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1

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2-  

Open Energy Info (EERE)

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Project Type / Topic 1 Laboratory Call for Submission of Applications for Research, Development and Analysis of Geothermal Technologies Project Type / Topic 2 Tracers and Tracer Interpretation Project Description The concepts and theory behind the use of heat-sensitive tracers to study the thermal evolution of geothermal reservoirs was developed in the late 1980's under the Hot Dry Rock Project. Those studies described-conceptually and mathematically-the application of reactive tracers to tracking thermal fronts and to reservoir sizing. Later mathematical treatments focused on application of a single reactive tracer test to recover the temperature profile of a single streamtube. Previous tracer work has mainly focused on identifying conservative tracers. In these studies, chemicals that degraded at reservoir temperatures were discarded. Benzoic acids and dicarboxylic acids, which were found by Adams to degrade, may be useful as reactive tracers. Organic esters and amide tracers that undergo hydrolysis have been investigated and their use as reactive tracers appears feasible over a temperature range of 100ºC to 275ºC. However their reaction rates are pH dependent and sorption reactions have not been evaluated. While reactive tracer parameters have been measured in the lab, reactive tracers have not been extensively tested in the field. Thus, while reactive tracers appear to be a promising means of monitoring the thermal evolution of a geothermal reservoir, the concept has yet to be tested at the scale necessary for successful implementation, and tools for analyzing results of such tracer tests under the non-ideal conditions of an actual geothermal system have yet to be developed.

2

Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Peer Review 2010 - Presentation. This project aims to develop reactive tracer method for monitoring thermal drawdown in enhanced geothermal systems.

3

Advancing Reactive Tracer Methods for Measurement of Thermal Evolution in Geothermal Reservoirs: Final Report  

SciTech Connect

The injection of cold fluids into engineered geothermal system (EGS) and conventional geothermal reservoirs may be done to help extract heat from the subsurface or to maintain pressures within the reservoir (e.g., Rose et al., 2001). As these injected fluids move along fractures, they acquire heat from the rock matrix and remove it from the reservoir as they are extracted to the surface. A consequence of such injection is the migration of a cold-fluid front through the reservoir (Figure 1) that could eventually reach the production well and result in the lowering of the temperature of the produced fluids (thermal breakthrough). Efficient operation of an EGS as well as conventional geothermal systems involving cold-fluid injection requires accurate and timely information about thermal depletion of the reservoir in response to operation. In particular, accurate predictions of the time to thermal breakthrough and subsequent rate of thermal drawdown are necessary for reservoir management, design of fracture stimulation and well drilling programs, and forecasting of economic return. A potential method for estimating migration of a cold front between an injection well and a production well is through application of reactive tracer tests, using chemical whose rate of degradation is dependent on the reservoir temperature between the two wells (e.g., Robinson 1985). With repeated tests, the rate of migration of the thermal front can be determined, and the time to thermal breakthrough calculated. While the basic theory behind the concept of thermal tracers has been understood for some time, effective application of the method has yet to be demonstrated. This report describes results of a study that used several methods to investigate application of reactive tracers to monitoring the thermal evolution of a geothermal reservoir. These methods included (1) mathematical investigation of the sensitivity of known and hypothetical reactive tracers, (2) laboratory testing of novel tracers that would improve method sensitivity, (3) development of a software tool for design and interpretation of reactive tracer tests and (4) field testing of the reactive tracer temperature monitoring concept.

Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; Laurence C. Hull; George D. Redden

2011-07-01T23:59:59.000Z

4

Tracer Methods for Characterizing Fracture Stimulation in Engineered...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS) Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal...

5

Tracer Methods for Characterizing Fracture Creation in Enhanced...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing Fracture...

6

Tracer Methods for Characterizing Fracture Stimulation in Enhanced...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Tracer Methods for Characterizing Fracture Stimulation in Enhanced Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing...

7

Passive Tracer Gas Methods to Measure  

NLE Websites -- All DOE Office Websites (Extended Search)

Experiments to Evaluate and Implement Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure Ventilation Rates in Homes Melissa Lunden, David Faulkner, Elizabeth Heredia, Sebastian Cohn, Darryl Dickerhoff, Federico Noris, Jennifer Logue, Toshifumi Hotchi, Brett Singer and Max H. Sherman Environmental Energy Technologies Division October 2012 LBNL-5984E 2 Disclaimer: This document was prepared as an account of work sponsored by the United States

8

Tracer Methods for Characterizing Fracture Creation in Enhanced...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

75 4.6.6 Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems Presentation Number: 033 Investigator: Rose, Peter (University of Utah) Objectives: To...

9

Tracer Methods for Characterizing Fracture Stimulation in Enhanced...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

80 4.6.7 Tracer Methods for Characterizing Fracture Stimulation in Enhanced Geothermal Systems (EGS) Presentation Number: 034 Investigator: Pruess, Karsten (Lawrence Berkeley...

10

Tracer Methods for Characterizing Fracture Stimulation in Engineered...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS) Karsten Pruess Lawrence Berkeley National Lab. May 19, 2010 This presentation does not...

11

Method of dispersing particulate aerosol tracer  

DOE Patents (OSTI)

A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

O'Holleran, Thomas P. (Belleville, MI)

1988-01-01T23:59:59.000Z

12

Tracer method in numerical simulation of combustion processes  

Science Journals Connector (OSTI)

Fuel-rich laminar flat hydrogen-methane-air flames are studied numerically using the tracer method. It is found that, in the near-limit mixture, hydrogen has an advantage in the oxidation by oxygen. As the sto...

V. A. Bunev; A. V. Baklanov; I. G. Namyatov

2007-11-01T23:59:59.000Z

13

Preferred methods of analysis for chemical tracers in moderate- and  

Open Energy Info (EERE)

Preferred methods of analysis for chemical tracers in moderate- and Preferred methods of analysis for chemical tracers in moderate- and high-temperature geothermal environments Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Report: Preferred methods of analysis for chemical tracers in moderate- and high-temperature geothermal environments Details Activities (2) Areas (2) Regions (0) Abstract: This report describes the sampling and analytical techniques used for tracer analysis in the Raft River and East Mesa field tests. The collection procedures and sample preservation techniques, analytical methods and possible sources of contamination or error are discussed in detail. Author(s): Kroneman, R. L.; Yorgason, K. R.; Moore, J. N. Published: DOE Information Bridge, 12/1/1984 Document Number: Unavailable DOI: 10.2172/5121460

14

Methods and systems using encapsulated tracers and chemicals for reservoir interrogation and manipulation  

DOE Patents (OSTI)

An apparatus, method, and system of reservoir interrogation. A tracer is encapsulating in a receptacle. The receptacle containing the tracer is injected into the reservoir. The tracer is analyzed for reservoir interrogation.

Roberts, Jeffery; Aines, Roger D; Duoss, Eric B; Spadaccini, Christopher M

2014-11-04T23:59:59.000Z

15

Validation of Geothermal Tracer Methods in Highly Constrained...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of Research Hypothesis: Smart tracers can measure potential heat exchange between fracture and rock mass Hypothesis Test: A tracer test proving ground System must be simple...

16

Validation of Geothermal Tracer Methods in Highly Constrained Field Experiments  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Peer Review 2010 - Project Summary. This project will test smartdiffusive tracers for measuring heat exchange.

17

Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts  

DOE Patents (OSTI)

A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Anderson, Raymond P. (Idaho Falls, ID)

2008-08-05T23:59:59.000Z

18

Advancing reactive tracer methods for measuring thermal evolution...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

et al. (2003) - Use simplified geometry of hypothetical fracture system - Develop in MATLAB, to allow distribution to industry via the MATLAB compiler * Conducted 2-D finite...

19

Verification of Geothermal Tracer Methods in Highly Constrained...  

Open Energy Info (EERE)

tracers of varying rates of molecular diffusion. Exchange of heat energy between fracture and bulk rock (matrix) behaves in the same manner as the exchange of dissolved mass....

20

Preliminary Investigation of Tracer Gas Reaeration Method for Shallow Bays  

E-Print Network (OSTI)

was used with propane for the tracer gas and Rhodamine-WT, a fluorescent dye, for the "conservative" tracer. The propane was injected through porous tile diffusers, and the dye was released simultaneously. The propane acts as a model for the surface...

Baker, Sarah H.; Holley, Edward R.

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Validation of Geothermal Tracer Methods in Highly Constrained...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs Fracture Evolution Following a Hydraulic Stimulation within an EGS Reservoir Quantum Dot...

22

Uncertainties in Air Exchange using Continuous-Injection, Long-Term Sampling Tracer-Gas Methods  

SciTech Connect

The PerFluorocarbon Tracer (PFT) method is a low-cost approach commonly used for measuring air exchange in buildings using tracer gases. It is a specific application of the more general Continuous-Injection, Long-Term Sampling (CILTS) method. The technique is widely used but there has been little work on understanding the uncertainties (both precision and bias) associated with its use, particularly given that it is typically deployed by untrained or lightly trained people to minimize experimental costs. In this article we will conduct a first-principles error analysis to estimate the uncertainties and then compare that analysis to CILTS measurements that were over-sampled, through the use of multiple tracers and emitter and sampler distribution patterns, in three houses. We find that the CILTS method can have an overall uncertainty of 10-15percent in ideal circumstances, but that even in highly controlled field experiments done by trained experimenters expected uncertainties are about 20percent. In addition, there are many field conditions (such as open windows) where CILTS is not likely to provide any quantitative data. Even avoiding the worst situations of assumption violations CILTS should be considered as having a something like a ?factor of two? uncertainty for the broad field trials that it is typically used in. We provide guidance on how to deploy CILTS and design the experiment to minimize uncertainties.

Sherman, Max H.; Walker, Iain S.; Lunden, Melissa M.

2013-12-01T23:59:59.000Z

23

Analytical methods for determining the reactivity of pyrochemical salts  

SciTech Connect

Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

Phillips, A.G.; Stakebake, J.L.

1994-05-01T23:59:59.000Z

24

CO2 tracer gas concentration decay method for measuring air change rate  

Science Journals Connector (OSTI)

Abstract The measure of air change rate (ACR) in building is a difficult and usually expensive task. The tracer gas method is the reference technique but its implementation is difficult and the interpretation of results is not straightforward. In the present work, the concentration decay method by multiple CO2 transmitters is experimentally validated in the case of cross-ventilation. It is observed that in-situ CO2 transmitters lead to ACR values in good agreement with reference measurements obtained from mechanically controlled values. Whereas multiple transmitters in different sampling positions show the imperfect mixing, a sensor located at the outlet or an averaged value of all sensors can provide an accurate measure of the ACR. Moreover, the spatial variation of CO2 concentration can be used to assess the ventilation efficiency in the test chamber. Different measures and calculation methods are discussed, and the uncertainty analysis of each method is carried out.

Shuqing Cui; Michal Cohen; Pascal Stabat; Dominique Marchio

2015-01-01T23:59:59.000Z

25

Environmentally stable reactive alloy powders and method of making same  

DOE Patents (OSTI)

Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

1998-09-22T23:59:59.000Z

26

Research on fuzzy logic based dynamic boundary voltage and reactive power integrated control method  

Science Journals Connector (OSTI)

Aiming at the existing problems of conventional substation voltage and reactive power integrated control method, a new fuzzy logic based dynamic reactive power boundary voltage and reactive power integrated control method is proposed. Fuzzy logic control ... Keywords: dynamic boundary, fuzzy logic, reactive power, voltage

Zigang Xu; Fei Wang

2009-06-01T23:59:59.000Z

27

Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS)  

Energy.gov (U.S. Department of Energy (DOE))

Project objectives: identify tracers with sorption properties favorable for EGS applications; apply reversibly sorbing tracers to determine the fracture-matrix interface area available for heat transfer; and; explore the feasibility of obtaining fracture-matrix interface area from non-isothermal; single-well injection-withdrawal (SWIW) tests.

28

Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same  

DOE Patents (OSTI)

An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

Fritz, Gregory M; Knepper, Robert Allen; Weihs, Timothy P; Gash, Alexander E; Sze, John S

2013-04-30T23:59:59.000Z

29

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect

Many contaminated areas consist of a source area and a plume. In the source area, the contaminant moves vertically downward from a release point through the vadose zone to an underlying saturated region. Where contaminants are organic liquids, NAPL may accumulate on the water table, or it may continue to migrate downward through the saturated region. Early developments of permeable barrier technology have focused on intercepting horizontally moving plumes with vertical structures, such as trenches, filled with reactive material capable of immobilizing or degrading dissolved contaminants. This focus resulted in part from a need to economically treat the potentially large volumes of contaminated water in a plume, and in part from the availability of construction technology to create the vertical structures that could house reactive compounds. Contaminant source areas, however, have thus far remained largely excluded from the application of permeable barrier technology. One reason for this is the lack of conventional construction methods for creating suitable horizontal structures that would place reactive materials in the path of downward-moving contaminants. Methods of hydraulic fracturing have been widely used to create flat-lying to gently dipping layers of granular material in unconsolidated sediments. Most applications thus far have involved filling fractures with coarse-grained sand to create permeable layers that will increase the discharge of wells recovering contaminated water or vapor. However, it is possible to fill fractures with other compounds that alter the chemical composition of the subsurface. One early application involved development and field testing micro-encapsulated sodium percarbonate, a solid compound that releases oxygen and can create aerobic conditions suitable for biodegradation in the subsurface for several months.

Murdoch, L. [FRx Inc., Cincinnati, OH (United States); [Clemson Univ., SC (United States); Siegrist, B. [Oak Ridge National Lab., TN (United States); Vesper, S. [Univ. of Cincinnati, OH (United States)] [and others

1997-12-31T23:59:59.000Z

30

Tracer method to measure landfill gas emissions from leachate collection systems  

Science Journals Connector (OSTI)

This paper describes a method developed for quantification of gas emissions from the leachate collection system at landfills and present emission data measured at two Danish landfills with no landfill gas collection systems in place: Fakse landfill and AV Milj. Landfill top covers are often designed to prevent infiltration of water and thus are made from low permeable materials. At such sites a large part of the gas will often emit through other pathways such as the leachate collection system. These point releases of gaseous constituents from these locations cannot be measured using traditional flux chambers, which are often used to measure gas emissions from landfills. Comparing tracer measurements of methane (CH4) emissions from leachate systems at Fakse landfill and AV Milj to measurements of total CH4 emissions, it was found that approximately 47% (351kg CH4 d?1) and 27% (211kg CH4 d?1), respectively, of the CH4 emitting from the sites occurred from the leachate collection systems. Emission rates observed from individual leachate collection wells at the two landfills ranged from 0.1 to 76kg CH4 d?1. A strong influence on emission rates caused by rise and fall in atmospheric pressure was observed when continuously measuring emission from a leachate well over a week. Emission of CH4 was one to two orders of magnitude higher during periods of decreasing pressure compared to periods of increasing pressure.

Anders M. Fredenslund; Charlotte Scheutz; Peter Kjeldsen

2010-01-01T23:59:59.000Z

31

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

32

Tracer Testing | Open Energy Information  

Open Energy Info (EERE)

Tracer Testing Tracer Testing Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Tracer Testing Details Activities (9) Areas (5) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Testing Techniques Parent Exploration Technique: Well Testing Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Fracture zones and formation permeability Hydrological: Flow rates, flow direction, hydrologic connections, storativity Thermal: Dictionary.png Tracer Testing: A method based on injecting chemical tracers into the reservoir and monitoring how long it takes and where those tracers travel. The purpose is to model subsurface hydrothermal flow characteristics.

33

An Improved Gas Chromatographic Method for the Determination of Perfluorocarbon Tracers in the Atmosphere  

Science Journals Connector (OSTI)

......U.S. Department of Energy, New York, New York...U.S. Department of Energy, New York, New York...quantity, hence the cost, of the tracer required...experiments in the geysers geothermal area. RH. Gudiksen...U. S. Department of Energy, New York, NY(1991......

Raymond J. Lagomarsino

1996-09-01T23:59:59.000Z

34

Tracers and Tracer Interpretation | Open Energy Information  

Open Energy Info (EERE)

Tracers and Tracer Interpretation Tracers and Tracer Interpretation Jump to: navigation, search Contents 1 Geothermal Lab Call Projects for Tracers and Tracer Interpretation 2 Geothermal ARRA Funded Projects for Tracers and Tracer Interpretation Geothermal Lab Call Projects for Tracers and Tracer Interpretation Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026

35

Uncertainties in Air Exchange using Continuous-Injection, Long-Term Sampling Tracer-Gas Methods  

E-Print Network (OSTI)

Pollutant Control Index: A New Method of Characterizing Ventilation in Commercial Buildings." Proceedings of Indoor Air'

Sherman, Max H.

2014-01-01T23:59:59.000Z

36

Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure Ventilation Rates in Homes  

E-Print Network (OSTI)

Pollutant Control Index: A New Method of Characterizing Ventilation in Commercial Buildings." Proceedings of Indoor Air'

Lunden, Melissa

2014-01-01T23:59:59.000Z

37

Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity  

DOE Patents (OSTI)

A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime (about 40 ps), high frequency (about 5G hz), high power bursts of low-duty factor microwaves sufficient to generate a dielectric barrier discharge and passing a gas to treated through the discharge so as to cause dissociative reduction of the exhaust gases. The invention also includes a reactor for generating the non-thermal plasma.

Whealton, John H. (Oak Ridge, TN); Hanson, Gregory R. (Clinton, TN); Storey, John M. (Oak Ridge, TN); Raridon, Richard J. (Oak Ridge, TN); Armfield, Jeffrey S. (Upsilanti, MI); Bigelow, Timothy S. (Knoxville, TN); Graves, Ronald L. (Knoxville, TN)

2001-01-01T23:59:59.000Z

38

Quantum Dot Tracers for Use in Engineered Geothermal | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

tracerspeer2013.pdf More Documents & Publications Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS) Quantum Dot Tracers for Use in...

39

Radon entry rate analyses using in situ tracer gas method application  

Science Journals Connector (OSTI)

......indoor environment, standard methods of radon diagnosis...ventilation (specific modes of HVAC systems operation...for new houses given in standards. Table-5. Results...efforts to comply with the standard requirements on new buildings...services in buildings like HVAC systems, water and gas......

A. Fro?ka; K. Jlek

2014-07-01T23:59:59.000Z

40

BNL | Tracer Technology Group | BNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracer Technology Group Tracer Technology Group Tracer Technology Image The Tracer Technology Group (TTG) developed the use of perfluorocarbon tracers (PFTs) as tools for studying long range atmospheric transport and dispersion in the early 1980s.We are world leaders in the use of PFTs for solving diverse research and engineering problems in the atmospheric sciences, the energy production and utility industries, and building characterization. The unique capabilities of the TTG are derived from our analytical expertise, infrastructure, and experience. We have developed PFT analytical methods that have detection limits at the femtogram level. We can measure global background levels of PFTS at the parts per quadrillion levels. Our scientists and technical staff have extensive experience in

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Comparison of the optoacoustic and Hg tracer methods for the study of energy-transfer processes in gas mixtures  

SciTech Connect

Rates of energy transfer from vibrationally excited SF/sub 6/ and pentafluorobenzene to argon in the gas phase have been studied by using the Hg tracer technique and time-resolved optoacoustics. These two techniques which rely on fundamentally different physical principles were found to give equivalent results. The implications for the study of energy-transfer processes in gas mixtures are discussed.

Wallington, T.J.; Braun, W.; Beck, K.M.; Gordon, R.J.

1988-06-30T23:59:59.000Z

42

Probing Material Reactivity Using X-ray Pair Distribution Function Methods  

NLE Websites -- All DOE Office Websites (Extended Search)

Material Reactivity Using X-ray Pair Distribution Material Reactivity Using X-ray Pair Distribution Function Methods Karena W. Chapman X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA Understanding how advanced functional materials react and transform, at an atomic scale, is a characterization challenge with many diverse phenomena possible; components with varying particle size, morphology, and microstructure can evolve from multi-atom clusters to multi-million atom crystals. The pair distribution function (PDF) method shows great promise for providing quantitative insight such reactions. Recent advances in experimental methods, have improved the efficiency of X-ray PDF measurements, to allow time-resolved experiments with sufficient resolution to study reactions in solid

43

Method of extruding and packaging a thin sample of reactive material, including forming the extrusion die  

DOE Patents (OSTI)

This invention teaches a method of cutting a narrow slot in an extrusion die with an electrical discharge machine by first drilling spaced holes at the ends of where the slot will be, whereby the oil can flow through the holes and slot to flush the material eroded away as the slot is being cut. The invention further teaches a method of extruding a very thin ribbon of solid highly reactive material such as lithium or sodium through the die in an inert atmosphere of nitrogen, argon, or the like as in a glovebox. The invention further teaches a method of stamping out sample discs from the ribbon and of packaging each disc by sandwiching it between two aluminum sheets and cold welding the sheets together along an annular seam beyond the outer periphery of the disc. This provides a sample of high purity reactive material that can have a long shelf life.

Lewandowski, E.F.; Peterson, L.L.

1981-11-30T23:59:59.000Z

44

Method of extruding and packaging a thin sample of reactive material including forming the extrusion die  

DOE Patents (OSTI)

This invention teaches a method of cutting a narrow slot in an extrusion die with an electrical discharge machine by first drilling spaced holes at the ends of where the slot will be, whereby the oil can flow through the holes and slot to flush the material eroded away as the slot is being cut. The invention further teaches a method of extruding a very thin ribbon of solid highly reactive material such as lithium or sodium through the die in an inert atmosphere of nitrogen, argon or the like as in a glovebox. The invention further teaches a method of stamping out sample discs from the ribbon and of packaging each disc by sandwiching it between two aluminum sheets and cold welding the sheets together along an annular seam beyond the outer periphery of the disc. This provides a sample of high purity reactive material that can have a long shelf life.

Lewandowski, Edward F. (Westmont, IL); Peterson, Leroy L. (Joliet, IL)

1985-01-01T23:59:59.000Z

45

Tracers and Exploration Technologies  

Energy.gov (U.S. Department of Energy (DOE))

Below are the project presentations and respective peer review results for Tracers and Exploration Technologies.

46

Catalytic and reactive polypeptides and methods for their preparation and use  

DOE Patents (OSTI)

Catalytic and reactive polypeptides include a binding site specific for a reactant or reactive intermediate involved in a chemical reaction of interest. The polypeptides further include at least one active functionality proximate the binding site, where the active functionality is capable of catalyzing or chemically participating in the chemical reaction in such a way that the reaction rate is enhanced. Methods for preparing the catalytic peptides include chemical synthesis, site-directed mutagenesis of antibody and enzyme genes, covalent attachment of the functionalities through particular amino acid side chains, and the like. This invention was made with Government support under Grant Contract No. AI-24695, awarded by the Department of health and Human Services, and under Grant Contract No. N 00014-87-K-0256, awarded by the Office of Naval Research. The Government has certain rights in this invention.

Schultz, Peter (Oakland, CA)

1994-01-01T23:59:59.000Z

47

Systems and methods for reactive distillation with recirculation of light components  

SciTech Connect

Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

2011-07-26T23:59:59.000Z

48

GUINEVERE experiment: Kinetic analysis of some reactivity measurement methods by deterministic and Monte Carlo codes  

SciTech Connect

The GUINEVERE experiment (Generation of Uninterrupted Intense Neutrons at the lead Venus Reactor) is an experimental program in support of the ADS technology presently carried out at SCK-CEN in Mol (Belgium). In the experiment a modified lay-out of the original thermal VENUS critical facility is coupled to an accelerator, built by the French body CNRS in Grenoble, working in both continuous and pulsed mode and delivering 14 MeV neutrons by bombardment of deuterons on a tritium-target. The modified lay-out of the facility consists of a fast subcritical core made of 30% U-235 enriched metallic Uranium in a lead matrix. Several off-line and on-line reactivity measurement techniques will be investigated during the experimental campaign. This report is focused on the simulation by deterministic (ERANOS French code) and Monte Carlo (MCNPX US code) calculations of three reactivity measurement techniques, Slope ({alpha}-fitting), Area-ratio and Source-jerk, applied to a GUINEVERE subcritical configuration (namely SC1). The inferred reactivity, in dollar units, by the Area-ratio method shows an overall agreement between the two deterministic and Monte Carlo computational approaches, whereas the MCNPX Source-jerk results are affected by large uncertainties and allow only partial conclusions about the comparison. Finally, no particular spatial dependence of the results is observed in the case of the GUINEVERE SC1 subcritical configuration. (authors)

Bianchini, G.; Burgio, N.; Carta, M. [ENEA C.R. CASACCIA, via Anguillarese, 301, 00123 S. Maria di Galeria Roma (Italy); Peluso, V. [ENEA C.R. BOLOGNA, Via Martiri di Monte Sole, 4, 40129 Bologna (Italy); Fabrizio, V.; Ricci, L. [Univ. of Rome La Sapienza, C/o ENEA C.R. CASACCIA, via Anguillarese, 301, 00123 S. Maria di Galeria Roma (Italy)

2012-07-01T23:59:59.000Z

49

Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier  

DOE Patents (OSTI)

Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

Harrup, Mason K. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID)

2007-05-15T23:59:59.000Z

50

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents (OSTI)

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

51

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents (OSTI)

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

52

Microseismic Tracer Particles for Hydraulic Fracturing  

NLE Websites -- All DOE Office Websites (Extended Search)

Microseismic Tracer Particles for Hydraulic Fracturing Microseismic Tracer Particles for Hydraulic Fracturing Microseismic Tracer Particles for Hydraulic Fracturing Scientists at Los Alamos National Laboratory have developed a method by which microseismic events can be discriminated/detected that correspond to only the portion of the hydraulic fracture that contains the proppant material and can be expected to be conductive to the flow of oil and gas. July 3, 2013 Microseismic Tracer Particles for Hydraulic Fracturing Figure 1: A graph of ionic conductivity as a function of temperature for the anti-perovskite Li3OCl. Available for thumbnail of Feynman Center (505) 665-9090 Email Microseismic Tracer Particles for Hydraulic Fracturing Applications: Oil and gas production Geophysical exploration Benefits: Tracks the disposition of material in a hydraulic fracturing

53

Accelerated test methods for evaluating alkali-silica reactivity of recycled concrete aggregates.  

E-Print Network (OSTI)

??This thesis reports the findings of a study carried out to determine the effectiveness of Accelerated Tests in evaluating the Alkali-Silica Reactivity of Recycled Concrete (more)

Johnson, Robert C (Author)

2011-01-01T23:59:59.000Z

54

REACTIVITY MONITORING USING THE AREA METHOD FOR THE SUBCRITICAL VENUS-F CORE WITHIN THE FRAMEWORK OF THE FREYA PROJECT  

E-Print Network (OSTI)

1 REACTIVITY MONITORING USING THE AREA METHOD FOR THE SUBCRITICAL VENUS-F CORE WITHIN THE FRAMEWORK consists of the coupling of a subcritical fast reactor to a particle accelerator via a heavy material). It couples the VENUS-F subcritical fast core with the GENEPI-3C accelerator. The latter delivers a beam

Paris-Sud XI, Université de

55

Category:Tracer Testing | Open Energy Information  

Open Energy Info (EERE)

Tracer Testing page? For detailed information on Tracer Testing, click here. Category:Tracer Testing Add.png Add a new Tracer Testing Technique Pages in category "Tracer Testing"...

56

Sensitivity analysis of reactivity responses using one-dimensional discrete ordinates and three-dimensional Monte Carlo methods  

SciTech Connect

The TSUNAMI computational sequences currently in the SCALE 5 code system provide an automated approach to performing sensitivity and uncertainty analysis for eigenvalue responses, using either one-dimensional discrete ordinates or three-dimensional Monte Carlo methods. This capability has recently been expanded to address eigenvalue-difference responses such as reactivity changes. This paper describes the methodology and presents results obtained for an example advanced CANDU reactor design. (authors)

Williams, M. L.; Gehin, J. C.; Clarno, K. T. [Oak Ridge National Laboratory, Bldg. 5700, P.O. Box 2008, Oak Ridge, TN 37831-6170 (United States)

2006-07-01T23:59:59.000Z

57

First Tracer Test After Circulation in Desert Peak 27-15  

DOE Data Explorer (OSTI)

Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

Peter Rose

58

First Tracer Test After Circulation in Desert Peak 27-15  

SciTech Connect

Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

Rose, Peter

2013-11-16T23:59:59.000Z

59

Tracer Testing At Coso Geothermal Area (1993) | Open Energy Information  

Open Energy Info (EERE)

Tracer Testing At Coso Geothermal Area (1993) Tracer Testing At Coso Geothermal Area (1993) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Tracer Testing At Coso Geothermal Area (1993) Exploration Activity Details Location Coso Geothermal Area Exploration Technique Tracer Testing Activity Date 1993 Usefulness useful DOE-funding Unknown Exploration Basis To determine the steam and water mass flow rate Notes The method involves precisely metered injection of liquid and vapor phase tracers into the two-phase production pipeline and concurrent sampling of each phase downstream of the injection point. Subsequent chemical analysis of the steam and water samples for tracer content enables the calculation of mass flowrate for each phase given the known mass injection rates of

60

Microsoft PowerPoint - Tracer plume detection-LANL(Fessenden).ppt  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracer Testing of Plume Movement Tracer Testing of Plume Movement Julianna Fessenden and Paul Reimus, Los Alamos National Laboratory Plume modeling (atmosphere, reservoir, groundwater) Purpose of Tracing Plumes Monitor species of interest within reservoir Monitor species of interest outside reservoir Monitor Flow paths Capture zones Monitor Breaches Extent of movement Desirable Tracer Characteristics (1) Inexpensive (measurement, analytical) (2) Low detection limits, no analytical interferences (3) Quick, easy to sample and measure (4) Non toxic, readily permitted (5) Both sorbing/non-sorbing tracer use Perflorocarbon Tracer deployment NETL facilities Classes of Tracers (1) Gas Phase (2) Liquid Phase (3) Organic, inorganic, aqueous (4) Conservative/nonreacting (5) Reactive with mineral surfaces or soluble in non-carrier phase

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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61

Reactive air brazing: A novel method of sealing SOFCs and other solid-state electrochemical devices  

SciTech Connect

High temperature electrochemical devices operate via an ion gradient that develops across a solid electrolyte; consequently, hermeticity across this membrane is paramount. Not only must the electrolyte contain no interconnected porosity, but it must be connected to device chassis with a gas-tight seal. Here we report a new method of brazing developed specifically for solid-state electrochemical applications. We demonstrate that the seal is hermetic and resistant to thermal aging, can be thermally cycled under rapid heating rates with no measurable loss in seal strength, and has shown promise in sealing full-size pSOFC components.

Weil, K. Scott; Kim, Jin Yong Y.; Hardy, John S.

2005-02-28T23:59:59.000Z

62

Quantitative assessment of alkali-reactive aggregate mineral content through XRD using polished sections as a supplementary tool to RILEM AAR-1 (petrographic method)  

SciTech Connect

The mineral content of 5 aggregate samples from 4 different countries, including reactive and non-reactive aggregate types, was assessed quantitatively by X-ray diffraction (XRD) using polished sections. Additionally, electron probe microanalyzer (EPMA) mapping and cathodoluminescence (CL) were used to characterize the opal-CT identified in one of the aggregate samples. Critical review of results from polished sections against traditionally powdered specimen has demonstrated that for fine-grained rocks without preferred orientation the assessment of mineral content by XRD using polished sections may represent an advantage over traditional powder specimens. Comparison of data on mineral content and silica speciation with expansion data from PARTNER project confirmed that the presence of opal-CT plays an important role in the reactivity of one of the studied aggregates. Used as a complementary tool to RILEM AAR-1, the methodology suggested in this paper has the potential to improve the strength of the petrographic method.

Castro, Nelia, E-mail: nelia.castro@ntnu.no [Norwegian University of Science and Technology (NTNU), Department of Geology and Mineral Resources Engineering, Sem Saelands vei 1, N-7491 Trondheim (Norway)] [Norwegian University of Science and Technology (NTNU), Department of Geology and Mineral Resources Engineering, Sem Saelands vei 1, N-7491 Trondheim (Norway); Sorensen, Bjorn E. [Norwegian University of Science and Technology (NTNU), Department of Geology and Mineral Resources Engineering, Sem Saelands vei 1, N-7491 Trondheim (Norway)] [Norwegian University of Science and Technology (NTNU), Department of Geology and Mineral Resources Engineering, Sem Saelands vei 1, N-7491 Trondheim (Norway); Broekmans, Maarten A.T.M. [Geological Survey of Norway, Department of Industrial Minerals and Metals, PO Box 6315 Sluppen, N-7491 Trondheim (Norway)

2012-11-15T23:59:59.000Z

63

Reactivity monitoring using the area method for the subcritic al VENUS-F core within the framework of the FREYA Project  

E-Print Network (OSTI)

Accelerator-Driven Systems (ADS) could be employed to incinerate minor actinides and so partly contribute to answer the problem of nuclear waste management. An ADS consists of the coupling of a subcritical fast reactor to a particle accelerator via a heavy material spallation target. The on-line reactivity monitoring of such an ADS is a serious issue regarding its safety. In order to study the methodology of this monitoring, zero-power experimentswere undertaken at the GUINEVERE facility within the framework of the FP6-IP-EUROTRANS programme. Such experiments have been under completion within the FREYA FP7 project. The GUINEVERE facility is hosted at the SCK-CEN site in Mol (Belgium). It couples the VENUS-F subcritical fast core with the GENEPI-3C accelerator. The latter delivers a beam of deuterons, which are converted into 14-MeV neutrons via fusion reactions on a tritiated target. This paper presents one of the investigated methods for ADS on-line reactivity monitoring which has to be validated in the program of the FREYA project. It describes the results obtained when Pulsed Neutron Source experiments are analysed using the so called Area Method, in order to estimate the reactivity of a few sub-critical configurations of the VENUS-F reactor, around keff= 0.96. First the GUINEVERE facility is described. Then, following general considerations on the Area method, the results of its application to the neutron population time decrease spectra measured after a pulse by several fission chambers spread out over the whole reactor are discussed. Finally the reactivity values extracted are compared to the static reactivity values obtained using the Modified Source Multiplication (MSM) method.

N. Marie; G. Lehaut; J. L. Lecouey; A. Billebaud; S. Chabod; X. Doligez; F. R. Lecolley; A. Kochetkov; W. Uyttenhove; G. Vittiglio; J. Wagemans; F. Mellier; G. Ban; H. E. Thybault; D. Villamarin

2013-06-05T23:59:59.000Z

64

Multispecies Reactive Tracer Test in a Sand and  

E-Print Network (OSTI)

of water quality in public water systems; remediation of contaminated sites, sediments and ground water Subsurface Protection and Remediation Division National Risk Management Research Laboratory Ada, OK 74820 Agency is charged by Congress with protecting the Nation's land, air, and water resources. Under

65

A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene  

Open Energy Info (EERE)

Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Details Activities (1) Areas (1) Regions (0) Abstract: A tracer test was conducted at the Coso geothermal field in order to characterize the flow patterns of fluid injected into well 68-20RD. A conservative liquid phase tracer, 2-naphthalene sulfonate, and a two-phase tracer, ethanol, were injected into well 68-20RD. Surrounding production wells were sampled over the subsequent 125 days and analyzed for the two tracers. The liquid-phase tracer showed negligible returns, whereas the

66

Quantitative interpretation of tracer test data | Open Energy Information  

Open Energy Info (EERE)

Quantitative interpretation of tracer test data Quantitative interpretation of tracer test data Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Quantitative interpretation of tracer test data Abstract Geothermal reinjection is an important part of sustainable management of geothermal resources. Reinjection started out as a method of waste-water disposal, but is now also being used to counteract pressure draw-down and to extract more thermal energy from reservoir rocks. The possible cooling of production wells, or thermal breakthrough, is one of the main disadvantages associated with injection. To minimize this danger while maintaining the benefit from reinjection requires careful testing and research. Tracer testing, which is used to study flow-paths and quantify fluid-flow in hydrological systems, is probably the most important tool for

67

Nanoscale study of reactive transport in catalyst layer of proton exchange membrane fuel cells with precious and non-precious catalysts using lattice Boltzmann method  

E-Print Network (OSTI)

High-resolution porous structures of catalyst layer (CL) with multicomponent in proton exchange membrane fuel cells are reconstructed using a reconstruction method called quartet structure generation set. Characterization analyses of nanoscale structures are implemented including pore size distribution, specific area and phase connectivity. Pore-scale simulation methods based on the lattice Boltzmann method are developed and used to predict the macroscopic transport properties including effective diffusivity and proton conductivity. Nonuniform distributions of ionomer in CL generates more tortuous pathway for reactant transport and greatly reduces the effective diffusivity. Tortuosity of CL is much higher than conventional Bruggeman equation adopted. Knudsen diffusion plays a significant role in oxygen diffusion and significantly reduces the effective diffusivity. Reactive transport inside the CL is also investigated. Although the reactive surface area of non-precious metal catalyst (NPMC) CL is much higher t...

Chen, Li; Kang, Qinjun; Holby, Edward F; Tao, Wen-Quan

2014-01-01T23:59:59.000Z

68

A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene...  

Open Energy Info (EERE)

navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase...

69

Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain Site Characterization Study; Progress report, June 1--December 31, 1990  

SciTech Connect

Ground water tracers are solutes dissolved in or carried by ground water to delineate flow pathways. Tracers provide information on direction and speed of water movement and that of contaminants that might be conveyed by the water. Tracers can also be used to measure effective porosity, hydraulic conductivity, dispersivity and solute distribution coefficients. For most applications tracers should be conservative, that is, move at the same rate as the water and not sorb to aquifer materials. Tracers must have a number of properties to be functional. Regardless of the desired properties, the chemical and physical behavior of a tracer in ground water and the porous medium under study must be understood. Good estimates of tracer behavior can be obtained from laboratory studies. Studies in this proposal will address tracer properties with analytical method development, static sorption and degradation studies and column transport studies, Mutagenicity tests will be performed on promising candidates. The tracers that will be used for these experiments are fluorinated organic acids and other organic compounds that have the chemical and biological stability necessary to be effective in the Yucca Mountain environment. Special emphasis will be placed on compounds that fluoresce or have very large ultraviolet absorption coefficients for very high analytical sensitivity.

Stetzenbach, K.J.

1990-12-31T23:59:59.000Z

70

Non-invasive in situ plasma monitoring of reactive gases using the floating harmonic method for inductively coupled plasma etching application  

SciTech Connect

The floating harmonic method was developed for in situ plasma diagnostics of allowing real time measurement of electron temperature (T{sub e}) and ion flux (J{sub ion}) without contamination of the probe from surface modification by reactive species. In this study, this novel non-invasive diagnostic system was studied to characterize inductively coupled plasma of reactive gases monitoring T{sub e} and J{sub ion} for investigating the optimum plasma etching conditions and controlling of the real-time plasma surface reaction in the range of 200-900 W source power, 10-100 W bias power, and 3-15 mTorr chamber pressure, respectively.

Lee, J. H.; Kim, M. J. [Department of Materials Science and Engineering, University of Texas at Dallas, Texas 75080 (United States); Yoon, Y. S. [Department of Electrical Engineering, University of Texas at Dallas, Texas 75080 (United States)

2013-04-15T23:59:59.000Z

71

Reactive Maintenance  

Energy.gov (U.S. Department of Energy (DOE))

Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities.

72

Brush potential curve tracer  

DOE Patents (OSTI)

A device for analyzing commutating characteristics of a motor or generator includes a holder for supporting a plurality of probes adjacent a brush of the motor or generator. Measurements of electrical current characteristics in each of the probes provides information useful in analyzing operation of the machine. Methods for employing a device in accordance with the invention are also disclosed.

Finch, Hilvan A. (Schenectady, NY)

1987-01-01T23:59:59.000Z

73

Brush potential curve tracer  

DOE Patents (OSTI)

A device for analyzing commutating characteristics of a motor or generator includes a holder for supporting a plurality of probes adjacent a brush of the motor or generator. Measurements of electrical current characteristics of the probes provides information useful in analyzing operation of the machine. Methods for employing a device in accordance with the invention are also disclosed.

Finch, H.A.

1985-06-21T23:59:59.000Z

74

Hydrological Tracers Using Nanobiotechnology: Proof of Concept  

Science Journals Connector (OSTI)

This new tracer is composed of polylactic acid (PLA) microspheres into which short strands of synthetic DNA and paramagnetic iron oxide nanoparticles are incorporated. ... The synthetic DNA serves as the label or tag in our tracers that allow us to distinguish one tracer from another, and paramagnetic iron oxide nanoparticles are included in the tracer to facilitate magnetic concentration of the tracers in potentially dilute water samples. ... Mahler et al.(30) attached synthetic DNA strands to silica and montmorillonite clay and measured the DNA concentration on the particles and in the supernatant over a three week period. ...

Asha N. Sharma; Dan Luo; M. Todd Walter

2012-07-25T23:59:59.000Z

75

New particle transport diagnostics with tracer-encapsulated solid pellet  

Science Journals Connector (OSTI)

A new diagnostic method for local particle transport, which is based on injection of the tracer-encapsulated solid pellet (TESPEL), was applied for the first time in experiments on the CHS device. Such a configuration of the pellet allows the lithium hydride tracer to reach the core plasma region and be deposited within a few centimetres in the radial direction, which was confirmed by measurements with photomultipliers and CCD imaging. The radial diffusion of the fully ionized tracer is observed by means of charge exchange recombination spectroscopy with the heating neutral beam as a source. The local tracer deposition and complete ionization of the tracer greatly simplify the transport analysis and allow the use of analytic expressions for deriving the diffusion coefficient, D. With this procedure, the diffusion coefficient was determined for various plasma conditions and was found to be larger for discharges with higher electron temperature. An impurity transport code was also applied to the experimental data, which allowed more precise calculation of the transport coefficients including the pinch velocity, V. It is expected that a higher accuracy will be achieved for the case of TESPEL injection into a larger-scale plasma.

K Khlopenkov; S Sudo

2001-01-01T23:59:59.000Z

76

Reactive Power Compensator.  

DOE Patents (OSTI)

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation. 26 figs.

El-Sharkawi, M.A.; Venkata, S.S.; Chen, M.; Andexler, G.; Huang, T.

1992-07-28T23:59:59.000Z

77

Reactive power compensator  

DOE Patents (OSTI)

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation.

El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Woodinville, WA); Chen, Mingliang (Kirkland, WA); Andexler, George (Everett, WA); Huang, Tony (Seattle, WA)

1992-01-01T23:59:59.000Z

78

Fuel Temperature Coefficient of Reactivity  

SciTech Connect

A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

Loewe, W.E.

2001-07-31T23:59:59.000Z

79

Pore-scale simulation of coupled reactive transport and dissolution in fractures and porous media using the level set interface tracking method  

SciTech Connect

A level set simulation methodology developed for modeling coupled reactive transport and structure evolution has been applied to dissolution in fracture apertures and porous media. The coupled processes such as fluid flow, reactant transport and dissolution at the solid-liquid interfaces are handled simultaneously. The reaction-induced evolution of solid-liquid interfaces is captured using the level set method, with the advantage of representing the interface with sub-grid scale resolution. The coupled processes are simulated for several geometric models of fractures and porous media under various flow conditions and reaction rates. Quantitative relationships between permeability and porosity are obtained from some of the simulation results and compared with analytical constitutive relations (i.e., the conventional cubic law and the Carman-Kozeny law) based on simplified pore space geometries and reaction induced geometric evolutions. The drastic deviation of the simulation results from these analytical theories is explained by the development of large local concentration gradients of reactants within fracture apertures and individual pores observed in the simulation results and consequently the complex geometric evolution patterns of fracture apertures and pores due to mineral dissolution. The simulation results support the argument that traditional constitutive relations based on simplified geometries and conditions have limited applicability in predicting field scale reactive transport and that incorporation of micro-scale physics is necessary.

Hai Huang; Xiaoyi Li

2011-01-01T23:59:59.000Z

80

Reactivity monitoring using the area method for the subcritic al VENUS-F core within the framework of the FREYA Project  

E-Print Network (OSTI)

Accelerator-Driven Systems (ADS) could be employed to incinerate minor actinides and so partly contribute to answer the problem of nuclear waste management. An ADS consists of the coupling of a subcritical fast reactor to a particle accelerator via a heavy material spallation target. The on-line reactivity monitoring of such an ADS is a serious issue regarding its safety. In order to study the methodology of this monitoring, zero-power experimentswere undertaken at the GUINEVERE facility within the framework of the FP6-IP-EUROTRANS programme. Such experiments have been under completion within the FREYA FP7 project. The GUINEVERE facility is hosted at the SCK-CEN site in Mol (Belgium). It couples the VENUS-F subcritical fast core with the GENEPI-3C accelerator. The latter delivers a beam of deuterons, which are converted into 14-MeV neutrons via fusion reactions on a tritiated target. This paper presents one of the investigated methods for ADS on-line reactivity monitoring which has to be validated in the prog...

Marie, N; Lecouey, J L; Billebaud, A; Chabod, S; Doligez, X; Lecolley, F R; Kochetkov, A; Uyttenhove, W; Vittiglio, G; Wagemans, J; Mellier, F; Ban, G; Thybault, H E; Villamarin, D

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Simulation of single well tracer tests for surfactantpolymer flooding  

Science Journals Connector (OSTI)

A single well tracer test (SWTT) is a method to investigate the residual oil saturation near the wellbore. It presents an important tool to evaluate enhanced oil recovery (EOR) processes. For EOR evaluation, ...

Peter X. Bu; Abdulkareem M. AlSofi; Jim Liu

2014-10-01T23:59:59.000Z

82

Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain Site Characterization Study; Progress report, January 1, 1991--June 30, 1991  

SciTech Connect

Studies continue on the use of organic acids as tracers in hydrology studies of Yucca Mountain. Work performed during this time period has been concentrated in three main areas: the familiarization with, and optimization of, the LC-MS hardware and data system; the initial development of soil column test procedures, which are used for evaluation of both the columns themselves and the tracer compounds; and continuation of the batch sorption and degradation studies for the potential tracers. All three of these tasks will continue, as the addition of new tracer compounds, analytical information, and equipment will necessitate further evaluation of existing methods and procedures. Also included in this report is the final report on an information system.

Stetzenbach, K.J.

1991-12-31T23:59:59.000Z

83

RCUT: A Non-Invasive Method for Detection, Location, and Quantification of Radiological Contaminants in Pipes and Ducts - 12514  

SciTech Connect

Radiological Characterization Using Tracers (RCUT) is a minimally invasive method for detection and location of residual radiological contamination in pipes and ducts. The RCUT technology utilizes reactive gaseous tracers that dissociate when exposed to gamma and/or beta radiation emitting from a radiological contaminant in a pipe or duct. Sulfur hexafluoride (SF{sub 6}) was selected as a tracer for this radiological application, because it is a chemically inert gas that is both nonflammable, nontoxic, and breaks down when exposed to gamma radiation. Laboratory tests demonstrated that the tracer pair of SF{sub 6} and O{sub 2} formed SO{sub 2}F{sub 2} when exposed to a gamma or beta radioactive field, which indicated the presence of radiological contamination. Field application of RCUT involves first injecting the reactive tracers into the pipe to fill the pipe being inspected and allowing sufficient time for the tracer to interact with any contaminants present. This is followed by the injection of an inert gas at one end of the pipe to push the reactive tracer at a known or constant flow velocity along the pipe and then out the exit and sampling port at the end of the pipeline where its concentration is measured by a gas chromatograph. If a radiological contaminant is present in the pipe being tested, the presence of SO{sub 2}F{sub 2} will be detected. The time of arrival of the SO{sub 2}F{sub 2} can be used to locate the contaminant. If the pipe is free of radiological contamination, no SO{sub 2}F{sub 2} will be detected. RCUT and PCUT are both effective technologies that can be used to detect contamination within pipelines without the need for mechanical or human inspection. These methods can be used to detect, locate, and/or estimate the volume of a variety of radioactive materials and hazardous chemicals such as chlorinated solvents, petroleum products, and heavy metals. While further optimization is needed for RCUT, the key first step of identification of a tracer compound appropriate for the application of detecting radioactive pipeline contamination through the detection of decomposition products of SF{sub 6} has been demonstrated. Other tracer gases that will also undergo radiolysis will be considered in the future. The next step for the RCUT development process is conducting laboratory scale tests using short pipelines to define analytical requirements, establish performance boundaries, and develop strategies for lower exposure levels. Studies to identify additional analytical techniques using equipment that is more field rugged than a GC/MS would also be beneficial. (authors)

Bratton, Wesley L.; Maresca, Joseph W. Jr.; Beck, Deborah A. [Vista Engineering Technologies, L.L.C., Richland, WA, 99352 (United States)

2012-07-01T23:59:59.000Z

84

Effect of room air recirculation delay on the decay rate of tracer gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of room air recirculation delay on the decay rate of tracer gas Effect of room air recirculation delay on the decay rate of tracer gas concentration Title Effect of room air recirculation delay on the decay rate of tracer gas concentration Publication Type Journal Article Year of Publication 2007 Authors Lorenzetti, David M., Astrid H. Kristoffersen, and Ashok J. Gadgil Journal Indoor Air Pagination 7 Keywords recirculating ventilation, tracer decay rate Abstract Tracer gas measurements are used to estimate the flow rate of fresh air into a room or building. These methods commonly account for the decay of tracer gas concentration as the result of ventilation air supply and infiltration, using a well-mixed model of the space. Some researchers also have considered the effect of leakage in the ventilation ductwork. This paper considers the effect of recirculation through ventilation ducts on the calculated fresh air supply rate. Transport delay in the ducts can significantly alter the time evolution of tracer concentration, and hence alter the estimated air change rate.

85

Effect of room air recirculation delay on the decay rate of tracer gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of room air recirculation delay on the decay rate of tracer gas Effect of room air recirculation delay on the decay rate of tracer gas Title Effect of room air recirculation delay on the decay rate of tracer gas Publication Type Conference Proceedings Year of Publication 2004 Authors Kristoffersen, Astrid H., Ashok J. Gadgil, and David M. Lorenzetti Conference Name 9th International Conference on Air Distribution in Rooms - RoomVent 2004, Pagination pp 6 Date Published September 5-8, 2 Conference Location Coimbra, Portugal Abstract Tracer gas measurements are commonly used to estimate the fresh air exchange rate in a room or building. Published tracer decay methods account for fresh air supply, infiltration, and leaks in ductwork. However, the time delay associated with a ventilation system recirculating tracer back to the room also affects the decay rate. We present an analytical study of tracer gas decay in a well-mixed, mechanically-ventilated room with recirculation. The analysis shows that failing to account for delays can lead to under- or over-estimates of the fresh air supply, depending on whether the decay rate calculation includes the duct volume

86

Reactive Air Aluminization  

SciTech Connect

Ferritic stainless steels and other alloys are of great interest to SOFC developers for applications such as interconnects, cell frames, and balance of plant components. While these alloys offer significant advantages (e.g., low material and manufacturing cost, high thermal conductivity, and high temperature oxidation resistance), there are challenges which can hinder their utilization in SOFC systems; these challenges include Cr volatility and reactivity with glass seals. To overcome these challenges, protective coatings and surface treatments for the alloys are under development. In particular, aluminization of alloy surfaces offers the potential for mitigating both evaporation of Cr from the alloy surface and reaction of alloy constituents with glass seals. Commercial aluminization processes are available to SOFC developers, but they tend to be costly due to their use of exotic raw materials and/or processing conditions. As an alternative, PNNL has developed Reactive Air Aluminization (RAA), which offers a low-cost, simpler alternative to conventional aluminization methods.

Choi, Jung-Pyung; Chou, Y. S.; Stevenson, Jeffry W.

2011-10-28T23:59:59.000Z

87

Chelated Indium Activable Tracers for Geothermal Reservoirs  

E-Print Network (OSTI)

SGP-TR-99 Chelated Indium Activable Tracers for Geothermal Reservoirs Constantinos V. Chrysikopoulos Paul Kruger June 1986 Financial support was provided through the Stanford Geothermal Program under University Stanford Geothermal Program Interdisciplinary Research in Engineering and Earth Sciences STANFORD

Stanford University

88

An investigation of radial tracer flow in naturally fractured reservoirs  

SciTech Connect

This study presents a general solution for the radial flow of tracers in naturally fractured reservoirs. Continuous and finite step injection of chemical and radioactive tracers are considered. The reservoir is treated as being composed of two regions: a mobile region where longitudinal dispersion and convection take place and a stagnant region where only diffusion and adsorption are allowed. Radioactive decay is considered in both regions. The model of this study is thoroughly compared to those previously presented in literature by Moench and Ogata, Tang et al., Chen et al., and Hsieh et al. The solution is numerically inverted by means of the Crump algorithm. A detailed validation of the model with respect to solutions previously presented and/or simplified physical conditions solutions (i.e., homogeneous case) or limit solutions (i.e., for short times) was carried out. The influence of various dimensionless parameters that enter into the solution was investigated. A discussion of results obtained through the Crump and Stehfest algorithm is presented, concluding that the Crump method provides more reliable tracer concentrations.

Jetzabeth, Ramirez-Sabag; Fernando, Samaniego V.; Jesus, Rivera R.; Fernando Rodriguez

1991-01-01T23:59:59.000Z

89

Thermal Stability of Chelated Indium Activable Tracers  

SciTech Connect

The thermal stability of indium tracer chelated with organic ligands ethylenediaminetetraacetic acid (EDTA) and nitrilotriacetic acid (NTA) was measured for reservoir temperatures of 150, 200, and 240 C. Measurements of the soluble indium concentration was made as a function of time by neutron activation analysis. From the data, approximate thermal decomposition rates were estimated. At 150 C, both chelated tracers were stable over the experimental period of 20 days. At 200 C, the InEDTA concentration remained constant for 16 days, after which the thermal decomposition occurred at a measured rate constant of k = 0.09 d{sup -1}. The thermal decomposition of InNTA at 200 C showed a first order reaction with a measured rate constant of k = 0.16 d{sup -1}. At 240 C, both indium chelated tracers showed rapid decomposition with rate constants greater than 1.8 d{sup -1}. The data indicate that for geothermal reservoir with temperatures up to about 200 C, indium chelated tracers can be used effectively for transit times of at least 20 days. These experiments were run without reservoir rock media, and do not account for concomitant loss of indium tracer by adsorption processes.

Chrysikopoulos, Costas; Kruger, Paul

1986-01-21T23:59:59.000Z

90

Consideration of spatial effects in reactivity measurements  

SciTech Connect

Various methods of considering spatial effects in reactivity measurements are presented. These methods are employed both at the critical (mainly fast-neutron) facilities and at the BN-600 reactor.

Matveenko, I. P., E-mail: matveenko@ippe.ru; Lititskii, V. A.; Shokod'ko, A. G. [Institute of Physics and Power Engineering (Russian Federation)

2010-12-15T23:59:59.000Z

91

Geologic flow characterization using tracer techniques  

SciTech Connect

A new tracer flow-test system has been developed for in situ characterization of geologic formations. This report describes two sets of test equipment: one portable and one for testing in deep formations. Equations are derived for in situ detector calibration, raw data reduction, and flow logging. Data analysis techniques are presented for computing porosity and permeability in unconfined isotropic media, and porosity, permeability and fracture characteristics in media with confined or unconfined two-dimensional flow. The effects of tracer pulse spreading due to divergence, dispersion, and porous formations are also included.

Klett, R. D.; Tyner, C. E.; Hertel, Jr., E. S.

1981-04-01T23:59:59.000Z

92

The Proton Transfer Reaction-Mass Spectrometer for Atmospheric Chemistry Tracers of Diesel Exhaust Emissions and Measurements of Trace gas and Aerosol properties.  

E-Print Network (OSTI)

The Proton Transfer Reaction-Mass Spectrometer for Atmospheric Chemistry Tracers of Diesel Exhaust exhaust experiment It has previously been difficult to identify the emissions of diesel exhaust until reactive with organic compounds such as alkanes which are present in diesel exhaust emissions. The reaction

Collins, Gary S.

93

Tracer Testing At Coso Geothermal Area (2006) | Open Energy Information  

Open Energy Info (EERE)

Tracer Testing At Coso Geothermal Area (2006) Tracer Testing At Coso Geothermal Area (2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Tracer Testing At Coso Geothermal Area (2006) Exploration Activity Details Location Coso Geothermal Area Exploration Technique Tracer Testing Activity Date 2006 Usefulness useful DOE-funding Unknown Exploration Basis To characterize the flow patterns of fluid injected into well 68-20RD. Notes A conservative liquid phase tracer, 2-naphthalene sulfonate, and a two-phase tracer, ethanol, were injected into well 68-20RD. Surrounding production wells were sampled over the subsequent 125 days and analyzed for the two tracers. The results demonstrate the efficacy of the simultaneous use of liquid-phase and two-phase tracers in fluid-depleted geothermal

94

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory  

E-Print Network (OSTI)

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory Modifying memory: Selectively enhancing and updating personal memories for a museum; Reactivating personal memory 2 Abstract Memory can be modified when reactivated

Schacter, Daniel

95

Production and acceleration of tracer encapsulated solid pellets for particle transport diagnostics  

Science Journals Connector (OSTI)

A new method for producing a tracer-encapsulated solid pellet (TESPEL) has been developed for a local deposition of the tracer ions in the core plasma and an accurate measurement of the particle transport. The method allows manufacturing of TESPELs in the form of polystyrene shells containing lithium hydride inside as a tracer. The TESPEL acceleration has been successfully performed and photos of the pellets in flight confirmed the TESPEL integrity. For the pellets with diameter 300400 ? m and wall thickness 4050 ? m the pellet fragility becomes insignificant. Calculation of the TESPEL ablation rate has showed that the achieved pellet velocities and sizes are appropriate for the injection into a medium size plasma. It was proposed to fractionate the tracer contents in order to provide better localization of the deposited tracer ions in the plasma. The data obtained in these experiments have proved that injection of the TESPEL made from the plastic shells can be a promising tool for the particle transport diagnostics.

K. V. Khlopenkov; S. Sudo

1998-01-01T23:59:59.000Z

96

Enthalpy and mass flowrate measurements for two-phase geothermal production by Tracer dilution techniques  

SciTech Connect

A new technique has been developed for the measurement of steam mass flowrate, water mass flowrate and total enthalpy of two-phase fluids produced from geothermal wells. The method involves precisely metered injection of liquid and vapor phase tracers into the two-phase production pipeline and concurrent sampling of each phase downstream of the injection point. Subsequent chemical analysis of the steam and water samples for tracer content enables the calculation of mass flowrate for each phase given the known mass injection rates of tracer. This technique has now been used extensively at the Coso geothermal project, owned and operated by California Energy Company. Initial validation of the method was performed at the Roosevelt Hot Springs geothermal project on wells producing to individual production separators equipped with orificeplate flowmeters for each phase.

Hirtz, Paul; Lovekin, Jim; Copp, John; Buck, Cliff; Adams, Mike

1993-01-28T23:59:59.000Z

97

Groundwater well with reactive filter pack  

DOE Patents (OSTI)

A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

1998-01-01T23:59:59.000Z

98

Groundwater well with reactive filter pack  

DOE Patents (OSTI)

A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

1998-09-08T23:59:59.000Z

99

Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate Amino  

Open Energy Info (EERE)

Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate Amino Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate Amino G, and Fluorescein Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate Amino G, and Fluorescein Abstract A series of four tracer tests was recently conducted at the Dixie Valley, Nevada, geothermal reservoir in order to determine fluid-flow processes and to evaluate candidate tracers for use in hydrothermal systems. These tests have resulted in the first successful use of the compounds amino G and pyrenetetrasulfonate as tracers in a geothermal reservoir. The tracer candidates were subjected to simulated hydrothermal conditions in laboratory reactors at temperatures as high as 300°C in order to determine

100

Ca and 87/86 Sr isotopes as tracers of silicate weathering in small  

E-Print Network (OSTI)

44/40 Ca and 87/86 Sr isotopes as tracers of silicate weathering in small catchments of the Massif, Laboratory Division, Orléans, France 2 U.S. Geological Survey, Water Resources Division, Menlo Park, CA 94025).Measurements of 44/40 Ca isotope ratios (44/40 Ca measured by the double spike method on TIMS and normalized

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Method of uranium reclamation from aqueous systems by reactive ion exchange. [US DOE patent application; anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands  

DOE Patents (OSTI)

A reactive ion exchange method for separation and recovery of values of uranium, neptunium, plutonium, or americium from substantially neutral aqueous systems of said metals comprises contacting said system with an effective amount of a basic anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands to achieve nearly 100% sorption of said actinyl ion onto said resin and an aqueous system practically free of said actinyl ions. The method is operational over an extensive range of concentrations from about 10/sup -6/ M to 1.0 M actinyl ion and a pH range of about 4 to 7. The method has particulr application to treatment of waste streams from Purex-type nuclear fuel reprocessing facilities and hydrometallurgical processes involving U, Np, P, or Am.

Maya, L.

1981-11-05T23:59:59.000Z

102

Monitoring Single Molecule Reactivity On a Carbon Nanotube  

E-Print Network (OSTI)

LETTERS Monitoring Single-Molecule Reactivity on a Carbondevice directly transduces single-molecule attachments andoptical methods in single-molecule research. Compared to

Collins, Philip G

2008-01-01T23:59:59.000Z

103

Hydrogeology of the Blautopf spring - Tracer tests in Blauhohle cave |  

Open Energy Info (EERE)

Hydrogeology of the Blautopf spring - Tracer tests in Blauhohle cave Hydrogeology of the Blautopf spring - Tracer tests in Blauhohle cave Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Hydrogeology of the Blautopf spring - Tracer tests in Blauhohle cave Author Andreas Kucha Published Publisher Not Provided, 2012 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Hydrogeology of the Blautopf spring - Tracer tests in Blauhohle cave Citation Andreas Kucha. Hydrogeology of the Blautopf spring - Tracer tests in Blauhohle cave [Internet]. 2012. [cited 2013/10/17]. Available from: http://www.agw.kit.edu/english/blauhoele_cave.php Retrieved from "http://en.openei.org/w/index.php?title=Hydrogeology_of_the_Blautopf_spring_-_Tracer_tests_in_Blauhohle_cave&oldid=688895"

104

Tracer Testing At East Mesa Geothermal Area (1984) | Open Energy...  

Open Energy Info (EERE)

to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Tracer Testing At East Mesa Geothermal Area (1984) Exploration Activity Details Location East Mesa...

105

Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate...  

Open Energy Info (EERE)

to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate Amino G, and Fluorescein...

106

Tracer Testing At Fenton Hill HDR Geothermal Area (Callahan,...  

Open Energy Info (EERE)

to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Tracer Testing At Fenton Hill HDR Geothermal Area (Callahan, 1996) Exploration Activity Details...

107

Using Thermally-Degrading, Partitioning, and Nonreactive Tracers...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Using Thermally-Degrading,...

108

Integrated Approach to Use Natural Chemical and Isotopic Tracers...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems Integrated Approach to Use Natural Chemical and...

109

Using Thermally-Degrading, Partitioning, and Nonreactive Tracers...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Track Name May 19, 2010 This...

110

Use of Tracers to Characterize Fractures in Engineered Geothermal...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fractures in Engineered Geothermal Systems Project Objectives: Measure interwell fracture surface area and fracture spacing using sorbing tracers; measure fracture surface...

111

Quantum Dot Tracers for Use in Engineered Geothermal  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

tracers, colloidal quantum dots, that offer great promise for use in characterizing fracture networks in EGS reservoirs. Since the wavelength of fluorescence (color) of these...

112

Integrated Approach to Use Natural Chemical and Isotopic Tracers...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems B. Mack Kennedy (Presenter) and H. H. Liu Lawrence Berkeley...

113

Tracer Testing At Dixie Valley Geothermal Area (Reed, 2007) ...  

Open Energy Info (EERE)

Nevada, Using Pyrene Tetrasulfonate Amino G, and Fluorescein Peter E. Rose, Stuart D. Johnson, Phaedra Kilbourn (2001) Tracer Testing at Dixie Valley, Nevada, Using 2-Naphthalene...

114

Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics  

Energy.gov (U.S. Department of Energy (DOE))

Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics presentation at the April 2013 peer review meeting held in Denver, Colorado.

115

Using conversions of chemically reacting tracers for numerical determination of temperature profiles in flowing systems and temperature histories in batch systems  

SciTech Connect

This report presents the mathematical bases for measuring internal temperatures within batch and flowing systems using chemically reacting tracers. This approach can obtain temperature profiles of plug-flow systems and temperature histories within batch systems. The differential equations for reactant conversion can be converted into Fredholm integral equations of the first kind. The experimental variable is the tracer-reaction activation energy. When more than one tracer is used, the reactions must have different activation energies to gain information. In systems with temperature extrema, multiple solutions for the temperature profiles or histories can exist, When a single parameter in the temperature distribution is needed, a single-tracer test may furnish this information. For multi-reaction tracer tests, three Fredholm equations are developed. Effects of tracer-reaction activation energy, number of tracers used, and error in the data are evaluated. The methods can determine temperature histories and profiles for many existing systems, and can be a basis for analysis of the more complicated dispersed-flow systems. An alternative to using the Fredholm-equation approach is the use of an assumed temperature- distribution function and incorporation of this function into the basic integral equation describing tracer behavior. The function contains adjustable parameters which are optimized to give the temperature distribution. The iterative Fredholm equation method is tested to see what is required to discriminate between two models of the temperature behavior of Hot Dry Rock (HDR) geothermal reservoirs. Experimentally, ester and amide hydrolyses are valid HDR tracer reactions for measuring temperatures in the range 75-100{degrees}C. Hydrolyses of bromobenzene derivatives are valid HDR tracer reactions for measuring temperatures in the range 150-275{degrees}C.

Brown, L.F.; Chemburkar, R.M.; Robinson, B.A.; Travis, B.J.

1996-04-01T23:59:59.000Z

116

The ATLAS DDM Tracer monitoring framework  

E-Print Network (OSTI)

The DDM Tracer Service is aimed to trace and monitor the atlas file operations on the Worldwide LHC Computing Grid. The volume of traces has increased significantly since the service started in 2009. Now there are about ~5 million trace messages every day and peaks of greater than 250Hz, with peak rates continuing to climb, which gives the current service structure a big challenge. Analysis of large datasets based on on-demand queries to the relational database management system (RDBMS), i.e. Oracle, can be problematic, and have a significant effect on the database's performance. Consequently, We have investigated some new high availability technologies like messaging infrastructure, specifically ActiveMQ, and key-value stores. The advantages of key value store technology are that they are distributed and have high scalability; also their write performances are usually much better than RDBMS, all of which are very useful for the Tracer service. Indexes and distributed counters have been also tested to improve...

ZANG, D; The ATLAS collaboration; BARISITS, M; LASSNIG, M; Andrew STEWART, G; MOLFETAS, A; BEERMANN, T

2012-01-01T23:59:59.000Z

117

Theoretical Investigation of Hydrogen Adsorption and Dissociation on Iron and Iron Carbide Surfaces Using the ReaxFF Reactive Force Field Method  

SciTech Connect

We have developed a ReaxFF reactive force field to describe hydrogen adsorption and dissociation on iron and iron carbide surfaces relevant for simulation of FischerTropsch (FT) synthesis on iron catalysts. This force field enables large system (>>1000 atoms) simulations of hydrogen related reactions with iron. The ReaxFF force field parameters are trained against a substantial amount of structural and energetic data including the equations of state and heats of formation of iron and iron carbide related materials, as well as hydrogen interaction with iron surfaces and different phases of bulk iron. We have validated the accuracy and applicability of ReaxFF force field by carrying out molecular dynamics simulations of hydrogen adsorption, dissociation and recombination on iron and iron carbide surfaces. The barriers and reaction energies for molecular dissociation on these two types of surfaces have been compared and the effect of subsurface carbon on hydrogen interaction with iron surface is evaluated. We found that existence of carbon atoms at subsurface iron sites tends to increase the hydrogen dissociation energy barrier on the surface, and also makes the corresponding hydrogen dissociative state relatively more stable compared to that on bare iron. These properties of iron carbide will affect the dissociation rate of H{sub 2} and will retain more surface hydride species, thus influencing the dynamics of the FT synthesis process.

Zou, Chenyu; van Duin, Adri C.T.; Sorescu, Dan C.

2012-06-01T23:59:59.000Z

118

Use of Tracers to Characterize Fractures in Engineered Geothermal Systems  

Energy.gov (U.S. Department of Energy (DOE))

Project Objectives: Measure interwell fracture surface area and fracture spacing using sorbing tracers; measure fracture surface areas adjacent to a single geothermal well using tracers and injection/backflow techniques; design, fabricate and test a downhole instrument for measuring fracture flow following a hydraulic stimulation experiment.

119

Parallel Finite Element Simulation of Tracer Injection in Oil Reservoirs  

E-Print Network (OSTI)

Parallel Finite Element Simulation of Tracer Injection in Oil Reservoirs Alvaro L.G.A. Coutinho In this work, parallel finite element techniques for the simulation of tracer injection in oil reservoirs. Supercomputers have made it possible to consider global reservoir effects which can not be represented using

Coutinho, Alvaro L. G. A.

120

MIPAS observations of organic tracers for biomass burning and intercontinental transport  

E-Print Network (OSTI)

MIPAS observations of organic tracers for biomass burning and intercontinental transport observations of organic tracers for biomass burning and intercontinental transport Introduction Suite - Oxford - September 2009 #12;MIPAS observations of organic tracers for biomass burning

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Tracer Testing At East Mesa Geothermal Area (1983) | Open Energy  

Open Energy Info (EERE)

Tracer Testing At East Mesa Geothermal Area (1983) Tracer Testing At East Mesa Geothermal Area (1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Tracer Testing At East Mesa Geothermal Area (1983) Exploration Activity Details Location East Mesa Geothermal Area Exploration Technique Tracer Testing Activity Date 1983 Usefulness not indicated DOE-funding Unknown Notes Two field experiments were conducted to develop chemical tracer procedures for use with injection-backflow testing, one on the fracture-permeability Raft River reservoir and the other on the matrix-permeability East Mesa reservoir. Results from tests conducted with incremental increases in the injection volume at both East Mesa and Raft River suggests that, for both reservoirs, permeability remained uniform with increasing distance from the

122

Quantitative determination of collateral anterior olfactory nucleus projections using a fluorescent tracer with an algebraic solution to the problem of double retrograde labeling  

Science Journals Connector (OSTI)

The bilateral projections of the rat anterior olfactory nucleus (AON) were evaluated using retrograde fluorescent tracers. Competitive effects of these tracers led to severe underestimation of bilaterally projecting neurons, when double-labeled cells were counted. The underestimate was corrected using a numerical approach, which is of general utility for problems in double labeling and requires only a single tracer. With this method we estimated that approximately 63% of AON neurons project bilaterally to the olfactory bulbs, except for the external part which projects exclusively to the contralateral olfactory bulb. No other AON neurons project only to the contralateral bulb.

George F. Alheid; Jrn Carlsen; Jose de Olmos; Lennart Heimer

1984-01-01T23:59:59.000Z

123

Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Use of Tracers to Characterize...

124

Surface reactivity and oxygen migration in amorphous indium-gallium-zinc oxide films annealed in humid atmosphere  

SciTech Connect

An isotope tracer study, i.e., {sup 18}O/{sup 16}O exchange using {sup 18}O{sub 2} and H{sub 2}{sup 18}O, was performed to determine how post-deposition annealing (PDA) affected surface reactivity and oxygen diffusivity of amorphous indiumgalliumzinc oxide (a-IGZO) films. The oxygen tracer diffusivity was very high in the bulk even at low temperatures, e.g., 200?C, regardless of PDA and exchange conditions. In contrast, the isotope exchange rate, dominated by surface reactivity, was much lower for {sup 18}O{sub 2} than for H{sub 2}{sup 18}O. PDA in a humid atmosphere at 400?C further suppressed the reactivity of O{sub 2} at the a-IGZO film surface, which is attributable to OH-terminated surface formation.

Watanabe, Ken, E-mail: Watanabe.Ken@nims.go.jp [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan)] [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan); Lee, Dong-Hee [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Sakaguchi, Isao; Haneda, Hajime [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan)] [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Nomura, Kenji [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)] [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Kamiya, Toshio [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Hosono, Hideo [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Ohashi, Naoki, E-mail: Ohashi.Naoki@nims.go.jp [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)

2013-11-11T23:59:59.000Z

125

Oxyferryl Heme Reactivity  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxyferryl Heme Reactivity Using both Radiation and Photochemical Oxyferryl Heme Reactivity Using both Radiation and Photochemical Techniques A. M. English, T. Fox, G. Tsaprailis, C. W. Fenwick, J. F. Wishart, J. T. Hazzard, and G. Tollin Adv. Chem. Ser. 254, Ch. 6, pp. 81-98 Abstract: Flash photolysis and pulse radiolysis were used to generate reductants in situ to study the electron-transfer (ET) reactivity of the FeIV=O heme centers in myoglobin and cytochrome c peroxidase. Reduction of a5RuIII groups covalently bound to surface histidines allowed intramolecular RuII --> FeIV=O ET rates to be measured. Protonation of the oxene ligand was found to be largely rate determining in myoglobin, consistent with the lack of proton donors in its heme pocket. The large distance (21-23 Å) between surface histidines and the heme in wild-type

126

Reactivity of Acid Generators  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactivity of Acid Generators for Chemically Amplified Resists with Reactivity of Acid Generators for Chemically Amplified Resists with Low-Energy Electrons Atsuro Nakano, Takahiro Kozawa, Seiichi Tagawa, Tomasz Szreder, James F. Wishart, Toshiyuki Kai and Tsutomu Shimokawa Jpn. J. Appl. Phys., 45, L197-L200 (2006). [Find paper at the Japanese Journal of Applied Physics] Abstract: In chemically amplified resists for ionizing radiations such as electron beams and extreme ultraviolet (EUV), low-energy electrons play an important role in the pattern formation processes. The reactivity of acid generators with low-energy electrons was evaluated using solvated electrons in tetrahydrofuran, which were generated by a pulsed electron beam. The rate constants of acid generators with the solvated electrons ranged from 0.6 to 1.9 x 1011 M-1s-1

127

Tracer Gas Transport under Mixed Convection Conditions in an Experimental  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracer Gas Transport under Mixed Convection Conditions in an Experimental Tracer Gas Transport under Mixed Convection Conditions in an Experimental Atrium: Comparison Between Experiments and CFD Predictions Title Tracer Gas Transport under Mixed Convection Conditions in an Experimental Atrium: Comparison Between Experiments and CFD Predictions Publication Type Journal Article Year of Publication 2006 Authors Jayaraman, Buvaneswari, Elizabeth U. Finlayson, Michael D. Sohn, Tracy L. Thatcher, Phillip N. Price, Emily E. Wood, Richard G. Sextro, and Ashok J. Gadgil Journal Atmospheric Environment Volume 40 Start Page Chapter Pagination 5236-5250 Keywords airflow and pollutant transport group, atria, indoor airflow and pollutant transport, indoor environment department, indoor pollutant dispersion, mixed convection, turbulence model

128

Reactive Power Compensating System.  

DOE Patents (OSTI)

The circuit was designed for the specific application of wind-driven induction generators. It has great potential for application in any situation where a varying reactive power load is present, such as with induction motors or generators, or for transmission network compensation.

Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

1985-01-04T23:59:59.000Z

129

Reactive power compensating system  

DOE Patents (OSTI)

The reactive power of an induction machine is compensated by providing fixed capacitors on each phase line for the minimum compensation required, sensing the current on one line at the time its voltage crosses zero to determine the actual compensation required for each phase, and selecting switched capacitors on each line to provide the balance of the compensation required.

Williams, Timothy J. (Redondo Beach, CA); El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Seattle, WA)

1987-01-01T23:59:59.000Z

130

Primordial black holes as biased tracers  

E-Print Network (OSTI)

Primordial black holes (PBHs) are theoretical black holes which may be formed during the radiation dominant era and, basically, caused by the gravitational collapse of radiational overdensities. It has been well known that in the context of the structure formation in our Universe such collapsed objects, e.g., halos/galaxies, could be considered as bias tracers of underlying matter fluctuations and the halo/galaxy bias has been studied well. Employing a peak-background split picture which is known to be a useful tool to discuss the halo bias, we consider the large scale clustering behavior of the PBH and propose an almost mass-independent constraint to the scenario that dark matters (DMs) consist of PBHs. We consider the case where the statistics of the primordial curvature perturbations is almost Gaussian, but with small local-type non-Gaussianity. If PBHs account for the DM abundance, such a large scale clustering of PBHs behaves as nothing but the matter isocurvature perturbation and constrained strictly by...

Tada, Yuichiro

2015-01-01T23:59:59.000Z

131

Thermal single-well injection-withdrawal tracer tests for determining fracture-matrix heat transfer area  

SciTech Connect

Single-well injection-withdrawal (SWIW) tracer tests involve injection of traced fluid and subsequent tracer recovery from the same well, usually with some quiescent time between the injection and withdrawal periods. SWIW are insensitive to variations in advective processes that arise from formation heterogeneities, because upon withdrawal, fluid parcels tend to retrace the paths taken during injection. However, SWIW are sensitive to diffusive processes, such as diffusive exchange of conservative or reactive solutes between fractures and rock matrix. This paper focuses on SWIW tests in which temperature itself is used as a tracer. Numerical simulations demonstrate the sensitivity of temperature returns to fracture-matrix interaction. We consider thermal SWIW response to the two primary reservoir improvements targeted with stimulation, (1) making additional fractures accessible to injected fluids, and (2) increasing the aperture and permeability of pre-existing fractures. It is found that temperature returns in SWIW tests are insensitive to (2), while providing a strong signal of more rapid temperature recovery during the withdrawal phase for (1).

Pruess, K.; Doughty, C.

2010-01-15T23:59:59.000Z

132

Tracer Testing At Raft River Geothermal Area (1984) | Open Energy...  

Open Energy Info (EERE)

84 Usefulness not indicated DOE-funding Unknown Notes Tracer testing was undertaken at Raft River geothermal area. References Kroneman, R. L.; Yorgason, K. R.; Moore, J. N. (1...

133

Tracer stirring around a meddy: The formation of layering  

Science Journals Connector (OSTI)

The dynamics of the formation of layering surrounding meddy-like vortex lenses is investigated using Primitive Equation (PE), Quasi Geostrophic (QG) and tracer advection models. Recent in situ data inside a meddy confirmed the formation of highly ...

Thomas Meunier; Claire Mnesguen; Richard Schopp; Sylvie Le Gentil

134

Geographic Information Systems- Tools For Geotherm Exploration, Tracers  

Open Energy Info (EERE)

Systems- Tools For Geotherm Exploration, Tracers Systems- Tools For Geotherm Exploration, Tracers Data Analysis, And Enhanced Data Distribution, Visualization, And Management Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Paper: Geographic Information Systems- Tools For Geotherm Exploration, Tracers Data Analysis, And Enhanced Data Distribution, Visualization, And Management Details Activities (4) Areas (3) Regions (0) Abstract: Geographic information systems (GIS) are an underused resource that can help the geothermal industry in exploration, tracer analysis, infrastructure management, and the general distribution and use of data. GIS systems are highly customizable to specific user needs and can use entire corporate data sets through a visual interface. This paper briefly documents the use of GIS in specific examples of geothermal research at the

135

A semi-experimental nodal synthesis method for the on-line reconstruction of three-dimensional neutron flux-shapes and reactivity  

SciTech Connect

The safety and optimal performance of large, commercial, light-water reactors require the knowledge at all time of the neutron-flux distribution in the core. In principle, this information can be obtained by solving the time-dependent neutron diffusion equations. However, this approach is complicated and very expensive. Sufficiently accurate, real-time calculations (time scale of approximately one second) are not yet possible on desktop computers, even with fast-running, nodal kinetics codes. A semi-experimental, nodal synthesis method which avoids the solution of the time-dependent, neutron diffusion equations is described. The essential idea of this method is to approximate instantaneous nodal group-fluxes by a linear combination of K, precomputed, three-dimensional, static expansion-functions. The time-dependent coefficients of the combination are found from the requirement that the reconstructed flux-distribution agree in a least-squares sense with the readings of J ({ge}K) fixed, prompt-responding neutron-detectors. Possible numerical difficulties with the least-squares solution of the ill-conditioned, J-by-K system of equations are brought under complete control by the use of a singular-value-decomposition technique. This procedure amounts to the rearrangement of the original, linear combination of K expansion functions into an equivalent more convenient, linear combination of R ({le}K) orthogonalized modes'' of decreasing magnitude. Exceedingly small modes are zeroed to eliminate any risk of roundoff-error amplification, and to assure consistency with the limited accuracy of the data. Additional modes are zeroed when it is desirable to limit the sensitivity of the results to measurement noise.

Jacqmin, R.P.

1991-12-10T23:59:59.000Z

136

A semi-experimental nodal synthesis method for the on-line reconstruction of three-dimensional neutron flux-shapes and reactivity. Final report  

SciTech Connect

The safety and optimal performance of large, commercial, light-water reactors require the knowledge at all time of the neutron-flux distribution in the core. In principle, this information can be obtained by solving the time-dependent neutron diffusion equations. However, this approach is complicated and very expensive. Sufficiently accurate, real-time calculations (time scale of approximately one second) are not yet possible on desktop computers, even with fast-running, nodal kinetics codes. A semi-experimental, nodal synthesis method which avoids the solution of the time-dependent, neutron diffusion equations is described. The essential idea of this method is to approximate instantaneous nodal group-fluxes by a linear combination of K, precomputed, three-dimensional, static expansion-functions. The time-dependent coefficients of the combination are found from the requirement that the reconstructed flux-distribution agree in a least-squares sense with the readings of J ({ge}K) fixed, prompt-responding neutron-detectors. Possible numerical difficulties with the least-squares solution of the ill-conditioned, J-by-K system of equations are brought under complete control by the use of a singular-value-decomposition technique. This procedure amounts to the rearrangement of the original, linear combination of K expansion functions into an equivalent more convenient, linear combination of R ({le}K) orthogonalized ``modes`` of decreasing magnitude. Exceedingly small modes are zeroed to eliminate any risk of roundoff-error amplification, and to assure consistency with the limited accuracy of the data. Additional modes are zeroed when it is desirable to limit the sensitivity of the results to measurement noise.

Jacqmin, R.P.

1991-12-10T23:59:59.000Z

137

Resuspension rates from aged inert-tracer sources  

SciTech Connect

Wind-caused particle resuspension rates were investigated with molybdenum tracers at two circular resuspension sites in the Hanford area. The tracer particles were calcium molybdate. The radii of each circular tracer-source area were 22.9 m and 29.9 m respectively for tracer deposited on 2 October 1973 and 29 May 1979. Resuspension rates were investigated by sampling resuspended tracer with air sampling equipment mounted as a function of height on a centrally located sampling tower at each site. Sampling equipment was operated as a function of wind speed increments in order to investigate resuspension rates, wind speed dependencies of resuspension rates, and for subsequent comparisons of resuspension rate changes as a function of time for constant wind speed ranges. Experimental results are reported for measurements over several years. Resuspension rates ranged from about 10/sup -13/ to 10/sup -6/ fraction of the tracer source resuspended per second. Resuspension rates tended to increase with increasing wind speed. At one investigation site, resuspension rates were nearly constant, except for seasonal variations, for a four-year time period. Resuspension rates appear higher in the autumn than in the spring and summer.

Sehmel, G.A.

1982-11-01T23:59:59.000Z

138

Design and synthesis of reactive separation systems  

SciTech Connect

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-01-01T23:59:59.000Z

139

Water reactive hydrogen fuel cell power system  

DOE Patents (OSTI)

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-11-25T23:59:59.000Z

140

Water reactive hydrogen fuel cell power system  

DOE Patents (OSTI)

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-01-21T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


141

HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS  

SciTech Connect

The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

2012-01-01T23:59:59.000Z

142

Reactive Maintenance | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reactive Maintenance Reactive Maintenance Reactive Maintenance October 7, 2013 - 9:40am Addthis Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities. Advantages Reactive maintenance advantages are a double-edged sword. Federal agencies following a purely reactive maintenance strategy can expect little expenditures for manpower or system upkeep until something breaks. However, systems do break. With new equipment, Federal agencies can expect minimal incidents of failure. However, older equipment often experiences higher failure incidents and costlier repairs. Other advantages of reactive maintenance are:

143

Cooperative Strategies and Reactive Search: A Hybrid Model Proposal  

Science Journals Connector (OSTI)

Cooperative strategies and reactive search are very promising techniques for solving hard optimization problems, since they reduce human intervention required to set up a method when the resolution of an unknown instance is needed. However, as far as ...

Antonio D. Masegosa; Franco Mascia; David Pelta; Mauro Brunato

2009-11-01T23:59:59.000Z

144

Tracer Testing At Raft River Geothermal Area (1983) | Open Energy  

Open Energy Info (EERE)

3) 3) Exploration Activity Details Location Raft River Geothermal Area Exploration Technique Tracer Testing Activity Date 1983 Usefulness not indicated DOE-funding Unknown Exploration Basis To develop chemical tracing procedures for geothermal areas. Notes Two field experiments were conducted to develop chemical tracer procedures for use with injection-backflow testing, one on the fracture-permeability Raft River reservoir and the other on the matrix-permeability East Mesa reservoir. Results from tests conducted with incremental increases in the injection volume at both East Mesa and Raft River suggests that, for both reservoirs, permeability remained uniform with increasing distance from the well bore. Increased mixing during quiescent periods, between injection and

145

Preliminary assessment of halogenated alkanes as vapor-phase tracers  

SciTech Connect

New tracers are needed to evaluate the efficiency of injection strategies in vapor-dominated environments. One group of compounds that seems to meet the requirements for vapor-phase tracing are the halogenated alkanes (HCFCs). HCFCs are generally nontoxic, and extrapolation of tabulated thermodynamic data indicate that they will be thermally stable and nonreactive in a geothermal environment. The solubilities and stabilities of these compounds, which form several homologous series, vary according to the substituent ratios of fluorine, chlorine, and hydrogen. Laboratory and field tests that will further define the suitability of HCFCs as vapor-phase tracers are under way.

Adams, Michael C.; Moore, Joseph N.; Hirtz, Paul

1991-01-01T23:59:59.000Z

146

Mined land reclamation by biological reactivation  

SciTech Connect

A mine reclamation technique, developed in Europe, restores land to full productivity within two years without topsoil replacement. The method deliberately reestablishes within one year following mining, the required biological balance between microbes, enzymes, and trace elements in the rock spoil rather than waiting five or more years for natural processes to restore balance. The technique is called Biological Reactivation (BR). This paper discusses the feasibility of BR reclamation after surface mining operations in the US. Staff of the Ohio Mining and Mineral Resources Research Institute completed an OSM-sponsored research project on BR in which physical and chemical tests characterized 140 spoil samples obtained from 10 surface mining operations. Test results indicated that Biological Reactivation technology could be effectively applied, at least in the test areas sampled within Appalachia. Preliminary estimates make clear that the new technique reduces reclamation costs on prime farmland by approximately 95% compared to topsoil segregation and replacement methods.

Gozon, J.S.; Konya, C.J.; Lukovic, S.S.; Lundquist, R.G.; Olah, J.

1982-12-01T23:59:59.000Z

147

Federal Energy Management Program: Reactive Maintenance  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactive Reactive Maintenance to someone by E-mail Share Federal Energy Management Program: Reactive Maintenance on Facebook Tweet about Federal Energy Management Program: Reactive Maintenance on Twitter Bookmark Federal Energy Management Program: Reactive Maintenance on Google Bookmark Federal Energy Management Program: Reactive Maintenance on Delicious Rank Federal Energy Management Program: Reactive Maintenance on Digg Find More places to share Federal Energy Management Program: Reactive Maintenance on AddThis.com... Sustainable Buildings & Campuses Operations & Maintenance Federal Requirements Program Management Commissioning Metering Computerized Maintenance Management Systems Maintenance Types Reactive Preventive Predictive Reliability-Centered Major Equipment Types

148

ANALYSIS OF TRACER AND THERMAL TRANSIENTS DURING REINJECTION  

E-Print Network (OSTI)

and developed a new technique which combines the results from in- terwell tracer tests and thermal injection variables of the injection and backflow periods. Finally we suggested thermal injection-backflow tests for interpreting thermal injection-backflow tests. In fact, the MD model was first developed by Lauwerier to study

Stanford University

149

RADIOGENIC ISOTOPES: TRACERS OF PAST OCEAN CIRCULATION AND EROSIONAL INPUT  

E-Print Network (OSTI)

in the ocean has varied as a function of changes in paleocircu- lation, source provenances, style and intensity-established paleoceano- graphic tracers such as carbon isotopes. INDEX TERMS: 1040 Geochemistry: Isotopic composition Atlantic Deep Water (NADW) according to latest estimates based on results of the World Ocean Circulation

Jellinek, Mark

150

DIVISION S-3-NOTES HYDROLOGIC TRACER EFFECTS ON SOIL  

E-Print Network (OSTI)

and denitrification (the conversion of NOf to N gas)can be important to the fate of NOf and organic pollutants on microbial activity. These effects could be important whentracers areused instudies of the fate and transport of pollutants in the environment. In such studies, it is important to determine if tracer compounds affect

Gold, Art

151

Calibration of hydraulic and tracer tests in fractured media  

E-Print Network (OSTI)

Calibration of hydraulic and tracer tests in fractured media represented by a DFN Model L. D. Donado, X. Sanchez-Vila, E. Ruiz* & F. J. Elorza** * Enviros Spain S.L. ** UPM #12;Fractured Media Water flows through fractures (matrix basically impervious ­ though relevant to transport) Fractures at all

Politècnica de Catalunya, Universitat

152

Partitioning and Interfacial Tracers for Differentiating NAPL Entrapment Configuration:? Column-Scale Investigation  

Science Journals Connector (OSTI)

Partitioning and Interfacial Tracers for Differentiating NAPL Entrapment Configuration:? Column-Scale Investigation ... In field investigations, such as partitioning interwell tracer tests (PITTs), tracers are deployed before and after cleanup implementation to assess remedial performance (13, 26?28). ... The use of 222Rn, a naturally occurring radioactive isotope, was investigated as a partitioning tracer to detect and quantify the amt. of non-aq.-phase ...

Dongping Dai; Frank T. Barranco Jr.; Tissa H. Illangasekare

2001-11-17T23:59:59.000Z

153

Metal-based reactive nanomaterials  

Science Journals Connector (OSTI)

Recent developments in materials processing and characterization resulted in the discovery of a new type of reactive materials containing nanoscaled metal components. The well-known high oxidation energies of metallic fuels can now be released very rapidly because of the very high reactive interface areas in such metal-based reactive nanomaterials. Consequently, these materials are currently being examined for an entire range of applications in energetic formulations inappropriate for conventional, micron-sized metal fuels having relatively low reaction rates. New application areas, such as reactive structural materials, are also being explored. Research remains active in manufacturing and characterization of metal-based reactive nanomaterials including elemental metal nanopowders and various nanocomposite material systems. Because of the nanometer scale of the individual particles, or phase domains, and because of the very high enthalpy of reaction between components of the nanocomposite materials, the final phase compositions, morphology, and thermodynamic properties of the reactive nanocomposite materials may be different from those of their micron-scaled counterparts. Ignition mechanisms in such materials can be governed by heterogeneous reactions that are insignificant for materials with less developed reactive interface areas. New combustion regimes are being observed that are affected by very short ignition delays combined with very high metal combustion temperatures. Current progress in this rapidly growing research area is reviewed and some potential directions for the future research are discussed.

Edward L. Dreizin

2009-01-01T23:59:59.000Z

154

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

155

Chemically Reactive Working Fluids | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chemically Reactive Working Fluids for the Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Chemically Reactive Working Fluids SunShot CSP...

156

Formation, characterization and reactivity of adsorbed oxygen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

157

Conservation of reactive electromagnetic energy in reactive time  

E-Print Network (OSTI)

The complex Poynting theorem (CPT) is extended to a canonical time-scale domain $(t,s)$. Time-harmonic phasors are replaced by the positive-frequency parts of general fields, which extend analytically to complex time $t+is$, with $s>0$ interpreted as a time resolution scale. The real part of the extended CPT gives conservation in $t$ of a time-averaged field energy, and its imaginary part gives conservation in $s$ of a time-averaged reactive energy. In both cases, the averaging windows are determined by a Cauchy kernel of width $\\Delta t\\sim \\pm s$. This completes the time-harmonic CPT, whose imaginary part is generally supposed to be vaguely `related to' reactive energy without giving a conservation law, or even an expression, for the latter. The interpretation of $s$ as reactive time, tracking the leads and lags associated with stored capacitative and inductive energy, gives a simple explanation of the volt-ampere reactive (var) unit measuring reactive power: a var is simply one Joule per reactive second. T...

Kaiser, Gerald

2015-01-01T23:59:59.000Z

158

Tracer Studies on F-Actin Fluctuations  

Science Journals Connector (OSTI)

We present a study on the fluctuations of semiflexible actin filaments using fluorescence videomicroscopy, focusing on the end-to-end fluctuations of single filaments. In order to specifically measure the position of the polymers ends, we developed a novel noninvasive method that consists of annealing short end tags to the filaments. This allows us to probe polymer fluctuations to a very high accuracy. We compared the distribution of the end-to-end distance with recent theoretical results, and found excellent agreement. We also studied the dynamics of the mean-square end-to-end distance ?R2(t) and orientation of the ends, ??2(t), finding power laws t3/4 and t1/4, respectively. Scaling behavior for ?R2(t) is observed over several decades in relaxation time in agreement with theoretical results.

Loc Le Goff; Oskar Hallatschek; Erwin Frey; Franois Amblard

2002-12-03T23:59:59.000Z

159

Conductivity tracer studies for a fluidized-bed bioreactor  

SciTech Connect

An automated conductivity tracer test was developed to measure the residence time distribution (RTD) of a cometabolic fluidized-bed bioreactor (FBBR). The FBBR contained sand-core bioparticles grown with phenol and it provided high (70% to 80%) removal of trichloroethene (TCE) at short (3 minute) detention times. The tracer test apparatus was constructed with off-the-shelf components controlled with a PC-based data acquisition system. Non-disruptive hydrodynamic testing was obtained during normal operation of the FBBR. The conductivity of injected brine pulses was monitored at the reactor inlet and outlet. Dispersion numbers and detention times were computed by fitting the advection-dispersion model to the tracer curves. Typical dispersion numbers attributed to the fluidized-bed of bioparticles ranged from 0.07 to 0.11. In simplified modeling of the FBBR, dispersion was found to have little effect on TCE removal. Based on the dispersion of brine pulses, it was determined that phenol feed pulses injected at inhibitory concentrations over 2 g/L would be rapidly dispersed in the biological bed to non-inhibitory concentrations.

Leung, S.Y.; Segar, R.L. Jr. [Univ. of Missouri, Columbia, MO (United States). Dept. of Civil Engineering

1997-12-31T23:59:59.000Z

160

Tracer-encapsulated cryogenic pellet production for particle transport diagnostics  

Science Journals Connector (OSTI)

A device for producing a tracer-encapsulated cryogenic pellet is constructed for an accurate transport diagnostic system to measure particle transport both parallel and perpendicular to the magnetic-field lines in magnetic confinementdevices. As for the typical configuration of the tracer-encapsulated pellet it is proposed that a 50250 ?m diam tracer made of a light atom such as lithium carbon etc. is encapsulated in the center of a 13 mm diam cylindrical pellet of hydrogen. For demonstration of the device operation a 240 ?m diam carbon sphere is encapsulated in the center of a 3 mm diam cylindrical pellet of hydrogen and accelerated by a light gas gun to velocities of 400800 m/s in a test chamber. The pellet has been photographed simultaneously from two directions and the two two-dimensional images are reconstructed to a three-dimensional image. Thus the proof of principle of the device operation has been demonstrated.

S. Sudo; H. Itoh; K. Khlopenkov

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Monitoring of saline tracer movement with vertically distributed self-potential measurements at the HOBE agricultural test site, Voulund, Denmark  

E-Print Network (OSTI)

The self-potential (SP) method is sensitive to water fluxes in saturated and partially saturated porous media, such as those associated with rainwater infiltration and groundwater recharge. We present a field-based study at the Voulund agricultural test site, Denmark, that is, to the best of our knowledge, the first to focus on the vertical self-potential distribution prior to and during a saline tracer test. A coupled hydrogeophysical modeling framework is used to simulate the SP response to precipitation and saline tracer infiltration. A layered hydrological model is first obtained by inverting dielectric and matric potential data. The resulting model that compares favorably with electrical resistance tomography models is subsequently used to predict the SP response. The electrokinetic contribution (caused by water fluxes in a charged porous soil) is modeled by an effective excess charge approach that considers both water saturation and pore water salinity. Our results suggest that the effective excess char...

Jougnot, Damien; Haarder, Eline B; Looms, Majken C

2015-01-01T23:59:59.000Z

162

Core follow calculation with the nTRACER numerical reactor and verification using power reactor measurement data  

SciTech Connect

The nTRACER direct whole core transport code employing the planar MOC solution based 3-D calculation method, the subgroup method for resonance treatment, the Krylov matrix exponential method for depletion, and a subchannel thermal/hydraulic calculation solver was developed for practical high-fidelity simulation of power reactors. Its accuracy and performance is verified by comparing with the measurement data obtained for three pressurized water reactor cores. It is demonstrated that accurate and detailed multi-physic simulation of power reactors is practically realizable without any prior calculations or adjustments. (authors)

Jung, Y. S.; Joo, H. G. [Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul (Korea, Republic of); Yoon, J. I. [KEPCO Nuclear Fuel, 1047 Daedukdae-ro, Yuseong-gu, Daejeon (Korea, Republic of)

2013-07-01T23:59:59.000Z

163

JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1029/, What is the skill of ocean tracers in reducing uncertainties  

E-Print Network (OSTI)

in current Earth system models and (ii) imperfect knowledge of model parameters. Ocean tracers observa- tions

Haran, Murali

164

Mixing properties in the advection of passive tracers via recurrences and extreme value theory  

E-Print Network (OSTI)

In this paper we characterize the mixing properties in the advection of passive tracers by exploiting the extreme value theory for dynamical systems. With respect to classical techniques directly related to the Poincar\\'e recurrences analysis, our method provides reliable estimations of the characteristic mixing times and distinguishes between barriers and unstable fixed points. The method is based on a check of convergence for extreme value laws on finite datasets. We define the mixing times in terms of the shortest time intervals such that extremes converge to the asymptotic (known) parameters of the Generalized Extreme Value distribution. Our technique is suitable for applications in the analysis of other systems where mixing time scales need to be determined and limited datasets are available.

Davide Faranda; Xavier Leoncini; Sandro Vaienti

2014-02-16T23:59:59.000Z

165

Mechanical models of fracture reactivation and slip on bedding surfaces during folding of the asymmetric anticline at Sheep Mountain, Wyoming  

E-Print Network (OSTI)

Mechanical models of fracture reactivation and slip on bedding surfaces during folding June 2008 Accepted 5 June 2008 Available online 13 June 2008 Keywords: Fold Fracture reactivation Bed methods to investigate the reactivation of fractures (opening and shearing) and the development of bedding

Borja, Ronaldo I.

166

Reactivity of surface carbon deposited on supported Rh catalysts by the disproportionation of CO  

SciTech Connect

Recent investigations on hydrocarbon synthesis from CO and H/sub 2/ over Group VIII metals have proposed that the surface carbon formed by the dissociation of CO is an intermediate for hydrocarbon formation. It implies that metals which dissociate CO readily (e.g., Ni, Co, and Ru) are good catalysts for hydrocarbon synthesis unless the surface carbon is bound too strongly. There is a certain controversy in the literature on whether CO undergoes dissociation on Rh surfaces under UHV conditions. In the present work, the authors have investigated the reactivity of surface carbon deposited on TiO/sub 2/- or SiO/sub 2/-supported Rh catalysts in the presence of molecularly adsorbed CO by means of the isotopic tracer technique and have made a direct comparison of the reactivity of adsorbed CO with that of surface carbon. It has been revealed that three forms of carbon are produced by the disproportionation of CO.

Orita, H.; Naito, S.; Tamaru, K.

1988-06-01T23:59:59.000Z

167

Reactive decontamination formulation  

DOE Patents (OSTI)

The present invention provides a universal decontamination formulation and method for detoxifying chemical warfare agents (CWA's) and biological warfare agents (BWA's) without producing any toxic by-products, as well as, decontaminating surfaces that have come into contact with these agents. The formulation includes a sorbent material or gel, a peroxide source, a peroxide activator, and a compound containing a mixture of KHSO.sub.5, KHSO.sub.4 and K.sub.2 SO.sub.4. The formulation is self-decontaminating and once dried can easily be wiped from the surface being decontaminated. A method for decontaminating a surface exposed to chemical or biological agents is also disclosed.

Giletto, Anthony (College Station, TX); White, William (College Station, TX); Cisar, Alan J. (Cypress, TX); Hitchens, G. Duncan (Bryan, TX); Fyffe, James (Bryan, TX)

2003-05-27T23:59:59.000Z

168

Cellular-automaton model for reactive systems  

Science Journals Connector (OSTI)

A method for constructing a variety of probabilistic lattice-gas cellular automata for chemically reacting systems is described. The microscopic reactive dynamics give rise to a general fourth-order polynomial rate law for the average particle density. The reduction of the microdynamical equations to a discrete or continuous Boltzmann equation is presented. Connection between the linearized Boltzmann equations and a reaction-diffusion macroscopic equation is discussed. As an example of the general formalism a set of cellular automata rules that yield the Schlgl phenomenological model is constructed. Simulation results are presented.

David Dab; Anna Lawniczak; Jean-Pierre Boon; Raymond Kapral

1990-05-14T23:59:59.000Z

169

IAEA sodium void reactivity benchmark calculations  

SciTech Connect

In this paper, the IAEA-1 992 ``Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core`` problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-12-01T23:59:59.000Z

170

IAEA sodium void reactivity benchmark calculations  

SciTech Connect

In this paper, the IAEA-1 992 Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core'' problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-01-01T23:59:59.000Z

171

Interpretation of Colloid-Homologue Tracer Test 10-03, Including Comparisons to Test 10-01  

SciTech Connect

This presentation covers the interpretations of colloid-homologue tracer test 10-03 conducted at the Grimsel Test Site, Switzerland, in 2010. It also provides a comparison of the interpreted test results with those of tracer test 10-01, which was conducted in the same fracture flow system and using the same tracers than test 10-03, but at a higher extraction flow rate. A method of correcting for apparent uranine degradation in test 10-03 is presented. Conclusions are: (1) Uranine degradation occurred in test 10-03, but not in 10-01; (2) Uranine correction based on apparent degradation rate in injection loop in test 11-02 seems reasonable when applied to data from test 10-03; (3) Colloid breakthrough curves quite similar in the two tests with similar recoveries relative to uranine (after correction); and (4) Much slower apparent desorption of homologues in test 10-03 than in 10-01 (any effect of residual homologues from test 10-01 in test 10-03?).

Reimus, Paul W. [Los Alamos National Laboratory

2012-06-26T23:59:59.000Z

172

Wear Measurement of Highly Cross-linked UHMWPE using a 7Be Tracer Implantation Technique  

SciTech Connect

The very low wear rates achieved with the current highly cross-linked ultrahigh molecular weight polyethylenes (UHMWPE) used in joint prostheses have proven to be difficult to measure accurately by gravimetry. Tracer methods are there- fore being explored. The purpose of this study was to perform a proof-of-concept experiment on the use of the radioactive tracer beryllium-7 (7Be) for the determination of in vitro wear in a highly cross-linked orthopedic UHMWPE. Three cross-linked and four conventional UHMWPE pins made from compression- molded GUR 1050, were activated with 109 to 1010 7Be nuclei using a new implantation setup that produced a homogenous distribution of implanted nuclei up to 8.5 lm below the surface. The pins were tested for wear in a six-station pin-on-flat appara- tus for up to 7.1 million cycles (178 km). A Germanium gamma detector was employed to determine activity loss of the UHMWPE pins at preset intervals during the wear test. The wear of the cross-linked UHMWPE pins was readily detected and esti- mated to be 17 6 3 lg per million cycles. The conventional-to- cross-linked ratio of the wear rates was 13.1 6 0.8, in the expected range for these materials. Oxidative degradation dam- age from implantation was negligible; however, a weak depend- ence of wear on implantation dose was observed limiting the number of radioactive tracer atoms that can be introduced. Future applications of this tracer technology may include the analysis of location-specific wear, such as loss of material in the post or backside of a tibial insert.

Wimmer, Markus A. [Rush Uniiv. Medical Center; Laurent, Michael P. [Rush Univ. Medical Center; Dwivedi, Yasha [Rush Univ. Medical Center; Gallardo, Luis A. [Rush Univ. Medical Center; Chipps, K. [Colorado School of Mines, Golden; Blackmon, Jeffery C [Louisiana State University; Kozub, R. L. [Tennessee Technological University; Bardayan, Daniel W [ORNL; Gross, Carl J [ORNL; Stracener, Daniel W [ORNL; Smith, Michael Scott [ORNL; Nesaraja, Caroline D [ORNL; Erikson, Luke [Colorado School of Mines, Golden; Patel, Nidhi [Colorado School of Mines, Golden; Rehm, Karl E. [Argonne National Laboratory (ANL); Ahmad, Irshad [Argonne National Laboratory (ANL); Greene, John P. [Argonne National Laboratory (ANL); Greife, Uwe [Colorado School of Mines, Golden

2013-01-01T23:59:59.000Z

173

Tracer Recovery and Mixing from Two Geothermal Injection-Backflow Studies |  

Open Energy Info (EERE)

Tracer Recovery and Mixing from Two Geothermal Injection-Backflow Studies Tracer Recovery and Mixing from Two Geothermal Injection-Backflow Studies Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: Tracer Recovery and Mixing from Two Geothermal Injection-Backflow Studies Details Activities (2) Areas (2) Regions (0) Abstract: Injection-backflow tracer testing on a single well is not a commonly used procedure for geothermal reservoir evaluation, and, consequently, there is little published information on the character or interpretation of tracer recovery curves. Two field experiments were conducted to develop chemical tracer procedures for use with injection-backflow testing, one on the fracture-permeability Raft River reservoir and the other on the matrix-permeability East Mesa reservoir. Results from tests conducted with incremental increases in the injection

174

Reactive ion etching: Optimized diamond membrane fabrication for transmission electron microscopy  

E-Print Network (OSTI)

Commonly used preparation method for thin diamond membranes by focused ion beam (FIB) techniques results in surface damage. Here, the authors introduce an alternative method based on reactive ion etching (RIE). To compare ...

Li, Luozhou

175

Joint Energy and Reactive Power Market Considering Coupled Active and Reactive Reserve Market Ensuring System Security  

Science Journals Connector (OSTI)

Reactive power market is usually held as independent from energy and reserved active power markets; however, active and reactive power are ... synchronous generator capacity curve. Therefore, reactive power market

Hamed Ahmadi; Asghar Akbari Foroud

2014-06-01T23:59:59.000Z

176

Characterization of four potential laser-induced fluorescence tracers for diesel engine applications  

Science Journals Connector (OSTI)

Four potential laser-induced fluorescence (LIF) tracers, 1-phenyloctane, 1-phenyldecane, 1-methylnaphthalene, and 2-methylnaphthalene, are characterized for diesel engine applications....

Trost, Johannes; Zigan, Lars; Leipertz, Alfred; Sahoo, Dipankar; Miles, Paul C

2013-01-01T23:59:59.000Z

177

Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Peer Review 2010 - Presentation. The objective of this project is to develop a matrix of the smart geothermal tracer and its interpretation tools.

178

Using Seismic Reflection to Locate a Tracer Testing Complex South of Yucca Mountain, Nye County, Nevada.  

E-Print Network (OSTI)

??Tracer testing in the fractured volcanic aquifer near Yucca Mountain, and in the alluvial aquifer south of Yucca Mountain, Nevada has been conducted in the (more)

Kryder, Levi

2014-01-01T23:59:59.000Z

179

Determination of Water Saturation in Relatively Dry Porous Media Using Gas-phase Tracer Tests  

SciTech Connect

Soil desiccation (drying), involving water evaporation induced by dry air injection and extraction, is a potentially robust remediation process to slow migration of inorganic or radionuclide contaminants through the vadose zone. The application of gas-phase partitioning tracer tests has been proposed as a means to estimate initial water volumes and to monitor the progress of the desiccation process at pilot-test and field sites. In this paper, tracer tests have been conducted in porous medium columns with various water saturations using sulfur hexafluoride as the conservative tracer and tricholorofluoromethane and difluoromethane as the water-partitioning tracers. For porous media with minimal silt and/or organic matter fractions, tracer tests provided reasonable saturation estimates for saturations close to zero. However, for sediments with significant silt and/or organic matter fractions, tracer tests only provided satisfactory results when the water saturation was at least 0.1 - 0.2. For dryer conditions, the apparent tracer retardation increases due to air soil sorption, which is not included in traditional retardation coefficients derived from advection-dispersion equations accounting only for air water partitioning and water soil sorption. Based on these results, gas-phase partitioning tracer tests may be used to determine initial water volumes in sediments, provided the initial water saturations are sufficiently large. However, tracer tests are not suitable for quantifying moisture content in desiccated sediments.

Oostrom, Martinus; Tartakovsky, Guzel D.; Wietsma, Thomas W.; Truex, Michael J.; Dane, Jacob H.

2011-04-15T23:59:59.000Z

180

Calcium translocation and whole plant transpiration: spatial and temporal measurements using radio-Strontium as tracer  

E-Print Network (OSTI)

comparison with zinc, strontium and rubidium. Annals of783- Wasserman RH. 1998. Strontium as a tracer for calciumor inapplicable. As Strontium (Sr) was found to behave in

Seligmann, Ron; Wengrowicz, Udi; Tirosh, Danny; Yermiyahu, Uri; Bar-Tal, Asher; Schwartz, Amnon

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

E-Print Network 3.0 - atmospheric tracer experiments Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Summary: for incorporating Lagrangian tracer positions into a model of flows (such as ocean currents). Such models... are important in understanding the behaviour of...

182

Tracer Testing At Neal Hot Springs Geothermal Area (U.S. Geothermal...  

Open Energy Info (EERE)

to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Tracer Testing At Neal Hot Springs Geothermal Area (U.S. Geothermal Inc., 2012) Exploration Activity...

183

E-Print Network 3.0 - activity optimal tracers Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

AND AMOC Abstract Current projections of the oceanic response... in current Earth system models and (ii) imperfect knowledge of model parameters. Ocean tracers observa- tions...

184

Triclosan Reactivity in Chloraminated Waters  

Science Journals Connector (OSTI)

Triclosan Reactivity in Chloraminated Waters ... Triclosan, widely employed as an antimicrobial additive in many household personal care products, has recently been detected in wastewater treatment plant effluents and in source waters used for drinking water supplies. ... Chloramines used either as alternative disinfectants in drinking water treatment or formed during chlorination of nonnitrified wastewater effluents have the potential to react with triclosan. ...

Aimee E. Greyshock; Peter J. Vikesland

2006-03-16T23:59:59.000Z

185

Estimation of tracer diffusion coefficients of ions in aqueous solution  

SciTech Connect

Equations are given for estimating tracer diffusion coefficients D/sub i//sup 0/ of ions at infinite dilution in terms of limiting ionic conductances ..lambda../sub i//sup 0/. Also given are generalized Nernst-Hartley equations for binary and multicomponent diffusion coefficients D/sup 0/ and D/sub ij//sup 0/, respectively, at infinite dilution. Data, estimates, and correlations for ..lambda../sub i//sup 0/ at 25/sup 0/C and other temperatures are discussed. Estimated values of ..lambda../sub i//sup 0/ are tabulated from 0-300/sup 0/C for ions of waste isolation interest and for ions of economic interest in geothermal brines. Estimates of their tracer diffusion coefficients at infinite dilution are tabulated. A rule of thumb, good to a factor of 2, is presented. Very limited data (available only at 25/sup 0/C) indicate that D/sub i//D/sub i//sup 0/ generally declines as the concentration of salt or supporting electrolyte increases. 6 figures, 2 tables.

Miller, D.G.

1982-09-07T23:59:59.000Z

186

Definition: Reactive Power | Open Energy Information  

Open Energy Info (EERE)

Reactive Power Reactive Power Jump to: navigation, search Dictionary.png Reactive Power The portion of electricity that establishes and sustains the electric and magnetic fields of alternating-current equipment. Reactive power must be supplied to most types of magnetic equipment, such as motors and transformers. It also must supply the reactive losses on transmission facilities. Reactive power is provided by generators, synchronous condensers, or electrostatic equipment such as capacitors and directly influences electric system voltage. It is usually expressed in kilovars (kvar) or megavars (Mvar).[1] View on Wikipedia Wikipedia Definition In electric power transmission and distribution, volt-ampere reactive (var) is a unit used to measure reactive power in an AC electric

187

Mitochondrial reactive oxygen species and cancer  

E-Print Network (OSTI)

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

188

Reactive Power Support Services in Electricity Markets  

E-Print Network (OSTI)

Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Final Project Report Power Systems Engineering Research Center A National Science Foundation Industry Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Project

189

Substituent Effects on the Reactivity of the Silicon-Carbon  

E-Print Network (OSTI)

Canada L8S 4M1 Received April 28, 2000 ABSTRACT Laser flash photolysis of various organosilicon compounds as a reactive intermediate in the high-temperature pyrolysis of a silacyclobutane deriva- tive.9 Hundreds describes our efforts to employ these techniquess laser flash photolysis methods in particularsto study

Leigh, William J.

190

Reactive materials can quickly form plugs for blowout control  

SciTech Connect

Various types of reactive materials, or gunk, can react directly with produced fluids (oil, condensate, or brine) or with an additionally injected fluid to form a plug to kill blowout wells or shut off large flow paths. Several recent blowouts were successfully controlled with reactive plugs; other conventional methods would have been more difficult operationally and cost more. Several plug mixtures are available on the market and can be made to suit the type of application and any particular environmental concerns. With proper planning and application, reactive plugs should be considered as a prime well control method when injection into the blowout flow path is available. This method of blowout control can save significant time and expense. The paper discusses the two basic methods of using reactive fluids depending on the flow path available, the use of cements, application steps, environmental concerns, and three case histories: a horizontal well in Texas, a high pressure, high temperature well offshore Louisiana, and a gas blowout in Argentina.

Flak, L.H. [Wright Boots and Coots, Houston, TX (United States)

1995-04-17T23:59:59.000Z

191

Design and synthesis of reactive separation systems. Final report  

SciTech Connect

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-12-31T23:59:59.000Z

192

SAND TRACER MOVEMENT MEASURED IN A STRONG RIP CURRENT Nicholas C. Kraus  

E-Print Network (OSTI)

exceeding 50 cm/sec in areas where instruments could be placed. Three colors of sand tracer were injected the diver's signal, a float tied to the diver's wrist was released and allowed to flow with the current because of the cold water, placed instruments, injected the tracer, and sampled the bottom with ropes tied

US Army Corps of Engineers

193

IAEA-CN-80/66 ISOTOPE TRACERS IN GLOBAL WATER AND CLIMATE STUDIES  

E-Print Network (OSTI)

comprehensive source of data for evaluating the modern global isotope field generated by atmospheric generalIAEA-CN-80/66 ISOTOPE TRACERS IN GLOBAL WATER AND CLIMATE STUDIES OF THE PAST AND PRESENT T Agency, Wagramer Strasse 5, P.O. Box 100, A-1400 Vienna, AUSTRIA Abstract ISOTOPE TRACERS IN GLOBAL WATER

Edwards, Thomas W.D.

194

Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period  

E-Print Network (OSTI)

Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period R (2006), Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period histories from ice coring of Greenland and Antarctica over the period 2 to 45 ka, using SO4 anomalies

Price, P. Buford

195

Stochastic inversion of tracer test and electrical geophysical data to estimate hydraulic conductivities  

E-Print Network (OSTI)

MonteCarlo (McMC) methodology to jointly invert the dynamic resistivity data, together with borehole tracer heterogeneity with respect to wellbore separation, where flow and transport are largely controlled by highly of drill cores and/or the results of tracer and pumping experiments; however, these techniques are often

Singha, Kamini

196

Heat as a tracer to determine streambed water exchanges Jim Constantz1  

E-Print Network (OSTI)

Heat as a tracer to determine streambed water exchanges Jim Constantz1 Received 13 March 2008 of heat as a tracer of shallow groundwater movement and describes current temperature-based approaches relying on traditional observation wells, and remote sensing and other large-scale advanced temperature

197

Saline tracer visualized with three-dimensional electrical resistivity tomography: Field-scale spatial moment analysis  

E-Print Network (OSTI)

Saline tracer visualized with three-dimensional electrical resistivity tomography: Field; accepted 14 February 2005; published 24 May 2005. [1] Cross-well electrical resistivity tomography (ERT., and S. M. Gorelick (2005), Saline tracer visualized with three-dimensional electrical resistivity

Singha, Kamini

198

The effect of pulse reactivity for stochastic neutron point kinetic equation in nuclear reactor dynamics  

Science Journals Connector (OSTI)

In this present analysis, the numerical simulation methods are applied to calculate the solution for Stochastic Neutron Point Kinetic Equations (SNPKE) with pulse reactivity in dynamical system of a nuclear reactor. The resulting systems of differential equations are solved for each time step-size. Using experimental data, the methods are investigated with pulse reactivity. The computational results designate that these numerical approximation methods are straightforward, effective and easy for solving stochastic point kinetic equations.

A. Patra; S. Saha Ray

2014-01-01T23:59:59.000Z

199

Reactive Ion Benjamin A. Small  

E-Print Network (OSTI)

(torr) plasma etching reactive ion etching ion milling m cm 100µm µm #12;5 Mechanics ~40 mTorrE380 kHz, 13.56 MHz ~30 sccm #12;6 Chemistry X X X X F- F- F-F- X F-F- F- F- F- R++ R++ R++ #12;7 Chemistry before opening · Silanes are explosive in the atmosphere #12;13 Bibliography Campbell, Stephen A

Garmestani, Hamid

200

Tracer Testing at Dixie Valley, Nevada, Using 2-Naphthalene Sulfonate and  

Open Energy Info (EERE)

Tracer Testing at Dixie Valley, Nevada, Using 2-Naphthalene Sulfonate and Tracer Testing at Dixie Valley, Nevada, Using 2-Naphthalene Sulfonate and 2,7-Naphthalene Disulfonate Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Tracer Testing at Dixie Valley, Nevada, Using 2-Naphthalene Sulfonate and 2,7-Naphthalene Disulfonate Abstract The decay kinetics of the candidate tracers 2-naphthalene sulfonate and 2,7-naphthalenedisulfonate was studied under laboratory conditionsthat simulate a hydrothermal environment, withneither compound exhibiting any decay after oneweek at 330�C. These data indicate that thesecompounds are more thermally stable than any of thepreviously studied polyaromatic sulfonates. Both ofthe tracer candidates were successfully tested in afield study at the Dixie Valley, Nevada, geothermalreservoir. In addition to

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Tracer Testing At Coso Geothermal Area (2004) | Open Energy Information  

Open Energy Info (EERE)

Coso Geothermal Area (2004) Coso Geothermal Area (2004) Exploration Activity Details Location Coso Geothermal Area Exploration Technique Tracer Testing Activity Date 2004 Usefulness not indicated DOE-funding Unknown Exploration Basis To determine the EGS potential of the Coso Geothermal Field Notes A dramatic decrease in the ratio of chloride to boron was observed in the liquid discharge of a well proposed for EGS development. The decrease appears to be related to the transformation of some feed zones in the well from liquid-dominated to vapor-dominated. High concentrations of boron are transported to the wellbore in the steam, where it fractionates to the liquid phase flowing in from liquid-dominated feed zones. The high-boron steam is created when the reservoir liquid in some of the feed zones boils

202

Reactive composite compositions and mat barriers  

DOE Patents (OSTI)

A hazardous material storage area has a reactive multi-layer composite mat which lines an opening into which a reactive backfill and hazardous material are placed. A water-inhibiting cap may cover the hazardous material storage area. The reactive multi-layer composite mat has a backing onto which is placed an active layer which will neutralize or stabilize hazardous waste and a fronting layer so that the active layer is between the fronting and backing layers. The reactive backfill has a reactive agent which can stabilize or neutralize hazardous material and inhibit the movement of the hazardous material through the hazardous material storage area.

Langton, Christine A. (Aiken, SC); Narasimhan, Rajendran (Evans, GA); Karraker, David G. (Aiken, SC)

2001-01-01T23:59:59.000Z

203

Predictions of PuO{sub 2} and tracer compound release from ISV melts  

SciTech Connect

Two field tests were conducted at the Idaho National Engineering Laboratory (INEL) to assess in situ vitrification (ISV) suitability for long-term stabilization of buried radioactive waste. Both tests contained rare-earth oxide tracers (DY{sub 2}O{sub 3}, Yb{sub 2}O{sub 3}, and Tb{sub 4}O{sub 7}) to simulate the presence of plutonium in the form of PuO{sub 2}. In the first test, Intermediate Field Test (IFT)-l, approximately 4-% release of tracer material occurred during soil melting and associated off-gassing, while essentially nil release was observed for the second experiment (IFT-2) for which off-gassing was much reduced. This report presents an evaluation of the IFT test data in terms of governing release processes. Prediction of tracer release during ISV melting centered on an assessment of three potential transport mechanisms, (a) tracer diffusion through stagnant pool, (b) tracer transport by convective currents, and (c) tracer carry-off by escaping gas bubbles. Analysis indicates that tracer release by escaping gas is the dominant release mechanism, which is consistent with video records of gas bubble escape from the ISV melt surface. Quantitative mass transport predictions were also made for the IFT-I test conditions, indicating similarity between the 4-% release data and calculational results at viscosities of {approx} poise and tracer diffusivities of {approx}10{sub {minus}6} CM{sup 2}/s. Since PuO{sub 2} has similar chemical and transport (diffusivity) properties as the rare-earth tracers used in the rare earth tracers used in the IFT experiments, release of PuO{sub 2} is predicted for similar off-gassing conditions. Reduced off-gassing during ISV would thus be expected to improve the overall retention of heavy-oxides within vitrified soil.

Cronenberg, A.W. [Engineering Science and Analysis, Albuquerque, NM (United States); Callow, R.A. [EG and G Idaho, Inc., Idaho Falls, ID (United States)

1992-04-01T23:59:59.000Z

204

Predictions of PuO sub 2 and tracer compound release from ISV melts  

SciTech Connect

Two field tests were conducted at the Idaho National Engineering Laboratory (INEL) to assess in situ vitrification (ISV) suitability for long-term stabilization of buried radioactive waste. Both tests contained rare-earth oxide tracers (DY{sub 2}O{sub 3}, Yb{sub 2}O{sub 3}, and Tb{sub 4}O{sub 7}) to simulate the presence of plutonium in the form of PuO{sub 2}. In the first test, Intermediate Field Test (IFT)-l, approximately 4-% release of tracer material occurred during soil melting and associated off-gassing, while essentially nil release was observed for the second experiment (IFT-2) for which off-gassing was much reduced. This report presents an evaluation of the IFT test data in terms of governing release processes. Prediction of tracer release during ISV melting centered on an assessment of three potential transport mechanisms, (a) tracer diffusion through stagnant pool, (b) tracer transport by convective currents, and (c) tracer carry-off by escaping gas bubbles. Analysis indicates that tracer release by escaping gas is the dominant release mechanism, which is consistent with video records of gas bubble escape from the ISV melt surface. Quantitative mass transport predictions were also made for the IFT-I test conditions, indicating similarity between the 4-% release data and calculational results at viscosities of {approx} poise and tracer diffusivities of {approx}10{sub {minus}6} CM{sup 2}/s. Since PuO{sub 2} has similar chemical and transport (diffusivity) properties as the rare-earth tracers used in the rare earth tracers used in the IFT experiments, release of PuO{sub 2} is predicted for similar off-gassing conditions. Reduced off-gassing during ISV would thus be expected to improve the overall retention of heavy-oxides within vitrified soil.

Cronenberg, A.W. (Engineering Science and Analysis, Albuquerque, NM (United States)); Callow, R.A. (EG and G Idaho, Inc., Idaho Falls, ID (United States))

1992-04-01T23:59:59.000Z

205

Permeable Reactive Barriers | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barrier Field Projects Durango, Colorado DOE installed a PRB in October 1995 to treat ground water from a uranium mill tailings disposal site at Durango, Colorado Read more Cañon City, Colorado ESL personnel conduct tests and help evaluate performance at other PRB sites, such as Cotter Corporation's Cañon City site in Colorado. Read more Monticello, Utah Installation of a PRB hydraulically downgradient of the Monticello, Utah, millsite was completed June 30, 1999, as an Interim Remedial Action. Read more A permeable reactive barrier (PRB) is a zone of reactive material placed underground to intercept and react with a contaminant plume in ground water. Typically, PRBs are emplaced by replacing soils with reactive

206

Reactive capability limits of wind farms  

Science Journals Connector (OSTI)

Wind Energy Conversion Systems (WECS) technology can be classified into two main types: fixed speed and variable speed. Fixed speed WECS use an induction generator connected directly to the grid while variable speed WECS use a power converter to connect the generator to the grid. Fixed speed WECS require shunt capacitors for reactive power compensation, while variable speed WECS have reactive power capability. Under the Spanish grid code, wind farms have to operate in a range of power factor values. This paper determines the reactive power capability of wind farms equipped with both fixed and variable speed WECS. The reactive power capability can be represented as a reactive capability curve. In this paper, the reactive capability curve is used to calculate the additional reactive power compensation needed to meet the requirements of the Spanish grid code.

Alberto Rios Villacorta; Santiago Arnaltes Gomez; Jose Luis Rodriguez-Amenedo

2005-01-01T23:59:59.000Z

207

Fuzzy Control on Voltage/Reactive Power in Electric Power Substation  

Science Journals Connector (OSTI)

A fuzzy method using in voltage and reactive power control in electric substation is proposed based on the improved 17 ... times at the tap positions of transformers in substation are much less than usual. So,...

Xiu-hua Wu; Jun-cheng Wang; Ping Yang

2009-01-01T23:59:59.000Z

208

Predictions of tracer transport in interwell tracer tests at the C-Hole complex. Yucca Mountain site characterization project report milestone 4077  

SciTech Connect

This report presents predictions of tracer transport in interwell tracer tests that are to be conducted at the C-Hole complex at the Nevada Test Site on behalf of the Yucca Mountain Site Characterization Project. The predictions are used to make specific recommendations about the manner in which the tracer test should be conducted to best satisfy the needs of the Project. The objective of he tracer tests is to study flow and species transport under saturated conditions in the fractured tuffs near Yucca Mountain, Nevada, the site of a potential high-level nuclear waste repository. The potential repository will be located in the unsaturated zone within Yucca Mountain. The saturated zone beneath and around the mountain represents the final barrier to transport to the accessible environment that radionuclides will encounter if they breach the engineered barriers within the repository and the barriers to flow and transport provided by the unsaturated zone. Background information on the C-Holes is provided in Section 1.1, and the planned tracer testing program is discussed in Section 1.2.

Reimus, P.W.

1996-09-01T23:59:59.000Z

209

Tracers for monitoring the activity of sodium/glucose cotransporters in health and disease  

DOE Patents (OSTI)

Radiolabeled tracers for sodium/glucose cotransporters (SGLTs), their synthesis, and their use are provided. The tracers are methyl or ethyl pyranosides having an equatorial hydroxyl group at carbon-2 and a C 1 preferred conformation, radiolabeled with .sup.18F, .sup.123I, or .sup.124I, or free hexoses radiolabeled with .sup.18F, .sup.123I, or .sup.124. Also provided are in vivo and in vitro techniques for using these and other tracers as analytical and diagnostic tools to study glucose transport, in health and disease, and to evaluate therapeutic interventions.

Wright, Ernest M; Barrio, Jorge R; Hirayama, Bruce A; Kepe, Vladimir

2014-09-30T23:59:59.000Z

210

Rejuvenating Permeable Reactive Barriers by Chemical Flushing  

Energy.gov (U.S. Department of Energy (DOE))

Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

211

Exploring the reactivity of bacterial multicomponent monooxygenases  

E-Print Network (OSTI)

Chapter 1. Introduction: The Reactivity of Bacterial Multicomponent Monooxygenases Bacterial multicomponent monooxygenases constitute a remarkable family of enzymes that oxidize small, inert hydrocarbon substrates using ...

Tinberg, Christine Elaine

2010-01-01T23:59:59.000Z

212

Project definition study for the National Biomedical Tracer Facility  

SciTech Connect

The University of Alabama at Birmingham (UAB) has conducted a study of the proposed National Biomedical Tracer Facility (NBTF). In collaboration with General Atomics, RUST International, Coleman Research Corporation (CRC), IsoMed, Ernst and Young and the advisory committees, they have examined the issues relevant to the NBTF in terms of facility design, operating philosophy, and a business plan. They have utilized resources within UAB, CRC and Chem-Nuclear to develop recommendations on environmental, safety and health issues. The Institute of Medicine Panel`s Report on Isotopes for Medicine and the Life Sciences took the results of prior workshops further in developing recommendations for the mission of the NBTF. The IOM panel recommends that the NBTF accelerator have the capacity to accelerate protons to 80 MeV and a minimum of 750 microamperes of current. The panel declined to recommend a cyclotron or a linac. They emphasized a clear focus on research and development for isotope production including target design, separation chemistry and generator development. The facility needs to emphasize education and training in its mission. The facility must focus on radionuclide production for the research and clinical communities. The formation of a public-private partnership resembling the TRIUMF-Nordion model was encouraged. An advisory panel should assist with the NBTF operations and prioritization.

Roozen, K.

1995-02-15T23:59:59.000Z

213

Tracer diffusion in compacted, water-saturated bentonite  

SciTech Connect

Compacted Na-bentonite clay barriers, widely used in theisolation of solid-waste landfills and other contaminated sites, havebeen proposed for a similar use in the disposal of high-level radioactivewaste. Molecular diffusion through the pore space in these barriers playsa key role in their performance, thus motivating recent measurements ofthe apparent diffusion coefficient tensor of water tracers in compacted,water-saturated Na-bentonites. In the present study, we introduce aconceptual model in which the pore space of water-saturated bentonite isdivided into 'macropore' and 'interlayer nanopore' compartments. Withthis model we determine quantitatively the relative contributions ofpore-network geometry (expressed as a geometric factor) and of thediffusive behavior of water molecules near montmorillonite basal surfaces(expressed as a contristivity factor) to the apparent diffusioncoefficient tensor. Our model predicts, in agreement with experiment,that the mean principal value of the apparent diffusion coefficienttensor follows a single relationship when plotted against the partialmontmorillonite dry density (mass of montmorillonite per combined volumeof montmorillonite and pore space). Using a single fitted parameter, themean principal geometric factor, our model successfully describes thisrelationship for a broad range of bentonite-water system, from dilute gelto highly-compacted bentonite with 80 percent of its pore water ininterlayer nanopores.

Bourg, Ian C.; Sposito, Garrison; Bourg, Alain C.M.

2005-08-04T23:59:59.000Z

214

Non-Energetic Reactive Armor (NERA) and Semi-Energetic Reactive Armor (SERA) FY13 Final Report  

SciTech Connect

INL researchers have proposed prototypes for future lightweight armor systems that reside in a technology gap between explosive reactive armor and passive armor. The targets were designed to react under impact and throw a steel front plate into the path of the projectile, forcing the projectile to engage more of the front plate during its penetration process. These prototypes are intended to exhibit the enhanced efficiency of explosive reactive armor without the collateral damage often associated with explosive reactive armor. One of the prototype systems, Semi Energetic Reactive Armor (SERA), functions similarly to explosive reactive armor, but features a reactive material that reacts much slower than explosive reactive armor. Two different SERA test groups were built and featuring different ratios of aluminum Teflon(copyright) powders pressed into 0.5 in. thick energetic tiles and sandwiched between 0.25 in. thick RHA plates. The other prototype system, Non Energetic Reactive Armor (NERA), utilizes the strain energy in compressed rubber to launch a front flyer plate into the path of an incoming projectile. It is comprised of a 1 in. thick rubber layer sandwiched between two 0.25 in. thick RHA plates with bolt holes around the perimeter. Bolts are inserted through the entire target and tightened to compress the rubber sheet to significant strain levels (approximately 40%). A fourth group of targets was tested as a control group. It featured a 0.5 in. thick rubber sheet sandwiched between two 0.25 in. thick RHA plates, similar to the NERA test articles, but the rubber is uncompressed. The four test groups (uncompressed rubber, compressed rubber, 70/30 Al/PTFE, 50/50 Al/PTFE) were each fabricated with three identical test articles in each group. All twelve targets were subjected to ballistic testing at the National Security Test Range on July 17, 2013. They were tested with 0.5 in. diameter steel rods shot at a consistent velocity at each target. In order to characterize the energetic materials, break wires were embedded in the targets and burn velocities were measured. The residual mass method was used to compare the target performance of each group and final performance data is presented below.

Ben Langhorst; Nikki Rasmussen; Andrew Robinson

2013-08-01T23:59:59.000Z

215

Wintertime Dispersion in a Mountainous Basin at Roanoke, Virginia: Tracer Study  

Science Journals Connector (OSTI)

During January 1989, five nighttime SF6 tracer experiments were conducted in Roanoke, Virginia. The experiments were designed to help identify and understand the dispersion characteristics of a basin atmosphere during winter stagnation ...

K. Jerry Allwine; Brian K. Lamb; Robert Eskridge

1992-11-01T23:59:59.000Z

216

Reactivity during bench-scale combustion of biomass fuels for carbon capture and storage applications  

Science Journals Connector (OSTI)

Abstract Reactivities of four biomass samples were investigated in four combustion atmospheres using non-isothermal thermogravimetric analysis (TGA) under two heating rates. The chosen combustion atmospheres reflect carbon capture and storage (CCS) applications and include O 2 and CO 2 -enrichment. Application of the CoatsRedfern method assessed changes in reactivity. Reactivity varied due to heating rate: the reactivity of char oxidation was lower at higher heating rates while devolatilisation reactions were less affected. In general, and particularly at the higher heating rate, increasing [ O 2 ] increased combustion reactivity. A lesser effect was observed when substituting N 2 for CO 2 as the comburent; in unenriched conditions this tended to reduce char oxidation reactivity while in O 2 -enriched conditions the reactivity marginally increased. Combustion in a typical, dry oxyfuel environment (30% O 2 , 70% CO 2 ) was more reactive than in air in TGA experiments. These biomass results should interest researchers seeking to understand phenomena occurring in larger scale CCS-relevant experiments.

S. Pickard; S.S. Daood; M. Pourkashanian; W. Nimmo

2014-01-01T23:59:59.000Z

217

Glass mixing theory and tracer study results from the SF-10 run  

SciTech Connect

A general, partial differential equation governing glass mixing in the Slurry Fed Ceramic Melter (SFCM) was derived and a solution obtained based upon certain simplifying assumptions. Tracer studies were then conducted in the SFCM during the SF-10 run to test the theory and characterize glass mixing in this melter. Analysis of the tracer data shows that glass mixing in the SFCM can be explained by use of a model of two, well-mixed tanks in series.

Bowman, B.W.; Routt, K.R.

1988-08-01T23:59:59.000Z

218

Utility of Bromide and Heat Tracers for Aquifer Characterization Affected by Highly Transient Flow Conditions  

SciTech Connect

A tracer test using both bromide and heat tracers conducted at the Integrated Field Research Challenge site in Hanford 300 Area (300A), Washington, provided an instrument for evaluating the utility of bromide and heat tracers for aquifer characterization. The bromide tracer data were critical to improving the calibration of the flow model complicated by the highly dynamic nature of the flow field. However, most bromide concentrations were obtained from fully screened observation wells, lacking depth-specific resolution for vertical characterization. On the other hand, depth-specific temperature data were relatively simple and inexpensive to acquire. However, temperature-driven fluid density effects influenced heat plume movement. Moreover, the temperature data contained noise caused by heating during fluid injection and sampling events. Using the hydraulic conductivity distribution obtained from the calibration of the bromide transport model, the temperature depth profiles and arrival times of temperature peaks simulated by the heat transport model were in reasonable agreement with observations. This suggested that heat can be used as a cost-effective proxy for solute tracers for calibration of the hydraulic conductivity distribution, especially in the vertical direction. However, a heat tracer test must be carefully designed and executed to minimize fluid density effects and sources of noise in temperature data. A sensitivity analysis also revealed that heat transport was most sensitive to hydraulic conductivity and porosity, less sensitive to thermal distribution factor, and least sensitive to thermal dispersion and heat conduction. This indicated that the hydraulic conductivity remains the primary calibration parameter for heat transport.

Ma, Rui; Zheng, Chunmiao; Zachara, John M.; Tonkin, Matthew J.

2012-08-29T23:59:59.000Z

219

Reactivity of calcium sulfate from FBC systems  

Science Journals Connector (OSTI)

A relative estimate of the reactivity of calcium sulfate in a number of coal combustion ash samples was obtained, using the rate of solution in water as a parameter. Measurements were also performed on standard samples of calcium sulfate prepared in different ways, for comparison. The temperature of previous treatment appeared as the most important factor determining the reactivity of CaSO4; the grain size distribution was less important, and the duration of heating (even to 105 days) had very little influence. No correlation between specific surface of ash samples and their reactivity was apparent. Calcium sulfate in FBC ash samples was much more reactive than that contained in high-temperature ashes, and than calcium sulfate heated, alone or with various additions, at 850C for 2 days. Of the six FBC samples tested, five showed similar behaviour, including a sample from a pressurized system; only a deposit from 96 days operation of an industrial CFBC boiler burning petroleum coke showed considerably less reactivity. Surprisingly, CaSO4 from two FBC samples placed in an oven for 60 days under sulfating conditions showed a very similar rate of solution to that of the other FBC samples, while a third sample kept in the oven for 105 days also showed no decrease in reactivity. Only when one of these samples had agglomerated (which occurred between 60 and 105 days) did it show decreased reactivity, suggesting that the agglomeration process rather than duration is significant in promoting sintering and reducing the sulfate reactivity.

Agripanea P. Iribarne; Julio V. Iribarne; Edward J. Anthony

1997-01-01T23:59:59.000Z

220

In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared...  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and Reactive Landing of Mass Selected Ions. In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and...

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Numerical solution for stochastic point-kinetics equations with sinusoidal reactivity in dynamical system of nuclear reactor  

Science Journals Connector (OSTI)

In this present analysis, the numerical simulation methods are applied to calculate the solution for stochastic point-kinetic equations with sinusoidal reactivity in dynamical system of nuclear reactor. The resulting system of differential equations is solved for each time step-size. Using experimental data, the methods are investigated over initial conditions and with sinusoidal reactivity. The computational results designate that these numerical approximation methods are straightforward, effective and easy for solving stochastic point-kinetic equations.

S. Saha Ray; A. Patra

2013-01-01T23:59:59.000Z

222

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical

223

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

224

Characterization of Dual-Fuel Reactivity Controlled Compression...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI)...

225

Reactive multilayer synthesis of hard ceramic foils and films  

DOE Patents (OSTI)

A method for synthesizing hard ceramic materials such as carbides, borides nd aluminides, particularly in the form of coatings provided on another material so as to improve the wear and abrasion performance of machine tools, for example. The method involves the sputter deposition of alternating layers of reactive metals with layers of carbon, boron, or aluminum and the subsequent reaction of the multilayered structure to produce a dense crystalline ceramic. The material can be coated on a substrate or formed as a foil which can be coild as a tape for later use.

Makowiecki, Daniel M. (Livermore, CA); Holt, Joseph B. (San Jose, CA)

1996-01-01T23:59:59.000Z

226

Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems  

SciTech Connect

The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

Reimus, Paul W [Los Alamos National Laboratory

2011-01-21T23:59:59.000Z

227

Tracer transport in the Greenland Ice Sheet: constraints on ice cores and glacial history  

Science Journals Connector (OSTI)

The climate history and dynamics of the Greenland Ice Sheet are studied using a coupled model of the depositional provenance and transport of glacier ice, allowing simultaneous prediction of the detailed isotopic stratigraphy of ice cores at all the major Greenland sites. Adopting a novel method for reconstructing the agedepth relationship, we greatly improve the accuracy of semi-Lagrangian tracer tracking schemes and can readily incorporate an age-dependent ice rheology. The larger aim of our study is to impose new constraints on the glacial history of the Greenland Ice Sheet. Leading sources of uncertainty in the climate and dynamic history are encapsulated in a small number of parameters: the temperature and elevation isotopic sensitivities, the glacialinterglacial precipitation contrast and the effective viscosity of ice in the flow law. Comparing predicted and observed ice layering at ice core sites, we establish plausible ranges for the key model parameters, identify climate and dynamic histories that are mutually consistent and recover the past depositional elevation of ice cores to ease interpretation of their climatic records. With the coupled three-dimensional model of ice dynamics and provenance transport we propose a method to place all the ice core records on a common time scale and use discrepancies to adjust the reconstructed climate history. Analysis of simulated GRIP ice layering and borehole temperature profiles confirms that the GRIP record is sensitive to the dynamic as well as to the climatic history, but not enough to strongly limit speculation on the state of the Greenland Ice Sheet during the Eemian. In contrast, our study indicates that the Dye 3 and Camp Century ice cores are extremely sensitive to ice dynamics and greatly constrain Eemian ice sheet reconstructions. We suggest that the maximum Eemian sea-level contribution of the ice sheet was in the range of 3.54.5m.

Nicolas Lhomme; Garry K.C. Clarke; Shawn J. Marshall

2005-01-01T23:59:59.000Z

228

COAL SLAGGING AND REACTIVITY TESTING  

SciTech Connect

Union Fenosa's La Robla I Power Station is a 270-MW Foster Wheeler arch-fired system. The unit is located at the mine that provides a portion of the semianthracitic coal. The remaining coals used are from South Africa, Russia, Australia, and China. The challenges at the La Robla I Station stem from the various fuels used, the characteristics of which differ from the design coal. The University of North Dakota Energy & Environmental Research Center (EERC) and the Lehigh University Energy Research Center (LUERC) undertook a program to assess problematic slagging and unburned carbon issues occurring at the plant. Full-scale combustion tests were performed under baseline conditions, with elevated oxygen level and with redistribution of air during a site visit at the plant. During these tests, operating information, observations and temperature measurements, and coal, slag deposit, and fly ash samples were obtained to assess slagging and unburned carbon. The slagging in almost all cases appeared due to elevated temperatures rather than fuel chemistry. The most severe slagging occurred when the temperature at the sampling port was in excess of 1500 C, with problematic slagging where first-observed temperatures exceeded 1350 C. The presence of anorthite crystals in the bulk of the deposits analyzed indicates that the temperatures were in excess of 1350 C, consistent with temperature measurements during the sampling period. Elevated temperatures and ''hot spots'' are probably the result of poor mill performance, and a poor distribution of the coal from the mills to the specific burners causes elevated temperatures in the regions where the slag samples were extracted. A contributing cause appeared to be poor combustion air mixing and heating, resulting in oxygen stratification and increased temperatures in certain areas. Air preheater plugging was observed and reduces the temperature of the air in the windbox, which leads to poor combustion conditions, resulting in unburned carbon as well as slagging. A second phase of the project involved advanced analysis of the baseline coal along with an Australian coal fired at the plant. These analysis results were used in equilibrium thermodynamic modeling along with a coal quality model developed by the EERC to assess slagging, fouling, and opacity for the coals. Bench-scale carbon conversion testing was performed in a drop-tube furnace to assess the reactivity of the coals. The Australian coal had a higher mineral content with significantly more clay minerals present than the baseline coal. The presence of these clay minerals, which tend to melt at relatively low temperatures, indicated a higher potential for problematic slagging than the baseline coal. However, the pyritic minerals, comprising over 25% of the baseline mineral content, may form sticky iron sulfides, leading to severe slagging in the burner region if local areas with reducing conditions exist. Modeling results indicated that neither would present significant fouling problems. The Australian coal was expected to show slagging behavior much more severe than the baseline coal except at very high furnace temperatures. However, the baseline coal was predicted to exhibit opacity problems, as well as have a higher potential for problematic calcium sulfate-based low-temperature fouling. The baseline coal had a somewhat higher reactivity than the Australian coal, which was consistent with both the lower average activation energy for the baseline coal and the greater carbon conversion at a given temperature and residence time. The activation energy of the baseline coal showed some effect of oxygen on the activation energy, with E{sub a} increasing at the lower oxygen concentration, but may be due to the scatter in the baseline coal kinetic values at the higher oxygen level tested.

Donald P. McCollor; Kurt E. Eylands; Jason D. Laumb

2003-10-01T23:59:59.000Z

229

Systematic approach for chemical reactivity evaluation  

E-Print Network (OSTI)

Screening Tool (RSST) and the Automatic Pressure Tracking Adiabatic Calorimeter (APTAC) were employed to evaluate the reactive systems experimentally. The RSST detected exothermic behavior and measured the overall liberated energy. The APTAC simulated...

Aldeeb, Abdulrehman Ahmed

2004-09-30T23:59:59.000Z

230

Reactivity control assembly for nuclear reactor  

DOE Patents (OSTI)

Reactivity control assembly for nuclear reactor comprises supports stacked above reactor core for holding control rods. Couplers associated with the supports and a vertically movable drive shaft have lugs at their lower ends for engagement with the supports.

Bollinger, Lawrence R. (Schenectady, NY)

1984-01-01T23:59:59.000Z

231

Fossil plant layup and reactivation conference: Proceedings  

SciTech Connect

The Fossil Plant Layup and Reactivation Conference was held in New Orleans, Louisiana on April 14--15, 1992. The Conference was sponsored by EPRI and hosted by Entergy Services, Inc. to bring together representatives from utilities, consulting firms, manufacturers and architectural engineers. Eighteen papers were presented in three sessions. These sessions were devoted to layup procedures and practices, and reactivation case studies. A panel discussion was held on the second day to interactively discuss layup and reactivation issues. More than 80 people attended the Conference. This report contains technical papers and a summary of the panel discussion. Of the eighteen papers, three are related to general, one is related to regulatory issues, three are related to specific equipment, four are related to layup procedures and practices, and seven are layup and reactivation case studies.

Not Available

1992-10-01T23:59:59.000Z

232

A Tariff for Reactive Power - IEEE  

SciTech Connect

This paper describes a suggested tariff or payment for the local supply of reactive power from distributed energy resources. The authors consider four sample customers, and estimate the cost of supply of reactive power for each customer. The power system savings from the local supply of reactive power are also estimated for a hypothetical circuit. It is found that reactive power for local voltage regulation could be supplied to the distribution system economically by customers when new inverters are installed. The inverter would be supplied with a power factor of 0.8, and would be capable of local voltage regulation to a schedule supplied by the utility. Inverters are now installed with photovoltaic systems, fuel cells and microturbines, and adjustable-speed motor drives.

Kueck, John D [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator; Kirby, Brendan J [ORNL

2008-11-01T23:59:59.000Z

233

Reactive Attachment Disorder: Concepts, Treatment, and Research  

E-Print Network (OSTI)

Reactive Attachment Disorder (RAD) is a disorder characterized by controversy, both with respect to its definition and its treatment. By definition, the RAD diagnosis attempts to characterize and explain the origin of ...

Walter, Uta M.; Petr, Chris

2004-06-01T23:59:59.000Z

234

Radon entry rate analyses using in situ tracer gas method application  

Science Journals Connector (OSTI)

......underestimate the complexity of energy retrofitting itself. In...Hazards Associated With Home Energy Retrofits. (2012) The National Renewable Energy Laboratory, U.S. Department...for the purpose of radon mitigation effectiveness proper evaluation......

A. Fro?ka; K. Jlek

2014-07-01T23:59:59.000Z

235

Radon entry rate analyses using in situ tracer gas method application  

Science Journals Connector (OSTI)

......of newly built houses is primarily focused...buildings, the energy efficiency can be improved...in operation, house occupied. CONCLUSIONS...dominantly on home energy efficiency. The mean ACH in unoccupied houses was frequently......

A. Fro?ka; K. Jlek

2014-07-01T23:59:59.000Z

236

A radiocarbon method and multi-tracer approach to quantifying groundwater discharge to coastal waters  

E-Print Network (OSTI)

Groundwater discharge into estuaries and the coastal ocean is an important mechanism for the transport of dissolved chemical species to coastal waters. Because many dissolved species are present in groundwater in concentrations ...

Gramling, Carolyn M

2003-01-01T23:59:59.000Z

237

Radon entry rate analyses using in situ tracer gas method application  

Science Journals Connector (OSTI)

......underneath the exterior slab insulation into the indoor environment...load-bearing and thermo insulation functions. Double-layer...layer, and the exterior slab insulation based on extrude polystyrene foam boards was provided below......

A. Fro?ka; K. Jlek

2014-07-01T23:59:59.000Z

238

Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure  

E-Print Network (OSTI)

the concentrations of pollutants emitted by indoor sources and brings in pollutants from the outdoors. The air Development Office of Healthy Homes and Lead Hazard Control through Interagency Agreement I-PHI-01070; by the U.S. Environmental Protection Agency Office of Air and Radiation through Interagency Agreement DW-89

239

USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE  

Open Energy Info (EERE)

NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE COSO EGS PROJECT Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE COSO EGS PROJECT Details Activities (1) Areas (1) Regions (0) Abstract: A dramatic decrease in the ratio of chloride to boron was observed in the liquid discharge of a well proposed for EGS development in the Coso geothermal field. The decrease appears to be related to the transformation of some feed zones in the well from liquid-dominated to vapor-dominated. High concentrations of boron are transported to the wellbore in the steam, where it fractionates to the liquid phase flowing in from liquid-dominated feed zones. The high-boron steam is created when the

240

A comprehensive study of the analysis and economic benefits of radioactive tracer engineered simulation procedures  

SciTech Connect

Hydraulic Fracturing is an important technology to enhance production from tight gas reservoirs. Several techniques have been utilized to attempt to evaluate the effectiveness of hydraulic fracturing treatments. One technique, radioactive tracers, is currently used on over 15 % of the stimulation treatments performed in the U.S. With proper materials, design, and execution, tracers can be used to locate the presence and concentration of proppant at the wellbore in order to evaluate vertical and radial proppant distribution. A comprehensive study of over 100 fracture treatments has been completed in which radioactive tracers were used along with production logs, stress logs, post-fracturing completion reports, and production history to analyze completion effectiveness in four different reservoirs. Additionally, an economic benefit model was constructed to evaluate the benefit/cost ratio of applying the technology.

Fisher, K.; Robinson, B.M.; Voneiff, G.W.

1995-12-31T23:59:59.000Z

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While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

The Elemental Composition of High-Energy Cosmic Rays: Measurements with TRACER  

E-Print Network (OSTI)

TRACER ('Transition Radiation Array for Cosmic Energetic Radiation') is a balloon borne instrument that has been developed to directly measure the composition and energy spectra of individual heavy elements up to 10^15 eV per particle. TRACER achieves a large geometric factor (5 m^2 sr) through the use of a Transition Radiation Detector utilizing arrays of single wire proportional tubes. TRACER has measured the energy spectra of the elements O, Ne, Mg, Si, S, Ar, Ca, and Fe. The energy spectra reach energies in excess of 10^14 eV per particle and exhibit nearly the same spectral index (2.65 +/- 0.05) for all elements.

P. J. Boyle

2008-10-16T23:59:59.000Z

242

Using a DFIG-based wind farm for grid node reactive power compensation  

Science Journals Connector (OSTI)

Grid nodes voltages are not allowed to deviate excessively from nominal value. Appropriate measures should be taken to prevent such a deviation. The voltage difference between two nodes is strongly affected by reactive power flow. In contrast to frequency control, node voltage control must be achieved locally. This article investigates the use of a wind farm based on a doubly fed induction generators (DFIG) for reactive power compensation of a grid node. A wind speed variation sample is applied to the model of a wind power unit. The power flow between the stator of the DFIG-based wind power unit and the grid is controlled by using the decoupled active and reactive power vector control method. The limits or capacity of the stator and power converters to consume or provide reactive power are discussed. SIMULINK software has been used for the simulation of the system.

Mohamed Kesraoui; Ahmed Chaib; Abdullah Madri; Bilal Hammani

2013-01-01T23:59:59.000Z

243

Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel  

DOE Patents (OSTI)

Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

Herrmann, Steven Douglas

2014-05-27T23:59:59.000Z

244

Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site  

SciTech Connect

This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

2000-08-01T23:59:59.000Z

245

Surface Reactivity and Plasma Energetics of SiH Radicals during Plasma Deposition of Silicon-Based Materials  

Science Journals Connector (OSTI)

The surface reactivity of the SiH radical was measured during plasma deposition of various silicon-based materials using the imaging of radicals interacting with surfaces (IRIS) method. In this technique, spatially resolved laser-induced fluorescence (LIF)...

W. M. M. Kessels; Patrick R. McCurdy; Keri L. Williams; G. R. Barker; Vincent A. Venturo; Ellen R. Fisher

2002-02-09T23:59:59.000Z

246

Phase II: Performance Evaluation of Permeable Reactive Barriers and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Phase II: Performance Evaluation of Permeable Reactive Barriers and Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing U. S. Environmental Protection Agency Region 8 Support January 2004 Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing

247

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

248

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

249

Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Peer Review 2010 - Project Summary. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate quantitative characterization of temperature distributions and surface area available for heat transfer in EGS.

250

ADVANCES IN ATMOSPHERIC SCIENCES, VOL. 25, NO. 5, 2008, 805814 Diagnosing Ocean Tracer Transport from Sellafield  

E-Print Network (OSTI)

DRANGE1,2,3,4 , and Eric DELEERSNIJDER5 1 Nansen Environmental and Remote Sensing Center, Bergen, Norway applications thereof, idealized releases of passive tracers from the nuclear fuel reprocessing plants­814, doi: 10.1007/s00376-008-0805-y. 1. Introduction Estimating the integrated effect of processes acting

Drange, Helge

251

Project EARTH-14-SHELLDP1: Developing Metal Isotope Tracers for Understanding Sediment Depositional Environments  

E-Print Network (OSTI)

Project EARTH-14-SHELLDP1: Developing Metal Isotope Tracers for Understanding Sediment Depositional and the mechanisms behind temporal and spatial variations in organic matter quantity and quality. The project work will involve becoming proficient in clean room procedures, chemical separation techniques

Henderson, Gideon

252

Lignin biomarkers as tracers of mercury sources in lakes water column  

E-Print Network (OSTI)

Lignin biomarkers as tracers of mercury sources in lakes water column Jean-Franc¸ois Ouellet ? Marc the autochthonous from the allochthonous organic matter (OM), lignin derived biomarker signa- tures [Lambda, S/V, C/V, P/(V ? S), 3,5-Bd/V and (Ad/Al)v] were used. Since lignin is exclusively produced by terrigenous

Long, Bernard

253

USING LIDAR TO MEASURE PERFLUOROCARBON TRACERS FOR THE VERIFICATION AND MONITORING  

E-Print Network (OSTI)

USING LIDAR TO MEASURE PERFLUOROCARBON TRACERS FOR THE VERIFICATION AND MONITORING OF CAP AND COVER to detect PMCH (perfluoromethylcyclohexane, one of a group of PFTs used at BNL). Laboratory measurements then measured down to 1 ppb-m. These results are very promising and show great potential for monitoring

254

New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas Operations  

E-Print Network (OSTI)

New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas fingerprints of fluids that return to the surface after high volume hydraulic fracturing of unconventional oil the hydraulic fracturing process, resulting in the relative enrichment of boron and lithium in HFFF

Jackson, Robert B.

255

Physical causes and modeling challenges of anomalous diffusion of sediment tracers  

E-Print Network (OSTI)

Physical causes and modeling challenges of anomalous diffusion of sediment tracers Douglas Jerolmack Earth & Environmental Science, UPenn [sediment@sas.upenn.edu] "Bridging the Gap", Princeton U., 2" describable by: 1. Particle volume, v [L3 ]. 2.Average velocity, us , of bed load sediment [L/T]. 3. Surface

256

Evaluating the ability of a numerical weather prediction model to forecast tracer concentrations during ETEX 2  

E-Print Network (OSTI)

Evaluating the ability of a numerical weather prediction model to forecast tracer concentrations an operational numerical weather prediction model to forecast air quality are also investigated. These potential a numerical weather prediction (NWP) model independently of the CTM. The NWP output is typically archived

Dacre, Helen

257

Dynamic Reservoir Characterization Of Naturally Fractured Reservoirs From An Inter-Well Tracer Test  

E-Print Network (OSTI)

-spot pattern and breakthrough time of the injected tracer. Once the model became capable of matching historical field production, a 1-year prediction run was conducted for optimization. Cumulative oil production was increased by 8,000 bbl by allocating more...

Kilicaslan, Ufuk

2013-12-03T23:59:59.000Z

258

Seasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements  

E-Print Network (OSTI)

of indoor air pollution sources. Concurrently, great efforts are made to make buildings energy efficient 1970s, while less attention has been paid to IAQ. Insufficient venting of indoor air pollutantsSeasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements Marie

Hansen, René Rydhof

259

Analysis of tracer responses in the BULLION Forced-Gradient Experiment at Pahute Mesa, Nevada  

SciTech Connect

This report presents an analysis of the tracer data from the BULLION forced-gradient experiment (FGE) conducted on Pahute Mesa at the Nevada Test Site from June 2, 1997 through August 28, 1997, for the Underground Test Area (UGTA) Program. It also serves to document the polystyrene microsphere data from the FGE. The FGE involved the injection of solute and colloid tracers into wells ER-20-6 No. 1 and ER-20-6 No. 2 while ER-20-6 No. 3 was pumped at approximately 116 gallons per minute (gpm). The experimental configuration and test design are described briefly in this report; more details are provided elsewhere (IT, 1996, 1997, 1998). The tracer responses in the various wells yielded valuable information about transport processes such as longitudinal dispersion, matrix diffusion and colloid transport in the hydrogeologic system in the vicinity of the BULLION nuclear test cavity. Parameter values describing these processes are derived from the semi-analytical model interpretations presented in this report. A companion report (IT, 1998) presents more detailed numerical modeling interpretations of the solute tracer responses.

Paul W. Reimus; Marc J. Haga

1999-10-01T23:59:59.000Z

260

Supporting BioMedical Information Retrieval: The BioTracer Approach  

E-Print Network (OSTI)

Supporting BioMedical Information Retrieval: The BioTracer Approach Heri Ramampiaro1 and Chen Li2 1 biomedical in- formation has put a high demand on existing search systems. Such a tool should be able the relevant ones the highest rank- ing. Focusing on biomedical information, this work investigates how

Li, Chen

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Evidence of Multi-Process Matrix Diffusion in a Single Fracturefrom a Field Tracer Test  

SciTech Connect

Compared to values inferred from laboratory tests on matrix cores, many field tracer tests in fractured rock have shown enhanced matrix diffusion coefficient values (obtained using a single-process matrix-diffusion model with a homogeneous matrix diffusion coefficient). To investigate this phenomenon, a conceptual model of multi-process matrix diffusion in a single-fracture system was developed. In this model, three matrix diffusion processes of different diffusion rates were assumed to coexist: (1) diffusion into stagnant water and infilling materials within fractures, (2) diffusion into a degraded matrix zone, and (3) further diffusion into an intact matrix zone. The validity of the conceptual model was then demonstrated by analyzing a unique tracer test conducted using a long-time constant-concentration injection. The tracer-test analysis was conducted using a numerical model capable of tracking the multiple matrix-diffusion processes. The analysis showed that in the degraded zone, a diffusion process with an enhanced diffusion rate controlled the steep rising limb and decay-like falling limb in the observed breakthrough curve, whereas in the intact matrix zone, a process involving a lower diffusion rate affected the long-term middle platform of slowly increasing tracer concentration. The different matrix-diffusion-coefficient values revealed from the field tracer test are consistent with the variability of matrix diffusion coefficient measured for rock cores with different degrees of fracture coating at the same site. By comparing to the matrix diffusion coefficient calibrated using single-process matrix diffusion, we demonstrated that this multi-process matrix diffusion may contribute to the enhanced matrix-diffusion-coefficient values for single-fracture systems at the field scale.

Zhou, Quanlin; Liu, Hui-Hai; Bodvarsson, Gudmundur; Molz, Fred J.

2005-06-11T23:59:59.000Z

262

Analysis of Tracer Dispersion During a Prescribed Forest Burn  

E-Print Network (OSTI)

become a method to manage forest health, while preventing uncontrolled wild land fire. Low intensity, prescribed burns release less carbon dioxide than wildfires of the same size and may be used as a strategy. The ultimate goal of the project is to use the data from the burn, along with modeling techniques to improve

Collins, Gary S.

263

Informal Report USE OF PERFLUOROCARBON TRACER (PFT) TECHNOLOGY  

E-Print Network (OSTI)

to ground water movement, meteorological water infiltration, vapor- and gas-phase transport, transpiration). Introduction One of the more promising remediation options available to the DOE waste management community contaminant plumes and to restrict remediation methods, such as vacuum extraction, to a limited area

264

Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion  

SciTech Connect

Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-high vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) was found to be a good representation of both types of diffusion data that cover a broad range of temperatures between 250 - 627 C (523 900 K).

Kulkarni, Nagraj S [ORNL; Warmack, Robert J Bruce [ORNL; Radhakrishnan, Balasubramaniam [ORNL; HunterJr., Jerry [Virginia Polytechnic Institute and State University; Sohn, Yong Ho [University of Central Florida; Coffey, Kevin [University of Central Florida; Murch, Prof. Graeme [University of Newcastle, NSW, Australia; Belova, Irina [University of Newcastle, NSW, Australia

2014-01-01T23:59:59.000Z

265

Formation and Reactivity of Biogenic Iron Microminerals  

SciTech Connect

The overall purpose of the project is to explore and quantify the processes that control the formation and reactivity of biogenic iron microminerals and their impact on the solubility of metal contaminants. The research addresses how surface components of bacterial cells, extracellular organic material, and the aqueous geochemistry of the DIRB microenvironment impacts the mineralogy, chemical state and micromorphology of reduced iron phases.

Beveridge, Terrance J.; Glasauer, Susan; Korenevsky, Anton; Ferris, F. Grant

2000-08-08T23:59:59.000Z

266

Controlling uranium reactivity March 18, 2008  

E-Print Network (OSTI)

for the last decade. Most of their work involves depleted uranium, a more common form of uraniumMarch 2008 Controlling uranium reactivity March 18, 2008 Uranium is an often misunderstood metal uranium research. In reality, uranium presents a wealth of possibilities for funda- mental chemistry. Many

Meyer, Karsten

267

Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain site characterization project: Quality Assurance Project Plan, Revision 1; Quarterly progress report, October 1, 1993--December 31, 1993  

SciTech Connect

The purpose of this work is to identify and characterize candidate conservative organic tracers for use as hydrologic tracers for experiments to be conducted at the Yucca Mountain C-well complex. During this quarter the main effort was directed towards rewriting the quality assurance program in preparation for a review and audit by the USGS. However, due to budget constraints the review and audit were not carried out. The tracer QA plan and standard operating procedures (SOPs) were revised and copies are included in the report. Instrumental problems were encountered and corrected with the addition of new integration and sample control software. In the sampling, there was an unexplained peak in the chromatograms of the tracers being tested in the light tuff. This was not correctable and these experiments will be repeated in the next quarter.

Stetzenbach, K.J.

1993-12-13T23:59:59.000Z

268

Cell Comp't Thermal Reactivity & Improvements | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Comp't Thermal Reactivity & Improvements Cell Comp't Thermal Reactivity & Improvements Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on...

269

Isotope effects in methanol synthesis and the reactivity of copper...  

NLE Websites -- All DOE Office Websites (Extended Search)

Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

270

Design of processes with reactive distillation line diagrams  

SciTech Connect

On the basis of the transformation of concentration coordinates, the concept of reactive distillation lines is developed. It is applied to study the feasibility of a reactive distillation with an equilibrium reaction on all trays of a distillation column. The singular points in the distillation line diagrams are characterized in terms of nodes and saddles. Depending on the characterization of the reactive distillation line diagrams, it can be decided whether a column with two feed stages is required. On the basis of the reaction space concept, a procedure for identification of reactive distillation processes is developed, in which the reactive distillation column has to be divided into reactive and nonreactive sections. This can be necessary to overcome the limitations in separation which result from the chemical equilibrium. The concentration profile of this combined reactive/nonreactive distillation column is estimated using combined reactive/nonreactive distillation lines.

Bessling, B. [BASF Ludwigshafen (Germany). Engineering Research and Development] [BASF Ludwigshafen (Germany). Engineering Research and Development; Schembecker, G.; Simmrock, K.H. [Univ. of Dortmund (Germany). Dept. of Chemical Engineering] [Univ. of Dortmund (Germany). Dept. of Chemical Engineering

1997-08-01T23:59:59.000Z

271

Specificationbased Testing of Reactive Software: A Case Study in Technology Transfer  

E-Print Network (OSTI)

Specification­based Testing of Reactive Software: A Case Study in Technology Transfer Lalita be effective in practice. The case study illustrates that technology transfer efforts can benefit from that limit formal methods technology transfer. We also found that there is often a tension between the scope

Porter, Adam

272

Self-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy  

E-Print Network (OSTI)

investigated on the epitaxy and self- organization of laterally nanostructured transition metal TM silicideSelf-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy L to be a flexible and a convenient method for the preparation of dense arrays of Co silicide quantum dots

Ortega, Enrique

273

TRACER DETECTION TECHNOLOGY CORP. PRODUCTS AND SERVICES FOR CORPORATE AND GOVERNMENT SECURITY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

TRACER DETECTION TECHNOLOGY CORP. TRACER DETECTION TECHNOLOGY CORP. PRODUCTS AND SERVICES FOR CORPORATE AND GOVERNMENT SECURITY 3463 MAGIC DRIVE, SUITE T-19 SAN ANTONIO, TX 78229 March 29, 2009 Office of the Assistant General Counsel for Technology Transfer and Intellectual Property U.S. Department of Energy 1000 Independence Ave., SW. Washington, DC 20585. GC-62@hq.doe.gov ATTN: TECHNOLOGY TRANSFER QUESTIONS. Response to Request for Information - Federal Register "The Costs and Benefits of Dealing with Federal Laboratories" This "white paper" is intended to deal constructively with issues relating to technology transfer and interaction of small businesses with federal laboratories, and should be considered a response to #6 (other). As a small businessman and entrepreneur engaged in the

274

TRACER DETECTION TECHNOLOGY CORP. PRODUCTS AND SERVICES FOR CORPORATE AND GOVERNMENT SECURITY  

NLE Websites -- All DOE Office Websites (Extended Search)

TRACER DETECTION TECHNOLOGY CORP. TRACER DETECTION TECHNOLOGY CORP. PRODUCTS AND SERVICES FOR CORPORATE AND GOVERNMENT SECURITY 3463 MAGIC DRIVE, SUITE T-19 SAN ANTONIO, TX 78229 March 29, 2009 Office of the Assistant General Counsel for Technology Transfer and Intellectual Property U.S. Department of Energy 1000 Independence Ave., SW. Washington, DC 20585. GC-62@hq.doe.gov ATTN: TECHNOLOGY TRANSFER QUESTIONS. Response to Request for Information - Federal Register "The Costs and Benefits of Dealing with Federal Laboratories" This "white paper" is intended to deal constructively with issues relating to technology transfer and interaction of small businesses with federal laboratories, and should be considered a response to #6 (other). As a small businessman and entrepreneur engaged in the

275

Evaluation of Tracers for Use in the International Field Experiment on CO2 Ocean Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracers for Use in the International Field Experiment Tracers for Use in the International Field Experiment on CO 2 Ocean Sequestration E. Eric Adams (eeadams@mit.edu; 617-253-6595) Dept. of Civil and Environmental Engineering Massachusetts Institute of Technology Cambridge, MA 02139 USA Introduction An international field experiment is scheduled to take place off of the west coast of the big island of Hawaii during the second half of 2001 (Adams, et al., 1999; Herzog, et al., 2000). Scientists representing some dozen institutions in five countries on four continents are expected to participate. The experiment will involve several sub-experiments in which CO 2 will be released at a depth of 800 m as a buoyant liquid at rates of 0.1 to 1.0 kg/s. The releases will each be made for a duration of about one hour using nozzles with differing diameters and numbers of ports.

276

Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform in Houston, Texas: Trends and Tracers  

E-Print Network (OSTI)

and traffic counts except during variable working hours. To assign measured fluxes to local sources, we tested a bulk flux footprint model (Kormann and Meixner model) designed for uniform emission surface areas in this urban, heterogeneous landscape. Tracer...

Hale, Martin C

2014-05-08T23:59:59.000Z

277

Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Peer Review 2010 - Presentation. This objective of this project is to develop an innovative approach to estimate fracture surface area and spacing through interpretation of signals of natural chemical and isotopic tracers.

278

Field studies of streamflow generation using natural and injected tracers on Bickford and Walker Branch Watersheds  

SciTech Connect

Field studies of streamflow generation were undertaken on two forested watersheds, the West Road subcatchment of Bickford Watershed in central Massachusetts and the West Fork of Walker Branch Watershed in eastern Tennessee. A major component of the research was development of a two-stage methodology for the use of naturally-occurring {sup 222}Rn as a tracer. The first of the two stages was solving a mass-balance equation for {sup 222}Rn around a stream reach of interest in order to calculate Rn{sub q}, the {sup 222}Rn content of the lateral inflow to the reach; a conservative tracer (chloride) and a volatile tracer (propane) were injected into the study stream to account for lateral inflow to, and volatilization from, the study reach. The second stage involved quantitative comparison of Rn{sub q} to the measured {sup 222}Rn concentrations of different subsurface waters in order to assess how important these waters were in contributing lateral inflow to the stream reach.

Genereux, D.; Hemond, H. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Civil Engineering); Mulholland, P. (Oak Ridge National Lab., TN (United States))

1992-05-01T23:59:59.000Z

279

Comparison of observed and predicted short-term tracer gas concentrations in the atmosphere  

SciTech Connect

The Savannah River Laboratory is in the process of conducting a series of atmospheric tracer studies. The inert gas sulfurhexafluoride is released from a height of 62 m for 15 min and concentrations in air are measured on sampling arcs up to 30 km downwind of the release point. Maximum 15 min. air concentrations from 14 of these tracer tests have been compared with the ground-level, centerline air concentration predicted with a Gaussian plume atmospheric transport model using eight different sets of atmospheric dispersion parameters. Preliminary analysis of the results from these comparisons indicates that the dispersion parameters developed at Juelich, West Germany, based on tracers released from a height of 50 m, give the best overall agreement between the predicted and observed values. The median value of the ratio of predicted to observed air concentrations for this set of parameters is 1.3, and the correlation coefficient between the log of the predictions and the log of the observations is 0.72. For the commonly used Pasquill-Gifford dispersion parameters, the values of these same statistics are 4.4 and 0.68, respectively. The Gaussian plume model is widely used to predict air concentrations resulting from short-term radionuclide release to the atmosphere. The results of comparisons such as these must be considered whenever the Gaussian model is used for such purposes. 22 references, 3 tables.

Cotter, S.J.; Miller, C.W.; Lin, W.C.T.

1985-01-01T23:59:59.000Z

280

High-resolution stratospheric tracer fields estimated from satellite observations using Lagrangian trajectory calculations  

SciTech Connect

A technique is introduced by which high-resolution tracer fields may be constructed from low-resolution satellite observations. The technique relies upon the continual cascade of tracer variance from large to small scales and makes use of wind fields generated by a data assimilation scheme. To demonstrate its usefulness, the technique has been applied in a study of isentropic distributions of nitrous oxide in the winter midstratosphere, using measurements made by the Improved Stratospheric and Mesospheric Sounder (ISAMS) instrument on the Upper Atmosphere Research Satellite (UARS). The results show that the high-resolution fields significantly increase the amount of information that is available from the satellite observations. The fields give insights into the characteristic structure and evolution of tracer distributions at scales that are normally obscured from view. Two results are particularly noteworthy. First, at the interface between low and middle latitudes there is evidence of active mixing. This mixing occurs on the eastern, equatorward side of air that is being drawn toward high latitudes around the polar vortex. Second, in the anticyclone, a complex pattern of transport is revealed. Air drawn in from low latitudes spirals together with ambient midlatitude air. Small scales are generated relatively slowly in the organized flow, and persistent filamentary structures, with transverse scales of hundreds of kilometers or greater, are seen.

Sutton, R.T.; Maclean, H.; Swinbank, R.; O`Neill, A.; Taylor, F.W. [Oxford Univ., Oxford (United Kingdom)] [Oxford Univ., Oxford (United Kingdom); [Meteorological Office, Bracknell, Berkshire (United Kingdom); [Univ. of Reading, Reading (United Kingdom)

1994-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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281

Reactivity control assembly for nuclear reactor. [LMFBR  

DOE Patents (OSTI)

This invention, which resulted from a contact with the United States Department of Energy, relates to a control mechanism for a nuclear reactor and, more particularly, to an assembly for selectively shifting different numbers of reactivity modifying rods into and out of the core of a nuclear reactor. It has been proposed heretofore to control the reactivity of a breeder reactor by varying the depth of insertion of control rods (e.g., rods containing a fertile material such as ThO/sub 2/) in the core of the reactor, thereby varying the amount of neutron-thermalizing coolant and the amount of neutron-capturing material in the core. This invention relates to a mechanism which can advantageously be used in this type of reactor control system.

Bollinger, L.R.

1982-03-17T23:59:59.000Z

282

REACTIVITY OF ANIONS IN INTERSTELLAR MEDIA: DETECTABILITY AND APPLICATIONS  

SciTech Connect

We propose a general rule to distinguish between detectable and undetectable astronomical anions. We believe that only few anions live long enough in the interstellar medium and thus can be detected. Our method is based on quantum mechanical calculations capable of describing accurately the evolution of electronic states during chemical processes. The still not fully understood reactivity at low temperatures is discussed considering non-adiabatic effects. The role of excited states has usually been neglected in previous works which basically focused on the ground electronic state for interpretations of experimental observations. Here, we deal with unsaturated carbon chains (e.g., C{sub n} H{sup -}), which show a high density of electronic states close to their corresponding ground electronic states, complex molecular dynamics, and non-adiabatic phenomena. Our general rule shows that it is not sufficient that anions exist in the gas phase (in the laboratory) to be present in media such as astrophysical media, since formation and decomposition reactions of these anions may allow the population of anionic electronic states to autodetach, forming neutrals. For C{sub n} H, reactivity depends strongly on n, where long and short chains behave differently. Formation of linear chains is relevant.

Senent, M. L. [Departamento de Quimica y Fisica Teoricas, Instituto de Estructura de la Materia, IEM-C.S.I.C., Serrano 121, Madrid E-28006 (Spain); Hochlaf, M., E-mail: senent@iem.cfmac.csic.es, E-mail: hochlaf@univ-mlv.fr [Laboratoire de Modelisation et Simulation Multi Echelle, Universite Paris-Est, MSME UMR 8208 CNRS, 5 boulevard Descartes, F-77454 Marne-la-Vallee (France)

2013-05-01T23:59:59.000Z

283

A semi-analytical model for heat and mass transfer in geothermal reservoirs to estimate fracture surface-are-to-volume ratios and thermal breakthrough using thermally-decaying and diffusing tracers  

SciTech Connect

A semi-analytical model was developed to conduct rapid scoping calculations of responses of thermally degrading and diffusing tracers in multi-well tracer tests in enhanced geothermal systems (EGS). The model is based on an existing Laplace transform inversion model for solute transport in dual-porosity media. The heat- and mass-transfer calculations are decoupled and conducted sequentially, taking advantage of the fact that heat transfer between fractures and the rock matrix is much more rapid than mass transfer and therefore mass transfer will effectively occur in a locally isothermal system (although the system will be nonisothermal along fracture flow pathways, which is accounted for by discretizing the flow pathways into multiple segments that have different temperature histories). The model takes advantage of the analogies between heat and mass transfer, solving the same governing equations with k{sub m}/({rho}C{sub p}){sub w} being substituted for {phi}D{sub m} in the equation for fracture transport and k{sub m}/({rho}C{sub p}){sub m} being subsituted for D{sub m} in the equation for matrix transport; where k = thermal conductivity (cal/cm-s-K), {rho} = density (g/cm{sup 3}), C{sub p} = heat capacity (at constant pressure) (cal/g-K), {phi} = matrix porosity, and D = tracer diffusion coefficient (cm{sup 2}/s), with the subscripts w and m referring to water and matrix, respectively. A significant advantage of the model is that it executes in a fraction of second on a single-CPU personal computer, making it very amenable for parameter estimation algorithms that involve repeated runs to find global minima. The combined thermal-mass transport model was used to evaluate the ability to estimate when thermal breakthrough would occur in a multi-well EGS configuration using thermally degrading tracers. Calculations were conducted to evaluate the range of values of Arrhenius parameters, A and E{sub {alpha}} (pre-exponential factor, 1/s, and activation energy, cal/mol) required to obtain interpretable responses of thermally-degrading tracers that decay according to the rate constant k{sub d} = Ae{sup -E{sub {alpha}}/RT}, where k{sub d} = decay rate constant (1/s), R = ideal gas constant (1.987 cal/mol-K), and T = absolute temperature (K). It is shown that there are relatively narrow ranges of A and E{sub {alpha}} that will result in readily interpretable tracer responses for any given combination of ambient reservoir temperature and working fluid residence time in a reservoir. The combined model was also used to simulate the responses of conservative tracers with different diffusion coefficients as a way of estimating fracture surface-area-to-volume ratios (SA/V) in multi-well EGS systems. This method takes advantage of the fact that the differences in breakthrough curves of tracers with different matrix diffusion coefficients are a function of SA/V. The model accounts for differences in diffusion coefficients as a function of temperature so that tracer responses obtained at different times can be used to obtain consistent estimates of SA/V as the reservoir cools down. Some single-well applications of this approach are simulated with a numerical model to demonstrate the potential to evaluate the effectiveness of EGS stimulations before a second well is drilled.

Reimus, Paul W [Los Alamos National Laboratory

2010-12-08T23:59:59.000Z

284

Quantification of multiple methane emission sources at landfills using a double tracer technique  

SciTech Connect

Research highlights: > Precise and reliable measurements of emissions from landfills are needed. > A tracer technique involving simultaneous release of two tracers was proven successful. > Measurements to be performed at times with low changing trends in barometric pressure. - Abstract: A double tracer technique was used successfully to quantify whole-site methane (CH{sub 4}) emissions from Fakse Landfill. Emissions from different sections of the landfill were quantified by using two different tracers. A scaled-down version of the tracer technique measuring close-by to localized sources having limited areal extent was also used to quantify emissions from on-site sources at the landfill facility, including a composting area and a sewage sludge storage pit. Three field campaigns were performed. At all three field campaigns an overall leak search showed that the CH{sub 4} emissions from the old landfill section were localized to the leachate collection wells and slope areas. The average CH{sub 4} emissions from the old landfill section were quantified to be 32.6 {+-} 7.4 kg CH{sub 4} h{sup -1}, whereas the source at the new section was quantified to be 10.3 {+-} 5.3 kg CH{sub 4} h{sup -1}. The CH{sub 4} emission from the compost area was 0.5 {+-} 0.25 kg CH{sub 4} h{sup -1}, whereas the carbon dioxide (CO{sub 2}) and nitrous oxide (N{sub 2}O) flux was quantified to be in the order of 332 {+-} 166 kg CO{sub 2} h{sup -1} and 0.06 {+-} 0.03 kg N{sub 2}O h{sup -1}, respectively. The sludge pit located west of the compost material was quantified to have an emission of 2.4 {+-} 0.63 kg h{sup -1} CH{sub 4}, and 0.03 {+-} 0.01 kg h{sup -1} N{sub 2}O.

Scheutz, C., E-mail: chs@env.dtu.dk [Department of Environmental Engineering, Technical University of Denmark, Miljovej, Building 113, 2800 Kongens Lyngby (Denmark); Samuelsson, J., E-mail: jerker.samuelsson@fluxsense.se [Chalmers University of Technology/FluxSense AB, SE-412 96 Goeteborg (Sweden); Fredenslund, A.M., E-mail: amf@env.dtu.dk [Department of Environmental Engineering, Technical University of Denmark, Miljovej, Building 113, 2800 Kongens Lyngby (Denmark); Kjeldsen, P., E-mail: pk@env.dtu.dk [Department of Environmental Engineering, Technical University of Denmark, Miljovej, Building 113, 2800 Kongens Lyngby (Denmark)

2011-05-15T23:59:59.000Z

285

Isotopic Tracers for Biogeochemical Processes and Contaminant Transport: Hanford, Washington  

SciTech Connect

Our goal is to use isotopic measurements to understand how contaminants are introduced to and stored in the vadose zone, and what processes control migration from the vadose zone to groundwater and then to surface water. We have been using the Hanford Site in south-central Washington as our field laboratory, and our investigations are often stimulated by observations made as part of the groundwater monitoring program and vadose zone characterization activities. Understanding the transport of contaminants at Hanford is difficult due to the presence of multiple potential sources within small areas, the long history of activities, the range of disposal methods, and the continuing evolution of the hydrological system. Observations often do not conform to simple models, and cannot be adequately understood with standard characterization approaches, even though the characterization activities are quite extensive. One of our objectives is to test the value of adding isotopic techniques to the characterization program, which has the immediate potential benefit of addressing specific remediation issues, but more importantly, it allows us to study fundamental processes at the scale and in the medium where they need to be understood. Here we focus on two recent studies at the waste management area (WMA) T-TX-TY, which relate to the sources and transport histories of vadose zone and groundwater contamination and contaminant fluid-sediment interaction. The WMA-T and WMA-TX-TY tank farms are located within the 200 West Area in the central portion of the Hanford Site (Fig. 2). They present a complicated picture of mixed groundwater plumes of nitrate, {sup 99}Tc, Cr{sup 6+}, carbon tetrachloride, etc. and multiple potential vadose zone sources such as tank leaks and disposal cribs (Fig. 3). To access potential vadose zone sources, we analyzed samples from cores C3832 near tank TX-104 and from C4104 near tank T-106. Tank T-106 was involved in a major event in 1973 in which 435,000 L of high activity waste leaked to the vadose zone over a seven-week period. Other nearby tanks (T-103 and T-101) are also suspected of having leaked or overfilled. Pore water from these cores was analyzed for U and Sr isotopic compositions. Increasing {sup 99}Tc concentration in monitoring well 299-W11-39 (to 27,000 pCi/L in 2005) near the northeast corner of the WMA-T area prompted the emplacement of a series of new wells, 299-W11-25B, W11-45 (down gradient), and W11-47 (Fig. 3), during which depth discrete samples were collected below the groundwater surface. The depth profile from W11-25B revealed high {sup 99}Tc concentrations peaking at 182,000 pCi/L at {approx}10 m below the water table (Dresel et al. 2006). We obtained aliquots for isotopic analysis of groundwater samples produced by purge-and-pump sampling during the drilling of W11-25B, -45 and -47. In addition we have analyzed groundwater samples from monitoring wells in the vicinity of WMA T-TX-TY.

Donald J. DePaolo; John N. Christensen; Mark E. Conrad; and P. Evan Dresel

2007-04-19T23:59:59.000Z

286

Anode reactive bleed and injector shift control strategy  

DOE Patents (OSTI)

A system and method for correcting a large fuel cell voltage spread for a split sub-stack fuel cell system. The system includes a hydrogen source that provides hydrogen to each split sub-stack and bleed valves for bleeding the anode side of the sub-stacks. The system also includes a voltage measuring device for measuring the voltage of each cell in the split sub-stacks. The system provides two levels for correcting a large stack voltage spread problem. The first level includes sending fresh hydrogen to the weak sub-stack well before a normal reactive bleed would occur, and the second level includes sending fresh hydrogen to the weak sub-stack and opening the bleed valve of the other sub-stack when the cell voltage spread is close to stack failure.

Cai, Jun [Rochester, NY; Chowdhury, Akbar [Pittsford, NY; Lerner, Seth E [Honeoye Falls, NY; Marley, William S [Rush, NY; Savage, David R [Rochester, NY; Leary, James K [Rochester, NY

2012-01-03T23:59:59.000Z

287

Properties of Reactive Oxygen Species by Quantum Monte Carlo  

E-Print Network (OSTI)

The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of Chemistry, Biology and Atmospheric Science. Nevertheless, the electronic structure of such species is a challenge for ab-initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as $N^3-N^4$, where $N$ is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

Andrea Zen; Bernhardt L. Trout; Leonardo Guidoni

2014-03-11T23:59:59.000Z

288

Reactive sticking coefficients of silane on silicon  

SciTech Connect

Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition rate measurements using molecular beam scattering and a very low pressure cold wall reactor. The RSCs have non-Arrhenius temperature dependences and decreases with increasing flux at low (710/sup 0/) temperatures. A simple model involving dissociative adsorption of silane is consistent with these results. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1988-09-15T23:59:59.000Z

289

Theoretical and Experimental Evaluation of Chemical Reactivity  

E-Print Network (OSTI)

released and the rate of energy released for a specific reactive chemical. 2.1 DSC DSC is a popular screening tool (safe and fast) and can provide an overall indication of exothermic activity of the chemical being tested. In a DSC, a sample and a... endothermic or exothermic reaction. When the rate of heat generation in the sample exceeds a particular value, the heat supply to the sample is cut off and this additional heat gain is attributed to exothermic activity within the sample.17 From the DSC...

Wang, Qingsheng

2011-10-21T23:59:59.000Z

290

Preparation of reactive beta-dicalcium silicate  

DOE Patents (OSTI)

This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane and hydrogen, at a temperature of about 850.degree.-1000.degree. C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

Shen, Ming-Shing (Laramie, WY, NJ); Chen, James M. (Rahway, NJ); Yang, Ralph T. (Amherst, NY)

1982-01-01T23:59:59.000Z

291

A new statistical dispersion model for tracer tests and contaminant spread in porous media  

SciTech Connect

Dispersion of solutes moving in permeable media is an essential control to describe fluid flow in permeable media. Dispersion can be thought of as a spreading of a solute caused by the presence of microscopic inhomogeneities. An accurate model for dispersion is needed for accurate estimation of oil recovery efficiencies and clean up costs of subsurface contaminants. Current approaches utilizing the fickian assumption fall short in describing the real physics of spreading during a solute transport process. Numerous field investigations have shown that dispersivities measured in the field are much larger than those measured in the lab for the same type of porous material. Moreover, field measured dispersivities have been shown to be scale dependent, that is, a tracer test conducted over a longer travel path will yield a larger dispersivity value than a tracer test conducted in the same geologic formation over a shorter travel path. Numerous approaches to address this problem have been developed yet none attempted to go beyond the Fickian dispersion assumption. In this study, a convective dispersivity is introduced. New model assumes that dispersion is dimensionless and mainly determined by pore size distribution. The new model results in a spread that increases linearly with time contrary to conventional model, which predicts a mixing zone length that increases with square root of time. Therefore, new model explains the field test results that indicate increasing dispersivity with distance. The model validations are in perfect agreement with experimental results, which include; Ganapathy et al.`s slug experiment on Antolini sandstone, Handy`s radioactive tracer experiment on Alhambra sandstone, and CT experiment conducted at BDM-OK/NIPER facilities on Tallant sandstone.

Ates, H.; Kasap, E. [Univ. of Tulsa, OK (United States)

1995-12-31T23:59:59.000Z

292

Atmospheric reactivity of gaseous dimethyl sulfate  

SciTech Connect

The atmospheric reactivity of dimethyl sulfate (DMS) with a series of atmospheric species has been investigated. Upper limits to the rate constants for the homogeneous gas-phase reactions of DMS with O{sub 3}, NH{sub 3}, and H{sub 2}O have been determined by using FTIR spectroscopy and are <1.4 {times} 10{sup {minus}21}, <1.5 {times} 10{sup {minus}21}, and <1.1 {times} 10{sup {minus}23} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. The reactivity of DMS toward ON radicals and Cl atoms has been determined by using relative rate techniques, and the rate constants for those reactions are <5 {times} 10{sup {minus}13} and (4.2 {plus minus} 0.5) {times} 10{sup {minus}13} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. These rate constants correspond to atmospheric lifetimes ranging from >23 days with respect to reaction with OH radicals to >33 years with respect to reaction with ozone. With the possible exception of its reaction with water, for which the calculated lifetime of DMS is >2 days, these results indicate that the atmospheric fate of DMS is not determined by its homogeneous gas-phase reactions with any of the atmosphere species studied.

Japar, S.M.; Wallington, T.J.; Andino, J.M.; Ball, J.C. (Ford Motor Co., Dearborn, MI (USA))

1990-03-01T23:59:59.000Z

293

Measurement of VOC reactivities using a photochemical flow reactor  

SciTech Connect

A commercial ambient air monitoring instrument, the Airtrak 2000, has been modified for use as a photochemical flow reactor and used to measure the absolute and incremental reactivity of 18 single test VOCs and the incremental reactivity of six multicomponent VOC mixtures. A flow technique is a useful supplement to traditional static chamber experiments. The static chamber technique involves periodic sampling of an irradiated mixture in a photochemical chamber. Under these conditions, the irradiated mixture is always in transition. Using a flow system, a steady-state condition is established within the flow reactor that is representative, in this case, of the early stages of the smog forming process in the atmosphere. The measurement technique also allows changes in the background chamber reactivity to be monitored and taken into account. The incremental reactivity of 13 of the 18 test compounds measured is compared with previously reported results from a static chamber experiment, and the two data sets are generally in good agreement. The additivity of reactivity was tested by measuring the incremental reactivity of six multicomponent mixtures, the components being compounds measured individually in this study. The measured reactivity of a mixture was compared to that calculated from the sum of the measured reactivity of the mixture`s individual components. The results show that reactivity is additive for the concentration range studied.

Hurley, M.D.; Chang, T.Y.; Japar, S.M.; Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.] [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.

1998-07-01T23:59:59.000Z

294

Reactive Dehydration technology for Production of Fuels and Chemicals...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based chemicals from complex aqueous mixtures. SeparationPurification of Biomass...

295

Airborne measurement of OH reactivity during INTEX-B  

E-Print Network (OSTI)

plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

2009-01-01T23:59:59.000Z

296

Reactive Landing of Peptide Ions on Self-Assembled Monolayer...  

NLE Websites -- All DOE Office Websites (Extended Search)

were characterized ex situ using time of flight-secondary ion mass spectrometry (TOF-SIMS) and infrared reflection absorption spectroscopy (IRRAS). We demonstrate that reactive...

297

Probing the structure and reactivity of gaseous ions.  

E-Print Network (OSTI)

??Studying ions in the gas phase provides the opportunity to observe their intrinsic structure and reactivity without extraneous perturbations such as solvent effects, aggregation or (more)

Meyer, Matthew Michael

2010-01-01T23:59:59.000Z

298

Chemically Reactive Working Fluids for the Capture and Transport...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working Fluids Low-Cost Light Weigh Thin Film Solar Concentrators...

299

Physical Organic Chemistry of Reactive Intermediates | The Ames...  

NLE Websites -- All DOE Office Websites (Extended Search)

Physical Organic Chemistry of Reactive Intermediates The Jenks group specializes in physical organic chemistry, the "how" of organic reactions. Much of the work has centered on...

300

Chemical Analysis of Complex Organic Mixtures Using Reactive...  

NLE Websites -- All DOE Office Websites (Extended Search)

Mass Spectrometry. Abstract: Reactive nanospray desorption electrospray ionization (nano-DESI) combined with high-resolution mass spectrometry was utilized for the analysis of...

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

A method for activation analysis of ruthenium in sea water  

E-Print Network (OSTI)

of these isotopes in the marine environment, it is essential that a method for the analysis of trace amounts of stable ruthenium be developed, and applied to the study of the chemical and physical dis- tribution of ruthenium in sea water, marine biota... 100 27. 2 82 34. 8 100 30. 2 91 30. 6 92 26. 9 81 8 (Tracer Only) 34. 5 100 Standard 33. 3 Average Counting time ? Eorty minutes 103 Tracer ? Ru 93 Stable ruthenium added ? 0. Z6 ug 14 TABLE 4 Nuclear Data for Ruthenium Isotope Per Cent...

Dixon, Bryan William

2012-06-07T23:59:59.000Z

302

Neural network approaches to tracer identification as related to PIV research  

SciTech Connect

Neural networks have become very powerful tools in many fields of interest. This thesis examines the application of neural networks to another rapidly growing field flow visualization. Flow visualization research is used to experimentally determine how fluids behave and to verify computational results obtained analytically. A form of flow visualization, particle image velocimetry (PIV). determines the flow movement by tracking neutrally buoyant particles suspended in the fluid. PIV research has begun to improve rapidly with the advent of digital imagers, which can quickly digitize an image into arrays of grey levels. These grey level arrays are analyzed to determine the location of the tracer particles. Once the particles positions have been determined across multiple image frames, it is possible to track their movements, and hence, the flow of the fluid. This thesis explores the potential of several different neural networks to identify the positions of the tracer particles. Among these networks are Backpropagation, Kohonen (counter-propagation), and Cellular. Each of these algorithms were employed in their basic form, and training and testing were performed on a synthetic grey level array. Modifications were then made to them in attempts to improve the results.

Seeley, C.H. Jr.

1992-12-01T23:59:59.000Z

303

Discrete sliding mode control strategy for direct real and reactive power regulation of wind driven DFIG  

Science Journals Connector (OSTI)

Abstract This paper investigates a discrete sliding mode control (DSMC) strategy for direct real and reactive power regulation for wind driven doubly fed induction generator (DFIG). The real and reactive power errors are eliminated by directly calculating the rotor control voltages through DSMC. In the stator stationary reference frame, direct real and reactive power control strategy is implemented. Therefore, it does not require the angular information of the stator and rotor currents or voltages. It does not involve any extra current loops which results into simple design. The use of constant converter switching frequency via space vector pulse width modulation eases the AC harmonic filter design and improves the power quality. The use of fast and flexible discrete controller makes the system competent with modern digital world. Detailed simulations have been carried out to validate the method. The simulation results reveal that the real and reactive power references are followed smoothly even in the presence of speed perturbations and performance of the system is robust against parameter variations and system disturbances.

V.N. Pande; U.M. Mate; Shailaja Kurode

2013-01-01T23:59:59.000Z

304

Lattice Boltzmann simulations of phase separation in chemically reactive binary fluids  

E-Print Network (OSTI)

We use a lattice Boltzmann method to study pattern formation in chemically reactive binary fluids in the regime where hydrodynamic effects are important. The coupled equations solved by the method are a Cahn-Hilliard equation, modified by the inclusion of a reactive source term, and the Navier-Stokes equations for conservation of mass and momentum. The coupling is two-fold, resulting from the advection of the order-parameter by the velocity field and the effect of fluid composition on pressure. We study the the evolution of the system following a critical quench for a linear and for a quadratic reaction source term. Comparison is made between the high and low viscosity regimes to identify the influence of hydrodynamic flows. In both cases hydrodynamics is found to influence the pathways available for domain growth and the eventual steady-states.

K. Furtado; J. M. Yeomans

2006-05-31T23:59:59.000Z

305

XCHEM-1D: A Heat Transfer/Chemical Kinetics Computer Program for multilayered reactive materials  

SciTech Connect

An eXplosive CHEMical kinetics code, XCHEM, has been developed to solve the reactive diffusion equations associated with thermal ignition of energetic materials. This method-of-lines code uses stiff numerical methods and adaptive meshing to resolve relevant combustion physics. Solution accuracy is maintained between multilayered materials consisting of blends of reactive components and/or inert materials. Phase change and variable properties are included in one-dimensional slab, cylindrical and spherical geometries. Temperature-dependent thermal properties have been incorporated and the modification of thermal conductivities to include decomposition effects are estimated using solid/gas volume fractions determined by species fractions. Gas transport properties, including high pressure corrections, have also been included. Time varying temperature, heat flux, convective and thermal radiation boundary conditions, and layer to layer contact resistances have also been implemented.

Gross, R.J.; Baer, M.R.; Hobbs, M.L.

1993-10-01T23:59:59.000Z

306

Challenges in the Theoretical Description of Nanoparticle Reactivity: Nano Zero-Valent Iron  

E-Print Network (OSTI)

The reactivity of iron atoms, clusters and nanoparticles (nZVI) is of increasing interest owing to their important practical applications, ranging from the steel industry to water remediation technologies. Here, we provide an overview of computational methods and models that can be applied to study nZVI reactions and discuss their benefits and limitations. We also report current progress in calculations through recent examples treating the reactivity of nZVI particles. Finally, we consider the potential use of highly accurate methods with favorable scaling (such as quantum Monte Carlo or random phase approximation), which are currently considered too computationally expensive but are expected to become more amenable in the future as computer power increases.

Karlick, Frantiek

2014-01-01T23:59:59.000Z

307

ANN-based reactive power controller with real-time web monitoring  

Science Journals Connector (OSTI)

This study introduced a real-time reactive power controller based on artificial neural network with web-based monitoring. A feed-forward employing back-propagation was used as training technique. The inputs to the network were the active and reactive power of each load. The targets were to switch on/off the capacitor banks during normal and abnormal conditions. The network was trained using developed MATLAB program and the weights resulted to minimum mean-square-error were fed to the microcontroller unit. The method was then tested in a three-bus radial distribution system model and implemented using Zilog microcontroller. The system actions were monitored using web-based monitoring application. The method was validated in actual operation of the system using the test data and results were satisfactorily obtained.

Carl John O. Salaan; Mark Joseph M. Victoria; Noel R. Estoperez

2013-01-01T23:59:59.000Z

308

Instrumentation @ Catalysis: Reactivity and Structure Group | Chemistry  

NLE Websites -- All DOE Office Websites (Extended Search)

Instrumentation Instrumentation The Catalysis Group at BNL is leading research initiatives into the development of new tools and techniques that focus on the characterization of heterogeneous catalytic reactions and catalysts using imaging, spectroscopy and scattering techniques and integrated combinations of them under reaction conditions to unravel the morphology, chemical and structural properties, of catalysts, respectively. These efforts revolve around the use of synchrotron radiation (NSLS), electrons (CFN) and quantum tunneling tools with particular thrusts into imaging, spectroscopy and scattering. Groups Instrumentation(BNL) Three UHV chambers with diverse instrumentation for surface characterization: LEED, UPS, XPS, AES, TPD, ISS, PM-AP-IRRAS, Reactivity Cell. All the systems include ancillary instrumentation such as sputtering guns and metal evaporators. The IRRAS system was retrofitted with an ambient pressure (AP) cell on top of the UHV system. The sample can be prepared and characterized in UHV and then transfer in vacuum to the AP cell.

309

Review of existing reactive transport software  

SciTech Connect

Simulations of thermal and hydrological evolution following the potential emplacement of a subterranean nuclear waste repository at Yucca Mountain, NV provide data that suggest the inevitability of dependent, simultaneous chemical evolution in this system. These chemical changes will modify significantly both the magnitude and structure of local porosity and permeability; hence, they will have a dynamic feedback effect on the evolving thermal and hydrological regime. Yet, despite this intimate interdependence of transport and chemical processes, a rigorous quantitative analysis of the post- emplacement environment that incorporates this critical feedback mechanism has not been completed to date. As an initial step in this direction, the present document outlines the fundamental chemical and transport processes that must be accounted for in such an analysis, and reviews the inventory of existing software that encodes these processed in explicitly coupled form. A companion report describes the prioritization of specific capabilities that are needed for modeling post-emplacement reactive transport at Yucca Mountain.

Glassley, W., LLNL

1998-02-03T23:59:59.000Z

310

The Post-Shock Chemical Lifetimes of Outflow Tracers and a Possible New Mechanism to Produce Water Ice Mantles  

E-Print Network (OSTI)

We have used a coupled time-dependent chemical and dynamical model to investigate the lifetime of the chemical legacy left in the wake of C-type shocks. We concentrate this study on the chemistry of H2O and O2, two molecules which are predicted to have abundances that are significantly affected in shock-heated gas. Two models are presented: (1) a three-stage model of pre-shock, shocked, and post-shock gas; and (2) a Monte-Carlo cloud simulation where we explore the effects of stochastic shock activity on molecular gas over a cloud lifetime. In agreement with previous studies, we find that shock velocities in excess of 10 km s^-1 are required to convert all of the oxygen not locked in CO into H2O before the gas has an opportunity to cool. For pure gas-phase models the lifetime of the high water abundances, or ``H2O legacy'', in the post-shock gas is 4 - 7 x 10^5 years. Through the Monte Carlo cloud simulation we demonstrate that the time-average abundance of H2O is a sensitive function of the frequency of shocks. Thus we predict that the abundance of H2O and other known outflow tracers can be used to trace the history of shock activity in molecular gas. For gas-grain models we find that the abundance of water-ice on grain surfaces can be quite large and is comparable to that observed in molecular clouds. This offers a possible alternative method to create water mantles without resorting to grain surface chemistry: gas heating and chemical modification due to a C-type shock and subsequent depletion of the gas-phase species onto grain mantles.

Edwin A. Bergin; Gary J. Melnick; David A. Neufeld

1998-03-30T23:59:59.000Z

311

A Learning-Based Approach to Reactive Security  

E-Print Network (OSTI)

Terms--Reactive security, risk management, attack graphs, online learning, adversarial learning, game vulnerability is plugged, CISOs typically perform a cost- benefit analysis to identify which risks to address of reactive strategies in an economic model of the CISO's security cost-benefit trade- offs. Unlike previously

Song, Dawn

312

A Reactive Measurement Framework Mark Allman and Vern Paxson  

E-Print Network (OSTI)

A Reactive Measurement Framework Mark Allman and Vern Paxson International Computer Science Institute Abstract. Often when assessing complex network behavior a single measure- ment is not enough for thinking about "measurement" as a process rather than an event. We introduce reactive measurement (REM

Paxson, Vern

313

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network (OSTI)

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

314

A Reactive Control Approach for Pipeline Inspection with an AUV  

E-Print Network (OSTI)

A Reactive Control Approach for Pipeline Inspection with an AUV Pedro K. Paim, Bruno Jouvencel and research activities, performing tasks such as survey, inspection of sub-sea pipelines and object recovery of mission. This paper proposes a reactive control approach for pipeline following by a torpedo- like

Paris-Sud XI, Université de

315

Etching radical controlled gas chopped deep reactive ion etching  

DOE Patents (OSTI)

A method for silicon micromachining techniques based on high aspect ratio reactive ion etching with gas chopping has been developed capable of producing essentially scallop-free, smooth, sidewall surfaces. The method uses precisely controlled, alternated (or chopped) gas flow of the etching and deposition gas precursors to produce a controllable sidewall passivation capable of high anisotropy. The dynamic control of sidewall passivation is achieved by carefully controlling fluorine radical presence with moderator gasses, such as CH.sub.4 and controlling the passivation rate and stoichiometry using a CF.sub.2 source. In this manner, sidewall polymer deposition thicknesses are very well controlled, reducing sidewall ripples to very small levels. By combining inductively coupled plasmas with controlled fluorocarbon chemistry, good control of vertical structures with very low sidewall roughness may be produced. Results show silicon features with an aspect ratio of 20:1 for 10 nm features with applicability to nano-applications in the sub-50 nm regime. By comparison, previous traditional gas chopping techniques have produced rippled or scalloped sidewalls in a range of 50 to 100 nm roughness.

Olynick, Deidre; Rangelow, Ivo; Chao, Weilun

2013-10-01T23:59:59.000Z

316

From Teleo-Reactive specifications to architectural components: A model-driven approach  

Science Journals Connector (OSTI)

The Teleo-Reactive approach designed by N.J. Nilsson offers a high-level programming model that permits the development of reactive systems, such as robotic vehicles. Teleo-Reactive programs are written in a manner that allows engineers to define the ... Keywords: Component-based software development, Model-driven software development, Reactive systems, Robotics, Teleo-Reactive programs

Pedro SNchez; Diego Alonso; Jos Miguel Morales; Pedro Javier Navarro

2012-11-01T23:59:59.000Z

317

First results of operating and monitoring an innovative design of a permeable reactive barrier for the remediation of chromate contaminated groundwater  

Science Journals Connector (OSTI)

An innovative setup of a permeable reactive barrier (PRB) was installed in Willisau, Switzerland to remediate chromate contaminated groundwater. Instead of a conventional continuous barrier, this PRB consists of cylinders installed in rows: a single row for lower expected CrVI-concentrations and an offset double row for higher expected CrVI-concentrations. The cylinders are filled with reactive grey cast-Fe shavings mixed with gravel to prevent extensive precipitation of secondary phases in the pore space. The treatment of the contaminants takes place both within the cylinders and in the dissolved FeII plume generated downstream of the barrier. Monitoring of the contamination situation over a period of 3 a provided evidence of the mobilization, transport and behavior of the contaminants in the aquifer. Groundwater and reactive material were sampled upstream, within and downstream of the barrier by a Multi-Port Sampling System (MPSS) that revealed the geochemical processes as a function of time and space. Comprehensive chemical analyses included sensitive parameters such as CrVI, FeII/FeIII, redox potential, dissolved O2 and pH. Several campaigns using multiple optical tracers revealed a rather complex hydrological regime at different scales, thereby complicating the barrier performance. Results from the large 3D hydrogeochemical dataset show that the double row of cylinders successfully treated the chromate contamination. Remediation by the single row was not effective enough due to insufficient lateral overlap of the cylinders and their FeII-plumes. The low amount of precipitated secondary phases observed in the pore space of the reactive material reduced the risk of clogging the system and suggested a favorable longevity of the barrier. Limiting factors for the long-term operation are inferred to be the availability and accessibility of FeII within the cylinders and the concentration within the generated FeII-plume.

Bettina Flury; Urs Eggenberger; Urs Mder

2009-01-01T23:59:59.000Z

318

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

319

Dynamics of reverse osmosis in a standalone cogenerative nuclear reactor (Part I: reactivity changes)  

Science Journals Connector (OSTI)

The present study considers the dynamic behaviour of the pressurised water reactor safety features, represented by the integrity of the fuel cladding, under some transient cases. A cosine-shaped heating through the fuel is taken with the corresponding coolant lumps, to simulate realistic cases encountered in nuclear reactors. A mathematical model was developed for the Westinghouse 3411 MWth pressurised water reactor, as an example of a familiar design with predominantly published data design. The model consists of two parts. The first part is concerned with the dynamics of the primary side of the reactor, which is described in this paper. The second part is concerned with the secondary side of the plant, which is described elsewhere in this issue. To study the dynamics of the reactor, a model of 17 lumped parameters was used, consisting of first-order differential equations deduced from the first principles considering six groups of delayed neutrons. A computer program was developed using the Runge-Kutta method to solve these equations and to predict the behaviour of the state variables with time. Two case studies were considered as examples for normal transients. The first case study, which represents Part 1 of this study, considers the effect of primary side transient on the system as the reactivity changes. Reactor reactivity changes, including movements of the reactor control rods, which are taken as an example for the effect of the reactor primary side conditions. These reactivity changes vary from 0.0005 up to 0.003, both for positive and negative reactivity. The results of the developed model, which describe the dynamic response of the reactor primary circuit, have been analysed and verified with the relevant models. These results indicate that the reactor components and the integrity of the fuel cladding were attained during different step changes of reactivity.

Aly Karameldin; M.M. Shamloul; M.R. Shaalan; M.H. Esawy

2007-01-01T23:59:59.000Z

320

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures  

E-Print Network (OSTI)

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures Elodie Salmon a , Adri C.T. van Duin b , François Lorant Brown coal using the ReaxFF reactive force field. We find that these reactive MD simulations

Goddard III, William A.

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While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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321

Reactive barriers for {sup 137}Cs retention  

SciTech Connect

{sup 137}Cs was dispersed globally by cold war activities and, more recently, by the Chernobyl accident. Engineered extraction of {sup 137}Cs from soils and groundwaters is exceedingly difficult. Because the half life of {sup 137}Cs is only 30.2 years, remediation might be more effective (and less costly) if {sup 137}Cs bioavailability could be demonstrably limited for even a few decades by use of a reactive barrier. Essentially permanent isolation must be demonstrated in those few settings where high nuclear level wastes contaminated the environment with {sup 135}Cs (half life 2.3x10{sup 6} years) in addition to {sup 137}Cs. Clays are potentially a low-cost barrier to Cs movement, though their long-term effectiveness remains untested. To identify optimal clays for Cs retention Cs resorption was measured for five common clays: Wyoming Montmorillonite (SWy-1), Georgia Kaolinites (KGa-1 and KGa-2), Fithian Illite (F-Ill), and K-Metabentonite (K-Mbt). Exchange sites were pre-saturated with 0.16 M CsCl for 14 days and readily exchangeable Cs was removed by a series of LiNO{sub 3} and LiCl washes. Washed clay were then placed into dialysis bags and the Cs release to the deionized water outside the bags measured. Release rates from 75 to 139 days for SWy-1, K-Mbt and F- 111 were similar; 0.017 to 0.021% sorbed Cs released per day. Both kaolinites released Cs more rapidly (0.12 to 0.05% of the sorbed Cs per day). In a second set of experiments, clays were doped for 110 days and subjected to an extreme and prolonged rinsing process. All the clays exhibited some capacity for irreversible Cs uptake so most soils have some limited ability to act as a natural barrier to Cs migration. However, the residual loading was greatest on K-Mbt ({approximately} 0.33 wt% Cs). Thus, this clay would be the optimal material for constructing artificial reactive barriers.

KRUMHANSL,JAMES L.; BRADY,PATRICK V.; ANDERSON,HOWARD L.

2000-05-19T23:59:59.000Z

322

{sup 41}Ca as a tracer for calcium uptake and deposition in heart tissue during ischemia and reperfusion  

SciTech Connect

We have developed techniques and are commencing experiments using enriched {sup 41}Ca as a tracer in isolated rabbit heart preparations. The aims of the study are to measure calcium uptake and deposition in response to cardiac ischemia and reperfusion, and to investigate events and mechanism leading to irreversible myocyte injury.

Southon, J.R. [Lawrence Livermore National Lab., CA (United States); Bishop, M.S.; Kost, G.J. [California Univ., Davis, CA (United States). Dept. of Medical Pathology and Biomedical Engineering

1993-09-17T23:59:59.000Z

323

Reactive sticking coefficients of silane on silicon  

SciTech Connect

We have investigated the reaction of room-temperature silane and disilane on a hot polycrystalline silicon surface using both a collision-free molecular beam and a very low pressure CVD cell. Reactive sticking coefficients were obtained from deposition rate data over a wide range of temperatures and silane (disilane) fluxes. The RSCs are substantially less than one, ranging from 6 x 10/sup -5/ to 4 x 10/sup -2/. For silane we observed curved Arrhenius plots with slopes decreasing from approx.60 kcal mol/sup -1/ at low temperatures to approx.2 kcal mol/sup -1/ at higher temperatures. The RSCs are independent of flux (pressure) at 1040/sup 0/C, but vary as flux to the approx.-1/2 power at 710/sup 0/C. A model comprised of a dissociative adsorption mechanism with competing associative desorption and reaction was found to give reasonable agreement. For disilane, we observed RSCs that were roughly ten times higher than those for silane. We also observed a curved Arrhenius plot and a flux dependence at 710/sup 0/C for disilane. 22 refs., 5 figs.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1987-01-01T23:59:59.000Z

324

On the estimation of the unknown reactivity coefficients in a CANDU reactor  

Science Journals Connector (OSTI)

A space-time kinetics based inverse architecture method is suggested to analyze the reactivity variations associated with power excursions in a generic CANDU reactor. It is intended to provide diagnosis tools to gain enhanced control thereby ensuring safe operation of the plant. A methodology for analyzing the data available from the in core flux detectors and extracting the unknown reactivity coefficients is presented. The proposed system uses a reference model in conjunction with an optimal estimator. The reference model is composed of a state space representation of the space-time dynamics of neutron flux in the core, based on modal expansion approximation, and a time domain optimal estimator filter. We investigated three different estimation techniques based on recursive prediction error method (RPEM), dual extended Kalman filter (DEKF), and joint extended Kalman filter (JEKF). We compared their applicability to the estimation of coolant-void dynamic reactivity in loss-of-coolant accident in a CANDU reactor. The state equations also include the characteristics of the detector responses. The thermal hydraulic models were not included in the calculations. Two different types of detectors are considered in this analysis, the over prompt responsive Platinum detector of the reactor shutdown systems, and the under delayed responsive Vanadium detector of the flux mapping system.

Lobat Tayebi; Daryoosh Vashaee

2013-01-01T23:59:59.000Z

325

Assessment of sorbent reactivation by water hydration for fluidized bed combustion application  

SciTech Connect

Disposal of fluidized bed combustion (FBC) solid residues currently represents one of the major issues in FBC design and operation, and contributes significantly to its operating cost. This issue has triggered research activities on the enhancement of sorbent utilization for in situ sulfur removal. The present study addresses the effectiveness of the reactivation by liquid water hydration of FB spent sorbents. Two materials are considered in the study, namely the bottom ash from the operation of a full-scale utility FB boiler and the raw commercial limestone used in the same boiler. Hydration-reactivation tests were carried out at temperatures of 40{sup o}C and 80{sup o}C and for curing times ranging from 15 minutes to 2d, depending on the sample. The influence of hydration conditions on the enhancement of sulfur utilization has been assessed. A combination of methods has been used to characterize the properties of liquid water-hydrated materials

Fabio Montagnaro; Piero Salatino; Fabrizio Scala; Yinghai Wu; Edward J. Anthony; Lufei Jia [Universita degli Studi di Napoli Federico II, Complesso Universitario del Monte di Sant'Angelo, Naples (Italy). Dipartimento di Chimica

2006-06-15T23:59:59.000Z

326

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

327

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms...  

NLE Websites -- All DOE Office Websites (Extended Search)

reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally...

328

Metal-Pyrrolide Complexes in Three-fold Symmetry: Synthesis, Structure, Reactivity and Magnetism  

E-Print Network (OSTI)

Structure, Reactivity and Magnetism by William Hill Harman AStructure, Reactivity and Magnetism by William Hill Harmanlost time. Dave taught me magnetism and what it takes to win

Harman, William Hill

2010-01-01T23:59:59.000Z

329

Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene  

E-Print Network (OSTI)

The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement ...

Arizpe, Luis (Luis Alfredo)

2011-01-01T23:59:59.000Z

330

Aging Enhances the Production of Reactive Oxygen Species andBactericid...  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

331

Reactive gases evolved during pyrolysis of Devonian oil shale  

SciTech Connect

Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

1986-11-01T23:59:59.000Z

332

A reaction-based paradigm to model reactive chemical transport in groundwater with general kinetic and equilibrium reactions  

SciTech Connect

This paper presents a reaction-based water quality transport model in subsurface flow systems. Transport of chemical species with a variety of chemical and physical processes is mathematically described by M partial differential equations (PDEs). Decomposition via Gauss-Jordan column reduction of the reaction network transforms M species reactive transport equations into two sets of equations: a set of thermodynamic equilibrium equations representing NE equilibrium reactions and a set of reactive transport equations of M-NE kinetic-variables involving no equilibrium reactions (a kinetic-variable is a linear combination of species). The elimination of equilibrium reactions from reactive transport equations allows robust and efficient numerical integration. The model solves the PDEs of kinetic-variables rather than individual chemical species, which reduces the number of reactive transport equations and simplifies the reaction terms in the equations. A variety of numerical methods are investigated for solving the coupled transport and reaction equations. Simulation comparisons with exact solutions were performed to verify numerical accuracy and assess the effectiveness of various numerical strategies to deal with different application circumstances. Two validation examples involving simulations of uranium transport in soil columns are presented to evaluate the ability of the model to simulate reactive transport with complex reaction networks involving both kinetic and equilibrium reactions.

Zhang, Fan [ORNL; Yeh, Gour-Tsyh [University of Central Florida, Orlando; Parker, Jack C [ORNL; Brooks, Scott C [ORNL; Pace, Molly [ORNL; Kim, Young Jin [ORNL; Jardine, Philip M [ORNL; Watson, David B [ORNL

2007-01-01T23:59:59.000Z

333

Continuous measurements of atmospheric argon/nitrogen as a tracer of air-sea heat flux : models, methods, and data  

E-Print Network (OSTI)

bubble injection (Schudlich and Emerson 1996), supersaturation caused by mixing between two water parcels (curvature-induced supersaturation), the stability

Blaine, Tegan Woodward

2005-01-01T23:59:59.000Z

334

Method of detecting leakage from geologic formations used to sequester CO.sub.2  

DOE Patents (OSTI)

The invention provides methods for the measurement of carbon dioxide leakage from sequestration reservoirs. Tracer moieties are injected along with carbon dioxide into geological formations. Leakage is monitored by gas chromatographic analyses of absorbents. The invention also provides a process for the early leak detection of possible carbon dioxide leakage from sequestration reservoirs by measuring methane (CH.sub.4), ethane (C.sub.2H.sub.6), propane (C.sub.3H.sub.8), and/or radon (Rn) leakage rates from the reservoirs. The invention further provides a method for branding sequestered carbon dioxide using perfluorcarbon tracers (PFTs) to show ownership.

White, Curt (Pittsburgh, PA); Wells, Arthur (Bridgeville, PA); Diehl, J. Rodney (Pittsburgh, PA); Strazisar, Brian (Venetia, PA)

2010-04-27T23:59:59.000Z

335

Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior in Complex Interfacial Systems. Final Technical Report  

SciTech Connect

This research program explored the efficacy of using molecular-level manipulation, imaging and scanning tunneling spectroscopy in conjunction with supersonic molecular beam gas-surface scattering to significantly enhance our understanding of chemical processes occurring on well-characterized interfaces. One program focus was on the spatially-resolved emergent behavior of complex reaction systems as a function of the local geometry and density of adsorbate-substrate systems under reaction conditions. Another focus was on elucidating the emergent electronic and related reactivity characteristics of intentionally constructed single and multicomponent atom- and nanoparticle-based materials. We also examined emergent chirality and self-organization in adsorbed molecular systems where collective interactions between adsorbates and the supporting interface lead to spatial symmetry breaking. In many of these studies we combined the advantages of scanning tunneling (STM) and atomic force (AFM) imaging, scanning tunneling local electronic spectroscopy (STS), and reactive supersonic molecular beams to elucidate precise details of interfacial reactivity that had not been observed by more traditional surface science methods. Using these methods, it was possible to examine, for example, the differential reactivity of molecules adsorbed at different bonding sites in conjunction with how reactivity is modified by the local configuration of nearby adsorbates. At the core of this effort was the goal of significantly extending our understanding of interfacial atomic-scale interactions to create, with intent, molecular assemblies and materials with advanced chemical and physical properties. This ambitious program addressed several key topics in DOE Grand Challenge Science, including emergent chemical and physical properties in condensed phase systems, novel uses of chemical imaging, and the development of advanced reactivity concepts in combustion and catalysis including carbon management. These activities directly benefitted national science objectives in the areas of chemical energy production and advanced materials development.

Sibener, Steven J. [University of Chicago, IL (United States)] [University of Chicago, IL (United States)

2014-03-11T23:59:59.000Z

336

3D Field-Scale Reactive Transport Modeling of In Situ Immobilization of Uranium in Structured Porous Media via Biostimulation  

SciTech Connect

A several-month-long ethanol injection experiment is being conducted to study the impacts of porous media structure (i.e., heterogeneity existing at multiple scales) on the effectiveness of metal/radionuclide bioremediation in a highly heterogeneous unconfined aquifer near Oak Ridge, TN, USA. We have constructed a 3D field-scale groundwater flow and multicomponent reactive transport model to simulate the experimental observations. The model incorporates a suite of abiotic reactions and microbially-mediated redox reactions for multiple terminal electron accepting processes (TEAPs) including soluble oxygen, nitrate, U(VI) and sulfate and solid-phase electron acceptors. Different biomass populations are considered in the model. Growth of these populations is derived from the bioenergetics-based approach in which the partitioning of electron flow between energy generation and cell biomass production is dependent on the free energy of the corresponding TEAP. TEAP reaction rates were free energy constrained. The TEAP model and reaction system have been formulated and used to simulate laboratory batch experimental observations. We conducted the field-scale simulation starting with the reaction system and parameters obtained from the batch experiment and hydrologic parameters estimated from the results of pumping tests, water level monitoring and model interpretation of a tracer test conducted in August 2004. Reaction parameters were investigated to compare simulation results and field experiment observations.

Fang, Yilin; Scheibe, Timothy D.; Roden, Eirc E.; Kamolpornwijit, Wiwat; Brooks, Scott C.

2006-09-12T23:59:59.000Z

337

Photo of the Week: Reactive Ion Etching | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reactive Ion Etching Reactive Ion Etching Photo of the Week: Reactive Ion Etching October 17, 2013 - 1:26pm Addthis Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material structures. In this photo, the drop-like domes were carved through a process called reactive ion etching, which produced the striped bubbles you see in the Laue lens. The prototype in this image helped scientists perfect the process of creating lenses so precise that scientists are able to focus x-rays to within a single nanometer. | Photo courtesy of Brookhaven National Laboratory. Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material

338

Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquids: Reactivity of Primary Species Liquids: Reactivity of Primary Species James F. Wishart In "Ionic Liquids as Green Solvents: Progress and Prospects" Rogers, R. D. and Seddon, K. R. , Eds.; ACS Symp. Ser. 856, Ch. 31, pp. 381-395, American Chemical Society, Washington, DC, 2003. (ISBN 0-84123-856-1) [Information about the book] Abstract: An understanding of the radiation chemistry of ionic liquids is important for development of their applications in radioactive material processing and for the application of pulse radiolysis techniques to the general study of chemical reactivity in ionic liquids. The distribution of primary radiolytic species and their reactivities determine the yields of ultimate products and the radiation stability of a particular ionic liquid. This chapter introduces some principles of radiation chemistry and the

339

Detoxification of hydrolysate by reactive-extraction for generating biofuels  

Science Journals Connector (OSTI)

We introduce a reactive extraction to detoxify hydrolysate before fermentation to biofuels. In the selection of diluents, n-octanol showed the highest removal yield of 5-hydroxymethylfurfural (5-HMF) and levulini...

Gwi-Taek Jeong; Sung-Koo Kim; Don-Hee Park

2013-02-01T23:59:59.000Z

340

Mechanisms of Photochemistry and Reactive Oxygen Production by  

E-Print Network (OSTI)

photosensitizer that produces reactive oxygen species (ROS) in the presence of light; however, its properties medical and environmental contexts as well as the potential applications implied for industrial or water of transferring light energy to chemical oxidation potential in theformof

Alvarez, Pedro J.

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network (OSTI)

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

342

The Safe Storage Study for Autocatalytic Reactive Chemicals  

E-Print Network (OSTI)

In the U.S. Chemical Safety and Hazard Investigation Board (CSB) report, Improving Reactive Hazard Management, there are 37 out of 167 accidents, which occurred in a storage tank or a storage area. This fact demonstrates that thermal runaway...

Liu, Lijun

2010-10-12T23:59:59.000Z

343

Reactive Power Compensation Strategy of DGIF Wind Park  

Science Journals Connector (OSTI)

In this chapter, two different wind park reactive power compensation strategies for the DFIG wind park connected to the sub-transmission level are proposed. Except considering DFIG wind turbines as dynamic reacti...

JingJing Zhao; Yang Fu; DongDong Li

2014-01-01T23:59:59.000Z

344

Evolution of Memory in Reactive Artificial Neural Networks  

E-Print Network (OSTI)

in the context of evolution: how reactive agents could have evolved into cognitive ones with internalized memory? This study strives to find an answer to the question by simulating neuroevolution on artificial neural networks, with the hypothesis...

Chung, Ji Ryang

2012-07-16T23:59:59.000Z

345

Reactive Support and Voltage Control Service: Key Issues and Challenges  

E-Print Network (OSTI)

Reactive Support and Voltage Control Service: Key Issues and Challenges George Gross^, Paolo of Illinois at Urbana-Champaign, Urbana, IL 61801, USA, e-mail gross@uiuc.edu ° Dipartimento di Ingegneria

Gross, George

346

Reactive oxygen species: a breath of life or death?  

E-Print Network (OSTI)

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

347

Local Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network (OSTI)

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the re...

Turitsyn, Konstantin S; Backhaus, Scott; Chertkov, Misha

2010-01-01T23:59:59.000Z

348

Assessing low power reactivity levels in subcritical CANDU reactors  

SciTech Connect

A new technique has been developed for monitoring slow reactivity changes in Canadian deuterium uranium (CANDU) nuclear reactors during low power operation, following a sustained period of high power operation. The power doubling halving worth (PDHW) test tracks slow reactivity changes by evaluating the reactivity perturbation required by the power regulating system to halve and double reactor power over time. During low power operation of a CANDU reactor, the PDHW test is used to monitor the decay of the photoneutron precursors, so that the reactor power can be lowered using a preset amount of reactivity. The PDHW test is described in this paper and is validated by using computer simulations and operating data from a CANDU reactor.

Teare, S.W. [Corporation of the City of Mississauga, Ontario (Canada)] [Corporation of the City of Mississauga, Ontario (Canada); Shanes, F.C. [Ontario Hydro, Toronto, Ontario (Canada)] [Ontario Hydro, Toronto, Ontario (Canada); Hersey, M.W. [Pickering Nuclear Generating Station, Ontario (Canada)] [Pickering Nuclear Generating Station, Ontario (Canada)

1996-08-01T23:59:59.000Z

349

Using CO2 Lidar for Standoff Detection of a Perfluorocarbon Tracer in Air  

SciTech Connect

The Tag, Track and Location System Program (TTL) is investigating the use of PFTs as tracers for tagging and tracking items of interest or fallen soldiers. In order for the tagging and tracking to be valuable there must be a location system that can detect the PFTs. This report details the development of an infrared lidar platform for standoff detection of PFTs released into the air from a tagged object or person. Furthering work performed using a table top lidar system in an indoor environment; a mobile mini lidar platform was assembled using an existing Raman lidar platform, a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was then successfully demonstrated at an outdoor test. The lidar system was able to detect PFTs released into a vehicle from a distance of 100 meters. In its final, fully optimized configuration the lidar was capable of repeatedly detecting PFTs in the air released from tagged vehicles. Responses were immediate and clear. This report details the results of a proof-of-concept demonstration for standoff detection of a perfluorocarbon tracer (PFT) using infrared lidar. The project is part of the Tag, Track and Location System Program and was performed under a contract with Tracer Detection Technology Corp. with funding from the Office of Naval Research. A lidar capable of detecting PFT releases at distance was assembled by modifying an existing Raman lidar platform by incorporating a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was successfully demonstrated at an outdoor test. The demonstration test (scripted by the sponsor) consisted of three parked cars, two of which were tagged with the PFT. The cars were located 70 (closest) to 100 meters (farthest) from the lidar (the lidar beam path was limited by site constraints and was {approx}100 meters). When one door of each of the cars was opened (sequentially), the lidar was clearly able to determine which vehicles had been tagged and which one was not. The lidar is probably capable of greater than 0.5 kilometer standoff distances based on the extreme amount of signal return achieved (so much that the system had to be de-tuned). The BNL lidar system, while optimized to the extent possible with available parts and budget, was not as sensitive as it could be. Steps to improve the lidar are detailed in this report and include using a better laser system (for more stable power output), dual wavelengths (to improve the sensitivity and allow common mode noise reduction and to allow the use of the lidar in a scanning configuration), heterodyning (for range resolved PFT detection) and an off-axis optical configuration (for improved near field sensitivity).

Heiser,J.H.; Smith, S.; Sedlacek, A.

2008-02-06T23:59:59.000Z

350

Unnatural reactive amino acid genetic code additions  

DOE Patents (OSTI)

This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

2014-08-26T23:59:59.000Z

351

(Electronic structure and reactivities of transition metal clusters)  

SciTech Connect

The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

Not Available

1992-01-01T23:59:59.000Z

352

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive Reactive  

E-Print Network (OSTI)

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition) homogeneous reactions with indoor pollutants. The #12;Proceedings of Healthy Buildings 2009 Paper 336 latter

Siegel, Jeffrey

353

RAFT: A simulator for ReActive Flow and Transport of groundwater contaminants  

SciTech Connect

This report documents the use of the simulator RAFT for the ReActive flow and Transport of groundwater contaminants. RAFT can be used as a predictive tool in the design and analysis of laboratory and field experiments or it can be used for the estimation of model/process parameters from experiments. RAFT simulates the reactive transport of groundwater contaminants in one, two-, or three-dimensions and it can model user specified source/link configurations and arbitrary injection strategies. A suite of solvers for transport, reactions and regression are employed so that a combination of numerical methods best suited for a problem can be chosen. User specified coupled equilibrium and kinetic reaction systems can be incorporated into RAFT. RAFT is integrated with a symbolic computational language MAPLE, to automate code generation for arbitrary reaction systems. RAFT is expected to be used as a simulator for engineering design for field experiments in groundwater remediation including bioremediation, reactive barriers and redox manipulation. As an integrated tool with both the predictive ability and the ability to analyze experimental data, RAFT can help in the development of remediation technologies, from laboratory to field.

Chilakapati, A.

1995-07-01T23:59:59.000Z

354

Preliminary Interpretation of a Radionuclide and Colloid Tracer Test in a Granodiorite Shear Zone at the Grimsel Test Site, Switzerland  

SciTech Connect

In February and March 2012, a tracer test involving the injection of a radionuclide-colloid cocktail was conducted in the MI shear zone at the Grimsel Test Site, Switzerland, as part of the Colloids Formation and Migration (CFM) project. The colloids were derived from FEBEX bentonite, which is mined in Spain and is being considered as a potential waste package backfill in a Spanish nuclear waste repository. The tracer test, designated test 12-02 (second test in 2012), involved the injection of the tracer cocktail into borehole CFM 06.002i2 and extraction from the Pinkel surface packer at the main access tunnel wall approximately 6.1 m from the injection interval. The test configuration is depicted in Figure 1. This configuration has been used in several conservative tracer tests and two colloid-homologue tracer tests since 2007, and it is will be employed in an upcoming test involving the emplacement of a radionuclide-doped bentonite plug into CFM 06.002i2 to evaluate the swelling and erosion of the bentonite and the transport of bentonite colloids and radionuclides from the source to the extraction point at the tunnel wall. Interpretive analyses of several of the previous tracer tests, from 09-01 through 12-02 were provided in two previous Used Fuel Disposition Program milestone reports (Arnold et al., 2011; Kersting et al., 2012). However, only the data for the conservative tracer Amino-G Acid was previously analyzed from test 12-02 because the other tracer data from this test were not available at the time. This report documents the first attempt to quantitatively analyze the radionuclide and colloid breakthrough curves from CFM test 12-02. This report was originally intended to also include an experimental assessment of colloid-facilitated transport of uranium by bentonite colloids in the Grimsel system, but this assessment was not conducted because it was reported by German collaborators at the Karlsruhe Institute of Technology (KIT) that neither uranium nor neptunium adsorbed appreciably to FEBEX bentonite colloids in Grimsel groundwater (Huber et al., 2011). The Grimsel groundwater has a relatively high pH of {approx}9, so the lack of uranium and neptunium adsorption to clay is not surprising given the tendency for these actinides to form very stable negative or neutrally-charged uranyl- or calcium-uranyl-carbonate complexes at these pH, particularly in a water that is effectively saturated with respect to calcite. It was also observed in testing conducted at LANL earlier in 2012 that uranium did not adsorb measurably to Grimsel granodiorite in a synthetic Grimsel groundwater at pH {approx}8.5 (Kersting et al., 2012). Thus, the planned experimental work was not pursued because all the available information clearly pointed to an expected result that uranium transport would not be facilitated by clay colloids in the Grimsel system.

Reimus, Paul W. [Los Alamos National Laboratory

2012-08-30T23:59:59.000Z

355

Spectroscopic diagnostics for ablation cloud of tracer-encapsulated solid pellet in LHD  

SciTech Connect

In the Large Helical Device (LHD), various spectroscopic diagnostics have been applied to study the ablation process of an advanced impurity pellet, tracer-encapsulated solid pellet (TESPEL). The total light emission from the ablation cloud of TESPEL is measured by photomultipliers equipped with individual interference filters, which provide information about the TESPEL penetration depth. The spectra emitted from the TESPEL ablation cloud are measured with a 250 mm Czerny-Turner spectrometer equipped with an intensified charge coupled device detector, which is operated in the fast kinetic mode. This diagnostic allows us to evaluate the temporal evolution of the electron density in the TESPEL ablation cloud. In order to gain information about the spatial distribution of the cloud parameters, a nine image optical system that can simultaneously acquire nine images of the TESPEL ablation cloud has recently been developed. Several images of the TESPEL ablation cloud in different spectral domains will give us the spatial distribution of the TESPEL cloud density and temperature.

Tamura, N.; Kalinina, D. V.; Sato, K.; Sudo, S. [National Institute for Fusion Science, 322-6, Oroshi-cho, Toki-City, Gifu 509-5292 (Japan); Sergeev, V. Yu.; Miroshnikov, I. V.; Sharov, I. A.; Bakhareva, O. A.; Ivanova, D. M.; Timokhin, V. M. [State Polytechnical University, Politechnicheskaya 29, St. Petersburg 195251 (Russian Federation); Kuteev, B. V. [Nuclear Fusion Institute, RRC 'Kurchatov Institute', Kurchatov square 1, Moscow 123182 (Russian Federation)

2008-10-15T23:59:59.000Z

356

Applications of radioactive tracer technology in the real-time measurement of wear and corrosion  

Science Journals Connector (OSTI)

Radioactive tracer technology has been used for many years as a tool to make highly sensitive real-time measurements of wear and corrosion. With this technique, the material of interest is tagged with radioactive isotopes through either direct activation of a relatively small number of atoms in the component itself, or implantation of radioactive isotopes. As the component wears or corrodes under test, radioactive atoms are transported from the surface in the form of wear particles or corrosion products. Wear or corrosion is measured in real-time through either interrogation of the buildup of radioactivity in the transport fluid, or by the reduction in activity of the labeled wear component. The process involves selection of an appropriate labeling technique, labeling of a component or components of interest, calibration, testing and data reduction and analysis. Although the majority of the work performed has been in the automotive engine and lubricant industry, Southwest Research Institute has recently extended the application into other fields, such as hydraulic pump wear, prosthetic hip joint wear, wear in marine engines and crude oil corrosivity. This paper discusses the various techniques employed to label components of interest, the advantages of the techniques, and gives several examples of current applications of this technology.

D.C. Eberle; C.M. Wall; M.B. Treuhaft

2005-01-01T23:59:59.000Z

357

Reservoir characterization based on tracer response and rank analysis of production and injection rates  

SciTech Connect

Quantification of the spatial distribution of properties is important for many reservoir-engineering applications. But, before applying any reservoir-characterization technique, the type of problem to be tackled and the information available should be analyzed. This is important because difficulties arise in reservoirs where production records are the only information for analysis. This paper presents the results of a practical technique to determine preferential flow trends in a reservoir. The technique is a combination of reservoir geology, tracer data, and Spearman rank correlation coefficient analysis. The Spearman analysis, in particular, will prove to be important because it appears to be insightful and uses injection/production data that are prevalent in circumstances where other data are nonexistent. The technique is applied to the North Buck Draw field, Campbell County, Wyoming. This work provides guidelines to assess information about reservoir continuity in interwell regions from widely available measurements of production and injection rates at existing wells. The information gained from the application of this technique can contribute to both the daily reservoir management and the future design, control, and interpretation of subsequent projects in the reservoir, without the need for additional data.

Refunjol, B.T. [Lagoven, S.A., Pdvsa (Venezuela); Lake, L.W. [Univ. of Texas, Austin, TX (United States)

1997-08-01T23:59:59.000Z

358

Mapping subsurface radionuclide migration and groundwater flow with organic tracers. [Shallow-land burial  

SciTech Connect

At Pacific Northwest Laboratory we have had the opportunity to study the subsurface migration of radionuclides at the Maxey Flats burial site. We constructed an experimental study area adjacent to one of the waste-filled trenches at the site. In this report we describe some preliminary results of organic research currently underway at Maxey Flats. This research is aimed at: (1) elucidating the role of organic species in the subsurface migration of radionuclides; and (2) testing the usefulness of artificial and in situ organic groundwater tracers for mapping radionuclide migration and groundwater flow. We also describe two analytical procedures developed for this research. First, as part of a survey study of organics in Maxey Flats groundwater we have developed a procedure for the isolation and characterization of trace levels of organics in radioactive groundwaters. Second, for a detailed chemical speciation study we developed a procedure based on steric exclusion chromatography for testing whether or not organics are chelated to radionuclides. 1 figure, 1 table.

Toste, A.P.; Kirby, L.J.; Pahl, T.R.; Myers, R.B.

1983-10-01T23:59:59.000Z

359

Development and Evaluation of a State-of-the-Science Reactive Plume  

E-Print Network (OSTI)

for plume rise, plume visibility, and stack opacity (5). Examples of other reactive plume models include

Zhang, Yang

360

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah  

Energy.gov (U.S. Department of Energy (DOE))

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

129 Iodine: A New Hydrologic Tracer for Aquifer Recharge Conditions Influenced by River Flow Rate and Evapotranspiration  

E-Print Network (OSTI)

County using boron isotopes and general geochemistry, In Lawrence Livermore National Laboratory UCRL-ID-133529 (pp. 44). ? Davisson, M.L., Hudson, G.B., Herndon, R., & Woodside, G. (1999b). Report on isotope tracer investigations in the Forebay... of the Orange County Groundwater Basin: Fiscal years 1996 and 1997, In Lawrence Livermore National Laboratory UCRL-ID- 133531 (pp. 44). ? Dissanayake, C.B. & Chandrajith, R. (1999). Medical geochemistry of tropical environments. Earth-Science Reviews 47, 219...

Schwehr, K. A.; Santschi, P. H.; Moran, J. E.

2003-01-01T23:59:59.000Z

362

Characterization of volatile organic compounds (VOCs) in Asian and north American pollution plumes during INTEX-B: identification of specific Chinese air mass tracers  

E-Print Network (OSTI)

coal and biofuel combustion and biomass burning (Khalil andcombustion products ethyne and benzene, and of the biomass/combustion tracer ethyne, the industrial solvent CH 2 Cl 2 , and the two coal/biomass

2009-01-01T23:59:59.000Z

363

Neutron kinetics in subcritical cores with application to the source modulation method  

E-Print Network (OSTI)

Neutron kinetics in subcritical cores with application to the source modulation method J. Wright for the measurement of reactivity in subcritical, source-driven cores. Methods of measuring reactivity by a single. Hence, first, the conditions of point kinetic behaviour in subcritical source-driven cores are revis

Pázsit, Imre

364

Kinetics and mechanisms of reactions involving small aromatic reactive intermediates  

SciTech Connect

Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

Lin, M.C. [Emory Univ., Atlanta, GA (United States)

1993-12-01T23:59:59.000Z

365

Photoconductivity in reactively evaporated copper indium selenide thin films  

SciTech Connect

Copper indium selenide thin films of composition CuInSe{sub 2} with thickness of the order of 130 nm are deposited on glass substrate at a temperature of 423 5 K and pressure of 10{sup ?5} mbar using reactive evaporation, a variant of Gunther's three temperature method with high purity Copper (99.999%), Indium (99.999%) and Selenium (99.99%) as the elemental starting materials. X-ray diffraction (XRD) studies shows that the films are polycrystalline in nature having preferred orientation of grains along the (112) plane. The structural type of the film is found to be tetragonal with particle size of the order of 32 nm. The structural parameters such as lattice constant, particle size, dislocation density, number of crystallites per unit area and strain in the film are also evaluated. The surface morphology of CuInSe{sub 2} films are studied using 2D and 3D atomic force microscopy to estimate the grain size and surface roughness respectively. Analysis of the absorption spectrum of the film recorded using UV-Vis-NIR Spectrophotometer in the wavelength range from 2500 nm to cutoff revealed that the film possess a direct allowed transition with a band gap of 1.05 eV and a high value of absorption coefficient (?) of 10{sup 6} cm{sup ?1} at 570 nm. Photoconductivity at room temperature is measured after illuminating the film with an FSH lamp (82 V, 300 W). Optical absorption studies in conjunction with the good photoconductivity of the prepared p-type CuInSe{sub 2} thin films indicate its suitability in photovoltaic applications.

Urmila, K. S., E-mail: urmilaks7@gmail.com; Asokan, T. Namitha, E-mail: urmilaks7@gmail.com; Pradeep, B., E-mail: urmilaks7@gmail.com [Solid State Physics Laboratory, Cochin University of Science and Technology, Kochi, Kerala (India); Jacob, Rajani; Philip, Rachel Reena [Thin Film Research Laboratory, Union Christian College, Aluva, Kerala (India)

2014-01-28T23:59:59.000Z

366

Permanganate Treatment of DNAPLs in Reactive Barriers and Source Zone Flooding Schemes  

SciTech Connect

In situ oxidation with potassium permanganate has been widely evaluated, as a potential remediation method for dissolved or pure DNAPL in groundwater system. The goals of this study are (1) to elucidate the basic mechanisms by which potassium permanganate oxidizes common chlorinated solvents, various constituents in aqueous solution, and porous medium solids, and (2) to assess the potential for chemical oxidation by potassium permanganate to serve as a remedial scheme involving either source zone flooding or reactive barriers. The study is organized with a laboratory component that looks generally at the basic reaction processes and kinetics, and a theoretical component that is developing modeling tools appropriate for designing systems under field conditions.

Schwartz, Frank W.; Zhang, Hubao

2000-06-30T23:59:59.000Z

367

Active and reactive power ripple minimization in direct power control of matrix converter-fed DFIG  

Science Journals Connector (OSTI)

Abstract Despite the advantages of matrix converters (MCs) compared with standard voltage source converters (VSCs), all of the direct power control (DPC) strategies for doubly fed induction generator (DFIG) reported in the literature, only utilize VSCs. In this paper, the influence of MC voltage vectors on active and reactive powers variation is investigated. Compared with VSCs, \\{MCs\\} generate higher number of voltage vectors. Using this inherent advantage of MC, the main contribution of this paper is to reduce large active and reactive power ripples which is one of the main drawbacks of conventional DPC method. Utilizing a wide range of voltage vectors with different amplitudes, a new switching table is derived which using this table, not only large power ripple is compensated but also, a close to unity input power factor for MC can be achieved. In the other word, the presented scheme adds the advantages of MC and DPC together. Moreover, Owing to the operation of MC in direct acac form, the presented scheme effectively eliminates the need for the grid side converter used in conventional DPC, which has a complicated control method is eliminated. Simulation results show the effectiveness of the proposed method and have a reasonable correspondence with theoretical and mathematical analysis.

Arjang Yousefi-Talouki; Edris Pouresmaeil; Bo Nrregaard Jrgensen

2014-01-01T23:59:59.000Z

368

Method for producing high quality thin layer films on substrates  

DOE Patents (OSTI)

A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate.

Strongin, Myron (Center Moriches, NY); Ruckman, Mark (Middle Island, NY); Strongin, Daniel (Port Jefferson, NY)

1994-01-01T23:59:59.000Z

369

Method for producing high quality thin layer films on substrates  

DOE Patents (OSTI)

A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate. 4 figures.

Strongin, M.; Ruckman, M.; Strongin, D.

1994-04-26T23:59:59.000Z

370

Modeling The GRB Host Galaxy Mass Distribution: Are GRBs Unbiased Tracers of Star Formation?  

SciTech Connect

We model the mass distribution of long gamma-ray burst (GRB) host galaxies given recent results suggesting that GRBs occur in low metallicity environments. By utilizing measurements of the redshift evolution of the mass-metallicity (M-Z) relationship for galaxies, along with a sharp host metallicity cut-off suggested by Modjaz and collaborators, we estimate an upper limit on the stellar mass of a galaxy that can efficiently produce a GRB as a function of redshift. By employing consistent abundance indicators, we find that sub-solar metallicity cut-offs effectively limit GRBs to low stellar mass spirals and dwarf galaxies at low redshift. At higher redshifts, as the average metallicity of galaxies in the Universe falls, the mass range of galaxies capable of hosting a GRB broadens, with an upper bound approaching the mass of even the largest spiral galaxies. We compare these predicted limits to the growing number of published GRB host masses and find that extremely low metallicity cut-offs of 0.1 to 0.5 Z{sub {circle_dot}} are effectively ruled out by a large number of intermediate mass galaxies at low redshift. A mass function that includes a smooth decrease in the efficiency of producing GRBs in galaxies of metallicity above 12+log(O/H){sub KK04} = 8.7 can, however, accommodate a majority of the measured host galaxy masses. We find that at z {approx} 1, the peak in the observed GRB host mass distribution is inconsistent with the expected peak in the mass of galaxies harboring most of the star formation. This suggests that GRBs are metallicity biased tracers of star formation at low and intermediate redshifts, although our model predicts that this bias should disappear at higher redshifts due to the evolving metallicity content of the universe.

Kocevski, Daniel; /KIPAC, Menlo Park; West, Andrew A.; /UC, Berkeley, Astron. Dept. /MIT, MKI; Modjaz, Maryam; /UC, Berkeley, Astron. Dept.

2009-08-03T23:59:59.000Z

371

The Development and Application of Reactive Transport Modeling Techniques to Study Radionuclide Migration at Yucca Mountain, NV  

SciTech Connect

Yucca Mountain, Nevada has been chosen as a possible site for the first high level radioactive waste repository in the United States. As part of the site investigation studies, we need to make scientifically rigorous estimations of radionuclide migration in the event of a repository breach. Performance assessment models used to make these estimations are computationally intensive. We have developed two reactive transport modeling techniques to simulate radionuclide transport at Yucca Mountain: (1) the selective coupling approach applied to the convection-dispersion-reaction (CDR) model and (2) a reactive stream tube approach (RST). These models were designed to capture the important processes that influence radionuclide migration while being computationally efficient. The conventional method of modeling reactive transport models is to solve a coupled set of multi-dimensional partial differential equations for the relevant chemical components in the system. We have developed an iterative solution technique, denoted the selective coupling method, that represents a versatile alternative to traditional uncoupled iterative techniques and the filly coupled global implicit method. We show that selective coupling results in computational and memory savings relative to these approaches. We develop RST as an alternative to the CDR method for solving large two- or three-dimensional reactive transport simulations for cases in which one is interested in predicting the flux across a specific control plane. In the RST method, the multidimensional problem is reduced to a series of one-dimensional transport simulations along streamlines. The key assumption with RST is that mixing at the control plane approximates the transverse dispersion between streamlines. We compare the CDR and RST approaches for several scenarios that are relevant to the Yucca Mountain Project. For example, we apply the CDR and RST approaches to model an ongoing field experiment called the Unsaturated Zone Transport Test.

Viswanathan, Hari Selvi

1999-09-01T23:59:59.000Z

372

Internal structure, hygroscopic and reactive properties of mixed sodium  

NLE Websites -- All DOE Office Websites (Extended Search)

Internal structure, hygroscopic and Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Print Friday, 13 May 2011 00:00 Scientists recently combined experimental approaches and molecular dynamics modeling to gain new insights into the internal structure of sea salt particles and relate it to their fundamental chemical reactivity in the atmosphere. This research shows that surface enhancement or depletion of chemical components in marine particles can occur because of the difference in the chemical nature of the species. Because the atmospheric chemistry of the salt particles takes place at the gas-particle interface, understanding their complex surfaces provides new insights about their effect on the environment and climate change. Article Link.

373

Ionic Liquids and Ionizing Radiation: Reactivity of Highly Energetic  

NLE Websites -- All DOE Office Websites (Extended Search)

Ionizing Radiation: Reactivity of Highly Energetic Ionizing Radiation: Reactivity of Highly Energetic Species James F. Wishart J. Phys. Chem. Lett. 1, 3225-3231 (2010). [Find paper at ACS Publications] or use ACS Articles on Request View the video on this Perspective article at The Journal of Physical Chemistry Letters (5:03) Selected for the ACS Special Virtual Issue on Ionic Liquids (March 2011). Abstract: Due to their unique properties, ionic liquids present many opportunities for basic research on the interactions of radiation with materials under conditions not previously available. At the same time, there are practical applied reasons for characterizing, understanding, and being able to predict how ionic-liquid-based devices and industrial-scale systems will perform under conditions of extreme reactivity, including radiation. This

374

Options for Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network (OSTI)

High penetration levels of distributed photovoltaic(PV) generation on an electrical distribution circuit present several challenges and opportunities for distribution utilities. Rapidly varying irradiance conditions may cause voltage sags and swells that cannot be compensated by slowly responding utility equipment resulting in a degradation of power quality. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We discuss and compare via simulation various design options for control systems to manage the reactive power generated by these inverters. An important design de...

Sulc, Petr; Backhaus, Scott; Chertkov, Michael

2010-01-01T23:59:59.000Z

375

REACTIVE TRANSPORT MODELING USING A PARALLEL FULLY-COUPLED SIMULATOR BASED ON PRECONDITIONED JACOBIAN-FREE NEWTON-KRYLOV  

SciTech Connect

Systems of multicomponent reactive transport in porous media that are large, highly nonlinear, and tightly coupled due to complex nonlinear reactions and strong solution-media interactions are often described by a system of coupled nonlinear partial differential algebraic equations (PDAEs). A preconditioned Jacobian-Free Newton-Krylov (JFNK) solution approach is applied to solve the PDAEs in a fully coupled, fully implicit manner. The advantage of the JFNK method is that it avoids explicitly computing and storing the Jacobian matrix during Newton nonlinear iterations for computational efficiency considerations. This solution approach is also enhanced by physics-based blocking preconditioning and multigrid algorithm for efficient inversion of preconditioners. Based on the solution approach, we have developed a reactive transport simulator named RAT. Numerical results are presented to demonstrate the efficiency and massive scalability of the simulator for reactive transport problems involving strong solution-mineral interactions and fast kinetics. It has been applied to study the highly nonlinearly coupled reactive transport system of a promising in situ environmental remediation that involves urea hydrolysis and calcium carbonate precipitation.

Luanjing Guo; Chuan Lu; Hai Huang; Derek R. Gaston

2012-06-01T23:59:59.000Z

376

The implementation of a 3D characteristics solver for the generation of incremental cross sections for reactivity devices in a CANDU reactor  

SciTech Connect

We are presenting issues related to the generation of consistent incremental cross sections for the reactivity devices in a CANDU reactor. Such calculations involve the solution of the neutron transport equation over complex 3D geometries representing a single vertical reactivity device inserted mid-way between two horizontal fuel channels. The DRAGON lattice code has recently been upgraded and can handle the exact geometry of such configurations for trajectory-based transport solvers. Within this framework, the detailed representation of the reactivity devices implies an increase in the number of regions when the strongly absorbing regions and fuel clusters are described without cylinderization. In this paper, a solution based on the characteristics method is compared with the standard procedure, based on the collision probabilities method. The coherence of both solvers is highlighted and a comparison of their computational costs is presented. (authors)

Le Tellier, R.; Hebert, A.; Marleau, G. [Ecole Polytechnique de Montreal, C.P. 6079 suce. Centre-Ville, Montreal, Que. H3C 3A7 (Canada)

2006-07-01T23:59:59.000Z

377

Reactive Search Optimization: Learning while Roberto Battiti and Mauro Brunato  

E-Print Network (OSTI)

Reactive Search Optimization: Learning while Optimizing Roberto Battiti and Mauro Brunato 1, Universit`a di Trento, Italy, e-mail: roberto.battiti@unitn.it Mauro Brunato LION Lab, Universit`a di Trento, Italy, e-mail: mauro.brunato@unitn.it 1 #12;2 Roberto Battiti and Mauro Brunato in the loop between

Battiti, Roberto

378

Toward a new paradigm for reactive flow modeling.  

SciTech Connect

Traditional reactive flow modeling provides a computational representation of shock initiation of energetic materials. Most reactive flow models require ad hoc assumptions to obtain robust simulations, assumptions that result from partitioning energy and volume change between constituents in a reactive mixture. For example, most models assume pressure and/or temperature equilibrium for the mixture. Many mechanical insults to energetic materials violate these approximations. Careful analysis is required to ensure that the model assumptions and limitations are not exceeded. One limitation is that the shock to detonation transition is replicated only for strong planar shocks. Many models require different parameters to match data from thin pulse, ramp wave, or multidimensional loading, an approach that fails for complex loading. To accurately simulate reaction under non-planar shock impact scenarios a new formalism is required. The continuum mixture theory developed by Baer and Nunziato is used to eliminate ad hoc assumptions and limitations of current reactive flow models. This modeling paradigm represents the multiphase nature of reacting condensed/gas mixtures. Comparisons between simulations and data are presented.

Schmitt, Robert Gerard

2005-08-01T23:59:59.000Z

379

Resilient Intrusion Tolerance through Proactive and Reactive Recovery  

E-Print Network (OSTI)

system's correct operation. We design a proactive- reactive recovery service based on a hybrid the resilience of an intrusion-tolerant firewall adequate for the protection of critical infrastructures infras- tructures like the Power grid. One approach that promises to satisfy this requirement

Neves, Nuno

380

Voltage Regulation through Smart Utilization of Potential Reactive Power Resources  

Science Journals Connector (OSTI)

The introduction of demand response concept, in addition to increment of penetration of distributed generation (DG) based on renewable energies, make opportunities for the novel control schemes to be integrated in power system on a smart grid framework. ... Keywords: Demand response, distributed generation, reactive power, renewable energy, smart grid, voltage control

H. Kazari; A. Abbaspour-Tehrani Fard; A. S. Dobakhshari; A. M. Ranjbar

2011-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Surface tension in a reactive binary mixture of incompressible fluids  

E-Print Network (OSTI)

Surface tension in a reactive binary mixture of incompressible fluids Henning Struchtrup Institute with a distributed form of surface tension. The model describes chemistry, diffusion, viscosity and heat transfer tension at the front. Keywords: Binary mixtures, Surface tension, Irreversible thermodynamics, Hele

Struchtrup, Henning

382

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network (OSTI)

of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may depend are combined is certainly not arbitrary. For instance, the repetition of one cycle may rely on the repetitionsDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Leue, Stefan

383

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network (OSTI)

processes of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may in which cycle executions are combined is certainly not arbitrary. For instance, the repetition of oneDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Reiterer, Harald

384

Effect of Number of Fractionating Trays on Reactive Distillation Performance  

E-Print Network (OSTI)

Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

Al-Arfaj, Muhammad A.

385

Neutron economic reactivity control system for light water reactors  

DOE Patents (OSTI)

A neutron reactivity control system for a LWBR incorporating a stationary seed-blanket core arrangement. The core arrangement includes a plurality of contiguous hexagonal shaped regions. Each region has a central and a peripheral blanket area juxapositioned an annular seed area. The blanket areas contain thoria fuel rods while the annular seed area includes seed fuel rods and movable thoria shim control rods.

Luce, Robert G. (Glenville, NY); McCoy, Daniel F. (Latham, NY); Merriman, Floyd C. (Rotterdam, NY); Gregurech, Steve (Scotia, NY)

1989-01-01T23:59:59.000Z

386

Generalized Chemical Reactivity of Curved Surfaces: Carbon Nanotubes  

E-Print Network (OSTI)

. Following the decomposition, the total reaction energy Etotal, which is the index of chemical reactivity, can be divided into three terms: strain energy Estrain, C-X binding energy EC-X, and global relaxation in a CNT can enhance the hydrogenation energy at the location of the excess deformation so

Srivastava, Deepak

387

Local control of reactive power by distributed photovoltaic generators  

SciTech Connect

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the real power generated by the PVs. Using one adjustable parameter per circuit, we balance the requirements on power quality and desire to minimize thermal losses. Numerical analysis of two exemplary systems, with comparable total PV generation albeit a different spatial distribution, show how to adjust the optimization parameter depending on the goal. Overall, this local scheme shows excellent performance; it's capable of guaranteeing acceptable power quality and achieving significant saving in thermal losses in various situations even when the renewable generation in excess of the circuit own load, i.e. feeding power back to the higher-level system.

Chertkov, Michael [Los Alamos National Laboratory; Turitsyn, Konstantin [Los Alamos National Laboratory; Sulc, Petr [Los Alamos National Laboratory; Backhaus, Scott [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

388

Sleep & Memory/Review Memory reactivation and consolidation during sleep  

E-Print Network (OSTI)

Sleep & Memory/Review Memory reactivation and consolidation during sleep Ken A. Paller1 and Joel L, Illinois 60208-2710, USA Do our memories remain static during sleep, or do they change? We argue here that memory change is not only a natural result of sleep cognition, but further, that such change constitutes

Paller, Ken

389

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Final Report Phase II: Performance Evaluation of Permeable Reactive

390

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Phase II: Performance Evaluation of Permeable Reactive Barriers and

391

Photoluminescent silicon nanocrystals synthesized by reactive laser Daria Riabinina,a  

E-Print Network (OSTI)

Photoluminescent silicon nanocrystals synthesized by reactive laser ablation Daria Riabinina reactive laser ablation in oxygen atmosphere followed by annealing. We observe a strong photoluminescence size, obtained independently by fitting photoluminescence spectra and from x-ray diffraction patterns

392

Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel  

Energy.gov (U.S. Department of Energy (DOE))

This study uses numerical simulations to explore the use of wet ethanol as the low-reactivity fuel and diesel as the high-reactivity fuel for RCCI operation in a heavy-duty diesel engine.

393

Bioinformatic analysis of xenobiotic reactive metabolite target proteins and their interacting partners  

E-Print Network (OSTI)

Background Protein covalent binding by reactive metabolites of drugs, chemicals and natural products can lead to acute cytotoxicity. Recent rapid progress in reactive metabolite target protein identification has shown ...

Hanzlik, Robert P.; Fang, Jianwen; Koen, Yakov M.

2009-06-12T23:59:59.000Z

394

Chemical Reactivity of Reduced TiO2(110): The dominant role of...  

NLE Websites -- All DOE Office Websites (Extended Search)

Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

395

Reactive ion etching-assisted surface-enhanced Raman scattering measurements on the single nanoparticle level  

SciTech Connect

Single-nanoparticle surface-enhanced Raman scattering (SERS) measurement is of essential importance for both fundamental research and practical applications. In this work, we develop a class of single-particle SERS approaches, i.e., reactive ion etching (RIE)-assisted SERS measurements correlated with scanning electron microscopy (SEM) strategy (RIE/SERS/SEM), enabling precise and high-resolution identification of single gold nanoparticle (AuNP) in facile and reliable manners. By using AuNP-coated silicon wafer and quartz glass slide as models, we further employ the developed RIE/SERS/SEM method for interrogating the relationship between SERS substrates and enhancement factor (EF) on the single particle level. Together with theoretical calculation using an established finite-difference-time-domain (FDTD) method, we demonstrate silicon wafer as superior SERS substrates, facilitating improvement of EF values.

Wang, Si-Yi; Jiang, Xiang-Xu; Wei, Xin-Pan; Lee, Shuit-Tong, E-mail: apannale@suda.edu.cn, E-mail: yaohe@suda.edu.cn; He, Yao, E-mail: apannale@suda.edu.cn, E-mail: yaohe@suda.edu.cn [Institute of Functional Nano and Soft Materials - FUNSOM, Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Devices Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Xu, Ting-Ting [Institute of Functional Nano and Soft Materials - FUNSOM, Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, and Devices Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, Hong Kong, China and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (China)

2014-06-16T23:59:59.000Z

396

Boron-carbide-aluminum and boron-carbide-reactive metal cermets  

DOE Patents (OSTI)

Hard, tough, lightweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidation step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modulus of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi.sqroot.in. These composites and methods can be used to form a variety of structural elements.

Halverson, Danny C. (Manteca, CA); Pyzik, Aleksander J. (Seattle, WA); Aksay, Ilhan A. (Seattle, WA)

1986-01-01T23:59:59.000Z

397

Fuel Cell Manufacturing Diagnostic Techniques: IR Thermography with Reactive Flow through Excitation  

SciTech Connect

While design and material considerations for PEMFCs have a large impact on cost, it is also necessary to consider a transition to high volume production of fuel cell systems, including MEA components, to enable economies of scale and reduce per unit cost. One of the critical manufacturing tasks is developing and deploying techniques to provide in?process measurement of fuel cell components for quality control. This effort requires a subsidiary task: The study of the effect of manufacturing defects on performance and durability with the objective to establish validated manufacturing tolerances for fuel cell components. This work focuses on the development of a potential quality control method for gas diffusion electrodes (GDEs). The method consists of infrared (IR) thermography combined with reactive flow through (RFT) excitation. Detection of catalyst loading reduction defects in GDE catalyst layers will be presented.

Manak, A. J.; Ulsh, M.; Bender, G.

2012-01-01T23:59:59.000Z

398

Lewis Base Adduct Stabilized Organogallium Azides:? Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas  

Science Journals Connector (OSTI)

Lewis Base Adduct Stabilized Organogallium Azides:? Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas ... Solvents were dried under argon according to standard methods; n-pentane and toluene were stored over Na/K alloy, and diethyl ether and thf over potassium benzophenoate (residual water solubility in other solvents than thf. ...

Alexander Miehr; Mike R. Mattner; Roland A. Fischer

1996-04-16T23:59:59.000Z

399

E-Print Network 3.0 - advected reactive scalars Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

through... reactive scalars that are initially distinct, ... Source: Crimaldi, John P. - Department of Civil, Environmental, and Architectural Engineering, University of...

400

Quantifying biomineralization of zinc in the Rio Naracauli (Sardinia, Italy), using a tracer injection and synoptic sampling  

Science Journals Connector (OSTI)

Abstract Streams draining mined areas throughout the world commonly have high concentrations of Zn. Because Zn is not easily removed from stream water and because it can be toxic to aquatic organisms, its presence is a persistent problem. The discovery of biomineralization of Zn-bearing solids in the mine drainage of Rio Naracauli, in Sardinia, Italy, provides insights into strategies for removing Zn and improving water quality in streams affected by mine drainage. Until now, the transport and attenuation of Zn has not been quantified in this stream setting. A continuous tracer injection experiment was conducted to quantify the biomineralization process and to identify the loading of constituents that causes a change from precipitation of hydrozincite [Zn5(CO3)2(OH)6] in the upstream reach to precipitation of a Zn-silicate phase downstream. Based on the mass-load calculations derived from the tracer experiment, about 1.2kg/day of Zn is sequestered in hydrozincite. This biomineralization represents nearly 90% removal of Zn. Other elements such as Pb and Cd also are sequestered, either in the hydrozincite, or in a separate phase that forms simultaneously. In the lower 600m of the stream, where the Zn-silicate forms, as much as 0.7kg/day Zn are sequestered in this solid, but additions of Zn to the stream from groundwater discharge lead to an overall increase in load in that portion of the Rio Naracauli.

G. De Giudici; R.B. Wanty; F. Podda; B.A. Kimball; P.L. Verplanck; P. Lattanzi; R. Cidu; D. Medas

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Experimental investigation of direct injection charge cooling in optical GDI engine using tracer-based PLIF technique  

Science Journals Connector (OSTI)

Abstract Investigation of direct injection charge cooling effects is indispensable in design and development of new combustion systems for Gasoline Direct Injection (GDI) engines. The charge cooling can be utilized to increase engine volumetric efficiency or compression ratio. It can be employed to suppress pre-ignition of highly boosted downsized engines or knocking combustion of naturally aspirated engines. The main purpose of this work was to develop an experimental setup for quantitative measurements of charge cooling during fuel injection process inside the combustion chamber of a GDI engine with optical access. For this purpose a tracer-based two-line Planar Laser Induced Fluorescence (PLIF) technique was implemented for the measurements. A specially designed Constant Volume Chamber (CVC) was utilized for quasi in situ calibration measurement so in-cylinder charge temperature measurements can be achieved independent of the photophysical model of dopant tracer. The thermometry technique was evaluated by measurements of average in-cylinder charge temperature during compression stroke for both motoring and firing cycles and comparing the results with temperature values calculated from in-cylinder pressure data assuming a polytropic compression. The PLIF technique was successfully utilized to quantify the extend of global temperature decrease as a result of direct injection charge cooling of two injection timings of 90 and 250CA ATDC and two injection quantities of 10 and 30mg/cycle. Test results demonstrated the capability of the two-line PLIF thermometry technique in quantitative study of direct injection charge cooling effects.

Mohammadreza Anbari Attar; Mohammad Reza Herfatmanesh; Hua Zhao; Alasdair Cairns

2014-01-01T23:59:59.000Z

402

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network (OSTI)

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

403

Abstract This paper reviews specific issues and challenges in reactive power management within the competitive electricity  

E-Print Network (OSTI)

, points out various deficiencies in the reactive power procurement in the US markets and provides recommendations for, and lists a number of challenges in the reactive power supply and usage area. Basically of the same type as active power or active energy. Many reactive power management issues concern the static

Gross, George

404

Neural network and area method interpretation of pulsed experiments  

SciTech Connect

The determination of the subcriticality level is an important issue in accelerator-driven system technology. The area method, originally introduced by N. G. Sjoestrand, is a classical technique to interpret flux measurement for pulsed experiments in order to reconstruct the reactivity value. In recent times other methods have also been developed, to account for spatial and spectral effects, which were not included in the area method, since it is based on the point kinetic model. The artificial neural network approach can be an efficient technique to infer reactivities from pulsed experiments. In the present work, some comparisons between the two methods are carried out and discussed. (authors)

Dulla, S.; Picca, P.; Ravetto, P. [Politecnico di Torino, Dipartimento di Energetica, Corso Duca degli Abruzzi, 24 - 10129 Torino (Italy); Canepa, S. [Lab of Reactor Physics and Systems Behaviour LRS, Paul Scherrer Inst., 5232 Villigen (Switzerland)

2012-07-01T23:59:59.000Z

405

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure Modes from Reactive Dynamics Simulations  

Science Journals Connector (OSTI)

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure Modes from Reactive Dynamics Simulations ... Ettringite is a hexacalcium aluminate trisulfate hydrate mineral that forms during Portland cement hydration. ... Here, we report on the development of this ReaxFF force field and on its validation and application using reactive molecular dynamics (RMD) simulations to characterize and understand the elastic, plastic, and failure response of ettringite at the atomic scale. ...

Lianchi Liu; Andres Jaramillo-Botero; William A. Goddard; III; Huai Sun

2012-03-13T23:59:59.000Z

406

Engine combustion control at low loads via fuel reactivity stratification  

DOE Patents (OSTI)

A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

2014-10-07T23:59:59.000Z

407

Reactive Membrane Barriers for Containment of Subsurface Contamination  

SciTech Connect

The overall goal of this project was to develop reactive membrane barriers--a new and flexible technique to contain and stabilize subsurface contaminants. Polymer membranes will leak once a contaminant is able to diffuse through the membrane. By incorporating a reactive material in the polymer, however, the contaminant is degraded or immobilized within the membrane. These processes increase the time for contaminants to breakthrough the barrier (i.e. the lag time) and can dramatically extend barrier lifetimes. In this work, reactive barrier membranes containing zero-valent iron (Fe{sup 0}) or crystalline silicotitanate (CST) were developed to prevent the migration of chlorinated solvents and cesium-137, respectively. These studies were complemented by the development of models quantifying the leakage/kill time of reactive membranes and describing the behavior of products produced via the reactions within the membranes. First, poly(vinyl alcohol) (PVA) membranes containing Fe{sup 0} and CST were prepared and tested. Although PVA is not useful in practical applications, it allows experiments to be performed rapidly and the results to be compared to theory. For copper ions (Cu{sup 2+}) and carbon tetrachloride, the barrier was effective, increasing the time to breakthrough over 300 times. Even better performance was expected, and the percentage of the iron used in the reaction with the contaminants was determined. For cesium, the CST laden membranes increased lag times more than 30 times, and performed better than theoretical predictions. A modified theory was developed for ion exchangers in reactive membranes to explain this result. With the PVA membranes, the effect of a groundwater matrix on barrier performance was tested. Using Hanford groundwater, the performance of Fe{sup 0} barriers decreased compared to solutions containing a pH buffer and high levels of chloride (both of which promote iron reactivity). For the CST bearing membrane, performance improved by a factor of three when groundwater was used in place of deionized water. The performance of high density polyethylene (HDPE) membranes containing Fe{sup 0} was then evaluating using carbon tetrachloride as the target contaminant. Only with a hydrophilic additive (glycerol), was the iron able to extend lag times. Lag times were increased by a factor of 15, but only 2-3% of the iron was used, likely due to formation of oxide precipitates on the iron surface, which slowed the reaction. With thicker membranes and lower carbon tetrachloride concentrations, it is expected that performance will improve. Previous models for reactive membranes were also extended. The lag time is a measurement of when the barrier is breached, but contaminants do slowly leak through prior to the lag time. Thus, two parameters, the leakage and the kill time, were developed to determine when a certain amount of pollutant has escaped (the kill time) or when a given exposure (concentration x time) occurs (the leakage). Finally, a model was developed to explain the behavior of mobile reaction products in reactive barrier membranes. Although the goal of the technology is to avoid such products, it is important to be able to predict how these products will behave. Interestingly, calculations show that for any mobile reaction products, one half of the mass will diffuse into the containment area and one half will escape, assuming that the volumes of the containment area and the surrounding environment are much larger than the barrier membrane. These parameters/models will aid in the effective design of barrier membranes.

William A. Arnold; Edward L. Cussler

2007-02-26T23:59:59.000Z

408

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents (OSTI)

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

409

Kinetic azeotropy and design of reactive distillation columns  

SciTech Connect

The reactive fixed points in the distillation maps of a reactive distillation column (RDC) with kinetically controlled reactions are identified and their role in deciding the design feasibility has been elucidated. The fixed points at which both reaction and distillation vectors have zero magnitudes correspond to the equilibrium fixed point. It is known that the relative positions of these points for the rectifying and stripping sections determine the value of the minimum reflux ratio. However, apart from these fixed points, there are certain fixed points in the distillation map at which, though the reaction and distillation vectors have nonzero magnitudes, they nullify the effects of each other. These points correspond to the kinetic fixed points and have a special significance. Their positions have direct influence on the feasible product composition. A simple example of an ideal ternary system undergoing a reaction 2B {longleftrightarrow} A + c has been illustrated to show the importance of kinetic azeotropy in the design aspects of RDC.

Mahajani, S.M. [Monash Univ., Clayton, Victoria (Australia). Dept. of Chemical Engineering] [Monash Univ., Clayton, Victoria (Australia). Dept. of Chemical Engineering

1999-01-01T23:59:59.000Z

410

Reactivity Effects of Differences Between JEFF-3.1 and ENDF/B-VI.8 in Analysis of Six MASURCA Cores of the R-Z Program  

SciTech Connect

Six early cores of the MASURCA R-Z program were modeled using ERANOS 2.1. These cores were designed such that their neutron spectra would be similar to that of an oxide-fueled sodium-cooled fast reactor, some containing enriched uranium and others containing depleted uranium and plutonium. Effects of modeling assumptions and solution methods both in ECCO lattice calculations and in BISTRO Sn flux solutions were evaluated using JEFF-3.1 cross-section libraries. Reactivity effects of differences between JEFF-3.1 and ENDF/B-VI.8 were also quantified using perturbation theory analysis. The most important nuclide with respect to reactivity differences between cross-section libraries was 23Na, primarily a result of differences in the angular dependence of elastic scattering which is more forward-peaked in ENDF/B-VI.8 than in JEFF-3.1. Differences in 23Na inelastic scattering cross-sections between libraries also generated significant differences in reactivity, more due to the differences in magnitude of the cross-sections than the angular dependence. The nuclide 238U was also found to be important with regard to reactivity differences between the two libraries mostly due to a large effect of inelastic scattering differences and two smaller effects of elastic scattering and fission cross-sections. In the cores which contained plutonium, 239Pu fission cross-section differences contributed significantly to the reactivity differences between libraries.

MIchael A. Pope

2010-02-01T23:59:59.000Z

411

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide  

SciTech Connect

Cerium oxide is a principal component in many heterogeneous catalytic processes. One of its key characteristics is the ability to provide or remove oxygen in chemical reactions. The different crystallographic faces of ceria present significantly different surface structures and compositions that may alter the catalytic reactivity. The structure and composition determine the number of coordination vacancies surrounding surface atoms, the availability of adsorption sites, the spacing between adsorption sites and the ability to remove O from the surface. To investigate the role of surface orientation on reactivity, CeO2 films were grown with two different orientations. CeO2(100) films were grown ex situ by pulsed laser deposition on Nb-doped SrTiO3(100). CeO2(111) films were grown in situ by thermal deposition of Ce metal onto Ru(0001) in an oxygen atmosphere. The chemical reactivity was characterized by the adsorption and decomposition of various molecules such as alcohols, aldehydes and organic acids. In general the CeO2(100) surface was found to be more active, i.e. molecules adsorbed more readily and reacted to form new products, especially on a fully oxidized substrate. However the CeO2(100) surface was less selective with a greater propensity to produce CO, CO2 and water as products. The differences in chemical reactivity are discussed in light of possible structural terminations of the two surfaces. Recently nanocubes and nano-octahedra have been synthesized that display CeO2(100) and CeO2(111) faces, respectively. These nanoparticles enable us to correlate reactions on high surface area model catalysts at atmospheric pressure with model single crystal films in a UHV environment.

Mullins, David R [ORNL] [ORNL; Albrecht, Peter M [ORNL] [ORNL; Calaza, Florencia C [ORNL] [ORNL

2013-01-01T23:59:59.000Z

412

Die singulation method  

DOE Patents (OSTI)

A method is disclosed for singulating die from a semiconductor substrate (e.g. a semiconductor-on-insulator substrate or a bulk silicon substrate) containing an oxide layer (e.g. silicon dioxide or a silicate glass) and one or more semiconductor layers (e.g. monocrystalline or polycrystalline silicon) located above the oxide layer. The method etches trenches through the substrate and through each semiconductor layer about the die being singulated, with the trenches being offset from each other around at least a part of the die so that the oxide layer between the trenches holds the substrate and die together. The trenches can be anisotropically etched using a Deep Reactive Ion Etching (DRIE) process. After the trenches are etched, the oxide layer between the trenches can be etched away with a HF etchant to singulate the die. A release fixture can be located near one side of the substrate to receive the singulated die.

Swiler, Thomas P [Albuquerque, NM; Garcia, Ernest J [Albuquerque, NM; Francis, Kathryn M [Rio Rancho, NM

2014-01-07T23:59:59.000Z

413

Initiation and reactivation of Proterozoic aulacogen, northern Mexico  

SciTech Connect

Geochemical and petrologic affinities of late Proterozoic (approx. 1Ga) bimodal igneous rocks of the Franklin Mountains, west Texas, suggest a rift origin. Scattered occurrences of similar rocks southward into the state of Chihuahua, Mexico, indicate a southerly trend for the feature. The feature is bounded by stable blocks: the stable craton of west Texas to the east and northeast, and the Sierra del Nido block to the west and southwest. Separation of the Sierra del Nido block from the craton occurred about 1 Ga. Gravity gradients mark the boundaries of the blocks, and a northwest-trending Bouger gravity high may mark the axis of the aulacogen. The aulacogen and the Sierra del Nido block are truncated to the south by the Mesozoic Mojave-Sonora discontinuity. The aulacogen was reactivated, at least in part, in the late Paleozoic as the Pedregosa basin and in the Mesozoic as the Chihuahua trough. These reactivations were apparently not full-fledged rifting events, but did result in basin development. The Sierra del Nido block was a paleographic high throughout the Paleozoic, and the Aldama platform developed on this block during the Cretaceous. The most recent reactivation of the aulacogen is as the southern extension of the Rio Grande rift, as evidenced by trends of high heat flow, recent mafic magmatism, and regional extensional faulting.

Goodell, P.C.; Dyer, R.; Keller, G.R.

1985-02-01T23:59:59.000Z

414

Bioassays for the detection of chemicals that can form bioactivation-dependent reactive free radicals  

SciTech Connect

In vitro bioassays were developed for the detection of chemicals that can be bioactivated to reactive free radical species in microsomal fractions. Two methods were deployed, a down-scaled spectrophotometric method for the detection of chemicals that can cause lipid peroxidation using the measurement of thiobarbituric acid-reactive substances (TBARS) and a fluorometric method for the detection of chemicals that can undergo redox cycling to generate superoxide radicals based on the detection of hydrogen peroxide. The response of these systems to prototypical and environmentally relevant chemicals, including tetrachloromethane and paraquat, was examined. The detection limit of the lipid peroxidation bioassay, based on the formation of TBARS, was about 1 [micro]M for tetrachloromethane; that of the bioassay for redox cyclers, based on the production of hydrogen peroxide, was about 2 [micro]M for paraquat and about 100-fold lower for the potent redox cycler 2,3,5,6-tetramethylbenzoquinone (TMBQ). Several binary mixtures of chemicals were tested for potential nonadditive effects in both in vitro systems. Some antagonistic effects among halogenated methanes were observed in the lipid peroxidation assay. In the hydrogen peroxide production assay, greater than additive effects were seen between small concentrations of paraquat and TMBQ. A number of surface water concentrates from several locations in The Netherlands, with various levels of chemical contamination, exhibited a weak response in the hydrogen peroxide production assay. Acetone was found to interfere with the response of the bioassay to redox cyclers and, therefore, the water concentrates (originally in acetone) were transferred to ethanol prior to testing. A good correlation was observed between the response of the water concentrates in the hydrogen peroxide production assay and their acute toxicity in Daphnia magna. No correlation was observed between this bioassay response and toxicity in the Microtox[trademark] assay using Photobacterium phosphoreum.

Sanderson, J.T.; Commandeur, J.N.M.; Wezel, A. van; Vermeulen, N.P.E. (Free Univ. of Amsterdam (Netherlands). Div. of Molecular Toxicology National Inst. for Coastal and Marine Management, Den Haag (Netherlands))

1999-06-01T23:59:59.000Z

415

Dependence of post-drop reactivity on data analysis model for rod drop experiment in a subcritical reactor with external source  

SciTech Connect

This paper presents an improved rod-drop reactivity and source strength measurement by the inverse kinetics method in subcritical reactor system. The inverse kinetics method extended to be applicable to subcritical system, which is referred to as least squares inverse kinetics method (LSIKM), can estimate both the reactivity and the external source strength by applying least square approximation. However, the application of the conventional fitting model of the LSIKM to fluctuating data leads to serious errors in the estimation. In this study, a specific fitting model proposed by Itagaki and Kitano is used for the LSIKM and the effectiveness for fluctuating data is demonstrated experimentally. Furthermore, the spatial dependence of the estimated results is investigated and the reduction method is proposed. (authors)

Taninaka, H. [Interdisciplinary Graduate School of Science and Technology, Kinki Univ., 3-4-1, Kowakae, Higashi-Osaka, 577-8502 (Japan); Hashimoto, K. [Atomic Energy Research Inst., Kinki Univ., 3-4-1, Kowakae, Higashi-Osaka, 577-8502 (Japan)

2006-07-01T23:59:59.000Z

416

Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns  

SciTech Connect

Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs generally have low volatilities and are combustion-resistant, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of primary radiation chemistry, charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of reactions and product distributions. We study these issues by characterization of primary radiolysis products and measurements of their yields and reactivity, quantification of electron solvation dynamics and scavenging of electrons in different states of solvation. From this knowledge we wish to learn how to predict radiolytic mechanisms and control them or mitigate their effects on the properties of materials used in nuclear fuel processing, for example, and to apply IL radiation chemistry to answer questions about general chemical reactivity in ionic liquids that will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that the slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increase the importance of pre-solvated electron reactivity and consequently alter product distributions and subsequent chemistry. This difference from conventional solvents has profound effects on predicting and controlling radiolytic yields, which need to be quantified for the successful use under radiolytic conditions. Electron solvation dynamics in ILs are measured directly when possible and estimated using proxies (e.g. coumarin-153 dynamic emission Stokes shifts or benzophenone anion solvation) in other cases. Electron reactivity is measured using ultrafast kinetics techniques for comparison with the solvation process.

Wishart, J.F.

2011-06-12T23:59:59.000Z

417

Performance of a Permeable Reactive Barrier Using Granular Zero-Valent  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Performance of a Permeable Reactive Barrier Using Granular Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing

418

Types of Oil Shale Ash and Methods for Increasing their Reactivity  

Science Journals Connector (OSTI)

In the Republic of Estonia, electricity is produced by high-temperature (1200-1400C) combustion of powdered oil shale, which contains 20-25% organic matter...Table 1)[1]. It has a heating value of 8-10 MJ/kg. Be...

R. Kuusik; T. Kaljuvee

2000-01-01T23:59:59.000Z

419

REACTIVE FLOW IN VUGGY CARBONATES: METHODS AND MODELS APPLIED TO MATRIX ACIDIZING OF CARBONATES  

E-Print Network (OSTI)

Carbonates invariably have small (micron) to large (centimeter) scale heterogeneities in flow properties that may cause the effects of injected acids to differ greatly from what is predicted by a model based on a homogenous formation. To the best...

Izgec, Omer

2010-07-14T23:59:59.000Z

420

An Operator Splitting Method for Nonlinear Reactive Transport Equations and Its  

E-Print Network (OSTI)

model ground- water contaminant biodegradation and many other interesting applications. The proposed contaminants in groundwater provides valuable guidelines for in-situ remediation strategies. Injection

Ewing, Richard E.

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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to obtain the most current and comprehensive results.


421

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. 1. Reactivity Based Trading and Potential for Ozone Hot Spot Formation  

Science Journals Connector (OSTI)

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. ... (12)?Thompson, T. M.; Wang, L.; Web, A.; McDonald-Buller, E.; Allen, D. T. Photochemical Modeling of the Air Quality Impacts of an Emissions Trading Program for Highly Reactive Volatile Organic Compounds (HRVOCs) in Texas; Air and Waste Management Association Annual Meeting, New Orleans, June, 2006. ...

Linlin Wang; Tammy Thompson; Elena C. McDonald-Buller; Alba Webb; David T. Allen

2007-02-27T23:59:59.000Z

422

Photovoltaic solar system connected to the electric power grid operating as active power generator and reactive power compensator  

SciTech Connect

In the case of photovoltaic (PV) systems acting as distributed generation (DG) systems, the DC energy that is produced is fed to the grid through the power-conditioning unit (inverter). The majority of contemporary inverters used in DG systems are current source inverters (CSI) operating at unity power factor. If, however, we assume that voltage source inverters (VSI) can replace CSIs, we can generate reactive power proportionally to the remaining unused capacity at any given time. According to the theory of instantaneous power, the inverter reactive power can be regulated by changing the amplitude of its output voltage. In addition, the inverter active power can be adjusted by modifying the phase angle of its output voltage. Based on such theory, both the active power supply and the reactive power compensation (RPC) can be carried out simultaneously. When the insolation is weak or the PV modules are inoperative at night, the RPC feature of a PV system can still be used to improve the inverter utilisation factor. Some MATLAB simulation results are included here to show the feasibility of the method. (author)

Albuquerque, Fabio L.; Moraes, Adelio J.; Guimaraes, Geraldo C.; Sanhueza, Sergio M.R.; Vaz, Alexandre R. [Universidade Federal de Uberlandia, Uberlandia-MG, CEP 38400-902 (Brazil)

2010-07-15T23:59:59.000Z

423

Strontium isotope geochemistry of alluvial groundwater: a tracer for groundwater resources characterisation Hydrology and Earth System Sciences, 8(5), 959972 (2004) EGU  

E-Print Network (OSTI)

Strontium isotope geochemistry of alluvial groundwater: a tracer for groundwater resources characterisation 959 Hydrology and Earth System Sciences, 8(5), 959972 (2004) © EGU Strontium isotope geochemistry for corresponding author : p.negrel@brgm.fr Abstract This study presents strontium isotope and major ion data

Paris-Sud XI, Université de

424

Project EARTH-13-GMH2: U-series nuclides as tracers of modern ocean processes Supervisors: Prof. Gideon Henderson and Dr. Alex Thomas  

E-Print Network (OSTI)

flow of Atlantic deep water during the Last Glacial Maximum', Nature. Vol. 468, pp. 84 #12;Project EARTH-13-GMH2: U-series nuclides as tracers of modern ocean processes Supervisors: Prof provides information about the removal rate of material from the water-column and, for the former, about

Henderson, Gideon

425

Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation  

SciTech Connect

Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH{sub 4}{sup +} production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface.

Wu, Y.; Ajo-Franklin, J.B.; Spycher, N.; Hubbard, S.S.; Zhang, G.; Williams, K.H.; Taylor, J.; Fujita, Y.; Smith, R.

2011-07-15T23:59:59.000Z

426

Reactive sticking coefficients for silane and disilane on polycrystalline silicon  

SciTech Connect

Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition-rate measurements using molecular beam scattering and a very low-pressure cold-wall reactor. The RSCs have nonlinear Arrhenius temperature dependencies and decrease with increasing flux at low (710 /sup 0/C) temperatures. Several simple models are proposed to explain these observations. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction and low-pressure chemical vapor deposition-rate measurements.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1988-04-15T23:59:59.000Z

427

Modeling biogechemical reactive transport in a fracture zone  

SciTech Connect

A coupled model of groundwater flow, reactive solute transport and microbial processes for a fracture zone of the Aspo site at Sweden is presented. This is the model of the so-called Redox Zone Experiment aimed at evaluating the effects of tunnel construction on the geochemical conditions prevailing in a fracture granite. It is found that a model accounting for microbially-mediated geochemical processes is able to reproduce the unexpected measured increasing trends of dissolved sulfate and bicarbonate. The model is also useful for testing hypotheses regarding the role of microbial processes and evaluating the sensitivity of model results to changes in biochemical parameters.

Molinero, Jorge; Samper, Javier; Yang, Chan Bing, and Zhang, Guoxiang; Guoxiang, Zhang

2005-01-14T23:59:59.000Z

428

Determination of the relative power density distribution in a heterogeneous reactor from the results of measurements of the reactivity effects and the neutron importance function  

SciTech Connect

A method for experimental determination of the relative power density distribution in a heterogeneous reactor based on measurements of fuel reactivity effects and importance of neutrons from a californium source is proposed. The method was perfected on two critical assembly configurations at the NARCISS facility of the Kurchatov Institute, which simulated a small-size heterogeneous nuclear reactor. The neutron importance measurements were performed on subcritical and critical assemblies. It is shown that, along with traditionally used activation methods, the developed method can be applied to experimental studies of special features of the power density distribution in critical assemblies and reactors.

Bobrov, A. A.; Glushkov, E. S.; Zimin, A. A.; Kapitonova, A. V.; Kompaniets, G. V.; Nosov, V. I., E-mail: rpp@adis.vver.kiae.ru; Petrushenko, R. P.; Smirnov, O. N. [Russian Research Centre Kurchatov Institute (Russian Federation)

2012-12-15T23:59:59.000Z

429

Synthesis of belite cement clinker of high hydraulic reactivity  

SciTech Connect

This study is concerned with the increase of the cooling rate of belite clinker, by using the water quenching for the chemical stabilization of reactive belite, which improves the hydraulic properties of this clinker. The addition of adequate mineralizers, as NaF and Fe{sub 2}O{sub 3}, contributes to the improvement of the clinker properties obtained at low burning temperature. X-ray fluorescence spectroscopy, X-ray diffraction analysis and optical microscopy were used to determine the chemical and mineralogical compositions of this clinker. The samples were analyzed by means of a scanning electronic microscope connected with an energy-dispersive X-ray spectrometer to detect the composition of the belite phase and its morphology. Physical and mechanical properties of this clinker cement were determined. The results show that the belite clinker obtained at 1150 {sup o}C, with lime saturation factor 0.67, is characterized by a great hydraulic reactivity, similar to that of the ordinary alite clinker. The addition of 2% of NaF and the water quenching improved the chemical, mineralogical and structural properties, while improving the cement hydraulic properties.

Kacimi, Larbi [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)], E-mail: kacimi20002000@yahoo.fr; Simon-Masseron, Angelique [Laboratoire des Materiaux a Porosite Controlee, CNRS UMR 7016, Universite de Haute-Alsace, 3, rue Alfred-Werner, F-68093 Mulhouse cedex (France)], E-mail: A.Simon@univ-mulhouse.fr; Salem, Souria [Departement d'Architecture, Faculte de Genie Civile, USTO-Oran (Algeria)], E-mail: zinaisalem@yahoo.fr; Ghomari, Abdelhamid [Departement de Chimie, U.A.I.B., Route de Belahcel, Mostaganem (Algeria)], E-mail: belkey@hotmail.com; Derriche, Zoubir [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)

2009-07-15T23:59:59.000Z

430

Interaction phenomena at reactive metal/ceramic interfaces.  

SciTech Connect

The objective of this study was to understand the interface chemical reactions between stable ceramics and reactive liquid metals, and developing microstructure. Experiments were conducted at elevated temperatures where small metal samples of Zr and Zr-alloy were placed on top of selected oxide and non-oxide ceramic substrates (Y{sub 2}O{sub 3}, ZrN, ZrC, and HfC). The sample stage was heated in high-purity argon to about 2000 C, held in most cases for five minutes at the peak temperature, and then cooled to room temperature at {approximately}20 c/min. An external video camera was used to monitor the in-situ wetting and interface reactions. Post-test examinations of the systems were conducted by scanning electron microscopy and energy dispersive spectroscopy. It was determined that the Zr and the Zr-alloy are very active in the wetting of stable ceramics at elevated temperatures. In addition, in some systems, such as Zr/ZrN, a reactive transition phase formed between the ceramic and the metal. In other systems, such as Zr/Y{sub 2}O{sub 3}, Zr/ZrC and Zr/HfC, no reaction products formed, but a continuous and strong joint developed under these circumstances also.

McDeavitt, S. M.; Billings, G. W.; Indacochea, J. E.

2000-11-03T23:59:59.000Z

431

Electrochemical behavior of reactively sputtered iron-doped nickel oxide  

SciTech Connect

Iron-doped nickel oxide films were deposited by reactive sputtering from elemental and alloy targets in a 20% oxygen/argon atmosphere and were characterized for use as oxygen evolution catalysts. The incorporation of iron reduced the overpotential required for oxygen evolution by as much as 300 mV at a current density of 100 mA/cm{sup 2} compared to undoped nickel oxide deposited under similar conditions. Tafel slopes were reduced from 95 mV/dec in undoped NiO{sub x} films to less than 40 mV/dec for films containing 1.6 to 5.6 mole percent (m/o) iron, indicating a change in the rate-limiting step from the primary discharge of OH{sup {minus}} ions to the recombination of oxygen radicals. Resistivity, structural, and compositional measurements indicate that high oxygen content is necessary to gain the full benefit of the iron dopant. Initial tests in KOH indicate excellent long-term stability. A film deposited from the FeNi alloy target, which exhibited low oxygen overpotentials and a Tafel slope of 35 mV/dec, had not degraded appreciably following more than 7,000 h of operation at an anodic current density of 20 mA/cm{sup 2}. Taken together, the low oxygen evolution reaction overpotentials, the excellent stability in KOH, and the relative insensitivity to iron content indicative that reactively sputtered iron-doped nickel oxide is promising as an oxygen catalyst.

Miller, E.L.; Rocheleau, R.E. [Univ. of Hawaii, Honolulu, HI (United States)

1997-09-01T23:59:59.000Z

432

Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.  

SciTech Connect

In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

2012-02-01T23:59:59.000Z

433

Reactive-coupling-induced normal mode splittings in microdisk resonators coupled to waveguides  

SciTech Connect

We study the optomechanical design introduced by M. Li et al. [Phys. Rev. Lett. 103, 223901 (2009)], which is very effective for investigation of the effects of reactive coupling. We show the normal mode splitting that is due solely to reactive coupling rather than due to dispersive coupling. We suggest feeding the waveguide with a pump field along with a probe field and scanning the output probe for evidence of reactive-coupling-induced normal mode splitting.

Huang Sumei; Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)

2010-05-15T23:59:59.000Z

434

Tracer dye transport from a well fitted with a downhole heat exchanger, Klamath Falls, Oregon  

SciTech Connect

Low or medium temperature geothermal resources are often used for space and domestic hot water heating. If the resource is located at reasonably shallow depths and adjacent to a major population centre large amounts of relatively cheap, clean heat can be provided. Geothermal fluid is often brought to the surface, either under natural artesian pressure or by pumping, to be used in surface heat exchangers (SHEs). This method generally requires a second well for disposal of the cooled fluid and a substantial capital outlay for pumps and heat exchangers. Large amounts of heat can be extracted from just one or two wells using surface heat exchangers and the method can prove very cost effective in areas with a high density of energy intensive users. For smaller heat loads surface heat exchangers can become expensive and in many instances a downhole heat exchanger (DHE) installed directly in the well bore is capable of supplying cheap heat to a smaller number of users. This report first describes the methods used to carry out the series of dye tests, from well selection to injection of the dye samples. It then discusses the results of these tests in terms of how much dye was recovered, where it was recovered from and how long it took to arrive. The results of the concurrent temperature monitoring work and DHE heat output performance are also presented. Some recommendations are made for any future testing. 13 refs., 42 figs.

Dunstall, M.G.

1990-02-01T23:59:59.000Z

435

Promoting the Reduction Reactivity of Ilmenite by Introducing Foreign Ions in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Promoting the Reduction Reactivity of Ilmenite by Introducing Foreign Ions in Chemical Looping Combustion ... Industrial & Engineering Chemistry Research2014 53 (39), 15157-15166 ...

Jinhua Bao; Zhenshan Li; Ningsheng Cai

2013-04-15T23:59:59.000Z

436

Removal and Recycling of Phosphorus from Wastewater Using Reactive Filter Material Polonite.  

E-Print Network (OSTI)

?? Literature reviews and laboratory work were used to examine the phosphorus removal efficiency of the reactive filter material Polonite. This material is produced from (more)

sterberg, Anna

2012-01-01T23:59:59.000Z

437

Control of nanoparticle size, reactivity and magnetic properties during the bioproduction of magnetite by Geobacter sulfurreducens  

E-Print Network (OSTI)

Control of nanoparticle size, reactivity and magneticbenign route to magnetic nanoparticle synthesis. Here, wed In both thin film and nanoparticle formation, the dominant

Byrne, J. M.

2012-01-01T23:59:59.000Z

438

Natural nanoparticle structure, properties and reactivity from X-ray studies  

E-Print Network (OSTI)

Another important aspect of nanoparticle work relates to theWe thus expect that nanoparticle research will also shedNATURAL NANOPARTICLE STRUCTURE, PROPERTIES AND REACTIVITY

Waychunas, Glenn A.

2010-01-01T23:59:59.000Z

439

E-Print Network 3.0 - administration reduces reactive Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

reactive power losses, and increasing line charging and shunt capacitor... Summary Bonneville Power Administration is investigating wide-area stability and voltage...

440

Moderator displacers for reducing coolant void reactivity in CANDU reactors: a neutronics scoping study.  

E-Print Network (OSTI)

??When the coolant is voided in a CANDU lattice, the net reactivity change is positive, due primarily to the fact that the coolant and moderator (more)

Farkas, Robert

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Simulations of Deflagration-to-Detonation Transition in Reactive Gases |  

NLE Websites -- All DOE Office Websites (Extended Search)

numerically generated pseudo-schlieren image numerically generated pseudo-schlieren image Weak ignition behind a reflected Mach=1.5 shock in a stoichiometric hydrogen-oxygen mixture at 0.1 atm initial pressure. Picture shows a numerically generated pseudo-schlieren image of the onset of a detonation in a turbulent boundary layer. Alexei Khokhlov, University of Chicago; Charles Bacon, Argonne National Laboratory, Joanna Austin, Andrew Knisely, University of Illinois at Urbanna-Champaign Simulations of Deflagration-to-Detonation Transition in Reactive Gases PI Name: Alexei Khokhlov PI Email: ajk@oddjob.uchicago.edu Institution: The University of Chicago Allocation Program: INCITE Allocation Hours at ALCF: 130 Million Year: 2013 Research Domain: Chemistry Hydrogen is an abundant, environmentally friendly fuel with the potential

442

Development of a standard for calculation and measurement of the moderator temperature coefficient of reactivity in water-moderated power reactors  

SciTech Connect

The contents of ANS 19.11, the standard for ``Calculation and Measurement of the Moderator Temperature Coefficient of Reactivity in Water-Moderated Power Reactors,`` are described. The standard addresses the calculation of the moderator temperature coefficient (MTC) both at standby conditions and at power. In addition, it describes several methods for the measurement of the at-power MTC and assesses their relative advantages and disadvantages. Finally, it specifies a minimum set of documentation requirements for compliance with the standard.

Mosteller, R.D. [Los Alamos National Lab., NM (United States); Hall, R.A. [Virginia Power, Glen Allen, VA (United States). Innsbrook Technical Center; Apperson, C.E. Jr. [Westinghouse Safety Management Solutions, Inc., Aiken, SC (United States); Lancaster, D.B. [TRW Environmental Safety Systems, Inc., Vienna, VA (United States); Young, E.H. [Commonwealth Edison Co., Downers Grove, IL (United States); Gavin, P.H. [ABB Combustion Engineering, Windsor, CT (United States); Robertson, S.T. [Framatome/COGEMA Fuels, Lynchburg, VA (United States)

1998-12-01T23:59:59.000Z

443

Application of a NAPL partitioning interwell tracer test (PITT) to support DNAPL remediation at the Sandia National Laboratories/New Mexico chemical waste landfill  

SciTech Connect

Chlorinated solvents as dense non-aqueous phase liquid (DNAPL) are present at a large number of hazardous waste sites across the U.S. and world. DNAPL is difficult to detect in the subsurface, much less characterize to any degree of accuracy. Without proper site characterization, remedial decisions are often difficult to make and technically effective, cost-efficient remediations are even more difficult to obtain. A new non-aqueous phase liquid (NAPL) characterization technology that is superior to conventional technologies has been developed and applied at full-scale. This technology, referred to as the Partitioning Interwell Tracer Test (PITT), has been adopted from oil-field practices and tailored to environmental application in the vadose and saturated zones. A PITT has been applied for the first time at full-scale to characterize DNAPL in the vadose zone. The PITT was applied in December 1995 beneath two side-by-side organic disposal pits at Sandia National Laboratories/New Mexico (SNL/NM) RCRA Interim Status Chemical Waste Landfill (CWL), located in Albuquerque, New Mexico. DNAPL, consisting of a mixture of chlorinated solvents, aromatic hydrocarbons, and PCE oils, is known to exist in at least one of the two buried pits. The vadose zone PITT was conducted by injecting a slug of non-partitioning and NAPL-partitioning tracers into and through a zone of interest under a controlled forced gradient. The forced gradient was created by a balanced extraction of soil gas at a location 55 feet from the injector. The extracted gas stream was sampled over time to define tracer break-through curves. Soil gas sampling ports from multilevel monitoring installations were sampled to define break-through curves at specific locations and depths. Analytical instrumentation such as gas chromatographs and a photoacoustical analyzers operated autonomously, were used for tracer detection.

Studer, J.E. [INTERA Inc., Albuquerque, NM (United States); Mariner, P.; Jin, M. [INTERA Inc., Austin, TX (United States)] [and others

1996-05-01T23:59:59.000Z

444

DATE  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2 2 CX Posting No.: DOE-ID-INL-10-003 SECTION A. Project Title: American Recovery and Reinvestment Act (ARRA) Reactive Tracers. SECTION B. Project Description The American Recovery and Reinvestment Act (ARRA) Reactive Tracers project will be conducted at both the Raft River hydrothermal site in South Central Idaho and at the INL Research Center in Idaho Falls. The purpose of this work is to characterize tracers and test these tracers at the Raft River project through use of tracers and methods under realistic conditions. INL researchers will use an existing commercial hydrothermal site at Raft River that is currently operated by U.S. Geothermal, Inc. (USG), with whom INL has established a Cooperative Research and Development Agreement (CRADA) partnership. Numerous wells have previously been

445

DATE  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 CX Posting No.: DOE-ID-INL-10-003 SECTION A. Project Title: American Recovery and Reinvestment Act (ARRA) Reactive Tracers. SECTION B. Project Description The American Recovery and Reinvestment Act (ARRA) Reactive Tracers project will be conducted at both the Raft River hydrothermal site in South Central Idaho and at the INL Research Center in Idaho Falls. The purpose of this work is to characterize tracers and test these tracers at the Raft River project through use of tracers and methods under realistic conditions. INL researchers will use an existing commercial hydrothermal site at Raft River that is currently operated by U.S. Geothermal, Inc. (USG), with whom INL has established a Cooperative Research and Development Agreement (CRADA) partnership. Numerous wells have previously been

446

TRAVELING WAVES IN 2D REACTIVE BOUSSINESQ SYSTEMS WITH NO-SLIP BOUNDARY CONDITIONS  

E-Print Network (OSTI)

TRAVELING WAVES IN 2D REACTIVE BOUSSINESQ SYSTEMS WITH NO-SLIP BOUNDARY systems of reactive Boussinesq equations in two di* *men- sional strips that are not aligned Boussinesq systems with no-slip boundary conditions (the fluid flow vanishes at* * the boundary). Much

Constantin, Peter

447

Computational mapping reveals dramatic effect of Hoogsteen breathing on duplex DNA reactivity  

E-Print Network (OSTI)

Computational mapping reveals dramatic effect of Hoogsteen breathing on duplex DNA reactivity Formaldehyde has long been recognized as a haz- ardous environmental agent highly reactive with DNA. Recently-ray and nuclear magnetic resonance techniques for observing weakly specific interactions of small organic

Vajda, Sandor

448

Multicomponent reactive transport modeling at the Ratones uranium mine, Cceres (Spain)  

E-Print Network (OSTI)

Multicomponent reactive transport modeling at the Ratones uranium mine, Cáceres (Spain) Modelación management. The Ratones uranium mine was abandoned and flooded in 1974. Due to its reducing underground water, uranium, reactive transport, granite hydrochemistry, Ratones mine. Resumen La inundación de minas

Politècnica de Catalunya, Universitat

449

Monaco-A domain-specific language solution for reactive process control programming with hierarchical components  

Science Journals Connector (OSTI)

In this paper, we present Monaco - a domain-specific language for developing event-based, reactive process control programs - and its visual interactive programming environment. The main purpose of the language is to bring process control programming ... Keywords: Automation control, Component-based systems, Domain-specific languages, Reactive programming

Herbert Prhofer; Roland Schatz; Christian Wirth; Dominik Hurnaus; Hanspeter Mssenbck

2013-10-01T23:59:59.000Z

450

General Multiobjective Force Field Optimization Framework, with Application to Reactive Force Fields for Silicon Carbide  

E-Print Network (OSTI)

Fields for Silicon Carbide Andres Jaramillo-Botero,* Saber Naserifar, and William A. Goddard, III: (1) the ReaxFF reactive force field for modeling the adiabatic reactive dynamics of silicon carbide specific force field parameters for tripod metal templates, tripodMO(CO)3, using the root mean square

Goddard III, William A.

451

Intelligent Voltage and Reactive Power Control of Mini-Hydro Power Stations for Maximisation of Real  

E-Print Network (OSTI)

of a Mini-Hydro Power Generator to the Rural Grid The UK distribution network has been significantly exten1 Intelligent Voltage and Reactive Power Control of Mini-Hydro Power Stations for Maximisation Control (APFC) modes. The ability to export active and reactive power from mini-hydro power generators

Harrison, Gareth

452

Reactive Power Operation Analysis of a Single-Phase EV/PHEV Bidirectional Battery Charger  

E-Print Network (OSTI)

--More battery powered electric vehicles (EVs) and plug-in hybrid electric vehicles (PHEVs) will be introduced, charger, electric vehicle, EV, PHEV, reactive power, V2G. I. INTRODUCTION According to the international of the electric grid by supplying ancillary services such as reactive power compensation, voltage regulation

Tolbert, Leon M.

453

Reactive transport model for the ambient unsaturated hydrogeochemical system at Yucca mountain, Nevada  

Science Journals Connector (OSTI)

To assist a technical review of a potential application for a geologic repository, a reactive transport model is presented for the ambient hydrogeochemical system at Yucca Mountain (YM). The model simulates two-phase, nonisothermal, advective and diffusive ... Keywords: Yucca mountain, geochemistry, groundwater chemistry, groundwater flow and transport, hydrology, reactive transport model, unsaturated zone

Lauren Browning; William M. Murphy; Chandrika Manepally; Randall Fedors

2003-04-01T23:59:59.000Z

454

Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column  

E-Print Network (OSTI)

Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column distillation columns have been explored in many papers, very few papers have dealt with closed-loop control. Most of these control papers consider reactive distillation columns in which there is only one product

Al-Arfaj, Muhammad A.

455

Optical fibers by butyl methacrylate reactive extrusion Berthet Romuald, Chalamet Yvan, Taha Mohamed*, Zerroukhi Amar  

E-Print Network (OSTI)

limitations. Reactive extrusion experiments were carried out in a twin-screw extruder and the effect optical fibbers, polymethacrylate. Introduction Twin screw extruders are playing an increasing role of reactive extrusion is explained by the different advantages offered by the use of the twin-screw extruders

Paris-Sud XI, Université de

456

Study of STATCOM on Reactive Power Compensation Strategy of Wind Farm  

Science Journals Connector (OSTI)

For voltage stability problems caused by grid-connected wind farms, a strategy of coordinated reactive power compensation is proposed in this paper. The strategy utilizes static synchronous compensator (STATCOM) and doubly-fed induction generator (DFIG) ... Keywords: Reactive Power Compensation Strategy, STATCOM, DFIG, Wind Farm

Hui Li; Shucai Li; Hao Zhang; Weihua Bao

2013-12-01T23:59:59.000Z

457

Joint optimization algorithm for network reconfiguration and reactive power control of wind farm in distribution system  

Science Journals Connector (OSTI)

In recent years, the number of small size wind farms used as DG sources located within the distribution system are rapidly increasing. Wind farm made up with doubly fed induction generators (DFIG) is proposed in this paper as the continuous reactive ... Keywords: DFIG wind turbine, network reconfiguration, particle swarm optimization, reactive power control, wind farm

Jingjing Zhao; Xin Li; Jiping Lu; Congli Zhang

2009-02-01T23:59:59.000Z

458

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH  

E-Print Network (OSTI)

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH Ojwang' J.G.O.*, Rutger van is the fall in potential energy surface during heating. Keywords: hydrogen storage, reactive force field governing hydrogen desorption in NaH. During the abstraction process of surface molecular hydrogen charge

Goddard III, William A.

459

Discovering Regulated Networks During HIV-1 Latency and Reactivation Sourav Bandyopadhyay, Ryan Kelley, and Trey Ideker  

E-Print Network (OSTI)

corresponding to stages of HIV synthesis. In the early stage, fully spliced mRNAs for Rev, Tat and NefDiscovering Regulated Networks During HIV-1 Latency and Reactivation Sourav Bandyopadhyay, Ryan NETWORKS DURING HIV-1 LATENCY AND REACTIVATION SOURAV BANDYOPADHYAY, RYAN KELLEY, TREY IDEKER1,2 1 Program

460

A gas-kinetic scheme for reactive ows Yongsheng Lian, Kun Xu*  

E-Print Network (OSTI)

A gas-kinetic scheme for reactive ¯ows Yongsheng Lian, Kun Xu* Department of Mathematics, Hong Kong in revised form 22 July 1999; accepted 22 July 1999 Abstract In this paper, the gas-kinetic BGK scheme for the compressible ¯ow equations is extended to chemical reactive ¯ow. The mass fraction of the unburnt gas

Xu, Kun

Note: This page contains sample records for the topic "reactive tracer methods" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

A Tariff for Reactive Power 0 100 200 300 400 500 600 700 800  

E-Print Network (OSTI)

to the distribution system economically by customers when new inverters are installed. The inverter would be supplied, and adjustable-speed motor drives. Index Terms--Inverter, Power Factor, Reactive Power, Tariff, Voltage efficiency. Reactive power is theoretically available from any inverter-based equipment such as photovoltaic

Pennycook, Steve

462

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials  

E-Print Network (OSTI)

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A and unpainted drywall as passive ozone control surfaces in a room-sized laboratory chamber. Mean deposition-50%, resulted in increased reactivity for activated carbon. In our model for a typical house, about 35

Siegel, Jeffrey

463

X-ray microtomography characterization of porosity, permeability and reactive surface changes during dissolution  

E-Print Network (OSTI)

X-ray microtomography characterization of porosity, permeability and reactive surface changes from X-ray microtomography data obtained before and after a set of dissolution experiments of pure.V. All rights reserved. Keywords: Reactive transport Carbon storage Permeability X-ray microtomography 1

Luquot, Linda

464

Studies on optoelectronic properties of DC reactive magnetron sputtered CdTe thin films  

SciTech Connect

Cadmium telluride continues to be a leading candidate for the development of cost effective photovoltaics for terrestrial applications. In the present work two individual metallic targets of Cd and Te were used for the deposition of CdTe thin films on mica substrates from room temperature to 300 C by DC reactive magnetron sputtering method. XRD patterns of CdTe thin films deposited on mica substrates exhibit peaks at 2? = 27.7, 46.1 and 54.6, which corresponds to reflection on (1 1 1), (2 2 0) and (3 1 1) planes of CdTe cubic structure. The intensities of XRD patterns increases with the increase of substrate temperature upto 150 C and then it decreases at higher substrate temperatures. The conductivity of CdTe thin films measured from four probe method increases with the increase of substrate temperature. The activation energies (?E) are found to be decrease with the increase of substrate temperature. The optical transmittance spectra of CdTe thin films deposited on mica have a clear interference pattern in the longer wavelength region. The films have good transparency (T > 85 %) exhibiting interference pattern in the spectral region between 1200 2500 nm. The optical band gap of CdTe thin films are found to be in the range of 1.48 1.57. The refractive index, n decreases with the increase of wavelength, ?. The value of n and k increases with the increase of substrate temperature.

Kumar, B. Rajesh, E-mail: rajphyind@gmail.com [Department of Physics, Sri Venkateswara University, Tirupati - 517 502, A.P, India and Department of Physics, Sri Krishnadevaraya University, Anantapur - 515 003, A.P (India); Hymavathi, B.; Rao, T. Subba [Department of Physics, Sri Krishnadevaraya University, Anantapur - 515 003, A.P (India)

2014-01-28T23:59:59.000Z

465

An Electrical Analogue for Analysis of Tracer Distribution Kinetics in Biological Systems Author(s): J. R. MacDonald, E. G. Perry, L. L. Madison, D. W. Seldin  

E-Print Network (OSTI)

(s): J. R. MacDonald, E. G. Perry, L. L. Madison, D. W. Seldin Source: Radiation Research, Vol. 6, No. 5 of Tracer Distribution Kinetics in Biological Systems1 J. R. MACDONALD AND E. G. PERRY Research Division

Macdonald, James Ross

466

Compatibility Analysis on Existing Reactivity Devices in CANDU 6 Reactors for DUPIC Fuel Cycle  

SciTech Connect

The performance of reactivity devices for a Canada deuterium uranium (CANDU) 6 reactor loaded with Direct Use of Spent Pressurized Water Reactor Fuel In CANDU reactors (DUPIC) fuel is assessed. The reactivity devices studied are the zone controller units, the adjuster rods, and the mechanical control absorbers. For the zone controller system, the bulk reactivity control, spatial power control, and damping capability for spatial oscillation are investigated. For the adjusters, the xenon override, restart after a poison-out, shim operation, and power step-back capabilities are confirmed. The mechanical control absorber is assessed for the function of compensating temperature reactivity feedback following a power reduction. This study shows that the current reactivity device system of a CANDU 6 reactor is compatible with DUPIC fuel for normal and transient operations.

Jeong, Chang-Joon; Choi, Hangbok [Korea Atomic Energy Research Institute (Korea, Republic of)

2000-03-15T23:59:59.000Z

467

Characterization and performance evaluation of a new passive neutron albedo reactivity counter for safeguards measurements  

Science Journals Connector (OSTI)

Abstract A prototype 3He-based Passive Neutron Albedo Reactivity (PNAR) counter was developed and tested at Los Alamos National Laboratory (LANL) in collaboration with the Korea Atomic Energy Research Institute (KAERI) to measure the fissile content in electrochemical recycling (ER) product materials. The counter consists of 16 3He cylindrical gas-filled proportional counters at 4atm of pressure embedded in high-density polyethylene. In this work, experimental measurements were performed at LANL to characterize the performance of the PNAR counter using surrogate materials for the uranium metal ingot. The purpose of these experiments was to: 1) measure the operating and calibration parameters of the PNAR counter (e.g. efficiency profiles, coincidence gate fractions, die-away time) and 2) evaluate the accuracy and sensitivity of the PNAR method and the time correlated induced fission (TCIF) method for quantifying the 235U mass in PWR fresh LEU fuel rods and Materials Testing Reactor (MTR) HEU fuel plates. A small 244Cm reference source (13,373 n/s) was placed in the center of the fuel rods and fuel plates to simulate spontaneous fission from sub-ppm (parts per million) levels of Cm contamination in the U ingot. In order to compare the relative accuracy of the PNAR and TCIF methods for quantifying 235U mass, calibration curves were generated for the net doubles rate and the doubles Cd ratio using the Deming software. The results from this experiment will be used to obtain a better understanding of the sensitivity of the PNAR and TCIF methods for samples with low neutron multiplication. Furthermore, this experimental measurement data will also help inform safeguards research and development (R&D) efforts on the viability of nondestructive assay (NDA) techniques and detector designs for quantifying fissile content in ER product materials. Future work will include performing measurements with the PNAR counter on small samples of U/TRU materials.

Adrienne M. LaFleur; Seong-Kyu Ahn; Howard O. Menlove; Michael C. Browne; Ho-Dong Kim

2014-01-01T23:59:59.000Z

468

Reactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms  

Science Journals Connector (OSTI)

Reactivity of coordinated [Ph2PCHP(S)Ph2]- and [Ph2P(S)CHP(S)Ph2]-: two-center, regiospecific reactivity in rhodium and iridium complexes and formation of a disubstituted methylene bridge between platinum atoms ...

Jane. Browning; Keith R. Dixon; Robert W. Hilts

1989-02-01T23:59:59.000Z

469

DOE/EA-1310: Environmental Assessment for Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Couples Fast Reactivity Measurements Facility at the Idaho National Engineering and Environmental Laboratory  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0 0 March 2000 Environmental Assessment for Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Coupled Fast Reactivity Measurements Facility at the Idaho National Engineering and Environmental Laboratory DOE/EA-1310 Environmental Assessment for Decontamination and Dismantlement of the Advanced Reactivity Measurement Facility and Coupled Fast Reactivity Measurements Facility at the Idaho National Engineering and Environmental Laboratory Published March 2000 Prepared for the U.S. Department of Energy Idaho Operations Office iii CONTENTS ACRONYMS ............................................................................................................................... v HELPFUL INFORMATION ........................................................................................................

470

Understanding the stability and reactivity of ultrathin tellurium nanowires in solution: An emerging platform for chemical transformation and material design  

Science Journals Connector (OSTI)

The stability and reactivity of nanomaterials are of crucial importance for their application, but the long-term effects of stability and reactivity of nanomaterials under practical conditions are still not well ...

Liang Xu; Hai-Wei Liang; Hui-Hui Li; Kai Wang; Yuan Yang; Lu-Ting Song

2014-11-01T23:59:59.000Z

471

A conceptual design of a Reactive Ion Etch back end system for the direct reuse of process gases  

E-Print Network (OSTI)

The use of Plasma Etching, specifically Reactive Ion Etching (RIE), is a vital tool in manufacturing semiconductor devices. Most gases used in RIE processes were initially chosen because of their relatively low toxicity and reactivity. However, many...

Tiner, Paul Alan

2012-06-07T23:59:59.000Z

472

Boron-carbide-aluminum and boron-carbide-reactive metal cermets. [B/sub 4/C-Al  

DOE Patents (OSTI)

Hard, tough, lighweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidated step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modules of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi..sqrt..in. These composites and methods can be used to form a variety of structural elements.

Halverson, D.C.; Pyzik, A.J.; Aksay, I.A.

1985-05-06T23:59:59.000Z

473

Final Report- Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support  

Energy.gov (U.S. Department of Energy (DOE))

Final Report - Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

474

LX-17 Corner-Turning and Reactive Flow Failure  

SciTech Connect

We have performed a series of highly-instrumented experiments examining corner-turning of detonation. A TATB booster is inset 15 mm into LX-17 (92.5% TATB, 7.5% kel-F) so that the detonation must turn a right angle around an air well. An optical pin located at the edge of the TATB gives the start time of the corner-turn. The breakout time on the side and back edges is measured with streak cameras. Three high-resolution X-ray images were taken on each experiment to examine the details of the detonation. We have concluded that the detonation cannot turn the corner and subsequently fails, but the shock wave continues to propagate in the unreacted explosive, leaving behind a dead zone. The detonation front farther out from the corner slowly turns and eventually reaches the air well edge 180{sup o} from its original direction. The dead zone is stable and persists 7.7 {micro}s after the corner-turn, although it has drifted into the original air well area. Our regular reactive flow computer models sometimes show temporary failure but they recover quickly and are unable to model the dead zones. We present a failure model that cuts off the reaction rate below certain detonation velocities and reproduces the qualitative features of the corner-turning failure.

Souers, P C; Andreski, H; Cook III, C F; Garza, R; Pastrone, R; Phillips, D; Roeske, F; Vitello, P; Molitoris, J

2004-03-11T23:59:59.000Z

475

Installation of reactive metals groundwater collection and treatment systems  

SciTech Connect

Three groundwater plumes contaminated with volatile organic compounds (VOCs) and radionuclides at the Rocky Flats Environmental Technology Site are scheduled for remediation by 1999 based on the Rocky Flats Cleanup Agreement (RFCA) (DOE, 1996). These three plumes are among the top 20 environmental cleanup sites at Rocky Flats. One of these plumes, the Mound Site Plume, is derived from a previous drum storage area, and daylights as seeps near the South Walnut Creek drainage. Final design for remediation of the Mound Site Plume has been completed based on use of reactive metals to treat the contaminated groundwater, and construction is scheduled for early 1998. The two other plumes, the 903 Pad/Ryan`s Pit and the East Trenches Plumes, are derived from VOCs either from drums that leaked or that were disposed of in trenches. These two plumes are undergoing characterization and conceptual design in 1998 and construction is scheduled in 1999. The contaminants of concern in these plumes are tetrachloroethene, trichloroethene, carbon tetrachloride and low levels of uranium and americium.

Hopkins, J.K.; Primrose, A.L. [Rocky Mountain Remediation Services, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site; Vogan, J. [EnviroMetal Technologies, Inc., Guelph, Ontario (Canada); Uhland, J. [Kaiser-Hill, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site

1998-07-01T23:59:59.000Z

476

Reactivity initiated accident test series Test RIA 1-4  

SciTech Connect

The Reactivity Initiated Accident (RIA) Test RIA 1-4, the first 9-rod fuel rod bundle RIA Test to be performed at BWR hot startup conditions, was completed on April 16, 1980. The test was performed in the Power Burst Facility (PBF). Objective for Test RIA 1-4 was to provide information regarding loss-of-coolable fuel rod geometry following a RIA event for a peak fuel enthalpy equivalent to the present licensing criteria of 280 cal/g. The most severe RIA is the postulated Boiling Water Reactor (BWR) control rod drop during reactor startup. Therefore the test was conducted at BWR hot startup coolant conditions (538 K, 6.45 MPa, 0.8 1/sec). The test sequence began with steady power operation to condition the fuel, establish a short-lived fission product inventory, and calibrate the calorimetric measurements and core power chambers, neutron flux and gamma flux detectors. The test train was removed from the in-pile tube (IPT) to replace one of the fuel rods with a nominally identical irradiated rod and twelve flux wire monitors. A 2.8 ms period power burst was then performed. Coolant flow measurements were made before and after the power burst to characterize the flow blockage that occurred as a result of fuel rod failure.

Martinson, Z.R.; El-Genk, M.S.; Fukuda, S.K.; LaPointe, R.E.; Osetek, D.J.

1980-05-01T23:59:59.000Z

477

SSC analysis of the GEMs for reactivity control in PRISM  

SciTech Connect

The performance of three Gas Expansion Modules (GEMS) utilized the Advanced Liquid Metal Reactor (ALMR) concept, PRISM, was analyzed using the computer code, SSC. GE has submitted the PRISM design for a Preapplication Safety Evaluation Report (PSER). The draft PSER indicated a potential weakness in the Unscrammed Loss of Flow (ULOF) event, and GE modified the design by adding three GEMs. The PRISM design was analyzed by SSC for two cases. First, the design`s original response to a ULOF where one Electro Magnetic (EM) pump fails to produce a coastdown was analyzed. Then the revised design with the GEMs included was analyzed. The original design had little or no safety margin for this case. The peak fuel temperature in the hot channel was predicted to be 1358K, which is above the solidus temperature of the fuel. However, after the GEMs were added, the loss of one EM pump coastdown became a benign event. The GEM feedback was predicted by SSC to dominate the other reactivity feedbacks and the GEMS, essentially, responded like passive control rods. The fuel temperature quickly dropped below operating temperatures, while the margin to sodium boiling was predicted to be greater than 350K.

Slovik, G.C.; Rodnizki, J.

1992-12-31T23:59:59.000Z

478

SSC analysis of the GEMs for reactivity control in PRISM  

SciTech Connect

The performance of three Gas Expansion Modules (GEMS) utilized the Advanced Liquid Metal Reactor (ALMR) concept, PRISM, was analyzed using the computer code, SSC. GE has submitted the PRISM design for a Preapplication Safety Evaluation Report (PSER). The draft PSER indicated a potential weakness in the Unscrammed Loss of Flow (ULOF) event, and GE modified the design by adding three GEMs. The PRISM design was analyzed by SSC for two cases. First, the design's original response to a ULOF where one Electro Magnetic (EM) pump fails to produce a coastdown was analyzed. Then the revised design with the GEMs included was analyzed. The original design had little or no safety margin for this case. The peak fuel temperature in the hot channel was predicted to be 1358K, which is above the solidus temperature of the fuel. However, after the GEMs were added, the loss of one EM pump coastdown became a benign event. The GEM feedback was predicted by SSC to dominate the other reactivity feedbacks and the GEMS, essentially, responded like passive control rods. The fuel temperature quickly dropped below operating temperatures, while the margin to sodium boiling was predicted to be greater than 350K.

Slovik, G.C.; Rodnizki, J.

1992-01-01T23:59:59.000Z

479

Reactivity of iron-bearing minerals and CO2 sequestration: A multi-disciplinary experimental approach  

SciTech Connect

The reactivity of sandstones was studied under conditions relevant to the injection of supercritical carbon dioxide in the context of carbon geosequestration. The emphasis of the study was on the reactivity of iron-bearing minerals when exposed to supercritical CO2 (scCO2) and scCO2 with commingled aqueous solutions containing H2S and/or SO2. Flow through and batch experiments were conducted. Results indicate that sandstones, irrespective of their mineralogy, are not reactive when exposed to pure scCO2 or scCO2 with commingled aqueous solutions containing H2S and/or SO2 under conditions simulating the environment near the injection point (flow through experiments). However, sandstones are reactive under conditions simulating the edge of the injected CO2 plume or ahead of the plume (batch experiments). Sandstones containing hematite (red sandstone) are particularly reactive. The composition of the reaction products is strongly dependent on the composition of the aqueous phase. The presence of dissolved sulfide leads to the conversion of hematite into pyrite and siderite. The relative amount of the pyrite and siderite is influenced by the ionic strength of the solution. Little reactivity is observed when sulfite is present in the aqueous phase. Sandstones without hematite (grey sandstones) show little reactivity regardless of the solution composition.

Schoonen, Martin A. [Stony Brook University] (ORCID:0000000271331160)

2014-12-22T23:59:59.000Z

480

Reactivity of low-valent nickel-1,3-BIS (o-Diphenylphosphinophenylthio) propane (arom-PSSP) with small molecules  

E-Print Network (OSTI)

The reactivity of NiO(arom-PSSP) with small molecules was studied in comparison to the reactivity of NIO(PSSP) which was studied by previous members of our group. The low-valent nickel atom in this arom-PSSP ligand exhibited reactivity toward small...

Kang, Jeehee

2012-06-07T23:59:59.000Z

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