National Library of Energy BETA

Sample records for reactor integrated gasification

  1. Pneumatic solids feeder for coal gasification reactor

    SciTech Connect (OSTI)

    Notestein, J.E.; Halow, J.S.

    1991-12-31

    This invention is comprised of a pneumatic feeder system for a coal gasification reactor which includes one or more feeder tubes entering the reactor above the level of the particle bed inside the reactor. The tubes are inclined downward at their outer ends so that coal particles introduced into the tubes through an aperture at the top of the tubes slides downward away from the reactor and does not fall directly into the reactor. Pressurized gas introduced into, or resulting from ignition of recycled combustible gas in a chamber adjacent to the tube ends, propels the coal from the tube into the reactor volume and onto the particle bed. Leveling of the top of the bed is carried out by a bladed rotor mounted on the reactor stirring shaft. Coal is introduced into the tubes from containers above the tubes by means of rotary valves placed across supply conduits. This system avoids placement of feeder hardware in the plenum above the particle bed and keeps the coal from being excessively heated prior to reaching the particle bed.

  2. Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper

    SciTech Connect (OSTI)

    A.M. Gandrik

    2012-04-01

    This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

  3. Solar coal gasification reactor with pyrolysis gas recycle

    DOE Patents [OSTI]

    Aiman, William R.; Gregg, David W.

    1983-01-01

    Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

  4. A Texas project illustrates the benefits of integrated gasification

    SciTech Connect (OSTI)

    Philcox, J.; Fenner, G.W.

    1997-07-14

    Gasification can be an attractive option for converting a variety of petroleum feedstocks to chemicals. Natural gas is commonly sued to produce acetic acid, isocyanates, plastics, and fibers. But low-cost, bottom-of-the-barrel feeds, such as vacuum resid, petroleum coke, and asphaltenes, also can be used. In any case, gasification products include synthesis gas, carbon monoxide, hydrogen, steam, carbon dioxide, and power. The more a gasification facility is integrated with utilities and other non-core operations of a production complex, the more economical the products are for all consumers. The paper discusses gasification of natural gas, light hydrocarbons (ethane, propanes, and butanes), and heavy hydrocarbons (distillates, heavy residues, asphalts, coals, petroleum coke). The paper then describes a Texas City Gasification Project, which gasifies methane to produce carbon monoxide, hydrogen, and alcohol. The plant is integrated with a cogeneration plant. Economics are discussed.

  5. Second stage gasifier in staged gasification and integrated process

    DOE Patents [OSTI]

    Liu, Guohai; Vimalchand, Pannalal; Peng, Wan Wang

    2015-10-06

    A second stage gasification unit in a staged gasification integrated process flow scheme and operating methods are disclosed to gasify a wide range of low reactivity fuels. The inclusion of second stage gasification unit operating at high temperatures closer to ash fusion temperatures in the bed provides sufficient flexibility in unit configurations, operating conditions and methods to achieve an overall carbon conversion of over 95% for low reactivity materials such as bituminous and anthracite coals, petroleum residues and coke. The second stage gasification unit includes a stationary fluidized bed gasifier operating with a sufficiently turbulent bed of predefined inert bed material with lean char carbon content. The second stage gasifier fluidized bed is operated at relatively high temperatures up to 1400.degree. C. Steam and oxidant mixture can be injected to further increase the freeboard region operating temperature in the range of approximately from 50 to 100.degree. C. above the bed temperature.

  6. EIS-0409: Kemper County Integrated Gasification Combined Cycle Project, Mississippi

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's decision to provide funding for the Kemper County Integrated Gasification Combined Cycle Project in Kemper County, Mississippi to assess the potential environmental impacts associated with the construction and operation of a project proposed by Southern Power Company, through its affiliate Mississippi Power Company, which has been selected by DOE for consideration under the Clean Coal Power Initiative (CCPI) program.

  7. Integrated gasification fuel cell (IGFC) demonstration test

    SciTech Connect (OSTI)

    Steinfeld, G.; Ghezel-Ayagh, H.; Sanderson, R.; Abens, S.

    2000-07-01

    As concern about the environment generates interest in ultra-clean energy plants, fuel cell power plants can respond to the challenge. Fuel cells convert hydrocarbon fuels to electricity at efficiencies exceeding conventional heat engine technologies while generating extremely low emissions. Emissions of SOx and NOx are expected to be well below current and anticipated future standards. Nitrogen oxides, a product of combustion, will be extremely low in this power plant because power is produced electrochemically rather than by combustion. Due to its higher efficiencies, a fuel cell power plant also produces less carbon dioxide. Fuel cells in combination with coal gasification, are an efficient and environmentally acceptable means to utilize the abundant coal reserves both in the US and around the world. To demonstrate this technology, FuelCell Energy, Inc. (FCE), is planning to build and test a 2-MW Fuel Cell Power Plant for operation on coal derived gas. This power plant is based on Direct Fuel Cell (DFC{trademark}) technology and will be part of a Clean Coal V IGCC project supported by the US DOE. A British Gas Lurgi (BGL) slagging fixed-bed gasification system with cold gas clean up is planned as part of a 400 MW IGCC power plant to provide a fuel gas slip stream to the fuel cell. The IGFC power plant will be built by Kentucky Pioneer Energy, A subsidiary of Global Energy, in Clark County, KY. This demonstration will result in the world's largest fuel cell power plant operating on coal derived gas. The objective of this test is to demonstrate fuel cell operation on coal derived gas at a commercial scale and to verify the efficiency and environmental benefits.

  8. Heavy oil upgrading using an integrated gasification process

    SciTech Connect (OSTI)

    Quintana, M.E.; Falsetti, J.S.

    1995-12-31

    The value of abundant, low-grade heavy crude oil reserves can be enhanced by appropriate upgrade processing at the production site to yield marketable refinery feedstocks or ultimate products. One of the upgrading process sequences most commonly considered involves vacuum distillation followed by a bottoms processing step such as solvent deasphalting or coking. These schemes can be further enhanced with the addition of a gasification step to convert the unsaleable, bottom-of-the-barrel residues into useful products, such as high-purity hydrogen for hydrotreating, electrical power, steam for enhanced oil recovery and distillation, etc. This paper describes the Texaco Gasification Process and the T-STARs hydrotreating process, and their application in an integrated upgrade processing scheme in which an optimal, virtually bottomless oil utilization can be achieved. Illustrative examples of this integration are provided with comparative economic information.

  9. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael L. Swanson

    2005-08-30

    The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was

  10. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W.

    1980-01-01

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  11. Small Modular Nuclear Reactors: Parametric Modeling of Integrated...

    Office of Environmental Management (EM)

    Small Modular Nuclear Reactors: Parametric Modeling of Integrated Reactor Vessel ... Small Modular Nuclear Reactors: Parametric Modeling of Integrated Reactor Vessel ...

  12. Model Predictive Control of Integrated Gasification Combined Cycle Power Plants

    SciTech Connect (OSTI)

    B. Wayne Bequette; Priyadarshi Mahapatra

    2010-08-31

    The primary project objectives were to understand how the process design of an integrated gasification combined cycle (IGCC) power plant affects the dynamic operability and controllability of the process. Steady-state and dynamic simulation models were developed to predict the process behavior during typical transients that occur in plant operation. Advanced control strategies were developed to improve the ability of the process to follow changes in the power load demand, and to improve performance during transitions between power levels. Another objective of the proposed work was to educate graduate and undergraduate students in the application of process systems and control to coal technology. Educational materials were developed for use in engineering courses to further broaden this exposure to many students. ASPENTECH software was used to perform steady-state and dynamic simulations of an IGCC power plant. Linear systems analysis techniques were used to assess the steady-state and dynamic operability of the power plant under various plant operating conditions. Model predictive control (MPC) strategies were developed to improve the dynamic operation of the power plants. MATLAB and SIMULINK software were used for systems analysis and control system design, and the SIMULINK functionality in ASPEN DYNAMICS was used to test the control strategies on the simulated process. Project funds were used to support a Ph.D. student to receive education and training in coal technology and the application of modeling and simulation techniques.

  13. INTEGRATED GASIFICATION COMBINED CYCLE PROJECT 2 MW FUEL CELL DEMONSTRATION

    SciTech Connect (OSTI)

    FuelCell Energy

    2005-05-16

    With about 50% of power generation in the United States derived from coal and projections indicating that coal will continue to be the primary fuel for power generation in the next two decades, the Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCTDP) has been conducted since 1985 to develop innovative, environmentally friendly processes for the world energy market place. The 2 MW Fuel Cell Demonstration was part of the Kentucky Pioneer Energy (KPE) Integrated Gasification Combined Cycle (IGCC) project selected by DOE under Round Five of the Clean Coal Technology Demonstration Program. The participant in the CCTDP V Project was Kentucky Pioneer Energy for the IGCC plant. FuelCell Energy, Inc. (FCE), under subcontract to KPE, was responsible for the design, construction and operation of the 2 MW fuel cell power plant. Duke Fluor Daniel provided engineering design and procurement support for the balance-of-plant skids. Colt Engineering Corporation provided engineering design, fabrication and procurement of the syngas processing skids. Jacobs Applied Technology provided the fabrication of the fuel cell module vessels. Wabash River Energy Ltd (WREL) provided the test site. The 2 MW fuel cell power plant utilizes FuelCell Energy's Direct Fuel Cell (DFC) technology, which is based on the internally reforming carbonate fuel cell. This plant is capable of operating on coal-derived syngas as well as natural gas. Prior testing (1992) of a subscale 20 kW carbonate fuel cell stack at the Louisiana Gasification Technology Inc. (LGTI) site using the Dow/Destec gasification plant indicated that operation on coal derived gas provided normal performance and stable operation. Duke Fluor Daniel and FuelCell Energy developed a commercial plant design for the 2 MW fuel cell. The plant was designed to be modular, factory assembled and truck shippable to the site. Five balance-of-plant skids incorporating fuel processing, anode gas oxidation, heat recovery, water

  14. Light Water Reactor Sustainability Program - Integrated Program...

    Office of Environmental Management (EM)

    Program - Integrated Program Plan Light Water Reactor Sustainability Program - Integrated Program Plan The Light Water Reactor Sustainability (LWRS) Program is a research and ...

  15. NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE

    SciTech Connect (OSTI)

    Dennis A. Horazak; Richard A. Newby; Eugene E. Smeltzer; Rachid B. Slimane; P. Vann Bush; James L. Aderhold Jr; Bruce G. Bryan

    2005-12-01

    Development efforts have been underway for decades to replace dry-gas cleaning technology with humid-gas cleaning technology that would maintain the water vapor content in the raw gas by conducting cleaning at sufficiently high temperature to avoid water vapor condensation and would thus significantly simplify the plant and improve its thermal efficiency. Siemens Power Generation, Inc. conducted a program with the Gas Technology Institute (GTI) to develop a Novel Gas Cleaning process that uses a new type of gas-sorbent contactor, the ''filter-reactor''. The Filter-Reactor Novel Gas Cleaning process described and evaluated here is in its early stages of development and this evaluation is classified as conceptual. The commercial evaluations have been coupled with integrated Process Development Unit testing performed at a GTI coal gasifier test facility to demonstrate, at sub-scale the process performance capabilities. The commercial evaluations and Process Development Unit test results are presented in Volumes 1 and 2 of this report, respectively. Two gas cleaning applications with significantly differing gas cleaning requirements were considered in the evaluation: IGCC power generation, and Methanol Synthesis with electric power co-production. For the IGCC power generation application, two sets of gas cleaning requirements were applied, one representing the most stringent ''current'' gas cleaning requirements, and a second set representing possible, very stringent ''future'' gas cleaning requirements. Current gas cleaning requirements were used for Methanol Synthesis in the evaluation because these cleaning requirements represent the most stringent of cleaning requirements and the most challenging for the Filter-Reactor Novel Gas Cleaning process. The scope of the evaluation for each application was: (1) Select the configuration for the Filter-Reactor Novel Gas Cleaning Process, the arrangement of the individual gas cleaning stages, and the probable operating

  16. Tampa Electric Company`s Polk Power Station Integrated Gasification Combined Cycle Project

    SciTech Connect (OSTI)

    Jenkins, S.D.; Shafer, J.R.

    1994-12-31

    Tampa Electric Company (TEC) is in the construction phase for the new Polk Power Station, Unit {number_sign}1. This will be the first unit at a new site and will use Integrated Gasification Combined Cycle (IGCC) technology for power generation. The unit will utilize oxygen-blown entrained-flow coal gasification, along with combined cycle technology, to provide nominal net 26OMW of generation. As part of the environmental features of this process, the sulfur species in the coal will be recovered as a commercial grade sulfuric acid by-product. The sulfur will be removed from the synthesis gas utilizing a cold gas clean-up system (CGCU).

  17. Advanced integration concepts for oxygen plants and gas turbines in gasification/IGCC facilities

    SciTech Connect (OSTI)

    Smith, A.R.; Klosek, J.; Woodward, D.W.

    1996-12-31

    The commercialization of Integrated Gasification Combined-Cycle (IGCC) power has been aided by concepts involving the integration of a cryogenic air separation unit (ASU) with the gas turbine combined-cycle module. Other processes, such as coal-based ironmaking and combined power and industrial gas production facilities, can benefit from the integration of these two units. It is known and now widely accepted that an ASU designed for elevated pressure service and optimally integrated with the gas turbine can increase overall IGCC power output, increase overall efficiency, and decrease the net cost of power generation compared to non-integrated facilities employing low pressure ASU`s. Depending upon the specific gas turbine, gasification technology, NOx emission specification, and other site specific factors, various degrees of compressed air and nitrogen integration are optimal. Air Products has supplied ASU`s with no integration (Destec/Plaquemine IGCC), nitrogen-only integration (Tampa Electric/Polk County IGCC), and full air and nitrogen integration (Demkolec/Buggenum IGCC). Continuing advancements in both air separation and gas turbine technologies offer new integration opportunities to further improve performance and reduce costs. This paper will review basic integration principles and describe advanced concepts based on emerging high compression ratio gas turbines. Humid Air Turbine (HAT) cycles, and integration of compression heat and refrigeration sources from the ASU. Operability issues associated with integration will be reviewed and control measures described for the safe, efficient, and reliable operation of these facilities.

  18. Catalytic combustor for integrated gasification combined cycle power plant

    DOE Patents [OSTI]

    Bachovchin, Dennis M.; Lippert, Thomas E.

    2008-12-16

    A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

  19. Integrated Biomass Gasification with Catalytic Partial Oxidation for Selective Tar Conversion

    SciTech Connect (OSTI)

    Zhang, Lingzhi; Wei, Wei; Manke, Jeff; Vazquez, Arturo; Thompson, Jeff; Thompson, Mark

    2011-05-28

    Biomass gasification is a flexible and efficient way of utilizing widely available domestic renewable resources. Syngas from biomass has the potential for biofuels production, which will enhance energy security and environmental benefits. Additionally, with the successful development of low Btu fuel engines (e.g. GE Jenbacher engines), syngas from biomass can be efficiently used for power/heat co-generation. However, biomass gasification has not been widely commercialized because of a number of technical/economic issues related to gasifier design and syngas cleanup. Biomass gasification, due to its scale limitation, cannot afford to use pure oxygen as the gasification agent that used in coal gasification. Because, it uses air instead of oxygen, the biomass gasification temperature is much lower than well-understood coal gasification. The low temperature leads to a lot of tar formation and the tar can gum up the downstream equipment. Thus, the biomass gasification tar removal is a critical technology challenge for all types of biomass gasifiers. This USDA/DOE funded program (award number: DE-FG36-O8GO18085) aims to develop an advanced catalytic tar conversion system that can economically and efficiently convert tar into useful light gases (such as syngas) for downstream fuel synthesis or power generation. This program has been executed by GE Global Research in Irvine, CA, in collaboration with Professor Lanny Schmidt's group at the University of Minnesota (UoMn). Biomass gasification produces a raw syngas stream containing H2, CO, CO2, H2O, CH4 and other hydrocarbons, tars, char, and ash. Tars are defined as organic compounds that are condensable at room temperature and are assumed to be largely aromatic. Downstream units in biomass gasification such as gas engine, turbine or fuel synthesis reactors require stringent control in syngas quality, especially tar content to avoid plugging (gum) of downstream equipment. Tar- and ash-free syngas streams are a critical

  20. Development of a plant-wide dynamic model of an integrated gasification combined cycle (IGCC) plant

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2009-01-01

    In this presentation, development of a plant-wide dynamic model of an advanced Integrated Gasification Combined Cycle (IGCC) plant with CO2 capture will be discussed. The IGCC reference plant generates 640 MWe of net power using Illinois No.6 coal as the feed. The plant includes an entrained, downflow, General Electric Energy (GEE) gasifier with a radiant syngas cooler (RSC), a two-stage water gas shift (WGS) conversion process, and two advanced 'F' class combustion turbines partially integrated with an elevated-pressure air separation unit (ASU). A subcritical steam cycle is considered for heat recovery steam generation. Syngas is selectively cleaned by a SELEXOL acid gas removal (AGR) process. Sulfur is recovered using a two-train Claus unit with tail gas recycle to the AGR. A multistage intercooled compressor is used for compressing CO2 to the pressure required for sequestration. Using Illinois No.6 coal, the reference plant generates 640 MWe of net power. The plant-wide steady-state and dynamic IGCC simulations have been generated using the Aspen Plus{reg_sign} and Aspen Plus Dynamics{reg_sign} process simulators, respectively. The model is generated based on the Case 2 IGCC configuration detailed in the study available in the NETL website1. The GEE gasifier is represented with a restricted equilibrium reactor model where the temperature approach to equilibrium for individual reactions can be modified based on the experimental data. In this radiant-only configuration, the syngas from the Radiant Syngas Cooler (RSC) is quenched in a scrubber. The blackwater from the scrubber bottom is further cleaned in the blackwater treatment plant. The cleaned water is returned back to the scrubber and also used for slurry preparation. The acid gas from the sour water stripper (SWS) is sent to the Claus plant. The syngas from the scrubber passes through a sour shift process. The WGS reactors are modeled as adiabatic plug flow reactors with rigorous kinetics based on the mid

  1. Transient studies of an Integrated Gasification Combined Cycle (IGCC) plant with CO2 capture

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2010-01-01

    Next-generation coal-fired power plants need to consider the option for CO2 capture as stringent governmental mandates are expected to be issued in near future. Integrated gasification combined cycle (IGCC) plants are more efficient than the conventional coal combustion processes when the option for CO2 capture is considered. However, no IGCC plant with CO2 capture currently exists in the world. Therefore, it is important to consider the operability and controllability issues of such a plant before it is commercially built. To facilitate this objective, a detailed plant-wide dynamic simulation of an IGCC plant with 90% CO2 capture has been developed in Aspen Plus Dynamics{reg_sign}. The plant considers a General Electric Energy (GEE)-type downflow radiant-only gasifier followed by a quench section. A two-stage water gas shift (WGS) reaction is considered for conversion of CO to CO2. A two-stage acid gas removal (AGR) process based on a physical solvent is simulated for selective capture of H2S and CO2. Compression of the captured CO2 for sequestration, an oxy-Claus process for removal of H2S and NH3, black water treatment, and the sour water treatment are also modeled. The tail gas from the Claus unit is recycled to the SELEXOL unit. The clean syngas from the AGR process is sent to a gas turbine followed by a heat recovery steam generator. This turbine is modeled as per published data in the literature. Diluent N2 is used from the elevated-pressure ASU for reducing the NOx formation. The heat recovery steam generator (HRSG) is modeled by considering generation of high-pressure, intermediate-pressure, and low-pressure steam. All of the vessels, reactors, heat exchangers, and the columns have been sized. The basic IGCC process control structure has been synthesized by standard guidelines and existing practices. The steady state results are validated with data from a commercial gasifier. In the future grid-connected system, the plant should satisfy the environmental

  2. Steam Gasification Rates of Three Bituminous Coal Chars in an Entrained-Flow Reactor at Pressurized Conditions

    SciTech Connect (OSTI)

    Lewis, Aaron D.; Holland, Troy M.; Marchant, Nathaniel R.; Fletcher, Emmett G.; Henley, Daniel J.; Fuller, Eric G.; Fletcher, Thomas H.

    2015-02-26

    Three bituminous coal chars (Illinois #6, Utah Skyline, and Pittsburgh #8) were gasified separately at total pressures of 10 and 15 atm in an entrained-flow reactor using gas temperatures up to 1830 K and particle residence times <240 ms. The experiments were performed at conditions where the majority of particle mass release was due to H2O gasification, although select experiments were performed at conditions where significant mass release was due to gasification by both H2O and CO2. The measured coal data we recorded were fit to three char gasification models including a simple first-order global model, as well as the CCKNand CCK models that stem from the CBK model. The optimal kinetic parameters for each of the three models are reported, and the steam reactivity of the coal chars at the studied conditions is as follows: Pittsburgh #8 > Utah Skyline > Illinois #6.

  3. Gasification Research Center

    SciTech Connect (OSTI)

    2006-09-01

    Gas Technology Institute (GTI) is leading an effort to integrate and evaluate syngas cleanup and treatment technologies for syngas from biomass gasification processes.

  4. Gasification system

    DOE Patents [OSTI]

    Haldipur, Gaurang B.; Anderson, Richard G.; Cherish, Peter

    1983-01-01

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  5. Gasification system

    DOE Patents [OSTI]

    Haldipur, Gaurang B.; Anderson, Richard G.; Cherish, Peter

    1985-01-01

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  6. CoalFleet RD&D augmentation plan for integrated gasification combined cycle (IGCC) power plants

    SciTech Connect (OSTI)

    2007-01-15

    To help accelerate the development, demonstration, and market introduction of integrated gasification combined cycle (IGCC) and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiative, which facilitates collaborative research by more than 50 organizations from around the world representing power generators, equipment suppliers and engineering design and construction firms, the U.S. Department of Energy, and others. This group advised EPRI as it evaluated more than 120 coal-gasification-related research projects worldwide to identify gaps or critical-path activities where additional resources and expertise could hasten the market introduction of IGCC advances. The resulting 'IGCC RD&D Augmentation Plan' describes such opportunities and how they could be addressed, for both IGCC plants to be built in the near term (by 2012-15) and over the longer term (2015-25), when demand for new electric generating capacity is expected to soar. For the near term, EPRI recommends 19 projects that could reduce the levelized cost-of-electricity for IGCC to the level of today's conventional pulverized-coal power plants with supercritical steam conditions and state-of-the-art environmental controls. For the long term, EPRI's recommended projects could reduce the levelized cost of an IGCC plant capturing 90% of the CO{sub 2} produced from the carbon in coal (for safe storage away from the atmosphere) to the level of today's IGCC plants without CO{sub 2} capture. EPRI's CoalFleet for Tomorrow program is also preparing a companion RD&D augmentation plan for advanced-combustion-based (i.e., non-gasification) clean coal technologies (Report 1013221). 7 refs., 30 figs., 29 tabs., 4 apps.

  7. Model predictive control system and method for integrated gasification combined cycle power generation

    DOE Patents [OSTI]

    Kumar, Aditya; Shi, Ruijie; Kumar, Rajeeva; Dokucu, Mustafa

    2013-04-09

    Control system and method for controlling an integrated gasification combined cycle (IGCC) plant are provided. The system may include a controller coupled to a dynamic model of the plant to process a prediction of plant performance and determine a control strategy for the IGCC plant over a time horizon subject to plant constraints. The control strategy may include control functionality to meet a tracking objective and control functionality to meet an optimization objective. The control strategy may be configured to prioritize the tracking objective over the optimization objective based on a coordinate transformation, such as an orthogonal or quasi-orthogonal projection. A plurality of plant control knobs may be set in accordance with the control strategy to generate a sequence of coordinated multivariable control inputs to meet the tracking objective and the optimization objective subject to the prioritization resulting from the coordinate transformation.

  8. Method and system to estimate variables in an integrated gasification combined cycle (IGCC) plant

    DOE Patents [OSTI]

    Kumar, Aditya; Shi, Ruijie; Dokucu, Mustafa

    2013-09-17

    System and method to estimate variables in an integrated gasification combined cycle (IGCC) plant are provided. The system includes a sensor suite to measure respective plant input and output variables. An extended Kalman filter (EKF) receives sensed plant input variables and includes a dynamic model to generate a plurality of plant state estimates and a covariance matrix for the state estimates. A preemptive-constraining processor is configured to preemptively constrain the state estimates and covariance matrix to be free of constraint violations. A measurement-correction processor may be configured to correct constrained state estimates and a constrained covariance matrix based on processing of sensed plant output variables. The measurement-correction processor is coupled to update the dynamic model with corrected state estimates and a corrected covariance matrix. The updated dynamic model may be configured to estimate values for at least one plant variable not originally sensed by the sensor suite.

  9. Integrated reformer and shift reactor

    DOE Patents [OSTI]

    Bentley, Jeffrey M.; Clawson, Lawrence G.; Mitchell, William L.; Dorson, Matthew H.

    2006-06-27

    A hydrocarbon fuel reformer for producing diatomic hydrogen gas is disclosed. The reformer includes a first reaction vessel, a shift reactor vessel annularly disposed about the first reaction vessel, including a first shift reactor zone, and a first helical tube disposed within the first shift reactor zone having an inlet end communicating with a water supply source. The water supply source is preferably adapted to supply liquid-phase water to the first helical tube at flow conditions sufficient to ensure discharge of liquid-phase and steam-phase water from an outlet end of the first helical tube. The reformer may further include a first catalyst bed disposed in the first shift reactor zone, having a low-temperature shift catalyst in contact with the first helical tube. The catalyst bed includes a plurality of coil sections disposed in coaxial relation to other coil sections and to the central longitudinal axis of the reformer, each coil section extending between the first and second ends, and each coil section being in direct fluid communication with at least one other coil section.

  10. Gasification of refinery sludge in an updraft reactor for syngas production

    SciTech Connect (OSTI)

    Ahmed, Reem; Eldmerdash, Usama; Sinnathambi, Chandra M.

    2014-10-24

    The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H{sub 2}, CH{sub 4} compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO{sub 2}+C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm{sup −3} of, and 2.5 Nm{sup 3} kg{sup −1} respectively.

  11. Small Modular Nuclear Reactors: Parametric Modeling of Integrated...

    Office of Environmental Management (EM)

    Reactor Vessel Manufacturing Within a Factory Environment - Volume 1 This study focused on the learning process for the factory built components of the Integrated Reactor ...

  12. Preliminary Experimental Results of Integrated Gasification Fuel Cell Operation Using Hardware Simulation

    SciTech Connect (OSTI)

    Traverso, Alberto; Tucker, David; Haynes, Comas L.

    2012-07-01

    A newly developed integrated gasification fuel cell (IGFC) hybrid system concept has been tested using the Hybrid Performance (Hyper) project hardware-based simulation facility at the U.S. Department of Energy, National Energy Technology Laboratory. The cathode-loop hardware facility, previously connected to the real-time fuel cell model, was integrated with a real-time model of a gasifier of solid (biomass and fossil) fuel. The fuel cells are operated at the compressor delivery pressure, and they are fueled by an updraft atmospheric gasifier, through the syngas conditioning train for tar removal and syngas compression. The system was brought to steady state; then several perturbations in open loop (variable speed) and closed loop (constant speed) were performed in order to characterize the IGFC behavior. Coupled experiments and computations have shown the feasibility of relatively fast control of the plant as well as a possible mitigation strategy to reduce the thermal stress on the fuel cells as a consequence of load variation and change in gasifier operating conditions. Results also provided an insight into the different features of variable versus constant speed operation of the gas turbine section.

  13. Highly Selective H2 Separation Zeolite Membranes for Coal Gasification Membrane Reactor Applications

    SciTech Connect (OSTI)

    Mei Hong; Richard D. Noble; John L. Falconer

    2006-09-24

    Zeolite membranes are thermally, chemically, and mechanically stable. They also have tunable molecular sieving and catalytic ability. These unique properties make zeolite membrane an excellent candidate for use in catalytic membrane reactor applications related to coal conversion and gasification, which need high temperature and high pressure range separation in chemically challenging environment where existing technologies are inefficient or unable to operate. Small pore, good quality, and thin zeolite membranes are needed for highly selective H{sub 2} separation from other light gases (CO{sub 2}, CH{sub 4}, CO). However, zeolite membranes have not been successful for H{sub 2} separation from light gases because the zeolite pores are either too big or the membranes have a large number of defects. The objective of this study is to develop zeolite membranes that are more suitable for H{sub 2} separation. In an effort to tune the size of zeolite pores and/or to decrease the number of defects, medium-pore zeolite B-ZSM-5 (MFI) membranes were synthesized and silylated. Silylation on B-ZSM-5 crystals reduced MFI-zeolite pore volume, but had little effect on CO{sub 2} and CH{sub 4} adsorption. Silylation on B-ZSM-5 membranes increased H{sub 2} selectivity both in single component and in mixtures with CO{sub 2}CO{sub 2}, CH{sub 4}, or N2. Single gas and binary mixtures of H{sub 2}/CO{sub 2} and H{sub 2}/CH{sub 4} were separated through silylated B-ZSM-5 membranes at feed pressures up to 1.7 MPa and temperatures up to 773 K. For one BZSM-5 membrane after silylation, the H2/CO{sub 2} separation selectivity at 473 K increased from 1.4 to 37, whereas the H{sub 2}/CH{sub 4} separation selectivity increased from 1.6 to 33. Hydrogen permeance through a silylated B-ZSM-5 membrane was activated, but the CO{sub 2} and CH4 permeances decreased slightly with temperature in both single gas and in mixtures. Therefore, the H{sub 2} permeance and H{sub 2}/CO{sub 2} and H{sup 2} /CH{sub 4

  14. Highly Selective H2 Separation Zeolite Membranes for Coal Gasification Membrane Reactor Applications

    SciTech Connect (OSTI)

    Mei Hong; Richard Noble; John Falconer

    2007-09-24

    Zeolite membranes are thermally, chemically, and mechanically stable. They also have tunable molecular sieving and catalytic ability. These unique properties make zeolite membrane an excellent candidate for use in catalytic membrane reactor applications related to coal conversion and gasification, which need high temperature and high pressure range separation in chemically challenging environment where existing technologies are inefficient or unable to operate. Small pore, good quality, and thin zeolite membranes are needed for highly selective H2 separation from other light gases (CO2, CH4, CO). However, current zeolite membranes have either too big zeolite pores or a large number of defects and have not been successful for H2 separation from light gases. The objective of this study is to develop zeolite membranes that are more suitable for H2 separation. In an effort to tune the size of zeolite pores and/or to decrease the number of defects, medium-pore zeolite B-ZSM-5 (MFI) membranes were synthesized and silylated. Silylation on B-ZSM-5 crystals reduced MFI-zeolite pore volume, but had little effect on CO2 and CH4 adsorption. Silylation on B-ZSM-5 membranes increased H2 selectivity both in single component and in mixtures with CO2, CH4, or N2. Single gas and binary mixtures of H2/CO2 and H2/CH4 were permeated through silylated B-ZSM-5 membranes at feed pressures up to 1.7 MPa and temperatures up to 773 K. For one B-ZSM-5 membrane after silylation, the H2/CO2 separation selectivity at 473 K increased from 1.4 to 37, whereas the H2/CH4 separation selectivity increased from 1.6 to 33. Hydrogen permeance through a silylated BZSM-5 membrane was activated with activation energy of {approx}10 kJ/mol, but the CO2 and CH4 permeances decreased slightly with temperature in both single gas and in mixtures. Therefore, the H2 permeance and H2/CO2 and H2/CH4 separation selectivities increased with temperature. At 673 K, the H2 permeance was 1.0x10-7 mol{center_dot}m-2{center

  15. EIS-0428: Mississippi Gasification, LLC, Industrial Gasification...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS EIS-0428: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS ...

  16. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification

    SciTech Connect (OSTI)

    Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

    2012-06-20

    Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

  17. Integrated Sensing and Controls for Coal Gasification - Development of Model-Based Controls for GE's Gasifier and Syngas Cooler

    SciTech Connect (OSTI)

    Aditya Kumar

    2010-12-30

    This report summarizes the achievements and final results of this program. The objective of this program is to develop a comprehensive systems approach to integrated design of sensing and control systems for an Integrated Gasification Combined Cycle (IGCC) plant, using advanced model-based techniques. In particular, this program is focused on the model-based sensing and control system design for the core gasification section of an IGCC plant. The overall approach consists of (i) developing a first-principles physics-based dynamic model of the gasification section, (ii) performing model-reduction where needed to derive low-order models suitable for controls analysis and design, (iii) developing a sensing system solution combining online sensors with model-based estimation for important process variables not measured directly, and (iv) optimizing the steady-state and transient operation of the plant for normal operation as well as for startup using model predictive controls (MPC). Initially, available process unit models were implemented in a common platform using Matlab/Simulink{reg_sign}, and appropriate model reduction and model updates were performed to obtain the overall gasification section dynamic model. Also, a set of sensor packages were developed through extensive lab testing and implemented in the Tampa Electric Company IGCC plant at Polk power station in 2009, to measure temperature and strain in the radiant syngas cooler (RSC). Plant operation data was also used to validate the overall gasification section model. The overall dynamic model was then used to develop a sensing solution including a set of online sensors coupled with model-based estimation using nonlinear extended Kalman filter (EKF). Its performance in terms of estimating key unmeasured variables like gasifier temperature, carbon conversion, etc., was studied through extensive simulations in the presence sensing errors (noise and bias) and modeling errors (e.g. unknown gasifier kinetics, RSC

  18. Light Water Reactor Sustainability Program - Integrated Program Plan |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Light Water Reactor Sustainability Program - Integrated Program Plan Light Water Reactor Sustainability Program - Integrated Program Plan The Light Water Reactor Sustainability (LWRS) Program is a research and development (R&D) program sponsored by the U. S. Department of Energy (DOE), performed in close collaboration and cooperation with related industry R&D programs. Light Water Reactor Sustainability Program - Integrated Program Plan - Revision 3 (2.66 MB)

  19. Small Modular Nuclear Reactors: Parametric Modeling of Integrated Reactor Vessel Manufacturing Within a Factory Environment- Volume 1

    Broader source: Energy.gov [DOE]

    Small Modular Nuclear Reactors: Parametric Modeling of Integrated Reactor Vessel Manufacturing Within a Factory Environment - Volume 1 August 2013

  20. Small Modular Nuclear Reactors: Parametric Modeling of Integrated Reactor Vessel Manufacturing Within a Factory Environment- Volume 2

    Office of Energy Efficiency and Renewable Energy (EERE)

    Small Modular Nuclear Reactors: Parametric Modeling of Integrated Reactor Vessel Manufacturing Within a Factory Environment - Volume 2 August 2013

  1. EIS-0428: Department of Energy Loan Guarantee for Mississippi Integrated Gasification Combined Cycle, Moss Point, Mississippi

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of a petroleum coke-to-substitute natural gas facility proposed to be built by Mississippi Gasification. The facility would be designed to produce 120 million standard cubic feet of gas per day. Other products would be marketable sulfuric acid, carbon dioxide, argon, and electric power. This project is inactive.

  2. EIS-0429: Department of Energy Loan Guarantee for Indiana Integrated Gasification Combined Cycle, Rockport, IN

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of a coal-to-substitute natural gas facility proposed to be built in Rockport, IN by Indiana Gasification. The facility would utilize Illinois Basin coal. Other products would be marketable sulfuric acid, argon, and electric power. This project is inactive.

  3. Integral Fast Reactor fuel pin processor

    SciTech Connect (OSTI)

    Levinskas, D.

    1993-03-01

    This report discusses the pin processor which receives metal alloy pins cast from recycled Integral Fast Reactor (IFR) fuel and prepares them for assembly into new IFR fuel elements. Either full length as-cast or precut pins are fed to the machine from a magazine, cut if necessary, and measured for length, weight, diameter and deviation from straightness. Accepted pins are loaded into cladding jackets located in a magazine, while rejects and cutting scraps are separated into trays. The magazines, trays, and the individual modules that perform the different machine functions are assembled and removed using remote manipulators and master-slaves.

  4. Integral Fast Reactor fuel pin processor

    SciTech Connect (OSTI)

    Levinskas, D.

    1993-01-01

    This report discusses the pin processor which receives metal alloy pins cast from recycled Integral Fast Reactor (IFR) fuel and prepares them for assembly into new IFR fuel elements. Either full length as-cast or precut pins are fed to the machine from a magazine, cut if necessary, and measured for length, weight, diameter and deviation from straightness. Accepted pins are loaded into cladding jackets located in a magazine, while rejects and cutting scraps are separated into trays. The magazines, trays, and the individual modules that perform the different machine functions are assembled and removed using remote manipulators and master-slaves.

  5. Gasification FAQS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FAQS faq-header-big.jpg GASIFICATION BASICS Q: What is gasification? A: Gasification is the first step in many processes that are used to convert coal into plastic, fertilizer, gasoline, diesel fuel, hydrogen, chemicals, and electricity. Specifically, gasification is a technological process that uses heat, pressure, steam, and often oxygen or air to convert any carbonaceous (carbon-based) raw material into synthesis gas (syngas for short). Syngas is composed primarily of the colorless, odorless,

  6. Gasification Technologie: Opportunities & Challenges

    SciTech Connect (OSTI)

    Breault, R.

    2012-01-01

    This course has been put together to provide a single source document that not only reviews the historical development of gasification but also compares the process to combustion. It also provides a short discussion on integrated gasification and combined cycle processes. The major focus of the course is to describe the twelve major gasifiers being developed today. The hydrodynamics and kinetics of each are reviewed along with the most likely gas composition from each of the technologies when using a variety of fuels under different conditions from air blown to oxygen blown and atmospheric pressure to several atmospheres. If time permits, a more detailed discussion of low temperature gasification will be included.

  7. Integral reactor system and method for fuel cells

    DOE Patents [OSTI]

    Fernandes, Neil Edward; Brown, Michael S; Cheekatamarla, Praveen; Deng, Thomas; Dimitrakopoulos, James; Litka, Anthony F

    2013-11-19

    A reactor system is integrated internally within an anode-side cavity of a fuel cell. The reactor system is configured to convert hydrocarbons to smaller species while mitigating the lower production of solid carbon. The reactor system may incorporate one or more of a pre-reforming section, an anode exhaust gas recirculation device, and a reforming section.

  8. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D.; Dumesic, James A.

    2013-04-02

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  9. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D.; Dumesic, James A.

    2011-01-18

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  10. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D.; Dumesic, James A.

    2012-04-10

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  11. Evaluation of in-vessel corium retention through external reactor vessel cooling for integral reactor

    SciTech Connect (OSTI)

    Park, R. J.; Lee, J. R.; Kim, S. B.; Jin, Y.; Kim, H. Y.

    2012-07-01

    In-vessel corium retention through external reactor vessel cooling (IVR-ERVC) for a small integral reactor has been evaluated to determine the thermal margin for the prevention of a reactor vessel failure. A thermal load analysis from the corium pool to the outer reactor vessel wall in the lower plenum of the reactor vessel has been performed to determine the heat flux distribution. The critical heat flux (CHF) on the outer reactor vessel wall has been determined to fix the maximum heat removal rate through the external coolant between the outer reactor vessel and the insulation of the reactor vessel. Finally, the thermal margin has been evaluated by comparison of the thermal load with the maximum heat removal rate of the CHF on the outer reactor vessel wall. The maximum heat flux from the corium pool to the outer reactor vessel is estimated at approximately 0.25 MW/m{sup 2} in the metallic layer because of the focusing effect. The CHF of the outer reactor vessel is approximately 1.1 MW/m{sup 2} because of a two phase natural circulation mass flow. Since the thermal margin for the IVR-ERVC is sufficient, the reactor vessel integrity is maintained during a severe accident of a small integral reactor. (authors)

  12. Investigation of an integrated switchgrass gasification/fuel cell power plant. Final report for Phase 1 of the Chariton Valley Biomass Power Project

    SciTech Connect (OSTI)

    Brown, R.C.; Smeenk, J.; Steinfeld, G.

    1998-09-30

    The Chariton Valley Biomass Power Project, sponsored by the US Department of Energy Biomass Power Program, has the goal of converting switchgrass grown on marginal farmland in southern Iowa into electric power. Two energy conversion options are under evaluation: co-firing switchgrass with coal in an existing utility boiler and gasification of switchgrass for use in a carbonate fuel cell. This paper describes the second option under investigation. The gasification study includes both experimental testing in a pilot-scale gasifier and computer simulation of carbonate fuel cell performance when operated on gas derived from switchgrass. Options for comprehensive system integration between a carbonate fuel cell and the gasification system are being evaluated. Use of waste heat from the carbonate fuel cell to maximize overall integrated plant efficiency is being examined. Existing fuel cell power plant design elements will be used, as appropriate, in the integration of the gasifier and fuel cell power plant to minimize cost complexity and risk. The gasification experiments are being performed by Iowa State University and the fuel cell evaluations are being performed by Energy Research Corporation.

  13. Integrated Gasification Combined Cycle (IGCC) demonstration project, Polk Power Station -- Unit No. 1. Annual report, October 1993--September 1994

    SciTech Connect (OSTI)

    1995-05-01

    This describes the Tampa Electric Company`s Polk Power Station Unit 1 (PPS-1) Integrated Gasification Combined Cycle (IGCC) demonstration project which will use a Texaco pressurized, oxygen-blown, entrained-flow coal gasifier to convert approximately 2,300 tons per day of coal (dry basis) coupled with a combined cycle power block to produce a net 250 MW electrical power output. Coal is slurried in water, combined with 95% pure oxygen from an air separation unit, and sent to the gasifier to produce a high temperature, high pressure, medium-Btu syngas with a heat content of about 250 Btu/scf (LHV). The syngas then flows through a high temperature heat recovery unit which cools the syngas prior to its entering the cleanup systems. Molten coal ash flows from the bottom of the high temperature heat recovery unit into a water-filled quench chamber where it solidifies into a marketable slag by-product.

  14. Reactor pressure vessel structural integrity research

    SciTech Connect (OSTI)

    Pennell, W.E.; Corwin, W.R.

    1995-04-01

    Development continues on the technology used to assess the safety of irradiation-embrittled nuclear reactor pressure vessels (RPVs) containing flaws. Fracture mechanics tests on RPV steel, coupled with detailed elastic-plastic finite-element analyses of the crack-tip stress fields, have shown that (1) constraint relaxation at the crack tip of shallows surface flaws results in increased data scatter but no increase in the lower-bound fracture toughness, (2) the nil ductility temperature (NDT) performs better than the reference temperature for nil ductility transition (RT{sub NDT}) as a normalizing parameter for shallow-flaw fracture toughness data, (3) biaxial loading can reduce the shallow-flaw fracture toughness, (4) stress-based dual-parameter fracture toughness correlations cannot predict the effect of biaxial loading on a shallow-flaw fracture toughness because in-plane stresses at the crack tip are not influenced by biaxial loading, and (5) an implicit strain-based dual-parameter fracture toughness correlation can predict the effect of biaxial loading on shallow-flaw fracture toughness. Experimental irradiation investigations have shown that (1) the irradiation-induced shift in Charpy V-notch vs temperature behavior may not be adequate to conservatively assess fracture toughness shifts due to embrittlement, and (2) the wide global variations of initial chemistry and fracture properties of a nominally uniform material within a pressure vessel may confound accurate integrity assessments that require baseline properties.

  15. Integrated gasification and plasma cleaning for waste treatment: A life cycle perspective

    SciTech Connect (OSTI)

    Evangelisti, Sara; Tagliaferri, Carla; Clift, Roland; Lettieri, Paola; Taylor, Richard; Chapman, Chris

    2015-09-15

    Highlights: • A life cycle assessment of an advanced two-stage process is undertaken. • A comparison of the impacts of the process when fed with 7 feedstock is presented. • Sensitivity analysis on the system is performed. • The treatment of RDF shows the lowest impact in terms of both GWP and AP. • The plasma shows a small contribution to the overall impact of the plant. - Abstract: In the past, almost all residual municipal waste in the UK was landfilled without treatment. Recent European waste management directives have promoted the uptake of more sustainable treatment technologies, especially for biodegradable waste. Local authorities have started considering other options for dealing with residual waste. In this study, a life cycle assessment of a future 20 MWe plant using an advanced two-stage gasification and plasma technology is undertaken. This plant can thermally treat waste feedstocks with different composition and heating value to produce electricity, steam and a vitrified product. The objective of the study is to analyse the environmental impacts of the process when fed with seven different feedstocks (including municipal solid waste, solid refuse fuel, reuse-derived fuel, wood biomass and commercial & industrial waste) and identify the process steps which contribute more to the environmental burden. A scenario analysis on key processes, such as oxygen production technology, metal recovery and the appropriate choice for the secondary market aggregate material, is performed. The influence of accounting for the biogenic carbon content in the waste from the calculations of the global warming potential is also shown. Results show that the treatment of the refuse-derived fuel has the lowest impact in terms of both global warming potential and acidification potential because of its high heating value. For all the other impact categories analysed, the two-stage gasification and plasma process shows a negative impact for all the waste streams

  16. Process Intensification with Integrated Water-Gas-Shift Membrane Reactor |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Intensification with Integrated Water-Gas-Shift Membrane Reactor Process Intensification with Integrated Water-Gas-Shift Membrane Reactor water-gas-shift.pdf (597.03 KB) More Documents & Publications ITP Energy Intensive Processes: Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry CX-014220: Categorical Exclusion Determination

  17. Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies

    SciTech Connect (OSTI)

    Phillips, S. D.; Tarud, J. K.; Biddy, M. J.; Dutta, A.

    2011-01-01

    This report documents the National Renewable Energy Laboratory's (NREL's) assessment of the feasibility of making gasoline via the methanol-to-gasoline route using syngas from a 2,000 dry metric tonne/day (2,205 U.S. ton/day) biomass-fed facility. A new technoeconomic model was developed in Aspen Plus for this study, based on the model developed for NREL's thermochemical ethanol design report (Phillips et al. 2007). The necessary process changes were incorporated into a biomass-to-gasoline model using a methanol synthesis operation followed by conversion, upgrading, and finishing to gasoline. Using a methodology similar to that used in previous NREL design reports and a feedstock cost of $50.70/dry ton ($55.89/dry metric tonne), the estimated plant gate price is $16.60/MMBtu ($15.73/GJ) (U.S. $2007) for gasoline and liquefied petroleum gas (LPG) produced from biomass via gasification of wood, methanol synthesis, and the methanol-to-gasoline process. The corresponding unit prices for gasoline and LPG are $1.95/gallon ($0.52/liter) and $1.53/gallon ($0.40/liter) with yields of 55.1 and 9.3 gallons per U.S. ton of dry biomass (229.9 and 38.8 liters per metric tonne of dry biomass), respectively.

  18. The U.S. Department of Energy`s integrated gasification combined cycle research, development and demonstration program

    SciTech Connect (OSTI)

    Brdar, R.D.; Cicero, D.C.

    1996-07-01

    Historically, coal has played a major role as a fuel source for power generation both domestically and abroad. Despite increasingly stringent environmental constraints and affordable natural gas, coal will remain one of the primary fuels for producing electricity. This is due to its abundance throughout the world, low price, ease of transport an export, decreasing capital cost for coal-based systems, and the need to maintain fuel diversity. Recognizing the role coal will continue to play, the US Department of Energy (DOE) is working in partnership with industry to develop ways to use this abundant fuel resource in a manner that is more economical, more efficient and environmentally superior to conventional means to burn coal. The most promising of these technologies is integrated gasification combined cycle (IGCC) systems. Although IGCC systems offer many advantages, there are still several hurdles that must be overcome before the technology achieves widespread commercial acceptance. The major hurdles to commercialization include reducing capital and operating costs, reducing technical risk, demonstrating environmental and technical performance at commercial scale, and demonstrating system reliability and operability. Overcoming these hurdles, as well as continued progress in improving system efficiency, are the goals of the DOE IGCC research, development and demonstrate (RD and D) program. This paper provides an overview of this integrated RD and D program and describes fundamental areas of technology development, key research projects and their related demonstration scale activities.

  19. Gasification News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Modular Oxygen Production in Fossil Energy Gasification Systems August 24, 2016 Two projects were selected to develop stand-alone oxygen-production technologies for use in coal gasification processes. The new technologies will produce oxygen of at least 95 percent purity for use in small-scale (500 kilowatt to 5 megawatt) modular power plants at significantly lower cost than commercial state-of-the-art oxygen-production technologies. Archive

  20. EIS-0429: Indiana Gasification, LLC, Industrial Gasification...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EIS-0429: Indiana Gasification, LLC, Industrial Gasification Facility in Rockport, IN and CO2 Pipeline Documents Available for Download EIS-0429: Notice of Intent to Prepare an ...

  1. Uncertainty analysis of integrated gasification combined cycle systems based on Frame 7H versus 7F gas turbines

    SciTech Connect (OSTI)

    Yunhua Zhu; H. Christopher Frey

    2006-12-15

    Integrated gasification combined cycle (IGCC) technology is a promising alternative for clean generation of power and coproduction of chemicals from coal and other feedstocks. Advanced concepts for IGCC systems that incorporate state-of-the-art gas turbine systems, however, are not commercially demonstrated. Therefore, there is uncertainty regarding the future commercial-scale performance, emissions, and cost of such technologies. The Frame 7F gas turbine represents current state-of-practice, whereas the Frame 7H is the most recently introduced advanced commercial gas turbine. The objective of this study was to evaluate the risks and potential payoffs of IGCC technology based on different gas turbine combined cycle designs. Models of entrained-flow gasifier-based IGCC systems with Frame 7F (IGCC-7F) and 7H gas turbine combined cycles (IGCC-7H) were developed in ASPEN Plus. An uncertainty analysis was conducted. Gasifier carbon conversion and project cost uncertainty are identified as the most important uncertain inputs with respect to system performance and cost. The uncertainties in the difference of the efficiencies and costs for the two systems are characterized. Despite uncertainty, the IGCC-7H system is robustly preferred to the IGCC-7F system. Advances in gas turbine design will improve the performance, emissions, and cost of IGCC systems. The implications of this study for decision-making regarding technology selection, research planning, and plant operation are discussed. 38 refs., 11 figs., 5 tabs.

  2. Coal Gasification for Power Generation, 3. edition

    SciTech Connect (OSTI)

    2007-11-15

    The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

  3. Process Intensification with Integrated Water-Gas-Shift Membrane Reactor

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intensification with Integrated Water-Gas-Shift Membrane Reactor Hydrogen-Selective Membranes for High- Pressure Hydrogen Separation This project will develop hydrogen-selective membranes for an innovative water-gas-shift reactor that improves gas separation effciency, enabling reduced energy use and greenhouse gas emissions. Introduction The goal of process intensifcation is to reduce the equipment footprint, energy consumption, and environmental impact of manufacturing processes. One candidate

  4. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect (OSTI)

    Howard Meyer

    2010-11-30

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energy’s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process – High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  5. Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass via Integrated Pyrolysis and Catalytic Hydroconversion - Wastewater Cleanup by Catalytic Hydrothermal Gasification

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Olarte, Mariefel V.; Hart, Todd R.

    2015-06-19

    DOE-EE Bioenergy Technologies Office has set forth several goals to increase the use of bioenergy and bioproducts derived from renewable resources. One of these goals is to facilitate the implementation of the biorefinery. The biorefinery will include the production of liquid fuels, power and, in some cases, products. The integrated biorefinery should stand-alone from an economic perspective with fuels and power driving the economy of scale while the economics/profitability of the facility will be dependent on existing market conditions. UOP LLC proposed to demonstrate a fast pyrolysis based integrated biorefinery. Pacific Northwest National Laboratory (PNNL) has expertise in an important technology area of interest to UOP for use in their pyrolysis-based biorefinery. This CRADA project provides the supporting technology development and demonstration to allow incorporation of this technology into the biorefinery. PNNL developed catalytic hydrothermal gasification (CHG) for use with aqueous streams within the pyrolysis biorefinery. These aqueous streams included the aqueous phase separated from the fast pyrolysis bio-oil and the aqueous byproduct streams formed in the hydroprocessing of the bio-oil to finished products. The purpose of this project was to demonstrate a technically and economically viable technology for converting renewable biomass feedstocks to sustainable and fungible transportation fuels. To demonstrate the technology, UOP constructed and operated a pilot-scale biorefinery that processed one dry ton per day of biomass using fast pyrolysis. Specific objectives of the project were to: The anticipated outcomes of the project were a validated process technology, a range of validated feedstocks, product property and Life Cycle data, and technical and operating data upon which to base the design of a full-scale biorefinery. The anticipated long-term outcomes from successful commercialization of the technology were: (1) the replacement of a significant

  6. Integrated systems analysis of the PIUS reactor

    SciTech Connect (OSTI)

    Fullwood, F.; Kroeger, P.; Higgins, J.

    1993-11-01

    Results are presented of a systems failure analysis of the PIUS plant systems that are used during normal reactor operation and postulated accidents. This study was performed to provide the NRC with an understanding of the behavior of the plant. The study applied two diverse failure identification methods, Failure Modes Effects & Criticality Analysis (FMECA) and Hazards & Operability (HAZOP) to the plant systems, supported by several deterministic analyses. Conventional PRA methods were also used along with a scheme for classifying events by initiator frequency and combinations of failures. Principal results of this study are: (a) an extensive listing of potential event sequences, grouped in categories that can be used by the NRC, (b) identification of support systems that are important to safety, and (c) identification of key operator actions.

  7. Apparatus for solar coal gasification

    DOE Patents [OSTI]

    Gregg, D.W.

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

  8. Foundational development of an advanced nuclear reactor integrated safety code.

    SciTech Connect (OSTI)

    Clarno, Kevin; Lorber, Alfred Abraham; Pryor, Richard J.; Spotz, William F.; Schmidt, Rodney Cannon; Belcourt, Kenneth; Hooper, Russell Warren; Humphries, Larry LaRon

    2010-02-01

    This report describes the activities and results of a Sandia LDRD project whose objective was to develop and demonstrate foundational aspects of a next-generation nuclear reactor safety code that leverages advanced computational technology. The project scope was directed towards the systems-level modeling and simulation of an advanced, sodium cooled fast reactor, but the approach developed has a more general applicability. The major accomplishments of the LDRD are centered around the following two activities. (1) The development and testing of LIME, a Lightweight Integrating Multi-physics Environment for coupling codes that is designed to enable both 'legacy' and 'new' physics codes to be combined and strongly coupled using advanced nonlinear solution methods. (2) The development and initial demonstration of BRISC, a prototype next-generation nuclear reactor integrated safety code. BRISC leverages LIME to tightly couple the physics models in several different codes (written in a variety of languages) into one integrated package for simulating accident scenarios in a liquid sodium cooled 'burner' nuclear reactor. Other activities and accomplishments of the LDRD include (a) further development, application and demonstration of the 'non-linear elimination' strategy to enable physics codes that do not provide residuals to be incorporated into LIME, (b) significant extensions of the RIO CFD code capabilities, (c) complex 3D solid modeling and meshing of major fast reactor components and regions, and (d) an approach for multi-physics coupling across non-conformal mesh interfaces.

  9. GASIFICATION FOR DISTRIBUTED GENERATION

    SciTech Connect (OSTI)

    Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

    2000-05-01

    evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

  10. Integral Fast Reactor Program. Annual progress report, FY 1992

    SciTech Connect (OSTI)

    Chang, Y.I.; Walters, L.C.; Laidler, J.J.; Pedersen, D.R.; Wade, D.C.; Lineberry, M.J.

    1993-06-01

    This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1992. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R&D.

  11. Integral Fast Reactor Program annual progress report, FY 1991

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1991. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R D.

  12. Integral Fast Reactor Program annual progress report, FY 1991

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1991. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R&D.

  13. Integral Fast Reactor Program annual progress report, FY 1994

    SciTech Connect (OSTI)

    Chang, Y.I.; Walters, L.C.; Laidler, J.J.; Pedersen, D.R.; Wade, D.C.; Lineberry, J.J.

    1994-12-01

    This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1994. Technical accomplishments are presented in the following areas of the IFR technology development activities: metal fuel performance; pyroprocess development; safety experiments and analyses; core design development; fuel cycle demonstration; and LMR technology R&D.

  14. Integral Fast Reactor Program. Annual progress report, FY 1993

    SciTech Connect (OSTI)

    Chang, Y.I.; Walters, L.C.; Laidler, J.J.; Pedersen, D.R.; Wade, D.C.; Lineberry, M.J.

    1994-10-01

    This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1993. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R and D.

  15. Integrity of the reactor coolant boundary of the European pressurized water reactor (EPR)

    SciTech Connect (OSTI)

    Goetsch, D.; Bieniussa, K.; Schulz, H.; Jalouneix, J.

    1997-04-01

    This paper is an abstract of the work performed in the frame of the development of the IPSN/GRS approach in view of the EPR conceptual safety features. EPR is a pressurized water reactor which will be based on the experience gained by utilities and designers in France and in Germany. The reactor coolant boundary of a PWR includes the reactor pressure vessel (RPV), those parts of the steam generators (SGs) which contain primary coolant, the pressurizer (PSR), the reactor coolant pumps (RCPs), the main coolant lines (MCLs) with their branches as well as the other connecting pipes and all branching pipes including the second isolation valves. The present work covering the integrity of the reactor coolant boundary is mainly restricted to the integrity of the main coolant lines (MCLs) and reflects the design requirements for the main components of the reactor coolant boundary. In the following the conceptual aspects, i.e. design, manufacture, construction and operation, will be assessed. A main aspect is the definition of break postulates regarding overall safety implications.

  16. NETL: Coal Gasification Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gasification Systems Coal Gasification is a process that can turn coal into clean power, chemicals, hydrogen and transportation fuels, and can be used to capture the carbon from ...

  17. Space reactor electric systems: system integration studies, Phase 1 report

    SciTech Connect (OSTI)

    Anderson, R.V.; Bost, D.; Determan, W.R.; Harty, R.B.; Katz, B.; Keshishian, V.; Lillie, A.F.; Thomson, W.B.

    1983-03-29

    This report presents the results of preliminary space reactor electric system integration studies performed by Rockwell International's Energy Systems Group (ESG). The preliminary studies investigated a broad range of reactor electric system concepts for powers of 25 and 100 KWe. The purpose of the studies was to provide timely system information of suitable accuracy to support ongoing mission planning activities. The preliminary system studies were performed by assembling the five different subsystems that are used in a system: the reactor, the shielding, the primary heat transport, the power conversion-processing, and the heat rejection subsystems. The subsystem data in this report were largely based on Rockwell's recently prepared Subsystem Technology Assessment Report. Nine generic types of reactor subsystems were used in these system studies. Several levels of technology were used for each type of reactor subsystem. Seven generic types of power conversion-processing subsystems were used, and several levels of technology were again used for each type. In addition, various types and levels of technology were used for the shielding, primary heat transport, and heat rejection subsystems. A total of 60 systems were studied.

  18. Integrated Reactor and Centrifugal Separator - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Integrated Reactor and Centrifugal Separator Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryA more efficient reaction and separation process for reaction products was invented by ORNL researchers. This method is specifically applicable to the production of biodiesel through the esterification of organic oils and fats. DescriptionIn conventional biodiesel manufacturing,

  19. 2007 gasification technologies conference papers

    SciTech Connect (OSTI)

    2007-07-01

    Sessions covered: gasification industry roundtable; the gasification market in China; gasification for power generation; the gasification challenge: carbon capture and use storage; industrial and polygeneration applications; gasification advantage in refinery applications; addressing plant performance; reliability and availability; gasification's contribution to supplementing gaseous and liquid fuels supplies; biomass gasification for fuel and power markets; and advances in technology-research and development

  20. "Integrated Gasification Combined Cycle"

    U.S. Energy Information Administration (EIA) Indexed Site

    Turbine",,"X" " - Heat Recovery Steam Generator",,,"X" " - Gasifier",,"X" " - Balance of Plant",,,"X" "Conventional Natural Gas Combined Cycle" " - Conventional Combustion Turbine"...

  1. Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes

    SciTech Connect (OSTI)

    Lee O. Nelson

    2011-04-01

    This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540°C and the helium coolant was delivered at 7 MPa at 625–925°C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

  2. Actinide behavior in the Integral Fast Reactor. Final project report

    SciTech Connect (OSTI)

    Courtney, J.C.

    1994-11-01

    The Integral Fast Reactor (IFR) under development by Argonne National Laboratory uses metallic fuels instead of ceramics. This allows electrorefining of spent fuels and presents opportunities for recycling minor actinide elements. Four minor actinides ({sup 237}Np, {sup 240}Pu, {sup 241}Am, and {sup 243}Am) determine the waste storage requirements of spent fuel from all types of fission reactors. These nuclides behave the same as uranium and other plutonium isotopes in electrorefining, so they can be recycled back to the reactor without elaborate chemical processing. An experiment has been designed to demonstrate the effectiveness of the high-energy neutron spectra of the IFR in consuming these four nuclides and weapons grade plutonium. Eighteen sets of seven actinide and five light metal targets have been selected for seven day exposure in the Experimental Breeder Reactor-II which serves as a prototype of the IFR. Post-irradiation analyses of the exposed targets by gamma, alpha, and mass spectroscopy are used to determine nuclear reaction rates and neutron spectra. These experimental data increase the authors confidence in their ability to predict reaction rates in candidate IFR designs using a variety of neutron transport and diffusion programs.

  3. Method for increasing steam decomposition in a coal gasification process

    DOE Patents [OSTI]

    Wilson, Marvin W.

    1988-01-01

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  4. Method for increasing steam decomposition in a coal gasification process

    DOE Patents [OSTI]

    Wilson, M.W.

    1987-03-23

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  5. The shell coal gasification process

    SciTech Connect (OSTI)

    Koenders, L.O.M.; Zuideveld, P.O.

    1995-12-01

    Future Integrated Coal Gasification Combined Cycle (ICGCC) power plants will have superior environmental performance and efficiency. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an ICGCC plant. SCGP flexibility has been demonstrated for high-rank bituminous coals to low rank lignites and petroleum coke, and the process is well suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV), depending on choice of coal and gas turbine efficiency. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology has been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The construction of the unit was completed end 1993 and is now followed by start-up and a 3 year demonstration period, after that the plant will be part of the Dutch electricity generating system.

  6. Current Gasification Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    With coal gasification now in modern commercial-scale applications, the U.S. Department of Energy's (DOE) Office of Fossil Energy has turned its attention to future gasification concepts that offer...

  7. Gasification | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gasification Gasification The Wabash River Clean Coal Power Plant The Wabash River Clean Coal ... that could reduce NOx from hydrogen fired turbines to as low as 2 parts per million. ...

  8. 2010 Worldwide Gasification Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers.

  9. Novel, Integrated Reactor / Power Conversion System (LMR-AMTEC)

    SciTech Connect (OSTI)

    Pablo Rubiolo, Principal Investigator

    2003-03-21

    The main features of this project were the development of a long life (up to 10 years) Liquid Metal Reactor (LMR) and a static conversion subsystem comprising an Alkali Metal Thermal-to-Electric (AMTEC) topping cycle and a ThermoElectric (TE) Bottom cycle. Various coupling options of the LMR with the energy conversion subsystem were explored and, base in the performances found in this analysis, an Indirect Coupling (IC) between the LMR and the AMTEC/TE converters with Alkali Metal Boilers (AMB) was chosen as the reference design. The performance model of the fully integrated sodium-and potassium-AMTEC/TE converters shows that a combined conversion efficiency in excess of 30% could be achieved by the plant. (B204)

  10. Apparatus for solar coal gasification

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-04

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

  11. Integrated Sensing & Controls for Coal Gasification - Development of Model-Based Controls for GE's Gasifier & Syngas Cooler. Topical Rerport for Phase III

    SciTech Connect (OSTI)

    Kumar, Aditya

    2011-02-17

    This Topical Report for the final Phase III of the program summarizes the results from the Task 3 of the program. In this task, the separately designed extended Kalman Filter (EKF) and model predictive controls (MPC) with ideal sensing, developed in Phase II, were integrated to achieve the overall sensing and control system for the gasification section of an IGCC plant. The EKF and MPC algorithms were updated and re-tuned to achieve closed-loop system stability as well as good steady-state and transient control response. In particular, the performance of the integrated EKF and MPC solution was tested extensively through multiple simulation studies to achieve improved steady-state as well as transient performance, with coal as well as coal-petcoke blended fuel, in the presence of unknown modeling errors as well as sensor errors (noise and bias). The simulation studies demonstrated significant improvements in steady state and transient operation performance, similar to that achieved by MPC with ideal sensors in Phase II of the program.

  12. Apparatus and method for solar coal gasification

    DOE Patents [OSTI]

    Gregg, David W.

    1980-01-01

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

  13. Generation IV Reactors Integrated Materials Technology Program Plan: Focus on Very High Temperature Reactor Materials

    SciTech Connect (OSTI)

    Corwin, William R; Burchell, Timothy D; Katoh, Yutai; McGreevy, Timothy E; Nanstad, Randy K; Ren, Weiju; Snead, Lance Lewis; Wilson, Dane F

    2008-08-01

    : (a) Qualification of short-term, high-temperature properties of light water reactor steels for anticipated VHTR off-normal conditions must be determined, as well as the effects of aging on tensile, creep, and toughness properties, and on thermal emissivity. (b) Large-scale fabrication process for higher temperature alloys, such as 9Cr-1MoV, including ensuring thick-section and weldment integrity must be developed, as well as improved definitions of creep-fatigue and negligible creep behavior. (5) High-Temperature Alloys: (a) Qualification and codification of materials for the intermediate heat exchanger, such as Alloys 617 or 230, for long-term very high-temperature creep, creep-fatigue, and environmental aging degradation must be done, especially in thin sections for compact designs, for both base metal and weldments. (b) Constitutive models and an improved methodology for high-temperature design must be developed.

  14. Coal gasification players, projects, prospects

    SciTech Connect (OSTI)

    Blankinship, S.

    2006-07-15

    Integrated gasification combined cycle (IGCC) technology has been running refineries and chemical plants for decades. Power applications have dotted the globe. Two major IGCC demonstration plants operating in the United States since the mid-1900s have helped set the stage for prime time, which is now approaching. Two major reference plant designs are in the wings and at least two major US utilities are poised to build their own IGCC power plants. 2 figs.

  15. EIS-0428: Mississippi Gasification, LLC, Industrial Gasification Facility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Moss Point, MS | Department of Energy 8: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS EIS-0428: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS Documents Available for Download November 12, 2009 EIS-0428: Notice of Intent to Prepare an Environmental Impact Statement Construction and Startup of the Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, Mississippi December 1, 2009 EIS-0428:

  16. EIS-0429: Indiana Gasification, LLC, Industrial Gasification Facility in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rockport, IN and CO2 Pipeline | Department of Energy 9: Indiana Gasification, LLC, Industrial Gasification Facility in Rockport, IN and CO2 Pipeline EIS-0429: Indiana Gasification, LLC, Industrial Gasification Facility in Rockport, IN and CO2 Pipeline Documents Available for Download November 12, 2009 EIS-0429: Notice of Intent to Prepare an Environmental Impact Statement Construction and Startup of the Indiana Gasification, LLC, Industrial Gasification Facility in Rockport, Indiana December

  17. The United States of America and the People`s Republic of China experts report on integrated gasification combined-cycle technology (IGCC)

    SciTech Connect (OSTI)

    1996-12-01

    A report written by the leading US and Chinese experts in Integrated Gasification Combined Cycle (IGCC) power plants, intended for high level decision makers, may greatly accelerate the development of an IGCC demonstration project in the People`s Republic of China (PRC). The potential market for IGCC systems in China and the competitiveness of IGCC technology with other clean coal options for China have been analyzed in the report. Such information will be useful not only to the Chinese government but also to US vendors and companies. The goal of this report is to analyze the energy supply structure of China, China`s energy and environmental protection demand, and the potential market in China in order to make a justified and reasonable assessment on feasibility of the transfer of US Clean Coal Technologies to China. The Expert Report was developed and written by the joint US/PRC IGCC experts and will be presented to the State Planning Commission (SPC) by the President of the CAS to ensure consideration of the importance of IGCC for future PRC power production.

  18. Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill

    SciTech Connect (OSTI)

    Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

    2010-01-27

    As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry’s energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also

  19. Gasification Systems Portfolio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015 Gasification Systems Project Portfolio Gasification is a clean way to efficiently produce electric power, a wide range of transportation fuels, and chemicals from coal and other solid feedstocks. By first converting the solid feedstock to a gaseous form (syngas), potential pollutants can be captured and reduced to any desired level and then converted to useful by-products or safely disposed. The Gasification Systems Program is developing advanced technologies to improve the economics and

  20. Gasification of Biorefinery Residues

    SciTech Connect (OSTI)

    2006-04-01

    This project is addressing syngas clean-up by developing a better understanding of the chemical mechanisms and kinetics of trace product formation in biomass gasification.

  1. Gasification Systems Project Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Syngas Chemical Looping for Hydrogen Production Ohio State University Research Foundation Gasification Systems FE0024068 Increasing the Rate and Extent of Microbial Coal to ...

  2. Gasification-based biomass

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    The gasification-based biomass section of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  3. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2000-09-01

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  4. Gasification: A Cornerstone Technology

    SciTech Connect (OSTI)

    Gary Stiegel

    2008-03-26

    NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

  5. Gasification: A Cornerstone Technology

    ScienceCinema (OSTI)

    Gary Stiegel

    2010-01-08

    NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

  6. The Ongoing Impact of the U.S. Fast Reactor Integral Experiments Program

    SciTech Connect (OSTI)

    John D. Bess; Michael A. Pope; Harold F. McFarlane

    2012-11-01

    The creation of a large database of integral fast reactor physics experiments advanced nuclear science and technology in ways that were unachievable by less capital intensive and operationally challenging approaches. They enabled the compilation of integral physics benchmark data, validated (or not) analytical methods, and provided assurance of future rector designs The integral experiments performed at Argonne National Laboratory (ANL) represent decades of research performed to support fast reactor design and our understanding of neutronics behavior and reactor physics measurements. Experiments began in 1955 with the Zero Power Reactor No. 3 (ZPR-3) and terminated with the Zero Power Physics Reactor (ZPPR, originally the Zero Power Plutonium Reactor) in 1990 at the former ANL-West site in Idaho, which is now part of the Idaho National Laboratory (INL). Two additional critical assemblies, ZPR-6 and ZPR-9, operated at the ANL-East site in Illinois. A total of 128 fast reactor assemblies were constructed with these facilities [1]. The infrastructure and measurement capabilities are too expensive to be replicated in the modern era, making the integral database invaluable as the world pushes ahead with development of liquid metal cooled reactors.

  7. 2006 gasification technologies conference papers

    SciTech Connect (OSTI)

    2006-07-01

    Sessions covered: business overview, industry trends and new developments; gasification projects progress reports; industrial applications and opportunities; Canadian oil sands; China/Asia gasification markets - status and projects; carbon management with gasification technologies; gasification economics and performance issues addressed; and research and development, and new technologies initiatives.

  8. Improving process performances in coal gasification for power and synfuel production

    SciTech Connect (OSTI)

    M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana

    2008-11-15

    This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

  9. EMERY BIOMASS GASIFICATION POWER SYSTEM

    SciTech Connect (OSTI)

    Benjamin Phillips; Scott Hassett; Harry Gatley

    2002-11-27

    Emery Recycling Corporation (now Emery Energy Company, LLC) evaluated the technical and economical feasibility of the Emery Biomass Gasification Power System (EBGPS). The gasifier technology is owned and being developed by Emery. The Emery Gasifier for this project was an oxygen-blown, pressurized, non-slagging gasification process that novelly integrates both fixed-bed and entrained-flow gasification processes into a single vessel. This unique internal geometry of the gasifier vessel will allow for tar and oil destruction within the gasifier. Additionally, the use of novel syngas cleaning processes using sorbents is proposed with the potential to displace traditional amine-based and other syngas cleaning processes. The work scope within this project included: one-dimensional gasifier modeling, overall plant process modeling (ASPEN), feedstock assessment, additional analyses on the proposed syngas cleaning process, plant cost estimating, and, market analysis to determine overall feasibility and applicability of the technology for further development and commercial deployment opportunities. Additionally, the project included the development of a detailed technology development roadmap necessary to commercialize the Emery Gasification technology. Process modeling was used to evaluate both combined cycle and solid oxide fuel cell power configurations. Ten (10) cases were evaluated in an ASPEN model wherein nine (9) cases were IGCC configurations with fuel-to-electricity efficiencies ranging from 38-42% and one (1) case was an IGFC solid oxide case where 53.5% overall plant efficiency was projected. The cost of electricity was determined to be very competitive at scales from 35-71 MWe. Market analysis of feedstock availability showed numerous market opportunities for commercial deployment of the technology with modular capabilities for various plant sizes based on feedstock availability and power demand.

  10. Dynamic simulation and load-following control of an integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture

    SciTech Connect (OSTI)

    Bhattacharyya, D,; Turton, R.; Zitney, S.

    2012-01-01

    Load-following control of future integrated gasification combined cycle (IGCC) plants with pre-combustion CO{sub 2} capture is expected to be far more challenging as electricity produced by renewable energy is connected to the grid and strict environmental limits become mandatory requirements. To study control performance during load following, a plant-wide dynamic simulation of a coal-fed IGCC plant with CO{sub 2} capture has been developed. The slurry-fed gasifier is a single-stage, downward-fired, oxygen-blown, entrained-flow type with a radiant syngas cooler (RSC). The syngas from the outlet of the RSC goes to a scrubber followed by a two-stage sour shift process with inter-stage cooling. The acid gas removal (AGR) process is a dual-stage physical solvent-based process for selective removal of H{sub 2}S in the first stage and CO{sub 2} in the second stage. Sulfur is recovered using a Claus unit with tail gas recycle to the AGR. The recovered CO{sub 2} is compressed by a split-shaft multistage compressor and sent for sequestration after being treated in an absorber with triethylene glycol for dehydration. The clean syngas is sent to two advanced “F”-class gas turbines (GTs) partially integrated with an elevated-pressure air separation unit. A subcritical steam cycle is used for heat recovery steam generation. A treatment unit for the sour water strips off the acid gases for utilization in the Claus unit. The steady-state model developed in Aspen Plus® is converted to an Aspen Plus Dynamics® simulation and integrated with MATLAB® for control studies. The results from the plant-wide dynamic model are compared qualitatively with the data from a commercial plant having different configuration, operating condition, and feed quality than what has been considered in this work. For load-following control, the GT-lead with gasifier-follow control strategy is considered. A modified proportional–integral–derivative (PID) control is considered for the syngas

  11. JV Task 46 - Development and Testing of a Thermally Integrated SOFC-Gasification System for Biomass Power Generation

    SciTech Connect (OSTI)

    Phillip Hutton; Nikhil Patel; Kyle Martin; Devinder Singh

    2008-02-01

    The Energy & Environmental Research Center has designed a biomass power system using a solid oxide fuel cell (SOFC) thermally integrated with a downdraft gasifier. In this system, the high-temperature effluent from the SOFC enables the operation of a substoichiometric air downdraft gasifier at an elevated temperature (1000 C). At this temperature, moisture in the biomass acts as an essential carbon-gasifying medium, reducing the equivalence ratio at which the gasifier can operate with complete carbon conversion. Calculations show gross conversion efficiencies up to 45% (higher heating value) for biomass moisture levels up to 40% (wt basis). Experimental work on a bench-scale gasifier demonstrated increased tar cracking within the gasifier and increased energy density of the resultant syngas. A series of experiments on wood chips demonstrated tar output in the range of 9.9 and 234 mg/m{sup 3}. Both button cells and a 100-watt stack was tested on syngas from the gasifier. Both achieved steady-state operation with a 22% and 15% drop in performance, respectively, relative to pure hydrogen. In addition, tar tolerance testing on button cells demonstrated an upper limit of tar tolerance of approximately 1%, well above the tar output of the gasifier. The predicted system efficiency was revised down to 33% gross and 27% net system efficiency because of the results of the gasifier and fuel cell experiments. These results demonstrate the feasibility and benefits of thermally integrating a gasifier and a high-temperature fuel cell in small distributed power systems.

  12. Multi-Purpose Thermal Hydraulic Loop: Advanced Reactor Technology Integral System Test (ARTIST) Facility for Support of Advanced Reactor Technologies

    SciTech Connect (OSTI)

    James E. O'Brien; Piyush Sabharwall; SuJong Yoon

    2001-11-01

    Effective and robust high temperature heat transfer systems are fundamental to the successful deployment of advanced reactors for both power generation and non-electric applications. Plant designs often include an intermediate heat transfer loop (IHTL) with heat exchangers at either end to deliver thermal energy to the application while providing isolation of the primary reactor system. In order to address technical feasibility concerns and challenges a new high-temperature multi-fluid, multi-loop test facility “Advanced Reactor Technology Integral System Test facility” (ARTIST) is under development at the Idaho National Laboratory. The facility will include three flow loops: high-temperature helium, molten salt, and steam/water. Details of some of the design aspects and challenges of this facility, which is currently in the conceptual design phase, are discussed

  13. An integrated approach for the verification of fresh mixed oxide fuel (MOX) assemblies at light water reactor MOX recycle reactors

    SciTech Connect (OSTI)

    Menlove, Howard O; Lee, Sang - Yoon

    2009-01-01

    This paper presents an integrated approach for the verification of mixed oxide (MOX) fuel assemblies prior to their being loaded into the reactor. There is a coupling of the verification approach that starts at the fuel fabrication plant and stops with the transfer of the assemblies into the thermal reactor. The key measurement points are at the output of the fuel fabrication plant, the receipt at the reactor site, and the storage in the water pool as fresh fuel. The IAEA currently has the capability to measure the MOX fuel assemblies at the output of the fuel fabrication plants using a passive neutron coincidence counting systems of the passive neutron collar (PNCL) type. Also. at the MOX reactor pool, the underwater coincidence counter (UWCC) has been developed to measure the MOX assemblies in the water. The UWCC measurement requires that the fuel assembly be lifted about two meters up in the storage rack to avoid interference from the fuel that is stored in the rack. This paper presents a new method to verify the MOX fuel assemblies that are in the storage rack without the necessity of moving the fuel. The detector system is called the Underwater MOX Verification System (UMVS). The integration and relationship of the three measurements systems is described.

  14. Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications

    SciTech Connect (OSTI)

    Lee Nelson

    2011-09-01

    This report is a summary of analyses performed by the NGNP project to determine whether it is technically and economically feasible to integrate high temperature gas cooled reactor (HTGR) technology into industrial processes. To avoid an overly optimistic environmental and economic baseline for comparing nuclear integrated and conventional processes, a conservative approach was used for the assumptions and calculations.

  15. Integrated process of distillation with side reactors for synthesis of organic acid esters

    DOE Patents [OSTI]

    Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri; Miller, Dennis J; Lira, Carl T

    2015-11-04

    An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

  16. Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass Feed and Gasification The Biomass Feed and Gasification Key Technology will advance scientific knowledge of the feeding and conversion of biomass and coal-biomass mixtures as essential upstream steps for production of liquid transportation fuels with a lower net GHG emissions than conventional oil refining. Activities support research for handling and processing of coal-biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on

  17. Coal gasification. Quarterly report, January-March 1979. [US DOE supported

    SciTech Connect (OSTI)

    1980-01-01

    Progress in DOE-supported coal gasification pilot plant projects is reported: company, location, contract number, funding, process description, history and progress in the current quarter. Two support projects are discussed: preparation of a technical data book and mathematical modeling of gasification reactors. (LTN)

  18. Coal gasification for power generation. 2nd ed.

    SciTech Connect (OSTI)

    2006-10-15

    The report gives an overview of the opportunities for coal gasification in the power generation industry. It provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered in the report include: An overview of coal generation including its history, the current market environment, and the status of coal gasification; A description of gasification technology including processes and systems; An analysis of the key business factors that are driving increased interest in coal gasification; An analysis of the barriers that are hindering the implementation of coal gasification projects; A discussion of Integrated Gasification Combined Cycle (IGCC) technology; An evaluation of IGCC versus other generation technologies; A discussion of IGCC project development options; A discussion of the key government initiatives supporting IGCC development; Profiles of the key gasification technology companies participating in the IGCC market; and A description of existing and planned coal IGCC projects.

  19. Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture

    SciTech Connect (OSTI)

    Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01

    Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics® (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel

  20. INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING

    SciTech Connect (OSTI)

    Eric P. Robertson; Michael G. McKellar; Lee O. Nelson

    2011-05-01

    This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

  1. METHOD OF MEASURING THE INTEGRATED ENERGY OUTPUT OF A NEUTRONIC CHAIN REACTOR

    DOE Patents [OSTI]

    Sturm, W.J.

    1958-12-01

    A method is presented for measuring the integrated energy output of a reactor conslsting of the steps of successively irradiating calibrated thin foils of an element, such as gold, which is rendered radioactive by exposure to neutron flux for periods of time not greater than one-fifth the mean life of the induced radioactlvity and producing an indication of the radioactivity induced in each foil, each foil belng introduced into the reactor immediately upon removal of its predecessor.

  2. Underground coal gasification: a brief review of current status

    SciTech Connect (OSTI)

    Shafirovich, E.; Varma, A.

    2009-09-15

    Coal gasification is a promising option for the future use of coal. Similarly to gasification in industrial reactors, underground coal gasification (UCG) produces syngas, which can be used for power generation or for the production of liquid hydrocarbon fuels and other valuable chemical products. As compared with conventional mining and surface gasification, UCG promises lower capital/operating costs and also has other advantages, such as no human labor underground. In addition, UCG has the potential to be linked with carbon capture and sequestration. The increasing demand for energy, depletion of oil and gas resources, and threat of global climate change lead to growing interest in UCG throughout the world. In this article, we review the current status of this technology, focusing on recent developments in various countries.

  3. Light Water Reactor Sustainability Program Integrated Program Plan

    SciTech Connect (OSTI)

    McCarthy, Kathryn A.; Busby, Jeremy; Hallbert, Bruce; Bragg-Sitton, Shannon; Smith, Curtis; Barnard, Cathy

    2014-04-01

    Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline—even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy’s Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration’s energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans.

  4. Light Water Reactor Sustainability Program Integrated Program Plan

    SciTech Connect (OSTI)

    Kathryn McCarthy; Jeremy Busby; Bruce Hallbert; Shannon Bragg-Sitton; Curtis Smith; Cathy Barnard

    2013-04-01

    Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline—even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy’s Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration’s energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans.

  5. Light Water Reactor Sustainability Program Integrated Program Plan

    SciTech Connect (OSTI)

    George Griffith; Robert Youngblood; Jeremy Busby; Bruce Hallbert; Cathy Barnard; Kathryn McCarthy

    2012-01-01

    Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline - even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy's Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration's energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program's plans.

  6. Underground Coal Gasification Program

    Energy Science and Technology Software Center (OSTI)

    1994-12-01

    CAVSIM is a three-dimensional, axisymmetric model for resource recovery and cavity growth during underground coal gasification (UCG). CAVSIM is capable of following the evolution of the cavity from near startup to exhaustion, and couples explicitly wall and roof surface growth to material and energy balances in the underlying rubble zones. Growth mechanisms are allowed to change smoothly as the system evolves from a small, relatively empty cavity low in the coal seam to a large,more » almost completely rubble-filled cavity extending high into the overburden rock. The model is applicable to nonswelling coals of arbitrary seam thickness and can handle a variety of gas injection flow schedules or compositions. Water influx from the coal aquifer is calculated by a gravity drainage-permeation submodel which is integrated into the general solution. The cavity is considered to consist of up to three distinct rubble zones and a void space at the top. Resistance to gas flow injected from a stationary source at the cavity floor is assumed to be concentrated in the ash pile, which builds up around the source, and also the overburden rubble which accumulates on top of this ash once overburden rock is exposed at the cavity top. Char rubble zones at the cavity side and edges are assumed to be highly permeable. Flow of injected gas through the ash to char rubble piles and the void space is coupled by material and energy balances to cavity growth at the rubble/coal, void/coal and void/rock interfaces. One preprocessor and two postprocessor programs are included - SPALL calculates one-dimensional mean spalling rates of coal or rock surfaces exposed to high temperatures and generates CAVSIM input: TAB reads CAVSIM binary output files and generates ASCII tables of selected data for display; and PLOT produces dot matrix printer or HP printer plots from TAB output.« less

  7. Integrated Decision-Making Tool to Develop Spent Fuel Strategies for Research Reactors

    SciTech Connect (OSTI)

    Beatty, Randy L; Harrison, Thomas J

    2016-01-01

    IAEA Member States operating or having previously operated a Research Reactor are responsible for the safe and sustainable management and disposal of associated radioactive waste, including research reactor spent nuclear fuel (RRSNF). This includes the safe disposal of RRSNF or the corresponding equivalent waste returned after spent fuel reprocessing. One key challenge to developing general recommendations lies in the diversity of spent fuel types, locations and national/regional circumstances rather than mass or volume alone. This is especially true given that RRSNF inventories are relatively small, and research reactors are rarely operated at a high power level or duration typical of commercial power plants. Presently, many countries lack an effective long-term policy for managing RRSNF. This paper presents results of the International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) #T33001 on Options and Technologies for Managing the Back End of the Research Reactor Nuclear Fuel Cycle which includes an Integrated Decision Making Tool called BRIDE (Back-end Research reactor Integrated Decision Evaluation). This is a multi-attribute decision-making tool that combines the Total Estimated Cost of each life-cycle scenario with Non-economic factors such as public acceptance, technical maturity etc and ranks optional back-end scenarios specific to member states situations in order to develop a specific member state strategic plan with a preferred or recommended option for managing spent fuel from Research Reactors.

  8. Underground coal gasification. Presentations

    SciTech Connect (OSTI)

    2007-07-01

    The 8 presentations are: underground coal gasification (UCG) and the possibilities for carbon management (J. Friedmann); comparing the economics of UCG with surface gasification technologies (E. Redman); Eskom develops UCG technology project (C. Gross); development and future of UCG in the Asian region (L. Walker); economically developing vast deep Powder River Basin coals with UCG (S. Morzenti); effectively managing UCG environmental issues (E. Burton); demonstrating modelling complexity of environmental risk management; and UCG research at the University of Queensland, Australia (A.Y. Klimenko).

  9. Parametric Gasification of Oak and Pine Feedstocks Using the TCPDU and Slipstream Water-Gas Shift Catalysis

    SciTech Connect (OSTI)

    Hrdlicka, J.; Feik, C.; Carpenter, D.; Pomeroy, M.

    2008-12-01

    With oak and pine feedstocks, the Gasification of Biomass to Hydrogen project maximizes hydrogen production using the Full Stream Reformer during water-gas shift fixed-bed reactor testing. Results indicate that higher steam-to-biomass ratio and higher thermal cracker temperature yield higher hydrogen concentration. NREL's techno-economic models and analyses indicate hydrogen production from biomass may be viable at an estimated cost of $1.77/kg (current) and $1.47/kg (advanced in 2015). To verify these estimates, NREL used the Thermochemical Process Development Unit (TCPDU), an integrated system of unit operations that investigates biomass thermochemical conversion to gaseous and liquid fuels and chemicals.

  10. Gasification Systems Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gasification Systems Publications Table of Contents National Carbon Capture Center at the Power Systems Development Facility Reports Patents Program Presentations Solicitations Technical Presentations & Papers New program direction concepts are described in a 3-pager Radically Engineered Modular Systems Presentation 2013 Program Plan Technology Readiness Assessment (Comprehensive Report | Overview Report) Video, Images & Photos Closely Aligned Carbon Capture & Storage and Power

  11. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, Arthur L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  12. Variable capacity gasification burner

    SciTech Connect (OSTI)

    Saxon, D.I.

    1985-03-05

    A variable capacity burner that may be used in gasification processes, the burner being adjustable when operating in its intended operating environment to operate at two different flow capacities, with the adjustable parts being dynamically sealed within a statically sealed structural arrangement to prevent dangerous blow-outs of the reactants to the atmosphere.

  13. Pressurized Combustion and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressurized Combustion and Gasification - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management

  14. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, A.L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  15. The role of actinide burning and the Integral Fast Reactor in the future of nuclear power

    SciTech Connect (OSTI)

    Hollaway, W.R.; Lidsky, L.M.; Miller, M.M.

    1990-12-01

    A preliminary assessment is made of the potential role of actinide burning and the Integral Fast Reactor (IFR) in the future of nuclear power. The development of a usable actinide burning strategy could be an important factor in the acceptance and implementation of a next generation of nuclear power. First, the need for nuclear generating capacity is established through the analysis of energy and electricity demand forecasting models which cover the spectrum of bias from anti-nuclear to pro-nuclear. The analyses take into account the issues of global warming and the potential for technological advances in energy efficiency. We conclude, as do many others, that there will almost certainly be a need for substantial nuclear power capacity in the 2000--2030 time frame. We point out also that any reprocessing scheme will open up proliferation-related questions which can only be assessed in very specific contexts. The focus of this report is on the fuel cycle impacts of actinide burning. Scenarios are developed for the deployment of future nuclear generating capacity which exploit the advantages of actinide partitioning and actinide burning. Three alternative reactor designs are utilized in these future scenarios: The Light Water Reactor (LWR); the Modular Gas-Cooled Reactor (MGR); and the Integral Fast Reactor (FR). Each of these alternative reactor designs is described in some detail, with specific emphasis on their spent fuel streams and the back-end of the nuclear fuel cycle. Four separation and partitioning processes are utilized in building the future nuclear power scenarios: Thermal reactor spent fuel preprocessing to reduce the ceramic oxide spent fuel to metallic form, the conventional PUREX process, the TRUEX process, and pyrometallurgical reprocessing.

  16. Fuel Flexibility in Gasification

    SciTech Connect (OSTI)

    McLendon, T. Robert; Pineault, Richard L.; Richardson, Steven W.; Rockey, John M.; Beer, Stephen K.; Lui, Alain P.; Batton, William A.

    2001-11-06

    coal to percent by weight sawdust. The mixtures of interest were: 65/35 subbituminous, 75/25 subbituminous, 85/15 subbituminous, and 75/25 bituminous. Steady state was achieved quickly when going from one subbituminous mixture to another, but longer when going from subbituminous to bituminous coal. The most apparent observation when comparing the base case to subbituminous coal/sawdust mixtures is that operating conditions are nearly the same. Product gas does not change much in composition and temperatures remain nearly the same. Comparisons of identical weight ratios of sawdust and subbituminous and bituminous mixtures show considerable changes in operating conditions and gas composition. The highly caking bituminous coal used in this test swelled up and became about half as dense as the comparable subbituminous coal char. Some adjustments were required in accommodating changes in solids removal during the test. Nearly all the solids in the bituminous coal sawdust were conveyed into the upper freeboard section and removed at the mid-level of the reactor. This is in marked contrast to the ash-agglomerating condition where most solids are removed at the very bottom of the gasifier. Temperatures in the bottom of the reactor during the bituminous test were very high and difficult to control. The most significant discovery of the tests was that the addition of sawdust allowed gasification of a coal type that had previously resulted in nearly instant clinkering of the gasifier. Several previous attempts at using Pittsburgh No. 8 were done only at the end of the tests when shutdown was imminent anyway. It is speculated that the fine wood dust somehow coats the pyrolyzed sticky bituminous coal particles and prevents them from agglomerating quickly. As the bituminous coal char particles swell, they are carried to the cooler upper regions of the reactor where they re-solidify. Other interesting phenomena were revealed regarding the transport (rheological) properties of the

  17. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect (OSTI)

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  18. Dynamic Complexity Study of Nuclear Reactor and Process Heat Application Integration

    SciTech Connect (OSTI)

    J'Tia Patrice Taylor; David E. Shropshire

    2009-09-01

    Abstract This paper describes the key obstacles and challenges facing the integration of nuclear reactors with process heat applications as they relate to dynamic issues. The paper also presents capabilities of current modeling and analysis tools available to investigate these issues. A pragmatic approach to an analysis is developed with the ultimate objective of improving the viability of nuclear energy as a heat source for process industries. The extension of nuclear energy to process heat industries would improve energy security and aid in reduction of carbon emissions by reducing demands for foreign derived fossil fuels. The paper begins with an overview of nuclear reactors and process application for potential use in an integrated system. Reactors are evaluated against specific characteristics that determine their compatibility with process applications such as heat outlet temperature. The reactor system categories include light water, heavy water, small to medium, near term high-temperature, and far term high temperature reactors. Low temperature process systems include desalination, district heating, and tar sands and shale oil recovery. High temperature processes that support hydrogen production include steam reforming, steam cracking, hydrogen production by electrolysis, and far-term applications such as the sulfur iodine chemical process and high-temperature electrolysis. A simple static matching between complementary systems is performed; however, to gain a true appreciation for system integration complexity, time dependent dynamic analysis is required. The paper identifies critical issues arising from dynamic complexity associated with integration of systems. Operational issues include scheduling conflicts and resource allocation for heat and electricity. Additionally, economic and safety considerations that could impact the successful integration of these systems are considered. Economic issues include the cost differential arising due to an integrated

  19. Coal gasification power plant and process

    DOE Patents [OSTI]

    Woodmansee, Donald E.

    1979-01-01

    In an integrated coal gasification power plant, a humidifier is provided for transferring as vapor, from the aqueous blowdown liquid into relatively dry air, both (I) at least a portion of the water contained in the aqueous liquid and (II) at least a portion of the volatile hydrocarbons therein. The resulting humidified air is advantageously employed as at least a portion of the hot air and water vapor included in the blast gas supplied via a boost compressor to the gasifier.

  20. Evaluation of integral continuing experimental capability (CEC) concepts for light water reactor research: PWR scaling concepts

    SciTech Connect (OSTI)

    Condie, K G; Larson, T K; Davis, C B; McCreery, G E

    1987-02-01

    In this report reactor transients and thermal-hydraulic phenomena of importance (based on probabilistic risk assessment and the International Code Assessment Program) to reactor safety were examined and identified. Established scaling methodologies were used to develop potential concepts for integral thermal-hydraulic testing facilities. Advantages and disadvantages of each concept are evaluated. Analysis is conducted to examine the scaling of various phenomena in each of the selected concepts. Results generally suggest that a facility capable of operating at typical reactor operating conditions will scale most phenomena reasonably well. Although many phenomena in facilities using Freon or water at nontypical pressure will scale reasonably well, those phenomena that are heavily dependent on quality (heat transfer or critical flow for example) can be distorted. Furthermore, relation of data produced in facilities operating with nontypical fluids or at nontypical pressures to large plants will be a difficult and time consuming process.

  1. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 3 (April 2016) Archived Editions: Coal ...

  2. Gasification Plant Databases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plant Databases Welcome to the U. S. Department of Energy, National Energy Technology Laboratory's Gasification Plant Databases Within these databases you will find current publicly available information on proposed projects and projects undergoing construction and initial operation within the United States and worldwide. Currently operating projects are excluded. The data have been compiled here to keep the public informed of the technologies and investments in major industrial coal

  3. Applicability of GALE-86 Codes to Integral Pressurized Water Reactor designs

    SciTech Connect (OSTI)

    Geelhood, Kenneth J.; Rishel, Jeremy P.

    2012-06-01

    This report describes work that Pacific Northwest National Laboratory is doing to assist the U.S. Nuclear Regulatory Commission (NRC) Office of New Reactors (NRO) staff in their reviews of applications for nuclear power plants using new reactor core designs. These designs include small integral PWRs (IRIS, mPower, and NuScale reactor designs), HTGRs, (pebble-bed and prismatic-block modular reactor designs) and SFRs (4S and PRISM reactor designs). Under this specific task, PNNL will assist the NRC staff in reviewing the current versions of the GALE codes and identify features and limitations that would need to be modified to accommodate the technical review of iPWR and mPower® license applications and recommend specific changes to the code, NUREG-0017, and associated NRC guidance. This contract is necessary to support the licensing of iPWRs with a near-term focus on the B&W mPower® reactor design. While the focus of this review is on the mPower® reactor design, the review of the code and the scope of recommended changes consider a revision of the GALE codes that would make them universally applicable for other types of integral PWR designs. The results of a detailed comparison between PWR and iPWR designs are reported here. Also included is an investigation of the GALE code and its basis and a determination as to the applicability of each of the bases to an iPWR design. The issues investigated come from a list provided by NRC staff, the results of comparing the PWR and iPWR designs, the parameters identified as having a large impact on the code outputs from a recent sensitivity study and the main bases identified in NUREG-0017. This report will provide a summary of the gaps in the GALE codes as they relate to iPWR designs and for each gap will propose what work could be performed to fill that gap and create a version of GALE that is applicable to integral PWR designs.

  4. Gasification Plant Cost and Performance Optimization

    SciTech Connect (OSTI)

    Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

    2005-05-01

    facility based on the Subtask 3.2 design. The air-blown case was chosen since it was less costly and had a better return on investment than the oxygen-blown gasifier case. Under appropriate conditions, this study showed a combined heat and power air-blown gasification facility could be an attractive option for upgrading or expanding the utilities area of industrial facilities. Subtask 3.4 developed a base case design for a large lignite-fueled IGCC power plant that uses the advanced GE 7FB combustion turbine to be located at a generic North Dakota site. This plant uses low-level waste heat to dry the lignite that otherwise would be rejected to the atmosphere. Although this base case plant design is economically attractive, further enhancements should be investigated. Furthermore, since this is an oxygen-blown facility, it has the potential for capture and sequestration of CO{sub 2}. The third objective for Task 3 was accomplished by having NETL personnel working closely with Nexant and Gas Technology Institute personnel during execution of this project. Technology development will be the key to the long-term commercialization of gasification technologies. This will be important to the integration of this environmentally superior solid fuel technology into the existing mix of power plants and industrial facilities. As a result of this study, several areas have been identified in which research and development will further advance gasification technology. Such areas include improved system availability, development of warm-gas clean up technologies, and improved subsystem designs.

  5. REACTOR

    DOE Patents [OSTI]

    Szilard, L.

    1963-09-10

    A breeder reactor is described, including a mass of fissionable material that is less than critical with respect to unmoderated neutrons and greater than critical with respect to neutrons of average energies substantially greater than thermal, a coolant selected from sodium or sodium--potassium alloys, a control liquid selected from lead or lead--bismuth alloys, and means for varying the quantity of control liquid in the reactor. (AEC)

  6. REACTOR

    DOE Patents [OSTI]

    Christy, R.F.

    1961-07-25

    A means is described for co-relating the essential physical requirements of a fission chain reaction in order that practical, compact, and easily controllable reactors can be built. These objects are obtained by employing a composition of fissionsble isotope and moderator in fluid form in which the amount of fissionsble isotcpe present governs the reaction. The size of the reactor is no longer a critical factor, the new criterion being the concentration of the fissionable isotope.

  7. Development of Regulatory Technical Requirements for the Advanced Integral Type Research Reactor

    SciTech Connect (OSTI)

    Jo, Jong Chull; Yune, Young Gill; Kim, Woong Sik; Kim, Hho Jung

    2004-07-01

    This paper presents the current status of the study on the development of regulatory technical requirements for the licensing review of an advanced integral type research reactor of which the license application is expected in a few years. According to the Atomic Energy Act of Korea, both research and education reactors are subject to the technical requirements for power reactors in the licensing review. But, some of the requirements may not be applicable or insufficient for the licensing reviews of reactors with unique design features. Thus it is necessary to identify which review topics or areas can not be addressed by the existing requirements and to develop the required ones newly or supplement appropriately. Through the study performed so far, it has been identified that the following requirements need to be developed newly for the licensing review of SMART-P: the use of proven technology, the interfacial facility, the non-safety systems, and the metallic fuels. The approach and basis for the development of each of the requirements are discussed. (authors)

  8. Synthesis Gas Production by Rapid Solar Thermal Gasification of Corn Stover

    SciTech Connect (OSTI)

    Perkins, C. M.; Woodruff, B.; Andrews, L.; Lichty, P.; Lancaster, B.; Weimer, A. W.; Bingham, C.

    2008-03-01

    Biomass resources hold great promise as renewable fuel sources for the future, and there exists great interest in thermochemical methods of converting these resources into useful fuels. The novel approach taken by the authors uses concentrated solar energy to efficiently achieve temperatures where conversion and selectivity of gasification are high. Use of solar energy removes the need for a combustion fuel and upgrades the heating value of the biomass products. The syngas product of the gasification can be transformed into a variety of fuels useable with today?s infrastructure. Gasification in an aerosol reactor allows for rapid kinetics, allowing efficient utilization of the incident solar radiation and high solar efficiency.

  9. PNNL Coal Gasification Research

    SciTech Connect (OSTI)

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  10. Underground gasification of coal

    DOE Patents [OSTI]

    Pasini, III, Joseph; Overbey, Jr., William K.; Komar, Charles A.

    1976-01-20

    There is disclosed a method for the gasification of coal in situ which comprises drilling at least one well or borehole from the earth's surface so that the well or borehole enters the coalbed or seam horizontally and intersects the coalbed in a direction normal to its major natural fracture system, initiating burning of the coal with the introduction of a combustion-supporting gas such as air to convert the coal in situ to a heating gas of relatively high calorific value and recovering the gas. In a further embodiment the recovered gas may be used to drive one or more generators for the production of electricity.

  11. REACTOR

    DOE Patents [OSTI]

    Roman, W.G.

    1961-06-27

    A pressurized water reactor in which automatic control is achieved by varying the average density of the liquid moderator-cooiant is patented. Density is controlled by the temperature and power level of the reactor ftself. This control can be effected by the use of either plate, pellet, or tubular fuel elements. The fuel elements are disposed between upper and lower coolant plenum chambers and are designed to permit unrestricted coolant flow. The control chamber has an inlet opening communicating with the lower coolant plenum chamber and a restricted vapor vent communicating with the upper coolant plenum chamber. Thus, a variation in temperature of the fuel elements will cause a variation in the average moderator density in the chamber which directly affects the power level of the reactor.

  12. REACTORS

    DOE Patents [OSTI]

    Spitzer, L. Jr.

    1961-10-01

    Thermonuclear reactors, methods, and apparatus are described for controlling and confining high temperature plasma. Main axial confining coils in combination with helical windings provide a rotational transform that avoids the necessity of a figure-eight shaped reactor tube. The helical windings provide a multipolar helical magnetic field transverse to the axis of the main axial confining coils so as to improve the effectiveness of the confining field by counteracting the tendency of the more central lines of force in the stellarator tube to exchange positions with the magnetic lines of force nearer the walls of the tube. (AEC)

  13. Testing of an advanced thermochemical conversion reactor system

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This report presents the results of work conducted by MTCI to verify and confirm experimentally the ability of the MTCI gasification process to effectively generate a high-quality, medium-Btu gas from a wider variety of feedstock and waste than that attainable in air-blown, direct gasification systems. The system's overall simplicity, due to the compact nature of the pulse combustor, and the high heat transfer rates attainable within the pulsating flow resonance tubes, provide a decided and near-term potential economic advantage for the MTCI indirect gasification system. The primary objective of this project was the design, construction, and testing of a Process Design Verification System for an indirectly heated, thermochemical fluid-bed reactor and a pulse combustor an an integrated system that can process alternative renewable sources of energy such as biomass, black liquor, municipal solid waste and waste hydrocarbons, including heavy oils into a useful product gas. The test objectives for the biomass portion of this program were to establish definitive performance data on biomass feedstocks covering a wide range of feedstock qualities and characteristics. The test objectives for the black liquor portion of this program were to verify the operation of the indirect gasifier on commercial black liquor containing 65 percent solids at several temperature levels and to characterize the bed carbon content, bed solids particle size and sulfur distribution as a function of gasification conditions. 6 refs., 59 figs., 29 tabs.

  14. Hot-Gas Filter Testing with a Transport Reactor Gasifier

    SciTech Connect (OSTI)

    Swanson, M.L.; Hajicek, D.R.

    2002-09-18

    Today, coal supplies over 55% of the electricity consumed in the United States and will continue to do so well into the next century. One of the technologies being developed for advanced electric power generation is an integrated gasification combined cycle (IGCC) system that converts coal to a combustible gas, cleans the gas of pollutants, and combusts the gas in a gas turbine to generate electricity. The hot exhaust from the gas turbine is used to produce steam to generate more electricity from a steam turbine cycle. The utilization of advanced hot-gas particulate and sulfur control technologies together with the combined power generation cycles make IGCC one of the cleanest and most efficient ways available to generate electric power from coal. One of the strategic objectives for U.S. Department of Energy (DOE) IGCC research and development program is to develop and demonstrate advanced gasifiers and second-generation IGCC systems. Another objective is to develop advanced hot-gas cleanup and trace contaminant control technologies. One of the more recent gasification concepts to be investigated is that of the transport reactor gasifier, which functions as a circulating fluid-bed gasifier while operating in the pneumatic transport regime of solid particle flow. This gasifier concept provides excellent solid-gas contacting of relatively small particles to promote high gasification rates and also provides the highest coal throughput per unit cross-sectional area of any other gasifier, thereby reducing capital cost of the gasification island.

  15. Biomass waste gasification - Can be the two stage process suitable for tar reduction and power generation?

    SciTech Connect (OSTI)

    Sulc, Jindrich; Stojdl, Jiri; Richter, Miroslav; Popelka, Jan; Svoboda, Karel; Smetana, Jiri; Vacek, Jiri; Skoblja, Siarhei; Buryan, Petr

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Comparison of one stage (co-current) and two stage gasification of wood pellets. Black-Right-Pointing-Pointer Original arrangement with grate-less reactor and upward moving bed of the pellets. Black-Right-Pointing-Pointer Two stage gasification leads to drastic reduction of tar content in gas. Black-Right-Pointing-Pointer One stage gasification produces gas with higher LHV at lower overall ER. Black-Right-Pointing-Pointer Content of ammonia in gas is lower in two stage moving bed gasification. - Abstract: A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter-current downdraft in the second stage was developed and exploited for studying effects of two stage gasification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass particles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW{sub th}. The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950 Degree-Sign C) and for gasification reaction of the fuel gas with char. The second stage used additional combustion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar

  16. High-Temperature Water-Gas Shift Membrane Reactor Study

    SciTech Connect (OSTI)

    Ciocco, M.V.; Iyoha, O.; Enick, R.M.; Killmeyer, R.P.

    2007-06-01

    NETL’s Office of Research and Development is exploring the integration of membrane reactors into coal gasification plants as a way of increasing efficiency and reducing costs. Water-Gas Shift Reaction experiments were conducted in membrane reactors at conditions similar to those encountered at the outlet of a coal gasifier. The changes in reactant conversion and product selectivity due to the removal of hydrogen via the membrane reactor were quantified. Research was conducted to determine the influence of residence time and H2S on CO conversion in both Pd and Pd80wt%Cu membrane reactors. Effects of the hydrogen sulfide-to-hydrogen ratio on palladium and a palladium-copper alloy at high-temperature were also investigated. These results were compared to thermodynamic calculations for the stability of palladium sulfides.

  17. Catalytic Hydrothermal Gasification of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2008-05-06

    A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

  18. Gasification Systems 2013 Project Selections

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Department of Energy in 2013 selected ten projects that will focus on reducing the cost of gasification with carbon capture for producing electric power, fuels, and chemicals. The projects will...

  19. Power production from renewable resources in a gasification power system

    SciTech Connect (OSTI)

    Paisley, M.A.; Farris, G.; Bain, R.

    1996-12-31

    The US Department of Energy (DOE) has been a leader in the promotion and development of alternative fuel supplies based on renewable energy crops. One promising power generation technology is biomass gasification coupled with either a gas turbine in a combined cycle system or a fuel cell. The gasification of biomass can efficiently and economically produce a renewable source of a clean gaseous fuel suitable for use in these high efficiency power systems or as a substitute fuel in other combustion devices such as boilers, kilns, or other natural gas fired equipment. This paper discusses the development and commercialization of the Battelle high-throughput gasification process for gas turbine based power generation systems. Projected process economics for a gas turbine combined cycle plant are presented along with a description of integrated system operation coupling a 200kW gas turbine power generation system to a 10 ton per day gasifier, and current commercialization activities. 6 refs., 3 figs., 1 tab.

  20. Wabash River coal gasification repowering project -- first year operation experience

    SciTech Connect (OSTI)

    Troxclair, E.J.; Stultz, J.

    1997-12-31

    The Wabash River Coal Gasification Repowering Project (WRCGRP), a joint venture between Destec Energy, Inc. and PSI Energy, Inc., began commercial operation in November of 1995. The Project, selected by the United States Department of Energy (DOE) under the Clean Coal Program (Round IV) represents the largest operating coal gasification combined cycle plant in the world. This Demonstration Project has allowed PSI Energy to repower a 1950`s vintage steam turbine and install a new syngas fired combustion turbine to provide 262 MW (net) of electricity in a clean, efficient manner in a commercial utility setting while utilizing locally mined high sulfur Indiana bituminous coal. In doing so, the Project is also demonstrating some novel technology while advancing the commercialization of integrated coal gasification combined cycle technology. This paper discusses the first year operation experience of the Wabash Project, focusing on the progress towards achievement of the demonstration objectives.

  1. Coal gasification vessel

    DOE Patents [OSTI]

    Loo, Billy W.

    1982-01-01

    A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

  2. Coal liquefaction and gasification technologies

    SciTech Connect (OSTI)

    Mangold, E.C.; Muradaz, M.A.; Ouellette, R.P.; Farah, O.G.; Cheremisinoff, P.N.

    1982-01-01

    The state-of-the-art of selected coal liquefaction and gasification processes developed with support from the United States are reviewed. The Exxon Donor Solvent, H-Coal, SRC-I, SRC-II, Mobile Gasoline Synthesis, Fischer-Tropsch Synthesis, and Zinc Halide Hydrocracking liquefaction processes and the Slagging Lurgi, Texaco, Combustion Engineering, COGAS, and Shell-Koppers gasification processes are covered. Separate abstracts were prepared for 5 chapters.

  3. Materials of Gasification

    SciTech Connect (OSTI)

    2005-09-15

    The objective of this project was to accumulate and establish a database of construction materials, coatings, refractory liners, and transitional materials that are appropriate for the hardware and scale-up facilities for atmospheric biomass and coal gasification processes. Cost, fabricability, survivability, contamination, modes of corrosion, failure modes, operational temperatures, strength, and compatibility are all areas of materials science for which relevant data would be appropriate. The goal will be an established expertise of materials for the fossil energy area within WRI. This would be an effort to narrow down the overwhelming array of materials information sources to the relevant set which provides current and accurate data for materials selection for fossil fuels processing plant. A significant amount of reference material on materials has been located, examined and compiled. The report that describes these resources is well under way. The reference material is in many forms including texts, periodicals, websites, software and expert systems. The most important part of the labor is to refine the vast array of available resources to information appropriate in content, size and reliability for the tasks conducted by WRI and its clients within the energy field. A significant has been made to collate and capture the best and most up to date references. The resources of the University of Wyoming have been used extensively as a local and assessable location of information. As such, the distribution of materials within the UW library has been added as a portion of the growing document. Literature from recent journals has been combed for all pertinent references to high temperature energy based applications. Several software packages have been examined for relevance and usefulness towards applications in coal gasification and coal fired plant. Collation of the many located resources has been ongoing. Some web-based resources have been examined.

  4. Coal gasification construction materials: an overview

    SciTech Connect (OSTI)

    Arnold, J.M.; Laurens, R.M.; Danyluk, S.

    1981-12-01

    Materials performance test results are presented for two coal gasification processes, HYGAS SNG process, which converts any type of coal to substitute natural gas (SNG), and U-GAS fuel gas process, which converts coal to a low- or medium-heat value gas. A description of the pilot plant for each process and discussion of some experiences with materials and components used in plant construction is presented. Metals performance inside the gasifier reactors and in off-gas locations depended upon the character of the process. At moderate operating temperatures (427/sup 0/C), low-carbon steels are advisable. Very high-temperature environments may not only require use of exotic alloys, clads, and/or coatings but may also preclude extensive use of internal piping/valving in scale-up designs. Inconel 182, 600, and Monel 400 have all performed erratically in the plants; but in quench and purification sections, austenitic stainless steels performed well. 9 references. (BLM)

  5. June 2007 gasification technologies workshop papers

    SciTech Connect (OSTI)

    2007-06-15

    Topics covered in this workshop are fundamentals of gasification, carbon capture and sequestration, reviews of financial and regulatory incentives, co-production, and focus on gasification in the Western US.

  6. Reactor

    DOE Patents [OSTI]

    Evans, Robert M.

    1976-10-05

    1. A neutronic reactor having a moderator, coolant tubes traversing the moderator from an inlet end to an outlet end, bodies of material fissionable by neutrons of thermal energy disposed within the coolant tubes, and means for circulating water through said coolant tubes characterized by the improved construction wherein the coolant tubes are constructed of aluminum having an outer diameter of 1.729 inches and a wall thickness of 0.059 inch, and the means for circulating a liquid coolant through the tubes includes a source of water at a pressure of approximately 350 pounds per square inch connected to the inlet end of the tubes, and said construction including a pressure reducing orifice disposed at the inlet ends of the tubes reducing the pressure of the water by approximately 150 pounds per square inch.

  7. Hybrid Combustion-Gasification Chemical Looping

    SciTech Connect (OSTI)

    Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

    2009-01-07

    For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2

  8. Hydrogen Production: Biomass Gasification | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Gasification Hydrogen Production: Biomass Gasification Photo of a man standing near a pilot-scale gasification system. Biomass gasification is a mature technology pathway that uses a controlled process involving heat, steam, and oxygen to convert biomass to hydrogen and other products, without combustion. Because growing biomass removes carbon dioxide from the atmosphere, the net carbon emissions of this method can be low, especially if coupled with carbon capture, utilization, and

  9. Hydrogen Production: Coal Gasification | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal Gasification Hydrogen Production: Coal Gasification The U.S. Department of Energy (DOE) Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically through the process of coal gasification with carbon capture, utilization, and storage. DOE anticipates that coal gasification for hydrogen production with carbon capture, utilization, and storage could be deployed in the mid-term time frame. How Does It Work? Chemically, coal is a complex and highly

  10. Current Gasification Research | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    improvements in efficiency, fuel flexibility, economics and environmental sustainability. Fuel flexibility is especially important. Tomorrow's gasification plants conceivably could...

  11. Method and system for controlling a gasification or partial oxidation process

    DOE Patents [OSTI]

    Rozelle, Peter L; Der, Victor K

    2015-02-10

    A method and system for controlling a fuel gasification system includes optimizing a conversion of solid components in the fuel to gaseous fuel components, controlling the flux of solids entrained in the product gas through equipment downstream of the gasifier, and maximizing the overall efficiencies of processes utilizing gasification. A combination of models, when utilized together, can be integrated with existing plant control systems and operating procedures and employed to develop new control systems and operating procedures. Such an approach is further applicable to gasification systems that utilize both dry feed and slurry feed.

  12. Status of health and environmental research relative to coal gasification 1976 to the present

    SciTech Connect (OSTI)

    Wilzbach, K.E.; Reilly, C.A. Jr.

    1982-10-01

    Health and environmental research relative to coal gasification conducted by Argonne National Laboratory, the Inhalation Toxicology Research Institute, and Oak Ridge National Laboratory under DOE sponsorship is summarized. The studies have focused on the chemical and toxicological characterization of materials from a range of process streams in five bench-scale, pilot-plant and industrial gasifiers. They also address ecological effects, industrial hygiene, environmental control technology performance, and risk assessment. Following an overview of coal gasification technology and related environmental concerns, integrated summaries of the studies and results in each area are presented and conclusions are drawn. Needed health and environmental research relative to coal gasification is identified.

  13. Beluga Coal Gasification - ISER

    SciTech Connect (OSTI)

    Steve Colt

    2008-12-31

    ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

  14. Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel

    DOE Patents [OSTI]

    Schreiber, Roger B.; Fero, Arnold H.; Sejvar, James

    1997-01-01

    The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor.

  15. Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel

    DOE Patents [OSTI]

    Schreiber, R.B.; Fero, A.H.; Sejvar, J.

    1997-12-16

    The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor. 8 figs.

  16. Beluga coal gasification feasibility study

    SciTech Connect (OSTI)

    Robert Chaney; Lawrence Van Bibber

    2006-07-15

    The objective of the study was to determine the economic feasibility of developing and siting a coal-based integrated gasification combined-cycle (IGCC) plant in the Cook Inlet region of Alaska for the co-production of electric power and marketable by-products. The by-products, which may include synthesis gas, Fischer-Tropsch (F-T) liquids, fertilizers such as ammonia and urea, alcohols, hydrogen, nitrogen and carbon dioxide, would be manufactured for local use or for sale in domestic and foreign markets. This report for Phase 1 summarizes the investigation of an IGCC system for a specific industrial setting on the Cook Inlet, the Agrium U.S. Inc. ('Agrium') fertilizer plant in Nikiski, Alaska. Faced with an increase in natural gas price and a decrease in supply, the Agrium is investigating alternatives to gas as feed stock for their plant. This study considered all aspects of the installation and infrastructure, including: coal supply and cost, coal transport costs, delivery routes, feedstock production for fertilizer manufacture, plant steam and power, carbon dioxide (CO{sub 2}) uses, markets for possible additional products, and environmental permit requirements. The Cook Inlet-specific Phase 1 results, reported here, provided insight and information that led to the conclusion that the second study should be for an F-T plant sited at the Usibelli Coal Mine near Healy, Alaska. This Phase 1 case study is for a very specific IGCC system tailored to fit the chemical and energy needs of the fertilizer manufacturing plant. It demonstrates the flexibility of IGCC for a variety of fuel feedstocks depending on plant location and fuel availability, as well as the available variety of gas separation, gas cleanup, and power and steam generation technologies to fit specific site needs. 18 figs., 37 tabs., 6 apps.

  17. Integrating Safety, Operations, Security, and Safeguards (ISOSS) into the design of small modular reactors : a handbook.

    SciTech Connect (OSTI)

    Middleton, Bobby D.; Mendez, Carmen Margarita

    2013-10-01

    The existing regulatory environment for nuclear reactors impacts both the facility design and the cost of operations once the facility is built. Delaying the consideration of regulatory requirements until late in the facility design - or worse, until after construction has begun - can result in costly retrofitting as well as increased operational costs to fulfill safety, security, safeguards, and emergency readiness requirements. Considering the scale and scope, as well as the latest design trends in the next generation of nuclear facilities, there is an opportunity to evaluate the regulatory requirements and optimize the design process for Small Modular Reactors (SMRs), as compared to current Light Water Reactors (LWRs). To this end, Sandia has embarked on an initiative to evaluate the interactions of regulations and operations as an approach to optimizing the design of SMR facilities, supporting operational efficiencies, as well as regulatory requirements. The early stages of this initiative consider two focus areas. The first focus area, reported by LaChance, et al. (2007), identifies the regulatory requirements established for the current fleet of LWR facilities regarding Safety, Security, Operations, Safeguards, and Emergency Planning, and evaluates the technical bases for these requirements. The second focus area, developed in this report, documents the foundations for an innovative approach that supports a design framework for SMR facilities that incorporates the regulatory environment, as well as the continued operation of the facility, into the early design stages, eliminating the need for costly retrofitting and additional operating personnel to fulfill regulatory requirements. The work considers a technique known as Integrated Safety, Operations, Security and Safeguards (ISOSS) (Darby, et al., 2007). In coordination with the best practices of industrial operations, the goal of this effort is to develop a design framework that outlines how ISOSS

  18. Production of High-Quality Syngas via Biomass Gasification for Catalytic Synthesis of Liquid Fuels Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project 2015 Peer Review NC A&T Renewable Energy Center -Production of High-Quality Syngas via Biomass Gasification for Catalytic Synthesis of Liquid Fuels March 26 th 2015 Technology Area Review: Biomass Gasification Ghasem Shahbazi Biological Engineering North Carolina Agricultural and Technical State University Goal Statement The major goal of this project is to study an integrated biomass gasification and hot syngas cleaning process to produce high- quality syngas from woody biomass and

  19. Fundamental research on novel process alternatives for coal gasification: Final report

    SciTech Connect (OSTI)

    Hill, A H; Knight, R A; Anderson, G L; Feldkirchner, H L; Babu, S P

    1986-10-01

    The Institute of Gas Technology has conducted a fundamental research program to determine the technical feasibility of and to prepare preliminary process evaluations for two new approaches to coal gasification. These two concepts were assessed under two major project tasks: Task 1. CO/sub 2/-Coal Gasification Process Concept; Task 2. Internal Recirculation Catalysts Coal Gasification Process Concept. The first process concept involves CO/sub 2/-O/sub 2/ gasification of coal followed by CO/sub 2/ removal from the hot product gas by a solid MgO-containing sorbent. The sorbent is regenerated by either a thermal- or a pressure-swing step and the CO/sub 2/ released is recycled back to the gasifier. The product is a medium-Btu gas. The second process concept involves the use of novel ''semivolatile'' materials as internal recirculating catalysts for coal gasification. These materials remain in the gasifier because their vapor pressure-temperature behavior is such that they will be in the vapor state at the hotter, char exit part of the reactor and will condense in the colder, coal-inlet part of the reactor. 21 refs., 43 figs., 43 tabs.

  20. Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1

    SciTech Connect (OSTI)

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. ); Duthie, R.G. ); Wootten, J.M. )

    1991-09-01

    Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

  1. Black liquor gasification phase 2D final report

    SciTech Connect (OSTI)

    Kohl, A.L.; Stewart, A.E.

    1988-06-01

    This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

  2. Coal Gasification and Transportation Fuels Magazine | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 3 (April 2016) Archived Editions: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 2 (Jan 2016) Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 1 (Oct 2015) Coal Gasification and Transportation Fuels Quarterly News, Vol. 1, Issue 4 (July 2015) Coal Gasification and Transportation Fuels Quarterly News, Vol.

  3. Supercritical Pulverized Coal and Integrated Gasification Combined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of COE, plant HHV efficiency, cost of CO 2 captured, and CO 2 capture rate with design emission levels for SC PC cases ......

  4. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C.

    1980-01-01

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  5. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  6. Gasification of chars produced under simulated in situ processing...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; CHARS; GASIFICATION; COAL; PYROLYSIS; IN-SITU GASIFICATION; MATHEMATICAL MODELS; ...

  7. EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX February 18, 2009 EIS-0412: ...

  8. Advanced Biomass Gasification Technologies Inc ABGT | Open Energy...

    Open Energy Info (EERE)

    Biomass Gasification Technologies Inc ABGT Jump to: navigation, search Name: Advanced Biomass Gasification Technologies Inc. (ABGT) Place: New York, New York Zip: 10036 Product:...

  9. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis ...

  10. Integration of improved decontamination and characterization technologies in the decommissioning of the CP-5 research reactor

    SciTech Connect (OSTI)

    Bhattacharyya, S. K.; Boing, L. E.

    2000-02-17

    The aging of research reactors worldwide has resulted in a heightened awareness in the international technical decommissioning community of the timeliness to review and address the needs of these research institutes in planning for and eventually performing the decommissioning of these facilities. By using the reactors already undergoing decommissioning as test beds for evaluating enhanced or new/innovative technologies for decommissioning, it is possible that new techniques could be made available for those future research reactor decommissioning projects. Potentially, the new technologies will result in: reduced radiation doses to the work force, larger safety margins in performing decommissioning and cost and schedule savings to the research institutes in performing the decommissioning of these facilities. Testing of these enhanced technologies for decontamination, dismantling, characterization, remote operations and worker protection are critical to furthering advancements in the technical specialty of decommissioning. Furthermore, regulatory acceptance and routine utilization for future research reactor decommissioning will be assured by testing and developing these technologies in realistically contaminated environments prior to use in the research reactors. The decommissioning of the CP-5 Research Reactor is currently in the final phase of dismantlement. In this paper the authors present results of work performed at Argonne National Laboratory (ANL) in the development, testing and deployment of innovative and/or enhanced technologies for the decommissioning of research reactors.

  11. Coal gasification plant

    DOE Patents [OSTI]

    Wood, Andrew

    1978-01-01

    A removable annular hearth member, shaped to fit over the slag outlet of a slagging gasifier, comprises a cast body of high thermal conductivity having integral coolant passageways, said passageways being formed by shaping a metal tube into a coil having an inlet and an outlet, and casting metal to the desired shape around the coil such that the inlet and outlet communicate exteriorly of the cast body.

  12. INTEGRAL BENCHMARKS AVAILABLE THROUGH THE INTERNATIONAL REACTOR PHYSICS EXPERIMENT EVALUATION PROJECT AND THE INTERNATIONAL CRITICALITY SAFETY BENCHMARK EVALUATION PROJECT

    SciTech Connect (OSTI)

    J. Blair Briggs; Lori Scott; Enrico Sartori; Yolanda Rugama

    2008-09-01

    Interest in high-quality integral benchmark data is increasing as efforts to quantify and reduce calculational uncertainties accelerate to meet the demands of next generation reactor and advanced fuel cycle concepts. The International Reactor Physics Experiment Evaluation Project (IRPhEP) and the International Criticality Safety Benchmark Evaluation Project (ICSBEP) continue to expand their efforts and broaden their scope to identify, evaluate, and provide integral benchmark data for method and data validation. Benchmark model specifications provided by these two projects are used heavily by the international reactor physics, nuclear data, and criticality safety communities. Thus far, 14 countries have contributed to the IRPhEP, and 20 have contributed to the ICSBEP. The status of the IRPhEP and ICSBEP is discussed in this paper, and the future of the two projects is outlined and discussed. Selected benchmarks that have been added to the IRPhEP and ICSBEP handbooks since PHYSOR’06 are highlighted, and the future of the two projects is discussed.

  13. THE INTEGRATION OF PROCESS HEAT APPLICATIONS TO HIGH TEMPERATURE GAS REACTORS

    SciTech Connect (OSTI)

    Michael G. McKellar

    2011-11-01

    A high temperature gas reactor, HTGR, can produce industrial process steam, high-temperature heat-transfer gases, and/or electricity. In conventional industrial processes, these products are generated by the combustion of fossil fuels such as coal and natural gas, resulting in significant emissions of greenhouse gases such as carbon dioxide. Heat or electricity produced in an HTGR could be used to supply process heat or electricity to conventional processes without generating any greenhouse gases. Process heat from a reactor needs to be transported by a gas to the industrial process. Two such gases were considered in this study: helium and steam. For this analysis, it was assumed that steam was delivered at 17 MPa and 540 C and helium was delivered at 7 MPa and at a variety of temperatures. The temperature of the gas returning from the industrial process and going to the HTGR must be within certain temperature ranges to maintain the correct reactor inlet temperature for a particular reactor outlet temperature. The returning gas may be below the reactor inlet temperature, ROT, but not above. The optimal return temperature produces the maximum process heat gas flow rate. For steam, the delivered pressure sets an optimal reactor outlet temperature based on the condensation temperature of the steam. ROTs greater than 769.7 C produce no additional advantage for the production of steam.

  14. Chemical looping coal gasification with calcium ferrite and barium ferrite via solid--solid reactions

    SciTech Connect (OSTI)

    Siriwardane, Ranjani; Tian, Hanjing; Richards, George

    2016-01-01

    Coal gasification to produce synthesis gas by chemical looping was investigated with two oxygen carriers, barium ferrite (BaFe2O4) and calcium ferrite (CaFe2O4). Thermo-gravimetric analysis (TGA) and fixed-bed flow reactor data indicated that a solid–solid interaction occurred between oxygen carriers and coal to produce synthesis gas. Both thermodynamic analysis and experimental data indicated that BaFe2O4 and CaFe2O4 have high reactivity with coal but have a low reactivity with synthesis gas, which makes them very attractive for the coal gasification process. Adding steam increased the production of hydrogen (H2) and carbon monoxide (CO), but carbon dioxide (CO2) remained low because these oxygen carriers have minimal reactivity with H2 and CO. Therefore, the combined steam–oxygen carrier produced the highest quantity of synthesis gas. It appeared that neither the water–gas shift reaction nor the water splitting reaction promoted additional H2 formation with the oxygen carriers when steam was present. Wyodak coal, which is a sub-bituminous coal, had the best gasification yield with oxygen carrier–steam while Illinois #6 coal had the lowest. The rate of gasification and selectivity for synthesis gas production was significantly higher when these oxygen carriers were present during steam gasification of coal. The rates and synthesis gas yields during the temperature ramps of coal–steam with oxygen carriers were better than with gaseous oxygen.

  15. Pyrolysis and gasification of coal at high temperatures

    SciTech Connect (OSTI)

    Zygourakis, K.

    1988-01-01

    Coals of different ranks will be pyrolyzed in a microscope hot-stage reactor using inert and reacting atmospheres. The macropore structure of the produced chars will be characterized using video microscopy and digital image processing techniques to obtain pore size distributions. Comparative studies will quantify the effect of pyrolysis conditions (heating rates, final heat treatment temperatures, particle size and inert or reacting atmosphere) on the pore structure of the devolatilized chars. The devolatilized chars will be gasified in the regime of strong intraparticle diffusional limitations using O{sub 2}/N{sub 2} and O{sub 2}/H{sub 2}O/N{sub 2}2 mixtures. Constant temperature and programmed-temperature experiments in a TGA will be used for these studies. Additional gasification experiments performed in the hot-stage reactor will be videotaped and selected images will be analyzed to obtain quantitative data on particle shrinkage and fragmentation. Discrete mathematical models will be developed and validated using the experimental gasification data.

  16. Improved catalysts for carbon and coal gasification

    DOE Patents [OSTI]

    McKee, D.W.; Spiro, C.L.; Kosky, P.G.

    1984-05-25

    This invention relates to improved catalysts for carbon and coal gasification and improved processes for catalytic coal gasification for the production of methane. The catalyst is composed of at least two alkali metal salts and a particulate carbonaceous substrate or carrier is used. 10 figures, 2 tables.

  17. Updated Generation IV Reactors Integrated Materials Technology Program Plan, Revision 2

    SciTech Connect (OSTI)

    Corwin, William R; Burchell, Timothy D; Halsey, William; Hayner, George; Katoh, Yutai; Klett, James William; McGreevy, Timothy E; Nanstad, Randy K; Ren, Weiju; Snead, Lance Lewis; Stoller, Roger E; Wilson, Dane F

    2005-12-01

    The Department of Energy's (DOE's) Generation IV Nuclear Energy Systems Program will address the research and development (R&D) necessary to support next-generation nuclear energy systems. Such R&D will be guided by the technology roadmap developed for the Generation IV International Forum (GIF) over two years with the participation of over 100 experts from the GIF countries. The roadmap evaluated over 100 future systems proposed by researchers around the world. The scope of the R&D described in the roadmap covers the six most promising Generation IV systems. The effort ended in December 2002 with the issue of the final Generation IV Technology Roadmap [1.1]. The six most promising systems identified for next generation nuclear energy are described within the roadmap. Two employ a thermal neutron spectrum with coolants and temperatures that enable hydrogen or electricity production with high efficiency (the Supercritical Water Reactor - SCWR and the Very High Temperature Reactor - VHTR). Three employ a fast neutron spectrum to enable more effective management of actinides through recycling of most components in the discharged fuel (the Gas-cooled Fast Reactor - GFR, the Lead-cooled Fast Reactor - LFR, and the Sodium-cooled Fast Reactor - SFR). The Molten Salt Reactor (MSR) employs a circulating liquid fuel mixture that offers considerable flexibility for recycling actinides, and may provide an alternative to accelerator-driven systems. A few major technologies have been recognized by DOE as necessary to enable the deployment of the next generation of advanced nuclear reactors, including the development and qualification of the structural materials needed to ensure their safe and reliable operation. Accordingly, DOE has identified materials as one of the focus areas for Gen IV technology development.

  18. Coal gasification plant

    SciTech Connect (OSTI)

    Hebden, D.; Brooks, C.T.

    1984-12-11

    A slagging gasifier has a hearth comprising an annular solid cast structure formed from a high thermal conductivity metal such as copper and shaped to fit above a slag tap of the gasifier. The hearth is provided with one or more integrally formed passageways for circulating a coolant liquid therethrough and has an upper tundish surface with a slope of at least 10/sup 0/ to the horizontal (preferably between 25/sup 0/ and 45/sup 0/), across which tundish surface the molten slag flows downwardly and inwardly towards the slag tap. The annular structure may be formed from at least three sector-shaped cast parts secured together in situ in the gasifier.

  19. Process and technological aspects of municipal solid waste gasification. A review

    SciTech Connect (OSTI)

    Arena, Umberto

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Critical assessment of the main commercially available MSW gasifiers. Black-Right-Pointing-Pointer Detailed discussion of the basic features of gasification process. Black-Right-Pointing-Pointer Description of configurations of gasification-based waste-to-energy units. Black-Right-Pointing-Pointer Environmental performance analysis, on the basis of independent sources data. - Abstract: The paper proposes a critical assessment of municipal solid waste gasification today, starting from basic aspects of the process (process types and steps, operating and performance parameters) and arriving to a comparative analysis of the reactors (fixed bed, fluidized bed, entrained bed, vertical shaft, moving grate furnace, rotary kiln, plasma reactor) as well as of the possible plant configurations (heat gasifier and power gasifier) and the environmental performances of the main commercially available gasifiers for municipal solid wastes. The analysis indicates that gasification is a technically viable option for the solid waste conversion, including residual waste from separate collection of municipal solid waste. It is able to meet existing emission limits and can have a remarkable effect on reduction of landfill disposal option.

  20. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect (OSTI)

    Calderon, A.; Madison, E.; Probert, P.

    1992-01-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H[sub 2] mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO[sub x] (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  1. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect (OSTI)

    Calderon, A.; Madison, E.; Probert, P.

    1992-11-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H{sub 2} mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO{sub x} (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  2. Coal gasification plant

    SciTech Connect (OSTI)

    Anderson, J.A.

    1980-04-01

    A coal slagging gasifier and method of operating such gasifier are improved by providing an improved slag removal orifice. The orifice is located centrally within the hearth of a gasifier of the type in which hot burner gases are directed up through the orifice to retain the slag in molten condition on the hearth and in which the slag is periodically discharged through the slag removal orifice. The slag removal orifice is formed as a substantially vertical passageway through the removable slag tap member which comprises a solid cast mass of high thermal conductivity metal having an integrally formed metal tube for circulating liquid coolant through the cast mass. The upper tundish surface of the slag tap member slopes downwardly and inwardly and merges with the slag removal orifice. The coolant tube is capable of retaining its shape without any appreciable distortion during the casting of the surrounding metal mass, extends through the cast mass, and forms a coolant conduit adjacent to the tundish surface and to the surface of the orifice passageway and spaced from these surfaces a distance of 0.25 to 5 inches. The ends of the tube project out from the mass provide a coolant inlet and outlet. In operation, coolant is circulated through the tube such that the surfaces of the cast mass in direct contact with slag and burner gases are maintained at a temperature of from 50/sup 0/C to 400/sup 0/C.

  3. Mississippi Ethanol Gasification Project, Final Scientific / Technical Report

    SciTech Connect (OSTI)

    Pearson, Larry, E.

    2007-04-30

    The Mississippi Ethanol (ME) Project is a comprehensive effort to develop the conversion of biomass to ethanol utilizing a proprietary gasification reactor technology developed by Mississippi Ethanol, LLC. Tasks were split between operation of a 1/10 scale unit at the Diagnostic Instrumentation and Analysis Laboratory (DIAL) of Mississippi State University (MSU) and the construction, development, and operation of a full scale pilot unit located at the ME facility in Winona, Mississippi. In addition to characterization of the ME reactor gasification system, other areas considered critical to the operational and economic viability of the overall ME concept were evaluated. These areas include syngas cleanup, biological conversion of syngas to alcohol, and effects of gasification scale factors. Characterization of run data from the Pre-Pilot and Pilot Units has allowed development of the factors necessary for scale-up from the small unit to the larger unit. This scale range is approximately a factor of 10. Particulate and tar sampling gave order of magnitude values for preliminary design calculations. In addition, sampling values collected downstream of the ash removal system show significant reductions in observed loadings. These loading values indicate that acceptable particulate and tar loading rates could be attained with standard equipment additions to the existing configurations. Overall operation both the Pre-Pilot and Pilot Units proceeded very well. The Pilot Unit was operated as a system, from wood receiving to gas flaring, several times and these runs were used to address possible production-scale concerns. Among these, a pressure feed system was developed to allow feed of material against gasifier system pressure with little or no purge requirements. Similarly, a water wash system, with continuous ash collection, was developed, installed, and tested. Development of a biological system for alcohol production was conducted at Mississippi State University with

  4. Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor

    SciTech Connect (OSTI)

    Mahesh Iyer; Shwetha Ramkumar; Liang-Shih Fan

    2006-03-31

    Hydrogen production from coal gasification can be enhanced by driving the equilibrium limited Water Gas Shift reaction forward by incessantly removing the CO{sub 2} by-product via the carbonation of calcium oxide. This project uses the high-reactivity mesoporous precipitated calcium carbonate sorbent for removing the CO{sub 2} product to enhance H{sub 2} production. Preliminary experiments demonstrate the show the superior performance of the PCC sorbent over other naturally occurring calcium sorbents. It was observed that the CO{sub 2} released during the in-situ calcination causes the deactivation of the iron oxide WGS catalyst by changing the active phase of the catalyst from magnetite (F{sub 3}O{sub 4}). Detailed understanding of the iron oxide phase diagram helped in developing a catalyst pretreatment procedure using a H{sub 2}/H{sub 2}O system. Intermediate catalyst pretreatment helps prevent its deactivation by reducing the catalyst back to its active magnetite (Fe{sub 3}O{sub 4}) form. Multicyclic runs which consist of combined WGS/carbonation reaction followed by in-situ calcination with a subsequent catalyst pretreatment procedure sustains the catalytic activity and prevents deactivation. The water gas shift reaction was studied at different temperatures, different steam to carbon monoxide ratios (S/C) 3:1, 2:1, 1:1 and different total pressures ranging from 0-300 psig. The CO conversion was found to have an optimal value with increasing pressure, S/C ratio and temperatures. The combined water gas shift and carbonation reaction was investigated at 650 C, S/C ratio of 3:1and at different pressures of 0-300 psig.

  5. Defective fuel rod detection in operating pressurized water reactors during periods of continuously decreasing fuel rod integrity levels

    SciTech Connect (OSTI)

    Zanker, H. )

    1989-09-01

    Periods of continuously decreasing levels of fuel rod integrity due to debris-induced cladding damage, vibration-induced fretting wear of the cladding, etc. cause difficulties in the assessment of fuel rod performance from coolant activity data. The calculational models currently in use for this purpose in nuclear power plants are not sufficiently capable of indicating cases in which they are invalid. This can mislead reactor operators by misinterpretation of the coolant activity data, especially in situations where fast reactions are necessary. A quick test of validity is suggested to check the applicability of the currently available calculational models for estimating the number and average size of fuel rod defects. This paper describes how to recognize immediately periods of continuously decreasing levels of fuel rod integrity in order to prevent complications in routine power plant maintenance as well as accident situations caused by more severe fuel rod degradation.

  6. Integral cross section measurement of the U 235 ( n , n ' ) U 235 m reaction in a pulsed reactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bélier, G.; Bond, E. M.; Vieira, D. J.; Authier, N.; Becker, J. A.; Hyneck, D.; Jacquet, X.; Jansen, Y.; Legendre, J.; Macri, R.; et al

    2015-04-08

    The integral measurement of the neutron inelastic cross section leading to the 26-minute half-life 235mU isomer in a fission-like neutron spectrum is presented. The experiment has been performed at a pulsed reactor, where the internal conversion decay of the isomer was measured using a dedicated electron detector after activation. The sample preparation, efficiency measurement, irradiation, radiochemistry purification, and isomer decay measurement will be presented. We determined the integral cross section for the ²³⁵U(n,n')235mU reaction to be 1.00±0.13b. This result supports an evaluation performed with TALYS-1.4 code with respect to the isomer excitation as well as the total neutron inelastic scatteringmore » cross section.« less

  7. Steam gasification of carbon: Catalyst properties

    SciTech Connect (OSTI)

    Falconer, J.L.

    1993-01-10

    Coal gasification by steam is of critical importance in converting coal to gaseous products (CO, H[sub 2], CO[sub 2], CH[sub 4]) that can then be further converted to synthetic natural gas and higher hydrocarbon fuels. Alkali and alkaline earth metals (present as oxides) catalyze coal gasification reactions and cause them to occur at significantly lower temperatures. A more fundamental understanding of the mechanism of the steam gasification reaction and catalyst utilization may well lead to better production techniques, increased gasification rates, greater yields, and less waste. We are studying the gasification of carbon by steam in the presence of alkali and alkaline earth oxides, using carbonates as the starting materials. Carbon dioxide gasification (CO[sub 2] + C --> 2CO) has been studied in some detail recently, but much less has been done on the actual steam gasification reaction, which is the main thrust of our work. In particular, the form of the active catalyst compound during reaction is still questioned and the dependence of the concentration of active sites on reaction parameters is not known. Until recently, no measurements of active site concentrations during reaction had been made. We have recently used transient isotope tracing to determine active site concentration during CO[sub 2] gasification. We are investigating the mechanism and the concentration of active sites for steam gasification with transient isotopic tracing. For this technique, the reactant feed is switched from H[sub 2]0 to isotopically-labeled water at the same concentration and tow rate. We can then directly measure, at reaction the concentration of active catalytic sites, their kinetic rate constants, and the presence of more than one rate constant. This procedure allows us to obtain transient kinetic data without perturbing the steady-state surface reactions.

  8. The direct observation of alkali vapor species in biomass combustion and gasification

    SciTech Connect (OSTI)

    French, R.J.; Dayton, D.C.; Milne, T.A.

    1994-01-01

    This report summarizes new data from screening various feedstocks for alkali vapor release under combustion conditions. The successful development of a laboratory flow reactor and molecular beam, mass spectrometer interface is detailed. Its application to several herbaceous and woody feedstocks, as well as a fast-pyrolysis oil, under 800 and 1,100{degrees}C batch combustion, is documented. Chlorine seems to play a large role in the facile mobilization of potassium. Included in the report is a discussion of relevant literature on the alkali problem in combustors and turbines. Highlighted are the phenomena identified in studies on coal and methods that have been applied to alkali speciation. The nature of binding of alkali in coal versus biomass is discussed, together with the implications for the ease of release. Herbaceous species and many agricultural residues appear to pose significant problems in release of alkali species to the vapor at typical combustor temperatures. These problems could be especially acute in direct combustion fired turbines, but may be ameliorated in integrated gasification combined cycles.

  9. Fluidized bed catalytic coal gasification process

    DOE Patents [OSTI]

    Euker, Jr., Charles A.; Wesselhoft, Robert D.; Dunkleman, John J.; Aquino, Dolores C.; Gouker, Toby R.

    1984-01-01

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  10. Integrated production of fuel gas and oxygenated organic compounds from synthesis gas

    DOE Patents [OSTI]

    Moore, Robert B.; Hegarty, William P.; Studer, David W.; Tirados, Edward J.

    1995-01-01

    An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

  11. Industrial co-generation through use of a medium BTU gas from biomass produced in a high throughput reactor

    SciTech Connect (OSTI)

    Feldmann, H.F.; Ball, D.A.; Paisley, M.A.

    1983-01-01

    A high-throughput gasification system has been developed for the steam gasification of woody biomass to produce a fuel gas with a heating value of 475 to 500 Btu/SCF without using oxygen. Recent developments have focused on the use of bark and sawdust as feedstocks in addition to wood chips and the testing of a new reactor concept, the so-called controlled turbulent zone (CTZ) reactor to increase gas production per unit of wood fed. Operating data from the original gasification system and the CTZ system are used to examine the preliminary economics of biomass gasification/gas turbine cogeneration systems. In addition, a ''generic'' pressurized oxygen-blown gasification system is evaluated. The economics of these gasification systems are compared with a conventional wood boiler/steam turbine cogeneration system.

  12. Mass transfer effects in a gasification riser

    SciTech Connect (OSTI)

    Breault, Ronald W; Li, Tingwen; Nicoletti, Phillip

    2013-01-01

    In the development of multiphase reacting computational fluid dynamics (CFD) codes, a number of simplifications were incorporated into the codes and models. One of these simplifications was the use of a simplistic mass transfer correlation for the faster reactions and omission of mass transfer effects completely on the moderate speed and slow speed reactions such as those in a fluidized bed gasifier. Another problem that has propagated is that the mass transfer correlation used in the codes is not universal and is being used far from its developed bubbling fluidized bed regime when applied to circulating fluidized bed (CFB) riser reactors. These problems are true for the major CFD codes. To alleviate this problem, a mechanistic based mass transfer coefficient algorithm has been developed based upon an earlier work by Breault et al. This fundamental approach uses the local hydrodynamics to predict a local, time varying mass transfer coefficient. The predicted mass transfer coefficients and the corresponding Sherwood numbers agree well with literature data and are typically about an order of magnitude lower than the correlation noted above. The incorporation of the new mass transfer model gives the expected behavior for all the gasification reactions evaluated in the paper. At the expected and typical design values for the solid flow rate in a CFB riser gasifier an ANOVA analysis has shown the predictions from the new code to be significantly different from the original code predictions. The new algorithm should be used such that the conversions are not over predicted. Additionally, its behaviors with changes in solid flow rate are consistent with the changes in the hydrodynamics.

  13. Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1. Final report

    SciTech Connect (OSTI)

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H.; Duthie, R.G.; Wootten, J.M.

    1991-09-01

    Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

  14. Hydrogen Production Cost Estimate Using Biomass Gasification...

    Broader source: Energy.gov (indexed) [DOE]

    potential of Hydrogen Production Cost Estimate Using Biomass Gasification The Panel reviewed the current H2A case (Version 2.12, Case 01D) for hydrogen production via ...

  15. Catalysts for carbon and coal gasification

    DOE Patents [OSTI]

    McKee, Douglas W.; Spiro, Clifford L.; Kosky, Philip G.

    1985-01-01

    Catalyst for the production of methane from carbon and/or coal by means of catalytic gasification. The catalyst compostion containing at least two alkali metal salts. A particulate carbonaceous substrate or carrier is used.

  16. How Coal Gasification Power Plants Work

    Broader source: Energy.gov [DOE]

    The heart of a gasification-based system is the gasifier. A gasifier converts hydrocarbon feedstock into gaseous components by applying heat under pressure in the presence of steam.  

  17. Development and commercialization of a biomass gasification/power generation system

    SciTech Connect (OSTI)

    Paisley, M.A.; Farris, G.

    1995-11-01

    The US Department of Energy (DOE) has been a leader in the promotion and development of alternative fuel supplies based on renewable energy crops. One promising power generation technology is biomass gasification coupled with either a gas turbine in a combined cycle system or a fuel cell. The gasification of biomass can efficiently and economically produce a renewable source of a clean gaseous fuel suitable for use in these high efficiency power systems or as a substitute fuel in other combustion devices such as boilers, kilns, or other natural gas fired equipment. This paper discusses the development and commercialization of the Battelle high-throughput gasification process for gas turbine based power generation systems. Projected process economics for a gas turbine combined cycle plant are presented along with a description of integrated system operation coupling a 200kW gas turbine power generation system to a 10 ton per day gasifier, and current commercialization activities.

  18. Updraft Fixed Bed Gasification Aspen Plus Model

    SciTech Connect (OSTI)

    2007-09-27

    The updraft fixed bed gasification model provides predictive modeling capabilities for updraft fixed bed gasifiers, when devolatilization data is available. The fixed bed model is constructed using Aspen Plus, process modeling software, coupled with a FORTRAN user kinetic subroutine. Current updraft gasification models created in Aspen Plus have limited predictive capabilities and must be "tuned" to reflect a generalized gas composition as specified in literature or by the gasifier manufacturer. This limits the applicability of the process model.

  19. Hot waste-to-energy flue gas treatment using an integrated fluidised bed reactor

    SciTech Connect (OSTI)

    Bianchini, A.; Pellegrini, M.; Saccani, C.

    2009-04-15

    This paper describes an innovative process to increase superheated steam temperatures in waste-to-energy (WTE) plants. This solution is mainly characterised by a fluidised bed reactor in which hot flue gas is treated both chemically and mechanically. This approach, together with gas recirculation, increases the energy conversion efficiency, and raises the superheated steam temperature without decreasing the useful life of the superheater. This paper presents new experimental data obtained from the test facility installed at the Hera S.p.A. WTE plant in Forli, Italy; discusses changes that can be implemented to increase the duration of experimental testing; offers suggestions for the design of an industrial solution.

  20. Integral Validation of Minor Actinide Nuclear Data by using Samples Irradiated at Dounreay Prototype Fast Reactor

    SciTech Connect (OSTI)

    Tsujimoto, Kazufumi; Oigawa, Hiroyuki; Shinohara, Nobuo [Japan Atomic Energy Research Institute, Shirakata Shirane 2-4, Tokai, Ibaraki 319-1195 (Japan)

    2005-05-24

    The reliability of nuclear data for minor actinides was evaluated by using the results of the post-irradiation experiment for actinide samples irradiated at the Dounreay Prototype Fast Reactor. The burnup calculations with JENDL-3.3, ENDF/B-VI.8, and JEFF-3.0 were performed. From the comparison between the experimental data and the calculational results, in general, the reliability of nuclear data for the minor actinides are at an adequate level for the conceptual design study of transmutation systems. It is, however, found that improvement of the accuracy is necessary for some nuclides, such as 238Pu, 242Pu, and 241Am.

  1. Screening of low cost sorbents for arsenic and mercury capture in gasification systems

    SciTech Connect (OSTI)

    Cedric Charpenteau; Revata Seneviratne; Anthe George; Marcos Millan; Denis R. Dugwell; Rafael Kandiyoti

    2007-09-15

    A novel laboratory-scale fixed-bed reactor has been developed to investigate trace metal capture on selected sorbents for cleaning the hot raw gas in Integrated Gasification Combined Cycle (IGCC) power plants. The new reactor design is presented, together with initial results for mercury and arsenic capture on five sorbents. It was expected that the capture efficiency of sorbents would decrease with increasing temperature. However, a commercial activated carbon, Norit Darco 'Hg', and a pyrolysis char prepared from scrap tire rubber exhibit similar efficiencies for arsenic at 200 and at 400{sup o}C (70% and 50%, respectively). Meta-kaolinite and fly ash both exhibit an efficiency of around 50% at 200{sup o}C, which then dropped as the test temperature was increased to 400{sup o}C. Activated scrap tire char performed better at 200{sup o}C than the pyrolysis char showing an arsenic capture capacity similar to that of commercial Norit Darco 'Hg'; however, efficiency dropped to below 40% at 400{sup o}C. These results suggest that the capture mechanism of arsenic (As4) is more complex than purely physical adsorption onto the sorbents. Certain elements within the sorbents may have significant importance for chemical adsorption, in addition to the effect of surface area, as determined by the BET method. This was indeed the case for the mercury capture efficiency for all four sorbents tested. Three of the sorbents tested retained 90% of the mercury when operated at 100{sup o}C. As the temperature increased, the efficiency of activated carbon and pyrolysis char reduced significantly. Curiously, despite having the smallest Brunauer-Emmet-Teller (BET) surface area, a pf-combustion ash was the most effective in capturing mercury over the temperature range studied. These observations suggest that the observed mercury capture was not purely physical adsorption but a combination of physical and chemical processes. 27 refs., 4 figs., 4 tabs.

  2. Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor

    SciTech Connect (OSTI)

    Shwetha Ramkumar; Mahesh Iyer; Danny Wong; Himanshu Gupta; Bartev Sakadjian; Liang-Lhih Fan

    2008-09-30

    High purity hydrogen is commercially produced from syngas by the Water Gas Shift Reaction (WGSR) in high and low temperature shift reactors using iron oxide and copper catalysts respectively. However, the WGSR is thermodynamically limited at high temperatures towards hydrogen production necessitating excess steam addition and catalytic operation. In the calcium looping process, the equilibrium limited WGSR is driven forward by the incessant removal of CO{sub 2} by-product through the carbonation of calcium oxide. At high pressures, this process obviates the need for a catalyst and excess steam requirement, thereby removing the costs related to the procurement and deactivation of the catalyst and steam generation. Thermodynamic analysis for the combined WGS and carbonation reaction was conducted. The combined WGS and carbonation reaction was investigated at varying pressures, temperatures and S/C ratios using a bench scale reactor system. It was found that the purity of hydrogen increases with the increase in pressure and at a pressure of 300 psig, almost 100% hydrogen is produced. It was also found that at high pressures, high purity hydrogen can be produced using stoichiometric quantities of steam. On comparing the catalytic and non catalytic modes of operation in the presence of calcium oxide, it was found that there was no difference in the purity of hydrogen produced at elevated pressures. Multicyclic reaction and regeneration experiments were also conducted and it was found that the purity of hydrogen remains almost constant after a few cycles.

  3. Micro-channel catalytic reactor integration in CAPER and research/development on highly tritiated water handling and processing

    SciTech Connect (OSTI)

    Demange, D.; Cristescu, I.; Fanghaenel, E.; Gramlich, N.; Le, T.L.; Michling, R.; Moosmann, H.; Simon, K.H.; Wagner, R.; Welte, S.; Glugla, M.; Shu, W.M.; Willms, R.S.

    2015-03-15

    The CAPER facility of the Tritium Laboratory Karlsruhe has demonstrated the technology for the tokamak exhaust processing. CAPER has been significantly upgraded to pursue research/development programs towards highly tritiated water (HTW) handling and processing. The preliminary tests using a metal oxide reactor producing HTW afterward de-tritiated with PERMCAT were successful. In a later stage, a micro-channel catalytic reactor was installed in view of long term research program on HTW. The integration of this new system in CAPER was carried out along with a careful safety analysis due to high risk associated with such experiments. First experiments using the μ-CCR were performed trouble free, and HTW up to 360 kCi/kg was produced at a rate of 0.5 g/h. Such HTW was collected into a platinum zeolite bed (2 g of HTW for 20 g of Pt-zeolite), and in-situ detritiation was performed via isotopic exchange with deuterium. These first experimental results with tritium confirmed the potential for the capture and exchange method to be used for HTW in ITER. (authors)

  4. Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications

    SciTech Connect (OSTI)

    Lee Nelson

    2009-10-01

    This report is a preliminary comparison of conventional and potential HTGR-integrated processesa in several common industrial areas: ? Producing electricity via a traditional power cycle ? Producing hydrogen ? Producing ammonia and ammonia-derived products, such as fertilizer ? Producing gasoline and diesel from natural gas or coal ? Producing substitute natural gas from coal, and ? Steam-assisted gravity drainage (extracting oil from tar sands).

  5. Low-temperature catalytic gasification of wet industrial wastes

    SciTech Connect (OSTI)

    Elliott, D C; Neuenschwander, G G; Baker, E G; Sealock, Jr, L J; Butner, R S

    1991-04-01

    Bench-scale reactor tests are in progress at Pacific Northwest Laboratory to develop a low-temperature, catalytic gasification system. The system, licensed under the trade name Thermochemical Environmental Energy System (TEES{reg sign}), is designed for treating a wide variety of feedstocks ranging from dilute organics in water to waste sludges from food processing. This report describes a test program which used a continuous-feed tubular reactor. This test program is an intermediate stage in the process development. The reactor is a laboratory-scale version of the commercial concept as currently envisioned by the process developers. An energy benefit and economic analysis was also completed on the process. Four conceptual commercial installations of the TEES process were evaluated for three food processing applications and one organic chemical manufacturing application. Net energy production (medium-Btu gas) was achieved in all four cases. The organic chemical application was found to be economically attractive in the present situation. Based on sensitivity studies included in the analysis, the three food processing cases will likely become attractive in the near future as waste disposal regulations tighten and disposal costs increase. 21 refs., 2 figs., 9 tabs.

  6. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and

  7. Gasification of chars produced under simulated in situ processing...

    Office of Scientific and Technical Information (OSTI)

    COAL; CRYOGENIC FLUIDS; DECOMPOSITION; ELEMENTS; ENERGY SOURCES; FLUIDS; FOSSIL FUELS; FUELS; GASES; GASIFICATION; HYDROCARBONS; IN-SITU PROCESSING; KINETICS; MICROSCOPY; ...

  8. Potential trace element emissions from the gasification of Illinois...

    Office of Scientific and Technical Information (OSTI)

    MATERIALS; CHEMICAL ANALYSIS; DIAGRAMS; EMISSION SPECTROSCOPY; ENERGY SOURCES; FOSSIL FUELS; FUELS; GASIFICATION; GREAT LAKES REGION; HALOGENS; INDUSTRIAL PLANTS; METALS; ...

  9. DOE Technical Targets for Hydrogen Production from Biomass Gasification |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Biomass Gasification DOE Technical Targets for Hydrogen Production from Biomass Gasification These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen production from biomass gasification. More information about targets can be found in the Hydrogen Production section of the Fuel Cell Technologies Office's Multi-Year Research, Development, and Demonstration Plan. Technical Targets: Biomass Gasification/Pyrolysis

  10. Thermochemical Conversion Research and Development: Gasification and Pyrolysis (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2009-09-01

    Biomass gasification and pyrolysis research and development activities at the National Renewable Energy Laboratory and Pacific Northwest National Laboratory.

  11. Quarterly Report, Dec. 1, 1999-Feb. 29, 2000, Novel, Integrated Reactor

    SciTech Connect (OSTI)

    Paramono, D.V.

    2000-03-29

    The basic core design requirements were defined in the previous reporting period. During the second quarter, several series of neutronic calculations were performed. Monte Carlo BOL (Beginning-of-Life) simulations were performed to evaluate the impact of various design alternatives on key core parameters. Fuel design alternatives that were examined by these studies included: fuel form (oxide, carbide and nitride) (note that due to the AMTEC high temperature requirement, metal fuel was eliminated from further considerations); fissile fuel content, and fuel rod and lattice pitch. The key neutronic parameters that were compared include: core reactivity, neutron spectrum, fast neutron flux and projected lifetime fast fluence (E > 0.1 MeV), and material damage indicator, dpa (displacement-per-atom) and dpa rate. These analyses indicated that the fast neutron fluence will probably be the most limiting factor, with estimated fast fluence ranging between 3 x 10{sup 23} n/cm{sup 2} and up to 9 x 10{sup 23} n/cm{sup 2}, depending on the fuel characteristics. Therefore, different fuel forms were examined and the projected fast fluence and dpa compared. Using MOX fuel results in the highest fast fluence and dpa, about 10% higher than for the carbide or nitride fuel. The nitride fuel leads to the lowest dpa, for the same reactor power density, up to {approx} 4% and {approx} 7% lower than for the carbide and MOX fuel, respectively.

  12. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S.

    1992-01-01

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  13. EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TX | Department of Energy 2: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX February 18, 2009 EIS-0412: Notice of Intent to Prepare an Environmental Impact Statement Construction of the TX Energy, LLC, Industrial Gasification Facility near Beaumont, Texas

  14. Imperium/Lanzatech Syngas Fermentation Project - Biomass Gasification and Syngas Conditioning for Fermentation Evaluation: Cooperative Research and Development Final Report, CRADA Number CRD-12-474

    SciTech Connect (OSTI)

    Wilcox, E.

    2014-09-01

    LanzaTech and NREL will investigate the integration between biomass gasification and LanzaTech's proprietary gas fermentation process to produce ethanol and 2,3-butanediol. Using three feed materials (woody biomass, agricultural residue and herbaceous grass) NREL will produce syngas via steam indirect gasification and syngas conditioning over a range of process relevant operating conditions. The gasification temperature, steam-to-biomass ratio of the biomass feed into the gasifier, and several levels of syngas conditioning (based on temperature) will be varied to produce multiple syngas streams that will be fed directly to 10 liter seed fermenters operating with the Lanzatech organism. The NREL gasification system will then be integrated with LanzaTech's laboratory pilot unit to produce large-scale samples of ethanol and 2,3-butanediol for conversion to fuels and chemicals.

  15. Integrated Water Gas Shift Membrane Reactors Utilizing Novel, Non Precious Metal Mixed Matrix Membrane

    SciTech Connect (OSTI)

    Ferraris, John

    2013-09-30

    Nanoparticles of zeolitic imidazolate frameworks and other related hybrid materials were prepared by modifying published synthesis procedures by introducing bases, changing stoichiometric ratios, or adjusting reaction conditions. These materials were stable at temperatures >300 °C and were compatible with the polymer matrices used to prepare mixed- matrix membranes (MMMs). MMMs tested at 300 °C exhibited a >30 fold increase in permeability, compared to those measured at 35 °C, while maintaining H{sub 2}/CO{sub 2} selectivity. Measurements at high pressure (up to 30 atm) and high temperature (up to 300 °C) resulted in an increase in gas flux across the membrane with retention of selectivity. No variations in permeability were observed at high pressures at either 35 or 300 °C. CO{sub 2}-induced plasticization was not observed for Matrimid®, VTEC, and PBI polymers or their MMMs at 30 atm and 300 °C. Membrane surface modification by cross-linking with ethanol diamine resulted in an increase in H{sub 2}/CO{sub 2} selectivity at 35 °C. Spectrometric analysis showed that the cross-linking was effective to temperatures <150 °C. At higher temperatures, the cross-linked membranes exhibit a H{sub 2}/CO{sub 2} selectivity similar to the uncross-linked polymer. Performance of the polybenzimidazole (PBI) hollow fibers prepared at Santa Fe Science and Technology (SFST, Inc.) showed increased flux o to a flat PBI membrane. A water-gas shift reactor has been built and currently being optimized for testing under DOE conditions.

  16. Fixed-bed gasification research using US coals. Volume 15. Gasification of ''fresh'' Rosebud subbituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-09-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and government agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the fifteenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Rosebud subbituminous coal, from June 17, 1985 to June 24, 1985. 4 refs., 20 figs., 15 tabs.

  17. Biomass Gasification Technology Assessment: Consolidated Report

    SciTech Connect (OSTI)

    Worley, M.; Yale, J.

    2012-11-01

    Harris Group Inc. (HGI) was commissioned by the National Renewable Energy Laboratory to assess gasification and tar reforming technologies. Specifically, the assessments focused on gasification and tar reforming technologies that are capable of producing a syngas suitable for further treatment and conversion to liquid fuels. HGI gathered sufficient information to analyze three gasification and tar reforming systems. This report summarizes the equipment, general arrangement of the equipment, operating characteristics, and operating severity for each technology. The order of magnitude capital cost estimates are supported by a basis-of-estimate write-up, which is also included in this report. The report also includes Microsoft Excel workbook models, which can be used to design and price the systems. The models can be used to analyze various operating capacities and pressures. Each model produces a material balance, equipment list, capital cost estimate, equipment drawings and preliminary general arrangement drawings. Example outputs of each model are included in the Appendices.

  18. Process for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S.

    1992-01-01

    The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  19. Catalyst specificities in high pressure hydroprocessing of pyrolysis and gasification tars

    SciTech Connect (OSTI)

    Soltes, E.J.; Lin, S.C.K.; Sheu, Y.H.E.

    1987-04-01

    Over a period of several years, the Department of Forest Science at Texas A and M University has been conducting studies in the hydroprocessing (catalytic high pressure hydrotreating or hydrodeoxygenation accompanied by hydrocracking) of pyrolytic tars produced in biomass pyrolysis and gasification. Upgrading through hydroprocessing results in good yields of volatile hydrocarbon and phenolic products. This paper compares the performance of twenty different catalysts selected for hydroprocessing of a pine pyrolysis oil, describes the use of noble metal catalysts with tars produced from nine different biomass feedstocks (oil from pine pyrolysis and the tars from pine wood chip, pine plywood trim, pecan shell, peanut shell, sugarcane bagasse, corncob, rice hull, and cottonseed hull gasification), and compares the use of several catalysts in a trickle bed reactor for kinetic studies of the hyroprocessing reaction.

  20. Integral and Separate Effects Tests for Thermal Hydraulics Code Validation for Liquid-Salt Cooled Nuclear Reactors

    SciTech Connect (OSTI)

    Peterson, Per

    2012-10-30

    The objective of the 3-year project was to collect integral effects test (IET) data to validate the RELAP5-3D code and other thermal hydraulics codes for use in predicting the transient thermal hydraulics response of liquid salt cooled reactor systems, including integral transient response for forced and natural circulation operation. The reference system for the project is a modular, 900-MWth Pebble Bed Advanced High Temperature Reactor (PB-AHTR), a specific type of Fluoride salt-cooled High temperature Reactor (FHR). Two experimental facilities were developed for thermal-hydraulic integral effects tests (IETs) and separate effects tests (SETs). The facilities use simulant fluids for the liquid fluoride salts, with very little distortion to the heat transfer and fluid dynamics behavior. The CIET Test Bay facility was designed, built, and operated. IET data for steady state and transient natural circulation was collected. SET data for convective heat transfer in pebble beds and straight channel geometries was collected. The facility continues to be operational and will be used for future experiments, and for component development. The CIET 2 facility is larger in scope, and its construction and operation has a longer timeline than the duration of this grant. The design for the CIET 2 facility has drawn heavily on the experience and data collected on the CIET Test Bay, and it was completed in parallel with operation of the CIET Test Bay. CIET 2 will demonstrate start-up and shut-down transients and control logic, in addition to LOFC and LOHS transients, and buoyant shut down rod operation during transients. Design of the CIET 2 Facility is complete, and engineering drawings have been submitted to an external vendor for outsourced quality controlled construction. CIET 2 construction and operation continue under another NEUP grant. IET data from both CIET facilities is to be used for validation of system codes used for FHR modeling, such as RELAP5-3D. A set of

  1. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    SciTech Connect (OSTI)

    David Liscinsky

    2002-10-20

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated

  2. Production of Hydrogen from Underground Coal Gasification

    DOE Patents [OSTI]

    Upadhye, Ravindra S.

    2008-10-07

    A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

  3. Updraft Fixed Bed Gasification Aspen Plus Model

    Energy Science and Technology Software Center (OSTI)

    2007-09-27

    The updraft fixed bed gasification model provides predictive modeling capabilities for updraft fixed bed gasifiers, when devolatilization data is available. The fixed bed model is constructed using Aspen Plus, process modeling software, coupled with a FORTRAN user kinetic subroutine. Current updraft gasification models created in Aspen Plus have limited predictive capabilities and must be "tuned" to reflect a generalized gas composition as specified in literature or by the gasifier manufacturer. This limits the applicability ofmore » the process model.« less

  4. Indirectly heated fluidized bed biomass gasification using a latent heat ballast

    SciTech Connect (OSTI)

    Pletka, R.; Brown, R.; Smeenk, J.

    1998-12-31

    The objective of this study is to improve the heating value of gas produced during gasification of biomass fuels using an indirectly heated gasifier based on latent heat ballasting. The latent heat ballast consists of lithium fluoride salt encased in tubes suspended in the reactor. The lithium fluoride has a melting point that is near the desired gasification temperature. With the ballast a single reactor operating in a cyclic mode stores energy during a combustion phase and releases it during a pyrolysis phase. Tests were carried out in a fluidized bed reactor to evaluate the concept. The time to cool the reactor during the pyrolysis phase from 1,172 K (1,650 F) to 922 K (1,200 F) increased 102% by use of the ballast system. This extended pyrolysis time allowed 33% more biomass to be gasified during a cycle. Additionally, the total fuel fraction pyrolyzed to produce useful gas increased from 74--80%. Higher heating values of 14.2 to 16.6 MJ/Nm{sup 3} (382--445 Btu/scf) on a dry basis were obtained from the ballasted gasifier.

  5. World Gasification Database Now Available from DOE

    Broader source: Energy.gov [DOE]

    A database just released by the U.S. Department of Energy documents the worldwide growth of gasification, the expected technology of choice for future coal-based plants that produce power, fuels, and/or chemicals with near-zero emissions.

  6. Wabash River Coal Gasification Repowering Project

    SciTech Connect (OSTI)

    Amick, P.; Mann, G.J.; Cook, J.J.; Fisackerly, R.; Spears, R.C.

    1992-01-01

    The Destec gasification process features an oxygen-blown, two stage entrained flow gasifier. PSI will procure coal for the Project consistent with the design specification ranges of Destec's coal gasification facility. Destec's plant will be designed to accept coal with a maximum sulfur content of 5.9% (dry basis) and a minimum energy content of 13,5000 BTU/pound (moisture and ash free basis). PSI and Destec will test at least two other coals for significant periods during the demonstration period. In the Destec process, coal is ground with water to form a slurry. It is then pumped into a gasification vessel where oxygen is added to form a hot raw gas through partial combustion. Most of the noncarbon material in the coal melts and flows out the bottom of the vessel forming slag -- a black, glassy, non-leaching, sand-like material. Particulates, sulfur and other impurities are removed from the gas before combustion to make it acceptable fuel for the gas turbine. The synthetic fuel gas (syngas) is piped to a General Electric MS 7001F high temperature combustion turbine generator. A heat recovery steam generator recovers gas turbine exhaust heat to produce high pressure steam. This steam and the steam generated in the gasification process supply an existing steam turbine-generator. The plant will be designed to outperform air emission standards established by the Clean Air Act Amendments for the year 2000.

  7. Wabash River Coal Gasification Repowering Project

    SciTech Connect (OSTI)

    Amick, P.; Mann, G.J.; Cook, J.J.; Fisackerly, R.; Spears, R.C.

    1992-11-01

    The Destec gasification process features an oxygen-blown, two stage entrained flow gasifier. PSI will procure coal for the Project consistent with the design specification ranges of Destec`s coal gasification facility. Destec`s plant will be designed to accept coal with a maximum sulfur content of 5.9% (dry basis) and a minimum energy content of 13,5000 BTU/pound (moisture and ash free basis). PSI and Destec will test at least two other coals for significant periods during the demonstration period. In the Destec process, coal is ground with water to form a slurry. It is then pumped into a gasification vessel where oxygen is added to form a hot raw gas through partial combustion. Most of the noncarbon material in the coal melts and flows out the bottom of the vessel forming slag -- a black, glassy, non-leaching, sand-like material. Particulates, sulfur and other impurities are removed from the gas before combustion to make it acceptable fuel for the gas turbine. The synthetic fuel gas (syngas) is piped to a General Electric MS 7001F high temperature combustion turbine generator. A heat recovery steam generator recovers gas turbine exhaust heat to produce high pressure steam. This steam and the steam generated in the gasification process supply an existing steam turbine-generator. The plant will be designed to outperform air emission standards established by the Clean Air Act Amendments for the year 2000.

  8. 2013 Peer Review Presentations—Gasification

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Bioenergy Technologies Office hosted its 2013 Project Peer Review on May 20–24, 2015, at the Hilton Mark Center in Alexandria, Virginia. The presentations from the gasification session are available to view and download below. For detailed session descriptions and presentation titles, view the 2013 Project Peer Review Program Booklet.

  9. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W.

    1981-01-01

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  10. THE PRODUCTION OF SYNGAS VIA HIGH TEMPERATURE ELECTROLYSIS AND BIO-MASS GASIFICATION

    SciTech Connect (OSTI)

    M. G. McKellar; G. L. Hawkes; J. E. O'Brien

    2008-11-01

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to improve the hydrogen production efficiency of the steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon dioxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K.

  11. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Breakout Session 2A-Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Santosh Gangwal, Director-Business Development, Energy Technologies, Southern Research Institute gangwal_biomass_2014.pdf (1.36

  12. DOE Selects Gasification Technology Research Projects for Funding |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Gasification Technology Research Projects for Funding DOE Selects Gasification Technology Research Projects for Funding July 14, 2015 - 11:15am Addthis The Department of Energy's (DOE) National Energy Technology Laboratory (NETL) has selected seven projects to receive funding through NETL's Gasification System Program. This program supports a wide range of research and development activities aimed at improving fuel and product versatility, efficiency, and economics of

  13. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, D.C.; DaPrato, P.L.; Gouker, T.R.; Knoer, P.

    1984-07-06

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone with an aqueous solution having a pH above 12.0 at a temperature between 65/sup 0/C and 110/sup 0/C for a period of time sufficient to remove bitumens from the coal into said aqueous solution, and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m/sup 3/. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step. 2 figs., 1 tab.

  14. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, Dolores C.; DaPrato, Philip L.; Gouker, Toby R.; Knoer, Peter

    1986-01-01

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

  15. Gas turbine power generation from biomass gasification

    SciTech Connect (OSTI)

    Paisley, M.A.; Litt, R.D.; Overend, R.P.; Bain, R.L.

    1994-12-31

    The Biomass Power Program of the US Department of Energy (DOE) has as a major goal the development of cost-competitive technologies for the production of power from renewable biomass crops. The gasification of biomass provides the potential to meet this goal by efficiently and economically producing a renewable source of a clean gaseous fuel suitable for use in high efficiency gas turbines or as a substitute fuel in other combustion devices such as boilers, kilns, or other natural gas fired equipment. This paper discusses the development of the use of the Battelle high-throughput gasification process for power generation systems. Projected process economics are presented along with a description of current experimental operations coupling a gas turbine power generation system to the research scale gasifier.

  16. EIS-0383: Southern Company's Orlando Gasification Project, Orlando, FL

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's decision to provide cost-shared funding for construction, design, and operation of a new gasification plant in Orlando, Florida.

  17. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Breakout Session 2A-Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, ...

  18. Potential trace element emissions from the gasification of Illinois...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; ASHES; CHEMICAL COMPOSITION; COAL; COAL GASIFICATION PLANTS; ENVIRONMENTAL EFFECTS; ABSORPTION SPECTROSCOPY; ACTIVATION ANALYSIS; AIR POLLUTION...

  19. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter; Salvador, Louis A.

    1981-01-01

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  20. GASIFICATION BASED BIOMASS CO-FIRING

    SciTech Connect (OSTI)

    Babul Patel; Kevin McQuigg; Robert Toerne; John Bick

    2003-01-01

    Biomass gasification offers a practical way to use this widespread fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be used as a supplemental fuel in an existing utility boiler. This strategy of co-firing is compatible with a variety of conventional boilers including natural gas and oil fired boilers, pulverized coal fired conventional and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a wider selection of biomass as fuel and providing opportunity in reduction of carbon dioxide emissions to the atmosphere through the commercialization of this technology. This study evaluated two plants: Wester Kentucky Energy Corporation's (WKE's) Reid Plant and TXU Energy's Monticello Plant for technical and economical feasibility. These plants were selected for their proximity to large supply of poultry litter in the area. The Reid plant is located in Henderson County in southwest Kentucky, with a large poultry processing facility nearby. Within a fifty-mile radius of the Reid plant, there are large-scale poultry farms that generate over 75,000 tons/year of poultry litter. The local poultry farmers are actively seeking environmentally more benign alternatives to the current use of the litter as landfill or as a farm spread as fertilizer. The Monticello plant is located in Titus County, TX near the town of Pittsburgh, TX, where again a large poultry processor and poultry farmers in the area generate over 110,000 tons/year of poultry litter. Disposal of this litter in the area is also a concern. This project offers a model opportunity to demonstrate the feasibility of biomass co-firing and at the same time eliminate poultry litter

  1. Biomass Gasification Research Facility Final Report

    SciTech Connect (OSTI)

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-02GO12024 and DE-FC36-03GO13175) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. The primary objectives of Cooperative Agreement DE-FC36-02GO12024 were the selection, acquisition, and application of a suite of gas analyzers capable of providing near real-time gas analyses to suitably conditioned syngas streams. A review was conducted of sampling options, available analysis technologies, and commercially available analyzers, that could be successfully applied to the challenging task of on-line syngas characterization. The majority of thermochemical process streams comprise multicomponent gas mixtures that, prior to crucial, sequential cleanup procedures, include high concentrations of condensable species, multiple contaminants, and are often produced at high temperatures and pressures. Consequently, GTI engaged in a concurrent effort under Cooperative Agreement DE-FC36-03GO13175 to develop the means to deliver suitably prepared, continuous streams of extracted syngas to a variety of on-line gas analyzers. The review of candidate analysis technology

  2. Experimental development of a multi-solid fluidized bed reactor concept

    SciTech Connect (OSTI)

    Litt, R.D.; Paisley, M.A.; Tewksbury, T.L.

    1990-02-01

    Battelle's Columbus Division is developing a coal mild gasification process based upon the Multi-Solid Fluidized bed reactor system to produce high quality liquid and gaseous products. This process uses 2-stages to gasify coal at high throughputs to produce a range of products in compact reactors without requiring an oxygen plant. 8 refs., 14 figs., 12 tabs.

  3. Gasification Characteristics of Coal/Biomass Mixed Fuels

    SciTech Connect (OSTI)

    Mitchell, Reginald

    2013-09-30

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle

  4. Fluidized-bed combustion and gasification of biomass

    SciTech Connect (OSTI)

    LePori, W.A.; Anthony, R.G.; Lalk, T.R.; Craig, J.D.

    1981-01-01

    A 0.61 meter (2 ft) diameter fluidized-bed combustion reactor was used for tests on direct combustion of cotton gin trash. Raw gin trash was continuously augered into the unit with fuel and air rates set to maintain bed temperatures of 760/sup 0/ to 816/sup 0/C (1400/sup 0/ to 1500/sup 0/F). Particulate emissions in the hot stack gases were measured and found to be lower than federal standards for incinerators. Mild steel and stainless alloy samples were placed in the hot stack gas stream to study corrosion and erosion of materials. High rates of potassium, calcium, and sodium deposits accumulated on the samples, and high erosion rates were found. A 0.3 meter (13 in) diameter fluidized-bed gasifier was used to convert raw gin trash into a combustible gas with bed temperatures between 683/sup 0/C and 881/sup 0/C (1261/sup 0/F and 1618/sup 0/F). By limiting the amount of oxygen compared to the fuel feed, only partial combustion occurs, producing heat and endothermic gasification chemical reactions. The combustible gas was composed primarily of carbon monoxide and hydrogen. It had a heating value ranging from 3.40 to 4.82 M Joules per standard cubic meter (98 to 142 Btu/scf), and about 50 percent of the heat value of the gin trash was converted into this low energy gas.

  5. MANTA. An Integral Reactor Physics Experiment to Infer the Neutron Capture Cross Sections of Actinides and Fission Products in Fast and Epithermal Spectra

    SciTech Connect (OSTI)

    Youinou, Gilles Jean-Michel

    2015-10-01

    neutron irradiation allows to infer energy-integrated neutron cross sections, i.e. ∫₀σ(E)φ(E)dE, where φ(E) is the neutron flux “seen” by the sample. This approach, which is usually defined and led by reactor physicists, is referred to as integral and is the object of this report. These two sources of information, i.e. differential and integral, are complementary and are used by the nuclear physicists in charge of producing the evaluated nuclear data files used by the nuclear community (ENDF, JEFF…). The generation of accurate nuclear data files requires an iterative process involving reactor physicists and nuclear data evaluators. This experimental program has been funded by the ATR National Scientific User Facility (ATR-NSUF) and by the DOE Office of Science in the framework of the Recovery Act. It has been given the name MANTRA for Measurement of Actinides Neutron TRAnsmutation.

  6. Coal gasification. Quarterly report, July-September 1979

    SciTech Connect (OSTI)

    1980-07-01

    The status of 18 coal gasification pilot plants or supporting projects supported by US DOE is reviewed under the following headings: company involved, location, contract number, funding, gasification process, history, process description, flowsheet and progress in the July-September 1979 quarter. (LTN)

  7. Methods for sequestering carbon dioxide into alcohols via gasification fermentation

    DOE Patents [OSTI]

    Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

    2013-11-26

    The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

  8. Gasification of refuse derived fuel in the Battelle high throughput gasification system

    SciTech Connect (OSTI)

    Paisley, M.A.; Creamer, K.S.; Tweksbury, T.L.; Taylor, D.R. )

    1989-07-01

    This report presents the results of an experimental program to demonstrate the suitability of the Battelle High Throughput Gasification Process to non-wood biomass fuels. An extensive data base on wood gasification was generated during a multi-year experimental program. This data base and subsequent design and economic analysis activities led to the discussion to study the gasification character of other fuels. The specific fuel studied was refuse derived fuel (RDF) which is a prepared municipal solid waste (MSW). The use of RDF, while providing a valuable fuel, can also provide a solution to MSW disposal problems. Gasification of MSW provides advantages over land fill or mass burn technology since a more usable form of energy, medium Btu gas, is produced. Land filling of wastes produces no usable products and mass burning while greatly reducing the volume of wastes for disposal can produce only steam. This steam must be used on site or very nearby this limiting the potential locations for mass burn facilities. Such a gas, if produced from currently available supplies of MSW, can contribute 2 quads to the US energy supply. 3 refs., 12 figs., 7 tabs.

  9. Green wood chip gasification due under boiler

    SciTech Connect (OSTI)

    Not Available

    1981-12-14

    It is reported that Applied Engineering Co. has begun installing the first greenwood chip gasification system to be used in conjunction with fossil fuels at Florida Power Corp's Suwannee generating station near Lake City, Florida. The unit's design capacity is about 37 MMBTU/hour and will provide as much as 25% of the fuel requirements of a large utility type natural gas boiler under normal load conditions. The system is expected to back out as much as 1 million gal/year of fuel oil at a savings of approximately $850,000/year.

  10. Vaporization and gasification of hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Davies, H.S.; Garstang, J.H.; Timmins, C.

    1983-08-23

    Heavy hydrocarbon feedstocks, e.g. gas oils, are vaporized and subsequently gasified at high temperatures without pyrolytic degradation by first admixing the hydrocarbon with a hot gaseous reactant, e.g. product gas or steam, to bring the temperature of the mixture above that of the dew point of the hydrocarbon and thereafter raising the temperature of the mixture to above that at which pyrolysis of the hydrocarbon begins to be significant by admixture with further quantities of the reactant which are superheated thereby to bring the temperature of the resultant mixture to that required for effecting a catalytic gasification reaction.

  11. ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING

    SciTech Connect (OSTI)

    Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

    2002-06-01

    Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. The technical and economic performances of the selected processes were evaluated using computer models and available literature. Using these results, the carbon sequestration potential of the three technologies was then evaluated. The results of these evaluations are given in this final report.

  12. ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING

    SciTech Connect (OSTI)

    Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

    2002-04-01

    Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. During this reporting period, the technical and economic performances of the selected processes were evaluated using computer models and available literature. The results of these evaluations are summarized in this report.

  13. Coal gasification. (Latest citations from the EI compendex*plus database). Published Search

    SciTech Connect (OSTI)

    1998-03-01

    The bibliography contains citations concerning the development and assessment of coal gasification technology. Combined-cycle gas turbine power plants are reviewed. References also discuss dry-feed gasification, gas turbine interface, coal gasification pilot plants, underground coal gasification, gasification with nuclear heat, and molten bath processes. Clean-coal based electric power generation and environmental issues are examined. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  14. Integrated analysis of the {open_quotes}sponge iron reactor and fuel cell system{close_quotes}

    SciTech Connect (OSTI)

    Lehrhofer, J.; Ghaemi, M.; Wernigg, H.

    1996-12-31

    The system Sponge Iron Reactor/Fuel Cell (SIR/FC) is investigated from the ecological and technical aspects and also the pre-conversion energy chain as a part of the natural gas fuel cycle is analyzed. What are the decisive characteristics of a sponge iron reactor or the basic process cycle sponge iron/hydrogen/iron oxide? This process cycle offers a simple possibility to store the energy of synthesis gases in the form of sponge iron and at the same time to reform and condition these synthesis gases. As {open_quote}product{close_quote} of this energy storage one receives pure hydrogen which is intended for the running of fuel cells.

  15. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect (OSTI)

    Samuel S. Tam

    2002-05-01

    The goal of this series of design and estimating efforts was to start from the as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project and to develop optimized designs for several coal and petroleum coke IGCC power and coproduction projects. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This unoptimized plant has a thermal efficiency of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW. This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal and coke-fueled power plants. This side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, showed their similarity both in design and cost (1,318 $/kW for the

  16. Thermochemical Process Integration, Scale-Up, and Piloting |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Read more The NREL Research Gasifier (NRG) is an integrated gasification system that converts solid biomass to clean, compressed syngas (H2 and CO) in one convenient and compact ...

  17. Method for in situ gasification of a subterranean coal bed

    DOE Patents [OSTI]

    Shuck, Lowell Z.

    1977-05-31

    The method of the present invention relates to providing controlled directional bores in subterranean earth formations, especially coal beds for facilitating in situ gasification operations. Boreholes penetrating the coal beds are interconnected by laser-drilled bores disposed in various arrays at selected angles to the major permeability direction in the coal bed. These laser-drilled bores are enlarged by fracturing prior to the gasification of the coal bed to facilitate the establishing of combustion zones of selected configurations in the coal bed for maximizing the efficiency of the gasification operation.

  18. Fixed-bed gasification research using US coals. Volume 2. Gasification of Jetson bituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-03-31

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report describes the gasification testing of Jetson bituminous coal. This Western Kentucky coal was gasified during an initial 8-day and subsequent 5-day period. Material flows and compositions are reported along with material and energy balances. Operational experience is also described. 4 refs., 24 figs., 17 tabs.

  19. Savannah River reactor process water heat exchanger tube structural integrity margin Task Number 92-005-1

    SciTech Connect (OSTI)

    Mertz, G.E.; Barnes, D.M.; Sindelar, R.L.

    1992-02-01

    Twelve process water heat exchangers are designed to remove heat generated in the reactor tank. Each heat exchanger has approximately 9000, 1/2 inch diameter {times} 0.049 inches thick tubes. Minimum structural tubing requirements and the leak rate through postulated tubing defects are developed in this report A comparison of the structural requirements and the defect size calculated to produce leak rates of 0.5 lbs./day demonstrate adequate structural margins against gross tube rupture. Commercial nuclear experience with pressurized water reactor (PWR) steam generator plugging criteria are used for guidance in performing this analysis. It is important to note that the SRS reactors are low energy systems with normal operating pressures of 203 psig at 130{degree}F while the PWR is a high energy system with operating pressures near 2200 psig at 600{degree}F. Clearly the PVM steam generator has loadings which are more severe than the SRS heat exchangers. Consistent with the Regulatory Guide 1.121 criteria both wastage (wall thinning) and cracking are addressed. Structural limits on wall thinning and crack size are developed to preclude gross rupture. ASME Section XI criteria, with the factors of safety recommended by Regulatory Guide 1.121 are used to develop the allowable crack size criteria. Normal operating conditions (pressure, dead weight, and hydraulic drag) are considered with seismic and water hammer accident conditions. Both the wall thinning and crack size criteria are developed for the end-of-evaluation period. Allowances for corrosion, wear, or crack growth have not been included in this analysis Structurally, the tubing is over designed and can tolerate large defects with adequate margins against gross rupture. The structural margins of heat exchanger tubing are evident by contrasting the tubing`s structural capacity, per the ASME Code, with its operating conditions/configuration.

  20. Savannah River reactor process water heat exchanger tube structural integrity margin Task Number 92-005-1

    SciTech Connect (OSTI)

    Mertz, G.E.; Barnes, D.M.; Sindelar, R.L.

    1992-02-01

    Twelve process water heat exchangers are designed to remove heat generated in the reactor tank. Each heat exchanger has approximately 9000, 1/2 inch diameter {times} 0.049 inches thick tubes. Minimum structural tubing requirements and the leak rate through postulated tubing defects are developed in this report A comparison of the structural requirements and the defect size calculated to produce leak rates of 0.5 lbs./day demonstrate adequate structural margins against gross tube rupture. Commercial nuclear experience with pressurized water reactor (PWR) steam generator plugging criteria are used for guidance in performing this analysis. It is important to note that the SRS reactors are low energy systems with normal operating pressures of 203 psig at 130{degree}F while the PWR is a high energy system with operating pressures near 2200 psig at 600{degree}F. Clearly the PVM steam generator has loadings which are more severe than the SRS heat exchangers. Consistent with the Regulatory Guide 1.121 criteria both wastage (wall thinning) and cracking are addressed. Structural limits on wall thinning and crack size are developed to preclude gross rupture. ASME Section XI criteria, with the factors of safety recommended by Regulatory Guide 1.121 are used to develop the allowable crack size criteria. Normal operating conditions (pressure, dead weight, and hydraulic drag) are considered with seismic and water hammer accident conditions. Both the wall thinning and crack size criteria are developed for the end-of-evaluation period. Allowances for corrosion, wear, or crack growth have not been included in this analysis Structurally, the tubing is over designed and can tolerate large defects with adequate margins against gross rupture. The structural margins of heat exchanger tubing are evident by contrasting the tubing's structural capacity, per the ASME Code, with its operating conditions/configuration.

  1. Fixed-bed gasification research using US coals. Volume 11. Gasification of Minnesota peat. [Peat pellets and peat sods

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a coooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the eleventh volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of peat pellets and peat sods during 3 different test periods. 2 refs., 20 figs., 13 tabs.

  2. Carbonate fuel cell system with thermally integrated gasification

    DOE Patents [OSTI]

    Steinfeld, G.; Meyers, S.J.; Lee, A.

    1996-09-10

    A fuel cell system is described which employs a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell. 2 figs.

  3. Carbonate fuel cell system with thermally integrated gasification

    DOE Patents [OSTI]

    Steinfeld, George; Meyers, Steven J.; Lee, Arthur

    1996-01-01

    A fuel cell system employing a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell.

  4. Two-stage coal gasification and desulfurization apparatus

    DOE Patents [OSTI]

    Bissett, Larry A.; Strickland, Larry D.

    1991-01-01

    The present invention is directed to a system which effectively integrates a two-stage, fixed-bed coal gasification arrangement with hot fuel gas desulfurization of a first stream of fuel gas from a lower stage of the two-stage gasifier and the removal of sulfur from the sulfur sorbent regeneration gas utilized in the fuel-gas desulfurization process by burning a second stream of fuel gas from the upper stage of the gasifier in a combustion device in the presence of calcium-containing material. The second stream of fuel gas is taken from above the fixed bed in the coal gasifier and is laden with ammonia, tar and sulfur values. This second stream of fuel gas is burned in the presence of excess air to provide heat energy sufficient to effect a calcium-sulfur compound forming reaction between the calcium-containing material and sulfur values carried by the regeneration gas and the second stream of fuel gas. Any ammonia values present in the fuel gas are decomposed during the combustion of the fuel gas in the combustion chamber. The substantially sulfur-free products of combustion may then be combined with the desulfurized fuel gas for providing a combustible fluid utilized for driving a prime mover.

  5. Study of catalysis of coal gasification at elevated pressures...

    Office of Scientific and Technical Information (OSTI)

    Study of catalysis of coal gasification at elevated pressures. Evaluation of 20 compounds at 850sup 0C Citation Details In-Document Search Title: Study of catalysis of coal ...

  6. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review

    Office of Energy Efficiency and Renewable Energy (EERE)

    This independent review report assesses the 2009 state-of-the-art and 2020 projected capital cost, energy efficiency, and levelized cost for hydrogen production from biomass via gasification.

  7. Energy Department Announces New Investments in Gasification Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    WASHINGTON--Today, as part of the Administration’s all-of-the-above energy approach, the Department of Energy has selected four projects to receive funding for next-generation gasification systems...

  8. GASIFICATION BASED BIOMASS CO-FIRING - PHASE I

    SciTech Connect (OSTI)

    Babul Patel; Kevin McQuigg; Robert F. Toerne

    2001-12-01

    Biomass gasification offers a practical way to use this locally available fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be fed directly into the boiler. This strategy of co-firing is compatible with variety of conventional boilers including natural gas fired boilers as well as pulverized coal fired and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a reduction in the primary fossil fuel consumption in the boiler and thereby reducing the greenhouse gas emissions to the atmosphere.

  9. Integrated Removal of NOx with Carbon Monoxide as Reductant, and Capture of Mercury in a Low Temperature Selective Catalytic and Adsorptive Reactor

    SciTech Connect (OSTI)

    Neville Pinto; Panagiotis Smirniotis; Stephen Thiel

    2010-08-31

    Coal will likely continue to be a dominant component of power generation in the foreseeable future. This project addresses the issue of environmental compliance for two important pollutants: NO{sub x} and mercury. Integration of emission control units is in principle possible through a Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR) in which NO{sub x} removal is achieved in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The capture of mercury is integrated into the same process unit. Such an arrangement would reduce mercury removal costs significantly, and provide improved control for the ultimate disposal of mercury. The work completed in this project demonstrates that the use of CO as a reductant in LTSCR is technically feasible using supported manganese oxide catalysts, that the simultaneous warm-gas capture of elemental and oxidized mercury is technically feasible using both nanostructured chelating adsorbents and ceria-titania-based materials, and that integrated removal of mercury and NO{sub x} is technically feasible using ceria-titania-based materials.

  10. Production and gasification tests of coal fines/coal tar extrudate. Final report June 1982-December 1983

    SciTech Connect (OSTI)

    Furman, A.; Rib, D.; Smith, D.; Waslo, D.

    1984-01-01

    Gasification is a fuels conversion technology that permits the production of clean synthetic gas from coal and other carbonaceous fuels. Of the various gasifier types, however, the fixed bed is the only system currently being offered on a commercial basis. While this reactor type offers proven performance in terms of reliability and thermal efficiency, it requires a sized feedstock. This means that up to 30% of the incoming run-of-mine coal could be rejected as fines. Direct extrusion of this - 1/8-inch coal fines fraction with a tar binder offers a potentially attractive solution to this problem by consolidating the fines and, at the same time, providing a feed mechanism to the pressurized reactor. Work is described on a recently completed extrudate evaluation program conducted at the General Electric Research and Development Center in Schenectady under GRI and NYSERDA sponsorship. A 6-inch, single screw extruder was used to produce 88 tons of Illinois No. 6 coal extrudate with tar binder, which was then successfully gasified in General Electric's 1-ton/hr, Process Evaluation Facility (PEF) scale, fixed-bed reactor. Performance data on the extrusion process and on gasification testing are presented. The test results indicate that the extrudate makes a satisfactory gasifier feedstock in terms of both thermal and mechanical performance.

  11. Method for control of subsurface coal gasification

    DOE Patents [OSTI]

    Komar, Charles A.

    1976-12-14

    The burn front in an in situ underground coal gasification operation is controlled by utilizing at least two parallel groups of vertical bore holes disposed in the coalbed at spaced-apart locations in planes orthogonal to the plane of maximum permeability in the coalbed. The combustion of the coal is initiated in the coalbed adjacent to one group of the bore holes to establish a combustion zone extending across the group while the pressure of the combustion supporting gas mixture and/or the combustion products is regulated at each well head by valving to control the burn rate and maintain a uniform propagation of the burn front between the spaced-apart hole groups to gasify virtually all the coal lying therebetween.

  12. Metallic heat exchangers for coal gasification

    SciTech Connect (OSTI)

    Natesan, K.

    1984-07-01

    A high-temperature corrosion program is being conducted to evaluate the corrosion behavior of selected metallic alloys and coatings in mixed-gas atmospheres for application in heat recovery systems of coal gasification schemes. The experiments conducted with internally air-cooled specimens have established three key variables, namely the gas temperature, metal temperature, and gas chemistry. In addition, the alloy chemistry and exposure time have a strong influence on the corrosion scale morphologies and metal recession rates. The results showed that the scale growth in carbon steel and low- to medium-chromium steels is predominantly linear with time. Selection of these materials will be primarily based upon acceptable corrosion wastage rate. On the other hand, high-chromium alloys can develop thin oxide scales resulting in negligible wastage via corrosion, but are susceptible to accelerated corrosion in mixed-gas atmospheres. 6 references, 12 figures, 4 tables.

  13. Biomass Gasification Research Facility Final Report

    SciTech Connect (OSTI)

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-03GO13175 and DE-FC36-02GO12024) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. This multi-year effort to develop methods to effectively monitor gaseous species produced in thermochemical process streams resulted in a sampling and analysis approach that is continuous, sensitive, comprehensive, accurate, reliable, economical, and safe. The improved approach for sampling thermochemical processes that GTI developed and demonstrated in its series of field demonstrations successfully provides continuous transport of vapor-phase syngas streams extracted from the main gasification process stream to multiple, commercially available analyzers. The syngas stream is carefully managed through multiple steps to successfully convey it to the analyzers, while at the same time bringing the stream to temperature and pressure conditions that are compatible with the analyzers. The primary principle that guides the sample transport is that throughout the entire sampling train, the temperature of the syngas stream is maintained above the maximum condensation temperature

  14. Advanced Gasification By-Product Utilization

    SciTech Connect (OSTI)

    Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

    2006-08-31

    With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this

  15. Heat exchanger for coal gasification process

    DOE Patents [OSTI]

    Blasiole, George A.

    1984-06-19

    This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

  16. A Thermo-Mechanical Analysis for a Nozzle Header of a Once-Through Steam Generator Designed for an Integral Reactor

    SciTech Connect (OSTI)

    Kim, YongWan; Kim, Dong Ok; Lee, Jae Seon; Kim, Jong In; Zee, Sung Quun [Korea Atomic Energy Research Institute, PO Box 105, YuSong, Taejon, 305-600 (Korea, Republic of)

    2004-07-01

    Thermo-mechanical behavior of the nozzle header of a steam generator developed for an integral reactor was investigated using experimental and finite element methods. The nozzle feedwater header suffers from severe thermal transient loadings during the operation of the nuclear reactor. The nozzle header is exposed to the low temperature inlet feedwater and the high temperature outlet superheated steam. The other side of the nozzle header is in contacts with the high temperature primary coolant. This temperature gradient results in high thermal stresses in the nozzle header structure. The thermal transient loading has been simulated in the test loop. The thermo-hydraulic parameters of the primary and the secondary system were controlled according to the operation mode programmed in the computer. Strain gauges and thermocouples attached at the highly stressed region monitored the thermo-mechanical behavior of the nozzle header. In parallel to the experimental study, the transient behavior of the nozzle header was simulated utilizing a commercial finite element code. The fluid temperature and the pressure obtained from the test loop were used for the input of the finite element analysis. As a result of this investigation, the thermo-mechanical load carrying capacity of the developed steam generator nozzle header was proved numerically and experimentally. (authors)

  17. Gasification Studies Task 4 Topical Report

    SciTech Connect (OSTI)

    Whitty, Kevin; Fletcher, Thomas; Pugmire, Ronald; Smith, Philip; Sutherland, James; Thornock, Jeremy; Boshayeshi, Babak; Hunsacker, Isaac; Lewis, Aaron; Waind, Travis; Kelly, Kerry

    2014-02-01

    A key objective of the Task 4 activities has been to develop simulation tools to support development, troubleshooting and optimization of pressurized entrained-flow coal gasifiers. The overall gasifier models (Subtask 4.1) combine submodels for fluid flow (Subtask 4.2) and heat transfer (Subtask 4.3) with fundamental understanding of the chemical processes (Subtask 4.4) processes that take place as coal particles are converted to synthesis gas and slag. However, it is important to be able to compare predictions from the models against data obtained from actual operating coal gasifiers, and Subtask 4.6 aims to provide an accessible, non-proprietary system, which can be operated over a wide range of conditions to provide well-characterized data for model validation. Highlights of this work include: • Verification and validation activities performed with the Arches coal gasification simulation tool on experimental data from the CANMET gasifier (Subtask 4.1). • The simulation of multiphase reacting flows with coal particles including detailed gas-phase chemistry calculations using an extension of the one-dimensional turbulence model’s capability (Subtask 4.2). • The demonstration and implementation of the Reverse Monte Carlo ray tracing (RMCRT) radiation algorithm in the ARCHES code (Subtask 4.3). • Determination of steam and CO{sub 2} gasification kinetics of bituminous coal chars at high temperature and elevated pressure under entrained-flow conditions (Subtask 4.4). In addition, attempts were made to gain insight into the chemical structure differences between young and mature coal soot, but both NMR and TEM characterization efforts were hampered by the highly reacted nature of the soot. • The development, operation, and demonstration of in-situ gas phase measurements from the University of Utah’s pilot-scale entrained-flow coal gasifier (EFG) (Subtask 4.6). This subtask aimed at acquiring predictable, consistent performance and characterizing the

  18. Subtask 4.2 - Coal Gasification Short Course

    SciTech Connect (OSTI)

    Kevin Galbreath

    2009-06-30

    Major utilities, independent power producers, and petroleum and chemical companies are intent on developing a fleet of gasification plants primarily because of high natural gas prices and the implementation of state carbon standards, with federal standards looming. Currently, many projects are being proposed to utilize gasification technologies to produce a synthesis gas or fuel gas stream for the production of hydrogen, liquid fuels, chemicals, and electricity. Financing these projects is challenging because of the complexity, diverse nature of gasification technologies, and the risk associated with certain applications of the technology. The Energy & Environmental Research Center has developed a gasification short course that is designed to provide technical personnel with a broad understanding of gasification technologies and issues, thus mitigating the real or perceived risk associated with the technology. Based on a review of research literature, tutorial presentations, and Web sites on gasification, a short course presentation was prepared. The presentation, consisting of about 500 PowerPoint slides, provides at least 7 hours of instruction tailored to an audience's interests and needs. The initial short course is scheduled to be presented September 9 and 10, 2009, in Grand Forks, North Dakota.

  19. AN INTEGRAL REACTOR PHYSICS EXPERIMENT TO INFER ACTINIDE CAPTURE CROSS-SECTIONS FROM THORIUM TO CALIFORNIUM WITH ACCELERATOR MASS SPECTROMETRY

    SciTech Connect (OSTI)

    G. Youinou; M. Salvatores; M. Paul; R. Pardo; G. Palmiotti; F. Kondev; G. Imel

    2010-04-01

    The principle of the proposed experiment is to irradiate very pure actinide samples in the Advanced Test Reactor (ATR) at INL and, after a given time, determine the amount of the different transmutation products. The determination of the nuclide densities before and after neutron irradiation will allow inference of effective neutron capture cross-sections. This approach has been used in the past and the novelty of this experiment is that the atom densities of the different transmutation products will be determined using the Accelerator Mass Spectroscopy (AMS) technique at the ATLAS facility located at ANL. It is currently planned to irradiate the following isotopes: 232Th, 235U, 236U, 238U, 237Np, 238Pu, 239Pu, 240Pu, 241Pu, 242Pu, 241Am, 243Am and 248Cm.

  20. Technical Report Cellulosic Based Black Liquor Gasification and Fuels Plant Final Technical Report

    SciTech Connect (OSTI)

    Fornetti, Micheal; Freeman, Douglas

    2012-10-31

    The Cellulosic Based Black Liquor Gasification and Fuels Plant Project was developed to construct a black liquor to Methanol biorefinery in Escanaba, Michigan. The biorefinery was to be co-located at the existing pulp and paper mill, NewPage’s Escanaba Paper Mill and when in full operation would: • Generate renewable energy for Escanaba Paper Mill • Produce Methanol for transportation fuel of further refinement to Dimethyl Ether • Convert black liquor to white liquor for pulping. Black liquor is a byproduct of the pulping process and as such is generated from abundant and renewable lignocellulosic biomass. The biorefinery would serve to validate the thermochemical pathway and economic models for black liquor gasification. It was a project goal to create a compelling new business model for the pulp and paper industry, and support the nation’s goal for increasing renewable fuels production and reducing its dependence on foreign oil. NewPage Corporation planned to replicate this facility at other NewPage Corporation mills after this first demonstration scale plant was operational and had proven technical and economic feasibility. An overview of the process begins with black liquor being generated in a traditional Kraft pulping process. The black liquor would then be gasified to produce synthesis gas, sodium carbonate and hydrogen sulfide. The synthesis gas is then cleaned with hydrogen sulfide and carbon dioxide removed, and fed into a Methanol reactor where the liquid product is made. The hydrogen sulfide is converted into polysulfide for use in the Kraft pulping process. Polysulfide is a known additive to the Kraft process that increases pulp yield. The sodium carbonate salts are converted to caustic soda in a traditional recausticizing process. The caustic soda is then part of the white liquor that is used in the Kraft pulping process. Cellulosic Based Black Liquor Gasification and Fuels Plant project set out to prove that black liquor gasification could

  1. Numerical Study of Coal Gasification Using Eulerian-Eulerian Multiphase Model

    SciTech Connect (OSTI)

    Shi, S.; Guenther, C.; Orsino, S.

    2007-09-01

    Gasification converts the carbon-containing material into a synthesis gas (syngas) which can be used as a fuel to generate electricity or used as a basic chemical building block for a large number of uses in the petrochemical and refining industries. Based on the mode of conveyance of the fuel and the gasifying medium, gasification can be classified into fixed or moving bed, fluidized bed, and entrained flow reactors. Entrained flow gasifiers normally feature dilute flow with small particle size and can be successfully modeled with the Discrete Phase Method (DPM). For the other types, the Eulerian-Eulerian (E-E) or the so called two-fluid multiphase model is a more appropriate approach. The E-E model treats the solid phase as a distinct interpenetrating granular fluid and it is the most general-purposed multi-fluid model. This approach provides transient, three-dimensional, detailed information inside the reactor which would otherwise be unobtainable through experiments due to the large scale, high pressure and/or temperature. In this paper, a transient, three-dimensional model of the Power Systems Development Facility (PSDF) transport gasifier will be presented to illustrate how Computational Fluid Dynamics (CFD) can be used for large-scale complicated geometry with detailed physics and chemistry. In the model, eleven species are included in the gas phase while four pseudo-species are assumed in the solid phase. A total of sixteen reactions, both homogeneous (involving only gas phase species) and heterogeneous (involving species in both gas and solid phases), are used to model the coal gasification chemistry. Computational results have been validated against PSDF experimental data from lignite to bituminous coals under both air and oxygen blown conditions. The PSDF gasifier geometry was meshed with about 70,000, hexahedra-dominated cells. A total of six cases with different coal, feed gas, and/or operation conditions have been performed. The predicted and

  2. Cyclic flow underground coal gasification process

    DOE Patents [OSTI]

    Bissett, Larry A.

    1978-01-01

    The present invention is directed to a method of in situ coal gasification for providing the product gas with an enriched concentration of carbon monoxide. The method is practiced by establishing a pair of combustion zones in spaced-apart boreholes within a subterranean coal bed and then cyclically terminating the combustion in the first of the two zones to establish a forward burn in the coal bed so that while an exothermic reaction is occurring in the second combustion zone to provide CO.sub.2 -laden product gas, an endothermic CO-forming reaction is occurring in the first combustion zone between the CO.sub.2 -laden gas percolating thereinto and the hot carbon in the wall defining the first combustion zone to increase the concentration of CO in the product gas. When the endothermic reaction slows to a selected activity the roles of the combustion zones are reversed by re-establishing an exothermic combustion reaction in the first zone and terminating the combustion in the second zone.

  3. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect (OSTI)

    Sheldon Kramer

    2003-09-01

    This project developed optimized designs and cost estimates for several coal and petroleum coke IGCC coproduction projects that produced hydrogen, industrial grade steam, and hydrocarbon liquid fuel precursors in addition to power. The as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project was the starting point for this study that was performed by Bechtel, Global Energy and Nexant under Department of Energy contract DE-AC26-99FT40342. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This non-optimized plant has a thermal efficiency to power of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW.1 This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for

  4. Advanced Hydrogen Transport Membrane for Coal Gasification

    SciTech Connect (OSTI)

    Schwartz, Joseph; Porter, Jason; Patki, Neil; Kelley, Madison; Stanislowski, Josh; Tolbert, Scott; Way, J. Douglas; Makuch, David

    2015-12-23

    A pilot-scale hydrogen transport membrane (HTM) separator was built that incorporated 98 membranes that were each 24 inches long. This separator used an advanced design to minimize the impact of concentration polarization and separated over 1000 scfh of hydrogen from a hydrogen-nitrogen feed of 5000 scfh that contained 30% hydrogen. This mixture was chosen because it was representative of the hydrogen concentration expected in coal gasification. When tested with an operating gasifier, the hydrogen concentration was lower and contaminants in the syngas adversely impacted membrane performance. All 98 membranes survived the test, but flux was lower than expected. Improved ceramic substrates were produced that have small surface pores to enable membrane production and large pores in the bulk of the substrate to allow high flux. Pd-Au was chosen as the membrane alloy because of its resistance to sulfur contamination and good flux. Processes were developed to produce a large quantity of long membranes for use in the demonstration test.

  5. Countercurrent fixed-bed gasification of biomass at laboratory scale

    SciTech Connect (OSTI)

    Di Blasi, C.; Signorelli, G.; Portoricco, G.

    1999-07-01

    A laboratory-scale countercurrent fixed-bed gasification plant has been designed and constructed to produce data for process modeling and to compare the gasification characteristics of several biomasses (beechwood, nutshells, olive husks, and grape residues). The composition of producer gas and spatial temperature profiles have been measured for biomass gasification at different air flow rates. The gas-heating value always attains a maximum as a function of this operating variable, associated with a decrease of the air-to-fuel ratio. Optical gasification conditions of wood and agricultural residues give rise to comparable gas-heating values, comprised in the range 5--5.5 MJ/Nm{sup 3} with 28--30% CO, 5--7% CO{sub 2}, 6--8% H{sub 2}, 1--2% CH{sub 4}, and small amounts of C{sub 2}- hydrocarbons (apart from nitrogen). However, gasification of agricultural residues is more difficult because of bed transport, partial ash sintering, nonuniform flow distribution, and the presence of a muddy phase in the effluents, so that proper pretreatments are needed for largescale applications.

  6. Survey of biomass gasification. Volume III. Current technology and research

    SciTech Connect (OSTI)

    1980-04-01

    This survey of biomass gasification was written to aid the Department of Energy and the Solar Energy Research Institute Biological and Chemical Conversion Branch in determining the areas of gasification that are ready for commercialization now and those areas in which further research and development will be most productive. Chapter 8 is a survey of gasifier types. Chapter 9 consists of a directory of current manufacturers of gasifiers and gasifier development programs. Chapter 10 is a sampling of current gasification R and D programs and their unique features. Chapter 11 compares air gasification for the conversion of existing gas/oil boiler systems to biomass feedstocks with the price of installing new biomass combustion equipment. Chapter 12 treats gas conditioning as a necessary adjunct to all but close-coupled gasifiers, in which the product is promptly burned. Chapter 13 evaluates, technically and economically, synthesis-gas processes for conversion to methanol, ammonia, gasoline, or methane. Chapter 14 compiles a number of comments that have been assembled from various members of the gasifier community as to possible roles of the government in accelerating the development of gasifier technology and commercialization. Chapter 15 includes recommendations for future gasification research and development.

  7. Pyrolysis and gasification of coal at high temperatures. Quarterly progress report No. 5, September 15, 1988--December 15, 1988

    SciTech Connect (OSTI)

    Zygourakis, K.

    1988-12-31

    Coals of different ranks will be pyrolyzed in a microscope hot-stage reactor using inert and reacting atmospheres. The macropore structure of the produced chars will be characterized using video microscopy and digital image processing techniques to obtain pore size distributions. Comparative studies will quantify the effect of pyrolysis conditions (heating rates, final heat treatment temperatures, particle size and inert or reacting atmosphere) on the pore structure of the devolatilized chars. The devolatilized chars will be gasified in the regime of strong intraparticle diffusional limitations using O{sub 2}/N{sub 2} and O{sub 2}/H{sub 2}O/N{sub 2}2 mixtures. Constant temperature and programmed-temperature experiments in a TGA will be used for these studies. Additional gasification experiments performed in the hot-stage reactor will be videotaped and selected images will be analyzed to obtain quantitative data on particle shrinkage and fragmentation. Discrete mathematical models will be developed and validated using the experimental gasification data.

  8. Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, Scott S.; Zacher, Alan H.; Engelhard, Mark H.; Young, James S.; McCready, David E.

    2004-07-01

    Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

  9. Thermophysical models of underground coal gasification and FEM analysis

    SciTech Connect (OSTI)

    Yang, L.H.

    2007-11-15

    In this study, mathematical models of the coupled thermohydromechanical process of coal rock mass in an underground coal gasification panel are established. Combined with the calculation example, the influence of heating effects on the observed values and simulated values for pore water pressure, stress, and displacement in the gasification panel are fully discussed and analyzed. Calculation results indicate that 38, 62, and 96 days after the experiment, the average relative errors for the calculated values and measured values for the temperature and water pressure were between 8.51-11.14% and 3-10%, respectively; with the passage of gasification time, the calculated errors for the vertical stress and horizontal stress gradually declined, but the simulated errors for the horizontal and vertical displacements both showed a rising trend. On the basis of the research results, the calculated values and the measured values agree with each other very well.

  10. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  11. Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture

    SciTech Connect (OSTI)

    Siefert, Nicholas S.; Shekhawat, Dushyant; Litster, Shawn; Berry, David A.

    2013-08-15

    We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst-capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst-capture agents on (1) the syngas composition, (2) CO2 and H2S capture, and (3) the steam-coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO-CaCO3 chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO3 was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO-CaCO3 cycles. The increased steam-coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2-4% per CaO-CaCO3 cycle. We also discuss an important application of this combined gasifier-calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO4 and ash in the precalcined feedstock.

  12. Characterization of cellulosic wastes and gasification products from chicken farms

    SciTech Connect (OSTI)

    Joseph, Paul; Tretsiakova-McNally, Svetlana; McKenna, Siobhan

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer The gas chromatography indicated the variable quality of the producer gas. Black-Right-Pointing-Pointer The char had appreciable NPK values, and can be used as a fertiliser. Black-Right-Pointing-Pointer The bio-oil produced was of poor quality, having high moisture content and low pH. Black-Right-Pointing-Pointer Mass and energy balances showed inadequate level energy recovery from the process. Black-Right-Pointing-Pointer Future work includes changing the operating parameters of the gasification unit. - Abstract: The current article focuses on gasification as a primary disposal solution for cellulosic wastes derived from chicken farms, and the possibility to recover energy from this process. Wood shavings and chicken litter were characterized with a view to establishing their thermal parameters, compositional natures and calorific values. The main products obtained from the gasification of chicken litter, namely, producer gas, bio-oil and char, were also analysed in order to establish their potential as energy sources. The experimental protocol included bomb calorimetry, pyrolysis combustion flow calorimetry (PCFC), thermo-gravimetric analyses (TGA), differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, elemental analyses, X-ray diffraction (XRD), mineral content analyses and gas chromatography. The mass and energy balances of the gasification unit were also estimated. The results obtained confirmed that gasification is a viable method of chicken litter disposal. In addition to this, it is also possible to recover some energy from the process. However, energy content in the gas-phase was relatively low. This might be due to the low energy efficiency (19.6%) of the gasification unit, which could be improved by changing the operation parameters.

  13. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review

    SciTech Connect (OSTI)

    none,

    2011-10-01

    This independent review is the conclusion arrived at from data collection, document reviews, interviews and deliberation from December 2010 through April 2011 and the technical potential of Hydrogen Production Cost Estimate Using Biomass Gasification. The Panel reviewed the current H2A case (Version 2.12, Case 01D) for hydrogen production via biomass gasification and identified four principal components of hydrogen levelized cost: CapEx; feedstock costs; project financing structure; efficiency/hydrogen yield. The panel reexamined the assumptions around these components and arrived at new estimates and approaches that better reflect the current technology and business environments.

  14. High-pressure gasification of Montana subbituminous coal

    SciTech Connect (OSTI)

    Goyal, A.; Bryan, B.; Rehmat, A.

    1991-01-01

    A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

  15. Simulated Performance of the Integrated Passive Neutron Albedo Reactivity and Self-Interrogation Neutron Resonance Densitometry Detector Designed for Spent Fuel Measurement at the Fugen Reactor in Japan

    SciTech Connect (OSTI)

    Ulrich, Timothy J. II; Lafleur, Adrienne M.; Menlove, Howard O.; Swinhoe, Martyn T.; Tobin, Stephen J.; Seya, Michio; Bolind, Alan M.

    2012-07-16

    An integrated nondestructive assay instrument, which combined the Passive Neutron Albedo Reactivity (PNAR) and the Self-Interrogation Neutron Resonance Densitometry (SINRD) techniques, is the research focus for a collaborative effort between Los Alamos National Laboratory (LANL) and the Japanese Atomic Energy Agency as part of the Next Generation Safeguard Initiative. We will quantify the anticipated performance of this experimental system in two physical environments: (1) At LANL we will measure fresh Low Enriched Uranium (LEU) assemblies for which the average enrichment can be varied from 0.2% to 3.2% and for which Gd laced rods will be included. (2) At Fugen we will measure spent Mixed Oxide (MOX-B) and LEU spent fuel assemblies from the heavy water moderated Fugen reactor. The MOX-B assemblies will vary in burnup from {approx}3 GWd/tHM to {approx}20 GWd/tHM while the LEU assemblies ({approx}1.9% initial enrichment) will vary from {approx}2 GWd/tHM to {approx}7 GWd/tHM. The estimated count rates will be calculated using MCNPX. These preliminary results will help the finalization of the hardware design and also serve a guide for the experiment. The hardware of the detector is expected to be fabricated in 2012 with measurements expected to take place in 2012 and 2013. This work is supported by the Next Generation Safeguards Initiative, Office of Nuclear Safeguards and Security, National Nuclear Security Administration.

  16. Integrity assessment of the ferritic / austenitic dissimilar weld joint between intermediate heat exchanger and steam generator in fast reactor

    SciTech Connect (OSTI)

    Jayakumar, T.; Laha, K.; Chandravathi, K. S.; Parameswaran, P.; Goyal, S.; Kumar, J. G.; Mathew, M. D.

    2012-07-01

    Integrity of the modified 9Cr-1Mo / alloy 800 dissimilar joint welded with Inconel 182 electrodes has been assessed under creep condition based on the detailed analysis of microstructure and stress distribution across the joint by finite element analysis. A hardness peak at the ferritic / austenitic weld interface and a hardness trough at the inter-critical heat affected zone (HAZ) in ferritic base metal developed. Un-tempered martensite was found at the ferritic / austenitic weld interface to impart high hardness in it; whereas annealing of martensitic structure of modified 9Cr-1Mo steel by inter-critical heating during welding thermal cycle resulted in hardness tough in the inter-critical HAZ. Creep tests were carried out on the joint and ferritic steel base metal at 823 K over a stress range of 160-320 MPa. The joint possessed lower creep rupture strength than its ferritic steel base metal. Failure of the joint at relatively lower stresses occurred at the ferritic / austenitic weld interface; whereas it occurred at inter-critical region of HAZ at moderate stresses. Cavity nucleation associated with the weld interface particles led to premature failure of the joint. Finite element analysis of stress distribution across the weld joint considering the micro-mechanical strength inhomogeneity across it revealed higher von-Mises and principal stresses at the weld interface. These stresses induced preferential creep cavitation at the weld interface. Role of precipitate in enhancing creep cavitation at the weld interface has been elucidated based on the FE analysis of stress distribution across it. (authors)

  17. A study of toxic emissions from a coal-fired gasification plant. Final report

    SciTech Connect (OSTI)

    1995-12-01

    Under the Fine Particulate Control/Air Toxics Program, the US Department of Energy (DOE) has been performing comprehensive assessments of toxic substance emissions from coal-fired electric utility units. An objective of this program is to provide information to the US Environmental Protection Agency (EPA) for use in evaluating hazardous air pollutant emissions as required by the Clean Air Act Amendments (CAAA) of 1990. The Electric Power Research Institute (EPRI) has also performed comprehensive assessments of emissions from many power plants and provided the information to the EPA. The DOE program was implemented in two. Phase 1 involved the characterization of eight utility units, with options to sample additional units in Phase 2. Radian was one of five contractors selected to perform these toxic emission assessments.Radian`s Phase 1 test site was at southern Company Service`s Plant Yates, Unit 1, which, as part of the DOE`s Clean Coal Technology Program, was demonstrating the CT-121 flue gas desulfurization technology. A commercial-scale prototype integrated gasification-combined cycle (IGCC) power plant was selected by DOE for Phase 2 testing. Funding for the Phase 2 effort was provided by DOE, with assistance from EPRI and the host site, the Louisiana Gasification Technology, Inc. (LGTI) project This document presents the results of that effort.

  18. FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Robert Hurt; Joseph Calo; Thomas H. Fletcher; Alan Sayre

    2005-04-29

    The goal of this project was to carry out the necessary experiments and analyses to extend current capabilities for modeling fuel transformations to the new conditions anticipated in next-generation coal-based, fuel-flexible combustion and gasification processes. This multi-organization, multi-investigator project has produced data, correlations, and submodels that extend present capabilities in pressure, temperature, and fuel type. The combined experimental and theoretical/computational results are documented in detail in Chapters 1-8 of this report, with Chapter 9 serving as a brief summary of the main conclusions. Chapters 1-3 deal with the effect of elevated pressure on devolatilization, char formation, and char properties. Chapters 4 and 5 deal with advanced combustion kinetic models needed to cover the extended ranges of pressure and temperature expected in next-generation furnaces. Chapter 6 deals with the extension of kinetic data to a variety of alternative solid fuels. Chapter 7 focuses on the kinetics of gasification (rather than combustion) at elevated pressure. Finally, Chapter 8 describes the integration, testing, and use of new fuel transformation submodels into a comprehensive CFD framework. Overall, the effects of elevated pressure, temperature, heating rate, and alternative fuel use are all complex and much more work could be further undertaken in this area. Nevertheless, the current project with its new data, correlations, and computer models provides a much improved basis for model-based design of next generation systems operating under these new conditions.

  19. Nuclear reactor

    DOE Patents [OSTI]

    Pennell, William E.; Rowan, William J.

    1977-01-01

    A nuclear reactor in which the core components, including fuel-rod assemblies, control-rod assemblies, fertile rod-assemblies, and removable shielding assemblies, are supported by a plurality of separate inlet modular units. These units are referred to as inlet module units to distinguish them from the modules of the upper internals of the reactor. The modular units are supported, each removable independently of the others, in liners in the supporting structure for the lower internals of the reactor. The core assemblies are removably supported in integral receptacles or sockets of the modular units. The liners, units, sockets and assmblies have inlet openings for entry of the fluid. The modular units are each removably mounted in the liners with fluid seals interposed between the opening in the liner and inlet module into which the fluid enters and the upper and lower portion of the liner. Each assembly is similarly mounted in a corresponding receptacle with fluid seals interposed between the openings where the fluid enters and the lower portion of the receptacle or fitting closely in these regions. As fluid flows along each core assembly a pressure drop is produced along the fluid so that the fluid which emerges from each core assembly is at a lower pressure than the fluid which enters the core assembly. However because of the seals interposed in the mountings of the units and assemblies the pressures above and below the units and assemblies are balanced and the units are held in the liners and the assemblies are held in the receptacles by their weights as they have a higher specific gravity than the fluid. The low-pressure spaces between each module and its liner and between each core assembly and its module is vented to the low-pressure regions of the vessel to assure that fluid which leaks through the seals does not accumulate and destroy the hydraulic balance.

  20. Method and apparatus for a combination moving bed thermal treatment reactor and moving bed filter

    SciTech Connect (OSTI)

    Badger, Phillip C.; Dunn, Jr., Kenneth J.

    2015-09-01

    A moving bed gasification/thermal treatment reactor includes a geometry in which moving bed reactor particles serve as both a moving bed filter and a heat carrier to provide thermal energy for thermal treatment reactions, such that the moving bed filter and the heat carrier are one and the same to remove solid particulates or droplets generated by thermal treatment processes or injected into the moving bed filter from other sources.

  1. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Fermi, E.; Zinn, W.H.; Anderson, H.L.

    1958-09-16

    Means are presenied for increasing the reproduction ratio of a gaphite- moderated neutronic reactor by diminishing the neutron loss due to absorption or capture by gaseous impurities within the reactor. This means comprised of a fluid-tight casing or envelope completely enclosing the reactor and provided with a valve through which the casing, and thereby the reactor, may be evacuated of atmospheric air.

  2. Biomass gasification at the focus of the Odeillo (France 1-MW (thermal) solar furnace

    SciTech Connect (OSTI)

    Antal, M.J. Jr.; Royere, C.; Vialaron, A.

    1980-01-01

    Experiments described in this paper were undertaken to explore the use of concentrated solar radiation for the flash pyrolysis of biomass. Biomass materials (powdered, microcrystalline cellulose and ground corn cob material) have been successfully gasified in a windowed chemical reactor operating at the focus of the Odeillo 1 MW/sub th/ solar furnace. The quartz window survived radiant flux levels in excess of 1000 W/cm/sup 2/; however impurities carried by the steam flow into the reactor ultimately clouded the window. Pyrolytic char yields of the Odeillo experimetns were quite low: ranging between one and four percent. Gas yields were also relatively low, but condensible yields were high. These results reflect the important role played by the gas phase chemistry (largely unaffected by the high solar flux) in the production of permanent gases from biomass. A consideration of the characteristic times for chemical kinetic and heat transfer phenomenon within a rapidly pyrolyzing particle indicate that heat transfer (not chemical kinetics) is the rate limiting step. However, the thermochemical and optical properties of biomass materials are poorly understood and much more experimental work must be completed before definitive conclusions in this important area can be made. Because the use of concentrated solar radiation for direct gasification of biomass materials results in the formation of little or no char without reliance on the water gas or Boudourad reactions, solar flash pyrolysis of biomass holds unusual promise for the economical production of liquid and gaseous fuels from renewable resources.

  3. EIS-0072: Great Plains Gasification Project, Mercer County, North Dakota

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy prepared this EIS to evaluate the impacts of a project to construct a 125 million cubic feet per day coal gasification facility located in Mercer County, North Dakota. The Office of Fossil Energy adopted three environmental impact evaluation documents prepared by other Federal agencies to develop this EIS.

  4. Power Systems Development Facility Gasification Test Campaign TC22

    SciTech Connect (OSTI)

    Southern Company Services

    2008-11-01

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC22, the first test campaign using a high moisture lignite from Mississippi as the feedstock in the modified Transport Gasifier configuration. TC22 was conducted from March 24 to April 17, 2007. The gasification process was operated for 543 hours, increasing the total gasification operation at the PSDF to over 10,000 hours. The PSDF gasification process was operated in air-blown mode with a total of about 1,080 tons of coal. Coal feeder operation was challenging due to the high as-received moisture content of the lignite, but adjustments to the feeder operating parameters reduced the frequency of coal feeder trips. Gasifier operation was stable, and carbon conversions as high as 98.9 percent were demonstrated. Operation of the PCD and other support equipment such as the recycle gas compressor and ash removal systems operated reliably.

  5. EIS-0007: Low Btu Coal Gasification Facility and Industrial Park

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) prepared this draft environmental impact statement that evaluates the potential environmental impacts that may be associated with the construction and operation of a low-Btu coal gasification facility and the attendant industrial park in Georgetown, Scott County, Kentucky. DOE cancelled this project after publication of the draft.

  6. Subtask 7.4 - Power River Basin Subbituminous Coal-Biomass Cogasification Testing in a Transport Reactor

    SciTech Connect (OSTI)

    Michael Swanson; Daniel Laudal

    2009-03-01

    The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the Kellogg Brown and Root transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 3600 hours of operation on 17 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air- and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 90% have also been obtained and are highly dependent on the oxygen

  7. Bed Agglomeration During the Steam Gasification of a High Lignin Corn Stover Simultaneous Saccharification and Fermentation (SSF) Digester Residue

    SciTech Connect (OSTI)

    Howe, Daniel T.; Taasevigen, Danny J.; Gerber, Mark A.; Gray, Michel J.; Fernandez, Carlos A.; Saraf, Laxmikant; Garcia-Perez, Manuel; Wolcott, Michael P.

    2015-11-13

    This research investigates the bed agglomeration phenomena during the steam gasification of a high lignin residue produced from the simultaneous saccharification and fermentation (SSF) of corn stover in a bubbling fluidized bed. The studies were conducted at 895°C using alumina as bed material. Biomass was fed at 1.5 kg/hr, while steam was fed to give a velocity equal to 2.5 times the minimum fluidization velocity, with a steam/carbon ratio of 0.9. The pelletized feedstock was co-fed with a cooling nitrogen stream to mitigate feed line plugging issues. Tar production was high at 50.3 g/Nm3, and the fraction of C10+ compounds was greater than that seen in the gasification of traditional lignocellulosic feedstocks. Carbon closures over 94 % were achieved for all experiments. Bed agglomeration was found to be problematic, indicated by pressure drop increases observed below the bed and upstream of the feed line. Two size categories of solids were recovered from the reactor, +60 mesh and -60 mesh. After a 2.75-hour experiment, 61.7 wt % was recovered as -60 mesh particles and 38.2 wt% of the recovered reactor solids were +60 mesh. A sizeable percentage, 31.8 wt%, was +20 mesh. The -60 mesh particles were mainly formed by the initial bed material (Al2O3). Almost 50 wt. % of the + 20 mesh particles was found to be formed by organics. The unreacted carbon remaining in the reactor resulted in a low conversion rate to product gas. ICP-AES, SEM, SEM-EDS, and XRD confirmed that the large agglomerates (+ 20 mesh) were not encapsulated bed material but rather un-gasified feedstock pellets with sand particles attached to it.

  8. Fuel-Flexible Gasification-Combustion Technology for Production of H2 and Sequestration-Ready CO2

    SciTech Connect (OSTI)

    Parag Kulkarni; Jie Guan; Raul Subia; Zhe Cui; Jeff Manke; Arnaldo Frydman; Wei Wei; Roger Shisler; Raul Ayala; om McNulty; George Rizeq; Vladimir Zamansky; Kelly Fletcher

    2008-03-31

    In the near future, the nation will continue to rely on fossil fuels for electricity, transportation, and chemicals. It is necessary to improve both the process efficiency and environmental impact of fossil fuel utilization including greenhouse gas management. GE Global Research (GEGR) investigated an innovative fuel-flexible Unmixed Fuel Processor (UFP) technology with potential to produce H{sub 2}, power, and sequestration-ready CO{sub 2} from coal and other solid fuels. The UFP technology offers the long-term potential for reduced cost, increased process efficiency relative to conventional gasification and combustion systems, and near-zero pollutant emissions. GE was awarded a contract from U.S. DOE NETL to investigate and develop the UFP technology. Work started on the Phase I program in October 2000 and on the Phase II effort in April 2005. In the UFP technology, coal, water and air are simultaneously converted into (1) hydrogen rich stream that can be utilized in fuel cells or turbines, (2) CO{sub 2} rich stream for sequestration, and (3) high temperature/pressure vitiated air stream to produce electricity in a gas turbine expander. The process produces near-zero emissions with an estimated efficiency higher than Integrated Gasification Combined Cycle (IGCC) process with conventional CO{sub 2} separation. The Phase I R&D program established the chemical feasibility of the major reactions of the integrated UFP technology through lab-, bench- and pilot-scale testing. A risk analysis session was carried out at the end of Phase I effort to identify the major risks in the UFP technology and a plan was developed to mitigate these risks in the Phase II of the program. The Phase II effort focused on three high-risk areas: economics, lifetime of solids used in the UFP process, and product gas quality for turbines (or the impact of impurities in the coal on the overall system). The economic analysis included estimating the capital cost as well as the costs of hydrogen

  9. Dynamic Impregnator Reactor System (Poster), NREL (National Renewable...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dynamic Impregnator Reactor System Multifaceted system designed for complex feedstock impregnation and processing Integrated Biorefi nery Research Facility | NREL * Golden, ...

  10. FEED SYSTEM INNOVATION FOR GASIFICATION OF LOCALLY ECONOMICAL ALTERNATIVE FUELS (FIGLEAF)

    SciTech Connect (OSTI)

    Michael L. Swanson; Mark A. Musich; Darren D. Schmidt; Joseph K. Schultz

    2003-02-01

    The Feed System Innovation for Gasification of Locally Economical Alternative Fuels (FIGLEAF) project was conducted by the Energy & Environmental Research Center and Gasification Engineering Corporation of Houston, Texas (a subsidiary of Global Energy Inc., Cincinnati, Ohio), with 80% cofunding from the U.S. Department of Energy (DOE). The goal of the project was to identify and evaluate low-value fuels that could serve as alternative feedstocks and to develop a feed system to facilitate their use in integrated gasification combined-cycle and gasification coproduction facilities. The long-term goal, to be accomplished in a subsequent project, is to install a feed system for the selected fuel(s) at Global Energy's commercial-scale 262-MW Wabash River Coal Gasification Facility in West Terre Haute, Indiana. The feasibility study undertaken for the project consisted of identifying and evaluating the economic feasibility of potential fuel sources, developing a feed system design capable of providing a fuel at 400 psig to the second stage of the E-Gas (Destec) gasifier to be cogasified with coal, performing bench- and pilot-scale testing to verify concepts and clarify decision-based options, reviewing information on high-pressure feed system designs, and determining the economics of cofeeding alternative feedstocks with the conceptual feed system design. A preliminary assessment of feedstock availability within Indiana and Illinois was conducted. Feedstocks evaluated included those with potential tipping fees to offset processing cost: sewage sludge, municipal solid waste, used railroad ties, urban wood waste (UWW), and used tires/tire-derived fuel. Agricultural residues and dedicated energy crop fuels were not considered since they would have a net positive cost to the plant. Based on the feedstock assessment, sewage sludge was selected as the primary feedstock for consideration at the Wabash River Plant. Because of the limited waste heat available for drying and the

  11. FEED SYSTEM INNOVATION FOR GASIFICATION OF LOCALLY ECONOMICAL ALTERNATIVE FUELS (FIGLEAF)

    SciTech Connect (OSTI)

    Michael L. Swanson; Mark A. Musich; Darren D. Schmidt

    2001-11-01

    The Feed System Innovation for Gasification of Locally Economical Alternative Fuels (FIGLEAF) project is being conducted by the Energy and Environmental Research Center and Gasification Engineering Corporation of Houston, Texas (a subsidiary of Global Energy Inc., Cincinnati, Ohio), with 80% cofunding from the U.S. Department of Energy. The goal of the project is to identify and evaluate low-value fuels that could serve as alternative feedstocks and to develop a feed system to facilitate their use in integrated gasification combined cycle and gasification coproduction facilities. The long-term goal, to be accomplished in a subsequent project, is to install a feed system for the selected fuels at Global Energy's commercial-scale 262-MW Wabash River Coal Gasification Facility in West Terre Haute, Indiana. The feasibility study undertaken for the project consists of identifying and evaluating the economic feasibility of potential fuel sources, developing a feed system design capable of providing a fuel at 400 psig to the second stage of the E-Gas (Destec) gasifier to be cogasified with coal at up to 30% on a Btu basis, performing bench- and pilot-scale testing to verify concepts and clarify decision-based options, reviewing prior art with respect to high-pressure feed system designs, and determining the economics of cofeeding alternative feedstocks with the conceptual feed system design. Activities and results thus far include the following. Several potential alternative fuels have been obtained for evaluation and testing as potential feedstocks, including sewage sludge, used railroad ties, urban wood waste, municipal solid waste, and used waste tires/tire-derived fuel. Only fuels with potential tipping fees were considered; potential energy crop fuels were not considered since they would have a net positive cost to the plant. Based on the feedstock assessment, sewage sludge has been selected as one of the primary feedstocks for consideration at the Wabash plant

  12. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    SciTech Connect (OSTI)

    Francis Lau

    2002-12-01

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more

  13. Molten salt coal gasification process development unit. Phase 1. Volume 1. PDU operations. Final report

    SciTech Connect (OSTI)

    Kohl, A.L.

    1980-05-01

    This report summarizes the results of a test program conducted on the Molten Salt Coal Gasification Process, which included the design, construction, and operation of a Process Development Unit. In this process, coal is gasified by contacting it with air in a turbulent pool of molten sodium carbonate. Sulfur and ash are retained in the melt, and a small stream is continuously removed from the gasifier for regeneration of sodium carbonate, removal of sulfur, and disposal of the ash. The process can handle a wide variety of feed materials, including highly caking coals, and produces a gas relatively free from tars and other impurities. The gasification step is carried out at approximately 1800/sup 0/F. The PDU was designed to process 1 ton per hour of coal at pressures up to 20 atm. It is a completely integrated facility including systems for feeding solids to the gasifier, regenerating sodium carbonate for reuse, and removing sulfur and ash in forms suitable for disposal. Five extended test runs were made. The observed product gas composition was quite close to that predicted on the basis of earlier small-scale tests and thermodynamic considerations. All plant systems were operated in an integrated manner during one of the runs. The principal problem encountered during the five test runs was maintaining a continuous flow of melt from the gasifier to the quench tank. Test data and discussions regarding plant equipment and process performance are presented. The program also included a commercial plant study which showed the process to be attractive for use in a combined-cycle, electric power plant. The report is presented in two volumes, Volume 1, PDU Operations, and Volume 2, Commercial Plant Study.

  14. BOILING REACTORS

    DOE Patents [OSTI]

    Untermyer, S.

    1962-04-10

    A boiling reactor having a reactivity which is reduced by an increase in the volume of vaporized coolant therein is described. In this system unvaporized liquid coolant is extracted from the reactor, heat is extracted therefrom, and it is returned to the reactor as sub-cooled liquid coolant. This reduces a portion of the coolant which includes vaporized coolant within the core assembly thereby enhancing the power output of the assembly and rendering the reactor substantially self-regulating. (AEC)

  15. Reactor Safety Research Programs

    SciTech Connect (OSTI)

    Edler, S. K.

    1981-07-01

    This document summarizes the work performed by Pacific Northwest Laboratory (PNL) from January 1 through March 31, 1981, for the Division of Reactor Safety Research within the U.S. Nuclear Regulatory Commission (NRC). Evaluations of nondestructive examination (NDE) techniques and instrumentation are reported; areas of investigation include demonstrating the feasibility of determining the strength of structural graphite, evaluating the feasibility of detecting and analyzing flaw growth in reactor pressure boundary systems, examining NDE reliability and probabilistic fracture mechanics, and assessing the integrity of pressurized water reactor (PWR) steam generator tubes where service-induced degradation has been indicated. Experimental data and analytical models are being provided to aid in decision-making regarding pipeto- pipe impacts following postulated breaks in high-energy fluid system piping. Core thermal models are being developed to provide better digital codes to compute the behavior of full-scale reactor systems under postulated accident conditions. Fuel assemblies and analytical support are being provided for experimental programs at other facilities. These programs include loss-ofcoolant accident (LOCA) simulation tests at the NRU reactor, Chalk River, Canada; fuel rod deformation, severe fuel damage, and postaccident coolability tests for the ESSOR reactor Super Sara Test Program, Ispra, Italy; the instrumented fuel assembly irradiation program at Halden, Norway; and experimental programs at the Power Burst Facility, Idaho National Engineering Laboratory (INEL). These programs will provide data for computer modeling of reactor system and fuel performance during various abnormal operating conditions.

  16. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Daniels, F.

    1959-10-27

    A reactor in which at least a portion of the moderator is in the form of movable refractory balls is described. In addition to their moderating capacity, these balls may serve as carriers for fissionable material or fertile material, or may serve in a coolant capacity to remove heat from the reactor. A pneumatic system is used to circulate the balls through the reactor.

  17. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below

  18. NETL - Chemical Looping Reactor

    SciTech Connect (OSTI)

    2013-07-24

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  19. Reactor component automatic grapple

    DOE Patents [OSTI]

    Greenaway, Paul R.

    1982-01-01

    A grapple for handling nuclear reactor components in a medium such as liquid sodium which, upon proper seating and alignment of the grapple with the component as sensed by a mechanical logic integral to the grapple, automatically seizes the component. The mechanical logic system also precludes seizure in the absence of proper seating and alignment.

  20. NETL - Chemical Looping Reactor

    ScienceCinema (OSTI)

    None

    2014-06-26

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  1. CONVECTION REACTOR

    DOE Patents [OSTI]

    Hammond, R.P.; King, L.D.P.

    1960-03-22

    An homogeneous nuclear power reactor utilizing convection circulation of the liquid fuel is proposed. The reactor has an internal heat exchanger looated in the same pressure vessel as the critical assembly, thereby eliminating necessity for handling the hot liquid fuel outside the reactor pressure vessel during normal operation. The liquid fuel used in this reactor eliminates the necessity for extensive radiolytic gas rocombination apparatus, and the reactor is resiliently pressurized and, without any movable mechanical apparatus, automatically regulates itself to the condition of criticality during moderate variations in temperature snd pressure and shuts itself down as the pressure exceeds a predetermined safe operating value.

  2. Biomass gasification for liquid fuel production

    SciTech Connect (OSTI)

    Najser, Jan E-mail: vaclav.peer@vsb.cz; Peer, Václav E-mail: vaclav.peer@vsb.cz

    2014-08-06

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they dońt compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  3. Co-gasification of municipal solid waste and material recovery in a large-scale gasification and melting system

    SciTech Connect (OSTI)

    Tanigaki, Nobuhiro; Manako, Kazutaka; Osada, Morihiro

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer This study evaluates the effects of co-gasification of MSW with MSW bottom ash. Black-Right-Pointing-Pointer No significant difference between MSW treatment with and without MSW bottom ash. Black-Right-Pointing-Pointer PCDD/DFs yields are significantly low because of the high carbon conversion ratio. Black-Right-Pointing-Pointer Slag quality is significantly stable and slag contains few hazardous heavy metals. Black-Right-Pointing-Pointer The final landfill amount is reduced and materials are recovered by DMS process. - Abstract: This study evaluates the effects of co-gasification of municipal solid waste with and without the municipal solid waste bottom ash using two large-scale commercial operation plants. From the viewpoint of operation data, there is no significant difference between municipal solid waste treatment with and without the bottom ash. The carbon conversion ratios are as high as 91.7% and 95.3%, respectively and this leads to significantly low PCDD/DFs yields via complete syngas combustion. The gross power generation efficiencies are 18.9% with the bottom ash and 23.0% without municipal solid waste bottom ash, respectively. The effects of the equivalence ratio are also evaluated. With the equivalence ratio increasing, carbon monoxide concentration is decreased, and carbon dioxide and the syngas temperature (top gas temperature) are increased. The carbon conversion ratio is also increased. These tendencies are seen in both modes. Co-gasification using the gasification and melting system (Direct Melting System) has a possibility to recover materials effectively. More than 90% of chlorine is distributed in fly ash. Low-boiling-point heavy metals, such as lead and zinc, are distributed in fly ash at rates of 95.2% and 92.0%, respectively. Most of high-boiling-point heavy metals, such as iron and copper, are distributed in metal. It is also clarified that slag is stable and contains few harmful heavy metals such

  4. Agglomerating combustor-gasifier method and apparatus for coal gasification

    DOE Patents [OSTI]

    Chen, Joseph L. P.; Archer, David H.

    1976-09-21

    A method and apparatus for gasifying coal wherein the gasification takes place in a spout fluid bed at a pressure of about 10 to 30 atmospheres and a temperature of about 1800.degree. to 2200.degree.F and wherein the configuration of the apparatus and the manner of introduction of gases for combustion and fluidization is such that agglomerated ash can be withdrawn from the bottom of the apparatus and gas containing very low dust loading is produced. The gasification reaction is self-sustaining through the burning of a stoichiometric amount of coal with air in the lower part of the apparatus to form the spout within the fluid bed. The method and apparatus are particularly suitable for gasifying coarse coal particles.

  5. Biomass gasification for gas turbine-based power generation

    SciTech Connect (OSTI)

    Paisley, M.A.; Anson, D.

    1998-04-01

    The Biomass Power Program of the US Department of Energy (DOE) has as a major goal the development of cost-competitive technologies for the production of power from renewable biomass crops. The gasification of biomass provides the potential to meet this goal by efficiently and economically producing a renewable source of a clean gaseous fuel suitable for use in high-efficiency gas turbines. This paper discusses the development and first commercial demonstration of the Battelle high-throughput gasification process for power generation systems. Projected process economics are presented along with a description of current experimental operations coupling a gas turbine power generation system to the research scale gasifier and the process scaleup activities in Burlington, Vermont.

  6. NETL, USDA design coal-stabilized biomass gasification unit

    SciTech Connect (OSTI)

    2008-09-30

    Coal, poultry litter, contaminated corn, rice hulls, moldly hay, manure sludge - these are representative materials that could be tested as fuel feedstocks in a hybrid gasification/combustion concept studied in a recent US Department of Energy (DOE) design project. DOE's National Energy Technology Laboratory (NETL) and the US Department of Agriculture (USDA) collaborated to develop a design concept of a power system that incorporates Hybrid Biomass Gasification. This system would explore the use of a wide range of biomass and agricultural waste products as gasifier feedstocks. The plant, if built, would supply one-third of electrical and steam heating needs at the USDA's Beltsville (Maryland) Agricultural Research Center. 1 fig., 1 photo.

  7. Methods and apparatus for catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

    2012-08-14

    Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  8. Hydrogen Production from Biomass via Indirect Gasification: The Impact of NREL Process Development Unit Gasifier Correlations

    SciTech Connect (OSTI)

    Kinchin, C. M.; Bain, R. L.

    2009-05-01

    This report describes a set of updated gasifier correlations developed by NREL to predict biomass gasification products and Minimum Hydrogen Selling Price.

  9. Market Assessment of Biomass Gasification and Combustion Technology for Small- and Medium-Scale Applications

    SciTech Connect (OSTI)

    Peterson, D.; Haase, S.

    2009-07-01

    This report provides a market assessment of gasification and direct combustion technologies that use wood and agricultural resources to generate heat, power, or combined heat and power (CHP) for small- to medium-scale applications. It contains a brief overview of wood and agricultural resources in the U.S.; a description and discussion of gasification and combustion conversion technologies that utilize solid biomass to generate heat, power, and CHP; an assessment of the commercial status of gasification and combustion technologies; a summary of gasification and combustion system economics; a discussion of the market potential for small- to medium-scale gasification and combustion systems; and an inventory of direct combustion system suppliers and gasification technology companies. The report indicates that while direct combustion and close-coupled gasification boiler systems used to generate heat, power, or CHP are commercially available from a number of manufacturers, two-stage gasification systems are largely in development, with a number of technologies currently in demonstration. The report also cites the need for a searchable, comprehensive database of operating combustion and gasification systems that generate heat, power, or CHP built in the U.S., as well as a national assessment of the market potential for the systems.

  10. Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION...

    Office of Scientific and Technical Information (OSTI)

    carbon capture, utilisation, and storage Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION; POWER GENERATION; CARBON DIOXIDE; CAPTURE; STORAGE; USA; ENHANCED...

  11. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E.; Rosinski, Joseph

    1984-12-04

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  12. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E.; Rosinski, Joseph

    1984-02-28

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  13. UTILIZATION OF LIGHTWEIGHT MATERIALS MADE FROM COAL GASIFICATION SLAGS

    SciTech Connect (OSTI)

    Vas Choudhry; Stephen Kwan; Steven R. Hadley

    2001-07-01

    The objective of the project entitled ''Utilization of Lightweight Materials Made from Coal Gasification Slags'' was to demonstrate the technical and economic viability of manufacturing low-unit-weight products from coal gasification slags which can be used as substitutes for conventional lightweight and ultra-lightweight aggregates. In Phase I, the technology developed by Praxis to produce lightweight aggregates from slag (termed SLA) was applied to produce a large batch (10 tons) of expanded slag using pilot direct-fired rotary kilns and a fluidized bed calciner. The expanded products were characterized using basic characterization and application-oriented tests. Phase II involved the demonstration and evaluation of the use of expanded slag aggregates to produce a number of end-use applications including lightweight roof tiles, lightweight precast products (e.g., masonry blocks), structural concrete, insulating concrete, loose fill insulation, and as a substitute for expanded perlite and vermiculite in horticultural applications. Prototypes of these end-use applications were made and tested with the assistance of commercial manufacturers. Finally, the economics of expanded slag production was determined and compared with the alternative of slag disposal. Production of value-added products from SLA has a significant potential to enhance the overall gasification process economics, especially when the avoided costs of disposal are considered.

  14. Gasification of high ash, high ash fusion temperature bituminous coals

    DOE Patents [OSTI]

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  15. Transient kinetics study of catalytic char gasification in carbon dioxide

    SciTech Connect (OSTI)

    Lizzio, A.A.; Radovic, L.R. . Dept. of Materials Science and Engineering)

    1991-08-01

    In this paper, the deactivation behavior of K, Ca, and Ni catalysts during carbon (char) gasification in CO{sub 2} is investigated. Correlations were sought between gasification rates and reactive surface areas (RSA) of the chars. In addition, the results allowed some speculation on recently proposed mechanisms of catalysis. An excellent correlation was found in the case of K catalysis, suggesting the rate-determining step in the overall mechanism to be the same as in the uncatalyzed reaction, i.e., desorption of the reactive C(O) intermediate. For the Ca-catalyzed reaction, the quality of the correlation depended on catalyst dispersion, suggesting that an additional process, besides the direct decomposition of the reactive C(O) intermediate, contributed to the transient evolution of CO (e.g., oxygen spillover). No correlation was found for Ni-catalyzed gasification; an oxygen-transfer mechanism is proposed to explain these findings. Mixed catalyst systems (Ca/K, K/Ni, Ca/Ni) were also studied. An excellent correlation between reactivity and RSA was observed in cases where the K-catalyzed reaction was dominant.

  16. Power Systems Development Facility Gasification Test Campaing TC18

    SciTech Connect (OSTI)

    Southern Company Services

    2005-08-31

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details Test Campaign TC18 of the PSDF gasification process. Test campaign TC18 began on June 23, 2005, and ended on August 22, 2005, with the gasifier train accumulating 1,342 hours of operation using Powder River Basin (PRB) subbituminous coal. Some of the testing conducted included commissioning of a new recycle syngas compressor for gasifier aeration, evaluation of PCD filter elements and failsafes, testing of gas cleanup technologies, and further evaluation of solids handling equipment. At the conclusion of TC18, the PSDF gasification process had been operated for more than 7,750 hours.

  17. Method for using fast fluidized bed dry bottom coal gasification

    DOE Patents [OSTI]

    Snell, George J.; Kydd, Paul H.

    1983-01-01

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  18. REACTOR GROUT THERMAL PROPERTIES

    SciTech Connect (OSTI)

    Steimke, J.; Qureshi, Z.; Restivo, M.; Guerrero, H.

    2011-01-28

    Savannah River Site has five dormant nuclear production reactors. Long term disposition will require filling some reactor buildings with grout up to ground level. Portland cement based grout will be used to fill the buildings with the exception of some reactor tanks. Some reactor tanks contain significant quantities of aluminum which could react with Portland cement based grout to form hydrogen. Hydrogen production is a safety concern and gas generation could also compromise the structural integrity of the grout pour. Therefore, it was necessary to develop a non-Portland cement grout to fill reactors that contain significant quantities of aluminum. Grouts generate heat when they set, so the potential exists for large temperature increases in a large pour, which could compromise the integrity of the pour. The primary purpose of the testing reported here was to measure heat of hydration, specific heat, thermal conductivity and density of various reactor grouts under consideration so that these properties could be used to model transient heat transfer for different pouring strategies. A secondary purpose was to make qualitative judgments of grout pourability and hardened strength. Some reactor grout formulations were unacceptable because they generated too much heat, or started setting too fast, or required too long to harden or were too weak. The formulation called 102H had the best combination of characteristics. It is a Calcium Alumino-Sulfate grout that contains Ciment Fondu (calcium aluminate cement), Plaster of Paris (calcium sulfate hemihydrate), sand, Class F fly ash, boric acid and small quantities of additives. This composition afforded about ten hours of working time. Heat release began at 12 hours and was complete by 24 hours. The adiabatic temperature rise was 54 C which was within specification. The final product was hard and displayed no visible segregation. The density and maximum particle size were within specification.

  19. F Reactor Inspection

    SciTech Connect (OSTI)

    Grindstaff, Keith; Hathaway, Boyd; Wilson, Mike

    2014-10-29

    Workers from Mission Support Alliance, LLC., removed the welds around the steel door of the F Reactor before stepping inside the reactor to complete its periodic inspection. This is the first time the Department of Energy (DOE) has had the reactor open since 2008. The F Reactor is one of nine reactors along the Columbia River at the Department's Hanford Site in southeastern Washington State, where environmental cleanup has been ongoing since 1989. As part of the Tri-Party Agreement, the Department completes surveillance and maintenance activities of cocooned reactors periodically to evaluate the structural integrity of the safe storage enclosure and to ensure confinement of any remaining hazardous materials. "This entry marks a transition of sorts because the Hanford Long-Term Stewardship Program, for the first time, was responsible for conducting the entry and surveillance and maintenance activities," said Keith Grindstaff, Energy Department Long-Term Stewardship Program Manager. "As the River Corridor cleanup work is completed and transitioned to long-term stewardship, our program will manage any on-going requirements."

  20. F Reactor Inspection

    ScienceCinema (OSTI)

    Grindstaff, Keith; Hathaway, Boyd; Wilson, Mike

    2014-11-24

    Workers from Mission Support Alliance, LLC., removed the welds around the steel door of the F Reactor before stepping inside the reactor to complete its periodic inspection. This is the first time the Department of Energy (DOE) has had the reactor open since 2008. The F Reactor is one of nine reactors along the Columbia River at the Department's Hanford Site in southeastern Washington State, where environmental cleanup has been ongoing since 1989. As part of the Tri-Party Agreement, the Department completes surveillance and maintenance activities of cocooned reactors periodically to evaluate the structural integrity of the safe storage enclosure and to ensure confinement of any remaining hazardous materials. "This entry marks a transition of sorts because the Hanford Long-Term Stewardship Program, for the first time, was responsible for conducting the entry and surveillance and maintenance activities," said Keith Grindstaff, Energy Department Long-Term Stewardship Program Manager. "As the River Corridor cleanup work is completed and transitioned to long-term stewardship, our program will manage any on-going requirements."

  1. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Fraas, A.P.; Mills, C.B.

    1961-11-21

    A neutronic reactor in which neutron moderation is achieved primarily in its reflector is described. The reactor structure consists of a cylindrical central "island" of moderator and a spherical moderating reflector spaced therefrom, thereby providing an annular space. An essentially unmoderated liquid fuel is continuously passed through the annular space and undergoes fission while contained therein. The reactor, because of its small size, is particularly adapted for propulsion uses, including the propulsion of aircraft. (AEC)

  2. Low-temperature catalytic gasification of wet industrial wastes. FY 1993--1994 interim report

    SciTech Connect (OSTI)

    Elliott, D.C.; Hart, T.R.; Neuenschwander, G.G.; Deverman, G.S.; Werpy, T.A.; Phelps, M.R.; Baker, E.G.; Sealock, L.J. Jr.

    1995-03-01

    Process development research is continuing on a low-temperature, catalytic gasification system that has been demonstrated to convert organics in water (dilute or concentrated) to useful and environmentally safe gases. The system, licensed under the trade name Thermochemical Environmental Energy System (TEESO), treats a wide variety of feedstocks ranging from hazardous organics in water to waste sludges from food processing. The current research program is focused on the use of continuous-feed, tubular reactors systems for testing catalysts and feedstocks in the process. A range of catalysts have been tested, including nickel and other base metals, as well as ruthenium and other precious metals. Results of extensive testing show that feedstocks, ranging from 2% para-cresol in water to potato waste and spent grain, can be processed to > 99% reduction of chemical oxygen demand (COD). The product fuel gas contains from 40% up to 75% methane, depending on the feedstock. The balance of the gas is mostly carbon dioxide with < 5% hydrogen and usually < 1% ethane and higher hydrocarbons. The byproduct water stream carries residual organics from 10 to 1,000 mg/l COD, depending on the feedstock. The level of development of TEES has progressed to the initial phases of industrial process demonstration. Testing of industrial waste streams is under way at both the bench scale and engineering scale of development.

  3. REACTOR COOLING

    DOE Patents [OSTI]

    Quackenbush, C.F.

    1959-09-29

    A nuclear reactor with provisions for selectively cooling the fuel elements is described. The reactor has a plurality of tubes extending throughout. Cylindrical fuel elements are disposed within the tubes and the coolant flows through the tubes and around the fuel elements. The fuel elements within the central portion of the reactor are provided with roughened surfaces of material. The fuel elements in the end portions of the tubes within the reactor are provlded with low conduction jackets and the fuel elements in the region between the central portion and the end portions are provided with smooth surfaces of high heat conduction material.

  4. High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor

    SciTech Connect (OSTI)

    Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

    2011-07-31

    Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

  5. Development of an advanced, continuous mild gasification process for the production of co-products: Topical report

    SciTech Connect (OSTI)

    Cha, C.Y.; Merriam, N.W.; Jha, M.C.; Breault, R.W.

    1988-06-01

    Research on mild gasification is discussed. The report is divided into three sections: literature survey of mild gasification processes; literature survey of char, condensibles, and gas upgrading and utilization methods; and industrial market assessment of products of mild gasification. Recommendations are included in each section. (CBS) 248 refs., 58 figs., 62 tabs.

  6. A study of cellulose gasification in a fluidized bed using a high-temperature solar furnace

    SciTech Connect (OSTI)

    Murray, J.P.

    1989-01-01

    A 4.2-meter solar furnace was used to study the gasification of cellulose with steam in a fluidized bed. The heating value of the high-temperature equilibrium products is about twenty percent higher than that of the reactants. The increase represents stored solar energy; and the product, synthesis gas, is valuable as a chemical feedstock or pipeline gas. All experiments were performed at atmospheric pressure. Pure tabular alumina as well as crushed automotive exhaust was used as a bed material. Microcrystalline {alpha}-cellulose, entrained in argon, entered the fluidized bed just above the distributor. Steam heated to the operating temperature in a 10 cm packed bed section below the fluidized bed. In all cases, the process ran with more steam than required to produce an equimolar mixture of carbon monoxide and hydrogen. We used a quartz reactor between 1100 and 1430 K; a steel reactor at 1500 K and an Inconel reactor at 1600 K. Reactor inside diameter, nominally 5 cm, varied slightly; the bed height was adjusted to keep the gas residence time constant. Hydrogen production rate was measured before and after experiments with steam alone, with this amount subtracted. Equilibrium mixtures were not achieved. Catalysts improved hydrogen yields with higher than expected concentrations of carbon monoxide, methane and lighter hydrocarbons such as ethylene and acetylene. Experiments performed without catalyst at 1300 K, achieved a mixture (dry, argon-free) of 46 mole% CO, 30% H{sub 2} 14% CH{sub 4} 5% CO{sub 2} and 5% C{sub 2}H{sub 4}. An equilibrium mixture at this temperature would have contained 39% CO, 30% H{sub 2} 7% CO{sub 2} and no CH{sub 4} or C{sub 2}H{sub 4}. With the catalyst, the CO and CH{sub 4} decreased to 40% and 2% respectively, the H{sub 2} increased to 47%, and CO{sub 2} remained the same. No ethylene was formed. The hydrocarbon-rich mixtures achieved are typical of rapid-pyrolysis processes.

  7. Computational fluid dynamics modeling of coal gasification in a pressurized spout-fluid bed

    SciTech Connect (OSTI)

    Zhongyi Deng; Rui Xiao; Baosheng Jin; He Huang; Laihong Shen; Qilei Song; Qianjun Li

    2008-05-15

    Computational fluid dynamics (CFD) modeling, which has recently proven to be an effective means of analysis and optimization of energy-conversion processes, has been extended to coal gasification in this paper. A 3D mathematical model has been developed to simulate the coal gasification process in a pressurized spout-fluid bed. This CFD model is composed of gas-solid hydrodynamics, coal pyrolysis, char gasification, and gas phase reaction submodels. The rates of heterogeneous reactions are determined by combining Arrhenius rate and diffusion rate. The homogeneous reactions of gas phase can be treated as secondary reactions. A comparison of the calculated and experimental data shows that most gasification performance parameters can be predicted accurately. This good agreement indicates that CFD modeling can be used for complex fluidized beds coal gasification processes. 37 refs., 7 figs., 5 tabs.

  8. Heat dissipating nuclear reactor

    DOE Patents [OSTI]

    Hunsbedt, A.; Lazarus, J.D.

    1985-11-21

    Disclosed is a nuclear reactor containment adapted to retain and cool core debris in the unlikely event of a core meltdown and subsequent breach in the reactor vessel. The reactor vessel is seated in a cavity which has a thick metal sidewall that is integral with a thick metal basemat at the bottom of the cavity. The basemat extends beyond the perimeter of the cavity sidewall. Underneath the basemat is a porous bed with water pipes and steam pipes running into it. Water is introduced into the bed and converted into steam which is vented to the atmosphere. A plurality of metal pilings in the form of H-beams extend from the metal base plate downwardly and outwardly into the earth.

  9. Heat dissipating nuclear reactor

    DOE Patents [OSTI]

    Hunsbedt, Anstein; Lazarus, Jonathan D.

    1987-01-01

    Disclosed is a nuclear reactor containment adapted to retain and cool core debris in the unlikely event of a core meltdown and subsequent breach in the reactor vessel. The reactor vessel is seated in a cavity which has a thick metal sidewall that is integral with a thick metal basemat at the bottom of the cavity. The basemat extends beyond the perimeter of the cavity sidewall. Underneath the basemat is a porous bed with water pipes and steam pipes running into it. Water is introduced into the bed and converted into steam which is vented to the atmosphere. A plurality of metal pilings in the form of H-beams extends from the metal base plate downwardly and outwardly into the earth.

  10. Catalytic gasification studies in a pressurized fluid-bed unit

    SciTech Connect (OSTI)

    Mudge, L.K.; Baker, E.G.; Mitchell, D.H.; Robertus, R.J.; Brown, M.D.

    1983-07-01

    The purpose of the project is to evaluate the technical and economic feasibility of producing specific gas products via the catalytic gasification of biomass. This report presents the results of research conducted from October 1980 to November 1982. In the laboratory scale studis, active catalysts were developed for generation of synthesis gases from wood by steam gasification. A trimetallic catalyst, Ni-Co-Mo on silica-alumina doped with 2 wt % Na, was found to retain activity indefinitely for generation of a methanol synthesis gas from wood at 1380/sup 0/F (750/sup 0/C) and 1 atm (100 kPa) absolute pressure. Catalysts for generation of a methane-rich gas were deactivated rapidly and could not be regenerated as required for economic application. Sodium carbonate and potassium carbonate were effective as catalysts for conversion of wood to synthesis gases and methane-rich gas and should be economically viable. Catalytic gasification conditions were found to be suitable for processing of alternative feedstocks: bagasse, alfalfa, rice hulls, and almond hulls. The PDU was operated successfully at absolute pressures of up to 10 atm (1000 kPa) and temperatures of up to 1380/sup 0/F (750/sup 0/C). Yields of synthesis gases at elevated pressure were greater than those used for previous economic evaluations. A trimetallic catalyst, Ni-Cu-Mo on silica-alumina, did not display a long life as did the doped trimetallic catalyst used in laboratory studies. A computer program for a Radio Shack TRS-80 Model I microcomputer was developed to evaluate rapidly the economics of producing either methane or methanol from wood. The program is based on economic evaluations reported in previous studies. Improved yields from the PDU studies were found to result in a reduction of about 9 cents/gal in methanol cost.

  11. Coal gasification. Quarterly report, April-June 1979

    SciTech Connect (OSTI)

    1980-04-01

    In DOE's program for the conversion of coal to gaseous fuels both high-and low-Btu gasification processes are being developed. High-Btu gas can be distributed economically to consumers in the same pipeline systems now used to carry natural gas. Low-Btu gas, the cheapest of the gaseous fuels produced from coal, can be used economically only on site, either for electric power generation or by industrial and petrochemical plants. High-Btu natural gas has a heating value of 950 to 1000 Btu per standard cubic foot, is composed essentially of methane, and contains virtually no sulfur, carbon monoxide, or free hydrogen. The conversion of coal to High-Btu gas requires a chemical and physical transformation of solid coal. Coals have widely differing chemical and physical properties, depending on where they are mined, and are difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, DOE, together with the American Gas Association (AGA), is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, each of the processes under development have unique characteristics. A number of the processes for converting coal to high-Btu gas have reached the pilot plant Low-Btu gas, with a heating value of up to 350 Btu per standard cubic foot, is an economical fuel for industrial use as well as for power generation in combined gas-steam turbine power cycles. Because different low-Btu gasification processes are optimum for converting different types of coal, and because of the need to provide commercially acceptable processes at the earliest possible date, DOE is sponsoring the concurrent development of several basic types of gasifiers (fixed-bed, fluidized-bed, and entrained-flow).

  12. Commercial low-Btu coal-gasification plant

    SciTech Connect (OSTI)

    1981-11-01

    In response to a 1980 Department of Energy solicitation, the General Refractories Company submitted a Proposal for a feasibility study of a low Btu gasification facility for its Florence, KY plant. The proposed facility would substitute low Btu gas from a fixed bed gasifier for natural gas now used in the manufacture of insulation board. The Proposal was prompted by a concern over the rising costs of natural gas, and the anticipation of a severe increase in fuel costs resulting from deregulation. The feasibility study consisted of the following tasks: perform preliminary engineering of a gasification facility; provide a definitive full gas cost estimate based upon the preliminary engineering fuel design; determine the preferred source of coal; determine the potential for the disposition of, and income from, by-products; develop a health and safety program; perform an analysis of the risks involved in constructing and operating such a facility; and prepare a Financial Analysis of General Refractories selected Dravo Engineers and Constructors based upon the qualifications of Dravo in the field of coal conversion, and the fact that Dravo has acquired the rights to the Wellman-Galusha technology. Given the various natural gas forecasts available, there seems to be a reasonable possibility that the five-gasifier LBG prices will break even with natural gas prices somewhere between 1984 and 1989. General Refractories recognizes that there are many uncertainties in developing these natural gas forecasts and, if the present natural gas decontrol plan is not fully implemented, some budgetary risks would occur in undertaking the proposed gasification facility. Because of this, General Refractories has decided to wait for more substantiating evidence that natural gas prices will rise as is now being predicted.

  13. Power Systems Development Facility Gasification Test Campaign TC25

    SciTech Connect (OSTI)

    Southern Company Services

    2008-12-01

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC25, the second test campaign using a high moisture lignite coal from the Red Hills mine in Mississippi as the feedstock in the modified Transport Gasifier configuration. TC25 was conducted from July 4, 2008, through August 12, 2008. During TC25, the PSDF gasification process operated for 742 hours in air-blown gasification mode. Operation with the Mississippi lignite was significantly improved in TC25 compared to the previous test (TC22) with this fuel due to the addition of a fluid bed coal dryer. The new dryer was installed to dry coals with very high moisture contents for reliable coal feeding. The TC25 test campaign demonstrated steady operation with high carbon conversion and optimized performance of the coal handling and gasifier systems. Operation during TC25 provided the opportunity for further testing of instrumentation enhancements, hot gas filter materials, and advanced syngas cleanup technologies. The PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane with syngas from the Transport Gasifier.

  14. Power Systems Development Facility Gasification Test Campaign TC24

    SciTech Connect (OSTI)

    Southern Company Services

    2008-03-30

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC24, the first test campaign using a bituminous coal as the feedstock in the modified Transport Gasifier configuration. TC24 was conducted from February 16, 2008, through March 19, 2008. The PSDF gasification process operated for about 230 hours in air-blown gasification mode with about 225 tons of Utah bituminous coal feed. Operational challenges in gasifier operation were related to particle agglomeration, a large percentage of oversize coal particles, low overall gasifier solids collection efficiency, and refractory degradation in the gasifier solids collection unit. The carbon conversion and syngas heating values varied widely, with low values obtained during periods of low gasifier operating temperature. Despite the operating difficulties, several periods of steady state operation were achieved, which provided useful data for future testing. TC24 operation afforded the opportunity for testing of various types of technologies, including dry coal feeding with a developmental feeder, the Pressure Decoupled Advanced Coal (PDAC) feeder; evaluating a new hot gas filter element media configuration; and enhancing syngas cleanup with water-gas shift catalysts. During TC24, the PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane.

  15. Fuel-Flexible Gasification-Combustion Technology for Production of H2 and Sequestration-Ready CO2

    SciTech Connect (OSTI)

    George Rizeq; Parag Kulkarni; Wei Wei; Arnaldo Frydman; Thomas McNulty; Roger Shisler

    2005-11-01

    It is expected that in the 21st century the Nation will continue to rely on fossil fuels for electricity, transportation, and chemicals. It will be necessary to improve both the process efficiency and environmental impact performance of fossil fuel utilization. GE Global Research is developing an innovative fuel-flexible Unmixed Fuel Processor (UFP) technology to produce H{sub 2}, power, and sequestration-ready CO{sub 2} from coal and other solid fuels. The UFP module offers the potential for reduced cost, increased process efficiency relative to conventional gasification and combustion systems, and near-zero pollutant emissions including NO{sub x}. GE was awarded a contract from U.S. DOE NETL to develop the UFP technology. Work on the Phase I program started in October 2000, and work on the Phase II effort started in April 2005. In the UFP technology, coal and air are simultaneously converted into separate streams of (1) high-purity hydrogen that can be utilized in fuel cells or turbines, (2) sequestration-ready CO{sub 2}, and (3) high temperature/pressure vitiated air to produce electricity in a gas turbine. The process produces near-zero emissions with an estimated efficiency higher than IGCC with conventional CO2 separation. The Phase I R&D program established the feasibility of the integrated UFP technology through lab-, bench- and pilot-scale testing and investigated operating conditions that maximize separation of CO{sub 2} and pollutants from the vent gas, while simultaneously maximizing coal conversion efficiency and hydrogen production. The Phase I effort integrated experimental testing, modeling and preliminary economic studies to demonstrate the UFP technology. The Phase II effort will focus on three high-risk areas: economics, sorbent attrition and lifetime, and product gas quality for turbines. The economic analysis will include estimating the capital cost as well as the costs of hydrogen and electricity for a full-scale UFP plant. These costs will be

  16. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Production Cost Estimate Using Biomass Gasification National Renewable Energy Laboratory 1617 Cole Boulevard * Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Contract No. DE-AC36-08GO28308 Independent Review Published for the U.S. Department of Energy Hydrogen and Fuel Cells Program NREL/BK-6A10-51726 October

  17. Revised users manual, Pulverized Coal Gasification or Combustion: 2-dimensional (87-PCGC-2): Final report, Volume 2. [87-PCGC-2

    SciTech Connect (OSTI)

    Smith, P.J.; Smoot, L.D.; Brewster, B.S.

    1987-12-01

    A two-dimensional, steady-state model for describing a variety of reactive and non-reactive flows, including pulverized coal combustion and gasification, is presented. Recent code revisions and additions are described. The model, referred to as 87-PCGC-2, is applicable to cylindrical axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using either a flux method or discrete ordinates method. The particle phase is modeled in a Lagrangian framework, such that mean paths of particle groups are followed. Several multi-step coal devolatilization schemes are included along with a heterogeneous reaction scheme that allows for both diffusion and chemical reaction. Major gas-phase reactions are modeled assuming local instantaneous equilibrium, and thus the reaction rates are limited by the turbulent rate mixing. A NO/sub x/ finite rate chemistry submodel is included which integrates chemical kinetics and the statistics of the turbulence. The gas phase is described by elliptic partial differential equations that are solved by an iterative line-by-line technique. Under-relaxation is used to achieve numerical stability. The generalized nature of the model allows for calculation of isothermal fluid mechanicsgaseous combustion, droplet combustion, particulate combustion and various mixtures of the above, including combustion of coal-water and coal-oil slurries. Both combustion and gasification environments are permissible. User information and theory are presented, along with sample problems. 106 refs.

  18. CFD Simulations of a Regenerative Process for Carbon Dioxide Capture in Advanced Gasification Based Power Systems

    SciTech Connect (OSTI)

    Arastoopour, Hamid; Abbasian, Javad

    2014-07-31

    the method of moments, called Finite size domain Complete set of trial functions Method Of Moments (FCMOM) was used to solve the population balance equations. The PBE model was implemented in a commercial CFD code, Ansys Fluent 13.0. The code was used to test the model in some simple cases and the results were verified against available analytical solution in the literature. Furthermore, the code was used to simulate CO2 capture in a packed-bed and the results were in excellent agreement with the experimental data obtained in the packed bed. The National Energy Laboratory (NETL) Carbon Capture Unit (C2U) design was used in simulate of the hydrodynamics of the cold flow gas/solid system (Clark et al.58). The results indicate that the pressure drop predicted by the model is in good agreement with the experimental data. Furthermore, the model was shown to be able to predict chugging behavior, which was observed during the experiment. The model was used as a base-case for simulations of reactive flow at elevated pressure and temperatures. The results indicate that by controlling the solid circulation rate, up to 70% CO2 removal can be achieved and that the solid hold up in the riser is one of the main factors controlling the extent of CO2 removal. The CFD/PBE simulation model indicates that by using a simulated syngas with a composition of 20% CO2, 20% H2O, 30% CO, and 30% H2, the composition (wet basis) in the reactor outlet corresponded to about 60% CO2 capture with and exit gas containing 65% H2. A preliminary base-case-design was developed for a regenerative MgO-based pre-combustion carbon capture process for a 500 MW IGCC power plant. To minimize the external energy requirement, an extensive heat integration network was developed in Aspen/HYSYS® to produce the steam required in the regenerator and heat integration. In this process, liquid CO2 produced at 50 atm can easily be pumped and sequestered or stored. The preliminary economic analyses indicate that the

  19. Development of an advanced continuous mild gasification process for the production of co-products. Final report, September 1987--September 1996

    SciTech Connect (OSTI)

    1996-12-31

    Char, the major co-product of mild coal gasification, represents about 70 percent of the total product yield. The only viable use for the char is in the production of formed coke. Early work to develop formed coke used char from a pilot plant sized mild gasification unit (MGU), which was based on commercial units of the COALITE plant in England. Formed coke was made at a bench-scale production level using MGU chars from different coals. An evolutionary formed coke development process over a two-year period resulted in formed coke production at bench-scale levels that met metallurgical industries` specifications. In an ASTM D5341 reactivity test by a certified lab, the coke tested CRI 30.4 and CSR 67.0 which is excellent. The standard is CRI < 32 and CSR > 55. In 1991, a continuous 1000 pounds per hour coal feed mild coal gasification pilot plant (CMGU) was completed. The gasification unit is a heated unique screw conveyor designed to continuously process plastic coal, vent volatiles generated by pyrolysis of coal, and convert the plastic coal to free flowing char. The screw reactor auxiliary components are basic solids materials handling equipment. The screw reactor will convert coal to char and volatile co-products at a rate greater than 1000 pounds per hour of coal feed. Formed coke from CMGU char is comparable to that from the MGU char. In pilot-plant test runs, up to 20 tons of foundry coke were produced. Three formed coke tests at commercial foundries were successful. In all of the cupola tests, the iron temperature and composition data indicated that the formed coke performed satisfactorily. No negative change in the way the cupola performed was noticed. The last 20-ton test was 100 percent CTC/DOE coke. With conventional coke in this cupola charging rates were 10 charges per hour. The formed coke charges were 11 to 12 charges per hour. This equates to a higher melt rate. A 10 percent increase in cupola production would be a major advantage. 13 figs., 13 tabs.

  20. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Moore, R.V.; Bowen, J.H.; Dent, K.H.

    1958-12-01

    A heterogeneous, natural uranium fueled, solid moderated, gas cooled reactor is described, in which the fuel elements are in the form of elongated rods and are dlsposed within vertical coolant channels ln the moderator symmetrically arranged as a regular lattice in groups. This reactor employs control rods which operate in vertical channels in the moderator so that each control rod is centered in one of the fuel element groups. The reactor is enclosed in a pressure vessel which ls provided with access holes at the top to facilitate loading and unloadlng of the fuel elements, control rods and control rod driving devices.

  1. REACTOR MODERATOR STRUCTURE

    DOE Patents [OSTI]

    Greenstreet, B.L.

    1963-12-31

    A system for maintaining the alignment of moderator block structures in reactors is presented. Integral restraining grids are placed between each layer of blocks in the moderator structure, at the top of the uppermost layer, and at the bottom of the lowermost layer. Slots are provided in the top and bottom surfaces of the moderator blocks so as to provide a keying action with the grids. The grids are maintained in alignment by vertical guiding members disposed about their peripheries. (AEC)

  2. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2004-12-01

    This report describes the work performed, accomplishments and conclusion obtained from the project entitled ''Novel Composite Membranes for Hydrogen Separation in Gasification Processes in Vision 21 Energy Plants'' under the United States Department of Energy Contract DE-FC26-01NT40973. ITN Energy Systems was the prime contractor. Team members included: the Idaho National Engineering and Environmental Laboratory; Nexant Consulting; Argonne National Laboratory and Praxair. The objective of the program was to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The separation technology module is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of these plants. Of particular importance is that this technology will also produce a stream of pure carbon dioxide. This allows facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner. The program developed and evaluated composite membranes and catalysts for hydrogen separation. Components of the monolithic modules were fabricated by plasma spray processing. The engineering and economic characteristics of the proposed Ion Conducting Ceramic Membrane (ICCM) approach, including system integration issues, were also assessed. This resulted in a comprehensive evaluation of the technical and economic feasibility of integration schemes of ICCM hydrogen separation technology within Vision 21 fossil fuel plants. Several results and conclusion were obtained during this program. In the area of materials synthesis, novel

  3. Simulation of carbon gasification kinetics using an edge recession model

    SciTech Connect (OSTI)

    Takashi Kyotani; Leon y Leon, C.A.L.; Radovic, L.R. )

    1993-07-01

    An edge recession modeling method is proposed as a new approach to the prediction of carbon gasification kinetics. Using this method, the variations in reactive surface area (RSA) and specific reactivity (R) with conversion were simulated for several polynuclear aromatic molecules adopted as models of carbon crystallites. The effects of crystallite size and shape, edge site reactivity and vacancies on the changes in RSA and R with conversion were investigated. As a result, RSA and R were found to be essentially independent of crystallite shape, but to depend on crystallite size and the presence of vacancies. Good agreement was obtained between model predictions and experimental data for several kinds of model carbon crystallites. In the case of structurally disordered carbons (such as chars), simultaneous gasification of model crystallites of two different sizes gave better predictions than that of single-size crystallites. The edge recession model is proposed as an alternative, or at least complementary, approach to the more conventional (and, arguably, less physically meaningful) pore structure development models.

  4. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Hurwitz, H. Jr.; Brooks, H.; Mannal, C.; Payne, J.H.; Luebke, E.A.

    1959-03-24

    A reactor of the heterogeneous, liquid cooled type is described. This reactor is comprised of a central region of a plurality of vertically disposed elongated tubes surrounded by a region of moderator material. The central region is comprised of a central core surrounded by a reflector region which is surrounded by a fast neutron absorber region, which in turn is surrounded by a slow neutron absorber region. Liquid sodium is used as the primary coolant and circulates through the core which contains the fuel elements. Control of the reactor is accomplished by varying the ability of the reflector region to reflect neutrons back into the core of the reactor. For this purpose the reflector is comprised of moderator and control elements having varying effects on reactivity, the control elements being arranged and actuated by groups to give regulation, shim, and safety control.

  5. NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Wigner, E.P.

    1960-11-22

    A nuclear reactor is described wherein horizontal rods of thermal- neutron-fissionable material are disposed in a body of heavy water and extend through and are supported by spaced parallel walls of graphite.

  6. REACTOR SHIELD

    DOE Patents [OSTI]

    Wigner, E.P.; Ohlinger, L.E.; Young, G.J.; Weinberg, A.M.

    1959-02-17

    Radiation shield construction is described for a nuclear reactor. The shield is comprised of a plurality of steel plates arranged in parallel spaced relationship within a peripheral shell. Reactor coolant inlet tubes extend at right angles through the plates and baffles are arranged between the plates at right angles thereto and extend between the tubes to create a series of zigzag channels between the plates for the circulation of coolant fluid through the shield. The shield may be divided into two main sections; an inner section adjacent the reactor container and an outer section spaced therefrom. Coolant through the first section may be circulated at a faster rate than coolant circulated through the outer section since the area closest to the reactor container is at a higher temperature and is more radioactive. The two sections may have separate cooling systems to prevent the coolant in the outer section from mixing with the more contaminated coolant in the inner section.

  7. Reactor apparatus

    DOE Patents [OSTI]

    Echtler, J. Paul

    1981-01-01

    A reactor apparatus for hydrocracking a polynuclear aromatic hydrocarbonaceous feedstock to produce lighter hydrocarbon fuels by contacting the hydrocarbonaceous feedstock with hydrogen in the presence of a molten metal halide catalyst.

  8. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Anderson, H.L.

    1960-09-20

    A nuclear reactor is described comprising fissionable material dispersed in graphite blocks, helium filling the voids of the blocks and the spaces therebetween, and means other than the helium in thermal conductive contact with the graphite for removing heat.

  9. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Fermi, E.

    1960-04-01

    A nuclear reactor is described consisting of blocks of graphite arranged in layers, natural uranium bodies disposed in holes in alternate layers of graphite blocks, and coolant tubes disposed in the layers of graphite blocks which do not contain uranium.

  10. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Miller, H.I.; Smith, R.C.

    1958-01-21

    This patent relates to nuclear reactors of the type which use a liquid fuel, such as a solution of uranyl sulfate in ordinary water which acts as the moderator. The reactor is comprised of a spherical vessel having a diameter of about 12 inches substantially surrounded by a reflector of beryllium oxide. Conventionnl control rods and safety rods are operated in slots in the reflector outside the vessel to control the operation of the reactor. An additional means for increasing the safety factor of the reactor by raising the ratio of delayed neutrons to prompt neutrons, is provided and consists of a soluble sulfate salt of beryllium dissolved in the liquid fuel in the proper proportion to obtain the result desired.

  11. NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Vernon, H.C.

    1959-01-13

    A neutronic reactor of the heterogeneous, fluid cooled tvpe is described. The reactor is comprised of a pressure vessel containing the moderator and a plurality of vertically disposed channels extending in spaced relationship through the moderator. Fissionable fuel material is placed within the channels in spaced relationship thereto to permit circulation of the coolant fluid. Separate means are provided for cooling the moderator and for circulating a fluid coolant thru the channel elements to cool the fuel material.

  12. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Anderson, C.R.

    1962-07-24

    A fluidized bed nuclear reactor and a method of operating such a reactor are described. In the design means are provided for flowing a liquid moderator upwardly through the center of a bed of pellets of a nentron-fissionable material at such a rate as to obtain particulate fluidization while constraining the lower pontion of the bed into a conical shape. A smooth circulation of particles rising in the center and falling at the outside of the bed is thereby established. (AEC)

  13. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Breden, C.R.; Dietrich, J.R.

    1961-06-20

    A water-soluble non-volatile poison may be introduced into a reactor to nullify excess reactivity. The poison is removed by passing a side stream of the water containing the soluble poison to an evaporation chamber. The vapor phase is returned to the reactor to decrease the concentration of soluble poison and the liquid phase is returned to increase the concentration of soluble poison.

  14. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Grebe, J.J.

    1959-07-14

    High temperature reactors which are uniquely adapted to serve as the heat source for nuclear pcwered rockets are described. The reactor is comprised essentially of an outer tubular heat resistant casing which provides the main coolant passageway to and away from the reactor core within the casing and in which the working fluid is preferably hydrogen or helium gas which is permitted to vaporize from a liquid storage tank. The reactor core has a generally spherical shape formed entirely of an active material comprised of fissile material and a moderator material which serves as a diluent. The active material is fabricated as a gas permeable porous material and is interlaced in a random manner with very small inter-connecting bores or capillary tubes through which the coolant gas may flow. The entire reactor is divided into successive sections along the direction of the temperature gradient or coolant flow, each section utilizing materials of construction which are most advantageous from a nuclear standpoint and which at the same time can withstand the operating temperature of that particular zone. This design results in a nuclear reactor characterized simultaneously by a minimum critiral size and mass and by the ability to heat a working fluid to an extremely high temperature.

  15. Modeling and comparative assessment of municipal solid waste gasification for energy production

    SciTech Connect (OSTI)

    Arafat, Hassan A. Jijakli, Kenan

    2013-08-15

    Highlights: • Study developed a methodology for the evaluation of gasification for MSW treatment. • Study was conducted comparatively for USA, UAE, and Thailand. • Study applies a thermodynamic model (Gibbs free energy minimization) using the Gasify software. • The energy efficiency of the process and the compatibility with different waste streams was studied. - Abstract: Gasification is the thermochemical conversion of organic feedstocks mainly into combustible syngas (CO and H{sub 2}) along with other constituents. It has been widely used to convert coal into gaseous energy carriers but only has been recently looked at as a process for producing energy from biomass. This study explores the potential of gasification for energy production and treatment of municipal solid waste (MSW). It relies on adapting the theory governing the chemistry and kinetics of the gasification process to the use of MSW as a feedstock to the process. It also relies on an equilibrium kinetics and thermodynamics solver tool (Gasify®) in the process of modeling gasification of MSW. The effect of process temperature variation on gasifying MSW was explored and the results were compared to incineration as an alternative to gasification of MSW. Also, the assessment was performed comparatively for gasification of MSW in the United Arab Emirates, USA, and Thailand, presenting a spectrum of socioeconomic settings with varying MSW compositions in order to explore the effect of MSW composition variance on the products of gasification. All in all, this study provides an insight into the potential of gasification for the treatment of MSW and as a waste to energy alternative to incineration.

  16. Steam gasification of carbon: Catalyst properties. Final report, September 15, 1988--October 31, 1992

    SciTech Connect (OSTI)

    Falconer, J.L.

    1993-01-10

    Coal gasification by steam is of critical importance in converting coal to gaseous products (CO, H{sub 2}, CO{sub 2}, CH{sub 4}) that can then be further converted to synthetic natural gas and higher hydrocarbon fuels. Alkali and alkaline earth metals (present as oxides) catalyze coal gasification reactions and cause them to occur at significantly lower temperatures. A more fundamental understanding of the mechanism of the steam gasification reaction and catalyst utilization may well lead to better production techniques, increased gasification rates, greater yields, and less waste. We are studying the gasification of carbon by steam in the presence of alkali and alkaline earth oxides, using carbonates as the starting materials. Carbon dioxide gasification (CO{sub 2} + C --> 2CO) has been studied in some detail recently, but much less has been done on the actual steam gasification reaction, which is the main thrust of our work. In particular, the form of the active catalyst compound during reaction is still questioned and the dependence of the concentration of active sites on reaction parameters is not known. Until recently, no measurements of active site concentrations during reaction had been made. We have recently used transient isotope tracing to determine active site concentration during CO{sub 2} gasification. We are investigating the mechanism and the concentration of active sites for steam gasification with transient isotopic tracing. For this technique, the reactant feed is switched from H{sub 2}0 to isotopically-labeled water at the same concentration and tow rate. We can then directly measure, at reaction the concentration of active catalytic sites, their kinetic rate constants, and the presence of more than one rate constant. This procedure allows us to obtain transient kinetic data without perturbing the steady-state surface reactions.

  17. Pressurized reactor system and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, J.M.

    1996-06-18

    A method and apparatus are provided for operating a pressurized reactor system in order to precisely control the temperature within a pressure vessel in order to minimize condensation of corrosive materials from gases on the surfaces of the pressure vessel or contained circulating fluidized bed reactor, and to prevent the temperature of the components from reaching a detrimentally high level, while at the same time allowing quick heating of the pressure vessel interior volume during start-up. Super-atmospheric pressure gas is introduced from the first conduit into the fluidized bed reactor and heat derived reactions such as combustion and gasification are maintained in the reactor. Gas is exhausted from the reactor and pressure vessel through a second conduit. Gas is circulated from one part of the inside volume to another to control the temperature of the inside volume, such as by passing the gas through an exterior conduit which has a heat exchanger, control valve, blower and compressor associated therewith, or by causing natural convection flow of circulating gas within one or more generally vertically extending gas passages entirely within the pressure vessel (and containing heat exchangers, flow rate control valves, or the like therein). Preferably, inert gas is provided as a circulating gas, and the inert gas may also be used in emergency shut-down situations. In emergency shut-down reaction gas being supplied to the reactor is cut off, while inert gas from the interior gas volume of the pressure vessel is introduced into the reactor. 2 figs.

  18. Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification April 10, 2012 - 1:00pm Addthis A rendering of the Pratt & Whitney Rocketdyne high pressure, dry-solids feed pump. A rendering of the Pratt & Whitney Rocketdyne high pressure, dry-solids feed pump. Washington, DC - Gasification. It's a versatile technology that uses coal to produce power, chemicals, and fuels. Inherently

  19. Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration

    DOE Patents [OSTI]

    Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

    1981-09-14

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  20. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology

    SciTech Connect (OSTI)

    Swanson, Michael; Henderson, Ann

    2012-04-01

    The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in

  1. Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Jordi Perez; Marc Hornbostel; Kai-Hung Lau; Angel Sanjurjo

    2007-05-31

    Advanced electric power generation systems use a coal gasifier to convert coal to a gas rich in fuels such as H{sub 2} and CO. The gas stream contains impurities such as H{sub 2}S and HCl, which attack metal components of the coal gas train, causing plant downtime and increasing the cost of power generation. Corrosion-resistant coatings would improve plant availability and decrease maintenance costs, thus allowing the environmentally superior integrated-gasification-combined-cycle (IGCC) plants to be more competitive with standard power-generation technologies. Heat-exchangers, particle filters, turbines, and other components in the IGCC system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low cost alloy will improve is resistance to such sulfidation attack and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. The Fe- and Ni-based high-temperature alloys are susceptible to sulfidation attack unless they are fortified with high levels of Cr, Al, and Si. To impart corrosion resistance, these elements need not be in the bulk of the alloy and need only be present at the surface layers. In this study, the use of corrosion-resistant coatings on low alloy steels was investigated for use as high-temperature components in IGCC systems. The coatings were deposited using SRI's fluidized-bed reactor chemical vapor deposition technique. Diffusion coatings of Cr and Al were deposited by this method on to dense and porous, low alloy stainless steel substrates. Bench-scale exposure tests at 900 C with a simulated coal gas stream containing 1.7% H{sub 2}S showed that the low alloy steels such SS405 and SS409 coated with {approx

  2. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Ohlinger, L.A.; Wigner, E.P.; Weinberg, A.M.; Young, G.J.

    1958-09-01

    This patent relates to neutronic reactors of the heterogeneous water cooled type, and in particular to a fuel element charging and discharging means therefor. In the embodiment illustrated the reactor contains horizontal, parallel coolant tubes in which the fuel elements are disposed. A loading cart containing a magnzine for holding a plurality of fuel elements operates along the face of the reactor at the inlet ends of the coolant tubes. The loading cart is equipped with a ram device for feeding fuel elements from the magazine through the inlot ends of the coolant tubes. Operating along the face adjacent the discharge ends of the tubes there is provided another cart means adapted to receive irradiated fuel elements as they are forced out of the discharge ends of the coolant tubes by the incoming new fuel elements. This cart is equipped with a tank coataining a coolant, such as water, into which the fuel elements fall, and a hydraulically operated plunger to hold the end of the fuel element being discharged. This inveation provides an apparatus whereby the fuel elements may be loaded into the reactor, irradiated therein, and unloaded from the reactor without stopping the fiow of the coolant and without danger to the operating personnel.

  3. Life cycle assessment of a biomass gasification combined-cycle power system

    SciTech Connect (OSTI)

    Mann, M.K.; Spath, P.L.

    1997-12-01

    The potential environmental benefits from biomass power are numerous. However, biomass power may also have some negative effects on the environment. Although the environmental benefits and drawbacks of biomass power have been debated for some time, the total significance has not been assessed. This study serves to answer some of the questions most often raised in regard to biomass power: What are the net CO{sub 2} emissions? What is the energy balance of the integrated system? Which substances are emitted at the highest rates? What parts of the system are responsible for these emissions? To provide answers to these questions, a life cycle assessment (LCA) of a hypothetical biomass power plant located in the Midwest United States was performed. LCA is an analytical tool for quantifying the emissions, resource consumption, and energy use, collectively known as environmental stressors, that are associated with converting a raw material to a final product. Performed in conjunction with a technoeconomic feasibility study, the total economic and environmental benefits and drawbacks of a process can be quantified. This study complements a technoeconomic analysis of the same process, reported in Craig and Mann (1996) and updated here. The process studied is based on the concept of power Generation in a biomass integrated gasification combined cycle (BIGCC) plant. Broadly speaking, the overall system consists of biomass production, its transportation to the power plant, electricity generation, and any upstream processes required for system operation. The biomass is assumed to be supplied to the plant as wood chips from a biomass plantation, which would produce energy crops in a manner similar to the way food and fiber crops are produced today. Transportation of the biomass and other materials is by both rail and truck. The IGCC plant is sized at 113 MW, and integrates an indirectly-heated gasifier with an industrial gas turbine and steam cycle. 63 refs., 34 figs., 32 tabs.

  4. Twenty-First Water Reactor Safety Information Meeting. Volume 3, Primary system integrity; Aging research, products and applications; Structural and seismic engineering; Seismology and geology: Proceedings

    SciTech Connect (OSTI)

    Monteleone, S.

    1994-04-01

    This three-volume report contains 90 papers out of the 102 that were presented at the Twenty-First Water Reactor Safety Information Meeting held at the Bethesda Marriott Hotel, Bethesda, Maryland, during the week of October 25-27, 1993. The papers are printed in the order of their presentation in each session and describe progress and results of programs in nuclear safety research conducted in this country and abroad. Foreign participation in the meeting included papers presented by researchers from France, Germany, Japan, Russia, Switzerland, Taiwan, and United Kingdom. The titles of the papers and the names of the authors have been updated and may differ from those that appeared in the final program of the meeting. Selected papers were indexed separately for inclusion in the Energy Science and Technology Database.

  5. Nuclear Reactors and Technology

    SciTech Connect (OSTI)

    Cason, D.L.; Hicks, S.C.

    1992-01-01

    This publication Nuclear Reactors and Technology (NRT) announces on a monthly basis the current worldwide information available from the open literature on nuclear reactors and technology, including all aspects of power reactors, components and accessories, fuel elements, control systems, and materials. This publication contains the abstracts of DOE reports, journal articles, conference papers, patents, theses, and monographs added to the Energy Science and Technology Database during the past month. Also included are US information obtained through acquisition programs or interagency agreements and international information obtained through the International Energy Agency`s Energy Technology Data Exchange or government-to-government agreements. The digests in NRT and other citations to information on nuclear reactors back to 1948 are available for online searching and retrieval on the Energy Science and Technology Database and Nuclear Science Abstracts (NSA) database. Current information, added daily to the Energy Science and Technology Database, is available to DOE and its contractors through the DOE Integrated Technical Information System. Customized profiles can be developed to provide current information to meet each user`s needs.

  6. Passive compact molten salt reactor (PCMSR), modular thermal breeder reactor with totally passive safety system

    SciTech Connect (OSTI)

    Harto, Andang Widi

    2012-06-06

    Design Study Passive Compact Molten Salt Reactor (PCMSR) with totally passive safety system has been performed. The term of Compact in the PCMSR name means that the reactor system is designed to have relatively small volume per unit power output by using modular and integral concept. In term of modular, the reactor system consists of three modules, i.e. reactor module, turbine module and fuel management module. The reactor module is an integral design that consists of reactor, primary and intermediate heat exchangers and passive post shutdown cooling system. The turbine module is an integral design of a multi heating, multi cooling, regenerative gas turbine. The fuel management module consists of all equipments related to fuel preparation, fuel reprocessing and radioactive handling. The preliminary calculations show that the PCMSR has negative temperature and void reactivity coefficient, passive shutdown characteristic related to fuel pump failure and possibility of using natural circulation for post shutdown cooling system.

  7. Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, G.; Gerdes, K.; Song, X.; Chen, Y.; Shutthanandan, V.; Englehard, M.; Zhu, Z.; Thevuthasan, S.; Gemmen, R.

    2012-01-01

    Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  8. Catalytic reactor

    DOE Patents [OSTI]

    Aaron, Timothy Mark; Shah, Minish Mahendra; Jibb, Richard John

    2009-03-10

    A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

  9. POWER REACTOR

    DOE Patents [OSTI]

    Zinn, W.H.

    1958-07-01

    A fast nuclear reactor system ls described for producing power and radioactive isotopes. The reactor core is of the heterogeneous, fluid sealed type comprised of vertically arranged elongated tubular fuel elements having vertical coolant passages. The active portion is surrounded by a neutron reflector and a shield. The system includes pumps and heat exchangers for the primary and secondary coolant circuits. The core, primary coolant pump and primary heat exchanger are disposed within an irapenforate tank which is filled with the primary coolant, in this case a liquid metal such as Na or NaK, to completely submerge these elements. The tank is completely surrounded by a thick walled concrete shield. This reactor system utilizes enriched uranium or plutonium as the fissionable material, uranium or thorium as a diluent and thorium or uranium containing less than 0 7% of the U/sup 235/ isotope as a fertile material.

  10. REACTOR CONTROL

    DOE Patents [OSTI]

    Fortescue, P.; Nicoll, D.

    1962-04-24

    A control system employed with a high pressure gas cooled reactor in which a control rod is positioned for upward and downward movement into the neutron field from a position beneath the reactor is described. The control rod is positioned by a coupled piston cylinder releasably coupled to a power drive means and the pressurized coolant is directed against the lower side of the piston. The coolant pressure is offset by a higher fiuid pressure applied to the upper surface of the piston and means are provided for releasing the higher pressure on the upper side of the piston so that the pressure of the coolant drives the piston upwardly, forcing the coupled control rod into the ncutron field of the reactor. (AEC)

  11. Bioconversion reactor

    DOE Patents [OSTI]

    McCarty, Perry L.; Bachmann, Andre

    1992-01-01

    A bioconversion reactor for the anaerobic fermentation of organic material. The bioconversion reactor comprises a shell enclosing a predetermined volume, an inlet port through which a liquid stream containing organic materials enters the shell, and an outlet port through which the stream exits the shell. A series of vertical and spaced-apart baffles are positioned within the shell to force the stream to flow under and over them as it passes from the inlet to the outlet port. The baffles present a barrier to the microorganisms within the shell causing them to rise and fall within the reactor but to move horizontally at a very slow rate. Treatment detention times of one day or less are possible.

  12. NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Wigner, E.P.; Young, G.J.

    1958-10-14

    A method is presented for loading and unloading rod type fuel elements of a neutronic reactor of the heterogeneous, solld moderator, liquid cooled type. In the embodiment illustrated, the fuel rods are disposed in vertical coolant channels in the reactor core. The fuel rods are loaded and unloaded through the upper openings of the channels which are immersed in the coolant liquid, such as water. Unloading is accomplished by means of a coffer dam assembly having an outer sleeve which is placed in sealing relation around the upper opening. A radiation shield sleeve is disposed in and reciprocable through the coffer dam sleeve. A fuel rod engaging member operates through the axial bore in the radiation shield sleeve to withdraw the fuel rod from its position in the reactor coolant channel into the shield, the shield snd rod then being removed. Loading is accomplished in the reverse procedure.

  13. Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

    SciTech Connect (OSTI)

    Wiser, W. H.

    1980-09-01

    Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

  14. Thermochemical Ethanol via Direct Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Dutta, A.; Phillips, S. D.

    2009-07-01

    This report evaluates process design and technoeconomic criteria for a direct gasification process for conversion of biomass to ethanol. Follow-up to NREL/TP-510-41168.

  15. EA-1219: Hoe Creek Underground Coal Gasification Test Site Remediation, Campbell County, Wyoming

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposed Hoe Creek Underground Coal Gasification Test Site Remediation that would be performed at the Hoe Creek site in Campbell County, Wyoming.

  16. Recent regulatory experience of low-Btu coal gasification. Volume III. Supporting case studies

    SciTech Connect (OSTI)

    Ackerman, E.; Hart, D.; Lethi, M.; Park, W.; Rifkin, S.

    1980-02-01

    The MITRE Corporation conducted a five-month study for the Office of Resource Applications in the Department of Energy on the regulatory requirements of low-Btu coal gasification. During this study, MITRE interviewed representatives of five current low-Btu coal gasification projects and regulatory agencies in five states. From these interviews, MITRE has sought the experience of current low-Btu coal gasification users in order to recommend actions to improve the regulatory process. This report is the third of three volumes. It contains the results of interviews conducted for each of the case studies. Volume 1 of the report contains the analysis of the case studies and recommendations to potential industrial users of low-Btu coal gasification. Volume 2 contains recommendations to regulatory agencies.

  17. INTEGRATED PYROLYSIS COMBINED CYCLE BIOMASS POWER SYSTEM CONCEPT DEFINITION

    SciTech Connect (OSTI)

    Eric Sandvig; Gary Walling; Robert C. Brown; Ryan Pletka; Desmond Radlein; Warren Johnson

    2003-03-01

    Advanced power systems based on integrated gasification/combined cycles (IGCC) are often presented as a solution to the present shortcomings of biomass as fuel. Although IGCC has been technically demonstrated at full scale, it has not been adopted for commercial power generation. Part of the reason for this situation is the continuing low price for coal. However, another significant barrier to IGCC is the high level of integration of this technology: the gas output from the gasifier must be perfectly matched to the energy demand of the gas turbine cycle. We are developing an alternative to IGCC for biomass power: the integrated (fast) pyrolysis/ combined cycle (IPCC). In this system solid biomass is converted into liquid rather than gaseous fuel. This liquid fuel, called bio-oil, is a mixture of oxygenated organic compounds and water that serves as fuel for a gas turbine topping cycle. Waste heat from the gas turbine provides thermal energy to the steam turbine bottoming cycle. Advantages of the biomass-fueled IPCC system include: combined cycle efficiency exceeding 37 percent efficiency for a system as small as 7.6 MW{sub e}; absence of high pressure thermal reactors; decoupling of fuel processing and power generation; and opportunities for recovering value-added products from the bio-oil. This report provides a technical overview of the system including pyrolyzer design, fuel clean-up strategies, pyrolysate condenser design, opportunities for recovering pyrolysis byproducts, gas turbine cycle design, and Rankine steam cycle. The report also reviews the potential biomass fuel supply in Iowa, provide and economic analysis, and present a summery of benefits from the proposed system.

  18. (Reactor dosimetry)

    SciTech Connect (OSTI)

    West, C.D.

    1990-09-13

    The lead in most aspects of research reactor design and use passed from the USA about 15 years ago, soon after the construction of the HFIR and HFBR. The Europeans have consistently upgraded and improved their existing facilities and have built new ones including the HFR at Grenoble and ORPHEE at Saclay. They studied ultra-high flux concepts ({approximately}10{sup 20}/m{sup {minus}2}{center dot}s{sup {minus}1}) about 10 years ago, and are in the design phase of a new, highly efficient medium flux reactor to be built at Garching, near Munich in Germany. A visit was made to Interatom, the firm -- the equivalent of the Architect/Engineer for the ANS project -- responsible, under contract to the Technical University of Munich, for the new Munich reactor design. There are many similarities to the ANS design, and we reviewed and discussed technical and safety aspects of the two reactors. A request was made for some new, hitherto proprietary, experimental data on reactor thermal hydraulics and cooling that will be very valuable to the ANS project. I presented a seminar on the ANS project. A visit was made to Kernforschungszentrum Karlsruhe and knowledge was gained from Dr. Kuchle, a true pioneer of ultra-high flux reactor concepts, of their work. Dr. Kuchle kindly reviewed the ANS reference core and cooling system design (with favorable conclusions). I then talked with researchers working on materials irradiation damage and activation of structural materials by neutron irradiation, both key issues for the ANS. I was shown some new techniques they have developed for testing materials irradiation effects at high fluences, in a short time, using accelerated particle beams.

  19. Proceedings of the ninth annual underground coal gasification symposium

    SciTech Connect (OSTI)

    Wieber, P.R.; Martin, J.W.; Byrer, C.W.

    1983-12-01

    The Ninth Underground Coal Gasification Symposium was held August 7 to 10, 1983 at the Indian Lakes Resort and Conference Center in Bloomingdale, Illinois. Over one-hundred attendees from industry, academia, National Laboratories, State Government, and the US Government participated in the exchange of ideas, results and future research plans. Representatives from six countries including France, Belgium, United Kingdom, The Netherlands, West Germany, and Brazil also participated by presenting papers. Fifty papers were presented and discussed in four formal sessions and two informal poster sessions. The presentations described current and future field testing plans, interpretation of field test data, environmental research, laboratory studies, modeling, and economics. All papers were processed for inclusion in the Energy Data Base.

  20. Metallic heat exchangers for coal gasification. Final report

    SciTech Connect (OSTI)

    Natesan, K.

    1984-05-01

    A high-temperature corrosion program is being conducted to evaluate the corrosion behavior of selected metallic alloys and coatings in mixed-gas atmospheres for application in heat recovery systems of coal gasification schemes. The experiments conducted with internally air-cooled specimens have established three key variables, namely the gas temperature, metal temperature, and gas chemistry. In addition, the alloy chemistry and exposure time have a strong influence on the corrosion scale morphologies and metal recession rates. The results showed that the scale growth in carbon steel and low- to medium-chromium steels is predominantly linear with time. Selection of these materials will be primarily based upon acceptable corrosion wastage rate. On the other hand, high-chromium alloys can develop thin oxide scales resulting in negligible wastage via corrosion, but are susceptible to accelerated corrosion in mixed-gas atmospheres.

  1. Process for control of pollutants generated during coal gasification

    DOE Patents [OSTI]

    Frumerman, Robert; Hooper, Harold M.

    1979-01-01

    The present invention is directed to an improvement in the coal gasification process that effectively eliminates substantially all of the environmental pollutants contained in the producer gas. The raw producer gas is passed through a two-stage water scrubbing arrangement with the tars being condensed essentially water-free in the first stage and lower boiling condensables, including pollutant laden water, being removed in the second stage. The pollutant-laden water is introduced into an evaporator in which about 95 percent of the water is vaporized and introduced as steam into the gas producer. The condensed tars are combusted and the resulting products of combustion are admixed with the pollutant-containing water residue from the evaporator and introduced into the gas producer.

  2. First results, problems of French deep gasification program

    SciTech Connect (OSTI)

    Gaussens, P.

    1983-01-01

    The development of a technology for the gasification of deep coal reserves that are technically and economically not exploitable by classic mining methods was investigated. The principal problem is the very low permeability of the deep coal which makes it necessary to create an artificial connection between the injection and production wells which is done of hydrofracturing method. The possibilities of an electrical connection are studied. Difficulties related to the spontaneous ignition of the coal and the creation of a backward combustion are revealed. Exploration of the factors that might limit the quality of the gas produced or the quantity of coal extracted by doublet is suggested which should lead to obtaining criteria for site selection. Knowledge of the natural conditions of a site is essential for the decision and the selection of the operating method. The characterization can be obtained by using exploration methods such as coring, logging, surface geophysics.

  3. Gasification CFD Modeling for Advanced Power Plant Simulations

    SciTech Connect (OSTI)

    Zitney, S.E.; Guenther, C.P.

    2005-09-01

    In this paper we have described recent progress on developing CFD models for two commercial-scale gasifiers, including a two-stage, coal slurry-fed, oxygen-blown, pressurized, entrained-flow gasifier and a scaled-up design of the PSDF transport gasifier. Also highlighted was NETL’s Advanced Process Engineering Co-Simulator for coupling high-fidelity equipment models with process simulation for the design, analysis, and optimization of advanced power plants. Using APECS, we have coupled the entrained-flow gasifier CFD model into a coal-fired, gasification-based FutureGen power and hydrogen production plant. The results for the FutureGen co-simulation illustrate how the APECS technology can help engineers better understand and optimize gasifier fluid dynamics and related phenomena that impact overall power plant performance.

  4. Method for gasification of deep, thin coal seams

    DOE Patents [OSTI]

    Gregg, David W.

    1982-01-01

    A method of gasification of coal in deep, thin seams by using controlled bending subsidence to confine gas flow to a region close to the unconsumed coal face. The injection point is moved sequentially around the perimeter of a coal removal area from a production well to sweep out the area to cause the controlled bending subsidence. The injection holes are drilled vertically into the coal seam through the overburden or horizontally into the seam from an exposed coal face. The method is particularly applicable to deep, thin seams found in the eastern United States and at abandoned strip mines where thin seams were surface mined into a hillside or down a modest dip until the overburden became too thick for further mining.

  5. Method for gasification of deep, thin coal seams. [DOE patent

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-29

    A method of gasification of coal in deep, thin seams by using controlled bending subsidence to confine gas flow to a region close to the unconsumed coal face is given. The injection point is moved sequentially around the perimeter of a coal removal area from a production well to sweep out the area to cause the controlled bending subsidence. The injection holes are drilled vertically into the coal seam through the overburden or horizontally into the seam from an exposed coal face. The method is particularly applicable to deep, thin seams found in the eastern United States and at abandoned strip mines where thin seams were surface mined into a hillside or down a modest dip until the overburden became too thick for further mining.

  6. Integrating catalytic coal gasifiers with solid oxide fuel cells

    SciTech Connect (OSTI)

    Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

    2010-01-01

    A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

  7. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Fermi, E.; Szilard, L.

    1957-09-24

    Reactors of the type employing plates of natural uranium in a moderator are discussed wherein the plates are um-formly disposed in parallel relationship to each other thereby separating the moderator material into distinct and individual layers. Each plate has an uninterrupted sunface area substantially equal to the cross-sectional area of the active portion of the reactor, the particular size of the plates and the volume ratio of moderator to uranium required to sustain a chain reaction being determinable from the known purity of these materials and other characteristics such as the predictable neutron losses due to the formation of radioactive elements of extremely high neutron capture cross section.

  8. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Wigner, E.P.; Weinberg, A.W.; Young, G.J.

    1958-04-15

    A nuclear reactor which uses uranium in the form of elongated tubes as fuel elements and liquid as a coolant is described. Elongated tubular uranium bodies are vertically disposed in an efficient neutron slowing agent, such as graphite, for example, to form a lattice structure which is disposed between upper and lower coolant tanks. Fluid coolant tubes extend through the uranium bodies and communicate with the upper and lower tanks and serve to convey the coolant through the uranium body. The reactor is also provided with means for circulating the cooling fluid through the coolant tanks and coolant tubes, suitable neutron and gnmma ray shields, and control means.

  9. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Young, G.

    1963-01-01

    This patent covers a power-producing nuclear reactor in which fuel rods of slightly enriched U are moderated by heavy water and cooled by liquid metal. The fuel rods arranged parallel to one another in a circle are contained in a large outer closed-end conduit that extends into a tank containing the heavy water. Liquid metal is introduced into the large conduit by a small inner conduit that extends within the circle of fuel rods to a point near the lower closed end of the outer conduit. (AEC) Production Reactors

  10. Effects of effluents of coal combustion and gasification upon lung structure and function. Annual report

    SciTech Connect (OSTI)

    Hinton, D.E.

    1980-01-01

    The overall objective of the proposed research is to correlate both structural and functional alterations in cells and tissues of the lung brought about by exposure to fluidized bed combustion and fixed bed gasification effluents and reagent grade oxides of metals known to be associated with coal combustion gasification. Projected milestones are described. Progress during the first year in setting up aerosol exposure facilities, intratracheal instillations, pulmonary mechanics, and morphometric examinations is reported. (DMC)

  11. Plasma-enhanced gasification of low-grade coals for compact power plants

    SciTech Connect (OSTI)

    Uhm, Han S.; Hong, Yong C.; Shin, Dong H.; Lee, Bong J.

    2011-10-15

    A high temperature of a steam torch ensures an efficient gasification of low-grade coals, which is comparable to that of high-grade coals. Therefore, the coal gasification system energized by microwaves can serve as a moderately sized power plant due to its compact and lightweight design. This plasma power plant of low-grade coals would be useful in rural or sparsely populated areas without access to a national power grid.

  12. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect (OSTI)

    Not Available

    1981-03-31

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  13. 2015 Gasification Systems and Coal and Coal-Biomass to Liquids Workshop |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    netl.doe.gov 5 Gasification Systems and Coal & Coal-Biomass to Liquids Workshop Workshop Summary Additional materials will be added when they are received from the author. Presentations Monday, August 10, 2015 Welcome and Introduction Jenny Tennant, Technology Manager for Gasification and C&CBTL U.S. Department of Energy, National Energy Technology Laboratory Wyoming Coal's Role in the World-Recent Past, Present and Future Don Collins, CEO of the Western Research Institute SESSION I

  14. Ground movements associated with large-scale underground coal gasification

    SciTech Connect (OSTI)

    Siriwardane, H.J.; Layne, A.W.

    1989-09-01

    The primary objective of this work was to predict the surface and underground movement associated with large-scale multiwell burn sites in the Illinois Basin and Appalachian Basin by using the subsidence/thermomechanical model UCG/HEAT. This code is based on the finite element method. In particular, it can be used to compute (1) the temperature field around an underground cavity when the temperature variation of the cavity boundary is known, and (2) displacements and stresses associated with body forces (gravitational forces) and a temperature field. It is hypothesized that large Underground Coal Gasification (UCG) cavities generated during the line-drive process will be similar to those generated by longwall mining. If that is the case, then as a UCG process continues, the roof of the cavity becomes unstable and collapses. In the UCG/HEAT computer code, roof collapse is modeled using a simplified failure criterion (Lee 1985). It is anticipated that roof collapse would occur behind the burn front; therefore, forward combustion can be continued. As the gasification front propagates, the length of the cavity would become much larger than its width. Because of this large length-to-width ratio in the cavity, ground response behavior could be analyzed by considering a plane-strain idealization. In a plane-strain idealization of the UCG cavity, a cross-section perpendicular to the axis of propagation could be considered, and a thermomechanical analysis performed using a modified version of the two-dimensional finite element code UCG/HEAT. 15 refs., 9 figs., 3 tabs.

  15. Neutronic reactor

    DOE Patents [OSTI]

    Wende, Charles W. J.; Babcock, Dale F.; Menegus, Robert L.

    1983-01-01

    A nuclear reactor includes an active portion with fissionable fuel and neutron moderating material surrounded by neutron reflecting material. A control element in the active portion includes a group of movable rods constructed of neutron-absorbing material. Each rod is movable with respect to the other rods to vary the absorption of neutrons and effect control over neutron flux.

  16. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Starr, C.

    1963-01-01

    This patent relates to a combination useful in a nuclear reactor and is comprised of a casing, a mass of graphite irapregnated with U compounds in the casing, and at least one coolant tube extending through the casing. The coolant tube is spaced from the mass, and He is irtroduced irto the space between the mass and the coolant tube. (AEC)

  17. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Creutz, E.C.; Ohlinger, L.A.; Weinberg, A.M.; Wigner, E.P.; Young, G.J.

    1959-10-27

    BS>A reactor cooled by water, biphenyl, helium, or other fluid with provision made for replacing the fuel rods with the highest plutonium and fission product content without disassembling the entire core and for promptly cooling the rods after their replacement in order to prevent build-up of heat from fission product activity is described.

  18. Neutronic reactor

    DOE Patents [OSTI]

    Wende, Charles W. J.

    1976-08-17

    A safety rod for a nuclear reactor has an inner end portion having a gamma absorption coefficient and neutron capture cross section approximately equal to those of the adjacent shield, a central portion containing materials of high neutron capture cross section and an outer end portion having a gamma absorption coefficient at least equal to that of the adjacent shield.

  19. Neutronic reactor

    DOE Patents [OSTI]

    Carleton, John T.

    1977-01-25

    A graphite-moderated nuclear reactor includes channels between blocks of graphite and also includes spacer blocks between adjacent channeled blocks with an axis of extension normal to that of the axis of elongation of the channeled blocks to minimize changes in the physical properties of the graphite as a result of prolonged neutron bombardment.

  20. NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Anderson, H.L.

    1958-10-01

    The design of control rods for nuclear reactors are described. In this design the control rod consists essentially of an elongated member constructed in part of a neutron absorbing material and having tube means extending therethrough for conducting a liquid to cool the rod when in use.

  1. Nuclear Reactors and Technology; (USA)

    SciTech Connect (OSTI)

    Cason, D.L.; Hicks, S.C.

    1991-01-01

    Nuclear Reactors and Technology (NRT) announces on a monthly basis the current worldwide information available from the open literature on nuclear reactors and technology, including all aspects of power reactors, components and accessories, fuel elements, control systems, and materials. This publication contains the abstracts of DOE reports, journal articles, conference papers, patents, theses, and monographs added to the Energy Science and Technology Database (EDB) during the past month. Also included are US information obtained through acquisition programs or interagency agreements and international information obtained through the International Energy Agency's Energy Technology Data Exchange or government-to-government agreements. The digests in NRT and other citations to information on nuclear reactors back to 1948 are available for online searching and retrieval on EDB and Nuclear Science Abstracts (NSA) database. Current information, added daily to EDB, is available to DOE and its contractors through the DOE integrated Technical Information System. Customized profiles can be developed to provide current information to meet each user's needs.

  2. Electrorefining {open_quotes}N{close_quotes} reactor fuel

    SciTech Connect (OSTI)

    Gay, E.C.; Miller, W.E.

    1995-02-01

    Principles of purifying of uranium metal by electrorefining are reviewed. Metal reactor fuel after irradiation is a form of impure uranium. Dissolution and deposition electrorefining processes were developed for spent metal fuel under the Integral Fast Reactor Program. Application of these processes to the conditioning of spent N-reactor fuel slugs is examined.

  3. Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment

    SciTech Connect (OSTI)

    Kevin Whitty

    2008-06-30

    The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at

  4. Hydrothermal Processing of Macroalgal Feedstocks in Continuous-Flow Reactors

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Roesijadi, Guritno; Zacher, Alan H.; Magnuson, Jon K.

    2014-02-18

    Wet macroalgal slurries can be converted into a biocrude by hydrothermal liquefaction (HTL). High levels of carbon conversion to gravity-separable oil product were accomplished at relatively low temperature (350 C) in a pressurized (sub-critical liquid water) environment (20 MPa). As opposed to earlier work in batch reactors reported by others, direct oil recovery was achieved without the use of a solvent and biomass trace mineral components were removed by processing steps so that they did not cause processing difficulties. In addition, catalytic hydrothermal gasification was effectively applied for HTL byproduct water cleanup and fuel gas production from water soluble organics. As a result, high conversion of macroalgae to liquid and gas fuel products was found with low levels of organic contamination in byproduct water. Both process steps were accomplished in continuous-flow reactor systems such that design data for process scale-up was generated.

  5. REACTOR MONITORING

    DOE Patents [OSTI]

    Bugbee, S.J.; Hanson, V.F.; Babcock, D.F.

    1959-02-01

    A neutron density inonitoring means for reactors is described. According to this invention a tunnel is provided beneath and spaced from the active portion of the reactor and extends beyond the opposite faces of the activc portion. Neutron beam holes are provided between the active portion and the tunnel and open into the tunnel near the middle thereof. A carriage operates back and forth in the tunnel and is adapted to convey a neutron detector, such as an ion chamber, and position it beneath one of the neutron beam holes. This arrangement affords convenient access of neutron density measuring instruments to a location wherein direct measurement of neutron density within the piles can be made and at the same time affords ample protection to operating personnel.

  6. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Treshow, M.

    1958-08-19

    A neuclear reactor is described of the heterogeneous type and employing replaceable tubular fuel elements and heavy water as a coolant and moderator. A pluraltty of fuel tubesa having their axes parallel, extend through a tank type pressure vessel which contatns the liquid moderator. The fuel elements are disposed within the fuel tubes in the reaetive portion of the pressure vessel during normal operation and the fuel tubes have removable plug members at each end to permit charging and discharging of the fuel elements. The fuel elements are cylindrical strands of jacketed fissionable material having helical exterior ribs. A bundle of fuel elements are held within each fuel tube with their longitudinal axes parallel, the ribs serving to space them apart along their lengths. Coolant liquid is circulated through the fuel tubes between the spaced fuel elements. Suitable control rod and monitoring means are provided for controlling the reactor.

  7. REACTOR UNLOADING

    DOE Patents [OSTI]

    Leverett, M.C.

    1958-02-18

    This patent is related to gas cooled reactors wherein the fuel elements are disposed in vertical channels extending through the reactor core, the cooling gas passing through the channels from the bottom to the top of the core. The invention is a means for unloading the fuel elements from the core and comprises dump values in the form of flat cars mounted on wheels at the bottom of the core structure which support vertical stacks of fuel elements. When the flat cars are moved, either manually or automatically, for normal unloading purposes, or due to a rapid rise in the reproduction ratio within the core, the fuel elements are permtted to fall by gravity out of the core structure thereby reducing the reproduction ratio or stopping the reaction as desired.

  8. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Wade, E.J.

    1958-09-16

    This patent relates to a reflector means for a neutronic reactor. A reflector comprised of a plurality of vertically movable beryllium control members is provided surrounding the sides of the reactor core. An absorber of fast neutrons comprised of natural uramum surrounds the reflector. An absorber of slow neutrons surrounds the absorber of fast neutrons and is formed of a plurality of beryllium blocks having natural uranium members distributcd therethrough. in addition, a movable body is positioned directly below the core and is comprised of a beryllium reflector and an absorbing member attached to the botiom thereof, the absorbing member containing a substance selected from the goup consisting of natural urantum and Th/sup 232/.

  9. Nuclear reactor

    DOE Patents [OSTI]

    Wade, Elman E.

    1979-01-01

    A nuclear reactor including two rotatable plugs and a positive top core holddown structure. The top core holddown structure is divided into two parts: a small core cover, and a large core cover. The small core cover, and the upper internals associated therewith, are attached to the small rotating plug, and the large core cover, with its associated upper internals, is attached to the large rotating plug. By so splitting the core holddown structures, under-the-plug refueling is accomplished without the necessity of enlarging the reactor pressure vessel to provide a storage space for the core holddown structure during refueling. Additionally, the small and large rotating plugs, and their associated core covers, are arranged such that the separation of the two core covers to permit rotation is accomplished without the installation of complex lifting mechanisms.

  10. NUCLEAR REACTOR

    DOE Patents [OSTI]

    Grebe, J.J.

    1959-12-15

    A reactor which is particularly adapted tu serve as a heat source for a nuclear powered alrcraft or rocket is described. The core of this reactor consists of a porous refractory modera;or body which is impregnated with fissionable nuclei. The core is designed so that its surface forms tapered inlet and outlet ducts which are separated by the porous moderator body. In operation a gaseous working fluid is circulated through the inlet ducts to the surface of the moderator, enters and passes through the porous body, and is heated therein. The hot gas emerges into the outlet ducts and is available to provide thrust. The principle advantage is that tremendous quantities of gas can be quickly heated without suffering an excessive pressure drop.

  11. Economic development through biomass system integration: Volume 1

    SciTech Connect (OSTI)

    DeLong, M.M.

    1995-10-01

    This report documents a feasibility study for an integrated biomass power system, where an energy crop (alfalfa) is the feedstock for a processing plant and a power plant (integrated gasification combined cycle) in a way that benefits the facility owners. Chapters describe alfalfa basics, production risks, production economics, transportation and storage, processing, products, market analysis, business analysis, environmental impact, and policy issues. 69 figs., 63 tabs.

  12. NUCLEAR REACTORS

    DOE Patents [OSTI]

    Long, E.; Ashby, J.W.

    1958-09-16

    ABS>A graphite moderator structure is presented for a nuclear reactor compriscd of an assembly of similarly orientated prismatic graphite blocks arranged on spaced longitudinal axes lying in common planes wherein the planes of the walls of the blocks are positioned so as to be twisted reintive to the planes of said axes so thatthe unlmpeded dtrect paths in direction wholly across the walls of the blocks are limited to the width of the blocks plus spacing between the blocks.

  13. Neutronic reactor

    DOE Patents [OSTI]

    Lewis, Warren R.

    1978-05-30

    A graphite-moderated, water-cooled nuclear reactor including a plurality of rectangular graphite blocks stacked in abutting relationship in layers, alternate layers having axes which are normal to one another, alternate rows of blocks in alternate layers being provided with a channel extending through the blocks, said channeled blocks being provided with concave sides and having smaller vertical dimensions than adjacent blocks in the same layer, there being nuclear fuel in the channels.

  14. NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Anderson, J.B.

    1960-01-01

    A reactor is described which comprises a tank, a plurality of coaxial steel sleeves in the tank, a mass of water in the tank, and wire grids in abutting relationship within a plurality of elongated parallel channels within the steel sleeves, the wire being provided with a plurality of bends in the same plane forming adjacent parallel sections between bends, and the sections of adjacent grids being normally disposed relative to each other.

  15. REACTOR CONTROL

    DOE Patents [OSTI]

    Ruano, W.J.

    1957-12-10

    This patent relates to nuclear reactors of the type which utilize elongited rod type fuel elements immersed in a liquid moderator and shows a design whereby control of the chain reaction is obtained by varying the amount of moderator or reflector material. A central tank for containing liquid moderator and fuel elements immersed therein is disposed within a surrounding outer tank providing an annular space between the two tanks. This annular space is filled with liquid moderator which functions as a reflector to reflect neutrons back into the central reactor tank to increase the reproduction ratio. Means are provided for circulating and cooling the moderator material in both tanks and additional means are provided for controlling separately the volume of moderator in each tank, which latter means may be operated automatically by a neutron density monitoring device. The patent also shows an arrangement for controlling the chain reaction by injecting and varying an amount of poisoning material in the moderator used in the reflector portion of the reactor.

  16. Energy, Environmental, and Economic Analyses of Design Concepts for the Co-Production of Fuels and Chemicals with Electricity via Co-Gasification of Coal and Biomass

    SciTech Connect (OSTI)

    Eric Larson; Robert Williams; Thomas Kreutz; Ilkka Hannula; Andrea Lanzini; Guangjian Liu

    2012-03-11

    The overall objective of this project was to quantify the energy, environmental, and economic performance of industrial facilities that would coproduce electricity and transportation fuels or chemicals from a mixture of coal and biomass via co-gasification in a single pressurized, oxygen-blown, entrained-flow gasifier, with capture and storage of CO{sub 2} (CCS). The work sought to identify plant designs with promising (Nth plant) economics, superior environmental footprints, and the potential to be deployed at scale as a means for simultaneously achieving enhanced energy security and deep reductions in U.S. GHG emissions in the coming decades. Designs included systems using primarily already-commercialized component technologies, which may have the potential for near-term deployment at scale, as well as systems incorporating some advanced technologies at various stages of R&D. All of the coproduction designs have the common attribute of producing some electricity and also of capturing CO{sub 2} for storage. For each of the co-product pairs detailed process mass and energy simulations (using Aspen Plus software) were developed for a set of alternative process configurations, on the basis of which lifecycle greenhouse gas emissions, Nth plant economic performance, and other characteristics were evaluated for each configuration. In developing each set of process configurations, focused attention was given to understanding the influence of biomass input fraction and electricity output fraction. Self-consistent evaluations were also carried out for gasification-based reference systems producing only electricity from coal, including integrated gasification combined cycle (IGCC) and integrated gasification solid-oxide fuel cell (IGFC) systems. The reason biomass is considered as a co-feed with coal in cases when gasoline or olefins are co-produced with electricity is to help reduce lifecycle greenhouse gas (GHG) emissions for these systems. Storing biomass-derived CO

  17. Chapter 8: Pyrolysis Mechanisms of Lignin Model Compounds Using a Heated Micro-Reactor

    SciTech Connect (OSTI)

    Robichaud, David J.; Nimlos, Mark R.; Ellison, G. Barney

    2015-10-03

    Lignin is an important component of biomass, and the decomposition of its thermal deconstruction products is important in pyrolysis and gasification. In this chapter, we investigate the unimolecular pyrolysis chemistry through the use of singly and doubly substituted benzene molecules that are model compounds representative of lignin and its primary pyrolysis products. These model compounds are decomposed in a heated micro-reactor, and the products, including radicals and unstable intermediates, are measured using photoionization mass spectrometry and matrix isolation infrared spectroscopy. We show that the unimolecular chemistry can yield insight into the initial decomposition of these species. At pyrolysis and gasification severities, singly substituted benzenes typically undergo bond scission and elimination reactions to form radicals. Some require radical-driven chain reactions. For doubly substituted benzenes, proximity effects of the substituents can change the reaction pathways.

  18. Apparatus, components and operating methods for circulating fluidized bed transport gasifiers and reactors

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2015-02-24

    The improvements proposed in this invention provide a reliable apparatus and method to gasify low rank coals in a class of pressurized circulating fluidized bed reactors termed "transport gasifier." The embodiments overcome a number of operability and reliability problems with existing gasifiers. The systems and methods address issues related to distribution of gasification agent without the use of internals, management of heat release to avoid any agglomeration and clinker formation, specific design of bends to withstand the highly erosive environment due to high solid particles circulation rates, design of a standpipe cyclone to withstand high temperature gasification environment, compact design of seal-leg that can handle high mass solids flux, design of nozzles that eliminate plugging, uniform aeration of large diameter Standpipe, oxidant injection at the cyclone exits to effectively modulate gasifier exit temperature and reduction in overall height of the gasifier with a modified non-mechanical valve.

  19. PID Control Effectiveness for Surface Reactor Concepts

    SciTech Connect (OSTI)

    Dixon, David D.; Marsh, Christopher L.; Poston, David I.

    2007-01-30

    Control of space and surface fission reactors should be kept as simple as possible, because of the need for high reliability and the difficulty to diagnose and adapt to control system failures. Fortunately, compact, fast-spectrum, externally controlled reactors are very simple in operation. In fact, for some applications it may be possible to design low-power surface reactors without the need for any reactor control after startup; however, a simple proportional, integral, derivative (PID) controller can allow a higher performance concept and add more flexibility to system operation. This paper investigates the effectiveness of a PID control scheme for several anticipated transients that a surface reactor might experience. To perform these analyses, the surface reactor transient code FRINK was modified to simulate control drum movements based on bulk coolant temperature.

  20. Chemical Processing in High-Pressure Aqueous Environments. 9. Process Development for Catalytic Gasification of Algae Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.

    2012-07-26

    Through the use of a metal catalyst, gasification of wet algae slurries can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In a pressurized-water environment (20 MPa), near-total conversion of the organic structure of the algae to gases has been achieved in the presence of a supported ruthenium metal catalyst. The process is essentially steam reforming, as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high levels of methane, as dictated by thermodynamic equilibrium. As opposed to earlier work, biomass trace components were removed by processing steps so that they did not cause processing difficulties in the fixed catalyst bed tubular reactor system. As a result, the algae feedstocks, even those with high ash contents, were much more reliably processed. High conversions were obtained even with high slurry concentrations. Consistent catalyst operation in these short-term tests suggested good stability and minimal poisoning effects. High methane content in the product gas was noted with significant carbon dioxide captured in the aqueous byproduct in combination with alkali constituents and the ammonia byproduct derived from proteins in the algae. High conversion of algae to gas products was found with low levels of byproduct water contamination and low to moderate loss of carbon in the mineral separation step.

  1. Development of an advanced, continuous mild gasification process for the production of co-products technical evaluation

    SciTech Connect (OSTI)

    Ness, R.O. Jr.; Runge, B.; Sharp, L.

    1992-11-01

    The University of North Dakota Energy and Environmental Research Center (EERC) and the AMAX Research and Development Center are cooperating in the development of a Mild Gasification process that will rapidly devolatilize coals of all ranks at relatively low temperatures between 930[degree] and 1470[degree]F (500[degree]and 800[degree]C) and near atmospheric pressure to produce primary products that include a reactive char, a hydrocarbon condensate, and a low-Btu gas. These will be upgraded in a coal refinery'' system having the flexibility to optimize products based on market demand. Task 2 of the four-task development sequence primarily covered bench-scale testing on a 10-gram thermogravimetric analyzer (TGA) and a 1 to 4-lb/hr continuous fluidized-bed reactor (CFBR). Tests were performed to determine product yields and qualities for the two major test coals-one a high-sulfur bituminous coal from the Illinois Basin (Indiana No. 3) and the other a low-sulfur subbituminous coal from the Powder River Basin (Wyodak). Results from Task 3, on product upgrading tests performed by AMAX Research and Development (R D), are also reported. Task 4 included the construction, operation of a Process Research Unit (PRU), and the upgrading of the products. An economic evaluation of a commercial facility was made, based on the data produced in the PRU, CFBR, and the physical cleaning steps.

  2. Development of an advanced, continuous mild gasification process for the production of co-products technical evaluation. Final report

    SciTech Connect (OSTI)

    Ness, R.O. Jr.; Runge, B.; Sharp, L.

    1992-11-01

    The University of North Dakota Energy and Environmental Research Center (EERC) and the AMAX Research and Development Center are cooperating in the development of a Mild Gasification process that will rapidly devolatilize coals of all ranks at relatively low temperatures between 930{degree} and 1470{degree}F (500{degree}and 800{degree}C) and near atmospheric pressure to produce primary products that include a reactive char, a hydrocarbon condensate, and a low-Btu gas. These will be upgraded in a ``coal refinery`` system having the flexibility to optimize products based on market demand. Task 2 of the four-task development sequence primarily covered bench-scale testing on a 10-gram thermogravimetric analyzer (TGA) and a 1 to 4-lb/hr continuous fluidized-bed reactor (CFBR). Tests were performed to determine product yields and qualities for the two major test coals-one a high-sulfur bituminous coal from the Illinois Basin (Indiana No. 3) and the other a low-sulfur subbituminous coal from the Powder River Basin (Wyodak). Results from Task 3, on product upgrading tests performed by AMAX Research and Development (R&D), are also reported. Task 4 included the construction, operation of a Process Research Unit (PRU), and the upgrading of the products. An economic evaluation of a commercial facility was made, based on the data produced in the PRU, CFBR, and the physical cleaning steps.

  3. Treatment of biomass gasification wastewaters using reverse osmosis

    SciTech Connect (OSTI)

    Petty, S.E.; Eliason, S.D.; Laegreid, M.M.

    1981-09-01

    Reverse osmosis (RO) was evaluated as a treatment technology for the removal of organics from biomass gasification wastewaters (BGW) generated from an experimental biomass gasifier at Texas Tech University. Wastewaters were characteristically high in chemical oxygen demand (COD) with initial values ranging from 32,000 to 68,000 mg/1. Since RO is normally considered a complementary treatment technology, wastewaters were pretreated by biological or wet air oxidation (WAO) processes. One set of experiments were run using untreated wastewaters to compare membrane performance with those experiments using pretreated wastewaters. Experiments were run for 8 to 10 hrs using UOP's TFC-85 membrane operating at 700 psig and 18 to 20/sup 0/C. This membrane is similar to the NS-100, a membrane known for being effective in the separation of organics from solution. Separation of organics from solution was determined by COD removal. Removal percentages for biologically pretreated wastewaters averaged 98% except for one group of runs averaging 69% removal. This exception was probably due to the presence of milk solids in the feed. Use of RO on WAO pretreated wastewaters and unpretreated feeds resulted in 90% COD removal. Membrane degradation was observed when using full-strength and WAO pretreated feeds, but not when using feeds that had undergone biological pretreatment. Color removal was computed for the majority of experiments completed. Overall, 99 to 100% of the total color was removed from BGW feeds, values which coincide with those reported in the literature for other wastewaters.

  4. Techno-Economic Analysis of Biofuels Production Based on Gasification

    SciTech Connect (OSTI)

    Swanson, R. M.; Platon, A.; Satrio, J. A.; Brown, R. C.; Hsu, D. D.

    2010-11-01

    This study compares capital and production costs of two biomass-to-liquid production plants based on gasification. The first biorefinery scenario is an oxygen-fed, low-temperature (870?C), non-slagging, fluidized bed gasifier. The second scenario is an oxygen-fed, high-temperature (1,300?C), slagging, entrained flow gasifier. Both are followed by catalytic Fischer-Tropsch synthesis and hydroprocessing to naphtha-range (gasoline blend stock) and distillate-range (diesel blend stock) liquid fractions. Process modeling software (Aspen Plus) is utilized to organize the mass and energy streams and cost estimation software is used to generate equipment costs. Economic analysis is performed to estimate the capital investment and operating costs. Results show that the total capital investment required for nth plant scenarios is $610 million and $500 million for high-temperature and low-temperature scenarios, respectively. Product value (PV) for the high-temperature and low-temperature scenarios is estimated to be $4.30 and $4.80 per gallon of gasoline equivalent (GGE), respectively, based on a feedstock cost of $75 per dry short ton. Sensitivity analysis is also performed on process and economic parameters. This analysis shows that total capital investment and feedstock cost are among the most influential parameters affecting the PV.

  5. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla

    2009-04-15

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  6. A review of the factors influencing the physicochemical characteristics of underground coal gasification

    SciTech Connect (OSTI)

    Yang, L.H.

    2008-07-01

    In this article, the physicochemical characteristics of the oxidation zone, the reduction zone, and the destructive distillation and dry zone in the process of underground coal gasification (UCG) were explained. The effect of such major factors as temperature, coal type, water-inrush or -intake rate, the quantity and quality of wind blasting, the thickness of coal seams, operational pressure, the length, and the section of gasification gallery on the quality of the underground gas and their interrelationship were discussed. Research showed that the temperature conditions determined the underground gas compositions; the appropriate water-inrush or -intake rate was conducive to the improvement in gas heat value; the properties of the gasification agent had an obvious effect on the compositions and heat value of the product gas. Under the cyclically changing pressure, heat losses decreased by 60%, with the heat efficiency and gasification efficiency being 1.4 times and 2 times those of constant pressure, respectively. The test research further proved that the underground gasifier with a long channel and a big cross-section, to a large extent, improved the combustion-gasification conditions.

  7. Analysis of energy recovery potential using innovative technologies of waste gasification

    SciTech Connect (OSTI)

    Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Energy recovery from waste by gasification was simulated. Black-Right-Pointing-Pointer Two processes: high temperature gasification and gasification associated to plasma. Black-Right-Pointing-Pointer Two types of feeding waste: Refuse Derived Fuel (RDF) and pulper residues. Black-Right-Pointing-Pointer Different configurations for the energy cycles were considered. Black-Right-Pointing-Pointer Comparison with performances from conventional Waste-to-Energy process. - Abstract: In this paper, two alternative thermo-chemical processes for waste treatment were analysed: high temperature gasification and gasification associated to plasma process. The two processes were analysed from the thermodynamic point of view, trying to reconstruct two simplified models, using appropriate simulation tools and some support data from existing/planned plants, able to predict the energy recovery performances by process application. In order to carry out a comparative analysis, the same waste stream input was considered as input to the two models and the generated results were compared. The performances were compared with those that can be obtained from conventional combustion with energy recovery process by means of steam turbine cycle. Results are reported in terms of energy recovery performance indicators as overall energy efficiency, specific energy production per unit of mass of entering waste, primary energy source savings, specific carbon dioxide production.

  8. B Reactor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Operational Management History Manhattan Project Signature Facilities B Reactor B Reactor B Reactor Completed in September 1944, the B Reactor was the world's first ...

  9. A comparison of radioactive waste from first generation fusion reactors and fast fission reactors with actinide recycling

    SciTech Connect (OSTI)

    Koch, M.; Kazimi, M.S.

    1991-04-01

    Limitations of the fission fuel resources will presumably mandate the replacement of thermal fission reactors by fast fission reactors that operate on a self-sufficient closed fuel cycle. This replacement might take place within the next one hundred years, so the direct competitors of fusion reactors will be fission reactors of the latter rather than the former type. Also, fast fission reactors, in contrast to thermal fission reactors, have the potential for transmuting long-lived actinides into short-lived fission products. The associated reduction of the long-term activation of radioactive waste due to actinides makes the comparison of radioactive waste from fast fission reactors to that from fusion reactors more rewarding than the comparison of radioactive waste from thermal fission reactors to that from fusion reactors. Radioactive waste from an experimental and a commercial fast fission reactor and an experimental and a commercial fusion reactor has been characterized. The fast fission reactors chosen for this study were the Experimental Breeder Reactor 2 and the Integral Fast Reactor. The fusion reactors chosen for this study were the International Thermonuclear Experimental Reactor and a Reduced Activation Ferrite Helium Tokamak. The comparison of radioactive waste parameters shows that radioactive waste from the experimental fast fission reactor may be less hazardous than that from the experimental fusion reactor. Inclusion of the actinides would reverse this conclusion only in the long-term. Radioactive waste from the commercial fusion reactor may always be less hazardous than that from the commercial fast fission reactor, irrespective of the inclusion or exclusion of the actinides. The fusion waste would even be far less hazardous, if advanced structural materials, like silicon carbide or vanadium alloy, were employed.

  10. NUCLEAR REACTORS

    DOE Patents [OSTI]

    Long, E.; Ashley, J.W.

    1958-12-16

    A graphite moderator structure is described for a gas-cooled nuclear reactor having a vertical orlentation wherein the structure is physically stable with regard to dlmensional changes due to Wigner growth properties of the graphite, and leakage of coolant gas along spaces in the structure is reduced. The structure is comprised of stacks of unlform right prismatic graphite blocks positioned in layers extending in the direction of the lengths of the blocks, the adjacent end faces of the blocks being separated by pairs of tiles. The blocks and tiles have central bores which are in alignment when assembled and are provided with cooperatlng keys and keyways for physical stability.

  11. Photocatalytic reactor

    DOE Patents [OSTI]

    Bischoff, B.L.; Fain, D.E.; Stockdale, J.A.D.

    1999-01-19

    A photocatalytic reactor is described for processing selected reactants from a fluid medium comprising at least one permeable photocatalytic membrane having a photocatalytic material. The material forms an area of chemically active sites when illuminated by light at selected wavelengths. When the fluid medium is passed through the illuminated membrane, the reactants are processed at these sites separating the processed fluid from the unprocessed fluid. A light source is provided and a light transmitting means, including an optical fiber, for transmitting light from the light source to the membrane. 4 figs.

  12. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  13. Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Jordi Perez-Mariano; Angel Sanjurjo

    2006-06-30

    Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this period, we analyzed several coated and exposed samples of 409 steel by scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). We report here on findings of this analysis: (1) A SS409 coupon that was coated with multilayered combined nitrides of Ti, Al, and Si showed adherent coatings on the surface; (2) A similarly coated coupon, after exposure to simulated coal gas at 900 C for 300 h, revealed that the coating has cracked during the exposure; (3) An SS409 coupon that was coated with nitrides of Ti and Si with a barrier layer of tungsten in between to improve the adhesion of the coating and to prevent outward diffusion of iron to the surface. (4) A porous coupon was coated with nitrides of Ti and Al and examination of the coupon revealed deposition of Ti at the interior surfaces. A similarly prepared coupon was exposed to simulated coal gas at 370 C for 300 h, and it showed no corrosion.

  14. RAPID-L Highly Automated Fast Reactor Concept Without Any Control Rods (1) Reactor concept and plant dynamics analyses

    SciTech Connect (OSTI)

    Kambe, Mitsuru [Central Research Institute of Electric Power Industry (CRIEPI), 2-11-1, Iwado Kita, Komae-shi, Tokyo, 201-8511 (Japan); Tsunoda, Hirokazu [Mitsubishi Research Institute, Inc. 3-6, Otemachi 2-chome, Chiyoda-ku, Tokyo, 100-8141 (Japan); Mishima, Kaichiro [Research Reactor Institute, Kyoto University, Kumatori-cho, Sennan-gun, Osaka, 590-20494 (Japan); Iwamura, Takamichi [Japan Atomic Energy Research Institute, 2-4, Shirakata-shirane, Tokai-mura, Naka-gun, Ibaraki-ken, 319-1195 (Japan)

    2002-07-01

    The 200 kWe uranium-nitride fueled lithium cooled fast reactor concept 'RAPID-L' to achieve highly automated reactor operation has been demonstrated. RAPID-L is designed for Lunar base power system. It is one of the variants of RAPID (Refueling by All Pins Integrated Design), fast reactor concept, which enable quick and simplified refueling. The essential feature of RAPID concept is that the reactor core consists of an integrated fuel assembly instead of conventional fuel subassemblies. In this small size reactor core, 2700 fuel pins are integrated altogether and encased in a fuel cartridge. Refueling is conducted by replacing a fuel cartridge. The reactor can be operated without refueling for up to 10 years. Unique challenges in reactivity control systems design have been attempted in RAPID-L concept. The reactor has no control rod, but involves the following innovative reactivity control systems: Lithium Expansion Modules (LEM) for inherent reactivity feedback, Lithium Injection Modules (LIM) for inherent ultimate shutdown, and Lithium Release Modules (LRM) for automated reactor startup. All these systems adopt lithium-6 as a liquid poison instead of B{sub 4}C rods. In combination with LEMs, LIMs and LRMs, RAPID-L can be operated without operator. This is the first reactor concept ever established in the world. This reactor concept is also applicable to the terrestrial fast reactors. In this paper, RAPID-L reactor concept and its transient characteristics are presented. (authors)

  15. Utilization of solid wastes from the gasification of coal-water slurries

    SciTech Connect (OSTI)

    M.Y. Shpirt; N.P. Goryunova

    2009-07-01

    It was found that only fly and bottom ashes are the solid wastes of water-coal slurry gasification in a direct-flow gasifier. The yields and chemical compositions of fly and bottom ashes obtained after the gasification of water-coal slurries prepared using brown (B) and long-flame (D) coals from the Berezovskii and Mokhovskii strip mines (Kansk-Achinsk and Kuznetsk Basins, respectively) were characterized. Based on an analysis of currently available information, the areas of utilization of fly and bottom ashes after water-coal slurry gasification with dry ash removal were summarized. The use of these wastes in the construction of high-ways and earthwork structures (for the parent coals of B and D grades) and in the manufacture of ash concrete (for the parent coal of D grade) is most promising.

  16. Integration of oxygen plants and gas turbines in IGCC facilities

    SciTech Connect (OSTI)

    Smith, A.R.; Sorensen, J.C.; Woodward, D.W.

    1996-10-01

    The commercialization of Integrated Gasification Combined-Cycle (IGCC) power has been aided by concepts involving the integration of a cryogenic air separation unit (ASU) with the gas turbine combined-cycle module. It is known and now widely accepted that an ASU designed for elevated pressure service and optimally integrated with the gas turbine can increase overall IGCC power output, increase overall efficiency, and decrease the net cost of power generation compared to non-integrated facilities employing low pressure ASU`s. Depending upon the specific gas turbine, gasification technology, NO{sub x} emission specification, and other site specific factors, various degrees of compressed air and nitrogen integration are optimal. Air Products has supplied ASU`s with no integration (Destec/Plaquemine IGCC), nitrogen-only integration (Tampa Electric/Polk County IGCC), and full air and nitrogen integration (Demkolec/Buggenum IGCC). Continuing advancements in both air separation and gas turbine technologies offer new integration opportunities to further improve performance and reduce costs. This paper reviews basic integration principles, highlights the integration scheme used at Polk County, and describes some advanced concepts based on emerging gas turbines. Operability issues associated with integration will be reviewed and control measures described for the safe, efficient, and reliable operation of these facilities.

  17. Hybrid adsorptive membrane reactor

    DOE Patents [OSTI]

    Tsotsis, Theodore T.; Sahimi, Muhammad; Fayyaz-Najafi, Babak; Harale, Aadesh; Park, Byoung-Gi; Liu, Paul K. T.

    2011-03-01

    A hybrid adsorbent-membrane reactor in which the chemical reaction, membrane separation, and product adsorption are coupled. Also disclosed are a dual-reactor apparatus and a process using the reactor or the apparatus.

  18. H Reactor - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Projects & Facilities H Reactor About Us About Hanford Cleanup Hanford History ... 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and ...

  19. C Reactor - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C Reactor About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs ... 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and ...

  20. F Reactor - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Projects & Facilities F Reactor About Us About Hanford Cleanup Hanford History ... 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and ...

  1. N Reactor - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Projects & Facilities N Reactor About Us About Hanford Cleanup Hanford History Hanford ... 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and ...

  2. Integrated Evaluation of Cost, Emissions, and Resource Potential for Algal Biofuels at the National Scale

    SciTech Connect (OSTI)

    Davis, Ryan; Fishman, Daniel; Frank, Edward D.; Johnson, Michael C.; Jones, Susanne B.; Kinchin, Christopher; Skaggs, Richard; Venteris, Erik R.; Wigmosta, Mark S.

    2014-04-21

    Costs, emissions, and resource availability were modeled for the production of 5 billion gallons yr-1 (5 BGY) of renewable diesel in the United States from Chlorella biomass by hydrothermal liquefaction (HTL). The HTL model utilized data from a continuous 1-L reactor including catalytic hydrothermal gasification of the aqueous phase, and catalytic hydrotreatment of the HTL oil. A biophysical algae growth model coupled with weather and pond simulations predicted biomass productivity from experimental growth parameters, allowing site-by-site and temporal prediction of biomass production. The 5 BGY scale required geographically and climatically distributed sites. Even though screening down to 5 BGY significantly reduced spatial and temporal variability, site-to-site, season-to-season, and inter-annual variations in productivity affected economic and environmental performance. Performance metrics based on annual average or peak productivity were inadequate; temporally and spatially explicit computations allowed more rigorous analysis of these dynamic systems. For example, 3-season operation with a winter shutdown was favored to avoid high greenhouse gas emissions, and economic performance was harmed by underutilized equipment during slow-growth periods. Thus, analysis of algal biofuel pathways must combine spatiotemporal resource assessment, economic analysis, and environmental analysis integrated over many sites when assessing national scale performance.

  3. Control Means for Reactor

    DOE Patents [OSTI]

    Manley, J. H.

    1961-06-27

    An apparatus for controlling a nuclear reactor includes a tank just below the reactor, tubes extending from the tank into the reactor, and a thermally expansible liquid neutron absorbent material in the tank. The liquid in the tank is exposed to a beam of neutrons from the reactor which heats the liquid causing it to expand into the reactor when the neutron flux in the reactor rises above a predetermincd danger point. Boron triamine may be used for this purpose.

  4. Economic and Technical Assessment of Wood Biomass Fuel Gasification for Industrial Gas Production

    SciTech Connect (OSTI)

    Anastasia M. Gribik; Ronald E. Mizia; Harry Gatley; Benjamin Phillips

    2007-09-01

    This project addresses both the technical and economic feasibility of replacing industrial gas in lime kilns with synthesis gas from the gasification of hog fuel. The technical assessment includes a materials evaluation, processing equipment needs, and suitability of the heat content of the synthesis gas as a replacement for industrial gas. The economic assessment includes estimations for capital, construction, operating, maintenance, and management costs for the reference plant. To perform these assessments, detailed models of the gasification and lime kiln processes were developed using Aspen Plus. The material and energy balance outputs from the Aspen Plus model were used as inputs to both the material and economic evaluations.

  5. Coal gasification. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    1997-06-01

    The bibliography contains citations of selected patents concerning methods and processes for the gasification of coals. Included are patents for a variety of processes, including fluidized beds, alkali-metal catalytic systems, fixed beds, hot inert heat transfer; and in-situ, pressurized, and steam-iron processes. Topics also include catalyst recovery, desulfurization during gasification, heating methods, pretreatment of coals, heat recovery, electrical power generation, byproduct applications, and pollution control. Liquefaction of coal is examined in a related published bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  6. Coal gasification. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    The bibliography contains citations of selected patents concerning methods and processes for the gasification of coals. Included are patents for a variety of processes, including fluidized beds, alkali-metal catalytic systems, fixed beds, hot inert heat transfer; and in-situ, pressurized, and steam-iron processes. Topics also include catalyst recovery, desulfurization during gasification, heating methods, pretreatment of coals, heat recovery, electrical power generation, byproduct applications, and pollution control. Liquefaction of coal is examined in a related published bibliography. (Contains 250 citations and includes a subject term index and title list.)

  7. Coal gasification. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    1995-01-01

    The bibliography contains citations of selected patents concerning methods and processes for the gasification of coals. Included are patents for a variety of processes, including fluidized beds, alkali-metal catalytic systems, fixed beds, hot inert heat transfer; and in-situ, pressurized, and steam-iron processes. Topics also include catalyst recovery, desulfurization during gasification, heating methods, pretreatment of coals, heat recovery, electrical power generation, byproduct applications, and pollution control. Liquefaction of coal is examined in a related published bibliography. (Contains 250 citations and includes a subject term index and title list.)

  8. Power Burst Facility (PBF) Reactor Reactor Decommissioning

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Click here to view Click here to view Reactor Decommissioning Click on an image to enlarge A crane removes the reactor vessel from the Power Burst Facility (top), then places it ...

  9. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Stewart, H.B.

    1958-12-23

    A nuclear reactor of the type speclfically designed for the irradiation of materials is discussed. In this design a central cyllndrical core of moderating material ls surrounded by an active portlon comprlsed of an annular tank contalning fissionable material immersed ln a liquid moderator. The active portion ls ln turn surrounded by a reflector, and a well ls provided in the center of the core to accommodate the materlals to be irradiated. The over-all dimensions of the core ln at least one plane are equal to or greater than twice the effective slowing down length and equal to or less than twlce the effective diffuslon length for neutrons in the core materials.

  10. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Daniels, F.

    1962-12-18

    A power plant is described comprising a turbine and employing round cylindrical fuel rods formed of BeO and UO/sub 2/ and stacks of hexagonal moderator blocks of BeO provided with passages that loosely receive the fuel rods so that coolant may flow through the passages over the fuels to remove heat. The coolant may be helium or steam and fiows through at least one more heat exchanger for producing vapor from a body of fluid separate from the coolant, which fluid is to drive the turbine for generating electricity. By this arrangement the turbine and directly associated parts are free of particles and radiations emanating from the reactor. (AEC)

  11. NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Wigner, E.P.

    1957-09-17

    A reactor of the type having coolant liquid circulated through clad fuel elements geometrically arranged in a solid moderator, such as graphite, is described. The core is enclosed in a pressure vessel and suitable shielding, wherein means is provided for circulating vapor through the core to superheat the same. This is accomplished by drawing off the liquid which has been heated in the core due to the fission of the fuel, passing it to a nozzle within a chamber where it flashes into a vapor, and then passing the vapor through separate tubes extending through the moderator to pick up more heat developed in the core due to the fission of the fuel, thereby producing superheated vapor.

  12. Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions

    SciTech Connect (OSTI)

    Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

    2008-11-01

    Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

  13. Nuclear reactor

    DOE Patents [OSTI]

    Yant, Howard W.; Stinebiser, Karl W.; Anzur, Gregory C.

    1977-01-01

    A nuclear reactor, particularly a liquid-metal breeder reactor, whose upper internals include outlet modules for channeling the liquid-metal coolant from selected areas of the outlet of the core vertically to the outlet plenum. The modules are composed of a highly-refractory, high corrosion-resistant alloy, for example, INCONEL-718. Each module is disposed to confine and channel generally vertically the coolant emitted from a subplurality of core-component assemblies. Each module has a grid with openings, each opening disposed to receive the coolant from an assembly of the subplurality. The grid in addition serves as a holdown for the assemblies of the corresponding subplurality preventing their excessive ejection upwardly from the core. In the region directly over the core the outlet modules are of such peripheral form that they nest forming a continuum over the core-component assemblies whose outlet coolant they confine. Each subassembly includes a chimney which confines the coolant emitted by its corresponding subassemblies to generally vertical flow between the outlet of the core and the outlet plenum. Each subplurality of assemblies whose emitted coolant is confined by an outlet module includes assemblies which emit lower-temperature coolant, for example, a control-rod assembly, or fertile assemblies, and assemblies which emit coolant of substantially higher temperature, for example, fuel-rod assemblies. The coolants of different temperatures are mixed in the chimneys reducing the effect of stripping (hot-cold temperature fluctuations) on the remainder of the upper internals which are composed typically of AISI-304 or AISI-316 stainless steel.

  14. Reactor and method of operation

    DOE Patents [OSTI]

    Wheeler, John A.

    1976-08-10

    A nuclear reactor having a flattened reactor activity curve across the reactor includes fuel extending over a lesser portion of the fuel channels in the central portion of the reactor than in the remainder of the reactor.

  15. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2004-01-01

    ITN Energy Systems, along with its team members, the Idaho National Engineering and Environmental Laboratory, Nexant Consulting, Argonne National Laboratory and Praxair, propose to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is taking a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into fabrication designs; combining functionally graded materials, monolithic module concept and plasma spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing with low costs. This program will develop and evaluate composite membranes and catalysts for hydrogen separation. Components of the monolithic modules will be fabricated by plasma spray processing. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, will also be assessed. This will result in a complete evaluation of the technical and economic feasibility of ICCM hydrogen separation for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of

  16. Novel Composite Membranes for Hydrogen Separation in Gasification Processes in Vision 21 Energy Plants

    SciTech Connect (OSTI)

    Schwartz, Michael

    2001-11-06

    ITN Energy Systems, Inc. (ITN) and its partners, the Idaho National Engineering and Environmental Laboratory, Argonne National Laboratory, Nexant Consulting, LLC and Praxair, Inc. are developing composite membranes for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is pursuing a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into module fabrication designs; combining functionally-graded materials, monolithic module concept and thermal spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows for the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing techniques with low costs. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, are being assessed. This will result in an evaluation of the technical and economic feasibility of the proposed ICCM hydrogen separation approach for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and

  17. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2003-10-01

    ITN Energy Systems, along with its team members, the Idaho National Engineering and Environmental Laboratory, Nexant Consulting, Argonne National Laboratory and Praxair, propose to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is taking a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into fabrication designs; combining functionally graded materials, monolithic module concept and plasma spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing with low costs. This program will develop and evaluate composite membranes and catalysts for hydrogen separation. Components of the monolithic modules will be fabricated by plasma spray processing. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, will also be assessed. This will result in a complete evaluation of the technical and economic feasibility of ICCM hydrogen separation for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of

  18. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2003-07-01

    ITN Energy Systems, along with its team members, the Idaho National Engineering and Environmental Laboratory, Nexant Consulting, Argonne National Laboratory and Praxair, propose to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is taking a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into fabrication designs; combining functionally graded materials, monolithic module concept and plasma spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing with low costs. This program will develop and evaluate composite membranes and catalysts for hydrogen separation. Components of the monolithic modules will be fabricated by plasma spray processing. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, will also be assessed. This will result in a complete evaluation of the technical and economic feasibility of ICCM hydrogen separation for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of

  19. A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL

    SciTech Connect (OSTI)

    Shain Doong; Estela Ong; Mike Atroshenko; Francis Lau; Mike Roberts

    2005-04-28

    Gas Technology Institute is developing a novel concept of membrane reactor coupled with a gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal-derived synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. To evaluate the performances of the candidate membranes under the gasification conditions, a high temperature/high pressure hydrogen permeation unit has been constructed in this project. The unit is designed to operate at temperatures up to 1100 C and pressures to 60 atm for evaluation of ceramic membranes such as mixed protonic-electronic conducting membrane. Several perovskite membranes based on the formulations of BCN (BaCe{sub 0.8}Nd{sub 0.2}O{sub 3-x}), BCY (BaCe{sub 0.8}Y{sub 0.2}O{sub 3-x}), Eu-doped SrCeO{sub 3} (SCE) and SrCe{sub 0.95}Tm{sub 0.05}O{sub 3} (SCTm) were successfully tested in the new permeation unit. During this reporting period, a thin BCN membrane supported on a porous BCN layer was fabricated. The objective was to increase the hydrogen flux with a further reduction of the thickness of the active membrane layer. The thinnest dense layer that could be achieved in our laboratory currently was about 0.2 mm. Nevertheless, the membrane was tested in the permeation unit and showed reasonable flux compared to the previous BCN samples of the same thickness. A long term durability test was conducted for a SCTm membrane with pure hydrogen in the feed side and nitrogen in the sweep side. The pressure was 1 bar and the temperature was around 1010 C. No decline of hydrogen

  20. Light Water Reactor Sustainability (LWRS) Program | Department...

    Energy Savers [EERE]

    Nuclear Reactor Technologies Light Water Reactor Sustainability (LWRS) Program Light Water Reactor Sustainability (LWRS) Program Light Water Reactor Sustainability (LWRS) ...