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1

Advancing Reactive Tracer Methods for Measuring Thermal Evolution...  

Open Energy Info (EERE)

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Geothermal Lab Call Project Jump to: navigation, search Last...

2

Advancing reactive tracer methods for measuring thermal evolution...  

Broader source: Energy.gov (indexed) [DOE]

Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Quantum Dot Tracers for Use in...

3

Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. This project aims to develop reactive tracer method for monitoring thermal drawdown in enhanced geothermal systems.

4

ADVANCING REACTIVE TRACER METHODS FOR MONITORING THERMAL DRAWDOWN IN GEOTHERMAL ENHANCED GEOTHERMAL RESERVOIRS  

SciTech Connect (OSTI)

Reactive tracers have long been considered a possible means of measuring thermal drawdown in a geothermal system, before significant cooling occurs at the extraction well. Here, we examine the sensitivity of the proposed method to evaluate reservoir cooling and demonstrate that while the sensitivity of the method as generally proposed is low, it may be practical under certain conditions.

Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; George D. Redden; Laurence C. Hull

2010-10-01T23:59:59.000Z

5

Advancing Reactive Tracer Methods for Measurement of Thermal Evolution in Geothermal Reservoirs: Final Report  

SciTech Connect (OSTI)

The injection of cold fluids into engineered geothermal system (EGS) and conventional geothermal reservoirs may be done to help extract heat from the subsurface or to maintain pressures within the reservoir (e.g., Rose et al., 2001). As these injected fluids move along fractures, they acquire heat from the rock matrix and remove it from the reservoir as they are extracted to the surface. A consequence of such injection is the migration of a cold-fluid front through the reservoir (Figure 1) that could eventually reach the production well and result in the lowering of the temperature of the produced fluids (thermal breakthrough). Efficient operation of an EGS as well as conventional geothermal systems involving cold-fluid injection requires accurate and timely information about thermal depletion of the reservoir in response to operation. In particular, accurate predictions of the time to thermal breakthrough and subsequent rate of thermal drawdown are necessary for reservoir management, design of fracture stimulation and well drilling programs, and forecasting of economic return. A potential method for estimating migration of a cold front between an injection well and a production well is through application of reactive tracer tests, using chemical whose rate of degradation is dependent on the reservoir temperature between the two wells (e.g., Robinson 1985). With repeated tests, the rate of migration of the thermal front can be determined, and the time to thermal breakthrough calculated. While the basic theory behind the concept of thermal tracers has been understood for some time, effective application of the method has yet to be demonstrated. This report describes results of a study that used several methods to investigate application of reactive tracers to monitoring the thermal evolution of a geothermal reservoir. These methods included (1) mathematical investigation of the sensitivity of known and hypothetical reactive tracers, (2) laboratory testing of novel tracers that would improve method sensitivity, (3) development of a software tool for design and interpretation of reactive tracer tests and (4) field testing of the reactive tracer temperature monitoring concept.

Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; Laurence C. Hull; George D. Redden

2011-07-01T23:59:59.000Z

6

Biological tracer method  

DOE Patents [OSTI]

The present invention is a biological tracer method for characterizing the movement of a material through a medium, comprising the steps of: introducing a biological tracer comprising a microorganism having ice nucleating activity into a medium; collecting at least one sample of the medium from a point removed from the introduction point; and analyzing the sample for the presence of the biological tracer. The present invention is also a method for using a biological tracer as a label for material identification by introducing a biological tracer having ice nucleating activity into a material, collecting a sample of a portion of the labelled material and analyzing the sample for the presence of the biological tracer. 2 figs.

Strong-Gunderson, J.M.; Palumbo, A.V.

1998-09-15T23:59:59.000Z

7

Biological tracer method  

DOE Patents [OSTI]

The present invention is a biological tracer method for characterizing the movement of a material through a medium, comprising the steps of: introducing a biological tracer comprising a microorganism having ice nucleating activity into a medium; collecting at least one sample of the medium from a point removed from the introduction point; and analyzing the sample for the presence of the biological tracer. The present invention is also a method for using a biological tracer as a label for material identification by introducing a biological tracer having ice nucleating activity into a material, collecting a sample of a portion of the labelled material and analyzing the sample for the presence of the biological tracer.

Strong-Gunderson, Janet M. (Ten Mile, TN); Palumbo, Anthony V. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

8

Tracking thermal fronts with temperature-sensitive, chemically reactive tracers  

SciTech Connect (OSTI)

Los Alamos is developing tracer techniques using reactive chemicals to track thermal fronts in fractured geothermal reservoirs. If a nonadsorbing tracer flowing from the injection to production well chemically reacts, its reaction rate will be a strong function of temperature. Thus the extent of chemical reaction will be greatest early in the lifetime of the system, and less as the thermal front progresses from the injection to production well. Early laboratory experiments identified tracers with chemical kinetics suitable for reservoirs in the temperature range of 75 to 100/sup 0/C. Recent kinetics studies have focused on the kinetics of hydrolysis of derivatives of bromobenzene. This class of reactions can be used in reservoirs ranging in temperature from 150 to 275/sup 0/C, which is of greater interest to the geothermal industry. Future studies will include laboratory adsorption experiments to identify possibly unwanted adsorption on granite, development of sensitive analytical techniques, and a field demonstration of the reactive tracer concept.

Robinson, B.A.; Birdsell, S.A.

1987-01-01T23:59:59.000Z

9

Tracers and Tracer Testing: Design, Implementation, Tracer Selection, and Interpretation Methods  

SciTech Connect (OSTI)

Conducting a successful tracer test requires adhering to a set of steps. The steps include identifying appropriate and achievable test goals, identifying tracers with the appropriate properties, and implementing the test as designed. When these steps are taken correctly, a host of tracer test analysis methods are available to the practitioner. This report discusses the individual steps required for a successful tracer test and presents methods for analysis. The report is an overview of tracer technology; the Suggested Reading section offers references to the specifics of test design and interpretation.

G. Michael Shook; Shannon L.; Allan Wylie

2004-01-01T23:59:59.000Z

10

Tracer Methods for Characterizing Fracture Stimulation in Engineered...  

Broader source: Energy.gov (indexed) [DOE]

Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS) Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal...

11

Tracer Methods for Characterizing Fracture Creation in Enhanced...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing Fracture...

12

Tracer Methods for Characterizing Fracture Stimulation in Enhanced...  

Broader source: Energy.gov (indexed) [DOE]

Tracer Methods for Characterizing Fracture Stimulation in Enhanced Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing...

13

Diagnostic Implications of the Reactivity of Fluorescence Tracers  

SciTech Connect (OSTI)

Measurements of fuel concentration distributions with planar laser induced fluorescence of tracer molecules that are added to a base fuel are commonly used in combustion research and development. It usually is assumed that the tracer concentration follows the parent fuel concentration if physical properties such as those determining evaporation are matched. As an example to address this general issue a computational study of combustion of biacetyl/iso-octane mixtures was performed to investigate how well the concentration of biacetyl represents the concentration of iso-octane. For premixed mixture conditions with flame propagation the spatial concentration profiles of the two species in the flame front are separated by 110 {micro}m at 1 bar and by 11 {micro}m at 10 bar. For practical applications this spatial separation is insignificantly small. However, for conditions that mimic ignition and combustion in diesel and HCCI-like operation the differences in tracer and fuel concentration can be significant, exceeding hundreds of percent. At low initial temperature biacetyl was found to be more stable whereas at higher temperature (>1000K) iso-octane is more stable. Similar findings were obtained for a multi-component fuel comprised of iso-octane, n-heptane, methylcyclohexane, and toluene. It may be assumed that similar differences can exist for other tracer/fuel combinations. Caution has therefore to be applied when interpreting PLIF measurements in homogeneous reaction conditions such as in HCCI engine studies.

Sick, V; Westbrook, C

2008-07-14T23:59:59.000Z

14

Tracer Methods for Characterizing Fracture Stimulation in Enhanced...  

Broader source: Energy.gov (indexed) [DOE]

80 4.6.7 Tracer Methods for Characterizing Fracture Stimulation in Enhanced Geothermal Systems (EGS) Presentation Number: 034 Investigator: Pruess, Karsten (Lawrence Berkeley...

15

Tracer Methods for Characterizing Fracture Stimulation in Engineered...  

Broader source: Energy.gov (indexed) [DOE]

Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS) Karsten Pruess Lawrence Berkeley National Lab. May 19, 2010 This presentation does not...

16

Method of dispersing particulate aerosol tracer  

DOE Patents [OSTI]

A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

O'Holleran, Thomas P. (Belleville, MI)

1988-01-01T23:59:59.000Z

17

Methods and systems using encapsulated tracers and chemicals for reservoir interrogation and manipulation  

DOE Patents [OSTI]

An apparatus, method, and system of reservoir interrogation. A tracer is encapsulating in a receptacle. The receptacle containing the tracer is injected into the reservoir. The tracer is analyzed for reservoir interrogation.

Roberts, Jeffery; Aines, Roger D; Duoss, Eric B; Spadaccini, Christopher M

2014-11-04T23:59:59.000Z

18

Semianalytical Solutions of Radioactive or Reactive Tracer Transport in Layered Fractured Media  

SciTech Connect (OSTI)

In this paper, semianalytical solutions are developed for the problem of transport of radioactive or reactive tracers (solutes or colloids) through a layered system of heterogeneous fractured media with misaligned fractures. The tracer transport equations in the matrix account for (a) diffusion, (b) surface diffusion (for solutes only), (c) mass transfer between the mobile and immobile water fractions, (d) linear kinetic or equilibrium physical, chemical, or combined solute sorption or colloid filtration, and (e) radioactive decay or first order chemical reactions. Any number of radioactive decay daughter products (or products of a linear, first-order reaction chain) can be tracked. The tracer-transport equations in the fractures account for the same processes, in addition to advection and hydrodynamic dispersion. Additionally, the colloid transport equations account for straining and velocity adjustments related to the colloidal size. The solutions, which are analytical in the Laplace space, are numerically inverted to provide the solution in time and can accommodate any number of fractured and/or porous layers. The solutions are verified using analytical solutions for limiting cases of solute and colloid transport through fractured and porous media. The effect of important parameters on the transport of {sup 3}H, {sup 237}Np and {sup 239}Pu (and its daughters) is investigated in several test problems involving layered geological systems of varying complexity. {sup 239}Pu colloid transport problems in multilayered systems indicate significant colloid accumulations at straining interfaces but much faster transport of the colloid than the corresponding strongly sorbing solute species.

G.J. Moridis; G. S. Bodvarsson

2001-10-01T23:59:59.000Z

19

QUANTIFICATION OF FUGITIVE REACTIVE ALKENE EMISSIONS FROM PETROCHEMICAL PLANTS WITH PERFLUOROCARBON TRACERS.  

SciTech Connect (OSTI)

Recent studies demonstrate the impact of fugitive emissions of reactive alkenes on the atmospheric chemistry of the Houston Texas metropolitan area (1). Petrochemical plants located in and around the Houston area emit atmospheric alkenes, such as ethene, propene and 1,3-butadiene. The magnitude of emissions is a major uncertainty in assessing their effects. Even though the petrochemical industry reports that fugitive emissions of alkenes have been reduced to less than 0.1% of daily production, recent measurement data, obtained during the TexAQS 2000 experiment indicates that emissions are perhaps a factor of ten larger than estimated values. Industry figures for fugitive emissions are based on adding up estimated emission factors for every component in the plant to give a total estimated emission from the entire facility. The dramatic difference between estimated and measured rates indicates either that calculating emission fluxes by summing estimates for individual components is seriously flawed, possibly due to individual components leaking well beyond their estimated tolerances, that not all sources of emissions for a facility are being considered in emissions estimates, or that there are known sources of emissions that are not being reported. This experiment was designed to confirm estimates of reactive alkene emissions derived from analysis of the TexAQS 2000 data by releasing perfluorocarbon tracers (PFTs) at a known flux from a petrochemical plant and sampling both the perfluorocarbon tracer and reactive alkenes downwind using the Piper-Aztec research aircraft operated by Baylor University. PFTs have been extensively used to determine leaks in pipelines, air infiltration in buildings, and to characterize the transport and dispersion of air parcels in the atmosphere. Over 20 years of development by the Tracer Technology Center (TTC) has produced a range of analysis instruments, field samplers and PFT release equipment that have been successfully deployed in a large variety of experiments. PFTs are inert, nontoxic, noncombustible and nonreactive. Up to seven unique PFTs can be simultaneously released, sampled and analyzed and the technology is well suited for determining emission fluxes from large petrochemical facilities. The PFT experiment described here was designed to quantitate alkene emissions from a single petrochemical facility, but such experiments could be applied to other industrial sources or groups of sources in the Houston area.

SENUM,G.I.; DIETZ,R.N.

2004-06-30T23:59:59.000Z

20

Validation of Geothermal Tracer Methods in Highly Constrained...  

Broader source: Energy.gov (indexed) [DOE]

of Research Hypothesis: Smart tracers can measure potential heat exchange between fracture and rock mass Hypothesis Test: A tracer test proving ground System must be simple...

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts  

DOE Patents [OSTI]

A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Anderson, Raymond P. (Idaho Falls, ID)

2008-08-05T23:59:59.000Z

22

Validation of Geothermal Tracer Methods in Highly Constrained Field Experiments  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Project Summary. This project will test smartdiffusive tracers for measuring heat exchange.

23

Advancing reactive tracer methods for measuring thermal evolution...  

Broader source: Energy.gov (indexed) [DOE]

et al. (2003) - Use simplified geometry of hypothetical fracture system - Develop in MATLAB, to allow distribution to industry via the MATLAB compiler * Conducted 2-D finite...

24

Verification of Geothermal Tracer Methods in Highly Constrained...  

Open Energy Info (EERE)

tracers of varying rates of molecular diffusion. Exchange of heat energy between fracture and bulk rock (matrix) behaves in the same manner as the exchange of dissolved mass....

25

Preliminary Investigation of Tracer Gas Reaeration Method for Shallow Bays  

E-Print Network [OSTI]

was used with propane for the tracer gas and Rhodamine-WT, a fluorescent dye, for the "conservative" tracer. The propane was injected through porous tile diffusers, and the dye was released simultaneously. The propane acts as a model for the surface...

Baker, Sarah H.; Holley, Edward R.

26

THE NEW YORK CITY URBAN DISPERSION PROGRAM MARCH 2005 FIELD STUDY: TRACER METHODS AND RESULTS.  

SciTech Connect (OSTI)

The Urban Dispersion Program March 2005 Field Study tracer releases, sampling, and analytical methods are described in detail. There were two days where tracer releases and sampling were conducted. A total of 16.0 g of six tracers were released during the first test day or Intensive Observation Period (IOP) 1 and 15.7 g during IOP 2. Three types of sampling instruments were used in this study. Sequential air samplers, or SAS, collected six-minute samples, while Brookhaven atmospheric tracer samplers (BATS) and personal air samplers (PAS) collected thirty-minute samples. There were a total of 1300 samples resulting from the two IOPs. Confidence limits in the sampling and analysis method were 20% as determined from 100 duplicate samples. The sample recovery rate was 84%. The integrally averaged 6-minute samples were compared to the 30-minute samples. The agreement was found to be good in most cases. The validity of using a background tracer to calculate sample volumes was examined and also found to have a confidence level of 20%. Methods for improving sampling and analysis are discussed. The data described in this report are available as Excel files. An additional Excel file of quality assured tracer data for use in model validation efforts is also available. The file consists of extensively quality assured BATS tracer data with background concentrations subtracted.

WATSON, T.B.; HEISER, J.; KALB, P.; DIETZ, R.N.; WILKE, R.; WIESER, R.; VIGNATO, G.

2005-10-01T23:59:59.000Z

27

Reactive ion etched substrates and methods of making and using  

DOE Patents [OSTI]

Disclosed herein are substrates comprising reactive ion etched surfaces and specific binding agents immobilized thereon. The substrates may be used in methods and devices for assaying or isolating analytes in a sample. Also disclosed are methods of making the reactive ion etched surfaces.

Rucker, Victor C. (San Francisco, CA); Shediac, Rene (Oakland, CA); Simmons, Blake A. (San Francisco, CA); Havenstrite, Karen L. (New York, NY)

2007-08-07T23:59:59.000Z

28

Validation of Geothermal Tracer Methods in Highly Constrained...  

Broader source: Energy.gov (indexed) [DOE]

methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs Fracture Evolution Following a Hydraulic Stimulation within an EGS Reservoir Quantum Dot...

29

Perfluorocarbon tracer method for air-infiltration measurements  

DOE Patents [OSTI]

A method of measuring air infiltration rates suitable for use in rooms of homes and buildings comprises the steps of emitting perfluorocarbons in the room to be measured, sampling the air containing the emitted perfluorocarbons over a period of time, and analyzing the samples at a laboratory or other facility.

Dietz, R.N.

1982-09-23T23:59:59.000Z

30

Uncertainties in Air Exchange using Continuous-Injection, Long-Term Sampling Tracer-Gas Methods  

SciTech Connect (OSTI)

The PerFluorocarbon Tracer (PFT) method is a low-cost approach commonly used for measuring air exchange in buildings using tracer gases. It is a specific application of the more general Continuous-Injection, Long-Term Sampling (CILTS) method. The technique is widely used but there has been little work on understanding the uncertainties (both precision and bias) associated with its use, particularly given that it is typically deployed by untrained or lightly trained people to minimize experimental costs. In this article we will conduct a first-principles error analysis to estimate the uncertainties and then compare that analysis to CILTS measurements that were over-sampled, through the use of multiple tracers and emitter and sampler distribution patterns, in three houses. We find that the CILTS method can have an overall uncertainty of 10-15percent in ideal circumstances, but that even in highly controlled field experiments done by trained experimenters expected uncertainties are about 20percent. In addition, there are many field conditions (such as open windows) where CILTS is not likely to provide any quantitative data. Even avoiding the worst situations of assumption violations CILTS should be considered as having a something like a ?factor of two? uncertainty for the broad field trials that it is typically used in. We provide guidance on how to deploy CILTS and design the experiment to minimize uncertainties.

Sherman, Max H.; Walker, Iain S.; Lunden, Melissa M.

2013-12-01T23:59:59.000Z

31

Environmentally stable reactive alloy powders and method of making same  

DOE Patents [OSTI]

Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

1998-09-22T23:59:59.000Z

32

Potential method for measurement of CO2 leakage from underground sequestration fields using radioactive tracers  

SciTech Connect (OSTI)

Reduction of anthropogenic carbon dioxide (CO2) release to the environment is a pressing challenge that should be addressed to avert the potential devastating effects of global warming. Within the United States, the most abundant sources of CO2 emissions are those generate from coal- or gas-fired power plants; one method to control CO2 emissions is to sequester it in deep underground geological formations. From integrated assessment models the overall leakage rates from these storage locations must be less than 0.1% of stored volume per year for long-term control. The ability to detect and characterize nascent leaks, in conjunction with subsequent remediation efforts, will significantly decrease the amount of CO2 released back into the environment. Because potential leakage pathways are not necessarily known a priori, onsite monitoring must be performed; the monitoring region in the vicinity of a CO2 injection well may be as large as 100 km2, which represents the estimated size of a supercritical CO2 bubble that would form under typical injection scenarios. By spiking the injected CO2 with a radiological or stable isotope tracer, it will be possible to detect ground leaks from the sequestered CO2 using fewer sampling stations, with greater accuracy than would be possible using simple CO2 sensors. The relative merits of various sorbent materials, radiological and stable isotope tracers, detection methods and potential interferences will be discussed.

Bachelor, Paula P.; McIntyre, Justin I.; Amonette, James E.; Hayes, James C.; Milbrath, Brian D.; Saripalli, Prasad

2008-07-01T23:59:59.000Z

33

Parallel computation of multigroup reactivity coefficient using iterative method  

SciTech Connect (OSTI)

One of the research activities to support the commercial radioisotope production program is a safety research target irradiation FPM (Fission Product Molybdenum). FPM targets form a tube made of stainless steel in which the nuclear degrees of superimposed high-enriched uranium. FPM irradiation tube is intended to obtain fission. The fission material widely used in the form of kits in the world of nuclear medicine. Irradiation FPM tube reactor core would interfere with performance. One of the disorders comes from changes in flux or reactivity. It is necessary to study a method for calculating safety terrace ongoing configuration changes during the life of the reactor, making the code faster became an absolute necessity. Neutron safety margin for the research reactor can be reused without modification to the calculation of the reactivity of the reactor, so that is an advantage of using perturbation method. The criticality and flux in multigroup diffusion model was calculate at various irradiation positions in some uranium content. This model has a complex computation. Several parallel algorithms with iterative method have been developed for the sparse and big matrix solution. The Black-Red Gauss Seidel Iteration and the power iteration parallel method can be used to solve multigroup diffusion equation system and calculated the criticality and reactivity coeficient. This research was developed code for reactivity calculation which used one of safety analysis with parallel processing. It can be done more quickly and efficiently by utilizing the parallel processing in the multicore computer. This code was applied for the safety limits calculation of irradiated targets FPM with increment Uranium.

Susmikanti, Mike [Center for Development of Nuclear Informatics, National Nuclear Energy Agency of Indonesia PUSPIPTEK Area, Tangerang (Indonesia)] [Center for Development of Nuclear Informatics, National Nuclear Energy Agency of Indonesia PUSPIPTEK Area, Tangerang (Indonesia); Dewayatna, Winter [Center for Nuclear Fuel Technology, National Nuclear Energy Agency of Indonesia PUSPIPTEK Area, Tangerang (Indonesia)] [Center for Nuclear Fuel Technology, National Nuclear Energy Agency of Indonesia PUSPIPTEK Area, Tangerang (Indonesia)

2013-09-09T23:59:59.000Z

34

Method for preparing hydride configurations and reactive metal surfaces  

DOE Patents [OSTI]

A method for preparing highly hydrogen-reactive surfaces on metals which normally require substantial heating, high pressures, or an extended induction period, which involves pretreatment of said surfaces with either a non-oxidizing acid or hydrogen gas to form a hydrogen-bearing coating on said surfaces, and subsequently heating said coated metal in the absence of moisture and oxygen for a period sufficient to decompose said coating and cooling said metal to room temperature. Surfaces so treated will react almost instantaneously with hydrogen gas at room temperature and low pressure. The method is particularly applicable to uranium, thorium, and lanthanide metals.

Silver, Gary L. (Centerville, OH)

1988-08-16T23:59:59.000Z

35

Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same  

DOE Patents [OSTI]

An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

Fritz, Gregory M; Knepper, Robert Allen; Weihs, Timothy P; Gash, Alexander E; Sze, John S

2013-04-30T23:59:59.000Z

36

Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS)  

Broader source: Energy.gov [DOE]

Project objectives: identify tracers with sorption properties favorable for EGS applications; apply reversibly sorbing tracers to determine the fracture-matrix interface area available for heat transfer; and; explore the feasibility of obtaining fracture-matrix interface area from non-isothermal; single-well injection-withdrawal (SWIW) tests.

37

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

Many contaminated areas consist of a source area and a plume. In the source area, the contaminant moves vertically downward from a release point through the vadose zone to an underlying saturated region. Where contaminants are organic liquids, NAPL may accumulate on the water table, or it may continue to migrate downward through the saturated region. Early developments of permeable barrier technology have focused on intercepting horizontally moving plumes with vertical structures, such as trenches, filled with reactive material capable of immobilizing or degrading dissolved contaminants. This focus resulted in part from a need to economically treat the potentially large volumes of contaminated water in a plume, and in part from the availability of construction technology to create the vertical structures that could house reactive compounds. Contaminant source areas, however, have thus far remained largely excluded from the application of permeable barrier technology. One reason for this is the lack of conventional construction methods for creating suitable horizontal structures that would place reactive materials in the path of downward-moving contaminants. Methods of hydraulic fracturing have been widely used to create flat-lying to gently dipping layers of granular material in unconsolidated sediments. Most applications thus far have involved filling fractures with coarse-grained sand to create permeable layers that will increase the discharge of wells recovering contaminated water or vapor. However, it is possible to fill fractures with other compounds that alter the chemical composition of the subsurface. One early application involved development and field testing micro-encapsulated sodium percarbonate, a solid compound that releases oxygen and can create aerobic conditions suitable for biodegradation in the subsurface for several months.

Murdoch, L. [FRx Inc., Cincinnati, OH (United States); [Clemson Univ., SC (United States); Siegrist, B. [Oak Ridge National Lab., TN (United States); Vesper, S. [Univ. of Cincinnati, OH (United States)] [and others

1997-12-31T23:59:59.000Z

38

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2-  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 SouthWaterBrasil Jump to:IowaResource Evaluation And Reservoir Management

39

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

40

Method of measuring reactive acoustic power density in a fluid  

DOE Patents [OSTI]

A method for determining reactive acoustic power density level and its direction in a fluid using a single sensor is disclosed. In the preferred embodiment, an apparatus for conducting the method, which is termed a thermoacoustic couple, consists of a stack of thin, spaced apart polymeric plates, selected ones of which include multiple bimetallic thermocouple junctions positioned along opposite end edges thereof. The thermocouple junctions are connected in series in the nature of a thermopile, and are arranged so as to be responsive to small temperature differences between the opposite edges of the plates. The magnitude of the temperature difference, as represented by the magnitude of the electrical potential difference generated by the thermopile, is found to be directly related to the level of acoustic power density in the gas. 5 figs.

Wheatley, J.C.; Swift, G.W.; Migliori, A.

1985-09-03T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Evaluation of Methods to Predict Reactivity of Gold Nanoparticles...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

relationship to the concept of frontier molecular orbital theory. The d-band theory of Hammer and Nřrskov is perhaps the most widely used predictor of reactivity on metallic...

42

Survey of Reactive Power Planning Methods Wenjuan Zhang, Student Member, IEEE, Leon M. Tolbert, Senior Member, IEEE  

E-Print Network [OSTI]

Survey of Reactive Power Planning Methods Wenjuan Zhang, Student Member, IEEE, Leon M. Tolbert, Senior Member, IEEE Abstract Reactive power planning (RPP) involves optimal allocation and determination to solve the RPP problem. Index Terms -- reactive power planning, reactive power optimization, optimal

Tolbert, Leon M.

43

Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity  

DOE Patents [OSTI]

A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime (about 40 ps), high frequency (about 5G hz), high power bursts of low-duty factor microwaves sufficient to generate a dielectric barrier discharge and passing a gas to treated through the discharge so as to cause dissociative reduction of the exhaust gases. The invention also includes a reactor for generating the non-thermal plasma.

Whealton, John H. (Oak Ridge, TN); Hanson, Gregory R. (Clinton, TN); Storey, John M. (Oak Ridge, TN); Raridon, Richard J. (Oak Ridge, TN); Armfield, Jeffrey S. (Upsilanti, MI); Bigelow, Timothy S. (Knoxville, TN); Graves, Ronald L. (Knoxville, TN)

2001-01-01T23:59:59.000Z

44

Uncertainties in Air Exchange using Continuous-Injection, Long-Term Sampling Tracer-Gas Methods  

E-Print Network [OSTI]

Pollutant Control Index: A New Method of Characterizing Ventilation in Commercial Buildings." Proceedings of Indoor Air'

Sherman, Max H.

2014-01-01T23:59:59.000Z

45

Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure Ventilation Rates in Homes  

E-Print Network [OSTI]

Pollutant Control Index: A New Method of Characterizing Ventilation in Commercial Buildings." Proceedings of Indoor Air'

Lunden, Melissa

2014-01-01T23:59:59.000Z

46

Methods and apparatuses for reagent delivery, reactive barrier formation, and pest control  

DOE Patents [OSTI]

A reagent delivery method includes positioning reagent delivery tubes in contact with soil. The tubes can include a wall that is permeable to a soil-modifying reagent. The method further includes supplying the reagent in the tubes, diffusing the reagent through the permeable wall and into the soil, and chemically modifying a selected component of the soil using the reagent. The tubes can be in subsurface contact with soil, including groundwater, and can be placed with directional drilling equipment independent of groundwater well casings. The soil-modifying reagent includes a variety of gases, liquids, colloids, and adsorbents that may be reactive or non-reactive with soil components. The method may be used inter alia to form reactive barriers, control pests, and enhance soil nutrients for microbes and plants.

Gilmore, Tyler [Pasco, WA; Kaplan, Daniel I [Aiken, SC; Last, George [Richland, WA

2002-07-09T23:59:59.000Z

47

The semismooth Newton method for multicomponent reactive transport with minerals  

E-Print Network [OSTI]

is that problems containing CCs (so-called complementarity problems, CPs) are well known in the field of optimization theory. In this field, it is a well known strategy to solve CPs with the semismooth Newton method essential. The article is structured as follows. In Sec. 2.1 we introduce the mineral precipitation

Kraeutle, Serge

48

Evaluation of Methods to Predict Reactivity of Gold Nanoparticles. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicy and Assistance100 ton StanatAccepted|theEvaluation ofMethods to

49

Tracer airflow measurement system (TRAMS)  

DOE Patents [OSTI]

A method and apparatus for measuring fluid flow in a duct is disclosed. The invention uses a novel high velocity tracer injector system, an optional insertable folding mixing fan for homogenizing the tracer within the duct bulk fluid flow, and a perforated hose sampling system. A preferred embodiment uses CO.sub.2 as a tracer gas for measuring air flow in commercial and/or residential ducts. In extant commercial buildings, ducts not readily accessible by hanging ceilings may be drilled with readily plugged small diameter holes to allow for injection, optional mixing where desired using a novel insertable foldable mixing fan, and sampling hose.

Wang, Duo (Albany, CA)

2007-04-24T23:59:59.000Z

50

Apparatus and method for atmospheric pressure reactive atom plasma processing for shaping of damage free surfaces  

DOE Patents [OSTI]

Fabrication apparatus and methods are disclosed for shaping and finishing difficult materials with no subsurface damage. The apparatus and methods use an atmospheric pressure mixed gas plasma discharge as a sub-aperture polisher of, for example, fused silica and single crystal silicon, silicon carbide and other materials. In one example, workpiece material is removed at the atomic level through reaction with fluorine atoms. In this example, these reactive species are produced by a noble gas plasma from trace constituent fluorocarbons or other fluorine containing gases added to the host argon matrix. The products of the reaction are gas phase compounds that flow from the surface of the workpiece, exposing fresh material to the etchant without condensation and redeposition on the newly created surface. The discharge provides a stable and predictable distribution of reactive species permitting the generation of a predetermined surface by translating the plasma across the workpiece along a calculated path.

Carr; Jeffrey W. (Livermore, CA)

2009-03-31T23:59:59.000Z

51

Abstract--This paper proposes an optimization based method of planning reactive power control for electric transmission  

E-Print Network [OSTI]

1 Abstract--This paper proposes an optimization based method of planning reactive power control for electric transmission systems to endow them with the capability of being reconfigured to a secure planning, reactive power control, reconfiguration, voltage stability. I. INTRODUCTION PPROPRIATE long

Kumar, Ratnesh

52

GUINEVERE experiment: Kinetic analysis of some reactivity measurement methods by deterministic and Monte Carlo codes  

SciTech Connect (OSTI)

The GUINEVERE experiment (Generation of Uninterrupted Intense Neutrons at the lead Venus Reactor) is an experimental program in support of the ADS technology presently carried out at SCK-CEN in Mol (Belgium). In the experiment a modified lay-out of the original thermal VENUS critical facility is coupled to an accelerator, built by the French body CNRS in Grenoble, working in both continuous and pulsed mode and delivering 14 MeV neutrons by bombardment of deuterons on a tritium-target. The modified lay-out of the facility consists of a fast subcritical core made of 30% U-235 enriched metallic Uranium in a lead matrix. Several off-line and on-line reactivity measurement techniques will be investigated during the experimental campaign. This report is focused on the simulation by deterministic (ERANOS French code) and Monte Carlo (MCNPX US code) calculations of three reactivity measurement techniques, Slope ({alpha}-fitting), Area-ratio and Source-jerk, applied to a GUINEVERE subcritical configuration (namely SC1). The inferred reactivity, in dollar units, by the Area-ratio method shows an overall agreement between the two deterministic and Monte Carlo computational approaches, whereas the MCNPX Source-jerk results are affected by large uncertainties and allow only partial conclusions about the comparison. Finally, no particular spatial dependence of the results is observed in the case of the GUINEVERE SC1 subcritical configuration. (authors)

Bianchini, G.; Burgio, N.; Carta, M. [ENEA C.R. CASACCIA, via Anguillarese, 301, 00123 S. Maria di Galeria Roma (Italy); Peluso, V. [ENEA C.R. BOLOGNA, Via Martiri di Monte Sole, 4, 40129 Bologna (Italy); Fabrizio, V.; Ricci, L. [Univ. of Rome La Sapienza, C/o ENEA C.R. CASACCIA, via Anguillarese, 301, 00123 S. Maria di Galeria Roma (Italy)

2012-07-01T23:59:59.000Z

53

Application of Partial-Order Methods to Reactive Programs with Event Memorization  

E-Print Network [OSTI]

with event memorization. The reactive systems are specified with an asynchronous reactive language Electre, 3 (2001) 287-316" #12;2 Electre: an Asynchronous Reactive Language with Event Memorization 3 2 of a semantic model of an asyn- chronous reactive language: Electre [PRH92, CR95]. Indeed, this language

Paris-Sud XI, Université de

54

Tracer Interpretation Using Temporal Moments on a Spreadsheet  

SciTech Connect (OSTI)

This report presents a method for interpreting geothermal tracer tests. The method is based on the first temporal moment (mean residence time) of the tracer in the subsurface. The individual steps required to interpret a tracer test are reviewed and discussed. And an example tracer test directs the user through the interpretation method. An Excel spreadsheet application of the interpretation method is a companion document to this report.

G. Michael Shook; J. Hope Forsmann

2005-06-01T23:59:59.000Z

55

THE BROOKHAVEN NATIONAL LABORATORY PERFLUOROCARBON TRACER TECHNOLOGY: A PROVEN AND COST EFFECTIVE METHOD TO VERIFY INTEGRITY AND MONITOR LONG TERM PERFORMANCE OF WALLS, FLOORS, CAPS, AND COVER SYSTEMS.  

SciTech Connect (OSTI)

Currently, containment system failures are detected by monitoring wells downstream of the waste site. Clearly this approach is inefficient, as the contaminants will have migrated from the disposal area before they are detected. Methods that indicate early cover failure (prior to contaminant release) or predict impending cover failure are needed. The Brookhaven National Laboratory (BNL) Perfluorocarbon Tracer (PFT) technology can measure performance changes and integrity losses as the cover ages. This allows early detection of cover failure or pending failure so that repair or replacement can be made before contaminants leave the disposal cell. The PFT technology has been successfully applied to four subsurface barrier problems, one leak detection problem from underground ducts, and one surface cover problem. Testing has demonstrated that the PFTs are capable of accurately detecting and locating leaks down to fractions of an inch. The PFT technology has several advantages over competing approaches. The ability to simultaneously use multiple PFTs separates it from other gas tracer technologies. Using multiple tracers provides independent confirmation of flaw location, helps to clearly define transport pathways, and can be used for confirmatory testing (e.g., repeat the test using a new tracer). The PFT tests provide a direct measure of flaws in a barrier, whereas other measurements (pressure, moisture content, temperature, subsidence) provide indirect measures that need interpretation. The focus of the six PFT demonstrations has been on engineering aspects of the technology with the intent of finding if a flaw existed in the barrier. Work remains to be done on the scientific basis for this technology. This includes determining PFT diffusion rates through various materials (soils and barrier) as a function of moisture content, determining the effects of barometric pumping on PFT flow for cover systems, and determining wind effects on side slopes of cover systems and their impact on PFT performance. It also includes application of models to assist in the design of the monitoring system and the interpretation of the data. The set of demonstrations was performed on small sites (< 1/4 acre). Future work also needs to consider scaling issues to develop and design optimal techniques for delivery and monitoring of the PFTs.

HEISER, J.; SULLIVAN, T.

2002-03-11T23:59:59.000Z

56

Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier  

DOE Patents [OSTI]

Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

Harrup, Mason K. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID)

2007-05-15T23:59:59.000Z

57

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

58

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

59

Accelerated test methods for evaluating alkali-silica reactivity of recycled concrete aggregates.  

E-Print Network [OSTI]

??This thesis reports the findings of a study carried out to determine the effectiveness of Accelerated Tests in evaluating the Alkali-Silica Reactivity of Recycled Concrete… (more)

Johnson, Robert C (Author)

2011-01-01T23:59:59.000Z

60

REACTIVITY MONITORING USING THE AREA METHOD FOR THE SUBCRITICAL VENUS-F CORE WITHIN THE FRAMEWORK OF THE FREYA PROJECT  

E-Print Network [OSTI]

1 REACTIVITY MONITORING USING THE AREA METHOD FOR THE SUBCRITICAL VENUS-F CORE WITHIN THE FRAMEWORK consists of the coupling of a subcritical fast reactor to a particle accelerator via a heavy material). It couples the VENUS-F subcritical fast core with the GENEPI-3C accelerator. The latter delivers a beam

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

First Tracer Test After Circulation in Desert Peak 27-15  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

Rose, Peter

62

First Tracer Test After Circulation in Desert Peak 27-15  

SciTech Connect (OSTI)

Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

Rose, Peter

2013-11-16T23:59:59.000Z

63

An Integrated Approach to Characterizing Bypassed Oil in Heterogeneous and Fractured Reservoirs Using Partitioning Tracers  

SciTech Connect (OSTI)

We explore the use of efficient streamline-based simulation approaches for modeling partitioning interwell tracer tests in hydrocarbon reservoirs. Specifically, we utilize the unique features of streamline models to develop an efficient approach for interpretation and history matching of field tracer response. A critical aspect here is the underdetermined and highly ill-posed nature of the associated inverse problems. We have investigated the relative merits of the traditional history matching ('amplitude inversion') and a novel travel time inversion in terms of robustness of the method and convergence behavior of the solution. We show that the traditional amplitude inversion is orders of magnitude more non-linear and the solution here is likely to get trapped in local minimum, leading to inadequate history match. The proposed travel time inversion is shown to be extremely efficient and robust for practical field applications. The streamline approach is generalized to model water injection in naturally fractured reservoirs through the use of a dual media approach. The fractures and matrix are treated as separate continua that are connected through a transfer function, as in conventional finite difference simulators for modeling fractured systems. A detailed comparison with a commercial finite difference simulator shows very good agreement. Furthermore, an examination of the scaling behavior of the computation time indicates that the streamline approach is likely to result in significant savings for large-scale field applications. We also propose a novel approach to history matching finite-difference models that combines the advantage of the streamline models with the versatility of finite-difference simulation. In our approach, we utilize the streamline-derived sensitivities to facilitate history matching during finite-difference simulation. The use of finite-difference model allows us to account for detailed process physics and compressibility effects. The approach is very fast and avoids much of the subjective judgments and time-consuming trial-and-errors associated with manual history matching. We demonstrate the power and utility of our approach using a synthetic example and two field examples. We have also explored the use of a finite difference reservoir simulator, UTCHEM, for field-scale design and optimization of partitioning interwell tracer tests. The finite-difference model allows us to include detailed physics associated with reactive tracer transport, particularly those related with transverse and cross-streamline mechanisms. We have investigated the potential use of downhole tracer samplers and also the use of natural tracers for the design of partitioning tracer tests. Finally, we discuss several alternative ways of using partitioning interwell tracer tests (PITTs) in oil fields for the calculation of oil saturation, swept pore volume and sweep efficiency, and assess the accuracy of such tests under a variety of reservoir conditions.

Akhil Datta-Gupta

2006-12-31T23:59:59.000Z

64

Methods for modeling impact-induced reactivity changes in small reactors.  

SciTech Connect (OSTI)

This paper describes techniques for determining impact deformation and the subsequent reactivity change for a space reactor impacting the ground following a potential launch accident or for large fuel bundles in a shipping container following an accident. This technique could be used to determine the margin of subcriticality for such potential accidents. Specifically, the approach couples a finite element continuum mechanics model (Pronto3D or Presto) with a neutronics code (MCNP). DAGMC, developed at the University of Wisconsin-Madison, is used to enable MCNP geometric queries to be performed using Pronto3D output. This paper summarizes what has been done historically for reactor launch analysis, describes the impact criticality analysis methodology, and presents preliminary results using representative reactor designs.

Tallman, Tyler N.; Radel, Tracy E.; Smith, Jeffrey A.; Villa, Daniel L.; Smith, Brandon M. (U. of Wisconsin, Madison, WI); Radel, Ross F.; Lipinski, Ronald J.; Wilson, Paul Philip Hood (U. of Wisconsin, Madison, WI)

2010-10-01T23:59:59.000Z

65

Enhanced Oil Recovery: Aqueous Flow Tracer Measurement  

SciTech Connect (OSTI)

A low detection limit analytical method was developed to measure a suite of benzoic acid and fluorinated benzoic acid compounds intended for use as tracers for enhanced oil recovery operations. Although the new high performance liquid chromatography separation successfully measured the tracers in an aqueous matrix at low part per billion levels, the low detection limits could not be achieved in oil field water due to interference problems with the hydrocarbon-saturated water using the system's UV detector. Commercial instrument vendors were contacted in an effort to determine if mass spectrometry could be used as an alternate detection technique. The results of their work demonstrate that low part per billion analysis of the tracer compounds in oil field water could be achieved using ultra performance liquid chromatography mass spectrometry.

Joseph Rovani; John Schabron

2009-02-01T23:59:59.000Z

66

Development of Models to Simulate Tracer Tests for Characterization of Enhanced Geothermal Systems  

SciTech Connect (OSTI)

A recent report found that power and heat produced from enhanced (or engineered) geothermal systems (EGSs) could have a major impact on the U.S energy production capability while having a minimal impact on the environment. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distribution, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for the design and commercial development of the geothermal energy of a potential EGS site. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. This project was initially focused on tracer development with the application of perfluorinated tracer (PFT) compounds, non-reactive tracers used in numerous applications from atmospheric transport to underground leak detection, to geothermal systems, and evaluation of encapsulated PFTs that would release tracers at targeted reservoir temperatures. After the 2011 midyear review and subsequent discussions with the U.S. Department of Energy Geothermal Technology Program (GTP), emphasis was shifted to interpretive tool development, testing, and validation. Subsurface modeling capabilities are an important component of this project for both the design of suitable tracers and the interpretation of data from in situ tracer tests, be they single- or multi-well tests. The purpose of this report is to describe the results of the tracer and model development for simulating and conducting tracer tests for characterizing EGS parameters.

Williams, Mark D.; Reimus, Paul; Vermeul, Vincent R.; Rose, Peter; Dean, Cynthia A.; Watson, Tom B.; Newell, D.; Leecaster, Kevin; Brauser, Eric

2013-05-01T23:59:59.000Z

67

Enforcing positivity in intrusive PC-UQ methods for reactive ODE systems  

SciTech Connect (OSTI)

We explore the relation between the development of a non-negligible probability of negative states and the instability of numerical integration of the intrusive Galerkin ordinary differential equation system describing uncertain chemical ignition. To prevent this instability without resorting to either multi-element local polynomial chaos (PC) methods or increasing the order of the PC representation in time, we propose a procedure aimed at modifying the amplitude of the PC modes to bring the probability of negative state values below a user-defined threshold. This modification can be effectively described as a filtering procedure of the spectral PC coefficients, which is applied on-the-fly during the numerical integration when the current value of the probability of negative states exceeds the prescribed threshold. We demonstrate the filtering procedure using a simple model of an ignition process in a batch reactor. This is carried out by comparing different observables and error measures as obtained by non-intrusive Monte Carlo and Gauss-quadrature integration and the filtered intrusive procedure. The filtering procedure has been shown to effectively stabilize divergent intrusive solutions, and also to improve the accuracy of stable intrusive solutions which are close to the stability limits.

Najm, Habib N. [Sandia National Laboratories, Livermore, CA 94551 (United States); Valorani, Mauro [Mechanical and Aerospace Engineering Dept., Sapienza University of Rome, Rome (Italy)

2014-08-01T23:59:59.000Z

68

AN INTEGRATED APPROACH TO CHARACTERIZING BYPASSED OIL IN HETEROGENEOUS AND FRACTURED RESERVOIRS USING PARTITIONING TRACERS  

SciTech Connect (OSTI)

We explore the use of efficient streamline-based simulation approaches for modeling partitioning interwell tracer tests in hydrocarbon reservoirs. Specifically, we utilize the unique features of streamline models to develop an efficient approach for interpretation and history matching of field tracer response. A critical aspect here is the underdetermined and highly ill-posed nature of the associated inverse problems. We have adopted an integrated approach whereby we combine data from multiple sources to minimize the uncertainty and non-uniqueness in the interpreted results. For partitioning interwell tracer tests, these are primarily the distribution of reservoir permeability and oil saturation distribution. A novel approach to multiscale data integration using Markov Random Fields (MRF) has been developed to integrate static data sources from the reservoir such as core, well log and 3-D seismic data. We have also explored the use of a finite difference reservoir simulator, UTCHEM, for field-scale design and optimization of partitioning interwell tracer tests. The finite-difference model allows us to include detailed physics associated with reactive tracer transport, particularly those related with transverse and cross-streamline mechanisms. We have investigated the potential use of downhole tracer samplers and also the use of natural tracers for the design of partitioning tracer tests. Finally, the behavior of partitioning tracer tests in fractured reservoirs is investigated using a dual-porosity finite-difference model.

Akhil Datta-Gupta

2003-08-01T23:59:59.000Z

69

Mass spectral characterization of petroleum dyes, tracers, and additives  

SciTech Connect (OSTI)

Petroleum dyes, additives, and tracers are important for identifying gasolines in spill and contamination problems. High-resolution mass spectrometry (HRMS) was used for the characterization of 21 commercial petroleum dyes. Many contained common chromophores, typically azo or anthraquinone groups, and often differed only in their degree of alkyl substitution. Few dyes were pure and typically contained several chromogens with homologous series of substituents. A separation method was developed to concentrate the polar fractions containing the additives. Subsequent characterization of the polar fraction by GC/MS showed distinct differences between different gasolines. Various colorless tracers were evaluated in terms of detectability, soil adsorption, and cost. Many tracers exhibited soil adsorption and interferences which limited their detectability. Alcohols in the C8-C10 range were found to be the most suitable tracers with GC/MS detection limits of 1 ppm. 22 references, 4 figures, 3 tables.

Youngless, T.L.; Swansiger, J.T.; Danner, D.A.; Greco, M.

1985-08-01T23:59:59.000Z

70

Innovative techniques for the description of reservoir heterogeneity using tracers. Second technical annual progress report, October 1991--September 1992  

SciTech Connect (OSTI)

This second annual report on innovative uses of tracers for reservoir characterization contains four sections each describing a novel use of oilfield tracers. The first section describes and illustrates the use of a new single-well tracer test to estimate wettability. This test consists of the injection of brine containing tracers followed by oil containing tracers, a shut-in period to allow some of the tracers to react, and then production of the tracers. The inclusion of the oil injection slug with tracers is unique to this test, and this is what makes the test work. We adapted our chemical simulator, UTCHEM, to enable us to study this tracer method and made an extensive simulation study to evaluate the effects of wettability based upon characteristic curves for relative permeability and capillary pressure for differing wetting states typical of oil reservoirs. The second section of this report describes a new method for analyzing interwell tracer data based upon a type-curve approach. Theoretical frequency response functions were used to build type curves of ``transfer function`` and ``phase spectrum`` that have dimensionless heterogeneity index as a parameter to characterize a stochastic permeability field. We illustrate this method by analyzing field tracer data. The third section of this report describes a new theory for interpreting interwell tracer data in terms of channeling and dispersive behavior for reservoirs. Once again, a stochastic approach to reservoir description is taken. The fourth section of this report describes our simulation of perfluorocarbon gas tracers. This new tracer technology developed at Brookhaven National Laboratory is being tested at the Elk Hills Naval Petroleum Reserve No. 1 in California. We report preliminary simulations made of these tracers in one of the oil reservoirs under evaluation with these tracers in this field. Our compostional simulator (UTCOMP) was used for this simulation study.

Pope, G.A.; Sepehrnoori, K.

1992-12-31T23:59:59.000Z

71

Non-invasive in situ plasma monitoring of reactive gases using the floating harmonic method for inductively coupled plasma etching application  

SciTech Connect (OSTI)

The floating harmonic method was developed for in situ plasma diagnostics of allowing real time measurement of electron temperature (T{sub e}) and ion flux (J{sub ion}) without contamination of the probe from surface modification by reactive species. In this study, this novel non-invasive diagnostic system was studied to characterize inductively coupled plasma of reactive gases monitoring T{sub e} and J{sub ion} for investigating the optimum plasma etching conditions and controlling of the real-time plasma surface reaction in the range of 200-900 W source power, 10-100 W bias power, and 3-15 mTorr chamber pressure, respectively.

Lee, J. H.; Kim, M. J. [Department of Materials Science and Engineering, University of Texas at Dallas, Texas 75080 (United States); Yoon, Y. S. [Department of Electrical Engineering, University of Texas at Dallas, Texas 75080 (United States)

2013-04-15T23:59:59.000Z

72

Reactive Maintenance  

Broader source: Energy.gov [DOE]

Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities.

73

Groundwater prospecting for sandstone-type uranium deposits: the merits of mineral-solution equilibria versus single element tracer methods. Volume II  

SciTech Connect (OSTI)

This report presents the results of further research on the groundwater geochemistry of 96 well waters in two uraniferous aquifers in Texas and Wyoming, and is a continuation of the work presented by Chatham et al. (1981). In this study variations in concentrations of U, As, Mo, Se and V were compared with the saturation state of the groundwater with respect to mineral phases of these elements known or expected to occur in each area. The non-radiogenic trace elements exhibited strong redox dependence consistent with thermodynamic predictions, but their variations did not pinpoint existing uranium ore bodies, because of a shift in groundwater flow patterns since the time of ore emplacement. Saturation levels of trace element minerals such as realgar, native Se, and molybdenite showed broad anomalies around the ore-bearing areas, similar to patterns found for U minerals by Langmuir and Chatham (1980), and Chatham et al. (1981). The radiogenic elements Ra and Rn showed significant anomalies directly within the ore zones. Helium anomalies were displaced in the direction of groundwater flow, but by their magnitude and areal extent provided strong evidence for the existence of nearby uranium accumulations. Uranium isotope ratios showed no systematic variations within the two aquifers studied. Saturation maps for kaolinite, illite, montmorillonite and the zeolites analcime and clinoptilolite provided 1 to 2 km anomalies around the ore at the Texas site. Saturation values for the gangue minerals pyrite and calcite defined the redox interface and often suggested the position of probable uranium mineralization. When properly used, the groundwater geochemical concepts for exploration can accurately pinpoint uranium mineralization at a fraction of the cost of conventional methods that involve test drilling and geophysical and core logging.

Wanty, R.B.; Langmuir, D.; Chatham, J.R.

1981-08-01T23:59:59.000Z

74

Brush potential curve tracer  

DOE Patents [OSTI]

A device for analyzing commutating characteristics of a motor or generator includes a holder for supporting a plurality of probes adjacent a brush of the motor or generator. Measurements of electrical current characteristics of the probes provides information useful in analyzing operation of the machine. Methods for employing a device in accordance with the invention are also disclosed.

Finch, H.A.

1985-06-21T23:59:59.000Z

75

Multiple-tracer gas analyzer  

SciTech Connect (OSTI)

A multi-gas tracer system has been designed, built, and used on an explosively fractured oil shale rubble bed. This paper deals exclusively with the hardware, software, and overall operation of the tracer system. This system is a field portable, self-contained unit, which utilizes a mass spectrometer for gas analysis. The unit has a 20 channel sample port capability and is controlled by a desk top computer. The system is configured to provide a dynamic sensitivity range of up to six orders of magnitude. A roots blower is manifolded to the unit to provide continuous flow in all sample lines. The continuous flow process allows representative samples as well as decreasing the time between each measurement. Typical multiplex cycle time to evaluate four unique gases is approximately 12 seconds.

Uhl, J.E.

1982-01-01T23:59:59.000Z

76

Reactive power compensator  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation.

El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Woodinville, WA); Chen, Mingliang (Kirkland, WA); Andexler, George (Everett, WA); Huang, Tony (Seattle, WA)

1992-01-01T23:59:59.000Z

77

Reactive Power Compensator.  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation. 26 figs.

El-Sharkawi, M.A.; Venkata, S.S.; Chen, M.; Andexler, G.; Huang, T.

1992-07-28T23:59:59.000Z

78

Reactive Gliosis Reactive Oxygen Species: Superoxide  

E-Print Network [OSTI]

. By sensing the electric signals generated by other 3368 Reactive Gliosis #12;individuals, mormyrids are alsoReactive Gliosis Glial Scar Reactive Oxygen Species: Superoxide Anions Neuroinflammation motor output. Reafferent Control in Electric Communication Reafferent Control in Electric Communication

79

Fuel Temperature Coefficient of Reactivity  

SciTech Connect (OSTI)

A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

Loewe, W.E.

2001-07-31T23:59:59.000Z

80

A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene...  

Open Energy Info (EERE)

Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Jump to: navigation, search OpenEI Reference LibraryAdd...

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain Site Characterization Study; Progress report, January 1, 1991--June 30, 1991  

SciTech Connect (OSTI)

Studies continue on the use of organic acids as tracers in hydrology studies of Yucca Mountain. Work performed during this time period has been concentrated in three main areas: the familiarization with, and optimization of, the LC-MS hardware and data system; the initial development of soil column test procedures, which are used for evaluation of both the columns themselves and the tracer compounds; and continuation of the batch sorption and degradation studies for the potential tracers. All three of these tasks will continue, as the addition of new tracer compounds, analytical information, and equipment will necessitate further evaluation of existing methods and procedures. Also included in this report is the final report on an information system.

Stetzenbach, K.J.

1991-12-31T23:59:59.000Z

82

RCUT: A Non-Invasive Method for Detection, Location, and Quantification of Radiological Contaminants in Pipes and Ducts - 12514  

SciTech Connect (OSTI)

Radiological Characterization Using Tracers (RCUT) is a minimally invasive method for detection and location of residual radiological contamination in pipes and ducts. The RCUT technology utilizes reactive gaseous tracers that dissociate when exposed to gamma and/or beta radiation emitting from a radiological contaminant in a pipe or duct. Sulfur hexafluoride (SF{sub 6}) was selected as a tracer for this radiological application, because it is a chemically inert gas that is both nonflammable, nontoxic, and breaks down when exposed to gamma radiation. Laboratory tests demonstrated that the tracer pair of SF{sub 6} and O{sub 2} formed SO{sub 2}F{sub 2} when exposed to a gamma or beta radioactive field, which indicated the presence of radiological contamination. Field application of RCUT involves first injecting the reactive tracers into the pipe to fill the pipe being inspected and allowing sufficient time for the tracer to interact with any contaminants present. This is followed by the injection of an inert gas at one end of the pipe to push the reactive tracer at a known or constant flow velocity along the pipe and then out the exit and sampling port at the end of the pipeline where its concentration is measured by a gas chromatograph. If a radiological contaminant is present in the pipe being tested, the presence of SO{sub 2}F{sub 2} will be detected. The time of arrival of the SO{sub 2}F{sub 2} can be used to locate the contaminant. If the pipe is free of radiological contamination, no SO{sub 2}F{sub 2} will be detected. RCUT and PCUT are both effective technologies that can be used to detect contamination within pipelines without the need for mechanical or human inspection. These methods can be used to detect, locate, and/or estimate the volume of a variety of radioactive materials and hazardous chemicals such as chlorinated solvents, petroleum products, and heavy metals. While further optimization is needed for RCUT, the key first step of identification of a tracer compound appropriate for the application of detecting radioactive pipeline contamination through the detection of decomposition products of SF{sub 6} has been demonstrated. Other tracer gases that will also undergo radiolysis will be considered in the future. The next step for the RCUT development process is conducting laboratory scale tests using short pipelines to define analytical requirements, establish performance boundaries, and develop strategies for lower exposure levels. Studies to identify additional analytical techniques using equipment that is more field rugged than a GC/MS would also be beneficial. (authors)

Bratton, Wesley L.; Maresca, Joseph W. Jr.; Beck, Deborah A. [Vista Engineering Technologies, L.L.C., Richland, WA, 99352 (United States)

2012-07-01T23:59:59.000Z

83

Guidance Document Reactive Chemicals  

E-Print Network [OSTI]

showers and chillers. Health Hazards: The reactive chemicals are grouped primarily because of the physical

84

Using Biofuel Tracers to Study Alternative Combustion Regimes  

E-Print Network [OSTI]

Section B (NIMB) Using Biofuel Tracers to Study Alternativeinjection. We investigate biofuel HCCI combustion, and use

Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

2006-01-01T23:59:59.000Z

85

Consideration of spatial effects in reactivity measurements  

SciTech Connect (OSTI)

Various methods of considering spatial effects in reactivity measurements are presented. These methods are employed both at the critical (mainly fast-neutron) facilities and at the BN-600 reactor.

Matveenko, I. P., E-mail: matveenko@ippe.ru; Lititskii, V. A.; Shokod'ko, A. G. [Institute of Physics and Power Engineering (Russian Federation)

2010-12-15T23:59:59.000Z

86

Tracer measurements during long-term circulation of the Rosemanowes HDR geothermal system  

SciTech Connect (OSTI)

Circulation experiments have been in operation for over two years in the artificially stimulated hot dry rock (HDR) doublet of the Camborne School of Mines (CSM) research facility in Cornwall, England. During that period tracer tests have been run at intervals using inert and reactive compounds. Initially, the results of the inert tracer investigations showed that the active volume (indicated by modal and median volumes) of the circulating system was dormant. Then, after a period of sustained oscillation, notable increases in active volume were observed which depended on both the subsequent flow rate changes and circulation time. these dynamic changes had almost reached optimum values when a downhole pump was introduced in the production well. The drawdown in the production well caused a reduction of the modal volume, whilst the median volume remained almost the same. Since then, the active volume has remained unchanged and irresponsive to circulation time and flow rate. The results of the reactive tracer tests confirm increasing chemical reaction with increasing circulation time and correlate qualitatively with the opening of newer and hotter pathways within the reservoir. However, repeated production logs throughout the circulation have identified flow paths that have depleted thermally; a discrepancy that can be explained by the geometry of the system and the preferential downward reservoir growth.

Kwakwa, K.A.

1988-01-01T23:59:59.000Z

87

Use of tracers in materials-holdup study  

SciTech Connect (OSTI)

Holdup measurements of special nuclear materials in large processing facilities offer considerable challenges to conventional nondestructive-assay techniques. The use of judiciously chosen radioactive tracers offer a unique method of overcoming this difficulty. Three examples involving the use of /sup 46/Sc and fission products from activated uranium in large-scale experimental studies of uranium holdup are discussed. A justification for the method and its advantages along with examples of successful applications of this technique for large-sale experimental studies are presented.

Pillay, K.K.S.

1983-01-01T23:59:59.000Z

88

Thermal Stability of Chelated Indium Activable Tracers  

SciTech Connect (OSTI)

The thermal stability of indium tracer chelated with organic ligands ethylenediaminetetraacetic acid (EDTA) and nitrilotriacetic acid (NTA) was measured for reservoir temperatures of 150, 200, and 240 C. Measurements of the soluble indium concentration was made as a function of time by neutron activation analysis. From the data, approximate thermal decomposition rates were estimated. At 150 C, both chelated tracers were stable over the experimental period of 20 days. At 200 C, the InEDTA concentration remained constant for 16 days, after which the thermal decomposition occurred at a measured rate constant of k = 0.09 d{sup -1}. The thermal decomposition of InNTA at 200 C showed a first order reaction with a measured rate constant of k = 0.16 d{sup -1}. At 240 C, both indium chelated tracers showed rapid decomposition with rate constants greater than 1.8 d{sup -1}. The data indicate that for geothermal reservoir with temperatures up to about 200 C, indium chelated tracers can be used effectively for transit times of at least 20 days. These experiments were run without reservoir rock media, and do not account for concomitant loss of indium tracer by adsorption processes.

Chrysikopoulos, Costas; Kruger, Paul

1986-01-21T23:59:59.000Z

89

E-Print Network 3.0 - atmospheric tracer experiments Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Geosciences 11 The University of Reading Helen Dacre Evaluating pollution transport in Summary: study Tracer experiments NAME tracer analysis UM tracer...

90

Geologic flow characterization using tracer techniques  

SciTech Connect (OSTI)

A new tracer flow-test system has been developed for in situ characterization of geologic formations. This report describes two sets of test equipment: one portable and one for testing in deep formations. Equations are derived for in situ detector calibration, raw data reduction, and flow logging. Data analysis techniques are presented for computing porosity and permeability in unconfined isotropic media, and porosity, permeability and fracture characteristics in media with confined or unconfined two-dimensional flow. The effects of tracer pulse spreading due to divergence, dispersion, and porous formations are also included.

Klett, R. D.; Tyner, C. E.; Hertel, Jr., E. S.

1981-04-01T23:59:59.000Z

91

Chelated Indium Activable Tracers for Geothermal Reservoirs  

E-Print Network [OSTI]

Center (SLAC), for providing the califclmiurh-252 neutron source. Appreciation is extended to Lew, rock size, and temperature on the tracer adsoqjtion and ther- mal degradation. The rock employed for these measurements was gragwacke, a prek valent rock type at The Geysers, California geothermal field. The re

Stanford University

92

Enthalpy and mass flowrate measurements for two-phase geothermal production by Tracer dilution techniques  

SciTech Connect (OSTI)

A new technique has been developed for the measurement of steam mass flowrate, water mass flowrate and total enthalpy of two-phase fluids produced from geothermal wells. The method involves precisely metered injection of liquid and vapor phase tracers into the two-phase production pipeline and concurrent sampling of each phase downstream of the injection point. Subsequent chemical analysis of the steam and water samples for tracer content enables the calculation of mass flowrate for each phase given the known mass injection rates of tracer. This technique has now been used extensively at the Coso geothermal project, owned and operated by California Energy Company. Initial validation of the method was performed at the Roosevelt Hot Springs geothermal project on wells producing to individual production separators equipped with orificeplate flowmeters for each phase.

Hirtz, Paul; Lovekin, Jim; Copp, John; Buck, Cliff; Adams, Mike

1993-01-28T23:59:59.000Z

93

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

1998-01-01T23:59:59.000Z

94

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

1998-09-08T23:59:59.000Z

95

Ca and 87/86 Sr isotopes as tracers of silicate weathering in small  

E-Print Network [OSTI]

44/40 Ca and 87/86 Sr isotopes as tracers of silicate weathering in small catchments of the Massif, Laboratory Division, Orléans, France 2 U.S. Geological Survey, Water Resources Division, Menlo Park, CA 94025).Measurements of 44/40 Ca isotope ratios (44/40 Ca measured by the double spike method on TIMS and normalized

Paris-Sud XI, Université de

96

Method of uranium reclamation from aqueous systems by reactive ion exchange. [US DOE patent application; anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands  

DOE Patents [OSTI]

A reactive ion exchange method for separation and recovery of values of uranium, neptunium, plutonium, or americium from substantially neutral aqueous systems of said metals comprises contacting said system with an effective amount of a basic anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands to achieve nearly 100% sorption of said actinyl ion onto said resin and an aqueous system practically free of said actinyl ions. The method is operational over an extensive range of concentrations from about 10/sup -6/ M to 1.0 M actinyl ion and a pH range of about 4 to 7. The method has particulr application to treatment of waste streams from Purex-type nuclear fuel reprocessing facilities and hydrometallurgical processes involving U, Np, P, or Am.

Maya, L.

1981-11-05T23:59:59.000Z

97

Asian Tracer Experiment and Atmospheric Modeling (TEAM) Project: Draft Field Work Plan for the Asian Long-Range Tracer Experiment  

SciTech Connect (OSTI)

This report provides an experimental plan for a proposed Asian long-range tracer study as part of the international Tracer Experiment and Atmospheric Modeling (TEAM) Project. The TEAM partners are China, Japan, South Korea and the United States. Optimal times of year to conduct the study, meteorological measurements needed, proposed tracer release locations, proposed tracer sampling locations and the proposed durations of tracer releases and subsequent sampling are given. Also given are the activities necessary to prepare for the study and the schedule for completing the preparation activities leading to conducting the actual field operations. This report is intended to provide the TEAM members with the information necessary for planning and conducting the Asian long-range tracer study. The experimental plan is proposed, at this time, to describe the efforts necessary to conduct the Asian long-range tracer study, and the plan will undoubtedly be revised and refined as the planning goes forward over the next year.

Allwine, K Jerry; Flaherty, Julia E.

2007-08-01T23:59:59.000Z

98

Theoretical Investigation of Hydrogen Adsorption and Dissociation on Iron and Iron Carbide Surfaces Using the ReaxFF Reactive Force Field Method  

SciTech Connect (OSTI)

We have developed a ReaxFF reactive force field to describe hydrogen adsorption and dissociation on iron and iron carbide surfaces relevant for simulation of Fischer–Tropsch (FT) synthesis on iron catalysts. This force field enables large system (>>1000 atoms) simulations of hydrogen related reactions with iron. The ReaxFF force field parameters are trained against a substantial amount of structural and energetic data including the equations of state and heats of formation of iron and iron carbide related materials, as well as hydrogen interaction with iron surfaces and different phases of bulk iron. We have validated the accuracy and applicability of ReaxFF force field by carrying out molecular dynamics simulations of hydrogen adsorption, dissociation and recombination on iron and iron carbide surfaces. The barriers and reaction energies for molecular dissociation on these two types of surfaces have been compared and the effect of subsurface carbon on hydrogen interaction with iron surface is evaluated. We found that existence of carbon atoms at subsurface iron sites tends to increase the hydrogen dissociation energy barrier on the surface, and also makes the corresponding hydrogen dissociative state relatively more stable compared to that on bare iron. These properties of iron carbide will affect the dissociation rate of H{sub 2} and will retain more surface hydride species, thus influencing the dynamics of the FT synthesis process.

Zou, Chenyu; van Duin, Adri C.T.; Sorescu, Dan C.

2012-06-01T23:59:59.000Z

99

Using Thermally-Degrading, Partitioning, and Nonreactive Tracers...  

Broader source: Energy.gov (indexed) [DOE]

Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Using Thermally-Degrading,...

100

Integrated Approach to Use Natural Chemical and Isotopic Tracers...  

Broader source: Energy.gov (indexed) [DOE]

Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems Integrated Approach to Use Natural Chemical and...

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Using Thermally-Degrading, Partitioning, and Nonreactive Tracers...  

Broader source: Energy.gov (indexed) [DOE]

Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Track Name May 19, 2010 This...

102

Use of Tracers to Characterize Fractures in Engineered Geothermal...  

Broader source: Energy.gov (indexed) [DOE]

Fractures in Engineered Geothermal Systems Project Objectives: Measure interwell fracture surface area and fracture spacing using sorbing tracers; measure fracture surface...

103

Quantum Dot Tracers for Use in Engineered Geothermal  

Broader source: Energy.gov (indexed) [DOE]

tracers, colloidal quantum dots, that offer great promise for use in characterizing fracture networks in EGS reservoirs. Since the wavelength of fluorescence (color) of these...

104

Integrated Approach to Use Natural Chemical and Isotopic Tracers...  

Broader source: Energy.gov (indexed) [DOE]

Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems B. Mack Kennedy (Presenter) and H. H. Liu Lawrence Berkeley...

105

Using conversions of chemically reacting tracers for numerical determination of temperature profiles in flowing systems and temperature histories in batch systems  

SciTech Connect (OSTI)

This report presents the mathematical bases for measuring internal temperatures within batch and flowing systems using chemically reacting tracers. This approach can obtain temperature profiles of plug-flow systems and temperature histories within batch systems. The differential equations for reactant conversion can be converted into Fredholm integral equations of the first kind. The experimental variable is the tracer-reaction activation energy. When more than one tracer is used, the reactions must have different activation energies to gain information. In systems with temperature extrema, multiple solutions for the temperature profiles or histories can exist, When a single parameter in the temperature distribution is needed, a single-tracer test may furnish this information. For multi-reaction tracer tests, three Fredholm equations are developed. Effects of tracer-reaction activation energy, number of tracers used, and error in the data are evaluated. The methods can determine temperature histories and profiles for many existing systems, and can be a basis for analysis of the more complicated dispersed-flow systems. An alternative to using the Fredholm-equation approach is the use of an assumed temperature- distribution function and incorporation of this function into the basic integral equation describing tracer behavior. The function contains adjustable parameters which are optimized to give the temperature distribution. The iterative Fredholm equation method is tested to see what is required to discriminate between two models of the temperature behavior of Hot Dry Rock (HDR) geothermal reservoirs. Experimentally, ester and amide hydrolyses are valid HDR tracer reactions for measuring temperatures in the range 75-100{degrees}C. Hydrolyses of bromobenzene derivatives are valid HDR tracer reactions for measuring temperatures in the range 150-275{degrees}C.

Brown, L.F.; Chemburkar, R.M.; Robinson, B.A.; Travis, B.J.

1996-04-01T23:59:59.000Z

106

The ATLAS DDM Tracer monitoring framework  

E-Print Network [OSTI]

The DDM Tracer Service is aimed to trace and monitor the atlas file operations on the Worldwide LHC Computing Grid. The volume of traces has increased significantly since the service started in 2009. Now there are about ~5 million trace messages every day and peaks of greater than 250Hz, with peak rates continuing to climb, which gives the current service structure a big challenge. Analysis of large datasets based on on-demand queries to the relational database management system (RDBMS), i.e. Oracle, can be problematic, and have a significant effect on the database's performance. Consequently, We have investigated some new high availability technologies like messaging infrastructure, specifically ActiveMQ, and key-value stores. The advantages of key value store technology are that they are distributed and have high scalability; also their write performances are usually much better than RDBMS, all of which are very useful for the Tracer service. Indexes and distributed counters have been also tested to improve...

ZANG, D; The ATLAS collaboration; BARISITS, M; LASSNIG, M; Andrew STEWART, G; MOLFETAS, A; BEERMANN, T

2012-01-01T23:59:59.000Z

107

Use of Tracers to Characterize Fractures in Engineered Geothermal Systems  

Broader source: Energy.gov [DOE]

Project Objectives: Measure interwell fracture surface area and fracture spacing using sorbing tracers; measure fracture surface areas adjacent to a single geothermal well using tracers and injection/backflow techniques; design, fabricate and test a downhole instrument for measuring fracture flow following a hydraulic stimulation experiment.

108

Parallel Finite Element Simulation of Tracer Injection in Oil Reservoirs  

E-Print Network [OSTI]

Parallel Finite Element Simulation of Tracer Injection in Oil Reservoirs Alvaro L.G.A. Coutinho In this work, parallel finite element techniques for the simulation of tracer injection in oil reservoirs. Supercomputers have made it possible to consider global reservoir effects which can not be represented using

Coutinho, Alvaro L. G. A.

109

MIPAS observations of organic tracers for biomass burning and intercontinental transport  

E-Print Network [OSTI]

MIPAS observations of organic tracers for biomass burning and intercontinental transport observations of organic tracers for biomass burning and intercontinental transport Introduction Suite - Oxford - September 2009 #12;MIPAS observations of organic tracers for biomass burning

110

When do tracer particles dominate the Lyapunov spectrum?  

E-Print Network [OSTI]

Dynamical instability is studied in a deterministic dynamical system of Hamiltonian type composed of a tracer particle in a fluid of many particles. The tracer and fluid particles are hard balls (disks, in two dimensions, or spheres, in three dimensions) undergoing elastic collisions. The dynamical instability is characterized by the spectrum of Lyapunov exponents. The tracer particle is shown to dominate the Lyapunov spectrum in the neighborhoods of two limiting cases: the Lorentz-gas limit in which the tracer particle is much lighter than the fluid particles and the Rayleigh-flight limit in which the fluid particles have a vanishing radius and form an ideal gas. In both limits, a gap appears in the Lyapunov spectrum between the few largest Lyapunov exponents associated with the tracer and the rest of the Lyapunov spectrum.

Pierre Gaspard; Henk van Beijeren

2002-02-22T23:59:59.000Z

111

National Biomedical Tracer Facility. Project definition study  

SciTech Connect (OSTI)

We request a $25 million government-guaranteed, interest-free loan to be repaid over a 30-year period for construction and initial operations of a cyclotron-based National Biomedical Tracer Facility (NBTF) in North Central Texas. The NBTF will be co-located with a linear accelerator-based commercial radioisotope production facility, funded by the private sector at approximately $28 million. In addition, research radioisotope production by the NBTF will be coordinated through an association with an existing U.S. nuclear reactor center that will produce research and commercial radioisotopes through neutron reactions. The combined facilities will provide the full range of technology for radioisotope production and research: fast neutrons, thermal neutrons, and particle beams (H{sup -}, H{sup +}, and D{sup +}). The proposed NBTF facility includes an 80 MeV, 1 mA H{sup -} cyclotron that will produce proton-induced (neutron deficient) research isotopes.

Schafer, R.

1995-02-14T23:59:59.000Z

112

Introduction of the Development ofIntroduction of the Development of New PET TracersNew PET Tracers  

E-Print Network [OSTI]

Introduction of the Development ofIntroduction of the Development of New PET TracersNew PET Tracers The Center for Translational Neuroimaging KunKun--EekEek KilKil #12;Principles of PET-1 PET: Positron Emission Tomography #12;Principles of PET-2 Cyclotron Scanner #12;Principles of PET-3 0 0.01 0.02 0.03 0

113

Surface reactivity and oxygen migration in amorphous indium-gallium-zinc oxide films annealed in humid atmosphere  

SciTech Connect (OSTI)

An isotope tracer study, i.e., {sup 18}O/{sup 16}O exchange using {sup 18}O{sub 2} and H{sub 2}{sup 18}O, was performed to determine how post-deposition annealing (PDA) affected surface reactivity and oxygen diffusivity of amorphous indium–gallium–zinc oxide (a-IGZO) films. The oxygen tracer diffusivity was very high in the bulk even at low temperatures, e.g., 200?°C, regardless of PDA and exchange conditions. In contrast, the isotope exchange rate, dominated by surface reactivity, was much lower for {sup 18}O{sub 2} than for H{sub 2}{sup 18}O. PDA in a humid atmosphere at 400?°C further suppressed the reactivity of O{sub 2} at the a-IGZO film surface, which is attributable to –OH-terminated surface formation.

Watanabe, Ken, E-mail: Watanabe.Ken@nims.go.jp [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan)] [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan); Lee, Dong-Hee [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Sakaguchi, Isao; Haneda, Hajime [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan)] [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Nomura, Kenji [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)] [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Kamiya, Toshio [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Hosono, Hideo [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Ohashi, Naoki, E-mail: Ohashi.Naoki@nims.go.jp [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)

2013-11-11T23:59:59.000Z

114

Preferred methods of analysis for chemical tracers in moderate...  

Open Energy Info (EERE)

of contamination or error are discussed in detail. Authors Kroneman, R. L.; Yorgason, K. R.; Moore and J. N. Published DOE Information Bridge, 1211984 DOI 10.21725121460...

115

Verification of Geothermal Tracer Methods in Highly Constrained Field  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov PtyInformation UCOpen EnergyVelankani Group JumpVerdiem Jump

116

Tracer Methods for Characterizing Fracture Stimulation in Enhanced  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyThe EnergyDepartment7 th ,Top Value AddedTotalTown ofTown o

117

Preferred methods of analysis for chemical tracers in moderate- and  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth'sOklahoma/GeothermalOrangePeru:Job CorpPowerVerde IncStar (07)high-temperature

118

Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up from theDepartment of EnergyThe Sun and ItsXVIIofPotentialSystems; 2010 Geothermal

119

Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics...  

Broader source: Energy.gov (indexed) [DOE]

Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Use of Tracers to Characterize...

120

Kinetic analysis of 18F-fluorodihydrorotenone as a deposited myocardial flow tracer: Comparison to thallium-201.  

SciTech Connect (OSTI)

The goal of this investigation was to assess the accuracy of 18F-fluorodihydrorotenone (18F-FDHR) as a new deposited myocardial flow tracer and compare the results to those for 201Tl. Methods. The kinetics of these flow tracers were evaluated in 22 isolated, erythrocyte- and albumin-perfused rabbit hearts over a flow range encountered in patients. The two flow tracers plus a vascular reference tracer (131I-albumin) were introduced as a bolus through a port just above the aortic cannula. Myocardial extraction, retention, washout, and uptake parameters were computed from the venous outflow curves using the multiple indicator dilution technique and spectral analysis. Results. The mean initial extraction fractions of 18F-FDHR (0.85 +- 0.07) and 201Tl (0.87 +- 0.05) were not significantly different, although the initial extraction fraction for 18F-FDHR declined with flow (P < 0.0001), whereas the initial extraction fraction of 201Tl did not. Washout of 201Tl was faster (P < 0.001) and more affected by flow (P < 0.05) than 18F-FDHR washout. Except for initial extraction fraction, 18F-FDHR retention was greater (P < 0.001) and less affected by flow (P < 0.05) than 201Tl retention. Reflecting its superior retention, net uptake of 18F-FDHR was better correlated with flow than 201Tl uptake at both one and fifteen minutes after tracer introduction (P < 0.0001 for both comparisons). Conclusion. The superior correlation of 18F-FDHR uptake with flow indicates that it is a better flow tracer than 201Tl in the isolated rabbit heart. Compared to the other currently available positron-emitting flow tracers (82Rb, 13N-ammonia, and 15O-water), 18F-FDHR has the potential of providing excellent image resolution without the need for an on-site cyclotron.

Marshall, Robert C.; Powers-Risius, Patricia; Reutter, Bryan W.; O'Neil, James P.; La Belle, Michael; Huesman, Ronald H.; VanBrocklin, Henry F.

2004-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hillslope Hydrological Processes in a Costa Rican Rainforest: Water Supply Partitioning Using Isotope Tracers  

E-Print Network [OSTI]

Blancas Hydroelectric Project, and for improved predictions in similar, ungauged watersheds (ICE 2002). Study Watershed The study watershed is located in San Juan de Peńas Blancas, east of the Cordillera de Tilarán mountain range backing up... peaks. These goals were accomplished by supplementing hydraulic and physical data already available at the site with use of isotope tracers. Methods Study Site The 2.2 ha watershed used in this research is located in Peńas Blancas, Costa Rica...

DuMont, Andrea Lyn

2014-04-24T23:59:59.000Z

122

Reactive Power Compensating System.  

DOE Patents [OSTI]

The circuit was designed for the specific application of wind-driven induction generators. It has great potential for application in any situation where a varying reactive power load is present, such as with induction motors or generators, or for transmission network compensation.

Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

1985-01-04T23:59:59.000Z

123

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-11-25T23:59:59.000Z

124

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-01-21T23:59:59.000Z

125

Primordial black holes as biased tracers  

E-Print Network [OSTI]

Primordial black holes (PBHs) are theoretical black holes which may be formed during the radiation dominant era and, basically, caused by the gravitational collapse of radiational overdensities. It has been well known that in the context of the structure formation in our Universe such collapsed objects, e.g., halos/galaxies, could be considered as bias tracers of underlying matter fluctuations and the halo/galaxy bias has been studied well. Employing a peak-background split picture which is known to be a useful tool to discuss the halo bias, we consider the large scale clustering behavior of the PBH and propose an almost mass-independent constraint to the scenario that dark matters (DMs) consist of PBHs. We consider the case where the statistics of the primordial curvature perturbations is almost Gaussian, but with small local-type non-Gaussianity. If PBHs account for the DM abundance, such a large scale clustering of PBHs behaves as nothing but the matter isocurvature perturbation and constrained strictly by...

Tada, Yuichiro

2015-01-01T23:59:59.000Z

126

Thermal single-well injection-withdrawal tracer tests for determining fracture-matrix heat transfer area  

SciTech Connect (OSTI)

Single-well injection-withdrawal (SWIW) tracer tests involve injection of traced fluid and subsequent tracer recovery from the same well, usually with some quiescent time between the injection and withdrawal periods. SWIW are insensitive to variations in advective processes that arise from formation heterogeneities, because upon withdrawal, fluid parcels tend to retrace the paths taken during injection. However, SWIW are sensitive to diffusive processes, such as diffusive exchange of conservative or reactive solutes between fractures and rock matrix. This paper focuses on SWIW tests in which temperature itself is used as a tracer. Numerical simulations demonstrate the sensitivity of temperature returns to fracture-matrix interaction. We consider thermal SWIW response to the two primary reservoir improvements targeted with stimulation, (1) making additional fractures accessible to injected fluids, and (2) increasing the aperture and permeability of pre-existing fractures. It is found that temperature returns in SWIW tests are insensitive to (2), while providing a strong signal of more rapid temperature recovery during the withdrawal phase for (1).

Pruess, K.; Doughty, C.

2010-01-15T23:59:59.000Z

127

Inverse modeling of partitioning interwell tracer tests: A streamline approach  

E-Print Network [OSTI]

computations, inverse modeling 1. Introduction [2] It is recognized that the presence of nonaqueous phaseInverse modeling of partitioning interwell tracer tests: A streamline approach Akhil Datta orders of magnitude. INDEX TERMS: 1832 Hydrology: Groundwater transport; 1829 Hydrology: Groundwater

Datta-Gupta, Akhil

128

USING PERFLUOROCARBON TRACERS FOR VERIFICATION OF CAP AND COVER SYSTEMS PERFORMANCE.  

SciTech Connect (OSTI)

The Department of Energy (DOE) Environmental Management (EM) office has committed itself to an accelerated cleanup of its national facilities. The goal is to have much of the DOE legacy waste sites remediated by 2006. This includes closure of several sites (e.g., Rocky Flats and Fernald). With the increased focus on accelerated cleanup, there has been considerable concern about long-term stewardship issues in general, and verification and long-term monitoring (LTM) of caps and covers, in particular. Cap and cover systems (covers) are vital remedial options that will be extensively used in meeting these 2006 cleanup goals. Every buried waste site within the DOE complex will require some form of cover system. These covers are expected to last from 100 to 1000 years or more. The stakeholders can be expected to focus on system durability and sustained performance. DOE EM has set up a national committee of experts to develop a long-term capping (LTC) guidance document. Covers are subject to subsidence, erosion, desiccation, animal intrusion, plant root infiltration, etc., all of which will affect the overall performance of the cover. Very little is available in terms of long-term monitoring other than downstream groundwater or surface water monitoring. By its very nature, this can only indicate that failure of the cover system has already occurred and contaminants have been transported away from the site. This is unacceptable. Methods that indicate early cover failure (prior to contaminant release) or predict approaching cover failure are needed. The LTC committee has identified predictive monitoring technologies as a high priority need for DOE, both for new covers as well as existing covers. The same committee identified a Brookhaven National Laboratory (BNL) technology as one approach that may be capable of meeting the requirements for LTM. The Environmental Research and Technology Division (ERTD) at BNL developed a novel methodology for verifying and monitoring subsurface barriers (1,2). The technology uses perfluorocarbon tracers (PFTs) to determine flaws (e.g., holes or cracks) and high permeability areas in subsurface barriers. Gaseous tracers are injected on one side of the barrier and searched for on the opposite side of the barrier. The sampling grid, concentration, and time of arrival of the tracer(s) on the opposite side are used to determine the size and location of flaws and relative permeability of the barrier. In addition, there are multiple tracers available, which allows different tracers to be injected in different quadrants of the barrier. This yields additional information on transport phenomena of the barrier.

HEISER,J.; SULLIVAN,T.

2001-11-01T23:59:59.000Z

129

HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS  

SciTech Connect (OSTI)

The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

2012-01-01T23:59:59.000Z

130

Chemical tracers of episodic accretion in low-mass protostars  

E-Print Network [OSTI]

Aims: Accretion rates in low-mass protostars can be highly variable in time. Each accretion burst is accompanied by a temporary increase in luminosity, heating up the circumstellar envelope and altering the chemical composition of the gas and dust. This paper aims to study such chemical effects and discusses the feasibility of using molecular spectroscopy as a tracer of episodic accretion rates and timescales. Methods: We simulate a strong accretion burst in a diverse sample of 25 spherical envelope models by increasing the luminosity to 100 times the observed value. Using a comprehensive gas-grain network, we follow the chemical evolution during the burst and for up to 10^5 yr after the system returns to quiescence. The resulting abundance profiles are fed into a line radiative transfer code to simulate rotational spectra of C18O, HCO+, H13CO+, and N2H+ at a series of time steps. We compare these spectra to observations taken from the literature and to previously unpublished data of HCO+ and N2H+ 6-5 from th...

Visser, Ruud; Jorgensen, Jes K

2015-01-01T23:59:59.000Z

131

Spectral analysis for evaluation of myocardial tracers for medical imaging  

SciTech Connect (OSTI)

Kinetic analysis of dynamic tracer data is performed with the goal of evaluating myocardial radiotracers for cardiac nuclear medicine imaging. Data from experiments utilizing the isolated rabbit heart model are acquired by sampling the venous blood after introduction of a tracer of interest and a reference tracer. We have taken the approach that the kinetics are properly characterized by an impulse response function which describes the difference between the reference molecule (which does not leave the vasculature) and the molecule of interest which is transported across the capillary boundary and is made available to the cell. Using this formalism we can model the appearance of the tracer of interest in the venous output of the heart as a convolution of the appearance of the reference tracer with the impulse response. In this work we parameterize the impulse response function as the sum of a large number of exponential functions whose predetermined decay constants form a spectrum, and each is required only to have a nonnegative coefficient. This approach, called spectral analysis, has the advantage that it allows conventional compartmental analysis without prior knowledge of the number of compartments which the physiology may require or which the data will support.

Huesman, Ronald H.; Reutter, Bryan W.; Marshall, Robert C.

2000-10-11T23:59:59.000Z

132

Mined land reclamation by biological reactivation  

SciTech Connect (OSTI)

A mine reclamation technique, developed in Europe, restores land to full productivity within two years without topsoil replacement. The method deliberately reestablishes within one year following mining, the required biological balance between microbes, enzymes, and trace elements in the rock spoil rather than waiting five or more years for natural processes to restore balance. The technique is called Biological Reactivation (BR). This paper discusses the feasibility of BR reclamation after surface mining operations in the US. Staff of the Ohio Mining and Mineral Resources Research Institute completed an OSM-sponsored research project on BR in which physical and chemical tests characterized 140 spoil samples obtained from 10 surface mining operations. Test results indicated that Biological Reactivation technology could be effectively applied, at least in the test areas sampled within Appalachia. Preliminary estimates make clear that the new technique reduces reclamation costs on prime farmland by approximately 95% compared to topsoil segregation and replacement methods.

Gozon, J.S.; Konya, C.J.; Lukovic, S.S.; Lundquist, R.G.; Olah, J.

1982-12-01T23:59:59.000Z

133

Preliminary assessment of halogenated alkanes as vapor-phase tracers  

SciTech Connect (OSTI)

New tracers are needed to evaluate the efficiency of injection strategies in vapor-dominated environments. One group of compounds that seems to meet the requirements for vapor-phase tracing are the halogenated alkanes (HCFCs). HCFCs are generally nontoxic, and extrapolation of tabulated thermodynamic data indicate that they will be thermally stable and nonreactive in a geothermal environment. The solubilities and stabilities of these compounds, which form several homologous series, vary according to the substituent ratios of fluorine, chlorine, and hydrogen. Laboratory and field tests that will further define the suitability of HCFCs as vapor-phase tracers are under way.

Adams, Michael C.; Moore, Joseph N.; Hirtz, Paul

1991-01-01T23:59:59.000Z

134

Effects from influent boundary conditions on tracer migration and spatial variability features in intermediate-scale experiments  

SciTech Connect (OSTI)

In previous unsaturated transport studies at Los Alamos dispersion coefficients were estimated to be higher close to the tracer source than at greater distances from the source. Injection of tracers through discrete influent outlets could have accounted for those higher dispersions. Also, a lack of conservation of mass of the tracers was observed and suspected to be due to spatial variability in transport. In the present study experiments were performed under uniform influent (ponded) conditions in which breakthrough of tracers was monitored at four locations at each of four depths. All other conditions were similar to those of the unsaturated transport experiments. A comparison of results from these two sets of experiments indicates differences in the parameter estimates. Estimates were made for the dispersion coefficient and the retardation factor by the one-dimensional steady flow computer code, CFITIM. Estimates were also made for mass and for velocity and the dispersion coefficient by the method of moments. The dispersion coefficient decreased with depth under discrete influent application and increased with depth under ponded influent application. Retardation was predicted better under the discrete influent application than under ponded influent application. Differences in breakthroughs and in estimated parameters among locations at the same depth were observed under ponded influent application. Those differences indicate that there is a lack of conservation of mass as well as significant spatial variability across the experimental domain. 14 refs., 9 figs., 8 tabs.

Fuentes, H.R.; Polzer, W.L.; Springer, E.P.

1987-04-01T23:59:59.000Z

135

A Tariff for Reactive Power  

SciTech Connect (OSTI)

Two kinds of power are required to operate an electric power system: real power, measured in watts, and reactive power, measured in volt-amperes reactive or VARs. Reactive power supply is one of a class of power system reliability services collectively known as ancillary services, and is essential for the reliable operation of the bulk power system. Reactive power flows when current leads or lags behind voltage. Typically, the current in a distribution system lags behind voltage because of inductive loads such as motors. Reactive power flow wastes energy and capacity and causes voltage droop. To correct lagging power flow, leading reactive power (current leading voltage) is supplied to bring the current into phase with voltage. When the current is in phase with voltage, there is a reduction in system losses, an increase in system capacity, and a rise in voltage. Reactive power can be supplied from either static or dynamic VAR sources. Static sources are typically transmission and distribution equipment, such as capacitors at substations, and their cost has historically been included in the revenue requirement of the transmission operator (TO), and recovered through cost-of-service rates. By contrast, dynamic sources are typically generators capable of producing variable levels of reactive power by automatically controlling the generator to regulate voltage. Transmission system devices such as synchronous condensers can also provide dynamic reactive power. A class of solid state devices (called flexible AC transmission system devices or FACTs) can provide dynamic reactive power. One specific device has the unfortunate name of static VAR compensator (SVC), where 'static' refers to the solid state nature of the device (it does not include rotating equipment) and not to the production of static reactive power. Dynamic sources at the distribution level, while more costly would be very useful in helping to regulate local voltage. Local voltage regulation would reduce system losses, increase circuit capacity, increase reliability, and improve efficiency. Reactive power is theoretically available from any inverter-based equipment such as photovoltaic (PV) systems, fuel cells, microturbines, and adjustable-speed drives. However, the installation is usually only economical if reactive power supply is considered during the design and construction phase. In this report, we find that if the inverters of PV systems or the generators of combined heat and power (CHP) systems were designed with capability to supply dynamic reactive power, they could do this quite economically. In fact, on an annualized basis, these inverters and generators may be able to supply dynamic reactive power for about $5 or $6 per kVAR. The savings from the local supply of dynamic reactive power would be in reduced losses, increased capacity, and decreased transmission congestion. The net savings are estimated to be about $7 per kVAR on an annualized basis for a hypothetical circuit. Thus the distribution company could economically purchase a dynamic reactive power service from customers for perhaps $6/kVAR. This practice would provide for better voltage regulation in the distribution system and would provide an alternate revenue source to help amortize the cost of PV and CHP installations. As distribution and transmission systems are operated under rising levels of stress, the value of local dynamic reactive supply is expected to grow. Also, large power inverters, in the range of 500 kW to 1 MW, are expected to decrease in cost as they become mass produced. This report provides one data point which shows that the local supply of dynamic reactive power is marginally profitable at present for a hypothetical circuit. We expect that the trends of growing power flow on the existing system and mass production of inverters for distributed energy devices will make the dynamic supply of reactive power from customers an integral component of economical and reliable system operation in the future.

Kueck, John D [ORNL; Kirby, Brendan J [ORNL; Li, Fangxing [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator

2008-07-01T23:59:59.000Z

136

36Cl as a tracer in geothermal systems- Example from Valles Caldera...  

Open Energy Info (EERE)

Cl as a tracer in geothermal systems- Example from Valles Caldera, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: 36Cl as a tracer...

137

Time-scales of passive tracers in the ocean with paleoapplications  

E-Print Network [OSTI]

Quantifying time-responses of the ocean to passive and active tracers is critical when interpreting paleodata from sediment cores. Surface-injected tracers are not spreading instantaneously or uniformly throughout the ...

Siberlin, Charlotte

2010-01-01T23:59:59.000Z

138

RADIOGENIC ISOTOPES: TRACERS OF PAST OCEAN CIRCULATION AND EROSIONAL INPUT  

E-Print Network [OSTI]

in the ocean has varied as a function of changes in paleocircu- lation, source provenances, style and intensity-established paleoceano- graphic tracers such as carbon isotopes. INDEX TERMS: 1040 Geochemistry: Isotopic composition Atlantic Deep Water (NADW) according to latest estimates based on results of the World Ocean Circulation

Jellinek, Mark

139

DIVISION S-3-NOTES HYDROLOGIC TRACER EFFECTS ON SOIL  

E-Print Network [OSTI]

and denitrification (the conversion of NOf to N gas)can be important to the fate of NOf and organic pollutants on microbial activity. These effects could be important whentracers areused instudies of the fate and transport of pollutants in the environment. In such studies, it is important to determine if tracer compounds affect

Gold, Art

140

The feasibility of ethyl iodide as an atmospheric tracer  

E-Print Network [OSTI]

. The CCl? was dissolved in toluene and measured with an electron-capture detector. The differences between the two tracers appeared in the lateral distribution measurements where the CC1, showed higher values than the HTO. The HTO results were described...

Everett, Joe Vincent

1976-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

ANALYSIS OF TRACER AND THERMAL TRANSIENTS DURING REINJECTION  

E-Print Network [OSTI]

and developed a new technique which combines the results from in- terwell tracer tests and thermal injection variables of the injection and backflow periods. Finally we suggested thermal injection-backflow tests for interpreting thermal injection-backflow tests. In fact, the MD model was first developed by Lauwerier to study

Stanford University

142

Diss. ETH Nr. 10714 Helium und Tritium als Tracer fr  

E-Print Network [OSTI]

Diss. ETH Nr. 10714 Helium und Tritium als Tracer für physikalische Prozesse in Seen ABHANDLUNG zur Zürich 1994 #12;Kurzfassung ix Kurzfassung Der radioaktive Zerfall von 3H (Tritium) zu 3He mit einer Fluide aus dem Erdinnern. Helium und Tritium werden massenspektrometrisch analysiert. Im Rahmen dieser Ar

Aeschbach-Hertig, Werner

143

Calibration of hydraulic and tracer tests in fractured media  

E-Print Network [OSTI]

Calibration of hydraulic and tracer tests in fractured media represented by a DFN Model L. D. Donado, X. Sanchez-Vila, E. Ruiz* & F. J. Elorza** * Enviros Spain S.L. ** UPM #12;Fractured Media Water flows through fractures (matrix basically impervious ­ though relevant to transport) Fractures at all

Politècnica de Catalunya, Universitat

144

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

145

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

146

DYES AS TRACERS FOR VADOSE ZONE HYDROLOGY Markus Flury and Nu Nu Wai  

E-Print Network [OSTI]

DYES AS TRACERS FOR VADOSE ZONE HYDROLOGY Markus Flury and Nu Nu Wai Department of Crop and Soil tracers have provided clues about the hydrological cycle as well as flow and transport processes information on dyes used as hydrological tracers, with particular emphasis on vadose zone hydrol- ogy. We

Flury, Markus

147

Conservation of reactive electromagnetic energy in reactive time  

E-Print Network [OSTI]

The complex Poynting theorem (CPT) is extended to a canonical time-scale domain $(t,s)$. Time-harmonic phasors are replaced by the positive-frequency parts of general fields, which extend analytically to complex time $t+is$, with $s>0$ interpreted as a time resolution scale. The real part of the extended CPT gives conservation in $t$ of a time-averaged field energy, and its imaginary part gives conservation in $s$ of a time-averaged reactive energy. In both cases, the averaging windows are determined by a Cauchy kernel of width $\\Delta t\\sim \\pm s$. This completes the time-harmonic CPT, whose imaginary part is generally supposed to be vaguely `related to' reactive energy without giving a conservation law, or even an expression, for the latter. The interpretation of $s$ as reactive time, tracking the leads and lags associated with stored capacitative and inductive energy, gives a simple explanation of the volt-ampere reactive (var) unit measuring reactive power: a var is simply one Joule per reactive second. The related 'complex radiation impedance density' is introduced to represent the field's local reluctance to radiate.

Gerald Kaiser

2015-01-05T23:59:59.000Z

148

Conservation of reactive electromagnetic energy in reactive time  

E-Print Network [OSTI]

The complex Poynting theorem (CPT) is extended to a canonical time-scale domain $(t,s)$. Time-harmonic phasors are replaced by the positive-frequency parts of general fields, which extend analytically to complex time $t+is$, with $s>0$ interpreted as a time resolution scale. The real part of the extended CPT gives conservation in $t$ of a time-averaged field energy, and its imaginary part gives conservation in $s$ of a time-averaged reactive energy. In both cases, the averaging windows are determined by a Cauchy kernel of width $\\Delta t\\sim \\pm s$. This completes the time-harmonic CPT, whose imaginary part is generally supposed to be vaguely `related to' reactive energy without giving a conservation law, or even an expression, for the latter. The interpretation of $s$ as reactive time, tracking the leads and lags associated with stored capacitative and inductive energy, gives a simple explanation of the volt-ampere reactive (var) unit measuring reactive power: a var is simply one Joule per reactive second. T...

Kaiser, Gerald

2015-01-01T23:59:59.000Z

149

Modeling of CBM production, CO{sub 2} injection, and tracer movement at a field CO{sub 2} sequestration site  

SciTech Connect (OSTI)

Sequestration of carbon dioxide in unmineable coal seams is a potential technology mainly because of the potential for simultaneous enhanced coalbed methane production (ECBM). Several pilot tests have been performed around the globe leading to mixed results. Numerous modeling efforts have been carried out successfully to model methane production and carbon dioxide (CO{sub 2}) injection. Sensitivity analyses and history matching along with several optimization tools were used to estimate reservoir properties and to investigate reservoir performance. Geological and geophysical techniques have also been used to characterize field sequestration sites and to inspect reservoir heterogeneity. The fate and movement of injected CO{sub 2} can be determined by using several monitoring techniques. Monitoring of perfluorocarbon (PFC) tracers is one of these monitoring technologies. As a part of this monitoring technique, a small fraction of a traceable fluid is added to the injection wellhead along with the CO{sub 2} stream at different times to monitor the timing and location of the breakthrough in nearby monitoring wells or offset production wells. A reservoir modeling study was performed to simulate a pilot sequestration site located in the San Juan coal basin of northern New Mexico. Several unknown reservoir properties at the field site were estimated by modeling the coal seam as a dual porosity formation and by history matching the methane production and CO{sub 2} injection. In addition to reservoir modeling of methane production and CO{sub 2} injection, tracer injection was modeled. Tracers serve as a surrogate for determining potential leakage of CO{sub 2}. The tracer was modeled as a non-reactive gas and was injected into the reservoir as a mixture along with CO{sub 2}. Geologic and geometric details of the field site, numerical modeling details of methane production, CO{sub 2} injection, and tracer injection are presented in this paper. Moreover, the numerical predictions of the tracer arrival times were compared with the measured field data. Results show that tracer modeling is useful in investigating movement of injected CO{sub 2} into the coal seam at the field site. Also, such new modeling techniques can be utilized to determine potential leakage pathways, and to investigate reservoir anisotropy and heterogeneity.

Siriwardane, Hema J.; Bowes, Benjamin D.; Bromhal, Grant S.; Gondle, Raj K.; Wells, Arthur W.; Strazisar, Brian R.

2012-07-01T23:59:59.000Z

150

RESUS-D-12-00285 Mild hypothermia reduces per-ischemic reactive oxygen species production4  

E-Print Network [OSTI]

this dysfunction through per-ischemic3 inhibition of reactive oxygen species (ROS) generation.4 Methods: First, ROS ischemic injuries through complex events2 involving reactive oxygen species (ROS) generation 1, 2RESUS-D-12-00285 1 2 3 Mild hypothermia reduces per-ischemic reactive oxygen species production4

Paris-Sud XI, Université de

151

Mechanical models of fracture reactivation and slip on bedding surfaces during folding of the asymmetric anticline at Sheep Mountain, Wyoming  

E-Print Network [OSTI]

Mechanical models of fracture reactivation and slip on bedding surfaces during folding June 2008 Accepted 5 June 2008 Available online 13 June 2008 Keywords: Fold Fracture reactivation Bed methods to investigate the reactivation of fractures (opening and shearing) and the development of bedding

Borja, Ronaldo I.

152

Quantitative interpretation of tracer test data | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: EnergyPotentialUrbanUtilityScalePVCapacityPulaski County, Kentucky:County, Georgia: Energy79.tracer test data

153

Core follow calculation with the nTRACER numerical reactor and verification using power reactor measurement data  

SciTech Connect (OSTI)

The nTRACER direct whole core transport code employing the planar MOC solution based 3-D calculation method, the subgroup method for resonance treatment, the Krylov matrix exponential method for depletion, and a subchannel thermal/hydraulic calculation solver was developed for practical high-fidelity simulation of power reactors. Its accuracy and performance is verified by comparing with the measurement data obtained for three pressurized water reactor cores. It is demonstrated that accurate and detailed multi-physic simulation of power reactors is practically realizable without any prior calculations or adjustments. (authors)

Jung, Y. S.; Joo, H. G. [Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul (Korea, Republic of); Yoon, J. I. [KEPCO Nuclear Fuel, 1047 Daedukdae-ro, Yuseong-gu, Daejeon (Korea, Republic of)

2013-07-01T23:59:59.000Z

154

Monitoring of saline tracer movement with vertically distributed self-potential measurements at the HOBE agricultural test site, Voulund, Denmark  

E-Print Network [OSTI]

The self-potential (SP) method is sensitive to water fluxes in saturated and partially saturated porous media, such as those associated with rainwater infiltration and groundwater recharge. We present a field-based study at the Voulund agricultural test site, Denmark, that is, to the best of our knowledge, the first to focus on the vertical self-potential distribution prior to and during a saline tracer test. A coupled hydrogeophysical modeling framework is used to simulate the SP response to precipitation and saline tracer infiltration. A layered hydrological model is first obtained by inverting dielectric and matric potential data. The resulting model that compares favorably with electrical resistance tomography models is subsequently used to predict the SP response. The electrokinetic contribution (caused by water fluxes in a charged porous soil) is modeled by an effective excess charge approach that considers both water saturation and pore water salinity. Our results suggest that the effective excess char...

Jougnot, Damien; Haarder, Eline B; Looms, Majken C

2015-01-01T23:59:59.000Z

155

Reactive decontamination formulation  

DOE Patents [OSTI]

The present invention provides a universal decontamination formulation and method for detoxifying chemical warfare agents (CWA's) and biological warfare agents (BWA's) without producing any toxic by-products, as well as, decontaminating surfaces that have come into contact with these agents. The formulation includes a sorbent material or gel, a peroxide source, a peroxide activator, and a compound containing a mixture of KHSO.sub.5, KHSO.sub.4 and K.sub.2 SO.sub.4. The formulation is self-decontaminating and once dried can easily be wiped from the surface being decontaminated. A method for decontaminating a surface exposed to chemical or biological agents is also disclosed.

Giletto, Anthony (College Station, TX); White, William (College Station, TX); Cisar, Alan J. (Cypress, TX); Hitchens, G. Duncan (Bryan, TX); Fyffe, James (Bryan, TX)

2003-05-27T23:59:59.000Z

156

Reactivity of surface carbon deposited on supported Rh catalysts by the disproportionation of CO  

SciTech Connect (OSTI)

Recent investigations on hydrocarbon synthesis from CO and H/sub 2/ over Group VIII metals have proposed that the surface carbon formed by the dissociation of CO is an intermediate for hydrocarbon formation. It implies that metals which dissociate CO readily (e.g., Ni, Co, and Ru) are good catalysts for hydrocarbon synthesis unless the surface carbon is bound too strongly. There is a certain controversy in the literature on whether CO undergoes dissociation on Rh surfaces under UHV conditions. In the present work, the authors have investigated the reactivity of surface carbon deposited on TiO/sub 2/- or SiO/sub 2/-supported Rh catalysts in the presence of molecularly adsorbed CO by means of the isotopic tracer technique and have made a direct comparison of the reactivity of adsorbed CO with that of surface carbon. It has been revealed that three forms of carbon are produced by the disproportionation of CO.

Orita, H.; Naito, S.; Tamaru, K.

1988-06-01T23:59:59.000Z

157

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 ``Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core`` problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-12-01T23:59:59.000Z

158

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core'' problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-01-01T23:59:59.000Z

159

JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1029/, What is the skill of ocean tracers in reducing uncertainties  

E-Print Network [OSTI]

in current Earth system models and (ii) imperfect knowledge of model parameters. Ocean tracers observa- tions

Haran, Murali

160

Mixing properties in the advection of passive tracers via recurrences and extreme value theory  

E-Print Network [OSTI]

In this paper we characterize the mixing properties in the advection of passive tracers by exploiting the extreme value theory for dynamical systems. With respect to classical techniques directly related to the Poincar\\'e recurrences analysis, our method provides reliable estimations of the characteristic mixing times and distinguishes between barriers and unstable fixed points. The method is based on a check of convergence for extreme value laws on finite datasets. We define the mixing times in terms of the shortest time intervals such that extremes converge to the asymptotic (known) parameters of the Generalized Extreme Value distribution. Our technique is suitable for applications in the analysis of other systems where mixing time scales need to be determined and limited datasets are available.

Davide Faranda; Xavier Leoncini; Sandro Vaienti

2014-02-16T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Reactive ion etching: Optimized diamond membrane fabrication for transmission electron microscopy  

E-Print Network [OSTI]

Commonly used preparation method for thin diamond membranes by focused ion beam (FIB) techniques results in surface damage. Here, the authors introduce an alternative method based on reactive ion etching (RIE). To compare ...

Li, Luozhou

162

90Sr liquid scintillation urine analysis utilizing different approaches for tracer recovery.  

SciTech Connect (OSTI)

90Sr is one of the isotopes most commonly produced by nuclear fission. This medium lived isotope presents serious challenges to radiation workers, the environment, and following a nuclear event, the general public. Methods of identifying this nuclide have been in existence for a number of years (e.g. Horwitz, E.P. [1], Maxwell, S.L.[2], EPA 905.0 [3]) which are time consuming, requiring a month or more for full analysis. This time frame is unacceptable in the present security environment. It is therefore important to have a dependable and rapid method for the determination of Sr. The purposes of this study are to reduce analysis time to less than half a day by utilizing a single method of radiation measurement while continuing to yield precise results. This paper presents findings on three methods that can meet this criteria; (1) stable Sr carrier, (2) 85Sr by gamma spectroscopy, and (3) 85Sr by LSC. Two methods of analyzing and calculating the 85Sr tracer recovery were investigated (gamma spectroscopy and a low energy window-Sr85LEBAB by LSC) as well as the use of two different types of Sr tracer (85Sr and stable Sr carrier). Three separate stock blank urine samples were spiked with various activity levels of 239Pu, 137Cs, 90Sr /90Y to determine the effectiveness of the Eichrome Sr-spec%C2%AE resin 2mL extractive columns. The objective was to compare the recoveries of 85Sr versus a stable strontium carrier, attempt to compare the rate at which samples can be processed by evaluating evaporation, neutralization, and removing the use of another instrument (gamma spectrometer) by using the LSC spectrometer to obtain 85Sr recovery. It was found that when using a calibration curve comprised of a different cocktail and a non-optimum discriminator setting reasonable results (bias of %C2%B1 25%) were achieved. The results from spiked samples containing 85Sr demonstrated that a higher recovery is obtained when using gamma spectroscopy (89-95%) than when using the LEB window from LSC (120-470%). The high recovery for 85Sr by LSC analysis may be due to the interference/cross talk from the alpha region since alpha counts were observed in all sample sets. After further investigation it was determined that the alpha counts were due to 239Pu breakthrough on the Sr-spec%C2%AE column. This requires further development to purify the Sr before an accurate tracer recovery determination can be made. Sample preparation times varied and ranged from 4-6 hours depending on the specific sample preparation process. The results from the spiked samples containing stable strontium nitrate Sr(NO3)2 carrier demonstrate that gravimetric analysis yields the most consistent high recoveries (97-101%) when evaporation is carefully performed. Since this method did not have a variation on the tracer recovery method, the samples were counted in 1) LEB/Alpha/Beta mode optimized for Sr-90, 2) DPM for Sr-90, and 3) general LEB/Alpha/Beta mode. The results (from the known) ranged from 79-104%, 107-177%, and 85-89% for 1, 2, and 3 respectively. Counting the prepared samples in a generic low energy beta/alpha/beta protocol yielded more accurate and consistent results and also yielded the shortest sample preparation turn-around-time of 3.5 hours.

Piraner, Olga [Centers for Disease Control and Prevention, Atlanta, GA; Preston, Rose T. [Sandia Staffing Alliance, LLC, Albuquerque, NM; Shanks, Sonoya Toyoko; Jones, Robert [Centers for Disease Control and Prevention, Atlanta, GA

2010-08-01T23:59:59.000Z

163

Interpretation of Colloid-Homologue Tracer Test 10-03, Including Comparisons to Test 10-01  

SciTech Connect (OSTI)

This presentation covers the interpretations of colloid-homologue tracer test 10-03 conducted at the Grimsel Test Site, Switzerland, in 2010. It also provides a comparison of the interpreted test results with those of tracer test 10-01, which was conducted in the same fracture flow system and using the same tracers than test 10-03, but at a higher extraction flow rate. A method of correcting for apparent uranine degradation in test 10-03 is presented. Conclusions are: (1) Uranine degradation occurred in test 10-03, but not in 10-01; (2) Uranine correction based on apparent degradation rate in injection loop in test 11-02 seems reasonable when applied to data from test 10-03; (3) Colloid breakthrough curves quite similar in the two tests with similar recoveries relative to uranine (after correction); and (4) Much slower apparent desorption of homologues in test 10-03 than in 10-01 (any effect of residual homologues from test 10-01 in test 10-03?).

Reimus, Paul W. [Los Alamos National Laboratory

2012-06-26T23:59:59.000Z

164

Wear Measurement of Highly Cross-linked UHMWPE using a 7Be Tracer Implantation Technique  

SciTech Connect (OSTI)

The very low wear rates achieved with the current highly cross-linked ultrahigh molecular weight polyethylenes (UHMWPE) used in joint prostheses have proven to be difficult to measure accurately by gravimetry. Tracer methods are there- fore being explored. The purpose of this study was to perform a proof-of-concept experiment on the use of the radioactive tracer beryllium-7 (7Be) for the determination of in vitro wear in a highly cross-linked orthopedic UHMWPE. Three cross-linked and four conventional UHMWPE pins made from compression- molded GUR 1050, were activated with 109 to 1010 7Be nuclei using a new implantation setup that produced a homogenous distribution of implanted nuclei up to 8.5 lm below the surface. The pins were tested for wear in a six-station pin-on-flat appara- tus for up to 7.1 million cycles (178 km). A Germanium gamma detector was employed to determine activity loss of the UHMWPE pins at preset intervals during the wear test. The wear of the cross-linked UHMWPE pins was readily detected and esti- mated to be 17 6 3 lg per million cycles. The conventional-to- cross-linked ratio of the wear rates was 13.1 6 0.8, in the expected range for these materials. Oxidative degradation dam- age from implantation was negligible; however, a weak depend- ence of wear on implantation dose was observed limiting the number of radioactive tracer atoms that can be introduced. Future applications of this tracer technology may include the analysis of location-specific wear, such as loss of material in the post or backside of a tibial insert.

Wimmer, Markus A. [Rush Uniiv. Medical Center; Laurent, Michael P. [Rush Univ. Medical Center; Dwivedi, Yasha [Rush Univ. Medical Center; Gallardo, Luis A. [Rush Univ. Medical Center; Chipps, K. [Colorado School of Mines, Golden; Blackmon, Jeffery C [Louisiana State University; Kozub, R. L. [Tennessee Technological University; Bardayan, Daniel W [ORNL; Gross, Carl J [ORNL; Stracener, Daniel W [ORNL; Smith, Michael Scott [ORNL; Nesaraja, Caroline D [ORNL; Erikson, Luke [Colorado School of Mines, Golden; Patel, Nidhi [Colorado School of Mines, Golden; Rehm, Karl E. [Argonne National Laboratory (ANL); Ahmad, Irshad [Argonne National Laboratory (ANL); Greene, John P. [Argonne National Laboratory (ANL); Greife, Uwe [Colorado School of Mines, Golden

2013-01-01T23:59:59.000Z

165

COMPARISON OF THREE TRACER TESTS AT THE RAFT RIVER GEOTHERMAL SITE  

SciTech Connect (OSTI)

Three conservative tracer tests have been conducted through the Bridge Fault fracture zone at the Raft River Geothermal (RRG) site. All three tests were conducted between injection well RRG-5 and production wells RRG-1 (790 m distance) and RRG-4 (740 m distance). The injection well is used during the summer months to provide pressure support to the production wells. The first test was conducted in 2008 using 136 kg of fluorescein tracer. Two additional tracers were injected in 2010. The first 2010 tracer injected was 100 kg fluorescein disodium hydrate salt on June, 21. The second tracer (100 kg 2,6-naphthalene disulfonic acid sodium salt) was injected one month later on July 21. Sampling of the two productions wells is still being performed to obtain the tail end of the second 2010 tracer test. Tracer concentrations were measured using HPLC with a fluorescence detector. Results for the 2008 test, suggest 80% tracer recover at the two production wells. Of the tracer recovered, 85% of tracer mass was recovered in well RRG-4 indicating a greater flow pathway connection between injection well and RRG-4 than RRG-1. Fluorescein tracer results appear to be similar between the 2008 and 2010 tests for well RRG-4 with peak concentrations arriving approximately 20 days after injection despite the differences between the injection rates for the two tests (~950 gpm to 475 gpm) between the 2008 and 2010. The two 2010 tracer tests will be compared to determine if the results support the hypothesis that rock contraction along the flow pathway due to the 55 oC cooler water injection alters the flow through the ~140 oC reservoir.

Earl D Mattson; Mitchell Plummer; Carl Palmer; Larry Hull; Samantha Miller; Randy Nye

2011-02-01T23:59:59.000Z

166

Determination of water saturation using gas phase partitioning tracers and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesData FilesShape, Density,TiO2(110). |Gas-phase Tracer

167

Sandia National Laboratories: tracer studies integrated with geophysical  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbineredox-activeNational SolartSSLPV materialsmethods tracer

168

Determination of Water Saturation in Relatively Dry Porous Media Using Gas-phase Tracer Tests  

SciTech Connect (OSTI)

Soil desiccation (drying), involving water evaporation induced by dry air injection and extraction, is a potentially robust remediation process to slow migration of inorganic or radionuclide contaminants through the vadose zone. The application of gas-phase partitioning tracer tests has been proposed as a means to estimate initial water volumes and to monitor the progress of the desiccation process at pilot-test and field sites. In this paper, tracer tests have been conducted in porous medium columns with various water saturations using sulfur hexafluoride as the conservative tracer and tricholorofluoromethane and difluoromethane as the water-partitioning tracers. For porous media with minimal silt and/or organic matter fractions, tracer tests provided reasonable saturation estimates for saturations close to zero. However, for sediments with significant silt and/or organic matter fractions, tracer tests only provided satisfactory results when the water saturation was at least 0.1 - 0.2. For dryer conditions, the apparent tracer retardation increases due to air – soil sorption, which is not included in traditional retardation coefficients derived from advection-dispersion equations accounting only for air – water partitioning and water – soil sorption. Based on these results, gas-phase partitioning tracer tests may be used to determine initial water volumes in sediments, provided the initial water saturations are sufficiently large. However, tracer tests are not suitable for quantifying moisture content in desiccated sediments.

Oostrom, Martinus; Tartakovsky, Guzel D.; Wietsma, Thomas W.; Truex, Michael J.; Dane, Jacob H.

2011-04-15T23:59:59.000Z

169

Calcium translocation and whole plant transpiration: spatial and temporal measurements using radio-Strontium as tracer  

E-Print Network [OSTI]

comparison with zinc, strontium and rubidium. Annals of783- Wasserman RH. 1998. Strontium as a tracer for calciumor inapplicable. As Strontium (Sr) was found to behave in

Seligmann, Ron; Wengrowicz, Udi; Tirosh, Danny; Yermiyahu, Uri; Bar-Tal, Asher; Schwartz, Amnon

2009-01-01T23:59:59.000Z

170

Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. The objective of this project is to develop a matrix of the smart geothermal tracer and its interpretation tools.

171

E-Print Network 3.0 - activity optimal tracers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AND AMOC Abstract Current projections of the oceanic response... in current Earth system models and (ii) imperfect knowledge of model parameters. Ocean tracers observa- tions...

172

Steam tracer experiment at the Hoe Creek No. 3 underground coal gasification field test  

SciTech Connect (OSTI)

Water plays an important role in in-situ coal gasification. To better understand this role, we conducted a steam tracer test during the later stages of the Hoe Creek No. 3 underground coal gasification field test. Deuterium oxide was used as the tracer. This report describes the tracer test and the analysis of the data obtained. The analysis indicates that at Hoe Creek the injected steam interacts with a large volume of water as it passes through the underground system. We hypothesize that this water is undergoing continual reflux in the underground system, resulting in a tracer response typical of a well-stirred tank.

Thorsness, C.B.

1980-11-26T23:59:59.000Z

173

MEASURING REACTIVE MARKET POWER Fernando L. Alvarado Thomas Overbye Peter Sauer  

E-Print Network [OSTI]

MEASURING REACTIVE MARKET POWER Fernando L. Alvarado Thomas Overbye Peter Sauer The University-Hirschman Index) can be used to measure reactive power market concentration. The proposed method is illustrated by means of a simple example. Keywords: Electric power transmission, monopoly, mar- ket concentration. 1

174

Learning Reactive Neurocontrollers using Simulated Annealing for Mobile Philippe Lucidarme, Alain Ligeois  

E-Print Network [OSTI]

Learning Reactive Neurocontrollers using Simulated Annealing for Mobile Robots Philippe Lucidarme a method based on simulated annealing to learn reactive behaviors. This work is related with multi is a neural network and we use a simulated annealing techniques to learn the synaptic weights. We'll first

Paris-Sud XI, Université de

175

Particle Swarm Optimization Based Reactive Power Optimization  

E-Print Network [OSTI]

Reactive power plays an important role in supporting the real power transfer by maintaining voltage stability and system reliability. It is a critical element for a transmission operator to ensure the reliability of an electric system while minimizing the cost associated with it. The traditional objectives of reactive power dispatch are focused on the technical side of reactive support such as minimization of transmission losses. Reactive power cost compensation to a generator is based on the incurred cost of its reactive power contribution less the cost of its obligation to support the active power delivery. In this paper an efficient Particle Swarm Optimization (PSO) based reactive power optimization approach is presented. The optimal reactive power dispatch problem is a nonlinear optimization problem with several constraints. The objective of the proposed PSO is to minimize the total support cost from generators and reactive compensators. It is achieved by maintaining the whole system power loss as minimum...

Sujin, P R; Linda, M Mary

2010-01-01T23:59:59.000Z

176

Reactive Power Support Services in Electricity Markets  

E-Print Network [OSTI]

Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Final Project Report Power Systems Engineering Research Center A National Science Foundation Industry Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Project

177

Engine combustion control via fuel reactivity stratification  

DOE Patents [OSTI]

A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choose the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

2013-12-31T23:59:59.000Z

178

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

179

Reactive materials can quickly form plugs for blowout control  

SciTech Connect (OSTI)

Various types of reactive materials, or gunk, can react directly with produced fluids (oil, condensate, or brine) or with an additionally injected fluid to form a plug to kill blowout wells or shut off large flow paths. Several recent blowouts were successfully controlled with reactive plugs; other conventional methods would have been more difficult operationally and cost more. Several plug mixtures are available on the market and can be made to suit the type of application and any particular environmental concerns. With proper planning and application, reactive plugs should be considered as a prime well control method when injection into the blowout flow path is available. This method of blowout control can save significant time and expense. The paper discusses the two basic methods of using reactive fluids depending on the flow path available, the use of cements, application steps, environmental concerns, and three case histories: a horizontal well in Texas, a high pressure, high temperature well offshore Louisiana, and a gas blowout in Argentina.

Flak, L.H. [Wright Boots and Coots, Houston, TX (United States)

1995-04-17T23:59:59.000Z

180

Substituent Effects on the Reactivity of the Silicon-Carbon  

E-Print Network [OSTI]

Canada L8S 4M1 Received April 28, 2000 ABSTRACT Laser flash photolysis of various organosilicon compounds as a reactive intermediate in the high-temperature pyrolysis of a silacyclobutane deriva- tive.9 Hundreds describes our efforts to employ these techniquess laser flash photolysis methods in particularsto study

Leigh, William J.

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Plasma & reactive ion etching to prepare ohmic contacts  

DOE Patents [OSTI]

A method of making a low-resistance electrical contact between a metal and a layer of p-type CdTe surface by plasma etching and reactive ion etching comprising: a) placing a CdS/CdTe layer into a chamber and evacuating said chamber; b) backfilling the chamber with Argon or a reactive gas to a pressure sufficient for plasma ignition; and c) generating plasma ignition by energizing a cathode which is connected to a power supply to enable the plasma to interact argon ions alone or in the presence of a radio-frequency DC self-bias voltage with the p-CdTe surface.

Gessert, Timothy A. (Conifer, CO)

2002-01-01T23:59:59.000Z

182

Estimation of tracer diffusion coefficients of ions in aqueous solution  

SciTech Connect (OSTI)

Equations are given for estimating tracer diffusion coefficients D/sub i//sup 0/ of ions at infinite dilution in terms of limiting ionic conductances ..lambda../sub i//sup 0/. Also given are generalized Nernst-Hartley equations for binary and multicomponent diffusion coefficients D/sup 0/ and D/sub ij//sup 0/, respectively, at infinite dilution. Data, estimates, and correlations for ..lambda../sub i//sup 0/ at 25/sup 0/C and other temperatures are discussed. Estimated values of ..lambda../sub i//sup 0/ are tabulated from 0-300/sup 0/C for ions of waste isolation interest and for ions of economic interest in geothermal brines. Estimates of their tracer diffusion coefficients at infinite dilution are tabulated. A rule of thumb, good to a factor of 2, is presented. Very limited data (available only at 25/sup 0/C) indicate that D/sub i//D/sub i//sup 0/ generally declines as the concentration of salt or supporting electrolyte increases. 6 figures, 2 tables.

Miller, D.G.

1982-09-07T23:59:59.000Z

183

Apparatus for making environmentally stable reactive alloy powders  

DOE Patents [OSTI]

Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

1996-12-31T23:59:59.000Z

184

Systems and methods for forming defects on graphitic materials and curing radiation-damaged graphitic materials  

DOE Patents [OSTI]

Systems and methods are disclosed herein for forming defects on graphitic materials. The methods for forming defects include applying a radiation reactive material on a graphitic material, irradiating the applied radiation reactive material to produce a reactive species, and permitting the reactive species to react with the graphitic material to form defects. Additionally, disclosed are methods for removing defects on graphitic materials.

Ryu, Sunmin; Brus, Louis E.; Steigerwald, Michael L.; Liu, Haitao

2012-09-25T23:59:59.000Z

185

A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 SouthWater Rights,Information Of The Transiel Method On The

186

Numerical study of the diapycnal flow through a tidal front with passive tracers  

E-Print Network [OSTI]

. This qualitatively agrees with a recent field experiment using a dye tracer on Georges Bank. Additional experiments are performed to investigate the sensitivity of the tracer dispersion to the tidal phase and the location, the previous studies indicated Eulerian cross-front mean circu- lation maybe is in a multiple-cell structure

Dong, Changming "Charles"

187

SOURCES AND EFFECTS OF MINING-RELATED AND NATURAL ACID ROCK DRAINAGE QUANTIFIED USING TRACER  

E-Print Network [OSTI]

SOURCES AND EFFECTS OF MINING-RELATED AND NATURAL ACID ROCK DRAINAGE QUANTIFIED USING TRACER, and Architectural Engineering 2006 #12;ii This thesis entitled: Sources and Effects of Mining-Related and Natural Acid Rock Drainage Quantified Using Tracer Dilution, Coal Creek Watershed, Gunnison County, Colorado

Ryan, Joe

188

A dye tracer reveals cross-shelf dispersion and interleaving on the Oregon shelf  

E-Print Network [OSTI]

A dye tracer reveals cross-shelf dispersion and interleaving on the Oregon shelf A. C. Dale,1 M. D December 2005; published 3 February 2006. [1] A fluorescent dye tracer was injected into the pycnocline the other in the water column, split by interleaving dye-free water. The vertical scale of these layers

Kurapov, Alexander

189

Verification of flow processes in soils with combined sprinkling and dye tracer experiments  

E-Print Network [OSTI]

1 Verification of flow processes in soils with combined sprinkling and dye tracer experiments with sprinkling experiments and dye tracing under different rainfall intensities and soil moisture conditions. The dye tracer was continuously applied with the sprinkling water on 1 m2 plots. After the sprinkling

Weiler, Markus

190

Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period  

E-Print Network [OSTI]

Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period R (2006), Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period histories from ice coring of Greenland and Antarctica over the period 2 to 45 ka, using SO4 anomalies

Price, P. Buford

191

Slew-rate dependence of tracer magnetization response in magnetic particle imaging  

SciTech Connect (OSTI)

Magnetic Particle Imaging (MPI) is a new biomedical imaging technique that produces real-time, high-resolution tomographic images of superparamagnetic iron oxide nanoparticle tracers. Currently, 25?kHz and 20?mT/?{sub 0} excitation fields are common in MPI, but lower field amplitudes may be necessary for patient safety in future designs. Here, we address fundamental questions about MPI tracer magnetization dynamics and predict tracer performance in future scanners that employ new combinations of excitation field amplitude (H{sub o}) and frequency (?). Using an optimized, monodisperse MPI tracer, we studied how several combinations of drive field frequencies and amplitudes affect the tracer's response, using Magnetic Particle Spectrometry and AC hysteresis, for drive field conditions at 15.5, 26, and 40.2?kHz, with field amplitudes ranging from 7 to 52?mT/?{sub 0}. For both fluid and immobilized nanoparticle samples, we determined that magnetic response was dominated by Néel reversal. Furthermore, we observed that the peak slew-rate (?H{sub o}) determined the tracer magnetic response. Smaller amplitudes provided correspondingly smaller field of view, sometimes resulting in excitation of minor hysteresis loops. Changing the drive field conditions but keeping the peak slew-rate constant kept the tracer response almost the same. Higher peak slew-rates led to reduced maximum signal intensity and greater coercivity in the tracer response. Our experimental results were in reasonable agreement with Stoner-Wohlfarth model based theories.

Shah, Saqlain A.; Krishnan, K. M., E-mail: kannanmk@uw.edu [Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States); Ferguson, R. M. [LodeSpin Labs, P.O. Box 95632, Seattle, Washington 98145 (United States)

2014-10-28T23:59:59.000Z

192

Heat as a tracer to determine streambed water exchanges Jim Constantz1  

E-Print Network [OSTI]

Heat as a tracer to determine streambed water exchanges Jim Constantz1 Received 13 March 2008 of heat as a tracer of shallow groundwater movement and describes current temperature-based approaches relying on traditional observation wells, and remote sensing and other large-scale advanced temperature

193

SAND TRACER MOVEMENT MEASURED IN A STRONG RIP CURRENT Nicholas C. Kraus  

E-Print Network [OSTI]

exceeding 50 cm/sec in areas where instruments could be placed. Three colors of sand tracer were injected the diver's signal, a float tied to the diver's wrist was released and allowed to flow with the current because of the cold water, placed instruments, injected the tracer, and sampled the bottom with ropes tied

US Army Corps of Engineers

194

Curvature Induced Activation of a Passive Tracer in an Active Bath  

E-Print Network [OSTI]

We use numerical simulations to study the motion of a large asymmetric tracer immersed in a low density suspension of self-propelled nanoparticles in two dimensions. Specifically, we analyze how the curvature of the tracer affects its translational and rotational motion in an active environment. We find that even very small amounts of curvature are sufficient for the active bath to impart directed motion to the tracer which results in its effective activation. We propose simple scaling arguments to characterize this induced activity in terms of the curvature of the tracer and the strength of the self-propelling force. Our results suggest new ways of controlling the transport properties of passive tracers in an active medium by carefully tailoring their geometry.

S. A. Mallory; C. Valeriani; A. Cacciuto

2014-09-25T23:59:59.000Z

195

L\\'evy Fluctuations and Tracer Diffusion in Dilute Suspensions of Algae and Bacteria  

E-Print Network [OSTI]

Swimming microorganisms rely on effective mixing strategies to achieve efficient nutrient influx. Recent experiments, probing the mixing capability of unicellular biflagellates, revealed that passive tracer particles exhibit anomalous non-Gaussian diffusion when immersed in a dilute suspension of self-motile Chlamydomonas reinhardtii algae. Qualitatively, this observation can be explained by the fact that the algae induce a fluid flow that may occasionally accelerate the colloidal tracers to relatively large velocities. A satisfactory quantitative theory of enhanced mixing in dilute active suspensions, however, is lacking at present. In particular, it is unclear how non-Gaussian signatures in the tracers' position distribution are linked to the self-propulsion mechanism of a microorganism. Here, we develop a systematic theoretical description of anomalous tracer diffusion in active suspensions, based on a simplified tracer-swimmer interaction model that captures the typical distance scaling of a microswimmer'...

Zaid, Irwin M; Yeomans, Julia M

2010-01-01T23:59:59.000Z

196

A General Solid Phase Method for the Preparation of Diverse Azapeptide  

E-Print Network [OSTI]

the incorporation of diverse reactive warheads linked to different peptide recognition elements. Application warhead groups linked to peptide recognition elements carrying tags, such as fluoro- phores, biotin, or radioactive tracers.6 However, to develop novel, highly specific probes for application to functional

Bogyo, Matthew

197

Using Biofuel Tracers to Study Alternative Combustion Regimes  

SciTech Connect (OSTI)

Interest in the use of alternative fuels and combustion regimes is increasing as the price of petroleum climbs. The inherently higher efficiency of Diesel engines has led to increased adoption of Diesels in Europe, capturing approximately 40% of the new passenger car market. Unfortunately, lower CO{sub 2} emissions are countered with higher nitrogen oxides (NOx) and particulate matter (PM) emissions, and higher noise. Noise and PM have traditionally been the obstacles toward consumer acceptance of Diesel passenger cars in North America, while NOx (a key component in photochemical smog) has been more of an engineering challenge. Diesels are lean burning (combustion with excess oxygen) and reducing NOx to N2 in an oxygen rich environment is difficult. Adding oxygenated compounds to the fuel helps reduce PM emissions, but relying on fuel alone to reduce PM is unrealistic. Keeping peak combustion temperature below 1700 K prevents NOx formation. Altering the combustion regime to burn at temperatures below the NOx threshold and accept a wide variety of fuels seems like a promising alternative for future engines. Homogeneous Charge Compression Ignition (HCCI) is a possible solution. Fuel and air are well mixed prior to intake into a cylinder (homogeneous charge) and ignition occurs by compression of the fuel-air mixture by the piston. HCCI is rapid and relatively cool, producing little NOx and PM. Unfortunately, it is hard to control since HCCI is initiated by temperature and pressure instead of a spark or direct fuel injection. We investigate biofuel HCCI combustion, and use intrinsically labeled biofuels as tracers of HCCI combustion. Data from tracer experiments are used to validate combustion modeling.

Mack, J H; Flowers, D L; Buchholz, B A; Dibble, R W

2006-02-14T23:59:59.000Z

198

Deep Reactive Ion Etching | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct: CrudeOffice ofINL isSeparationsRelevantDeep Reactive Ion

199

Estimates of Tracer-Based Piston-Flow Ages of Groundwater From Selected Sites: National Water-Quality Assessment  

E-Print Network [OSTI]

Estimates of Tracer-Based Piston-Flow Ages of Groundwater From Selected Sites: National Water;Estimates of Tracer-Based Piston-Flow Ages of Groundwater from Selected Sites: National Water.N., Busenberg, Eurybiades, Widman, P.K., Casile, G.C., and Wayland, J.E., 2010, Estimates of tracer-based piston

200

Anisotropic reactive ion etching of vanadium dioxide  

E-Print Network [OSTI]

. Weichold Vanadium dioxide (V02) was anisotropically reactive ion etched using carbon tetrafluoride (CF4) . CF4, as an etch gas, provided the chemistry along with the control needed to achieve an anisotropic etch. This chemistry was practically inert... with vanadium quite easily. This leads to interest in using a fluorine- based chemistry. The goal of this research is to produce a selective anisotropic reactive ion etch for VO2 /photoresist using only carbon tetrafluoride (CFq) . Reactive ion etching...

Radle, Byron K

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Analysis of Injection-Backflow Tracer Tests in Fractured Geothermal Reservoirs  

SciTech Connect (OSTI)

Tracer tests have been an important technique for determining the flow and reservoir characteristics in various rock matrix systems. While the interwell tracer tests are aimed at the characterization of the regions between the wells, single-well injection-backflow tracer tests may be useful tools of preliminary evaluation, before implementing long term interwell tracer tests. This work is concerned with the quantitative evaluation of the tracer return profiles obtained from single well injection-backflow tracer tests. First, two mathematical models of tracer transport through fractures, have been reviewed. These two models are based on two different principles: Taylor Dispersion along the fracture and simultaneous diffusion in and out of the adjacent matrix. Then the governing equations for the transport during the injection-backflow tests have been solved. Finally the results were applied to field data obtained from Raft River and East Mesa geothermal fields. In order to determine the values of the parameters of the models that define the transport mechanisms through fractures a non-linear optimization technique was employed. 26 refs., 10 figs.

Kocabas, I.; Horne, R.N.

1987-01-20T23:59:59.000Z

202

Rejuvenating Permeable Reactive Barriers by Chemical Flushing  

Broader source: Energy.gov [DOE]

Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

203

Exploring the reactivity of bacterial multicomponent monooxygenases  

E-Print Network [OSTI]

Chapter 1. Introduction: The Reactivity of Bacterial Multicomponent Monooxygenases Bacterial multicomponent monooxygenases constitute a remarkable family of enzymes that oxidize small, inert hydrocarbon substrates using ...

Tinberg, Christine Elaine

2010-01-01T23:59:59.000Z

204

Permeable Reactive Barriers | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

react with a contaminant plume in ground water. Typically, PRBs are emplaced by replacing soils with reactive material in a trench cut through a contaminated ground water aquifer....

205

Non-Energetic Reactive Armor (NERA) and Semi-Energetic Reactive Armor (SERA) FY13 Final Report  

SciTech Connect (OSTI)

INL researchers have proposed prototypes for future lightweight armor systems that reside in a technology gap between explosive reactive armor and passive armor. The targets were designed to react under impact and throw a steel front plate into the path of the projectile, forcing the projectile to engage more of the front plate during its penetration process. These prototypes are intended to exhibit the enhanced efficiency of explosive reactive armor without the collateral damage often associated with explosive reactive armor. One of the prototype systems, Semi Energetic Reactive Armor (SERA), functions similarly to explosive reactive armor, but features a reactive material that reacts much slower than explosive reactive armor. Two different SERA test groups were built and featuring different ratios of aluminum Teflon(copyright) powders pressed into 0.5 in. thick energetic tiles and sandwiched between 0.25 in. thick RHA plates. The other prototype system, Non Energetic Reactive Armor (NERA), utilizes the strain energy in compressed rubber to launch a front flyer plate into the path of an incoming projectile. It is comprised of a 1 in. thick rubber layer sandwiched between two 0.25 in. thick RHA plates with bolt holes around the perimeter. Bolts are inserted through the entire target and tightened to compress the rubber sheet to significant strain levels (approximately 40%). A fourth group of targets was tested as a control group. It featured a 0.5 in. thick rubber sheet sandwiched between two 0.25 in. thick RHA plates, similar to the NERA test articles, but the rubber is uncompressed. The four test groups (uncompressed rubber, compressed rubber, 70/30 Al/PTFE, 50/50 Al/PTFE) were each fabricated with three identical test articles in each group. All twelve targets were subjected to ballistic testing at the National Security Test Range on July 17, 2013. They were tested with 0.5 in. diameter steel rods shot at a consistent velocity at each target. In order to characterize the energetic materials, break wires were embedded in the targets and burn velocities were measured. The residual mass method was used to compare the target performance of each group and final performance data is presented below.

Ben Langhorst; Nikki Rasmussen; Andrew Robinson

2013-08-01T23:59:59.000Z

206

A transport based one-dimensional perturbation code for reactivity calculations in metal systems  

SciTech Connect (OSTI)

A one-dimensional reactivity calculation code is developed using first order perturbation theory. The reactivity equation is based on the multi-group transport equation using the discrete ordinates method for angular dependence. In addition to the first order perturbation approximations, the reactivity code uses only the isotropic scattering data, but cross section libraries with higher order scattering data can still be used with this code. The reactivity code obtains all the flux, cross section, and geometry data from the standard interface files created by ONEDANT, a discrete ordinates transport code. Comparisons between calculated and experimental reactivities were done with the central reactivity worth data for Lady Godiva, a bare uranium metal assembly. Good agreement is found for isotopes that do not violate the assumptions in the first order approximation. In general for cases where there are large discrepancies, the discretized cross section data is not accurately representing certain resonance regions that coincide with dominant flux groups in the Godiva assembly. Comparing reactivities calculated with first order perturbation theory and a straight {Delta}k/k calculation shows agreement within 10% indicating the perturbation of the calculated fluxes is small enough for first order perturbation theory to be applicable in the modeled system. Computation time comparisons between reactivities calculated with first order perturbation theory and straight {Delta}k/k calculations indicate considerable time can be saved performing a calculation with a perturbation code particularly as the complexity of the modeled problems increase.

Wenz, T.R.

1995-02-01T23:59:59.000Z

207

Tracers for monitoring the activity of sodium/glucose cotransporters in health and disease  

DOE Patents [OSTI]

Radiolabeled tracers for sodium/glucose cotransporters (SGLTs), their synthesis, and their use are provided. The tracers are methyl or ethyl pyranosides having an equatorial hydroxyl group at carbon-2 and a C 1 preferred conformation, radiolabeled with .sup.18F, .sup.123I, or .sup.124I, or free hexoses radiolabeled with .sup.18F, .sup.123I, or .sup.124. Also provided are in vivo and in vitro techniques for using these and other tracers as analytical and diagnostic tools to study glucose transport, in health and disease, and to evaluate therapeutic interventions.

Wright, Ernest M; Barrio, Jorge R; Hirayama, Bruce A; Kepe, Vladimir

2014-09-30T23:59:59.000Z

208

Environmental Tracers for Determining Water Resource Vulnerability to Climate Change  

SciTech Connect (OSTI)

Predicted changes in the climate will have profound impacts on water availability in the Western US, but large uncertainties exist in our ability to predict how natural and engineered hydrological systems will respond. Most predictions suggest that the impacts of climate change on California water resources are likely to include a decrease in the percentage of precipitation that falls as snow, earlier onset of snow-pack melting, and an increase in the number of rain on snow events. These processes will require changes in infrastructure for water storage and flood control, since much of our current water supply system is built around the storage of winter precipitation as mountain snow pack. Alpine aquifers play a critical role by storing and releasing snowmelt as baseflow to streams long after seasonal precipitation and the disappearance of the snow pack, and in this manner significantly impact the stream flow that drives our water distribution systems. Mountain groundwater recharge and, in particular, the contribution of snowmelt to recharge and baseflow, has been identified as a potentially significant effect missing from current climate change impact studies. The goal of this work is to understand the behavior of critical hydrologic systems, with an emphasis on providing ground truth for next generation models of climate-water system interactions by implementing LLNL capabilities in environmental tracer and isotopic science. We are using noble gas concentrations and multiple isotopic tracers ({sup 3}H/{sup 3}He, {sup 35}S, {sup 222}Rn, {sup 2}H/{sup 1}H, {sup 18}O/{sup 16}O, and {sup 13}C/{sup 12}C) in groundwater and stream water in a small alpine catchment to (1) provide a snapshot of temperature, altitude, and physical processes at the time of recharge, (2) determine subsurface residence times (over time scales ranging from months to decades) of different groundwater age components, and (3) deconvolve the contribution of these different groundwater components to alpine stream baseflow. This research is showing that groundwater in alpine areas spends between a few years to several decades in the saturated zone below the surface, before feeding into streams or being pumped for use. This lag time may act to reduce the impact on water resources from extreme wet or dry years. Furthermore, our measurements show that the temperature of water when it reaches the water table during recharge is 4 to 9 degrees higher than would be expected for direct influx of snowmelt, and that recharge likely occurs over diffuse vegetated areas, rather than along exposed rock faces and fractures. These discoveries have implications for how alpine basins will respond to climate effects that lead to more rain than snow and earlier snow pack melting.

Singleton, M

2009-07-08T23:59:59.000Z

209

Tracer diffusion in compacted, water-saturated bentonite  

SciTech Connect (OSTI)

Compacted Na-bentonite clay barriers, widely used in theisolation of solid-waste landfills and other contaminated sites, havebeen proposed for a similar use in the disposal of high-level radioactivewaste. Molecular diffusion through the pore space in these barriers playsa key role in their performance, thus motivating recent measurements ofthe apparent diffusion coefficient tensor of water tracers in compacted,water-saturated Na-bentonites. In the present study, we introduce aconceptual model in which the pore space of water-saturated bentonite isdivided into 'macropore' and 'interlayer nanopore' compartments. Withthis model we determine quantitatively the relative contributions ofpore-network geometry (expressed as a geometric factor) and of thediffusive behavior of water molecules near montmorillonite basal surfaces(expressed as a contristivity factor) to the apparent diffusioncoefficient tensor. Our model predicts, in agreement with experiment,that the mean principal value of the apparent diffusion coefficienttensor follows a single relationship when plotted against the partialmontmorillonite dry density (mass of montmorillonite per combined volumeof montmorillonite and pore space). Using a single fitted parameter, themean principal geometric factor, our model successfully describes thisrelationship for a broad range of bentonite-water system, from dilute gelto highly-compacted bentonite with 80 percent of its pore water ininterlayer nanopores.

Bourg, Ian C.; Sposito, Garrison; Bourg, Alain C.M.

2005-08-04T23:59:59.000Z

210

REACTIVE LOAD MODELINGIMPACTS ONNODAL PRICESINPOOL MODELELECTRICITYMARKETS  

E-Print Network [OSTI]

REACTIVE LOAD MODELINGIMPACTS ONNODAL PRICESINPOOL MODELELECTRICITYMARKETS EttoreBompard, Enrico of the nodal prices in competitive electricity markets based on the Pool paradigm. Such prices focus of the paper is on the explicit evaluation of the impactsof the reactive load onthenodal real

Gross, George

211

REACTIVE ENVIRONMENTS AND AUGMENTED MEDIA SPACES  

E-Print Network [OSTI]

REACTIVE ENVIRONMENTS AND AUGMENTED MEDIA SPACES by Jeremy R. Cooperstock A thesis submitted in conformity with the requirements for the degree of Doctor of Philosophy Graduate Department of Electrical and Computer Engineering University of Toronto © Copyright by Jeremy R. Cooperstock, 1996 #12;ii REACTIVE

Cooperstock, Jeremy R.

212

Radium isotopes as tracers of coastal circulation pathways in the Mid-Atlantic Blight  

E-Print Network [OSTI]

Pathways of exchange between the shelf and slope in the Mid-Atlantic Bight were investigated using a combination of radiochemical tracer and hydrographic measurements. The motivation was to provide evidence of transport ...

Rasmussen, Linda L

2003-01-01T23:59:59.000Z

213

The use of tracers to analyze the effects of reinjection into fractured geothermal reservoirs  

SciTech Connect (OSTI)

This paper discusses the use of tracers as a reservoir engineering tool in fractured geothermal reservoirs. The principle concern in injecting cooler spent fluids into a fractured reservoir is that the fluids may move through high permeability channels and return to the production wells after contacting a relatively small volume of rock. As a consequence of this rapid transport, the fluids will be only partially reheated and after a short period time will effectively mine the heat from the limited volume of rock. The production wells will then experience a rapid and premature reduction in thermal output. Tracers can be used to infer the existence of high mobility conduits between injection and production wells and to monitor chemical changes of an injected fluid. Since tracer arrival precedes thermal breakthrough, tracer tests are a very useful forecasting tool.

Horne, R.N.; Johns, R.A.; Adams, M.C.; Moore, J.N.; Stiger, S.G.

1987-01-01T23:59:59.000Z

214

Dynamic Reservoir Characterization Of Naturally Fractured Reservoirs From An Inter-Well Tracer Test  

E-Print Network [OSTI]

After field redevelopment in the Sherrod Unit of the Spraberry Trend Area, an inter-well tracer test was conducted at the field scale in order to understand the fracture system, which forms preferential flow paths for better management...

Kilicaslan, Ufuk

2013-12-03T23:59:59.000Z

215

Development of Models to Simulate Tracer Behavior in Enhanced Geothermal Systems  

SciTech Connect (OSTI)

A recent report found that power and heat produced from engineered (or enhanced) geothermal systems (EGSs) could have a major impact on the United States while incurring minimal environmental impacts. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distributions, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for commercial development of geothermal energy. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. Modeling capabilities are being developed as part of this project to support laboratory and field testing to characterize engineered geothermal systems in single- and multi-well tests using tracers. The objective of this report is to describe the simulation plan and the status of model development for simulating tracer tests for characterizing EGS.

Williams, Mark D.; Vermeul, Vincent R.; Reimus, P. W.; Newell, D.; Watson, Tom B.

2010-06-01T23:59:59.000Z

216

Author's personal copy Thorium-234 as a tracer of spatial, temporal and vertical variability  

E-Print Network [OSTI]

Author's personal copy Thorium-234 as a tracer of spatial, temporal and vertical variability 2009 Accepted 6 April 2009 Available online 16 April 2009 Keywords: Thorium-234 Particle flux Sediment

Buesseler, Ken

217

CHEMICAL TRACER RETENTION IN POROUS MEDIA Submitted to the Department of Petroleum Engineering  

E-Print Network [OSTI]

* CHEMICAL TRACER RETENTION IN POROUS MEDIA A Report Submitted to the Department of Petroleum Engineering of Stanford University in Fulfillment of the Requirement for the Degree of Master of Science

Stanford University

218

Assessment of Controlling Processes for Field-Scale Uranium Reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at the 300A site. However, the model simulations also revealed that the groundwater chemistry was relatively stable during the uranium tracer experiment and therefore...

219

Glass mixing theory and tracer study results from the SF-10 run  

SciTech Connect (OSTI)

A general, partial differential equation governing glass mixing in the Slurry Fed Ceramic Melter (SFCM) was derived and a solution obtained based upon certain simplifying assumptions. Tracer studies were then conducted in the SFCM during the SF-10 run to test the theory and characterize glass mixing in this melter. Analysis of the tracer data shows that glass mixing in the SFCM can be explained by use of a model of two, well-mixed tanks in series.

Bowman, B.W.; Routt, K.R.

1988-08-01T23:59:59.000Z

220

Analysis of Reactivity Induced Accident for Control Rods Ejection with Loss of Cooling  

E-Print Network [OSTI]

Understanding of the time-dependent behavior of the neutron population in nuclear reactor in response to either a planned or unplanned change in the reactor conditions, is a great importance to the safe and reliable operation of the reactor. In the present work, the point kinetics equations are solved numerically using stiffness confinement method (SCM). The solution is applied to the kinetics equations in the presence of different types of reactivities and is compared with different analytical solutions. This method is also used to analyze reactivity induced accidents in two reactors. The first reactor is fueled by uranium and the second is fueled by plutonium. This analysis presents the effect of negative temperature feedback with the addition positive reactivity of control rods to overcome the occurrence of control rod ejection accident and damaging of the reactor. Both power and temperature pulse following the reactivity- initiated accidents are calculated. The results are compared with previous works and satisfactory agreement is found.

Hend Mohammed El Sayed Saad; Hesham Mohammed Mohammed Mansour; Moustafa Aziz Abd El Wahab

2013-06-05T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Analysis of Reactivity Induced Accident for Control Rods Ejection with Loss of Cooling  

E-Print Network [OSTI]

Understanding of the time-dependent behavior of the neutron population in nuclear reactor in response to either a planned or unplanned change in the reactor conditions, is a great importance to the safe and reliable operation of the reactor. In the present work, the point kinetics equations are solved numerically using stiffness confinement method (SCM). The solution is applied to the kinetics equations in the presence of different types of reactivities and is compared with different analytical solutions. This method is also used to analyze reactivity induced accidents in two reactors. The first reactor is fueled by uranium and the second is fueled by plutonium. This analysis presents the effect of negative temperature feedback with the addition positive reactivity of control rods to overcome the occurrence of control rod ejection accident and damaging of the reactor. Both power and temperature pulse following the reactivity- initiated accidents are calculated. The results are compared with previous works and...

Saad, Hend Mohammed El Sayed; Wahab, Moustafa Aziz Abd El

2013-01-01T23:59:59.000Z

222

Lévy Fluctuations and Tracer Diffusion in Dilute Suspensions of Algae and Bacteria  

E-Print Network [OSTI]

Swimming microorganisms rely on effective mixing strategies to achieve efficient nutrient influx. Recent experiments, probing the mixing capability of unicellular biflagellates, revealed that passive tracer particles exhibit anomalous non-Gaussian diffusion when immersed in a dilute suspension of self-motile Chlamydomonas reinhardtii algae. Qualitatively, this observation can be explained by the fact that the algae induce a fluid flow that may occasionally accelerate the colloidal tracers to relatively large velocities. A satisfactory quantitative theory of enhanced mixing in dilute active suspensions, however, is lacking at present. In particular, it is unclear how non-Gaussian signatures in the tracers' position distribution are linked to the self-propulsion mechanism of a microorganism. Here, we develop a systematic theoretical description of anomalous tracer diffusion in active suspensions, based on a simplified tracer-swimmer interaction model that captures the typical distance scaling of a microswimmer's flow field. We show that the experimentally observed non-Gaussian tails are generic and arise due to a combination of truncated L\\'evy statistics for the velocity field and algebraically decaying time correlations in the fluid. Our analytical considerations are illustrated through extensive simulations, implemented on graphics processing units to achieve the large sample sizes required for analyzing the tails of the tracer distributions.

Irwin M. Zaid; Jörn Dunkel; Julia M. Yeomans

2010-09-20T23:59:59.000Z

223

Reactive Support and Voltage Control Service: Key Issues and Challenges  

E-Print Network [OSTI]

reactive support and voltage control services. Keywords ­ Competitive Electricity Markets, Reactive PowerReactive Support and Voltage Control Service: Key Issues and Challenges George Gross^, Paolo Marannino° and Gianfranco Chicco* ^ Department of Electrical and Computer Engineering, University

Gross, George

224

Reactive facies: An approach for parameterizing field-scale reactive transport models using geophysical methods  

E-Print Network [OSTI]

source rock (organic rich sedimen- tary rocks versus silicate dominated igneous and metamor- phic rocks) and to differences in sediment maturity (

Sassen, D.

2014-01-01T23:59:59.000Z

225

Characterization of Dual-Fuel Reactivity Controlled Compression...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI)...

226

A smoothed particle hydrodynamics model for reactive transport...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A smoothed particle hydrodynamics model for reactive transport and mineral precipitation in porous and fractured porous media. A smoothed particle hydrodynamics model for reactive...

227

Using Biofuel Tracers to Study Alternative Combustion Regimes  

E-Print Network [OSTI]

Internal Combustion Engines The methods described below for tracing fuel component carbon in the emissions

Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

2006-01-01T23:59:59.000Z

228

COAL SLAGGING AND REACTIVITY TESTING  

SciTech Connect (OSTI)

Union Fenosa's La Robla I Power Station is a 270-MW Foster Wheeler arch-fired system. The unit is located at the mine that provides a portion of the semianthracitic coal. The remaining coals used are from South Africa, Russia, Australia, and China. The challenges at the La Robla I Station stem from the various fuels used, the characteristics of which differ from the design coal. The University of North Dakota Energy & Environmental Research Center (EERC) and the Lehigh University Energy Research Center (LUERC) undertook a program to assess problematic slagging and unburned carbon issues occurring at the plant. Full-scale combustion tests were performed under baseline conditions, with elevated oxygen level and with redistribution of air during a site visit at the plant. During these tests, operating information, observations and temperature measurements, and coal, slag deposit, and fly ash samples were obtained to assess slagging and unburned carbon. The slagging in almost all cases appeared due to elevated temperatures rather than fuel chemistry. The most severe slagging occurred when the temperature at the sampling port was in excess of 1500 C, with problematic slagging where first-observed temperatures exceeded 1350 C. The presence of anorthite crystals in the bulk of the deposits analyzed indicates that the temperatures were in excess of 1350 C, consistent with temperature measurements during the sampling period. Elevated temperatures and ''hot spots'' are probably the result of poor mill performance, and a poor distribution of the coal from the mills to the specific burners causes elevated temperatures in the regions where the slag samples were extracted. A contributing cause appeared to be poor combustion air mixing and heating, resulting in oxygen stratification and increased temperatures in certain areas. Air preheater plugging was observed and reduces the temperature of the air in the windbox, which leads to poor combustion conditions, resulting in unburned carbon as well as slagging. A second phase of the project involved advanced analysis of the baseline coal along with an Australian coal fired at the plant. These analysis results were used in equilibrium thermodynamic modeling along with a coal quality model developed by the EERC to assess slagging, fouling, and opacity for the coals. Bench-scale carbon conversion testing was performed in a drop-tube furnace to assess the reactivity of the coals. The Australian coal had a higher mineral content with significantly more clay minerals present than the baseline coal. The presence of these clay minerals, which tend to melt at relatively low temperatures, indicated a higher potential for problematic slagging than the baseline coal. However, the pyritic minerals, comprising over 25% of the baseline mineral content, may form sticky iron sulfides, leading to severe slagging in the burner region if local areas with reducing conditions exist. Modeling results indicated that neither would present significant fouling problems. The Australian coal was expected to show slagging behavior much more severe than the baseline coal except at very high furnace temperatures. However, the baseline coal was predicted to exhibit opacity problems, as well as have a higher potential for problematic calcium sulfate-based low-temperature fouling. The baseline coal had a somewhat higher reactivity than the Australian coal, which was consistent with both the lower average activation energy for the baseline coal and the greater carbon conversion at a given temperature and residence time. The activation energy of the baseline coal showed some effect of oxygen on the activation energy, with E{sub a} increasing at the lower oxygen concentration, but may be due to the scatter in the baseline coal kinetic values at the higher oxygen level tested.

Donald P. McCollor; Kurt E. Eylands; Jason D. Laumb

2003-10-01T23:59:59.000Z

229

Reactivity control assembly for nuclear reactor  

DOE Patents [OSTI]

Reactivity control assembly for nuclear reactor comprises supports stacked above reactor core for holding control rods. Couplers associated with the supports and a vertically movable drive shaft have lugs at their lower ends for engagement with the supports.

Bollinger, Lawrence R. (Schenectady, NY)

1984-01-01T23:59:59.000Z

230

Fossil plant layup and reactivation conference: Proceedings  

SciTech Connect (OSTI)

The Fossil Plant Layup and Reactivation Conference was held in New Orleans, Louisiana on April 14--15, 1992. The Conference was sponsored by EPRI and hosted by Entergy Services, Inc. to bring together representatives from utilities, consulting firms, manufacturers and architectural engineers. Eighteen papers were presented in three sessions. These sessions were devoted to layup procedures and practices, and reactivation case studies. A panel discussion was held on the second day to interactively discuss layup and reactivation issues. More than 80 people attended the Conference. This report contains technical papers and a summary of the panel discussion. Of the eighteen papers, three are related to general, one is related to regulatory issues, three are related to specific equipment, four are related to layup procedures and practices, and seven are layup and reactivation case studies.

Not Available

1992-10-01T23:59:59.000Z

231

A Tariff for Reactive Power - IEEE  

SciTech Connect (OSTI)

This paper describes a suggested tariff or payment for the local supply of reactive power from distributed energy resources. The authors consider four sample customers, and estimate the cost of supply of reactive power for each customer. The power system savings from the local supply of reactive power are also estimated for a hypothetical circuit. It is found that reactive power for local voltage regulation could be supplied to the distribution system economically by customers when new inverters are installed. The inverter would be supplied with a power factor of 0.8, and would be capable of local voltage regulation to a schedule supplied by the utility. Inverters are now installed with photovoltaic systems, fuel cells and microturbines, and adjustable-speed motor drives.

Kueck, John D [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator; Kirby, Brendan J [ORNL

2008-11-01T23:59:59.000Z

232

Systematic approach for chemical reactivity evaluation  

E-Print Network [OSTI]

Screening Tool (RSST) and the Automatic Pressure Tracking Adiabatic Calorimeter (APTAC) were employed to evaluate the reactive systems experimentally. The RSST detected exothermic behavior and measured the overall liberated energy. The APTAC simulated...

Aldeeb, Abdulrehman Ahmed

2004-09-30T23:59:59.000Z

233

Reactive Attachment Disorder: Concepts, Treatment, and Research  

E-Print Network [OSTI]

Reactive Attachment Disorder (RAD) is a disorder characterized by controversy, both with respect to its definition and its treatment. By definition, the RAD diagnosis attempts to characterize and explain the origin of ...

Walter, Uta M.; Petr, Chris

2004-06-01T23:59:59.000Z

234

Relative reactivities of solid benzoic acids  

E-Print Network [OSTI]

RELATIVE REACTIVITIES OF SOLID BENZOIC ACIDS A Thesis By EDWIN J, WARWAS Submitted to the Graduate College of the Texas A8rM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1967' Major... Subject: Chemistry RELATIVE REACTIVITIES OF SOLID BENZOIC ACIDS A Thesis By EDWIN J. WARWAS Submitted to the Graduate College of the Texas ASSAM University in partial fulfillment of the requirements for the degree of MAST ER OF S CIENCE January...

Warwas, Edwin James

2012-06-07T23:59:59.000Z

235

Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel  

DOE Patents [OSTI]

Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

Herrmann, Steven Douglas

2014-05-27T23:59:59.000Z

236

Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems  

SciTech Connect (OSTI)

The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

Reimus, Paul W [Los Alamos National Laboratory

2011-01-21T23:59:59.000Z

237

Results of injection and tracer tests in Olkaria north east field in Kenya  

SciTech Connect (OSTI)

Tracer and injection tests were performed in the Olkaria North East Field with the objective to reduce uncertainty in the engineering design and to determine the suitability of well OW-704 as a re-injection well for the waste brine from the steam field during production. An organic dye (sodium fluorescein) was injected into well OW-704 as a slug. The tracer returns were observed in well OW-M2 which is 580 m deep, 620 m from well OW-704 and well OW-716 which is 900 m from well OW-704. The other wells on discharge, OW-714, and OW-725 did not show any tracer returns. However, other chemical constituents suggested., that well OW-716 experienced a chemical breakthrough earlier than OW-M2. Tracer return velocities of 0.31 m/hr and 1.3 m/hr were observed. Results of the tracer and injection tests indicate that OW-704 may be used as a re-injection well provided a close monitoring program is put in place.

Karingithi, C.W. [Kenya Power Company Ltd., Naivasha (Kenya)

1995-12-31T23:59:59.000Z

238

A Preliminary Analysis of the Economics of Using Distributed Energy as a Source of Reactive Power Supply  

SciTech Connect (OSTI)

A major blackout affecting 50 million people in the Northeast United States, where insufficient reactive power supply was an issue, and an increased number of filings made to the Federal Energy Regulatory Commission by generators for reactive power has led to a closer look at reactive power supply and compensation. The Northeastern Massachusetts region is one such area where there is an insufficiency in reactive power compensation. Distributed energy due to its close proximity to loads seems to be a viable option for solving any present or future reactive power shortage problems. Industry experts believe that supplying reactive power from synchronized distributed energy sources can be 2 to 3 times more effective than providing reactive support in bulk from longer distances at the transmission or generation level. Several technology options are available to supply reactive power from distributed energy sources such as small generators, synchronous condensers, fuel cells or microturbines. In addition, simple payback analysis indicates that investments in DG to provide reactive power can be recouped in less than 5 years when capacity payments for providing reactive power are larger than $5,000/kVAR and the DG capital and installation costs are lower than $30/kVAR. However, the current institutional arrangements for reactive power compensation present a significant barrier to wider adoption of distributed energy as a source of reactive power. Furthermore, there is a significant difference between how generators and transmission owners/providers are compensated for reactive power supplied. The situation for distributed energy sources is even more difficult, as there are no arrangements to compensate independent DE owners interested in supplying reactive power to the grid other than those for very large IPPs. There are comparable functionality barriers as well, as these smaller devices do not have the control and communications requirements necessary for automatic operation in response to local or system operators. There are no known distributed energy asset owners currently receiving compensation for reactive power supply or capability. However, there are some cases where small generators on the generation and transmission side of electricity supply have been tested and have installed the capability to be dispatched for reactive power support. Several concerns need to be met for distributed energy to become widely integrated as a reactive power resource. The overall costs of retrofitting distributed energy devices to absorb or produce reactive power need to be reduced. There needs to be a mechanism in place for ISOs/RTOs to procure reactive power from the customer side of the meter where distributed energy resides. Novel compensation methods should be introduced to encourage the dispatch of dynamic resources close to areas with critical voltage issues. The next phase of this research will investigate in detail how different options of reactive power producing DE can compare both economically and functionally with shunt capacitor banks. Shunt capacitor banks, which are typically used for compensating reactive power consumption of loads on distribution systems, are very commonly used because they are very cost effective in terms of capital costs. However, capacitor banks can require extensive maintenance especially due to their exposure to lightning at the top of utility poles. Also, it can be problematic to find failed capacitor banks and their maintenance can be expensive, requiring crews and bucket trucks which often requires total replacement. Another shortcoming of capacitor banks is the fact that they usually have one size at a location (typically sized as 300, 600, 900 or 1200kVAr) and thus don't have variable range as do reactive power producing DE, and cannot respond to dynamic reactive power needs. Additional future work is to find a detailed methodology to identify the hidden benefit of DE for providing reactive power and the best way to allocate the benefit among customers, utilities, transmission companies or RTOs.

Li, Fangxing [ORNL; Kueck, John D [ORNL; Rizy, D Tom [ORNL; King, Thomas F [ORNL

2006-04-01T23:59:59.000Z

239

Reactive Distillation for Esterification of Bio-based Organic Acids  

SciTech Connect (OSTI)

The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

2008-09-23T23:59:59.000Z

240

Eoeective Recognizability and Model Checking of Reactive Fioeo Automata  

E-Print Network [OSTI]

Electre. For this, we deøne a particular behavioral model for Electre programs, Reactive Fioeo Au­ tomata speciøed with the reactive language Electre [CR95]. A reactive pro­ gram is supposed to reactEoeective Recognizability and Model Checking of Reactive Fioeo Automata G. Sutre 1 , A. Finkel 1

Sutre, Grégoire

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure  

E-Print Network [OSTI]

the concentrations of pollutants emitted by indoor sources and brings in pollutants from the outdoors. The air Development Office of Healthy Homes and Lead Hazard Control through Interagency Agreement I-PHI-01070; by the U.S. Environmental Protection Agency Office of Air and Radiation through Interagency Agreement DW-89

242

A comprehensive study of the analysis and economic benefits of radioactive tracer engineered simulation procedures  

SciTech Connect (OSTI)

Hydraulic Fracturing is an important technology to enhance production from tight gas reservoirs. Several techniques have been utilized to attempt to evaluate the effectiveness of hydraulic fracturing treatments. One technique, radioactive tracers, is currently used on over 15 % of the stimulation treatments performed in the U.S. With proper materials, design, and execution, tracers can be used to locate the presence and concentration of proppant at the wellbore in order to evaluate vertical and radial proppant distribution. A comprehensive study of over 100 fracture treatments has been completed in which radioactive tracers were used along with production logs, stress logs, post-fracturing completion reports, and production history to analyze completion effectiveness in four different reservoirs. Additionally, an economic benefit model was constructed to evaluate the benefit/cost ratio of applying the technology.

Fisher, K.; Robinson, B.M.; Voneiff, G.W.

1995-12-31T23:59:59.000Z

243

Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site  

SciTech Connect (OSTI)

This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

2000-08-01T23:59:59.000Z

244

Estimation of Fracture Porosity in an Unsaturated Fractured Welded Tuff Using Gas Tracer Testing  

SciTech Connect (OSTI)

Kinematic fracture porosity is an important hydrologic transport parameter for predicting the potential of rapid contaminant migration through fractured rock. The transport velocity of a solute moving within a fracture network is inversely related to the fracture porosity. Since fracture porosity is often one or two orders of magnitude smaller than matrix porosity, and fracture permeability is often orders of magnitude greater than matrix permeability, solutes may travel significantly faster in the fracture network than in the surrounding matrix. This dissertation introduces a new methodology for conducting gas tracer tests using a field portable mass spectrometer along with analytical tools for estimating fracture porosity using the measured tracer concentration breakthrough curves. Field experiments were conducted at Yucca Mountain, Nevada, consisting of air-permeability transient testing and gas-tracer-transport tests. The experiments were conducted from boreholes drilled within an underground tunnel as part of an investigation of rock mass hydrological behavior. Air-permeability pressure transients, recorded during constant mass flux injections, have been analyzed using a numerical inversion procedure to identify fracture permeability and porosity. Dipole gas tracer tests have also been conducted from the same boreholes used for air-permeability testing. Mass breakthrough data has been analyzed using a random walk particle-tracking model, with a dispersivity that is a function of the advective velocity. The estimated fracture porosity using the tracer test and air-injection test data ranges from .001 to .015. These values are an order of magnitude greater than the values estimated by others using hydraulically estimated fracture apertures. The estimates of porosity made using air-permeability test data are shown to be highly sensitive to formation heterogeneity. Uncertainty analyses performed on the gas tracer test results show high confidence in the parameter estimates made.

B.M. Freifeild

2001-10-18T23:59:59.000Z

245

Total Matrix Intercomparison: A Method for Determining the Geometry of Water-Mass Pathways  

E-Print Network [OSTI]

Ocean tracer distributions have long been used to decompose the deep ocean into constituent water masses, but previous inverse methods have generally been limited to just a few water masses that have been defined by a ...

Gebbie, Geoffrey

246

Adaptive Methods for Modelling Transport Processes in Fractured Subsurface Systems  

E-Print Network [OSTI]

­ discrete Galerkin method applying finite differences for the discretization in time and the StreamlineAdaptive Methods for Modelling Transport Processes in Fractured Subsurface Systems 3rd­adaptive methods for modelling transport processes in fractured rock. As a simplification, ideal tracers

Cirpka, Olaf Arie

247

Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Project Summary. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate quantitative characterization of temperature distributions and surface area available for heat transfer in EGS.

248

Fracture Model, Ground Displacements and Tracer Observations: Fruitland Coals, San Juan Basin, New Mexico,  

E-Print Network [OSTI]

that the coal reservoirs consist of six separate coal beds rather than three. Perfluorocarbon tracer monitoring the site consist of two coal beds, each separated by a shale parting. This observation indicates will improve our understanding of Fruitland coal reservoirs; help develop more effective strategies to enhance

Wilson, Thomas H.

249

Physical causes and modeling challenges of anomalous diffusion of sediment tracers  

E-Print Network [OSTI]

Physical causes and modeling challenges of anomalous diffusion of sediment tracers Douglas Jerolmack Earth & Environmental Science, UPenn [sediment@sas.upenn.edu] "Bridging the Gap", Princeton U., 2" describable by: 1. Particle volume, v [L3 ]. 2.Average velocity, us , of bed load sediment [L/T]. 3. Surface

250

BOREHOLE RADAR ATTENUATION-DIFFERENCE TOMOGRAPHY DURING THE TRACER/TIME-LAPSE TEST AT THE BOISE  

E-Print Network [OSTI]

to those suggested by radar level run attenuation differences, shot-receiver attenuation difference be explained by the difference in support volumes for the radar and chemistry measurements, and alsoBOREHOLE RADAR ATTENUATION-DIFFERENCE TOMOGRAPHY DURING THE TRACER/TIME-LAPSE TEST AT THE BOISE

Barrash, Warren

251

Project EARTH-14-SHELLDP1: Developing Metal Isotope Tracers for Understanding Sediment Depositional Environments  

E-Print Network [OSTI]

Project EARTH-14-SHELLDP1: Developing Metal Isotope Tracers for Understanding Sediment Depositional and the mechanisms behind temporal and spatial variations in organic matter quantity and quality. The project work will involve becoming proficient in clean room procedures, chemical separation techniques

Henderson, Gideon

252

TRACER: A Trace Replay Tool to Evaluate Energy-Efficiency of Mass Storage Systems  

E-Print Network [OSTI]

TRACER: A Trace Replay Tool to Evaluate Energy-Efficiency of Mass Storage Systems Zhuo Liu1 , Fei of accurately evaluating energy-efficient storage systems and objectively comparing a wide range of energy RAID5 enterprise disk array. Our experiments demonstrate that energy-efficient mass storage systems can

Qin, Xiao

253

Near-Infrared Gold Nanocages as a New Class of Tracers for Photoacoustic  

E-Print Network [OSTI]

radiation damage to the connective tissues of the skin. Therefore, noninvasive, nonionizing, and highNear-Infrared Gold Nanocages as a New Class of Tracers for Photoacoustic Sentinel Lymph Node based on Au nanocages shows a number of attractive features: noninvasiveness, strong optical absorption

Wang, Lihong

254

Evaluating the ability of a numerical weather prediction model to forecast tracer concentrations during ETEX 2  

E-Print Network [OSTI]

Evaluating the ability of a numerical weather prediction model to forecast tracer concentrations an operational numerical weather prediction model to forecast air quality are also investigated. These potential a numerical weather prediction (NWP) model independently of the CTM. The NWP output is typically archived

Dacre, Helen

255

Ammonium transport and reaction in contaminated groundwater: Application of isotope tracers and isotope fractionation studies  

E-Print Network [OSTI]

Ammonium transport and reaction in contaminated groundwater: Application of isotope tracers the groundwater velocity. Retardation factors and groundwater ages indicate that much of the NH4 + in the plume was recharged early in the history of the wastewater disposal. NO3 Ă? and excess N2 gas, which were related

256

Tracer studies of pathways and rates of meltwater transport through Arctic summer sea ice  

E-Print Network [OSTI]

Tracer studies of pathways and rates of meltwater transport through Arctic summer sea ice H. Eicken) program's field site in the northern Chukchi Sea, snow and ice meltwater flow was found to have a strong impact on the heat and mass balance of sea ice during the summer of 1998. Pathways and rates of meltwater

Eicken, Hajo

257

Seasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements  

E-Print Network [OSTI]

of indoor air pollution sources. Concurrently, great efforts are made to make buildings energy efficient 1970s, while less attention has been paid to IAQ. Insufficient venting of indoor air pollutantsSeasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements Marie

Hansen, René Rydhof

258

Using chemical tracers in hillslope soils to estimate the importance of chemical denudation under  

E-Print Network [OSTI]

also examine relationships between transient mechanical and chemical denudation rates. Soil particle, burrowing by mammals, or freeze-thaw mechanisms [e.g., see Birkeland, 1999]. Once created, mobile soilUsing chemical tracers in hillslope soils to estimate the importance of chemical denudation under

259

Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers  

E-Print Network [OSTI]

Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers November 2006; published 4 May 2007. [1] Understanding factors that control methane exchange between soils-based technique to investigate the relative importance of three mechanisms for explaining landscape

260

Tracer Gas as a Practical Field Diagnostic Tool for Assessing Duct System Leaks  

E-Print Network [OSTI]

diagnostic tools for detecting and locating leaks in the air distribution system. The tracer gas tests described are a good complement to these tools in the detection, location, and measurement of duct leakage. Testing for house infiltration once with the air...

Cummings, J. B.

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Lignin biomarkers as tracers of mercury sources in lakes water column  

E-Print Network [OSTI]

Lignin biomarkers as tracers of mercury sources in lakes water column Jean-Franc¸ois Ouellet � Marc the autochthonous from the allochthonous organic matter (OM), lignin derived biomarker signa- tures [Lambda, S/V, C/V, P/(V ? S), 3,5-Bd/V and (Ad/Al)v] were used. Since lignin is exclusively produced by terrigenous

Long, Bernard

262

ADVANCES IN ATMOSPHERIC SCIENCES, VOL. 25, NO. 5, 2008, 805814 Diagnosing Ocean Tracer Transport from Sellafield  

E-Print Network [OSTI]

DRANGE1,2,3,4 , and Eric DELEERSNIJDER5 1 Nansen Environmental and Remote Sensing Center, Bergen, Norway applications thereof, idealized releases of passive tracers from the nuclear fuel reprocessing plants­814, doi: 10.1007/s00376-008-0805-y. 1. Introduction Estimating the integrated effect of processes acting

Drange, Helge

263

Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts  

E-Print Network [OSTI]

Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

Iglesia, Enrique

264

New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas Operations  

E-Print Network [OSTI]

New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas produced waters sampled from conventional oil and gas wells. We posit that boron isotope geochemistry can tool is validated by examining the composition of effluent discharge from an oil and gas brine

Jackson, Robert B.

265

Supporting BioMedical Information Retrieval: The BioTracer Approach  

E-Print Network [OSTI]

Supporting BioMedical Information Retrieval: The BioTracer Approach Heri Ramampiaro1 and Chen Li2 1 biomedical in- formation has put a high demand on existing search systems. Such a tool should be able the relevant ones the highest rank- ing. Focusing on biomedical information, this work investigates how

Li, Chen

266

Rotanone analogs: method of preparation and use  

SciTech Connect (OSTI)

The present invention provides rotenone analogs and methods of making and using them. Labeled with single photon and positron emitting isotopes, the rotenone analogs of the present invention are useful in, for example, clinical imaging applications as tracers to measure cardiac blood flow and detect regions of ischemia.

2013-10-08T23:59:59.000Z

267

Evidence of Multi-Process Matrix Diffusion in a Single Fracturefrom a Field Tracer Test  

SciTech Connect (OSTI)

Compared to values inferred from laboratory tests on matrix cores, many field tracer tests in fractured rock have shown enhanced matrix diffusion coefficient values (obtained using a single-process matrix-diffusion model with a homogeneous matrix diffusion coefficient). To investigate this phenomenon, a conceptual model of multi-process matrix diffusion in a single-fracture system was developed. In this model, three matrix diffusion processes of different diffusion rates were assumed to coexist: (1) diffusion into stagnant water and infilling materials within fractures, (2) diffusion into a degraded matrix zone, and (3) further diffusion into an intact matrix zone. The validity of the conceptual model was then demonstrated by analyzing a unique tracer test conducted using a long-time constant-concentration injection. The tracer-test analysis was conducted using a numerical model capable of tracking the multiple matrix-diffusion processes. The analysis showed that in the degraded zone, a diffusion process with an enhanced diffusion rate controlled the steep rising limb and decay-like falling limb in the observed breakthrough curve, whereas in the intact matrix zone, a process involving a lower diffusion rate affected the long-term middle platform of slowly increasing tracer concentration. The different matrix-diffusion-coefficient values revealed from the field tracer test are consistent with the variability of matrix diffusion coefficient measured for rock cores with different degrees of fracture coating at the same site. By comparing to the matrix diffusion coefficient calibrated using single-process matrix diffusion, we demonstrated that this multi-process matrix diffusion may contribute to the enhanced matrix-diffusion-coefficient values for single-fracture systems at the field scale.

Zhou, Quanlin; Liu, Hui-Hai; Bodvarsson, Gudmundur; Molz, Fred J.

2005-06-11T23:59:59.000Z

268

Studies on Waterborne Pathogen Reactivation after Disinfection  

E-Print Network [OSTI]

ultraviolet (LP UV) irradiation at five titanium dioxide (TiO_(2)) concentrations (1 g/L, 0.5 g/L, 0.75 g/L, and 0.1 g/L) to achieve 5 log_(10) reduction of a laboratory E. coli K-12 strain (ATCC® 10798). Regrowth and reactivation of E. coli in dark and light...

Kaur, Jasjeet

2013-12-09T23:59:59.000Z

269

Gasification reactivities of solid biomass fuels  

SciTech Connect (OSTI)

The design and operation of the biomass based gasification processes require knowledge about the biomass feedstocks characteristics and their typical gasification behaviour in the process. In this study, the gasification reactivities of various biomasses were investigated in laboratory scale Pressurized Thermogravimetric apparatus (PTG) and in the PDU-scale (Process Development Unit) Pressurized Fluidized-Bed (PFB) gasification test facility of VTT.

Moilanen, A.; Kurkela, E.

1995-12-31T23:59:59.000Z

270

Controlling uranium reactivity March 18, 2008  

E-Print Network [OSTI]

for the last decade. Most of their work involves depleted uranium, a more common form of uraniumMarch 2008 Controlling uranium reactivity March 18, 2008 Uranium is an often misunderstood metal uranium research. In reality, uranium presents a wealth of possibilities for funda- mental chemistry. Many

Meyer, Karsten

271

Analysis of Tracer Dispersion During a Prescribed Forest Burn  

E-Print Network [OSTI]

become a method to manage forest health, while preventing uncontrolled wild land fire. Low intensity, prescribed burns release less carbon dioxide than wildfires of the same size and may be used as a strategy. The ultimate goal of the project is to use the data from the burn, along with modeling techniques to improve

Collins, Gary S.

272

Assessment of the Economic Potential of Microgrids for Reactive Power Supply  

E-Print Network [OSTI]

Reactive Power from Distributed Energy”, The Electricityvoltage. Electricity consumers’ demand for reactive power ison electricity supply security, the costs of local reactive

Appen, Jan von

2012-01-01T23:59:59.000Z

273

Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion  

SciTech Connect (OSTI)

Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-high vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) was found to be a good representation of both types of diffusion data that cover a broad range of temperatures between 250 - 627 C (523 900 K).

Kulkarni, Nagraj S [ORNL; Warmack, Robert J Bruce [ORNL; Radhakrishnan, Balasubramaniam [ORNL; HunterJr., Jerry [Virginia Polytechnic Institute and State University; Sohn, Yong Ho [University of Central Florida; Coffey, Kevin [University of Central Florida; Murch, Prof. Graeme [University of Newcastle, NSW, Australia; Belova, Irina [University of Newcastle, NSW, Australia

2014-01-01T23:59:59.000Z

274

Parallel Web Scripting with Reactive Constraints Thibaud Hottelier  

E-Print Network [OSTI]

Parallel Web Scripting with Reactive Constraints Thibaud Hottelier James Ide Doug Kimelman Ras Bodik Electrical Engineering and Computer Sciences University of California at Berkeley Technical Report to lists, requires prior specific permission. #12;Parallel Web Scripting with Reactive Constraints Thibaud

Bodik, Rastisla

275

Self-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy  

E-Print Network [OSTI]

investigated on the epitaxy and self- organization of laterally nanostructured transition metal TM silicideSelf-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy L to be a flexible and a convenient method for the preparation of dense arrays of Co silicide quantum dots

Ortega, Enrique

276

Optimal Reactive Power Dispatch in Real-Time S. Salamat Sharif1  

E-Print Network [OSTI]

) an improvement in the volt- age profile and voltage stability, and 2) a savings in ac- tive power loss of view. A reduction in active power loss gained from ORPD can save a significant amount of money reactive power dispatch, power loss minimization, optimization methods 1 Introduction Optimal power

Taylor, James H.

277

Specificationbased Testing of Reactive Software: A Case Study in Technology Transfer  

E-Print Network [OSTI]

Specification­based Testing of Reactive Software: A Case Study in Technology Transfer Lalita be effective in practice. The case study illustrates that technology transfer efforts can benefit from that limit formal methods technology transfer. We also found that there is often a tension between the scope

Porter, Adam

278

LEVEL OF HIGH-SENSITIVITY C-REACTIVE PROTEIN IN SAUDI PATIENTS WITH CHRONIC STABLE CORONARY ARTERY DISEASE  

E-Print Network [OSTI]

Background: Inflammatory biomarker high-sensitivity C-reactive protein (hsCRP) is an independent predictor of future cardiovascular events and it predicts risk of incident hypertension and diabetes. The aim of this study was to determine the serum levels of the circulating acute-phase reactant high-sensitivity C-reactive protein (hsCRP) in Saudi patients with chronic stable Coronary Artery Disease (CAD). Methods: This cross

J Ayub; Med Coll Abbottabad; Syed Shahid Habib

279

ENVIRONMENTAL REACTIVITY OF SOLID STATE HYDRIDE MATERIALS  

SciTech Connect (OSTI)

In searching for high gravimetric and volumetric density hydrogen storage systems, it is inevitable that higher energy density materials will be used. In order to make safe and commercially acceptable condensed phase hydrogen storage systems, it is important to understand quantitatively the risks involved in using and handling these materials and to develop appropriate mitigation strategies to handle potential material exposure events. A crucial aspect of the development of risk identification and mitigation strategies is the development of rigorous environmental reactivity testing standards and procedures. This will allow for the identification of potential risks and implementation of risk mitigation strategies. Modified testing procedures for shipping air and/or water sensitive materials, as codified by the United Nations, have been used to evaluate two potential hydrogen storage materials, 2LiBH{sub 4} {center_dot} MgH{sub 2} and NH{sub 3}BH{sub 3}. The modified U.N. procedures include identification of self-reactive substances, pyrophoric substances, and gas-emitting substances with water contact. The results of these tests for air and water contact sensitivity will be compared to the pure material components where appropriate (e.g. LiBH{sub 4} and MgH{sub 2}). The water contact tests are divided into two scenarios dependent on the hydride to water mole ratio and heat transport characteristics. Air contact tests were run to determine whether a substance will spontaneously react with air in a packed or dispersed form. In the case of the 2LiBH{sub 4} {center_dot} MgH{sub 2} material, the results from the hydride mixture compared to the pure materials results showed the MgH{sub 2} to be the least reactive component and LiBH{sub 4} the more reactive. The combined 2LiBH{sub 4} {center_dot} MgH{sub 2} resulted in a material having environmental reactivity between these two materials. Relative to 2LiBH{sub 4} {center_dot} MgH{sub 2}, the chemical hydride NH{sub 3}BH{sub 3} was observed to be less environmentally reactive.

Gray, J; Donald Anton, D

2009-04-23T23:59:59.000Z

280

WSi2/Si Multilayer Sectioning by Reactive Ion Etching for Multilayer Laue Lens Fabrication  

SciTech Connect (OSTI)

SPIE Conference paper/talk presentation: Introduction: Reactive ion etching (RIE) has been employed in a wide range of fields such as semiconductor fabrication, MEMS (microelectromechanical systems), and refractive x-ray optics with a large investment put towards the development of deep RIE. Due to the intrinsic differing chemistries related to reactivity, ion bombardment, and passivation of materials, the development of recipes for new materials or material systems can require intense effort and resources. For silicon in particular, methods have been developed to provide reliable anisotropic profiles with good dimensional control and high aspect ratios1,2,3, high etch rates, and excellent material to mask etch selectivity...

Bouet, N.; Conley, R.; Biancarosaa, J.; Divanc, R.; Macrander, A. T.

2010-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

The Simulation of Synchronous Reactive Systems In Ptolemy II  

E-Print Network [OSTI]

The Simulation of Synchronous Reactive Systems In Ptolemy II by Paul Whitaker Submitted to the Department of Electrical Engineering and Computer Sciences, University of California at Berkeley, in partial;_____________________________________________________________________ Simulation of Synchronous Reactive Systems in Ptolemy II ii Abstract The Synchronous Reactive (SR) domain

282

Autonomic Reactive Systems via Online Learning Sanjit A. Seshia  

E-Print Network [OSTI]

Autonomic Reactive Systems via Online Learning Sanjit A. Seshia Department of Electrical@eecs.berkeley.edu Abstract-- Reactive systems are those that maintain an ongoing interaction with their environment- covering a class of reactive systems from run-time failures. This class of systems comprises those whose

California at Irvine, University of

283

Towards Synthesis of Reactive & Robust Behavior Chains Amol D. Mali  

E-Print Network [OSTI]

Towards Synthesis of Reactive & Robust Behavior Chains Amol D. Mali Electrical Engg. & Computer robots need to be reactive and robust. Behavior-based robots that identify and repair the failures have of reactivity and robustness have been hitherto only informally used and have been loaded with var- ious

Mali, Amol D.

284

A Synchronous Approach to Reactive System Design1 Charles Andr  

E-Print Network [OSTI]

our experience teaching discrete-event reactive systems to Electrical Engineering students. The courseA Synchronous Approach to Reactive System Design1 Charles André I3S Laboratory ­ UNSA/CNRS BP 121 This paper was presented at the 12th EAEEIE Annual Conf., 14-16 May 2001, Nancy (France). Abstract Reactive

André, Charles

285

On Some Properties of Instantaneous Active and Reactive Powers  

E-Print Network [OSTI]

On Some Properties of Instantaneous Active and Reactive Powers Leszek S. CZARNECKI, Fellow IEEE Louisiana State University, USA Abstract: Some features of the instantaneous active and reactive powers p control. Also it was shown that the instantaneous reactive power q cannot be interpreted as a measure

Czarnecki, Leszek S.

286

Single Well Injection Withdrawl Tracer Tests for Proppant Detection -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2)Sharing Smart GridShiftMethodSimwYpes(tm)

287

Stirring and mixing of biologically reactive tracers K. J. Richards, S. J. Brentnall, P. McLeod, and A. P. Martin  

E-Print Network [OSTI]

and fluid flow Fluid flow can impact on the marine ecological sys- tem in two distinct ways: (a) through incorpo- rated into models of climate change to predict global warming scenarios (see, e.g., it Cox et al models the marine ecological system is a matter of debate. There is s

Cambridge, University of

288

Nuclear reactivity control using laser induced polarization  

DOE Patents [OSTI]

A control element for reactivity control of a fission source provides an atomic density of .sup.3 He in a control volume which is effective to control criticality as the .sup.3 He is spin-polarized. Spin-polarization of the .sup.3 He affects the cross section of the control volume for fission neturons and hence, the reactivity. An irradiation source is directed within the .sup.3 He for spin-polarizing the .sup.3 He. An alkali-metal vapor may be included with the .sup.3 He where a laser spin-polarizes the alkali-metal atoms which in turn, spin-couple with .sup.3 He to spin-polarize the .sup.3 He atoms.

Bowman, Charles D. (Los Alamos, NM)

1990-01-01T23:59:59.000Z

289

Nuclear reactivity control using laser induced polarization  

DOE Patents [OSTI]

A control element for reactivity control of a fission source provides an atomic density of .sup.3 He in a control volume which is effective to control criticality as the .sup.3 He is spin-polarized. Spin-polarization of the .sup.3 He affects the cross section of the control volume for fission neutrons and hence, the reactivity. An irradiation source is directed within the .sup.3 He for spin-polarizing the .sup.3 He. An alkali-metal vapor may be included with the .sup.3 He where a laser spin-polarizes the alkali-metal atoms which in turn, spin-couple with .sup.3 He to spin-polarize the .sup.3 He atoms.

Bowman, Charles D. (Los Alamos, NM)

1991-01-01T23:59:59.000Z

290

Reactivity control assembly for nuclear reactor. [LMFBR  

DOE Patents [OSTI]

This invention, which resulted from a contact with the United States Department of Energy, relates to a control mechanism for a nuclear reactor and, more particularly, to an assembly for selectively shifting different numbers of reactivity modifying rods into and out of the core of a nuclear reactor. It has been proposed heretofore to control the reactivity of a breeder reactor by varying the depth of insertion of control rods (e.g., rods containing a fertile material such as ThO/sub 2/) in the core of the reactor, thereby varying the amount of neutron-thermalizing coolant and the amount of neutron-capturing material in the core. This invention relates to a mechanism which can advantageously be used in this type of reactor control system.

Bollinger, L.R.

1982-03-17T23:59:59.000Z

291

Spectral shift reactor control method  

SciTech Connect (OSTI)

A method of operating a pressurized water nuclear reactor is described which comprises the determining of the present core power and reactivity levels and predicting the change in such levels due to displacer rod movements. Groups or single clusters of displacer rods can be inserted or withdrawn based on the predicted core power and reactivity levels to change the core power level and power distribution thereby providing load follow capability, without changing control rod positions or coolant boron concentrations.

Impink, A.J. Jr.

1984-02-21T23:59:59.000Z

292

Inversion of field-scale partitioning tracer response for characterizing oil saturation distribution: a streamline approach  

E-Print Network [OSTI]

INVERSION OF FIELD-SCALE PARTITIONING TRACER RESPONSE FOR CHARACTERIZING OIL SATURATION DISTRIBUTION: A STREAMLINE APPROACH A Thesis by PAVEL ALEXANDROVICH ILIASSOV Submitted to the Office of Graduate Studies of Texas A&M University... A Thesis by PAVEL ALEXANDROVICH ILIASSOV Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style and content by: c 4- Akhil Datta-Gupta (Chair of Committee...

Iliassov, Pavel Alexandrovich

2000-01-01T23:59:59.000Z

293

Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform in Houston, Texas: Trends and Tracers  

E-Print Network [OSTI]

and traffic counts except during variable working hours. To assign measured fluxes to local sources, we tested a bulk flux footprint model (Kormann and Meixner model) designed for uniform emission surface areas in this urban, heterogeneous landscape. Tracer...

Hale, Martin C

2014-05-08T23:59:59.000Z

294

Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. This objective of this project is to develop an innovative approach to estimate fracture surface area and spacing through interpretation of signals of natural chemical and isotopic tracers.

295

Thorium-234 as a tracer of spatial, temporal and vertical variability in particle flux in the North Pacific  

E-Print Network [OSTI]

Thorium-234 as a tracer of spatial, temporal and vertical variability in particle flux in the North Available online 16 April 2009 Keywords: Thorium-234 Particle flux Sediment trap Scavenging North Pacific

Siegel, David A.

296

ELIXYS - a fully automated, three-reactor high-pressure radiosynthesizer for development and routine production of diverse PET tracers.  

E-Print Network [OSTI]

cancer treatment with PET/CT: does it make a difference? Jfor decentralized production of PET tracers. In Positronprobes FMAU, FHBG, and FHPG as PET imaging agents for HSV1-

2013-01-01T23:59:59.000Z

297

Interpreting Energy and Tracer Spectra of Upper-Ocean Turbulence in the Submesoscale Range (1–200 km)  

E-Print Network [OSTI]

Submesoscale (1–200 km) wavenumber spectra of kinetic and potential energy and tracer variance are obtained from in situ observations in the Gulf Stream region and in the eastern subtropical North Pacific. In the Gulf ...

Ferrari, Raffaele

298

High-resolution stratospheric tracer fields estimated from satellite observations using Lagrangian trajectory calculations  

SciTech Connect (OSTI)

A technique is introduced by which high-resolution tracer fields may be constructed from low-resolution satellite observations. The technique relies upon the continual cascade of tracer variance from large to small scales and makes use of wind fields generated by a data assimilation scheme. To demonstrate its usefulness, the technique has been applied in a study of isentropic distributions of nitrous oxide in the winter midstratosphere, using measurements made by the Improved Stratospheric and Mesospheric Sounder (ISAMS) instrument on the Upper Atmosphere Research Satellite (UARS). The results show that the high-resolution fields significantly increase the amount of information that is available from the satellite observations. The fields give insights into the characteristic structure and evolution of tracer distributions at scales that are normally obscured from view. Two results are particularly noteworthy. First, at the interface between low and middle latitudes there is evidence of active mixing. This mixing occurs on the eastern, equatorward side of air that is being drawn toward high latitudes around the polar vortex. Second, in the anticyclone, a complex pattern of transport is revealed. Air drawn in from low latitudes spirals together with ambient midlatitude air. Small scales are generated relatively slowly in the organized flow, and persistent filamentary structures, with transverse scales of hundreds of kilometers or greater, are seen.

Sutton, R.T.; Maclean, H.; Swinbank, R.; O`Neill, A.; Taylor, F.W. [Oxford Univ., Oxford (United Kingdom)] [Oxford Univ., Oxford (United Kingdom); [Meteorological Office, Bracknell, Berkshire (United Kingdom); [Univ. of Reading, Reading (United Kingdom)

1994-10-01T23:59:59.000Z

299

Field studies of streamflow generation using natural and injected tracers on Bickford and Walker Branch Watersheds  

SciTech Connect (OSTI)

Field studies of streamflow generation were undertaken on two forested watersheds, the West Road subcatchment of Bickford Watershed in central Massachusetts and the West Fork of Walker Branch Watershed in eastern Tennessee. A major component of the research was development of a two-stage methodology for the use of naturally-occurring {sup 222}Rn as a tracer. The first of the two stages was solving a mass-balance equation for {sup 222}Rn around a stream reach of interest in order to calculate Rn{sub q}, the {sup 222}Rn content of the lateral inflow to the reach; a conservative tracer (chloride) and a volatile tracer (propane) were injected into the study stream to account for lateral inflow to, and volatilization from, the study reach. The second stage involved quantitative comparison of Rn{sub q} to the measured {sup 222}Rn concentrations of different subsurface waters in order to assess how important these waters were in contributing lateral inflow to the stream reach.

Genereux, D.; Hemond, H. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Civil Engineering); Mulholland, P. (Oak Ridge National Lab., TN (United States))

1992-05-01T23:59:59.000Z

300

Comparison of observed and predicted short-term tracer gas concentrations in the atmosphere  

SciTech Connect (OSTI)

The Savannah River Laboratory is in the process of conducting a series of atmospheric tracer studies. The inert gas sulfurhexafluoride is released from a height of 62 m for 15 min and concentrations in air are measured on sampling arcs up to 30 km downwind of the release point. Maximum 15 min. air concentrations from 14 of these tracer tests have been compared with the ground-level, centerline air concentration predicted with a Gaussian plume atmospheric transport model using eight different sets of atmospheric dispersion parameters. Preliminary analysis of the results from these comparisons indicates that the dispersion parameters developed at Juelich, West Germany, based on tracers released from a height of 50 m, give the best overall agreement between the predicted and observed values. The median value of the ratio of predicted to observed air concentrations for this set of parameters is 1.3, and the correlation coefficient between the log of the predictions and the log of the observations is 0.72. For the commonly used Pasquill-Gifford dispersion parameters, the values of these same statistics are 4.4 and 0.68, respectively. The Gaussian plume model is widely used to predict air concentrations resulting from short-term radionuclide release to the atmosphere. The results of comparisons such as these must be considered whenever the Gaussian model is used for such purposes. 22 references, 3 tables.

Cotter, S.J.; Miller, C.W.; Lin, W.C.T.

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Experimental investigation of piston heat transfer under conventional diesel and reactivity-controlled compression ignition combustion regimes  

SciTech Connect (OSTI)

The piston of a heavy-duty single-cylinder research engine was instrumented with 11 fast-response surface thermocouples, and a commercial wireless telemetry system was used to transmit the signals from the moving piston. The raw thermocouple data were processed using an inverse heat conduction method that included Tikhonov regularization to recover transient heat flux. By applying symmetry, the data were compiled to provide time-resolved spatial maps of the piston heat flux and surface temperature. A detailed comparison was made between conventional diesel combustion and reactivity-controlled compression ignition combustion operations at matched conditions of load, speed, boost pressure, and combustion phasing. The integrated piston heat transfer was found to be 24% lower, and the mean surface temperature was 25 C lower for reactivity-controlled compression ignition operation as compared to conventional diesel combustion, in spite of the higher peak heat release rate. Lower integrated piston heat transfer for reactivity-controlled compression ignition was found over all the operating conditions tested. The results showed that increasing speed decreased the integrated heat transfer for conventional diesel combustion and reactivity-controlled compression ignition. The effect of the start of injection timing was found to strongly influence conventional diesel combustion heat flux, but had a negligible effect on reactivity-controlled compression ignition heat flux, even in the limit of near top dead center high-reactivity fuel injection timings. These results suggest that the role of the high-reactivity fuel injection does not significantly affect the thermal environment even though it is important for controlling the ignition timing and heat release rate shape. The integrated heat transfer and the dynamic surface heat flux were found to be insensitive to changes in boost pressure for both conventional diesel combustion and reactivity-controlled compression ignition. However, for reactivity-controlled compression ignition, the mean surface temperature increased with changes in boost suggesting that equivalence ratio affects steady-state heat transfer.

Splitter, Derek A [ORNL; Hendricks, Terry Lee [Sandia National Laboratories (SNL); Ghandhi, Jaal B [University of Wisconsin

2014-01-01T23:59:59.000Z

302

A semi-analytical model for heat and mass transfer in geothermal reservoirs to estimate fracture surface-are-to-volume ratios and thermal breakthrough using thermally-decaying and diffusing tracers  

SciTech Connect (OSTI)

A semi-analytical model was developed to conduct rapid scoping calculations of responses of thermally degrading and diffusing tracers in multi-well tracer tests in enhanced geothermal systems (EGS). The model is based on an existing Laplace transform inversion model for solute transport in dual-porosity media. The heat- and mass-transfer calculations are decoupled and conducted sequentially, taking advantage of the fact that heat transfer between fractures and the rock matrix is much more rapid than mass transfer and therefore mass transfer will effectively occur in a locally isothermal system (although the system will be nonisothermal along fracture flow pathways, which is accounted for by discretizing the flow pathways into multiple segments that have different temperature histories). The model takes advantage of the analogies between heat and mass transfer, solving the same governing equations with k{sub m}/({rho}C{sub p}){sub w} being substituted for {phi}D{sub m} in the equation for fracture transport and k{sub m}/({rho}C{sub p}){sub m} being subsituted for D{sub m} in the equation for matrix transport; where k = thermal conductivity (cal/cm-s-K), {rho} = density (g/cm{sup 3}), C{sub p} = heat capacity (at constant pressure) (cal/g-K), {phi} = matrix porosity, and D = tracer diffusion coefficient (cm{sup 2}/s), with the subscripts w and m referring to water and matrix, respectively. A significant advantage of the model is that it executes in a fraction of second on a single-CPU personal computer, making it very amenable for parameter estimation algorithms that involve repeated runs to find global minima. The combined thermal-mass transport model was used to evaluate the ability to estimate when thermal breakthrough would occur in a multi-well EGS configuration using thermally degrading tracers. Calculations were conducted to evaluate the range of values of Arrhenius parameters, A and E{sub {alpha}} (pre-exponential factor, 1/s, and activation energy, cal/mol) required to obtain interpretable responses of thermally-degrading tracers that decay according to the rate constant k{sub d} = Ae{sup -E{sub {alpha}}/RT}, where k{sub d} = decay rate constant (1/s), R = ideal gas constant (1.987 cal/mol-K), and T = absolute temperature (K). It is shown that there are relatively narrow ranges of A and E{sub {alpha}} that will result in readily interpretable tracer responses for any given combination of ambient reservoir temperature and working fluid residence time in a reservoir. The combined model was also used to simulate the responses of conservative tracers with different diffusion coefficients as a way of estimating fracture surface-area-to-volume ratios (SA/V) in multi-well EGS systems. This method takes advantage of the fact that the differences in breakthrough curves of tracers with different matrix diffusion coefficients are a function of SA/V. The model accounts for differences in diffusion coefficients as a function of temperature so that tracer responses obtained at different times can be used to obtain consistent estimates of SA/V as the reservoir cools down. Some single-well applications of this approach are simulated with a numerical model to demonstrate the potential to evaluate the effectiveness of EGS stimulations before a second well is drilled.

Reimus, Paul W [Los Alamos National Laboratory

2010-12-08T23:59:59.000Z

303

ALPHA SPECTROMETRIC EVALUATION OF SRM-995 AS A POTENTIAL URANIUM/THORIUM DOUBLE TRACER SYSTEM FOR AGE-DATING URANIUM MATERIALS  

SciTech Connect (OSTI)

Uranium-233 (t{sub 1/2} {approx} 1.59E5 years) is an artificial, fissile isotope of uranium that has significant importance in nuclear forensics. The isotope provides a unique signature in determining the origin and provenance of uranium-bearing materials and is valuable as a mass spectrometric tracer. Alpha spectrometry was employed in the critical evaluation of a {sup 233}U standard reference material (SRM-995) as a dual tracer system based on the in-growth of {sup 229}Th (t{sub 1/2} {approx} 7.34E3 years) for {approx}35 years following radiochemical purification. Preliminary investigations focused on the isotopic analysis of standards and unmodified fractions of SRM-995; all samples were separated and purified using a multi-column anion-exchange scheme. The {sup 229}Th/{sup 233}U atom ratio for SRM-995 was found to be 1.598E-4 ({+-} 4.50%) using recovery-corrected radiochemical methods. Using the Bateman equations and relevant half-lives, this ratio reflects a material that was purified {approx} 36.8 years prior to this analysis. The calculated age is discussed in contrast with both the date of certification and the recorded date of last purification.

Beals, D.

2011-12-06T23:59:59.000Z

304

Anode reactive bleed and injector shift control strategy  

DOE Patents [OSTI]

A system and method for correcting a large fuel cell voltage spread for a split sub-stack fuel cell system. The system includes a hydrogen source that provides hydrogen to each split sub-stack and bleed valves for bleeding the anode side of the sub-stacks. The system also includes a voltage measuring device for measuring the voltage of each cell in the split sub-stacks. The system provides two levels for correcting a large stack voltage spread problem. The first level includes sending fresh hydrogen to the weak sub-stack well before a normal reactive bleed would occur, and the second level includes sending fresh hydrogen to the weak sub-stack and opening the bleed valve of the other sub-stack when the cell voltage spread is close to stack failure.

Cai, Jun [Rochester, NY; Chowdhury, Akbar [Pittsford, NY; Lerner, Seth E [Honeoye Falls, NY; Marley, William S [Rush, NY; Savage, David R [Rochester, NY; Leary, James K [Rochester, NY

2012-01-03T23:59:59.000Z

305

A novel reactive processing technique: using telechelic polymers to reactively compatibilize polymer blends  

SciTech Connect (OSTI)

Difunctional reactive polymers, telechelics, were used to reactively form multiblock copolymers in situ when melt-blended with a blend of polystyrene and polyisoprene. To quantify the ability of the copolymer to compatibilize the blends, the time evolution of the domain size upon annealing was analyzed by SEM. It was found that the most effective parameter to quantify the ability of the copolymer to inhibit droplet coalescence is Kreltstable, the relative coarsening constant multiplied by the stabilization time. These results indicate that intermediate-molecular-weight telechelic pairs of both highly reactive Anhydride-PS-Anhydride/NH2-PI-NH2 and slower reacting Epoxy-PS-Epoxy/COOH-PI-COOH both effectively suppress coalescence, with the optimal molecular weight being slightly above the critical molecular weight of the homopolymer,Mc. The effects of telechelic loading were also investigated, where the optimal loading concentration for this system was 0.5 wt %, as higher concentrations exhibited a plasticizing effect due to the presence of unreacted low-molecular-weight telechelics present in the blend. A determination of the interfacial coverage of the copolymer shows that a conversion of 1.5-3.0% was required for 20% surface coverage at 5.0 wt % telechelic loading, indicating a large excess of telechelics in this system. At the optimal loading level of 0.5 wt %, a conversion of 15% was required for 20% surface coverage. The results of these experiments provide a clear understanding of the role of telechelic loading and molecular weight on its ability to reactively form interfacial modifiers in phase-separated polymer blends and provide guidelines for the development of similar reactive processing schemes that can use telechelic polymers to reactively compatibilize a broad range of polymer blends.

Ashcraft, Earl C [ORNL; Ji, Haining [ORNL; Mays, Jimmy [ORNL; Dadmun, Mark D [ORNL

2009-01-01T23:59:59.000Z

306

Local Dynamic Reactive Power for Correction of System Voltage Problems  

SciTech Connect (OSTI)

Distribution systems are experiencing outages due to a phenomenon known as local voltage collapse. Local voltage collapse is occurring in part because modern air conditioner compressor motors are much more susceptible to stalling during a voltage dip than older motors. These motors can stall in less than 3 cycles (.05s) when a fault, such as on the sub-transmission system, causes voltage to sag to 70 to 60%. The reasons for this susceptibility are discussed in the report. During the local voltage collapse, voltages are depressed for a period of perhaps one or two minutes. There is a concern that these local events are interacting together over larger areas and may present a challenge to system reliability. An effective method of preventing local voltage collapse is the use of voltage regulation from Distributed Energy Resources (DER) that can supply or absorb reactive power. DER, when properly controlled, can provide a rapid correction to voltage dips and prevent motor stall. This report discusses the phenomenon and causes of local voltage collapse as well as the control methodology we have developed to counter voltage sag. The problem is growing because of the use of low inertia, high efficiency air conditioner (A/C) compressor motors and because the use of electric A/C is growing in use and becoming a larger percentage of system load. A method for local dynamic voltage regulation is discussed which uses reactive power injection or absorption from local DER. This method is independent, rapid, and will not interfere with conventional utility system voltage control. The results of simulations of this method are provided. The method has also been tested at the ORNL s Distributed Energy Communications and Control (DECC) Laboratory using our research inverter and synchronous condenser. These systems at the DECC Lab are interconnected to an actual distribution system, the ORNL distribution system, which is fed from TVA s 161kV sub-transmission backbone. The test results are also provided and discussed. The simulations and testing show that local voltage control from DER can prevent local voltage collapse. The results also show that the control can be provided so quickly, within 0.5 seconds, that is does not interfere with conventional utility methods.

Kueck, John D [ORNL; Rizy, D Tom [ORNL; Li, Fangxing [ORNL; Xu, Yan [ORNL; Li, Huijuan [University of Tennessee, Knoxville (UTK); Adhikari, Sarina [ORNL; Irminger, Philip [ORNL

2008-12-01T23:59:59.000Z

307

Properties of Reactive Oxygen Species by Quantum Monte Carlo  

E-Print Network [OSTI]

The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of Chemistry, Biology and Atmospheric Science. Nevertheless, the electronic structure of such species is a challenge for ab-initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as $N^3-N^4$, where $N$ is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

Andrea Zen; Bernhardt L. Trout; Leonardo Guidoni

2014-03-11T23:59:59.000Z

308

Properties of reactive oxygen species by quantum Monte Carlo  

SciTech Connect (OSTI)

The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of chemistry, biology, and atmospheric science. Nevertheless, the electronic structure of such species is a challenge for ab initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution, and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular, we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as N{sup 3} ? N{sup 4}, where N is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

Zen, Andrea [Dipartimento di Fisica, La Sapienza - Universitŕ di Roma, Piazzale Aldo Moro 2, 00185 Rome (Italy); Trout, Bernhardt L. [Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Ave, Cambridge, Massachusetts 02139 (United States); Guidoni, Leonardo, E-mail: leonardo.guidoni@univaq.it [Dipartimento di Scienze Fisiche e Chimiche, Universitŕ degli studi de L'Aquila, Via Vetoio, 67100 Coppito, L'Aquila (Italy)

2014-07-07T23:59:59.000Z

309

Isotopic Tracers for Biogeochemical Processes and Contaminant Transport: Hanford, Washington  

SciTech Connect (OSTI)

Our goal is to use isotopic measurements to understand how contaminants are introduced to and stored in the vadose zone, and what processes control migration from the vadose zone to groundwater and then to surface water. We have been using the Hanford Site in south-central Washington as our field laboratory, and our investigations are often stimulated by observations made as part of the groundwater monitoring program and vadose zone characterization activities. Understanding the transport of contaminants at Hanford is difficult due to the presence of multiple potential sources within small areas, the long history of activities, the range of disposal methods, and the continuing evolution of the hydrological system. Observations often do not conform to simple models, and cannot be adequately understood with standard characterization approaches, even though the characterization activities are quite extensive. One of our objectives is to test the value of adding isotopic techniques to the characterization program, which has the immediate potential benefit of addressing specific remediation issues, but more importantly, it allows us to study fundamental processes at the scale and in the medium where they need to be understood. Here we focus on two recent studies at the waste management area (WMA) T-TX-TY, which relate to the sources and transport histories of vadose zone and groundwater contamination and contaminant fluid-sediment interaction. The WMA-T and WMA-TX-TY tank farms are located within the 200 West Area in the central portion of the Hanford Site (Fig. 2). They present a complicated picture of mixed groundwater plumes of nitrate, {sup 99}Tc, Cr{sup 6+}, carbon tetrachloride, etc. and multiple potential vadose zone sources such as tank leaks and disposal cribs (Fig. 3). To access potential vadose zone sources, we analyzed samples from cores C3832 near tank TX-104 and from C4104 near tank T-106. Tank T-106 was involved in a major event in 1973 in which 435,000 L of high activity waste leaked to the vadose zone over a seven-week period. Other nearby tanks (T-103 and T-101) are also suspected of having leaked or overfilled. Pore water from these cores was analyzed for U and Sr isotopic compositions. Increasing {sup 99}Tc concentration in monitoring well 299-W11-39 (to 27,000 pCi/L in 2005) near the northeast corner of the WMA-T area prompted the emplacement of a series of new wells, 299-W11-25B, W11-45 (down gradient), and W11-47 (Fig. 3), during which depth discrete samples were collected below the groundwater surface. The depth profile from W11-25B revealed high {sup 99}Tc concentrations peaking at 182,000 pCi/L at {approx}10 m below the water table (Dresel et al. 2006). We obtained aliquots for isotopic analysis of groundwater samples produced by purge-and-pump sampling during the drilling of W11-25B, -45 and -47. In addition we have analyzed groundwater samples from monitoring wells in the vicinity of WMA T-TX-TY.

Donald J. DePaolo; John N. Christensen; Mark E. Conrad; and P. Evan Dresel

2007-04-19T23:59:59.000Z

310

Theoretical and Experimental Evaluation of Chemical Reactivity  

E-Print Network [OSTI]

released and the rate of energy released for a specific reactive chemical. 2.1 DSC DSC is a popular screening tool (safe and fast) and can provide an overall indication of exothermic activity of the chemical being tested. In a DSC, a sample and a... endothermic or exothermic reaction. When the rate of heat generation in the sample exceeds a particular value, the heat supply to the sample is cut off and this additional heat gain is attributed to exothermic activity within the sample.17 From the DSC...

Wang, Qingsheng

2011-10-21T23:59:59.000Z

311

Preparation of reactive beta-dicalcium silicate  

DOE Patents [OSTI]

This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane and hydrogen, at a temperature of about 850.degree.-1000.degree. C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

Shen, Ming-Shing (Laramie, WY, NJ); Chen, James M. (Rahway, NJ); Yang, Ralph T. (Amherst, NY)

1982-01-01T23:59:59.000Z

312

Preparation of reactive beta-dicalcium silicate  

DOE Patents [OSTI]

This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica, and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane, and hydrogen, at a temperature of about 850 to 1000/sup 0/C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

Shen, M.S.; Chen, J.M.; Yang, R.T.

1980-02-28T23:59:59.000Z

313

Section 10: Turbulence and reactive flows 1 Section 10: Turbulence and reactive flows  

E-Print Network [OSTI]

premixed combustion is recently a theme of interest in gas turbines and other industrial applications flames #12;2 Section 10: Turbulence and reactive flows for gas turbine application. In: International Gas combustion LES in- cluding thickened flame model A. Hosseinzadeh, A. Sadiki, J. Janicka (TU Darmstadt) Lean

Kohlenbach, Ulrich

314

A new statistical dispersion model for tracer tests and contaminant spread in porous media  

SciTech Connect (OSTI)

Dispersion of solutes moving in permeable media is an essential control to describe fluid flow in permeable media. Dispersion can be thought of as a spreading of a solute caused by the presence of microscopic inhomogeneities. An accurate model for dispersion is needed for accurate estimation of oil recovery efficiencies and clean up costs of subsurface contaminants. Current approaches utilizing the fickian assumption fall short in describing the real physics of spreading during a solute transport process. Numerous field investigations have shown that dispersivities measured in the field are much larger than those measured in the lab for the same type of porous material. Moreover, field measured dispersivities have been shown to be scale dependent, that is, a tracer test conducted over a longer travel path will yield a larger dispersivity value than a tracer test conducted in the same geologic formation over a shorter travel path. Numerous approaches to address this problem have been developed yet none attempted to go beyond the Fickian dispersion assumption. In this study, a convective dispersivity is introduced. New model assumes that dispersion is dimensionless and mainly determined by pore size distribution. The new model results in a spread that increases linearly with time contrary to conventional model, which predicts a mixing zone length that increases with square root of time. Therefore, new model explains the field test results that indicate increasing dispersivity with distance. The model validations are in perfect agreement with experimental results, which include; Ganapathy et al.`s slug experiment on Antolini sandstone, Handy`s radioactive tracer experiment on Alhambra sandstone, and CT experiment conducted at BDM-OK/NIPER facilities on Tallant sandstone.

Ates, H.; Kasap, E. [Univ. of Tulsa, OK (United States)

1995-12-31T23:59:59.000Z

315

Results of injection and tracer tests in Olkaria East Geothermal Field  

SciTech Connect (OSTI)

This paper presents results of a six month Injection and Tracer test done in Olkaria East Geothermal Field The Injection tests show that commencement of injection prior to onset of large drawdown in the reservoir leads to greater sustenance of well production and can reduce well cycling which is a common feature of wells in Olkaria East Field. For cases where injection is started after some drawdown has occurred in the reservoir, injection while leading to improvement of well output can also lead to increase in well cycling which is a non desirable side effect. Tracer tests reveal slow rate of fluid migration (< 5 m/hr). However estimates of the cumulative tracer returns over the period of injection is at least 31% which is large and reveals the danger of late time thermal drawdown and possible loss of production. It is shown in the discussion that the two sets of results are consistent with a reservoir where high permeability occurs along contact surfaces which act as horizontal "fractures" while the formations between the "fractures" have low permeability. This type of fracture system will lead to channeled flow of injected fluid and therefore greater thermal depletion along the fractures while formations further from the fracture would still be at higher temperature. In an attempt to try and achieve a more uniform thermal depletion in the reservoir, it is proposed that continuous injection be done for short periods (~2 years) and this be followed by recovery periods of the nearly the same length of time before resumption of injection again.

Ambusso, Willis J.

1994-01-20T23:59:59.000Z

316

Reactive Dehydration technology for Production of Fuels and Chemicals...  

Broader source: Energy.gov (indexed) [DOE]

Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based chemicals from complex aqueous mixtures. SeparationPurification of Biomass...

317

Comparison of Conventional Diesel and Reactivity Controlled Compressio...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of Advanced Diesel Engine Combustion Strategies Effect of Compression Ratio and Piston Geometry on RCCI load limit High Efficiency Fuel Reactivity Controlled Compression...

318

Chemically Reactive Working Fluids for the Capture and Transport...  

Broader source: Energy.gov (indexed) [DOE]

Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working Fluids Low-Cost Light Weigh Thin Film Solar Concentrators...

319

Chemical Analysis of Complex Organic Mixtures Using Reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mass Spectrometry. Abstract: Reactive nanospray desorption electrospray ionization (nano-DESI) combined with high-resolution mass spectrometry was utilized for the analysis of...

320

Airborne measurement of OH reactivity during INTEX-B  

E-Print Network [OSTI]

plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

XCHEM-1D: A Heat Transfer/Chemical Kinetics Computer Program for multilayered reactive materials  

SciTech Connect (OSTI)

An eXplosive CHEMical kinetics code, XCHEM, has been developed to solve the reactive diffusion equations associated with thermal ignition of energetic materials. This method-of-lines code uses stiff numerical methods and adaptive meshing to resolve relevant combustion physics. Solution accuracy is maintained between multilayered materials consisting of blends of reactive components and/or inert materials. Phase change and variable properties are included in one-dimensional slab, cylindrical and spherical geometries. Temperature-dependent thermal properties have been incorporated and the modification of thermal conductivities to include decomposition effects are estimated using solid/gas volume fractions determined by species fractions. Gas transport properties, including high pressure corrections, have also been included. Time varying temperature, heat flux, convective and thermal radiation boundary conditions, and layer to layer contact resistances have also been implemented.

Gross, R.J.; Baer, M.R.; Hobbs, M.L.

1993-10-01T23:59:59.000Z

322

Completing the complex Poynting theorem: Conservation of reactive energy in reactive time  

E-Print Network [OSTI]

The complex Poynting theorem is extended canonically to a time-scale domain $(t, s)$ by replacing the phasors of time-harmonic fields by the analytic signals $X(r, t+is)$ of fields $X(r,t)$ with general time dependence. The imaginary time $s>0$ is shown to play the role of a time resolution scale, and the extended Poynting theorem splits into two conservation laws: its real part gives the conservation in $t$ of the scale-averaged active energy at fixed $s$, and its imaginary part gives the conservation in $s$ of the scale-averaged reactive energy at fixed $t$. At coarse scales (large $s$, slow time), where the system reduces to the circuit level, this may have applications to the theory of electric power transmission and conditioning. At fine scales (small $s$, fast time) it describes reactive energy dynamics in radiating systems.

Gerald Kaiser

2014-12-11T23:59:59.000Z

323

The Lagrangian dynamics of thermal tracer particles in Navier-Stokes fluids  

E-Print Network [OSTI]

A basic issue for Navier-Stokes (NS) fluids is their characterization in terms of the so-called NS phase-space classical dynamical system, which provides a mathematical model for the description of the dynamics of infinitesimal (or i\\textit{deal}) tracer particles in these fluids. The goal of this paper is to analyze the properties of a particular subset of solutions of the NS dynamical system, denoted as \\textit{thermal tracer particles} (TTPs), whose states are determined uniquely by the NS fluid fields. Applications concerning both deterministic and stochastic NS fluids are pointed out. In particular, in both cases it is shown that in terms of the ensemble of TTPs a statistical description of NS fluids can be formulated. In the case of stochastic fluids this feature permits to uniquely establish the corresponding Langevin and Fokker-Planck dynamics. Finally, the relationship with the customary statistical treatment of hydrodynamic turbulence (HT) is analyzed and a solution to the closure problem for the statistical description of HT is proposed.

Massimo Tessarotto; Claudio Asci; Claudio Cremaschini; Alessandro Soranzo; Marco Tessarotto; Gino Tironi

2012-03-17T23:59:59.000Z

324

A Really Good Hammer: Quantification of Mass Transfer Using Perfluorocarbon Tracers (475th Brookhaven Lecture)  

SciTech Connect (OSTI)

Brookhaven Lab’s perfluorocarbon tracer (PFT) technology can be viewed as a hammer looking for nails. But, according to Tom Watson, leader of the Lab’s Tracer Technology Group in the Environmental Research and Technology Division (ERTD), “It’s a really good hammer!” The colorless, odorless and safe gases have a number of research uses, from modeling how airborne contaminants might move through urban canyons to help first responders plan their response to potential terrorist attacks and accidents to locating leaks in underground gas pipes. Their extremely low background level — detectable at one part per quadrillion — allows their transport to be easily tracked. Lab researchers used PFTs during the 2005 Urban Dispersion Program field studies in New York City, gathering data to help improve models of how a gas or chemical release might move around Manhattan’s tall buildings and canyons. Closer to home, scientists also used PFTs to make ventilation measurements in Bldg. 400 on the Lab site to provide data to test air flow models used in determining the effects of passive and active air exchange on the levels of indoor and outdoor air pollution, and to determine the effects of an accidental or intentional release of hazardous substances in or around buildings.

Watson, Tom [BNL Environmental Sciences, Tracer Technology Group

2012-02-15T23:59:59.000Z

325

Etching radical controlled gas chopped deep reactive ion etching  

DOE Patents [OSTI]

A method for silicon micromachining techniques based on high aspect ratio reactive ion etching with gas chopping has been developed capable of producing essentially scallop-free, smooth, sidewall surfaces. The method uses precisely controlled, alternated (or chopped) gas flow of the etching and deposition gas precursors to produce a controllable sidewall passivation capable of high anisotropy. The dynamic control of sidewall passivation is achieved by carefully controlling fluorine radical presence with moderator gasses, such as CH.sub.4 and controlling the passivation rate and stoichiometry using a CF.sub.2 source. In this manner, sidewall polymer deposition thicknesses are very well controlled, reducing sidewall ripples to very small levels. By combining inductively coupled plasmas with controlled fluorocarbon chemistry, good control of vertical structures with very low sidewall roughness may be produced. Results show silicon features with an aspect ratio of 20:1 for 10 nm features with applicability to nano-applications in the sub-50 nm regime. By comparison, previous traditional gas chopping techniques have produced rippled or scalloped sidewalls in a range of 50 to 100 nm roughness.

Olynick, Deidre; Rangelow, Ivo; Chao, Weilun

2013-10-01T23:59:59.000Z

326

The Specification and Execution of Heterogeneous Synchronous Reactive Systems  

E-Print Network [OSTI]

The Specification and Execution of Heterogeneous Synchronous Reactive Systems by Stephen Anthony in Engineering---Electrical Engineering and Computer Sciences in the GRADUATE DIVISION of the UNIVERSITY of Heterogeneous Synchronous Reactive Systems Copyright ĂŁ 1997 by Stephen Anthony Edwards #12; Abstract

327

A Modified Reactive Control Framework for Cooperative Mobile Robots  

E-Print Network [OSTI]

A Modified Reactive Control Framework for Cooperative Mobile Robots J. Salido a , J.M. Dolan a , J Dept. of Electrical & Computer Engineering, Carnegie Mellon Univ. Pittsburgh, PA 15213­3890 USA. Purely reactive approaches such as that of Brooks are efficient, but lack a mechanism for global control

328

Reactive Sputtering of Bismuth Vanadate Photoanodes for Solar Water Splitting  

E-Print Network [OSTI]

Reactive Sputtering of Bismuth Vanadate Photoanodes for Solar Water Splitting Le Chen,, Esther of Electrical Engineering and Computer Sciences, University of California, Berkeley, Berkeley, California 94720 has remained relatively underexplored. Here, we report the synthesis of BiVO4 thin films by reactive

Javey, Ali

329

Reactive Rearrangement of Parts under Sensor Inaccuracy: Particle Filter Approach  

E-Print Network [OSTI]

Reactive Rearrangement of Parts under Sensor Inaccuracy: Particle Filter Approach Hal^uk Bayram, Electrical and Electronic Engineering Bogazici University, Bebek 34342 Istanbul Turkey Abstract-- The paper will be left undisturbed, the robot is required to employ a reactive strategy. A feedback-based event

330

Reactive oxygen species deglycosilate glomerular a-dystroglycan  

E-Print Network [OSTI]

Reactive oxygen species deglycosilate glomerular a-dystroglycan NPJ Vogtla¨nder1 , WPM Tamboer1 open. Reactive oxygen species (ROS) are known to degrade and depolymerize carbohydrates, and to playDa in skeletal muscle, ranging from 120 kDa in brain to 190 kDa in the Torpedo electric organ.8

Campbell, Kevin P.

331

Towards Interactive Timing Analysis for Designing Reactive Systems  

E-Print Network [OSTI]

Towards Interactive Timing Analysis for Designing Reactive Systems Insa Fuhrmann David Broman Steven Smyth Reinhard von Hanxleden Electrical Engineering and Computer Sciences University of California Interactive Timing Analysis for Designing Reactive Systems Insa Fuhrmann1 , David Broman2,3 , Steven Smyth1

332

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network [OSTI]

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

333

On-Road Emission Measurements of Reactive Nitrogen Compounds from  

E-Print Network [OSTI]

, nitric oxide (NO), nitrogen dioxide (NO2), ammonia (NH3), and nitrous acid (HONO) produced by internalOn-Road Emission Measurements of Reactive Nitrogen Compounds from Three California Cities G A R Y measurements of reactive nitrogen compounds from light-duty vehicles. At the San Jose and wLA sites

Denver, University of

334

ALUMINOSILICATE-COATED SILICA SAND FOR REACTIVE TRANSPORT EXPERIMENTS  

E-Print Network [OSTI]

ALUMINOSILICATE-COATED SILICA SAND FOR REACTIVE TRANSPORT EXPERIMENTS By JORGE ANTONIO JEREZ transport experiments; Dr. Barbara Williams and Jason Shira from University of Idaho for providing access-COATED SILICA SAND FOR REACTIVE TRANSPORT EXPERIMENTS Abstract by Jorge Antonio Jerez Briones, Ph.D. Washington

Flury, Markus

335

REAL-TIME TRACER MONITORING OF RESERVOIR STIMULATION PROCEDURES VIA ELECTRONIC WIRELINE AND TELEMETRY DATA TRANSMISSION  

SciTech Connect (OSTI)

Finalized Phase 2-3 project work has field-proven two separate real-time reservoir processes that were co-developed via funding by the National Energy Technology Laboratory (NETL). Both technologies are presently patented in the United States and select foreign markets; a downhole-commingled reservoir stimulation procedure and a real-time tracer-logged fracturing diagnostic system. Phase 2 and early Phase 3 project work included the research, development and well testing of a U.S. patented gamma tracer fracturing diagnostic system. This stimulation logging process was successfully field-demonstrated; real-time tracer measurement of fracture height while fracturing was accomplished and proven technically possible. However, after the initial well tests, there were several licensing issues that developed between service providers that restricted and minimized Realtimezone's (RTZ) ability to field-test the real-time gamma diagnostic system as was originally outlined for this project. Said restrictions were encountered after when one major provider agreed to license their gamma logging tools to another. Both of these companies previously promised contributory support toward Realtimezone's DE-FC26-99FT40129 project work, however, actual support was less than desired when newly-licensed wireline gamma logging tools from one company were converted by the other from electric wireline into slickline, batter-powered ''memory'' tools for post-stimulation logging purposes. Unfortunately, the converted post-fracture measurement memory tools have no applications in experimentally monitoring real-time movement of tracers in the reservoir concurrent with the fracturing treatment. RTZ subsequently worked with other tracer gamma-logging tool companies for basic gamma logging services, but with lessened results due to lack of multiple-isotope detection capability. In addition to real-time logging system development and well testing, final Phase 2 and Phase 3 project work included the development of a real-time reservoir stimulation procedure, which was successfully field-demonstrated and is presently patented in the U.S. and select foreign countries, including Venezuela, Brazil and Canada. Said patents are co-owned by RTZ and the National Energy Technology Lab (NETL). In 2002, Realtimezone and the NETL licensed said patents to Halliburton Energy Services (HES). Additional licensing agreements (LA) are anticipated with other service industry companies in 2005. Final Phase 3 work has led to commercial applications of the real-time reservoir stimulation procedure. Four successfully downhole-mixed well tests were conducted with commercially expected production results. The most recent, fourth field test was a downhole-mixed stimulated well completed in June, 2004, which currently produces 11 BOPD with 90 barrels of water per day. Conducted Phase 2 and Phase 3 field-test work to date has resulted in the fine-tuning of a real-time enhanced stimulation system that will significantly increase future petroleum well recoveries in the United States and foreign petroleum fields, both onshore and offshore, and in vertical and horizontal wells.

George L. Scott III

2005-01-01T23:59:59.000Z

336

Addition of tracers into the polypropylene in view of automatic sorting of plastic wastes using X-ray fluorescence spectrometry  

SciTech Connect (OSTI)

This study focused on the detection of rare earth oxides, used as tracers for the identification of polymer materials, using XRF (X-ray fluorescence) spectrometry. The tests were carried out in a test system device which allows the collection of static measurements of the samples' spectrum through the use of energy dispersive X-ray fluorescence technology. A sorting process based on tracers added into the polymer matrix is proposed in order to increase sorting selectivity of polypropylene during end-of-life recycling. Tracers consist of systems formed by one or by several substances dispersed into a material, to add a selective property to it, with the aim of improving the efficiency of sorting and high speed identification. Several samples containing rare earth oxides (Y{sub 2}O{sub 3}, CeO{sub 2}, Nd{sub 2}O{sub 3}, Gd{sub 2}O{sub 3}, Dy{sub 2}O{sub 3}, Er{sub 2}O{sub 3} and Yb{sub 2}O{sub 3}) in different concentrations were prepared in order to analyse some of the parameters which can influence the detection, such as the concentration of tracers, the acquisition time and the possible overlapping among the tracers. This work shows that by using the XRF test system device, it was possible to detect 5 of the 7 tracers tested for 1 min exposure time and at a concentration level of 1000 ppm. These two parameters will play an important role in the development of an industrial device, which indicates the necessity of further works that needs to be conducted in order to reduce them.

Bezati, F., E-mail: feliks.bezati@ensam.e [MAPIE-Laboratoire de Modelisation, Analyse et Prevention des Impacts Environnementaux, Institut ENSAM Savoie Technolac, 4 Rue du Lac Majeur, F-73375 Le Bourget du Lac Cedex (France); IMP/LMM-Ingenierie des Materiaux Polymeres - Laboratoire des Materiaux Macromoleculaires UMR 5223, INSA de Lyon Bat. Jules VERNE, 17, rue Jean Capelle F-69621 Villeurbanne Cedex (France); Froelich, D. [MAPIE-Laboratoire de Modelisation, Analyse et Prevention des Impacts Environnementaux, Institut ENSAM Savoie Technolac, 4 Rue du Lac Majeur, F-73375 Le Bourget du Lac Cedex (France); Massardier, V. [IMP/LMM-Ingenierie des Materiaux Polymeres - Laboratoire des Materiaux Macromoleculaires UMR 5223, INSA de Lyon Bat. Jules VERNE, 17, rue Jean Capelle F-69621 Villeurbanne Cedex (France); Maris, E. [MAPIE-Laboratoire de Modelisation, Analyse et Prevention des Impacts Environnementaux, Institut ENSAM Savoie Technolac, 4 Rue du Lac Majeur, F-73375 Le Bourget du Lac Cedex (France)

2010-04-15T23:59:59.000Z

337

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect (OSTI)

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

338

Development of reactivity feedback effect measurement techniques under sub-critical condition in fast reactors  

SciTech Connect (OSTI)

The first-of-a-kind reactor has been licensed by a safety examination of the plant design based on the measured data in precedent mock-up experiments. The validity of the safety design can be confirmed without a mock-up experiment, if the reactor feed-back characteristics can be measured before operation, with the constructed reactor itself. The 'Synthesis Method', a systematic and sophisticated method of sub-criticality measurement, is proposed in this work to ensure the safety margin before operation. The 'Synthesis Method' is based on the modified source multiplication method (MSM) combined with the noise analysis method to measure the reference sub-criticality level for MSM. A numerical simulation for the control-rod reactivity worth and the isothermal feed-back reactivity was conducted for typical fast reactors of 100 MWe-size, 300 MWe-size, 750 MWe-size, and 1500 MWe-size to investigate the applicability of Synthesis Method. The number of neutron detectors and their positions necessary for the measurement were investigated for both methods of MSM and the noise analysis by a series of parametric survey calculations. As a result, it was suggested that a neutron detector located above the core center and three or more neutron detectors located above the radial blanket region enable the measurement of sub-criticality within 10% uncertainty from -$0.5 to -$2 and within 15% uncertainty for the deeper sub-criticality. (authors)

Kitano, A.; Nishi, H. [Japan Atomic Energy Agency, 1 1, Shiraki, Tsuruga-shi, Fukui-ken, 919-1279 (Japan); Suzuki, T. [Japan Atomic Energy Agency, 2-4, Shirakata-Shirane, Tokai-mura, Naka-gun, Ibaraki-ken, 319-1195 (Japan); Okajima, S.; Kanemoto, S. [Univ. of Aizu, Tsuruga, Ikki-machi, Aizu-Wakamatsu-shi, Fukushima-ken, 965-8580 (Japan)

2012-07-01T23:59:59.000Z

339

The Post-Shock Chemical Lifetimes of Outflow Tracers and a Possible New Mechanism to Produce Water Ice Mantles  

E-Print Network [OSTI]

We have used a coupled time-dependent chemical and dynamical model to investigate the lifetime of the chemical legacy left in the wake of C-type shocks. We concentrate this study on the chemistry of H2O and O2, two molecules which are predicted to have abundances that are significantly affected in shock-heated gas. Two models are presented: (1) a three-stage model of pre-shock, shocked, and post-shock gas; and (2) a Monte-Carlo cloud simulation where we explore the effects of stochastic shock activity on molecular gas over a cloud lifetime. In agreement with previous studies, we find that shock velocities in excess of 10 km s^-1 are required to convert all of the oxygen not locked in CO into H2O before the gas has an opportunity to cool. For pure gas-phase models the lifetime of the high water abundances, or ``H2O legacy'', in the post-shock gas is 4 - 7 x 10^5 years. Through the Monte Carlo cloud simulation we demonstrate that the time-average abundance of H2O is a sensitive function of the frequency of shocks. Thus we predict that the abundance of H2O and other known outflow tracers can be used to trace the history of shock activity in molecular gas. For gas-grain models we find that the abundance of water-ice on grain surfaces can be quite large and is comparable to that observed in molecular clouds. This offers a possible alternative method to create water mantles without resorting to grain surface chemistry: gas heating and chemical modification due to a C-type shock and subsequent depletion of the gas-phase species onto grain mantles.

Edwin A. Bergin; Gary J. Melnick; David A. Neufeld

1998-03-30T23:59:59.000Z

340

Reactive flash volatilization of fluid fuels  

DOE Patents [OSTI]

The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

2013-01-08T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Geochemical fluid characteristics and main achievements about tracer tests at Soultz-sous-Forts (France) 1 EC Contract SES6-CT-2003-502706  

E-Print Network [OSTI]

Geochemical fluid characteristics and main achievements about tracer tests at Soultz Related with Work Package WP1a (Short term fluid circulation tests) and WP1c (Data acquisition) GEOCHEMICAL FLUID CHARACTERISTICS AND MAIN ACHIEVEMENTS ABOUT TRACER TESTS AT SOULTZ-SOUS-FORĂ?TS (FRANCE

Boyer, Edmond

342

Hydrogen absorption characteristics of amorphous LaNi[sub 5. 0] films prepared by reactive sputtering  

SciTech Connect (OSTI)

Amorphous LaNi[sub 5] thin films are expected to be one of the promising materials for use in hydrogen separation and battery electrodes, because the durability of the films is great in regard to the hydrogen absorption-desorption cycling process and the films have excellent resistance to harmful impurities in the hydrogen gas in comparison with the crystalline bulk material. An amorphous LaNi[sub 5.0] film having high hydrogen density and low hydrogen-induced stress was obtained by means of a reactive sputtering method using an Ar-H[sub 2] gas mixture. Pressure-composition isotherms show that the amount of hydrogen (H/LaNi[sub 5.0]) taken up by a formula weight of LaNi[sub 5.0] is about 1.5 times larger for the reactive sputtered film than for the conventional sputtered film prepared by using Ar gas. 18 refs., 1 fig, 1 tabs.

Sakaguchi, H.; Tsujimoto, T.; Adachi, Ginya (Osaka University, Suita (Japan))

1993-01-01T23:59:59.000Z

343

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

344

Metal-Pyrrolide Complexes in Three-fold Symmetry: Synthesis, Structure, Reactivity and Magnetism  

E-Print Network [OSTI]

Structure, Reactivity and Magnetism by William Hill Harman AStructure, Reactivity and Magnetism by William Hill Harmanlost time. Dave taught me magnetism and what it takes to win

Harman, William Hill

2010-01-01T23:59:59.000Z

345

Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene  

E-Print Network [OSTI]

The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement ...

Arizpe, Luis (Luis Alfredo)

2011-01-01T23:59:59.000Z

346

Aging Enhances the Production of Reactive Oxygen Species andBactericid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

347

E-Print Network 3.0 - accumulate reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reactive oxygen Search Powered by Explorit Topic List Advanced Search Sample search results for: accumulate reactive oxygen Page: << < 1 2 3 4 5 > >> 1 CLINICAL CONCEPTS AND...

348

Reactivity of iron-bearing minerals and CO2 sequestration: A...  

Office of Scientific and Technical Information (OSTI)

Reactivity of iron-bearing minerals and CO2 sequestration: A multi-disciplinary experimental approach Re-direct Destination: The reactivity of sandstones was studied under...

349

ESTIMATING THE UNCERTAINTY IN REACTIVITY ACCIDENT NEUTRONIC CALCULATIONS  

SciTech Connect (OSTI)

A study of the uncertainty in calculations of the rod ejection accident in a pressurized water reactor is being carried out for the US Nuclear Regulatory Commission. This paper is a progress report on that study. Results are presented for the sensitivity of core energy deposition to the key parameters: ejected rod worth, delayed neutron fraction, Doppler reactivity coefficient, and fuel specific heat. These results can be used in the future to estimate the uncertainty in local fuel enthalpy given some assumptions about the uncertainty in the key parameters. This study is also concerned with the effect of the intra-assembly representation in calculations. The issue is the error that might be present if assembly-average power is calculated, and pin peaking factors from a static calculation are then used to determine local fuel enthalpy. This is being studied with the help of a collaborative effort with Russian and French analysts who are using codes with different intra-assembly representations. The US code being used is PARCS which calculates power on an assembly-average basis. The Russian code being used is BARS which calculates power for individual fuel pins using a heterogeneous representation based on a Green's Function method.

DIAMOND,D.J.; YANG,C.Y.; ARONSON,A.L.

1998-10-26T23:59:59.000Z

350

Estimating the uncertainty in reactivity accident neutronic calculations  

SciTech Connect (OSTI)

A study of the uncertainty in calculations of the rod ejection accident in a pressurized water reactor is being carried out for the US Nuclear Regulatory Commission. This paper is a progress report on that study. Results are presented for the sensitivity of core energy deposition to the key parameters: ejected rod worth, delayed neutron fraction, Doppler reactivity coefficient, and fuel specific heat. These results can be used in the future to estimate the uncertainty in local fuel enthalpy given some assumptions about the uncertainty in the key parameters. This study is also concerned with the effect of the intra-assembly representation in calculations. The issue is the error that might be present if assembly-average power is calculated, and pin peaking factors from a static calculation are then used to determine local fuel enthalpy. This is being studied with the help of a collaborative effort with Russian and French analysts who are using codes with different intra-assembly representations. The US code being used is PARCS which calculates power on an assembly-average basis. The Russian code being used is BARS which calculates power for individual fuel pins using a heterogeneous representation based on a Green`s Function method.

Diamond, D.J.; Yang, C.Y.; Aronson, A.L.

1998-12-31T23:59:59.000Z

351

Reactive gases evolved during pyrolysis of Devonian oil shale  

SciTech Connect (OSTI)

Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

1986-11-01T23:59:59.000Z

352

AN INTEGRATED APPROACH TO CHARACTERIZING BYPASSED OIL IN HETEROGENEOUS AND FRACTURED RESERVOIRS USING PARTITIONING TRACERS  

SciTech Connect (OSTI)

We explore the use of efficient streamline-based simulation approaches for modeling and analysis partitioning interwell tracer tests in heterogeneous and fractured hydrocarbon reservoirs. The streamline approach is generalized to model water injection in naturally fractured reservoirs through the use of a dual media approach. The fractures and matrix are treated as separate continua that are connected through a transfer function, as in conventional finite difference simulators for modeling fractured systems. A detailed comparison with a commercial finite difference simulator shows very good agreement. Furthermore, an examination of the scaling behavior of the computation time indicates that the streamline approach is likely to result in significant savings for large-scale field applications. We also propose a novel approach to history matching finite-difference models that combines the advantage of the streamline models with the versatility of finite-difference simulation. In our approach, we utilize the streamline-derived sensitivities to facilitate history matching during finite-difference simulation. The use of finite-difference model allows us to account for detailed process physics and compressibility effects. The approach is very fast and avoids much of the subjective judgments and time-consuming trial-and-errors associated with manual history matching. We demonstrate the power and utility of our approach using a synthetic example and two field examples. Finally, we discuss several alternative ways of using partitioning interwell tracer tests (PITTs) in oil fields for the calculation of oil saturation, swept pore volume and sweep efficiency, and assess the accuracy of such tests under a variety of reservoir conditions.

Akhil Datta-Gupta

2004-08-01T23:59:59.000Z

353

{sup 41}Ca as a tracer for calcium uptake and deposition in heart tissue during ischemia and reperfusion  

SciTech Connect (OSTI)

We have developed techniques and are commencing experiments using enriched {sup 41}Ca as a tracer in isolated rabbit heart preparations. The aims of the study are to measure calcium uptake and deposition in response to cardiac ischemia and reperfusion, and to investigate events and mechanism leading to irreversible myocyte injury.

Southon, J.R. [Lawrence Livermore National Lab., CA (United States); Bishop, M.S.; Kost, G.J. [California Univ., Davis, CA (United States). Dept. of Medical Pathology and Biomedical Engineering

1993-09-17T23:59:59.000Z

354

Self-consistent magnetic properties of magnetite tracers optimized for magnetic particle imaging measured by ac susceptometry,  

E-Print Network [OSTI]

Self-consistent magnetic properties of magnetite tracers optimized for magnetic particle imaging measured by ac susceptometry, magnetorelaxometry and magnetic particle spectroscopy Frank Ludwig a , Hilke. Krishnan b,n a Institute of Electrical Measurement and Fundamental Electrical Engineering, TU Braunschweig

Krishnan, Kannan M.

355

Thorium isotopes as tracers of particles dynamics and deep water circulation in the Indian sector of the  

E-Print Network [OSTI]

Thorium isotopes as tracers of particles dynamics and deep water circulation in the Indian sector to study the distribution of thorium isotopes (234 Th, 232 Th and 230 Th) in the water column of the Indian in surface water (0­100 m) and a model was applied to estimate a residence time relative to the thorium

Coppola, Laurent

356

Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique Iglesia*  

E-Print Network [OSTI]

Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique unlabeled products from mixtures of propene and propane-2-13C reactants. Aromatic products of propane-2-13C-Parmer) that allowed differential reactor operation (propane reactions were

Iglesia, Enrique

357

A reaction-based paradigm to model reactive chemical transport in groundwater with general kinetic and equilibrium reactions  

SciTech Connect (OSTI)

This paper presents a reaction-based water quality transport model in subsurface flow systems. Transport of chemical species with a variety of chemical and physical processes is mathematically described by M partial differential equations (PDEs). Decomposition via Gauss-Jordan column reduction of the reaction network transforms M species reactive transport equations into two sets of equations: a set of thermodynamic equilibrium equations representing NE equilibrium reactions and a set of reactive transport equations of M-NE kinetic-variables involving no equilibrium reactions (a kinetic-variable is a linear combination of species). The elimination of equilibrium reactions from reactive transport equations allows robust and efficient numerical integration. The model solves the PDEs of kinetic-variables rather than individual chemical species, which reduces the number of reactive transport equations and simplifies the reaction terms in the equations. A variety of numerical methods are investigated for solving the coupled transport and reaction equations. Simulation comparisons with exact solutions were performed to verify numerical accuracy and assess the effectiveness of various numerical strategies to deal with different application circumstances. Two validation examples involving simulations of uranium transport in soil columns are presented to evaluate the ability of the model to simulate reactive transport with complex reaction networks involving both kinetic and equilibrium reactions.

Zhang, Fan [ORNL; Yeh, Gour-Tsyh [University of Central Florida, Orlando; Parker, Jack C [ORNL; Brooks, Scott C [ORNL; Pace, Molly [ORNL; Kim, Young Jin [ORNL; Jardine, Philip M [ORNL; Watson, David B [ORNL

2007-01-01T23:59:59.000Z

358

Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior in Complex Interfacial Systems. Final Technical Report  

SciTech Connect (OSTI)

This research program explored the efficacy of using molecular-level manipulation, imaging and scanning tunneling spectroscopy in conjunction with supersonic molecular beam gas-surface scattering to significantly enhance our understanding of chemical processes occurring on well-characterized interfaces. One program focus was on the spatially-resolved emergent behavior of complex reaction systems as a function of the local geometry and density of adsorbate-substrate systems under reaction conditions. Another focus was on elucidating the emergent electronic and related reactivity characteristics of intentionally constructed single and multicomponent atom- and nanoparticle-based materials. We also examined emergent chirality and self-organization in adsorbed molecular systems where collective interactions between adsorbates and the supporting interface lead to spatial symmetry breaking. In many of these studies we combined the advantages of scanning tunneling (STM) and atomic force (AFM) imaging, scanning tunneling local electronic spectroscopy (STS), and reactive supersonic molecular beams to elucidate precise details of interfacial reactivity that had not been observed by more traditional surface science methods. Using these methods, it was possible to examine, for example, the differential reactivity of molecules adsorbed at different bonding sites in conjunction with how reactivity is modified by the local configuration of nearby adsorbates. At the core of this effort was the goal of significantly extending our understanding of interfacial atomic-scale interactions to create, with intent, molecular assemblies and materials with advanced chemical and physical properties. This ambitious program addressed several key topics in DOE Grand Challenge Science, including emergent chemical and physical properties in condensed phase systems, novel uses of chemical imaging, and the development of advanced reactivity concepts in combustion and catalysis including carbon management. These activities directly benefitted national science objectives in the areas of chemical energy production and advanced materials development.

Sibener, Steven J. [University of Chicago, IL (United States)] [University of Chicago, IL (United States)

2014-03-11T23:59:59.000Z

359

Reactive Blast Waves from Composite Charges  

SciTech Connect (OSTI)

Investigated here is the performance of composite explosives - measured in terms of the blast wave they drive into the surrounding environment. The composite charge configuration studied here was a spherical booster (1/3 charge mass), surrounded by aluminum (Al) powder (2/3 charge mass) at an initial density of {rho}{sub 0} = 0.604 g/cc. The Al powder acts as a fuel but does not detonate - thereby providing an extreme example of a 'non-ideal' explosive (where 2/3 of the charge does not detonate). Detonation of the booster charge creates a blast wave that disperses the Al powder and ignites the ensuing Al-air mixture - thereby forming a two-phase combustion cloud embedded in the explosion. Afterburning of the booster detonation products with air also enhances and promotes the Al-air combustion process. Pressure waves from such reactive blast waves have been measured in bomb calorimeter experiments. Here we describe numerical simulations of those experiments. A Heterogeneous Continuum Model was used to model the dispersion and combustion of the Al particle cloud. It combines the gasdynamic conservation laws for the gas phase with a dilute continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models of Khasainov. It incorporates a combustion model based on mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Adaptive Mesh Refinement (AMR) was used to capture the energy-bearing scales of the turbulent flow on the computational grid, and to track/resolve reaction zones. Numerical simulations of the explosion fields from 1.5-g and 10-kg composite charges were performed. Computed pressure histories (red curve) are compared with measured waveforms (black curves) in Fig. 1. Comparison of these results with a waveform for a non-combustion case in nitrogen (blue curve) demonstrates that a reactive blast wave was formed. Cross-sectional views of the temperature field at various times are presented in Fig. 2, which shows that the flow is turbulent. Initially, combustion occurs at the fuel-air interface, and the energy release rate is controlled by the rate of turbulent mixing. Eventually, oxidizer becomes distributed throughout the cloud via ballistic mixing of the particles with air; energy release then occurs in a distributed combustion mode, and Al particle kinetics controls the energy release rate. Details of the Heterogeneous Continuum Model and results of the numerical simulations of composite charge explosions will be described in the paper.

Kuhl, A L; Bell, J B; Beckner, V E

2009-10-16T23:59:59.000Z

360

The Safe Storage Study for Autocatalytic Reactive Chemicals  

E-Print Network [OSTI]

In the U.S. Chemical Safety and Hazard Investigation Board (CSB) report, Improving Reactive Hazard Management, there are 37 out of 167 accidents, which occurred in a storage tank or a storage area. This fact demonstrates that thermal runaway...

Liu, Lijun

2010-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network [OSTI]

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

362

Pre-plated reactive diffusion-bonded battery electrode plaques  

DOE Patents [OSTI]

A high strength, metallic fiber battery plaque is made using reactive diffusion bonding techniques, where a substantial amount of the fibers are bonded together by an iron-nickel alloy.

Maskalick, Nicholas J. (Pittsburgh, PA)

1984-01-01T23:59:59.000Z

363

Dynamic Reactive Power Control of Isolated Power Systems  

E-Print Network [OSTI]

This dissertation presents dynamic reactive power control of isolated power systems. Isolated systems include MicroGrids in islanded mode, shipboard power systems operating offshore, or any other power system operating in islanded mode intentionally...

Falahi, Milad

2012-10-03T23:59:59.000Z

364

Mechanical properties of amorphous Lix Si alloys: a reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

was downloaded on 08102013 at 15:46 Please note that terms and conditions apply. Mechanical properties of amorphous Li x Si alloys: a reactive force field study View the table...

365

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

366

Local Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the re...

Turitsyn, Konstantin S; Backhaus, Scott; Chertkov, Misha

2010-01-01T23:59:59.000Z

367

Method of detecting leakage from geologic formations used to sequester CO.sub.2  

DOE Patents [OSTI]

The invention provides methods for the measurement of carbon dioxide leakage from sequestration reservoirs. Tracer moieties are injected along with carbon dioxide into geological formations. Leakage is monitored by gas chromatographic analyses of absorbents. The invention also provides a process for the early leak detection of possible carbon dioxide leakage from sequestration reservoirs by measuring methane (CH.sub.4), ethane (C.sub.2H.sub.6), propane (C.sub.3H.sub.8), and/or radon (Rn) leakage rates from the reservoirs. The invention further provides a method for branding sequestered carbon dioxide using perfluorcarbon tracers (PFTs) to show ownership.

White, Curt (Pittsburgh, PA); Wells, Arthur (Bridgeville, PA); Diehl, J. Rodney (Pittsburgh, PA); Strazisar, Brian (Venetia, PA)

2010-04-27T23:59:59.000Z

368

Unnatural reactive amino acid genetic code additions  

DOE Patents [OSTI]

This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

2014-08-26T23:59:59.000Z

369

Unnatural reactive amino acid genetic code additions  

DOE Patents [OSTI]

This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNAsyn-thetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

Deiters, Alexander (La Jolla, CA); Cropp, T. Ashton (Bethesda, MD); Chin, Jason W. (Cambridge, GB); Anderson, J. Christopher (San Francisco, CA); Schultz, Peter G. (La Jolla, CA)

2011-08-09T23:59:59.000Z

370

Unnatural reactive amino acid genetic code additions  

DOE Patents [OSTI]

This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

Deiters, Alexander; Cropp, Ashton T; Chin, Jason W; Anderson, Christopher J; Schultz, Peter G

2013-05-21T23:59:59.000Z

371

(Electronic structure and reactivities of transition metal clusters)  

SciTech Connect (OSTI)

The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

Not Available

1992-01-01T23:59:59.000Z

372

3D Field-Scale Reactive Transport Modeling of In Situ Immobilization of Uranium in Structured Porous Media via Biostimulation  

SciTech Connect (OSTI)

A several-month-long ethanol injection experiment is being conducted to study the impacts of porous media structure (i.e., heterogeneity existing at multiple scales) on the effectiveness of metal/radionuclide bioremediation in a highly heterogeneous unconfined aquifer near Oak Ridge, TN, USA. We have constructed a 3D field-scale groundwater flow and multicomponent reactive transport model to simulate the experimental observations. The model incorporates a suite of abiotic reactions and microbially-mediated redox reactions for multiple terminal electron accepting processes (TEAPs) including soluble oxygen, nitrate, U(VI) and sulfate and solid-phase electron acceptors. Different biomass populations are considered in the model. Growth of these populations is derived from the bioenergetics-based approach in which the partitioning of electron flow between energy generation and cell biomass production is dependent on the free energy of the corresponding TEAP. TEAP reaction rates were free energy constrained. The TEAP model and reaction system have been formulated and used to simulate laboratory batch experimental observations. We conducted the field-scale simulation starting with the reaction system and parameters obtained from the batch experiment and hydrologic parameters estimated from the results of pumping tests, water level monitoring and model interpretation of a tracer test conducted in August 2004. Reaction parameters were investigated to compare simulation results and field experiment observations.

Fang, Yilin; Scheibe, Timothy D.; Roden, Eirc E.; Kamolpornwijit, Wiwat; Brooks, Scott C.

2006-09-12T23:59:59.000Z

373

Spectral shift reactor control method  

SciTech Connect (OSTI)

The method is described of closely controlling the reactor water coolant temperature of an operating spectral-shift nuclear reactor, the reactor comprising a core formed of fuel assemblies through which the reactor water coolant flows; different types of elongated elements operable to be controllably moved into and out of the core; one type of the elongated elements comprising control rods formed of neutron absorbing material and operable to decrease reactivity through neutron absorption when inserted into the core; another of the types of elongated elements comprising displacer rods formed of material which has a low absorption for neutrons and which have overall neutron-absorbing and moderating characteristics essentially not exceeding those of hollow tubular Zircaloy members with a filling zirconium oxide or aluminum oxide, the displacer rods operating to displace an equivalent volume of water coolant fluid from the core when inserted therein to decrease reactivity and to increase reactivity when moved from the core.

Impink, A.J. Jr.

1987-08-18T23:59:59.000Z

374

Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyThe EnergyDepartment7 th ,Top Value AddedTotalTown ofTown o f5

375

Application of the ''reactivity constraint approach'' to automatic reactor control  

SciTech Connect (OSTI)

The ''reactivity constraint approach'' is described and demonstrated to be an effective and reliable means for the automatic control of power in nuclear reactors. This approach functions by restricting the effect of the delayed neutron populations to that which can be balanced by an induced change in the prompt population. This is done by limiting the net reactivity to the amount that can be offset by reversing the direction of motion of the automated control mechanism. The necessary reactivity constraints are obtained from the dynamic period equation, which gives the instantaneous reactor period as a function of the reactivity and the rate of change of reactivity. The derivation of this equation is described with emphasis on the recently obtained ''alternate'' formulation. Following a discussion of the behavior of each term of this alternate equation as a function of reactivity, its use in the design and operation of a nonlinear, closed-loop, digital controller for reactor power is in the design and operation of a nonlinear, closed-loop, digital controller for reactor power is described. Details of the initial experimental trials of the resulting controller are given.

Bernard, J.A.; Henry, A.F.; Lanning, D.D.

1988-02-01T23:59:59.000Z

376

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive Reactive  

E-Print Network [OSTI]

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition) homogeneous reactions with indoor pollutants. The #12;Proceedings of Healthy Buildings 2009 Paper 336 latter

Siegel, Jeffrey

377

In situ formation of magnetite reactive barriers in soil for waste stabilization  

DOE Patents [OSTI]

Reactive barriers containing magnetite and methods for making magnetite reactive barriers in situ in soil for sequestering soil contaminants including actinides and heavy metals, organic materials, iodine and technetium are disclosed. According to one embodiment, a two-step reagent introduction into soil takes place. In the first step, free oxygen is removed from the soil by separately injecting into the soil aqueous solutions of iron (II) salt, for example FeCl.sub.2, and base, for example NaOH or NH.sub.3 in about a 1:1 volume ratio. Then, in the second step, similar reagents are injected a second time (however, according to about a 1:2 volume ratio, iron to salt) to form magnetite. The magnetite formation is facilitated, in part, due to slow intrusion of oxygen into the soil from the surface. The invention techniques are suited to injection of reagents into soil in proximity to a contamination plume or source allowing in situ formation of the reactive barrier at the location of waste or hazardous material. Mixing of reagents to form. precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

Moore, Robert C. (Edgewood, NM)

2003-01-01T23:59:59.000Z

378

Reactive Power Laboratory: Synchronous Condenser Testing&Modeling Results - Interim Report  

SciTech Connect (OSTI)

The subject report documents the work carried out by Oak Ridge National Laboratory (ORNL) during months 5-7 (May-July 2005) of a multi-year research project. The project has the overall goal of developing methods of incorporating distributed energy (DE) that can produce reactive power locally and for injecting into the distribution system. The objective for this new type of DE is to be able to provide voltage regulation and dynamic reactive power reserves without the use of extensive communication and control systems. The work performed over this three-month period focused on four aspects of the overall objective: (1) characterization of a 250HP (about 300KVAr) synchronous condenser (SC) via test runs at the ORNL Reactive Power Laboratory; (2) development of a data acquisition scheme for collecting the necessary voltage, current and power readings at the synchronous condenser and on the distribution system; (3) development of algorithms for analyzing raw test data from the various test runs; and (4) validation of a steady-state model for the synchronous condenser via the use of a commercial software package to study its effects on the ORNL 13.8/2.4kV distribution network.

Henry, SD

2005-09-27T23:59:59.000Z

379

RAFT: A simulator for ReActive Flow and Transport of groundwater contaminants  

SciTech Connect (OSTI)

This report documents the use of the simulator RAFT for the ReActive flow and Transport of groundwater contaminants. RAFT can be used as a predictive tool in the design and analysis of laboratory and field experiments or it can be used for the estimation of model/process parameters from experiments. RAFT simulates the reactive transport of groundwater contaminants in one, two-, or three-dimensions and it can model user specified source/link configurations and arbitrary injection strategies. A suite of solvers for transport, reactions and regression are employed so that a combination of numerical methods best suited for a problem can be chosen. User specified coupled equilibrium and kinetic reaction systems can be incorporated into RAFT. RAFT is integrated with a symbolic computational language MAPLE, to automate code generation for arbitrary reaction systems. RAFT is expected to be used as a simulator for engineering design for field experiments in groundwater remediation including bioremediation, reactive barriers and redox manipulation. As an integrated tool with both the predictive ability and the ability to analyze experimental data, RAFT can help in the development of remediation technologies, from laboratory to field.

Chilakapati, A.

1995-07-01T23:59:59.000Z

380

STATISTICAL METHODS STATISTICAL METHODS  

E-Print Network [OSTI]

STATISTICAL METHODS 1 STATISTICAL METHODS Arnaud Delorme, Swartz Center for Computational@salk.edu. Keywords: statistical methods, inference, models, clinical, software, bootstrap, resampling, PCA, ICA Abstract: Statistics represents that body of methods by which characteristics of a population are inferred

Delorme, Arnaud

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Development and Evaluation of a State-of-the-Science Reactive Plume  

E-Print Network [OSTI]

for plume rise, plume visibility, and stack opacity (5). Examples of other reactive plume models include

Zhang, Yang

382

Measurement of HVAC system performance and local ventilation using passive perfluorocarbon tracer technology  

SciTech Connect (OSTI)

In April of 1993, two (2) perfluorocarbon tracer (PFT) ventilation/indoor air quality assessment tests were performed in the Gleeson Hall building of the SUNY Farmingdale campus. The building was being modified, in part, as a result of significant occupant complaints of perceived poor air quality. The four story building had a basement first floor with air supplied normally by an HVAC system labelled as AC1. During this study, AC1 was inoperational and the basement interior rooms (walls) were primarily gone; the other three floors were still being used for classes. It is possible that a sense of poor air quality may have been perceived by first-floor occupants because they were working in the basement, but this issue could not be addressed. The second floor had two (2) lecture halls--Rm 202 (handled by AC4) and Rm 204 (handled by AC5); the balance of the second floor interior rooms and corridors was split between two other air handling systems, AC2 for the west side of the building and AC3 for the east side. The remaining 3rd and 4th floors were also split about evenly between AC2 and AC3. The perimeter rooms, equipped with wall units having their own outside air (OA) source plus centralized return air (RA) bypasses, were not included in this testing which was restricted to the basement floor (1st floor) and the four operating air handling systems, AC2 to AC5, during Test 1 and only AC2 to AC5 during Test 2. Two types of tests were performed using the full suite of 5 PFT types available. The first test was designed to measure the infiltration, exfiltration, and air exchange between the 5 AC zones above and the second test used the 5th tracer, which had been in the basement, as a distributed source throughout the four other zones to act as a surrogate pollutant source. This report provides final conclusions of both tests and suggestions regarding its usefulness in similar building ventilation and indoor air quality assessments.

Dietz, R.N.; Goodrich, R.W.

1995-06-01T23:59:59.000Z

383

Neutron kinetics in subcritical cores with application to the source modulation method  

E-Print Network [OSTI]

Neutron kinetics in subcritical cores with application to the source modulation method J. Wright for the measurement of reactivity in subcritical, source-driven cores. Methods of measuring reactivity by a single. Hence, first, the conditions of point kinetic behaviour in subcritical source-driven cores are revis

Pázsit, Imre

384

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures  

E-Print Network [OSTI]

for each source rock. This allowed the bulk rate of oil and gas generation for a source rockEarly maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive

Goddard III, William A.

385

Kinetics and mechanisms of reactions involving small aromatic reactive intermediates  

SciTech Connect (OSTI)

Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

Lin, M.C. [Emory Univ., Atlanta, GA (United States)

1993-12-01T23:59:59.000Z

386

Photoconductivity in reactively evaporated copper indium selenide thin films  

SciTech Connect (OSTI)

Copper indium selenide thin films of composition CuInSe{sub 2} with thickness of the order of 130 nm are deposited on glass substrate at a temperature of 423 ±5 K and pressure of 10{sup ?5} mbar using reactive evaporation, a variant of Gunther's three temperature method with high purity Copper (99.999%), Indium (99.999%) and Selenium (99.99%) as the elemental starting materials. X-ray diffraction (XRD) studies shows that the films are polycrystalline in nature having preferred orientation of grains along the (112) plane. The structural type of the film is found to be tetragonal with particle size of the order of 32 nm. The structural parameters such as lattice constant, particle size, dislocation density, number of crystallites per unit area and strain in the film are also evaluated. The surface morphology of CuInSe{sub 2} films are studied using 2D and 3D atomic force microscopy to estimate the grain size and surface roughness respectively. Analysis of the absorption spectrum of the film recorded using UV-Vis-NIR Spectrophotometer in the wavelength range from 2500 nm to cutoff revealed that the film possess a direct allowed transition with a band gap of 1.05 eV and a high value of absorption coefficient (?) of 10{sup 6} cm{sup ?1} at 570 nm. Photoconductivity at room temperature is measured after illuminating the film with an FSH lamp (82 V, 300 W). Optical absorption studies in conjunction with the good photoconductivity of the prepared p-type CuInSe{sub 2} thin films indicate its suitability in photovoltaic applications.

Urmila, K. S., E-mail: urmilaks7@gmail.com; Asokan, T. Namitha, E-mail: urmilaks7@gmail.com; Pradeep, B., E-mail: urmilaks7@gmail.com [Solid State Physics Laboratory, Cochin University of Science and Technology, Kochi, Kerala (India); Jacob, Rajani; Philip, Rachel Reena [Thin Film Research Laboratory, Union Christian College, Aluva, Kerala (India)

2014-01-28T23:59:59.000Z

387

Preliminary Interpretation of a Radionuclide and Colloid Tracer Test in a Granodiorite Shear Zone at the Grimsel Test Site, Switzerland  

SciTech Connect (OSTI)

In February and March 2012, a tracer test involving the injection of a radionuclide-colloid cocktail was conducted in the MI shear zone at the Grimsel Test Site, Switzerland, as part of the Colloids Formation and Migration (CFM) project. The colloids were derived from FEBEX bentonite, which is mined in Spain and is being considered as a potential waste package backfill in a Spanish nuclear waste repository. The tracer test, designated test 12-02 (second test in 2012), involved the injection of the tracer cocktail into borehole CFM 06.002i2 and extraction from the Pinkel surface packer at the main access tunnel wall approximately 6.1 m from the injection interval. The test configuration is depicted in Figure 1. This configuration has been used in several conservative tracer tests and two colloid-homologue tracer tests since 2007, and it is will be employed in an upcoming test involving the emplacement of a radionuclide-doped bentonite plug into CFM 06.002i2 to evaluate the swelling and erosion of the bentonite and the transport of bentonite colloids and radionuclides from the source to the extraction point at the tunnel wall. Interpretive analyses of several of the previous tracer tests, from 09-01 through 12-02 were provided in two previous Used Fuel Disposition Program milestone reports (Arnold et al., 2011; Kersting et al., 2012). However, only the data for the conservative tracer Amino-G Acid was previously analyzed from test 12-02 because the other tracer data from this test were not available at the time. This report documents the first attempt to quantitatively analyze the radionuclide and colloid breakthrough curves from CFM test 12-02. This report was originally intended to also include an experimental assessment of colloid-facilitated transport of uranium by bentonite colloids in the Grimsel system, but this assessment was not conducted because it was reported by German collaborators at the Karlsruhe Institute of Technology (KIT) that neither uranium nor neptunium adsorbed appreciably to FEBEX bentonite colloids in Grimsel groundwater (Huber et al., 2011). The Grimsel groundwater has a relatively high pH of {approx}9, so the lack of uranium and neptunium adsorption to clay is not surprising given the tendency for these actinides to form very stable negative or neutrally-charged uranyl- or calcium-uranyl-carbonate complexes at these pH, particularly in a water that is effectively saturated with respect to calcite. It was also observed in testing conducted at LANL earlier in 2012 that uranium did not adsorb measurably to Grimsel granodiorite in a synthetic Grimsel groundwater at pH {approx}8.5 (Kersting et al., 2012). Thus, the planned experimental work was not pursued because all the available information clearly pointed to an expected result that uranium transport would not be facilitated by clay colloids in the Grimsel system.

Reimus, Paul W. [Los Alamos National Laboratory

2012-08-30T23:59:59.000Z

388

Transport of tracers and pollutants from the Geysers Geothermal Resource Area  

SciTech Connect (OSTI)

An initial analysis of both surface and aerial SF/sub 6/ tracer data from the Geysers illustrates the importance that terrain, vertical wind shear, time-varying winds and stability have on the downwind distribution of cooling tower effluents during the daytime. Atmospheric stability and near surface winds above 3 m/s results in fumigation and surface impaction of a portion of cooling tower plumes on downwind surfaces and terrain. Vertical wind shear and possible gravity waves in upper-levels (approx. 1800 to 2000 m m.s.l), in addition, to terrain influences assist in distributing plumes horizontally and in the vertical at relative short (approx. 10 to 20 km) distances from the source. Small quantities of gaseous sulfur, primarily H/sub 2/S, are transported up to 20 km or more from the Geysers area. A variety of trace materials such as sulfate, copper, zinc, arsenic, bromine, lead, antimony, selenium and barium appear to be enriched over background levels and transported downwind from the Geysers Area at times.

Orgill, M.M.; Lee, R.N.; Schreck, R.I.

1983-08-01T23:59:59.000Z

389

Reservoir characterization based on tracer response and rank analysis of production and injection rates  

SciTech Connect (OSTI)

Quantification of the spatial distribution of properties is important for many reservoir-engineering applications. But, before applying any reservoir-characterization technique, the type of problem to be tackled and the information available should be analyzed. This is important because difficulties arise in reservoirs where production records are the only information for analysis. This paper presents the results of a practical technique to determine preferential flow trends in a reservoir. The technique is a combination of reservoir geology, tracer data, and Spearman rank correlation coefficient analysis. The Spearman analysis, in particular, will prove to be important because it appears to be insightful and uses injection/production data that are prevalent in circumstances where other data are nonexistent. The technique is applied to the North Buck Draw field, Campbell County, Wyoming. This work provides guidelines to assess information about reservoir continuity in interwell regions from widely available measurements of production and injection rates at existing wells. The information gained from the application of this technique can contribute to both the daily reservoir management and the future design, control, and interpretation of subsequent projects in the reservoir, without the need for additional data.

Refunjol, B.T. [Lagoven, S.A., Pdvsa (Venezuela); Lake, L.W. [Univ. of Texas, Austin, TX (United States)

1997-08-01T23:59:59.000Z

390

A New Multi-wavelength Solar Telescope: Optical and Near-infrared Solar Eruption Tracer (ONSET)  

E-Print Network [OSTI]

A new multi-wavelength solar telescope, Optical and Near-infrared Solar Eruption Tracer (ONSET) of Nanjing University, was constructed, being fabricated by Nanjing Institute of Astronomical Optics & Technology and run in cooperation with Yunnan Astronomical Observatory. ONSET is able to observe the Sun in three wavelength windows: He {\\small I} 10830 \\AA, H$\\alpha$, and white-light at 3600 \\AA and 4250 \\AA, which are selected in order to obtain the dynamics in the corona, chromosphere, and the photosphere simultaneously. Full-disk or partial-disk solar images with a field of 10 arcmin at three wavelengths can be obtained nearly simultaneously. It is designed to trace solar eruptions with high spatial and temporal resolutions. This telescope was installed at a new solar observing site near Fuxian Lake in Yunnan Province, southwest China. The site is located at E102N24, with an altitude of 1722 m. The seeing is stable and of high quality. We give a brief description of the scientific objectives and the basi...

Fang, C; Li, Z; Ding, M D; Dai, Y; Zhang, X Y; Mao, W J; Zhang, J P; Li, T; Liang, Y J; Lu, H T

2013-01-01T23:59:59.000Z

391

Infiltration processing of boron carbide-, boron-, and boride-reactive metal cermets  

DOE Patents [OSTI]

A chemical pretreatment method is used to produce boron carbide-, boron-, and boride-reactive metal composites by an infiltration process. The boron carbide or other starting constituents, in powder form, are immersed in various alcohols, or other chemical agents, to change the surface chemistry of the starting constituents. The chemically treated starting constituents are consolidated into a porous ceramic precursor which is then infiltrated by molten aluminum or other metal by heating to wetting conditions. Chemical treatment of the starting constituents allows infiltration to full density. The infiltrated precursor is further heat treated to produce a tailorable microstructure. The process at low cost produces composites with improved characteristics, including increased toughness, strength.

Halverson, Danny C. (Manteca, CA); Landingham, Richard L. (Livermore, CA)

1988-01-01T23:59:59.000Z

392

Calculating kinetics parameters and reactivity changes with continuous-energy Monte Carlo  

SciTech Connect (OSTI)

The iterated fission probability interpretation of the adjoint flux forms the basis for a method to perform adjoint weighting of tally scores in continuous-energy Monte Carlo k-eigenvalue calculations. Applying this approach, adjoint-weighted tallies are developed for two applications: calculating point reactor kinetics parameters and estimating changes in reactivity from perturbations. Calculations are performed in the widely-used production code, MCNP, and the results of both applications are compared with discrete ordinates calculations, experimental measurements, and other Monte Carlo calculations.

Kiedrowski, Brian C [Los Alamos National Laboratory; Brown, Forrest B [Los Alamos National Laboratory; Wilson, Paul [UNIV. WISCONSIN

2009-01-01T23:59:59.000Z

393

Options for Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic(PV) generation on an electrical distribution circuit present several challenges and opportunities for distribution utilities. Rapidly varying irradiance conditions may cause voltage sags and swells that cannot be compensated by slowly responding utility equipment resulting in a degradation of power quality. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We discuss and compare via simulation various design options for control systems to manage the reactive power generated by these inverters. An important design de...

Sulc, Petr; Backhaus, Scott; Chertkov, Michael

2010-01-01T23:59:59.000Z

394

Dielectric covered hairpin probe for its application in reactive plasmas  

SciTech Connect (OSTI)

The hairpin probe is a well known technique for measuring local electron density in low temperature plasmas. In reactive plasmas, the probe characteristics are affected by surface sputtering, contamination, and secondary electron emission. At higher densities, the plasma absorbs the entire electromagnetic energy of hairpin and hence limits the density measurements. These issues can be resolved by covering the hairpin surface with a thin layer of dielectric. In this letter, the dielectric contribution to the probe characteristics is incorporated in a theory which is experimentally verified. The dielectric covering improves the performance of probe and also allows the hairpin tip to survive in reactive plasma where classical electrical probes are easily damaged.

Gogna, G. S.; Gaman, C.; Turner, M. M. [NCPST, School of Physical Sciences, Dublin City University, Dublin 9 (Ireland); Karkari, S. K. [Institute for Plasma Research Center, Bhat Gandhinagar, Gujarat 382428 (India)

2012-07-23T23:59:59.000Z

395

REACTIVE TRANSPORT MODELING USING A PARALLEL FULLY-COUPLED SIMULATOR BASED ON PRECONDITIONED JACOBIAN-FREE NEWTON-KRYLOV  

SciTech Connect (OSTI)

Systems of multicomponent reactive transport in porous media that are large, highly nonlinear, and tightly coupled due to complex nonlinear reactions and strong solution-media interactions are often described by a system of coupled nonlinear partial differential algebraic equations (PDAEs). A preconditioned Jacobian-Free Newton-Krylov (JFNK) solution approach is applied to solve the PDAEs in a fully coupled, fully implicit manner. The advantage of the JFNK method is that it avoids explicitly computing and storing the Jacobian matrix during Newton nonlinear iterations for computational efficiency considerations. This solution approach is also enhanced by physics-based blocking preconditioning and multigrid algorithm for efficient inversion of preconditioners. Based on the solution approach, we have developed a reactive transport simulator named RAT. Numerical results are presented to demonstrate the efficiency and massive scalability of the simulator for reactive transport problems involving strong solution-mineral interactions and fast kinetics. It has been applied to study the highly nonlinearly coupled reactive transport system of a promising in situ environmental remediation that involves urea hydrolysis and calcium carbonate precipitation.

Luanjing Guo; Chuan Lu; Hai Huang; Derek R. Gaston

2012-06-01T23:59:59.000Z

396

Modeling The GRB Host Galaxy Mass Distribution: Are GRBs Unbiased Tracers of Star Formation?  

SciTech Connect (OSTI)

We model the mass distribution of long gamma-ray burst (GRB) host galaxies given recent results suggesting that GRBs occur in low metallicity environments. By utilizing measurements of the redshift evolution of the mass-metallicity (M-Z) relationship for galaxies, along with a sharp host metallicity cut-off suggested by Modjaz and collaborators, we estimate an upper limit on the stellar mass of a galaxy that can efficiently produce a GRB as a function of redshift. By employing consistent abundance indicators, we find that sub-solar metallicity cut-offs effectively limit GRBs to low stellar mass spirals and dwarf galaxies at low redshift. At higher redshifts, as the average metallicity of galaxies in the Universe falls, the mass range of galaxies capable of hosting a GRB broadens, with an upper bound approaching the mass of even the largest spiral galaxies. We compare these predicted limits to the growing number of published GRB host masses and find that extremely low metallicity cut-offs of 0.1 to 0.5 Z{sub {circle_dot}} are effectively ruled out by a large number of intermediate mass galaxies at low redshift. A mass function that includes a smooth decrease in the efficiency of producing GRBs in galaxies of metallicity above 12+log(O/H){sub KK04} = 8.7 can, however, accommodate a majority of the measured host galaxy masses. We find that at z {approx} 1, the peak in the observed GRB host mass distribution is inconsistent with the expected peak in the mass of galaxies harboring most of the star formation. This suggests that GRBs are metallicity biased tracers of star formation at low and intermediate redshifts, although our model predicts that this bias should disappear at higher redshifts due to the evolving metallicity content of the universe.

Kocevski, Daniel; /KIPAC, Menlo Park; West, Andrew A.; /UC, Berkeley, Astron. Dept. /MIT, MKI; Modjaz, Maryam; /UC, Berkeley, Astron. Dept.

2009-08-03T23:59:59.000Z

397

Effect of Cr2O3 on the 18O Tracer Incorporation in SOFC Materials  

SciTech Connect (OSTI)

Investigations of the impact of Cr{sub 2}O{sub 3} overlayers on the oxygen self diffusion in two SOFC materials were conducted to gain insight into the Cr poisoning mechanism at the cathode side of solid oxide fuel cells (SOFCs) with stainless steel interconnects. High density Y{sub 0.15}Zr{sub 0.85}O{sub 2} (YSZ) and La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF) sintered pellets were covered with 3 to 30 nm Cr overlayers that were subsequently oxidized, forming Cr{sub 2}O{sub 3}. Standard {sup 18}O tracer diffusion experiments at 800 C were performed and ToF-SIMS profiling revealed that the oxygen ion diffusion coefficients were unaffected by the thin Cr{sub 2}O{sub 3} overlayers, which is predictable since they are a bulk property, but the extracted effective surface exchange coefficients varied with Cr{sub 2}O{sub 3} overlayer thickness. Solid-state reaction measurements and electronic structure considerations concerning the surface exchange, led to the conclusion that the observed oxygen uptake hindrance for Cr{sub 2}O{sub 3} capped LSCF and the slight increase of the surface exchange coefficient for Cr{sub 2}O{sub 3} capped YSZ can be attributed to the electronic properties of Cr{sub 2}O{sub 3}. A critical thickness for Cr{sub 2}O{sub 3} was determined to be 12 nm where the transition from decreasing cathode-performance to a Cr{sub 2}O{sub 3}-property-governed regime occurs.

Finsterbusch, M.; Lussier, A; Negusse, E; Zhu, Z; Smith, R; Schaefer, J; Idzerda, Y

2010-01-01T23:59:59.000Z

398

MARKETS FOR REACTIVE POWER AND RELIABILITY: A WHITE PAPER  

E-Print Network [OSTI]

1 MARKETS FOR REACTIVE POWER AND RELIABILITY: A WHITE PAPER Engineering and Economics of Electricity Research Group (E3 RG) CORNELL UNIVERSITY E3 RG contributing authors: Robert Thomas, Director the Consortium for Electric Reliability Technology Solutions (CERTS) and in part by the National Science

399

Surface tension in a reactive binary mixture of incompressible fluids  

E-Print Network [OSTI]

Surface tension in a reactive binary mixture of incompressible fluids Henning Struchtrup Institute with a distributed form of surface tension. The model describes chemistry, diffusion, viscosity and heat transfer tension at the front. Keywords: Binary mixtures, Surface tension, Irreversible thermodynamics, Hele

Struchtrup, Henning

400

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may depend are combined is certainly not arbitrary. For instance, the repetition of one cycle may rely on the repetitionsDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Leue, Stefan

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401

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

processes of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may in which cycle executions are combined is certainly not arbitrary. For instance, the repetition of oneDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Reiterer, Harald

402

Active and reactive power in stochastic resonance for energy harvesting  

E-Print Network [OSTI]

A power allocation to active and reactive power in stochastic resonance is discussed for energy harvesting from mechanical noise. It is confirmed that active power can be increased at stochastic resonance, in the same way of the relationship between energy and phase at an appropriate setting in resonance.

Kubota, Madoka; Hikihara, Takashi

2015-01-01T23:59:59.000Z

403

Permeable Reactive Biobarriers for the Containment of Heavy Metal  

E-Print Network [OSTI]

. Heavy metals are leached as ground water reaches the exposed ores. Arizona has a rich historyPermeable Reactive Biobarriers for the Containment of Heavy Metal Contamination in Acid Mine) is defined as the presence heavy metals, increased acidity, and sulfate as a direct result of mining

Fay, Noah

404

Toward a new paradigm for reactive flow modeling.  

SciTech Connect (OSTI)

Traditional reactive flow modeling provides a computational representation of shock initiation of energetic materials. Most reactive flow models require ad hoc assumptions to obtain robust simulations, assumptions that result from partitioning energy and volume change between constituents in a reactive mixture. For example, most models assume pressure and/or temperature equilibrium for the mixture. Many mechanical insults to energetic materials violate these approximations. Careful analysis is required to ensure that the model assumptions and limitations are not exceeded. One limitation is that the shock to detonation transition is replicated only for strong planar shocks. Many models require different parameters to match data from thin pulse, ramp wave, or multidimensional loading, an approach that fails for complex loading. To accurately simulate reaction under non-planar shock impact scenarios a new formalism is required. The continuum mixture theory developed by Baer and Nunziato is used to eliminate ad hoc assumptions and limitations of current reactive flow models. This modeling paradigm represents the multiphase nature of reacting condensed/gas mixtures. Comparisons between simulations and data are presented.

Schmitt, Robert Gerard

2005-08-01T23:59:59.000Z

405

Author's personal copy Reactivity of lithium exposed graphite surface  

E-Print Network [OSTI]

on the surface [18]. Hence the effect of lithium on plasma­wall interactions is expected to dependAuthor's personal copy Reactivity of lithium exposed graphite surface S.S. Harilal a, *, J in fusion devices [1­5]. For example, wall conditioning with thin lithium layers gives rise to low hydrogen

Harilal, S. S.

406

A REACTIVE APPROACH FOR MINING PROJECT EVALUATION UNDER PRICE UNCERTAINTY  

E-Print Network [OSTI]

deterministic forward commodity price which, in most cases, historical data demonstrates to be quite volatileA REACTIVE APPROACH FOR MINING PROJECT EVALUATION UNDER PRICE UNCERTAINTY Meimei Zhang and operating cash flow. This industry is usually considered high risk because of historically volatile

Duffy, Ken

407

Neutron economic reactivity control system for light water reactors  

DOE Patents [OSTI]

A neutron reactivity control system for a LWBR incorporating a stationary seed-blanket core arrangement. The core arrangement includes a plurality of contiguous hexagonal shaped regions. Each region has a central and a peripheral blanket area juxapositioned an annular seed area. The blanket areas contain thoria fuel rods while the annular seed area includes seed fuel rods and movable thoria shim control rods.

Luce, Robert G. (Glenville, NY); McCoy, Daniel F. (Latham, NY); Merriman, Floyd C. (Rotterdam, NY); Gregurech, Steve (Scotia, NY)

1989-01-01T23:59:59.000Z

408

Stability, electronic structure and reactivity of the polymerized fullerite forms  

E-Print Network [OSTI]

Stability, electronic structure and reactivity of the polymerized fullerite forms V.V. Belavina , L density distribution from selected crystal orbitals of polymerized C60 forms was carried out. Linear chain with the highest occupied (HO) and lowest unoccupied (LU) bands. The polymerized C60 forms were found to be less

409

Field, Laboratory, and Modeling Study of Reactive Transport of  

E-Print Network [OSTI]

University of New York, Flushing, New York 11367, Department of Marine Chemistry and Geochemistry, Woods Hole Bay, MA, shed light on coupled control of chemistry and hydrology on reactive transport), phosphate (5), and oxyanions of molybdenum (6) and uranium (7, 8) in aquifers. In addition

410

Effect of Number of Fractionating Trays on Reactive Distillation Performance  

E-Print Network [OSTI]

Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

Al-Arfaj, Muhammad A.

411

Towards Energy-Efficient Reactive Thermal Management in Instrumented Datacenters  

E-Print Network [OSTI]

Towards Energy-Efficient Reactive Thermal Management in Instrumented Datacenters Ivan Rodero, Eun techniques used to alleviate thermal anomalies (i.e., hotspots) in cloud datacenter's servers of by reducing such as voltage scaling that also can be applied to reduce the temperature of the servers in datacenters. Because

Pompili, Dario

412

Generalized Chemical Reactivity of Curved Surfaces: Carbon Nanotubes  

E-Print Network [OSTI]

. Following the decomposition, the total reaction energy Etotal, which is the index of chemical reactivity, can be divided into three terms: strain energy Estrain, C-X binding energy EC-X, and global relaxation in a CNT can enhance the hydrogenation energy at the location of the excess deformation so

Srivastava, Deepak

413

Local control of reactive power by distributed photovoltaic generators  

SciTech Connect (OSTI)

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the real power generated by the PVs. Using one adjustable parameter per circuit, we balance the requirements on power quality and desire to minimize thermal losses. Numerical analysis of two exemplary systems, with comparable total PV generation albeit a different spatial distribution, show how to adjust the optimization parameter depending on the goal. Overall, this local scheme shows excellent performance; it's capable of guaranteeing acceptable power quality and achieving significant saving in thermal losses in various situations even when the renewable generation in excess of the circuit own load, i.e. feeding power back to the higher-level system.

Chertkov, Michael [Los Alamos National Laboratory; Turitsyn, Konstantin [Los Alamos National Laboratory; Sulc, Petr [Los Alamos National Laboratory; Backhaus, Scott [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

414

Reactive Phosphorus Removal from Aquaculture and Poultry Productions  

E-Print Network [OSTI]

Reactive Phosphorus Removal from Aquaculture and Poultry Productions Systems Using Polymeric and poultry production wastewater effluents. The sorbent used was a cross-linked polyamine (PAA,HCl) polymeric poultry and aquaculture wastewater effluents. Upon treatment, phosphorus anion concentrations were reduced

Rubloff, Gary W.

415

Abduction with Negation as Failure for Active and Reactive Rules  

E-Print Network [OSTI]

Abduction with Negation as Failure for Active and Reactive Rules Fariba Sadri and Francesca Toni suggested abductive logic programming as a suitable formalism to represent active databases and intelligent agents. In particular, abducibles in abductive logic programs can be used to repre- sent actions

Toni, Francesca

416

Nitrogen dynamics in flow-through microcosms of reactive media.  

E-Print Network [OSTI]

wastewater inputs to estuaries is similarly an important issue. Individual wastewater treatments have been University, Worcester MA December 19, 2005 Marine Biological Laboratory 1 #12;Abstract There have been many, the Marine Biological Laboratory is currently testing two experimental permeable reactive barriers along

Vallino, Joseph J.

417

Reactivity loss validation of high burn-up PWR fuels with pile-oscillation experiments in MINERVE  

SciTech Connect (OSTI)

The ALIX experimental program relies on the experimental validation of the spent fuel inventory, by chemical analysis of samples irradiated in a PWR between 5 and 7 cycles, and also on the experimental validation of the spent fuel reactivity loss with bum-up, obtained by pile-oscillation measurements in the MINERVE reactor. These latter experiments provide an overall validation of both the fuel inventory and of the nuclear data responsible for the reactivity loss. This program offers also unique experimental data for fuels with a burn-up reaching 85 GWd/t, as spent fuels in French PWRs never exceeds 70 GWd/t up to now. The analysis of these experiments is done in two steps with the APOLLO2/SHEM-MOC/CEA2005v4 package. In the first one, the fuel inventory of each sample is obtained by assembly calculations. The calculation route consists in the self-shielding of cross sections on the 281 energy group SHEM mesh, followed by the flux calculation by the Method Of Characteristics in a 2D-exact heterogeneous geometry of the assembly, and finally a depletion calculation by an iterative resolution of the Bateman equations. In the second step, the fuel inventory is used in the analysis of pile-oscillation experiments in which the reactivity of the ALIX spent fuel samples is compared to the reactivity of fresh fuel samples. The comparison between Experiment and Calculation shows satisfactory results with the JEFF3.1.1 library which predicts the reactivity loss within 2% for burn-up of {approx}75 GWd/t and within 4% for burn-up of {approx}85 GWd/t. (authors)

Leconte, P.; Vaglio-Gaudard, C.; Eschbach, R.; Di-Salvo, J.; Antony, M.; Pepino, A. [CEA, DEN, DER, Cadarache, F-13108 Saint-Paul-Lez-Durance (France)

2012-07-01T23:59:59.000Z

418

Method for bonding thin film thermocouples to ceramics  

DOE Patents [OSTI]

A method is provided for adhering a thin film metal thermocouple to a ceramic substrate used in an environment up to 700 degrees Centigrade, such as at a cylinder of an internal combustion engine. The method includes the steps of: depositing a thin layer of a reactive metal on a clean ceramic substrate; and depositing thin layers of platinum and a platinum-10% rhodium alloy forming the respective legs of the thermocouple on the reactive metal layer. The reactive metal layer serves as a bond coat between the thin noble metal thermocouple layers and the ceramic substrate. The thin layers of noble metal are in the range of 1-4 micrometers thick. Preferably, the ceramic substrate is selected from the group consisting of alumina and partially stabilized zirconia. Preferably, the thin layer of reactive metal is in the range of 0.015-0.030 micrometers (15-30 nanometers) thick. The preferred reactive metal is chromium. Other reactive metals may be titanium or zirconium. The thin layer of reactive metal may be deposited by sputtering in ultra high purity argon in a vacuum of approximately 2 milliTorr (0.3 Pascals).

Kreider, Kenneth G. (Potomac, MD)

1993-01-01T23:59:59.000Z

419

Reactive ion etching-assisted surface-enhanced Raman scattering measurements on the single nanoparticle level  

SciTech Connect (OSTI)

Single-nanoparticle surface-enhanced Raman scattering (SERS) measurement is of essential importance for both fundamental research and practical applications. In this work, we develop a class of single-particle SERS approaches, i.e., reactive ion etching (RIE)-assisted SERS measurements correlated with scanning electron microscopy (SEM) strategy (RIE/SERS/SEM), enabling precise and high-resolution identification of single gold nanoparticle (AuNP) in facile and reliable manners. By using AuNP-coated silicon wafer and quartz glass slide as models, we further employ the developed RIE/SERS/SEM method for interrogating the relationship between SERS substrates and enhancement factor (EF) on the single particle level. Together with theoretical calculation using an established finite-difference-time-domain (FDTD) method, we demonstrate silicon wafer as superior SERS substrates, facilitating improvement of EF values.

Wang, Si-Yi; Jiang, Xiang-Xu; Wei, Xin-Pan; Lee, Shuit-Tong, E-mail: apannale@suda.edu.cn, E-mail: yaohe@suda.edu.cn; He, Yao, E-mail: apannale@suda.edu.cn, E-mail: yaohe@suda.edu.cn [Institute of Functional Nano and Soft Materials - FUNSOM, Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Devices Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Xu, Ting-Ting [Institute of Functional Nano and Soft Materials - FUNSOM, Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Devices Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, Hong Kong, China and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (China)

2014-06-16T23:59:59.000Z

420

Boron-carbide-aluminum and boron-carbide-reactive metal cermets  

DOE Patents [OSTI]

Hard, tough, lightweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidation step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modulus of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi.sqroot.in. These composites and methods can be used to form a variety of structural elements.

Halverson, Danny C. (Manteca, CA); Pyzik, Aleksander J. (Seattle, WA); Aksay, Ilhan A. (Seattle, WA)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Fuel Cell Manufacturing Diagnostic Techniques: IR Thermography with Reactive Flow through Excitation  

SciTech Connect (OSTI)

While design and material considerations for PEMFCs have a large impact on cost, it is also necessary to consider a transition to high volume production of fuel cell systems, including MEA components, to enable economies of scale and reduce per unit cost. One of the critical manufacturing tasks is developing and deploying techniques to provide in?process measurement of fuel cell components for quality control. This effort requires a subsidiary task: The study of the effect of manufacturing defects on performance and durability with the objective to establish validated manufacturing tolerances for fuel cell components. This work focuses on the development of a potential quality control method for gas diffusion electrodes (GDEs). The method consists of infrared (IR) thermography combined with reactive flow through (RFT) excitation. Detection of catalyst loading reduction defects in GDE catalyst layers will be presented.

Manak, A. J.; Ulsh, M.; Bender, G.

2012-01-01T23:59:59.000Z

422

Reactive Transport Modeling and Geophysical Monitoring of Bioclogging at Reservoir Scale  

E-Print Network [OSTI]

Reactive Transport Modeling and Geophysical Monitoring of Bioclogging at Reservoir Scale Vikranth scale using a combination of reactive transport modeling and geophysical imaging tools (EM & seismic Sacramento basin, California; the model well (Citizen Green #1) was characterized using sonic, electrical

Hubbard, Susan

423

An Aircraft Electric Power Testbed for Validating Automatically Synthesized Reactive Control Protocols  

E-Print Network [OSTI]

An Aircraft Electric Power Testbed for Validating Automatically Synthesized Reactive Control reactive synthesis; testbed; aircraft electric power system 1. INTRODUCTION AND MOTIVATION Aircraft of Pennsylvania utopcu@seas.upenn.edu ABSTRACT Modern aircraft increasingly rely on electric power for sub

Xu , Huan

424

Stabilization of liquid crystal photoaligning layers by reactive mesogens O. Yaroshchuk,1  

E-Print Network [OSTI]

Stabilization of liquid crystal photoaligning layers by reactive mesogens O. Yaroshchuk,1 V photoaligning layers by thin layers of reactive mesogens, strong enhancement in LC alignment stability layer, the photoalignment technique minimizes me- chanical damage and electric charging, provides

425

Pollution-enhanced reactive chlorine chemistry in the eastern tropical Atlantic boundary layer  

E-Print Network [OSTI]

doi:10.1029/2008GL036666, 2009 Pollution-enhanced reactiveE. S. Saltzman (2009), Pollution-enhanced reactive chlorine5 L08810 LAWLER ET AL. : POLLUTION-ENHANCED CLX IN THE MBL

2009-01-01T23:59:59.000Z

426

Solution-mediated strategies for synthesizing metal oxides, borates and phosphides using nanocrystals as reactive precursors  

E-Print Network [OSTI]

Because of their high surface area (and hence, increased reactivity) nanocrystals can be used as reactive precursors in the low-temperature synthesis of solid state materials. When nanocrystals are used as reactants, the temperatures needed...

Henkes, Amanda Erin

2009-05-15T23:59:59.000Z

427

E-Print Network 3.0 - atom-diatom reactive scattering Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

diatom reactive scattering Search Powered by Explorit Topic List Advanced Search Sample search results for: atom-diatom reactive scattering Page: << < 1 2 3 4 5 > >> 1 Eur. Phys....

428

Photoluminescent silicon nanocrystals synthesized by reactive laser Daria Riabinina,a  

E-Print Network [OSTI]

Photoluminescent silicon nanocrystals synthesized by reactive laser ablation Daria Riabinina reactive laser ablation in oxygen atmosphere followed by annealing. We observe a strong photoluminescence size, obtained independently by fitting photoluminescence spectra and from x-ray diffraction patterns

429

Bioinformatic analysis of xenobiotic reactive metabolite target proteins and their interacting partners  

E-Print Network [OSTI]

Background Protein covalent binding by reactive metabolites of drugs, chemicals and natural products can lead to acute cytotoxicity. Recent rapid progress in reactive metabolite target protein identification has shown ...

Hanzlik, Robert P.; Fang, Jianwen; Koen, Yakov M.

2009-06-12T23:59:59.000Z

430

Chemical Reactivity of Reduced TiO2(110): The dominant role of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

431

Measurement of the Tracer Gradient and Sampling System Bias of the Hot Fuel Examination Facility Stack Air Monitoring System  

SciTech Connect (OSTI)

This report describes tracer gas uniformity and bias measurements made in the exhaust air discharge of the Hot Fuel Examination Facility at Idaho National Laboratory. The measurements were a follow-up on earlier measurements which indicated a lack of mixing of the two ventilation streams being discharged via a common stack. The lack of mixing is detrimental to the accuracy of air emission measurements. The lack of mixing was confirmed in these new measurements. The air sampling probe was found to be out of alignment and that was corrected. The suspected sampling bias in the air sample stream was disproved.

Glissmeyer, John A.; Flaherty, Julia E.

2011-07-20T23:59:59.000Z

432

Exotic populations in Globular Clusters: Blue Stragglers as tracers of the internal dynamical evolution of stellar systems  

E-Print Network [OSTI]

In this paper I present an overview of the main observational properties of a special class of exotic objects (the so-called Blue Straggler Stars, BSSs) in Galactic Globular Clusters (GCs). The BSS specific frequency and their radial distribution are discussed in the framework of using this stellar population as probe of GC internal dynamics. In particular, the shape of the BSS radial distribution has been found to be a powerful tracer of the dynamical evolution of stellar systems, thus allowing the definition of an empirical "clock" able to measure the dynamical age of stellar aggregates from pure observational properties.

Ferraro, Francesco R

2015-01-01T23:59:59.000Z

433

Using Reactive Rules to Guide a Forward-Chaining Murray Shanahan  

E-Print Network [OSTI]

1 Using Reactive Rules to Guide a Forward-Chaining Planner Murray Shanahan Department of Electrical.shanahan@ic.ac.uk Keywords: planning and execution, reactive planning, robot planning Abstract This paper presents a planning technique in which a flawed set of reactive rules is used to guide a stochastic forward-chaining search

Shanahan, Murray

434

A pulser for medium-frequency modulated direct-current reactive sputter deposition of insulators  

E-Print Network [OSTI]

for medium-frequency modulated direct-current dc reactive sputter deposition of electrical insulators at the target surface inherent to high- deposition-rate reactive sputtering of electrical insulators. TypicallyA pulser for medium-frequency modulated direct-current reactive sputter deposition of insulators G

Cao, Hui

435

Abstract This paper reviews specific issues and challenges in reactive power management within the competitive electricity  

E-Print Network [OSTI]

and physical considerations and so depends on the market players and the electricity market rules. Reactive local nature of reactive power restricts its ability to be transmitted over electrically large distancesAbstract ­ This paper reviews specific issues and challenges in reactive power management within

Gross, George

436

TO APPEAR IN IEEE TRANSACTION ON POWER SYSTEMS 1 Effect of Reactive Power Limit Modeling on  

E-Print Network [OSTI]

, generator capability curves, maximum loadability, voltage stability, electrical energy markets, reactive- active power in electric power systems. Although there are other important reactive power sourcesTO APPEAR IN IEEE TRANSACTION ON POWER SYSTEMS 1 Effect of Reactive Power Limit Modeling on Maximum

Cañizares, Claudio A.

437

CARIBBEAN COLLOQUIUM ON POWER QUALITY (CCPQ), JUNE 2003 100 Defining Reactive Power in Circuit Transients via  

E-Print Network [OSTI]

CARIBBEAN COLLOQUIUM ON POWER QUALITY (CCPQ), JUNE 2003 100 Defining Reactive Power in Circuit the notion of reactive power during circuit transients. The definition we propose is based on the concept, namely Short- Time Fourier Coefficients and Haar Wavelets. We illustrate this "dynamic" reactive power

Stankoviæ, Aleksandar

438

Finite Bisimulation of Reactive Untimed Infinite State Systems Modeled as Automata with Variables  

E-Print Network [OSTI]

1 Finite Bisimulation of Reactive Untimed Infinite State Systems Modeled as Automata with Variables for reactive untimed infinite state systems called input- output extended finite automaton (I/O-EFA), which of a finite bisimilar abstraction. The results are illustrated through examples that model reactive software

Kumar, Ratnesh

439

Toward Optimized Bioclogging and Biocementation Through Combining Advanced Geophysical Monitoring and Reactive Transport Modeling  

E-Print Network [OSTI]

and electrical techniques); (ii) developing and using a reactive transport simulator capable of predicting and Reactive Transport Modeling Approaches Christopher G Hubbard1 , Susan S. Hubbard1 , Yuxin Wu1 , Vikranth heterogeneities at the field scale. Optimization of these strategies requires advances in mechanistic reactive

Hubbard, Susan

440

Voltage Control of Distribution Networks with Distributed Generation using Reactive Power  

E-Print Network [OSTI]

Voltage Control of Distribution Networks with Distributed Generation using Reactive Power to control voltage of distribution networks with DG using reactive power compensation approach. In this paper profile within the specified limits, it is essential to regulate the reactive power of the compensators

Pota, Himanshu Roy

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Generation of reactive oxygen species by a persulfide (BnSSH) Tonika Chatterji,  

E-Print Network [OSTI]

Generation of reactive oxygen species by a persulfide (BnSSH) Tonika Chatterji, Kripa Keerthi generate reactive oxygen species under biologically rele- vant conditions via the sequence of reactions by reactive oxygen species generated in this manner may contribute to the cytotoxic properties of leinamycin

Gates, Kent. S.

442

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network [OSTI]

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

443

Analytical solutions for sequentially coupled one-dimensional reactive transport problems Part I: Mathematical derivations  

E-Print Network [OSTI]

Analytical solutions for sequentially coupled one-dimensional reactive transport problems ­ Part I-species reactive transport equations coupled through sorption and sequential first-order reactions are commonly. Although researchers have been attempting to solve various forms of these reactive transport equations

Clement, Prabhakar

444

VOF-BASED SIMULATION OF REACTIVE MASS TRANSFER ACROSS DEFORMABLE INTERFACES  

E-Print Network [OSTI]

. of the bubbles is there- fore of fundamental importance for effective design of the reactor. In case of fast-based approach for the Direct Numerical Simulation of reactive mass transfer in gas-liquid flows is described simulation results are presented for non reactive and reactive mass transfer from rising gas bubbles

Bothe, Dieter

445

Arylpalladium Phosphonate Complexes as Reactive Intermediates in Phosphorus-Carbon Bond Forming Reactions  

SciTech Connect (OSTI)

Phosphorus-carbon bond formation from discrete transition metal complexes have been investigated through a combination of synthetic, spectroscopic, crystallographic, and computational methods. Reactive intermediates of the type (diphosphine)Pd(aryl)(P(O)(OEt)(2)) have been prepared, characterized, and studied as possible intermediates in metal-mediated coupling reactions. Several of the reactive intermediates were characterized crystallographicaliy, and a discussion of the solid state structures is presented. In contrast to other carbon-heteroelement bond forming reactions, palladium complexes containing electron-donating substituents on the aromatic fragment exhibited faster rates of reductive elimination. Large bite angle diphosphine ligands induced rapid rates of elimination, while bipyridine and small bite angle diphosphine ligands resulted in much slower rates of elimination. An investigation of the effect of typical impurities on the elimination reaction was carried out. While excess diphosphine, pyridine, and acetonitrile had little effect on the observed rate, the addition of water slowed the phosphorus-carbon bond forming reaction. Coordination of water to the complex was observed spectroscopically and crystallographically. Computational studies were utilized to probe the reaction pathways for P-C bond formation via Pd catalysis.

Kohler, Mark C. [Bucknell University; Grimes, Thomas V. [University of North Texas; Wang, Xiaoping [ORNL; Cundari, Thomas R. [University of North Texas; Stockland, Robert A. Jr. [Bucknell University

2009-01-01T23:59:59.000Z

446

Reactivity impact of delayed neutron spectra on MCNP calculations  

SciTech Connect (OSTI)

The new features in MCNP4C, the latest version of the MCNP Monte Carlo code, include the capability to sample from delayed as well as prompt fission emission spectra. Previous versions of MCNP all have sampled exclusively from prompt spectra. Delayed neutrons typically account for <1% of all neutrons emitted from fission, but the emission spectra for delayed neutrons are somewhat softer than those for prompt neutrons. Because of the softer spectrum, delayed neutrons are less likely to leak from the system, and they also are less likely to cause fission in isotopes that have an effective threshold for fission (e.g., {sup 238}U and {sup 240}Pu). Consequently, the inclusion of delayed neutron spectra can have a small but significant effect on reactivity calculations. This study performs MCNP4C calculations for a series of established benchmarks and quantifies the reactivity impact of the delayed neutron spectra.

Mosteller, R.D.; Werner, C.J.

2000-07-01T23:59:59.000Z

447

Engine combustion control at low loads via fuel reactivity stratification  

DOE Patents [OSTI]

A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

2014-10-07T23:59:59.000Z

448

Reactive Membrane Barriers for Containment of Subsurface Contamination  

SciTech Connect (OSTI)

The overall goal of this project was to develop reactive membrane barriers--a new and flexible technique to contain and stabilize subsurface contaminants. Polymer membranes will leak once a contaminant is able to diffuse through the membrane. By incorporating a reactive material in the polymer, however, the contaminant is degraded or immobilized within the membrane. These processes increase the time for contaminants to breakthrough the barrier (i.e. the lag time) and can dramatically extend barrier lifetimes. In this work, reactive barrier membranes containing zero-valent iron (Fe{sup 0}) or crystalline silicotitanate (CST) were developed to prevent the migration of chlorinated solvents and cesium-137, respectively. These studies were complemented by the development of models quantifying the leakage/kill time of reactive membranes and describing the behavior of products produced via the reactions within the membranes. First, poly(vinyl alcohol) (PVA) membranes containing Fe{sup 0} and CST were prepared and tested. Although PVA is not useful in practical applications, it allows experiments to be performed rapidly and the results to be compared to theory. For copper ions (Cu{sup 2+}) and carbon tetrachloride, the barrier was effective, increasing the time to breakthrough over 300 times. Even better performance was expected, and the percentage of the iron used in the reaction with the contaminants was determined. For cesium, the CST laden membranes increased lag times more than 30 times, and performed better than theoretical predictions. A modified theory was developed for ion exchangers in reactive membranes to explain this result. With the PVA membranes, the effect of a groundwater matrix on barrier performance was tested. Using Hanford groundwater, the performance of Fe{sup 0} barriers decreased compared to solutions containing a pH buffer and high levels of chloride (both of which promote iron reactivity). For the CST bearing membrane, performance improved by a factor of three when groundwater was used in place of deionized water. The performance of high density polyethylene (HDPE) membranes containing Fe{sup 0} was then evaluating using carbon tetrachloride as the target contaminant. Only with a hydrophilic additive (glycerol), was the iron able to extend lag times. Lag times were increased by a factor of 15, but only 2-3% of the iron was used, likely due to formation of oxide precipitates on the iron surface, which slowed the reaction. With thicker membranes and lower carbon tetrachloride concentrations, it is expected that performance will improve. Previous models for reactive membranes were also extended. The lag time is a measurement of when the barrier is breached, but contaminants do slowly leak through prior to the lag time. Thus, two parameters, the leakage and the kill time, were developed to determine when a certain amount of pollutant has escaped (the kill time) or when a given exposure (concentration x time) occurs (the leakage). Finally, a model was developed to explain the behavior of mobile reaction products in reactive barrier membranes. Although the goal of the technology is to avoid such products, it is important to be able to predict how these products will behave. Interestingly, calculations show that for any mobile reaction products, one half of the mass will diffuse into the containment area and one half will escape, assuming that the volumes of the containment area and the surrounding environment are much larger than the barrier membrane. These parameters/models will aid in the effective design of barrier membranes.

William A. Arnold; Edward L. Cussler

2007-02-26T23:59:59.000Z

449

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents [OSTI]

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

450

Die singulation method  

DOE Patents [OSTI]

A method is disclosed for singulating die from a semiconductor substrate (e.g. a semiconductor-on-insulator substrate or a bulk silicon substrate) containing an oxide layer (e.g. silicon dioxide or a silicate glass) and one or more semiconductor layers (e.g. monocrystalline or polycrystalline silicon) located above the oxide layer. The method etches trenches through the substrate and through each semiconductor layer about the die being singulated, with the trenches being offset from each other around at least a part of the die so that the oxide layer between the trenches holds the substrate and die together. The trenches can be anisotropically etched using a Deep Reactive Ion Etching (DRIE) process. After the trenches are etched, the oxide layer between the trenches can be etched away with a HF etchant to singulate the die. A release fixture can be located near one side of the substrate to receive the singulated die.

Swiler, Thomas P [Albuquerque, NM; Garcia, Ernest J [Albuquerque, NM; Francis, Kathryn M [Rio Rancho, NM

2014-01-07T23:59:59.000Z

451

Die singulation method  

DOE Patents [OSTI]

A method is disclosed for singulating die from a semiconductor substrate (e.g. a semiconductor-on-insulator substrate or a bulk silicon substrate) containing an oxide layer (e.g. silicon dioxide or a silicate glass) and one or more semiconductor layers (e.g. monocrystalline or polycrystalline silicon) located above the oxide layer. The method etches trenches through the substrate and through each semiconductor layer about the die being singulated, with the trenches being offset from each other around at least a part of the die so that the oxide layer between the trenches holds the substrate and die together. The trenches can be anisotropically etched using a Deep Reactive Ion Etching (DRIE) process. After the trenches are etched, the oxide layer between the trenches can be etched away with an HF etchant to singulate the die. A release fixture can be located near one side of the substrate to receive the singulated die.

Swiler, Thomas P.; Garcia, Ernest J.; Francis, Kathryn M.

2013-06-11T23:59:59.000Z

452

Dynamics of inelastic and reactive gas-surface collisions  

SciTech Connect (OSTI)

The dynamics of inelastic and reactive collisions in atomic beam-surface scattering are presented. The inelastic scattering of hyperthermal rare gaseous atoms from three alkali halide surfaces (LiF, NaCl, GI)was studied to understand mechanical energy transfer in unreactive systems. The dynamics of the chemical reaction in the scattering of H(D) atoms from the surfaces of LIF(001) and the basal plane of graphite were also studied.

Smoliar, L.A.

1995-04-01T23:59:59.000Z

453

Options for Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic(PV) generation on an electrical distribution circuit present several challenges and opportunities for distribution utilities. Rapidly varying irradiance conditions may cause voltage sags and swells that cannot be compensated by slowly responding utility equipment resulting in a degradation of power quality. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We discuss and compare via simulation various design options for control systems to manage the reactive power generated by these inverters. An important design decision that weighs on the speed and quality of communication required is whether the control should be centralized or distributed (i.e. local). In general, we find that local control schemes are capable for maintaining voltage within acceptable bounds. We consider the benefits of choosing different local variables on which to control and how the control system can be continuously tuned between robust voltage control, suitable for daytime operation when circuit conditions can change rapidly, and loss minimization better suited for nighttime operation.

Petr Sulc; Konstantin Turitsyn; Scott Backhaus; Michael Chertkov

2010-08-04T23:59:59.000Z

454

Dependence of post-drop reactivity on data analysis model for rod drop experiment in a subcritical reactor with external source  

SciTech Connect (OSTI)

This paper presents an improved rod-drop reactivity and source strength measurement by the inverse kinetics method in subcritical reactor system. The inverse kinetics method extended to be applicable to subcritical system, which is referred to as least squares inverse kinetics method (LSIKM), can estimate both the reactivity and the external source strength by applying least square approximation. However, the application of the conventional fitting model of the LSIKM to fluctuating data leads to serious errors in the estimation. In this study, a specific fitting model proposed by Itagaki and Kitano is used for the LSIKM and the effectiveness for fluctuating data is demonstrated experimentally. Furthermore, the spatial dependence of the estimated results is investigated and the reduction method is proposed. (authors)

Taninaka, H. [Interdisciplinary Graduate School of Science and Technology, Kinki Univ., 3-4-1, Kowakae, Higashi-Osaka, 577-8502 (Japan); Hashimoto, K. [Atomic Energy Research Inst., Kinki Univ., 3-4-1, Kowakae, Higashi-Osaka, 577-8502 (Japan)

2006-07-01T23:59:59.000Z

455

Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns  

SciTech Connect (OSTI)

Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs generally have low volatilities and are combustion-resistant, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of primary radiation chemistry, charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of reactions and product distributions. We study these issues by characterization of primary radiolysis products and measurements of their yields and reactivity, quantification of electron solvation dynamics and scavenging of electrons in different states of solvation. From this knowledge we wish to learn how to predict radiolytic mechanisms and control them or mitigate their effects on the properties of materials used in nuclear fuel processing, for example, and to apply IL radiation chemistry to answer questions about general chemical reactivity in ionic liquids that will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that the slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increase the importance of pre-solvated electron reactivity and consequently alter product distributions and subsequent chemistry. This difference from conventional solvents has profound effects on predicting and controlling radiolytic yields, which need to be quantified for the successful use under radiolytic conditions. Electron solvation dynamics in ILs are measured directly when possible and estimated using proxies (e.g. coumarin-153 dynamic emission Stokes shifts or benzophenone anion solvation) in other cases. Electron reactivity is measured using ultrafast kinetics techniques for comparison with the solvation process.

Wishart, J.F.

2011-06-12T23:59:59.000Z

456

IEEE TRANSACTIONS ON KNOWLEDGE AND DATA ENGINEERING 1 A Predictive-Reactive Method for Improving the  

E-Print Network [OSTI]

applications, need to process queries and transactions in a timely fashion using fresh (temporally consistent quote queries and trade transactions should be processed within the acceptable response time bound using be processed in a timely manner using fresh data representing the current traffic status. Most existing (non

Kang, Kyoung-Don

457

REACTIVE FLOW IN VUGGY CARBONATES: METHODS AND MODELS APPLIED TO MATRIX ACIDIZING OF CARBONATES  

E-Print Network [OSTI]

and its effect on fluid flow is numerical simulation. A 3D finite difference numerical model is developed based on Darcy-Brinkman formulation (DBF). Using the developed simulator a flow-based inversion approach is implemented to understand the connectivity...

Izgec, Omer

2010-07-14T23:59:59.000Z

458

Reactive Air Brazing: Method of Joining Ceramic and Metal Parts in Solid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298, andEpidermalOxide Fuel Cells - Energy Innovation

459

Photovoltaic solar system connected to the electric power grid operating as active power generator and reactive power compensator  

SciTech Connect (OSTI)

In the case of photovoltaic (PV) systems acting as distributed generation (DG) systems, the DC energy that is produced is fed to the grid through the power-conditioning unit (inverter). The majority of contemporary inverters used in DG systems are current source inverters (CSI) operating at unity power factor. If, however, we assume that voltage source inverters (VSI) can replace CSIs, we can generate reactive power proportionally to the remaining unused capacity at any given time. According to the theory of instantaneous power, the inverter reactive power can be regulated by changing the amplitude of its output voltage. In addition, the inverter active power can be adjusted by modifying the phase angle of its output voltage. Based on such theory, both the active power supply and the reactive power compensation (RPC) can be carried out simultaneously. When the insolation is weak or the PV modules are inoperative at night, the RPC feature of a PV system can still be used to improve the inverter utilisation factor. Some MATLAB simulation results are included here to show the feasibility of the method. (author)

Albuquerque, Fabio L.; Moraes, Adelio J.; Guimaraes, Geraldo C.; Sanhueza, Sergio M.R.; Vaz, Alexandre R. [Universidade Federal de Uberlandia, Uberlandia-MG, CEP 38400-902 (Brazil)

2010-07-15T23:59:59.000Z

460

Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation  

SciTech Connect (OSTI)

Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH{sub 4}{sup +} production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface.

Wu, Y.; Ajo-Franklin, J.B.; Spycher, N.; Hubbard, S.S.; Zhang, G.; Williams, K.H.; Taylor, J.; Fujita, Y.; Smith, R.

2011-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Tracer Detection by Laser Spectroscopy for Applications in the Oil and Gas R. Nava, Texas A&M University, H. Schuessler, M. Fahes and H. Nasrabadi, Texas A&M University at Qatar, and  

E-Print Network [OSTI]

SPE 124689 Tracer Detection by Laser Spectroscopy for Applications in the Oil and Gas Industry R and more accurate option for applications in the oil and gas industry. The research work is currently being applications in the oil and gas industry. Chemical or radioactive tracers are used to label fluids from

Schuessler, Hans

462

Reactive Distillation for Esterification of Bio-based Organic Acids  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,--SpeedingSpeedingSpeeding access to scienceSpeedingReactive

463

Low Reactivity SI Engine Lubricant Program | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10IO1OP001Long-Term Storage ofEnergyReactivity SI Engine

464

Redox-Reactive Membrane Vesicles produced by Shewanella. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298,NIST 800-53 RevisionDivision andIonRedox-Reactive

465

Project Profile: Chemically Reactive Working Fluids | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d FNEPA/309Department ofDepartmentProjectatChemically Reactive Working

466

Determination of the relative power density distribution in a heterogeneous reactor from the results of measurements of the reactivity effects and the neutron importance function  

SciTech Connect (OSTI)

A method for experimental determination of the relative power density distribution in a heterogeneous reactor based on measurements of fuel reactivity effects and importance of neutrons from a californium source is proposed. The method was perfected on two critical assembly configurations at the NARCISS facility of the Kurchatov Institute, which simulated a small-size heterogeneous nuclear reactor. The neutron importance measurements were performed on subcritical and critical assemblies. It is shown that, along with traditionally used activation methods, the developed method can be applied to experimental studies of special features of the power density distribution in critical assemblies and reactors.

Bobrov, A. A.; Glushkov, E. S.; Zimin, A. A.; Kapitonova, A. V.; Kompaniets, G. V.; Nosov, V. I., E-mail: rpp@adis.vver.kiae.ru; Petrushenko, R. P.; Smirnov, O. N. [Russian Research Centre Kurchatov Institute (Russian Federation)

2012-12-15T23:59:59.000Z

467

Strontium isotope geochemistry of alluvial groundwater: a tracer for groundwater resources characterisation Hydrology and Earth System Sciences, 8(5), 959972 (2004) EGU  

E-Print Network [OSTI]

Strontium isotope geochemistry of alluvial groundwater: a tracer for groundwater resources characterisation 959 Hydrology and Earth System Sciences, 8(5), 959972 (2004) © EGU Strontium isotope geochemistry for corresponding author : p.negrel@brgm.fr Abstract This study presents strontium isotope and major ion data

Paris-Sud XI, Université de

468

Project EARTH-13-GMH2: U-series nuclides as tracers of modern ocean processes Supervisors: Prof. Gideon Henderson and Dr. Alex Thomas  

E-Print Network [OSTI]

flow of Atlantic deep water during the Last Glacial Maximum', Nature. Vol. 468, pp. 84 #12;Project EARTH-13-GMH2: U-series nuclides as tracers of modern ocean processes Supervisors: Prof provides information about the removal rate of material from the water-column and, for the former, about

Henderson, Gideon

469

Abstract. We present a method to treat the solvent ef-ficiently in hybrid quantum mechanical/molecular me-  

E-Print Network [OSTI]

Abstract. We present a method to treat the solvent ef- ficiently in hybrid quantum mechanical, the central reactive region is treated quan- tum mechanically to allow key bonds to be made and broken, while the surrounding non-reactive region is treated classically to make the calculations computa- tionally feasible

Dinner, Aaron

470

Hybrid nuclear reactor grey rod to obtain required reactivity worth  

DOE Patents [OSTI]

Hybrid nuclear reactor grey rods are described, wherein geometric combinations of relatively weak neutron absorber materials such as stainless steel, zirconium or INCONEL, and relatively strong neutron absorber materials, such as hafnium, silver-indium cadmium and boron carbide, are used to obtain the reactivity worths required to reach zero boron change load follow. One embodiment includes a grey rod which has combinations of weak and strong neutron absorber pellets in a stainless steel cladding. The respective pellets can be of differing heights. A second embodiment includes a grey rod with a relatively thick stainless steel cladding receiving relatively strong neutron absorber pellets only. A third embodiment includes annular relatively weak netron absorber pellets with a smaller diameter pellet of relatively strong absorber material contained within the aperture of each relatively weak absorber pellet. The fourth embodiment includes pellets made of a homogeneous alloy of hafnium and a relatively weak absorber material, with the percentage of hafnium chosen to obtain the desired reactivity worth.

Miller, John V. (Munhall, PA); Carlson, William R. (Scott Township, Allegheny County, PA); Yarbrough, Michael B. (Hempfield Township, Westmoreland County, PA)

1991-01-01T23:59:59.000Z

471

Synthesis of belite cement clinker of high hydraulic reactivity  

SciTech Connect (OSTI)

This study is concerned with the increase of the cooling rate of belite clinker, by using the water quenching for the chemical stabilization of reactive belite, which improves the hydraulic properties of this clinker. The addition of adequate mineralizers, as NaF and Fe{sub 2}O{sub 3}, contributes to the improvement of the clinker properties obtained at low burning temperature. X-ray fluorescence spectroscopy, X-ray diffraction analysis and optical microscopy were used to determine the chemical and mineralogical compositions of this clinker. The samples were analyzed by means of a scanning electronic microscope connected with an energy-dispersive X-ray spectrometer to detect the composition of the belite phase and its morphology. Physical and mechanical properties of this clinker cement were determined. The results show that the belite clinker obtained at 1150 {sup o}C, with lime saturation factor 0.67, is characterized by a great hydraulic reactivity, similar to that of the ordinary alite clinker. The addition of 2% of NaF and the water quenching improved the chemical, mineralogical and structural properties, while improving the cement hydraulic properties.

Kacimi, Larbi [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)], E-mail: kacimi20002000@yahoo.fr; Simon-Masseron, Angelique [Laboratoire des Materiaux a Porosite Controlee, CNRS UMR 7016, Universite de Haute-Alsace, 3, rue Alfred-Werner, F-68093 Mulhouse cedex (France)], E-mail: A.Simon@univ-mulhouse.fr; Salem, Souria [Departement d'Architecture, Faculte de Genie Civile, USTO-Oran (Algeria)], E-mail: zinaisalem@yahoo.fr; Ghomari, Abdelhamid [Departement de Chimie, U.A.I.B., Route de Belahcel, Mostaganem (Algeria)], E-mail: belkey@hotmail.com; Derriche, Zoubir [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)

2009-07-15T23:59:59.000Z

472

Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.  

SciTech Connect (OSTI)

In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

2012-02-01T23:59:59.000Z

473

Reactive-coupling-induced normal mode splittings in microdisk resonators coupled to waveguides  

SciTech Connect (OSTI)

We study the optomechanical design introduced by M. Li et al. [Phys. Rev. Lett. 103, 223901 (2009)], which is very effective for investigation of the effects of reactive coupling. We show the normal mode splitting that is due solely to reactive coupling rather than due to dispersive coupling. We suggest feeding the waveguide with a pump field along with a probe field and scanning the output probe for evidence of reactive-coupling-induced normal mode splitting.

Huang Sumei; Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)

2010-05-15T23:59:59.000Z

474

Effect of different intravenous iron preparations on lymphocyte intracellular reactive oxygen species generation and subpopulation survival.  

E-Print Network [OSTI]

IV iron compounds induced greater intracellular ROS generation,IV iron preparations on intracellular reactive oxygen species generationIV iron preparations on intracellular immune cell ROS generation

Gupta, Ajay; Zhuo, Jiaying; Zha, Junli; Reddy, Srinivasa; Olp, Jonathan; Pai, Amy

2010-01-01T23:59:59.000Z

475

E-Print Network 3.0 - acquired reactive perforating Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technologies and Information Sciences 2 Thesis for the Degree of Licentiate of Philosophy Reactive Shared Objects Summary: variations in order to achieve good perfor- mance...

476

E-Print Network 3.0 - anti-glutathione peroxidase-antibody reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Reactive Support and Voltage Control Service: Key Issues and Challenges George Gross, Paolo... -mail: gianfranco.chicco@polito.it Abstract -- This paper reviews...

477

Modelling of reactive gas transport in unsaturated soil. A coupled thermo-hydro-chemical-mechanical approach.  

E-Print Network [OSTI]

??This thesis presents the development of a reactive gas transport equation under coupled framework of thermal, hydraulic, chemical and mechanical (THCM) behaviour of variably saturated… (more)

Masum, Shakil Al

2012-01-01T23:59:59.000Z

478

Direct coupling of a genome-scale microbial in silico model and a groundwater reactive transport model  

SciTech Connect (OSTI)

The activity of microorganisms often plays an important role in dynamic natural attenuation or engineered bioremediation of subsurface contaminants, such as chlorinated solvents, metals, and radionuclides. To evaluate and/or design bioremediated systems, quantitative reactive transport models are needed. State-of-the-art reactive transport models often ignore the microbial effects or simulate the microbial effects with static growth yield and constant reaction rate parameters over simulated conditions, while in reality microorganisms can dynamically modify their functionality (such as utilization of alternative respiratory pathways) in response to spatial and temporal variations in environmental conditions. Constraint-based genome-scale microbial in silico models, using genomic data and multiple-pathway reaction networks, have been shown to be able to simulate transient metabolism of some well studied microorganisms and identify growth rate, substrate uptake rates, and byproduct rates under different growth conditions. These rates can be identified and used to replace specific microbially-mediated reaction rates in a reactive transport model using local geochemical conditions as constraints. We previously demonstrated the potential utility of integrating a constraint based microbial metabolism model with a reactive transport simulator as applied to bioremediation of uranium in groundwater. However, that work relied on an indirect coupling approach that was effective for initial demonstration but may not be extensible to more complex problems that are of significant interest (e.g., communities of microbial species, multiple constraining variables). Here, we extend that work by presenting and demonstrating a method of directly integrating a reactive transport model (FORTRAN code) with constraint-based in silico models solved with IBM ILOG CPLEX linear optimizer base system (C library). The models were integrated with BABEL, a language interoperability tool. The modeling system is designed in such a way that constraint-based models targeting different microorganisms or competing organism communities can be easily plugged into the system. Constraint-based modeling is very costly given the size of a genome-scale reaction network. To save computation time, a binary tree is traversed to examine the concentration and solution pool generated during the simulation in order to decide whether the constraint-based model should be called. We also show preliminary results from the integrated model including a comparison of the direct and indirect coupling approaches.

Fang, Yilin; Scheibe, Timothy D.; Mahadevan, Radhakrishnan; Garg, Srinath; Long, Philip E.; Lovley, Derek R.

2011-02-28T23:59:59.000Z

479

Tracers and Tracer Interpretation | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov Pty LtdSteen,LtdInformation Dixie Valley Geothermal Area (Reed, 2007)testing

480

Distributed control for optimal reactive power compensation in smart microgrids  

E-Print Network [OSTI]

We consider the problem of optimal reactive power compensation for the minimization of power distribution losses in a smart microgrid. We first propose an approximate model for the power distribution network, which allows us to cast the problem into the class of convex quadratic, linearly constrained, optimization problems. We also show how this model provides the tools for a distributed approach, in which agents have a partial knowledge of the problem parameters and state, and can only perform local measurements. Then, we design a randomized, gossip-like optimization algorithm, providing conditions for convergence together with an analytic characterization of the convergence speed. The analysis shows that the best performance can be achieved when we command cooperation among agents that are neighbors in the smart microgrid topology. Numerical simulations are included to validate the proposed model and to confirm the analytic results about the performance of the proposed algorithm.

Bolognani, Saverio

2011-01-01T23:59:59.000Z

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481

Development of a standard for calculation and measurement of the moderator temperature coefficient of reactivity in water-moderated power reactors  

SciTech Connect (OSTI)

The contents of ANS 19.11, the standard for ``Calculation and Measurement of the Moderator Temperature Coefficient of Reactivity in Water-Moderated Power Reactors,`` are described. The standard addresses the calculation of the moderator temperature coefficient (MTC) both at standby conditions and at power. In addition, it describes several methods for the measurement of the at-power MTC and assesses their relative advantages and disadvantages. Finally, it specifies a minimum set of documentation requirements for compliance with the standard.

Mosteller, R.D. [Los Alamos National Lab., NM (United States); Hall, R.A. [Virginia Power, Glen Allen, VA (United States). Innsbrook Technical Center; Apperson, C.E. Jr. [Westinghouse Safety Management Solutions, Inc., Aiken, SC (United States); Lancaster, D.B. [TRW Environmental Safety Systems, Inc., Vienna, VA (United States); Young, E.H. [Commonwealth Edison Co., Downers Grove, IL (United States); Gavin, P.H. [ABB Combustion Engineering, Windsor, CT (United States); Robertson, S.T. [Framatome/COGEMA Fuels, Lynchburg, VA (United States)

1998-12-01T23:59:59.000Z

482

PROOF OF CONCEPT TEST OF A UNIQUE GASEOUS PERFLUROCARBON TRACER SYSTEM FOR VERIFICATION AND LONG TERM MONITORING OF CAPS AND COVER SYSTEMS CONDUCTED AT THE SAVANNAH RIVER SITE BENTONITE MAT TEST FACILITY.  

SciTech Connect (OSTI)

Engineered covers have been placed on top of buried/subsurface wastes to minimize water infiltration and therefore, release of hazardous contaminants. In order for the cover to protect the environment it must remain free of holes and breaches throughout its service life. Covers are subject to subsidence, erosion, animal intrusion, plant root infiltration, etc., all of which will affect the overall performance of the cover. The U.S. Department of Energy Environmental Management (DOE-EM) Program 2006 Accelerated Cleanup Plan is pushing for rapid closure of many of the DOE facilities. This will require a great number of new cover systems. Some of these new covers are expected to maintain their performance for periods of up to 1000 years. Long-term stewardship will require monitoring/verification of cover performance over the course of the designed lifetime. In addition, many existing covers are approaching the end of their design life and will need validation of current performance (if continued use is desired) or replacement (if degraded). The need for a reliable method of verification and long-term monitoring is readily apparent. Currently, failure is detected through monitoring wells downstream of the waste site. This is too late as the contaminants have already left the disposal area. The proposed approach is the use of gaseous Perfluorocarbon tracers (PFT) to verify and monitor cover performance. It is believed that PFTs will provide a technology that can verify a cover meets all performance objectives upon installation, be capable of predicting changes in cover performance and failure (defined as contaminants leaving the site) before it happens, and be cost-effective in supporting stewardship needs. The PFTs are injected beneath the cover and air samples taken above (either air samples or soil gas samples) at the top of the cover. The location, concentrations, and time of arrival of the tracer(s) provide a direct measure of cover performance. PFT technology can be used as a non-invasive method (if injection ports are emplaced prior to cover emplacement) on new covers or a minimally invasive method on existing covers. PFT verification will be useful at all buried waste sites using a cover system (e.g., treated or untreated chemical waste landfills) including DOE, commercial, and private sector sites. This paper discusses the initial field trial of the PFT cover monitoring system performed at the Savannah River Site (SRS) in FY01. The experiments provided a successful proof-of-principle test of the PFT technology in monitoring caps and covers. An injection and sampling array was installed in the Bentomat test cap at the SRS Caps Test Facility. This system contained 6 feet of sandy soil beneath a 1/2 inch geosynthetic clay liner covered by an HDPE liner which was covered by 2 feet of clayey to