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1

HYDROGEOCHEM: A coupled model of HYDROlogic transport and GEOCHEMical equilibria in reactive multicomponent systems  

SciTech Connect (OSTI)

This report presents the development of a hydrogeochemical transport model for multicomponent systems. The model is designed for applications to proper hydrological setting, accommodation of complete suite of geochemical equilibrium processes, easy extension to deal with chemical kinetics, and least constraints of computer resources. The hydrological environment to which the model can be applied is the heterogeneous, anisotropic, saturated-unsaturated subsurface media under either transient or steady state flow conditions. The geochemical equilibrium processes included in the model are aqueous complexation, adsorption-desorption, ion exchange, precipitation-dissolution, redox, and acid-base reactions. To achieve the inclusion of the full complement of these geochemical processes, total analytical concentrations of all chemical components are chosen as the primary dependent variables in the hydrological transport equations. Attendant benefits of this choice are to make the extension of the model to deal with kinetics of adsorption-desorption, ion exchange, precipitation-dissolution, and redox relatively easy. To make the negative concentrations during the iteration between the hydrological transport and geochemical equilibrium least likely, an implicit form of transport equations are proposed. To alleviate severe constraints of computer resources in terms of central processing unit (CPU) time and CPU memory, various optional numerical schemes are incorporated in the model. The model consists of a hydrological transport module and geochemical equilibrium module. Both modules were thoroughly tested in code consistency and were found to yield plausible results. The model is verified with ten examples. 79 refs., 21 figs., 17 tabs.

Yeh, G.T.; Tripathi, V.S.

1990-11-01T23:59:59.000Z

2

Modeling biogechemical reactive transport in a fracture zone  

SciTech Connect (OSTI)

A coupled model of groundwater flow, reactive solute transport and microbial processes for a fracture zone of the Aspo site at Sweden is presented. This is the model of the so-called Redox Zone Experiment aimed at evaluating the effects of tunnel construction on the geochemical conditions prevailing in a fracture granite. It is found that a model accounting for microbially-mediated geochemical processes is able to reproduce the unexpected measured increasing trends of dissolved sulfate and bicarbonate. The model is also useful for testing hypotheses regarding the role of microbial processes and evaluating the sensitivity of model results to changes in biochemical parameters.

Molinero, Jorge; Samper, Javier; Yang, Chan Bing, and Zhang, Guoxiang; Guoxiang, Zhang

2005-01-14T23:59:59.000Z

3

Advective diffusive/dispersive transport in geochemical processes  

SciTech Connect (OSTI)

Comprehensive understanding of chemical transport in response to fluid flow and diffusion in geologic processes requires thermodynamic and transport properties of a wide variety of aqueous species at the temperature and pressure of interest, as well as mass transfer computer codes that provide simultaneously for fluid flow, diffusion, dispersion, homogeneous chemical reactions, and mineral solubilities. As a result of research carried out with support from DOE in prior years of this grant, considerable progress has been made in developing computer codes to calculate advective-dispersive-diffusional transport at both high and low pressures and temperatures. These codes have become highly sophisticated, but their application to geochemical processes is limited by the availability of thermodynamic and transport data for the major solute species in the aqueous phase. Over the past three years, research has been directed primarily toward characterizing the thermodynamic behavior of concentrated supercritical aqueous electrolyte solutions and predicting the diffusion coefficients of organic species in oil field brines. Related research has been concerned with characterizing the growth rate of hydrothermal alteration zones and assessing the relative importance of aqueous diffusion and heterogeneous reactions at mineral surfaces in geochemical processes. 103 refs., 12 figs.

Helgeson, H.C.

1991-05-28T23:59:59.000Z

4

STOMP-ECKEChem: An Engineering Perspective on Reactive Transport in Geologic Media  

SciTech Connect (OSTI)

ECKEChem (Equilibrium, Conservation, Kinetic Equation Chemistry) is a reactive transport module for the STOMP suite of multifluid subsurface flow and transport simulators that was developed from an engineering perspective. STOMP comprises a suite of operational modes that are distinguished by the solved coupled conservation equations with capabilities for a variety of subsurface applications (e.g., environmental remediation and stewardship, geologic sequestration of greenhouse gases, gas hydrate production, and oil shale production). The ECKEChem module was designed to provide integrated reactive transport capabilities across the suite of STOMP simulator operational modes. The initial application for the ECKEChem module was in the simulation of the mineralization reactions that occurred with the injection of supercritical carbon dioxide into deep Columbia River basalt formations, where it was implemented in the STOMP-CO2 simulator. The STOMP-ECKEChem solution approach to modeling reactive transport in multifluid geologic media is founded on an engineering perspective: (1) sequential non-iterative coupling between the flow and reactive transport is sufficient, (2) reactive transport can be modeled by operator splitting with local geochemistry and global transport, (3) geochemistry can be expressed as a system of coupled nonlinear equilibrium, conservation and kinetic equations, (4) a limited number of kinetic equation forms are used in geochemical practice. This chapter describes the conceptual approach to converting a geochemical reaction network into a series of equilibrium, conservation and kinetic equations, the implementation of ECKEChem in STOMP, the numerical solution approach, and a demonstration of the simulator on a complex application involving desorption of uranium from contaminated field-textured sediments.

White, Mark D.; Fang, Yilin

2012-04-04T23:59:59.000Z

5

Review of existing reactive transport software  

SciTech Connect (OSTI)

Simulations of thermal and hydrological evolution following the potential emplacement of a subterranean nuclear waste repository at Yucca Mountain, NV provide data that suggest the inevitability of dependent, simultaneous chemical evolution in this system. These chemical changes will modify significantly both the magnitude and structure of local porosity and permeability; hence, they will have a dynamic feedback effect on the evolving thermal and hydrological regime. Yet, despite this intimate interdependence of transport and chemical processes, a rigorous quantitative analysis of the post- emplacement environment that incorporates this critical feedback mechanism has not been completed to date. As an initial step in this direction, the present document outlines the fundamental chemical and transport processes that must be accounted for in such an analysis, and reviews the inventory of existing software that encodes these processed in explicitly coupled form. A companion report describes the prioritization of specific capabilities that are needed for modeling post-emplacement reactive transport at Yucca Mountain.

Glassley, W., LLNL

1998-02-03T23:59:59.000Z

6

Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation  

SciTech Connect (OSTI)

Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH{sub 4}{sup +} production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface.

Wu, Y.; Ajo-Franklin, J.B.; Spycher, N.; Hubbard, S.S.; Zhang, G.; Williams, K.H.; Taylor, J.; Fujita, Y.; Smith, R.

2011-07-15T23:59:59.000Z

7

Geochemical factors affecting radionuclide transport through near and far fields at a Low-Level Waste Disposal Site  

SciTech Connect (OSTI)

The concentration of low-level waste (LLW) contaminants in groundwater is determined by the amount of contaminant present in the solid waste, rate of release from the waste and surrounding barriers, and a number of geochemical processes including adsorption, desorption, diffusion, precipitation, and dissolution. To accurately predict radionuclide transport through the subsurface, it is essential that the important geochemical processes affecting radionuclide transport be identified and, perhaps more importantly, accurately quantified and described in a mathematically defensible manner.

Kaplan, D.I.; Seme, R.J. [Pacific Northwest Lab., Richland, WA (United States); Piepkho, M.G. [Westinghouse Hanford Co., Richland, WA (United States)

1995-03-01T23:59:59.000Z

8

Reactive transport model for the ambient unsaturated hydrogeochemical system at Yucca mountain, Nevada  

Science Journals Connector (OSTI)

To assist a technical review of a potential application for a geologic repository, a reactive transport model is presented for the ambient hydrogeochemical system at Yucca Mountain (YM). The model simulates two-phase, nonisothermal, advective and diffusive ... Keywords: Yucca mountain, geochemistry, groundwater chemistry, groundwater flow and transport, hydrology, reactive transport model, unsaturated zone

Lauren Browning; William M. Murphy; Chandrika Manepally; Randall Fedors

2003-04-01T23:59:59.000Z

9

Final Report Coupling in silico microbial models with reactive transport models to predict the fate of contaminants in the subsurface.  

SciTech Connect (OSTI)

This project successfully accomplished its goal of coupling genome-scale metabolic models with hydrological and geochemical models to predict the activity of subsurface microorganisms during uranium bioremediation. Furthermore, it was demonstrated how this modeling approach can be used to develop new strategies to optimize bioremediation. The approach of coupling genome-scale metabolic models with reactive transport modeling is now well enough established that it has been adopted by other DOE investigators studying uranium bioremediation. Furthermore, the basic principles developed during our studies will be applicable to much broader investigations of microbial activities, not only for other types of bioremediation, but microbial metabolism in diversity of environments. This approach has the potential to make an important contribution to predicting the impact of environmental perturbations on the cycling of carbon and other biogeochemical cycles.

Lovley, Derek R.

2012-10-31T23:59:59.000Z

10

Multicomponent reactive transport modeling at the Ratones uranium mine, Cceres (Spain)  

E-Print Network [OSTI]

Multicomponent reactive transport modeling at the Ratones uranium mine, Cáceres (Spain) Modelación management. The Ratones uranium mine was abandoned and flooded in 1974. Due to its reducing underground water, uranium, reactive transport, granite hydrochemistry, Ratones mine. Resumen La inundación de minas

Politècnica de Catalunya, Universitat

11

Reactive Transport Modeling of Acid Gas Generation and Condensation  

SciTech Connect (OSTI)

Pulvirenti et al. (2004) recently conducted a laboratory evaporation/condensation experiment on a synthetic solution of primarily calcium chloride. This solution represents one potential type of evaporated pore water at Yucca Mountain, Nevada, a site proposed for geologic storage of high-level nuclear waste. These authors reported that boiling this solution to near dryness (a concentration factor >75,000 relative to actual pore waters) leads to the generation of acid condensate (pH 4.5) presumably due to volatilization of HCl (and minor HF and/or HNO{sub 3}). To investigate the various processes taking place, including boiling, gas transport, and condensation, their experiment was simulated by modifying an existing multicomponent and multiphase reactive transport code (TOUGHREACT). This code was extended with a Pitzer ion-interaction model to deal with high ionic strength. The model of the experiment was set-up to capture the observed increase in boiling temperature (143 C at {approx}1 bar) resulting from high concentrations of dissolved salts (up to 8 m CaCl{sub 2}). The computed HCI fugacity ({approx} 10{sup -4} bars) generated by boiling under these conditions is not sufficient to lower the pH of the condensate (cooled to 80 and 25 C) down to observed values unless the H{sub 2}O mass fraction in gas is reduced below {approx}10%. This is because the condensate becomes progressively diluted by H{sub 2}O gas condensation. However, when the system is modeled to remove water vapor, the computed pH of instantaneous condensates decreases to {approx}1.7, consistent with the experiment (Figure 1). The results also show that the HCl fugacity increases, and calcite, gypsum, sylvite, halite, MgCl{sub 2}4H{sub 2}O and CaCl{sub 2} precipitate sequentially with increasing concentration factors.

G. Zhahg; N. Spycher; E. Sonnenthal; C. Steefel

2005-01-25T23:59:59.000Z

12

Chemically Reactive Working Fluids for the Capture and Transport...  

Broader source: Energy.gov (indexed) [DOE]

Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working Fluids Low-Cost Light Weigh Thin Film Solar Concentrators...

13

Influence of calcite on uranium(VI) reactive transport in the groundwaterriver mixing zone  

SciTech Connect (OSTI)

Calcite is an important mineral that can affect uranyl reactive transport in subsurface sediments. This study investigated the distribution of calcite and its influence on uranyl adsorption and reactive transport in the groundwater-river mixing zone at US Hanford 300A, Washington State. Simulations using a 2D reactive transport model under field-relevant hydrogeochemical conditions revealed a complex distribution of calcite concentration as a result of dynamic groundwater-river interactions. The calcite concentration distribution in turn affected the spatial and temporal changes in aqueous carbonate, calcium, and pH, which subsequently influenced U(VI) mobility and discharge rates into the river. The results implied that calcite distribution and its concentration dynamics is an important consideration for field characterization, monitoring, and reactive transport prediction.

Ma, Rui; Liu, Chongxuan; Greskowiak, Janek; Prommer, Henning; Zachara, John M.; Zheng, Chunmiao

2014-01-23T23:59:59.000Z

14

INEEL Subregional Conceptual Model Report Volume 2: Summary of Existing Knowledge of Geochemical Influences on the Fate and Transport of Contaminants in the Subsurface at the INEEL  

SciTech Connect (OSTI)

This document summarizes previous descriptions of geochemical system conceptual models for the vadose zone and groundwater zone (aquifer) beneath the Idaho National Engineering and Environmental Laboratory (INEEL). The primary focus is on groundwater because contaminants derived from wastes disposed at INEEL are present in groundwater, groundwater provides a pathway for potential migration to receptors, and because geochemical characteristics in and processes in the aquifer can substantially affect the movement, attenuation, and toxicity of contaminants. The secondary emphasis is perched water bodies in the vadose zone. Perched water eventually reaches the regional groundwater system, and thus processes that affect contaminants in the perched water bodies are important relative to the migration of contaminants into groundwater. Similarly, processes that affect solutes during transport from nearsurface disposal facilities downward through the vadose zone to the aquifer are relevant. Sediments in the vadose zone can affect both water and solute transport by restricting the downward migration of water sufficiently that a perched water body forms, and by retarding solute migration via ion exchange. Geochemical conceptual models have been prepared by a variety of researchers for different purposes. They have been published in documents prepared by INEEL contractors, the United States Geological Survey (USGS), academic researchers, and others. The documents themselves are INEEL and USGS reports, and articles in technical journals. The documents reviewed were selected from citation lists generated by searching the INEEL Technical Library, the INEEL Environmental Restoration Optical Imaging System, and the ISI Web of Science databases. The citation lists were generated using the keywords ground water, groundwater, chemistry, geochemistry, contaminant, INEL, INEEL, and Idaho. In addition, a list of USGS documents that pertain to the INEEL was obtained and manually searched. The documents that appeared to be the most pertinent were selected from further review. These documents are tabulated in the citation list. This report summarizes existing geochemical conceptual models, but does not attempt to generate a new conceptual model or select the ''right'' model. This document is organized as follows. Geochemical models are described in general in Section 2. Geochemical processes that control the transport and fate of contaminants introduced into groundwater are described in Section 3. The natural geochemistry of the Eastern Snake River Plain Aquifer (SRPA) is described in Section 4. The effect of waste disposal on the INEEL subsurface is described in Section 5. The geochemical behavior of the major contaminants is described in Section 6. Section 7 describes the site-specific geochemical models developed for various INEEL facilities.

Paul L. Wichlacz; Robert C. Starr; Brennon Orr

2003-09-01T23:59:59.000Z

15

Using reactive transport modeling to evaluate the source term at Yucca mountain  

Science Journals Connector (OSTI)

The conventional approach of source-term evaluation for performance assessment of nuclear waste repositories uses the dissolution rate of waste form and the solubility of pure phases of radioactive elements to constrain radionuclide concentrations. This ... Keywords: neptunium, nuclear waste, radionuclide solubility, reactive-transport modeling, secondary phases, spent nuclear fuel, uranium

Yueting Chen

2003-04-01T23:59:59.000Z

16

A case against Kd-based transport models: natural attenuation at a mill tailings site  

Science Journals Connector (OSTI)

This study compares numerical modeling results of contaminant transport using a multi-component coupled reactive mass transport model and a distribution coefficient (Kd)-based transport model. The study site is a contaminated groundwater ... Keywords: contaminant, coupled processes, geochemical modeling, transport

Chen Zhu

2003-04-01T23:59:59.000Z

17

RAFT: A simulator for ReActive Flow and Transport of groundwater contaminants  

SciTech Connect (OSTI)

This report documents the use of the simulator RAFT for the ReActive flow and Transport of groundwater contaminants. RAFT can be used as a predictive tool in the design and analysis of laboratory and field experiments or it can be used for the estimation of model/process parameters from experiments. RAFT simulates the reactive transport of groundwater contaminants in one, two-, or three-dimensions and it can model user specified source/link configurations and arbitrary injection strategies. A suite of solvers for transport, reactions and regression are employed so that a combination of numerical methods best suited for a problem can be chosen. User specified coupled equilibrium and kinetic reaction systems can be incorporated into RAFT. RAFT is integrated with a symbolic computational language MAPLE, to automate code generation for arbitrary reaction systems. RAFT is expected to be used as a simulator for engineering design for field experiments in groundwater remediation including bioremediation, reactive barriers and redox manipulation. As an integrated tool with both the predictive ability and the ability to analyze experimental data, RAFT can help in the development of remediation technologies, from laboratory to field.

Chilakapati, A.

1995-07-01T23:59:59.000Z

18

A reaction-based paradigm to model reactive chemical transport in groundwater with general kinetic and equilibrium reactions  

SciTech Connect (OSTI)

This paper presents a reaction-based water quality transport model in subsurface flow systems. Transport of chemical species with a variety of chemical and physical processes is mathematically described by M partial differential equations (PDEs). Decomposition via Gauss-Jordan column reduction of the reaction network transforms M species reactive transport equations into two sets of equations: a set of thermodynamic equilibrium equations representing NE equilibrium reactions and a set of reactive transport equations of M-NE kinetic-variables involving no equilibrium reactions (a kinetic-variable is a linear combination of species). The elimination of equilibrium reactions from reactive transport equations allows robust and efficient numerical integration. The model solves the PDEs of kinetic-variables rather than individual chemical species, which reduces the number of reactive transport equations and simplifies the reaction terms in the equations. A variety of numerical methods are investigated for solving the coupled transport and reaction equations. Simulation comparisons with exact solutions were performed to verify numerical accuracy and assess the effectiveness of various numerical strategies to deal with different application circumstances. Two validation examples involving simulations of uranium transport in soil columns are presented to evaluate the ability of the model to simulate reactive transport with complex reaction networks involving both kinetic and equilibrium reactions.

Zhang, Fan [ORNL; Yeh, Gour-Tsyh [University of Central Florida, Orlando; Parker, Jack C [ORNL; Brooks, Scott C [ORNL; Pace, Molly [ORNL; Kim, Young Jin [ORNL; Jardine, Philip M [ORNL; Watson, David B [ORNL

2007-01-01T23:59:59.000Z

19

Coupled Geochemical and Hydrological Processes Governing the Fate and Transport of Radionuclides and Toxic Metals Beneath the Hanford Tank Farms  

SciTech Connect (OSTI)

The goal of this research was to provide an improved understanding and predictive capability of coupled hydrological and geochemical mechanisms that are responsible for the accelerated migration and immobilization of radionuclides and toxic metals in the badose zone beneath the Hanford Tank Farms.

Scott Fendorf; Phil Jardine

2006-07-21T23:59:59.000Z

20

Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot  

SciTech Connect (OSTI)

To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

2009-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Reactive Geochemical Transport Modeling of Concentrated Aqueous Solutions: Supplement to TOUGHREACT User's Guide for the Pitzer Ion-Interaction Model  

E-Print Network [OSTI]

Activity Coefficient of CaCl2 80 degree C Measured Osmotic80 degree C Measured Calculated Molality of CaCl2 Molalityof CaCl2 Figure 5-1. Comparison of the TOUGHREACT-

Zhang, Guoxiang; Spycher, Nicolas; Xu, Tianfu; Sonnenthal, Eric; Steefel, Carl

2006-01-01T23:59:59.000Z

22

Reactive Geochemical Transport Modeling of Concentrated Aqueous Solutions: Supplement to TOUGHREACT User's Guide for the Pitzer Ion-Interaction Model  

E-Print Network [OSTI]

gypsum, niter, soda niter, halite, sylvite, epsomite, Mg(NO7 1.0E-8 1.0E-9 Gypsum Halite CaCl2:2H2O Sylvite Calcite Na+

Zhang, Guoxiang; Spycher, Nicolas; Xu, Tianfu; Sonnenthal, Eric; Steefel, Carl

2006-01-01T23:59:59.000Z

23

Chombo-Crunch: Modeling Pore-Scale Reactive Transport in Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transient pH on calcite grains in capillary tube experiment. 1 billion grid points computed on 48K cores. 1 micron resolution. Transient pH on calcite grains in capillary tube experiment. 1 billion grid points computed on 48K cores. 1 micron resolution. Transient pH on calcite grains in capillary tube experiment. 1 billion grid points computed on 48K cores. 1 micron resolution. David Trebotich, Lawrence Berkeley National Laboratory Chombo-Crunch: Modeling Pore-Scale Reactive Transport in Carbon Sequestration PI Name: David Trebotich PI Email: treb@lbl.gov Institution: Lawrence Berkeley National Laboratory Allocation Program: INCITE Allocation Hours at ALCF: 80 Million Year: 2014 Research Domain: Earth Science Carbon sequestration, the process of capturing carbon dioxide (CO2) before it enters the atmosphere and transferring it into the earth, is a promising technique to help control greenhouse gas emissions. Researchers from the

24

REACTIVE TRANSPORT MODELING USING A PARALLEL FULLY-COUPLED SIMULATOR BASED ON PRECONDITIONED JACOBIAN-FREE NEWTON-KRYLOV  

SciTech Connect (OSTI)

Systems of multicomponent reactive transport in porous media that are large, highly nonlinear, and tightly coupled due to complex nonlinear reactions and strong solution-media interactions are often described by a system of coupled nonlinear partial differential algebraic equations (PDAEs). A preconditioned Jacobian-Free Newton-Krylov (JFNK) solution approach is applied to solve the PDAEs in a fully coupled, fully implicit manner. The advantage of the JFNK method is that it avoids explicitly computing and storing the Jacobian matrix during Newton nonlinear iterations for computational efficiency considerations. This solution approach is also enhanced by physics-based blocking preconditioning and multigrid algorithm for efficient inversion of preconditioners. Based on the solution approach, we have developed a reactive transport simulator named RAT. Numerical results are presented to demonstrate the efficiency and massive scalability of the simulator for reactive transport problems involving strong solution-mineral interactions and fast kinetics. It has been applied to study the highly nonlinearly coupled reactive transport system of a promising in situ environmental remediation that involves urea hydrolysis and calcium carbonate precipitation.

Luanjing Guo; Chuan Lu; Hai Huang; Derek R. Gaston

2012-06-01T23:59:59.000Z

25

Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport  

SciTech Connect (OSTI)

Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided thorough characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, partial pressure of carbon dioxide, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions. In this final report, we provide detailed descriptions of our results from this three-year study, completed in 2012 following a one-year no cost extension.

Chorover, Jon; Perdrial, Nico; Mueller, Karl; Strepka, Caleb; Oƒ ƒ ‚ ¢ƒ ‚ ‚ € ƒ ‚ ‚ ™ Day, Peggy; Rivera, Nelson; Um, Wooyong; Chang, Hyun-Shik; Steefel, Carl; Thompson, Aaron

2012-11-05T23:59:59.000Z

26

The Development and Application of Reactive Transport Modeling Techniques to Study Radionuclide Migration at Yucca Mountain, NV  

SciTech Connect (OSTI)

Yucca Mountain, Nevada has been chosen as a possible site for the first high level radioactive waste repository in the United States. As part of the site investigation studies, we need to make scientifically rigorous estimations of radionuclide migration in the event of a repository breach. Performance assessment models used to make these estimations are computationally intensive. We have developed two reactive transport modeling techniques to simulate radionuclide transport at Yucca Mountain: (1) the selective coupling approach applied to the convection-dispersion-reaction (CDR) model and (2) a reactive stream tube approach (RST). These models were designed to capture the important processes that influence radionuclide migration while being computationally efficient. The conventional method of modeling reactive transport models is to solve a coupled set of multi-dimensional partial differential equations for the relevant chemical components in the system. We have developed an iterative solution technique, denoted the selective coupling method, that represents a versatile alternative to traditional uncoupled iterative techniques and the filly coupled global implicit method. We show that selective coupling results in computational and memory savings relative to these approaches. We develop RST as an alternative to the CDR method for solving large two- or three-dimensional reactive transport simulations for cases in which one is interested in predicting the flux across a specific control plane. In the RST method, the multidimensional problem is reduced to a series of one-dimensional transport simulations along streamlines. The key assumption with RST is that mixing at the control plane approximates the transverse dispersion between streamlines. We compare the CDR and RST approaches for several scenarios that are relevant to the Yucca Mountain Project. For example, we apply the CDR and RST approaches to model an ongoing field experiment called the Unsaturated Zone Transport Test.

Viswanathan, Hari Selvi

1999-09-01T23:59:59.000Z

27

Determination of the transport mechanisms in mixed conduction of reactively sputtered ZnO thin films  

Science Journals Connector (OSTI)

Material grown at highly Zn-rich conditions in reactive sputtering of ZnO thin films resulted in mixed conduction, indicating that stable p-type ZnO can be produced. In n-type conductivity, neutral flaw scattering transport mechanism via centres seems to be dominant due to the existence of oxygen vacancies in high concentrations. An exponential decrease in electron mobility is observed upon cooling from room temperature to 210?K while the concentration of the inactive state increases. This is also a cause of p-type conduction in the low temperature range ( scattering. Quantitative evaluations of VO centres show that fractional distribution of , and charge states are, respectively, around 4%, 95% and 1% of the total [VO] at the room temperature conditions. The energy of phonons interacting with the centre is estimated to be 38.5?meV which is a local phonon mode relaxation, most probably resulting in negative-U behaviour of VO centres.

S Tzemen; Emre Gr; S Do?an

2008-01-01T23:59:59.000Z

28

Quantification of Hydrological, Geochemical, and Mineralogical Processes Governing the Fate and Transport of Uranium over Multiple Scales in Hanford Sediments  

SciTech Connect (OSTI)

A long-term measure of the DOE Environmental Remediation Sciences Division is to provide sufficient scientific understanding to allow a significant fraction of DOE sites to incorporate coupled biological, chemical, and physical processes into decision making for environmental remediation and long-term stewardship by 2015. Our research targets two related, major obstacles to understanding and predicting contaminant transport at DOE sites: the heterogeneity of subsurface geologic media, and the scale dependence of experimental and modeled results.

Fendorf, Scott; Mayes, Melanie A.; Perfect, Edmund; van den Berg, Elmer; Parker, Jack C.; Jardine, Philip M.; Tang, Guoping

2006-11-15T23:59:59.000Z

29

Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical  

Open Energy Info (EERE)

Geochemical, Groundwater Geochemical, And Radiometric Geophysical Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three Geothermal Prospects In Northern Nevada Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Paper: Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three Geothermal Prospects In Northern Nevada Details Activities (14) Areas (3) Regions (0) Abstract: Ground water sampling, desorbed mercury soil geochemical surveys and a radiometric geophysical survey was conducted in conjunction with geological mapping at three geothermal prospects in northern Nevada. Orientation sample lines from 610 m (2000 ft.) to 4575 m (15,000 ft.) in length were surveyed at right angles to known and suspected faults. Scintillometer readings (gamma radiation - total counts / second) were also

30

HBH-GEOCHEM-GEOPHY  

Energy Science and Technology Software Center (OSTI)

003015WKSTN00 Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

31

Using Reactive Transport Modeling to Evaluate the Source Term at Yucca Mountain  

SciTech Connect (OSTI)

The conventional approach of source-term evaluation for performance assessment of nuclear waste repositories uses speciation-solubility modeling tools and assumes pure phases of radioelements control their solubility. This assumption may not reflect reality, as most radioelements (except for U) may not form their own pure phases. As a result, solubility limits predicted using the conventional approach are several orders of magnitude higher then the concentrations of radioelements measured in spent fuel dissolution experiments. This paper presents the author's attempt of using a non-conventional approach to evaluate source term of radionuclide release for Yucca Mountain. Based on the general reactive-transport code AREST-CT, a model for spent fuel dissolution and secondary phase precipitation has been constructed. The model accounts for both equilibrium and kinetic reactions. Its predictions have been compared against laboratory experiments and natural analogues. It is found that without calibrations, the simulated results match laboratory and field observations very well in many aspects. More important is the fact that no contradictions between them have been found. This provides confidence in the predictive power of the model. Based on the concept of Np incorporated into uranyl minerals, the model not only predicts a lower Np source-term than that given by conventional Np solubility models, but also produces results which are consistent with laboratory measurements and observations. Moreover, two hypotheses, whether Np enters tertiary uranyl minerals or not, have been tested by comparing model predictions against laboratory observations, the results favor the former. It is concluded that this non-conventional approach of source term evaluation not only eliminates over-conservatism in conventional solubility approach to some extent, but also gives a realistic representation of the system of interest, which is a prerequisite for truly understanding the long-term behavior of the proposed repository. Therefore, it is a very promising alternative approach for source-term evaluation.

Y. Chen

2001-12-19T23:59:59.000Z

32

Geochemical, mineralogical and microbiological characteristics...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium Geochemical, mineralogical and microbiological characteristics...

33

Groundwater Reactive Transport Models, 2012, 141-159 141 Fan Zhang, Gour-Tsyh (George) Yeh, Jack C. Parker and Xiaonan Shi (Eds)  

E-Print Network [OSTI]

performance computing, reactive transport, carbon sequestration, multiple realizations, multiphase flow transport at the Hanford 300 Area and CO2 sequestration in deep geologic formations. Keywords: High resources, such as CO2 sequestration in deep geologic formations, on the environment, and the efficacy

Mills, Richard

34

Final Project Report: Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport  

SciTech Connect (OSTI)

Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided detailed characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, PCO2, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions.

Jon Chorover, University of Arizona; Peggy O'‚ € ‚ ™ Day, University of California, Merced; Karl Mueller, Penn State University; Wooyong Um, Pacific Northwest National Laboratory; Carl Steefel, Lawrence Berkeley National Laboratory

2012-10-01T23:59:59.000Z

35

High Performance Computations of Subsurface Reactive Transport Processes at the Pore Scale  

E-Print Network [OSTI]

such as carbon sequestration drive the geochemistry of porous media far from equilibrium in relatively short time in reservoir scale models. In the DOE Energy Frontier Research Center for Nanoscale Control of Geologic Carbon such as reactive surface area or reaction rates as they affect CO2 sequestration, with an objective of upscaling

36

High-Resolution Simulation of Pore-Scale Reactive Transport Processes Associated with Carbon Sequestration  

Science Journals Connector (OSTI)

New investigative tools combined with experiments and computational methods are being developed to build a next-generation understanding of molecular-to-pore-scale processes in fluid-rock systems and to demonstrate the ability to control critical aspects of flow and transport in porous rock media in particular as applied to geologic sequestration of CO. Of scientific interest is to establish the rules governing emergent behavior at the porous-continuum macroscale under far from equilibrium conditions by carefully understanding the behavior at the underlying pore microscale. To this end the authors present a direct numerical simulation modeling capability that can resolve flow and transport processes in geometric features obtained from the image data of realistic pore space at unprecedented scale and resolution. Here they focus on scaling a new algorithmic approach based on embedded boundary finite-volume methods and algebraic multigrid. They demonstrate the scalability of this new capability known as Chombo-Crunch to more than 100 000 processor cores and show results from pore-scale flow and transport in the realistic pore space obtained from image data.

2014-01-01T23:59:59.000Z

37

Final Report Coupled In Silico Microbial and Geochemical Reactive Transport Models: Extension to Multi-Organism Communities, Upscaling, and Experimental Validation  

SciTech Connect (OSTI)

The project was highly successful in improving the understanding of physiological and ecological factors controlling the growth and interaction of subsurface microorganisms and in developing better strategies for in silico modeling of the interactions of subsurface microorganisms with other species and their environment.

Lovley, Derek R.

2014-03-05T23:59:59.000Z

38

TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media, V1.2.1  

E-Print Network [OSTI]

mineralogic model of Yucca Mountain, Nevada, Rev 2.0 . , Losfrom tuffs at Yucca Mountain, Nevada, USA. Geochim.in zeolitized tuffs at Yucca Mountain, Nevada, USA. Geochim.

Xu, Tianfu

2008-01-01T23:59:59.000Z

39

TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media, V1.2.1  

E-Print Network [OSTI]

01 0.41427325E+04 -0.12694335E+05 'halite' 1.000 ' na+' 1.000 'cl-' 'halite' 'halite' 1.2697E+02 -8.0477E+02 -1.2435E-01 4.4956E+04 -

Xu, Tianfu

2008-01-01T23:59:59.000Z

40

TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media, V1.2.1  

E-Print Network [OSTI]

Drift, heat was applied solely to the drift-center gridsquares) indicate grid block coordinates. Heat was appliedgrid block KCYC=KCYC+1 Time step: ?t Solve fluid and heat

Xu, Tianfu

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Nanoscale study of reactive transport in catalyst layer of proton exchange membrane fuel cells with precious and non-precious catalysts using lattice Boltzmann method  

E-Print Network [OSTI]

High-resolution porous structures of catalyst layer (CL) with multicomponent in proton exchange membrane fuel cells are reconstructed using a reconstruction method called quartet structure generation set. Characterization analyses of nanoscale structures are implemented including pore size distribution, specific area and phase connectivity. Pore-scale simulation methods based on the lattice Boltzmann method are developed and used to predict the macroscopic transport properties including effective diffusivity and proton conductivity. Nonuniform distributions of ionomer in CL generates more tortuous pathway for reactant transport and greatly reduces the effective diffusivity. Tortuosity of CL is much higher than conventional Bruggeman equation adopted. Knudsen diffusion plays a significant role in oxygen diffusion and significantly reduces the effective diffusivity. Reactive transport inside the CL is also investigated. Although the reactive surface area of non-precious metal catalyst (NPMC) CL is much higher t...

Chen, Li; Kang, Qinjun; Holby, Edward F; Tao, Wen-Quan

2014-01-01T23:59:59.000Z

42

Geochemical Techniques | Open Energy Information  

Open Energy Info (EERE)

Geochemical Techniques Geochemical Techniques Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Geochemical Techniques Details Activities (0) Areas (0) Regions (0) NEPA(1) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: None Parent Exploration Technique: Exploration Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png Geochemical Techniques: No definition has been provided for this term. Add a Definition Related Techniques Geochemical Techniques Geochemical Data Analysis Geothermometry Gas Geothermometry Isotope Geothermometry Liquid Geothermometry Cation Geothermometers Multicomponent Geothermometers Silica Geothermometers Thermal Ion Dispersion

43

3D Field-Scale Reactive Transport Modeling of In Situ Immobilization of Uranium in Structured Porous Media via Biostimulation  

SciTech Connect (OSTI)

A several-month-long ethanol injection experiment is being conducted to study the impacts of porous media structure (i.e., heterogeneity existing at multiple scales) on the effectiveness of metal/radionuclide bioremediation in a highly heterogeneous unconfined aquifer near Oak Ridge, TN, USA. We have constructed a 3D field-scale groundwater flow and multicomponent reactive transport model to simulate the experimental observations. The model incorporates a suite of abiotic reactions and microbially-mediated redox reactions for multiple terminal electron accepting processes (TEAPs) including soluble oxygen, nitrate, U(VI) and sulfate and solid-phase electron acceptors. Different biomass populations are considered in the model. Growth of these populations is derived from the bioenergetics-based approach in which the partitioning of electron flow between energy generation and cell biomass production is dependent on the free energy of the corresponding TEAP. TEAP reaction rates were free energy constrained. The TEAP model and reaction system have been formulated and used to simulate laboratory batch experimental observations. We conducted the field-scale simulation starting with the reaction system and parameters obtained from the batch experiment and hydrologic parameters estimated from the results of pumping tests, water level monitoring and model interpretation of a tracer test conducted in August 2004. Reaction parameters were investigated to compare simulation results and field experiment observations.

Fang, Yilin; Scheibe, Timothy D.; Roden, Eirc E.; Kamolpornwijit, Wiwat; Brooks, Scott C.

2006-09-12T23:59:59.000Z

44

TWO-DIMENSIONAL REACTIVE TRANSPORT MODELING OF CO2 INJECTION IN A SALINE AQUIFER AT THE SLEIPNER SITE  

E-Print Network [OSTI]

. To ensure safety, a low permeable formation, called the cap rock, is required on the top of the storage zone in the brine, and geochemical reactions with the host rock are considered in the model. Two mineralogical assemblages are considered in the Utsira formation, a sand formation that is highly permeable and a shale

Boyer, Edmond

45

Chemically Reactive Working Fluids | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Chemically Reactive Working Fluids for the Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Chemically Reactive Working Fluids SunShot CSP...

46

Pore-scale simulation of coupled reactive transport and dissolution in fractures and porous media using the level set interface tracking method  

SciTech Connect (OSTI)

A level set simulation methodology developed for modeling coupled reactive transport and structure evolution has been applied to dissolution in fracture apertures and porous media. The coupled processes such as fluid flow, reactant transport and dissolution at the solid-liquid interfaces are handled simultaneously. The reaction-induced evolution of solid-liquid interfaces is captured using the level set method, with the advantage of representing the interface with sub-grid scale resolution. The coupled processes are simulated for several geometric models of fractures and porous media under various flow conditions and reaction rates. Quantitative relationships between permeability and porosity are obtained from some of the simulation results and compared with analytical constitutive relations (i.e., the conventional cubic law and the Carman-Kozeny law) based on simplified pore space geometries and reaction induced geometric evolutions. The drastic deviation of the simulation results from these analytical theories is explained by the development of large local concentration gradients of reactants within fracture apertures and individual pores observed in the simulation results and consequently the complex geometric evolution patterns of fracture apertures and pores due to mineral dissolution. The simulation results support the argument that traditional constitutive relations based on simplified geometries and conditions have limited applicability in predicting field scale reactive transport and that incorporation of micro-scale physics is necessary.

Hai Huang; Xiaoyi Li

2011-01-01T23:59:59.000Z

47

Geochemical Data Analysis | Open Energy Information  

Open Energy Info (EERE)

Geochemical Data Analysis Geochemical Data Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Geochemical Data Analysis Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geochemical Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png Geochemical Data Analysis: No definition has been provided for this term. Add a Definition References No exploration activities found. Print PDF Retrieved from "http://en.openei.org/w/index.php?title=Geochemical_Data_Analysis&oldid=594157" Categories: Geochemical Techniques Exploration Techniques

48

Do geochemical estimates of sediment focusing pass the sediment test in the equatorial Pacific?  

E-Print Network [OSTI]

Do geochemical estimates of sediment focusing pass the sediment test in the equatorial Pacific] The paleoceanographic recording fidelity of pelagic sediments is limited by chemical diagenesis and physical mixing (bioturbation and horizontal sediment transport). Diagenesis and bioturbation are relatively well

Kurapov, Alexander

49

TOUGHREACT Version 2.0: A simulator for subsurface reactive transport under non-isothermal multiphase flow conditions  

SciTech Connect (OSTI)

TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media, and was developed by introducing reactive chemistry into the multiphase fluid and heat flow simulator TOUGH2 V2. The first version of TOUGHREACT was released to the public through the U.S. Department of Energy's Energy Science and Technology Software Center (ESTSC) in August 2004. It is among the most frequently requested of ESTSC's codes. The code has been widely used for studies in CO{sub 2} geological sequestration, nuclear waste isolation, geothermal energy development, environmental remediation, and increasingly for petroleum applications. Over the past several years, many new capabilities have been developed, which were incorporated into Version 2 of TOUGHREACT. Major additions and improvements in Version 2 are discussed here, and two application examples are presented: (1) long-term fate of injected CO{sub 2} in a storage reservoir and (2) biogeochemical cycling of metals in mining-impacted lake sediments.

Xu, T.; Spycher, N.; Sonnenthal, E.; Zhang, G.; Zheng, L.; Pruess, K.

2010-08-01T23:59:59.000Z

50

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

51

Transportation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Transportation Transportation of Depleted Uranium Materials in Support of the Depleted Uranium Hexafluoride Conversion Program Issues associated with transport of depleted UF6 cylinders and conversion products. Conversion Plan Transportation Requirements The DOE has prepared two Environmental Impact Statements (EISs) for the proposal to build and operate depleted uranium hexafluoride (UF6) conversion facilities at its Portsmouth and Paducah gaseous diffusion plant sites, pursuant to the National Environmental Policy Act (NEPA). The proposed action calls for transporting the cylinder at ETTP to Portsmouth for conversion. The transportation of depleted UF6 cylinders and of the depleted uranium conversion products following conversion was addressed in the EISs.

52

Using laboratory flow experiments and reactive chemical transport modeling for designing waterflooding of the Agua Fria Reservoir, Poza Rica-Altamira Field, Mexico  

SciTech Connect (OSTI)

Waterflooding for enhanced oil recovery requires that injected waters must be chemically compatible with connate reservoir waters, in order to avoid mineral dissolution-and-precipitation cycles that could seriously degrade formation permeability and injectivity. Formation plugging is a concern especially in reservoirs with a large content of carbonates, such as calcite and dolomite, as such minerals typically react rapidly with an aqueous phase, and have strongly temperature-dependent solubility. Clay swelling can also pose problems. During a preliminary waterflooding pilot project, the Poza Rica-Altamira oil field, bordering the Gulf coast in the eastern part of Mexico, experienced injectivity loss after five months of reinjection of formation waters into well AF-847 in 1999. Acidizing with HCl restored injectivity. We report on laboratory experiments and reactive chemistry modeling studies that were undertaken in preparation for long-term waterflooding at Agua Frma. Using analogous core plugs obtained from the same reservoir interval, laboratory coreflood experiments were conducted to examine sensitivity of mineral dissolution and precipitation effects to water composition. Native reservoir water, chemically altered waters, and distilled water were used, and temporal changes in core permeability, mineral abundances and aqueous concentrations of solutes were monitored. The experiments were simulated with the multi-phase, nonisothermal reactive transport code TOUGHREACT, and reasonable to good agreement was obtained for changes in solute concentrations. Clay swelling caused an additional impact on permeability behavior during coreflood experiments, whereas the modeled permeability depends exclusively on chemical processes. TOUGHREACT was then used for reservoir-scale simulation of injecting ambient-temperature water (30 C, 86 F) into a reservoir with initial temperature of 80 C (176 F). Untreated native reservoir water was found to cause serious porosity and permeability reduction due to calcite precipitation, which is promoted by the retrograde solubility of this mineral. Using treated water that performed well in the laboratory flow experiments was found to avoid excessive precipitation, and allowed injection to proceed.

Birkle, P.; Pruess, K.; Xu, T.; Figueroa, R.A. Hernandez; Lopez, M. Diaz; Lopez, E. Contreras

2008-10-01T23:59:59.000Z

53

Transportation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Health Risks » Transportation Health Risks » Transportation DUF6 Health Risks line line Accidents Storage Conversion Manufacturing Disposal Transportation Transportation A discussion of health risks associated with transport of depleted UF6. Transport Regulations and Requirements In the future, it is likely that depleted uranium hexafluoride cylinders will be transported to a conversion facility. For example, it is currently anticipated that the cylinders at the ETTP Site in Oak Ridge, TN, will be transported to the Portsmouth Site, OH, for conversion. Uranium hexafluoride has been shipped safely in the United States for over 40 years by both truck and rail. Shipments of depleted UF6 would be made in accordance with all applicable transportation regulations. Shipment of depleted UF6 is regulated by the

54

Modeling subsurface contaminant reactions and transport at the watershed scale  

SciTech Connect (OSTI)

The objectives of this research are: (1) to numerically examine the multiscale effects of physical and chemical mass transfer processes on watershed scale, variably saturated subsurface contaminant transport, and (2) to conduct numerical simulations on watershed scale reactive solute transport and evaluate their implications to uncertainty characterization and cost benefit analysis. Concurrent physical and chemical nonequilibrium caused by inter aggregate gradients of pressure head and solute concentration and intra-aggregate geochemical and microbiological processes, respectively, may arise at various scales and flowpaths. To this date, experimental investigations of these complex processes at watershed scale remain a challenge and numerical studies are often needed for guidance of water resources management and decision making. This research integrates the knowledge bases developed during previous experimental and numerical investigations at a proposed waste disposal site at the Oak Ridge National Laboratory to study the concurrent effects of physical and chemical nonequilibrium. Comparison of numerical results with field data indicates that: (1) multiregion, preferential flow and solute transport exist under partially saturated condition and can be confirmed theoretically, and that (2) mass transfer between pore regions is an important process influencing contaminant movement in the subsurface. Simulations of watershed scale, multi species reactive solute transport suggest that dominance of geochemistry and hydrodynamics may occur simultaneously at different locales and influence the movement of one species relative to another. Execution times on the simulations of the reactive solute transport model also indicate that the model is ready to assist the selection of important parameters for site characterization.

Gwo, J.P.; Jardine, P.M.; D`Azevedo, E.F. [Oak Ridge National Lab., TN (United States); Wilson, G.V. [Desert Research Inst., Las Vegas, NV (United States). Water Resources Center

1997-12-01T23:59:59.000Z

55

Category:Geochemical Techniques | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Category Edit History Facebook icon Twitter icon » Category:Geochemical Techniques Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Geochemical Techniques page? For detailed information on exploration techniques, click here. Category:Geochemical Techniques Add.png Add a new Geochemical Techniques Technique Subcategories This category has only the following subcategory. G [×] Geochemical Data Analysis‎ 3 pages Pages in category "Geochemical Techniques" This category contains only the following page. G Geochemical Data Analysis Retrieved from "http://en.openei.org/w/index.php?title=Category:Geochemical_Techniques&oldid=689823"

56

System-Scale Model of Aquifer, Vadose Zone, and River Interactions for the Hanford 300 Area - Application to Uranium Reactive Transport  

SciTech Connect (OSTI)

This report represents a synthesis and integration of basic and applied research into a system-scale model of the Hanford 300 Area groundwater uranium plume, supported by the U.S. Department of Energys Richland Operations (DOE-RL) office. The report integrates research findings and data from DOE Office of Science (DOE-SC), Office of Environmental Management (DOE-EM), and DOE-RL projects, and from the site remediation and closure contractor, Washington Closure Hanford, LLC (WCH). The three-dimensional, system-scale model addresses water flow and reactive transport of uranium for the coupled vadose zone, unconfined aquifer, and Columbia River shoreline of the Hanford 300 Area. The system-scale model of the 300 Area was developed to be a decision-support tool to evaluate processes of the total system affecting the groundwater uranium plume. The model can also be used to address what if questions regarding different remediation endpoints, and to assist in design and evaluation of field remediation efforts. For example, the proposed cleanup plan for the Hanford 300 Area includes removal, treatment, and disposal of contaminated sediments from known waste sites, enhanced attenuation of uranium hot spots in the vadose and periodically rewetted zone, and continued monitoring of groundwater with institutional controls. Illustrative simulations of polyphosphate infiltration were performed to demonstrate the ability of the system-scale model to address these types of questions. The use of this model in conjunction with continued field monitoring is expected to provide a rigorous basis for developing operational strategies for field remediation and for defining defensible remediation endpoints.

Rockhold, Mark L.; Bacon, Diana H.; Freedman, Vicky L.; Parker, Kyle R.; Waichler, Scott R.; Williams, Mark D.

2013-10-01T23:59:59.000Z

57

Transportation  

Science Journals Connector (OSTI)

The romantic rides in Sandburgs eagle-car changed society. On the one hand, motor vehicle transportation is an integral thread of societys fabric. On the other hand, excess mobility fractures old neighborh...

David Hafemeister

2014-01-01T23:59:59.000Z

58

Rare earth element transport in the Yucca Mountain region.  

E-Print Network [OSTI]

??In sync with environmental pollution of solutes in nature, from source, process to consequence, geochemical processes (leaching and sorption) and hydraulic transportation of the rare (more)

Zhang, Liqiong

2010-01-01T23:59:59.000Z

59

Reactive Maintenance  

Broader source: Energy.gov [DOE]

Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities.

60

Influence of Mg2+ on CaCO3 precipitation during subsurface reactive transport in a homogeneous silicon-etched pore network  

SciTech Connect (OSTI)

Calcium carbonate (CaCO3) geochemical reactions exert a fundamental control on the evolution of porosity and permeability in shallow-to-deep subsurface siliciclastic and limestone rock reservoirs. As a result, these carbonate water-rock interactions play a critically important role in research on groundwater remediation, geological carbon sequestration, and hydrocarbon exploration. A study was undertaken to determine the effects of Mg2+ concentration on CaCO3 crystal morphology, precipitation rate, and porosity occlusion under flow and mixing conditions similar to those in subsurface aquifers.

Boyd, Victoria; Yoon, Hongkyu; Zhang, Changyong; Oostrom, Martinus; Hess, Nancy J.; Fouke, Bruce W.; Valocchi, Albert J.; Werth, Charles J.

2014-05-19T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Merging high resolution geophysical and geochemical surveys to...  

Broader source: Energy.gov (indexed) [DOE]

high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon Merging high resolution geophysical and geochemical surveys to reduce...

62

Transportation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Due to limited parking, all visitors are strongly encouraged to: Due to limited parking, all visitors are strongly encouraged to: 1) car-pool, 2) take the Lab's special conference shuttle service, or 3) take the regular off-site shuttle. If you choose to use the regular off-site shuttle bus, you will need an authorized bus pass, which can be obtained by contacting Eric Essman in advance. Transportation & Visitor Information Location and Directions to the Lab: Lawrence Berkeley National Laboratory is located in Berkeley, on the hillside directly above the campus of University of California at Berkeley. The address is One Cyclotron Road, Berkeley, California 94720. For comprehensive directions to the lab, please refer to: http://www.lbl.gov/Workplace/Transportation.html Maps and Parking Information: On Thursday and Friday, a limited number (15) of barricaded reserved parking spaces will be available for NON-LBNL Staff SNAP Collaboration Meeting participants in parking lot K1, in front of building 54 (cafeteria). On Saturday, plenty of parking spaces will be available everywhere, as it is a non-work day.

63

ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion Transport in Yttria-Stabilized Zirconia  

E-Print Network [OSTI]

ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion through yttria-stabilized zirconia (YSZ) solid oxide fuel cell (SOFC) membranes. All parameters for Reax temperature, leading to applications as oxygen sensors and as membranes for high temperature solid oxide fuel

Goddard III, William A.

64

Progress Report, December 2010: Improved Site Characterization And Storage Prediction Through Stochastic Inversion Of Time-Lapse Geophysical And Geochemical Data  

SciTech Connect (OSTI)

Over the last project six months, our project activities have concentrated on three areas: (1) performing a stochastic inversion of pattern 16 seismic data to deduce reservoir permeability, (2) development of the geochemical inversion strategy and implementation of associated software, and (3) completing the software implementation of TProGS and the geostatistical analysis that provides the information needed when using the software to produce realizations of the Midale reservoir. The report partially the following deliverables: D2: Model development: MCMC tool (synthetic fluid chemistry data); deliverable completed. D4: Model development/verification: MCMC tool (TProGS, field seismic/chemistry data) work product; deliverable requirements partially fulfilled. D5: Field-based single-pattern simulations work product; deliverable requirements partially fulfilled. When completed, our completed stochastic inversion tool will explicitly integrate reactive transport modeling, facies-based geostatistical methods, and a novel stochastic inversion technique to optimize agreement between observed and predicted storage performance. Such optimization will be accomplished through stepwise refinement of: (1) the reservoir model - principally its permeability magnitude and heterogeneity - and (2) geochemical parameters - primarily key mineral volume fractions and kinetic data. We anticipate that these refinements will facilitate significantly improved history matching and forward modeling of CO{sub 2} storage. Our tool uses the Markov Chain Monte Carlo (MCMC) methodology. Deliverable D1, previously submitted as a report titled ''Development of a Stochastic Inversion Tool To Optimize Agreement Between The Observed And Predicted Seismic Response To CO{sub 2} Injection/Migration in the Weyburn-Midale Project'' (Ramirez et al., 2009), described the stochastic inversion approach that will identify reservoir models that optimize agreement between the observed and predicted seismic response. The software that implements this approach has been completed, tested, and used to process seismic data from pattern 16. A previously submitted report titled ''Model verification: synthetic single pattern simulations using seismic reflection data'', Ramirez et al. 2010, partially fulfilled deliverable D3 by summarizing verification activities that evaluate the performance of the seismic software and its ability to recover reservoir model permeabilities using synthetic seismic reflection data. A future progress report will similarly describe summarizing verification activities of the geochemical inversion software, thereby completing deliverable D3. This document includes a chapter that shows and discusses permeability models produced by seismic inversion that used seismic data from pattern 16 in Phase 1A. It partially fulfills deliverable D5: Field-based single-pattern simulations work product. The D5 work product is supposed to summarize the results of applying NUFT/MCMC to refine the reservoir model and geochemical parameters by optimizing observation/prediction agreement for the seismic/geochemical response to CO{sub 2} injection/migration within a single pattern of Phase 1A/1B. A future progress report will show inversion results for the same pattern using geochemical data, thereby completing deliverable D5. This document also contains a chapter that fulfills deliverable D2: Model development: MCMC tool (synthetic fluid chemistry data). The chapter will summarize model development activities required to facilitate application of NUFT/MCMC to optimize agreement between the observed and predicted geochemical response to CO{sub 2} injection/migration. Lastly, this document also contains a chapter that partially fulfills deliverable D4: Model development/verification: MCMC tool (TProGS, field seismic/chemistry data) work product. This work product is supposed to summarize model development activities required for (1) application of TProGS to Weyburn, (2) use of TProGS within the MCMC tool, and (3) application of the MCMC tool to address field seismic and g

Ramirez, A; Mcnab, W; Carle, S; Hao, Y; White, D; Johnson, J

2010-12-17T23:59:59.000Z

65

Geothermal/Geochemical Database | Open Energy Information  

Open Energy Info (EERE)

Jump to: navigation, search OpenEI Reference LibraryAdd to library Chart: GeothermalGeochemical DatabaseInfo GraphicMapChart Author Nevada Bureau of Mines and Geology Published...

66

A three-dimensional model of microbial transport and biodegradation at the Schoolcraft, Michigan, site  

E-Print Network [OSTI]

-dimensional reactive transport modeling of carbon tetrachloride (CT) bioremediation at the Schoolcraft site in western

67

Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis  

SciTech Connect (OSTI)

The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

2005-03-01T23:59:59.000Z

68

Oxidation-induced geochemical changes in trench leachates from the Maxey Flats low-level radioactive waste disposal site  

SciTech Connect (OSTI)

A knowledge of extra-trench processes related to oxidation-induced geochemical changes that are likely to occur when iron-rich, anoxic trench waters encounter an oxidizing environment along a redox gradient is essential for modeling radionuclide transport at low-level waste (LLW) disposal sites. The results of laboratory oxidation experiments on several trench leachates from the Maxey Flats site show that, upon oxidation, a series of geochemical changes were initiated that resulted in a drastically different solute geochemistry, involving oxidation of ferrous iron and subsequent precipitation of ferric oxyhydroxide, changes in alkalinity and acidity, a drastic increase in redox potential (Eh), and generally relatively little change in the concentrations of /sup 60/Co, /sup 137/Cs, and /sup 85/Sr in solution. The observations made in this study have important geochemical implications for the modeling of LLW sites in that the source term as an input parameter cannot be assumed to be constant, both spatially and temporally. The acid-generating potential and buffering capacity of an anoxic source term are important geochemical controls that maintain a balance between acidity and alkalinity and largely determine the nature and extent of oxidation-induced geochemical changes likely to occur along a redox gradient. The presence of organic chelating agents can alter the source term geochemistry to such an extent that authigenic ferric oxyhydroxide, which represents a geochemical discontinuity at the redox interface along leachate migration paths, proves to be a relatively ineffective sink for radionuclides.

Dayal, R.; Pietrzak, R.F.; Clinton, J.H.

1986-02-01T23:59:59.000Z

69

NUREG/CR-6870 Consideration of Geochemical  

E-Print Network [OSTI]

in Groundwater Restoration at Uranium In-Situ Leach Mining Facilities Manuscript Completed: December 2006 Date associated with uranium mining sites throughout the United States are also included in this report. A tableNUREG/CR-6870 Consideration of Geochemical Issues in Groundwater Restoration at Uranium In

70

Geochemical engineering problem identification and program description. Final report  

SciTech Connect (OSTI)

The Geochemical Engineering Program has as its goal the improvement of geochemical fluid management techniques. This document presents the strategy and status of the Geochemical Engineering Program. The magnitude and scope of geochemical-related problems constraining geothermal industry productivity are described. The goals and objectives of the DGE Geochemical Engineering Program are defined. The rationale and strategy of the program are described. The structure, priorities, funding, and management of specific elements within the program are delineated, and the status of the overall program is presented.

Crane, C.H.; Kenkeremath, D.C.

1981-05-01T23:59:59.000Z

71

Experimental Geochemical Studies Relevant to Carbon Sequestration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geochemical Studies Relevant to Geochemical Studies Relevant to Carbon Sequestration James G. Blencoe (blencoejg@ornl.gov; 865-574-7041) David R. Cole (coledr@ornl.gov; 865-574-5473) Juske Horita (horitaj@ornl.gov; 865-576-2750) Geochemistry Group Chemical and Analytical Sciences Division Oak Ridge National Laboratory P.O. Box 2008, Building 4500-S Oak Ridge, TN 37831-6110 Gerilynn R. Moline (molinegr@ornl.gov; 865-576-5134) Environmental Sciences Division Oak Ridge National Laboratory P.O. Box 2008, Building 1505 Oak Ridge, TN 37831-6038 Introduction Evidence is mounting that rising levels of atmospheric CO 2 will have profound effects on future global climates (1-2) . Consequently, many experts agree that technologies are needed to slow, and ultimately stop, further buildup (3-5) . One of the strategies proposed to achieve this aim

72

Geochemical Characterization of Chromate Contamination in the 100 Area Vadose Zone at the Hanford Site  

SciTech Connect (OSTI)

The major objectives of the proposed study were to: 1.) determine the leaching characteristics of hexavalent chromium [Cr(VI)] from contaminated sediments collected from 100 Area spill sites; 2.) elucidate possible Cr(VI) mineral and/or chemical associations that may be responsible for Cr(VI) retention in the Hanford Site 100 Areas through the use of i.) macroscopic leaching studies and ii.) microscale characterization of contaminated sediments; and 3.) provide information to construct a conceptual model of Cr(VI) geochemistry in the Hanford 100 Area vadose zone. In addressing these objectives, additional benefits accrued were: (1) a fuller understanding of Cr(VI) entrained in the vadose zone that will that can be utilized in modeling potential Cr(VI) source terms, and (2) accelerating the Columbia River 100 Area corridor cleanup by providing valuable information to develop remedial action based on a fundamental understanding of Cr(VI) vadose zone geochemistry. A series of macroscopic column experiments were conducted with contaminated and uncontaminated sediments to study Cr(VI) desorption patterns in aged and freshly contaminated sediments, evaluate the transport characteristics of dichromate liquid retrieved from old pipelines of the 100 Area; and estimate the effect of strongly reducing liquid on the reduction and transport of Cr(VI). Column experiments used the < 2 mm fraction of the sediment samples and simulated Hanford groundwater solution. Periodic stop-flow events were applied to evaluate the change in elemental concentration during time periods of no flow and greater fluid residence time. The results were fit using a two-site, one dimensional reactive transport model. Sediments were characterized for the spatial and mineralogical associations of the contamination using an array of microscale techniques such as XRD, SEM, EDS, XPS, XMP, and XANES. The following are important conclusions and implications. Results from column experiments indicated that most of contaminant Cr travels fast through the sediments and appears as Cr(VI) in the effluents. The significance of this for groundwater concentrations would, however, depend on the mass flux of recharge to the water table. adsorption of Cr(VI) to sediments from spiked Cr(VI) solution is low; calculated retardation coefficients are close to one. Calcium polysulfide solutions readily reduced Cr(VI) to Cr(III) in column experiments. However a significant amount of the Cr(VI) was mobilized ahead of the polysulfide solution front. This has significant implications for in-situ reductive remediation techniques. The experiments suggest that it would be difficult to design a remedial measure using infiltration of liquid phase reductants without increasing transport of Cr(VI) toward the water table. The microscopic characterization results are consistent with the column studies. Cr(VI) is found as ubiquitous coatings on sediment grain surfaces. Small, higher concentration, chromium sites are associated with secondary clay mineral inclusions, with occasional barium chromate minerals, and reduced to Cr(III) in association with iron oxides that are most likely magnetite primary minerals. Within the restricted access domains of sediment matrix, ferrous iron could also diffuse from in situ, high-surface-area minerals to cause the reductive immobilization of chromate. This process may be favored at microscale geochemical zones where ferrous iron could be supplied. Once nucleated, micrometer-scale precipitates are favored as growing locales for further accumulation, causing the formation of discrete zones of Cr(III).

Dresel, P. Evan; Qafoku, Nikolla; McKinley, James P.; Fruchter, Jonathan S.; Ainsworth, Calvin C.; Liu, Chongxuan; Ilton, Eugene S.; Phillips, J. L.

2008-07-16T23:59:59.000Z

73

Category:Geochemical Data Analysis | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Category Edit History Facebook icon Twitter icon » Category:Geochemical Data Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Geochemical Data Analysis page? For detailed information on exploration techniques, click here. Category:Geochemical Data Analysis Add.png Add a new Geochemical Data Analysis Technique Pages in category "Geochemical Data Analysis" The following 3 pages are in this category, out of 3 total. G Geothermometry T Thermal Ion Dispersion Thermochronometry Retrieved from "http://en.openei.org/w/index.php?title=Category:Geochemical_Data_Analysis&oldid=689825"

74

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory  

E-Print Network [OSTI]

Reactivating personal memory 1 RUNNING HEAD: Reactivating personal memory Modifying memory: Selectively enhancing and updating personal memories for a museum; Reactivating personal memory 2 Abstract Memory can be modified when reactivated

Schacter, Daniel

75

Geochemical and Geophysical Changes during Ammonia Gas Treatment...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geophysical Changes during Ammonia Gas Treatment of Vadose Zone Sediments for Uranium Remediation. Geochemical and Geophysical Changes during Ammonia Gas Treatment of Vadose Zone...

76

Merging high resolution geophysical and geochemical surveys to...  

Broader source: Energy.gov (indexed) [DOE]

high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon Patrick Walsh Ormat Nevada Inc. Innovative technologies May 19, 2010...

77

Stable Isotope Fractionations in Biogeochemical Reactive Transport  

E-Print Network [OSTI]

Standard Review Plan for the Review of DOE Plans for Achieving Regulatory Compliance at Sites with Contaminated Groundwater under Title I of the Uranium

Druhan, Jennifer Lea

2012-01-01T23:59:59.000Z

78

Stable Isotope Fractionations in Biogeochemical Reactive Transport  

E-Print Network [OSTI]

between these values. (B) measured TIC in effluentand the calculated TIC assuming all acetate consumed (asin A) is converted to TIC. Dissolved methane concentrations

Druhan, Jennifer Lea

2012-01-01T23:59:59.000Z

79

Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral/Water Interface  

E-Print Network [OSTI]

Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral in the Earth's Critical Zone is the kinetics. The timescales for geochemical processes range from milliseconds geochemical processes including surface complexation, mineral transformations, and oxidation

Sparks, Donald L.

80

First results of operating and monitoring an innovative design of a permeable reactive barrier for the remediation of chromate contaminated groundwater  

Science Journals Connector (OSTI)

An innovative setup of a permeable reactive barrier (PRB) was installed in Willisau, Switzerland to remediate chromate contaminated groundwater. Instead of a conventional continuous barrier, this PRB consists of cylinders installed in rows: a single row for lower expected CrVI-concentrations and an offset double row for higher expected CrVI-concentrations. The cylinders are filled with reactive grey cast-Fe shavings mixed with gravel to prevent extensive precipitation of secondary phases in the pore space. The treatment of the contaminants takes place both within the cylinders and in the dissolved FeII plume generated downstream of the barrier. Monitoring of the contamination situation over a period of 3 a provided evidence of the mobilization, transport and behavior of the contaminants in the aquifer. Groundwater and reactive material were sampled upstream, within and downstream of the barrier by a Multi-Port Sampling System (MPSS) that revealed the geochemical processes as a function of time and space. Comprehensive chemical analyses included sensitive parameters such as CrVI, FeII/FeIII, redox potential, dissolved O2 and pH. Several campaigns using multiple optical tracers revealed a rather complex hydrological regime at different scales, thereby complicating the barrier performance. Results from the large 3D hydrogeochemical dataset show that the double row of cylinders successfully treated the chromate contamination. Remediation by the single row was not effective enough due to insufficient lateral overlap of the cylinders and their FeII-plumes. The low amount of precipitated secondary phases observed in the pore space of the reactive material reduced the risk of clogging the system and suggested a favorable longevity of the barrier. Limiting factors for the long-term operation are inferred to be the availability and accessibility of FeII within the cylinders and the concentration within the generated FeII-plume.

Bettina Flury; Urs Eggenberger; Urs Mder

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
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81

Transport in Porous Media 37: 327346, 1999. c 1999 Kluwer Academic Publishers. Printed in the Netherlands.  

E-Print Network [OSTI]

in the Netherlands. 327 A Decomposition Method for Solving Coupled Multi-Species Reactive Transport Problems YUNWEI

Clement, Prabhakar

82

Reactivity of Organic Compounds in Hot Water: Geochemical and Technological Implications  

Science Journals Connector (OSTI)

...HIGH-TEMPERATURE HYDROLYSIS AND THERMOLYSIS OF TETRAHYDROTHIOPHENE IN RELATION TO STEAM STIMULATION...HIGH-TEMPERATURE HYDROLYSIS OF TETRAHYDROTHIOPHENE AND THIOPHENE, FUEL 63 : 125...3. REACTION OF THIOPHENE AND TETRAHYDROTHIOPHENE WITH VANADYL AND NICKEL SALTS...

MICHAEL SISKIN; ALAN R. KATRITZKY

1991-10-11T23:59:59.000Z

83

Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado  

Broader source: Energy.gov [DOE]

Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado

84

Geochemical Data Package for Performance Assessment Calculations Related to the Savannah River Site  

SciTech Connect (OSTI)

The Savannah River Site disposes of certain types of radioactive waste within subsurface-engineered facilities. One of the tools used to establish the capacity of a given site to safely store radioactive waste (i.e., that a site does not exceed its Waste Acceptance Criteria) is the Performance Assessment (PA). The objective of this document is to provide the geochemical values for the PA calculations. This work is being conducted as part of the on-going maintenance program that permits the PA to periodically update existing calculations when new data becomes available. Because application of values without full understanding of their original purpose may lead to misuse, this document also provides the geochemical conceptual model, approach used for selecting the values, the justification for selecting data, and the assumptions made to assure that the conceptual and numerical geochemical models are reasonably conservative (i.e., reflect conditions that will tend to predict the maximum risk to the hypothetical recipient). The geochemical parameters describe transport processes for 38 elements (>90 radioisotopes) potentially occurring within eight disposal units (Slit Trenches, Engineered Trenches, Low Activity Waste (LAW) Vault, Intermediate Level (ILV) Vaults, TRU-Pad-1, Naval Reactor Waste Pads, Components-in-Grout Trenches, and Saltstone Facility). This work builds upon well-documented work from previous PA calculations (McDowell-Boyer et al. 2000). The new geochemical concepts introduced in this data package are: (1) In the past, solubility products were used only in a few conditions (element existing in a specific environmental setting). This has been expanded to >100 conditions. (2) Radionuclide chemistry in cementitious environments is described through the use of both the Kd and apparent solubility concentration limit. Furthermore, the solid phase is assumed to age during the assessment period (thousands of years), resulting in three main types of controlling solid phases, each possessing a unique set of radionuclide sorption parameters (Kd and solubility concentration limit). (3) A large amount of recent site-specific sorption research has been conducted since the last PA (McDowell-Boyer et al. 2000). These new data have replaced previous Kd values derived from literature values, thus reducing uncertainty and improving accuracy. Finally, because this document will be used by future PA calculations and external acceptance of the document will eventually be required, this document was extensively reviewed. The review process, including the internal review, site review, and external review process is described.

Kaplan, D

2006-02-28T23:59:59.000Z

85

Geochemical Sampling of Thermal Waters in Nevada | Open Energy Information  

Open Energy Info (EERE)

Geochemical Sampling of Thermal Waters in Nevada Geochemical Sampling of Thermal Waters in Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Geochemical Sampling of Thermal Waters in Nevada Abstract There are 1000 thermal springs in Nevada for which a location is known, but for which there are no available temperature (or chemical) measurements. Although many of these sites are within known geothermal areas and are located near springs for which temperature and/or geochemical data are available for one of the springs, many of these sites are not so located and require evaluation before the geothermal potential of the area can be assessed. In order to begin filling in data gaps, water sampling commenced in 2002 when over 70 analyses were obtained from springs with previously

86

Factors Controlling The Geochemical Evolution Of Fumarolic Encrustations,  

Open Energy Info (EERE)

Controlling The Geochemical Evolution Of Fumarolic Encrustations, Controlling The Geochemical Evolution Of Fumarolic Encrustations, Valley Of Ten Thousand Smokes, Alaska Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Factors Controlling The Geochemical Evolution Of Fumarolic Encrustations, Valley Of Ten Thousand Smokes, Alaska Details Activities (3) Areas (1) Regions (0) Abstract: Factor and canonical correlation analysis of geochemical data from eight fossil fumaroles suggest that six major factors controlled the formation and evolution of fumarolic encrustations on the 1912 ash-flow sheet in the Valley of Ten Thousand Smokes (VTTS). The six-factor solution model explains a large proportion (low of 74% for Ni to high of 99% for Si) of the individual element data variance. Although the primary fumarolic

87

A Reconnaissance Geochemical Study Of La Primavera Geothermal...  

Open Energy Info (EERE)

Study Of La Primavera Geothermal Area, Jalisco, Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Reconnaissance Geochemical Study Of La...

88

A Geochemical Reconnaissance Of The Alid Volcaniccenter And Geothermal  

Open Energy Info (EERE)

Geochemical Reconnaissance Of The Alid Volcaniccenter And Geothermal Geochemical Reconnaissance Of The Alid Volcaniccenter And Geothermal System, Danakil Depression, Eritrea Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Geochemical Reconnaissance Of The Alid Volcaniccenter And Geothermal System, Danakil Depression, Eritrea Details Activities (0) Areas (0) Regions (0) Abstract: Geological and geochemical studies indicate that a high-temperature geothermalsystem underlies the Alid volcanic center in the northern Danakil depression of Eritrea Alid is avery late-Pleistocene structural dome formed by shallow intrusion of rhyolitic magma some of which vented as lavas and pyroclastic flows Fumaroles and boiling pools distributed widelyover an area of ~10 km2 on the northern half of Alid suggest that an activehydrothermal system underlies much of that part of

89

Computed solid phases limiting the concentration of dissolved constituents in basalt aquifers of the Columbia Plateau in eastern Washington. Geochemical modeling and nuclide/rock/groundwater interaction studies  

SciTech Connect (OSTI)

A speciation-solubility geochemical model, WATEQ2, was used to analyze geographically-diverse, ground-water samples from the aquifers of the Columbia Plateau basalts in eastern Washington. The ground-water samples compute to be at equilibrium with calcite, which provides both a solubility control for dissolved calcium and a pH buffer. Amorphic ferric hydroxide, Fe(OH)/sub 3/(A), is at saturation or modestly oversaturated in the few water samples with measured redox potentials. Most of the ground-water samples compute to be at equilibrium with amorphic silica (glass) and wairakite, a zeolite, and are saturated to oversaturated with respect to allophane, an amorphic aluminosilicate. The water samples are saturated to undersaturated with halloysite, a clay, and are variably oversaturated with regard to other secondary clay minerals. Equilibrium between the ground water and amorphic silica presumably results from the dissolution of the glassy matrix of the basalt. The oversaturation of the clay minerals other than halloysite indicates that their rate of formation lags the dissolution rate of the basaltic glass. The modeling results indicate that metastable amorphic solids limit the concentration of dissolved silicon and suggest the same possibility for aluminum and iron, and that the processes of dissolution of basaltic glass and formation of metastable secondary minerals are continuing even though the basalts are of Miocene age. The computed solubility relations are found to agree with the known assemblages of alteration minerals in the basalt fractures and vesicles. Because the chemical reactivity of the bedrock will influence the transport of solutes in ground water, the observed solubility equilibria are important factors with regard to chemical-retention processes associated with the possible migration of nuclear waste stored in the earth's crust.

Deutsch, W.J.; Jenne, E.A.; Krupka, K.M.

1982-08-01T23:59:59.000Z

90

Reactive Power Compensator.  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation. 26 figs.

El-Sharkawi, M.A.; Venkata, S.S.; Chen, M.; Andexler, G.; Huang, T.

1992-07-28T23:59:59.000Z

91

Reactive power compensator  

DOE Patents [OSTI]

A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation.

El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Woodinville, WA); Chen, Mingliang (Kirkland, WA); Andexler, George (Everett, WA); Huang, Tony (Seattle, WA)

1992-01-01T23:59:59.000Z

92

Oxyferryl Heme Reactivity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxyferryl Heme Reactivity Using both Radiation and Photochemical Oxyferryl Heme Reactivity Using both Radiation and Photochemical Techniques A. M. English, T. Fox, G. Tsaprailis, C. W. Fenwick, J. F. Wishart, J. T. Hazzard, and G. Tollin Adv. Chem. Ser. 254, Ch. 6, pp. 81-98 Abstract: Flash photolysis and pulse radiolysis were used to generate reductants in situ to study the electron-transfer (ET) reactivity of the FeIV=O heme centers in myoglobin and cytochrome c peroxidase. Reduction of a5RuIII groups covalently bound to surface histidines allowed intramolecular RuII --> FeIV=O ET rates to be measured. Protonation of the oxene ligand was found to be largely rate determining in myoglobin, consistent with the lack of proton donors in its heme pocket. The large distance (21-23 Å) between surface histidines and the heme in wild-type

93

Reactivity of Acid Generators  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Acid Generators for Chemically Amplified Resists with Reactivity of Acid Generators for Chemically Amplified Resists with Low-Energy Electrons Atsuro Nakano, Takahiro Kozawa, Seiichi Tagawa, Tomasz Szreder, James F. Wishart, Toshiyuki Kai and Tsutomu Shimokawa Jpn. J. Appl. Phys., 45, L197-L200 (2006). [Find paper at the Japanese Journal of Applied Physics] Abstract: In chemically amplified resists for ionizing radiations such as electron beams and extreme ultraviolet (EUV), low-energy electrons play an important role in the pattern formation processes. The reactivity of acid generators with low-energy electrons was evaluated using solvated electrons in tetrahydrofuran, which were generated by a pulsed electron beam. The rate constants of acid generators with the solvated electrons ranged from 0.6 to 1.9 x 1011 M-1s-1

94

Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal  

Open Energy Info (EERE)

Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal Areas Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal Areas Details Activities (5) Areas (5) Regions (0) Abstract: Hg contents of soils in geothermal areas in the western U.S. were measured and a three-fold distribution was observed: peak, aureole and background. Peak values (up to several 100 ppm Hg) occur in fumaroles of vapour-dominated systems, around hot springs, and in zones overlying steeply dipping, hot-water aquifers. Aureoic values (up to several 100 ppb Hg) are found in zones surrounding the peak areas and delineate areas with shallow geothermal convection. Background values vary between 7 and 40 ppb

95

A Geochemical Model Of The Platanares Geothermal System, Honduras | Open  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » A Geochemical Model Of The Platanares Geothermal System, Honduras Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Geochemical Model Of The Platanares Geothermal System, Honduras Details Activities (0) Areas (0) Regions (0) Abstract: Results of exploration drilling combined with results of geologic, geophysical, and hydrogeochemical investigations have been used to construct a geochemical model of the Platanares geothermal system, Honduras. Three coreholes were drilled, two of which produced fluids from fractured Miocene andesite and altered Cretaceous to Eocene conglomerate at

96

Temporal Geochemical Variations In Volatile Emissions From Mount St Helens,  

Open Energy Info (EERE)

Temporal Geochemical Variations In Volatile Emissions From Mount St Helens, Temporal Geochemical Variations In Volatile Emissions From Mount St Helens, Usa, 1980-1994 Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Temporal Geochemical Variations In Volatile Emissions From Mount St Helens, Usa, 1980-1994 Details Activities (2) Areas (1) Regions (0) Abstract: Fumarole discharges (95-560°C) collected from the dacite dome inside Mount St. Helens crater show temporal changes in their isotopic and chemical compositions. A ΔD vs. Δ18O plot shows that condensed waters from the gases are mixtures of meteoric and magmatic components, but that the apparent magmatic end-member in 1994 was depleted by about 7‰ in ΔD relative to the apparent end-member in 1980. Based on ΔD modeling, approximately 63% of shallow, post-1980 magma has yet to degas.

97

Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining District,  

Open Energy Info (EERE)

Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining District, Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining District, Eastern California Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining District, Eastern California Details Activities (0) Areas (0) Regions (0) Abstract: Banded, epithermal quartz-adularia veins have produced about 1.5 million ounces of gold and 7 million ounces of silver from the Bodie mining district, eastern California. The veins cut dacitic lava flows, pyroclastic rocks and intrusions. Sinter boulders occur in a graben structure at the top of Bodie Bluff and fragments of sinter and mineralized quartz veins occur in hydrothermal breccias nearby. Explosive venting evidently was part of the evolution of the ore-forming geothermal systems which, at one time,

98

Spatial And Temporal Geochemical Trends In The Hydrothermal System Of  

Open Energy Info (EERE)

Spatial And Temporal Geochemical Trends In The Hydrothermal System Of Spatial And Temporal Geochemical Trends In The Hydrothermal System Of Yellowstone National Park- Inferences From River Solute Fluxes Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Spatial And Temporal Geochemical Trends In The Hydrothermal System Of Yellowstone National Park- Inferences From River Solute Fluxes Details Activities (2) Areas (1) Regions (0) Abstract: We present and analyze a chemical dataset that includes the concentrations and fluxes of HCO3-, SO42-, Cl-, and F- in the major rivers draining Yellowstone National Park (YNP) for the 2002-2004 water years (1 October 2001 - 30 September 2004). The total (molar) flux in all rivers decreases in the following order, HCO3- > Cl- > SO42- > F-, but each river is characterized by a distinct chemical composition, implying large-scale

99

A Reconnaissance Geochemical Study Of La Primavera Geothermal Area,  

Open Energy Info (EERE)

Reconnaissance Geochemical Study Of La Primavera Geothermal Area, Reconnaissance Geochemical Study Of La Primavera Geothermal Area, Jalisco, Mexico Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Reconnaissance Geochemical Study Of La Primavera Geothermal Area, Jalisco, Mexico Details Activities (0) Areas (0) Regions (0) Abstract: The Sierra La Primavera, a late Pleistocene rhyolitic caldera complex in Jalisco, Mexico, contains fumaroles and large-discharge 65°C hot springs that are associated with faults related to caldera collapse and to later magma insurgence. The nearly-neutral, sodium bicarbonate, hot springs occur at low elevations at the margins of the complex, whereas the water-rich fumaroles are high and central. The Comision Federal de Electricidad de Mexico (CFE) has recently drilled two deep holes at the

100

Reactive Power Compensating System.  

DOE Patents [OSTI]

The circuit was designed for the specific application of wind-driven induction generators. It has great potential for application in any situation where a varying reactive power load is present, such as with induction motors or generators, or for transmission network compensation.

Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

1985-01-04T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Reactive power compensating system  

DOE Patents [OSTI]

The reactive power of an induction machine is compensated by providing fixed capacitors on each phase line for the minimum compensation required, sensing the current on one line at the time its voltage crosses zero to determine the actual compensation required for each phase, and selecting switched capacitors on each line to provide the balance of the compensation required.

Williams, Timothy J. (Redondo Beach, CA); El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Seattle, WA)

1987-01-01T23:59:59.000Z

102

Chemically Reactive Working Fluids  

Broader source: Energy.gov (indexed) [DOE]

Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Argonne National Laboratory Award Number: CPS25657 | April 15, 2013 | Brotzman * Thermodynamic and...

103

Preliminary Simulations of CO2 Transport in the Dolostone Formations in the Ordos Basin, China  

SciTech Connect (OSTI)

This report summarizes preliminary 2-D reactive-transport simulations on the injection, storage and transport of supercritical CO{sub 2} in dolostone formations in the Ordos Basin in China. The purpose of the simulations was to evaluate the role that basin heterogeneity, permeability, CO{sub 2} flux, and geochemical reactions between the carbonate geology and the CO{sub 2} equilibrated brines have on the evolution of porosity and permeability in the storage reservoir. The 2-D simulation of CO{sub 2} injection at 10{sup 3} ton/year corresponds to CO{sub 2} injection at a rate of 3 x 10{sup 5} ton/year in a 3-D, low permeable rock. An average permeability of 10 md was used in the simulation and reflects the upper range of permeability reported for the Ordos Basin Majiagou Group. Transport and distribution of CO{sub 2} between in the gas, aqueous, and solid phases were followed during a 10-year injection phase and a 10-year post injection phase. Our results show that CO{sub 2} flux and the spatial distribution of reservoir permeability will dictate the transport of CO{sub 2} in the injection and post injection phases. The injection rate of supercritical CO{sub 2} into low permeable reservoirs may need to be adjusted to avoid over pressure and mechanical damage to the reservoir. Although it should be noted that 3-D simulations are needed to more accurately model pressure build-up in the injection phase. There is negligible change in porosity and permeability due to carbonate mineral dissolution or anhydrite precipitation because a very small amount of carbonate dissolution is required to reach equilibrium with respect these phases. Injected CO{sub 2} is stored largely in supercritical and dissolved phases. During the injection phase, CO{sub 2} is transport driven by pressure build up and CO{sub 2} buoyancy.

Hao, Y; Wolery, T; Carroll, S

2009-04-30T23:59:59.000Z

104

Crustal melting in the Himalayan orogen : field, geochemical and geochronological studies in the Everest region, Nepal  

E-Print Network [OSTI]

A combination of field studies and geochemical techniques were used to investigate the timing and processes involved in leucogranite generation in the Everest region of the Himalayan orogen. Geochemical investigations ...

Viskupic, Karen M. (Karen Marie), 1975-

2003-01-01T23:59:59.000Z

105

Geochemical Modeling of ILAW Lysimeter Water Extracts  

SciTech Connect (OSTI)

Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network than gibbsite under field conditions. This may be due to the availability of carbonate that exists in the Hanford sediments as calcite. A significant source of carbonate was not available in the PCTs and this may account for why this phase did not appear in the PCTs. Sepiolite was consistently highly undersaturated, suggesting that another phase controls the solubility of magnesium. For samples that were most impacted by the effects of glass corrosion, magnesite appears to control glass corrosion. For samples that show less impacts from glass corrosion, clinochlore-7A or saponite-Mg appears to control the magnesium concentrations. For zinc, it appears that zincite is a better candidate than Zn(OH)2-? for controlling zinc concentrations in the extracts; however, in some samples all zinc phases considered were highly oversaturated. As a result the phase that controls zinc concentrations in the lysimeter extracts remains uncertain.

Cantrell, Kirk J.

2014-12-22T23:59:59.000Z

106

Geochemical and physical properties of wetland soils at the Savannah River site  

SciTech Connect (OSTI)

The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

1996-05-01T23:59:59.000Z

107

U.S. Geological Survey National Produced Waters Geochemical Database v2.0 (PROVISIONAL)  

E-Print Network [OSTI]

U.S. Geological Survey National Produced Waters Geochemical Database v2.0 (PROVISIONAL (USGS) National Produced Waters Geochemical Database v2.0 are provisional and subject to revision Produced Waters Geochemical Database v2.0 should be used with careful consideration of its limitations

Torgersen, Christian

108

Reactive Air Aluminization  

SciTech Connect (OSTI)

Ferritic stainless steels and other alloys are of great interest to SOFC developers for applications such as interconnects, cell frames, and balance of plant components. While these alloys offer significant advantages (e.g., low material and manufacturing cost, high thermal conductivity, and high temperature oxidation resistance), there are challenges which can hinder their utilization in SOFC systems; these challenges include Cr volatility and reactivity with glass seals. To overcome these challenges, protective coatings and surface treatments for the alloys are under development. In particular, aluminization of alloy surfaces offers the potential for mitigating both evaporation of Cr from the alloy surface and reaction of alloy constituents with glass seals. Commercial aluminization processes are available to SOFC developers, but they tend to be costly due to their use of exotic raw materials and/or processing conditions. As an alternative, PNNL has developed Reactive Air Aluminization (RAA), which offers a low-cost, simpler alternative to conventional aluminization methods.

Choi, Jung-Pyung; Chou, Y. S.; Stevenson, Jeffry W.

2011-10-28T23:59:59.000Z

109

Initiation and reactivation of Proterozoic aulacogen, northern Mexico  

SciTech Connect (OSTI)

Geochemical and petrologic affinities of late Proterozoic (approx. 1Ga) bimodal igneous rocks of the Franklin Mountains, west Texas, suggest a rift origin. Scattered occurrences of similar rocks southward into the state of Chihuahua, Mexico, indicate a southerly trend for the feature. The feature is bounded by stable blocks: the stable craton of west Texas to the east and northeast, and the Sierra del Nido block to the west and southwest. Separation of the Sierra del Nido block from the craton occurred about 1 Ga. Gravity gradients mark the boundaries of the blocks, and a northwest-trending Bouger gravity high may mark the axis of the aulacogen. The aulacogen and the Sierra del Nido block are truncated to the south by the Mesozoic Mojave-Sonora discontinuity. The aulacogen was reactivated, at least in part, in the late Paleozoic as the Pedregosa basin and in the Mesozoic as the Chihuahua trough. These reactivations were apparently not full-fledged rifting events, but did result in basin development. The Sierra del Nido block was a paleographic high throughout the Paleozoic, and the Aldama platform developed on this block during the Cretaceous. The most recent reactivation of the aulacogen is as the southern extension of the Rio Grande rift, as evidenced by trends of high heat flow, recent mafic magmatism, and regional extensional faulting.

Goodell, P.C.; Dyer, R.; Keller, G.R.

1985-02-01T23:59:59.000Z

110

Merging High Resolution Geophysical and Geochemical Surveys to Reduce  

Open Energy Info (EERE)

Merging High Resolution Geophysical and Geochemical Surveys to Reduce Merging High Resolution Geophysical and Geochemical Surveys to Reduce Exploration Risk at Glass Buttes, Oregon Geothermal Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Merging High Resolution Geophysical and Geochemical Surveys to Reduce Exploration Risk at Glass Buttes, Oregon Project Type / Topic 1 Recovery Act: Geothermal Technologies Program Project Type / Topic 2 Validation of Innovative Exploration Technologies Project Description This program will combine detailed gravity, high resolution aeromagnetic, and LIDAR data, all of which will be combined for structural modeling, with hyperspectral data, which will identify and map specific minerals and mineral assemblages that may point to upflow zones. The collection of these surveys and analyses of the merged data and model will be used to site deeper slim holes. Slim holes will be flow tested to determine whether or not Ormat can move forward with developing this resource. An innovative combination of geophysical and geochemical tools will significantly reduce risk in exploring this area, and the results will help to evaluate the value of these tools independently and in combination when exploring for blind resources where structure, permeability, and temperature are the most pressing questions. The slim holes will allow testing of models and validation of methods, and the surveys within the wellbores will be used to revise the models and site production wells if their drilling is warranted.

111

NMR of Layered Silicates in Argonne Coals and Geochemical Implications  

Science Journals Connector (OSTI)

NMR of Layered Silicates in Argonne Coals and Geochemical Implications ... Chemistry Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 ... High-resolution 27Al and 29Si NMR were employed to characterize layered silicates in the suite of eight Argonne Premium coals. ...

A. R. Thompson; R. E. Botto

2000-12-13T23:59:59.000Z

112

X-ray microtomography characterization of porosity, permeability and reactive surface changes during dissolution  

E-Print Network [OSTI]

X-ray microtomography characterization of porosity, permeability and reactive surface changes from X-ray microtomography data obtained before and after a set of dissolution experiments of pure.V. All rights reserved. Keywords: Reactive transport Carbon storage Permeability X-ray microtomography 1

Luquot, Linda

113

Reactive Maintenance | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Reactive Maintenance Reactive Maintenance Reactive Maintenance October 7, 2013 - 9:40am Addthis Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities. Advantages Reactive maintenance advantages are a double-edged sword. Federal agencies following a purely reactive maintenance strategy can expect little expenditures for manpower or system upkeep until something breaks. However, systems do break. With new equipment, Federal agencies can expect minimal incidents of failure. However, older equipment often experiences higher failure incidents and costlier repairs. Other advantages of reactive maintenance are:

114

Lectures on geochemical interpretation of hydrothermal waters | Open Energy  

Open Energy Info (EERE)

form form View source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with form History Facebook icon Twitter icon » Lectures on geochemical interpretation of hydrothermal waters Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Lectures on geochemical interpretation of hydrothermal waters Abstract The alkali carbonates, Na, K, and Li, are relatively soluble at all temperatures and generally precipitate only where there is extreme evapora- tion. In contrast, the alkaline earth carbonates. Ca. Ht, Sr, and Ba, are moderately to sparingly soluble and commonly precipitate in bydrothecmal systems. Calcite is by far the most abundant and important carbonate found

115

Geochemical modeling of the Raft River geothermal field | Open Energy  

Open Energy Info (EERE)

Page Page Edit History Facebook icon Twitter icon » Geochemical modeling of the Raft River geothermal field Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Report: Geochemical modeling of the Raft River geothermal field Details Activities (1) Areas (1) Regions (0) Abstract: The results to date of chemical modeling of the Raft River KGRA are presented. Earlier work indicated a northwest-southeast anomaly in the contours. Modeling techniques applied to more complete data allowed further definition of the anomaly. Models described in this report show the source of various minerals in the geothermal water. There appears to be a regional heat source that gives rise to uniform conductive heat flow in the region, but convective flow is concentrated near the upwelling in the Crook well

116

Geochemical characterization of geothermal systems in the Great Basin:  

Open Energy Info (EERE)

characterization of geothermal systems in the Great Basin: characterization of geothermal systems in the Great Basin: Implications for exploration, exploitation, and environmental issues Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Paper: Geochemical characterization of geothermal systems in the Great Basin: Implications for exploration, exploitation, and environmental issues Details Activities (0) Areas (0) Regions (0) Abstract: The objective of this ongoing project is the development of a representative geochemical database for a comprehensive range of elemental and isotopic parameters (i.e., beyond the typical data suite) for a range of geothermal systems in the Great Basin. Development of this database is one of the first steps in understanding the nature of geothermal systems in the Great Basin. Of particular importance in the Great Basin is utilizing

117

Version 4. 00 of the MINTEQ geochemical code  

SciTech Connect (OSTI)

The MINTEQ code is a thermodynamic model that can be used to calculate solution equilibria for geochemical applications. Included in the MINTEQ code are formulations for ionic speciation, ion exchange, adsorption, solubility, redox, gas-phase equilibria, and the dissolution of finite amounts of specified solids. Since the initial development of the MINTEQ geochemical code, a number of undocumented versions of the source code and data files have come into use at the Pacific Northwest Laboratory (PNL). This report documents these changes, describes source code modifications made for the Aquifer Thermal Energy Storage (ATES) program, and provides comprehensive listings of the data files. A version number of 4.00 has been assigned to the MINTEQ source code and the individual data files described in this report.

Eary, L.E.; Jenne, E.A.

1992-09-01T23:59:59.000Z

118

Version 4.00 of the MINTEQ geochemical code  

SciTech Connect (OSTI)

The MINTEQ code is a thermodynamic model that can be used to calculate solution equilibria for geochemical applications. Included in the MINTEQ code are formulations for ionic speciation, ion exchange, adsorption, solubility, redox, gas-phase equilibria, and the dissolution of finite amounts of specified solids. Since the initial development of the MINTEQ geochemical code, a number of undocumented versions of the source code and data files have come into use at the Pacific Northwest Laboratory (PNL). This report documents these changes, describes source code modifications made for the Aquifer Thermal Energy Storage (ATES) program, and provides comprehensive listings of the data files. A version number of 4.00 has been assigned to the MINTEQ source code and the individual data files described in this report.

Eary, L.E.; Jenne, E.A.

1992-09-01T23:59:59.000Z

119

Asphaltenes as indicators of the geochemical history of oil  

SciTech Connect (OSTI)

A method of decomposition of native asphaltenes from naphthenic oils is proposed as a source of information on the geochemical history of the oils. It is demonstrated that formation of naphthenic oils occurs in nature through biodegradation of primary paraffinic oils. The relative abundances of structural groups and individual saturated hydrocarbons obtained from the asphaltenes in naphthenic oils is similar to the relative abundance of hydrocarbons in paraffinic oils, which are their genetic precursors. (JMT)

Aref'yev, O.A.; Makushina, V.M.; Petrov, A.A.

1982-06-01T23:59:59.000Z

120

Argonne Geothermal Geochemical Database v2.0  

SciTech Connect (OSTI)

A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

Christopher Harto

2013-05-22T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Federal Energy Management Program: Reactive Maintenance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactive Reactive Maintenance to someone by E-mail Share Federal Energy Management Program: Reactive Maintenance on Facebook Tweet about Federal Energy Management Program: Reactive Maintenance on Twitter Bookmark Federal Energy Management Program: Reactive Maintenance on Google Bookmark Federal Energy Management Program: Reactive Maintenance on Delicious Rank Federal Energy Management Program: Reactive Maintenance on Digg Find More places to share Federal Energy Management Program: Reactive Maintenance on AddThis.com... Sustainable Buildings & Campuses Operations & Maintenance Federal Requirements Program Management Commissioning Metering Computerized Maintenance Management Systems Maintenance Types Reactive Preventive Predictive Reliability-Centered Major Equipment Types

122

A geochemical model of the Kilauea east rift zone | Open Energy Information  

Open Energy Info (EERE)

A geochemical model of the Kilauea east rift zone A geochemical model of the Kilauea east rift zone Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A geochemical model of the Kilauea east rift zone Abstract N/A Author Donald Thomas Published Journal US Geological Survey Professional Paper 1350, 1987 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for A geochemical model of the Kilauea east rift zone Citation Donald Thomas. 1987. A geochemical model of the Kilauea east rift zone. US Geological Survey Professional Paper 1350. (!) . Retrieved from "http://en.openei.org/w/index.php?title=A_geochemical_model_of_the_Kilauea_east_rift_zone&oldid=682589" Categories: Missing Required Information References Uncited References Geothermal References

123

Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems  

Broader source: Energy.gov [DOE]

Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems presentation at the April 2013 peer review meeting held in Denver, Colorado.

124

Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners  

Broader source: Energy.gov [DOE]

Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners presentation at the April 2013 peer review meeting held in Denver, Colorado.

125

Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators  

Broader source: Energy.gov [DOE]

Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators presentation at the April 2013 peer review meeting held in Denver, Colorado.

126

Metal-based reactive nanomaterials  

Science Journals Connector (OSTI)

Recent developments in materials processing and characterization resulted in the discovery of a new type of reactive materials containing nanoscaled metal components. The well-known high oxidation energies of metallic fuels can now be released very rapidly because of the very high reactive interface areas in such metal-based reactive nanomaterials. Consequently, these materials are currently being examined for an entire range of applications in energetic formulations inappropriate for conventional, micron-sized metal fuels having relatively low reaction rates. New application areas, such as reactive structural materials, are also being explored. Research remains active in manufacturing and characterization of metal-based reactive nanomaterials including elemental metal nanopowders and various nanocomposite material systems. Because of the nanometer scale of the individual particles, or phase domains, and because of the very high enthalpy of reaction between components of the nanocomposite materials, the final phase compositions, morphology, and thermodynamic properties of the reactive nanocomposite materials may be different from those of their micron-scaled counterparts. Ignition mechanisms in such materials can be governed by heterogeneous reactions that are insignificant for materials with less developed reactive interface areas. New combustion regimes are being observed that are affected by very short ignition delays combined with very high metal combustion temperatures. Current progress in this rapidly growing research area is reviewed and some potential directions for the future research are discussed.

Edward L. Dreizin

2009-01-01T23:59:59.000Z

127

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

128

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

129

Feed gas contaminant removal in ion transport membrane systems  

SciTech Connect (OSTI)

An oxygen ion transport membrane process wherein a heated oxygen-containing gas having one or more contaminants is contacted with a reactive solid material to remove the one or more contaminants. The reactive solid material is provided as a deposit on a support. The one or more contaminant compounds in the heated oxygen-containing gas react with the reactive solid material. The contaminant-depleted oxygen-containing gas is contacted with a membrane, and oxygen is transported through the membrane to provide transported oxygen.

Underwood, Richard Paul (Allentown, PA); Makitka, III, Alexander (Hatfield, PA); Carolan, Michael Francis (Allentown, PA)

2012-04-03T23:59:59.000Z

130

Conservation of reactive electromagnetic energy in reactive time  

E-Print Network [OSTI]

The complex Poynting theorem (CPT) is extended to a canonical time-scale domain $(t,s)$. Time-harmonic phasors are replaced by the positive-frequency parts of general fields, which extend analytically to complex time $t+is$, with $s>0$ interpreted as a time resolution scale. The real part of the extended CPT gives conservation in $t$ of a time-averaged field energy, and its imaginary part gives conservation in $s$ of a time-averaged reactive energy. In both cases, the averaging windows are determined by a Cauchy kernel of width $\\Delta t\\sim \\pm s$. This completes the time-harmonic CPT, whose imaginary part is generally supposed to be vaguely `related to' reactive energy without giving a conservation law, or even an expression, for the latter. The interpretation of $s$ as reactive time, tracking the leads and lags associated with stored capacitative and inductive energy, gives a simple explanation of the volt-ampere reactive (var) unit measuring reactive power: a var is simply one Joule per reactive second. T...

Kaiser, Gerald

2015-01-01T23:59:59.000Z

131

Geochemical data package for the Hanford immobilized low-activity tank waste performance assessment (ILAW PA)  

SciTech Connect (OSTI)

Lockheed Martin Hanford Company (LMHC) is designing and assessing the performance of disposal facilities to receive radioactive wastes that are stored in single- and double-shell tanks at the Hanford Site. The preferred method of disposing of the portion that is classified as low-activity waste is to vitrify the liquid/slurry and place the solid product in near-surface, shallow-land burial facilities. The LMHC project to assess the performance of these disposal facilities is the Hanford Immobilized Low-Activity Tank Waste (ILAW) Performance Assessment (PA) activity. The goal of this project is to provide a reasonable expectation that the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require prediction of contaminant migration from the facilities. This migration is expected to occur primarily via the movement of water through the facilities, and the consequent transport of dissolved contaminants in the porewater of the vadose zone. Pacific Northwest National Laboratory assists LMHC in their performance assessment activities. One of the PNNL tasks is to provide estimates of the geochemical properties of the materials comprising the disposal facility, the disturbed region around the facility, and the physically undisturbed sediments below the facility (including the vadose zone sediments and the aquifer sediments in the upper unconfined aquifer). The geochemical properties are expressed as parameters that quantify the adsorption of contaminants and the solubility constraints that might apply for those contaminants that may exceed solubility constraints. The common parameters used to quantify adsorption and solubility are the distribution coefficient (K{sub d}) and the thermodynamic solubility product (K{sub sp}), respectively. In this data package, the authors approximate the solubility of contaminants using a more simplified construct, called the solution concentration limit, a constant value. In future geochemical data packages, they will determine whether a more rigorous measure of solubility is necessary or warranted based on the dose predictions emanating from the ILAW 2001 PA and reviewers' comments. The K{sub d}s and solution concentration limits for each contaminant are direct inputs to subsurface flow and transport codes used to predict the performance of the ILAW system. In addition to the best-estimate K{sub d}s, a reasonable conservative value and a range are provided. They assume that K{sub d} values are log normally distributed over the cited ranges. Currently, they do not give estimates for the range in solubility limits or their uncertainty. However, they supply different values for both the K{sub d}s and solution concentration limits for different spatial zones in the ILAW system and supply time-varying K{sub d}s for the concrete zone, should the final repository design include concrete vaults or cement amendments to buffer the system pH.

DI Kaplan; RJ Serne

2000-02-24T23:59:59.000Z

132

Fuel Temperature Coefficient of Reactivity  

SciTech Connect (OSTI)

A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

Loewe, W.E.

2001-07-31T23:59:59.000Z

133

Effect of Subgrid Heterogeneity on Scaling Geochemical and Biogeochemical Reactions: A Case of U(VI) Desorption  

SciTech Connect (OSTI)

The effect of subgrid heterogeneity in sediment properties on the rate of uranyl[U(VI)] desorption was investigated using a sediment collected from the US Department of Energy Hanford site. The sediment was sieved into 7 grain size fractions that each exhibited different U(VI) desorption properties. Six columns were assembled using the sediment with its grain size fractions arranged in different spatial configurations to mimic subgrid heterogeneity in reactive transport properties. The apparent rate of U(VI) desorption varied significantly in the columns. Those columns with sediment structures leading to preferential transport had much lower rates of U(VI) desorption than those with relatively homogeneous transport. Modeling analysis indicated that the U(VI) desorption model and parameters characterized from well-mixed reactors significantly over-predicted the measured U(VI) desorption in the columns with preferential transport. A dual domain model, which operationally separates reactive transport properties into two subgrid domains improved the predictions significantly. A similar effect of subgrid heterogeneity, albeit at a less degree, was observed for denitrification, which also occurred in the columns. The results imply that subgrid heterogeneity is an important consideration in extrapolating reaction rates from the laboratory to field.

Liu, Chongxuan; Shang, Jianying; Shan, Huimei; Zachara, John M.

2014-02-04T23:59:59.000Z

134

Surface and Subsurface Geochemical Monitoring of an EOR-CO2 Field: Buracica, Brazil  

E-Print Network [OSTI]

Surface and Subsurface Geochemical Monitoring of an EOR-CO2 Field: Buracica, Brazil C. Magnier1, V Monitoring of an EOR-CO2 Field: Buracica, Brazil -- This paper presents a surface and subsurface geochemical survey of the Buracica EOR-CO2 field onshore Brazil. We adopted a methodology coupling the stable

Paris-Sud XI, Université de

135

UNDERGRADUATE FELLOWSHIP RECIPIENTS: Stephanie Freeman -Permanent Reactive  

E-Print Network [OSTI]

Baillie - Quantifying San Pedro River Inflows to Improve Riparian Sustainability Efforts: A Geochemical of Development near Riparian Areas through Community Design and Land Stewardship, Landscape Architecture Carla De Engineering GRADUATE FELLOWSHIP RECIPIENTS: Dustin Garrick - Simulating Sustainability: Conjunctively Managing

Fay, Noah

136

Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers  

SciTech Connect (OSTI)

This report is the final scientific one for the award DE- FE0000988 entitled Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers. The work has been divided into six tasks. In task, Development of a Three-Phase Non-Isothermal CO2 Flow Module, we developed a fluid property module for brine-CO2 mixtures designed to handle all possible phase combinations of aqueous phase, sub-critical liquid and gaseous CO2, supercritical CO2, and solid salt. The thermodynamic and thermophysical properties of brine-CO2 mixtures (density, viscosity, and specific enthalpy of fluid phases; partitioning of mass components among the different phases) use the same correlations as an earlier fluid property module that does not distinguish between gaseous and liquid CO2-rich phases. We verified the fluid property module using two leakage scenarios, one that involves CO2 migration up a blind fault and subsequent accumulation in a secondary parasitic reservoir at shallower depth, and another investigating leakage of CO2 from a deep storage reservoir along a vertical fault zone. In task, Development of a Rock Mechanical Module, we developed a massively parallel reservoir simulator for modeling THM processes in porous media brine aquifers. We derived, from the fundamental equations describing deformation of porous elastic media, a momentum conservation equation relating mean stress, pressure, and temperature, and incorporated it alongside the mass and energy conservation equations from the TOUGH2 formulation, the starting point for the simulator. In addition, rock properties, namely permeability and porosity, are functions of effective stress and other variables that are obtained from the literature. We verified the simulator formulation and numerical implementation using analytical solutions and example problems from the literature. For the former, we matched a one-dimensional consolidation problem and a two-dimensional simulation of the Mandel-Cryer effect. For the latter, we obtained a good match of temperature and gas saturation profiles, and surface uplift, after injection of hot fluid into a model of a caldera structure. In task, Incorporation of Geochemical Reactions of Selected Important Species, we developed a novel mathematical model of THMC processes in porous and fractured saline aquifers, simulating geo-chemical reactions associated with CO2 sequestration in saline aquifers. Two computational frameworks, sequentially coupled and fully coupled, were used to simulate the reactions and transport. We verified capabilities of the THMC model to treat complex THMC processes during CO2 sequestration by analytical solutions and we constructed reactive transport models to analyze the THMC process quantitatively. Three of these are 1D reactive transport under chemical equilibrium, a batch reaction model with equilibrium chemical reactions, and a THMC model with CO2 dissolution. In task Study of Instability in CO2 Dissolution-Diffusion-Convection Processes, We reviewed literature related to the study of density driven convective flows and on the instability of CO2 dissolution-diffusion-convection processes. We ran simulations that model the density-driven flow instability that would occur during CO2 sequestration. CO2 diffused through the top of the system and dissolved in the aqueous phase there, increasing its density. Density fingers formed along the top boundary, and coalesced into a few prominent ones, causing convective flow that forced the fluid to the system bottom. These simulations were in two and three dimensions. We ran additional simulations of convective mixing with density contrast caused by variable dissolved CO2 concentration in saline water, modeled after laboratory experiments in which supercritical CO2 was circulated in the headspace above a brine saturated packed sand in a pressure vessel. As CO2 dissolved into the upper part of the saturated sand, liquid phase density increases causing instability and setting off convective mixing. We obtained good agreement

Wu, Yu-Shu; Chen, Zizhong; Kazemi, Hossein; Yin, Xiaolong; Pruess, Karsten; Oldenburg, Curt; Winterfeld, Philip; Zhang, Ronglei

2014-09-30T23:59:59.000Z

137

Transportation Services  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Services Transporting nuclear materials within the United States and throughout the world is a complicated and sometimes highly controversial effort requiring...

138

Local Transportation  

E-Print Network [OSTI]

Local Transportation. Transportation from the Airport to Hotel. There are two types of taxi companies that operate at the airport: special and regular taxis (

139

Modeling biogechemical reactive transport in a fracture zone  

E-Print Network [OSTI]

is a prototype, full-scale underground facility launched andof Stockholm. The underground facility consists of a 3,600 m

Molinero, Jorge; Samper, Javier; Yang, Chan Bing, and Zhang, Guoxiang; Guoxiang, Zhang

2005-01-01T23:59:59.000Z

140

Fluid-Rock Interaction: A Reactive Transport Approach  

Science Journals Connector (OSTI)

...fluid-rock interaction systems as well-mixed reactors was challenged and it was shown how an...Q, Lichtner PC, Zhang D (2007) An improved lattice Boltzmann model for multicomponent...Eric H. editor CNRS-Universite Paul Sabatier, Laboratoire de Mecanisme de Transfert...

Carl I. Steefel; Kate Maher

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Chamber transport  

SciTech Connect (OSTI)

Heavy ion beam transport through the containment chamber plays a crucial role in all heavy ion fusion (HIF) scenarios. Here, several parameters are used to characterize the operating space for HIF beams; transport modes are assessed in relation to evolving target/accelerator requirements; results of recent relevant experiments and simulations of HIF transport are summarized; and relevant instabilities are reviewed. All transport options still exist, including (1) vacuum ballistic transport, (2) neutralized ballistic transport, and (3) channel-like transport. Presently, the European HIF program favors vacuum ballistic transport, while the US HIF program favors neutralized ballistic transport with channel-like transport as an alternate approach. Further transport research is needed to clearly guide selection of the most attractive, integrated HIF system.

OLSON,CRAIG L.

2000-05-17T23:59:59.000Z

142

WATEQ3 geochemical model: thermodynamic data for several additional solids  

SciTech Connect (OSTI)

Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

Krupka, K.M.; Jenne, E.A.

1982-09-01T23:59:59.000Z

143

Joint Energy and Reactive Power Market Considering Coupled Active and Reactive Reserve Market Ensuring System Security  

Science Journals Connector (OSTI)

Reactive power market is usually held as independent from energy and reserved active power markets; however, active and reactive power are ... synchronous generator capacity curve. Therefore, reactive power market

Hamed Ahmadi; Asghar Akbari Foroud

2014-06-01T23:59:59.000Z

144

Triclosan Reactivity in Chloraminated Waters  

Science Journals Connector (OSTI)

Triclosan Reactivity in Chloraminated Waters ... Triclosan, widely employed as an antimicrobial additive in many household personal care products, has recently been detected in wastewater treatment plant effluents and in source waters used for drinking water supplies. ... Chloramines used either as alternative disinfectants in drinking water treatment or formed during chlorination of nonnitrified wastewater effluents have the potential to react with triclosan. ...

Aimee E. Greyshock; Peter J. Vikesland

2006-03-16T23:59:59.000Z

145

Definition: Reactive Power | Open Energy Information  

Open Energy Info (EERE)

Reactive Power Reactive Power Jump to: navigation, search Dictionary.png Reactive Power The portion of electricity that establishes and sustains the electric and magnetic fields of alternating-current equipment. Reactive power must be supplied to most types of magnetic equipment, such as motors and transformers. It also must supply the reactive losses on transmission facilities. Reactive power is provided by generators, synchronous condensers, or electrostatic equipment such as capacitors and directly influences electric system voltage. It is usually expressed in kilovars (kvar) or megavars (Mvar).[1] View on Wikipedia Wikipedia Definition In electric power transmission and distribution, volt-ampere reactive (var) is a unit used to measure reactive power in an AC electric

146

Reactive Power Support Services in Electricity Markets  

E-Print Network [OSTI]

Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Final Project Report Power Systems Engineering Research Center A National Science Foundation Industry Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Project

147

Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley  

Open Energy Info (EERE)

Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999) Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999) Abstract This report tabulates an extensive geochemical database on waters, gases, scales,rocks, and hot-spring deposits from the Dixie Valley region, Nevada. The samples fromwhich the data were obtained were collected and analyzed during 1996 to 1999. Thesedata provide useful information for ongoing and future investigations on geothermalenergy, volcanism, ore deposits, environmental issues, and groundwater quality in thisregion. Authors Los Alamos National Laboratory and NM Published

148

Merging high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon  

Broader source: Energy.gov [DOE]

DOE Geothermal Technologies Peer Review - 2010. The primary objective of this project is to combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships.

149

UPb and geochemical evidence for a Cryogenian magmatic arc in central Novaya Zemlya, Arctic Russia  

E-Print Network [OSTI]

U­Pb and geochemical evidence for a Cryogenian magmatic arc in central Novaya Zemlya, Arctic Russia-0349 Oslo, Norway Introduction The High Arctic of Scandinavia and Russia consists of a collage

Svensen, Henrik

150

Geochemical characteristics and formation process of natural gas in Kela 2 gas field  

Science Journals Connector (OSTI)

On the basis of a large amount of natural gas components and the carbon isotope as well ... as some other analysis data in Kela 2 gas field, the geochemical characteristics, source, origin, and formation process ...

Mengjun Zhao; Shuangfang Lu; Tingdong Wang; Jian Li

2002-12-01T23:59:59.000Z

151

Geochemical characterization of karst groundwater in the cradle of humankind world heritage site, South Africa  

Science Journals Connector (OSTI)

The karst of the Cradle of Humankind World Heritage Site plays a major role ... model, indicating varying contributions of three identified end members (acid mine drainage, treated sewage ... , geochemical and sp...

M. Holland; K. T. Witthser

2009-04-01T23:59:59.000Z

152

Microbiological and Geochemical Heterogeneity in an In Situ Uranium Bioremediation Field Site  

Science Journals Connector (OSTI)

...VI) bioremediation. FIG. 1. Stratigraphy of borehole logs. Borehole logs collected from the in situ treatment plot installed...geochemical gradients that could be attributed in large part to the manner in which acetate was distributed...

Helen A. Vrionis; Robert T. Anderson; Irene Ortiz-Bernad; Kathleen R. O'Neill; Charles T. Resch; Aaron D. Peacock; Richard Dayvault; David C. White; Philip E. Long; Derek R. Lovley

2005-10-01T23:59:59.000Z

153

Migratory patterns of American shad (Alosa sapidissima) revealed by natural geochemical tags in otoliths  

E-Print Network [OSTI]

Geochemical signatures in the otoliths of diadromous fishes may allow for retrospective analyses of natal origins. In an assessment of river-specific signatures in American shad (Alosa sapidissima), an anadromous clupeid ...

Walther, Benjamin (Benjamin Dwaine)

2007-01-01T23:59:59.000Z

154

A Geological and Hydro-Geochemical Study of the Animas Geothermal...  

Open Energy Info (EERE)

Hydro-Geochemical Study of the Animas Geothermal Area, Hidalgo County, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Geological...

155

MODELING FLOW AND TRANSPORT PATHWAYS TO THE POTENTIAL REPOSITORY HORIZON AT YUCCA MOUNTAIN  

SciTech Connect (OSTI)

The isotopic ratios of {sup 36}Cl/Cl are used in conjunction with geologic interpretation and numerical modeling to evaluate flow and transport pathways, processes, and model parameters in the unsaturated zone at Yucca Mountain. By synthesizing geochemical and geologic data, the numerical model results provide insight into the validity of alternative hydrologic parameter sets, flow and transport processes in and away from fault zones, and the applicability of {sup 36}Cl/Cl. ratios for evaluating alternative conceptual models.

A.V. WOLFSBERG, G.J.C. ROEMER, J.T. FABRYKA-MARTIN, B.A. ROBINSON

1998-03-04T23:59:59.000Z

156

Characterization of the geochemical and physical properties of wetland soils on the Savannah River Site: Field sampling activities. Final report  

SciTech Connect (OSTI)

There are 36,000 acres of wetlands on the Savannah River Site (SRS) and an additional 5,000 acres of floodplain. Recent studies of wetland soils near various waste sites at SRS have shown that some wetlands have been contaminated with pollutants resulting from SRS operations. In general, releases of contaminants to wetland areas have been indirect. These releases may have originated at disposal lagoons or waste facilities located in the vicinity of the wetland areas. Transport mechanisms such as surface runoff, soil erosion, sediment transport, and groundwater seepage into downgradient wetland areas are responsible for the indirect discharges to the wetland areas. The SRS determined that a database of background geochemical and physical properties for wetland soils on the SRS was needed to facilitate future remedial investigations, human health and ecological risk assessments, treatability studies, and feasibility studies for the wetland areas. These data are needed for comparison to contaminant data collected from wetland soils that have been affected by contamination from SRS operations. This report describes the efforts associated with the collection of soil cores, preparation of a lithologic log for each core, and the processing and packaging of individual soil samples for shipment to analytical laboratory facilities.

Dixon, K.L. [Westinghouse Savannah River Co., Aiken, SC (United States)

1992-11-01T23:59:59.000Z

157

Reactive Ion Benjamin A. Small  

E-Print Network [OSTI]

(torr) plasma etching reactive ion etching ion milling m cm 100µm µm #12;5 Mechanics ~40 mTorrE380 kHz, 13.56 MHz ~30 sccm #12;6 Chemistry X X X X F- F- F-F- X F-F- F- F- F- R++ R++ R++ #12;7 Chemistry before opening · Silanes are explosive in the atmosphere #12;13 Bibliography Campbell, Stephen A

Garmestani, Hamid

158

Reactive composite compositions and mat barriers  

DOE Patents [OSTI]

A hazardous material storage area has a reactive multi-layer composite mat which lines an opening into which a reactive backfill and hazardous material are placed. A water-inhibiting cap may cover the hazardous material storage area. The reactive multi-layer composite mat has a backing onto which is placed an active layer which will neutralize or stabilize hazardous waste and a fronting layer so that the active layer is between the fronting and backing layers. The reactive backfill has a reactive agent which can stabilize or neutralize hazardous material and inhibit the movement of the hazardous material through the hazardous material storage area.

Langton, Christine A. (Aiken, SC); Narasimhan, Rajendran (Evans, GA); Karraker, David G. (Aiken, SC)

2001-01-01T23:59:59.000Z

159

Permeable Reactive Barriers | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barriers Permeable Reactive Barrier Field Projects Durango, Colorado DOE installed a PRB in October 1995 to treat ground water from a uranium mill tailings disposal site at Durango, Colorado Read more Cañon City, Colorado ESL personnel conduct tests and help evaluate performance at other PRB sites, such as Cotter Corporation's Cañon City site in Colorado. Read more Monticello, Utah Installation of a PRB hydraulically downgradient of the Monticello, Utah, millsite was completed June 30, 1999, as an Interim Remedial Action. Read more A permeable reactive barrier (PRB) is a zone of reactive material placed underground to intercept and react with a contaminant plume in ground water. Typically, PRBs are emplaced by replacing soils with reactive

160

Reactive capability limits of wind farms  

Science Journals Connector (OSTI)

Wind Energy Conversion Systems (WECS) technology can be classified into two main types: fixed speed and variable speed. Fixed speed WECS use an induction generator connected directly to the grid while variable speed WECS use a power converter to connect the generator to the grid. Fixed speed WECS require shunt capacitors for reactive power compensation, while variable speed WECS have reactive power capability. Under the Spanish grid code, wind farms have to operate in a range of power factor values. This paper determines the reactive power capability of wind farms equipped with both fixed and variable speed WECS. The reactive power capability can be represented as a reactive capability curve. In this paper, the reactive capability curve is used to calculate the additional reactive power compensation needed to meet the requirements of the Spanish grid code.

Alberto Rios Villacorta; Santiago Arnaltes Gomez; Jose Luis Rodriguez-Amenedo

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Final Report: Molecular Basis for Microbial Adhesion and Geochemical Surface Reactions: A Study Across Scales  

SciTech Connect (OSTI)

Computational chemistry was used to help provide a molecular level description of the interactions of Gram-negative microbial membranes with subsurface materials. The goal is to develop a better understanding of the molecular processes involved in microbial metal binding, microbial attachment to mineral surfaces, and, eventually, oxidation/reduction reactions (electron transfer) that can occur at these surfaces and are mediated by the bacterial exterior surface. The project focused on the interaction of the outer microbial membrane, which is dominated by an exterior lipopolysaccharide (LPS) portion, of Pseudomonas aeruginosa with the mineral goethite and with solvated ions in the environment. This was originally a collaborative project with T.P. Straatsma and B. Lowery of the Pacific Northwest National Laboratory. The University of Alabama effort used electronic structure calculations to predict the molecular behavior of ions in solution and the behavior of the sugars which form a critical part of the LPS. The interactions of the sugars with metal ions are expected to dominate much of the microscopic structure and transport phenomena in the LPS. This work, in combination with the molecular dynamics simulations of Straatsma and the experimental electrochemistry and microscopy measurements of Lowry, both at PNNL, is providing new insights into the detailed molecular behavior of these membranes in geochemical environments. The effort at The University of Alabama has three components: solvation energies and structures of ions in solution, prediction of the acidity of the critical groups in the sugars in the LPS, and binding of metal ions to the sugar anions. An important aspect of the structure of the LPS membrane as well as ion transport in the LPS is the ability of the sugar side groups such as the carboxylic acids and the phosphates to bind positively charged ions. We are studying the acidity of the acidic side groups in order to better understand the ability of these groups to bind metal ions. We need to understand the solvation properties of the metal ions in solution and their ability to bind not only to the sugars but to proteins and to other anions. Our goal is then to be able to predict the ability of the side groups to bind metal ions. One result from the earlier molecular dynamics simulations is the exclusion of water from the inner hydrophobic part of the membrane. We thus need to investigate the binding of the cations in media with different dielectric constants.

Dixon, David Adams [The University of Alabama

2013-06-27T23:59:59.000Z

162

BNL | CFN: Transport of Hazardous Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation of Hazardous Materials and Nanomaterials Transportation of Hazardous Materials and Nanomaterials The following contains guidance for transporting materials to and from BNL and for on-site transfers. All staff and users must adhere to Laboratory guidelines when making plans to move materials either by commercial carrier or in rented or personal vehicles. BNL hazardous material transport guidelines apply for products that meet the definition of hazardous materials according to 49 CFR 171.8 and any nanomaterial that has known hazardous properties (toxic, flammable, reactive). BNL guidelines are also provided for all other nanomaterials even if they have not been identified as hazardous materials. Some materials may be transported in personal vehicles as per "Materials of Trade" (MOT) guidance. The regulations for transporting MOT are much

163

Origin and geochemical evolution of the Michigan basin brine  

SciTech Connect (OSTI)

Chemical and isotopic data were collected on 126 oil field brine samples and were used to investigate the origin and geochemical evolution of water in 8 geologic formations in the Michigan basin. Two groups of brine are found in the basin, the Na-Ca-Cl brine in the upper Devonian formations, and Ca-Na-Cl brine from the lower Devonian and Silurian aged formations. Water in the upper Devonian Berea, Traverse, and Dundee formations originated from seawater concentrated into halite facies. This brine evolved by halite precipitation, dolomitization, aluminosilicate reactions, and the removal of SO{sub 4} by bacterial action or by CaSO{sub 4} precipitation. The stable isotopic composition (D, O) is thought to represent dilution of evapo-concentrated seawater by meteoric water. Water in the lower Devonian Richfield, Detroit River Group, and Niagara-Salina formations is very saline Ca-Na-Cl brine. Cl/Br suggest it originated from seawater concentrated through the halite and into the MgSO{sub 4} salt facies, with an origin linked to the Silurian and Devonian salt deposits. Dolomitization and halite precipitation increased the Ca/Na, aluminosilicate reactions removed K, and bacterial action or CaSO{sub 4} precipitation removed SO{sub 4} from this brine. Water chemistry in the Ordovician Trenton-Black River formations indicates dilution of evapo-concentrated seawater by fresh or seawater. Possible saline end-members include Ordovician seawater, present-day upper Devonian brine, or Ca-Cl brine from the deeper areas in the basin.

Wilson, T.P.

1989-01-01T23:59:59.000Z

164

Transportation Demand  

Gasoline and Diesel Fuel Update (EIA)

page intentionally left blank page intentionally left blank 69 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2011 Transportation Demand Module The NEMS Transportation Demand Module estimates transportation energy consumption across the nine Census Divisions (see Figure 5) and over ten fuel types. Each fuel type is modeled according to fuel-specific technology attributes applicable by transportation mode. Total transportation energy consumption is the sum of energy use in eight transport modes: light-duty vehicles (cars and light trucks), commercial light trucks (8,501-10,000 lbs gross vehicle weight), freight trucks (>10,000 lbs gross vehicle weight), buses, freight and passenger aircraft, freight and passenger rail, freight shipping, and miscellaneous

165

Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same  

DOE Patents [OSTI]

An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

Fritz, Gregory M; Knepper, Robert Allen; Weihs, Timothy P; Gash, Alexander E; Sze, John S

2013-04-30T23:59:59.000Z

166

Model evaluation of geochemically induced swelling/shrinkage in argillaceous formations for nuclear waste disposal  

Science Journals Connector (OSTI)

Abstract Argillaceous formations are being considered as host rocks for geologic disposal of nuclear waste in a number of countries. One advantage of emplacing nuclear waste in such formations is the potential self-sealing capability of clay due to swelling, which is of particular importance for the sealing and healing of disturbed rock zones (DRZ). It is therefore necessary to understand and be able to predict the changes in swelling properties within clay rock near the waste-emplacement tunnel. In this paper, considering that the clay rock formation is mostly under saturated conditions and the swelling property changes are mostly due to geochemical changes, we propose a modeling method that links a THC simulator with a swelling module that is based on diffuse double layer theory. Simulations were conducted to evaluate the geochemically induced changes in the swelling properties of the clay rock. Our findings are as follows: (1) geochemically induced swelling/shrinkage occurs exclusively in the EBSclay formation interface, within a few meters from the waste-emplacement tunnels; (2) swelling/shrinkage-induced porosity changes are generally much smaller than those caused by mineral precipitation/dissolution processes; (3) geochemically induced swelling/shrinkage of the host clay rock is affected by variations in the pore water chemistry, exchangeable cations, and smectite abundance. Neglecting any of these three factors might lead to a miscalculation of the geochemically induced swelling pressure.

Liange Zheng; Jonny Rutqvist; Hui-Hai Liu; Jens T. Birkholzer; Eric Sonnenthal

2014-01-01T23:59:59.000Z

167

WIPP Transportation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transuranic Waste Transportation Container Documents Documents related to transuranic waste containers and packages. CBFO Tribal Program Information about WIPP shipments across...

168

Transportation Security  

Broader source: Energy.gov (indexed) [DOE]

Preliminary Draft - For Review Only 1 Transportation Security Draft Annotated Bibliography Review July 2007 Preliminary Draft - For Review Only 2 Work Plan Task * TEC STG Work...

169

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

170

Rejuvenating Permeable Reactive Barriers by Chemical Flushing  

Broader source: Energy.gov [DOE]

Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

171

Exploring the reactivity of bacterial multicomponent monooxygenases  

E-Print Network [OSTI]

Chapter 1. Introduction: The Reactivity of Bacterial Multicomponent Monooxygenases Bacterial multicomponent monooxygenases constitute a remarkable family of enzymes that oxidize small, inert hydrocarbon substrates using ...

Tinberg, Christine Elaine

2010-01-01T23:59:59.000Z

172

Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area,  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah Abstract Chemical interaction of thermal brines with reservoir rock in the Roosevelt Hot Springs thermal area has resulted in the development of distinctive trace element signatures. Geochemical analysis of soil sample, shallow temperature gradient drill hole cuttings and deep drill hole cutting provides a three dimensional perspective of trace element distributions within the system. Distributions of As, Hg and Li provide the clearest expression of hydrothermal activity. Comparison of these distribution

173

A Mineralogical Petrographic And Geochemical Study Of Samples From Wells In  

Open Energy Info (EERE)

Mineralogical Petrographic And Geochemical Study Of Samples From Wells In Mineralogical Petrographic And Geochemical Study Of Samples From Wells In The Geothermal Field Of Milos Island (Greece) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Mineralogical Petrographic And Geochemical Study Of Samples From Wells In The Geothermal Field Of Milos Island (Greece) Details Activities (0) Areas (0) Regions (0) Abstract: This paper presents a study of hydrothermal alteration on Milos island, Greece. Examination of cores and cuttings from the two drill sites, obtained from a depth of about 1100 m in Milos geothermal field, showed that the hydrothermal minerals occurring in the rock include: K-feldspar, albite, chlorite, talc, diopside, epidote, muscovite, tremolite, kaolinite, montmorillonite, alunite, anhydrite, gypsum, calcite, and opaque minerals.

174

Geochemical studies of commercial low-level radioactive waste disposal sites  

SciTech Connect (OSTI)

The results of source term characterization studies for the commercially operated low-level waste (LLW) disposal sites located in the eastern United States are used to provide an understanding of the importance of hydrological and geochemical factors in controlling the mechanics of leachate formation, evolution of leachate compositions, microbial degradation of organic waste and development of anoxia in the trenches, and the nature and extent of leaching of waste materials. The varying degrees of the intensity of these processes, as determined by the different site characteristics, are clearly reflected in the contrasting leachate geochemistries of Maxey Flats and West Valley trenches, as compared to those of Barnwell and Sheffield trenches. These are important geochemical considerations which not only define LLW source terms but also shed light on the nature and extent of geochemical changes that are likely to occur along a redox gradient outside of the trench environment.

Dayal, R.; Pietrzak, R.F.; Clinton, J.H.

1986-06-01T23:59:59.000Z

175

Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts  

DOE Patents [OSTI]

A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Anderson, Raymond P. (Idaho Falls, ID)

2008-08-05T23:59:59.000Z

176

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting  

SciTech Connect (OSTI)

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

2011-03-15T23:59:59.000Z

177

Internal neutronics-temperature coupling in Serpent 2 - Reactivity differences resulting from choice of material property correlations  

SciTech Connect (OSTI)

This paper describes the unique way of simultaneously solving the power and temperature distributions of a nuclear system with the Monte Carlo neutron transport code Serpent 2. The coupled solution is achieved through the implementation of an internal temperature solver and material property correlations in the code. The program structure is reviewed concerning the temperature solver and the internal correlations as well as the internal coupling between these two and the neutron transport part. To estimate the reactivity differences resulting from correlation choices a simple pin-cell case has been calculated. It is established, that some correlation choices may result in difference in reactivity of approximately 100 pcm. (authors)

Valtavirta, V. [VTT Technical Research Centre of Finland, P.O. Box 1000, FI-02044 VTT (Finland)

2013-07-01T23:59:59.000Z

178

Transportation Market Distortions  

E-Print Network [OSTI]

of Highways, Volpe National Transportation Systems Center (Evaluating Criticism of Transportation Costing, VictoriaFrom Here: Evaluating Transportation Diversity, Victoria

Litman, Todd

2006-01-01T23:59:59.000Z

179

New technology of optimizing heavy oil reservoir management by geochemical means: A case study in block Leng 43, Liaohe Oilfield, China  

Science Journals Connector (OSTI)

Geochemical methods can be used to optimize heavy oil reservoir management. The distribution of some biomarkers in oils is different with the degree of biodegradation. Geochemical parameters can be used to pre...

Zhao Hongjing; Zhang Chunming; Mei Bowen; S. R. Larter

2002-10-01T23:59:59.000Z

180

Reactivity of calcium sulfate from FBC systems  

Science Journals Connector (OSTI)

A relative estimate of the reactivity of calcium sulfate in a number of coal combustion ash samples was obtained, using the rate of solution in water as a parameter. Measurements were also performed on standard samples of calcium sulfate prepared in different ways, for comparison. The temperature of previous treatment appeared as the most important factor determining the reactivity of CaSO4; the grain size distribution was less important, and the duration of heating (even to 105 days) had very little influence. No correlation between specific surface of ash samples and their reactivity was apparent. Calcium sulfate in FBC ash samples was much more reactive than that contained in high-temperature ashes, and than calcium sulfate heated, alone or with various additions, at 850C for 2 days. Of the six FBC samples tested, five showed similar behaviour, including a sample from a pressurized system; only a deposit from 96 days operation of an industrial CFBC boiler burning petroleum coke showed considerably less reactivity. Surprisingly, CaSO4 from two FBC samples placed in an oven for 60 days under sulfating conditions showed a very similar rate of solution to that of the other FBC samples, while a third sample kept in the oven for 105 days also showed no decrease in reactivity. Only when one of these samples had agglomerated (which occurred between 60 and 105 days) did it show decreased reactivity, suggesting that the agglomeration process rather than duration is significant in promoting sintering and reducing the sulfate reactivity.

Agripanea P. Iribarne; Julio V. Iribarne; Edward J. Anthony

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

182

The global geochemical cycles of iron and calcium: using novel isotope systems to understand weathering, global mass budgets, natural reaction rates, and paleoclimate  

E-Print Network [OSTI]

. Traditional geochemical proxies utilize variations in the oxygen, carbon, and boron isotopic compositionThe global geochemical cycles of iron and calcium: using novel isotope systems to understand of California, Berkeley Spring 2005 #12;The global geochemical cycles of iron and calcium: using novel isotope

Fantle, Matthew

183

The impact of local geochemical variability on quantifying hillslope soil production and chemical weathering  

E-Print Network [OSTI]

the physical and chemical processes of soil production and erosion and revisit three granitic study areas on the hillslope-scale physical and chemical soil production and erosion processes. To explain why understandingThe impact of local geochemical variability on quantifying hillslope soil production and chemical

Heimsath, Arjun M.

184

Microscale geochemical gradients in Hanford 300 Area sediment biofilms and influence of uranium  

SciTech Connect (OSTI)

The presence and importance of microenvironments in the subsurface at contaminated sites were suggested by previous geochemical studies. However, no direct quantitative characterization of the geochemical microenvironments had been reported. We quantitatively characterized microscale geochemical gradients (dissolved oxygen (DO), H(2), pH, and redox potential) in Hanford 300A subsurface sediment biofilms. Our results revealed significant differences in geochemical parameters across the sediment biofilm/water interface in the presence and absence of U(VI) under oxic and anoxic conditions. While the pH was relatively constant within the sediment biofilm, the redox potential and the DO and H(2) concentrations were heterogeneous at the microscale (<500-1000 ?m). We found microenvironments with high DO levels (DO hotspots) when the sediment biofilm was exposed to U(VI). On the other hand, we found hotspots (high concentrations) of H(2) under anoxic conditions both in the presence and in the absence of U(VI). The presence of anoxic microenvironments inside the sediment biofilms suggests that U(VI) reduction proceeds under bulk oxic conditions. To test this, we operated our biofilm reactor under air-saturated conditions in the presence of U(VI) and characterized U speciation in the sediment biofilm. U L(III)-edge X-ray absorption spectroscopy (XANES and EXAFS) showed that 80-85% of the U was in the U(IV) valence state.

Nguyen, Hung D.; Cao, Bin; Mishra, Bhoopesh; Boyanov, Maxim I.; Kemner, Kenneth M.; Fredrickson, Jim K.; Beyenal, Haluk

2012-01-01T23:59:59.000Z

185

22th International Meeting on org. geochem. The fate of organic matter in mangrove sediments  

E-Print Network [OSTI]

22th International Meeting on org. geochem. The fate of organic matter in mangrove sediments and the unvegetated sediments, and various vascular plants specific to these swamps. An elemental, pyrolytic sediments characterised by great changes in the redox conditions. Several specific results have already been

Boyer, Edmond

186

Laghi di Monticchio (Southern Italy, Region Basilicata): genesis of sediments--a geochemical study  

E-Print Network [OSTI]

Laghi di Monticchio (Southern Italy, Region Basilicata): genesis of sediments--a geochemical study and Sediments, Telegrafenberg C328, 14473 Potsdam, Germany (2) Institut des Sciences de la Terre d'Orléans (ISTO Cedex 2, France Abstract The sedimentation record of Lago Grande di Monticchio (LGM) is one of the most

Boyer, Edmond

187

Discrimination of geochemical compositions between the Changjiang and the Huanghe sediments and  

E-Print Network [OSTI]

Discrimination of geochemical compositions between the Changjiang and the Huanghe sediments and its application for the identi¢cation of sediment source in the Jiangsu coastal plain, China S.Y. Yang a;b;? , C 2002 Abstract Concentrations of 25 elements in the fine-grained fraction ( 6 63 Wm) of bottom sediments

Yang, Shouye

188

Continental Shelf Research 26 (2006) 1524 Geochemical compositions of river and shelf sediments in the  

E-Print Network [OSTI]

Continental Shelf Research 26 (2006) 15­24 Geochemical compositions of river and shelf sediments in the Yellow Sea: Grain-size normalization and sediment provenance D.I. Lima,?, H.S. Jungb , J.Y. Choic , S 14 November 2005 Abstract The geochemistry of sediment samples from Korean and Chinese rivers

Yang, Shouye

189

Large volume recycling of oceanic lithosphere over short time scales: geochemical constraints from the Caribbean Large  

E-Print Network [OSTI]

Large volume recycling of oceanic lithosphere over short time scales: geochemical constraints from with derivation from recycled oceanic crust, while the depleted lavas are derived from a highly residual source source mantle could have been 9 500 Ma before CLIP formation and interpreted to reflect the recycling

Graham, David W.

190

A GEOCHEMICAL MODULE FOR "AMDTreat" TO COMPUTE CAUSTIC QUANTITY, EFFLUENT QUALITY, AND SLUDGE VOLUME1  

E-Print Network [OSTI]

1413 A GEOCHEMICAL MODULE FOR "AMDTreat" TO COMPUTE CAUSTIC QUANTITY, EFFLUENT QUALITY, AND SLUDGE with the quantities of chemical added and sludge produced. The pH and metals concentrations do not change linearlyH and the corresponding effluent composition and sludge volume can not be accurately determined without empirical

191

Inferring dispersal and migrations from incomplete geochemical baselines: analysis of population structure  

E-Print Network [OSTI]

. 2008). Trace element tags as well as stable iso- topes contained within inert structures, such as fish baseline or reference atlas. Individuals of unknown origin are then assigned to one of the sources in this reference atlas based on their geochemical signature. The identifiability of potential sources is

Shima, Jeff

192

CAN THE GEOCHEMICAL TOPSOIL ATLAS BE USED TO PREDICT TRACE METAL DEFICIENCY IN CATTLE?  

E-Print Network [OSTI]

CAN THE GEOCHEMICAL TOPSOIL ATLAS BE USED TO PREDICT TRACE METAL DEFICIENCY IN CATTLE? By: Emily courtesy LTSN Bioscience. http://bio.ltsn.ac.uk/imagebank/ Just as trace metals are important to humans to the structural stability of molecules and membranes. For these reasons, incorrect trace metal levels can

Nottingham, University of

193

Organic geochemical evidence for pine tar production in middle Eastern Sweden during the Roman Iron Age  

E-Print Network [OSTI]

Organic geochemical evidence for pine tar production in middle Eastern Sweden during the Roman Iron Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden b Upplands muse´et, St: Eriks gra¨nd 6, SE-753 10 Uppsala, Sweden Received 21 September 2004; received in revised form 15 June 2005; accepted 21

194

Geochemical Constraints on the Origin of a Shallow Ash Occurrence: in the Mahanadi Basin, offshore India  

E-Print Network [OSTI]

Geochemical Constraints on the Origin of a Shallow Ash Occurrence: in the Mahanadi Basin, offshore sampled in the continental margins offshore India (Fig 1). A volcanic ash layer was recovered below seafloor Surrounding Sediments: Grey sediment in A is a nannofossil and plant debris bearing clay

New Hampshire, University of

195

Geochemical anomalies in soil and sandstone overlying the Phoenix uranium deposit, Athabasca Basin Natural Resources  

E-Print Network [OSTI]

Co Mo Ni UU Geochemical anomalies in soil and sandstone overlying the Phoenix uranium deposit, Athabasca Basin Natural Resources Canada Geological Survey of Canada with Provincial and Territorial Collaboration Introduction The Wheeler River Property, host of Denison Mine's Phoenix uranium deposit

196

In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and Reactive Landing of Mass Selected Ions. In Situ Reactivity and TOF SIMS Analysis of Surfaces Prepared by Soft and...

197

EMSL - Subsurface Flow and Transport  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbonate (CaCO3) geochemical reactions exert a fundamental control on the evolution of porosity and permeability in shallow-to-deep subsurface siliciclastic and limestone rock...

198

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Broader source: Energy.gov (indexed) [DOE]

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical

199

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Broader source: Energy.gov (indexed) [DOE]

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

200

Characterization of Dual-Fuel Reactivity Controlled Compression...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI)...

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

COAL SLAGGING AND REACTIVITY TESTING  

SciTech Connect (OSTI)

Union Fenosa's La Robla I Power Station is a 270-MW Foster Wheeler arch-fired system. The unit is located at the mine that provides a portion of the semianthracitic coal. The remaining coals used are from South Africa, Russia, Australia, and China. The challenges at the La Robla I Station stem from the various fuels used, the characteristics of which differ from the design coal. The University of North Dakota Energy & Environmental Research Center (EERC) and the Lehigh University Energy Research Center (LUERC) undertook a program to assess problematic slagging and unburned carbon issues occurring at the plant. Full-scale combustion tests were performed under baseline conditions, with elevated oxygen level and with redistribution of air during a site visit at the plant. During these tests, operating information, observations and temperature measurements, and coal, slag deposit, and fly ash samples were obtained to assess slagging and unburned carbon. The slagging in almost all cases appeared due to elevated temperatures rather than fuel chemistry. The most severe slagging occurred when the temperature at the sampling port was in excess of 1500 C, with problematic slagging where first-observed temperatures exceeded 1350 C. The presence of anorthite crystals in the bulk of the deposits analyzed indicates that the temperatures were in excess of 1350 C, consistent with temperature measurements during the sampling period. Elevated temperatures and ''hot spots'' are probably the result of poor mill performance, and a poor distribution of the coal from the mills to the specific burners causes elevated temperatures in the regions where the slag samples were extracted. A contributing cause appeared to be poor combustion air mixing and heating, resulting in oxygen stratification and increased temperatures in certain areas. Air preheater plugging was observed and reduces the temperature of the air in the windbox, which leads to poor combustion conditions, resulting in unburned carbon as well as slagging. A second phase of the project involved advanced analysis of the baseline coal along with an Australian coal fired at the plant. These analysis results were used in equilibrium thermodynamic modeling along with a coal quality model developed by the EERC to assess slagging, fouling, and opacity for the coals. Bench-scale carbon conversion testing was performed in a drop-tube furnace to assess the reactivity of the coals. The Australian coal had a higher mineral content with significantly more clay minerals present than the baseline coal. The presence of these clay minerals, which tend to melt at relatively low temperatures, indicated a higher potential for problematic slagging than the baseline coal. However, the pyritic minerals, comprising over 25% of the baseline mineral content, may form sticky iron sulfides, leading to severe slagging in the burner region if local areas with reducing conditions exist. Modeling results indicated that neither would present significant fouling problems. The Australian coal was expected to show slagging behavior much more severe than the baseline coal except at very high furnace temperatures. However, the baseline coal was predicted to exhibit opacity problems, as well as have a higher potential for problematic calcium sulfate-based low-temperature fouling. The baseline coal had a somewhat higher reactivity than the Australian coal, which was consistent with both the lower average activation energy for the baseline coal and the greater carbon conversion at a given temperature and residence time. The activation energy of the baseline coal showed some effect of oxygen on the activation energy, with E{sub a} increasing at the lower oxygen concentration, but may be due to the scatter in the baseline coal kinetic values at the higher oxygen level tested.

Donald P. McCollor; Kurt E. Eylands; Jason D. Laumb

2003-10-01T23:59:59.000Z

202

GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS  

SciTech Connect (OSTI)

Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require ultimate disposal when it is put to use. Each task three waste was evaluated for utilization potential based on its physical properties, bulk chemical composition, and mineral composition. Only one of the thirteen materials studied might be suitable for use as a pozzolanic concrete additive. However, many wastes appeared to be suitable for other high-volume uses such as blasting grit, fine aggregate for asphalt concrete, road deicer, structural fill material, soil stabilization additives, waste stabilization additives, landfill cover material, and pavement base course construction.

Edwin S. Olson; Charles J. Moretti

1999-11-01T23:59:59.000Z

203

Consideration of spatial effects in reactivity measurements  

SciTech Connect (OSTI)

Various methods of considering spatial effects in reactivity measurements are presented. These methods are employed both at the critical (mainly fast-neutron) facilities and at the BN-600 reactor.

Matveenko, I. P., E-mail: matveenko@ippe.ru; Lititskii, V. A.; Shokod'ko, A. G. [Institute of Physics and Power Engineering (Russian Federation)

2010-12-15T23:59:59.000Z

204

Systematic approach for chemical reactivity evaluation  

E-Print Network [OSTI]

Screening Tool (RSST) and the Automatic Pressure Tracking Adiabatic Calorimeter (APTAC) were employed to evaluate the reactive systems experimentally. The RSST detected exothermic behavior and measured the overall liberated energy. The APTAC simulated...

Aldeeb, Abdulrehman Ahmed

2004-09-30T23:59:59.000Z

205

Reactivity control assembly for nuclear reactor  

DOE Patents [OSTI]

Reactivity control assembly for nuclear reactor comprises supports stacked above reactor core for holding control rods. Couplers associated with the supports and a vertically movable drive shaft have lugs at their lower ends for engagement with the supports.

Bollinger, Lawrence R. (Schenectady, NY)

1984-01-01T23:59:59.000Z

206

Fossil plant layup and reactivation conference: Proceedings  

SciTech Connect (OSTI)

The Fossil Plant Layup and Reactivation Conference was held in New Orleans, Louisiana on April 14--15, 1992. The Conference was sponsored by EPRI and hosted by Entergy Services, Inc. to bring together representatives from utilities, consulting firms, manufacturers and architectural engineers. Eighteen papers were presented in three sessions. These sessions were devoted to layup procedures and practices, and reactivation case studies. A panel discussion was held on the second day to interactively discuss layup and reactivation issues. More than 80 people attended the Conference. This report contains technical papers and a summary of the panel discussion. Of the eighteen papers, three are related to general, one is related to regulatory issues, three are related to specific equipment, four are related to layup procedures and practices, and seven are layup and reactivation case studies.

Not Available

1992-10-01T23:59:59.000Z

207

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

1998-01-01T23:59:59.000Z

208

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

1998-09-08T23:59:59.000Z

209

A Tariff for Reactive Power - IEEE  

SciTech Connect (OSTI)

This paper describes a suggested tariff or payment for the local supply of reactive power from distributed energy resources. The authors consider four sample customers, and estimate the cost of supply of reactive power for each customer. The power system savings from the local supply of reactive power are also estimated for a hypothetical circuit. It is found that reactive power for local voltage regulation could be supplied to the distribution system economically by customers when new inverters are installed. The inverter would be supplied with a power factor of 0.8, and would be capable of local voltage regulation to a schedule supplied by the utility. Inverters are now installed with photovoltaic systems, fuel cells and microturbines, and adjustable-speed motor drives.

Kueck, John D [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator; Kirby, Brendan J [ORNL

2008-11-01T23:59:59.000Z

210

Reactive Attachment Disorder: Concepts, Treatment, and Research  

E-Print Network [OSTI]

Reactive Attachment Disorder (RAD) is a disorder characterized by controversy, both with respect to its definition and its treatment. By definition, the RAD diagnosis attempts to characterize and explain the origin of ...

Walter, Uta M.; Petr, Chris

2004-06-01T23:59:59.000Z

211

MSIV leakage airborne iodine transport  

SciTech Connect (OSTI)

Gaseous iodine deposits on surfaces exposed to vapors. Basic chemical and physical principles predict this behavior, and several laboratory and in-plant measurements demonstrate the characteristic. An empirical model was developed that describes the deposition, resuspension, and transformation of airborne radioiodine molecular species as a stream containing these forms moves along its pathway. The model uses a data base of measured values of deposition and resuspension rates in its application and describes the conversion of the more reactive inorganic iodine species I[sub 2] to the less reactive organic species CH[sub 3]I as the iodine deposits and resuspends along the path. It also considers radioactive decay and chemical surface bonding during residence on surfaces. For the 8-day [sup 131]I, decay during the airborne portion of the transport is negligible. Verification of the model included measurement tests of long gaseous-activity sampling lines of different diameters, operated at different flow rates and stream temperatures. The model was applied to the streams at a boiling water reactor nuclear power plant to describe the transport through leaking main steam isolation valves (MSIVs), following a loss-of-coolant accident.

Cline, J.E. (Cline Associates Inc., Rockville, MD (United States))

1993-01-01T23:59:59.000Z

212

Neurotransmitter Transporters  

E-Print Network [OSTI]

at specialized synaptic junctions where electrical excitability in the form of an action potential is translated membrane of neurons and glial cells. Transporters harness electrochemical gradients to force the movement.els.net #12;The response produced when a transmitter interacts with its receptors, the synaptic potential

Bergles, Dwight

213

PROCEEDINGS, Thirty-Sixth Workshop on Geothermal Reservoir Engineering Stanford University, Stanford, California, January 31 -February 2, 2011  

E-Print Network [OSTI]

from low permeability and/or porosity geothermal resources. Existing geochemical reactive transport reservoir characterization and present example analyses of the pore systems of representative rocks fromPROCEEDINGS, Thirty-Sixth Workshop on Geothermal Reservoir Engineering Stanford University

Stanford University

214

Origin of geochemical heterogeneity in the mantle : constraints from volcanism associated with Hawaiian and Kerguelen mantle plumes  

E-Print Network [OSTI]

Lavas derived from long-lived mantle plumes provide important information of mantle compositions and the processes that created the geochemical heterogeneity within the mantle. Kerguelen and Hawaii are two long-lived mantle ...

Xu, Guangping

2007-01-01T23:59:59.000Z

215

Geochemical and isotopic variations in shallow groundwater in areas of the Fayetteville Shale development, north-central Arkansas q  

E-Print Network [OSTI]

similar to the brine in the Fayetteville Shale. Nonetheless, no spatial relationship was found between CH4. The integration of multiple geochemical and isoto- pic proxies shows no direct evidence of contamination

Jackson, Robert B.

216

Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

Wilson, Cathy; Newman, Brent; Heikoop, Jeff

217

Geochemical Aspects of the Carbonation of Magnesium Silicates in an Aqueous Medium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

GEOCHEMICAL ASPECTS OF THE CARBONATION OF MAGNESIUM GEOCHEMICAL ASPECTS OF THE CARBONATION OF MAGNESIUM SILICATES IN AN AQUEOUS MEDIUM George D. Guthrie, Jr. (gguthrie@lanl.gov 505-665-6340) J. William Carey (bcarey@lanl.gov 505-667-5540) Deborah Bergfeld (debberrg@lanl.gov 505-667-1812) Darrin Byler (dbyler@lanl.gov 505-665-9562) Steve Chipera (chipera@lanl.gov 505-667-1110) Hans-Joachim Ziock (ziock@lanl.gov 505-667-7265) Hydrology, Geochemistry, & Geology Los Alamos National Laboratory Los Alamos, NM 87545 Klaus Lackner (ksl@lanl.gov 505-667-5694) Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM and Columbia University, New York, NY KEYWORDS: CO 2 sequestration, magnesium silicate, mineral carbonation INTRODUCTION The volume of carbon dioxide associated with the use of fossil fuels to produce

218

Isotope and Ion Selectivity in Reverse Osmosis Desalination: Geochemical Tracers for Man-made Freshwater  

Science Journals Connector (OSTI)

A systematic measurement of ions and 2H/1H, 7Li/6Li, 11B/10B, 18O/16O, and 87Sr/86Sr isotopes in feed-waters, permeates, and brines from commercial reverse osmosis (RO) desalination plants in Israel (Ashkelon, Eilat, and Nitzana) and Cyprus (Larnaca) reveals distinctive geochemical and isotopic fingerprints of fresh water generated from desalination of seawater (SWRO) and brackish water (BWRO). ... The specific geochemical and isotopic fingerprints of SWRO provide a unique tool for tracing man-made fresh water as an emerging recharge component of natural water resources. ... O and H isotopes were determined by dual inlet and continuous flow mass spectrometry following gaswater equilibration (analytical uncertainties 0.8 for ?2H and 0.1 for ?18O). ...

Wolfram Kloppmann; Avner Vengosh; Catherine Guerrot; Romain Millot; Irena Pankratov

2008-05-21T23:59:59.000Z

219

NREL: Transportation Research - News  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

News NREL provides a number of transportation and hydrogen news sources. Transportation News Find news stories that highlight NREL's transportation research, development, and...

220

Phase II: Performance Evaluation of Permeable Reactive Barriers and  

Broader source: Energy.gov (indexed) [DOE]

Phase II: Performance Evaluation of Permeable Reactive Barriers and Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing U. S. Environmental Protection Agency Region 8 Support January 2004 Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Rejuvenating Permeable Reactive Barriers by Chemical Flushing

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Broader source: Energy.gov (indexed) [DOE]

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

222

Final Report Phase II: Performance Evaluation of Permeable Reactive  

Broader source: Energy.gov (indexed) [DOE]

Final Report Phase II: Performance Evaluation of Permeable Reactive Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report - Rejuvenating Permeable Reactive Barriers by Chemical Flushing, U.S. Environmental Protection Agency Region 8 Support

223

Controlling reactivity of nanoporous catalyst materials by tuning reaction product-pore interior interactions: Statistical mechanical modeling  

SciTech Connect (OSTI)

Statistical mechanical modeling is performed of a catalytic conversion reaction within a functionalized nanoporous material to assess the effect of varying the reaction product-pore interior interaction from attractive to repulsive. A strong enhancement in reactivity is observed not just due to the shift in reaction equilibrium towards completion but also due to enhanced transport within the pore resulting from reduced loading. The latter effect is strongest for highly restricted transport (single-file diffusion), and applies even for irreversible reactions. The analysis is performed utilizing a generalized hydrodynamic formulation of the reaction-diffusion equations which can reliably capture the complex interplay between reaction and restricted transport.

Wang, Jing [Ames Laboratory; Ackerman, David M. [Ames Laboratory; Lin, Victor S.-Y. [Ames Laboratory; Pruski, Marek [Ames Laboratory; Evans, James W. [Ames Laboratory

2013-04-02T23:59:59.000Z

224

Geologic and geochemical studies of the New Albany Shale Group (Devonian-Mississippian) in Illinois. Final report  

SciTech Connect (OSTI)

The Illinois State Geological Survey is conducting geological and geochemical investigations to evaluate the potential of New Albany Group shales as a source of hydrocarbons, particularly natural gas. Geological studies include stratigraphy and structure, mineralogic and petrographic characterization; analyses of physical properties; and development of a computer-based resources evaluation system. Geochemical studies include organic carbon content and trace elements; hydrocarbon content and composition; and adsorption/desorption studies of gas through shales. Separate abstracts have been prepared for each task reported.

Bergstrom, R.E.; Shimp, N.F.

1980-06-30T23:59:59.000Z

225

Hydrological and geochemical monitoring for a CO2 sequestration pilot in a brine formation  

SciTech Connect (OSTI)

Hydrological and geochemical monitoring are key components of site characterization and CO2 plume monitoring for a pilot test to inject CO2 into a brine-bearing sand of the fluvial-deltaic Frio formation in the upper Texas Gulf Coast. In situ, injected CO2 forms a supercritical phase that has gas-like properties (low density and viscosity) compared to the surrounding brine, while some CO2 dissolves in the brine. The pilot test employs one injection well and one monitor well, with continuous pressure and flow-rate monitoring in both wells, and continuous surface fluid sampling and periodic down-hole fluid sampling from the monitor well. Pre-injection site-characterization includes pump tests with pressure-transient analysis to estimate single-phase flow properties, establish hydraulic connectivity between the wells, determine appropriate boundary conditions, and analyze ambient phase conditions within the formation. Additionally, a pre-injection tracer test furnishes estimates of kinematic porosity and the geometry of flow paths between injection and monitor wells under single-phase conditions. Pre-injection geochemical sampling provides a baseline for subsequent geochemical monitoring and helps determine the optimal tracers to accompany CO2 injection. During CO2 injection, hydrological monitoring enables estimation of two-phase flow properties and helps track the movement of the injected CO2 plume, while geochemical sampling provides direct evidence of the arrival of CO2 and tracers at the monitor well. Furthermore, CO2-charged water acts as a weak acid, and reacts to some extent with the minerals in the aquifer, producing a distinct chemical signature in the water collected at the monitor well. Comparison of breakthrough curves for the single-phase tracer test and the CO2 (and its accompanying tracers) illuminates two-phase flow processes between the supercritical CO2 and native brine, an area of current uncertainty that must be better understood to effectively sequester CO2 in saline aquifers.

Doughty, Christine; Pruess, Karsten; Benson, Sally M.; Freifeld, Barry M.; Gunter, William D.

2004-05-17T23:59:59.000Z

226

Transportation Security  

Broader source: Energy.gov (indexed) [DOE]

For Review Only 1 Transportation Security Draft Annotated Bibliography Review July 2007 Preliminary Draft - For Review Only 2 Work Plan Task * TEC STG Work Plan, dated 8/2/06, Product #16, stated: "Develop an annotated bibliography of publicly-available documents related to security of radioactive material transportation." * Earlier this year, a preliminary draft annotated bibliography on this topic was developed by T-REX , UNM, to initially address this STG Work Plan Task. Preliminary Draft - For Review Only 3 Considerations in Determining Release of Information * Some "Publicly-available" documents could potentially contain inappropriate information according to standards set by DOE information security policy and DOE Guides. - Such documents would not be freely

227

Transportation Issues  

Broader source: Energy.gov (indexed) [DOE]

Issues Issues and Resolutions - Compilation of Laboratory Transportation Work Package Reports Prepared for U.S. Department of Energy Used Fuel Disposition Campaign Compiled by Paul McConnell Sandia National Laboratories September 30, 2012 FCRD-UFD-2012-000342 Transportation Issues and Resolutions ii September 2012 Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any

228

Policy Research TRANSPORTATION  

E-Print Network [OSTI]

Policy Research TRANSPORTATION CENTER Thestate's transportation system is central to its ability movement of goods to maintain and enhance global economic competitiveness. An effective transportation, TTI has identified the following set of initial transportation issues which must be better understood

229

Design and synthesis of reactive separation systems  

SciTech Connect (OSTI)

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-01-01T23:59:59.000Z

230

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-11-25T23:59:59.000Z

231

Water reactive hydrogen fuel cell power system  

DOE Patents [OSTI]

A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

2014-01-21T23:59:59.000Z

232

Semi-Analytical Solutions of One-Dimensional Multispecies Reactive Transport in a Permeable Reactive Barrier-Aquifer System  

E-Print Network [OSTI]

equations presented by Eykholt [1997], Rabideau et al. [2005], and Park and Zhan [2009] utilize the advection-dispersion equation (ADE) with first-order reaction g4666g2019g4667 as the governing equation(s) but differ primarily in their application... of the boundary conditions. For example, the two equations of Eykholt [1997] were derived using van Genuchten?s [1981] analytical solutions of the ADE with a first-type boundary condition g1829 g46660, g1872g4667 = g1829g3036g3041 at the influent face...

Mieles, John Michael

2012-07-16T23:59:59.000Z

233

Intelligent Transportation Systems - Center for Transportation Analysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intelligent Transportation Systems Intelligent Transportation Systems The Center for Transportation Analysis does specialty research and development in intelligent transportation systems. Intelligent Transportation Systems (ITS) are part of the national strategy for improving the operational safety, efficiency, and security of our nation's highways. Since the early 1990s, ITS has been the umbrella under which significant efforts have been conducted in research, development, testing, deployment and integration of advanced technologies to improve the measures of effectiveness of our national highway network. These measures include level of congestion, the number of accidents and fatalities, delay, throughput, access to transportation, and fuel efficiency. A transportation future that includes ITS will involve a significant improvement in these

234

Formation and Reactivity of Biogenic Iron Microminerals  

SciTech Connect (OSTI)

The overall purpose of the project is to explore and quantify the processes that control the formation and reactivity of biogenic iron microminerals and their impact on the solubility of metal contaminants. The research addresses how surface components of bacterial cells, extracellular organic material, and the aqueous geochemistry of the DIRB microenvironment impacts the mineralogy, chemical state and micromorphology of reduced iron phases.

Beveridge, Terrance J.; Glasauer, Susan; Korenevsky, Anton; Ferris, F. Grant

2000-08-08T23:59:59.000Z

235

Controlling uranium reactivity March 18, 2008  

E-Print Network [OSTI]

for the last decade. Most of their work involves depleted uranium, a more common form of uraniumMarch 2008 Controlling uranium reactivity March 18, 2008 Uranium is an often misunderstood metal uranium research. In reality, uranium presents a wealth of possibilities for funda- mental chemistry. Many

Meyer, Karsten

236

Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt & Subtle Volcanic Systems, Hawaii & Maui  

Broader source: Energy.gov [DOE]

DOE Geothermal Technologies Peer Review 2010 - Presentation. Project Objective: To use a combination of traditional geophysical and geochemical tools with exploration suites not typically used in geothermal exploration.

237

Geochemical investigations at Maxey Flats radioactive waste disposal site. [Shallow land burial  

SciTech Connect (OSTI)

As part of the NRC efforts to develop a data base on source term characteristics for low level wastes, Brookhaven National Laboratory (BNL) has produced and analyzed a large amount of data on trench leachate chemistry at existing shallow land burial sites. In this report, we present the results of our investigations at the Maxey Flats, Kentucky disposal site. In particular, data on trench leachate chemistry are reviewed and discussed in terms of mechanisms and processes controlling the composition of trench solutes. Particular emphasis is placed on identifying both intra- and extra-trench factors and processes contributing to source term characteristics, modifications, and uncertainties. BNL research on the Maxey Flats disposal site has provided important information not only on the source term characteristics and the factors contributing to uncertainties in the source term but also some generic insights into such geochemical processes and controls as the mechanics of leachate formation, microbial degradation and development of anoxia, organic complexation and radionuclide mobility, redox inversion and modification of the source term, solubility constraints on solute chemistry, mineral authigenesis, corrosion products and radionuclide scavenging, and the role of organic complexants in geochemical partitioning of radionuclides. A knowledge of such processes and controls affecting the geochemical cycling of radionuclides as well as an understanding of the important factors that contribute to variability and uncertainties in the source term is essential for evaluating the performance of waste package and the site, making valid predictions of release for dose calculations, and for planning site performance monitoring as well as remedial actions. 43 references, 47 figures, 30 tables.

Dayal, R.; Pietrzak, R.F.; Clinton, J.

1984-09-01T23:59:59.000Z

238

Geochemical evaluation of CO2 injection and containment in a depleted gas field  

Science Journals Connector (OSTI)

Abstract The short- and long-term geochemical impact of CO2 injection into a depleted gas reservoir (DGR) is investigated using reservoir/geochemical modeling with TOUGH2/TOUGHREACT and 1D kinetic diffusion modeling with PHREEQC (caprock/well-cement). Simulations of CO2 injection into the reservoir predict displacement and buoyancy of post-production CH4, as well as dry-out of the near-well zone. We computed that the areal extent of the CH4/brine dominated zone and the dry-out zone are relatively small compared to the CO2/brine dominated zone after well-closure. For the current DGR model we therefore conclude that it is reasonable to model geochemical reactions in the reservoir without taking into account post-production CH4. Although the CO2 dissolution capacity of the studied DGR is smaller compared to a deep saline aquifer of similar size, the modeling predicts that dissolution and subsequent CO2 mineral trapping proceed faster. Precipitation of dawsonite and magnesite were yet predicted at initial CO2 partial pressure (PCO2) of 9.3bar, while these minerals were not identified in reservoir samples. This could indicate that their tendency of precipitation is overestimated by the model and hence the database used. This has significant impact on long-term modeled bulk porosity and PCO2. Simulations of CO2 diffusion through the caprock show that mineral reactions significantly retard the total dissolved carbon (TDC) plume. After 10,000 years, 99% of the TDC is present within the first 6.4m above the reservoir contact. The progression of the TDC plume in the caprock is sensitive to the composition, kinetic rates, and surface area of primary and secondary minerals. Cement alteration modeling shows progressive carbonation of cement phases, resulting in three zones of distinct mineralogy and porosity. The three zones are predominantly characterized by: (i) unaltered cement, (ii) portlandite dissolution, and (iii) calcite precipitation. The simulated thickness of the affected zone is 3.8cm after 100 years. This distance is sensitive to kinetic rate constants of CSH phases, but less sensitive to kinetic rate constant of portlandite. In summary, our applied methodology provides quantitative predictions of the geochemical impact of CO2 on the DGR storage complex. The methodology can be used for screening of potential DGR storage locations and to define criteria for minimal caprock and cement sheet thickness, for assuring short- and long-term integrity of the storage location.

Tim J. Tambach; Marille Koenen; Laura J. Wasch; Frank van Bergen

2015-01-01T23:59:59.000Z

239

XCHEM-1D: A Heat Transfer/Chemical Kinetics Computer Program for multilayered reactive materials  

SciTech Connect (OSTI)

An eXplosive CHEMical kinetics code, XCHEM, has been developed to solve the reactive diffusion equations associated with thermal ignition of energetic materials. This method-of-lines code uses stiff numerical methods and adaptive meshing to resolve relevant combustion physics. Solution accuracy is maintained between multilayered materials consisting of blends of reactive components and/or inert materials. Phase change and variable properties are included in one-dimensional slab, cylindrical and spherical geometries. Temperature-dependent thermal properties have been incorporated and the modification of thermal conductivities to include decomposition effects are estimated using solid/gas volume fractions determined by species fractions. Gas transport properties, including high pressure corrections, have also been included. Time varying temperature, heat flux, convective and thermal radiation boundary conditions, and layer to layer contact resistances have also been implemented.

Gross, R.J.; Baer, M.R.; Hobbs, M.L.

1993-10-01T23:59:59.000Z

240

Cell Comp't Thermal Reactivity & Improvements | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Comp't Thermal Reactivity & Improvements Cell Comp't Thermal Reactivity & Improvements Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on...

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Isotope effects in methanol synthesis and the reactivity of copper...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

242

Design of processes with reactive distillation line diagrams  

SciTech Connect (OSTI)

On the basis of the transformation of concentration coordinates, the concept of reactive distillation lines is developed. It is applied to study the feasibility of a reactive distillation with an equilibrium reaction on all trays of a distillation column. The singular points in the distillation line diagrams are characterized in terms of nodes and saddles. Depending on the characterization of the reactive distillation line diagrams, it can be decided whether a column with two feed stages is required. On the basis of the reaction space concept, a procedure for identification of reactive distillation processes is developed, in which the reactive distillation column has to be divided into reactive and nonreactive sections. This can be necessary to overcome the limitations in separation which result from the chemical equilibrium. The concentration profile of this combined reactive/nonreactive distillation column is estimated using combined reactive/nonreactive distillation lines.

Bessling, B. [BASF Ludwigshafen (Germany). Engineering Research and Development] [BASF Ludwigshafen (Germany). Engineering Research and Development; Schembecker, G.; Simmrock, K.H. [Univ. of Dortmund (Germany). Dept. of Chemical Engineering] [Univ. of Dortmund (Germany). Dept. of Chemical Engineering

1997-08-01T23:59:59.000Z

243

Geochemical Society  

Science Journals Connector (OSTI)

...the Ha y-Lacroix Prize rewarded the PhD work of Aur lie Violette and Johan Villeneuve (see Elements, volume 7, number 4...its vibrational spectra Jakub Matusik, Eva Scholtzov , and Daniel Tunega Clay mineralogy of the Zhada sediments: Evidence for...

244

Geochemical handbook  

Science Journals Connector (OSTI)

... FOUR years have elapsed since the pub lication of Part 4 of the Handbook of Geochemistry, the longest gap in the pro duction schedule, which has extended almost ... 1500 pages. The original intention of the editorial board was that Volume 2 of the Handbook would ultimately contain approximately 2000 pages in four instalments, with publication completed several years ...

D.G. Murchison

1979-09-20T23:59:59.000Z

245

Transportation Security | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Security SHARE Global Threat Reduction Initiative Transportation Security Cooperation Secure Transport Operations (STOP) Box Security of radioactive material while...

246

Transportation Security | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Transportation Security Transportation Security Transportation Security More Documents & Publications Overview for Newcomers West Valley Demonstration Project Low-Level Waste...

247

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

248

Strategic Freight Transportation Contract Procurement  

E-Print Network [OSTI]

Based Procurement for Transportation Services, Journal ofCoia, A. , Evolving transportation exchanges, World trade,an Auction Based Transportation Marketplace, Transportation

Nandiraju, Srinivas

2006-01-01T23:59:59.000Z

249

Reactivity control assembly for nuclear reactor. [LMFBR  

DOE Patents [OSTI]

This invention, which resulted from a contact with the United States Department of Energy, relates to a control mechanism for a nuclear reactor and, more particularly, to an assembly for selectively shifting different numbers of reactivity modifying rods into and out of the core of a nuclear reactor. It has been proposed heretofore to control the reactivity of a breeder reactor by varying the depth of insertion of control rods (e.g., rods containing a fertile material such as ThO/sub 2/) in the core of the reactor, thereby varying the amount of neutron-thermalizing coolant and the amount of neutron-capturing material in the core. This invention relates to a mechanism which can advantageously be used in this type of reactor control system.

Bollinger, L.R.

1982-03-17T23:59:59.000Z

250

Mined land reclamation by biological reactivation  

SciTech Connect (OSTI)

A mine reclamation technique, developed in Europe, restores land to full productivity within two years without topsoil replacement. The method deliberately reestablishes within one year following mining, the required biological balance between microbes, enzymes, and trace elements in the rock spoil rather than waiting five or more years for natural processes to restore balance. The technique is called Biological Reactivation (BR). This paper discusses the feasibility of BR reclamation after surface mining operations in the US. Staff of the Ohio Mining and Mineral Resources Research Institute completed an OSM-sponsored research project on BR in which physical and chemical tests characterized 140 spoil samples obtained from 10 surface mining operations. Test results indicated that Biological Reactivation technology could be effectively applied, at least in the test areas sampled within Appalachia. Preliminary estimates make clear that the new technique reduces reclamation costs on prime farmland by approximately 95% compared to topsoil segregation and replacement methods.

Gozon, J.S.; Konya, C.J.; Lukovic, S.S.; Lundquist, R.G.; Olah, J.

1982-12-01T23:59:59.000Z

251

Geochemical and geologic factors effecting the formulation of gas hydrate: Task No. 5, Final report  

SciTech Connect (OSTI)

The main objective of our work has been to determine the primary geochemical and geological factors controlling gas hydrate information and occurrence and particularly in the factors responsible for the generation and accumulation of methane in oceanic gas hydrates. In order to understand the interrelation of geochemical/geological factors controlling gas hydrate occurrence, we have undertaken a multicomponent program which has included (1) comparison of available information at sites where gas hydrates have been observed through drilling by the Deep Sea Drilling Project (DSDP) on the Blake Outer Ridge and Middle America Trench; (2) regional synthesis of information related to gas hydrate occurrences of the Middle America Trench; (3) development of a model for the occurrence of a massive gas hydrate as DSDP Site 570; (4) a global synthesis of gas hydrate occurrences; and (5) development of a predictive model for gas hydrate occurrence in oceanic sediment. The first three components of this program were treated as part of a 1985 Department of Energy Peer Review. The present report considers the last two components and presents information on the worldwide occurrence of gas hydrates with particular emphasis on the Circum-Pacific and Arctic basins. A model is developed to account for the occurrence of oceanic gas hydrates in which the source of the methane is from microbial processes. 101 refs., 17 figs., 6 tabs.

Kvenvolden, K.A.; Claypool, G.E.

1988-01-01T23:59:59.000Z

252

"Educating transportation professionals."  

E-Print Network [OSTI]

"Educating transportation professionals." Michael Demetsky Henry L. Kinnier Professor mjd of Virginia Charlottesville, VA 434.924.7464 Transportation Engineering & Management Research Our group works closely with the Virginia Center for Transportation Innovation and Research (VCTIR), located

Acton, Scott

253

Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas  

DOE Patents [OSTI]

In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

Durai-Swamy, Kandaswamy (Culver City, CA)

1982-01-01T23:59:59.000Z

254

The implementation of a 3D characteristics solver for the generation of incremental cross sections for reactivity devices in a CANDU reactor  

SciTech Connect (OSTI)

We are presenting issues related to the generation of consistent incremental cross sections for the reactivity devices in a CANDU reactor. Such calculations involve the solution of the neutron transport equation over complex 3D geometries representing a single vertical reactivity device inserted mid-way between two horizontal fuel channels. The DRAGON lattice code has recently been upgraded and can handle the exact geometry of such configurations for trajectory-based transport solvers. Within this framework, the detailed representation of the reactivity devices implies an increase in the number of regions when the strongly absorbing regions and fuel clusters are described without cylinderization. In this paper, a solution based on the characteristics method is compared with the standard procedure, based on the collision probabilities method. The coherence of both solvers is highlighted and a comparison of their computational costs is presented. (authors)

Le Tellier, R.; Hebert, A.; Marleau, G. [Ecole Polytechnique de Montreal, C.P. 6079 suce. Centre-Ville, Montreal, Que. H3C 3A7 (Canada)

2006-07-01T23:59:59.000Z

255

Transportation Efficiency Resources  

Broader source: Energy.gov [DOE]

Transportation efficiency reduces travel demand as measured by vehicle miles traveled (VMT). While transportation efficiency policies are often implemented under local governments, national and...

256

Transportation and its Infrastructure  

E-Print Network [OSTI]

cost to mitigate transports GHG emissions. There are alsoenergy consumption and GHG mitigation, especially inParis, 2005. ECON, 2003: GHG Emissions from International

2007-01-01T23:59:59.000Z

257

Transportation and its Infrastructure  

E-Print Network [OSTI]

Transport and its infrastructure Chapter 5 Hybrid vehiclesincluding hybrid- Transport and its infrastructure Chapter 5infrastructure Gt CO 2 -eq 1 - Diesels (LDVs) 2 - Hybrids (

2007-01-01T23:59:59.000Z

258

Sustainability and Transport  

E-Print Network [OSTI]

2005. Integrating Sustainability into the Trans- portationTHOUGHT PIECE Sustainability and Transport by Richardof the concept of sustainability to transport planning. In

Gilbert, Richard

2006-01-01T23:59:59.000Z

259

Analysis of Mineral Trapping for CO2 Disposal in Deep Aquifers  

Office of Scientific and Technical Information (OSTI)

Reactive Geochemical Transport Simulation to Study Mineral Trapping Reactive Geochemical Transport Simulation to Study Mineral Trapping for CO 2 Disposal in Deep Saline Arenaceous Aquifers Tianfu Xu, John A. Apps, and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA Abstract. A reactive fluid flow and geochemical transport numerical model for evaluating long-term CO 2 disposal in deep aquifers has been developed. Using this model, we performed a number of sensitivity simulations under CO 2 injection conditions for a commonly encountered Gulf Coast sediment to analyze the impact of CO 2 immobilization through carbonate precipitation. Geochemical models are needed because alteration of the predominant host rock aluminosilicate minerals is very slow and is not

260

Graduate Certificate in Transportation  

E-Print Network [OSTI]

Graduate Certificate in Transportation Nohad A. Toulan School of Urban Studies and Planning of Engineering and Computer Science integrated transportation systems. The Graduate Certificate in Transportation their capabilities. Students in the program can choose among a wide range of relevant courses in transportation

Bertini, Robert L.

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

TRANSPORTATION Annual Report  

E-Print Network [OSTI]

2003 CENTER FOR TRANSPORTATION STUDIES Annual Report #12;Center for Transportation Studies University of Minnesota 200 Transportation and Safety Building 511 Washington Avenue S.E. Minneapolis, MN publication is a report of transportation research, education, and outreach activities for the period July

Minnesota, University of

262

Career Map: Transportation Worker  

Broader source: Energy.gov [DOE]

The Wind Program's Career Map provides job description information for Transportation Worker positions.

263

Transportation Organization and Functions  

Broader source: Energy.gov [DOE]

Office of Packaging and Transportation list of organizations and functions, with a list of acronyms.

264

Evaluating oil quality and monitoring production from heavy oil reservoirs using geochemical methods: Application to the Boscan Field, Venezuela  

SciTech Connect (OSTI)

Many oil fields worldwide contain heavy oil in one or more reservoir units. The low gravity of these oils is most frequently due to biodegradation and/or low maturity. The challenge is to find ways to economically recover this oil. Methods which reduce the operating costs of producing heavy oil add significant value to such projects. Geochemical techniques which use the composition of the reservoir fluids as natural tracers offer cost effective methods to assist with reservoir management. The low viscosity and gravity of heavy oil, combined with frequent high water cuts, low flow rates, and the presence of downhole artificial lift equipment, make many conventional production logging methods difficult to apply. Therefore, monitoring production, especially if the produced oil is commingled from multiple reservoirs, can be difficult. Geochemical methods can be used to identify oil/water contacts, tubing string leaks and to allocate production to individual zones from commingled production. An example of a giant heavy oil field where geochemical methods may be applicable is the Boscan Field in Venezuela. Low maturity oil, averaging 10{degrees} API gravity, is produced from the Eocene Upper and Lower Boscan (Miosa) Sands. Geochemical, stratigraphic and engineering data have helped to better define the controls on oil quality within the field, identified new reservoir compartments and defined unique characteristics of the Upper and Lower Boscan oils. This information can be used to identify existing wells in need of workovers due to mechanical problems and to monitor production from new infill wells.

Kaufman, R.L.; Noguera, V.H.; Bantz, D.M. [Chevron Overseas Petroleum, San Ramon, CA (United States); Rodriguez, R. [Maraven, S.A., Caracas (Venezuela)

1996-08-01T23:59:59.000Z

265

Geochemical Data on Waters, gases, scales, and rocks from the Dixie Valley Region, Nevada (1996-1999)  

SciTech Connect (OSTI)

This report tabulates an extensive geochemical database on waters, gases, scales, rocks, and hot-spring deposits from the Dixie Valley region, Nevada. The samples from which the data were obtained were collected and analyzed during 1996 to 1999. These data provide useful information for ongoing and future investigations on geothermal energy, volcanism, ore deposits, environmental issues, and groundwater quality in this region.

Goff, Fraser; Bergfeld, Deborah; Janik, C.J.; et al

2002-08-01T23:59:59.000Z

266

PUBLISHED ONLINE: 19 JUNE 2011 | DOI: 10.1038/NGEO1183 Influence of subsurface biosphere on geochemical  

E-Print Network [OSTI]

estimate the net flux of methane, carbon dioxide and hydrogen from diffuse and focused hydrothermal vents on geochemical fluxes from diffuse hydrothermal fluids Scott D. Wankel1 , Leonid N. Germanovich2 , Marvin D. Girguis1 * Hydrothermal vents along mid-ocean systems host unique, highly productive biological

Girguis, Peter R.

267

Oxygen is a key element for biology and the cycling of geochemical elements, and has shaped the chemical  

E-Print Network [OSTI]

Oxygen is a key element for biology and the cycling of geochemical elements, and has shaped the chemical and biological evolution of Earth. The oceans appear to be loosing oxygen due to on-going climate change, with resulting impacts on marine ecosystems and global biogeochemical cycles. As oxygen levels

Handy, Todd C.

268

Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freig pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedestr  

E-Print Network [OSTI]

Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freig pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedestrian > Ports and waterways >>> Transportation ope

269

Reactive sticking coefficients of silane on silicon  

SciTech Connect (OSTI)

Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition rate measurements using molecular beam scattering and a very low pressure cold wall reactor. The RSCs have non-Arrhenius temperature dependences and decreases with increasing flux at low (710/sup 0/) temperatures. A simple model involving dissociative adsorption of silane is consistent with these results. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1988-09-15T23:59:59.000Z

270

Cellular-automaton model for reactive systems  

Science Journals Connector (OSTI)

A method for constructing a variety of probabilistic lattice-gas cellular automata for chemically reacting systems is described. The microscopic reactive dynamics give rise to a general fourth-order polynomial rate law for the average particle density. The reduction of the microdynamical equations to a discrete or continuous Boltzmann equation is presented. Connection between the linearized Boltzmann equations and a reaction-diffusion macroscopic equation is discussed. As an example of the general formalism a set of cellular automata rules that yield the Schlgl phenomenological model is constructed. Simulation results are presented.

David Dab; Anna Lawniczak; Jean-Pierre Boon; Raymond Kapral

1990-05-14T23:59:59.000Z

271

Theoretical and Experimental Evaluation of Chemical Reactivity  

E-Print Network [OSTI]

released and the rate of energy released for a specific reactive chemical. 2.1 DSC DSC is a popular screening tool (safe and fast) and can provide an overall indication of exothermic activity of the chemical being tested. In a DSC, a sample and a... endothermic or exothermic reaction. When the rate of heat generation in the sample exceeds a particular value, the heat supply to the sample is cut off and this additional heat gain is attributed to exothermic activity within the sample.17 From the DSC...

Wang, Qingsheng

2011-10-21T23:59:59.000Z

272

Preparation of reactive beta-dicalcium silicate  

DOE Patents [OSTI]

This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane and hydrogen, at a temperature of about 850.degree.-1000.degree. C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

Shen, Ming-Shing (Laramie, WY, NJ); Chen, James M. (Rahway, NJ); Yang, Ralph T. (Amherst, NY)

1982-01-01T23:59:59.000Z

273

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 ``Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core`` problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-12-01T23:59:59.000Z

274

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core'' problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-01-01T23:59:59.000Z

275

Graduate Studies Transportation Systems Engineering  

E-Print Network [OSTI]

Graduate Studies Transportation Systems Engineering TRANSPORTATION SYSTEMS The transportation that transportation systems engineering can promote a thriving economy and a better quality of life by ensuring that transportation systems themselves affect the environment through operations, construction, and maintenance

Jacobs, Laurence J.

276

Introduction Transport in disordered graphene  

E-Print Network [OSTI]

Introduction Transport in disordered graphene Summary Ballistic transport in disordered graphene P, Gornyi, Mirlin Ballistic transport in disordered graphene #12;Introduction Transport in disordered graphene Summary Outline 1 Introduction Model Experimental motivation Transport in clean graphene 2

Fominov, Yakov

277

Petroleum geochemistry of Lower Indus Basin, Pakistan: I. Geochemical interpretation and origin of crude oils  

Science Journals Connector (OSTI)

Abstract The study focused on the petroleum geochemistry of crude oils produced from Cretaceous reservoirs. Geochemical portrayal of crude oils has been carried out by means of diagnostic biomarker parameters like relative distribution of steranes (C27C28C29 ???-20R steranes), C19 and C23 tricyclic terpanes (TT), C24 tetracyclic terpanes (TeT) and hopanes. These parameters suggest that the crude oils contain terrigenous organic matter (OM) mixed with small input of marine OM. The OM of the source rocks was deposited in oxic depositional environment. Maturity parameters, C32 22S/(22S+22R) homohopanes and sterane isomerization ratios [20S/(20S+20R), ???/(???+???) for C29 steranes] indicate that these crude oil are produced from the source rocks at early mature stage to mature stage.

Arif Nazir; Tahira Fazeelat

2014-01-01T23:59:59.000Z

278

Workshop on hydrologic and geochemical monitoring in the Long Valley Caldera: proceedings  

SciTech Connect (OSTI)

A workshop reviewed the results of hydrologic and geochemical monitoring in the Long Valley caldera. Such monitoring is being done to detect changes in the hydrothermal system induced by ongoing magmatic and tectonic processes. Workshop participants discussed the need to instrument sites for continuous measurements of several parameters and to obtain additional hydrologic and chemical information from intermediate and deep drill holes. In addition to seismic and deformation monitoring, programs are currently in progress to monitor changes in the discharge characteristics of hot springs, fumaroles, and soil gases, as well as pressures and temperatures in wells. Some hydrochemical parameters are measured continuously, others are measured monthly or at longer intervals. This report summarizes the information presented at the hydrologic monitoring workshop, following the workshop agenda which was divided into four sessions: (1) overview of the hydrothermal system; (2) monitoring springs, fumaroles, and wells; (3) monitoring gas emissions; and (4) conclusions and recommendations.

Sorey, M.L.; Farrar, C.D.; Wollenberg, H.A.

1984-10-01T23:59:59.000Z

279

Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report  

SciTech Connect (OSTI)

Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

Alicia M. Wilson

2009-11-30T23:59:59.000Z

280

Atmospheric reactivity of gaseous dimethyl sulfate  

SciTech Connect (OSTI)

The atmospheric reactivity of dimethyl sulfate (DMS) with a series of atmospheric species has been investigated. Upper limits to the rate constants for the homogeneous gas-phase reactions of DMS with O{sub 3}, NH{sub 3}, and H{sub 2}O have been determined by using FTIR spectroscopy and are <1.4 {times} 10{sup {minus}21}, <1.5 {times} 10{sup {minus}21}, and <1.1 {times} 10{sup {minus}23} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. The reactivity of DMS toward ON radicals and Cl atoms has been determined by using relative rate techniques, and the rate constants for those reactions are <5 {times} 10{sup {minus}13} and (4.2 {plus minus} 0.5) {times} 10{sup {minus}13} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. These rate constants correspond to atmospheric lifetimes ranging from >23 days with respect to reaction with OH radicals to >33 years with respect to reaction with ozone. With the possible exception of its reaction with water, for which the calculated lifetime of DMS is >2 days, these results indicate that the atmospheric fate of DMS is not determined by its homogeneous gas-phase reactions with any of the atmosphere species studied.

Japar, S.M.; Wallington, T.J.; Andino, J.M.; Ball, J.C. (Ford Motor Co., Dearborn, MI (USA))

1990-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

NREL: Transportation Research - Sustainable Transportation Basics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Department of Energy's Alternative Fuels Data Center (AFDC) provide an introduction to sustainable transportation. NREL research supports development of electric, hybrid,...

282

Transportation Baseline Schedule  

SciTech Connect (OSTI)

The 1999 National Transportation Program - Transportation Baseline Report presents data that form a baseline to enable analysis and planning for future Department of Energy (DOE) Environmental Management (EM) waste/material transportation. The companion 1999 Transportation Barriers Analysis analyzes the data and identifies existing and potential problems that may prevent or delay transportation activities based on the data presented. The 1999 Transportation Baseline Schedule (this report) uses the same data to provide an overview of the transportation activities of DOE EM waste/materials. This report can be used to identify areas where stakeholder interface is needed, and to communicate to stakeholders the quantity/schedule of shipments going through their area. Potential bottlenecks in the transportation system can be identified; the number of packages needed, and the capacity needed at receiving facilities can be planned. This report offers a visualization of baseline DOE EM transportation activities for the 11 major sites and the Geologic Repository Disposal site (GRD).

Fawcett, Ricky Lee; John, Mark Earl

2000-01-01T23:59:59.000Z

283

Measurement of VOC reactivities using a photochemical flow reactor  

SciTech Connect (OSTI)

A commercial ambient air monitoring instrument, the Airtrak 2000, has been modified for use as a photochemical flow reactor and used to measure the absolute and incremental reactivity of 18 single test VOCs and the incremental reactivity of six multicomponent VOC mixtures. A flow technique is a useful supplement to traditional static chamber experiments. The static chamber technique involves periodic sampling of an irradiated mixture in a photochemical chamber. Under these conditions, the irradiated mixture is always in transition. Using a flow system, a steady-state condition is established within the flow reactor that is representative, in this case, of the early stages of the smog forming process in the atmosphere. The measurement technique also allows changes in the background chamber reactivity to be monitored and taken into account. The incremental reactivity of 13 of the 18 test compounds measured is compared with previously reported results from a static chamber experiment, and the two data sets are generally in good agreement. The additivity of reactivity was tested by measuring the incremental reactivity of six multicomponent mixtures, the components being compounds measured individually in this study. The measured reactivity of a mixture was compared to that calculated from the sum of the measured reactivity of the mixture`s individual components. The results show that reactivity is additive for the concentration range studied.

Hurley, M.D.; Chang, T.Y.; Japar, S.M.; Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.] [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.

1998-07-01T23:59:59.000Z

284

Reactive Dehydration technology for Production of Fuels and Chemicals...  

Broader source: Energy.gov (indexed) [DOE]

Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based chemicals from complex aqueous mixtures. SeparationPurification of Biomass...

285

Airborne measurement of OH reactivity during INTEX-B  

E-Print Network [OSTI]

plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

2009-01-01T23:59:59.000Z

286

Reactive Landing of Peptide Ions on Self-Assembled Monolayer...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

were characterized ex situ using time of flight-secondary ion mass spectrometry (TOF-SIMS) and infrared reflection absorption spectroscopy (IRRAS). We demonstrate that reactive...

287

Probing the structure and reactivity of gaseous ions.  

E-Print Network [OSTI]

??Studying ions in the gas phase provides the opportunity to observe their intrinsic structure and reactivity without extraneous perturbations such as solvent effects, aggregation or (more)

Meyer, Matthew Michael

2010-01-01T23:59:59.000Z

288

Monitoring Single Molecule Reactivity On a Carbon Nanotube  

E-Print Network [OSTI]

LETTERS Monitoring Single-Molecule Reactivity on a Carbondevice directly transduces single-molecule attachments andoptical methods in single-molecule research. Compared to

Collins, Philip G

2008-01-01T23:59:59.000Z

289

Physical Organic Chemistry of Reactive Intermediates | The Ames...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Physical Organic Chemistry of Reactive Intermediates The Jenks group specializes in physical organic chemistry, the "how" of organic reactions. Much of the work has centered on...

290

Chemical Analysis of Complex Organic Mixtures Using Reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mass Spectrometry. Abstract: Reactive nanospray desorption electrospray ionization (nano-DESI) combined with high-resolution mass spectrometry was utilized for the analysis of...

291

Isotope Program Transportation | Department of Energy  

Office of Environmental Management (EM)

Isotope Program Transportation Isotope Program Transportation Isotope Program Transportation More Documents & Publications Nuclear Fuel Storage and Transportation Planning Project...

292

Nuclear Transportation Management Services | Department of Energy  

Office of Environmental Management (EM)

Nuclear Transportation Management Services Nuclear Transportation Management Services Nuclear Transportation Management Services More Documents & Publications Transportation and...

293

Transportation Issues and Resolutions Compilation of Laboratory...  

Broader source: Energy.gov (indexed) [DOE]

Transportation Issues and Resolutions Compilation of Laboratory Transportation Work Package Reports Transportation Issues and Resolutions Compilation of Laboratory Transportation...

294

Transportation | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Transportation Power Electronics and Electric Machinery Fuels, Engines, Emissions Transportation Analysis Vehicle Systems Energy Storage Propulsion Materials Lightweight Materials Bioenergy Fuel Cell Technologies Clean Energy Home | Science & Discovery | Clean Energy | Research Areas | Transportation SHARE Transportation Research ORNL researcher Jim Szybist uses a variable valve-train engine to evaluate different types of fuels, including ethanol blends, and their effects on the combustion process in an internal combustion engine. Oak Ridge National Laboratory brings together science and technology experts from across scientific disciplines to partner with government and industry in addressing transportation challenges. Research objectives are

295

Midwestern Radioactive Materials Transportation Committee Agenda...  

Office of Environmental Management (EM)

Midwestern Radioactive Materials Transportation Committee Agenda Midwestern Radioactive Materials Transportation Committee Agenda Midwestern Radioactive Materials Transportation...

296

Instrumentation @ Catalysis: Reactivity and Structure Group | Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Instrumentation Instrumentation The Catalysis Group at BNL is leading research initiatives into the development of new tools and techniques that focus on the characterization of heterogeneous catalytic reactions and catalysts using imaging, spectroscopy and scattering techniques and integrated combinations of them under reaction conditions to unravel the morphology, chemical and structural properties, of catalysts, respectively. These efforts revolve around the use of synchrotron radiation (NSLS), electrons (CFN) and quantum tunneling tools with particular thrusts into imaging, spectroscopy and scattering. Groups Instrumentation(BNL) Three UHV chambers with diverse instrumentation for surface characterization: LEED, UPS, XPS, AES, TPD, ISS, PM-AP-IRRAS, Reactivity Cell. All the systems include ancillary instrumentation such as sputtering guns and metal evaporators. The IRRAS system was retrofitted with an ambient pressure (AP) cell on top of the UHV system. The sample can be prepared and characterized in UHV and then transfer in vacuum to the AP cell.

297

Transportation Infrastructure and Sustainable Development  

E-Print Network [OSTI]

A Better Forecasting Tool for Transportation Decision-making, Mineta Transportation Institute, San Jose Stateat the 2008 meeting of the Transportation Research Board and

Boarnet, Marlon G.

2008-01-01T23:59:59.000Z

298

Transportation Analysis | Clean Energy | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Analysis SHARE Transportation Analysis Transportation Analysis efforts at Oak Ridge National Laboratory contribute to the efficient, safe, and free movement of...

299

The universal radiative transport equation  

E-Print Network [OSTI]

THE UNIVERSAL RADIATIVE TRANSPORT EQUATION Rudolph W.The Universal Radiative Transport Equation Rudolph W.The various radiative transport equations used in general

Preisendorfer, Rudolph W

1959-01-01T23:59:59.000Z

300

OVERVIEW OF PROPOSED TRANSPORTATION ENERGY  

E-Print Network [OSTI]

.......................................................................................................................4 PROPOSED CALIFORNIA TRANSPORTATION FUEL PRICE FORECASTS......... 6 Summary....................................................................................................6 Petroleum Transportation Fuel Price Forecast Assumptions .............................................................6 California Transportation Fuel Price Forecasts

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

transportation | OpenEI  

Open Energy Info (EERE)

transportation transportation Dataset Summary Description The 2009 National Household Travel Survey (NHTS) provides information to assist transportation planners and policy makers who need comprehensive data on travel and transportation patterns in the United States. The 2009 NHTS updates information gathered in the 2001 NHTS and in prior Nationwide Personal Transportation Surveys (NPTS) conducted in 1969, 1977, 1983, 1990, and 1995. Source U.S. Department of Transportation, Federal Highway Administration Date Released February 28th, 2011 (3 years ago) Date Updated Unknown Keywords NHTS TEF transportation Transportation Energy Futures travel trip Data application/zip icon Travel Day Trip File (zip, 42.6 MiB) application/zip icon Household File (zip, 5 MiB) application/zip icon Person File (zip, 17.4 MiB)

302

Transportation Management Workshop: Proceedings  

SciTech Connect (OSTI)

This report is a compilation of discussions presented at the Transportation Management Workshop held in Gaithersburg, Maryland. Topics include waste packaging, personnel training, robotics, transportation routing, certification, containers, and waste classification.

Not Available

1993-10-01T23:59:59.000Z

303

Packaging and Transportation Safety  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Establishes safety requirements for the proper packaging and transportation of Department of Energy (DOE) offsite shipments and onsite transfers of hazardous materials and for modal transport. Cancels DOE O 460.1.

1996-10-02T23:59:59.000Z

304

Packaging and Transportation Safety  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Establishes safety requirements for the proper packaging and transportation of Department of Energy (DOE) offsite shipments and onsite transfers of hazardous materials and for modal transport. Canceled by DOE 460.1A

1995-09-27T23:59:59.000Z

305

Modelling transport fuel demand  

Science Journals Connector (OSTI)

Transport fuels account for an increasing share of oil ... interest to study the economics of the transport fuel market and thereby to evaluate the efficiency of the price mechanism as an instrument of policy in ...

Thomas Sterner; Carol A. Dahl

1992-01-01T23:59:59.000Z

306

Transportation Demand This  

U.S. Energy Information Administration (EIA) Indexed Site

Transportation Demand Transportation Demand This page inTenTionally lefT blank 75 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2013 Transportation Demand Module The NEMS Transportation Demand Module estimates transportation energy consumption across the nine Census Divisions (see Figure 5) and over ten fuel types. Each fuel type is modeled according to fuel-specific and associated technology attributes applicable by transportation mode. Total transportation energy consumption is the sum of energy use in eight transport modes: light-duty vehicles (cars and light trucks), commercial light trucks (8,501-10,000 lbs gross vehicle weight), freight trucks (>10,000 lbs gross vehicle weight), buses, freight and passenger aircraft, freight

307

Transportation and its Infrastructure  

E-Print Network [OSTI]

alternative means. In general, collective modes of transport use less energy and generate less GHGs than private cars.

2007-01-01T23:59:59.000Z

308

NREL: Transportation Research - Publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and fact sheets. Visit the following online resources to find publications about sustainable transportation research, development, and deployment. NREL Publications...

309

Vadose Zone Transport Field Study: Summary Report  

SciTech Connect (OSTI)

From FY 2000 through FY 2003, a series of vadose zone transport field experiments were conducted as part of the U.S. Department of Energys Groundwater/Vadose Zone Integration Project Science and Technology Project, now known as the Remediation and Closure Science Project, and managed by the Pacific Northwest National Laboratory (PNNL). The series of experiments included two major field campaigns, one at a 299-E24-11 injection test site near PUREX and a second at a clastic dike site off Army Loop Road. The goals of these experiments were to improve our understanding of vadose zone transport processes; to develop data sets to validate and calibrate vadose zone flow and transport models; and to identify advanced monitoring techniques useful for evaluating flow-and-transport mechanisms and delineating contaminant plumes in the vadose zone at the Hanford Site. This report summarizes the key findings from the field studies and demonstrates how data collected from these studies are being used to improve conceptual models and develop numerical models of flow and transport in Hanfords vadose zone. Results of these tests have led to a better understanding of the vadose zone. Fine-scale geologic heterogeneities, including grain fabric and lamination, were observed to have a strong effect on the large-scale behavior of contaminant plumes, primarily through increased lateral spreading resulting from anisotropy. Conceptual models have been updated to include lateral spreading and numerical models of unsaturated flow and transport have revised accordingly. A new robust model based on the concept of a connectivity tensor was developed to describe saturation-dependent anisotropy in strongly heterogeneous soils and has been incorporated into PNNLs Subsurface Transport Over Multiple Phases (STOMP) simulator. Application to field-scale transport problems have led to a better understanding plume behavior at a number of sites where lateral spreading may have dominated waste migration (e.g. BC Cribs and Trenches). The improved models have been also coupled with inverse models and newly-developed parameter scaling techniques to allow estimation of field-scale and effective transport parameters for the vadose zone. The development and utility of pedotransfer functions for describing fine-scale hydrogeochemical heterogeneity and for incorporating this heterogeneity into reactive transport models was explored. An approach based on grain-size statistics appears feasible and has been used to describe heterogeneity in hydraulic properties and sorption properties, such as the cation exchange capacity and the specific surface area of Hanford sediments. This work has also led to the development of inverse modeling capabilities for time-dependent, subsurface, reactive transport with transient flow fields using an automated optimization algorithm. In addition, a number of geophysical techniques investigated for their potential to provide detailed information on the subtle changes in lithology and bedding surfaces; plume delineation, leak detection. High-resolution resistivity is now being used for detecting saline plumes at several waste sites at Hanford, including tank farms. Results from the field studies and associated analysis have appeared in more than 46 publications generated over the past 4 years. These publications include test plans and status reports, in addition to numerous technical notes and peer reviewed papers.

Ward, Andy L.; Conrad, Mark E.; Daily, William D.; Fink, James B.; Freedman, Vicky L.; Gee, Glendon W.; Hoversten, Gary M.; Keller, Jason M.; Majer, Ernest L.; Murray, Christopher J.; White, Mark D.; Yabusaki, Steven B.; Zhang, Z. F.

2006-07-31T23:59:59.000Z

310

Burning of coal waste piles from Douro Coalfield (Portugal): Petrological, geochemical and mineralogical characterization  

Science Journals Connector (OSTI)

In the Douro Coalfield anthracites were exploited for decades (17951994). Besides many small mines Douro Coalfield had two principal mining areas (S. Pedro da Cova and Pejo). Coal mining activities cause several impacts on the environment, one of which is the amount of discard or waste which was disposed of all over Douro Coalfield resulting in one of the most significant and severe impacts on the environment. Over 20 waste piles exist in the old mining areas, geographically dispersed, and three of them are presently burning. Their ignition was caused by forest fires during the summer of 2005. Samples from the burning and unburned zones of the waste piles were studied as were the gas from vents and the minerals resulting after combustion. Geochemical processes and mineralogical transformations in the burning coal waste pile were investigated. Microscopic analyses of the samples identified some particular aspects related with combustion: oxidation of pyrite, the presence of iron oxides, organic particles with cracks and rims with lowered (suppressed) Rr, devolatilization vacuoles and some char structures. The occurrence of vitreous (glassy) material as well as FeAl spinels in the burning coal waste provide evidences that the combustion temperature could have reached values above 1000C. Due to combustion, and as expected, the samples studied reported high ash yields. Samples taken from the burning zones reported an increase of As, Cr, Li, Nb, Ni, Pb, Rb, Sr and LREE concentrations and a decrease in Zr and HREE concentrations. Enrichment in Cs, Li and Rb was noted when comparing with the geochemical composition of black shales and world coals composition that is related with the contribution of granitic rocks in the sediments that originated the main lithologies of the Douro Coalfield (carbonaceous shale and lithic arenites). Cluster analyses (R-type and Q-type) were performed to understand the trend between the unburned and burning samples and it seems that some chemical variations are responsible for this separation. Elemental sulphur and salammoniac (ammonium salt) are the coal fire gas minerals neoformed on the surface of piles, near the burning zones. They were identified by different techniques, mainly SEM-EDX, XRD and FTIR. Relatively high concentrations of several aromatic compounds were detected in the gas collected at the studied areas, as well as aliphatic hydrocarbons. The highest concentrations of aromatic hydrocarbons were measured in gas samples from S. Pedro da Cova waste pile. The exposure to hazardous compounds present in the gas is a serious risk to human health and the environment.

J. Ribeiro; E. Ferreira da Silva; D. Flores

2010-01-01T23:59:59.000Z

311

Northwestern University Transportation Center  

E-Print Network [OSTI]

Northwestern University Transportation Center 2011 Business Advisory Committee NUTC #12;#12;I have the pleasure of presenting our Business Advisory Committee members--a distinguished group of transportation industry lead- ers who have partnered with the Transportation Center in advancing the state of knowledge

Bustamante, Fabián E.

312

Louisiana Transportation Research Center  

E-Print Network [OSTI]

Louisiana Transportation Research Center LTRC www.ltrc.lsu.edu 2012-13 ANNUALREPORT #12;The Louisiana Transportation Research Center (LTRC) is a research, technology transfer, and training center administered jointly by the Louisiana Department of Transportation and Development (DOTD) and Louisiana State

Harms, Kyle E.

313

TRANSPORTATION: THE POTENTIAL  

E-Print Network [OSTI]

INTERMODAL TRANSPORTATION: THE POTENTIAL AND THE CHALLENGE A Summary Report 2003 #12;June 2003 To the Reader This report summarizes the second James L. Oberstar Forum on Transportation Policy and Technology. Over two days, we explored the chal- lenges and opportunities in intermodal transportation, addressing

Minnesota, University of

314

PalladianDigest Transportation  

E-Print Network [OSTI]

PalladianDigest CONNECT. EMPOWER. GROW. Tackling Transportation Challenges Nebraska has been a vital link in the nation's transportation system since the days when carts, wagons to University of Nebraska­Lincoln research. That's fine with UNL transportation researchers, said Larry Rilett

Farritor, Shane

315

Geologic, geophysical, and geochemical aspects of site-specific studies of the geopressured-geothermal energy resource of southern Louisiana. Final report  

SciTech Connect (OSTI)

The report consists of four sections dealing with progress in evaluating geologic, geochemical, and geophysical aspects of geopressured-geothermal energy resources in Louisiana. Separate abstracts have been prepared for the individual sections. (ACR)

Pilger, R.H. Jr. (ed.)

1985-01-01T23:59:59.000Z

316

A Learning-Based Approach to Reactive Security  

E-Print Network [OSTI]

Terms--Reactive security, risk management, attack graphs, online learning, adversarial learning, game vulnerability is plugged, CISOs typically perform a cost- benefit analysis to identify which risks to address of reactive strategies in an economic model of the CISO's security cost-benefit trade- offs. Unlike previously

Song, Dawn

317

A Reactive Measurement Framework Mark Allman and Vern Paxson  

E-Print Network [OSTI]

A Reactive Measurement Framework Mark Allman and Vern Paxson International Computer Science Institute Abstract. Often when assessing complex network behavior a single measure- ment is not enough for thinking about "measurement" as a process rather than an event. We introduce reactive measurement (REM

Paxson, Vern

318

Tropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest  

E-Print Network [OSTI]

and absolute contributions of nitric acid (HNO3) and NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) to totalTropospheric Reactive Nitrogen Speciation, Deposition, and Chemistry at Harvard Forest A thesis. Steven C. Wofsy Cassandra Volpe Horii Tropospheric Reactive Nitrogen Speciation, Deposition

319

A Reactive Control Approach for Pipeline Inspection with an AUV  

E-Print Network [OSTI]

A Reactive Control Approach for Pipeline Inspection with an AUV Pedro K. Paim, Bruno Jouvencel and research activities, performing tasks such as survey, inspection of sub-sea pipelines and object recovery of mission. This paper proposes a reactive control approach for pipeline following by a torpedo- like

Paris-Sud XI, Université de

320

From Teleo-Reactive specifications to architectural components: A model-driven approach  

Science Journals Connector (OSTI)

The Teleo-Reactive approach designed by N.J. Nilsson offers a high-level programming model that permits the development of reactive systems, such as robotic vehicles. Teleo-Reactive programs are written in a manner that allows engineers to define the ... Keywords: Component-based software development, Model-driven software development, Reactive systems, Robotics, Teleo-Reactive programs

Pedro SNchez; Diego Alonso; Jos Miguel Morales; Pedro Javier Navarro

2012-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Core-based integrated sedimentologic, stratigraphic, and geochemical analysis of the oil shale bearing Green River Formation, Uinta Basin, Utah  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DOE Award No.: DE-FE0001243 DOE Award No.: DE-FE0001243 Topical Report CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH Submitted by: University of Utah Institute for Clean and Secure Energy 155 South 1452 East, Room 380 Salt Lake City, UT 84112 Prepared for: United States Department of Energy National Energy Technology Laboratory April 2011 Oil & Natural Gas Technology Office of Fossil Energy Core-based integrated sedimentologic, stratigraphic, and geochemical analysis of the oil shale bearing Green River Formation, Uinta Basin, Utah Topical Report Reporting Period: October 31, 2009 through March 31, 2011 Authors: Lauren P. Birgenheier, Energy and Geoscience Insitute, University of Utah

322

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect (OSTI)

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

323

Injection and Reservoir Hazard Management: Mechanical Deformation and Geochemical Alteration at the InSalah CO2 Storage Project  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Injection and Reservoir Hazard Injection and Reservoir Hazard Management: Mechanical Deformation and Geochemical Alteration at the In Salah CO 2 Storage Project Background Safe and permanent storage of carbon dioxide (CO 2 ) in geologic reservoirs is critical to geologic sequestration. The In Salah Project (joint venture of British Petroleum (BP), Sonatrach, and StatoilHydro) has two fundamental goals: (1) 25-30 years of 9 billion cubic feet per year (bcfy) natural gas production from 8 fields in the Algerian

324

Use of iodine surface geochemical surveys in the Lodgepole and Minnelusa plays, U.S. northern Rockies  

SciTech Connect (OSTI)

The use of surface geochemistry is becoming more prevalent in oil exploration, especially for focusing specific target areas for 2D and 3D seismic surveys. Presented here are two surface geochemical surveys utilizing the iodine method in delineating Upper Minnelusa sands of Permian age in the Powder River basin and Lodgepole Waulsortian-like mounds of Mississippian age in the Williston basin. Iodine is an indirect indicator of a petroleum accumulation at depth. Increases in iodine anomalies are caused by the presence of petroleum seepage in the upper part of the soil section. In the very shallow surface, less than 10 ft, a reaction occurs between hydrocarbons and iodine under sunlight forming inorganic compounds. The source of the iodine is either from minerals in the soil and/or from the atmosphere with ultraviolet light as the initiator of the reaction. Any iodine in the subsurface could not migrate far in the presence of hydrocarbons and due to its large molecular size. The compounds that form in the soil remain solid and are relatively difficult to remove. Any surface geochemical anomaly needs to be followed by seismic in order to provide a specific drilling target. If a surface geochemical survey is properly designed and implemented, when no anomaly is present, then to date regardless of the type of method used the results have been dry holes. If a surface geochemical anomaly is present, the intensity, areal extent, and quality of the anomaly cannot determine the economic viability of the accumulation of depth, but there is a significant increase in the success rate. The best utilization of these methods is to determine areas where there is no possibility of finding petroleum and focusing on areas that do. In the case of the Lodgepole and Minnelusa plays, surface geochemistry allows a low cost approach and helps focus and minimize 2D and 3D survey costs.

Tedesco, S.A.; Bretz, S. [Atoka Geochemical Services Corp., Englewood, CO (United States)

1995-06-05T23:59:59.000Z

325

GEOCHEMICAL APPROACHES TO THE STUDY OF LIFE AND DEATH OF DINOSAURS FROM THE EARLY CRETACEOUS CEDAR MOUNTAIN FORMATION, UTAH  

E-Print Network [OSTI]

., Brown, T., Kirkland, J., and Stantucci, V. (Eds.), Proceedings of the 8th Conference on Fossil Resources, May 19-21, St. George, UT. 7-9. 8 Trueman, C. N., Benton, M.J., and Palmer, M.R. (2003) Geochemical taphonomy and shallow marine vertebrate... Chapter 2. Heterogeneous rare earth element (REE) patterns and concentrations in a fossil bone: implications for the use of REE in vertebrate taphonomy and fossilization history...........................................................................9...

Suarez, Celina Angelica

2010-04-22T23:59:59.000Z

326

Transportation Business Plan  

SciTech Connect (OSTI)

The Transportation Business Plan is a step in the process of procuring the transportation system. It sets the context for business strategy decisions by providing pertinent background information, describing the legislation and policies governing transportation under the NWPA, and describing requirements of the transportation system. Included in the document are strategies for procuring shipping casks and transportation support services. In the spirit of the NWPA directive to utilize the private sector to the maximum extent possible, opportunities for business ventures are obvious throughout the system development cycle.

Not Available

1986-01-01T23:59:59.000Z

327

Geochemical modeling of the near-surface hydrothermal system beneath the southern moat of Long Valley Caldera, California  

Science Journals Connector (OSTI)

Geochemical reaction path and mass balance modeling techniques were used to test the hypothesis that an eastwardly flowing plume of thermal water in the southern moat of the Long Valley caldera system reacts with hydrothermally altered intra-caldera tuffs and mixes with non-thermal groundwater. Our conceptual model is based on hypotheses in the literature and published geochemical and petrologic data. Mixing of thermal and non-thermal waters and reaction with wall rock were simulated using the reaction path code EQ3/6. Mass balance calculations were conducted to estimate the extent of waterrock interaction between the intra-caldera tuffs and fluids. A mixing ratio of 82% thermal and 18% non-thermal water reacting with altered tuff minerals closely matches Casa Diablo fluid compositions and minerals observed in petrographic studies. Results of this study show that the mineralogy and fluid chemistry observed in the shallow reservoir at Long Valley caldera are formed in an open system. Further, calcite precipitated in the system serves as a sink for high levels of CO2 generated by the deeper magmatic system. Our study serves as an example that processes acting in a geothermal system can be effectively quantified using geochemical modeling and mass balance calculations.

Regina N. Tempel; Daniel M. Sturmer; Jill Schilling

2011-01-01T23:59:59.000Z

328

The application of iodine and magnetic susceptibility surface geochemical surveys in the Lodgepole Play, Eastern Williston Basin, North Dakota  

SciTech Connect (OSTI)

The use of surface geochemistry as a first pass exploration tool is becoming more prevalent in petroleum exploration. This is especially true due to the high cost of 2-D and 3-D surveys in defining small targets such as the Waulsortian mounds of the Lodgepole Formation. Surface geochemical surveys are very effective in pinpointing specific target areas for seismic surveying and thus reducing costs. Presented are examples of surface geochemical surveys utilizing magnetic susceptibility and iodine methods in delineating reservoirs in the Lodgepole, Mission Canyon and Red River formations. The types of surveys presented vary from reconnaissance to detail and examples of how to define a grid will be discussed. Surface geochemical surveys can be very effective when the areal extent of the target(s) and the purpose of the survey are clearly defined prior to implementation. By determining which areas have microseepage and which areas do not, surface geochemistry can be a very effective tool in focusing exploration efforts and maximizing exploration dollars.

Tedesco, S.A. [Atoka Geochemical Services Corp., Englewood, CO (United States)

1996-06-01T23:59:59.000Z

329

Persistence and transport potential of chemicals in a multimedia environment  

SciTech Connect (OSTI)

Persistence in the environment and potential for long-range transport are related since time in the environment is required for transport. A persistent chemical will travel longer distances than a reactive chemical that shares similar chemical properties. Scheringer (1997) has demonstrated the correlation between persistence and transport distance for different organic chemicals. However, this correlation is not sufficiently robust to predict one property from the other. Specific chemicals that are persistent mayor may not exhibit long-range transport potential. Persistence and long-range transport also present different societal concerns. Persistence concerns relate to the undesired possibility that chemicals produced and used now may somehow negatively affect future generations. Long-range transport concerns relate to the undesired presence of chemicals in areas where these compounds have not been used. Environmental policy decisions can be based on either or both considerations depending on the aim of the regulatory program. In this chapter, definitions and methods for quantifying persistence and transport potential of organic chemicals are proposed which will assist in the development of sound regulatory frameworks.

van de Meent, D.; McKone, T.E.; Parkerton, T.; Matthies, M.; Scheringer, M.; Wania, F.; Purdy, R.; Bennett, D.H.

2000-02-01T23:59:59.000Z

330

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures  

E-Print Network [OSTI]

Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures Elodie Salmon a , Adri C.T. van Duin b , François Lorant Brown coal using the ReaxFF reactive force field. We find that these reactive MD simulations

Goddard III, William A.

331

FLOW AND REACTIVE TRANSPORT IN POROUS MEDIA INDUCED BY WELL INJECTION: SIMILARITY SOLUTION  

E-Print Network [OSTI]

with radius '' ? 0. Figure 1. Injection of contaminant into the soil (N = 2). *Delft University of Technology and Stochastics, Hausvogteiplatz 5­7, D­O­1086 Berlin, GERMANY. #12; The water flow regime is characterized by flushing with clean water. As the analysis of both cases is substantially different, we will restrict here

332

Research Activities at U.S. Government Agencies in Subsurface Reactive Transport Modeling  

Science Journals Connector (OSTI)

...Therefore, it is critical to understand and...CO. A list of critical contaminants related...Parks Shallow Land Disposal Area Parks Township...Rifle, CO X X UMTRA Salt Lake City, UT X...field experiments are critical complements to the...Available at www.srs.gov/general...

Randall T. Cygan; Caroline T. Stevens; Robert W. Puls; Steven B. Yabusaki; Robert D. Wauchope; Christian J. McGrath; Gary P. Curtis; Malcolm D. Siegel; Linda A. Veblen; David R. Turner

333

Fluid flow and reactive transport around potential nuclear waste emplacement tunnels at Yucca Mountain, Nevada  

E-Print Network [OSTI]

Unsaturated Zone at Yucca Mountain, Nevada. U.S. Geologicalzone model at Yucca Mountain, Nevada. J. Contaminantinvesti- gations at Yucca Mountain - the potential

Spycher, N.F.; Sonnenthal, E.L.; Apps, J.A.

2002-01-01T23:59:59.000Z

334

Stochastic modeling of transport and degradation of reactive solutes in heterogeneous aquifers  

E-Print Network [OSTI]

and Rubin, 1996]. Hydraulic properties can be represented mathematically as stationary correlated space random functions (SRF). SRFs are usually characterized by their first two statistical moments: the mean and the variance [Gelhar...

Fadel, Ziad Joseph

2006-08-16T23:59:59.000Z

335

An Operator Splitting Method for Nonlinear Reactive Transport Equations and Its  

E-Print Network [OSTI]

model ground- water contaminant biodegradation and many other interesting applications. The proposed contaminants in groundwater provides valuable guidelines for in-situ remediation strategies. Injection

Ewing, Richard E.

336

An exponential integrator for advection-dominated reactive transport in heterogeneous porous media  

E-Print Network [OSTI]

-engineering appli-5 cations, including oil and gas recovery from hydrocarbon reservoirs, ground-6 water adequate remediation sch

Lord, Gabriel

337

Uncertainty in the reactive transport model response to an alkaline perturbation in a clay formation  

E-Print Network [OSTI]

CSH_1.1 Gismondine Gyrolite Ettringite Katoite Stratlingite2) monosulfoaluminate ? ettringite. In clay, the major paths

Burnol, A.; Blanc, P.; Xu, T.; Spycher, N.; Gaucher, E.C.

2006-01-01T23:59:59.000Z

338

Reactive Transport Modeling of Natural Attenuation in Stormwater Bioretention Cells and Under Land Application of Wastewater  

E-Print Network [OSTI]

Natural attenuation is a cost effective method to treat wastewater applied into soil. The natural attenuation process includes diffusion, dispersion, microbial activity, oxidation, mineral precipitation, sorption, and ion exchange to mitigate...

Zhang, Jingqiu

2014-04-29T23:59:59.000Z

339

Trace element geochemical zoning in the Roosevelt Hot Springs thermal area, Utah  

SciTech Connect (OSTI)

Chemical interaction of thermal brines with reservoir rock in the Roosevelt Hot Springs thermal area has resulted in the development of distinctive trace element signatures. Geochemical analysis of soil samples, shallow temperature-gradient drill hole cuttings and deep drill hole cuttings provides a three-dimensional perspective of trace element distributions within the system. Distributions of As, Hg and Li provide the clearest expression of hydrothermal activity. Comparison of these distributions suggests that Li, followed by As and Hg, are progressively deposited by outward flowing, cooling, thermal fluids. Hg, in contrast to As and Li, is distributed only within the outer portions of the thermal system where temperatures are less than about 225/sup 0/C. Heating experiments indicate that extensive Hg remobilization in Roosevelt samples occurs at temperatures as low as 200/sup 0/ to 250/sup 0/C. This suggests that the distribution of Hg largely reflects the present system thermal configuration and that this distribution may be a useful soild geothermometer.

Christensen, O.D.; Moore, J.N.; Capuano, R.M.

1980-09-01T23:59:59.000Z

340

Geochemical Fingerprinting of Coltan Ores by Machine Learning on Uneven Datasets  

SciTech Connect (OSTI)

Two modern machine learning techniques, Linear Programming Boosting (LPBoost) and Support Vector Machines (SVMs), are introduced and applied to a geochemical dataset of niobium-tantalum ('coltan') ores from Central Africa to demonstrate how such information may be used to distinguish ore provenance, i.e., place of origin. The compositional data used include uni- and multivariate outliers and elemental distributions are not described by parametric frequency distribution functions. The 'soft margin' techniques of LPBoost and SVMs can be applied to such data. Optimization of their learning parameters results in an average accuracy of up to c. 92%, if spot measurements are assessed to estimate the provenance of ore samples originating from two geographically defined source areas. A parameterized performance measure, together with common methods for its optimization, was evaluated to account for the presence of uneven datasets. Optimization of the classification function threshold improves the performance, as class importance is shifted towards one of those classes. For this dataset, the average performance of the SVMs is significantly better compared to that of LPBoost.

Savu-Krohn, Christian, E-mail: christian.savu-krohn@unileoben.ac.at; Rantitsch, Gerd, E-mail: gerd.rantitsch@unileoben.ac.at [Montanuniversitaet Leoben, Department of Applied Geosciences and Geophysics (Austria); Auer, Peter, E-mail: auer@unileoben.ac.at [Chair for Information Technology, Montanuniversitaet Leoben (Austria); Melcher, Frank, E-mail: frank.melcher@bgr.de; Graupner, Torsten, E-mail: torsten.graupner@bgr.de [Federal Institute for Geosciences and Natural Resources (Germany)

2011-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

National Transportation Stakeholders Forum  

Broader source: Energy.gov (indexed) [DOE]

Transportation Stakeholders Forum Transportation Stakeholders Forum May 14-16, 2013 Tuesday, May 14 7:00 am - 5:00 pm Registration Niagara Foyer 7:00 am - 7:45 am Breakfast and Networking Grand A 8:00 am - 10:00 am National Updates for Transportation Stakeholder Groups and Guests - Panel Grand BC Moderator: John Giarrusso Jr., MA Emergency Management Agency / Northeast High-Level Radioactive Waste Transportation Task Force Co-Chair US Department of Energy, Office of Environmental Management - Steve O'Connor, Director, Office of Packaging & Transportation US Nuclear Regulatory Commission - Earl P. Easton, Senior Level Advisor (retired) and David W. Pstrak, Transportation and Storage Specialist, Division of Spent Fuel Storage and Transportation

342

Transportation System Requirements Document  

SciTech Connect (OSTI)

This Transportation System Requirements Document (Trans-SRD) describes the functions to be performed by and the technical requirements for the Transportation System to transport spent nuclear fuel (SNF) and high-level radioactive waste (HLW) from Purchaser and Producer sites to a Civilian Radioactive Waste Management System (CRWMS) site, and between CRWMS sites. The purpose of this document is to define the system-level requirements for Transportation consistent with the CRWMS Requirement Document (CRD). These requirements include design and operations requirements to the extent they impact on the development of the physical segments of Transportation. The document also presents an overall description of Transportation, its functions, its segments, and the requirements allocated to the segments and the system-level interfaces with Transportation. The interface identification and description are published in the CRWMS Interface Specification.

Not Available

1993-09-01T23:59:59.000Z

343

Transportation risk assessment for ethanol transport  

E-Print Network [OSTI]

(California, Texas Gulf Coast, New England Atlantic Coast) will be of particular interest. The goal is to conduct a quantitative risk assessment on the pipeline, truck, and rail transportation modes to these areas. As a result of the quantitative risk...

Shelton Davis, Anecia Delaine

2009-05-15T23:59:59.000Z

344

Reactive barriers for {sup 137}Cs retention  

SciTech Connect (OSTI)

{sup 137}Cs was dispersed globally by cold war activities and, more recently, by the Chernobyl accident. Engineered extraction of {sup 137}Cs from soils and groundwaters is exceedingly difficult. Because the half life of {sup 137}Cs is only 30.2 years, remediation might be more effective (and less costly) if {sup 137}Cs bioavailability could be demonstrably limited for even a few decades by use of a reactive barrier. Essentially permanent isolation must be demonstrated in those few settings where high nuclear level wastes contaminated the environment with {sup 135}Cs (half life 2.3x10{sup 6} years) in addition to {sup 137}Cs. Clays are potentially a low-cost barrier to Cs movement, though their long-term effectiveness remains untested. To identify optimal clays for Cs retention Cs resorption was measured for five common clays: Wyoming Montmorillonite (SWy-1), Georgia Kaolinites (KGa-1 and KGa-2), Fithian Illite (F-Ill), and K-Metabentonite (K-Mbt). Exchange sites were pre-saturated with 0.16 M CsCl for 14 days and readily exchangeable Cs was removed by a series of LiNO{sub 3} and LiCl washes. Washed clay were then placed into dialysis bags and the Cs release to the deionized water outside the bags measured. Release rates from 75 to 139 days for SWy-1, K-Mbt and F- 111 were similar; 0.017 to 0.021% sorbed Cs released per day. Both kaolinites released Cs more rapidly (0.12 to 0.05% of the sorbed Cs per day). In a second set of experiments, clays were doped for 110 days and subjected to an extreme and prolonged rinsing process. All the clays exhibited some capacity for irreversible Cs uptake so most soils have some limited ability to act as a natural barrier to Cs migration. However, the residual loading was greatest on K-Mbt ({approximately} 0.33 wt% Cs). Thus, this clay would be the optimal material for constructing artificial reactive barriers.

KRUMHANSL,JAMES L.; BRADY,PATRICK V.; ANDERSON,HOWARD L.

2000-05-19T23:59:59.000Z

345

Reactive sticking coefficients of silane on silicon  

SciTech Connect (OSTI)

We have investigated the reaction of room-temperature silane and disilane on a hot polycrystalline silicon surface using both a collision-free molecular beam and a very low pressure CVD cell. Reactive sticking coefficients were obtained from deposition rate data over a wide range of temperatures and silane (disilane) fluxes. The RSCs are substantially less than one, ranging from 6 x 10/sup -5/ to 4 x 10/sup -2/. For silane we observed curved Arrhenius plots with slopes decreasing from approx.60 kcal mol/sup -1/ at low temperatures to approx.2 kcal mol/sup -1/ at higher temperatures. The RSCs are independent of flux (pressure) at 1040/sup 0/C, but vary as flux to the approx.-1/2 power at 710/sup 0/C. A model comprised of a dissociative adsorption mechanism with competing associative desorption and reaction was found to give reasonable agreement. For disilane, we observed RSCs that were roughly ten times higher than those for silane. We also observed a curved Arrhenius plot and a flux dependence at 710/sup 0/C for disilane. 22 refs., 5 figs.

Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

1987-01-01T23:59:59.000Z

346

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

347

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally...

348

Metal-Pyrrolide Complexes in Three-fold Symmetry: Synthesis, Structure, Reactivity and Magnetism  

E-Print Network [OSTI]

Structure, Reactivity and Magnetism by William Hill Harman AStructure, Reactivity and Magnetism by William Hill Harmanlost time. Dave taught me magnetism and what it takes to win

Harman, William Hill

2010-01-01T23:59:59.000Z

349

Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene  

E-Print Network [OSTI]

The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement ...

Arizpe, Luis (Luis Alfredo)

2011-01-01T23:59:59.000Z

350

Aging Enhances the Production of Reactive Oxygen Species andBactericid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

351

Transportation | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Transportation From modeling and simulation programs to advanced electric powertrains, engines, biofuels, lubricants, and batteries, Argonne's transportation research is vital to the development of next-generation vehicles. Revolutionary advances in transportation are critical to reducing our nation's petroleum consumption and the environmental impact of our vehicles. Some of the most exciting new vehicle technologies are being ushered along by research conducted at Argonne National Laboratory. Our Transportation Technology R&D Center (TTRDC) brings together scientists and engineers from many disciplines across the laboratory to work with the U.S. Department of Energy (DOE), automakers and other industrial partners. Our goal is to put new transportation technologies on the road that improve

352

Transportation Services | Staff Services  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Services Transportation Services The BNL Transportation Office, located at 20 Brookhaven Avenue, Building 400A, is available to assist BNL employees, guests and visitors with transportation needs in support of Laboratory programs. The hours of operation are 8:30 AM - 5:00 PM Monday through Friday. To contact the Transportation Office call (631) 344-2535. Stony Brook Parking Passes The Transportation Office has a limited number of parking passes for the three (3) parking garages at Stony Brook University. The passes are available to and are intended for use by BNL employees/scientific staff on official business only. Passes may be used at the Administration, University Hospital and Health Services Center garages on the Stony Brook campus when visiting SBU on official business.

353

NREL: Transportation Research - Capabilities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Capabilities A Vision for Sustainable Transportation Line graph illustrating three pathways (biofuel, hydrogen, and electric vehicle) to reduce energy use and greenhouse gas...

354

Electronic Transport in Graphene  

Science Journals Connector (OSTI)

This chapter provides an experimental overview of the electrical transport properties of graphene and graphene nanoribbons, focusing on phenomena related to electronics ... and compares the characteristics of exf...

Jun Zhu

2012-01-01T23:59:59.000Z

355

NREL: Transportation Research - Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of a wide range of vehicle technologies and applications. NREL's innovative transportation research, development, and deployment projects accelerate widespread adoption of...

356

WIPP Transportation (FINAL)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(DOE) has established an elaborate system for safely transporting transuranic, or TRU, radioactive waste to the Waste Isolation Pilot Plant (WIPP) for permanent disposal, or...

357

UZ Colloid Transport Model  

SciTech Connect (OSTI)

The UZ Colloid Transport model development plan states that the objective of this Analysis/Model Report (AMR) is to document the development of a model for simulating unsaturated colloid transport. This objective includes the following: (1) use of a process level model to evaluate the potential mechanisms for colloid transport at Yucca Mountain; (2) Provide ranges of parameters for significant colloid transport processes to Performance Assessment (PA) for the unsaturated zone (UZ); (3) Provide a basis for development of an abstracted model for use in PA calculations.

M. McGraw

2000-04-13T23:59:59.000Z

358

Radioactive Material Transportation Practices  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Establishes standard transportation practices for Departmental programs to use in planning and executing offsite shipments of radioactive materials including radioactive waste. Does not cancel other directives.

2002-09-23T23:59:59.000Z

359

Reactive solid-state dewetting of Cu-Ni films on silicon  

SciTech Connect (OSTI)

The behavior of a 50 nm Cu-Ni alloy film on Si in a process of reactive solid-state dewetting is presented. The films were annealed at a range of temperatures (300-700 deg. C) in 1%H{sub 2} 99%N{sub 2} reducing atmosphere. The resulting alloy and silicide particles formed by film dewetting and film reaction with the substrate were distinguished by selective wet etching and examined by scanning electron microscopy and spectroscopy. After potassium hydroxide etch, regions that etch slower than silicon substrate have distribution statistics similar to the alloy and silicide particles prior to their removal, indicating strong coupling between mass transport across the interface and along the surface.

Clearfield, Raphael; Railsback, Justin G.; Melechko, Anatoli V. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Pearce, Ryan C. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Hensley, Dale K.; Fowlkes, Jason D.; Fuentes-Cabrera, Miguel [Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Simpson, Michael L.; Rack, Philip D. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2010-12-20T23:59:59.000Z

360

Photo of the Week: Reactive Ion Etching | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Reactive Ion Etching Reactive Ion Etching Photo of the Week: Reactive Ion Etching October 17, 2013 - 1:26pm Addthis Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material structures. In this photo, the drop-like domes were carved through a process called reactive ion etching, which produced the striped bubbles you see in the Laue lens. The prototype in this image helped scientists perfect the process of creating lenses so precise that scientists are able to focus x-rays to within a single nanometer. | Photo courtesy of Brookhaven National Laboratory. Have you ever heard of Laue lenses? These multilayer lenses are used to focus high-intensity x-ray beams to show the details of nano material

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquids: Reactivity of Primary Species Liquids: Reactivity of Primary Species James F. Wishart In "Ionic Liquids as Green Solvents: Progress and Prospects" Rogers, R. D. and Seddon, K. R. , Eds.; ACS Symp. Ser. 856, Ch. 31, pp. 381-395, American Chemical Society, Washington, DC, 2003. (ISBN 0-84123-856-1) [Information about the book] Abstract: An understanding of the radiation chemistry of ionic liquids is important for development of their applications in radioactive material processing and for the application of pulse radiolysis techniques to the general study of chemical reactivity in ionic liquids. The distribution of primary radiolytic species and their reactivities determine the yields of ultimate products and the radiation stability of a particular ionic liquid. This chapter introduces some principles of radiation chemistry and the

362

Detoxification of hydrolysate by reactive-extraction for generating biofuels  

Science Journals Connector (OSTI)

We introduce a reactive extraction to detoxify hydrolysate before fermentation to biofuels. In the selection of diluents, n-octanol showed the highest removal yield of 5-hydroxymethylfurfural (5-HMF) and levulini...

Gwi-Taek Jeong; Sung-Koo Kim; Don-Hee Park

2013-02-01T23:59:59.000Z

363

Cooperative Strategies and Reactive Search: A Hybrid Model Proposal  

Science Journals Connector (OSTI)

Cooperative strategies and reactive search are very promising techniques for solving hard optimization problems, since they reduce human intervention required to set up a method when the resolution of an unknown instance is needed. However, as far as ...

Antonio D. Masegosa; Franco Mascia; David Pelta; Mauro Brunato

2009-11-01T23:59:59.000Z

364

Mechanisms of Photochemistry and Reactive Oxygen Production by  

E-Print Network [OSTI]

photosensitizer that produces reactive oxygen species (ROS) in the presence of light; however, its properties medical and environmental contexts as well as the potential applications implied for industrial or water of transferring light energy to chemical oxidation potential in theformof

Alvarez, Pedro J.

365

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network [OSTI]

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

366

The Safe Storage Study for Autocatalytic Reactive Chemicals  

E-Print Network [OSTI]

In the U.S. Chemical Safety and Hazard Investigation Board (CSB) report, Improving Reactive Hazard Management, there are 37 out of 167 accidents, which occurred in a storage tank or a storage area. This fact demonstrates that thermal runaway...

Liu, Lijun

2010-10-12T23:59:59.000Z

367

Reactive Power Compensation Strategy of DGIF Wind Park  

Science Journals Connector (OSTI)

In this chapter, two different wind park reactive power compensation strategies for the DFIG wind park connected to the sub-transmission level are proposed. Except considering DFIG wind turbines as dynamic reacti...

JingJing Zhao; Yang Fu; DongDong Li

2014-01-01T23:59:59.000Z

368

Evolution of Memory in Reactive Artificial Neural Networks  

E-Print Network [OSTI]

in the context of evolution: how reactive agents could have evolved into cognitive ones with internalized memory? This study strives to find an answer to the question by simulating neuroevolution on artificial neural networks, with the hypothesis...

Chung, Ji Ryang

2012-07-16T23:59:59.000Z

369

Reactive Support and Voltage Control Service: Key Issues and Challenges  

E-Print Network [OSTI]

Reactive Support and Voltage Control Service: Key Issues and Challenges George Gross^, Paolo of Illinois at Urbana-Champaign, Urbana, IL 61801, USA, e-mail gross@uiuc.edu ° Dipartimento di Ingegneria

Gross, George

370

Analytical methods for determining the reactivity of pyrochemical salts  

SciTech Connect (OSTI)

Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

Phillips, A.G.; Stakebake, J.L.

1994-05-01T23:59:59.000Z

371

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

372

Local Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the re...

Turitsyn, Konstantin S; Backhaus, Scott; Chertkov, Misha

2010-01-01T23:59:59.000Z

373

Assessing low power reactivity levels in subcritical CANDU reactors  

SciTech Connect (OSTI)

A new technique has been developed for monitoring slow reactivity changes in Canadian deuterium uranium (CANDU) nuclear reactors during low power operation, following a sustained period of high power operation. The power doubling halving worth (PDHW) test tracks slow reactivity changes by evaluating the reactivity perturbation required by the power regulating system to halve and double reactor power over time. During low power operation of a CANDU reactor, the PDHW test is used to monitor the decay of the photoneutron precursors, so that the reactor power can be lowered using a preset amount of reactivity. The PDHW test is described in this paper and is validated by using computer simulations and operating data from a CANDU reactor.

Teare, S.W. [Corporation of the City of Mississauga, Ontario (Canada)] [Corporation of the City of Mississauga, Ontario (Canada); Shanes, F.C. [Ontario Hydro, Toronto, Ontario (Canada)] [Ontario Hydro, Toronto, Ontario (Canada); Hersey, M.W. [Pickering Nuclear Generating Station, Ontario (Canada)] [Pickering Nuclear Generating Station, Ontario (Canada)

1996-08-01T23:59:59.000Z

374

2006 TRANSPORTATION TOMORROW SURVEY JOINT PROGRAM IN TRANSPORTATION  

E-Print Network [OSTI]

2006 TRANSPORTATION TOMORROW SURVEY JOINT PROGRAM IN TRANSPORTATION UNIVERSITY OF TORONTO 2006 Transportation Tomorrow Survey Data Presentation #12;2006 TRANSPORTATION TOMORROW SURVEY JOINT PROGRAM IN TRANSPORTATION UNIVERSITY OF TORONTO City of Hamilton City of Kawartha Lakes City of Guelph City of Brantford

Toronto, University of

375

(Electronic structure and reactivities of transition metal clusters)  

SciTech Connect (OSTI)

The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

Not Available

1992-01-01T23:59:59.000Z

376

Measuring prehistoric mobility strategies based on obsidian geochemical and technological signatures in the Owens Valley, California  

E-Print Network [OSTI]

signatures in the Owens Valley, California Jelmer W. Eerkens a,*, Amy M. Spurling a,c , Michelle A. Gras b, a village site in southern Owens Valley, eastern California. Previous archaeological studies suggest quarrying within long-distance trips to distant hunting grounds, and subsequently transported bifacial cores

377

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive Reactive  

E-Print Network [OSTI]

Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition) homogeneous reactions with indoor pollutants. The #12;Proceedings of Healthy Buildings 2009 Paper 336 latter

Siegel, Jeffrey

378

Biofuels and Transportation  

E-Print Network [OSTI]

Biofuels and Transportation Impacts and Uncertainties Some Observations of a Reformed Ethanol and Logistics Symposium 3 Topics · Why Biofuels · Ethanol Economics · Ethanol Transportation Equipment Biofuels? · National Security · Reduce Imports of oil · Peak Oil · Replace Fossil Resources

Minnesota, University of

379

Northwestern University Transportation Center  

E-Print Network [OSTI]

and challenges for our society. Energy and sustainability, economic growth and development, quality of life in the world to recognize transportation as an interdisciplinary field, the Transportation Center was founded, as the tradition lives on, and the Center continues to renew itself and engage faculty and students with new

MacIver, Malcolm A.

380

Packaging and Transportation Safety  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

To establish safety requirements for the proper packaging and transportation of Department of Energy (DOE)/National Nuclear Security Administration (NNSA) offsite shipments and onsite transfers of hazardous materials and for modal transport. Cancels DOE O 460.1A. Canceled by DOE O 460.1C.

2003-04-04T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Packaging and Transportation Safety  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The order establishes safety requirements for the proper packaging and transportation of DOE, including NNSA, offsite shipments and onsite transfers of radioactive and other hazardous materials and for modal transportation. Cancels DOE O 460.1B, 5-14-10

2010-05-14T23:59:59.000Z

382

INLAND PORT TRANSPORTATION EVALUATION GUIDE  

E-Print Network [OSTI]

INLAND PORT TRANSPORTATION EVALUATION GUIDE by Robert Harrison, Center for Transportation Research Transportation Institute, The Texas A&M University System; and Jolanda Prozzi, Center for Transportation Research, The University of Texas at Austin CENTER FOR TRANSPORTATION RESEARCH Bureau of Engineering Research

Texas at Austin, University of

383

http://tti.tamu.edu Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freight  

E-Print Network [OSTI]

http://tti.tamu.edu Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freight pipeline transportation >>> Transportation operat > Freight traffic > Commodities > Travel time > Travel demand > http

384

TRANSPORTATION ENERGY RESEARCH PIER Transportation Research  

E-Print Network [OSTI]

engine and an Eaton Fuller 10speed manual transmission as the study's representative baseline vehicle beginning in 2017 while providing net savings over the life of the vehicle. Also, fuel cost savings far.energy.ca.gov/research/ transportation/ January 2011 Heavy-Duty Vehicle Emissions and Fuel Consumption Improvement Illustration

385

Transportation | Open Energy Information  

Open Energy Info (EERE)

Transportation Transportation Jump to: navigation, search Click to return to AEO2011 page AEO2011 Data From AEO2011 report . Market Trends From 2009 to 2035, transportation sector energy consumption grows at an average annual rate of 0.6 percent (from 27.2 quadrillion Btu to 31.8 quadrillion Btu), slower than the 1.2 percent average rate from 1975 to 2009. The slower growth is a result of changing demographics, increased LDV fuel economy, and saturation of personal travel demand.[1] References [1] ↑ 1.0 1.1 AEO2011 Transportation Sector Retrieved from "http://en.openei.org/w/index.php?title=Transportation&oldid=378906" What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load)

386

Argonne Transportation Current News  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

8 Transportation News & Highlights 8 Transportation News & Highlights EDTA Publications Now Online December 2008 -- View them here. Argonne to advise battery alliance December 2008 -- A coalition of more than fourteen companies has announced the creation of a new business alliance aimed at promoting U.S. production of lithium ion batteries. The newly formed National Alliance for Advanced Transportation Battery Cell Manufacture is based in Chicago. Argonne National Laboratory will serve in an advisory role as the Alliance begins operations. More... French Auto Industry Visits Center for Transportation Research November 18, 2008 -- Representatives of the French auto industry visited the Argonne Center for Transportation Research on November 18, 2008. The purpose of the visit was to share information and discuss technology opportunities for hybrid and electric vehicles. More...

387

GIS Regional Spatial Data from the Great Basin Center for Geothermal Energy: Geochemical, Geodesic, Geologic, Geophysical, Geothermal, and Groundwater Data  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The Great Basin Center for Geothermal Energy, part of the University of Nevada, Reno, conducts research towards the establishment of geothermal energy as an economically viable energy source within the Great Basin. The Center specializes in collecting and synthesizing geologic, geochemical, geodetic, geophysical, and tectonic data, and using Geographic Information System (GIS) technology to view and analyze this data and to produce favorability maps of geothermal potential. The center also makes its collections of spatial data available for direct download to the public. Data are in Lambert Conformable Conic Projection.

388

Advances in Transportation Technologies | Department of Energy  

Office of Environmental Management (EM)

Advances in Transportation Technologies Advances in Transportation Technologies Advances in Transportation Technologies More Documents & Publications TEC Working Group Topic Groups...

389

Transportation Emergency Preparedness Program | Department of...  

Office of Environmental Management (EM)

Transportation Emergency Preparedness Program Transportation Emergency Preparedness Program Planning for a Shipment Campaign - Identification of Responder Needs Transportation...

390

Transuranic Waste Transportation Working Group Agenda | Department...  

Office of Environmental Management (EM)

Transuranic Waste Transportation Working Group Agenda Transuranic Waste Transportation Working Group Agenda Transuranic Waste Transportation Working Group Agenda More Documents &...

391

Waste Isolation Pilot Plant Transportation Security | Department...  

Office of Environmental Management (EM)

Waste Isolation Pilot Plant Transportation Security Waste Isolation Pilot Plant Transportation Security Waste Isolation Pilot Plant Transportation Security More Documents &...

392

Research on fuzzy logic based dynamic boundary voltage and reactive power integrated control method  

Science Journals Connector (OSTI)

Aiming at the existing problems of conventional substation voltage and reactive power integrated control method, a new fuzzy logic based dynamic reactive power boundary voltage and reactive power integrated control method is proposed. Fuzzy logic control ... Keywords: dynamic boundary, fuzzy logic, reactive power, voltage

Zigang Xu; Fei Wang

2009-06-01T23:59:59.000Z

393

Development and Evaluation of a State-of-the-Science Reactive Plume  

E-Print Network [OSTI]

for plume rise, plume visibility, and stack opacity (5). Examples of other reactive plume models include

Zhang, Yang

394

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah  

Broader source: Energy.gov [DOE]

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

395

Transportation activity analysis using smartphones  

E-Print Network [OSTI]

Transportation activity surveys investigate when, where and how people travel in urban areas to provide information necessary for urban transportation planning. In Singapore, the Land Transport Authority (LTA) carries out ...

Xiao, Yu

396

Argonne Transportation - Publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Publications All downloadable documents on this site are in PDF format. You will need Adobe Reader to view these files (download Adobe Reader). Please note that some of these files are very large and may take some time to download. transforum TransForum The Center's quarterly newsletter featuring articles and photographs about current transportation research and breakthroughs. A 2011 STC Excellence Award winner. Subscribe to TransForum » factsheet icon Fact Sheets One sheet summaries on transportation topics and research argonne logo Recent Papers & Presentations Search for Papers, Presentations & More Find publications highlighting researcher work presented at conferences and other venues. Search by WORD or PHRASE Enter word or phrase

397

Sandia National Laboratories: Transportation Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Energy Electric Car Challenge Sparks Students' STEM Interest On January 9, 2015, in Energy, Energy Storage, News, News & Events, Partnership, Transportation Energy...

398

Development and Application of a Paleomagnetic/Geochemical Method for Constraining the Timing of Burial Diagenetic and Fluid  

SciTech Connect (OSTI)

Studies of diagenesis caused by fluid migration or other events are commonly hindered by a lack of temporal control. Our results to date demonstrate that a paleomagnetic/geochemical approach can be used to date fluid migration as well as burial diagenetic events. Our principal working hypothesis is that burial diagenetic processes (e.g., maturation of organic-rich sediments and clay diagenesis) and the migration of fluids can trigger the authigenesis of magnetic mineral phases. The ages of these events can be constrained by comparing chemical remanent magnetizations (CRMs) to independently established Apparent Polar Wander Paths. While geochemical (e.g. stable isotope and organic analyses) and petrographic studies provide important clues for establishing these relationships, the ultimate test of this hypothesis requires the application of independent dating methods to verify the paleomagnetic ages. Towards this end, we have used K-Ar dating of illitization as an alternative method for constraining the ages of magnetic mineral phases in our field areas.

Elmore, Richard D.; Engel, Michael H.

2005-03-10T23:59:59.000Z

399

Transportation risk assessment for ethanol transport  

E-Print Network [OSTI]

the quantitative risks involved with an ethanol pipeline. Pipelines that run from the Midwest, where the vast majority of ethanol is produced, to the target areas where reformulated gasoline is required (California, Texas Gulf Coast, New England Atlantic Coast... Atlantic Coast because of the large volume. It is beneficial to look at these areas as opposed to the iv smaller areas because pipeline transportation requires very large volumes. In order to find a meaningful comparison between all three...

Shelton Davis, Anecia Delaine

2008-10-10T23:59:59.000Z

400

Update Sustainable Transportation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transportation Transportation Vol.4, No.2 * August 2013 ORNL researchers Andreas Malikopoulos (right) and Stuart Daw Intelligent transportation vehicle subsystems will continue to grow exponentially, Andreas added. Developing control systems that are able to mimic the efficient learning and decision-making processes of biological organisms without resorting to on-board supercomputers could revolutionize transportation, he said. Stuart suggested, in the long-term, that "smart" vehicles need to mimic the ability of humans to efficiently perceive, filter, and rapidly respond to the flood of information available from the local environment, as well as from their own internal parts. He added that the idea of "intelligence" can also be extended to groups of vehicles.

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Managing Director Buildings, Transportation  

E-Print Network [OSTI]

Site Development Will Terris Manager Gardening Maintenance Jim Gish Manager Landscape Specialty Tegwyn Maintenance and project Delivery Scott Sherwood Director Transportation Services Glenl Wear Director Grounds Supervisor Specialty Crews 17 Area supervisors Custodial Maintenance Charles Anderson Supervisor Activity

Seamons, Kent E.

402

Transportation Baseline Report  

SciTech Connect (OSTI)

The National Transportation Program 1999 Transportation Baseline Report presents data that form a baseline to enable analysis and planning for future Department of Energy (DOE) Environmental Management (EM) waste and materials transportation. In addition, this Report provides a summary overview of DOEs projected quantities of waste and materials for transportation. Data presented in this report were gathered as a part of the IPABS Spring 1999 update of the EM Corporate Database and are current as of July 30, 1999. These data were input and compiled using the Analysis and Visualization System (AVS) which is used to update all stream-level components of the EM Corporate Database, as well as TSD System and programmatic risk (disposition barrier) information. Project (PBS) and site-level IPABS data are being collected through the Interim Data Management System (IDMS). The data are presented in appendices to this report.

Fawcett, Ricky Lee; Kramer, George Leroy Jr.

1999-12-01T23:59:59.000Z

403

Transportation Energy and Alternatives  

E-Print Network [OSTI]

Station in Indonesia Hydrogen refueling in Munich, Germany "You will never see widespread use of the fuel fuels" Potentially used for Transportation · Biogas (primarily for onsite electrical generation) LFG

Handy, Susan L.

404

Atmospheric Transport of Radionuclides  

SciTech Connect (OSTI)

The purpose of atmospheric transport and diffusion calculations is to provide estimates of concentration and surface deposition from routine and accidental releases of pollutants to the atmosphere. This paper discusses this topic.

Crawford, T.V.

2003-03-03T23:59:59.000Z

405

NREL: Transportation Research - Facilities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

work closely with a wide variety of partners to research and develop advanced transportation technologies and systems, moving them from the R&D arena to the marketplace. Learn...

406

Electron Heat Transport Measured  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Heat Transport Measured in a Stochastic Magnetic Field T. M. Biewer, * C. B. Forest, J. K. Anderson, G. Fiksel, B. Hudson, S. C. Prager, J. S. Sarff, and J. C. Wright...

407

Transport organ physiology  

Science Journals Connector (OSTI)

... Transport in Biology. Vol.IV A and B. Edited by G.Giebisch, D.C.Tosteson and H.H.Ussing. Pp.471; 939. (Springer: Berlin, Heidelberg and New ...

O.H. Petersen

1980-01-10T23:59:59.000Z

408

PBA Transportation Websites  

Broader source: Energy.gov [DOE]

PBA Transportation Websites presented to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of systems analysis in DOE Hydrogen Program.

409

Accident resistant transport container  

DOE Patents [OSTI]

The invention relates to a container for the safe air transport of plutonium having several intermediate wood layers and a load spreader intermediate an inner container and an outer shell for mitigation of shock during a hypothetical accident.

Andersen, John A. (Albuquerque, NM); Cole, James K. (Albuquerque, NM)

1980-01-01T23:59:59.000Z

410

Fluid transport container  

DOE Patents [OSTI]

An improved fluid container for the transport, collection, and dispensing of a sample fluid that maintains the fluid integrity relative to the conditions of the location at which it is taken. More specifically, the invention is a fluid sample transport container that utilizes a fitting for both penetrating and sealing a storage container under controlled conditions. Additionally, the invention allows for the periodic withdrawal of portions of the sample fluid without contamination or intermixing from the environment surrounding the sample container. 13 figs.

DeRoos, B.G.; Downing, J.P. Jr.; Neal, M.P.

1995-11-14T23:59:59.000Z

411

What are Intelligent Transportation Intelligent Transportation Systems (ITS) are  

E-Print Network [OSTI]

What are Intelligent Transportation Systems? Intelligent Transportation Systems (ITS) are existing, combined in innovative ways, integrated into the management of our multimodal transportation system aimed at saving lives, time, and resources. Transportation is the backbone of our society-- the movement of people

Bertini, Robert L.

412

Membrane Transport Chloride Transport Across Vesicle and Cell  

E-Print Network [OSTI]

Membrane Transport Chloride Transport Across Vesicle and Cell Membranes by Steroid-Based Receptors-established that molecules which transport cations across cell membranes (cationophores) can have potent biological effects the formation of an ion pair.[4a­g] Anion transport by purely electroneutral systems is still quite rare.[4j

Smith, Bradley D.

413

Internal structure, hygroscopic and reactive properties of mixed sodium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Internal structure, hygroscopic and Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Print Friday, 13 May 2011 00:00 Scientists recently combined experimental approaches and molecular dynamics modeling to gain new insights into the internal structure of sea salt particles and relate it to their fundamental chemical reactivity in the atmosphere. This research shows that surface enhancement or depletion of chemical components in marine particles can occur because of the difference in the chemical nature of the species. Because the atmospheric chemistry of the salt particles takes place at the gas-particle interface, understanding their complex surfaces provides new insights about their effect on the environment and climate change. Article Link.

414

Ionic Liquids and Ionizing Radiation: Reactivity of Highly Energetic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ionizing Radiation: Reactivity of Highly Energetic Ionizing Radiation: Reactivity of Highly Energetic Species James F. Wishart J. Phys. Chem. Lett. 1, 3225-3231 (2010). [Find paper at ACS Publications] or use ACS Articles on Request View the video on this Perspective article at The Journal of Physical Chemistry Letters (5:03) Selected for the ACS Special Virtual Issue on Ionic Liquids (March 2011). Abstract: Due to their unique properties, ionic liquids present many opportunities for basic research on the interactions of radiation with materials under conditions not previously available. At the same time, there are practical applied reasons for characterizing, understanding, and being able to predict how ionic-liquid-based devices and industrial-scale systems will perform under conditions of extreme reactivity, including radiation. This

415

Environmentally stable reactive alloy powders and method of making same  

DOE Patents [OSTI]

Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

1998-09-22T23:59:59.000Z

416

Options for Control of Reactive Power by Distributed Photovoltaic Generators  

E-Print Network [OSTI]

High penetration levels of distributed photovoltaic(PV) generation on an electrical distribution circuit present several challenges and opportunities for distribution utilities. Rapidly varying irradiance conditions may cause voltage sags and swells that cannot be compensated by slowly responding utility equipment resulting in a degradation of power quality. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We discuss and compare via simulation various design options for control systems to manage the reactive power generated by these inverters. An important design de...

Sulc, Petr; Backhaus, Scott; Chertkov, Michael

2010-01-01T23:59:59.000Z

417

Design and synthesis of reactive separation systems. Final report  

SciTech Connect (OSTI)

During the last decade there has been a rapid upturn in interest in reactive distillation. The chemical process industry recognizes the favorable economics of carrying out reaction simultaneously with distillation for certain classes of reacting systems, and many new processes have been built based on this technology. Interest is also increasing by academics and software vendors. Systematic design methods for reactive distillation systems have only recently begun to emerge. In this report we survey the available design techniques and point out the contributions made by our group at the University of Massachusetts.

Doherty, M.F.

1992-12-31T23:59:59.000Z

418

Transportation Systems Engineering GRADUATE STUDIES  

E-Print Network [OSTI]

Transportation Systems Engineering GRADUATE STUDIES TRANSPORTATION SYSTEMS are the building blocks and provides for an improved quality of life. However, transportation systems by their very nature also affect the environment through physical construction and operation of transportation facilities, and through the travel

Wang, Yuhang

419

Texas Transportation Poll Final report  

E-Print Network [OSTI]

Texas Transportation Poll Final report PRC 14-16-F #12;2 Texas Transportation Poll Texas A&M Transportation Institute PRC 14-16-F September 2014 Authors Chris Simek Tina Geiselbrecht #12;3 Table of Contents .......................................................................................................................... 8 Transportation Funding

420

Advanced Vehicle Electrification and Transportation Sector Electrifica...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Vehicle Electrification and Transportation Sector Electrification Advanced Vehicle Electrification & Transportation Sector...

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Petrographic, geochemical, and paleohydrologic evidence of nature of petroleum migration in Illinois basin  

SciTech Connect (OSTI)

Detailed studies of the petrography and geochemistry of petroleum source rocks, the geochemistry of petroleum accumulations, and the paleohydrology of the Illinois basin suggest an episode of long-range migration of Devonian-sourced petroleum during a period of regional ground water flow. Petrographic analyses of samples of the New Albany Shale group (Devonian/Mississippian) were used to define lateral and vertical variation in composition and thermal maturity of organic matter within the basin. These data delineate likely New Albany Shale group petroleum source areas. GC, GCMS, and carbon isotopic analyses of thermally mature New Albany Shale in southeastern Illinois and Silurian-reservoired petroleum samples from central Illinois were used in making oil-oil and oil-source rock correlations. These correlations indicate long-range lateral and downward cross-stratigraphic net migration. Compaction-driven and elevation head-driven ground-water flows within the basin were numerically modeled using available stratigraphic, structural, and hydrologic data. Calculations based on compaction-driven flow show the possibility of down-stratigraphic migration. Compaction-driven flow, however, cannot explain the amount of lateral transport inferred. Regional ground-water flow due to the uplift of the Pascola arch could explain the long-range lateral migration. Calculations of the effects of advective heat transport by elevation head-driven flow agree with estimates of temperatures made from fluid inclusions in basin mineralization.

Bethke, C.M.; Pruitt, J.D.; Barrows, M.H.

1984-04-01T23:59:59.000Z

422

Director Position Center for Urban Transportation  

E-Print Network [OSTI]

Director Position Center for Urban Transportation The Center for Urban Transportation Research for state policymakers, transportation agencies, transportation professionals and the public. CUTR conducts of Transportation's Federal Transit Administration and Federal Highway Administration, the Florida Department

Arslan, Hüseyin

423

Delaware Transportation Infrastructure Forum Problem Identification Statements  

E-Print Network [OSTI]

2013 Delaware Transportation Infrastructure Forum Problem Identification Statements Sponsored by The Delaware Center for Transportation and the Delaware Department of Transportation Delaware Center for Transportation Your main resource for transportation education and research Identifying Important Issues Related

Firestone, Jeremy

424

Non-Energetic Reactive Armor (NERA) and Semi-Energetic Reactive Armor (SERA) FY13 Final Report  

SciTech Connect (OSTI)

INL researchers have proposed prototypes for future lightweight armor systems that reside in a technology gap between explosive reactive armor and passive armor. The targets were designed to react under impact and throw a steel front plate into the path of the projectile, forcing the projectile to engage more of the front plate during its penetration process. These prototypes are intended to exhibit the enhanced efficiency of explosive reactive armor without the collateral damage often associated with explosive reactive armor. One of the prototype systems, Semi Energetic Reactive Armor (SERA), functions similarly to explosive reactive armor, but features a reactive material that reacts much slower than explosive reactive armor. Two different SERA test groups were built and featuring different ratios of aluminum Teflon(copyright) powders pressed into 0.5 in. thick energetic tiles and sandwiched between 0.25 in. thick RHA plates. The other prototype system, Non Energetic Reactive Armor (NERA), utilizes the strain energy in compressed rubber to launch a front flyer plate into the path of an incoming projectile. It is comprised of a 1 in. thick rubber layer sandwiched between two 0.25 in. thick RHA plates with bolt holes around the perimeter. Bolts are inserted through the entire target and tightened to compress the rubber sheet to significant strain levels (approximately 40%). A fourth group of targets was tested as a control group. It featured a 0.5 in. thick rubber sheet sandwiched between two 0.25 in. thick RHA plates, similar to the NERA test articles, but the rubber is uncompressed. The four test groups (uncompressed rubber, compressed rubber, 70/30 Al/PTFE, 50/50 Al/PTFE) were each fabricated with three identical test articles in each group. All twelve targets were subjected to ballistic testing at the National Security Test Range on July 17, 2013. They were tested with 0.5 in. diameter steel rods shot at a consistent velocity at each target. In order to characterize the energetic materials, break wires were embedded in the targets and burn velocities were measured. The residual mass method was used to compare the target performance of each group and final performance data is presented below.

Ben Langhorst; Nikki Rasmussen; Andrew Robinson

2013-08-01T23:59:59.000Z

425

CO2 maritime transportation  

Science Journals Connector (OSTI)

The objective of this study is to describe the complete transport chain of CO2 between capture and storage including a ship transport. This last one is composed by the following steps: Shore terminal including the liquefaction, temporary storage and CO2 loading. Ship with a capacity of 30,000m3. On or off shore terminal including an unloading system, temporary storage and export towards the final storage. Between all the possible thermodynamic states, the liquid one is most relevant two options are compared in the study (?50C, 7bar) and (?30C, 15bar). The ship has an autonomy of 6 days, is able to cover 1000km with a cargo of 2.5Mt/year. Several scenarios are studied varying the geographical position of the CO2 source, the number of harbours and the way the CO2 is finally stored. Depending on the option, the transport cost varies from 24 to 32/tCO2. This study confirms the conclusion of a previous study supported by ADEME, the cost transport is not negligible regarding the capture one when ships are considered. Transport by ship becomes a more economical option compared with an off shore pipeline when the distance exceeds 350km and with an onshore pipeline when it exceeds 1100km.

Sandrine Decarre; Julien Berthiaud; Nicolas Butin; Jean-Louis Guillaume-Combecave

2010-01-01T23:59:59.000Z

426

ADVANCED CUTTINGS TRANSPORT STUDY  

SciTech Connect (OSTI)

This is the second quarterly progress report for Year 2 of the ACTS project. It includes a review of progress made in Flow Loop development and research during the period of time between Oct 1, 2000 and December 31, 2000. This report presents a review of progress on the following specific tasks: (a) Design and development of an Advanced Cuttings Transport Facility (Task 2: Addition of a foam generation and breaker system), (b) Research project (Task 6): ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)'', (c) Research project (Task 7): ''Study of Cuttings Transport with Aerated Muds Under LPAT Conditions (Joint Project with TUDRP)'', (d) Research project (Task 8): ''Study of Flow of Synthetic Drilling Fluids Under Elevated Pressure and Temperature Conditions'', (e) Research project (Task 9): ''Study of Foam Flow Behavior Under EPET Conditions'', (f) Research project (Task 10): ''Study of Cuttings Transport with Aerated Mud Under Elevated Pressure and Temperature Conditions'', (g) Research on instrumentation tasks to measure: Cuttings concentration and distribution in a flowing slurry (Task 11), and Foam properties while transporting cuttings. (Task 12), (h) Development of a Safety program for the ACTS Flow Loop. Progress on a comprehensive safety review of all flow-loop components and operational procedures. (Task 1S). (i) Activities towards technology transfer and developing contacts with Petroleum and service company members, and increasing the number of JIP members. The tasks Completed During This Quarter are Task 7 and Task 8.

Troy Reed; Stefan Miska; Nicholas Takach; Kaveh Ashenayi; Gerald Kane; Mark Pickell; Len Volk; Mike Volk; Barkim Demirdal; Affonso Lourenco; Evren Ozbayoglu; Paco Vieira; Lei Zhou

2000-01-30T23:59:59.000Z

427

The Geography of Transport Systems-Maritime Transportation | Open Energy  

Open Energy Info (EERE)

The Geography of Transport Systems-Maritime Transportation The Geography of Transport Systems-Maritime Transportation Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Geography of Transport Systems-Maritime Transportation Agency/Company /Organization: Hofstra University Sector: Energy Focus Area: Transportation Topics: Technology characterizations Resource Type: Publications, Technical report Website: people.hofstra.edu/geotrans/eng/ch3en/conc3en/ch3c4en.html Cost: Free Language: English References: Maritime Transportation[1] "Maritime transportation, similar to land and air modes, operates on its own space, which is at the same time geographical by its physical attributes, strategic by its control and commercial by its usage. While geographical considerations tend to be constant in time, strategic and

428

Reactive Search Optimization: Learning while Roberto Battiti and Mauro Brunato  

E-Print Network [OSTI]

Reactive Search Optimization: Learning while Optimizing Roberto Battiti and Mauro Brunato 1, Universit`a di Trento, Italy, e-mail: roberto.battiti@unitn.it Mauro Brunato LION Lab, Universit`a di Trento, Italy, e-mail: mauro.brunato@unitn.it 1 #12;2 Roberto Battiti and Mauro Brunato in the loop between

Battiti, Roberto

429

Toward a new paradigm for reactive flow modeling.  

SciTech Connect (OSTI)

Traditional reactive flow modeling provides a computational representation of shock initiation of energetic materials. Most reactive flow models require ad hoc assumptions to obtain robust simulations, assumptions that result from partitioning energy and volume change between constituents in a reactive mixture. For example, most models assume pressure and/or temperature equilibrium for the mixture. Many mechanical insults to energetic materials violate these approximations. Careful analysis is required to ensure that the model assumptions and limitations are not exceeded. One limitation is that the shock to detonation transition is replicated only for strong planar shocks. Many models require different parameters to match data from thin pulse, ramp wave, or multidimensional loading, an approach that fails for complex loading. To accurately simulate reaction under non-planar shock impact scenarios a new formalism is required. The continuum mixture theory developed by Baer and Nunziato is used to eliminate ad hoc assumptions and limitations of current reactive flow models. This modeling paradigm represents the multiphase nature of reacting condensed/gas mixtures. Comparisons between simulations and data are presented.

Schmitt, Robert Gerard

2005-08-01T23:59:59.000Z

430

Resilient Intrusion Tolerance through Proactive and Reactive Recovery  

E-Print Network [OSTI]

system's correct operation. We design a proactive- reactive recovery service based on a hybrid the resilience of an intrusion-tolerant firewall adequate for the protection of critical infrastructures infras- tructures like the Power grid. One approach that promises to satisfy this requirement

Neves, Nuno

431

Voltage Regulation through Smart Utilization of Potential Reactive Power Resources  

Science Journals Connector (OSTI)

The introduction of demand response concept, in addition to increment of penetration of distributed generation (DG) based on renewable energies, make opportunities for the novel control schemes to be integrated in power system on a smart grid framework. ... Keywords: Demand response, distributed generation, reactive power, renewable energy, smart grid, voltage control

H. Kazari; A. Abbaspour-Tehrani Fard; A. S. Dobakhshari; A. M. Ranjbar

2011-11-01T23:59:59.000Z

432

Substituent Effects on the Reactivity of the Silicon-Carbon  

E-Print Network [OSTI]

Canada L8S 4M1 Received April 28, 2000 ABSTRACT Laser flash photolysis of various organosilicon compounds as a reactive intermediate in the high-temperature pyrolysis of a silacyclobutane deriva- tive.9 Hundreds describes our efforts to employ these techniquess laser flash photolysis methods in particularsto study

Leigh, William J.

433

Surface tension in a reactive binary mixture of incompressible fluids  

E-Print Network [OSTI]

Surface tension in a reactive binary mixture of incompressible fluids Henning Struchtrup Institute with a distributed form of surface tension. The model describes chemistry, diffusion, viscosity and heat transfer tension at the front. Keywords: Binary mixtures, Surface tension, Irreversible thermodynamics, Hele

Struchtrup, Henning

434

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may depend are combined is certainly not arbitrary. For instance, the repetition of one cycle may rely on the repetitionsDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Leue, Stefan

435

Dependency Analysis for Control Flow Cycles in Reactive Communicating Processes  

E-Print Network [OSTI]

processes of the system. The way in which cycle executions are combined is not ar- bitrary since cycles may in which cycle executions are combined is certainly not arbitrary. For instance, the repetition of oneDependency Analysis for Control Flow Cycles in Reactive Communicating Processes Stefan Leue1 , Alin

Reiterer, Harald

436

Effect of Number of Fractionating Trays on Reactive Distillation Performance  

E-Print Network [OSTI]

Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

Al-Arfaj, Muhammad A.

437

Reactive materials can quickly form plugs for blowout control  

SciTech Connect (OSTI)

Various types of reactive materials, or gunk, can react directly with produced fluids (oil, condensate, or brine) or with an additionally injected fluid to form a plug to kill blowout wells or shut off large flow paths. Several recent blowouts were successfully controlled with reactive plugs; other conventional methods would have been more difficult operationally and cost more. Several plug mixtures are available on the market and can be made to suit the type of application and any particular environmental concerns. With proper planning and application, reactive plugs should be considered as a prime well control method when injection into the blowout flow path is available. This method of blowout control can save significant time and expense. The paper discusses the two basic methods of using reactive fluids depending on the flow path available, the use of cements, application steps, environmental concerns, and three case histories: a horizontal well in Texas, a high pressure, high temperature well offshore Louisiana, and a gas blowout in Argentina.

Flak, L.H. [Wright Boots and Coots, Houston, TX (United States)

1995-04-17T23:59:59.000Z

438

Neutron economic reactivity control system for light water reactors  

DOE Patents [OSTI]

A neutron reactivity control system for a LWBR incorporating a stationary seed-blanket core arrangement. The core arrangement includes a plurality of contiguous hexagonal shaped regions. Each region has a central and a peripheral blanket area juxapositioned an annular seed area. The blanket areas contain thoria fuel rods while the annular seed area includes seed fuel rods and movable thoria shim control rods.

Luce, Robert G. (Glenville, NY); McCoy, Daniel F. (Latham, NY); Merriman, Floyd C. (Rotterdam, NY); Gregurech, Steve (Scotia, NY)

1989-01-01T23:59:59.000Z

439

Generalized Chemical Reactivity of Curved Surfaces: Carbon Nanotubes  

E-Print Network [OSTI]

. Following the decomposition, the total reaction energy Etotal, which is the index of chemical reactivity, can be divided into three terms: strain energy Estrain, C-X binding energy EC-X, and global relaxation in a CNT can enhance the hydrogenation energy at the location of the excess deformation so

Srivastava, Deepak

440

Local control of reactive power by distributed photovoltaic generators  

SciTech Connect (OSTI)

High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the real power generated by the PVs. Using one adjustable parameter per circuit, we balance the requirements on power quality and desire to minimize thermal losses. Numerical analysis of two exemplary systems, with comparable total PV generation albeit a different spatial distribution, show how to adjust the optimization parameter depending on the goal. Overall, this local scheme shows excellent performance; it's capable of guaranteeing acceptable power quality and achieving significant saving in thermal losses in various situations even when the renewable generation in excess of the circuit own load, i.e. feeding power back to the higher-level system.

Chertkov, Michael [Los Alamos National Laboratory; Turitsyn, Konstantin [Los Alamos National Laboratory; Sulc, Petr [Los Alamos National Laboratory; Backhaus, Scott [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Sleep & Memory/Review Memory reactivation and consolidation during sleep  

E-Print Network [OSTI]

Sleep & Memory/Review Memory reactivation and consolidation during sleep Ken A. Paller1 and Joel L, Illinois 60208-2710, USA Do our memories remain static during sleep, or do they change? We argue here that memory change is not only a natural result of sleep cognition, but further, that such change constitutes

Paller, Ken

442

Flow and transport model of the Savannah River Site Old Burial Grounds using Data Fusion modeling (DFM)  

SciTech Connect (OSTI)

The Data Fusion Modeling (DFM) approach has been used to develop a groundwater flow and transport model of the Old Burial Grounds (OBG) at the US Department of Energy`s Savannah River Site (SRS). The resulting DFM model was compared to an existing model that was calibrated via the typical trial-and-error method. The OBG was chosen because a substantial amount of hydrogeologic information is available, a FACT (derivative of VAM3DCG) flow and transport model of the site exists, and the calibration and numerics were challenging with standard approaches. The DFM flow model developed here is similar to the flow model by Flach et al. This allows comparison of the two flow models and validates the utility of DFM. The contaminant of interest for this study is tritium, because it is a geochemically conservative tracer that has been monitored along the seepline near the F-Area effluent and Fourmile Branch for several years.

NONE

1995-11-01T23:59:59.000Z

443

Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freight pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedes  

E-Print Network [OSTI]

and development > Airport maintenance > Bicycle and pedestrian > Ports and waterways >>> Transportation operat and development > Airport maintenance > Bicycle and pedestrian > Ports and waterways >>> Transportation operations pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedestrian

444

Efficient Transportation Decision Public Web Site: Bridging the Gap Between Transportation Planning and the Public  

E-Print Network [OSTI]

for accomplishing transportation planning and projectprocess the Efficient Transportation Decision Making (Process - is to make transportation decisions more quickly

Roaza, Ruth

2007-01-01T23:59:59.000Z

445

Argonne Transportation 2007 News  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 Transportation News & Highlights 7 Transportation News & Highlights Argonne Plug-In Hybrid Electric Vehicle Experts to Present Research at 23rd Electric Vehicle Symposium November 30, 2007 - Researchers from Argonne National Laboratory's Transportation Technology R&D Center will present 11 papers during the Electric Vehicle Symposium-23 that will be held in Anaheim, Calif., from Dec. 2-5. Download papers and presentations. Read about EVS-23. Argonne Teams with Industry to Promote PHEV R&D Nov. 12, 2007 - The U.S. Department of Energy's (DOE) Argonne National Laboratory has teamed up with several industrial partners, including some of America's largest automakers, to promote research and development of plug-in hybrid electric vehicles (PHEVs). Plug-in hybrids could revolutionize the automotive industry because, unlike conventional hybrid cars, they have the potential to run largely on electricity. More...

446

Rail Coal Transportation Rates  

U.S. Energy Information Administration (EIA) Indexed Site

reports reports Coal Transportation Rates to the Electric Power Sector With Data through 2010 | Release Date: November 16, 2012 | Next Release Date: December 2013 | Correction Previous editions Year: 2011 2004 Go Figure 1. Deliveries from major coal basins to electric power plants by rail, 2010 Background In this latest release of Coal Transportation Rates to the Electric Power Sector, the U.S. Energy Information Administration (EIA) significantly expands upon prior versions of this report with the incorporation of new EIA survey data. Figure 1. Percent of total U.S. rail shipments represented in data figure data Previously, EIA relied solely on data from the U.S. Surface Transportation Board (STB), specifically their confidential Carload Waybill Sample. While valuable, due to the statistical nature of the Waybill data,

447

National Transportation Stakeholders Forum  

Broader source: Energy.gov (indexed) [DOE]

N N ti l T t ti National Transportation Stakeholders Forum Chicago, IL, May 26, 2010 Ahmad Al-Daouk Date and page number - 1 Director, National Security Department National Nuclear Security Administration Service Center - Albuquerque, NM National Transportation Stakeholders Forum OSRP * NNSA Contractors transporting in commerce, are required law to comply with applicable regulations required law to comply with applicable regulations (e.g. federal, local, tribal) * Great majority of NNSA shipments are non-secured * Off-Site Source Recovery Program (OSRP) - OSRP is a U.S. Government activity sponsored and overseen by NNSA Office of Global Threat Reduction and the program is managed by LANL Mi i i t t d b d d Date and page number - 2 - Mission is to remove excess, unwanted, abandoned, or

448

Water Transport Exploratory Studies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Exploratory Studies Exploratory Studies Office of Hydrogen, Fuel Cells, and Infrastructure Technologies 2007 kickoff meeting February 13-14, 2007 DOE Forrestal Building Rod Borup Mukundan Rangachary, Bryan Pivovar, Yu Seung Kim, John Davey, David Wood, Tom Springer, Muhammad Arif , Ken Chen, Simon Cleghorn, Will Johnson, Karren More, Peter Wilde, Tom Zawodzinski Los Alamos National Lab This presentation does not contain any proprietary or confidential information Objectives * Develop understanding of water transport in PEM Fuel Cells (non-design-specific) * Evaluate structural and surface properties of materials affecting water transport and performance * Develop (enable) new components and operating methods * Accurately model water transport within the fuel cell * Develop a better understanding of the effects of

449

ADVANCED CUTTINGS TRANSPORT STUDY  

SciTech Connect (OSTI)

This report includes a review of the progress made in ACTF Flow Loop development and research during 90 days pre-award period (May 15-July 14, 1999) and the following three months after the project approval date (July15-October 15, 1999) The report presents information on the following specific subjects; (a) Progress in Advanced Cuttings Transport Facility design and development, (b) Progress report on the research project ''Study of Flow of Synthetic Drilling Fluids Under Elevated Pressure and Temperature Conditions'', (c) Progress report on the research project ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)'', (d) Progress report on the research project ''Study of Cuttings Transport with Aerated Muds Under LPAT Conditions (Joint Project with TUDRP)'', (e) Progress report on the research project ''Study of Foam Flow Behavior Under EPET Conditions'', (f) Progress report on the instrumentation tasks (Tasks 11 and 12) (g) Activities towards technology transfer and developing contacts with oil and service company members.

Ergun Kuru; Stefan Miska; Nicholas Takach; Kaveh Ashenayi; Gerald Kane; Len Volk; Mark Pickell; Evren Ozbayoglu; Barkim Demirdal; Paco Vieira; Affonso Lourenco

1999-10-15T23:59:59.000Z

450

Transportation Politics and Policy  

U.S. Energy Information Administration (EIA) Indexed Site

Reducing Greenhouse Reducing Greenhouse Gas Emissions from U.S. Transportation Steven Plotkin, Argonne National Laboratory (co-author is David Greene of Oak Ridge) 2011 EIA Energy Conference May 26-27, 2011 Washington, DC Overview  Presentation based on recent report from the Pew Center on Global Climate Change  Task: Assess the potential to substantially reduce transportation's GHG emissions by 2035 & 2050.  Base Case: Annual Energy Outlook 2010 Reference Case, extended to 2050  Three scenarios with differing assumptions about technological progress, policy initiatives, and public attitudes  Rely on existing studies to estimate impacts  Scenario analysis uses Kaya method to integrate policy impacts and avoid

451

Argonne Transportation Site Index  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Student Competitions Technology Analysis Transportation Research and Analysis Computing Center Working With Argonne Contact TTRDC Site Index General Information About TTRDC Media Center Current News News Archive Photo Archive Transportation Links Awards Contact Us Interesting Links Working with Argonne Research Resources Experts Batteries Engines & Fuels Fuel Cells Management Materials Systems Assessment Technology Analysis Tribology Vehicle Recycling Vehicle Systems Facilities Advanced Powertrain Research Facility Powertrain Test Cell 4-Wheel Drive Chassis Dynamometer Battery Test Facility Engine Research Facility Fuel Cell Test Facility Tribology Laboratory Tribology Laboratory Photo Tour Vehicle Recycling Partnership Plant Publications Searchable Database: patents, technical papers, presentations

452

Transportation Emergency Preparedness Program  

Broader source: Energy.gov (indexed) [DOE]

Stakeholders Forum 1 Planning for a Shipment Campaign Identifying Responders Needs National Transportation Stakeholders Forum Tom Clawson US Department of Energy Transportation Emergency Preparedness Program 2 Topics to Discuss * Campaign and Routings * Identifying Stakeholders * Communication Information * Determining Training Needs * Types of Training Programs * Support Resources 3 Campaign and Routing * Type of Shipments * Duration of Campaign * Possible Routes * Proposed Schedule 4 Identifying & Working with Stakeholders * Regional Groups * State Point of Contacts * Coordination Options 5 Communication Information * Fact sheet on campaign * Distribution of information * Conference calls and progress reports * National stakeholder meetings

453

EPAct Transportation Regulatory Activities: Contacts for EPAct  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Contacts Contacts for EPAct Transportation Regulatory Activities to someone by E-mail Share EPAct Transportation Regulatory Activities: Contacts for EPAct Transportation Regulatory Activities on Facebook Tweet about EPAct Transportation Regulatory Activities: Contacts for EPAct Transportation Regulatory Activities on Twitter Bookmark EPAct Transportation Regulatory Activities: Contacts for EPAct Transportation Regulatory Activities on Google Bookmark EPAct Transportation Regulatory Activities: Contacts for EPAct Transportation Regulatory Activities on Delicious Rank EPAct Transportation Regulatory Activities: Contacts for EPAct Transportation Regulatory Activities on Digg Find More places to share EPAct Transportation Regulatory Activities: Contacts for EPAct Transportation Regulatory Activities on

454

Mass Transport within Soils  

SciTech Connect (OSTI)

Contaminants in soil can impact human health and the environment through a complex web of interactions. Soils exist where the atmosphere, hydrosphere, geosphere, and biosphere converge. Soil is the thin outer zone of the earth's crust that supports rooted plants and is the product of climate and living organisms acting on rock. A true soil is a mixture of air, water, mineral, and organic components. The relative proportions of these components determine the value of the soil for agricultural and for other human uses. These proportions also determine, to a large extent, how a substance added to soil is transported and/or transformed within the soil (Spositio, 2004). In mass-balance models, soil compartments play a major role, functioning both as reservoirs and as the principal media for transport among air, vegetation, surface water, deeper soil, and ground water (Mackay, 2001). Quantifying the mass transport of chemicals within soil and between soil and atmosphere is important for understanding the role soil plays in controlling fate, transport, and exposure to multimedia pollutants. Soils are characteristically heterogeneous. A trench dug into soil typically reveals several horizontal layers having different colors and textures. As illustrated in Figure 1, these multiple layers are often divided into three major horizons: (1) the A horizon, which encompasses the root zone and contains a high concentration of organic matter; (2) the B horizon, which is unsaturated, lies below the roots of most plants, and contains a much lower organic carbon content; and (3) the C horizon, which is the unsaturated zone of weathered parent rock consisting of bedrock, alluvial material, glacial material, and/or soil of an earlier geological period. Below these three horizons lies the saturated zone - a zone that encompasses the area below ground surface in which all interconnected openings within the geologic media are completely filled with water. Similarly to the unsaturated zone with three major horizons, the saturated zone can be further divided into other zones based on hydraulic and geologic conditions. Wetland soils are a special and important class in which near-saturation conditions exist most of the time. When a contaminant is added to or formed in a soil column, there are several mechanisms by which it can be dispersed, transported out of the soil column to other parts of the environment, destroyed, or transformed into some other species. Thus, to evaluate or manage any contaminant introduced to the soil column, one must determine whether and how that substance will (1) remain or accumulate within the soil column, (2) be transported by dispersion or advection within the soil column, (3) be physically, chemically, or biologically transformed within the soil (i.e., by hydrolysis, oxidation, etc.), or (4) be transported out of the soil column to another part of the environment through a cross-media transfer (i.e., volatilization, runoff, ground water infiltration, etc.). These competing processes impact the fate of physical, chemical, or biological contaminants found in soils. In order to capture these mechanisms in mass transfer models, we must develop mass-transfer coefficients (MTCs) specific to soil layers. That is the goal of this chapter. The reader is referred to other chapters in this Handbook that address related transport processes, namely Chapter 13 on bioturbation, Chapter 15 on transport in near-surface geological formations, and Chapter 17 on soil resuspention. This chapter addresses the following issues: the nature of soil pollution, composition of soil, transport processes and transport parameters in soil, transformation processes in soil, mass-balance models, and MTCs in soils. We show that to address vertical heterogeneity in soils in is necessary to define a characteristic scaling depth and use this to establish process-based expressions for soil MTCs. The scaling depth in soil and the corresponding MTCs depend strongly on (1) the composition of the soil and physical state of the soil, (2) the chemical and physic

McKone, Thomas E.

2009-03-01T23:59:59.000Z

455

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Broader source: Energy.gov (indexed) [DOE]

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Final Report Phase II: Performance Evaluation of Permeable Reactive

456

Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium  

Broader source: Energy.gov (indexed) [DOE]

Alternatives for Mending a Permeable Reactive Barrier at a Former Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah Alternatives for Mending a Permeable Reactive Barrier at a Former Uranium Milling Site: Monticello, Utah More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium Mill Phase II: Performance Evaluation of Permeable Reactive Barriers and

457

Photoluminescent silicon nanocrystals synthesized by reactive laser Daria Riabinina,a  

E-Print Network [OSTI]

Photoluminescent silicon nanocrystals synthesized by reactive laser ablation Daria Riabinina reactive laser ablation in oxygen atmosphere followed by annealing. We observe a strong photoluminescence size, obtained independently by fitting photoluminescence spectra and from x-ray diffraction patterns

458

Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel  

Broader source: Energy.gov [DOE]

This study uses numerical simulations to explore the use of wet ethanol as the low-reactivity fuel and diesel as the high-reactivity fuel for RCCI operation in a heavy-duty diesel engine.

459

Bioinformatic analysis of xenobiotic reactive metabolite target proteins and their interacting partners  

E-Print Network [OSTI]

Background Protein covalent binding by reactive metabolites of drugs, chemicals and natural products can lead to acute cytotoxicity. Recent rapid progress in reactive metabolite target protein identification has shown ...

Hanzlik, Robert P.; Fang, Jianwen; Koen, Yakov M.

2009-06-12T23:59:59.000Z

460

Chemical Reactivity of Reduced TiO2(110): The dominant role of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Transportation and Program Management Services  

Broader source: Energy.gov (indexed) [DOE]

Atlanta, Georgia Atlanta, Georgia Transportation and Program Management Services Secured Transportation Services, LLC Founded: December, 2003 ff Staff: 7 Experience: Over 145 years combined experience in Nuclear Transportation, Security, HP & Operations Services Transportation The largest Transportation Coordinators of Spent Nuclear Fuel in North America On-Site, Hands-On Assistance (Before & During both Loading & Transport) P d A i t (W iti d/ R i ) Procedure Assistance (Writing and/or Review) Package Handling, Loading Services Certificate of Compliance and Competent Authority Reviews & Requests Carrier Coordination (Empty Packages & Equipment, Loaded, & Returns) Vessel Charters, Special Trains, Dedicated Exclusive Use Trucks p

462

Sustainable Transportation | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Sustainable Transportation Sustainable Transportation Sustainable Transportation Bioenergy Read more Hydrogen and Fuel Cells Read more Vehicles Read more The Office of Energy Efficiency and Renewable Energy (EERE) leads U.S. researchers and other partners in making transportation cleaner and more efficient through solutions that put electric drive vehicles on the road and replace oil with clean domestic fuels. Through our Vehicle, Bioenergy, and Fuel Cell Technologies Offices, EERE advances the development of next-generation technologies to improve plug-in electric and other alternative-fuel vehicles, advanced combustion engine and vehicle efficiency, and produce low-carbon domestic transportation fuels. SUSTAINABLE TRANSPORTATION Vehicles Bioenergy Hydrogen & Fuel Cells Vehicles Bioenergy

463

Geochemical and hydrogeologic evolution of alkaline discharges from abandoned coal mines  

SciTech Connect (OSTI)

Numerous large flow (> 2,000 l/min), historically (pre-1973) acidic, abandoned underground deep mine discharges in southwestern Pennsylvania are now alkaline in character, with circumneutral pH. Recently measured flow rates are consistent with those measured 25--30 years ago; thus the change in chemistry is not simply due to dilution by increased flows of uncontaminated water through the mines. It is likely that flooding of the mines has decreased the extent of acidity enhancing aerobic conditions, and that decades of weathering have reduced the amount of reactive pyrite. However, the mines continue to yield a sulfate-rich, Fe-contaminated (19--79 ppm) drainage. These highly alkaline discharges (up to 330 ppm as CaCO{sub 3}) are accompanied by large concentrations of sodium (up to 700 ppm) and suggest cation exchange with the associated overburden. To assess the hydrogeological conditions that result in the formation of alkaline Fe-contaminated mine discharges, the authors examined all the major discharges from a single synclinal basin. The northeast-trending Irwin synclinal coal basin encompasses 94 mi{sup 2} and was extensively mined by underground methods during the first half of this century. All major streams that arise within or cross the syncline are polluted by mine drainage that ranges from highly acidic Fe- and Al-contaminated discharges in the northern portion of the syncline to highly alkaline, iron and sulfate-contaminated discharges to the south. The hydrology of the basin is controlled by its southern plunging structure, by outcrops or drainage tunnels on the western arms of the syncline, and by several coal barriers. A first-order hydrogeologic model was constructed to evaluate ground water flow into and through the mine complexes found in the basin. The model integrates the basin geometry with structural and mine barrier components to determine groundwater flow paths and estimate residence time. Water quality is related to the cumulative proportion of up-gradient flooded and unflooded mine workings. Small discharges from unflooded, gravity-flow portions of the mined-out portion of the Pittsburgh Coal seam are highly acidic, and large artesian flows of water affected by only a short flow through flooded anoxic mine pools are moderately acidic. Those discharges subjected to increased residence time in flooded anoxic portions of the mines are increasingly alkaline. Refinement of this model could aid in prediction and hydrogeologic manipulation of these high flow Fe-contaminated discharges that are the main pollutant in many streams throughout Northern Appalachia and other coal mining areas throughout the world.

Winters, W.R.; Capo, R.C.; Wolinsky, M.A.; Weaver, T.J.; Hedin, R.S.

1999-07-01T23:59:59.000Z

464

Update Sustainable Transportation Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 * July 2012 3 * July 2012 Boosting the battery industry Future automotive batteries could cost less and pack more power because of ORNL's new Battery Manufacturing Facility. Co-located with the National Transportation Research Center and Manufacturing Demonstration Facility off Hardin Valley Road, the $3 million DOE facility allows for collaboration with industry and other national labs while protecting

465

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

466

Regional Transportation Coordination Study  

E-Print Network [OSTI]

.......................................................................................................... 6-1 Option to Increase Motor Vehicle Registration Fee .................................................................... 6-2 Transportation Development Credits... identified except for inefficiencies in rural vehicles sitting idle waiting for passengers. Gaps in service identified included employee access to work and a lack of rural/urban evening and weekend service. Along with assessing the current service level...

Golden Crescent Regional Planning Commission

467

Transport reactor development status  

SciTech Connect (OSTI)

This project is part of METC`s Power Systems Development Facility (PSDF) located at Wilsonville, Alabama. The primary objective of the Advanced Gasifier module is to produce vitiated gases for intermediate-term testing of Particulate Control Devices (PCDs). The Transport reactor potentially allows particle size distribution, solids loading, and particulate characteristics in the off-gas stream to be varied in a number of ways. Particulates in the hot gases from the Transport reactor will be removed in the PCDs. Two PCDs will be initially installed in the module; one a ceramic candle filter, the other a granular bed filter. After testing of the initial PCDs they will be removed and replaced with PCDs supplied by other vendors. A secondary objective is to verify the performance of a Transport reactor for use in advanced Integrated Gasification Combined Cycle (IGCC), Integrated Gasification Fuel Cell (IG-FC), and Pressurized Combustion Combined Cycle (PCCC) power generation units. This paper discusses the development of the Transport reactor design from bench-scale testing through pilot-scale testing to design of the Process Development Unit (PDU-scale) facility at Wilsonville.

Rush, R.E.; Fankhanel, M.O.; Campbell, W.M.

1994-10-01T23:59:59.000Z

468

Climate Change and Transportation  

E-Print Network [OSTI]

, 2009, EPA sent report to OMB with finding that GHG emissions are an endangerment to the public's health that FHWA guidance will focus on planning- level approach to GHG ­ Effect on transportation projects;6 WSDOT Efforts · Climate Change Team · Project Level GHG Approach · Planning Level GHG Approach

Minnesota, University of

469

Transport of Entanglement  

E-Print Network [OSTI]

We consider the propagation of two-photon light in a random medium. We show that the Wigner distribution of the two-photon wave function obeys an equation that is analogous to the radiative transport equation for classical light. Using this result, we predict that the entanglement of a photon pair is destroyed with propagation.

Manabu Machida; Vadim A Markel; John C Schotland

2012-10-17T23:59:59.000Z

470

Storing and transporting energy  

DOE Patents [OSTI]

Among other things, hydrogen is released from water at a first location using energy from a first energy source; the released hydrogen is stored in a metal hydride slurry; and the metal hydride slurry is transported to a second location remote from the first location.

McClaine, Andrew W. (Lexington, MA); Brown, Kenneth (Reading, MA)

2010-09-07T23:59:59.000Z

471

TRANSPORTATION Policy Research CENTER  

E-Print Network [OSTI]

, and describes conditions necessary for successful public-private transportation partnerships. The researchers found that effective P3 programs rely on these factors for their success: Enabling Legislation in the process is necessary. Economic Environment: Favorable economic conditions conducive to investment-- from

472

ADVANCED CUTTINGS TRANSPORT STUDY  

SciTech Connect (OSTI)

This is the first quarterly progress report for Year 2 of the ACTS project. It includes a review of progress made in Flow Loop development and research during the period of time between July 14, 2000 and September 30, 2000. This report presents information on the following specific tasks: (a) Progress in Advanced Cuttings Transport Facility design and development (Task 2), (b) Progress on research project (Task 8): ''Study of Flow of Synthetic Drilling Fluids Under Elevated Pressure and Temperature Conditions'', (c) Progress on research project (Task 6): ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)'', (d) Progress on research project (Task 7): ''Study of Cuttings Transport with Aerated Muds Under LPAT Conditions (Joint Project with TUDRP)'', (e) Progress on research project (Task 9): ''Study of Foam Flow Behavior Under EPET Conditions'', (f) Initiate research on project (Task 10): ''Study of Cuttings Transport with Aerated Mud Under Elevated Pressure and Temperature Conditions'', (g) Progress on instrumentation tasks to measure: Cuttings concentration and distribution (Tasks 11), and Foam properties (Task 12), (h) Initiate a comprehensive safety review of all flow-loop components and operational procedures. Since the previous Task 1 has been completed, we will now designate this new task as: (Task 1S). (i) Activities towards technology transfer and developing contacts with Petroleum and service company members, and increasing the number of JIP members.

Troy Reed; Stefan Miska; Nicholas Takach; Kaveh Ashenayi; Gerald Kane; Mark Pickell; Len Volk; Mike Volk; Barkim Demirdal; Affonso Lourenco; Evren Ozbayoglu; Paco Vieira

2000-10-30T23:59:59.000Z

473

ADVANCED CUTTINGS TRANSPORT STUDY  

SciTech Connect (OSTI)

This is the second quarterly progress report for Year 3 of the ACTS project. It includes a review of progress made in: (1) Flow Loop development and (2) research tasks during the period of time between Oct 1, 2001 and Dec. 31, 2001. This report presents a review of progress on the following specific tasks: (a) Design and development of an Advanced Cuttings Transport Facility (Task 3: Addition of a Cuttings Injection/Collection System), (b) Research project (Task 6): ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)'', (c) Research project (Task 9): ''Study of Foam Flow Behavior Under EPET Conditions'', (d) Research project (Task 10): ''Study of Cuttings Transport with Aerated Mud Under Elevated Pressure and Temperature Conditions'', (e) Research on instrumentation tasks to measure: Cuttings concentration and distribution in a flowing slurry (Task 11), and Foam properties while transporting cuttings. (Task 12), (f) Development of a Safety program for the ACTS Flow Loop. Progress on a comprehensive safety review of all flow-loop components and operational procedures. (Task 1S). (g) Activities towards technology transfer and developing contacts with Petroleum and service company members, and increasing the number of JIP members.

Troy Reed; Stefan Miska; Nicholas Takach; Kaveh Ashenayi; Gerald Kane; Mark Pickell; Len Volk; Mike Volk; Affonso Lourenco; Evren Ozbayoglu; Lei Zhou

2002-01-30T23:59:59.000Z

474

ADVANCED CUTTINGS TRANSPORT STUDY  

SciTech Connect (OSTI)

This is the third quarterly progress report for Year 3 of the ACTS Project. It includes a review of progress made in: (1) Flow Loop construction and development and (2) research tasks during the period of time between Jan. 1, 2002 and Mar. 31, 2002. This report presents a review of progress on the following specific tasks: (a) Design and development of an Advanced Cuttings Transport Facility (Task 3: Addition of a Cuttings Injection/Separation System), (b) Research project (Task 6): ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)'', (c) Research project (Task 9b): ''Study of Foam Flow Behavior Under EPET Conditions'', (d) Research project (Task 10): ''Study of Cuttings Transport with Aerated Mud Under Elevated Pressure and Temperature Conditions'', (e) Research on three instrumentation tasks to measure: Cuttings concentration and distribution in a flowing slurry (Task 11), Foam texture while transporting cuttings. (Task 12), and Viscosity of Foam under EPET (Task 9b); (f) Development of a Safety program for the ACTS Flow Loop, progress on a comprehensive safety review of all flow-loop components and operational procedures. (Task 1S); and (g) Activities towards technology transfer and developing contacts with Petroleum and service company members, and increasing the number of JIP members.

Troy Reed; Stefan Miska; Nicholas Takach; Kaveh Ashenayi; Mark Pickell; Len Volk; Mike Volk; Evren Ozbayoglu; Lei Zhou

2002-04-30T23:59:59.000Z

475

ADVANCED CUTTINGS TRANSPORT STUDY  

SciTech Connect (OSTI)

This is the fourth quarterly progress report for Year-3 of the ACTS Project. It includes a review of progress made in: (1) Flow Loop construction and development and (2) research tasks during the period of time between April 1, 2002 and June 30, 2002. This report presents a review of progress on the following specific tasks: (a) Design and development of an Advanced Cuttings Transport Facility (Task 3: Addition of a Cuttings Injection/Separation System), (b) Research project (Task 6): ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)''; (c) Research project (Task 9b): ''Study of Foam Flow Behavior Under EPET Conditions''; (d) Research project (Task 10): ''Study of Cuttings Transport with Aerated Mud Under Elevated Pressure and Temperature Conditions''; (e) Research on three instrumentation tasks to measure: Cuttings concentration and distribution in a flowing slurry (Task 11), Foam texture while transporting cuttings. (Task 12), and Viscosity of Foam under EPET (Task 9b); (f) Development of a Safety program for the ACTS Flow Loop. Progress on a comprehensive safety review of all flow-loop components and operational procedures. (Task 1S); (g) Activities towards technology transfer and developing contacts with Petroleum and service company members, and increasing the number of JIP members.

Troy Reed; Stefan Miska; Nicholas Takach; Kaveh Ashenayi; Mark Pickell; Len Volk; Mike Volk; Evren Ozbayoglu; Lei Zhou

2002-07-30T23:59:59.000Z

476

21st Annual Transportation  

E-Print Network [OSTI]

would cost more than $40 billion over next 20 years ·! If used alone, state gas tax would need more than levels #12;Benefits of new approach ·! Recognizes uncertainties of transportation revenue forecasts arise ·! Provides greatest regional benefit if current revenue forecasts prove true #12;MHSIS Maps

Minnesota, University of

477

E-Print Network 3.0 - advected reactive scalars Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

through... reactive scalars that are initially distinct, ... Source: Crimaldi, John P. - Department of Civil, Environmental, and Architectural Engineering, University of...

478

35 Alternative Transportation Fuels in California ALTERNATIVE TRANSPORTATION  

E-Print Network [OSTI]

35 Alternative Transportation Fuels in California Chapter 4 ALTERNATIVE TRANSPORTATION FUELS IN CALIFORNIA INTRODUCTION The introduction of alternative fuels into California's transportation market has supply at low prices. But, with an uncertain long-term future for oil supplies and prices, alternative

479

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network [OSTI]

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

480

Abstract This paper reviews specific issues and challenges in reactive power management within the competitive electricity  

E-Print Network [OSTI]

, points out various deficiencies in the reactive power procurement in the US markets and provides recommendations for, and lists a number of challenges in the reactive power supply and usage area. Basically of the same type as active power or active energy. Many reactive power management issues concern the static

Gross, George

Note: This page contains sample records for the topic "reactive geochemical transport" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Microsoft PowerPoint - Proceedings Cover Sheets  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrological, Geochemical, Geophysical and Geomechanical Hydrological, Geochemical, Geophysical and Geomechanical Modeling for CO 2 Sequestration Larry R. Myer Earth Sciences Division Lawrence Berkeley National Laboratory Fifth Annual Conference on Carbon Capture and Sequestration May 10, 2006 LM-01L Numerical Modeling is One Important Component of the Toolbox * CCS technology requires multiple tools * Level of detail/sophistication is application dependent - R&D - Technology development/deployment - Regulation LM-01L Categories of Models * Forward models -Input properties, output "behavior" -Hydrological, geophysical modeling * Coupled models -Reactive geochemical transport models -Hydro-geomechanical models * Inverse models -Input measurements of behavior, output properties -Geophysical, hydro-geomechanical models * Integration of models

482

Essays on Transportation Safety, Economics, and Policy  

E-Print Network [OSTI]

2002. TCF, 2000, Widening the Transportation Divide: HowGovernor Davis Transportation Plan Leaves Transit-People Stranded, Transportation Choices Forum, 2000.

Scholl, Patricia Lynn

2011-01-01T23:59:59.000Z

483

Transportation of Nuclear Materials | Department of Energy  

Energy Savers [EERE]

Transportation of Nuclear Materials Transportation of Nuclear Materials GC-52 provides legal advice to DOE on legal and regulatory requirements and standards for transportation of...

484

Transportation and Program Management Services | Department of...  

Office of Environmental Management (EM)

and Program Management Services Transportation and Program Management Services Overview of Secured Transportation Services (STS) Transportation and Program Management Services More...

485

We're All Transportation Planners  

E-Print Network [OSTI]

of facts that global warming is real, that transportationCalifornia Transportation Center, with help is a majorresearch on compelling transportation can both reduce the

Curry, Melanie

2006-01-01T23:59:59.000Z

486

VTPI-Transportation Statistics | Open Energy Information  

Open Energy Info (EERE)

Area: Transportation Resource Type: Dataset Website: www.vtpi.orgtdmtdm80.htm Cost: Free VTPI-Transportation Statistics Screenshot References: VTPI-Transportation Statistics1...

487

Downstream Emissions Trading for Transport  

Science Journals Connector (OSTI)

This chapter addresses the issue of downstream emission trading within the transport sector. It is argued that emission trading may be relevant in this sector, and ... regarding international transport, it is arg...

Charles Raux

2011-01-01T23:59:59.000Z

488

Integrated transportation system design optimization  

E-Print Network [OSTI]

Traditionally, the design of a transportation system has focused on either the vehicle design or the network flow, assuming the other as given. However, to define a system level architecture for a transportation system, ...

Taylor, Christine P. (Christine Pia), 1979-

2007-01-01T23:59:59.000Z

489

Transforming California's Freight Transport System  

E-Print Network [OSTI]

Transforming California's Freight Transport System Policy Forum on the Role of Freight Transport Standard #12;2050 Vision- Key Conceptual Outcomes Technology Transformation Early Action Cleaner Combustion Multiple Strategies Federal Action Efficiency Gains Energy Transformation 9 #12;Further reduce localized

California at Davis, University of

490

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure Modes from Reactive Dynamics Simulations  

Science Journals Connector (OSTI)

Development of a ReaxFF Reactive Force Field for Ettringite and Study of its Mechanical Failure Modes from Reactive Dynamics Simulations ... Ettringite is a hexacalcium aluminate trisulfate hydrate mineral that forms during Portland cement hydration. ... Here, we report on the development of this ReaxFF force field and on its validation and application using reactive molecular dynamics (RMD) simulations to characterize and understand the elastic, plastic, and failure response of ettringite at the atomic scale. ...

Lianchi Liu; Andres Jaramillo-Botero; William A. Goddard; III; Huai Sun

2012-03-13T23:59:59.000Z

491

Engine combustion control at low loads via fuel reactivity stratification  

DOE Patents [OSTI]

A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

2014-10-07T23:59:59.000Z

492

Reactive Membrane Barriers for Containment of Subsurface Contamination  

SciTech Connect (OSTI)

The overall goal of this project was to develop reactive membrane barriers--a new and flexible technique to contain and stabilize subsurface contaminants. Polymer membranes will leak once a contaminant is able to diffuse through the membrane. By incorporating a reactive material in the polymer, however, the contaminant is degraded or immobilized within the membrane. These processes increase the time for contaminants to breakthrough the barrier (i.e. the lag time) and can dramatically extend barrier lifetimes. In this work, reactive barrier membranes containing zero-valent iron (Fe{sup 0}) or crystalline silicotitanate (CST) were developed to prevent the migration of chlorinated solvents and cesium-137, respectively. These studies were complemented by the development of models quantifying the leakage/kill time of reactive membranes and describing the behavior of products produced via the reactions within the membranes. First, poly(vinyl alcohol) (PVA) membranes containing Fe{sup 0} and CST were prepared and tested. Although PVA is not useful in practical applications, it allows experiments to be performed rapidly and the results to be compared to theory. For copper ions (Cu{sup 2+}) and carbon tetrachloride, the barrier was effective, increasing the time to breakthrough over 300 times. Even better performance was expected, and the percentage of the iron used in the reaction with the contaminants was determined. For cesium, the CST laden membranes increased lag times more than 30 times, and performed better than theoretical predictions. A modified theory was developed for ion exchangers in reactive membranes to explain this result. With the PVA membranes, the effect of a groundwater matrix on barrier performance was tested. Using Hanford groundwater, the performance of Fe{sup 0} barriers decreased compared to solutions containing a pH buffer and high levels of chloride (both of which promote iron reactivity). For the CST bearing membrane, performance improved by a factor of three when groundwater was used in place of deionized water. The performance of high density polyethylene (HDPE) membranes containing Fe{sup 0} was then evaluating using carbon tetrachloride as the target contaminant. Only with a hydrophilic additive (glycerol), was the iron able to extend lag times. Lag times were increased by a factor of 15, but only 2-3% of the iron was used, likely due to formation of oxide precipitates on the iron surface, which slowed the reaction. With thicker membranes and lower carbon tetrachloride concentrations, it is expected that performance will improve. Previous models for reactive membranes were also extended. The lag time is a measurement of when the barrier is breached, but contaminants do slowly leak through prior to the lag time. Thus, two parameters, the leakage and the kill time, were developed to determine when a certain amount of pollutant has escaped (the kill time) or when a given exposure (concentration x time) occurs (the leakage). Finally, a model was developed to explain the behavior of mobile reaction products in reactive barrier membranes. Although the goal of the technology is to avoid such products, it is important to be able to predict how these products will behave. Interestingly, calculations show that for any mobile reaction products, one half of the mass will diffuse into the containment area and one half will escape, assuming that the volumes of the containment area and the surrounding environment are much larger than the barrier membrane. These parameters/models will aid in the effective design of barrier membranes.

William A. Arnold; Edward L. Cussler

2007-02-26T23:59:59.000Z

493

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents [OSTI]

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

494

Kinetic azeotropy and design of reactive distillation columns  

SciTech Connect (OSTI)

The reactive fixed points in the distillation maps of a reactive distillation column (RDC) with kinetically controlled reactions are identified and their role in deciding the design feasibility has been elucidated. The fixed points at which both reaction and distillation vectors have zero magnitudes correspond to the equilibrium fixed point. It is known that the relative positions of these points for the rectifying and stripping sections determine the value of the minimum reflux ratio. However, apart from these fixed points, there are certain fixed points in the distillation map at which, though the reaction and distillation vectors have nonzero magnitudes, they nullify the effects of each other. These points correspond to the kinetic fixed points and have a special significance. Their positions have direct influence on the feasible product composition. A simple example of an ideal ternary system undergoing a reaction 2B {longleftrightarrow} A + c has been illustrated to show the importance of kinetic azeotropy in the design aspects of RDC.

Mahajani, S.M. [Monash Univ., Clayton, Victoria (Australia). Dept. of Chemical Engineering] [Monash Univ., Clayton, Victoria (Australia). Dept. of Chemical Engineering

1999-01-01T23:59:59.000Z

495

Sandia National Laboratories: Transportation Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sensors & Optical Diagnostics, Systems Analysis, Systems Engineering, Transportation Energy Sandia and industrial giant Caterpillar Inc. have signed their first...

496

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide  

SciTech Connect (OSTI)

Cerium oxide is a principal component in many heterogeneous catalytic processes. One of its key characteristics is the ability to provide or remove oxygen in chemical reactions. The different crystallographic faces of ceria present significantly different surface structures and compositions that may alter the catalytic reactivity. The structure and composition determine the number of coordination vacancies surrounding surface atoms, the availability of adsorption sites, the spacing between adsorption sites and the ability to remove O from the surface. To investigate the role of surface orientation on reactivity, CeO2 films were grown with two different orientations. CeO2(100) films were grown ex situ by pulsed laser deposition on Nb-doped SrTiO3(100). CeO2(111) films were grown in situ by thermal deposition of Ce metal onto Ru(0001) in an oxygen atmosphere. The chemical reactivity was characterized by the adsorption and decomposition of various molecules such as alcohols, aldehydes and organic acids. In general the CeO2(100) surface was found to be more active, i.e. molecules adsorbed more readily and reacted to form new products, especially on a fully oxidized substrate. However the CeO2(100) surface was less selective with a greater propensity to produce CO, CO2 and water as products. The differences in chemical reactivity are discussed in light of possible structural terminations of the two surfaces. Recently nanocubes and nano-octahedra have been synthesized that display CeO2(100) and CeO2(111) faces, respectively. These nanoparticles enable us to correlate reactions on high surface area model catalysts at atmospheric pressure with model single crystal films in a UHV environment.

Mullins, David R [ORNL] [ORNL; Albrecht, Peter M [ORNL] [ORNL; Calaza, Florencia C [ORNL] [ORNL

2013-01-01T23:59:59.000Z

497

Integrated Transportation System Design Optimization  

E-Print Network [OSTI]

Integrated Transportation System Design Optimization by Christine Taylor B.S. Cornell University by . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Professor Jaime Peraire Chairman, Department Graduate Committee #12;2 #12;Integrated Transportation System Abstract Traditionally, the design of a transportation system has focused on either the vehicle design

498

Transportation Center Seminar........ Patrice Marcotte  

E-Print Network [OSTI]

Transportation Center Seminar........ Patrice Marcotte Professor and Acting Director Computer on a Transportation Network With Rigid Capacities" Abstract: Static network equilibrium is a well transportation network, taking into account that users behave selfishly, i.e., only travel on shortest paths

Bustamante, Fabián E.

499

Council of University Transportation Centers  

E-Print Network [OSTI]

Council of University Transportation Centers 13th Anniversary CUTC Awards Banquet January 9, 2010 Omni Shoreham Hotel Washington, D.C. #12;Council of University Transportation Centers 13th Anniversary Awards Banquet Saturday, January 9, 2010 Welcome Stephen Albert, CUTCVice-President WesternTransportation

Nagurney, Anna

500

6 Ion Transport, Osmoregulation, and  

E-Print Network [OSTI]

177 6 Ion Transport, Osmoregulation, and Acid­Base Balance W.S. Marshall and M. Grosell CONTENTS I)............................................................................182 5. Skin and Opercular Membrane..................................................................................................183 2. Sea-Water Transport Mode -- Na+,K+-ATPase and Na+,K+, 2Cl­ Co-transport

Grosell, Martin