National Library of Energy BETA

Sample records for reactive tracer methods

  1. Advancing Reactive Tracer Methods for Measurement of Thermal...

    Office of Scientific and Technical Information (OSTI)

    These methods included (1) mathematical investigation of the sensitivity of known and hypothetical reactive tracers, (2) laboratory testing of novel tracers that would improve ...

  2. Advancing reactive tracer methods for measuring thermal evolution in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2-and water-based geothermal reservoirs | Department of Energy Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs DOE Geothermal Peer Review 2010 - Presentation. This project aims to develop reactive tracer method for monitoring thermal drawdown in enhanced geothermal systems. tracers_hull_thermal_evolution.pdf (852.51

  3. Advancing Reactive Tracer Methods for Measuring Thermal Evolution...

    Open Energy Info (EERE)

    and interpret reactive tracer tests - Development of suitable tracers to cover a range of reservoir temperature and residence time conditions - Testing the tools and tracers in a...

  4. Advancing reactive tracer methods for measuring thermal evolution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ....51 KB) More Documents & Publications Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area ...

  5. ADVANCING REACTIVE TRACER METHODS FOR MONITORING THERMAL DRAWDOWN IN GEOTHERMAL ENHANCED GEOTHERMAL RESERVOIRS

    SciTech Connect (OSTI)

    Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; George D. Redden; Laurence C. Hull

    2010-10-01

    Reactive tracers have long been considered a possible means of measuring thermal drawdown in a geothermal system, before significant cooling occurs at the extraction well. Here, we examine the sensitivity of the proposed method to evaluate reservoir cooling and demonstrate that while the sensitivity of the method as generally proposed is low, it may be practical under certain conditions.

  6. Advancing Reactive Tracer Methods for Measurement of Thermal Evolution in Geothermal Reservoirs: Final Report

    SciTech Connect (OSTI)

    Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; Laurence C. Hull; George D. Redden

    2011-07-01

    The injection of cold fluids into engineered geothermal system (EGS) and conventional geothermal reservoirs may be done to help extract heat from the subsurface or to maintain pressures within the reservoir (e.g., Rose et al., 2001). As these injected fluids move along fractures, they acquire heat from the rock matrix and remove it from the reservoir as they are extracted to the surface. A consequence of such injection is the migration of a cold-fluid front through the reservoir (Figure 1) that could eventually reach the production well and result in the lowering of the temperature of the produced fluids (thermal breakthrough). Efficient operation of an EGS as well as conventional geothermal systems involving cold-fluid injection requires accurate and timely information about thermal depletion of the reservoir in response to operation. In particular, accurate predictions of the time to thermal breakthrough and subsequent rate of thermal drawdown are necessary for reservoir management, design of fracture stimulation and well drilling programs, and forecasting of economic return. A potential method for estimating migration of a cold front between an injection well and a production well is through application of reactive tracer tests, using chemical whose rate of degradation is dependent on the reservoir temperature between the two wells (e.g., Robinson 1985). With repeated tests, the rate of migration of the thermal front can be determined, and the time to thermal breakthrough calculated. While the basic theory behind the concept of thermal tracers has been understood for some time, effective application of the method has yet to be demonstrated. This report describes results of a study that used several methods to investigate application of reactive tracers to monitoring the thermal evolution of a geothermal reservoir. These methods included (1) mathematical investigation of the sensitivity of known and hypothetical reactive tracers, (2) laboratory testing of novel

  7. Validation of Geothermal Tracer Methods in Highly Constrained...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This project will test smartdiffusive tracers for measuring heat exchange. ... Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based ...

  8. Biological tracer method

    DOE Patents [OSTI]

    Strong-Gunderson, Janet M. (Ten Mile, TN); Palumbo, Anthony V. (Oak Ridge, TN)

    1998-01-01

    The present invention is a biological tracer method for characterizing the movement of a material through a medium, comprising the steps of: introducing a biological tracer comprising a microorganism having ice nucleating activity into a medium; collecting at least one sample of the medium from a point removed from the introduction point; and analyzing the sample for the presence of the biological tracer. The present invention is also a method for using a biological tracer as a label for material identification by introducing a biological tracer having ice nucleating activity into a material, collecting a sample of a portion of the labelled material and analyzing the sample for the presence of the biological tracer.

  9. Biological tracer method

    DOE Patents [OSTI]

    Strong-Gunderson, J.M.; Palumbo, A.V.

    1998-09-15

    The present invention is a biological tracer method for characterizing the movement of a material through a medium, comprising the steps of: introducing a biological tracer comprising a microorganism having ice nucleating activity into a medium; collecting at least one sample of the medium from a point removed from the introduction point; and analyzing the sample for the presence of the biological tracer. The present invention is also a method for using a biological tracer as a label for material identification by introducing a biological tracer having ice nucleating activity into a material, collecting a sample of a portion of the labelled material and analyzing the sample for the presence of the biological tracer. 2 figs.

  10. Validation of Geothermal Tracer Methods in Highly Constrained Field

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experiments | Department of Energy Geothermal Tracer Methods in Highly Constrained Field Experiments Validation of Geothermal Tracer Methods in Highly Constrained Field Experiments DOE Geothermal Peer Review 2010 - Project Summary. This project will test smartdiffusive tracers for measuring heat exchange. tracers_becker_verification_methods.pdf (1.81 MB) More Documents & Publications track 3: enhanced geothermal systems (EGS) | geothermal 2015 peer review Advancing reactive tracer

  11. Tracer Methods for Characterizing Fracture Creation in Enhanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems; 2010 ... Systems by Wellbore and Reservoir Analysis; 2010 Geothermal Technology Program Peer ...

  12. Tracer Methods for Characterizing Fracture Stimulation in Enhanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stimulation in Enhanced Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing Fracture Stimulation in Enhanced...

  13. Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Tracers to Characterize Fractures in Engineered Geothermal Systems Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs

  14. Method of dispersing particulate aerosol tracer

    DOE Patents [OSTI]

    O'Holleran, Thomas P.

    1988-01-01

    A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

  15. Tracer Test Interpretation Methods for Reservior Properties

    SciTech Connect (OSTI)

    Shook, George Michael

    2001-08-01

    The purpose of this project is to develop tools that can be used to interpret tracer tests and obtain estimates of reservoir and operational parameters. These tools (mostly in the form of spreadsheet applications) can be used to optimize geothermal resource management.

  16. Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems; 2010 Geothermal Technology Program Peer Review Report | Department of Energy Creation in Enhanced Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report DOE 2010 Geothermal Technologies Program Peer Review reservoir_033_rose.pdf (207.82 KB) More Documents & Publications Tracer Methods for Characterizing Fracture Stimulation

  17. Tracer Methods for Characterizing Fracture Stimulation in Enhanced

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report | Department of Energy in Enhanced Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing Fracture Stimulation in Enhanced Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report DOE 2010 Geothermal Technologies Program Peer Review reservoir_034_pruess.pdf (203.28 KB) More Documents & Publications Tracer Methods for

  18. Methods and systems using encapsulated tracers and chemicals for reservoir interrogation and manipulation

    DOE Patents [OSTI]

    Roberts, Jeffery; Aines, Roger D; Duoss, Eric B; Spadaccini, Christopher M

    2014-11-04

    An apparatus, method, and system of reservoir interrogation. A tracer is encapsulating in a receptacle. The receptacle containing the tracer is injected into the reservoir. The tracer is analyzed for reservoir interrogation.

  19. Semianalytical Solutions of Radioactive or Reactive Tracer Transport in Layered Fractured Media

    SciTech Connect (OSTI)

    G.J. Moridis; G. S. Bodvarsson

    2001-10-01

    In this paper, semianalytical solutions are developed for the problem of transport of radioactive or reactive tracers (solutes or colloids) through a layered system of heterogeneous fractured media with misaligned fractures. The tracer transport equations in the matrix account for (a) diffusion, (b) surface diffusion (for solutes only), (c) mass transfer between the mobile and immobile water fractions, (d) linear kinetic or equilibrium physical, chemical, or combined solute sorption or colloid filtration, and (e) radioactive decay or first order chemical reactions. Any number of radioactive decay daughter products (or products of a linear, first-order reaction chain) can be tracked. The tracer-transport equations in the fractures account for the same processes, in addition to advection and hydrodynamic dispersion. Additionally, the colloid transport equations account for straining and velocity adjustments related to the colloidal size. The solutions, which are analytical in the Laplace space, are numerically inverted to provide the solution in time and can accommodate any number of fractured and/or porous layers. The solutions are verified using analytical solutions for limiting cases of solute and colloid transport through fractured and porous media. The effect of important parameters on the transport of {sup 3}H, {sup 237}Np and {sup 239}Pu (and its daughters) is investigated in several test problems involving layered geological systems of varying complexity. {sup 239}Pu colloid transport problems in multilayered systems indicate significant colloid accumulations at straining interfaces but much faster transport of the colloid than the corresponding strongly sorbing solute species.

  20. Radiocarbon as a Reactive Tracer for Tracking Permanent CO2 Storage in Basaltic Rocks

    SciTech Connect (OSTI)

    Matter, Juerg; Stute, Martin; Schlosser, Peter; Broecker, Wallace

    2015-09-30

    In view of concerns about the long-term integrity and containment of CO2 storage in geologic reservoirs, many efforts have been made to improve the monitoring, verification and accounting methods for geologically stored CO2. Our project aimed to demonstrate that carbon-14 (14C) could be used as a reactive tracer to monitor geochemical reactions and evaluate the extent of mineral trapping of CO2 in basaltic rocks. The capacity of a storage reservoir for mineral trapping of CO2 is largely a function of host rock composition. Mineral carbonation involves combining CO2 with divalent cations including Ca2+, Mg2+ and Fe2+. The most abundant geological sources for these cations are basaltic rocks. Based on initial storage capacity estimates, we know that basalts have the necessary capacity to store million to billion tons of CO2 via in situ mineral carbonation. However, little is known about CO2-fluid-rock reactions occurring in a basaltic storage reservoir during and post-CO2 injection. None of the common monitoring and verification techniques have been able to provide a surveying tool for mineral trapping. The most direct method for quantitative monitoring and accounting involves the tagging of the injected CO2 with 14C because 14C is not present in deep geologic reservoirs prior to injection. Accordingly, we conducted two CO2 injection tests at the CarbFix pilot injection site in Iceland to study the feasibility of 14C as a reactive tracer for monitoring CO2-fluid-rock reactions and CO2 mineralization. Our newly developed monitoring techniques, using 14C as a reactive tracer, have been successfully demonstrated. For the first time, permanent and safe disposal of CO2 as environmentally benign carbonate minerals in basaltic rocks could be shown. Over 95% of the injected CO2 at the Carb

  1. QUANTIFICATION OF FUGITIVE REACTIVE ALKENE EMISSIONS FROM PETROCHEMICAL PLANTS WITH PERFLUOROCARBON TRACERS.

    SciTech Connect (OSTI)

    SENUM,G.I.; DIETZ,R.N.

    2004-06-30

    Recent studies demonstrate the impact of fugitive emissions of reactive alkenes on the atmospheric chemistry of the Houston Texas metropolitan area (1). Petrochemical plants located in and around the Houston area emit atmospheric alkenes, such as ethene, propene and 1,3-butadiene. The magnitude of emissions is a major uncertainty in assessing their effects. Even though the petrochemical industry reports that fugitive emissions of alkenes have been reduced to less than 0.1% of daily production, recent measurement data, obtained during the TexAQS 2000 experiment indicates that emissions are perhaps a factor of ten larger than estimated values. Industry figures for fugitive emissions are based on adding up estimated emission factors for every component in the plant to give a total estimated emission from the entire facility. The dramatic difference between estimated and measured rates indicates either that calculating emission fluxes by summing estimates for individual components is seriously flawed, possibly due to individual components leaking well beyond their estimated tolerances, that not all sources of emissions for a facility are being considered in emissions estimates, or that there are known sources of emissions that are not being reported. This experiment was designed to confirm estimates of reactive alkene emissions derived from analysis of the TexAQS 2000 data by releasing perfluorocarbon tracers (PFTs) at a known flux from a petrochemical plant and sampling both the perfluorocarbon tracer and reactive alkenes downwind using the Piper-Aztec research aircraft operated by Baylor University. PFTs have been extensively used to determine leaks in pipelines, air infiltration in buildings, and to characterize the transport and dispersion of air parcels in the atmosphere. Over 20 years of development by the Tracer Technology Center (TTC) has produced a range of analysis instruments, field samplers and PFT release equipment that have been successfully deployed in a

  2. Waste tank ventilation rates measured with a tracer gas method

    SciTech Connect (OSTI)

    Huckaby, J.L.; Evans, J.C.; Sklarew, D.S.; Mitroshkov, A.V.

    1998-08-01

    Passive ventilation with the atmosphere is used to prevent accumulation of waste gases and vapors in the headspaces of 132 of the 177 high-level radioactive waste Tanks at the Hanford Site in Southeastern Washington State. Measurements of the passive ventilation rates are needed for the resolution of two key safety issues associated with the rates of flammable gas production and accumulation and the rates at which organic salt-nitrate salt mixtures dry out. Direct measurement of passive ventilation rates using mass flow meters is not feasible because ventilation occurs va multiple pathways to the atmosphere (i.e., via the filtered breather riser and unsealed tank risers and pits), as well as via underground connections to other tanks, junction boxes, and inactive ventilation systems. The tracer gas method discussed in this report provides a direct measurement of the rate at which gases are removed by ventilation and an indirect measurement of the ventilation rate. The tracer gas behaves as a surrogate of the waste-generated gases, but it is only diminished via ventilation, whereas the waste gases are continuously released by the waste and may be subject to depletion mechanisms other than ventilation. The fiscal year 1998 tracer studies provide new evidence that significant exchange of air occurs between tanks via the underground cascade pipes. Most of the single-shell waste tanks are connected via 7.6-cm diameter cascade pipes to one or two adjacent tanks. Tracer gas studies of the Tank U-102/U-103 system indicated that the ventilation occurring via the cascade line could be a significant fraction of the total ventilation. In this two-tank cascade, air evidently flowed from Tank U-103 to Tank U-102 for a time and then was observed to flow from Tank U-102 to Tank U-103.

  3. Single well tracer method to evaluate enhanced recovery

    DOE Patents [OSTI]

    Sheely, Jr., Clyde Q.; Baldwin, Jr., David E.

    1978-01-01

    Data useful to evaluate the effectiveness of or to design an enhanced recovery process (the recovery process involving mobilizing and moving hydrocarbons through a hydrocarbon-bearing subterranean formation from an injection well to a production well by injecting a mobilizing fluid into the injection well) are obtained by a process which comprises sequentially: determining hydrocarbon saturation in the formation in a volume in the formation near a well bore penetrating the formation, injecting sufficient of the mobilizing fluid to mobilize and move hydrocarbons from a volume in the formation near the well bore penetrating the formation, and determining by the single well tracer method a hydrocarbon saturation profile in a volume from which hydrocarbons are moved. The single well tracer method employed is disclosed by U.S. Pat. No. 3,623,842. The process is useful to evaluate surfactant floods, water floods, polymer floods, CO.sub.2 floods, caustic floods, micellar floods, and the like in the reservoir in much less time at greatly reduced costs, compared to conventional multi-well pilot test.

  4. Tracer Methods for Characterizing Fracture Stimulation in Engineered...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    sorbing tracers to determine the fracture-matrix interface area available for heat transfer; and; explore the feasibility of obtaining fracture-matrix interface area from ...

  5. Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Anderson, Raymond P.

    2008-08-05

    A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

  6. THE NEW YORK CITY URBAN DISPERSION PROGRAM MARCH 2005 FIELD STUDY: TRACER METHODS AND RESULTS.

    SciTech Connect (OSTI)

    WATSON, T.B.; HEISER, J.; KALB, P.; DIETZ, R.N.; WILKE, R.; WIESER, R.; VIGNATO, G.

    2005-10-01

    The Urban Dispersion Program March 2005 Field Study tracer releases, sampling, and analytical methods are described in detail. There were two days where tracer releases and sampling were conducted. A total of 16.0 g of six tracers were released during the first test day or Intensive Observation Period (IOP) 1 and 15.7 g during IOP 2. Three types of sampling instruments were used in this study. Sequential air samplers, or SAS, collected six-minute samples, while Brookhaven atmospheric tracer samplers (BATS) and personal air samplers (PAS) collected thirty-minute samples. There were a total of 1300 samples resulting from the two IOPs. Confidence limits in the sampling and analysis method were 20% as determined from 100 duplicate samples. The sample recovery rate was 84%. The integrally averaged 6-minute samples were compared to the 30-minute samples. The agreement was found to be good in most cases. The validity of using a background tracer to calculate sample volumes was examined and also found to have a confidence level of 20%. Methods for improving sampling and analysis are discussed. The data described in this report are available as Excel files. An additional Excel file of quality assured tracer data for use in model validation efforts is also available. The file consists of extensively quality assured BATS tracer data with background concentrations subtracted.

  7. Pre-fire warning system and method using a perfluorocarbon tracer

    DOE Patents [OSTI]

    Dietz, Russell N.; Senum, Gunnar I.

    1994-01-01

    A composition and method for detecting thermal overheating of an apparatus or system and for quickly and accurately locating the portions of the apparatus or system that experience a predetermined degree of such overheating. A composition made according to the invention includes perfluorocarbon tracers (PFTs) mixed with certain non-reactive carrier compounds that are effective to trap or block the PFTs within the composition at normal room temperature or at normal operating temperature of the coated apparatus or system. When a predetermined degree of overheating occurs in any of the coated components of the apparatus or system, PFTs are emitted from the compositions at a rate corresponding to the degree of overheating of the component. An associated PFT detector (or detectors) is provided and monitored to quickly identify the type of PFTs emitted so that the PFTs can be correlated with the respective PFT in the coating compositions applied on respective components in the system, thereby to quickly and accurately localize the source of the overheating of such components.

  8. Pre-fire warning system and method using a perfluorocarbon tracer

    DOE Patents [OSTI]

    Dietz, R.N.; Senum, G.I.

    1994-11-08

    A composition and method are disclosed for detecting thermal overheating of an apparatus or system and for quickly and accurately locating the portions of the apparatus or system that experience a predetermined degree of such overheating. A composition made according to the invention includes perfluorocarbon tracers (PFTs) mixed with certain non-reactive carrier compounds that are effective to trap or block the PFTs within the composition at normal room temperature or at normal operating temperature of the coated apparatus or system. When a predetermined degree of overheating occurs in any of the coated components of the apparatus or system, PFTs are emitted from the compositions at a rate corresponding to the degree of overheating of the component. An associated PFT detector (or detectors) is provided and monitored to quickly identify the type of PFTs emitted so that the PFTs can be correlated with the respective PFT in the coating compositions applied on respective components in the system, thereby to quickly and accurately localize the source of the overheating of such components. 4 figs.

  9. Single well surfactant test to evaluate surfactant floods using multi tracer method

    DOE Patents [OSTI]

    Sheely, Clyde Q.

    1979-01-01

    Data useful for evaluating the effectiveness of or designing an enhanced recovery process said process involving mobilizing and moving hydrocarbons through a hydrocarbon bearing subterranean formation from an injection well to a production well by injecting a mobilizing fluid into the injection well, comprising (a) determining hydrocarbon saturation in a volume in the formation near a well bore penetrating formation, (b) injecting sufficient mobilizing fluid to mobilize and move hydrocarbons from a volume in the formation near the well bore, and (c) determining the hydrocarbon saturation in a volume including at least a part of the volume of (b) by an improved single well surfactant method comprising injecting 2 or more slugs of water containing the primary tracer separated by water slugs containing no primary tracer. Alternatively, the plurality of ester tracers can be injected in a single slug said tracers penetrating varying distances into the formation wherein the esters have different partition coefficients and essentially equal reaction times. The single well tracer method employed is disclosed in U.S. Pat. No. 3,623,842. This method designated the single well surfactant test (SWST) is useful for evaluating the effect of surfactant floods, polymer floods, carbon dioxide floods, micellar floods, caustic floods and the like in subterranean formations in much less time and at much reduced cost compared to conventional multiwell pilot tests.

  10. Method For Reactivating Solid Catalysts Used For Alklation Reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Coates, Kyle; Zalewski, David J.; Fox, Robert V.

    2005-05-03

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  11. Method for reactivating solid catalysts used in alkylation reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Coates, Kyle; Zalewski, David J.; Fox, Robert V.

    2003-06-17

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  12. Perfluorocarbon tracer method for air-infiltration measurements

    DOE Patents [OSTI]

    Dietz, R.N.

    1982-09-23

    A method of measuring air infiltration rates suitable for use in rooms of homes and buildings comprises the steps of emitting perfluorocarbons in the room to be measured, sampling the air containing the emitted perfluorocarbons over a period of time, and analyzing the samples at a laboratory or other facility.

  13. Reactive ion etched substrates and methods of making and using

    DOE Patents [OSTI]

    Rucker, Victor C.; Shediac, Rene; Simmons, Blake A.; Havenstrite, Karen L.

    2007-08-07

    Disclosed herein are substrates comprising reactive ion etched surfaces and specific binding agents immobilized thereon. The substrates may be used in methods and devices for assaying or isolating analytes in a sample. Also disclosed are methods of making the reactive ion etched surfaces.

  14. Recover Act. Verification of Geothermal Tracer Methods in Highly Constrained Field Experiments

    SciTech Connect (OSTI)

    Becker, Matthew W.

    2014-05-16

    The prediction of the geothermal system efficiency is strong linked to the character of the flow system that connects injector and producer wells. If water flow develops channels or “short circuiting” between injection and extraction wells thermal sweep is poor and much of the reservoir is left untapped. The purpose of this project was to understand how channelized flow develops in fracture geothermal reservoirs and how it can be measured in the field. We explored two methods of assessing channelization: hydraulic connectivity tests and tracer tests. These methods were tested at a field site using two verification methods: ground penetrating radar (GPR) images of saline tracer and heat transfer measurements using distributed temperature sensing (DTS). The field site for these studies was the Altona Flat Fractured Rock Research Site located in northeastern New York State. Altona Flat Rock is an experimental site considered a geologic analog for some geothermal reservoirs given its low matrix porosity. Because soil overburden is thin, it provided unique access to saturated bedrock fractures and the ability image using GPR which does not effectively penetrate most soils. Five boreholes were drilled in a “five spot” pattern covering 100 m2 and hydraulically isolated in a single bedding plane fracture. This simple system allowed a complete characterization of the fracture. Nine small diameter boreholes were drilled from the surface to just above the fracture to allow the measurement of heat transfer between the fracture and the rock matrix. The focus of the hydraulic investigation was periodic hydraulic testing. In such tests, rather than pumping or injection in a well at a constant rate, flow is varied to produce an oscillating pressure signal. This pressure signal is sensed in other wells and the attenuation and phase lag between the source and receptor is an indication of hydraulic connection. We found that these tests were much more effective than constant

  15. Tracers and Tracer Testing: Design, Implementation, Tracer Selection...

    Office of Scientific and Technical Information (OSTI)

    presents methods for analysis. The report is an overview of tracer technology; the Suggested Reading section offers references to the specifics of test design and interpretation. ...

  16. Method for preparing hydride configurations and reactive metal surfaces

    DOE Patents [OSTI]

    Silver, G.L.

    1984-05-18

    A method for preparing reactive metal surfaces, particularly uranium surfaces is disclosed, whereby the metal is immediately reactive to hydrogen gas at room temperature and low pressure. The metal surfaces are first pretreated by exposure to an acid which forms an adherent hydride-bearing composition on the metal surface. Subsequent heating of the pretreated metal at a temperature sufficient to decompose the hydride coating in vacuum or inert gas renders the metal surface instantaneously reactive to hydrogen gas at room temperature and low pressure.

  17. Analytical methods for determining the reactivity of pyrochemical salts

    SciTech Connect (OSTI)

    Phillips, A.G.; Stakebake, J.L.

    1994-05-01

    Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

  18. Method and apparatus for measuring reactivity of fissile material

    DOE Patents [OSTI]

    Lee, D.M.; Lindquist, L.O.

    1982-09-07

    Given are a method and apparatus for measuring nondestructively and noninvasively (i.e., using no internal probing) the burnup, reactivity, or fissile content of any material which emits neutrons and which has fissionable components. The assay is accomplished by altering the return flux of neutrons into the fuel assembly by means of changing the reflecting material. The existing passive neutron emissions in the material being assayed are used as the source of interrogating neutrons. Two measurements of either emitted neutron or emitted gamma-ray count rates are made and are then correlated to either reactivity, burnup, or fissionable content of the material being assayed, thus providing a measurement of either reactivity, burnup, or fissionable content of the material being assayed. Spent fuel which has been freshly discharged from a reactor can be assayed using this method and apparatus. Precisions of 1000 MWd/tU appear to be feasible.

  19. Environmentally stable reactive alloy powders and method of making same

    DOE Patents [OSTI]

    Anderson, Iver E.; Lograsso, Barbara K.; Terpstra, Robert L.

    1998-09-22

    Apparatus and method for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment.

  20. Environmentally stable reactive alloy powders and method of making same

    DOE Patents [OSTI]

    Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

    1998-09-22

    Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

  1. Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS)

    Broader source: Energy.gov [DOE]

    Project objectives: identify tracers with sorption properties favorable for EGS applications; apply reversibly sorbing tracers to determine the fracture-matrix interface area available for heat transfer; and; explore the feasibility of obtaining fracture-matrix interface area from non-isothermal; single-well injection-withdrawal (SWIW) tests.

  2. Method and apparatus for measuring reactivity of fissile material

    DOE Patents [OSTI]

    Lee, David M.; Lindquist, Lloyd O.

    1985-01-01

    Given are a method and apparatus for measuring nondestructively and non-invasively (i.e., using no internal probing) the burnup, reactivity, or fissile content of any material which emits neutrons and which has fissionable components. No external neutron-emitting interrogation source or fissile material is used and no scanning is required, although if a profile is desired scanning can be used. As in active assays, here both reactivity and content of fissionable material can be measured. The assay is accomplished by altering the return flux of neutrons into the fuel assembly. The return flux is altered by changing the reflecting material. The existing passive neutron emissions in the material being assayed are used as the source of interrogating neutrons. Two measurements of either emitted neutron or emitted gamma-ray count rates are made and are then correlated to either reactivity, burnup, or fissionable content of the material being assayed, thus providing a measurement of either reactivity, burnup, or fissionable content of the material being assayed. Spent fuel which has been freshly discharged from a reactor can be assayed using this method and apparatus. Precisions of 1000 MWd/tU appear to be feasible.

  3. Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity

    DOE Patents [OSTI]

    Whealton, John H.; Hanson, Gregory R.; Storey, John M.; Raridon, Richard J.; Armfield, Jeffrey S.; Bigelow, Timothy S.; Graves, Ronald L.

    2002-01-01

    A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime, high frequency, high power bursts of low-duty factor microwaves sufficient to generate a plasma discharge and passing a gas to be treated through the discharge so as to cause dissociative reduction of the exhaust gases and enhanced catalyst reactivity through application of the pulsed microwave fields directly to the catalyst material sufficient to cause a polarizability catastrophe and enhanced heating of the metal crystallite particles of the catalyst, and in the presence or absence of the plasma. The invention also includes a reactor for aftertreatment of exhaust gases.

  4. Method for preparing hydride configurations and reactive metal surfaces

    SciTech Connect (OSTI)

    Silver, G L

    1986-11-28

    Disclosed is a method for preparing highly hydrogen-reactive surfaces on metals which normally require substantial heating, high pressures, or an extended induction period. The method involves pretreatment of surfaces with either a nonoxidizing acid or hydrogen gas to form a hydrogen-bearing coating. The coated metal is heated in the absence of moisture and oxygen for a period sufficient to decompose the coating, and then cooled to room temperature. Surfaces so treated will react almost instantaneously with hydrogen gas at room temperature and low pressure. The method is particularly applicable to uranium, thorium, and lanthanide metals. 3 figs.

  5. Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same

    DOE Patents [OSTI]

    Fritz, Gregory M.; Weihs, Timothy P.; Grzyb, Justin A.

    2016-07-05

    An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

  6. Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same

    DOE Patents [OSTI]

    Fritz, Gregory M; Knepper, Robert Allen; Weihs, Timothy P; Gash, Alexander E; Sze, John S

    2013-04-30

    An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

  7. Method for preparing hydride configurations and reactive metal surfaces

    DOE Patents [OSTI]

    Silver, Gary L.

    1988-08-16

    A method for preparing highly hydrogen-reactive surfaces on metals which normally require substantial heating, high pressures, or an extended induction period, which involves pretreatment of said surfaces with either a non-oxidizing acid or hydrogen gas to form a hydrogen-bearing coating on said surfaces, and subsequently heating said coated metal in the absence of moisture and oxygen for a period sufficient to decompose said coating and cooling said metal to room temperature. Surfaces so treated will react almost instantaneously with hydrogen gas at room temperature and low pressure. The method is particularly applicable to uranium, thorium, and lanthanide metals.

  8. Advanced hydraulic fracturing methods to create in situ reactive barriers

    SciTech Connect (OSTI)

    Murdoch, L. |; Siegrist, B.; Vesper, S.

    1997-12-31

    Many contaminated areas consist of a source area and a plume. In the source area, the contaminant moves vertically downward from a release point through the vadose zone to an underlying saturated region. Where contaminants are organic liquids, NAPL may accumulate on the water table, or it may continue to migrate downward through the saturated region. Early developments of permeable barrier technology have focused on intercepting horizontally moving plumes with vertical structures, such as trenches, filled with reactive material capable of immobilizing or degrading dissolved contaminants. This focus resulted in part from a need to economically treat the potentially large volumes of contaminated water in a plume, and in part from the availability of construction technology to create the vertical structures that could house reactive compounds. Contaminant source areas, however, have thus far remained largely excluded from the application of permeable barrier technology. One reason for this is the lack of conventional construction methods for creating suitable horizontal structures that would place reactive materials in the path of downward-moving contaminants. Methods of hydraulic fracturing have been widely used to create flat-lying to gently dipping layers of granular material in unconsolidated sediments. Most applications thus far have involved filling fractures with coarse-grained sand to create permeable layers that will increase the discharge of wells recovering contaminated water or vapor. However, it is possible to fill fractures with other compounds that alter the chemical composition of the subsurface. One early application involved development and field testing micro-encapsulated sodium percarbonate, a solid compound that releases oxygen and can create aerobic conditions suitable for biodegradation in the subsurface for several months.

  9. Method of measuring reactive acoustic power density in a fluid

    DOE Patents [OSTI]

    Wheatley, J.C.; Swift, G.W.; Migliori, A.

    1985-09-03

    A method for determining reactive acoustic power density level and its direction in a fluid using a single sensor is disclosed. In the preferred embodiment, an apparatus for conducting the method, which is termed a thermoacoustic couple, consists of a stack of thin, spaced apart polymeric plates, selected ones of which include multiple bimetallic thermocouple junctions positioned along opposite end edges thereof. The thermocouple junctions are connected in series in the nature of a thermopile, and are arranged so as to be responsive to small temperature differences between the opposite edges of the plates. The magnitude of the temperature difference, as represented by the magnitude of the electrical potential difference generated by the thermopile, is found to be directly related to the level of acoustic power density in the gas. 5 figs.

  10. Method of measuring reactive acoustic power density in a fluid

    DOE Patents [OSTI]

    Wheatley, John C.; Swift, Gregory W.; Migliori, Albert

    1985-01-01

    A method for determining reactive acoustic power density level and its direction in a fluid using a single sensor is disclosed. In the preferred embodiment, an apparatus for conducting the method, which is termed a thermoacoustic couple, consists of a stack of thin, spaced apart polymeric plates, selected ones of which include multiple bimetallic thermocouple junctions positioned along opposite end edges thereof. The thermocouple junctions are connected in series in the nature of a thermopile, and are arranged so as to be responsive to small temperature differences between the opposite edges of the plates. The magnitude of the temperature difference, as represented by the magnitude of the electrical potential difference generated by the thermopile, is found to be directly related to the level of acoustic power density in the gas.

  11. METHOD OF ALLOYING REACTIVE METALS WITH ALUMINUM OR BERYLLIUM

    DOE Patents [OSTI]

    Runnalls, O.J.C.

    1957-10-15

    A halide of one or more of the reactive metals, neptunium, cerium and americium, is mixed with aluminum or beryllium. The mass is heated at 700 to 1200 deg C, while maintaining a substantial vacuum of above 10/sup -3/ mm of mercury or better, until the halide of the reactive metal is reduced and the metal itself alloys with the reducing metal. The reaction proceeds efficiently due to the volatilization of the halides of the reducing metal, aluminum or beryllium.

  12. In Situ Tracer method for establishing the presence and predicting the activity of heavy metal-reducing microbes in the subsurface. Final Report

    SciTech Connect (OSTI)

    Hatfield, K.

    2003-07-01

    Tracer method to establish presence and distribution of chromium reducing microbes. The primary objective of this research was to establish an in situ tracer method for detecting the presence. distribution. and activity of subsurface heavy metal-reducing microorganisms. Research focused on microbial systems responsible for the reduction of chromium and a suite of biotracers coupled to the reduction process. The tracer method developed may be used to characterize sites contaminated with chromium or expedite bioremediation: and although research focused on chromium. the method can be easily extended to other metals, organics, and radionuclides. This brief final report contains three major sections. The first identifies specific products of the research effort such as students supported and publications. The second section briefly presents major research findings, while the last section summarizes the overall research effort.

  13. Tracers and Tracer Testing: Design, Implementation, Tracer Selection...

    Office of Scientific and Technical Information (OSTI)

    Conducting a successful tracer test requires adhering to a set of steps. The steps include identifying appropriate and achievable test goals, identifying tracers with the ...

  14. Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity

    DOE Patents [OSTI]

    Whealton, John H.; Hanson, Gregory R.; Storey, John M.; Raridon, Richard J.; Armfield, Jeffrey S.; Bigelow, Timothy S.; Graves, Ronald L.

    2001-01-01

    A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime (about 40 ps), high frequency (about 5G hz), high power bursts of low-duty factor microwaves sufficient to generate a dielectric barrier discharge and passing a gas to treated through the discharge so as to cause dissociative reduction of the exhaust gases. The invention also includes a reactor for generating the non-thermal plasma.

  15. Tracers for Characterizing Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Karen Wright; George Redden; Carl D. Palmer; Harry Rollins; Mark Stone; Mason Harrup; Laurence C. Hull

    2010-02-01

    Information about the times of thermal breakthrough and subsequent rates of thermal drawdown in enhanced geothermal systems (EGS) is necessary for reservoir management, designing fracture stimulation and well drilling programs, and forecasting economic return. Thermal breakthrough in heterogeneous porous media can be estimated using conservative tracers and assumptions about heat transfer rates; however, tracers that undergo temperature-dependent changes can provide more detailed information about the thermal profile along the flow path through the reservoir. To be effectively applied, the thermal reaction rates of such temperature sensitive traces must be well characterized for the range of conditions that exist in geothermal systems. Reactive tracers proposed in the literature include benzoic and carboxylic acids (Adams) and organic esters and amides (Robinson et al.); however, the practical temperature range over which these tracers can be applied (100-275C) is somewhat limited. Further, for organic esters and amides, little is known about their sorption to the reservoir matrix and how such reactions impact data interpretation. Another approach involves tracers where the reference condition is internal to the tracer itself. Two examples are: 1) racemization of polymeric amino acids, and 2) mineral thermoluminescence. In these cases internal ratios of states are measured rather than extents of degradation and mass loss. Racemization of poly-L-lactic acid (for example) is temperature sensitive and therefore can be used as a temperature-recording tracer depending on the rates of racemization and stability of the amino acids. Heat-induced quenching of thermoluminescence of pre-irradiated LiF can also be used. To protect the tracers from alterations (extraneous reactions, dissolution) in geothermal environments we are encapsulating the tracers in core-shell colloidal structures that will subsequently be tested for their ability to be transported and to protect the

  16. Methods and apparatuses for reagent delivery, reactive barrier formation, and pest control

    DOE Patents [OSTI]

    Gilmore, Tyler [Pasco, WA; Kaplan, Daniel I [Aiken, SC; Last, George [Richland, WA

    2002-07-09

    A reagent delivery method includes positioning reagent delivery tubes in contact with soil. The tubes can include a wall that is permeable to a soil-modifying reagent. The method further includes supplying the reagent in the tubes, diffusing the reagent through the permeable wall and into the soil, and chemically modifying a selected component of the soil using the reagent. The tubes can be in subsurface contact with soil, including groundwater, and can be placed with directional drilling equipment independent of groundwater well casings. The soil-modifying reagent includes a variety of gases, liquids, colloids, and adsorbents that may be reactive or non-reactive with soil components. The method may be used inter alia to form reactive barriers, control pests, and enhance soil nutrients for microbes and plants.

  17. Tracer airflow measurement system (TRAMS)

    DOE Patents [OSTI]

    Wang, Duo

    2007-04-24

    A method and apparatus for measuring fluid flow in a duct is disclosed. The invention uses a novel high velocity tracer injector system, an optional insertable folding mixing fan for homogenizing the tracer within the duct bulk fluid flow, and a perforated hose sampling system. A preferred embodiment uses CO.sub.2 as a tracer gas for measuring air flow in commercial and/or residential ducts. In extant commercial buildings, ducts not readily accessible by hanging ceilings may be drilled with readily plugged small diameter holes to allow for injection, optional mixing where desired using a novel insertable foldable mixing fan, and sampling hose.

  18. Application of a data assimilation method via an ensemble Kalman filter to reactive urea hydrolysis transport modeling

    SciTech Connect (OSTI)

    Juxiu Tong; Bill X. Hu; Hai Huang; Luanjin Guo; Jinzhong Yang

    2014-03-01

    With growing importance of water resources in the world, remediations of anthropogenic contaminations due to reactive solute transport become even more important. A good understanding of reactive rate parameters such as kinetic parameters is the key to accurately predicting reactive solute transport processes and designing corresponding remediation schemes. For modeling reactive solute transport, it is very difficult to estimate chemical reaction rate parameters due to complex processes of chemical reactions and limited available data. To find a method to get the reactive rate parameters for the reactive urea hydrolysis transport modeling and obtain more accurate prediction for the chemical concentrations, we developed a data assimilation method based on an ensemble Kalman filter (EnKF) method to calibrate reactive rate parameters for modeling urea hydrolysis transport in a synthetic one-dimensional column at laboratory scale and to update modeling prediction. We applied a constrained EnKF method to pose constraints to the updated reactive rate parameters and the predicted solute concentrations based on their physical meanings after the data assimilation calibration. From the study results we concluded that we could efficiently improve the chemical reactive rate parameters with the data assimilation method via the EnKF, and at the same time we could improve solute concentration prediction. The more data we assimilated, the more accurate the reactive rate parameters and concentration prediction. The filter divergence problem was also solved in this study.

  19. Method of extruding and packaging a thin sample of reactive material, including forming the extrusion die

    DOE Patents [OSTI]

    Lewandowski, E.F.; Peterson, L.L.

    1981-11-30

    This invention teaches a method of cutting a narrow slot in an extrusion die with an electrical discharge machine by first drilling spaced holes at the ends of where the slot will be, whereby the oil can flow through the holes and slot to flush the material eroded away as the slot is being cut. The invention further teaches a method of extruding a very thin ribbon of solid highly reactive material such as lithium or sodium through the die in an inert atmosphere of nitrogen, argon, or the like as in a glovebox. The invention further teaches a method of stamping out sample discs from the ribbon and of packaging each disc by sandwiching it between two aluminum sheets and cold welding the sheets together along an annular seam beyond the outer periphery of the disc. This provides a sample of high purity reactive material that can have a long shelf life.

  20. Method of extruding and packaging a thin sample of reactive material including forming the extrusion die

    DOE Patents [OSTI]

    Lewandowski, Edward F.; Peterson, Leroy L.

    1985-01-01

    This invention teaches a method of cutting a narrow slot in an extrusion die with an electrical discharge machine by first drilling spaced holes at the ends of where the slot will be, whereby the oil can flow through the holes and slot to flush the material eroded away as the slot is being cut. The invention further teaches a method of extruding a very thin ribbon of solid highly reactive material such as lithium or sodium through the die in an inert atmosphere of nitrogen, argon or the like as in a glovebox. The invention further teaches a method of stamping out sample discs from the ribbon and of packaging each disc by sandwiching it between two aluminum sheets and cold welding the sheets together along an annular seam beyond the outer periphery of the disc. This provides a sample of high purity reactive material that can have a long shelf life.

  1. Apparatus and method for atmospheric pressure reactive atom plasma processing for shaping of damage free surfaces

    DOE Patents [OSTI]

    Carr; Jeffrey W. (Livermore, CA)

    2009-03-31

    Fabrication apparatus and methods are disclosed for shaping and finishing difficult materials with no subsurface damage. The apparatus and methods use an atmospheric pressure mixed gas plasma discharge as a sub-aperture polisher of, for example, fused silica and single crystal silicon, silicon carbide and other materials. In one example, workpiece material is removed at the atomic level through reaction with fluorine atoms. In this example, these reactive species are produced by a noble gas plasma from trace constituent fluorocarbons or other fluorine containing gases added to the host argon matrix. The products of the reaction are gas phase compounds that flow from the surface of the workpiece, exposing fresh material to the etchant without condensation and redeposition on the newly created surface. The discharge provides a stable and predictable distribution of reactive species permitting the generation of a predetermined surface by translating the plasma across the workpiece along a calculated path.

  2. Reactive Air Brazing: Method of Joining Ceramic and Metal Parts in Solid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxide Fuel Cells - Energy Innovation Portal Reactive Air Brazing: Method of Joining Ceramic and Metal Parts in Solid Oxide Fuel Cells Pacific Northwest National Laboratory Contact PNNL About This Technology The use of air brazing in hermetically sealing metal and ceramic components in an oxygen separation device. The use of air brazing in hermetically sealing metal and ceramic components in an oxygen separation device. The use of air brazing in hermetically sealing solid oxide fuel cell

  3. Catalytic and reactive polypeptides and methods for their preparation and use

    DOE Patents [OSTI]

    Schultz, Peter

    1994-01-01

    Catalytic and reactive polypeptides include a binding site specific for a reactant or reactive intermediate involved in a chemical reaction of interest. The polypeptides further include at least one active functionality proximate the binding site, where the active functionality is capable of catalyzing or chemically participating in the chemical reaction in such a way that the reaction rate is enhanced. Methods for preparing the catalytic peptides include chemical synthesis, site-directed mutagenesis of antibody and enzyme genes, covalent attachment of the functionalities through particular amino acid side chains, and the like. This invention was made with Government support under Grant Contract No. AI-24695, awarded by the Department of health and Human Services, and under Grant Contract No. N 00014-87-K-0256, awarded by the Office of Naval Research. The Government has certain rights in this invention.

  4. INL Tracer Interpretation

    Energy Science and Technology Software Center (OSTI)

    2007-03-27

    This spreadsheet application is for tracer test analysis. The analyses are based on the first temporal moment of a tracer. The governing equations are briefly discussed, and the individual steps required of the user are outlined. A series of Excel macros written in Visual Basic calculate mean residence time, swept pore volume, and flow-storage geometry from a tracer history.

  5. Systems and methods for reactive distillation with recirculation of light components

    DOE Patents [OSTI]

    Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  6. Tracers and Tracer Interpretation | Open Energy Information

    Open Energy Info (EERE)

    Component Research and DevelopmentAnalysis Nathrop, CO 1,840,000 460,000 2,300,000 Quantum Dot Tracers for Use in Engineered Geothermal Systems Utah University of Utah Recovery...

  7. Catalytic and reactive polypeptides and methods for their preparation and use

    DOE Patents [OSTI]

    Schultz, Peter

    1993-01-01

    Catalytic and reactive polypeptides include a binding site specific for a reactant or reactive intermediate involved in a chemical reaction of interest. The polypeptides further include at least one active functionality proximate the bi.

  8. Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier

    DOE Patents [OSTI]

    Harrup, Mason K.; Stewart, Frederick F.

    2007-05-15

    Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

  9. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, P.C.

    1997-05-06

    A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

  10. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, Peter C.

    1997-01-01

    A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

  11. Method for atmospheric pressure reactive atom plasma processing for surface modification

    DOE Patents [OSTI]

    Carr, Jeffrey W.

    2009-09-22

    Reactive atom plasma processing can be used to shape, polish, planarize and clean the surfaces of difficult materials with minimal subsurface damage. The apparatus and methods use a plasma torch, such as a conventional ICP torch. The workpiece and plasma torch are moved with respect to each other, whether by translating and/or rotating the workpiece, the plasma, or both. The plasma discharge from the torch can be used to shape, planarize, polish, and/or clean the surface of the workpiece, as well as to thin the workpiece. The processing may cause minimal or no damage to the workpiece underneath the surface, and may involve removing material from the surface of the workpiece.

  12. Quantitative interpretation of tracer test data | Open Energy...

    Open Energy Info (EERE)

    of tracer test data Abstract Geothermal reinjection is an important part of sustainable management of geothermal resources. Reinjection started out as a method of waste-water...

  13. Tracer Testing At Raft River Geothermal Area (1984) | Open Energy...

    Open Energy Info (EERE)

    undertaken at Raft River geothermal area. References Kroneman, R. L.; Yorgason, K. R.; Moore, J. N. (1 December 1984) Preferred methods of analysis for chemical tracers in...

  14. Tracer Testing At East Mesa Geothermal Area (1984) | Open Energy...

    Open Energy Info (EERE)

    not indicated DOE-funding Unknown References Kroneman, R. L.; Yorgason, K. R.; Moore, J. N. (1 December 1984) Preferred methods of analysis for chemical tracers in...

  15. Mark 22 Reactivity

    SciTech Connect (OSTI)

    Buckner, M.R.

    2001-07-02

    Calculations for reactivity held in control rods have underpredicted the observed Mark 22 reactivity. Reactivity predictions by charge designers have accounted for this by including large biases which change with exposure and reactor region. The purpose of this study was to thoroughly investigate the methods and data used in the reactivity calculations. The goal was to identify errors and improvements and make necessary corrections.

  16. Category:Tracer Testing | Open Energy Information

    Open Energy Info (EERE)

    Pages in category "Tracer Testing" This category contains only the following page. T Tracer Testing Retrieved from "http:en.openei.orgwindex.php?titleCategory:TracerTe...

  17. First Tracer Test After Circulation in Desert Peak 27-15

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Rose, Peter

    Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

  18. First Tracer Test After Circulation in Desert Peak 27-15

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Rose, Peter

    2013-11-16

    Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

  19. An Integrated Approach to Characterizing Bypassed Oil in Heterogeneous and Fractured Reservoirs Using Partitioning Tracers

    SciTech Connect (OSTI)

    Akhil Datta-Gupta

    2006-12-31

    We explore the use of efficient streamline-based simulation approaches for modeling partitioning interwell tracer tests in hydrocarbon reservoirs. Specifically, we utilize the unique features of streamline models to develop an efficient approach for interpretation and history matching of field tracer response. A critical aspect here is the underdetermined and highly ill-posed nature of the associated inverse problems. We have investigated the relative merits of the traditional history matching ('amplitude inversion') and a novel travel time inversion in terms of robustness of the method and convergence behavior of the solution. We show that the traditional amplitude inversion is orders of magnitude more non-linear and the solution here is likely to get trapped in local minimum, leading to inadequate history match. The proposed travel time inversion is shown to be extremely efficient and robust for practical field applications. The streamline approach is generalized to model water injection in naturally fractured reservoirs through the use of a dual media approach. The fractures and matrix are treated as separate continua that are connected through a transfer function, as in conventional finite difference simulators for modeling fractured systems. A detailed comparison with a commercial finite difference simulator shows very good agreement. Furthermore, an examination of the scaling behavior of the computation time indicates that the streamline approach is likely to result in significant savings for large-scale field applications. We also propose a novel approach to history matching finite-difference models that combines the advantage of the streamline models with the versatility of finite-difference simulation. In our approach, we utilize the streamline-derived sensitivities to facilitate history matching during finite-difference simulation. The use of finite-difference model allows us to account for detailed process physics and compressibility effects. The

  20. Method and apparatus for continuously referenced analysis of reactive components in solution

    DOE Patents [OSTI]

    Bostick, W.D.; Denton, M.S.; Dinsmore, S.R.

    1979-07-31

    A continuously referenced apparatus for measuring the concentration of a reactive chemical species in solution comprises in combination conduit means for introducing a sample solution, means for introducing one or more reactants into a sample solution, and a stream separator disposed within the conduit means for separating the sample solution into a first sample stream and a second sample stream. A reactor is disposed in fluid communication with the first sample stream. A reaction takes place between the reactants introduced and the reactive chemical species of interest, causing the consumption or production of an indicator species in the first sample stream. Measurement means such as a photometric system are disposed in communication with the first and second sample streams, and the outputs of the measurement means are compared to provide a blanked measurement of the concentration of indicator species. The apparatus is particularly suitable for measurement of isoenzymes in body tissues or fluids.

  1. Reactive facies: An approach for parameterizing field-scale reactive...

    Office of Scientific and Technical Information (OSTI)

    transport models using geophysical methods Citation Details In-Document Search Title: Reactive facies: An approach for parameterizing field-scale reactive transport models ...

  2. Enhanced Oil Recovery: Aqueous Flow Tracer Measurement

    SciTech Connect (OSTI)

    Joseph Rovani; John Schabron

    2009-02-01

    A low detection limit analytical method was developed to measure a suite of benzoic acid and fluorinated benzoic acid compounds intended for use as tracers for enhanced oil recovery operations. Although the new high performance liquid chromatography separation successfully measured the tracers in an aqueous matrix at low part per billion levels, the low detection limits could not be achieved in oil field water due to interference problems with the hydrocarbon-saturated water using the system's UV detector. Commercial instrument vendors were contacted in an effort to determine if mass spectrometry could be used as an alternate detection technique. The results of their work demonstrate that low part per billion analysis of the tracer compounds in oil field water could be achieved using ultra performance liquid chromatography mass spectrometry.

  3. Methods for modeling impact-induced reactivity changes in small reactors.

    SciTech Connect (OSTI)

    Tallman, Tyler N.; Radel, Tracy E.; Smith, Jeffrey A.; Villa, Daniel L.; Smith, Brandon M.; Radel, Ross F.; Lipinski, Ronald J.; Wilson, Paul Philip Hood

    2010-10-01

    This paper describes techniques for determining impact deformation and the subsequent reactivity change for a space reactor impacting the ground following a potential launch accident or for large fuel bundles in a shipping container following an accident. This technique could be used to determine the margin of subcriticality for such potential accidents. Specifically, the approach couples a finite element continuum mechanics model (Pronto3D or Presto) with a neutronics code (MCNP). DAGMC, developed at the University of Wisconsin-Madison, is used to enable MCNP geometric queries to be performed using Pronto3D output. This paper summarizes what has been done historically for reactor launch analysis, describes the impact criticality analysis methodology, and presents preliminary results using representative reactor designs.

  4. System for reactivating catalysts

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Anderson, Raymond P.

    2010-03-02

    A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst is provided. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

  5. Tracer Testing | Open Energy Information

    Open Energy Info (EERE)

    In The Past 20 Years- Geochemistry In Geothermal Exploration Resource Evaluation And Reservoir Management Tracer Testing At Coso Geothermal Area (1993) Coso Geothermal Area...

  6. Development of Modeling Methods and Tools for Predicting Coupled Reactive Transport Processes in Porous Media at Multiple Scales

    SciTech Connect (OSTI)

    Clement, T Prabhakar; Barnett, Mark O; Zheng, Chunmiao; Jones, Norman L

    2010-05-05

    DE-FG02-06ER64213: Development of Modeling Methods and Tools for Predicting Coupled Reactive Transport Processes in Porous Media at Multiple Scales Investigators: T. Prabhakar Clement (PD/PI) and Mark O. Barnett (Auburn), Chunmiao Zheng (Univ. of Alabama), and Norman L. Jones (BYU). The objective of this project was to develop scalable modeling approaches for predicting the reactive transport of metal contaminants. We studied two contaminants, a radioactive cation [U(VI)] and a metal(loid) oxyanion system [As(III/V)], and investigated their interactions with two types of subsurface materials, iron and manganese oxyhydroxides. We also developed modeling methods for describing the experimental results. Overall, the project supported 25 researchers at three universities. Produced 15 journal articles, 3 book chapters, 6 PhD dissertations and 6 MS theses. Three key journal articles are: 1) Jeppu et al., A scalable surface complexation modeling framework for predicting arsenate adsorption on goethite-coated sands, Environ. Eng. Sci., 27(2): 147-158, 2010. 2) Loganathan et al., Scaling of adsorption reactions: U(VI) experiments and modeling, Applied Geochemistry, 24 (11), 2051-2060, 2009. 3) Phillippi, et al., Theoretical solid/solution ratio effects on adsorption and transport: uranium (VI) and carbonate, Soil Sci. Soci. of America, 71:329-335, 2007

  7. Development of Models to Simulate Tracer Tests for Characterization of Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Williams, Mark D.; Reimus, Paul; Vermeul, Vincent R.; Rose, Peter; Dean, Cynthia A.; Watson, Tom B.; Newell, D.; Leecaster, Kevin; Brauser, Eric

    2013-05-01

    A recent report found that power and heat produced from enhanced (or engineered) geothermal systems (EGSs) could have a major impact on the U.S energy production capability while having a minimal impact on the environment. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distribution, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for the design and commercial development of the geothermal energy of a potential EGS site. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. This project was initially focused on tracer development with the application of perfluorinated tracer (PFT) compounds, non-reactive tracers used in numerous applications from atmospheric transport to underground leak detection, to geothermal systems, and evaluation of encapsulated PFTs that would release tracers at targeted reservoir temperatures. After the 2011 midyear review and subsequent discussions with the U.S. Department of Energy Geothermal Technology Program (GTP), emphasis was shifted to interpretive tool development, testing, and validation. Subsurface modeling capabilities are an important component of this project for both the design of suitable tracers and the interpretation of data from in situ tracer tests, be they single- or multi-well tests. The purpose of this report is to describe the results of the tracer and model development for simulating and conducting tracer tests for characterizing EGS parameters.

  8. Radioactive tracers offer a closer look at horizontal completions

    SciTech Connect (OSTI)

    Holcomb, D.L.; Read, D.A. )

    1991-11-01

    Radioactive tracer tagging during stimulation treatments on vertical wells has been in use for many years and applications have been discussed in literature. More recently, multiple radioactive tracers have been employed to help evaluate various aspects of well stimulation. They have become standard industry practice for evaluation of treatment containment, fracture height growth, channeling behind casing, fracture initiation from perforations, diversion and acid or proppant distribution. In this paper completion techniques are analyzed using gamma ray-emitting isotopes and spectral-gamma ray logging. Examples of Austin Chalk and Bakken Shale evaluations show how operators can qualitatively compare stimulation and diversion effectiveness, and completion methods by using tracer technology.

  9. Enforcing positivity in intrusive PC-UQ methods for reactive ODE systems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Najm, Habib N.; Valorani, Mauro

    2014-04-12

    We explore the relation between the development of a non-negligible probability of negative states and the instability of numerical integration of the intrusive Galerkin ordinary differential equation system describing uncertain chemical ignition. To prevent this instability without resorting to either multi-element local polynomial chaos (PC) methods or increasing the order of the PC representation in time, we propose a procedure aimed at modifying the amplitude of the PC modes to bring the probability of negative state values below a user-defined threshold. This modification can be effectively described as a filtering procedure of the spectral PC coefficients, which is applied on-the-flymore » during the numerical integration when the current value of the probability of negative states exceeds the prescribed threshold. We demonstrate the filtering procedure using a simple model of an ignition process in a batch reactor. This is carried out by comparing different observables and error measures as obtained by non-intrusive Monte Carlo and Gauss-quadrature integration and the filtered intrusive procedure. Lastly, the filtering procedure has been shown to effectively stabilize divergent intrusive solutions, and also to improve the accuracy of stable intrusive solutions which are close to the stability limits.« less

  10. Innovative techniques for the description of reservoir heterogeneity using tracers. Final report, October 1992--December 1993

    SciTech Connect (OSTI)

    Pope, G.A.; Sepehrnoori, K.; Delshad, M.; Ferreira, L.; Gupta, A.; Maroongroge, V.

    1994-11-01

    This is the final report of a three year research project on the use of tracers for reservoir characterization. The objective of this research was to develop advanced, innovative techniques for the description of reservoir characteristics using both single-well backflow and interwell tracer tests. (1) The authors implemented and validated tracer modeling features in a compositional simulator (UTCOMP). (2) They developed and applied a new single well tracer test for estimating reservoir heterogeneity. (3) They developed and applied a new single well tracer test for estimating reservoir wettability in-situ. (4) They developed a new, simple and efficient method to analyze two well tracer tests based upon type curve matching and illustrated its use with actual field tracer data. (5) They developed a new method for deriving an integrated reservoir description based upon combinatorial optimization schemes. (6) They developed a new, interwell tracer test for reservoir heterogeneity called vertical tracer profiling (VTP) and demonstrated its advantages over conventional interwell tracer testing. (7) They developed a simple and easy analytical method to estimate swept pore volume from interwell tracer data and showed both the theoretical basis for this method and its practical utility. (8) They made numerous enhancements to our compositional reservoir simulator such as including the full permeability tensor, adding faster solvers, improving its speed and robustness and making it easier to use (better I/0) for tracer simulation problems. (9) They applied the enhanced version of UTCOMP to the analysis of interwell tracer data using perfluorocarbons at Elks Hill Naval Petroleum Reserve. All of these accomplishments taken together have significantly improved the state of reservoir tracer technology and have demonstrated that it is a far more powerful and useful tool for quantitative reservoir characterization than previously realized or practiced by the industry.

  11. Tracers and Exploration Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracers and Exploration Technologies Tracers and Exploration Technologies Below are the project presentations and respective peer review results for Tracers and Exploration Technologies. Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs, Thomas Watson, Brookhaven National Laboratory; Paul W. Reimus, Los Alamos National Laboratory; Vince Vermeul, Pacific Northwest National

  12. Wear Measurement of Highly Cross-linked UHMWPE using a 7Be Tracer...

    Office of Scientific and Technical Information (OSTI)

    Tracer methods are there- fore being explored. The purpose of this study was to perform a proof-of-concept experiment ... Country of Publication: United States Language: English ...

  13. A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene...

    Open Energy Info (EERE)

    Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Jump to: navigation, search OpenEI Reference...

  14. Quantitative assessment of alkali-reactive aggregate mineral content through XRD using polished sections as a supplementary tool to RILEM AAR-1 (petrographic method)

    SciTech Connect (OSTI)

    Castro, Nelia; Sorensen, Bjorn E.; Broekmans, Maarten A.T.M.

    2012-11-15

    The mineral content of 5 aggregate samples from 4 different countries, including reactive and non-reactive aggregate types, was assessed quantitatively by X-ray diffraction (XRD) using polished sections. Additionally, electron probe microanalyzer (EPMA) mapping and cathodoluminescence (CL) were used to characterize the opal-CT identified in one of the aggregate samples. Critical review of results from polished sections against traditionally powdered specimen has demonstrated that for fine-grained rocks without preferred orientation the assessment of mineral content by XRD using polished sections may represent an advantage over traditional powder specimens. Comparison of data on mineral content and silica speciation with expansion data from PARTNER project confirmed that the presence of opal-CT plays an important role in the reactivity of one of the studied aggregates. Used as a complementary tool to RILEM AAR-1, the methodology suggested in this paper has the potential to improve the strength of the petrographic method.

  15. Brush potential curve tracer

    DOE Patents [OSTI]

    Finch, H.A.

    1985-06-21

    A device for analyzing commutating characteristics of a motor or generator includes a holder for supporting a plurality of probes adjacent a brush of the motor or generator. Measurements of electrical current characteristics of the probes provides information useful in analyzing operation of the machine. Methods for employing a device in accordance with the invention are also disclosed.

  16. Brush potential curve tracer

    DOE Patents [OSTI]

    Finch, Hilvan A.

    1987-01-01

    A device for analyzing commutating characteristics of a motor or generator includes a holder for supporting a plurality of probes adjacent a brush of the motor or generator. Measurements of electrical current characteristics in each of the probes provides information useful in analyzing operation of the machine. Methods for employing a device in accordance with the invention are also disclosed.

  17. Reactive power pricing and management

    SciTech Connect (OSTI)

    Hao, S.; Papalexopoulos, A.

    1997-02-01

    This paper explores the technical and economic issues of determining reactive power pricing structures in an open-access environment. It is believed that reactive power pricing and management under open-access will depend upon two important developments: (1) the functional unbundling of facilities that support the reactive power and voltage control service, and (2) grid rules to facilitate the coordination between generation and transmission systems for reliable system operation. The paper discusses the characteristics of reactive power that must be considered in order to develop a framework for reactive power pricing and management. Several cost allocation methods for valuing reactive power are presented. Two workable reactive power pricing structures are also proposed. The first is based on performance standards and the second is based on the local reactive power market concept.

  18. Non-invasive in situ plasma monitoring of reactive gases using the floating harmonic method for inductively coupled plasma etching application

    SciTech Connect (OSTI)

    Lee, J. H.; Kim, M. J.; Yoon, Y. S.

    2013-04-15

    The floating harmonic method was developed for in situ plasma diagnostics of allowing real time measurement of electron temperature (T{sub e}) and ion flux (J{sub ion}) without contamination of the probe from surface modification by reactive species. In this study, this novel non-invasive diagnostic system was studied to characterize inductively coupled plasma of reactive gases monitoring T{sub e} and J{sub ion} for investigating the optimum plasma etching conditions and controlling of the real-time plasma surface reaction in the range of 200-900 W source power, 10-100 W bias power, and 3-15 mTorr chamber pressure, respectively.

  19. Unit vent airflow measurements using a tracer gas technique

    SciTech Connect (OSTI)

    Adams, D.G.; Lagus, P.L.; Fleming, K.M.

    1997-08-01

    An alternative method for assessing flowrates that does not depend on point measurements of air flow velocity is the constant tracer injection technique. In this method one injects a tracer gas at a constant rate into a duct and measures the resulting concentration downstream of the injection point. A simple equation derived from the conservation of mass allows calculation of the flowrate at the point of injection. Flowrate data obtained using both a pitot tube and a flow measuring station were compared with tracer gas flowrate measurements in the unit vent duct at the Callaway Nuclear Station during late 1995 and early 1996. These data are presented and discussed with an eye toward obtaining precise flowrate data for release rate calculations. The advantages and disadvantages of the technique are also described. In those test situations for which many flowrate combinations are required, or in large area ducts, a tracer flowrate determination requires fewer man-hours than does a conventional traverse-based technique and does not require knowledge of the duct area. 6 refs., 10 figs., 6 tabs.

  20. A Simple, Fast Method of Estimating Fractured Reservoir Geometry...

    Open Energy Info (EERE)

    Fractured Reservoir Geometry from Tracer Tests Abstract A simple method of estimating flow geometry and pore geometry from conservative tracer tests in single phase geothermal...

  1. Reactive power compensator

    DOE Patents [OSTI]

    El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.; Chen, Mingliang; Andexler, George; Huang, Tony

    1992-01-01

    A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation.

  2. Reactive Power Compensator.

    DOE Patents [OSTI]

    El-Sharkawi, M.A.; Venkata, S.S.; Chen, M.; Andexler, G.; Huang, T.

    1992-07-28

    A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation. 26 figs.

  3. Pore-scale simulation of coupled reactive transport and dissolution in fractures and porous media using the level set interface tracking method

    SciTech Connect (OSTI)

    Hai Huang; Xiaoyi Li

    2011-01-01

    A level set simulation methodology developed for modeling coupled reactive transport and structure evolution has been applied to dissolution in fracture apertures and porous media. The coupled processes such as fluid flow, reactant transport and dissolution at the solid-liquid interfaces are handled simultaneously. The reaction-induced evolution of solid-liquid interfaces is captured using the level set method, with the advantage of representing the interface with sub-grid scale resolution. The coupled processes are simulated for several geometric models of fractures and porous media under various flow conditions and reaction rates. Quantitative relationships between permeability and porosity are obtained from some of the simulation results and compared with analytical constitutive relations (i.e., the conventional cubic law and the Carman-Kozeny law) based on simplified pore space geometries and reaction induced geometric evolutions. The drastic deviation of the simulation results from these analytical theories is explained by the development of large local concentration gradients of reactants within fracture apertures and individual pores observed in the simulation results and consequently the complex geometric evolution patterns of fracture apertures and pores due to mineral dissolution. The simulation results support the argument that traditional constitutive relations based on simplified geometries and conditions have limited applicability in predicting field scale reactive transport and that incorporation of micro-scale physics is necessary.

  4. Fuel Temperature Coefficient of Reactivity

    SciTech Connect (OSTI)

    Loewe, W.E.

    2001-07-31

    A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

  5. ARM - CARES - Tracer Forecast for CARES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CampaignsCarbonaceous Aerosols and Radiative Effects Study (CARES)Tracer Forecast for CARES Related Links CARES Home AAF Home ARM Data Discovery Browse Data Post-Campaign Data Sets Field Updates CARES Wiki Campaign Images Experiment Planning Proposal Abstract and Related Campaigns Science Plan Operations Plan Measurements Forecasts News News & Press Backgrounder (PDF, 1.45MB) G-1 Aircraft Fact Sheet (PDF, 1.3MB) Contacts Rahul Zaveri, Lead Scientist Tracer Forecasts for CARES This webpage

  6. Analysis of tracer and thermal transients during reinjection

    SciTech Connect (OSTI)

    Kocabas, I.

    1989-10-01

    This work studied tracer and thermal transients during reinjection in geothermal reserviors and developed a new technique which combines the results from interwell tracer tests and thermal injection-backflow tests to estimate the thermal breakthrough times. Tracer tests are essential to determine the degree of connectivity between the injection wells and the producing wells. To analyze the tracer return profiles quantitatively, we employed three mathematical models namely, the convection-dispersion (CD) model, matrix diffusion (MD) model, and the Avodnin (AD) model, which were developed to study tracer and heat transport in a single vertical fracture. We considered three types of tracer tests namely, interwell tracer tests without recirculation, interwell tracer tests with recirculation, and injection-backflow tracer tests. To estimate the model parameters, we used a nonlinear regression program to match tracer return profiles to the solutions.

  7. Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Multidimensional Tracers for Geothermal Inter-Well Diagnostics Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics presentation at the April 2013 peer review meeting held in Denver, Colorado. tang_peer2013.pdf (1.14 MB) More Documents & Publications Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics Use of Tracers to Characterize Fractures in Engineered Geothermal

  8. RCUT: A Non-Invasive Method for Detection, Location, and Quantification of Radiological Contaminants in Pipes and Ducts - 12514

    SciTech Connect (OSTI)

    Bratton, Wesley L.; Maresca, Joseph W. Jr.; Beck, Deborah A.

    2012-07-01

    Radiological Characterization Using Tracers (RCUT) is a minimally invasive method for detection and location of residual radiological contamination in pipes and ducts. The RCUT technology utilizes reactive gaseous tracers that dissociate when exposed to gamma and/or beta radiation emitting from a radiological contaminant in a pipe or duct. Sulfur hexafluoride (SF{sub 6}) was selected as a tracer for this radiological application, because it is a chemically inert gas that is both nonflammable, nontoxic, and breaks down when exposed to gamma radiation. Laboratory tests demonstrated that the tracer pair of SF{sub 6} and O{sub 2} formed SO{sub 2}F{sub 2} when exposed to a gamma or beta radioactive field, which indicated the presence of radiological contamination. Field application of RCUT involves first injecting the reactive tracers into the pipe to fill the pipe being inspected and allowing sufficient time for the tracer to interact with any contaminants present. This is followed by the injection of an inert gas at one end of the pipe to push the reactive tracer at a known or constant flow velocity along the pipe and then out the exit and sampling port at the end of the pipeline where its concentration is measured by a gas chromatograph. If a radiological contaminant is present in the pipe being tested, the presence of SO{sub 2}F{sub 2} will be detected. The time of arrival of the SO{sub 2}F{sub 2} can be used to locate the contaminant. If the pipe is free of radiological contamination, no SO{sub 2}F{sub 2} will be detected. RCUT and PCUT are both effective technologies that can be used to detect contamination within pipelines without the need for mechanical or human inspection. These methods can be used to detect, locate, and/or estimate the volume of a variety of radioactive materials and hazardous chemicals such as chlorinated solvents, petroleum products, and heavy metals. While further optimization is needed for RCUT, the key first step of identification of a

  9. Reactive Air Aluminization

    SciTech Connect (OSTI)

    Choi, Jung-Pyung; Chou, Y. S.; Stevenson, Jeffry W.

    2011-10-28

    Ferritic stainless steels and other alloys are of great interest to SOFC developers for applications such as interconnects, cell frames, and balance of plant components. While these alloys offer significant advantages (e.g., low material and manufacturing cost, high thermal conductivity, and high temperature oxidation resistance), there are challenges which can hinder their utilization in SOFC systems; these challenges include Cr volatility and reactivity with glass seals. To overcome these challenges, protective coatings and surface treatments for the alloys are under development. In particular, aluminization of alloy surfaces offers the potential for mitigating both evaporation of Cr from the alloy surface and reaction of alloy constituents with glass seals. Commercial aluminization processes are available to SOFC developers, but they tend to be costly due to their use of exotic raw materials and/or processing conditions. As an alternative, PNNL has developed Reactive Air Aluminization (RAA), which offers a low-cost, simpler alternative to conventional aluminization methods.

  10. Tracer Testing At Coso Geothermal Area (2006) | Open Energy Informatio...

    Open Energy Info (EERE)

    and two-phase tracers in fluid-depleted geothermal fields. References Mella, M.; Rose, P.; McCulloch, J.; Buck, C. (1 January 2006) A Tracer Test Using Ethanol as a...

  11. Quantum Dot Tracers for Use in Engineered Geothermal

    Broader source: Energy.gov [DOE]

    Quantum Dot Tracers for Use in Engineered Geothermal presentation at the April 2013 peer review meeting held in Denver, Colorado.

  12. Tracer Testing At Raft River Geothermal Area (1983) | Open Energy...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Tracer Testing At Raft River Geothermal Area (1983) Exploration Activity Details Location Raft River...

  13. Use of Tracers to Characterize Fractures in Engineered Geothermal Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Use of Tracers to Characterize Fractures in Engineered Geothermal Systems Use of Tracers to Characterize Fractures in Engineered Geothermal Systems Project Objectives: Measure interwell fracture surface area and fracture spacing using sorbing tracers; measure fracture surface areas adjacent to a single geothermal well using tracers and injection/backflow techniques; design, fabricate and test a downhole instrument for measuring fracture flow following a hydraulic

  14. Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain site characterization study. Final report

    SciTech Connect (OSTI)

    Stetzenbach, K.; Farnham, I.

    1996-06-01

    Extensive tracer testing is expected to take place at the C-well complex in the Nevada Test Site as part of the Yucca Mountain Site Characterization Project. The C-well complex consists of one pumping well, C3, and two injection wells, C1 and C2 into which tracer will be introduced. The goal of this research was to provide USGS with numerous tracers to completed these tests. Several classes of fluorinated organic acids have been evaluated. These include numerous isomers of fluorinated benzoic acids, cinnamic acids, and salicylic acids. Also several derivatives of 2-hydroxy nicotinic acid (pyridone) have been tested. The stability of these compounds was determined using batch and column tests. Ames testing (mutagenicity/carcinogenicity) was conducted on the fluorinated benzoic acids and a literature review of toxicity of the fluorobenzoates and three perfluoro aliphatic acids was prepared. Solubilities were measured and method development work was performed to optimize the detection of these compounds. A Quality Assurance (QA) Program was developed under existing DOE and USGS guidelines. The program includes QA procedures and technical standard operating procedures. A tracer test, using sodium iodide, was performed at the C-well complex. HRC chemists performed analyses on site, to provide real time data for the USGS hydrologists and in the laboratories at UNLV. Over 2,500 analyses were performed. This report provides the results of the laboratory experiments and literature reviews used to evaluate the potential tracers and reports on the results of the iodide C-well tracer test.

  15. Permeable Reactive Barriers

    Broader source: Energy.gov [DOE]

    A permeable reactive barrier (PRB) is a zone of reactive material placed underground to intercept and react with a contaminant plume in ground water. Typically, PRBs are emplaced by replacing soils...

  16. DETERMINATION OF SPECIFIC NEUTRONIC REACTIVITY

    DOE Patents [OSTI]

    Dessauer, G.

    1960-05-10

    A method is given for production-line determination of the specific neutronic reactivity of such objects as individual nuclear fuel or neutron absorber elements and is notable for rapidity and apparatus simplicity. The object is incorporated in a slightly sub-critical chain fission reactive assembly having a discrete neutron source, thereby establishing a K/sub eff/ within the crucial range of 0.95 to 0.995. The range was found to afford, uniquely, flux- transient damped response in a niatter of seconds simultaneously with acceptable analytical sensitivity. The resulting neutron flux measured at a situs spaced from both object and source within the assembly serves as a calibrable indication of said reactivity.

  17. COMPARISON OF THREE TRACER TESTS AT THE RAFT RIVER GEOTHERMAL...

    Office of Scientific and Technical Information (OSTI)

    TESTS AT THE RAFT RIVER GEOTHERMAL SITE Citation Details In-Document Search Title: COMPARISON OF THREE TRACER TESTS AT THE RAFT RIVER GEOTHERMAL SITE Three conservative ...

  18. Tracer Testing At Coso Geothermal Area (1993) | Open Energy Informatio...

    Open Energy Info (EERE)

    Activity Details Location Coso Geothermal Area Exploration Technique Tracer Testing Activity Date 1993 Usefulness useful DOE-funding Unknown Exploration Basis To determine...

  19. Tracer Testing At Dixie Valley Geothermal Area (Reed, 2007) ...

    Open Energy Info (EERE)

    tetrasulfonate compounds. Tracer analysis was conducted by a combination of liquid chromatography and ultraviolet-fluorescence spectroscopy. Mean residence time, fracture volume in...

  20. Integrated Approach to Use Natural Chemical and Isotopic Tracers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fracture Spacing and Surface Area in EGS Systems Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems DOE ...

  1. Using Thermally-Degrading, Partitioning, and Nonreactive Tracers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and FractureHeat Transfer Surface Area in Geothermal Reservoirs Using ...

  2. Unraveling DPF Degradation using Chemical Tracers and Opportunities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Opportunities for Extending Filter Life Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending Filter Life A unique electrochemical sensing strategy ...

  3. Groundwater well with reactive filter pack

    DOE Patents [OSTI]

    Gilmore, Tyler J.; Holdren, Jr., George R.; Kaplan, Daniel I.

    1998-01-01

    A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

  4. Groundwater well with reactive filter pack

    DOE Patents [OSTI]

    Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

    1998-09-08

    A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

  5. Method of uranium reclamation from aqueous systems by reactive ion exchange. [US DOE patent application; anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands

    DOE Patents [OSTI]

    Maya, L.

    1981-11-05

    A reactive ion exchange method for separation and recovery of values of uranium, neptunium, plutonium, or americium from substantially neutral aqueous systems of said metals comprises contacting said system with an effective amount of a basic anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands to achieve nearly 100% sorption of said actinyl ion onto said resin and an aqueous system practically free of said actinyl ions. The method is operational over an extensive range of concentrations from about 10/sup -6/ M to 1.0 M actinyl ion and a pH range of about 4 to 7. The method has particulr application to treatment of waste streams from Purex-type nuclear fuel reprocessing facilities and hydrometallurgical processes involving U, Np, P, or Am.

  6. National Biomedical Tracer Facility. Project definition study

    SciTech Connect (OSTI)

    Schafer, R.

    1995-02-14

    We request a $25 million government-guaranteed, interest-free loan to be repaid over a 30-year period for construction and initial operations of a cyclotron-based National Biomedical Tracer Facility (NBTF) in North Central Texas. The NBTF will be co-located with a linear accelerator-based commercial radioisotope production facility, funded by the private sector at approximately $28 million. In addition, research radioisotope production by the NBTF will be coordinated through an association with an existing U.S. nuclear reactor center that will produce research and commercial radioisotopes through neutron reactions. The combined facilities will provide the full range of technology for radioisotope production and research: fast neutrons, thermal neutrons, and particle beams (H{sup -}, H{sup +}, and D{sup +}). The proposed NBTF facility includes an 80 MeV, 1 mA H{sup -} cyclotron that will produce proton-induced (neutron deficient) research isotopes.

  7. Theoretical Investigation of Hydrogen Adsorption and Dissociation on Iron and Iron Carbide Surfaces Using the ReaxFF Reactive Force Field Method

    SciTech Connect (OSTI)

    Zou, Chenyu; van Duin, Adri C.T.; Sorescu, Dan C.

    2012-06-01

    We have developed a ReaxFF reactive force field to describe hydrogen adsorption and dissociation on iron and iron carbide surfaces relevant for simulation of FischerTropsch (FT) synthesis on iron catalysts. This force field enables large system (>>1000 atoms) simulations of hydrogen related reactions with iron. The ReaxFF force field parameters are trained against a substantial amount of structural and energetic data including the equations of state and heats of formation of iron and iron carbide related materials, as well as hydrogen interaction with iron surfaces and different phases of bulk iron. We have validated the accuracy and applicability of ReaxFF force field by carrying out molecular dynamics simulations of hydrogen adsorption, dissociation and recombination on iron and iron carbide surfaces. The barriers and reaction energies for molecular dissociation on these two types of surfaces have been compared and the effect of subsurface carbon on hydrogen interaction with iron surface is evaluated. We found that existence of carbon atoms at subsurface iron sites tends to increase the hydrogen dissociation energy barrier on the surface, and also makes the corresponding hydrogen dissociative state relatively more stable compared to that on bare iron. These properties of iron carbide will affect the dissociation rate of H{sub 2} and will retain more surface hydride species, thus influencing the dynamics of the FT synthesis process.

  8. Preferred methods of analysis for chemical tracers in moderate...

    Open Energy Info (EERE)

    or error are discussed in detail. Authors Kroneman, R. L.; Yorgason, K. R.; Moore and J. N. Published DOE Information Bridge, 1211984 DOI 10.21725121460 Citation...

  9. Tracer Methods for Characterizing Fracture Creation in Enhanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Initially, experimental tools and techniques have been developed and tested. Lab experiments are integrated with computational experiments as a means of data inversion. Each of the ...

  10. Verification of Geothermal Tracer Methods in Highly Constrained...

    Open Energy Info (EERE)

    the problem can be fully constrained. In a shallow horizontal sandstone fracture surface ground penetrating radar (GPR) is used to map the flow paths in the fracture independently...

  11. Apparatus and method for downhole injection of radioactive tracer

    DOE Patents [OSTI]

    Potter, R.M.; Archuleta, J.; Fink, C.F.

    The disclosure relates to downhole injection of radioactive /sup 82/Br and monitoring its progress through fractured structure to determine the nature thereof. An ampule containing granular /sup 82/Br is remotely crushed and water is repeatedly flushed through it to cleanse the instrument as well as inject the /sup 82/Br into surrounding fractured strata. A sensor in a remote horehole reads progress of the radioactive material through fractured structure.

  12. Apparatus and method for downhole injection of radioactive tracer

    DOE Patents [OSTI]

    Potter, Robert M.; Archuleta, Jacobo R.; Fink, Conrad F.

    1983-01-01

    The disclosure relates to downhole injection of radioactive .sup.82 Br and monitoring its progress through fractured structure to determine the nature thereof. An ampule containing granular .sup.82 Br is remotely crushed and water is repeatedly flushed through it to cleanse the instrument as well as inject the .sup.82 Br into surrounding fractured strata. A sensor in a remote borehole reads progress of the radioactive material through fractured structure.

  13. Tracer Testing At Fenton Hill HDR Geothermal Area (Callahan,...

    Open Energy Info (EERE)

    the Hot Dry Rock Geothermal System, Fenton Hill, New Mexico- Tracer Test Results Donald Brown, Robert DuTeaux (1997) Three Principal Results from Recent Fenton Hill Flow Testing...

  14. Tracer advection by steady groundwater flow in a stratified aquifer

    SciTech Connect (OSTI)

    Sposito, Garrison; Weeks, Scott W.

    1997-01-02

    The perfectly stratified aquifer has often been investigated as a simple, tractable model for exploring new theoretical issues in subsurface hydrology. Adopting this approach, we show that steady groundwater flows in the perfectly stratified aquifer are always confined to a set of nonintersecting permanent surfaces, on which both streamlines and vorticity lines lie. This foliation of the flow domain exists as well for steady groundwater flows in any isotropic, spatially heterogeneous aquifer. In the present model example it is a direct consequence of the existence of a stream function, we then demonstrate that tracer plume advection by steady groundwater flow in a perfectly stratified aquifer is never ergodic, regardless of the initial size of the tracer plume. This nonergodicity, which holds also for tracer advection in any isotropic, spatially heterogeneous aquifer, implies that stochastic theories of purely advective tracer plume movement err in assuming ergodic behavior to simplify probabilistic calculations of plume spatial concentration moments.

  15. Tracer testing in geothermal reservoirs | Open Energy Information

    Open Energy Info (EERE)

    geothermal reservoirs Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Tracer testing in geothermal reservoirs Author PetroWiki Published PetroWiki,...

  16. Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate...

    Open Energy Info (EERE)

    at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate Amino G, and Fluorescein Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Tracer Testing at...

  17. Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics Principal Investigator : Yongchun Tang Presenter: John Ma Power Environmental Energy Research Institute DE-EE0003032 Project Officer: John Ma Total Project Funding: $2,300,000 April 23, 2013 This presentation does not contain any proprietary confidential, or otherwise restricted information. 2 | US DOE Geothermal Office eere.energy.gov Relevance/Impact of Research Objective: Develop a matrix of the smart geothermal tracer and

  18. Unraveling DPF Degradation using Chemical Tracers and Opportunities for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Extending Filter Life | Department of Energy Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending Filter Life Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending Filter Life A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs deer10_sappok.pdf

  19. Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs | Department of Energy Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs DOE Geothermal Peer Review 2010 -

  20. Integrated Approach to Use Natural Chemical and Isotopic Tracers to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Estimate Fracture Spacing and Surface Area in EGS Systems | Department of Energy Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems DOE Geothermal Peer Review 2010 - Presentation. This objective of this project is to develop an innovative approach to estimate fracture surface area and spacing through

  1. HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS

    SciTech Connect (OSTI)

    Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

    2012-01-01

    The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

  2. Appraisal of transport and deformation in shale reservoirs using natural noble gas tracers

    SciTech Connect (OSTI)

    Heath, Jason E.; Kuhlman, Kristopher L.; Robinson, David G.; Bauer, Stephen J.; Gardner, William Payton

    2015-09-01

    This report presents efforts to develop the use of in situ naturally-occurring noble gas tracers to evaluate transport mechanisms and deformation in shale hydrocarbon reservoirs. Noble gases are promising as shale reservoir diagnostic tools due to their sensitivity of transport to: shale pore structure; phase partitioning between groundwater, liquid, and gaseous hydrocarbons; and deformation from hydraulic fracturing. Approximately 1.5-year time-series of wellhead fluid samples were collected from two hydraulically-fractured wells. The noble gas compositions and isotopes suggest a strong signature of atmospheric contribution to the noble gases that mix with deep, old reservoir fluids. Complex mixing and transport of fracturing fluid and reservoir fluids occurs during production. Real-time laboratory measurements were performed on triaxially-deforming shale samples to link deformation behavior, transport, and gas tracer signatures. Finally, we present improved methods for production forecasts that borrow statistical strength from production data of nearby wells to reduce uncertainty in the forecasts.

  3. A Study Plan for Determining Recharge Rates at the Hanford Site Using Environmental Tracers

    SciTech Connect (OSTI)

    Murphy,, E. M.; Szecsody,, J. E.; Phillips,, S. J.

    1991-02-01

    . Seven study sites on the Hanford Site have been selected, in two primary soil types that are believed to represent the extremes in recharge, the Quincy sand and the Warden silt loam. An additional background study site upwind of the Hanford facilities has been chosen at the Yakima Firing Center. Study sites at Hanford were chosen close to micrometeorology stations on downwind transects from the operational facilities. Initial testing will be done on sites that lack perennial vegetation. Six tracer techniques (total chlortde, {sup 36}Cl, {sup 3}H, nitrate, {sup 129}I, and {sup 99}Tc) will be tested on at least one site in the Quincy sand, one site in the Warden si~ loam, and the background site, to determine which combination of tracers wortks best for a given soil type. In subsequent years, additional sites will be investigated to determine the effect of vegetation on recharge estimates and on the performance of individual tracers. The use of environmental tracers is perhaps the only cost-effective method for estimating the spatial vartability of recharge at a site as large as Hanford. The tracer techniques used at Hanford have wide applicability at other and sites operated by the U.S. Department of Energy as well as at low-level radioactive waste disposal sites.

  4. A semi-experimental nodal synthesis method for the on-line reconstruction of three-dimensional neutron flux-shapes and reactivity

    SciTech Connect (OSTI)

    Jacqmin, R.P.

    1991-12-10

    The safety and optimal performance of large, commercial, light-water reactors require the knowledge at all time of the neutron-flux distribution in the core. In principle, this information can be obtained by solving the time-dependent neutron diffusion equations. However, this approach is complicated and very expensive. Sufficiently accurate, real-time calculations (time scale of approximately one second) are not yet possible on desktop computers, even with fast-running, nodal kinetics codes. A semi-experimental, nodal synthesis method which avoids the solution of the time-dependent, neutron diffusion equations is described. The essential idea of this method is to approximate instantaneous nodal group-fluxes by a linear combination of K, precomputed, three-dimensional, static expansion-functions. The time-dependent coefficients of the combination are found from the requirement that the reconstructed flux-distribution agree in a least-squares sense with the readings of J ({ge}K) fixed, prompt-responding neutron-detectors. Possible numerical difficulties with the least-squares solution of the ill-conditioned, J-by-K system of equations are brought under complete control by the use of a singular-value-decomposition technique. This procedure amounts to the rearrangement of the original, linear combination of K expansion functions into an equivalent more convenient, linear combination of R ({le}K) orthogonalized modes'' of decreasing magnitude. Exceedingly small modes are zeroed to eliminate any risk of roundoff-error amplification, and to assure consistency with the limited accuracy of the data. Additional modes are zeroed when it is desirable to limit the sensitivity of the results to measurement noise.

  5. A semi-experimental nodal synthesis method for the on-line reconstruction of three-dimensional neutron flux-shapes and reactivity. Final report

    SciTech Connect (OSTI)

    Jacqmin, R.P.

    1991-12-10

    The safety and optimal performance of large, commercial, light-water reactors require the knowledge at all time of the neutron-flux distribution in the core. In principle, this information can be obtained by solving the time-dependent neutron diffusion equations. However, this approach is complicated and very expensive. Sufficiently accurate, real-time calculations (time scale of approximately one second) are not yet possible on desktop computers, even with fast-running, nodal kinetics codes. A semi-experimental, nodal synthesis method which avoids the solution of the time-dependent, neutron diffusion equations is described. The essential idea of this method is to approximate instantaneous nodal group-fluxes by a linear combination of K, precomputed, three-dimensional, static expansion-functions. The time-dependent coefficients of the combination are found from the requirement that the reconstructed flux-distribution agree in a least-squares sense with the readings of J ({ge}K) fixed, prompt-responding neutron-detectors. Possible numerical difficulties with the least-squares solution of the ill-conditioned, J-by-K system of equations are brought under complete control by the use of a singular-value-decomposition technique. This procedure amounts to the rearrangement of the original, linear combination of K expansion functions into an equivalent more convenient, linear combination of R ({le}K) orthogonalized ``modes`` of decreasing magnitude. Exceedingly small modes are zeroed to eliminate any risk of roundoff-error amplification, and to assure consistency with the limited accuracy of the data. Additional modes are zeroed when it is desirable to limit the sensitivity of the results to measurement noise.

  6. Reactive Power Compensating System.

    DOE Patents [OSTI]

    Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

    1985-01-04

    The circuit was designed for the specific application of wind-driven induction generators. It has great potential for application in any situation where a varying reactive power load is present, such as with induction motors or generators, or for transmission network compensation.

  7. Reactive power compensating system

    DOE Patents [OSTI]

    Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

    1987-01-01

    The reactive power of an induction machine is compensated by providing fixed capacitors on each phase line for the minimum compensation required, sensing the current on one line at the time its voltage crosses zero to determine the actual compensation required for each phase, and selecting switched capacitors on each line to provide the balance of the compensation required.

  8. Quantifying groundwater travel time near managed recharge operations using 35S as an intrinsic tracer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urióstegui, Stephanie H.; Bibby, Richard K.; Esser, Bradley K.; Clark, Jordan F.

    2016-04-23

    By identifying groundwater retention times near managed aquifer recharge (MAR) facilities is a high priority for managing water quality, especially for operations that incorporate recycled wastewater. In order to protect public health, California guidelines for Groundwater Replenishment Reuse Projects require a minimum 2–6 month subsurface retention time for recycled water depending on the level of disinfection, which highlights the importance of quantifying groundwater travel times on short time scales. This study developed and evaluated a new intrinsic tracer method using the naturally occurring radioisotope sulfur-35 (35S). The 87.5 day half-life of 35S is ideal for investigating groundwater travel times onmore » the <1 year timescale of interest to MAR managers. Natural concentrations of 35S found in water as dissolved sulfate (35SO4) were measured in source waters and groundwater at the Rio Hondo Spreading Grounds in Los Angeles County, CA, and Orange County Groundwater Recharge Facilities in Orange County, CA. 35SO4 travel times are comparable to travel times determined by well-established deliberate tracer studies. The study also revealed that 35SO4 in MAR source water can vary seasonally and therefore careful characterization of 35SO4 is needed to accurately quantify groundwater travel time. But, more data is needed to fully assess whether or not this tracer could become a valuable tool for managers.« less

  9. Permeable Reactive Barriers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barrier Field Projects Durango, Colorado Durango, Colorado DOE installed a PRB in October 1995 to treat ...

  10. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-01-21

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  11. Water reactive hydrogen fuel cell power system

    SciTech Connect (OSTI)

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-11-25

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  12. Effects from influent boundary conditions on tracer migration and spatial variability features in intermediate-scale experiments

    SciTech Connect (OSTI)

    Fuentes, H.R.; Polzer, W.L.; Springer, E.P.

    1987-04-01

    In previous unsaturated transport studies at Los Alamos dispersion coefficients were estimated to be higher close to the tracer source than at greater distances from the source. Injection of tracers through discrete influent outlets could have accounted for those higher dispersions. Also, a lack of conservation of mass of the tracers was observed and suspected to be due to spatial variability in transport. In the present study experiments were performed under uniform influent (ponded) conditions in which breakthrough of tracers was monitored at four locations at each of four depths. All other conditions were similar to those of the unsaturated transport experiments. A comparison of results from these two sets of experiments indicates differences in the parameter estimates. Estimates were made for the dispersion coefficient and the retardation factor by the one-dimensional steady flow computer code, CFITIM. Estimates were also made for mass and for velocity and the dispersion coefficient by the method of moments. The dispersion coefficient decreased with depth under discrete influent application and increased with depth under ponded influent application. Retardation was predicted better under the discrete influent application than under ponded influent application. Differences in breakthroughs and in estimated parameters among locations at the same depth were observed under ponded influent application. Those differences indicate that there is a lack of conservation of mass as well as significant spatial variability across the experimental domain. 14 refs., 9 figs., 8 tabs.

  13. Using {sup 222}Rn as a tracer of geophysical processes in underground environments

    SciTech Connect (OSTI)

    Lacerda, T.; Anjos, R. M.; Silva, A. A. R. da; Yoshimura, E. M.

    2014-11-11

    Radon levels in two old mines in San Luis, Argentina, are reported and analyzed. These mines are today used for touristic visitation. Our goal was to assess the potential use of such radioactive noble gas as tracer of geological processes in underground environments. CR-39 nuclear track detectors were used during the winter and summer seasons. The findings show that the significant radon concentrations reported in this environment are subject to large seasonal modulations, due to the strong dependence of natural ventilation on the variations of outside temperature. The results also indicate that radon pattern distribution appear as a good method to localize unknown ducts, fissures or secondary tunnels in subterranean environments.

  14. High upwind concentrations observed during an upslope tracer event

    SciTech Connect (OSTI)

    Ciolek, J.T. Jr.

    1993-10-01

    In February of 1991 the Rocky Flats Plant conducted twelve tracer experiments to validate an emergency response dispersion model known as the Terrain-Responsive Atmospheric Code (TRAC) (Hodgin 1985). Experimenters released 140 to 260 kilograms of inert tracer gas (sulfur hexafloride) from the plant over an 11 hour period. During each release, one hundred and sixty-five samples, most of which formed concentric rings of 8 and 16 km radius from the plant, recorded cumulative hourly concentrations of the tracer at one meter above ground level (AGL). Figure 1 contains a depiction of the sampler location, the terrain, and the meteorological stations available within the tracer study area. Brown (1991) describes the experimental setup in more detail. The subject of this paper is an event that occurred early in the fifth experiment, on February 9, 1991. In this experiment, tracer material released from 13:00 to 17:00 LST appeared both downwind and upwind of the source, with the highest concentrations upwind. During the fifth experiment, high pressure in Utah produced mostly sunny skis around Rocky Flats. For most of the day, one could find moderate (5 to 10 ms{sup {minus}1}) northerly (from the North) flow within the 700 to 500 mb level of the atmosphere (approximately 3000 to 5500 meters above Mean Sea Level (MSL)). Synoptic scale motions were isolated enough from the surface layer and heating was great enough to produce a 1 km deep upslope flow (flow from the East to the West) by late afternoon. The winds reversed and became downslope at approximately 17:30 LST.

  15. Multiscale reactive molecular dynamics | Argonne Leadership Computing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facility reactive molecular dynamics Authors: Chris KnighT, Gerrick E. Lindberg, Gregory A. Voth Many processes important to chemistry, materials science, and biology cannot be described without considering electronic and nuclear-level dynamics and their coupling to slower, cooperative motions of the system. These inherently multiscale problems require computationally efficient and accurate methods to converge statistical properties. In this paper, a method is presented that uses data

  16. Low Cost Non-Reactive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Prepared: 10/28/09 Low Cost Non-Reactive Coating for Refractory Metals A non-reactive coating for refractory metals has been developed at The Ames Laboratory. Contamination of rare earth and reactive metals and their alloys has been a chronic problem that results from their interaction with the crucibles or other vessels used in high temperature processing or during other applications. As a consequence, processing and other costs are high due to the need to replace equipment or containers, or

  17. A Bayesian Modeling Approach for Estimation of a Shape-Free Groundwater Age Distribution using Multiple Tracers

    SciTech Connect (OSTI)

    Massoudieh, Arash; Visser, Ate; Sharifi, Soroosh; Broers, Hans Peter

    2013-10-15

    The mixing of groundwaters with different ages in aquifers, groundwater age is more appropriately represented by a distribution rather than a scalar number. To infer a groundwater age distribution from environmental tracers, a mathematical form is often assumed for the shape of the distribution and the parameters of the mathematical distribution are estimated using deterministic or stochastic inverse methods. We found that the prescription of the mathematical form limits the exploration of the age distribution to the shapes that can be described by the selected distribution. In this paper, the use of freeform histograms as groundwater age distributions is evaluated. A Bayesian Markov Chain Monte Carlo approach is used to estimate the fraction of groundwater in each histogram bin. This method was able to capture the shape of a hypothetical gamma distribution from the concentrations of four age tracers. The number of bins that can be considered in this approach is limited based on the number of tracers available. The histogram method was also tested on tracer data sets from Holten (The Netherlands; 3H, 3He, 85Kr, 39Ar) and the La Selva Biological Station (Costa-Rica; SF 6, CFCs, 3H, 4He and 14C), and compared to a number of mathematical forms. According to standard Bayesian measures of model goodness, the best mathematical distribution performs better than the histogram distributions in terms of the ability to capture the observed tracer data relative to their complexity. Among the histogram distributions, the four bin histogram performs better in most of the cases. The Monte Carlo simulations showed strong correlations in the posterior estimates of bin contributions, indicating that these bins cannot be well constrained using the available age tracers. The fact that mathematical forms overall perform better than the freeform histogram does not undermine the benefit of the

  18. A Bayesian Modeling Approach for Estimation of a Shape-Free Groundwater Age Distribution using Multiple Tracers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Massoudieh, Arash; Visser, Ate; Sharifi, Soroosh; Broers, Hans Peter

    2013-10-15

    The mixing of groundwaters with different ages in aquifers, groundwater age is more appropriately represented by a distribution rather than a scalar number. To infer a groundwater age distribution from environmental tracers, a mathematical form is often assumed for the shape of the distribution and the parameters of the mathematical distribution are estimated using deterministic or stochastic inverse methods. We found that the prescription of the mathematical form limits the exploration of the age distribution to the shapes that can be described by the selected distribution. In this paper, the use of freeform histograms as groundwater age distributions is evaluated.more » A Bayesian Markov Chain Monte Carlo approach is used to estimate the fraction of groundwater in each histogram bin. This method was able to capture the shape of a hypothetical gamma distribution from the concentrations of four age tracers. The number of bins that can be considered in this approach is limited based on the number of tracers available. The histogram method was also tested on tracer data sets from Holten (The Netherlands; 3H, 3He, 85Kr, 39Ar) and the La Selva Biological Station (Costa-Rica; SF 6, CFCs, 3H, 4He and 14C), and compared to a number of mathematical forms. According to standard Bayesian measures of model goodness, the best mathematical distribution performs better than the histogram distributions in terms of the ability to capture the observed tracer data relative to their complexity. Among the histogram distributions, the four bin histogram performs better in most of the cases. The Monte Carlo simulations showed strong correlations in the posterior estimates of bin contributions, indicating that these bins cannot be well constrained using the available age tracers. The fact that mathematical forms overall perform better than the freeform histogram does not undermine the benefit of the freeform approach, especially for the cases where a larger amount of observed data is

  19. Quantum Dot Tracers for Use in Engineered Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quantum Dot Tracers for Use in Engineered Geothermal Systems DE-EE0002768 Peter Rose, EGI/University of Utah Michael Bartl, Department of Chemistry at the University of Utah Paul Reimus, Los Alamos National Lab Project Officer: Lauren Boyd Total Project Funding: $1,238,499 April 23, 2013 This presentation does not contain any proprietary confidential, or otherwise restricted information. 2 | US DOE Geothermal Office eere.energy.gov Relevance/Impact of Research The objective of this project is to

  20. Single Well Injection Withdrawl Tracer Tests for Proppant Detection -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Find More Like This Return to Search Single Well Injection Withdrawl Tracer Tests for Proppant Detection Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (800 KB) Technology Marketing SummaryA large question preventing optimal natural gas production from "hydrofracked" shales is how far proppants, injected to keep shale fractures open, move into the gas-bearing shales. Knowing precisely

  1. A Tariff for Reactive Power

    SciTech Connect (OSTI)

    Kueck, John D; Kirby, Brendan J; Li, Fangxing; Tufon, Christopher; Isemonger, Alan

    2008-07-01

    Two kinds of power are required to operate an electric power system: real power, measured in watts, and reactive power, measured in volt-amperes reactive or VARs. Reactive power supply is one of a class of power system reliability services collectively known as ancillary services, and is essential for the reliable operation of the bulk power system. Reactive power flows when current leads or lags behind voltage. Typically, the current in a distribution system lags behind voltage because of inductive loads such as motors. Reactive power flow wastes energy and capacity and causes voltage droop. To correct lagging power flow, leading reactive power (current leading voltage) is supplied to bring the current into phase with voltage. When the current is in phase with voltage, there is a reduction in system losses, an increase in system capacity, and a rise in voltage. Reactive power can be supplied from either static or dynamic VAR sources. Static sources are typically transmission and distribution equipment, such as capacitors at substations, and their cost has historically been included in the revenue requirement of the transmission operator (TO), and recovered through cost-of-service rates. By contrast, dynamic sources are typically generators capable of producing variable levels of reactive power by automatically controlling the generator to regulate voltage. Transmission system devices such as synchronous condensers can also provide dynamic reactive power. A class of solid state devices (called flexible AC transmission system devices or FACTs) can provide dynamic reactive power. One specific device has the unfortunate name of static VAR compensator (SVC), where 'static' refers to the solid state nature of the device (it does not include rotating equipment) and not to the production of static reactive power. Dynamic sources at the distribution level, while more costly would be very useful in helping to regulate local voltage. Local voltage regulation would reduce

  2. Measuring and monitoring KIPT Neutron Source Facility Reactivity

    SciTech Connect (OSTI)

    Cao, Yan; Gohar, Yousry; Zhong, Zhaopeng

    2015-08-01

    Argonne National Laboratory (ANL) of USA and Kharkov Institute of Physics and Technology (KIPT) of Ukraine have been collaborating on developing and constructing a neutron source facility at Kharkov, Ukraine. The facility consists of an accelerator-driven subcritical system. The accelerator has a 100 kW electron beam using 100 MeV electrons. The subcritical assembly has keff less than 0.98. To ensure the safe operation of this neutron source facility, the reactivity of the subcritical core has to be accurately determined and continuously monitored. A technique which combines the area-ratio method and the flux-to-current ratio method is purposed to determine the reactivity of the KIPT subcritical assembly at various conditions. In particular, the area-ratio method can determine the absolute reactivity of the subcritical assembly in units of dollars by performing pulsed-neutron experiments. It provides reference reactivities for the flux-to-current ratio method to track and monitor the reactivity deviations from the reference state while the facility is at other operation modes. Monte Carlo simulations are performed to simulate both methods using the numerical model of the KIPT subcritical assembly. It is found that the reactivities obtained from both the area-ratio method and the flux-to-current ratio method are spatially dependent on the neutron detector locations and types. Numerical simulations also suggest optimal neutron detector locations to minimize the spatial effects in the flux-to-current ratio method. The spatial correction factors are calculated using Monte Carlo methods for both measuring methods at the selected neutron detector locations. Monte Carlo simulations are also performed to verify the accuracy of the flux-to-current ratio method in monitoring the reactivity swing during a fuel burnup cycle.

  3. You are not always what we think you eat. Selective assimilation across multiple whole-stream isotopic tracer studies

    SciTech Connect (OSTI)

    Dodds, W. K.; Collins, S. M.; Hamilton, S. K.; Tank, J. L.; Johnson, S.; Webster, J. R.; Simon, K. S.; Whiles, M. R.; Rantala, H. M.; McDowell, W. H.; Peterson, S. D.; Riis, T.; Crenshaw, C. L.; Thomas, S. A.; Kristensen, P. B.; Cheever, B. M.; Flecker, A. S.; Griffiths, N. A.; Crowl, T.; Rosi-Marshall, E. J.; El-Sabaawi, R.; Martí, E.

    2014-10-01

    Analyses of 21 15N stable isotope tracer experiments, designed to examine food web dynamics in streams around the world, indicated that the isotopic composition of food resources assimilated by primary consumers (mostly invertebrates) poorly reflected the presumed food sources. Modeling indicated that consumers assimilated only 33–50% of the N available in sampled food sources such as decomposing leaves, epilithon, and fine particulate detritus over feeding periods of weeks or more. Thus, common methods of sampling food sources consumed by animals in streams do not sufficiently reflect the pool of N they assimilate. Lastly, Isotope tracer studies, combined with modeling and food separation techniques, can improve estimation of N pools in food sources that are assimilated by consumers.

  4. You are not always what we think you eat. Selective assimilation across multiple whole-stream isotopic tracer studies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dodds, W. K.; Collins, S. M.; Hamilton, S. K.; Tank, J. L.; Johnson, S.; Webster, J. R.; Simon, K. S.; Whiles, M. R.; Rantala, H. M.; McDowell, W. H.; et al

    2014-10-01

    Analyses of 21 15N stable isotope tracer experiments, designed to examine food web dynamics in streams around the world, indicated that the isotopic composition of food resources assimilated by primary consumers (mostly invertebrates) poorly reflected the presumed food sources. Modeling indicated that consumers assimilated only 33–50% of the N available in sampled food sources such as decomposing leaves, epilithon, and fine particulate detritus over feeding periods of weeks or more. Thus, common methods of sampling food sources consumed by animals in streams do not sufficiently reflect the pool of N they assimilate. Lastly, Isotope tracer studies, combined with modeling andmore » food separation techniques, can improve estimation of N pools in food sources that are assimilated by consumers.« less

  5. Core follow calculation with the nTRACER numerical reactor and verification using power reactor measurement data

    SciTech Connect (OSTI)

    Jung, Y. S.; Joo, H. G.; Yoon, J. I.

    2013-07-01

    The nTRACER direct whole core transport code employing the planar MOC solution based 3-D calculation method, the subgroup method for resonance treatment, the Krylov matrix exponential method for depletion, and a subchannel thermal/hydraulic calculation solver was developed for practical high-fidelity simulation of power reactors. Its accuracy and performance is verified by comparing with the measurement data obtained for three pressurized water reactor cores. It is demonstrated that accurate and detailed multi-physic simulation of power reactors is practically realizable without any prior calculations or adjustments. (authors)

  6. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    SciTech Connect (OSTI)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO₂ to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As

  7. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO₂ to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big

  8. Interpretation of Colloid-Homologue Tracer Test 10-03, Including Comparisons to Test 10-01

    SciTech Connect (OSTI)

    Reimus, Paul W.

    2012-06-26

    This presentation covers the interpretations of colloid-homologue tracer test 10-03 conducted at the Grimsel Test Site, Switzerland, in 2010. It also provides a comparison of the interpreted test results with those of tracer test 10-01, which was conducted in the same fracture flow system and using the same tracers than test 10-03, but at a higher extraction flow rate. A method of correcting for apparent uranine degradation in test 10-03 is presented. Conclusions are: (1) Uranine degradation occurred in test 10-03, but not in 10-01; (2) Uranine correction based on apparent degradation rate in injection loop in test 11-02 seems reasonable when applied to data from test 10-03; (3) Colloid breakthrough curves quite similar in the two tests with similar recoveries relative to uranine (after correction); and (4) Much slower apparent desorption of homologues in test 10-03 than in 10-01 (any effect of residual homologues from test 10-01 in test 10-03?).

  9. Final Progress Report for Project Entitled: Quantum Dot Tracers for Use in Engineered Geothermal Systems

    SciTech Connect (OSTI)

    Rose, Peter; Bartl, Michael; Reimus, Paul; Williams, Mark; Mella, Mike

    2015-09-12

    The objective of this project was to develop and demonstrate a new class of tracers that offer great promise for use in characterizing fracture networks in EGS reservoirs. From laboratory synthesis and testing through numerical modeling and field demonstrations, we have demonstrated the amazing versatility and applicability of quantum dot tracers. This report summarizes the results of four years of research into the design, synthesis, and characterization of semiconductor nanocrystals (quantum dots) for use as geothermal tracers.

  10. COMPARISON OF THREE TRACER TESTS AT THE RAFT RIVER GEOTHERMAL SITE

    SciTech Connect (OSTI)

    Earl D Mattson; Mitchell Plummer; Carl Palmer; Larry Hull; Samantha Miller; Randy Nye

    2011-02-01

    Three conservative tracer tests have been conducted through the Bridge Fault fracture zone at the Raft River Geothermal (RRG) site. All three tests were conducted between injection well RRG-5 and production wells RRG-1 (790 m distance) and RRG-4 (740 m distance). The injection well is used during the summer months to provide pressure support to the production wells. The first test was conducted in 2008 using 136 kg of fluorescein tracer. Two additional tracers were injected in 2010. The first 2010 tracer injected was 100 kg fluorescein disodium hydrate salt on June, 21. The second tracer (100 kg 2,6-naphthalene disulfonic acid sodium salt) was injected one month later on July 21. Sampling of the two productions wells is still being performed to obtain the tail end of the second 2010 tracer test. Tracer concentrations were measured using HPLC with a fluorescence detector. Results for the 2008 test, suggest 80% tracer recover at the two production wells. Of the tracer recovered, 85% of tracer mass was recovered in well RRG-4 indicating a greater flow pathway connection between injection well and RRG-4 than RRG-1. Fluorescein tracer results appear to be similar between the 2008 and 2010 tests for well RRG-4 with peak concentrations arriving approximately 20 days after injection despite the differences between the injection rates for the two tests (~950 gpm to 475 gpm) between the 2008 and 2010. The two 2010 tracer tests will be compared to determine if the results support the hypothesis that rock contraction along the flow pathway due to the 55 oC cooler water injection alters the flow through the ~140 oC reservoir.

  11. Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. The objective of this project is to develop a matrix of the smart geothermal tracer and its interpretation tools.

  12. Modeling of CBM production, CO{sub 2} injection, and tracer movement...

    Office of Scientific and Technical Information (OSTI)

    The fate and movement of injected COsub 2 can be determined by using several monitoring techniques. Monitoring of perfluorocarbon (PFC) tracers is one of these monitoring ...

  13. The use of synthetic colloids in tracer transport experiments in saturated rock fractures

    SciTech Connect (OSTI)

    Reimus, P.W.

    1995-08-01

    Studies of groundwater flow and contaminant transport in saturated, fractured geologic media are of great interest to researchers studying the potential long-term storage of hazardous wastes in or near such media. A popular technique for conducting such studies is to introduce tracers having different chemical and physical properties into a system and then observe the tracers at one or more downstream locations, inferring flow and transport mechanisms from the breakthrough characteristics of the different tracers. Many tracer studies have been conducted in saturated, fractured media to help develop and/or refine models capable of predicting contaminant transport over large scales in such media.

  14. Reactive decontamination formulation

    DOE Patents [OSTI]

    Giletto, Anthony; White, William; Cisar, Alan J.; Hitchens, G. Duncan; Fyffe, James

    2003-05-27

    The present invention provides a universal decontamination formulation and method for detoxifying chemical warfare agents (CWA's) and biological warfare agents (BWA's) without producing any toxic by-products, as well as, decontaminating surfaces that have come into contact with these agents. The formulation includes a sorbent material or gel, a peroxide source, a peroxide activator, and a compound containing a mixture of KHSO.sub.5, KHSO.sub.4 and K.sub.2 SO.sub.4. The formulation is self-decontaminating and once dried can easily be wiped from the surface being decontaminated. A method for decontaminating a surface exposed to chemical or biological agents is also disclosed.

  15. Measuring seasonal variations of moisture in a landfill with the partitioning gas tracer test

    SciTech Connect (OSTI)

    Han, Byunghyun; Jafarpour, Behnam; Gallagher, Victoria N.; Imhoff, Paul T. . E-mail: imhoff@udel.edu; Chiu, Pei C.; Fluman, Daniel A.

    2006-07-01

    Seven pilot-scale partitioning gas tracer tests (PGTTs) were conducted to assess the accuracy and reproducibility of this method for measuring water in municipal solid waste landfills. Tests were conducted in the same location over a 12-month period, and measured moisture conditions ranged from possible dry waste to refuse with a moisture content of 24.7%. The final moisture content of 24.7% was in reasonable agreement with gravimetric measurements of excavated refuse, where the moisture content was 26.5 {+-} 6.0CI%. Laboratory tests were used to assess the utility of the PGTT for measuring water in small pores, water sorbed to solid surfaces, and the influence of dry waste on PGTTs. These experiments indicated that when refuse surfaces are not completely solvated with water, PGTTs may produce misleading results (negative estimates) of water saturation and moisture content.

  16. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research Development Center (AMAX R D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  17. Complex functionality with minimal computation. Promise and pitfalls of reduced-tracer ocean biogeochemistry models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Galbraith, Eric D.; Dunne, John P.; Gnanadesikan, Anand; Slater, Richard D.; Sarmiento, Jorge L.; Dufour, Carolina O.; de Souza, Gregory F.; Bianchi, Daniele; Claret, Mariona; Rodgers, Keith B.; et al

    2015-12-21

    Earth System Models increasingly include ocean biogeochemistry models in order to predict changes in ocean carbon storage, hypoxia, and biological productivity under climate change. However, state-of-the-art ocean biogeochemical models include many advected tracers, that significantly increase the computational resources required, forcing a trade-off with spatial resolution. Here, we compare a state-of the art model with 30 prognostic tracers (TOPAZ) with two reduced-tracer models, one with 6 tracers (BLING), and the other with 3 tracers (miniBLING). The reduced-tracer models employ parameterized, implicit biological functions, which nonetheless capture many of the most important processes resolved by TOPAZ. All three are embedded inmore » the same coupled climate model. Despite the large difference in tracer number, the absence of tracers for living organic matter is shown to have a minimal impact on the transport of nutrient elements, and the three models produce similar mean annual preindustrial distributions of macronutrients, oxygen, and carbon. Significant differences do exist among the models, in particular the seasonal cycle of biomass and export production, but it does not appear that these are necessary consequences of the reduced tracer number. With increasing CO2, changes in dissolved oxygen and anthropogenic carbon uptake are very similar across the different models. Thus, while the reduced-tracer models do not explicitly resolve the diversity and internal dynamics of marine ecosystems, we demonstrate that such models are applicable to a broad suite of major biogeochemical concerns, including anthropogenic change. Lastly, these results are very promising for the further development and application of reduced-tracer biogeochemical models that incorporate ‘‘sub-ecosystem-scale’’ parameterizations.« less

  18. Complex functionality with minimal computation. Promise and pitfalls of reduced-tracer ocean biogeochemistry models

    SciTech Connect (OSTI)

    Galbraith, Eric D.; Dunne, John P.; Gnanadesikan, Anand; Slater, Richard D.; Sarmiento, Jorge L.; Dufour, Carolina O.; de Souza, Gregory F.; Bianchi, Daniele; Claret, Mariona; Rodgers, Keith B.; Marvasti, Seyedehsafoura Sedigh

    2015-12-21

    Earth System Models increasingly include ocean biogeochemistry models in order to predict changes in ocean carbon storage, hypoxia, and biological productivity under climate change. However, state-of-the-art ocean biogeochemical models include many advected tracers, that significantly increase the computational resources required, forcing a trade-off with spatial resolution. Here, we compare a state-of the art model with 30 prognostic tracers (TOPAZ) with two reduced-tracer models, one with 6 tracers (BLING), and the other with 3 tracers (miniBLING). The reduced-tracer models employ parameterized, implicit biological functions, which nonetheless capture many of the most important processes resolved by TOPAZ. All three are embedded in the same coupled climate model. Despite the large difference in tracer number, the absence of tracers for living organic matter is shown to have a minimal impact on the transport of nutrient elements, and the three models produce similar mean annual preindustrial distributions of macronutrients, oxygen, and carbon. Significant differences do exist among the models, in particular the seasonal cycle of biomass and export production, but it does not appear that these are necessary consequences of the reduced tracer number. With increasing CO2, changes in dissolved oxygen and anthropogenic carbon uptake are very similar across the different models. Thus, while the reduced-tracer models do not explicitly resolve the diversity and internal dynamics of marine ecosystems, we demonstrate that such models are applicable to a broad suite of major biogeochemical concerns, including anthropogenic change. Lastly, these results are very promising for the further development and application of reduced-tracer biogeochemical models that incorporate ‘‘sub-ecosystem-scale’’ parameterizations.

  19. Nonlocal reactive transport with physical and chemical heterogeneity: Localization errors

    SciTech Connect (OSTI)

    Cushman, J.H.; Hu, B.X.; Deng, F.W.

    1995-09-01

    The origin of nonlocality in {open_quotes}macroscale{close_quotes} models for subsurface chemical transport is illustrated. It is argued that media that are either nonperiodic (e.g., media with evolving heterogeneity) or periodic viewed on a scale wherein a unit cell is discernible must display some nonlocality in the mean. A metaphysical argument suggests that owing to the scarcity of information on natural scales of heterogeneity and on scales of observation associated with an instrument window, constitutive theories for the mean concentration should at the outset of any modeling effort always be considered nonlocal. The intuitive appeal to nonlocality is reinforced with an analytical derivation of the constitutive theory for a conservative tracer without appeal to any mathematical approximations. Comparisons are made between the fully nonlocal (FNL), nonlocal in time (NLT), and fully localized (FL) theories. For conservative transport, there is little difference between the first-order FL and FNL models for spatial moments up to and including the third. However, for conservative transport the first-order NLT model differs significantly from the FNL model in the third spatial moments. For reactive transport, all spatial moments differ between the FNL and FL models. The second transverse-horizontal and third longitudinal-horizontal moments for the NLT model differ from the FNL model. These results suggest that localized first-order transport models for conservative tracers are reasonable if only lower-order moments are desired. However, when the chemical reacts with its environment, the localization approximation can lead to significant error in all moments, and a FNL model will in general be required for accurate simulation. 18 refs., 9 figs., 1 tab.

  20. Fossil power plant layup and reactivation

    SciTech Connect (OSTI)

    Tsou, J.L.

    1996-07-01

    In recent years, many utilities have developed excess generation capacity problems during period of low system load growth, particularly with new generation units coming on-line. System load studies may indicate that the situation is temporary and higher generation capacity will be needed in the near future. The objective of layup is to prevent component deterioration during the long shut down periods. This paper discusses equipment preservation practices in use in the industry and the advantages/disadvantages of various layup methods. Other issues related to plant layup and reactivation are also presented.

  1. Flash pyrolysis of biomass with reactive and non-reactive gases

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.

    1982-06-01

    The rapid or flash pyrolysis of wood biomass is being studied in a 1'' downflow entrained tubular reactor with a capacity of approximately 1 lb/hr of wood. The process chemistry data is being obtained with the view of building a data base and ascertaining the value of producing synthetic fuels and chemical feedstocks by the flash pyrolysis method. Data is being obtained on the effect of non-reactive pyrolyzing gases and the effect of reactive gases, hydrogen for the flash hydropyrolysis of wood and methane for flash methanolysis of wood. Preliminary process design and analysis has been made. The yield of ethylene and benzene is especially attractive for the production of chemical feedstocks from the reaction of methane and wood in a flash methanolysis process.

  2. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M.; Splitter, Derek A.; Kokjohn, Sage L.

    2015-07-14

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  3. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

    2013-12-31

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choose the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  4. Environmental Tracers for Determining Water Resource Vulnerability to Climate Change

    SciTech Connect (OSTI)

    Singleton, M

    2009-07-08

    Predicted changes in the climate will have profound impacts on water availability in the Western US, but large uncertainties exist in our ability to predict how natural and engineered hydrological systems will respond. Most predictions suggest that the impacts of climate change on California water resources are likely to include a decrease in the percentage of precipitation that falls as snow, earlier onset of snow-pack melting, and an increase in the number of rain on snow events. These processes will require changes in infrastructure for water storage and flood control, since much of our current water supply system is built around the storage of winter precipitation as mountain snow pack. Alpine aquifers play a critical role by storing and releasing snowmelt as baseflow to streams long after seasonal precipitation and the disappearance of the snow pack, and in this manner significantly impact the stream flow that drives our water distribution systems. Mountain groundwater recharge and, in particular, the contribution of snowmelt to recharge and baseflow, has been identified as a potentially significant effect missing from current climate change impact studies. The goal of this work is to understand the behavior of critical hydrologic systems, with an emphasis on providing ground truth for next generation models of climate-water system interactions by implementing LLNL capabilities in environmental tracer and isotopic science. We are using noble gas concentrations and multiple isotopic tracers ({sup 3}H/{sup 3}He, {sup 35}S, {sup 222}Rn, {sup 2}H/{sup 1}H, {sup 18}O/{sup 16}O, and {sup 13}C/{sup 12}C) in groundwater and stream water in a small alpine catchment to (1) provide a snapshot of temperature, altitude, and physical processes at the time of recharge, (2) determine subsurface residence times (over time scales ranging from months to decades) of different groundwater age components, and (3) deconvolve the contribution of these different groundwater components

  5. Predictions of tracer transport in interwell tracer tests at the C-Hole complex. Yucca Mountain site characterization project report milestone 4077

    SciTech Connect (OSTI)

    Reimus, P.W.

    1996-09-01

    This report presents predictions of tracer transport in interwell tracer tests that are to be conducted at the C-Hole complex at the Nevada Test Site on behalf of the Yucca Mountain Site Characterization Project. The predictions are used to make specific recommendations about the manner in which the tracer test should be conducted to best satisfy the needs of the Project. The objective of he tracer tests is to study flow and species transport under saturated conditions in the fractured tuffs near Yucca Mountain, Nevada, the site of a potential high-level nuclear waste repository. The potential repository will be located in the unsaturated zone within Yucca Mountain. The saturated zone beneath and around the mountain represents the final barrier to transport to the accessible environment that radionuclides will encounter if they breach the engineered barriers within the repository and the barriers to flow and transport provided by the unsaturated zone. Background information on the C-Holes is provided in Section 1.1, and the planned tracer testing program is discussed in Section 1.2.

  6. Gamma Survey of a Permeable Reactive Barrier at Monticello, Utah...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gamma Survey of a Permeable Reactive Barrier at Monticello, Utah Gamma Survey of a Permeable Reactive Barrier at Monticello, Utah Gamma Survey of a Permeable Reactive Barrier at...

  7. Tracers for monitoring the activity of sodium/glucose cotransporters in health and disease

    DOE Patents [OSTI]

    Wright, Ernest M; Barrio, Jorge R; Hirayama, Bruce A; Kepe, Vladimir

    2014-09-30

    Radiolabeled tracers for sodium/glucose cotransporters (SGLTs), their synthesis, and their use are provided. The tracers are methyl or ethyl pyranosides having an equatorial hydroxyl group at carbon-2 and a C 1 preferred conformation, radiolabeled with .sup.18F, .sup.123I, or .sup.124I, or free hexoses radiolabeled with .sup.18F, .sup.123I, or .sup.124. Also provided are in vivo and in vitro techniques for using these and other tracers as analytical and diagnostic tools to study glucose transport, in health and disease, and to evaluate therapeutic interventions.

  8. Tracer diffusion in compacted, water-saturated bentonite

    SciTech Connect (OSTI)

    Bourg, Ian C.; Sposito, Garrison; Bourg, Alain C.M.

    2005-08-04

    Compacted Na-bentonite clay barriers, widely used in theisolation of solid-waste landfills and other contaminated sites, havebeen proposed for a similar use in the disposal of high-level radioactivewaste. Molecular diffusion through the pore space in these barriers playsa key role in their performance, thus motivating recent measurements ofthe apparent diffusion coefficient tensor of water tracers in compacted,water-saturated Na-bentonites. In the present study, we introduce aconceptual model in which the pore space of water-saturated bentonite isdivided into 'macropore' and 'interlayer nanopore' compartments. Withthis model we determine quantitatively the relative contributions ofpore-network geometry (expressed as a geometric factor) and of thediffusive behavior of water molecules near montmorillonite basal surfaces(expressed as a contristivity factor) to the apparent diffusioncoefficient tensor. Our model predicts, in agreement with experiment,that the mean principal value of the apparent diffusion coefficienttensor follows a single relationship when plotted against the partialmontmorillonite dry density (mass of montmorillonite per combined volumeof montmorillonite and pore space). Using a single fitted parameter, themean principal geometric factor, our model successfully describes thisrelationship for a broad range of bentonite-water system, from dilute gelto highly-compacted bentonite with 80 percent of its pore water ininterlayer nanopores.

  9. Fuel temperature reactivity coefficient calculation by Monte Carlo perturbation techniques

    SciTech Connect (OSTI)

    Shim, H. J.; Kim, C. H.

    2013-07-01

    We present an efficient method to estimate the fuel temperature reactivity coefficient (FTC) by the Monte Carlo adjoint-weighted correlated sampling method. In this method, a fuel temperature change is regarded as variations of the microscopic cross sections and the temperature in the free gas model which is adopted to correct the asymptotic double differential scattering kernel. The effectiveness of the new method is examined through the continuous energy MC neutronics calculations for PWR pin cell problems. The isotope-wise and reaction-type-wise contributions to the FTCs are investigated for two free gas models - the constant scattering cross section model and the exact model. It is shown that the proposed method can efficiently predict the reactivity change due to the fuel temperature variation. (authors)

  10. Reactive composite compositions and mat barriers

    SciTech Connect (OSTI)

    Langton, Christine A.; Narasimhan, Rajendran; Karraker, David G.

    2001-01-01

    A hazardous material storage area has a reactive multi-layer composite mat which lines an opening into which a reactive backfill and hazardous material are placed. A water-inhibiting cap may cover the hazardous material storage area. The reactive multi-layer composite mat has a backing onto which is placed an active layer which will neutralize or stabilize hazardous waste and a fronting layer so that the active layer is between the fronting and backing layers. The reactive backfill has a reactive agent which can stabilize or neutralize hazardous material and inhibit the movement of the hazardous material through the hazardous material storage area.

  11. Plasma & reactive ion etching to prepare ohmic contacts

    DOE Patents [OSTI]

    Gessert, Timothy A.

    2002-01-01

    A method of making a low-resistance electrical contact between a metal and a layer of p-type CdTe surface by plasma etching and reactive ion etching comprising: a) placing a CdS/CdTe layer into a chamber and evacuating said chamber; b) backfilling the chamber with Argon or a reactive gas to a pressure sufficient for plasma ignition; and c) generating plasma ignition by energizing a cathode which is connected to a power supply to enable the plasma to interact argon ions alone or in the presence of a radio-frequency DC self-bias voltage with the p-CdTe surface.

  12. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  15. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  16. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  17. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  18. Development of Models to Simulate Tracer Behavior in Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Williams, Mark D.; Vermeul, Vincent R.; Reimus, P. W.; Newell, D.; Watson, Tom B.

    2010-06-01

    A recent report found that power and heat produced from engineered (or enhanced) geothermal systems (EGSs) could have a major impact on the United States while incurring minimal environmental impacts. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distributions, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for commercial development of geothermal energy. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. Modeling capabilities are being developed as part of this project to support laboratory and field testing to characterize engineered geothermal systems in single- and multi-well tests using tracers. The objective of this report is to describe the simulation plan and the status of model development for simulating tracer tests for characterizing EGS.

  19. 36Cl as a tracer in geothermal systems- Example from Valles Caldera...

    Open Energy Info (EERE)

    the use of chlorine-36 as a geothermal tracer. Authors F.M. Phillips, Fraser E. Goff, Francois D. Vuataz, H.W. Bentley and H.E. Gove Published Journal Geophysical Research...

  20. Apparatus for making environmentally stable reactive alloy powders

    DOE Patents [OSTI]

    Anderson, Iver E.; Lograsso, Barbara K.; Terpstra, Robert L.

    1996-12-31

    Apparatus and method for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment.

  1. Apparatus for making environmentally stable reactive alloy powders

    DOE Patents [OSTI]

    Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

    1996-12-31

    Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

  2. Urban Dispersion Program MSG05 Field Study: Summary of Tracer and Meteorological Measurements

    SciTech Connect (OSTI)

    Allwine, K Jerry; Flaherty, Julia E.

    2006-08-09

    The Urban Dispersion Program is a multi-year project, funded by the U.S. Department of Homeland Security, to better understand the flow and dispersion of airborne contaminants through and around the deep street canyons of New York City. The first tracer and meteorological field study was a limited study conducted during March 2005 near the Madison Square Garden in midtown Manhattan. Six safe, inert, gaseous perfluorocarbon tracers were released simultaneously at five street-level locations during two experimental days. In addition to collecting tracer data, meteorological data were also collected. Brookhaven National Laboratory conducted the bulk of the tracer and meteorological field efforts with Pacific Northwest National Laboratory and Stevens Institute of Technology assisting by measuring the vertical profile of winds. The Environmental Protection Agency worked with Brookhaven National Laboratory in accomplishing the personal exposure component of the study. This report presents some results from this analysis. In general, different release locations showed vastly different plume footprints for tracer materials, and the situation was made very complex with upwind and/or crosswind transport of tracer near street-level for the different release locations. Overall wind speeds and directions upwind and over the city were generally constant throughout each of the two experimental periods.

  3. Final report on isotope tracer investigations in the Forebay of the Orange County groundwater basin.

    SciTech Connect (OSTI)

    Davisson, M; Woodside, G

    2003-12-13

    directly measure groundwater ages and perform two artificial tracer studies using isotope methods to quantify flowpath directions, groundwater residence times, and the rate and extent of recharge water and groundwater mixing. In addition, Jordan Clark at University of California, Santa Barbara also performed an artificial tracer experiment using sulfur-hexafluoride, whose results have been integrated into the LLNL findings.

  4. Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain site characterization study. Progress report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Stetzenbach, K.; Farnham, I.

    1994-12-31

    The bromide anion has been used extensively as a tracer for mapping the flow of groundwater. It has proven to be both a safe and reliable groundwater tracer. The goal in this study is to find several tracing compounds with characteristics similar to the bromide anion to be used in multiple well tracing tests. Four groups of fluorinated organic acids were selected as candidates for groundwater tracers. These groups include fluorinated benzoic acids (FBA), fluorinated salicylic acids (FSA), fluorinated toluic acids (FTA), and fluorinated cinnamic acids (FCA). These compounds have been shown to move readily with the flow of water and do not adsorb to soil. They are also non-toxic. In this study, the retention of the fluorinated organic acids on to a soil column is compared to that of the bromide ion. The time required for the elution of each analyte from the soil column is measured using a UV-Vis detector. The soils consist of the light, medium, and dark tuffs used in the batch study. The work performed during this quarter consists of the continuation of the batch studies for the fluorinated benzoic acids and column studies for several potential tracer compounds.

  5. New Tracers of Gas Migration in the Continental Crust

    SciTech Connect (OSTI)

    Kurz, Mark D.

    2015-11-01

    Noble gases are exceptional tracers in continental settings due to the remarkable isotopic variability between the mantle, crust, and atmosphere, and because they are inert. Due to systematic variability in physical properties, such as diffusion, solubility, and production rates, the combination of helium, neon, and argon provides unique but under-utilized indices of gas migration. Existing noble gas data sets are dominated by measurements of gas and fluid phases from gas wells, ground waters and hot springs. There are very few noble gas measurements from the solid continental crust itself, which means that this important reservoir is poorly characterized. The central goal of this project was to enhance understanding of gas distribution and migration in the continental crust using new measurements of noble gases in whole rocks and minerals from existing continental drill cores, with an emphasis on helium, neon, argon. We carried out whole-rock and mineral-separate noble gas measurements on Precambrian basement samples from the Texas Panhandle. The Texas Panhandle gas field is the southern limb of the giant Hugoton-Panhandle oil and gas field; it has high helium contents (up to ~ 2 %) and 3He/4He of 0.21 (± 0.03) Ra. Because the total amount of helium in the Panhandle gas field is relatively well known, crustal isotopic data and mass balance calculations can be used to constrain the ultimate source rocks, and hence the helium migration paths. The new 3He/4He data range from 0.03 to 0.11 Ra (total), all of which are lower than the gas field values. There is internal isotopic heterogeneity in helium, neon, and argon, within all the samples; crushing extractions yield less radiogenic values than melting, demonstrating that fluid inclusions preserve less radiogenic gases. The new data suggest that the Precambrian basement has lost significant amounts of helium, and shows the importance of measuring helium with neon and argon. The 4He/40Ar values are particularly useful

  6. Interfacial Structure and Reactivity | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a robust, molecular-scale understanding of its structure and reactivity? Research Context The transport of ions across the electrodeelectrolyte interface can lead to kinetic...

  7. Shock Desensitization Experiments and Reactive Flow Modeling...

    Office of Scientific and Technical Information (OSTI)

    Shock Desensitization Experiments and Reactive Flow Modeling on Self-Sustaining LX-17 Detonation Waves Citation Details In-Document Search Title: Shock Desensitization Experiments ...

  8. Rejuvenating Permeable Reactive Barriers by Chemical Flushing

    Broader source: Energy.gov [DOE]

    Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

  9. Directional Reactive Power Ground Plane Transmission - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marketing SummaryORNL researchers have developed a pioneering power alternative to batteries using directional reactive power. Batteries are currently the primary option for...

  10. Systems and methods for forming defects on graphitic materials and curing radiation-damaged graphitic materials

    DOE Patents [OSTI]

    Ryu, Sunmin; Brus, Louis E.; Steigerwald, Michael L.; Liu, Haitao

    2012-09-25

    Systems and methods are disclosed herein for forming defects on graphitic materials. The methods for forming defects include applying a radiation reactive material on a graphitic material, irradiating the applied radiation reactive material to produce a reactive species, and permitting the reactive species to react with the graphitic material to form defects. Additionally, disclosed are methods for removing defects on graphitic materials.

  11. Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems

    SciTech Connect (OSTI)

    Reimus, Paul W

    2011-01-21

    The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

  12. Leak testing of bubble-tight dampers using tracer gas techniques

    SciTech Connect (OSTI)

    Lagus, P.L.; DuBois, L.J.; Fleming, K.M.

    1995-02-01

    Recently tracer gas techniques have been applied to the problem of measuring the leakage across an installed bubble-tight damper. A significant advantage of using a tracer gas technique is that quantitative leakage data are obtained under actual operating differential pressure conditions. Another advantage is that leakage data can be obtained using relatively simple test setups that utilize inexpensive materials without the need to tear ducts apart, fabricate expensive blank-off plates, and install test connections. Also, a tracer gas technique can be used to provide an accurate field evaluation of the performance of installed bubble-tight dampers on a periodic basis. Actual leakage flowrates were obtained at Zion Generating Station on four installed bubble-tight dampers using a tracer gas technique. Measured leakage rates ranged from 0.01 CFM to 21 CFM. After adjustment and subsequent retesting, the 21 CFM damper leakage was reduced to a leakage of 3.8 CFM. In light of the current regulatory climate and the interest in Control Room Habitability issues, imprecise estimates of critical air boundary leakage rates--such as through bubble-tight dampers--are not acceptable. These imprecise estimates can skew radioactive dose assessments as well as chemical contaminant exposure calculations. Using a tracer gas technique, the actual leakage rate can be determined. This knowledge eliminates a significant source of uncertainty in both radioactive dose and/or chemical exposure assessments.

  13. General Reactive Atomistic Simulation Program

    Energy Science and Technology Software Center (OSTI)

    2004-09-22

    GRASP (General Reactive Atomistic Simulation Program) is primarily intended as a molecular dynamics package for complex force fields, The code is designed to provide good performance for large systems, either in parallel or serial execution mode, The primary purpose of the code is to realistically represent the structural and dynamic properties of large number of atoms on timescales ranging from picoseconds up to a microsecond. Typically the atoms form a representative sample of some material,more » such as an interface between polycrystalline silicon and amorphous silica. GRASP differs from other parallel molecular dynamics codes primarily due to it’s ability to handle relatively complicated interaction potentials and it’s ability to use more than one interaction potential in a single simulation. Most of the computational effort goes into the calculation of interatomic forces, which depend in a complicated way on the positions of all the atoms. The forces are used to integrate the equations of motion forward in time using the so-called velocity Verlet integration scheme. Alternatively, the forces can be used to find a minimum energy configuration, in which case a modified steepest descent algorithm is used.« less

  14. Multiple-tracer tests for contaminant transport process identification in saturated municipal solid waste

    SciTech Connect (OSTI)

    Woodman, N.D. Rees-White, T.C.; Stringfellow, A.M.; Beaven, R.P.; Hudson, A.P.

    2015-04-15

    Highlights: • Multiple tracers were applied to saturated MSW to test dual-porosity properties. • Lithium demonstrated to be non-conservative as a tracer. • 260 mm diameter column too small to test transport properties of MSW. • The classical advection-dispersion mode was rejected due to high dispersivity. • Characteristic diffusion times did not vary with the tracer. - Abstract: Two column tests were performed in conditions emulating vertical flow beneath the leachate table in a biologically active landfill to determine dominant transport mechanisms occurring in landfills. An improved understanding of contaminant transport process in wastes is required for developing better predictions about potential length of the long term aftercare of landfills, currently measured in timescales of centuries. Three tracers (lithium, bromide and deuterium) were used. Lithium did not behave conservatively. Given that lithium has been used extensively for tracing in landfill wastes, the tracer itself and the findings of previous tests which assume that it has behaved conservatively may need revisiting. The smaller column test could not be fitted with continuum models, probably because the volume of waste was below a representative elemental volume. Modelling compared advection-dispersion (AD), dual porosity (DP) and hybrid AD–DP models. Of these models, the DP model was found to be the most suitable. Although there is good evidence to suggest that diffusion is an important transport mechanism, the breakthrough curves of the different tracers did not differ from each other as would be predicted based on the free-water diffusion coefficients. This suggested that solute diffusion in wastes requires further study.

  15. Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site

    SciTech Connect (OSTI)

    MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

    2000-08-01

    This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

  16. Estimation of Fracture Porosity in an Unsaturated Fractured Welded Tuff Using Gas Tracer Testing

    SciTech Connect (OSTI)

    B.M. Freifeild

    2001-10-18

    Kinematic fracture porosity is an important hydrologic transport parameter for predicting the potential of rapid contaminant migration through fractured rock. The transport velocity of a solute moving within a fracture network is inversely related to the fracture porosity. Since fracture porosity is often one or two orders of magnitude smaller than matrix porosity, and fracture permeability is often orders of magnitude greater than matrix permeability, solutes may travel significantly faster in the fracture network than in the surrounding matrix. This dissertation introduces a new methodology for conducting gas tracer tests using a field portable mass spectrometer along with analytical tools for estimating fracture porosity using the measured tracer concentration breakthrough curves. Field experiments were conducted at Yucca Mountain, Nevada, consisting of air-permeability transient testing and gas-tracer-transport tests. The experiments were conducted from boreholes drilled within an underground tunnel as part of an investigation of rock mass hydrological behavior. Air-permeability pressure transients, recorded during constant mass flux injections, have been analyzed using a numerical inversion procedure to identify fracture permeability and porosity. Dipole gas tracer tests have also been conducted from the same boreholes used for air-permeability testing. Mass breakthrough data has been analyzed using a random walk particle-tracking model, with a dispersivity that is a function of the advective velocity. The estimated fracture porosity using the tracer test and air-injection test data ranges from .001 to .015. These values are an order of magnitude greater than the values estimated by others using hydraulically estimated fracture apertures. The estimates of porosity made using air-permeability test data are shown to be highly sensitive to formation heterogeneity. Uncertainty analyses performed on the gas tracer test results show high confidence in the parameter

  17. Image reconstruction in higher dimensions: myocardial perfusion imaging of tracer dynamics with cardiac motion due to deformation and respiration

    SciTech Connect (OSTI)

    Shrestha, Uttam M.; Seo, Youngho; Botvinick, Elias H.; Gullberg, Grant T.

    2015-10-09

    Myocardial perfusion imaging (MPI) using slow rotating large field of view cameras requires spatiotemporal reconstruction of dynamically acquired data to capture the time variation of the radiotracer concentration. In vivo, MPI contains additional degrees of freedom involving unavoidable motion of the heart due to quasiperiodic beating and the effects of respiration, which can severely degrade the quality of the images. This work develops a technique for a single photon emission computed tomography (SPECT) that reconstructs the distribution of the radiotracer concentration in the myocardium using a tensor product of different sets of basis functions that approximately describe the spatiotemporal variation of the radiotracer concentration and the motion of the heart. In this study the temporal B-spline basis functions are chosen to reflect the dynamics of the radiotracer, while the intrinsic deformation and the extrinsic motion of the heart are described by a product of a discrete set of Gaussian basis functions. Reconstruction results are presented showing the dynamics of the tracer in the myocardium as it deforms due to cardiac beating, and is displaced due to respiratory motion. We find these results are compared with the conventional 4D-spatiotemporal reconstruction method that models only the temporal changes of the tracer activity. The higher dimensional reconstruction method proposed here improves bias, yet the signal-to-noise ratio (SNR) decreases slightly due to redistribution of the counts over the cardiac-respiratory gates. Additionally, there is a trade-off between the number of gates and the number of projections per gate to achieve high contrast images.

  18. Image reconstruction in higher dimensions: myocardial perfusion imaging of tracer dynamics with cardiac motion due to deformation and respiration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shrestha, Uttam M.; Seo, Youngho; Botvinick, Elias H.; Gullberg, Grant T.

    2015-10-09

    Myocardial perfusion imaging (MPI) using slow rotating large field of view cameras requires spatiotemporal reconstruction of dynamically acquired data to capture the time variation of the radiotracer concentration. In vivo, MPI contains additional degrees of freedom involving unavoidable motion of the heart due to quasiperiodic beating and the effects of respiration, which can severely degrade the quality of the images. This work develops a technique for a single photon emission computed tomography (SPECT) that reconstructs the distribution of the radiotracer concentration in the myocardium using a tensor product of different sets of basis functions that approximately describe the spatiotemporal variationmore » of the radiotracer concentration and the motion of the heart. In this study the temporal B-spline basis functions are chosen to reflect the dynamics of the radiotracer, while the intrinsic deformation and the extrinsic motion of the heart are described by a product of a discrete set of Gaussian basis functions. Reconstruction results are presented showing the dynamics of the tracer in the myocardium as it deforms due to cardiac beating, and is displaced due to respiratory motion. We find these results are compared with the conventional 4D-spatiotemporal reconstruction method that models only the temporal changes of the tracer activity. The higher dimensional reconstruction method proposed here improves bias, yet the signal-to-noise ratio (SNR) decreases slightly due to redistribution of the counts over the cardiac-respiratory gates. Additionally, there is a trade-off between the number of gates and the number of projections per gate to achieve high contrast images.« less

  19. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  20. Generalized chloride mass balance: Forward and inverse solutions for one-dimensional tracer convection under transient flux

    SciTech Connect (OSTI)

    Ginn, T.R.; Murphy, E.M.

    1996-12-01

    Forward and inverse solutions are provided for analysis of inert tracer profiles resulting from one-dimensional convective transport under fluxes which vary with time and space separately. The developments are displayed as an extension of conventional chloride mass balance (CMB) techniques to account for transient as well as space-dependent water fluxes. The conventional chloride mass balance has been used over two decades to estimate recharge over large time scales in arid environments. In this mass balance approach, the chloride concentration in the pore water, originating from atmospheric fallout, is inversely proportional to the flux of water through the sediments. The CMB method is especially applicable to arid and semi-arid regions where evapotranspirative enrichment of the pore water produces a distinct chloride profile in the unsaturated zone. The solutions presented allow incorporation of transient fluxes and boundary conditions in CMB analysis, and allow analysis of tracer profile data which is not constant with depth below extraction zone in terms of a rational water transport model. A closed-form inverse solution is derived which shows uniqueness of model parameter and boundary condition (including paleoprecipitation) estimation, for the specified flow model. Recent expressions of the conventional chloride mass balance technique are derived from the general model presented here; the conventional CMB is shown to be fully compatible with this transient flow model and it requires the steady-state assumption on chloride mass deposition only (and not on water fluxes or boundary conditions). The solutions and results are demonstrated on chloride profile data from west central New Mexico.

  1. Reactivity of perovskites with water: Role of hydroxylation in...

    Office of Scientific and Technical Information (OSTI)

    Reactivity of perovskites with water: Role of hydroxylation in wetting and implications ... Title: Reactivity of perovskites with water: Role of hydroxylation in wetting and ...

  2. Experimental Evidence for Self-Limiting Reactive Flow through...

    Office of Scientific and Technical Information (OSTI)

    Experimental Evidence for Self-Limiting Reactive Flow through a Fractured Cement Core: ... Title: Experimental Evidence for Self-Limiting Reactive Flow through a Fractured Cement ...

  3. The Reactivity of Energetic Materials Under High Pressure and...

    Office of Scientific and Technical Information (OSTI)

    The Reactivity of Energetic Materials Under High Pressure and Temperature Citation Details In-Document Search Title: The Reactivity of Energetic Materials Under High Pressure and ...

  4. Inducing and Quantifying Forbidden Reactivity with Single Molecule...

    Office of Scientific and Technical Information (OSTI)

    Inducing and Quantifying Forbidden Reactivity with Single Molecule Polymer Mechanochemistry Citation Details In-Document Search Title: Inducing and Quantifying Forbidden Reactivity ...

  5. Chemical Imaging and Dynamical Studies of Reactivity and Emergent...

    Office of Scientific and Technical Information (OSTI)

    Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior in Complex ... Title: Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior in ...

  6. Reactivity of Ozone with Solid Potassium Iodide Investigated...

    Office of Scientific and Technical Information (OSTI)

    Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy Citation Details In-Document Search Title: Reactivity of Ozone with Solid Potassium...

  7. Modeling of fault reactivation and induced seismicity during...

    Office of Scientific and Technical Information (OSTI)

    Modeling of fault reactivation and induced seismicity during hydraulic fracturing of shale-gas reservoirs Citation Details In-Document Search Title: Modeling of fault reactivation ...

  8. Investigation of long term reactive stability of ceria for use...

    Office of Scientific and Technical Information (OSTI)

    reactive stability of ceria for use in solar thermochemical cycles This content will ... reactive stability of ceria for use in solar thermochemical cycles Authors: Rhodes, ...

  9. Reactivity control assembly for nuclear reactor

    DOE Patents [OSTI]

    Bollinger, Lawrence R.

    1984-01-01

    Reactivity control assembly for nuclear reactor comprises supports stacked above reactor core for holding control rods. Couplers associated with the supports and a vertically movable drive shaft have lugs at their lower ends for engagement with the supports.

  10. Mild coal pretreatment to improve liquefaction reactivity

    SciTech Connect (OSTI)

    Miller, R.L.

    1991-01-01

    This report describes work completed during the fourth quarter of a three year project to study the effects of mild chemical pretreatment on coal dissolution reactivity during low severity liquefaction or coal/oil coprocessing. The overall objective of this research is to elucidate changes in the chemical and physical structure of coal by pretreating with methanol or other simple organic solvent and a trace amount of hydrochloric acid and measure the influence of these changes on coal dissolution reactivity. This work is part of a larger effort to develop a new coal liquefaction or coal/oil coprocessing scheme consisting of three main process steps: (1) mile pretreatment of the feed coal to enhance dissolution reactivity and dry the coal, (2) low severity thermal dissolution of the pretreated coal to obtain a very reactive coal-derived residual material amenable to upgrading, and (3) catalytic upgrading of the residual products to distillate liquids.

  11. A Tariff for Reactive Power - IEEE

    SciTech Connect (OSTI)

    Kueck, John D; Tufon, Christopher; Isemonger, Alan; Kirby, Brendan J

    2008-11-01

    This paper describes a suggested tariff or payment for the local supply of reactive power from distributed energy resources. The authors consider four sample customers, and estimate the cost of supply of reactive power for each customer. The power system savings from the local supply of reactive power are also estimated for a hypothetical circuit. It is found that reactive power for local voltage regulation could be supplied to the distribution system economically by customers when new inverters are installed. The inverter would be supplied with a power factor of 0.8, and would be capable of local voltage regulation to a schedule supplied by the utility. Inverters are now installed with photovoltaic systems, fuel cells and microturbines, and adjustable-speed motor drives.

  12. Reactivity control mechanisms for a HPLWR fuel assembly

    SciTech Connect (OSTI)

    Schlagenhaufer, Marc; Schulenberg, Thomas; Vogt, Bastian

    2007-07-01

    A parametric study of different reactivity control mechanisms has been performed for the cross section of a single fuel assembly of a High Performance Light Water Reactor using the Monte Carlo code MCNP5. The fuel temperature feedback, known as the Doppler Effect, and the coolant density feedback have been determined for fresh UO{sub 2} fuel in a large range of fuel and coolant temperatures. The local shutdown reactivity of different control rods with different absorber materials has been predicted. The neutron flux inside the control rods, the power profile in the fuel pins with and without control rods and the coolant density coefficient have been evaluated for future core optimization. Methods to improve the power profile with additional absorbers mounted outside the fuel cluster have been studied exemplarily. (authors)

  13. Reactive multilayer synthesis of hard ceramic foils and films

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Holt, Joseph B. (San Jose, CA)

    1996-01-01

    A method for synthesizing hard ceramic materials such as carbides, borides nd aluminides, particularly in the form of coatings provided on another material so as to improve the wear and abrasion performance of machine tools, for example. The method involves the sputter deposition of alternating layers of reactive metals with layers of carbon, boron, or aluminum and the subsequent reaction of the multilayered structure to produce a dense crystalline ceramic. The material can be coated on a substrate or formed as a foil which can be coild as a tape for later use.

  14. Assessment of Controlling Processes for Field-Scale Uranium Reactive Transport under Highly Transient Flow Conditions

    SciTech Connect (OSTI)

    Ma, Rui; Zheng, Chunmiao; Liu, Chongxuan; Greskowiak, Janek; Prommer, Henning; Zachara, John M.

    2014-02-13

    This paper presents the results of a comprehensive model-based analysis of a uranium tracer test conducted at the U.S Department of Energy Hanford 300 Area (300A) IFRC site. A three-dimensional multi-component reactive transport model was employed to assess the key factors and processes that control the field-scale uranium reactive transport. Taking into consideration of relevant physical and chemical processes, the selected conceptual/numerical model replicates the spatial and temporal variations of the observed U(VI) concentrations reasonably well in spite of the highly complex field conditions. A sensitivity analysis was performed to interrogate the relative importance of various processes and factors for reactive transport of U(VI) at the field-scale. The results indicate that multi-rate U(VI) sorption/desorption, U(VI) surface complexation reactions, and initial U(VI) concentrations were the most important processes and factors controlling U(VI) migration. On the other hand, cation exchange reactions, the choice of the surface complexation model, and dual-domain mass transfer processes, which were previously identified to be important in laboratory experiments, played less important roles under the field-scale experimental condition at the 300A site. However, the model simulations also revealed that the groundwater chemistry was relatively stable during the uranium tracer experiment and therefore presumably not dynamic enough to appropriately assess the effects of ion exchange reaction and the choice of surface complexation models on U(VI) sorption and desorption. Furthermore, it also showed that the field experimental duration (16 days) was not sufficiently long to precisely assess the role of a majority of the sorption sites that were accessed by slow kinetic processes within the dual domain model. The sensitivity analysis revealed the crucial role of the intraborehole flow that occurred within the long-screened monitoring wells and thus significantly

  15. EPA/ITRC-RTDF permeable reactive barrier short course. Permeable reactive barriers: Application and deployment

    SciTech Connect (OSTI)

    Not Available

    1999-01-01

    This report focuses on the following: Permeable Reactive Barriers: Application and Deployment; Introduction to Permeable Reactive Barriers (PRBs) for Remediating and Managing Contaminated Groundwater in Situ; Collection and Interpretation of Design Data 1: Site Characterization for PRBs; Reactive Materials: Zero-Valent Iron; Collection and Interpretation of Design Data 2: Laboratory and Pilot Scale Tests; Design Calculations; Compliance Monitoring, Performance Monitoring and Long-Term Maintenance for PRBs; PRB Emplacement Techniques; PRB Permitting and Implementation; Treatment of Metals; Non-Metallic Reactive Materials; Economic Considerations for PRB Deployment; and Bibliography.

  16. EPA/ITRC-RTDF permeable reactive barrier short course. Permeable reactive barriers: Application and deployment

    SciTech Connect (OSTI)

    1999-11-01

    This report focuses on the following: Permeable Reactive Barriers: Application and Deployment; Introduction to Permeable Reactive Barriers (PRBs) for Remediating and Managing Contaminated Groundwater in Situ; Collection and Interpretation of Design Data 1: Site Characterization for PRBs; Reactive Materials: Zero-Valent Iron; Collection and Interpretation of Design Data 2: Laboratory and Pilot Scale Tests; Design Calculations; Compliance Monitoring, Performance Monitoring and Long-Term Maintenance for PRBs; PRB Emplacement Techniques; PRB Permitting and Implementation; Treatment of Metals; Non-Metallic Reactive Materials; Economic Considerations for PRB Deployment; and Bibliography.

  17. Fracture Evolution Following a Hydraulic Stimulation within an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fracture Evolution Following a Hydraulic Stimulation within an EGS Reservoir Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal ...

  18. Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kulkarni, Nagraj S.; Bruce Warmack, Robert J.; Radhakrishnan, Bala; Hunter, Jerry L.; Sohn, Yongho; Coffey, Kevin R.; Murch, Graeme E.; Belova, Irina V.

    2014-09-23

    Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-highmore » vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) was found to be a good representation of both types of diffusion data that cover a broad range of temperatures between 250 - 627° C (523 900 K).« less

  19. Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion

    SciTech Connect (OSTI)

    Kulkarni, Nagraj S.; Bruce Warmack, Robert J.; Radhakrishnan, Bala; Hunter, Jerry L.; Sohn, Yongho; Coffey, Kevin R.; Murch, Graeme E.; Belova, Irina V.

    2014-09-23

    Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-high vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) was found to be a good representation of both types of diffusion data that cover a broad range of temperatures between 250 - 627° C (523 900 K).

  20. Reactivation of landslides by surface subsidence from longwall mining

    SciTech Connect (OSTI)

    Iannacchione, A.T.; Ackman, T.E.

    1984-12-01

    Subsidence research by the US Bureau of Mines has identified and documented the occurrence of landslides over a longwall mining area in the Dunkard basin. Mining by longwall methods has been observed or produce a gradual surface subsidence profile of up to 60% of the thickness of the mined coal bed. The gradual subsidence of panels averaging 600 x 5000 ft (180 x 1525 m) can cause reactivation of older landslide deposits by decreasing the support to the landslide toe area. Examination of surficial features over a longwall mining area comprised of nine panels has led to the identification of several reactivated landslides. The two largest landslides occurred above a thin sandstone member with several associated springs. The largest landslides ranged from 100 to 300 ft (30 to 90 m) in length and from 100 to 200 ft (30 to 60 m) in width. Maximum scarp-slope displacements were approximately 7 ft (2 m). Less significant mass wasting was also observed over the longwall panels. Identification of landslides was accomplished through examination of premining aerial photographs and geologic field investigation. Characterization of reactivated zones was achieved through evaluation of current aerial 2-ft (0.6-m) surface contour map and field surveys. Recognition of problem areas will make civic and mining personnel aware of the landslide potential so that damage in such areas can be minimized.

  1. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential

  2. Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel

    DOE Patents [OSTI]

    Herrmann, Steven Douglas

    2014-05-27

    Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

  3. Effects of CT-based attenuation correction of rat microSPECT images on relative myocardial perfusion and quantitative tracer uptake

    SciTech Connect (OSTI)

    Strydhorst, Jared H. Ruddy, Terrence D.; Wells, R. Glenn

    2015-04-15

    Purpose: Our goal in this work was to investigate the impact of CT-based attenuation correction on measurements of rat myocardial perfusion with {sup 99m}Tc and {sup 201}Tl single photon emission computed tomography (SPECT). Methods: Eight male Sprague-Dawley rats were injected with {sup 99m}Tc-tetrofosmin and scanned in a small animal pinhole SPECT/CT scanner. Scans were repeated weekly over a period of 5 weeks. Eight additional rats were injected with {sup 201}Tl and also scanned following a similar protocol. The images were reconstructed with and without attenuation correction, and the relative perfusion was analyzed with the commercial cardiac analysis software. The absolute uptake of {sup 99m}Tc in the heart was also quantified with and without attenuation correction. Results: For {sup 99m}Tc imaging, relative segmental perfusion changed by up to +2.1%/−1.8% as a result of attenuation correction. Relative changes of +3.6%/−1.0% were observed for the {sup 201}Tl images. Interscan and inter-rat reproducibilities of relative segmental perfusion were 2.7% and 3.9%, respectively, for the uncorrected {sup 99m}Tc scans, and 3.6% and 4.3%, respectively, for the {sup 201}Tl scans, and were not significantly affected by attenuation correction for either tracer. Attenuation correction also significantly increased the measured absolute uptake of tetrofosmin and significantly altered the relationship between the rat weight and tracer uptake. Conclusions: Our results show that attenuation correction has a small but statistically significant impact on the relative perfusion measurements in some segments of the heart and does not adversely affect reproducibility. Attenuation correction had a small but statistically significant impact on measured absolute tracer uptake.

  4. Quantitative measurement of binary liquid distributions using multiple-tracer x-ray fluorescence and radiography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Halls, Benjamin R.; Meyer, Terrence R.; Kastengren, Alan L.

    2015-01-23

    The complex geometry and large index-of-refraction gradients that occur near the point of impingement of binary liquid jets present a challenging environment for optical interrogation. A simultaneous quadruple-tracer x-ray fluorescence and line-of-sight radiography technique is proposed as a means of distinguishing and quantifying individual liquid component distributions prior to, during, and after jet impact. Two different pairs of fluorescence tracers are seeded into each liquid stream to maximize their attenuation ratio for reabsorption correction and differentiation of the two fluids during mixing. This approach for instantaneous correction of x-ray fluorescence reabsorption is compared with a more time-intensive approach of usingmorestereographic reconstruction of x-ray attenuation along multiple lines of sight. The proposed methodology addresses the need for a quantitative measurement technique capable of interrogating optically complex, near-field liquid distributions in many mixing systems of practical interest involving two or more liquid streams.less

  5. Quantitative measurement of binary liquid distributions using multiple-tracer x-ray fluorescence and radiography

    SciTech Connect (OSTI)

    Halls, Benjamin R.; Meyer, Terrence R.; Kastengren, Alan L.

    2015-01-01

    The complex geometry and large index-of-refraction gradients that occur near the point of impingement of binary liquid jets present a challenging environment for optical interrogation. A simultaneous quadruple-tracer x-ray fluorescence and line-of-sight radiography technique is proposed as a means of distinguishing and quantifying individual liquid component distributions prior to, during, and after jet impact. Two different pairs of fluorescence tracers are seeded into each liquid stream to maximize their attenuation ratio for reabsorption correction and differentiation of the two fluids during mixing. This approach for instantaneous correction of x-ray fluorescence reabsorption is compared with a more time-intensive approach of using stereographic reconstruction of x-ray attenuation along multiple lines of sight. The proposed methodology addresses the need for a quantitative measurement technique capable of interrogating optically complex, near-field liquid distributions in many mixing systems of practical interest involving two or more liquid streams.

  6. Rotanone analogs: method of preparation and use

    DOE Patents [OSTI]

    2013-10-08

    The present invention provides rotenone analogs and methods of making and using them. Labeled with single photon and positron emitting isotopes, the rotenone analogs of the present invention are useful in, for example, clinical imaging applications as tracers to measure cardiac blood flow and detect regions of ischemia.

  7. Nuclear engine flow reactivity shim control

    DOE Patents [OSTI]

    Walsh, J.M.

    1973-12-11

    A nuclear engine control system is provided which automatically compensates for reactor reactivity uncertainties at the start of life and reactivity losses due to core corrosion during the reactor life in gas-cooled reactors. The coolant gas flow is varied automatically by means of specially provided control apparatus so that the reactor control drums maintain a predetermined steady state position throughout the reactor life. This permits the reactor to be designed for a constant drum position and results in a desirable, relatively flat temperature profile across the core. (Official Gazette)

  8. REAL-TIME TRACER MONITORING OF RESERVOIR STIMULATION PROCEDURES VIA ELECTRONIC WIRELINE AND TELEMETRY DATA TRANSMISSION

    SciTech Connect (OSTI)

    George Scott III

    2003-08-01

    Ongoing Phase 2-3 work comprises the final development and field-testing of two complementary real-time reservoir technologies; a stimulation process and a tracer fracturing diagnostic system. Initial DE-FC26-99FT40129 project work included research, development, and testing of the patented gamma tracer fracturing diagnostic system. This process was field-proven to be technically useful in providing tracer measurement of fracture height while fracturing; however, technical licensing restrictions blocked Realtimezone from fully field-testing this real-time gamma diagnostic system, as originally planned. Said restrictions were encountered during Phase 2 field test work as result of licensing limitations and potential conflicts between service companies participating in project work, as related to their gamma tracer logging tool technology. Phase 3 work principally demonstrated field-testing of Realtimezone (RTZ) and NETL's Downhole-mixed Reservoir Stimulation process. Early on, the simplicity of and success of downhole-mixing was evident from well tests, which were made commercially productive. A downhole-mixed acid stimulation process was tested successfully and is currently commercially used in Canada. The fourth well test was aborted due to well bore conditions, and an alternate test project is scheduled April, 2004. Realtimezone continues to effectuate ongoing patent protection in the United States and foreign markets. In 2002, Realtimezone and the NETL licensed their United States patent to Halliburton Energy Services (HES). Additional licensing arrangements with other industry companies are anticipated in 2004-2005. Ongoing Phase 2 and Phase 3 field-testing continues to confirm applications of both real-time technologies. Technical data transfer to industry is ongoing via Internet tech-transfer and various industry presentations and publications including Society of Petroleum Engineers. These real-time enhanced stimulation procedures should significantly

  9. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D.; Downs, William; Jankura, Bryan J.; McCoury, Jr., John M.

    1990-01-01

    An apparatus and method for sampling gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extends in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  10. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D.; Downs, William; Jankura, Bryan J.; McCoury, Jr., John M.

    1989-01-01

    An apparatus and method for sampling a gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extend in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  11. Perspective on fossil power plant layup and reactivation

    SciTech Connect (OSTI)

    Tsou, J.L.

    1996-12-31

    In recent years, many utilities have developed excess generation capacity problems during period of low system load growth, particularly with new generation units coming on-line. System load studies may indicate that the situation is temporary and higher generation capacity will be needed in the near future. The objective of layup is to prevent component deterioration during the long shut down periods. This paper discusses equipment preservation practices in use by the electric utility industry and the advantages/disadvantages of various layup methods. Other issues related to plant layup and reactivation are also presented.

  12. Field studies of streamflow generation using natural and injected tracers on Bickford and Walker Branch Watersheds

    SciTech Connect (OSTI)

    Genereux, D.; Hemond, H. . Dept. of Civil Engineering); Mulholland, P. )

    1992-05-01

    Field studies of streamflow generation were undertaken on two forested watersheds, the West Road subcatchment of Bickford Watershed in central Massachusetts and the West Fork of Walker Branch Watershed in eastern Tennessee. A major component of the research was development of a two-stage methodology for the use of naturally-occurring {sup 222}Rn as a tracer. The first of the two stages was solving a mass-balance equation for {sup 222}Rn around a stream reach of interest in order to calculate Rn{sub q}, the {sup 222}Rn content of the lateral inflow to the reach; a conservative tracer (chloride) and a volatile tracer (propane) were injected into the study stream to account for lateral inflow to, and volatilization from, the study reach. The second stage involved quantitative comparison of Rn{sub q} to the measured {sup 222}Rn concentrations of different subsurface waters in order to assess how important these waters were in contributing lateral inflow to the stream reach.

  13. Mass transport parameters of aspen wood chip beds via stimulus-response tracer techniques

    SciTech Connect (OSTI)

    Hradil, G.; Calo, J.M.; Wunderlich, T.K. Jr. )

    1993-02-05

    A stimulus-response tracer technique has been used to characterize packed beds of untreated, as well as acid prehydrolyzed, and enzymatically hydrolyzed aspen wood chips. Glucose was used as the trace. Bulk liquid phase dispersion, interphase mass transfer, and intraparticle diffusion coefficients were determined for these materials as well as effective porosities and tortuosities. The untreated and prehydrolyzed aspen wood chips were found to have effective void fractions of ca. 0.8, while the enzymatically hydrolyzed wood chips exhibited a void fraction of 0.37. Intraparticle diffusion was approximately twice as rapid in the prehydrolyzed and enzymatically hydrolyzed wood chips as in the untreated wood chips. Also, under the current experimental conditions, intraparticle diffusional transport resistance accounted for roughly half of the total tracer pulse dispersion. It is demonstrated that stimulus-response tracer techniques can be useful and convenient probes for beds of lignocellulosic, or other porous materials, which vary in character with extent of conversion and/or treatment.

  14. Characterization of a real-time tracer for Isoprene Epoxydiols-derived Secondary Organic Aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, W. W.; Campuzano-Jost, P.; Palm, B. B.; Day, D. A.; Ortega, A. M.; Hayes, P. L.; Krechmer, J. E.; Chen, Q.; Kuwata, M.; Liu, Y. J.; et al

    2015-04-16

    from isoprene. We introduce a graphical diagnostic to study the presence and aging of IEPOX-SOA as a "triangle plot" of fCO2 vs. fC5H6O. Finally, we develop a simplified method to estimate ambient IEPOX-SOA mass concentrations, which is shown to perform well compared to the full PMF method. The uncertainty of the tracer method is up to a factor of ~ 2 if the fC5H6O of the local IEPOX-SOA is not available. When only unit mass resolution data is available, as with the aerosol chemical speciation monitor (ACSM), all methods may perform less well because of increased interferences from other ions at m/z 82. This study clarifies the strengths and limitations of the different AMS methods for detection of IEPOX-SOA and will enable improved characterization of this OA component.« less

  15. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    SciTech Connect (OSTI)

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injection strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still significant

  16. 100-NR-2 Apatite Treatability Test: Fall 2010 Tracer Infiltration Test (White Paper)

    SciTech Connect (OSTI)

    Vermeul, Vincent R.; Fritz, Brad G.; Fruchter, Jonathan S.; Greenwood, William J.; Johnson, Timothy C.; Horner, Jacob A.; Strickland, Christopher E.; Szecsody, James E.; Williams, Mark D.

    2011-04-14

    The primary objectives of the tracer infiltration test were to 1) determine whether field-scale hydraulic properties for the compacted roadbed materials and underlying Hanford fm. sediments comprising the zone of water table fluctuation beneath the site are consistent with estimates based laboratory-scale measurements on core samples and 2) characterize wetting front advancement and distribution of soil moisture achieved for the selected application rate. These primary objectives were met. The test successfully demonstrated that 1) the remaining 2 to 3 ft of compacted roadbed material below the infiltration gallery does not limit infiltration rates to levels that would be expected to eliminate near surface application as a viable amendment delivery approach and 2) the combined aqueous and geophysical monitoring approaches employed at this site, with some operational adjustments based on lessons learned, provides an effective means of assessing wetting front advancement and the distribution of soil moisture achieved for a given solution application. Reasonably good agreement between predicted and observed tracer and moisture front advancement rates was observed. During the first tracer infiltration test, which used a solution application rate of 0.7 cm/hr, tracer arrivals were observed at the water table (10 to 12 ft below the bottom of the infiltration gallery) after approximately 5 days, for an advancement rate of approximately 2 ft/day. This advancement rate is generally consistent with pre-test modeling results that predicted tracer arrival at the water table after approximately 5 days (see Figure 8, bottom left panel). This agreement indicates that hydraulic property values specified in the model for the compacted roadbed materials and underlying Hanford formation sediments, which were based on laboratory-scale measurements, are reasonable estimates of actual field-scale conditions. Additional work is needed to develop a working relationship between resistivity

  17. Neutron Radiography Reactor Reactivity -- Focused Lessons Learned

    SciTech Connect (OSTI)

    Eric Woolstenhulme; Randal Damiana; Kenneth Schreck; Ann Marie Phillips; Dana Hewit

    2010-11-01

    As part of the Global Threat Reduction Initiative, the Neutron Radiography Reactor (NRAD) at the Idaho National Laboratory (INL) was converted from using highly enriched uranium (HEU) to low enriched uranium (LEU) fuel. After the conversion, NRAD resumed operations and is meeting operational requirements. Radiography image quality and the number of images that can be produced in a given time frame match pre-conversion capabilities. However, following the conversion, NRADs excess reactivity with the LEU fuel was less than it had been with the HEU fuel. Although some differences between model predictions and actual performance are to be expected, the lack of flexibility in NRADs safety documentation prevented adjusting the reactivity by adding more fuel, until the safety documentation could be modified. To aid future reactor conversions, a reactivity-focused Lessons Learned meeting was held. This report summarizes the findings of the lessons learned meeting and addresses specific questions posed by DOE regarding NRADs conversion and reactivity.

  18. Wet oxidation of high-concentration reactive dyes

    SciTech Connect (OSTI)

    Chen, G.; Lei, L.; Yue, P.L.

    1999-05-01

    Advanced oxidation methods were used to degrade reactive dyes at high concentrations in aqueous solutions. Wet peroxide oxidation (WPO) was found to be the best method in terms of the removal of color and total organic carbon (TOC). Reactive blue (Basilen Brilliant Blue P-3R) was chosen as a model dye for determining the suitable reaction conditions. The variables studied include reaction temperature, H{sub 2}O{sub 2} dosage, solution pH, dye concentration, and catalyst usage. The removal of TOC and color by wet oxidation is very sensitive to the reaction temperature. At 150 C, the removal of 77% TOC and 90% color was obtained in less than 30 min. The initial TOC removal rate is proportional to the H{sub 2}O{sub 2} dosage. The TOC removal is insignificant even when 50% of the stoichiometric amount of H{sub 2}O{sub 2} is used. No color change is observed until the dosage of H{sub 2}O{sub 2} is 100% of the stoichiometric amount. The color removal is closely related to TOC removal. When the pH of the solution is adjusted to 3.5, the dye degradation rate increases significantly. The rates of TOC and color removal are enhanced by using a Cu{sup 2+} catalyst. Another four reactive dyes, Procion Red PX-4B, Cibacron Yellow P-6GS, Cibacron Brown P-6R, and Procion Black PX-2R, were treated at 150 C using WPO. More than 80% TOC was removed from the solution in less than 15 min. The process can remove the colors of al these dyes except Procion Black PX-2R.

  19. ALPHA SPECTROMETRIC EVALUATION OF SRM-995 AS A POTENTIAL URANIUM/THORIUM DOUBLE TRACER SYSTEM FOR AGE-DATING URANIUM MATERIALS

    SciTech Connect (OSTI)

    Beals, D.

    2011-12-06

    Uranium-233 (t{sub 1/2} {approx} 1.59E5 years) is an artificial, fissile isotope of uranium that has significant importance in nuclear forensics. The isotope provides a unique signature in determining the origin and provenance of uranium-bearing materials and is valuable as a mass spectrometric tracer. Alpha spectrometry was employed in the critical evaluation of a {sup 233}U standard reference material (SRM-995) as a dual tracer system based on the in-growth of {sup 229}Th (t{sub 1/2} {approx} 7.34E3 years) for {approx}35 years following radiochemical purification. Preliminary investigations focused on the isotopic analysis of standards and unmodified fractions of SRM-995; all samples were separated and purified using a multi-column anion-exchange scheme. The {sup 229}Th/{sup 233}U atom ratio for SRM-995 was found to be 1.598E-4 ({+-} 4.50%) using recovery-corrected radiochemical methods. Using the Bateman equations and relevant half-lives, this ratio reflects a material that was purified {approx} 36.8 years prior to this analysis. The calculated age is discussed in contrast with both the date of certification and the recorded date of last purification.

  20. Technical Basis for Peak Reactivity Burnup Credit for BWR Spent Nuclear Fuel in Storage and Transportation Systems

    SciTech Connect (OSTI)

    Marshall, William BJ J; Ade, Brian J; Bowman, Stephen M; Gauld, Ian C; Ilas, Germina; Mertyurek, Ugur; Radulescu, Georgeta

    2015-01-01

    Oak Ridge National Laboratory and the United States Nuclear Regulatory Commission have initiated a multiyear project to investigate application of burnup credit for boiling-water reactor (BWR) fuel in storage and transportation casks. This project includes two phases. The first phase (1) investigates applicability of peak reactivity methods currently used in spent fuel pools (SFPs) to storage and transportation systems and (2) evaluates validation of both reactivity (keff) calculations and burnup credit nuclide concentrations within these methods. The second phase will focus on extending burnup credit beyond peak reactivity. This paper documents the first phase, including an analysis of lattice design parameters and depletion effects, as well as both validation components. Initial efforts related to extended burnup credit are discussed in a companion paper. Peak reactivity analyses have been used in criticality analyses for licensing of BWR fuel in SFPs over the last 20 years. These analyses typically combine credit for the gadolinium burnable absorber present in the fuel with a modest amount of burnup credit. Gadolinium burnable absorbers are used in BWR assemblies to control core reactivity. The burnable absorber significantly reduces assembly reactivity at beginning of life, potentially leading to significant increases in assembly reactivity for burnups less than 15–20 GWd/MTU. The reactivity of each fuel lattice is dependent on gadolinium loading. The number of gadolinium-bearing fuel pins lowers initial lattice reactivity, but it has a small impact on the burnup and reactivity of the peak. The gadolinium concentration in each pin has a small impact on initial lattice reactivity but a significant effect on the reactivity of the peak and the burnup at which the peak occurs. The importance of the lattice parameters and depletion conditions are primarily determined by their impact on the gadolinium depletion. Criticality code validation for BWR burnup

  1. Structure and Reactivity of X-ray Amorphous Uranyl Peroxide,...

    Office of Scientific and Technical Information (OSTI)

    Published Article: Structure and Reactivity of X-ray Amorphous Uranyl Peroxide, U 2 O 7 Prev Next Title: Structure and Reactivity of X-ray Amorphous Uranyl Peroxide, U 2 O 7 ...

  2. Insight from simulations of single-well injection-withdrawal tracer tests on simple and complex fractures

    SciTech Connect (OSTI)

    Tsang, C.-F.; Doughty, C.

    2009-08-06

    The single-well injection withdrawal (SWIW) test, a tracer test utilizing only one well, is proposed as a useful contribution to site characterization of fractured rock, as well as providing parameters relevant to tracer diffusion and sorption. The usual conceptual model of flow and solute transport through fractured rock with low matrix permeability involves solute advection and dispersion through a fracture network coupled with diffusion and sorption into the surrounding rock matrix. Unlike two-well tracer tests, results of SWIW tests are ideally independent of advective heterogeneity, channeling and flow dimension, and, instead, focus on diffusive and sorptive characteristics of tracer (solute) transport. Thus, they can be used specifically to study such characteristics and evaluate the diffusive parameters associated with tracer transport through fractured media. We conduct simulations of SWIW tests on simple and complex fracture models, the latter being defined as having two subfractures with altered rock blocks in between and gouge material in their apertures. Using parameters from the Aspo site in Sweden, we calculate and study SWIW tracer breakthrough curves (BTCs) from a test involving four days of injection and then withdrawal. By examining the peak concentration C{sub pk} of the SWIW BTCs for a variety of parameters, we confirm that C{sub pk} is largely insensitive to the fracture advective flow properties, in particular to permeability heterogeneity over the fracture plane or to subdividing the flow into two subfractures in the third dimension orthogonal to the fracture plane. The peak arrival time t{sub pk} is not a function of fracture or rock properties, but is controlled by the time schedule of the SWIW test. The study shows that the SWIW test is useful for the study of tracer diffusion-sorption processes, including the effect of the so-called flow-wetted surface (FWS) of the fracture. Calculations with schematic models with different FWS values are

  3. Nuclear reactivity control using laser induced polarization

    DOE Patents [OSTI]

    Bowman, Charles D.

    1991-01-01

    A control element for reactivity control of a fission source provides an atomic density of .sup.3 He in a control volume which is effective to control criticality as the .sup.3 He is spin-polarized. Spin-polarization of the .sup.3 He affects the cross section of the control volume for fission neutrons and hence, the reactivity. An irradiation source is directed within the .sup.3 He for spin-polarizing the .sup.3 He. An alkali-metal vapor may be included with the .sup.3 He where a laser spin-polarizes the alkali-metal atoms which in turn, spin-couple with .sup.3 He to spin-polarize the .sup.3 He atoms.

  4. Nuclear reactivity control using laser induced polarization

    DOE Patents [OSTI]

    Bowman, Charles D.

    1990-01-01

    A control element for reactivity control of a fission source provides an atomic density of .sup.3 He in a control volume which is effective to control criticality as the .sup.3 He is spin-polarized. Spin-polarization of the .sup.3 He affects the cross section of the control volume for fission neturons and hence, the reactivity. An irradiation source is directed within the .sup.3 He for spin-polarizing the .sup.3 He. An alkali-metal vapor may be included with the .sup.3 He where a laser spin-polarizes the alkali-metal atoms which in turn, spin-couple with .sup.3 He to spin-polarize the .sup.3 He atoms.

  5. Reactivity control assembly for nuclear reactor. [LMFBR

    DOE Patents [OSTI]

    Bollinger, L.R.

    1982-03-17

    This invention, which resulted from a contact with the United States Department of Energy, relates to a control mechanism for a nuclear reactor and, more particularly, to an assembly for selectively shifting different numbers of reactivity modifying rods into and out of the core of a nuclear reactor. It has been proposed heretofore to control the reactivity of a breeder reactor by varying the depth of insertion of control rods (e.g., rods containing a fertile material such as ThO/sub 2/) in the core of the reactor, thereby varying the amount of neutron-thermalizing coolant and the amount of neutron-capturing material in the core. This invention relates to a mechanism which can advantageously be used in this type of reactor control system.

  6. Computationally Efficient Multiconfigurational Reactive Molecular Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Argonne Leadership Computing Facility Computationally Efficient Multiconfigurational Reactive Molecular Dynamics Authors: Takefumi Yamashita, Yuxing Peng, Chris Knight, Gregory A. Voth It is a computationally demanding task to explicitly simulate the electronic degrees of freedom in a system to observe the chemical transformations of interest, while at the same time sampling the time and length scales required to converge statistical properties and thus reduce artifacts due to initial

  7. Scalable subsurface inverse modeling of huge data sets with an application to tracer concentration breakthrough data from magnetic resonance imaging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lee, Jonghyun; Yoon, Hongkyu; Kitanidis, Peter K.; Werth, Charles J.; Valocchi, Albert J.

    2016-06-09

    When characterizing subsurface properties is crucial for reliable and cost-effective groundwater supply management and contaminant remediation. With recent advances in sensor technology, large volumes of hydro-geophysical and geochemical data can be obtained to achieve high-resolution images of subsurface properties. However, characterization with such a large amount of information requires prohibitive computational costs associated with “big data” processing and numerous large-scale numerical simulations. To tackle such difficulties, the Principal Component Geostatistical Approach (PCGA) has been proposed as a “Jacobian-free” inversion method that requires much smaller forward simulation runs for each iteration than the number of unknown parameters and measurements needed inmore » the traditional inversion methods. PCGA can be conveniently linked to any multi-physics simulation software with independent parallel executions. In our paper, we extend PCGA to handle a large number of measurements (e.g. 106 or more) by constructing a fast preconditioner whose computational cost scales linearly with the data size. For illustration, we characterize the heterogeneous hydraulic conductivity (K) distribution in a laboratory-scale 3-D sand box using about 6 million transient tracer concentration measurements obtained using magnetic resonance imaging. Since each individual observation has little information on the K distribution, the data was compressed by the zero-th temporal moment of breakthrough curves, which is equivalent to the mean travel time under the experimental setting. Moreover, only about 2,000 forward simulations in total were required to obtain the best estimate with corresponding estimation uncertainty, and the estimated K field captured key patterns of the original packing design, showing the efficiency and effectiveness of the proposed method. This article is protected by copyright. All rights reserved.« less

  8. Tracer study of oxygen and hydrogen uptake by Mg alloys in air with water vapor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brady, M. P.; Fayek, M.; Meyer, H. M.; Leonard, D. N.; Elsentriecy, H. H.; Unocic, K. A.; Anovitz, L. M.; Cakmak, E.; Keiser, J. R.; Song, G. L.; et al

    2015-05-15

    We studied the pure oxidation of Mg, Mg–3Al–1Zn (AZ31B), and Mg–1Zn–0.25Zr–<0.5Nd (ZE10A) at 85 °C in humid air using sequential exposures with H218O and D216O for water vapor. Incorporation of 18O in the hydroxide/oxide films indicated that oxygen from water vapor participated in the reaction. Moreover, penetration of hydrogen into the underlying metal was observed, particularly for the Zr- and Nd-containing ZE10A. Isotopic tracer profiles suggested a complex mixed inward/outward film growth mechanism.

  9. DOE - Office of Legacy Management -- Reactive Metals Inc - OH 10

    Office of Legacy Management (LM)

    Reactive Metals Inc - OH 10 FUSRAP Considered Sites Site: Reactive Metals Inc. (OH.10) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Ashtabula Site Documents Related to Reactive Metals Inc

  10. Kinetic and mechanistic studies of reactive intermediates in photochemical and transition metal-assisted oxidation, decarboxylation and alkyl transfer reactions

    SciTech Connect (OSTI)

    Carraher, Jack McCaslin

    2014-01-01

    Reactive species like high-valent metal-oxo complexes and carbon and oxygen centered radicals are important intermediates in enzymatic systems, atmospheric chemistry, and industrial processes. Understanding the pathways by which these intermediates form, their relative reactivity, and their fate after reactions is of the utmost importance. Herein are described the mechanistic detail for the generation of several reactive intermediates, synthesis of precursors, characterization of precursors, and methods to direct the chemistry to more desirable outcomes yielding ‘greener’ sources of commodity chemicals and fuels.

  11. Spatial corrections for pulsed-neutron reactivity measurements.

    SciTech Connect (OSTI)

    Cao, Y.; Lee, J.; Nuclear Engineering Division; Univ. of Michigan

    2010-07-01

    For pulsed-neutron experiments performed in a subcritical reactor, the reactivity obtained from the area-ratio method is sensitive to detector positions. The spatial effects are induced by the presence of both the prompt neutron harmonics and the delayed neutron harmonics in the reactor. The traditional kinetics distortion factor is only limited to correcting the spatial effects caused by the fundamental prompt-{alpha} mode. In this paper, we derive spatial correction factors fp and fd to account for spatial effects induced by the prompt neutron harmonics and the delayed neutron harmonics, respectively. Our numerical simulations with the FX2-TH time-dependent multigroup diffusion code indicate that the high-order prompt neutron harmonics lead to significant spatial effects and cannot be neglected in calculating the spatial correction factors. The prompt spatial correction factor fp can be simply determined by the ratio of the normalized detector responses corresponding to the fundamental k-mode and the prompt neutron flux integrated over the pulse period. Thus, it is convenient to calculate and provides physically intuitive explanations on the spatial dependence of reactivity measured in the MUSE-4 experiments: overestimation of the subcriticality in regions close to the external neutron source and underestimation of the subcriticality away from the source but within the fuel region.

  12. End-Member Formulation of Solid Solutions and Reactive Transport

    SciTech Connect (OSTI)

    Lichtner, Peter C.

    2015-09-01

    A model for incorporating solid solutions into reactive transport equations is presented based on an end-member representation. Reactive transport equations are solved directly for the composition and bulk concentration of the solid solution. Reactions of a solid solution with an aqueous solution are formulated in terms of an overall stoichiometric reaction corresponding to a time-varying composition and exchange reactions, equivalent to reaction end-members. Reaction rates are treated kinetically using a transition state rate law for the overall reaction and a pseudo-kinetic rate law for exchange reactions. The composition of the solid solution at the onset of precipitation is assumed to correspond to the least soluble composition, equivalent to the composition at equilibrium. The stoichiometric saturation determines if the solid solution is super-saturated with respect to the aqueous solution. The method is implemented for a simple prototype batch reactor using Mathematica for a binary solid solution. Finally, the sensitivity of the results on the kinetic rate constant for a binary solid solution is investigated for reaction of an initially stoichiometric solid phase with an undersaturated aqueous solution.

  13. Gas chromatograph-mass spectrometer (GC/MS) system for quantitative analysis of reactive chemical compounds

    DOE Patents [OSTI]

    Grindstaff, Quirinus G.

    1992-01-01

    Described is a new gas chromatograph-mass spectrometer (GC/MS) system and method for quantitative analysis of reactive chemical compounds. All components of such a GC/MS system external to the oven of the gas chromatograph are programmably temperature controlled to operate at a volatilization temperature specific to the compound(s) sought to be separated and measured.

  14. Uranium transport in a crushed granodiorite: Experiments and reactive transport modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dittrich, T. M.; Reimus, P. W.

    2015-02-12

    The primary objective of this study was to develop and demonstrate an experimental method to refine and better parameterize process models for reactive contaminant transport in aqueous subsurface environments and to reduce conservatism in such models without attempting to fully describe the geochemical system.

  15. WSi2/Si Multilayer Sectioning by Reactive Ion Etching for Multilayer Laue Lens Fabrication

    SciTech Connect (OSTI)

    Bouet, N.; Conley, R.; Biancarosaa, J.; Divanc, R.; Macrander, A. T.

    2010-08-01

    SPIE Conference paper/talk presentation: Introduction: Reactive ion etching (RIE) has been employed in a wide range of fields such as semiconductor fabrication, MEMS (microelectromechanical systems), and refractive x-ray optics with a large investment put towards the development of deep RIE. Due to the intrinsic differing chemistries related to reactivity, ion bombardment, and passivation of materials, the development of recipes for new materials or material systems can require intense effort and resources. For silicon in particular, methods have been developed to provide reliable anisotropic profiles with good dimensional control and high aspect ratios1,2,3, high etch rates, and excellent material to mask etch selectivity...

  16. A Really Good Hammer: Quantification of Mass Transfer Using Perfluorocarbon Tracers (475th Brookhaven Lecture)

    SciTech Connect (OSTI)

    Watson, Tom

    2012-02-15

    Brookhaven Labs perfluorocarbon tracer (PFT) technology can be viewed as a hammer looking for nails. But, according to Tom Watson, leader of the Labs Tracer Technology Group in the Environmental Research and Technology Division (ERTD), Its a really good hammer! The colorless, odorless and safe gases have a number of research uses, from modeling how airborne contaminants might move through urban canyons to help first responders plan their response to potential terrorist attacks and accidents to locating leaks in underground gas pipes. Their extremely low background level detectable at one part per quadrillion allows their transport to be easily tracked. Lab researchers used PFTs during the 2005 Urban Dispersion Program field studies in New York City, gathering data to help improve models of how a gas or chemical release might move around Manhattans tall buildings and canyons. Closer to home, scientists also used PFTs to make ventilation measurements in Bldg. 400 on the Lab site to provide data to test air flow models used in determining the effects of passive and active air exchange on the levels of indoor and outdoor air pollution, and to determine the effects of an accidental or intentional release of hazardous substances in or around buildings.

  17. REAL-TIME TRACER MONITORING OF RESERVOIR STIMULATION PROCEDURES VIA ELECTRONIC WIRELINE AND TELEMETRY DATA TRANSMISSION

    SciTech Connect (OSTI)

    George L. Scott III

    2005-01-01

    Finalized Phase 2-3 project work has field-proven two separate real-time reservoir processes that were co-developed via funding by the National Energy Technology Laboratory (NETL). Both technologies are presently patented in the United States and select foreign markets; a downhole-commingled reservoir stimulation procedure and a real-time tracer-logged fracturing diagnostic system. Phase 2 and early Phase 3 project work included the research, development and well testing of a U.S. patented gamma tracer fracturing diagnostic system. This stimulation logging process was successfully field-demonstrated; real-time tracer measurement of fracture height while fracturing was accomplished and proven technically possible. However, after the initial well tests, there were several licensing issues that developed between service providers that restricted and minimized Realtimezone's (RTZ) ability to field-test the real-time gamma diagnostic system as was originally outlined for this project. Said restrictions were encountered after when one major provider agreed to license their gamma logging tools to another. Both of these companies previously promised contributory support toward Realtimezone's DE-FC26-99FT40129 project work, however, actual support was less than desired when newly-licensed wireline gamma logging tools from one company were converted by the other from electric wireline into slickline, batter-powered ''memory'' tools for post-stimulation logging purposes. Unfortunately, the converted post-fracture measurement memory tools have no applications in experimentally monitoring real-time movement of tracers in the reservoir concurrent with the fracturing treatment. RTZ subsequently worked with other tracer gamma-logging tool companies for basic gamma logging services, but with lessened results due to lack of multiple-isotope detection capability. In addition to real-time logging system development and well testing, final Phase 2 and Phase 3 project work included the

  18. Preparation of reactive beta-dicalcium silicate

    DOE Patents [OSTI]

    Shen, Ming-Shing (Laramie, WY, NJ); Chen, James M. (Rahway, NJ); Yang, Ralph T. (Amherst, NY)

    1982-01-01

    This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane and hydrogen, at a temperature of about 850.degree.-1000.degree. C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

  19. Preparation of reactive beta-dicalcium silicate

    DOE Patents [OSTI]

    Shen, M.S.; Chen, J.M.; Yang, R.T.

    1980-02-28

    This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica, and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane, and hydrogen, at a temperature of about 850 to 1000/sup 0/C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

  20. Anode reactive bleed and injector shift control strategy

    DOE Patents [OSTI]

    Cai, Jun [Rochester, NY; Chowdhury, Akbar [Pittsford, NY; Lerner, Seth E [Honeoye Falls, NY; Marley, William S [Rush, NY; Savage, David R [Rochester, NY; Leary, James K [Rochester, NY

    2012-01-03

    A system and method for correcting a large fuel cell voltage spread for a split sub-stack fuel cell system. The system includes a hydrogen source that provides hydrogen to each split sub-stack and bleed valves for bleeding the anode side of the sub-stacks. The system also includes a voltage measuring device for measuring the voltage of each cell in the split sub-stacks. The system provides two levels for correcting a large stack voltage spread problem. The first level includes sending fresh hydrogen to the weak sub-stack well before a normal reactive bleed would occur, and the second level includes sending fresh hydrogen to the weak sub-stack and opening the bleed valve of the other sub-stack when the cell voltage spread is close to stack failure.

  1. Properties of reactive oxygen species by quantum Monte Carlo

    SciTech Connect (OSTI)

    Zen, Andrea; Trout, Bernhardt L.; Guidoni, Leonardo

    2014-07-07

    The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of chemistry, biology, and atmospheric science. Nevertheless, the electronic structure of such species is a challenge for ab initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution, and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular, we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as N{sup 3} ? N{sup 4}, where N is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

  2. Experimental investigation of piston heat transfer under conventional diesel and reactivity-controlled compression ignition combustion regimes

    SciTech Connect (OSTI)

    Splitter, Derek A; Hendricks, Terry Lee; Ghandhi, Jaal B

    2014-01-01

    The piston of a heavy-duty single-cylinder research engine was instrumented with 11 fast-response surface thermocouples, and a commercial wireless telemetry system was used to transmit the signals from the moving piston. The raw thermocouple data were processed using an inverse heat conduction method that included Tikhonov regularization to recover transient heat flux. By applying symmetry, the data were compiled to provide time-resolved spatial maps of the piston heat flux and surface temperature. A detailed comparison was made between conventional diesel combustion and reactivity-controlled compression ignition combustion operations at matched conditions of load, speed, boost pressure, and combustion phasing. The integrated piston heat transfer was found to be 24% lower, and the mean surface temperature was 25 C lower for reactivity-controlled compression ignition operation as compared to conventional diesel combustion, in spite of the higher peak heat release rate. Lower integrated piston heat transfer for reactivity-controlled compression ignition was found over all the operating conditions tested. The results showed that increasing speed decreased the integrated heat transfer for conventional diesel combustion and reactivity-controlled compression ignition. The effect of the start of injection timing was found to strongly influence conventional diesel combustion heat flux, but had a negligible effect on reactivity-controlled compression ignition heat flux, even in the limit of near top dead center high-reactivity fuel injection timings. These results suggest that the role of the high-reactivity fuel injection does not significantly affect the thermal environment even though it is important for controlling the ignition timing and heat release rate shape. The integrated heat transfer and the dynamic surface heat flux were found to be insensitive to changes in boost pressure for both conventional diesel combustion and reactivity-controlled compression ignition

  3. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 4, July--September 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  4. Rocky Flats 1990--91 winter validation tracer study: Volume 1

    SciTech Connect (OSTI)

    Brown, K.J.

    1991-10-01

    During the winter of 1990--91, North American Weather Consultants (NAWC) and its subcontractor, ABB Environmental Services (ABBES), conducted a Winter Validation Study (WVS) for EG&G Rocky Flats involving 12 separate tracer experiments conducted between February 3 and February 19, 1991. Six experiments were conducted during nighttime hours and four experiments were conducted during daytime hours. In addition, there was one day/night and one night/day transitional experiment conducted. The primary purpose of the WVS was to gather data to further the approval process for the Terrain Responsive Atmospheric Code (TRAC). TRAC is an atmospheric dispersion model developed and operated at the Department of Energy`s (DOE`s) Rocky Flats Plant (RFP) north of Denver, Colorado. A secondary objective was to gather data that will serve to validate the TRAC model physics.

  5. Haze in the Grand Canyon: An evaluation of the Winter Haze Intensive Tracer Experiment

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    The Grand Canyon is one of the most spectacular natural sights on earth. Approximately 4 million visitors travel to Grand Canyon National Park (GCNP) each year to enjoy its majestic geological formations and intensely colored views. However, visibility in GCNP can be impaired by small increases in concentrations of fine suspended particles that scatter and absorb light; the resulting visibility degradation is perceived as haze. Sulfate particles are a major factor in visibility impairment at Grand Canyon in summer and winter. Many wintertime hazes at GCNP are believed to result from the accumulation of emissions from local sources during conditions of air stagnation, which occur more frequently in winter than in summer. In January and February 1987, the National Park Service (NPS) carried out a large-scale experiment known as the Winter Haze Intensive Tracer Experiment (WHITEX) to investigate the causes of wintertime haze in the region of GCNP and Canyonlands National Park. The overall objective of WHITEX was to assess the feasibility of attributing visibility impairment in specific geographic regions to emissions from a single point source. The experiment called for the injection of a tracer, deuterated methane (CD{sub 4}), into one of the stacks of the Navajo Generating Station (NGS), a major coal-fired power plant located 25 km from the GCNP boundary and 110 km northeast of Grand Canyon Village. A network of field stations was established in the vicinity -- mostly to the northeast of GCNP and NGS -- to measure CD{sub 4} concentrations, atmospheric aerosol and optical properties, and other chemical and physical attributes. 19 refs., 3 figs.

  6. PERFLUOROCARBON GAS TRACER STUDIES TO SUPPORT RISK ASSESSMENT MODELING OF CRITICAL INFRASTRUCTURE SUBJECTED TO TERRORIST ATTACKS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; HEISER, J.; WATSON, T.; ALLWINE, K.J.; FLAHERTY, J.E.

    2006-05-06

    Development of real-time predictive modeling to identify the dispersion and/or source(s) of airborne weapons of mass destruction including chemical, biological, radiological, and nuclear material in urban environments is needed to improve response to potential releases of these materials via either terrorist or accidental means. These models will also prove useful in defining airborne pollution dispersion in urban environments for pollution management/abatement programs. Predicting gas flow in an urban setting on a scale of less than a few kilometers is a complicated and challenging task due to the irregular flow paths that occur along streets and alleys and around buildings of different sizes and shapes, i.e., ''urban canyons''. In addition, air exchange between the outside and buildings and subway areas further complicate the situation. Transport models that are used to predict dispersion of WMD/CBRN materials or to back track the source of the release require high-density data and need defensible parameterizations of urban processes. Errors in the data or any of the parameter inputs or assumptions will lead to misidentification of the airborne spread or source release location(s). The need for these models to provide output in a real-time fashion if they are to be useful for emergency response provides another challenge. To improve the ability of New York City's (NYC's) emergency management teams and first response personnel to protect the public during releases of hazardous materials, the New York City Urban Dispersion Program (UDP) has been initiated. This is a four year research program being conducted from 2004 through 2007. This paper will discuss ground level and subway Perfluorocarbon tracer (PFT) release studies conducted in New York City. The studies released multiple tracers to study ground level and vertical transport of contaminants. This paper will discuss the results from these tests and how these results can be used for improving transport models

  7. Comparison of Conventional Diesel and Reactivity Controlled Compression

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ignition (RCCI) Combustion in a Light-Duty Engine | Department of Energy Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI) Combustion in a Light-Duty Engine Comparison of Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI) Combustion in a Light-Duty Engine CFD modeling was used to compare conventional diesel and dual-fuel Reactivity Controlled Compression Ignition combustion at US Tier 2 Bin 5 NOx levels, while accounting for Diesel Exhaust Fluid

  8. Geopolymer with hierarchically meso-/macroporous structures from reactive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    emulsion templating Geopolymer with hierarchically meso-/macroporous structures from reactive emulsion templating Authors: Medpelli, D., Seo, J.-M., and Seo, D.-K. Title: Geopolymer with hierarchically meso-/macroporous structures from reactive emulsion templating Source: J. Amer. Ceram. Soc. Year: 2014 Volume: 97 (1) Pages: 70-73 ABSTRACT: We present a simple synthetic route to hierarchically porous geopolymers using triglyceride oil for a reactive emulsion template. In the new synthetic

  9. High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Fuel Reactivity Controlled Compression Ignition Combustion High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion An optimized dual-fuel PCCI concept, RCCI, is proposed. deer10_reitz.pdf (960.46 KB) More Documents & Publications Effect of Compression Ratio and Piston Geometry on RCCI load limit Optimization of Advanced Diesel Engine Combustion Strategies Comparison of Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI)

  10. Green River air quality model development: meteorological and tracer data, July/August 1982 field study in Brush Valley, Colorado

    SciTech Connect (OSTI)

    Whiteman, C.D.; Lee, R.N.; Orgill, M.M.; Zak, B.D.

    1984-06-01

    Meteorological and atmospheric tracer studies were conducted during a 3-week period in July and August of 1982 in the Brush Creek Valley of northwestern Colorado. The objective of the field experiments was to obtain data to evaluate a model, called VALMET, developed at PNL to predict dispersion of air pollutants released from an elevated stack located within a deep mountain valley in the post-sunrise temperature inversion breakup period. Three tracer experiments were conducted in the valley during the 2-week period. In these experiments, sulfur hexafluoride (SF/sub 6/) was released from a height of approximately 100 m, beginning before sunrise and continuing until the nocturnal down-valley winds reversed several hours after sunrise. Dispersion of the sulfur hexafluoride after release was evaluated by measuring SF/sub 6/ concentrations in ambient air samples taken from sampling devices operated within the valley up to about 8 km down valley from the source. An instrumented research aircraft was also used to measure concentrations in and above the valley. Tracer samples were collected using a network of radio-controlled bag sampling stations, two manually operated gas chromatographs, a continuous SF/sub 6/ monitor, and a vertical SF/sub 6/ profiler. In addition, basic meteorological data were collected during the tracer experiments. Frequent profiles of vertical wind and temperature structure were obtained with tethered balloons operated at the release site and at a site 7.7 km down the valley from the release site. 10 references, 63 figures, 50 tables.

  11. Sample Memorandum to Reactivate a Directive Placed on Hold (NOTE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sample Memorandum to Reactivate a Directive Placed on Hold (NOTE: Per Office of Executive Secretariat procedures, please use Calibri, 12 point font for this memorandum.) (Effective...

  12. WP-07 Reactive Power Supplemental Proposal (wp07/initial)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This modification is necessary in light of recent FERC cases regarding generation input cost for generation supplied reactive power and voltage control. On February 13, BPA...

  13. PFLOTRAN User Manual: A Massively Parallel Reactive Flow and...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: PFLOTRAN User Manual: A Massively Parallel Reactive Flow and Transport Model for Describing Surface and Subsurface Processes Citation Details In-Document Search...

  14. PFLOTRAN User Manual: A Massively Parallel Reactive Flow and...

    Office of Scientific and Technical Information (OSTI)

    PFLOTRAN User Manual: A Massively Parallel Reactive Flow and Transport Model for Describing Surface and Subsurface Processes Lichtner, Peter OFM Research; Karra, Satish Los...

  15. Light-Duty Reactivity Controlled Compression Ignition Drive Cycle...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ignition Drive Cycle Fuel Economy and Emissions Estimates Light-Duty Reactivity Controlled Compression Ignition Drive Cycle Fuel Economy and Emissions Estimates Vehicle ...

  16. Review of Reactivity Experiments for Lithium Ternary Alloys ...

    Office of Scientific and Technical Information (OSTI)

    The plant uses lithium in both the primary coolant and blanket; therefore, lithium related hazards are of primary concern. Reducing chemical reactivity is the primary motivation ...

  17. Persistence of Hydrologic Variables and Reactive Stream Solute...

    Office of Scientific and Technical Information (OSTI)

    Watershed Citation Details In-Document Search Title: Persistence of Hydrologic Variables and Reactive Stream Solute Concentrations in an East Tennessee Watershed Time and ...

  18. Double Shock Experiments and Reactive Flow Modeling of High Pressure...

    Office of Scientific and Technical Information (OSTI)

    Double Shock Experiments and Reactive Flow Modeling of High Pressure LX-17 Detonation Reaction Product States Citation Details In-Document Search Title: Double Shock Experiments ...

  19. Reactivity of the Gold/Water Interface During Selective Oxidation...

    Office of Scientific and Technical Information (OSTI)

    the GoldWater Interface During Selective Oxidation Catalysis Citation Details In-Document Search Title: Reactivity of the GoldWater Interface During Selective Oxidation Catalysis ...

  20. CL-20 Reactivity in the Subsurface Environment and Potential...

    Office of Scientific and Technical Information (OSTI)

    and Potential for Migration Citation Details In-Document Search Title: CL-20 Reactivity in the Subsurface Environment and Potential for Migration Hexanitrohexaazaisowurtzit...

  1. Characterization of Dual-Fuel Reactivity Controlled Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (RCCI) Using Hydrated Ethanol and Diesel Fuel Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel This study ...

  2. Chemically Reactive Working Fluids for the Capture and Transport...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Planar Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working Fluids Low-Cost Light Weigh Thin Film Solar ...

  3. Comparison of Conventional Diesel and Reactivity Controlled Compressio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engine Combustion Strategies High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion Effect of Compression Ratio and Piston Geometry on RCCI load limit

  4. Reactive Molecular Simulations of Protonation of Water Clusters...

    Office of Scientific and Technical Information (OSTI)

    of Water Clusters and Depletion of Acidity in H-ZSM-5 Zeolite Citation Details In-Document Search Title: Reactive Molecular Simulations of Protonation of Water Clusters ...

  5. Hydraulic Conductivity of the Monticello Permeable Reactive Barrier...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Caon City, Colorado, Uranium Mill

  6. Review of existing reactive transport software

    SciTech Connect (OSTI)

    Glassley, W., LLNL

    1998-02-03

    Simulations of thermal and hydrological evolution following the potential emplacement of a subterranean nuclear waste repository at Yucca Mountain, NV provide data that suggest the inevitability of dependent, simultaneous chemical evolution in this system. These chemical changes will modify significantly both the magnitude and structure of local porosity and permeability; hence, they will have a dynamic feedback effect on the evolving thermal and hydrological regime. Yet, despite this intimate interdependence of transport and chemical processes, a rigorous quantitative analysis of the post- emplacement environment that incorporates this critical feedback mechanism has not been completed to date. As an initial step in this direction, the present document outlines the fundamental chemical and transport processes that must be accounted for in such an analysis, and reviews the inventory of existing software that encodes these processed in explicitly coupled form. A companion report describes the prioritization of specific capabilities that are needed for modeling post-emplacement reactive transport at Yucca Mountain.

  7. A Uranium Bioremediation Reactive Transport Benchmark

    SciTech Connect (OSTI)

    Yabusaki, Steven B.; Sengor, Sevinc; Fang, Yilin

    2015-06-01

    A reactive transport benchmark problem set has been developed based on in situ uranium bio-immobilization experiments that have been performed at a former uranium mill tailings site in Rifle, Colorado, USA. Acetate-amended groundwater stimulates indigenous microorganisms to catalyze the reduction of U(VI) to a sparingly soluble U(IV) mineral. The interplay between the flow, acetate loading periods and rates, microbially-mediated and geochemical reactions leads to dynamic behavior in metal- and sulfate-reducing bacteria, pH, alkalinity, and reactive mineral surfaces. The benchmark is based on an 8.5 m long one-dimensional model domain with constant saturated flow and uniform porosity. The 159-day simulation introduces acetate and bromide through the upgradient boundary in 14-day and 85-day pulses separated by a 10 day interruption. Acetate loading is tripled during the second pulse, which is followed by a 50 day recovery period. Terminal electron accepting processes for goethite, phyllosilicate Fe(III), U(VI), and sulfate are modeled using Monod-type rate laws. Major ion geochemistry modeled includes mineral reactions, as well as aqueous and surface complexation reactions for UO2++, Fe++, and H+. In addition to the dynamics imparted by the transport of the acetate pulses, U(VI) behavior involves the interplay between bioreduction, which is dependent on acetate availability, and speciation-controlled surface complexation, which is dependent on pH, alkalinity and available surface complexation sites. The general difficulty of this benchmark is the large number of reactions (74), multiple rate law formulations, a multisite uranium surface complexation model, and the strong interdependency and sensitivity of the reaction processes. Results are presented for three simulators: HYDROGEOCHEM, PHT3D, and PHREEQC.

  8. A Preliminary Analysis of the Economics of Using Distributed Energy as a Source of Reactive Power Supply

    SciTech Connect (OSTI)

    Li, Fangxing; Kueck, John D; Rizy, D Tom; King, Thomas F

    2006-04-01

    operation in response to local or system operators. There are no known distributed energy asset owners currently receiving compensation for reactive power supply or capability. However, there are some cases where small generators on the generation and transmission side of electricity supply have been tested and have installed the capability to be dispatched for reactive power support. Several concerns need to be met for distributed energy to become widely integrated as a reactive power resource. The overall costs of retrofitting distributed energy devices to absorb or produce reactive power need to be reduced. There needs to be a mechanism in place for ISOs/RTOs to procure reactive power from the customer side of the meter where distributed energy resides. Novel compensation methods should be introduced to encourage the dispatch of dynamic resources close to areas with critical voltage issues. The next phase of this research will investigate in detail how different options of reactive power producing DE can compare both economically and functionally with shunt capacitor banks. Shunt capacitor banks, which are typically used for compensating reactive power consumption of loads on distribution systems, are very commonly used because they are very cost effective in terms of capital costs. However, capacitor banks can require extensive maintenance especially due to their exposure to lightning at the top of utility poles. Also, it can be problematic to find failed capacitor banks and their maintenance can be expensive, requiring crews and bucket trucks which often requires total replacement. Another shortcoming of capacitor banks is the fact that they usually have one size at a location (typically sized as 300, 600, 900 or 1200kVAr) and thus don't have variable range as do reactive power producing DE, and cannot respond to dynamic reactive power needs. Additional future work is to find a detailed methodology to identify the hidden benefit of DE for providing reactive power and

  9. Radionuclide tracers for the fate of metals in the Savannah estuary: River-ocean exchange processes

    SciTech Connect (OSTI)

    Olsen, C.R.; Thein, M.; Larsen, I.L.; Byrd, J.T.; Windom, H.L.

    1989-01-01

    Plutonium-238 from the US Department of Energy's Savannah River Plant labels riverborne particles, providing a unique opportunity for examining the fate of metals in estuaries and for tracing river-ocean exchange processes. Results indicate that plutonium and lead-210 are enriched on estuarine particles and that inputs of plutonium from oceanic sources greatly exceed inputs from riverborne or drainage-basin sources as far upstream as the landward limit of seawater penetration. We suggest that these radionuclides (and other chemically reactive metals) are being scavenged from oceanic water by sorption onto particles in turbid estuarine and coastal areas. Since estuaries, bays, mangroves, and intertidal areas serve as effective traps for fine particles and associated trace substances, these results have important implications concerning the disposal of chemically reactive substances in oceanic waters. 13 refs., 1 fig., 1 tab.

  10. The Reactivity of Energetic Materials At Extreme Conditions

    SciTech Connect (OSTI)

    Fried, L E

    2006-10-23

    shock conditions, for example, energetic materials undergo rapid heating to a few thousand degrees and are subjected to a compression of hundreds of kilobars, resulting in almost 30% volume reduction. Complex chemical reactions are thus initiated, in turn releasing large amounts of energy to sustain the detonation process. Clearly, understanding of the various chemical events at these extreme conditions is essential in order to build predictive material models. Scientific investigations into the reactive process have been undertaken over the past two decades. However, the sub-{micro}s time scale of explosive reactions, in addition to the highly exothermic conditions of an explosion, make experimental investigation of the decomposition pathways difficult at best. More recently, new computational approaches to investigate condensed-phase reactivity in energetic materials have been developed. Here we focus on two different approaches to condensed-phase reaction modeling: chemical equilibrium methods and atomistic modeling of condensed-phase reactions. These are complementary approaches to understanding the chemical reactions of high explosives. Chemical equilibrium modeling uses a highly simplified thermodynamic picture of the reaction process, leading to a convenient and predictive model of detonation and other decomposition processes. Chemical equilibrium codes are often used in the design of new materials, both at the level of synthesis chemistry and formulation. Atomistic modeling is a rapidly emerging area. The doubling of computational power approximately every 18 months has made atomistic condensed-phase modeling more feasible. Atomistic calculations employ far fewer empirical parameters than chemical equilibrium calculations. Nevertheless, the atomistic modeling of chemical reactions requires an accurate global Born-Oppenheimer potential energy surface. Traditionally, such a surface is constructed by representing the potential energy surface with an analytical fit

  11. IONIC LIQUIDS: RADIATION CHEMISTRY, SOLVATION DYNAMICS AND REACTIVITY PATTERNS.

    SciTech Connect (OSTI)

    WISHART,J.F.

    2007-10-01

    energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs are generally nonvolatile, noncombustible, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of chemical reactions and product distributions. Successful use of ionic liquids in radiation-filled environments, where their safety advantages could be significant, requires an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of IL radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material. An understanding of ionic liquid radiation chemistry will also facilitate pulse radiolysis studies of general chemical reactivity in ILs, which will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increases the importance of pre-solvated electron reactivity and consequently alters product distributions. Parallel studies of IL solvation phenomena using coumarin-153 dynamic Stokes shifts and polarization anisotropy decay rates are done to compare with electron solvation studies and to evaluate the influence of ILs on charge transport processes. Methods. Picosecond pulse radiolysis studies at BNL

  12. Mapping the March to Methodical Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping the March to Methodical Materials Mapping the March to Methodical Materials Computational Chemistry Provides Proof of Popular MOF's Reactivity September 18, 2014 Contact: Kristin Manke, kristin.manke@pnnl.gov, +1 509.372.6011 marchmof Scientists from Pacific Northwest National Laboratory demonstrated the fundamental reactions that occur when synthesizing the building blocks of a metal-organic framework. Image: PNNL Selective and reactive, metal-organic frameworks (MOFs) could replace

  13. Reactive power planning under high penetration of wind energy using Benders decomposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Yan; Wei, Yanli; Fang, Xin; Li, Fangxing; Azim, Riyasat

    2015-11-05

    This study addresses the optimal allocation of reactive power volt-ampere reactive (VAR) sources under the paradigm of high penetration of wind energy. Reactive power planning (RPP) in this particular condition involves a high level of uncertainty because of wind power characteristic. To properly model wind generation uncertainty, a multi-scenario framework optimal power flow that considers the voltage stability constraint under the worst wind scenario and transmission N 1 contingency is developed. The objective of RPP in this study is to minimise the total cost including the VAR investment cost and the expected generation cost. Therefore RPP under this condition ismore » modelled as a two-stage stochastic programming problem to optimise the VAR location and size in one stage, then to minimise the fuel cost in the other stage, and eventually, to find the global optimal RPP results iteratively. Benders decomposition is used to solve this model with an upper level problem (master problem) for VAR allocation optimisation and a lower problem (sub-problem) for generation cost minimisation. Impact of the potential reactive power support from doubly-fed induction generator (DFIG) is also analysed. Lastly, case studies on the IEEE 14-bus and 118-bus systems are provided to verify the proposed method.« less

  14. Reactive power planning under high penetration of wind energy using Benders decomposition

    SciTech Connect (OSTI)

    Xu, Yan; Wei, Yanli; Fang, Xin; Li, Fangxing; Azim, Riyasat

    2015-11-05

    This study addresses the optimal allocation of reactive power volt-ampere reactive (VAR) sources under the paradigm of high penetration of wind energy. Reactive power planning (RPP) in this particular condition involves a high level of uncertainty because of wind power characteristic. To properly model wind generation uncertainty, a multi-scenario framework optimal power flow that considers the voltage stability constraint under the worst wind scenario and transmission N 1 contingency is developed. The objective of RPP in this study is to minimise the total cost including the VAR investment cost and the expected generation cost. Therefore RPP under this condition is modelled as a two-stage stochastic programming problem to optimise the VAR location and size in one stage, then to minimise the fuel cost in the other stage, and eventually, to find the global optimal RPP results iteratively. Benders decomposition is used to solve this model with an upper level problem (master problem) for VAR allocation optimisation and a lower problem (sub-problem) for generation cost minimisation. Impact of the potential reactive power support from doubly-fed induction generator (DFIG) is also analysed. Lastly, case studies on the IEEE 14-bus and 118-bus systems are provided to verify the proposed method.

  15. Using CO2 Lidar for Standoff Detection of a Perfluorocarbon Tracer in Air

    SciTech Connect (OSTI)

    Heiser,J.H.; Smith, S.; Sedlacek, A.

    2008-02-06

    The Tag, Track and Location System Program (TTL) is investigating the use of PFTs as tracers for tagging and tracking items of interest or fallen soldiers. In order for the tagging and tracking to be valuable there must be a location system that can detect the PFTs. This report details the development of an infrared lidar platform for standoff detection of PFTs released into the air from a tagged object or person. Furthering work performed using a table top lidar system in an indoor environment; a mobile mini lidar platform was assembled using an existing Raman lidar platform, a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was then successfully demonstrated at an outdoor test. The lidar system was able to detect PFTs released into a vehicle from a distance of 100 meters. In its final, fully optimized configuration the lidar was capable of repeatedly detecting PFTs in the air released from tagged vehicles. Responses were immediate and clear. This report details the results of a proof-of-concept demonstration for standoff detection of a perfluorocarbon tracer (PFT) using infrared lidar. The project is part of the Tag, Track and Location System Program and was performed under a contract with Tracer Detection Technology Corp. with funding from the Office of Naval Research. A lidar capable of detecting PFT releases at distance was assembled by modifying an existing Raman lidar platform by incorporating a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was successfully demonstrated at an outdoor test. The demonstration test (scripted by the sponsor) consisted of three parked cars, two of which were tagged with the PFT. The cars were located 70 (closest) to 100 meters (farthest

  16. Variational reactivity estimates: new analyses and new results

    SciTech Connect (OSTI)

    Favorite, Jeffrey A

    2009-01-01

    A modified form of the variational estimate of the reactivity worth ofa perturbation was previously developed to extend the range of applicability of variational perturbation theory for perturbations leading to negative reactivity worths. Recent numerical results challenged the assumptions behind the modified form. In this paper, more results are obtained, leading to the conclusion that sometimes the modified form extends the range ofapplicability of variational perturbation theory for positive reactivity worths as well, and sometimes the standard variational form is more accurate for negative-reactivity perturbations. In addition, this paper proves that using the exact generalized adjoint function would lead to an inaccurate variational reactivity estimate when the error in the first-order estimate is large; the standard generalized adjoint function, an approximation to the exact one, leads to Lore accurate results. This conclusion is also demonstrated numerically. Transport calculations use the PARTISN multi group discrete ordinates code

  17. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  18. Etching radical controlled gas chopped deep reactive ion etching

    DOE Patents [OSTI]

    Olynick, Deidre; Rangelow, Ivo; Chao, Weilun

    2013-10-01

    A method for silicon micromachining techniques based on high aspect ratio reactive ion etching with gas chopping has been developed capable of producing essentially scallop-free, smooth, sidewall surfaces. The method uses precisely controlled, alternated (or chopped) gas flow of the etching and deposition gas precursors to produce a controllable sidewall passivation capable of high anisotropy. The dynamic control of sidewall passivation is achieved by carefully controlling fluorine radical presence with moderator gasses, such as CH.sub.4 and controlling the passivation rate and stoichiometry using a CF.sub.2 source. In this manner, sidewall polymer deposition thicknesses are very well controlled, reducing sidewall ripples to very small levels. By combining inductively coupled plasmas with controlled fluorocarbon chemistry, good control of vertical structures with very low sidewall roughness may be produced. Results show silicon features with an aspect ratio of 20:1 for 10 nm features with applicability to nano-applications in the sub-50 nm regime. By comparison, previous traditional gas chopping techniques have produced rippled or scalloped sidewalls in a range of 50 to 100 nm roughness.

  19. Glycoconjugates and methods

    DOE Patents [OSTI]

    Bertozzi, Carolyn; Yarema, Kevin J.; Mahal, Lara K.

    2000-01-01

    Methods for making the functionalized glycoconjugates include (a) contacting a cell with a first monosaccharide, and (b) incubating the cell under conditions whereby the cell (i) internalizes the first monosaccharide, (ii) biochemically processes the first monosaccharide into a second saccharide, (iii) conjugates the saccharide to a carrier to form a glycoconjugate, and (iv) extracellularly expresses the glycoconjugate to form an extracellular glycoconjugate comprising a selectively reactive functional group. Methods for forming products at a cell further comprise contacting the functional group of the extracellularly expressed glycoconjugate with an agent which selectively reacts with the functional group to form a product. Subject compositions include cyto-compatible monosaccharides comprising a nitrogen or ether linked functional group selectively reactive at a cell surface and compositions and cells comprising such saccharides.

  20. Glycoconjugates and methods

    DOE Patents [OSTI]

    Bertozzi, Carolyn; Yarema, Kevin J.; Mahal, Lara K.

    2002-10-01

    Methods for making the functionalized glycoconjugates include (a) contacting a cell with a first monosaccharide, and (b) incubating the cell under conditions whereby the cell (i) internalizes the first monosaccharide, (ii) biochemically processes the first monosaccharide into a second saccharide, (iii) conjugates the saccharide to a carrier to form a glycoconjugate, and (iv) extracellularly expresses the glycoconjugate to form an extracellular glycoconjugate comprising a selectively reactive functional group. Methods for forming products at a cell further comprise contacting the functional group of the extracellularly expressed glycoconjugate with an agent which selectively reacts with the functional group to form a product. Subject compositions include cyto-compatible monosaccharides comprising a nitrogen or ether linked functional group selectively reactive at a cell surface and compositions and cells comprising such saccharides.

  1. Glycoconjugates And Methods

    DOE Patents [OSTI]

    Bertozzi, Carolyn; Yarema, Kevin J.; Mahal, Lara K.

    2005-08-30

    Methods for making the functionalized glycoconjugates include (a) contacting a cell with a first monosaccharide, and (b) incubating the cell under conditions whereby the cell (i) internalizes the first monosaccharide, (ii) biochemically processes the first monosaccharide into a second saccharide, (iii) conjugates the saccharide to a carrier to form a glycoconjugate, and (iv) extracellularly expresses the glycoconjugate to form an extracellular glycoconjugate comprising a selectively reactive functional group. Methods for forming products at a cell further comprise contacting the functional group of the extracellularly expressed glycoconjugate with an agent which selectively reacts with the functional group to form a product. Subject compositions include cyto-compatible monosaccharides comprising a nitrogen or ether linked functional group selectively reactive at a cell surface and compositions and cells comprising such saccharides.

  2. Glycoconjugates and methods

    DOE Patents [OSTI]

    Bertozzi, Carolyn C.; Yarema, Kevin J.; Mahal; Lara K.

    2008-04-01

    Methods for making the functionalized glycoconjugates include (a) contacting a cell with a first monosaccharide, and (b) incubating the cell under conditions whereby the cell (i) internalizes the first monosaccharide, (ii) biochemically processes the first monosaccharide into a second saccharide, (iii) conjugates the saccharide to a carrier to form a glycoconjugate, and (iv) extracellularly expresses the glycoconjugate to form an extracellular glycoconjugate comprising a selectively reactive functional group. Methods for forming products at a cell further comprise contacting the functional group of the extracellularly expressed glycoconjugate with an agent which selectively reacts with the functional group to form a product. Subject compositions include cyto-compatible monosaccharides comprising a nitrogen or ether linked functional group selectively reactive at a cell surface and compositions and cells comprising such saccharides.

  3. Reactive flash volatilization of fluid fuels

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

    2013-01-08

    The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

  4. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injectionmore » strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still

  5. Reservoir characterization based on tracer response and rank analysis of production and injection rates

    SciTech Connect (OSTI)

    Refunjol, B.T.; Lake, L.W.

    1997-08-01

    Quantification of the spatial distribution of properties is important for many reservoir-engineering applications. But, before applying any reservoir-characterization technique, the type of problem to be tackled and the information available should be analyzed. This is important because difficulties arise in reservoirs where production records are the only information for analysis. This paper presents the results of a practical technique to determine preferential flow trends in a reservoir. The technique is a combination of reservoir geology, tracer data, and Spearman rank correlation coefficient analysis. The Spearman analysis, in particular, will prove to be important because it appears to be insightful and uses injection/production data that are prevalent in circumstances where other data are nonexistent. The technique is applied to the North Buck Draw field, Campbell County, Wyoming. This work provides guidelines to assess information about reservoir continuity in interwell regions from widely available measurements of production and injection rates at existing wells. The information gained from the application of this technique can contribute to both the daily reservoir management and the future design, control, and interpretation of subsequent projects in the reservoir, without the need for additional data.

  6. Preliminary Interpretation of a Radionuclide and Colloid Tracer Test in a Granodiorite Shear Zone at the Grimsel Test Site, Switzerland

    SciTech Connect (OSTI)

    Reimus, Paul W.

    2012-08-30

    In February and March 2012, a tracer test involving the injection of a radionuclide-colloid cocktail was conducted in the MI shear zone at the Grimsel Test Site, Switzerland, as part of the Colloids Formation and Migration (CFM) project. The colloids were derived from FEBEX bentonite, which is mined in Spain and is being considered as a potential waste package backfill in a Spanish nuclear waste repository. The tracer test, designated test 12-02 (second test in 2012), involved the injection of the tracer cocktail into borehole CFM 06.002i2 and extraction from the Pinkel surface packer at the main access tunnel wall approximately 6.1 m from the injection interval. The test configuration is depicted in Figure 1. This configuration has been used in several conservative tracer tests and two colloid-homologue tracer tests since 2007, and it is will be employed in an upcoming test involving the emplacement of a radionuclide-doped bentonite plug into CFM 06.002i2 to evaluate the swelling and erosion of the bentonite and the transport of bentonite colloids and radionuclides from the source to the extraction point at the tunnel wall. Interpretive analyses of several of the previous tracer tests, from 09-01 through 12-02 were provided in two previous Used Fuel Disposition Program milestone reports (Arnold et al., 2011; Kersting et al., 2012). However, only the data for the conservative tracer Amino-G Acid was previously analyzed from test 12-02 because the other tracer data from this test were not available at the time. This report documents the first attempt to quantitatively analyze the radionuclide and colloid breakthrough curves from CFM test 12-02. This report was originally intended to also include an experimental assessment of colloid-facilitated transport of uranium by bentonite colloids in the Grimsel system, but this assessment was not conducted because it was reported by German collaborators at the Karlsruhe Institute of Technology (KIT) that neither uranium nor

  7. Regional respiratory tract absorption of inhaled reactive gases

    SciTech Connect (OSTI)

    Miller, F.J.; Overton, J.H.; Kimbell, J.S.; Russell, M.L.

    1992-06-29

    Highly reactive gases present unique problems due to the number of factors which must be taken into account to determine regional respiratory tract uptake. The authors reviewed some of the physical, chemical, and biological factors that affect dose and that must be understood to interpret toxicological data, to evaluate experimental dosimetry studies, and to develop dosimetry models. Selected dosimetry experiments involving laboratory animals and humans were discussed, showing the variability and uptake according to animal species and respiratory tract region for various reactive gases. New experimental dosimetry approaches, such as those involving isotope ratio mass spectroscopy and cyclotron generation reactive gases, were discussed that offer great promise for improving the ability to study regional respiratory tract absorption of reactive gases. Various dosimetry modeling applications were discussed which demonstrate: the importance of airflow patterns for site-specific dosimetry in the upper respiratory tract, the influence of the anatomical model used to make inter- and intraspecies dosimetric comparisons, the influence of tracheobronchial path length on predicted dose curves, and the implications of ventilatory unit structure and volume on dosimetry and response. Collectively, these examples illustrate important aspects of regional respiratory tract absorption of inhaled reactive gases. Given the complex nature of extent and pattern of injury in the respiratory tract from exposure to reactive gases, understanding interspecies differences in the absorption of reactive gases will continue to be an important area for study.

  8. Method of detecting leakage from geologic formations used to sequester CO.sub.2

    DOE Patents [OSTI]

    White, Curt; Wells, Arthur; Diehl, J. Rodney; Strazisar, Brian

    2010-04-27

    The invention provides methods for the measurement of carbon dioxide leakage from sequestration reservoirs. Tracer moieties are injected along with carbon dioxide into geological formations. Leakage is monitored by gas chromatographic analyses of absorbents. The invention also provides a process for the early leak detection of possible carbon dioxide leakage from sequestration reservoirs by measuring methane (CH.sub.4), ethane (C.sub.2H.sub.6), propane (C.sub.3H.sub.8), and/or radon (Rn) leakage rates from the reservoirs. The invention further provides a method for branding sequestered carbon dioxide using perfluorcarbon tracers (PFTs) to show ownership.

  9. Experimental Observation of Quantum Oscillation of Surface Chemical Reactivities

    SciTech Connect (OSTI)

    Ma, X.; Jiang, P.; Qi, Y.; Jia, J.; Yang, Y.; Duan, W.; Li, W. X.; Bao, X.; Zhang, S. B.

    2007-05-29

    Here we present direct observation of a quantum reactivity with respect to the amounts of O2 adsorbed and the rates of surface oxidation as a function of film thickness on ultrathin (2-6 nm) Pb mesas by scanning tunneling microscopy. Simultaneous spectroscopic measurements on the electronic structures reveal a quantum oscillation that originates from quantum well states of the mesas, as a generalization of the Fabry-P{acute e}rot modes of confined electron waves. We expect the quantum reactivity to be a general phenomenon for most ultrathin metal films with broad implications, such as nanostructure tuning of surface reactivities and rational design of heterogeneous catalysts.

  10. Demonstration of the BNL Continuous Dual Trap Analyzer to Detect Perfluorocarbon Tracers for the Tag, Track and Location Program

    SciTech Connect (OSTI)

    Heiser,J.H.; Adams, J.; Dietz, R..; Milian, L.; Watson, T.

    2008-10-07

    The Tag, Track and Location System (TTL) Program is investigating methods of tracking an asset using perfluorocarbon tracers (PFT). The success of any TTL method requires sound detection/location instrumentation. Tracer Detection Technologies Corp (TDT), through a contract with the Office of Naval Research (ONR), is investigating different detection systems. The detections systems generally fall into two categories; proximity detectors and standoff detectors. Proximity detectors, as the name implies, need to be in close proximity (e.g., meter to 10's of meters) to the PFT source. Standoff detection searches for the PFT from a greater distance away from the source (e.g., 100's of meters to kilometers). Gas Chromatographs (GC) are generally considered a proximity detection systems, but in the case of PFTs should be considered for both proximity and standoff detection with the caveat that in standoff use the GC needs to be somewhere in the PFT plume, i.e., generally downwind of the source. With a properly sized PFT source, the right GC can afford fairly large standoff (distance from the source) distances; 100's of meters to kilometers downwind. Brookhaven National Laboratory (BNL) has such a GC system and offered to demonstrate the CDTA for TTL as a no cost addition to the TDTTTL project, of which BNL was a participant. BNL is a leading authority on the sampling, collection, release and detection of PFTs. In addition, the BNL team has extensive background in atmospheric dispersion, the application of PFTs to such studies and the development of applications utilizing PFTs such as building infiltration measurements, control room integrity determination, leak location and environmental investigations. This experience and expertise is essential in developing any PFT application were dispersion, dilution and overcoming environmental conditions and interferences are integral to success. BNL has developed sophisticated gas chromatography methods and instruments that allow

  11. Flash pyrolysis of biomass with reactive and non-reactive gases

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1984-03-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H/sub 2/ and CH/sub 4/ and with the non-reactive gases He and N/sub 2/ is being determined in an 1'' downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000/sup 0/C. With hydrogen, flash hydropyrolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000/sup 0/C and approximately 1 sec residence time, the ethylene yield based on pine wood carbon conversion is 27%, for benzene it is 25% and for CO the yield is 39%, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood. The yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, thus indicating a free radical reaction between CH/sub 4/ and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicate an economically competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 7 references, 13 figures, 1 table.

  12. Analysis of three sets of SWIW tracer-test data using a two-population complex fracture model for matrix diffusion and sorption

    SciTech Connect (OSTI)

    Doughty, C.; Tsang, C.F.

    2009-08-01

    A complex fracture model employing two populations for diffusion and sorption is proposed to analyze three representative single-well injection-withdrawal (SWIW) tracer tests from Forsmark and Laxemar, the two sites under investigation by the Swedish Nuclear Fuel and Waste Management Company (SKB). One population represents the semi-infinite rock matrix and the other represents finite blocks that can become saturated, thereafter accepting no further diffusion or sorption. The diffusion and sorption parameters of the models are inferred by matching tracer breakthrough curves (BTCs). Three tracers are simultaneously injected, uranine (Ur), which is conservative, and rubidium (Rb) and cesium (Cs), which are non-conservative. For non-sorbing tracer uranine, the finite blocks become saturated with test duration of the order of 10 hours, and both the finite and the semi-infinite populations play a distinct role in controlling BTCs. For sorbing tracers Rb and Cs, finite blocks do not saturate, but act essentially as semi-infinite, and thus BTC behavior is comparable to that obtained for a model containing only a semi-infinite rock matrix. The ability to obtain good matches to BTCs for both sorbing and non-sorbing tracers for these three different SWIW data sets demonstrates that the two-population complex fracture model may be a useful conceptual model to analyze all SWIW tracer tests in fractured rock, and perhaps also usual multiwell tracer tests. One of the two populations should be semi-infinite rock matrix and the other finite blocks that can saturate. The latter can represent either rock blocks or gouge within the fracture, a fracture skin zone, or stagnation zones.

  13. Unnatural reactive amino acid genetic code additions

    SciTech Connect (OSTI)

    Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

    2014-08-26

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  14. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

    2011-08-09

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNAsyn-thetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  15. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander; Cropp, Ashton T; Chin, Jason W; Anderson, Christopher J; Schultz, Peter G

    2013-05-21

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  16. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

    2011-02-15

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  17. Well ER-6-1 Tracer Test Analysis: Yucca Flat, Nevada Test Site, Nye County, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Greg Ruskauff

    2006-09-01

    The ER-6-1 multiple-well aquifer test-tracer test (MWAT-TT) investigated groundwater flow and transport processes relevant to the transport of radionuclides from sources on the Nevada Test Site (NTS) through the lower carbonate aquifer (LCA) hydrostratigraphic unit (HSU). The LCA, which is present beneath much of the NTS, is the principal aquifer for much of southern Nevada. This aquifer consists mostly of limestone and dolomite, and is pervasively fractured. Groundwater flow in this aquifer is primarily in the fractures, and the hydraulic properties are primarily related to fracture frequency and fracture characteristics (e.g., mineral coatings, aperture, connectivity). The objective of the multiple-well aquifer test (MWAT) was to determine flow and hydraulic characteristics for the LCA in Yucca Flat. The data were used to derive representative flow model and parameter values for the LCA. The items of specific interest are: Hydraulic conductivity; Storage parameters; Dual-porosity behavior; and Fracture flow characteristics. The objective of the tracer transport experiment was to evaluate the transport properties and processes of the LCA and to derive representative transport parameter values for the LCA. The properties of specific interest are: Effective porosity; Matrix diffusion; Longitudinal dispersivity; Adsorption characteristics; and Colloid transport characteristics. These properties substantially control the rate of transport of contaminants in the groundwater system and concentration distributions. To best support modeling at the scale of the corrective action unit (CAU), these properties must be investigated at the field scale. The processes represented by these parameters are affected by in-situ factors that are either difficult to investigate at the laboratory scale or operate at a much larger scale than can be reproduced in the laboratory. Measurements at the field scale provide a better understanding of the effective average parameter values. The

  18. Pebble Fuel Handling and Reactivity Control for Salt-Cooled High...

    Office of Scientific and Technical Information (OSTI)

    and Reactivity Control for Salt-Cooled High Temperature Reactors Citation Details In-Document Search Title: Pebble Fuel Handling and Reactivity Control for Salt-Cooled High ...

  19. Coupled hydro-mechanical processes and fault reactivation induced...

    Office of Scientific and Technical Information (OSTI)

    Coupled hydro-mechanical processes and fault reactivation induced by Co2 Injection in a three-layer storage formation Citation Details In-Document Search This content will become ...

  20. Laboratory and field scale demonstration of reactive barrier systems

    SciTech Connect (OSTI)

    Dwyer, B.P.; Marozas, D.C.; Cantrell, K.; Stewart, W.

    1996-10-01

    In an effort to devise a cost efficient technology for remediation of uranium contaminated groundwater, the Department of Energy`s Uranium Mill Tailings Remedial Action (DOE-UMTRA) Program through Sandia National Laboratories (SNL) fabricated a pilot scale research project utilizing reactive subsurface barriers at an UMTRA site in Durango, Colorado. A reactive subsurface barrier is produced by placing a reactant material (in this experiment, metallic iron) in the flow path of the contaminated groundwater. The reactive media then removes and/or transforms the contaminant(s) to regulatory acceptable levels. Experimental design and results are discussed with regard to other potential applications of reactive barrier remediation strategies at other sites with contaminated groundwater problems.

  1. Pre-plated reactive diffusion-bonded battery electrode plaques

    DOE Patents [OSTI]

    Maskalick, Nicholas J.

    1984-01-01

    A high strength, metallic fiber battery plaque is made using reactive diffusion bonding techniques, where a substantial amount of the fibers are bonded together by an iron-nickel alloy.

  2. Reactivity of Chromium(III) Nutritional Supplements in Biological...

    Office of Scientific and Technical Information (OSTI)

    Reactivities of Cr(III) complexes used in nutritional formulations, including Cr3O(OCOEt)6(OH2)3+ (A), Cr(pic)3 (pic) 2-pyridinecarboxylato(-) (B), and trans-CrCl2(OH2)4+ ...

  3. Highly reactive light-dependent monoterpenes in the Amazon

    SciTech Connect (OSTI)

    Jardine, A. B.; Jardine, K. J.; Fuentes, J. D.; Martin, S. T.; Martins, G.; Durgante, F.; Carneiro, V.; Higuchi, N.; Manzi, A. O.; Chambers, J. Q.

    2015-03-06

    Despite orders of magnitude difference in atmospheric reactivity and great diversity in biological functioning, little is known about monoterpene speciation in tropical forests. Here we report vertically resolved ambient air mixing ratios for 12 monoterpenes in a central Amazon rainforest including observations of the highly reactive cis-β-ocimene (160 ppt), trans-β-ocimene (79 ppt), and terpinolene (32 ppt) which accounted for an estimated 21% of total monoterpene composition yet 55% of the upper canopy monoterpene ozonolysis rate. All 12 monoterpenes showed a mixing ratio peak in the upper canopy, with three demonstrating subcanopy peaks in 7 of 11 profiles. Leaf level emissions of highly reactive monoterpenes accounted for up to 1.9% of photosynthesis confirming light-dependent emissions across several Amazon tree genera. These results suggest that highly reactive monoterpenes play important antioxidant roles during photosynthesis in plants and serve as near-canopy sources of secondary organic aerosol precursors through atmospheric photooxidation via ozonolysis.

  4. Hydrogen absorption characteristics of amorphous LaNi[sub 5. 0] films prepared by reactive sputtering

    SciTech Connect (OSTI)

    Sakaguchi, H.; Tsujimoto, T.; Adachi, Ginya (Osaka University, Suita (Japan))

    1993-01-01

    Amorphous LaNi[sub 5] thin films are expected to be one of the promising materials for use in hydrogen separation and battery electrodes, because the durability of the films is great in regard to the hydrogen absorption-desorption cycling process and the films have excellent resistance to harmful impurities in the hydrogen gas in comparison with the crystalline bulk material. An amorphous LaNi[sub 5.0] film having high hydrogen density and low hydrogen-induced stress was obtained by means of a reactive sputtering method using an Ar-H[sub 2] gas mixture. Pressure-composition isotherms show that the amount of hydrogen (H/LaNi[sub 5.0]) taken up by a formula weight of LaNi[sub 5.0] is about 1.5 times larger for the reactive sputtered film than for the conventional sputtered film prepared by using Ar gas. 18 refs., 1 fig, 1 tabs.

  5. On the late-time behavior of tracer test breakthrough curves

    SciTech Connect (OSTI)

    HAGGERTY,ROY; MCKENNA,SEAN A.; MEIGS,LUCY C.

    2000-06-12

    The authors investigated the late-time (asymptotic) behavior of tracer test breakthrough curves (BTCs) with rate-limited mass transfer (e.g., in dual or multi-porosity systems) and found that the late-time concentration, c, is given by the simple expression: c = t{sub ad} (c{sub 0}g {minus} m{sub 0}{partial_derivative}g/{partial_derivative}t), for t >> t{sub ad} and t{sub a} >> t{sub ad} where t{sub ad} is the advection time, c{sub 0} is the initial concentration in the medium, m{sub 0} is the 0th moment of the injection pulse; and t{sub a} is the mean residence time in the immobile domain (i.e., the characteristic mass transfer time). The function g is proportional to the residence time distribution in the immobile domain, the authors tabulate g for many geometries, including several distributed (multirate) models of mass transfer. Using this expression they examine the behavior of late-time concentration for a number of mass transfer models. One key results is that if rate-limited mass transfer causes the BTC to behave as a power-law at late-time (i.e., c {approximately} t{sup {minus}k}), then the underlying density function of rate coefficients must also be a power-law with the form a{sup k{minus}}, as a {r_arrow}0. This is true for both density functions of first-order and diffusion rate coefficients. BTCs with k < 3 persisting to the end of the experiment indicate a mean residence time longer than the experiment and possibly infinite, and also suggest an effective rate coefficient that is either undefined or changes as a function of observation time. They apply their analysis to breakthrough curves from Single-Well Injection-Withdrawal tests at the Waste Isolation Pilot Plant, New Mexico.

  6. [C II] 158 μm EMISSION AS A STAR FORMATION TRACER

    SciTech Connect (OSTI)

    Herrera-Camus, R.; Bolatto, A. D.; Wolfire, M. G.; Smith, J. D.; Croxall, K. V.; Kennicutt, R. C.; Boquien, M.; Calzetti, D.; Helou, G.; Walter, F.; Meidt, S. E.; Leroy, A. K.; Draine, B.; Brandl, B. R.; Armus, L.; Sandstrom, K. M.; Dale, D. A.; Aniano, G.; Hunt, L. K.; Galametz, M.; and others

    2015-02-10

    The [C II] 157.74 μm transition is the dominant coolant of the neutral interstellar gas, and has great potential as a star formation rate (SFR) tracer. Using the Herschel KINGFISH sample of 46 nearby galaxies, we investigate the relation of [C II] surface brightness and luminosity with SFR. We conclude that [C II] can be used for measurements of SFR on both global and kiloparsec scales in normal star-forming galaxies in the absence of strong active galactic nuclei (AGNs). The uncertainty of the Σ{sub [C} {sub II]} – Σ{sub SFR} calibration is ±0.21 dex. The main source of scatter in the correlation is associated with regions that exhibit warm IR colors, and we provide an adjustment based on IR color that reduces the scatter. We show that the color-adjusted Σ{sub [C} {sub II]} – Σ{sub SFR} correlation is valid over almost five orders of magnitude in Σ{sub SFR}, holding for both normal star-forming galaxies and non-AGN luminous infrared galaxies. Using [C II] luminosity instead of surface brightness to estimate SFR suffers from worse systematics, frequently underpredicting SFR in luminous infrared galaxies even after IR color adjustment (although this depends on the SFR measure employed). We suspect that surface brightness relations are better behaved than the luminosity relations because the former are more closely related to the local far-UV field strength, most likely the main parameter controlling the efficiency of the conversion of far-UV radiation into gas heating. A simple model based on Starburst99 population-synthesis code to connect SFR to [C II] finds that heating efficiencies are 1%-3% in normal galaxies.

  7. Isotopic tracer studies of Fischer-Tropsch Synthesis over Ru/TiO sub 2 catalysts

    SciTech Connect (OSTI)

    Krishna, K.R.

    1992-01-01

    Fischer-Tropsch synthesis is a process in which CO and H{sub 2} react to give predominantly liquid hydrocarbons. The reaction can be considered a special type of polymerization in which the monomer is produced in situ, and chain growth occurs by a sequence of independently repeated additions of the monomer to the growing chain. A investigation has been conducted to study the CO hydrogenation reaction in order to better understand catalyst deactivation and the elementary surface processes involved in chain growth. Isotopic tracers are used in conjunction with transient-response techniques in this study of Fischer-Tropsch synthesis over Ru/TiO{sub 2} catalysts. Experiments are conducted at a total pressure of 1 atmosphere, reaction temperatures of 453--498 K and D{sub 2}/CO (or H{sub 2}/CO) ratios of 2--5. Synthesis products are analyzed by gas chromatography or isotope-ratio gas chromatography-mass spectrometry. Rate constants for chain initiation, propagation and termination are evaluated under steady-state reaction conditions by using transients in isotopic composition. The activation energy for chain termination is much higher than that for propagation, accounting for the observed decrease in the chain growth parameter are also estimated. Coverages by reaction intermediates are also estimated. When small amounts of {sup 12}C-labelled ethylene are added to {sup 13}CO/H{sub 2} synthesis gas, ethylene acts as the sole chain initiator. Ethylene-derived carbon also accounts for 45% of the C{sub 1} monomer pool. 102 refs., 29 figs., 11 tabs.

  8. Isotopic tracer studies of Fischer-Tropsch Synthesis over Ru/TiO{sub 2} catalysts

    SciTech Connect (OSTI)

    Krishna, K.R.

    1992-01-01

    Fischer-Tropsch synthesis is a process in which CO and H{sub 2} react to give predominantly liquid hydrocarbons. The reaction can be considered a special type of polymerization in which the monomer is produced in situ, and chain growth occurs by a sequence of independently repeated additions of the monomer to the growing chain. A investigation has been conducted to study the CO hydrogenation reaction in order to better understand catalyst deactivation and the elementary surface processes involved in chain growth. Isotopic tracers are used in conjunction with transient-response techniques in this study of Fischer-Tropsch synthesis over Ru/TiO{sub 2} catalysts. Experiments are conducted at a total pressure of 1 atmosphere, reaction temperatures of 453--498 K and D{sub 2}/CO (or H{sub 2}/CO) ratios of 2--5. Synthesis products are analyzed by gas chromatography or isotope-ratio gas chromatography-mass spectrometry. Rate constants for chain initiation, propagation and termination are evaluated under steady-state reaction conditions by using transients in isotopic composition. The activation energy for chain termination is much higher than that for propagation, accounting for the observed decrease in the chain growth parameter are also estimated. Coverages by reaction intermediates are also estimated. When small amounts of {sup 12}C-labelled ethylene are added to {sup 13}CO/H{sub 2} synthesis gas, ethylene acts as the sole chain initiator. Ethylene-derived carbon also accounts for 45% of the C{sub 1} monomer pool. 102 refs., 29 figs., 11 tabs.

  9. Reactive MD Simulation of Shock-Induced Cavitation Damage | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Leadership Computing Facility Billion atom reactive molecular dynamics simulation of nanobubble collapse in wa Billion atom reactive molecular dynamics simulation of nanobubble collapse in water near a ceramic surface under shock compression. A 2km/sec shock wave compresses the nanobubble and creates high compressive stress and novel chemical reactions (production of hydronium ions) not found under normal conditions. The simulations reveal that high pressure in the shock wave deforms the

  10. (Electronic structure and reactivities of transition metal clusters)

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

  11. Project Profile: Chemically Reactive Working Fluids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemically Reactive Working Fluids Project Profile: Chemically Reactive Working Fluids ANL logo -- This project is inactive -- Argonne National Laboratory (ANL), under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), is working to identify and test new heat-transfer fluids (HTFs) that store energy chemically for more efficient energy transfer in CSP applications. Approach Chart with an upward curve with ideal power generation efficiency on the

  12. Reactive and Catalytic Air Purification Materials - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Building Energy Efficiency Building Energy Efficiency Advanced Materials Advanced Materials Find More Like This Return to Search Reactive and Catalytic Air Purification Materials Naval Research Laboratory Contact NRL About This Technology Publications: PDF Document Publication AirPurification (546 KB) Technology Marketing SummarySorbents for the removal of toxic in-dustrial gases such as ammonia and phosgene. The materials offer reactive and/or catalytic sites within a high surface

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 8, July--September 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 9, October--December 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  15. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report No. 3, April--June 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  16. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 2, January--March 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  17. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 1, Bench-scale testing and analysis

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  18. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 7, April--June 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  19. An adaptive sparse-grid high-order stochastic collocation method...

    Office of Scientific and Technical Information (OSTI)

    stochastic collocation method for Bayesian inference in groundwater reactive transport modeling Zhang, Guannan ORNL; Webster, Clayton G ORNL; Gunzburger, Max D ORNL...

  20. A reaction-based paradigm to model reactive chemical transport in groundwater with general kinetic and equilibrium reactions

    SciTech Connect (OSTI)

    Zhang, Fan; Yeh, Gour-Tsyh; Parker, Jack C; Brooks, Scott C; Pace, Molly; Kim, Young Jin; Jardine, Philip M; Watson, David B

    2007-01-01

    This paper presents a reaction-based water quality transport model in subsurface flow systems. Transport of chemical species with a variety of chemical and physical processes is mathematically described by M partial differential equations (PDEs). Decomposition via Gauss-Jordan column reduction of the reaction network transforms M species reactive transport equations into two sets of equations: a set of thermodynamic equilibrium equations representing NE equilibrium reactions and a set of reactive transport equations of M-NE kinetic-variables involving no equilibrium reactions (a kinetic-variable is a linear combination of species). The elimination of equilibrium reactions from reactive transport equations allows robust and efficient numerical integration. The model solves the PDEs of kinetic-variables rather than individual chemical species, which reduces the number of reactive transport equations and simplifies the reaction terms in the equations. A variety of numerical methods are investigated for solving the coupled transport and reaction equations. Simulation comparisons with exact solutions were performed to verify numerical accuracy and assess the effectiveness of various numerical strategies to deal with different application circumstances. Two validation examples involving simulations of uranium transport in soil columns are presented to evaluate the ability of the model to simulate reactive transport with complex reaction networks involving both kinetic and equilibrium reactions.

  1. Flash pyrolysis of biomass with reactive and non-reactive gases

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1985-03-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H/sub 2/ and CH/sub 4/ and with the non-reactive gases He and N/sub 2/ is being determined in a 1'' downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000/sup 0/C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000/sup 0/C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 30% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH/sub 4/ and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates an economically competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 8 refs., 18 figs., 1 tab.

  2. In situ formation of magnetite reactive barriers in soil for waste stabilization

    DOE Patents [OSTI]

    Moore, Robert C.

    2003-01-01

    Reactive barriers containing magnetite and methods for making magnetite reactive barriers in situ in soil for sequestering soil contaminants including actinides and heavy metals, organic materials, iodine and technetium are disclosed. According to one embodiment, a two-step reagent introduction into soil takes place. In the first step, free oxygen is removed from the soil by separately injecting into the soil aqueous solutions of iron (II) salt, for example FeCl.sub.2, and base, for example NaOH or NH.sub.3 in about a 1:1 volume ratio. Then, in the second step, similar reagents are injected a second time (however, according to about a 1:2 volume ratio, iron to salt) to form magnetite. The magnetite formation is facilitated, in part, due to slow intrusion of oxygen into the soil from the surface. The invention techniques are suited to injection of reagents into soil in proximity to a contamination plume or source allowing in situ formation of the reactive barrier at the location of waste or hazardous material. Mixing of reagents to form. precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

  3. GEOCENTRIFUGE STUDIES OF FLOW AND TRANSPORT IN POROUS MEDIA, FINAL REPORT FOR GRANT NUMBER DE-FG02-03ER63567 TO THE UNIVERSITY OF IDAHO (RW SMITH), ENVIRONMENTAL MANAGEMENT SCIENCE PROGRAM PROJECT NUMBER 86598, COUPLED FLOW AND REACTIVITY IN VARIABLY SATURATED POROUS MEDIA

    SciTech Connect (OSTI)

    Robert W. Smith; Carl D. Palmer; Earl D. Mattson

    2007-06-15

    is in its infancy experimental apparatus such as pumps, flow meters, columns, fraction collectors, etc. that would reliably function under the increased self weight experienced on the centrifuge had to be developed and tested as part of this project. Although, we initially planed to conduct experiments using reactive tracer and 2-dimensional heterogeneities, the cost and time associated with designing, building, and testing of experimental apparatus limited our experimental program to conservative tracer experiments using 1-dimensional columns. The results we obtained in this study indicate that the geocentrifuge technique is a viable experimental method for the study of subsurface processes where gravitational acceleration is important. The geocentrifuge allows experiments to be completed more quickly than tests conducted at 1-g, can be used to experimentally address important scaling issues, and permits experiments under a range of conditions that would be difficult or impossible using conventional approaches. The application of the geocentrifuge approaches and associated models developed in this project allows more meaningful investigation of DOE relevant vadose-zone issues under scalable conditions in time frames previously not obtainable.

  4. Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

    Broader source: Energy.gov [DOE]

    Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

  5. Fuel reactivity effects on the efficiency and operational window of dual-fuel compression ignition engines

    SciTech Connect (OSTI)

    Splitter, Derek A; Reitz, Rolf

    2014-01-01

    Fuel reactivity effects on the efficiency and operational window of dual-fuel compression ignition engines

  6. Kinetics and mechanisms of reactions involving small aromatic reactive intermediates

    SciTech Connect (OSTI)

    Lin, M.C.

    1993-12-01

    Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

  7. Measurement of the Tracer Gradient and Sampling System Bias of the Hot Fuel Examination Facility Stack Air Monitoring System

    SciTech Connect (OSTI)

    Glissmeyer, John A.; Flaherty, Julia E.

    2011-07-20

    This report describes tracer gas uniformity and bias measurements made in the exhaust air discharge of the Hot Fuel Examination Facility at Idaho National Laboratory. The measurements were a follow-up on earlier measurements which indicated a lack of mixing of the two ventilation streams being discharged via a common stack. The lack of mixing is detrimental to the accuracy of air emission measurements. The lack of mixing was confirmed in these new measurements. The air sampling probe was found to be out of alignment and that was corrected. The suspected sampling bias in the air sample stream was disproved.

  8. Assessment of the Economic Benefits from Reactive Power Compensation

    SciTech Connect (OSTI)

    Li, Fangxing; Kueck, John D; Rizy, D Tom; Tolbert, Leon M; Zhang, Wenjuan

    2006-01-01

    The U.S. power industry is under great pressure to provide reactive power or Var support. Although it is generally known that there are technical benefits for utilities and industrial customers to provide local reactive power support, a thorough quantitative investigation of the economic benefit is greatly needed. This paper seeks to provide a quantitative approach to evaluate the benefits from local reactive power compensation. This paper investigates the benefits including reduced losses, shifting reactive power flow to real power flow, and increased transfer capability. These benefits are illustrated with a simple two-bus model and then presented with a more complicated model using Optimal Power Flow. Tests are conducted on a system with seven buses in two areas. These simulations show that the economic benefits can be significant, if compared with capacity payment to central generators or power factor penalties applied to utilities. This economic value may give utilities a better understanding of the Var benefits to assist their cost-benefit analysis for Var compensation. In addition, since the economic benefits are significant, this paper suggests that the future reactive power market should consider local Var providers.

  9. The ReaxFF reactive force-field: Development, applications, and future directions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Senftle, Thomas; Hong, Sungwook; Islam, Md Mahbubul; Kylasa, Sudhir; Zheng, Yuanzia; Shin, Yun Kyung; Junkermeier, Chad; Engel-Herbert, Roman; Janik, Michael J.; Aktulga, Hasan Metin; et al

    2016-03-04

    The reactive force-field (ReaxFF) interatomic potential is a powerful computational tool for exploring, developing and optimizing material properties. Methods based on the principles of quantum mechanics (QM), while offering valuable theoretical guidance at the electronic level, are often too computationally intense for simulations that consider the full dynamic evolution of a system. Alternatively, empirical interatomic potentials that are based on classical principles require significantly fewer computational resources, which enables simulations to better describe dynamic processes over longer timeframes and on larger scales. Such methods, however, typically require a predefined connectivity between atoms, precluding simulations that involve reactive events. The ReaxFFmore » method was developed to help bridge this gap. Approaching the gap from the classical side, ReaxFF casts the empirical interatomic potential within a bond-order formalism, thus implicitly describing chemical bonding without expensive QM calculations. As a result, this article provides an overview of the development, application, and future directions of the ReaxFF method.« less

  10. An adaptive sparse-grid high-order stochastic collocation method for

    Office of Scientific and Technical Information (OSTI)

    Bayesian inference in groundwater reactive transport modeling (Technical Report) | SciTech Connect An adaptive sparse-grid high-order stochastic collocation method for Bayesian inference in groundwater reactive transport modeling Citation Details In-Document Search Title: An adaptive sparse-grid high-order stochastic collocation method for Bayesian inference in groundwater reactive transport modeling Although Bayesian analysis has become vital to the quantification of prediction uncertainty

  11. Si etching with reactive neutral beams of very low energy

    SciTech Connect (OSTI)

    Hara, Yasuhiro; Hamagaki, Manabu; Mise, Takaya; Iwata, Naotaka; Hara, Tamio

    2014-12-14

    A Si etching process has been investigated with reactive neutral beams (NBs) extracted using a low acceleration voltage of less than 100 V from CF{sub 4} and Ar mixed plasmas. The etched Si profile shows that the etching process is predominantly anisotropic. The reactive NB has a constant Si etching rate in the acceleration voltage range from 20 V to 80 V. It is considered that low-energy NBs can trigger Si etching because F radicals adsorb onto the Si surface and weaken Si–Si bonds. The etching rate per unit beam flux is 33 times higher than that with Ar NB. These results show that the low-energy reactive NB is useful for damage-free high speed Si etching.

  12. Increasing Class C fly ash reduces alkali silica reactivity

    SciTech Connect (OSTI)

    Hicks, J.K.

    2007-07-01

    Contrary to earlier studies, it has been found that incremental additions of Class C fly ash do reduce alkali silica reactivity (ASR), in highly reactive, high alkali concrete mixes. AST can be further reduced by substituting 5% metakaolin or silica fume for the aggregate in concrete mixes with high (more than 30%) Class C fly ash substitution. The paper reports results of studies using Class C fly ash from the Labadie Station plant in Missouri which typically has between 1.3 and 1.45% available alkalis by ASTM C311. 7 figs.

  13. Approximate photochemical dynamics of azobenzene with reactive force fields

    SciTech Connect (OSTI)

    Li, Yan; Hartke, Bernd

    2013-12-14

    We have fitted reactive force fields of the ReaxFF type to the ground and first excited electronic states of azobenzene, using global parameter optimization by genetic algorithms. Upon coupling with a simple energy-gap transition probability model, this setup allows for completely force-field-based simulations of photochemical cis?trans- and trans?cis-isomerizations of azobenzene, with qualitatively acceptable quantum yields. This paves the way towards large-scale dynamics simulations of molecular machines, including bond breaking and formation (via the reactive force field) as well as photochemical engines (presented in this work)

  14. Infiltration processing of boron carbide-, boron-, and boride-reactive metal cermets

    DOE Patents [OSTI]

    Halverson, Danny C.; Landingham, Richard L.

    1988-01-01

    A chemical pretreatment method is used to produce boron carbide-, boron-, and boride-reactive metal composites by an infiltration process. The boron carbide or other starting constituents, in powder form, are immersed in various alcohols, or other chemical agents, to change the surface chemistry of the starting constituents. The chemically treated starting constituents are consolidated into a porous ceramic precursor which is then infiltrated by molten aluminum or other metal by heating to wetting conditions. Chemical treatment of the starting constituents allows infiltration to full density. The infiltrated precursor is further heat treated to produce a tailorable microstructure. The process at low cost produces composites with improved characteristics, including increased toughness, strength.

  15. Low-load indentation behavior of HfN thin films deposited by reactive rf sputtering

    SciTech Connect (OSTI)

    Nowak, R.; Li, C.L.; Maruno, S.

    1997-01-01

    Deformation of HfN thin films deposited by reactive sputtering method on silicon and alumina substrates has been investigated using depth-sensing indentation. The experiments performed in a low load range (2{endash}50 mN) revealed that the even extremely shallow indentations were affected by elastic/plastic response of the substrate. The analysis of the shape of the indentation load-depth hysteresis loops and of conventional hardness data was supplemented by considerations based on the recently proposed energy principle of indentation. {copyright} {ital 1997 Materials Research Society.}

  16. Reactivity of North Bohemian coals in coprocessing of coal/oil mixtures

    SciTech Connect (OSTI)

    Sebor, G.; Cerny, J.; Maxa, D.; Blazek, J.; Sykorova, I.

    1995-12-01

    Autoclave experiments with North Bohemian coal were done in order to evaluate their reactivity in coprocessing with petroleum vacuum residue, Selected coals were comprehensively characterized by using a number of analytical methods. While the coals were of similar geological origin, some of their characteristics differed largely from one coal to another. Despite the differences in physical and chemical structure, the coals provided very similar yields of desired reaction products. The yields of a heavy non- distillable fraction and/or an insoluble solid residue were, under experimental conditions, largely affected by retrogressive reactions (coking). The insoluble solid fractions were examined microscopically under polarized light.

  17. Highly reactive light-dependent monoterpenes in the Amazon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jardine, A. B.; Jardine, K. J.; Fuentes, J. D.; Martin, S. T.; Martins, G.; Durgante, F.; Carneiro, V.; Higuchi, N.; Manzi, A. O.; Chambers, J. Q.

    2015-03-06

    Despite orders of magnitude difference in atmospheric reactivity and great diversity in biological functioning, little is known about monoterpene speciation in tropical forests. Here we report vertically resolved ambient air mixing ratios for 12 monoterpenes in a central Amazon rainforest including observations of the highly reactive cis-β-ocimene (160 ppt), trans-β-ocimene (79 ppt), and terpinolene (32 ppt) which accounted for an estimated 21% of total monoterpene composition yet 55% of the upper canopy monoterpene ozonolysis rate. All 12 monoterpenes showed a mixing ratio peak in the upper canopy, with three demonstrating subcanopy peaks in 7 of 11 profiles. Leaf level emissionsmore » of highly reactive monoterpenes accounted for up to 1.9% of photosynthesis confirming light-dependent emissions across several Amazon tree genera. These results suggest that highly reactive monoterpenes play important antioxidant roles during photosynthesis in plants and serve as near-canopy sources of secondary organic aerosol precursors through atmospheric photooxidation via ozonolysis.« less

  18. Neutron economic reactivity control system for light water reactors

    DOE Patents [OSTI]

    Luce, Robert G.; McCoy, Daniel F.; Merriman, Floyd C.; Gregurech, Steve

    1989-01-01

    A neutron reactivity control system for a LWBR incorporating a stationary seed-blanket core arrangement. The core arrangement includes a plurality of contiguous hexagonal shaped regions. Each region has a central and a peripheral blanket area juxapositioned an annular seed area. The blanket areas contain thoria fuel rods while the annular seed area includes seed fuel rods and movable thoria shim control rods.

  19. NO2 oxidation reactivity and burning mode of diesel particulates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Strzelec, Andrea; Vander Wal, Randy L.; Thompson, Thomas N.; Toops, Todd J.; Daw, C. Stuart

    2016-03-24

    The NO2 oxidation kinetics and burning mode for diesel particulate from light-duty and medium-duty engines fueled with either ultra low sulfur diesel or soy methyl ester biodiesel blends have been investigated and are shown to be significantly different from oxidation by O2. Oxidation kinetics were measured using a flow-through packed bed microreactor for temperature programmed reactions and isothermal differential pulsed oxidation reactions. The burning mode was evaluated using the same reactor system for flowing BET specific surface area measurements and HR-TEM with fringe analysis to evaluate the nanostructure of the nascent and partially oxidized particulates. The low activation energy measured,more » specific surface area progression with extent of oxidation, HR-TEM images and difference plots of fringe length and tortuosity paint a consistent picture of higher reactivity for NO2, which reacts indiscriminately immediately upon contact with the surface, leading to the Zone I or shrinking core type oxidation. In comparison, O2 oxidation is shown to have relatively lower reactivity, preferentially attacking highly curved lamella, which are more reactive due to bond strain, and short lamella, which have a higher proportion of more reactive edge sites. Furthermore, this preferential oxidation leads to Zone II type oxidation, where solid phase diffusion of oxygen via pores contributes significantly to slowing the overall oxidation rate, by comparison.« less

  20. Local control of reactive power by distributed photovoltaic generators

    SciTech Connect (OSTI)

    Chertkov, Michael; Turitsyn, Konstantin; Sulc, Petr; Backhaus, Scott

    2010-01-01

    High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the real power generated by the PVs. Using one adjustable parameter per circuit, we balance the requirements on power quality and desire to minimize thermal losses. Numerical analysis of two exemplary systems, with comparable total PV generation albeit a different spatial distribution, show how to adjust the optimization parameter depending on the goal. Overall, this local scheme shows excellent performance; it's capable of guaranteeing acceptable power quality and achieving significant saving in thermal losses in various situations even when the renewable generation in excess of the circuit own load, i.e. feeding power back to the higher-level system.

  1. The Development and Application of Reactive Transport Modeling Techniques to Study Radionuclide Migration at Yucca Mountain, NV

    SciTech Connect (OSTI)

    Viswanathan, Hari Selvi

    1999-09-01

    Yucca Mountain, Nevada has been chosen as a possible site for the first high level radioactive waste repository in the United States. As part of the site investigation studies, we need to make scientifically rigorous estimations of radionuclide migration in the event of a repository breach. Performance assessment models used to make these estimations are computationally intensive. We have developed two reactive transport modeling techniques to simulate radionuclide transport at Yucca Mountain: (1) the selective coupling approach applied to the convection-dispersion-reaction (CDR) model and (2) a reactive stream tube approach (RST). These models were designed to capture the important processes that influence radionuclide migration while being computationally efficient. The conventional method of modeling reactive transport models is to solve a coupled set of multi-dimensional partial differential equations for the relevant chemical components in the system. We have developed an iterative solution technique, denoted the selective coupling method, that represents a versatile alternative to traditional uncoupled iterative techniques and the filly coupled global implicit method. We show that selective coupling results in computational and memory savings relative to these approaches. We develop RST as an alternative to the CDR method for solving large two- or three-dimensional reactive transport simulations for cases in which one is interested in predicting the flux across a specific control plane. In the RST method, the multidimensional problem is reduced to a series of one-dimensional transport simulations along streamlines. The key assumption with RST is that mixing at the control plane approximates the transverse dispersion between streamlines. We compare the CDR and RST approaches for several scenarios that are relevant to the Yucca Mountain Project. For example, we apply the CDR and RST approaches to model an ongoing field experiment called the Unsaturated Zone

  2. Reactive processing of textile-natural fiber reinforced anionic polyamide-6 composites

    SciTech Connect (OSTI)

    Kan, Ze; Chen, Peng; Liu, Zhengying; Feng, Jianmin; Yang, Mingbo

    2015-05-22

    Nowadays natural fiber, used in reinforced composites, is widely concerned. However, no natural fiber reinforced reactive thermoplastic polymer grades had been prepared so far. Through our studies, it was demonstrated that there was a severe retardation and discoloration occurred in the reactive processing between anionic polyamide-6 (APA-6) and natural fiber, which result in incomplete polymerization when put together. In order to solve the problem, two methods were adopted in this paper, which are fiber pretreatment and usage of a new-style initiator called caprolactam magnesium bromide. The former is to remove sizing agent and impurities on the surface of fiber, and the latter is to weaken the side reactions between APA-6 and natural fiber by the nature of its lower reactivity and weaker alkaline. In cooperation with both methods, the severe retardation and discoloration had been improved significantly, so that the polymerization of APA-6 in natural fiber was occurred smoothly. Following textile-natural fiber reinforced APA-6 composites with an average thickness of 2.5 mm and a fiber volume content of 50% was prepared by vacuum assisted resin transfer molding (VARTM). The soxhlet extraction, dilute solution viscometry and differential scanning calorimeter (DSC) measurements respectively suggested the degree of conversion, viscosity-average molar mass and crystallization of composites was up to 94%, 11.3×104 and 50%. Remarkable improvement of mechanical properties were achieved through dynamic mechanical analysis (DMA), tensile and three-point bending test. Favorable interfacial adhesion and wettability were revealed by scanning electron microscopy (SEM) observation. Therefore, all of the above good performance make this new-style and environmentally friendly composites have broad application prospects.

  3. Physisorption and Chemisorption Methods for Evaluating the Total Surface

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Area and Active Surface Area of Two Types of Carbon Materials | Department of Energy Physisorption and Chemisorption Methods for Evaluating the Total Surface Area and Active Surface Area of Two Types of Carbon Materials Physisorption and Chemisorption Methods for Evaluating the Total Surface Area and Active Surface Area of Two Types of Carbon Materials TSA is a gross indicator of soot reactivity and does not always correlate well with the real reactivity. This research shows that a more

  4. Method for producing high quality thin layer films on substrates

    DOE Patents [OSTI]

    Strongin, Myron; Ruckman, Mark; Strongin, Daniel

    1994-01-01

    A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate.

  5. Method for producing high quality thin layer films on substrates

    DOE Patents [OSTI]

    Strongin, M.; Ruckman, M.; Strongin, D.

    1994-04-26

    A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate. 4 figures.

  6. The correlation between reactivity and ash mineralogy of coke

    SciTech Connect (OSTI)

    Kerkkonen, O.; Mattila, E.; Heiniemi, R.

    1996-12-31

    Rautaruukki is a modern integrated Finnish steel works having a production of 2.4 mil. t/year of flat products. The total fuel consumption of the two blast furnaces in 1994 was 435 kg/t HM. Coke used was 345 kg/t HM and oil injection was 90 kg/t HM. The coking plant was taken in to operation in 1987 and is the only one in Finland, which means that the coking tradition is very short. Coke production is 0.9 mil. t/year. The coking blends include 70--80% medium volatile coals having a wide range of total dilatation. From time to time disturbances in the operation of the blast furnaces have occurred in spite of the fact that the reactivity of the coke used has remained constant or even decreased. It was thought necessary to investigate the factors affecting coke reactivity, in order to better understand the results of the reactivity test. This paper deals with carbonization tests done in a 7 kg test oven using nine individual coals having volatile-matter contents of 17--36% (dry) and seven blends made from these coals. Coke reactivity with CO{sub 2} at 1100 C (CRI) and coke strength after reaction (CSR) were determined using the test developed by the Nippon Steel Corporation. The influence of coke carbon form, porosity and especially ash mineralogy on the coke reactivity were examined. The effects of some additives; petroleum coke (pet coke), the spillage material from the coke ovens and oxidized coal, on coke quality were also studied. Typical inorganic minerals found in coals were added to one of the high volatile coals, which was then coked to determine the affect of the minerals on the properties of the coke produced.

  7. Reactive multilayers fabricated by vapor deposition. A critical review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adams, D. P.

    2014-10-02

    The reactive multilayer thin films are a class of energetic materials that continue to attract attention for use in joining applications and as igniters. Generally composed of two reactants, these heterogeneous solids can be stimulated by an external source to promptly release stored chemical energy in a sudden emission of light and heat. In our critical review article, results from recent investigations of these materials are discussed. Discussion begins with a brief description of the vapor deposition techniques that provide accurate control of layer thickness and film composition. More than 50 reactive film compositions have been reported to date, withmore » most multilayers fabricated by magnetron sputter deposition or electron-beam evaporation. In later sections, we review how multilayer ignition threshold, reaction rate, and total heat are tailored via thin film design. For example, planar multilayers with nanometer-scale periodicity exhibit rapid, self-sustained reactions with wavefront velocities up to 100 m/s. Numeric and analytical models have elucidated many of the fundamental processes that underlie propagating exothermic reactions while demonstrating how reaction rates vary with multilayer design. Recent, time-resolved diffraction and imaging studies have further revealed the phase transformations and the wavefront dynamics associated with propagating chemical reactions. Many reactive multilayers (e.g., Co/Al) form product phases that are consistent with published equilibrium phase diagrams, yet a few systems, such as Pt/Al, develop metastable products. The final section highlights current and emerging applications of reactive multilayers. Examples include reactive Ni(V)/Al and Pd/Al multilayers which have been developed for localized soldering of heat-sensitive components.« less

  8. Reactive multilayers fabricated by vapor deposition. A critical review

    SciTech Connect (OSTI)

    Adams, D. P.

    2014-10-02

    The reactive multilayer thin films are a class of energetic materials that continue to attract attention for use in joining applications and as igniters. Generally composed of two reactants, these heterogeneous solids can be stimulated by an external source to promptly release stored chemical energy in a sudden emission of light and heat. In our critical review article, results from recent investigations of these materials are discussed. Discussion begins with a brief description of the vapor deposition techniques that provide accurate control of layer thickness and film composition. More than 50 reactive film compositions have been reported to date, with most multilayers fabricated by magnetron sputter deposition or electron-beam evaporation. In later sections, we review how multilayer ignition threshold, reaction rate, and total heat are tailored via thin film design. For example, planar multilayers with nanometer-scale periodicity exhibit rapid, self-sustained reactions with wavefront velocities up to 100 m/s. Numeric and analytical models have elucidated many of the fundamental processes that underlie propagating exothermic reactions while demonstrating how reaction rates vary with multilayer design. Recent, time-resolved diffraction and imaging studies have further revealed the phase transformations and the wavefront dynamics associated with propagating chemical reactions. Many reactive multilayers (e.g., Co/Al) form product phases that are consistent with published equilibrium phase diagrams, yet a few systems, such as Pt/Al, develop metastable products. The final section highlights current and emerging applications of reactive multilayers. Examples include reactive Ni(V)/Al and Pd/Al multilayers which have been developed for localized soldering of heat-sensitive components.

  9. Manipulating Interfaces through Surface Confinement of Poly(glycidyl methacrylate)-block-poly(vinyldimethylazlactone), a Dually Reactive Block Copolymer

    SciTech Connect (OSTI)

    Lokitz, Bradley S; Wei, Jifeng; Hinestrosa Salazar, Juan P; Ivanov, Ilia N; Browning, James B; Ankner, John Francis; Kilbey, II, S Michael; Messman, Jamie M

    2012-01-01

    The assembly of dually reactive, well-defined diblock copolymers incorporating the chemoselective/functional monomer, 4,4-dimethyl-2-vinylazlactone (VDMA) and the surface-reactive monomer glycidyl methacrylate (GMA) is examined to understand how competition between surface attachment and microphase segregation influences interfacial structure. Reaction of the PGMA block with surface hydroxyl groups not only anchors the copolymer to the surface, but limits chain mobility, creating brush-like structures comprising PVDMA blocks, which contain reactive azlactone groups. The block copolymers are spin coated at various solution concentrations and annealed at elevated temperature to optimize film deposition to achieve a molecularly uniform layer. The thickness and structure of the polymer thin films are investigated by ellipsometry, infrared spectroscopy, and neutron reflectometry. The results show that deposition of PGMA-b-PVDMA provides a useful route to control film thickness while preserving azlactone groups that can be further modified with biotin-poly(ethylene glycol)amine to generate designer surfaces. The method described herein offers guidance for creating highly functional surfaces, films, or coatings through the use of dually reactive block copolymers and postpolymerization modification.

  10. Stochastic Analysis of Advection-diffusion-Reactive Systems with Applications to Reactive Transport in Porous Media

    SciTech Connect (OSTI)

    Tartakovsky, Daniel

    2013-08-30

    We developed new CDF and PDF methods for solving non-linear stochastic hyperbolic equations that does not rely on linearization approximations and allows for rigorous formulation of the boundary conditions.

  11. The 'virtual density' principle of neutronics: Toward rapid computation of reactivity effects in practical core distortion scenarios

    SciTech Connect (OSTI)

    Reed, M.; Smith, K.; Forget, B.

    2013-07-01

    Fast reactor core reactivities are sensitive to geometric distortions arising from three distinct phenomena: (1) irradiation swelling of fuel throughout core lifetime, (2) thermal expansion of fuel during transients, and (3) mechanical oscillations during seismic events. Performing comprehensive reactivity analysis of these distortions requires methods for rapidly computing a multitude of minute reactivity changes. Thus, we introduce the 'virtual density' principle of neutronics as a new perturbation technique to achieve this rapid computation. This new method obviates many of the most challenging aspects of conventional geometric perturbation theory. Essentially, this 'virtual density' principle converts geometric perturbations into equivalent material density perturbations (either isotropic or anisotropic), which are highly accurate and comparatively simple to evaluate. While traditional boundary perturbation theory employs surface integrals, the 'virtual density' principle employs equivalent volume integrals. We introduce and validate this method in three subsequent stages: (1) isotropic 'virtual density', (2) anisotropic 'virtual density' for whole cores, and (3) anisotropic 'virtual density' for interior zones within cores. We numerically demonstrate its accuracy for 2-D core flowering scenarios. (authors)

  12. Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel

    Broader source: Energy.gov [DOE]

    This study uses numerical simulations to explore the use of wet ethanol as the low-reactivity fuel and diesel as the high-reactivity fuel for RCCI operation in a heavy-duty diesel engine.

  13. A Reactive Force Field study of Li/C Systems for Electrical Energy...

    Office of Scientific and Technical Information (OSTI)

    A Reactive Force Field study of LiC Systems for Electrical Energy Storage Citation Details In-Document Search Title: A Reactive Force Field study of LiC Systems for Electrical ...

  14. Reactive codoping of GaAlInP compound semiconductors (Patent...

    Office of Scientific and Technical Information (OSTI)

    Patent: Reactive codoping of GaAlInP compound semiconductors Citation Details In-Document Search Title: Reactive codoping of GaAlInP compound semiconductors A GaAlInP compound ...

  15. Development of a Full-core Reactivity Equivalence for FeCrAl...

    Office of Scientific and Technical Information (OSTI)

    Reactivity Equivalence for FeCrAl Enhanced Accident Tolerant Fuel in BWRs Citation Details In-Document Search Title: Development of a Full-core Reactivity Equivalence for ...

  16. Catalytic destruction of groundwater contaminants in reactive extraction wells

    DOE Patents [OSTI]

    McNab, Jr., Walt W.; Reinhard, Martin

    2002-01-01

    A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

  17. Engine combustion control at low loads via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

    2014-10-07

    A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

  18. Physical Characterization and Steam Chemical Reactivity of Carbon Fiber Composites

    SciTech Connect (OSTI)

    Anderl, Robert Andrew; Pawelko, Robert James; Smolik, Galen Richard

    2001-05-01

    This report documents experiments and analyses that have been done at the Idaho National Engineering and Environmental Laboratory (INEEL) to measure the steam chemical reactivity of two types of carbon fiber composites, NS31 and NB31, proposed for use at the divertor strike points in an ITER-like tokamak. These materials are 3D CFCs constituted by a NOVOLTEX preform and densified by pyrocarbon infiltration and heat treatment. NS31 differs from NB31 in that the final infiltration was done with liquid silicon to reduce the porosity and enhance the thermal conductivity of the CFC. Our approach in this work was twofold: (1) physical characterization measurements of the specimens and (2) measurements of the chemical reactivity of specimens exposed to steam.

  19. Solid polymer battery electrolyte and reactive metal-water battery

    DOE Patents [OSTI]

    Harrup, Mason K.; Peterson, Eric S.; Stewart, Frederick F.

    2000-01-01

    In one implementation, a reactive metal-water battery includes an anode comprising a metal in atomic or alloy form selected from the group consisting of periodic table Group 1A metals, periodic table Group 2A metals and mixtures thereof. The battery includes a cathode comprising water. Such also includes a solid polymer electrolyte comprising a polyphosphazene comprising ligands bonded with a phosphazene polymer backbone. The ligands comprise an aromatic ring containing hydrophobic portion and a metal ion carrier portion. The metal ion carrier portion is bonded at one location with the polymer backbone and at another location with the aromatic ring containing hydrophobic portion. The invention also contemplates such solid polymer electrolytes use in reactive metal/water batteries, and in any other battery.

  20. Reactive Membrane Barriers for Containment of Subsurface Contamination

    SciTech Connect (OSTI)

    William A. Arnold; Edward L. Cussler

    2007-02-26

    The overall goal of this project was to develop reactive membrane barriers--a new and flexible technique to contain and stabilize subsurface contaminants. Polymer membranes will leak once a contaminant is able to diffuse through the membrane. By incorporating a reactive material in the polymer, however, the contaminant is degraded or immobilized within the membrane. These processes increase the time for contaminants to breakthrough the barrier (i.e. the lag time) and can dramatically extend barrier lifetimes. In this work, reactive barrier membranes containing zero-valent iron (Fe{sup 0}) or crystalline silicotitanate (CST) were developed to prevent the migration of chlorinated solvents and cesium-137, respectively. These studies were complemented by the development of models quantifying the leakage/kill time of reactive membranes and describing the behavior of products produced via the reactions within the membranes. First, poly(vinyl alcohol) (PVA) membranes containing Fe{sup 0} and CST were prepared and tested. Although PVA is not useful in practical applications, it allows experiments to be performed rapidly and the results to be compared to theory. For copper ions (Cu{sup 2+}) and carbon tetrachloride, the barrier was effective, increasing the time to breakthrough over 300 times. Even better performance was expected, and the percentage of the iron used in the reaction with the contaminants was determined. For cesium, the CST laden membranes increased lag times more than 30 times, and performed better than theoretical predictions. A modified theory was developed for ion exchangers in reactive membranes to explain this result. With the PVA membranes, the effect of a groundwater matrix on barrier performance was tested. Using Hanford groundwater, the performance of Fe{sup 0} barriers decreased compared to solutions containing a pH buffer and high levels of chloride (both of which promote iron reactivity). For the CST bearing membrane, performance improved by a

  1. Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Milling Site: Monticello, Utah | Department of Energy Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah (4.47 MB) More

  2. Three-Dimensional Modeling of the Reactive Transport of CO2 and...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: CO2 reservoir, reactive transport, geochemistry, geomechanics, geomechanical modeling, mineral composition, homogenization, fault, hydraulic fracture, elastic modulus Word ...

  3. Point kinetics calculations with fully coupled thermal fluids reactivity feedback

    SciTech Connect (OSTI)

    Zhang, H.; Zou, L.; Andrs, D.; Zhao, H.; Martineau, R.

    2013-07-01

    The point kinetics model has been widely used in the analysis of the transient behavior of a nuclear reactor. In the traditional nuclear reactor system safety analysis codes such as RELAP5, the reactivity feedback effects are calculated in a loosely coupled fashion through operator splitting approach. This paper discusses the point kinetics calculations with the fully coupled thermal fluids and fuel temperature feedback implemented into the RELAP-7 code currently being developed with the MOOSE framework. (authors)

  4. Reactive MD Simulations of Electrochemical Oxide Interfaces at Mesoscale |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility molecular dynamics demonstrating the sintering mechanism under the influence of e-field Large-scale reactive molecular dynamics demonstrating the sintering mechanism under the influence of e-field. Tailoring the properties of nanoscale oxide-based technologies such as chemical activity, efficiency, durability, and reliability requires a better understanding of the nanoscale oxide growth kinetics under various oxidation conditions, the resulting film

  5. Reactive MD Simulations of Electrochemical Oxide Interfaces at Mesoscale |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Large-scale reactive molecular dynamics demonstrating the sintering mechanism under the influence of e-field. Tailoring the properties of nanoscale oxide-based technologies such as chemical activity, efficiency, durability, and reliability requires a better understanding of the nanoscale oxide growth kinetics under various oxidation conditions, the resulting film morphology, as well as their functional properties. Subramanian Sankaranarayanan, Argonne

  6. Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide

    SciTech Connect (OSTI)

    Mullins, David R; Albrecht, Peter M; Calaza, Florencia C

    2013-01-01

    Cerium oxide is a principal component in many heterogeneous catalytic processes. One of its key characteristics is the ability to provide or remove oxygen in chemical reactions. The different crystallographic faces of ceria present significantly different surface structures and compositions that may alter the catalytic reactivity. The structure and composition determine the number of coordination vacancies surrounding surface atoms, the availability of adsorption sites, the spacing between adsorption sites and the ability to remove O from the surface. To investigate the role of surface orientation on reactivity, CeO2 films were grown with two different orientations. CeO2(100) films were grown ex situ by pulsed laser deposition on Nb-doped SrTiO3(100). CeO2(111) films were grown in situ by thermal deposition of Ce metal onto Ru(0001) in an oxygen atmosphere. The chemical reactivity was characterized by the adsorption and decomposition of various molecules such as alcohols, aldehydes and organic acids. In general the CeO2(100) surface was found to be more active, i.e. molecules adsorbed more readily and reacted to form new products, especially on a fully oxidized substrate. However the CeO2(100) surface was less selective with a greater propensity to produce CO, CO2 and water as products. The differences in chemical reactivity are discussed in light of possible structural terminations of the two surfaces. Recently nanocubes and nano-octahedra have been synthesized that display CeO2(100) and CeO2(111) faces, respectively. These nanoparticles enable us to correlate reactions on high surface area model catalysts at atmospheric pressure with model single crystal films in a UHV environment.

  7. Simulations of Deflagration-to-Detonation Transition in Reactive Gases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Simulations of Deflagration-to-Detonation Transition in Reactive Gases PI Name: Alexei Khokhlov PI Email: ajk@oddjob.uchicago.edu Institution: University of Chicago Allocation Program: INCITE Allocation Hours at ALCF: 20,000,000 Year: 2012 Research Domain: Chemistry First-principles direct numerical simulations explain and predict high-speed combustion and deflagration-to-detonation transition (DDT) in hydrogen-oxygen gaseous mixtures. DDT and the

  8. Boron-carbide-aluminum and boron-carbide-reactive metal cermets

    DOE Patents [OSTI]

    Halverson, Danny C.; Pyzik, Aleksander J.; Aksay, Ilhan A.

    1986-01-01

    Hard, tough, lightweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidation step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modulus of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi.sqroot.in. These composites and methods can be used to form a variety of structural elements.

  9. Elementary surface processes during reactive magnetron sputtering of chromium

    SciTech Connect (OSTI)

    Monje, Sascha; Corbella, Carles Keudell, Achim von

    2015-10-07

    The elementary surface processes occurring on chromium targets exposed to reactive plasmas have been mimicked in beam experiments by using quantified fluxes of Ar ions (400–800 eV) and oxygen atoms and molecules. For this, quartz crystal microbalances were previously coated with Cr thin films by means of high-power pulsed magnetron sputtering. The measured growth and etching rates were fitted by flux balance equations, which provided sputter yields of around 0.05 for the compound phase and a sticking coefficient of O{sub 2} of 0.38 on the bare Cr surface. Further fitted parameters were the oxygen implantation efficiency and the density of oxidation sites at the surface. The increase in site density with a factor 4 at early phases of reactive sputtering is identified as a relevant mechanism of Cr oxidation. This ion-enhanced oxygen uptake can be attributed to Cr surface roughening and knock-on implantation of oxygen atoms deeper into the target. This work, besides providing fundamental data to control oxidation state of Cr targets, shows that the extended Berg's model constitutes a robust set of rate equations suitable to describe reactive magnetron sputtering of metals.

  10. Reactivity transients during a blowdown in a MSIV closure ATWS

    SciTech Connect (OSTI)

    Cheng, H.S.; Diamond, D.J. (Brookhaven National Lab., Upton, NY (USA))

    1988-01-01

    Anticipated transients without scram (ATWS) events have received considerable attention in the past and are still a subject of great interest in severe-accident analysis. Of special interest is the effect of the low-pressure emergency core cooling system (ECCS) on the plant response following a blowdown by the automatic depressurization system (ADS). There is a potential for positive reactivity insertion due to the cold water injection of the low-pressure coolant injection (LPCI) system and the low-pressure core spray system in a boiling water reactor (BWR)/4. The main concern is whether a power excursion and pressure oscillation can occur in such an event. Furthermore, since thermal-hydraulic feedback plays an important role in these accidents, the uncertainty of the reactivity feedback coefficients used can impact the outcome of the analysis for such a power excursion. The objectives of the work reported in this paper are to study the consequences of the reactivity transients during a blowdown in an ATWS event with closure of the main steam isolation valves (MSIVs) and to evaluate the effect of the LPCI system and the sensitivity of plant response to the feedback coefficients. This work was performed with the Brookhaven National Laboratory plant analyzer.

  11. Die singulation method

    DOE Patents [OSTI]

    Swiler, Thomas P.; Garcia, Ernest J.; Francis, Kathryn M.

    2013-06-11

    A method is disclosed for singulating die from a semiconductor substrate (e.g. a semiconductor-on-insulator substrate or a bulk silicon substrate) containing an oxide layer (e.g. silicon dioxide or a silicate glass) and one or more semiconductor layers (e.g. monocrystalline or polycrystalline silicon) located above the oxide layer. The method etches trenches through the substrate and through each semiconductor layer about the die being singulated, with the trenches being offset from each other around at least a part of the die so that the oxide layer between the trenches holds the substrate and die together. The trenches can be anisotropically etched using a Deep Reactive Ion Etching (DRIE) process. After the trenches are etched, the oxide layer between the trenches can be etched away with an HF etchant to singulate the die. A release fixture can be located near one side of the substrate to receive the singulated die.

  12. Die singulation method

    DOE Patents [OSTI]

    Swiler, Thomas P [Albuquerque, NM; Garcia, Ernest J [Albuquerque, NM; Francis, Kathryn M [Rio Rancho, NM

    2014-01-07

    A method is disclosed for singulating die from a semiconductor substrate (e.g. a semiconductor-on-insulator substrate or a bulk silicon substrate) containing an oxide layer (e.g. silicon dioxide or a silicate glass) and one or more semiconductor layers (e.g. monocrystalline or polycrystalline silicon) located above the oxide layer. The method etches trenches through the substrate and through each semiconductor layer about the die being singulated, with the trenches being offset from each other around at least a part of the die so that the oxide layer between the trenches holds the substrate and die together. The trenches can be anisotropically etched using a Deep Reactive Ion Etching (DRIE) process. After the trenches are etched, the oxide layer between the trenches can be etched away with a HF etchant to singulate the die. A release fixture can be located near one side of the substrate to receive the singulated die.

  13. Method for bonding thin film thermocouples to ceramics

    DOE Patents [OSTI]

    Kreider, Kenneth G. (Potomac, MD)

    1993-01-01

    A method is provided for adhering a thin film metal thermocouple to a ceramic substrate used in an environment up to 700 degrees Centigrade, such as at a cylinder of an internal combustion engine. The method includes the steps of: depositing a thin layer of a reactive metal on a clean ceramic substrate; and depositing thin layers of platinum and a platinum-10% rhodium alloy forming the respective legs of the thermocouple on the reactive metal layer. The reactive metal layer serves as a bond coat between the thin noble metal thermocouple layers and the ceramic substrate. The thin layers of noble metal are in the range of 1-4 micrometers thick. Preferably, the ceramic substrate is selected from the group consisting of alumina and partially stabilized zirconia. Preferably, the thin layer of reactive metal is in the range of 0.015-0.030 micrometers (15-30 nanometers) thick. The preferred reactive metal is chromium. Other reactive metals may be titanium or zirconium. The thin layer of reactive metal may be deposited by sputtering in ultra high purity argon in a vacuum of approximately 2 milliTorr (0.3 Pascals).

  14. Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns

    SciTech Connect (OSTI)

    Wishart, J.F.

    2011-06-12

    Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs generally have low volatilities and are combustion-resistant, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of primary radiation chemistry, charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of reactions and product distributions. We study these issues by characterization of primary radiolysis products and measurements of their yields and reactivity, quantification of electron solvation dynamics and scavenging of electrons in different states of solvation. From this knowledge we wish to learn how to predict radiolytic mechanisms and control them or mitigate their effects on the properties of materials used in nuclear fuel processing, for example, and to apply IL radiation chemistry to answer questions about general chemical reactivity in ionic liquids that will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that the slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increase the importance of pre-solvated electron reactivity and consequently alter product distributions and subsequent chemistry. This difference from conventional solvents has profound effects on predicting and controlling radiolytic yields

  15. Flash pyrolysis of biomass with reactive and non-reactive gases. Summary report, March 1982-March 1983

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1983-03-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H/sub 2/ and CH/sub 4/ and with the non-reactive gas He is being determined in a 1'' downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000/sup 0/C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol production. With methane, flash methanolysis of wood, leads to high yields of ethylene, benzene and CO which can be used for the production of valuable feedstocks and methanol fuel. At reactor conditions of 50 psi and 1000/sup 0/C and approximately 1 sec residence time, the ethylene yield based on wood carbon converted is 22%, benzene 12% and the CO yield is 48%. The yield of ethylene is 2.2 times higher with methane than with helium, thus indicating a free radical rection between CH/sub 4/ and the pyrolyzed wood. A preliminary process analysis indicates an economically competitive process for the production of ethylene, benzene and methanol based on the methanolysis of wood. It is recommended to further develop the data base for the flash pyrolysis of wood and other biomass materials with methane as well as with other reactive gases (e.g. CO and CO/sub 2/) and determine the role of the hemi-cellulose and lignin in the formation of these valuable fuels and feedstocks.

  16. Quantum Theory of (H,H{Sub 2}) Scattering: Approximate Treatments of Reactive Scattering

    DOE R&D Accomplishments [OSTI]

    Tang, K. T.; Karplus, M.

    1970-10-01

    A quantum mechanical study is made of reactive scattering in the (H, H{sub 2}) system. The problem is formulated in terms of a form of the distorted-wave Born approximation (DWBA) suitable for collisions in which all particles have finite mass. For certain incident energies, differential and total cross sections, as well as other attributes of the reactive collisions, (e.g. reaction configuration), are determined. Two limiting models in the DWBA formulation are compared; in one, the molecule is unperturbed by the incoming atom and in the other, the molecule adiabatically follows the incoming atom. For thermal incident energies and semi-empirical interaction potential employed, the adiabatic model seems to be more appropriate. Since the DWBA method is too complicated for a general study of the (H, H{sub 2}) reaction, a much simpler approximation method, the “linear model” is developed. This model is very different in concept from treatments in which the three atoms are constrained to move on a line throughout the collision. The present model includes the full three-dimensional aspect of the collision and it is only the evaluation of the transition matrix element itself that is simplified. It is found that the linear model, when appropriately normalized, gives results in good agreement with that of the DWBA method. By application of this model, the energy dependence, rotational state of dependence and other properties of the total and differential reactions cross sections are determined. These results of the quantum mechanical treatment are compared with the classical calculation for the same potential surface. The most important result is that, in agreement with the classical treatment, the differential cross sections are strongly backward peaked at low energies and shifts in the forward direction as the energy increases. Finally, the implications of the present calculations for a theory of chemical kinetics are discussed.

  17. Method and apparatus to image biological interactions in plants

    DOE Patents [OSTI]

    Weisenberger, Andrew; Bonito, Gregory M.; Reid, Chantal D.; Smith, Mark Frederick

    2015-12-22

    A method to dynamically image the actual translocation of molecular compounds of interest in a plant root, root system, and rhizosphere without disturbing the root or the soil. The technique makes use of radioactive isotopes as tracers to label molecules of interest and to image their distribution in the plant and/or soil. The method allows for the study and imaging of various biological and biochemical interactions in the rhizosphere of a plant, including, but not limited to, mycorrhizal associations in such regions.

  18. Synthesis and processing of composites by reactive metal penetration

    SciTech Connect (OSTI)

    Loehman, R.E.; Ewsuk, K.G.; Tomsia, A.P.

    1997-04-01

    Achieving better performance in commercial products and processes often is dependent on availability of new and improved materials. Ceramic-metal composites have advantages over more conventional materials because of their high stiffness-to-weight ratios, good fracture toughness, and because their electrical and thermal properties can be varied through control of their compositions and microstructures. However, ceramic composites will be more widely used only when their costs are competitive with other materials and when designers have more confidence in their reliability. Over the past four years reactive metal penetration has been shown to be a promising technique for making ceramic and metal-matrix composites to near-net-shape with control of both composition and microstructure. It appears that, with sufficient development, reactive metal penetration could be an economical process for manufacturing many of the advanced ceramic composites that are needed for light-weight structural and wear applications for transportation and energy conversion devices. Near-net-shape fabrication of parts is a significant advantage because costly and energy intensive grinding and machining operations are substantially reduced, and the waste generated from such finishing operations is minimized. The most promising compositions to date consist of Al and Al{sub 2}O{sub 3}; thus, these composites should be of particular interest to the aluminum industry. The goals of this ceramic-metal composite research and development program are: (1) to identify compositions favorable for making composites by reactive metal penetration; (2) to understand the mechanism(s) by which these composites are formed; (3) to control and optimize the process so that composites and composite coatings can be made economically; and (4) to apply R&D results to problems of interest to the aluminum industry.

  19. Hydrogen Atom Reactivity toward Aqueous tert-Butyl Alcohol

    SciTech Connect (OSTI)

    Lymar S. V.; Schwarz, H.A.

    2012-02-09

    Through a combination of pulse radiolysis, purification, and analysis techniques, the rate constant for the H + (CH{sub 3}){sub 3}COH {yields} H{sub 2} + {sm_bullet}CH{sub 2}C(CH{sub 3}){sub 2}OH reaction in aqueous solution is definitively determined to be (1.0 {+-} 0.15) x 10{sup 5} M{sup -1} s{sup -1}, which is about half of the tabulated number and 10 times lower than the more recently suggested revision. Our value fits on the Polanyi-type, rate-enthalpy linear correlation ln(k/n) = (0.80 {+-} 0.05){Delta}H + (3.2 {+-} 0.8) that is found for the analogous reactions of other aqueous aliphatic alcohols with n equivalent abstractable H atoms. The existence of such a correlation and its large slope are interpreted as an indication of the mechanistic similarity of the H atom abstraction from {alpha}- and {beta}-carbon atoms in alcohols occurring through the late, product-like transition state. tert-Butyl alcohol is commonly contaminated by much more reactive secondary and primary alcohols (2-propanol, 2-butanol, ethanol, and methanol), whose content can be sufficient for nearly quantitative scavenging of the H atoms, skewing the H atom reactivity pattern, and explaining the disparity of the literature data on the H + (CH{sub 3}){sub 3}COH rate constant. The ubiquitous use of tert-butyl alcohol in pulse radiolysis for investigating H atom reactivity and the results of this work suggest that many other previously reported rate constants for the H atom, particularly the smaller ones, may be in jeopardy.

  20. New NIR Calibration Models Speed Biomass Composition and Reactivity Characterization

    SciTech Connect (OSTI)

    2015-09-01

    Obtaining accurate chemical composition and reactivity (measures of carbohydrate release and yield) information for biomass feedstocks in a timely manner is necessary for the commercialization of biofuels. This highlight describes NREL's work to use near-infrared (NIR) spectroscopy and partial least squares multivariate analysis to develop calibration models to predict the feedstock composition and the release and yield of soluble carbohydrates generated by a bench-scale dilute acid pretreatment and enzymatic hydrolysis assay. This highlight is being developed for the September 2015 Alliance S&T Board meeting.

  1. Reactive Flash Volatilization of Solid, Nonvolatile Fuel - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Reactive Flash Volatilization of Solid, Nonvolatile Fuel DOE Grant Recipients University of Minnesota Contact University of Minnesota About This Technology <span id="Caption"><span id="ctl00_MainContentHolder_zoomimage_defaultCaption">Syngas or Synthesis Gas</span></span> Syngas or Synthesis Gas <span id="Caption"><span

  2. Studies on optoelectronic properties of DC reactive magnetron sputtered chromium doped CdO thin films

    SciTech Connect (OSTI)

    Hymavathi, B. Rao, T. Subba; Kumar, B. Rajesh

    2014-10-15

    Cr doped CdO thin films were deposited on glass substrates by DC reactive magnetron sputtering method and subsequently annealed from 200 °C to 500 °C. X-ray diffraction analysis showed that the films exhibit (1 1 1) preferred orientation. The optical transmittance of the films increases from 64% to 88% with increasing annealing temperature. The optical band gap values were found to be decreased from 2.77 to 2.65 eV with the increase of annealing temperature. The decrease in optical band gap energy with increasing annealing temperature can be attributed to improvement in the crystallinity of the films and may also be due to quantum confinement effect. A minimum resistivity of 2.23 × 10{sup −4} Ω.cm and sheet resistance of 6.3 Ω/sq is obtained for Cr doped CdO film annealed at 500 °C.

  3. Detection of high molecular weight organic tracers in vegetation smoke samples by high-temperature gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Elias, V.O.; Simoneit, B.R.T. ); Pereira, A.S.; Cardoso, J.N. ); Cabral, J.A. )

    1999-07-15

    High-temperature high-resolution gas chromatography (HTGC) is an established technique for the separation of complex mixtures of high molecular weight (HMW) compounds which do not elute when analyzed on conventional GC columns. The combination of this technique with mass spectrometry is not so common and application to aerosols is novel. The HTGC and HTGC-MS analyses of smoke samples taken by particle filtration from combustion of different species of plants provided the characterization of various classes of HMW compounds reported to occur for the first time in emissions from biomass burning. Among these components are a series of wax esters with up to 58 carbon numbers, aliphatic hydrocarbons, triglycerides, long chain methyl ketones, alkanols and a series of triterpenyl fatty acid esters which have been characterized as novel natural products. Long chain fatty acids with more than 32 carbon numbers are not present in the smoke samples analyzed. The HMW compounds in smoke samples from the burning of plants from Amazonia indicate the input of directly volatilized natural products in the original plants during their combustion. However, the major organic compounds extracted from smoke consist of a series of lower molecular weight polar components, which are not natural products but the result of the thermal breakdown of cellulose and lignin. In contrast, the HMW natural products may be suitable tracers for specific sources of vegetation combustion because they are emitted as particles without thermal alternation in the smoke and can thus be related directly to the original plant material.

  4. Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation

    SciTech Connect (OSTI)

    Wu, Y.; Ajo-Franklin, J.B.; Spycher, N.; Hubbard, S.S.; Zhang, G.; Williams, K.H.; Taylor, J.; Fujita, Y.; Smith, R.

    2011-07-15

    Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH{sub 4}{sup

  5. Geophysical Monitoring and Reactive Transport Modeling of Ureolytically-Driven Calcium Carbonate Precipitation

    SciTech Connect (OSTI)

    Yuxin Wu; Jonathan B. Ajo-Franklin; Nicolas Spycher; Susan S. Hubbard; Guoxiang Zhang; Kenneth H. Williams; Joanna Taylor; Yoshiko Fujita; Robert Smith

    2011-09-01

    Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH4

  6. High temperature cooling system and method

    DOE Patents [OSTI]

    Loewen, Eric P.

    2006-12-12

    A method for cooling a heat source, a method for preventing chemical interaction between a vessel and a cooling composition therein, and a cooling system. The method for cooling employs a containment vessel with an oxidizable interior wall. The interior wall is oxidized to form an oxide barrier layer thereon, the cooling composition is monitored for excess oxidizing agent, and a reducing agent is provided to eliminate excess oxidation. The method for preventing chemical interaction between a vessel and a cooling composition involves introducing a sufficient quantity of a reactant which is reactive with the vessel in order to produce a barrier layer therein that is non-reactive with the cooling composition. The cooling system includes a containment vessel with oxidizing agent and reducing agent delivery conveyances and a monitor of oxidation and reduction states so that proper maintenance of a vessel wall oxidation layer occurs.

  7. METHOD OF SEPARATING PLUTONIUM

    DOE Patents [OSTI]

    Brown, H.S.; Hill, O.F.

    1958-02-01

    Plutonium hexafluoride is a satisfactory fluorinating agent and may be reacted with various materials capable of forming fluorides, such as copper, iron, zinc, etc., with consequent formation of the metal fluoride and reduction of the plutonium to the form of a lower fluoride. In accordance with the present invention, it has been found that the reactivity of plutonium hexafluoride with other fluoridizable materials is so great that the process may be used as a method of separating plutonium from mixures containing plutonium hexafluoride and other vaporized fluorides even though the plutonium is present in but minute quantities. This process may be carried out by treating a mixture of fluoride vapors comprising plutonium hexafluoride and fluoride of uranium to selectively reduce the plutonium hexafluoride and convert it to a less volatile fluoride, and then recovering said less volatile fluoride from the vapor by condensation.

  8. METHOD OF PRODUCING NEUTRONS

    DOE Patents [OSTI]

    Imhoff, D.H.; Harker, W.H.

    1964-02-01

    A method for producing neutrons is described in which there is employed a confinement zone defined between longitudinally spaced localized gradient regions of an elongated magnetic field. Changed particles and neutralizing electrons, more specifically deuterons and tritons and neutralizng electrons, are injected into the confinement field from ion sources located outside the field. The rotational energy of the parrticles is increased at the gradients by imposing an oscillating transverse electrical field thereacross. The imposition of such oscillating transverse electrical fields improves the reflection capability of such gradient fielda so that the reactive particles are retained more effectively within the zone. With the attainment of appropriate densities of plasma particles and provided that such particles are at a sufficiently high temperature, neutron-producing reactions ensue and large quantities of neutrons emerge from the containment zone. (AEC)

  9. Hybrid nuclear reactor grey rod to obtain required reactivity worth

    DOE Patents [OSTI]

    Miller, John V.; Carlson, William R.; Yarbrough, Michael B.

    1991-01-01

    Hybrid nuclear reactor grey rods are described, wherein geometric combinations of relatively weak neutron absorber materials such as stainless steel, zirconium or INCONEL, and relatively strong neutron absorber materials, such as hafnium, silver-indium cadmium and boron carbide, are used to obtain the reactivity worths required to reach zero boron change load follow. One embodiment includes a grey rod which has combinations of weak and strong neutron absorber pellets in a stainless steel cladding. The respective pellets can be of differing heights. A second embodiment includes a grey rod with a relatively thick stainless steel cladding receiving relatively strong neutron absorber pellets only. A third embodiment includes annular relatively weak netron absorber pellets with a smaller diameter pellet of relatively strong absorber material contained within the aperture of each relatively weak absorber pellet. The fourth embodiment includes pellets made of a homogeneous alloy of hafnium and a relatively weak absorber material, with the percentage of hafnium chosen to obtain the desired reactivity worth.

  10. Synthesis of belite cement clinker of high hydraulic reactivity

    SciTech Connect (OSTI)

    Kacimi, Larbi Simon-Masseron, Angelique Salem, Souria Ghomari, Abdelhamid Derriche, Zoubir

    2009-07-15

    This study is concerned with the increase of the cooling rate of belite clinker, by using the water quenching for the chemical stabilization of reactive belite, which improves the hydraulic properties of this clinker. The addition of adequate mineralizers, as NaF and Fe{sub 2}O{sub 3}, contributes to the improvement of the clinker properties obtained at low burning temperature. X-ray fluorescence spectroscopy, X-ray diffraction analysis and optical microscopy were used to determine the chemical and mineralogical compositions of this clinker. The samples were analyzed by means of a scanning electronic microscope connected with an energy-dispersive X-ray spectrometer to detect the composition of the belite phase and its morphology. Physical and mechanical properties of this clinker cement were determined. The results show that the belite clinker obtained at 1150 {sup o}C, with lime saturation factor 0.67, is characterized by a great hydraulic reactivity, similar to that of the ordinary alite clinker. The addition of 2% of NaF and the water quenching improved the chemical, mineralogical and structural properties, while improving the cement hydraulic properties.

  11. Fluid-rock interaction: A reactive transport approach

    SciTech Connect (OSTI)

    Steefel, C.; Maher, K.

    2009-04-01

    Fluid-rock interaction (or water-rock interaction, as it was more commonly known) is a subject that has evolved considerably in its scope over the years. Initially its focus was primarily on interactions between subsurface fluids of various temperatures and mostly crystalline rocks, but the scope has broadened now to include fluid interaction with all forms of subsurface materials, whether they are unconsolidated or crystalline ('fluid-solid interaction' is perhaps less euphonious). Disciplines that previously carried their own distinct names, for example, basin diagenesis, early diagenesis, metamorphic petrology, reactive contaminant transport, chemical weathering, are now considered to fall under the broader rubric of fluid-rock interaction, although certainly some of the key research questions differ depending on the environment considered. Beyond the broadening of the environments considered in the study of fluid-rock interaction, the discipline has evolved in perhaps an even more important way. The study of water-rock interaction began by focusing on geochemical interactions in the absence of transport processes, although a few notable exceptions exist (Thompson 1959; Weare et al. 1976). Moreover, these analyses began by adopting a primarily thermodynamic approach, with the implicit or explicit assumption of equilibrium between the fluid and rock. As a result, these early models were fundamentally static rather than dynamic in nature. This all changed with the seminal papers by Helgeson and his co-workers (Helgeson 1968; Helgeson et al. 1969) wherein the concept of an irreversible reaction path was formally introduced into the geochemical literature. In addition to treating the reaction network as a dynamically evolving system, the Helgeson studies introduced an approach that allowed for the consideration of a multicomponent geochemical system, with multiple minerals and species appearing as both reactants and products, at least one of which could be

  12. The spiral arms of the Milky Way: The relative location of each different arm tracer within a typical spiral arm width

    SciTech Connect (OSTI)

    Vallée, Jacques P.

    2014-07-01

    From the Sun's location in the Galactic disk, different arm tracers (CO, H I, hot dust, etc.) have been employed to locate a tangent to each spiral arm. Using all various and different observed spiral arm tracers (as published elsewhere), we embark on a new goal, namely the statistical analysis of these published data (data mining) to statistically compute the mean location of each spiral arm tracer. We show for a typical arm cross-cut, a separation of 400 pc between the mid-arm and the dust lane (at the inner edge of the arm, toward the Galactic center). Are some arms major and others minor? Separating arms into two sets, as suggested by some, we find the same arm widths between the two sets. Our interpretation is that we live in a multiple (four-arm) spiral (logarithmic) pattern (around a pitch angle of 12°) for the stars and gas in the Milky Way, with a sizable interarm separation (around 3 kpc) at the Sun's location and the same arm width for each arm (near 400 pc from mid-arm to dust lane).

  13. The effect of variable atmospheric forcing on oceanic subduction of a passive tracer in a numerical model: Implications for global warming

    SciTech Connect (OSTI)

    Horsfall, F.; Bleck, R.; Hanson, H.P.

    1997-11-01

    This study addresses the issue of the ocean`s response to the changing climate. The objectives is to determine the effect of variable atmospheric forcing on the ocean on decadal time scales, specifically on the subduction of a passive tracer. In the context of the model used in this study, this tracer is {open_quotes}tagged{close_quotes} water that is subducted into the thermocline and into the deep ocean. The model used in this study is the Miami Isopycnic Coordinate Ocean Model which has a realistic Atlantic domain from 20{degrees}S to 60{degrees}N. There are twelve model layers, the first (top) layer being the thermodynamically active mixed layer and the lower eleven layers all having constant potential density ({sigma}{sub {theta}}). The atmospheric forcing changes vary latitudinally, allowing for a maximum increase in wind at midlatitudes and a maximum increase in temperature at the poles. In these experiments, it was found that wind speed and temperature effects dominate in bringing about changes in mixed-layer depth and in tracer penetration at high latitudes, with wind speed effects having the greater weight. It is apparent from the results that the weakening of the North Atlantic thermohaline circulation is dependent on the atmospheric changes in air temperature and in the wind field. 11 refs., 2 figs.

  14. Surprising differences in the reactivity of cyanoaromatic radical anions generated by photoinduced electron transfer

    SciTech Connect (OSTI)

    Kellett, M.A.; Whitten, D.G. ); Gould, I.R. ); Bergmark, W.R. )

    1991-01-02

    In this paper, the authors report some studies that indicate that the reactivity of photogenerated cyanoaromatic anion radicals is strongly affected by the medium in which they are generated; interestingly they report conditions under which potentially reactive anion radicals of strongly affected by the medium in which they are generated; interestingly they report conditions under which potentially reactive anion radicals of DCA and 2,6,9,10-tetracyanoanthracene (TCA) can be the stable end products of photoinduced redox reactions.

  15. Performance of a Permeable Reactive Barrier Using Granular Zero-Valent

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site | Department of Energy of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable

  16. In-Cylinder Mechanisms of PCI Heat-Release Rate Control by Fuel Reactivity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stratification | Department of Energy Mechanisms of PCI Heat-Release Rate Control by Fuel Reactivity Stratification In-Cylinder Mechanisms of PCI Heat-Release Rate Control by Fuel Reactivity Stratification Explores in-cylinder mechanisms by which fuel reactivity stratification via a two fuel system affects premixed charge compression ignition heat release rate to achieve diesel-like efficiency deer11_kokjohn.pdf (3.98 MB) More Documents & Publications Heavy-Duty Low-Temperature and

  17. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; et al

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility atmore » an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.« less

  18. Flash pyrolysis of biomass with reactive and nonreactive gases

    SciTech Connect (OSTI)

    Sundaram, M.S.; Steinberg, M.; Fallon, P.

    1982-10-01

    Studies were done on the flash pyrolysis of Douglas fir wood in the presence of reactive and nonreactive gases including hydrogen, methane, and helium. Pyrolysis and gasification of the wood particles was done in one step, without catalysts. Almost complete (98%) gasification of the carbon in Douglas fir wood was achieved at 1000/sup 0/C and 500-psi hydrogen pressure. The reaction products were methane, ethane, ethylene, carbon monoxide, BTX, and water. Flash hydropyrolysis produced a large yield of hydrocarbon gases (up to 78% C) comprising methane and ethane. High yields of ethylene (up to 21% C) and BTX (up to 12% C) were obtained via methane pyrolysis of fir wood; a free-radical mechanism is proposed to explain the enhanced yield of ethylene in a methane atmosphere.

  19. Transparent electrical conducting films by activated reactive evaporation

    DOE Patents [OSTI]

    Bunshah, Rointan; Nath, Prem

    1982-01-01

    Process and apparatus for producing transparent electrical conducting thin films by activated reactive evaporation. Thin films of low melting point metals and alloys, such as indium oxide and indium oxide doped with tin, are produced by physical vapor deposition. The metal or alloy is vaporized by electrical resistance heating in a vacuum chamber, oxygen and an inert gas such as argon are introduced into the chamber, and vapor and gas are ionized by a beam of low energy electrons in a reaction zone between the resistance heater and the substrate. There is a reaction between the ionized oxygen and the metal vapor resulting in the metal oxide which deposits on the substrate as a thin film which is ready for use without requiring post deposition heat treatment.

  20. Ionic Liquids: Radiation Chemistry, Solvation Dynamics and Reactivity Patterns

    SciTech Connect (OSTI)

    Wishart,J.F.

    2008-09-29

    Ionic liquids (ILs) are a rapidly expanding family of condensed-phase media with important applications in energy production, nuclear fuel and waste processing, improving the efficiency and safety of industrial chemical processes, and pollution prevention. ILs are generally nonvolatile, noncombustible, highly conductive, recyclable and capable of dissolving a wide variety of materials. They are finding new uses in chemical synthesis, catalysis, separations chemistry, electrochemistry and other areas. Ionic liquids have dramatically different properties compared to conventional molecular solvents, and they provide a new and unusual environment to test our theoretical understanding of charge transfer and other reactions. We are interested in how IL properties influence physical and dynamical processes that determine the stability and lifetimes of reactive intermediates and thereby affect the courses of chemical reactions and product distributions. Successful use of ionic liquids in radiation-filled environments, where their safety advantages could be significant, requires an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of IL radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material. An understanding of ionic liquid radiation chemistry will also facilitate pulse radiolysis studies of general chemical reactivity in ILs, which will aid in the development of applications listed above. Very early in our radiolysis studies it became evident that slow solvation dynamics of the excess electron in ILs (which vary over a wide viscosity range) increases the importance of pre-solvated electron reactivity and consequently alters product distributions. Parallel studies of IL solvation phenomena using coumarin-153 dynamic Stokes shifts and polarization anisotropy decay rates are done to compare with electron solvation studies and to evaluate

  1. Quantifying and Addressing the DOE Material Reactivity Requirements with Analysis and Testing of Hydrogen Storage Materials & Systems

    SciTech Connect (OSTI)

    Khalil, Y. F

    2015-01-05

    The objective of this project is to examine safety aspects of candidate hydrogen storage materials and systems being developed in the DOE Hydrogen Program. As a result of this effort, the general DOE safety target will be given useful meaning by establishing a link between the characteristics of new storage materials and the satisfaction of safety criteria. This will be accomplished through the development and application of formal risk analysis methods, standardized materials testing, chemical reactivity characterization, novel risk mitigation approaches and subscale system demonstration. The project also will collaborate with other DOE and international activities in materials based hydrogen storage safety to provide a larger, highly coordinated effort.

  2. Coupled reactive mass transport and fluid flow: Issues in model verification

    SciTech Connect (OSTI)

    Freedman, Vicky L.; Ibaraki, Motomu

    2003-01-03

    Model verification and validation are both important steps in the development of reactive transport models. In this paper, a distinction is made between verification and validation, and the focus is on codifying the issues of verification for a numerical, reactive transport flow model. First, the conceptual basis of model verification is reviewed, which shows that verification should be understood as a first step in model development, and be followed by a protocol that assures that the model accurately represents system behavior. Second, commonly used procedures and methods of model verification are presented. In the third part of this paper, an intercomparison of models is used to demonstrate that model verification can be performed despite differences in hydrogeochemical transport code formulations. Results of an example simulation of transport are presented in which the numerical model is tested against other hydrogeochemical codes. Different kinetic formulations between solid and aqueous phases used among numerical models complicates model verification. This test problem involves uranium transport under conditions of varying pH and oxidation potential, with reversible precipitation of calcium uranate and coffinite. Results between the different hydrogeochemical transport codes show differences in oxidation potentials, but similarities in mineral assemblages and aqueous transport patterns. Because model verification can be further complicated by differences in the approach for solving redox problems, a comparison of a fugacity approach to both the external approach (based on hypothetical electron activity) and effective internal approach (based on conservation of electrons) is performed. The comparison demonstrates that the oxygen fugacity approach produces different redox potentials and mineral assemblages than both the effective internal and external approaches.

  3. A sequential partly iterative approach for multicomponent reactive transport with CORE2D

    SciTech Connect (OSTI)

    Samper, J.; Xu, T.; Yang, C.

    2008-11-01

    CORE{sup 2D} V4 is a finite element code for modeling partly or fully saturated water flow, heat transport and multicomponent reactive solute transport under both local chemical equilibrium and kinetic conditions. It can handle coupled microbial processes and geochemical reactions such as acid-base, aqueous complexation, redox, mineral dissolution/precipitation, gas dissolution/exsolution, ion exchange, sorption via linear and nonlinear isotherms, sorption via surface complexation. Hydraulic parameters may change due to mineral precipitation/dissolution reactions. Coupled transport and chemical equations are solved by using sequential iterative approaches. A sequential partly-iterative approach (SPIA) is presented which improves the accuracy of the traditional sequential noniterative approach (SNIA) and is more efficient than the general sequential iterative approach (SIA). While SNIA leads to a substantial saving of computing time, it introduces numerical errors which are especially large for cation exchange reactions. SPIA improves the efficiency of SIA because the iteration between transport and chemical equations is only performed in nodes with a large mass transfer between solid and liquid phases. The efficiency and accuracy of SPIA are compared to those of SIA and SNIA using synthetic examples and a case study of reactive transport through the Llobregat Delta aquitard in Spain. SPIA is found to be as accurate as SIA while requiring significantly less CPU time. In addition, SPIA is much more accurate than SNIA with only a minor increase in computing time. A further enhancement of the efficiency of SPIA is achieved by improving the efficiency of the Newton-Raphson method used for solving chemical equations. Such an improvement is obtained by working with increments of log-concentrations and ignoring the terms of the Jacobian matrix containing derivatives of activity coefficients. A proof is given for the symmetry and non-singularity of the Jacobian matrix

  4. Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.

    SciTech Connect (OSTI)

    Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

    2012-02-01

    In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested

  5. Pebble Fuel Handling and Reactivity Control for Salt-Cooled High Temperature Reactors

    SciTech Connect (OSTI)

    Peterson, Per; Greenspan, Ehud

    2015-02-09

    This report documents the work completed on the X-PREX facility under NEUP Project 11- 3172. This project seeks to demonstrate the viability of pebble fuel handling and reactivity control for fluoride salt-cooled high-temperature reactors (FHRs). The research results also improve the understanding of pebble motion in helium-cooled reactors, as well as the general, fundamental understanding of low-velocity granular flows. Successful use of pebble fuels in with salt coolants would bring major benefits for high-temperature reactor technology. Pebble fuels enable on-line refueling and operation with low excess reactivity, and thus simpler reactivity control and improved fuel utilization. If fixed fuel designs are used, the power density of salt- cooled reactors is limited to 10 MW/m3 to obtain adequate duration between refueling, but pebble fuels allow power densities in the range of 20 to 30 MW/m3. This can be compared to the typical modular helium reactor power density of 5 MW/m3. Pebble fuels also permit radial zoning in annular cores and use of thorium or graphite pebble blankets to reduce neutron fluences to outer radial reflectors and increase total power production. Combined with high power conversion efficiency, compact low-pressure primary and containment systems, and unique safety characteristics including very large thermal margins (>500°C) to fuel damage during transients and accidents, salt-cooled pebble fuel cores offer the potential to meet the major goals of the Advanced Reactor Concepts Development program to provide electricity at lower cost than light water reactors with improved safety and system performance.This report presents the facility description, experimental results, and supporting simulation methods of the new X-Ray Pebble Recirculation Experiment (X-PREX), which is now operational and being used to collect data on the behavior of slow dense granular flows relevant to pebble bed reactor core designs. The X

  6. Reactivity-controlled compression ignition drive cycle emissions and fuel economy estimations using vehicle system simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Curran, Scott J.; Gao, Zhiming; Wagner, Robert M.

    2014-12-22

    In-cylinder blending of gasoline and diesel to achieve reactivity-controlled compression ignition has been shown to reduce NOX and soot emissions while maintaining or improving brake thermal efficiency as compared with conventional diesel combustion. The reactivity-controlled compression ignition concept has an advantage over many advanced combustion strategies in that the fuel reactivity can be tailored to the engine speed and load, allowing stable low-temperature combustion to be extended over more of the light-duty drive cycle load range. In this paper, a multi-mode reactivity-controlled compression ignition strategy is employed where the engine switches from reactivity-controlled compression ignition to conventional diesel combustion whenmore » speed and load demand are outside of the experimentally determined reactivity-controlled compression ignition range. The potential for reactivity-controlled compression ignition to reduce drive cycle fuel economy and emissions is not clearly understood and is explored here by simulating the fuel economy and emissions for a multi-mode reactivity-controlled compression ignition–enabled vehicle operating over a variety of US drive cycles using experimental engine maps for multi-mode reactivity-controlled compression ignition, conventional diesel combustion, and a 2009 port-fuel injected gasoline engine. Drive cycle simulations are completed assuming a conventional mid-size passenger vehicle with an automatic transmission. Multi-mode reactivity-controlled compression ignition fuel economy simulation results are compared with the same vehicle powered by a representative 2009 port-fuel injected gasoline engine over multiple drive cycles. Finally, engine-out drive cycle emissions are compared with conventional diesel combustion, and observations regarding relative gasoline and diesel tank sizes needed for the various drive cycles are also summarized.« less

  7. Reactivity-controlled compression ignition drive cycle emissions and fuel economy estimations using vehicle system simulations

    SciTech Connect (OSTI)

    Curran, Scott J.; Gao, Zhiming; Wagner, Robert M.

    2014-12-22

    In-cylinder blending of gasoline and diesel to achieve reactivity-controlled compression ignition has been shown to reduce NOX and soot emissions while maintaining or improving brake thermal efficiency as compared with conventional diesel combustion. The reactivity-controlled compression ignition concept has an advantage over many advanced combustion strategies in that the fuel reactivity can be tailored to the engine speed and load, allowing stable low-temperature combustion to be extended over more of the light-duty drive cycle load range. In this paper, a multi-mode reactivity-controlled compression ignition strategy is employed where the engine switches from reactivity-controlled compression ignition to conventional diesel combustion when speed and load demand are outside of the experimentally determined reactivity-controlled compression ignition range. The potential for reactivity-controlled compression ignition to reduce drive cycle fuel economy and emissions is not clearly understood and is explored here by simulating the fuel economy and emissions for a multi-mode reactivity-controlled compression ignition–enabled vehicle operating over a variety of US drive cycles using experimental engine maps for multi-mode reactivity-controlled compression ignition, conventional diesel combustion, and a 2009 port-fuel injected gasoline engine. Drive cycle simulations are completed assuming a conventional mid-size passenger vehicle with an automatic transmission. Multi-mode reactivity-controlled compression ignition fuel economy simulation results are compared with the same vehicle powered by a representative 2009 port-fuel injected gasoline engine over multiple drive cycles. Finally, engine-out drive cycle emissions are compared with conventional diesel combustion, and observations regarding relative gasoline and diesel tank sizes needed for the various drive cycles are also summarized.

  8. Predictive modeling of reactive wetting and metal joining.

    SciTech Connect (OSTI)

    van Swol, Frank B.

    2013-09-01

    The performance, reproducibility and reliability of metal joints are complex functions of the detailed history of physical processes involved in their creation. Prediction and control of these processes constitutes an intrinsically challenging multi-physics problem involving heating and melting a metal alloy and reactive wetting. Understanding this process requires coupling strong molecularscale chemistry at the interface with microscopic (diffusion) and macroscopic mass transport (flow) inside the liquid followed by subsequent cooling and solidification of the new metal mixture. The final joint displays compositional heterogeneity and its resulting microstructure largely determines the success or failure of the entire component. At present there exists no computational tool at Sandia that can predict the formation and success of a braze joint, as current capabilities lack the ability to capture surface/interface reactions and their effect on interface properties. This situation precludes us from implementing a proactive strategy to deal with joining problems. Here, we describe what is needed to arrive at a predictive modeling and simulation capability for multicomponent metals with complicated phase diagrams for melting and solidification, incorporating dissolutive and composition-dependent wetting.

  9. Spectroscopy, Thermochemistry, and Reactivity of Lanthanide and Actinide Molecules

    SciTech Connect (OSTI)

    Morse, Michael D.; Armentrout, Peter B.

    2012-08-16

    The research undertaken under this grant is described in this document. The document describes progress in the construction of an instrument for recording photodissociation action spectra of mass-selected cryo-cooled cations. The instrument is not yet functional, but we anticipate trapping ions and conducting photodissociation experiments before the end of the year. It also describes resonant two-photon ionization spectra that have been recorded for uranium mononitride (UN) in the visible portion of the spectrum. These experiments are still underway at the present time. Although the spectra are a bit difficult to properly fit, due to upper state perturbations, it appears that the molecule has a ground state with {Omega} = 3.5 and a bond length of approximately 1.76 {angstrom}. Finally, results on the thermochemistry and reactivity of Th{sup +} are presented. In these studies the bond energies of the following bonds have been determined: D{sub 0}(Th{sup +}-2O) = 10.2 {+-} 0.2 eV; D0(Th{sup +}-N) = 6.69 {+-} 0.35 eV; D0(Th{sup +}-O) = 8.40 {+-} 0.28 eV; D{sub 0}(OTh{sup +}-O) = 1.8 {+-} 0.4 eV.

  10. Reactivity of amine antioxidants relative to OH and anti e

    SciTech Connect (OSTI)

    Minkhadzhidinova, D.R.; Nikiforov, G.A.; Khrapova, N.G.; Sharpatyi, V.A.

    1986-06-20

    An ESR study was carried out on the reactivity of various types of amines relative to OH/sup ./ and anti e. The selection of these compounds having anti-oxidant properties was also based on the circumstance that amine molecules contain a set of functional groups which may be potential sites for the attack of both OH and anti e radicals. A sample of 6 M H/sub 3/PO/sub 4/ was used for the matrix solutions and forms a glass upon rapid insertion into liquid nitrogen. The phosphoric acid solutions of these compounds taken in concentrations from 0.025 to 0.05 M were flushed with argon to remove oxygen. Ampules containing the solutions were inserted into liquid nitrogen and irradiated from a cobalt source. The ESR spectra of the irradiated solutions clearly show the components of the atomic hydrogen doublet with a = 50 mT and of H/sub 2/PO/sub 4//sup ./ radicals in the central region of the spectrum.

  11. Installation of reactive metals groundwater collection and treatment systems

    SciTech Connect (OSTI)

    Hopkins, J.K.; Primrose, A.L.; Vogan, J.; Uhland, J.

    1998-07-01

    Three groundwater plumes contaminated with volatile organic compounds (VOCs) and radionuclides at the Rocky Flats Environmental Technology Site are scheduled for remediation by 1999 based on the Rocky Flats Cleanup Agreement (RFCA) (DOE, 1996). These three plumes are among the top 20 environmental cleanup sites at Rocky Flats. One of these plumes, the Mound Site Plume, is derived from a previous drum storage area, and daylights as seeps near the South Walnut Creek drainage. Final design for remediation of the Mound Site Plume has been completed based on use of reactive metals to treat the contaminated groundwater, and construction is scheduled for early 1998. The two other plumes, the 903 Pad/Ryan`s Pit and the East Trenches Plumes, are derived from VOCs either from drums that leaked or that were disposed of in trenches. These two plumes are undergoing characterization and conceptual design in 1998 and construction is scheduled in 1999. The contaminants of concern in these plumes are tetrachloroethene, trichloroethene, carbon tetrachloride and low levels of uranium and americium.

  12. Apparatus for continuously referenced analysis of reactive components in solution

    DOE Patents [OSTI]

    Bostick, William D.; Denton, Mark S.; Dinsmore, Stanley R.

    1981-01-01

    A continuously referenced apparatus for measuring the concentration of a reactive chemical species in solution comprises in combination conduit means for introducing a sample solution, means for introducing one or more reactants into a sample solution, a reaction zone in fluid communication with said conduit means wherein a first chemical reaction occurs between said species and reactants, and a stream separator disposed within the conduit means for separating the sample solution into a sample stream and a reference stream. An enzymatic reactor is disposed in fluid communication with only the sample stream wherein a second reaction takes place between the said reactants, species, and reactor enzymes causing the consumption or production of an indicator species in just the sample stream. Measurement means such as a photometric system are disposed in communication with the sample and reference streams, and the outputs of the measurement means are compared to provide a blanked measurement of the concentration of indicator species. A peristaltic pump is provided to equalize flow through the apparatus by evacuation. The apparatus is particularly suitable for measurement of isoenzymes in body tissues or fluids.

  13. LX-17 Corner-Turning and Reactive Flow Failure

    SciTech Connect (OSTI)

    Souers, P C; Andreski, H; Cook III, C F; Garza, R; Pastrone, R; Phillips, D; Roeske, F; Vitello, P; Molitoris, J

    2004-03-11

    We have performed a series of highly-instrumented experiments examining corner-turning of detonation. A TATB booster is inset 15 mm into LX-17 (92.5% TATB, 7.5% kel-F) so that the detonation must turn a right angle around an air well. An optical pin located at the edge of the TATB gives the start time of the corner-turn. The breakout time on the side and back edges is measured with streak cameras. Three high-resolution X-ray images were taken on each experiment to examine the details of the detonation. We have concluded that the detonation cannot turn the corner and subsequently fails, but the shock wave continues to propagate in the unreacted explosive, leaving behind a dead zone. The detonation front farther out from the corner slowly turns and eventually reaches the air well edge 180{sup o} from its original direction. The dead zone is stable and persists 7.7 {micro}s after the corner-turn, although it has drifted into the original air well area. Our regular reactive flow computer models sometimes show temporary failure but they recover quickly and are unable to model the dead zones. We present a failure model that cuts off the reaction rate below certain detonation velocities and reproduces the qualitative features of the corner-turning failure.

  14. Correlation methods

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1981-01-01

    Correlation methods have been developed to provide a quick and relatively simple technique for estimating the performance of passive solar systems. The correlations are done with respect to data generated from simulation models. The techniques and accuracies are described. Both the Solar Load Ratio and Un-Utilizability methods are described. The advantages and limitations of correlation methods as design tools are discussed.

  15. Rapid method for the determination of 226Ra in hydraulic fracturing wastewater samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Warren, Richard A.; McAlister, Daniel R.

    2016-03-24

    A new method that rapidly preconcentrates and measures 226Ra from hydraulic fracturing wastewater samples was developed in the Savannah River Environmental Laboratory. The method improves the quality of 226Ra measurements using gamma spectrometry by providing up to 100x preconcentration of 226Ra from this difficult sample matrix, which contains very high levels of calcium, barium, strontium, magnesium and sodium. The high chemical yield, typically 80-90%, facilitates a low detection limit, important for lower level samples, and indicates method ruggedness. Ba-133 tracer is used to determine chemical yield and correct for geometry-related counting issues. The 226Ra sample preparation takes < 2 hours.

  16. Reactivity of iron-bearing minerals and CO2 sequestration: A multi-disciplinary experimental approach

    SciTech Connect (OSTI)

    Schoonen, Martin A.

    2014-12-22

    The reactivity of sandstones was studied under conditions relevant to the injection of supercritical carbon dioxide in the context of carbon geosequestration. The emphasis of the study was on the reactivity of iron-bearing minerals when exposed to supercritical CO2 (scCO2) and scCO2 with commingled aqueous solutions containing H2S and/or SO2. Flow through and batch experiments were conducted. Results indicate that sandstones, irrespective of their mineralogy, are not reactive when exposed to pure scCO2 or scCO2 with commingled aqueous solutions containing H2S and/or SO2 under conditions simulating the environment near the injection point (flow through experiments). However, sandstones are reactive under conditions simulating the edge of the injected CO2 plume or ahead of the plume (batch experiments). Sandstones containing hematite (red sandstone) are particularly reactive. The composition of the reaction products is strongly dependent on the composition of the aqueous phase. The presence of dissolved sulfide leads to the conversion of hematite into pyrite and siderite. The relative amount of the pyrite and siderite is influenced by the ionic strength of the solution. Little reactivity is observed when sulfite is present in the aqueous phase. Sandstones without hematite (grey sandstones) show little reactivity regardless of the solution composition.

  17. Final Report- Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

    Broader source: Energy.gov [DOE]

    Final Report - Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

  18. Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing

    Office of Energy Efficiency and Renewable Energy (EERE)

    Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing

  19. Predicting fissile content of spent nuclear fuel assemblies with the passive neutron Albedo reactivity technique and Monte Carlo code emulation

    SciTech Connect (OSTI)

    Conlin, Jeremy Lloyd; Tobin, Stephen J

    2010-10-13

    There is a great need in the safeguards community to be able to nondestructively quantify the mass of plutonium of a spent nuclear fuel assembly. As part of the Next Generation of Safeguards Initiative, we are investigating several techniques, or detector systems, which, when integrated, will be capable of quantifying the plutonium mass of a spent fuel assembly without dismantling the assembly. This paper reports on the simulation of one of these techniques, the Passive Neutron Albedo Reactivity with Fission Chambers (PNAR-FC) system. The response of this system over a wide range of spent fuel assemblies with different burnup, initial enrichment, and cooling time characteristics is shown. A Monte Carlo method of using these modeled results to estimate the fissile content of a spent fuel assembly has been developed. A few numerical simulations of using this method are shown. Finally, additional developments still needed and being worked on are discussed.

  20. Boron-carbide-aluminum and boron-carbide-reactive metal cermets. [B/sub 4/C-Al

    DOE Patents [OSTI]

    Halverson, D.C.; Pyzik, A.J.; Aksay, I.A.

    1985-05-06

    Hard, tough, lighweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidated step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modules of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi..sqrt..in. These composites and methods can be used to form a variety of structural elements.

  1. Long-Term Monitoring of Permeable Reactive Barriers - Progress Report

    SciTech Connect (OSTI)

    Liang, L.

    2001-04-12

    The purpose of this project is to conduct collaborative research to evaluate and maximize the effectiveness of permeable reactive barriers (PRBs) with a broad-based working group including representatives from the U.S. Department of Energy (DOE), U.S. Department of Defense (DoD), and the U.S. Environmental Protection Agency (EPA). The Naval Facilities Engineering Service Center (NFESC) and its project partner, Battelle, are leading the DoD effort with funding from DoD's Environmental Security Technology Certification Program (ESTCP) and Strategic Environmental Research and Development Program (SERDP). Oak Ridge National Laboratory (ORNL) is coordinating the DOE effort with support from Subsurface Contaminant Focus Area (SCFA), a research program under DOEs Office of Science and Technology. The National Risk Management Research Laboratory's Subsurface Protection and Remediation Division is leading EPA's effort. The combined effort of these three agencies allows the evaluation of a large number of sites. Documents generated by this joint project will be reviewed by the participating agencies' principal investigators, the Permeable Barriers Group of the Remediation Technologies Development Forum (RTDF), and the Interstate Technology and Regulatory Cooperation (ITRC). The technical objectives of this project are to collect and review existing field data at selected PRB sites, identify data gaps, conduct additional measurements, and provide recommendations to DOE users on suitable long-term monitoring strategies. The specific objectives are to (1) evaluate geochemical and hydraulic performance of PRBs, (2) develop guidelines for hydraulic and geochemical characterization/monitoring, and (3) devise and implement long-term monitoring strategies through the use of hydrological and geochemical models. Accomplishing these objectives will provide valuable information regarding the optimum configuration and lifetime of barriers at specific sites. It will also permit

  2. Review of Reactivity Experiments for Lithium Ternary Alloys

    SciTech Connect (OSTI)

    Jolodosky, A.; Bolind, A.; Fratoni, M.

    2015-09-28

    Lithium is often the preferred choice as breeder and coolant in fusion blankets as it offers high tritium breeding, excellent heat transfer and corrosion properties, and most importantly, it has very high tritium solubility and results in very low levels of tritium permeation throughout the facility infrastructure. However, lithium metal vigorously reacts with air and water and exacerbates plant safety concerns. Consequently, Lawrence Livermore National Laboratory (LLNL) is attempting to develop a lithium-based alloy—most likely a ternary alloy—which maintains the beneficial properties of lithium (e.g. high tritium breeding and solubility) while reducing overall flammability concerns for use in the blanket of an inertial fusion energy (IFE) power plant. The LLNL concept employs inertial confinement fusion (ICF) through the use of lasers aimed at an indirect-driven target composed of deuterium-tritium fuel. The fusion driver/target design implements the same physics currently experimented at the National Ignition Facility (NIF). The plant uses lithium in both the primary coolant and blanket; therefore, lithium related hazards are of primary concern. Reducing chemical reactivity is the primary motivation for the development of new lithium alloys, and it is therefore important to come up with proper ways to conduct experiments that can physically study this phenomenon. This paper will start to explore this area by outlining relevant past experiments conducted with lithium/air reactions and lithium/water reactions. Looking at what was done in the past will then give us a general idea of how we can setup our own experiments to test a variety of lithium alloys.

  3. Instantaneous reactive power and power factor of instantaneous...

    Office of Scientific and Technical Information (OSTI)

    This provides a theoretical foundation for power quality monitoring, diagnostics, and compensation methods. Authors: Hsu, J.S. Publication Date: 1998-02-01 OSTI Identifier: 654174 ...

  4. An example of neutronic penalizations in reactivity transient analysis using 3D coupled chain HEMERA

    SciTech Connect (OSTI)

    Dubois, F.; Normand, B.; Sargeni, A.

    2012-07-01

    HEMERA (Highly Evolutionary Methods for Extensive Reactor Analyses), is a fully coupled 3D computational chain developed jointly by IRSN and CEA. It is composed of CRONOS2 (core neutronics, cross sections library from APOLLO2), FLICA4 (core thermal-hydraulics) and the system code CATHARE. Multi-level and multi-dimensional models are developed to account for neutronics, core thermal-hydraulics, fuel thermal analysis and system thermal-hydraulics, dedicated to best-estimate, conservative simulations and sensitivity analysis. In IRSN, the HEMERA chain is widely used to study several types of reactivity accidents and for sensitivity studies. Just as an example of the HEMERA possibilities, we present here two types of neutronic penalizations and their impact on a power transient due to a REA (Rod Ejection Accident): in the first one, we studied a bum-up distribution modification and in the second one, a delayed-neutron fraction modification. Both modifications are applied to the whole core or localized in a few assemblies. Results show that it is possible to use global or local changes but 1) in case of bum-up modification, the total core power can increase when assembly peak power decrease so, care has to be taken if the goal is to maximize a local power peak and 2) for delayed-neutron fraction, a local modification can have the same effect as the one on the whole core, provided that it is large enough. (authors)

  5. Photodetachment and electron reactivity in 1-methyl-1-butyl-pyrrolidinium bis(trifluoromethylsulfonyl)amide

    SciTech Connect (OSTI)

    Molins i Domenech, Francesc; FitzPatrick, Benjamin; Healy, Andrew T.; Blank, David A.

    2012-07-21

    The transient absorption spectrum in the range 500 nm-1000 nm was measured with ultrafast time resolution on a flowing neat, aliphatic, room-temperature ionic liquid following anion photodetachment. In this region the spectrum was shown to be a combination of absorption from the electron and the hole. Spectrally-resolved electron quenching determined a bimodal shape for the hole spectrum in agreement with recent computational predictions on a smaller aliphatic ionic liquid [Margulis et al., J. Am. Chem. Soc. 133, 20186 (2011)]. For time delays beyond 15 ps, spectral evolution qualitatively agrees with recent radiolysis experiments [Wishart et al., Faraday Discuss. 154, 353 (2012)]. However, the shape of the spectrum is different, reflecting the contrast in ionization energy between the two methods. Previously unobserved reactivity of the electron was found with a time constant of 300 fs. The results demonstrate solvent control of the rate coefficient for reaction between the electron and proton, with a rapid decline in the rate within the first picosecond.

  6. Controllable generation of reactive oxygen species by femtosecond-laser irradiation

    SciTech Connect (OSTI)

    Yan, Wei; He, Hao Wang, Yintao; Wang, Yisen; Hu, Minglie; Wang, Chingyue

    2014-02-24

    Femtosecond lasers have been advancing Biophotonics research in the past two decades with multiphoton microscopy, microsurgery, and photodynamic therapy. Nevertheless, laser irradiation is identified to bring photodamage to cells via reactive oxygen species (ROS) generation with unclear mechanism. Meanwhile, currently in biological researches, there is no effective method to provide controllable ROS production precisely, which originally is leaked from mitochondria during respiration and plays a key role in a lot of important cellular processes and cellular signaling pathways. In this study, we show the process of how the tightly focused femtosecond-laser induces ROS generation solely in mitochondria at the very beginning and then release to cytosol if the stimulus is intense enough. At certain weak power levels, the laser pulses induce merely moderate Ca{sup 2+} release but this is necessary for the laser to generate ROS in mitochondria. Cellular original ROS are also involved with a small contribution. When the power is above a threshold, ROS are then released to cytosol, indicating photodamage overwhelming cellular repair ability. The mechanisms in those two cases are quite different. Those results clarify parts of the mechanism in laser-induced ROS generation. Hence, it is possible to further this optical scheme to provide controllable ROS generation for ROS-related biological researches including mitochondrial diseases and aging.

  7. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  8. Structural and optical properties of DC reactive magnetron sputtered zinc aluminum oxide thin films

    SciTech Connect (OSTI)

    Kumar, B. Rajesh; Rao, T. Subba

    2014-10-15

    Highly transparent conductive Zinc Aluminum Oxide (ZAO) thin films have been deposited on glass substrates using DC reactive magnetron sputtering method. The thin films were deposited at 200 C and post-deposition annealing from 15 to 90 min. XRD patterns of ZAO films exhibit only (0 0 2) diffraction peak, indicating that they have c-axis preferred orientation perpendicular to the substrate. Scanning electron microscopy (SEM) is used to study the surface morphology of the films. The grain size obtained from SEM images of ZAO thin films are found to be in the range of 20 - 26 nm. The minimum resistivity of 1.74 10{sup ?4} ? cm and an average transmittance of 92% are obtained for the thin film post annealed for 30 min. The optical band gap of ZAO thin films increased from 3.49 to 3.60 eV with the increase of annealing time due to Burstein-Moss effect. The optical constants refractive index (n) and extinction coefficient (k) were also determined from the optical transmission spectra.

  9. Connection method

    DOE Patents [OSTI]

    Weyand, John D.

    1986-01-01

    A method of making a region exhibiting a range of compositions, comprising plasma spraying various compositions on top of one another onto a base.

  10. Connection method

    DOE Patents [OSTI]

    Weyand, J.D.

    1986-11-18

    A method is disclosed of making a region exhibiting a range of compositions, comprising plasma spraying various compositions on top of one another onto a base. 2 figs.

  11. Real Power and Reactive Power Control of a Three-Phase Single-Stage-PV System and PV voltage Stability

    SciTech Connect (OSTI)

    Li, Huijuan; Xu, Yan; Adhikari, Sarina; Rizy, D Tom; Li, Fangxing; Irminger, Philip

    2012-01-01

    Grid-connected photovoltaic (PV) systems with power electronic interfaces can provide both real and reactive power to meet power system needs with appropriate control algorithms. This paper presents the control algorithm design for a three-phase single-stage grid-connected PV inverter to achieve either maximum power point tracking (MPPT) or a certain amount of real power injection, as well as the voltage/var control. The switching between MPPT control mode and a certain amount of real power control mode is automatic and seamless. Without the DC-to-DC booster stage, PV DC voltage stability is an important issue in the control design especially when the PV inverter is operating at maximum power point (MPP) with voltage/var control. The PV DC voltage collapse phenomenon and its reason are discussed. The method based on dynamic correction of the PV inverter output is proposed to ensure PV DC voltage stability. Simulation results of the single-stage PV system during system disturbances and fast solar irradiation changes confirm that the proposed control algorithm for single-stage PV inverters can provide appropriate real and reactive power services and ensure PV DC voltage stability during dynamic system operation and atmospheric conditions.

  12. Influence of calcite on uranium(VI) reactive transport in the groundwaterriver mixing zone

    SciTech Connect (OSTI)

    Ma, Rui; Liu, Chongxuan; Greskowiak, Janek; Prommer, Henning; Zachara, John M.; Zheng, Chunmiao

    2014-01-23

    Calcite is an important mineral that can affect uranyl reactive transport in subsurface sediments. This study investigated the distribution of calcite and its influence on uranyl adsorption and reactive transport in the groundwater-river mixing zone at US Hanford 300A, Washington State. Simulations using a 2D reactive transport model under field-relevant hydrogeochemical conditions revealed a complex distribution of calcite concentration as a result of dynamic groundwater-river interactions. The calcite concentration distribution in turn affected the spatial and temporal changes in aqueous carbonate, calcium, and pH, which subsequently influenced U(VI) mobility and discharge rates into the river. The results implied that calcite distribution and its concentration dynamics is an important consideration for field characterization, monitoring, and reactive transport prediction.

  13. Sub-picosecond IR study of the reactive intermediate in an alkane...

    Office of Scientific and Technical Information (OSTI)

    Sub-picosecond IR study of the reactive intermediate in an alkane C-H bond activation reaction by CpRh(CO)2 Citation Details In-Document Search Title: Sub-picosecond IR study of ...

  14. Memo to Reactivate a Directive Placed on Hold for DOE - DOE Directives,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Delegations, and Requirements DOE by Website Administrator application/vnd.openxmlformats-officedocument.wordprocessingml.document icon memo_to_reactivate_directive_on_hold_doe -5.docx - application/vnd.openxmlformats-officedocument.wordprocessingml.document, 15 KB (15629

  15. Memo to Reactivate a Directive Placed on Hold for NNSA - DOE Directives,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Delegations, and Requirements NNSA by Website Administrator Microsoft Word Document icon memo_to_reactivate_directive_on_hold_nnsa -5 (1).doc - Microsoft Word Document, 25 KB (26112

  16. The evaluation of the Nippon Steel Corporation reactivity and post-reaction-strength test for coke

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    A systematic investigation was made of the factors influencing the reactivity of coke, including test temperature, coke structural properties, mineral inclusions and additives, and the inert content of the charge.

  17. Assessment of the Economic Potential of Microgrids for Reactive Power Supply

    SciTech Connect (OSTI)

    Appen, Jan von; Marnay, Chris; Stadler, Michael; Momber, Ilan; Klapp, David; Scheven, Alexander von

    2011-05-01

    As power generation from variable distributed energy resources (DER) grows, energy flows in the network are changing, increasing the requirements for ancillary services, including voltage support. With the appropriate power converter, DER can provide ancillary services such as frequency control and voltage support. This paper outlines the economic potential of DERs coordinated in a microgrid to provide reactive power and voltage support at its point of common coupling. The DER Customer Adoption Model assesses the costs of providing reactive power, given local utility rules. Depending on the installed DER, the cost minimizing solution for supplying reactive power locally is chosen. Costs include the variable cost of the additional losses and the investment cost of appropriately over-sizing converters or purchasing capacitors. A case study of a large health care building in San Francisco is used to evaluate different revenue possibilities of creating an incentive for microgrids to provide reactive power.

  18. Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing

    Office of Energy Efficiency and Renewable Energy (EERE)

    Final ReportPhase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical FlushingU. S. Environmental Protection Agency Region 8 SupportJanuary 2004

  19. Mild coal pretreatment to improve liquefaction reactivity. Quarterly technical progress report, June--August 1991

    SciTech Connect (OSTI)

    Miller, R.L.

    1991-12-31

    This report describes work completed during the fourth quarter of a three year project to study the effects of mild chemical pretreatment on coal dissolution reactivity during low severity liquefaction or coal/oil coprocessing. The overall objective of this research is to elucidate changes in the chemical and physical structure of coal by pretreating with methanol or other simple organic solvent and a trace amount of hydrochloric acid and measure the influence of these changes on coal dissolution reactivity. This work is part of a larger effort to develop a new coal liquefaction or coal/oil coprocessing scheme consisting of three main process steps: (1) mile pretreatment of the feed coal to enhance dissolution reactivity and dry the coal, (2) low severity thermal dissolution of the pretreated coal to obtain a very reactive coal-derived residual material amenable to upgrading, and (3) catalytic upgrading of the residual products to distillate liquids.

  20. Static reactive power compensators for high-voltage power systems. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-04-01

    A study conducted to summarize the role of static reactive power compensators for high voltage power system applications is described. This information should be useful to the utility system planning engineer in applying static var systems (SVS) to high voltage as (HVAC) systems. The static var system is defined as a form of reactive power compensator. The general need for reactive power compensation in HVAC systems is discussed, and the static var system is compared to other devices utilized to provide reactive power compensation. Examples are presented of applying SVS for specific functions, such as the prevention of voltage collapse. The operating principles of commercially available SVS's are discussed in detail. The perormance and active power loss characteristics of SVS types are compared.

  1. Enhanced transient reactivity of an O-sputtered Au(111) surface

    SciTech Connect (OSTI)

    Biener, M M; Biener, J; Friend, C M

    2004-12-02

    The interaction of SO{sub 2} with oxygen-sputtered Au(111) surfaces ({theta}{sub oxygen} {le} 0.35 ML) was studied by monitoring the oxygen and sulfur coverages as a function of SO{sub 2} exposure. Two reaction regimes were observed: oxygen depletion followed by sulfur deposition. An enhanced, transient sulfur deposition rate is observed at the oxygen depletion point. This effect is specifically pronounced if the Au surface is continuously exposed to SO{sub 2}. The enhanced reactivity towards S deposition seems to be linked to the presence of highly reactive, under-coordinated Au atoms. Adsorbed oxygen appears to stabilize, but also to block these sites. In absence of the stabilization effect of adsorbed oxygen, i.e. at the oxygen depletion point, the enhanced reactivity decays on a timescale of a few minutes. These observations shed a new light on the catalytic reactivity of highly dispersed gold nanoparticles.

  2. Permeability Modification Using a Reactive Alkaline-Soluble Biopolymer

    SciTech Connect (OSTI)

    Snadra L. Fox; X. Xie; K. D. Schaller; E. P. Robertson; G. A. Bala

    2003-10-01

    Polymer injection has been used in reservoirs to alleviate contrasting permeability zones. Current technology relies on the use of cross-linking agents to initiate gelation. The use of biological polymers are advantageous in that they can block high permeability areas, are environmentally friendly, and have potential to form reversible gels without the use of hazardous cross-linkers. Recent efforts at the Idaho National Engineering and Environmental Laboratory (INEEL) have produced a reactive alkaline-soluble biopolymer from Agrobacterium sp. ATCC no. 31749 that gels upon decreasing the pH of the polymeric solution. The focus of this study was to determine the impact an alkaline-soluble biopolymer can have on sandstone permeability. Permeability modification was investigated by injecting solubilized biopolymer into Berea sandstone cores and defining the contribution of pH, salt, temperature, and Schuricht crude oil on biopolymer gelation. The biopolymer was soluble in KOH at a pH greater than 11.4 and gelled when the pH dropped below 10.8. The Berea sandstone core buffered the biopolymer solution, decreasing the pH sufficiently to form a gel, which subsequently decreased the permeability. The effluent pH of the control cores injected with 0.01 {und M} KOH (pH 12.0) and 0.10{und M} KOH (pH 13.0) decreased to 10.6 and 12.7, respectively. The permeability of the sandstone core injected with biopolymer was decreased to greater than 95% of the original permeability at 25 C in the presence of 2% NaCl, and Schuricht crude oil; however, the permeability increased when the temperature of the core was increased to 60 C. Residual resistance factors as high as 792 were seen in Berea cores treated with biopolymer. The buffering capacity of sandstone has been demonstrated to reduce the pH of a biopolymer solution sufficiently to cause the polymer to form a stable in-situ gel. This finding could potentially lead to alternate technology for permeability modification, thus

  3. Photoisomerization and photodissociation dynamics of reactive free radicals

    SciTech Connect (OSTI)

    Bise, Ryan T.

    2000-08-24

    The photofragmentation pathways of chemically reactive free radicals have been examined using the technique of fast beam photofragment translational spectroscopy. Measurements of the photodissociation cross-sections, product branching ratios, product state energy distributions, and angular distributions provide insight into the excited state potential energy surfaces and nonadiabatic processes involved in the dissociation mechanisms. Photodissociation spectroscopy and dynamics of the predissociative {tilde A}{sup 2}A{sub 1} and {tilde B}{sup 2}A{sub 2} states of CH{sub 3}S have been investigated. At all photon energies, CH{sub 3} + S({sup 3}P{sub j}), was the main reaction channel. The translational energy distributions reveal resolved structure corresponding to vibrational excitation of the CH{sub 3} umbrella mode and the S({sup 3}P{sub j}) fine-structure distribution from which the nature of the coupled repulsive surfaces is inferred. Dissociation rates are deduced from the photofragment angular distributions, which depend intimately on the degree of vibrational excitation in the C-S stretch. Nitrogen combustion radicals, NCN, CNN and HNCN have also been studied. For all three radicals, the elimination of molecular nitrogen is the primary reaction channel. Excitation to linear excited triplet and singlet electronic states of the NCN radical generates resolved vibrational structure of the N{sub 2} photofragment. The relatively low fragment rotational excitation suggests dissociation via a symmetric C{sub 2V} transition state. Resolved vibrational structure of the N{sub 2} photofragment is also observed in the photodissociation of the HNCN radical. The fragment vibrational and rotational distributions broaden with increased excitation energy. Simple dissociation models suggest that the HNCN radical isomerizes to a cyclic intermediate (c-HCNN) which then dissociates via a tight cyclic transition state. In contrast to the radicals mentioned above, resolved

  4. Methods Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Methods Research Methods being developed by MANTISSA Researchers Celeste: Bayesian modeling for astronomical images Randomized Linear Algebra for BioImaging Large-Scale PCA for Climate Efficient Graph Analytics for Genomics Unsupervised Learning for Neuroscience Deep Learning for Object Recognition Deep Learning for Daya Bay Unsupervised Learning in Neuroscience Last edited: 2016-07-18 16:52:3

  5. Semipermeable polymers and method for producing same

    DOE Patents [OSTI]

    Buschmann, Wayne E.

    2012-04-03

    A polyamide membrane comprising reaction product of an anhydrous solution comprising an anhydrous solvent, at least one polyfunctional secondary amine and a pre-polymer deposition catalyst; and an anhydrous, organic solvent solution comprising a polyfunctional aromatic amine-reactive reactant comprising one ring. A composite semipermeable membrane comprising the polyamide membrane on a porous support. A method of making a composite semipermeable membrane by coating a porous support with an anhydrous solution comprising an anhydrous solvent, a polyfunctional secondary amine and a pre-polymer deposition catalyst, to form an activated pre-polymer layer on the porous support and contacting the activated pre-polymer layer with an anhydrous, organic solvent solution comprising a polyfunctional amine-reactive reactant to interfacially condense the amine-reactive reactant with the polyfunctional secondary amine, thereby forming a cross-linked, interfacial polyamide layer on the porous support. A method of impregnating a composite semipermeable membrane with nanoparticles selected from heavy metals and/or oxides of heavy metals.

  6. Non-cementitious compositions comprising vaterite and methods thereof

    DOE Patents [OSTI]

    Devenney, Martin; Fernandez, Miguel; Morgan, Samuel O.

    2015-09-15

    Non-cementitious compositions and products are provided. The compositions of the invention include a carbonate additive comprising vaterite such as reactive vaterite. Additional aspects of the invention include methods of making and using the non-cementitious compositions and products.

  7. Method and apparatus for pyrolysis of atactic polypropylene

    DOE Patents [OSTI]

    Staffin, H.K.; Roaper, R.B.

    1986-09-23

    This invention relates to an apparatus and a method for pyrolytic decomposition of polymeric materials into lower molecular weight products involving the heat treatment of raw polymeric material within reactive conduits submerged in a fluidized bed furnace operated at pyrolyzing temperatures. 1 fig.

  8. Method of producing adherent metal oxide coatings on metallic surfaces

    DOE Patents [OSTI]

    Lane, Michael H.; Varrin, Jr., Robert D.

    2001-01-01

    Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

  9. Method and apparatus for pyrolysis of atactic polypropylene

    DOE Patents [OSTI]

    Staffin, H. Kenneth; Roaper, R. B.

    1986-09-23

    This invention relates to an apparatus and a method for pyrolytic decomposition of polymeric materials into lower molecular weight products involving the heat treatment of raw polymeric material within reactive conduits submerged in a fluidized bed furnace operated at pyrolizing temperatures.

  10. Reactive Dehydration technology for Production of Fuels and Chemicals from Biomass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dr. James R. Kittrell, KSE, Inc. Dr. Carl R. Dupre, KSE, Inc. Dr. Michael F. Malone (Subcontractor) U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. 2 Project Objective Commercialize a novel reactive distillation technology using the iCARD platform (Intensified Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based

  11. Synthesis, characterization, and reactivity of pentamethylcyclopentadienyl complexes of divalent cobalt and nickel

    SciTech Connect (OSTI)

    Smith, M.E.

    1993-10-01

    The thesis is divided into the following 4 chapters: synthesis, characterization, and reactivity of trinuclear pentamethylcyclopentadienyl cobalt and nickel clusters with triply-bridging methylidyne groups; chemical and physical properties of pentamethylcyclopentadienyl acetylacetonate complexes of Co(II) and Ni(II); synthesis, characterization, and reactivity of pentamethylcyclopentadienyl halide complexes of Co and Ni; and crystallographic studies of distortions in metallocenes with C{sub 5}-symmetrical cyclopentadienyl rings.

  12. Modelling of multi-ion-beam reactive cosputtering for metal oxide thin films

    SciTech Connect (OSTI)

    Xiao, D.Q.; Zhu, J.G.; Qian, Z.H.; Peng, W.B.; Wei, L.F.; Li, Z.S.

    1995-12-31

    Very recently a new technique named multi-ion-beam reactive cosputtering (MIBRECS) was developed for preparing multi-component metal oxide thin films. Epitaxial or highly oriented (Pb, La) TiO{sub 3} thin films sputtered from pure metals of lead, titanium and lathanium were deposited by using this technique. In order to consummate the technique and to study the mechanism of reactive cosputtering, a general model of multi-ion-beam reactive cosputtering was proposed for the first time based on the well-known gas kinetics under stable sputtering circumstances, and a computer numerical simulation of the model was carried out with the parameters adopted in the experiments. The relationships among the sputtering ratios of the targets, and the coverage ratios of simple substances and oxides of the target metals on substrate surface with the total reactive gas flux and the densities of the sputtering ion beam were obtained respectively, and the hysteresis effect of the characteristic of reactive sputtering and the interactions during multi-ion-beam reactive cosputtering processes were also obtained. The numerical simulation results are at least qualitatively in agreement with the experiments.

  13. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

    2009-02-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  14. Numerical investigation of CO{sub 2} emission and thermal stability of a convective and radiative stockpile of reactive material in a cylindrical pipe of variable thermal conductivity

    SciTech Connect (OSTI)

    Lebelo, Ramoshweu Solomon

    2014-10-24

    In this paper the CO{sub 2} emission and thermal stability in a long cylindrical pipe of combustible reactive material with variable thermal conductivity are investigated. It is assumed that the cylindrical pipe loses heat by both convection and radiation at the surface. The nonlinear differential equations governing the problem are tackled numerically using Runge-Kutta-Fehlberg method coupled with shooting technique method. The effects of various thermophysical parameters on the temperature and carbon dioxide fields, together with critical conditions for thermal ignition are illustrated and discussed quantitatively.

  15. Rapid analysis of composition and reactivity in cellulosic biomass feedstocks with near-infrared spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Payne, Courtney E.; Wolfrum, Edward J.

    2015-03-12

    Obtaining accurate chemical composition and reactivity (measures of carbohydrate release and yield) information for biomass feedstocks in a timely manner is necessary for the commercialization of biofuels. Our objective was to use near-infrared (NIR) spectroscopy and partial least squares (PLS) multivariate analysis to develop calibration models to predict the feedstock composition and the release and yield of soluble carbohydrates generated by a bench-scale dilute acid pretreatment and enzymatic hydrolysis assay. Major feedstocks included in the calibration models are corn stover, sorghum, switchgrass, perennial cool season grasses, rice straw, and miscanthus. Here are the results: We present individual model statistics tomore » demonstrate model performance and validation samples to more accurately measure predictive quality of the models. The PLS-2 model for composition predicts glucan, xylan, lignin, and ash (wt%) with uncertainties similar to primary measurement methods. A PLS-2 model was developed to predict glucose and xylose release following pretreatment and enzymatic hydrolysis. An additional PLS-2 model was developed to predict glucan and xylan yield. PLS-1 models were developed to predict the sum of glucose/glucan and xylose/xylan for release and yield (grams per gram). The release and yield models have higher uncertainties than the primary methods used to develop the models. In conclusion, it is possible to build effective multispecies feedstock models for composition, as well as carbohydrate release and yield. The model for composition is useful for predicting glucan, xylan, lignin, and ash with good uncertainties. The release and yield models have higher uncertainties; however, these models are useful for rapidly screening sample populations to identify unusual samples.« less

  16. Rapid analysis of composition and reactivity in cellulosic biomass feedstocks with near-infrared spectroscopy

    SciTech Connect (OSTI)

    Payne, Courtney E.; Wolfrum, Edward J.

    2015-03-12

    Obtaining accurate chemical composition and reactivity (measures of carbohydrate release and yield) information for biomass feedstocks in a timely manner is necessary for the commercialization of biofuels. Our objective was to use near-infrared (NIR) spectroscopy and partial least squares (PLS) multivariate analysis to develop calibration models to predict the feedstock composition and the release and yield of soluble carbohydrates generated by a bench-scale dilute acid pretreatment and enzymatic hydrolysis assay. Major feedstocks included in the calibration models are corn stover, sorghum, switchgrass, perennial cool season grasses, rice straw, and miscanthus. Here are the results: We present individual model statistics to demonstrate model performance and validation samples to more accurately measure predictive quality of the models. The PLS-2 model for composition predicts glucan, xylan, lignin, and ash (wt%) with uncertainties similar to primary measurement methods. A PLS-2 model was developed to predict glucose and xylose release following pretreatment and enzymatic hydrolysis. An additional PLS-2 model was developed to predict glucan and xylan yield. PLS-1 models were developed to predict the sum of glucose/glucan and xylose/xylan for release and yield (grams per gram). The release and yield models have higher uncertainties than the primary methods used to develop the models. In conclusion, it is possible to build effective multispecies feedstock models for composition, as well as carbohydrate release and yield. The model for composition is useful for predicting glucan, xylan, lignin, and ash with good uncertainties. The release and yield models have higher uncertainties; however, these models are useful for rapidly screening sample populations to identify unusual samples.

  17. Reactive sputter deposition of pyrite structure transition metal disulfide thin films: Microstructure, transport, and magnetism

    SciTech Connect (OSTI)

    Baruth, A.; Manno, M.; Narasimhan, D.; Shankar, A.; Zhang, X.; Johnson, M.; Aydil, E. S.; Leighton, C. [Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2012-09-01

    Transition metal disulfides crystallizing in the pyrite structure (e.g., TMS{sub 2}, with TM = Fe, Co, Ni, and Cu) are a class of materials that display a remarkably diverse array of functional properties. These properties include highly spin-polarized ferromagnetism (in Co{sub 1-x}Fe{sub x}S{sub 2}), superconductivity (in CuS{sub 2}), an antiferromagnetic Mott insulating ground state (in NiS{sub 2}), and semiconduction with close to optimal parameters for solar absorber applications (in FeS{sub 2}). Exploitation of these properties in heterostructured devices requires the development of reliable and reproducible methods for the deposition of high quality pyrite structure thin films. In this manuscript, we report on the suitability of reactive sputter deposition from metallic targets in an Ar/H{sub 2}S environment as a method to achieve exactly this. Optimization of deposition temperature, Ar/H{sub 2}S pressure ratio, and total working gas pressure, assisted by plasma optical emission spectroscopy, reveals significant windows over which deposition of single-phase, polycrystalline, low roughness pyrite films can be achieved. This is illustrated for the test cases of the ferromagnetic metal CoS{sub 2} and the diamagnetic semiconductor FeS{sub 2}, for which detailed magnetic and transport characterization are provided. The results indicate significant improvements over alternative deposition techniques such as ex situ sulfidation of metal films, opening up exciting possibilities for all-sulfide heterostructured devices. In particular, in the FeS{sub 2} case it is suggested that fine-tuning of the sputtering conditions provides a potential means to manipulate doping levels and conduction mechanisms, critical issues in solar cell applications. Parenthetically, we note that conditions for synthesis of phase-pure monosulfides and thiospinels are also identified.

  18. Dispersoid reinforced alloy powder and method of making

    DOE Patents [OSTI]

    Anderson, Iver E; Terpstra, Robert L

    2014-10-21

    A method of making dispersion-strengthened alloy particles involves melting an alloy having a corrosion and/or oxidation resistance-imparting alloying element, a dispersoid-forming element, and a matrix metal wherein the dispersoid-forming element exhibits a greater tendency to react with a reactive species acquired from an atomizing gas than does the alloying element. The melted alloy is atomized with the atomizing gas including the reactive species to form atomized particles so that the reactive species is (a) dissolved in solid solution to a depth below the surface of atomized particles and/or (b) reacted with the dispersoid-forming element to form dispersoids in the atomized particles to a depth below the surface of said atomized particles. Bodies made from the dispersion strengthened solidified particles exhibit enhanced fatigue and creep resistance and reduced wear as well as enhanced corrosion and/or oxidation resistance at high temperatures.

  19. Electrodeionization method

    DOE Patents [OSTI]

    Lin, YuPo J.; Hestekin, Jamie; Arora, Michelle; St. Martin, Edward J.

    2004-09-28

    An electrodeionization method for continuously producing and or separating and/or concentrating ionizable organics present in dilute concentrations in an ionic solution while controlling the pH to within one to one-half pH unit method for continuously producing and or separating and/or concentrating ionizable organics present in dilute concentrations in an ionic solution while controlling the pH to within one to one-half pH unit.

  20. Nanofabrication of sharp diamond tips by e-beam lithography and inductively coupled plasma reactive ion etching.

    SciTech Connect (OSTI)

    Moldovan, N.; Divan, R.; Zeng, H.; Carlisle, J. A.; Advanced Diamond Tech.

    2009-12-07

    Ultrasharp diamond tips make excellent atomic force microscopy probes, field emitters, and abrasive articles due to diamond's outstanding physical properties, i.e., hardness, low friction coefficient, low work function, and toughness. Sharp diamond tips are currently fabricated as individual tips or arrays by three principal methods: (1) focused ion beam milling and gluing onto a cantilever of individual diamond tips, (2) coating silicon tips with diamond films, or (3) molding diamond into grooves etched in a sacrificial substrate, bonding the sacrificial substrate to another substrate or electrodepositing of a handling chip, followed by dissolution of the sacrificial substrate. The first method is tedious and serial in nature but does produce very sharp tips, the second method results in tips whose radius is limited by the thickness of the diamond coating, while the third method involves a costly bonding and release process and difficulties in thoroughly filling the high aspect ratio apex of molding grooves with diamond at the nanoscale. To overcome the difficulties with these existing methods, this article reports on the feasibility of the fabrication of sharp diamond tips by direct etching of ultrananocrystalline diamond (UNCD{reg_sign}) as a starting and structural material. The UNCD is reactive ion etched using a cap-precursor-mask scheme. An optimized etching recipe demonstrates the formation of ultrasharp diamond tips ({approx} 10 nm tip radius) with etch rates of 650 nm/min.