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1

Modeling and Optimization of Membrane Reactors for Carbon Capture in Integrated Gasification Combined Cycle Units  

Science Journals Connector (OSTI)

Modeling and Optimization of Membrane Reactors for Carbon Capture in Integrated Gasification Combined Cycle Units ... This paper investigates the alternative of precombustion capture of carbon dioxide from integrated gasification combined cycle (IGCC) plants using membrane reactors equipped with H2-selective zeolite membranes for the water gas shift reaction. ...

Fernando V. Lima; Prodromos Daoutidis; Michael Tsapatsis; John J. Marano

2012-03-08T23:59:59.000Z

2

Integrated Gasification Combined Cycle Dynamic Model: H2S Absorption/Stripping, Water?Gas Shift Reactors, and CO2 Absorption/Stripping  

Science Journals Connector (OSTI)

Integrated Gasification Combined Cycle Dynamic Model: H2S Absorption/Stripping, Water?Gas Shift Reactors, and CO2 Absorption/Stripping ... Future chemical plants may be required to have much higher flexibility and agility than existing process facilities in order to be able to handle new hybrid combinations of power and chemical units. ...

Patrick J. Robinson; William L. Luyben

2010-04-26T23:59:59.000Z

3

Integrated Gasification Combined Cycle Based on Pressurized Fluidized Bed Gasification  

Science Journals Connector (OSTI)

Enviropower Inc. has developed a modern power plant concept based on an integrated pressurized fluidized bed gasification and gas turbine combined cycle (IGCC)....

Kari Salo; J. G. Patel

1997-01-01T23:59:59.000Z

4

Integrated Coal Gasification Power Plant Credit (Kansas)  

Energy.gov (U.S. Department of Energy (DOE))

Integrated Coal Gasification Power Plant Credit states that an income taxpayer that makes a qualified investment in a new integrated coal gasification power plant or in the expansion of an existing...

5

DOE Hydrogen Analysis Repository: Biomass Integrated Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Biomass Integrated Gasification Combined-Cycle Power Systems Biomass Integrated Gasification Combined-Cycle Power Systems Project Summary Full Title: Cost and Performance Analysis of Biomass-Based Integrated Gasification Combined-Cycle (BIGCC) Power Systems Project ID: 106 Principal Investigator: Margaret Mann Brief Description: This project examines the cost and performance potential of three biomass-based integrated gasification combined cycle (IGCC) systems--high-pressure air blown, low-pressure air blown, and low-pressure indirectly heated. Purpose Examine the cost and performance potential of three biomass-based integrated gasification combined cycle (IGCC) systems - a high pressure air-blown, a low pressure indirectly heated, and a low pressure air-blown. Performer Principal Investigator: Margaret Mann

6

Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper  

SciTech Connect

This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

A.M. Gandrik

2012-04-01T23:59:59.000Z

7

Solar coal gasification reactor with pyrolysis gas recycle  

DOE Patents (OSTI)

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

8

Flow Simulation and Optimization of Plasma Reactors for Coal Gasification  

Science Journals Connector (OSTI)

This paper reports a 3-d numerical simulation system to analyze the complicated flow in plasma reactors for coal gasification, which involve complex chemical reaction, two-phase flow and plasma effect. On the basis of analytic results, the distribution of the density, temperature and components' concentration are obtained and a different plasma reactor configuration is proposed to optimize the flow parameters. The numerical simulation results show an improved conversion ratio of the coal gasification. Different kinds of chemical reaction models are used to simulate the complex flow inside the reactor. It can be concluded that the numerical simulation system can be very useful for the design and optimization of the plasma reactor.

Ji Chunjun; Zhang Yingzi; Ma Tengcai

2003-01-01T23:59:59.000Z

9

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

10

Improved System Integration for Integrated Gasification Combined Cycle (IGCC) Systems  

Science Journals Connector (OSTI)

Improved System Integration for Integrated Gasification Combined Cycle (IGCC) Systems ... The model is applied to evaluate integration schemes involving nitrogen injection, air extraction, and combinations of both, as well as different ASU pressure levels. ... The optimal nitrogen injection only case in combination with an elevated pressure ASU had the highest efficiency and power output and approximately the lowest emissions per unit output of all cases considered, and thus is a recommended design option. ...

H. Christopher Frey; Yunhua Zhu

2006-02-02T23:59:59.000Z

11

Coal Integrated Gasification Fuel Cell System Study  

SciTech Connect

This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

2004-01-31T23:59:59.000Z

12

Heavy metals behaviour in a gasification reactor  

Science Journals Connector (OSTI)

Sludge coming from cleaning processes of wastewater, Municipal Solid Waste (MSW), and Refuse Derived Fuel (RDF) can be exploited for producing energy because of their heating value. Cleaning the produced syngas is important because of environmental troubles, ... Keywords: heavy metals, syngas, thermodynamic, waste gasification

Martino Paolucci; Carlo Borgianni; Paolo De Filippis

2011-07-01T23:59:59.000Z

13

Coal Gasification in a Transport Reactor  

Science Journals Connector (OSTI)

These simulations were used to compare the response of coals gasified to those combusted substoichiometrically, to evaluate the optimum operating conditions and to predict the performance in larger-scale units with less heat loss. ... Entrained-flow gasifiers use high temperatures (1350?1550 °C) and gasify coals in 2?3 s. ... Kinetic studies were carried out to elucidate the mechanisms of steam and CO2 gasification of char and the interactions of these gasifying agents. ...

Lawrence J. Shadle; Esmail R. Monazam; Michael L. Swanson

2001-05-25T23:59:59.000Z

14

EIS-0431: Hydrogen Energy California's Integrated Gasification Combined  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Hydrogen Energy California's Integrated Gasification 1: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California EIS-0431: Hydrogen Energy California's Integrated Gasification Combined Cycle and Carbon Capture and Sequestration Project, California Summary This EIS evaluates the potential environmental impacts of a proposal to provide financial assistance for the construction and operation of Hydrogen Energy California LLC (HECA's) project, which would produce and sell electricity, carbon dioxide and fertilizer. DOE selected this project for an award of financial assistance through a competitive process under the Clean Coal Power Initiative program. Public Comment Opportunities None available at this time. Documents Available for Download September 5, 2013

15

A Texas project illustrates the benefits of integrated gasification  

SciTech Connect

Gasification can be an attractive option for converting a variety of petroleum feedstocks to chemicals. Natural gas is commonly sued to produce acetic acid, isocyanates, plastics, and fibers. But low-cost, bottom-of-the-barrel feeds, such as vacuum resid, petroleum coke, and asphaltenes, also can be used. In any case, gasification products include synthesis gas, carbon monoxide, hydrogen, steam, carbon dioxide, and power. The more a gasification facility is integrated with utilities and other non-core operations of a production complex, the more economical the products are for all consumers. The paper discusses gasification of natural gas, light hydrocarbons (ethane, propanes, and butanes), and heavy hydrocarbons (distillates, heavy residues, asphalts, coals, petroleum coke). The paper then describes a Texas City Gasification Project, which gasifies methane to produce carbon monoxide, hydrogen, and alcohol. The plant is integrated with a cogeneration plant. Economics are discussed.

Philcox, J. [Praxair Inc., Houston, TX (United States); Fenner, G.W. [Praxair Inc., Tonawanda, NY (United States)

1997-07-14T23:59:59.000Z

16

Avestar® - Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator The AVESTAR® center offers courses using the Integrated Gasification Combined Cycle (IGCC) Dynamic Simulator. The IGCC simulator builds on and reaches beyond existing combined-cycle and conventional-coal power plant simulators to combine--for the first time--a Gasification with CO2 Capture process simulator with a Combined-Cycle power simulator together in a single dynamic simulation framework. The AVESTAR® center IGCC courses provide unique, comprehensive training on all aspects of an IGCC plant, illustrating the high-efficiency aspects of the gasifier, gas turbine, and steam turbine integration. IGCC Operator training station HMI display for overview of IGCC Plant - Train A Reference:

17

Integration Strategy of Gasification Technology:? A Gateway to Future Refining  

Science Journals Connector (OSTI)

The historical evidence of the operation of a coal gasification plant goes as far back in time as 1878.1 The United State's first power plant based on coal gasification technology was installed in 1980.2 The concept of gasification has begun to attract much attention from the refining industry because of stringent environmental regulations on transportation fuel, slashing demands for fuel oils, and uncertainty in the availability of good crude oils. ... Therefore, it is a challenging task for refining industries to economically integrate gasification technology, and this is the major theme of the paper. ... Gasification is superior to many of the available power production and waste disposal technologies by addressing various issues together regarding environmental emissions, maintaining quality of refining products, and waste management. ...

Jhuma Sadhukhan; X. X. Zhu

2002-02-09T23:59:59.000Z

18

Analysis of Biomass/Coal Co-Gasification for Integrated Gasification Combined Cycle (IGCC) Systems with Carbon Capture.  

E-Print Network (OSTI)

?? In recent years, Integrated Gasification Combined Cycle Technology (IGCC) has become more common in clean coal power operations with carbon capture and sequestration (CCS).… (more)

Long, Henry A, III

2011-01-01T23:59:59.000Z

19

Automobile Shredder Residue (ASR) destruction in a plasma gasification reactor  

Science Journals Connector (OSTI)

Test results on Automobile Shredder Residue (ASR), or car fluff, demonstrated destruction efficiency and safe conversion to synthesis gas and a glass residue, in a plasma gasification system. The synthesis gas consists primarily of hydrogen and carbon monoxide in the range between 20 and 22 vol-% respectively, or 45 and 55 vol-% dry basis, when corrected for nitrogen. In dry reforming operation, carbon dioxide conversion approached 90%. The system is designed to work with oxygen in autothermal conditions, reducing thus the electric power requirement for the plasma reactor. The vitrified residue leach rate makes the product suitable for construction works.

Marco G. Tellini; Paolo Centola; James A. Batdorf; William J. Quapp

2007-01-01T23:59:59.000Z

20

Integration of carbonate fuel cells with advanced coal gasification systems  

SciTech Connect

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation`s carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. [Energy Research Corp., Danbury, CT (United States); Meyers, S.J. [Fluor Daniel, Inc., Irvine, CA (United States); Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

1992-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Integration of carbonate fuel cells with advanced coal gasification systems  

SciTech Connect

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation's carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. (Energy Research Corp., Danbury, CT (United States)); Meyers, S.J. (Fluor Daniel, Inc., Irvine, CA (United States)); Hauserman, W.B. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

1992-01-01T23:59:59.000Z

22

Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas-phase chemistry  

E-Print Network (OSTI)

Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas: Coal gasification Carbon gasification Detailed chemistry Heterogeneous surface reactions Radiation Multi-physics numerical modeling a b s t r a c t Fuel synthesis through coal and biomass gasification

Qiao, Li

23

Mathematical Modeling of Coal Gasification Processes in a Well-Stirred Reactor: Effects of Devolatilization and Moisture Content  

E-Print Network (OSTI)

Mathematical Modeling of Coal Gasification Processes in a Well- Stirred Reactor: Effects in coal and biomass play an important role on the gasification performance of these fuels to simulate the gasification processes in a well-stirred reactor. This model is a first

Qiao, Li

24

EIS-0409: Kemper County Integrated Gasification Combined Cycle Project, Mississippi  

Energy.gov (U.S. Department of Energy (DOE))

This EIS analyzes DOE's decision to provide funding for the Kemper County Integrated Gasification Combined Cycle Project in Kemper County, Mississippi to assess the potential environmental impacts associated with the construction and operation of a project proposed by Southern Power Company, through its affiliate Mississippi Power Company, which has been selected by DOE for consideration under the Clean Coal Power Initiative (CCPI) program.

25

Advanced CO2 Capture Technology for Low Rank Coal Integrated Gasification Combined Cycle (IGCC) Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

CO CO 2 Capture Technology for Low Rank Coal Integrated Gasification Combined Cycle (IGCC) Systems Background Gasification of coal or other solid feedstocks (wood waste, petroleum coke, etc.) is a clean way to produce electricity and produce or co-produce a variety of commercial products. The major challenge is cost reduction; current integrated gasification combined cycle (IGCC) technology is estimated to produce power at a cost higher than that of pulverized coal combustion. However, the Gasification

26

Integrated gasification fuel cell (IGFC) demonstration test  

SciTech Connect

As concern about the environment generates interest in ultra-clean energy plants, fuel cell power plants can respond to the challenge. Fuel cells convert hydrocarbon fuels to electricity at efficiencies exceeding conventional heat engine technologies while generating extremely low emissions. Emissions of SOx and NOx are expected to be well below current and anticipated future standards. Nitrogen oxides, a product of combustion, will be extremely low in this power plant because power is produced electrochemically rather than by combustion. Due to its higher efficiencies, a fuel cell power plant also produces less carbon dioxide. Fuel cells in combination with coal gasification, are an efficient and environmentally acceptable means to utilize the abundant coal reserves both in the US and around the world. To demonstrate this technology, FuelCell Energy, Inc. (FCE), is planning to build and test a 2-MW Fuel Cell Power Plant for operation on coal derived gas. This power plant is based on Direct Fuel Cell (DFC{trademark}) technology and will be part of a Clean Coal V IGCC project supported by the US DOE. A British Gas Lurgi (BGL) slagging fixed-bed gasification system with cold gas clean up is planned as part of a 400 MW IGCC power plant to provide a fuel gas slip stream to the fuel cell. The IGFC power plant will be built by Kentucky Pioneer Energy, A subsidiary of Global Energy, in Clark County, KY. This demonstration will result in the world's largest fuel cell power plant operating on coal derived gas. The objective of this test is to demonstrate fuel cell operation on coal derived gas at a commercial scale and to verify the efficiency and environmental benefits.

Steinfeld, G.; Ghezel-Ayagh, H.; Sanderson, R.; Abens, S.

2000-07-01T23:59:59.000Z

27

Benefits of Integrating PWR and RTI Advanced Gasification Technologies for  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Processing Systems Syngas Processing Systems Benefits of Integrating PWR and RTI Advanced Gasification Technologies for Hydrogen-Rich Syngas Production Research Triangle Institute (RTI) Project Number: FE0012066 Project Description The project will assess the potential for integrated advanced technologies to substantially reduce capital and production costs for hydrogen-rich syngas with near-zero emissions from coal gasification for power production with carbon capture and for coal-to-liquids (specifically methanol) with carbon capture. These integrated technologies include those already tested successfully at pilot-scale with a new and innovative water-gas-shift technology, to show how multiple advanced technologies will leverage each other for significant cost and efficiency gains.

28

Method for the operation of internal combustion engines. [gasification reactor for reforming gasoline  

SciTech Connect

This is a method for the operation of internal combustion engines which is designed to decontaminate the exhaust gases. The method includes: feeding a gasification air stream into a gasification reactor; feeding fuel into the same gasification reactor; combining the fuel with the gasification air into a homogeneous fuel-air mixture in the gasification reactor; and converting the fuel-air mixture by partial combustion into a soot -free reformed gas. Then, the reformed gas is fed from the gasification reactor to a mixer where the reformed gas is mixed with combustion air and the reformed gas-air mixture is fed to the internal combustion engine for further combustion with the result that there is intensive decontamination of the exhaust gases which thereby reduces air pollution. The reformed gas temperature is adjusted low for maximum engine output, and is adjusted higher for lower engine temperatures in order to obtain a reformed gas which is richer in hydrogen and thereby produce exhaust gases which are lower in harmful substances. In reference to the exhaust gases in an internal combustion engine, this method achieves the highest possible degree of decontamination, not only of the carbon monoxide and hydrocarbons , but also of the nitrous oxides in the exhaust gases. Using this method, the internal combustion engine can be operated not only with high-test, no-knock gasoline, but also with cheap, lead-free low octane, straight-run gasoline which is low in aromatics and olefins, which normally do not have no-knock properties, and the internal combustion engine can be operated with the lowest possible fuel consumption. The gasification reactor operates through chemical reaction in the presence of a catalyst. Optionally, this method may include a return of part of the reformed gas to the input of the gasification reactor.

Muhlberg, E.

1980-01-29T23:59:59.000Z

29

Application of the integrated gasification combined cycle technology and BGL gasification design for power generation  

SciTech Connect

Integrated gasification combined cycle (IGCC) technology promises to be the power generation technology of choice in the late 1990s and beyond. Based on the principle that almost any fuel can be burned more cleanly and efficiently if first turned into a gas, an IGCC plant extracts more electricity from a ton of coal by burning it as a gas in a turbine rather than as a solid in a boiler. Accordingly, coal gasification is the process of converting coal to a clean-burning synthetic gas. IGCC technology is the integration of the coal-gasification plant with a conventional combined-cycle plant to produce electricity. The benefits of this technology merger are many and result in a highly efficient and environmentally superior energy production facility. The lGCC technology holds significant implications for Asia-Pacific countries and for other parts of the world. High-growth regions require additional baseload capacity. Current low prices for natural gas and minimal emissions that result from its use for power generation favor its selection as the fuel source for new power generation capacity. However, fluctuations in fuel price and fuel availability are undermining the industry`s confidence in planning future capacity based upon gas-fueled generation. With the world`s vast coal reserves, there is a continuing effort to provide coal-fueled power generation technologies that use coal cleanly and efficiently. The lGCC technology accomplishes this objective. This chapter provides a summary of the status of lGCC technology and lGCC projects known to date. It also will present a technical overview of the British Gas/Lurgi (BGL) technology, one of the leading and most promising coal gasifier designs.

Edmonds, R.F. Jr.; Hulkowich, G.J.

1993-12-31T23:59:59.000Z

30

Entrainment Coal Gasification Modeling  

Science Journals Connector (OSTI)

Entrainment Coal Gasification Modeling ... Equivalent Reactor Network Model for Simulating the Air Gasification of Polyethylene in a Conical Spouted Bed Gasifier ... Equivalent Reactor Network Model for Simulating the Air Gasification of Polyethylene in a Conical Spouted Bed Gasifier ...

C. Y. Wen; T. Z. Chaung

1979-10-01T23:59:59.000Z

31

THERMODYNAMIC MODELLING OF BIOMASS INTEGRATED GASIFICATION COMBINED CYCLE (BIGCC) POWER GENERATION SYSTEM.  

E-Print Network (OSTI)

??An attractive and practicable possibility of biomass utilization for energy production is gasification integrated with a combined cycle. This technology seems to have the possibility… (more)

Desta, Melaku

2011-01-01T23:59:59.000Z

32

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect

The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

Michael L. Swanson

2005-08-30T23:59:59.000Z

33

"Integrated Gasification Combined Cycle"  

U.S. Energy Information Administration (EIA) Indexed Site

Status of technologies and components modeled by EIA" Status of technologies and components modeled by EIA" ,"Revolutionary","Evolutionary","Mature" "Pulverized Coal",,,"X" "Pulverized Coal with CCS" " - Non-CCS portion of Pulverized Coal Plant",,,"X" " - CCS","X" "Integrated Gasification Combined Cycle" " - Advanced Combustion Turbine",,"X" " - Heat Recovery Steam Generator",,,"X" " - Gasifier",,"X" " - Balance of Plant",,,"X" "Conventional Natural Gas Combined Cycle" " - Conventional Combustion Turbine",,,"X" " - Heat Recovery Steam Generator",,,"X" " - Balance of Plant",,,"X"

34

Integration of coal utilization and environmental control in integrated gasification combined cycle systems  

Science Journals Connector (OSTI)

Integration of coal utilization and environmental control in integrated gasification combined cycle systems ... The Cost of Carbon Capture and Storage for Natural Gas Combined Cycle Power Plants ... The Cost of Carbon Capture and Storage for Natural Gas Combined Cycle Power Plants ...

H. Christopher Frey; Edward S. Rubin

1992-10-01T23:59:59.000Z

35

Life Cycle Analysis: Integrated Gasification Combined Cycle (IGCC) Power Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

Life Cycle Analysis: Integrated Life Cycle Analysis: Integrated Gasification Combined Cycle (IGCC) Power Plant Revision 2, March 2012 DOE/NETL-2012/1551 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or

36

NOVEL GAS CLEANING/ CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE  

NLE Websites -- All DOE Office Websites (Extended Search)

INTEGRATED GASIFICATION COMBINED CYCLE VOLUME I - CONCEPTUAL COMMERCIAL EVALUATION OPTIONAL PROGRAM FINAL REPORT September 1, 2001 - December 31, 2005 By Dennis A. Horazak (Siemens), Program Manager Richard A. Newby (Siemens) Eugene E. Smeltzer (Siemens) Rachid B. Slimane (GTI) P. Vann Bush (GTI) James L. Aderhold, Jr. (GTI) Bruce G. Bryan (GTI) December 2005 DOE Award Number: DE-AC26-99FT40674 Prepared for U.S. Department of Energy National Energy Technology Laboratory Prepared by Siemens Power Generation, Inc. 4400 Alafaya Trail Orlando, FL 32826 & Gas Technology Institute 1700 S. Mt. Prospect Rd. Des Plaines, Illinois 60018 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government.

37

Development of an Integrated Multicontaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

an Integrated an Integrated Multicontaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems Background The U.S. has more coal than any other country, and it can be converted through gasification into electricity, liquid fuels, chemicals, or hydrogen. However, for coal gasification to become sufficiently competitive to benefit the U.S. economy and help reduce our dependence on foreign fuels, gasification costs must be reduced

38

An update technology for integrated biomass gasification combined cycle power plant  

Science Journals Connector (OSTI)

A discussion is presented on the technical analysis of a 6.4 MWe integrated biomass gasification combined cycle (IBGCC) plant. It features three numbers ... producing 5.85 MW electrical power in open cycle and 55...

Paritosh Bhattacharya; Suman Dey

2014-01-01T23:59:59.000Z

39

Integration of stripping of fines slurry in a coking and gasification process  

DOE Patents (OSTI)

In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

DeGeorge, Charles W. (Chester, NJ)

1980-01-01T23:59:59.000Z

40

Simulation of petcoke gasification in slagging moving bed reactors  

Science Journals Connector (OSTI)

A mathematical model for simulation of moving bed petcoke gasifiers was developed. The model introduces a new feed characterization method, gas-phase resistance and volatilization models. The model is validated using reported data for a slagging gasifier. Effect of feed oxygen-to-coke and steam-to-coke ratios and feed coke rates on gasification performance was examined. Slagging zone moving bed gasifier operation with very high petcoke fluxes of over 4000 kg/m2/h was possible with high petcoke conversion. Peak gas temperatures exceeded 1500 °C. Fluxes higher than 5000 kg/m2/h are limited by an approach to fluidization of small particles in the combustion zone. The moving bed gasifier performance was found superior to performance of an entrained flow gasifier (EFG) with respect to energy efficiency and oxygen consumption.

Soumitro Nagpal; T.K. Sarkar; P.K. Sen

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Model Predictive Control of Integrated Gasification Combined Cycle Power Plants  

SciTech Connect

The primary project objectives were to understand how the process design of an integrated gasification combined cycle (IGCC) power plant affects the dynamic operability and controllability of the process. Steady-state and dynamic simulation models were developed to predict the process behavior during typical transients that occur in plant operation. Advanced control strategies were developed to improve the ability of the process to follow changes in the power load demand, and to improve performance during transitions between power levels. Another objective of the proposed work was to educate graduate and undergraduate students in the application of process systems and control to coal technology. Educational materials were developed for use in engineering courses to further broaden this exposure to many students. ASPENTECH software was used to perform steady-state and dynamic simulations of an IGCC power plant. Linear systems analysis techniques were used to assess the steady-state and dynamic operability of the power plant under various plant operating conditions. Model predictive control (MPC) strategies were developed to improve the dynamic operation of the power plants. MATLAB and SIMULINK software were used for systems analysis and control system design, and the SIMULINK functionality in ASPEN DYNAMICS was used to test the control strategies on the simulated process. Project funds were used to support a Ph.D. student to receive education and training in coal technology and the application of modeling and simulation techniques.

B. Wayne Bequette; Priyadarshi Mahapatra

2010-08-31T23:59:59.000Z

42

Modelling and simulation of coal and petcoke gasification in a Co-current flow reactor  

Science Journals Connector (OSTI)

A mathematical model is developed for the simulation of the gasification process in a reactor where a carbon slurry is fed together with oxygen and water vapour. The model considers several heterogeneous and homogeneous reactions to estimate flows and composition of the exit gases, including combustion, gasification and hydro-pyrolysis of carbon. Mass and heat-transfer phenomena are described for the particular physical arrangement, including bulk film diffusion processes with variable particle size and heat transfer by radiation from the hot region downstream to the cooler entrance region. Preliminary results are in good agreement with experimental data from a pilot plant, including exit composition and temperatures, and ignition and highest-temperature points. An analysis of the main operational parameters is given, which could be used for the final design of the plant.

Elida M. López; Vicente Garza; Joaquín Acevedo

2006-01-01T23:59:59.000Z

43

Steam Gasification of Cellulose with Cobalt Catalysts in a Fluidized Bed Reactor  

Science Journals Connector (OSTI)

The catalytic performance of Co/MgO catalysts for the treatment of tar derived from cellulose steam gasification in a bubbling fluidized bed gasifier of 22 mm i.d. and 500 mm height was investigated by means of two different methods:? hot gas cleaning in a fixed bed reactor after the fluidized bed gasifier (secondary method) and treatment inside the gasifier with catalyst as a fluidizing medium (primary method). ... From this perspective, developing a more effective catalyst is essential for scaling down the plant size while still facilitating high and stable catalytic performance. ... At 720-760°, space-times 0.10-0.20 s, catalyst sizes <1.0 ...

Kazuhiko Tasaka; Takeshi Furusawa; Atsushi Tsutsumi

2007-01-19T23:59:59.000Z

44

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project, Final Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8 8 U.S. Department of Energy Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project Final Environmental Impact Statement November 2002 U.S. Department of Energy National Energy Technology Laboratory COVER SHEET Responsible Agency: U.S. Department of Energy (DOE) Title: Kentucky Pioneer Integrated Gasification Combined Cycle (IGCC) Demonstration Project Final Environmental Impact Statement (EIS) (DOE/EIS-0318) Location: Clark County, Kentucky Contacts: For further information on this environmental For further information on the DOE National impact statement (EIS), call: Environmental Policy Act (NEPA) process, call: 1-800-432-8330 ext. 5460 1-800-472-2756 or contact: or contact: Mr. Roy Spears Ms. Carol Borgstrom

45

Integrated catalytic coal devolatilization and steam gasification process  

SciTech Connect

Hydrocarbon liquids and a methane-containing gas are produced from carbonaceous feed solids by contacting the solids with a mixture of gases containing carbon monoxide and hydrogen in a devolatilization zone at a relatively low temperature in the presence of a carbon-alkali metal catalyst. The devolatilization zone effluent is treated to condense out hydrocarbon liquids and at least a portion of the remaining methane-rich gas is steam reformed to produce the carbon monoxide and hydrogen with which the carbonaceous feed solids are contacted in the devolatilization zone. The char produced in the devolatilization zone is reacted with steam in a gasification zone under gasification conditions in the presence of a carbon-alkali metal catalyst and the resultant raw product gas is treated to recover a methane-containing gas.

Ryan, D.F.; Wesselhoft, R.D.

1981-09-29T23:59:59.000Z

46

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

Science Journals Connector (OSTI)

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification ... National Bioenergy Center, National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, Colorado 80401, United States ... Similar activation energies (9-10 kcal/mol) were measured for ZnO and Zn-Ti-O sulfidation. ...

Abhijit Dutta; Singfoong Cheah; Richard Bain; Calvin Feik; Kim Magrini-Bair; Steven Phillips

2012-05-23T23:59:59.000Z

47

Equivalent Reactor Network Model for Simulating the Air Gasification of Polyethylene in a Conical Spouted Bed Gasifier  

Science Journals Connector (OSTI)

Equivalent Reactor Network Model for Simulating the Air Gasification of Polyethylene in a Conical Spouted Bed Gasifier ... Plastic waste treatment technologies, apart from chemical recycling, constitute a growing social problem, such as the loss of natural resources, the depletion of landfill space, and the environmental pollution. ...

Yupeng Du; Qi Yang; Abdallah S. Berrouk; Chaohe Yang; Ahmed S. Al Shoaibi

2014-11-06T23:59:59.000Z

48

Steam Gasification of Bio-Oil and Bio-Oil/Char Slurry in a Fluidized Bed Reactor  

Science Journals Connector (OSTI)

In the present study, the steam gasification of bio-oil/char slurry was investigated using a lab-scale fluidized bed reactor filled with either Ni-based naphtha steam reforming catalyst or silica sand. ... LOI: Loss on ignition after a 30 min fusion at 1000 °C. ... Table 5. Product Gas Composition (in Mol %) and Heating Value from Steam Gasification of the Bio-Oil and the Slurry with the Catalyst and the Sand at T ? 800°C, H2O/C ? 5.5, and GC1HSV ? 340 h?1; Wet with Nitrogen and Dry Nitrogen Free Basisa ...

Masakazu Sakaguchi; A. Paul Watkinson; Naoko Ellis

2010-08-23T23:59:59.000Z

49

Biomass Gasification in Supercritical Water  

Science Journals Connector (OSTI)

Biomass Gasification in Supercritical Water† ... A packed bed of carbon within the reactor catalyzed the gasification of these organic vapors in the water; consequently, the water effluent of the reactor was clean. ... A method for removing plugs from the reactor was developed and employed during an 8-h gasification run involving potato wastes. ...

Michael Jerry Antal, Jr.; Stephen Glen Allen; Deborah Schulman; Xiaodong Xu; Robert J. Divilio

2000-10-14T23:59:59.000Z

50

Biomass Gasification-Based Syngas Production for a Conventional Oxo Synthesis Plant—Process Modeling, Integration Opportunities, and Thermodynamic Performance  

Science Journals Connector (OSTI)

Biomass Gasification-Based Syngas Production for a Conventional Oxo Synthesis Plant—Process Modeling, Integration Opportunities, and Thermodynamic Performance ... A small amount of steam (0.4 kton·y–1) is used to control the burner temperature. ...

Maria Arvidsson; Matteo Morandin; Simon Harvey

2014-05-07T23:59:59.000Z

51

Kinetics Of Carbon Gasification  

Science Journals Connector (OSTI)

Kinetics Of Carbon Gasification ... The steam–carbon reaction, which is the essential reaction of the gasification processes of carbon-based feed stocks (e.g., coal and biomass), produces synthesis gas (H2 + CO), a synthetically flexible, environmentally benign energy source. ... Coal Gasification in CO2 and Steam:? Development of a Steam Injection Facility for High-Pressure Wire-Mesh Reactors ...

C. W. Zielke; Everett. Gorin

1957-03-01T23:59:59.000Z

52

Carbon Dioxide Capture from Integrated Gasification Combined Cycle Gas Streams Using the Ammonium Carbonate-Ammonium Bicarbonate Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Integrated Gasification Combined Cycle Gas Streams Using the Ammonium Carbonate- Ammonium Bicarbonate Process Description Current commercial processes to remove carbon dioxide (CO 2 ) from conventional power plants are expensive and energy intensive. The objective of this project is to reduce the cost associated with the capture of CO 2 from coal based gasification processes, which convert coal and other carbon based feedstocks to synthesis gas.

53

Analysis of the energy efficiency of solar aided biomass gasification for pure hydrogen production  

Science Journals Connector (OSTI)

Abstract This paper presents a simulative analysis of the energy efficiency of solar aided biomass gasification for pure hydrogen production. Solar heat has been considered as available at 250 °C in three gasification processes: i) gasification reactor followed by two water gas shift reactors and a pressure swing adsorber; ii) gasification reactor followed by an integrated membrane water gas shift reactor; iii) supercritical gasification reactor followed by two flash separators and a pressure swing adsorber. Simulations are performed with the commercial software Aspen Plus® by considering biomass moisture content and the amount of solar heat as system variables. Results are presented in terms of energy and exergy system efficiency and are discussed and compared with the case of no solar integration.

Lucia Salemme; Marino Simeone; Riccardo Chirone; Piero Salatino

2014-01-01T23:59:59.000Z

54

Catalytic combustor for integrated gasification combined cycle power plant  

DOE Patents (OSTI)

A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

2008-12-16T23:59:59.000Z

55

Syngas Production by Thermochemical Gasification of Carbonaceous Waste Materials in a 150 kWth Packed-Bed Solar Reactor  

Science Journals Connector (OSTI)

The carbonaceous feedstocks experimentally investigated included coal,(9-11) petcoke,(12, 13) cellulose,(14, 15) biochar,(11, 16) and waste materials such as scrap tire chips and powders, dried sewage sludge, industrial sludges, and fluff. ... reactor for the steam-gasification of petcoke, carried out in a high-flux solar furnace. ... A petcoke-water slurry was continuously injected into a solar cavity-receiver to create a vortex flow directly exposed to concd. ...

Christian Wieckert; Albert Obrist; Peter von Zedtwitz; Gilles Maag; Aldo Steinfeld

2013-07-16T23:59:59.000Z

56

NETL: Gasification Systems - Integrated Warm Gas Multicontaminant Cleanup  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas Project Number: DE-FC26-05NT42459 Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas Project ID: DE-FC26-05NT42459 Objective: The objective is to develop a warm multi-contaminant syngas cleaning system for operation between 300 and 700° F. This project will continue development of the RTI warm syngas cleanup technology suite. Based on the field testing results with real syngas from Eastman Chemical Company's gasifier under DOE Contract DE-AC26-99FT40675, additional technical issues need to be addressed to move the technologies used in warm syngas cleaning further towards commercial deployment especially for chemical/fuels production. These issues range from evaluation of startup and standby options for the more developed desulfurization processes to integration and actual pilot plant testing with real coal-derived syngas for the technologies that were tested at bench scale during Phase I. Development shall continue of the warm gas syngas cleaning technology platform through a combination of lab-scale R&D and larger integrated pilot plant testing with real coal-derived syngas as well as process/systems analysis and simulation for optimization of integration and intensification.

57

Feasibility Studies to Improve Plant Availability and Reduce Total Installed Cost in Integrated Gasification Combined Cycle Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Feasibility Studies to Improve Plant Feasibility Studies to Improve Plant Availability and Reduce Total Installed Cost in Integrated Gasification Combined Cycle Plants Background Gasification provides the means to turn coal and other carbonaceous solid, liquid and gaseous feedstocks as diverse as refinery residues, biomass, and black liquor into synthesis gas and valuable byproducts that can be used to produce low-emissions power, clean-burning fuels and a wide range of commercial products to support

58

CFD Modeling of Biomass Gasification Using a Circulating Fluidized Bed Reactor.  

E-Print Network (OSTI)

??Biomass, as a renewable energy resource, can be utilized to generate chemicals, heat, and electricity. Compared with biomass combustion, biomass gasification is more eco-friendly because… (more)

Liu, Hui

2014-01-01T23:59:59.000Z

59

CO2 Gasification Rates of Petroleum Coke in a Pressurized Flat-Flame Burner Entrained-Flow Reactor  

Science Journals Connector (OSTI)

Two petcoke samples were gasified by CO2 at total pressures of 10 and 15 atm in a high-pressure flat-flame burner reactor at conditions where the bulk phase consisted of either 40 or 90 mol % CO2 with gas temperatures up to 1909 K. Particle diameters of 45–75 ?m were used in the experiments. ... The mass release data caused by CO2 gasification of the petcoke chars were fit to a global first-order model, and the optimal kinetic parameters are reported. ... The CO2 char gasification rates of both petcokes were shown to be higher than Illinois #6 coal when reacted at conditions of high temperature and pressure, even though most reactivity comparisons between petcoke and coal at lower temperature, pressure, and heating rates typically result in coal being more reactive. ...

Aaron D. Lewis; Emmett G. Fletcher; Thomas H. Fletcher

2014-06-05T23:59:59.000Z

60

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxygen Oxygen Commercial Technologies for Oxygen Production Gasification processes require an oxidant, most commonly oxygen; less frequently air or just steam may suffice as the gasification agent depending on the process. Oxygen-blown systems have the advantage of minimizing the size of the gasification reactor and its auxiliary process systems. However, the oxygen for the process must be separated from the atmosphere. Commercial large-scale air separation plants are based on cryogenic distillation technology, capable of supplying oxygen at high purity1 and pressure. This technology is well understood, having been in practice for over 75 years. Cryogenic air separation is recognized for its reliability, and it can be designed for high capacity (up to 5,000 tons per day).

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Gasification Characteristics of Coal/Biomass Blend in a Dual Circulating Fluidized Bed Reactor  

Science Journals Connector (OSTI)

circulating flow/forestry, agricultural waste, industry wastes + coalcoke ... Whereas, a dual fluidized bed gasification technology enables production of the medium calorific value gas (12?18 MJ/Nm3) by separating the combustion and gasification zones in which steam is used as a gasifying agent. ... Since Quercus acutissima is widely used in building, pulp, and shipping industries, its demand and supply in Korea is high. ...

Myung Won Seo; Jeong Hoi Goo; Sang Done Kim; See Hoon Lee; Young Chan Choi

2010-04-23T23:59:59.000Z

62

CoalFleet RD&D augmentation plan for integrated gasification combined cycle (IGCC) power plants  

SciTech Connect

To help accelerate the development, demonstration, and market introduction of integrated gasification combined cycle (IGCC) and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiative, which facilitates collaborative research by more than 50 organizations from around the world representing power generators, equipment suppliers and engineering design and construction firms, the U.S. Department of Energy, and others. This group advised EPRI as it evaluated more than 120 coal-gasification-related research projects worldwide to identify gaps or critical-path activities where additional resources and expertise could hasten the market introduction of IGCC advances. The resulting 'IGCC RD&D Augmentation Plan' describes such opportunities and how they could be addressed, for both IGCC plants to be built in the near term (by 2012-15) and over the longer term (2015-25), when demand for new electric generating capacity is expected to soar. For the near term, EPRI recommends 19 projects that could reduce the levelized cost-of-electricity for IGCC to the level of today's conventional pulverized-coal power plants with supercritical steam conditions and state-of-the-art environmental controls. For the long term, EPRI's recommended projects could reduce the levelized cost of an IGCC plant capturing 90% of the CO{sub 2} produced from the carbon in coal (for safe storage away from the atmosphere) to the level of today's IGCC plants without CO{sub 2} capture. EPRI's CoalFleet for Tomorrow program is also preparing a companion RD&D augmentation plan for advanced-combustion-based (i.e., non-gasification) clean coal technologies (Report 1013221). 7 refs., 30 figs., 29 tabs., 4 apps.

NONE

2007-01-15T23:59:59.000Z

63

Coal Gasification Report.indb  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Coal Integrated Coal Gasification Combined Cycle: Market Penetration Recommendations and Strategies Produced for the Department of Energy (DOE)/ National Energy Technology Laboratory (NETL) and the Gasification Technologies Council (GTC) September 2004 Coal-Based Integrated Gasification Combined Cycle: Market Penetration Strategies and Recommendations Final Report Study Performed by:

64

Gasification system  

DOE Patents (OSTI)

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

1985-01-01T23:59:59.000Z

65

Gasification system  

DOE Patents (OSTI)

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

1983-01-01T23:59:59.000Z

66

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

NLE Websites -- All DOE Office Websites (Extended Search)

EnhancEd hydrogEn Production EnhancEd hydrogEn Production intEgratEd with co 2 SEParation in a SinglE-StagE rEactor Description One alternative for the United States to establish independence from foreign energy sources is to utilize the nation's abundant domestic reserves of coal. Gasification provides a route to produce liquid fuels, chemical feedstocks, and hydrogen from coal. Coal continues to be viewed as the fuel source for the 21st century. Products from coal gasification, however, contain other gases, particularly carbon dioxide, as well as other contaminants that must be removed to produce the pure stream of hydrogen needed to operate fuel cells and other devices. This project seeks to demonstrate a technology to efficiently produce a pure hydrogen stream from

67

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project, Final Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

S-1 S-1 SUMMARY The U.S. Department of Energy (DOE) prepared this environmental impact statement (EIS) on the proposed Kentucky Pioneer Integrated Gasification Combined Cycle (IGCC) Demonstration Project in compliance with the National Environmental Policy Act (NEPA). The National Environmental Policy Act Process NEPA is a federal law that serves as the basic national charter for protection of the environment. For major federal actions that may significantly affect the quality of the environment, NEPA requires federal agencies to prepare a detailed statement that includes the potential environmental impacts of the Proposed Action and reasonable alternatives. A fundamental objective of NEPA is to foster better decisionmaking by ensuring that high quality environmental information is available to public officials and members of the

68

Method and system to estimate variables in an integrated gasification combined cycle (IGCC) plant  

DOE Patents (OSTI)

System and method to estimate variables in an integrated gasification combined cycle (IGCC) plant are provided. The system includes a sensor suite to measure respective plant input and output variables. An extended Kalman filter (EKF) receives sensed plant input variables and includes a dynamic model to generate a plurality of plant state estimates and a covariance matrix for the state estimates. A preemptive-constraining processor is configured to preemptively constrain the state estimates and covariance matrix to be free of constraint violations. A measurement-correction processor may be configured to correct constrained state estimates and a constrained covariance matrix based on processing of sensed plant output variables. The measurement-correction processor is coupled to update the dynamic model with corrected state estimates and a corrected covariance matrix. The updated dynamic model may be configured to estimate values for at least one plant variable not originally sensed by the sensor suite.

Kumar, Aditya; Shi, Ruijie; Dokucu, Mustafa

2013-09-17T23:59:59.000Z

69

Model predictive control system and method for integrated gasification combined cycle power generation  

SciTech Connect

Control system and method for controlling an integrated gasification combined cycle (IGCC) plant are provided. The system may include a controller coupled to a dynamic model of the plant to process a prediction of plant performance and determine a control strategy for the IGCC plant over a time horizon subject to plant constraints. The control strategy may include control functionality to meet a tracking objective and control functionality to meet an optimization objective. The control strategy may be configured to prioritize the tracking objective over the optimization objective based on a coordinate transformation, such as an orthogonal or quasi-orthogonal projection. A plurality of plant control knobs may be set in accordance with the control strategy to generate a sequence of coordinated multivariable control inputs to meet the tracking objective and the optimization objective subject to the prioritization resulting from the coordinate transformation.

Kumar, Aditya; Shi, Ruijie; Kumar, Rajeeva; Dokucu, Mustafa

2013-04-09T23:59:59.000Z

70

Biomass Pyrolysis and Gasification of Varying Particle Sizes in a Fluidized-Bed Reactor  

Science Journals Connector (OSTI)

Light gases, char, and tar evolution as function of the bed temperature and particle size have been compared to literature data. ... A review of the primary measures for tar elimination in biomass gasification processes Biomass Bioenergy 2003, 24 ( 2) 125– 140 ... Some aspects of primary methods and the research and development in this area are reviewed and cited in the present paper. ...

Katherine R. Gaston; Mark W. Jarvis; Perrine Pepiot; Kristin M. Smith; William J. Frederick, Jr.; Mark R. Nimlos

2011-05-06T23:59:59.000Z

71

Catalytic gasification of tars from a dumping site  

Science Journals Connector (OSTI)

The work deals with catalytic gasification, pyrolysis and non-catalytic gasification of tar from an industrial dumping site. ... were carried out in a vertical stainless steel gasification reactor at 800 °C. Crus...

Lukáš Gašparovi?; Lukáš Šugár…

2013-10-01T23:59:59.000Z

72

The integral fast reactor fuel cycle  

SciTech Connect

The liquid-metal reactor (LMR) has the potential to extend the uranium resource by a factor of 50 to 100 over current commercial light water reactors (LWRs). In the integral fast reactor (IFR) development program, the entire reactor system - reactor, fuel cycle, and waste process - is being developed and optimized at the same time as a single integral entity. A key feature of the IFR concept is the metallic fuel. The lead irradiation tests on the new U-Pu-Zr metallic fuel in the Experimental Breeder Reactor II have surpassed 185000 MWd/t burnup, and its high burnup capability has now been fully demonstrated. The metallic fuel also allows a radically improved fuel cycle technology. Pyroprocessing, which utilizes high temperatures and molten salt and molten metal solvents, can be advantageously utilized for processing metal fuels because the product is metal suitable for fabrication into new fuel elements. Direct production of a metal product avoids expensive and cumbersome chemical conversion steps that would result from use of the conventional Purex solvent extraction process. The key step in the IFR process is electrorefining, which provides for recovery of the valuable fuel constituents, uranium and plutonium, and for removal of fission products. A notable feature of the IFR process is that the actinide elements accompany plutonium through the process. This results in a major advantage in the high-level waste management.

Chang, Y.I. (Argonne National Lab., IL (United States))

1990-01-01T23:59:59.000Z

73

Cost of energy analysis of integrated gasification combined cycle (IGCC) power plant with respect to CO2 capture ratio under climate change scenarios  

Science Journals Connector (OSTI)

This paper presents the results of the cost of energy (COE) analysis of an integrated gasification...2...capture ratio under the climate change scenarios. To obtain process data for a COE analysis, simulation mod...

Kyungtae Park; Dongil Shin; Gibaek Lee…

2012-09-01T23:59:59.000Z

74

Gasification of refinery sludge in an updraft reactor for syngas production  

Science Journals Connector (OSTI)

The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time oxidation temperature and equivalence ratios on carbon gas conversion rate gasification efficiency heating value and fuel gas yield are presented. The results show that the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions meanwhile as the temperature decreased the CO H 2 CH 4 compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction ( CO 2 + C ?=?450?2 CO ) and accelerated the carbon conversion and gasification efficiencies resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies high heating value of gas and fuel gas yield to reach their maximum values of 96.1 % and 53.7 % 5.42 MJ Nm?3 of and 2.5 Nm3 kg?1 respectively.

2014-01-01T23:59:59.000Z

75

Is Integrated Gasification Combined Cycle with Carbon Capture-Storage the Solution for Conventional Coal Power Plants  

E-Print Network (OSTI)

Engineering Management Field Project Is Integrated Gasification Combined Cycle with Carbon Capture-Storage the Solution for Conventional Coal Power Plants By Manish Kundi Fall Semester, 2011 An EMGT Field Project report... 2.4 Environmental Aspects-Emissions 23 3.0 Procedure & Methodology 3.1 Working technology – Conventional Coal Plants 30 3.2 Working technology – IGCC Power Plants 32 3.3 Carbon Capture and Storage 35 3...

Kundi, Manish

2011-12-16T23:59:59.000Z

76

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Usage in Coal to Electrical Applications Usage in Coal to Electrical Applications The Integrated Gasification Combined Cycle (IGCC) application of gasification offers some water-saving advantages over other technologies for producing electricity from coal. Regions with limited water resources, typical of many parts of the western United States, could conserve resources by meeting increasing electricity demand with IGCC generation. Many of these areas have good coal resources and a need for new generating capacity. Water use in a thermoelectric power plant is described by two separate terms: water withdrawal and water consumption. Water withdrawal is the amount of water taken into the plant from an outside source. Water consumption refers to the portion of the withdrawn water that is not returned directly to the outside source - for example, water lost to evaporative cooling.

77

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

CO2: CO2 Capture: Impacts on IGCC Plant Designs CO2: CO2 Capture: Impacts on IGCC Plant Designs Specific Impacts on IGCC Plant Designs from CO2 Capture In foregoing discussion, results of NETL's comprehensive study comparing the performance and cost of various fossil fuel-based power generation technologies with and without CO2 capture were reviewed. Of particular interest in that study was the companion set of integrated gasification combined cycle (IGCC) designs, using GE's gasification technology, which can be used to illustrate the design changes needed for CO2 capture. Current Technology - IGCC Plant Design Figure 1 shows a simplified block flow diagram (BFD) of a market-ready IGCC design without CO2 capture. As shown, the IGCC plant consists of the following processing islands, of which a more detailed description of each can be found in the cited NETL referenced report: 1

78

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

SciTech Connect

Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

2012-06-20T23:59:59.000Z

79

Technoeconomic Analysis and Life Cycle Assessment of an Integrated Biomass Gasification Combined Cycle System  

Science Journals Connector (OSTI)

A biomass gasification combined-cycle power plant, consisting of a low pressure...®...Economic analyses were then performed to determine the levelized cost of electricity. The economic viability and efficiency of...

M. K. Mann; P. L. Spath

1997-01-01T23:59:59.000Z

80

Studies of the thermal circuit of an advanced integrated gasification combined-cycle power plant  

Science Journals Connector (OSTI)

The results obtained from a study of the thermal circuit of a combined-cycle plant with coal gasification are presented, and ... of producer gas and calculated values of the combined-cycle power plant efficiency ...

D. G. Grigoruk; A. V. Turkin

2010-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

EIS-0428: Mississippi Gasification, LLC, Industrial Gasification...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS EIS-0428: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS...

82

17 - Fluidized bed gasification  

Science Journals Connector (OSTI)

Abstract: The chapter describes the state-of-the-art of fluidized bed gasification of solid fuels, starting from the key role played by hydrodynamics, and its strong correlation with physical and chemical phenomena of the process and operating performance parameters of the reactor. The possible configurations of fluidized bed gasification plants are also assessed, and an analysis of the main methods for syngas cleaning is reported. Finally, the chapter describes some of the most interesting commercial experiences. The analysis indicates that the gasification of biomass and also of municipal and industrial solid wastes appear to be the most interesting sectors for the industrial development and utilization of fluidized bed gasifiers.

U. Arena

2013-01-01T23:59:59.000Z

83

Integrated Sensing and Controls for Coal Gasification - Development of Model-Based Controls for GE's Gasifier and Syngas Cooler  

SciTech Connect

This report summarizes the achievements and final results of this program. The objective of this program is to develop a comprehensive systems approach to integrated design of sensing and control systems for an Integrated Gasification Combined Cycle (IGCC) plant, using advanced model-based techniques. In particular, this program is focused on the model-based sensing and control system design for the core gasification section of an IGCC plant. The overall approach consists of (i) developing a first-principles physics-based dynamic model of the gasification section, (ii) performing model-reduction where needed to derive low-order models suitable for controls analysis and design, (iii) developing a sensing system solution combining online sensors with model-based estimation for important process variables not measured directly, and (iv) optimizing the steady-state and transient operation of the plant for normal operation as well as for startup using model predictive controls (MPC). Initially, available process unit models were implemented in a common platform using Matlab/Simulink{reg_sign}, and appropriate model reduction and model updates were performed to obtain the overall gasification section dynamic model. Also, a set of sensor packages were developed through extensive lab testing and implemented in the Tampa Electric Company IGCC plant at Polk power station in 2009, to measure temperature and strain in the radiant syngas cooler (RSC). Plant operation data was also used to validate the overall gasification section model. The overall dynamic model was then used to develop a sensing solution including a set of online sensors coupled with model-based estimation using nonlinear extended Kalman filter (EKF). Its performance in terms of estimating key unmeasured variables like gasifier temperature, carbon conversion, etc., was studied through extensive simulations in the presence sensing errors (noise and bias) and modeling errors (e.g. unknown gasifier kinetics, RSC fouling). In parallel, an MPC solution was initially developed using ideal sensing to optimize the plant operation during startup pre-heating as well as steady state and transient operation under normal high-pressure conditions, e.g. part-load, base-load, load transition and fuel changes. The MPC simulation studies showed significant improvements both for startup pre-heating and for normal operation. Finally, the EKF and MPC solutions were coupled to achieve the integrated sensing and control solution and its performance was studied through extensive steady state and transient simulations in the presence of sensor and modeling errors. The results of each task in the program and overall conclusions are summarized in this final report.

Aditya Kumar

2010-12-30T23:59:59.000Z

84

Hydrogen production by steam-gasification of carbonaceous materials using concentrated solar energy – V. Reactor modeling, optimization, and scale-up  

Science Journals Connector (OSTI)

A chemical reactor for the steam-gasification of carbonaceous particles (e.g. coal, coke) is considered for using concentrated solar radiation as the energy source of high-temperature process heat. A two-phase reactor model that couples radiative, convective, and conductive heat transfer to the chemical kinetics is applied to optimize the reactor geometrical configuration and operational parameters (feedstock's initial particle size, feeding rates, and solar power input) for maximum reaction extent and solar-to-chemical energy conversion efficiency of a 5 kW prototype reactor and its scale-up to 300 kW. For the 300 kW reactor, complete reaction extent is predicted for an initial feedstock particle size up to 35 ?m at residence times of less than 10 s and peak temperatures of 1818 K, yielding high-quality syngas with a calorific content that has been solar-upgraded by 19% over that of the petcoke gasified.

A. Z'Graggen; A. Steinfeld

2008-01-01T23:59:59.000Z

85

The Integral Fast Reactor (IFR) - Reactors designed/built by Argonne  

NLE Websites -- All DOE Office Websites (Extended Search)

Integral Fast Reactor Integral Fast Reactor About Director's Welcome Organization Achievements Highlights Fact Sheets, Brochures & Other Documents Multimedia Library Visit Argonne Work with Argonne Contact us Nuclear Energy Why Nuclear Energy? Why are some people afraid of Nuclear Energy? How do nuclear reactors work? Cheaper & Safer Nuclear Energy Helping to Solve the Nuclear Waste Problem Nuclear Reactors Nuclear Reactors Early Exploration Training Reactors Basic and Applied Science Research LWR Technology Development BORAX-III lighting Arco, Idaho (Press Release) Heavy Water and Graphite Reactors Fast Reactor Technology Integral Fast Reactor Argonne Reactor Tree CP-1 70th Anniversary CP-1 70th Anniversary Argonne's Nuclear Science and Technology Legacy Argonne's Nuclear Science and Technology Legacy

86

Gasification of Glucose in Supercritical Water  

Science Journals Connector (OSTI)

Gasification of Glucose in Supercritical Water ... Gasification of 0.6 M glucose in supercritical water was investigated at a temperature range from 480 to 750 °C and 28 MPa with a reactor residence time of 10?50 s. ... Carbon gasification efficiency reached 100% at 700 °C. ...

In-Gu Lee; Mi-Sun Kim; Son-Ki Ihm

2002-01-31T23:59:59.000Z

87

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Background Gasification Background Challenges for Gasification The widespread market penetration of gasification continues to face some challenges. Over the years, gasification challenges related to gasifier and supporting unit availability, operability, and maintainability have been addressed with substantial success, and new implementations of gasification will continue to improve in this area. At present, perhaps the most significant remaining challenge is the relatively high capital costs of gasification plants, particularly given the low capital investment required for NGCC-based power production combined with low natural gas prices currently being experienced in the domestic market. Accordingly, technology that can decrease capital costs of gasification systems and plant supporting systems will be most important towards further deployment of gasification.

88

Gasification of a solid recovered fuel in a pilot scale fluidized bed reactor  

Science Journals Connector (OSTI)

Abstract The paper investigates the technical feasibility of an air gasification process of a Solid Recovered Fuel (SRF) obtained from municipal solid waste. A pilot scale bubbling fluidized bed gasifier, having a feedstock capacity of about 70 kg/h and a maximum thermal output of about 400 kW, provided the experimental data: the complete composition of the syngas (including the tar, particulate and acid/basic gas contents), the chemical and physical characterization of the bed material and that of entrained fines collected at the cyclone. The experimental runs were carried out by reaching a condition of thermal and chemical steady state under values of equivalence ratio ranging from 0.25 to 0.33. The results indicate that the selected SRF can be conveniently gasified, yielding a syngas of valuable quality for energy applications. The rather high content of tar in the syngas indicates that the more appropriate plant configuration should be that of a “thermal gasifier”, with the direct combustion of the syngas in a burner ad hoc designed, coupled with an adequate energy-conversion device.

Umberto Arena; Fabrizio Di Gregorio

2014-01-01T23:59:59.000Z

89

EIS-0429: Department of Energy Loan Guarantee for Indiana Integrated Gasification Combined Cycle, Rockport, IN  

Energy.gov (U.S. Department of Energy (DOE))

This EIS evaluates the environmental impacts of a coal-to-substitute natural gas facility proposed to be built in Rockport, IN by Indiana Gasification. The facility would utilize Illinois Basin coal. Other products would be marketable sulfuric acid, argon, and electric power.

90

EIS-0428: Department of Energy Loan Guarantee for Mississippi Integrated Gasification Combined Cycle, Moss Point, Mississippi  

Energy.gov (U.S. Department of Energy (DOE))

This EIS evaluates the environmental impacts of a petroleum coke-to-substitute natural gas facility proposed to be built by Mississippi Gasification. The facility would be designed to produce 120 million standard cubic feet of gas per day. Other products would be marketable sulfuric acid, carbon dioxide, argon, and electric power.

91

Gasification Technologie: Opportunities & Challenges  

SciTech Connect

This course has been put together to provide a single source document that not only reviews the historical development of gasification but also compares the process to combustion. It also provides a short discussion on integrated gasification and combined cycle processes. The major focus of the course is to describe the twelve major gasifiers being developed today. The hydrodynamics and kinetics of each are reviewed along with the most likely gas composition from each of the technologies when using a variety of fuels under different conditions from air blown to oxygen blown and atmospheric pressure to several atmospheres. If time permits, a more detailed discussion of low temperature gasification will be included.

Breault, R.

2012-01-01T23:59:59.000Z

92

Actinide burning in the integral fast reactor  

SciTech Connect

During the past few years, Argonne National Laboratory has been developing the integral fast reactor (IFR), an advanced liquid-metal reactor concept. In the IFR, the inherent properties of liquid-metal cooling are combined with a new metallic fuel and a radically different refining process to allow breakthroughs in passive safety, fuel cycle economics, and waste management. A key feature of the IFR concept is its unique pyroprocessing. Pyroprocessing has the potential to radically improve long-term waste management strategies by exploiting the following attributes: 1. Minor actinides accompany plutonium product stream; therefore, actinide recycling occurs naturally. Actinides, the primary source of long-term radiological toxicity, are removed from the waste stream and returned to the reactor for in situ burning, generating useful energy. 2. High-level waste volume from pyroprocessing call be reduced substantially as compared with direct disposal of spent fuel. 3. Decay heat loading in the repository can be reduced by a large factor, especially for the long-term burden. 4. Low-level waste generation is minimal. 5. Troublesome fission products, such as [sup 99]Tc, [sup 129]I, and [sup 14]C, are contained and immobilized. Singly or in combination, the foregoing attributes provide important improvements in long-term waste management in terms of the ease in meeting technical performance requirements (perhaps even the feasibility of demonstrating that technical performance requirements can be met) and perhaps also in ultimate public acceptance. Actinide recycling, if successfully developed, could well help the current repository program by providing an opportunity to enhance capacity utilization and by deferring the need for future repositories. It also represents a viable technical backup option in the event unforeseen difficulties arise in the repository licensing process.

Chang, Y.I. (Argonne National Lab., IL (United States))

1993-01-01T23:59:59.000Z

93

Kentucky Pioneer Integrated Gasification Combined Cycle Demonstration Project, Final Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Comments Comments Kentucky Pioneer IGCC Demonstration Project Final Environmental Impact Statement Clark County Public Library Winchester, KY Page 1 of 5 D-1 Comment No. 1 Issue Code: 11 Gasification is different from incineration. It is a better, more environmentally responsible approach to generating energy from the use of fossil fuels and refuse derived fuel (RDF). Incineration produces criteria pollutants, semi-volatile and volatile organic compounds and dioxin/furan compounds. Ash from hazardous waste incinerators is considered a hazardous waste under the Resource Conservation and Recovery Act (RCRA). In contrast, gasification, which occurs at high temperatures and pressures, produces no air emissions, only small amounts of wastewater containing salts. Synthesis gas (syngas)

94

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Cleanup: Syngas Contaminant Removal and Conditioning Syngas Cleanup: Syngas Contaminant Removal and Conditioning Acid Gas Removal (AGR) Acid gases produced in gasification processes mainly consist of hydrogen sulfide (H2S), carbonyl sulfide (COS), and carbon dioxide (CO2). Syngas exiting the particulate removal and gas conditioning systems, typically near ambient temperature at 100°F, needs to be cleaned of the sulfur-bearing acid gases to meet either environmental emissions regulations, or to protect downstream catalysts for chemical processing applications. For integrated gasification combined cycle (IGCC) applications, environmental regulations require that the sulfur content of the product syngas be reduced to less than 30 parts per million by volume (ppmv) in order to meet the stack gas emission target of less than 4 ppmv sulfur dioxide (SO2)1. In IGCC applications, where selective catalytic reduction (SCR) is required to lower NOx emissions to less than 10 ppmv, syngas sulfur content may have to be lowered to 10 to 20 ppmv in order to prevent ammonium bisulfate fouling of the heat recovery steam generator's (HRSG) cold end tubes. For fuels production or chemical production, the downstream synthesis catalyst sulfur tolerance dictates the sulfur removal level, which can be less than 0.1 ppmv.

95

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network (OSTI)

Using Self-Sustained Hydro- Gasification." [0011] In aprocess, using a steam hydro-gasification reactor (SHR) thepyrolysis and hydro-gasification in a single step. This

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

96

NEW OPTIMIZATION-BASED APPROACH TO CHEMICAL REACTOR SYNTHESIS TOWARDS THE FULL INTEGRATION OF REACTOR  

E-Print Network (OSTI)

NEW OPTIMIZATION-BASED APPROACH TO CHEMICAL REACTOR SYNTHESIS ­ TOWARDS THE FULL INTEGRATION solutions. However, it does not provide optimal reactor design from both economical and environmental and methods for reactor design. It also explores the possibilities for actuation improvement for the optimal

Van den Hof, Paul

97

Evaluation of in-vessel corium retention through external reactor vessel cooling for integral reactor  

SciTech Connect

In-vessel corium retention through external reactor vessel cooling (IVR-ERVC) for a small integral reactor has been evaluated to determine the thermal margin for the prevention of a reactor vessel failure. A thermal load analysis from the corium pool to the outer reactor vessel wall in the lower plenum of the reactor vessel has been performed to determine the heat flux distribution. The critical heat flux (CHF) on the outer reactor vessel wall has been determined to fix the maximum heat removal rate through the external coolant between the outer reactor vessel and the insulation of the reactor vessel. Finally, the thermal margin has been evaluated by comparison of the thermal load with the maximum heat removal rate of the CHF on the outer reactor vessel wall. The maximum heat flux from the corium pool to the outer reactor vessel is estimated at approximately 0.25 MW/m{sup 2} in the metallic layer because of the focusing effect. The CHF of the outer reactor vessel is approximately 1.1 MW/m{sup 2} because of a two phase natural circulation mass flow. Since the thermal margin for the IVR-ERVC is sufficient, the reactor vessel integrity is maintained during a severe accident of a small integral reactor. (authors)

Park, R. J.; Lee, J. R.; Kim, S. B.; Jin, Y.; Kim, H. Y. [Korea Atomic Energy Research Inst., 1045 Daedeok-daero, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2012-07-01T23:59:59.000Z

98

Chapter 5 - Gasification Processes  

Science Journals Connector (OSTI)

Publisher Summary There is a broad range of reactor types that are used in the practical realization of the gasification process. For most purposes, these reactor types can be grouped into one of three categories: moving-bed gasifiers, fluid-bed gasifiers, and entrained-flow gasifiers. Moving-bed processes are the oldest processes, and two processes in particular, the producer gas process and the water gas process, have played an important role in the production of synthesis gas from coal and coke. In moving bed processes, there are the sasol-lurgi dry bottom process, British Gas/Lurgi (BGL) slagging gasifier, that are detailed in the chapter along with their applications. Following this, fluid-bed processes are discussed in which the blast has two functions: that of blast as a reactant and that of the fluidizing medium for the bed. The best known fluid-bed gasifiers that have no tar problem are regenerators of catalytic cracking units that often operate under reducing, that is, gasification conditions that can be found in many refineries. HRL process, BHEL gasifier, circulating fluidized-bed (CFB) processes, the KBR transport gasifier, agglomerating fluid-bed processes, the Pratt & Whitney Rocketdyne (PWR) gasifier, the GEE gasification process, the Shell Gasification Process (SGP), Lurgi’ s Multi-Purpose Gasification process (MPG), etc. are the various processes discussed in the chapter.

Christopher Higman; Maarten van der Burgt

2008-01-01T23:59:59.000Z

99

Co-gasification of biosolids with biomass: Thermogravimetric analysis and pilot scale study in a bubbling fluidized bed reactor  

Science Journals Connector (OSTI)

Abstract This work studied the feasibility of co-gasification of biosolids with biomass as a means of disposal with energy recovery. The kinetics study at 800 °C showed that biomass, such as switchgrass, could catalyze the reactions because switchgrass ash contained a high proportion of potassium, an excellent catalyst for gasification. However, biosolids could also inhibit gasification due to interaction between biomass alkali/alkaline earth metals and biosolids clay minerals. In the pilot scale experiments, increasing the proportion of biosolids in the feedstock affected gasification performance negatively. Syngas yield and char conversion decreased from 1.38 to 0.47 m3/kg and 82–36% respectively as the biosolids proportion in the fuel increased from 0% to 100%. Over the same range, the tar content increased from 10.3 to 200 g/m3, while the ammonia concentration increased from 1660 to 19,200 ppmv. No more than 25% biosolids in the fuel feed is recommended to maintain a reasonable gasification.

Ming Ming Yu; Mohammad S. Masnadi; John R. Grace; Xiaotao T. Bi; C. Jim Lim; Yonghua Li

2015-01-01T23:59:59.000Z

100

Integrated Gasification Combined Cycle (IGCC) demonstration project, Polk Power Station -- Unit No. 1. Annual report, October 1993--September 1994  

SciTech Connect

This describes the Tampa Electric Company`s Polk Power Station Unit 1 (PPS-1) Integrated Gasification Combined Cycle (IGCC) demonstration project which will use a Texaco pressurized, oxygen-blown, entrained-flow coal gasifier to convert approximately 2,300 tons per day of coal (dry basis) coupled with a combined cycle power block to produce a net 250 MW electrical power output. Coal is slurried in water, combined with 95% pure oxygen from an air separation unit, and sent to the gasifier to produce a high temperature, high pressure, medium-Btu syngas with a heat content of about 250 Btu/scf (LHV). The syngas then flows through a high temperature heat recovery unit which cools the syngas prior to its entering the cleanup systems. Molten coal ash flows from the bottom of the high temperature heat recovery unit into a water-filled quench chamber where it solidifies into a marketable slag by-product.

NONE

1995-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Coal Gasification  

Energy.gov (U.S. Department of Energy (DOE))

DOE's Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically via the process of coal gasification with sequestration. DOE anticipates that coal...

102

A next-generation reactor concept: The Integral Fast Reactor (IFR)  

SciTech Connect

The Integral Fast Reactor (IFR) is an advanced liquid metal reactor concept being developed at Argonne National Laboratory as reactor technology for the 21st century. It seeks to specifically exploit the inherent properties of liquid metal cooling and metallic fuel in a way that leads to substantial improvements in the characteristics of the complete reactor system, in particular passive safety and waste management. The IFR concept consists of four technical features: (1) liquid sodium cooling, (2) pool-type reactor configuration, (3) metallic fuel, and (4) fuel cycle closure based on pyroprocessing.

Chang, Y.I.

1992-01-01T23:59:59.000Z

103

A next-generation reactor concept: The Integral Fast Reactor (IFR)  

SciTech Connect

The Integral Fast Reactor (IFR) is an advanced liquid metal reactor concept being developed at Argonne National Laboratory as reactor technology for the 21st century. It seeks to specifically exploit the inherent properties of liquid metal cooling and metallic fuel in a way that leads to substantial improvements in the characteristics of the complete reactor system, in particular passive safety and waste management. The IFR concept consists of four technical features: (1) liquid sodium cooling, (2) pool-type reactor configuration, (3) metallic fuel, and (4) fuel cycle closure based on pyroprocessing.

Chang, Y.I.

1992-07-01T23:59:59.000Z

104

Kinetic mechanism of dimethyl ether production process using syngas from integrated gasification combined cycle power plant  

Science Journals Connector (OSTI)

In a 1-step synthesis gas-to-dimethyl ether process, synthesis gas is converted into dimethyl ether (DME) in a single reactor. Three reactions are involved in this process: methanol synthesis, methanol dehydra...

Hee-Woo Park; Jin-Kuk Ha; Euy Soo Lee

2014-07-01T23:59:59.000Z

105

Light Water Reactor Sustainability Program - Integrated Program Plan |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Light Water Reactor Sustainability Program - Integrated Program Light Water Reactor Sustainability Program - Integrated Program Plan Light Water Reactor Sustainability Program - Integrated Program Plan The Light Water Reactor Sustainability (LWRS) Program is a research and development (R&D) program sponsored by the U. S. Department of Energy (DOE), performed in close collaboration and cooperation with related industry R&D programs. The LWRS Program provides technical foundations for licensing and managing the long-term, safe, and economical operation of current nuclear power plants, utilizing the unique capabilities of the national laboratory system. Sustainability is defined as the ability to maintain safe and economic operation of the existing fleet of nuclear power plants for a longer than-initially-licensed lifetime. It has two facets

106

Production of hydrogen rich bio-oil derived syngas from co-gasification of bio-oil and waste engine oil as feedstock for lower alcohols synthesis in two-stage bed reactor  

Science Journals Connector (OSTI)

Abstract High efficient production of lower alcohols (C1–C5 mixed alcohols) from hydrogen rich bio-oil derived syngas was achieved in this work. A non-catalytic partial oxidation (NPOX) gasification technology was successfully applied in the production and conditioning of bio-oil derived syngas using bio-oil (BO) and emulsifying waste engine oil (EWEO) as feedstock. The effects of water addition and feedstock composition on the gasification performances were investigated. When the BO20 and EWEO30 was mixed with mass ratio of 1: 0.33, the maximum hydrogen yield of 93.7% with carbon conversion of 96.7% was obtained, and the hydrogen rich bio-oil derived syngas was effectively produced. Furthermore, a two-stage bed reactor was applied in the downstream process of lower alcohols synthesis from hydrogen rich bio-oil derived syngas (H2/CO/CO2/CH4/N2 = 52.2/19.5/3.0/9.4/15.9, v/v). The highest carbon conversion of 42.5% and the maximum alcohol yield of 0.18 kg/kgcat h with selectivity of 53.8 wt% were obtained over the Cu/ZnO/Al2O3(2.5)//Cu25Fe22Co3K3/SiO2(2.5) catalyst combination system. The mechanism and evaluation for lower alcohols synthesis from model bio-oil derived syngas and model mixture gas were also discussed. The integrative process of hydrogen rich bio-oil derived syngas production and downstream lower alcohols synthesis, potentially providing a promising route for the conversion of organic wastes into high performance fuels and high value-added chemicals.

Haijun Guo; Fen Peng; Hairong Zhang; Lian Xiong; Shanggui Li; Can Wang; Bo Wang; Xinde Chen; Yong Chen

2014-01-01T23:59:59.000Z

107

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifier: Commercial Gasifiers Gasifier: Commercial Gasifiers Gasifiers and Impact of Coal Rank and Coal Properties The available commercial gasification technologies are often optimized for a particular rank of coal or coal properties, and in some cases, certain ranks of coal might be unsuitable for utilization in a given gasification technology. On the other hand, there is considerable flexibility in most of the common gasifiers; this is highlighted by the following table, which provides an overview of the level of experience for the various commercially available gasifiers by manufacturer for each coal type. This experience will only continue to expand as more gasification facilities come online and more demonstrations are completed. SOLID FUEL GASIFICATION EXPERIENCE1 High Ash Coals

108

Gasification Plant Databases  

NLE Websites -- All DOE Office Websites (Extended Search)

coal gasification projects throughout the world. These databases track proposed gasification projects with approximate outputs greater than 100 megawatts electricity...

109

Gasification Plant Databases  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Plant Databases News Gasifipedia Gasifier Optimization Feed Systems Syngas Processing Systems Analyses Gasification Plant Databases International Activity Program Plan...

110

NETL: Coal Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal Gasification Systems News Gasifipedia Gasifier Optimization Feed Systems Syngas Processing Systems Analyses Gasification Plant Databases International Activity Program Plan...

111

Gasification Systems Project Portfolio  

NLE Websites -- All DOE Office Websites (Extended Search)

2014 Gasification Systems Project Portfolio News Gasifipedia Gasifier Optimization Feed Systems Syngas Processing Systems Analyses Gasification Plant Databases International...

112

Filter system cost comparison for integrated gasification combined cycle and pressurized fluidized-bed combustion power systems  

SciTech Connect

To assess the relative cost of components and sub-systems for a hot gas particulate cleanup system a cost comparison between the filter systems for two advanced coal-based power plants was conducted. Assessing component and sub-system costs permits the most beneficial areas for product improvement to be identified. The results from this study are presented. The filter system is based on a Westinghouse Advanced Particulate Filter Concept which is designed to operate with ceramic candle filters. The Foster Wheeler second Generation 453 MWe (net) Pressurized Fluidized-Bed Combustor (PFBC) and the KRW 458 MWe (net) Integrated Gasification Combined Cycle (IGCC) power plants are used for the comparison. The comparison presents the general differences of the two power plants and the process related filtration conditions for PFBC and IGCC systems. The results present the conceptual designs for the PFBC and IGCC filter systems as well as a cost summary comparison. The cost summary comparison includes the total plant cost, the fixed operating and maintenance cost, the variable operating and maintenance cost and the effect on the cost of electricity for the two filter systems. The most beneficial areas for product improvement are identified.

Dennis, R.A.; McDaniel, H.M. [Dept. of Energy, Morgantown, WV (United States). Morgantown Energy Technology Center; Buchanan, T.; Chen, H.; Harbaugh, L.B.; Klett, M.; Zaharchuk, R. [Gilbert/Commonwealth, Reading, PA (United States)

1995-12-31T23:59:59.000Z

113

The Integral Fast Reactor: A practical approach to waste management  

SciTech Connect

This report discusses development of the method for pyroprocessing of spent fuel from the Integral Fast Reactor (or Advanced Liquid Metal Reactor). The technology demonstration phase, in which recycle will be demonstrated with irradiated fuel from the EBR-II reactor has been reached. Methods for recovering actinides from spent LWR fuel are at an earlier stage of development but appear to be technically feasible at this time, and a large-scale demonstration of this process has begun. The utilization of fully compatible processes for recycling valuable spent fuel materials promises to provide substantial economic incentives for future applications of the pyroprocessing technology.

Laidler, J.J.

1993-12-31T23:59:59.000Z

114

The O{sub 2}-enriched air gasification of coal, plastics and wood in a fluidized bed reactor  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer The effect of the O{sub 2} in the gasification stream of a BFB gasifier has been studied. Black-Right-Pointing-Pointer Main advantage of the O{sub 2}-enriched air is the increasing of the bed temperature. Black-Right-Pointing-Pointer No remarkable effects on tar reduction. Decreasing of recognized PAHs. Black-Right-Pointing-Pointer Gasification reactions completed inside the dense bed and splashing zone. Black-Right-Pointing-Pointer Polycondensation reactions occur mainly in the freeboard region. - Abstract: The effect of oxygen-enriched air during fluidized bed co-gasification of a mixture of coal, plastics and wood has been investigated. The main components of the obtained syngas were measured by means of on-line analyzers and a gas chromatograph while those of the condensate phase were off-line analysed by means of a gas chromatography-mass spectrometer (GC-MS). The characterization of condensate phase as well as that of the water used as scrubbing medium completed the performed diagnostics. The experimental results were further elaborated in order to provide material and substances flow analyses inside the plant boundaries. These analyses allowed to obtain the main substance distribution between solid, gaseous and condensate phases and to estimate the conversion efficiency of carbon and hydrogen but also to easily visualise the waste streams produced by the process. The process performance was then evaluated on the basis of parameters related to the conversion efficiency of fuels into valuable products (i.e. by considering tar and particulate as process losses) as well as those related to the energy recovery.

Mastellone, Maria Laura, E-mail: mlaura.mastellone@unina2.it [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy); Zaccariello, Lucio; Santoro, Donato; Arena, Umberto [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy)

2012-04-15T23:59:59.000Z

115

Coal Gasification for Power Generation, 3. edition  

SciTech Connect

The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

NONE

2007-11-15T23:59:59.000Z

116

Integrated intelligent systems in advanced reactor control rooms  

SciTech Connect

An intelligent, reactor control room, information system is designed to be an integral part of an advanced control room and will assist the reactor operator's decision making process by continuously monitoring the current plant state and providing recommended operator actions to improve that state. This intelligent system is an integral part of, as well as an extension to, the plant protection and control systems. This paper describes the interaction of several functional components (intelligent information data display, technical specifications monitoring, and dynamic procedures) of the overall system and the artificial intelligence laboratory environment assembled for testing the prototype. 10 refs., 5 figs.

Beckmeyer, R.R.

1989-01-01T23:59:59.000Z

117

NETL: Coal/Biomass Feed and Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed & Gasification Coal/Biomass Feed & Gasification Coal and Coal/Biomass to Liquids Coal/Biomass Feed and Gasification The Coal/Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal and/or coal-biomass mixtures. Activities support research for handling and processing of coal/biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on downstream components, catalyst and reactor optimization, and characterizing the range of products and product quality. Active projects within the program portfolio include the following: Coal-biomass fuel preparation Development of Biomass-Infused Coal Briquettes for Co-Gasification Coal-biomass gasification modeling

118

NETL: Gasification Systems Video, Images & Photos  

NLE Websites -- All DOE Office Websites (Extended Search)

Video, Images, Photos Video, Images, Photos Gasification Systems Reference Shelf - Video, Images & Photos The following was established to show a variety of Gasification Technologies: Gasfication powerplant photo Gasification: A Cornerstone Technology (Mar 2008) Movie Icon Windows Media Video (WMV-26MB) [ view | download ] NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants. Proposed APS Advanced Hydrogasification Process Proposed APS Advanced Hydrogasification Process* TRDU and Hot-Gas Vessel in the EERC Gasification Tower Transport reactor development unit

119

Integral Fast Reactor Program annual progress report, FY 1991  

SciTech Connect

This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1991. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R&D.

Not Available

1992-06-01T23:59:59.000Z

120

Integral Fast Reactor Program annual progress report, FY 1991  

SciTech Connect

This report summarizes highlights of the technical progress made in the Integral Fast Reactor (IFR) Program in FY 1991. Technical accomplishments are presented in the following areas of the IFR technology development activities: (1) metal fuel performance, (2) pyroprocess development, (3) safety experiments and analyses, (4) core design development, (5) fuel cycle demonstration, and (6) LMR technology R D.

Not Available

1992-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal: Alternatives/Supplements to Coal - Feedstock Flexibility Coal: Alternatives/Supplements to Coal - Feedstock Flexibility As important as coal is as a primary gasification feedstock, gasification technology offers the important ability to take a wide range of feedstocks and process them into syngas, from which a similarly diverse number of end products are possible. Gasifiers have been developed to suit all different ranks of coal, and other fossil fuels, petcoke and refinery streams, biomass including agricultural waste, and industrial and municipal waste. The flexibility stems from the ability of gasification to take any carbon and hydrogen containing feedstock and then thermochemically break down the feedstock to a gas containing simple compounds which are easy to process into several marketable products.

122

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia Coal: Feedstock Flexibility Refinery Streams Gasification is a known method for converting petroleum coke (petcoke) and other refinery waste streams and residuals (vacuum residual, visbreaker tar, and deasphalter pitch) into power, steam and hydrogen for use in the production of cleaner transportation fuels. The main requirement for a gasification feedstock is that it contains both hydrogen and carbon. Below is a table that shows the specifications for a typical refinery feedstock. Specifications for a typical refinery feedstock A number of factors have increased the interest in gasification applications in petroleum refinery operations: Coking capacity has increased with the shift to heavier, more sour crude oils being supplied to the refiners.

123

ENHANCED HYDROGEN PRODUCTION INTEGRATED WITH CO2 SEPARATION IN A SINGLE-STAGE REACTOR  

SciTech Connect

The water gas shift reaction (WGSR) plays a major role in increasing the hydrogen production from fossil fuels. However, the enhanced hydrogen production is limited by thermodynamic constrains posed by equilibrium limitations of WGSR. This project aims at using a mesoporous, tailored, highly reactive calcium based sorbent system for incessantly removing the CO{sub 2} product which drives the equilibrium limited WGSR forward. In addition, a pure sequestration ready CO{sub 2} stream is produced simultaneously. A detailed project vision with the description of integration of this concept with an existing coal gasification process for hydrogen production is presented. Conceptual reactor designs for investigating the simultaneous water gas shift and the CaO carbonation reactions are presented. In addition, the options for conducting in-situ sorbent regeneration under vacuum or steam are also reported. Preliminary, water gas shift reactions using high temperature shift catalyst and without any sorbent confirmed the equilibrium limitation beyond 600 C demonstrating a carbon monoxide conversion of about 80%. From detailed thermodynamic analyses performed for fuel gas streams from typical gasifiers the optimal operating temperature range to prevent CaO hydration and to effect its carbonation is between 575-830 C.

Himanshu Gupta; Mahesh Iyer; Bartev Sakadjian; Liang-Shih Fan

2005-03-10T23:59:59.000Z

124

Gasification of lignite in a fixed bed reactor: Influence of particle size on performance of downdraft gasifier  

Science Journals Connector (OSTI)

Abstract In this work, an experimental study of the gasification of lignite with various particle sizes was carried out in a pilot-scale (10 kWe) downdraft type fixed bed gasifier. The main objective of the study was to investigate the feasibility of the lignite as a fuel for downdraft gasifier and to evaluate the effect of the particle size on gasifier performance. The influence of the particle size on fuel consumption rate, temperature profile in various zone, gas yield, gas composition and cold gas efficiency was studied. Six different particle sizes viz. 13–16 mm, 16–19 mm, 19–22 mm, 22–25 mm, 25–28 mm, 28–31 mm were selected for experimental work. With the increase in particle size, the reduction in fuel consumption rate was observed, whereas the producer gas production rate had increased. The heating value of the gas increased as particle size increased from 13–16 mm to 22–25 mm and then same had decreased with increase in particle size. Higher temperature in reduction zone resulted in higher H2 and CO contents in producer gas. Under the experiment conditions, the fuel consumption rate, gas yields, LHV (Lower heating value) of gas fuel and cold gas efficiency varied in the range of 9.58–10.67 kg/hr, 2.43–2.63 Nm3/kg, 3.33–4.17 MJ/Nm3 and 51.5%–65.7% respectively. The experimental results showed that the gasification performance was better with lignite particle size of 22–25 mm.

Vimal R. Patel; Darshit S. Upadhyay; Rajesh N. Patel

2014-01-01T23:59:59.000Z

125

GASIFICATION FOR DISTRIBUTED GENERATION  

SciTech Connect

A recent emphasis in gasification technology development has been directed toward reduced-scale gasifier systems for distributed generation at remote sites. The domestic distributed power generation market over the next decade is expected to be 5-6 gigawatts per year. The global increase is expected at 20 gigawatts over the next decade. The economics of gasification for distributed power generation are significantly improved when fuel transport is minimized. Until recently, gasification technology has been synonymous with coal conversion. Presently, however, interest centers on providing clean-burning fuel to remote sites that are not necessarily near coal supplies but have sufficient alternative carbonaceous material to feed a small gasifier. Gasifiers up to 50 MW are of current interest, with emphasis on those of 5-MW generating capacity. Internal combustion engines offer a more robust system for utilizing the fuel gas, while fuel cells and microturbines offer higher electric conversion efficiencies. The initial focus of this multiyear effort was on internal combustion engines and microturbines as more realistic near-term options for distributed generation. In this project, we studied emerging gasification technologies that can provide gas from regionally available feedstock as fuel to power generators under 30 MW in a distributed generation setting. Larger-scale gasification, primarily coal-fed, has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries. Commercial-scale gasification activities are under way at 113 sites in 22 countries in North and South America, Europe, Asia, Africa, and Australia, according to the Gasification Technologies Council. Gasification studies were carried out on alfalfa, black liquor (a high-sodium waste from the pulp industry), cow manure, and willow on the laboratory scale and on alfalfa, black liquor, and willow on the bench scale. Initial parametric tests evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

2000-05-01T23:59:59.000Z

126

AVESTAR® - Training - Gasification Process Operations  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Process Operations Gasification Process Operations This course is designed as a familiarization course to increase understanding of the gasification with CO2 capture process. During the training, participants will startup and shutdown the simulated unit in an integrated manner and will be exposed to simple and complex unit malfunctions in the control room and in the field. Course objectives are as follows: Introduce trainees to gasification and CO2 capture process systems and major components and how they dynamically interact Familiarize trainees with the Human Machine Interface (HMI) and plant control and how safe and efficient operation of the unit can be affected by plant problems Provide the trainees with hands-on operating experiences in plant operations using the HMI

127

Analysis of Membrane and Adsorbent Processes for Warm Syngas Cleanup in Integrated Gasification Combined-Cycle Power with CO2 Capture and Sequestration  

Science Journals Connector (OSTI)

Analysis of Membrane and Adsorbent Processes for Warm Syngas Cleanup in Integrated Gasification Combined-Cycle Power with CO2 Capture and Sequestration ... The clean syngas is diluted with N2 from the ASU and enters the gas turbine burner. ... The amount of N2 diluent to be added is determined by the requirement of maintaining the appropriate lower heating value of the syngas feeding into the gas turbine burner to achieve sufficiently low NOx emissions (15–35 ppmv at 15% O2)(36) and to keep the temperature of the gas low enough to avoid blade failure. ...

David J. Couling; Kshitij Prakash; William H. Green

2011-08-11T23:59:59.000Z

128

Actinide recycle potential in the integral fast reactor  

SciTech Connect

The Integral Fast Reactor (IFR) fuel cycle holds promise for substantial improvements in economics, diversion-resistance, and waste management. In the IFR pyroprocessing, minor actinides accompany plutonium product stream, and therefore, actinide recycle occurs naturally. The fast neutron spectrum of the IFR makes it an ideal actinide burner, as well. This paper discusses technical features of the IFR fuel cycle, its technical progress, the development status, and potential implications on long-term waste management.

Chang, Y.I. [Argonne National Laboratory, IL (United States)

1993-12-31T23:59:59.000Z

129

Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

GASIFICATION SYSTEMS GASIFICATION SYSTEMS U.S. DEPARTMENT OF ENERGY TECHNOLOGY PROGRAM PLAN PREFACE ii DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any

130

NETL: Gasification Project Information  

NLE Websites -- All DOE Office Websites (Extended Search)

Project Information Project Information Gasification Systems Reference Shelf - Project Information Active Projects | Archived Projects | All NETL Fact Sheets Feed Systems A Cost-Effective Oxygen Separation System Based on Open Gradient Magnetic Field by Polymer Beads [SC0010151] Development of ITM Oxygen Technology for Low-cost and Low-emission Gasification and Other Industrial Applications [FE0012065] Dry Solids Pump Coal Feed Technology [FE0012062] Coal-CO2 Slurry Feeding System for Pressurized Gasifiers [FE0012500] National Carbon Capture Center at the Power Systems Development Facility [FE0000749] Modification of the Developmental Pressure Decoupled Advanced Coal (PDAC) Feeder [NT0000749] Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems [DE-FC26-98FT40343]

131

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Conditioning Conditioning Sulfur Recovery and Tail Gas Treating Sulfur is a component of coal and other gasification feed stocks. Sulfur compounds need to be removed in most gasification applications due to environmental regulations or to avoid catalyst poisoning. Whether it is electricity, liquid fuels, or some other product being output, sulfur emissions are regulated, and sulfur removal is important for this reason, along with the prevention of downstream component fouling. In addition to these constraints, recovering saleable sulfur is an important economic benefit for a gasification plant. To illustrate the previous point, in 2011 8.1 million tons of elemental sulfur was produced, with the majority of this coming from petroleum refining, natural gas processing and coking plants. Total shipments were valued at $1.6 billion, with the average mine or plant price of $200 per ton, up from $70.48 in 2010. The United States currently imports sulfur (36% of consumption, mostly from Canada), meaning the market can support more domestic sulfur production.

132

Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes  

SciTech Connect

This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540°C and the helium coolant was delivered at 7 MPa at 625–925°C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

Lee O. Nelson

2011-04-01T23:59:59.000Z

133

Characterization of Reactor Ash Deposits from Pilot-Scale Pressurized Entrained-Flow Gasification of Woody Biomass  

Science Journals Connector (OSTI)

(21, 22) Second, crude syngases can carry fly ash particles and gaseous inorganics that cause detrimental effects downstream, such as corrosion of heat recovery systems, contamination of syngas cleaning sorbents, and poisoning of biofuel production catalysts. ... Milled fuel is fed into the reactor via a single top-fired centrally positioned burner. ... The near-wall temperatures attained in the PEFG reactor were around 200–300 °C higher than the bed temperatures of most FB gasifiers/combustors.(4, 47-49) Considering also the temporal temperature elevations of particles (e.g., vicinal burning particles and passage through the O2-enriched flame regions), this would mean that both the average and temporal peak particle temperatures are significantly higher during PEFG. ...

Charlie Ma; Fredrik Weiland; Henry Hedman; Dan Boström; Rainer Backman; Marcus Öhman

2013-11-04T23:59:59.000Z

134

Progress and status of the integral fast reactor (IFR) development program  

SciTech Connect

This paper discusses the Integral Fast Reactor (IFR) development program, in which the entire reactor system - reactor, fuel cycle, and waste process is being developed and optimized at the same time as a single integral entity. Detailed discussions on the present status of the IFR technology development activities in the areas of fuels, pyroprocessing, safety, core design, and fuel cycle demonstration are also presented.

Chang, Y.I. (Argonne National Lab., Argonne, IL (US))

1992-01-01T23:59:59.000Z

135

Light Water Reactor Sustainability Program: Integrated Program Plan |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Integrated Program Plan Integrated Program Plan Light Water Reactor Sustainability Program: Integrated Program Plan Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas- emitting electric power generation in the United States. Domestic demand for electrical energy is expected to grow by more than 30% from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license, for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power

136

2007 gasification technologies conference papers  

SciTech Connect

Sessions covered: gasification industry roundtable; the gasification market in China; gasification for power generation; the gasification challenge: carbon capture and use storage; industrial and polygeneration applications; gasification advantage in refinery applications; addressing plant performance; reliability and availability; gasification's contribution to supplementing gaseous and liquid fuels supplies; biomass gasification for fuel and power markets; and advances in technology-research and development

NONE

2007-07-01T23:59:59.000Z

137

Biomass Gasification Combined Cycle  

SciTech Connect

Gasification combined cycle continues to represent an important defining technology area for the forest products industry. The ''Forest Products Gasification Initiative'', organized under the Industry's Agenda 2020 technology vision and supported by the DOE ''Industries of the Future'' program, is well positioned to guide these technologies to commercial success within a five-to ten-year timeframe given supportive federal budgets and public policy. Commercial success will result in significant environmental and renewable energy goals that are shared by the Industry and the Nation. The Battelle/FERCO LIVG technology, which is the technology of choice for the application reported here, remains of high interest due to characteristics that make it well suited for integration with the infrastructure of a pulp production facility. The capital cost, operating economics and long-term demonstration of this technology area key input to future economically sustainable projects and must be verified by the 200 BDT/day demonstration facility currently operating in Burlington, Vermont. The New Bern application that was the initial objective of this project is not currently economically viable and will not be implemented at this time due to several changes at and around the mill which have occurred since the inception of the project in 1995. The analysis shows that for this technology, and likely other gasification technologies as well, the first few installations will require unique circumstances, or supportive public policies, or both to attract host sites and investors.

Judith A. Kieffer

2000-07-01T23:59:59.000Z

138

An evaluation of integrated-gasification-combined-cycle and pulverized-coal-fired steam plants: Volume 1, Base case studies: Final report  

SciTech Connect

An evaluation of the performance and costs for a Texaco-based integrated gasification combined cycle (IGCC) power plant as compared to a conventional pulverized coal-fired steam (PCFS) power plant with flue gas desulfurization (FGD) is provided. A general set of groundrules was used within which each plant design was optimized. The study incorporated numerous sensitivity cases along with up-to-date operating and cost data obtained through participation of equipment vendors and process developers. Consequently, the IGCC designs presented in this study use the most recent data available from Texaco's ongoing international coal gasification development program and General Electric's continuing gas turbine development efforts. The Texaco-based IGCC has advantages over the conventional PCFS technology with regard to environmental emissions and natural resource requirements. SO/sub 2/, NOx, and particulate emissions are lower. Land area and water requirements are less for IGCC concepts. Coal consumption is less due to the higher plant thermal efficiency attainable in the IGCC plant. The IGCC plant also has the capability to be designed in several different configurations, with and without the use of natural gas or oil as a backup fuel. This capability may prove to be particularly advantageous in certain utility planning and operation scenarios. 107 figs., 114 tabs.

Pietruszkiewicz, J.; Milkavich, R.J.; Booras, G.S.; Thomas, G.O.; Doss, H.

1988-09-01T23:59:59.000Z

139

Design of advanced fossil-fuel systems (DAFFS): a study of three developing technologies for coal-fired, base-load electric power generation. Integrated coal gasification/combined cycle power plant with Texaco gasification process  

SciTech Connect

The objectives of this report are to present the facility description, plant layouts and additional information which define the conceptual engineering design, and performance and cost estimates for the Texaco Integrated Gasification Combined Cycle (IGCC) power plant. Following the introductory comments, the results of the Texaco IGCC power plant study are summarized in Section 2. In Section 3, a description of plant systems and facilities is provided. Section 4 includes pertinent performance information and assessments of availability, natural resource requirements and environmental impact. Estimates of capital costs, operation and maintenance costs and cost of electricity are presented in Section 5. A Bechtel Group, Inc. assessment and comments on the designs provided by Burns and Roe-Humphreys and Glasgow Synthetic Fuel, Inc. are included in Section 6. The design and cost estimate reports which were prepared by BRHG for those items within their scope of responsibility are included as Appendices A and B, respectively. Appendix C is an equipment list for items within the BGI scope. The design and cost estimate classifications chart referenced in Section 5 is included as Appendix D. 8 references, 17 figures, 15 tables.

Not Available

1983-06-01T23:59:59.000Z

140

Design of advanced fossil-fuel systems (DAFFS): a study of three developing technologies for coal-fired, base-load electric power generation. Integrated coal-gasification/combined power plant with BGC/Lurgi gasification process  

SciTech Connect

The objectives of this report are to present the facility description, plant layouts and additional information which define the conceptual engineering design, and performance and cost estimates for the BGC/Lurgi Integrated Gasification Combined Cycle (IGCC) power plant. Following the introductory comments, the results of the British Gas Corporation (BGC)/Lurgi IGCC power plant study are summarized in Section 2. In Secion 3, a description of plant systems and facilities is provided. Section 4 includes pertinent performance information and assessments of availability, natural resource requirements and environmental impact. Estimates of capital costs, operating and maintenance costs and cost of electricity are presented in Section 5. A Bechtel Group Inc. (BGI) assessment and comments on the designs provided by Burns and Roe-Humphreys and Glasgow Synthetic Fuels, Inc. (BRHG) are included in Section 6. The design and cost estimate reports which were prepared by BRHG for those items within their scope of responsibility are included as Appendices A and B, respectively. Apendix C is an equipment list for items within the BGI scope. The design and cost estimate classifications chart referenced in Section 5 is included as Appendix D. 8 references, 18 figures, 5 tables.

Not Available

1983-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Method for increasing steam decomposition in a coal gasification process  

DOE Patents (OSTI)

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, Marvin W. (Fairview, WV)

1988-01-01T23:59:59.000Z

142

Method for increasing steam decomposition in a coal gasification process  

DOE Patents (OSTI)

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, M.W.

1987-03-23T23:59:59.000Z

143

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Power: Typical IGCC Configuration Power: Typical IGCC Configuration Major Commercial Examples of IGCC Plants While there are many coal gasification plants in the world co-producing electricity, chemicals and/or steam, the following are four notable, commercial-size IGCC plants currently in operation solely for producing electricity from coal and/or coke. Tampa Electric, Polk County 250 MW GE Gasifier Wabash, West Terre Haute 265 MW CoP E-Gas(tm) Gasifier Nuon, Buggenum 250 MW Shell Gasifier Elcogas, Puertollano 300 MW Prenflo Gasifier All of the plants began operation prior to 2000 and employ high temperature entrained-flow gasification technology. GE (formerly Texaco-Chevron) and ConocoPhillips (CoP) are slurry feed gasifiers, while Shell and Prenflo are dry feed gasifiers. None of these plants currently capture carbon dioxide (CO2). A simplified process flow diagram of the 250-MW Tampa Electric IGCC plant is shown in Figure 1 to illustrate the overall arrangement of an operating commercial scale IGCC plant. The Tampa Electric plant is equipped with both radiant and convective coolers for heat recovery, generating high pressure (HP) steam.

144

Integration of renewable energy in microgrids coordinated with demand response resources: Economic evaluation of a biomass gasification plant by Homer Simulator  

Science Journals Connector (OSTI)

Abstract This paper deals with how demand response can contribute to the better integration of renewable energy resources such as wind power, solar, small hydro, biomass and CHP. In particular, an economic evaluation performed by means of the micro-power optimization model HOMER Energy has been done, considering a micro-grid supplied by a biomass gasification power plant, operating isolated to the grid and in comparison with other generation technologies. Different scenarios have been simulated considering variations in the power production of the gasified biomass generator and different solutions to guarantee the balance generation/consumption are analyzed, demonstrating as using demand response resources is much more profitable than producing this energy by other conventional technologies by using fossil fuels.

Lina Montuori; Manuel Alcázar-Ortega; Carlos Álvarez-Bel; Alex Domijan

2014-01-01T23:59:59.000Z

145

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Major Partner Test Sites Major Partner Test Sites Gasification Systems Technologies - Major Partner Test Sites Major Partner Test Sites Once a technology is ready to be tested at pilot or commercial scale, the cost of building a test facility becomes significant -- often beyond the funding provided for any one project. It then becomes critical to test the technology at a pre-existing facility willing to test experimental technologies. Not surprisingly, most commercial facilities are hesitant to interfere with their operations to experiment, but others, with a view towards the future, welcome promising technologies. Below is a list of major partner test sites that actively host DOE supported research activities. Many of the test sites were built with DOE support, but many were not. Some are commercial, and were designed to perform experimental work. All play an important role in developing technologies with minimal expense to the project, and to the U.S. taxpayer.

146

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Capture R&D Capture R&D DOE/NETL's pre-combustion CO2 control technology portfolio of R&D projects is examining various CO2 capture technologies, and supports identification of developmental pathways linking advanced fossil fuel conversion and CO2 capture. The Program's CO2 capture activity is being conducted in close coordination with that of advanced, higher-efficiency power generation and fossil fuel conversion technologies such as gasification. Links to the projects can be found here. Finally, an exhaustive and periodically updated report on CO2 capture R&D sponsored by NETL is available: DOE/NETL Advanced CO2 Capture R&D Program: Technology Update (also referred to as the CO2 Handbook). Carbon Dioxide CO2 Capture Commercial CO2 Uses & Carbon Dioxide Enhanced Oil Recovery

147

Major Environmental Aspects of Gasification-Based Power Generation Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Detailed Evaluation of the Environmental Performance of Gasification-Based Power Systems Detailed Evaluation of the Environmental Performance of Gasification-Based Power Systems DECEMBER 2002 U.S. DOE/NETL 2-1 2. DETAILED EVALUATION OF THE ENVIRONMENTAL PERFORMANCE OF GASIFICATION-BASED POWER SYTEMS 2.1 Introduction and Summary of Information Presented The single most compelling reason for utilities to consider coal gasification for electric power generation is superior environmental performance. 1 As shown in Figure 2-1, gasification has fundamental environmental advantages over direct coal combustion. Commercial-scale plants for both integrated gasification combined cycle (IGCC) electric power generation and chemicals applications have already successfully demonstrated these advantages. The superior environmental capabilities of coal gasification apply to all three areas of concern: air emissions,

148

Modeling the Performance, Emissions, and Cost of an Entrained-Flow Gasification Combined Cycle System Using  

E-Print Network (OSTI)

1 Modeling the Performance, Emissions, and Cost of an Entrained-Flow Gasification Combined Cycle-based Integrated Gasification Combined Cycle (IGCC) system using ASPEN. ASPEN is a steady-state chemical process-flow Integrated Gasification Combined Cycle (IGCC) system. This study aims at developing a base case analysis

Frey, H. Christopher

149

Gasification Research BIOENERGY PROGRAM  

E-Print Network (OSTI)

Gasification Research BIOENERGY PROGRAM Description Researchers inthe@tamu.edu Skid-mounted gasifier: 1.8 tons-per-day pilot unit Gasification of cotton gin trash The new Texas A

150

Gasification: redefining clean energy  

SciTech Connect

This booklet gives a comprehensive overview of how gasification is redefining clean energy, now and in the future. It informs the general public about gasification in a straight-forward, non-technical manner.

NONE

2008-05-15T23:59:59.000Z

151

Current Gasification Research  

Energy.gov (U.S. Department of Energy (DOE))

With coal gasification now in modern commercial-scale applications, the U.S. Department of Energy's (DOE) Office of Fossil Energy has turned its attention to future gasification concepts that offer...

152

Gasification | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification Gasification Gasification The Wabash River Clean Coal Power Plant The Wabash River Clean Coal Power Plant Gasification Technology R&D Coal gasification offers one of the most versatile and clean ways to convert coal into electricity, hydrogen, and other valuable energy products. Coal gasification electric power plants are now operating commercially in the United States and in other nations, and many experts predict that coal gasification will be at the heart of future generations of clean coal technology plants. Rather than burning coal directly, gasification (a thermo-chemical process) breaks down coal - or virtually any carbon-based feedstock - into its basic chemical constituents. In a modern gasifier, coal is typically exposed to steam and carefully controlled amounts of air or oxygen under high

153

Gasification and combustion modeling for porous char particles  

E-Print Network (OSTI)

Gasification and combustion of porous char particles occurs in many industrial applications. Reactor-scale outputs of importance depend critically on processes that occur at the particle-scale. Because char particles often ...

Singer, Simcha Lev

2012-01-01T23:59:59.000Z

154

Coal gasification development intensifies  

Science Journals Connector (OSTI)

Coal gasification development intensifies ... Three almost simultaneous developments in coal gasification, although widely divergent in purpose and geography, rapidly are accelerating the technology's movement into an era of commercial exploitation. ... A plant to be built in the California desert will be the first commercialsize coal gasification power plant in the U.S. In West Germany, synthesis gas from a coal gasification demonstration plant is now being used as a chemical feedstock, preliminary to scaleup of the process to commercial size. ...

1980-02-25T23:59:59.000Z

155

Gasification Systems Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifipedia Gasifier Optimization Feed Systems Syngas Processing Systems Analyses Gasification Plant Databases International Activity Program Plan Project Portfolio Project...

156

Gasification Systems Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Publications News Gasifipedia Gasifier Optimization Feed Systems Syngas Processing Systems Analyses Gasification Plant Databases International Activity Program Plan Project...

157

2010 Worldwide Gasification Database  

DOE Data Explorer (OSTI)

The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers.

158

Fundamental study of black liquor gasification kinetics using a pressurized entrained-flow reactor (PEFR). Quarterly progress report for the period July 1999 to September 1999  

SciTech Connect

The goal of the program is to identify the optimal operating window for black liquor gasification. The goals during this year are to prepare the PEFR for operation, conduct a series of preliminary screening tests to bracket BLG operating conditions, and develop a process model that can guide identification of the optimal operating window.

NONE

1999-10-29T23:59:59.000Z

159

Transport reactor development status  

SciTech Connect

This project is part of METC`s Power Systems Development Facility (PSDF) located at Wilsonville, Alabama. The primary objective of the Advanced Gasifier module is to produce vitiated gases for intermediate-term testing of Particulate Control Devices (PCDs). The Transport reactor potentially allows particle size distribution, solids loading, and particulate characteristics in the off-gas stream to be varied in a number of ways. Particulates in the hot gases from the Transport reactor will be removed in the PCDs. Two PCDs will be initially installed in the module; one a ceramic candle filter, the other a granular bed filter. After testing of the initial PCDs they will be removed and replaced with PCDs supplied by other vendors. A secondary objective is to verify the performance of a Transport reactor for use in advanced Integrated Gasification Combined Cycle (IGCC), Integrated Gasification Fuel Cell (IG-FC), and Pressurized Combustion Combined Cycle (PCCC) power generation units. This paper discusses the development of the Transport reactor design from bench-scale testing through pilot-scale testing to design of the Process Development Unit (PDU-scale) facility at Wilsonville.

Rush, R.E.; Fankhanel, M.O.; Campbell, W.M.

1994-10-01T23:59:59.000Z

160

Chemical-looping combustion in combination with integrated coal gasification -- A way to avoid CO{sub 2} emission from coal fired power plants without a significant decrease in net power efficiency  

SciTech Connect

Observation of the increased concentration of carbon dioxide, CO{sub 2}, in the atmosphere and the thereto suspected connected global warming effect has made prevention of CO{sub 2} emission from power plants an important field of research. Today, most fuels used in thermal power plants are fossil fuels like oil, coal or natural gas which upon combustion gives rise to a net release of CO{sub 2}. To avoid this emission, different gas separation techniques like membrane separation and absorption have been suggested to separate CO{sub 2} from the other exhaust gases before the exhaust is released into the atmosphere. This separation is, however, estimated to be rather costly due to the large volume of dilute gas that needs to be treated and the energy consumed in the separation process. In chemical-looping combustion (CLC), CO{sub 2} and the other combustion products are already separated in the combustion process. This is because fuel and air never enter the same reactor. Instead of oxidizing the fuel with oxygen from the combustion air, the fuel is oxidized by an oxygen carrier, that is, an oxygen containing compound, for instance a metal oxide. Chemical-looping combustion is also thought to result in a higher fuel energy conversion efficiency. It is possible to recover some of the heat from the exhaust within the CLC system. In this paper, estimations of the performance of a chemical-looping combustion combined cycle system with integrated coal gasification and NiO, Fe{sub 2}O{sub 3} or Mn{sub 3}O{sub 4} as an oxygen carrier is compared to the performance of a similarly simulated conventional IGCC-system. Calculations show that the systems reach about the same net power efficiencies but then the chemical-looping systems have an added advantage of CO{sub 2} separation.

Anheden, M.; Svedberg, G. [Royal Inst. of Tech., Stockholm (Sweden)

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Chapter 2 - Chemistry of Gasification  

Science Journals Connector (OSTI)

The gasification of any carbonaceous or hydrocarbonaceous material is, essentially, the conversion of the carbon constituents by any one of a variety of chemical processes to produce combustible gases. The process includes a series of reaction steps that convert the feedstock into synthesis gas (syngas, carbon monoxide, CO, plus hydrogen, H2) and other gaseous products. This conversion is generally accomplished by introducing a gasifying agent (air, oxygen, and/or steam) into a reactor vessel containing the feedstock where the temperature, pressure, and flow pattern (moving bed, fluidized, or entrained bed) are controlled. The gaseous products – other than carbon monoxide and hydrogen – and the proportions of these product gases (such as carbon dioxide, CO2, methane, CH4, water vapor, H2O, hydrogen sulfide, H2S, and sulfur dioxide, SO2) depends on the: (1) type of feedstock, (2) the chemical composition of the feedstock, (3) the gasifying agent or gasifying medium, as well as (4) the thermodynamics and chemistry of the gasification reactions as controlled by the process operating parameters. In addition, the kinetic rates and extents of conversion for the several chemical reactions that are a part of the gasification process are variable and are typically functions of: (1) temperature, (2) pressure, and (3) reactor configuration, and (4) the gas composition of the product gases and whether or not these gases influence the outcome of the reaction. It is the purpose of this chapter to present descriptions of the various reactions involved in gasification of carbonaceous and hydrocarbonaceous feedstocks as well as the various thermodynamic aspects of these reactions which dictate the process parameters used to produce the various gases.

James G. Speight

2014-01-01T23:59:59.000Z

162

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen: SNG from Coal: Process & Commercialization Hydrogen: SNG from Coal: Process & Commercialization Weyburn Project The Great Plains Synfuels Plant (GPSP) has had the ability to capture CO2 through the Rectisol process for sequestration or sale as a byproduct. However, no viable market was found for the CO2 in the early years of operation, and the captured CO2 was simply discharged to the atmosphere. This changed in 2000, when the GPSP began selling CO2 emissions, becoming one of the first commercial coal facilities to have its CO2 sequestered. The program had begun in 1997, when EnCana (formerly PanCanadian Resources) sought a solution to declining production in their Weyburn Oil Fields. Dakota Gasification Company, owners of the GPSP, and EnCana made an agreement to sell CO2 for use in Enhanced Oil Recovery (EOR). DGC installed two large CO2 compressors and began shipping 105 million standard cubic feet per day of compressed CO2 (60% of the total CO2 produced at the plant) through a 205 mile pipeline from Beulah, North Dakota, to the Weyburn Oil Fields, located in Saskatchewan, Canada, for EOR. The pipeline was constructed and operated by a BEPC subsidiary. The CO2, about 95.5% pure and very dry, is injected into the mature fields where it has doubled the oil recovery rate of the field. In 2006, a third compressor was installed and an additional agreement was reached with Apache Canada Ltd. to supply CO2 for EOR to their nearby oilfields. The three compressors increased CO2 delivery to 160 million standard cubic feet (MMSCF; or 8,000 tonnes) per day. Through 2007, over 12 million tons of CO2 had been sold, and over the current expected lifetime of the program, an anticipated 20 million tons of CO2 will be stored.

163

Gasification performance of switchgrass pretreated with torrefaction and densification  

SciTech Connect

The purpose of this study was to investigate gasification performance of four switchgrass pretreatments (torrefaction at 230 and 270 °C, densification, and combined torrefaction and densification) and three gasification temperatures (700, 800 and 900 °C). Gasification was performed in a fixed-bed externally heated reactor with air as an oxidizing agent. Switchgrass pretreatment and gasification temperature had significant effects on gasification performance such as gas yields, syngas lower heating value (LHV), and carbon conversion and cold gas efficiencies. With an increase in the gasification temperature, yields of H2 and CO, syngas LHV, and gasifier efficiencies increased whereas CH4, CO2 and N2 yields decreased. Among all switchgrass pretreatments, gasification performance of switchgrass with combined torrefaction and densification was the best followed by that of densified, raw and torrefied switchgrass. Gasification of combined torrefied and densified switchgrass resulted in the highest yields of H2 (0.03 kg/kg biomass) and CO (0.72 kg/kg biomass), highest syngas LHV (5.08 MJ m-3), CCE (92.53%), and CGE (68.40%) at the gasification temperature of 900 °C.

Jaya Shankar Tumuluru; Various

2014-08-01T23:59:59.000Z

164

The United States of America and the People`s Republic of China experts report on integrated gasification combined-cycle technology (IGCC)  

SciTech Connect

A report written by the leading US and Chinese experts in Integrated Gasification Combined Cycle (IGCC) power plants, intended for high level decision makers, may greatly accelerate the development of an IGCC demonstration project in the People`s Republic of China (PRC). The potential market for IGCC systems in China and the competitiveness of IGCC technology with other clean coal options for China have been analyzed in the report. Such information will be useful not only to the Chinese government but also to US vendors and companies. The goal of this report is to analyze the energy supply structure of China, China`s energy and environmental protection demand, and the potential market in China in order to make a justified and reasonable assessment on feasibility of the transfer of US Clean Coal Technologies to China. The Expert Report was developed and written by the joint US/PRC IGCC experts and will be presented to the State Planning Commission (SPC) by the President of the CAS to ensure consideration of the importance of IGCC for future PRC power production.

NONE

1996-12-01T23:59:59.000Z

165

NETL: Gasifipedia - Gasification in Detail  

NLE Websites -- All DOE Office Websites (Extended Search)

Commercial Gasifiers Commercial Gasifiers Types of Gasifiers Although there are various types of gasifers (gasification reactors), different in design and operational characteristics, there are three main gasifier classifications into which most of the commercially available gasifiers fall. These categories are as follows: Fixed-bed gasifiers (also referred as moving-bed gasifiers) Entrained-flow gasifiers Fluidized-bed gasifiers Commercial gasifiers of GE Energy, ConocoPhillips E-Gas(tm) and Shell SCGP are examples of entrained-flow types. Fixed-or moving-bed gasifiers include that of Lurgi and British Gas Lurgi (BGL). Fluidized-bed gasifiers include the catalytic gasifier technology being commercialized by Great Point Energy, the Winkler gasifier, and the KBR transport gasifiers. For more specific information on these gasifiers, follow the links for the bulleted gasifier types above. NOTE: Although specific gasifiers named above are described in detail throughout this website, it is realized that other gasification technologies exist. The gasifiers discussed herein were not preferentially chosen by NETL.

166

Major Environmental Aspects of Gasification-Based Power Generation Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Detailed Detailed Evaluation of the Environmental Performance of Gasification-Based Power Systems DECEMBER 2002 U.S. DOE/NETL 2-1 2. DETAILED EVALUATION OF THE ENVIRONMENTAL PERFORMANCE OF GASIFICATION-BASED POWER SYTEMS 2.1 Introduction and Summary of Information Presented The single most compelling reason for utilities to consider coal gasification for electric power generation is superior environmental performance. 1 As shown in Figure 2-1, gasification has fundamental environmental advantages over direct coal combustion. Commercial-scale plants for both integrated gasification combined cycle (IGCC) electric power generation and chemicals applications have already successfully demonstrated these advantages. The superior environmental capabilities of coal gasification apply to all three areas of concern: air emissions, water discharges, and solid

167

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur Recovery and Tail Gas Treating Sulfur Recovery and Tail Gas Treating SCOT Tail Gas Treating Figure 1 shows a simplified SCOT tail gas treating unit (TGTU). Tail gas from the Claus SRU is heated in an in-line burner before entering the hydrogenation reactor, where all sulfur species are converted to H2S. Hydrogenation reactor effluent is then cooled by generating low pressure (LP) steam, followed by additional cooling by cooling water exchange. Residual H2S in the cooled tail gas is removed with amine in a counter-current packed absorber. The treated tail gas from the absorber top is incinerated before being vented to the atmosphere. The rich solvent from the amine absorber is pumped to the regenerator after heat exchange against the hot lean solvent from the regenerator. Acid gases are stripped from the solvent in the trayed regenerator via a steam reboiler. The hot lean solvent from the regenerator bottom is pumped back to the absorber after being heat exchanged with rich solvent and cooling water to lower its temperature. Acid gas from TGTU amine regenerator overhead is recycled back to the Claus plant for sulfur recovery.

168

Catalytic steam gasification of coals  

Science Journals Connector (OSTI)

Catalytic steam gasification of coals ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ...

P. Pereira; G. A. Somorjai; H. Heinemann

1992-07-01T23:59:59.000Z

169

NETL: Gasification Archived Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Gasification Systems > Reference Shelf > Archived Projects Home > Technologies > Coal & Power Systems > Gasification Systems > Reference Shelf > Archived Projects Gasification Systems Reference Shelf - Archived Projects Archived Projects | Active Projects | All NETL Fact Sheets Feed Systems Reaction-Driven Ion Transport Membranes Gasifier Optimization and Plant Supporting Systems Coal/Biomass Gasification at Colorado School of Mines Co-Production of Electricity and Hydrogen Using a Novel Iron-Based Catalyst Co-Production of Substitute Natural Gas/Electricity via Catalytic Coal Gasification Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals Hybrid Combustion-Gasification Chemical Looping Coal Power Technology Development

170

Waste to energy by industrially integrated supercritical water gasification – Effects of alkali salts in residual by-products from the pulp and paper industry  

Science Journals Connector (OSTI)

Supercritical water gasification (SCWG) is a method by which biomass can be converted into a hydrogen-rich gas product. Wet industrial waste streams, which contain both organic and inorganic material, are well suited for treatment by SCWG. In this study, the gasification of two streams of biomass resulting from the pulp and paper industry, black liquor and paper sludge, has been investigated. The purpose is to convert these to useful products, both gaseous and solids, which can be used either in the papermaking process or in external applications. Simple compounds, such as glucose, have been fully gasified in SCWG, but gasification of more complex compounds, such as biomass and waste, have not reached as high conversions. The investigated paper sludge was not easily gasified. Improving gasification results with catalysts is an option and the use of alkali salts for this purpose was studied. The relationship between alkali concentration, temperature, and gasification yields was studied with the addition of KOH, K2CO3, NaOH and black liquor to the paper sludge. Addition of black liquor to the paper sludge resulted in similarly enhancing effects as when the alkali salts were added, which made it possible to raise the dry matter content and gasification yield without expensive additives.

I. Rönnlund; L. Myréen; K. Lundqvist; J. Ahlbeck; T. Westerlund

2011-01-01T23:59:59.000Z

171

2007 gasification technologies workshop papers  

SciTech Connect

Topics covered in this workshop are fundamentals of gasification, carbon capture, reviews of financial and regulatory incentives, coal to liquids, and focus on gasification in the Western US.

NONE

2007-03-15T23:59:59.000Z

172

Downdraft gasification of biomass.  

E-Print Network (OSTI)

??The objectives of this research were to investigate the parameters affecting the gasification process within downdraft gasifiers using biomass feedstocks. In addition to investigations with… (more)

Milligan, Jimmy B.

1994-01-01T23:59:59.000Z

173

Coal Gasification Systems Solicitations  

NLE Websites -- All DOE Office Websites (Extended Search)

Low Cost Coal Conversion to High Hydrogen Syngas; FE0023577 Alstom's Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation; FE0023497 OTM-Enhanced...

174

Investigation of nickel supported catalysts for the upgrading of brown peat derived gasification products  

Science Journals Connector (OSTI)

A gasification test rig was designed in which peat was gasified under nitrogen over a temperature range 25–550°C at 5°C min?1. The gasification unit resulted in 35.5 wt% of the carbon present in the peat being converted to a volatile fraction. The volatile fraction was transferred to a secondary catalytic reforming reactor at 800°C. The thermal effect of the second reactor resulted in an increase in the CO, CO2 and CH4 content of the volatile fraction, a syngas ratio of 0.75 and a higher heating value (HHV) of 26.5 MJ kg?1. Several nickel-supported catalysts were investigated with the intention that they should give an increase in the conversion of the condensable hydrocarbons in the volatile fraction to CO, CO2 and CH4, and a resultant gas stream suitable for use in an integrated gasification combined cycle plant (IGCC) (i.e. syngas ratio 2:1, low methane content and better HHV). Alumina-supported nickel catalysts investigated gave the highest activities and co-precipitated Ni/Al catalysts were most active. A Ni/Al 3:17 catalyst increased the conversion of the hydrocarbons to 91.5%, gave a syngas ratio of 1.81:1, increased the HHV by a factor of 5.3 and completely eliminated methane from the gas stream.

David Sutton; Brian Kelleher; Aidan Doyle; J.R.H Ross

2001-01-01T23:59:59.000Z

175

Dynamic simulation and load-following control of an integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture  

SciTech Connect

Load-following control of future integrated gasification combined cycle (IGCC) plants with pre-combustion CO{sub 2} capture is expected to be far more challenging as electricity produced by renewable energy is connected to the grid and strict environmental limits become mandatory requirements. To study control performance during load following, a plant-wide dynamic simulation of a coal-fed IGCC plant with CO{sub 2} capture has been developed. The slurry-fed gasifier is a single-stage, downward-fired, oxygen-blown, entrained-flow type with a radiant syngas cooler (RSC). The syngas from the outlet of the RSC goes to a scrubber followed by a two-stage sour shift process with inter-stage cooling. The acid gas removal (AGR) process is a dual-stage physical solvent-based process for selective removal of H{sub 2}S in the first stage and CO{sub 2} in the second stage. Sulfur is recovered using a Claus unit with tail gas recycle to the AGR. The recovered CO{sub 2} is compressed by a split-shaft multistage compressor and sent for sequestration after being treated in an absorber with triethylene glycol for dehydration. The clean syngas is sent to two advanced “F”-class gas turbines (GTs) partially integrated with an elevated-pressure air separation unit. A subcritical steam cycle is used for heat recovery steam generation. A treatment unit for the sour water strips off the acid gases for utilization in the Claus unit. The steady-state model developed in Aspen Plus® is converted to an Aspen Plus Dynamics® simulation and integrated with MATLAB® for control studies. The results from the plant-wide dynamic model are compared qualitatively with the data from a commercial plant having different configuration, operating condition, and feed quality than what has been considered in this work. For load-following control, the GT-lead with gasifier-follow control strategy is considered. A modified proportional–integral–derivative (PID) control is considered for the syngas pressure control. For maintaining the desired CO{sub 2} capture rate while load-following, a linear model predictive controller (LMPC) is implemented in MATLAB®. A combined process and disturbance model is identified by considering a number of model forms and choosing the final model based on an information-theoretic criterion. The performance of the LMPC is found to be superior to the conventional PID control for maintaining CO{sub 2} capture rates in an IGCC power plant while load following.

Bhattacharyya, D,; Turton, R.; Zitney, S.

2012-01-01T23:59:59.000Z

176

Analysis of kinetic models of the methanol-to-gasoline (MTG) process in an integral reactor  

Science Journals Connector (OSTI)

From experimental results obtained in a wide range of operating conditions (temperature and contact time) in an isothermal fixed bed integral reactor, the validity both of the kinetic models proposed in the literature as well as their modifications, for the methanol-to-gasoline (MTG) process at zero time on-stream, has been studied. The kinetic parameters for the various models have been calculated by solving the equation of mass conservation in the reactor for the lumps of the kinetic models. The usefulness of the model of Schipper and Krambeck for simulating the operation in the isothermal fixed bed integral reactor has been proven in the 573–648 K range.

Ana G. Gayubo; Pedro L. Benito; Andrés T. Aguayo; Itziar Aguirre; Javier Bilbao

1996-01-01T23:59:59.000Z

177

Effects of Feed Composition and Gasification Parameters on Product Gas from a Pilot Scale Fluidized Bed Gasifier.  

E-Print Network (OSTI)

??Biomass gasification is an integral part of a holistic project where low-value feedstocks are converted into ethanol via a gasification-fermentation process. Because microbial catalysts are… (more)

Cateni, Bruno Ghislain

2007-01-01T23:59:59.000Z

178

Coal Gasification in Australia  

Science Journals Connector (OSTI)

... P. S. Andrews gave a full account of the Federal project for the pressure gasification of non-coking coals for the combined purpose of town's gas ' and the ... of town's gas ' and the production of synthetic liquid fuel. Work on the gasification of brown coal in. Victoria was commenced in 1931 by the technical staff of ...

1955-06-11T23:59:59.000Z

179

Gasification: A Cornerstone Technology  

ScienceCinema (OSTI)

NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

Gary Stiegel

2010-01-08T23:59:59.000Z

180

Gasification: A Cornerstone Technology  

SciTech Connect

NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

Gary Stiegel

2008-03-26T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Incentives boost coal gasification  

SciTech Connect

Higher energy prices are making technologies to gasify the USA's vast coal reserves attractive again. The article traces the development of coal gasification technology in the USA. IGCC and industrial gasification projects are now both eligible for a 20% investment tax credit and federal loan guarantees can cover up to 80% of construction costs. 4 photos.

Hess, G.

2006-01-16T23:59:59.000Z

182

Improving process performances in coal gasification for power and synfuel production  

SciTech Connect

This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana [University of Padova, Milan (Italy). Italy and Foster Wheeler Italiana Spa

2008-11-15T23:59:59.000Z

183

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid Gas Removal (AGR) Acid Gas Removal (AGR) Sulfinol Sulfinol solvent is a composite solvent, consisting of a mixture of diisopropanolamine (30-45%) or MDEA, sulfolane (tetrahydrothiophene dioxide) (40-60%), and water (5-15%). The acid gas loading of the Sulfinol solvent is higher and the energy required for its regeneration is lower than those of purely chemical solvents. At the same time it has the advantage over purely physical solvents that severe product specifications can be met more easily and co-absorption of hydrocarbons is relatively low. For selective absorption of H2S, COS and mercaptans, while co-absorbing only part of the CO2, the Sulfinol-M process is used. Deep removal of CO2 in LNG plants is another application. Integration of gas treating with the SCOT solvent system is an option.

184

Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications  

SciTech Connect

This report is a summary of analyses performed by the NGNP project to determine whether it is technically and economically feasible to integrate high temperature gas cooled reactor (HTGR) technology into industrial processes. To avoid an overly optimistic environmental and economic baseline for comparing nuclear integrated and conventional processes, a conservative approach was used for the assumptions and calculations.

Lee Nelson

2011-09-01T23:59:59.000Z

185

2006 gasification technologies conference papers  

SciTech Connect

Sessions covered: business overview, industry trends and new developments; gasification projects progress reports; industrial applications and opportunities; Canadian oil sands; China/Asia gasification markets - status and projects; carbon management with gasification technologies; gasification economics and performance issues addressed; and research and development, and new technologies initiatives.

NONE

2006-07-01T23:59:59.000Z

186

EMERY BIOMASS GASIFICATION POWER SYSTEM  

SciTech Connect

Emery Recycling Corporation (now Emery Energy Company, LLC) evaluated the technical and economical feasibility of the Emery Biomass Gasification Power System (EBGPS). The gasifier technology is owned and being developed by Emery. The Emery Gasifier for this project was an oxygen-blown, pressurized, non-slagging gasification process that novelly integrates both fixed-bed and entrained-flow gasification processes into a single vessel. This unique internal geometry of the gasifier vessel will allow for tar and oil destruction within the gasifier. Additionally, the use of novel syngas cleaning processes using sorbents is proposed with the potential to displace traditional amine-based and other syngas cleaning processes. The work scope within this project included: one-dimensional gasifier modeling, overall plant process modeling (ASPEN), feedstock assessment, additional analyses on the proposed syngas cleaning process, plant cost estimating, and, market analysis to determine overall feasibility and applicability of the technology for further development and commercial deployment opportunities. Additionally, the project included the development of a detailed technology development roadmap necessary to commercialize the Emery Gasification technology. Process modeling was used to evaluate both combined cycle and solid oxide fuel cell power configurations. Ten (10) cases were evaluated in an ASPEN model wherein nine (9) cases were IGCC configurations with fuel-to-electricity efficiencies ranging from 38-42% and one (1) case was an IGFC solid oxide case where 53.5% overall plant efficiency was projected. The cost of electricity was determined to be very competitive at scales from 35-71 MWe. Market analysis of feedstock availability showed numerous market opportunities for commercial deployment of the technology with modular capabilities for various plant sizes based on feedstock availability and power demand.

Benjamin Phillips; Scott Hassett; Harry Gatley

2002-11-27T23:59:59.000Z

187

JV Task 46 - Development and Testing of a Thermally Integrated SOFC-Gasification System for Biomass Power Generation  

SciTech Connect

The Energy & Environmental Research Center has designed a biomass power system using a solid oxide fuel cell (SOFC) thermally integrated with a downdraft gasifier. In this system, the high-temperature effluent from the SOFC enables the operation of a substoichiometric air downdraft gasifier at an elevated temperature (1000 C). At this temperature, moisture in the biomass acts as an essential carbon-gasifying medium, reducing the equivalence ratio at which the gasifier can operate with complete carbon conversion. Calculations show gross conversion efficiencies up to 45% (higher heating value) for biomass moisture levels up to 40% (wt basis). Experimental work on a bench-scale gasifier demonstrated increased tar cracking within the gasifier and increased energy density of the resultant syngas. A series of experiments on wood chips demonstrated tar output in the range of 9.9 and 234 mg/m{sup 3}. Both button cells and a 100-watt stack was tested on syngas from the gasifier. Both achieved steady-state operation with a 22% and 15% drop in performance, respectively, relative to pure hydrogen. In addition, tar tolerance testing on button cells demonstrated an upper limit of tar tolerance of approximately 1%, well above the tar output of the gasifier. The predicted system efficiency was revised down to 33% gross and 27% net system efficiency because of the results of the gasifier and fuel cell experiments. These results demonstrate the feasibility and benefits of thermally integrating a gasifier and a high-temperature fuel cell in small distributed power systems.

Phillip Hutton; Nikhil Patel; Kyle Martin; Devinder Singh

2008-02-01T23:59:59.000Z

188

A Stoichiometric Analysis of Coal Gasification  

Science Journals Connector (OSTI)

A Stoichiometric Analysis of Coal Gasification ... Gasification of New Zealand Coals: A Comparative Simulation Study ... Gasification of New Zealand Coals: A Comparative Simulation Study ...

James Wei

1979-07-01T23:59:59.000Z

189

NETL: Gasification Systems Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Shelf Shelf Gasification Systems Reference Shelf TABLE OF CONTENTS Brochures Conferences and Workshops Gasification Systems Projects National Map Gasification Systems Projects and Performers Gasification Systems Project Portfolio Gasifipedia Multi-phase Flow with Interphase eXchange (MFIX) Patents Program Presentations Project Information Projects Summary Table by State Solicitations Systems and Industry Analyses Studies Technical Presentations & Papers Technology Readiness Assessment (Comprehensive Report | Overview Report) Video, Images & Photos Gasification Plant Databases CD Icon Request Gasification Technologies Information on a CD. Gasification RSS Feed Subscribe to the Gasification RSS Feed to follow website updates. LinkedIn DOE Gasification Program Group Subscribe to the LinkedIn DOE Gasification Program group for more information and discussion.

190

Sawdust Pyrolysis and Petroleum Coke CO2 Gasification at High Heating Rates.  

E-Print Network (OSTI)

??Clean and efficient electricity can be generated using an Integrated Gasification Combined Cycle (IGCC). Although IGCC is typically used with coal, it can also be… (more)

Lewis, Aaron D.

2011-01-01T23:59:59.000Z

191

An integrated approach for the verification of fresh mixed oxide fuel (MOX) assemblies at light water reactor MOX recycle reactors  

SciTech Connect

This paper presents an integrated approach for the verification of mixed oxide (MOX) fuel assemblies prior to their being loaded into the reactor. There is a coupling of the verification approach that starts at the fuel fabrication plant and stops with the transfer of the assemblies into the thermal reactor. The key measurement points are at the output of the fuel fabrication plant, the receipt at the reactor site, and the storage in the water pool as fresh fuel. The IAEA currently has the capability to measure the MOX fuel assemblies at the output of the fuel fabrication plants using a passive neutron coincidence counting systems of the passive neutron collar (PNCL) type. Also. at the MOX reactor pool, the underwater coincidence counter (UWCC) has been developed to measure the MOX assemblies in the water. The UWCC measurement requires that the fuel assembly be lifted about two meters up in the storage rack to avoid interference from the fuel that is stored in the rack. This paper presents a new method to verify the MOX fuel assemblies that are in the storage rack without the necessity of moving the fuel. The detector system is called the Underwater MOX Verification System (UMVS). The integration and relationship of the three measurements systems is described.

Menlove, Howard O [Los Alamos National Laboratory; Lee, Sang - Yoon [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

192

Investigation on syngas production via biomass conversion through the integration of pyrolysis and air–steam gasification processes  

Science Journals Connector (OSTI)

Abstract Fuel production from agro-waste has become an interesting alternative for energy generation due to energy policies and greater understanding of the importance of green energy. This research was carried out in a lab-scale gasifier and coconut shell was used as feedstock in the integrated process. In order to acquire the optimum condition of syngas production, the effect of the reaction temperature, equivalence ratio (ER) and steam/biomass (S/B) ratio was investigated. Under the optimized condition, H2 and syngas yield achieved to 83.3 g/kg feedstock and 485.9 g/kg feedstock respectively, while LHV of produced gases achieved to 12.54 MJ/N m3.

Reza Alipour Moghadam; Suzana Yusup; Wan Azlina; Shahab Nehzati; Ahmad Tavasoli

2014-01-01T23:59:59.000Z

193

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

SciTech Connect

Hydrogen production from coal gasification can be enhanced by driving the equilibrium limited Water Gas Shift reaction forward by incessantly removing the CO{sub 2} by-product via the carbonation of calcium oxide. This project aims at using the OSU patented high-reactivity mesoporous precipitated calcium carbonate sorbent for removing the CO{sub 2} product. Preliminary experiments demonstrate the show the superior performance of the PCC sorbent over other naturally occurring calcium sorbents. Gas composition analyses show the formation of 100% pure hydrogen. Novel calcination techniques could lead to smaller reactor footprint and single-stage reactors that can achieve maximum theoretical H{sub 2} production for multicyclic applications. Sub-atmospheric calcination studies reveal the effect of vacuum level, diluent gas flow rate, thermal properties of the diluent gas and the sorbent loading on the calcination kinetics which play an important role on the sorbent morphology. Steam, which can be easily separated from CO{sub 2}, is envisioned to be a potential diluent gas due to its enhanced thermal properties. Steam calcination studies at 700-850 C reveal improved sorbent morphology over regular nitrogen calcination. A mixture of 80% steam and 20% CO{sub 2} at ambient pressure was used to calcine the spent sorbent at 820 C thus lowering the calcination temperature. Regeneration of calcium sulfide to calcium carbonate was achieved by carbonating the calcium sulfide slurry by bubbling CO{sub 2} gas at room temperature.

Mahesh Iyer; Himanshu Gupta; Danny Wong; Liang-Shih Fan

2005-09-30T23:59:59.000Z

194

Biomass gasification using low-temperature solar-driven steam supply  

Science Journals Connector (OSTI)

Abstract A numerical modeling study on the low-temperature steam gasification process is presented to outline the possibility to drive the process with an integrated Concentrated Solar Power (CSP) plant, which provides low-temperature steam, with the aim of preserving a comparable efficiency of the new plant with traditional high-temperature biomass gasification processes. To meet this, the effective parameters and operating conditions are assessed and determined for low-temperature biomass gasification by means of sensitivity analysis, in order to find out the optimal design of the new gasifier. Crucial parameters comprise the residence time of the solid fuel and of the gas phase (leading to efficient gas–solid interactions), as well as the amount of injected oxygen and steam. Moreover, several operative parameters such as content of moisture in the biomass feedstock, size of the solid particles, equivalence ratio and structural components amount in the biomass feedstock are taken into account to optimize the operation. The molar ratio of H2/CO has been selected as a benchmark of efficiency in the process because the produced syngas would be applied in the methanol synthesis process, which needs a molar ratio of H2/CO close to the value of two. The percentage of the solid residue (weight % of the solid feedstock) has been evaluated along with the molar ratio of H2/CO in the low-temperature process to guide the re-design of the solar driven gasifier, in terms of reactor volume and amount of required oxygen and steam, which are necessary to sustain the process. The modeling and simulation to design the process have been accomplished by a comprehensive modeling package (GASDS), which includes kinetics of biomass devolatilization and pyrolysis, gasification, and secondary gas phase kinetic schemes. The gasifier, owing to its intrinsic multi-scale nature, is simulated describing both the particle and the reactor scales.

Zohreh Ravaghi-Ardebili; Flavio Manenti; Michele Corbetta; Carlo Pirola; Eliseo Ranzi

2015-01-01T23:59:59.000Z

195

The suitability of coal gasification in India's energy sector  

E-Print Network (OSTI)

Integrated Gasification Combined Cycle (IGCC), an advanced coal-based power generation technology, may be an important technology to help India meet its future power needs. It has the potential to provide higher generating ...

Simpson, Lori Allison

2006-01-01T23:59:59.000Z

196

Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification  

E-Print Network (OSTI)

Gasification is a thermo-chemical process which transforms biomass into valuable synthesis gas. Integrated with a biorefinery it can address the facility’s residue handling challenges and input demands. A number of feedstock, technology, oxidizer...

Georgeson, Adam

2012-02-14T23:59:59.000Z

197

INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING  

SciTech Connect

This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

Eric P. Robertson; Michael G. McKellar; Lee O. Nelson

2011-05-01T23:59:59.000Z

198

NETL: Gasification Systems - Gasifier Optimization  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifier Opt & Plant Supporting Systems Gasifier Opt & Plant Supporting Systems Gasification Systems Gasifier Optimization and Plant Supporting Systems The gasifier is the core system component in the gasification process. It determines both the primary requirements for raw material inputs and the product gas composition. The gasifier is generally a high temperature/pressure vessel where oxygen (or air) and steam are directly contacted with a fuel, such as coal, causing a series of chemical reactions to occur that result in production of a fuel gas. This fuel gas (also referred to either as synthesis gas or syngas) consists primarily of hydrogen, carbon monoxide, and carbon dioxide. Minor constituents present in the feedstock are converted to such products as hydrogen sulfide, ammonia, and ash/slag (mineral residues from coal). These products can be separated and captured for use or safe disposal. After cleaning to remove contaminants, the syngas consists mainly of carbon monoxide and hydrogen. According to the Department of Energy's vision for coal gasification, at this point steam may be added and the syngas sent through a water-gas shift (WGS) reactor to convert the carbon monoxide to nothing but carbon dioxide and additional hydrogen. After a gas separation process, the carbon dioxide is ready for utilization (such as for Enhanced Oil Recovery) or safe storage, and the hydrogen can be fired in a gas-turbine/steam-turbine generator set to produce electricity with stack emissions containing no greenhouse gases. Alternately, syngas or hydrogen can be used to produce highly-valued fuels and chemicals. Co-production of combinations of these products and electricity is also possible.

199

Plasma Treatments and Biomass Gasification  

Science Journals Connector (OSTI)

Exploitation of forest resources for energy production includes various methods of biomass processing. Gasification is one of the ways to recover energy from biomass. Syngas produced from biomass can be used to power internal combustion engines or, after purification, to supply fuel cells. Recent studies have shown the potential to improve conventional biomass processing by coupling a plasma reactor to a pyrolysis cyclone reactor. The role of the plasma is twofold: it acts as a purification stage by reducing production of tars and aerosols, and simultaneously produces a rich hydrogen syngas. In a first part of the paper we present results obtained from plasma treatment of pyrolysis oils. The outlet gas composition is given for various types of oils obtained at different experimental conditions with a pyrolysis reactor. Given the complexity of the mixtures from processing of biomass, we present a study with methanol considered as a model molecule. This experimental method allows a first modeling approach based on a combustion kinetic model suitable to validate the coupling of plasma with conventional biomass process. The second part of the paper is summarizing results obtained through a plasma-pyrolysis reactor arrangement. The goal is to show the feasibility of this plasma-pyrolysis coupling and emphasize more fundamental studies to understand the role of the plasma in the biomass treatment processes.

J Luche; Q Falcoz; T Bastien; J P Leninger; K Arabi; O Aubry; A Khacef; J M Cormier; J Lédé

2012-01-01T23:59:59.000Z

200

Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture  

SciTech Connect

Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics® (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel Computing® toolbox from Mathworks®. In this presentation, we will share our experience in setting up parallel computing using GA in the MATLAB® environment and present the overall approach for achieving higher computational efficiency in this framework.

Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

2012-01-01T23:59:59.000Z

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201

Coal gasification for power generation. 2nd ed.  

SciTech Connect

The report gives an overview of the opportunities for coal gasification in the power generation industry. It provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered in the report include: An overview of coal generation including its history, the current market environment, and the status of coal gasification; A description of gasification technology including processes and systems; An analysis of the key business factors that are driving increased interest in coal gasification; An analysis of the barriers that are hindering the implementation of coal gasification projects; A discussion of Integrated Gasification Combined Cycle (IGCC) technology; An evaluation of IGCC versus other generation technologies; A discussion of IGCC project development options; A discussion of the key government initiatives supporting IGCC development; Profiles of the key gasification technology companies participating in the IGCC market; and A description of existing and planned coal IGCC projects.

NONE

2006-10-15T23:59:59.000Z

202

Gasification Â… Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Clearwater Clean Coal Conference, Clearwater, Florida, June 5 to 9, 2011 Clearwater Clean Coal Conference, Clearwater, Florida, June 5 to 9, 2011 Gasification Technologies Advances for Future Energy Plants Jenny B. Tennant Technology Manager - Gasification 2 Gasification Program Goal "Federal support of scientific R&D is critical to our economic competitiveness" Dr. Steven Chu, Secretary of Energy November 2010 The goal of the Gasification Program is to reduce the cost of electricity, while increasing power plant availability and efficiency, and maintaining the highest environmental standards 3 Oxygen Membrane - APCI - 25% capital cost reduction - 5.0% COE reduction Warm Gas Cleaning - RTI in combination with H 2 /CO 2 Membrane - Eltron - 2.9 % pt efficiency increase - 12% COE decrease Oxygen CO 2 H 2 rich stream Water Gas Shift*

203

NETL: Gasification Systems - Solicitations  

NLE Websites -- All DOE Office Websites (Extended Search)

Shelf > Solicitations Shelf > Solicitations Gasification Systems Solicitations All NETL Solicitations / Funding Opportunity Announcements (FOA) Gasification RSS Feed NETL RSS Feeds: List of available NETL RSS feeds. Business & Solicitations RSS: Subscribe to this to be notified of all NETL solicitations or FOA postings. Gasification RSS: Subscribe to this to be notified of Gasification news, solicitations and FOA postings. Business Alert Notification System Official notification is available through the Business Alert Notification System. *These notifications are provided as a courtesy and there may be a delay between the opportunity announcement and the arrival of the alert. SOLICITATION TITLE / AWARDS ANNOUNCEMENT PROJECT PAGE(S) 12.11.13: Fossil Energy's Request for Information DE-FOA-0001054; titled "Novel Crosscutting Research and Development to Support Advanced Energy Systems." Application due date is January 15, 2014. Applications and/or instructions can be found with this Funding Opportunity Announcement on FedConnect.

204

Gasification Â… Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

th th Annual International Colloquium on Environmentally Preferred Advanced Power Generation, Costa Mesa, CA, February 7, 2012 An Overview of U.S. DOE's Gasification Systems Program Jenny B. Tennant Technology Manager - Gasification 2 Gasification Program Goal "Federal support of scientific R&D is critical to our economic competitiveness" Dr. Steven Chu, Secretary of Energy November 2010 The goal of the Gasification Program is to reduce the cost of electricity, while increasing power plant availability and efficiency, and maintaining the highest environmental standards 3 U.S. Coal Resources Low rank: lignite and sub-bituminous coal - About 50% of the U.S. coal reserves - Nearly 50% of U.S. coal production - Lower sulfur Bituminous coal

205

Coal gasification: Belgian first  

Science Journals Connector (OSTI)

... hope for Europe's coal production came with the announcement this month that the first gasification of coal at depths of nearly 1,000 metres would take place this May in ... of energy.

Jasper Becker

1982-03-04T23:59:59.000Z

206

The integral fast reactor fuels reprocessing laboratory at Argonne National Laboratory, Illinois  

SciTech Connect

The processing of Integral Fast Reactor (IFR) metal fuel utilizes pyrochemical fuel reprocessing steps. These steps include separation of the fission products from uranium and plutonium by electrorefining in a fused salt, subsequent concentration of uranium and plutonium for reuse, removal, concentration, and packaging of the waste material. Approximately two years ago a facility became operational at Argonne National Laboratory-Illinois to establish the chemical feasibility of proposed reprocessing and consolidation processes. Sensitivity of the pyroprocessing melts to air oxidation necessitated operation in atmosphere-controlled enclosures. The Integral Fast Reactor Fuels Reprocessing Laboratory is described.

Wolson, R.D.; Tomczuk, Z.; Fischer, D.F.; Slawecki, M.A.; Miller, W.E.

1986-09-01T23:59:59.000Z

207

Light Water Reactor Sustainability Program Integrated Program Plan  

SciTech Connect

Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline—even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy’s Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration’s energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans.

Kathryn McCarthy; Jeremy Busby; Bruce Hallbert; Shannon Bragg-Sitton; Curtis Smith; Cathy Barnard

2013-04-01T23:59:59.000Z

208

Light Water Reactor Sustainability Program Integrated Program Plan  

SciTech Connect

Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline—even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy’s Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration’s energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans.

McCarthy, Kathryn A [INL; Busby, Jeremy [ORNL; Hallbert, Bruce [INL; Bragg-Sitton, Shannon [INL; Smith, Curtis [INL; Barnard, Cathy [INL

2014-04-01T23:59:59.000Z

209

Light Water Reactor Sustainability Program Integrated Program Plan  

SciTech Connect

Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline - even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy's Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration's energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program's plans.

George Griffith; Robert Youngblood; Jeremy Busby; Bruce Hallbert; Cathy Barnard; Kathryn McCarthy

2012-01-01T23:59:59.000Z

210

Gasification characteristics of eastern oil shale  

SciTech Connect

The Institute of Gas Technology (IGT) is evaluating the gasification characteristics of Eastern oil shales as a part of a cooperative agreement between the US Department of Energy and HYCRUDE Corporation to expand the data base on moving-bed hydroretorting of Eastern oil shales. Gasification of shale fines will improve the overall resource utilization by producing synthesis gas or hydrogen needed for the hydroretorting of oil shale and the upgrading of shale oil. Gasification characteristics of an Indiana New Albany oil shale have been determined over temperature and pressure ranges of 1600 to 1900/sup 0/F and 15 to 500 psig, respectively. Carbon conversion of over 95% was achieved within 30 minutes at gasification conditions of 1800/sup 0/F and 15 psig in a hydrogen/steam gas mixture for the Indiana New Albany oil shale. This paper presents the results of the tests conducted in a laboratory-scale batch reactor to obtain reaction rate data and in a continuous mini-bench-scale unit to obtain product yield data. 2 refs., 7 figs., 4 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1986-11-01T23:59:59.000Z

211

Underground coal gasification: a brief review of current status  

SciTech Connect

Coal gasification is a promising option for the future use of coal. Similarly to gasification in industrial reactors, underground coal gasification (UCG) produces syngas, which can be used for power generation or for the production of liquid hydrocarbon fuels and other valuable chemical products. As compared with conventional mining and surface gasification, UCG promises lower capital/operating costs and also has other advantages, such as no human labor underground. In addition, UCG has the potential to be linked with carbon capture and sequestration. The increasing demand for energy, depletion of oil and gas resources, and threat of global climate change lead to growing interest in UCG throughout the world. In this article, we review the current status of this technology, focusing on recent developments in various countries.

Shafirovich, E.; Varma, A. [Purdue University, West Lafayette, IN (United States). School of Chemical Engineering

2009-09-15T23:59:59.000Z

212

Co-gasification of petroleum coke and biomass  

Science Journals Connector (OSTI)

Abstract Gasification may be an attractive alternative for converting heavy oil residue – petroleum coke into valuable synthetic gas. Due to the low reactivity of petroleum coke, it is maybe preferable to convert it in combination with other fuels such as biomass. Co-gasification of petroleum coke and biomass was studied in an atmospheric bubbling fluidised bed reactor and a thermogravimetric analyser (TGA) at KTH Royal University of Technology. Biomass ash in the blends was found to have a catalytic effect on the reactivity of petroleum coke during co-gasification. Furthermore, this synergetic effect between biomass and petcoke was observed in the kinetics data. The activation energy Ea determined from the Arrhenius law for pure petcoke steam gasification in the TGA was 121.5 kJ/mol, whereas for the 50/50 mixture it was 96.3, and for the 20/80 blend – 83.5 kJ/mol.

Vera Nemanova; Araz Abedini; Truls Liliedahl; Klas Engvall

2014-01-01T23:59:59.000Z

213

Gasification of Canola Meal and Factors Affecting Gasification Process  

Science Journals Connector (OSTI)

Non-catalytic gasification of canola meal for the production of ... in order to study the effects of different gasification parameters on gas composition, H2/CO ratio, gas yield, syngas yield, lower heating value...

Ashwini Tilay; Ramin Azargohar; Regan Gerspacher; Ajay Dalai…

2014-03-01T23:59:59.000Z

214

Progress and status of the Integral Fast Reactor (IFR) fuel cycle development  

SciTech Connect

The Integral Fast Reactor (IFR) fuel cycle holds promise for substantial improvements in economics, diversion-resistance, and waste management. This paper discusses technical features of the IFR fuel cycle, its technical progress, the development status, and the future plans and directions.

Till, C.E.; Chang, Y.I.

1993-01-01T23:59:59.000Z

215

Progress and status of the Integral Fast Reactor (IFR) fuel cycle development  

SciTech Connect

The Integral Fast Reactor (IFR) fuel cycle holds promise for substantial improvements in economics, diversion-resistance, and waste management. This paper discusses technical features of the IFR fuel cycle, its technical progress, the development status, and the future plans and directions.

Till, C.E.; Chang, Y.I.

1993-03-01T23:59:59.000Z

216

Progress and status of the Integral Fast Reactor (IFR) fuel cycle development  

SciTech Connect

The Integral Fast Reactor (IFR) fuel cycle holds promise for substantial improvements in economics, diversion-resistance, and waste management. This paper discusses technical features of the IFR fuel cycle, its technical progress, the development status, and the future plans and directions. 10 refs.

Till, C.E.; Chang, Y.I.

1991-01-01T23:59:59.000Z

217

Status of Coal Gasification: 1977  

Science Journals Connector (OSTI)

High-pressure technology is important to coal gasification for several reasons. When the end product ... of high pressures in all types of coal gasification reduces the pressure drop throughout the equipment,...

F. C. Schora; W. G. Bair

1979-01-01T23:59:59.000Z

218

Gasification of selected woody plants  

Science Journals Connector (OSTI)

The article contains laboratory data comparing the rate of gasification of five types of woody plants—beech, ... oak, willow, poplar and rose. The gasification rate was determined thermogravimetrically. Carbon di...

Buryan Petr

2014-07-01T23:59:59.000Z

219

NETL: C&CBTL - Investigation of Coal-Biomass Catalytic Gasification Using  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed and Gasification Coal/Biomass Feed and Gasification Investigation of Coal-Biomass Catalytic Gasification Using Experiments, Reaction Kinetics and Computational Fluid Dynamics Virginia Polytechnic Institute and State University Project Number: FE0005476 Project Description The objectives of the proposed study are to obtain experimental reactor data and develop kinetic rate expressions for pyrolysis and char gasification for the coal-biomass blends under conditions free from transport limitations, to develop a detailed understanding of the effect of pyrolysis conditions on the porous char structure, to build mathematical models that combine true kinetic rate expressions with transport models for predicting gasification behavior for a broad range of pressures and temperatures, and to investigate the physical and chemical parameters that might lead to synergistic effects in coal-biomass blends gasification.

220

Influence of Proteins on the Hydrothermal Gasification and Liquefaction of Biomass. 1. Comparison of Different Feedstocks  

Science Journals Connector (OSTI)

The hydrothermal gasification of glucose with the addition of K2CO3 and two biomass feedstocks was performed in a continuous stirred tank reactor at 500 °C and 30 MPa. ...

Andrea Kruse; Andrzej Krupka; Valentin Schwarzkopf; Céline Gamard; Thomas Henningsen

2005-03-17T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

MODELLING THE LOW-TAR BIG GASIFICATION CONCEPT Lars Andersen, Brian Elmegaard, Bjrn Qvale, Ulrik Henriksen  

E-Print Network (OSTI)

and gasification chamber are bubbling fluid beds, fluidised with steam. For moist fuels, the gasifier can be integrated with a steam drying process, where the produced steam is used in the pyrolysis plant systems: Gas engine, Simple cycle gas turbine, Recuperated gas turbine and Integrated Gasification

222

Actinide recycle potential in the IFR (Integral Fast Reactor)  

SciTech Connect

Rising concern about the greenhouse effect reinforces the need to reexamine the question of a next-generation reactor concept that can contribute significantly toward substitution for fossil-based energy generation. Even with only the nuclear capacity on-line today, world-wide reasonably assured uranium resources would last for only about 50 years. If nuclear is to make a significant contribution, breeding is a fundamental requirement. Uranium resources can then be extended by two orders of magnitude, making nuclear essentially a renewable energy source. The key technical elements of the IFR concept are metallic fuel and fuel cycle technology based on pyroprocessing. Pyroprocessing is radically different from the conventional PUREX reprocessing developed for the LWR oxide fuel. Chemical feasibility of pyroprocessing has been demonstrated. The next major step in the IFR development program will be the full-scale pyroprocessing demonstration to be carried out in conjunction with EBR-II. IFR fuel cycle closure based on pyroprocessing can also have a dramatic impact on the waste management options, and in particular on the actinide recycling. 6 figs.

Chang, Y.I.

1989-01-01T23:59:59.000Z

223

Benchmarking Biomass Gasification Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Biomass Gasification Technologies for Biomass Gasification Technologies for Fuels, Chemicals and Hydrogen Production Prepared for U.S. Department of Energy National Energy Technology Laboratory Prepared by Jared P. Ciferno John J. Marano June 2002 i ACKNOWLEDGEMENTS The authors would like to express their appreciation to all individuals who contributed to the successful completion of this project and the preparation of this report. This includes Dr. Phillip Goldberg of the U.S. DOE, Dr. Howard McIlvried of SAIC, and Ms. Pamela Spath of NREL who provided data used in the analysis and peer review. Financial support for this project was cost shared between the Gasification Program at the National Energy Technology Laboratory and the Biomass Power Program within the DOE's Office of Energy Efficiency and Renewable Energy.

224

Dynamic Complexity Study of Nuclear Reactor and Process Heat Application Integration  

SciTech Connect

Abstract This paper describes the key obstacles and challenges facing the integration of nuclear reactors with process heat applications as they relate to dynamic issues. The paper also presents capabilities of current modeling and analysis tools available to investigate these issues. A pragmatic approach to an analysis is developed with the ultimate objective of improving the viability of nuclear energy as a heat source for process industries. The extension of nuclear energy to process heat industries would improve energy security and aid in reduction of carbon emissions by reducing demands for foreign derived fossil fuels. The paper begins with an overview of nuclear reactors and process application for potential use in an integrated system. Reactors are evaluated against specific characteristics that determine their compatibility with process applications such as heat outlet temperature. The reactor system categories include light water, heavy water, small to medium, near term high-temperature, and far term high temperature reactors. Low temperature process systems include desalination, district heating, and tar sands and shale oil recovery. High temperature processes that support hydrogen production include steam reforming, steam cracking, hydrogen production by electrolysis, and far-term applications such as the sulfur iodine chemical process and high-temperature electrolysis. A simple static matching between complementary systems is performed; however, to gain a true appreciation for system integration complexity, time dependent dynamic analysis is required. The paper identifies critical issues arising from dynamic complexity associated with integration of systems. Operational issues include scheduling conflicts and resource allocation for heat and electricity. Additionally, economic and safety considerations that could impact the successful integration of these systems are considered. Economic issues include the cost differential arising due to an integrated system and the economic allocation of electricity and heat resources. Safety issues include changes in regulatory constraints imposed on the facilities. Modeling and analysis tools, such as System Dynamics for time dependent operational and economic issues and RELAP5 3D for chemical transient affects, are evaluated. The results of this study advance the body of knowledge toward integration of nuclear reactors and process heat applications.

J'Tia Patrice Taylor; David E. Shropshire

2009-09-01T23:59:59.000Z

225

Comparative Analysis of Alternative Configurations of the Mercury 50 Recuperated Gas-Turbine-Based Biomass Integrated Gasification Combined Heat and Power (BIGCHP) Plant  

Science Journals Connector (OSTI)

In this paper, several original configurations of the cogeneration system based on different gasification technologies and Mercury 50 recuperated gas turbine are proposed and examined theoretically. ... (14) Another key problem of the successful commercialization of the technology is the commercial availability of reliable and efficient gas turbines (GTs) modified for syngas operation. ... In particular, the paper presents current development status and design challenges being addressed by Siemens Westinghouse Power Corp. for large industrial engines (>200 MW) and by Solar Turbines for smaller engines (Turbine Systems (ATS) program. ...

Jacek Kalina

2011-11-29T23:59:59.000Z

226

NETL: Gasification - Recovery Act: High Temperature Syngas Cleanup  

NLE Websites -- All DOE Office Websites (Extended Search)

Program Background and Project Benefits Program Background and Project Benefits Gasification is used to convert a solid feedstock, such as coal, petcoke, or biomass, into a gaseous form, referred to as synthesis gas or syngas, which is primarily hydrogen and carbon monoxide. With gasification-based technologies, pollutants can be captured and disposed of or converted to useful products. Gasification can generate clean power by adding steam to the syngas in a water-gas-shift reactor to convert the carbon monoxide to carbon dioxide (CO2) and to produce additional hydrogen. The hydrogen and CO2 are separated-the hydrogen is used to make power and the CO2 is sent to storage, converted to useful products or used for EOR. In addition to efficiently producing electric power, a wide range of transportation fuels and chemicals can be produced from the cleaned syngas, thereby providing the flexibility needed to capitalize on the changing economic market. As a result, gasification provides a flexible technology option for using domestically available resources while meeting future environmental emission standards. Polygeneration plants that produce multiple products are uniquely possible with gasification technologies. The Gasification Systems program is developing technologies in three key areas to reduce the cost and increase the efficiency of producing syngas: (1) Feed Systems, (2) Gasifier Optimization and Plant Supporting Systems, and (3) Syngas Processing Systems.

227

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

NLE Websites -- All DOE Office Websites (Extended Search)

Program Background and Project Benefits Program Background and Project Benefits Gasification is used to convert a solid feedstock, such as coal, petcoke, or biomass, into a gaseous form, referred to as synthesis gas or syngas, which is primarily hydrogen and carbon monoxide. With gasification-based technologies, pollutants can be captured and disposed of or converted to useful products. Gasification can generate clean power by adding steam to the syngas in a water-gas-shift reactor to convert the carbon monoxide to carbon dioxide (CO2) and to produce additional hydrogen. The hydrogen and CO2 are separated-the hydrogen is used to make power and the CO2 is sent to storage, converted to useful products or used for EOR. In addition to efficiently producing electric power, a wide range of transportation fuels and chemicals can be produced from the cleaned syngas, thereby providing the flexibility needed to capitalize on the changing economic market. As a result, gasification provides a flexible technology option for using domestically available resources while meeting future environmental emission standards. Polygeneration plants that produce multiple products are uniquely possible with gasification technologies. The Gasification Systems program is developing technologies in three key areas to reduce the cost and increase the efficiency of producing syngas: (1) Feed Systems, (2) Gasifier Optimization and Plant Supporting Systems, and (3) Syngas Processing Systems.

228

Gasification of black liquor  

DOE Patents (OSTI)

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

Kohl, Arthur L. (Woodland Hills, CA)

1987-07-28T23:59:59.000Z

229

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

NLE Websites -- All DOE Office Websites (Extended Search)

Presentations, Papers, and Publications Presentations, Papers, and Publications ITM Oxygen Development for Advanced Oxygen Supply (Oct 2011) Ted Foster, Air Products & Chemicals, Inc. presented at the Gasification Technologies Conference, San Francisco, CA Oct 9-12, 2011. ASU/IGCC Integration Strategies (Oct 2009), David McCarthy, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Taking the Next Step (Oct 2009), VanEric Stein, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Scaling Up a Low-Cost Oxygen Supply Technology (Oct 2006) Philip Armstrong, Air Products & Chemicals, Inc., 2006 Gasification Technologies Conference, Washington, D.C. ITM Oxygen: The New Oxygen Supply for the New IGCC Market (Oct 2005)

230

Mass tracking and material accounting in the Integral Fast Reactor (IFR)  

SciTech Connect

The Integral Fast Reactor (IFR) is a generic advanced liquid metal cooled reactor concept being developed at Argonne National Laboratory (ANL). There are a number of technical features of the IFR which contribute to its potential as a next-generation reactor. These are associated with large safety margins with regard to off-normal events involving the heat transport system, and the use of metallic fuel which makes possible the utilization of innovative fuel cycle processes. The latter feature permits fuel cycle closure the compact, low-cost reprocessing facilities, collocated with the reactor plant. These primary features are being demonstrated in the facilities at ANL-West, utilizing Experimental Breeder Reactor 2 and the associated Fuel Cycle Facility (FCF) as an IFR prototype. The demonstration of this IFR prototype includes the design and implementation of the Mass-Tracking System (MTG). In this system, data from the operations of the FCF, including weights and batch-process parameters, are collected and maintained by the MTG running on distributed workstations. The components of the MTG System include: (1) an Oracle database manager with a Fortran interface, (2) a set of MTG Tasks'' which collect, manipulate and report data, (3) a set of MTG Terminal Sessions'' which provide some interactive control of the Tasks, and (4) a set of servers which manage the Tasks and which provide the communications link between the MTG System and Operator Control Stations, which control process equipment and monitoring devices within the FCF.

Orechwa, Y.; Adams, C.H.; White, A.M.

1991-01-01T23:59:59.000Z

231

Mass tracking and material accounting in the integral fast reactor (IFR)  

SciTech Connect

This paper reports on the Integral Fast Reactor (IFR) which is a generic advanced liquid metal cooled reactor concept being developed at Argonne National Laboratory. There are a number of technical features of the IFR which contribute to its potential as a next-generation reactor. These are associated with large safety margins with regard to off-normal events involving the heat transport system, and the use of metallic fuel which makes possible the utilization of innovative fuel cycle processes. The latter feature permits fuel cycle closure with compact, low-cost reprocessing facilities, collocated with the reactor plant. These primary features are being demonstrated in the facilities at ANL-West, utilizing Experimental Breeder Reactor II and the associated Fuel Cycle Facility (FCF) as an IFR prototype. The demonstration of this IFR prototype includes the design and implementation of the Mass-tracking System (MTG). In this system, data from the operations of the FCF, including weights and batch-process parameters, are collected and maintained by the MTG running on distributed workstations.

Orechwa, Y.; Adams, C.H.; White, A.M. (Argonne National Lab., IL (United States). Reactor Analysis and Safety Div.)

1991-01-01T23:59:59.000Z

232

NETL: 2010 World Gasification Database Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Gasification Systems > 2010 World Gasification Database Home > Technologies > Coal & Power Systems > Gasification Systems > 2010 World Gasification Database Gasification Systems 2010 Worldwide Gasification Database Archive DOE/NETL 2010 Worldwide Gasification Database Worldwide Gasification Database Analysis The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers.

233

NETL: Gasifipedia - Gasification in Detail  

NLE Websites -- All DOE Office Websites (Extended Search)

Fundamentals Fundamentals Gasification is a partial oxidation process. The term partial oxidation is a relative term which simply means that less oxygen is used in gasification than would be required for combustion (i.e., burning or complete oxidation) of the same amount of fuel. Gasification typically uses only 25 to 40 percent of the theoretical oxidant (either pure oxygen or air) to generate enough heat to gasify the remaining unoxidized fuel, producing syngas. The major combustible products of gasification are carbon monoxide (CO) and hydrogen (H2), with only a minor amount of the carbon completely oxidized to carbon dioxide (CO2) and water. The heat released by partial oxidation provides most of the energy needed to break up the chemical bonds in the feedstock, to drive the other endothermic gasification reactions, and to increase the temperature of the final gasification products.

234

Pioneering Gasification Plants | Department of Energy  

Energy Savers (EERE)

lighting street lights fueled by "town gas," frequently the product of early forms of coal gasification. Gasification of fuel also provided fuel for steel mills, and toward the...

235

Catalytic Coal Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Coal Gasification Process Catalytic Coal Gasification Process for the Production of Methane-Rich Syngas Opportunity Research is active on the patent pending technology, titled "Production of Methane-Rich Syngas from Fuels Using Multi-functional Catalyst/Capture Agent." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Reducing pollution emitted by coal and waste power plants in an economically viable manner and building power plants that co-generate fuels and chemicals during times of low electricity demand are pressing goals for the energy industry. One way to achieve these goals in an economically viable manner is through the use of a catalytic gasifier that

236

The Complete Gasification of Coal  

Science Journals Connector (OSTI)

... plant designed by C. B. Tully, and operated at Bedford, for the complete gasification of coal. Altogether, since 1919, about two hundred such plants have been erected ...

J. S. G. THOMAS

1923-06-09T23:59:59.000Z

237

Conceptual design report -- Gasification Product Improvement Facility (GPIF)  

SciTech Connect

The problems heretofore with coal gasification and IGCC concepts have been their high cost and historical poor performance of fixed-bed gasifiers, particularly on caking coals. The Gasification Product Improvement Facility (GPIF) project is being developed to solve these problems through the development of a novel coal gasification invention which incorporates pyrolysis (carbonization) with gasification (fixed-bed). It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration caused in the conventional process of gradually heating coal through the 400 F to 900 F range. In so doing, the coal is rapidly heated sufficiently such that the coal tar exists in gaseous form rather than as a liquid. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can become chemically bound to aluminosilicates in (or added to) the ash. To reduce NH{sub 3} and HCN from fuel born nitrogen, steam injection is minimized, and residual nitrogen compounds are partially chemically reduced in the cracking stage in the upper gasifier region. Assuming testing confirms successful deployment of all these integrated processes, future IGCC applications will be much simplified, require significantly less mechanical components, and will likely achieve the $1,000/kWe commercialized system cost goal of the GPIF project. This report describes the process and its operation, design of the plant and equipment, site requirements, and the cost and schedule. 23 refs., 45 figs., 23 tabs.

Sadowski, R.S.; Skinner, W.H.; House, L.S.; Duck, R.R. [CRS Sirrine Engineers, Inc., Greenville, SC (United States); Lisauskas, R.A.; Dixit, V.J. [Riley Stoker Corp., Worcester, MA (United States); Morgan, M.E.; Johnson, S.A. [PSI Technology Co., Andover, MA (United States). PowerServe Div.; Boni, A.A. [PSI-Environmental Instruments Corp., Andover, MA (United States)

1994-09-01T23:59:59.000Z

238

Fluidized-bed gasification of an eastern oil shale  

SciTech Connect

The current conceptual HYTORT process design for the hydroretorting of oil shales employs moving-bed retorts that utilize shale particles larger than 3 mm. Work at the Institute of Gas Technology (IGT) is in progress to investigate the potential of high-temperature (1100 to 1300 K) fluidized-bed gasification of shale fines (<3 mm size) using steam and oxygen as a technique for more complete utilization of the resource. Synthesis gas produced from fines gasification can be used for making some of the hydrogen needed in the HYTORT process. After completing laboratory-scale batch and continuous gasification tests with several Eastern oil shales, two tests with Indiana New Albany shale were conducted in a 0.2 m diameter fluidized-bed gasification process development unit (PDU). A conceptual gasifier design for 95% carbon conversion was completed. Gasification of 20% of the mined shale can produce the hydrogen required by the HYTORT reactor to retort 80% of the remaining shale. 12 refs., 1 fig., 5 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-01-01T23:59:59.000Z

239

NETL: Gasification - Request Gasification Systems Information on a CD  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Gasification Systems Request Gasification Systems Information on a CD Please fill in the form below to receive the CDs of your choice. * Denotes required field Requestor Contact Information Requested By (Agency/Company): First Name: * Last Name: * Address: * PO Box: City: * State: * Zip: * Country: Email: * Phone: CD Request Select CD(s):* Gasification Systems Project Portfolio Gasification Technologies Training Course Special Instructions: Submit Request Reset Contacts Program Contact: Jenny Tennant (304) 285-4830 jenny.tennant@netl.doe.gov Close Contacts Disclaimer Disclaimer of Liability: This system is made available by an agency of the United States Government. Neither the United States Government, the Department of Energy, the National Energy Technology Laboratory, nor any of

240

A Review of Proposed Upgrades to the High Flux Isotope Reactor and Potential Impacts to Reactor Vessel Integrity  

SciTech Connect

The High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) was scheduled in October 2000 to implement design upgrades that include the enlargement of the HB-2 and HB-4 beam tubes. Higher dose rates and higher radiation embrittlement rates were predicted for the two beam-tube nozzles and surrounding vessel areas. ORNL had performed calculations for the upgraded design to show that vessel integrity would be maintained at acceptable levels. Pacific Northwest National Laboratory (PNNL) was requested by the U.S. Department of Energy Headquarters (DOE/HQ) to perform an independent peer review of the ORNL evaluations. PNNL concluded that the calculated probabilities of failure for the HFIR vessel during hydrostatic tests and for operational conditions as estimated by ORNL are an acceptable basis for selecting pressures and test intervals for hydrostatic tests and for justifying continued operation of the vessel. While there were some uncertainties in the embrittlement predictions, the ongoing efforts at ORNL to measure fluence levels at critical locations of the vessel wall and to test materials from surveillance capsules should be effective in dealing with embrittlement uncertainties. It was recommended that ORNL continue to update their fracture mechanics calculations to reflect methods and data from ongoing research for commercial nuclear power plants. Such programs should provide improved data for vessel fracture mechanics calculations.

Simonen, Fredric A.

2001-05-31T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

NETL: Gasification Systems - Gasifier Optimization  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Program Gasification Systems Program Gasification is used to convert a solid feedstock, such as coal, petcoke, or biomass, into a gaseous form, referred to as synthesis gas or syngas, which is primarily hydrogen and carbon monoxide. Pollutants can be captured and disposed of or converted to useful products more easily with gasification-based technologies compared to conventional combustion of solid feedstocks. Gasification can generate clean power, and by adding steam to the syngas and performing water-gas-shift to convert the carbon monoxide to carbon dioxide (CO2), additional hydrogen can be produced. The hydrogen and CO2 are separated-the hydrogen is used to make power and the CO2 is sent to storage, converted to useful products or used for enhanced oil recovery (see Gasification Systems Program Research and Development Areas figure). In addition to efficiently producing electric power, a wide range of transportation fuels and chemicals can be produced from the cleaned syngas, thereby providing the flexibility needed to capitalize on the changing economic market. As a result, gasification provides a flexible technology option for using domestically available resources while meeting future environmental emission standards. Furthermore, polygeneration plants that produce multiple products are uniquely possible with gasification technologies.

242

Gasification of Coal and Oil  

Science Journals Connector (OSTI)

... , said the Gas Council is spending £120,000 this year on research into coal gasification, and the National Coal Board and the Central Electricity Generating Board £680,000 and ... coal utilization. The Gas Council is spending about £230,000 on research into the gasification of oil under a programme intended to contribute also to the improvement of the economics ...

1960-02-13T23:59:59.000Z

243

Underground Gasification of Coal Reported  

Science Journals Connector (OSTI)

Underground Gasification of Coal Reported ... RESULTS of a first step taken toward determining the feasibility of the underground gasification of coal were reported recently to the Interstate Oil Compact Commission by Milton H. Fies, manager of coal operations for the Alabama Power Co. ...

1947-05-12T23:59:59.000Z

244

Testing of an advanced thermochemical conversion reactor system  

SciTech Connect

This report presents the results of work conducted by MTCI to verify and confirm experimentally the ability of the MTCI gasification process to effectively generate a high-quality, medium-Btu gas from a wider variety of feedstock and waste than that attainable in air-blown, direct gasification systems. The system's overall simplicity, due to the compact nature of the pulse combustor, and the high heat transfer rates attainable within the pulsating flow resonance tubes, provide a decided and near-term potential economic advantage for the MTCI indirect gasification system. The primary objective of this project was the design, construction, and testing of a Process Design Verification System for an indirectly heated, thermochemical fluid-bed reactor and a pulse combustor an an integrated system that can process alternative renewable sources of energy such as biomass, black liquor, municipal solid waste and waste hydrocarbons, including heavy oils into a useful product gas. The test objectives for the biomass portion of this program were to establish definitive performance data on biomass feedstocks covering a wide range of feedstock qualities and characteristics. The test objectives for the black liquor portion of this program were to verify the operation of the indirect gasifier on commercial black liquor containing 65 percent solids at several temperature levels and to characterize the bed carbon content, bed solids particle size and sulfur distribution as a function of gasification conditions. 6 refs., 59 figs., 29 tabs.

Not Available

1990-01-01T23:59:59.000Z

245

Hot-Gas Filter Testing with a Transport Reactor Gasifier  

SciTech Connect

Today, coal supplies over 55% of the electricity consumed in the United States and will continue to do so well into the next century. One of the technologies being developed for advanced electric power generation is an integrated gasification combined cycle (IGCC) system that converts coal to a combustible gas, cleans the gas of pollutants, and combusts the gas in a gas turbine to generate electricity. The hot exhaust from the gas turbine is used to produce steam to generate more electricity from a steam turbine cycle. The utilization of advanced hot-gas particulate and sulfur control technologies together with the combined power generation cycles make IGCC one of the cleanest and most efficient ways available to generate electric power from coal. One of the strategic objectives for U.S. Department of Energy (DOE) IGCC research and development program is to develop and demonstrate advanced gasifiers and second-generation IGCC systems. Another objective is to develop advanced hot-gas cleanup and trace contaminant control technologies. One of the more recent gasification concepts to be investigated is that of the transport reactor gasifier, which functions as a circulating fluid-bed gasifier while operating in the pneumatic transport regime of solid particle flow. This gasifier concept provides excellent solid-gas contacting of relatively small particles to promote high gasification rates and also provides the highest coal throughput per unit cross-sectional area of any other gasifier, thereby reducing capital cost of the gasification island.

Swanson, M.L.; Hajicek, D.R.

2002-09-18T23:59:59.000Z

246

Gasification Product Improvement Facility (GPIF). Final report  

SciTech Connect

The gasifier selected for development under this contract is an innovative and patented hybrid technology which combines the best features of both fixed-bed and fluidized-bed types. PyGas{trademark}, meaning Pyrolysis Gasification, is well suited for integration into advanced power cycles such as IGCC. It is also well matched to hot gas clean-up technologies currently in development. Unlike other gasification technologies, PyGas can be designed into both large and small scale systems. It is expected that partial repowering with PyGas could be done at a cost of electricity of only 2.78 cents/kWh, more economical than natural gas repowering. It is extremely unfortunate that Government funding for such a noble cause is becoming reduced to the point where current contracts must be canceled. The Gasification Product Improvement Facility (GPIF) project was initiated to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology at a cost approaching $1,000 per kilowatt for electric power generation applications. The project was to include an innovative, advanced, air-blown, pressurized, fixed-bed, dry-bottom gasifier and a follow-on hot metal oxide gas desulfurization sub-system. To help defray the cost of testing materials, the facility was to be located at a nearby utility coal fired generating site. The patented PyGas{trademark} technology was selected via a competitive bidding process as the candidate which best fit overall DOE objectives. The paper describes the accomplishments to date.

NONE

1995-09-01T23:59:59.000Z

247

NETL: Gasification- Water-Gas Shift (WGS) Tests to Reduce Steam Use  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Processing Systems Syngas Processing Systems Water-Gas Shift (WGS) Tests to Reduce Steam Use National Carbon Capture Center at the Power Systems Development Facility Southern Company Services, Inc. Project Number: NT0000749 Project Description The National Carbon Capture Center is testing commercial water-gas shift (WGS) catalysts from multiple vendors in support of developing WGS reactor systems which will reduce the cost of carbon dioxide (CO2) capture from the production of syngas using coal. These tests have revealed that steam-to-carbon monoxide (CO) ratios can be reduced, resulting in a substantial increase in the net power output and significantly reducing the cost of electricity from an integrated gasification combined cycle (IGCC) plant with CO2 capture. Several commercially available WGS catalysts have been tested, and the results are being provided to the manufacturers to aid them in specifying future WGS systems for IGCC plants incorporating CO2 capture.

248

Modelling coal gasification  

Science Journals Connector (OSTI)

Coal gasification processes in a slurry-feed-type entrained-flow gasifier are studied. Novel simulation methods as well as numerical results are presented. We use the vorticity-stream function method to study the characteristics of gas flow and a scalar potential function is introduced to model the mass source terms. The random trajectory model is employed to describe the behaviour of slurry-coal droplets. Very detailed results regarding the impact of the O2/coal ratio on the distribution of velocity, temperature and concentration are obtained. Simulation results show that the methods are feasible and can be used to study a two-phase reacting flow efficiently.

Xiang Jun Liu; Wu Rong Zhang; Tae Jun Park

2001-01-01T23:59:59.000Z

249

PNNL Coal Gasification Research  

SciTech Connect

This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

2010-07-28T23:59:59.000Z

250

Methodology for technology evaluation under uncertainty and its application in advanced coal gasification processes  

E-Print Network (OSTI)

Integrated gasification combined cycle (IGCC) technology has attracted interest as a cleaner alternative to conventional coal-fired power generation processes. While a number of pilot projects have been launched to ...

Gong, Bo, Ph. D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

251

Thermochemical Gasification of Biomass: Fuel Conversion, Hot Gas Cleanup and Gas Turbine Combustion  

Science Journals Connector (OSTI)

Air-blown fluidized bed biomass gasification integrated with a gas- and steam turbine combined cycle (BIGCC) is a potentially attractive way to convert biomass into electricity and heat with a high efficiency.

J. Andries; W. de Jong; P. D. J. Hoppesteyn…

2002-01-01T23:59:59.000Z

252

Biomass waste gasification - Can be the two stage process suitable for tar reduction and power generation?  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Comparison of one stage (co-current) and two stage gasification of wood pellets. Black-Right-Pointing-Pointer Original arrangement with grate-less reactor and upward moving bed of the pellets. Black-Right-Pointing-Pointer Two stage gasification leads to drastic reduction of tar content in gas. Black-Right-Pointing-Pointer One stage gasification produces gas with higher LHV at lower overall ER. Black-Right-Pointing-Pointer Content of ammonia in gas is lower in two stage moving bed gasification. - Abstract: A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter-current downdraft in the second stage was developed and exploited for studying effects of two stage gasification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass particles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW{sub th}. The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950 Degree-Sign C) and for gasification reaction of the fuel gas with char. The second stage used additional combustion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar compound contents confirmed superiority of the two stage gasification system, drastic decrease of aromatic compounds with two and higher number of benzene rings by 1-2 orders. On the other hand the two stage gasification (with overall ER = 0.71) led to substantial reduction of gas heating value (LHV = 3.15 MJ/Nm{sup 3}), elevation of gas volume and increase of nitrogen content in fuel gas. The increased temperature (>950 Degree-Sign C) at the entrance to the char bed caused also substantial decrease of ammonia content in fuel gas. The char with higher content of ash leaving the second stage presented only few mass% of the inlet biomass stream.

Sulc, Jindrich; Stojdl, Jiri; Richter, Miroslav; Popelka, Jan [Faculty of the Environment, Jan Evangelista Purkyne University in Usti nad Labem, Kralova Vysina 7, 400 96 Usti nad Labem (Czech Republic); Svoboda, Karel, E-mail: svoboda@icpf.cas.cz [Faculty of the Environment, Jan Evangelista Purkyne University in Usti nad Labem, Kralova Vysina 7, 400 96 Usti nad Labem (Czech Republic); Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 02 Prague 6 (Czech Republic); Smetana, Jiri; Vacek, Jiri [D.S.K. Ltd., Ujezdecek - Dukla 264, 415 01 Teplice I (Czech Republic); Skoblja, Siarhei; Buryan, Petr [Dept. of Gas, Coke and Air protection, Institute of Chemical Technol., Technicka 5, 166 28 Prague 6 (Czech Republic)

2012-04-15T23:59:59.000Z

253

Chapter 2 - Black Liquor Gasification  

Science Journals Connector (OSTI)

Black liquor gasification (BLG) is being considered primarily as an option for production of biofuels in recent years due to the focus on the transport sector’s high oil dependence and climate impact. BLG may be performed either at low temperatures or at high temperatures, based on whether the process is conducted above or below the melting temperature range of the spent pulping chemicals. The development of various BLG technologies—SCA-Billerud process, the Copeland recovery process, Weyerhaeuser’s process, the St. Regis hydropyrolysis process, the Texaco process, VTT’s circulating fluidized bed BLG process, Babcock and Wilcox’s bubbling fluidized bed gasification process, NSP process (Ny Sodahus Process), DARS (Direct Alkali Recovery System) process, BLG with direct causticization, Manufacturing and Technology Conversion International fluidized bed gasification, Chemrec gasification, catalytic hydrothermal gasification of black liquor—is discussed in this chapter. The two main technologies under development are pressurized gasification and atmospheric gasification, being commercialized by Chemrec AB and ThermoChem Recovery International, respectively.

Pratima Bajpai

2014-01-01T23:59:59.000Z

254

Integrated continuous dissolution, refolding and tag removal of fusion proteins from inclusion bodies in a tubular reactor  

Science Journals Connector (OSTI)

Abstract An integrated continuous tubular reactor system was developed for processing an autoprotease expressed as inclusion bodies. The inclusion bodies were suspended and fed into the tubular reactor system for continuous dissolving, refolding and precipitation. During refolding, the dissolved autoprotease cleaves itself, separating the fusion tag from the target peptide. Subsequently, the cleaved fusion tag and any uncleaved autoprotease were precipitated out in the precipitation step. The processed exiting solution results in the purified soluble target peptide. Refolding and precipitation yields performed in the tubular reactor were similar to batch reactor and process was stable for at least 20 h. The authenticity of purified peptide was also verified by mass spectroscopy. Productivity (in mg/l/h and mg/h) calculated in the tubular process was twice and 1.5 times of the batch process, respectively. Although it is more complex to setup a tubular than a batch reactor, it offers faster mixing, higher productivity and better integration to other bioprocessing steps. With increasing interest of integrated continuous biomanufacturing, the use of tubular reactors in industrial settings offers clear advantages.

Siqi Pan; Monika Zelger; Alois Jungbauer; Rainer Hahn

2014-01-01T23:59:59.000Z

255

Economic Analysis of a 3MW Biomass Gasification Power Plant  

E-Print Network (OSTI)

green waste for use in a biomass gasification process togasification method to process some of the 1.4 million tons of wastegasification / power generation model, accessed April 2008 from http://biomass.ucdavis.edu/calculator.html 10. California Integrated Waste

Cattolica, Robert; Lin, Kathy

2009-01-01T23:59:59.000Z

256

E-Print Network 3.0 - argonaut eindhoven reactor Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Engineering, University of Kentucky Collection: Mathematics 14 PYROLYSIS, THERMAL GASIFICATION, AND LIQUEFACTION OF SOLID WASTES AND RESIDUES Summary: of a number of reactors...

257

Pyrolytic Gasification | Open Energy Information  

Open Energy Info (EERE)

Pyrolytic Gasification Pyrolytic Gasification Jump to: navigation, search Name Pyrolytic Gasification Sector Biomass References Balboa Pacific Corp[1] Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN","zoom":6,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

258

Co-Production of Substitute Natural Gas/Electricity Via Catalytic Coal Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 Co-ProduCtion of SubStitute natural GaS / eleCtriCity via CatalytiC Coal GaSifiCation Description The United States has vast reserves of low-cost coal, estimated to be sufficient for the next 250 years. Gasification-based technology, such as Integrated Gasification Combined Cycle (IGCC), is the only environmentally friendly technology that provides the flexibility to co-produce hydrogen, substitute natural gas (SNG), premium hydrocarbon liquids including transportation fuels, and electric power in desired combinations from coal and other carbonaceous feedstocks. Rising costs and limited domestic supply of crude oil and natural gas provide a strong incentive for the development of coal gasification-based co-production processes. This project addresses the co-production of SNG and electricity from coal via gasification

259

NETL: Gasification Systems Program Contacts  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Systems Program Contacts Gasification Systems Program Contacts Jenny Tennant Gasification Technology Manager U.S. Department of Energy National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 Phone: (304) 285-4830 Email: Jenny.Tennant@netl.doe.gov Pete Rozelle Division of Advanced Energy System - Program Manager, Office of Fossil Energy U.S. Department of Energy FE-221/Germantown Building 1000 Independence Avenue, S.W. Washington, DC 20585-1209 Phone: (301) 903-2338 Email: Peter.Rozelle@hq.doe.gov Heather Quedenfeld Gasification Division Director U.S. Department of Energy National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 Phone: (412) 386-5781 Email: Heather.Quedenfeld@netl.doe.gov Kristin Gerdes Performance Division

260

Catalytic Hydrothermal Gasification of Biomass  

SciTech Connect

A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

Elliott, Douglas C.

2008-05-06T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Gasification Systems 2013 Project Selections  

Energy.gov (U.S. Department of Energy (DOE))

The Department of Energy in 2013 selected ten projects that will focus on reducing the cost of gasification with carbon capture for producing electric power, fuels, and chemicals. The projects will...

262

Coal gasification vessel  

DOE Patents (OSTI)

A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

Loo, Billy W. (Oakland, CA)

1982-01-01T23:59:59.000Z

263

Chemical kinetics parameters of nuclear graphite gasification  

Science Journals Connector (OSTI)

This paper provides chemical kinetics parameters for the gasification of nuclear graphite grades of IG-110, IG-430, NBG-18 and NBG-25 and presents empirical correlations for their surface areas of free active sites as a function of mass. The kinetics parameters for the four elementary chemical reactions of gasification of these grades of nuclear graphite include the values and Gaussian distributions of the specific activation energies and the values of the pre-exponential rate coefficients for the adsorption of oxygen and desorption of CO and CO2 gases. The values of these parameters and the surface area of free active sites for IG-110 and NB-25, with fine and medium petroleum coke filler particles, are nearly the same, but slightly different from those of NBG-18 and IG-430, with medium and fine coal tar pitch coke filler particles. Recommended parameters are applicable to future safety analysis of high and very high temperature gas cooled reactors in the unlikely event of a massive air ingress accident.

Mohamed S. El-Genk; Jean-Michel P. Tournier

2013-01-01T23:59:59.000Z

264

Textile Drying Via Wood Gasification  

E-Print Network (OSTI)

TEXTILE DRYING VIA WOOD GASIFICATION Thomas F. ;McGowan, Anthony D. Jape Georgia Institute of Technology Atlanta, Georgia ABSTRACT This project was carried out to investigate the possibility of using wood gas as a direct replacement... for dryers. In addition to the experimental program described above, the DOE grant covered two other major areas. A survey of the textile industry was made to assess the market for gasification equip ment. The major findings were that a large amount...

McGowan, T. F.; Jape, A. D.

1983-01-01T23:59:59.000Z

265

Materials of Gasification  

SciTech Connect

The objective of this project was to accumulate and establish a database of construction materials, coatings, refractory liners, and transitional materials that are appropriate for the hardware and scale-up facilities for atmospheric biomass and coal gasification processes. Cost, fabricability, survivability, contamination, modes of corrosion, failure modes, operational temperatures, strength, and compatibility are all areas of materials science for which relevant data would be appropriate. The goal will be an established expertise of materials for the fossil energy area within WRI. This would be an effort to narrow down the overwhelming array of materials information sources to the relevant set which provides current and accurate data for materials selection for fossil fuels processing plant. A significant amount of reference material on materials has been located, examined and compiled. The report that describes these resources is well under way. The reference material is in many forms including texts, periodicals, websites, software and expert systems. The most important part of the labor is to refine the vast array of available resources to information appropriate in content, size and reliability for the tasks conducted by WRI and its clients within the energy field. A significant has been made to collate and capture the best and most up to date references. The resources of the University of Wyoming have been used extensively as a local and assessable location of information. As such, the distribution of materials within the UW library has been added as a portion of the growing document. Literature from recent journals has been combed for all pertinent references to high temperature energy based applications. Several software packages have been examined for relevance and usefulness towards applications in coal gasification and coal fired plant. Collation of the many located resources has been ongoing. Some web-based resources have been examined.

None

2005-09-15T23:59:59.000Z

266

Proliferation resistance of the fuel cycle for the Integral Fast Reactor  

SciTech Connect

Argonne National Laboratory has developed an electrorefining pyrochemical process for recovery and recycle of metal fuel discharged from the Integral Fast Reactor (FR). This inherently low decontamination process has an overall decontamination factor of only about 100 for the plutonium metal product. As a result, all of the fuel cycle operations must be conducted in heavily shielded cells containing a high-purity argon atmosphere. The FR fuel cycle possesses high resistance to clandestine diversion or overt, state- supported removal of plutonium for nuclear weapons production because of two main factors: the highly radioactive product, which is also contaminated with heat- and neutron-producing isotopes of plutonium and other actinide elements, and the difficulty of removing material from the FR facility through the limited number of cell transfer locks without detection.

Burris, L.

1993-09-01T23:59:59.000Z

267

Fuel cycle facility control system for the Integral Fast Reactor Program  

SciTech Connect

As part of the Integral Fast Reactor (IFR) Fuel Demonstration, a new distributed control system designed, implemented and installed. The Fuel processes are a combination of chemical and machining processes operated remotely. To meet this special requirement, the new control system provides complete sequential logic control motion and positioning control and continuous PID loop control. Also, a centralized computer system provides near-real time nuclear material tracking, product quality control data archiving and a centralized reporting function. The control system was configured to use programmable logic controllers, small logic controllers, personal computers with touch screens, engineering work stations and interconnecting networks. By following a structured software development method the operator interface was standardized. The system has been installed and is presently being tested for operations.

Benedict, R.W.; Tate, D.A.

1993-09-01T23:59:59.000Z

268

NETL: Gasifipedia - What is Gasification?  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Background Gasification Background Drivers for Gasification Technology The need for low-cost power produced in an environmentally sound way is certain, even if the future of regulations limiting the emission and/or encouraging the capture of CO2, and the price and availability of natural gas and oil are not. Gasification is not only capable of efficiently producing electric power, but a wide range of liquids and/or high-value chemicals (including diesel and gasoline for transportation) can be produced from cleaned syngas, providing the flexibility to capitalize on a range of dynamic changes to either domestic energy markets or global economic conditions. Polygeneration-plants that produce multiple products-is uniquely possible with gasification technologies. Continued advances in gasification-based technology will enable the conversion of our nation's abundant coal reserves into energy resources (power and liquid fuels), chemicals, and fertilizers needed to displace the use of imported oil and, thereby, help mitigate its high price and security supply concerns and to support U.S. economic competitiveness with unprecedented environmental performance.

269

Status of health and environmental research relative to coal gasification 1976 to the present  

SciTech Connect

Health and environmental research relative to coal gasification conducted by Argonne National Laboratory, the Inhalation Toxicology Research Institute, and Oak Ridge National Laboratory under DOE sponsorship is summarized. The studies have focused on the chemical and toxicological characterization of materials from a range of process streams in five bench-scale, pilot-plant and industrial gasifiers. They also address ecological effects, industrial hygiene, environmental control technology performance, and risk assessment. Following an overview of coal gasification technology and related environmental concerns, integrated summaries of the studies and results in each area are presented and conclusions are drawn. Needed health and environmental research relative to coal gasification is identified.

Wilzbach, K.E.; Reilly, C.A. Jr. (comps.)

1982-10-01T23:59:59.000Z

270

Hybrid Combustion-Gasification Chemical Looping  

SciTech Connect

For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2} separation, and also syngas production from coal with the calcium sulfide (CaS)/calcium sulfate (CaSO{sub 4}) loop utilizing the PDU facility. The results of Phase I were reported in Reference 1, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase I Report' The objective for Phase II was to develop the carbonate loop--lime (CaO)/calcium carbonate (CaCO{sub 3}) loop, integrate it with the gasification loop from Phase I, and ultimately demonstrate the feasibility of hydrogen production from the combined loops. The results of this program were reported in Reference 3, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase II Report'. The objective of Phase III is to operate the pilot plant to obtain enough engineering information to design a prototype of the commercial Chemical Looping concept. The activities include modifications to the Phase II Chemical Looping PDU, solids transportation studies, control and instrumentation studies and additional cold flow modeling. The deliverable is a report making recommendations for preliminary design guidelines for the prototype plant, results from the pilot plant testing and an update of the commercial plant economic estimates.

Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

2009-01-07T23:59:59.000Z

271

Hydrogen Production Cost Estimate Using Biomass Gasification  

E-Print Network (OSTI)

Hydrogen Production Cost Estimate Using Biomass Gasification National Renewable Energy Laboratory% postconsumer waste #12;i Independent Review Panel Summary Report September 28, 2011 From: Independent Review Panel, Hydrogen Production Cost Estimate Using Biomass Gasification To: Mr. Mark Ruth, NREL, DOE

272

Underground Coal Gasification in the USSR  

Science Journals Connector (OSTI)

By accomplishing in a single operation the extraction of coal and its conversion into a gaseous fuel, underground gasification makes it possible to avoid the heavy capital investments required for coal gasification

1983-01-01T23:59:59.000Z

273

June 2007 gasification technologies workshop papers  

SciTech Connect

Topics covered in this workshop are fundamentals of gasification, carbon capture and sequestration, reviews of financial and regulatory incentives, co-production, and focus on gasification in the Western US.

NONE

2007-06-15T23:59:59.000Z

274

Transport and Other Effects in Coal Gasification  

Science Journals Connector (OSTI)

The paper summarizes the kinetics of coal char gasification excepted surface reactions (mechanisms). The following subjects controlling coal char gasification are treated: Coal as the raw material ... of particle...

K. J. Hüttinger

1988-01-01T23:59:59.000Z

275

Behavior of chars from Bursa Mustafa Kemal Pasa Alpagut and Balkesir Dursunbey Cakiirca Lignite (Turkey) during non-catalytic and catalytic gasification  

SciTech Connect

The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures of the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.

Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.; Tekes, A.T.; Canel, M. [Ankara University, Ankara (Turkey). Dept. of Chemistry

2008-07-01T23:59:59.000Z

276

Beluga Coal Gasification - ISER  

SciTech Connect

ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

Steve Colt

2008-12-31T23:59:59.000Z

277

Biothermal gasification of biomass  

SciTech Connect

The BIOTHERMGAS Process is described for conversion of biomass, organic residues, and peat to substitute natural gas (SNG). This new process, under development at IGT, combines biological and thermal processes for total conversion of a broad variety of organic feeds (regardless of water or nutrient content). The process employs thermal gasification for conversion of refractory digester residues. Ammonia and other inorganic nutrients are recycled from the thermal process effluent to the bioconversion unit. Biomethanation and catalytic methanation are presented as alternative processes for methanation of thermal conversion product gases. Waste heat from the thermal component is used to supply the digester heat requirements of the bioconversion component. The results of a preliminary systems analysis of three possible applications of this process are presented: (1) 10,000 ton/day Bermuda grass plant with catalytic methanation; (2) 10,000 ton/day Bermuda grass plant with biomethanation; and (3) 1000 ton/day municipal solid waste (MSW) sewage sludge plant with biomethanation. The results indicate that for these examples, performance is superior to that expected for biological or thermal processes used separately. The results of laboratory studies presented suggest that effective conversion of thermal product gases can be accomplished by biomethanation.

Chynoweth, D.P.; Srivastava, V.J.; Henry, M.P.; Tarman, P.B.

1980-01-01T23:59:59.000Z

278

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

SciTech Connect

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-06-01T23:59:59.000Z

279

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

SciTech Connect

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-01-01T23:59:59.000Z

280

Kinetic study of steam gasification of two mineralogically different lignite chars: An active site/intermediate model  

Science Journals Connector (OSTI)

Abstract A new active site/intermediate model (ASIM) is formulated in terms of a simplified calcium-catalyzed mechanism of char gasification to characterize a conversion-dependent maximum in reaction rate. In a limited case, the model is retrogressed to a common volumetric model (VM). Two sets of kinetic data were experimentally gathered by steam gasification of two lignite chars in a fixed bed reactor with negligible mass diffusion limitation. The gasification behaviors of two chars were, respectively, representative of catalyzed and uncatalyzed gasification as a result of the influences of different mineral components in them. It was found that ASIM intimately fit the kinetic profiles over the entire range of conversion for both catalyzed and uncatalyzed char gasification, demonstrating the good adaptability to varying chars. The model could determine the activation energies for the formation of the total carbon-containing gases and of two individual gases (CO and CO2) from the oxygenated intermediate. Moreover, for the case of catalyzed gasification, ASIM reasonably predicted the formation, growth and decline of the intermediate with carbon conversion as well as the change in the intermediate concentration with gasification temperature. For the case of uncatalyzed gasification, the model portrayed essentially a linear decline in the intermediate concentration with increasing carbon conversion, similar to VM.

Jia Tang; Xuantao Wu; Jie Wang

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Development of High-Pressure Dry Feed Pump for Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Pressure Dry Feed Pressure Dry Feed Pump for Gasification Systems Background Even though coal-based power generation via Integrated Gasification Combined Cycle (IGCC) is more efficient, cleaner, and uses less water than conventional pulverized coal burning systems, widespread IGCC deployment has not occurred because of its relatively high cost. The Pratt & Whitney Rocketdyne (PWR) high-pressure dry feed pump addresses IGCC cost disparity by enabling lower cost and more reliable coal feed

282

Characterization of Filter Elements for Service in a Coal Gasification Environment  

SciTech Connect

The Power Systems Development Facility (PSDF) is a joint Department of Energy/Industry sponsored engineering-scale facility for testing advanced coal-based power generation technologies. High temperature, high pressure gas cleaning is critical to many of these advanced technologies. Barrier filter elements that can operate continuously for nearly 9000 hours are required for a successful gas cleaning system for use in commercial power generation. Since late 1999, the Kellogg Brown & Root Transport reactor at the PSDF has been operated in gasification mode. This paper describes the test results for filter elements operating in the Siemens-Westinghouse particle collection device (PCD) with the Transport reactor in gasification mode. Operating conditions in the PCD have varied during gasification operation as described elsewhere in these proceedings (Martin et al, 2002).

Spain, J.D.

2002-09-19T23:59:59.000Z

283

Fixed bed gasification studies on coal-feedlot biomass and coal-chicken litter biomass under batch mode operation  

E-Print Network (OSTI)

of the processes for energy conversion of biomass fuels is thermochemical gasification. For the current study, a laboratory scale, 10 kW[th], fixed-bed gasifier (reactor internal diameter 0.15 m, reactor height 0.30 m) facility was built at the Texas A...

Priyadarsan, Soyuz

2012-06-07T23:59:59.000Z

284

Dual-Bed Gasification of Petcoke: Model Development and Validation  

Science Journals Connector (OSTI)

Dual-Bed Gasification of Petcoke: Model Development and Validation ... A series of sensitivity analyses is performed with regard to a conventional gasifier fed by petcoke, and the effects of residence time and oxygen/carbon mass ratio in the feed are investigated over three process variables: char conversion at the gasifier exit, temperature at the gasifier exit, and amount of useful syngas (H2 and CO) produced, in terms of N?m3 per ton of petcoke. ... Different from most literature publications, such as refs 5 and 6, where coal and/or petcoke gasification models are checked against available data, with respect to the syngas composition obtained, and to the process cold gas efficiency, one of the purposes of our paper is to correlate experimental data to a parameter that is important both for simulation and for reactor design: the value of the residence time of the gasifier. ...

Maria Sudiro; Carlos Zanella; Alberto Bertucco; Luigi Bressan; Marco Fontana

2010-01-15T23:59:59.000Z

285

Pilot-Plant Gasification of Olive Stone: a Technical Assessment  

Science Journals Connector (OSTI)

This paper presents the results of pilot-plant gasification tests carried out at atmospheric pressure and temperatures within the range of 700?820 °C in order to assess the technical viability of gasifying untreated olive stone, also called “orujillo”, a byproduct of the olive oil industry that comprises both olive stone and pulp. ... Atmospheric air gasification of biomass/waste in a bubbling-fluidized-bed (BFB) reactor is an attractive simple process to convert a solid material to a gaseous fuel. ... Their different characteristics (mainly volatile and ash content) affect the plant operation because of the energy content and the ash fusibility, but both types were gasified efficiently and the problems found were similar. ...

A. Gómez-Barea; R. Arjona; P. Ollero

2004-12-31T23:59:59.000Z

286

NETL: Gasification Systems - Gas Separation  

NLE Websites -- All DOE Office Websites (Extended Search)

Separation Separation Ion-Transport Membrane Oxygen Separation Modules Ion-Transport Membrane Oxygen Separation Modules Gas separation unit operations represent major cost elements in gasification plants. The gas separation technology being supported in the DOE program promises significant reduction in cost of electricity, improved thermal efficiency, and superior environmental performance. Gasification-based energy conversion systems rely on two gas separation processes: (1) separation of oxygen from air for feed to oxygen-blown gasifiers; and (2) post-gasification separation of hydrogen from carbon dioxide following (or along with) the shifting of gas composition when carbon dioxide capture is required or hydrogen is the desired product. Research efforts include development of advanced gas separation

287

Impact of radiation embrittlement on integrity of pressure vessel supports for two PWR (pressurized-water-reactor) plants  

SciTech Connect

Recent pressure-vessel surveillance data from the High Flux Isotope Reactor (HFIR) indicate an embrittlement fluence-rate effect that is applicable to the evaluation of the integrity of light-water reactor (LWR) pressure vessel supports. A preliminary evaluation using the HFIR data indicated increases in the nil ductility transition temperature at 32 effective full-power years (EFPY) of 100 to 130/degree/C for pressurized-water-reactor (PWR) vessel supports located in the cavity at midheight of the core. This result indicated a potential problem with regard to life expectancy. However, an accurate assessment required a detailed, specific-plant, fracture-mechanics analysis. After a survey and cursory evaluation of all LWR plants, two PWR plants that appeared to have a potential problem were selected. Results of the analyses indicate minimum critical flaw sizes small enough to be of concern before 32 EFPY. 24 refs., 16 figs., 7 tabs.

Cheverton, R.D.; Pennell, W.E.; Robinson, G.C.; Nanstad, R.K.

1988-01-01T23:59:59.000Z

288

The Mass Tracking System for the Integral Fast Reactor fuel cycle  

SciTech Connect

As part of the Fuel Cycle Facility (FCF) of Argonne National Laboratory`s Integral Fast Reactor (IFR) demonstration, a computer-based Mass-Tracking (MTG) System has been developed. The MTG System collects, stores, retrieves and processes data on all operations which directly affect the flow of process material through FCF and supports such activities as process modeling, compliance with operating limits (e.g., criticality safety), material control and accountability and operational information services. Its architecture is client/server, with input and output connections to operator`s equipment-control stations on the floor of FCF as well as to terminal sessions. Its heterogeneous database includes a relational-database manager as well as both binary and ASCII data files. The design of the database, and the software that supports it, is based on a model of discrete accountable items distributed in space and time and constitutes a complete historical record of the material processed in FCF. Although still under development, much of the MTG System has been qualified and is in production use.

Adams, C.H.; Beitel, J.C.; Birgersson, G.; Bucher, R.G.; Carrico, C.B.; Daly, T.A. [Argonne National Lab., IL (United States); Keyes, R.W. [Argonne National Lab., Idaho Falls, ID (United States)

1994-07-01T23:59:59.000Z

289

Recovery of carbon fibres by the thermolysis and gasification of waste prepreg  

Science Journals Connector (OSTI)

Abstract This paper examines the recovery of carbon fibres from a composite used in the aeronautical industry, via a combined process of thermolysis and gasification in an air atmosphere. The waste was thermolysed at 500 °C, 600 °C or 700 °C in a pilot plant to determine the optimum thermolysis temperature. The solid residues produced – char covered carbon fibres – were characterized by SEM and XPS. The optimum time for the gasification of the char covering the fibres was determined in a combined thermolysis/gasification assay. After thermolysis at the optimum temperature (500 °C), 12 l/h of pure air were injected into the reactor and char gasification performed at 500 °C for 30–180 min. The optimum gasification time was 30 min. Longer gasification times led to the production of fibres of smaller diameter with oxidized surfaces and reduced tensile strength. The optimally recovered fibres showed about 70% of the tensile strength of virgin fibres and some 90–96% of their elasticity.

Félix A. López; Olga Rodríguez; Francisco José Alguacil; Irene García-Díaz; Teresa A. Centeno; José Luis García-Fierro; Carlos González

2013-01-01T23:59:59.000Z

290

Using Ilmenite To Reduce the Tar Yield in a Dual Fluidized Bed Gasification System  

Science Journals Connector (OSTI)

In this work, ilmenite was used as the catalytic material in the Chalmers 2–4 MWth dual fluidized bed gasifier to decrease the yield of tar. ... Indirect gasification, using the Dual Fluidized Bed (DFB) concept, has been identified as being suitable for medium- to large-scale production units. ... catalytic reactors, the implementation of specific reaction media such as supercrit. ...

Anton Larsson; Mikael Israelsson; Fredrik Lind; Martin Seemann; Henrik Thunman

2014-03-10T23:59:59.000Z

291

Current Gasification Research | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification » Current Gasification » Current Gasification Research Current Gasification Research Sponsored by the U.S. Department of Energy, the National Carbon Capture Center provides first-class facilities to test carbon capture technologies. Sponsored by the U.S. Department of Energy, the National Carbon Capture Center provides first-class facilities to test carbon capture technologies. With coal gasification now in modern commercial-scale applications, the U.S. Department of Energy's (DOE) Office of Fossil Energy has turned its attention to future gasification concepts that offer significant improvements in efficiency, fuel flexibility, economics and environmental sustainability. Fuel flexibility is especially important. Tomorrow's gasification plants conceivably could process a wide variety of low-cost feedstocks, handling

292

Coal gasification 2006: roadmap to commercialization  

SciTech Connect

Surging oil and gas prices, combined with supply security and environmental concerns, are prompting power generators and industrial firms to further develop coal gasification technologies. Coal gasification, the process of breaking down coal into its constituent chemical components prior to combustion, will permit the US to more effectively utilize its enormous, low cost coal reserves. The process facilitates lower environmental impact power generation and is becoming an increasingly attractive alternative to traditional generation techniques. The study is designed to inform the reader as to this rapidly evolving technology, its market penetration prospects and likely development. Contents include: Clear explanations of different coal gasification technologies; Emissions and efficiency comparisons with other fuels and technologies; Examples of US and global gasification projects - successes and failures; Commercial development and forecast data; Gasification projects by syngas output; Recommendations for greater market penetration and commercialization; Current and projected gasification technology market shares; and Recent developments including proposals for underground gasification process. 1 app.

NONE

2006-05-15T23:59:59.000Z

293

Hydrogen production by high-temperature steam gasification of biomass and coal  

SciTech Connect

High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

2009-04-15T23:59:59.000Z

294

Gasdynamic lasers utilizing carbon gasification  

Science Journals Connector (OSTI)

A theoretical investigation was made of the influence of the processes of carbon gasification by combustion products and oxidants on the chemical composition of the active medium and the energy characteristics of a gasdynamic CO2 laser. Conditions were found under which the stored energy of the active medium was greater than 100 J/g.

A S Biryukov; V M Marchenko; A M Prokhorov

1985-01-01T23:59:59.000Z

295

Clean Fuels from Coal Gasification  

Science Journals Connector (OSTI)

...been operated as a "pure" gasifier but to supply power gas for...was the air-blown Winkler gasifier pro-ducing power gas at Leuna...fines, additional gasification medium (air or oxygen-steam) is...partial pressure of steam in a gasifier blown with oxygen and steam...

Arthur M. Squires

1974-04-19T23:59:59.000Z

296

Clean Fuels from Coal Gasification  

Science Journals Connector (OSTI)

...appreciably larger sizes than coal to other...they grew to a size to fall upon an...air-blown Winkler gasifier pro-ducing power...additional gasification medium (air or oxygen-steam...provide "pure" gasifier Test revamp Develop larger sizes Develop pressure...

Arthur M. Squires

1974-04-19T23:59:59.000Z

297

Influences of Additives on Steam Gasification of Biomass. 1. Pyrolysis Procedure  

Science Journals Connector (OSTI)

To remove tar and upgrade the quality of gaseous product, researchers have extensively studied the influences of various additives(2-6) and diverse reactors(7-9) on biomass gasification. ... For the pyrolysis procedure, there are two effectual methods, improving operating conditions and adding additives into reactors, to control the formations of tar and CnHm. ... The chemical components of additives added in the related pyrolysis procedure are shown in Table 2. ...

Yu R. Xie; Lai H. Shen; Jun Xiao; Da X. Xie; Jing Zhu

2009-09-23T23:59:59.000Z

298

Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1  

SciTech Connect

Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. (Institute of Gas Technology, Chicago, IL (United States)); Duthie, R.G. (Bechtel Group, Inc., San Francisco, CA (United States)); Wootten, J.M. (Peabody Holding Co., Inc., St. Louis, MO (United States))

1991-09-01T23:59:59.000Z

299

Catalytic gasification of automotive shredder residues with hydrogen generation  

Science Journals Connector (OSTI)

Hydrogen is a clean and new energy carrier to generate power through the Proton exchange membrane fuel cell (PEMFC) system. Hydrogen can be effectively turned out through the catalytic gasification of organic material such as automotive shredder residues (ASR). The main objective of this manuscript is to present an analysis of the catalytic gasification of ASR for the generation of high-purity hydrogen in a lab-scale fixed-bed downdraft gasifier using 15 wt.% NiO/Al2O3 catalysts at 760–900 K. In the catalytic gasification process, reduction of Ni(II) catalyst into Ni(0) has been confirmed through XANES spectra and consequently EXAFS data shows that the central Ni atoms have Ni–O and Ni–Ni bonds with bond distances of 2.03 ± 0.05 and 2.46 ± 0.05 Å, respectively. ASR is partially oxidized and ultimately converts into hydrogen rich syngas (CO and H2) and increases of the reaction temperature are favored the generation of hydrogen with decomposition of the CO. As well, approximately 220 kg h?1 of ASR would be catalytically gasified at 760–900 K and 46.2 atm with the reactor volume 0.27 m3 to obtain approximately 3.42 × 105 kcal h?1 of thermal energy during over 87% syngas generation with the generation of 100 kW electric powers.

Kuen-Song Lin; Sujan Chowdhury; Ze-Ping Wang

2010-01-01T23:59:59.000Z

300

Economic Analysis of a 3MW Biomass Gasification Power Plant  

E-Print Network (OSTI)

Collaborative, Biomass gasification / power generationANALYSIS OF A 3MW BIOMASS GASIFICATION POWER PLANT R obert Cas a feedstock for gasification for a 3 MW power plant was

Cattolica, Robert; Lin, Kathy

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

October 2005 Gasification-Based Fuels and Electricity Production from  

E-Print Network (OSTI)

October 2005 Gasification-Based Fuels and Electricity Production from Biomass, without......................................................................... 9 3.1.1 Biomass Gasification, and production cost estimates for gasification-based thermochemical conversion of switchgrass into Fischer

302

Exergy analysis of biomass-to-synthetic natural gas (SNG) process via indirect gasification of various biomass feedstock  

Science Journals Connector (OSTI)

This paper presents an exergy analysis of SNG production via indirect gasification of various biomass feedstock, including virgin (woody) biomass as well as waste biomass (municipal solid waste and sludge). In indirect gasification heat needed for endothermic gasification reactions is produced by burning char in a separate combustion section of the gasifier and subsequently the heat is transferred to the gasification section. The advantages of indirect gasification are no syngas dilution with nitrogen and no external heat source required. The production process involves several process units, including biomass gasification, syngas cooler, cleaning and compression, methanation reactors and SNG conditioning. The process is simulated with a computer model using the flow-sheeting program Aspen Plus. The exergy analysis is performed for various operating conditions such as gasifier pressure, methanation pressure and temperature. The largest internal exergy losses occur in the gasifier followed by methanation and SNG conditioning. It is shown that exergetic efficiency of biomass-to-SNG process for woody biomass is higher than that for waste biomass. The exergetic efficiency for all biomass feedstock increases with gasification pressure, whereas the effects of methanation pressure and temperature are opposite for treated wood and waste biomass.

Caecilia R. Vitasari; Martin Jurascik; Krzysztof J. Ptasinski

2011-01-01T23:59:59.000Z

303

Integrated coal cleaning, liquefaction, and gasification process  

DOE Patents (OSTI)

Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

Chervenak, Michael C. (Pennington, NJ)

1980-01-01T23:59:59.000Z

304

Pioneering Gasification Plants | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification » Pioneering Gasification » Pioneering Gasification Plants Pioneering Gasification Plants In the 1800s, lamplighters made their rounds in the streets of many of America's largest cities lighting street lights fueled by "town gas," frequently the product of early forms of coal gasification. Gasification of fuel also provided fuel for steel mills, and toward the end of the 19th Century, electric power. These early gasifiers were called "gas producers," and the gas that they generated was called "producer gas." During the early 20th Century, improvements in the availability of petroleum and natural gas products, along with the extension of the infrastructure associated with these products, led to their widespread use, which replaced coal-based producer gas in the energy market.

305

INTEGRAL BENCHMARKS AVAILABLE THROUGH THE INTERNATIONAL REACTOR PHYSICS EXPERIMENT EVALUATION PROJECT AND THE INTERNATIONAL CRITICALITY SAFETY BENCHMARK EVALUATION PROJECT  

SciTech Connect

Interest in high-quality integral benchmark data is increasing as efforts to quantify and reduce calculational uncertainties accelerate to meet the demands of next generation reactor and advanced fuel cycle concepts. The International Reactor Physics Experiment Evaluation Project (IRPhEP) and the International Criticality Safety Benchmark Evaluation Project (ICSBEP) continue to expand their efforts and broaden their scope to identify, evaluate, and provide integral benchmark data for method and data validation. Benchmark model specifications provided by these two projects are used heavily by the international reactor physics, nuclear data, and criticality safety communities. Thus far, 14 countries have contributed to the IRPhEP, and 20 have contributed to the ICSBEP. The status of the IRPhEP and ICSBEP is discussed in this paper, and the future of the two projects is outlined and discussed. Selected benchmarks that have been added to the IRPhEP and ICSBEP handbooks since PHYSOR’06 are highlighted, and the future of the two projects is discussed.

J. Blair Briggs; Lori Scott; Enrico Sartori; Yolanda Rugama

2008-09-01T23:59:59.000Z

306

Simulation of Syngas Production from Municipal Solid Waste Gasification in a Bubbling Fluidized Bed Using Aspen Plus  

Science Journals Connector (OSTI)

Simulation of Syngas Production from Municipal Solid Waste Gasification in a Bubbling Fluidized Bed Using Aspen Plus ... When the reaction kinetics is not known, a rigorous reactor and multiphase equilibrium based on the minimization of the total Gibbs free energy of the product mixture (an RGibbs block) is preferred to predict the equilibrium composition of the produced syngas. ... Catalytic steam gasification of municipal solid waste (MSW) to produce hydrogen-rich gas or syngas (H2 + CO) with calcined dolomite as a catalyst in a bench-scale downstream fixed bed reactor was investigated. ...

Miaomiao Niu; Yaji Huang; Baosheng Jin; Xinye Wang

2013-09-06T23:59:59.000Z

307

Gasification world database 2007. Current industry status  

SciTech Connect

Information on trends and drivers affecting the growth of the gasification industry is provided based on information in the USDOE NETL world gasification database (available on the www.netl.doe.gov website). Sectors cover syngas production in 2007, growth planned through 2010, recent industry changes, and beyond 2010 - strong growth anticipated in the United States. A list of gasification-based power plant projects, coal-to-liquid projects and coal-to-SNG projects under consideration in the USA is given.

NONE

2007-10-15T23:59:59.000Z

308

An integrated performance model for high temperature gas cooled reactor coated particle fuel  

E-Print Network (OSTI)

The performance of coated fuel particles is essential for the development and deployment of High Temperature Gas Reactor (HTGR) systems for future power generation. Fuel performance modeling is indispensable for understanding ...

Wang, Jing, 1976-

2004-01-01T23:59:59.000Z

309

Thermal hydraulic performance analysis of a small integral pressurized water reactor core  

E-Print Network (OSTI)

A thermal hydraulic analysis of the International Reactor Innovative and Secure (IRIS) core has been performed. Thermal margins for steady state and a selection of Loss Of Flow Accidents have been assessed using three ...

Blair, Stuart R. (Stuart Ryan), 1972-

2003-01-01T23:59:59.000Z

310

EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX February 18, 2009 EIS-0412:...

311

Enabling Small-Scale Biomass Gasification for Liquid Fuel Production...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Breakout Session 2A-Conversion...

312

Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...  

Energy Savers (EERE)

Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of...

313

NETL: Gasification Systems - Gas Cleaning  

NLE Websites -- All DOE Office Websites (Extended Search)

Cleaning Cleaning Chemicals from Coal Complex Chemicals from Coal Complex (Eastman Company) Novel gas cleaning and conditioning are crucial technologies for achieving near-zero emissions, while meeting gasification system performance and cost targets. DOE's Gasification Systems program supports technology development in the area of gas cleaning and conditioning, including advanced sorbents and solvents, particulate filters, and other novel gas-cleaning approaches that remove and convert gas contaminants into benign and marketable by-products. To avoid the cost and efficiency penalties associated with cooling the gas stream to temperatures at which conventional gas clean-up systems operate, novel processes are being developed that operate at mild to high temperatures and incorporate multi-contaminant control to

314

Underground coal gasification using oxygen and steam  

SciTech Connect

In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

2009-07-01T23:59:59.000Z

315

NETL: Gasification Systems - Mitigation of Syngas Cooler Plugging and  

NLE Websites -- All DOE Office Websites (Extended Search)

Mitigation of Syngas Cooler Plugging and Fouling Mitigation of Syngas Cooler Plugging and Fouling Project No.: DE-FE0007952 Reaction Engineering International (REI) is working to develop practical solutions to mitigate the plugging and fouling of syngas coolers (SC) - fire tube heat exchangers located between the coal gasifier and the combustion turbine. Syngas coolers used in Integrated Gasification Combined Cycle (IGCC) plants offer high efficiency, but their reliability is generally lower than other process equipment in the gasification island. The principle downtime events associated with syngas coolers are typically a result of ash deposits that: form on (wall) surfaces upstream of the syngas cooler, break loose, and then lodge in the tubes; or form on the fireside surface of the syngas cooler tubes that lead to fouling and reduced heat transfer. Both ash deposit mechanisms result in reduced equipment life and increased maintenance costs.

316

Environmental Enterprise: Carbon Sequestration using Texaco Power Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Sequestration using Texaco Gasification Process Jeff Seabright Arthur Lee Richard Weissman, PhD. Texaco Inc. White Plains, New York Presented at: First National Conference on Carbon Sequestration May 14-17, 2001 Washington D.C. ABSTRACT Coal Integrated Gasification Combined Cycle (IGCC) is a commercially proven clean coal technology that offers significant environmental and economic benefits today, including decreased air and solids emissions. It also offers the potential to capture and sequester carbon dioxide. Coal IGCC provides electric utilities strategic options in meeting today's growing demand for energy products (electricity, fuel, chemicals) while protecting public health and the environment and providing a pathway to zero emissions coal-based power generation.

317

3 - Preparation of feedstocks for gasification for synthetic liquid fuel production  

Science Journals Connector (OSTI)

Abstract Gasification has been considered as a potential thermo-chemical method of conversion to effectively utilize the carbon (organic content) present in the feedstock. Preparation and handling methods of some of the potential feedstocks (i.e., coal, petroleum residue, biomass, and municipal solid waste (MSW) to produce the synthetic gas) for various applications are discussed. The pre-treatment process for feedstock constitutes the steps that must be imposed on the raw material in preparation for use in a gasification reactor. The properties of fuel that influence the gasification are energy content, moisture content, particle size and distribution, form of the fuel, bulk density of the fuel, volatile matter content, ash content, and composition and reactivity of the fuel.

B. Bhavya; R. Singh; T. Bhaskar

2015-01-01T23:59:59.000Z

318

Investigation of gasification chemical looping combustion combined cycle performance  

SciTech Connect

A novel combined cycle based on coal gasification and chemical looping combustion (CLC) offers a possibility of both high net power efficiency and separation of the greenhouse gas CO{sub 2}. The technique involves the use of a metal oxide as an oxygen carrier, which transfers oxygen from the combustion air to the fuel, and the avoidance of direct contact between fuel and combustion air. The fuel gas is oxidized by an oxygen carrier, an oxygen-containing compound, in the fuel reactor. The oxygen carrier in this study is NiO. The reduced oxygen carrier, Ni, in the fuel reactor is regenerated by the air in the air reactor. In this way, fuel and air are never mixed, and the fuel oxidation products CO{sub 2} and water vapor leave the system undiluted by air. All that is needed to get an almost pure CO{sub 2} product is to condense the water vapor and to remove the liquid water. When the technique is combined with gas turbine and heat recovery steam generation technology, a new type of combined cycle is formed which gives a possibility of obtaining high net power efficiency and CO{sub 2} separation. The performance of the combined cycle is simulated using the ASPEN software tool in this paper. The influence of the water/coal ratio on the gasification and the influence of the CLC process parameters such as the air reactor temperature, the turbine inlet supplementary firing, and the pressure ratio of the compressor on the system performance are discussed. Results show that, assuming an air reactor temperature of 1200{sup o}C, a gasification temperature of 1100 {sup o}C, and a turbine inlet temperature after supplementary firing of 1350{sup o}C, the system has the potential to achieve a thermal efficiency of 44.4% (low heating value), and the CO{sub 2} emission is 70.1 g/(kW h), 90.1% of the CO{sub 2} captured. 22 refs., 7 figs., 6 tabs.

Wenguo Xiang; Sha Wang; Tengteng Di [Southeast University, Nanjing (China). Key Laboratory of Clean Coal Power Generation and Combustion Technology of the Ministry of Education

2008-03-15T23:59:59.000Z

319

Changes in char structure during the gasification of a Victorian brown coal in steam and oxygen at 800{degree}C  

SciTech Connect

Char structure is an important factor influencing its reactivity during gasification. This study aims to investigate the changes in char structure during the gasification of brown coal. A Victorian brown coal was gasified in a fluidized-bed/fixed-bed reactor at 800{degree}C in atmospheres containing 15% H{sub 2}O, 2000 ppm O{sub 2}, or 15% H{sub 2}O and 2000 ppm O{sub 2}, respectively. Although the char gasification in 2000 ppm O{sub 2} was mainly rate-limited by the external diffusion of O{sub 2}, the char-H{sub 2}O reaction was mainly rate-limited by the chemical reactions. The structural features of char at different levels of char gasification conversion were examined with FT-Raman spectroscopy. Our results show that the chars from the gasification in the mixture of 2000 ppm O{sub 2} and 15% H{sub 2}O had almost the same features as the chars from the gasification in 15% H{sub 2}O alone when the same levels of char conversion were achieved. Both the thermal decomposition of char and the char gasification reactions could result in changes in char structure during gasification. 29 refs., 5 figs., 1 tab.

Xin Guo; Hui Ling Tay; Shu Zhang; Chun-Zhu Li [Monash University, Vic. (Australia). Department of Chemical Engineering

2008-11-15T23:59:59.000Z

320

Improved catalysts for carbon and coal gasification  

DOE Patents (OSTI)

This invention relates to improved catalysts for carbon and coal gasification and improved processes for catalytic coal gasification for the production of methane. The catalyst is composed of at least two alkali metal salts and a particulate carbonaceous substrate or carrier is used. 10 figures, 2 tables.

McKee, D.W.; Spiro, C.L.; Kosky, P.G.

1984-05-25T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Process and technological aspects of municipal solid waste gasification. A review  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Critical assessment of the main commercially available MSW gasifiers. Black-Right-Pointing-Pointer Detailed discussion of the basic features of gasification process. Black-Right-Pointing-Pointer Description of configurations of gasification-based waste-to-energy units. Black-Right-Pointing-Pointer Environmental performance analysis, on the basis of independent sources data. - Abstract: The paper proposes a critical assessment of municipal solid waste gasification today, starting from basic aspects of the process (process types and steps, operating and performance parameters) and arriving to a comparative analysis of the reactors (fixed bed, fluidized bed, entrained bed, vertical shaft, moving grate furnace, rotary kiln, plasma reactor) as well as of the possible plant configurations (heat gasifier and power gasifier) and the environmental performances of the main commercially available gasifiers for municipal solid wastes. The analysis indicates that gasification is a technically viable option for the solid waste conversion, including residual waste from separate collection of municipal solid waste. It is able to meet existing emission limits and can have a remarkable effect on reduction of landfill disposal option.

Arena, Umberto, E-mail: umberto.arena@unina2.it [Department of Environmental Sciences, Second University of Naples, Via A. Vivaldi, 43, 81100 Caserta (Italy)

2012-04-15T23:59:59.000Z

322

Environmental impact and techno-economic analysis of the coal gasification process with/without CO2 capture  

Science Journals Connector (OSTI)

Abstract Coal gasification, the technology for high-efficient utilization of coal, has been widely used in China. However, it suffers from high CO2 emissions problem due to the carbon-rich character of coal. To reduce CO2 emissions, different CO2 capture technologies are developed and integrated into the coal gasification based processes. However, involving CO2 capture would result in energetic and economic penalty. This paper analyses three cases of coal gasification processes from environmental, technical, and economical points of view. These processes are (1) a conventional coal gasification process; (2) a coal gasification process with CO2 capture and sequestration, in which CO2 is stored by mineral sequestration; (3) a coal gasification process with CO2 capture and utilization, in which CO2 is reused to produce syngas. The results show that the coal gasification process with CO2 capture and sequestration has advantage only in environmental aspect compared to the conventional process. The process with CO2 capture and utilization has advantages in both technical and environmental aspects while disadvantage in economic aspect. However, if the carbon tax higher than 15 USD/t CO2 is introduced, this disadvantage will be negligible.

Yi Man; Siyu Yang; Dong Xiang; Xiuxi Li; Yu Qian

2014-01-01T23:59:59.000Z

323

A study on ultra heavy oil gasification technology  

SciTech Connect

Raising the thermal efficiency of a thermal power plant is an important issue from viewpoints of effective energy utilization and environmental protection. In view of raising the thermal efficiency, a gas turbine combined cycle power generation is considered to be very effective. The thermal efficiency of the latest LNG combined cycle power plant has been raised by more than 50%. On the other hand, the diversification of fuels to ensure supply stability is also an important issue, particularly in Japan where natural resources are scarce. Because of excellent handling characteristics petroleum and LNG which produces clean combustion are used in many sectors, and so the demand for such fuels is expected to grow. However, the availability of such fuels is limited, and supplies will be exhausted in the near future. The development of a highly efficient and environment-friendly gas turbine combined cycle using ultra heavy oil such as Orimulsion{trademark} (trademark of BITOR) is thus a significant step towards resolving these two issues. Chubu Electric Power Co, Inc., the Central Research Institute of Electric Power Industry (CRIEPI), and Mitsubishi Heavy Industries, Ltd. (MHI) conducted a collaboration from 1994 to 1998 with the objective of developing an ultra heavy oil integrated gasification combined cycle (IGCC). Construction of the ultra heavy oil gasification testing facility (fuel capacity:2.4t/d) was completed in 1995, and Orimulsion{trademark} gasification tests were carried out in 1995 and 1996. In 1997, the hot dedusting facility with ceramic filter and the water scrubber used as a preprocessor of a wet desulfurization process were installed. Gasification and clean up the syngs tests were carried out on Orimulsion{trademark}, Asmulsion{trademark} (trademark of Nisseki Mitsubishi K.K.), and residue oil in 1997 and 1998. The results of the collaboration effort are described below.

Kidoguchi, Kazuhiro; Ashizawa, Masami; Taki, Masato; Ishimura, Masato; Takeno, Keiji

2000-07-01T23:59:59.000Z

324

Gasification of New Zealand coals: a comparative simulation study  

SciTech Connect

The aim of this study was to conduct a preliminary feasibility assessment of gasification of New Zealand (NZ) lignite and sub-bituminous coals, using a commercial simulation tool. Gasification of these coals was simulated in an integrated gasification combined cycle (IGCC) application and associated preliminary economics compared. A simple method of coal characterization was developed for simulation purposes. The carbon, hydrogen, and oxygen content of the coal was represented by a three component vapor solid system of carbon, methane, and water, the composition of which was derived from proximate analysis data on fixed carbon and volatile matter, and the gross calorific value, both on a dry, ash free basis. The gasification process was modeled using Gibb's free energy minimization. Data from the U.S. Department of Energy's Shell Gasifier base cases using Illinios No. 6 coal was used to verify both the gasifier and the IGCC flowsheet models. The H:C and O:C ratios of the NZ coals were adjusted until the simulated gasifier output composition and temperature matched the values with the base case. The IGCC power output and other key operating variables such as gas turbine inlet and exhaust temperatures were kept constant for study of comparative economics. The results indicated that 16% more lignite than sub-bituminous coal was required. This translated into the requirement of a larger gasifier and air separation unit, but smaller gas and steam turbines were required. The gasifier was the largest sole contributor (30%) to the estimated capital cost of the IGCC plant. The overall cost differential associated with the processing of lignite versus processing sub-bituminous coal was estimated to be of the order of NZ $0.8/tonne. 13 refs., 9 tabs.

Smitha V. Nathen; Robert D. Kirkpatrick; Brent R. Young [University of Auckland, Auckland (New Zealand). Department of Chemical and Materials Engineering

2008-07-15T23:59:59.000Z

325

Integrated production of fuel gas and oxygenated organic compounds from synthesis gas  

DOE Patents (OSTI)

An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

Moore, Robert B. (Allentown, PA); Hegarty, William P. (State College, PA); Studer, David W. (Wescosville, PA); Tirados, Edward J. (Easton, PA)

1995-01-01T23:59:59.000Z

326

A Generalized Pyrolysis Model for Simulating Charring, Intumescent, Smoldering, and Noncharring Gasification  

E-Print Network (OSTI)

on Nonflaming Transient Gasification of PMMA and PE duringT. , & Werner, K. , “Wood Gasification at Fire Level HeatConcentration on Nonflaming Gasification Rates and Evolved

Lautenberger, Chris; Fernandez-Pello, Carlos

2006-01-01T23:59:59.000Z

327

The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology  

E-Print Network (OSTI)

Higman, C. and M. Burgt, Gasification . 2003: Elsevier/Gulfand N.P. Cheremisinoff, Gasification technologies: a primerbiomass (part 3): gasification technologies. Bioresource

He, Wei

2011-01-01T23:59:59.000Z

328

E-Print Network 3.0 - advanced coal-gasification technical Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification to Produce SNG (Beulah, North Dakota, USA) (Source:DakotaGasification Petcoke... Source: NETL, 2009 12;12 Dakota Coal Gasification ... Source: Center for...

329

Mississippi Ethanol Gasification Project, Final Scientific / Technical Report  

SciTech Connect

The Mississippi Ethanol (ME) Project is a comprehensive effort to develop the conversion of biomass to ethanol utilizing a proprietary gasification reactor technology developed by Mississippi Ethanol, LLC. Tasks were split between operation of a 1/10 scale unit at the Diagnostic Instrumentation and Analysis Laboratory (DIAL) of Mississippi State University (MSU) and the construction, development, and operation of a full scale pilot unit located at the ME facility in Winona, Mississippi. In addition to characterization of the ME reactor gasification system, other areas considered critical to the operational and economic viability of the overall ME concept were evaluated. These areas include syngas cleanup, biological conversion of syngas to alcohol, and effects of gasification scale factors. Characterization of run data from the Pre-Pilot and Pilot Units has allowed development of the factors necessary for scale-up from the small unit to the larger unit. This scale range is approximately a factor of 10. Particulate and tar sampling gave order of magnitude values for preliminary design calculations. In addition, sampling values collected downstream of the ash removal system show significant reductions in observed loadings. These loading values indicate that acceptable particulate and tar loading rates could be attained with standard equipment additions to the existing configurations. Overall operation both the Pre-Pilot and Pilot Units proceeded very well. The Pilot Unit was operated as a system, from wood receiving to gas flaring, several times and these runs were used to address possible production-scale concerns. Among these, a pressure feed system was developed to allow feed of material against gasifier system pressure with little or no purge requirements. Similarly, a water wash system, with continuous ash collection, was developed, installed, and tested. Development of a biological system for alcohol production was conducted at Mississippi State University with much progress. However, the current state of biological technology is not deemed to be ready commercially. A preliminary estimate of capital and operating costs of a 12000 gallon per day gasification/biological facility was developed for comparison purposes. In addition, during the biological organism screening and testing, some possible alternative products were identified. One such possibility is the biological production of bio-diesel. Additional research is necessary for further evaluation of all of the biological concepts.

Pearson, Larry, E.

2007-04-30T23:59:59.000Z

330

The direct observation of alkali vapor species in biomass combustion and gasification  

SciTech Connect

This report summarizes new data from screening various feedstocks for alkali vapor release under combustion conditions. The successful development of a laboratory flow reactor and molecular beam, mass spectrometer interface is detailed. Its application to several herbaceous and woody feedstocks, as well as a fast-pyrolysis oil, under 800 and 1,100{degrees}C batch combustion, is documented. Chlorine seems to play a large role in the facile mobilization of potassium. Included in the report is a discussion of relevant literature on the alkali problem in combustors and turbines. Highlighted are the phenomena identified in studies on coal and methods that have been applied to alkali speciation. The nature of binding of alkali in coal versus biomass is discussed, together with the implications for the ease of release. Herbaceous species and many agricultural residues appear to pose significant problems in release of alkali species to the vapor at typical combustor temperatures. These problems could be especially acute in direct combustion fired turbines, but may be ameliorated in integrated gasification combined cycles.

French, R.J.; Dayton, D.C.; Milne, T.A.

1994-01-01T23:59:59.000Z

331

Fluidized bed catalytic coal gasification process  

DOE Patents (OSTI)

Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

Euker, Jr., Charles A. (15163 Dianna La., Houston, TX 77062); Wesselhoft, Robert D. (120 Caldwell, Baytown, TX 77520); Dunkleman, John J. (3704 Autumn La., Baytown, TX 77520); Aquino, Dolores C. (15142 McConn, Webster, TX 77598); Gouker, Toby R. (5413 Rocksprings Dr., LaPorte, TX 77571)

1984-01-01T23:59:59.000Z

332

Kinetic models for uncatalyzed and potassium-catalyzed gasification of char by carbon dioxide  

SciTech Connect

A differential packed-bed reactor has been employed to study the gasification of uncatalyzed and 7.5 wt% K/sub 2/CO/sub 3/-catalyzed Saran char in carbon dioxide/carbon monoxide mixtures at a total pressure near 1 atm (101.3 kPa). The gasification temperature was varied between 1131 and 1229 K for the uncatalyzed case, and between 922 and 1046 K for the catalyzed case. Gasification rate data were tested with a model which involves two-site adsorption and subsequent dissociation of CO/sub 2/ on the char surface. The results indicate that this model adequately explains both the uncatalyzed and catalyzed gasification data. However, higher concentrations of carbon-oxygen complex, (C(O)), exist on the surface during catalyzed gasification. The increase in (C(O)) weakens carbon-carbon bonds and thus lowers the activation energy for desorption of the C(O) complex. Adsorption of CO and CO/sub 2/ on both catalyzed and uncatalyzed chars was also followed with a volumetric adsorption apparatus at pressures between 1 and 100 kPa and temperatures from 273 to 725 K. The catalyzed char adsorbed an order of magnitude more CO/sub 2/ at 559 K than the uncatalyzed char. Subsequent dissociation of CO/sub 2/ on the carbon surface does not appear to be catalyzed by potassium. Thus, the catalysts' role is to augment the efficiency and/or number of sites for CO/sub 2/ adsorption, thereby creating more oxygen on the surface. The higher rate during catalyzed gasification can be attributed to a combination of increased (C(O)) and a smaller activation energy for desorption of C(O).

Koenig, P.C.

1985-01-01T23:59:59.000Z

333

Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1. Final report  

SciTech Connect

Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. [Institute of Gas Technology, Chicago, IL (United States); Duthie, R.G. [Bechtel Group, Inc., San Francisco, CA (United States); Wootten, J.M. [Peabody Holding Co., Inc., St. Louis, MO (United States)

1991-09-01T23:59:59.000Z

334

Fluidized bed steam reactor including two horizontal cyclone separators and an integral recycle heat exchanger  

SciTech Connect

A reactor is described comprising: a vessel; a first furnace section disposed in said vessel; a second furnace section disposed in said vessel; means in each of said furnace sections for receiving a combustible fuel for generating heat and combustion gases; a first heat recovery area located adjacent said furnace sections; a second heat recovery area located adjacent said furnace sections; means for passing said combustion gases from said first furnace section to said first heat recovery area; and means for passing said combustion gases from said second furnace section to said second heat recovery area.

Gorzegno, W.P.

1993-06-15T23:59:59.000Z

335

NETL: News Release - Coal Gasification Plant Returns $79 Million to DOE in  

NLE Websites -- All DOE Office Websites (Extended Search)

2, 2006 2, 2006 Coal Gasification Plant Returns $79 Million to DOE in Revenue-Sharing Gas Sales Plant Currently Supplies Carbon Dioxide for DOE Sequestration Project Washington, DC -A coal gasification plant purchased from the U.S. Department of Energy (DOE) in 1988 recently paid millions of dollars to DOE as part of a revenue sharing agreement and continues to be an integral part of a Department project to sequester millions of tons of carbon dioxide while doubling an oil field's recovery rate. MORE INFO Learn more about the Great Plains Synfuels Plant The Dakota Gasification Company (DGC), which purchased the Great Plains Synfuels Plant near Beulah, N.D., recently announced the payment of more than $79 million to DOE as part of a revenue-sharing agreement signed in

336

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

SciTech Connect

High purity hydrogen is commercially produced from syngas by the Water Gas Shift Reaction (WGSR) in high and low temperature shift reactors using iron oxide and copper catalysts respectively. However, the WGSR is thermodynamically limited at high temperatures towards hydrogen production necessitating excess steam addition and catalytic operation. In the calcium looping process, the equilibrium limited WGSR is driven forward by the incessant removal of CO{sub 2} by-product through the carbonation of calcium oxide. At high pressures, this process obviates the need for a catalyst and excess steam requirement, thereby removing the costs related to the procurement and deactivation of the catalyst and steam generation. Thermodynamic analysis for the combined WGS and carbonation reaction was conducted. The combined WGS and carbonation reaction was investigated at varying pressures, temperatures and S/C ratios using a bench scale reactor system. It was found that the purity of hydrogen increases with the increase in pressure and at a pressure of 300 psig, almost 100% hydrogen is produced. It was also found that at high pressures, high purity hydrogen can be produced using stoichiometric quantities of steam. On comparing the catalytic and non catalytic modes of operation in the presence of calcium oxide, it was found that there was no difference in the purity of hydrogen produced at elevated pressures. Multicyclic reaction and regeneration experiments were also conducted and it was found that the purity of hydrogen remains almost constant after a few cycles.

Shwetha Ramkumar; Mahesh Iyer; Danny Wong; Himanshu Gupta; Bartev Sakadjian; Liang-Lhih Fan

2008-09-30T23:59:59.000Z

337

Mass transfer effects in a gasification riser  

SciTech Connect

In the development of multiphase reacting computational fluid dynamics (CFD) codes, a number of simplifications were incorporated into the codes and models. One of these simplifications was the use of a simplistic mass transfer correlation for the faster reactions and omission of mass transfer effects completely on the moderate speed and slow speed reactions such as those in a fluidized bed gasifier. Another problem that has propagated is that the mass transfer correlation used in the codes is not universal and is being used far from its developed bubbling fluidized bed regime when applied to circulating fluidized bed (CFB) riser reactors. These problems are true for the major CFD codes. To alleviate this problem, a mechanistic based mass transfer coefficient algorithm has been developed based upon an earlier work by Breault et al. This fundamental approach uses the local hydrodynamics to predict a local, time varying mass transfer coefficient. The predicted mass transfer coefficients and the corresponding Sherwood numbers agree well with literature data and are typically about an order of magnitude lower than the correlation noted above. The incorporation of the new mass transfer model gives the expected behavior for all the gasification reactions evaluated in the paper. At the expected and typical design values for the solid flow rate in a CFB riser gasifier an ANOVA analysis has shown the predictions from the new code to be significantly different from the original code predictions. The new algorithm should be used such that the conversions are not over predicted. Additionally, its behaviors with changes in solid flow rate are consistent with the changes in the hydrodynamics.

Breault, Ronald W [U.S. DOE; Li, Tingwen [URS; Nicoletti, Phillip [URS

2013-01-01T23:59:59.000Z

338

The Gasification of Ponderosa Pine Charcoal  

Science Journals Connector (OSTI)

The gasification of wood chars with CO2 and steam is an important process step in the conversion of biomass to fuel and synthesis gases. Wood fuels can be gasified in a wide variety of sizes, shapes and densities...

Richard Edrich; Timothy Bradley…

1985-01-01T23:59:59.000Z

339

Catalysts for carbon and coal gasification  

DOE Patents (OSTI)

Catalyst for the production of methane from carbon and/or coal by means of catalytic gasification. The catalyst compostion containing at least two alkali metal salts. A particulate carbonaceous substrate or carrier is used.

McKee, Douglas W. (Burnt Hills, NY); Spiro, Clifford L. (Scotia, NY); Kosky, Philip G. (Schenectady, NY)

1985-01-01T23:59:59.000Z

340

A New Approach to Carbon Gasification  

Science Journals Connector (OSTI)

... carbon monoxide plus hydrogen respectively, under the usual conditions of temperature and pressure applying in gasification practice, the rates of reaction measured by the number of gm. moles of product ...

J. D. BLACKWOOD; F. K. McTAGGART

1959-08-08T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Biomass Gasification in Dual Fluidized Bed Gasifier  

Science Journals Connector (OSTI)

The dual fluidized bed gasification technology is prospective because it produces high...2...dilution even when air is used to generate the required endothermic heat via in situ combustion. This study is devoted ...

Toshiyuki Suda; Takahiro Murakami…

2007-01-01T23:59:59.000Z

342

Underground Coal Gasification at Tennessee Colony  

E-Print Network (OSTI)

The Tennessee Colony In Situ Coal Gasification Project conducted by Basic Resources Inc. is the most recent step in Texas Utilities Company's ongoing research into the utilization of Texas lignite. The project, an application of the Soviet...

Garrard, C. W.

1979-01-01T23:59:59.000Z

343

The Role of Oxygen in Coal Gasification  

E-Print Network (OSTI)

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

344

Partial Gasification for CO2Emissions Reduction  

Science Journals Connector (OSTI)

The chemical reaction during partial gasification of coal follows the form (Nag and Raha, 1994) which is based on the Amagat model for ideal gas mixtures: (9.1) ...

Nirmal V. Gnanapragasam; Bale V. Reddy; Marc A. Rosen

2010-01-01T23:59:59.000Z

345

Slagging Behavior of Straw and Corn Stover and the Fate of Potassium under Entrained-Flow Gasification Conditions  

Science Journals Connector (OSTI)

It was observed that, although the major part of the primarily siliceous native ash promptly forms a molten slag, much of the alkalis are evaporated into the syngas. ... Experiments were performed in an electrically heated atmospheric EF reactor [lab-scale combustion and gasification simulator (LCS)] equipped with a multi-stage gas burner that has been applied extensively in previous studies of PF combustion and gasification. ... However, deposition problems could arise when burning other coals, particularly coals with a high S or alkali metal content or a low content of ash. ...

Simon Leiser; Mariusz K. Cieplik; Ruben Smit

2012-12-20T23:59:59.000Z

346

Effect of potassium carbonate on char gasification by carbon dioxide  

SciTech Connect

A differential packed-bed reactor has been employed to study the gasification of 7.5 wt% K/sub 2/CO/sub 3/-catalyzed Saran char in carbon dioxide/carbon monoxide mixtures at a total pressure near 1 atm (101.3 kPa) and temperatures between 922 and 1046 K. The rate data were tested with a model which involves two-site adsorption and subsequent dissociation of CO/sub 2/ on the char surface. The results indicate that this model adequately explains the catalyzed gasification data. Moreover, the activation energy for desorption of carbon-oxygen complex is lower for the catalyzed case than for the uncatalyzed case. Adsorption of CO and CO/sub 2/ on both catalyzed and uncatalyzed chars was also followed with a volumetric adsorption apparatus at pressures between 1 and 100 kPa and temperatures from 273 to 725 K. The catalyzed char adsorbed an order of magnitude more CO/sub 2/ at 560 K than the uncatalyzed char. Subsequent dissociation of CO/sub 2/ on the carbon surface does not appear to be catalyzed by potassium. Thus, the catalyst's role is to enhance CO/sub 2/ adsorption, thereby creating more oxygen on the surface, and lowering the activation energy for desorption of the resultant carbon-oxygen species.

Koenig, P.C.; Squires, R.G.; Laurendeau, N.M.

1986-07-01T23:59:59.000Z

347

Potassium Retention in Updraft Gasification of Wood  

Science Journals Connector (OSTI)

Wood gasifiers are equipment used for a controlled combustion of wood in limited supply of air as the oxidizing medium to generate a combustible product gas. ... Other oxidizing media, such as oxygen and steam, or a combination of any two media can be used in the gasification process. ... The zone where high rates of char combustion and gasification occur is about 15 mm wide above the grate, as determined in a similar-sized gasifier by Di Blasi. ...

Joseph Olwa; Marcus Öhman; Pettersson Esbjörn; Dan Boström; Mackay Okure; Björn Kjellström

2013-10-14T23:59:59.000Z

348

The integral fast reactor and its role in a new generation of nuclear power plants, Tokai, Japan, November 19-21, 1986  

SciTech Connect

This report presents information on the Integral Fast Reactor and its role in the future. Information is presented in the areas of: inherent safety; other virtues of sodium-cooled breeder; and solving LWR fuel cycle problems with IFR technologies. (JDB)

Smith, R.R.

1986-01-01T23:59:59.000Z

349

Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications  

SciTech Connect

This report is a preliminary comparison of conventional and potential HTGR-integrated processesa in several common industrial areas: ? Producing electricity via a traditional power cycle ? Producing hydrogen ? Producing ammonia and ammonia-derived products, such as fertilizer ? Producing gasoline and diesel from natural gas or coal ? Producing substitute natural gas from coal, and ? Steam-assisted gravity drainage (extracting oil from tar sands).

Lee Nelson

2009-10-01T23:59:59.000Z

350

Environmental Enterprise: Carbon Sequestration using Texaco Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Environmental Enterprise: Carbon Sequestration using Texaco Carbon Sequestration using Texaco Gasification Process Gasification Process First National Conference on Carbon Sequestration First National Conference on Carbon Sequestration May 16, 2001 May 16, 2001 Jeff Seabright Jeff Seabright Texaco Inc. Texaco Inc. Presentation Highlights Presentation Highlights * * Texaco and climate change Texaco and climate change * * Introduction to gasification Introduction to gasification * * Environmental benefits of gasification Environmental benefits of gasification * * CO CO 2 2 capture & sequestration capture & sequestration * * Challenges going forward Challenges going forward Texaco's Climate Change Policy Texaco's Climate Change Policy * * Know enough to take action now Know enough to take action now

351

Plasmatron gasification of biomass lignocellulosic waste materials derived from municipal solid waste  

Science Journals Connector (OSTI)

Abstract The aim of this work is to study the feasibility and operational performance of plasmatron (plasma torch) gasification of municipal solid waste mixed with raw wood (MSW/RW) derived from the pretreatment of Steam Mechanical Heat Treatment (SMHT), as the target material (MRM). A 10 kW plasmatron reactor is used for gasification of the MRM. The production of syngas (CO and H2) is the major component, and almost 90% of the gaseous products appear in 2 min of reaction time, with relatively high reaction rates. The syngas yield is between 88.59 and 91.84 vol%, and the recovery mass ratio of syngas from MRM is 45.19 down to 27.18 wt% with and without steam with the energy yields of 59.07–111.89%. The concentrations of gaseous products from the continuous feeding of 200 g/h are stable and higher than the average concentrations of the batch feeding of 10 g. The residue from the plasmatron gasification with steam is between 0 and 4.52 wt%, with the inorganic components converted into non-leachable vitrified lava, which is non-hazardous. The steam methane reforming reaction, hydrogasification reaction and Boudouard reaction all contribute to the increase in the syngas yield. It is proved that MSW can be completely converted into bioenergy using SMHT, followed by plasmatron gasification.

Je-Lueng Shie; Li-Xun Chen; Kae-Long Lin; Ching-Yuan Chang

2014-01-01T23:59:59.000Z

352

GASIFICATION TEST RUN TC06  

SciTech Connect

This report discusses test campaign TC06 of the Kellogg Brown & Root, Inc. (KBR) Transport Reactor train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Reactor is an advanced circulating fluidized-bed reactor designed to operate as either a combustor or a gasifier using a particulate control device (PCD). The Transport Reactor was operated as a pressurized gasifier during TC06. Test run TC06 was started on July 4, 2001, and completed on September 24, 2001, with an interruption in service between July 25, 2001, and August 19, 2001, due to a filter element failure in the PCD caused by abnormal operating conditions while tuning the main air compressor. The reactor temperature was varied between 1,725 and 1,825 F at pressures from 190 to 230 psig. In TC06, 1,214 hours of solid circulation and 1,025 hours of coal feed were attained with 797 hours of coal feed after the filter element failure. Both reactor and PCD operations were stable during the test run with a stable baseline pressure drop. Due to its length and stability, the TC06 test run provided valuable data necessary to analyze long-term reactor operations and to identify necessary modifications to improve equipment and process performance as well as progressing the goal of many thousands of hours of filter element exposure.

Southern Company Services, Inc.

2003-08-01T23:59:59.000Z

353

Effect of Microstructural Changes on Gasification Reactivity of Coal Chars during Low Temperature Gasification  

Science Journals Connector (OSTI)

Effect of Microstructural Changes on Gasification Reactivity of Coal Chars during Low Temperature Gasification ... Pocahontas No. 3, Illinois No. 6, and Beulah-Zap coal char samples were gasified in 1% O2 at 500 °C or 600 °C up to 90% (daf) conversion, and their structure were observed under a high-resolution transmission electron microscope (HRTEM). ...

Atul Sharma; Hayato Kadooka; Takashi Kyotani; Akira Tomita

2001-11-28T23:59:59.000Z

354

DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)  

SciTech Connect

Foster Wheeler Development Corporation is working under DOE contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% while producing near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The unique aspect of the process is that it utilizes a pressurized circulating fluidized bed partial gasifier and does not attempt to consume the coal in a single step. To convert all the coal to syngas in a single step requires extremely high temperatures ({approx}2500 to 2800F) that melt and vaporize the coal and essentially drive all coal ash contaminants into the syngas. Since these contaminants can be corrosive to power generating equipment, the syngas must be cooled to near room temperature to enable a series of chemical processes to clean the syngas. Foster Wheeler's process operates at much lower temperatures that control/minimize the release of contaminants; this eliminates/minimizes the need for the expensive, complicated syngas heat exchangers and chemical cleanup systems typical of high temperature gasification. By performing the gasification in a circulating bed, a significant amount of syngas can still be produced despite the reduced temperature and the circulating bed allows easy scale up to large size plants. Rather than air, it can also operate with oxygen to facilitate sequestration of stack gas carbon dioxide gases for a 100% reduction in greenhouse gas emissions. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building block that offers all the advantages of coal gasification but in a more user friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. The PGM consists of a pressurized circulating fluidized bed (PCFB) reactor together with a recycle cyclone and a particulate removing barrier filter. Coal, air, steam, and possibly sand are fed to the bottom of the PCFB reactor and establish a relatively dense bed of coal/char in the bottom section. As these constituents react, a hot syngas is produced which conveys the solids residue vertically up through the reactor and into the recycle cyclone. Solids elutriated from the dense bed and contained in the syngas are collected in the cyclone and drain via a dipleg back to the dense bed at the bottom of the PCFB reactor. This recycle loop of hot solids acts as a thermal flywheel and promotes efficient solid-gas chemical reaction.

Unknown

2001-07-10T23:59:59.000Z

355

Kinetics of steam gasification of bituminous coals in terms of their use for underground coal gasification  

Science Journals Connector (OSTI)

Abstract The kinetics of steam gasification was examined for bituminous coals of a low coal rank. The examined coals can be the raw material for underground coal gasification. Measurements were carried out under isothermal conditions at a high pressure of 4 MPa and temperatures of 800, 900, 950, and 1000 °C. Yields of gasification products such as carbon monoxide and carbon dioxide, hydrogen and methane were calculated based on the kinetic curves of formation reactions of these products. Also carbon conversion degrees are presented. Moreover, calculations were made of the kinetic parameters of carbon monoxide and hydrogen formation reaction in the coal gasification process. The parameters obtained during the examinations enable a preliminary assessment of coal for the process of underground coal gasification.

Stanis?aw Porada; Grzegorz Czerski; Tadeusz Dziok; Przemys?aw Grzywacz; Dorota Makowska

2015-01-01T23:59:59.000Z

356

Light Water Reactors Technology Development - Nuclear Reactors  

NLE Websites -- All DOE Office Websites (Extended Search)

Light Water Reactors Light Water Reactors About Director's Welcome Organization Achievements Highlights Fact Sheets, Brochures & Other Documents Multimedia Library Visit Argonne Work with Argonne Contact us Nuclear Energy Why Nuclear Energy? Why are some people afraid of Nuclear Energy? How do nuclear reactors work? Cheaper & Safer Nuclear Energy Helping to Solve the Nuclear Waste Problem Nuclear Reactors Nuclear Reactors Early Exploration Training Reactors Basic and Applied Science Research LWR Technology Development BORAX-III lighting Arco, Idaho (Press Release) Heavy Water and Graphite Reactors Fast Reactor Technology Integral Fast Reactor Argonne Reactor Tree CP-1 70th Anniversary CP-1 70th Anniversary Argonne's Nuclear Science and Technology Legacy Argonne's Nuclear Science and Technology Legacy

357

World Gasification Database Now Available from DOE | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

World Gasification Database Now Available from DOE World Gasification Database Now Available from DOE World Gasification Database Now Available from DOE November 9, 2010 - 12:00pm Addthis Washington, DC - A database just released by the U.S. Department of Energy (DOE) documents the worldwide growth of gasification, the expected technology of choice for future coal-based plants that produce power, fuels, and/or chemicals with near-zero emissions. The 2010 Worldwide Gasification Database, a comprehensive collection of gasification plant data, describes the current world gasification industry and identifies near-term planned capacity additions. The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas

358

Utilization of char from biomass gasification in catalytic applications  

E-Print Network (OSTI)

Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Submitted Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Utilization takes place during catalytic decomposition. This thesis focuses on the utilization of char as a catalyst

359

Clean coal technology using process integration : a focus on the IGCC.  

E-Print Network (OSTI)

?? The integrated gasification combined cycle (IGCC) is the most environmentally friendly coal-fired power generation technology that offers near zero green house gas emissions. This… (more)

Madzivhandila, Vhutshilo

2011-01-01T23:59:59.000Z

360

Imperium/Lanzatech Syngas Fermentation Project - Biomass Gasification and Syngas Conditioning for Fermentation Evaluation: Cooperative Research and Development Final Report, CRADA Number CRD-12-474  

SciTech Connect

LanzaTech and NREL will investigate the integration between biomass gasification and LanzaTech's proprietary gas fermentation process to produce ethanol and 2,3-butanediol. Using three feed materials (woody biomass, agricultural residue and herbaceous grass) NREL will produce syngas via steam indirect gasification and syngas conditioning over a range of process relevant operating conditions. The gasification temperature, steam-to-biomass ratio of the biomass feed into the gasifier, and several levels of syngas conditioning (based on temperature) will be varied to produce multiple syngas streams that will be fed directly to 10 liter seed fermenters operating with the Lanzatech organism. The NREL gasification system will then be integrated with LanzaTech's laboratory pilot unit to produce large-scale samples of ethanol and 2,3-butanediol for conversion to fuels and chemicals.

Wilcox, E.

2014-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Thermochemical Conversion Research and Development: Gasification and Pyrolysis (Fact Sheet)  

SciTech Connect

Biomass gasification and pyrolysis research and development activities at the National Renewable Energy Laboratory and Pacific Northwest National Laboratory.

Not Available

2009-09-01T23:59:59.000Z

362

Biomass Anaerobic Digestion Facilities and Biomass Gasification Facilities (Indiana)  

Energy.gov (U.S. Department of Energy (DOE))

The Indiana Department of Environmental Management requires permits before the construction or expansion of biomass anaerobic digestion or gasification facilities.

363

Use of manganese ore in chemical-looping combustion (CLC)—Effect on steam gasification  

Science Journals Connector (OSTI)

The chemical-looping combustion (CLC) process is a novel solution for efficient combustion with direct separation of carbon dioxide. The process uses a metal oxide as an oxygen carrier to transfer oxygen from an air to a fuel reactor, where the fuel reacts with the solid oxygen carrier. When solid fuel is used in CLC, the char needs to be gasified by e.g. steam to form H2 and CO that can be subsequently oxidized to H2O and CO2 by the oxygen carrier. In this work, the influence of the oxygen carrier on the rate of steam gasification is studied, by comparing the conversion of petcoke in the presence of manganese ore to that of ilmenite. The experiments were carried out in a fluidized-bed reactor at 970 °C using a fluidization gas of 50% steam in nitrogen. The manganese ore shows an increase by a factor five in the rate of steam gasification of char as compared to ilmenite. The dramatic increase in rate of steam gasification, in combination with potentially low costs of this material suggests that manganese ore could be an interesting material for CLC with solid fuels.

Mehdi Arjmand; Henrik Leion; Anders Lyngfelt; Tobias Mattisson

2012-01-01T23:59:59.000Z

364

The Argonaut Reactor - Reactors designed/built by Argonne National  

NLE Websites -- All DOE Office Websites (Extended Search)

Achievements > Achievements > Argonne Reactors > Training Reactors About Director's Welcome Organization Achievements Highlights Fact Sheets, Brochures & Other Documents Multimedia Library Visit Argonne Work with Argonne Contact us Nuclear Energy Why Nuclear Energy? Why are some people afraid of Nuclear Energy? How do nuclear reactors work? Cheaper & Safer Nuclear Energy Helping to Solve the Nuclear Waste Problem Nuclear Reactors Nuclear Reactors Early Exploration Training Reactors Basic and Applied Science Research LWR Technology Development BORAX-III lighting Arco, Idaho (Press Release) Heavy Water and Graphite Reactors Fast Reactor Technology Integral Fast Reactor Argonne Reactor Tree CP-1 70th Anniversary CP-1 70th Anniversary Argonne's Nuclear Science and Technology Legacy

365

NETL: Gasification - Recovery Act: High Temperature Syngas Cleanup  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Processing Systems Syngas Processing Systems Recovery Act: High Temperature Syngas Cleanup Technology Scale-Up and Demonstration Project Research Triangle Institute Project Number: FE0000489 Project Description Research Triangle Institute (RTI) is designing, building, and testing the Warm Temperature Desulfurization Process (WDP) at pre-commercial scale (50 megawatt electric equivalent [MWe]) to remove more than 99.9 percent of the sulfur from coal-derived synthesis gas (syngas). RTI is integrating this WDP technology with an activated methyl diethanolamine (aMDEA) solvent technology to separate 90% of the carbon dioxide (CO2) from shifted syngas. The Polk Power Station, an integrated gasification combined cycle (IGCC) power plant, will supply approximately 20% of its coal-derived syngas as a slipstream to feed into the pre-commercial scale technologies being scaled-up.

366

Apparatus for fixed bed coal gasification  

DOE Patents (OSTI)

An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

Sadowski, Richard S. (Greenville, SC)

1992-01-01T23:59:59.000Z

367

5 - Gasification reaction kinetics for synthetic liquid fuel production  

Science Journals Connector (OSTI)

Abstract The gasification process is a chemically and physically complex operation. This chapter presents a description of the chemistry of gasification reactions. It also discusses the assorted reactions involved in gasification and the various thermodynamic aspects of these reactions that dictate the process parameters used to produce the various gases.

J.G. Speight

2015-01-01T23:59:59.000Z

368

Short Communication Catalytic coal gasification: use of calcium versus potassium*  

E-Print Network (OSTI)

Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R on the gasification in air and 3.1 kPa steam of North Dakota lignitic chars prepared under slow and rapid pyrolysis of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis

369

The Public Perceptions of Underground Coal Gasification (UCG)  

E-Print Network (OSTI)

The Public Perceptions of Underground Coal Gasification (UCG): A Pilot Study Simon Shackley #12;The Public Perceptions of Underground Coal Gasification (UCG): A Pilot Study Dr Simon Shackley of Underground Coal Gasification (UCG) in the United Kingdom. The objectives were to identify the main dangers

Watson, Andrew

370

Gasification of woody biomass Tessa Jansen (s0140600)  

E-Print Network (OSTI)

1 Gasification of woody biomass Tessa Jansen (s0140600) University of Twente Internship at SINTEF costs. So I would be working on biomass gasification and perform thermo gravimetric analysis (TGA process and char reactivity has been investigated by performing multiple gasification, pyrolysis

Luding, Stefan

371

An evaluation of tannery industry wastewater treatment sludge gasification by artificial neural network modeling  

Science Journals Connector (OSTI)

Abstract This paper reports on the calorific value of synthetic gas (syngas) produced by gasification of dewatered sludge derived from treatment of tannery wastewater. Proximate and ultimate analyses of samples were performed. Thermochemical conversion alters the chemical structure of the waste. Dried air was used as a gasification agent at varying flow rates, which allowed the feedstock to be quickly converted into gas by means of different heterogeneous reactions. A lab-scale updraft fixed-bed steel reactor was used for thermochemical conversion of sludge samples. Artificial neural network (ANN) modeling techniques were used to observe variations in the syngas related to operational conditions. Modeled outputs showed that temporal changes of model predictions were in close accordance with real values. Correlation coefficients (r) showed that the ANN used in this study gave results with high sensitivity.

Atakan Ongen; H. Kurtulus Ozcan; Semiha Aray?c?

2013-01-01T23:59:59.000Z

372

Biomass Gasification in Fluidized Bed:? Where To Locate the Dolomite To Improve Gasification?  

Science Journals Connector (OSTI)

Figure 5 Steam content in the flue gas vs relative amount of dolomite used for two different locations of the dolomite and for two gasifying agents; (a) gasification with H2O + O2 mixtures, GR = 0.86?1.16, ... Figure 6 Low heating value of the flue gas for two locations of the dolomite and for two gasifying agents; (a) gasification with H2O + O2 mixtures, GR = 0.86?1.16, ... Figure 7 Gas yield for two locations of the dolomite and for two gasifying agents; (a) gasification with H2O + O2 mixtures; GR = 0.86?1.16, ...

José Corella; María-Pilar Aznar; Javier Gil; Miguel A. Caballero

1999-10-28T23:59:59.000Z

373

Process for fixed bed coal gasification  

DOE Patents (OSTI)

The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

Sadowski, Richard S. (Greenville, SC)

1992-01-01T23:59:59.000Z

374

NETL: Gasification Systems - Model Based Optimal Sensor Network Design for  

NLE Websites -- All DOE Office Websites (Extended Search)

Model Based Optimal Sensor Network Design for Condition Monitoring Model Based Optimal Sensor Network Design for Condition Monitoring Project Number: FE0005712 General Electric (GE) Global Research is developing an advanced model-based optimal sensor network to monitor the condition of the gasification section in an integrated gasification combined cycle (IGCC) plant. The work builds on model-based controls aimed at enhancing efficiency and operational flexibility through increased automation. Within an overall strategy of employing model-based online monitoring and predictive controls, GE Global Research is extending existing models for the gasifier and radiant syngas cooler to include the effects of degradation and fouling on the sensed variables like temperature etc., and will implement an estimation algorithm to assess the extent of gasifier refractory degradation and radiant syngas cooler fouling. An optimization-based solution will be employed to optimally place the hardware sensors utilized in the estimation algorithm in order to achieve the monitoring requirements at the lowest cost. The performance of the sensor placement algorithm and resulting monitoring solution will be demonstrated through simulations using representative test cases. The overall approach is one of the first to be applicable to condition monitoring of critical components in IGCC plants.

375

Production of Hydrogen from Underground Coal Gasification  

DOE Patents (OSTI)

A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

Upadhye, Ravindra S. (Pleasanton, CA)

2008-10-07T23:59:59.000Z

376

Economic development through biomass system integration. Volumes 2--4  

SciTech Connect

Report documents a feasibility study for an integrated biomass power system, where an energy crop (alfalfa) is the feedstock for a processing plant and a power plant (integrated gasification combined cycle) in a way that benefits the facility owners.

DeLong, M.M.

1995-10-01T23:59:59.000Z

377

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Feed Systems Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems Air Products and Chemicals, Inc. Project Number: FC26-98FT40343 Project Description Air Products and Chemicals, Inc. is developing, scaling-up, and demonstrating a novel air separation technology for large-scale production of oxygen (O2) at costs that are approximately one-third lower than conventional cryogenic plants. An Ion Transport Membrane (ITM) Oxygen plant co-produces power and oxygen. A phased technology RD&D effort is underway to demonstrate all necessary technical and economic requirements for scale-up and industrial commercialization. The ITM Oxygen production technology is a radically different approach to producing high-quality tonnage oxygen and to enhance the performance of integrated gasification combined cycle and other advanced power generation systems. Instead of cooling air to cryogenic temperatures, oxygen is extracted from air at temperatures synergistic with power production operations. Process engineering and economic evaluations of integrated gasification combined cycle (IGCC) power plants comparing ITM Oxygen with a state-of-the-art cryogenic air separation unit are aimed to show that the installed capital cost of the air separation unit and the installed capital of IGCC facility are significantly lower compared to conventional technologies, while improving power plant output and efficiency. The use of low-cost oxygen in combustion processes would provide cost-effective emission reduction and carbon management opportunities. ITM Oxygen is an enabling module for future plants for producing coal derived shifted synthesis gas (a mixture of hydrogen [H2] and carbon dioxide [CO2]) ultimately for producing clean energy and fuels. Oxygen-intensive industries such as steel, glass, non-ferrous metallurgy, refineries, and pulp and paper may also realize cost and productivity benefits as a result of employing ITM Oxygen.

378

Selection of Coal Gasification Parameters for Injection of Gasification Products Into a Blast Furnace  

Science Journals Connector (OSTI)

An analytical study was performed on the influence of blast parameters on the course of the processes in the volume of a blast furnace and smelting rates by injection of low-grade coal gasification products. It w...

I. G. Tovarovsky; A. E. Merkulov

2014-01-01T23:59:59.000Z

379

Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, April 1--June 30, 1992  

SciTech Connect

This quarterly technical progress report summarizes work completed during the Seventh Quarter of the First Budget Period, April 1 through June 30, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion will include the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/Pressurized Circulating Fluidized Bed Gas Source; Hot Gas Cleanup Units to mate to all gas streams. Combustion Gas Turbine; Fuel Cell and associated gas treatment; and Externally Fired Gas Turbine/Water Augmented Gas Turbine. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

Not Available

1992-12-01T23:59:59.000Z

380

NETL: Gasification Systems - Liquid Carbon Dioxide/Coal Slurry for Feeding  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Feed Systems Liquid Carbon Dioxide/Coal Slurry for Feeding Low-Rank Coal to Gasifiers Project Number: DE-FE0007977 There is increased interest in carbon capture and storage (CCS) for future coal-based power plants, and in a CCS integrated gasification plant, relatively pure, high pressure CO2 stream(s) will be available within the power plant. Electric Power Research Institute (EPRI) aims to help reduce the cost and improve the efficiency of integrated gasification combined cycle (IGCC) with CCS by using a portion of the high purity CO2 product stream as the carrier fluid to feed low rank coal (LRC) into the gasifier. EPRI proposes to confirm the potential advantages of LRC/liquid carbon dioxide (LCO2) slurries by: Conducting plant-wide technical and economic simulations.

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Biomass Gasification at The Evergreen State College  

E-Print Network (OSTI)

Biomass Gasification at The Evergreen State College Written by Students of the Winter 2011 Program "Applied Research: Biomass, Energy, and Environmental Justice" At The Evergreen State College, Olympia://blogs.evergreen.edu/appliedresearch/ #12; i Table of Contents Chapter 1: Introduction to Biomass at the Evergreen State College by Dani

382

World Gasification Database Now Available from DOE  

Energy.gov (U.S. Department of Energy (DOE))

A database just released by the U.S. Department of Energy documents the worldwide growth of gasification, the expected technology of choice for future coal-based plants that produce power, fuels, and/or chemicals with near-zero emissions.

383

Optimum Design of Coal Gasification Plants  

E-Print Network (OSTI)

This paper deals with the optimum design of heat recovery systems using the Texaco Coal Gasification Process (TCGP). TCGP uses an entrained type gasifier and produces hot gases at approximately 2500oF with high heat flux. This heat is removed...

Pohani, B. P.; Ray, H. P.; Wen, H.

1982-01-01T23:59:59.000Z

384

NETL: Gasification Systems and Industry Analyses Studies  

NLE Websites -- All DOE Office Websites (Extended Search)

Analyses Studies Analyses Studies Gasification Systems Reference Shelf – Systems and Industry Analyses Studies Table of Contents Cost and Performance Baseline for Fossil Energy Power Plants Studies Gasification Systems Program's Systems and Industry Analyses Studies DOE/NETL possesses strong systems analysis and policy-support capabilities. Systems analysis in support of the Gasification Systems Program consists of conducting various energy analyses that provide input to decisions on issues such as national plans and programs, resource use, environmental and energy security policies, technology options for research and development programs, and paths to deployment of energy technology. Cost and Performance Baseline for Fossil Energy Power Plants Studies The Cost and Performance Baseline for Fossil Energy Power Plants studies establish up-to-date estimates for the cost and performance of combustion and gasification based power plants as well as options for co-generating synthetic natural gas and fuels, all with and without carbon dioxide capture and storage. Several ranks of coal are being assessed in process configurations that are based on technology that could be constructed today such that the plant could be operational in the 2010 - 2015 timeframe. The analyses were performed on a consistent technical and economic basis that accurately reflects current market conditions.

385

Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process  

DOE Patents (OSTI)

In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

DeGeorge, Charles W. (Chester, NJ)

1981-01-01T23:59:59.000Z

386

Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion Project. Quarterly report, April--June 1996  

SciTech Connect

The objective of this project is to evaluate hot gas particle control technologies using coal-derived as streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed Include the integration of the particulate control devices into coal utilization systems, on-line cleaning, techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing, Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: 1 . Carbonizer/Pressurized Circulating, Fluidized Bed Gas Source; 2. Hot Gas Cleanup Units to mate to all gas streams; 3. Combustion Gas Turbine; 4. Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during, this reporting period was continuing, the detailed design of the FW portion of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel is complete and the construction of steel for the coal preparation structure is complete.

NONE

1996-12-31T23:59:59.000Z

387

Draft Environmental Impact Statement for the Orlando Gasification Project  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

This environmental impact statement (EIS) has been prepared by the U.S. Department of Energy (DOE), in compliance with the National Environmental Policy Act of 1969 (NEPA) as amended (42 USC 4321 et seq.), Council on Environmental Quality regulations for implementing NEPA (40 CFR Parts 1500-1508), and DOE NEPA regulations (10 CFR Part 1021). The EIS evaluates the potential environmental impacts associated with the construction and operation of a project which was proposed by Southern Company in partnership with the Orlando Utilities Commission (OUC) and which has been selected by DOE under the Clean Coal Power Initiative (CCPI) program. The proposed project would demonstrate advanced power generation systems using Integrated Gasification Combined Cycle (IGCC)

388

NETL: Gasification - Feasibility Studies to Improve Plant Availability and  

NLE Websites -- All DOE Office Websites (Extended Search)

Feasibility Studies to Improve Plant Availability and Reduce Total Installed Cost in IGCC Plants Feasibility Studies to Improve Plant Availability and Reduce Total Installed Cost in IGCC Plants General Electric Company Project Number: FE0007859 Project Description General Electric Company (GE) is studying the feasibility of improving plant availability and reducing total installed costs in Integrated Gasification Combined Cycle (IGCC) plants. GE is evaluating the IGCC technology effects of total installed cost and availability through deployment of a multi-faceted approach in technology evaluation, constructability, and design methodology. Eastman Chemical Company will be supporting the GE effort on certain technologies by providing consulting on the evaluations and technology transfer phases of the project. The end result is aimed at reducing the time to technological maturity and enabling plants to reach higher values of availability in a shorter period of time and at a lower installed cost.

389

DIFFUSION COATINGS FOR CORROSION RESISTANT COMPONENTS IN COAL GASIFICATION SYSTEMS  

SciTech Connect

Advanced electric power generation systems use a coal gasifier to convert coal to a gas rich in fuels such as H{sub 2} and CO. The gas stream contains impurities such as H{sub 2}S and HCl, which attack metal components of the coal gas train, causing plant downtime and increasing the cost of power generation. Corrosion-resistant coatings would improve plant availability and decrease maintenance costs, thus allowing the environmentally superior integrated gasification combined cycle plants to be more competitive with standard power-generation technologies. A startup meeting was held at the National Energy Technology Center, Pittsburgh, PA site on July 28, 2003. SRI staff described the technical approach of the project.

Gopala N. Krishnan

2004-05-01T23:59:59.000Z

390

Device Scale Model Development for Transport Reactor  

NLE Websites -- All DOE Office Websites (Extended Search)

Gary J. stiegel Gary J. stiegel Gasification Technology Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-4499 gary.stiegel@netl.doe.gov Chris Guenther Computational Science Division National Energy Technology Laboratory 3610 Collins Ferry Road P. O. Box 880 Morgantown, WV 26507 304-285-4483 chris.guenther@netl.doe.gov 8/2006 Gasification Technologies Device Scale MoDel DevelopMent for tranSport reactor Background Coal gasification is an efficient and environmentally acceptable technology that can utilize the vast coal reserves in the United States to produce clean affordable power and reduce dependence on foreign oil. Coal and other carbon containing materials can be gasified to produce a synthesis gas. This syngas can be fed to a

391

Coal properties and system operating parameters for underground coal gasification  

SciTech Connect

Through the model experiment for underground coal gasification, the influence of the properties for gasification agent and gasification methods on underground coal gasifier performance were studied. The results showed that pulsating gasification, to some extent, could improve gas quality, whereas steam gasification led to the production of high heating value gas. Oxygen-enriched air and backflow gasification failed to improve the quality of the outlet gas remarkably, but they could heighten the temperature of the gasifier quickly. According to the experiment data, the longitudinal average gasification rate along the direction of the channel in the gasifying seams was 1.212 m/d, with transverse average gasification rate 0.069 m/d. Experiment indicated that, for the oxygen-enriched steam gasification, when the steam/oxygen ratio was 2:1, gas compositions remained stable, with H{sub 2} + CO content virtually standing between 60% and 70% and O{sub 2} content below 0.5%. The general regularities of the development of the temperature field within the underground gasifier and the reasons for the changes of gas quality were also analyzed. The 'autopneumatolysis' and methanization reaction existing in the underground gasification process were first proposed.

Yang, L. [China University of Mining & Technology, Xuzhou (China)

2008-07-01T23:59:59.000Z

392

Comparison of gasification kinetics parameters of different types of nuclear graphite  

SciTech Connect

A chemical-reaction kinetics model of nuclear graphite gasification has recently been developed and successfully validated with gasification rate measurements for nuclear graphite grades of IG-110, IG-430, NBG-18 and NBG-25. The model employs 4 elementary chemical reactions with applicable parameters, including the values and Gaussian-like distributions of the specific activation energies, the pre-exponential coefficients for adsorption of oxygen and desorption of CO and CO{sub 2} gases, and the surface area of free active sites. These parameters are determined from the reported measurements of the total gasification and transient weight loss using a multi-parameter optimization algorithm. The determined chemical kinetics parameters for IG-100 and NB-25 are nearly the same, but slightly different from those for NBG-18 and IG-430. The initial specific area of free active sites is inversely proportional to the square root of the mass or volume of the graphite specimens used in experiments. The recommended chemical kinetics parameters in this paper for these grades of nuclear graphite should be applicable to future safety analysis of high-temperature gas cooled reactors in the unlikely event of a massive air ingress accident. (authors)

El-Genk, M. S. [Inst. for Space and Nuclear Power Studies, Univ. of New Mexico, Albuquerque, NM (United States); Chemical and Nuclear Engineering Dept., Univ. of New Mexico, Albuquerque, NM (United States); Mechanical Engineering Dept., Univ. of New Mexico, Albuquerque, NM (United States); Tournier, J. M. P. [Inst. for Space and Nuclear Power Studies, Univ. of New Mexico, Albuquerque, NM (United States); Chemical and Nuclear Engineering Dept., Univ. of New Mexico, Albuquerque, NM (United States)

2012-07-01T23:59:59.000Z

393

Diffusion velocity correlation for nuclear graphite gasification at high temperature and low Reynolds numbers  

SciTech Connect

The safety analysis of High-Temperature and Very High Temperature gas-cooled Reactors requires reliable estimates of nuclear graphite gasification as a function of temperature, among other parameters, in the unlikely event of an air ingress accident. Although the rates of the prevailing chemical reactions increase exponentially with temperature, graphite gasification at high temperatures is limited by the oxygen diffusion through the boundary layer. The effective diffusion velocity depends on the total flow rate and pressure of the bulk air-gas mixture. This paper develops a semi-empirical Sherwood number correlation for calculating the oxygen diffusion velocity. The correlation is based on a compiled database of the results of convective heat transfer experiments with wires and cylinders of different diameters in air, water and paraffin oil at 0.006 {<=} Re {<=} 1,604 and 0.068 {<=} Sc {<=} 35.2, and of mass transfer experiments at 4.8 {<=} Re {<=} 77 and 1,300 {<=} Sc {<=} 2,000. The developed correlation is within {+-} 8% of the compiled database of 567 data points and consistent with reported gasification rate measurements at higher temperatures in experiments using different size specimens of nuclear graphite grades of NBG-18 and NB-25, IG-11, IG-110 and IG-430 in atmospheric air at 0.08 {<=} Re {<=} 30. Unlike the Graetz solution that gives a constant Sh of 3.66 at Re {<=} 1.0, the present correlation shows Sh decreases monotonically to much lower values with decreasing Re. (authors)

El-Genk, M. S. [Inst. for Space and Nuclear Power Studies, Univ. of New Mexico, Albuquerque, NM (United States); Chemical and Nuclear Engineering Dept., Univ. of New Mexico, Albuquerque, NM (United States); Mechanical Engineering Dept., Univ. of New Mexico, Albuquerque, NM (United States); Tournier, J. M. P. [Inst. for Space and Nuclear Power Studies, Univ. of New Mexico, Albuquerque, NM (United States); Chemical and Nuclear Engineering Dept., Univ. of New Mexico, Albuquerque, NM (United States)

2012-07-01T23:59:59.000Z

394

THE PRODUCTION OF SYNGAS VIA HIGH TEMPERATURE ELECTROLYSIS AND BIO-MASS GASIFICATION  

SciTech Connect

A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to improve the hydrogen production efficiency of the steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon dioxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K.

M. G. McKellar; G. L. Hawkes; J. E. O'Brien

2008-11-01T23:59:59.000Z

395

Gasification of Organosolv-lignin Over Charcoal Supported Noble Metal Salt Catalysts in Supercritical Water  

Science Journals Connector (OSTI)

Charcoal supported metal salt catalysts showed activities for the lignin gasification at 673 K, especially the catalysts without chloride anion showed the complete gasification. The order of activity for the gasification

Aritomo Yamaguchi; Norihito Hiyoshi; Osamu Sato; Masayuki Shirai

2012-08-01T23:59:59.000Z

396

Fixed Bed Counter Current Gasification of Mesquite and Juniper Biomass Using Air-steam as Oxidizer  

E-Print Network (OSTI)

Thermal gasification of biomass is being considered as one of the most promising technologies for converting biomass into gaseous fuel. Here we present results of gasification, using an adiabatic bed gasifier with air, steam as gasification medium...

Chen, Wei 1981-

2012-11-27T23:59:59.000Z

397

Integrated fuel performance and thermal-hydraulic sub-channel models for analysis of sodium fast reactors  

E-Print Network (OSTI)

Sodium Fast Reactors (SFR) show promise as an effective way to produce clean safe nuclear power while properly managing the fuel cycle. Accurate computer modeling is an important step in the design and eventual licensing ...

Fricano, Joseph William

2012-01-01T23:59:59.000Z

398

Advanced Biomass Gasification Technologies Inc ABGT | Open Energy  

Open Energy Info (EERE)

Gasification Technologies Inc ABGT Gasification Technologies Inc ABGT Jump to: navigation, search Name Advanced Biomass Gasification Technologies Inc. (ABGT) Place New York, New York Zip 10036 Product Company set up by UTEK specifically for its sale to Xethanol, holding the exclusive license for microgasification technology developed at the Energy and Environmental Research Center (EERC) at the University of North Dakota. References Advanced Biomass Gasification Technologies Inc. (ABGT)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Advanced Biomass Gasification Technologies Inc. (ABGT) is a company located in New York, New York . References ↑ "Advanced Biomass Gasification Technologies Inc. (ABGT)"

399

How Coal Gasification Power Plants Work | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification » How Coal Gasification » How Coal Gasification Power Plants Work How Coal Gasification Power Plants Work How Coal Gasification Power Plants Work The heart of a gasification-based system is the gasifier. A gasifier converts hydrocarbon feedstock into gaseous components by applying heat under pressure in the presence of steam. A gasifier differs from a combustor in that the amount of air or oxygen available inside the gasifier is carefully controlled so that only a relatively small portion of the fuel burns completely. This "partial oxidation" process provides the heat. Rather than burning, most of the carbon-containing feedstock is chemically broken apart by the gasifier's heat and pressure, setting into motion chemical reactions that produce "syngas." Syngas is primarily hydrogen and carbon monoxide, but can include

400

Gasification Characteristics of Coal/Biomass Mixed Fuels  

SciTech Connect

A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures. A key result of this work is the finding that the reactivities of the mixed chars were not always in between the reactivities of the pure component chars at comparable gasification conditions. Mixed char reactivity to CO2 was lower than the reactivities of both the pure Wyodak coal and pure corn stover chars to CO2. In contrast, mixed char reactivity to H2O was higher than the reactivities of both the pure Wyodak coal and pure corn stover chars to H2O. This was found to be in part, a consequence of the reduced mass specific surface areas of the coal char particles formed during devolatilization when the coal and biomass particles are co-fired. The biomass particles devolatilize prior to the coal particles, impacting the temperature and the composition of the environment in which the coal particles devolatilize. This situation results in coal char particles within the mixed char that differ in specific surface area and reactivity from the coal char particles produced in the absence of the devolatilizing biomass particles. Due to presence of this “affected” coal char, it was not possible to develop a mixed char reactivity model that uses linear mixing rules to determine the reactivity of a mixed char from only the reactivities of the pure mixture components. However, it was possible to predict both mixed char specific surface area and reactivity for a wide range of fuel mixture rat os provided the specific surface area and reactivity of the affected coal char particles are known. Using the kinetic parameters determined for the Wyodak coal and corn stover chars, the model was found to adequately predict the observed conversion times and off-gas compositions

Mitchell, Reginald

2013-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks  

Science Journals Connector (OSTI)

7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks ... 4 Here we report the preliminary results of continuous-flow reactor studies with wet biomass feedstocks using new catalyst systems developed specifically for these processing conditions. ... Developing catalysts for this processing environment has also been an important factor in making this processing technology viable.2 Previous reports of continuous reactor tests with biomass feedstocks provide preliminary short-term processing results,8,9 but also show the problems of long-term operation of the process with the contaminants inherent in biomass. ...

Douglas C. Elliott; Gary G. Neuenschwander; Todd R. Hart; R. Scott Butner; Alan H. Zacher; Mark H. Engelhard; James S. Young; David E. McCready

2004-03-25T23:59:59.000Z

402

NETL: Gasification - Recovery Act: Scale-Up of Hydrogen Transport Membranes  

NLE Websites -- All DOE Office Websites (Extended Search)

Recovery Act: Scale-Up of Hydrogen Transport Membranes for IGCC and FutureGen Plants Recovery Act: Scale-Up of Hydrogen Transport Membranes for IGCC and FutureGen Plants Eltron Research & Development Inc. Project Number: FC26-05NT42469 Project Description The Eltron Hydrogen Transport Membrane (HTM) technology uses composite metal alloy materials to separate H2 from coal-derived syngas (a mixture of H2, CO, CO2, and steam). Carbon dioxide on the feed side of the membrane remains at high pressure and in a concentrated form suitable for capture and re-use or storage. The Eltron HTM system is an enabling technology for the production of high purity H2 and the capture of CO2 at high pressure that is applicable to future integrated gasification combined cycle (IGCC) and central station H2 production plants. These novel membranes have an operating temperature of 280 to 440 degrees Celsius (°C), which is well-matched with emerging coal gas cleaning technologies and has the potential to significantly improve the overall efficiency and process economics for future gasification-based power, fuels, and chemical production plants. Eltron's membranes can withstand differential pressures of up to 1,000 pounds per square inch gauge (psig) without structural failure, allowing for successful integration into advanced, high-pressure coal gasification plants.

403

E-Print Network 3.0 - adiabatic fixed-bed gasification Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

State University ABSTRACT Gasification is a globally emerging technology in commercial markets... of the most developed and versatile gasification technologies is based upon...

404

NETL: 2013 Gasification Systems Project Portfolio  

NLE Websites -- All DOE Office Websites (Extended Search)

Reference Shelf > Project Portfolio Reference Shelf > Project Portfolio Gasification Systems 2013 Gasification Systems Project Portfolio Gasifier Optimization Gas Separation Gas Separation Gasifier Optimization Gasifier Optimization Gas Cleaning Gasifier Optimization Gas Cleaning Gas Separation U.S. Economic Competitiveness Gas Separation Gasifier Optimization U.S. Economic Competitiveness Gasifier Optimization U.S. Economic Competitiveness Gas Cleaning Gasifier Optimization Gas Cleaning Gasifier Optimization Gas Separation U.S. Economic Competitiveness Gas Separation U.S. Economic Competitiveness U.S. Economic Competitiveness Gas Cleaning Gas Cleaning Gas Separation Gas Cleaning Gas Separation Global Environmental Benefits Gas Separation Global Environmental Benefits Global Environmental Benefits Gas Cleaning Gas Separation Systems Analyses Global Environmental Benefits Gas Separation Systems Analyses Global Environmental Benefits Systems Analyses Global Environmental Benefits Gas Cleaning Systems Analyses Gas Cleaning Gas Separation Systems Analyses Systems Analyses Gas Cleaning Systems Analyses Systems Analyses Systems Analyses

405

Fluidized bed gasification of extracted coal  

DOE Patents (OSTI)

Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

1986-01-01T23:59:59.000Z

406

EIS-0383: Southern Company's Orlando Gasification Project, Orlando, FL  

Energy.gov (U.S. Department of Energy (DOE))

This EIS analyzes DOE's decision to provide cost-shared funding for construction, design, and operation of a new gasification plant in Orlando, Florida.

407

Biomass Gasification and Methane Digester Property Tax Exemption  

Energy.gov (U.S. Department of Energy (DOE))

Michigan exempts certain energy production related farm facilities from real and personal property taxes. Among exempted property are certain methane digesters, biomass gasification equipment,...

408

Upgrading of Pitch Produced by Mild Gasification of Subbituminous Cal  

Science Journals Connector (OSTI)

Upgrading of Pitch Produced by Mild Gasification of Subbituminous Cal ... Structural Characterization of Coal Tar Pitches Obtained by Heat Treatment under Different Conditions ...

Robert L. McCormick; Mahesh C. Jha

1994-03-01T23:59:59.000Z

409

Underground coal gasification : overview of an economic and environmental evaluation.  

E-Print Network (OSTI)

??This paper examines an overview of the economic and environmental aspects of Underground Coal Gasification (UCG) as a viable option to the above ground Surface… (more)

Kitaka, Richard Herbertson

2012-01-01T23:59:59.000Z

410

Fluidized bed injection assembly for coal gasification  

DOE Patents (OSTI)

A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

1981-01-01T23:59:59.000Z

411

Black liquor gasification. Phase 2 final report  

SciTech Connect

The experimental work included 23 bench-scale tests in a 6-in.-diameter gasifier and two extended runs in a 33-in.-ID pilot-scale unit. The two pilot-scale runs included 26 test periods, each evaluated separately. The engineering analysis work consisted primarily of the correlation of test results and the development of a computer model describing the gasification process. 4 refs., 13 figs., 23 tabs.

Kohl, A.L.; Barclay, K.M.; Stewart, A.E.; Estes, G.R.

1984-11-28T23:59:59.000Z

412

Improved Refractory Materials for Slagging Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Fac Fac ts Materials Science contact Bryan Morreale Focus Area Leader (Acting) Materials Science Office of Research and Development National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15326 412-386-5929 bryan.morreale@netl.doe.gov Partner Harbison-Walker Refractories Company Improved Refractory Materials for Slagging Gasification Systems Advances in technology are often directly linked to materials development. For

413

Stabilization of spent sorbents from coal gasification. Final technical report, September 1, 1992--August 31, 1993  

SciTech Connect

The objective of this investigation was to determine the rates of reactions involving partially sulfided dolomite and oxygen, which is needed for the design of the reactor system for the stabilization of sulfide-containing solid wastes from gasification of high sulfur coals. To achieve this objective, samples of partially sulfided dolomite were reacted with oxygen at a variety of operating conditions in a fluidized-bed reactor. The effect of external diffusion was eliminated by using small quantities of the sorbent and maintaining a high flow rate of the reactant gas. The reacted sorbents were analyzed to determine the extent of conversion as a function of operating variables including sorbent particle size, reaction temperature and pressure, and oxygen concentration. The results of sulfation tests indicate that the rate of reaction increases with increasing temperature, increasing oxygen partial pressure, and decreasing sorbent particle size. The rate of the sulfation reaction can be described by a diffuse interface model where both chemical reaction and intraparticle diffusion control the reaction rate. The kinetic model of the sulfation reaction was used to determine the requirements for the reactor system, i.e., reactor size and operating conditions, for successful stabilization of sulfide-containing solid wastes from gasification of high sulfur coals (with in-bed desulfurization using calcium based sorbents). The results indicate that the rate of reaction is fast enough to allow essentially complete sulfation in reactors with acceptable dimensions. The optimum sulfation temperature appears to be around 800{degrees}C for high pressure as well as atmospheric stabilization of the spent sorbents.

Abbasian, J.; Hill, A.H.; Rue, D.M.; Wangerow, J.R. [Institute of Gas Technology, Chicago, IL (United States)

1993-12-31T23:59:59.000Z

414

NETL: Gasification Systems - Evaluation of the Benefits of Advanced Dry  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Feed Systems Evaluation of the Benefits of Advanced Dry Feed System for Low Rank Coal Project Number: DE-FE0007902 General Electric Company (GE) is evaluating and demonstrating the benefits of novel dry feed technologies to effectively, reliably, and economically provide feeding of low-cost, low-rank coals into commercial Integrated Gasification Combined Cycle (IGCC) systems. GE is completing comparative techno-economic studies of two IGCC power plant cases, one without and one with advanced dry feed technologies. A common basis of design is being developed so that overall assumptions and methodologies are common in the two cases for both technical and economic areas. The baseline case, without advanced dry feed technologies, will use operational data from the Eastman Chemical Company Kingsport gasification facility in combination with DOE/NETL's Cost and Performance Baseline Low-Rank Coal to Electricity IGCC study for both cost and performance comparisons. Advanced dry feed technologies, based upon the Posimetric® pump currently under development by GE, will be developed to match the proposed plant conditions and configuration, and will be analyzed to provide comparative performance and cost information to the baseline plant case. The scope of this analysis will cover the feed system from the raw coal silo up to, and including, the gasifier injector. Test data from previous and current testing will be summarized in a report to support the assumptions used to evaluate the advanced technologies and the potential value for future applications. This study focuses primarily on IGCC systems with 90 percent carbon capture, utilization, and storage (CCUS), but the dry feed system will be applicable to all IGCC power generating plants, as well as other industries requiring pressurized syngas.

415

System study on partial gasification combined cycle with CO{sub 2} recovery - article no. 051801  

SciTech Connect

S partial gasification combined cycle with CO{sub 2} recovery is proposed in this paper. Partial gasification adopts cascade conversion of the composition of coal. Active composition of coal is simply gasified, while inactive composition, that is char, is burnt in a boiler. Oxy-fuel combustion of syngas produces only CO{sub 2} and H{sub 2}O, so the CO{sub 2} can be separated through cooling the working fluid. This decreases the amount of energy consumption to separate CO{sub 2} compared with conventional methods. The novel system integrates the above two key technologies by injecting steam from a steam turbine into the combustion chamber of a gas turbine to combine the Rankine cycle with the Brayton cycle. The thermal efficiency of this system will be higher based on the cascade utilization of energy level. Compared with the conventional integrated gasification combined cycle (IGCC), the compressor of the gas turbine, heat recovery steam generator (HRSG) and gasifier are substituted for a pump, reheater, and partial gasifier, so the system is simplified. Furthermore, the novel system is investigated by means of energy-utilization diagram methodology and provides a simple analysis of their economic and environmental performance. As a result, the thermal efficiency of this system may be expected to be 45%, with CO{sub 2} recovery of 41.2%, which is 1.5-3.5% higher than that of an IGCC system. At the same time, the total investment cost of the new system is about 16% lower than that of an IGCC. The comparison between the partial gasification technology and the IGCC technology is based on the two representative cases to identify the specific feature of the proposed system.

Xu, Y.J.; Jin, H.G.; Lin, R.M.; Han, W. [Chinese Academy of Science, Beijing (China)

2008-09-15T23:59:59.000Z

416

Co-gasification Reactivity of Coal and Woody Biomass in High-Temperature Gasification  

Science Journals Connector (OSTI)

(20) Although the total pressure was 0.5 MPa and lower than the usual conditions of the gasifier, it has been confirmed that the total pressure has little influence on the gasification rate of char when the partial pressure of the gasifying agent is the same and the total pressure is less than 2 MPa. ... While the pyrolysis and the char gasification were tested separately in the above experiments, raw samples of coals, cedar bark, and the mixtures were gasified with carbon dioxide at high temperature using the PDTF facility in this section, the same as the reductor in the air-blown two-stage entrained flow coal gasifier. ...

Shiro Kajitani; Yan Zhang; Satoshi Umemoto; Masami Ashizawa; Saburo Hara

2009-09-24T23:59:59.000Z

417

Biomass Gasification Research Facility Final Report  

SciTech Connect

While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-02GO12024 and DE-FC36-03GO13175) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. The primary objectives of Cooperative Agreement DE-FC36-02GO12024 were the selection, acquisition, and application of a suite of gas analyzers capable of providing near real-time gas analyses to suitably conditioned syngas streams. A review was conducted of sampling options, available analysis technologies, and commercially available analyzers, that could be successfully applied to the challenging task of on-line syngas characterization. The majority of thermochemical process streams comprise multicomponent gas mixtures that, prior to crucial, sequential cleanup procedures, include high concentrations of condensable species, multiple contaminants, and are often produced at high temperatures and pressures. Consequently, GTI engaged in a concurrent effort under Cooperative Agreement DE-FC36-03GO13175 to develop the means to deliver suitably prepared, continuous streams of extracted syngas to a variety of on-line gas analyzers. The review of candidate analysis technology also addressed safety concerns associated with thermochemical process operation that constrain the location and configuration of potential gas analysis equipment. Initial analyzer costs, reliability, accuracy, and operating and maintenance costs were also considered prior to the assembly of suitable analyzers for this work. Initial tests at GTI’s Flex-Fuel Test Facility (FFTF) in late 2004 and early 2005 successfully demonstrated the transport and subsequent analysis of a single depressurized, heat-traced syngas stream to a single analyzer (an Industrial Machine and Control Corporation (IMACC) Fourier-transform infrared spectrometer (FT-IR)) provided by GTI. In March 2005, our sampling approach was significantly expanded when this project participated in the U.S. DOE’s Novel Gas Cleaning (NGC) project. Syngas sample streams from three process locations were transported to a distribution manifold for selectable analysis by the IMACC FT-IR, a Stanford Research Systems QMS300 Mass Spectrometer (SRS MS) obtained under this Cooperative Agreement, and a Varian micro gas chromatograph with thermal conductivity detector (?GC) provided by GTI. A syngas stream from a fourth process location was transported to an Agilent Model 5890 Series II gas chromatograph for highly sensitive gas analyses. The on-line analyses made possible by this sampling system verified the syngas cleaning achieved by the NGC process. In June 2005, GTI collaborated with Weyerhaeuser to characterize the ChemrecTM black liquor gasifier at Weyerhaeuser’s New Bern, North Carolina pulp mill. Over a ten-day period, a broad range of process operating conditions were characterized with the IMACC FT-IR, the SRS MS, the Varian ?GC, and an integrated Gas Chromatograph, Mass Selective Detector, Flame Ionization Detector and Sulfur Chemiluminescence Detector (GC/MSD/FID/SCD) system acquired under this Cooperative Agreement from Wasson-ECE. In this field application, a single sample stream was extracted from this low-pressure, low-temperature process and successfully analyzed by these devices. In late 2005,

Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

2007-09-30T23:59:59.000Z

418

1 - Gasification and synthetic liquid fuel production: an overview  

Science Journals Connector (OSTI)

Abstract This chapter discusses general considerations on gasification processes and synthetic liquid fuel production. It provides an overview of state-of-the-art gasification technologies, feedstocks and applications in power generation, and synthetic fuels production, together with some recent future trends in the field.

R. Luque; J.G. Speight

2015-01-01T23:59:59.000Z

419

Study on the Nitric Compounds during Coal Gasification  

Science Journals Connector (OSTI)

This investigation involved the formation and evolution of NO? HCN and NH3 during coal gasification. Since HCN and NH3 are the precursors of NOX, their summation are considered to show the characteristics of the precursors in this paper. The experiments ... Keywords: gasification, NOX precursors, particle size, agent

Jun Xiang; Qingsen Zhao; Song Hu; Lushi Sun; Sheng Su; Kai Xu; Tengfei Lu; Gang Chen

2009-10-01T23:59:59.000Z

420

Methods for sequestering carbon dioxide into alcohols via gasification fermentation  

DOE Patents (OSTI)

The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

2013-11-26T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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to obtain the most current and comprehensive results.


421

Pyrolysis, combustion and gasification characteristics of miscanthus and sewage sludge  

Science Journals Connector (OSTI)

Abstract The energetic conversion of biomass into syngas is considered as reliable energy source. In this context, biomass (miscanthus) and sewage sludge have been investigated. A simultaneous thermal analyzer and mass spectrometer was used for the characterization of samples and identified the volatiles evolved during the heating of the sample up to 1100 °C under combustion and gasification conditions. The TG and DTA results were discussed in argon, oxygen, steam and steam blended gas atmospheres. Different stages of pyrolysis, combustion and gasification of the samples have been examined. It was shown that the combustion and gasification of char were occurred in two different temperature zones. The DTA–MS profile of the sample gives information on combustion and gasification process of the samples (ignition, peak combustion and burnout temperatures) and gases released (H2, O2, CO and CO2). The results showed that the different processes were mainly dependent on temperature. The evolution of the gas species was consistent with the weight loss of the samples during pyrolysis, combustion and gasification process. The effect of the ambiences during pyrolysis, combustion and gasification of the samples were reported. The appropriate temperature range to the sludge and miscanthus gasification was evaluated. The kinetic parameters of the biomass and sewage sludge were estimated for TGA using two models based on first-order reactions with distributed activation energies. The presence of ash in the biomass char was more influential during the gasification process.

Kandasamy Jayaraman; Iskender Gökalp

2015-01-01T23:59:59.000Z

422

Gasification of an Indonesian subbituminous coal in a pilot-scale coal gasification system  

Science Journals Connector (OSTI)

Indonesian Roto Middle subbituminous coal was gasified in a pilot-scale dry-feeding gasification system and the produced syngas was purified...2, and 5–8% CO2. Particulates in syngas were 99.8% removed by metal f...

Yongseung Yun; Seok Woo Chung

2007-07-01T23:59:59.000Z

423

Wabash River Coal Gasification Repowering Project Final Technical Report  

Office of Scientific and Technical Information (OSTI)

Wabash River Coal Gasification Wabash River Coal Gasification Repowering Project Final Technical Report August 2000 Work Performed Under Cooperative Agreement DE-FC21-92MC29310 For: The U.S. Department of Energy Office of Fossil Energy National Energy Technology Laboratory Morgantown, West Virginia Prepared by: The Men and Women of Wabash River Energy Ltd. For Further Information Contact: Roy A. Dowd, CHMM Environmental Supervisor Wabash River Coal Gasification Repowering Project 444 West Sandford Avenue West Terre Haute, IN 47885 LEGAL NOTICE/DISCLAIMER This report was prepared by the Wabash River Coal Gasification Repowering Project Joint Venture pursuant to a Cooperative Agreement partially funded by the U.S. Department of Energy, and neither the Wabash River Coal Gasification Repowering

424

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

SciTech Connect

We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst–capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst–capture agents on (1) the syngas composition, (2) CO{sub 2} and H{sub 2}S capture, and (3) the steam–coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO–CaCO{sub 3} chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO{sub 3} was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO–CaCO{sub 3} cycles. The increased steam–coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2–4% per CaO–CaCO{sub 3} cycle. We also discuss an important application of this combined gasifier–calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO{sub 4} and ash in the precalcined feedstock.

Siefert, Nicholas S.; Shekhawat, Dushyant; Litster, Shawn; Berry, David, A

2013-08-01T23:59:59.000Z

425

ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING  

SciTech Connect

Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. The technical and economic performances of the selected processes were evaluated using computer models and available literature. Using these results, the carbon sequestration potential of the three technologies was then evaluated. The results of these evaluations are given in this final report.

Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

2002-06-01T23:59:59.000Z

426

ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING  

SciTech Connect

Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. During this reporting period, the technical and economic performances of the selected processes were evaluated using computer models and available literature. The results of these evaluations are summarized in this report.

Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

2002-04-01T23:59:59.000Z

427

Nuclear Reactor (atomic reactor)  

Science Journals Connector (OSTI)

A nuclear reactor splits Uranium or Plutonium nuclei, and the...235 is fissionable but more than 99% of the naturally occurring Uranium is U238 that makes enrichment mandatory. In some reactors U238 and Thorium23...

2008-01-01T23:59:59.000Z

428

Reduction of iron oxide as an oxygen carrier by coal pyrolysis and steam char gasification intermediate products  

SciTech Connect

The feasibility of the reduction of oxygen carrier Fe{sub 2}O{sub 3} in chemical-looping combustion using solid fuel (lignite) provided a gasifying agent like steam was introduced into the reactor was investigated with a fixed-bed reactor. The X-ray diffractometer and scanning electron microscope were used for the characterization of the Fe{sub 2}O{sub 3} and its reduction residue. Results strongly supported the feasibility of Fe{sub 2}O{sub 3} reduction by lignite and obtaining pure CO{sub 2} from the off-gases. Fe{sub 2}O{sub 3} can be fully converted to Fe{sub 3}O{sub 4} by pyrolysis and gasification intermediates primarily H{sub 2} and CO, which was confirmed by both the off-gas concentrations and X-ray diffractometer analysis. A 0.75 g portion of Fe{sub 2}O{sub 3} can be completely reduced to Fe{sub 3}O{sub 4} by the volatile matter released from 0.1 g coal, and Fe{sub 2}O{sub 3} can be fully reduced to Fe{sub 3}O{sub 4} by steam char gasification products provided that the molar ratio of carbon in char to Fe{sub 2}O{sub 3} is 1:6. The purity of CO{sub 2} in the outlet gases was higher than 85% when Fe{sub 2}O{sub 3} was reduced by intermediate products during coal pyrolysis, and the purity of CO{sub 2} in the off-gases was higher than 95% when Fe{sub 2}O{sub 3} was reduced by intermediate products resulting from steam char gasification, making CO{sub 2} sequestration disposal desirable for high purity CO{sub 2}. The char gasification reaction rate was slow compared with the reactivity of the iron oxide with the char gasified intermediates, indicating that char gasification was the rate-limiting step in the reduction process. In the steam char gasification process, the times it took to reach 90% carbon conversion for K-10-char and Ca-10-char were 15 and 30 min, respectively, at 1123 K, but the time for the raw char was 50 min at 1173 K. 40 refs., 15 figs., 3 tabs.

Jing-biao Yang; Ning-sheng Cai; Zhen-shan Li [Tsinghua University, Beijing (China). Key Laboratory of Thermal Science and Power Engineering of Ministry of Education

2007-12-15T23:59:59.000Z

429

Key tests set for underground coal gasification  

SciTech Connect

Underground coal gasification (UCG) is about to undergo some tests. The tests will be conducted by Lawrence Livermore National Laboratory (LLNL) in a coal seam owned by Washington Irrigation and Development Co. A much-improved UCG system has been developed by Stephens and his associates at LLNL - the controlled retracting injection point (CRIP) method. Pritchard Corp., Kansas City, has done some conceptual process design and has further studied the feasibility of using the raw gas from a UCG burn as a feedstock for methanol synthesis and/or MTG gasoline. Each method was described. (DP)

Haggin, J.

1983-07-18T23:59:59.000Z

430

Site clean up of coal gasification residues  

SciTech Connect

The coal gasification plant residues tested in this research consists of various particle sizes of rock, gravel, tar-sand agglomerates, fine sand and soil. Most of the soils particles were tar free. One of the fractions examined contained over 3000 ppM polyaromatic hydrocarbons (PAHs). The residues were subjected to high pressure water jet washing, float and sink tests, and soil washing. Subsequent PAH analyses found less than 1 ppM PAHs in the water jet washing water. Soils washed with pure water lowered PAH concentrations to 276 ppM; the use of surfactants decreased PAHs to 47, 200, and 240 ppM for different test conditions. In the 47 ppM test, the surfactant temperature had been increased to 80 C, suggesting that surfactant washing efficiency can be greatly improved by increasing the solution temperature. The coal tar particles were not extracted by the surfactants used. Coke and tar-sand agglomerates collected from the float and sink gravimetric separation were tested for heating value. The tar exhibited a very high heating value, while the coke had a heating value close to that of bituminous coal. These processes are believed to have the potential to clean up coal gasification plant residues at a fairly low cost, pending pilot-scale testing and a feasibility study.

Wilson, J.W.; Ding, Y. [Univ. of Missouri, Rolla, MO (United States)

1995-12-31T23:59:59.000Z

431

GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION  

SciTech Connect

The goal of this series of design and estimating efforts was to start from the as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project and to develop optimized designs for several coal and petroleum coke IGCC power and coproduction projects. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This unoptimized plant has a thermal efficiency of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW. This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal and coke-fueled power plants. This side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, showed their similarity both in design and cost (1,318 $/kW for the coal plant and 1,260 $/kW for the coke plant). Therefore, in the near term, a coke IGCC power plant could penetrate the market and provide a foundation for future coal-fueled facilities. Subtask 1.6 generated a design, cost estimate and economics for a multiple train coal-fueled IGCC powerplant, also based on the Subtaks 1.3 cases. The Subtask 1.6 four gasification train plant has a thermal efficiency of 40.6% (HHV) and cost 1,066 $/kW. The single-train advanced Subtask 1.4 plant, which uses an advanced ''G/H-class'' combustion turbine, can have a thermal efficiency of 45.4% (HHV) and a plant cost of 1,096 $/kW. Multi-train plants will further reduce the cost. Again, all these plants have superior emissions performance. Subtask 1.7 developed an optimized design for a coal to hydrogen plant. At current natural gas prices, this facility is not competitive with hydrogen produced from natural gas. The preferred scenario is to coproduce hydrogen in a plant similar to Subtask 1.3, as described above. Subtask 1.8 evaluated the potential merits of warm gas cleanup technology. This study showed that selective catalytic oxidation of hydrogen sulfide (SCOHS) is promising. As gasification technology matures, SCOHS and other improvements identified in this study will lead to further cost reductions and efficiency improvements.

Samuel S. Tam

2002-05-01T23:59:59.000Z

432

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01T23:59:59.000Z

433

Plasma gasification of waste as a method of energy saving  

Science Journals Connector (OSTI)

Several versions of the organizations of the process of plasma-chemical gasification with the use of air, carbon dioxide, steam and their mixtures as the plasma-forming gas are considered in the presentation. The results of the calculation-theoretical evaluations of the quality of synthesis gas and efficiency of gasification, and also the results of experiments on plasma gasification of wood waste carried out on the experimental IEE RAS test-bench are given. The results of calculations are compared with experimental data.

V E Popov; A N Bratsev; V A Kuznetsov; S V Shtengel; A A Ufimtsev

2011-01-01T23:59:59.000Z

434

Chapter 4 - Obstacles to Implementation of Black Liquor Gasification  

Science Journals Connector (OSTI)

Obstacles hindering the commercialization of black liquor gasification are discussed. The most important of them include financial risks, protection of the gasifier, increase in the causticizing demand, tar condensation, hot gas cleanup, and steam deficit. Gasification system demands significant capital investment. The high temperature and pressure and the alkaline conditions create aggressive environment. Protection from an aggressive environment is very important in the operation of a gasifier because it determines the lifetime and hence the feasibility of gasification as a technology as a whole.

Pratima Bajpai

2014-01-01T23:59:59.000Z

435

Carbonate fuel cell system with thermally integrated gasification  

DOE Patents (OSTI)

A fuel cell system is described which employs a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell. 2 figs.

Steinfeld, G.; Meyers, S.J.; Lee, A.

1996-09-10T23:59:59.000Z

436

Carbonate fuel cell system with thermally integrated gasification  

DOE Patents (OSTI)

A fuel cell system employing a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell.

Steinfeld, George (Southbury, CT); Meyers, Steven J. (Huntington Beach, CA); Lee, Arthur (Fishkill, NY)

1996-01-01T23:59:59.000Z

437

Storing syngas lowers the carbon price for profitable coal gasification  

SciTech Connect

Integrated gasification combined cycle (IGCC) electric power generation systems with carbon capture and sequestration have desirable environmental qualities but are not profitable when the carbon dioxide price is less than approximately $50 per metric ton. We examine whether an IGCC facility that operates its gasifier continuously but stores the syngas and produces electricity only when daily prices are high may be profitable at significantly lower CO{sub 2} prices. Using a probabilistic analysis, we have calculated the plant-level return on investment (ROI) and the value of syngas storage for IGCC facilities located in the U.S. Midwest using a range of storage configurations. Adding a second turbine to use the stored syngas to generate electricity at peak hours and implementing 12 h of above-ground high-pressure syngas storage significantly increases the ROI and net present value. Storage lowers the carbon price at which IGCC enters the U.S. generation mix by approximately 25%. 36 refs., 7 figs., 1 tab.

Adam Newcomer; Jay Apt [Carnegie Mellon University, Pittsburgh, PA (USA). Carnegie Mellon Electricity Industry Center

2007-12-15T23:59:59.000Z

438

DOE Hydrogen Analysis Repository: Gasification-Based Fuels and Electricity  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification-Based Fuels and Electricity Production from Biomass Gasification-Based Fuels and Electricity Production from Biomass Project Summary Full Title: Gasification-Based Fuels and Electricity Production from Biomass, without and with Carbon Capture and Storage Project ID: 226 Principal Investigator: Eric D. Larson Keywords: Biomass; Fischer Tropsch; hydrogen Purpose Develop and analyze process designs for gasification-based thermochemical conversion of switchgrass into Fischer-Tropsch (F-T) fuels, dimethyl ether (DME), and hydrogen. All process designs will have some level of co-production of electricity, and some will include capture of byproduct CO2 for underground storage. Performer Principal Investigator: Eric D. Larson Organization: Princeton University Telephone: 609-258-4966 Email: elarson@princeton.edu

439

Hybrid Combustion-Gasification Chemical Looping Coal Power Technology Development  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Gasification Technologies contacts Gary J. stiegel Gasification Technology Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-4499 gary.stiegel@netl.doe.gov Ronald Breault Project Manager National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507 304-285-4486 ronald.breault@netl.doe.gov Herbert E. andrus, Jr. Principal Investigator ALSTOM Power 2000 Day Hill Rd. Windsor, CT 06095 860-285-4770 herbert.e.andrus@power.alstom.com Hybrid Combustion-GasifiCation CHemiCal loopinG Coal power teCHnoloGy development Description Gasification technologies can provide a stable, affordable energy supply for the nation, while also providing high efficiencies and near zero pollutants. With coal

440

Gasification of waste rigid polyurethane foam: optimizing operational conditions  

Science Journals Connector (OSTI)

The influence of temperature and catalyst type on production of combustible gas during the air gasification of waste rigid polyurethane foam has been...16 (43...) of three parameters was employed to optimize the...

Xiaoya Guo; Lixin Wang; Shouguang Li…

2014-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactor integrated gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Demonstration of Black Liquor Gasification at Big Island  

SciTech Connect

This Final Technical Report provides an account of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific LLC's Big Island, VA facility. This report covers the period from May 5, 2000 through November 30, 2006.

Robert DeCarrera

2007-04-14T23:59:59.000Z

442

Biomass Gasification for Electricity and Fuels , Large Scale  

Science Journals Connector (OSTI)

It is commonly agreed that gasification of biomass has a large potential for a more sustainable energy system in the future. However, a lot of research and demonstration efforts have been carried out during t...

Dr. Hermann Hofbauer

2012-01-01T23:59:59.000Z

443

Biomass Gasification for Electricity and Fuels , Large Scale  

Science Journals Connector (OSTI)

It is commonly agreed that gasification of biomass has a large potential for a more sustainable energy system in the future. However, a lot of research and demonstration efforts have been carried out during t...

Dr. Hermann Hofbauer

2013-01-01T23:59:59.000Z

444

Thermodynamic Analysis of the Supercritical Water Gasification of Biomass  

Science Journals Connector (OSTI)

The focus here is on biomass-water reacting system. The reaction process (gasification) is aimed at producing a syngas rich in combustible species, such as H2, CH4 and CO. According to the syngas final use (burner

Luca Fiori; Daniele Castello

2014-01-01T23:59:59.000Z

445

Gasification characteristics and kinetics for an eastern oil shale  

SciTech Connect

Gasification tests of Indiana New Albany oil shale fines have been conducted. Thermobalance test results indicate that over 95% of the organic carbon in the shale can be gasified at 1700{degree}F and 135 psig with 30 minutes residence time under a synthesis gas atmosphere and at 1800{degree}F and 15 psig with 30 minutes residence time under a hydrogen/steam atmosphere. A simple kinetic expression for hydrogen/steam gasification weight loss has been developed. Weight loss has been described as the sum of the weight loss from two independent, simultaneous reaction paths: a rapid (<2 minutes) first order reaction and a slower gasification reaction that can be expressed in terms of the steam/carbon reaction. Work is in progress to study the gasification of other Eastern shales and improve the kinetic description of weight loss.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-04-01T23:59:59.000Z

446

Storing Syngas Lowers the Carbon Price for Profitable Coal Gasification  

Science Journals Connector (OSTI)

There are currently eight gasification facilities operating worldwide producing about 1.7 GW of electricity from coal or petcoke feedstock (10), and in all of these facilities, the syngas is used immediately after it is produced. ...

Adam Newcomer; Jay Apt

2007-10-17T23:59:59.000Z

447

Materials Challenges for Advanced Combustion and Gasification Fossil Energy Systems  

Science Journals Connector (OSTI)

Through gasification, carbonaceous feedstock such as coal, petroleum coke (petcoke), and biomass is converted into synthesis...12–18] through, e.g., combustion or electrochemical conversion in fuel cells. Syngas ...

S. Sridhar; P. Rozzelle; B. Morreale…

2011-04-01T23:59:59.000Z

448

Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review  

Energy.gov (U.S. Department of Energy (DOE))

This independent review report assesses the 2009 state-of-the-art and 2020 projected capital cost, energy efficiency, and levelized cost for hydrogen production from biomass via gasification.

449

Wood Gasification: Where It's At, Where It's Going  

E-Print Network (OSTI)

This paper discusses the principles and practice of various designs of biomass/wood gasifiers. In general, the basic principle of gasification is reviewed. A look at existing gasifier schemes, including packed bed updraft, downdraft, and fluidized...

Murphy, M. L.

1981-01-01T23:59:59.000Z

450

Simulation of biomass gasification in a dual fluidized bed gasifier  

Science Journals Connector (OSTI)

Biomass gasification with steam in a dual-fluidized bed gasifier (DFBG) was simulated with ASPEN Plus. ... that the content of char transferred from the gasifier to the combustor decreases from 22.5...2 concentra...

Jie He; Kristina Göransson; Ulf Söderlind…

2012-03-01T23:59:59.000Z

451

Downdraft Gasification Of Various Biomass Feedstocks For Energy Production.  

E-Print Network (OSTI)

?? Gasification of biomass for energy production has the potential to be a cost effective and environmentally sustainable technology. Small scale, 20-250 kWth, downdraft gasifiers… (more)

Roesch, Hans Patric

2011-01-01T23:59:59.000Z

452

NETL: Gasification - Systems and Industry Analyses  

NLE Websites -- All DOE Office Websites (Extended Search)

E&P Technologies Gas Hydrates T&D and Refining Contacts E&P Technologies Gas Hydrates T&D and Refining Contacts Coal & Power Systems Major Demonstrations Innovations for Existing Plants Gasification Turbines Fuel Cells FutureGen Advanced Research Contacts Industrial Capture & Storage Carbon Sequestration Program Overview Core R&D Infrastructure Global Collaborations FAQs Reference Shelf Contacts Hydrogen & Clean Fuels Hydrogen-from-Coal RD&D Contacts ENERGY ANALYSIS About Us Search Products Contacts SMART GRID ANALYSIS BASELINE STUDIES NETL-RUA About NETL-RUA Research Technology Transfer Business Development Education News & Events Contacts Members Only Access TECHNOLOGY TRANSFER Available Technologies How to Partner Outreach Contacts SOLICITATIONS & BUSINESS Solicitations & Funding Opps. Related Links & Forms CDP/Financial Asst. Resources Unsolicited Proposals Available NETL Property Business Alert Notification IRS Tax Credit Program NETL Business Contacts

453

Heat exchanger for coal gasification process  

DOE Patents (OSTI)

This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

Blasiole, George A. (Greensburg, PA)

1984-06-19T23:59:59.000Z

454

Biomass Gasification Research Facility Final Report  

SciTech Connect

While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-03GO13175 and DE-FC36-02GO12024) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. This multi-year effort to develop methods to effectively monitor gaseous species produced in thermochemical process streams resulted in a sampling and analysis approach that is continuous, sensitive, comprehensive, accurate, reliable, economical, and safe. The improved approach for sampling thermochemical processes that GTI developed and demonstrated in its series of field demonstrations successfully provides continuous transport of vapor-phase syngas streams extracted from the main gasification process stream to multiple, commercially available analyzers. The syngas stream is carefully managed through multiple steps to successfully convey it to the analyzers, while at the same time bringing the stream to temperature and pressure conditions that are compatible with the analyzers. The primary principle that guides the sample transport is that throughout the entire sampling train, the temperature of the syngas stream is maintained above the maximum condensation temperature of the vapor phase components of the conveyed sample gas. In addition, to minimize adsorption or chemical changes in the syngas components prior to analysis, the temperature of the transported stream is maintained as hot as is practical, while still being cooled only as much necessary prior to entering the analyzer(s). The successful transport of the sample gas stream to the analyzer(s) is accomplished through the managed combination of four basic gas conditioning methods that are applied as specifically called for by the process conditions, the gas constituent concentrations, the analyzer requirements, and the objectives of the syngas analyses: 1) removing entrained particulate matter from the sample stream; 2) maintaining the temperature of the sample gas stream; 3) lowering the pressure of the sample gas stream to decrease the vapor pressures of all the component vapor species in the sample stream; and 4) diluting the gas stream with a metered, inert gas, such as nitrogen. Proof-of-concept field demonstrations of the sampling approach were conducted for gasification process streams from a black liquor gasifier, and from the gasification of biomass and coal feedstocks at GTI’s Flex-Fuel Test Facility. In addition to the descriptions and data included in this Final Report, GTI produced a Special Topical Report, Design and Protocol for Monitoring Gaseous Species in Thermochemical Processes, that explains and describes in detail the objectives, principles, design, hardware, installation, operation and representative data produced during this successful developmental effort. Although the specific analyzers used under Cooperative Agreement DE-FC36-02GO12024 were referenced in the Topical Report and this Final Report, the sampling interface design they present is generic enough to adapt to other analyzers that may be more appropriate to alternate process streams or facilities.

Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

2007-09-30T23:59:59.000Z

455

Advanced Gasification By-Product Utilization  

SciTech Connect

With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this collaborative effort between the University of Kentucky Center for Applied Energy Research (CAER), The Pennsylvania State University Energy Institute, and industry collaborators supplying gasifier char samples were to investigate the potential use of gasifier slag carbons as a source of low cost sorbent for Hg and NOX capture from combustion flue gas, concrete applications, polymer fillers and as a source of activated carbons. Primary objectives were to determine the relationship of surface area, pore size, pore size distribution, and mineral content on Hg storage of gasifier carbons and to define the site of Hg capture. The ability of gasifier slag carbon to capture NOX and the effect of NOX on Hg adsorption were goals. Secondary goals were the determination of the potential for use of the slags for cement and filler applications. Since gasifier chars have already gone through a devolatilization process in a reducing atmosphere in the gasifier, they only required to be activated to be used as activated carbons. Therefore, the principal objective of the work at PSU was to characterize and utilize gasification slag carbons for the production of activated carbons and other carbon fillers. Tests for the Hg and NOX adsorption potential of these activated gasifier carbons were performed at the CAER. During the course of this project, gasifier slag samples chemically and physically characterized at UK were supplied to PSU who also characterized the samples for sorption characteristics and independently tested for Hg-capture. At the CAER as-received slags were tested for Hg and NOX adsorption. The most promising of these were activated chemically. The PSU group applied thermal and steam activation to a representative group of the gasifier slag samples separated by particle sizes. The activated samples were tested at UK for Hg-sorption and NOX capture and the most promising Hg adsorbers were tested for Hg capture in a simulated flue gas. Both UK and PSU tested the use of the gasifier slag samples as fillers. The CAER analyzed the slags for possible use in cement applications

Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

2006-08-31T23:59:59.000Z

456

NETL: Gasification Systems - Conversion and Fouling  

NLE Websites -- All DOE Office Websites (Extended Search)

Conversion and Fouling Conversion and Fouling NETL Office of Research and Development Project Number: FWP-2012.03.03 Task 3 Project Description The objective for this NETL in-house conversion and fouling project is to improve the reliability, availability and maintainability (RAM) of gasification plants by providing tools that can be used to evaluate the impact that fuel properties have on slag and refractory interaction, and to reduce plugging and fouling throughout the syngas cooling system. Utilizing these tools will aid in minimizing plugging and fouling-increasing overall plant efficiency due to improved heat transfer in heat exchangers. Particle deposition experimental schematic Particle deposition experimental schematic (click to enlarge) Project Details Program Background and Project Benefits

457

Material Characterization and Analysis for Selection of Refractories Used in Black Liquor Gasification  

SciTech Connect

Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials such as the refractory lining of the reactor vessel have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, an updated summary of the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for both the hot-face and back-up linings used in this application.

Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

2010-01-01T23:59:59.000Z

458

Analysis and comparison of biomass pyrolysis/gasification condensates: Final report  

SciTech Connect

This report provides results of chemical and physical analysis of condensates from eleven biomass gasification and pyrolysis systems. The samples were representative of the various reactor configurations being researched within the Department of Energy, Biomass Thermochemical Conversion program. The condensates included tar phases and aqueous phases. The analyses included gross compositional analysis (elemental analysis, ash, moisture), physical characterization (pour point, viscosity, density, heat of combustion, distillation), specific chemical analysis (gas chromatography/mass spectrometry, infrared spectrophotometry, proton and carbon-13 nuclear magnetic resonance spectrometry) and biological activity (Ames assay and mouse skin tumorigenicity tests). These results are the first step of a longer term program to determine the properties, handling requirements, and utility of the condensates recovered from biomass gasification and pyrolysis. The analytical data demonstrates the wide range of chemical composition of the organics recovered in the condensates and suggests a direct relationship between operating temperature and chemical composition of the condensates. A continuous pathway of thermal degradation of the tar components as a function of temperature is proposed. Variations in the chemical composition of the organic components in the tars are reflected in the physical properties of tars and phase stability in relation to water in the condensate. The biological activity appears to be limited to the tars produced at high temperatures. 56 refs., 25 figs., 21 tabs.

Elliott, D.C.

1986-06-01T23:59:59.000Z