic steps to take to prepare for the storm: · Learn about your. · Identify potential home hazards and know how to secure or protect them before the hurricane strikes

  19. Multiscale QM/MM Molecular Dynamics Study on the First Steps of Guanine-Damage by Free Hydroxyl Radicals in Solution

    E-Print Network [OSTI]

    Abolfath, Ramin M; Rajnarayanam, R; Brabec, Thomas; Kodym, Reinhard; Papiez, Lech

    2012-01-01

    Understanding the damage of DNA bases from hydrogen abstraction by free OH radicals is of particular importance to reveal the effect of hydroxyl radicals produced by the secondary effect of radiation. Previous studies address the problem with truncated DNA bases as ab-initio quantum simulation required to study such electronic spin dependent processes are computationally expensive. Here, for the first time, we employ a multiscale and hybrid Quantum-Mechanical-Molecular-Mechanical simulation to study the interaction of OH radicals with guanine-deoxyribose-phosphate DNA molecular unit in the presence of water where all the water molecules and the deoxyribose-phosphate fragment are treated with the simplistic classical Molecular-Mechanical scheme. Our result illustrates that the presence of water strongly alters the hydrogen-abstraction reaction as the hydrogen bonding of OH radicals with water restricts the relative orientation of the OH-radicals with respective to the the DNA base (here guanine). This results ...

  20. DOE Zero Energy Ready Home Case Study: Southern Energy Homes — First DOE Zero Energy Ready Manufactured Home, Russellville, AL

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This home is the first manufactured home built to the DOE Zero Energy Ready Home standard and won an Affordable Builder award in the 2014 Housing Innovations Awards. This manufactured home achieved a HERS score of 57 without photovoltaics and includes superior insulation and air sealing.

  1. U.S. Offshore Wind Port Readiness

    SciTech Connect (OSTI)

    C. Elkinton, A. Blatiak, H. Ameen

    2013-10-13

    This study will aid decision-makers in making informed decisions regarding the choice of ports for specific offshore projects, and the types of investments that would be required to make individual port facilities suitable to serve offshore wind manufacturing, installation and/or operations.

  2. Composite Organic Radical - Inorganic Hybrid Cathode for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Huang, Qian; Cosimbescu, Lelia; Koech, Phillip K.; Choi, Daiwon; Lemmon, John P.

    2013-07-01

    A new organic radical inorganic hybrid cathode comprised of PTMA/LiFePO4 composite system is developed and reported for the first time. The hybrid cathodes demonstrate high pulse power capability resulting in a significant improvement over the pure PTMA or LiFePO4 cathode which is very promising for transportation and other high pulse power applications that require long cycle life and lower cost.

  3. Radical Compatibility with Nonaqueous Electrolytes and Its Impact...

    Office of Scientific and Technical Information (OSTI)

    Compatibility with Nonaqueous Electrolytes and Its Impact on an All-Organic Redox Flow Battery Citation Details In-Document Search Title: Radical Compatibility with...

  4. An ultra-sensitive microfluidic immunoassay using living radical...

    Office of Scientific and Technical Information (OSTI)

    microfluidic immunoassay using living radical polymerization and porous polymer monoliths. Citation Details In-Document Search Title: An ultra-sensitive microfluidic...

  5. Microgrid-Ready Solar PV; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    2015-07-01

    Designing new solar projects to be 'microgrid-ready' enables the U.S. DoD, other federal agencies, and the private sector to plan future microgrid initiatives to utilize solar PV as a generating resource. This fact sheet provides background information with suggested language for several up-front considerations that can be added to a solar project procurement or request for proposal (RFP) that will help ensure that PV systems are built for future microgrid connection.

  6. Rough and Ready Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk, NewMichigan: EnergyRocklinRohmRoshniRotokawa Geothermaland Ready

  7. Taking the Challenge at Singer Village--A Cold Climate Zero Energy Ready Home

    SciTech Connect (OSTI)

    Puttagunta, S.; Gaakye, O.

    2014-10-01

    After progressively incorporating ENERGY STAR(R) for Homes Versions 1, 2, and 3 into its standard practices over the years, this builder, Brookside Development, was seeking to build an even more sustainable product that would further increase energy efficiency, while also addressing indoor air quality, water conservation, renewable-ready, and resiliency. These objectives align with the framework of the DOE Challenge Home program, which 'builds upon the comprehensive building science requirements of ENERGY STAR for Homes Version 3, along with proven Building America innovations and best practices. Other special attribute programs are incorporated to help builders reach unparalleled levels of performance with homes designed to last hundreds of years.' CARB partnered with Brookside Development on the design optimization and construction of the first home in a small development of seven planned new homes being built on the old Singer Estate in Derby, CT.

  8. Taking the Challenge at Singer Village — A Cold Climate Zero Energy Ready Home

    SciTech Connect (OSTI)

    Puttagunta, S.; Faakye, O.

    2014-10-01

    After progressively incorporating ENERGY STAR® for Homes Versions 1, 2, and 3 into its standard practices over the years, this builder, Brookside Development, was seeking to build an even more sustainable product that would further increase energy efficiency, while also addressing indoor air quality, water conservation, renewable-ready, and resiliency. These objectives align with the framework of the DOE Challenge Home program, which "builds upon the comprehensive building science requirements of ENERGY STAR for Homes Version 3, along with proven Building America innovations and best practices. Other special attribute programs are incorporated to help builders reach unparalleled levels of performance with homes designed to last hundreds of years." Consortium for Advanced Residential Buildings (CARB) partnered with Brookside Development on the design optimization and construction of the first home in a small development of seven planned new homes being built on the old Singer Estate in Derby, CT.

  9. Spectroscopy, Kinetics, and Dynamics of Combustion Radicals

    SciTech Connect (OSTI)

    Nesbitt, David J.

    2013-08-06

    Spectroscopy, kinetics and dynamics of jet cooled hydrocarbon transients relevant to the DOE combustion mission have been explored, exploiting i) high resolution IR lasers, ii) slit discharge sources for formation of jet cooled radicals, and iii) high sensitivity detection with direct laser absorption methods and near the quantum shot noise limit. What makes this combination powerful is that such transients can be made under high concentrations and pressures characteristic of actual combustion conditions, and yet with the resulting species rapidly cooled (T ?10-15K) in the slit supersonic expansion. Combined with the power of IR laser absorption methods, this provides novel access to spectral detection and study of many critical combustion species.

  10. Evidence of radicals created by plasma in bacteria in water

    SciTech Connect (OSTI)

    Lee, Chae Bok; Na, Young Ho; Hong, Tae-Eun; Choi, Eun Ha; Uhm, Han S.; Baik, Ku Youn E-mail: gckwon@kw.ac.kr; Kwon, Gichung E-mail: gckwon@kw.ac.kr

    2014-08-18

    Heavy water (D{sub 2}O) was introduced into a non-thermal plasma-jet (NTPJ) device to generate deuterium monoxide (OD) radicals at room temperature. Owing to the similar reactivity and low prevalence of deuterium in nature, OD radicals can be utilized to visualize the OH radical interactions with water and living cells. Escherichia coli in water were treated with OD radicals, and D atom incorporation into cells was visualized using time-of-flight SIMS and Nano-SIMS. The results show that D atoms from NTPJ reach the cytoplasm of E. coli in H{sub 2}O, indicating the usefulness of this OD-tracking method for the study of radical interactions with living cells.

  11. Large Enhancement in the Heterogeneous Oxidation Rate of Organic Aerosols by Hydroxyl Radicals in the Presence of Nitric Oxide.

    E-Print Network [OSTI]

    Richards-Henderson, NK; Goldstein, AH; Wilson, KR

    2015-01-01

    Heterogeneous Reaction of Hydroxyl Radicals with Sub-Micronof Organic Aerosols by Hydroxyl Radicals in the Presence ofin an aerosol exposed to hydroxyl radicals (OH) is thought

  12. Environment-induced anisotropy and the sensitivity of the radical pair mechanism in the avian compass

    E-Print Network [OSTI]

    Alejandro Carrillo; Marcio F. Cornelio; Marcos C. de Oliveira

    2015-08-07

    Several experiments over the years have shown that the Earth's magnetic field is essential for orientation in birds migration. The most promising explanation for this orientation is the photo-stimulated radical pair (RP) mechanism. In order to define a reference frame for the orientation task radicals must have an intrinsic anisotropy. We show that this kind of anisotropy, and consequently the entanglement in the model, are not necessary for the proper functioning of the compass. Classically correlated initial conditions for the RP, subjected to a fast decoherence process, are able to provide the anisotropy required. Even a dephasing environment can provide the necessary frame for the compass to work, and also implies fast decay of any quantum correlation in the system without damaging the orientation ability. This fact significantly expands the range of applicability of the RP mechanism providing more elements for experimental search.

  13. Quantitative Mapping of Protein Structure by Hydroxyl Radical Footprinting-Mediated Structural Mass Spectrometry: A Protection

    E-Print Network [OSTI]

    Yang, Sichun

    Article Quantitative Mapping of Protein Structure by Hydroxyl Radical Footprinting, Case Western Reserve University, Cleveland, Ohio ABSTRACT Measurements from hydroxyl radical features of a protein can be comprehensively probed by hydroxyl radical footprinting (HRF) mediated

  14. "To Hesitate is Cowardly": Radicalism and American Manhood, 1870-1920

    E-Print Network [OSTI]

    Anthony, Kyle David

    2011-04-19

    workers' manhood. Thus, radicals called on workers to accept their radical programs as a means of regenerating their manhood. In response, the political and industrial elite successfully rebuffed radicalism, in part, by positioning the masculinity...

  15. DOE Zero Energy Ready Home Low Load High Efficiency HVAC Webinar (Text Version)

    Broader source: Energy.gov [DOE]

    Below is the text version of the DOE Zero Energy Ready Home webinar, Low Load High Efficiency HVAC, presented in May 2014.

  16. How do I Apply for Graduate School...? Ready Reference D-18

    E-Print Network [OSTI]

    & Technology Career Services Oklahoma State University College of Engineering, Architecture & TechnologyHow do I Apply for Graduate School...? Ready Reference D-18 College of Engineering, Architecture

  17. Zero Energy-Ready Single-Family Homes - Building America Top...

    Broader source: Energy.gov (indexed) [DOE]

    program, the Challenge Home (now Zero Energy Ready Home) program. This Top Innovation highlights Building America research teams who have worked directly with builders to...

  18. Marketing and Sales Solutions for Zero Energy Ready Homes Webinar (Text Version)

    Broader source: Energy.gov [DOE]

    Below is the text version of the webinar, Marketing and Sales Solutions for Zero Energy Ready Homes, presented in June 2014.

  19. HIA 2015 DOE Zero Energy Ready Home Case Study: Hammer and Hand...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    eerebuildingszero-energy-ready-home PNNL-SA-113527, September 2015 One minisplit heat pump provides all of the heating and cooling the highly efficient home needs. While...

  20. DOE ZERH Webinar: Updates to the DOE Zero Energy Ready Home Specs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    presented in May 2015. Watch the presentation. Lindsay Parker: Presentation cover slide: Hi, everyone. Welcome to the Department of Energy Zero Energy Ready Home Technical Training...

  1. Capturing Value in a Global Innovation Network: A Comparison of Radical and Incremental Innovation

    E-Print Network [OSTI]

    Dedrick, Jason; Kraemer, Kenneth L; Linden, Greg

    2007-01-01

    innovation Radical product innovation (Utterback, 1990) hasredefine a product category Incremental innovation - EarlyRadical innovation Opportunity - New product category - New

  2. Fine-tuning robot-assisted radical prostatectomy planning with MRI

    E-Print Network [OSTI]

    2013-01-01

    article Fine—tuning robot-assisted radical prostatectomyimaging in performing robot—assisted laparoscopic radicalleakage rates after robot—assisted radical prostatectomy.

  3. Reform or Radicalism: Left Social Movements from the Battle of Seattle to Occupy Wall Street

    E-Print Network [OSTI]

    Rowe, James K; Carroll, Myles

    2014-01-01

    abstract antipathy towards ‘tepid reform’ and ‘unrealisticReform or Radicalism: Left Social Movements from the Battledynamism between radical and reform wings drove gains. This

  4. Vacuum ultraviolet photoionization and photodissociation of polyatomic molecules and radicals

    SciTech Connect (OSTI)

    Ng, C.Y. [Iowa State Univ., Ames (United States)

    1993-12-01

    In the past decade, tremendous progress has been made in understanding the photodissociation (PD) dynamics of triatomic molecules. However, the PD study of radicals, especially polyatomic radicals, has remained essentially an unexplored research area. Detailed state-to-state PD cross sections for radicals in the UV and VUV provide challenges not only for dynamical calculations, but also for ab initio quantum chemical studies. The authors have developed a laser based pump-probe apparatus for the measurement of absolute PD cross sections for CH{sub 3}S and HS is summarized.

  5. Transverse flow reactor studies of the dynamics of radical reactions

    SciTech Connect (OSTI)

    Macdonald, R.G. [Argonne National Laboratory, IL (United States)

    1993-12-01

    Radical reactions are in important in combustion chemistry; however, little state-specific information is available for these reactions. A new apparatus has been constructed to measure the dynamics of radical reactions. The unique feature of this apparatus is a transverse flow reactor in which an atom or radical of known concentration will be produced by pulsed laser photolysis of an appropriate precursor molecule. The time dependence of individual quantum states or products and/or reactants will be followed by rapid infrared laser absorption spectroscopy. The reaction H + O{sub 2} {yields} OH + O will be studied.

  6. El Salvador-Climate Finance Readiness Programme | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:of theClimate Finance Readiness Programme Jump to:

  7. EECBG Success Story: LEDs Ready for Takeoff at Louisiana Airport |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of EnergyDepartment ofDepartment of Energy LEDs Ready

  8. Zero Energy Ready Home Update Newsletter | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About1996HowFOAShowingFuelWeatherize »EvePlantEnergy YuccaZero Energy Ready

  9. DOE Zero Energy Ready Home Resources | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electricLaboratory | DepartmentDOE Zero Energy Ready Home provides

  10. Crossed-beam studies of the dynamics of radical reactions

    SciTech Connect (OSTI)

    Liu, K. [Argonne National Laboratory, IL (United States)

    1993-12-01

    The objective of this program is to characterize the detailed dynamics of elementary radical reactions and to provide a better understanding of radical reactivity in general. The radical beam is typically generated by a laser photolysis method. After colliding with the reacting molecule in a crossed-beam apparatus, the reaction product state distribution is interrogated by laser spectroscopic techniques. Several radicals of combustion significance, such as O, CH, OH, CN and NCO have been successfully generated and their collisional behavior at the state-to-state integral cross section level of detail has been studied in this manner. During the past year, the detection system has been converted from LIF to REMPI schemes, and the emphasis of this program shifted to investigate the product angular distributions. Both inelastic and reactive processes have been studied.

  11. Open-air preaching as radical street performance 

    E-Print Network [OSTI]

    Blythe, Stuart McLeod

    2009-11-26

    In this thesis I examine the ways in which analysing open-air preaching as ‘radical street performance’ can inform our understanding of this expression of Christian preaching. Open-air preaching is commonly associated ...

  12. Hezbollah and Hugo Chavez: Radical Islam's Western Foothold

    E-Print Network [OSTI]

    Pickell, Samuel Vernon

    2010-04-02

    In recent years reports have appeared in government publications and the media alleging that the close relationship between Iran and Venezuela has resulted in the flourishing of radical Islamic groups like Hezbollah within Venezuela. This paper...

  13. Kinetic studies of isoprene reactions with hydroxyl and chlorine radicals 

    E-Print Network [OSTI]

    Suh, Inseon

    2000-01-01

    Kinetic studies of the isoprene oxidation reactions initiated by the hydroxyl radical OH and the chlorine atom Cl have been investigated using a fast-flow reactor in conjunction with chemical ionization mass spectrometry (CIMS) and using laser...

  14. Radical and open innovation : the challenge for established firms

    E-Print Network [OSTI]

    Leroy, Charlotte, S.M. Massachusetts Institute of Technology

    2014-01-01

    Past research has shown that breakthrough innovations are often prevalent in the context of entrants rather than incumbents. There are many challenges associated with radical and open innovation initiatives for established ...

  15. Hispanic Preschoolers' School Readiness: A Study Examining the Impact of Cultural, Social-Emotional, and Sociodemographic Factors 

    E-Print Network [OSTI]

    Avila Brizuela, Leonor

    2012-02-14

    of the literature by examining factors that impact school readiness among Hispanic preschoolers. The goal of this study was to determine the extent to which cultural variables can predict school readiness and social-emotional competence, above and beyond...

  16. Building America Top Innovations 2013 Profile – Zero Energy-Ready Single-Family Homes

    SciTech Connect (OSTI)

    none,

    2013-09-01

    Building homes that are zero energy-ready is a goal of the U.S. Department of Energy’s Building America program and one embodied in Building America’s premier home certification program, the Challenge Home program. This case study describes several examples of successful zero energy-ready home projects completed by Building America teams and partner builders.

  17. Weed Management Costs, Weed Best Management Practices, and The Roundup Ready Weed Management Program

    E-Print Network [OSTI]

    Mitchell, Paul D.

    Weed Management Costs, Weed Best Management Practices, and The Roundup Ready® Weed Management-commercial purposes by any means, provide that this copyright notice appears on all such copies. #12;1 Weed Management Costs, Weed Best Management Practices, and The Roundup Ready® Weed Management Program T.M. Hurley

  18. Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options

    E-Print Network [OSTI]

    Aickelin, Uwe

    Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options Xi Liang, Jia Li, Jon Gibbons and David Reiner December 2007 EPRG 0728 & CWPE 0761 #12;FINANCING CAPTURE READY COAL supercritical pulverized coal power plant in China, using a cash flow model with Monte-Carlo simulations

  19. `Capture ready' regulation of fossil fuel power plants Betting the UK's carbon emissions on promises of future technology

    E-Print Network [OSTI]

    Haszeldine, Stuart

    power stations licensed in 2009 have had to set off land adjacent to the power plant as a capture ready`Capture ready' regulation of fossil fuel power plants ­ Betting the UK's carbon emissions interest in investing in new fossil fuelled power plants. The question is whether capture ready policy can

  20. Social Media: Weather-Ready Wednesday Please help the NWS spread these important safety messages on social media! Everyone is

    E-Print Network [OSTI]

    Social Media: Weather-Ready Wednesday #WRW Please help the NWS spread these important safety build a WeatherReady Nation. WeatherReady Wednesday is a National Weather Service initiative to help spread weather safety messages each week. Each week you can pick a different topic to share. It can

  1. Kinetic and mechanistic studies of free-radical reactions in combustion

    SciTech Connect (OSTI)

    Tully, F.P. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01

    Combustion is driven by energy-releasing chemical reactions. Free radicals that participate in chain reactions carry the combustion process from reactants to products. Research in chemical kinetics enables us to understand the microscopic mechanisms involved in individual chemical reactions as well as to determine the rates at which they proceed. Both types of information are required for an understanding of how flames burn, why engines knock, how to minimize the production of pollutants, and many other important questions in combustion. In this program the authors emphasize accurate measurements over wide temperature ranges of the rates at which ubiquitous free radicals react with stable molecules. The authors investigate a variety of OH, CN, and CH + stable molecule reactions important to fuel conversion, emphasizing application of the extraordinarily precise technique of laser photolysis/continuous-wave laser-induced fluorescence (LP/cwLIF). This precision enables kinetic measurements to serve as mechanistic probes. Since considerable effort is required to study each individual reaction, prudent selection is critical. Two factors encourage selection of a specific reaction: (1) the rates and mechanisms of the subject reaction are required input to a combustion model; and (2) the reaction is a chemical prototype which, upon characterization, will provide fundamental insight into chemical reactivity, facilitate estimation of kinetic parameters for similar reactions, and constrain and test the computational limits of reaction-rate theory. Most studies performed in this project satisfy both conditions.

  2. Are the Radical Centers in Peptide Radical Cations Mobile? The Generation, Tautomerism, and Dissociation of Isomeric ?-Carbon-Centered Triglycine Radical Cations in the Gas Phase

    SciTech Connect (OSTI)

    Chu, Ivan K.; Zhao, Junfang; Xu, Minjie; Siu, Shiu On; Hopkinson, Alan C.; Siu , K W Michael

    2008-05-31

    The mobility of the radical center in three isomeric triglycine radical cationss[G•GG]+, [GG•G]+, and [GGG•]+shas been investigated theoretically via density functional theory (DFT) and experimentally via tandem mass spectrometry. These radical cations were generated by collision-induced dissociations (CIDs) of Cu(II)-containing ternary complexes that contain the tripeptides YGG, GYG, and GGY, respectively (G and Y are the glycine and tyrosine residues, respectively). Dissociative electron transfer within the complexes led to observation of [Y•GG]+, [GY•G]+, and [GGY•]+; CID resulted in cleavage of the tyrosine side chain as p-quinomethide, yielding [G•GG]+, [GG•G]+, and [GGG•]+, respectively. Interconversions between these isomeric triglycine radical cations have relatively high barriers (g44.7 kcal/mol), in support of the thesis that isomerically pure [G•GG]+, [GG•G]+, and [GGG•]+ can be experimentally produced. This is to be contrasted with barriers < 17 kcal/mol that were encountered in the tautomerism of protonated triglycine [Rodriquez C. F. et al. J. Am. Chem. Soc. 2001, 123, 3006-3012]. The CID spectra of [G•GG]+, [GG•G]+, and [GGG•]+ were substantially different, providing experimental proof that initially these ions have distinct structures. DFT calculations showed that direct dissociations are competitive with interconversions followed by dissociation.

  3. Carbon Characterization Laboratory Readiness to Receive Irradiated Graphite Samples

    SciTech Connect (OSTI)

    Karen A. Moore

    2011-05-01

    The Carbon Characterization Laboratory (CCL) is located in Labs C19 and C20 of the Idaho National Laboratory Research Center. The CCL was established under the Next Generation Nuclear Plant Project to support graphite and ceramic composite research and development activities. The research conducted in this laboratory will support the Advanced Graphite Creep experiments—a major series of material irradiation experiments within the Next Generation Nuclear Plant Graphite program. The CCL is designed to characterize and test low activated irradiated materials such as high purity graphite, carbon-carbon composites, silicon-carbide composite, and ceramic materials. The laboratory is fully capable of characterizing material properties for both irradiated and nonirradiated materials. Major infrastructural modifications were undertaken to support this new radiological facility at Idaho National Laboratory. Facility modifications are complete, equipment has been installed, radiological controls and operating procedures have been established and work management documents have been created to place the CCL in readiness to receive irradiated graphite samples.

  4. DOE ZERH Webinar: Updates to the DOE Zero Energy Ready Home Specs-- Revision 05

    Broader source: Energy.gov [DOE]

    In the year since DOE last updated the DOE Zero Energy Ready Home specs, we've continued to track our partner feedback and other industry issues. This brings us to the release of Revision 05, which changes the solar hot water ready provisions to "recommended", incorporates a phase-in period for the new ENERGY STAR window specs, and spells out how the program works in states where the 2012 IECC is in place. This one-hour webinar will cover the key changes in the DOE Zero Energy Ready Homes specs and explain their significance to our builder, rater, and designer partners.

  5. Operational readiness review for the Waste Experimental Reduction Facility. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    An Operational Readiness Review (ORR) at the Idaho National Engineering Laboratory`s (INEL`s) Waste Experimental Reduction Facility (WERF) was conducted by EG&G Idaho, Inc., to verify the readiness of WERF to resume operations following a shutdown and modification period of more than two years. It is the conclusion of the ORR Team that, pending satisfactory resolution of all pre-startup findings, WERF has achieved readiness to resume unrestricted operations within the approved safety basis. ORR appraisal forms are included in this report.

  6. Detailed Studies of Hydrocarbon Radicals: C2H Dissociation

    SciTech Connect (OSTI)

    Wittig, Curt

    2014-10-06

    A novel experimental technique was examined whose goal was the ejection of radical species into the gas phase from a platform (film) of cold non-reactive material. The underlying principle was one of photo-initiated heat release in a stratum that lies below a layer of CO2 or a layer of amorphous solid water (ASW) and CO2. A molecular precursor to the radical species of interest is deposited near or on the film's surface, where it can be photo-dissociated. It proved unfeasible to avoid the rampant formation of fissures, as opposed to large "flakes." This led to many interesting results, but resulted in our aborting the scheme as a means of launching cold C2H radical into the gas phase. A journal article resulted that is germane to astrophysics but not combustion chemistry.

  7. Kinetics for Tautomerizations and Dissociations of Triglycine Radical Cations

    SciTech Connect (OSTI)

    Siu, Chi-Kit; Zhao, Junfang; Laskin, Julia; Chu, Ivan K.; Hopkinson, Alan C.; Siu , K W Michael

    2009-06-01

    Fragmentations of tautomers of the ?-centered radical triglycine radical cation, [GGG*]+, [GG*G]+, and [G*GG]+, are charge-driven, giving b-type ions; these are processes that are facilitated by a mobile proton, as in the fragmentation of protonated triglycine (Rodriquez, C.F. et al. J. Am. Chem. Soc. 2001, 123, 3006 - 3012). By contrast, radical centers are less mobile. Two mechanisms have been examined theoretically utilizing density functional theory and Rice-Ramsperger-Kassel-Marcus modeling: (1) a direct hydrogen-atom migration between two ?-carbons, and (2) a two-step proton migration involving a canonical [GGG]*+ as an intermediate. Predictions employing the latter mechanism are in good agreement with results of recent CID experiments (Chu, I.K. et al. J. Am. Chem. Soc. 2008, 130, 7862 - 7872).

  8. Infrared absorption spectroscopy and chemical kinetics of free radicals

    SciTech Connect (OSTI)

    Curl, R.F.; Glass, G.P. [Rice Univ., Houston, TX (United States)

    1993-12-01

    This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

  9. Transnational Islamic activism and radicalization : patterns, trends, and prognosticators.

    SciTech Connect (OSTI)

    Colbaugh, Richard; Engi, Dennis; LaViolette, Randall A.; Spomer, Judith E.

    2010-06-01

    The research described in this report developed the theoretical and conceptual framework for understanding, recognizing, and anticipating the origins, dynamic mechanisms, perceptions, and social structures of Islamic social reform movements in the Muslim homeland and in diaspora communities. This research has revealed valuable insights into the dynamic mechanisms associated with reform movements and, as such, offers the potential to provide indications and warnings of impending violence. This study produced the following significant findings: (1) A framework for understanding Islamic radicalization in the context of Social Movement Theory was developed and implemented. This framework provides a causal structure for the interrelationships among the myriad features of a social movement. (2) The degree to which movement-related activity shows early diffusion across multiple social contexts is a powerful distinguisher of successful and unsuccessful social movements. Indeed, this measurable appears to have significantly more predictive power than volume of such activity and also more power than various system intrinsics. (3) Significant social movements can occur only if both the intra-context 'infectivity' of the movement exceeds a certain threshold and the inter-context interactions associated with the movement occur with a frequency that is larger than another threshold. Note that this is reminiscent of, and significantly extends, well-known results for epidemic thresholds in disease propagation models. (4) More in-depth content analysis of blogs through the lens of Argumentation Theory has the potential to reveal new insights into radicalization in the context of Social Movement Theory. This connection has the potential to be of value from two important perspectives - first, this connection has the potential to provide more in depth insights into the forces underlying the emergence of radical behavior and second, this connection may provide insights into how to use the blogosphere to influence the emergent dialog to effectively impact the resulting actions taken by the potential radicals. The authors of this report recognize that Islamic communities are not the only source of radicalism; indeed many other groups, religious and otherwise, have used and continue to use, radicalism to achieve their ends. Further, the authors also recognize that not all Muslims use, or condone the use of, radical behavior. Indeed, only a very small segment of the Muslim communities throughout the world use and/or support such behavior. Nevertheless, the focus of this research is, indeed, on understanding, recognizing, and anticipating the origins, dynamic mechanisms, perceptions, and social structures of Islamic radicalism.

  10. Tool Helps Utilities Assess Readiness for Electric Vehicle Charging (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    NREL research helps answer a fundamental question regarding electric vehicles: Is the grid ready to handle them? Environmental, economic and security concerns regarding oil consumption make electrifying the transportation sector a high national priority. NREL's Center for Transportation Technologies & Systems (CTTS) has developed a framework for utilities to evaluate the plug-in vehicle (PEV) readiness of distribution transformers. Combining a wealth of vehicle performance statistics with load data from partner utilities including the Hawaiian Electric Company and Xcel Energy, NREL analyzed the thermal loading characteristics of distribution transformers due to vehicle charging. After running millions of simulations replicating varying climates and conditions, NREL is now able to predict aging rates for transformers when PEVs are added to existing building loads. With the NREL tool, users define simulation parameters by inputting vehicle trip and weather data; transformer load profiles and ratings; PEV penetration, charging rates and battery sizes; utility rates; the number of houses on each transformer; and public charging availability. Transformer load profiles, drive cycles, and ambient temperature data are then run through the thermal model to produce a one-year timeseries of the hotspot temperature. Annual temperature durations are calculated to help determine the annual aging rate. Annual aging rate results are grouped by independent variables. The most useful measure is transformer mileage, a measure of how many electrically-driven miles must be supplied by the transformer. Once the spectrum analysis has been conducted for an area or utility, the outputs can be used to help determine if more detailed evaluation is necessary, or if transformer replacement is required. In the majority of scenarios, transformers have enough excess capacity to charge PEVs. Only in extreme cases does vehicle charging have negative long-term impact on transformers. In those cases, upgrades to larger transformers would be recommended. NREL analysis also showed opportunity for newly-installed smart grids to offset distribution demands by time-shifting the charging loads. Most importantly, the model demonstrated synergies between PEVs and distributed renewables, not only providing clean renewable energy for vehicles, but also reducing demand on the entire distribution infrastructure by supplying loads at the point of consumption.

  11. Are Batteries Ready for Plug-in Hybrid Buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Kurani, Kenneth S; Burke, Andy

    2009-01-01

    PHEV from which those battery requirements flow. The circlesbattery technologies do not meet the requirements that flowflow from them. In summary, policymakers, automakers, battery

  12. Are batteries ready for plug-in hybrid buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Kurani, Kenneth S.; Burke, Andrew

    2008-01-01

    PHEV from which those battery requirements flow. The circlesbattery technologies do not meet the requirements that flowflow from them. In summary, policymakers, automakers, battery

  13. U.S. Department of Energy Zero Energy Ready Home? LENDER PARTNER...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Zero Energy Ready Home(tm) LENDER PARTNER AGREEMENT This agreement is administered by the U.S. Department of Energy (DOE) in support of DOE Zero Energy...

  14. DOE Zero Energy Ready Home Case Study: Shore Road Project - Old...

    Energy Savers [EERE]

    ventilator. The house has a dual-fuel heat pump, an instantaneous condensing water heater, and 4.5-kW solar shingles. DOE Zero Energy Ready Home: Murphy Brothers Contracting,...

  15. Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options

    E-Print Network [OSTI]

    Liang, Xi; Reiner, David; Gibbons, Jon; Li, Jia

    investors diversify risk, and offer global warming investors an alternative investment opportunity. As a detailed case study, we assess the value of a Capture Option and Capture Ready plant for a 600 MW supercritical pulverized coal power plant in China...

  16. DOE Zero Energy Ready Home Case Study: New Town Builders, Denver...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ready Home in Denver, CO, that scored HERS 41 without PV, HERS 3 with PV. This 3,560-square-foot production home has R-36 double-stud walls, a vented attic with R-50 blown...

  17. DOE Zero Energy Ready Home Case Study: Ferguson Design and Constructio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zero Energy Ready Home in Long Island, NY, that scored HERS 43 without PV. This 5,088-square-foot custom home has R-25 double-stud walls, a vaulted roof with R-40 blown cellulose,...

  18. Influence of Agricultural Dual Credit on Student College Readiness Self-Efficacy 

    E-Print Network [OSTI]

    Neely, Alanna L.

    2013-07-12

    The purpose of this correlational and descriptive study was to examine the influence of an agricultural dual credit course curriculum on student self-efficacy of college readiness as students matriculate to post-secondary education. To evaluate...

  19. DOE Zero Energy Ready Home Case Study: StreetScape Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    foam, R-49 open-cell spray-foam sealed attic, an HRV, and a tankless water heater for hydro coil furnace with high-velocity, small-diameter ducts. BAZeroEnergyReadyStreetScape...

  20. DOE Zero Energy Ready Home Case Study: StreetScape Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    open-cell spray-foam sealed attic, an HRV, and a tankless water heater for hydro coil furnace with high-velocity, small-diameter ducts. BAZeroEnergyReadyStreetScape062414.pdf...

  1. Application of the cumulative risk model in predicting school readiness in Head Start children 

    E-Print Network [OSTI]

    Rodriguez-Escobar, Olga Lydia

    2009-05-15

    This study investigates the degree to which the cumulative risk index predicted school readiness in a Head Start population. In general, the reviewed studies indicated the cumulative risk model was efficacious in predicting adverse developmental...

  2. HIA 2015 DOE Zero Energy Ready Home Case Study: Greenhill Contracting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Green Acres 20, 26, 28 New Paltz, NY DOE ZERO ENERGY READY HOME(tm) The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of...

  3. DOE Zero Energy Ready Home Case Study: BPC Green Builders, Taft...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Taft School, Watertown, CT DOE Zero Energy Ready Home Case Study: BPC Green Builders, Taft School, Watertown, CT Case study of a DOE 2015 Housing Innovation Award winning custom...

  4. HIA 2015 DOE Zero Energy Ready Home Case Study: Carl Franklin...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Franklin Homes, L.C. Green Extreme Homes, CDC McKinley Project Garland, TX DOE ZERO ENERGY READY HOME(tm) The U.S. Department of Energy invites home builders across the country to...

  5. DOE Tour of Zero: The First DOE Zero Energy Ready Retrofit by...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    by Green Extreme Homes and Carl Franklin Homes DOE Tour of Zero: The First DOE Zero Energy Ready Retrofit by Green Extreme Homes and Carl Franklin Homes Addthis 1 of 11 Green...

  6. DOE Zero Energy Ready Home Case Study: BPC Green Builders, Custom...

    Energy Savers [EERE]

    Study: BPC Green Builders, Custom Home, New Fairfield, CT DOE Zero Energy Ready Home Case Study: BPC Green Builders, Custom Home, New Fairfield, CT Case study of a DOE Zero Energy...

  7. DOE Zero Energy Ready Home Case Study: Amerisips Homes — Miller-Bloch Residence, Johns Island, SC

    SciTech Connect (OSTI)

    none,

    2014-09-01

    For this DOE Zero Energy Ready Home that won a Custom Builder award in the 2014 Housing Innovation Awards, the builder uses structural insulated panels to construct the entire building shell, including the roof, walls, and floor of the home.

  8. DOE ZERH Webinar: Technical Resources for Marketing and Selling Zero Energy Ready Homes

    Broader source: Energy.gov [DOE]

    Plan review… energy modeling… field inspections… certification…done!  Right?  If only it were that simple to successfully transition to Zero Energy Ready Homes.  The reality is that there’s a lot...

  9. DOE Zero Energy Ready Home Case Study: Palo Duro Homes, Via del...

    Energy Savers [EERE]

    and R-5rigid foam at slab edge; vented attic with R-75 blown fiberglass; ducted minisplit heat pump 16.5 SEER, 9.5 HSPF. DOE Zero Energy Ready Home Case Study: Palo Duro Homes,...

  10. DOE Zero Energy Ready Home Case Study: Hammer and Hand, Pumpkin...

    Energy Savers [EERE]

    with R-29 rigid EPS foam under slab; vented attic with R-86 blown cellulose; minisplit heat pump; ducted with HRV; 15.5 SEER; 10 HSPF. DOE Zero Energy Ready Home Case Study:...

  11. DOE Zero Energy Ready Home Case Study: Habitat for Humanity South...

    Energy Savers [EERE]

    on interior walls; R-20 ocsf in roof of sealed attic, uninsulated slab, 15 SEER 8.0 HSPF heat pump walls for heating and cooling, heat pump water heater. DOE Zero Energy Ready...

  12. User readiness to interact with information systems - a human activity perspective 

    E-Print Network [OSTI]

    Sun, Jun

    2006-10-30

    This study focuses on how and why people become ready to interact with certain information systems (IS) based on their previous experiences with the same and/or similar systems. User-system interaction can be regarded as ...

  13. Envisioning a Bright Future for New Braunfels Children: A Community-Based Approach to School Readiness 

    E-Print Network [OSTI]

    Fanomezantsoa, Herilala; Hopkins, Elizabeth; Tooley, Kathryn

    2015-05-20

    Consulting Capstone Group (MCCG) mission was to provide the McKenna Foundation with informed recommendations regarding school readiness, so that they could effectively serve and advance the well-being of the New Braunfels community....

  14. DOE Zero Energy Ready Home Case Study: Clifton View Homes, Marine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Marine Drive and Port Hadlcok, Coupeville and Port Hadlock WA DOE Zero Energy Ready Home Case Study: Clifton View Homes, Marine Drive and Port Hadlcok, Coupeville and Port Hadlock...

  15. DOE Zero Energy Ready Home Case Study: e2 Homes, Winter Park...

    Energy Savers [EERE]

    study of a DOE Zero Energy Ready Home in Winter Park, FL, that scored HERS 57 without PV or HERS -7 with PV. This 4,305-square-foot custom home has autoclaved aerated concrete...

  16. Development of a culturally appropriate process for assessing distance learning readiness in Latin America 

    E-Print Network [OSTI]

    Villalobos Peñ alosa, Patricia

    2009-05-15

    The purpose of this study was to develop an instrument for assessing distance learning readiness of institutions in Latin America for international projects of food and agriculture with higher education institutions in the ...

  17. Savannah River Site Tank 48H Waste Treatment Project Technology Readiness Assessment

    SciTech Connect (OSTI)

    Harmon, H.D.; Young, J.K.; Berkowitz, J.B.; DeVine, Jr.J.C.; Sutter, H.G.

    2008-07-01

    One of U.S. Department of Energy's (DOE) primary missions at Savannah River Site (SRS) is to retrieve and treat the high level waste (HLW) remaining in SRS tanks and close the F and H tank farms. At present, a significant impediment to timely completion of this mission is the presence of significant organic chemical contamination in Tank 48H. Tank 48H is a 1.3 million gallon tank with full secondary containment, located and interconnected within the SRS tank system. However, the tank has been isolated from the system and unavailable for use since 1983, because its contents - approximately 250,000 gallons of salt solution containing Cs-137 and other radioisotopes - are contaminated with nearly 22,000 Kg of tetraphenylborate, a material which can release benzene vapor to the tank head space in potentially flammable concentrations. An important element of the DOE SRS mission is to remove, process, and dispose of the contents of Tank 48H, both to eliminate the hazard it presents to the SRS H-Tank Farm and to return Tank 48H to service. Tank 48H must be returned to service to support operation of the Salt Waste Processing Facility, to free up HLW tank space, and to allow orderly tank closures per Federal Facility Agreement commitments. The Washington Savannah River Company (WSRC), the SRS prime contractor, has evaluated alternatives and selected two processes, Wet Air Oxidation (WAO) and Fluidized Steam Bed Reforming (FBSR) as candidates for Tank 48H processing. Over the past year, WSRC has been testing and evaluating these two processes, and DOE is nearing a final technology selection in late 2007. In parallel with WSRC's ongoing work, DOE convened a team of independent qualified experts to conduct a Technology Readiness Assessment (TRA). The purpose of the TRA was to determine the maturity level of the Tank 48H treatment technology candidates - WAO and FBSR. The methodology used for this TRA is based on detailed guidance for conducting TRAs contained in the Department of Defense (DoD), Technology Readiness Assessment Desk-book. The TRA consists of three parts: - Determination of the Critical Technology Elements (CTEs) for each of the candidate processes. - Evaluation of the Technology Readiness Levels (TRLs) of each CTE for each process. - Defining of the technology testing or engineering work necessary to bring immature technologies to the appropriate maturity levels. The TRA methodology assigns a TRL to a technology based on the lowest TRL assigned to any CTE of that technology. Based on the assessment, the overall TRL for WAO was 2 and the TRL for FBSR was 3. WAO was limited by the current lack of definition for the off-gas treatment system (TRL of 2). The FBSR Product Handling had little or no test work and therefore received the lowest score (TRL of 3) for the FBSR CTEs. In summary, both FBSR and WAO appear to be viable technologies for treatment of Tank 48H legacy waste. FBSR has a higher degree of maturity than WAO, but additional technology development will be required for both technologies. However, the Assessment Team believes that sufficient information is available for DOE to select the preferred or primary technology. Limited testing of the backup technology should be conducted as a risk mitigation strategy. (authors)

  18. SAVANNAH RIVER SITE TANK 48H WASTE TREATMENT PROJECT TECHNOLOGY READINESS ASSESSMENT

    SciTech Connect (OSTI)

    Harmon, Harry D.; Young, Joan K.; Berkowitz, Joan B.; Devine, John C.; Sutter, Herbert G.

    2008-10-25

    ABSTRACT One of U.S. Department of Energy’s (DOE) primary missions at Savannah River Site (SRS) is to retrieve and treat the high level waste (HLW) remaining in SRS tanks and close the F&H tank farms. At present, a significant impediment to timely completion of this mission is the presence of significant organic chemical contamination in Tank 48H. Tank 48H is a 1.3 million gallon tank with full secondary containment, located and interconnected within the SRS tank system. However, the tank has been isolated from the system and unavailable for use since 1983, because its contents – approximately 250,000 gallons of salt solution containing Cs-137 and other radioisotopes – are contaminated with nearly 22,000 Kg of tetraphenylborate, a material which can release benzene vapor to the tank head space in potentially flammable concentrations. An important element of the DOE SRS mission is to remove, process, and dispose of the contents of Tank 48H, both to eliminate the hazard it presents to the SRS H-Tank Farm and to return Tank 48H to service. Tank 48H must be returned to service to support operation of the Salt Waste Processing Facility, to free up HLW tank space, and to allow orderly tank closures per Federal Facility Agreement commitments. The Washington Savannah River Company (WSRC), the SRS prime contractor, has evaluated alternatives and selected two processes, Wet Air Oxidation (WAO) and Fluidized Steam Bed Reforming (FBSR) as candidates for Tank 48H processing. Over the past year, WSRC has been testing and evaluating these two processes, and DOE is nearing a final technology selection in late 2007. In parallel with WSRC’s ongoing work, DOE convened a team of independent qualified experts to conduct a Technology Readiness Assessment (TRA). The purpose of the TRA was to determine the maturity level of the Tank 48H treatment technology candidates – WAO and FBSR. The methodology used for this TRA is based on detailed guidance for conducting TRAs contained in the Department of Defense (DoD), Technology Readiness Assessment Deskbook. The TRA consists of three parts: • Determination of the Critical Technology Elements (CTEs) for each of the candidate processes. • Evaluation of the Technology Readiness Levels (TRLs) of each CTE for each process. • Defining of the technology testing or engineering work necessary to bring immature technologies to the appropriate maturity levels. The TRA methodology assigns a TRL to a technology based on the lowest TRL assigned to any CTE of that technology. Based on the assessment, the overall TRL for WAO was 2 and the TRL for FBSR was 3. WAO was limited by the current lack of definition for the off-gas treatment system (TRL of 2). The FBSR Product Handling had little or no test work and therefore received the lowest score (TRL of 3) for the FBSR CTEs. In summary, both FBSR and WAO appear to be viable technologies for treatment of Tank 48H legacy waste. FBSR has a higher degree of maturity than WAO, but additional technology development will be required for both technologies. However, the Assessment Team believes that sufficient information is available for DOE to select the preferred or primary technology. Limited testing of the backup technology should be conducted as a risk mitigation strategy.

  19. SAVANNAH RIVER SITE TANK 48H WASTE TREATMENT PROJECT TECHNOLOGY READINESS ASSESSMENT

    SciTech Connect (OSTI)

    Harmon, Harry D.; Young, Joan K.; Berkowitz, Joan B.; Devine, John C.; Sutter, Herbert G.

    2008-03-18

    One of U.S. Department of Energy's (DOE) primary missions at Savannah River Site (SRS) is to retrieve and treat the high level waste (HLW) remaining in SRS tanks and close the F&H tank farms. At present, a significant impediment to timely completion of this mission is the presence of significant organic chemical contamination in Tank 48H. Tank 48H is a 1.3 million gallon tank with full secondary containment, located and interconnected within the SRS tank system. However, the tank has been isolated from the system and unavailable for use since 1983, because its contents - approximately 250,000 gallons of salt solution containing Cs-137 and other radioisotopes - are contaminated with nearly 22,000 Kg of tetraphenylborate, a material which can release benzene vapor to the tank head space in potentially flammable concentrations. An important element of the DOE SRS mission is to remove, process, and dispose of the contents of Tank 48H, both to eliminate the hazard it presents to the SRS H-Tank Farm and to return Tank 48H to service. Tank 48H must be returned to service to support operation of the Salt Waste Processing Facility, to free up HLW tank space, and to allow orderly tank closures per Federal Facility Agreement commitments. The Washington Savannah River Company (WSRC), the SRS prime contractor, has evaluated alternatives and selected two processes, Wet Air Oxidation (WAO) and Fluidized Steam Bed Reforming (FBSR) as candidates for Tank 48H processing. Over the past year, WSRC has been testing and evaluating these two processes, and DOE is nearing a final technology selection in late 2007. In parallel with WSRC's ongoing work, DOE convened a team of independent qualified experts to conduct a Technology Readiness Assessment (TRA). The purpose of the TRA was to determine the maturity level of the Tank 48H treatment technology candidates - WAO and FBSR. The methodology used for this TRA is based on detailed guidance for conducting TRAs contained in the Department of Defense (DoD), Technology Readiness Assessment Deskbook. The TRA consists of three parts: (1) Determination of the Critical Technology Elements (CTEs) for each of the candidate processes. (2) Evaluation of the Technology Readiness Levels (TRLs) of each CTE for each process. (3) Defining of the technology testing or engineering work necessary to bring immature technologies to the appropriate maturity levels. The TRA methodology assigns a TRL to a technology based on the lowest TRL assigned to any CTE of that technology. Based on the assessment, the overall TRL for WAO was 2 and the TRL for FBSR was 3. WAO was limited by the current lack of definition for the off-gas treatment system (TRL of 2). The FBSR Product Handling had little or no test work and therefore received the lowest score (TRL of 3) for the FBSR CTEs. In summary, both FBSR and WAO appear to be viable technologies for treatment of Tank 48H legacy waste. FBSR has a higher degree of maturity than WAO, but additional technology development will be required for both technologies. However, the Assessment Team believes that sufficient information is available for DOE to select the preferred or primary technology. Limited testing of the backup technology should be conducted as a risk mitigation strategy.

  20. Variance analysis in the quality control of ready mixed concrete in a major structure 

    E-Print Network [OSTI]

    Valle Aguilar, Jorge Luis

    1984-01-01

    of strength variations in concrete Fly ash in ready mixed concrete Statistical Inference Hypothesis testing . Analysis of variance Duality control charts Linear regression and correlation Page 10 12 15 17 18 19 20 22 24 24 24 26 27 CHAPTER... Comparison of variances (o') for different ready mixed plants Comparison of means (X) and variances (o'). Comparison of means (7J) and variances (o') for various mix designs, f'c = 3000 psi Comparison of means (X) and variances (o') for mix designs...

  1. Vehicle Technologies Office: AVTA- Evaluating Military Bases and Fleet Readiness for Electric Vehicles

    Broader source: Energy.gov [DOE]

    The Vehicle Technologies Office's Advanced Vehicle Testing Activity carries out testing on a wide range of advanced vehicles and technologies on dynamometers, closed test tracks, and on-the-road. Through the AVTA, Idaho National Laboratory also does fleet and other analysis to evaluate readiness for plug-in electric vehicles and other advanced technology vehicles. The following reports describe analysis studies Idaho National Laboratory conducted for the military to evaluate readiness for plug-in electric vehicles.

  2. A radical route to interstellar propylene formation

    E-Print Network [OSTI]

    Rawlings, J M C; Viti, S; Cecchi-Pestellini, C

    2013-01-01

    Complex organic molecules, such as propylene (CH3CHCH2), are detected in molecular clouds (such as TMC1) with high fractional abundances (~2.10^{-9}, relative to hydrogen) that cannot be explained by gas-phase chemical reactions under normal dark cloud conditions. To obtain such high abundances requires an efficient grain-driven chemistry to be operating, coupled with effective desorption of the complex organics back into the gas-phase. We propose that the mechanism that we have previously described; rapid high density gas-phase chemistry in the gas released following sudden, total, ice mantle sublimation - can explain the high abundances, without recourse to ill-defined surface chemical pathways. Our model provides a natural explanation for why it is that some sources harbour high abundances of propylene, whilst others do not; based on the age and level of dynamical activity within the source (which affects the ice composition) and the chemical composition of the ambient gas.

  3. Fundamental spectroscopic studies of carbenes and hydrocarbon radicals

    SciTech Connect (OSTI)

    Gottlieb, C.A.; Thaddeus, P. [Harvard Univ., Cambridge, MA (United States)

    1993-12-01

    Highly reactive carbenes and carbon-chain radicals are studied at millimeter wavelengths by observing their rotational spectra. The purpose is to provide definitive spectroscopic identification, accurate spectroscopic constants in the lowest vibrational states, and reliable structures of the key intermediates in reactions leading to aromatic hydrocarbons and soot particles in combustion.

  4. Photodissociation dynamics of the phenyl radical via photofragment translational spectroscopy

    E-Print Network [OSTI]

    Neumark, Daniel M.

    in the combustion chemistry of aromatic hydrocarbons. Its forma- tion from the bimolecular reaction of smaller as a combustion intermediate dates back to the shock-tube study by Bauer5 in 1963, where phenyl was observed-workers,10­12 in which phenyl radicals were produced by pulsed laser photolysis and rate constants were

  5. Oxidation of ferrous and ferrocyanide ions by peroxyl radicals

    SciTech Connect (OSTI)

    Khaikin, G.I.; Alfassi, Z.B.; Huie, R.E.; Neta, P. [National Inst. of Standards and Technology, Gaithersburg, MD (United States)] [National Inst. of Standards and Technology, Gaithersburg, MD (United States)

    1996-04-25

    Alkylperoxyl and arylperoxyl radicals were produced by pulse radiolysis in aqueous solutions, and their reactions with ferrous and ferrocyanide ions were studied by kinetic spectrophotometry. Oxidation of Fe(CN){sub 6}{sup 4-} took place with rate constants that varied from < 1 x 10{sup 5} to 5 x 10{sup 7} L mol{sup -1} s{sup -1}, depending on the electron-withdrawing effects of the substituents on the peroxyl radical and presumably reflecting variations in reduction potential of the peroxyl radical, as expected for outer-sphere electron transfer. Oxidation of Fe{sub aq}{sup 2+}, on the other hand, took place by an inner-sphere mechanism controlled by the rate of dissociative interchange of the water ligand. The rate constants were nearly the same for all the peroxyl radicals examined (k = (0.5-1.1) x 10{sup 6} L mol{sup -1} s{sup -1}) and involved the formation of a transient intermediate, RO{sub 2}{sup -}Fe{sup 3+}, which later decomposed to yield Fe{sub aq}{sup 3+}. The decomposition was accelerated by H{sup +} and by Fe{sup 2+}. The proposed mechanism is a modification of a previously suggested reaction scheme. 27 refs., 5 figs., 2 tabs.

  6. Relative importance of radical families The "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    · Relative importance of radical families · The "Ozone Hole" · Introduction to heterogeneous chemistry Tuesday, March 8, 2011 #12;Review of important points so far Stratospheric ozone is only produced with these parameters Sir Sydney Chapman nearly got it right. He could account for the formation of the ozone layer

  7. For Immediate Release RADICAL CHANGES IN CONSUMER PATTERNS PREDICTED

    E-Print Network [OSTI]

    Open_House on the future of broadcast media today brought together over 100 key thinkers in the sector who debated a radical shift in the broadcast industry that is changing consumers from passive media About Open_House Open_House at Media Lab Europe is a series of monthly research driven forums

  8. Preindustrial to present-day changes in tropospheric hydroxyl radical and methane lifetime from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP)

    E-Print Network [OSTI]

    2013-01-01

    al. : Changes in tropospheric hydroxyl radical and methaneal. : Changes in tropospheric hydroxyl radical and methaneal. : Changes in tropospheric hydroxyl radical and methane

  9. Secondary Organic Aerosol Formation From Radical-Initiated Reactions of Alkenes: Development of Mechanisms

    E-Print Network [OSTI]

    Matsunaga, Aiko

    2009-01-01

    the Nitrate Radical (NO 3 ) with Isoprene, 1,3-Butadiene and2,3- Dimethyl-1,3-Butadiene in Air. Atmos. Environ. , 26A,Phase Reactions of 1,3-Butadiene with OH and NO 3 Radicals.

  10. Secondary Organic Aerosol Formation From Radical-Initiated Reactions of Alkenes: Development of Mechanisms

    E-Print Network [OSTI]

    Matsunaga, Aiko

    2009-01-01

    Radical (NO 3 ) with Isoprene, 1,3-Butadiene and 2,3-Dimethyl-1,3-Butadiene in Air. Atmos. Environ. , 26A, 2771–Phase Reactions of 1,3-Butadiene with OH and NO 3 Radicals.

  11. Intense, hyperthermal source of organic radicals for matrix-isolation spectroscopy

    E-Print Network [OSTI]

    Ellison, Barney

    , for studying radical reactions. It has been known for almost 50 years that radicals can be isolated by freezing in cryogenic matrices. Matrix spectroscopy remains an im- portant tool for studying organic radicals, since high number densities of these reactive species can be accumulated in cryogenic matrices and held

  12. Mapping nucleic acid structure by hydroxyl radical cleavage Thomas D Tullius1,2

    E-Print Network [OSTI]

    Tullius, Thomas D.

    Mapping nucleic acid structure by hydroxyl radical cleavage Thomas D Tullius1,2 and Jason A Greenbaum2 Hydroxyl radical footprinting is a widely used method for following the folding of RNA molecules be followed simultaneously at single-nucleotide resolution. In recent work, hydroxyl radical footprinting has

  13. radicals. This requirement represents a major drawback in terms of atom economy and

    E-Print Network [OSTI]

    Yu, Haiyuan

    fluorescent light, with no external heating or cooling of the reaction mixture. For example, typical reaction right panel). The selectivities for one enantiomer rival those observed for the classical ionic and con

  14. Observations of hydroxyl and peroxy radicals and the impact of BrO at Summit, Greenland in 2007 and 2008

    E-Print Network [OSTI]

    2011-01-01

    Stohl, A. : Observations of hydroxyl and the sum of peroxyand Physics Observations of hydroxyl and peroxy radicals andet al. : Observations of hydroxyl and peroxy radicals and

  15. Are Wireless Sensors and Controls Ready for the Building Automation Industry? Selected Case Studies and Technology Development Activities

    SciTech Connect (OSTI)

    Kintner-Meyer, Michael CW; Brambley, Michael R.

    2006-09-13

    This paper discusses whether or not today’s wireless sensors are ready for building controls and energy efficiency monitoring applications.

  16. Make-buy decisions in the face of radical innovations.

    E-Print Network [OSTI]

    Perrons, Robert Kirby

    2004-10-26

    Connect DEC Digital Equipment Corporation DVD Digital Video Disc EM Expectation Maximization GDP Gross Domestic Product GE General Electric GM General Motors IBM International Business Machines IP Intellectual Property... ______________________________________________________________________________ Make-Buy Decisions in the Face of Radical Innovations 5 Balloon Tire Bicycle,” the “Aero Cycle,” and the built-in “Cycle Lock” brought about a quantum leap in the industry. Instead of outsourcing the production of the parts for his bicycles as had been...

  17. Living With Radical Uncertainty. The Exemplary case of Folding Protein

    E-Print Network [OSTI]

    Ignazio Licata

    2010-04-21

    Laplace's demon still makes strong impact on contemporary science, in spite of the fact that Logical Mathematics outcomes, Quantum Physics advent and more recently Complexity Science have pointed out the crucial role of uncertainty in the World's descriptions. We focus here on the typical problem of folding protein as an example of uncertainty, radical emergence and a guide to the "simple" principles for studying complex systems.

  18. DeNOx characteristics using two staged radical injection techniques

    SciTech Connect (OSTI)

    Kambara, S.; Kumano, Y.; Yukimura, K.

    2009-06-15

    Ammonia radical injection using pulsed dielectric barrier discharge (DBD) plasma has been investigated as a means to control NOx emissions from combustors. When DBD plasma-generated radicals (NH{sub 2}, NH, N, and H) are injected into a flue gas containing nitrogen oxide (NOx), NOx is removed efficiently by chain reactions in the gas phase. However, because the percentage of NOx removal gradually decreases with increasing oxygen concentrations beyond 1% O{sub 2}, improvement of the DeNOx (removal of nitrogen oxide) characteristics at high O{sub 2} concentrations was necessary for commercial combustors. A two-staged injection of the DeNOx agent was developed based on the detailed mechanisms of electron impact reactions and gas phase reactions. A concentration of H radical was observed to play an important role in NOx formation and removal. The effects of applied voltages, oxygen concentrations, and reaction temperatures on NOx removal were investigated under normal and staged injection. NOx removal was improved by approximately 20% using staged injection at O{sub 2} concentrations of 1 to 4%.

  19. GaN-Ready Aluminum Nitride Substrates for Cost-Effective, Very Low Dislocation Density III-Nitride LED's

    SciTech Connect (OSTI)

    Sandra Schujman; Leo Schowalter

    2010-10-15

    The objective of this project was to develop and then demonstrate the efficacy of a costeffective approach for a low defect density substrate on which AlInGaN LEDs can be fabricated. The efficacy of this “GaN-ready” substrate would then be tested by growing high efficiency, long lifetime InxGa1-xN blue LEDs. The approach used to meet the project objectives was to start with low dislocation density AlN single-crystal substrates and grow graded AlxGa1-xN layers on top. Pseudomorphic AlxGa1-xN epitaxial layers grown on bulk AlN substrates were used to fabricate light emitting diodes and demonstrate better device performance as a result of the low defect density in these layers when benched marked against state-of-the-art LEDs fabricated on sapphire substrates. The pseudomorphic LEDs showed excellent output powers compared to similar wavelength devices grown on sapphire substrates, with lifetimes exceeding 10,000 hours (which was the longest time that could reliably be estimated). In addition, high internal quantum efficiencies were demonstrated at high driving current densities even though the external quantum efficiencies were low due to poor photon extraction. Unfortunately, these pseudomorphic LEDs require high Al content so they emit in the ultraviolet. Sapphire based LEDs typically have threading dislocation densities (TDD) > 108 cm-2 while the pseudomorphic LEDs have TDD ? 105 cm-2. The resulting TDD, when grading the AlxGa1-xN layer all the way to pure GaN to produce a “GaN-ready” substrate, has varied between the mid 108 down to the 106 cm-2. These inconsistencies are not well understood. Finally, an approach to improve the LED structures on AlN substrates for light extraction efficiency was developed by thinning and roughening the substrate.

  20. Animation Requirements

    Broader source: Energy.gov [DOE]

    Animations include dynamic elements such as interactive images and games. For developing animations, follow these design and coding requirements.

  1. Power of the point, radical axis and radical center When reading these notes, please draw pictures. They will help. If you see any

    E-Print Network [OSTI]

    Timorin, Vladlen

    Power of the point, radical axis and radical center When reading these notes, please draw pictures) is called the power of the point P with respect to the circle . The power of the point depends on the point and on the circle. However, from our definition it might seem that the power of the point P also depends

  2. AN EVALUATION OF FUSION ENERGY R&D GAPS USING TECHNOLOGY READINESS LEVELS M. S. Tillack1

    E-Print Network [OSTI]

    Raffray, A. René

    in the science and technology, or "laboratory" environment almost invariably leads to cost and schedule overAN EVALUATION OF FUSION ENERGY R&D GAPS USING TECHNOLOGY READINESS LEVELS M. S. Tillack1 , A. D and remaining R&D needs, we adopted a methodology called "Technology Readiness Levels". We defined

  3. The purpose of NOAA's Weather-Ready Nation initiative is first and foremost to save lives and

    E-Print Network [OSTI]

    The purpose of NOAA's Weather-Ready Nation initiative is first and foremost to save lives public. The Weather-Ready Nation initiative will help America meet the challenges that come with increased extreme weather events by more actively engaging the public on preparedness and resiliency. What

  4. Hydroxyl Radical is the Active Species in Photochemical DNA Strand Scission by Bis(peroxo)vanadium(V) Phenanthroline

    E-Print Network [OSTI]

    Chanfreau, Guillaume

    Hydroxyl Radical is the Active Species in Photochemical DNA Strand Scission by Bis-N-oxide (DMPO) as spin-traps for singlet oxygen and hydroxyl radical, respectively, implicated hydroxyl radical reactions were run on the same lane. These findings identify hydroxyl radical produced from

  5. Conserved electron donor complex Dre2-Tah18 is required for ribonucleotide reductase metallocofactor assembly and DNA synthesis

    E-Print Network [OSTI]

    Zhang, Yan

    Eukaryotic ribonucleotide reductases (RNRs) require a diferric-tyrosyl radical (Fe[III over 2]-Y•) cofactor to produce deoxynucleotides essential for DNA replication and repair. This metallocofactor is an important target ...

  6. Studies of transition states and radicals by negative ion photodetachment

    SciTech Connect (OSTI)

    Metz, R.B.

    1991-12-01

    Negative ion photodetachment is a versatile tool for the production and study of transient neutral species such as reaction intermediates and free radicals. Photodetachment of the stable XHY{sup {minus}} anion provides a direct spectroscopic probe of the transition state region of the potential energy surface for the neutral hydrogen transfer reaction X + HY {yields} XH + Y, where X and Y are halogen atoms. The technique is especially sensitive to resonances, which occur at a specific energy, but the spectra also show features due to direct scattering. We have used collinear adiabatic simulations of the photoelectron spectra to evaluate trail potential energy surfaces for the biomolecular reactions and have extended the adiabatic approach to three dimensions and used it to evaluate empirical potential energy surfaces for the I + Hl and Br + HI reactions. In addition, we have derived an empirical, collinear potential energy surface for the Br + HBr reaction that reproduces our experimental results and have extended this surface to three dimensions. Photodetachment of a negative ion can be also used to study neutral free radicals. We have studied the vibrational and electronic spectroscopy of CH{sub 2}NO{sub 2} by photoelectron spectroscopy of CH{sub 2}NO{sub 2}{sup {minus}}, determining the electron affinity of CH{sub 2}NO{sub 2}, gaining insight on the bonding of the {sup 2}B{sub 1} ground state and observing the {sup 2}A{sub 2} excited state for the first time. Negative ion photodetachment also provides a novel and versatile source of mass-selected, jet-cooled free radicals. We have studied the photodissociation of CH{sub 2}NO{sub 2} at 270, 235, and 208 nm, obtaining information on the dissociation products by measuring the kinetic energy release in the photodissociation.

  7. Future Directions of Structural Mass Spectrometry using Hydroxyl Radical Footprinting

    SciTech Connect (OSTI)

    J Kiselar; M Chance

    2011-12-31

    Hydroxyl radical protein footprinting coupled to mass spectrometry has been developed over the last decade and has matured to a powerful method for analyzing protein structure and dynamics. It has been successfully applied in the analysis of protein structure, protein folding, protein dynamics, and protein-protein and protein-DNA interactions. Using synchrotron radiolysis, exposure of proteins to a 'white' X-ray beam for milliseconds provides sufficient oxidative modification to surface amino acid side chains, which can be easily detected and quantified by mass spectrometry. Thus, conformational changes in proteins or protein complexes can be examined using a time-resolved approach, which would be a valuable method for the study of macromolecular dynamics. In this review, we describe a new application of hydroxyl radical protein footprinting to probe the time evolution of the calcium-dependent conformational changes of gelsolin on the millisecond timescale. The data suggest a cooperative transition as multiple sites in different molecular subdomains have similar rates of conformational change. These findings demonstrate that time-resolved protein footprinting is suitable for studies of protein dynamics that occur over periods ranging from milliseconds to seconds. In this review, we also show how the structural resolution and sensitivity of the technology can be improved as well. The hydroxyl radical varies in its reactivity to different side chains by over two orders of magnitude, thus oxidation of amino acid side chains of lower reactivity are more rarely observed in such experiments. Here we demonstrate that the selected reaction monitoring (SRM)-based method can be utilized for quantification of oxidized species, improving the signal-to-noise ratio. This expansion of the set of oxidized residues of lower reactivity will improve the overall structural resolution of the technique. This approach is also suggested as a basis for developing hypothesis-driven structural mass spectrometry experiments.

  8. Are Batteries Ready for Plug-in Hybrid Buyers?

    E-Print Network [OSTI]

    Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

    2010-01-01

    depends on the assumed drive cycle—a pattern of varyingbattery performance. A drive cycle is usually made up of oneand (3) a more aggressive drive cycle. Required peak power

  9. Video Requirements

    Broader source: Energy.gov [DOE]

    All EERE videos, including webinar recordings, must meet Section 508's requirements for accessibility. All videos should be hosted on the DOE YouTube channel.

  10. DOE Zero Energy Ready Home Case Study: Boulder ZED Design Build - Boulder, Colorado

    SciTech Connect (OSTI)

    none,

    2014-11-01

    This case study describes a DOE Zero Energy Ready Home in Boulder, Colorado, that scored HERS 38 without PV and 0 with PV. This 2,504 ft2 custom home has advanced framed walls, superior insulation a ground-source heat pump, ERV, and triple-pane windows.

  11. Questions to Ask During Employer Research Ready ReferenceD-14

    E-Print Network [OSTI]

    & Technology Career Services Oklahoma State University College of Engineering, Architecture & TechnologyQuestions to Ask During Employer Research Ready ReferenceD-14 College of Engineering, Architecture the organization offer its employees? · How high is the employee turnover rate for the organization? · What

  12. Original Article Human readiness to throw: the sizeweight illusion is not an illusion when

    E-Print Network [OSTI]

    Indiana University

    are equivalent. Thus, the illusion is functional, not a misperception: optimal objects for throwing are picked that the illusion is a perceptual bias that reflects readiness to acquire fully functional throwing ability food. The ability to throw objects long distance is known to have been of central importance

  13. Capture-Ready Coal Plants -Options, Technologies and Economics Mark C. Bohm1

    E-Print Network [OSTI]

    1 Capture-Ready Coal Plants - Options, Technologies and Economics Mark C. Bohm1 , Howard J. Herzog1 be employed during the initial design and construction of a both pulverized coal and integrated gasification the Internet in the summer of 2006 [7]. Introduction Interest in the construction of coal-fired power

  14. Phase 5 storage (Project W-112) Central Waste Complex operational readiness review, final report

    SciTech Connect (OSTI)

    Wight, R.H.

    1997-05-30

    This document is the final report for the RFSH conducted, Contractor Operational Readiness Review (ORR) for the Central Waste Complex (CWC) Project W-112 and Interim Safety Basis implementation. As appendices, all findings, observations, lines of inquiry and the implementation plan are included.

  15. MEASURING READINESS FOR CAREER-DECISION MAKING WITH THE CAREER THOUGHTS INVENTORY IN FINLAND

    E-Print Network [OSTI]

    McQuade, D. Tyler

    1 MEASURING READINESS FOR CAREER-DECISION MAKING WITH THE CAREER THOUGHTS INVENTORY IN FINLAND University of Applied Sciences, Jyväskylä, Finland. James Sampson, Ph.D., is Associate Dean, College of Educational Research Methodology, the Institute for Educational Research, University of Jyväskylä, Finland

  16. Focus Sheet | Hazardous Waste Checklist How to be ready for state hazardous waste

    E-Print Network [OSTI]

    Wilcock, William

    storage cabinet. Avoid accumulating a lot of waste ­ keep areas clear. EPO ­ Hazardous Waste Checklist 07Focus Sheet | Hazardous Waste Checklist How to be ready for state hazardous waste inspectors. See a hazardous waste inspection. ons, rrosive. n hemicals? ical waste. Waste-like chemicals have als Are you

  17. Physics and Astronomy Department San Francisco State University Physics Readiness Exam

    E-Print Network [OSTI]

    Golterman, Maarten

    Physics and Astronomy Department San Francisco State University Physics Readiness Exam Math Qualification Test for Introductory Physics ­ Physics 111 or Physics 220 In addition to meeting course prerequisites, students wishing to enroll in Physics 111 or Physics 220 must demonstrate adequate competence

  18. DOE Zero Energy Ready Home Case Study: Promethean Homes — Gross-Shepard Residence, Charlottesville, VA

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This is the first DOE Zero Energy Ready Home for this builder, who earned a Custom Builder honor in the 2014 Housing Innovation Awards. The home included rigid mineral wool board insulation over house wrap and plywood on the 2x6 advanced framed walls, achieving HERS 33 without PV.

  19. DOE Zero Energy Ready Home Case Study: Mandalay Homes — Pronghorn Ranch, Prescott Valley, AZ

    SciTech Connect (OSTI)

    none,

    2014-09-01

    The builder has certified 20 homes to DOE Zero Energy Ready Home program and plans are underway for 50 more. Winner of a Production Builder prize in the 2014 Housing Innovation Awards, the homes achieved a HERS score of 48 without photovoltaics (PV) or HERS 25 with 3.5 kW PV included.

  20. DOE Zero Energy Ready Home Case Study: Cobblestone Homes — 2014 Model Home, Midland, MI

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This builder's first DOE Zero Energy Ready Home won a Custom Builder award in the 2014 Housing Innovation Awards, scored HERS 49 without PV or HERS 44 with 1.4 kW of PV, and served as a prototype and energy efficiency demonstration model while performance testing was conducted.

  1. IsYour Network Cloud Ready? Network EnableYour Cloud With MPLSVPNs

    E-Print Network [OSTI]

    Greenberg, Albert

    -enabled cloud that is highly-secure and reliable. It is critical for enterprises to evaluate a network, but the high level of shared infrastructure creates concerns about security risks.As a result, the public cloudIsYour Network Cloud Ready? Network EnableYour Cloud With MPLSVPNs A FROST & SULLIVAN EXECUTIVE

  2. Exploring Factors of Readiness to Learn about Infant Feeding in Mothers of NICU Infants

    E-Print Network [OSTI]

    Hadsell, Christine Ann

    2013-08-31

    Abstract Teaching the postpartum mother who has an infant in the Neonatal Intensive Care Unit (NICU) about infant feeding may be delayed if the nurse does not determine readiness to learn (RTL) and confidence to feed (CTF) and/or makes assumptions...

  3. Ohio-Kentucky-Indiana Regional Council of Governments Go Solar Ready – Solar Map

    Broader source: Energy.gov [DOE]

    The Ohio-Kentucky-Indiana Regional Council of Governments Go Solar Ready Map provides general information about the estimated annual solar energy potential on building rooftops in the OKI region. The intention of this tool is to provide the user a general understanding of the solar energy available on rooftops in the OKI tristate region.

  4. Is RPL Ready for Actuation? A Comparative Evaluation in a Smart City Scenario

    E-Print Network [OSTI]

    Picco, Gian Pietro

    Is RPL Ready for Actuation? A Comparative Evaluation in a Smart City Scenario Timofei Istomin1 of a large-scale infrastructure for smart city applications, which directly informs our evaluation, where we infrastructure of 860+ IEEE 802.15.4 nodes, for monitoring and control of public lighting and other "smart city

  5. CLAS12 Software Readiness Review -Replay Jerry Gilfoyle (for the CLAS12 Software Group)

    E-Print Network [OSTI]

    Gilfoyle, Jerry

    CLAS12 Software Readiness Review - Replay Jerry Gilfoyle (for the CLAS12 Software Group) Physics Department, University of Richmond, Virginia Outline: 0. History 1. Introduction 2. Software Framework 3 spectrometer based on CLAS6. Luminosity increases by a factor of ten over CLAS6 (L = 1035 cm-2s-1). Software

  6. DOE Zero Energy Ready Home Case Study: Brookside Development — Singer Village, Derby, CT

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This DOE Zero Energy Ready Home is one of a development of seven two-story homes that garnered a Production Builder award in the 2014 Housing Innovation Awards. Exceptional construction quality allowed the home to achieve a HERS score of 45 without photovoltaic, or HERS 26 with a 7-kW photovoltaic system included.

  7. DOE Zero Energy Ready Home Case Study: M Street Homes — Smartlux on Greenpark, Houston, TX

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This builder certified its first DOE Zero Energy Ready Home and won a Production Builder honor in the 2014 Housing Innovation Awards. It is the first home in the world to use a tri-generation system to supply electricity, heating, and cooling on site.

  8. Personal Internet Presence: Job Seeker Self-Audit Ready Reference D-17

    E-Print Network [OSTI]

    Personal Internet Presence: Job Seeker Self-Audit Ready Reference D-17 College of Engineering Internet Presence Job Seeker Self-Audit to evaluate your e-image on a regular basis. Personal Internet your resume been posted on the internet by your academic department? Yes No I don't know Do you belong

  9. An evaluation of fusion energy R&D gaps using Technology Readiness Levels

    E-Print Network [OSTI]

    An evaluation of fusion energy R&D gaps using Technology Readiness Levels M. S. Tillack for prioritization. #12;The topic of fusion energy R&D gaps is receiving increased attention page 2 of 16 In EU&D needs that is widely recognized and utilized outside of the fusion community. Initial efforts

  10. Team leader`s preparation guide for Operational Readiness Reviews (ORR)

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    This document provides instructions, explanations, and examples for the performance of all phases of an Operational Readiness Review (ORR). Details pertinent to the team leader, team members, and review coordinator are outlined. Sample forms and correspondence are included in appendices. Although this document is for use by DOE ORR team leaders, it can be used by contractor ORR team leaders also.

  11. VALUE OF A WEATHER-READY NATION LAST REVISED 10/13/2011

    E-Print Network [OSTI]

    1 VALUE OF A WEATHER-READY NATION LAST REVISED 10/13/2011 NOAA activities support science, service value of our work as it relates to the National Weather Service (NWS). Here we provide data on: What and by product or service type. If you find data about weather that may be useful in your work

  12. DOE Zero Energy Ready Home Case Study: Clifton View Homes — Kaltenbach Residence, Clinton, WA

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This home on Whidbey Island won a Custom Builder award in the 2014 Housing Innovation Awards. The DOE Zero Energy Ready Home scores HERS 37 without PV or HERS -13 with 10 kW PV, enough to power the home and an electric car.

  13. DOE Zero Energy Ready Home Case Study: AquaZephyr, Ithaca, NY...

    Energy Savers [EERE]

    study of a DOE Zero Energy Ready home in Ithaca, NY, that achieves a HERS 56 without PV or HERS 15 with 4-kW of PV. The two-story, 1,664-ft2 home is one of 17 single-family and...

  14. DOE Zero Energy Ready Home Case Study: One Sky Homes, San Jose...

    Broader source: Energy.gov (indexed) [DOE]

    Ready home in San Jose, CA, that achieved a HERS 69 on the California HERS score without PV, or HERS -1 with 6.4 kW of PV. The custom home has 2x6 advanced framed walls dense...

  15. DOE Zero Energy Ready Home Case Study: KB Home, Lancaster, CA...

    Energy Savers [EERE]

    study of a DOE Zero Energy Ready home in Lancaster, CA, that achieved a HERS 43 without PV 43 or HERS 0 with 6.9-kW PV. The two-story, 2,537ft2 home serves as a model for the...

  16. DOE Zero Energy Ready Home: Near Zero Maine Home II, Vassalboro...

    Energy Savers [EERE]

    study of a DOE Zero Energy Ready home in Vassalboro, Maine, that scored HERS 35 without PV and HERS 11 with PV. This 1,200 ft2 home has 10.5-inch-thick double-walls with 3 layers...

  17. Source-dependent variation in hydroxyl radical production by airborne particulate matter

    SciTech Connect (OSTI)

    Marjan Alaghmand; Neil V. Blough [University of Maryland, College Park, MD (United States). Department of Chemistry and Biochemistry

    2007-04-01

    Epidemiological studies suggest exposure to airborne particles is responsible for a wide range of adverse health effects, potentially arising from particle-induced oxidative stress. A highly sensitive fluorescence method was employed to measure the production of hydroxyl radical by a broad range of particle types including urban dust, diesel particulate matter, coal fly ash, kaolinite, and silica. Little or no production of OH was observed in the absence of an added electron donor or H{sub 2}O{sub 2}. In the presence of a biological electron donor (NADPH, 3 mM), the rate of OH production (R{sub OH}) for 3 mg/mL of these particles varied from 23 nM s{sup -1} for diesel particulate matter (SRM 2975) to 0.20 nM s{sup -1} for coal fly ash (SRM 2689). No detectable OH was produced by kaolinite or silica. Hydroxyl radical formation was eliminated under anaerobic conditions and in the presence of catalase, indicating that O{sub 2} and H{sub 2}O{sub 2} are required for its generation. Partial inhibition of OH formation by superoxide dismutase (SOD) was also observed in some cases, suggesting that superoxide is also involved. The metal chelator deferoxamine mesylate (DFX) in most cases suppressed OH formation, but diethylenetriaminepentaacetic acid (DTPA) generally enhanced it, implicating metal ion reactions in OH generation as well. The dependence of R{sub OH} on NADPH concentration further implicates particle surface reactions in OH formation. To the authors' knowledge, these measurements provide the first quantitative estimate of ROH for a broad range of particle types. 49 refs., 6 figs., 1 tab.

  18. Infrared spectroscopy of organic free radicals related to combustion processes

    SciTech Connect (OSTI)

    Weisshaar, J.C. [Univ. of Wisconsin, Madison (United States)

    1993-12-01

    The primary long-term goal of this work is to develop new techniques for measuring vibrational spectra of polyatomic neutral free radicals. The authors explore a variation of resonant two-photon ionization (R2PI) in which tunable {omega}{sub IR} excites the radical vibrationally and {omega}{sub UV} selectively ionizes only the vibrationally excited molecules. Development of the IR + UV R2PI experiment is underway. In the meantime, the authors have used optical R2PI and pulsed field ionization (PFI) detection to obtain new vibrational spectra of species such as the benzyl and phenylsilane cations. In benzyl, a great deal was learned about the vibronic coupling mechanism in the mixed q{sup 2}A{sub 2}-2{sup 2}B{sub 2} system near 450 nm by projecting the mixed states onto the manifold of cation vibrational states. In phenylsilane{sup +}, we find that the sixfold barrier to internal rotation of the silyl group is small (V{sub 6} = +19 cm{sup {minus}1}). We are beginning to understand the mechanisms of coupling of torsional states with vibration, overall rotation, and other electronic states. In addition, we are developing a new model of internal rotation in aromatic compounds based on Prof. Frank Weinhold`s natural resonance theory.

  19. Highly stable tetrathiafulvalene radical dimers in [3]catenanes

    SciTech Connect (OSTI)

    Spruell, Jason M.; Coskun, Ali; Friedman, Douglas C.; Forgan, Ross S.; Sarjeant, Amy A.; Trabolsi, Ali; Fahrenbach, Albert C.; Barin, Gokhan; Paxton, Walter F.; Dey, Sanjeev K.; Olson, Mark A.; Benítez, Diego; Tkatchouk, Ekaterina; Colvin, Michael T.; Carmielli, Raanan; Caldwell, Stuart T.; Rosair, Georgina M.; Hewage, Shanika Gunatilaka; Duclairoir, Florence; Seymour, Jennifer L.; Slawin, Alexandra M.Z.; Goddard, III, William A.; Wasielewski, Michael R.; Cooke, Graeme; Stoddart, J. Fraser

    2010-12-03

    Two [3]catenane 'molecular flasks' have been designed to create stabilized, redox-controlled tetrathiafulvalene (TTF) dimers, enabling their spectrophotometric and structural properties to be probed in detail. The mechanically interlocked framework of the [3]catenanes creates the ideal arrangement and ultrahigh local concentration for the encircled TTF units to form stable dimers associated with their discrete oxidation states. These dimerization events represent an affinity umpolung, wherein the inversion in electronic affinity replaces the traditional TTF-bipyridinium interaction, which is over-ridden by stabilizing mixed-valence (TTF){sub 2}{sup {sm_bullet}+} and radical-cation (TTF{sup {sm_bullet}+}){sub 2} states inside the 'molecular flasks.' The experimental data, collected in the solid state as well as in solution under ambient conditions, together with supporting quantum mechanical calculations, are consistent with the formation of stabilized paramagnetic mixed-valence dimers, and then diamagnetic radical-cation dimers following subsequent one-electron oxidations of the [3]catenanes.

  20. Absolute photoionization cross-section of the propargyl radical

    SciTech Connect (OSTI)

    Savee, John D.; Welz, Oliver; Taatjes, Craig A.; Osborn, David L. [Sandia National Laboratories, Combustion Research Facility, Livermore, California 94551 (United States); Soorkia, Satchin [Institut des Sciences Moleculaires d'Orsay, Universite Paris-Sud 11, Orsay (France); Selby, Talitha M. [Department of Chemistry, University of Wisconsin, Washington County Campus, West Bend, Wisconsin 53095 (United States)

    2012-04-07

    Using synchrotron-generated vacuum-ultraviolet radiation and multiplexed time-resolved photoionization mass spectrometry we have measured the absolute photoionization cross-section for the propargyl (C{sub 3}H{sub 3}) radical, {sigma}{sub propargyl}{sup ion}(E), relative to the known absolute cross-section of the methyl (CH{sub 3}) radical. We generated a stoichiometric 1:1 ratio of C{sub 3}H{sub 3} : CH{sub 3} from 193 nm photolysis of two different C{sub 4}H{sub 6} isomers (1-butyne and 1,3-butadiene). Photolysis of 1-butyne yielded values of {sigma}{sub propargyl}{sup ion}(10.213 eV)=(26.1{+-}4.2) Mb and {sigma}{sub propargyl}{sup ion}(10.413 eV)=(23.4{+-}3.2) Mb, whereas photolysis of 1,3-butadiene yielded values of {sigma}{sub propargyl}{sup ion}(10.213 eV)=(23.6{+-}3.6) Mb and {sigma}{sub propargyl}{sup ion}(10.413 eV)=(25.1{+-}3.5) Mb. These measurements place our relative photoionization cross-section spectrum for propargyl on an absolute scale between 8.6 and 10.5 eV. The cross-section derived from our results is approximately a factor of three larger than previous determinations.

  1. Photoinitiated proton-coupled electron transfer and radical transport kinetics in class la ribonucleotide reductase

    E-Print Network [OSTI]

    Pizano, Arturo A. (Arturo Alejandro)

    2013-01-01

    Proton-coupled electron transfer (PCET) is a critical mechanism in biology, underpinning key processes such as radical transport, energy transduction, and enzymatic substrate activation. Ribonucleotide reductases (RNRs) ...

  2. Reactions of the CN Radical with Benzene and Toluene: Product Detection and Low-Temperature Kinetics

    E-Print Network [OSTI]

    Trevitt, Adam J.

    2010-01-01

    of the CN Radical with Benzene and Toluene: Productare measured for the CN + benzene and CN + toluene reactionsdetection. The CN + benzene reaction rate coefficient at

  3. Can Planning Affect the Economic Crisis? Barely, and not unless planning changes radically

    E-Print Network [OSTI]

    Marcuse, Peter

    2010-01-01

    Can Planning Affect the Economic Crisis?Barely, and not unless planning changes radically By Petershould be clear that “urban planning and development” is not

  4. A versatile source to produce high-intensity, pulsed supersonic radical beams for crossed-beam experiments: The cyanogen radical CN,,X2

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    terrestrial and extraterrestrial environments. Initiated by the solar photolyses of hydrogen cyanide HCN are obtained by monitoring the decay kinetics of the CN radical, these investigations could not provide reac

  5. Are You Ready for This ? The New Uniform Guidance

    E-Print Network [OSTI]

    Kroll, Kristen L.

    ! ­ 99!separate!sec1ons!and!indexes! ­ Applicable!to!all!requirements!(administra1ve,!cost! and!audit)!and!all!types!of!grantees/26/14!!! · 200.112,!Conflict!of!interest!V!NEW! ­ Federal!agencies!must!establish!COI!policies! ­ Grantees!consider!financial!stability,!performance!history,! audit!reports!! ! #12;!!!!!!!!! 11! Sec.!200.3XX,!PostV!AwardV!Grantees!!! · 200.301,!Performance

  6. Radical re-appraisal of water structure in hydrophilic confinement

    E-Print Network [OSTI]

    A K Soper

    2013-09-26

    The structure of water confined in MCM41 silica cylindrical pores is studied to determine if confined water really is simply a version of the bulk liquid which can be substantially supercooled without crystallisation. A combination of total neutron scattering from the porous silica, both wet and dry,and computer simulation using a realistic model of the scattering substrate isused. The water in the pore is divided into three regions: core, interfacial and overlap. The average local densities of water in these simulations are found to be about 20% lower than bulk water density, while the density in the core region is below, but closer to, the bulk density. There is a decrease in both local and core densities when the temperature is lowered from 298K to 210K. The radical proposal is made here that water in hydrophilic confinement is under significant tension, around -100MPa, inside the pore.

  7. Spectroscopy and reaction dynamics of collision complexes containing hydroxyl radicals

    SciTech Connect (OSTI)

    Lester, M.I.

    1993-12-01

    The DOE supported work in this laboratory has focused on the spectroscopic characterization of the interaction potential between an argon atom and a hydroxyl radical in the ground X{sup 2}II and excited A {sup 2}{summation}{sup +} electronic states. The OH-Ar system has proven to be a test case for examining the interaction potential in an open-shell system since it is amenable to experimental investigation and theoretically tractable from first principles. Experimental identification of the bound states supported by the Ar + OH (X {sup 2}II) and Ar + OH(A {sup 2}{summation}{sup +}) potentials makes it feasible to derive realistic potential energy surfaces for these systems. The experimentally derived intermolecular potentials provide a rigorous test of ab initio theory and a basis for understanding the dramatically different collision dynamics taking place on the ground and excited electronic state surfaces.

  8. Role of surface generated radicals in catalytic combustion

    SciTech Connect (OSTI)

    Santavicca, D.A.; Stein, Y.; Royce, B.S.H.

    1984-04-01

    The role of surface generated OH radicals in determining the catalytic ignition characteristics for propane oxidation on platinum were studied. The experiments were conducted in a stacked-plate, catalyst bed. Transient measurements, during catalytic ignition, of the catalyst's axial temperature profile were made and the effect of equivalence ratio, inlet temperature and inlet velocity was investigated. These measurements will provide insights which will be useful in planning and interpreting to OH measurements. Attempts to measure OH concentration in the catalyst bed using resonance absorption spectroscopy were unsuccessful, indicating that OH concentrations are below 10 to the 16th power/cc but still possibly above equilibrium values. Measurements are currently underway using forward scatter laser induced fluorescence which should extend the OH detection limits several orders of magnitude below the equilibrium concentrations.

  9. Thermal oxidation technology ready for tougher paint finishing regs

    SciTech Connect (OSTI)

    Brooks, J.

    1995-04-01

    There is good news and bad news in the air for commercial paint finishers. The bad news is that future local and federal clean-air regulations are almost certain to require control of volatile organic compound emissions from spray booths and drying ovens. The good news is that one of the most effective systems for meeting such requirements also can help cut operations and maintenance costs. There are as many solutions to VOC emissions problems in paint finishing as there are types of paint-spraying facilities. However, despite the range of choices, regenerative thermal oxidation systems are gaining favor among plant managers, for whom performance and maximum application flexibility are key considerations. Compared to other VOC-destruction approaches, RTO systems are more forgiving and reliable. Although RTO systems involve somewhat higher capital investments than alternative approaches, such costs typically are offset by lower long-term fuel and maintenance requirements. In addition, RTO systems can convert pollutants into usable energy sources, helping minimize operating costs of abatement equipment.

  10. Technical Readiness and Gaps Analysis of Commercial Optical Materials and Measurement Systems for Advanced Small Modular Reactors

    SciTech Connect (OSTI)

    Anheier, Norman C.; Suter, Jonathan D.; Qiao, Hong; Andersen, Eric S.; Berglin, Eric J.; Bliss, Mary; Cannon, Bret D.; Devanathan, Ramaswami; Mendoza, Albert; Sheen, David M.

    2013-08-06

    This report intends to support Department of Energy’s Office of Nuclear Energy (DOE-NE) Nuclear Energy Research and Development Roadmap and industry stakeholders by evaluating optical-based instrumentation and control (I&C) concepts for advanced small modular reactor (AdvSMR) applications. These advanced designs will require innovative thinking in terms of engineering approaches, materials integration, and I&C concepts to realize their eventual viability and deployability. The primary goals of this report include: 1. Establish preliminary I&C needs, performance requirements, and possible gaps for AdvSMR designs based on best available published design data. 2. Document commercial off-the-shelf (COTS) optical sensors, components, and materials in terms of their technical readiness to support essential AdvSMR in-vessel I&C systems. 3. Identify technology gaps by comparing the in-vessel monitoring requirements and environmental constraints to COTS optical sensor and materials performance specifications. 4. Outline a future research, development, and demonstration (RD&D) program plan that addresses these gaps and develops optical-based I&C systems that enhance the viability of future AdvSMR designs. The development of clean, affordable, safe, and proliferation-resistant nuclear power is a key goal that is documented in the Nuclear Energy Research and Development Roadmap. This roadmap outlines RD&D activities intended to overcome technical, economic, and other barriers, which currently limit advances in nuclear energy. These activities will ensure that nuclear energy remains a viable component to this nation’s energy security.

  11. Predissociation of the Hydroxymethyl Radical in the 3pz Rydberg State: Formaldehyde + Hydrogen Atom Channel

    E-Print Network [OSTI]

    Reisler, Hanna

    Predissociation of the Hydroxymethyl Radical in the 3pz Rydberg State: Formaldehyde + Hydrogen Atom The photodissociation of the hydroxymethyl radical to hydrogen atom and formaldehyde was investigated following energy distribution derived from the data is broad, indicating that the formaldehyde cofragment

  12. Radical Intermediates in the Addition of OH to Propene: Photolytic Precursors and Angular Momentum E ects

    E-Print Network [OSTI]

    Butler, Laurie J.

    Supporting Information ABSTRACT: We investigate the photolytic production of two radical intermediates photofragment translational spectroscopy to detect several dissociation products of the unstable C3H6OH radicals: OH + propene, methyl + acetaldehyde, and ethyl + formaldehyde. We also use the angular momenta

  13. Author's personal copy Reaction dynamics of the phenyl radical with 1,2-butadiene

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Author's personal copy Reaction dynamics of the phenyl radical with 1,2-butadiene Xibin Gu t The crossed beams reaction of the phenyl radical (C6H5) with 1,2-butadiene (CH3HCCCH2) was studied under C1 atom of the 1,2-butadiene reactant. The initial reaction intermediate decomposed via atomic hydro

  14. Technology and Manufacturing Readiness of Early Market Motive and Non-Motive Hydrogen Storage Technologies for Fuel Cell Applications

    SciTech Connect (OSTI)

    Ronnebro, Ewa

    2012-06-16

    PNNL’s objective in this report is to provide DOE with a technology and manufacturing readiness assessment to identify hydrogen storage technologies’ maturity levels for early market motive and non-motive applications and to provide a path forward toward commercialization. PNNL’s Technology Readiness Assessment (TRA) is based on a combination of Technology Readiness Level (TRL) and Manufacturing Readiness Level (MRL) designations that enable evaluation of hydrogen storage technologies in varying levels of development. This approach provides a logical methodology and roadmap to enable the identification of hydrogen storage technologies, their advantages/disadvantages, gaps and R&D needs on an unbiased and transparent scale that is easily communicated to interagency partners. The TRA report documents the process used to conduct the TRA, reports the TRL and MRL for each assessed technology and provides recommendations based on the findings.

  15. DOE Zero Energy Ready Home Case Study: Caldwell and Johnson — Church Community and Housing Corporation, Charlestown, RI

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This DOE Zero Energy Ready Home garnered an Affordable Builder award in the 2014 Housing Innovation Awards, for its highly insulated construction, minisplit heat pump and water heater, and triple pane windows.

  16. Non-canonical active site architecture of the radical SAM thiamin pyrimidine synthase

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fenwick, Michael K.; Mehta, Angad P.; Zhang, Yang; Abdelwahed, Sameh H.; Begley, Tadhg P.; Ealick, Steven E.

    2015-03-27

    Radical S-adenosylmethionine (SAM) enzymes use a [4Fe-4S] cluster to generate a 5'-deoxyadenosyl radical. Canonical radical SAM enzymes are characterized by a ?-barrel-like fold and SAM anchors to the differentiated iron of the cluster, which is located near the amino terminus and within the ?-barrel, through its amino and carboxylate groups. Here we show that ?ThiC, the thiamin pyrimidine synthase in plants and bacteria, contains a tethered cluster-binding domain at its carboxy terminus that moves in and out of the active site during catalysis. In contrast to canonical radical SAM enzymes, we predict that SAM anchors to an additional active sitemore »metal through its amino and carboxylate groups. Superimposition of the catalytic domains of ?ThiC and glutamate mutase shows that these two enzymes share similar active site architectures, thus providing strong evidence for an evolutionary link between the radical ?SAM and adenosylcobalamin-dependent enzyme superfamilies.« less

  17. Technology Readiness Assessment Guide - DOE Directives, Delegations, and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S. CoalMexico IndependentMatter andPagesKey toRequirements

  18. DOE Zero Energy Ready Home Case Study: Leganza Residence - Greenbank, Washington

    SciTech Connect (OSTI)

    none,

    2014-11-01

    This case study describes a DOE Zero Energy Ready Home in Greenbank, Washington that scored HERS 37 without PV and a -5 with PV. This 1,955 ft2 custom home has 6.5-inch structural insulated panel (SIPs) walls, a 10.25-inch SIPS roof, an R-20 insulated slab, a 2-ton ground source heat pump, radiant floor heat, 7.1 kWh PV, and triple-pane windows.

  19. A review of "Radical Religion from Shakespeare to Milton: Figures of Nonconformity in Early Modern England." by Kristen Poole 

    E-Print Network [OSTI]

    Elizabeth Sauer

    2002-01-01

    Poole. Radical Religion from Shakespeare to Milton: Figures of Nonconformity in Early Modern England. Cambridge: Cambridge University Press, 2000. xiii + 272 pp. $59.95. Review by ELIZABETH SAUER, BROCK UNIVERSITY. While early modern radical...

  20. The chemistry of OH and HO2 radicals in the boundary layer over the tropical Atlantic Ocean

    E-Print Network [OSTI]

    2010-01-01

    J. M. C. : Peroxy radical chemistry and the control of ozoneImpact of halogen monoxide chemistry upon boundary layer OHL. K. Whalley et al. : Chemistry of OH and HO 2 radicals

  1. Tank waste remediation system retrieval and disposal mission readiness-to-proceed responses to internal independent assessment

    SciTech Connect (OSTI)

    Schaus, P.S.

    1998-01-06

    The US Department of Energy (DOE) is planning to make critical decisions during fiscal year (FY) 1998 regarding privatization contracts for the treatment of Hanford tank waste. Specifically, DOE, Richland Operations Office (RL), will make decisions related to proceeding with Phase 1 Privatization. In support of these decisions, the management and integration (M+I) contractor must be able to meet the requirements to support the Phase 1 privatization contractors. As part of the assessment of the Tank Waste Retrieval (TWR) Readiness-To-Proceed (RTP), an independent review of their process and products was required by the RL letter of August 8, 1997. The Independent Review Team reviewed the adequacy of the planning that has been done by the M+I contractor to validate that, if the plans are carried out, there is reasonable assurance of success. Overall, the RTP Independent Review Team concluded that, if the planning by the M+I contractor team is carried out with adequate funding, there is reasonable assurance that the M+I contractor will be able to deliver waste to the privatization contractor for the duration of Phase 1. This conclusion was based on addressing the recommendations contained in the Independent Review Team`s Final Report and in the individual Criteria and Review Approach (CRA) forms completed during the assessment. The purpose of this report is to formally document the independent assessment and the RTP team responses to the Independent Review Team recommendations. It also provides closure logics for selected recommendations from a Lockheed Martin Hanford Corporation (LMHC) internal assessment of the Technical Basis Review (TBR) packages. This report contains the RTP recommendation closure process (Section 2.0); the closure tables (Section 3.0) which provide traceability between each review team recommendation and its corresponding Project Hanford Management Contract closure logic; and two attachments that formally document the Independent Review Team Final Report and the Internal Assessment Final Report.

  2. Experimental and theoretical study of the gas phase reaction of ethynyl radical with methane HCBC CH4

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    Experimental and theoretical study of the gas phase reaction of ethynyl radical with methane HCBC September 2000 Abstract Absolute rate coecients of the reaction of ethynyl radical with methane were importance. In this work, we set out to investigate the reactivity of ethynyl radicals to- wards methane

  3. Biochemistry 1990, 29, 8017-8019 8017 Reaction of Single-Stranded DNA with Hydroxyl Radical Generated by

    E-Print Network [OSTI]

    Martin, Craig T.

    Biochemistry 1990, 29, 8017-8019 8017 Reaction of Single-Stranded DNA with Hydroxyl Radical are consistent with reaction of the hydroxyl radical with the bases in single-stranded DNA (although reaction that hydroxyl radicals may react preferentially with the nucleic acid bases in ssDNA and that reaction

  4. 614 Biochemistry 1994, 33, 614-621 Hydroxyl Radical Footprinting of Calicheamicin. Relationship of DNA Binding to

    E-Print Network [OSTI]

    Tullius, Thomas D.

    614 Biochemistry 1994, 33, 614-621 Hydroxyl Radical Footprinting of Calicheamicin. Relationship the method of hydroxyl radical footprinting. The drug binding sites determined in this way were compared sites of calicheamicin binding, determined by the hydroxyl radical footprinting method (Tullius

  5. Biochemistry 1990, 29, 6043-6050 6043 Detection of Drug Binding to DNA by Hydroxyl Radical Footprinting.

    E-Print Network [OSTI]

    Tullius, Thomas D.

    Biochemistry 1990, 29, 6043-6050 6043 Detection of Drug Binding to DNA by Hydroxyl Radical Manuscript Received March 29, 1990 ABSTRACT: We report the use of hydroxyl radical footprinting to analyze difference in the hydroxyl radical footprints of the two drugs. Distamycin gives a conventional (albeit high

  6. Thermodynamics of the Hydroxyl Radical Addition to Isoprene Marco A. Allodi, Karl N. Kirschner,*, and George C. Shields*,

    E-Print Network [OSTI]

    Blake, Geoffrey

    Thermodynamics of the Hydroxyl Radical Addition to Isoprene Marco A. Allodi, Karl N. Kirschner Oxidation of isoprene by the hydroxyl radical leads to tropospheric ozone formation. Consequently, a more common first step in the oxidation of isoprene is the formation of an adduct, with the hydroxyl radical

  7. Nuclear Energy Readiness Indicator Index (NERI): A benchmarking tool for assessing nuclear capacity in developing countries

    SciTech Connect (OSTI)

    Saum-Manning,L.

    2008-07-13

    Declining natural resources, rising oil prices, looming climate change and the introduction of nuclear energy partnerships, such as GNEP, have reinvigorated global interest in nuclear energy. The convergence of such issues has prompted countries to move ahead quickly to deal with the challenges that lie ahead. However, developing countries, in particular, often lack the domestic infrastructure and public support needed to implement a nuclear energy program in a safe, secure, and nonproliferation-conscious environment. How might countries become ready for nuclear energy? What is needed is a framework for assessing a country's readiness for nuclear energy. This paper suggests that a Nuclear Energy Readiness Indicator (NERI) Index might serve as a meaningful basis for assessing a country's status in terms of progress toward nuclear energy utilization under appropriate conditions. The NERI Index is a benchmarking tool that measures a country's level of 'readiness' for nonproliferation-conscious nuclear energy development. NERI first identifies 8 key indicators that have been recognized by the International Atomic Energy Agency as key nonproliferation and security milestones to achieve prior to establishing a nuclear energy program. It then measures a country's progress in each of these areas on a 1-5 point scale. In doing so NERI illuminates gaps or underdeveloped areas in a country's nuclear infrastructure with a view to enable stakeholders to prioritize the allocation of resources toward programs and policies supporting international nonproliferation goals through responsible nuclear energy development. On a preliminary basis, the indicators selected include: (1) demonstrated need; (2) expressed political support; (3) participation in nonproliferation and nuclear security treaties, international terrorism conventions, and export and border control arrangements; (4) national nuclear-related legal and regulatory mechanisms; (5) nuclear infrastructure; (6) the utilization of IAEA technical assistance; (7) participation in regional arrangements; and (8) public support for nuclear power. In this paper, the Index aggregates the indicators and evaluates and compares the level of readiness in seven countries that have recently expressed various degrees of interest in establishing a nuclear energy program. The NERI Index could be a valuable tool to be utilized by: (1) country officials who are considering nuclear power; (2) the international community, desiring reassurance of a country's capacity for the peaceful, safe, and secure use of nuclear energy; (3) foreign governments/NGO's, seeking to prioritize and direct resources toward developing countries; and (4) private stakeholders interested in nuclear infrastructure investment opportunities.

  8. Coherent chemical kinetics as quantum walks I: Reaction operators for radical pairs

    E-Print Network [OSTI]

    A. Chia; A. Gorecka; K. C. Tan; L. Pawela; P. Kurzynski; T. Paterek; D. Kaszlikowski

    2015-06-13

    Classical chemical kinetics use rate-equation models to describe how a reaction proceeds in time. Such models are sufficient for describing state transitions in a reaction where coherences between different states do not arise, or in other words, a reaction which contain only incoherent transitions. A prominent example reaction containing coherent transitions is the radical-pair model. The kinetics of such reactions is defined by the so-called reaction operator which determines the radical-pair state as a function of intermediate transition rates. We argue that the well-known concept of quantum walks from quantum information theory is a natural and apt framework for describing multisite chemical reactions. By composing Kraus maps that act only on two sites at a time, we show how the quantum-walk formalism can be applied to derive a reaction operator for the standard avian radical-pair reaction. Our reaction operator predicts a recombination dephasing rate consistent with recent experiments [J. Chem. Phys. {\\bf 139}, 234309 (2013)], in contrast to previous work by Jones and Hore [Chem. Phys. Lett. {\\bf 488}, 90 (2010)]. The standard radical-pair reaction has conventionally been described by either a normalised density operator incorporating both the radical pair and reaction products, or by a trace-decreasing density operator that considers only the radical pair. We demonstrate a density operator that is both normalised and refers only to radical-pair states. Generalisations to include additional dephasing processes and an arbitrary number of sites are also discussed.

  9. OH radicals distribution in an Ar-H{sub 2}O atmospheric plasma jet

    SciTech Connect (OSTI)

    Li, L.; Leys, C.; Nikiforov, A.; Institute of Solution Chemistry of the Russian Academy of Sciences, Academicheskaya St., 1, Ivanono, 153045 ; Xiong, Q.; College of Electrical and Electronic Engineering, HuaZhong University of Science and Technology, WuHan, Hubei 430074 ; Britun, N.; Snyders, R.; Materia Nova Research Centre, Parc Initialis, B-7000 Mons ; Lu, X.

    2013-09-15

    Recently, plasma jet systems found numerous applications in the field of biomedicine and treatment of temperature-sensitive materials. OH radicals are one of the main active species produced by these plasmas. Present study deals with the investigation of RF atmospheric pressure plasma jet in terms of OH radicals production by admixture of H{sub 2}O into argon used as a feed gas. Generation of OH radicals is studied by laser-induced fluorescence spectroscopy. The excitation dynamics of OH radicals induced by the laser photons is studied by time-resolved spectroscopy. It is shown that vibrational and rotational energy transfer processes, which are sensitive to the surrounding species, can lead to the complication in the OH radicals diagnostics at high pressure and have to be considered during experiments. The axial and radial 2D maps of absolute densities of hydroxyl radicals at different water contents are obtained. The highest density of 1.15 × 10{sup 20} m{sup ?3} is measured in the plasma core for the case of 0.3% H{sub 2}O. In the x–y-plane, the OH density steeply decreases within a range of ±2 mm from its maximum value down to 10{sup 18} m{sup ?3}. The effect of H{sub 2}O addition on the generation of OH radicals is investigated and discussed.

  10. Coherent chemical kinetics as quantum walks I: Reaction operators for radical pairs

    E-Print Network [OSTI]

    A. Chia; A. Gorecka; K. C. Tan; L. Pawela; P. Kurzynski; T. Paterek; D. Kaszlikowski

    2015-08-20

    Classical chemical kinetics use rate-equation models to describe how a reaction proceeds in time. Such models are sufficient for describing state transitions in a reaction where coherences between different states do not arise, or in other words, a reaction which contain only incoherent transitions. A prominent example reaction containing coherent transitions is the radical-pair model. The kinetics of such reactions is defined by the so-called reaction operator which determines the radical-pair state as a function of intermediate transition rates. We argue that the well-known concept of quantum walks from quantum information theory is a natural and apt framework for describing multisite chemical reactions. By composing Kraus maps that act only on two sites at a time, we show how the quantum-walk formalism can be applied to derive a reaction operator for the standard avian radical-pair reaction. Our reaction operator predicts a recombination dephasing rate consistent with recent experiments [J. Chem. Phys. {\\bf 139}, 234309 (2013)], in contrast to previous work by Jones and Hore [Chem. Phys. Lett. {\\bf 488}, 90 (2010)]. The standard radical-pair reaction has conventionally been described by either a normalised density operator incorporating both the radical pair and reaction products, or by a trace-decreasing density operator that considers only the radical pair. We demonstrate a density operator that is both normalised and refers only to radical-pair states. Generalisations to include additional dephasing processes and an arbitrary number of sites are also discussed.

  11. Radical Coupling Reactions in Lignin Synthesis: A Density Functional Theory Study

    SciTech Connect (OSTI)

    Sangha, A. K.; Parks, J. M.; Standaert, R. F.; Ziebell, A.; Davis, M.; Smith, J. C.

    2012-04-26

    Lignin is a complex, heterogeneous polymer in plant cell walls that provides mechanical strength to the plant stem and confers resistance to degrading microbes, enzymes, and chemicals. Lignin synthesis initiates through oxidative radical-radical coupling of monolignols, the most common of which are p-coumaryl, coniferyl, and sinapyl alcohols. Here, we use density functional theory to characterize radical-radical coupling reactions involved in monolignol dimerization. We compute reaction enthalpies for the initial self- and cross-coupling reactions of these monolignol radicals to form dimeric intermediates via six major linkages observed in natural lignin. The 8-O-4, 8-8, and 8-5 coupling are computed to be the most favorable, whereas the 5-O-4, 5-5, and 8-1 linkages are less favorable. Overall, p-coumaryl self- and cross-coupling reactions are calculated to be the most favorable. For cross-coupling reactions, in which each radical can couple via either of the two sites involved in dimer formation, the more reactive of the two radicals is found to undergo coupling at its site with the highest spin density.

  12. Progress toward Producing Demand-Response-Ready Appliances

    SciTech Connect (OSTI)

    Hammerstrom, Donald J.; Sastry, Chellury

    2009-12-01

    This report summarizes several historical and ongoing efforts to make small electrical demand-side devices like home appliances more responsive to the dynamic needs of electric power grids. Whereas the utility community often reserves the word demand response for infrequent 2 to 6 hour curtailments that reduce total electrical system peak load, other beneficial responses and ancillary services that may be provided by responsive electrical demand are of interest. Historically, demand responses from the demand side have been obtained by applying external, retrofitted, controlled switches to existing electrical demand. This report is directed instead toward those manufactured products, including appliances, that are able to provide demand responses as soon as they are purchased and that require few, or no, after-market modifications to make them responsive to needs of power grids. Efforts to be summarized include Open Automated Demand Response, the Association of Home Appliance Manufacturer standard CHA 1, a simple interface being developed by the U-SNAP Alliance, various emerging autonomous responses, and the recent PinBus interface that was developed at Pacific Northwest National Laboratory.

  13. Roaming radical kinetics in the decomposition of acetaldehyde.

    SciTech Connect (OSTI)

    Harding, L. B.; Georgievskii, Y.; Klippenstein, S. J.; Chemical Sciences and Engineering Division

    2010-01-01

    A novel theoretical framework for predicting the branching between roaming and bond fission channels in molecular dissociations is described and applied to the decomposition of acetaldehyde. This reduced dimensional trajectory (RDT) approach, which is motivated by the long-range nature of the roaming, bond fission, and abstraction dynamical bottlenecks, involves the propagation of rigid-body trajectories on an analytic potential energy surface. The analytic potential is obtained from fits to large-scale multireference ab initio electronic structure calculations. The final potential includes one-dimensional corrections from higher-level electronic structure calculations and for the effect of conserved mode variations along both the addition and abstraction paths. The corrections along the abstraction path play a significant role in the predicted branching. Master equation simulations are used to transform the microcanonical branching ratios obtained from the RDT simulations to the temperature- and pressure-dependent branching ratios observed in thermal decomposition experiments. For completeness, a transition-state theory treatment of the contributions of the tight transition states for the molecular channels is included in the theoretical analyses. The theoretically predicted branching between molecules and radicals in the thermal decomposition of acetaldehyde is in reasonable agreement with the corresponding shock tube measurement described in the companion paper. The prediction for the ratio of the tight to roaming contributions to the molecular channel also agrees well with results extracted from recent experimental and experimental/theoretical photodissociation studies.

  14. Radical-cured block copolymer-modified thermosets

    SciTech Connect (OSTI)

    Redline, Erica M.; Francis, Lorraine F.; Bates, Frank S.

    2013-01-10

    Poly(ethylene-alt-propylene)-b-poly(ethylene oxide) (PEP-PEO) diblock copolymers were synthesized and added at 4 wt % to 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane (BisGMA), a monomer that cures using free radical chemistry. In separate experiments, poly(ethylene glycol) dimethacrylate (PEGDMA) was combined as a secondary monomer with BisGMA and the monomers were loaded with 4 wt % PEP-PEO. The diblock copolymers self-assembled into well-dispersed spherical micelles with PEP cores and PEO coronas. No appreciable change in the final extent of cure of the thermosets was caused by the addition of diblock copolymer, except in the case of BisGMA, where the addition of the block copolymer increased extent of cure by 12%. Furthermore, the extent of cure was increased by 29% and 37% with the addition of 25 and 50 wt % PEGDMA, respectively. Elastic modulus and fracture resistance were also determined, and the values indicate that the addition of block copolymers does not significantly toughen the thermoset materials. This finding is surprising when compared with the large increase in fracture resistance seen in block copolymer-modified epoxies, and an explanation is proposed.

  15. Etching radical controlled gas chopped deep reactive ion etching

    DOE Patents [OSTI]

    Olynick, Deidre; Rangelow, Ivo; Chao, Weilun

    2013-10-01

    A method for silicon micromachining techniques based on high aspect ratio reactive ion etching with gas chopping has been developed capable of producing essentially scallop-free, smooth, sidewall surfaces. The method uses precisely controlled, alternated (or chopped) gas flow of the etching and deposition gas precursors to produce a controllable sidewall passivation capable of high anisotropy. The dynamic control of sidewall passivation is achieved by carefully controlling fluorine radical presence with moderator gasses, such as CH.sub.4 and controlling the passivation rate and stoichiometry using a CF.sub.2 source. In this manner, sidewall polymer deposition thicknesses are very well controlled, reducing sidewall ripples to very small levels. By combining inductively coupled plasmas with controlled fluorocarbon chemistry, good control of vertical structures with very low sidewall roughness may be produced. Results show silicon features with an aspect ratio of 20:1 for 10 nm features with applicability to nano-applications in the sub-50 nm regime. By comparison, previous traditional gas chopping techniques have produced rippled or scalloped sidewalls in a range of 50 to 100 nm roughness.

  16. Time-resolved FTIR emission studies of laser photofragmentation and radical reactions

    SciTech Connect (OSTI)

    Leone, S.R. [Univ. of Colorado, Boulder (United States)

    1993-12-01

    Recent studies have focused specifically on collision processes, such as single collision energy transfer, reaction dynamics, and radical reactions. The authors employ novel FTIR techniques in the study of single collision energy transfer processes using translationally fast H atom, as well as radical-radical reactions, e.g. CH{sub 3} + O, CF{sub 3} + H(D), and Cl + C{sub 2}H{sub 5}. The fast atoms permit unique high energy regions of certain transition states of combustion species to be probed for the first time.

  17. UTILITY ADVANCED TURBINE SYSTEMS (ATS) TECHNOLOGY READINESS TESTING

    SciTech Connect (OSTI)

    Unknown

    1999-10-01

    The overall objective of the Advanced Turbine System (ATS) Phase 3 Cooperative Agreement between GE and the U.S. Department of Energy (DOE) is the development of a highly efficient, environmentally superior, and cost-competitive utility ATS for base-load utility-scale power generation, the GE 7H (60 Hz) combined cycle power system, and related 9H (50 Hz) common technology. The major effort will be expended on detail design. Validation of critical components and technologies will be performed, including: hot gas path component testing, sub-scale compressor testing, steam purity test trials, and rotational heat transfer confirmation testing. Processes will be developed to support the manufacture of the first system, which was to have been sited and operated in Phase 4 but will now be sited and operated commercially by GE. This change has resulted from DOE's request to GE for deletion of Phase 4 in favor of a restructured Phase 3 (as Phase 3R) to include full speed, no load (FSNL) testing of the 7H gas turbine. Technology enhancements that are not required for the first machine design but will be critical for future ATS advances in performance, reliability, and costs will be initiated. Long-term tests of materials to confirm design life predictions will continue. A schematic of the GE H machine is shown in Figure 1-1. Information specifically related to 9H production is presented for continuity in H program reporting, but lies outside the ATS program. This report summarizes work accomplished from 4Q98 through 3Q99. The most significant accomplishments are listed.

  18. Building Simulation Modelers are we big-data ready?

    SciTech Connect (OSTI)

    Sanyal, Jibonananda; New, Joshua Ryan

    2014-01-01

    Recent advances in computing and sensor technologies have pushed the amount of data we collect or generate to limits previously unheard of. Sub-minute resolution data from dozens of channels is becoming increasingly common and is expected to increase with the prevalence of non-intrusive load monitoring. Experts are running larger building simulation experiments and are faced with an increasingly complex data set to analyze and derive meaningful insight. This paper focuses on the data management challenges that building modeling experts may face in data collected from a large array of sensors, or generated from running a large number of building energy/performance simulations. The paper highlights the technical difficulties that were encountered and overcome in order to run 3.5 million EnergyPlus simulations on supercomputers and generating over 200 TBs of simulation output. This extreme case involved development of technologies and insights that will be beneficial to modelers in the immediate future. The paper discusses different database technologies (including relational databases, columnar storage, and schema-less Hadoop) in order to contrast the advantages and disadvantages of employing each for storage of EnergyPlus output. Scalability, analysis requirements, and the adaptability of these database technologies are discussed. Additionally, unique attributes of EnergyPlus output are highlighted which make data-entry non-trivial for multiple simulations. Practical experience regarding cost-effective strategies for big-data storage is provided. The paper also discusses network performance issues when transferring large amounts of data across a network to different computing devices. Practical issues involving lag, bandwidth, and methods for synchronizing or transferring logical portions of the data are presented. A cornerstone of big-data is its use for analytics; data is useless unless information can be meaningfully derived from it. In addition to technical aspects of managing big data, the paper details design of experiments in anticipation of large volumes of data. The cost of re-reading output into an analysis program is elaborated and analysis techniques that perform analysis in-situ with the simulations as they are run are discussed. The paper concludes with an example and elaboration of the tipping point where it becomes more expensive to store the output than re-running a set of simulations.

  19. Structural insight into the assembly of iron-sulfur clusters and their function in radical generation

    E-Print Network [OSTI]

    Vey, Jessica L. (Jessica Lynn)

    2008-01-01

    This thesis addresses two emerging areas in the study of iron-sulfur cluster biochemistry: bioassembly of iron-sulfur clusters, and their involvement in initiation of radical chemistry. The structure of a cysteine desulfurase ...

  20. Synthesis of a Water-Soluble 1,3-Bis(diphenylene)2-phenylallyl Radical

    E-Print Network [OSTI]

    Swager, Timothy Manning

    The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear ...

  1. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore »cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  2. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zheng, Jianming [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Walter, Eric [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pan, Huilin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Lv, Dongping [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zuo, Pengjian [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Chen, Honghao [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Deng, Z. D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liaw, Bor Y. [School of Ocean and Earth Science and Technology, Hawaii Natural Energy Institute, (United States); Yu, Xiqian [Brookhaven National Laboratory, Upton, NY (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Upton, NY (United States); Zhang, Ji-Guang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liu, Jun [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Xiao, Jie [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  3. Asymmetry of will : the effect of religious radicalism on state military doctrine

    E-Print Network [OSTI]

    Lewis, Patrick (Patrick Joseph)

    2012-01-01

    How is a state's military doctrine affected by the presence of radical religious ideology in its military? Using analysis of satellite imagery, recent military exercises, and a series of source interviews, I examine the ...

  4. Chemistry of Secondary Organic Aerosol Formation From the Reaction of Hydroxyl Radicals With Aromatic Compounds

    E-Print Network [OSTI]

    Strollo Gordon, Christen Michelle

    2013-01-01

    C(O)OR Carboxyl C(O)OH Hydroxyl CHOH Peroxide ROOH E1 NA 1oxidation of toluene with hydroxyl radicals. Atmos. Environ.relevant isoprene-derived hydroxyl epoxides. Environ. Sci.

  5. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  6. Water-Soluble Narrow-Line Radicals for Dynamic Nuclear Polarization

    E-Print Network [OSTI]

    Haze, Olesya

    The synthesis of air-stable, highly water-soluble organic radicals containing a 1,3-bis(diphenylene)-2-phenylallyl (BDPA) core is reported. A sulfonated derivative, SA-BDPA, retains the narrow electron paramagnetic resonance ...

  7. Oxidative capacity of the Mexico City atmosphere - Part 1: A radical source perspective

    E-Print Network [OSTI]

    Volkamer, R.

    A detailed analysis of OH, HO2 [HO subscript 2] and RO2 [RO subscript 2] radical sources is presented for the near field photochemical regime inside the Mexico City Metropolitan Area (MCMA). During spring of 2003 (MCMA-2003 ...

  8. Spin-selective recombination reactions of radical pairs: Experimental test of validity of reaction operators

    SciTech Connect (OSTI)

    Maeda, Kiminori [Department of Chemistry, University of Oxford, Centre for Advanced Electron Spin Resonance, Inorganic Chemistry Laboratory, Oxford (United Kingdom)] [Department of Chemistry, University of Oxford, Centre for Advanced Electron Spin Resonance, Inorganic Chemistry Laboratory, Oxford (United Kingdom); Liddell, Paul; Gust, Devens [Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona, 85287-1604 (United States)] [Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona, 85287-1604 (United States); Hore, P. J. [Department of Chemistry, University of Oxford, Physical and Theoretical Chemistry Laboratory, Oxford (United Kingdom)] [Department of Chemistry, University of Oxford, Physical and Theoretical Chemistry Laboratory, Oxford (United Kingdom)

    2013-12-21

    Spin-selective reactions of radical pairs are conventionally modelled using an approach that dates back to the 1970s [R. Haberkorn, Mol. Phys. 32, 1491 (1976)]. An alternative approach based on the theory of quantum measurements has recently been suggested [J. A. Jones and P. J. Hore, Chem. Phys. Lett. 488, 90 (2010)]. We present here the first experimental attempt to discriminate between the two models. Pulsed electron paramagnetic resonance spectroscopy has been used to investigate intramolecular electron transfer in the radical pair form of a carotenoid-porphyrin-fullerene molecular triad. The rate of spin-spin relaxation of the fullerene radical in the triad was found to be inconsistent with the quantum measurement description of the spin-selective kinetics, and in accord with the conventional model when combined with spin-dephasing caused by rotational modulation of the anisotropic g-tensor of the fullerene radical.

  9. Nighttime Measurements of Dinitrogen Pentoxide and the Nitrate Radical via Cavity Ring-Down Spectroscopy 

    E-Print Network [OSTI]

    Perkins, Katie C.

    2010-10-12

    technique, known as cavity ring-down spectroscopy, will be introduced for simultaneously measuring the nitrate radical and dinitrogen pentoxide. The cavity ring-down spectrometer was initially designed and constructed based on the experiments by Steven Brown...

  10. Radical Democracy in the thought and work of Paulo Freire and Luis Villoro 

    E-Print Network [OSTI]

    Diaz, Kim

    2012-07-16

    This project explores democracy as a way of life (radical democracy) by drawing from both North and Latin American philosophers. I work with ideas from Paulo Freire (Brazil) and Luis Villoro (Mexico) to develop (a) a ...

  11. Reaction operators for spin-selective chemical reactions of radical pairs

    E-Print Network [OSTI]

    Jonathan A. Jones; Kiminori Maeda; Peter J. Hore

    2011-03-30

    Spin-selective reactions of radical pairs have traditionally been modelled theoretically by adding phenomenological rate equations to the quantum mechanical equation of motion of the radical pair spin density matrix. More recently an alternative set of rate expressions, based on a quantum measurement approach, has been suggested. Here we show how these two reaction operators can be seen as limiting cases of a more general reaction scheme.

  12. Membrane Separator for Redox Flow Batteries that Utilize Anion Radical Mediators.

    SciTech Connect (OSTI)

    Delnick, Frank M.

    2014-10-01

    A Na + ion conducting polyethylene oxide membrane is developed for an organic electrolyte redox flow battery that utilizes anion radical mediators. To achieve high specific ionic conductivity, tetraethyleneglycol dimethylether (TEGDME) is used as a plasticizer to reduce crystallinity and increase the free volume of the gel film. This membrane is physically and chemically stable in TEGDME electrolyte that contains highly reactive biphenyl anion radical mediators.

  13. DOE Zero Energy Ready Home Case Study: The Imery Group — Proud Green Home, Serenbe, GA

    SciTech Connect (OSTI)

    none,

    2014-09-01

    The first certified Zero Energy Ready Home in Georgia was honored in the Custom Builder category of the 2014 Housing Innovation Awards. The 2,811-ft2, two-story custom home has 2x6 advanced framed walls filled with R-20 of open-cell spray foam, plus an R-6.6 insulated coated OSB sheathing. Also included is electronic monitoring equipment that tracks the PV, solar thermal water heater, ERV, mini-split heat pump with three indoor heads, solar water heater, and LED and CFL lighting.

  14. Data Center Energy Efficiency and Renewable Energy Site Assessment: Anderson Readiness Center; Salem, Oregon

    SciTech Connect (OSTI)

    Metzger, I.; Van Geet, O.

    2014-06-01

    This report summarizes the results from the data center energy efficiency and renewable energy site assessment conducted for the Oregon Army National Guard in Salem, Oregon. A team led by NREL conducted the assessment of the Anderson Readiness Center data centers March 18-20, 2014 as part of ongoing efforts to reduce energy use and incorporate renewable energy technologies where feasible. Although the data centers in this facility account for less than 5% of the total square footage, they are estimated to be responsible for 70% of the annual electricity consumption.

  15. DOE Zero Energy Ready Home Case Study: Healthy Efficient Homes - Spirit Lake, Iowa

    SciTech Connect (OSTI)

    none,

    2014-11-01

    This case study describes a DOE Zero Energy Ready Home in Spirit Lake, Iowa, that scored HERS 41 without PV and HERS 28 with PV. This 3,048 ft2 custom home has advanced framed walls filled with 1.5 inches closed-cell spray foam, a vented attic with spray foam-sealed top plates and blown fiberglass over the ceiling deck. R-23 basement walls are ICF plus two 2-inch layers of EPS. The house also has a mini-split heat pump, fresh air fan intake, and a solar hot water heater.

  16. DOE Zero Energy Ready Home Case Study: Durable Energy Builders - Houston, Texas

    SciTech Connect (OSTI)

    none,

    2014-11-01

    This case study describes a DOE Zero Energy Ready Home in Houston, Texas, that scored HERS 39 without PV and HERS 29 with PV. This 5,947 ft2 custom home has 11.5-inch ICF walls. The attic is insulated along the roof line with 5 to 7 inches of open-cell spray foam. Most of the home's drinking water is supplied by a 11,500-gallon rainwater cistern. Hurricane strapping connects the roof to the walls. The triple-pane windows are impact resistant. The foundation is a raised slab.

  17. DOE Zero Energy Ready Home Case Study: Near Zero Maine Home II - Vassalboro, Maine

    SciTech Connect (OSTI)

    none,

    2014-11-01

    This case study describes a DOE Zero Energy Ready home in Vassalboro, Maine, that scored HERS 35 without PV and HERS 11 with PV. This 1,200 ft2 home has 10.5-inch-thick double-walls with 3 layers of mineral wool batt insulation, an R-20 insulated slab, R-70 cellulose in the attic, extensive air sealing, a mini-split heat pump, an heat recovery ventilator, solar water heating, LED lighting, 3.9 kWh PV, and triple-pane windows.

  18. DOE Zero Energy Ready Home Case Study: Shore Road Project - Old Greenwich, Connecticut

    SciTech Connect (OSTI)

    none,

    2014-11-01

    This case study describes a DOE Zero Energy Ready Home in Old Greenwich, CT, that scored HERS 40 without PV and HERS 27 with PV. This 4,100 ft2 custom home has 13-inch ICF basement walls and 11-inch ICF above-grade walls with a closed-cell spray foam-insulated roof deck, and a continuously running ERV. The house has a dual-fuel heat pump, an instantaneous condensing water heater, and 4.5-kW solar shingles.

  19. AVTA: Reports on Plug-in Electric Vehicle Readiness at 3 DOD Facilities

    Broader source: Energy.gov [DOE]

    The Vehicle Technologies Office's Advanced Vehicle Testing Activity carries out testing on a wide range of advanced vehicles and technologies on dynamometers, closed test tracks, and on-the-road. These results provide benchmark data that researchers can use to develop technology models and guide future research and development. The following reports analyze data and survey results on readiness for the use of plug-in electric vehicles on the Naval Air Station Jacksonville, Naval Station Mayport, and Joint Base Lewis McChord, as informed by the AVTA's testing on plug-in electric vehicle charging equipment. This research was conducted by Idaho National Laboratory.

  20. DOE Zero Energy Ready Home Case Study: Montlake Modern - Seattle, Washington

    SciTech Connect (OSTI)

    none,

    2014-11-01

    This case study describes a DOE Zero Energy Ready Home in Seattle, WA, that scored HERS 42 without PV and a -1 with PV. This 3,192 ft2 custom home has 6-inch SIP walls, a 12-inch SIP roof, an R-28 ICF-insulated foundation slab edge with R-20 rigid foam under the slab; an air-to-water heat pump plus radiant floor heat; 100% LED lighting; filtered-fan-powered fresh air intake; triple-pane windows, 9.7 kWh PV for electric car charging station.

  1. Calmodulin Methionine Residues are Targets For One-Electron Oxidation by Hydroxyl Radicals: Formation of S therefore N three-electron bonded Radical Complexes

    SciTech Connect (OSTI)

    Nauser, Thomas; Jacoby, Michael E.; Koppenol, Willem H.; Squier, Thomas C.; Schoneich, Christian

    2005-02-01

    The one-electron (1e) oxidation of organic sulfides and methionine (Met) constitutes an important reaction mechanism in vivo.1,2 Evidence for a Cu(II)-catalyzed oxidation of Met35 in the Alzheimer's disease -amyloid peptide was obtained,3 and, based on theoretical studies, Met radical cations were proposed as intermediates.4 In the structure of -amyloid peptide, the formation of Met radical cations appears to be facilitated by a preexisting close sulfur-oxygen (S-O) interaction between the Met35 sulfur and the carbonyl oxygen of the peptide bond C-terminal to Ile31.5 Substitution of Ile31 with Pro31 abolishes this S-O interaction,5 significantly reducing the ability of -amyloid to reduce Cu(II), and converts the neurotoxic wild-type -amyloid into a non-toxic peptide.6 The preexisting S-O bond characterized for wild-type -amyloid suggests that electron transfer from Met35 to Cu(II) is supported through stabilization of the Met radical cation by the electron-rich carbonyl oxygen, generating an SO-bonded7 sulfide radical cation (Scheme 1, reaction 1).5

  2. OM Code Requirements For MOVs -- OMN-1 and Appendix III

    SciTech Connect (OSTI)

    Kevin G. DeWall

    2011-08-01

    The purpose or scope of the ASME OM Code is to establish the requirements for pre-service and in-service testing of nuclear power plant components to assess their operational readiness. For MOVs this includes those that perform a specific function in shutting down a reactor to the safe shutdown condition, maintaining the safe shutdown condition, and mitigating the consequences of an accident. This paper will present a brief history of industry and regulatory activities related to MOVs and the development of Code requirements to address weaknesses in earlier versions of the OM Code. The paper will discuss the MOV requirements contained in the 2009 version of ASME OM Code, specifically Mandatory Appendix III and OMN-1, Revision 1.

  3. The Navy must be ready to fight and win today, while building the ability to prevail into the future. Education is our asymmetric advantage in developing

    E-Print Network [OSTI]

    CONCLUSION The Navy must be ready to fight and win today, while building the ability to prevail. Be Ready. #12;INTRODUCTION Sailors and naval officers­our warfighting force­ constitute the Navy's most prized and valuable resource. Education is our Navy's strategic investment to enhance effectiveness

  4. Use of Residual Solids from Pulp and Paper Mills for Enhancing Strength and Durability of Ready-Mixed Concrete

    SciTech Connect (OSTI)

    Tarun R. Naik; Yoon-moon Chun; Rudolph N. Kraus

    2003-09-18

    This research was conducted to establish mixture proportioning and production technologies for ready-mixed concrete containing pulp and paper mill residual solids and to study technical, economical, and performance benefits of using the residual solids in the concrete. Fibrous residuals generated from pulp and paper mills were used, and concrete mixture proportions and productions technologies were first optimized under controlled laboratory conditions. Based on the mixture proportions established in the laboratory, prototype field concrete mixtures were manufactured at a ready-mixed concrete plant. Afterward, a field construction demonstration was held to demonstrate the production and placement of structural-grade cold-weather-resistant concrete containing residual solids.

  5. New Developments in the Technology Readiness Assessment Process in US DOE-EM - 13247

    SciTech Connect (OSTI)

    Krahn, Steven; Sutter, Herbert; Johnson, Hoyt

    2013-07-01

    A Technology Readiness Assessment (TRA) is a systematic, metric-based process and accompanying report that evaluates the maturity of the technologies used in systems; it is designed to measure technology maturity using the Technology Readiness Level (TRL) scale pioneered by the National Aeronautics and Space Administration (NASA) in the 1980's. More recently, DoD has adopted and provided systematic guidance for performing TRAs and determining TRLs. In 2007 the GAO recommended that the DOE adopt the NASA/DoD methodology for evaluating technology maturity. Earlier, in 2006-2007, DOE-EM had conducted pilot TRAs on a number of projects at Hanford and Savannah River. In March 2008, DOE-EM issued a process guide, which established TRAs as an integral part of DOE-EM's Project Management Critical Decision Process. Since the development of its detailed TRA guidance in 2008, DOE-EM has continued to accumulate experience in the conduct of TRAs and the process for evaluating technology maturity. DOE has developed guidance on TRAs applicable department-wide. DOE-EM's experience with the TRA process, the evaluations that led to recently developed proposed revisions to the DOE-EM TRA/TMP Guide; the content of the proposed changes that incorporate the above lessons learned and insights are described. (authors)

  6. Readiness Assurance

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4) August 20123/%2A en NNSA

  7. Fuel-Flexible Gasification-Combustion Technology for Production of H2 and Sequestration-Ready CO2

    SciTech Connect (OSTI)

    George Rizeq; Parag Kulkarni; Wei Wei; Arnaldo Frydman; Thomas McNulty; Roger Shisler

    2005-11-01

    It is expected that in the 21st century the Nation will continue to rely on fossil fuels for electricity, transportation, and chemicals. It will be necessary to improve both the process efficiency and environmental impact performance of fossil fuel utilization. GE Global Research is developing an innovative fuel-flexible Unmixed Fuel Processor (UFP) technology to produce H{sub 2}, power, and sequestration-ready CO{sub 2} from coal and other solid fuels. The UFP module offers the potential for reduced cost, increased process efficiency relative to conventional gasification and combustion systems, and near-zero pollutant emissions including NO{sub x}. GE was awarded a contract from U.S. DOE NETL to develop the UFP technology. Work on the Phase I program started in October 2000, and work on the Phase II effort started in April 2005. In the UFP technology, coal and air are simultaneously converted into separate streams of (1) high-purity hydrogen that can be utilized in fuel cells or turbines, (2) sequestration-ready CO{sub 2}, and (3) high temperature/pressure vitiated air to produce electricity in a gas turbine. The process produces near-zero emissions with an estimated efficiency higher than IGCC with conventional CO2 separation. The Phase I R&D program established the feasibility of the integrated UFP technology through lab-, bench- and pilot-scale testing and investigated operating conditions that maximize separation of CO{sub 2} and pollutants from the vent gas, while simultaneously maximizing coal conversion efficiency and hydrogen production. The Phase I effort integrated experimental testing, modeling and preliminary economic studies to demonstrate the UFP technology. The Phase II effort will focus on three high-risk areas: economics, sorbent attrition and lifetime, and product gas quality for turbines. The economic analysis will include estimating the capital cost as well as the costs of hydrogen and electricity for a full-scale UFP plant. These costs will be benchmarked with IGCC polygen costs for plants of similar size. Sorbent attrition and lifetime will be addressed via bench-scale experiments that monitor sorbent performance over time and by assessing materials interactions at operating conditions. The product gas from the third reactor (high-temperature vitiated air) will be evaluated to assess the concentration of particulates, pollutants and other impurities relative to the specifications required for gas turbine feed streams. This is the eighteenth quarterly technical progress report for the UFP program, which is supported by U.S. DOE NETL (Contract No. DE-FC26-00FT40974) and GE. This report summarizes program accomplishments for the Phase II period starting July 01, 2005 and ending September 30, 2005. The report includes an introduction summarizing the UFP technology, main program tasks, and program objectives; it also provides a summary of program activities and accomplishments covering progress in tasks including process modeling, scale-up and economic analysis.

  8. Structural Requirements and Reaction Pathways in Dimethyl Ether Combustion Catalyzed by Supported Pt Clusters

    E-Print Network [OSTI]

    Iglesia, Enrique

    of the elementary steps required for catalytic combustion of dimethyl ether (DME) on Pt clusters were determined in developing economies. Recent studies have addressed steam reforming of DME on supported metal catalysts4-7 and its homogeneous combustion pathways via radical intermedi- ates.8,9 Here, we explore the catalytic

  9. Computational observation of enhanced solvation of the hydroxyl radical with increased NaCl concentration

    SciTech Connect (OSTI)

    Wick, Collin D.; Dang, Liem X.

    2006-05-11

    Classical molecular dynamics simulations with many-body potentials were carried out to quantitatively determine the effect of NaCl salt concentration on the aqueous solvation and surface concentration of hydroxyl radicals. The potential of mean force technique was used to track the incremental free energy of the hydroxyl radical from the vapor, crossing the air-water interface into the aqueous bulk. Results showed increased NaCl salt concentration significantly enhanced hydroxyl radical solvation, which should significantly increase its accommodation on water droplets. This has been experimentally observed for ozone aqueous accommodation with increased NaI concentration, but to our knowledge, no experimental study has probed this for hydroxyl radicals. The origin for this effect was found to be very favorable hydroxyl radical-chloride ion interactions, being stronger than for water-chloride. This work was performed at Pacific Northwest National Laboratory (PNNL) under the auspices of the Division of Chemical Sciences, Office of Basic Energy Sciences, U.S. Department of Energy. Battelle operates PNNL for the Department of Energy.

  10. Phenomenological modelling for Time-Resolved Electron Paramagnetic Resonance in radical-triplet system

    E-Print Network [OSTI]

    Wei Wu

    2015-01-01

    The spin dynamics of radical-triplet system (RTS) has been calculated by using the Lindblad formalism within the theory of open quantum system. The single-radical-triplet system (SRTS) is considered here for single-qubit quantum gate operations while double-radical-triplet system (DRTS) for two-qubit operations. The environment effects taken into account include the spin-lattice relaxation of the triplet exciton and radical spin-$\\frac{1}{2}$, the inter-system crossing process that induces the transition from singlet excited state to the triplet ground state, and the rather slow relaxation process from the triplet ground state back down to the singlet ground state. These calculations shown that the line shape broadening is strongly related to the exchange interaction between triplet and exciton, which can be understood as a spontaneous magnetic field created by the triplet renormalises the original spin-$\\frac{1}{2}$ electron spin resonance spectra. This work will provide key information about the spin dynamics for building optically-controlled molecular quantum gate out of radical-bearing molecules. Moreover, this has generated the further theoretical question on how the mixture of fermion and boson behaves.

  11. Requirements Evolution Empirical Analyses

    E-Print Network [OSTI]

    Felici, Massimo

    Requirements Evolution Empirical Analyses Massimo Felici 18 July 2001, ITC-IRST/ARS, Trento, Italy Massimo Felici Requirements Evolution ITC-IRST/ARS #12;Requirements Evolution 1 Overview · Why Requirements Evolution? · Empirical Requirements Evolution: Two Industrial Case Studies · Discussion

  12. Vehicle Technologies Office Merit Review 2015: Development of Radically Enhanced alnico Magnets (DREaM) for Traction Drive Motors

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Ames Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Development of Radically...

  13. Are PHP Applications Ready for Hack? Laleh Eshkevari, Fabien Dos Santos, James R. Cordy, and Giuliano Antoniol

    E-Print Network [OSTI]

    Cordy, James R.

    Are PHP Applications Ready for Hack? Laleh Eshkevari, Fabien Dos Santos, James R. Cordy be more difficult to understand and the source of many bugs. Hack, a new PHP variant endorsed by Facebook the constraints of Hack's static typing. We report evidence that dynamic typing is actually a relatively uncommon

  14. ScratchJr: Computer programming in early childhood education as a pathway to academic readiness and success

    E-Print Network [OSTI]

    Resnick, Mitchel

    1 ScratchJr: Computer programming in early childhood education as a pathway to academic readiness specifically for early childhood education (K-2). This is an educational segment where there are few powerful project will build on the PI's research on technologies in early childhood education, and on the work

  15. DOE Zero Energy Ready Home Case Study: New Town Builders — The ArtiZEN Plan, Denver, CO

    SciTech Connect (OSTI)

    none,

    2014-09-01

    The Grand Winner in the Production Builder category of the 2014 Housing Innovation Awards, this builder plans to convert all of its product lines to DOE Zero Energy Ready Home construction by the end of 2015. This home achieves HERS 38 without photovoltaics (PV) and HERS -3 with 8.0 kW of PV.

  16. Is the Internet ready for VoIP? Fouad A. Tobagi, Athina P. Markopoulou, Mansour J.Karam

    E-Print Network [OSTI]

    Markopoulou, Athina

    Is the Internet ready for VoIP? Fouad A. Tobagi, Athina P. Markopoulou, Mansour J.Karam Email communication over the Internet (VoIP). If the Internet were to become the universal network for all the packet loss and delay characteristics of today's Internet, in order to understand the effectiveness

  17. POST HOC STUDY OF A STATE SELECTION PROCESS TO PREDICT STATE READINESS TO PARTICIPATE IN SCHOOLWIDE INCLUSIVE SCHOOL REFORM

    E-Print Network [OSTI]

    Mitchiner, Melinda Sue

    2014-12-31

    by the national center for selecting state partners was predictive of state readiness to participate in schoolwide inclusive school reform, and to assess utility of the process for use by other national centers. The state selection process used by the national...

  18. Getting Ready for the Challenges for the Air Traffic Management for Unmanned Aerial Systems (UAS) C.W. Johnson,

    E-Print Network [OSTI]

    Johnson, Chris

    as EUROCONTROL's Spec-0102 on the Use of Military Unmanned Aerial Vehicles as Operational Air Traffic Outside-1- Getting Ready for the Challenges for the Air Traffic Management for Unmanned Aerial Systems's 08-01: Unmanned Aircraft Systems Operations in the U. S. National Airspace System, as well

  19. DOE Zero Energy Ready Home Case Study: One Sky Homes — Cottle Zero Net Energy Home, San Jose, CA

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This builder took home the Grand Winner prize in the Custom Builder category in the 2014 Housing Innovation Awards for its high performance building science approach. The builder used insulated concrete form blocks to create the insulated crawlspace foundation for its first DOE Zero Energy Ready Home, the first net zero energy new home certified in the state of California.

  20. Free radicals induced in aqueous solution by non-contact atmospheric-pressure cold plasma

    SciTech Connect (OSTI)

    Tani, Atsushi; Fukui, Satoshi; Ono, Yusuke; Kitano, Katsuhisa; Ikawa, Satoshi

    2012-06-18

    To understand plasma-induced chemical processing in liquids, we investigated the formation of free radicals in aqueous solution exposed to different types of non-contact atmospheric-pressure helium plasma using the spin-trapping technique. Both hydroxyl radical (OH{center_dot}) and superoxide anion radical (O{sub 2}{sup -}{center_dot}) adducts were observed when neutral oxygen gas was additionally supplied to the plasma. In particular, O{sub 2}{sup -}{center_dot} can be dominantly induced in the solution via oxygen flow into the afterglow gas of helium plasma. This type of plasma treatment can potentially be used in medical applications to control infectious diseases, because the O{sub 2}{sup -}{center_dot} is crucial for sterilization of liquids via atmospheric-pressure plasma.

  1. Coherent chemical kinetics as quantum walks II: Radical-pair reactions in Arabidopsis thaliana

    E-Print Network [OSTI]

    A. Chia; A. Gorecka; P. Kurzynski; T. Paterek; D. Kaszlikowski

    2015-08-20

    We apply the quantum-walk approach recently proposed in arXiv:quant-ph-1506.04213 to a radical-pair reaction where realistic estimates for the intermediate transition rates are available. The well-known average hitting time from quantum walks can be adopted as a measure of how quickly the reaction occurs and we calculate this for varying degrees of dephasing in the radical pair. The time for the radical pair to react to a product is found to be independent of the amount of dephasing introduced, even in the limit of no dephasing where the transient population dynamics exhibit strong coherent oscillations. This can be seen to arise from the existence of a rate-limiting step in the reaction and we argue that in such examples, a purely classical model based on rate equations can be used for estimating the timescale of the reaction but not necessarily its population dynamics.

  2. The radical-pair mechanism as a paradigm for the emerging science of quantum biology

    E-Print Network [OSTI]

    Kominis, I K

    2015-01-01

    The radical-pair mechanism was introduced in the 1960's to explain anomalously large EPR and NMR signals in chemical reactions of organic molecules. It has evolved to the cornerstone of spin chemistry, the study of the effect electron and nuclear spins have on chemical reactions, with the avian magnetic compass mechanism and the photosynthetic reaction center dynamics being prominent biophysical manifestations of such effects. In recent years the radical-pair mechanism was shown to be an ideal biological system where the conceptual tools of quantum information science can be fruitfully applied. We will here review recent work making the case that the radical-pair mechanism is indeed a major driving force of the emerging field of quantum biology.

  3. DOE Zero Energy Ready Home Case Study: Amaris Custom Homes, St. Paul, Minnesota

    SciTech Connect (OSTI)

    2015-06-01

    For this project, Amaris worked with U.S. Department of Energy (DOE) team, NorthernSTAR Building America Partnership, to develop the first Zero Energy Ready Home (ZERH) in Minnesota's cold climate using reasonable, cost-effective, and replicable construction materials and practices. The result is a passive solar, super-efficient 3542-ft2 walkout ranch-style home with all the creature comforts. Along with meeting ZERH standards, Amaris also achieved certifications for Leadership in Energy & Environmental Design for Homes v4, MN Green Path Emerald, and a Builders Association of the Twin Cities Reggie Award of Excellence. The home achieves a HERS score of 41 without photovoltaics; with PV, the home achieves a HERS score of 5.

  4. Competition Requirements | Department of Energy

    Office of Environmental Management (EM)

    Competition Requirements Competition Requirements Competition Requirements More Documents & Publications Competition Requirements Attachment FY2011-40(2) Competition Requirements...

  5. Calculation of the relative geometry of tRNAs in the ribosome from directed hydroxyl-radical

    E-Print Network [OSTI]

    Kondo, Derrick

    Calculation of the relative geometry of tRNAs in the ribosome from directed hydroxyl the combined use of computational analysis and tethered hydroxyl-radical probing to constrain their arrange end of deacylated tRNAPhe to generate hydroxyl radicals that probe proximal positions in the backbone

  6. Production and magnetic analysis of beams of S atoms and SO radicals. A collisional study of their interactions with

    E-Print Network [OSTI]

    Pirani, Fernando

    Production and magnetic analysis of beams of S atoms and SO radicals. A collisional study; Abstract An intense and stable continuous beam of S atoms and SO radicals has been produced to describe inelas­ tic processes concerning both fine structure transitions in collisions of open shell atoms

  7. Investigation of the O+allyl addition/elimination reaction pathways from the OCH2CHCH2 radical intermediate

    E-Print Network [OSTI]

    Butler, Laurie J.

    in the O+allyl bimolecular reaction. The data include velocity map imaging and molecular beam scatteringInvestigation of the O+allyl addition/elimination reaction pathways from the OCH2CHCH2 radical by which the radicals access the energetically allowed product channels of the bimolecular reaction

  8. Thermochemistry of radicals formed by hydrogen abstraction from 1-butanol, 2-methyl-1-propanol, and butanal

    E-Print Network [OSTI]

    Truhlar, Donald G

    , and butanal Ewa Papajak, Prasenjit Seal, Xuefei Xu, and Donald G. Truhlar Citation: J. Chem. Phys. 137, 104314 abstraction from 1-butanol, 2-methyl-1-propanol, and butanal Ewa Papajak, Prasenjit Seal, Xuefei Xu- propanol, and butanal. Electronic structure calculations for all conformers of the radicals were car- ried

  9. LETTER doi:10.1038/nature11718 Evaporative cooling of the dipolar hydroxyl radical

    E-Print Network [OSTI]

    LETTER doi:10.1038/nature11718 Evaporative cooling of the dipolar hydroxyl radical Benjamin K cooling of neutral hydroxyl (OH. ) molecules loaded from a Stark-decelerated beam into an extremely high challenged it23­25 . Hydroxyl (OH. , referred to here as OH) would not, at first glance, seem

  10. Photochemical Oxidation of Dissolved Elemental Mercury by Carbonate Radicals in Water

    SciTech Connect (OSTI)

    He, Feng; Zhao, Wenrong; Liang, Liyuan; Gu, Baohua

    2014-01-01

    Photochemical oxidation of dissolved elemental mercury [Hg(0)] affects mercury chemical speciation and its transfer at the water-air interface in the aquatic environment. The mechanisms and factors that control Hg(0) photooxidation, however, are not completely understood, especially in natural freshwaters containing dissolved organic matter (DOM) and carbonate. Here, we evaluate Hg(0) photooxidation rates affected by various reactive ionic species [e.g., DOM, HCO3-, NO3-] and free radicals in a creek water and a phosphate buffer solution (pH=8) under simulated solar irradiation. We report a high Hg(0) photooxidation rate (k = 1.44 h-1) in the presence of both HCO3- and NO3-, whereas HCO3-, NO3-, or DOM alone increased the oxidation rate slightly (k = 0.1 0.17 h-1). Using scavengers and enhancers for singlet oxygen (1O2) and hydroxyl (HO ) radicals, as well as electron paramagnetic resonance spectroscopy, we identify that carbonate radicals (CO3 -) primarily drive the Hg(0) photooxidation, whereas addition of DOM resulted in a 2-fold decrease in Hg(0) oxidation. This study identifies an unrecognized pathway of Hg(0) photooxidation by CO3 - radicals and the inhibitory effect of DOM, which could be important in assessing Hg transformation and fate in water containing carbonate such as hard water and seawater.

  11. Electron-Impact lonization Cross Sections for Polyatomic Molecules, Radicals, and Ions

    E-Print Network [OSTI]

    .S.A. Abstract. The binary-encounter-Bethe(BEB) model for calculating electron-impact ionization cross sections for molecules is described with emphasis on polyatomic molecules and their radicals and ions. The BEB model the molecular cross section. The BEB model produces reliable ionization cross sections from the threshold

  12. Quantification of OH and HO2 radicals during the lowtemperature oxidation of hydrocarbons by

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Quantification of OH and HO2 radicals during the lowtemperature oxidation of hydrocarbons of hydrocarbons and biofuels is of critical importance to allow the development of new combustion) but has never been applied to real hydrocarbons and lowtemperature oxidation. H atoms (10

  13. Microwave photochemistry. Photoinitiated radical addition of tetrahydrofuran to peruorohexylethene under microwave irradiation

    E-Print Network [OSTI]

    Cirkva, Vladimir

    ¯uorohexylethene under microwave irradiation VladimõÂr CõÂrkva, Milan HaÂjek* Institute of Chemical Process Fundamentals combined irradiation using a new simple photochemical reactor developed for organic synthetic reactions reserved. Keywords: Radical addition; Microwave irradiation; Photoinitiation; Electrodeless UV lamp

  14. SPASM and Twitch Domains in S-Adenosylmethionine (SAM) Radical Enzymes

    E-Print Network [OSTI]

    Goldman, Peter J.

    S-Adenosylmethionine (SAM, also known as AdoMet) radical enzymes use SAM and a [4Fe-4S] cluster to catalyze a diverse array of reactions. They adopt a partial triose-phosphate isomerase (TIM) barrel fold with N- and ...

  15. Reaction Dynamics of Phenyl Radicals in Extreme Environments: A Crossed Molecular

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    are toxic combustion products and a source of air pollution. In the interstellar medium, research sug- gests of precur- sor molecules to life. To build clean combustion devices and to understand the astrochemical radical reactions under single collision conditions similar to those found in combustion flames

  16. Recent legislative changes affect the way we teach and provide service at Western. The Accessibility for Ontarians with Disabilities Act (AODA) has new requirements that came into effect as of January 1, 2014,

    E-Print Network [OSTI]

    Lennard, William N.

    . Accessible Educational and Training Resources Under the Information and Communication Standard, we are required to provide educational or training resources in an accessible format that takes into account records. Purchase educational materials that include an accessible or conversion-ready electronic format

  17. The readiness of ATLAS Trigger-DAQ system for the second LHC run

    E-Print Network [OSTI]

    Rammensee, Michael; The ATLAS collaboration

    2015-01-01

    After its first shutdown, LHC will provide pp collisions with increased luminosity and energy. In the ATLAS experiment, the Trigger and Data Acquisition (TDAQ) system has been upgraded to deal with the increased event rates. The updated system is radically different from the previous implementation, both in terms of architecture and expected performance. The main architecture has been reshaped in order to profit from the technological progress and to maximize the flexibility and efficiency of the data selection process. The trigger system in ATLAS consists of a hardware Level-1 (L1) and a software based high-level trigger (HLT) that reduces the event rate from the design bunch-crossing rate of 40 MHz to an average recording rate of a few hundred Hz. The pre-existing two-level software filtering, known as L2 and the Event Filter, are now merged into a single process, performing incremental data collection and analysis. This design has many advantages, among which are: the radical simplification of the architec...

  18. Hydrogen Infrastructure Market Readiness: Opportunities and Potential for Near-term Cost Reductions; Proceedings of the Hydrogen Infrastructure Market Readiness Workshop and Summary of Feedback Provided through the Hydrogen Station Cost Calculator

    SciTech Connect (OSTI)

    Melaina, M. W.; Steward, D.; Penev, M.; McQueen, S.; Jaffe, S.; Talon, C.

    2012-08-01

    Recent progress with fuel cell electric vehicles (FCEVs) has focused attention on hydrogen infrastructure as a critical commercialization barrier. With major automakers focused on 2015 as a target timeframe for global FCEV commercialization, the window of opportunity is short for establishing a sufficient network of hydrogen stations to support large-volume vehicle deployments. This report describes expert feedback on the market readiness of hydrogen infrastructure technology from two activities.

  19. A VUV Photoionization Study on the Formation of Primary and Secondary Products in the Reaction of the Phenyl Radical with 1,3-Butadiene under Combustion Relevant Conditions

    E-Print Network [OSTI]

    Golan, Amir

    2013-01-01

    Phenyl Radical with 1,3-Butadiene under Combustion RelevantC 6 H 5 ) with 1,3-butadiene (H 2 CCHCHCH 2 ) exploiting abeams studies of the 1,3-butadiene – phenyl radical reaction

  20. ESR spectra and structure of the perchloryl fluoride radical anion (FC1O/sub 3//sup -/): A 33 valence electron radical with C/sub 30/ symmetry

    SciTech Connect (OSTI)

    Hasegawa, A.; Williams, F.

    1981-12-02

    The isotropic and anisotropic ESR spectra of FClO/sub 3//sup -/ have been observed, the former in the SF/sub 6/ matrix and the latter in both the FClO/sub 3/ and (CH/sub 3/)/sub 4/Si matrices. The isotropic hyperfine coupling constants derived from the anisotropic parameters agree with the values (/sup 35/a = 656 MHz, /sup 37/a = 546 MHz, /sup 19/a = 726 MHz) obtained from the isotropic spectrum. Moreover, the analysis of the anisotropic spectrum reveals that the chlorine and fluorine hyperfine tensors have cylindrical symmetry with their largest principal values lying along the same principal axis. This result rules out a trigonal-bipyramidal structure for this 33 valence electron radical but is entirely consistent with a C/sub 3/V structure in which the Cl-F bond represents the symmetry axis (z). Most of the spin density is concentrated in the antibonding sigma/sub Cl-F/* orbital which is composed of the 3s and 3p/sub z/ orbitals of chlorine (p/sub 3s/ = 0.14, p/sub 3p/ = 0.40) in combination with the 2p/sub z/ orbital of fluorine (p = 0.35). These results are in qualitative agreement with CNDO/2 calculations which also show that the Cl-F bond is longer in the radical anion than in the parent molecule. As expected from a consideration of its electronic structure, FClO/sub 3//sup -/ dissociates to give the neutral ClO/sub 3/ radical which has been detected in the SF/sub 6/ matrix.

  1. DOE Zero Energy Ready Home Case Study: John Hubert Associates — EXIT-0 House, North Cape May, NJ

    SciTech Connect (OSTI)

    none,

    2014-09-01

    This house is the first DOE Zero Energy Ready Home for this builder and won a Custom Builder award in the 2014 Housing Innovation Awards. The 1,871-ft2 home features advanced-framed above-grade walls with R-21 fiberglass batt plus an R-3.6-insulated coated OSB sheathing, R-18 rigid-foam-insulated crawlspace walls, solar water heating, a high-efficiency heat pump, an HRV, and mostly LED lighting.

  2. Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied by photoelectron spectroscopy of O (H2O) and H3O2

    E-Print Network [OSTI]

    Neumark, Daniel M.

    Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied to study the unstable neutral complexes involved in two fundamental re- actions of the hydroxyl radical OH H2OH2O OH, 1 OH OHO 3 P H2O. 2 The role of the hydroxyl radical as a propagator of chain reactions

  3. Investigation of the Role of Bicyclic Peroxy Radicals in the Oxidation Mechanism of Adam W. Birdsall, John F. Andreoni, and Matthew J. Elrod*

    E-Print Network [OSTI]

    Elrod, Matthew J.

    Investigation of the Role of Bicyclic Peroxy Radicals in the Oxidation Mechanism of Toluene Adam W as a range of total pressures. The bicyclic peroxy radical intermediate, a key proposed intermediate species to the central role of the bicyclic peroxy radical in determining the stable product distribution at atmospheric

  4. Reaction Dynamics of the 4Methylphenyl Radical (pTolyl) with 1,2-Butadiene (1-Methylallene): Are Methyl Groups Purely Spectators?

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Reaction Dynamics of the 4Methylphenyl Radical (pTolyl) with 1,2- Butadiene (1-Methylallene4CD3) with 1,2-butadiene (C4H6) have been probed in crossed molecular beams under single collision of the radical center of the 4-tolyl radical to the C1 or C3 carbon atoms of 1,2-butadiene. The collision

  5. Roles of plasma-generated vacuum-ultraviolet photons and oxygen radicals in damaging nanoporous low-k films

    SciTech Connect (OSTI)

    Lee, Joe; Graves, David B. [Department of Chemical Engineering, University of California, Berkeley, California 94720 (United States)

    2013-07-15

    One important class of low-k materials used as interconnect dielectrics employs methyl groups added to nanoporous SiO{sub 2} matrices. These carbon-doped oxide materials are known to be susceptible to damage from plasma species during various stages of plasma processing. Two key active species generated in O{sub 2} plasma are oxygen (O) radicals and vacuum-ultraviolet (VUV) photons. These species are known to cause carbon loss, resulting in damaging increases in dielectric constant throughout the film. However, the mechanisms through which this damage is incurred are poorly understood. By capping the substrate in different ways during plasma exposure, it is possible to expose films to either photons alone or O atoms alone. The authors report measurements of damage induced by VUV photons only, O radicals only, and the combination of O radicals and photons. Through HF stripping, they note that carbon extraction from photons and from radicals yields different outcomes; the profile of carbon concentration within the modified region is different for each case. Damage from photons alone can be modeled and model predictions are in good agreement with measurements. Damage from O atoms alone can only be modeled if it is assumed that the near-surface region has a significantly reduced diffusivity compared to the bulk of the film. Experiment and model agree that both photons alone and O radicals alone damage the material by removing carbon. When radicals and photons are present simultaneously during plasma exposure, however, more C removal appears to be occurring in the model than experimentally observed. Remarkably, if only radicals are exposed to the film after short (10-30 s) plasma exposures, very little additional damage is incurred during this radical-only exposure. The most straightforward interpretation of these results appears to be that photons combine synergistically with radicals in the pores to narrow the pores, thereby reducing film diffusivity in the C-poor, plasma-damaged regions.

  6. Analyses of Value-added for Case-ready Beef, with Special Emphasis on Texas. 

    E-Print Network [OSTI]

    Dietrich, R.A.; Farris, D.E.; Ward, J.B

    1992-01-01

    hundredweight cost advantages over other alternative packaging/ distribu tion systems (Table 35): (1) $1.00 over tray-ready, (2) $3.00 over central overwrap, (3) Almost $7.00 over central frozen, (4) Almost $9.00 over boxed beef (the pre- dominant 1988....48 165.48 Fixed 0.84 1.10 1.00 1.18 1.18 1.18 0.93 Labor 2.86 5.53 9.73 9.76 9.76 9.76 16.06 Package 2.24 2.60 5.21 10.10 18.43 10.10 10.10 Distribution 2.75 2.75 5.35 2.75 3.72 2.27 4.20 Other 2.86 10.03 10.34 10.34 11.34 16.04 11 .78 Sub-Total 177...

  7. The readiness of the ATLAS Trigger-DAQ system for the second LHC run

    E-Print Network [OSTI]

    Rammensee, Michael; The ATLAS collaboration

    2015-01-01

    After its first shutdown, the Large Hadron Collider (LHC) will provide proton-proton collisions with increased luminosity and energy. In the ATLAS experiment~\\cite{Atlas}, the Trigger and Data Acquisition (TDAQ) system has been upgraded to deal with the increased event rates~\\cite{TDAQPhase1}. The updated system is radically different from the previous implementation, both in terms of architecture and expected performance. The main architecture has been reshaped in order to profit from the technological progress and to maximize the flexibility and efficiency of the data selection process. Design choices and the strategies employed to minimize the data-collection and the selection latency will be discussed. First results of tests done during the commissioning phase and the operational performance after the first months of data taking will be presented.

  8. Government Printing Office Requirements

    Broader source: Energy.gov [DOE]

    This section describes the Government Printing Office (GPO) requirements for all print materials, whether printed electronically or on paper. This includes requirements for printing and copying for...

  9. A shock tube study of the reactions of the hydroxyl radical with combustion species

    SciTech Connect (OSTI)

    Cohen, N.; Koffend, J.B. [The Aerospace Corporation, Los Angeles, CA (United States)

    1993-12-01

    To extend the semi-empirical techniques of Benson and coworkers, and to extend the database of reliable high temperature measurements of OH radicals with hydrocarbons and other fuels and their decomposition products, the authors undertook a research program with both experimental and computational tasks. The experimental goal was to design a procedure for measuring, at combustion temperatures, the reaction rate coefficients of OH radicals with fuels and other species of importance in combustion or propulsion systems. The computational effort was intended to refine the semi-empirical transition-state-theory procedures for extrapolating rate coefficients of reactions of OH with combustion species of interest, for predicting rate coefficients for species not studied in the laboratory, and to examine the ability of the theory to predict rate coefficients for different pathways in the case the reagent possessed more than one nonequivalent H atoms.

  10. A review of "Perspectives on English Revolutionary Radicalism" edited by Dirk Weimann and Gaby Mahlberg 

    E-Print Network [OSTI]

    Schwarz, Marc

    2015-01-01

    seventeenth-century news Dirk Weimann and Gaby Mahlberg, eds. Perspectives on English Revolutionary Radicalism. Farnham, Surrey and Burlington, VT: Ashgate, 2014. x+ 228 pp. $124.95. Review by Marc Schwarz, University of New Hampshire. This volume...–Moorhead. As part of the Music Theory in Britain, 1500-1700: Critical Edi- tions series, this edition of Thomas Ravenscroft’s theoretical works, with accompanying introductory materials, is a welcome addition to the growing body of knowledge in this relatively new...

  11. Formation of the diphenyl molecule in the crossed beam reaction of phenyl radicals with benzene

    SciTech Connect (OSTI)

    Zhang Fangtong; Gu Xibin; Kaiser, Ralf I.

    2008-02-28

    The chemical dynamics to form the D5-diphenyl molecule, C{sub 6}H{sub 5}C{sub 6}D{sub 5}, via the neutral-neutral reaction of phenyl radicals (C{sub 6}H{sub 5}) with D6-benzene (C{sub 6}D{sub 6}), was investigated in a crossed molecular beams experiment at a collision energy of 185 kJ mol{sup -1}. The laboratory angular distribution and time-of-flight spectra of the C{sub 6}H{sub 5}C{sub 6}D{sub 5} product were recorded at mass to charge m/z of 159. Forward-convolution fitting of our data reveals that the reaction dynamics are governed by an initial addition of the phenyl radical to the {pi} electron density of the D6-benzene molecule yielding a short-lived C{sub 6}H{sub 5}C{sub 6}D{sub 6} collision complex. The latter undergoes atomic deuterium elimination via a tight exit transition state located about 30 kJ mol{sup -1} above the separated reactants; the overall reaction to form D5-diphenyl from phenyl and D6-benzene was found to be weakly exoergic. The explicit identification of the D5-biphenyl molecules suggests that in high temperature combustion flames, a diphenyl molecule can be formed via a single collision event between a phenyl radical and a benzene molecule.

  12. Modelling On Photogeneration Of Hydroxyl Radical In Surface Waters And Its Reactivity Towards Pharmaceutical Wastes

    SciTech Connect (OSTI)

    Das, Radha; Vione, Davide; Rubertelli, Francesca; Maurino, Valter; Minero, Claudio; Barbati, Stephane; Chiron, Serge

    2010-10-26

    This paper reports a simple model to describe the formation and reactivity of hydroxyl radicals in the whole column of freshwater lakes. It is based on empirical irradiation data and is a function of the water chemical composition (the photochemically significant parameters NPOC, nitrate, nitrite, carbonate and bicarbonate), the lake conformation best expressed as the average depth, and the water absorption spectrum in a simplified Lambert-Beer approach. The purpose is to derive the lifetime of dissolved molecules, due to reaction with OH, on the basis of their second-order rate constants with the hydroxyl radical. The model was applied to two compounds of pharmaceutical wastes ibuprofen and carbamazepine, for which the second-order rate constants for reaction with the hydroxyl radical were measured by means of the competition kinetics with 2-propanol. The measured values of the rate constants are 1.0x10{sup 10} and 1.6x10{sup 10} M{sup -1} s{sup -1} for ibuprofen and carbamazepine, respectively. The model suggests that the lifetime of a given compound can be very variable in different lakes, even more than the lifetime of different compounds in the same lake. It can be concluded that as far as the reaction with OH, is concerned the concepts of photolability and photostability, traditionally attached to definite compounds, are ecosystem-dependent at least as much as they depend on the molecule under consideration.

  13. Hybrid inorganic-organic, organic charge transfer, and radical based compounds with chalcofulvalene donors and organic acceptors 

    E-Print Network [OSTI]

    Reinheimer, Eric Wade

    2009-05-15

    The primary focus of this dissertation is the electrochemical preparation of radical cation salts utilizing the donor o-4,4’-dimethyltetrathiafulvalene (o-Me2TTF) and spherical, tetrahedral, octahedral, bimetallic, cyanometallate...

  14. The Radical Use of Rossmann and TIM Barrel Architectures for Controlling Coenzyme B[subscript 12] Chemistry

    E-Print Network [OSTI]

    Dowling, Daniel P.

    The ability of enzymes to harness free-radical chemistry allows for some of the most amazing transformations in nature, including reduction of ribonucleotides and carbon skeleton rearrangements. Enzyme cofactors involved ...

  15. Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign – Part 2: Model comparison and radical budget

    E-Print Network [OSTI]

    Dusanter, S.

    Measurements of hydroxyl (OH) and hydroperoxy (HO2) radicals were made during the Mexico City Metropolitan Area (MCMA) field campaign as part of the MILAGRO (Megacity Initiative: Local and Global Research Observations) ...

  16. Measuring Hydroxyl Radicals during the Oxidation of Methane, Ethane, Ethylene, and Acetylene in a Shock Tube Using UV Absorption Spectroscopy 

    E-Print Network [OSTI]

    Aul, Christopher J

    2013-05-02

    The hydroxyl (OH) radical is a common intermediate species in any hydrogen- or hydrocarbon-based flame. Investigating OH at elevated temperatures and pressures is not a trivial task, and many considerations must be made ...

  17. Radical anionic versus neutral 2,2'-bipyridyl coordination in uranium complexes supported by amide and ketimide ligands.

    E-Print Network [OSTI]

    Diaconescu, PL; Cummins, CC

    2015-01-01

    the organometallic chemistry of uranium. The radical anionicof Chemistry 2012 Journal Name present 2.4(9) at the uraniumChemistry 2013 Since our initial examples, others have also reported bridging benzene or toluene uranium

  18. A review of "The English Radical Imagination: Culture, Religion, and Revolution, 1630-1660" by Nicholas McDowell. 

    E-Print Network [OSTI]

    Jason Peacey

    2004-01-01

    might be called the ?radi- calism industry? has too often fallen into the trap of accepting the ideas of the radicals? contemporary opponents: that they were mis- guided, worthless, and indeed heretical, because of their lack of learning. Mc...

  19. Radical SAM enzyme QueE defines a new minimal core fold and metal-dependent mechanism

    E-Print Network [OSTI]

    Bruender, Nathan A

    7-carboxy-7-deazaguanine synthase (QueE) catalyzes a key S-adenosyl-L-methionine (AdoMet)- and Mg[superscript 2+]-dependent radical-mediated ring contraction step, which is common to the biosynthetic pathways of all ...

  20. Snapshots of radical enzyme catalysis : the crystal structures of biotin synthase and lysine 5,6-aminomutase

    E-Print Network [OSTI]

    Berkovitch, Frederick, 1978-

    2004-01-01

    (cont.) in the same pathway. To further probe the relationship of the adenosylmethionine and adenosylcobalamin-dependent radical enzymes, the crystal structure of lysine 5,6-aminomutase was determined to 2.8 [angstroms] ...

  1. A review of "Radicalism in British Literary Culture: From Revolution to Revolution." by T. Morton and N. Smith, eds. 

    E-Print Network [OSTI]

    R. C. Taylor

    2003-01-01

    this at their peril. Timothy Morton and Nigel Smith, eds. Radicalism in British Literary Culture, 1650-1830: From Revolution to Revolution. Cambridge: Cambridge University Press, 2002. x + 284 pp. $60.00. Review by RICHARD C. TAYLOR, EAST CAROLINA UNIVERSITY..., ideologies, and radical personae across a span of time (14). This collection of essays demonstrates how successive generations re- read the English Revolution by appropriating its central figures, theological disputes, and political debates for use in new...

  2. 3. MATERIAL CERTIFICATIONS REQUIRED NO RADIOGRAPHY REQUIRED.

    E-Print Network [OSTI]

    McDonald, Kirk

    SHALL BE DYE PENETRANT INSPECTED. ASME SECTION IX. NO CODE STAMP REQUIRED. 1. WELDING TO BE PERFORMED is property of 1. ALL DIMENSIONS ARE IN INCHES 2. INTERPRET DIMENSIONS AND TOLERANCES PER ASME Y14.5M 3

  3. Radical Supercomputing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation |Publications The NREL Queue LookFeatures »

  4. New Whole-House Solutions Case Study: EcoVillage: A Net Zero Energy Ready Community, Ithaca, New York

    SciTech Connect (OSTI)

    2015-04-01

    The Consortium for Advanced Residential Buildings is working with the EcoVillage co-housing community and builder AquaZephyr in Ithaca, New York, on their third neighborhood called the Third Residential EcoVillage Experience (TREE). This community-scale project consists of 40 housing units—15 apartments, and 25 single family residences that range in size from 1,250 ft2–1,664 ft2 and cost from $80,000 to $235,000. The community is pursing DOE Zero Energy Ready Home (ZERH), US Green Building Council Leadership in Energy and Environmental Design (LEED) Gold, and ENERGY STAR certifications for the entire project.

  5. Requirement Required Course Required Course English Composition: ENG 101 3

    E-Print Network [OSTI]

    Walker, Lawrence R.

    (4) 3 MATH _____ 3 MATH 427 Differential Equations 3 (1A) 3 MATH 453 Abstract Algebra 3 (1B) 3 MATH requirement MATH 181 Calculus I below see course choices www.unlv.edu/committees/gec 3* 1 MATH 181 Calculus I 4 MATH 182 Calculus II 4 (1) 3 MATH 251 Discrete Mathematics I 3 (2) 3 MATH 283 Calculus III 4 (3) 3

  6. Emergency Medical Treatment Required

    E-Print Network [OSTI]

    McQuade, D. Tyler

    Emergency Medical Treatment Required Non-Emergency Medical Treatment Required If possible, get help from colleague or supervisor Call 911 or go to hospital emergency room (for chemical exposure, bring Investigation Report" to Environmental Health & Safety within 48 hours Emergency Medical Treatment Required

  7. HIA 2015 DOE Zero Energy Ready Home Case Study: Mutual Housing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an indoor hydrobox that contains a refrigerant-to- water heat exchanger, pump, expansion tank, and other components typically required for hydronic systems. The heat exchangers...

  8. Kinetics of the Hydrogen Atom Abstraction Reactions from 1?Butanol by Hydroxyl Radical: Theory Matches Experiment and More

    SciTech Connect (OSTI)

    Seal, Prasenjit; Oyedepo, Gbenga; Truhlar, Donald G.

    2013-01-17

    In the present work, we study the H atom abstraction reactions by hydroxyl radical at all five sites of 1-butanol. Multistructural variational transition state theory (MS-VTST) was employed to estimate the five thermal rate constants. MS-VTST utilizes a multifaceted dividing surface that accounts for the multiple conformational structures of the transition state, and we also include all the structures of the reactant molecule. The vibrational frequencies and minimum energy paths (MEPs) were computed using the M08-HX/MG3S electronic structure method. The required potential energy surfaces were obtained implicitly by direct dynamics employing interpolated variational transition state theory with mapping (IVTST-M) using a variational reaction path algorithm. The M08-HX/MG3S electronic model chemistry was then used to calculate multistructural torsional anharmonicity factors to complete the MS-VTST rate constant calculations. The results indicate that torsional anharmonicity is very important at higher temperatures, and neglecting it would lead to errors of 26 and 32 at 1000 and 1500 K, respectively. Our results for the sums of the site-specific rate constants agree very well with the experimental values of Hanson and co-workers at 896?1269 K and with the experimental results of Campbell et al. at 292 K, but slightly less well with the experiments of Wallington et al., Nelson et al., and Yujing and Mellouki at 253?372 K; nevertheless, the calculated rates are within a factor of 1.61 of all experimental values at all temperatures. This gives us confidence in the site-specific values, which are currently inaccessible to experiment.

  9. SIMULTANEOUS PRODUCTION OF HIGH-PURITY HYDROGEN AND SEQUESTRATION-READY CO2 FROM SYNGAS

    SciTech Connect (OSTI)

    Linda Denton; Hana Lorethova; Tomasz Wiltowski; Court Moorefield; Parag Kulkarni; Vladimir Zamansky; Ravi Kumar

    2003-12-01

    This final report summarizes the progress made on the program ''Simultaneous Production of High-Purity Hydrogen and Sequestration-Ready CO{sub 2} from Syngas (contract number DE-FG26-99FT40682)'', during October 2000 through September of 2003. GE Energy and Environmental Research (GE-EER) and Southern Illinois University (SIU) at Carbondale conducted the research work for this program. This program addresses improved methods to efficiently produce simultaneous streams of high-purity hydrogen and separated carbon dioxide from synthesis gas (syngas). The syngas may be produced through either gasification of coal or reforming of natural gas. The process of production of H{sub 2} and separated CO{sub 2} utilizes a dual-bed reactor and regenerator system. The reactor produces hydrogen and the regenerator produces separated CO{sub 2}. The dual-bed system can be operated under either a circulating fluidized-bed configuration or a cyclic fixed-bed configuration. Both configurations were evaluated in this project. The experimental effort was divided into lab-scale work at SIU and bench-scale work at GE-EER. Tests in a lab-scale fluidized bed system demonstrated the process for the conversion of syngas to high purity H{sub 2} and separated CO{sub 2}. The lab-scale system generated up to 95% H{sub 2} (on a dry basis). Extensive thermodynamic analysis of chemical reactions between the syngas and the fluidized solids determined an optimum range of temperature and pressure operation, where the extent of the undesirable reactions is minimum. The cycling of the process between hydrogen generation and oxygen regeneration has been demonstrated. The fluidized solids did not regenerate completely and the hydrogen purity in the reuse cycle dropped to 70% from 95% (on a dry basis). Changes in morphology and particle size may be the most dominant factor affecting the efficiency of the repeated cycling between hydrogen production and oxygen regeneration. The concept of simultaneous production of hydrogen and separated stream of CO{sub 2} was proved using a fixed bed 2 reactor system at GE-EER. This bench-scale cyclic fixed-bed reactor system designed to reform natural gas to syngas has been fabricated in another coordinated DOE project. This system was modified to reform natural gas to syngas and then convert syngas to H{sub 2} and separated CO{sub 2}. The system produced 85% hydrogen (dry basis).

  10. Process improvement to the inspection readiness plan in chemical weapons convention challenge inspections. Master`s thesis

    SciTech Connect (OSTI)

    Triplett, W.M.

    1997-09-01

    This thesis identified current Information Technology initiatives to help improve the Navy`s Inspection Readiness Plan for Chemical Warfare Convention (CWC) Challenge Inspection. The CWC is an intensive inspection. The Challenge Inspection allows for a team of international inspectors to inspect a naval facility suspected of violating the CWC on very short notice. This thesis begins with a review of the CWC Challenge Inspection timeline. It then describes the Navy`s Inspection Readiness Plan for CWC Challenge Inspections as well as the Navy Tiger Team that is sent to naval facilities to assist the Commanding Officer and base personnel during inspections. One of the initiatives evaluated by this analysis is the use of videoconferencing. To ascertain the feasibility of using videoconferencing in the CWC Challenge Inspection process, this thesis reviews the current videoconferencing systems and standards, and the results of a questionnaire that was sent to various naval commands. This thesis concludes with recommendations for inclusion of videoconferencing and various other Information Technology initiatives in the CWC Challenge Inspection process.

  11. Recommendations for Tritium Science and Technology Research and Development in Support of the Tritium Readiness Campaign, TTP-7-084

    SciTech Connect (OSTI)

    Senor, David J.

    2013-10-30

    Between 2006 and 2012 the Tritium Readiness Campaign Development and Testing Program produced significant advances in the understanding of in-reactor TPBAR performance. Incorporating these data into existing TPBAR performance models has improved permeation predictions, and the discrepancy between predicted and observed tritium permeation in the WBN1 coolant has been decreased by about 30%. However, important differences between predicted and observed permeation still remain, and there are significant knowledge gaps that hinder the ability to reliably predict other aspects of TPBAR performance such as tritium distribution, component integrity, and performance margins. Based on recommendations from recent Tritium Readiness Campaign workshops and reviews coupled with technical and programmatic priorities, high-priority activities were identified to address knowledge gaps in the near- (3-5 year), middle- (5-10 year), and long-term (10+ year) time horizons. It is important to note that there are many aspects to a well-integrated research and development program. The intent is not to focus exclusively on one aspect or another, but to approach the program in a holistic fashion. Thus, in addition to small-scale tritium science studies, ex-reactor tritium technology experiments such as TMED, and large-scale in-reactor tritium technology experiments such as TMIST, a well-rounded research and development program must also include continued analysis of WBN1 performance data and post-irradiation examination of TPBARs and lead use assemblies to evaluate model improvements and compare separate-effects and integral component behavior.

  12. Oxidation of alpha-tocopherol in micelles and liposomes by the hydroxyl, perhydroxyl, and superoxide free radicals

    SciTech Connect (OSTI)

    Fukuzawa, K.; Gebicki, J.M.

    1983-10-01

    Rates of oxidation of alpha-tocopherol by the hydroxyl- and superoxide free radicals were measured. The radicals were produced in known yields by radiolysis of aqueous solutions with gamma rays. Two main systems were used to dissolve the tocopherol; micelles, made up from charged and uncharged amphiphiles, and membranes made from dimyristyl phosphatidylcholine which could be charged by addition of stearyl amine or dicetyl phosphate. The HO. radicals were efficient oxidants of alpha-tocopherol in all systems, with up to 83% of radicals generated in micelle and 32% in membrane suspensions initiating the oxidation. The HO/sub 2/ radical was an even more effective oxidant, but when most of it was in the O/sub 2/ form at neutral or alkaline pH, the oxidation rates became low. Tocopherol held in positively charged micelles or membranes was oxidized at a higher rate by the O/sub 2/ than in uncharged or negative particles. Possible biological significance of these results is discussed.

  13. Zeaxanthin Radical Cation Formation in Minor Light-Harvesting Complexes of Higher Plant Antenna

    SciTech Connect (OSTI)

    Avenson, Thomas H.; Ahn, Tae Kyu; Zigmantas, Donatas; Niyogi, Krishna K.; Li, Zhirong; Ballottari, Matteo; Bassi, Roberto; Fleming, Graham R.

    2008-01-31

    Previous work on intact thylakoid membranes showed that transient formation of a zeaxanthin radical cation was correlated with regulation of photosynthetic light-harvesting via energy-dependent quenching. A molecular mechanism for such quenching was proposed to involve charge transfer within a chlorophyll-zeaxanthin heterodimer. Using near infrared (880-1100 nm) transient absorption spectroscopy, we demonstrate that carotenoid (mainly zeaxanthin) radical cation generation occurs solely in isolated minor light-harvesting complexes that bind zeaxanthin, consistent with the engagement of charge transfer quenching therein. We estimated that less than 0.5percent of the isolated minor complexes undergo charge transfer quenching in vitro, whereas the fraction of minor complexes estimated to be engaged in charge transfer quenching in isolated thylakoids was more than 80 times higher. We conclude that minor complexes which bind zeaxanthin are sites of charge transfer quenching in vivo and that they can assume Non-quenching and Quenching conformations, the equilibrium LHC(N)<--> LHC(Q) of which is modulated by the transthylakoid pH gradient, the PsbS protein, and protein-protein interactions.

  14. Reconstitution of ThiC in thiamine pyrimidine biosynthesis expands the radical SAM superfamily

    SciTech Connect (OSTI)

    Chatterjee, Abhishek; Li, Yue; Zhang, Yang; Grove, Tyler L.; Lee, Michael; Krebs, Carsten; Booker, Squire J.; Begley, Tadhg P.; Ealick, Steven E. (Cornell); (Penn)

    2009-01-15

    4-Amino-5-hydroxymethyl-2-methylpyrimidine phosphate (HMP-P) synthase catalyzes a complex rearrangement of 5-aminoimidazole ribonucleotide (AIR) to form HMP-P, the pyrimidine moiety of thiamine phosphate. We determined the three-dimensional structures of HMP-P synthase and its complexes with the product HMP-P and a substrate analog imidazole ribotide. The structure of HMP-P synthase reveals a homodimer in which each protomer comprises three domains: an N-terminal domain with a novel fold, a central ({beta}{alpha}){sub 8} barrel and a disordered C-terminal domain that contains a conserved CX{sub 2}CX{sub 4}C motif, which is suggestive of a [4Fe-4S] cluster. Biochemical studies have confirmed that HMP-P synthase is iron sulfur cluster-dependent, that it is a new member of the radical SAM superfamily and that HMP-P and 5{prime}-deoxyadenosine are products of the reaction. Moessbauer and EPR spectroscopy confirm the presence of one [4Fe-4S] cluster. Structural comparisons reveal that HMP-P synthase is homologous to a group of adenosylcobalamin radical enzymes. This similarity supports an evolutionary relationship between these two superfamilies.

  15. Free radicals release vasodilator(s) from endothelial and smooth muscle cells

    SciTech Connect (OSTI)

    Chen, X.; Hu, Y.C.; Gillis, C.N. )

    1991-03-15

    Electrolysis-generated free radicals (ES-FR) injure the endothelium (EC) of rabbit lungs perfused in situ. The authors now report that ES-FR release EDRF-like substance(s) from both vascular EC and smooth muscle sources. Rabbit aortic segments with or without endothelium or columns of bovine aortic EC grown on biosilon beads were perfused with Krebs solution containing 6 uM indomethacin and 10 units/ml SOD. Effluent passed over two endothelial-denuded aortic rings precontracted with phenylephrine. Electrolysis of perfusion medium, released a vasodilator substance(s) from both. Vasodilatation was directly related to the current used and had t{sub 1/2} similar to that of EDRF released from EC columns by ADP. Release was attenuated by N-{omega}-nitro-L-arginine or sodium salicylate perfused through the cell column or aortic segments, or by 0.5% hemoglobin passed over the bioassay aortic rings. Finally, prompt transfer of 0.3-0.5 ml of medium, subjected to ES off-line, also relaxed pre-contracted aortic rings. Thus ES-FR can release EDRF-like substance(s) from both aortic EC and EC-denuded aortic smooth muscle. Since release was attenuated by salicylate, a specific trapping agent for hydroxyl radicals, the authors suggest that the latter is related to release of the vasodilator.

  16. PAH Formation under Single Collision Conditions: Reaction of Phenyl Radical and 1,3-Butadiene to Form 1,4-Dihydronaphthalene

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    PAH Formation under Single Collision Conditions: Reaction of Phenyl Radical and 1,3-Butadiene, United States ABSTRACT: The crossed beam reactions of the phenyl radical (C6H5, X2 A1) with 1,3-butadiene (C4H6, X1 Ag) and D6-1,3-butadiene (C4D6, X1 Ag) as well as of the D5-phenyl radical (C6D5, X2 A1

  17. Regulators, Requirements, Statutes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regulations and the New Mexico Administrative Code. Federal Requirements The Environmental Protection Agency (EPA) enforces the federal regulations. Code of Federal...

  18. Transuranic Waste Requirements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-07-09

    The guide provides criteria for determining if a waste is to be managed in accordance with DOE M 435.1-1, Chapter III, Transuranic Waste Requirements.

  19. Web Writing Requirements

    Broader source: Energy.gov [DOE]

    When writing content for Office of Energy Efficiency and Renewable Energy (EERE) websites and applications, follow these requirements. Also see EERE's Web writing best practices.

  20. Residential Solar Permit Requirements

    Broader source: Energy.gov [DOE]

    Washington's State Building Code sets requirements for the installation, inspection, maintenance and repair of solar photovoltaic (PV) energy systems. Local jurisdictions have the authority to is...

  1. Required Annual Notices

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Required Annual Notices The Women's Health and Cancer Rights Act of 1998 (WHCRA) The medical programs sponsored by LANS will not restrict benefits if you or your dependent...

  2. HOx radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Stark, H.; Li, R.; Palm, B. B.; Brune, W. H.; Jimenez, J. L.

    2015-04-20

    Oxidation flow reactors (OFRs) using OH produced from low-pressure Hg lamps at 254 nm (OFR254) or both 185 and 254 nm (OFR185) are commonly used in atmospheric chemistry and other fields. OFR254 requires the addition of externally formed O3 since OH is formed from O3 photolysis, while OFR185 does not since O2 can be photolyzed to produce O3 and OH can also be formed from H2O photolysis. In this study, we use a plug-flow kinetic model to investigate OFR properties under a very wide range of conditions applicable to both field and laboratory studies. We show that the radical chemistrymore »in OFRs can be characterized as a function of UV light intensity, H2O concentration, and total external OH reactivity (OHRext, e.g., from VOCs, NOx, and SO2). OH exposure is decreased by added external OH reactivity. OFR185 is especially sensitive to this effect at low UV intensity due to low primary OH production. OFR254 can be more resilient against OH suppression at high injected O3 (e.g., 70 ppm), as a larger primary OH source from O3, as well as enhanced recycling of HO2 to OH, make external perturbations to the radical chemistry less significant. However if the external OH reactivity in OFR254 is much larger than OH reactivity from injected O3, OH suppression can reach two orders of magnitude. For a typical input of 7 ppm O3 (OHRO3 = 10 s?1) ten-fold OH suppression is observed at OHRext ? 100 s?1, which is similar or lower than used in many laboratory studies. This finding may have important implications for the interpretation of past laboratory studies, as applying OHexp measurements acquired under different conditions could lead to over an order-of-magnitude error in the estimated OHexp. The uncertainties of key model outputs due to uncertainty in all rate constants and absorption cross-sections in the model are within ± 25% for OH exposure and within ± 60% for other parameters. These uncertainties are small relative to the dynamic range of outputs. Uncertainty analysis shows that most of the uncertainty is contributed by photolysis rates of O3, O2, and H2O and reactions of OH and HO2 with themselves or with some abundant species, i.e., O3 and H2O2. Using HOx-recycling vs. destructive external OH reactivity only leads to small changes in OHexp under most conditions. Changing the identity (rate constant) of external OH reactants can result in substantial changes in OHexp due to different reductions in OH suppression as the reactant is consumed. We also report two equations for estimating OH exposure in OFR254. We find that the equation estimating OHexp from measured O3 consumption performs better than an alternative equation that does not use it, and thus recommend measuring both input and output O3 concentrations in OFR254 experiments. This study contributes to establishing a firm and systematic understanding of the gas-phase HOx and Ox chemistry in these reactors, and enables better experiment planning and interpretation as well as improved design of future reactors.« less

  3. Getting waste ready for shipment to the WIPP: integration of characterization and certification activities

    SciTech Connect (OSTI)

    Sinkule, B.; Knudsen, K.; Rogers, P.

    1996-06-01

    The Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria (WAC) serve as the primary directive for assuring the safe handling, transportation, and disposal of transuranic (TRU) waste generated at Department of Energy (DOE) sites. The WIPP WAC address fulfillment of WIPP`s operational safety and performance assessment criteria, compliance with Resource Conservation and Recovery Act (RCRA) requirements, and preparation of waste packages that meet all transportation criteria. At individual generator sites, preparation of transuranic waste for final disposal at WIPP includes characterizing the waste to meet the requirements of the transuranic Waste Characterization Quality Assurance Program Plan (QAPP) and certifying waste containers to meet the WIPP WAC and the Transuranic Package Transporter-II Authorized Methods for Payload Control (TRAMPAC). This paper compares the quality assurance and quality control requirements specified in the WIPP WAC, QAPP, and TRAMPAC and discusses the potential to consolidate activities to comply with the TRU waste characterization and certification program requirements.

  4. Development of the Write Process for Pipeline-Ready Heavy Oil

    SciTech Connect (OSTI)

    Lee Brecher; Charles Mones; Frank Guffey

    2009-03-07

    Work completed under this program advances the goal of demonstrating Western Research Institute's (WRI's) WRITE{trademark} process for upgrading heavy oil at field scale. MEG Energy Corporation (MEG) located in Calgary, Alberta, Canada supported efforts at WRI to develop the WRITE{trademark} process as an oil sands, field-upgrading technology through this Task 51 Jointly Sponsored Research project. The project consisted of 6 tasks: (1) optimization of the distillate recovery unit (DRU), (2) demonstration and design of a continuous coker, (3) conceptual design and cost estimate for a commercial facility, (4) design of a WRITE{trademark} pilot plant, (5) hydrotreating studies, and (6) establish a petroleum analysis laboratory. WRITE{trademark} is a heavy oil and bitumen upgrading process that produces residuum-free, pipeline ready oil from heavy material with undiluted density and viscosity that exceed prevailing pipeline specifications. WRITE{trademark} uses two processing stages to achieve low and high temperature conversion of heavy oil or bitumen. The first stage DRU operates at mild thermal cracking conditions, yielding a light overhead product and a heavy residuum or bottoms material. These bottoms flow to the second stage continuous coker that operates at severe pyrolysis conditions, yielding light pyrolyzate and coke. The combined pyrolyzate and mildly cracked overhead streams form WRITE{trademark}'s synthetic crude oil (SCO) production. The main objectives of this project were to (1) complete testing and analysis at bench scale with the DRU and continuous coker reactors and provide results to MEG for process evaluation and scale-up determinations and (2) complete a technical and economic assessment of WRITE{trademark} technology to determine its viability. The DRU test program was completed and a processing envelope developed. These results were used for process assessment and for scaleup. Tests in the continuous coker were intended to determine the throughput capability of the coker so a scaled design could be developed that maximized feed rate for a given size of reactor. These tests were only partially successful because of equipment problems. A redesigned coker, which addressed the problems, has been build but not operated. A preliminary economic analysis conducted by MEG and an their engineering consultant concluded that the WRITE{trademark} process is a technically feasible method for upgrading bitumen and that it produces SCO that meets pipeline specifications for density. When compared to delayed coking, the industry benchmark for thermal upgrading of bitumen, WRITE{trademark} produced more SCO, less coke, less CO{sub 2} per barrel of bitumen fed, and had lower capital and operating costs. On the other hand, WRITE{trademark}'s lower processing severity yielded crude with higher density and a different product distribution for naphtha, light gas oil and vacuum oil that, taken together, might reduce the value of the SCO. These issues plus the completion of more detailed process evaluation and economics need to be resolved before WRITE{trademark} is deployed as a field-scale pilot.

  5. Vitamin and mineral requirements

    E-Print Network [OSTI]

    Laughlin, Robert B.

    Vitamin and mineral requirements in human nutrition Second edition Please go to the Table/WHO Expert Consultation on Human Vitamin and Mineral Requirements (1998 : Bangkok, Thailand). Vitamin, 21­30 September 1998. 1.Vitamins -- standards 2.Micronutrients -- standards 3.Trace elements

  6. General Responsibilities and Requirements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-07-09

    The material presented in this guide provides suggestions and acceptable ways of implementing DOE M 435.1-1 and should not be viewed as additional or mandatory requirements. The objective of the guide is to ensure that responsible individuals understand what is necessary and acceptable for implementing the requirements of DOE M 435.1-1.

  7. Information Technology Requirements

    E-Print Network [OSTI]

    Saskatchewan, University of

    -campus Televised Multi-mode Independent Study Web-based Other (specify) 3. Network Requirements 3.1 Does;General Web and e-mail usage Large (10MB or more) file transfers Other (specify) 3.2 Does the program list the software that will be required for the program (e.g. e-mail, web pages, SPSS, discipline

  8. NISTIR 7933 Requirements and

    E-Print Network [OSTI]

    NISTIR 7933 Requirements and Conformance Test Assertions for ANSI/NIST-ITL 1-2011 Record Type 18 #12;ii NISTIR 7933 Requirements and Conformance Test Assertions for ANSI/NIST-ITL 1-2011 Record Type/CTS designed to test implementations of ANSI/NIST-ITL 1- 2011 (AN-2011) "Data Format for the Interchange

  9. A PUBLICATION OF THE TEXAS TRANSPORTATION INSTITUTE MEMBER OF THE TEXAS A&M UNIVERSITY SYSTEM VOL. 41 NO. 3 2005 Is Texas ready for

    E-Print Network [OSTI]

    . 41 NO. 3 2005 Is Texas ready for high-speed rail? PAGE 2 Pecos facility open for business PAGE 6 Hall background research to determine the feasibility of high- speed rail in Texas. TTI is serving as a resource agency providing expertise and analytical capabilities to the Texas High- speed Rail and Transportation

  10. In 2006, the Alliance of Coastal Technology (ACT) evaluated the performance of five commercial-ready, in situ turbidity sensors at

    E-Print Network [OSTI]

    Boss, Emmanuel S.

    ABSTRACT In 2006, the Alliance of Coastal Technology (ACT) evaluated the performance of five commercial-ready, in situ turbidity sensors at eight test sites located throughout North America (Fig. 1, and a freshwater lake (Fig. 1) . The sensors used in this study consisted of: A backscatter Turbidity Probe ( =660

  11. Apple Harvest Time! Determining when apples are ready to be harvested can be tricky. You need to know the variety of the apple and its approximate harvest

    E-Print Network [OSTI]

    New Hampshire, University of

    Apple Harvest Time! Determining when apples are ready to be harvested can be tricky. You need to know the variety of the apple and its approximate harvest date. These dates vary each year with fluctuations in blooming rates, degree days and rainfall. If you're growing your own apples, perhaps the best

  12. 324 Building B-Cell Pressurized Water Reactor Spent Fuel Packaging & Shipment RL Readiness Assessment Final Report [SEC 1 Thru 3

    SciTech Connect (OSTI)

    HUMPHREYS, D C

    2002-08-01

    A parallel readiness assessment (RA) was conducted by independent Fluor Hanford (FH) and U. S. Department of Energy, Richland Operations Office (RL) team to verify that an adequate state of readiness had been achieved for activities associated with the packaging and shipping of pressurized water reactor fuel assemblies from B-Cell in the 324 Building to the interim storage area at the Canister Storage Building in the 200 Area. The RL review was conducted in parallel with the FH review in accordance with the Joint RL/FH Implementation Plan (Appendix B). The RL RA Team members were assigned a FH RA Team counterpart for the review. With this one-on-one approach, the RL RA Team was able to assess the FH Team's performance, competence, and adherence to the implementation plan and evaluate the level of facility readiness. The RL RA Team agrees with the FH determination that startup of the 324 Building B-Cell pressurized water reactor spent nuclear fuel packaging and shipping operations can safely proceed, pending completion of the identified pre-start items in the FH final report (see Appendix A), completion of the manageable list of open items included in the facility's declaration of readiness, and execution of the startup plan to operations.

  13. Math 115 Self-Assessment Test is designed to assist you to determine how ready you are to take Math 115 (Pre-Calculus) at UNBC.

    E-Print Network [OSTI]

    Northern British Columbia, University of

    Math/Stats Math 115 Self-Assessment Test is designed to assist you to determine how ready you are to take Math 115 (Pre-Calculus) at UNBC. Contents 1. About Math 115 2. How to take the Self Assessment Test 3. The Test 4. Scoring the Test, and What to do Next 1. About Math 115 (Pre-Calculus) at UNBC

  14. Reducing Extreme Weather Impacts: Building a Weather-Ready Nation For more than 140 years, the National Weather Service (NWS) has provided weather, water, and climate

    E-Print Network [OSTI]

    Reducing Extreme Weather Impacts: Building a Weather-Ready Nation For more than 140 years, the National Weather Service (NWS) has provided weather, water, and climate information to protect lives also been a year of extreme weather events. The impact of these events, both on lives and the economy

  15. Lead Coolant Test Facility - Design Concept and Requirements

    SciTech Connect (OSTI)

    Soli Khericha, Ph. D.

    2011-08-01

    The Idaho National Laboratory prepared a preliminary technical and functional requirements (T&FR), thermal hydraulic design and cost estimate for a lead coolant test facility. The purpose of this small scale facility is to simulate lead coolant fast reactor (LFR) coolant flow in an open lattice geometry core using seven electrical rods and liquid lead or lead-bismuth eutectic. Based on review of current world lead or lead-bismuth test facilities and research need listed in the Generation IV Roadmap, five broad areas of requirements are identified in this paper: (1) Develop and Demonstrate Feasibility of Submerged Heat Exchanger; (2) Develop and Demonstrate Open-lattice Flow in Electrically Heated Core; (3) Develop and Demonstrate Chemistry Control; (4) Demonstrate Safe Operation; and (5) Provision for Future Testing Across these five broad areas are supported by twenty-one specific requirements. The purpose of this facility is to focus the lead fast reactor community domestically on the requirements for the next unique state of the art test facility. The facility thermal hydraulic design is based on the maximum simulated core power using seven electrical heater rods of 420 kW; average linear heat generation rate of 300 W/cm. The core inlet temperature for liquid lead or Pb/Bi eutectic is 4200C. The design includes approximately seventy-five data measurements such as pressure, temperature, and flow rates. The preliminary estimated cost of construction of the facility is $3.7M (in 2006 $). It is also estimated that the facility will require two years to be constructed and ready for operation.

  16. Hyperfine structure of the hydroxyl free radical (OH) in electric and magnetic fields

    E-Print Network [OSTI]

    Maeda, Kenji; Carr, Lincoln D

    2014-01-01

    We investigate single-particle energy spectra of the hydroxyl free radical (OH) in the lowest electronic and rovibrational level under combined static electric and magnetic fields, as an example of heteronuclear polar diatomic molecules. In addition to the fine-structure interactions, the hyperfine interactions and centrifugal distortion effects are taken into account to yield the zero-field spectrum of the lowest ${}^2\\Pi_{3/2}$ manifold to an accuracy of less than 2 kHz. We also examine level crossings and repulsions in the hyperfine structure induced by applied electric and magnetic fields. Compared to previous work, we found more than 10 percent reduction of the magnetic fields at level repulsions in the Zeeman spectrum subjected to a perpendicular electric field. It is important to take into account hyperfine structure when we investigate physics of OH molecules at micro-Kelvin temperatures and below.

  17. Reactive Molecular Dynamics study on the first steps of DNA-damage by free hydroxyl radicals

    E-Print Network [OSTI]

    Abolfath, Ramin M; Brabec, Thomas

    2011-01-01

    We employ a large scale molecular simulation based on bond-order ReaxFF to simulate the chemical reaction and study the damage to a large fragment of DNA-molecule in the solution by ionizing radiation. We illustrate that the randomly distributed clusters of diatomic OH-radicals that are primary products of megavoltage ionizing radiation in water-based systems are the main source of hydrogen-abstraction as well as formation of carbonyl- and hydroxyl-groups in the sugar-moiety that create holes in the sugar-rings. These holes grow up slowly between DNA-bases and DNA-backbone and the damage collectively propagate to DNA single and double strand break.

  18. Production of cold formaldehyde molecules for study and control of chemical reaction dynamics with hydroxyl radicals

    E-Print Network [OSTI]

    Hudson, E R; Sawyer, B C; Taatjes, C A; Lewandowski, H J; Bochinski, J R; Bohn, J L; Ye, J; Hudson, Eric R.; Ticknor, Christopher; Sawyer, Brian C.; Taatjes, Craig A.; Bohn, John L.; Ye, Jun

    2005-01-01

    We propose a method for controlling a class of low temperature chemical reactions. Specifically, we show the hydrogen abstraction channel in the reaction of formaldehyde (H$_{2}$CO) and the hydroxyl radical (OH) can be controlled through either the molecular state or an external electric field. We also outline experiments for investigating and demonstrating control over this important reaction. To this end, we report the first Stark deceleration of the H$_{2}$CO molecule. We have decelerated a molecular beam of H$_{2}$CO essentially to rest, producing cold molecule packets at a temperature of 100 mK with a few million molecules in the packet at a density of $\\sim10^{6}$ cm$^{-3}$.

  19. New Whole-House Solutions Case Study: Zero Energy Ready Home Multifamily Project: Mutual Housing at Spring Lake

    SciTech Connect (OSTI)

    D. Springer and A. German

    2015-09-01

    Building cost effective, high performance homes that provide superior comfort, health, and durability is the goal of the Department of Energy's (DOE's) Zero Energy Ready Homes (ZERH) program. This case study describes the development of a 62-unit multifamily community constructed by nonprofit developer Mutual Housing at the Spring Lake subdivision in Woodland, California. The Spring Lake project is expected to be the first ZERH-certified multifamily project nationwide. Building America team Alliance for Residential Building Innovation worked with Mutual Housing throughout the project. An objective of this project was to gain a highly visible foothold for residential buildings built to the DOE ZERH specification that can be used to encourage participation by other California builders.

  20. Condensation Reactions between 1,3-Butadiene Radical Cation and Acetylene in the Gas Guy Bouchoux,*, Minh Tho Nguyen, and Jean-Yves Salpin,

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    Condensation Reactions between 1,3-Butadiene Radical Cation and Acetylene in the Gas Phase Guy experimental and theoretical results concerning the reaction of [1,3-butadiene]+· radical cation, 1-Alder reaction involving ionized 1,3-butadiene and ethylene gives ionized cyclopenteny