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Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Simulations of Deflagration-to-Detonation Transition in Reactive Gases |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

numerically generated pseudo-schlieren image numerically generated pseudo-schlieren image Weak ignition behind a reflected Mach=1.5 shock in a stoichiometric hydrogen-oxygen mixture at 0.1 atm initial pressure. Picture shows a numerically generated pseudo-schlieren image of the onset of a detonation in a turbulent boundary layer. Alexei Khokhlov, University of Chicago; Charles Bacon, Argonne National Laboratory, Joanna Austin, Andrew Knisely, University of Illinois at Urbanna-Champaign Simulations of Deflagration-to-Detonation Transition in Reactive Gases PI Name: Alexei Khokhlov PI Email: ajk@oddjob.uchicago.edu Institution: The University of Chicago Allocation Program: INCITE Allocation Hours at ALCF: 130 Million Year: 2013 Research Domain: Chemistry Hydrogen is an abundant, environmentally friendly fuel with the potential

2

Sorption of organic gases in residential rooms  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

residential rooms residential rooms Title Sorption of organic gases in residential rooms Publication Type Journal Article LBNL Report Number LBNL-59303 Year of Publication 2007 Authors Singer, Brett C., Alfred T. Hodgson, Toshifumi Hotchi, Katherine Y. Ming, Richard G. Sextro, Emily E. Wood, and Nancy J. Brown Journal Atmospheric Environment Volume 41 Start Page Chapter Pagination 3251-3265 Keywords adsorption, hazardous air pollutants, nerve agents, sink effect, volatile organic compounds Abstract Experiments were conducted to characterize organic gas sorption in residential rooms studied ''as-is'' with furnishings and material surfaces unaltered and in a furnished chamber designed to simulate a residential room. Results are presented for 10 rooms (five bedrooms, two bathrooms, a home office, and two multi-function spaces) and the chamber. Exposed materials were characterized and areas quantified. A mixture of volatile organic compounds (VOCs) was rapidly volatilized within each room as it was closed and sealed for a 5-h Adsorb phase; this was followed by 30-min Flush and 2-h closed-room Desorb phases. Included were alkane, aromatic, and oxygenated VOCs representing a range of ambient and indoor air pollutants. Three organophosphorus compounds served as surrogates for Sarin-like nerve agents. Measured gas-phase concentrations were fit to three variations of a mathematical model that considers sorption occurring at a surface sink and potentially a second, embedded sink. The 3-parameter sink-diffusion model provided acceptable fits for most compounds and the 4-parameter two-sink model provided acceptable fits for the others. Initial adsorption rates and sorptive partitioning increased with decreasing vapor pressure for the alkanes, aromatics and oxygenated VOCs. Best-fit sorption parameters obtained from experimental data from the chamber produced best-fit sorption parameters similar to those obtained from the residential rooms

3

Reactive gases evolved during pyrolysis of Devonian oil shale  

SciTech Connect (OSTI)

Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

1986-11-01T23:59:59.000Z

4

A conceptual design of a Reactive Ion Etch back end system for the direct reuse of process gases  

E-Print Network [OSTI]

The use of Plasma Etching, specifically Reactive Ion Etching (RIE), is a vital tool in manufacturing semiconductor devices. Most gases used in RIE processes were initially chosen because of their relatively low toxicity and reactivity. However, many...

Tiner, Paul Alan

2012-06-07T23:59:59.000Z

5

Physical Organic Chemistry of Reactive Intermediates | The Ames...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Physical Organic Chemistry of Reactive Intermediates The Jenks group specializes in physical organic chemistry, the "how" of organic reactions. Much of the work has centered on...

6

Sorption of organic gases in residential bedrooms and bathrooms  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sorption of organic gases in residential bedrooms and bathrooms Sorption of organic gases in residential bedrooms and bathrooms Title Sorption of organic gases in residential bedrooms and bathrooms Publication Type Conference Paper LBNL Report Number LBNL-56787 Year of Publication 2005 Authors Singer, Brett C., Alfred T. Hodgson, Toshifumi Hotchi, Katherine Y. Ming, Richard G. Sextro, Emily E. Wood, and Nancy J. Brown Conference Name Proceedings of the 10th International Conference on Indoor Air Quality and Climate - Indoor Air 2005 Volume 2(9) Publisher Tsinghua University Press Conference Location Beijing, China Abstract Experiments were conducted to characterize organic gas sorption in residential bedrooms (n=4), bathrooms (n=2), and a furnished test chamber. Rooms were studied "as-is" with material surfaces and furnishings unaltered. Surface materials were characterized and areas quantified. Experiments included rapid volatilization of a volatile organic compound (VOC) mixture with the room closed and sealed for a 5-h Adsorb phase, followed by 30-min Flush and 2-h closed-room Desorb phases. The mixture included n-alkanes, aromatics, glycol ethers, 2-ethyl-1-hexanol, dichlorobenzene, and organophosphorus compounds. Measured gas-phase concentrations were fit to three variations of a mathematical model that considers sorption occurring at one surface sink and one potential embedded sink. The 2-parameter sink model tracked measurements for most compounds, but improved fits were obtained for some VOCs with a 3-parameter sink-diffusion or a 4-parameter two-sink model. Sorptive partitioning and initial adsorption rates increased with decreasing vapour pressure within each chemical class.

7

Sorption of organic gases in a furnished room  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a furnished room a furnished room Title Sorption of organic gases in a furnished room Publication Type Journal Article LBNL Report Number LBNL-53943 Year of Publication 2004 Authors Singer, Brett C., Kenneth L. Revzan, Toshifumi Hotchi, Alfred T. Hodgson, and Nancy J. Brown Journal Atmospheric Environment Volume 38 Start Page Chapter Issue 16 Pagination 2483-2494 Abstract We present experimental data and semi-empirical models describing the sorption of organic gases in a simulated indoor residential environment. Two replicate experiments were conducted with 20 volatile organic compounds (VOCs) in a 50-m3 room finished with painted wallboard, carpet and cushion, draperies and furnishings. The VOCs span a wide volatility range and include ten Hazardous Air Pollutants. VOCs were introduced to the static chamber as a pulse and their gas-phase concentrations were measured during a net adsorption period and a subsequent net desorption period. Three sorption models were fit to the measured concentrations for each compound to determine the simplest formulation needed to adequately describe the observed behavior. Sorption parameter values were determined by fitting the models to adsorption period data then checked by comparing measured and predicted behavior during desorption. The adequacy of each model was evaluated using a goodness of fit parameter calculated for each period. Results indicate that sorption usually does not greatly affect indoor concentrations of methyl-tert-butyl ether, 2-butanone, isoprene and benzene. In contrast, sorption appears to be a relevant indoor process for many of the VOCs studied, including C8-C10 aromatic hydrocarbons (HC), terpenes, and pyridine. These compounds sorbed at rates close to typical residential air change rates and exhibited substantial sorptive partitioning at equilibrium. Polycyclic aromatic HCs, aromatic alcohols, ethenylpyridine and nicotine initially adsorbed to surfaces at rates of 1.5 to >6 h-1 and partitioned 95 to >99% in the sorbed phase at equilibrium

8

Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...  

Energy Savers [EERE]

organic gases (NMOG) and nitrogen oxides (NOx) that new light vehicles with gasoline engines are allowed to produce for model years 2017 to 2025. These standards apply to...

9

Flash Pyrolysis of Biomass with Reactive and Non-Reactive Gases: Summary Report for Period July 1983 through September 1984  

SciTech Connect (OSTI)

The purpose of this program is to study the conversion of biomass to liquid and gaseous hydrocarbon fuels and chemical feedstocks by a flash or rapid pyrolysis technique. During this period of study pine wood was flash pyrolyzed in atmospheres of methane and helium at a pressure of 50 psi and at temperatures up to 1050 C. The 1-inch I.D. entrained downflow tubular reactor was used in these experiments. Product yields of methane, ethane, ethylene, BTX, carbon monoxide and carbon dioxide were determined as a function of temperature and gas to wood ratio. Of particular interest were the ethylene and BTX yields. These represented as much as 29.6% and 24.6% of the carbon contained in the feed wood respectively when flash pyrolyzing in methane (flash methanolysls) and 14.7% and 9.7% when pyrolyzing in helium. In the case of flash methanolysis of wood the yields of ethylene and benzene increased with increasing methane to wood feed ratios. In the case of flash pyrolysis in helium the yields of ethylene and BTX decreased with increasing helium gas to wood feed ratios. These results indicate a mechanism by which a free radical reactive species originating from the wood interacts with the methane pyrolyzing gas to produce an enhanced yield of ethylene and benzene. The flash methanolysis of lignin extract from wood produced lower yields of ethylene, indicating the yields mainly originate from the cellulosic fractions of the wood. Some work was also performed on substituting wood ash for sillca flour (Cab-O-Sil) to allow free flow of wood particles through the entrained flow reactor. Preliminary process design and analysis indicates an economically competitive process for the flash methanolysis of wood for the production of methanol, benzene and ethylene. Future plans include completing the studies on obtaining the process chemistry of the flash methanolysis of woods, to obtain a better understanding of the enhanced ethylene and benzene yield and to investigate other biomass forms.

Steinberg M.; Fallon, P.T.; Sundaram, M.S.

1984-10-01T23:59:59.000Z

10

Nuclear magnetic resonance of laser-polarized noble gases in molecules, materials and organisms  

SciTech Connect (OSTI)

Conventional nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) are fundamentally challenged by the insensitivity that stems from the ordinarily low spin polarization achievable in even the strongest NMR magnets. However, by transferring angular momentum from laser light to electronic and nuclear spins, optical pumping methods can increase the nuclear spin polarization of noble gases by several orders of magnitude, thereby greatly enhancing their NMR sensitivity. This dissertation is primarily concerned with the principles and practice of optically pumped nuclear magnetic resonance (OPNMR). The enormous sensitivity enhancement afforded by optical pumping noble gases can be exploited to permit a variety of novel NMR experiments across many disciplines. Many such experiments are reviewed, including the void-space imaging of organisms and materials, NMR and MRI of living tissues, probing structure and dynamics of molecules in solution and on surfaces, and zero-field NMR and MRI.

Goodson, Boyd M.

1999-12-01T23:59:59.000Z

11

Separation of rare gases and chiral molecules by selective binding in porous organic cages  

SciTech Connect (OSTI)

Abstract: The rare gases krypton, xenon, and radon pose both an economic opportunity and a potential environmental hazard. Xenon is used in commercial lighting, medical imaging, and anesthesia, and can sell for $5,000 per kilogram. Radon, by contrast, Is naturally radioactive and the second largest cause of lung cancer, and radioactive xenon, 133Xe, was a major pollutant released In the Fukushima Daiichi Nuclear Power Plant disaster. We describe an organic cage molecule that can capture xenon and radon with unprecedented selectivity, suggesting new technologies for environmental monitoring, removal of pollutants, or the recovery of rare, valuable elements from air.

Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.; Holden, Daniel; Jelfs, Kim E.; Hasell, Tom; Little, Marc A.; Kewley, Adam; Briggs, Michael E.; Stephenson, Andrew; Thomas, K. M.; Armstrong, Jayne A.; Bell, Jon; Busto, Jose; Noel, Raymond; Liu, Jian; Strachan, Denis M.; Thallapally, Praveen K.; Cooper, Andrew I.

2014-10-31T23:59:59.000Z

12

Chemical Analysis of Complex Organic Mixtures Using Reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mass Spectrometry. Abstract: Reactive nanospray desorption electrospray ionization (nano-DESI) combined with high-resolution mass spectrometry was utilized for the analysis of...

13

Porous Metal-Organic Framework with Coordinatively Unsaturated MnII Sites:Sorption Properties for Various Gases  

E-Print Network [OSTI]

Porous Metal-Organic Framework with Coordinatively Unsaturated MnII Sites:Sorption Properties solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH4 gases and exhibits type I sorption behavior indicative of permanent

Paik Suh, Myunghyun

14

Non-invasive in situ plasma monitoring of reactive gases using the floating harmonic method for inductively coupled plasma etching application  

SciTech Connect (OSTI)

The floating harmonic method was developed for in situ plasma diagnostics of allowing real time measurement of electron temperature (T{sub e}) and ion flux (J{sub ion}) without contamination of the probe from surface modification by reactive species. In this study, this novel non-invasive diagnostic system was studied to characterize inductively coupled plasma of reactive gases monitoring T{sub e} and J{sub ion} for investigating the optimum plasma etching conditions and controlling of the real-time plasma surface reaction in the range of 200-900 W source power, 10-100 W bias power, and 3-15 mTorr chamber pressure, respectively.

Lee, J. H.; Kim, M. J. [Department of Materials Science and Engineering, University of Texas at Dallas, Texas 75080 (United States); Yoon, Y. S. [Department of Electrical Engineering, University of Texas at Dallas, Texas 75080 (United States)

2013-04-15T23:59:59.000Z

15

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. 1. Reactivity Based Trading and Potential for Ozone Hot Spot Formation  

Science Journals Connector (OSTI)

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. ... (12)?Thompson, T. M.; Wang, L.; Web, A.; McDonald-Buller, E.; Allen, D. T. Photochemical Modeling of the Air Quality Impacts of an Emissions Trading Program for Highly Reactive Volatile Organic Compounds (HRVOCs) in Texas; Air and Waste Management Association Annual Meeting, New Orleans, June, 2006. ...

Linlin Wang; Tammy Thompson; Elena C. McDonald-Buller; Alba Webb; David T. Allen

2007-02-27T23:59:59.000Z

16

Viscosity of -pinene secondary organic material and implications for particle growth and reactivity  

E-Print Network [OSTI]

Viscosity of -pinene secondary organic material and implications for particle growth and reactivity of secondary organic material (SOM) are abun- dant in the lower troposphere. The viscosity of these particles-mobility" technique and a "poke-flow" technique, in conjunction with simulations of fluid flow, the viscosity

17

Effect of residual gases in high vacuum on the energy-level alignment at noble metal/organic interfaces  

SciTech Connect (OSTI)

The energy-level alignment at metal/organic interfaces has traditionally been studied using ultraviolet photoelectron spectroscopy (UPS) in ultra-high vacuum (UHV). However, since most devices are fabricated in high vacuum (HV), these studies do not accurately reflect the interfaces in real devices. We demonstrate, using UPS measurements of samples prepared in HV and UHV and current-voltage measurements of devices prepared in HV, that the small amounts of residual gases that are adsorbed on the surface of clean Cu, Ag, and Au (i.e., the noble metals) in HV can significantly alter the energy-level alignment at metal/organic interfaces.

Helander, M. G.; Wang, Z. B.; Lu, Z. H.

2011-10-31T23:59:59.000Z

18

Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025  

Broader source: Energy.gov [DOE]

The Environmental Protection Agency finalized Tier 3 emission standards in a rule issued in March 2014. One effect of the rule is a decrease in the combined amount of non-methane organic gases ...

19

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. 2. Incorporation of Chlorine Emissions  

Science Journals Connector (OSTI)

As part of the State Implementation Plan for attaining the National Ambient Air Quality Standard for ozone, the Texas Commission of Environmental Quality has created a Highly Reactive Volatile Organic Compounds (HRVOC) Emissions Cap and Trade Program for ...

Linlin Wang; Tammy Thompson; Elena C. McDonald-Buller; David T. Allen

2007-02-27T23:59:59.000Z

20

Separation of polar gases from nonpolar gases  

DOE Patents [OSTI]

Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

Kulprathipanja, S.; Kulkarni, S.S.

1986-08-26T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Separation of polar gases from nonpolar gases  

DOE Patents [OSTI]

Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

1986-01-01T23:59:59.000Z

22

Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier  

DOE Patents [OSTI]

Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

Harrup, Mason K. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID)

2007-05-15T23:59:59.000Z

23

Viscosity of ?-pinene secondary organic material and implications for particle growth and reactivity  

SciTech Connect (OSTI)

Particles composed of secondary organic material (SOM) are abundant in the lower troposphere and play important roles in climate, air quality, and health. The viscosity of these particles is a fundamental property that is presently poorly quantified for conditions relevant to the lower troposphere. Using two new techniques, namely a bead-mobility technique and a poke-flow technique, in conjunction with simulations of fluid flow, we measure the viscosity of the watersoluble component of SOM produced by ?-pinene ozonolysis. The viscosity is comparable to that of honey at 90% relative humidity (RH), comparable to that of peanut butter at 70% RH and greater than or comparable to that of bitumen for ? 30% RH, implying that the studied SOM ranges from liquid to semisolid/solid at ambient relative humidities. With the Stokes-Einstein relation, the measured viscosities further imply that the growth and evaporation of SOM by the exchange of organic molecules between the gas and condensed phases may be confined to the surface region when RH ? 30%, suggesting the importance of an adsorption-type mechanism for partitioning in this regime. By comparison, for RH ? 70% partitioning of organic molecules may effectively occur by an absorption mechanism throughout the bulk of the particle. Finally, the net uptake rates of semi-reactive atmospheric oxidants such as O3 are expected to decrease by two to five orders of magnitude for a change in RH from 90% to ? 30% RH, with possible implications for the rates of chemical aging of SOM particles in the atmosphere.

Renbaum-Wolff, Lindsay; Grayson, James W.; Bateman, Adam P.; Kuwata, Mikinori; Sellier, Mathieu; Murray, Benjamin J.; Shilling, John E.; Martin, Scot T.; Bertram, Allan K.

2013-05-14T23:59:59.000Z

24

Airborne measurement of OH reactivity during INTEX-B  

E-Print Network [OSTI]

plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

2009-01-01T23:59:59.000Z

25

Correlation between gas-phase and solution-phase reactivities of hydroxyl radicals toward saturated organic compounds  

SciTech Connect (OSTI)

The gas-phase and aqueous-solution-phase reactivities of hydroxyl radicals with a wide variety of organic compounds are compared. When kinetic data are available for the same reaction occurring in both phases, this comparison provides useful information about the reaction mechanism. Through this comparison the authors can demonstrate a linear correlation between the gas/solution-phase OH reactivities for numerous saturated organic compounds. This empirical relationship can be used together with mechanistic information to estimate the OH reactivity in one phase from the measured rate constant in the other. In order to develop and extend the correlation, they have used the flash photolysis resonance fluorescence technique to measure rate constants for the gas-phase reactions of OH radicals with methanol-d/sub 4/, ethanol-d/sub 6/, 2-chloroethanol, 2,2,2-trichloroethanol, 2,2,2-trifluoroethanol, acetone-d/sub 6/, 1,1,1-trifluoroacetone, and 1,2-butylene oxide at 298 K. These results are reported herein.

Wallington, T.J.; Dagaut, P.; Kurylo, M.J.

1988-08-25T23:59:59.000Z

26

Voluntary Reporting of Greenhouse Gases  

Reports and Publications (EIA)

The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

2011-01-01T23:59:59.000Z

27

Adsorption and Separation of Light Gases on an Amino-Functionalized MetalľOrganic Framework: An Adsorption and In Situ XRD Study  

SciTech Connect (OSTI)

The NH{sub 2}-MIL-53(Al) metal-organic framework was studied for its use in the separation of CO{sub 2} from CH{sub 4}, H{sub 2}, N{sub 2} C{sub 2}H{sub 6} and C{sub 3}H{sub 8} mixtures. Isotherms of methane, ethane, propane, hydrogen, nitrogen, and CO{sub 2} were measured. The atypical shape of these isotherms is attributed to the breathing properties of the material, in which a transition from a very narrow pore form to a narrow pore form and from a narrow pore form to a large pore form occurs, depending on the total pressure and the nature of the adsorbate, as demonstrated by in-situ XRD patterns measured during adsorption. Apart from CO{sub 2}, all tested gases interacted weakly with the adsorbent. As a result, they are excluded from adsorption in the narrow pore form of the material at low pressure. CO{sub 2} interacted much more strongly and was adsorbed in significant amounts at low pressure. This gives the material excellent properties to separate CO{sub 2} from other gases. The separation of CO{sub 2} from methane, nitrogen, hydrogen, or a combination of these gases has been demonstrated by breakthrough experiments using pellets of NH{sub 2}-MIL-53(Al). The effect of total pressure (1-30 bar), gas composition, temperature (303-403 K) and contact time has been examined. In all cases, CO{sub 2} was selectively adsorbed, whereas methane, nitrogen, and hydrogen nearly did not adsorb at all. Regeneration of the adsorbent by thermal treatment, inert purge gas stripping, and pressure swing has been demonstrated. The NH{sub 2}-MIL-53(Al) pellets retained their selectivity and capacity for more than two years.

Couck S.; Stavitski E.; Gobehiya, E.; Kirschhock, C.E.A.; Serra-Crespo, P.; Juan-Alcaniz, J.; Martinez Joaristi, A.; Gascon, J.; Kapteijn, F.; Baron, G. V.; Denayer J.F.M.

2012-02-29T23:59:59.000Z

28

Development of efficiency-enhanced cogeneration system utilizing high-temperature exhaust-gas from a regenerative thermal oxidizer for waste volatile-organic-compound gases  

Science Journals Connector (OSTI)

We have developed a gas-turbine cogeneration system that makes effective use of the calorific value of the volatile organic compound (VOC) gases exhausted during production processes at a manufacturing plant. The system utilizes the high-temperature exhaust-gas from the regenerative thermal oxidizer (RTO) which is used for incinerating VOC gases. The high-temperature exhaust gas is employed to resuperheat the steam injected into the gasturbine. The steam-injection temperature raised in this way increases the heat input, resulting in the improved efficiency of the gas-turbine. Based on the actual operation of the system, we obtained the following results: Ľ Operation with the steam-injection temperature at 300á░C (45á░C resuperheated from 255á░C) increased the efficiency of the gasturbine by 0.7%. Ľ The system can enhance the efficiency by 1.3% when the steam-injection temperature is elevated to 340á░C (85á░C resuperheated). In this case, up to 6.6 million yen of the total energy cost and 400 tons of carbon dioxide (CO2) emissions can be reduced annually. Ľ A gas-turbine cogeneration and RTO system can reduce energy consumption by 23% and CO2 emission by 30.1% at the plant.

Masaaki Bannai; Akira Houkabe; Masahiko Furukawa; Takao Kashiwagi; Atsushi Akisawa; Takuya Yoshida; Hiroyuki Yamada

2006-01-01T23:59:59.000Z

29

Decisions to reduce greenhouse gases from agriculture and product transport: LCA case study of organic and conventional wheat  

Science Journals Connector (OSTI)

A streamlined hybrid life cycle assessment is conducted to compare the global warming potential (GWP) and primary energy use of conventional and organic wheat production and delivery in the US. Impact differences from agricultural inputs, grain farming, and transport processes are estimated. The GWP of a 1ákg loaf of organic wheat bread is about 30ág CO2-eq less than the conventional loaf. When organic wheat is shipped 420ákm farther to market, organic and conventional wheat systems have similar impacts. These results can change dramatically depending on soil carbon accumulation and nitrous oxide emissions from the two systems. Key parameters and their variability are discussed to provide producers, wholesale and retail consumers, and policymakers metrics to align their decisions with low-carbon objectives.

Kyle Meisterling; Constantine Samaras; Vanessa Schweizer

2009-01-01T23:59:59.000Z

30

Direct and indirect photoreactions of chromophoric dissolved organic matter : roles of reactive oxygen species and iron  

E-Print Network [OSTI]

Photochemical transformations of chromophoric dissolved organic matter (CDOM) are one of the principal processes controlling its fate in coastal waters. The photochemical decomposition of CDOM leads to the formation of a ...

Goldstone, Jared Verrill, 1971-

2002-01-01T23:59:59.000Z

31

-Draw a reaction mechanism based upon your gained knowledge of the reactivity of organic -Predict how organic molecules should interact with macromolecules, including components of  

E-Print Network [OSTI]

at Georgia Tech) and GT Engineers bookstore: 1) Book: "Essential Organic Chemistry", custom edition of organic molecules - Predict how organic molecules should interact with macromolecules, including of organic molecules in preventing childhood mortality, disrupting ecosystems, or driving sexual attraction

Houston, Paul L.

32

Greenhouse Gases Converted to Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Greenhouse Greenhouse Gases Converted to Fuel Greenhouse Gases Converted to Fuel carbon-conversion-fig-1.jpg Key Challenges: An important strategy for reducing global CO2 emissions calls for capturing the greenhouse gas and converting it to fuels and chemicals. Although researchers working toward that goal demonstrated in 1992 such a reaction in the lab, a key outstanding scientific challenge was explaining the details of how the reaction took place - its "mechanism." Why it Matters: An important potential strategy for reducing global CO2 emissions calls for capturing the greenhouse gas and converting it electrochemically to fuels and chemicals. Accomplishments: Computation to explain how carbon dioxide can be converted to small organic molecules with little energy input. The

33

Voluntary reporting of greenhouse gases, 1995  

SciTech Connect (OSTI)

The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

NONE

1996-07-01T23:59:59.000Z

34

Strongly interacting Fermi gases  

E-Print Network [OSTI]

Strongly interacting gases of ultracold fermions have become an amazingly rich test-bed for many-body theories of fermionic matter. Here we present our recent experiments on these systems. Firstly, we discuss high-precision ...

Bakr, W.

35

Reactive Maintenance  

Broader source: Energy.gov [DOE]

Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities.

36

The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation  

Open Energy Info (EERE)

Gases, Regulated Emissions, and Energy Use in Transportation Gases, Regulated Emissions, and Energy Use in Transportation Model (GREET) Jump to: navigation, search Tool Summary Name: The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation Model (GREET Fleet) Agency/Company /Organization: Argonne National Laboratory Sector: Energy Focus Area: Greenhouse Gas, Transportation Phase: Determine Baseline, Evaluate Options Topics: Baseline projection, GHG inventory Resource Type: Software/modeling tools User Interface: Spreadsheet Website: greet.es.anl.gov/main Cost: Free OpenEI Keyword(s): EERE tool, The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation Model, GREET References: GREET Fleet Main Page[1] Logo: The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation Model (GREET Fleet)

37

EIA-Voluntary Reporting of Greenhouse Gases Program  

U.S. Energy Information Administration (EIA) Indexed Site

of Greenhouse Gases Program of Greenhouse Gases Program Voluntary Reporting of Greenhouse Gases Program ***THE VOLUNTARY REPORTING OF GREENHOUSE GASES ("1605(b)") PROGRAM HAS BEEN SUSPENDED.*** This affects all survey respondents. Please visit the What's New page for full details. What Is the Voluntary Reporting Program? logo Established by Section 1605(b) of the Energy Policy Act of 1992, the Voluntary Reporting of Greenhouse Gases Program encourages corporations, government agencies, non-profit organizations, households, and other private and public entities to submit annual reports of their greenhouse gas emissions, emission reductions, and sequestration activities. The Program provides a means for voluntary reporting that is complete, reliable, and consistent. More information on the program...

38

Control of pollutants in flue gases and fuel gases  

E-Print Network [OSTI]

and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

Laughlin, Robert B.

39

Control of pollutants in flue gases and fuel gases  

E-Print Network [OSTI]

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . . 3-5 3.4 Emission

Zevenhoven, Ron

40

Federal Energy Management Program: Greenhouse Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Greenhouse Gases Greenhouse Gases to someone by E-mail Share Federal Energy Management Program: Greenhouse Gases on Facebook Tweet about Federal Energy Management Program: Greenhouse Gases on Twitter Bookmark Federal Energy Management Program: Greenhouse Gases on Google Bookmark Federal Energy Management Program: Greenhouse Gases on Delicious Rank Federal Energy Management Program: Greenhouse Gases on Digg Find More places to share Federal Energy Management Program: Greenhouse Gases on AddThis.com... Sustainable Buildings & Campuses Operations & Maintenance Greenhouse Gases Basics Federal Requirements Guidance & Reporting Inventories & Performance Mitigation Planning Resources Contacts Water Efficiency Data Center Energy Efficiency Industrial Facilities Sustainable Federal Fleets

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Global Research Alliance on Agricultural Greenhouse Gases | Open Energy  

Open Energy Info (EERE)

Global Research Alliance on Agricultural Greenhouse Gases Global Research Alliance on Agricultural Greenhouse Gases Jump to: navigation, search Name Global Research Alliance on Agricultural Greenhouse Gases Agency/Company /Organization United States Department of Agriculture Sector Land Focus Area Agriculture Topics GHG inventory, Policies/deployment programs Resource Type Guide/manual, Lessons learned/best practices Website http://globalresearchalliance. References Global Research Alliance on Agricultural Greenhouse Gases [1] Background "The Alliance is a bottom-up network, founded on the voluntary, collaborative efforts of countries. It will coordinate research on agricultural greenhouse gas emission reductions by linking up existing and new research efforts across a range of sub-sectors and work areas. It will

42

Organization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organization Print Organization Print 2012-12 org chart A complete ALS organization chart (June 2013) is available in PDF. Appointed and elected members of advisory panels provide guidance to Berkeley Lab and ALS management in developing the ALS scientific and user programs. ALS Staff Photo staff photo thumb Click on the image to see a recent photo of ALS staff in front of the dome. The photo was taken on May 14, 2013. ALS Management and Advisory Team Steve Kevan, Deputy Division Director, Science Michael J. Banda, Deputy Division Director, Operations Robert W. Schoenlein, Senior Staff Scientist, Next Generation Light Source Initiative Janos Kirz, Scientific Advisor Paul Adams, Division Deputy for Biosciences ALS Scientific, Technical, and User Support Groups Accelerator Physics

43

Greenhouse Gases | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Greenhouse Gases Greenhouse Gases Greenhouse Gases October 7, 2013 - 9:59am Addthis Executive Order 13514 requires Federal agencies to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate change. Basics: Read an overview of greenhouse gases. Federal Requirements: Look up requirements for agency greenhouse gas management as outlined in Federal initiatives and executive orders. Guidance and Reporting: Find guidance documents and resources for greenhouse gas accounting and reporting. GHG Inventories and Performance: See detailed comprehensive GHG inventories by Federal agency and progress toward achieving Scope 1 and 2 GHG and Scope 3 GHG reduction targets. Mitigation Planning: Learn how Federal agencies can cost-effectively meet their GHG reduction goals.

44

Degenerate quantum gases of strontium  

E-Print Network [OSTI]

Degenerate quantum gases of alkaline-earth-like elements open new opportunities in research areas ranging from molecular physics to the study of strongly correlated systems. These experiments exploit the rich electronic structure of these elements, which is markedly different from the one of other species for which quantum degeneracy has been attained. Specifically, alkaline-earth-like atoms, such as strontium, feature metastable triplet states, narrow intercombination lines, and a non-magnetic, closed-shell ground state. This review covers the creation of quantum degenerate gases of strontium and the first experiments performed with this new system. It focuses on laser-cooling and evaporation schemes, which enable the creation of Bose-Einstein condensates and degenerate Fermi gases of all strontium isotopes, and shows how they are used for the investigation of optical Feshbach resonances, the study of degenerate gases loaded into an optical lattice, as well as the coherent creation of Sr_2 molecules.

Stellmer, Simon; Killian, Thomas C

2013-01-01T23:59:59.000Z

45

Turning greenhouse gases into gold  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gases, with carbon dioxide (CO2) often accused of being the primary instigator of global climate change. As a result, numerous efforts are under way to find ways to prevent,...

46

ARM - What are Greenhouse Gases?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

radiative forcing (which means they enhance global warming). Many of these gases are naturally occurring and are essential to life on earth by providing a blanket for marine and...

47

Greenhouse Gases and Emissions Trading  

Science Journals Connector (OSTI)

Atmospheric concentrations of carbon dioxide and other greenhouse gases have grown rapidly since the beginning of this century. Unless emissions are controlled, the world could face rapid climate changes, incl...

Alice LeBlanc; Daniel J. Dudek

1993-01-01T23:59:59.000Z

48

Climate VISION: Greenhouse Gases Information  

Office of Scientific and Technical Information (OSTI)

GHG Information GHG Information Greenhouse Gases, Global Climate Change, and Energy Emissions of Greenhouse Gases in the United States 2001 [1605(a)] This report, required by Section 1605(a) of the Energy Policy Act of 1992, provides estimates of U.S. emissions of greenhouse gases, as well as information on the methods used to develop the estimates. The estimates are based on activity data and applied emissions factors, not on measured or metered emissions monitoring. Available Energy Footprints Industry NAICS* All Manufacturing Alumina & Aluminum 3313 Cement 327310 Chemicals 325 Fabricated Metals 332 Food and Beverages 311, 312 Forest Products 321, 322 Foundries 3315 Glass & Glass Products, Fiber Glass 3272, 3296 Iron & Steel Mills 331111 Machinery & Equipment 333, 334, 335, 336

49

Investigating and Using Biomass Gases  

K-12 Energy Lesson Plans and Activities Web site (EERE)

Students will be introduced to biomass gasification and will generate their own biomass gases. Students generate these everyday on their own and find it quite amusing, but this time theyĺll do it by heating wood pellets or wood splints in a test tube. They will collect the resulting gases and use the gas to roast a marshmallow. Students will also evaluate which biomass fuel is the best according to their own criteria or by examining the volume of gas produced by each type of fuel.

50

Finalize Historic National Program to Reduce Greenhouse Gases and Improve  

Open Energy Info (EERE)

Finalize Historic National Program to Reduce Greenhouse Gases and Improve Finalize Historic National Program to Reduce Greenhouse Gases and Improve Fuel Economy for Cars and Trucks Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Finalize Historic National Program to Reduce Greenhouse Gases and Improve Fuel Economy for Cars and Trucks Agency/Company /Organization: EPA and NHTSA Focus Area: Standards - Incentives - Policies - Regulations Topics: Policy Impacts Resource Type: Reports, Journal Articles, & Tools Website: www.epa.gov/oms/climate/regulations/420f10014.pdf This document establish a national program consisting of new standards for model year 2012 through 2016 light-duty vehicles that will reduce greenhouse gas emissions and improve fuel economy. EPA is finalizing the first-ever national greenhouse gas (GHG) emissions standards under the

51

Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation  

Open Energy Info (EERE)

Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) Model Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) Model Agency/Company /Organization: Argonne National Laboratory Focus Area: GHG Inventory Development Topics: Analysis Tools Website: greet.es.anl.gov/ This full life-cycle model evaluates the energy and emission impacts of advanced vehicle technologies and new transportation fuels. The model allows users to evaluate various vehicle and fuel combinations. How to Use This Tool This tool is most helpful when using these strategies: Shift - Change to low-carbon modes Improve - Enhance infrastructure & policies Learn more about the avoid, shift, improve framework for limiting air

52

Effect of temperature on reduction reactivity of oxygen carrier particles in a fixed bed chemical-looping combustor  

Science Journals Connector (OSTI)

In a chemical-looping combustor (CLC), gaseous fuel is oxidized...2...is separated from the exhaust gases during the combustion. In this study, NiO/bentonite particle...x formation during oxidation. Reactivity da...

Ho-Jung Ryu; Dal-Hee Bae; Gyoung-Tae Jin

2003-09-01T23:59:59.000Z

53

Clean Gases for Gas Chromatography  

Science Journals Connector (OSTI)

......to purchase such clean gases. Even research grades...no maintenance, at the cost of 500 watts of electrical...Exploration and Production Research Division, Hous...hour. The maintenance cost of the cold trap is only...displaces the contaminated gas which has passed into......

B. Osborne Prescott; Harold L. Wise

1966-02-01T23:59:59.000Z

54

Voluntary reporting of greenhouse gases 1997  

SciTech Connect (OSTI)

The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

NONE

1999-05-01T23:59:59.000Z

56

Industrial Gases as a Vehicle for Competitiveness  

E-Print Network [OSTI]

the diversity and options available to enable cost savings and environmentally driven process improvements. Industrial gases have come of age during the last fifteen years. Engineers and scientists have looked beyond the paradigms of their operations...INDUSTRIAL GASES AS A VEHICLE FOR COMPETITIVENESS James R. Dale, Director, Technology Programs, Airco Industrial Gases Division, The BOC Group, Inc., Murray Hill, New Jersey ABSTRACT Industrial gases are produced using compressed air...

Dale, J. R.

57

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory  

E-Print Network [OSTI]

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory Modifying memory: Selectively enhancing and updating personal memories for a museum; Reactivating personal memory 2 Abstract Memory can be modified when reactivated

Schacter, Daniel

58

The Viscosity of Compressed Gases  

Science Journals Connector (OSTI)

New data and a new theory for the viscosity of compressed gases are presented. Data for nitrogen, hydrogen and a mixture of these gases are given, in the calculation of which, the "end effects" are not neglected as has been done in the past. Previous viscosity data are of doubtful validity owing to neglect of this factor. The theory is based on an analogy between the kinetic pressure and viscosity of a gas and is derived using an equation of state of the Lorentz type. Allowance is made for the difference between the viscosity and compressibility covolumes. The theory is substantiated experimentally and further confirmed by the recalculation of other data on the variation of Reynolds' criterion with the pressure, which is here shown to be constant. The mixture data offer a direct opportunity of comparing the Lorentz and linear rules for the calculation of the covolume of a mixture from the covolumes of the components and such comparison indicates that the Lorentz rule is not to be preferred. The substantiation of the new theory is the first direct proof of the validity of the separate treatment of the kinetic and cohesive pressures in the equation of state.

James H. Boyd; Jr.

1930-05-15T23:59:59.000Z

59

ARM - Lesson Plans: Dissolved Gases in Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

released into the air, additional CO2 Would intensify an already-problematic greenhouse effect. Preparation Demonstrate that water contains invisible gases. Collect and cover...

60

Mechanical Stress and Reactivity in Organic Solids  

Science Journals Connector (OSTI)

...STOICHEFF, B.P., RARE GAS SOLIDS 2 : CH16 ( 1977...Specialty Operations, Corpus Christi, TX 78469. M. D. Holngswort...contains 13C or 180 in natural abundance. It is crucial...second radical, it is natural that the latter motion...

J. MICHAEL MCBRIDE; BRIGITTE E. SEGMULLER; MARK D. HOLLINGSWORTH; DAVID E. MILLS; BRUCE A. WEBER

1986-11-14T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Insights into Chemical Reactivity /  

E-Print Network [OSTI]

Modern Physical Organic Chemistry University Science Books:Modern Physical Organic Chemistry University Science Books:

Burke, Kathryn D.

2013-01-01T23:59:59.000Z

62

Granular gases under extreme driving  

E-Print Network [OSTI]

We study inelastic gases in two dimensions using event-driven molecular dynamics simulations. Our focus is the nature of the stationary state attained by rare injection of large amounts of energy to balance the dissipation due to collisions. We find that under such extreme driving, with the injection rate much smaller than the collision rate, the velocity distribution has a power-law high energy tail. The numerically measured exponent characterizing this tail is in excellent agreement with predictions of kinetic theory over a wide range of system parameters. We conclude that driving by rare but powerful energy injection leads to a well-mixed gas and constitutes an alternative mechanism for agitating granular matter. In this distinct nonequilibrium steady-state, energy cascades from large to small scales. Our simulations also show that when the injection rate is comparable with the collision rate, the velocity distribution has a stretched exponential tail.

W. Kang; J. Machta; E. Ben-Naim

2010-02-04T23:59:59.000Z

63

Formation and Reactivity of Biogenic Iron Microminerals  

SciTech Connect (OSTI)

The overall purpose of the project is to explore and quantify the processes that control the formation and reactivity of biogenic iron microminerals and their impact on the solubility of metal contaminants. The research addresses how surface components of bacterial cells, extracellular organic material, and the aqueous geochemistry of the DIRB microenvironment impacts the mineralogy, chemical state and micromorphology of reduced iron phases.

Beveridge, Terrance J.; Glasauer, Susan; Korenevsky, Anton; Ferris, F. Grant

2000-08-08T23:59:59.000Z

64

Modelling and experimental studies of biomass and organic pyrolysis.  

E-Print Network [OSTI]

??Pyrolysis is a thermal conversion process that decomposes organic materials into liquid hydrocarbons, carbonaceous residues and combustible gases in the absence of oxygen. Depending onů (more)

Lam, Ka Leung

2012-01-01T23:59:59.000Z

65

Photochemical production of polyols arising from significant photo-transformation of dissolved organic matter in the oligotrophic surface ocean  

E-Print Network [OSTI]

penetration and the photo-reactivity of organic matter. Quantitative analysis of mineralization rates (

2014-01-01T23:59:59.000Z

66

Raman Spectra of Polyatomic Gases  

Science Journals Connector (OSTI)

Raman spectra of gaseous CO2, N2O, NH3, CH4 and C2H4 have been photographed using the line ?2536 of mercury as the exciting radiation. Vibrational transitions have been observed in all the gases investigated, and rotational transitions in the cases of NH3 and CH4. For the frequency shifts due to the vibrational transitions, the following numerical values (in cm-1) have been found: CO2: 1264.5; 1285.1; 1387.7; 1408.4.CH4: 2914.8; 3022.1; 3071.5.N2O: 1281.8C2H4: 1342.4; 1623.3; 2880.1; 3019.3; 3240.3; 3272.3.NH3: 3333.6á Raman spectra of liquid NH3 have been photographed and found to give the two frequency shifts: 3298.4 and 3214.5. In the case of gaseous NH3, pure rotational transitions lead to a moment of inertia having the value I0=2.79Î10-40. In the case of methane, the positive and negative branches of the 3022.1 band lead to the value I0=5.17Î10-40. The relations between these data and infra-red absorption data are discussed.

R. G. Dickinson, R. T. Dillon, and F. Rasetti

1929-08-15T23:59:59.000Z

67

EIA-Voluntary Reporting of Greenhouse Gases Program - Reporting Guidelines  

U.S. Energy Information Administration (EIA) Indexed Site

Reporting Guidelines Reporting Guidelines Voluntary Reporting of Greenhouse Gases Program Reporting Guidelines The purpose of the guidelines is to establish the procedures and requirements for filing voluntary reports, and to ensure that the annual reports of greenhouse gas emissions, emission reductions, and sequestration activities submitted by corporations, government agencies, non-profit organizations, households, and other private and public entities to submit are complete, reliable, and consistent. Over time, it is anticipated that these reports will provide a reliable record of the contributions reporting entities have made toward reducing their greenhouse gas emissions. General Guidelines General Guidelines Technical Guidelines Technical Guidelines Appendices to the Technical Guidelines:

68

Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

69

EIA-Voluntary Reporting of Greenhouse Gases Program - What are...  

U.S. Energy Information Administration (EIA) Indexed Site

gases such as hydrofluorocarbons, perfluorocarbons, and sulfur hexafluoride). The Greenhouse Effect Concentrations of several important greenhouse gases have increased by about 33...

70

Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases  

SciTech Connect (OSTI)

The Performance Demonstration Program (PDP) for headspace gases distributes sample gases of volatile organic compounds (VOCs) for analysis. Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facilityĺs compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

Carlsbad Field Office

2006-04-01T23:59:59.000Z

71

Tropospheric Chemistry of Internally Mixed Sea Salt and Organic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tropospheric Chemistry of Internally Mixed Sea Salt and Organic Particles: Surprising Reactivity of NaCl with Weak Organic Acids Tropospheric Chemistry of Internally Mixed Sea Salt...

72

Comparing greenhouse gases for policy purposes  

E-Print Network [OSTI]

In order to derive optimal policies for greenhouse gas emissions control, the discounted marginal damages of emissions of different gases must be compared. The greenhouse warming potential (GWP) index, which is most often ...

Schmalensee, Richard

1993-01-01T23:59:59.000Z

73

Gases for an SSC muon detector  

SciTech Connect (OSTI)

Recent measurements of electron drift velocities as a function of the density-reduced electric field E/N are reported for a number of unitary gases and the mixtures CO{sub 2}/CH{sub 4} and NH{sub 3}/CF{sub 4}/Ar. Calculated values of the mean electron energy as a function of E/N are also reported for unitary gases and mixtures of CO{sub 2}/CH{sub 4}. 7 refs., 5 figs.

Christophorou, L.G.; Datskos, P.G.; Carter, J.G. (Oak Ridge National Lab., TN (USA) Tennessee Univ., Knoxville, TN (USA). Dept. of Physics and Astronomy)

1990-01-01T23:59:59.000Z

74

Emissions of greenhouse gases in the United States, 1985--1990  

SciTech Connect (OSTI)

The Earth`s capacity to support life depends on the moderating influences of gases that envelop the planet and warm its surface and protect it from harmful radiation. These gases are referred to as ``greenhouse gases.`` Their warming capacity, called ``the greenhouse effect,`` is essential to maintaining a climate hospitable to all plant, animal, and human life. In recent years, however, there has been increasing concern that human activity may be affecting the intricate balance between the Earth`s absorption of heat from the sun and its capacity to reradiate excess heat back into space. Emissions of greenhouse gases from human activities may be an important mechanism that affects global climate. Thus, research is intensifying to improve our understanding of the role human activities might play in influencing atmospheric concentrations of greenhouse gases. On the basis of scientific findings of the past few decades, the US Government and the international community at large are now taking steps toward stabilizing greenhouse gas emissions. This report contributes to that process. Mandated by Congress this report provides estimates of US emissions of the principal greenhouse gases--carbon dioxide, methane, nitrous oxide, chlorofluorcarbons, carbon monoxide, nitrogen oxides, and nonmethane volatile organic compounds. Estimates are for the period 1985 to 1990. Preliminary estimates for 1991 have also been included, whenever data were available.

Not Available

1993-11-10T23:59:59.000Z

75

Reactive Power Compensator.  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation. 26 figs.

El-Sharkawi, M.A.; Venkata, S.S.; Chen, M.; Andexler, G.; Huang, T.

1992-07-28T23:59:59.000Z

76

Reactive power compensator  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation.

El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Woodinville, WA); Chen, Mingliang (Kirkland, WA); Andexler, George (Everett, WA); Huang, Tony (Seattle, WA)

1992-01-01T23:59:59.000Z

77

Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases in Soils  

E-Print Network [OSTI]

Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases Emissions--Carbon Dioxide Emissions--Sequestration and Storage--Biochar--Basalt--Organic Fertilizers, this investigation focuses on the range of potential of different soil additives to enhance sequestration and storage

Vallino, Joseph J.

78

THE FUTURE OF ENERGY GASES David G. Howell, Editor  

E-Print Network [OSTI]

totally independent of oil. Methane is found in association with coal; it is a byproduct of metabolic the term "energy gases" to distinguish those natural gases, primarily methane, that have utility for energy consequences associated with an expanded role of energy gases? Energy gases, particularly methane, are commonly

79

Measuring the Isotopic Composition of Solar Wind Noble Gases  

E-Print Network [OSTI]

noble gases. #12;Exploring the Solar Wind94 Light solar wind noble gases were directly measured by mass of the light gases are known to vary with energy, so none of these provided solar isotopic and elemental5 Measuring the Isotopic Composition of Solar Wind Noble Gases Alex Meshik, Charles Hohenberg, Olga

80

Oxyferryl Heme Reactivity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxyferryl Heme Reactivity Using both Radiation and Photochemical Oxyferryl Heme Reactivity Using both Radiation and Photochemical Techniques A. M. English, T. Fox, G. Tsaprailis, C. W. Fenwick, J. F. Wishart, J. T. Hazzard, and G. Tollin Adv. Chem. Ser. 254, Ch. 6, pp. 81-98 Abstract: Flash photolysis and pulse radiolysis were used to generate reductants in situ to study the electron-transfer (ET) reactivity of the FeIV=O heme centers in myoglobin and cytochrome c peroxidase. Reduction of a5RuIII groups covalently bound to surface histidines allowed intramolecular RuII --> FeIV=O ET rates to be measured. Protonation of the oxene ligand was found to be largely rate determining in myoglobin, consistent with the lack of proton donors in its heme pocket. The large distance (21-23 ├ů) between surface histidines and the heme in wild-type

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Reactivity of Acid Generators  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Acid Generators for Chemically Amplified Resists with Reactivity of Acid Generators for Chemically Amplified Resists with Low-Energy Electrons Atsuro Nakano, Takahiro Kozawa, Seiichi Tagawa, Tomasz Szreder, James F. Wishart, Toshiyuki Kai and Tsutomu Shimokawa Jpn. J. Appl. Phys., 45, L197-L200 (2006). [Find paper at the Japanese Journal of Applied Physics] Abstract: In chemically amplified resists for ionizing radiations such as electron beams and extreme ultraviolet (EUV), low-energy electrons play an important role in the pattern formation processes. The reactivity of acid generators with low-energy electrons was evaluated using solvated electrons in tetrahydrofuran, which were generated by a pulsed electron beam. The rate constants of acid generators with the solvated electrons ranged from 0.6 to 1.9 x 1011 M-1s-1

82

Processes to remove acid forming gases from exhaust gases  

DOE Patents [OSTI]

The present invention relates to a process for reducing the concentration of NO in a gas, which process comprises: (A) contacting a gas sample containing NO with a gaseous oxidizing agent to oxidize the NO to NO[sub 2]; (B) contacting the gas sample of step (A) comprising NO[sub 2] with an aqueous reagent of bisulfite/sulfite and a compound selected from urea, sulfamic acid, hydrazinium ion, hydrazoic acid, nitroaniline, sulfanilamide, sulfanilic acid, mercaptopropanoic acid, mercaptosuccinic acid, cysteine or combinations thereof at between about 0 and 100 C at a pH of between about 1 and 7 for between about 0.01 and 60 sec; and (C) optionally contacting the reaction product of step (A) with conventional chemical reagents to reduce the concentrations of the organic products of the reaction in step (B) to environmentally acceptable levels. Urea or sulfamic acid are preferred, especially sulfamic acid, and step (C) is not necessary or performed. 16 figs.

Chang, S.G.

1994-09-20T23:59:59.000Z

83

Purchase, Delivery, and Storage of Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Purchase, Delivery, and Storage of Gases Print Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab Chemical Inventory All gas bottles and cylinders at the ALS must be identified with bar code and logged into the Berkeley Lab Chemical Inventory by ALS staff. The inventory will be updated periodically; for more information contact Experiment Coordination. Gases are stored either in the racks between buildings 6 and 7; toxic and corrosive gases are stored in Building 6, room 6C across the walkway from beamline 10.0.

84

Reactive Power Compensating System.  

DOE Patents [OSTI]

The circuit was designed for the specific application of wind-driven induction generators. It has great potential for application in any situation where a varying reactive power load is present, such as with induction motors or generators, or for transmission network compensation.

Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

1985-01-04T23:59:59.000Z

85

Reactive power compensating system  

DOE Patents [OSTI]

The reactive power of an induction machine is compensated by providing fixed capacitors on each phase line for the minimum compensation required, sensing the current on one line at the time its voltage crosses zero to determine the actual compensation required for each phase, and selecting switched capacitors on each line to provide the balance of the compensation required.

Williams, Timothy J. (Redondo Beach, CA); El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Seattle, WA)

1987-01-01T23:59:59.000Z

86

Emissions Of Greenhouse Gases From Rice Agriculture  

SciTech Connect (OSTI)

This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min Î 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

M. Aslam K. Khalil

2009-07-16T23:59:59.000Z

87

Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases  

SciTech Connect (OSTI)

The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facilityĺs compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

Carlsbad Field Office

2007-11-19T23:59:59.000Z

88

Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases  

SciTech Connect (OSTI)

The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facilityĺs compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

Carlsbad Field Office

2007-11-13T23:59:59.000Z

89

Quantitative organic vapor-particle sampler  

DOE Patents [OSTI]

A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

1998-01-01T23:59:59.000Z

90

Chemical Properties of the Rare Gases  

Science Journals Connector (OSTI)

... of argon of about 100 atm. I have already shown by an independent method1 that radon, too, forms a hydrate which is much more stable than those of other rare ... , forms a hydrate which is much more stable than those of other rare gases. Radon is easily held by crystals of sulphur dioxide hydrates, when they are formed from ...

B. A. NIKITIN

1937-10-09T23:59:59.000Z

91

New instruments for measuring landfill gases  

Science Journals Connector (OSTI)

New instruments for measuring landfill gases ... The legislation mandates that landfill operators monitor more than 1200 active sites for specific pollution products. ... According to Varian, the instrumentation systems can be adapted easily to meet landfill testing requirements that might be enacted in states other than California. ...

RUDY BAUM

1988-02-01T23:59:59.000Z

92

Reactive Air Aluminization  

SciTech Connect (OSTI)

Ferritic stainless steels and other alloys are of great interest to SOFC developers for applications such as interconnects, cell frames, and balance of plant components. While these alloys offer significant advantages (e.g., low material and manufacturing cost, high thermal conductivity, and high temperature oxidation resistance), there are challenges which can hinder their utilization in SOFC systems; these challenges include Cr volatility and reactivity with glass seals. To overcome these challenges, protective coatings and surface treatments for the alloys are under development. In particular, aluminization of alloy surfaces offers the potential for mitigating both evaporation of Cr from the alloy surface and reaction of alloy constituents with glass seals. Commercial aluminization processes are available to SOFC developers, but they tend to be costly due to their use of exotic raw materials and/or processing conditions. As an alternative, PNNL has developed Reactive Air Aluminization (RAA), which offers a low-cost, simpler alternative to conventional aluminization methods.

Choi, Jung-Pyung; Chou, Y. S.; Stevenson, Jeffry W.

2011-10-28T23:59:59.000Z

93

Reactive Maintenance | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Reactive Maintenance Reactive Maintenance Reactive Maintenance October 7, 2013 - 9:40am Addthis Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities. Advantages Reactive maintenance advantages are a double-edged sword. Federal agencies following a purely reactive maintenance strategy can expect little expenditures for manpower or system upkeep until something breaks. However, systems do break. With new equipment, Federal agencies can expect minimal incidents of failure. However, older equipment often experiences higher failure incidents and costlier repairs. Other advantages of reactive maintenance are:

94

EIA-Voluntary Reporting of Greenhouse Gases Program - Why Report  

U.S. Energy Information Administration (EIA) Indexed Site

Why Report Why Report Voluntary Reporting of Greenhouse Gases Program Why Report What Is the Purpose of Form EIA-1605? Form EIA-1605 provides the means for the voluntary reporting of greenhouse gas emissions, reductions, and sequestration under Section 1605(b) of the Energy Policy Act of 1992. The purpose of the Voluntary Reporting Program is to encourage corporations, government agencies, non-profit organizations, households, and other private and public entities to submit annual reports of their greenhouse gas emissions, emission reductions, and sequestration activities. Form EIA-1605 provides a means for voluntary reporting that is complete, reliable, and consistent. How Will My Entity Benefit From Reporting? There are a number of ways for your entity to benefit from reporting, including:

95

Gas Cleaning Methods for Ambient Air and Compressed Gases  

Science Journals Connector (OSTI)

Cleaning air or compressed gases in cleanroom installations requires removal of particulate and/or ... The technology used for cleaning gases for the cleanroom is derived from processes long used in ... fossil fu...

Alvin Lieberman

1992-01-01T23:59:59.000Z

96

Perdido LF-Gase to Electricity | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Perdido LF-Gase to Electricity Perdido LF-Gase to Electricity This presentation was given at the July 17, 2012, Community Renewable Energy Deployment webinar on successful landfill...

97

BOC Lienhwa Industrial Gases BOCLH | Open Energy Information  

Open Energy Info (EERE)

BOC Lienhwa Industrial Gases BOCLH BOC Lienhwa Industrial Gases BOCLH Jump to: navigation, search Name BOC Lienhwa Industrial Gases (BOCLH) Place Taipei, Taiwan Sector Solar Product BOCLH is a joint venture between the Lien Hwa Industrial Corporation and the BOC Group in the United Kingdom and produces high-purity gases used in solar component production. References BOC Lienhwa Industrial Gases (BOCLH)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. BOC Lienhwa Industrial Gases (BOCLH) is a company located in Taipei, Taiwan . References ÔćĹ "BOC Lienhwa Industrial Gases (BOCLH)" Retrieved from "http://en.openei.org/w/index.php?title=BOC_Lienhwa_Industrial_Gases_BOCLH&oldid=342956

98

Method for enhancing microbial utilization rates of gases using perfluorocarbons  

DOE Patents [OSTI]

A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

Turick, Charles E. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

99

An investigation of the sub-grid variability of trace gases and aerosols for global climate modeling  

SciTech Connect (OSTI)

One fundamental property and limitation of grid based models is their inability to identify spatial details smaller than the grid cell size. While decades of work have gone into developing sub-grid treatments for clouds and land surface processes in climate models, the quantitative understanding of sub-grid processes and variability for aerosols and their precursors is much poorer. In this study, WRF-Chem is used to simulate the trace gases and aerosols over central Mexico during the 2006 MILAGRO field campaign, with multiple spatial resolutions and emission/terrain scenarios. Our analysis focuses on quantifying the sub-grid variability (SGV) of trace gases and aerosols within a typical global climate model grid cell, i.e. 75x75 km2. Our results suggest that a simulation with 3-km horizontal grid spacing adequately reproduces the overall transport and mixing of trace gases and aerosols downwind of Mexico City, while 75-km horizontal grid spacing is insufficient to represent local emission and terrain-induced flows along the mountain ridge, subsequently affecting the transport and mixing of plumes from nearby sources. Therefore, the coarse model grid cell average may not correctly represent aerosol properties measured over polluted areas. Probability density functions (PDFs) for trace gases and aerosols show that secondary trace gases and aerosols, such as O3, sulfate, ammonium, and nitrate, are more likely to have a relatively uniform probability distribution (i.e. smaller SGV) over a narrow range of concentration values. Mostly inert and long-lived trace gases and aerosols, such as CO and BC, are more likely to have broad and skewed distributions (i.e. larger SGV) over polluted regions. Over remote areas, all trace gases and aerosols are more uniformly distributed compared to polluted areas. Both CO and O3 SGV vertical profiles are nearly constant within the PBL during daytime, indicating that trace gases are very efficiently transported and mixed vertically by turbulence. But, simulated horizontal variability indicates that trace gases and aerosols are not well mixed horizontally in the PBL. During nighttime the SGV for trace gases is maximum at the surface, and quickly decreases with height. Unlike the trace gases, the SGV of BC and secondary aerosols reaches a maximum at the PBL top during the day. The SGV decreases with distance away from the polluted urban area, has a more rapid decrease for long-lived trace gases and aerosols than for secondary ones, and is greater during daytime than nighttime. The SGV of trace gases and aerosols is generally larger than for meteorological quantities. Emissions can account for up to 50% of the SGV over urban areas such as Mexico City during daytime for less-reactive trace gases and aerosols, such as CO and BC. The impact of emission spatial variability on SGV decays with altitude in the PBL and is insignificant in the free troposphere. The emission variability affects SGV more significantly during daytime (rather than nighttime) and over urban (rather than rural or remote) areas. The terrain, through its impact on meteorological fields such as wind and the PBL structure, affects dispersion and transport of trace gases and aerosols and their SGV.

Qian, Yun; Gustafson, William I.; Fast, Jerome D.

2010-07-29T23:59:59.000Z

100

Process for removal of ammonia and acid gases from contaminated waters  

DOE Patents [OSTI]

Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

King, C.J.; Mackenzie, P.D.

1982-09-03T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Process for removal of ammonia and acid gases from contaminated waters  

DOE Patents [OSTI]

Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

1985-01-01T23:59:59.000Z

102

Carbon dioxide Information Analysis Center and World Data Center: A for Atmospheric trace gases. Annual progress report, FY 1994  

SciTech Connect (OSTI)

This report summarizes the activities and accomplishments made by the Carbon Dioxide Information Analysis Center and World Data Center-A for Atmospheric Trace Gases during the fiscal year 1994. Topics discussed in this report include; organization and staff, user services, systems, communications, Collaborative efforts with China, networking, ocean data and activities of the World Data Center-A.

Burtis, M.D. [comp.] [Tennessee Univ., Knoxville, TN (United States). Energy, Environment and Resources Center; Cushman, R.M.; Boden, T.A.; Jones, S.B.; Nelson, T.R.; Stoss, F.W. [Oak Ridge National Lab., TN (United States)

1995-03-01T23:59:59.000Z

103

Federal Energy Management Program: Reactive Maintenance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactive Reactive Maintenance to someone by E-mail Share Federal Energy Management Program: Reactive Maintenance on Facebook Tweet about Federal Energy Management Program: Reactive Maintenance on Twitter Bookmark Federal Energy Management Program: Reactive Maintenance on Google Bookmark Federal Energy Management Program: Reactive Maintenance on Delicious Rank Federal Energy Management Program: Reactive Maintenance on Digg Find More places to share Federal Energy Management Program: Reactive Maintenance on AddThis.com... Sustainable Buildings & Campuses Operations & Maintenance Federal Requirements Program Management Commissioning Metering Computerized Maintenance Management Systems Maintenance Types Reactive Preventive Predictive Reliability-Centered Major Equipment Types

104

Efficieny handling effluent gases through chemical scrubbing  

SciTech Connect (OSTI)

This paper is presented as an information source for efficiencies of chemical scrubbing. In it, we will discuss the specific problems of scrubbing silane, disilane, diborane, phosphine, hydrogen selenide and arsine. We will explain the scrubber dynamics, gases and flow rates used along with liquid mediums. The equipment and procedures used for testing, as well as the determination of the results, will be discussed. We intend to give examples of possible reactions and documentation of our efficiencies. Installation and maintenance will be touched, as well as our experiments into accidental catastrophic releases. From all of this we will derive conclusions as to the best possible means of wet chemical scrubbing.

Herman, T.; Soden, S.

1988-07-15T23:59:59.000Z

105

Heat conduction in relativistic neutral gases revisited  

E-Print Network [OSTI]

The kinetic theory of dilute gases to first order in the gradients yields linear relations between forces and fluxes. The heat flux for the relativistic gas has been shown to be related not only to the temperature gradient but also to the density gradient in the representation where number density, temperature and hydrodynamic velocity are the independent state variables. In this work we show the calculation of the corresponding transport coefficients from the full Boltzmann equation and compare the magnitude of the relativistic correction.

A. L. Garcia-Perciante; A. R. Mendez

2010-09-30T23:59:59.000Z

106

Computational mapping reveals dramatic effect of Hoogsteen breathing on duplex DNA reactivity  

E-Print Network [OSTI]

Computational mapping reveals dramatic effect of Hoogsteen breathing on duplex DNA reactivity Formaldehyde has long been recognized as a haz- ardous environmental agent highly reactive with DNA. Recently-ray and nuclear magnetic resonance techniques for observing weakly specific interactions of small organic

Vajda, Sandor

107

Frustrated Organic Solids Display Unexpected Gas Sorption  

SciTech Connect (OSTI)

Calixarene based organic solid can hold guests such as toluene and other organic molecules we have discovered a new type of material which believe involves a frustration of the solvate lattice as it moves toward the thermodynamically stable desolvated state. The intermediated phase with partial solvent content unexpectedly sorbs gases such as carbon dioxide and highly explosive acetylene deep inside the crystal lattice.

Thallapally, Praveen K.; Dalgarno, Scott J.; Atwood, Jerry L.

2006-11-27T23:59:59.000Z

108

EIA-Voluntary Reporting of Greenhouse Gases Program - Greenhouse Gases and  

U.S. Energy Information Administration (EIA) Indexed Site

Greenhouse Gases and Global Warming Potentials (GWP) Greenhouse Gases and Global Warming Potentials (GWP) Voluntary Reporting of Greenhouse Gases Program Greenhouse Gases and Global Warming Potentials (GWP) (From Appendix E of the instructions to Form EIA-1605) GREENHOUSE GAS NAME GREENHOUSE GAS CODE FORMULA GWP TAR1 AR42 (1) Carbon Dioxide CO2 CO2 1 1 (2) Methane CH4 CH4 23 25 (3) Nitrous Oxide N2O N2O 296 298 (4) Hydroflourocarbons HFC-23 (trifluoromethane) 15 CHF3 12000 14800 HFC-32 (difluoromethane) 16 CH2F2 550 675 HFC-41 (monofluoromethane) 43 CH3F 97 -3 HFC-125 (pentafluoroethane) 17 CHF2CF3 3400 3500 HFC-134 (1,1,2,2-tetrafluoroethane) 44 CHF2CHF2 1100 -3 HFC-134a (1,1,1,2-tetrafluoroethane) 18 CH2FCF3 1300 1430 HFC-143 (1,1,2-trifluorethane) 45 CHF2CH2F 330 -3 HFC-143a (1,1,1-trifluoroethane) 46 CF3CH3 4300 4470 HFC-152 (1,2-difluorethane) 47 CH2FCH2F

109

Asia-wide emissions of greenhouse gases  

SciTech Connect (OSTI)

Emissions of principal greenhouse gases (GHGs) from Asia are increasing faster than those from any other continent. This is a result of rapid economic growth, as well as the fact that almost half of the world`s population lives in Asian countries. In this paper, the author provides estimates of emissions of the two principal greenhouse gases, carbon dioxide (CO{sub 2}) and methane (CH{sub 4}), from individual countries and areas. Recent literature has been reviewed for emission estimates for individual sources, such as carbon dioxide from cement manufacture, and methane from rice fields. There are very large uncertainties in many of these estimates, so several estimates are provided, where available. The largest anthropogenic source of CO{sub 2} emissions is the use of fossil fuels. Energy consumption data from 1992 have been used to calculate estimated emissions of CO{sub 2} from this source. In view of the ongoing negotiations to limit future greenhouse gas emissions, estimates of projected CO{sub 2} emissions from the developing countries of Asia are also provided. These are likely to be 3 times their 1986 levels by 2010, under business as usual scenarios. Even with the implementation of energy efficiency measures and fuel switching where feasible, the emissions of CO{sub 2} are likely to double within the same time period.

Siddiqi, T.A. [East-West Center, Honolulu, HI (United States). Program on Environment

1995-11-01T23:59:59.000Z

110

The reactive metabolite target protein database (TPDB) ľ a web-accessible resource  

E-Print Network [OSTI]

Background The toxic effects of many simple organic compounds stem from their biotransformation to chemically reactive metabolites which bind covalently to cellular proteins. To understand the mechanisms of cytotoxic ...

Hanzlik, Robert P.; Koen, Yakov M.; Theertham, Bhargav; Dong, Yinghua; Fang, Jianwen

2007-03-16T23:59:59.000Z

111

The greenhouse gases HFCs, PFCs Danish consumption and emissions, 2007  

E-Print Network [OSTI]

The greenhouse gases HFCs, PFCs and SF6 Danish consumption and emissions, 2007 Tomas Sander Poulsen AND EMISSION OF F-GASES 7 1.1.1 Consumption 7 1.1.2 Emission 7 1.1.3 Trends in total GWP contribution from F 21 4 EMISSION OF F-GASES 23 4.1.1 Emissions of HFCs from refrigerants 23 4.1.2 Emissions of HFCs from

112

Suspended two-dimensional electron and hole gases  

SciTech Connect (OSTI)

We report on the fabrication of fully suspended two-dimensional electron and hole gases in III-V heterostructures. Low temperature transport measurements verify that the properties of the suspended gases are only slightly degraded with respect to the non-suspended gases. Focused ion beam technology is used to pattern suspended nanostructures with minimum damage from the ion beam, due to the small width of the suspended membrane.

Kazazis, D.; Bourhis, E.; Gierak, J.; Gennser, U. [Laboratoire de Photonique et de Nanostructures, CNRS-LPN, Route de Nozay, 91460 Marcoussis (France); Bourgeois, O. [Institut NÚel, CNRS-UJF, BP 166, 38042 Grenoble Cedex 9 (France); Antoni, T. [Laboratoire de Photonique et de Nanostructures, CNRS-LPN, Route de Nozay, 91460 Marcoussis, France and Laboratoire Kastler Brossel, UniversitÚ Pierre et Marie Curie, 4 Place Jussieu, 75005 Paris (France)

2013-12-04T23:59:59.000Z

113

Metal-based reactive nanomaterials  

Science Journals Connector (OSTI)

Recent developments in materials processing and characterization resulted in the discovery of a new type of reactive materials containing nanoscaled metal components. The well-known high oxidation energies of metallic fuels can now be released very rapidly because of the very high reactive interface areas in such metal-based reactive nanomaterials. Consequently, these materials are currently being examined for an entire range of applications in energetic formulations inappropriate for conventional, micron-sized metal fuels having relatively low reaction rates. New application areas, such as reactive structural materials, are also being explored. Research remains active in manufacturing and characterization of metal-based reactive nanomaterials including elemental metal nanopowders and various nanocomposite material systems. Because of the nanometer scale of the individual particles, or phase domains, and because of the very high enthalpy of reaction between components of the nanocomposite materials, the final phase compositions, morphology, and thermodynamic properties of the reactive nanocomposite materials may be different from those of their micron-scaled counterparts. Ignition mechanisms in such materials can be governed by heterogeneous reactions that are insignificant for materials with less developed reactive interface areas. New combustion regimes are being observed that are affected by very short ignition delays combined with very high metal combustion temperatures. Current progress in this rapidly growing research area is reviewed and some potential directions for the future research are discussed.

Edward L. Dreizin

2009-01-01T23:59:59.000Z

114

EIA-Voluntary Reporting of Greenhouse Gases Program - Emission...  

Gasoline and Diesel Fuel Update (EIA)

AP-42 Volume 2 mobile sources Global Warming Potentials The Intergovernmental Panel on Climate Change (IPCC) revised GWPs for certain greenhouse gases in 2007 for the Fourth...

115

Energetic Materials for EGS Well Stimulation (solids, liquids, gases)  

Broader source: Energy.gov [DOE]

Energetic Materials for EGS Well Stimulation (solids, liquids, gases) presentation at the April 2013 peer review meeting held in Denver, Colorado.

116

Chemistry 685 (CHE 685) Advanced Organic Chemistry: Organic Reaction Mechanisms and Molecular Interactions  

E-Print Network [OSTI]

Chemistry 685 (CHE 685) Advanced Organic Chemistry: Organic Reaction Mechanisms and Molecular and physical chemistry Course description and rationale CHE685 is a graduate-level organic chemistry course. These two courses focus on physical organic chemistry, which deals with the structure and reactivity

Mather, Patrick T.

117

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

118

Chemically Reactive Working Fluids | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Chemically Reactive Working Fluids for the Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Chemically Reactive Working Fluids SunShot CSP...

119

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

120

Conservation of reactive electromagnetic energy in reactive time  

E-Print Network [OSTI]

The complex Poynting theorem (CPT) is extended to a canonical time-scale domain $(t,s)$. Time-harmonic phasors are replaced by the positive-frequency parts of general fields, which extend analytically to complex time $t+is$, with $s>0$ interpreted as a time resolution scale. The real part of the extended CPT gives conservation in $t$ of a time-averaged field energy, and its imaginary part gives conservation in $s$ of a time-averaged reactive energy. In both cases, the averaging windows are determined by a Cauchy kernel of width $\\Delta t\\sim \\pm s$. This completes the time-harmonic CPT, whose imaginary part is generally supposed to be vaguely `related to' reactive energy without giving a conservation law, or even an expression, for the latter. The interpretation of $s$ as reactive time, tracking the leads and lags associated with stored capacitative and inductive energy, gives a simple explanation of the volt-ampere reactive (var) unit measuring reactive power: a var is simply one Joule per reactive second. T...

Kaiser, Gerald

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

EIA-Voluntary Reporting of Greenhouse Gases Program - About the 1605(b)  

U.S. Energy Information Administration (EIA) Indexed Site

About the 1605(b) Program About the 1605(b) Program Voluntary Reporting of Greenhouse Gases Program About the 1605(b) Program History Established by Section 1605(b) of the Energy Policy Act of 1992, the Voluntary Reporting of Greenhouse Gases Program (also known as the 1605(b) Program) encourages corporations, government agencies, non-profit organizations, households, and other private and public entities to submit annual reports of their greenhouse gas emissions, emission reductions, and sequestration activities. The Program provides a means for voluntary reporting that is complete, reliable, and consistent. The Voluntary Reporting Program began operations in 1994 under the auspices of the Energy Information Administration, the statistical branch of the Department of Energy. Under the original guidelines, the Program released annual reports and a public database for each reporting cycle from the 1994 through the 2005 data years.

122

Biological production of acetic acid from waste gases with Clostridium ljungdahlii  

DOE Patents [OSTI]

A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

Gaddy, J.L.

1998-09-15T23:59:59.000Z

123

FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS  

Office of Scientific and Technical Information (OSTI)

Bulletin 627 Bulletin 627 BUREAU o b MINES FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS By Michael G. Zabetakis DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement,

124

Refinery Yield of Liquefied Refinery Gases  

U.S. Energy Information Administration (EIA) Indexed Site

Refinery Yield Refinery Yield (Percent) Product: Liquefied Refinery Gases Finished Motor Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Residual Fuel Oil Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Still Gas Miscellaneous Products Processing Gain(-) or Loss(+) Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 5.3 5.4 5.2 5.2 5.1 3.9 1993-2013 PADD 1 4.4 5.1 4.9 4.9 4.6 2.1 1993-2013 East Coast 4.4 5.3 5.1 5.1 4.9 2.2 1993-2013

125

Shortcuts to adiabaticity for trapped ultracold gases  

E-Print Network [OSTI]

We study, experimentally and theoretically, the controlled transfer of harmonically trapped ultracold gases between different quantum states. In particular we experimentally demonstrate a fast decompression and displacement of both a non-interacting gas and an interacting Bose-Einstein condensate which are initially at equilibrium. The decompression parameters are engineered such that the final state is identical to that obtained after a perfectly adiabatic transformation despite the fact that the fast decompression is performed in the strongly non-adiabatic regime. During the transfer the atomic sample goes through strongly out-of-equilibrium states while the external confinement is modified until the system reaches the desired stationary state. The scheme is theoretically based on the invariants of motion and scaling equations techniques and can be generalized to decompression trajectories including an arbitrary deformation of the trap. It is also directly applicable to arbitrary initial non-equilibrium sta...

Schaff, Jean-Franšois; Labeyrie, Guillaume; Vignolo, Patrizia

2011-01-01T23:59:59.000Z

126

Shortcuts to adiabaticity for trapped ultracold gases  

E-Print Network [OSTI]

We study, experimentally and theoretically, the controlled transfer of harmonically trapped ultracold gases between different quantum states. In particular we experimentally demonstrate a fast decompression and displacement of both a non-interacting gas and an interacting Bose-Einstein condensate which are initially at equilibrium. The decompression parameters are engineered such that the final state is identical to that obtained after a perfectly adiabatic transformation despite the fact that the fast decompression is performed in the strongly non-adiabatic regime. During the transfer the atomic sample goes through strongly out-of-equilibrium states while the external confinement is modified until the system reaches the desired stationary state. The scheme is theoretically based on the invariants of motion and scaling equations techniques and can be generalized to decompression trajectories including an arbitrary deformation of the trap. It is also directly applicable to arbitrary initial non-equilibrium states.

Jean-Franšois Schaff; Pablo Capuzzi; Guillaume Labeyrie; Patrizia Vignolo

2011-05-11T23:59:59.000Z

127

Bogoliubov spectrum of interacting Bose gases  

E-Print Network [OSTI]

We study the large-N limit of a system of N bosons interacting with a potential of intensity 1/N. When the ground state energy is to the first order given by Hartree's theory, we study the next order, predicted by Bogoliubov's theory. We show the convergence of the lower eigenvalues and eigenfunctions towards that of the Bogoliubov Hamiltonian (up to a convenient unitary transform). We also prove the convergence of the free energy when the system is sufficiently trapped. Our results are valid in an abstract setting, our main assumptions being that the Hartree ground state is unique and non-degenerate, and that there is complete Bose-Einstein condensation on this state. Using our method we then treat two applications: atoms with ''bosonic'' electrons on one hand, and trapped 2D and 3D Coulomb gases on the other hand.

Mathieu Lewin; Phan ThÓnh Nam; Sylvia Serfaty; Jan Philip Solovej

2014-03-11T23:59:59.000Z

128

Fuel Temperature Coefficient of Reactivity  

SciTech Connect (OSTI)

A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

Loewe, W.E.

2001-07-31T23:59:59.000Z

129

Carbonaceous material for production of hydrogen from low heating value fuel gases  

DOE Patents [OSTI]

A process for the catalytic production of hydrogen, from a wide variety of low heating value fuel gases containing carbon monoxide, comprises circulating a carbonaceous material between two reactors--a carbon deposition reactor and a steaming reactor. In the carbon deposition reactor, carbon monoxide is removed from a fuel gas and is deposited on the carbonaceous material as an active carbon. In the steaming reactor, the reactive carbon reacts with steam to give hydrogen and carbon dioxide. The carbonaceous material contains a metal component comprising from about 75% to about 95% cobalt, from about 5% to about 15% iron, and up to about 10% chromium, and is effective in suppressing the production of methane in the steaming reactor.

Koutsoukos, Elias P. (Los Angeles, CA)

1989-01-01T23:59:59.000Z

130

Method of converting environmentally pollutant waste gases to methanol  

SciTech Connect (OSTI)

A continuous flow method is described of converting environmentally pollutant by-product gases emitted during the manufacture of silicon carbide to methanol comprising: (a) operating a plurality of batch furnaces of a silicon carbide manufacturing plant thereby producing silicon carbide and emitting by-product gases during the operation of the furnaces; (b) staggering the operation of the batch furnaces to achieve a continuous emission of the by-product gases; (c) continuously flowing the by-product gases as emitted from the batch furnaces directly to a methanol manufacturing plant; (d) cleansing the by-product gases of particulate matter, including removing the element sulfur from the by-product gases, as they are flowed to the methanol manufacturing plant, sufficiently for use of the by-product gases in producing methanol; and (e) immediately producing methanol from the by-product gases at the methanol manufacturing plant whereby the producing of silicon carbide is joined with the producing of methanol as a unified process.

Pfingstl, H.; Martyniuk, W.; Hennepin, A. Ill; McNally, T.; Myers, R.; Eberle, L.

1993-08-03T23:59:59.000Z

131

OBTAINING LAWS OF THERMODYNAMICS FOR IDEAL GASES USING ELASTIC COLLISIONS  

E-Print Network [OSTI]

OBTAINING LAWS OF THERMODYNAMICS FOR IDEAL GASES USING ELASTIC COLLISIONS STEPHEN MONTGOMERY law of expansion of ideal gases. 1. The Second Law of Thermodynamics A thermally isolated container-SMITH AND HANNAH MORGAN Abstract. The purpose of this note is to see to what extent ideal gas laws can be obtained

Montgomery-Smith, Stephen

132

Continuous cryopump with a method for removal of solidified gases  

DOE Patents [OSTI]

An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

Carlson, L.W.; Herman, H.

1988-05-05T23:59:59.000Z

133

EIA - Greenhouse Gas Emissions - High-GWP gases  

Gasoline and Diesel Fuel Update (EIA)

5. High-GWP gases 5. High-GWP gases 5.1. Total emissions Greenhouse gases with high global warming potential (high-GWP gases) are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which together represented 3 percent of U.S. greenhouse gas emissions in 2009. Emissions estimates for the high-GWP gases are provided to EIA by the EPA's Office of Air and Radiation. The estimates for emissions of HFCs not related to industrial processes or electric transmission are derived from the EPA Vintaging Model. Emissions from manufacturing and utilities are derived by the EPA from a mix of public and proprietary data, including from the EPA's voluntary emission reduction partnership programs. For this year's EIA inventory, 2008 values for HFC-23 from HCFC-22

134

Measuring non-condensable gases in steam  

SciTech Connect (OSTI)

In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1á%) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M{sup TM} Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

Doornmalen, J. P. C. M. van; Kopinga, K., E-mail: k.kopinga@tue.nl [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

2013-11-15T23:59:59.000Z

135

1 - Solubility of Atmospheric Gases in Freshwater  

Science Journals Connector (OSTI)

This chapter presents tabular information on the standard air saturation concentration (moist air at 1áatm) for oxygen, nitrogen, argon, and carbon dioxide gas in terms of ?mol/kg, mg/L, and mL/L; and in terms of Bunsen coefficients L real gas/(Láatm); mg real gas/(LámmHg); and mg real gas/(LákPa) for 0ľ40░C and freshwater conditions. Because the mole fraction of carbon dioxide in the atmosphere is changing, solubility information is provided for 2010 (390á?atm) and for 2030 (440á?atm) based on projected atmospheric values. Tabular information is also provided to allow computation of standard air saturation concentrations of carbon dioxide gas directly as a function of atmospheric mole fraction. Conversion factors are presented to convert these concentrations to other commonly used units. Equations and tabular information are provided to compute air saturation concentration for moist air at local barometric pressure for the four atmospheric gases. Because of the importance of dissolved oxygen in biological processes, the air solubility concentration is also presented as a function of elevation for both metric and English elevations. Equations and tabular information are provided to allow conversion of concentrations in mg/L to partial pressures in mmHg. Sample problems are included for representative examples. Keywords gas solubility, freshwater, oxygen, nitrogen, argon, carbon dioxide, standard air solubility, air solubility, Bunsen coefficients, partial pressures

John Colt

2012-01-01T23:59:59.000Z

136

Energy Efficiency and Greenhouse Gases | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Energy Efficiency Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program as defined in Executive Order (EO) 13423, Strengthening Federal Environmental, Energy, and Transportation Management, and (EO) 13514, Federal Leadership in Environmental, Energy, and Economic Performance, and DOE Order 436.1, Departmental Sustainability, and approved by LM. The team incorporates requirements for energy efficiency and reductions in greenhouse gases, and it advocates conserving environmental resources and improving operational capabilities and mission sustainability. Scope The team evaluates how to maintain and operate its buildings and facilities in a resource-efficient, sustainable, and economically viable manner. The

137

Unified Theory of Lattice Boltzmann Models for Nonideal Gases  

SciTech Connect (OSTI)

A nonideal gas lattice Boltzmann model is directly derived, in an {ital a priori} fashion, from the Enskog equation for dense gases. The model is rigorously obtained by a systematic procedure to discretize the Enskog equation (in the presence of an external force) in both phase space and time. The lattice Boltzmann model derived here is thermodynamically consistent and is free of the defects which exist in previous lattice Boltzmann models for nonideal gases. The existing lattice Boltzmann models for nonideal gases are analyzed and compared with the model derived here. {copyright} {ital 1998} {ital The American Physical Society}

Luo, L. [ICASE, MS 403, NASA Langley Research Center, 6 North Dryden Street, Building 1298, Hampton, Virginia 23681-0001 (United States)] [ICASE, MS 403, NASA Langley Research Center, 6 North Dryden Street, Building 1298, Hampton, Virginia 23681-0001 (United States)

1998-08-01T23:59:59.000Z

138

Global warming description using Daisyworld model with greenhouse gases  

Science Journals Connector (OSTI)

Abstract Daisyworld is an archetypal model of the earth that is able to describe the global regulation that can emerge from the interaction between life and environment. This article proposes a model based on the original Daisyworld considering greenhouse gases emission and absorption, allowing the description of the global warming phenomenon. Global and local analyses are discussed evaluating the influence of greenhouse gases in the planet dynamics. Numerical simulations are carried out showing the general qualitative behavior of the Daisyworld for different scenarios that includes solar luminosity variations and greenhouse gases effect. Nonlinear dynamics perspective is of concern discussing a way that helps the comprehension of the global warming phenomenon.

Susana L.D. Paiva; Marcelo A. Savi; Flavio M. Viola; Albino J.K. Leiroz

2014-01-01T23:59:59.000Z

139

Joint Energy and Reactive Power Market Considering Coupled Active and Reactive Reserve Market Ensuring System Security  

Science Journals Connector (OSTI)

Reactive power market is usually held as independent from energy and reserved active power markets; however, active and reactive power are ... synchronous generator capacity curve. Therefore, reactive power market

Hamed Ahmadi; Asghar Akbari Foroud

2014-06-01T23:59:59.000Z

140

Analysis of air pollution and greenhouse gases  

SciTech Connect (OSTI)

The current objective of the project Analysis of Air Pollution and Greenhouse Gases'' is to develop a study of emissions and emission sources that could easily be linked to models of economic activity. Initial studies were conducted to evaluate data currently available linking activity rates and emissions estimates. The emissions inventory developed for the National Acid Precipitation Assessment Program (NAPAP) presents one of the most comprehensive data sets, and was chosen for our initial studies, which are described in this report. Over 99% of the SO{sub 2} emissions, 98% of the NO{sub x} emission and 57% of the VOC emissions from area sources are related to fuel combustion. The majority of emission from these sources are generated by the transportation sector. Activity rates for area sources are not archived with the NAPAP inventory; alternative derivations of these data will be part of the future activities of this project. The availability and completeness of the fuel heat content data in the NAPAP inventory were also studied. Approximately 10% of the SO{sub 2} emissions, 13% of the NO{sub x} emissions and 46% of the VOC emissions are generated by sources with unavailable data for fuel heat content. Initial estimates of pollutant emission rate per unit fuel heat content. Initial estimates of pollutant emission rate per unit fuel heat content were generated. Future studies for this project include the derivation of activity rates for area sources, improved explanations for the default fuel parameters defined in the NAPAP inventory and the development of links to data bases of economic activity.

Benkovitz, C.M.

1992-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Triclosan Reactivity in Chloraminated Waters  

Science Journals Connector (OSTI)

Triclosan Reactivity in Chloraminated Waters ... Triclosan, widely employed as an antimicrobial additive in many household personal care products, has recently been detected in wastewater treatment plant effluents and in source waters used for drinking water supplies. ... Chloramines used either as alternative disinfectants in drinking water treatment or formed during chlorination of nonnitrified wastewater effluents have the potential to react with triclosan. ...

Aimee E. Greyshock; Peter J. Vikesland

2006-03-16T23:59:59.000Z

142

Semi-Continuous Detection of Mercury in Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Continuous Detection of Mercury in Gases Continuous Detection of Mercury in Gases Opportunity Research is currently active on the patented technology "Semi-Continuous Detection of Mercury in Gases." The technology, which is a spinoff of the National Energy Technology Laboratory's (NETL) GP-254 Process (U.S. patent 6,576,092), is available for licensing and/or further collaborative research from the U.S. Department of Energy's NETL. Overview This invention discloses a method for the quantitative detection of heavy metals, especially mercury, in effluent gas streams. The method employs photo-deposition and an array of surface acoustic wave sensors where each sensor monitors a specific metal. The U.S. Environmental Protection Agency issued a national regulation for mercury removal from coal-derived flue and fuel gases in December 2011,

143

Method of producing pyrolysis gases from carbon-containing materials  

DOE Patents [OSTI]

A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

1989-01-01T23:59:59.000Z

144

BIOSIGNATURE GASES IN H?-DOMINATED ATMOSPHERES ON ROCKY EXOPLANETS  

E-Print Network [OSTI]

Super-Earth exoplanets are being discovered with increasing frequency and some will be able to retain stable H2-dominated atmospheres. We study biosignature gases on exoplanets with thin H2 atmospheres and habitable surface ...

Seager, Sara

145

Spontaneous detonation of a mixture of two odd electron gases  

Science Journals Connector (OSTI)

Spontaneous detonation of a mixture of two odd electron gases ... Instructions for safe detonation of ClO2 and NO (the fastest known reaction between two stable molecules at room temperature). ...

Thomas S. Briggs

1991-01-01T23:59:59.000Z

146

Suitability of Non-Energy Greenhouse Gases for Emissions Trading  

Science Journals Connector (OSTI)

This paper assesses the suitability of different sources of non-energy greenhouse gases for emissions trading. Different forms of emissions trading are defined and criteria for determining whether a source is sui...

Erik Haites; Angelo Proestos

2000-01-01T23:59:59.000Z

147

Studying coherence in ultra-cold atomic gases  

E-Print Network [OSTI]

This thesis will discuss the study of coherence properties of ultra-cold atomic gases. The atomic systems investigated include a thermal cloud of atoms, a Bose-Einstein condensate and a fermion pair condensate. In each ...

Miller, Daniel E. (Daniel Edward)

2007-01-01T23:59:59.000Z

148

The Speciation and reactivity of wastewater-derived organic nitrogen  

E-Print Network [OSTI]

Aquatic toxicity of triclosan. Environ. Toxicol. Chem. , 21(wastewater origin, such as triclosan (Orvos et al. 2002) or

Sedlak, David L; Pehlivanoglu, Elif

2004-01-01T23:59:59.000Z

149

Reactive Distillation for Esterification of Bio-based Organic...  

Office of Scientific and Technical Information (OSTI)

bench-scale column and 1.0 liter for the pilot-scale column. Each column has two feed pumps to dispense feed solutions to the column at a controlled rate. The columns have...

150

Reactive Distillation for Esterification of Bio-based Organic...  

Office of Scientific and Technical Information (OSTI)

introduction of feed, and sample withdrawal. The columns are wrapped with electric heating tapes that are controlled by surface thermocouples and Omega controllers to...

151

Definition: Reactive Power | Open Energy Information  

Open Energy Info (EERE)

Reactive Power Reactive Power Jump to: navigation, search Dictionary.png Reactive Power The portion of electricity that establishes and sustains the electric and magnetic fields of alternating-current equipment. Reactive power must be supplied to most types of magnetic equipment, such as motors and transformers. It also must supply the reactive losses on transmission facilities. Reactive power is provided by generators, synchronous condensers, or electrostatic equipment such as capacitors and directly influences electric system voltage. It is usually expressed in kilovars (kvar) or megavars (Mvar).[1] View on Wikipedia Wikipedia Definition In electric power transmission and distribution, volt-ampere reactive (var) is a unit used to measure reactive power in an AC electric

152

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

153

Reactive Power Support Services in Electricity Markets  

E-Print Network [OSTI]

Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Final Project Report Power Systems Engineering Research Center A National Science Foundation Industry Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Project

154

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network [OSTI]

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

155

Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases  

DOE Patents [OSTI]

An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

Gross, Kenneth C. (Bolingbrook, IL); Markun, Francis (Joliet, IL); Zawadzki, Mary T. (South Bend, IN)

1998-01-01T23:59:59.000Z

156

Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases  

DOE Patents [OSTI]

An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

Gross, K.C.; Markun, F.; Zawadzki, M.T.

1998-04-28T23:59:59.000Z

157

Reactive Ion Benjamin A. Small  

E-Print Network [OSTI]

(torr) plasma etching reactive ion etching ion milling m cm 100┬Ám ┬Ám #12;5 Mechanics ~40 mTorrE380 kHz, 13.56 MHz ~30 sccm #12;6 Chemistry X X X X F- F- F-F- X F-F- F- F- F- R++ R++ R++ #12;7 Chemistry before opening ┬Ě Silanes are explosive in the atmosphere #12;13 Bibliography Campbell, Stephen A

Garmestani, Hamid

158

Reactive composite compositions and mat barriers  

DOE Patents [OSTI]

A hazardous material storage area has a reactive multi-layer composite mat which lines an opening into which a reactive backfill and hazardous material are placed. A water-inhibiting cap may cover the hazardous material storage area. The reactive multi-layer composite mat has a backing onto which is placed an active layer which will neutralize or stabilize hazardous waste and a fronting layer so that the active layer is between the fronting and backing layers. The reactive backfill has a reactive agent which can stabilize or neutralize hazardous material and inhibit the movement of the hazardous material through the hazardous material storage area.

Langton, Christine A. (Aiken, SC); Narasimhan, Rajendran (Evans, GA); Karraker, David G. (Aiken, SC)

2001-01-01T23:59:59.000Z

159

MST: Organizations: Organic Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adhesive Bonding Adhesive Bonding Composites Encapsulation Materials Characterization Mechanical Testing Molding, Thermoforming, & Compounding Organizations Organic Materials Composite-to-metal adhesive bond Experimental/analytical study of composit-to-metal adhesive bond. The Organic Materials department in the Advanced Manufacturing and Processing Laboratory provides innovative prototype fabrication, full service small lot production, materials technology, processing expertise, and a broad range of organic material characterization and mechanical testing techniques. We encapsulate, we join and bond, we foam, we analyze and image, we build composite structures. We strive to make you, our customers, successful! We partner with you to find the right combination of materials, processing, and fixturing that will result in the highest value

160

Organic Vegetable Organic Vegetable  

E-Print Network [OSTI]

marketed separately from conventionally grown produce in order to be profitably sold. Because of the amount of organic material include compost, Purdue University ┬Ě Cooperative Extension Service ┬Ě Knowledge to Go

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Permeable Reactive Barriers | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barrier Field Projects Durango, Colorado DOE installed a PRB in October 1995 to treat ground water from a uranium mill tailings disposal site at Durango, Colorado Read more Ca├▒on City, Colorado ESL personnel conduct tests and help evaluate performance at other PRB sites, such as Cotter Corporation's Ca├▒on City site in Colorado. Read more Monticello, Utah Installation of a PRB hydraulically downgradient of the Monticello, Utah, millsite was completed June 30, 1999, as an Interim Remedial Action. Read more A permeable reactive barrier (PRB) is a zone of reactive material placed underground to intercept and react with a contaminant plume in ground water. Typically, PRBs are emplaced by replacing soils with reactive

162

Reactive capability limits of wind farms  

Science Journals Connector (OSTI)

Wind Energy Conversion Systems (WECS) technology can be classified into two main types: fixed speed and variable speed. Fixed speed WECS use an induction generator connected directly to the grid while variable speed WECS use a power converter to connect the generator to the grid. Fixed speed WECS require shunt capacitors for reactive power compensation, while variable speed WECS have reactive power capability. Under the Spanish grid code, wind farms have to operate in a range of power factor values. This paper determines the reactive power capability of wind farms equipped with both fixed and variable speed WECS. The reactive power capability can be represented as a reactive capability curve. In this paper, the reactive capability curve is used to calculate the additional reactive power compensation needed to meet the requirements of the Spanish grid code.

Alberto Rios Villacorta; Santiago Arnaltes Gomez; Jose Luis Rodriguez-Amenedo

2005-01-01T23:59:59.000Z

163

Voluntary Reporting of Greenhouse Gases Program - Electricity Factors  

U.S. Energy Information Administration (EIA) Indexed Site

Voluntary Reporting Program > Coefficients Voluntary Reporting Program > Coefficients Voluntary Reporting of Greenhouse Gases Program (Voluntary Reporting of Greenhouse Gases Program Fuel Carbon Dioxide Emission Coefficients) Voluntary Reporting of Greenhouse Gases Program Fuel Emission Coefficients Table 1: Carbon Dioxide Emission Factors for Stationary Combustion Table 2: Carbon Dioxide Emission Factors for Transportation Fuels Table 3: Generic Methane and Nitrous Oxide Emission Factors for Stationary Fuel Combustion Table 4: Specific Methane and Nitrous Oxide Emission Factors for Biogenic Fuel Sources Table 5: Methane and Nitrous Oxide Emissions Factors for Highway Vehicles Table 6: Methane and Nitrous Oxide Emission Factors for Alternative Fuel Vehicles Table 7: Methane and Nitrous Oxide Emission Factors for Non-Highway Mobile Combustion

164

Lattice vibrations of pure and doped GaSe  

SciTech Connect (OSTI)

The Bridgman method is used to grow especially undoped and doped single crystals of GaSe. Composition and impurity content of the grown crystals were determined using X-ray fluorescence (XRF) method. X-ray diffraction, Raman scattering, photoluminescence (PL), and IR transmission measurements were performed at room temperature. The long wavelength lattice vibrations of four modifications of GaSe were described in the framework of modified one-layer linear-chain model which also takes into consideration the interaction of the selenium (Se) atom with the second nearest neighbor gallium (Ga) atom in the same layer. The existence of an eight-layer modification of GaSe is suggested and the vibrational frequencies of this modification are explained in the framework of a lattice dynamical model considered in the present work. Frequencies and the type of vibrations (gap, local, or resonance) for the impurity atoms were calculated and compared with the experimental results.

Allakhverdiev, K. [Materials Institute, Marmara Research Center, TUBITAK, Gebze/Kocaeli 41470 (Turkey) and Institute of Physics, Azerbaijan National Academy of Sciences, Baku AZ1143 (Azerbaijan)]. E-mail: kerim.allahverdi@mam.gov.tr; Baykara, T. [Materials Institute, Marmara Research Center, TUBITAK, Gebze/Kocaeli 41470 (Turkey); Ellialtioglu, S. [Department of Physics, Middle East Technical University, Ankara 06531 (Turkey); Hashimzade, F. [Institute of Physics, Azerbaijan National Academy of Sciences, Baku AZ1143 (Azerbaijan); Huseinova, D. [Institute of Physics, Azerbaijan National Academy of Sciences, Baku AZ1143 (Azerbaijan); Kawamura, K. [Institute of Materials Science, University of Tsukuba 305-8573 (Japan); Kaya, A.A. [Materials Institute, Marmara Research Center, TUBITAK, Gebze/Kocaeli 41470 (Turkey); Kulibekov, A.M. [Department of Physics, Mugla University, Mugla 48000 (Turkey); Onari, S. [Institute of Materials Science, University of Tsukuba 305-8573 (Japan)

2006-04-13T23:59:59.000Z

165

Emissions of greenhouse gases in the United States 1997  

SciTech Connect (OSTI)

This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

NONE

1998-10-01T23:59:59.000Z

166

Other States Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic  

U.S. Energy Information Administration (EIA) Indexed Site

Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Other States Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 513 491 515 539 557 534 541 579 574 585 558 573 1998 578 536 591 581 517 456 486 486 471 477 457 468 1999 466 438 489 495 499 510 547 557 544 555 541 579 2000 587 539 605 587 615 570 653 629 591 627 609 611 2001 658 591 677 690 718 694 692 679 686 697 688 700 2002 639 591 587 621 622 605 654 639 649 650 623 638 2003 689 624 649 676 702 691 733 732 704 734 719 748 2004 741 697 727 692 692 688 718 729 706 723 711 718

167

Assess Potential Agency Size Changes to Reduce Greenhouse Gases Using  

Broader source: Energy.gov (indexed) [DOE]

Assess Potential Agency Size Changes to Reduce Greenhouse Gases Assess Potential Agency Size Changes to Reduce Greenhouse Gases Using Renewable Energy in Buildings Assess Potential Agency Size Changes to Reduce Greenhouse Gases Using Renewable Energy in Buildings October 7, 2013 - 11:15am Addthis To support planning for using renewable energy to reduce greenhouse gas (GHG) emissions at the Federal agency or program-level, it is important to consider what changes to the agencies building or land-holding portfolio may have on opportunities for renewable energy. Changes to consider include: Addition of new buildings or sites to the agencies portfolio Major renovations to existing buildings Office moves into or out of agency-owned or leased space. As is the case with planning energy efficiency measures, planning for renewable energy in new construction can be more cost-effective than

168

Raman/FTIR spectroscopy of oil shale retort gases  

SciTech Connect (OSTI)

A Raman facility was assembled in order to aid in the evaluation of the feasibility of using Raman or FTIR spectroscopy for analyzing gas mixtures of interest in oil shale. Applications considered in oil shale research included both retort monitoring and laboratory kinetic studies. Both techniques gave limits of detection between 10 and 1000 ppM for ten representative pertinent gases. Both techniques are inferior as a general analytical technique for oil shale gas analysis in comparison with mass spectroscopy, which had detection limits between 1 and 50 ppM for the same gases. The conclusion of the feasibility study was to recommend that mass spectroscopic techniques be used for analyzing gases of interest to oil shale.

Richardson, J H; Monaco, S B; Sanborn, R H; Hirschfeld, T B; Taylor, J R

1982-08-01T23:59:59.000Z

169

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents [OSTI]

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

170

Hazardous Gases VASILIS M. FTHENAKIS Department of Applied Science  

Office of Scientific and Technical Information (OSTI)

Mitigation Options for Mitigation Options for Accidental Releases of Hazardous Gases VASILIS M. FTHENAKIS Department of Applied Science Brookhaven National Laboratory Upton, N Y 11973 ABSTRACT The objective of this paper is to review and compare technologies available for mitigation of unconfined releases of toxic and flammable gases. These technologies indude: secondary confinement, de- inventory, vapor barriers, foam spraying, and water sprays/monitors. Guidelines for the design and/or operation of effective post-release mitigation systems and case studies involving actual industrial mitigation systems are also presented. 1. ACCIDENT PREVENTION & MITIGATION OPTIONS Accident prevention and mitigation in the process industries is based on the military concept of defense in

171

Dissipative dynamics of a Josephson junction in the Bose gases  

SciTech Connect (OSTI)

The dissipative dynamics of a Josephson junction in Bose gases is considered within the framework of the model of a tunneling Hamiltonian. The effective action that describes the dynamics of the phase difference across the junction is derived using the functional integration method. The dynamic equation obtained for the phase difference across the junction is analyzed for the finite temperatures in the low-frequency limit involving the radiation terms. The asymmetric case of the Bose gases with the different order parameters is calculated as well.

Barankov, R.A. [Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Burmistrov, S.N. [RRC 'Kurchatov Institute', Kurchatov Sq.1, 123182 Moscow (Russian Federation)

2003-01-01T23:59:59.000Z

172

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

173

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

174

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents [OSTI]

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

175

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2-  

Open Energy Info (EERE)

Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Project Type / Topic 1 Laboratory Call for Submission of Applications for Research, Development and Analysis of Geothermal Technologies Project Type / Topic 2 Tracers and Tracer Interpretation Project Description The concepts and theory behind the use of heat-sensitive tracers to study the thermal evolution of geothermal reservoirs was developed in the late 1980's under the Hot Dry Rock Project. Those studies described-conceptually and mathematically-the application of reactive tracers to tracking thermal fronts and to reservoir sizing. Later mathematical treatments focused on application of a single reactive tracer test to recover the temperature profile of a single streamtube. Previous tracer work has mainly focused on identifying conservative tracers. In these studies, chemicals that degraded at reservoir temperatures were discarded. Benzoic acids and dicarboxylic acids, which were found by Adams to degrade, may be useful as reactive tracers. Organic esters and amide tracers that undergo hydrolysis have been investigated and their use as reactive tracers appears feasible over a temperature range of 100┬║C to 275┬║C. However their reaction rates are pH dependent and sorption reactions have not been evaluated. While reactive tracer parameters have been measured in the lab, reactive tracers have not been extensively tested in the field. Thus, while reactive tracers appear to be a promising means of monitoring the thermal evolution of a geothermal reservoir, the concept has yet to be tested at the scale necessary for successful implementation, and tools for analyzing results of such tracer tests under the non-ideal conditions of an actual geothermal system have yet to be developed.

176

Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes  

E-Print Network [OSTI]

nitric ox- ide (NO), nitrogen dioxide (NO 2 ), ammonia (NHNitric Oxide (NO) Nitrogen Dioxide (NO 2 ) Nitrogen Oxides (Nitric Oxide (NO) Nitrogen Dioxide (NO 2 ) Nitrogen Oxides (

2013-01-01T23:59:59.000Z

177

Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same  

DOE Patents [OSTI]

An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

Fritz, Gregory M; Knepper, Robert Allen; Weihs, Timothy P; Gash, Alexander E; Sze, John S

2013-04-30T23:59:59.000Z

178

Use of low temperature blowers for recirculation of hot gases  

DOE Patents [OSTI]

An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

Maru, H.C.; Forooque, M.

1982-08-19T23:59:59.000Z

179

AER1301: KINETIC THEORY OF GASES Assignment #2  

E-Print Network [OSTI]

AER1301: KINETIC THEORY OF GASES Assignment #2 1. Using the formalism of the text book is as follows. Assume that the particle number density is a slowly varying function of the z coordinate #27; ├? is a constant. 3. Show that if the potential function, U(r), varies as 1=r 4

Groth, Clinton P. T.

180

AER1301: KINETIC THEORY OF GASES Assignment #2  

E-Print Network [OSTI]

AER1301: KINETIC THEORY OF GASES Assignment #2 1. Using the formalism of the text book the particle number density and temperature are both slowly varying functions of the z coordinate of the previous problem is as follows. Assume that the particle number density is a slowly varying function

Groth, Clinton P. T.

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

OPTIONS FOR ABATING GREENHOUSE GASES FROM EXHAUST STREAMS.  

SciTech Connect (OSTI)

This report examines different alternatives for replacing, treating, and recycling greenhouse gases. It is concluded that treatment (abatement) is the only viable short-term option. Three options for abatement that were tested for use in semiconductor facilities are reviewed, and their performance and costs compared. This study shows that effective abatement options are available to the photovoltaic (PV) industry, at reasonable cost.

FTHENAKIS,V.

2001-12-01T23:59:59.000Z

182

THE GREENHOUSE EFFECT RISING GREENHOUSE GASES AND CLIMATE CHANGE  

E-Print Network [OSTI]

, methane, and nitrous oxides. The sun's energy passes through these gases, like light passing through risen by almost 40 percent. This is attributed primarily to the burning of fossil fuels (coal, oil, gasoline). Methane and nitrous oxides are also increasing rapidly, due in part to the expansion

183

Automatic Process Chromatographs for the Analysis of Corrosive Fluoride Gases  

Science Journals Connector (OSTI)

......hexaflu- oride matrix gas by a trapping procedure...the disadvantage of high cost and require skilled and...lacked reliability in gases of high halocarbon coolant...the uranium hexafluoride gas; impurities have a direct effect on production efficiency. Coolant-114......

J. G. Million; W. S. Pappas; C. W. Weber

1969-03-01T23:59:59.000Z

184

Optical Third-Harmonic Coefficients for Inert Gases  

Science Journals Connector (OSTI)

Optical third-harmonic coefficients ?zzzz(3?) for the inert gases have been calculated taking the LS coupling scheme for helium and Jj and jl coupling schemes for neon, argon, and krypton. Our calculated values agree reasonably well with the experimental values of set (i) of Ward and New.

B. P. Tripathi; R. K. Laloraya; S. L. Srivastava

1971-11-01T23:59:59.000Z

185

Mitigation options for accidental releases of hazardous gases  

SciTech Connect (OSTI)

The objective of this paper is to review and compare technologies available for mitigation of unconfined releases of toxic and flammable gases. These technologies include: secondary confinement, deinventory, vapor barriers, foam spraying, and water sprays/monitors. Guidelines for the design and/or operation of effective post-release mitigation systems and case studies involving actual industrial mitigation systems are also presented.

Fthenakis, V.M.

1995-05-01T23:59:59.000Z

186

SAFT Modeling of the Solubility of Gases in Perfluoroalkanes  

Science Journals Connector (OSTI)

SAFT Modeling of the Solubility of Gases in Perfluoroalkanes ... A molecular model within a SAFT context for quantitatively predicting the solubility of xenon and oxygen in n-perfluoroalkanes is presented and discussed here. ... Free-Volume Theory Coupled with Soft-SAFT for Viscosity Calculations: Comparison with Molecular Simulation and Experimental Data ...

Ana M. A. Dias; Josep C. PÓmies; JoŃo A. P. Coutinho; Isabel M. Marrucho; Lourdes F. Vega

2003-12-30T23:59:59.000Z

187

Rejuvenating Permeable Reactive Barriers by Chemical Flushing  

Broader source: Energy.gov [DOE]

Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

188

Exploring the reactivity of bacterial multicomponent monooxygenases  

E-Print Network [OSTI]

Chapter 1. Introduction: The Reactivity of Bacterial Multicomponent Monooxygenases Bacterial multicomponent monooxygenases constitute a remarkable family of enzymes that oxidize small, inert hydrocarbon substrates using ...

Tinberg, Christine Elaine

2010-01-01T23:59:59.000Z

189

Modeling Terrestrial Biogenic Sources of Oxygenated Organic Emissions  

Science Journals Connector (OSTI)

In recent years, oxygenated volatile organic chemicals (OVOCs) likeacetone have been recognized as important atmospheric constituents due to their ability to sequester reactive nitrogen in the form peroxyacetyl nitrate (PAN) and to be a source ...

Christopher Potter; Steven Klooster; David Bubenheim; Hanwant B. Singh; Ranga Myneni

2003-07-01T23:59:59.000Z

190

Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts  

DOE Patents [OSTI]

A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Anderson, Raymond P. (Idaho Falls, ID)

2008-08-05T23:59:59.000Z

191

Emission factors for particles, elemental carbon, and trace gases from the Kuwait oil fires  

SciTech Connect (OSTI)

Emission factors are presented for particles, elemental carbon (i.e., soot), total organic carbon in particles and vapor, and for various trace gases from the 1991 Kuwait oil fires. Particle emissions accounted for {approximately} 2% of the fuel burned. In general, soot emission factors were substantially lower than those used in recent {open_quotes}nuclear winter{close_quotes} calculations. Differences in the emissions and appearances of some of the individual fires are discussed. Carbon budget data for the composite plumes from the Kuwait fires are summarized; most of the burned carbon in the plumes was in the form of CO{sub 2}. Fluxes are presented for several combustion products. 26 refs., 1 fig., 5 tabs.

Laursen, K.K.; Ferek, R.J.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States); Rasmussen, R.A. [Oregon Graduate Institute of Science and Technology, Beaverton, OR (United States)

1992-09-20T23:59:59.000Z

192

A QSPR Study of the Solubility of Gases and Vapors in Water  

Science Journals Connector (OSTI)

QSPR correlation equations were developed for the prediction of the solubilities of organic gases and vapors in water. ... The Ostwald solubility coefficient (L) is defined as the ratio of the equilibrium concentrations of a gaseous compound in the liquid and in the gas phase (eq 1), where a superscript w (Lw) usually denotes water as a solvent. ... Table 2) are as follows:? the energy gap between HOMO and LUMO (EHOMO ? ELUMO), the numbers of nitrogen atoms and of oxygen atoms in the molecule, and the most negative partial charge weighted topological electronic index43a (PCWTE) defined by eq 7, where qi and qj are the Zefirov partial charges43b of the bonded atoms, rij is the respective bond lengths, and Qmin is the most negative partial charge. ...

Alan R. Katritzky; Lan Mu; Mati Karelson

1996-11-21T23:59:59.000Z

193

Strongly interacting Fermi gases : non-equilibrium dynamics and dimensional crossover  

E-Print Network [OSTI]

Experiments using ultracold atomic gases address fundamental problems in many-body physics. This thesis describes experiments on strongly-interacting gases of fermionic atoms, with a focus on non-equilibrium physics and ...

Sommer, Ariel T. (Ariel Tjodolv)

2013-01-01T23:59:59.000Z

194

Heat Transfer at Low Temperatures between Tube Walls and Gases in Turbulent Flow  

Science Journals Connector (OSTI)

...September 1947 research-article Heat Transfer at Low Temperatures between Tube...counter-flow system to study heat transfer between tube walls and gases at...Determinations on friction accompanying heat transfer with gases in turbulent flow at...

1947-01-01T23:59:59.000Z

195

Greenhouse Gases (GHG) Emissions from Gas Field Water in Southern Gas Field, Sichuan Basin, China  

Science Journals Connector (OSTI)

In order to assess correctly the gases emissions from oil/gas field water and its contributions to the source of greenhouse gases (GHG) at the atmospheric temperature and pressure, ... first developed to study th...

Guojun Chen; Wei Yang; Xuan Fang; Jiaai Zhongů

2014-03-01T23:59:59.000Z

196

Simultaneous Gas Chromatographic Determination of Four Toxic Gases Generally Present in Combustion Atmospheres  

Science Journals Connector (OSTI)

......determining these gases in mixtures...dioxide, nitrogen, water vapor, and...determining these gases in mixtures...dioxide, nitrogen, water vapor, and...to the solubility of A HCN in water, which was...thevariationin gas con- centrations......

Boyd R. Endecott; Donald C. Sanders; Arvind K. Chaturvedi

1996-01-01T23:59:59.000Z

197

E-Print Network 3.0 - atmospheric gases final Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on Climate and Planets http:icp.giss.nasa.gov The Role of the Atmosphere and Greenhouse Effect in Summary: gases, and scenario 3 - an atmosphere and greenhouse gases. Use...

198

Science Organizations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organizations Science Organizations National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place...

199

Reactivity of calcium sulfate from FBC systems  

Science Journals Connector (OSTI)

A relative estimate of the reactivity of calcium sulfate in a number of coal combustion ash samples was obtained, using the rate of solution in water as a parameter. Measurements were also performed on standard samples of calcium sulfate prepared in different ways, for comparison. The temperature of previous treatment appeared as the most important factor determining the reactivity of CaSO4; the grain size distribution was less important, and the duration of heating (even to 105 days) had very little influence. No correlation between specific surface of ash samples and their reactivity was apparent. Calcium sulfate in FBC ash samples was much more reactive than that contained in high-temperature ashes, and than calcium sulfate heated, alone or with various additions, at 850░C for 2 days. Of the six FBC samples tested, five showed similar behaviour, including a sample from a pressurized system; only a deposit from 96 days operation of an industrial CFBC boiler burning petroleum coke showed considerably less reactivity. Surprisingly, CaSO4 from two FBC samples placed in an oven for 60 days under sulfating conditions showed a very similar rate of solution to that of the other FBC samples, while a third sample kept in the oven for 105 days also showed no decrease in reactivity. Only when one of these samples had agglomerated (which occurred between 60 and 105 days) did it show decreased reactivity, suggesting that the agglomeration process rather than duration is significant in promoting sintering and reducing the sulfate reactivity.

Agripanea P. Iribarne; Julio V. Iribarne; Edward J. Anthony

1997-01-01T23:59:59.000Z

200

System for trapping and storing gases for subsequent chemical reduction to solids  

DOE Patents [OSTI]

A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

Vogel, John S. (San Jose, CA); Ognibene, Ted J. (Oakland, CA); Bench, Graham S. (Livermore, CA); Peaslee, Graham F. (Holland, MI)

2009-11-03T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

E-Print Network 3.0 - atmospheric greenhouse gases Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to longwave radiation 12;Greenhouse Gases Polyatomic molecules... the greenhouse effect ... Source: Frierson, Dargan - Department of Atmospheric Sciences, University of...

202

STOMP-ECKEChem: An Engineering Perspective on Reactive Transport in Geologic Media  

SciTech Connect (OSTI)

ECKEChem (Equilibrium, Conservation, Kinetic Equation Chemistry) is a reactive transport module for the STOMP suite of multifluid subsurface flow and transport simulators that was developed from an engineering perspective. STOMP comprises a suite of operational modes that are distinguished by the solved coupled conservation equations with capabilities for a variety of subsurface applications (e.g., environmental remediation and stewardship, geologic sequestration of greenhouse gases, gas hydrate production, and oil shale production). The ECKEChem module was designed to provide integrated reactive transport capabilities across the suite of STOMP simulator operational modes. The initial application for the ECKEChem module was in the simulation of the mineralization reactions that occurred with the injection of supercritical carbon dioxide into deep Columbia River basalt formations, where it was implemented in the STOMP-CO2 simulator. The STOMP-ECKEChem solution approach to modeling reactive transport in multifluid geologic media is founded on an engineering perspective: (1) sequential non-iterative coupling between the flow and reactive transport is sufficient, (2) reactive transport can be modeled by operator splitting with local geochemistry and global transport, (3) geochemistry can be expressed as a system of coupled nonlinear equilibrium, conservation and kinetic equations, (4) a limited number of kinetic equation forms are used in geochemical practice. This chapter describes the conceptual approach to converting a geochemical reaction network into a series of equilibrium, conservation and kinetic equations, the implementation of ECKEChem in STOMP, the numerical solution approach, and a demonstration of the simulator on a complex application involving desorption of uranium from contaminated field-textured sediments.

White, Mark D.; Fang, Yilin

2012-04-04T23:59:59.000Z

203

Self-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy  

E-Print Network [OSTI]

investigated on the epitaxy and self- organization of laterally nanostructured transition metal TM silicideSelf-assembly of silicide quantum dot arrays on stepped silicon surfaces by reactive epitaxy L to be a flexible and a convenient method for the preparation of dense arrays of Co silicide quantum dots

Ortega, Enrique

204

What are greenhouse gases? Many chemical compounds in the atmosphere act as  

E-Print Network [OSTI]

back into space. However, greenhouse gases will not let all the infrared light pass throughWhat are greenhouse gases? Many chemical compounds in the atmosphere act as greenhouse gases the land and oceans. The warmed Earth releases this heat in the form of infrared light (longwave radiation

205

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide  

SciTech Connect (OSTI)

Cerium oxide is a principal component in many heterogeneous catalytic processes. One of its key characteristics is the ability to provide or remove oxygen in chemical reactions. The different crystallographic faces of ceria present significantly different surface structures and compositions that may alter the catalytic reactivity. The structure and composition determine the number of coordination vacancies surrounding surface atoms, the availability of adsorption sites, the spacing between adsorption sites and the ability to remove O from the surface. To investigate the role of surface orientation on reactivity, CeO2 films were grown with two different orientations. CeO2(100) films were grown ex situ by pulsed laser deposition on Nb-doped SrTiO3(100). CeO2(111) films were grown in situ by thermal deposition of Ce metal onto Ru(0001) in an oxygen atmosphere. The chemical reactivity was characterized by the adsorption and decomposition of various molecules such as alcohols, aldehydes and organic acids. In general the CeO2(100) surface was found to be more active, i.e. molecules adsorbed more readily and reacted to form new products, especially on a fully oxidized substrate. However the CeO2(100) surface was less selective with a greater propensity to produce CO, CO2 and water as products. The differences in chemical reactivity are discussed in light of possible structural terminations of the two surfaces. Recently nanocubes and nano-octahedra have been synthesized that display CeO2(100) and CeO2(111) faces, respectively. These nanoparticles enable us to correlate reactions on high surface area model catalysts at atmospheric pressure with model single crystal films in a UHV environment.

Mullins, David R [ORNL] [ORNL; Albrecht, Peter M [ORNL] [ORNL; Calaza, Florencia C [ORNL] [ORNL

2013-01-01T23:59:59.000Z

206

Organization | Department of Energy  

Energy Savers [EERE]

About Us Organization Organization Organization Printable PDF News & Blog CIO Leadership Organization Contact Us...

207

Organization | Department of Energy  

Office of Environmental Management (EM)

About Us Organization Organization Organization News Leadership Organization History Careers Contact Us...

208

Enthalpy and entropy in chemical reactivity  

E-Print Network [OSTI]

Modern Physical Organic Chemistry; University Science Books:Modern Physical Organic Chemistry; University Science Books:Modern Physical Organic Chemistry; University Science Books:

Flach, Agnes

2012-01-01T23:59:59.000Z

209

Agricultural Mitigation of Greenhouse Gases: Science and Policy Options  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Agricultural Mitigation of Greenhouse Gases: Science and Policy Options Agricultural Mitigation of Greenhouse Gases: Science and Policy Options Keith Paustian (keithp@nrel.colostate.edu; 970-491-1547) Natural Resource Ecology Laboratory Colorado State University Ft. Collins, CO 80523 Bruce Babcock (babcock@iastate.edu; 515-294-6785) Cathy Kling (ckling@iastate.edu; 515-294-5767) Center for Agriculture and Rural Development Iowa State University Ames, IA 50011-1070 Jerry Hatfield (hatfield@nstl.gov; 515-294-5723) USDA - National Soil Tilth Laboratory Ames, IA 50011 Rattan Lal (lal.1@osu.edu; 614-292-9069) School of Natural Resources The Ohio State University Columbus, OH 43210-1085 Bruce McCarl (mccarl@tamu.edu; 979-845-1706) Department of Agricultural Economics Texas A&M University College Station, TX 77843-2124 Sandy McLaughlin (un4@ornl.gov; 865-574-7358)

210

CO2 Separation from Low-Temperature Flue Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

partners interested in implementing United States Patent Number 7,842,126 entitled "Co 2 Separation from Low-Temperature Flue Gases." Disclosed in this patent are novel methods for processing carbon dioxide (CO 2 ) from combustion gas streams. Researchers at NETL are focused on the development of novel sorbent systems that can effectively remove CO 2 and other gases in an economically feasible manner with limited impact on energy production cost. The current invention will help in reducing greenhouse gas emissions by using an improved, regenerable aqueous amine and soluble potassium carbonate sorbent system. This novel solvent system may be capable of achieving CO 2 capture from larger emission streams at lower overall cost. Overview Sequestration of CO

211

EIA - Emissions of Greenhouse Gases in the United States 2009  

Gasoline and Diesel Fuel Update (EIA)

Environment Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) This report-the eighteenth annual report-presents the U.S. Energy Information Administration's latest estimates of emissions for carbon dioxide, methane, nitrous oxide, and other greenhouse gases. Download the GHG Report Introduction For this report, activity data on coal and natural gas consumption and electricity sales and losses by sector were obtained from the January 2011 Monthly Energy Review (MER). In keeping with current international practice, this report presents data on greenhouse gas emissions in million metric tons carbon dioxide equivalent. The data can be converted to carbon equivalent units by

212

EIA-Voluntary Reporting of Greenhouse Gases Program - Getting Started  

U.S. Energy Information Administration (EIA) Indexed Site

Getting Started Getting Started Voluntary Reporting of Greenhouse Gases Program Getting Started Form EIA-1605 may seem daunting at first, even for entities that have reported under the original program. That's why EIA has developed the Getting Started page to help entities take a systematic approach to reporting their emissions and reductions. The Voluntary Reporting of Greenhouse Gases Program suggests that prospective reporters familiarize themselves with the specific requirements for reporting their entity's inventory and reductions by answering the questions embodied in the 10 steps below. In addition, EIA has prepared the interactive Getting Started tool to help reporters determine what parts of Form EIA-1605 they need to complete. Getting Started Tool Getting Started PDF Tables

213

Transporting & Shipping Hazardous Materials at LBNL: Compressed Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Compressed Gases Compressed Gases Self-Transport by Hand & Foot Self-Transport by Vehicle Ship by Common Carrier Conduct Field Work Return Cylinders Self-Transport by Hand & Foot Staff may personally move (self-transport) compressed gas cylinders by hand & foot between buildings and in connecting spaces (i.e., hallways, elevators, etc.) within buildings provided it can be done safely. The following safety precautions apply: Use standard cylinder dollies to transport compressed gas cylinders. While dollies are preferred, cylinders weighing 11 Kg (25 lbs) or less may be hand-carried. Never move a cylinder with a regulator connected to it. Cylinder valve-protection caps and valve-opening caps must be in place when moving cylinders. Lecture bottles and other cylinders that are

214

Recovery of CO2 from Flue Gases: Commercial Trends  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CO CO 2 from Flue Gases: Commercial Trends Originally presented at the Canadian Society of Chemical Engineers annual meeting October 4-6, 1999, Saskatoon, Saskatchewan, Canada Authors: Dan G. Chapel (dan.chapel@fluor.com; 949-349-7530) Carl L. Mariz (carl.mariz@fluor.com; 949-349-7530) FluorDaniel One Fluor Drive Aliso Viejo CA, 92698 John Ernest (john.ernest@minimed.com; 818-576-4293) Advanced Quality Services Inc 11024 Balboa Blvd. PMB154, Granada Hills, CA 91344-5007 1 Recovery of CO 2 from Flue Gases: Commercial Trends Originally presented at the Canadian Society of Chemical Engineers annual meeting October 4-6, 1999, Saskatoon, Saskatchewan, Canada Authors: Dan Chapel - Fluor Daniel Inc., Senior Vice President Technology; Oil, Gas & Power John Ernest - Advanced Quality Services Inc., Validation Engineer

215

PPPL wins Department of Energy award for reducing greenhouse gases |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PPPL wins Department of Energy award for reducing greenhouse gases PPPL wins Department of Energy award for reducing greenhouse gases By Jeanne Jackson DeVoe October 2, 2012 Tweet Widget Facebook Like Google Plus One PPPL engineer Tim Stevenson checks for possible leaks of sulfur hexafluoride (SF6), the gas used to insulate electronic equipment that has the potential to cause global warming at many times the rate of carbon dioxide. PPPL reduced leaks of SF6 by 65 percent over three years - reducing overall greenhouse gas emissions by 48 percent between 2008 and 2011. (Photo by Elle Starkman/PPPL Office of Communications) PPPL engineer Tim Stevenson checks for possible leaks of sulfur hexafluoride (SF6), the gas used to insulate electronic equipment that has the potential to cause global warming at many times the rate of carbon

216

Reading Comprehension - Properties of Solids, Liquids, and Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Properties of Solids, Liquids, and Gases Properties of Solids, Liquids, and Gases A solid has a definite _________ mass texture volume and a _________ 3D irregular definite shape. The particles in a solid are _________ free to move around motionless packed tightly together . Particles in a solid move by _________ sliding past one another vibrating back and forth slightly jiggling around . _________ Viscosity Amorphous Crystalline solids soften before melting. The particles in this type of solid are not arranged in regular pattern. Amorphous solids _________ do don't have a distinct melting point. Crystalline solids have a _________ distinct color and shape distinct pattern and melting point . Liquids have no _________ volume mass shape of their own. A liquid takes the shape of its container. Without a container liquids spread into a wide,

217

PPPL Wins Department of Energy Award For Reducing Greenhouse Gases |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wins Department of Energy Award For Reducing Greenhouse Gases Wins Department of Energy Award For Reducing Greenhouse Gases By Jeanne Jackson DeVoe October 2, 2012 Tweet Widget Facebook Like Google Plus One PPPL's Tim Stevenson takes inventory of the SF6 levels at a power supply tank for NSTX. (Photo by Elle Starkman, PPPL Office of Communications) PPPL's Tim Stevenson takes inventory of the SF6 levels at a power supply tank for NSTX. The U.S. Department of Energy's (DOE) Princeton Plasma Physics Laboratory (PPPL) has received a federal Sustainability Award for reducing overall greenhouse gas emissions 48 percent since 2008 - far exceeding the U.S. government's goal of a 28 percent reduction. Members of the PPPL staff were among the 20 recipients of the Sustainability Awards in a ceremony in Washington, D.C., on Thursday, Sept.

218

The extreme nonlinear optics of gases and femtosecond optical filamentation  

SciTech Connect (OSTI)

Under certain conditions, powerful ultrashort laser pulses can form greatly extended, propagating filaments of concentrated high intensity in gases, leaving behind a very long trail of plasma. Such filaments can be much longer than the longitudinal scale over which a laser beam typically diverges by diffraction, with possible applications ranging from laser-guided electrical discharges to high power laser propagation in the atmosphere. Understanding in detail the microscopic processes leading to filamentation requires ultrafast measurements of the strong field nonlinear response of gas phase atoms and molecules, including absolute measurements of nonlinear laser-induced polarization and high field ionization. Such measurements enable the assessment of filamentation models and make possible the design of experiments pursuing applications. In this paper, we review filamentation in gases and some applications, and discuss results from diagnostics developed at Maryland for ultrafast measurements of laser-gas interactions.

Milchberg, H. M.; Chen, Y.-H.; Cheng, Y.-H.; Jhajj, N.; Palastro, J. P.; Rosenthal, E. W.; Varma, S.; Wahlstrand, J. K.; Zahedpour, S. [Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

2014-10-15T23:59:59.000Z

219

Apparatus for the plasma destruction of hazardous gases  

DOE Patents [OSTI]

A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

Kang, Michael (Los Alamos, NM)

1995-01-01T23:59:59.000Z

220

Apparatus for the plasma destruction of hazardous gases  

DOE Patents [OSTI]

A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

Kang, M.

1995-02-07T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Decontamination of combustion gases in fluidized bed incinerators  

DOE Patents [OSTI]

Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

Leon, Albert M. (Mamaroneck, NY)

1982-01-01T23:59:59.000Z

222

Reduction of greenhouse gases using renewable energies in Mexico 2025  

Science Journals Connector (OSTI)

This study presents three scenarios relating to the environmental futures of Mexico up to the year 2025. The first scenario emphasizes the use of oil products, particularly fueloil, and represents the energy policy path that was in effect until 1990. The second scenario prioritizes the use of natural gas, reflecting the energy consumption pattern that arose in the mid-1990s as a result of reforms in the energy sector. In the third scenario, the high participation of renewable sources of energy, in particular renewable hydrogen, is considered feasible from a technical and economic point of view. The three scenarios are evaluated up to the year 2025 in terms of greenhouse gases (GHG), acid rain precursor gases (ARPG), and environmentľenergy intensity factors.

F Manzini; J Islas; M Mart??nez

2001-01-01T23:59:59.000Z

223

Evaluaciˇn de la generaciˇn de gases de efecto invernadero asociados al ciclo de vida de los biocombustibles colombianos = Assessment of greenhouse gases emissions associated to colombian biofuels lifecycle.  

E-Print Network [OSTI]

??Valencia Botero, Monica Julieth (2012) Evaluaciˇn de la generaciˇn de gases de efecto invernadero asociados al ciclo de vida de los biocombustibles colombianos = Assessmentů (more)

Valencia Botero, Monica Julieth

2012-01-01T23:59:59.000Z

224

Comparative Analysis of Alternative Means for Removing Noncondensable Gases  

Open Energy Info (EERE)

Comparative Analysis of Alternative Means for Removing Noncondensable Gases Comparative Analysis of Alternative Means for Removing Noncondensable Gases from Flashed-Steam Geothermal Power Plants:April 1999 - March 2000 Dataset Summary Description This dataset corresponds to the final report on a screening study to compare six methods of removing noncondensable gases from direct-use geo-thermal steam power plants. This report defines the study methodologies and compares the performance and economics of selected gas-removal systems. Recommendations are presented for follow-up investigations and implementation of some of the technologies discussed. The specific gas-removal methods include five vacuum system configurations using the conventional approach of evacuating gas/vapor mixtures from the power plant condenser system and a system for physical separation of steam and gases upstream of the power turbine. The study focused on flashed-steam applications, but the results apply equally well to flashed-steam and dry-steam geothermal power plant configurations. Two gas-removal options appear to offer profitable economic potential. The hybrid vacuum system configurations and the reboiler process yield positive net present value results over wide-ranging gas concentrations. The hybrid options look favorable for both low-temperature and high-temperature resource applications. The reboiler looks profitable for low-temperature resource applications for gas levels above about 20,000 parts per million by volume. A vacuum system configuration using a three-stage turbocompressor battery may be profitable for low-temperature resources, but results show that the hybrid system is more profitable. The biphase eductor alternative cannot be recommended for commercialization at this time. The report is available from NREL's publication database.

225

Extraction of uranium from spent fuels using liquefied gases  

SciTech Connect (OSTI)

For reprocessing of spent nuclear fuels, a novel method to extract actinides from spent fuel using highly compressed gases, nitrogen dioxide and carbon dioxide was proposed. As a fundamental study, the nitrate conversion with liquefied nitrogen dioxide and the nitrate extraction with supercritical carbon dioxide were demonstrated by using uranium dioxide powder, uranyl nitrate and tri-n-butylphosphate complex in the present study. (authors)

Sawada, Kayo; Hirabayashi, Daisuke; Enokida, Youichi [EcoTopia Science Institute, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603 (Japan)

2007-07-01T23:59:59.000Z

226

Analysis of greenhouse gases trading system using conversations among stakeholders  

Science Journals Connector (OSTI)

Greenhouse gas (GHG) reduction agreement makes up the targeted reduction of a legally binding GHG for each country or region. It enables us to buy and sell some GHG with other countries; it is the GHG trading system. But now, some free riders, ... Keywords: GHG emissions, GHG trading systems, MAS, agent-based modelling, agent-based systems, consumer behaviour, emissions reduction, free riders, genetic algorithms, global warming, greenhouse gases, multi-agent simulation, multi-agent systems

Setsuya Kurahashi; Masato Ohori

2010-08-01T23:59:59.000Z

227

In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and Reactive Landing of Mass Selected Ions. In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and...

228

Chemical production from industrial by-product gases: Final report  

SciTech Connect (OSTI)

The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

Lyke, S.E.; Moore, R.H.

1981-04-01T23:59:59.000Z

229

Production of quantum degenerate strontium gases: Larger, better, faster, colder  

E-Print Network [OSTI]

We report on an improved scheme to generate Bose-Einstein condensates (BECs) and degenerate Fermi gases of strontium. This scheme allows us to create quantum gases with higher atom number, a shorter time of the experimental cycle, or deeper quantum degeneracy than before. We create a BEC of 84-Sr exceeding 10^7 atoms, which is a 30-fold improvement over previously reported experiments. We increase the atom number of 86-Sr BECs to 2.5x10^4 (a fivefold improvement), and refine the generation of attractively interacting 88-Sr BECs. We present a scheme to generate 84-Sr BECs with a cycle time of 2s, which, to the best of our knowledge, is the shortest cycle time of BEC experiments ever reported. We create deeply-degenerate 87-Sr Fermi gases with T/T_F as low as 0.10(1), where the number of populated nuclear spin states can be set to any value between one and ten. Furthermore, we report on a total of five different double-degenerate Bose-Bose and Bose-Fermi mixtures. These studies prepare an excellent starting poi...

Stellmer, Simon; Schreck, Florian

2012-01-01T23:59:59.000Z

230

EIA-Voluntary Reporting of Greenhouse Gases Program - What's New  

U.S. Energy Information Administration (EIA) Indexed Site

Environment > Voluntary Reporting Program > What's New Environment > Voluntary Reporting Program > What's New Voluntary Reporting of Greenhouse Gases Program What's New Voluntary Reporting of Greenhouse Gases Program Suspended May 2011 The U.S. Energy Information Administration (EIA) Voluntary Reporting of Greenhouse Gases ("1605(b)") Program has been suspended. The suspension is due to recent reductions in budget appropriations and is effective immediately. Survey respondents may still submit data to the 1605(b) Program using the program's Workbook Form via EIA's Secure File Transfer mechanism. However, EIA will not be able to process and review submitted data or offer respondent support on the submitted data. Should a respondant submit data under the current collection cycle to EIA, the data will be retained in our electronic records. If the 1605(b) Program resumes normal operations, your submitted data will be reviewed and processed at that time. You will be notified in the future if the 1605(b) Program resumes normal operation. If you have any questions, please contact the survey manager, Paul McArdle, at paul.mcardle@eia.gov

231

Supporting Information:1 Contributions of individual reactive biogenic volatile organic compounds to organic2  

E-Print Network [OSTI]

System Laboratory, National Center for22 Atmospheric Research, Boulder, CO USA23 Now at: Air Pollution 8 Universit├ę Lille Nord de France, Lille, France16 9 ├?cole des Mines de Douai, Douai, France17 10

Meskhidze, Nicholas

232

Compatibility of Space Nuclear Power Plant Materials in an Inert He/Xe Working Gas Containing Reactive Impurities  

SciTech Connect (OSTI)

A major materials selection and qualification issue identified in the Space Materials Plan is the potential for creating materials compatibility problems by combining dissimilar reactor core, Brayton Unit and other power conversion plant materials in a recirculating, inert He/Xe gas loop containing reactive impurity gases. Reported here are results of equilibrium thermochemical analyses that address the compatibility of space nuclear power plant (SNPP) materials in high temperature impure He gas environments. These studies provide early information regarding the constraints that exist for SNPP materials selection and provide guidance for establishing test objectives and environments for SNPP materials qualification testing.

MM Hall

2006-01-31T23:59:59.000Z

233

Metal-organic frameworks with high capacity and selectivity for harmful gases  

E-Print Network [OSTI]

, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethyl- ene oxide, and carbon monoxide. Kinetic

Yaghi, Omar M.

234

Metal-organic frameworks with high capacity and selectivity for harmful gases  

Science Journals Connector (OSTI)

...sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene...dioxide, dichloromethane, and tetrahydrothiophene. We sample a wide range of size, acidity, vapor...001 0.036 0.092 0.190 1.76 Tetrahydrothiophene 0.001 0.007 0.090 <0.001...

David Britt; David Tranchemontagne; Omar M. Yaghi

2008-01-01T23:59:59.000Z

235

Nuclear magnetic resonance of laser-polarized noble gases in molecules, materials and organisms  

E-Print Network [OSTI]

Schmidt, D. Fick, and H.J. Jansch, Production of nitrogen-24-30 (1997). [52] H.J. Jansch, T. Hof, U. Ruth, J. Schmidt,

Goodson, B.M.

2010-01-01T23:59:59.000Z

236

Shock-induced chemistry in organic materials  

SciTech Connect (OSTI)

The combined 'extreme' environments of high pressure, temperature, and strain rates, encountered under shock loading, offer enormous potential for the discovery of new paradigms in chemical reactivity not possible under more benign conditions. All organic materials are expected to react under these conditions, yet we currently understand very little about the first bond-breaking steps behind the shock front, such as in the shock initiation of explosives, or shock-induced reactivity of other relevant materials. Here, I will present recent experimental results of shock-induced chemistry in a variety of organic materials under sustained shock conditions. A comparison between the reactivity of different structures is given, and a perspective on the kinetics of reaction completion under shock drives.

Dattelbaum, Dana M [Los Alamos National Laboratory; Sheffield, Steve [Los Alamos National Laboratory; Engelke, Ray [Los Alamos National Laboratory; Manner, Virginia [Los Alamos National Laboratory; Chellappa, Raja [Los Alamos National Laboratory; Yoo, Choong - Shik [WASHINGTON STATE UNIV

2011-01-20T23:59:59.000Z

237

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Broader source: Energy.gov (indexed) [DOE]

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical

238

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Broader source: Energy.gov (indexed) [DOE]

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Ca├▒on City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Ca├▒on City, Colorado, Uranium

239

Characterization of Dual-Fuel Reactivity Controlled Compression...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI)...

240

Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity  

DOE Patents [OSTI]

A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime (about 40 ps), high frequency (about 5G hz), high power bursts of low-duty factor microwaves sufficient to generate a dielectric barrier discharge and passing a gas to treated through the discharge so as to cause dissociative reduction of the exhaust gases. The invention also includes a reactor for generating the non-thermal plasma.

Whealton, John H. (Oak Ridge, TN); Hanson, Gregory R. (Clinton, TN); Storey, John M. (Oak Ridge, TN); Raridon, Richard J. (Oak Ridge, TN); Armfield, Jeffrey S. (Upsilanti, MI); Bigelow, Timothy S. (Knoxville, TN); Graves, Ronald L. (Knoxville, TN)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

COAL SLAGGING AND REACTIVITY TESTING  

SciTech Connect (OSTI)

Union Fenosa's La Robla I Power Station is a 270-MW Foster Wheeler arch-fired system. The unit is located at the mine that provides a portion of the semianthracitic coal. The remaining coals used are from South Africa, Russia, Australia, and China. The challenges at the La Robla I Station stem from the various fuels used, the characteristics of which differ from the design coal. The University of North Dakota Energy & Environmental Research Center (EERC) and the Lehigh University Energy Research Center (LUERC) undertook a program to assess problematic slagging and unburned carbon issues occurring at the plant. Full-scale combustion tests were performed under baseline conditions, with elevated oxygen level and with redistribution of air during a site visit at the plant. During these tests, operating information, observations and temperature measurements, and coal, slag deposit, and fly ash samples were obtained to assess slagging and unburned carbon. The slagging in almost all cases appeared due to elevated temperatures rather than fuel chemistry. The most severe slagging occurred when the temperature at the sampling port was in excess of 1500 C, with problematic slagging where first-observed temperatures exceeded 1350 C. The presence of anorthite crystals in the bulk of the deposits analyzed indicates that the temperatures were in excess of 1350 C, consistent with temperature measurements during the sampling period. Elevated temperatures and ''hot spots'' are probably the result of poor mill performance, and a poor distribution of the coal from the mills to the specific burners causes elevated temperatures in the regions where the slag samples were extracted. A contributing cause appeared to be poor combustion air mixing and heating, resulting in oxygen stratification and increased temperatures in certain areas. Air preheater plugging was observed and reduces the temperature of the air in the windbox, which leads to poor combustion conditions, resulting in unburned carbon as well as slagging. A second phase of the project involved advanced analysis of the baseline coal along with an Australian coal fired at the plant. These analysis results were used in equilibrium thermodynamic modeling along with a coal quality model developed by the EERC to assess slagging, fouling, and opacity for the coals. Bench-scale carbon conversion testing was performed in a drop-tube furnace to assess the reactivity of the coals. The Australian coal had a higher mineral content with significantly more clay minerals present than the baseline coal. The presence of these clay minerals, which tend to melt at relatively low temperatures, indicated a higher potential for problematic slagging than the baseline coal. However, the pyritic minerals, comprising over 25% of the baseline mineral content, may form sticky iron sulfides, leading to severe slagging in the burner region if local areas with reducing conditions exist. Modeling results indicated that neither would present significant fouling problems. The Australian coal was expected to show slagging behavior much more severe than the baseline coal except at very high furnace temperatures. However, the baseline coal was predicted to exhibit opacity problems, as well as have a higher potential for problematic calcium sulfate-based low-temperature fouling. The baseline coal had a somewhat higher reactivity than the Australian coal, which was consistent with both the lower average activation energy for the baseline coal and the greater carbon conversion at a given temperature and residence time. The activation energy of the baseline coal showed some effect of oxygen on the activation energy, with E{sub a} increasing at the lower oxygen concentration, but may be due to the scatter in the baseline coal kinetic values at the higher oxygen level tested.

Donald P. McCollor; Kurt E. Eylands; Jason D. Laumb

2003-10-01T23:59:59.000Z

242

Consideration of spatial effects in reactivity measurements  

SciTech Connect (OSTI)

Various methods of considering spatial effects in reactivity measurements are presented. These methods are employed both at the critical (mainly fast-neutron) facilities and at the BN-600 reactor.

Matveenko, I. P., E-mail: matveenko@ippe.ru; Lititskii, V. A.; Shokod'ko, A. G. [Institute of Physics and Power Engineering (Russian Federation)

2010-12-15T23:59:59.000Z

243

Systematic approach for chemical reactivity evaluation  

E-Print Network [OSTI]

Screening Tool (RSST) and the Automatic Pressure Tracking Adiabatic Calorimeter (APTAC) were employed to evaluate the reactive systems experimentally. The RSST detected exothermic behavior and measured the overall liberated energy. The APTAC simulated...

Aldeeb, Abdulrehman Ahmed

2004-09-30T23:59:59.000Z

244

Reactivity control assembly for nuclear reactor  

DOE Patents [OSTI]

Reactivity control assembly for nuclear reactor comprises supports stacked above reactor core for holding control rods. Couplers associated with the supports and a vertically movable drive shaft have lugs at their lower ends for engagement with the supports.

Bollinger, Lawrence R. (Schenectady, NY)

1984-01-01T23:59:59.000Z

245

Fossil plant layup and reactivation conference: Proceedings  

SciTech Connect (OSTI)

The Fossil Plant Layup and Reactivation Conference was held in New Orleans, Louisiana on April 14--15, 1992. The Conference was sponsored by EPRI and hosted by Entergy Services, Inc. to bring together representatives from utilities, consulting firms, manufacturers and architectural engineers. Eighteen papers were presented in three sessions. These sessions were devoted to layup procedures and practices, and reactivation case studies. A panel discussion was held on the second day to interactively discuss layup and reactivation issues. More than 80 people attended the Conference. This report contains technical papers and a summary of the panel discussion. Of the eighteen papers, three are related to general, one is related to regulatory issues, three are related to specific equipment, four are related to layup procedures and practices, and seven are layup and reactivation case studies.

Not Available

1992-10-01T23:59:59.000Z

246

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

1998-01-01T23:59:59.000Z

247

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

1998-09-08T23:59:59.000Z

248

A Tariff for Reactive Power - IEEE  

SciTech Connect (OSTI)

This paper describes a suggested tariff or payment for the local supply of reactive power from distributed energy resources. The authors consider four sample customers, and estimate the cost of supply of reactive power for each customer. The power system savings from the local supply of reactive power are also estimated for a hypothetical circuit. It is found that reactive power for local voltage regulation could be supplied to the distribution system economically by customers when new inverters are installed. The inverter would be supplied with a power factor of 0.8, and would be capable of local voltage regulation to a schedule supplied by the utility. Inverters are now installed with photovoltaic systems, fuel cells and microturbines, and adjustable-speed motor drives.

Kueck, John D [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator; Kirby, Brendan J [ORNL

2008-11-01T23:59:59.000Z

249

Reactive Attachment Disorder: Concepts, Treatment, and Research  

E-Print Network [OSTI]

Reactive Attachment Disorder (RAD) is a disorder characterized by controversy, both with respect to its definition and its treatment. By definition, the RAD diagnosis attempts to characterize and explain the origin of ...

Walter, Uta M.; Petr, Chris

2004-06-01T23:59:59.000Z

250

Emissions of trace gases and aerosols during the open combustion of biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Emissions of trace gases and aerosols during the open combustion of biomass Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory Title Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory Publication Type Journal Article Year of Publication 2009 Authors McMeeking, Gavin R., Sonia M. Kreidenweis, Stephen Baker, Christian M. Carrico, Judith C. Chow, Jeffrey Collett L. Jr., Wei Min Hao, Amanda S. Holden, Thomas W. Kirchstetter, William C. Malm, Hans Moosmuller, Amy P. Sullivan, and Cyle E. Wold Journal Journal of Geophysical Research Volume 114 Abstract We characterized the gas- and speciated aerosol-phase emissions from the open combustion of 33 different plant species during a series of 255 controlled laboratory burns during the Fire Laboratory at Missoula Experiments (FLAME). The plant species we tested were chosen to improve the existing database for U.S. domestic fuels: laboratory-based emission factors have not previously been reported for many commonly burned species that are frequently consumed by fires near populated regions and protected scenic areas. The plants we tested included the chaparral species chamise, manzanita, and ceanothus, and species common to the southeastern United States (common reed, hickory, kudzu, needlegrass rush, rhododendron, cord grass, sawgrass, titi, and wax myrtle). Fire-integrated emission factors for gas-phase CO2, CO, CH4, C2-4 hydrocarbons, NH3, SO2, NO, NO2, HNO3, and particle-phase organic carbon (OC), elemental carbon (EC), SO4 2, NO3, Cl, Na+, K+, and NH4 + generally varied with both fuel type and with the fire-integrated modified combustion efficiency (MCE), a measure of the relative importance of flaming- and smoldering-phase combustion to the total emissions during the burn. Chaparral fuels tended to emit less particulate OC per unit mass of dry fuel than did other fuel types, whereas southeastern species had some of the largest observed emission factors for total fine particulate matter. Our measurements spanned a larger range of MCE than prior studies, and thus help to improve estimates of the variation of emissions with combustion conditions for individual fuels.

251

Prospecting by sampling and analysis of airborne particulates and gases  

DOE Patents [OSTI]

A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

Sehmel, G.A.

1984-05-01T23:59:59.000Z

252

Coherence Length of Cold Exciton Gases in Coupled Quantum Wells  

Science Journals Connector (OSTI)

A Mach-Zehnder interferometer with spatial and spectral resolution was used to probe spontaneous coherence in cold exciton gases, which are implemented experimentally in the ring of indirect excitons in coupled quantum wells. A strong enhancement of the exciton coherence length is observed at temperatures below a few Kelvin. The increase of the coherence length is correlated with the macroscopic spatial ordering of excitons. The coherence length at the lowest temperature corresponds to a very narrow spread of the exciton momentum distribution, much smaller than that for a classical exciton gas.

Sen Yang, A. T. Hammack, M. M. Fogler, L. V. Butov, and A. C. Gossard

2006-10-31T23:59:59.000Z

253

Zero sound modes of dilute Fermi gases with arbitrary spin  

Science Journals Connector (OSTI)

Motivated by the recent success of optical trapping of alkali-metal bosons, we have studied the zero sound modes of dilute Fermi gases with arbitrary spin-f, which are spin-S excitations (0<~S<~2f). The dispersion of the mode (S) depends on a single Landau parameter F(S), which is related to the scattering lengths of the system through a simple formula. Measurement of (even a subset of) these modes in finite magnetic fields will enable one to determine all the interaction parameters of the system.

S.-K. Yip and Tin-Lun Ho

1999-06-01T23:59:59.000Z

254

Photoconversion of gasified organic materials into biologically-degradable plastics  

DOE Patents [OSTI]

A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer. 3 figures.

Weaver, P.F.; Pinching Maness.

1993-10-05T23:59:59.000Z

255

Photoconversion of gasified organic materials into biologically-degradable plastics  

DOE Patents [OSTI]

A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer.

Weaver, Paul F. (Golden, CO); Maness, Pin-Ching (Golden, CO)

1993-01-01T23:59:59.000Z

256

Phase II: Performance Evaluation of Permeable Reactive Barriers and  

Broader source: Energy.gov (indexed) [DOE]

Phase II: Performance Evaluation of Permeable Reactive Barriers and Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing U. S. Environmental Protection Agency Region 8 Support January 2004 Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing

257

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Broader source: Energy.gov (indexed) [DOE]

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Ca├▒on City, Colorado, Uranium

258

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Broader source: Energy.gov (indexed) [DOE]

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

259

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

Many contaminated areas consist of a source area and a plume. In the source area, the contaminant moves vertically downward from a release point through the vadose zone to an underlying saturated region. Where contaminants are organic liquids, NAPL may accumulate on the water table, or it may continue to migrate downward through the saturated region. Early developments of permeable barrier technology have focused on intercepting horizontally moving plumes with vertical structures, such as trenches, filled with reactive material capable of immobilizing or degrading dissolved contaminants. This focus resulted in part from a need to economically treat the potentially large volumes of contaminated water in a plume, and in part from the availability of construction technology to create the vertical structures that could house reactive compounds. Contaminant source areas, however, have thus far remained largely excluded from the application of permeable barrier technology. One reason for this is the lack of conventional construction methods for creating suitable horizontal structures that would place reactive materials in the path of downward-moving contaminants. Methods of hydraulic fracturing have been widely used to create flat-lying to gently dipping layers of granular material in unconsolidated sediments. Most applications thus far have involved filling fractures with coarse-grained sand to create permeable layers that will increase the discharge of wells recovering contaminated water or vapor. However, it is possible to fill fractures with other compounds that alter the chemical composition of the subsurface. One early application involved development and field testing micro-encapsulated sodium percarbonate, a solid compound that releases oxygen and can create aerobic conditions suitable for biodegradation in the subsurface for several months.

Murdoch, L. [FRx Inc., Cincinnati, OH (United States); [Clemson Univ., SC (United States); Siegrist, B. [Oak Ridge National Lab., TN (United States); Vesper, S. [Univ. of Cincinnati, OH (United States)] [and others

1997-12-31T23:59:59.000Z

260

Instantaneous and efficient surface wave excitation of a low pressure gas or gases  

DOE Patents [OSTI]

A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

Levy, Donald J. (Berkeley, CA); Berman, Samuel M. (San Francisco, CA)

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Illinois Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0

262

Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0 2009 0 0 0 0 0 0 0 0 0 0 0 0 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 NA NA NA NA NA NA NA NA NA NA NA NA

263

Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0 2009 0 0 0 0 0 0 0 0 0 0 0 0 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 NA NA NA NA NA NA NA NA NA NA NA NA

264

Synthetic Lorentz force in classical atomic gases via Doppler effect and radiation pressure  

E-Print Network [OSTI]

We theoretically predict a novel type of synthetic Lorentz force for classical (cold) atomic gases, which is based on the Doppler effect and radiation pressure. A fairly uniform and strong force can be constructed for gases in macroscopic volumes of several cubic millimeters and more. This opens the possibility to mimic classical charged gases in magnetic fields, such as those in a tokamak, in cold atom experiments.

Dub?ek, T; Juki?, D; Aumiler, D; Ban, T; Buljan, H

2014-01-01T23:59:59.000Z

265

Organic Photovoltaics  

Science Journals Connector (OSTI)

Satisfying the world's growing demand for energy is an urgent societal challenge. Organic photovoltaics holds promise as a cost-efficient and environmentally friendly solution.

Kippelen, Bernard

2007-01-01T23:59:59.000Z

266

E-Print Network 3.0 - automobile exhaust gases Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

exhaust gases Page: << < 1 2 3 4 5 > >> 1 Ability of Catalytic Converters to Reduce Air Pollution Summary: Air Pollution MEASUREMENT OF SELECTED AIR POLLUTANTS IN CAR EXHAUST...

267

E-Print Network 3.0 - aircraft exhaust gases Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gases FAA, 2005. Water in the aircraft exhaust at altitude may have a greenhouse effect... . Aircraft ... Source: Ecole Polytechnique, Centre de mathmatiques...

268

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

269

Reactivity of tributyl phosphate degradation products with nitric acid: Relevance to the Tomsk-7 accident  

SciTech Connect (OSTI)

The reaction of a degraded tributyl phosphate (TBP) solvent with nitric acid is thought to have caused the chemical explosion at the Tomsk-7 reprocessing plant at Tomsk, Russia in 1993. The estimated temperature of the organic layer was not high eneough to cause significant reaction of nitric acid with TBP or hydrocarbon diluent compounds. A more reactive organic compound was likely present in the organic layer that reacted with sufficient heat generation to raise the temperature to the point where an autocatalytic oxidation of the organic solvent was initiated. Two of the most likely reactive compounds that are present in degraded TBP solvents are n-butanol and n-butyl nitrate. The reactions of these compounds with nitric acid are the subject of this study. The objective of laboratory-scale tests was to identify chemical reactions that occur when n-butanol and n-butyl nitrate contact heated nitric acid solutions. Reaction products were identified and quantitified, the temperatures at which these reactions occur and heats of reaction were measured, and reaction variables (temperature, nitric acid concentration, organic concentration, and reaction time) were evaluated. Data showed that n-butyl nitrate is less reactive than n-butanol. An essentially complete oxidation reaction of n-butanol at 110-120 C produced four major reaction products. Mass spectrometry identified the major inorganic oxidation products for both n-butanol and n-butyl nitrate as nitric oxide and carbon dioxide. Calculated heats of reaction for n-butanol and n-butyl nitrate to form propionic acid, a major reaction product, are -1860 cal/g n-butanol and -953 cal/g n-butyl nitrate. These heats of reaction are significant and could have raised the temperature of the organic layer in the Tomsk-7 tank to the point where autocatalytic oxidation of other organic compounds present resulted in an explosion.

Barney, G.S.; Cooper, T.D. [Westinghouse Hanford Company, Richland, WA (United States)

1995-12-31T23:59:59.000Z

270

Design and synthesis of reactive separation systems  

SciTech Connect (OSTI)

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-01-01T23:59:59.000Z

271

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-11-25T23:59:59.000Z

272

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-01-21T23:59:59.000Z

273

Assess Potential Agency Size Changes that Impact Greenhouse Gases from  

Broader source: Energy.gov (indexed) [DOE]

Vehicles and Mobile Equipment Vehicles and Mobile Equipment Assess Potential Agency Size Changes that Impact Greenhouse Gases from Vehicles and Mobile Equipment October 7, 2013 - 11:31am Addthis YOU ARE HERE Step 1 Planned changes in a Federal agency's size, missions, transportation needs, and vehicle inventory all impact the strategic portfolio planning efforts that target greenhouse gas (GHG) emissions mitigation for vehicles and mobile equipment. Under Section 142 of the Energy Independence and Security Act (EISA) and Section 8 of Executive Order (E.O.) 13514, agencies are required to develop a plan that will reduce fleet GHG emissions to meet Federally mandated petroleum reduction and alternative fuel increase targets. Agencies can use these plans as a basis for determining potential changes in fleet size and

274

Assess Potential Agency Size Changes that Impact Greenhouse Gases from  

Broader source: Energy.gov (indexed) [DOE]

Employee Commuting Employee Commuting Assess Potential Agency Size Changes that Impact Greenhouse Gases from Employee Commuting October 7, 2013 - 1:42pm Addthis YOU ARE HERE Step 1 For employee commuting, it is important to account for any planned or expected changes in a Federal agency's size when estimating the greenhouse gas (GHG) reduction potential for different operating units or worksites. Considerations include: Are employment levels expected to change in the next decade at specific facilities or agency-wide? Are there any planned facility moves at major worksites? Employee commute coordinators may want to engage human resources and strategic planners in this effort to establish likely changes in employment numbers. Facility planners may be engaged to understand changes in commutes

275

The Breakdown of Gases in High Frequency Electrical Fields  

Science Journals Connector (OSTI)

A theory is proposed to explain the mechanism of breakdown of gases in high frequency electrical fields. It is assumed that breakdown occurs when the electrical field and the frequency are such that an electron acquires the ionizing energy at the end of one mean free path. The field for breakdown is thus a function of the frequency of the applied potential and the ionization potential and pressure of the gas. The fields for breakdown of argon and xenon are calculated and expressed as functions of the frequency and the gas pressure. The calculated potentials are compared with experimental data, and good agreement is found for frequencies greater than 10Î106 c.p.s.

Donald H. Hale

1948-05-01T23:59:59.000Z

276

WIMP Dark Matter Direct-Detection Searches in Noble Gases  

E-Print Network [OSTI]

Cosmological observations and the dynamics of the Milky Way provide ample evidence for an invisible and dominant mass component. This so-called dark matter could be made of new, colour and charge neutral particles, which were non-relativistic when they decoupled from ordinary matter in the early universe. Such weakly interacting massive particles (WIMPs) are predicted to have a non-zero coupling to baryons and could be detected via their collisions with atomic nuclei in ultra-low background, deep underground detectors. Among these, detectors based on liquefied noble gases have demonstrated tremendous discovery potential over the last decade. After briefly introducing the phenomenology of direct dark matter detection, I will review the main properties of liquefied argon and xenon as WIMP targets and discuss sources of background. I will then describe existing and planned argon and xenon detectors that employ the so-called single- and dual-phase detection techniques, addressing their complementarity and science...

Baudis, Laura

2014-01-01T23:59:59.000Z

277

WIMP Dark Matter Direct-Detection Searches in Noble Gases  

E-Print Network [OSTI]

Cosmological observations and the dynamics of the Milky Way provide ample evidence for an invisible and dominant mass component. This so-called dark matter could be made of new, colour and charge neutral particles, which were non-relativistic when they decoupled from ordinary matter in the early universe. Such weakly interacting massive particles (WIMPs) are predicted to have a non-zero coupling to baryons and could be detected via their collisions with atomic nuclei in ultra-low background, deep underground detectors. Among these, detectors based on liquefied noble gases have demonstrated tremendous discovery potential over the last decade. After briefly introducing the phenomenology of direct dark matter detection, I will review the main properties of liquefied argon and xenon as WIMP targets and discuss sources of background. I will then describe existing and planned argon and xenon detectors that employ the so-called single- and dual-phase detection techniques, addressing their complementarity and science reach.

Laura Baudis

2014-08-19T23:59:59.000Z

278

Trace gases, CO2, climate, and the greenhouse effect  

Science Journals Connector (OSTI)

Weather is driven by the sunĺs energy input and the difference between insolation per unit area of the poles and the equator. The energy flux of the Earth is in long?term balanceŚas much is radiated away by the Earth as is absorbed or the mean temperature would have to increase or decrease steadily (and of course this is not observed). CO2 and other ĹĹtrace gasesĺĺ can cause the Earthĺs mean temperature to rise through the Greenhouse Effect. The mean temperature in the Little Ice Age was only 1?░C cooler but large effects were felt especially toward the poles. The CO2 which stays in the atmosphere will raise Earthĺs mean temperature with effects which are relatively certain: a lot of warming at the poles and a very small amount of warming at the equator.

Gordon J. Aubrecht II

1988-01-01T23:59:59.000Z

279

Highly polarized Fermi gases across a narrow Feshbach resonance  

Science Journals Connector (OSTI)

We address the phase of a highly polarized Fermi gases across a narrow Feshbach resonance starting from the problem of a single down-spin fermion immersed in a Fermi sea of up spins. Both polaron and pairing states are considered using the variational wave function approach, and we find that the polaron-to-pairing transition will take place on the BCS side of the resonance, strongly in contrast to a wide resonance where the transition is located at the BEC side. For the pairing phase, we find the critical strength of the repulsive interaction between pairs above which the mixture of pairs and fermions will not phase separate. Therefore, nearby a narrow resonance, it is quite likely that magnetism can coexist with s-wave BCS superfluidity at large Zeeman fields, which is a remarkable property absent in conventional BCS superconductors (or fermion-pair superfluids).

Ran Qi and Hui Zhai

2012-04-13T23:59:59.000Z

280

Finite-size energy of non-interacting Fermi gases  

E-Print Network [OSTI]

We prove the asymptotics of the difference of the ground-state energies of two non-interacting $N$-particle Fermi gases on the half line of length $L$ in the thermodynamic limit up to order $1/L$. We are particularly interested in subdominant terms proportional to $1/L$, called finite-size energy. In the nineties Affleck and co-authors [Aff97, ZA97, AL94] claimed that the finite-size energy equals the decay exponent occuring in Anderson's orthogonality catastrophe. It turns out that the finite-size energy depends on the details of the thermodynamic limit and typically also includes a linear term in the scattering phase shift.

Martin Gebert

2014-06-14T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Granular Gases of Rod-Shaped Grains in Microgravity  

Science Journals Connector (OSTI)

Granular gases are convenient model systems to investigate the statistical physics of nonequilibrium systems. In the literature, one finds numerous theoretical predictions, but only few experiments. We study a weakly excited dilute gas of rods, confined in a cuboid container in microgravity during a suborbital rocket flight. With respect to a gas of spherical grains at comparable filling fraction, the mean free path is considerably reduced. This guarantees a dominance of grain-grain collisions over grain-wall collisions. No clustering was observed, unlike in similar experiments with spherical grains. Rod positions and orientations were determined and tracked. Translational and rotational velocity distributions are non-Gaussian. Equipartition of kinetic energy between translations and rotations is violated.

K. Harth; U. Kornek; T. Trittel; U. Strachauer; S. H÷me; K. Will; R. Stannarius

2013-04-02T23:59:59.000Z

282

Carrier cooling and exciton formation in GaSe  

Science Journals Connector (OSTI)

The initial cooling of hot carriers and the subsequent exciton formation in GaSe are studied by time-resolved photoluminescence (PL) using femtosecond up-conversion techniques. From the time-resolved PL spectra of this layered III-VI semiconductor two different energy relaxation channels are derived. After an initial subpicosecond cooling due to Fr÷hlich-type interaction of carriers with longitudinal optical E?(22) phonons a slower regime follows, which is dominated by deformation potential interaction with the nonpolar optical A1?(12) phonons. The coupling constant for nonpolar optical phonon scattering is derived. The subsequent formation of excitons is studied at different carrier densities and detection energies. A cross section for the free-exciton formation is determined based on a rate equation model.

S. NŘsse; P. Haring Bolivar; H. Kurz; V. Klimov; F. Levy

1997-08-15T23:59:59.000Z

283

Kovacs-like memory effect in driven granular gases  

E-Print Network [OSTI]

While memory effects have been reported for dense enough disordered systems such as glasses, we show here by a combination of analytical and simulation techniques that they are also intrinsic to the dynamics of dilute granular gases. By means of a certain driving protocol, we prepare the gas in a state where the granular temperature $T$ coincides with its long time limit. However, $T$ does not subsequently remain constant, but exhibits a non-monotonic evolution before reaching its non-equilibrium steady value. The corresponding so-called Kovacs hump displays a normal behavior for weak dissipation (as observed in molecular systems), but is reversed under strong dissipation, where it thus becomes anomalous.

A. Prados; E. Trizac

2014-04-24T23:59:59.000Z

284

Greenhouse Gases, Regulated Emissions, and Energy Use in Transportatio...  

Open Energy Info (EERE)

and Energy Use in Transportation (GREET) Model AgencyCompany Organization: Argonne National Laboratory Focus Area: GHG Inventory Development Topics: Analysis Tools...

285

Organic geochemistry and organic petrography  

SciTech Connect (OSTI)

The Vermillion Creek coals and shales contain dominantly humic organic matter originating from woody plant tissues except for one shale unit above the coals, which contains hydrogen-rich kerogen that is mostly remains of filamentous algae, of likely lacustrine origin. The coals have two unusual features - very low inertinite content and high sulfur content compared to mined western coals. However, neither of these features points to the limnic setting reported for the Vermillion Creek sequence. The vitrinite reflectance of Vermillion Creek shales is markedly lower than that of the coals and is inversely proportional to the H/C ratio of the shales. Rock-Eval pyrolysis results, analyses of H, C, and N, petrographic observations, isotope composition of organic carbon, and amounts and compositions of the CHCl/sub 3/-extractable organic matter all suggest mixtures of two types of organic matter in the Vermillion Creek coals and clay shales: (1) isotopically heavy, hydrogen-deficient, terrestrial organic matter, as was found in the coals, and (2) isotopically light, hydrogen-rich organic matter similar to that found in one of the clay-shale samples. The different compositions of the Vermillion Creek coal, the unnamed Williams Fork Formation coals, and coals from the Middle Pennsylvanian Marmaton and Cherokee Groups are apparently caused by differences in original plant composition, alteration of organic matter related to different pH conditions of the peat swamps, and slightly different organic maturation levels.

Bostick, N.H.; Hatch, J.R.; Daws, T.A.; Love, A.H.; Lubeck, S.C.M.; Threlkeld, C.N.

1987-01-01T23:59:59.000Z

286

Controlling uranium reactivity March 18, 2008  

E-Print Network [OSTI]

for the last decade. Most of their work involves depleted uranium, a more common form of uraniumMarch 2008 Controlling uranium reactivity March 18, 2008 Uranium is an often misunderstood metal uranium research. In reality, uranium presents a wealth of possibilities for funda- mental chemistry. Many

Meyer, Karsten

287

Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 1, Main text  

SciTech Connect (OSTI)

This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO{sub 2}), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO{sub 2}-equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO{sub 2}-equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles.

DeLuchi, M.A. [California Univ., Davis, CA (United States)

1991-11-01T23:59:59.000Z

288

Theory of the lattice Boltzmann method: Lattice Boltzmann models for nonideal gases Li-Shi Luo*  

E-Print Network [OSTI]

Theory of the lattice Boltzmann method: Lattice Boltzmann models for nonideal gases Li-Shi Luo is presented. This treat- ment provides a unified theory of lattice Boltzmann models for nonideal gases. The lattice Boltzmann equation is systematically obtained by discretizing the Enskog equation in phase space

Luo, Li-Shi

289

Preserving noble gases in a convecting mantle Helge M. Gonnermann1  

E-Print Network [OSTI]

of a processed and out- gassed lower-mantle source, residues of mantle melting10,11 , depleted in uranium and mixing of noble-gas-depleted slabs dilutes the concentrations of noble gases in the mantle, thereby melt, which forms the ocean crust and leaves the residual mantle severely depleted of noble gases

Mukhopadhyay, Sujoy

290

Helium Isotopes In Geothermal And Volcanic Gases Of The Western United  

Open Energy Info (EERE)

Helium Isotopes In Geothermal And Volcanic Gases Of The Western United Helium Isotopes In Geothermal And Volcanic Gases Of The Western United States, I, Regional Variability And Magmatic Origin Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Helium Isotopes In Geothermal And Volcanic Gases Of The Western United States, I, Regional Variability And Magmatic Origin Details Activities (1) Areas (1) Regions (0) Abstract: Helium isotope ratios in gases of thirty hot springs and geothermal wells and of five natural gas wells in the western United States show no relationship to regional conductive heat flow, but do show a correlation with magma-based thermal activity and reservoir fluid temperature (or total convective heat discharge). Gases from high-T (> 200┬░C) reservoirs have 3He/4He > 2 _ the atmospheric value, with high He

291

Cell Comp't Thermal Reactivity & Improvements | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Comp't Thermal Reactivity & Improvements Cell Comp't Thermal Reactivity & Improvements Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on...

292

Isotope effects in methanol synthesis and the reactivity of copper...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

293

Design of processes with reactive distillation line diagrams  

SciTech Connect (OSTI)

On the basis of the transformation of concentration coordinates, the concept of reactive distillation lines is developed. It is applied to study the feasibility of a reactive distillation with an equilibrium reaction on all trays of a distillation column. The singular points in the distillation line diagrams are characterized in terms of nodes and saddles. Depending on the characterization of the reactive distillation line diagrams, it can be decided whether a column with two feed stages is required. On the basis of the reaction space concept, a procedure for identification of reactive distillation processes is developed, in which the reactive distillation column has to be divided into reactive and nonreactive sections. This can be necessary to overcome the limitations in separation which result from the chemical equilibrium. The concentration profile of this combined reactive/nonreactive distillation column is estimated using combined reactive/nonreactive distillation lines.

Bessling, B. [BASF Ludwigshafen (Germany). Engineering Research and Development] [BASF Ludwigshafen (Germany). Engineering Research and Development; Schembecker, G.; Simmrock, K.H. [Univ. of Dortmund (Germany). Dept. of Chemical Engineering] [Univ. of Dortmund (Germany). Dept. of Chemical Engineering

1997-08-01T23:59:59.000Z

294

Use of hollow core fibers, fiber lasers, and photonic crystal fibers for spark delivery and laser ignition in gases  

Science Journals Connector (OSTI)

The fiber-optic delivery of sparks in gases is challenging as the output beam must be refocused to high

Joshi, Sachin; Yalin, Azer P; Galvanauskas, Almantas

2007-01-01T23:59:59.000Z

295

Reactivity control assembly for nuclear reactor. [LMFBR  

DOE Patents [OSTI]

This invention, which resulted from a contact with the United States Department of Energy, relates to a control mechanism for a nuclear reactor and, more particularly, to an assembly for selectively shifting different numbers of reactivity modifying rods into and out of the core of a nuclear reactor. It has been proposed heretofore to control the reactivity of a breeder reactor by varying the depth of insertion of control rods (e.g., rods containing a fertile material such as ThO/sub 2/) in the core of the reactor, thereby varying the amount of neutron-thermalizing coolant and the amount of neutron-capturing material in the core. This invention relates to a mechanism which can advantageously be used in this type of reactor control system.

Bollinger, L.R.

1982-03-17T23:59:59.000Z

296

Mined land reclamation by biological reactivation  

SciTech Connect (OSTI)

A mine reclamation technique, developed in Europe, restores land to full productivity within two years without topsoil replacement. The method deliberately reestablishes within one year following mining, the required biological balance between microbes, enzymes, and trace elements in the rock spoil rather than waiting five or more years for natural processes to restore balance. The technique is called Biological Reactivation (BR). This paper discusses the feasibility of BR reclamation after surface mining operations in the US. Staff of the Ohio Mining and Mineral Resources Research Institute completed an OSM-sponsored research project on BR in which physical and chemical tests characterized 140 spoil samples obtained from 10 surface mining operations. Test results indicated that Biological Reactivation technology could be effectively applied, at least in the test areas sampled within Appalachia. Preliminary estimates make clear that the new technique reduces reclamation costs on prime farmland by approximately 95% compared to topsoil segregation and replacement methods.

Gozon, J.S.; Konya, C.J.; Lukovic, S.S.; Lundquist, R.G.; Olah, J.

1982-12-01T23:59:59.000Z

297

Rapid?sampling system for dusts and gases  

Science Journals Connector (OSTI)

The Bureau of Mines has developed a system for the rapid grab sampling of heterogeneous mixtures of gases and dusts during the preignition and postignition stages of dust explosions. The combustion chamber in which the explosion occurs is first fitted with a hypodermic sampling needle with its inlet end at the desired sampling point within the chamber and its sharp injecting end protruding outside of the chamber. Rapid sampling (approximately 25 to 50 ms) is achieved with a double?acting air?pressure?actuated cylinder. The forward stroke of the cylinder thrusts the rubber septum seal of an evacuated glass sampling tube onto the protruding needle which punctures the septum filling the tube with gas and dust from the combustion chamber. The return stroke of the cylinder reseals the sampling tube by returning the mechanism to its original position. The initial time of sampling and the duration of sampling are independently variable and controlled by a microprocessor. Results obtained with a trimodal distribution of coal dust show no significant size discrimination at least up to 70 ?m. Data obtained from laboratory?scale coal dust explosion tests are also presented. Such data provide valuable insights into the basic phenomena involved in explosions.

R. S. Conti; M. Hertzberg; F. T. Duda; K. L. Cashdollar

1983-01-01T23:59:59.000Z

298

Reactive barrier technologies for treatment of contaminated groundwater at Rocky Flats  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) Office of Science and Technology Subsurface Contaminants Focus Area is supporting the investigation of reactive barrier technologies to mitigate the risks associated with mixed organic/radioactive waste at several DOE sites. Groundwater from a small contaminated plume at the Rocky Flats Environmental Technology Site (RFETS) is being used to evaluate passive reactive material treatment. Permeable reactive barriers which intercept contaminants and destroy the VOC component while containing radionuclides are attractive for a number of reasons relating to public and regulatory acceptance. In situ treatment keeps contaminants away from the earth`s surface, there is no above-ground treatment equipment that could expose workers and the public and operational costs are expected to be lower than currently used technologies. This paper will present results from preliminary site characterization and in-field small-scale column testing of reactive materials at RFETS. Successful demonstration is expected to lead to full-scale implementation of the technology at several DOE sites, including Rocky Flats.

Marozas, D.C.; Bujewski, G.E. [Sandia National Labs., Albuquerque, NM (United States); Castaneda, N. [Rocky Flats Field Office, Golden, CO (United States)

1997-12-31T23:59:59.000Z

299

Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

300

Gases as Working Fluid in Parabolic Trough CSP Plants  

Science Journals Connector (OSTI)

Abstract The energetic dimension of actual economy is massively oriented towards the use of fossil fuels: they cover a share of 87% of the energy needs and the trend of this share is increasing, in spite of the commitments adopted by almost all the Countries in the World. Most crucial concern is CO2 levels in the atmosphere and the positive feedback between Earth's temperature increase and carbon. Actual technologies which make use of renewable sources seem to be not fully suitable to invert this continuous increase of fossil fuels. Concentrated Solar Power plants (CSP) have had, recently, a huge attention as a technology able to give, in the mean future, a strong contribution to the electrical energy generation. CSP technology has an intrinsic superiority with respect to the other renewable plants but actual plants suffer of many drawbacks which slow down a massive diffusion: these aspects increase costs and do not insure the reliability levels required to make the investments profitable. Gas as heat transfer fluid inside solar receiver in a CSP Parabolic Trough (PT) type plant is discussed in this paper: this would simplify actual technology in the conversion section, downstream the solar energy collecting phase. The use of gases calls for a new conversion section discussed in this paper based on a direct expansion in gas turbine plants. The success of this concept is related to the possibility to increase the fluid (gas) temperature above the actual operating maximum values. The paper discusses the performances of a new gas cycle, the performances of actual receivers when fed with gas and introduces and discusses an optimization design parameter which allows a cost decrease and industrial reliability improvement.

Roberto Cipollone; Andrea Cinocca; Angelo Gualtieri

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

On surface temperature, greenhouse gases, and aerosols: models and observations  

SciTech Connect (OSTI)

The effect of changes in atmospheric carbon dioxide concentrations and sulphate aerosols on near-surface temperature is investigated using a version of the Hadley Centre atmospheric model coupled to a mixed layer ocean. The scattering of sunlight by sulphate aerosols is represented by appropriately enhancing the surface albedo. On doubling atmospheric carbon dioxide concentrations, the global mean temperature increases by 5.2 K. An integration with a 39% increase in CO{sub 2}, giving the estimated change in radiative heating due to increases in greenhouse gases since 1900, produced an equilibrium warming of 2.3 K, which, even allowing for oceanic inertia, is significantly higher than the observed warming over the same period. Furthermore, the simulation suggests a substantial warming everywhere, whereas the observations indicate isolated regions of cooling, including parts of the northern midlatitude continents. The addition of an estimate of the effect of scattering by current industrial aerosols (uncertain by a factor of at least 3) leads to improved agreement with the observed pattern of changes over the northern continents and reduces the global mean warming by about 30%. Doubling the aerosol forcing produces patterns that are still compatible with the observations, but further increase leads to unrealistically extensive cooling in the midlatitudes. The diurnal range of surface temperature decreases over most of the northern extratropics on increasing CO{sub 2}, in agreement with recent observations. The addition of the current industrial aerosol had little detectable effect on the diurnal range in the model because the direct effect of reduced solar heating at the surface is approximately balanced by the indirect effects of cooling. Thus, the ratio of the reduction in diurnal range to the mean warming is increased, in closer agreement with observations. Results from further sensitivity experiments with larger increases in aerosol and CO{sub 2} are presented.

Mitchell, J.F.B.; Davis, R.A.; Ingram, W.J.; Senior, C.A. [Hadley Centre for Climate Prediction and Research, Berkshire (United Kingdom)] [Hadley Centre for Climate Prediction and Research, Berkshire (United Kingdom)

1995-10-01T23:59:59.000Z

302

Excitation spectrum and quasiparticles in quantum gases. A rigorous approach  

E-Print Network [OSTI]

This thesis is devoted to a rigorous study of interacting quantum gases. The main objects of interest are the closely related concepts of excitation spectrum and quasiparticles. The immediate motivation of this work is to propose a spectral point of view concerning these two concepts. In the first part of this thesis we discuss the concepts of excitation spectrum and quasiparticles. We provide an overview of physical motivations and based on that we propose a spectral and Hamiltonian-based approach towards these terms. Based on that, we formulate definitions and propositions related to these concepts. In the second part we recall the Bogoliubov and Hartree-Fock-Bogoliubov approximations, which in the physics literature are used to obtain the quasiparticle picture. We show how these two approaches fit into a universal scheme which allows us to arrive at a quasiparticle picture in a more general setup. This scheme is based on the minimization of Hamiltonians over the so-called Gaussian states. Its abstract formulation is the content of Beliaev's Theorem. In the last part we present a rigorous result concerning the justification of the Bogoliubov approximation. This justification employs the concept of the mean-field and infinite-volume limit. We show that for a large number of particles, a large volume and a sufficiently high density, the low-lying energy-momentum spectrum of the homogeneous Bose gas is well described by the Bogoliubov approximation. This result, which is formulated in the form of a theorem, can be seen as the main result of this thesis.

Marcin Napiˇrkowski

2014-09-02T23:59:59.000Z

303

Measurement of the atmospheric reactivity of emissions from gasoline and alternative-fueled vehicles: Assessment of available methodologies. Part 1. Indoor smog chamber study of reactivity. Final report for the first year, January 1-December 31, 1993  

SciTech Connect (OSTI)

A set of multiple indoor smog chambers were used to measure the increase in smog formation (smog = NO oxidation + O3 formation) from a series of individual test volatile organic compounds (VOC`s), as well as carbon monoxide (CO), when they were added to a standard urban mixture and irradiated for 10-12 hours with a solar simulator. The chambers and the mixtures were designed to simulate the Carter incremental reactivity concept that is being used in California. The test compounds covered a wide range of mechanistic uncertainties and predicted reactivities (reactivity is the increase in smog divided by the amount of test compound added). Also, the chambers were used to test the recently developed Integrated Empirical Rate (IER) Model which predicts that the smog formation of a mixture is constant and independent of NOx in the so-called light-limited regime.

Kelly, N.A.; Wang, P.; Japar, S.M.; Hurley, M.D.; Wallington, T.J.

1994-06-30T23:59:59.000Z

304

Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley  

Open Energy Info (EERE)

Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999) Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999) Abstract This report tabulates an extensive geochemical database on waters, gases, scales,rocks, and hot-spring deposits from the Dixie Valley region, Nevada. The samples fromwhich the data were obtained were collected and analyzed during 1996 to 1999. Thesedata provide useful information for ongoing and future investigations on geothermalenergy, volcanism, ore deposits, environmental issues, and groundwater quality in thisregion. Authors Los Alamos National Laboratory and NM Published

305

Intensive Sampling Of Noble Gases In Fluids At Yellowstone- I, Early  

Open Energy Info (EERE)

Intensive Sampling Of Noble Gases In Fluids At Yellowstone- I, Early Intensive Sampling Of Noble Gases In Fluids At Yellowstone- I, Early Overview Of The Data, Regional Patterns Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Intensive Sampling Of Noble Gases In Fluids At Yellowstone- I, Early Overview Of The Data, Regional Patterns Details Activities (1) Areas (1) Regions (0) Abstract: The Roving Automated Rare Gas Analysis (RARGA) lab of Berkeley's Physics Department was deployed in Yellowstone National Park for a 19 week period commencing in June, 1983. During this time 66 gas and water samples representing 19 different regions of hydrothermal activity within and around the Yellowstone caldera were analyzed on site. Routinely, the abundances of five stable noble gases and the isotopic compositions of He,

306

Clarifying the Roles of Greenhouse Gases and ENSO in Recent Global Warming through Their Prediction Performance  

Science Journals Connector (OSTI)

It is well known that natural external forcings and decadal-to-millennial variability drove changes in the climate system throughout the Holocene. Regarding recent times, attribution studies have shown that greenhouse gases (GHGs) determined the ...

Umberto Triacca; Antonello Pasini; Alessandro Attanasio; Alessandro Giovannelli; Marco Lippi

2014-10-01T23:59:59.000Z

307

Eddy covariance flux measurements of pollutant gases in urban Mexico City  

E-Print Network [OSTI]

Eddy covariance (EC) flux measurements of the atmosphere/surface exchange of gases over an urban area are a direct way to improve and evaluate emissions inventories, and, in turn, to better understand urban atmospheric ...

Velasco, Erik

308

Characteristic parameters of geigermŘller counter gases. Propane-argon and propane-helium mixtures  

Science Journals Connector (OSTI)

The combination of the Wilkinson and the Diethorn-Kohman expressions of counter operation was tested under conditions in which different rare gases were used with the same quench gas as Geiger-MŘller counter f...

Richard G. Pannbacker; Robert W. Kiser

1962-02-01T23:59:59.000Z

309

Cosmogenic and trapped rare gases in Luna-24 drill core samples  

Science Journals Connector (OSTI)

The elemental and isotopic composition of noble gases in six samples from different depths of the Luna-24 drill core soil column, obtained by mass spectrometric analyses, are presented and the results are comp...

J. T. Padia; M. N. Rao; T. R. Venkatesan

1979-06-01T23:59:59.000Z

310

Adsorption Modeling of Coalbed Gases and the Effects of Water on Their Adsorption Behavior.  

E-Print Network [OSTI]

??The simplified local-density/Peng-Robinson (SLD-PR) adsorption model was utilized to investigate the adsorption behavior of coalbed gases on coals of varying rank. The model parameters wereů (more)

Mohammad, Sayeed Ahmed

2009-01-01T23:59:59.000Z

311

Quantifying emissions of greenhouse gases from South Asia through a targeted measurement campaign  

E-Print Network [OSTI]

Methane (CH 4 ), nitrous oxide (N20) and sulfur hexafluoride (SF6) are powerful greenhouse gases with global budgets that are well-known but regional distributions that are not adequately constrained for the purposes of ...

Ganesan, Anita Lakshmi

2013-01-01T23:59:59.000Z

312

Load Preheating Using Flue Gases from a Fuel-Fired Heating System  

Broader source: Energy.gov [DOE]

This tip sheet discusses how the thermal efficiency of a process heating system can be improved significantly by using heat contained in furnace flue gases to preheat the furnace load.

313

Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases  

DOE Patents [OSTI]

An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

Natesan, K.

1992-11-17T23:59:59.000Z

314

Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases  

DOE Patents [OSTI]

An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

Natesan, Krishnamurti (Naperville, IL)

1992-01-01T23:59:59.000Z

315

Factors affecting the recovery of petroleum in projects involving the injection of liquefied petroleum gases (LPG)  

E-Print Network [OSTI]

FACTORS AFFECTING THE RECOVERY OF PETROLEUM IN PROJECTS INVOLVING THE INJECTION OF LIQUEFIED PETROLEUM GASES (LPG) A Thesis By GERRY A. GRAHAM Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE August, 1961 Major Subject: Petroleum Engineering GERRY A. GRAHAM FACTORS AFFECTING THE RECOVERY OF PETROLEUM IN PROJECTS INVOLVING THE INJECTION OF LIQUEFIED PETROLEUM GASES (LPG) A...

Graham, Gerry A

2012-06-07T23:59:59.000Z

316

Theoretical study of the electrical power behavior of a cesium thermionic converter for switching resistive and reactive loads  

SciTech Connect (OSTI)

Pulsed ionized diodes have shown to be an attractive mode to develop thermionic converters. Usually the investigations have been focused to work with additive gases and constant loads at steady state. The experimental transient graphs reported suggest a dynamic behavior of the thermionic converter. Periods of the order of 300 {micro}s have been reported for the decay time of voltage and current, a condition that is similar to a capacitive discharge. A circuit model for a thermionic converter to define this condition is proposed. Using this model, an electrical analysis of the thermionic converter power with different switching loads is made. Both, resistive and reactive loads are connected. Special emphasis is dedicated to determine the resonance frequencies.

Perez, J.G. [ICUAP-BUAP, Puebla (Mexico). Semiconductor Devices Research Center; Estrada, C.A.; Jimenez, A.E.; Cervantes, J.G. [UNAM, Temixco (Mexico). Energy Research Center

1997-12-31T23:59:59.000Z

317

Reactive sticking coefficients of silane on silicon  

SciTech Connect (OSTI)

Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition rate measurements using molecular beam scattering and a very low pressure cold wall reactor. The RSCs have non-Arrhenius temperature dependences and decreases with increasing flux at low (710/sup 0/) temperatures. A simple model involving dissociative adsorption of silane is consistent with these results. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1988-09-15T23:59:59.000Z

318

Cellular-automaton model for reactive systems  

Science Journals Connector (OSTI)

A method for constructing a variety of probabilistic lattice-gas cellular automata for chemically reacting systems is described. The microscopic reactive dynamics give rise to a general fourth-order polynomial rate law for the average particle density. The reduction of the microdynamical equations to a discrete or continuous Boltzmann equation is presented. Connection between the linearized Boltzmann equations and a reaction-diffusion macroscopic equation is discussed. As an example of the general formalism a set of cellular automata rules that yield the Schl÷gl phenomenological model is constructed. Simulation results are presented.

David Dab; Anna Lawniczak; Jean-Pierre Boon; Raymond Kapral

1990-05-14T23:59:59.000Z

319

Theoretical and Experimental Evaluation of Chemical Reactivity  

E-Print Network [OSTI]

released and the rate of energy released for a specific reactive chemical. 2.1 DSC DSC is a popular screening tool (safe and fast) and can provide an overall indication of exothermic activity of the chemical being tested. In a DSC, a sample and a... endothermic or exothermic reaction. When the rate of heat generation in the sample exceeds a particular value, the heat supply to the sample is cut off and this additional heat gain is attributed to exothermic activity within the sample.17 From the DSC...

Wang, Qingsheng

2011-10-21T23:59:59.000Z

320

Preparation of reactive beta-dicalcium silicate  

DOE Patents [OSTI]

This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane and hydrogen, at a temperature of about 850.degree.-1000.degree. C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

Shen, Ming-Shing (Laramie, WY, NJ); Chen, James M. (Rahway, NJ); Yang, Ralph T. (Amherst, NY)

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 ``Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core`` problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-12-01T23:59:59.000Z

322

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core'' problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-01-01T23:59:59.000Z

323

Electrochemical cell for the detection of noxious gases  

SciTech Connect (OSTI)

An electrochemical cell for quantitatively detecting ethylene oxide is described comprising: (a) a first working electrode comprising gas diffusion membrane having bonded thereto a catalytic portion electrochemically reactive with ethylene oxide; (b) a second working electrode having electrochemical activity with oxidation/reduction products produced at the first working electrode; (c) a counter electrode; (d) a reference electrode; (e) an electrolyte in contact with the catalytic portion of the first working electrode and in contact with the second working, counter and reference electrodes; (f) means for containing the electrolyte and the first and second working electrodes; (g) means for maintaining a fixed potential on the first working electrode relative to the reference electrode of from above 1.0 to about 1.8 volts with respect to the potential of the reversible hydrogen couple in the electrolyte of the cell; and (h) means for maintaining a fixed potential on the second working electrode relative to the reference electrode of from about 1.0 to 2.2 volts with respect to the potential of the reversible hydrogen couple in the electrolyte of the cell.

Schneider, A.A.; Stewart, D.A.; Jolson, J.D.; Auel, R.M.; Price, J.F.

1987-11-17T23:59:59.000Z

324

What CO2 well gases tell us about the origin of noble gases in the mantle and their relationship to the atmosphere  

Science Journals Connector (OSTI)

...mantle-rich CO2 well gases, with samples lying on the air-solar mixing line. The most solar-rich gas, from Bravo Dome in New Mexico, had a 10 per cent excess above air value. Since solar and Q-Xe are so similar in composition, it is not possible...

2008-01-01T23:59:59.000Z

325

Fast non-explosive gases for drift chambers  

SciTech Connect (OSTI)

Typical gases which are stock at Fermilab are Ar:C/sub 2/H/sub 6/(50:50) and Ar:CO/sub 2/ (80:20). Argon:Ethane has the virtue of high gas gain and a saturated drift velocity. In fact, parametrizing the drift velocity as a function of electric field we find v/sub d/(E) = v/sub o/(1/minus/e/sup -E/E/o) with v/sub o/ approx. = 5.4 cm/..mu..sec and E/sub o/ = 160 V/cm. However, safety considerations make this gas somewhat inconvenient. The addition of alcohol as quencher also raises the saturation field to, for example, E/sub o/ approx. = 500 V/cm for 1.5% added alcohol. This gas also tends to break up in a high-beam flux environment and leave carbon deposits. The addition of alcohol to avoid such aging often takes a unit cell out of saturation over its entire volume. Finally, for collider applications it is useful to exclude free protons from the gas in order to reduce the sensitivity to the sea of slow neutrons which are present in the collider environment. In contrast, Ar:CO/sub 2/ (80:20) is a gas with more moderate gas gain. The drift velocity at high field is v/sub d/(E > 1.5 kV/cm) approx. = 5.8 cm/..mu..sec. For most field configurations this gas does not saturate, causing a long tail in the drift time distrubtion due to low field regions in the unit cell. The virtues of this gas mixture are that it is cheap, not flammable, and stable under high-beam flux. However as the Collider Upgrade progresses, we wish to find a gas which is faster than 5.0 cm/..mu..sec since the time separation between collisions will at some point be less than drift time of 1..mu..sec for drift distance of 5 cm. 3 refs., 5 figs.

Green, D.; Haggerty, H.; Oshima, N.; Yamada, R.

1988-05-01T23:59:59.000Z

326

A Theory of the Electric Discharge Through Gases  

Science Journals Connector (OSTI)

Three general differential equations are set up which determine the average behavior of a discharge of electricity through a gas. Approximate solutions, giving the electric field E and the concentration of electrons and positive ions, n1 and n2, at any distance x from the cathode, are found for several ranges of value of E.When E is large, the solution corresponds to the conditions in the cathode and anode fall spaces in a glow discharge. Equations are obtained for the potential drop V across the fall space; the current density at the electrode divided by the square of the gas pressure, jp2; and the thickness of the fall space times the pressure, pd.These equations indicate that for the cathode fall space there is a certain minimum value of V, called Vn; and for jp2, called jnp2; and a corresponding maximum value of pd, pdn, beyond which values the discharge ceases. These stationary values are shown to be constants, dependent only on the nature of the gas used and of the cathode material, and correspond to the normal cathode fall space. The equation determining Vn is shown to be of the right from by comparison with the experimentally determined values. From these values of Vn, values of jnp2 and of pdn are calculated for four gases and four cathode materials, and the calculated values check with the experimental data. The corresponding equations for the anode fall space show why there is no corresponding normal anode fall.A consideration of the discharge when E is large throughout the distance between electrodes indicates that there is another stationary value of the cathode fall space when the current density at the cathode reaches its maximum possible value. The V in this case is much smaller than the Vn for the glow discharge, and the form of the equations indicate that they describe the conditions in an electric arc.Another approximate equation is obtained when E is constant, which is the case in the positive column of a glow discharge. This solution indicates that within certain limits of pressure and current density, small sinusoidal variations about the average value Ep, are possible in E. These correspond to the striations sometimes observed in the positive column. The equations determining Ep and those determining the distance between striations check with the known empirical laws relating these amounts to the pressure, the radius of the discharge tube and the critical potentials of the gas used. A general discussion is given of the Faraday dark space and reasons are given why it should be near the cathode rather than the anode.

Philip M. Morse

1928-06-01T23:59:59.000Z

327

PHASE BEHAVIOR OF LIGHT GASES IN HYDROCARBON AND AQUEOUS SOLVENTS  

SciTech Connect (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present period, the Park-Gasem-Robinson (PGR) equation of state (EOS) has been modified to improve its volumetric and equilibrium predictions. Specifically, the attractive term of the PGR equation was modified to enhance the flexibility of the model, and a new expression was developed for the temperature dependence of the attractive term in this segment-segment interaction model. The predictive capability of the modified PGR EOS for vapor pressure, and saturated liquid and vapor densities was evaluated for selected normal paraffins, normal alkenes, cyclo-paraffins, light aromatics, argon, carbon dioxide and water. The generalized EOS constants and substance-specific characteristic parameters in the modified PGR EOS were obtained from the pure component vapor pressures, and saturated liquid and vapor molar volumes. The calculated phase properties were compared to those of the Peng-Robinson (PR), the simplified-perturbed-hard-chain theory (SPHCT) and the original PGR equations. Generally, the performance of the proposed EOS was better than the PR, SPHCT and original PGR equations in predicting the pure fluid properties (%AAD of 1.3, 2.8 and 3.7 for vapor pressure, saturated liquid and vapor densities, respectively).

KHALED A.M. GASEM; ROBERT L. ROBINSON, JR.

1998-08-31T23:59:59.000Z

328

Atmospheric reactivity of gaseous dimethyl sulfate  

SciTech Connect (OSTI)

The atmospheric reactivity of dimethyl sulfate (DMS) with a series of atmospheric species has been investigated. Upper limits to the rate constants for the homogeneous gas-phase reactions of DMS with O{sub 3}, NH{sub 3}, and H{sub 2}O have been determined by using FTIR spectroscopy and are <1.4 {times} 10{sup {minus}21}, <1.5 {times} 10{sup {minus}21}, and <1.1 {times} 10{sup {minus}23} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. The reactivity of DMS toward ON radicals and Cl atoms has been determined by using relative rate techniques, and the rate constants for those reactions are <5 {times} 10{sup {minus}13} and (4.2 {plus minus} 0.5) {times} 10{sup {minus}13} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. These rate constants correspond to atmospheric lifetimes ranging from >23 days with respect to reaction with OH radicals to >33 years with respect to reaction with ozone. With the possible exception of its reaction with water, for which the calculated lifetime of DMS is >2 days, these results indicate that the atmospheric fate of DMS is not determined by its homogeneous gas-phase reactions with any of the atmosphere species studied.

Japar, S.M.; Wallington, T.J.; Andino, J.M.; Ball, J.C. (Ford Motor Co., Dearborn, MI (USA))

1990-03-01T23:59:59.000Z

329

Installation of reactive metals groundwater collection and treatment systems  

SciTech Connect (OSTI)

Three groundwater plumes contaminated with volatile organic compounds (VOCs) and radionuclides at the Rocky Flats Environmental Technology Site are scheduled for remediation by 1999 based on the Rocky Flats Cleanup Agreement (RFCA) (DOE, 1996). These three plumes are among the top 20 environmental cleanup sites at Rocky Flats. One of these plumes, the Mound Site Plume, is derived from a previous drum storage area, and daylights as seeps near the South Walnut Creek drainage. Final design for remediation of the Mound Site Plume has been completed based on use of reactive metals to treat the contaminated groundwater, and construction is scheduled for early 1998. The two other plumes, the 903 Pad/Ryan`s Pit and the East Trenches Plumes, are derived from VOCs either from drums that leaked or that were disposed of in trenches. These two plumes are undergoing characterization and conceptual design in 1998 and construction is scheduled in 1999. The contaminants of concern in these plumes are tetrachloroethene, trichloroethene, carbon tetrachloride and low levels of uranium and americium.

Hopkins, J.K.; Primrose, A.L. [Rocky Mountain Remediation Services, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site; Vogan, J. [EnviroMetal Technologies, Inc., Guelph, Ontario (Canada); Uhland, J. [Kaiser-Hill, LLC, Golden, CO (United States). Rocky Flats Environmental Technology Site

1998-07-01T23:59:59.000Z

330

Measurement of VOC reactivities using a photochemical flow reactor  

SciTech Connect (OSTI)

A commercial ambient air monitoring instrument, the Airtrak 2000, has been modified for use as a photochemical flow reactor and used to measure the absolute and incremental reactivity of 18 single test VOCs and the incremental reactivity of six multicomponent VOC mixtures. A flow technique is a useful supplement to traditional static chamber experiments. The static chamber technique involves periodic sampling of an irradiated mixture in a photochemical chamber. Under these conditions, the irradiated mixture is always in transition. Using a flow system, a steady-state condition is established within the flow reactor that is representative, in this case, of the early stages of the smog forming process in the atmosphere. The measurement technique also allows changes in the background chamber reactivity to be monitored and taken into account. The incremental reactivity of 13 of the 18 test compounds measured is compared with previously reported results from a static chamber experiment, and the two data sets are generally in good agreement. The additivity of reactivity was tested by measuring the incremental reactivity of six multicomponent mixtures, the components being compounds measured individually in this study. The measured reactivity of a mixture was compared to that calculated from the sum of the measured reactivity of the mixture`s individual components. The results show that reactivity is additive for the concentration range studied.

Hurley, M.D.; Chang, T.Y.; Japar, S.M.; Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.] [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.

1998-07-01T23:59:59.000Z

331

Reactive Dehydration technology for Production of Fuels and Chemicals...  

Broader source: Energy.gov (indexed) [DOE]

Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based chemicals from complex aqueous mixtures. SeparationPurification of Biomass...

332

Reactive Landing of Peptide Ions on Self-Assembled Monolayer...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

were characterized ex situ using time of flight-secondary ion mass spectrometry (TOF-SIMS) and infrared reflection absorption spectroscopy (IRRAS). We demonstrate that reactive...

333

Probing the structure and reactivity of gaseous ions.  

E-Print Network [OSTI]

??Studying ions in the gas phase provides the opportunity to observe their intrinsic structure and reactivity without extraneous perturbations such as solvent effects, aggregation orů (more)

Meyer, Matthew Michael

2010-01-01T23:59:59.000Z

334

Chemically Reactive Working Fluids for the Capture and Transport...  

Broader source: Energy.gov (indexed) [DOE]

Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working Fluids Low-Cost Light Weigh Thin Film Solar Concentrators...

335

Monitoring Single Molecule Reactivity On a Carbon Nanotube  

E-Print Network [OSTI]

LETTERS Monitoring Single-Molecule Reactivity on a Carbondevice directly transduces single-molecule attachments andoptical methods in single-molecule research. Compared to

Collins, Philip G

2008-01-01T23:59:59.000Z

336

Pulsed Laser Deposition of Photoresponsive Two-Dimensional GaSe Nanosheet Networks  

SciTech Connect (OSTI)

Here we explore pulsed laser deposition (PLD), a well known and versatile synthesis method principally used for epitaxial oxide thin film growth, for the synthesis of functional metal chalcogenide (GaSe) nanosheet networks by stoichiometric transfer of laser vaporized material from bulk GaSe targets in Ar background gas. Uniform coverage of interconnected, crystalline, few-layer, photoresponsive GaSe nanosheets in both in-plane and out-of-plane orientations were achieved under different ablation plume conditions over ~1.5 cm2 areas. Plume propagation was characterized by in situ ICCD-imaging. High (1 Torr) Ar background gas pressures were found to be crucial for the stoichiometric growth of GaSe nanosheet networks. Individual 1-3 layer GaSe triangular nanosheets of ~ 200 nm domain size were formed within 30 laser pulses, coalescing to form nanosheet networks in as few as 100 laser pulses. The thickness of the deposited networks increased linearly with pulse number, adding layers in a two-dimensional (2D) growth mode while maintaining a surface roughness of 2 GaSe layers for increasing overall thickness. Field effect transistors using these interconnected crystalline GaSe networks showed p-type semiconducting characteristics with mobilities reaching as high as 0.1 cm2V-1s-1. Spectrally-resolved photoresponsivities and external quantum efficiencies ranged from 0.4 AW-1 and 100% at 700 nm, to 1.4 AW-1 and 600 % at 240 nm, respectively. Pulsed laser deposition under these conditions appears to provide a versatile and rapid approach to stoichiometrically transfer and deposit photoresponsive networks of 2D nanosheets with digital thickness control and substrate-scale uniformity for a variety of applications.

Mahjouri-Samani, Masoud [ORNL; Gresback, Ryan G [ORNL; Tian, Mengkun [ORNL; Puretzky, Alexander A [ORNL; Rouleau, Christopher M [ORNL; Eres, Gyula [ORNL; Ivanov, Ilia N [ORNL; Xiao, Kai [ORNL; McGuire, Michael A [ORNL; Duscher, Gerd [University of Tennessee, Knoxville (UTK); Geohegan, David B [ORNL

2014-01-01T23:59:59.000Z

337

A BIOMASS-BASED MODEL TO ESTIMATE THE PLAUSIBILITY OF EXOPLANET BIOSIGNATURE GASES  

SciTech Connect (OSTI)

Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H{sub 2}S, CH{sub 4}, CH{sub 3}Cl, and DMS. We have applied the models to propose NH{sub 3} as a biosignature gas on a 'cold Haber World', a planet with a N{sub 2}-H{sub 2} atmosphere, and to demonstrate why gases such as CH{sub 3}Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such as CH{sub 4}, H{sub 2}S, and N{sub 2}O) produced from life that extracts energy from chemical potential energy gradients will always have false positives because geochemistry has the same gases to work with as life does, and gases (such as DMS and CH{sub 3}Cl) produced for secondary metabolic reasons are far less likely to have false positives but because of their highly specialized origin are more likely to be produced in small quantities. The biomass model estimates are valid to one or two orders of magnitude; the goal is an independent approach to testing whether a biosignature gas is plausible rather than a precise quantification of atmospheric biosignature gases and their corresponding biomasses.

Seager, S.; Bains, W.; Hu, R. [Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139 (United States)

2013-10-01T23:59:59.000Z

338

A Biomass-based Model to Estimate the Plausibility of Exoplanet Biosignature Gases  

Science Journals Connector (OSTI)

Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H2S, CH4, CH3Cl, and DMS. We have applied the models to propose NH3 as a biosignature gas on a "cold Haber World," a planet with a N2-H2 atmosphere, and to demonstrate why gases such as CH3Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such as CH4, H2S, and N2O) produced from life that extracts energy from chemical potential energy gradients will always have false positives because geochemistry has the same gases to work with as life does, and gases (such as DMS and CH3Cl) produced for secondary metabolic reasons are far less likely to have false positives but because of their highly specialized origin are more likely to be produced in small quantities. The biomass model estimates are valid to one or two orders of magnitude; the goal is an independent approach to testing whether a biosignature gas is plausible rather than a precise quantification of atmospheric biosignature gases and their corresponding biomasses.

S. Seager; W. Bains; R. Hu

2013-01-01T23:59:59.000Z

339

Waste Heat Recovery from High Temperature Off-Gases from Electric Arc Furnace  

SciTech Connect (OSTI)

This article presents a study and review of available waste heat in high temperature Electric Arc Furnace (EAF) off gases and heat recovery techniques/methods from these gases. It gives details of the quality and quantity of the sensible and chemical waste heat in typical EAF off gases, energy savings potential by recovering part of this heat, a comprehensive review of currently used waste heat recovery methods and potential for use of advanced designs to achieve a much higher level of heat recovery including scrap preheating, steam production and electric power generation. Based on our preliminary analysis, currently, for all electric arc furnaces used in the US steel industry, the energy savings potential is equivalent to approximately 31 trillion Btu per year or 32.7 peta Joules per year (approximately $182 million US dollars/year). This article describes the EAF off-gas enthalpy model developed at Oak Ridge National Laboratory (ORNL) to calculate available and recoverable heat energy for a given stream of exhaust gases coming out of one or multiple EAF furnaces. This Excel based model calculates sensible and chemical enthalpy of the EAF off-gases during tap to tap time accounting for variation in quantity and quality of off gases. The model can be used to estimate energy saved through scrap preheating and other possible uses such as steam generation and electric power generation using off gas waste heat. This article includes a review of the historical development of existing waste heat recovery methods, their operations, and advantages/limitations of these methods. This paper also describes a program to develop and test advanced concepts for scrap preheating, steam production and electricity generation through use of waste heat recovery from the chemical and sensible heat contained in the EAF off gases with addition of minimum amount of dilution or cooling air upstream of pollution control equipment such as bag houses.

Nimbalkar, Sachin U [ORNL; Thekdi, Arvind [E3M Inc; Keiser, James R [ORNL; Storey, John Morse [ORNL

2014-01-01T23:59:59.000Z

340

Porous media to separate gases liquid droplets and/or solid particles from gases or vapors and coalesce entrained droplets  

SciTech Connect (OSTI)

Gas-vapor treating and filter mats are described that are composed of glass fibers intermixed with micro-bits of any of an expanded thermoplastic styrene-polymer or expanded thermoplastic lower polyolefin or flexible foam polyurethane and a suitable organic bonding agent, which mat may contain any of fibers of a fiber-forming terephthalate polyester, activated carbon, and gas-vapor adsorbent crystalline zeolite molecular sieve particles.

Klein, M.

1980-12-16T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Organic tank safety project: Preliminary results of energetics and thermal behavior studies of model organic nitrate and/or nitrite mixtures and a simulated organic waste  

SciTech Connect (OSTI)

As a result of years of production and recovery of nuclear defense materials and subsequent waste management at the Hanford Site, organic-bearing radioactive high-level wastes (HLW) are currently stored in large (up to 3. ML) single-shell storage tanks (SSTs). Because these wastes contain both fuels (organics) and the oxidants nitrate and nitrite, rapid energetic reactions at certain conditions could occur. In support of Westinghouse Hanford Company`s (WHC) efforts to ensure continued safe storage of these organic- and oxidant-bearing wastes and to define the conditions necessary for reactions to occur, we measured the thermal sensitivities and thermochemical and thermokinetic properties of mixtures of selected organics and sodium nitrate and/or nitrite and a simulated Hanford organic-bearing waste using thermoanalytical technologies. These thermoanalytical technologies are used by chemical reactivity hazards evaluation organizations within the chemical industry to assess chemical reaction hazards.

Scheele, R.D.; Sell, R.L.; Sobolik, J.L.; Burger, L.L.

1995-08-01T23:59:59.000Z

342

PHASE BEHAVIOR OF LIGHT GASES IN HYDROGEN AND AQUEOUS SOLVENTS  

SciTech Connect (OSTI)

Under previous support from the US Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, the solubilities of hydrogen in n-hexane, carbon monoxide in cyclohexane, and nitrogen in phenanthrene and pyrene were measured using a static equilibrium cell over the temperature range from 344.3 to 433.2 K and pressures to 22.8 MPa. The uncertainty in these new solubility measurements is estimated to be less than 0.001 in mole fraction. The data were analyzed using the Peng-Robinson (PR) equation of state (EOS). In general, the PR EOS represents the experimental data well when a single interaction parameter (C{sub ij}) is used for each isotherm. In addition, the predictive capability of the modified Park-Gasem-Robinson (PGR) equation of state (EOS) was evaluated for selected carbon dioxide + normal paraffins, ethane + normal paraffins, and hydrogen + normal paraffins. A set of mixing rules was proposed for the modified EOS to extend its predictive capabilities to mixtures. The predicted bubble point pressures for the ethane + n-paraffin and carbon dioxide + n-paraffin binaries were compared to those of the Peng-Robinson (PR), simplified-perturbed-hard-chain theory (SPHCT) and original PGR equations. The predictive capability of the proposed equation is better or comparable to the PR, SPHCT and original PGR equations of state for the ethane binaries (%AAD of 1.9) and carbon dioxide binaries (%AAD of 2.0). For the hydrogen binaries, the modified PGR EOS showed much better performance (%AAD of 1.7) than the original PGR equation and comparable to the PR equation.

KHALED A.M. GASEM; ROBERT L. ROBINSON, JR.

1999-03-31T23:59:59.000Z

343

Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents  

SciTech Connect (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

1997-09-01T23:59:59.000Z

344

Chemical filters by non-thermal atmospheric pressure plasmas for reactive fields  

Science Journals Connector (OSTI)

Non-thermal plasmas in electrode configurations are designed in this study and investigated at atmospheric pressure for generation of reactive fields. A combination of insulated wire electrodes and bare metal wire electrodes makes it possible to obtain a filter-like assembly of microplasmas, even in ambient air or in aqueous solutions. Oxidation and reduction fields are obtained by controlling the gas supply of hydrogen, oxygen, and water vapor, and these fields benefit various functional processes such as recycling CO2, decomposing organic molecules, and increasing the work function on metal surfaces.

Osamu Sakai; Tadasuke Morita; Yoshihiko Ueda; Noriaki Sano; Kunihide Tachibana

2011-01-01T23:59:59.000Z

345

Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance  

DOE Patents [OSTI]

Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.

Gupta, Raghubir P. (Durham, NC); Gangwal, Santosh K. (Durham, NC); Jain, Suresh C. (Morgantown, WV)

1993-01-01T23:59:59.000Z

346

Permanganate Treatment of DNAPLs in Reactive Barriers and Source Zone Flooding Schemes  

SciTech Connect (OSTI)

In situ oxidation with potassium permanganate has been widely evaluated, as a potential remediation method for dissolved or pure DNAPL in groundwater system. The goals of this study are (1) to elucidate the basic mechanisms by which potassium permanganate oxidizes common chlorinated solvents, various constituents in aqueous solution, and porous medium solids, and (2) to assess the potential for chemical oxidation by potassium permanganate to serve as a remedial scheme involving either source zone flooding or reactive barriers. The study is organized with a laboratory component that looks generally at the basic reaction processes and kinetics, and a theoretical component that is developing modeling tools appropriate for designing systems under field conditions.

Schwartz, Frank W.; Zhang, Hubao

2000-06-30T23:59:59.000Z

347

Instrumentation @ Catalysis: Reactivity and Structure Group | Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Instrumentation Instrumentation The Catalysis Group at BNL is leading research initiatives into the development of new tools and techniques that focus on the characterization of heterogeneous catalytic reactions and catalysts using imaging, spectroscopy and scattering techniques and integrated combinations of them under reaction conditions to unravel the morphology, chemical and structural properties, of catalysts, respectively. These efforts revolve around the use of synchrotron radiation (NSLS), electrons (CFN) and quantum tunneling tools with particular thrusts into imaging, spectroscopy and scattering. Groups Instrumentation(BNL) Three UHV chambers with diverse instrumentation for surface characterization: LEED, UPS, XPS, AES, TPD, ISS, PM-AP-IRRAS, Reactivity Cell. All the systems include ancillary instrumentation such as sputtering guns and metal evaporators. The IRRAS system was retrofitted with an ambient pressure (AP) cell on top of the UHV system. The sample can be prepared and characterized in UHV and then transfer in vacuum to the AP cell.

348

Review of existing reactive transport software  

SciTech Connect (OSTI)

Simulations of thermal and hydrological evolution following the potential emplacement of a subterranean nuclear waste repository at Yucca Mountain, NV provide data that suggest the inevitability of dependent, simultaneous chemical evolution in this system. These chemical changes will modify significantly both the magnitude and structure of local porosity and permeability; hence, they will have a dynamic feedback effect on the evolving thermal and hydrological regime. Yet, despite this intimate interdependence of transport and chemical processes, a rigorous quantitative analysis of the post- emplacement environment that incorporates this critical feedback mechanism has not been completed to date. As an initial step in this direction, the present document outlines the fundamental chemical and transport processes that must be accounted for in such an analysis, and reviews the inventory of existing software that encodes these processed in explicitly coupled form. A companion report describes the prioritization of specific capabilities that are needed for modeling post-emplacement reactive transport at Yucca Mountain.

Glassley, W., LLNL

1998-02-03T23:59:59.000Z

349

Combustion behavior of a spark ignition engine fueled with synthetic gases derived from biogas  

Science Journals Connector (OSTI)

Abstract Combustion results obtained from a spark ignition engine fueled with two synthetic gases obtained from catalytic decomposition of biogas are presented in this paper. These results are compared with those obtained when the engine was fueled with gasoline, methane and with the biogas from which synthetic gases are extracted. Experimental tests were performed under a wide range of speeds and at three equivalence ratios. Results showed that fractions of hydrogen in synthetic gases increased maximum pressures inside cylinder. Moreover, peak pressures were detected closer to top dead center than methane and biogas. Despite the fraction of diluents in the composition of synthetic gases, high speeds and lean conditions resulted in higher indicated efficiencies than those obtained with gasoline. Moreover, combustion speed and heat release rate were strongly influenced by the proportion of diluents and hydrogen in gaseous blends. CO and CO2 content in the composition of synthetic gases contributed to increase the exhaust concentrations of these pollutants compared with the other fuels, while HC decreased because of the small fraction of methane which remained unburned. Although \\{NOx\\} emissions were mitigated by diluents, like CO2 and air excess, high hydrogen fraction in composition of syngas involved elevated \\{NOx\\} emissions due to the increase in flame temperature that hydrogen produces.

J. Arroyo; F. Moreno; M. Mu˝oz; C. MonnÚ; N. Bernal

2014-01-01T23:59:59.000Z

350

A Learning-Based Approach to Reactive Security  

E-Print Network [OSTI]

Terms--Reactive security, risk management, attack graphs, online learning, adversarial learning, game vulnerability is plugged, CISOs typically perform a cost- benefit analysis to identify which risks to address of reactive strategies in an economic model of the CISO's security cost-benefit trade- offs. Unlike previously

Song, Dawn

351

A Reactive Measurement Framework Mark Allman and Vern Paxson  

E-Print Network [OSTI]

A Reactive Measurement Framework Mark Allman and Vern Paxson International Computer Science Institute Abstract. Often when assessing complex network behavior a single measure- ment is not enough for thinking about "measurement" as a process rather than an event. We introduce reactive measurement (REM

Paxson, Vern

352

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network [OSTI]

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

353

A Reactive Control Approach for Pipeline Inspection with an AUV  

E-Print Network [OSTI]

A Reactive Control Approach for Pipeline Inspection with an AUV Pedro K. Paim, Bruno Jouvencel and research activities, performing tasks such as survey, inspection of sub-sea pipelines and object recovery of mission. This paper proposes a reactive control approach for pipeline following by a torpedo- like

Paris-Sud XI, Universit├ę de

354

From Teleo-Reactive specifications to architectural components: A model-driven approach  

Science Journals Connector (OSTI)

The Teleo-Reactive approach designed by N.J. Nilsson offers a high-level programming model that permits the development of reactive systems, such as robotic vehicles. Teleo-Reactive programs are written in a manner that allows engineers to define the ... Keywords: Component-based software development, Model-driven software development, Reactive systems, Robotics, Teleo-Reactive programs

Pedro SßNchez; Diego Alonso; JosÚ Miguel Morales; Pedro Javier Navarro

2012-11-01T23:59:59.000Z

355

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect (OSTI)

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

356

Solubility Coefficients for Solar Liquids, a New Method to Quantify Undissolved Gases and Practical Recommendations  

Science Journals Connector (OSTI)

Abstract Solubility of nitrogen in propylene glycol/water mixtures (25%, 41.84% and 100% glycol by weight) have been determined in a temperature range from 10á░C to 110á░C using a static isochoric measuring method and are compared to the solubility of a typical solar liquid. To evaluate the amount of gas in a solar system it is necessary to measure the part of gases dissolved in the solar liquid, but also to consider the fraction of free gases (gas bubbles or gas cushions) in the system. Measuring this part was either not possible or only possible with a big technical effort until now. Therefore a new method was developed, which easily and fast identifies the volume of undissolved gases (ôGas Bubble Testö). The method was validated in extensive investigations in real solar systems.

Martin Heymann; Felix Panitz; Karin RŘhling; Clemens Felsmann

2014-01-01T23:59:59.000Z

357

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

358

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

359

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures  

E-Print Network [OSTI]

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures Elodie Salmon a , Adri C.T. van Duin b , Fran├žois Lorant Brown coal using the ReaxFF reactive force field. We find that these reactive MD simulations

Goddard III, William A.

360

GEI 41040G - Specification for Fuel Gases for COmbustion in Heavy-Duty Gas Turbines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Turbine Gas Turbine Revised, January 2002 GEI 41040G These instructions do not purport to cover all details or variations in equipment nor to provide for every possible contingency to be met in connection with installation, operation or maintenance. Should further information be desired or should particular problems arise which are not covered sufficiently for the purchaser's purposes the matter should be referred to the GE Company. ┬ę 1999 GENERAL ELECTRIC COMPANY Specification for Fuel Gases for Combustion in Heavy-Duty Gas Turbines GEI 41040G Specification for Fuel Gases for Combustion in Heavy-Duty Gas Turbines 2 TABLE OF CONTENTS I. INTRODUCTION 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Dissipative Dynamics of a Josephson Junction In the Bose-Gases  

E-Print Network [OSTI]

The dissipative dynamics of a Josephson junction in the Bose-gases is considered within the framework of the model of a tunneling Hamiltonian. The effective action which describes the dynamics of the phase difference across the junction is derived using functional integration method. The dynamic equation obtained for the phase difference across the junction is analyzed for the finite temperatures in the low frequency limit involving the radiation terms. The asymmetric case of the Bose-gases with the different order parameters is calculated as well.

R. A. Barankov; S. N. Burmistrov

2003-01-09T23:59:59.000Z

362

Spin noise spectroscopy to probe quantum states of ultracold fermionic atom gases  

SciTech Connect (OSTI)

We theoretically demonstrate that optical measurements of electron spin noise can be a spectroscopic probe of the entangled quantum states of ultracold fermionic atom gases and unambiguously reveal the detailed nature of the underlying interatomic correlations. Different models of the effective interatomic interactions predict entirely new sets of resonances in the spin noise spectrum. Once the correct effective interatomic interaction model is identified, the detailed noise line shapes of the spin noise can be used to constrain this model. We estimate the magnitude of spin noise signals expected in ultracold fermionic atom gases via noise measurements in classical alkali vapors, which demonstrate the feasibility of this approach.

Mihaila, Bogdan; Blagoev, Krastan B.; Smith, Darryl L. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Crooker, Scott A.; Rickel, Dwight G. [National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Littlewood, Peter B. [Cavendish Laboratory, Madingley Road, Cambridge CB3 0HE (United Kingdom)

2006-12-15T23:59:59.000Z

363

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

364

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

365

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

366

Chemical Imaging and Dynamical Studies of Reactivity and Emergent Behavior in Complex Interfacial Systems. Final Technical Report  

SciTech Connect (OSTI)

This research program explored the efficacy of using molecular-level manipulation, imaging and scanning tunneling spectroscopy in conjunction with supersonic molecular beam gas-surface scattering to significantly enhance our understanding of chemical processes occurring on well-characterized interfaces. One program focus was on the spatially-resolved emergent behavior of complex reaction systems as a function of the local geometry and density of adsorbate-substrate systems under reaction conditions. Another focus was on elucidating the emergent electronic and related reactivity characteristics of intentionally constructed single and multicomponent atom- and nanoparticle-based materials. We also examined emergent chirality and self-organization in adsorbed molecular systems where collective interactions between adsorbates and the supporting interface lead to spatial symmetry breaking. In many of these studies we combined the advantages of scanning tunneling (STM) and atomic force (AFM) imaging, scanning tunneling local electronic spectroscopy (STS), and reactive supersonic molecular beams to elucidate precise details of interfacial reactivity that had not been observed by more traditional surface science methods. Using these methods, it was possible to examine, for example, the differential reactivity of molecules adsorbed at different bonding sites in conjunction with how reactivity is modified by the local configuration of nearby adsorbates. At the core of this effort was the goal of significantly extending our understanding of interfacial atomic-scale interactions to create, with intent, molecular assemblies and materials with advanced chemical and physical properties. This ambitious program addressed several key topics in DOE Grand Challenge Science, including emergent chemical and physical properties in condensed phase systems, novel uses of chemical imaging, and the development of advanced reactivity concepts in combustion and catalysis including carbon management. These activities directly benefitted national science objectives in the areas of chemical energy production and advanced materials development.

Sibener, Steven J. [University of Chicago, IL (United States)] [University of Chicago, IL (United States)

2014-03-11T23:59:59.000Z

367

Reactive barriers for {sup 137}Cs retention  

SciTech Connect (OSTI)

{sup 137}Cs was dispersed globally by cold war activities and, more recently, by the Chernobyl accident. Engineered extraction of {sup 137}Cs from soils and groundwaters is exceedingly difficult. Because the half life of {sup 137}Cs is only 30.2 years, remediation might be more effective (and less costly) if {sup 137}Cs bioavailability could be demonstrably limited for even a few decades by use of a reactive barrier. Essentially permanent isolation must be demonstrated in those few settings where high nuclear level wastes contaminated the environment with {sup 135}Cs (half life 2.3x10{sup 6} years) in addition to {sup 137}Cs. Clays are potentially a low-cost barrier to Cs movement, though their long-term effectiveness remains untested. To identify optimal clays for Cs retention Cs resorption was measured for five common clays: Wyoming Montmorillonite (SWy-1), Georgia Kaolinites (KGa-1 and KGa-2), Fithian Illite (F-Ill), and K-Metabentonite (K-Mbt). Exchange sites were pre-saturated with 0.16 M CsCl for 14 days and readily exchangeable Cs was removed by a series of LiNO{sub 3} and LiCl washes. Washed clay were then placed into dialysis bags and the Cs release to the deionized water outside the bags measured. Release rates from 75 to 139 days for SWy-1, K-Mbt and F- 111 were similar; 0.017 to 0.021% sorbed Cs released per day. Both kaolinites released Cs more rapidly (0.12 to 0.05% of the sorbed Cs per day). In a second set of experiments, clays were doped for 110 days and subjected to an extreme and prolonged rinsing process. All the clays exhibited some capacity for irreversible Cs uptake so most soils have some limited ability to act as a natural barrier to Cs migration. However, the residual loading was greatest on K-Mbt ({approximately} 0.33 wt% Cs). Thus, this clay would be the optimal material for constructing artificial reactive barriers.

KRUMHANSL,JAMES L.; BRADY,PATRICK V.; ANDERSON,HOWARD L.

2000-05-19T23:59:59.000Z

368

Reactive sticking coefficients of silane on silicon  

SciTech Connect (OSTI)

We have investigated the reaction of room-temperature silane and disilane on a hot polycrystalline silicon surface using both a collision-free molecular beam and a very low pressure CVD cell. Reactive sticking coefficients were obtained from deposition rate data over a wide range of temperatures and silane (disilane) fluxes. The RSCs are substantially less than one, ranging from 6 x 10/sup -5/ to 4 x 10/sup -2/. For silane we observed curved Arrhenius plots with slopes decreasing from approx.60 kcal mol/sup -1/ at low temperatures to approx.2 kcal mol/sup -1/ at higher temperatures. The RSCs are independent of flux (pressure) at 1040/sup 0/C, but vary as flux to the approx.-1/2 power at 710/sup 0/C. A model comprised of a dissociative adsorption mechanism with competing associative desorption and reaction was found to give reasonable agreement. For disilane, we observed RSCs that were roughly ten times higher than those for silane. We also observed a curved Arrhenius plot and a flux dependence at 710/sup 0/C for disilane. 22 refs., 5 figs.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1987-01-01T23:59:59.000Z

369

Reactivity Differences between [alpha, beta]-Unsaturated Carbonyls and Hydrazones Investigated by Experimental and Theoretical Electron Density and Electron Localizability Analyses  

SciTech Connect (OSTI)

It is still a challenge to predict a compound's reactivity from its ground-state electronic nature although Bader-type topological analyses of the electron density (ED) and electron localizability indicator (ELI) give detailed and useful information on electron concentration and electron-pair localization, respectively. Both ED and ELI can be obtained from theoretical calculations as well as high-resolution X-ray diffraction experiments. Besides ED and ELI descriptors, the delocalization index is used here; it is likewise derived from theoretical calculations as well as from experimental X-ray results, but in the latter case, demonstrated here for the first time. We investigate {alpha},{beta}-unsaturated carbonyl and hydrazone compounds because resonance exhibited by these compounds in the electronic ground-state determines their reactive behavior. The degree of resonance as well as the reactivity contrast are quantified with the electronic descriptors. Moreover, competitive mesomeric substituent effects are studied using the two biologically important compounds acrolein and acrylamide. The reactivity differences predicted from the analyses are in line with the known reactivity of these compounds in organic synthesis. Hence, the capability of the ED and ELI for rationalizing and predicting different and competing substituent effects with respect to reactivity is demonstrated.

Grabowsky, Simon; Weber, Manuela; Jayatilaka, Dylan; Chen, Yu-Sheng; Grabowski, Matthias T.; Brehme, Rainer; Hesse, Malte; Schirmeister, Tanja; Luger, Peter (UWA); (Wurzburg); (UC); (Berlin)

2012-10-11T23:59:59.000Z

370

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

371

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally...

372

Metal-Pyrrolide Complexes in Three-fold Symmetry: Synthesis, Structure, Reactivity and Magnetism  

E-Print Network [OSTI]

Structure, Reactivity and Magnetism by William Hill Harman AStructure, Reactivity and Magnetism by William Hill Harmanlost time. Dave taught me magnetism and what it takes to win

Harman, William Hill

2010-01-01T23:59:59.000Z

373

Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene  

E-Print Network [OSTI]

The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement ...

Arizpe, Luis (Luis Alfredo)

2011-01-01T23:59:59.000Z

374

Aging Enhances the Production of Reactive Oxygen Species andBactericid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

375

Detection of Irradiated Frozen Deboned Seafood with the Level of Radiolytic H2 and CO Gases as a Probe  

Science Journals Connector (OSTI)

A method to detect irradiated frozen shrimp without cuticle, cod slices, and deshelled oyster has been developed based on the fact that radiolytic H2 and CO gases are retained in the irradiated samples for a certain period during the storage. These gases ...

Masakazu Furuta; Takaaki Dohmaru; Tadashi Katayama; Hirokazu Toratani; Atsuhiko Takeda

1997-10-15T23:59:59.000Z

376

Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents  

DOE Patents [OSTI]

A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known pressure swing adsorption'' technique utilizing the same sorption material. 1 fig.

Judkins, R.R.; Burchell, T.D.

1999-07-20T23:59:59.000Z

377

Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents  

DOE Patents [OSTI]

A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known "pressure swing adsorption" technique utilizing the same sorption material.

Judkins, Roddie R. (9917 Rainbow Dr., Knoxville, TN 37922); Burchell, Timothy D. (109 Greywood Pl., Oak Ridge, TN 37830)

1999-01-01T23:59:59.000Z

378

Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs  

E-Print Network [OSTI]

Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs PETER CONDORELLI of California at Irvine, Irvine, CA (Received 18 November 1997; accepted 9 February 1999) Abstract--Gas phase in terms of a lumped variable, Per(L/D)n . (Sh) increases as the solu- bility of the gas in tissue

George, Steven C.

379

Photoconductivity and luminescence in GaSe crystals at high levels of optical excitation  

SciTech Connect (OSTI)

The photoconductivity and luminescence of GaSe layered crystals at high levels of optical excitation are studied experimentally. The specific features observed in the photoconductivity and photoluminescence spectra are controlled by the nonlinear optical absorption in the region of excitonic resonance.

Kyazym-zade, A. G.; Salmanov, V. M., E-mail: vagif_salmanov@yahoo.com; Salmanova, A. A. [Baku State University (Azerbaijan); Alieva, A. M.; Ibaeva, R. Z. [National Academy of Sciences, Institute of Physics (Azerbaijan)

2010-03-15T23:59:59.000Z

380

Operational aspects of the desulfurization process of energy gases mimics in biotrickling filters5  

E-Print Network [OSTI]

. Introduction Energy rich off-gases such as biogas are sometimes not used for electric power generation due impurities. H2S concentrations in biogas can range from 0.1 to 5 We dedicate this article to the memory/v (1000e20,000 ppmv), whereas the specifications for the maximum content of H2S in typical biogas

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

1988 Pilot Institute on Global Change on trace gases and the biosphere  

SciTech Connect (OSTI)

This proposal seeks multi-agency funding to conduct an international, multidisciplinary 1988 Pilot Institute on Global Change to take place from August 7 through 21, 1988, on the topic: Trace Gases and the Biosphere. The institute, to be held in Snowmass, Colorado, is envisioned as a pilot version of a continuing series of institutes on Global Change (IGC). This proposal seeks support for the 1988 pilot institute only. The concept and structure for the continuing series, and the definition of the 1988 pilot institute, were developed at an intensive and multidisciplinary Summer Institute Planning Meeting in Boulder, Colorado, on August 24--25, 1987. The theme for the 1988 PIGC, Trace Gases and the Biosphere, will focus a concerted, high-level multidisciplinary effort on a scientific problem central to the Global Change Program. Dramatic year-to-year increases in the global concentrations of radiatively-active trace gases such as methane and carbon dioxide are now well documented. The predicted climatic effects of these changes lend special urgency to efforts to study the biospheric sources and sinks of these gases and to clarify their interactions and role in the geosphere-biosphere system.

Eddy, J.A.; Moore, B. III

1998-07-01T23:59:59.000Z

382

Bose-Einstein Condensation in Atomic Gases Jerzy Zachorowski and Wojciech Gawlik  

E-Print Network [OSTI]

. It is instructive to compare orders of magnitude typical for the thermal and condensed gas samples. For atom gasBose-Einstein Condensation in Atomic Gases Jerzy Zachorowski and Wojciech Gawlik M. Smoluchowski on the Bose-Einstein condensate. We also present main parameters and expected characteristics of the first Pol

383

Ion fragmentation in an electrospray ionization mass spectrometer interface with different gases  

E-Print Network [OSTI]

in the gas phase. However, particularly in multi- component samples, this may not be enough to unambigu predicts that the degree of ion fragmentation increases with increasing mass of the curtain gas. However with argon and krypton is caused by condensation of the gases within the free jet expansion between

Chen, David D.Y.

384

UA Researchers design a catalyst that neutralizes the gases responsible for climate change  

E-Print Network [OSTI]

UA Researchers design a catalyst that neutralizes the gases responsible for climate change Toxic Researchers at the University of Alicante have developed and patented a novel catalyst capable of decomposing gas streams. "However, nitrous oxide can be decomposed at lower temperatures using a suitable catalyst

Escolano, Francisco

385

Radiative-convective model of warming Mars with artificial greenhouse gases  

E-Print Network [OSTI]

spectra of seven artificial greenhouse gases (CF4, C2F6, C3F8, SF6, CF3Cl, CF3Br, CF2Cl2 ecosynthesis, CF4, C2F6, and SF6 were 17%, 49%, and 48% as effective as C3F8, respectively. The optimal mixture

Kite, Edwin

386

A Biomass-based Model to Estimate the Plausibility of Exoplanet Biosignature Gases  

E-Print Network [OSTI]

Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H2S, CH4, CH3Cl, and DMS. We have applied the models to propose NH3 as a biosignature gas on a "cold Haber World," a planet with a N2-H2 atmosphere, and to demonstrate why gases such as CH3Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such...

Seager, S; Hu, R

2013-01-01T23:59:59.000Z

387

Article published Greenhouse Gases: Science and Technology DOI: 10.1002/ghg.1395  

E-Print Network [OSTI]

Article published Greenhouse Gases: Science and Technology DOI: 10.1002/ghg.1395 National Corridors.1002/ghg.1395 #12;1 Introduction The need to reduce greenhouse gas (GHG) emissions by present energy.1, 2 Carbon dioxide (CO2) is the most worrisome GHG because of its long residence time

Paris-Sud XI, Universit├ę de

388

Ballistic spin transport in exciton gases A. V. Kavokin,1, 2  

E-Print Network [OSTI]

, or spin-optronics challeng- ing. How possibly one can explore the current, which is carried by neutral are possible in exciton and exciton-polariton Bose gases. Bosonic spintronics or spin-optronics operates,28 . Combined with evident advantages of bosonic amplifica- tion and low dephasing, this makes spin-optronics

Paris-Sud XI, Universit├ę de

389

ESTABoues, a decision tool to assess greenhouse gases of sewage sludge treatment and di  

E-Print Network [OSTI]

digestion, aerobic digestion, dewatering, al composting, drying) and sludge disposal route (land applicationORBIT2012 G ESTABoues, a decision tool to assess greenhouse gases of sewage sludge treatment and di-laure.reverdy@irstea.fr EXECUTIVE SUMMARY Sewage sludge production increases continuously reaching almost 20% (946 700 t 1 118 795

Paris-Sud XI, Universit├ę de

390

Gas Chromatographic Measurement of Trace Oxygen and Other Dissolved Gases in Thermally Stressed Jet Fuel  

Science Journals Connector (OSTI)

......additional light hydrocarbon gases (e.g...stream, and the data can be obtained...system. The output data from this analytical...F33615-87-C-2714 and the Combustion and Heat Transfer Studies...from deoxygenated hydrocarbons: I. General features......

Wayne A. Rubey; Richard C. Striebich; Michael D. Tissandier; Debra A. Tirey; Steven D. Anderson

1995-08-01T23:59:59.000Z

391

Experimental observation of a traveling plasma grating formed by two crossing filaments in gases  

SciTech Connect (OSTI)

The spatial motion and effective duration of a traveling plasma grating formed by two interfering femtosecond laser filaments in gases is characterized by its Doppler effect imparted on a probe pulse. The shift velocity determined experimentally agrees with the theoretical calculations.

Durand, Magali [Laboratoire d'Optique Appliquee, ENSTA ParisTech-Ecole Polytechnique-CNRS, 91761 Palaiseau (France); ONERA, Chemin de la Huniere, 91761 Palaiseau (France); Liu Yi; Forestier, Benjamin; Houard, Aurelien; Mysyrowicz, Andre [Laboratoire d'Optique Appliquee, ENSTA ParisTech-Ecole Polytechnique-CNRS, 91761 Palaiseau (France)

2011-03-21T23:59:59.000Z

392

Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine  

E-Print Network [OSTI]

Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine fuel cells are usually described as devices able to convert chemical energy into electrical energy. Conventional solid oxide fuel cells are separated into two compartments containing each electrode split

Boyer, Edmond

393

Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network infrastructures are  

E-Print Network [OSTI]

Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network on the overall power consumption and on the GHG emissions with just 25% of green energy sources. I. INTRODUCTION]. In the zero carbon approach, renewable (green) energy sources (e.g. sun, wind, tide) are employed and no GHGs

Polit├Ęcnica de Catalunya, Universitat

394

Kolmogorov-Sinai entropy for dilute gases in equilibrium H. van Beijeren,1  

E-Print Network [OSTI]

. Posch,3 and Ch. Dellago3,4 1 Institute for Theoretical Physics, University of Utrecht, Postbus 80006, 3508 TA Utrecht, The Netherlands 2 Institute for Physical Science and Technology and Department the kinetic theory of gases have been applied to compute the chaotic properties of simple systems such as hard

Dellago, Christoph

395

Towards a history of the international industrial gases industry Ray Stokes, Ralf Banken, and Matthias Phl  

E-Print Network [OSTI]

industrial revolution" and their component companies. From David Landes's classic study, The Unbound of the industries of the second industrial revolution has been virtually ignored in this scholarship to date1 Towards a history of the international industrial gases industry Ray Stokes, Ralf Banken

Guo, Zaoyang

396

Reactivity of Organic Compounds in Hot Water: Geochemical and Technological Implications  

Science Journals Connector (OSTI)

...HIGH-TEMPERATURE HYDROLYSIS AND THERMOLYSIS OF TETRAHYDROTHIOPHENE IN RELATION TO STEAM STIMULATION...HIGH-TEMPERATURE HYDROLYSIS OF TETRAHYDROTHIOPHENE AND THIOPHENE, FUEL 63 : 125...3. REACTION OF THIOPHENE AND TETRAHYDROTHIOPHENE WITH VANADYL AND NICKEL SALTS...

MICHAEL SISKIN; ALAN R. KATRITZKY

1991-10-11T23:59:59.000Z

397

Quantifying the Reactive Uptake of OH by Organic Aerosols in a Continuous Flow Stirred Tank Reactor  

E-Print Network [OSTI]

in a Continuous Flow Stirred Tank Reactor Dung L. Che, 1,2a continuous flow stirred tank reactor. This approach isa continuous flow stirred tank reactor (CFSTR) at lower OH

Che, Dung L.

2010-01-01T23:59:59.000Z

398

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty  

E-Print Network [OSTI]

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty perform research in molecular machines, exotic CHEMISTRY FACULTY RESEARCH INTERESTS Anne M. Andrews, Professor-in-Residence: Understanding how areas of interest include cross- coupling reactions, green chemistry, heterocycle synthesis, and natural

Levine, Alex J.

399

Photo of the Week: Reactive Ion Etching | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Reactive Ion Etching Reactive Ion Etching Photo of the Week: Reactive Ion Etching October 17, 2013 - 1:26pm Addthis Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material structures. In this photo, the drop-like domes were carved through a process called reactive ion etching, which produced the striped bubbles you see in the Laue lens. The prototype in this image helped scientists perfect the process of creating lenses so precise that scientists are able to focus x-rays to within a single nanometer. | Photo courtesy of Brookhaven National Laboratory. Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material

400

Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquids: Reactivity of Primary Species Liquids: Reactivity of Primary Species James F. Wishart In "Ionic Liquids as Green Solvents: Progress and Prospects" Rogers, R. D. and Seddon, K. R. , Eds.; ACS Symp. Ser. 856, Ch. 31, pp. 381-395, American Chemical Society, Washington, DC, 2003. (ISBN 0-84123-856-1) [Information about the book] Abstract: An understanding of the radiation chemistry of ionic liquids is important for development of their applications in radioactive material processing and for the application of pulse radiolysis techniques to the general study of chemical reactivity in ionic liquids. The distribution of primary radiolytic species and their reactivities determine the yields of ultimate products and the radiation stability of a particular ionic liquid. This chapter introduces some principles of radiation chemistry and the

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Detoxification of hydrolysate by reactive-extraction for generating biofuels  

Science Journals Connector (OSTI)

We introduce a reactive extraction to detoxify hydrolysate before fermentation to biofuels. In the selection of diluents, n-octanol showed the highest removal yield of 5-hydroxymethylfurfural (5-HMF) and levulini...

Gwi-Taek Jeong; Sung-Koo Kim; Don-Hee Park

2013-02-01T23:59:59.000Z

402

Cooperative Strategies and Reactive Search: A Hybrid Model Proposal  

Science Journals Connector (OSTI)

Cooperative strategies and reactive search are very promising techniques for solving hard optimization problems, since they reduce human intervention required to set up a method when the resolution of an unknown instance is needed. However, as far as ...

Antonio D. Masegosa; Franco Mascia; David Pelta; Mauro Brunato

2009-11-01T23:59:59.000Z

403

Mechanisms of Photochemistry and Reactive Oxygen Production by  

E-Print Network [OSTI]

photosensitizer that produces reactive oxygen species (ROS) in the presence of light; however, its properties medical and environmental contexts as well as the potential applications implied for industrial or water of transferring light energy to chemical oxidation potential in theformof

Alvarez, Pedro J.

404

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network [OSTI]

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

405

The Safe Storage Study for Autocatalytic Reactive Chemicals  

E-Print Network [OSTI]

In the U.S. Chemical Safety and Hazard Investigation Board (CSB) report, Improving Reactive Hazard Management, there are 37 out of 167 accidents, which occurred in a storage tank or a storage area. This fact demonstrates that thermal runaway...

Liu, Lijun

2010-10-12T23:59:59.000Z

406

Reactive Power Compensation Strategy of DGIF Wind Park  

Science Journals Connector (OSTI)

In this chapter, two different wind park reactive power compensation strategies for the DFIG wind park connected to the sub-transmission level are proposed. Except considering DFIG wind turbines as dynamic reacti...

JingJing Zhao; Yang Fu; DongDong Liů

2014-01-01T23:59:59.000Z

407

Evolution of Memory in Reactive Artificial Neural Networks  

E-Print Network [OSTI]

in the context of evolution: how reactive agents could have evolved into cognitive ones with internalized memory? This study strives to find an answer to the question by simulating neuroevolution on artificial neural networks, with the hypothesis...

Chung, Ji Ryang

2012-07-16T23:59:59.000Z

408

Reactive Support and Voltage Control Service: Key Issues and Challenges  

E-Print Network [OSTI]

Reactive Support and Voltage Control Service: Key Issues and Challenges George Gross^, Paolo of Illinois at Urbana-Champaign, Urbana, IL 61801, USA, e-mail gross@uiuc.edu ┬░ Dipartimento di Ingegneria

Gross, George

409

Analytical methods for determining the reactivity of pyrochemical salts  

SciTech Connect (OSTI)

Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

Phillips, A.G.; Stakebake, J.L.

1994-05-01T23:59:59.000Z

410

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

411

Local Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the re...

Turitsyn, Konstantin S; Backhaus, Scott; Chertkov, Misha

2010-01-01T23:59:59.000Z

412

Assessing low power reactivity levels in subcritical CANDU reactors  

SciTech Connect (OSTI)

A new technique has been developed for monitoring slow reactivity changes in Canadian deuterium uranium (CANDU) nuclear reactors during low power operation, following a sustained period of high power operation. The power doubling halving worth (PDHW) test tracks slow reactivity changes by evaluating the reactivity perturbation required by the power regulating system to halve and double reactor power over time. During low power operation of a CANDU reactor, the PDHW test is used to monitor the decay of the photoneutron precursors, so that the reactor power can be lowered using a preset amount of reactivity. The PDHW test is described in this paper and is validated by using computer simulations and operating data from a CANDU reactor.

Teare, S.W. [Corporation of the City of Mississauga, Ontario (Canada)] [Corporation of the City of Mississauga, Ontario (Canada); Shanes, F.C. [Ontario Hydro, Toronto, Ontario (Canada)] [Ontario Hydro, Toronto, Ontario (Canada); Hersey, M.W. [Pickering Nuclear Generating Station, Ontario (Canada)] [Pickering Nuclear Generating Station, Ontario (Canada)

1996-08-01T23:59:59.000Z

413

(Electronic structure and reactivities of transition metal clusters)  

SciTech Connect (OSTI)

The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

Not Available

1992-01-01T23:59:59.000Z

414

Observations of Secondary Organic Aerosol Production and Soot Aging under Atmospheric Conditions Using a Novel Environmental Aerosol Chamber  

E-Print Network [OSTI]

, heterogeneous surface reactions, cloud processing, and gas-to-particle partitioning through the formation of secondary organic aerosol (SOA) by organic gases (Pankow 1994). Moreover, SOA has been linked to adverse health effects as they typically contain... 1985; Ng et al. 2006; Presto et al. 2005; Saathoff et al. 2003). Such classes include cycloalkenes, aromatic hydrocarbons, and terpenes, most of which are cyclic compounds. When these compounds undergo atmospheric oxidation, 3 they produce first-generation...

Glen, Crystal

2012-02-14T23:59:59.000Z

415

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive Reactive  

E-Print Network [OSTI]

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition) homogeneous reactions with indoor pollutants. The #12;Proceedings of Healthy Buildings 2009 Paper 336 latter

Siegel, Jeffrey

416

The Organic Rankine Cycle  

Science Journals Connector (OSTI)

Chap. 3 is dedicated to Rankine cycles with organic fluids: the so-called organic Rankine cycles (ORC), which in recent years have ... of the use of...

Costante Mario Invernizzi

2013-01-01T23:59:59.000Z

417

Organization | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Organization Organization The Office of Economic Impact and Diversity is comprised of: The Office of the Director- contact us Office of Minority Business and Economic Development -...

418

Controlled Vapor Phase Growth of Single Crystalline, Two-Dimensional GaSe Crystals with High Photoresponse  

SciTech Connect (OSTI)

Abstract Compared with their bulk counterparts, atomically thin two-dimensional (2D) crystals exhibit new physical properties, and have the potential to enable next-generation electronic and optoelectronic devices. However, controlled synthesis of large uniform monolayer and multi-layer 2D crystals is still challenging. Here, we report the controlled synthesis of 2D GaSe crystals on SiO2/Si substrates using a vapor phase deposition method. For the first time, uniform, large (up to ~60 m in lateral size), single-crystalline, triangular monolayer GaSe crystals were obtained and their atomic resolution structure were characterized. The size, density, shape, thickness, and uniformity of the 2D GaSe crystals were shown to be controllable by growth duration, growth region, growth temperature, and argon carrier gas flow rate. The theoretical modeling of the electronic structure and Raman spectroscopy demonstrate a direct-to-indirect bandgap transition and progressive confinement-induced bandgap shifts for 2D GaSe crystals. The 2D GaSe crystals show p-type semiconductor characteristics and high photoresponsivity (~1.7 A/W under white light illumination) comparable to exfoliated GaSe nanosheets. These 2D GaSe crystals are potentially useful for next-generation electronic and optoelectronic devices such as photodetectors and field-effect transistors.

Li, Xufan [ORNL; Lin, Ming-Wei [ORNL; Zhang, Huidong [University of Tennessee, Knoxville (UTK); Puretzky, Alexander A [ORNL; Idrobo Tapia, Juan C [ORNL; Ma, Cheng [ORNL; Chi, Miaofang [ORNL; Yoon, Mina [ORNL; Rouleau, Christopher M [ORNL; Kravchenko, Ivan I [ORNL; Geohegan, David B [ORNL; Xiao, Kai [ORNL

2014-01-01T23:59:59.000Z

419

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases  

DOE Patents [OSTI]

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Ayala, Raul E. (Clifton Park, NY)

1993-01-01T23:59:59.000Z

420

Effects of land use on surfaceľatmosphere exchanges of trace gases and energy in Borneo: comparing fluxes over oil palm plantations and a rainforest  

Science Journals Connector (OSTI)

...27 November 2011 research-article Articles...trace gases and energy in Borneo: comparing...boundary layer using a research aircraft in Sabah...exchange fluxes of energy and trace gases...Geophys. Res. Abstracts 12, EGU2010-15408...trace gases and energy in Borneo: comparing...

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Research on fuzzy logic based dynamic boundary voltage and reactive power integrated control method  

Science Journals Connector (OSTI)

Aiming at the existing problems of conventional substation voltage and reactive power integrated control method, a new fuzzy logic based dynamic reactive power boundary voltage and reactive power integrated control method is proposed. Fuzzy logic control ... Keywords: dynamic boundary, fuzzy logic, reactive power, voltage

Zigang Xu; Fei Wang

2009-06-01T23:59:59.000Z

422

Development and Evaluation of a State-of-the-Science Reactive Plume  

E-Print Network [OSTI]

for plume rise, plume visibility, and stack opacity (5). Examples of other reactive plume models include

Zhang, Yang

423

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah  

Broader source: Energy.gov [DOE]

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

424

,"Ohio Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030oh2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030oh2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:25 AM" "Back to Contents","Data 1: Ohio Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" "Sourcekey","N9030OH2" "Date","Ohio Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" 33253,0 33284,0 33312,0

425

,"Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030tn2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030tn2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:27 AM" "Back to Contents","Data 1: Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" "Sourcekey","N9030TN2" "Date","Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" 33253,0 33284,0

426

,"Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2010 Annual",2010 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030tn2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030tn2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:27 AM" "Back to Contents","Data 1: Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" "Sourcekey","N9030TN2" "Date","Tennessee Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" 35611,0 35976,0 37802,0 38898,0

427

,"Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030va2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030va2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:29 AM" "Back to Contents","Data 1: Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" "Sourcekey","N9030VA2" "Date","Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" 33253,0 33284,0

428

Emissions of Greenhouse Gases in the United States 2009, DOE/EIA-0573(2009)  

Gasoline and Diesel Fuel Update (EIA)

March 2011 www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Emissions of Greenhouse Gases in the United States 2009 ii Contacts This report, Emissions of Greenhouse Gases in the United States 2009, was prepared under the general direction of John Conti, Assistant Administrator for Energy Analysis, and Paul Holtberg, Team Leader, Analysis Integration Team. General questions concerning the content of this report may be directed to the Office of Communications at 202/586-8800. Technical information concerning the content of the report may be obtained from Perry Lindstrom at 202/586-0934 (email, perry. lindstrom@eia.gov). Without the assistance of Science Applications International Corporation (SAIC), this report would not have

429

,"Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2010 Annual",2010 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030pa2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030pa2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:26 AM" "Back to Contents","Data 1: Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" "Sourcekey","N9030PA2" "Date","Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" 35611,0 35976,0 37802,0

430

Comparative Analysis of Alternative Means for Removing Noncondensable Gases from Flashed-Steam Geothermal Power Plants  

Open Energy Info (EERE)

June 2000 * NREL/SR-550-28329 June 2000 * NREL/SR-550-28329 Martin Vorum, P.E. Englewood, Colorado Eugene A. Fritzler, P.E. Fort Morgan, Colorado Comparative Analysis of Alternative Means for Removing Noncondensable Gases from Flashed-Steam Geothermal Power Plants April 1999-March 2000 National Renewable Energy Laboratory 1617 Cole Boulevard Golden, Colorado 80401-3393 NREL is a U.S. Department of Energy Laboratory Operated by Midwest Research Institute * * * * Battelle * * * * Bechtel Contract No. DE-AC36-99-GO10337 June 2000 * NREL/SR-550-28329 Comparative Analysis of Alternative Means for Removing Noncondensable Gases from Flashed-Steam Geothermal Power Plants April 1999-March 2000 Martin Vorum, P.E. Englewood, Colorado Eugene A. Fritzler, P.E. Fort Morgan, Colorado NREL Technical Monitor: C. Kutscher

431

,"South Dakota Natural Gas Nonhydrocarbon Gases Removed (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030sd2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030sd2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:26 AM" "Back to Contents","Data 1: South Dakota Natural Gas Nonhydrocarbon Gases Removed (MMcf)" "Sourcekey","N9030SD2" "Date","South Dakota Natural Gas Nonhydrocarbon Gases Removed (MMcf)" 33253,0 33284,0 33312,0 33343,0 33373,0

432

Removal of oxides of nitrogen from gases in multi-stage coal combustion  

DOE Patents [OSTI]

Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

1998-01-01T23:59:59.000Z

433

A comprehensive study of different gases in inductively coupled plasma torch operating at one atmosphere  

Science Journals Connector (OSTI)

A numerical study is done to understand the possible operating regimes of RF-ICP torch (3?MHz 50?kW) using different gases for plasma formation at atmospheric pressure. A two dimensional numerical simulation of RF-ICP torch using argon nitrogen oxygen and air as plasma gas has been investigated using computational fluid dynamic (CFD) software fluentę. The operating parameters varied here are central gas flow sheath gas flow RF-power dissipated in plasma and plasma gas. The temperature contours flow field axial and radial velocity profiles were investigated under different operating conditions. The plasmaresistance inductance of the torch and the heat distribution for various plasma gases have also been investigated. The plasma impedance of ICP torch varies with different operating parameters and plays an important role for RF oscillator design and power coupling. These studies will be useful to decide the design criteria for ICP torches required for different material processing applications.

Sangeeta B. Punjabi; N. K. Joshi; H. A. Mangalvedekar; B. K. Lande; A. K. Das; D. C. Kothari

2012-01-01T23:59:59.000Z

434

Membranes, methods of making membranes, and methods of separating gases using membranes  

DOE Patents [OSTI]

Membranes, methods of making membranes, and methods of separating gases using membranes are provided. The membranes can include at least one hydrophilic polymer, at least one cross-linking agent, at least one base, and at least one amino compound. The methods of separating gases using membranes can include contacting a gas stream containing at least one of CO.sub.2, H.sub.2S, and HCl with one side of a nonporous and at least one of CO.sub.2, H.sub.2S, and HCl selectively permeable membrane such that at least one of CO.sub.2, H.sub.2S, and HCl is selectively transported through the membrane.

Ho, W. S. Winston

2012-10-02T23:59:59.000Z

435

Bose and Fermi gases in the early Universe with self-gravitational effect  

SciTech Connect (OSTI)

We study the self-gravitational effect on the equation of state (EoS) of Bose and Fermi gases in thermal equilibrium at the end of reheating, the period after quark-hadron transition and before big bang nucleosynthesis (BBN). After introducing new grand canonical partition functions based on the work of Uhlenbeck and Gropper, we notice some interesting features of the newly developed EoSs with distinct behaviors of relativistic and nonrelativistic gases under self-gravity. The usual negligence of the self-gravitational effect when solving the background expansion of the early Universe is justified with numerical results, showing the magnitude of the self-gravitational modification of the state constant to be less than O(10{sup -78}). This helps us to clarify the background thermal evolution of the primordial patch. Such clarification is crucial in testing gravity theories, evaluating inflation models and determining element abundances in BBN.

Niu Yuezhen; Huang Junwu; Ma Boqiang [School of Physics and State Keye Laboratory of Nuclear Physics and Technology, Peking University, Beijing 100871 (China); School of Physics and State Key Laboratory of Nuclear Physics and Technology, Peking University, Beijing 100871 (China) and Center for High Energy Physics, Peking University, Beijing 100871 (China) and Center for History and Philosophy of Science, Peking University, Beijing 100871 (China)

2011-03-15T23:59:59.000Z

436

,"Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2010 Annual",2010 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030va2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030va2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:29 AM" "Back to Contents","Data 1: Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" "Sourcekey","N9030VA2" "Date","Virginia Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" 35611,0 35976,0 37802,0 38898,0

437

EIA-Voluntary Reporting of Greenhouse Gases Program - Original 1605(b)  

U.S. Energy Information Administration (EIA) Indexed Site

Program Program Voluntary Reporting of Greenhouse Gases Program Original 1605(b) Program Section 1605(b) of the Energy Policy Act of 1992 established the Voluntary Reporting of Greenhouse Gases Program. The Program operated under the original 1994 guidelines through the 2005 data year (for reports containing data through 2005). Reports containing data through 2007 and beyond submitted beginning in 2008 will be conducted under the revised General and Technical Guidelines issued in 2006 and 2007, respectively. More about the original 1605(b) Program. Old Program Reporting Guidelines Old Program Electricity Emissions Factors Old Program Calculation Tools Old Program Forms and Software Old Program Reports for the reporting years 1994 to 2004. Old Program Data for the reporting years 1994 to 2005.

438

ARM - PI Product - ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ProductsARM-LBNL-NOAA Flask Sampler for Carbon Cycle ProductsARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : ARM-LBNL-NOAA Flask Sampler for Carbon Cycle Gases Site(s) SGP General Description Data from ccg-flasks are sampled at the ARM SGP site and analyzed by the NOAA Earth System Research Laboratory (ESRL) as part of the NOAA Cooperative Global Air Sampling Network. Surface samples are collected from a 60m tower at the SGP Central Facility, usually once per week on one afternoon. The aircraft samples are collected approximately weekly from a chartered aircraft, and the collection flight path is centered over the tower where the surface samples are collected. Samples are collected by the ARM/LBNL Carbon Project. CO2 flask data contains measurements of CO2

439

,"Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n9030pa2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n9030pa2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/19/2013 6:56:26 AM" "Back to Contents","Data 1: Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" "Sourcekey","N9030PA2" "Date","Pennsylvania Natural Gas Nonhydrocarbon Gases Removed (Million Cubic Feet)" 33253,0

440

Adsorption of molecular gases on porous materials in the SAFT-VR approximation  

E-Print Network [OSTI]

A simple molecular thermodynamic approach is applied to the study of the adsorption of gases of chain molecules on solid surfaces. We use a model based on the Statistical Associating Fluid Theory for Variable Range (SAFT-VR) potentials [A. Gil-Villegas, A. Galindo, P. J. Whitehead, S. J. Mills, G. Jackson, A. N. Burgess, J. Chem. Phys. 106 (1997) 4168] that we extend by including a quasi-two-dimensional approximation to describe the adsorption properties of this type of real gases [A. Martinez, M. Castro, C. McCabe, A. Gil-Villegas, J. Chem. Phys. 126 (2007) 074707]. The model is applied to ethane, ethylene, propane, and carbon dioxide adsorbed on activated carbon and silica gel, which are porous media of significant industrial interest. We show that the adsorption isotherms obtained by means of the present SAFT-VR modeling are in fair agreement with the experimental results provided in the literature

Castro, M; Martinez, A; Rosu, H C; 10.1016/j.physa.2010.04.028

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Transportation Organization and Functions  

Broader source: Energy.gov [DOE]

Office of Packaging and Transportation list of organizations and functions, with a list of acronyms.

442

Plasmon mass and Drude weight in strongly spin-orbit-coupled two-dimensional electron gases  

E-Print Network [OSTI]

) spin- orbit-coupled 2D electron and hole gases, which are promising candidates for semiconductor spintronics,1 (ii) graphene2 (a monolayer of carbon atoms arranged in a 2D honeycomb lattice), which has attracted a great deal of interest because..., in the case of graphene) degree of freedom. This coupling, being of relativistic origin,12 naturally breaks Galilean invariance and is thus the basic reason for a quite sensitive dependence of several observables on electron-electron interactions, even...

Agarwal, Amit; Chesi, Stefano; Jungwirth, T.; Sinova, Jairo; Vignale, G.; Polini, Marco.

2011-01-01T23:59:59.000Z

443

Changes in atmospheric gases during isobaric storage of beef packaged pre- and post-rigor  

E-Print Network [OSTI]

displacement measurements of the head- space volume were conducted during two weeks of storage. Males of the headspace gases were calculated using the general gas law (PU = nRT). Carbon dioxide absorption by the meat was greatest in steaks stored in 100% C... OF FIGURES INTRODUCTION LITERATURE REV IELV Microbiol ogical Aspects of Packaging Meat Shelf-Life of Packaged Meat Respiration . Carbon Dioxide Absorption OBJECTIVES EXPERIMENTAL PROCEDURES RESULTS AND DISCUSSION Description of Meat Samples . Molar...

Hoermann, Karen Lee

1980-01-01T23:59:59.000Z

444

Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases  

SciTech Connect (OSTI)

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

2001-11-06T23:59:59.000Z

445

Purification of Natural Gases with High CO2 Content Using Gas Hydrates  

Science Journals Connector (OSTI)

Purification of Natural Gases with High CO2 Content Using Gas Hydrates ... The feed was separated using a cascade of continuously stirred tank crystallizer vessels, which can also be regarded as an ideal crystallizer column resembling a gas-hydrate-based scrubbing process. ... Pressurized gas scrubbing, pressure swing adsorption, chemical absorption, and membrane and cryogenic processes are some examples of well-established technologies for the removal of CO2 from gaseous products. ...

Nena Dabrowski; Christoph Windmeier; Lothar R. Oellrich

2009-09-25T23:59:59.000Z

446

Gas chromatographic identification of interferences and their elimination in measuring total reduced sulfur gases  

SciTech Connect (OSTI)

This paper reports on a selective filter that is capable of eliminating positive interference in the coulometric measurement of ambient concentrations of total reduced sulfur gases which has been successfully developed and field tested. Most of the interference was found to be caused by terpenes, which react with bromine, the active reagent in the coulometric titrators. Terpenes are given off by conifer trees in the natural environment as well as emitted in pulping and other wood-handling and lumber manufacturing operations.

de Souza, T.L.C. (Pulp and Paper Research Inst. of Canada, Pointe Claire, PQ (Canada))

1992-05-01T23:59:59.000Z

447

Solubility and displacement behavior of a viscous crude with CO[sub 2] and hydrocarbon gases  

SciTech Connect (OSTI)

The West Sak reservoir on the Alaskan North Slope contains an estimated 15 to 25 billion bbl of low-temperature, viscous crude. The reservoir has promising development potential by means of a gas injection process. An experimental study of the solubility and displacement behavior of West Sak oil with CO[sub 2] and hydrocarbon gases shows simple black-oil to complex, multiphase equilibrium behaviors.

DeRuiter, R.A.; Nash, L.J.; Singletary, M.S.

1994-05-01T23:59:59.000Z

448

Domain walls and bubble-droplets in immiscible binary Bose gases  

E-Print Network [OSTI]

The existence and stability of domain walls (DWs) and bubble-droplet (BD) states in binary mixtures of quasi-one-dimensional ultracold Bose gases with inter- and intra-species repulsive interactions is considered. Previously, DWs were studied by means of coupled systems of Gross-Pitaevskii equations (GPEs) with cubic terms, which model immiscible binary Bose-Einstein condensates (BECs). We address immiscible BECs with two- and three-body repulsive interactions, as well as binary Tonks--Girardeau (TG) gases, using systems of GPEs with cubic and quintic nonlinearities for the binary BEC, and coupled nonlinear Schr\\"{o}dinger equations with quintic terms for the TG gases. Exact DW\\ solutions are found for the symmetric BEC mixture, with equal intra-species scattering lengths. Stable asymmetric DWs in the BEC mixtures with dissimilar interactions in the two components, as well as of symmetric and asymmetric DWs in the binary TG gas, are found by means of numerical and approximate analytical methods. In the BEC sy...

Filatrella, G; Salerno, M

2014-01-01T23:59:59.000Z

449

Emissions of greenhouse gases in the United States, 1987--1994  

SciTech Connect (OSTI)

The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

NONE

1995-09-25T23:59:59.000Z

450

Novel Aryne Chemistry in Organic Synthesis  

SciTech Connect (OSTI)

Arynes are among the most intensively studied systems in chemistry. However, many aspects of the chemistry of these reactive intermediates are not well understood yet and their use as reagents in synthetic organic chemistry has been somewhat limited, due to the harsh conditions needed to generate arynes and the often uncontrolled reactivity exhibited by these species. Recently, o-silylaryl triflates, which can generate the corresponding arynes under very mild reaction conditions, have been found very useful in organic synthesis. This thesis describes several novel and useful methodologies by employing arynes, which generate from o-silylaryl triflates, in organic synthesis. An efficient, reliable method for the N-arylation of amines, sulfonamides and carbamates, and the O-arylation of phenols and carboxylic acids is described in Chapter 1. Amines, sulfonamides, phenols, and carboxylic acids are good nucleophiles, which can react with arynes generated from a-silylaryl triflates to afford the corresponding N- and O-arylated products in very high yields. The regioselectivity of unsymmetrical arynes has also been studied. A lot of useful, functional groups can tolerate our reaction conditions. Carbazoles and dibenzofurans are important heteroaromatic compounds, which have a variety of biological activities. A variety of substituted carbazoles and dibenzofwans are readily prepared in good to excellent yields starting with the corresponding o-iodoanilines or o-iodophenols and o-silylaryl triflates by a treatment with CsF, followed by a Pd-catalyzed cyclization, which overall provides a one-pot, two-step process. By using this methodology, the carbazole alkaloid mukonine has been concisely synthesized in a very good yield. Insertion of an aryne into a {sigma}-bond between a nucleophile and an electrophile (Nu-E) should potentially be a very beneficial process from the standpoint of organic synthesis. A variety of substituted ketones and sulfoxides have been synthesized in good yields via the intermolecular C-N {sigma}-bond addition of amides and S-N {sigma}-bond addition of sulfinamides to arynes under mild reaction conditions. The indazole moiety is a frequently found subunit in drug substances with important biological activities. Indazole analogues have been readily synthesized under mild reaction conditions by the [3+2] cycloaddition of a variety of diazo compounds with o-silylaryl triflates in the presence of CsF or TBAF. Polycyclic aromatic and heteroaromatic hydrocarbons have been synthesized in high yields by two different processes involving the Pd-catalyzed annulation of arynes. Both processes appear to involve the catalytic, stepwise coupling of two very reactive substrates, an aryne and an organopalladium species, to generate excellent yields of cross-coupled products.

Zhijian Liu

2006-12-12T23:59:59.000Z

451

High-Pressure Phase Equilibria of Ionic Liquids and Compressed Gases for Applications in Reactions and Absorption Refrigeration  

E-Print Network [OSTI]

of high-melting solids not liquids at processing conditions. Coupling ionic liquids with compressed gases systems may overcome most of these difficulties for their applications in separations, reactions, materials processing and engineering applications...

Ren, Wei

2009-12-29T23:59:59.000Z

452

PII S0016-7037(01)00802-X Volatilization kinetics of silicon carbide in reducing gases: An experimental study with  

E-Print Network [OSTI]

PII S0016-7037(01)00802-X Volatilization kinetics of silicon carbide in reducing gases occurring hexagonal sili- con carbide ( -SiC), and -SiC, the cubic form, are occasion- ally reported

Grossman, Lawrence

453

Methods for reducing emissions of dioxins and furans in flue gases at plants burning solid domestic waste  

Science Journals Connector (OSTI)

Methods are discussed for reducing emissions of toxic chlorinated dibenzo-dioxins and dibenzo-furans in flue gases at plants which burn solid domestic waste. Results are presented from a study of ... number of th...

A. N. Tugov; V. F. Moskvichev; L. G. Fedorovů

2009-01-01T23:59:59.000Z

454

Pulsed quantum cascade laser instrument with compact design for rapid, high sensitivity measurements of trace gases in air  

Science Journals Connector (OSTI)

We have developed a compact instrument for sensitive, rapid and continuous measurement of trace gases in air, with results presented here for methane (CH4), nitric oxide (NO), nitrous oxide (N2O) and ammonia (NH3

J.B. McManus; J.H. Shorter; D.D. Nelson; M.S. Zahniser; D.E. Glennů

2008-09-01T23:59:59.000Z

455

Coal-Fired Power Plants, Greenhouse Gases, and State Statutory Substantial Endangerment Provisions: Climate Change Comes to Kansas  

E-Print Network [OSTI]

economy standards on motor vehicles by states such as California. But the states have also targeted stationary sources of greenhouse gases. In particular, they have sought to minimize carbon dioxide emissions from coal-fired power plants. States have used...

Glicksman, Robert L.

2008-04-01T23:59:59.000Z

456

Hydrogeological studies on the mechanical behavior of landfill gases and leachate of the Nanjido Landfill in Seoul, Korea  

Science Journals Connector (OSTI)

?The Nanjido Landfill is the largest uncontrolled landfill in Korea and it causes various kinds of environmental problems. Landfill gases and leachate are recognized as the most serious environmental problems ass...

K. K. Lee; Y. Y. Kim; H. W. Chang; S. Y. Chung

1997-06-01T23:59:59.000Z

457

An analytical inversion method for determining regional and global emissions of greenhouse gases: Sensitivity studies and application to halocarbons  

E-Print Network [OSTI]

A new analytical inversion method has been developed to determine the regional and global emissions of long-lived atmospheric trace gases. It exploits in situ measurement data from three global networks and builds on ...

Stohl, A.

458

The atmospheric reactivity of. alpha. -methyltetrahydrofuran  

SciTech Connect (OSTI)

Biomass-derived {alpha}-methyltetrahydrofuran (MTHF) has been proposed as an automotive fuel additive. Since MTHF is a volatile organic compound, the environmental impact of evaporation to the atmosphere needs to be considered. The major loss process of MTHF in the atmosphere is expected to occur via reaction with hydroxyl radical; hence we have conducted a study of the kinetics of the reaction OH + MTHF {yields} products using both absolute (flash photolysis resonance fluorescence) and relative rate techniques. The absolute rate experiments were performed over the temperature range 240-400 K at total pressures of 35 Torr (4.7 kPa) argon; the relative rate experiments were conducted at 295 K in 740 Torr (99 kPa) synthetic air. The results from both techniques were in good agreement and yield k{sub 1} = (2.52 {plus minus} 0.74) {times} 10{sup {minus}12} exp-((650 {plus minus} 80)/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, with k{sub 1} (298 K) = 2.2 {times} 10{sup {minus}11} cm{sup 3} molecule{sup {minus}1}. The implications of these results for the atmospheric chemistry of MTHF are discussed.

Wallington, T.J.; Siegl, W.O. (Ford Motor Company, Dearborn, MI (USA)); Liu, Renzhang; Zhang, Zhengyu; Huie, R.E.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1990-10-01T23:59:59.000Z

459

Internal structure, hygroscopic and reactive properties of mixed sodium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Internal structure, hygroscopic and Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Print Friday, 13 May 2011 00:00 Scientists recently combined experimental approaches and molecular dynamics modeling to gain new insights into the internal structure of sea salt particles and relate it to their fundamental chemical reactivity in the atmosphere. This research shows that surface enhancement or depletion of chemical components in marine particles can occur because of the difference in the chemical nature of the species. Because the atmospheric chemistry of the salt particles takes place at the gas-particle interface, understanding their complex surfaces provides new insights about their effect on the environment and climate change. Article Link.

460

Ionic Liquids and Ionizing Radiation: Reactivity of Highly Energetic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ionizing Radiation: Reactivity of Highly Energetic Ionizing Radiation: Reactivity of Highly Energetic Species James F. Wishart J. Phys. Chem. Lett. 1, 3225-3231 (2010). [Find paper at ACS Publications] or use ACS Articles on Request View the video on this Perspective article at The Journal of Physical Chemistry Letters (5:03) Selected for the ACS Special Virtual Issue on Ionic Liquids (March 2011). Abstract: Due to their unique properties, ionic liquids present many opportunities for basic research on the interactions of radiation with materials under conditions not previously available. At the same time, there are practical applied reasons for characterizing, understanding, and being able to predict how ionic-liquid-based devices and industrial-scale systems will perform under conditions of extreme reactivity, including radiation. This

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Environmentally stable reactive alloy powders and method of making same  

DOE Patents [OSTI]

Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

1998-09-22T23:59:59.000Z

462

Options for Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic(PV) generation on an electrical distribution circuit present several challenges and opportunities for distribution utilities. Rapidly varying irradiance conditions may cause voltage sags and swells that cannot be compensated by slowly responding utility equipment resulting in a degradation of power quality. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We discuss and compare via simulation various design options for control systems to manage the reactive power generated by these inverters. An important design de...

Sulc, Petr; Backhaus, Scott; Chertkov, Michael

2010-01-01T23:59:59.000Z

463

Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework  

SciTech Connect (OSTI)

Cerium compounds have played vital roles in organic, inorganic, and materials chemistry due to their reversible redox chemistry between trivalent and tetravalent oxidation states. However, attempts to rationally access molecular cerium complexes in both oxidation states have been frustrated by unpredictable reactivity in cerium(III) oxidation chemistry. Such oxidation reactions are limited by steric saturation at the metal ion, which can result in high energy activation barriers for electron transfer. An alternative approach has been realized using a rare earth/alkali metal/1,1'-BINOLate (REMB) heterobimetallic framework, which uses redox-inactive metals within the secondary coordination sphere to control ligand reorganization. The rational syntheses of functionalized cerium(IV) products and a mechanistic examination of the role of ligand reorganization in cerium(III) oxidation are presented.

Robinson, Jerome R.; Gordon, Zachary; Booth, Corwin H.; Carroll, Patrick J.; Walsh, Patrick J.; Schelter, Eric J.

2014-06-24T23:59:59.000Z

464

Design and synthesis of reactive separation systems. Final report  

SciTech Connect (OSTI)

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-12-31T23:59:59.000Z

465

Mixed crystal organic scintillators  

DOE Patents [OSTI]

A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

2014-09-16T23:59:59.000Z

466

Reactivity and Transformation of Antibacterial N-Oxides in the  

E-Print Network [OSTI]

shown in Figure 1) represent organic N-oxides that are common in many pharmaceuticals, agrochemicals

Huang, Ching-Hua

467

Non-Energetic Reactive Armor (NERA) and Semi-Energetic Reactive Armor (SERA) FY13 Final Report  

SciTech Connect (OSTI)

INL researchers have proposed prototypes for future lightweight armor systems that reside in a technology gap between explosive reactive armor and passive armor. The targets were designed to react under impact and throw a steel front plate into the path of the projectile, forcing the projectile to engage more of the front plate during its penetration process. These prototypes are intended to exhibit the enhanced efficiency of explosive reactive armor without the collateral damage often associated with explosive reactive armor. One of the prototype systems, Semi Energetic Reactive Armor (SERA), functions similarly to explosive reactive armor, but features a reactive material that reacts much slower than explosive reactive armor. Two different SERA test groups were built and featuring different ratios of aluminum Teflon(copyright) powders pressed into 0.5 in. thick energetic tiles and sandwiched between 0.25 in. thick RHA plates. The other prototype system, Non Energetic Reactive Armor (NERA), utilizes the strain energy in compressed rubber to launch a front flyer plate into the path of an incoming projectile. It is comprised of a 1 in. thick rubber layer sandwiched between two 0.25 in. thick RHA plates with bolt holes around the perimeter. Bolts are inserted through the entire target and tightened to compress the rubber sheet to significant strain levels (approximately 40%). A fourth group of targets was tested as a control group. It featured a 0.5 in. thick rubber sheet sandwiched between two 0.25 in. thick RHA plates, similar to the NERA test articles, but the rubber is uncompressed. The four test groups (uncompressed rubber, compressed rubber, 70/30 Al/PTFE, 50/50 Al/PTFE) were each fabricated with three identical test articles in each group. All twelve targets were subjected to ballistic testing at the National Security Test Range on July 17, 2013. They were tested with 0.5 in. diameter steel rods shot at a consistent velocity at each target. In order to characterize the energetic materials, break wires were embedded in the targets and burn velocities were measured. The residual mass method was used to compare the target performance of each group and final performance data is presented below.

Ben Langhorst; Nikki Rasmussen; Andrew Robinson

2013-08-01T23:59:59.000Z

468

Semitransparent organic solar cells  

Science Journals Connector (OSTI)

The organic solar cell technology has attracted great interests due to ... low cost solution process capability. Bulk heterojunction organic solar cells offer a potentially much cheaper alternative way to harness...

Furong Zhu

2014-03-01T23:59:59.000Z

469

Reactive Search Optimization: Learning while Roberto Battiti and Mauro Brunato  

E-Print Network [OSTI]

Reactive Search Optimization: Learning while Optimizing Roberto Battiti and Mauro Brunato 1, Universit`a di Trento, Italy, e-mail: roberto.battiti@unitn.it Mauro Brunato LION Lab, Universit`a di Trento, Italy, e-mail: mauro.brunato@unitn.it 1 #12;2 Roberto Battiti and Mauro Brunato in the loop between

Battiti, Roberto

470

Toward a new paradigm for reactive flow modeling.  

SciTech Connect (OSTI)

Traditional reactive flow modeling provides a computational representation of shock initiation of energetic materials. Most reactive flow models require ad hoc assumptions to obtain robust simulations, assumptions that result from partitioning energy and volume change between constituents in a reactive mixture. For example, most models assume pressure and/or temperature equilibrium for the mixture. Many mechanical insults to energetic materials violate these approximations. Careful analysis is required to ensure that the model assumptions and limitations are not exceeded. One limitation is that the shock to detonation transition is replicated only for strong planar shocks. Many models require different parameters to match data from thin pulse, ramp wave, or multidimensional loading, an approach that fails for complex loading. To accurately simulate reaction under non-planar shock impact scenarios a new formalism is required. The continuum mixture theory developed by Baer and Nunziato is used to eliminate ad hoc assumptions and limitations of current reactive flow models. This modeling paradigm represents the multiphase nature of reacting condensed/gas mixtures. Comparisons between simulations and data are presented.

Schmitt, Robert Gerard

2005-08-01T23:59:59.000Z

471

Resilient Intrusion Tolerance through Proactive and Reactive Recovery  

E-Print Network [OSTI]

system's correct operation. We design a proactive- reactive recovery service based on a hybrid the resilience of an intrusion-tolerant firewall adequate for the protection of critical infrastructures infras- tructures like the Power grid. One approach that promises to satisfy this requirement

Neves, Nuno

472

Voltage Regulation through Smart Utilization of Potential Reactive Power Resources  

Science Journals Connector (OSTI)

The introduction of demand response concept, in addition to increment of penetration of distributed generation (DG) based on renewable energies, make opportunities for the novel control schemes to be integrated in power system on a smart grid framework. ... Keywords: Demand response, distributed generation, reactive power, renewable energy, smart grid, voltage control

H. Kazari; A. Abbaspour-Tehrani Fard; A. S. Dobakhshari; A. M. Ranjbar

2011-11-01T23:59:59.000Z

473

Substituent Effects on the Reactivity of the Silicon-Carbon  

E-Print Network [OSTI]

Canada L8S 4M1 Received April 28, 2000 ABSTRACT Laser flash photolysis of various organosilicon compounds as a reactive intermediate in the high-temperature pyrolysis of a silacyclobutane deriva- tive.9 Hundreds describes our efforts to employ these techniquess laser flash photolysis methods in particularsto study

Leigh, William J.

474

Surface tension in a reactive binary mixture of incompressible fluids  

E-Print Network [OSTI]

Surface tension in a reactive binary mixture of incompressible fluids Henning Struchtrup Institute with a distributed form of surface tension. The model describes chemistry, diffusion, viscosity and heat transfer tension at the front. Keywords: Binary mixtures, Surface tension, Irreversible thermodynamics, Hele

Struchtrup, Henning

475

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may depend are combined is certainly not arbitrary. For instance, the repetition of one cycle may rely on the repetitionsDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Leue, Stefan

476

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

processes of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may in which cycle executions are combined is certainly not arbitrary. For instance, the repetition of oneDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Reiterer, Harald

477

Effect of Number of Fractionating Trays on Reactive Distillation Performance  

E-Print Network [OSTI]

Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

Al-Arfaj, Muhammad A.

478

Reactive materials can quickly form plugs for blowout control  

SciTech Connect (OSTI)

Various types of reactive materials, or gunk, can react directly with produced fluids (oil, condensate, or brine) or with an additionally injected fluid to form a plug to kill blowout wells or shut off large flow paths. Several recent blowouts were successfully controlled with reactive plugs; other conventional methods would have been more difficult operationally and cost more. Several plug mixtures are available on the market and can be made to suit the type of application and any particular environmental concerns. With proper planning and application, reactive plugs should be considered as a prime well control method when injection into the blowout flow path is available. This method of blowout control can save significant time and expense. The paper discusses the two basic methods of using reactive fluids depending on the flow path available, the use of cements, application steps, environmental concerns, and three case histories: a horizontal well in Texas, a high pressure, high temperature well offshore Louisiana, and a gas blowout in Argentina.

Flak, L.H. [Wright Boots and Coots, Houston, TX (United States)

1995-04-17T23:59:59.000Z

479

Neutron economic reactivity control system for light water reactors  

DOE Patents [OSTI]

A neutron reactivity control system for a LWBR incorporating a stationary seed-blanket core arrangement. The core arrangement includes a plurality of contiguous hexagonal shaped regions. Each region has a central and a peripheral blanket area juxapositioned an annular seed area. The blanket areas contain thoria fuel rods while the annular seed area includes seed fuel rods and movable thoria shim control rods.

Luce, Robert G. (Glenville, NY); McCoy, Daniel F. (Latham, NY); Merriman, Floyd C. (Rotterdam, NY); Gregurech, Steve (Scotia, NY)

1989-01-01T23:59:59.000Z

480

Generalized Chemical Reactivity of Curved Surfaces: Carbon Nanotubes  

E-Print Network [OSTI]

. Following the decomposition, the total reaction energy Etotal, which is the index of chemical reactivity, can be divided into three terms: strain energy Estrain, C-X binding energy EC-X, and global relaxation in a CNT can enhance the hydrogenation energy at the location of the excess deformation so

Srivastava, Deepak

Note: This page contains sample records for the topic "reactive organic gases" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Local control of reactive power by distributed photovoltaic generators  

SciTech Connect (OSTI)

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the real power generated by the PVs. Using one adjustable parameter per circuit, we balance the requirements on power quality and desire to minimize thermal losses. Numerical analysis of two exemplary systems, with comparable total PV generation albeit a different spatial distribution, show how to adjust the optimization parameter depending on the goal. Overall, this local scheme shows excellent performance; it's capable of guaranteeing acceptable power quality and achieving significant saving in thermal losses in various situations even when the renewable generation in excess of the circuit own load, i.e. feeding power back to the higher-level system.

Chertkov, Michael [Los Alamos National Laboratory; Turitsyn, Konstantin [Los Alamos National Laboratory; Sulc, Petr [Los Alamos National Laboratory; Backhaus, Scott [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

482

Sleep & Memory/Review Memory reactivation and consolidation during sleep  

E-Print Network [OSTI]

Sleep & Memory/Review Memory reactivation and consolidation during sleep Ken A. Paller1 and Joel L, Illinois 60208-2710, USA Do our memories remain static during sleep, or do they change? We argue here that memory change is not only a natural result of sleep cognition, but further, that such change constitutes

Paller, Ken

483

Organic photosensitive devices  

DOE Patents [OSTI]

The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photosensitive optoelectronic devices having a photoactive organic region containing encapsulated nanoparticles that exhibit plasmon resonances. An enhancement of the incident optical field is achieved via surface plasmon polariton resonances. This enhancement increases the absorption of incident light, leading to a more efficient device.

Rand, Barry P; Forrest, Stephen R

2013-11-26T23:59:59.000Z

484

Relevance of Bose-Einstein condensation to the interference of two independent Bose gases  

SciTech Connect (OSTI)

Interference of two independently prepared ideal Bose gases is discussed, on the basis of the idea of measurement-induced interference. It is known that, even if the number of atoms in each gas is individually fixed finite and the symmetry of the system is not broken, an interference pattern is observed on each single snapshot. The key role is played by the Hanbury Brown and Twiss effect, which leads to an oscillating pattern of the cloud of identical atoms. Then, how essential is the Bose-Einstein condensation to the interference? In this work, we describe two ideal Bose gases trapped in two separate three-dimensional harmonic traps at a finite temperature T, using the canonical ensembles (with fixed numbers of atoms). We compute the full statistics of the snapshot profiles of the expanding and overlapping gases released from the traps. We obtain a simple formula valid for finite T, which shows that the average fringe spectrum (average fringe contrast) is given by the purity of each gas. The purity is known to be a good measure of condensation, and the formula clarifies the relevance of the condensation to the interference. The results for T=0, previously known in the literature, can be recovered from our analysis. The fluctuation of the interference spectrum is also studied, and it is shown that the fluctuation is vanishingly small only below the critical temperature T{sub c}, meaning that interference pattern is certainly observed on every snapshot below T{sub c}. The fact that the number of atoms is fixed in the canonical ensemble is crucial to this vanishing fluctuation.

Iazzi, Mauro [International School for Advanced Studies (SISSA), via Beirut 2-4, I-34014 Trieste (Italy); Yuasa, Kazuya [Waseda Institute for Advanced Study, Waseda University, Tokyo 169-8050 (Japan)

2011-03-15T23:59:59.000Z

485

Relevance of Bose-Einstein condensation to the interference of two independent Bose gases  

Science Journals Connector (OSTI)

Interference of two independently prepared ideal Bose gases is discussed, on the basis of the idea of measurement-induced interference. It is known that, even if the number of atoms in each gas is individually fixed finite and the symmetry of the system is not broken, an interference pattern is observed on each single snapshot. The key role is played by the Hanbury Brown and Twiss effect, which leads to an oscillating pattern of the cloud of identical atoms. Then, how essential is the Bose-Einstein condensation to the interference? In this work, we describe two ideal Bose gases trapped in two separate three-dimensional harmonic traps at a finite temperature T, using the canonical ensembles (with fixed numbers of atoms). We compute the full statistics of the snapshot profiles of the expanding and overlapping gases released from the traps. We obtain a simple formula valid for finite T, which shows that the average fringe spectrum (average fringe contrast) is given by the purity of each gas. The purity is known to be a good measure of condensation, and the formula clarifies the relevance of the condensation to the interference. The results for T=0, previously known in the literature, can be recovered from our analysis. The fluctuation of the interference spectrum is also studied, and it is shown that the fluctuation is vanishingly small only below the critical temperature Tc, meaning that interference pattern is certainly observed on every snapshot below Tc. The fact that the number of atoms is fixed in the canonical ensemble is crucial to this vanishing fluctuation.

Mauro Iazzi and Kazuya Yuasa

2011-03-14T23:59:59.000Z

486

Shear viscosity and spin sum rules in strongly interacting Fermi gases  

E-Print Network [OSTI]

Fermi gases with short-range interactions are ubiquitous in ultracold atomic systems. In the absence of spin-flipping processes the number of atoms in each spin species is conserved separately, and we discuss the associated Ward identities. For contact interactions the spin conductivity spectral function sigma_s(omega) has universal power-law tails at high frequency. We derive the spin f-sum rule and show that it is not affected by these tails in dviscosity spectral function eta(omega) has universal tails; in contrast they modify the viscosity sum rule in a characteristic way.

Tilman Enss

2012-09-14T23:59:59.000Z

487

Finite-temperature phase transitions in quasi-two-dimensional spin-1 Bose gases  

SciTech Connect (OSTI)

Recently, the Berezinskii-Kosterlitz-Thouless transition was found to be mediated by half-quantum vortices (HQVs) in two-dimensional (2D) antiferromagnetic Bose gases [S. Mukerjee, C. Xu, and J. E. Moore, Phys. Rev. Lett. 97, 120406 (2006)]. We study the thermal activation of HQVs in the experimentally relevant trapped quasi-2D system and find a crossover temperature at which free HQVs proliferate at the center of the trap. Above the crossover temperature, we observe transitions corresponding to the onset of a coherent condensate and a quasicondensate and discuss the absence of a fragmented condensate.

Pietilae, Ville [Department of Applied Physics/COMP, Aalto University, Post Office Box 15100, FI-00076 Aalto (Finland); Australian Research Council Centre of Excellence for Quantum Computer Technology, School of Electrical Engineering and Telecommunications, University of New South Wales, Sydney NSW 2052 (Australia); Simula, Tapio P. [Department of Physics, Okayama University, Okayama 700-8530 (Japan); School of Physics, Monash University, Victoria 3800 (Australia); Moettoenen, Mikko [Department of Applied Physics/COMP, Aalto University, Post Office Box 15100, FI-00076 Aalto (Finland); Australian Research Council Centre of Excellence for Quantum Computer Technology, School of Electrical Engineering and Telecommunications, University of New South Wales, Sydney NSW 2052 (Australia); Low Temperature Laboratory, Aalto University, Post Office Box 13500, FI-00076 Aalto (Finland)

2010-03-15T23:59:59.000Z

488

Critical behavior of two freely evolving granular gases separated by an adiabatic piston  

E-Print Network [OSTI]

Two granular gases separated by an adiabatic piston and initially in the same macroscopic state are considered. It is found that a phase transition with an spontaneous symmetry breaking occurs. When the mass of the piston is increased beyond a critical value, the piston moves to a stationary position different from the middle of the system. The transition is accurately described by a simple kinetic model that takes into account the velocity fluctuations of the piston. Interestingly, the final state is not characterized by the equality of the temperatures of the subsystems but by the cooling rates being the same. Some relevant consequences of this feature are discussed.

J. Javier Brey; Nagi Khalil

2010-09-23T23:59:59.000Z

489

Overview of the Flammability of Gases Generated in Hanford Waste Tanks  

SciTech Connect (OSTI)

This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

2000-07-21T23:59:59.000Z

490

Organic Light Emitters Gain Longevity  

Science Journals Connector (OSTI)

...power and reactive-gas partial-pressure...1970s to enhance the life of cutting tools and...can enhance the life of rolling ele-ments...big enough to coat life-size components such as drill bits or turbine blades, which is...pressure of the reactive gas (nitrogen) was used...

Robert F. Service

1996-08-16T23:59:59.000Z

491

Organization | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Organization Organization Organization Office of Indian Energy Organizational Structure As a program office at DOE responsible for implementing energy programs, the Office of Indian Energy is structurally organized under the Office of the Under Secretary. This programmatic structure also focuses and facilitates the coordination between the Office of Indian Energy and the other companion program offices such as the Office of Fossil Energy, Office of Electricity and Energy Reliability and Office of Energy Efficiency and Renewable Energy. The Office of Indian Energy is organized around its major statutory functions, namely, policy and programs: Indian Energy Policy. The Office of Indian Energy coordinates participation in the development, refinement, training, and advice

492

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Broader source: Energy.gov (indexed) [DOE]

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Ca├▒on City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Ca├▒on City, Colorado, Uranium Mill Final Report Phase II: Performance Evaluation of Permeable Reactive

493

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Broader source: Energy.gov (indexed) [DOE]

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Ca├▒on City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Ca├▒on City, Colorado, Uranium Mill Phase II: Performance Evaluation of Permeable Reactive Barriers and

494

Photoluminescent silicon nanocrystals synthesized by reactive laser Daria Riabinina,a  

E-Print Network [OSTI]

Photoluminescent silicon nanocrystals synthesized by reactive laser ablation Daria Riabinina reactive laser ablation in oxygen atmosphere followed by annealing. We observe a strong photoluminescence size, obtained independently by fitting photoluminescence spectra and from x-ray diffraction patterns

495

Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel  

Broader source: Energy.gov [DOE]

This study uses numerical simulations to explore the use of wet ethanol as the low-reactivity fuel and diesel as the high-reactivity fuel for RCCI operation in a heavy-duty diesel engine.

496

Bioinformatic analysis of xenobiotic reactive metabolite target proteins and their interacting partners  

E-Print Network [OSTI]

Background Protein covalent binding by reactive metabolites of drugs, chemicals and natural products can lead to acute cytotoxicity. Recent rapid progress in reactive metabolite target protein identification has shown ...

Hanzlik, Robert P.; Fang, Jianwen; Koen, Yakov M.

2009-06-12T23:59:59.000Z

497

Chemical Reactivity of Reduced TiO2(110): The dominant role of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

498

Effect of Terrestrial and Marine Organic Aerosol on Regional and Global Climate: Model Development, Application, and Verification with Satellite Data  

SciTech Connect (OSTI)

In this DOE project the improvements to parameterization of marine primary organic matter (POM) emissions, hygroscopic properties of marine POM, marine isoprene derived secondary organic aerosol (SOA) emissions, surfactant effects, new cloud droplet activation parameterization have been implemented into Community Atmosphere Model (CAM 5.0), with a seven mode aerosol module from the Pacific Northwest National Laboratory (PNNL)├?┬?├?┬ó├?┬?├?┬?├?┬?├?┬?s Modal Aerosol Model (MAM7). The effects of marine aerosols derived from sea spray and ocean emitted biogenic volatile organic compounds (BVOCs) on microphysical properties of clouds were explored by conducting 10 year CAM5.0-MAM7 model simulations at a grid resolution 1.9├?┬?├?┬?├?┬?├?┬░├?┬?├?┬?├?┬?├?┬?2.5├?┬?├?┬?├?┬?├?┬░ with 30 vertical layers. Model-predicted relationship between ocean physical and biological systems and the abundance of CCN in remote marine atmosphere was compared to data from the A-Train satellites (MODIS, CALIPSO, AMSR-E). Model simulations show that on average, primary and secondary organic aerosol emissions from the ocean can yield up to 20% increase in Cloud Condensation Nuclei (CCN) at 0.2% Supersaturation, and up to 5% increases in droplet number concentration of global maritime shallow clouds. Marine organics were treated as internally or externally mixed with sea salt. Changes associated with cloud properties reduced (absolute value) the model-predicted short wave cloud forcing from -1.35 Wm-2 to -0.25 Wm-2. By using different emission scenarios, and droplet activation parameterizations, this study suggests that addition of marine primary aerosols and biologically generated reactive gases makes an important difference in radiative forcing assessments. All baseline and sensitivity simulations for 2001 and 2050 using global-through-urban WRF/Chem (GU-WRF) were completed. The main objective of these simulations was to evaluate the capability of GU-WRF for an accurate representation of the global atmosphere by exploring the most accurate configuration of physics options in GWRF for global scale modeling in 2001 at a horizontal grid resolution of 1├?┬?├?┬?├?┬?├?┬░ x 1├?┬?├?┬?├?┬?├?┬░. GU-WRF model output was evaluated using observational datasets from a variety of sources including surface based observations (NCDC and BSRN), model reanalysis (NCEP/ NCAR Reanalysis and CMAP), and remotely-sensed data (TRMM) to evaluate the ability of GU-WRF to simulate atmospheric variables at the surface as well as aloft. Explicit treatment of nanoparticles produced from new particle formation in GU-WRF/Chem-MADRID was achieved by expanding particle size sections from 8 to 12 to cover particles with the size range of 1.16 nm to 11.6 ├?┬?├?┬?├?┬?├?┬Ám. Simulations with two different nucleation parameterizations were conducted for August 2002 over a global domain at a 4├?┬?├?┬?├?┬?├?┬║ by 5├?┬?├?┬?├?┬?├?┬║ horizontal resolution. The results are evaluated against field measurement data from the 2002 Aerosol Nucleation and Real Time Characterization Experiment (ANARChE) in Atlanta, Georgia, as well as satellite and reanalysis data. We have also explored the relationship between ├?┬?├?┬ó├?┬?├?┬?├?┬?├?┬?clean marine├?┬?├?┬ó├?┬?├?┬?├?┬?├?┬Ł aerosol optical properties and ocean surface wind speed using remotely sensed data from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) on board the CALIPSO satellite and the Advanced Microwave Scanning Radiometer (AMSR-E) on board the AQUA satellite. Detailed data analyses

Meskhidze, Nicholas; Zhang, Yang; Kamykowski, Daniel

2012-03-28T23:59:59.000Z

499

E-Print Network 3.0 - advected reactive scalars Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

through... reactive scalars that are initially distinct, ... Source: Crimaldi, John P. - Department of Civil, Environmental, and Architectural Engineering, University of...

500

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal g