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Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
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1

Duke Energy's Edwardsport Integrated Gasification Combined Cycle...  

NLE Websites -- All DOE Office Websites (Extended Search)

Duke Energy's Edwardsport Integrated Gasification Combined Cycle (IGCC) Station presently under construction in Knox County, Indiana. (Photos courtesy of Duke Energy.) Gasification...

2

Integrated Coal Gasification Power Plant Credit (Kansas)  

Energy.gov (U.S. Department of Energy (DOE))

Integrated Coal Gasification Power Plant Credit states that an income taxpayer that makes a qualified investment in a new integrated coal gasification power plant or in the expansion of an existing...

3

EIS-0431: Hydrogen Energy California's Integrated Gasification...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

31: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California EIS-0431: Hydrogen Energy California's Integrated...

4

Economic Rationale for Safety Investment in Integrated Gasification Combined-Cycle Gas Turbine Membrane Reactor Modules  

E-Print Network (OSTI)

utilized in the petrochemical,, chemical processing industries as well as natural gas?based power generation, However, their integration represents a fairly recently conceived technology option to produce commercial electricity... . Please notice that after the condensation of steam and given the fact that CO2 is at a high pressure (~25 atm), a significant reduction in the compression costs associated with the operation of the sequestration units downstream...

Koc, Reyyan; Kazantzis, Nikolaos K.; Nuttall, William J.; Ma, Yi Hua

2012-05-09T23:59:59.000Z

5

DOE Hydrogen Analysis Repository: Biomass Integrated Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Biomass Integrated Gasification Combined-Cycle Power Systems Biomass Integrated Gasification Combined-Cycle Power Systems Project Summary Full Title: Cost and Performance Analysis of Biomass-Based Integrated Gasification Combined-Cycle (BIGCC) Power Systems Project ID: 106 Principal Investigator: Margaret Mann Brief Description: This project examines the cost and performance potential of three biomass-based integrated gasification combined cycle (IGCC) systems--high-pressure air blown, low-pressure air blown, and low-pressure indirectly heated. Purpose Examine the cost and performance potential of three biomass-based integrated gasification combined cycle (IGCC) systems - a high pressure air-blown, a low pressure indirectly heated, and a low pressure air-blown. Performer Principal Investigator: Margaret Mann

6

Exploration of supercritical water gasification of biomass using batch reactor .  

E-Print Network (OSTI)

??The focus of this study is on gasification of a biomass in supercritical water. Vapor mass yield in a batch reactor after 20 minutes in… (more)

Venkitasamy, Chandrasekar

2011-01-01T23:59:59.000Z

7

Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper  

SciTech Connect

This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

A.M. Gandrik

2012-04-01T23:59:59.000Z

8

Pneumatic solids feeder for coal gasification reactor  

DOE Patents (OSTI)

This invention is comprised of a pneumatic feeder system for a coal gasification reactor which includes one or more feeder tubes entering the reactor above the level of the particle bed inside the reactor. The tubes are inclined downward at their outer ends so that coal particles introduced into the tubes through an aperture at the top of the tubes slides downward away from the reactor and does not fall directly into the reactor. Pressurized gas introduced into, or resulting from ignition of recycled combustible gas in a chamber adjacent to the tube ends, propels the coal from the tube into the reactor volume and onto the particle bed. Leveling of the top of the bed is carried out by a bladed rotor mounted on the reactor stirring shaft. Coal is introduced into the tubes from containers above the tubes by means of rotary valves placed across supply conduits. This system avoids placement of feeder hardware in the plenum above the particle bed and keeps the coal from being excessively heated prior to reaching the particle bed.

Notestein, J.E.; Halow, J.S.

1991-12-31T23:59:59.000Z

9

Coal Integrated Gasification Fuel Cell System Study  

DOE Green Energy (OSTI)

The pre-baseline configuration for an Integrated Gasification Fuel Cell (IGFC) system has been developed. This case uses current gasification, clean-up, gas turbine, and bottoming cycle technologies together with projected large planar Solid Oxide Fuel Cell (SOFC) technology. This pre-baseline case will be used as a basis for identifying the critical factors impacting system performance and the major technical challenges in implementing such systems. Top-level system requirements were used as the criteria to evaluate and down select alternative sub-systems. The top choice subsystems were subsequently integrated to form the pre-baseline case. The down-selected pre-baseline case includes a British Gas Lurgi (BGL) gasification and cleanup sub-system integrated with a GE Power Systems 6FA+e gas turbine and the Hybrid Power Generation Systems planar Solid Oxide Fuel Cell (SOFC) sub-system. The overall efficiency of this system is estimated to be 43.0%. The system efficiency of the pre-baseline system provides a benchmark level for further optimization efforts in this program.

Gregory Wotzak; Chellappa Balan; Faress Rahman; Nguyen Minh

2003-08-01T23:59:59.000Z

10

Solar coal gasification reactor with pyrolysis gas recycle  

DOE Patents (OSTI)

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

11

Coal Integrated Gasification Fuel Cell System Study  

DOE Green Energy (OSTI)

This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

2004-01-31T23:59:59.000Z

12

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

13

Heavy metals behaviour in a gasification reactor  

Science Conference Proceedings (OSTI)

Sludge coming from cleaning processes of wastewater, Municipal Solid Waste (MSW), and Refuse Derived Fuel (RDF) can be exploited for producing energy because of their heating value. Cleaning the produced syngas is important because of environmental troubles, ... Keywords: heavy metals, syngas, thermodynamic, waste gasification

Martino Paolucci; Carlo Borgianni; Paolo De Filippis

2011-07-01T23:59:59.000Z

14

Integrated Gasification Combined Cycle (IGCC) Design Considerations for High Availability  

Science Conference Proceedings (OSTI)

This report analyses public domain availability data from Integrated Gasification Combined Cycles (IGCC) and other significant coal gasification facilities, backed up with additional data gained from interviews and discussions with plant operators. Predictions for the availability of future IGCCs are made based on the experience of the existing fleet and anticipated improvements from the implementation of lessons learned.

2007-03-26T23:59:59.000Z

15

EIS-0431: Hydrogen Energy California's Integrated Gasification Combined  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Hydrogen Energy California's Integrated Gasification 1: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California EIS-0431: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California Summary This EIS evaluates the potential environmental impacts of a proposal to provide financial assistance for the construction and operation of Hydrogen Energy California LLC (HECA's) project, which would produce and sell electricity, carbon dioxide and fertilizer. DOE selected this project for an award of financial assistance through a competitive process under the Clean Coal Power Initiative program. Public Comment Opportunities None available at this time. Documents Available for Download September 5, 2013

16

Avestar® - Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator The AVESTAR® center offers courses using the Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator. The IGCC simulator builds on and reaches beyond existing combined-cycle and conventional-coal power plant simulators to combine--for the first time--a Gasification with CO2 Capture process simulator with a Combined-Cycle power simulator together in a single dynamic simulation framework. The AVESTAR® center IGCC courses provide unique, comprehensive training on all aspects of an IGCC plant, illustrating the high-efficiency aspects of the gasifier, gas turbine, and steam turbine integration. IGCC Operator training station HMI display for overview of IGCC Plant - Train A Reference:

17

2009 Integrated Gasification Combined Cycle Engineering Economic Evaluation  

Science Conference Proceedings (OSTI)

The 2009 Electric Power Research Institute (EPRI) report Integrated Gasification Combined Cycle (IGCC) Design Considerations for Carbon Dioxide (CO2) Capture (1015690) contains engineering and economic evaluations of state-of-the-art integrated gasification combined cycle (IGCC) power plant designs available for near-term deployment. The study assessed the expected performance and costs of coal-fed IGCC power plants before and after retrofit for carbon dioxide (CO2) capture. The study evaluated paired ca...

2009-09-30T23:59:59.000Z

18

Coal gasification-based integrated coproduction energy facilities  

SciTech Connect

Coal gasification has been a technological reality for over a half century, being first used in great detail in Europe as an alternative to petroleum. Several projects in the US in the last decade have led to the commercial demonstration and verification of the coal gasification process. This paper reports that, in an effort to reduce the cost of electricity from an Integrated Gasification Combined Cycle Plant, the Electric Power Research Institute embarked in a program to research, evaluate and potentially demonstrate a coal gasification-based integrated coproduction energy facility, and release an RFP in mid 1990 as Phase I of that program. Houston Lighting and Power Company responded with a proposal in its ongoing effort to study emerging technologies for electricity production. HL and P recognized the opportunities available to them in coproduction because of their close proximity to the world's largest petrochemical complex located on the Houston Ship Channel.

Baumann, P.D. (InterFact, Inc., Dallas, TX (US)); Epstein, M. (Electric Power Research Inst., Palo Alto, CA (United States)); Kern, E.E. (Houston Lighting and Power Co., TX (United States))

1992-01-01T23:59:59.000Z

19

Analysis of Biomass/Coal Co-Gasification for Integrated Gasification Combined Cycle (IGCC) Systems with Carbon Capture.  

E-Print Network (OSTI)

?? In recent years, Integrated Gasification Combined Cycle Technology (IGCC) has become more common in clean coal power operations with carbon capture and sequestration (CCS).… (more)

Long, Henry A, III

2011-01-01T23:59:59.000Z

20

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation's carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. (Energy Research Corp., Danbury, CT (United States)); Meyers, S.J. (Fluor Daniel, Inc., Irvine, CA (United States)); Hauserman, W.B. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation`s carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. [Energy Research Corp., Danbury, CT (United States); Meyers, S.J. [Fluor Daniel, Inc., Irvine, CA (United States); Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

1992-12-01T23:59:59.000Z

22

Gasification Portal  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Home Gasification Home Gasification Home Gasification Home Gasification Home Gasification Home Gasification Home Gasification Home Gasification Home Gasification Home...

23

Integrated gasification combined cycle - a view to the future  

SciTech Connect

DOE is involved in research, development, and demonstration of Integrated Gasification Combined Cycle because of a strong belief that it will result in widespread commercialization that will be of great benefit to this nation. METC`s long-range vision comprises (1) product goals that require improvements to known technical advantages, and (2) market goals that are based on expectations of market pull.

Schmidt, D.K.

1994-10-01T23:59:59.000Z

24

Integrated gasification combined cycle overview of FETC--S program  

Science Conference Proceedings (OSTI)

Changing market conditions, brought about by utility deregulation and increased environmental regulations, have encouraged the Department of Energy/Federal Energy Technology Center (DOE/FETC) to restructure its Integrated Gasification Combined Cycle (IGCC) program. The program emphasis, which had focused on baseload electricity production from coal, is now expanded to more broadly address the production of a suite of energy and chemical products. The near-term market barrier for baseload power applications for conventional IGCC systems combines with increasing opportunities to process a range of low- and negative-value opportunity feedstocks. The new program is developing a broader range of technology options that will increase the versatility and the technology base for commercialization of gasification-based technologies. This new strategy supports gasification in niche markets where, due to its ability to coproduce a wide variety of commodity and premium products to meet market requirements, it is an attractive alternative. By obtaining operating experience in industrial coproduction applications today, gasification system modules can be refined and improved leading to commercial guarantees and acceptance of gasification technology as a cost-effective technology for baseload power generation and coproduction as these markets begin to open.

Stiegel, G.J.; Maxwell, R.C.

1999-07-01T23:59:59.000Z

25

Advanced CO2 Capture Technology for Low Rank Coal Integrated Gasification Combined Cycle (IGCC) Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

CO CO 2 Capture Technology for Low Rank Coal Integrated Gasification Combined Cycle (IGCC) Systems Background Gasification of coal or other solid feedstocks (wood waste, petroleum coke, etc.) is a clean way to produce electricity and produce or co-produce a variety of commercial products. The major challenge is cost reduction; current integrated gasification combined cycle (IGCC) technology is estimated to produce power at a cost higher than that of pulverized coal combustion. However, the Gasification

26

Benefits of Integrating PWR and RTI Advanced Gasification Technologies for  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Processing Systems Syngas Processing Systems Benefits of Integrating PWR and RTI Advanced Gasification Technologies for Hydrogen-Rich Syngas Production Research Triangle Institute (RTI) Project Number: FE0012066 Project Description The project will assess the potential for integrated advanced technologies to substantially reduce capital and production costs for hydrogen-rich syngas with near-zero emissions from coal gasification for power production with carbon capture and for coal-to-liquids (specifically methanol) with carbon capture. These integrated technologies include those already tested successfully at pilot-scale with a new and innovative water-gas-shift technology, to show how multiple advanced technologies will leverage each other for significant cost and efficiency gains.

27

The Integral Fast Reactor  

SciTech Connect

Argonne National Laboratory, since 1984, has been developing the Integral Fast Reactor (IFR). This paper will describe the way in which this new reactor concept came about; the technical, public acceptance, and environmental issues that are addressed by the IFR; the technical progress that has been made; and our expectations for this program in the near term. 5 refs., 3 figs.

Till, C.E.; Chang, Y.I. (Argonne National Lab., IL (USA)); Lineberry, M.J. (Argonne National Lab., Idaho Falls, ID (USA))

1990-01-01T23:59:59.000Z

28

Integrated gasification combined-cycle research development and demonstration activities  

Science Conference Proceedings (OSTI)

The United States Department of Energy (DOE) has selected six integrated gasification combined-cycle (IGCC) advanced power systems for demonstration in the Clean Coal Technology (CCT) Program. DOE`s Office of Fossil Energy, Morgantown Energy Technology Center, is managing a research development and demonstration (RD&D) program that supports the CCT program, and addresses long-term improvements in support of IGCC technology. This overview briefly describes the CCT projects and the supporting RD&D activities.

Ness, H.M.; Reuther, R.B.

1995-12-01T23:59:59.000Z

29

Coal Fleet Integrated Gasification Combined Cycle (IGCC Permitting) Guidelines  

Science Conference Proceedings (OSTI)

This report provides guidance to owners of planned Integrated Gasification Combined Cycle (IGCC) power plants in order to assist them in permitting these advanced coal power generation facilities. The CoalFleet IGCC Permitting Guidelines summarize U.S. federal requirements for obtaining air, water, and solid waste permits for a generic IGCC facility, as described in the CoalFleet User Design Basis Specification (UDBS). The report presents characteristics of IGCC emissions that must be considered in the p...

2006-03-14T23:59:59.000Z

30

NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE  

SciTech Connect

The objective of this program is to develop and evaluate novel sorbents for the Siemens Westinghouse Power Company's (SWPC's) ''Ultra-Clean Gas Cleaning Process'' for reducing to near-zero levels the sulfur- and chlorine-containing gas emissions and fine particulate matter (PM2.5) caused by fuel bound constituents found in carbonaceous materials, which are processed in Integrated Gasification Combined Cycle (IGCC) technologies.

Javad Abbasian

2001-07-01T23:59:59.000Z

31

2012 Integrated Gasification Combined Cycle (IGCC) Research and Development Roadmap  

Science Conference Proceedings (OSTI)

BackgroundThe second generation of integrated gasification combined cycle (IGCC) power plants is now being built or planned following nearly two decades of commercial demonstration at multiple units. State-of-the-art IGCC plants have efficiencies equivalent to that of pulverized coal power plants while exhibiting equal or superior environmental performance and lower water usage. Precombustion CO2 capture technology is commercially available and has been ...

2012-10-30T23:59:59.000Z

32

Integrated gasification combined cycle -- A review of IGCC technology  

SciTech Connect

Over the past three decades, significant efforts have been made toward the development of cleaner and more efficient technology for power generation. Coal gasification technology received a big thrust with the concept of combined cycle power generation. The integration of coal gasification with combined cycle for power generation (IGCC) had the inherent characteristic of gas cleanup and waste minimization, which made this system environmentally preferable. Commercial-scale demonstration of a cool water plant and other studies have shown that the greenhouse gas and particulates emission from an IGCC plant is drastically lower than the recommended federal New Source Performance Standard levels. IGCC also offers a phased construction and repowering option, which allows multiple-fuel flexibility and the necessary economic viability. IGCC technology advances continue to improve efficiency and further reduce the emissions, making it the technology of the 21st century.

Joshi, M.M.; Lee, S. [Univ. of Akron, OH (United States)

1996-07-01T23:59:59.000Z

33

Solar coal-gasification reactor with pyrolysis-gas recycle. [Patent application  

DOE Patents (OSTI)

Coal (or other carbonaceous matter, such as biomass) is converted into a product gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor, and solar energy is directed into the reactor onto coal char, creating a gasification front and a pyrolysis front. A gasification zone is produced well above the coal level within the reactor. A pyrolysis zone is produced immediately above the coal level. Steam, injected into the reactor adjacent to the gasification zone, reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases flow from the gasification zone to the pyrolysis zone to generate hot char. Gases are withdrawn from the pyrolysis zone and reinjected into the region of the reactor adjacent the gasification zone. This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas is withdrawn from a region of the reactor between the gasification zone and the pyrolysis zone. The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Aiman, W.R.; Gregg, D.W.

1981-04-06T23:59:59.000Z

34

Modeling the Performance, Emissions, and Costs of Texaco Gasifier-Based Integrated Gasification Combined Cycle Systems.  

E-Print Network (OSTI)

??Integrated Gasification Combined Cycle (IGCC) systems are an advanced power generation concept with the flexibility to use coal, heavy oils, petroleum coke, biomass, and waste… (more)

Akunuri, Naveen

1999-01-01T23:59:59.000Z

35

"Integrated Gasification Combined Cycle"  

U.S. Energy Information Administration (EIA) Indexed Site

Status of technologies and components modeled by EIA" Status of technologies and components modeled by EIA" ,"Revolutionary","Evolutionary","Mature" "Pulverized Coal",,,"X" "Pulverized Coal with CCS" " - Non-CCS portion of Pulverized Coal Plant",,,"X" " - CCS","X" "Integrated Gasification Combined Cycle" " - Advanced Combustion Turbine",,"X" " - Heat Recovery Steam Generator",,,"X" " - Gasifier",,"X" " - Balance of Plant",,,"X" "Conventional Natural Gas Combined Cycle" " - Conventional Combustion Turbine",,,"X" " - Heat Recovery Steam Generator",,,"X" " - Balance of Plant",,,"X"

36

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

DOE Green Energy (OSTI)

The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

Michael L. Swanson

2005-08-30T23:59:59.000Z

37

Life Cycle Analysis: Integrated Gasification Combined Cycle (IGCC) Power Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

Life Cycle Analysis: Integrated Life Cycle Analysis: Integrated Gasification Combined Cycle (IGCC) Power Plant Revision 2, March 2012 DOE/NETL-2012/1551 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or

38

NOVEL GAS CLEANING/ CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE  

NLE Websites -- All DOE Office Websites (Extended Search)

INTEGRATED GASIFICATION COMBINED CYCLE VOLUME I - CONCEPTUAL COMMERCIAL EVALUATION OPTIONAL PROGRAM FINAL REPORT September 1, 2001 - December 31, 2005 By Dennis A. Horazak (Siemens), Program Manager Richard A. Newby (Siemens) Eugene E. Smeltzer (Siemens) Rachid B. Slimane (GTI) P. Vann Bush (GTI) James L. Aderhold, Jr. (GTI) Bruce G. Bryan (GTI) December 2005 DOE Award Number: DE-AC26-99FT40674 Prepared for U.S. Department of Energy National Energy Technology Laboratory Prepared by Siemens Power Generation, Inc. 4400 Alafaya Trail Orlando, FL 32826 & Gas Technology Institute 1700 S. Mt. Prospect Rd. Des Plaines, Illinois 60018 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government.

39

Development of an Integrated Multicontaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

an Integrated an Integrated Multicontaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems Background The U.S. has more coal than any other country, and it can be converted through gasification into electricity, liquid fuels, chemicals, or hydrogen. However, for coal gasification to become sufficiently competitive to benefit the U.S. economy and help reduce our dependence on foreign fuels, gasification costs must be reduced

40

Integration of stripping of fines slurry in a coking and gasification process  

DOE Patents (OSTI)

In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

DeGeorge, Charles W. (Chester, NJ)

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Integration of Ion Transport Membrane Technology with Integrated Gasification Combined Cycle Power Generation Systems  

Science Conference Proceedings (OSTI)

EPRI, in conjunction with Air Products and Chemicals, Inc. (AP), has reviewed the integrated gasification combined cycle (IGCC) process, whereby coal (or some other hydrocarbon such as petroleum coke or heavy oil) is broken down into its constituent volatile and nonvolatile components through the process of oxidative-pyrolysis. Combustible synthetic gas created in the process can be used in a traditional combined cycle. IGCC is particularly appealing for its potentially higher efficiencies compared ...

2013-10-30T23:59:59.000Z

42

Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas-phase chemistry  

E-Print Network (OSTI)

. The conceptual design of the reactor was made to obtain a cost estimation. The principal caracteristics or the hydrothermal gasification of the unconverted residues from the ethanol production process. A steam turbine.4% The highest energy efficiency of 67.5% is obtained in the case of hydrothermal gasification. For combustion

Qiao, Li

43

Mathematical Modeling of Coal Gasification Processes in a Well-Stirred Reactor: Effects of Devolatilization and Moisture Content  

E-Print Network (OSTI)

Mathematical Modeling of Coal Gasification Processes in a Well- Stirred Reactor: Effects in coal and biomass play an important role on the gasification performance of these fuels on the syngas composition. The coal conversion time is most sensitive to the heat transfer rates including both

Qiao, Li

44

Model Predictive Control of Integrated Gasification Combined Cycle Power Plants  

SciTech Connect

The primary project objectives were to understand how the process design of an integrated gasification combined cycle (IGCC) power plant affects the dynamic operability and controllability of the process. Steady-state and dynamic simulation models were developed to predict the process behavior during typical transients that occur in plant operation. Advanced control strategies were developed to improve the ability of the process to follow changes in the power load demand, and to improve performance during transitions between power levels. Another objective of the proposed work was to educate graduate and undergraduate students in the application of process systems and control to coal technology. Educational materials were developed for use in engineering courses to further broaden this exposure to many students. ASPENTECH software was used to perform steady-state and dynamic simulations of an IGCC power plant. Linear systems analysis techniques were used to assess the steady-state and dynamic operability of the power plant under various plant operating conditions. Model predictive control (MPC) strategies were developed to improve the dynamic operation of the power plants. MATLAB and SIMULINK software were used for systems analysis and control system design, and the SIMULINK functionality in ASPEN DYNAMICS was used to test the control strategies on the simulated process. Project funds were used to support a Ph.D. student to receive education and training in coal technology and the application of modeling and simulation techniques.

B. Wayne Bequette; Priyadarshi Mahapatra

2010-08-31T23:59:59.000Z

45

INTEGRATED GASIFICATION COMBINED CYCLE PROJECT 2 MW FUEL CELL DEMONSTRATION  

DOE Green Energy (OSTI)

With about 50% of power generation in the United States derived from coal and projections indicating that coal will continue to be the primary fuel for power generation in the next two decades, the Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCTDP) has been conducted since 1985 to develop innovative, environmentally friendly processes for the world energy market place. The 2 MW Fuel Cell Demonstration was part of the Kentucky Pioneer Energy (KPE) Integrated Gasification Combined Cycle (IGCC) project selected by DOE under Round Five of the Clean Coal Technology Demonstration Program. The participant in the CCTDP V Project was Kentucky Pioneer Energy for the IGCC plant. FuelCell Energy, Inc. (FCE), under subcontract to KPE, was responsible for the design, construction and operation of the 2 MW fuel cell power plant. Duke Fluor Daniel provided engineering design and procurement support for the balance-of-plant skids. Colt Engineering Corporation provided engineering design, fabrication and procurement of the syngas processing skids. Jacobs Applied Technology provided the fabrication of the fuel cell module vessels. Wabash River Energy Ltd (WREL) provided the test site. The 2 MW fuel cell power plant utilizes FuelCell Energy's Direct Fuel Cell (DFC) technology, which is based on the internally reforming carbonate fuel cell. This plant is capable of operating on coal-derived syngas as well as natural gas. Prior testing (1992) of a subscale 20 kW carbonate fuel cell stack at the Louisiana Gasification Technology Inc. (LGTI) site using the Dow/Destec gasification plant indicated that operation on coal derived gas provided normal performance and stable operation. Duke Fluor Daniel and FuelCell Energy developed a commercial plant design for the 2 MW fuel cell. The plant was designed to be modular, factory assembled and truck shippable to the site. Five balance-of-plant skids incorporating fuel processing, anode gas oxidation, heat recovery, water treatment/instrument air, and power conditioning/controls were built and shipped to the site. The two fuel cell modules, each rated at 1 MW on natural gas, were fabricated by FuelCell Energy in its Torrington, CT manufacturing facility. The fuel cell modules were conditioned and tested at FuelCell Energy in Danbury and shipped to the site. Installation of the power plant and connection to all required utilities and syngas was completed. Pre-operation checkout of the entire power plant was conducted and the plant was ready to operate in July 2004. However, fuel gas (natural gas or syngas) was not available at the WREL site due to technical difficulties with the gasifier and other issues. The fuel cell power plant was therefore not operated, and subsequently removed by October of 2005. The WREL fuel cell site was restored to the satisfaction of WREL. FuelCell Energy continues to market carbonate fuel cells for natural gas and digester gas applications. A fuel cell/turbine hybrid is being developed and tested that provides higher efficiency with potential to reach the DOE goal of 60% HHV on coal gas. A system study was conducted for a 40 MW direct fuel cell/turbine hybrid (DFC/T) with potential for future coal gas applications. In addition, FCE is developing Solid Oxide Fuel Cell (SOFC) power plants with Versa Power Systems (VPS) as part of the Solid State Energy Conversion Alliance (SECA) program and has an on-going program for co-production of hydrogen. Future development in these technologies can lead to future coal gas fuel cell applications.

FuelCell Energy

2005-05-16T23:59:59.000Z

46

Integrating Coal Gasification into a Rotary Kiln Electric Furnace Plant  

Science Conference Proceedings (OSTI)

Coal gasification is a potential alternative to conventional coal or natural gas- fired power plants ... Fundamentals of Spark-Plasma Sintering: Net-Shaping and Size Effects ... Investigation on a Microwave High-Temperature Air Heat Exchanger.

47

Light Water Reactor Sustainability Program: Integrated Program...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Light Water Reactor Sustainability Program: Integrated Program Plan Light Water Reactor Sustainability Program: Integrated Program Plan Nuclear power has safely, reliably, and...

48

2012 Integrated Gasification Combined Cycle (IGCC) Research and Development Roadmap - PUBLIC  

Science Conference Proceedings (OSTI)

The second generation of integrated-gasification combined-cycle (IGCC) power plants is now being built or planned following nearly two decades of commercial demonstration at multiple units. State-of-the-art IGCC plants have efficiencies equivalent to that of pulverized coal power plants while exhibiting equal or superior environmental performance and lower water usage. Pre-combustion CO2 capture technology is commercially available and has been demonstrated in several gasification plants, ...

2012-12-20T23:59:59.000Z

49

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

the following discussion considers a comparison of coal-fired Integrated Gasification Combined Cycle (IGCC) and pulverized coal (PC) power plants, representing a balanced...

50

Theoretical and experimental studies of fixed-bed coal gasification reactors. Final report  

Science Conference Proceedings (OSTI)

A laboratory fixed-bed gasification reactor was designed and built with the objective of collecting operational data for model validation and parameter estimation. The reactor consists of a 4 inch stainless steel tube filled with coal or char. Air and steam is fed at one end of the reactor and the dynamic progress of gasification in the coal or char bed is observed through thermocouples mounted at various radial and axial locations. Product gas compositions are also monitored as a function of time. Results of gasification runs using Wyoming coal are included in this report. In parallel with the experimental study, a two-dimensional model of moving bed gasifiers was developed, coded into a computer program and tested. This model was used to study the laboratory gasifier by setting the coal feed rate equal to zero. The model is based on prior work on steady state and dynamic modeling done at Washington University and published elsewhere in the literature. Comparisons are made between model predictions and experimental results. These are also included in this report. 23 references, 18 figures, 6 tables.

Joseph, B.; Bhattacharya, A.; Salam, L.; Dudukovic, M.P.

1983-09-01T23:59:59.000Z

51

NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE  

DOE Green Energy (OSTI)

Development efforts have been underway for decades to replace dry-gas cleaning technology with humid-gas cleaning technology that would maintain the water vapor content in the raw gas by conducting cleaning at sufficiently high temperature to avoid water vapor condensation and would thus significantly simplify the plant and improve its thermal efficiency. Siemens Power Generation, Inc. conducted a program with the Gas Technology Institute (GTI) to develop a Novel Gas Cleaning process that uses a new type of gas-sorbent contactor, the ''filter-reactor''. The Filter-Reactor Novel Gas Cleaning process described and evaluated here is in its early stages of development and this evaluation is classified as conceptual. The commercial evaluations have been coupled with integrated Process Development Unit testing performed at a GTI coal gasifier test facility to demonstrate, at sub-scale the process performance capabilities. The commercial evaluations and Process Development Unit test results are presented in Volumes 1 and 2 of this report, respectively. Two gas cleaning applications with significantly differing gas cleaning requirements were considered in the evaluation: IGCC power generation, and Methanol Synthesis with electric power co-production. For the IGCC power generation application, two sets of gas cleaning requirements were applied, one representing the most stringent ''current'' gas cleaning requirements, and a second set representing possible, very stringent ''future'' gas cleaning requirements. Current gas cleaning requirements were used for Methanol Synthesis in the evaluation because these cleaning requirements represent the most stringent of cleaning requirements and the most challenging for the Filter-Reactor Novel Gas Cleaning process. The scope of the evaluation for each application was: (1) Select the configuration for the Filter-Reactor Novel Gas Cleaning Process, the arrangement of the individual gas cleaning stages, and the probable operating conditions of the gas cleaning stages to conceptually satisfy the gas cleaning requirements; (2) Estimate process material & energy balances for the major plant sections and for each gas cleaning stage; (3) Conceptually size and specify the major gas cleaning process equipment; (4) Determine the resulting overall performance of the application; and (5) Estimate the investment cost and operating cost for each application. Analogous evaluation steps were applied for each application using conventional gas cleaning technology, and comparison was made to extract the potential benefits, issues, and development needs of the Filter-Reactor Novel Gas Cleaning technology. The gas cleaning process and related gas conditioning steps were also required to meet specifications that address plant environmental emissions, the protection of the gas turbine and other Power Island components, and the protection of the methanol synthesis reactor. Detailed material & energy balances for the gas cleaning applications, coupled with preliminary thermodynamic modeling and laboratory testing of candidate sorbents, identified the probable sorbent types that should be used, their needed operating conditions in each stage, and their required levels of performance. The study showed that Filter-Reactor Novel Gas Cleaning technology can be configured to address and conceptually meet all of the gas cleaning requirements for IGCC, and that it can potentially overcome several of the conventional IGCC power plant availability issues, resulting in improved power plant thermal efficiency and cost. For IGCC application, Filter-Reactor Novel Gas Cleaning yields 6% greater generating capacity and 2.3 percentage-points greater efficiency under the Current Standards case, and more than 9% generating capacity increase and 3.6 percentage-points higher efficiency in the Future Standards case. While the conceptual equipment costs are estimated to be only slightly lower for the Filter-Reactor Novel Gas Cleaning processes than for the conventional processes, the improved power plant capacity results in the potentia

Dennis A. Horazak; Richard A. Newby; Eugene E. Smeltzer; Rachid B. Slimane; P. Vann Bush; James L. Aderhold Jr; Bruce G. Bryan

2005-12-01T23:59:59.000Z

52

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project, Final Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8 8 U.S. Department of Energy Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project Final Environmental Impact Statement November 2002 U.S. Department of Energy National Energy Technology Laboratory COVER SHEET Responsible Agency: U.S. Department of Energy (DOE) Title: Kentucky Pioneer Integrated Gasification Combined Cycle (IGCC) Demonstration Project Final Environmental Impact Statement (EIS) (DOE/EIS-0318) Location: Clark County, Kentucky Contacts: For further information on this environmental For further information on the DOE National impact statement (EIS), call: Environmental Policy Act (NEPA) process, call: 1-800-432-8330 ext. 5460 1-800-472-2756 or contact: or contact: Mr. Roy Spears Ms. Carol Borgstrom

53

Thermal energy storage for an integrated coal gasification combined-cycle power plant  

DOE Green Energy (OSTI)

This study investigates the use of molten nitrate salt thermal energy storage in an integrated gasification combined-cycle power plant allowing the facility to economically provide peak- and intermediate-load electric power. The results of the study show that an integrated gasification combined-cycle power plant with thermal energy storage can reduce the cost of coal-fired peak- or intermediate-load electric power by between 5% and 20% depending on the plants operating schedule. The use of direct-contact salt heating can further improve the economic attractiveness of the concept. 11 refs., 1 fig., 4 tabs.

Drost, M.K.; Antoniak, Z.I.; Brown, D.R.

1990-03-01T23:59:59.000Z

54

Thermal energy storage for an integrated coal gasification combined-cycle power plant  

Science Conference Proceedings (OSTI)

This study investigates the use of molten nitrate salt thermal energy storage in an integrated gasification combined-cycle power plant allowing the facility to economically provide peak- and intermediate-load electric power. The results of the study show that an integrated gasification combined-cycle power plant with thermal energy storage can reduce the cost of coal-fired peak- or intermediate-load electric power by between 5% and 20% depending on the plants operating schedule. The use of direct-contact salt heating can further improve the economic attractiveness of the concept. 12 refs., 1 fig., 5 tabs.

Drost, K.; Antoniak, Z.; Brown, D.; Somasundaram, S.

1991-10-01T23:59:59.000Z

55

Integrated Biomass Gasification with Catalytic Partial Oxidation for Selective Tar Conversion  

SciTech Connect

Biomass gasification is a flexible and efficient way of utilizing widely available domestic renewable resources. Syngas from biomass has the potential for biofuels production, which will enhance energy security and environmental benefits. Additionally, with the successful development of low Btu fuel engines (e.g. GE Jenbacher engines), syngas from biomass can be efficiently used for power/heat co-generation. However, biomass gasification has not been widely commercialized because of a number of technical/economic issues related to gasifier design and syngas cleanup. Biomass gasification, due to its scale limitation, cannot afford to use pure oxygen as the gasification agent that used in coal gasification. Because, it uses air instead of oxygen, the biomass gasification temperature is much lower than well-understood coal gasification. The low temperature leads to a lot of tar formation and the tar can gum up the downstream equipment. Thus, the biomass gasification tar removal is a critical technology challenge for all types of biomass gasifiers. This USDA/DOE funded program (award number: DE-FG36-O8GO18085) aims to develop an advanced catalytic tar conversion system that can economically and efficiently convert tar into useful light gases (such as syngas) for downstream fuel synthesis or power generation. This program has been executed by GE Global Research in Irvine, CA, in collaboration with Professor Lanny Schmidt's group at the University of Minnesota (UoMn). Biomass gasification produces a raw syngas stream containing H2, CO, CO2, H2O, CH4 and other hydrocarbons, tars, char, and ash. Tars are defined as organic compounds that are condensable at room temperature and are assumed to be largely aromatic. Downstream units in biomass gasification such as gas engine, turbine or fuel synthesis reactors require stringent control in syngas quality, especially tar content to avoid plugging (gum) of downstream equipment. Tar- and ash-free syngas streams are a critical requirement for commercial deployment of biomass-based power/heat co-generation and biofuels production. There are several commonly used syngas clean-up technologies: (1) Syngas cooling and water scrubbing has been commercially proven but efficiency is low and it is only effective at small scales. This route is accompanied with troublesome wastewater treatment. (2) The tar filtration method requires frequent filter replacement and solid residue treatment, leading to high operation and capital costs. (3) Thermal destruction typically operates at temperatures higher than 1000oC. It has slow kinetics and potential soot formation issues. The system is expensive and materials are not reliable at high temperatures. (4) In-bed cracking catalysts show rapid deactivation, with durability to be demonstrated. (5) External catalytic cracking or steam reforming has low thermal efficiency and is faced with problematic catalyst coking. Under this program, catalytic partial oxidation (CPO) is being evaluated for syngas tar clean-up in biomass gasification. The CPO reaction is exothermic, implying that no external heat is needed and the system is of high thermal efficiency. CPO is capable of processing large gas volume, indicating a very compact catalyst bed and a low reactor cost. Instead of traditional physical removal of tar, the CPO concept converts tar into useful light gases (eg. CO, H2, CH4). This eliminates waste treatment and disposal requirements. All those advantages make the CPO catalytic tar conversion system a viable solution for biomass gasification downstream gas clean-up. This program was conducted from October 1 2008 to February 28 2011 and divided into five major tasks. - Task A: Perform conceptual design and conduct preliminary system and economic analysis (Q1 2009 ~ Q2 2009) - Task B: Biomass gasification tests, product characterization, and CPO tar conversion catalyst preparation. This task will be conducted after completing process design and system economics analysis. Major milestones include identification of syngas cleaning requirements for proposed system

Zhang, Lingzhi; Wei, Wei; Manke, Jeff; Vazquez, Arturo; Thompson, Jeff; Thompson, Mark

2011-05-28T23:59:59.000Z

56

Cost and performance analysis of biomass-based integrated gasification combined-cycle (BIGCC) power systems  

DOE Green Energy (OSTI)

To make a significant contribution to the power mix in the United States biomass power systems must be competitive on a cost and efficiency basis. We describe the cost and performance of three biomass-based integrated gasification combined cycle (IGCC) systems. The economic viability and efficiency performance of the IGCC generation technology appear to be quite attractive.

Craig, K. R.; Mann, M. K.

1996-10-01T23:59:59.000Z

57

Tampa Electric Company Polk Integrated Gasification Combined Cycle Plant Carbon Capture Retrofit Study  

Science Conference Proceedings (OSTI)

In support of the Industry Technology Demonstration Program on Integrated Gasification Combined Cycle (IGCC) with carbon capture and storage (CCS), an engineering study was conducted to evaluate the cost and performance impacts of various CCS schemes at the Tampa Electric Polk Power Station. The portion of the work presented here was funded by the Electric Power Research Institute (EPRI) IGCC with CCS demonstration program collaborative and focuses on novel CO2 capture and purification systems integrated...

2010-03-30T23:59:59.000Z

58

Syn-Gas Production from Catalytic Steam Gasification of Municipal Solid Wastes in a Combined Fixed Bed Reactor  

Science Conference Proceedings (OSTI)

The catalytic steam gasi?cation of municipal solid wastes (MSW) for syn-gas production was experimentally investigated in a combined fixed bed reactor using the newly developed tri-metallic catalyst. A series of experiments have been performed to explore ... Keywords: Biomass gasification, municipal solid wastes, catalyst, hydrogen production, energy recovery

Jianfen Li; Jianjun Liu; Shiyan Liao; Xiaorong Zhou; Rong Yan

2010-10-01T23:59:59.000Z

59

Catalytic combustor for integrated gasification combined cycle power plant  

DOE Patents (OSTI)

A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

2008-12-16T23:59:59.000Z

60

Carbon Dioxide Capture from Integrated Gasification Combined Cycle Gas Streams Using the Ammonium Carbonate-Ammonium Bicarbonate Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Integrated Gasification Combined Cycle Gas Streams Using the Ammonium Carbonate- Ammonium Bicarbonate Process Description Current commercial processes to remove carbon dioxide (CO 2 ) from conventional power plants are expensive and energy intensive. The objective of this project is to reduce the cost associated with the capture of CO 2 from coal based gasification processes, which convert coal and other carbon based feedstocks to synthesis gas.

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Gasification Systems Projects National Map  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Gasification Systems Projects National Map Click on a number to go to the project page. Hybrid Solar Coal Gasifier ITM Oxygen Technology for Integration in...

62

Tampa Electric Company Integrated Gasification Combined Cycle Project  

SciTech Connect

The proposed project will utilize commercially available gasification technology as provided by Texaco in their licensed oxygen-blown entrained-flow gasifier. In this arrangement, coal is ground to specification and slurried in water to the desired concentration (60--70% solids) in rod mills. This coal slurry and an oxidant (95 % pure oxygen) are then mixed in the gasifier burner where the coal partially combusts, in an oxygen deficient environment, to produce syngas with a heat content of about 250 BTU/SCF (LHV) at a temperature in excess of 2500{degrees}F. The oxygen will be produced from an Air Separation Unit (ASU). The gasifier is expected to achieve greater than 95% carbon conversion in a single pass. It is currently planned for the gasifier to be a single vessel feeding into one radiant syngas cooler where the temperature will be reduced from about 2500{degrees}F to about 1300{degrees}F. After the radiant cooler, the gas will then be split into two (2) parallel convective coolers, where the temperature will be cooled further to about 900{degrees}F. One stream will go to the 50% HGCU system and the other stream to the traditional CGCU system with 100% capacity. This flow arrangement was selected to provide assurance to Tampa Electric that the IGCC capability would not be restricted due to the demonstration of the HGCU system. A traditional amine scrubber type system with conventional sulfur recovery will be used. Sulfur from the HGCU and CGCU systems will be recovered in the form of H{sub 2}SO{sub 4} and elemental sulfur respectively.The key components of the combined cycle are the advanced combustion.turbine (CT), heat recovery steam generator (HRSG), and steam turbine (ST), and generators. The advanced CT will be a GE 7F operating with a firing temperature of about 2300{degrees}F.

Pless, D.E.; Black, C.R.

1992-11-01T23:59:59.000Z

63

Tampa Electric Company Integrated Gasification Combined Cycle Project  

SciTech Connect

The proposed project will utilize commercially available gasification technology as provided by Texaco in their licensed oxygen-blown entrained-flow gasifier. In this arrangement, coal is ground to specification and slurried in water to the desired concentration (60--70% solids) in rod mills. This coal slurry and an oxidant (95 % pure oxygen) are then mixed in the gasifier burner where the coal partially combusts, in an oxygen deficient environment, to produce syngas with a heat content of about 250 BTU/SCF (LHV) at a temperature in excess of 2500[degrees]F. The oxygen will be produced from an Air Separation Unit (ASU). The gasifier is expected to achieve greater than 95% carbon conversion in a single pass. It is currently planned for the gasifier to be a single vessel feeding into one radiant syngas cooler where the temperature will be reduced from about 2500[degrees]F to about 1300[degrees]F. After the radiant cooler, the gas will then be split into two (2) parallel convective coolers, where the temperature will be cooled further to about 900[degrees]F. One stream will go to the 50% HGCU system and the other stream to the traditional CGCU system with 100% capacity. This flow arrangement was selected to provide assurance to Tampa Electric that the IGCC capability would not be restricted due to the demonstration of the HGCU system. A traditional amine scrubber type system with conventional sulfur recovery will be used. Sulfur from the HGCU and CGCU systems will be recovered in the form of H[sub 2]SO[sub 4] and elemental sulfur respectively.The key components of the combined cycle are the advanced combustion.turbine (CT), heat recovery steam generator (HRSG), and steam turbine (ST), and generators. The advanced CT will be a GE 7F operating with a firing temperature of about 2300[degrees]F.

Pless, D.E.; Black, C.R.

1992-01-01T23:59:59.000Z

64

CoalFleet Integrated Gasification Combined Cycle Research and Development Roadmap  

Science Conference Proceedings (OSTI)

This report is an update of EPRI technical report 1013219, “CoalFleet RD&D Augmentation Plan for Integrated Gasification Combined Cycle (IGCC) Power Plants” that was published in January 2007. The purpose of the current study is to evaluate the state of IGCC technology, gauge technology development progress made since 2007, and discuss updated estimates on the potential for advanced technologies to improve power plant performance and economics. The report consists of the following four parts: establishme...

2011-10-31T23:59:59.000Z

65

Integrated Gasification Combined Cycle (IGCC) Design Considerations for CO2 Capture and Storage (CCS)  

Science Conference Proceedings (OSTI)

The objectives of this research were to assess the performance and costs of coal-fired integrated gasification combined cycle (IGCC) power plants with Greenfield and retrofitted carbon dioxide (CO2) capture. The study is part of the CoalFleet Program, a collaborative research and development program that promotes deployment of advanced coal technologies, including IGCC, ultrasupercritical pulverized, oxy-fuel combustion, and supercritical circulating fluidized bed technologies. Two types of coalPittsburg...

2010-10-01T23:59:59.000Z

66

Integrated gasification combined-cycle research development and demonstration activities in the US  

Science Conference Proceedings (OSTI)

The United States Department of Energy (DOE)`s Office of Fossil Energy, Morgantown Energy Technology Center, is managing a research development and demonstration (RD&D) program that supports the commercialization of integrated gasification combined-cycle (IGCC) advanced power systems. This overview briefly describes the supporting RD&D activities and the IGCC projects selected for demonstration in the Clean Coal Technology (CCT) Program.

Ness, H.M.; Brdar, R.D.

1996-09-01T23:59:59.000Z

67

Integrated gasification combined-cycle research development and demonstration activities in the U.S.  

Science Conference Proceedings (OSTI)

The United States Department of Energy (DOE) has selected seven integrated gasification combined-cycle (IGCC) advanced power systems for demonstration in the Clean Coal Technology (CCT) Program. DOE`s Office of Fossil Energy, Morgantown Energy Technology Center, is managing a research development and demonstration (RD&D)program that supports the CCT program, and addresses long-term improvements in support of IGCC technology. This overview briefly describes the CCT projects and the supporting RD&D activities.

Ness, H.M.

1994-12-31T23:59:59.000Z

68

CoalFleet RD&D Augmentation Plan for Integrated Gasification Combined Cycle (IGCC) Power Plants  

Science Conference Proceedings (OSTI)

Advanced, clean coal technologies such as integrated gasification combined cycle (IGCC) offer societies around the world the promise of efficient, affordable power generation at markedly reduced levels of emissions8212including "greenhouse gases" linked to global climate change8212relative to today's current fleet of coal-fired power plants. To help accelerate the development, demonstration, and market introduction of IGCC and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiati...

2007-01-24T23:59:59.000Z

69

Development of a plant-wide dynamic model of an integrated gasification combined cycle (IGCC) plant  

Science Conference Proceedings (OSTI)

In this presentation, development of a plant-wide dynamic model of an advanced Integrated Gasification Combined Cycle (IGCC) plant with CO2 capture will be discussed. The IGCC reference plant generates 640 MWe of net power using Illinois No.6 coal as the feed. The plant includes an entrained, downflow, General Electric Energy (GEE) gasifier with a radiant syngas cooler (RSC), a two-stage water gas shift (WGS) conversion process, and two advanced 'F' class combustion turbines partially integrated with an elevated-pressure air separation unit (ASU). A subcritical steam cycle is considered for heat recovery steam generation. Syngas is selectively cleaned by a SELEXOL acid gas removal (AGR) process. Sulfur is recovered using a two-train Claus unit with tail gas recycle to the AGR. A multistage intercooled compressor is used for compressing CO2 to the pressure required for sequestration. Using Illinois No.6 coal, the reference plant generates 640 MWe of net power. The plant-wide steady-state and dynamic IGCC simulations have been generated using the Aspen Plus{reg_sign} and Aspen Plus Dynamics{reg_sign} process simulators, respectively. The model is generated based on the Case 2 IGCC configuration detailed in the study available in the NETL website1. The GEE gasifier is represented with a restricted equilibrium reactor model where the temperature approach to equilibrium for individual reactions can be modified based on the experimental data. In this radiant-only configuration, the syngas from the Radiant Syngas Cooler (RSC) is quenched in a scrubber. The blackwater from the scrubber bottom is further cleaned in the blackwater treatment plant. The cleaned water is returned back to the scrubber and also used for slurry preparation. The acid gas from the sour water stripper (SWS) is sent to the Claus plant. The syngas from the scrubber passes through a sour shift process. The WGS reactors are modeled as adiabatic plug flow reactors with rigorous kinetics based on the mid-life activity of the shift-catalyst. The SELEXOL unit consists of the H2S and CO2 absorbers that are designed to meet the stringent environmental limits and requirements of other associated units. The model also considers the stripper for recovering H2S that is sent as a feed to a split-flow Claus unit. The tail gas from the Claus unit is recycled to the SELEXOL unit. The cleaned syngas is sent to the GE 7FB gas turbine. This turbine is modeled as per published data in the literature. Diluent N2 is used from the elevated-pressure ASU for reducing the NOx formation. The heat recovery steam generator (HRSG) is modeled by considering generation of high-pressure, intermediate-pressure, and low-pressure steam. All of the vessels, reactors, heat exchangers, and the columns have been sized. The basic IGCC process control structure has been synthesized by standard guidelines and existing practices. The steady-state simulation is solved in sequential-modular mode in Aspen Plus{reg_sign} and consists of more than 300 unit operations, 33 design specs, and 16 calculator blocks. The equation-oriented dynamic simulation consists of more than 100,000 equations solved using a multi-step Gear's integrator in Aspen Plus Dynamics{reg_sign}. The challenges faced in solving the dynamic model and key transient results from this dynamic model will also be discussed.

Bhattacharyya, D.; Turton, R.; Zitney, S.

2009-01-01T23:59:59.000Z

70

NETL: Gasification Systems - Integrated Warm Gas Multicontaminant Cleanup  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas Project Number: DE-FC26-05NT42459 Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas Project ID: DE-FC26-05NT42459 Objective: The objective is to develop a warm multi-contaminant syngas cleaning system for operation between 300 and 700° F. This project will continue development of the RTI warm syngas cleanup technology suite. Based on the field testing results with real syngas from Eastman Chemical Company's gasifier under DOE Contract DE-AC26-99FT40675, additional technical issues need to be addressed to move the technologies used in warm syngas cleaning further towards commercial deployment especially for chemical/fuels production. These issues range from evaluation of startup and standby options for the more developed desulfurization processes to integration and actual pilot plant testing with real coal-derived syngas for the technologies that were tested at bench scale during Phase I. Development shall continue of the warm gas syngas cleaning technology platform through a combination of lab-scale R&D and larger integrated pilot plant testing with real coal-derived syngas as well as process/systems analysis and simulation for optimization of integration and intensification.

71

Bench-scale reactor tests of low-temperature, catalytic gasification of wet, industrial wastes  

DOE Green Energy (OSTI)

Bench-scale reactor tests are under way at Pacific Northwest Laboratory to develop a low-temperature, catalytic gasification system. The system, licensed under the trade name Thermochemical Environmental Energy System (TEES{reg sign}), is designed for to a wide variety of feedstocks ranging from dilute organics in water to waste sludges from food processing. The current research program is focused on the use of a continuous-feed, tubular reactor. The catalyst is nickel metal on an inert support. Typical results show that feedstocks such as solutions of 2% para-cresol or 5% and 10% lactose in water or cheese whey can be processed to >99% reduction of chemical oxygen demand (COD) at a rate of up to 2 L/hr. The estimated residence time is less than 5 min at 360{degree}C and 3000 psig, not including 1 to 2 min required in the preheating zone of the reactor. The liquid hourly space velocity has been varied from 1.8 to 2.9 L feedstock/L catalyst/hr depending on the feedstock. The product fuel gas contains 40% to 55% methane, 35% to 50% carbon dioxide, and 5% to 10% hydrogen with as much as 2% ethane, but less than 0.1% ethylene or carbon monoxide, and small amounts of higher hydrocarbons. The byproduct water stream carries residual organics amounting to less than 500 mg/L COD. 9 refs., 1 fig., 4 tabs.

Elliott, D.C.; Neuenschwander, G.G.; Baker, E.G.; Butner, R.S.; Sealock, L.J.

1990-04-01T23:59:59.000Z

72

Feasibility Studies to Improve Plant Availability and Reduce Total Installed Cost in Integrated Gasification Combined Cycle Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Feasibility Studies to Improve Plant Feasibility Studies to Improve Plant Availability and Reduce Total Installed Cost in Integrated Gasification Combined Cycle Plants Background Gasification provides the means to turn coal and other carbonaceous solid, liquid and gaseous feedstocks as diverse as refinery residues, biomass, and black liquor into synthesis gas and valuable byproducts that can be used to produce low-emissions power, clean-burning fuels and a wide range of commercial products to support

73

Fission energy: The integral fast reactor  

SciTech Connect

The Integral Fast Reactor (IFR) is an innovative reactor concept being developed at Argonne National Laboratory as a such next- generation reactor concept. The IFR concept has a number of specific technical advantages that collectively address the potential difficulties facing the expansion of nuclear power deployment. In particular, the IFR concept can meet all three fundamental requirements needed in a next-generation reactor as discussed below. This document discusses these requirements.

Chang, Yoon I.

1989-01-01T23:59:59.000Z

74

Short Communication Catalytic coal gasification: use of calcium versus potassium*  

E-Print Network (OSTI)

career on process optimization and control, fluid mechanics, the analysis of coal gasification reactors my earlier work on coal gasification reactors, polymer fiber spinning, and the activated sludge

75

Transient studies of an Integrated Gasification Combined Cycle (IGCC) plant with CO2 capture  

SciTech Connect

Next-generation coal-fired power plants need to consider the option for CO2 capture as stringent governmental mandates are expected to be issued in near future. Integrated gasification combined cycle (IGCC) plants are more efficient than the conventional coal combustion processes when the option for CO2 capture is considered. However, no IGCC plant with CO2 capture currently exists in the world. Therefore, it is important to consider the operability and controllability issues of such a plant before it is commercially built. To facilitate this objective, a detailed plant-wide dynamic simulation of an IGCC plant with 90% CO2 capture has been developed in Aspen Plus Dynamics{reg_sign}. The plant considers a General Electric Energy (GEE)-type downflow radiant-only gasifier followed by a quench section. A two-stage water gas shift (WGS) reaction is considered for conversion of CO to CO2. A two-stage acid gas removal (AGR) process based on a physical solvent is simulated for selective capture of H2S and CO2. Compression of the captured CO2 for sequestration, an oxy-Claus process for removal of H2S and NH3, black water treatment, and the sour water treatment are also modeled. The tail gas from the Claus unit is recycled to the SELEXOL unit. The clean syngas from the AGR process is sent to a gas turbine followed by a heat recovery steam generator. This turbine is modeled as per published data in the literature. Diluent N2 is used from the elevated-pressure ASU for reducing the NOx formation. The heat recovery steam generator (HRSG) is modeled by considering generation of high-pressure, intermediate-pressure, and low-pressure steam. All of the vessels, reactors, heat exchangers, and the columns have been sized. The basic IGCC process control structure has been synthesized by standard guidelines and existing practices. The steady state results are validated with data from a commercial gasifier. In the future grid-connected system, the plant should satisfy the environmental targets and quality of the feed to other sections, wherever applicable, without violating the operating constraints, and without sacrificing the efficiency. However, it was found that the emission of acid gases may far exceed the environmental targets and the overshoot of some of the key variables may be unacceptable under transient operation while following the load. A number of operational strategies and control configurations is explored for achieving these stringent requirements. The transient response of the plant is also studied by perturbing a number of key inputs.

Bhattacharyya, D.; Turton, R.; Zitney, S.

2010-01-01T23:59:59.000Z

76

Energy impacts of controlling carbon dioxide emissions from an integrated gasification/combined-cycle system  

SciTech Connect

This paper presents results from a study of the impacts associated with CO{sub 2} recovery in integrated gasification/combined-cycle (IGCC) systems which is being conducted for the Morgantown Energy Technology Center by Argonne National Laboratory. The objective of the study is to compare, on a consistent systems-oriented basis, the energy and economic impacts of adding CO{sub 2} capture and sequestration to an IGCC system. The research reported here has emphasized commercial technologies for capturing CO{sub 2}, but ongoing work is also addressing advanced technologies under development and alternate power-system configurations that may enhance system efficiency.

Livengood, C.D.; Doctor, R.D.; Molburg, J.C.; Thimmapuram, P.

1994-08-01T23:59:59.000Z

77

Feasibility Study for an Integrated Gasification Combined Cycle Facility at a Texas Site  

Science Conference Proceedings (OSTI)

Interest in integrated gasification combined-cycle technology (IGCC) has grown sharply since the passage of the Energy Policy Act in 2005. Many new projects are being planned since the AEP and Duke 600-MW IGCC plants were announced nearly two years ago. This report compares the cost and performance of IGCC with a supercritical pulverized coal plant (SCPC) based on lower-rank Powder River Basin (PRB) coal. IGCC options included 100% PRB and 50/50 PRB/petcoke cases. The addition of CO2 capture equipment al...

2006-10-23T23:59:59.000Z

78

Equilibrium Modeling, Design, Construction, and Validation Testing of a Pilot Scale, USS Gasification Reactor.  

E-Print Network (OSTI)

??Fluidized bed gasification is currently not economically feasible on small and medium scales due to the expensive catalytic reformation of tar. It has been proposed… (more)

Hlebak, Joshua J.

2011-01-01T23:59:59.000Z

79

CoalFleet RD&D augmentation plan for integrated gasification combined cycle (IGCC) power plants  

SciTech Connect

To help accelerate the development, demonstration, and market introduction of integrated gasification combined cycle (IGCC) and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiative, which facilitates collaborative research by more than 50 organizations from around the world representing power generators, equipment suppliers and engineering design and construction firms, the U.S. Department of Energy, and others. This group advised EPRI as it evaluated more than 120 coal-gasification-related research projects worldwide to identify gaps or critical-path activities where additional resources and expertise could hasten the market introduction of IGCC advances. The resulting 'IGCC RD&D Augmentation Plan' describes such opportunities and how they could be addressed, for both IGCC plants to be built in the near term (by 2012-15) and over the longer term (2015-25), when demand for new electric generating capacity is expected to soar. For the near term, EPRI recommends 19 projects that could reduce the levelized cost-of-electricity for IGCC to the level of today's conventional pulverized-coal power plants with supercritical steam conditions and state-of-the-art environmental controls. For the long term, EPRI's recommended projects could reduce the levelized cost of an IGCC plant capturing 90% of the CO{sub 2} produced from the carbon in coal (for safe storage away from the atmosphere) to the level of today's IGCC plants without CO{sub 2} capture. EPRI's CoalFleet for Tomorrow program is also preparing a companion RD&D augmentation plan for advanced-combustion-based (i.e., non-gasification) clean coal technologies (Report 1013221). 7 refs., 30 figs., 29 tabs., 4 apps.

2007-01-15T23:59:59.000Z

80

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxygen Oxygen Commercial Technologies for Oxygen Production Gasification processes require an oxidant, most commonly oxygen; less frequently air or just steam may suffice as the gasification agent depending on the process. Oxygen-blown systems have the advantage of minimizing the size of the gasification reactor and its auxiliary process systems. However, the oxygen for the process must be separated from the atmosphere. Commercial large-scale air separation plants are based on cryogenic distillation technology, capable of supplying oxygen at high purity1 and pressure. This technology is well understood, having been in practice for over 75 years. Cryogenic air separation is recognized for its reliability, and it can be designed for high capacity (up to 5,000 tons per day).

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Coal Gasification Report.indb  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Coal Integrated Coal Gasification Combined Cycle: Market Penetration Recommendations and Strategies Produced for the Department of Energy (DOE)/ National Energy Technology Laboratory (NETL) and the Gasification Technologies Council (GTC) September 2004 Coal-Based Integrated Gasification Combined Cycle: Market Penetration Strategies and Recommendations Final Report Study Performed by:

82

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project, Final Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

S-1 S-1 SUMMARY The U.S. Department of Energy (DOE) prepared this environmental impact statement (EIS) on the proposed Kentucky Pioneer Integrated Gasification Combined Cycle (IGCC) Demonstration Project in compliance with the National Environmental Policy Act (NEPA). The National Environmental Policy Act Process NEPA is a federal law that serves as the basic national charter for protection of the environment. For major federal actions that may significantly affect the quality of the environment, NEPA requires federal agencies to prepare a detailed statement that includes the potential environmental impacts of the Proposed Action and reasonable alternatives. A fundamental objective of NEPA is to foster better decisionmaking by ensuring that high quality environmental information is available to public officials and members of the

83

Method and system to estimate variables in an integrated gasification combined cycle (IGCC) plant  

DOE Patents (OSTI)

System and method to estimate variables in an integrated gasification combined cycle (IGCC) plant are provided. The system includes a sensor suite to measure respective plant input and output variables. An extended Kalman filter (EKF) receives sensed plant input variables and includes a dynamic model to generate a plurality of plant state estimates and a covariance matrix for the state estimates. A preemptive-constraining processor is configured to preemptively constrain the state estimates and covariance matrix to be free of constraint violations. A measurement-correction processor may be configured to correct constrained state estimates and a constrained covariance matrix based on processing of sensed plant output variables. The measurement-correction processor is coupled to update the dynamic model with corrected state estimates and a corrected covariance matrix. The updated dynamic model may be configured to estimate values for at least one plant variable not originally sensed by the sensor suite.

Kumar, Aditya; Shi, Ruijie; Dokucu, Mustafa

2013-09-17T23:59:59.000Z

84

Integrated gasification-combined-cycle power plants - Performance and cost estimates  

SciTech Connect

Several studies of Integrated Gasification-combined-cycle (IGCC) power plants have indicated that these plants have the potential for providing performance and cost improvements over conventional coal-fired steam power plants with flue gas desulfurization. Generally, IGCC power plants have a higher energy-conversion efficiency, require less water, conform with existing environmental standards at lower cost, and are expected to convert coal to electricity at lower costs than coal-fired steam plants. This study compares estimated costs and performance of various IGCC plant design configurations. A second-law analysis identifies the real energy waste in each design configuration. In addition, a thermoeconomic analysis reveals the potential for reducing the cost of electricity generated by an IGCC power plant.

Tsatsaronis, G.; Tawfik, T.; Lin, L. (Tennessee State Univ., Nashville (USA))

1990-04-01T23:59:59.000Z

85

Model predictive control system and method for integrated gasification combined cycle power generation  

DOE Patents (OSTI)

Control system and method for controlling an integrated gasification combined cycle (IGCC) plant are provided. The system may include a controller coupled to a dynamic model of the plant to process a prediction of plant performance and determine a control strategy for the IGCC plant over a time horizon subject to plant constraints. The control strategy may include control functionality to meet a tracking objective and control functionality to meet an optimization objective. The control strategy may be configured to prioritize the tracking objective over the optimization objective based on a coordinate transformation, such as an orthogonal or quasi-orthogonal projection. A plurality of plant control knobs may be set in accordance with the control strategy to generate a sequence of coordinated multivariable control inputs to meet the tracking objective and the optimization objective subject to the prioritization resulting from the coordinate transformation.

Kumar, Aditya; Shi, Ruijie; Kumar, Rajeeva; Dokucu, Mustafa

2013-04-09T23:59:59.000Z

86

Gasification system  

DOE Patents (OSTI)

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

1983-01-01T23:59:59.000Z

87

Gasification system  

DOE Patents (OSTI)

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

1985-01-01T23:59:59.000Z

88

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

NLE Websites -- All DOE Office Websites (Extended Search)

EnhancEd hydrogEn Production EnhancEd hydrogEn Production intEgratEd with co 2 SEParation in a SinglE-StagE rEactor Description One alternative for the United States to establish independence from foreign energy sources is to utilize the nation's abundant domestic reserves of coal. Gasification provides a route to produce liquid fuels, chemical feedstocks, and hydrogen from coal. Coal continues to be viewed as the fuel source for the 21st century. Products from coal gasification, however, contain other gases, particularly carbon dioxide, as well as other contaminants that must be removed to produce the pure stream of hydrogen needed to operate fuel cells and other devices. This project seeks to demonstrate a technology to efficiently produce a pure hydrogen stream from

89

The Integral Fast Reactor (IFR) concept  

SciTech Connect

In addition to maintaining the viability of its present commercial nuclear technology, a principal challenge in the US in the 1990s and beyond will be to regain and maintain a position among the world leadership in advanced reactor research and development. In this paper we'll discuss factors which we believe should today provide the rationale and focus for advanced reactor R and D, and we will then review the status of the major US effort, the Integral Fast Reactor (IFR) program.

Till, C.E.; Chang, Y.I.

1989-01-01T23:59:59.000Z

90

Cost modeling approach and economic analysis of biomass gasification integrated solid oxide fuel cell systems  

Science Conference Proceedings (OSTI)

This paper presents a cost modeling approach and the economic feasibility for selected plant configurations operating under three modes: air gasification

Rajesh S. Kempegowda; Øyvind Skreiberg; Khanh-Quang Tran

2012-01-01T23:59:59.000Z

91

Extractors manual for Integrated Gasification Combined Cycle Data Base System: Major Plants Data Base  

SciTech Connect

National concern over the depletion of conventional energy sources has prompted industry to evaluate coal gasification as an alternative source of energy. One approach being evaluated is gasifying coal in a gasifier and feeding the fuel gas to a combined-cycle power plant. This system is called an Integrated Gasification Combined-Cycle (IGCC) power plant. The US Department of Energy (DOE) is also encouraging the development of new technologies by sponsoring research and development (R and D) projects in IGCC. In order to make data generated from these projects available to government and private sector personnel, the IGCC Data System has been established. A technology-specific data system consists of data that are stored for that technology in each of the specialized data bases that make up the Morgantown Energy Technology Center (METC) data system. The IGCC Data System consists of data stored in the Major Plants Data Base (MPDB) and the Test Data Data Base (TDDB). To capture the results of government-sponsored IGCC research programs, documents have been written for the MPDB and TDDB to specify the data that contractors need to report and the procedures for reporting them. The IGCC documents identify and define the data that need to be reported for IGCC projects so that the data entered into the TDDB and MPDB will meet the needs of the users of the IGCC Data System. This document addresses what information is needed and how it must be formatted so that it can be entered into the MPDB for IGCC. The data that are most relevant to potential IGCC Data System users have been divided into four categories: project tracking needs; economic/commercialization needs; critical performance needs; and modeling and R and D needs. 4 figs., 28 tabs.

1986-11-01T23:59:59.000Z

92

Extractors manual for Integrated Gasification Combined Cycle Data Base System: Test Data Data Base  

SciTech Connect

National concern over the depletion of conventional energy sources has prompted industry to evaluate coal gasification as an alternative source of energy. One approach being evaluated is gasifying coal in a gasifier and feeding the fuel gas to a combined-cycle power plant. This system is called an Integrated Gasification Combined-Cycle (IGCC) power plant. The US Department of Energy (DOE) is also encouraging the development of new technologies by sponsoring research and development (R and D) projects in IGCC. In order to make data generated from these projects available to government and private sector personnel, the IGCC Data System has been established. A technology-specific data system consists of data that are stored for that technology in each of the specialized data bases that make up the Morgantown Energy Technology Center (METC) data system. The IGCC Data System consists of data stored in the Major Plants Data Base (MPDB) and the Test Data Data Base (TDDB). To capture the results of government-sponsored IGCC research programs, documents have been written for the TDDB and MPDB to specify the data that contractors need to report and the procedures for reporting them. The IGCC documents identify and define the data that need to be reported for IGCC projects so that the data entered into the TDDB and MPDB will meet the needs of the users of the IGCC Data System. This document addresses what information is needed and how it must be formatted so that it can be entered into the TDDB for IGCC. The data that are most relevant to potential IGCC Data System users have been divided into four categories: project tracking needs; economic/commercialization needs; critical performance needs; and modeling and R and D needs.

1986-11-01T23:59:59.000Z

93

Biomass gasification integration in recuperative gas turbine cycles and recuperative fuel cell integrated gas turbine cycles.  

E-Print Network (OSTI)

?? A multi-reactor, multi-temperature, waste-heat driven biomass thermochemical converter is proposed and simulated in the process simulation tool Aspen Plus?. The thermochemical converter is in… (more)

Løver, Kristian Aase

2007-01-01T23:59:59.000Z

94

Gasification Technology Status: August 2002  

Science Conference Proceedings (OSTI)

This technical report covers the lessons learned from the integrated gasification combined cycle (IGCC) plants that are now accumulating commercial operating experience. The current gasification experience includes coal, petroleum residuals, biomass, and wastes.

2002-09-30T23:59:59.000Z

95

Preliminary Experimental Results of Integrated Gasification Fuel Cell Operation Using Hardware Simulation  

Science Conference Proceedings (OSTI)

A newly developed integrated gasification fuel cell (IGFC) hybrid system concept has been tested using the Hybrid Performance (Hyper) project hardware-based simulation facility at the U.S. Department of Energy, National Energy Technology Laboratory. The cathode-loop hardware facility, previously connected to the real-time fuel cell model, was integrated with a real-time model of a gasifier of solid (biomass and fossil) fuel. The fuel cells are operated at the compressor delivery pressure, and they are fueled by an updraft atmospheric gasifier, through the syngas conditioning train for tar removal and syngas compression. The system was brought to steady state; then several perturbations in open loop (variable speed) and closed loop (constant speed) were performed in order to characterize the IGFC behavior. Coupled experiments and computations have shown the feasibility of relatively fast control of the plant as well as a possible mitigation strategy to reduce the thermal stress on the fuel cells as a consequence of load variation and change in gasifier operating conditions. Results also provided an insight into the different features of variable versus constant speed operation of the gas turbine section.

Traverso, Alberto; Tucker, David; Haynes, Comas L.

2012-07-01T23:59:59.000Z

96

CoalFleet User Design Basis Specification for Coal-Based Integrated Gasification Combined Cycle (IGCC) Power Plants  

Science Conference Proceedings (OSTI)

The Duke Edwardsport integrated gasification combined-cycle (IGCC) power plant started up in 2012, and Mississippi Power’s Kemper County IGCC plant is in construction. The capital cost of these initial commercial scale IGCC plants is high. The industry needs specifications that encourage greater standardization in IGCC design in order to bring down the investment cost for the next generation of plants. Standardization also supports repeatable, reliable performance and reduces the time and cost ...

2012-12-12T23:59:59.000Z

97

Program on Technology Innovation: Tampa Electric Company Polk Integrated Gasification Combined Cycle Plant Carbon Capture Retrofit Study  

Science Conference Proceedings (OSTI)

In support of the Industry Technology Demonstration Program on Integrated Gasification Combined Cycle (IGCC) with carbon capture and storage (CCS), an engineering study was conducted to evaluate the cost and performance impacts of various CCS schemes at the Tampa Electric Polk Power Station. The portion of the work presented here was funded by the Electric Power Research Institute (EPRI) Technology Innovation Program and focuses on a comparison of chemical and physical solvent-based CO2 capture systems i...

2010-03-30T23:59:59.000Z

98

Gas turbine effects on integrated-gasification-combined-cycle power plant operations  

SciTech Connect

This study used detailed thermodynamic modeling procedures to assess the influence of different gas turbine characteristics and steam cycle conditions on the design and off-design performance of integrated gasification-combined-cycle (IGCC) power plants. IGCC plant simulation models for a base case plant with Texaco gasifiers and both radiant and convective syngas coolers were developed, and three different types of gas turbines were evaluated as well as non-reheat and reheat steam systems. Results indicated that improving the gas turbine heat rate significantly improves the heat rate of the IGCC power plant. In addition results indicated that using a reheat steam system with current gas turbines improves IGCC performance, though as gas turbine efficiency increases, the impact of using a reheat steam system decreases. Increasing gas turbine temperatures from 1985{degree}F to 2500{degree}F was also found to have the potential to reduce overall IGCC system heat rates by approximately 700 BTU/kWh. The methodologies and models developed for this work are extremely useful tools for investigating the impact of specific gas turbine and steam cycle conditions on the overall performance of IGCC power plants. Moreover, they can assist utilities during the preliminary engineering phase of an IGCC project in evaluating the cost effectiveness of using specific gas turbines and steam cycles in the overall plant design. 45 refs., 20 figs., 10 tabs.

Eustis, F.H. (Stanford Univ., CA (USA). High Temperature Gasdynamics Lab.)

1990-03-01T23:59:59.000Z

99

Combustion Engineering Integrated Coal Gasification Combined Cycle Repowering Project: Clean Coal Technology Program  

SciTech Connect

On February 22, 1988, DOE issued Program Opportunity Notice (PON) Number-DE-PS01-88FE61530 for Round II of the CCT Program. The purpose of the PON was to solicit proposals to conduct cost-shared ICCT projects to demonstrate technologies that are capable of being commercialized in the 1990s, that are more cost-effective than current technologies, and that are capable of achieving significant reduction of SO[sub 2] and/or NO[sub x] emissions from existing coal burning facilities, particularly those that contribute to transboundary and interstate pollution. The Combustion Engineering (C-E) Integrated Coal Gasification Combined Cycle (IGCC) Repowering Project was one of 16 proposals selected by DOE for negotiation of cost-shared federal funding support from among the 55 proposals that were received in response to the PON. The ICCT Program has developed a three-level strategy for complying with the National Environmental Policy Act (NEPA) that is consistent with the President's Council on Environmental Quality regulations implementing NEPA (40 CFR 1500-1508) and the DOE guidelines for compliance with NEPA (10 CFR 1021). The strategy includes the consideration of programmatic and project-specific environmental impacts during and subsequent to the reject selection process.

1992-03-01T23:59:59.000Z

100

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project Final Environmental Impact Statement  

Science Conference Proceedings (OSTI)

The abundance of coal in the United States makes it one of our Nation's most important strategic resources in building a secure energy future. With today's prices and technology, recoverable reserves located in the United States could supply the Nation's coal consumption for approximately 250 years at current usage rates. However, if coal is to reach its full potential as an environmentally acceptable source of energy, an expanded menu of advanced clean coal technologies must be developed to provide substantially improved options both for the consumer and private industry. Before any technology can be seriously considered for commercialization, it must be demonstrated at a sufficiently large-scale to develop industry confidence in its technical and economic feasibility. The implementation of a federal technology demonstration program is the established means of accelerating the development of technology to meet national energy strategy and environmental policy goals, to reduce the risk to human health and the environment to an acceptable level, to accelerate commercialization, and to provide the incentives required for continued activity in research and development directed at providing solutions to long-range energy problems. The U.S. Department of Energy (DOE) prepared this environmental impact statement (EIS) on the proposed Kentucky Pioneer Integrated Gasification Combined Cycle (IGCC) Demonstration Project in compliance with the National Environmental Policy Act (NEPA).

N /A

2002-12-13T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Final Report Environmental Footprints and Costs of Coal-Based Integrated Gasification Combined Cycle and  

E-Print Network (OSTI)

Currently, over 50 percent of electricity in the U.S. is generated from coal. Given that coal reserves in the U.S. are estimated to meet our energy needs over the next 250 years, coal is expected to continue to play a major role in the generation of electricity in this country. With dwindling supplies and high prices of natural gas and oil, a large proportion of the new power generation facilities built in the U.S. can be expected to use coal as the main fuel. The environmental impact of these facilities can only be minimized by innovations in technology that allow for efficient burning of coal, along with an increased capture of the air pollutants that are an inherent part of coal combustion. EPA considers integrated gasification combined cycle (IGCC) as one of the most promising technologies in reducing environmental consequences of generating electricity from coal. EPA has undertaken several initiatives to facilitate and incentivize development and deployment of this technology. This report is the result of one of these initiatives and it represents the combined efforts of a joint EPA/DOE team formed to advance the IGCC technology. The various offices within DOE that participated in the development/review of this report were the Office of Fossil Energy, including the Clean Coal Office and the National Energy Technology Laboratory.

Pulverized Coal; Technologies Foreword

2006-01-01T23:59:59.000Z

102

Combustion Engineering Integrated Coal Gasification Combined Cycle Repowering Project, Clean Coal Technology Program  

Science Conference Proceedings (OSTI)

The DOE entered into a cooperative agreement with Combustion Engineering, Inc. (C-E) under which DOE proposes to provide cost-shared funding to design, construct, and operate an Integrated Coal Gasification Combined Cycle (IGCC) project to repower an existing steam turbine generator set at the Springfield (Illinois) City Water, Light and Power (CWL P) Lakeside Generating Station, while capturing 90% of the coal's sulfur and producing elemental sulfur as a salable by-product. The proposed demonstration would help determine the technical and economic feasibility of the proposed IGCC technology on a scale that would allow the utility industry to assess its applicability for repowering other coal-burning power plants. This Environmental Assessment (EA) has been prepared by DOE in compliance with the requirements of National Environmental Policy Act (NEPA). The sources of information for this EA include the following: C-E's technical proposal for the project submitted to DOE in response to the Innovative Clean Coal Technology (ICCT) Program Opportunity Notice (PON); discussions with C-E and CWL P staff; the volume of environmental information for the project and its supplements provided by C-E; and a site visit to the proposed project site.

Not Available

1992-03-01T23:59:59.000Z

103

Combustion Engineering Integrated Coal Gasification Combined Cycle Repowering Project, Clean Coal Technology Program. Environmental Assessment  

Science Conference Proceedings (OSTI)

The DOE entered into a cooperative agreement with Combustion Engineering, Inc. (C-E) under which DOE proposes to provide cost-shared funding to design, construct, and operate an Integrated Coal Gasification Combined Cycle (IGCC) project to repower an existing steam turbine generator set at the Springfield (Illinois) City Water, Light and Power (CWL&P) Lakeside Generating Station, while capturing 90% of the coal`s sulfur and producing elemental sulfur as a salable by-product. The proposed demonstration would help determine the technical and economic feasibility of the proposed IGCC technology on a scale that would allow the utility industry to assess its applicability for repowering other coal-burning power plants. This Environmental Assessment (EA) has been prepared by DOE in compliance with the requirements of National Environmental Policy Act (NEPA). The sources of information for this EA include the following: C-E`s technical proposal for the project submitted to DOE in response to the Innovative Clean Coal Technology (ICCT) Program Opportunity Notice (PON); discussions with C-E and CWL&P staff; the volume of environmental information for the project and its supplements provided by C-E; and a site visit to the proposed project site.

Not Available

1992-03-01T23:59:59.000Z

104

NETL: Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Brochures Gasification Systems Reference Shelf - Brochures The Gasification Technology brochures are as follows: Gasification Plant Databases (Aug 2013) Gasification Systems...

105

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

DOE Green Energy (OSTI)

Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

2012-06-20T23:59:59.000Z

106

Steady-state simulation and optimization of an integrated gasification combined cycle power plant with CO2 capture  

SciTech Connect

Integrated gasification combined cycle (IGCC) plants are a promising technology option for power generation with carbon dioxide (CO2) capture in view of their efficiency and environmental advantages over conventional coal utilization technologies. This paper presents a three-phase, top-down, optimization-based approach for designing an IGCC plant with precombustion CO2 capture in a process simulator environment. In the first design phase, important global design decisions are made on the basis of plant-wide optimization studies with the aim of increasing IGCC thermal efficiency and thereby making better use of coal resources and reducing CO2 emissions. For the design of an IGCC plant with 90% CO2 capture, the optimal combination of the extent of carbon monoxide (CO) conversion in the water-gas shift (WGS) reactors and the extent of CO2 capture in the SELEXOL process, using dimethylether of polyethylene glycol as the solvent, is determined in the first phase. In the second design phase, the impact of local design decisions is explored considering the optimum values of the decision variables from the first phase as additional constraints. Two decisions are made focusing on the SELEXOL and Claus unit. In the third design phase, the operating conditions are optimized considering the optimum values of the decision variables from the first and second phases as additional constraints. The operational flexibility of the plant must be taken into account before taking final design decisions. Two studies on the operational flexibility of the WGS reactors and one study focusing on the operational flexibility of the sour water stripper (SWS) are presented. At the end of the first iteration, after executing all the phases once, the net plant efficiency (HHV basis) increases to 34.1% compared to 32.5% in a previously published study (DOE/NETL-2007/1281; National Energy Technology Laboratory, 2007). The study shows that the three-phase, top-down design approach presented is very useful and effective in a process simulator environment for improving efficiency and flexibility of IGCC power plants with CO2 capture. In addition, the study identifies a number of key design variables that has strong impact on the efficiency of an IGCC plant with CO2 capture.

Bhattacharyya, D.; Turton, R.; Zitney, S.

2011-01-01T23:59:59.000Z

107

Thermal energy storage for integrated gasification combined-cycle power plants  

SciTech Connect

There are increasingly strong indications that the United States will face widespread electrical power generating capacity constraints in the 1990s; most regions of the country could experience capacity shortages by the year 2000. The demand for new generating capacity occurs at a time when there is increasing emphasis on environmental concerns. The integrated gasification combined-cycle (IGCC) power plant is an example of an advanced coal-fired technology that will soon be commercially available. The IGCC concept has proved to be efficient and cost-effective while meeting all current environmental regulations on emissions; however, the operating characteristics of the IGCC system have limited it to base load applications. The integration of thermal energy storage (TES) into an IGCC plant would allow it to meet cyclic loads while avoiding undesirable operating characteristics such as poor turn-down capability, impaired part-load performance, and long startup times. In an IGCC plant with TES, a continuously operated gasifier supplies medium-Btu fuel gas to a continuously operated gas turbine. The thermal energy from the fuel gas coolers and the gas turbine exhaust is stored as sensible heat in molten nitrate salt; heat is extracted during peak demand periods to produce electric power in a Rankine steam power cycle. The study documented in this report was conducted by Pacific Northwest Laboratory (PNL) and consists of a review of the technical and economic feasibility of using TES in an IGCC power plant to produce intermediate and peak load power. The study was done for the US Department of Energy's (DOE) Office of Energy Storage and Distribution. 11 refs., 5 figs., 18 tabs.

Drost, M.K.; Antoniak, Z.I.; Brown, D.R.; Somasundaram, S.

1990-07-01T23:59:59.000Z

108

Thermal energy storage for integrated gasification combined-cycle power plants  

DOE Green Energy (OSTI)

There are increasingly strong indications that the United States will face widespread electrical power generating capacity constraints in the 1990s; most regions of the country could experience capacity shortages by the year 2000. The demand for new generating capacity occurs at a time when there is increasing emphasis on environmental concerns. The integrated gasification combined-cycle (IGCC) power plant is an example of an advanced coal-fired technology that will soon be commercially available. The IGCC concept has proved to be efficient and cost-effective while meeting all current environmental regulations on emissions; however, the operating characteristics of the IGCC system have limited it to base load applications. The integration of thermal energy storage (TES) into an IGCC plant would allow it to meet cyclic loads while avoiding undesirable operating characteristics such as poor turn-down capability, impaired part-load performance, and long startup times. In an IGCC plant with TES, a continuously operated gasifier supplies medium-Btu fuel gas to a continuously operated gas turbine. The thermal energy from the fuel gas coolers and the gas turbine exhaust is stored as sensible heat in molten nitrate salt; heat is extracted during peak demand periods to produce electric power in a Rankine steam power cycle. The study documented in this report was conducted by Pacific Northwest Laboratory (PNL) and consists of a review of the technical and economic feasibility of using TES in an IGCC power plant to produce intermediate and peak load power. The study was done for the US Department of Energy's (DOE) Office of Energy Storage and Distribution. 11 refs., 5 figs., 18 tabs.

Drost, M.K.; Antoniak, Z.I.; Brown, D.R.; Somasundaram, S.

1990-07-01T23:59:59.000Z

109

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Usage in Coal to Electrical Applications Usage in Coal to Electrical Applications The Integrated Gasification Combined Cycle (IGCC) application of gasification offers some water-saving advantages over other technologies for producing electricity from coal. Regions with limited water resources, typical of many parts of the western United States, could conserve resources by meeting increasing electricity demand with IGCC generation. Many of these areas have good coal resources and a need for new generating capacity. Water use in a thermoelectric power plant is described by two separate terms: water withdrawal and water consumption. Water withdrawal is the amount of water taken into the plant from an outside source. Water consumption refers to the portion of the withdrawn water that is not returned directly to the outside source - for example, water lost to evaporative cooling.

110

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

CO2: CO2 Capture: Impacts on IGCC Plant Designs CO2: CO2 Capture: Impacts on IGCC Plant Designs Specific Impacts on IGCC Plant Designs from CO2 Capture In foregoing discussion, results of NETL's comprehensive study comparing the performance and cost of various fossil fuel-based power generation technologies with and without CO2 capture were reviewed. Of particular interest in that study was the companion set of integrated gasification combined cycle (IGCC) designs, using GE's gasification technology, which can be used to illustrate the design changes needed for CO2 capture. Current Technology - IGCC Plant Design Figure 1 shows a simplified block flow diagram (BFD) of a market-ready IGCC design without CO2 capture. As shown, the IGCC plant consists of the following processing islands, of which a more detailed description of each can be found in the cited NETL referenced report: 1

111

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Closely Aligned Programs Gasification Systems Technologies Closely Aligned Programs The Department of Energy's (DOE) Gasification Systems is conducted under the Clean Coal Research...

112

Advanced Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Gasification Carbon feedstock gasification is a promising pathway for high-efficiency, low-pollutant power generation and chemical production. The inability, however, to...

113

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Events Gasification Current Calendar of Events Below are events that are specifically related to Gasification. Also visit the NETL Events page to learn about other events....

114

Integrated Sensing and Controls for Coal Gasification - Development of Model-Based Controls for GE's Gasifier and Syngas Cooler  

Science Conference Proceedings (OSTI)

This report summarizes the achievements and final results of this program. The objective of this program is to develop a comprehensive systems approach to integrated design of sensing and control systems for an Integrated Gasification Combined Cycle (IGCC) plant, using advanced model-based techniques. In particular, this program is focused on the model-based sensing and control system design for the core gasification section of an IGCC plant. The overall approach consists of (i) developing a first-principles physics-based dynamic model of the gasification section, (ii) performing model-reduction where needed to derive low-order models suitable for controls analysis and design, (iii) developing a sensing system solution combining online sensors with model-based estimation for important process variables not measured directly, and (iv) optimizing the steady-state and transient operation of the plant for normal operation as well as for startup using model predictive controls (MPC). Initially, available process unit models were implemented in a common platform using Matlab/Simulink{reg_sign}, and appropriate model reduction and model updates were performed to obtain the overall gasification section dynamic model. Also, a set of sensor packages were developed through extensive lab testing and implemented in the Tampa Electric Company IGCC plant at Polk power station in 2009, to measure temperature and strain in the radiant syngas cooler (RSC). Plant operation data was also used to validate the overall gasification section model. The overall dynamic model was then used to develop a sensing solution including a set of online sensors coupled with model-based estimation using nonlinear extended Kalman filter (EKF). Its performance in terms of estimating key unmeasured variables like gasifier temperature, carbon conversion, etc., was studied through extensive simulations in the presence sensing errors (noise and bias) and modeling errors (e.g. unknown gasifier kinetics, RSC fouling). In parallel, an MPC solution was initially developed using ideal sensing to optimize the plant operation during startup pre-heating as well as steady state and transient operation under normal high-pressure conditions, e.g. part-load, base-load, load transition and fuel changes. The MPC simulation studies showed significant improvements both for startup pre-heating and for normal operation. Finally, the EKF and MPC solutions were coupled to achieve the integrated sensing and control solution and its performance was studied through extensive steady state and transient simulations in the presence of sensor and modeling errors. The results of each task in the program and overall conclusions are summarized in this final report.

Aditya Kumar

2010-12-30T23:59:59.000Z

115

The potential for control of carbon dioxide emissions from integrated gasification/combined-cycle systems  

SciTech Connect

Initiatives to limit carbon dioxide (CO{sub 2}) emissions have drawn considerable interest to integrated gasification/combined-cycle (IGCC) power generation, a process that reduces CO{sub 2} production through efficient fuel used is amenable to CO{sub 2} capture. This paper presents a comparison of energy systems that encompass fuel supply, an IGCC system, CO{sub 2} recovery using commercial technologies, CO{sub 2} transport by pipeline, and land-based sequestering in geological reservoirs. The intent is to evaluate the energy-efficiency impacts of controlling CO{sub 2} in such systems and to provide the CO{sub 2} budget, or an to equivalent CO{sub 2}`` budget, associated with each of the individual energy-cycle steps. The value used for the ``equivalent CO{sub 2}`` budget is 1 kg/kWh CO{sub 2}. The base case for the comparison is a 457-MW IGCC system that uses an air-blown Kellogg-Rust-Westinghouse (KRW) agglomerating fluidized-bed gasifier, Illinois No. 6 bituminous coal, and in-bed sulfur removal. Mining, preparation, and transportation of the coal and limestone result in a net system electric power production of 454 MW with a 0.835 kg/kwh CO{sub 2} release rate. For comparison, the gasifier output is taken through a water-gas shift to convert CO to CO{sub 2} and then processed in a glycol-based absorber unit to recover CO{sub 2} Prior to the combustion turbine. A 500-km pipeline then transports the CO{sub 2} for geological sequestering. The net electric power production for the system with CO{sub 2} recovery is 381 MW with a 0.156 kg/kwh CO{sub 2} release rate.

Livengood, C.D.; Doctor, R.D.; Molburg, J.C.; Thimmapuram, P.; Berry, G.F.

1994-06-01T23:59:59.000Z

116

Highly Selective H2 Separation Zeolite Membranes for Coal Gasification Membrane Reactor Applications  

DOE Green Energy (OSTI)

Zeolite membranes are thermally, chemically, and mechanically stable. They also have tunable molecular sieving and catalytic ability. These unique properties make zeolite membrane an excellent candidate for use in catalytic membrane reactor applications related to coal conversion and gasification, which need high temperature and high pressure range separation in chemically challenging environment where existing technologies are inefficient or unable to operate. Small pore, good quality, and thin zeolite membranes are needed for highly selective H2 separation from other light gases (CO2, CH4, CO). However, current zeolite membranes have either too big zeolite pores or a large number of defects and have not been successful for H2 separation from light gases. The objective of this study is to develop zeolite membranes that are more suitable for H2 separation. In an effort to tune the size of zeolite pores and/or to decrease the number of defects, medium-pore zeolite B-ZSM-5 (MFI) membranes were synthesized and silylated. Silylation on B-ZSM-5 crystals reduced MFI-zeolite pore volume, but had little effect on CO2 and CH4 adsorption. Silylation on B-ZSM-5 membranes increased H2 selectivity both in single component and in mixtures with CO2, CH4, or N2. Single gas and binary mixtures of H2/CO2 and H2/CH4 were permeated through silylated B-ZSM-5 membranes at feed pressures up to 1.7 MPa and temperatures up to 773 K. For one B-ZSM-5 membrane after silylation, the H2/CO2 separation selectivity at 473 K increased from 1.4 to 37, whereas the H2/CH4 separation selectivity increased from 1.6 to 33. Hydrogen permeance through a silylated BZSM-5 membrane was activated with activation energy of {approx}10 kJ/mol, but the CO2 and CH4 permeances decreased slightly with temperature in both single gas and in mixtures. Therefore, the H2 permeance and H2/CO2 and H2/CH4 separation selectivities increased with temperature. At 673 K, the H2 permeance was 1.0x10-7 mol{center_dot}m-2{center_dot}s-1{center_dot}Pa-1, and the H2/CO2 separation selectivity was 47. Above 673 K, the silylated membrane catalyzed reverse water gas shift reaction and still separated H2 with high selectivity; and it was thermally stable. However, silylation decreased H2 permeance more than one order of magnitude. Increasing the membrane feed pressure increased the H2 flux and the H2 mole fraction in the permeate stream for both H2/CO2 and H2/CH4 mixtures. The H2 separation performance of the silylated B-ZSM-5 membranes depended on the initial membrane quality and acidity, as well as the silane precursors. Another approach used in this study is optimizing the synthesis of small-pore SAPO-34 (CHA) membranes and/or modifying SAPO-34 membranes by silylation or ion exchange. For SAPO-34 membranes, strong CO2 adsorption inhibited H2 adsorption and decreased H2 permeances, especially at low temperatures. At 253 K, CO2/H2 separation selectivities of a SAPO-34 membrane were greater than 100 with CO2 permeances of about 3 x 10-8 mol{center_dot}m-2{center_dot}s-1{center_dot}Pa-1. The high reverse-selectivity of the SAPO-34 membranes can minimize H2 recompression because H2 remained in the retentate stream at a higher pressure. The CO2/H2 separation selectivity exhibited a maximum with CO2 feed concentration possibly caused by a maximum in the CO2/H2 sorption selectivity with increased CO2 partial pressure. The SAPO-34 membrane separated H2 from CH4 because CH4 is close to the SAPO-34 pore size so its diffusivity (ABSTRACT TRUNCATED)

Mei Hong; Richard Noble; John Falconer

2007-09-24T23:59:59.000Z

117

Acid Gas Removal by Customized Sorbents for Integrated Gasification Fuel Cell Systems  

DOE Green Energy (OSTI)

In order to reduce exergy losses, gas cleaning at high temperatures is favored in IGFC systems. As shown by thermodynamic data, separation efficiencies of common sorbents decrease with increasing temperature. Therefore, acid gas removal systems have to be developed for IGFC applications considering sorbent capacity, operation temperature, gasification feedstock composition and fuel cell threshold values.

Kapfenberger, J.; Sohnemann, J.; Schleitzer, D.; Loewen, A.

2002-09-20T23:59:59.000Z

118

EIS-0429: Department of Energy Loan Guarantee for Indiana Integrated Gasification Combined Cycle, Rockport, IN  

Energy.gov (U.S. Department of Energy (DOE))

This EIS evaluates the environmental impacts of a coal-to-substitute natural gas facility proposed to be built in Rockport, IN by Indiana Gasification. The facility would utilize Illinois Basin coal. Other products would be marketable sulfuric acid, argon, and electric power.

119

EIS-0428: Department of Energy Loan Guarantee for Mississippi Integrated Gasification Combined Cycle, Moss Point, Mississippi  

Energy.gov (U.S. Department of Energy (DOE))

This EIS evaluates the environmental impacts of a petroleum coke-to-substitute natural gas facility proposed to be built by Mississippi Gasification. The facility would be designed to produce 120 million standard cubic feet of gas per day. Other products would be marketable sulfuric acid, carbon dioxide, argon, and electric power.

120

The Integral Fast Reactor (IFR) - Reactors designed/built by Argonne  

NLE Websites -- All DOE Office Websites (Extended Search)

Integral Fast Reactor Integral Fast Reactor About Director's Welcome Organization Achievements Highlights Fact Sheets, Brochures & Other Documents Multimedia Library Visit Argonne Work with Argonne Contact us Nuclear Energy Why Nuclear Energy? Why are some people afraid of Nuclear Energy? How do nuclear reactors work? Cheaper & Safer Nuclear Energy Helping to Solve the Nuclear Waste Problem Nuclear Reactors Nuclear Reactors Early Exploration Training Reactors Basic and Applied Science Research LWR Technology Development BORAX-III lighting Arco, Idaho (Press Release) Heavy Water and Graphite Reactors Fast Reactor Technology Integral Fast Reactor Argonne Reactor Tree CP-1 70th Anniversary CP-1 70th Anniversary Argonne's Nuclear Science and Technology Legacy Argonne's Nuclear Science and Technology Legacy

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121

Materials Reliability Program: Reactor Pressure Vessel Integrity Primer (MRP-278)  

Science Conference Proceedings (OSTI)

This primer is based on two earlier Electric Power Research Institute (EPRI) reports: Reactor Vessel Embrittlement Management Handbook: A Handbook for Managing Reactor Vessel Embrittlement and Vessel Integrity (TR-101975-T2) and Primer: Fracture Mechanics in the Nuclear Power Industry (NP-5792-SR, Rev. 1). The information in those earlier reports has been updated extensively and focuses on todays reactor pressure vessel (RPV) embrittlement, integrity, and plant license renewal issues. This RPV integrity ...

2010-06-09T23:59:59.000Z

122

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Background Gasification Background Challenges for Gasification The widespread market penetration of gasification continues to face some challenges. Over the years, gasification challenges related to gasifier and supporting unit availability, operability, and maintainability have been addressed with substantial success, and new implementations of gasification will continue to improve in this area. At present, perhaps the most significant remaining challenge is the relatively high capital costs of gasification plants, particularly given the low capital investment required for NGCC-based power production combined with low natural gas prices currently being experienced in the domestic market. Accordingly, technology that can decrease capital costs of gasification systems and plant supporting systems will be most important towards further deployment of gasification.

123

Gasification Technology Status -- December 2008  

Science Conference Proceedings (OSTI)

Over the past 5 years, several major power companies have been developing and conducting detailed design studies of commercial-sized coal-based integrated gasification combined-cycle (IGCC) and pulverized coal (PC) projects. Integrated gasification combined-cycle (IGCC) plants can meet very stringent emissions targets, including those for mercury and CO2. This report covers current IGCC designs being offered and reviews the commercial status of gasification technologies, potential improvements, and lesso...

2008-12-18T23:59:59.000Z

124

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project, Final Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Comments Comments Kentucky Pioneer IGCC Demonstration Project Final Environmental Impact Statement Clark County Public Library Winchester, KY Page 1 of 5 D-1 Comment No. 1 Issue Code: 11 Gasification is different from incineration. It is a better, more environmentally responsible approach to generating energy from the use of fossil fuels and refuse derived fuel (RDF). Incineration produces criteria pollutants, semi-volatile and volatile organic compounds and dioxin/furan compounds. Ash from hazardous waste incinerators is considered a hazardous waste under the Resource Conservation and Recovery Act (RCRA). In contrast, gasification, which occurs at high temperatures and pressures, produces no air emissions, only small amounts of wastewater containing salts. Synthesis gas (syngas)

125

Gary J. stiegel Gasification Technology Manager  

E-Print Network (OSTI)

ContaCts Gary J. stiegel Gasification Technology Manager National Energy Technology Laboratory 626. Box 880 Morgantown, MV 26507 304-285-4685 madhava.syamlal@netl.doe.gov 8/2006 Gasification to address. Development of a chemical-looping fuels-reactor model was started. · Transport Gasifer: MFIX

126

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

(kWh) to 8.25 centskWh. Chemical Solvents Diagram Pre-Combustion CO2 Capture for Gasification Application Pre-combustion CO2 capture related to a gasification plant is...

127

Gasification Systems Projects & Performers  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Gasification Systems Projects & Performers Gasification Systems - Key Technologies Feed Systems Gasifier Optimization and Plant Supporting Systems Syngas...

128

Gasification Technologie: Opportunities & Challenges  

SciTech Connect

This course has been put together to provide a single source document that not only reviews the historical development of gasification but also compares the process to combustion. It also provides a short discussion on integrated gasification and combined cycle processes. The major focus of the course is to describe the twelve major gasifiers being developed today. The hydrodynamics and kinetics of each are reviewed along with the most likely gas composition from each of the technologies when using a variety of fuels under different conditions from air blown to oxygen blown and atmospheric pressure to several atmospheres. If time permits, a more detailed discussion of low temperature gasification will be included.

Breault, R.

2012-01-01T23:59:59.000Z

129

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Cleanup: Syngas Contaminant Removal and Conditioning Syngas Cleanup: Syngas Contaminant Removal and Conditioning Acid Gas Removal (AGR) Acid gases produced in gasification processes mainly consist of hydrogen sulfide (H2S), carbonyl sulfide (COS), and carbon dioxide (CO2). Syngas exiting the particulate removal and gas conditioning systems, typically near ambient temperature at 100°F, needs to be cleaned of the sulfur-bearing acid gases to meet either environmental emissions regulations, or to protect downstream catalysts for chemical processing applications. For integrated gasification combined cycle (IGCC) applications, environmental regulations require that the sulfur content of the product syngas be reduced to less than 30 parts per million by volume (ppmv) in order to meet the stack gas emission target of less than 4 ppmv sulfur dioxide (SO2)1. In IGCC applications, where selective catalytic reduction (SCR) is required to lower NOx emissions to less than 10 ppmv, syngas sulfur content may have to be lowered to 10 to 20 ppmv in order to prevent ammonium bisulfate fouling of the heat recovery steam generator's (HRSG) cold end tubes. For fuels production or chemical production, the downstream synthesis catalyst sulfur tolerance dictates the sulfur removal level, which can be less than 0.1 ppmv.

130

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents (OSTI)

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2011-01-18T23:59:59.000Z

131

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents (OSTI)

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D.; Dumesic, James A.

2013-04-02T23:59:59.000Z

132

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents (OSTI)

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2012-04-10T23:59:59.000Z

133

The role of Integrated Gasification Combined Cycle in the USDOE`s Clean Coal Research, Development and Demonstration Program  

SciTech Connect

For many years, the US Department of Energy (DOE) has been funding research, development, and demonstration (RD&D) projects to develop advanced power generation technologies. The goal of this activity is to catalyze the private sector to commercialize technologies that will provide reasonably priced electricity and still meet stringent environmental standards. Integrated Gasification Combined Cycle (IGCC) systems are emerging as one of the more attractive candidate technologies to meet this goal. The Morgantown Energy Technology Center (METC) has been assigned the responsibility for implementing IGCC projects in DOE`s Clean Coal RD&D program. The IGCC technology offers the potential for significant Improvements in environmental performance, compared to today`s coal-fired power plants. Sulfur dioxide and nitrogen oxide emissions from IGCC systems will be less than one-tenth of existing environmental standards. Thus, the IGCC technology will make coal-based plants as clean as plants that bum natural gas.

Bajura, R.A.; Schmidt, D.K.

1993-06-01T23:59:59.000Z

134

Integrated Gasification Combined Cycle (IGCC) demonstration project, Polk Power Station -- Unit No. 1. Annual report, October 1993--September 1994  

SciTech Connect

This describes the Tampa Electric Company`s Polk Power Station Unit 1 (PPS-1) Integrated Gasification Combined Cycle (IGCC) demonstration project which will use a Texaco pressurized, oxygen-blown, entrained-flow coal gasifier to convert approximately 2,300 tons per day of coal (dry basis) coupled with a combined cycle power block to produce a net 250 MW electrical power output. Coal is slurried in water, combined with 95% pure oxygen from an air separation unit, and sent to the gasifier to produce a high temperature, high pressure, medium-Btu syngas with a heat content of about 250 Btu/scf (LHV). The syngas then flows through a high temperature heat recovery unit which cools the syngas prior to its entering the cleanup systems. Molten coal ash flows from the bottom of the high temperature heat recovery unit into a water-filled quench chamber where it solidifies into a marketable slag by-product.

NONE

1995-05-01T23:59:59.000Z

135

Investigation of an integrated switchgrass gasification/fuel cell power plant. Final report for Phase 1 of the Chariton Valley Biomass Power Project  

DOE Green Energy (OSTI)

The Chariton Valley Biomass Power Project, sponsored by the US Department of Energy Biomass Power Program, has the goal of converting switchgrass grown on marginal farmland in southern Iowa into electric power. Two energy conversion options are under evaluation: co-firing switchgrass with coal in an existing utility boiler and gasification of switchgrass for use in a carbonate fuel cell. This paper describes the second option under investigation. The gasification study includes both experimental testing in a pilot-scale gasifier and computer simulation of carbonate fuel cell performance when operated on gas derived from switchgrass. Options for comprehensive system integration between a carbonate fuel cell and the gasification system are being evaluated. Use of waste heat from the carbonate fuel cell to maximize overall integrated plant efficiency is being examined. Existing fuel cell power plant design elements will be used, as appropriate, in the integration of the gasifier and fuel cell power plant to minimize cost complexity and risk. The gasification experiments are being performed by Iowa State University and the fuel cell evaluations are being performed by Energy Research Corporation.

Brown, R.C.; Smeenk, J. [Iowa State Univ., Ames, IA (United States); Steinfeld, G. [Energy Research Corp., Danbury, CT (United States)

1998-09-30T23:59:59.000Z

136

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network (OSTI)

Using Self-Sustained Hydro- Gasification." [0011] In aprocess, using a steam hydro-gasification reactor (SHR) thepyrolysis and hydro-gasification in a single step. This

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

137

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal: AlternativesSupplements to Coal - Feedstock Flexibility Waste Streams Gasification can be applied to a variety of waste streams, of which municipal solid waste (MSW)...

138

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

runs a very active Carbon Storage Program as a companion strategic activity to gasification, under the Coal and Power Systems Program. Also, see the Carbon Sequestration...

139

Gasification Users Association Update, June 2013  

Science Conference Proceedings (OSTI)

The Gasification Users Group (GUA) Update is published quarterly and provides information on gasification projects in development and in construction, along with a summary of new integrated gasification combined cycle (IGCC)/ gasification technology developments.  The following articles are featured in this issue of the GUA Update:Quarterly SummaryOngoing U.S. Energy Program UpdatesEuropean Union Plans Support of Multiple CCS ...

2013-07-31T23:59:59.000Z

140

Gasification Users Association Newsletter: June 2012  

Science Conference Proceedings (OSTI)

The Gasification Users Group (GUA) Update is published quarterly and provides information on gasification projects in development and in construction, along with a summary of new integrated gasification combined cycle (IGCC)/ gasification technology developments. The following articles are featured in this issue of the GUA Update: Quarterly Summary Ongoing U.S. Energy Program Updates European Union Plans Support of Multiple CCS Projects News Items on Operating IGCC Plants U.S. IGCC Project Updates Inte...

2012-07-20T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Gasification Users Association Newsletter: September 2012  

Science Conference Proceedings (OSTI)

The Gasification Users Group (GUA) Update is published quarterly and provides information on gasification projects in development and in construction, along with a summary of new integrated gasification combined cycle (IGCC)/ gasification technology developments.  The following articles are featured in this issue of the GUA Update:Quarterly SummaryOngoing U.S. Energy Program UpdatesEuropean Union Plans Support of Multiple CCS ...

2012-10-12T23:59:59.000Z

142

Gasification Users Association (GUA) Update, September 2013  

Science Conference Proceedings (OSTI)

The Gasification Users Association (GUA) Update is published quarterly and provides information on gasification projects in development and in construction, along with a summary of new integrated gasification combined cycle (IGCC)/ gasification technology developments. The following articles are featured in this issue of the GUA Update:Quarterly SummaryOngoing U.S. Energy Program UpdatesNews Items on Operating IGCC PlantsU.S. ...

2013-10-30T23:59:59.000Z

143

Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies  

DOE Green Energy (OSTI)

This report documents the National Renewable Energy Laboratory's (NREL's) assessment of the feasibility of making gasoline via the methanol-to-gasoline route using syngas from a 2,000 dry metric tonne/day (2,205 U.S. ton/day) biomass-fed facility. A new technoeconomic model was developed in Aspen Plus for this study, based on the model developed for NREL's thermochemical ethanol design report (Phillips et al. 2007). The necessary process changes were incorporated into a biomass-to-gasoline model using a methanol synthesis operation followed by conversion, upgrading, and finishing to gasoline. Using a methodology similar to that used in previous NREL design reports and a feedstock cost of $50.70/dry ton ($55.89/dry metric tonne), the estimated plant gate price is $16.60/MMBtu ($15.73/GJ) (U.S. $2007) for gasoline and liquefied petroleum gas (LPG) produced from biomass via gasification of wood, methanol synthesis, and the methanol-to-gasoline process. The corresponding unit prices for gasoline and LPG are $1.95/gallon ($0.52/liter) and $1.53/gallon ($0.40/liter) with yields of 55.1 and 9.3 gallons per U.S. ton of dry biomass (229.9 and 38.8 liters per metric tonne of dry biomass), respectively.

Phillips, S. D.; Tarud, J. K.; Biddy, M. J.; Dutta, A.

2011-01-01T23:59:59.000Z

144

The U.S. Department of Energy`s integrated gasification combined cycle research, development and demonstration program  

SciTech Connect

Historically, coal has played a major role as a fuel source for power generation both domestically and abroad. Despite increasingly stringent environmental constraints and affordable natural gas, coal will remain one of the primary fuels for producing electricity. This is due to its abundance throughout the world, low price, ease of transport an export, decreasing capital cost for coal-based systems, and the need to maintain fuel diversity. Recognizing the role coal will continue to play, the US Department of Energy (DOE) is working in partnership with industry to develop ways to use this abundant fuel resource in a manner that is more economical, more efficient and environmentally superior to conventional means to burn coal. The most promising of these technologies is integrated gasification combined cycle (IGCC) systems. Although IGCC systems offer many advantages, there are still several hurdles that must be overcome before the technology achieves widespread commercial acceptance. The major hurdles to commercialization include reducing capital and operating costs, reducing technical risk, demonstrating environmental and technical performance at commercial scale, and demonstrating system reliability and operability. Overcoming these hurdles, as well as continued progress in improving system efficiency, are the goals of the DOE IGCC research, development and demonstrate (RD and D) program. This paper provides an overview of this integrated RD and D program and describes fundamental areas of technology development, key research projects and their related demonstration scale activities.

Brdar, R.D.; Cicero, D.C.

1996-07-01T23:59:59.000Z

145

Light Water Reactor Sustainability Program - Integrated Program Plan |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Light Water Reactor Sustainability Program - Integrated Program Light Water Reactor Sustainability Program - Integrated Program Plan Light Water Reactor Sustainability Program - Integrated Program Plan The Light Water Reactor Sustainability (LWRS) Program is a research and development (R&D) program sponsored by the U. S. Department of Energy (DOE), performed in close collaboration and cooperation with related industry R&D programs. The LWRS Program provides technical foundations for licensing and managing the long-term, safe, and economical operation of current nuclear power plants, utilizing the unique capabilities of the national laboratory system. Sustainability is defined as the ability to maintain safe and economic operation of the existing fleet of nuclear power plants for a longer than-initially-licensed lifetime. It has two facets

146

Technical Support for the Development of the U.S. Department of Energy's Integrated Gasification Combined Cycle Dynamic Training Sim ulator  

Science Conference Proceedings (OSTI)

Integrated-gasification-combined-cycle (IGCC) is one technology option from the next generation of coal-fired power plants with high efficiency and near-zero emissions that has been evaluated by major utilities and developers for baseload capacity additions. The increased attention to IGCC power generation has created a growing demand for experience with the analysis, operation, and control of commercial-scale IGCC plants. To meet this need, DOE’s National Energy Technology Laboratory (NETL) has led a pr...

2011-06-28T23:59:59.000Z

147

Advanced reactor development: The LMR integral fast reactor program at Argonne  

SciTech Connect

Reactor technology for the 21st Century must develop with characteristics that can now be seen to be important for the future, quite different from the things when the fundamental materials and design choices for present reactors were made in the 1950s. Argonne National Laboratory, since 1984, has been developing the Integral Fast Reactor (IFR). This paper will describe the way in which this new reactor concept came about; the technical, public acceptance, and environmental issues that are addressed by the IFR; the technical progress that has been made; and our expectations for this program in the near term. 3 figs.

Till, C.E.

1990-01-01T23:59:59.000Z

148

Gasification Plant Databases  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Gasification Plant Databases Welcome to the U. S. Department of Energy, National Energy Technology Laboratory's Gasification Plant Databases Within these...

149

Rapid gasification of nascent char in steam atmosphere during the pyrolysis of Na- and Ca-ion-exchanged brown coals in a drop-tube reactor  

Science Conference Proceedings (OSTI)

Several recent studies on in situ steam gasification of coal suggest a possibility of extremely fast steam gasification of char from rapid pyrolysis of pulverized brown coal. The unprecedented rate of char steam gasification can be achieved by exposing nascent char, that is, after tar evolution (temperature range >600{sup o}C), but before devolatilization (coal samples, that is, H-form coal with Na/Ca contents coal with Na content = 2.8 wt % and Ca-form coal with Ca content = 3.2 wt %. These samples were pyrolyzed in an atmospheric drop-tube reactor at a temperature of 900{sup o}C, inlet steam concentration of 50 vol. %, and a particle residence times of 2.8 s. The char yields from the pyrolysis of Na-form and Ca-form coals were as low as 12 and 33% on the respective coal carbon bases, and accounted for only 18 and 53% of the char yields from the full devolatilization of the respective coals at 900{sup o}C. In addition, the pyrolysis also consumed as much as 0.7-1.1 mol of H{sub 2}O per mol of coal C. On the other hand, the nascent char from the H-form coal allowed carbon deposition from the nascent tar, resulting in a char yield as high as 115% of that from the full devolatilization. The chars from the Na-form and Ca-form coals also acted as catalysts for steam reforming of tar, which was evidenced by significant negative synergistic effects of blending of H-form coal with Na-form coal or Ca-form coal on the tar and soot yields. 57 refs., 6 figs.

Ondej Maek; Sou Hosokai; Koyo Norinaga; Chun-Zhu Li; Jun-ichiro Hayashi [Hokkaido University, Kita-ku (Japan). Center for Advanced Research of Energy Conversion Materials

2009-09-15T23:59:59.000Z

150

Uncertainty analysis of integrated gasification combined cycle systems based on Frame 7H versus 7F gas turbines  

SciTech Connect

Integrated gasification combined cycle (IGCC) technology is a promising alternative for clean generation of power and coproduction of chemicals from coal and other feedstocks. Advanced concepts for IGCC systems that incorporate state-of-the-art gas turbine systems, however, are not commercially demonstrated. Therefore, there is uncertainty regarding the future commercial-scale performance, emissions, and cost of such technologies. The Frame 7F gas turbine represents current state-of-practice, whereas the Frame 7H is the most recently introduced advanced commercial gas turbine. The objective of this study was to evaluate the risks and potential payoffs of IGCC technology based on different gas turbine combined cycle designs. Models of entrained-flow gasifier-based IGCC systems with Frame 7F (IGCC-7F) and 7H gas turbine combined cycles (IGCC-7H) were developed in ASPEN Plus. An uncertainty analysis was conducted. Gasifier carbon conversion and project cost uncertainty are identified as the most important uncertain inputs with respect to system performance and cost. The uncertainties in the difference of the efficiencies and costs for the two systems are characterized. Despite uncertainty, the IGCC-7H system is robustly preferred to the IGCC-7F system. Advances in gas turbine design will improve the performance, emissions, and cost of IGCC systems. The implications of this study for decision-making regarding technology selection, research planning, and plant operation are discussed. 38 refs., 11 figs., 5 tabs.

Yunhua Zhu; H. Christopher Frey [Pacific Northwest National Laboratory, Richland, WA (United States)

2006-12-15T23:59:59.000Z

151

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project Draft Environmental Impact Statement  

DOE Green Energy (OSTI)

The Kentucky Pioneer IGCC Demonstration Project DEIS assesses the potential environmental impacts that would result from a proposed DOE action to provide cost-shared financial support for construction and operation of an electrical power station demonstrating use of a Clean Coal Technology in Clark County, Kentucky. Under the Proposed Action, DOE would provide financial assistance, through a Cooperative Agreement with Kentucky Pioneer Energy, LLC, for design, construction, and operation of a 540 megawatt demonstration power station comprised of two synthesis gas-fired combined cycle units in Clark County, Kentucky. The station would also be comprised of a British Gas Lurgi (BGL) gasifier to produce synthesis gas from a co-feed of coal and refuse-derived fuel pellets and a high temperature molten carbonate fuel cell. The facility would be powered by the synthesis gas feed. The proposed project would consist of the following major components: (1) refuse-derived fuel pellets and coal receipt and storage facilities; (2) a gasification plant; (3) sulfur removal and recovery facilities; (4) an air separation plant; (5) a high-temperature molten carbonate fuel cell; and (6) two combined cycle generation units. The IGCC facility would be built to provide needed power capacity to central and eastern Kentucky. At a minimum, 50 percent of the high sulfur coal used would be from the Kentucky region. Two No Action Alternatives are analyzed in the DEIS. Under the No Action Alternative 1, DOE would not provide cost-shared funding for construction and operation of the proposed facility and no new facility would be built. Under the No Action Alternative 2, DOE would not provide any funding and, instead of the proposed demonstration project, Kentucky Pioneer Energy, LLC, a subsidiary of Global Energy, Inc., would construct and operate, a 540 megawatt natural gas-fired power station. Evaluation of impacts on land use, socioeconomics, cultural resources, aesthetic and scenic resources, geology, air resources, water resources, ecological resources, noise, traffic and transportation, occupational and public health and safety, and environmental justice were included in the assessment.

N /A

2001-11-16T23:59:59.000Z

152

Integral Fast Reactor: A future source of nuclear energy  

SciTech Connect

Argonne National Laboratory is developing a reactor concept that would be an important part of the worlds energy future. This report discusses the Integral Fast Reactor (IFR) concept which provides significant improvements over current generation reactors in reactor safety, plant complexity, nuclear proliferation, and waste generation. Two major facilities, a reactor and a fuel cycle facility, make up the IFR concept. The reactor uses fast neutrons and metal fuel in a sodium coolant at atmospheric pressure that relies on laws of physics to keep it safe. The fuel cycle facility is a hot cell using remote handling techniques for fabricating reactor fuel. The fuel feed stock includes spent fuel from the reactor, and potentially, spent light water reactor fuel and plutonium from weapons. This paper discusses the unique features of the IFR concept and the differences the quality assurance program has from current commercial practices. The IFR concept provides an opportunity to design a quality assurance program that makes use of the best contemporary ideas on management and quality.

Southon, R.

1993-09-01T23:59:59.000Z

153

A DESCRIPTION OF INTEGRAL PHYSICS DATA FOR FAST REACTOR DESIGN  

SciTech Connect

Integral physics data for fast reactor design are discussed. The measurements needed include those of critical mass, shape factor, detector ratios, neutron spectra, material replacement experiments, reflector savings, neutron lifetime, Rossi- alpha , and similar quantities. Topics covered include Pu- and U/sup 233/-fueled systems, highly enriched U/sup 235/ systems in optimum geometry, uranium cores of various enrichments and dilutions, extreme geometry critical experiments, specific reactor systems, core mockup inhomogeneities, spectral studies and detector ratios, uranium equilibrium spectrum data, materialreplacement measurements, fast reactor dynamics, and suggested future experiments and experimental programs. (M.C.G.)

Loewenstein, W.B.; Meneghetti, D.

1961-07-01T23:59:59.000Z

154

The Integral Fast Reactor: A practical approach to waste management  

SciTech Connect

This report discusses development of the method for pyroprocessing of spent fuel from the Integral Fast Reactor (or Advanced Liquid Metal Reactor). The technology demonstration phase, in which recycle will be demonstrated with irradiated fuel from the EBR-II reactor has been reached. Methods for recovering actinides from spent LWR fuel are at an earlier stage of development but appear to be technically feasible at this time, and a large-scale demonstration of this process has begun. The utilization of fully compatible processes for recycling valuable spent fuel materials promises to provide substantial economic incentives for future applications of the pyroprocessing technology.

Laidler, J.J.

1993-12-31T23:59:59.000Z

155

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifier: Commercial Gasifiers Gasifier: Commercial Gasifiers Gasifiers and Impact of Coal Rank and Coal Properties The available commercial gasification technologies are often optimized for a particular rank of coal or coal properties, and in some cases, certain ranks of coal might be unsuitable for utilization in a given gasification technology. On the other hand, there is considerable flexibility in most of the common gasifiers; this is highlighted by the following table, which provides an overview of the level of experience for the various commercially available gasifiers by manufacturer for each coal type. This experience will only continue to expand as more gasification facilities come online and more demonstrations are completed. SOLID FUEL GASIFICATION EXPERIENCE1 High Ash Coals

156

Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

GASIFICATION SYSTEMS U.S. DEPARTMENT OF ENERGY TECHNOLOGY PROGRAM PLAN PREFACE ii DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United...

157

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Technology Options CO2 Capture Technology Options All gasification-based conversion processes require removal of hydrogen sulfide (H2S; an acid gas) from the synthesis gas (syngas)...

158

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Water Gas Shift & Hydrogen Production Slag High-temperatureWarm Sygas Cleanup & DOE R&D Other DOE R&D Supporting Syngas Cleanup Technology Emissions Advantages of Gasification...

159

Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems  

Science Conference Proceedings (OSTI)

This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energyâ??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process â?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

Howard Meyer

2010-11-30T23:59:59.000Z

160

Analysis of Carbon Dioxide Capture Retrofit Options: Duke Edwardsport Integrated-Gasification Combined-Cycle Plant  

Science Conference Proceedings (OSTI)

This report summarizes the results of a project supported by Duke Energy using tailored collaboration funds to study the potential impact to plant performance of retrofitted carbon dioxide (CO2) capture on the Duke Edwardsport integrated-gasificationcombined-cycle (IGCC) plant. The Duke Edwardsport IGCC plant is under construction and scheduled to begin operation in September 2012. Details on the project have been published in a 2010 Electric Power Research Institute (EPRI) report, Duke Edwardsport Gener...

2011-09-27T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Program on Technology Innovation: Development of an Integrated Gasification Combined Cycle Performance and Cost Modeling Tool  

Science Conference Proceedings (OSTI)

This report describes the development of an integrated performance and cost model for advanced coal power plant undertaken to enable users to screen technologies prior to engaging in more extensive studies of their preferred choice. Such screening activities generally require utilities to contract with outside engineering firms with access to sophisticated engineering modeling software and experienced staff to perform the studies, thus costing significant time and investment.

2010-12-31T23:59:59.000Z

162

Integrated gasification combined cycle and steam injection gas turbine powered by biomass joint-venture evaluation  

DOE Green Energy (OSTI)

This report analyzes the economic and environmental potential of biomass integrated gasifier/gas turbine technology including its market applications. The mature technology promises to produce electricity at $55--60/MWh and to be competitive for market applications conservatively estimated at 2000 MW. The report reviews the competitiveness of the technology of a stand-alone, mature basis and finds it to be substantial and recognized by DOE, EPRI, and the World Bank Global Environmental Facility.

Sterzinger, G J [Economics, Environment and Regulation, Washington, DC (United States)

1994-05-01T23:59:59.000Z

163

Integrated systems analysis of the PIUS reactor  

SciTech Connect

Results are presented of a systems failure analysis of the PIUS plant systems that are used during normal reactor operation and postulated accidents. This study was performed to provide the NRC with an understanding of the behavior of the plant. The study applied two diverse failure identification methods, Failure Modes Effects & Criticality Analysis (FMECA) and Hazards & Operability (HAZOP) to the plant systems, supported by several deterministic analyses. Conventional PRA methods were also used along with a scheme for classifying events by initiator frequency and combinations of failures. Principal results of this study are: (a) an extensive listing of potential event sequences, grouped in categories that can be used by the NRC, (b) identification of support systems that are important to safety, and (c) identification of key operator actions.

Fullwood, F.; Kroeger, P.; Higgins, J. [Brookhaven National Lab., Upton, NY (United States)] [and others

1993-11-01T23:59:59.000Z

164

Foundational development of an advanced nuclear reactor integrated safety code.  

SciTech Connect

This report describes the activities and results of a Sandia LDRD project whose objective was to develop and demonstrate foundational aspects of a next-generation nuclear reactor safety code that leverages advanced computational technology. The project scope was directed towards the systems-level modeling and simulation of an advanced, sodium cooled fast reactor, but the approach developed has a more general applicability. The major accomplishments of the LDRD are centered around the following two activities. (1) The development and testing of LIME, a Lightweight Integrating Multi-physics Environment for coupling codes that is designed to enable both 'legacy' and 'new' physics codes to be combined and strongly coupled using advanced nonlinear solution methods. (2) The development and initial demonstration of BRISC, a prototype next-generation nuclear reactor integrated safety code. BRISC leverages LIME to tightly couple the physics models in several different codes (written in a variety of languages) into one integrated package for simulating accident scenarios in a liquid sodium cooled 'burner' nuclear reactor. Other activities and accomplishments of the LDRD include (a) further development, application and demonstration of the 'non-linear elimination' strategy to enable physics codes that do not provide residuals to be incorporated into LIME, (b) significant extensions of the RIO CFD code capabilities, (c) complex 3D solid modeling and meshing of major fast reactor components and regions, and (d) an approach for multi-physics coupling across non-conformal mesh interfaces.

Clarno, Kevin (Oak Ridge National Laboratory, Oak Ridge, TN); Lorber, Alfred Abraham; Pryor, Richard J.; Spotz, William F.; Schmidt, Rodney Cannon; Belcourt, Kenneth (Ktech Corporation, Albuquerque, NM); Hooper, Russell Warren; Humphries, Larry LaRon

2010-02-01T23:59:59.000Z

165

Preparations for the Integral Fast Reactor fuel cycle demonstration  

Science Conference Proceedings (OSTI)

Modifications to the Hot Fuel Examination Facility-South (HFEF/S) have been in progress since mid-1988 to ready the facility for demonstration of the unique Integral Fast Reactor (IFR) pyroprocess fuel cycle. This paper updates the last report on this subject to the American Nuclear Society and describes the progress made in the modifications to the facility and in fabrication of the new process equipment. The IFR is a breeder reactor, which is central to the capability of any reactor concept to contribute to mitigation of environmental impacts of fossil fuel combustion. As a fast breeder, fuel of course must be recycled in order to have any chance of an economical fuel cycle. The pyroprocess fuel cycle, relying on a metal alloy reactor fuel rather than oxide, has the potential to be economical even at small-scale deployment. Establishing this quantitatively is one important goal of the IFR fuel cycle demonstration.

Lineberry, M.J.; Phipps, R.D.

1989-01-01T23:59:59.000Z

166

Recovery, transport, and disposal of CO{sub 2} from an integrated gasification combined-cycle power plant  

SciTech Connect

Initiatives to limit CO{sub 2} emissions have drawn considerable interest to integrated gasification combined-cycle (IGCC) power generation, a process that reduces CO{sub 2} production and is amenable to CO{sub 2} capture. This paper presents a comparison of energy systems that encompass fuel supply, an IGCC system, CO{sub 2} recovery using commercial technologies, CO{sub 2} transport by pipeline, and land-based sequestering in geological reservoirs. The intent is to evaluate the energy efficiency impacts of controlling CO{sub 2} in such a system, and to provide the CO{sub 2} budget, or an equivalent CO{sub 2} budget, associated with each of the individual energy-cycle steps. The value used for the equivalent CO{sub 2} budget is 1 kg CO{sub 2}/kWh. The base case for the comparison is a 458-MW IGCC system using an air-blown Kellogg Rust Westinghouse (KRW) agglomerating fluidized-bed gasifier, Illinois No.6 bituminous coal, and in-bed sulfur removal. Mining, transportation, and preparation of the coal and limestone result in a net electric power production of 448 MW with a 0.872 kg/kWh CO{sub 2} release rate. For comparison, the gasifier output was taken through a water-gas shift to convert CO to CO{sub 2}, and processed in a Selexol unit to recover CO{sub 2} prior to the combustion turbine. A 500-km pipeline then took the CO{sub 2} to geological sequestering. The net electric power production was 383 MW with a 0.218 kg/kWh CO{sub 2} release rate.

Livengood, C.D.; Doctor, R.D.; Molburg, J.C.; Thimmapuram, P.; Berry, G.F.

1993-12-31T23:59:59.000Z

167

Integral Fast Reactor Program. Annual progress report, FY 1993  

Science Conference Proceedings (OSTI)

This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1993. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R and D.

Chang, Y.I.; Walters, L.C.; Laidler, J.J.; Pedersen, D.R.; Wade, D.C.; Lineberry, M.J.

1994-10-01T23:59:59.000Z

168

Integral Fast Reactor Program annual progress report, FY 1994  

Science Conference Proceedings (OSTI)

This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1994. Technical accomplishments are presented in the following areas of the IFR technology development activities: metal fuel performance; pyroprocess development; safety experiments and analyses; core design development; fuel cycle demonstration; and LMR technology R&D.

Chang, Y.I.; Walters, L.C.; Laidler, J.J.; Pedersen, D.R.; Wade, D.C.; Lineberry, J.J.

1994-12-01T23:59:59.000Z

169

Integrated autothermal reactor concepts for oxidative coupling and reforming of  

E-Print Network (OSTI)

. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.3 Oxidative coupling and steam reforming of methane . . . . . . . . . . 5 1.4 This thesis of methane . . . . . . . . . . . . . . . . . . . 23 2.4 Only steam reforming of methane#12;Integrated autothermal reactor concepts for oxidative coupling and reforming of methane #12

Twente, Universiteit

170

Integral Fast Reactor Program. Annual progress report, FY 1992  

Science Conference Proceedings (OSTI)

This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1992. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R&D.

Chang, Y.I.; Walters, L.C.; Laidler, J.J.; Pedersen, D.R.; Wade, D.C.; Lineberry, M.J.

1993-06-01T23:59:59.000Z

171

Nuon Magnum Integrated-Gasification -Combined-Cycle (IGCC) Project Preliminary Design Specification  

Science Conference Proceedings (OSTI)

This is the second pre-design specification (PDS) in a projected series for integrated-gasificationcombined-cycle (IGCC) plants, sponsored by EPRIs CoalFleet for Tomorrow program and involving more than 50 power industry companies. A PDS represents the level of nonproprietary information available at the feasibility study stage in the development of an IGCC project. This PDS is based on the design of the 1200-MWe Magnum IGCC plant, which Nuon Power Generation B.V. has proposed to build on the northern co...

2008-03-31T23:59:59.000Z

172

The O{sub 2}-enriched air gasification of coal, plastics and wood in a fluidized bed reactor  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer The effect of the O{sub 2} in the gasification stream of a BFB gasifier has been studied. Black-Right-Pointing-Pointer Main advantage of the O{sub 2}-enriched air is the increasing of the bed temperature. Black-Right-Pointing-Pointer No remarkable effects on tar reduction. Decreasing of recognized PAHs. Black-Right-Pointing-Pointer Gasification reactions completed inside the dense bed and splashing zone. Black-Right-Pointing-Pointer Polycondensation reactions occur mainly in the freeboard region. - Abstract: The effect of oxygen-enriched air during fluidized bed co-gasification of a mixture of coal, plastics and wood has been investigated. The main components of the obtained syngas were measured by means of on-line analyzers and a gas chromatograph while those of the condensate phase were off-line analysed by means of a gas chromatography-mass spectrometer (GC-MS). The characterization of condensate phase as well as that of the water used as scrubbing medium completed the performed diagnostics. The experimental results were further elaborated in order to provide material and substances flow analyses inside the plant boundaries. These analyses allowed to obtain the main substance distribution between solid, gaseous and condensate phases and to estimate the conversion efficiency of carbon and hydrogen but also to easily visualise the waste streams produced by the process. The process performance was then evaluated on the basis of parameters related to the conversion efficiency of fuels into valuable products (i.e. by considering tar and particulate as process losses) as well as those related to the energy recovery.

Mastellone, Maria Laura, E-mail: mlaura.mastellone@unina2.it [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy); Zaccariello, Lucio; Santoro, Donato; Arena, Umberto [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy)

2012-04-15T23:59:59.000Z

173

Coal Gasification for Power Generation, 3. edition  

SciTech Connect

The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

2007-11-15T23:59:59.000Z

174

ENHANCED HYDROGEN PRODUCTION INTEGRATED WITH CO2 SEPARATION IN A SINGLE-STAGE REACTOR  

DOE Green Energy (OSTI)

The water gas shift reaction (WGSR) plays a major role in increasing the hydrogen production from fossil fuels. However, the enhanced hydrogen production is limited by thermodynamic constrains posed by equilibrium limitations of WGSR. This project aims at using a mesoporous, tailored, highly reactive calcium based sorbent system for incessantly removing the CO{sub 2} product which drives the equilibrium limited WGSR forward. In addition, a pure sequestration ready CO{sub 2} stream is produced simultaneously. A detailed project vision with the description of integration of this concept with an existing coal gasification process for hydrogen production is presented. Conceptual reactor designs for investigating the simultaneous water gas shift and the CaO carbonation reactions are presented. In addition, the options for conducting in-situ sorbent regeneration under vacuum or steam are also reported. Preliminary, water gas shift reactions using high temperature shift catalyst and without any sorbent confirmed the equilibrium limitation beyond 600 C demonstrating a carbon monoxide conversion of about 80%. From detailed thermodynamic analyses performed for fuel gas streams from typical gasifiers the optimal operating temperature range to prevent CaO hydration and to effect its carbonation is between 575-830 C.

Himanshu Gupta; Mahesh Iyer; Bartev Sakadjian; Liang-Shih Fan

2005-03-10T23:59:59.000Z

175

NETL: Coal/Biomass Feed and Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed & Gasification Coal/Biomass Feed & Gasification Coal and Coal/Biomass to Liquids Coal/Biomass Feed and Gasification The Coal/Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal and/or coal-biomass mixtures. Activities support research for handling and processing of coal/biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on downstream components, catalyst and reactor optimization, and characterizing the range of products and product quality. Active projects within the program portfolio include the following: Coal-biomass fuel preparation Development of Biomass-Infused Coal Briquettes for Co-Gasification Coal-biomass gasification modeling

176

NETL: Gasification Systems Video, Images & Photos  

NLE Websites -- All DOE Office Websites (Extended Search)

Video, Images, Photos Video, Images, Photos Gasification Systems Reference Shelf - Video, Images & Photos The following was established to show a variety of Gasification Technologies: Gasfication powerplant photo Gasification: A Cornerstone Technology (Mar 2008) Movie Icon Windows Media Video (WMV-26MB) [ view | download ] NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants. Proposed APS Advanced Hydrogasification Process Proposed APS Advanced Hydrogasification Process* TRDU and Hot-Gas Vessel in the EERC Gasification Tower Transport reactor development unit

177

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal: Alternatives/Supplements to Coal - Feedstock Flexibility Coal: Alternatives/Supplements to Coal - Feedstock Flexibility As important as coal is as a primary gasification feedstock, gasification technology offers the important ability to take a wide range of feedstocks and process them into syngas, from which a similarly diverse number of end products are possible. Gasifiers have been developed to suit all different ranks of coal, and other fossil fuels, petcoke and refinery streams, biomass including agricultural waste, and industrial and municipal waste. The flexibility stems from the ability of gasification to take any carbon and hydrogen containing feedstock and then thermochemically break down the feedstock to a gas containing simple compounds which are easy to process into several marketable products.

178

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia Coal: Feedstock Flexibility Refinery Streams Gasification is a known method for converting petroleum coke (petcoke) and other refinery waste streams and residuals (vacuum residual, visbreaker tar, and deasphalter pitch) into power, steam and hydrogen for use in the production of cleaner transportation fuels. The main requirement for a gasification feedstock is that it contains both hydrogen and carbon. Below is a table that shows the specifications for a typical refinery feedstock. Specifications for a typical refinery feedstock A number of factors have increased the interest in gasification applications in petroleum refinery operations: Coking capacity has increased with the shift to heavier, more sour crude oils being supplied to the refiners.

179

Gasification Technology Status - December 2010  

Science Conference Proceedings (OSTI)

Several Integrated Gasification Combined Cycle (IGCC) projects that incorporate various degrees of CO2 Capture and Sequestration (CCS) are under development worldwide. This report covers current IGCC designs on offer that include CO2 capture and reviews the commercial status of gasification technologies, potential improvements, and lessons learned from commercial operating experience at IGCC plants. It describes and evaluates the considerable R&D program of the U.S. DOE and industrial companies to improv...

2010-12-31T23:59:59.000Z

180

Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification  

E-Print Network (OSTI)

Gasification is a thermo-chemical process which transforms biomass into valuable synthesis gas. Integrated with a biorefinery it can address the facility’s residue handling challenges and input demands. A number of feedstock, technology, oxidizer and product options are available for gasification along with combinations thereof. The objective of this work is to create a systematic method for optimizing the design of a residual biomass gasification unit. In detail, this work involves development of an optimization superstructure, creation of a biorefining scenario, process simulation, equipment sizing & costing, economic evaluation and optimization. The superstructure accommodates different feedstocks, reactor technologies, syngas cleaning options and final processing options. The criterion for optimization is annual worth. A biorefining scenario for the production of renewable diesel fuel from seed oil is developed; gasification receives the residues from this biorefinery. Availability of Soybeans, Jatropha, Chinese Tallow and woody biomass material is set by land use within a 50-mile radius. Four reactor technologies are considered, based on oxidizer type and operating pressure, along with three syngas cleaning methods and five processing options. Results show that residual gasification is profitable for large-scale biorefineries with the proper configuration. Low-pressure air gasification with filters, water-gas shift and hydrogen separation is the most advantageous combination of technology and product with an annual worth of $9.1 MM and a return on investment of 10.7 percent. Low-pressure air gasification with filters and methanol synthesis is the second most advantageous combination with an annual worth of $9.0 MM. Gasification is more economic for residue processing than combustion or disposal, and it competes well with natural gas-based methanol synthesis. However, it is less economic than steam-methane reforming of natural gas to hydrogen. Carbon dioxide credits contribute to profitability, affecting some configurations more than others. A carbon dioxide credit of $33/t makes the process competitive with conventional oil and gas development. Sensitivity analysis demonstrates a 10 percent change in hydrogen or electricity price results in a change to the optimal configuration of the unit. Accurate assessment of future commodity prices is critical to maximizing profitability.

Georgeson, Adam

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Reactor Vessel Embrittlement Management Handbook: A Handbook for Managing Reactor Vessel Embrittlement and Vessel Integrity  

Science Conference Proceedings (OSTI)

For many reactor pressure vessels, embrittlement is the primary concern for continued safe operation. The shutdown of the Yankee Rowe plant because of uncertainties related to embrittlement of the vessel demonstrates the importance of adequately addressing embrittlement issues. Managing embrittlement requires integration, management, and implementation of diverse technical, regulatory, planning, and economic activities. An effective embrittlement management program will ensure vessel safety and reliabili...

1994-01-22T23:59:59.000Z

182

GASIFICATION FOR DISTRIBUTED GENERATION  

DOE Green Energy (OSTI)

A recent emphasis in gasification technology development has been directed toward reduced-scale gasifier systems for distributed generation at remote sites. The domestic distributed power generation market over the next decade is expected to be 5-6 gigawatts per year. The global increase is expected at 20 gigawatts over the next decade. The economics of gasification for distributed power generation are significantly improved when fuel transport is minimized. Until recently, gasification technology has been synonymous with coal conversion. Presently, however, interest centers on providing clean-burning fuel to remote sites that are not necessarily near coal supplies but have sufficient alternative carbonaceous material to feed a small gasifier. Gasifiers up to 50 MW are of current interest, with emphasis on those of 5-MW generating capacity. Internal combustion engines offer a more robust system for utilizing the fuel gas, while fuel cells and microturbines offer higher electric conversion efficiencies. The initial focus of this multiyear effort was on internal combustion engines and microturbines as more realistic near-term options for distributed generation. In this project, we studied emerging gasification technologies that can provide gas from regionally available feedstock as fuel to power generators under 30 MW in a distributed generation setting. Larger-scale gasification, primarily coal-fed, has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries. Commercial-scale gasification activities are under way at 113 sites in 22 countries in North and South America, Europe, Asia, Africa, and Australia, according to the Gasification Technologies Council. Gasification studies were carried out on alfalfa, black liquor (a high-sodium waste from the pulp industry), cow manure, and willow on the laboratory scale and on alfalfa, black liquor, and willow on the bench scale. Initial parametric tests evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

2000-05-01T23:59:59.000Z

183

Interim waste storage for the Integral Fast Reactor  

SciTech Connect

The Integral Fast Reactor (IFR), which Argonne National Laboratory is developing, is an innovative liquid metal breeder reactor that uses metallic fuel and has a close coupled fuel recovery process. A pyrochemical process is used to separate the fission products from the actinide elements. These actinides are used to make new fuel for the reactor. As part of the overall IFR development program, Argonne has refurbished an existing Fuel Cycle Facility at ANL-West and is installing new equipment to demonstrate the remote reprocessing and fabrication of fuel for the Experimental Breeder Reactor II (EBR-II). During this demonstration the wastes that are produced will be treated and packaged to produce waste forms that would be typical of future commercial operations. These future waste forms would, assuming Argonne development goals are fulfilled, be essentially free of long half-life transuranic isotopes. Promising early results indicate that actinide extraction processes can be developed to strip these isotopes from waste stream and return them to the IFR type reactors for fissioning. 1 fig.

Benedict, R.W.; Phipps, R.D. (Argonne National Lab., Idaho Falls, ID (USA)); Condiff, D.W. (Argonne National Lab., IL (USA))

1991-01-01T23:59:59.000Z

184

AVESTAR® - Training - Gasification Process Operations  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Process Operations Gasification Process Operations This course is designed as a familiarization course to increase understanding of the gasification with CO2 capture process. During the training, participants will startup and shutdown the simulated unit in an integrated manner and will be exposed to simple and complex unit malfunctions in the control room and in the field. Course objectives are as follows: Introduce trainees to gasification and CO2 capture process systems and major components and how they dynamically interact Familiarize trainees with the Human Machine Interface (HMI) and plant control and how safe and efficient operation of the unit can be affected by plant problems Provide the trainees with hands-on operating experiences in plant operations using the HMI

185

Integrated Gasification Combined Cycle  

E-Print Network (OSTI)

This presentation was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed therein do not necessarily state or reflect those of the United States Government or any agency thereof.

Pulverized Coal

2007-01-01T23:59:59.000Z

186

EBR-2 (Experimental Breeder Reactor-2), IFR (Integral Fast Reactor) prototype testing programs  

SciTech Connect

The Experimental Breeder Reactor-2 (EBR-2) is a sodium cooled power reactor supplying about 20 MWe to the Idaho National Engineering Laboratory (INEL) grid and, in addition, is the key component in the development of the Integral Fast Reactor (IFR). EBR-2's testing capability is extensive and has seen four major phases: (1) demonstration of LMFBR power plant feasibility, (2) irradiation testing for fuel and material development. (3) testing the off-normal performance of fuel and plant systems and (4) operation as the IFR prototype, developing and demonstrating the IFR technology associated with fuel and plant design. Specific programs being carried out in support of the IFR include advanced fuels and materials development and component testing. This paper discusses EBR-2 as the IFR prototype and the associated testing programs. 29 refs.

Lehto, W.K.; Sackett, J.I.; Lindsay, R.W. (Argonne National Lab., Idaho Falls, ID (USA). EBR-II Div. Argonne National Lab., IL (USA)); Planchon, H.P.; Lambert, J.D.B. (Argonne National Lab., IL (USA))

1990-01-01T23:59:59.000Z

187

Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

GASIFICATION SYSTEMS GASIFICATION SYSTEMS U.S. DEPARTMENT OF ENERGY TECHNOLOGY PROGRAM PLAN PREFACE ii DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any

188

Light Water Reactor Sustainability Program: Integrated Program Plan |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Integrated Program Plan Integrated Program Plan Light Water Reactor Sustainability Program: Integrated Program Plan Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas- emitting electric power generation in the United States. Domestic demand for electrical energy is expected to grow by more than 30% from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license, for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power

189

Behavior of actinides in the Integral Fast Reactor fuel cycle  

SciTech Connect

The Integral Fast Reactor (IFR) under development by Argonne National Laboratory uses metallic fuels instead of ceramics. This allows electrorefining of spent fuels and presents opportunities for recycling minor actinide elements. Four minor actinides ({sup 237}Np, {sup 240}Pu, {sup 241}Am, and {sup 243}Am) determine the waste storage requirements of spent fuel from all types of fission reactors. These nuclides behave the same as uranium and other plutonium isotopes in electrorefining, so they can be recycled back to the reactor without elaborate chemical processing. An experiment has been designed to demonstrate the effectiveness of the high-energy neutron spectra of the IFR in consuming these four nuclides and plutonium. Eighteen sets of seven actinide and five light metal targets have been selected for ten day exposure in the Experimental Breeder Reactor-2 which serves as a prototype of the IFR. Post-irradiation analyses of the exposed targets by gamma, alpha, and mass spectroscopy are used to determine nuclear reaction-rates and neutron spectra. These experimental data increase the authors` confidence in their ability to predict reaction rates in candidate IFR designs using a variety of neutron transport and diffusion programs.

Courtney, J.C. [Louisiana State Univ., Baton Rouge, LA (United States). Nuclear Science Center; Lineberry, M.J. [Argonne National Lab., Idaho Falls, ID (United States). Technology Development Div.

1994-06-01T23:59:59.000Z

190

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Conditioning Conditioning Sulfur Recovery and Tail Gas Treating Sulfur is a component of coal and other gasification feed stocks. Sulfur compounds need to be removed in most gasification applications due to environmental regulations or to avoid catalyst poisoning. Whether it is electricity, liquid fuels, or some other product being output, sulfur emissions are regulated, and sulfur removal is important for this reason, along with the prevention of downstream component fouling. In addition to these constraints, recovering saleable sulfur is an important economic benefit for a gasification plant. To illustrate the previous point, in 2011 8.1 million tons of elemental sulfur was produced, with the majority of this coming from petroleum refining, natural gas processing and coking plants. Total shipments were valued at $1.6 billion, with the average mine or plant price of $200 per ton, up from $70.48 in 2010. The United States currently imports sulfur (36% of consumption, mostly from Canada), meaning the market can support more domestic sulfur production.

191

NETL: Gasification Project Information  

NLE Websites -- All DOE Office Websites (Extended Search)

Project Information Project Information Gasification Systems Reference Shelf - Project Information Active Projects | Archived Projects | All NETL Fact Sheets Feed Systems A Cost-Effective Oxygen Separation System Based on Open Gradient Magnetic Field by Polymer Beads [SC0010151] Development of ITM Oxygen Technology for Low-cost and Low-emission Gasification and Other Industrial Applications [FE0012065] Dry Solids Pump Coal Feed Technology [FE0012062] Coal-CO2 Slurry Feeding System for Pressurized Gasifiers [FE0012500] National Carbon Capture Center at the Power Systems Development Facility [FE0000749] Modification of the Developmental Pressure Decoupled Advanced Coal (PDAC) Feeder [NT0000749] Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems [DE-FC26-98FT40343]

192

Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes  

DOE Green Energy (OSTI)

This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540°C and the helium coolant was delivered at 7 MPa at 625–925°C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

Lee O. Nelson

2011-04-01T23:59:59.000Z

193

NETL: Gasification - Systems Analyses  

NLE Websites -- All DOE Office Websites (Extended Search)

System Analyses Gasification Systems Systems Analyses Go to the NETL Gasification Systems Program's Systems and Industry Analyses Studies Technology & CostPerformance Studies NETL...

194

NETL: Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Coal and Power Systems Gasification Systems Gasifier Optimization & Plant Supporting Systems Feed Systems Feed Systems Gasifier Optimization & Plant Supporting...

195

AVESTAR® - Gasification Dynamic Simulator  

NLE Websites -- All DOE Office Websites (Extended Search)

Meet Our Partners Simulators IGCC Gasification Combined Cycle NGCC SCOT Oxy-coal Shale Gas 3D Virtual IGCC Training How to Register for Training IGCC Gasification Combined...

196

Gasification Users Association (GUA) Update Newsletter: March 2012  

Science Conference Proceedings (OSTI)

The Gasification Users Group (GUA) Update is published quarterly and provides information on gasification projects in development and in construction, along with a summary of new integrated gasification combined cycle (IGCC)/ gasification technology developments. The following articles are featured in this issue of the GUA Update: Quarterly Summary Ongoing U.S. Energy Program Updates European Union Plans Support of Multiple CCS Projects News Items on Operating IGCC Plants U.S. IGCC Project Updates Inte...

2012-03-31T23:59:59.000Z

197

An evaluation of integrated-gasification-combined-cycle and pulverized-coal-fired steam plants: Volume 1, Base case studies: Final report  

SciTech Connect

An evaluation of the performance and costs for a Texaco-based integrated gasification combined cycle (IGCC) power plant as compared to a conventional pulverized coal-fired steam (PCFS) power plant with flue gas desulfurization (FGD) is provided. A general set of groundrules was used within which each plant design was optimized. The study incorporated numerous sensitivity cases along with up-to-date operating and cost data obtained through participation of equipment vendors and process developers. Consequently, the IGCC designs presented in this study use the most recent data available from Texaco's ongoing international coal gasification development program and General Electric's continuing gas turbine development efforts. The Texaco-based IGCC has advantages over the conventional PCFS technology with regard to environmental emissions and natural resource requirements. SO/sub 2/, NOx, and particulate emissions are lower. Land area and water requirements are less for IGCC concepts. Coal consumption is less due to the higher plant thermal efficiency attainable in the IGCC plant. The IGCC plant also has the capability to be designed in several different configurations, with and without the use of natural gas or oil as a backup fuel. This capability may prove to be particularly advantageous in certain utility planning and operation scenarios. 107 figs., 114 tabs.

Pietruszkiewicz, J.; Milkavich, R.J.; Booras, G.S.; Thomas, G.O.; Doss, H.

1988-09-01T23:59:59.000Z

198

An evaluaton of integrated-gasification-combined-cycle and pulverized-coal-fired steam plants: Volume 2, Sensitivity studies and appendixes: Final report  

SciTech Connect

The Electric Power Research Institute contracted with Bechtel Group, Inc., to provide an evaluation of the performance and costs for a Texaco-based integrated gasification combined cycle (IGCC) power plant as compared to a conventional pulverized coal-fired steam (PCFS) power plant with flue gas desulfurization (FGD). A general set of groundrules was used within which each plant design was optimized. The study incorporated numerous sensitivity cases along with up-to-date operating and cost data obtained through participation of equipment vendors and process developers. Consequently, the IGCC designs presented in this study use the most recent data available from Texaco's ongoing international coal gasification development program and General Electric's continuing gas turbine development efforts. The study confirms that the Texaco-based IGCC has advantages over the conventional PCFS technology with regard to environmental emissions and natural resource requirements. SO/sub 2/, NOx, and particulate emissions are lower. Land area and water requirements are less for IGCC concepts. In addition, coal consumption is less due to the higher plant thermal efficiency attainable in the IGCC plant. The IGCC plant also has the capability to be designed in several different configurations, with and without the use of natural gas or oil as a backup fuel. This capability may prove to be particularly advantageous in certain utility planning and operation scenarios.

Pietruszkiewicz, J.; Milkavich, R.J.; Booras, G.S.; Thomas, G.O.; Doss, H.

1988-09-01T23:59:59.000Z

199

Recycle of LWR (Light Water Reactor) actinides to an IFR (Integral Fast Reactor)  

SciTech Connect

A large quantity of actinide elements is present in irradiated Light Water Reactor (LWR) fuel that is stored throughout the world. Because of the high fission-to-capture ratio for the transuranium (TRU) elements with the high-energy neutrons in the metal-fueled Integral Fast Reactor (IFR), that reactor can consume these elements effectively. The stored fuel represents a valuable resource for an expanding application of fast power reactors. In addition, removal of the TRU elements from the spent LWR fuel has the potential for increasing the capacity of a high-level waste facility by reducing the heat loads and increasing the margin of safety in meeting licensing requirements. Argonne National Laboratory (ANL) is developing a pyrochemical process, which is compatible with the IFR fuel cycle, for the recovery of TRU elements from LWR fuel. The proposed product is a metallic actinide ingot, which can be introduced into the electrorefining step of the IFR process. The major objective of the LWR fuel recovery process is high TRU element recovery, with decontamination a secondary issue, because fission product removal is accomplished in the IFR process. The extensive pyrochemical processing studies of the 1960s and 1970s provide a basis for the design of possible processes. Two processes were selected for laboratory-scale investigation. One is based on the Salt Transport Process studied at ANL for mixed-oxide fast reactor fuel, and the other is based on the blanket processing studies done for ANL's second Experimental Breeder Reactor (EBR-2). This paper discusses the two processes and is a status report on the experimental studies. 5 refs., 2 figs., 2 tabs.

Pierce, R.D.; Ackerman, J.P.; Johnson, G.K.; Mulcahey, T.P.; Poa, D.S.

1991-01-01T23:59:59.000Z

200

Biomass Gasification Combined Cycle  

DOE Green Energy (OSTI)

Gasification combined cycle continues to represent an important defining technology area for the forest products industry. The ''Forest Products Gasification Initiative'', organized under the Industry's Agenda 2020 technology vision and supported by the DOE ''Industries of the Future'' program, is well positioned to guide these technologies to commercial success within a five-to ten-year timeframe given supportive federal budgets and public policy. Commercial success will result in significant environmental and renewable energy goals that are shared by the Industry and the Nation. The Battelle/FERCO LIVG technology, which is the technology of choice for the application reported here, remains of high interest due to characteristics that make it well suited for integration with the infrastructure of a pulp production facility. The capital cost, operating economics and long-term demonstration of this technology area key input to future economically sustainable projects and must be verified by the 200 BDT/day demonstration facility currently operating in Burlington, Vermont. The New Bern application that was the initial objective of this project is not currently economically viable and will not be implemented at this time due to several changes at and around the mill which have occurred since the inception of the project in 1995. The analysis shows that for this technology, and likely other gasification technologies as well, the first few installations will require unique circumstances, or supportive public policies, or both to attract host sites and investors.

Judith A. Kieffer

2000-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Rigorous Kinetic Modeling, Optimization, and Operability Studies of a Modified Claus Unit for an Integrated Gasification Combined Cycle (IGCC) Power Plant with CO{sub 2} Capture  

Science Conference Proceedings (OSTI)

The modified Claus process is one of the most common technologies for sulfur recovery from acid gas streams. Important design criteria for the Claus unit, when part of an Integrated Gasification Combined Cycle (IGCC) power plant, are the ability to destroy ammonia completely and the ability to recover sulfur thoroughly from a relatively low purity acid gas stream without sacrificing flame stability. Because of these criteria, modifications to the conventional process are often required, resulting in a modified Claus process. For the studies discussed here, these modifications include the use of a 95% pure oxygen stream as the oxidant, a split flow configuration, and the preheating of the feeds with the intermediate pressure steam generated in the waste heat boiler (WHB). In the future, for IGCC plants with CO{sub 2} capture, the Claus unit must satisfy emission standards without sacrificing the plant efficiency in the face of typical disturbances of an IGCC plant, such as rapid change in the feed flow rates due to load-following and wide changes in the feed composition because of changes in the coal feed to the gasifier. The Claus unit should be adequately designed and efficiently operated to satisfy these objectives. Even though the Claus process has been commercialized for decades, most papers concerned with the modeling of the Claus process treat the key reactions as equilibrium reactions. Such models are validated by manipulating the temperature approach to equilibrium for a set of steady-state operating data, but they are of limited use for dynamic studies. One of the objectives of this study is to develop a model that can be used for dynamic studies. In a Claus process, especially in the furnace and the WHB, many reactions may take place. In this work, a set of linearly independent reactions has been identified, and kinetic models of the furnace flame and anoxic zones, WHB, and catalytic reactors have been developed. To facilitate the modeling of the Claus furnace, a four-stage method was devised so as to determine which set of linearly independent reactions would best describe the product distributions from available plant data. Various approaches are taken to derive the kinetic rate expressions, which are either missing in the open literature or found to be inconsistent. A set of plant data is used for optimal estimation of the kinetic parameters. The final model agrees well with the published plant data. Using the developed kinetics models of the Claus reaction furnace, WHB, and catalytic stages, two optimization studies are carried out. The first study shows that there exists an optimal steam pressure generated in the WHB that balances hydrogen yield, oxygen demand, and power generation. In the second study, it is shown that an optimal H{sub 2}S/SO{sub 2} ratio exists that balances single-pass conversion, hydrogen yield, oxygen demand, and power generation. In addition, an operability study has been carried out to examine the operating envelope in which both the H{sub 2}S/SO{sub 2} ratio and the adiabatic flame temperature can be controlled in the face of disturbances typical for the operation of an IGCC power plant with CO{sub 2} capture. Impact of CO{sub 2} capture on the Claus process has also been discussed.

Jones, Dustin; Bhattacharyya, Debangsu; Turton, Richard; Zitney, Stephen E

2011-12-15T23:59:59.000Z

202

Rigorous Kinetic Modeling and Optimization Study of a Modified Claus Unit for an Integrated Gasification Combined Cycle (IGCC) Power Plant with CO{sub 2} Capture  

SciTech Connect

The modified Claus process is one of the most common technologies for sulfur recovery from acid gas streams. Important design criteria for the Claus unit, when part of an Integrated Gasification Combined Cycle (IGCC) power plant, are the ability to destroy ammonia completely and the ability to recover sulfur thoroughly from a relatively low purity acid gas stream without sacrificing flame stability. Because of these criteria, modifications to the conventional process are often required, resulting in a modified Claus process. For the studies discussed here, these modifications include the use of a 95% pure oxygen stream as the oxidant, a split flow configuration, and the preheating of the feeds with the intermediate pressure steam generated in the waste heat boiler (WHB). In the future, for IGCC plants with CO{sub 2} capture, the Claus unit must satisfy emission standards without sacrificing the plant efficiency in the face of typical disturbances of an IGCC plant, such as rapid change in the feed flow rates due to load-following and wide changes in the feed composition because of changes in the coal feed to the gasifier. The Claus unit should be adequately designed and efficiently operated to satisfy these objectives. Even though the Claus process has been commercialized for decades, most papers concerned with the modeling of the Claus process treat the key reactions as equilibrium reactions. Such models are validated by manipulating the temperature approach to equilibrium for a set of steady-state operating data, but they are of limited use for dynamic studies. One of the objectives of this study is to develop a model that can be used for dynamic studies. In a Claus process, especially in the furnace and the WHB, many reactions may take place. In this work, a set of linearly independent reactions has been identified, and kinetic models of the furnace flame and anoxic zones, WHB, and catalytic reactors have been developed. To facilitate the modeling of the Claus furnace, a four-stage method was devised so as to determine which set of linearly independent reactions would best describe the product distributions from available plant data. Various approaches are taken to derive the kinetic rate expressions, which are either missing in the open literature or found to be inconsistent. A set of plant data is used for optimal estimation of the kinetic parameters. The final model agrees well with the published plant data. Using the developed kinetics models of the Claus reaction furnace, WHB, and catalytic stages, two optimization studies are carried out. The first study shows that there exists an optimal steam pressure generated in the WHB that balances hydrogen yield, oxygen demand, and power generation. In the second study, it is shown that an optimal H{sub 2}S/SO{sub 2} ratio exists that balances single-pass conversion, hydrogen yield, oxygen demand, and power generation. In addition, an operability study has been carried out to examine the operating envelope in which both the H{sub 2}S/SO{sub 2} ratio and the adiabatic flame temperature can be controlled in the face of disturbances typical for the operation of an IGCC power plant with CO{sub 2} capture. Impact of CO{sub 2} capture on the Claus process has also been discussed.

Jones, Dustin; Bhattacharyya, Debangsu; Turton, Richard; Zitney, Stephen E.

2012-02-08T23:59:59.000Z

203

2007 gasification technologies conference papers  

Science Conference Proceedings (OSTI)

Sessions covered: gasification industry roundtable; the gasification market in China; gasification for power generation; the gasification challenge: carbon capture and use storage; industrial and polygeneration applications; gasification advantage in refinery applications; addressing plant performance; reliability and availability; gasification's contribution to supplementing gaseous and liquid fuels supplies; biomass gasification for fuel and power markets; and advances in technology-research and development

NONE

2007-07-01T23:59:59.000Z

204

NETL: Gasification Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Archive KEY: News News & Features Events Events Publications Publications 2013 2012 2011 2010...

205

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Power: Typical IGCC Configuration Power: Typical IGCC Configuration Major Commercial Examples of IGCC Plants While there are many coal gasification plants in the world co-producing electricity, chemicals and/or steam, the following are four notable, commercial-size IGCC plants currently in operation solely for producing electricity from coal and/or coke. Tampa Electric, Polk County 250 MW GE Gasifier Wabash, West Terre Haute 265 MW CoP E-Gas(tm) Gasifier Nuon, Buggenum 250 MW Shell Gasifier Elcogas, Puertollano 300 MW Prenflo Gasifier All of the plants began operation prior to 2000 and employ high temperature entrained-flow gasification technology. GE (formerly Texaco-Chevron) and ConocoPhillips (CoP) are slurry feed gasifiers, while Shell and Prenflo are dry feed gasifiers. None of these plants currently capture carbon dioxide (CO2). A simplified process flow diagram of the 250-MW Tampa Electric IGCC plant is shown in Figure 1 to illustrate the overall arrangement of an operating commercial scale IGCC plant. The Tampa Electric plant is equipped with both radiant and convective coolers for heat recovery, generating high pressure (HP) steam.

206

NETL: Gasification Systems - Advanced CO2 Capture Technology...  

NLE Websites -- All DOE Office Websites (Extended Search)

is demonstrating the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low-rank coals. The...

207

NETL: Gasification - Mitigation of Syngas Cooler Plugging and...  

NLE Websites -- All DOE Office Websites (Extended Search)

the coal gasifier and the combustion turbine. Syngas coolers used in Integrated Gasification Combined Cycle (IGCC) plants offer high efficiency, but their reliability is...

208

NETL: Gasification Systems - Evaluation of the Benefits of Advanced...  

NLE Websites -- All DOE Office Websites (Extended Search)

economically provide feeding of low-cost, low-rank coals into commercial Integrated Gasification Combined Cycle (IGCC) systems. GE is completing comparative techno-economic studies...

209

NETL: Gasification Systems - High Temperature Syngas Cleanup...  

NLE Websites -- All DOE Office Websites (Extended Search)

construct the project and sequester the CO2. The Polk Power Station, an integrated gasification combined cycle (IGCC) power plant, will supply a portion of its coal-derived syngas...

210

Thermodynamic Phase Stability in Gasification Carbon Feedstock ...  

Science Conference Proceedings (OSTI)

Conference Tools for 2014 TMS Annual Meeting & Exhibition ... Symposium, Energy Technologies and Carbon Dioxide Management ... Abstract Scope, Integrated Gasification Combined Cycle for power production is considered a clean ... of Differently Heat Treated Steels in CCS Environment with Supercritical CO2.

211

Method for increasing steam decomposition in a coal gasification process  

SciTech Connect

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, Marvin W. (Fairview, WV)

1988-01-01T23:59:59.000Z

212

Method for increasing steam decomposition in a coal gasification process  

DOE Patents (OSTI)

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, M.W.

1987-03-23T23:59:59.000Z

213

Catalysis in biomass gasification  

DOE Green Energy (OSTI)

The objective of these studies is to evaluate the technical and economic feasibility of producing specific gas products by catalytic gasification of biomass. Catalyst performance is a key factor in the feasibility of catalytic gasification processes. The results of studies designed to gain a fundamental understanding of catalytic mechanisms and causes of deactivation, and discussion of the state-of-the-art of related catalytic processes are presented. Experiments with primary and secondary catalysts were conducted in a 5-cm-diameter, continuous-wood-feed, fixed-catalyst-bed reactor. The primary catalysts used in the experiments were alkali carbonates mixed with the biomass feed; the secondary catalysts included nickel or other transition metals on supports such as alumina, silica, or silica-alumina. The primary catalysts were found to influence wood pyrolysis as well as the char/steam reaction. Secondary catalysts were used in a fixed-bed configuration to direct gas phase reactions. Results of the performance of these catalysts are presented. Secondary catalysts were found to be highly effective for conversion of biomass to specific gas products: synthesis gases and methane-rich gas. With an active catalyst, equilibrium gas composition are obtained, and all liquid pyrolysis products are converted to gases. The major cause of catalyst deactivation was carbon deposition, or coking. Loss of surface area by sintering was also inportant. Catalyst deactivation by sulfur poisoning was observed when bagasse was used as the feedstock for catalytic gasification. Mechanisms of catalyst activity and deactivation are discussed. Model compounds (methane, ethylene, and phenol) were used to determine coking behavior of catalysts. Carbon deposition is more prevalent with ethylene and phenol than with methane. Catalyst formulations that are resistant to carbon deposition are presented. 60 references, 10 figures, 21 tables.

Baker, E.G.; Mudge, L.K.

1984-06-01T23:59:59.000Z

214

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Major Partner Test Sites Major Partner Test Sites Gasification Systems Technologies - Major Partner Test Sites Major Partner Test Sites Once a technology is ready to be tested at pilot or commercial scale, the cost of building a test facility becomes significant -- often beyond the funding provided for any one project. It then becomes critical to test the technology at a pre-existing facility willing to test experimental technologies. Not surprisingly, most commercial facilities are hesitant to interfere with their operations to experiment, but others, with a view towards the future, welcome promising technologies. Below is a list of major partner test sites that actively host DOE supported research activities. Many of the test sites were built with DOE support, but many were not. Some are commercial, and were designed to perform experimental work. All play an important role in developing technologies with minimal expense to the project, and to the U.S. taxpayer.

215

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Capture R&D Capture R&D DOE/NETL's pre-combustion CO2 control technology portfolio of R&D projects is examining various CO2 capture technologies, and supports identification of developmental pathways linking advanced fossil fuel conversion and CO2 capture. The Program's CO2 capture activity is being conducted in close coordination with that of advanced, higher-efficiency power generation and fossil fuel conversion technologies such as gasification. Links to the projects can be found here. Finally, an exhaustive and periodically updated report on CO2 capture R&D sponsored by NETL is available: DOE/NETL Advanced CO2 Capture R&D Program: Technology Update (also referred to as the CO2 Handbook). Carbon Dioxide CO2 Capture Commercial CO2 Uses & Carbon Dioxide Enhanced Oil Recovery

216

Novel, Integrated Reactor / Power Conversion System (LMR-AMTEC)  

DOE Green Energy (OSTI)

The main features of this project were the development of a long life (up to 10 years) Liquid Metal Reactor (LMR) and a static conversion subsystem comprising an Alkali Metal Thermal-to-Electric (AMTEC) topping cycle and a ThermoElectric (TE) Bottom cycle. Various coupling options of the LMR with the energy conversion subsystem were explored and, base in the performances found in this analysis, an Indirect Coupling (IC) between the LMR and the AMTEC/TE converters with Alkali Metal Boilers (AMB) was chosen as the reference design. The performance model of the fully integrated sodium-and potassium-AMTEC/TE converters shows that a combined conversion efficiency in excess of 30% could be achieved by the plant. (B204)

Pablo Rubiolo, Principal Investigator

2003-03-21T23:59:59.000Z

217

Thermogravimetric Study of Effect of Mineral Content and Maceral Composition on Illinois Coal Gasification.  

E-Print Network (OSTI)

??The effects of mineral and maceral composition on Illinois coal gasification were studied by thermogravimetric analysis and semi-batch reactor. Macerals were separated from coal samples.… (more)

Zhang, Quan

2013-01-01T23:59:59.000Z

218

Major Environmental Aspects of Gasification-Based Power Generation Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Detailed Evaluation of the Environmental Performance of Gasification-Based Power Systems Detailed Evaluation of the Environmental Performance of Gasification-Based Power Systems DECEMBER 2002 U.S. DOE/NETL 2-1 2. DETAILED EVALUATION OF THE ENVIRONMENTAL PERFORMANCE OF GASIFICATION-BASED POWER SYTEMS 2.1 Introduction and Summary of Information Presented The single most compelling reason for utilities to consider coal gasification for electric power generation is superior environmental performance. 1 As shown in Figure 2-1, gasification has fundamental environmental advantages over direct coal combustion. Commercial-scale plants for both integrated gasification combined cycle (IGCC) electric power generation and chemicals applications have already successfully demonstrated these advantages. The superior environmental capabilities of coal gasification apply to all three areas of concern: air emissions,

219

Gasification | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification Gasification Gasification The Wabash River Clean Coal Power Plant The Wabash River Clean Coal Power Plant Gasification Technology R&D Coal gasification offers one of the most versatile and clean ways to convert coal into electricity, hydrogen, and other valuable energy products. Coal gasification electric power plants are now operating commercially in the United States and in other nations, and many experts predict that coal gasification will be at the heart of future generations of clean coal technology plants. Rather than burning coal directly, gasification (a thermo-chemical process) breaks down coal - or virtually any carbon-based feedstock - into its basic chemical constituents. In a modern gasifier, coal is typically exposed to steam and carefully controlled amounts of air or oxygen under high

220

Gasification: redefining clean energy  

Science Conference Proceedings (OSTI)

This booklet gives a comprehensive overview of how gasification is redefining clean energy, now and in the future. It informs the general public about gasification in a straight-forward, non-technical manner.

NONE

2008-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Coal gasification  

Science Conference Proceedings (OSTI)

A standard series of two staged gas generators (GG) has been developed in the United States for producing gas with a combustion heat from 4,700 to 7,600 kilojoules per cubic meter from coal (U). The diameter of the gas generators is from 1.4 to 3.65 meters and the thermal capacity based on purified cold gas is from 12.5 to 89 million kilojoules per hour. Certain standard sized gas generators have undergone experimental industrial tests which showed that it is most expedient to feed the coal into the gas generators pneumatically. This reduces the dimensions of the charging device, makes it possible to use more common grades of structural steels and reduces the cost of the gas. A double valve reliably prevents ejections of the gasification product and promotes the best distribution of the coal in the gas generator. The gas generators may successfully operate on high moisture (up to 36 percent) brown coal. Blasting with oxygen enriched to 38 percent made it possible to produce a gas with a combustion heat of 9,350 kilojoules per cubic meter. This supports a combustion temperature of 1,700C.

Rainey, D.L.

1983-01-01T23:59:59.000Z

222

Biomass Gasification Technology Commercialization  

Science Conference Proceedings (OSTI)

Reliable cost and performance data on biomass gasification technology is scarce because of limited experience with utility-scale gasification projects and the reluctance of vendors to share proprietary information. The lack of this information is a major obstacle to the implementation of biomass gasification-based power projects in the U.S. market. To address this problem, this report presents four case studies for bioenergy projects involving biomass gasification technologies: A utility-scale indirect c...

2010-12-10T23:59:59.000Z

223

Orlando Gasification Project Generic Design Specification  

Science Conference Proceedings (OSTI)

Integrated Gasification Combined Cycle (IGCC) technology is now entering commercial service, so there is a need to develop specifications that encourage greater standardization in IGCC design. This Generic Design Specification (GDS), sponsored by EPRI's CoalFleet for Tomorrow program with support from 50 power companies, provides technical information from Front End Engineering Design (FEED) results submitted by Southern Company Services to DOE regarding their Orlando Gasification Project (OGP), a 270 MW...

2008-05-12T23:59:59.000Z

224

Gasification and combustion modeling for porous char particles  

E-Print Network (OSTI)

Gasification and combustion of porous char particles occurs in many industrial applications. Reactor-scale outputs of importance depend critically on processes that occur at the particle-scale. Because char particles often ...

Singer, Simcha Lev

2012-01-01T23:59:59.000Z

225

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen: SNG from Coal: Process & Commercialization Hydrogen: SNG from Coal: Process & Commercialization Weyburn Project The Great Plains Synfuels Plant (GPSP) has had the ability to capture CO2 through the Rectisol process for sequestration or sale as a byproduct. However, no viable market was found for the CO2 in the early years of operation, and the captured CO2 was simply discharged to the atmosphere. This changed in 2000, when the GPSP began selling CO2 emissions, becoming one of the first commercial coal facilities to have its CO2 sequestered. The program had begun in 1997, when EnCana (formerly PanCanadian Resources) sought a solution to declining production in their Weyburn Oil Fields. Dakota Gasification Company, owners of the GPSP, and EnCana made an agreement to sell CO2 for use in Enhanced Oil Recovery (EOR). DGC installed two large CO2 compressors and began shipping 105 million standard cubic feet per day of compressed CO2 (60% of the total CO2 produced at the plant) through a 205 mile pipeline from Beulah, North Dakota, to the Weyburn Oil Fields, located in Saskatchewan, Canada, for EOR. The pipeline was constructed and operated by a BEPC subsidiary. The CO2, about 95.5% pure and very dry, is injected into the mature fields where it has doubled the oil recovery rate of the field. In 2006, a third compressor was installed and an additional agreement was reached with Apache Canada Ltd. to supply CO2 for EOR to their nearby oilfields. The three compressors increased CO2 delivery to 160 million standard cubic feet (MMSCF; or 8,000 tonnes) per day. Through 2007, over 12 million tons of CO2 had been sold, and over the current expected lifetime of the program, an anticipated 20 million tons of CO2 will be stored.

226

The United States of America and the People`s Republic of China experts report on integrated gasification combined-cycle technology (IGCC)  

SciTech Connect

A report written by the leading US and Chinese experts in Integrated Gasification Combined Cycle (IGCC) power plants, intended for high level decision makers, may greatly accelerate the development of an IGCC demonstration project in the People`s Republic of China (PRC). The potential market for IGCC systems in China and the competitiveness of IGCC technology with other clean coal options for China have been analyzed in the report. Such information will be useful not only to the Chinese government but also to US vendors and companies. The goal of this report is to analyze the energy supply structure of China, China`s energy and environmental protection demand, and the potential market in China in order to make a justified and reasonable assessment on feasibility of the transfer of US Clean Coal Technologies to China. The Expert Report was developed and written by the joint US/PRC IGCC experts and will be presented to the State Planning Commission (SPC) by the President of the CAS to ensure consideration of the importance of IGCC for future PRC power production.

1996-12-01T23:59:59.000Z

227

Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill  

Science Conference Proceedings (OSTI)

As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry’s energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also produced a comparable tensile and burst index pulps. Product gas composition determined using computer simulations The results demonstrate that RVS-1 can effectively remove > 99.8% of the H2S present in simulated synthesis gas generated from the gasification of black liquor. This level of sulfur removal was consistent over simulated synthesis gas mixtures that contained from 6 to 9.5 vol % H2S.A significant amount of the sulfur in the simulated syngas was recovered as SO2 during regeneration. The average recovery of sulfur as SO2 was about 75%. Because these are first cycle results, this sulfur recovery is expected to improve. Developed WINGems model of the process.The total decrease in variable operating costs for the BLG process compared to the HERB was in excess of $6,200,000 per year for a mill producing 350,000 tons of pulp per year. This represents a decrease in operating cost of about $17.7/ton of oven dry pulp produced. There will be additional savings in labor and maintenance cost that has not been taken into account. The capital cost for the MSSAQ based gasifier system was estimated at $164,000,000, which is comparable to a High Efficiency Recovery Boiler. The return on investment was estimated at 4%. A gasifier replacement cannot be justified on its own, however if the recovery boiler needs to be replaced the MSSAQ gasifier system shows significantly higher savings. Before black liquor based gasifer technology can be commercialized more work is necessary. The recovery of the absorbed sulfur in the absorbent as sulfur dioxide is only 75%. This needs to be greater than 90% for economical operation. It has been suggested that as the number of cycles is increased the sulfur dioxide recovery might improve. Further research is necessary. Even though a significant amount of work has been done on a pilot scale gasifiers using liquors containing sulfur, both at low and high temperatures the lack of a commercial unit is an impediment to the implementation of the MSSAQ technology. The implementation of a commercial unit needs to be facilated before the benefits of

Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

2010-01-27T23:59:59.000Z

228

Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill  

SciTech Connect

As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry’s energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also produced a comparable tensile and burst index pulps. Product gas composition determined using computer simulations The results demonstrate that RVS-1 can effectively remove > 99.8% of the H2S present in simulated synthesis gas generated from the gasification of black liquor. This level of sulfur removal was consistent over simulated synthesis gas mixtures that contained from 6 to 9.5 vol % H2S.A significant amount of the sulfur in the simulated syngas was recovered as SO2 during regeneration. The average recovery of sulfur as SO2 was about 75%. Because these are first cycle results, this sulfur recovery is expected to improve. Developed WINGems model of the process.The total decrease in variable operating costs for the BLG process compared to the HERB was in excess of $6,200,000 per year for a mill producing 350,000 tons of pulp per year. This represents a decrease in operating cost of about $17.7/ton of oven dry pulp produced. There will be additional savings in labor and maintenance cost that has not been taken into account. The capital cost for the MSSAQ based gasifier system was estimated at $164,000,000, which is comparable to a High Efficiency Recovery Boiler. The return on investment was estimated at 4%. A gasifier replacement cannot be justified on its own, however if the recovery boiler needs to be replaced the MSSAQ gasifier system shows significantly higher savings. Before black liquor based gasifer technology can be commercialized more work is necessary. The recovery of the absorbed sulfur in the absorbent as sulfur dioxide is only 75%. This needs to be greater than 90% for economical operation. It has been suggested that as the number of cycles is increased the sulfur dioxide recovery might improve. Further research is necessary. Even though a significant amount of work has been done on a pilot scale gasifiers using liquors containing sulfur, both at low and high temperatures the lack of a commercial unit is an impediment to the implementation of the MSSAQ technology. The implementation of a commercial unit needs to be facilated before the benefits of

Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

2010-01-27T23:59:59.000Z

229

2010 Worldwide Gasification Database  

DOE Data Explorer (OSTI)

The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers. [Copied from http://www.netl.doe.gov/technologies/coalpower/gasification/worlddatabase/index.html

230

Apparatus for solar coal gasification  

DOE Patents (OSTI)

Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

Gregg, D.W.

1980-08-04T23:59:59.000Z

231

State estimation of an acid gas removal (AGR) plant as part of an integrated gasification combined cycle (IGCC) plant with CO2 capture  

Science Conference Proceedings (OSTI)

An accurate estimation of process state variables not only can increase the effectiveness and reliability of process measurement technology, but can also enhance plant efficiency, improve control system performance, and increase plant availability. Future integrated gasification combined cycle (IGCC) power plants with CO2 capture will have to satisfy stricter operational and environmental constraints. To operate the IGCC plant without violating stringent environmental emission standards requires accurate estimation of the relevant process state variables, outputs, and disturbances. Unfortunately, a number of these process variables cannot be measured at all, while some of them can be measured, but with low precision, low reliability, or low signal-to-noise ratio. As a result, accurate estimation of the process variables is of great importance to avoid the inherent difficulties associated with the inaccuracy of the data. Motivated by this, the current paper focuses on the state estimation of an acid gas removal (AGR) process as part of an IGCC plant with CO2 capture. This process has extensive heat and mass integration and therefore is very suitable for testing the efficiency of the designed estimators in the presence of complex interactions between process variables. The traditional Kalman filter (KF) (Kalman, 1960) algorithm has been used as a state estimator which resembles that of a predictor-corrector algorithm for solving numerical problems. In traditional KF implementation, good guesses for the process noise covariance matrix (Q) and the measurement noise covariance matrix (R) are required to obtain satisfactory filter performance. However, in the real world, these matrices are unknown and it is difficult to generate good guesses for them. In this paper, use of an adaptive KF will be presented that adapts Q and R at every time step of the algorithm. Results show that very accurate estimations of the desired process states, outputs or disturbances can be achieved by using the adaptive KF.

Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

2012-01-01T23:59:59.000Z

232

Coal gasification players, projects, prospects  

SciTech Connect

Integrated gasification combined cycle (IGCC) technology has been running refineries and chemical plants for decades. Power applications have dotted the globe. Two major IGCC demonstration plants operating in the United States since the mid-1900s have helped set the stage for prime time, which is now approaching. Two major reference plant designs are in the wings and at least two major US utilities are poised to build their own IGCC power plants. 2 figs.

Blankinship, S.

2006-07-15T23:59:59.000Z

233

Gasification Technology Status – September 2004  

Science Conference Proceedings (OSTI)

Concern over the continued availability of natural gas at competitive prices has led many power companies to initiate studies and projects on clean coal technologies as a strategic hedge against over-reliance on natural gas alone to provide future power needs. Integrated gasification combined cycle (IGCC) plants can meet very stringent emissions targets, including those for mercury and carbon dioxide (CO2). Several years of commercial operation have been accumulated on coal based IGCC plants in the Unite...

2004-09-29T23:59:59.000Z

234

Apparatus and method for solar coal gasification  

DOE Patents (OSTI)

Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

Gregg, David W. (Moraga, CA)

1980-01-01T23:59:59.000Z

235

Materials Reliability Program: Reactor Pressure Vessel Integrity Training Module (MRP-286)  

Science Conference Proceedings (OSTI)

For many reactor pressure vessels, embrittlement is the primary concern in ensuring continued safe operation. The shutdown of the Yankee Rowe plant, which occurred because of uncertainties related to embrittlement of the vessel, demonstrated the importance of adequately addressing embrittlement issues. Managing embrittlement involves the integration, management, and implementation of diverse technical, regulatory, planning, and economic activities. Reactor vessel embrittlement management is an essential ...

2010-11-22T23:59:59.000Z

236

The Ongoing Impact of the U.S. Fast Reactor Integral Experiments Program  

SciTech Connect

The creation of a large database of integral fast reactor physics experiments advanced nuclear science and technology in ways that were unachievable by less capital intensive and operationally challenging approaches. They enabled the compilation of integral physics benchmark data, validated (or not) analytical methods, and provided assurance of future rector designs The integral experiments performed at Argonne National Laboratory (ANL) represent decades of research performed to support fast reactor design and our understanding of neutronics behavior and reactor physics measurements. Experiments began in 1955 with the Zero Power Reactor No. 3 (ZPR-3) and terminated with the Zero Power Physics Reactor (ZPPR, originally the Zero Power Plutonium Reactor) in 1990 at the former ANL-West site in Idaho, which is now part of the Idaho National Laboratory (INL). Two additional critical assemblies, ZPR-6 and ZPR-9, operated at the ANL-East site in Illinois. A total of 128 fast reactor assemblies were constructed with these facilities [1]. The infrastructure and measurement capabilities are too expensive to be replicated in the modern era, making the integral database invaluable as the world pushes ahead with development of liquid metal cooled reactors.

John D. Bess; Michael A. Pope; Harold F. McFarlane

2012-11-01T23:59:59.000Z

237

Testing of Biomass in a Transport Reactor Gasifier  

Science Conference Proceedings (OSTI)

A 200-hour gasification test was undertaken on biomass fuels from sources that include wood waste and a potential energy crop such as switchgrass. The test involved the design and construction of a feed system to allow 100% biomass to be continuously fed to the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center. Biomass performance was also assessed in a high-efficiency transport reactor gasifier, the centerpiece of an advanced biomass integrated ...

2012-11-28T23:59:59.000Z

238

Advanced Reactor Design for Integrated WGS/Pre-combustion CO2...  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Reactor Design for Integrated WGSPre-combustion CO2 Capture TDA Research, Inc. Project Number: FE0012048 Project Description The purpose is to develop a new high-hydrogen...

239

22.39 Integration of Reactor Design, Operations, and Safety, Fall 2005  

E-Print Network (OSTI)

This course integrates studies of reactor physics and engineering sciences into nuclear power plant design. Topics include materials issues in plant design and operations, aspects of thermal design, fuel depletion and ...

Todreas, Neil E.

240

Dynamic simulation and load-following control of an integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture  

Science Conference Proceedings (OSTI)

Load-following control of future integrated gasification combined cycle (IGCC) plants with pre-combustion CO{sub 2} capture is expected to be far more challenging as electricity produced by renewable energy is connected to the grid and strict environmental limits become mandatory requirements. To study control performance during load following, a plant-wide dynamic simulation of a coal-fed IGCC plant with CO{sub 2} capture has been developed. The slurry-fed gasifier is a single-stage, downward-fired, oxygen-blown, entrained-flow type with a radiant syngas cooler (RSC). The syngas from the outlet of the RSC goes to a scrubber followed by a two-stage sour shift process with inter-stage cooling. The acid gas removal (AGR) process is a dual-stage physical solvent-based process for selective removal of H{sub 2}S in the first stage and CO{sub 2} in the second stage. Sulfur is recovered using a Claus unit with tail gas recycle to the AGR. The recovered CO{sub 2} is compressed by a split-shaft multistage compressor and sent for sequestration after being treated in an absorber with triethylene glycol for dehydration. The clean syngas is sent to two advanced “F”-class gas turbines (GTs) partially integrated with an elevated-pressure air separation unit. A subcritical steam cycle is used for heat recovery steam generation. A treatment unit for the sour water strips off the acid gases for utilization in the Claus unit. The steady-state model developed in Aspen Plus® is converted to an Aspen Plus Dynamics® simulation and integrated with MATLAB® for control studies. The results from the plant-wide dynamic model are compared qualitatively with the data from a commercial plant having different configuration, operating condition, and feed quality than what has been considered in this work. For load-following control, the GT-lead with gasifier-follow control strategy is considered. A modified proportional–integral–derivative (PID) control is considered for the syngas pressure control. For maintaining the desired CO{sub 2} capture rate while load-following, a linear model predictive controller (LMPC) is implemented in MATLAB®. A combined process and disturbance model is identified by considering a number of model forms and choosing the final model based on an information-theoretic criterion. The performance of the LMPC is found to be superior to the conventional PID control for maintaining CO{sub 2} capture rates in an IGCC power plant while load following.

Bhattacharyya, D,; Turton, R.; Zitney, S.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur Recovery and Tail Gas Treating Sulfur Recovery and Tail Gas Treating SCOT Tail Gas Treating Figure 1 shows a simplified SCOT tail gas treating unit (TGTU). Tail gas from the Claus SRU is heated in an in-line burner before entering the hydrogenation reactor, where all sulfur species are converted to H2S. Hydrogenation reactor effluent is then cooled by generating low pressure (LP) steam, followed by additional cooling by cooling water exchange. Residual H2S in the cooled tail gas is removed with amine in a counter-current packed absorber. The treated tail gas from the absorber top is incinerated before being vented to the atmosphere. The rich solvent from the amine absorber is pumped to the regenerator after heat exchange against the hot lean solvent from the regenerator. Acid gases are stripped from the solvent in the trayed regenerator via a steam reboiler. The hot lean solvent from the regenerator bottom is pumped back to the absorber after being heat exchanged with rich solvent and cooling water to lower its temperature. Acid gas from TGTU amine regenerator overhead is recycled back to the Claus plant for sulfur recovery.

242

Engineering and Economic Evaluations of Integrated-Gasification Combined-Cycle Plant Designs with Carbon Dioxide Capture  

Science Conference Proceedings (OSTI)

The objectives of this research were to assess the performance and costs of coal-fired integrated-gasificationcombined-cycle (IGCC) power plants. The base cases are Greenfield designs without carbon dioxide (CO2) capture; two additional cases were studied with retrofitted full CO2 capture. The study represents Phase 3 of a multiyear study executed on behalf of the CoalFleet for Tomorrow program, a collaborative research and development program that promotes the deployment of advanced coal technologies, i...

2011-09-29T23:59:59.000Z

243

NETL: Gasifipedia - Gasification in Detail  

NLE Websites -- All DOE Office Websites (Extended Search)

Commercial Gasifiers Commercial Gasifiers Types of Gasifiers Although there are various types of gasifers (gasification reactors), different in design and operational characteristics, there are three main gasifier classifications into which most of the commercially available gasifiers fall. These categories are as follows: Fixed-bed gasifiers (also referred as moving-bed gasifiers) Entrained-flow gasifiers Fluidized-bed gasifiers Commercial gasifiers of GE Energy, ConocoPhillips E-Gas(tm) and Shell SCGP are examples of entrained-flow types. Fixed-or moving-bed gasifiers include that of Lurgi and British Gas Lurgi (BGL). Fluidized-bed gasifiers include the catalytic gasifier technology being commercialized by Great Point Energy, the Winkler gasifier, and the KBR transport gasifiers. For more specific information on these gasifiers, follow the links for the bulleted gasifier types above. NOTE: Although specific gasifiers named above are described in detail throughout this website, it is realized that other gasification technologies exist. The gasifiers discussed herein were not preferentially chosen by NETL.

244

NETL: Gasification Archived Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Gasification Systems > Reference Shelf > Archived Projects Home > Technologies > Coal & Power Systems > Gasification Systems > Reference Shelf > Archived Projects Gasification Systems Reference Shelf - Archived Projects Archived Projects | Active Projects | All NETL Fact Sheets Feed Systems Reaction-Driven Ion Transport Membranes Gasifier Optimization and Plant Supporting Systems Coal/Biomass Gasification at Colorado School of Mines Co-Production of Electricity and Hydrogen Using a Novel Iron-Based Catalyst Co-Production of Substitute Natural Gas/Electricity via Catalytic Coal Gasification Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals Hybrid Combustion-Gasification Chemical Looping Coal Power Technology Development

245

Major Environmental Aspects of Gasification-Based Power Generation Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Detailed Detailed Evaluation of the Environmental Performance of Gasification-Based Power Systems DECEMBER 2002 U.S. DOE/NETL 2-1 2. DETAILED EVALUATION OF THE ENVIRONMENTAL PERFORMANCE OF GASIFICATION-BASED POWER SYTEMS 2.1 Introduction and Summary of Information Presented The single most compelling reason for utilities to consider coal gasification for electric power generation is superior environmental performance. 1 As shown in Figure 2-1, gasification has fundamental environmental advantages over direct coal combustion. Commercial-scale plants for both integrated gasification combined cycle (IGCC) electric power generation and chemicals applications have already successfully demonstrated these advantages. The superior environmental capabilities of coal gasification apply to all three areas of concern: air emissions, water discharges, and solid

246

Biomass Gasification Syngas Cleanup  

Science Conference Proceedings (OSTI)

In December 2012, the Electric Power Research Institute (EPRI) published report 1023994, Engineering and Economic Evaluation of Biomass Gasification, prepared by CH2M HILL Engineers, Inc. (CH2M HILL). It provided a global overview of commercially available biomass gasification technologies that can be used for power production in the 25- to 50-MWe range. The report provided detailed descriptions of biomass gasification technologies, typical operational parameters, emissions information, and ...

2013-12-23T23:59:59.000Z

247

Gasification of Lignite Coal  

Science Conference Proceedings (OSTI)

This report on the gasification of lignite coal is presented in two parts. The first includes research into technology options for preparing low-rank fuels for gasification, gasifiers for converting the coal into synthesis gas, and technologies that may be used to convert synthesis gas into valuable chemical products. The second part focuses on performance and cost screening analyses for either Greenfield or retrofit gasification options fueled by low-rank lignite coal. The work was funded through Tailor...

2009-01-23T23:59:59.000Z

248

JV Task 46 - Development and Testing of a Thermally Integrated SOFC-Gasification System for Biomass Power Generation  

DOE Green Energy (OSTI)

The Energy & Environmental Research Center has designed a biomass power system using a solid oxide fuel cell (SOFC) thermally integrated with a downdraft gasifier. In this system, the high-temperature effluent from the SOFC enables the operation of a substoichiometric air downdraft gasifier at an elevated temperature (1000 C). At this temperature, moisture in the biomass acts as an essential carbon-gasifying medium, reducing the equivalence ratio at which the gasifier can operate with complete carbon conversion. Calculations show gross conversion efficiencies up to 45% (higher heating value) for biomass moisture levels up to 40% (wt basis). Experimental work on a bench-scale gasifier demonstrated increased tar cracking within the gasifier and increased energy density of the resultant syngas. A series of experiments on wood chips demonstrated tar output in the range of 9.9 and 234 mg/m{sup 3}. Both button cells and a 100-watt stack was tested on syngas from the gasifier. Both achieved steady-state operation with a 22% and 15% drop in performance, respectively, relative to pure hydrogen. In addition, tar tolerance testing on button cells demonstrated an upper limit of tar tolerance of approximately 1%, well above the tar output of the gasifier. The predicted system efficiency was revised down to 33% gross and 27% net system efficiency because of the results of the gasifier and fuel cell experiments. These results demonstrate the feasibility and benefits of thermally integrating a gasifier and a high-temperature fuel cell in small distributed power systems.

Phillip Hutton; Nikhil Patel; Kyle Martin; Devinder Singh

2008-02-01T23:59:59.000Z

249

Trace metal transformation in gasification  

SciTech Connect

The Energy & Environmental Research Center (EERC) is carrying out an investigation that will provide methods to predict the fate of selected trace elements in integrated gasification combined cycle (IGCC) and integrated gasification fuel cell (IGFC) systems to aid in the development of methods to control the emission of trace elements determined to be air toxics. The goal of this project is to identify the effects of critical chemical and physical transformations associated with trace element behavior in IGCC and IGFC systems. The trace elements included in this project are arsenic, chromium, cadmium, mercury, nickel, selenium, and lead. The research seeks to identify and fill, experimentally and/or theoretically, data gaps that currently exist on the fate and composition of trace elements. The specific objectives are to 1) review the existing literature to identify the type and quantity of trace elements from coal gasification systems, 2) perform laboratory-scale experimentation and computer modeling to enable prediction of trace element emissions, and 3) identify methods to control trace element emissions.

Benson, S.A.; Erickson, T.A.; Zygarlicke, C.J.; O`Keefe, C.A.; Katrinak, K.A.; Allen, S.E.; Hassett, D.J.; Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center; Holcombe, N.T. [USDOE Morgantown Energy Technology Center, WV (United States)

1996-12-31T23:59:59.000Z

250

Trace metal transformations in gasification  

SciTech Connect

The Energy & Environmental Research Center (EERC) is carrying out an investigation that will provide methods to predict the fate of selected trace elements in integrated gasification combined cycle (IGCC) and integrated gasification fuel cell (IGFC) systems to aid in the development of methods to control the emission of trace elements determined to be air toxics. The goal of this project is to identify the effects of critical chemical and physical transformations associated with trace element behavior in IGCC and IGFC systems. The trace elements included in this project are arsenic, chromium, cadmium, mercury, nickel, selenium, and lead. The research seeks to identify and fill, experimentally and/or theoretically, data gaps that currently exist on the fate and composition of trace elements. The specific objectives are to (1) review the existing literature to identify the type and quantity of trace elements from coal gasification systems, (2) perform laboratory-scale experimentation and computer modeling to enable prediction of trace element emissions, and (3) identify methods to control trace element emissions.

Benson, S.; Erickson, T.A.; Zygarlicke, C.J. [and others

1995-12-01T23:59:59.000Z

251

Gasification Technologies_PRINT  

NLE Websites -- All DOE Office Websites (Extended Search)

electricity generation and production of chemicals and clean liquid fuels. In a time of electricity and fuel-price spikes, flexible gasification systems provide for operation on...

252

NETL: Gasification Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Archive KEY: News News & Features Events Events Publications Publications Archive 02.20.2013 News Funding Opportunity Announcement DE-FOA-0000784 entitled "Advanced...

253

2007 gasification technologies workshop papers  

Science Conference Proceedings (OSTI)

Topics covered in this workshop are fundamentals of gasification, carbon capture, reviews of financial and regulatory incentives, coal to liquids, and focus on gasification in the Western US.

NONE

2007-03-15T23:59:59.000Z

254

NETL: Gasifipedia - Introduction to Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Introduction Gasification is a technological process that uses heat, pressure, steam, and often oxygen to convert any carbonaceous (carbon-based) raw material into...

255

WABASH RIVER COAL GASIFICATION REPOWERING PROJECT  

Science Conference Proceedings (OSTI)

The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

Unknown

2000-09-01T23:59:59.000Z

256

Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications  

Science Conference Proceedings (OSTI)

This report is a summary of analyses performed by the NGNP project to determine whether it is technically and economically feasible to integrate high temperature gas cooled reactor (HTGR) technology into industrial processes. To avoid an overly optimistic environmental and economic baseline for comparing nuclear integrated and conventional processes, a conservative approach was used for the assumptions and calculations.

Lee Nelson

2011-09-01T23:59:59.000Z

257

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid Gas Removal (AGR) Acid Gas Removal (AGR) Sulfinol Sulfinol solvent is a composite solvent, consisting of a mixture of diisopropanolamine (30-45%) or MDEA, sulfolane (tetrahydrothiophene dioxide) (40-60%), and water (5-15%). The acid gas loading of the Sulfinol solvent is higher and the energy required for its regeneration is lower than those of purely chemical solvents. At the same time it has the advantage over purely physical solvents that severe product specifications can be met more easily and co-absorption of hydrocarbons is relatively low. For selective absorption of H2S, COS and mercaptans, while co-absorbing only part of the CO2, the Sulfinol-M process is used. Deep removal of CO2 in LNG plants is another application. Integration of gas treating with the SCOT solvent system is an option.

258

Adaptive nuclear reactor control for integral quadratic cost functions  

Science Conference Proceedings (OSTI)

The problem of optimally controlling the power level changes of a nuclear reactor is considered. The model of an existing power plant is used, which is a ninth-order nonlinear system, having time-varying parameters. A closed form solution of the optimal ...

George T. Bereznai; Naresh K. Sinha

1973-09-01T23:59:59.000Z

259

INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING  

Science Conference Proceedings (OSTI)

This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

Eric P. Robertson; Michael G. McKellar; Lee O. Nelson

2011-05-01T23:59:59.000Z

260

An integrated approach for the verification of fresh mixed oxide fuel (MOX) assemblies at light water reactor MOX recycle reactors  

Science Conference Proceedings (OSTI)

This paper presents an integrated approach for the verification of mixed oxide (MOX) fuel assemblies prior to their being loaded into the reactor. There is a coupling of the verification approach that starts at the fuel fabrication plant and stops with the transfer of the assemblies into the thermal reactor. The key measurement points are at the output of the fuel fabrication plant, the receipt at the reactor site, and the storage in the water pool as fresh fuel. The IAEA currently has the capability to measure the MOX fuel assemblies at the output of the fuel fabrication plants using a passive neutron coincidence counting systems of the passive neutron collar (PNCL) type. Also. at the MOX reactor pool, the underwater coincidence counter (UWCC) has been developed to measure the MOX assemblies in the water. The UWCC measurement requires that the fuel assembly be lifted about two meters up in the storage rack to avoid interference from the fuel that is stored in the rack. This paper presents a new method to verify the MOX fuel assemblies that are in the storage rack without the necessity of moving the fuel. The detector system is called the Underwater MOX Verification System (UMVS). The integration and relationship of the three measurements systems is described.

Menlove, Howard O [Los Alamos National Laboratory; Lee, Sang - Yoon [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

DOE Green Energy (OSTI)

Hydrogen production from coal gasification can be enhanced by driving the equilibrium limited Water Gas Shift reaction forward by incessantly removing the CO{sub 2} by-product via the carbonation of calcium oxide. This project aims at using the OSU patented high-reactivity mesoporous precipitated calcium carbonate sorbent for removing the CO{sub 2} product. Preliminary experiments demonstrate the show the superior performance of the PCC sorbent over other naturally occurring calcium sorbents. Gas composition analyses show the formation of 100% pure hydrogen. Novel calcination techniques could lead to smaller reactor footprint and single-stage reactors that can achieve maximum theoretical H{sub 2} production for multicyclic applications. Sub-atmospheric calcination studies reveal the effect of vacuum level, diluent gas flow rate, thermal properties of the diluent gas and the sorbent loading on the calcination kinetics which play an important role on the sorbent morphology. Steam, which can be easily separated from CO{sub 2}, is envisioned to be a potential diluent gas due to its enhanced thermal properties. Steam calcination studies at 700-850 C reveal improved sorbent morphology over regular nitrogen calcination. A mixture of 80% steam and 20% CO{sub 2} at ambient pressure was used to calcine the spent sorbent at 820 C thus lowering the calcination temperature. Regeneration of calcium sulfide to calcium carbonate was achieved by carbonating the calcium sulfide slurry by bubbling CO{sub 2} gas at room temperature.

Mahesh Iyer; Himanshu Gupta; Danny Wong; Liang-Shih Fan

2005-09-30T23:59:59.000Z

262

Gasification Product Improvement Facility status  

SciTech Connect

The objective of the Gasification Product Improvement Facility (GPIF) project is to provide a test site to support early commercialization of the Integrated Gasification Combined Cycle (IGCC) technology. The design of this facility will by based on PyGas{trademark}, a patented air blown fixed bed gasification process. The GPIF will be capable of processing run-of-mine high swelling coals that comprise 87% of all Eastern US coals. The GPIF project is expected to deliver a gasifier design that will satisfy the criteria for good process performance and cost effectiveness. The PyGas{trademark} process was conceived to handle high swelling coals, crack tars, and reduce ammonia and trace metal emissions. The GPIF program will generate useful scale up data. Initially, the PyGas{trademark}-IGCC systems will be offered as modular units for the repowering markets which will reduce the financial burden on utilities in comparison to large plants. In addition, modular designs will also reduce the plant construction schedules.

Carson, R.D.; Sadowski, R.S.; Skinner, W.H. [CRS Sirrine Engineers, Inc., Greenville, SC (United States); Dixit, V.B.; Lisauskas, R.A. [Riley Stoker Corp., Worcester, MA (United States); Johnson, S.A. [PSI Technology Co., Andover, MA (United States). PowerServe Div.

1994-10-01T23:59:59.000Z

263

EMERY BIOMASS GASIFICATION POWER SYSTEM  

DOE Green Energy (OSTI)

Emery Recycling Corporation (now Emery Energy Company, LLC) evaluated the technical and economical feasibility of the Emery Biomass Gasification Power System (EBGPS). The gasifier technology is owned and being developed by Emery. The Emery Gasifier for this project was an oxygen-blown, pressurized, non-slagging gasification process that novelly integrates both fixed-bed and entrained-flow gasification processes into a single vessel. This unique internal geometry of the gasifier vessel will allow for tar and oil destruction within the gasifier. Additionally, the use of novel syngas cleaning processes using sorbents is proposed with the potential to displace traditional amine-based and other syngas cleaning processes. The work scope within this project included: one-dimensional gasifier modeling, overall plant process modeling (ASPEN), feedstock assessment, additional analyses on the proposed syngas cleaning process, plant cost estimating, and, market analysis to determine overall feasibility and applicability of the technology for further development and commercial deployment opportunities. Additionally, the project included the development of a detailed technology development roadmap necessary to commercialize the Emery Gasification technology. Process modeling was used to evaluate both combined cycle and solid oxide fuel cell power configurations. Ten (10) cases were evaluated in an ASPEN model wherein nine (9) cases were IGCC configurations with fuel-to-electricity efficiencies ranging from 38-42% and one (1) case was an IGFC solid oxide case where 53.5% overall plant efficiency was projected. The cost of electricity was determined to be very competitive at scales from 35-71 MWe. Market analysis of feedstock availability showed numerous market opportunities for commercial deployment of the technology with modular capabilities for various plant sizes based on feedstock availability and power demand.

Benjamin Phillips; Scott Hassett; Harry Gatley

2002-11-27T23:59:59.000Z

264

Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture  

Science Conference Proceedings (OSTI)

Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics® (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel Computing® toolbox from Mathworks®. In this presentation, we will share our experience in setting up parallel computing using GA in the MATLAB® environment and present the overall approach for achieving higher computational efficiency in this framework.

Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

2012-01-01T23:59:59.000Z

265

METHOD OF MEASURING THE INTEGRATED ENERGY OUTPUT OF A NEUTRONIC CHAIN REACTOR  

DOE Patents (OSTI)

A method is presented for measuring the integrated energy output of a reactor conslsting of the steps of successively irradiating calibrated thin foils of an element, such as gold, which is rendered radioactive by exposure to neutron flux for periods of time not greater than one-fifth the mean life of the induced radioactlvity and producing an indication of the radioactivity induced in each foil, each foil belng introduced into the reactor immediately upon removal of its predecessor.

Sturm, W.J.

1958-12-01T23:59:59.000Z

266

Improving process performances in coal gasification for power and synfuel production  

Science Conference Proceedings (OSTI)

This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana [University of Padova, Milan (Italy). Italy and Foster Wheeler Italiana Spa

2008-11-15T23:59:59.000Z

267

Dual Fluidized Bed Biomass Gasification  

DOE Green Energy (OSTI)

The dual fluidized bed reactor is a recirculating system in which one half of the unit operates as a steam pyrolysis device for biomass. The pyrolysis occurs by introducing biomass and steam to a hot fluidized bed of inert material such as coarse sand. Syngas is produced during the pyrolysis and exits the top of the reactor with the steam. A crossover arm, fed by gravity, moves sand and char from the pyrolyzer to the second fluidized bed. This sand bed uses blown air to combust the char. The exit stream from this side of the reactor is carbon dioxide, water and ash. There is a second gravity fed crossover arm to return sand to the pyrolysis side. The recirculating action of the sand and the char is the key to the operation of the dual fluidized bed reactor. The objective of the project was to design and construct a dual fluidized bed prototype reactor from literature information and in discussion with established experts in the field. That would be appropriate in scale and operation to measure the relative performance of the gasification of biomass and low ranked coals to produce a high quality synthesis gas with no dilution from nitrogen or combustion products.

None

2005-09-30T23:59:59.000Z

268

NETL: Gasification Systems Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Shelf Shelf Gasification Systems Reference Shelf TABLE OF CONTENTS Brochures Conferences and Workshops Gasification Systems Projects National Map Gasification Systems Projects and Performers Gasification Systems Project Portfolio Gasifipedia Multi-phase Flow with Interphase eXchange (MFIX) Patents Program Presentations Project Information Projects Summary Table by State Solicitations Systems and Industry Analyses Studies Technical Presentations & Papers Technology Readiness Assessment (Comprehensive Report | Overview Report) Video, Images & Photos Gasification Plant Databases CD Icon Request Gasification Technologies Information on a CD. Gasification RSS Feed Subscribe to the Gasification RSS Feed to follow website updates. LinkedIn DOE Gasification Program Group Subscribe to the LinkedIn DOE Gasification Program group for more information and discussion.

269

The suitability of coal gasification in India's energy sector  

E-Print Network (OSTI)

Integrated Gasification Combined Cycle (IGCC), an advanced coal-based power generation technology, may be an important technology to help India meet its future power needs. It has the potential to provide higher generating ...

Simpson, Lori Allison

2006-01-01T23:59:59.000Z

270

NETL: Gasification Systems - Liquid Carbon Dioxide/Coal Slurry...  

NLE Websites -- All DOE Office Websites (Extended Search)

and storage (CCS) for future coal-based power plants, and in a CCS integrated gasification plant, relatively pure, high pressure CO2 stream(s) will be available within the...

271

Light Water Reactor Sustainability Program Integrated Program Plan  

SciTech Connect

Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline—even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy’s Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration’s energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans.

Kathryn McCarthy; Jeremy Busby; Bruce Hallbert; Shannon Bragg-Sitton; Curtis Smith; Cathy Barnard

2013-04-01T23:59:59.000Z

272

Light Water Reactor Sustainability Program Integrated Program Plan  

Science Conference Proceedings (OSTI)

Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline - even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy's Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration's energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program's plans.

George Griffith; Robert Youngblood; Jeremy Busby; Bruce Hallbert; Cathy Barnard; Kathryn McCarthy

2012-01-01T23:59:59.000Z

273

The Tampa Electric Integrated Gasification  

E-Print Network (OSTI)

A report on a project conducted jointly under a cooperative agreement between: The U.S. Department of Energy and Tampa Electric CompanyCover image: The Polk Power Plant site as seen from across the lake in early evening. Photography

An Update; Power Plant Description

2000-01-01T23:59:59.000Z

274

A big leap forward for biomass gasification  

Science Conference Proceedings (OSTI)

This article describes the McNeil Generating Station in Vermont, the first industrial scale-up of Battelle Columbus Laboratory`s biomass gasification process. The plant is part of a major US DOE initiative to demonstrate gasification of renewable biomass for electricity production. The project will integrate the Battelle high-through-put gasifier with a high-effiency gas turbine. The history of the project is described, along with an overview of the technology and the interest and resources available in Vermont that will help insure a successful project.

Moon, S.

1995-12-31T23:59:59.000Z

275

Generation IV Reactors Integrated Materials Technology Program Plan: Focus on Very High Temperature Reactor Materials  

Science Conference Proceedings (OSTI)

Since 2002, the Department of Energy's (DOE's) Generation IV Nuclear Energy Systems (Gen IV) Program has addressed the research and development (R&D) necessary to support next-generation nuclear energy systems. The six most promising systems identified for next-generation nuclear energy are described within this roadmap. Two employ a thermal neutron spectrum with coolants and temperatures that enable hydrogen or electricity production with high efficiency (the Supercritical Water Reactor-SCWR and the Very High Temperature Reactor-VHTR). Three employ a fast neutron spectrum to enable more effective management of actinides through recycling of most components in the discharged fuel (the Gas-cooled Fast Reactor-GFR, the Lead-cooled Fast Reactor-LFR, and the Sodium-cooled Fast Reactor-SFR). The Molten Salt Reactor (MSR) employs a circulating liquid fuel mixture that offers considerable flexibility for recycling actinides and may provide an alternative to accelerator-driven systems. At the inception of DOE's Gen IV program, it was decided to significantly pursue five of the six concepts identified in the Gen IV roadmap to determine which of them was most appropriate to meet the needs of future U.S. nuclear power generation. In particular, evaluation of the highly efficient thermal SCWR and VHTR reactors was initiated primarily for energy production, and evaluation of the three fast reactor concepts, SFR, LFR, and GFR, was begun to assess viability for both energy production and their potential contribution to closing the fuel cycle. Within the Gen IV Program itself, only the VHTR class of reactors was selected for continued development. Hence, this document will address the multiple activities under the Gen IV program that contribute to the development of the VHTR. A few major technologies have been recognized by DOE as necessary to enable the deployment of the next generation of advanced nuclear reactors, including the development and qualification of the structural materials needed to ensure their safe and reliable operation. The focus of this document will be the overall range of DOE's structural materials research activities being conducted to support VHTR development. By far, the largest portion of material's R&D supporting VHTR development is that being performed directly as part of the Next-Generation Nuclear Plant (NGNP) Project. Supplementary VHTR materials R&D being performed in the DOE program, including university and international research programs and that being performed under direct contracts with the American Society for Mechanical Engineers (ASME) Boiler and Pressure Vessel Code, will also be described. Specific areas of high-priority materials research that will be needed to deploy the NGNP and provide a basis for subsequent VHTRs are described, including the following: (1) Graphite: (a) Extensive unirradiated materials characterization and assessment of irradiation effects on properties must be performed to qualify new grades of graphite for nuclear service, including thermo-physical and mechanical properties and their changes, statistical variations from billot-to-billot and lot-to-lot, creep, and especially, irradiation creep. (b) Predictive models, as well as codification of the requirements and design methods for graphite core supports, must be developed to provide a basis for licensing. (2) Ceramics: Both fibrous and load-bearing ceramics must be qualified for environmental and radiation service as insulating materials. (3) Ceramic Composites: Carbon-carbon and SiC-SiC composites must be qualified for specialized usage in selected high-temperature components, such as core stabilizers, control rods, and insulating covers and ducting. This will require development of component-specific designs and fabrication processes, materials characterization, assessment of environmental and irradiation effects, and establishment of codes and standards for materials testing and design requirements. (4) Pressure Vessel Steels: (a) Qualification of short-term, high-temperature properties of light water rea

Corwin, William R [ORNL; Burchell, Timothy D [ORNL; Katoh, Yutai [ORNL; McGreevy, Timothy E [ORNL; Nanstad, Randy K [ORNL; Ren, Weiju [ORNL; Snead, Lance Lewis [ORNL; Wilson, Dane F [ORNL

2008-08-01T23:59:59.000Z

276

NETL: Gasification Systems - Gasifier Optimization  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifier Opt & Plant Supporting Systems Gasifier Opt & Plant Supporting Systems Gasification Systems Gasifier Optimization and Plant Supporting Systems The gasifier is the core system component in the gasification process. It determines both the primary requirements for raw material inputs and the product gas composition. The gasifier is generally a high temperature/pressure vessel where oxygen (or air) and steam are directly contacted with a fuel, such as coal, causing a series of chemical reactions to occur that result in production of a fuel gas. This fuel gas (also referred to either as synthesis gas or syngas) consists primarily of hydrogen, carbon monoxide, and carbon dioxide. Minor constituents present in the feedstock are converted to such products as hydrogen sulfide, ammonia, and ash/slag (mineral residues from coal). These products can be separated and captured for use or safe disposal. After cleaning to remove contaminants, the syngas consists mainly of carbon monoxide and hydrogen. According to the Department of Energy's vision for coal gasification, at this point steam may be added and the syngas sent through a water-gas shift (WGS) reactor to convert the carbon monoxide to nothing but carbon dioxide and additional hydrogen. After a gas separation process, the carbon dioxide is ready for utilization (such as for Enhanced Oil Recovery) or safe storage, and the hydrogen can be fired in a gas-turbine/steam-turbine generator set to produce electricity with stack emissions containing no greenhouse gases. Alternately, syngas or hydrogen can be used to produce highly-valued fuels and chemicals. Co-production of combinations of these products and electricity is also possible.

277

Gasification Â… Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Clearwater Clean Coal Conference, Clearwater, Florida, June 5 to 9, 2011 Clearwater Clean Coal Conference, Clearwater, Florida, June 5 to 9, 2011 Gasification Technologies Advances for Future Energy Plants Jenny B. Tennant Technology Manager - Gasification 2 Gasification Program Goal "Federal support of scientific R&D is critical to our economic competitiveness" Dr. Steven Chu, Secretary of Energy November 2010 The goal of the Gasification Program is to reduce the cost of electricity, while increasing power plant availability and efficiency, and maintaining the highest environmental standards 3 Oxygen Membrane - APCI - 25% capital cost reduction - 5.0% COE reduction Warm Gas Cleaning - RTI in combination with H 2 /CO 2 Membrane - Eltron - 2.9 % pt efficiency increase - 12% COE decrease Oxygen CO 2 H 2 rich stream Water Gas Shift*

278

NETL: Gasification Systems - Solicitations  

NLE Websites -- All DOE Office Websites (Extended Search)

Shelf > Solicitations Shelf > Solicitations Gasification Systems Solicitations All NETL Solicitations / Funding Opportunity Announcements (FOA) Gasification RSS Feed NETL RSS Feeds: List of available NETL RSS feeds. Business & Solicitations RSS: Subscribe to this to be notified of all NETL solicitations or FOA postings. Gasification RSS: Subscribe to this to be notified of Gasification news, solicitations and FOA postings. Business Alert Notification System Official notification is available through the Business Alert Notification System. *These notifications are provided as a courtesy and there may be a delay between the opportunity announcement and the arrival of the alert. SOLICITATION TITLE / AWARDS ANNOUNCEMENT PROJECT PAGE(S) 12.11.13: Fossil Energy's Request for Information DE-FOA-0001054; titled "Novel Crosscutting Research and Development to Support Advanced Energy Systems." Application due date is January 15, 2014. Applications and/or instructions can be found with this Funding Opportunity Announcement on FedConnect.

279

Gasification Â… Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

th th Annual International Colloquium on Environmentally Preferred Advanced Power Generation, Costa Mesa, CA, February 7, 2012 An Overview of U.S. DOE's Gasification Systems Program Jenny B. Tennant Technology Manager - Gasification 2 Gasification Program Goal "Federal support of scientific R&D is critical to our economic competitiveness" Dr. Steven Chu, Secretary of Energy November 2010 The goal of the Gasification Program is to reduce the cost of electricity, while increasing power plant availability and efficiency, and maintaining the highest environmental standards 3 U.S. Coal Resources Low rank: lignite and sub-bituminous coal - About 50% of the U.S. coal reserves - Nearly 50% of U.S. coal production - Lower sulfur Bituminous coal

280

Advanced gasification projects. [Support research needs; contains list of advanced gasification projects supported by US DOE  

Science Conference Proceedings (OSTI)

An analysis of the needs for coal gasification reveals the following principal categories of information gaps that can be filled by programs already in progress or those readily initiated. The gaps are technology base needs required for successful application of both currently available and advanced gasification processes. The need areas are classified as follows: Reactor design/performance, gas cleaning/cooling separation, acid-gas removal/gas shift/gas conversion, wastewater treatment, and general data base on both state-of-the-art and advanced technologies. During the future operating and optimization phases of most of the coal gasification projects, when additional troubles will surface, the technical support program described herein will have provided the additional data base needed to correct deficiencies and/or to advance the state-of-the-art. The report describes US DOE supported projects in this area: brief description, title, contractor, objective, accomplishments, current work and possible application.

Not Available

1982-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Solar test of an integrated sodium reflux heat pipe receiver/reactor for thermochemical energy transport  

DOE Green Energy (OSTI)

A chemical reactor for carbon dioxide reforming of methane was integrated into a sodium reflux heat pipe receiver and tested in the solar furnace of the Weizmann Institute of Science, Rehovot, Israel. The receiver/reactor was a heat pipe with seven tubes inside an evacuated metal box containing sodium. The catalyst, 0.5 wt% Rh on alumina, filled two of the tubes with the front surface of the box serving as the solar absorber. In operation, concentrated sunlight heated the front plate and vaporized sodium from a wire mesh wick attached to other side. Sodium vapor condensed on the reactor tubes, releasing latent heat and returning to the wick by gravity. The receiver system performed satisfactorily in many tests under varying flow conditions. The maximum power absorbed was 7.5 kW at temperatures above 800C. The feasibility of operating a heat pipe receiver/reactor under solar conditions was proven, and the advantages of reflux devices confirmed.

Diver, R.B.; Fish, J.D. (Sandia National Labs., Albuquerque, NM (United States)); Levitan, R.; Levy, M.; Meirovitch, E.; Rosin, H. (Weizmann Inst. of Science, Rehovot (Israel)); Paripatyadar, S.A.; Richardson, J.T. (Univ. of Houston, TX (United States))

1992-01-01T23:59:59.000Z

282

Transuranic material recovery in the Integral Fast Reactor fuel cycle demonstration  

SciTech Connect

The Integral Fast Reactor is an innovative liquid metal reactor concept that is being developed by Argonne National Laboratory. It takes advantage of the properties of metallic fuel and liquid metal cooling to offer significant improvements in reactor safety, operation, fuel cycle economics, environmental protection, and safeguards. The plans for demonstrating the IFR fuel cycle, including its waste processing options, by processing irradiated fuel from the Experimental Breeder Reactor-II fuel in its associated Fuel Cycle Facility have been developed for the first refining series. This series has been designed to provide the data needed for the further development of the IFR program. An important piece of the data needed is the recovery of TRU material during the reprocessing and waste operations.

Benedict, R.W.; Goff, K.M.

1993-01-01T23:59:59.000Z

283

White Paper on Reactor Vessel Integrity Requirements for Level A and B Conditions  

Science Conference Proceedings (OSTI)

The ASME Section XI Task Group recommends that the Reactor Vessel Integrity Requirements of the ASME code be updated in several areas to reflect current technology. This report reviews current regulations to identify areas of conservatism and potential nonconservatism and to provide recommendations for future code improvements.

1993-03-09T23:59:59.000Z

284

Progress and status of the Integral Fast Reactor (IFR) fuel cycle development  

Science Conference Proceedings (OSTI)

The Integral Fast Reactor (IFR) fuel cycle holds promise for substantial improvements in economics, diversion-resistance, and waste management. This paper discusses technical features of the IFR fuel cycle, its technical progress, the development status, and the future plans and directions. 10 refs.

Till, C.E.; Chang, Y.I.

1991-01-01T23:59:59.000Z

285

The integral fast reactor (IFR) concept: Physics of operation and safety  

Science Conference Proceedings (OSTI)

The IFR concept employs a pool layout, a U/Pu/Zr metal alloy fuel and a closed fuel cycle based on pyrometallurgical reprocessing and injection casting refabrication. The reactor physics issues of designing for inherent safety and for a closed fissile self-sufficient integral fuel cycle with uranium startup and potential actinide transmutation are discussed.

Wade, D.C.; Chang, Y.I.

1987-01-01T23:59:59.000Z

286

Coal gasification for power generation. 2nd ed.  

SciTech Connect

The report gives an overview of the opportunities for coal gasification in the power generation industry. It provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered in the report include: An overview of coal generation including its history, the current market environment, and the status of coal gasification; A description of gasification technology including processes and systems; An analysis of the key business factors that are driving increased interest in coal gasification; An analysis of the barriers that are hindering the implementation of coal gasification projects; A discussion of Integrated Gasification Combined Cycle (IGCC) technology; An evaluation of IGCC versus other generation technologies; A discussion of IGCC project development options; A discussion of the key government initiatives supporting IGCC development; Profiles of the key gasification technology companies participating in the IGCC market; and A description of existing and planned coal IGCC projects.

2006-10-15T23:59:59.000Z

287

Biomass Anaerobic Digestion Facilities and Biomass Gasification...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Biomass Anaerobic Digestion Facilities and Biomass Gasification Facilities (Indiana) Biomass Anaerobic Digestion Facilities and Biomass Gasification Facilities (Indiana)...

288

NETL: Gasification Systems - Technical Presentations & Papers  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Reference Shelf - Technical Presentations & Papers Public presentations and papers supported by DOENETL Gasification Systems Program. Presentations and...

289

Actinide recycle potential in the IFR (Integral Fast Reactor)  

SciTech Connect

Rising concern about the greenhouse effect reinforces the need to reexamine the question of a next-generation reactor concept that can contribute significantly toward substitution for fossil-based energy generation. Even with only the nuclear capacity on-line today, world-wide reasonably assured uranium resources would last for only about 50 years. If nuclear is to make a significant contribution, breeding is a fundamental requirement. Uranium resources can then be extended by two orders of magnitude, making nuclear essentially a renewable energy source. The key technical elements of the IFR concept are metallic fuel and fuel cycle technology based on pyroprocessing. Pyroprocessing is radically different from the conventional PUREX reprocessing developed for the LWR oxide fuel. Chemical feasibility of pyroprocessing has been demonstrated. The next major step in the IFR development program will be the full-scale pyroprocessing demonstration to be carried out in conjunction with EBR-II. IFR fuel cycle closure based on pyroprocessing can also have a dramatic impact on the waste management options, and in particular on the actinide recycling. 6 figs.

Chang, Y.I.

1989-01-01T23:59:59.000Z

290

Integrated reactor-containment hyperbolic-cooling-tower system  

Science Conference Proceedings (OSTI)

A preliminary feasibility analysis has been conducted to evaluate placing a nuclear reactor containment building inside a large hyperbolic cooling tower, a concept previously suggested for fossil-fired units but for reasons other than those that motivate this evaluation. The geometry of the design, the amount of water available, and the shielding provided by the cooling tower are beneficial to the safety characteristics of the containment under accident conditions. Three means of decay heat management are employed: an initial water spray on the containment exterior, long-term air convection on side of the containment, and creation of a water pool inside the containment. A continuously spraying water tank on top of the containment allows for a completely passive decay heat removal system. An annular air chimney around the containment is effective in long-term removal of {approximately} 1O MW (thermal) through air convection. Five percent of the water inventory in the cooling-tower pond surrounding the containment is sufficient to flood the containment interior to a depth of 14.6 ft, thereby providing an internal containment heat sink. The packing and the height of the tower provide major scrubbing and dispersing sources for any uncontrolled radioactive leak. The cooling tower veil also protects the containment from external events such as lane crashes.

Patel, A.R.; Todreas, N.E.; Driscoll, M.J. [Massachusetts Institute of Technology, Cambridge, MA (United States)

1994-12-31T23:59:59.000Z

291

Gasification characteristics of eastern oil shale  

DOE Green Energy (OSTI)

The Institute of Gas Technology (IGT) is evaluating the gasification characteristics of Eastern oil shales as a part of a cooperative agreement between the US Department of Energy and HYCRUDE Corporation to expand the data base on moving-bed hydroretorting of Eastern oil shales. Gasification of shale fines will improve the overall resource utilization by producing synthesis gas or hydrogen needed for the hydroretorting of oil shale and the upgrading of shale oil. Gasification characteristics of an Indiana New Albany oil shale have been determined over temperature and pressure ranges of 1600 to 1900/sup 0/F and 15 to 500 psig, respectively. Carbon conversion of over 95% was achieved within 30 minutes at gasification conditions of 1800/sup 0/F and 15 psig in a hydrogen/steam gas mixture for the Indiana New Albany oil shale. This paper presents the results of the tests conducted in a laboratory-scale batch reactor to obtain reaction rate data and in a continuous mini-bench-scale unit to obtain product yield data. 2 refs., 7 figs., 4 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1986-11-01T23:59:59.000Z

292

Wabash River coal gasification repowering project: Public design report  

SciTech Connect

The Wabash River Coal Gasification Repowering Project (the Project), conceived in October of 1990 and selected by the US Department of Energy as a Clean Coal IV demonstration project in September 1991, is expected to begin commercial operations in August of 1995. The Participants, Destec Energy, Inc., (Destec) of Houston, Texas and PSI Energy, Inc., (PSI) of Plainfield, Indiana, formed the Wabash River Coal Gasification Repowering Project Joint Venture (the JV) to participate in the DOE`s Clean Coal Technology (CCT) program by demonstrating the coal gasification repowering of an existing 1950`s vintage generating unit affected by the Clean Air Act Amendments (CAAA). The Participants, acting through the JV, signed the Cooperative Agreement with the DOE in July 1992. The Participants jointly developed, and separately designed, constructed, own, and will operate an integrated coal gasification combined cycle (CGCC) power plant using Destec`s coal gasification technology to repower Unit {number_sign}1 at PSI`s Wabash River Generating Station located in Terre Haute, Indiana. PSI is responsible for the new power generation facilities and modification of the existing unit, while Destec is responsible for the coal gasification plant. The Project demonstrates integration of the pre-existing steam turbine generator, auxiliaries, and coal handling facilities with a new combustion turbine generator/heat recovery steam generator tandem and the coal gasification facilities.

1995-07-01T23:59:59.000Z

293

Underground coal gasification: a brief review of current status  

SciTech Connect

Coal gasification is a promising option for the future use of coal. Similarly to gasification in industrial reactors, underground coal gasification (UCG) produces syngas, which can be used for power generation or for the production of liquid hydrocarbon fuels and other valuable chemical products. As compared with conventional mining and surface gasification, UCG promises lower capital/operating costs and also has other advantages, such as no human labor underground. In addition, UCG has the potential to be linked with carbon capture and sequestration. The increasing demand for energy, depletion of oil and gas resources, and threat of global climate change lead to growing interest in UCG throughout the world. In this article, we review the current status of this technology, focusing on recent developments in various countries.

Shafirovich, E.; Varma, A. [Purdue University, West Lafayette, IN (United States). School of Chemical Engineering

2009-09-15T23:59:59.000Z

294

Dynamic Complexity Study of Nuclear Reactor and Process Heat Application Integration  

SciTech Connect

Abstract This paper describes the key obstacles and challenges facing the integration of nuclear reactors with process heat applications as they relate to dynamic issues. The paper also presents capabilities of current modeling and analysis tools available to investigate these issues. A pragmatic approach to an analysis is developed with the ultimate objective of improving the viability of nuclear energy as a heat source for process industries. The extension of nuclear energy to process heat industries would improve energy security and aid in reduction of carbon emissions by reducing demands for foreign derived fossil fuels. The paper begins with an overview of nuclear reactors and process application for potential use in an integrated system. Reactors are evaluated against specific characteristics that determine their compatibility with process applications such as heat outlet temperature. The reactor system categories include light water, heavy water, small to medium, near term high-temperature, and far term high temperature reactors. Low temperature process systems include desalination, district heating, and tar sands and shale oil recovery. High temperature processes that support hydrogen production include steam reforming, steam cracking, hydrogen production by electrolysis, and far-term applications such as the sulfur iodine chemical process and high-temperature electrolysis. A simple static matching between complementary systems is performed; however, to gain a true appreciation for system integration complexity, time dependent dynamic analysis is required. The paper identifies critical issues arising from dynamic complexity associated with integration of systems. Operational issues include scheduling conflicts and resource allocation for heat and electricity. Additionally, economic and safety considerations that could impact the successful integration of these systems are considered. Economic issues include the cost differential arising due to an integrated system and the economic allocation of electricity and heat resources. Safety issues include changes in regulatory constraints imposed on the facilities. Modeling and analysis tools, such as System Dynamics for time dependent operational and economic issues and RELAP5 3D for chemical transient affects, are evaluated. The results of this study advance the body of knowledge toward integration of nuclear reactors and process heat applications.

J'Tia Patrice Taylor; David E. Shropshire

2009-09-01T23:59:59.000Z

295

The role of actinide burning and the Integral Fast Reactor in the future of nuclear power  

Science Conference Proceedings (OSTI)

A preliminary assessment is made of the potential role of actinide burning and the Integral Fast Reactor (IFR) in the future of nuclear power. The development of a usable actinide burning strategy could be an important factor in the acceptance and implementation of a next generation of nuclear power. First, the need for nuclear generating capacity is established through the analysis of energy and electricity demand forecasting models which cover the spectrum of bias from anti-nuclear to pro-nuclear. The analyses take into account the issues of global warming and the potential for technological advances in energy efficiency. We conclude, as do many others, that there will almost certainly be a need for substantial nuclear power capacity in the 2000--2030 time frame. We point out also that any reprocessing scheme will open up proliferation-related questions which can only be assessed in very specific contexts. The focus of this report is on the fuel cycle impacts of actinide burning. Scenarios are developed for the deployment of future nuclear generating capacity which exploit the advantages of actinide partitioning and actinide burning. Three alternative reactor designs are utilized in these future scenarios: The Light Water Reactor (LWR); the Modular Gas-Cooled Reactor (MGR); and the Integral Fast Reactor (FR). Each of these alternative reactor designs is described in some detail, with specific emphasis on their spent fuel streams and the back-end of the nuclear fuel cycle. Four separation and partitioning processes are utilized in building the future nuclear power scenarios: Thermal reactor spent fuel preprocessing to reduce the ceramic oxide spent fuel to metallic form, the conventional PUREX process, the TRUEX process, and pyrometallurgical reprocessing.

Hollaway, W.R.; Lidsky, L.M.; Miller, M.M.

1990-12-01T23:59:59.000Z

296

GASIFICATION IN THE CANADIAN OIL SANDS:  

E-Print Network (OSTI)

The Long Lake integrated bitumen and upgrading project, now under construction by OPTI Canada Inc. and Nexen Inc., is the first application of large-scale gasification in Canada. It also represents the first implementation of a gasification project in conjunction with a heavy oil recovery and upgrading project. The Canadian oil sands are a vast petroleum resource that currently produces over one million barrels per day (bpd) using proven mining and in-situ recovery technologies. Production is projected to rise to over two million bpd by the end of the decade. However the large volumes of natural gas normally needed by the bitumen recovery and upgrading facilities are a significant barrier to economic development of the resource. The Long Lake Project uses a unique combination of technologies to provide a solution to the natural gas supply and cost issue. A key component is a gasification facility using the Shell Gasification Process (SGP) which is integrated with the bitumen upgrading to convert the liquid asphaltene by-product stream into hydrogen for the secondary upgrading step and syngas fuel. An Air Liquide air separation unit (ASU) will provide

unknown authors

2004-01-01T23:59:59.000Z

297

Main features of direct cycle helium gas turbines integrated with a high temperature reactor  

SciTech Connect

From international nuclear industries fair; Basel, Switzerland (16 Oct 1972). The main features and advantages of direct cycle helium gas turbines integrated with a high temperature reactor are presented. The proposed design concept is based on a logical extension of existirg knowledge and experience on currently built gas cooled reactors and industrial gas turbines. The direct cycle gas turbine offers many advantages in the form of high reliability, safety and simplicity; it emerges as a potential competitor to the main power generation prime mover, the steam turbine. (auth)

Burylo, P.

1972-01-01T23:59:59.000Z

298

NETL: Gasification Systems - Program Presentations  

NLE Websites -- All DOE Office Websites (Extended Search)

Program Presentations Gasification Systems Reference Shelf - Program Presentations Research Efforts at the National Energy Technology Laboratory to Improve Gasifier Performance...

299

Gasification Technology Status - December 2011  

Science Conference Proceedings (OSTI)

This report addresses the worldwide market and technology status of gasification technologies. The market for gasification technologies is primarily in China, where national policy has established a major coal-to-chemicals industry and plans to add major coal-to-substitute natural gas and coal-to-liquid transportation fuels in the next five-year plan. Gasification is being deployed to a lesser extent in other Asian countries and elsewhere. Gasification technology companies have responded to this market b...

2011-12-30T23:59:59.000Z

300

Gasification Technology Status - December 2012  

Science Conference Proceedings (OSTI)

This report addresses the worldwide market and technology status of gasification technologies. The market for gasification technologies is primarily in China, where national policy has established a major coal-to-chemicals industry and plans to add major coal–to–substitute natural gas and coal–to–liquid transportation fuels in the next five-year plan. Gasification is being deployed to a lesser extent in other Asian countries and elsewhere. Gasification technology companies ...

2012-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

NETL: C&CBTL - Investigation of Coal-Biomass Catalytic Gasification Using  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed and Gasification Coal/Biomass Feed and Gasification Investigation of Coal-Biomass Catalytic Gasification Using Experiments, Reaction Kinetics and Computational Fluid Dynamics Virginia Polytechnic Institute and State University Project Number: FE0005476 Project Description The objectives of the proposed study are to obtain experimental reactor data and develop kinetic rate expressions for pyrolysis and char gasification for the coal-biomass blends under conditions free from transport limitations, to develop a detailed understanding of the effect of pyrolysis conditions on the porous char structure, to build mathematical models that combine true kinetic rate expressions with transport models for predicting gasification behavior for a broad range of pressures and temperatures, and to investigate the physical and chemical parameters that might lead to synergistic effects in coal-biomass blends gasification.

302

Benchmarking Biomass Gasification Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Biomass Gasification Technologies for Biomass Gasification Technologies for Fuels, Chemicals and Hydrogen Production Prepared for U.S. Department of Energy National Energy Technology Laboratory Prepared by Jared P. Ciferno John J. Marano June 2002 i ACKNOWLEDGEMENTS The authors would like to express their appreciation to all individuals who contributed to the successful completion of this project and the preparation of this report. This includes Dr. Phillip Goldberg of the U.S. DOE, Dr. Howard McIlvried of SAIC, and Ms. Pamela Spath of NREL who provided data used in the analysis and peer review. Financial support for this project was cost shared between the Gasification Program at the National Energy Technology Laboratory and the Biomass Power Program within the DOE's Office of Energy Efficiency and Renewable Energy.

303

Status of the Integral Fast Reactor fuel cycle demonstration and waste management practices  

SciTech Connect

Over the past few years, Argonne National Laboratory has been preparing for the demonstration of the fuel cycle for the Integral Fast Reactor (IFR), an advanced reactor concept that takes advantage of the properties of metallic fuel and liquid metal cooling to offer significant improvements in reactor safety and operations, fuel-cycle economics, environmental protection, and safeguards. The IFR fuel cycle, which will be demonstrated at Argonne-West in Idaho, employs a pyrometallurgical process using molten salts and liquid metals to recover actinides from spent fuel. The required facility modifications and process equipment for the demonstration are nearing completion. Their status and the results from initial fuel fabrication work, including the waste management aspects, are presented. Additionally, estimated compositions of the various process waste streams have been made, and characterization and treatment methods are being developed. The status of advanced waste processing equipment being designed and fabricated is described.

Benedict, R.W.; Goff, K.M.; McFarlane, H.F.

1994-07-01T23:59:59.000Z

304

Catalyzed gasification of biomass  

DOE Green Energy (OSTI)

Catalyzed biomass gasification studies are being conducted by Battelle's Pacific Northwest Laboratories. Investigations are being carried out concurrently at the bench and process development unit scales. These studies are designed to test the technical and economic feasibility of producing specific gaseous products from biomass by enhancing its reactivity and product specificity through the use of specific catalysts. The program is directed at controlling the gasification reaction through the use of specific catalytic agents to produce desired products including synthetic natural gas, ammonia synthesis gas (H/sub 2//N/sub 2/), hydrogen, or syn gas (H/sub 2//CO). Such gaseous products are currently produced in tonnage quantities from non-renewable carbonaceous resources, e.g., natural gas and petroleum. The production of high yields of these specified gases from biomass is accomplished through optimization of gasification conditions and proper choice of catalytic agents. For instance, high yields of synthetic natural gas can be attained through gasification with steam in the presence of gasification catalyst such as trona (Na/sub 2/CO/sub 3/ . NaHCO/sub 3/ . 2H/sub 2/O) and a nickel methanation catalyst. The gasification catalyst enhances the steam-biomass reaction while the methanation catalyst converts gaseous intermediates from this reaction to methane, the most thermodynamically stable hydrocarbon product. This direct conversion to synthetic natural gas represents a significant advancement in the classical approach of producing synthetic natural gas from carbonaceous substrates through several unit operations. A status report, which includes experimental data and results of the program is presented.

Sealock, L.J. Jr.; Robertus, R.J.; Mudge, L.K.; Mitchell, D.H.; Cox, J.L.

1978-06-16T23:59:59.000Z

305

Hydroxide Formation and Carbon Species Distributions During High-Temperature Kraft Black Liquor Gasification .  

E-Print Network (OSTI)

??This work focuses on high-temperature kraft black liquor gasification in the presence of H2O and CO2 in a laboratory-scale Laminar Entrained-Flow Reactor (LEFR). The effects… (more)

Dance, Michael Raymond, Jr.

2005-01-01T23:59:59.000Z

306

Simultaneous H2 purification and CO2 capture in a post-gasifier membrane reactor  

DOE Green Energy (OSTI)

NETL envisions that the gasification of carbonaceous feedstocks may be the near- to mid-term sources of hydrogen for the transition to a renewable, hydrogen-based economy. However, the environmental impacts associated with the generation and emission of greenhouses gases from the gasification process remains a substantial concern. Therefore, NETL has devoted substantial resources towards the identification of efficient hydrogen separation and carbon capture/sequestration technologies. Hydrogen membranes integrated into a water-gas shift membrane reactor have been identified as a promising means of maximizing the production of pure hydrogen while simultaneously yielding a high-pressure, concentrated CO2 containing stream ready for sequestration.

Morreale, B.D.; Howard, B.H.; Killmeyer, R.P.; Taylor, C.E.; Iyoha, O.; Ciocco, M.V.

2007-03-01T23:59:59.000Z

307

Parametric Gasification of Oak and Pine Feedstocks Using the TCPDU and Slipstream Water-Gas Shift Catalysis  

DOE Green Energy (OSTI)

With oak and pine feedstocks, the Gasification of Biomass to Hydrogen project maximizes hydrogen production using the Full Stream Reformer during water-gas shift fixed-bed reactor testing. Results indicate that higher steam-to-biomass ratio and higher thermal cracker temperature yield higher hydrogen concentration. NREL's techno-economic models and analyses indicate hydrogen production from biomass may be viable at an estimated cost of $1.77/kg (current) and $1.47/kg (advanced in 2015). To verify these estimates, NREL used the Thermochemical Process Development Unit (TCPDU), an integrated system of unit operations that investigates biomass thermochemical conversion to gaseous and liquid fuels and chemicals.

Hrdlicka, J.; Feik, C.; Carpenter, D.; Pomeroy, M.

2008-12-01T23:59:59.000Z

308

The Role of Oxygen in Coal Gasification  

E-Print Network (OSTI)

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts in the oxidant on gasifier and downstream production units also favor the use of oxygen in place of air. Factors that must be considered in selecting the optimum oxygen purity include: end use of the gasifier products, oxygen delivery pressure and the cost of capital and energy. This paper examines the major factors in oxygen purity selection for typical coal gasifiers. Examples demonstrating the effect of oxygen purity on several processes are presented: production of synthetic natural gas (SNG), integrated gasification combined-cycle (IGCC) power generation and methanol synthesis. The potential impact of a non-cryogenic air separation process currently under development is examined based on integration with a high temperature processes.

Klosek, J.; Smith, A. R.; Solomon, J.

1986-06-01T23:59:59.000Z

309

Gasification of black liquor  

DOE Patents (OSTI)

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

Kohl, A.L.

1987-07-28T23:59:59.000Z

310

Gasification of black liquor  

DOE Patents (OSTI)

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

Kohl, Arthur L. (Woodland Hills, CA)

1987-07-28T23:59:59.000Z

311

NETL: Gasification - Recovery Act: High Temperature Syngas Cleanup  

NLE Websites -- All DOE Office Websites (Extended Search)

Program Background and Project Benefits Program Background and Project Benefits Gasification is used to convert a solid feedstock, such as coal, petcoke, or biomass, into a gaseous form, referred to as synthesis gas or syngas, which is primarily hydrogen and carbon monoxide. With gasification-based technologies, pollutants can be captured and disposed of or converted to useful products. Gasification can generate clean power by adding steam to the syngas in a water-gas-shift reactor to convert the carbon monoxide to carbon dioxide (CO2) and to produce additional hydrogen. The hydrogen and CO2 are separated-the hydrogen is used to make power and the CO2 is sent to storage, converted to useful products or used for EOR. In addition to efficiently producing electric power, a wide range of transportation fuels and chemicals can be produced from the cleaned syngas, thereby providing the flexibility needed to capitalize on the changing economic market. As a result, gasification provides a flexible technology option for using domestically available resources while meeting future environmental emission standards. Polygeneration plants that produce multiple products are uniquely possible with gasification technologies. The Gasification Systems program is developing technologies in three key areas to reduce the cost and increase the efficiency of producing syngas: (1) Feed Systems, (2) Gasifier Optimization and Plant Supporting Systems, and (3) Syngas Processing Systems.

312

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

NLE Websites -- All DOE Office Websites (Extended Search)

Program Background and Project Benefits Program Background and Project Benefits Gasification is used to convert a solid feedstock, such as coal, petcoke, or biomass, into a gaseous form, referred to as synthesis gas or syngas, which is primarily hydrogen and carbon monoxide. With gasification-based technologies, pollutants can be captured and disposed of or converted to useful products. Gasification can generate clean power by adding steam to the syngas in a water-gas-shift reactor to convert the carbon monoxide to carbon dioxide (CO2) and to produce additional hydrogen. The hydrogen and CO2 are separated-the hydrogen is used to make power and the CO2 is sent to storage, converted to useful products or used for EOR. In addition to efficiently producing electric power, a wide range of transportation fuels and chemicals can be produced from the cleaned syngas, thereby providing the flexibility needed to capitalize on the changing economic market. As a result, gasification provides a flexible technology option for using domestically available resources while meeting future environmental emission standards. Polygeneration plants that produce multiple products are uniquely possible with gasification technologies. The Gasification Systems program is developing technologies in three key areas to reduce the cost and increase the efficiency of producing syngas: (1) Feed Systems, (2) Gasifier Optimization and Plant Supporting Systems, and (3) Syngas Processing Systems.

313

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect

The project, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures'', is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (GT). The aims of the project are to: identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal; evaluate various impregnation or catalyst addition methods to improve catalyst dispersion; evaluate effects of major process variables (e.g., temperature, system pressure, etc.) on coal gasification; evaluate the recovery, regeneration and recycle of the spent catalysts in a bench-scale fixed bed reactor; and conduct thorough analysis and modeling of the gasification process to provide a better understanding of the fundamental mechanisms and kinetics of the process. The eutectic catalysts increased gasification rate significantly. The methods of catalyst preparation and addition had significant effect on the catalytic activity and coal gasification. The incipient wetness method gave more uniform catalyst distribution than that of physical mixing for the soluble catalysts resulting in higher gasification rates for the incipient wetness samples. The catalytic activity increased by varying degrees with catalyst loading. The above results are especially important since the eutectic catalysts (with low melting points) yield significant gasification rates even at low temperatures. Among the ternary eutectic catalysts studied, the system 39% Li{sub 2}CO{sub 3}-38.5% Na{sub 2}CO{sub 3}-22.5% Rb{sub 2}CO{sub 3} showed the best activity and will be used for further bench scale fixed-bed gasification reactor in the next period. Based on the Clark Atlanta University studies in the previous reporting period, the project team selected the 43.5% Li{sub 2}CO{sub 3}-31.5% Na{sub 2}CO{sub 3}-25% K{sub 2}CO{sub 3} ternary eutectic and the 29% Na{sub 2}CO{sub 3}-71% K{sub 2}CO{sub 3} binary eutectic for the fixed-bed studies at UTSI during this reporting period. Temperature was found to have a significant effect on the rate of gasification of coal. The rate of gasification increased up to 1400 F. Pressure did not have much effect on the gasification rates. The catalyst loading increased the gasification rate and approached complete conversion when 10 wt% of catalyst was added to the coal. Upon further increasing the catalyst amount to 20-wt% and above, there was no significant rise in gasification rate. The rate of gasification was lower for a 2:1 steam to char molar ratio (60%) compared to gasification rates at 3.4:1 molar ratio of steam-to-char where the conversion approached 100%. The characterization results of Georgia Tech are very preliminary and inconclusive and will be made available in the next report.

Unknown

1999-04-01T23:59:59.000Z

314

Fuel Flexibility in Gasification  

DOE Green Energy (OSTI)

In order to increase efficiencies of carbonizers, operation at high pressures is needed. In addition, waste biomass fuels of opportunity can be used to offset fossil fuel use. The National Energy Technology Laboratory (NETL) Fluidized Bed Gasifier/Combustor (FBG/C) was used to gasify coal and mixtures of coal and biomass (sawdust) at 425 psig. The purpose of the testing program was to generate steady state operating data for modeling efforts of carbonizers. A test program was completed with a matrix of parameters varied one at a time in order to avoid second order interactions. Variables were: coal feed rate, pressure, and varying mixtures of sawdust and coal types. Coal types were Montana Rosebud subbituminous and Pittsburgh No. 8 bituminous. The sawdust was sanding waste from a furniture manufacturer in upstate New York. Coal was sieved from -14 to +60 mesh and sawdust was sieved to -14 mesh. The FBG/C operates at a nominal 425 psig, but pressures can be lowered. For the tests reported it was operated as a jetting, fluidized bed, ash-agglomerating gasifier. Preheated air and steam are injected into the center of the bottom along with the solid feed that is conveyed with cool air. Fairly stable reactor internal flow patterns develop and temperatures stabilize (with some fluctuations) when steady state is reached. At nominal conditions the solids residence time in the reactor is on the order of 1.5 to 2 hours, so changes in feed types can require on the order of hours to equilibrate. Changes in operating conditions (e.g. feed rate) usually require much less time. The operating periods of interest for these tests were only the steady state periods, so transient conditions were not monitored as closely. The test matrix first established a base case of operations to which single parameter changes in conditions could be compared. The base case used Montana Rosebud at a coal feed rate of 70 lbm/hr at 425 psig. The coal sawdust mixtures are reported as percent by weight coal to percent by weight sawdust. The mixtures of interest were: 65/35 subbituminous, 75/25 subbituminous, 85/15 subbituminous, and 75/25 bituminous. Steady state was achieved quickly when going from one subbituminous mixture to another, but longer when going from subbituminous to bituminous coal. The most apparent observation when comparing the base case to subbituminous coal/sawdust mixtures is that operating conditions are nearly the same. Product gas does not change much in composition and temperatures remain nearly the same. Comparisons of identical weight ratios of sawdust and subbituminous and bituminous mixtures show considerable changes in operating conditions and gas composition. The highly caking bituminous coal used in this test swelled up and became about half as dense as the comparable subbituminous coal char. Some adjustments were required in accommodating changes in solids removal during the test. Nearly all the solids in the bituminous coal sawdust were conveyed into the upper freeboard section and removed at the mid-level of the reactor. This is in marked contrast to the ash-agglomerating condition where most solids are removed at the very bottom of the gasifier. Temperatures in the bottom of the reactor during the bituminous test were very high and difficult to control. The most significant discovery of the tests was that the addition of sawdust allowed gasification of a coal type that had previously resulted in nearly instant clinkering of the gasifier. Several previous attempts at using Pittsburgh No. 8 were done only at the end of the tests when shutdown was imminent anyway. It is speculated that the fine wood dust somehow coats the pyrolyzed sticky bituminous coal particles and prevents them from agglomerating quickly. As the bituminous coal char particles swell, they are carried to the cooler upper regions of the reactor where they re-solidify. Other interesting phenomena were revealed regarding the transport (rheological) properties of the coal sawdust mixtures. The coal sawdust mixtures segregate quickly when transported. This is visi

McLendon, T. Robert; Pineault, Richard L.; Richardson, Steven W.; Rockey, John M.; Beer, Stephen K. (U.S. DOE National Energy Technology Laboratory); Lui, Alain P.; Batton, William A. (Parsons Infrastructure and Technology Group, Inc.)

2001-11-06T23:59:59.000Z

315

Coal gasification power plant and process  

DOE Patents (OSTI)

In an integrated coal gasification power plant, a humidifier is provided for transferring as vapor, from the aqueous blowdown liquid into relatively dry air, both (I) at least a portion of the water contained in the aqueous liquid and (II) at least a portion of the volatile hydrocarbons therein. The resulting humidified air is advantageously employed as at least a portion of the hot air and water vapor included in the blast gas supplied via a boost compressor to the gasifier.

Woodmansee, Donald E. (Schenectady, NY)

1979-01-01T23:59:59.000Z

316

Gasification Technology Status--December 2007  

Science Conference Proceedings (OSTI)

Over the past four years, several major power companies have been conducting detailed design studies of commercial-sized coal based Integrated Gasification Combined Cycle (IGCC) and Pulverized Coal (PC) plants. Concern over the continued availability of natural gas at competitive prices has led many power companies to seriously consider clean coal technologies as a strategic hedge against over reliance on natural gas alone to provide future power needs. This report covers the IGCC designs currently offer...

2007-12-18T23:59:59.000Z

317

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

NLE Websites -- All DOE Office Websites (Extended Search)

Presentations, Papers, and Publications Presentations, Papers, and Publications ITM Oxygen Development for Advanced Oxygen Supply (Oct 2011) Ted Foster, Air Products & Chemicals, Inc. presented at the Gasification Technologies Conference, San Francisco, CA Oct 9-12, 2011. ASU/IGCC Integration Strategies (Oct 2009), David McCarthy, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Taking the Next Step (Oct 2009), VanEric Stein, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Scaling Up a Low-Cost Oxygen Supply Technology (Oct 2006) Philip Armstrong, Air Products & Chemicals, Inc., 2006 Gasification Technologies Conference, Washington, D.C. ITM Oxygen: The New Oxygen Supply for the New IGCC Market (Oct 2005)

318

Simulated first operating campaign for the Integral Fast Reactor fuel cycle demonstration  

Science Conference Proceedings (OSTI)

This report discusses the Integral Fast Reactor (IFR) which is an innovative liquid-metal-cooled reactor concept that is being developed by Argonne National Laboratory. It takes advantage of the properties of metallic fuel and liquid-metal cooling to offer significant improvements in reactor safety, operation, fuel cycle-economics, environmental protection, and safeguards. Over the next few years, the IFR fuel cycle will be demonstrated at Argonne-West in Idaho. Spent fuel from the Experimental Breeder Reactor II (EBR-II) win be processed in its associated Fuel Cycle Facility (FCF) using a pyrochemical method that employs molten salts and liquid metals in an electrorefining operation. As part of the preparation for the fuel cycle demonstration, a computer code, PYRO, was developed at Argonne to model the electrorefining operation using thermodynamic and empirical data. This code has been used extensively to evaluate various operating strategies for the fuel cycle demonstration. The modeled results from the first operating campaign are presented. This campaign is capable of processing more than enough material to refuel completely the EBR-II core.

Goff, K.M.; Mariani, R.D.; Benedict, R.W.; Park, K.H. [Argonne National Lab., Idaho Falls, ID (United States); Ackerman, J.P. [Argonne National Lab., IL (United States)

1993-09-01T23:59:59.000Z

319

NETL: 2010 World Gasification Database Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Gasification Systems > 2010 World Gasification Database Home > Technologies > Coal & Power Systems > Gasification Systems > 2010 World Gasification Database Gasification Systems 2010 Worldwide Gasification Database Archive DOE/NETL 2010 Worldwide Gasification Database Worldwide Gasification Database Analysis The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers.

320

MSW GASIFICATION UNDERSTANDING THE CHALLENGES Stephen Goff  

E-Print Network (OSTI)

MSW GASIFICATION ­ UNDERSTANDING THE CHALLENGES Stephen Goff Jeffrey Hahn Hanwei Zhang Shashank evaluating emerging gasification technologies and is committed to identifying and developing the most high reliability. This corrosion and fouling will also exist in gasification processes

Columbia University

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

NETL: Gasifipedia - Gasification in Detail  

NLE Websites -- All DOE Office Websites (Extended Search)

Fundamentals Fundamentals Gasification is a partial oxidation process. The term partial oxidation is a relative term which simply means that less oxygen is used in gasification than would be required for combustion (i.e., burning or complete oxidation) of the same amount of fuel. Gasification typically uses only 25 to 40 percent of the theoretical oxidant (either pure oxygen or air) to generate enough heat to gasify the remaining unoxidized fuel, producing syngas. The major combustible products of gasification are carbon monoxide (CO) and hydrogen (H2), with only a minor amount of the carbon completely oxidized to carbon dioxide (CO2) and water. The heat released by partial oxidation provides most of the energy needed to break up the chemical bonds in the feedstock, to drive the other endothermic gasification reactions, and to increase the temperature of the final gasification products.

322

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network (OSTI)

OPERATION OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BEDMaterial Using Self-Sustained Hydro- Gasification." [0011]the process, using a steam hydro-gasification reactor (SHR)

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

323

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network (OSTI)

of the process, using a steam hydro-gasification reactor (simultaneously in the presence of both hydrogen and steam toundergo steam pyrolysis and hydro-gasification in a single

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

324

Catalytic Coal Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Coal Gasification Process Catalytic Coal Gasification Process for the Production of Methane-Rich Syngas Opportunity Research is active on the patent pending technology, titled "Production of Methane-Rich Syngas from Fuels Using Multi-functional Catalyst/Capture Agent." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Reducing pollution emitted by coal and waste power plants in an economically viable manner and building power plants that co-generate fuels and chemicals during times of low electricity demand are pressing goals for the energy industry. One way to achieve these goals in an economically viable manner is through the use of a catalytic gasifier that

325

Great Plains gasification project  

SciTech Connect

This paper describes organizational and research work on a coal gasification project which is based on North Dakota lignite. Many design changes have been incorporated into this plant, which is now being built after years of delay due to environmental, financial, and regulatory problems. Engineering and operational details are given for a project designed for conversion of 22,000 tons/day of liquid into fuel gas and several by products. Economic considerations are included.

Kuhn, A.K.

1982-04-01T23:59:59.000Z

326

Advanced Biomass Gasification Projects  

DOE Green Energy (OSTI)

DOE has a major initiative under way to demonstrate two high-efficiency gasification systems for converting biomass into electricity. As this fact sheet explains, the Biomass Power Program is cost-sharing two scale-up projects with industry in Hawaii and Vermont that, if successful, will provide substantial market pull for U.S. biomass technologies, and provide a significant market edge over competing foreign technologies.

Not Available

1997-08-01T23:59:59.000Z

327

Gasification Research BIOENERGY PROGRAM  

E-Print Network (OSTI)

,switchgrass,high-tonnagesorghum,poultrylitter,andricehulls.Theresearch- ers can gasify various feedstocks, one after another, without shutting down the system. Research@tamu.edu Skid-mounted gasifier: 1.8 tons-per-day pilot unit Gasification of cotton gin trash The new Texas A&M University fluidized bed gasifier mounted on a trailer Synthesis gas Dry Mole % Hydrogen 9.8% Methane 2

328

Catalyzed steam gasification of biomass. Phase II. Final research report  

DOE Green Energy (OSTI)

The Wright-Malta gasification process is characterized by low-temperature, catalyzed steam gasification in a pressurized rotary kiln. Fresh biomass moves slowly and continuously through the kiln, where it is gradually heated to around 1200/sup 0/F in an atmosphere of 300 psi steam. During its traverse, pyrolysis and reaction of steam with the nascent char convert nearly all of the organic solids to the gaseous phase. The volatile pyrolysis products pass through the kiln co-currently with the solids and are similarly cracked and steam-reformed within the kiln to fixed gases. Heat for the gasification process is provided by sensible heat recovered from the product gas and the wood decomposition exotherm, making the process inherently very energy-efficient. This report summarizes the work done during the experimental, laboratory-scale phase of development of the W-M biomass gasification process. Two bench-scale experimental gasifiers were constructed and tested: the ''minikiln'', a batch-feed, rotating autoclave; and the ''biogasser'', a stationary, continuous-feed, tubular reactor with zone heating and auger transport. Studies were carried out in these reactors to determine the extent of conversion of biomass solids to gas, and the makeup of the product gas, over a wide range of process conditions. The process variables that were investigated included reactor pressure and temperature, catalyst type and concentration, moisture content and type of biomass feed.

Hooverman, R.H.

1979-05-01T23:59:59.000Z

329

Gasification, polygeneration capture interest of refiners  

SciTech Connect

Integrated gasification combined cycle (IGCC) plants are moving into the mainstream of international refining. Such plants can turn refinery dregs into the whitest of all products--sparkling electricity--plus hydrogen and synthesis gas. Hydrogen is an indispensable element for cleaning up and improving modern fuels, while syngas is the feedstock for important finished petrochemicals and intermediaries. The status and potential of gasification technologies and projects were covered in a 3 day conference early in October in San Francisco. What made this conference different from others on the subject in the past was recognition that oil and natural gas producers and the international refining industry are becoming major power producers without government subsidies. Such projects can pass the scrutiny of lenders and the test of commerciality. They are not targeted simply for electricity, but also for production of hydrogen, steam, and petrochemical feedstock. The process objective for projects now far exceeds simple cogeneration. It`s now trigeneration, even polygeneration.

Aalund, L.R.

1996-12-09T23:59:59.000Z

330

NETL: Gasification Systems Conferences and Workshops  

NLE Websites -- All DOE Office Websites (Extended Search)

ConferencesWorkshops Gasification Systems Reference Shelf - Conferences and Workshops Click here for a listing of upcoming Gasification Conferences and Workshops. The following...

331

Conceptual design report -- Gasification Product Improvement Facility (GPIF)  

SciTech Connect

The problems heretofore with coal gasification and IGCC concepts have been their high cost and historical poor performance of fixed-bed gasifiers, particularly on caking coals. The Gasification Product Improvement Facility (GPIF) project is being developed to solve these problems through the development of a novel coal gasification invention which incorporates pyrolysis (carbonization) with gasification (fixed-bed). It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration caused in the conventional process of gradually heating coal through the 400 F to 900 F range. In so doing, the coal is rapidly heated sufficiently such that the coal tar exists in gaseous form rather than as a liquid. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can become chemically bound to aluminosilicates in (or added to) the ash. To reduce NH{sub 3} and HCN from fuel born nitrogen, steam injection is minimized, and residual nitrogen compounds are partially chemically reduced in the cracking stage in the upper gasifier region. Assuming testing confirms successful deployment of all these integrated processes, future IGCC applications will be much simplified, require significantly less mechanical components, and will likely achieve the $1,000/kWe commercialized system cost goal of the GPIF project. This report describes the process and its operation, design of the plant and equipment, site requirements, and the cost and schedule. 23 refs., 45 figs., 23 tabs.

Sadowski, R.S.; Skinner, W.H.; House, L.S.; Duck, R.R. [CRS Sirrine Engineers, Inc., Greenville, SC (United States); Lisauskas, R.A.; Dixit, V.J. [Riley Stoker Corp., Worcester, MA (United States); Morgan, M.E.; Johnson, S.A. [PSI Technology Co., Andover, MA (United States). PowerServe Div.; Boni, A.A. [PSI-Environmental Instruments Corp., Andover, MA (United States)

1994-09-01T23:59:59.000Z

332

Reactor pressure vessel integrity research at the Oak Ridge National Laboratory  

Science Conference Proceedings (OSTI)

Maintaining the integrity of the reactor pressure vessel (RPV) in a light-water-cooled nuclear power plant is crucial in preventing and controlling severe accidents that have the potential for major contamination release. The RPV is the only key safety-related component of the plant for which a duplicate or redundant backup system does not exist. It is therefore imperative to understand and be able to predict the integrity inherent in the RPV. For this reason, the U.S. Nuclear Regulatory Commission has established the related research programs at ORNL described herein to provide for the development and confirmation of the methods used for: (1) establishing the irradiation exposure conditions within the RPV in the Embrittlement Data Base and Dosimetry Evaluation Program, (2) assessing the effects of irradiation on the RPV materials in the Heavy-Section Steel Irradiation Program, and (3) developing overall structural and fracture analyses of RPVs in the Heavy-Section Steel Technology Program.

Corwin, W.R.; Pennell, W.E.; Pace, J.V.

1995-12-31T23:59:59.000Z

333

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect

This progress report on the Department of Energy project DE-FG-97FT97263 entitled, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures'', covers the period April-September 1998. The specific aims of the project for this period were to identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal, evaluate various impregnation or catalyst addition methods to improve catalyst dispersion, and evaluate gasification performance in a bench-scale fixed bed reactor. The project is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (Georgia Tech) with CAU as the prime contractor. Several single salt catalysts and binary and ternary eutectic catalysts were investigated at Clark Atlanta University. Physical mixing and incipient wetness methods were investigated as catalyst addition techniques. Gasification was carried out using TGA at CAU and UTSI and with a fixed-bed reactor at UTSI. The results showed better gasification activity in the presence of the catalysts tested. The eutectic salt studies showed clear agreement between the melting points of the prepared eutectics and reported literature values. The order of catalytic activity observed was ternary > binary > single salt. With the soluble single salt catalysts, the incipient wetness method was found to give better results than physical mixing technique. Also, catalyst preparation conditions such as catalyst loading, drying time and temperature were found to influence the gasification rate. Based on the Clark Atlanta University studies on Task 1, the project team selected the 43.5%Li{sub 2}CO{sub 3}-31.5%Na{sub 2}CO{sub 3}-25%K{sub 2}CO{sub 3} ternary eutectic and the 29%Na{sub 2}CO{sub 3}-71%K{sub 2}CO{sub 3} and 2.3% KNO{sub 3}-97.7%K{sub 2}CO{sub 3} binary eutectic for the fixed bed studies at UTSI. The eutectic salts were found to be highly insoluble in aqueous medium. As a result the technique of adding the eutectic to the raw coal was found to be better than using wet methods. Also, addition of the catalyst to the raw coal appeared to give better gasification results than addition to pyrolyzed coal. In addition, eutectic catalysts added to the coal yielded better gasification rates than rates obtained by mixing the individual salts in the eutectic ratio with the coal. These results, especially with the eutectic catalysts are very significant since the use of the low melting eutectics will reduce the severity of gasification processes.

NONE

2000-04-01T23:59:59.000Z

334

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

Science Conference Proceedings (OSTI)

This progress report on the Department of Energy project DE-FG-97FT97263 entitled, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures,'' covers the period April-September 1998. The specific aims of the project for this period were to identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal, evaluate various impregnation or catalyst addition methods to improve catalyst dispersion, and evaluate gasification performance in a bench-scale fixed bed reactor. The project is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (Georgia Tech) with CAU as the prime contractor. Several single salt catalysts and binary and ternary eutectic catalysts were investigated at Clark Atlanta University. Physical mixing and incipient wetness methods were investigated as catalyst addition techniques. Gasification was carried out using TGA at CAU and UTSI and with a fixed-bed reactor at UTSI. The results showed better gasification activity in the presence of the catalysts tested. The eutectic salt studies showed clear agreement between the melting points of the prepared eutectics and reported literature values. The order of catalytic activity observed was ternary > binary > single salt. With the soluble single salt catalysts, the incipient wetness method was found to give better results than physical mixing technique. Also, catalyst preparation conditions such as catalyst loading, drying time and temperature were found to influence the gasification rate. Based on the Clark Atlanta University studies on Task 1, the project team selected the 43.5%Li{sub 2}CO{sub 3}-31.5%Na{sub 2}CO{sub 3}-25%K{sub 2}CO{sub 3} ternary eutectic and the 29%Na{sub 2}CO{sub 3}-71%K{sub 2}CO{sub 3} and 2.3%KNO{sub 3}-97.7%K{sub 2}CO{sub 3} binary eutectic for the fixed bed studies at UTSI. The eutectic salts were found to be highly insoluble in aqueous medium. As a result the technique of adding the eutectic to the raw coal was found to be better than using wet methods. Also, addition of the catalyst to the raw coal appeared to give better gasification results than addition to pyrolyzed coal. In addition, eutectic catalysts added to the coal yielded better gasification rates than rates obtained by mixing the individual salts in the eutectic ratio with the coal. These results, especially with the eutectic catalysts are very significant since the use of the low melting eutectics will reduce the severity of gasification processes.

NONE

1998-10-01T23:59:59.000Z

335

A summary report on combustion and gasification processes  

DOE Green Energy (OSTI)

Six poster papers regarding combustion and gasification were reviewed. These six papers address various different technology subjects: (1) underground coal gasification modeling, (2) wood gasification kinetics, (3) heat transfer surface pretreatment by iron implantation, (4) coal water slurry stabilization technology, (5) coal log pipeline technology, and (6) nuclear reactor decontamination. Summaries and comments of the following papers are presented: Characterization of Flow and Chemical Processes in an Underground Gasifier at Great Depth; Model for Reaction Kinetics in Pyrolysis of Wood; Development of a Stainless Steel Heat Transfer Surface with Low Scaling Tendency; Storage and Transportation of Coal Water Mixtures; Coal Log Pipeline: Development Status of the First Commercial System; and Decontamination of Nuclear Systems at the Grand Gulf Nuclear Station.

Rath, L.K.; Lee, G.T.

1996-08-01T23:59:59.000Z

336

Run - Beyond - Cladding - Breach (RBCB) test results for the Integral Fast Reactor (IFR) metallic fuels program  

Science Conference Proceedings (OSTI)

In 1984 Argonne National Laboratory (ANL) began an aggressive program of research and development based on the concept of a closed system for fast-reactor power generation and on-site fuel reprocessing, exclusively designed around the use of metallic fuel. This is the Integral Fast Reactor (IFR). Although the Experimental Breeder Reactor-II (EBR-II) has used metallic fuel since its creation 25 yeas ago, in 1985 ANL began a study of the characteristics and behavior of an advanced-design metallic fuel based on uranium-zirconium (U-Zr) and uranium-plutonium-zirconium (U-Pu-Zr) alloys. During the past five years several areas were addressed concerning the performance of this fuel system. In all instances of testing the metallic fuel has demonstrated its ability to perform reliably to high burnups under varying design conditions. This paper will present one area of testing which concerns the fuel system's performance under breach conditions. It is the purpose of this paper to document the observed post-breach behavior of this advanced-design metallic fuel. 2 figs., 1 tab.

Batte, G.L. (Argonne National Lab., Idaho Falls, ID (USA)); Hoffman, G.L. (Argonne National Lab., IL (USA))

1990-01-01T23:59:59.000Z

337

NETL: Gasification - Request Gasification Systems Information on a CD  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Gasification Systems Request Gasification Systems Information on a CD Please fill in the form below to receive the CDs of your choice. * Denotes required field Requestor Contact Information Requested By (Agency/Company): First Name: * Last Name: * Address: * PO Box: City: * State: * Zip: * Country: Email: * Phone: CD Request Select CD(s):* Gasification Systems Project Portfolio Gasification Technologies Training Course Special Instructions: Submit Request Reset Contacts Program Contact: Jenny Tennant (304) 285-4830 jenny.tennant@netl.doe.gov Close Contacts Disclaimer Disclaimer of Liability: This system is made available by an agency of the United States Government. Neither the United States Government, the Department of Energy, the National Energy Technology Laboratory, nor any of

338

Gasification Plant Cost and Performance Optimization  

DOE Green Energy (OSTI)

As part of an ongoing effort of the U.S. Department of Energy (DOE) to investigate the feasibility of gasification on a broader level, Nexant, Inc. was contracted to perform a comprehensive study to provide a set of gasification alternatives for consideration by the DOE. Nexant completed the first two tasks (Tasks 1 and 2) of the ''Gasification Plant Cost and Performance Optimization Study'' for the DOE's National Energy Technology Laboratory (NETL) in 2003. These tasks evaluated the use of the E-GAS{trademark} gasification technology (now owned by ConocoPhillips) for the production of power either alone or with polygeneration of industrial grade steam, fuel gas, hydrocarbon liquids, or hydrogen. NETL expanded this effort in Task 3 to evaluate Gas Technology Institute's (GTI) fluidized bed U-GAS{reg_sign} gasifier. The Task 3 study had three main objectives. The first was to examine the application of the gasifier at an industrial application in upstate New York using a Southeastern Ohio coal. The second was to investigate the GTI gasifier in a stand-alone lignite-fueled IGCC power plant application, sited in North Dakota. The final goal was to train NETL personnel in the methods of process design and systems analysis. These objectives were divided into five subtasks. Subtasks 3.2 through 3.4 covered the technical analyses for the different design cases. Subtask 3.1 covered management activities, and Subtask 3.5 covered reporting. Conceptual designs were developed for several coal gasification facilities based on the fluidized bed U-GAS{reg_sign} gasifier. Subtask 3.2 developed two base case designs for industrial combined heat and power facilities using Southeastern Ohio coal that will be located at an upstate New York location. One base case design used an air-blown gasifier, and the other used an oxygen-blown gasifier in order to evaluate their relative economics. Subtask 3.3 developed an advanced design for an air-blown gasification combined heat and power facility based on the Subtask 3.2 design. The air-blown case was chosen since it was less costly and had a better return on investment than the oxygen-blown gasifier case. Under appropriate conditions, this study showed a combined heat and power air-blown gasification facility could be an attractive option for upgrading or expanding the utilities area of industrial facilities. Subtask 3.4 developed a base case design for a large lignite-fueled IGCC power plant that uses the advanced GE 7FB combustion turbine to be located at a generic North Dakota site. This plant uses low-level waste heat to dry the lignite that otherwise would be rejected to the atmosphere. Although this base case plant design is economically attractive, further enhancements should be investigated. Furthermore, since this is an oxygen-blown facility, it has the potential for capture and sequestration of CO{sub 2}. The third objective for Task 3 was accomplished by having NETL personnel working closely with Nexant and Gas Technology Institute personnel during execution of this project. Technology development will be the key to the long-term commercialization of gasification technologies. This will be important to the integration of this environmentally superior solid fuel technology into the existing mix of power plants and industrial facilities. As a result of this study, several areas have been identified in which research and development will further advance gasification technology. Such areas include improved system availability, development of warm-gas clean up technologies, and improved subsystem designs.

Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

2005-05-01T23:59:59.000Z

339

Transport Reactor Facility  

SciTech Connect

The Morgantown Energy Technology Center (METC) is currently evaluating hot gas desulfurization (HGD)in its on-site transport reactor facility (TRF). This facility was originally constructed in the early 1980s to explore advanced gasification processes with an entrained reactor, and has recently been modified to incorporate a transport riser reactor. The TRF supports Integrated Gasification Combined Cycle (IGCC) power systems, one of METC`s advanced power generation systems. The HGD subsystem is a key developmental item in reducing the cost and increasing the efficiency of the IGCC concept. The TRF is a unique facility with high-temperature, high-pressure, and multiple reactant gas composition capability. The TRF can be configured for reacting a single flow pass of gas and solids using a variety of gases. The gas input system allows six different gas inputs to be mixed and heated before entering the reaction zones. Current configurations allow the use of air, carbon dioxide, carbon monoxide, hydrogen, hydrogen sulfide, methane, nitrogen, oxygen, steam, or any mixture of these gases. Construction plans include the addition of a coal gas input line. This line will bring hot coal gas from the existing Fluidized-Bed Gasifier (FBG) via the Modular Gas Cleanup Rig (MGCR) after filtering out particulates with ceramic candle filters. Solids can be fed either by a rotary pocket feeder or a screw feeder. Particle sizes may range from 70 to 150 micrometers. Both feeders have a hopper that can hold enough solid for fairly lengthy tests at the higher feed rates, thus eliminating the need for lockhopper transfers during operation.

Berry, D.A.; Shoemaker, S.A.

1996-12-31T23:59:59.000Z

340

NETL: Gasification Systems - Gasifier Optimization  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Program Gasification Systems Program Gasification is used to convert a solid feedstock, such as coal, petcoke, or biomass, into a gaseous form, referred to as synthesis gas or syngas, which is primarily hydrogen and carbon monoxide. Pollutants can be captured and disposed of or converted to useful products more easily with gasification-based technologies compared to conventional combustion of solid feedstocks. Gasification can generate clean power, and by adding steam to the syngas and performing water-gas-shift to convert the carbon monoxide to carbon dioxide (CO2), additional hydrogen can be produced. The hydrogen and CO2 are separated-the hydrogen is used to make power and the CO2 is sent to storage, converted to useful products or used for enhanced oil recovery (see Gasification Systems Program Research and Development Areas figure). In addition to efficiently producing electric power, a wide range of transportation fuels and chemicals can be produced from the cleaned syngas, thereby providing the flexibility needed to capitalize on the changing economic market. As a result, gasification provides a flexible technology option for using domestically available resources while meeting future environmental emission standards. Furthermore, polygeneration plants that produce multiple products are uniquely possible with gasification technologies.

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
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341

Fundamental studies of catalytic gasification  

Science Conference Proceedings (OSTI)

The major purpose of this project was to finding catalysts which will permit steam gasification of carbonaceous material at reasonable rates and at lower temperatures than currently practiced. This quarter, experiments with steam gasification of graphite were performed. Catalysts studied were potassium, calcium, and nickel oxides. Reaction kinetics are discussed. 28 refs., 34 figs., 8 tabs.

Heinemann, H.; Somorjai, G.A.

1991-06-01T23:59:59.000Z

342

In Situ Causticizing for Black Liquor Gasification  

Science Conference Proceedings (OSTI)

Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

Scott Alan Sinquefield

2005-10-01T23:59:59.000Z

343

Combustion Engineering Integrated Gasification Combined Cycle (IGCC) Repowering Project -- Clean Coal II Project. Annual report, November 20, 1990--December 31, 1991  

SciTech Connect

The IGCC system will consist of CE`s air-blown, entrained-flow, two-stage, pressurized coal gasifier; an advanced hot gas cleanup process; a combustion turbine adapted to use low-Btu coal gas; and all necessary coal handling equipment. The IGCC will include CE`s slogging, entrained-flow, gasifier operating in a pressurized mode and using air as the oxidant. The hot gas will be cleaned of particulate matter (char) which is recycled back to the gasifier. After particulate removal, the product gas will be cleaned of sulfur prior to burning in a gas turbine. The proposed project includes design and demonstration of two advanced hot gas cleanup processes for removal of sulfur from the product gas of the gasifier. The primary sulfur removal method features a newly developed moving-bed zinc ferrite system downstream of the gasifier. The process data from these pilot tests is expected to be sufficient for the design of a full-scale system to be used in the proposed demonstration. A second complementary process is in situ desulfurization achieved by adding limestone or dolomite directly to the coal feed. The benefit, should such an approach prove viable, is that the downstream cleanup system could be reduced in size. In this plant, the gasifier will be producing a low-Btu gas (LBG). The LBG will be used as fuel in a standard GE gas turbine to produce power. This gas turbine will have the capability to fire LBG and natural gas (for start-up). Since firing LBG uses less air than natural gas, the gas turbine air compressor will have extra capacity. This extra compressed air will be used to pressurize the gasifier and supply the air needed in the gasification process. The plant is made of three major blocks of equipment as shown in Figure 2. They are the fuel gas island which includes the gasifier and gas cleanup, gas turbine power block, and the steam turbine block which includes the steam turbine and the HRSG.

1993-03-01T23:59:59.000Z

344

PNNL Coal Gasification Research  

Science Conference Proceedings (OSTI)

This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

2010-07-28T23:59:59.000Z

345

Underground gasification of coal  

DOE Patents (OSTI)

There is disclosed a method for the gasification of coal in situ which comprises drilling at least one well or borehole from the earth's surface so that the well or borehole enters the coalbed or seam horizontally and intersects the coalbed in a direction normal to its major natural fracture system, initiating burning of the coal with the introduction of a combustion-supporting gas such as air to convert the coal in situ to a heating gas of relatively high calorific value and recovering the gas. In a further embodiment the recovered gas may be used to drive one or more generators for the production of electricity.

Pasini, III, Joseph (Morgantown, WV); Overbey, Jr., William K. (Morgantown, WV); Komar, Charles A. (Uniontown, PA)

1976-01-20T23:59:59.000Z

346

Biodesulfurization of mild gasification liquid products. Final technical report, 1 September, 1992--31 August, 1993  

Science Conference Proceedings (OSTI)

The mild gasification of coal, as being developed at IGT and elsewhere, is a promising new technology that can convert coal to multiple products: gas, solid, and liquids. Mild gasification liquids can be used as feedstock to make transportation fuels and chemicals. However, the sulfur content and aromaticity of mild gasification liquids limits their usefulness and biodesulfurization can potentially decrease both sulfur content and aromaticity. The objective of this project is to investigate and feasibility of using biodesulfurization to upgrade the quality of mild gasification liquids. During this project, it was shown that the middle distillate (360--440 F) fraction of liquids derived from the mild gasification of coal, and unfractionated liquids can be biodesulfurized. Moreover, it was demonstrated that lysed cell preparations and freeze-dried cells can be used to biodesulfurize mild coal gasification liquids. The importance of the finding that freeze-dried biocatalysts can be used to biodesulfurize mild coal gasification liquids is that freeze-dried cells can be produced at one location, stored indefinitely, and then shipped (at reduced weight, volume, and cost) to another location for coal biodesulfurization. Moreover, freeze-dried biocatalysts can be added directly to mild coal gasification liquids with only minimal additions of water so that reactor volumes can be minimized.

Kilbane, J.J. II [Institute of Gas Technology, Chicago, IL (United States)

1993-12-31T23:59:59.000Z

347

Gasification Product Improvement Facility (GPIF). Final report  

SciTech Connect

The gasifier selected for development under this contract is an innovative and patented hybrid technology which combines the best features of both fixed-bed and fluidized-bed types. PyGas{trademark}, meaning Pyrolysis Gasification, is well suited for integration into advanced power cycles such as IGCC. It is also well matched to hot gas clean-up technologies currently in development. Unlike other gasification technologies, PyGas can be designed into both large and small scale systems. It is expected that partial repowering with PyGas could be done at a cost of electricity of only 2.78 cents/kWh, more economical than natural gas repowering. It is extremely unfortunate that Government funding for such a noble cause is becoming reduced to the point where current contracts must be canceled. The Gasification Product Improvement Facility (GPIF) project was initiated to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology at a cost approaching $1,000 per kilowatt for electric power generation applications. The project was to include an innovative, advanced, air-blown, pressurized, fixed-bed, dry-bottom gasifier and a follow-on hot metal oxide gas desulfurization sub-system. To help defray the cost of testing materials, the facility was to be located at a nearby utility coal fired generating site. The patented PyGas{trademark} technology was selected via a competitive bidding process as the candidate which best fit overall DOE objectives. The paper describes the accomplishments to date.

NONE

1995-09-01T23:59:59.000Z

348

Low-temperature catalytic gasification of food processing wastes. 1995 topical report  

DOE Green Energy (OSTI)

The catalytic gasification system described in this report has undergone continuing development and refining work at Pacific Northwest National Laboratory (PNNL) for over 16 years. The original experiments, performed for the Gas Research Institute, were aimed at developing kinetics information for steam gasification of biomass in the presence of catalysts. From the fundamental research evolved the concept of a pressurized, catalytic gasification system for converting wet biomass feedstocks to fuel gas. Extensive batch reactor testing and limited continuous stirred-tank reactor tests provided useful design information for evaluating the preliminary economics of the process. This report is a follow-on to previous interim reports which reviewed the results of the studies conducted with batch and continuous-feed reactor systems from 1989 to 1994, including much work with food processing wastes. The discussion here provides details of experiments on food processing waste feedstock materials, exclusively, that were conducted in batch and continuous- flow reactors.

Elliott, D.C.; Hart, T.R.

1996-08-01T23:59:59.000Z

349

Synthesis Gas Production by Rapid Solar Thermal Gasification of Corn Stover  

DOE Green Energy (OSTI)

Biomass resources hold great promise as renewable fuel sources for the future, and there exists great interest in thermochemical methods of converting these resources into useful fuels. The novel approach taken by the authors uses concentrated solar energy to efficiently achieve temperatures where conversion and selectivity of gasification are high. Use of solar energy removes the need for a combustion fuel and upgrades the heating value of the biomass products. The syngas product of the gasification can be transformed into a variety of fuels useable with today?s infrastructure. Gasification in an aerosol reactor allows for rapid kinetics, allowing efficient utilization of the incident solar radiation and high solar efficiency.

Perkins, C. M.; Woodruff, B.; Andrews, L.; Lichty, P.; Lancaster, B.; Weimer, A. W.; Bingham, C.

2008-03-01T23:59:59.000Z

350

Instrumentation Needs for Integral Primary System Reactors (IPSRs) - Task 1 Final Report  

Science Conference Proceedings (OSTI)

This report presents the results of the Westinghouse work performed under Task 1 of this Financial Assistance Award and satisfies a Level 2 Milestone for the project. While most of the signals required for control of IPSRs are typical of other PWRs, the integral configuration poses some new challenges in the design or deployment of the sensors/instrumentation and, in some cases, requires completely new approaches. In response to this consideration, the overall objective of Task 1 was to establish the instrumentation needs for integral reactors, provide a review of the existing solutions where available, and, identify research and development needs to be addressed to enable successful deployment of IPSRs. The starting point for this study was to review and synthesize general characteristics of integral reactors, and then to focus on a specific design. Due to the maturity of its design and availability of design information to Westinghouse, IRIS (International Reactor Innovative and Secure) was selected for this purpose. The report is organized as follows. Section 1 is an overview. Section 2 provides background information on several representative IPSRs, including IRIS. A review of the IRIS safety features and its protection and control systems is used as a mechanism to ensure that all critical safety-related instrumentation needs are addressed in this study. Additionally, IRIS systems are compared against those of current advanced PWRs. The scope of this study is then limited to those systems where differences exist, since, otherwise, the current technology already provides an acceptable solution. Section 3 provides a detailed discussion on instrumentation needs for the representative IPSR (IRIS) with detailed qualitative and quantitative requirements summarized in the exhaustive table included as Appendix A. Section 3 also provides an evaluation of the current technology and the instrumentation used for measurement of required parameters in current PWRs. Section 4 examines those instrumentation/measurement needs where differences between IRIS and present PWRs exist and the current PWR implementation cannot be directly employed, and identifies two subcategories. In the first group, resolution can be readily identified, and is essentially an engineering solution (for example, modification of an existing approach, adaptation of existing instrument etc.). The second group presents true technological challenges as it may require new technology development. I n these cases, high level functional requirements have been identified together with relevant technical considerations to guide future development activities.

Gary D. Storrick; Bojan Petrovic; Luca Oriani; Lawrence E. Conway; Diego Conti

2005-09-30T23:59:59.000Z

351

NETL: Gasification- Water-Gas Shift (WGS) Tests to Reduce Steam Use  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Processing Systems Syngas Processing Systems Water-Gas Shift (WGS) Tests to Reduce Steam Use National Carbon Capture Center at the Power Systems Development Facility Southern Company Services, Inc. Project Number: NT0000749 Project Description The National Carbon Capture Center is testing commercial water-gas shift (WGS) catalysts from multiple vendors in support of developing WGS reactor systems which will reduce the cost of carbon dioxide (CO2) capture from the production of syngas using coal. These tests have revealed that steam-to-carbon monoxide (CO) ratios can be reduced, resulting in a substantial increase in the net power output and significantly reducing the cost of electricity from an integrated gasification combined cycle (IGCC) plant with CO2 capture. Several commercially available WGS catalysts have been tested, and the results are being provided to the manufacturers to aid them in specifying future WGS systems for IGCC plants incorporating CO2 capture.

352

NETL: News Release - World Gasification Database Now Available...  

NLE Websites -- All DOE Office Websites (Extended Search)

9, 2010 World Gasification Database Now Available from DOE Database Consolidates World's Gasification Plant Information, Illustrates Growth of Gasification Industry Washington,...

353

Methodology for technology evaluation under uncertainty and its application in advanced coal gasification processes  

E-Print Network (OSTI)

Integrated gasification combined cycle (IGCC) technology has attracted interest as a cleaner alternative to conventional coal-fired power generation processes. While a number of pilot projects have been launched to ...

Gong, Bo, Ph. D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

354

Proliferation resistance of the fuel cycle for the Integral Fast Reactor  

SciTech Connect

Argonne National Laboratory has developed an electrorefining pyrochemical process for recovery and recycle of metal fuel discharged from the Integral Fast Reactor (FR). This inherently low decontamination process has an overall decontamination factor of only about 100 for the plutonium metal product. As a result, all of the fuel cycle operations must be conducted in heavily shielded cells containing a high-purity argon atmosphere. The FR fuel cycle possesses high resistance to clandestine diversion or overt, state- supported removal of plutonium for nuclear weapons production because of two main factors: the highly radioactive product, which is also contaminated with heat- and neutron-producing isotopes of plutonium and other actinide elements, and the difficulty of removing material from the FR facility through the limited number of cell transfer locks without detection.

Burris, L.

1993-09-01T23:59:59.000Z

355

UPDATE ON GASIFICATION TESTING AT THE POWER SYSTEMS DEVELOPMENT FACILITY  

E-Print Network (OSTI)

The Power Systems Development Facility (PSDF) located in Wilsonville, Alabama was established in 1995 to lead the United States ' effort to develop cost-competitive, environmentally acceptable, coal-based power plant technologies. The PSDF is an engineering scale demonstration of key components of an Integrated Gasification Combined Cycle (IGCC) power

Senior Engineer; Pannalal Vimalchand; Roxann Leonard; Robert C. Lambrecht

2008-01-01T23:59:59.000Z

356

Pyrolytic Gasification | Open Energy Information  

Open Energy Info (EERE)

Pyrolytic Gasification Pyrolytic Gasification Jump to: navigation, search Name Pyrolytic Gasification Sector Biomass References Balboa Pacific Corp[1] Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN","zoom":6,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

357

Testing of an advanced thermochemical conversion reactor system  

DOE Green Energy (OSTI)

This report presents the results of work conducted by MTCI to verify and confirm experimentally the ability of the MTCI gasification process to effectively generate a high-quality, medium-Btu gas from a wider variety of feedstock and waste than that attainable in air-blown, direct gasification systems. The system's overall simplicity, due to the compact nature of the pulse combustor, and the high heat transfer rates attainable within the pulsating flow resonance tubes, provide a decided and near-term potential economic advantage for the MTCI indirect gasification system. The primary objective of this project was the design, construction, and testing of a Process Design Verification System for an indirectly heated, thermochemical fluid-bed reactor and a pulse combustor an an integrated system that can process alternative renewable sources of energy such as biomass, black liquor, municipal solid waste and waste hydrocarbons, including heavy oils into a useful product gas. The test objectives for the biomass portion of this program were to establish definitive performance data on biomass feedstocks covering a wide range of feedstock qualities and characteristics. The test objectives for the black liquor portion of this program were to verify the operation of the indirect gasifier on commercial black liquor containing 65 percent solids at several temperature levels and to characterize the bed carbon content, bed solids particle size and sulfur distribution as a function of gasification conditions. 6 refs., 59 figs., 29 tabs.

Not Available

1990-01-01T23:59:59.000Z

358

Hot-Gas Filter Testing with a Transport Reactor Gasifier  

Science Conference Proceedings (OSTI)

Today, coal supplies over 55% of the electricity consumed in the United States and will continue to do so well into the next century. One of the technologies being developed for advanced electric power generation is an integrated gasification combined cycle (IGCC) system that converts coal to a combustible gas, cleans the gas of pollutants, and combusts the gas in a gas turbine to generate electricity. The hot exhaust from the gas turbine is used to produce steam to generate more electricity from a steam turbine cycle. The utilization of advanced hot-gas particulate and sulfur control technologies together with the combined power generation cycles make IGCC one of the cleanest and most efficient ways available to generate electric power from coal. One of the strategic objectives for U.S. Department of Energy (DOE) IGCC research and development program is to develop and demonstrate advanced gasifiers and second-generation IGCC systems. Another objective is to develop advanced hot-gas cleanup and trace contaminant control technologies. One of the more recent gasification concepts to be investigated is that of the transport reactor gasifier, which functions as a circulating fluid-bed gasifier while operating in the pneumatic transport regime of solid particle flow. This gasifier concept provides excellent solid-gas contacting of relatively small particles to promote high gasification rates and also provides the highest coal throughput per unit cross-sectional area of any other gasifier, thereby reducing capital cost of the gasification island.

Swanson, M.L.; Hajicek, D.R.

2002-09-18T23:59:59.000Z

359

Steam-injected gas turbines uneconomical with coal gasification equipment  

SciTech Connect

Researchers at the Electric Power Research Institute conducted a series of engineering and economic studies to assess the possibility of substituting steam-injected gas (STIG) turbines for the gas turbines currently proposed for use in British Gas Corporation (BGC)/Lurgi coal gasification-combined cycle plants. The study sought to determine whether steam-injected gas turbines and intercooled steam-injected gas turbines, as proposed by General Electric would be economically competitive with conventional gas and steam turbines when integrated with coal gasification equipment. The results are tabulated in the paper.

1986-09-01T23:59:59.000Z

360

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network (OSTI)

GASIFIER IN A FLUIDIZED BED REACTOR Inventors: Joseph M .a steam hydro-gasification reactor (SHR) the carbonaceous0012] Fluidized bed reactors are well known and used in a

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

REACTOR  

DOE Patents (OSTI)

A pressurized water reactor in which automatic control is achieved by varying the average density of the liquid moderator-cooiant is patented. Density is controlled by the temperature and power level of the reactor ftself. This control can be effected by the use of either plate, pellet, or tubular fuel elements. The fuel elements are disposed between upper and lower coolant plenum chambers and are designed to permit unrestricted coolant flow. The control chamber has an inlet opening communicating with the lower coolant plenum chamber and a restricted vapor vent communicating with the upper coolant plenum chamber. Thus, a variation in temperature of the fuel elements will cause a variation in the average moderator density in the chamber which directly affects the power level of the reactor.

Roman, W.G.

1961-06-27T23:59:59.000Z

362

Biomass waste gasification - Can be the two stage process suitable for tar reduction and power generation?  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Comparison of one stage (co-current) and two stage gasification of wood pellets. Black-Right-Pointing-Pointer Original arrangement with grate-less reactor and upward moving bed of the pellets. Black-Right-Pointing-Pointer Two stage gasification leads to drastic reduction of tar content in gas. Black-Right-Pointing-Pointer One stage gasification produces gas with higher LHV at lower overall ER. Black-Right-Pointing-Pointer Content of ammonia in gas is lower in two stage moving bed gasification. - Abstract: A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter-current downdraft in the second stage was developed and exploited for studying effects of two stage gasification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass particles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW{sub th}. The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950 Degree-Sign C) and for gasification reaction of the fuel gas with char. The second stage used additional combustion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar compound contents confirmed superiority of the two stage gasification system, drastic decrease of aromatic compounds with two and higher number of benzene rings by 1-2 orders. On the other hand the two stage gasification (with overall ER = 0.71) led to substantial reduction of gas heating value (LHV = 3.15 MJ/Nm{sup 3}), elevation of gas volume and increase of nitrogen content in fuel gas. The increased temperature (>950 Degree-Sign C) at the entrance to the char bed caused also substantial decrease of ammonia content in fuel gas. The char with higher content of ash leaving the second stage presented only few mass% of the inlet biomass stream.

Sulc, Jindrich; Stojdl, Jiri; Richter, Miroslav; Popelka, Jan [Faculty of the Environment, Jan Evangelista Purkyne University in Usti nad Labem, Kralova Vysina 7, 400 96 Usti nad Labem (Czech Republic); Svoboda, Karel, E-mail: svoboda@icpf.cas.cz [Faculty of the Environment, Jan Evangelista Purkyne University in Usti nad Labem, Kralova Vysina 7, 400 96 Usti nad Labem (Czech Republic); Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 02 Prague 6 (Czech Republic); Smetana, Jiri; Vacek, Jiri [D.S.K. Ltd., Ujezdecek - Dukla 264, 415 01 Teplice I (Czech Republic); Skoblja, Siarhei; Buryan, Petr [Dept. of Gas, Coke and Air protection, Institute of Chemical Technol., Technicka 5, 166 28 Prague 6 (Czech Republic)

2012-04-15T23:59:59.000Z

363

Coal gasification vessel  

DOE Patents (OSTI)

A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

Loo, Billy W. (Oakland, CA)

1982-01-01T23:59:59.000Z

364

Co-Production of Substitute Natural Gas/Electricity Via Catalytic Coal Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 Co-ProduCtion of SubStitute natural GaS / eleCtriCity via CatalytiC Coal GaSifiCation Description The United States has vast reserves of low-cost coal, estimated to be sufficient for the next 250 years. Gasification-based technology, such as Integrated Gasification Combined Cycle (IGCC), is the only environmentally friendly technology that provides the flexibility to co-produce hydrogen, substitute natural gas (SNG), premium hydrocarbon liquids including transportation fuels, and electric power in desired combinations from coal and other carbonaceous feedstocks. Rising costs and limited domestic supply of crude oil and natural gas provide a strong incentive for the development of coal gasification-based co-production processes. This project addresses the co-production of SNG and electricity from coal via gasification

365

Materials of Gasification  

DOE Green Energy (OSTI)

The objective of this project was to accumulate and establish a database of construction materials, coatings, refractory liners, and transitional materials that are appropriate for the hardware and scale-up facilities for atmospheric biomass and coal gasification processes. Cost, fabricability, survivability, contamination, modes of corrosion, failure modes, operational temperatures, strength, and compatibility are all areas of materials science for which relevant data would be appropriate. The goal will be an established expertise of materials for the fossil energy area within WRI. This would be an effort to narrow down the overwhelming array of materials information sources to the relevant set which provides current and accurate data for materials selection for fossil fuels processing plant. A significant amount of reference material on materials has been located, examined and compiled. The report that describes these resources is well under way. The reference material is in many forms including texts, periodicals, websites, software and expert systems. The most important part of the labor is to refine the vast array of available resources to information appropriate in content, size and reliability for the tasks conducted by WRI and its clients within the energy field. A significant has been made to collate and capture the best and most up to date references. The resources of the University of Wyoming have been used extensively as a local and assessable location of information. As such, the distribution of materials within the UW library has been added as a portion of the growing document. Literature from recent journals has been combed for all pertinent references to high temperature energy based applications. Several software packages have been examined for relevance and usefulness towards applications in coal gasification and coal fired plant. Collation of the many located resources has been ongoing. Some web-based resources have been examined.

None

2005-09-15T23:59:59.000Z

366

NETL: Gasification Systems Program Contacts  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Program Contacts Gasification Systems Program Contacts Jenny Tennant Gasification Technology Manager U.S. Department of Energy National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 Phone: (304) 285-4830 Email: Jenny.Tennant@netl.doe.gov Pete Rozelle Division of Advanced Energy System - Program Manager, Office of Fossil Energy U.S. Department of Energy FE-221/Germantown Building 1000 Independence Avenue, S.W. Washington, DC 20585-1209 Phone: (301) 903-2338 Email: Peter.Rozelle@hq.doe.gov Heather Quedenfeld Gasification Division Director U.S. Department of Energy National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 Phone: (412) 386-5781 Email: Heather.Quedenfeld@netl.doe.gov Kristin Gerdes Performance Division

367

Materials Guidelines for Gasification Plants  

Science Conference Proceedings (OSTI)

This report distills and condenses EPRI's knowledge of materials performance in numerous pilot and commercial-scale gasifiers into guidelines for the application and expected performance of materials in key parts of gasification-combined-cycle power plants.

1998-06-16T23:59:59.000Z

368

Catalytic Hydrothermal Gasification of Biomass  

Science Conference Proceedings (OSTI)

A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

Elliott, Douglas C.

2008-05-06T23:59:59.000Z

369

NETL: Gasification Systems - Feed Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Gasification Systems Feed Systems Research on commercial gasifier feed systems is occurring in two primary areas of fuel (i.e. coal, biomass, etc.) feed and advanced...

370

NETL: Gasification Systems - Gasifier Optimization  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal Optimization Small-Scale Coal-biomass to Liquids Production Using Highly Selective Fischer-Tropsch Synthesis Small-Scale Pilot Plant for the Gasification of Coal and Coal...

371

Coupled hydrodynamic-structural analysis of an integral flowing sodium test loop in the TREAT reactor  

SciTech Connect

A hydrodynamic-structural response analysis of the Mark-IICB loop was performed for the TREAT (Transient Reactor Test Facility) test AX-1. Test AX-1 is intended to provide information concerning the potential for a vapor explosion in an advanced-fueled LMFBR. The test will be conducted in TREAT with unirradiated uranium-carbide fuel pins in the Mark-IICB integral flowing sodium loop. Our analysis addressed the ability of the experimental hardware to maintain its containment integrity during the reference accident postulated for the test. Based on a thermal-hydraulics analysis and assumptions for fuel-coolant interaction in the test section, a pressure pulse of 144 MPa maximum pressure and pulse width of 1.32 ms has been calculated as the reference accident. The response of the test loop to the pressure transient was obtained with the ICEPEL and STRAW codes. Modelling of the test section was completed with STRAW and the remainder of the loop was modelled by ICEPEL.

Zeuch, W.R.; A-Moneim, M.T.

1979-01-01T23:59:59.000Z

372

Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel  

DOE Patents (OSTI)

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor.

Schreiber, Roger B. (Penn Twp., PA); Fero, Arnold H. (New Kensington, PA); Sejvar, James (Murrysville, PA)

1997-01-01T23:59:59.000Z

373

Thermal insulating barrier and neutron shield providing integrated protection for a nuclear reactor vessel  

DOE Patents (OSTI)

The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel to form a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive valving also includes bistable vents at the upper end of the thermal insulating barrier for releasing steam. A removable, modular neutron shield extending around the upper end of the reactor cavity below the nozzles forms with the upwardly and outwardly tapered transition on the outer surface of the reactor vessel, a labyrinthine channel which reduces neutron streaming while providing a passage for the escape of steam during a severe accident, and for the cooling air which is circulated along the reactor cavity walls outside the thermal insulating barrier during normal operation of the reactor. 8 figs.

Schreiber, R.B.; Fero, A.H.; Sejvar, J.

1997-12-16T23:59:59.000Z

374

NETL: Gasifipedia - What is Gasification?  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Background Gasification Background Drivers for Gasification Technology The need for low-cost power produced in an environmentally sound way is certain, even if the future of regulations limiting the emission and/or encouraging the capture of CO2, and the price and availability of natural gas and oil are not. Gasification is not only capable of efficiently producing electric power, but a wide range of liquids and/or high-value chemicals (including diesel and gasoline for transportation) can be produced from cleaned syngas, providing the flexibility to capitalize on a range of dynamic changes to either domestic energy markets or global economic conditions. Polygeneration-plants that produce multiple products-is uniquely possible with gasification technologies. Continued advances in gasification-based technology will enable the conversion of our nation's abundant coal reserves into energy resources (power and liquid fuels), chemicals, and fertilizers needed to displace the use of imported oil and, thereby, help mitigate its high price and security supply concerns and to support U.S. economic competitiveness with unprecedented environmental performance.

375

Hydrogen-Rich Gas Production from Steam Gasification of Palm Oil Wastes Using the Supported Nano-NiO/?-Al2O3 Catalyst  

Science Conference Proceedings (OSTI)

The catalytic steam gasification of palm oil wastes for hydrogen-rich gas production was experimentally investigated in a combined fixed bed reactor using the newly developed nano-NiO/?-Al2O3 catalyst. The results indicated that the nano-NiO/?-Al2O3 ... Keywords: Biomass gasification, palm oil waste, catalyst, hydrogen production

Jianfen Li; Yanfang Yin; Jianjun Liu; Rong Yan

2009-10-01T23:59:59.000Z

376

Mass Balance Results for Pricetown I Underground Coal Gasification  

SciTech Connect

A mass balance model was applied to the Pricetown I test data. This model gave the values of various parameters such as water influx, percent devolatilization, percent gasification, amount of coal affected, thermal efficiency, etc., for the various phases of the test. Both hourly and daily values of the test data were used. At certain times, there was air loss to the coal seam or air gain from the coal seam as related to the underground reactor. Mass balances are modified accordingly. Realistic pyrolysis temperatures have been chosen for the different phases of the test based on the thermocouple responses. The nitrogen and argon balances gave similar results. The mass balance results showed that approximately 702 tons of coal was affected during the test. Approximately 232 tons of coal was completely gasified. The reverse combustion linkage through the virgin coal seam was dominated by the devolatilization and accounted for approximately 80% devoltilization whereas the same accounted for only 26% devolatilization during the gasification phase. During the enhanced linkage phase, the percent devolatilization ranged between that observed for the RCL and gasification phase. There was net influx of water and amounted to 0.59 barrels per ton of coal affected. The percent energy recovery for the gasification phase was 72% based on gas chromatographic data, and accounting the sensible heat of the gas and the latent heat of the water vapor in the gas.

Agarwal, A. K.; Seabaugh, P. W.; Zielinski, R. E.

1979-10-01T23:59:59.000Z

377

Experience with atmospheric fluidized bed gasification of switchgrass  

DOE Green Energy (OSTI)

Switchgrass was gasified in a bubbling fluidized bed reactor rated at 800 kW (2.75 MMBtu/hr) thermal input and operating at atmospheric pressure. A combustible gas with higher heating value varying between 4.2--5.9 MJ/Nm{sup 3} (114--160 Btu/scf) was produced. Carbon conversion was approximately 85%. Difficulties in feeding high moisture switchgrass inhibited smooth reactor operation. Several feed systems for switchgrass were tried with varying degrees of success. The results of gasification trials using switchgrass as fuel are described.

Smeenk, J.; Brown, R.C. [Iowa State Univ., Ames, IA (United States). Center for Coal and the Environment

1998-12-31T23:59:59.000Z

378

Coal gasification construction materials: an overview  

SciTech Connect

Materials performance test results are presented for two coal gasification processes, HYGAS SNG process, which converts any type of coal to substitute natural gas (SNG), and U-GAS fuel gas process, which converts coal to a low- or medium-heat value gas. A description of the pilot plant for each process and discussion of some experiences with materials and components used in plant construction is presented. Metals performance inside the gasifier reactors and in off-gas locations depended upon the character of the process. At moderate operating temperatures (427/sup 0/C), low-carbon steels are advisable. Very high-temperature environments may not only require use of exotic alloys, clads, and/or coatings but may also preclude extensive use of internal piping/valving in scale-up designs. Inconel 182, 600, and Monel 400 have all performed erratically in the plants; but in quench and purification sections, austenitic stainless steels performed well. 9 references. (BLM)

Arnold, J.M. (Inst. of Gas Tech., Chicago, IL); Laurens, R.M.; Danyluk, S.

1981-12-01T23:59:59.000Z

379

Hybrid Combustion-Gasification Chemical Looping  

DOE Green Energy (OSTI)

For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2} separation, and also syngas production from coal with the calcium sulfide (CaS)/calcium sulfate (CaSO{sub 4}) loop utilizing the PDU facility. The results of Phase I were reported in Reference 1, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase I Report' The objective for Phase II was to develop the carbonate loop--lime (CaO)/calcium carbonate (CaCO{sub 3}) loop, integrate it with the gasification loop from Phase I, and ultimately demonstrate the feasibility of hydrogen production from the combined loops. The results of this program were reported in Reference 3, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase II Report'. The objective of Phase III is to operate the pilot plant to obtain enough engineering information to design a prototype of the commercial Chemical Looping concept. The activities include modifications to the Phase II Chemical Looping PDU, solids transportation studies, control and instrumentation studies and additional cold flow modeling. The deliverable is a report making recommendations for preliminary design guidelines for the prototype plant, results from the pilot plant testing and an update of the commercial plant economic estimates.

Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

2009-01-07T23:59:59.000Z

380

Development of ceramic membrane reactors for high temperature gas cleanup. Final report  

SciTech Connect

The objective of this project was to develop high temperature, high pressure catalytic ceramic membrane reactors and to demonstrate the feasibility of using these membrane reactors to control gaseous contaminants (hydrogen sulfide and ammonia) in integrated gasification combined cycle (IGCC) systems. Our strategy was to first develop catalysts and membranes suitable for the IGCC application and then combine these two components as a complete membrane reactor system. We also developed a computer model of the membrane reactor and used it, along with experimental data, to perform an economic analysis of the IGCC application. Our results have demonstrated the concept of using a membrane reactor to remove trace contaminants from an IGCC process. Experiments showed that NH{sub 3} decomposition efficiencies of 95% can be achieved. Our economic evaluation predicts ammonia decomposition costs of less than 1% of the total cost of electricity; improved membranes would give even higher conversions and lower costs.

Roberts, D.L.; Abraham, I.C.; Blum, Y.; Gottschlich, D.E.; Hirschon, A.; Way, J.D.; Collins, J.

1993-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

June 2007 gasification technologies workshop papers  

SciTech Connect

Topics covered in this workshop are fundamentals of gasification, carbon capture and sequestration, reviews of financial and regulatory incentives, co-production, and focus on gasification in the Western US.

NONE

2007-06-15T23:59:59.000Z

382

Beluga Coal Gasification - ISER  

SciTech Connect

ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

Steve Colt

2008-12-31T23:59:59.000Z

383

Waste removal in pyrochemical fuel processing for the Integral Fast Reactor  

SciTech Connect

Electrorefining in a molten salt electrolyte is used in the Integral Fast Reactor fuel cycle to recover actinides from spent fuel. Processes that are being developed for removing the waste constituents from the electrorefiner and incorporating them into the waste forms are described in this paper. During processing, halogen, chalcogen, alkali, alkaline earth, and rare earth fission products build up in the molten salt as metal halides and anions, and fuel cladding hulls and noble metal fission products remain as metals of various particle sizes. Essentially all transuranic actinides are collected as metals on cathodes, and are converted to new metal fuel. After processing, fission products and other waste are removed to a metal and a mineral waste form. The metal waste form contains the cladding hulls, noble metal fission products, and (optionally) most rare earths in a copper or stainless steel matrix. The mineral waste form contains fission products that have been removed from the salt into a zeolite or zeolite-derived matrix.

Ackerman, J.P.; Johnson, T.R.; Laidler, J.J.

1994-01-01T23:59:59.000Z

384

Management of transuranics using the Integral Fast Reactor (IFR) fuel cycle  

Science Conference Proceedings (OSTI)

The 50 years of activities following the discovery of self-sustaining fission chains have given rise to a buildup of roughly 900 tons of manmade transuranics. Of the total, about 260 tons of Pu{sup 239} were generated for use in weapons while the remainder were generated as a byproduct of electrical power produced worldwide by the commercial thermal nuclear power industry. What is to be done with these actinides? The options for disposition include interminable storage, burial, or recycle for use. The pros and cons of each option are being vigorously debated regarding the impact upon the issues of human and ecological risk -- both current and future; weapons proliferation potential -- both current and future; and total life cycle benefits and costs. As to the options for utilization, commercial uses for actinides (uranium and transuranics) are of limited diversity. The actinides have in the past and will in the future find application in large scale mostly by virtue of their ability to release energy through fission, and here their utility is unmatched -- whether the application be in commercial electricity generation or in armaments. The integral Fast Reactor (IFR) fuel cycle offers a number of features for management of the current and future burden of manmade transuranic materials and for capturing the energy content of the U{sup 238}. These features are discussed here.

Wade, D.C.

1994-01-01T23:59:59.000Z

385

Survey of biomass gasification. Volume II. Principles of gasification  

DOE Green Energy (OSTI)

Biomass can be converted by gasification into a clean-burning gaseous fuel that can be used to retrofit existing gas/oil boilers, to power engines, to generate electricity, and as a base for synthesis of methanol, gasoline, ammonia, or methane. This survey describes biomass gasification, associated technologies, and issues in three volumes. Volume I contains the synopsis and executive summary, giving highlights of the findings of the other volumes. In Volume II the technical background necessary for understanding the science, engineering, and commercialization of biomass is presented. In Volume III the present status of gasification processes is described in detail, followed by chapters on economics, gas conditioning, fuel synthesis, the institutional role to be played by the federal government, and recommendations for future research and development.

Reed, T.B. (comp.)

1979-07-01T23:59:59.000Z

386

The Caterpillar Coal Gasification Facility  

E-Print Network (OSTI)

This paper is a review of one of America's premier coal gasification installations. The caterpillar coal gasification facility located in York, Pennsylvania is an award winning facility. The plant was recognized as the 'pace setter plant of the year' in 1981 and won the 'energy conservation award' for 1983. The decision to install and operate a coal gasification plant was based on severe natural gas curtailments at York with continuing supply interruptions. This paper will present a detailed description of the equipment used in the coal gasification system and the process itself. It also includes operating and gas production information along with an economic analysis. The characteristics of producer gas and its use in the various plant applications will be reviewed and compared with natural gas. In summary, this paper deals with caterpillar's experience with coal gasification to date. Caterpillar concludes that the coal gas system has the potential to favorably affect the corporation's commitment to stimulate coal utilization. The three years' operating experience at the York plant has demonstrated the practical use of coal gas as well as the economics associated with producing gas from coal.

Welsh, J.; Coffeen, W. G., III

1983-01-01T23:59:59.000Z

387

Engineering and Economic Evaluation of Biomass Gasification  

Science Conference Proceedings (OSTI)

The use of gasification technology to convert biomass to electric power has increased substantially over the last 10 years. Many new projects, using a wide range of gasification technologies, have been developed and become operational. Some of the key driving factors for biomass gasification-to-power facilities include:Abundant local supplies of biomass, at low or no cost, for use as a feedstock for gasification-to-power facilities.Federal and state tax credits ...

2012-12-20T23:59:59.000Z

388

Gasification Users Association (GUA) Update, September 2011  

Science Conference Proceedings (OSTI)

The Gasification Users Association (GUA) Update is published quarterly. The following articles are featured in this issue: Quarterly Summary Ongoing U.S. Energy Program Updates European Union Plans Support of Multiple CCS Projects News Items on Operating IGCC Plants U.S. IGCC Project Updates International IGCC Project Updates International Gasification Projects for Chemicals Biomass and Waste Gasification Projects Coal to SNG Coal to Liquids (CTL) Gas to Liquids (GTL) Underground Coal Gasification (U...

2011-10-07T23:59:59.000Z

389

Gasification Users Association: Technology Status - December 2012  

Science Conference Proceedings (OSTI)

This report addresses the worldwide market and technology status of gasification technologies. The market for gasification technologies is primarily in China, where national policy has established a major coal–to–chemicals industry and plans to add major coal–to–substitute natural gas and coal–to–liquid transportation fuels in the next five-year plan. Gasification is being deployed to a lesser extent in other Asian countries and elsewhere. Gasification technology ...

2012-12-31T23:59:59.000Z

390

Gasification Users Association - Technology Status - December 2011  

Science Conference Proceedings (OSTI)

This report addresses the worldwide market and technology status of gasification technologies. The market for gasification technologies is primarily in China where national policy has established a major coal-to-chemicals industry and plans to add major plants for coal-to-substitute natural gas (SNG) and coal-to-liquid transportation fuels in the next five-year plan. Gasification is also being deployed to some extent in other Asian countries (for example, Korea and India) and elsewhere. Gasification tech...

2011-12-30T23:59:59.000Z

391

Carbon-catalyzed gasification of organic feedstocks in supercritical water  

Science Conference Proceedings (OSTI)

Spruce wood charcoal, macadamia shell charcoal, coal activated carbon, and coconut shell activated carbon catalyze the gasification of organic compounds in supercritical water. Feedstocks studied in this paper include glycerol, glucose, cellobiose, whole biomass feedstocks (depithed bagasse liquid extract and sewage sludge), and representative Department of Defense (DoD) wastes (methanol, methyl ethyl ketone, ethylene glycol, acetic acid, and phenol). The effects of temperature, pressure, reactant concentration, weight hourly space velocity, and the type of catalyst on the gasification of glucose are reported. Complete conversion of glucose (22% by weight in water) to a hydrogen-rich synthesis gas was realized at a weight hourly space velocity (WHSV) of 22.2 h{sup {minus}1} in supercritical water at 600 C, 34.5 MPa. Complete conversions of the whole biomass feeds were also achieved at the same temperature and pressure. The destruction efficiencies for the representative DoD wastes were also high. Deactivation of the carbon catalyst was observed after 4 h of operation without swirl in the entrance region of the reactor, but the carbon gasification efficiency remained near 100% for more than 6 h when a swirl generator was employed in the entrance of the reactor.

Xu, X.; Matsumura, Y.; Stenberg, J.; Antal, M.J. Jr. [Univ. of Hawaii, Honolulu, HI (United States). Hawaii Natural Energy Inst.

1996-08-01T23:59:59.000Z

392

Investigation of a sulfur reduction technique for mild gasification char  

DOE Green Energy (OSTI)

The object of this program is to investigate the desulfurization of mild gasification char using hydrogen/methane mixtures in a laboratory-scale experimental study. In the first year of the two- year program, char is being treated with mixtures of H{sub 2} and CH{sub 4} at temperatures of 1100{degrees}C to 1550{degrees}F and pressures of 50 to 100 psig. The effects of temperature, pressure, residence time, gas velocity, and gas composition on sulfur removal and carbon gasification are being determined. The batch experiments are being performed in a nominal 2-inch-ID stainless-steel, batch, fluidized-bed reactor. The char to be desulfurized was produced by the IGT mild gasification process research unit (PRU) in a recently completed DOE/METC-sponsored technology development program. The parent coal was Illinois No. 6 from a preparation plant, and the char from the selected test contains 4.58 wt% sulfur. In the first quarter, we have obtained and prepared a char for the desulfurization tests. Ultimate and proximate analyses were performed on this char, and its pore size distribution and surface area were determined. Also this quarter, the fluidized-bed reactor system was constructed and equipped with high pressure mass flow controllers and a high pressure sintered metal filter to remove fines from the effluent gas stream.

Knight, R.A.

1991-01-01T23:59:59.000Z

393

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

DOE Green Energy (OSTI)

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-06-01T23:59:59.000Z

394

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

DOE Green Energy (OSTI)

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-01-01T23:59:59.000Z

395

NETL: Gasification Systems - Gas Separation  

NLE Websites -- All DOE Office Websites (Extended Search)

Separation Separation Ion-Transport Membrane Oxygen Separation Modules Ion-Transport Membrane Oxygen Separation Modules Gas separation unit operations represent major cost elements in gasification plants. The gas separation technology being supported in the DOE program promises significant reduction in cost of electricity, improved thermal efficiency, and superior environmental performance. Gasification-based energy conversion systems rely on two gas separation processes: (1) separation of oxygen from air for feed to oxygen-blown gasifiers; and (2) post-gasification separation of hydrogen from carbon dioxide following (or along with) the shifting of gas composition when carbon dioxide capture is required or hydrogen is the desired product. Research efforts include development of advanced gas separation

396

Development of High-Pressure Dry Feed Pump for Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Pressure Dry Feed Pressure Dry Feed Pump for Gasification Systems Background Even though coal-based power generation via Integrated Gasification Combined Cycle (IGCC) is more efficient, cleaner, and uses less water than conventional pulverized coal burning systems, widespread IGCC deployment has not occurred because of its relatively high cost. The Pratt & Whitney Rocketdyne (PWR) high-pressure dry feed pump addresses IGCC cost disparity by enabling lower cost and more reliable coal feed

397

Behavior of chars from Bursa Mustafa Kemal Pasa Alpagut and Balkesir Dursunbey Cakiirca Lignite (Turkey) during non-catalytic and catalytic gasification  

Science Conference Proceedings (OSTI)

The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures of the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.

Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.; Tekes, A.T.; Canel, M. [Ankara University, Ankara (Turkey). Dept. of Chemistry

2008-07-01T23:59:59.000Z

398

Integrated coal cleaning, liquefaction, and gasification process  

DOE Patents (OSTI)

Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

Chervenak, Michael C. (Pennington, NJ)

1980-01-01T23:59:59.000Z

399

Biomass Integrated Gasification Combined Cycles (BIGCC).  

E-Print Network (OSTI)

??Conversion of biomass to energy does not contribute to the net increase of carbon dioxide in the environment, therefore the use of biomass waste as… (more)

Yap, Mun Roy

2004-01-01T23:59:59.000Z

400

Life Cycle Analysis: Integrated Gasification Combined Cycle ...  

NLE Websites -- All DOE Office Websites (Extended Search)

87 Final Report: IGCC-LCA VII Prepared by: Laura Draucker Raj Bhander Barbara Bennet Tom Davis Robert Eckard William Ellis John Kauffman James Littlefield Amanda Malone Ron Munson...

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Life Cycle Analysis: Integrated Gasification Combined Cycle ...  

NLE Websites -- All DOE Office Websites (Extended Search)

"ASTM Standard Inch-Pound Reinforcing Bars". http:www.crsi.orgrebarmetric.html. Davis, Leroy,(2007). Reference & Information: American Wire Gauge Cable Descriptions....

402

Developing and Integrating Sustainable Chemical Processes into Existing Petro-Chemical Plant Complexes  

E-Print Network (OSTI)

pyrolysis or gasification (2). Finally, lipids from nonfood crops as well as algae (3) can be converted processes (17). Like pyrolysis, gasification also uses whole biomass but converts it spontaneously at very) combined the three reactions of older thermal gasification processes into a single, small reactor in which

Pike, Ralph W.

403

Current Gasification Research | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification » Current Gasification » Current Gasification Research Current Gasification Research Sponsored by the U.S. Department of Energy, the National Carbon Capture Center provides first-class facilities to test carbon capture technologies. Sponsored by the U.S. Department of Energy, the National Carbon Capture Center provides first-class facilities to test carbon capture technologies. With coal gasification now in modern commercial-scale applications, the U.S. Department of Energy's (DOE) Office of Fossil Energy has turned its attention to future gasification concepts that offer significant improvements in efficiency, fuel flexibility, economics and environmental sustainability. Fuel flexibility is especially important. Tomorrow's gasification plants conceivably could process a wide variety of low-cost feedstocks, handling

404

Investigation of a sulfur reduction technique for mild gasification char. Technical report, December 1, 1992--February 28, 1993  

DOE Green Energy (OSTI)

The objective of this program is to investigate the desulfurization of mild gasification char using H{sub 2}:CH{sub 4} mixtures. Mild gasification of coal produces char, liquids, and gases at 1000{degrees}--1500{degrees}F (538{degrees}-816{degrees}C) and near-ambient pressure. Char, comprising 60--70% of the product, can be used to make high-value form coke for steelmaking and foundries. However, a sulfur content below 1 wt% is desirable, and char from high-sulfur Illinois coals must be upgraded to meet this criterion. Illinois No. 6 chars were treated in a 2-inch batch fluidized-bed reactor with H{sub 2}:CH{sub 4} blends containing 9--24 vol % CH{sub 4} at 1100{degrees}-1600{degrees}F (538{degrees}-871{degrees}C) and 50--200 psig (0.35--1.38 Mpa). The data from these tests show sulfur removal of 6.0--92.5 wt % and carbon losses of 0.0--25.6 wt %, with the desulfurization susceptibility of char related to porosity, density, and crystallite size. The relationships among mild gasification parameters, char properties, and char desulfurization susceptibility are being studied. Acid washing of char to remove Ca and Fe is being explored for its effect on subsequent sulfur removal. Secondary desulfurization of form coke produced from the desulfurized chars is also being studied, and a final recommendation will be made for integration of char desulfurization into the IGT MILDGAS process.

Knight, R.A. [Institute of Gas Technology, Chicago, IL (United States); Banerjee, D. [Illinois Clean Coal Inst., Carterville, IL (United States)

1993-05-01T23:59:59.000Z

405

Great Plains Coal Gasification Project:  

Science Conference Proceedings (OSTI)

This progress report on the Great Plains Coal Gasification Project discusses Lignite coal, natural gas, and by-products production as well as gas quality. A tabulation of raw material, product and energy consumption is provided for plant operations. Capital improvement projects and plant maintenance activities are detailed and summaries are provided for environmental, safety, medical, quality assurance, and qualtiy control activities.

Not Available

1988-01-29T23:59:59.000Z

406

Gasification in pulverized coal flames. Semi-annual progress report, September 1977--March 1978  

DOE Green Energy (OSTI)

This project concerns the production of power and synthesis gases from pulverized coal via suspension gasification. Cyclone and confined jet gasifier configurations with swirling flow are being investigated. Emphasis is on the final design and construction of the test facility and the two experimental reactors. Calibration procedures are presented, as are data reduction techniques and preliminary experimental results for methane and coal combustion tests.

Barnhart, J. S.; George, P. E.; Thomas, J. F.; Laurendeau, N. M.

1978-04-01T23:59:59.000Z

407

H2 Enrichment with Simultaneous CO2 Concentration in a Membrane Reactor  

DOE Green Energy (OSTI)

NETL envisions that the gasification of carbonaceous feedstocks may be the near- to mid-term sources of hydrogen for the transition to a renewable, hydrogen-based economy. However, the environmental impacts associated with the generation and emission of greenhouses gases from the gasification process remains a substantial concern. Therefore, NETL has devoted substantial resources towards the identification of efficient hydrogen separation and carbon capture/sequestration technologies. Hydrogen membranes integrated into a water-gas shift membrane reactor have been identified as a promising means of maximizing the production of pure hydrogen while simultaneously yielding a high-pressure, concentrated CO2 containing stream ready for sequestration. Research groups, including NETL, are exploring the viability of dense metal hydrogen membrane technologies to enhance the production and separation of hydrogen as well as the capture of carbon dioxide from the coal gasification process. Areas of research to ensure the success of dense metal membrane technologies for implementation into the gasification scheme includes the fabrication of thin metallic films and support materials, an understanding of the interaction of membrane materials in the presence of both major and minor gas constituents, chemical and temperature induced morphological changes and the identification of new membrane materials through experimental and computational exploration.

Taylor, C.E.; Morreale, B.; Howard, B.H.; Killmeyer, R.P

2007-01-01T23:59:59.000Z

408

INTEGRAL BENCHMARKS AVAILABLE THROUGH THE INTERNATIONAL REACTOR PHYSICS EXPERIMENT EVALUATION PROJECT AND THE INTERNATIONAL CRITICALITY SAFETY BENCHMARK EVALUATION PROJECT  

SciTech Connect

Interest in high-quality integral benchmark data is increasing as efforts to quantify and reduce calculational uncertainties accelerate to meet the demands of next generation reactor and advanced fuel cycle concepts. The International Reactor Physics Experiment Evaluation Project (IRPhEP) and the International Criticality Safety Benchmark Evaluation Project (ICSBEP) continue to expand their efforts and broaden their scope to identify, evaluate, and provide integral benchmark data for method and data validation. Benchmark model specifications provided by these two projects are used heavily by the international reactor physics, nuclear data, and criticality safety communities. Thus far, 14 countries have contributed to the IRPhEP, and 20 have contributed to the ICSBEP. The status of the IRPhEP and ICSBEP is discussed in this paper, and the future of the two projects is outlined and discussed. Selected benchmarks that have been added to the IRPhEP and ICSBEP handbooks since PHYSOR’06 are highlighted, and the future of the two projects is discussed.

J. Blair Briggs; Lori Scott; Enrico Sartori; Yolanda Rugama

2008-09-01T23:59:59.000Z

409

Hydrogen production by high-temperature steam gasification of biomass and coal  

Science Conference Proceedings (OSTI)

High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

2009-04-15T23:59:59.000Z

410

An integrated performance model for high temperature gas cooled reactor coated particle fuel  

E-Print Network (OSTI)

The performance of coated fuel particles is essential for the development and deployment of High Temperature Gas Reactor (HTGR) systems for future power generation. Fuel performance modeling is indispensable for understanding ...

Wang, Jing, 1976-

2004-01-01T23:59:59.000Z

411

The role of integral experiments and nuclear cross section evaluations in space nuclear reactor design  

SciTech Connect

The importance of the nuclear and neutronic properties of candidate space reactor materials to the design process has been acknowledged as has been the use of benchmark reactor physics experiments to verify and qualify analytical tools used in design, safety, and performance evaluation. Since June 1966, the Cross Section Evaluation Working Group (CSEWG) has acted as an interagency forum for the assessment and evaluation of nuclear reaction data used in the nuclear design process. CSEWG data testing has involved the specification and calculation of benchmark experiments which are used widely for commercial reactor design and safety analysis. These benchmark experiments preceded the issuance oflthe industry standards for acceptance, but the benchmarks exceed the minimum acceptance criteria for such data. Thus, a starting place has been provided in assuring the accuracy and uncertainty of nuclear data important to space reactor applications. (FI)

Moses, D.L.; McKnight, R.D.

1987-01-01T23:59:59.000Z

412

Determination of Optimal Process Flowrates and Reactor Design for Autothermal Hydrogen Production in a Heat-Integrated Ceramic Microchannel Network  

E-Print Network (OSTI)

The present work aimed at designing a thermally efficient microreactor system coupling methanol steam reforming with methanol combustion for autothermal hydrogen production. A preliminary study was performed by analyzing three prototype reactor configurations to identify the optimal radial distribution pattern upon enhancing the reactor self-insulation. The annular heat integration pattern of Architecture C showed superior performance in providing efficient heat retention to the system with a 50 - 150 degrees C decrease in maximum external-surface temperature. Detailed work was performed using Architecture C configuration to optimize the catalyst placement in the microreactor network, and optimize reforming and combustion flows, using no third coolant line. The optimized combustion and reforming catalyst configuration prevented the hot-spot migration from the reactor midpoint and enabled stable reactor operation at all process flowrates studied. Best results were obtained at high reforming flowrates (1800 sccm) with an increase in combustion flowrate (300 sccm) with the net H2 yield of 53% and thermal efficiency of >80% from methanol with minimal insulation to the heatintegrated microchannel network. The use of the third bank of channels for recuperative heat exchange by four different reactor configurations was explored to further enhance the reactor performance; the maximum overall hydrogen yield was increased to 58% by preheating the reforming stream in the outer 16 heat retention channels. An initial 3-D COMSOL model of the 25-channeled heat-exchanger microreactor was developed to predict the reactor hotspot shape, location, optimum process flowrates and substrate thermal conductivity. This study indicated that low thermal conductivity materials (e.g. ceramics, glass) provides enhanced efficiencies than high conductivity materials (e.g. silicon, stainless steel), by maintaining substantial thermal gradients in the system through minimization of axial heat conduction. Final summary of the study included the determination of system energy density; a gravimetric energy density of 169.34 Wh/kg and a volumetric energy density of 506.02 Wh/l were achieved from brass architectures for 10 hrs operation, which is higher than the energy density of Li-Ion batteries (120 Wh/kg and 350 Wh/l). Overall, this research successfully established the optimal process flowrates and reactor design to enhance the potential of a thermally-efficient heat-exchanger microchannel network for autothermal hydrogen production in portable applications.

Damodharan, Shalini

2012-05-01T23:59:59.000Z

413

Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1  

SciTech Connect

Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. (Institute of Gas Technology, Chicago, IL (United States)); Duthie, R.G. (Bechtel Group, Inc., San Francisco, CA (United States)); Wootten, J.M. (Peabody Holding Co., Inc., St. Louis, MO (United States))

1991-09-01T23:59:59.000Z

414

THE INTEGRATION OF PROCESS HEAT APPLICATIONS TO HIGH TEMPERATURE GAS REACTORS  

SciTech Connect

A high temperature gas reactor, HTGR, can produce industrial process steam, high-temperature heat-transfer gases, and/or electricity. In conventional industrial processes, these products are generated by the combustion of fossil fuels such as coal and natural gas, resulting in significant emissions of greenhouse gases such as carbon dioxide. Heat or electricity produced in an HTGR could be used to supply process heat or electricity to conventional processes without generating any greenhouse gases. Process heat from a reactor needs to be transported by a gas to the industrial process. Two such gases were considered in this study: helium and steam. For this analysis, it was assumed that steam was delivered at 17 MPa and 540 C and helium was delivered at 7 MPa and at a variety of temperatures. The temperature of the gas returning from the industrial process and going to the HTGR must be within certain temperature ranges to maintain the correct reactor inlet temperature for a particular reactor outlet temperature. The returning gas may be below the reactor inlet temperature, ROT, but not above. The optimal return temperature produces the maximum process heat gas flow rate. For steam, the delivered pressure sets an optimal reactor outlet temperature based on the condensation temperature of the steam. ROTs greater than 769.7 C produce no additional advantage for the production of steam.

Michael G. McKellar

2011-11-01T23:59:59.000Z

415

Current status of the Run-Beyond-Cladding Breach (RBCB) tests for the Integral Fast Reactor (IFR). Metallic Fuels Program  

Science Conference Proceedings (OSTI)

This paper describes the results from the Integral Fast Reactor (IFR) metallic fuel Run-Beyond-Cladding-Breach (RBCB) experiments conducted in the Experimental Breeder Reactor II (EBR-II). Included in the report are scoping test results and the data collected from the prototypical tests as well as the exam results and discussion from a naturally occurring breach of one of the lead IFR fuel tests. All results showed a characteristic delayed neutron and fission gas release pattern that readily allows for identification and evaluation of cladding breach events. Also, cladding breaches are very small and do not propagate during extensive post breach operation. Loss of fuel from breached cladding was found to be insignificant. The paper will conclude with a brief description of future RBCB experiments planned for irradiation in EBR-II.

Batte, G.L.; Pahl, R.G. [Argonne National Lab., Idaho Falls, ID (United States); Hofman, G.L. [Argonne National Lab., IL (United States)

1993-09-01T23:59:59.000Z

416

Updated Generation IV Reactors Integrated Materials Technology Program Plan, Revision 2  

SciTech Connect

The Department of Energy's (DOE's) Generation IV Nuclear Energy Systems Program will address the research and development (R&D) necessary to support next-generation nuclear energy systems. Such R&D will be guided by the technology roadmap developed for the Generation IV International Forum (GIF) over two years with the participation of over 100 experts from the GIF countries. The roadmap evaluated over 100 future systems proposed by researchers around the world. The scope of the R&D described in the roadmap covers the six most promising Generation IV systems. The effort ended in December 2002 with the issue of the final Generation IV Technology Roadmap [1.1]. The six most promising systems identified for next generation nuclear energy are described within the roadmap. Two employ a thermal neutron spectrum with coolants and temperatures that enable hydrogen or electricity production with high efficiency (the Supercritical Water Reactor - SCWR and the Very High Temperature Reactor - VHTR). Three employ a fast neutron spectrum to enable more effective management of actinides through recycling of most components in the discharged fuel (the Gas-cooled Fast Reactor - GFR, the Lead-cooled Fast Reactor - LFR, and the Sodium-cooled Fast Reactor - SFR). The Molten Salt Reactor (MSR) employs a circulating liquid fuel mixture that offers considerable flexibility for recycling actinides, and may provide an alternative to accelerator-driven systems. A few major technologies have been recognized by DOE as necessary to enable the deployment of the next generation of advanced nuclear reactors, including the development and qualification of the structural materials needed to ensure their safe and reliable operation. Accordingly, DOE has identified materials as one of the focus areas for Gen IV technology development.

Corwin, William R [ORNL; Burchell, Timothy D [ORNL; Halsey, William [Lawrence Livermore National Laboratory (LLNL); Hayner, George [Idaho National Laboratory (INL); Katoh, Yutai [ORNL; Klett, James William [ORNL; McGreevy, Timothy E [ORNL; Nanstad, Randy K [ORNL; Ren, Weiju [ORNL; Snead, Lance Lewis [ORNL; Stoller, Roger E [ORNL; Wilson, Dane F [ORNL

2005-12-01T23:59:59.000Z

417

Investigation of gasification of biomass in the presence of catalysts  

DOE Green Energy (OSTI)

The overall objective of this study is to determine the technical and economic feasibility of catalyzed biomass gasification to produce specific products: (a) methane, (b) hydrogen, (c) carbon monoxide, and (d) synthesis gases for generation of ammonia, methanol, or hydrocarbons. Work to achieve the objectives of this study was continued in the laboratory and process development unit (PDU). Laboratory studies further defined the effect of primary catalyst concentration on gasification rate. Systems for direct generation of ammonia synthesis gas and hydrogen were defined at the laboratory scale. No promising system for direct carbon monoxide production was found. A new wood feed system was installed in the PDU and has proved to be reliable and effective for metering wood into the gasifier. New heaters installed in the PDU reactor have greatly improved temperature control in the system. Preliminary calculations on the feasibility of catalyzed gasification of wood to produce methanol are encouraging. Potential methanol yield is about 180 gallons per dry ton of wood. Energy efficiency of the process would be 68%. Details of the results obtained since the last contractors' meeting are presented in the discussion. Status of the project is also presented.

Mudge, L.K.; Robertus, R.J.; Sealock, L.J. Jr.; Mitchell, D.H.; Weber, S.L.; Stegen, G.E.

1979-01-01T23:59:59.000Z

418

Economic Analysis of a 3MW Biomass Gasification Power Plant  

E-Print Network (OSTI)

Collaborative, Biomass gasification / power generationANALYSIS OF A 3MW BIOMASS GASIFICATION POWER PLANT R obert Cas a feedstock for gasification for a 3 MW power plant was

Cattolica, Robert; Lin, Kathy

2009-01-01T23:59:59.000Z

419

Pioneering Gasification Plants | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification » Pioneering Gasification » Pioneering Gasification Plants Pioneering Gasification Plants In the 1800s, lamplighters made their rounds in the streets of many of America's largest cities lighting street lights fueled by "town gas," frequently the product of early forms of coal gasification. Gasification of fuel also provided fuel for steel mills, and toward the end of the 19th Century, electric power. These early gasifiers were called "gas producers," and the gas that they generated was called "producer gas." During the early 20th Century, improvements in the availability of petroleum and natural gas products, along with the extension of the infrastructure associated with these products, led to their widespread use, which replaced coal-based producer gas in the energy market.

420

NETL: Gasification Systems - Gas Cleaning  

NLE Websites -- All DOE Office Websites (Extended Search)

Cleaning Cleaning Chemicals from Coal Complex Chemicals from Coal Complex (Eastman Company) Novel gas cleaning and conditioning are crucial technologies for achieving near-zero emissions, while meeting gasification system performance and cost targets. DOE's Gasification Systems program supports technology development in the area of gas cleaning and conditioning, including advanced sorbents and solvents, particulate filters, and other novel gas-cleaning approaches that remove and convert gas contaminants into benign and marketable by-products. To avoid the cost and efficiency penalties associated with cooling the gas stream to temperatures at which conventional gas clean-up systems operate, novel processes are being developed that operate at mild to high temperatures and incorporate multi-contaminant control to

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