Sample records for reactive geochemical transport

  1. TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive geochemical Transport in Variable Saturated Geologic Media

    SciTech Connect (OSTI)

    Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas; Pruess, Karsten

    2004-05-24T23:59:59.000Z

    Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of mineral alteration in hydrothermal systems, waste disposal sites, acid mine drainage remediation, contaminant transport, and groundwater quality. A comprehensive non-isothermal multi-component reactive fluid flow and geochemical transport simulator, TOUGHREACT, has been developed. A wide range of subsurface thermo-physical-chemical processes is considered under various thermohydrological and geochemical conditions of pressure, temperature, water saturation, and ionic strength. The program can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The model can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions are considered, such as aqueous complexation, gas dissolution/exsolution, and cation exchange. Mineral dissolution/precipitation can proceed either subject to local equilibrium or kinetic conditions. Changes in porosity and permeability due to mineral dissolution and precipitation can be considered. Linear adsorption and decay can be included. For the purpose of future extensions, surface complexation by double layer model is coded in the program. Xu and Pruess (1998) developed a first version of a non-isothermal reactive geochemical transport model, TOUGHREACT, by introducing reactive geochemistry into the framework of the existing multi-phase fluid and heat flow code TOUGH2 (Pruess, 1991). Xu, Pruess, and their colleagues have applied the program to a variety of problems such as: (1) supergene copper enrichment (Xu et al, 2001), (2) caprock mineral alteration in a hydrothermal system (Xu and Pruess, 2001a), and (3) mineral trapping for CO{sub 2} disposal in deep saline aquifers (Xu et al, 2003b and 2004a). For modeling the coupled thermal, hydrological, and chemical processes during heater tests at proposed nuclear waste disposal site at Yucca Mountain (Nevada), Sonnenthal and Spycher (2000) and Spycher et al. (2003) enhanced TOUGHREACT on (1) high temperature geochemistry, (2) mineral reactive surface area calculations, and (3) porosity and permeability changes due to mineral alteration. On the other hand, Pruess et al. (1999) updated the TOUGH2 simulator to TOUGH2 V2. The present version of TOUGHREACT was developed by introducing the work of Sonnenthal and Spycher (2000) to the original work of Xu and Pruess (1998), and by replacing TOUGH2 (Pruess, 1991) by TOUGH2 V2 (Pruess et al, 1999). The TOUGHREACT program makes use of ''self-documenting'' features. It is distributed with a number of input data files for sample problems. Besides providing benchmarks for proper code installation, these can serve as self-teaching tutorial in the use of TOUGHREACT, and they provide templates to help jump-start new applications. The fluid and heat flow part of TOUGHREACT is derived from TOUGH2 V2, so in addition to the current manual, users must have manual of the TOUGH2 V2 (Pruess et al., 1999). The present version of TOUGHREACT provides the following different TOUGH2 fluid property or ''EOS'' (equation-of-state) modules: (1) EOS1 for water, or two waters with typical applications to hydrothermal problems, (2) EOS2 for multiphase mixtures of water and CO{sub 2} also with typical applications to hydrothermal problems, (3) EOS3 for multiphase mixtures of water and air with typical applications to vadose zone and nuclear waste disposal problems, (4) EOS4 that has the same capabilities as EOS3 but with vapor pressure lowering effects due to capillary pressure, (5) EOS9 for single phase water (Richards. equation) with typical applications to ambient reactive geochemical transport problems, (6) ECO2 for multiphase mixtures of water, CO{sub 2} and NaCl with typical applications to CO{sub 2} disposal in deep brine aquifers.

  2. Reactive geochemical transport simulation to study mineral trapping for CO2 disposal in deep saline arenaceous aquifers

    SciTech Connect (OSTI)

    Xu, Tianfu; Apps, John A.; Pruess, Karsten

    2002-04-01T23:59:59.000Z

    A reactive fluid flow and geochemical transport numerical model for evaluating long-term CO{sub 2} disposal in deep aquifers has been developed. Using this model, we performed a number of sensitivity simulations under CO{sub 2} injection conditions for a commonly encountered Gulf Coast sediment to analyze the impact of CO{sub 2} immobilization through carbonate precipitation. Geochemical models are needed because alteration of the predominant host rock aluminosilicate minerals is very slow and is not amenable to laboratory experiment under ambient deep-aquifer conditions. Under conditions considered in our simulations, CO{sub 2} trapping by secondary carbonate minerals such as calcite (CaCO{sub 3}), dolomite (CaMg(CO{sub 3}){sub 2}), siderite (FeCO{sub 3}), and dawsonite (NaAlCO{sub 3}(OH){sub 2}) could occur in the presence of high pressure CO{sub 2}. Variations in precipitation of secondary carbonate minerals strongly depend on rock mineral composition and their kinetic reaction rates. Using the data presented in this paper, CO{sub 2} mineral-trapping capability after 10,000 years is comparable to CO{sub 2} dissolution in pore waters (2-5 kg CO{sub 2} per cubic meter of formation). Under favorable conditions such as increase of the Mg-bearing mineral clinochlore (Mg{sub 5}Al{sub 2}Si{sub 3}O{sub 10}(OH){sub 8}) abundance, the capacity can be larger (10 kg CO{sub 2} per cubic meter of formation) due to increase of dolomite precipitation. Carbon dioxide-induced rock mineral alteration and the addition of CO{sub 2} mass as secondary carbonates to the solid matrix results in decreases in porosity. A maximum 3% porosity decrease is obtained in our simulations. A small decrease in porosity may result in a significant decrease in permeability. The numerical simulations described here provide useful insight into sequestration mechanisms, and their controlling conditions and parameters.

  3. TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media, V1.2.1

    SciTech Connect (OSTI)

    Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas; Pruess, Karsten

    2008-09-29T23:59:59.000Z

    Coupled modeling of subsurface multiphase fluid and heat flow, solute transport, and chemical reactions can be applied to many geologic systems and environmental problems, including geothermal systems, diagenetic and weathering processes, subsurface waste disposal, acid mine drainage remediation, contaminant transport, and groundwater quality. TOUGHREACT has been developed as a comprehensive non-isothermal multi-component reactive fluid flow and geochemical transport simulator to investigate these and other problems. A number of subsurface thermo-physical-chemical processes are considered under various thermohydrological and geochemical conditions of pressure, temperature, water saturation, and ionic strength. TOUGHREACT can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The code can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions are considered, such as aqueous complexation, gas dissolution/exsolution, and cation exchange. Mineral dissolution/precipitation can take place subject to either local equilibrium or kinetic controls, with coupling to changes in porosity and permeability and capillary pressure in unsaturated systems. Chemical components can also be treated by linear adsorption and radioactive decay. The first version of the non-isothermal reactive geochemical transport code TOUGHREACT was developed (Xu and Pruess, 1998) by introducing reactive geochemistry into the framework of the existing multi-phase fluid and heat flow code TOUGH2 (Pruess, 1991). TOUGHREACT was further enhanced with the addition of (1) treatment of mineral-water-gas reactive-transport under boiling conditions, (2) an improved HKF activity model for aqueous species, (3) gas species diffusion coefficients calculated as a function of pressure, temperature, and molecular properties, (4) mineral reactive surface area formulations for fractured and porous media, and (5) porosity, permeability, and capillary pressure changes owing to mineral precipitation/dissolution (Sonnenthal et al., 1998, 2000, 2001; Spycher et al., 2003a). Subsequently, TOUGH2 V2 was released with additional EOS modules and features (Pruess et al., 1999). The present version of TOUGHREACT includes all of the previous extensions to the original version, along with the replacement of the original TOUGH2 (Pruess, 1991) by TOUGH2 V2 (Pruess et al., 1999). TOUGHREACT has been applied to a wide variety of problems, some of which are included as examples, such as: (1) Supergene copper enrichment (Xu et al., 2001); (2) Mineral alteration in hydrothermal systems (Xu and Pruess, 2001a; Xu et al., 2004b; Dobson et al., 2004); (3) Mineral trapping for CO{sub 2} disposal in deep saline aquifers (Xu et al., 2003b and 2004a); (4) Coupled thermal, hydrological, and chemical processes in boiling unsaturated tuff for the proposed nuclear waste emplacement site at Yucca Mountain, Nevada (Sonnenthal et al., 1998, 2001; Sonnenthal and Spycher, 2000; Spycher et al., 2003a, b; Xu et al., 2001); (5) Modeling of mineral precipitation/dissolution in plug-flow and fracture-flow experiments under boiling conditions (Dobson et al., 2003); (6) Calcite precipitation in the vadose zone as a function of net infiltration (Xu et al., 2003); and (7) Stable isotope fractionation in unsaturated zone pore water and vapor (Singleton et al., 2004). The TOUGHREACT program makes use of 'self-documenting' features. It is distributed with a number of input data files for sample problems. Besides providing benchmarks for proper code installation, these can serve as a self-teaching tutorial in the use of TOUGHREACT, and they provide templates to help jump-start new applications. The fluid and heat flow part of TOUGHREACT is derived from TOUGH2 V2, so in addition to the current manual, users must have the manual of the TOUGH2 V2 (Pruess et al., 1999). The present version of TOUGHREACT provides the following TOUGH2 fluid property or 'EOS' (equation-of-state) modules: (1) EOS1 for

  4. TOURGHREACT: A Simulation Program for Non-isothermal MultiphaseReactive Geochemical Transport in Variably Saturated GeologicMedia

    SciTech Connect (OSTI)

    Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas; Pruess, Karsten

    2004-12-07T23:59:59.000Z

    TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media. The program was written in Fortran 77 and developed by introducing reactive geochemistry into the multiphase fluid and heat flow simulator TOUGH2. A variety of subsurface thermo-physical-chemical processes are considered under a wide range of conditions of pressure, temperature, water saturation, ionic strength, and pH and Eh. Interactions between mineral assemblages and fluids can occur under local equilibrium or kinetic rates. The gas phase can be chemically active. Precipitation and dissolution reactions can change formation porosity and permeability. The program can be applied to many geologic systems and environmental problems, including geothermal systems, diagenetic and weathering processes, subsurface waste disposal, acid mine drainage remediation, contaminant transport, and groundwater quality. Here we present two examples to illustrate applicability of the program: (1) injectivity effects of mineral scaling in a fractured geothermal reservoir and (2) CO2 disposal in a deep saline aquifer.

  5. Benchmarking a Visual-Basic based multi-component one-dimensional reactive transport modeling tool

    E-Print Network [OSTI]

    Clement, Prabhakar

    Benchmarking a Visual-Basic based multi-component one-dimensional reactive transport modeling tool of a comprehensive numerical modeling tool, RT1D, which can be used for simulating biochemical and geochemical, and it does not require any additional software tools. The code can be easily adapted by others for simulating

  6. A smoothed particle hydrodynamics model for reactive transport...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A smoothed particle hydrodynamics model for reactive transport and mineral precipitation in porous and fractured porous media. A smoothed particle hydrodynamics model for reactive...

  7. quantifying and Predicting Reactive Transport

    SciTech Connect (OSTI)

    Peter C. Burns, Department of Civil Engineering and Geological Sciences, University of Notre Dame

    2009-12-04T23:59:59.000Z

    This project was led by Dr. Jiamin Wan at Lawrence Berkeley National Laboratory. Peter Burns provided expertise in uranium mineralogy and in identification of uranium minerals in test materials. Dr. Wan conducted column tests regarding uranium transport at LBNL, and samples of the resulting columns were sent to Dr. Burns for analysis. Samples were analyzed for uranium mineralogy by X-ray powder diffraction and by scanning electron microscopy, and results were provided to Dr. Wan for inclusion in the modeling effort. Full details of the project can be found in Dr. Wan's final reports for the associated effort at LBNL.

  8. STOMP-ECKEChem: An Engineering Perspective on Reactive Transport in Geologic Media

    SciTech Connect (OSTI)

    White, Mark D.; Fang, Yilin

    2012-04-04T23:59:59.000Z

    ECKEChem (Equilibrium, Conservation, Kinetic Equation Chemistry) is a reactive transport module for the STOMP suite of multifluid subsurface flow and transport simulators that was developed from an engineering perspective. STOMP comprises a suite of operational modes that are distinguished by the solved coupled conservation equations with capabilities for a variety of subsurface applications (e.g., environmental remediation and stewardship, geologic sequestration of greenhouse gases, gas hydrate production, and oil shale production). The ECKEChem module was designed to provide integrated reactive transport capabilities across the suite of STOMP simulator operational modes. The initial application for the ECKEChem module was in the simulation of the mineralization reactions that occurred with the injection of supercritical carbon dioxide into deep Columbia River basalt formations, where it was implemented in the STOMP-CO2 simulator. The STOMP-ECKEChem solution approach to modeling reactive transport in multifluid geologic media is founded on an engineering perspective: (1) sequential non-iterative coupling between the flow and reactive transport is sufficient, (2) reactive transport can be modeled by operator splitting with local geochemistry and global transport, (3) geochemistry can be expressed as a system of coupled nonlinear equilibrium, conservation and kinetic equations, (4) a limited number of kinetic equation forms are used in geochemical practice. This chapter describes the conceptual approach to converting a geochemical reaction network into a series of equilibrium, conservation and kinetic equations, the implementation of ECKEChem in STOMP, the numerical solution approach, and a demonstration of the simulator on a complex application involving desorption of uranium from contaminated field-textured sediments.

  9. ALUMINOSILICATE-COATED SILICA SAND FOR REACTIVE TRANSPORT EXPERIMENTS

    E-Print Network [OSTI]

    Flury, Markus

    ALUMINOSILICATE-COATED SILICA SAND FOR REACTIVE TRANSPORT EXPERIMENTS By JORGE ANTONIO JEREZ transport experiments; Dr. Barbara Williams and Jason Shira from University of Idaho for providing access-COATED SILICA SAND FOR REACTIVE TRANSPORT EXPERIMENTS Abstract by Jorge Antonio Jerez Briones, Ph.D. Washington

  10. Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation

    SciTech Connect (OSTI)

    Wu, Y.; Ajo-Franklin, J.B.; Spycher, N.; Hubbard, S.S.; Zhang, G.; Williams, K.H.; Taylor, J.; Fujita, Y.; Smith, R.

    2011-07-15T23:59:59.000Z

    Ureolytically-driven calcium carbonate precipitation is the basis for a promising in-situ remediation method for sequestration of divalent radionuclide and trace metal ions. It has also been proposed for use in geotechnical engineering for soil strengthening applications. Monitoring the occurrence, spatial distribution, and temporal evolution of calcium carbonate precipitation in the subsurface is critical for evaluating the performance of this technology and for developing the predictive models needed for engineering application. In this study, we conducted laboratory column experiments using natural sediment and groundwater to evaluate the utility of geophysical (complex resistivity and seismic) sensing methods, dynamic synchrotron x-ray computed tomography (micro-CT), and reactive transport modeling for tracking ureolytically-driven calcium carbonate precipitation processes under site relevant conditions. Reactive transport modeling with TOUGHREACT successfully simulated the changes of the major chemical components during urea hydrolysis. Even at the relatively low level of urea hydrolysis observed in the experiments, the simulations predicted an enhanced calcium carbonate precipitation rate that was 3-4 times greater than the baseline level. Reactive transport modeling results, geophysical monitoring data and micro-CT imaging correlated well with reaction processes validated by geochemical data. In particular, increases in ionic strength of the pore fluid during urea hydrolysis predicted by geochemical modeling were successfully captured by electrical conductivity measurements and confirmed by geochemical data. The low level of urea hydrolysis and calcium carbonate precipitation suggested by the model and geochemical data was corroborated by minor changes in seismic P-wave velocity measurements and micro-CT imaging; the latter provided direct evidence of sparsely distributed calcium carbonate precipitation. Ion exchange processes promoted through NH{sub 4}{sup +} production during urea hydrolysis were incorporated in the model and captured critical changes in the major metal species. The electrical phase increases were potentially due to ion exchange processes that modified charge structure at mineral/water interfaces. Our study revealed the potential of geophysical monitoring for geochemical changes during urea hydrolysis and the advantages of combining multiple approaches to understand complex biogeochemical processes in the subsurface.

  11. Influence of Mg2+ on CaCO3 precipitation during subsurface reactive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    subsurface reactive transport in a homogeneous silicon-etched pore network. Abstract: Calcium carbonate (CaCO3) geochemical reactions exert a fundamental control on the...

  12. Multicomponent reactive transport modeling of uranium bioremediation field experiments

    SciTech Connect (OSTI)

    Fang, Yilin; Yabusaki, Steven B.; Morrison, Stan J.; Amonette, James E.; Long, Philip E.

    2009-10-15T23:59:59.000Z

    Biostimulation field experiments with acetate amendment are being performed at a former uranium mill tailings site in Rifle, Colorado, to investigate subsurface processes controlling in situ bioremediation of uranium-contaminated groundwater. An important part of the research is identifying and quantifying field-scale models of the principal terminal electron-accepting processes (TEAPs) during biostimulation and the consequent biogeochemical impacts to the subsurface receiving environment. Integrating abiotic chemistry with the microbially mediated TEAPs in the reaction network brings into play geochemical observations (e.g., pH, alkalinity, redox potential, major ions, and secondary minerals) that the reactive transport model must recognize. These additional constraints provide for a more systematic and mechanistic interpretation of the field behaviors during biostimulation. The reaction network specification developed for the 2002 biostimulation field experiment was successfully applied without additional calibration to the 2003 and 2007 field experiments. The robustness of the model specification is significant in that 1) the 2003 biostimulation field experiment was performed with 3 times higher acetate concentrations than the previous biostimulation in the same field plot (i.e., the 2002 experiment), and 2) the 2007 field experiment was performed in a new unperturbed plot on the same site. The biogeochemical reactive transport simulations accounted for four TEAPs, two distinct functional microbial populations, two pools of bioavailable Fe(III) minerals (iron oxides and phyllosilicate iron), uranium aqueous and surface complexation, mineral precipitation, and dissolution. The conceptual model for bioavailable iron reflects recent laboratory studies with sediments from the Old Rifle Uranium Mill Tailings Remedial Action (UMTRA) site that demonstrated that the bulk (~90%) of Fe(III) bioreduction is associated with the phyllosilicates rather than the iron oxides. The uranium reaction network includes a U(VI) surface complexation model based on laboratory studies with Old Rifle UMTRA sediments and aqueous complexation reactions that include ternary complexes (e.g., calcium-uranyl-carbonate). The bioreduced U(IV), Fe(II), and sulfide components produced during the experiments are strongly associated with the solid phases and may play an important role in long-term uranium immobilization.

  13. Modeling non-isothermal multiphase multi-species reactive chemical transport in geologic media

    SciTech Connect (OSTI)

    Tianfu Xu; Gerard, F.; Pruess, K.; Brimhall, G.

    1997-07-01T23:59:59.000Z

    The assessment of mineral deposits, the analysis of hydrothermal convection systems, the performance of radioactive, urban and industrial waste disposal, the study of groundwater pollution, and the understanding of natural groundwater quality patterns all require modeling tools that can consider both the transport of dissolved species as well as their interactions with solid (or other) phases in geologic media and engineered barriers. Here, a general multi-species reactive transport formulation has been developed, which is applicable to homogeneous and/or heterogeneous reactions that can proceed either subject to local equilibrium conditions or kinetic rates under non-isothermal multiphase flow conditions. Two numerical solution methods, the direct substitution approach (DSA) and sequential iteration approach (SIA) for solving the coupled complex subsurface thermo-physical-chemical processes, are described. An efficient sequential iteration approach, which solves transport of solutes and chemical reactions sequentially and iteratively, is proposed for the current reactive chemical transport computer code development. The coupled flow (water, vapor, air and heat) and solute transport equations are also solved sequentially. The existing multiphase flow code TOUGH2 and geochemical code EQ3/6 are used to implement this SIA. The flow chart of the coupled code TOUGH2-EQ3/6, required modifications of the existing codes and additional subroutines needed are presented.

  14. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-05-01T23:59:59.000Z

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  15. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-01-01T23:59:59.000Z

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  16. Geochemical factors affecting radionuclide transport through near and far fields at a Low-Level Waste Disposal Site

    SciTech Connect (OSTI)

    Kaplan, D.I.; Seme, R.J. [Pacific Northwest Lab., Richland, WA (United States); Piepkho, M.G. [Westinghouse Hanford Co., Richland, WA (United States)

    1995-03-01T23:59:59.000Z

    The concentration of low-level waste (LLW) contaminants in groundwater is determined by the amount of contaminant present in the solid waste, rate of release from the waste and surrounding barriers, and a number of geochemical processes including adsorption, desorption, diffusion, precipitation, and dissolution. To accurately predict radionuclide transport through the subsurface, it is essential that the important geochemical processes affecting radionuclide transport be identified and, perhaps more importantly, accurately quantified and described in a mathematically defensible manner.

  17. Field, Laboratory, and Modeling Study of Reactive Transport of

    E-Print Network [OSTI]

    University of New York, Flushing, New York 11367, Department of Marine Chemistry and Geochemistry, Woods Hole Bay, MA, shed light on coupled control of chemistry and hydrology on reactive transport), phosphate (5), and oxyanions of molybdenum (6) and uranium (7, 8) in aquifers. In addition

  18. Reactive Transport Modeling and Geophysical Monitoring of Bioclogging at Reservoir Scale

    E-Print Network [OSTI]

    Hubbard, Susan

    Reactive Transport Modeling and Geophysical Monitoring of Bioclogging at Reservoir Scale Vikranth scale using a combination of reactive transport modeling and geophysical imaging tools (EM & seismic Sacramento basin, California; the model well (Citizen Green #1) was characterized using sonic, electrical

  19. USER’S GUIDE of TOUGH2-EGS: A Coupled Geomechanical and Reactive Geochemical Simulator for Fluid and Heat Flow in Enhanced Geothermal Systems Version 1.0

    SciTech Connect (OSTI)

    Fakcharoenphol, Perapon [Colorado School of Mines; Xiong, Yi [Colorado School of Mines; Hu, Litang; Winterfeld, Philip H. [Colorado School of Mines; Xu, Tianfu [Lawrence Berkeley National Laboratory; Wu, Yu-Shu [Colorado School of Mines

    2013-05-01T23:59:59.000Z

    TOUGH2-EGS is a numerical simulation program coupling geomechanics and chemical reactions for fluid and heat flows in porous media and fractured reservoirs of enhanced geothermal systems. The simulator includes the fully-coupled geomechanical (THM) module, the fully-coupled geochemical (THC) module, and the sequentially coupled reactive geochemistry (THMC) module. The fully-coupled flow-geomechanics model is developed from the linear elastic theory for the thermo-poro-elastic system and is formulated with the mean normal stress as well as pore pressure and temperature. The chemical reaction is sequentially coupled after solution of flow equations, which provides the flow velocity and phase saturation for the solute transport calculation at each time step. In addition, reservoir rock properties, such as porosity and permeability, are subjected to change due to rock deformation and chemical reactions. The relationships between rock properties and geomechanical and chemical effects from poro-elasticity theories and empirical correlations are incorporated into the simulator. This report provides the user with detailed information on both mathematical models and instructions for using TOUGH2-EGS for THM, THC or THMC simulations. The mathematical models include the fluid and heat flow equations, geomechanical equation, reactive geochemistry equations, and discretization methods. Although TOUGH2-EGS has the capability for simulating fluid and heat flows coupled with both geomechanical and chemical effects, it is up to the users to select the specific coupling process, such as THM, THC, or THMC in a simulation. There are several example problems illustrating the applications of this program. These example problems are described in details and their input data are presented. The results demonstrate that this program can be used for field-scale geothermal reservoir simulation with fluid and heat flow, geomechanical effect, and chemical reaction in porous and fractured media.

  20. Analytical solutions for sequentially coupled one-dimensional reactive transport problems Part I: Mathematical derivations

    E-Print Network [OSTI]

    Clement, Prabhakar

    Analytical solutions for sequentially coupled one-dimensional reactive transport problems ­ Part I-species reactive transport equations coupled through sorption and sequential first-order reactions are commonly. Although researchers have been attempting to solve various forms of these reactive transport equations

  1. Toward Optimized Bioclogging and Biocementation Through Combining Advanced Geophysical Monitoring and Reactive Transport Modeling

    E-Print Network [OSTI]

    Hubbard, Susan

    and electrical techniques); (ii) developing and using a reactive transport simulator capable of predicting and Reactive Transport Modeling Approaches Christopher G Hubbard1 , Susan S. Hubbard1 , Yuxin Wu1 , Vikranth heterogeneities at the field scale. Optimization of these strategies requires advances in mechanistic reactive

  2. PFLOTRAN: Reactive Flow & Transport Code for Use on Laptops to Leadership-Class Supercomputers

    SciTech Connect (OSTI)

    Hammond, Glenn E.; Lichtner, Peter C.; Lu, Chuan; Mills, Richard T.

    2012-04-18T23:59:59.000Z

    PFLOTRAN, a next-generation reactive flow and transport code for modeling subsurface processes, has been designed from the ground up to run efficiently on machines ranging from leadership-class supercomputers to laptops. Based on an object-oriented design, the code is easily extensible to incorporate additional processes. It can interface seamlessly with Fortran 9X, C and C++ codes. Domain decomposition parallelism is employed, with the PETSc parallel framework used to manage parallel solvers, data structures and communication. Features of the code include a modular input file, implementation of high-performance I/O using parallel HDF5, ability to perform multiple realization simulations with multiple processors per realization in a seamless manner, and multiple modes for multiphase flow and multicomponent geochemical transport. Chemical reactions currently implemented in the code include homogeneous aqueous complexing reactions and heterogeneous mineral precipitation/dissolution, ion exchange, surface complexation and a multirate kinetic sorption model. PFLOTRAN has demonstrated petascale performance using 2{sup 17} processor cores with over 2 billion degrees of freedom. Accomplishments achieved to date include applications to the Hanford 300 Area and modeling CO{sub 2} sequestration in deep geologic formations.

  3. Variably Saturated Flow and Multicomponent Biogeochemical Reactive Transport Modeling of a Uranium Bioremediation Field Experiment

    SciTech Connect (OSTI)

    Yabusaki, Steven B.; Fang, Yilin; Williams, Kenneth H.; Murray, Christopher J.; Ward, Anderson L.; Dayvault, Richard; Waichler, Scott R.; Newcomer, Darrell R.; Spane, Frank A.; Long, Philip E.

    2011-11-01T23:59:59.000Z

    Field experiments at a former uranium mill tailings site have identified the potential for stimulating indigenous bacteria to catalyze the conversion of aqueous uranium in the +6 oxidation state to immobile solid-associated uranium in the +4 oxidation state. This effectively removes uranium from solution resulting in groundwater concentrations below actionable standards. Three-dimensional, coupled variably-saturated flow and biogeochemical reactive transport modeling of a 2008 in situ uranium bioremediation field experiment is used to better understand the interplay of transport rates and biogeochemical reaction rates that determine the location and magnitude of key reaction products. A comprehensive reaction network, developed largely through previous 1-D modeling studies, was used to simulate the impacts on uranium behavior of pulsed acetate amendment, seasonal water table variation, spatially-variable physical (hydraulic conductivity, porosity) and geochemical (reactive surface area) material properties. A principal challenge is the mechanistic representation of biologically-mediated terminal electron acceptor process (TEAP) reactions whose products significantly alter geochemical controls on uranium mobility through increases in pH, alkalinity, exchangeable cations, and highly reactive reduction products. In general, these simulations of the 2008 Big Rusty acetate biostimulation field experiment in Rifle, Colorado confirmed previously identified behaviors including (1) initial dominance by iron reducing bacteria that concomitantly reduce aqueous U(VI), (2) sulfate reducing bacteria that become dominant after {approx}30 days and outcompete iron reducers for the acetate electron donor, (3) continuing iron-reducer activity and U(VI) bioreduction during dominantly sulfate reducing conditions, and (4) lower apparent U(VI) removal from groundwater during dominantly sulfate reducing conditions. New knowledge on simultaneously active metal and sulfate reducers has been incorporated into the modeling. In this case, an initially small population of slow growing sulfate reducers is active from the initiation of biostimulation. Three-dimensional, variably saturated flow modeling was used to address impacts of a falling water table during acetate injection. These impacts included a significant reduction in aquifer saturated thickness and isolation of residual reactants and products, as well as unmitigated uranium, in the newly unsaturated vadose zone. High permeability sandy gravel structures resulted in locally high flow rates in the vicinity of injection wells that increased acetate dilution. In downgradient locations, these structures created preferential flow paths for acetate delivery that enhanced local zones of TEAP reactivity and subsidiary reactions. Conversely, smaller transport rates associated with the lower permeability lithofacies (e.g., fine) and vadose zone were shown to limit acetate access and reaction. Once accessed by acetate, however, these same zones limited subsequent acetate dilution and provided longer residence times that resulted in higher concentrations of TEAP products when terminal electron donors and acceptors were not limiting. Finally, facies-based porosity and reactive surface area variations were shown to affect aqueous uranium concentration distributions; however, the ranges were sufficiently small to preserve general trends. Large computer memory and high computational performance were required to simulate the detailed coupled process models for multiple biogeochemical components in highly resolved heterogeneous materials for the 110-day field experiment and 50 days of post-biostimulation behavior. In this case, a highly-scalable subsurface simulator operating on 128 processor cores for 12 hours was used to simulate each realization. An equivalent simulation without parallel processing would have taken 60 days, assuming sufficient memory was available.

  4. Analytical solutions for sequentially coupled one-dimensional reactive transport problems Part II: Special cases,

    E-Print Network [OSTI]

    Clement, Prabhakar

    Analytical solutions for sequentially coupled one-dimensional reactive transport problems ­ Part II solutions to multi-species reactive transport equations coupled through sorption and sequential first special-case transport scenarios involving zero initial condition, identical retardation factors and zero

  5. Transportation of a 40-year-old reactive mixed waste

    SciTech Connect (OSTI)

    Dietz, C.G. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1996-12-31T23:59:59.000Z

    Now a national landmark, Experimental Breeder Reactor-I was the worlds first nuclear reactor to produce a usable amount of commercial electricity in 1951. It is located on the Arco desert in Eastern Idaho at the Idaho National Engineering Laboratory (INEL). In 1955, the reactor experienced a cooling accident that resulted in core damage and a partial meltdown of the reactor, which left a serious cleanup challenge that had not been addressed until recently. The EBR-I reactor used liquid metal sodium-potassium (NaK) as a coolant because it is eutectic; that is, it remains a liquid at the lowest possible temperature and was a very effective coolant. NaK looks very much like mercury out of a thermometer. However, NaK is reactive and will burn in the presence of air (absorbing moisture from it) and is extremely reactive in direct contact with water, producing hydrogen. Furthermore, this highly reactive coolant was radioactively contaminated from the accident. Most of the radioactively contaminated NaK was processed and disposed of in 1955. However, approximately 180 gal of residual contaminated NaK remained because of the possibility it contained 10 1-gram foils of plutonium, which were in the reactor core at the time of the meltdown. This NaK was stored in four containers: two 55-gallon stainless steel transportation drums, one 60-gallon carbon steel container (used as a transfer vessel), and one 10-gallon carbon steel container (used to store radioactively contaminated water). This paper describes the transport of this waste from its temporary storage bunker to Argonne National Laboratory West for final treatment and preparation for disposal.

  6. Enhanced Land Subsidence and Seidment Dynamics in Galveston Bay- Implications for Geochemical Processes and Fate and Transport of Contaminants

    E-Print Network [OSTI]

    Almukaimi, Mohammad E

    2013-07-05T23:59:59.000Z

    ENHANCED LAND SUBSIDENCE AND SEDIMENT DYNAMICS IN GALVESTON BAY- IMPLICATIONS FOR GEOCHEMICAL PROCESSES AND FATE AND TRANSPORT OF CONTAMINANTS A Thesis by MOHAMMAD ALMUKAIMI Submitted to the Office of Graduate Studies of Texas A... August 2013 Major Subject: Oceanography Copyright 2013 Mohammad Almukaimi ii ABSTRACT Galveston Bay is the second largest estuary in the Gulf of Mexico. The bay?s watershed and shoreline contains one of the largest concentrations...

  7. Final Report Coupling in silico microbial models with reactive transport models to predict the fate of contaminants in the subsurface.

    SciTech Connect (OSTI)

    Lovley, Derek R.

    2012-10-31T23:59:59.000Z

    This project successfully accomplished its goal of coupling genome-scale metabolic models with hydrological and geochemical models to predict the activity of subsurface microorganisms during uranium bioremediation. Furthermore, it was demonstrated how this modeling approach can be used to develop new strategies to optimize bioremediation. The approach of coupling genome-scale metabolic models with reactive transport modeling is now well enough established that it has been adopted by other DOE investigators studying uranium bioremediation. Furthermore, the basic principles developed during our studies will be applicable to much broader investigations of microbial activities, not only for other types of bioremediation, but microbial metabolism in diversity of environments. This approach has the potential to make an important contribution to predicting the impact of environmental perturbations on the cycling of carbon and other biogeochemical cycles.

  8. Direct coupling of a genome-scale microbial in silico model and a groundwater reactive transport model

    SciTech Connect (OSTI)

    Fang, Yilin; Scheibe, Timothy D.; Mahadevan, Radhakrishnan; Garg, Srinath; Long, Philip E.; Lovley, Derek R.

    2011-02-28T23:59:59.000Z

    The activity of microorganisms often plays an important role in dynamic natural attenuation or engineered bioremediation of subsurface contaminants, such as chlorinated solvents, metals, and radionuclides. To evaluate and/or design bioremediated systems, quantitative reactive transport models are needed. State-of-the-art reactive transport models often ignore the microbial effects or simulate the microbial effects with static growth yield and constant reaction rate parameters over simulated conditions, while in reality microorganisms can dynamically modify their functionality (such as utilization of alternative respiratory pathways) in response to spatial and temporal variations in environmental conditions. Constraint-based genome-scale microbial in silico models, using genomic data and multiple-pathway reaction networks, have been shown to be able to simulate transient metabolism of some well studied microorganisms and identify growth rate, substrate uptake rates, and byproduct rates under different growth conditions. These rates can be identified and used to replace specific microbially-mediated reaction rates in a reactive transport model using local geochemical conditions as constraints. We previously demonstrated the potential utility of integrating a constraint based microbial metabolism model with a reactive transport simulator as applied to bioremediation of uranium in groundwater. However, that work relied on an indirect coupling approach that was effective for initial demonstration but may not be extensible to more complex problems that are of significant interest (e.g., communities of microbial species, multiple constraining variables). Here, we extend that work by presenting and demonstrating a method of directly integrating a reactive transport model (FORTRAN code) with constraint-based in silico models solved with IBM ILOG CPLEX linear optimizer base system (C library). The models were integrated with BABEL, a language interoperability tool. The modeling system is designed in such a way that constraint-based models targeting different microorganisms or competing organism communities can be easily plugged into the system. Constraint-based modeling is very costly given the size of a genome-scale reaction network. To save computation time, a binary tree is traversed to examine the concentration and solution pool generated during the simulation in order to decide whether the constraint-based model should be called. We also show preliminary results from the integrated model including a comparison of the direct and indirect coupling approaches.

  9. Chemically Reactive Working Fluids for the Capture and Transport...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Planar Optical Waveguide Coupler Transformers for High-Power Solar Enegy Collection and Transmission Chemically Reactive Working...

  10. Application of reactive transport modelling to growth and transport of microorganisms in the capillary fringe

    E-Print Network [OSTI]

    Hron, Pavel; Bastian, Peter; Gallert, Claudia; Winter, Josef; Ippisch, Olaf

    2014-01-01T23:59:59.000Z

    A multicomponent multiphase reactive transport simulator has been developed to facilitate the investigation of a large variety of phenomena in porous media including component transport, diffusion, microbiological growth and decay, cell attachment and detachment and phase exchange. The coupled problem is solved using operator splitting. This approach allows a flexible adaptation of the solution strategy to the concrete problem. Moreover, the individual submodels were optimised to be able to describe behaviour of Escherichia coli (HB101 K12 pGLO) in the capillary fringe in the presence or absence of dissolved organic carbon and oxygen under steady-state and flow conditions. Steady-state and flow through experiments in a Hele-Shaw cell, filled with quartz sand, were conducted to study eutrophic bacterial growth and transport in both saturated and unsaturated porous media. As E. coli cells can form the green fluorescent protein (GFP), the cell densities, calculated by evaluation of measured fluorescence intensit...

  11. Geochemical Characterization Using Geophysical Data and Markov Chain Monte Carolo methods: A Case Study at the South Oyster Bacterial Transport Site in Virginia

    SciTech Connect (OSTI)

    Chen, Jinsong; Hubbard, Susan; Rubin, Yoram; Murray, Chris; Roden, Eric; Majer, Ernest

    2003-11-18T23:59:59.000Z

    The spatial distribution of field-scale geochemical parameters, such as extractable Fe(II) and Fe(III), influences microbial processes and thus the efficacy of bioremediation. Because traditional characterization of those parameters is invasive and laborious, it is rarely performed sufficiently at the field-scale. Since both geochemical and geophysical parameters often correlate to some common physical properties (such as lithofacies), we investigated the utility of tomographic radar attenuation data for improving estimation of geochemical parameters using a Markov Chain Monte Carlo (MCMC) approach. The data used in this study included physical, geophysical, and geochemical measurements collected in and between several boreholes at the DOE South Oyster Bacterial Transport Site in Virginia. Results show that geophysical data, constrained by physical data, provided field-scale information about extractable Fe(II) and Fe(III) in a minimally invasive manner and with a resolution unparalleled by other geochemical characterization methods. This study presents our estimation framework for estimating Fe(II) and Fe(III), and its application to a specific site. Our hypothesis--that geochemical parameters and geophysical attributes can be linked through their mutual dependence on physical properties--should be applicable for estimating other geochemical parameters at other sites.

  12. Performance of a zerovalent iron reactive barrier for the treatment of arsenic in groundwater: Part 2. Geochemical modeling and solid phase studies

    SciTech Connect (OSTI)

    Beak, Douglas G.; Wilkin, Richard T.; (EPA)

    2009-06-12T23:59:59.000Z

    Arsenic uptake processes were evaluated in a zerovalent iron reactive barrier installed at a lead smelting facility using geochemical modeling, solid-phase analysis, and X-ray absorption spectroscopy techniques. Aqueous speciation of arsenic is expected to play a key role in directing arsenic uptake processes. Geochemical modeling reveals contrasting pH-dependencies for As(III) and As(V) precipitation. At the moderately alkaline pH conditions typically encountered in zerovalent iron reactive barriers, As(III) is unlikely to precipitate as an oxide or a sulfide phase. Conversely, increasing pH is expected to drive precipitation of metal arsenates including ferrous arsenate. Bacterially mediated sulfate reduction plays an important role in field installations of granular iron. Neoformed iron sulfides provide surfaces for adsorption of oxyanion and thioarsenic species of As(III) and As(V) and are expected to provide enhanced arsenic removal capacity. X-ray absorption near edge structure (XANES) spectra indicate that arsenic is sequestered in the solid phase as both As(III) and As(V) in coordination environments with O and S. Arsenic removal in the PRB probably results from several pathways, including adsorption to iron oxide and iron sulfide surfaces, and possible precipitation of ferrous arsenate. Corrosion of granular iron appears to result in some As(III) oxidation to As(V) as the proportion of As(V) to As(III) in the solid phase is greater compared to influent groundwater. As(0) was not detected in the PRB materials. These results are broadly comparable to laboratory based studies of arsenic removal by zerovalent iron, but additional complexity is revealed in the field environment, which is largely due to the influence of subsurface microbiota.

  13. Influence of calcite on uranium(VI) reactive transport in the groundwater–river mixing zone

    SciTech Connect (OSTI)

    Ma, Rui; Liu, Chongxuan; Greskowiak, Janek; Prommer, Henning; Zachara, John M.; Zheng, Chunmiao

    2014-01-23T23:59:59.000Z

    Calcite is an important mineral that can affect uranyl reactive transport in subsurface sediments. This study investigated the distribution of calcite and its influence on uranyl adsorption and reactive transport in the groundwater-river mixing zone at US Hanford 300A, Washington State. Simulations using a 2D reactive transport model under field-relevant hydrogeochemical conditions revealed a complex distribution of calcite concentration as a result of dynamic groundwater-river interactions. The calcite concentration distribution in turn affected the spatial and temporal changes in aqueous carbonate, calcium, and pH, which subsequently influenced U(VI) mobility and discharge rates into the river. The results implied that calcite distribution and its concentration dynamics is an important consideration for field characterization, monitoring, and reactive transport prediction.

  14. Reactive Transport Modeling of Natural Attenuation in Stormwater Bioretention Cells and Under Land Application of Wastewater 

    E-Print Network [OSTI]

    Zhang, Jingqiu

    2014-04-29T23:59:59.000Z

    hydrocarbon, nutrient, metals, and solids. Vegetation also plays an important role in reducing water volume, and removing nutrients and solutes from the contaminated soil. We used a reactive transport model MIN3P-THM to simulate the natural attenuation...

  15. FLOW AND REACTIVE TRANSPORT IN POROUS MEDIA INDUCED BY WELL INJECTION: SIMILARITY SOLUTION

    E-Print Network [OSTI]

    FLOW AND REACTIVE TRANSPORT IN POROUS MEDIA INDUCED BY WELL INJECTION: SIMILARITY SOLUTION C.J. VAN from laboratory batch experiments. Typical examples of isotherms are (see e.g. Freeze and Cherry [FC

  16. A transport based one-dimensional perturbation code for reactivity calculations in metal systems

    SciTech Connect (OSTI)

    Wenz, T.R.

    1995-02-01T23:59:59.000Z

    A one-dimensional reactivity calculation code is developed using first order perturbation theory. The reactivity equation is based on the multi-group transport equation using the discrete ordinates method for angular dependence. In addition to the first order perturbation approximations, the reactivity code uses only the isotropic scattering data, but cross section libraries with higher order scattering data can still be used with this code. The reactivity code obtains all the flux, cross section, and geometry data from the standard interface files created by ONEDANT, a discrete ordinates transport code. Comparisons between calculated and experimental reactivities were done with the central reactivity worth data for Lady Godiva, a bare uranium metal assembly. Good agreement is found for isotopes that do not violate the assumptions in the first order approximation. In general for cases where there are large discrepancies, the discretized cross section data is not accurately representing certain resonance regions that coincide with dominant flux groups in the Godiva assembly. Comparing reactivities calculated with first order perturbation theory and a straight {Delta}k/k calculation shows agreement within 10% indicating the perturbation of the calculated fluxes is small enough for first order perturbation theory to be applicable in the modeled system. Computation time comparisons between reactivities calculated with first order perturbation theory and straight {Delta}k/k calculations indicate considerable time can be saved performing a calculation with a perturbation code particularly as the complexity of the modeled problems increase.

  17. Pore scale modeling of reactive transport involved in geologic CO2 sequestration

    SciTech Connect (OSTI)

    Kang, Qinjin [Los Alamos National Laboratory; Lichtner, Peter C [Los Alamos National Laboratory; Viswanathan, Hari S [Los Alamos National Laboratory; Abdel-fattah, Amr I [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    We apply a multi-component reactive transport lattice Boltzmann model developed in previolls studies to modeling the injection of a C02 saturated brine into various porous media structures at temperature T=25 and 80 C. The porous media are originally consisted of calcite. A chemical system consisting of Na+, Ca2+, Mg2+, H+, CO2(aq), and CI-is considered. The fluid flow, advection and diHusion of aqueous species, homogeneous reactions occurring in the bulk fluid, as weB as the dissolution of calcite and precipitation of dolomite are simulated at the pore scale. The effects of porous media structure on reactive transport are investigated. The results are compared with continuum scale modeling and the agreement and discrepancy are discussed. This work may shed some light on the fundamental physics occurring at the pore scale for reactive transport involved in geologic C02 sequestration.

  18. INEEL Subregional Conceptual Model Report Volume 2: Summary of Existing Knowledge of Geochemical Influences on the Fate and Transport of Contaminants in the Subsurface at the INEEL

    SciTech Connect (OSTI)

    Paul L. Wichlacz; Robert C. Starr; Brennon Orr

    2003-09-01T23:59:59.000Z

    This document summarizes previous descriptions of geochemical system conceptual models for the vadose zone and groundwater zone (aquifer) beneath the Idaho National Engineering and Environmental Laboratory (INEEL). The primary focus is on groundwater because contaminants derived from wastes disposed at INEEL are present in groundwater, groundwater provides a pathway for potential migration to receptors, and because geochemical characteristics in and processes in the aquifer can substantially affect the movement, attenuation, and toxicity of contaminants. The secondary emphasis is perched water bodies in the vadose zone. Perched water eventually reaches the regional groundwater system, and thus processes that affect contaminants in the perched water bodies are important relative to the migration of contaminants into groundwater. Similarly, processes that affect solutes during transport from nearsurface disposal facilities downward through the vadose zone to the aquifer are relevant. Sediments in the vadose zone can affect both water and solute transport by restricting the downward migration of water sufficiently that a perched water body forms, and by retarding solute migration via ion exchange. Geochemical conceptual models have been prepared by a variety of researchers for different purposes. They have been published in documents prepared by INEEL contractors, the United States Geological Survey (USGS), academic researchers, and others. The documents themselves are INEEL and USGS reports, and articles in technical journals. The documents reviewed were selected from citation lists generated by searching the INEEL Technical Library, the INEEL Environmental Restoration Optical Imaging System, and the ISI Web of Science databases. The citation lists were generated using the keywords ground water, groundwater, chemistry, geochemistry, contaminant, INEL, INEEL, and Idaho. In addition, a list of USGS documents that pertain to the INEEL was obtained and manually searched. The documents that appeared to be the most pertinent were selected from further review. These documents are tabulated in the citation list. This report summarizes existing geochemical conceptual models, but does not attempt to generate a new conceptual model or select the ''right'' model. This document is organized as follows. Geochemical models are described in general in Section 2. Geochemical processes that control the transport and fate of contaminants introduced into groundwater are described in Section 3. The natural geochemistry of the Eastern Snake River Plain Aquifer (SRPA) is described in Section 4. The effect of waste disposal on the INEEL subsurface is described in Section 5. The geochemical behavior of the major contaminants is described in Section 6. Section 7 describes the site-specific geochemical models developed for various INEEL facilities.

  19. Reactive transport of trace elements and isotopes in the Eutaw coastal plain aquifer, Alabama

    E-Print Network [OSTI]

    Wang, Yang

    geochemistry, mineralogy, and numerical modeling techniques to study the reactive transport of heavy metals ground- water geochemistry. Because the possible biogeochemical reactions in regional aquifers are quite suggest that that elevated metal concentrations may be derived from bacterial iron and manganese reduction

  20. Simulation of reactive transport of uranium(VI) in groundwater with variable chemical conditions

    E-Print Network [OSTI]

    stored in poorly designed facilities or where it has been leached from U mill tailings [USDOE, 1996Simulation of reactive transport of uranium(VI) in groundwater with variable chemical conditions alluvial aquifer beneath a former U(VI) mill located near Naturita, CO, was simulated using a surface

  1. A model for reactive porous transport during re-wetting of hardened concrete

    E-Print Network [OSTI]

    Stockie, John

    A model for reactive porous transport during re-wetting of hardened concrete Michael Chapwanya residing in the porous concrete matrix. The main hypothesis in this model is that the reaction product hydration; Porous media; Reaction-diffusion equations; Vari- able porosity. 1. Introduction Concrete

  2. PARALLEL PROCESSING OF THREE-DIMENSIONAL FIELD-SCALE REACTIVE TRANSPORT APPLICATIONS

    E-Print Network [OSTI]

    Boyer, Edmond

    BRGM (French Geological Survey), Water Department, Groundwater and Geochemistry Modeling 3, Avenue C for the mixed hybrid finite element kernel. Com- putations of the reaction step are performed using a newly- tions. 1. INTRODUCTION The shape and scope of multi-component reactive transport models changed dramati

  3. Application of a data assimilation method via an ensemble Kalman filter to reactive urea hydrolysis transport modeling

    SciTech Connect (OSTI)

    Juxiu Tong; Bill X. Hu; Hai Huang; Luanjin Guo; Jinzhong Yang

    2014-03-01T23:59:59.000Z

    With growing importance of water resources in the world, remediations of anthropogenic contaminations due to reactive solute transport become even more important. A good understanding of reactive rate parameters such as kinetic parameters is the key to accurately predicting reactive solute transport processes and designing corresponding remediation schemes. For modeling reactive solute transport, it is very difficult to estimate chemical reaction rate parameters due to complex processes of chemical reactions and limited available data. To find a method to get the reactive rate parameters for the reactive urea hydrolysis transport modeling and obtain more accurate prediction for the chemical concentrations, we developed a data assimilation method based on an ensemble Kalman filter (EnKF) method to calibrate reactive rate parameters for modeling urea hydrolysis transport in a synthetic one-dimensional column at laboratory scale and to update modeling prediction. We applied a constrained EnKF method to pose constraints to the updated reactive rate parameters and the predicted solute concentrations based on their physical meanings after the data assimilation calibration. From the study results we concluded that we could efficiently improve the chemical reactive rate parameters with the data assimilation method via the EnKF, and at the same time we could improve solute concentration prediction. The more data we assimilated, the more accurate the reactive rate parameters and concentration prediction. The filter divergence problem was also solved in this study.

  4. REVIEW AND ANALYSIS Research Activities at U.S. Government Agencies in Subsurface Reactive Transport Modeling

    E-Print Network [OSTI]

    All T. Cygan; Caroline T. Stevens; Robert W. Puls; Steven B. Yabusaki; Robert D; David R. Turner

    Subsurface reactive transport modeling may be defi ned as the use of mathematical models to simulate the fate and transport of dissolved species and particulates in groundwater as these species are transported through porous media and react with each other, with mineral surfaces, and with microbes associated with the porous media matrix. This type of modeling has evolved over the last 30 yr from a specialized research topic involving a dozen or so practitioners (with often large stacks of computer punch cards) to a common offi ce tool found today on the personal computer (and occasional supercomputer) of many environmental chemists, geochemists, and soil scientists. The devel-

  5. acid transporter hpat1: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  6. acid transporters eaat-1: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  7. acid transporters ntcp: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  8. acid transporter lat1: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  9. Coupling lattice Boltzmann and continuum equations for flow and reactive transport in porous media.

    SciTech Connect (OSTI)

    Coon, Ethan [Los Alamos National Laboratory; Porter, Mark L. [Los Alamos National Laboratory; Kang, Qinjun [Los Alamos National Laboratory; Moulton, John D. [Los Alamos National Laboratory; Lichtner, Peter C. [Los Alamos National Laboratory

    2012-06-18T23:59:59.000Z

    In spatially and temporally localized instances, capturing sub-reservoir scale information is necessary. Capturing sub-reservoir scale information everywhere is neither necessary, nor computationally possible. The lattice Boltzmann Method for solving pore-scale systems. At the pore-scale, LBM provides an extremely scalable, efficient way of solving Navier-Stokes equations on complex geometries. Coupling pore-scale and continuum scale systems via domain decomposition. By leveraging the interpolations implied by pore-scale and continuum scale discretizations, overlapping Schwartz domain decomposition is used to ensure continuity of pressure and flux. This approach is demonstrated on a fractured medium, in which Navier-Stokes equations are solved within the fracture while Darcy's equation is solved away from the fracture Coupling reactive transport to pore-scale flow simulators allows hybrid approaches to be extended to solve multi-scale reactive transport.

  10. Semianalytical Solutions of Radioactive or Reactive Tracer Transport in Layered Fractured Media

    SciTech Connect (OSTI)

    G.J. Moridis; G. S. Bodvarsson

    2001-10-01T23:59:59.000Z

    In this paper, semianalytical solutions are developed for the problem of transport of radioactive or reactive tracers (solutes or colloids) through a layered system of heterogeneous fractured media with misaligned fractures. The tracer transport equations in the matrix account for (a) diffusion, (b) surface diffusion (for solutes only), (c) mass transfer between the mobile and immobile water fractions, (d) linear kinetic or equilibrium physical, chemical, or combined solute sorption or colloid filtration, and (e) radioactive decay or first order chemical reactions. Any number of radioactive decay daughter products (or products of a linear, first-order reaction chain) can be tracked. The tracer-transport equations in the fractures account for the same processes, in addition to advection and hydrodynamic dispersion. Additionally, the colloid transport equations account for straining and velocity adjustments related to the colloidal size. The solutions, which are analytical in the Laplace space, are numerically inverted to provide the solution in time and can accommodate any number of fractured and/or porous layers. The solutions are verified using analytical solutions for limiting cases of solute and colloid transport through fractured and porous media. The effect of important parameters on the transport of {sup 3}H, {sup 237}Np and {sup 239}Pu (and its daughters) is investigated in several test problems involving layered geological systems of varying complexity. {sup 239}Pu colloid transport problems in multilayered systems indicate significant colloid accumulations at straining interfaces but much faster transport of the colloid than the corresponding strongly sorbing solute species.

  11. acid transporter slc10a5: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRANSPORT AND GEOCHEMICAL EVOLUTION OF ACID MINE DRAINAGE THROUGH Environmental Management and Restoration Websites Summary: SIMULATING TRANSPORT AND GEOCHEMICAL...

  12. Coupled Geochemical and Hydrological Processes Governing the Fate and Transport of Radionuclides and Toxic Metals Beneath the Hanford Tank Farms

    SciTech Connect (OSTI)

    Scott Fendorf; Phil Jardine

    2006-07-21T23:59:59.000Z

    The goal of this research was to provide an improved understanding and predictive capability of coupled hydrological and geochemical mechanisms that are responsible for the accelerated migration and immobilization of radionuclides and toxic metals in the badose zone beneath the Hanford Tank Farms.

  13. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect (OSTI)

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01T23:59:59.000Z

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  14. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    SciTech Connect (OSTI)

    Zheng, L.; Samper, J.; Montenegro, L.; Major, J.C.

    2008-10-15T23:59:59.000Z

    During the construction and operational phases of a high-level radioactive waste (HLW) repository constructed in a clay formation, ventilation of underground drifts will cause desaturation and oxidation of the rock. The Ventilation Experiment (VE) was performed in a 1.3 m diameter unlined horizontal microtunnel on Opalinus clay at Mont Terri underground research laboratory in Switzerland to evaluate the impact of desaturation on rock properties. A multiphase flow and reactive transport model of VE is presented here. The model accounts for liquid, vapor and air flow, evaporation/condensation and multicomponent reactive solute transport with kinetic dissolution of pyrite and siderite and local-equilibrium dissolution/precipitation of calcite, ferrihydrite, dolomite, gypsum and quartz. Model results reproduce measured vapor flow, liquid pressure and hydrochemical data and capture the trends of measured relative humidities, although such data are slightly overestimated near the rock interface due to uncertainties in the turbulence factor. Rock desaturation allows oxygen to diffuse into the rock and triggers pyrite oxidation, dissolution of calcite and siderite, precipitation of ferrihydrite, dolomite and gypsum and cation exchange. pH in the unsaturated rock varies from 7.8 to 8 and is buffered by calcite. Computed changes in the porosity and the permeability of Opalinus clay in the unsaturated zone caused by oxidation and mineral dissolution/precipitation are smaller than 5%. Therefore, rock properties are not expected to be affected significantly by ventilation of underground drifts during construction and operational phases of a HLW repository in clay.

  15. Assessment of Controlling Processes for Field-Scale Uranium Reactive Transport under Highly Transient Flow Conditions

    SciTech Connect (OSTI)

    Ma, Rui; Zheng, Chunmiao; Liu, Chongxuan; Greskowiak, Janek; Prommer, Henning; Zachara, John M.

    2014-02-13T23:59:59.000Z

    This paper presents the results of a comprehensive model-based analysis of a uranium tracer test conducted at the U.S Department of Energy Hanford 300 Area (300A) IFRC site. A three-dimensional multi-component reactive transport model was employed to assess the key factors and processes that control the field-scale uranium reactive transport. Taking into consideration of relevant physical and chemical processes, the selected conceptual/numerical model replicates the spatial and temporal variations of the observed U(VI) concentrations reasonably well in spite of the highly complex field conditions. A sensitivity analysis was performed to interrogate the relative importance of various processes and factors for reactive transport of U(VI) at the field-scale. The results indicate that multi-rate U(VI) sorption/desorption, U(VI) surface complexation reactions, and initial U(VI) concentrations were the most important processes and factors controlling U(VI) migration. On the other hand, cation exchange reactions, the choice of the surface complexation model, and dual-domain mass transfer processes, which were previously identified to be important in laboratory experiments, played less important roles under the field-scale experimental condition at the 300A site. However, the model simulations also revealed that the groundwater chemistry was relatively stable during the uranium tracer experiment and therefore presumably not dynamic enough to appropriately assess the effects of ion exchange reaction and the choice of surface complexation models on U(VI) sorption and desorption. Furthermore, it also showed that the field experimental duration (16 days) was not sufficiently long to precisely assess the role of a majority of the sorption sites that were accessed by slow kinetic processes within the dual domain model. The sensitivity analysis revealed the crucial role of the intraborehole flow that occurred within the long-screened monitoring wells and thus significantly affected both field-scale measurements and simulated U(VI) concentrations as a combined effect of aquifer heterogeneity and highly dynamic flow conditions. Overall, this study, which provides one of the few detailed and highly data-constrained uranium transport simulations, highlights the difference in controlling processes between laboratory and field scale that prevent a simple direct upscaling of laboratory-scale models.

  16. Reactive geochemical transport simulation to study mineral trapping for CO2 disposal in deep saline arenaceous aquifers

    E-Print Network [OSTI]

    Xu, Tianfu; Apps, John A.; Pruess, Karsten

    2002-01-01T23:59:59.000Z

    vol. 11, p. Eberl, D. and Hower, J. , 1976, Kinetics ofincrease (Eberl and Hower, 1976). Purported field evidence

  17. TOUGHREACT: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic M

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not FoundInformation DOEInformation Summary Big* - 'TOUGHREACT: A Simulation

  18. Semi-Analytical Solutions of One-Dimensional Multispecies Reactive Transport in a Permeable Reactive Barrier-Aquifer System

    E-Print Network [OSTI]

    Mieles, John Michael

    2012-07-16T23:59:59.000Z

    At many sites it has become apparent that most chemicals of concern (COCs) in groundwater are persistent and not effectively treated by conventional remediation methods. In recent years, the permeable reactive barrier (PRB) technology has proven...

  19. Modeling hydrology and reactive transport in roads: The effect of cracks, the edge, and contaminant properties

    SciTech Connect (OSTI)

    Apul, Defne S. [Department of Civil Engineering, University of Toledo, 2801 W. Bancroft St., Mail Stop 307, Toledo, OH 43606 (United States)], E-mail: Defne.apul@utoledo.edu; Gardner, Kevin H. [Environmental Research Group, Department of Civil Engineering, 35 Colovos Road, Durham, NH 03824 (United States)], E-mail: Kevin.gardner@unh.edu; Eighmy, T. Taylor [Environmental Research Group, Department of Civil Engineering, 35 Colovos Road, Durham, NH 03824 (United States)], E-mail: Taylor.eighmy@unh.edu

    2007-07-01T23:59:59.000Z

    The goal of this research was to provide a tool for regulators to evaluate the groundwater contamination from the use of virgin and secondary materials in road construction. A finite element model, HYDRUS2D, was used to evaluate generic scenarios for secondary material use in base layers. Use of generic model results for particular applications was demonstrated through a steel slag example. The hydrology and reactive transport of contaminants were modeled in a two-dimensional cross section of a road. Model simulations showed that in an intact pavement, lateral velocities from the edge towards the centerline may transport contaminants in the base layer. The dominant transport mechanisms are advection closer to the edge and diffusion closer to the centerline. A shoulder joint in the pavement allows 0.03 to 0.45 m{sup 3}/day of infiltration per meter of joint length as a function of the base and subgrade hydrology and the rain intensity. Scenario simulations showed that salts in the base layer of pavements are depleted by 99% in the first 20 years, whereas the metals may not reach the groundwater in 20 years at any significant concentrations if the pavement is built on adsorbing soils.

  20. Upscaling of Long-Term U(VI) Desorption from Pore Scale Kinetics to Field-Scale Reactive Transport Models

    SciTech Connect (OSTI)

    Steefel, Carl I.; Li Li; Davis, J.A.; Curtis, G.P.; Honeyman, B.D.; Kent, D.B.; Kohler, M.; Rodriguez, D.R.; Johnson, K.J.; Miller, A.

    2006-06-01T23:59:59.000Z

    The focus of the project is the development of scientifically defensible approaches for upscaling reactive transport models (RTM) through a detailed understanding of U(VI) desorption across several spatial scales: bench-, intermediate-, and field-scales. The central hypothesis of the project is that the development of this methodology will lead to a scientifically defensible approach for conceptual model development for multicomponent RTM at contaminated DOE sites, leading to predictive transport simulations with reduced uncertainty.

  1. REACTIVE TRANSPORT MODELING USING A PARALLEL FULLY-COUPLED SIMULATOR BASED ON PRECONDITIONED JACOBIAN-FREE NEWTON-KRYLOV

    SciTech Connect (OSTI)

    Luanjing Guo; Chuan Lu; Hai Huang; Derek R. Gaston

    2012-06-01T23:59:59.000Z

    Systems of multicomponent reactive transport in porous media that are large, highly nonlinear, and tightly coupled due to complex nonlinear reactions and strong solution-media interactions are often described by a system of coupled nonlinear partial differential algebraic equations (PDAEs). A preconditioned Jacobian-Free Newton-Krylov (JFNK) solution approach is applied to solve the PDAEs in a fully coupled, fully implicit manner. The advantage of the JFNK method is that it avoids explicitly computing and storing the Jacobian matrix during Newton nonlinear iterations for computational efficiency considerations. This solution approach is also enhanced by physics-based blocking preconditioning and multigrid algorithm for efficient inversion of preconditioners. Based on the solution approach, we have developed a reactive transport simulator named RAT. Numerical results are presented to demonstrate the efficiency and massive scalability of the simulator for reactive transport problems involving strong solution-mineral interactions and fast kinetics. It has been applied to study the highly nonlinearly coupled reactive transport system of a promising in situ environmental remediation that involves urea hydrolysis and calcium carbonate precipitation.

  2. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Lindquist, W Brent

    2009-03-03T23:59:59.000Z

    The overall goal of the project was to bridge the gap between our knowledge of small-scale geochemical reaction rates and reaction rates meaningful for modeling transport at core scales. The working hypothesis was that reaction rates, determined from laboratory measurements based upon reactions typically conducted in well mixed batch reactors using pulverized reactive media may be significantly changed in in situ porous media flow due to rock microstructure heterogeneity. Specifically we hypothesized that, generally, reactive mineral surfaces are not uniformly accessible to reactive fluids due to the random deposition of mineral grains and to the variation in flow rates within a pore network. Expected bulk reaction rates would therefore have to be correctly up-scaled to reflect such heterogeneity. The specific objective was to develop a computational tool that integrates existing measurement capabilities with pore-scale network models of fluid flow and reactive transport. The existing measurement capabilities to be integrated consisted of (a) pore space morphology, (b) rock mineralogy, and (c) geochemical reaction rates. The objective was accomplished by: (1) characterizing sedimentary sandstone rock morphology using X-ray computed microtomography, (2) mapping rock mineralogy using back-scattered electron microscopy (BSE), X-ray dispersive spectroscopy (EDX) and CMT, (3) characterizing pore-accessible reactive mineral surface area, and (4) creating network models to model acidic CO{sub 2} saturated brine injection into the sandstone rock samples.

  3. Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport

    SciTech Connect (OSTI)

    Chorover, Jon; Perdrial, Nico; Mueller, Karl; Strepka, Caleb; Oà ƒ  ¢Ã ‚  € à ‚  ™ Day, Peggy; Rivera, Nelson; Um, Wooyong; Chang, Hyun-Shik; Steefel, Carl; Thompson, Aaron

    2012-11-05T23:59:59.000Z

    Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided thorough characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, partial pressure of carbon dioxide, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions. In this final report, we provide detailed descriptions of our results from this three-year study, completed in 2012 following a one-year no cost extension.

  4. An investigation of the effect of pore scale flow on average geochemical reaction rates using direct numerical simulation

    SciTech Connect (OSTI)

    Rafa, S. Molins; Trebotich, D.; Steefel, C. I.; Shen, C.

    2012-02-01T23:59:59.000Z

    The scale-dependence of geochemical reaction rates hinders their use in continuum scale models intended for the interpretation and prediction of chemical fate and transport in subsurface environments such as those considered for geologic sequestration of CO{sub 2}. Processes that take place at the pore scale, especially those involving mass transport limitations to reactive surfaces, may contribute to the discrepancy commonly observed between laboratory-determined and continuum-scale or field rates. Here, the dependence of mineral dissolution rates on the pore structure of the porous media is investigated by means of pore scale modeling of flow and multicomponent reactive transport. The pore scale model is comprised of high performance simulation tools and algorithms for incompressible flow and conservative transport combined with a general-purpose multicomponent geochemical reaction code. The model performs direct numerical simulation of reactive transport based on an operator-splitting approach to coupling transport and reactions. The approach is validated with a Poiseuille flow single-pore experiment and verified with an equivalent 1D continuum-scale model of a capillary tube packed with calcite spheres. Using the case of calcite dissolution as an example, the high resolution model is used to demonstrate that non-uniformity in the flow field at the pore scale has the effect of decreasing the overall reactivity of the system, even when systems with identical reactive surface area are considered. The effect becomes more pronounced as the heterogeneity of the reactive grain packing increases, particularly where the flow slows sufficiently such that the solution approaches equilibrium locally and the average rate becomes transport-limited.

  5. HBH-GEOCHEM-GEOPHY

    Energy Science and Technology Software Center (OSTI)

    003015WKSTN00 Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software   

  6. A general-purpose, geochemical reservoir simulator

    SciTech Connect (OSTI)

    Liu, X.; Ortoleva, P.

    1996-12-31T23:59:59.000Z

    A geochemical simulator for the analysis of coupled reaction and transport processes is presented. The simulator is based on the numerical solution of the equations of coupled multi-phase fluid flow, species transport, energy balance and rock/fluid reactions. It also accounts for the effects of grain growth/dissolution and the alteration of porosity and permeability due to mineral reactions. The simulator can be used to analyze core floods, single-well scenarios and multiple production/injection well systems on the reservoir scale. Additionally, the simulator provides two flow options: the Darcy law for fluid flow in porous media and the Brinkman law that subsumes both free and porous medium flows. The simulator was tested using core acidizing data and results were in good agreement with laboratory observations. The simulator was applied to analyze matrix acidizing treatments for a horizontal well. The evolution of the skin factor was predicted and the optimal volume of acid required to remove the near-wellbore damage was determined. Reactive fluid infiltration was shown to lead to reaction-front fingering under certain conditions. Viscosity contrast in multiphase flow could also result in viscous fingering. Examples in this study also address these nonlinear fingering phenomena. A waterflood on the reservoir scale was analyzed and simulation results show that scale formation during waterfloods can occur far beyond injection wells. Two cases of waste disposal by deep well injection were evaluated and our simulation results were consistent with field measured data.

  7. Groundwater Reactive Transport Models, 2012, 141-159 141 Fan Zhang, Gour-Tsyh (George) Yeh, Jack C. Parker and Xiaonan Shi (Eds)

    E-Print Network [OSTI]

    Mills, Richard

    performance computing, reactive transport, carbon sequestration, multiple realizations, multiphase flow transport at the Hanford 300 Area and CO2 sequestration in deep geologic formations. Keywords: High resources, such as CO2 sequestration in deep geologic formations, on the environment, and the efficacy

  8. Resonant charge-exchange involving excited helium atoms and reactive transport of local thermodynamic equilibrium helium plasma

    SciTech Connect (OSTI)

    Kosarim, A. V.; Smirnov, B. M. [Joint Institute for High Temperatures RAS, Moscow (Russian Federation); Laricchiuta, A. [CNR IMIP Bari, Bari (Italy); Capitelli, M. [CNR IMIP Bari, Bari (Italy); Department of Chemistry, University of Bari, Bari (Italy)

    2012-06-15T23:59:59.000Z

    The cross sections for charge-exchange and charge-transfer processes are evaluated for collisions of helium ions with parent-atoms in ground and excited states, with the principal quantum number n= 1-5, in the collision energy range from thermal up to 10 eV. Corresponding diffusion-type collision integrals are derived, and the role of 'abnormal' transport of electronically excited states on the reactive thermal conductivity of equilibrium helium plasma, at atmospheric pressure, estimated in the frame of a simplified approach.

  9. Final Project Report: Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport

    SciTech Connect (OSTI)

    Jon Chorover, University of Arizona; Peggy O' €  ™ Day, University of California, Merced; Karl Mueller, Penn State University; Wooyong Um, Pacific Northwest National Laboratory; Carl Steefel, Lawrence Berkeley National Laboratory

    2012-10-01T23:59:59.000Z

    Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided detailed characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, PCO2, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions.

  10. High Performance Computations of Subsurface Reactive Transport Processes at the Pore Scale

    E-Print Network [OSTI]

    such as carbon sequestration drive the geochemistry of porous media far from equilibrium in relatively short time in reservoir scale models. In the DOE Energy Frontier Research Center for Nanoscale Control of Geologic Carbon such as reactive surface area or reaction rates as they affect CO2 sequestration, with an objective of upscaling

  11. Upscaling reactive transport in porous media : laboratory visualization and stochastic models

    E-Print Network [OSTI]

    Oates, Peter M. (Peter Michael), 1977-

    2007-01-01T23:59:59.000Z

    Solute transport models are essential tools for understanding and forecasting chemical concentrations in groundwater. Advection-dispersion based models can adequately predict spatial averages of conservative solute ...

  12. The effects of gas-fluid-rock interactions on CO2 injection and storage: Insights from reactive transport modeling

    SciTech Connect (OSTI)

    Xiao, Y.; Xu, T.; Pruess, K.

    2008-10-15T23:59:59.000Z

    Possible means of reducing atmospheric CO{sub 2} emissions include injecting CO{sub 2} in petroleum reservoirs for Enhanced Oil Recovery or storing CO{sub 2} in deep saline aquifers. Large-scale injection of CO{sub 2} into subsurface reservoirs would induce a complex interplay of multiphase flow, capillary trapping, dissolution, diffusion, convection, and chemical reactions that may have significant impacts on both short-term injection performance and long-term fate of CO{sub 2} storage. Reactive Transport Modeling is a promising approach that can be used to predict the spatial and temporal evolution of injected CO{sub 2} and associated gas-fluid-rock interactions. This presentation will summarize recent advances in reactive transport modeling of CO{sub 2} storage and review key technical issues on (1) the short- and long-term behavior of injected CO{sub 2} in geological formations; (2) the role of reservoir mineral heterogeneity on injection performance and storage security; (3) the effect of gas mixtures (e.g., H{sub 2}S and SO{sub 2}) on CO{sub 2} storage; and (4) the physical and chemical processes during potential leakage of CO{sub 2} from the primary storage reservoir. Simulation results suggest that CO{sub 2} trapping capacity, rate, and impact on reservoir rocks depend on primary mineral composition and injecting gas mixtures. For example, models predict that the injection of CO{sub 2} alone or co-injection with H{sub 2}S in both sandstone and carbonate reservoirs lead to acidified zones and mineral dissolution adjacent to the injection well, and carbonate precipitation and mineral trapping away from the well. Co-injection of CO{sub 2} with H{sub 2}S and in particular with SO{sub 2} causes greater formation alteration and complex sulfur mineral (alunite, anhydrite, and pyrite) trapping, sometimes at a much faster rate than previously thought. The results from Reactive Transport Modeling provide valuable insights for analyzing and assessing the dynamic behaviors of injected CO{sub 2}, identifying and characterizing potential storage sites, and managing injection performance and reducing costs.

  13. A model for reactive porous transport during re-wetting of hardened concrete

    E-Print Network [OSTI]

    Chapwanya, Michael; Stockie, John M

    2008-01-01T23:59:59.000Z

    We develop a mathematical model that captures the transport of liquid water in hardened concrete, as well as the chemical reactions that occur between the infiltrating water and the residual calcium silicate compounds that reside in the porous concrete matrix. We investigate the hypothesis that the reaction product -- calcium silicate hydrate gel -- clogs the pores within the concrete thereby hindering water transport. Using numerical simulations, we determine the sensitivity of the model solution to changes in various physical parameters, and compare to experimental results available in the literature.

  14. Model-Based Analysis of the Role of Biological, Hydrological and Geochemical Factors Affecting Uranium Bioremediation

    SciTech Connect (OSTI)

    Zhao, Jiao; Scheibe, Timothy D.; Mahadevan, Radhakrishnan

    2011-01-24T23:59:59.000Z

    Uranium contamination is a serious concern at several sites motivating the development of novel treatment strategies such as the Geobacter-mediated reductive immobilization of uranium. However, this bioremediation strategy has not yet been optimized for the sustained uranium removal. While several reactive-transport models have been developed to represent Geobacter-mediated bioremediation of uranium, these models often lack the detailed quantitative description of the microbial process (e.g., biomass build-up in both groundwater and sediments, electron transport system, etc.) and the interaction between biogeochemical and hydrological process. In this study, a novel multi-scale model was developed by integrating our recent model on electron capacitance of Geobacter (Zhao et al., 2010) with a comprehensive simulator of coupled fluid flow, hydrologic transport, heat transfer, and biogeochemical reactions. This mechanistic reactive-transport model accurately reproduces the experimental data for the bioremediation of uranium with acetate amendment. We subsequently performed global sensitivity analysis with the reactive-transport model in order to identify the main sources of prediction uncertainty caused by synergistic effects of biological, geochemical, and hydrological processes. The proposed approach successfully captured significant contributing factors across time and space, thereby improving the structure and parameterization of the comprehensive reactive-transport model. The global sensitivity analysis also provides a potentially useful tool to evaluate uranium bioremediation strategy. The simulations suggest that under difficult environments (e.g., highly contaminated with U(VI) at a high migration rate of solutes), the efficiency of uranium removal can be improved by adding Geobacter species to the contaminated site (bioaugmentation) in conjunction with the addition of electron donor (biostimulation). The simulations also highlight the interactive effect of initial cell concentration and flow rate on U(VI) reduction.

  15. Exact PDF equations and closure approximations for advective-reactive transport

    SciTech Connect (OSTI)

    Venturi, D.; Tartakovsky, Daniel M.; Tartakovsky, Alexandre M.; Karniadakis, George E.

    2013-06-01T23:59:59.000Z

    Mathematical models of advection–reaction phenomena rely on advective flow velocity and (bio) chemical reaction rates that are notoriously random. By using functional integral methods, we derive exact evolution equations for the probability density function (PDF) of the state variables of the advection–reaction system in the presence of random transport velocity and random reaction rates with rather arbitrary distributions. These PDF equations are solved analytically for transport with deterministic flow velocity and a linear reaction rate represented mathematically by a heterog eneous and strongly-correlated random field. Our analytical solution is then used to investigate the accuracy and robustness of the recently proposed large-eddy diffusivity (LED) closure approximation [1]. We find that the solution to the LED-based PDF equation, which is exact for uncorrelated reaction rates, is accurate even in the presence of strong correlations and it provides an upper bound of predictive uncertainty.

  16. Stochastic modeling of transport and degradation of reactive solutes in heterogeneous aquifers

    E-Print Network [OSTI]

    Fadel, Ziad Joseph

    2006-08-16T23:59:59.000Z

    ? fate and transport have been reported in the literature (e.g. correlation between the sorption?s distribution coefficient Kd and the hydraulic conductivity [Allen-King et al., 1998; Robin et al., 1991]), whereas the connection between... KKKK hh + += -++- 1,,11,,1 , (23) where KA, KB, KC and KD (Eq. 24) represent the harmonic mean of the hydraulic conductivities related to the groundwater flow across two adjacent cells. Figure 8. Contour plot of a (100m x 10m) log...

  17. Nanoscale study of reactive transport in catalyst layer of proton exchange membrane fuel cells with precious and non-precious catalysts using lattice Boltzmann method

    E-Print Network [OSTI]

    Chen, Li; Kang, Qinjun; Holby, Edward F; Tao, Wen-Quan

    2014-01-01T23:59:59.000Z

    High-resolution porous structures of catalyst layer (CL) with multicomponent in proton exchange membrane fuel cells are reconstructed using a reconstruction method called quartet structure generation set. Characterization analyses of nanoscale structures are implemented including pore size distribution, specific area and phase connectivity. Pore-scale simulation methods based on the lattice Boltzmann method are developed and used to predict the macroscopic transport properties including effective diffusivity and proton conductivity. Nonuniform distributions of ionomer in CL generates more tortuous pathway for reactant transport and greatly reduces the effective diffusivity. Tortuosity of CL is much higher than conventional Bruggeman equation adopted. Knudsen diffusion plays a significant role in oxygen diffusion and significantly reduces the effective diffusivity. Reactive transport inside the CL is also investigated. Although the reactive surface area of non-precious metal catalyst (NPMC) CL is much higher t...

  18. TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media, V1.2.1

    E-Print Network [OSTI]

    Xu, Tianfu

    2008-01-01T23:59:59.000Z

    using the same kinetic expression as that for dissolution.directly from kinetic expressions. For equilibrium, thesechemical system. The kinetic rate expressions for mineral

  19. Final Report Coupled In Silico Microbial and Geochemical Reactive Transport Models: Extension to Multi-Organism Communities, Upscaling, and Experimental Validation

    SciTech Connect (OSTI)

    Lovley, Derek R.

    2014-03-05T23:59:59.000Z

    The project was highly successful in improving the understanding of physiological and ecological factors controlling the growth and interaction of subsurface microorganisms and in developing better strategies for in silico modeling of the interactions of subsurface microorganisms with other species and their environment.

  20. Pore Scale Modeling of the Reactive Transport of Chromium in the Cathode of a Solid Oxide Fuel Cell

    SciTech Connect (OSTI)

    Ryan, Emily M.; Tartakovsky, Alexandre M.; Recknagle, Kurtis P.; Khaleel, Mohammad A.; Amon, Cristina

    2011-01-01T23:59:59.000Z

    We present a pore scale model of a solid oxide fuel cell (SOFC) cathode. Volatile chromium species are known to migrate from the current collector of the SOFC into the cathode where over time they decrease the voltage output of the fuel cell. A pore scale model is used to investigate the reactive transport of chromium species in the cathode and to study the driving forces of chromium poisoning. A multi-scale modeling approach is proposed which uses a cell level model of the cathode, air channel and current collector to determine the boundary conditions for a pore scale model of a section of the cathode. The pore scale model uses a discrete representation of the cathode to explicitly model the surface reactions of oxygen and chromium with a cathode material. The pore scale model is used to study the reaction mechanisms of chromium by considering the effects of reaction rates, diffusion coefficients, chromium vaporization, and oxygen consumption on chromium’s deposition in the cathode. The study shows that chromium poisoning is most significantly affected by the chromium reaction rates in the cathode and that the reaction rates are a function of the local current density in the cathode.

  1. Assessment of Controlling Processes for Field-Scale Uranium Reactive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reactive transport model was employed to assess the key factors and processes that control the field-scale uranium reactive transport. Taking into consideration of relevant...

  2. A Many-Task Parallel Approach for Multiscale Simulations of Subsurface Flow and Reactive Transport

    SciTech Connect (OSTI)

    Scheibe, Timothy D.; Yang, Xiaofan; Schuchardt, Karen L.; Agarwal, Khushbu; Chase, Jared M.; Palmer, Bruce J.; Tartakovsky, Alexandre M.

    2014-12-16T23:59:59.000Z

    Continuum-scale models have long been used to study subsurface flow, transport, and reactions but lack the ability to resolve processes that are governed by pore-scale mixing. Recently, pore-scale models, which explicitly resolve individual pores and soil grains, have been developed to more accurately model pore-scale phenomena, particularly reaction processes that are controlled by local mixing. However, pore-scale models are prohibitively expensive for modeling application-scale domains. This motivates the use of a hybrid multiscale approach in which continuum- and pore-scale codes are coupled either hierarchically or concurrently within an overall simulation domain (time and space). This approach is naturally suited to an adaptive, loosely-coupled many-task methodology with three potential levels of concurrency. Each individual code (pore- and continuum-scale) can be implemented in parallel; multiple semi-independent instances of the pore-scale code are required at each time step providing a second level of concurrency; and Monte Carlo simulations of the overall system to represent uncertainty in material property distributions provide a third level of concurrency. We have developed a hybrid multiscale model of a mixing-controlled reaction in a porous medium wherein the reaction occurs only over a limited portion of the domain. Loose, minimally-invasive coupling of pre-existing parallel continuum- and pore-scale codes has been accomplished by an adaptive script-based workflow implemented in the Swift workflow system. We describe here the methods used to create the model system, adaptively control multiple coupled instances of pore- and continuum-scale simulations, and maximize the scalability of the overall system. We present results of numerical experiments conducted on NERSC supercomputing systems; our results demonstrate that loose many-task coupling provides a scalable solution for multiscale subsurface simulations with minimal overhead.

  3. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical...

  4. Characterizing Microbial Community and Geochemical Dynamics at...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microbial Community and Geochemical Dynamics at Hydrothermal Vents Using Osmotically Driven Continuous Fluid Characterizing Microbial Community and Geochemical Dynamics at...

  5. Thermodynamic Data for Geochemical Modeling of Carbonate Reactions Associated with CO2 Sequestration – Literature Review

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Cantrell, Kirk J.; McGrail, B. Peter

    2010-09-28T23:59:59.000Z

    Permanent storage of anthropogenic CO2 in deep geologic formations is being considered as a means to reduce the concentration of atmospheric CO2 and thus its contribution to global climate change. To ensure safe and effective geologic sequestration, numerous studies have been completed of the extent to which the CO2 migrates within geologic formations and what physical and geochemical changes occur in these formations when CO2 is injected. Sophisticated, computerized reservoir simulations are used as part of field site and laboratory CO2 sequestration studies. These simulations use coupled multiphase flow-reactive chemical transport models and/or standalone (i.e., no coupled fluid transport) geochemical models to calculate gas solubility, aqueous complexation, reduction/oxidation (redox), and/or mineral solubility reactions related to CO2 injection and sequestration. Thermodynamic data are critical inputs to modeling geochemical processes. The adequacy of thermodynamic data for carbonate compounds has been identified as an important data requirement for the successful application of these geochemical reaction models to CO2 sequestration. A review of thermodynamic data for CO2 gas and carbonate aqueous species and minerals present in published data compilations and databases used in geochemical reaction models was therefore completed. Published studies that describe mineralogical analyses from CO2 sequestration field and natural analogue sites and laboratory studies were also reviewed to identify specific carbonate minerals that are important to CO2 sequestration reactions and therefore require thermodynamic data. The results of the literature review indicated that an extensive thermodynamic database exists for CO2 and CH4 gases, carbonate aqueous species, and carbonate minerals. Values of ?fG298° and/or log Kr,298° are available for essentially all of these compounds. However, log Kr,T° or heat capacity values at temperatures above 298 K exist for less than approximately one-third of these compounds. Because the temperatures of host formations that will be used for CO2 injection and sequestration will be at tempera¬tures in the range of 50ºC to 100ºC or greater, the lack of high temperature thermodynamic values for key carbonate compounds especially minerals, will impact the accuracy of some modeling calculations.

  6. Solid phase evolution in the Biosphere 2 hillslope experiment as predicted by modeling of hydrologic and geochemical fluxes

    SciTech Connect (OSTI)

    Dontsova, K.; Steefel, C.I.; Desilets, S.; Thompson, A.; Chorover, J.

    2009-07-15T23:59:59.000Z

    A reactive transport geochemical modeling study was conducted to help predict the mineral transformations occurring over a ten year time-scale that are expected to impact soil hydraulic properties in the Biosphere 2 (B2) synthetic hillslope experiment. The modeling sought to predict the rate and extent of weathering of a granular basalt (selected for hillslope construction) as a function of climatic drivers, and to assess the feedback effects of such weathering processes on the hydraulic properties of the hillslope. Flow vectors were imported from HYDRUS into a reactive transport code, CrunchFlow2007, which was then used to model mineral weathering coupled to reactive solute transport. Associated particle size evolution was translated into changes in saturated hydraulic conductivity using Rosetta software. We found that flow characteristics, including velocity and saturation, strongly influenced the predicted extent of incongruent mineral weathering and neo-phase precipitation on the hillslope. Results were also highly sensitive to specific surface areas of the soil media, consistent with surface reaction controls on dissolution. Effects of fluid flow on weathering resulted in significant differences in the prediction of soil particle size distributions, which should feedback to alter hillslope hydraulic conductivities.

  7. Mulitdimensional reactive transport modeling of CO2 minreal sequestration in basalts at the Helllisheidi geothermal field, Iceland

    E-Print Network [OSTI]

    Aradottir, E.S.P.

    2013-01-01T23:59:59.000Z

    using the same kinetic expression as that for dissolution,used for the kinetic rate expression of different mineralsKinetic rates are a product of the rate constant and reactive surface area, according to the following general rate expression,

  8. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Peters, Catherine A

    2013-02-28T23:59:59.000Z

    Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of mineral accessible surface area, and should not be used in reactive transport modeling. Our work showed that reaction rates would be overestimated by three to five times.

  9. WINTERTemplate Geochemical mechanisms of

    E-Print Network [OSTI]

    Borissova, Daniela

    WINTERTemplate 01 Geochemical mechanisms of carbonate equilibria in the system CO2 -H2O-CaCO3 #12 dissolved in soil · Dissolution of CaCO3 · Precipitation of CaCO3 · Physicochemical precipitation (prevention of the CO2 outgassing) #12;07Dissolution of CaCO3 H2CO3 HCO3 - CO3 2- H+ CO3 2- + H+ HCO3 - HCO3

  10. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    SciTech Connect (OSTI)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08T23:59:59.000Z

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  11. Comparison of parameter sensitivities between a laboratory and field scale model of uranium transport in a dual domain, distributed-rate reactive system

    SciTech Connect (OSTI)

    Greskowiak, Janek; Prommer, Henning; Liu, Chongxuan; Post, Vincent; Ma, Rui; Zheng, Chunmiao; Zachara, John M.

    2010-09-16T23:59:59.000Z

    A laboratory-derived conceptual and numerical model for U(VI) transport at the Hanford 300A site, Washington, USA, was applied to a range of field-scale scenarios of different complexity to systematically evaluate model parameter sensitivities. The model, originally developed from column experiment data, included distributed-rate surface complexation kinetics of U(VI), aqueous speciation, and physical non-equilibrium transport processes. A rigorous parameter sensitivity analysis was carried out with respect to different state variables: concentrations, mass fluxes, total mass and spatial moments of dissolved U(VI) for laboratory systems, and various simulation scenarios that represented the field-scale characteristics at the Hanford 300A site. The field-scenarios accounted for transient groundwater flow and variable geochemical conditions driven by frequent water level changes of the nearby Columbia River. Simulations indicated that the transient conditions significantly affected U(VI) plume migration at the site. The parameter sensitivities were largely similar between the laboratory and field scale systems. Where differences existed, they were shown to result from differing degrees of U(VI) adsorption disequilibrium caused by hydraulic or hydrogeochemical conditions. Adorption disequilibrium was found to differ (i) between short duration peak flow events at the field scale and much longer flow events in the laboratory, (ii) for changing groundwater chemical compositions due to river water intrusion, and (iii) for different sampling locations at the field scale. Parameter sensitivities were also found to vary with respect to the different investigated state variables. An approach is demonstrated that elucidates the most important parameters of a laboratory-scale model that must constrained in both the laboratory and field for meaningful field application.

  12. Geochemical engineering and materials program plan

    SciTech Connect (OSTI)

    None

    1982-08-01T23:59:59.000Z

    The Department of Energy (DOE) was designated as lead agency in discharging the overall legislative mandate for federal R&D to assist the private sector in developing appropriate technology for exploiting geothermal energy resources. The Geochemical Engineering and Materials (GEM) Program was conceived, as part of DOE'S overall strategy, to address specific and plant-wide problems and uncertainties in the use of materials and in geochemical engineering. This program assists industry in the conduct of long-term,high-risk R&D needed to overcome the significant technical and economic GEM-related obstacles faced by developers and potential developers of this alternative energy source. The program focuses on: (1) Increasing the knowledge about the properties of materials and their performance under geothermal energy system conditions; (2) Developing and utilizing more reliable and/or cost-effective materials than previously available; and (3) Developing a greater understanding of and control over geochemical processes during fluid production and transport, energy conversion, and waste management. As a stand-alone program and as support to other DOE geothermal technology development programs, the GEM Program contributes to the feasibility of designing and operating efficient, reliable, and safe fluid handling and energy conversion systems.

  13. Langevin and Fokker-Planck analyses of inhibited molecular passing processes controlling transport and reactivity in nanoporous materials

    SciTech Connect (OSTI)

    Wang, Chi-Jen [Ames Laboratory; Ackerman, David M. [Ames Laboratory; Slowing, Igor I. [Ames Laboratory; Evans, James W. [Ames Laboratory

    2014-07-14T23:59:59.000Z

    Inhibited passing of reactant and product molecules within the linear pores of nanoporous catalytic materials strongly reduces reactivity. The dependence of the passing propensity P on pore radius R is analyzed utilizing Langevin dynamics to account for solvent effects. We find that P?(R?Rc)?, where passing is sterically blocked for R?Rc, with ? below the transition state theory value. Deeper insight comes from analysis of the corresponding high-dimensional Fokker-Planck equation, which facilitates an effective small-P approximation, and dimensional reduction enabling utilization of conformal mapping ideas. We analyze passing for spherical molecules and also assess the effect of rotational degrees of freedom for elongated molecules.

  14. TOUGHREACT Version 2.0: A simulator for subsurface reactive transport under non-isothermal multiphase flow conditions

    SciTech Connect (OSTI)

    Xu, T.; Spycher, N.; Sonnenthal, E.; Zhang, G.; Zheng, L.; Pruess, K.

    2010-08-01T23:59:59.000Z

    TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media, and was developed by introducing reactive chemistry into the multiphase fluid and heat flow simulator TOUGH2 V2. The first version of TOUGHREACT was released to the public through the U.S. Department of Energy's Energy Science and Technology Software Center (ESTSC) in August 2004. It is among the most frequently requested of ESTSC's codes. The code has been widely used for studies in CO{sub 2} geological sequestration, nuclear waste isolation, geothermal energy development, environmental remediation, and increasingly for petroleum applications. Over the past several years, many new capabilities have been developed, which were incorporated into Version 2 of TOUGHREACT. Major additions and improvements in Version 2 are discussed here, and two application examples are presented: (1) long-term fate of injected CO{sub 2} in a storage reservoir and (2) biogeochemical cycling of metals in mining-impacted lake sediments.

  15. Actualistic and Geochemical Modeling of Reservoir Rock, CO2 and Formation Fluid Interaction, Citronelle Oil Field, Alabama

    SciTech Connect (OSTI)

    Weislogel, Amy

    2014-01-31T23:59:59.000Z

    This report includes description of the Citronelle field study area and the work carried out in the project to characterize the geology and composition of reservoir rock material and to collect an analyze the geochemical composition of produced fluid waters from the Citronelle field. Reservoir rock samples collected from well bore core were made into thin-sections and assessed for textural properties, including pore types and porosity distribution. Compositional framework grain modal data were collected via point-counting, and grain and cement mineralogy was assessed using SEM-EDS. Geochemistry of fluid samples is described and modeled using PHREEQC. Composition of rock and produced fluids were used as inputs for TOUGHREACT reactive transport modeling, which determined the rock-fluid system was in disequilibrium.

  16. Mitochondrial reactive oxygen species and cancer

    E-Print Network [OSTI]

    Chandel, Navdeep S

    Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

  17. Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Home Agenda Awards Exhibitors Lodging Posters Registration Transportation Workshops Contact Us User Meeting Archives Users' Executive Committee Getting to Berkeley...

  18. Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Print Home Agenda Awards Exhibitors Lodging Posters Registration Transportation Workshops Contact Us User Meeting Archives Users' Executive Committee Getting to...

  19. An Example Uncertainty and Sensitivity Analysis for Reactive Transport at the Horonobe Site for Performance Assessment Calculations.

    SciTech Connect (OSTI)

    James, Scott; Cohan, Alexander [Sandia National Laboratories, Albuquerque, NM] [Sandia National Laboratories, Albuquerque, NM

    2005-08-01T23:59:59.000Z

    Given pre-existing Groundwater Modeling System (GMS) models of the Horonobe Underground Research Laboratory (URL) at both the regional and site scales, this work performs an example uncertainty analysis for performance assessment (PA) applications. After a general overview of uncertainty and sensitivity analysis techniques, the existing GMS site-scale model is converted to a PA model of the steady-state conditions expected after URL closure. This is done to examine the impact of uncertainty in site-specific data in conjunction with conceptual model uncertainty regarding the location of the Oomagari Fault. A heterogeneous stochastic model is developed and corresponding flow fields and particle tracks are calculated. In addition, a quantitative analysis of the ratio of dispersive to advective forces, the F-ratio, is performed for stochastic realizations of each conceptual model. Finally, a one-dimensional transport abstraction is modeled based on the particle path lengths and the materials through which each particle passes to yield breakthrough curves at the model boundary. All analyses indicate that accurate characterization of the Oomagari Fault with respect to both location and hydraulic conductivity is critical to PA calculations. This work defines and outlines typical uncertainty and sensitivity analysis procedures and demonstrates them with example PA calculations relevant to the Horonobe URL. Acknowledgement: This project was funded by Japan Nuclear Cycle Development Institute (JNC). This work was conducted jointly between Sandia National Laboratories (SNL) and JNC under a joint JNC/U.S. Department of Energy (DOE) work agreement. Performance assessment calculations were conducted and analyzed at SNL based on a preliminary model by Kashima, Quintessa, and JNC and include significant input from JNC to make sure the results are relevant for the Japanese nuclear waste program.

  20. Transportation

    E-Print Network [OSTI]

    Vinson, Steve

    2013-01-01T23:59:59.000Z

    Transportation in ancient Egypt entailed the use of boats2007 Land transport in Roman Egypt: A study of economics andDieter 1991 Building in Egypt: Pharaonic stone masonry. New

  1. System-Scale Model of Aquifer, Vadose Zone, and River Interactions for the Hanford 300 Area - Application to Uranium Reactive Transport

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Bacon, Diana H.; Freedman, Vicky L.; Parker, Kyle R.; Waichler, Scott R.; Williams, Mark D.

    2013-10-01T23:59:59.000Z

    This report represents a synthesis and integration of basic and applied research into a system-scale model of the Hanford 300 Area groundwater uranium plume, supported by the U.S. Department of Energy’s Richland Operations (DOE-RL) office. The report integrates research findings and data from DOE Office of Science (DOE-SC), Office of Environmental Management (DOE-EM), and DOE-RL projects, and from the site remediation and closure contractor, Washington Closure Hanford, LLC (WCH). The three-dimensional, system-scale model addresses water flow and reactive transport of uranium for the coupled vadose zone, unconfined aquifer, and Columbia River shoreline of the Hanford 300 Area. The system-scale model of the 300 Area was developed to be a decision-support tool to evaluate processes of the total system affecting the groundwater uranium plume. The model can also be used to address “what if” questions regarding different remediation endpoints, and to assist in design and evaluation of field remediation efforts. For example, the proposed cleanup plan for the Hanford 300 Area includes removal, treatment, and disposal of contaminated sediments from known waste sites, enhanced attenuation of uranium hot spots in the vadose and periodically rewetted zone, and continued monitoring of groundwater with institutional controls. Illustrative simulations of polyphosphate infiltration were performed to demonstrate the ability of the system-scale model to address these types of questions. The use of this model in conjunction with continued field monitoring is expected to provide a rigorous basis for developing operational strategies for field remediation and for defining defensible remediation endpoints.

  2. Reactive Maintenance

    Broader source: Energy.gov [DOE]

    Reactive maintenance follows a run-it-until-it-breaks strategy where no actions or efforts are taken to maintain equipment as intended by the manufacturer. Studies indicate this is still the predominant mode of maintenance for Federal facilities.

  3. Geochemical aspects of Michigan waterfloods

    SciTech Connect (OSTI)

    Tinker, G.E.; Barnes, P.F.; Olson, E.E.

    1983-10-01T23:59:59.000Z

    Waterflooding started in the carbonate oil reservoirs of the Northern Michigan Niagaran reef trend in 1978 with Shell's Chester 18 waterflood. Ten projects had been installed by the end of 1982 so that significant operational results are available for evaluation. The design and operating programs initially planned for the projects have been proven successful. Operating data from some of the more mature projects indicate that the understanding and proper management of the geochemical systems for these projects will be crucial to the success of the project. The intent of this paper is to present what is currently known and understood about the geochemistry of Michigan waterfloods. The geochemical system is here defined as all the various interconnected fluid environments constituting the project, namely the fresh water source system, the injection well system, the reservoir, the production wells, the production facilities, and the produced water disposal or reinjection facilities. Problem areas have been identified and corrective action has been taken or planned to counteract the detrimental effects of disruptions to the geochemical system. These upsets are brought about by injection of water into the reservoir where an equilibrium condition had existed between the formation fluids and the rock.

  4. Spatial and Geochemical Spatial and Geochemical Heterogeneity Impacts on Iron Biomineralization and Uranium Sequestration

    SciTech Connect (OSTI)

    Scott Fendorf; Shawn Benner; Jim Neiss; Colleen Hansel; Peter Nico; Chris Francis; Phil Jardine

    2004-03-17T23:59:59.000Z

    Bioreductive transformations of iron (hydr)oxides are a critically important processes controlling the fate and transport of contaminants in soil and aquifer systems. Heterogeneity arising from both chemical and physical conditions will lead to various biomineralization products of iron oxides and will additionally alter reactions controlling the partitioning of hazardous elements such as uranium. We are presently exploring chemical and mineralogical transformations within physically complex material having a range of pore-size distribution and chemical environments. Here we discuss the impact of calcium on the reactive transport of uranium and the spatial heterogeneity in iron hydroxide mineralization and concomitant uranium reduction along a diffusive flow path.

  5. Influence of Mg2+ on CaCO3 precipitation during subsurface reactive transport in a homogeneous silicon-etched pore network

    SciTech Connect (OSTI)

    Boyd, Victoria; Yoon, Hongkyu; Zhang, Changyong; Oostrom, Martinus; Hess, Nancy J.; Fouke, Bruce W.; Valocchi, Albert J.; Werth, Charles J.

    2014-05-19T23:59:59.000Z

    Calcium carbonate (CaCO3) geochemical reactions exert a fundamental control on the evolution of porosity and permeability in shallow-to-deep subsurface siliciclastic and limestone rock reservoirs. As a result, these carbonate water-rock interactions play a critically important role in research on groundwater remediation, geological carbon sequestration, and hydrocarbon exploration. A study was undertaken to determine the effects of Mg2+ concentration on CaCO3 crystal morphology, precipitation rate, and porosity occlusion under flow and mixing conditions similar to those in subsurface aquifers.

  6. Characterization of materials for a reactive transport model validation experiment: Interim report on the caisson experiment. Yucca Mountain Site Characterization Project

    SciTech Connect (OSTI)

    Siegel, M.D.; Cheng, W.C. [Sandia National Labs., Albuquerque, NM (United States); Ward, D.B.; Bryan, C.R. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Earth and Planetary Sciences

    1995-08-01T23:59:59.000Z

    Models used in performance assessment and site characterization activities related to nuclear waste disposal rely on simplified representations of solute/rock interactions, hydrologic flow field and the material properties of the rock layers surrounding the repository. A crucial element in the design of these models is the validity of these simplifying assumptions. An intermediate-scale experiment is being carried out at the Experimental Engineered Test Facility at Los Alamos Laboratory by the Los Alamos and Sandia National Laboratories to develop a strategy to validate key geochemical and hydrological assumptions in performance assessment models used by the Yucca Mountain Site Characterization Project.

  7. Pore-scale simulation of microbial growth using a genome-scale metabolic model: Implications for Darcy-scale reactive transport

    SciTech Connect (OSTI)

    Tartakovsky, Guzel D.; Tartakovsky, Alexandre M.; Scheibe, Timothy D.; Fang, Yilin; Mahadevan, Radhakrishnan; Lovley, Derek R.

    2013-09-07T23:59:59.000Z

    Recent advances in microbiology have enabled the quantitative simulation of microbial metabolism and growth based on genome-scale characterization of metabolic pathways and fluxes. We have incorporated a genome-scale metabolic model of the iron-reducing bacteria Geobacter sulfurreducens into a pore-scale simulation of microbial growth based on coupling of iron reduction to oxidation of a soluble electron donor (acetate). In our model, fluid flow and solute transport is governed by a combination of the Navier-Stokes and advection-diffusion-reaction equations. Microbial growth occurs only on the surface of soil grains where solid-phase mineral iron oxides are available. Mass fluxes of chemical species associated with microbial growth are described by the genome-scale microbial model, implemented using a constraint-based metabolic model, and provide the Robin-type boundary condition for the advection-diffusion equation at soil grain surfaces. Conventional models of microbially-mediated subsurface reactions use a lumped reaction model that does not consider individual microbial reaction pathways, and describe reactions rates using empirically-derived rate formulations such as the Monod-type kinetics. We have used our pore-scale model to explore the relationship between genome-scale metabolic models and Monod-type formulations, and to assess the manifestation of pore-scale variability (microenvironments) in terms of apparent Darcy-scale microbial reaction rates. The genome-scale model predicted lower biomass yield, and different stoichiometry for iron consumption, in comparisonto prior Monod formulations based on energetics considerations. We were able to fit an equivalent Monod model, by modifying the reaction stoichiometry and biomass yield coefficient, that could effectively match results of the genome-scale simulation of microbial behaviors under excess nutrient conditions, but predictions of the fitted Monod model deviated from those of the genome-scale model under conditions in which one or more nutrients were limiting. The fitted Monod kinetic model was also applied at the Darcy scale; that is, to simulate average reaction processes at the scale of the entire pore-scale model domain. As we expected, even under excess nutrient conditions for which the Monod and genome-scale models predicted equal reaction rates at the pore scale, the Monod model over-predicted the rates of biomass growth and iron and acetate utilization when applied at the Darcy scale. This discrepancy is caused by an inherent assumption of perfect mixing over the Darcy-scale domain, which is clearly violated in the pore-scale models. These results help to explain the need to modify the flux constraint parameters in order to match observations in previous applications of the genome-scale model at larger scales. These results also motivate further investigation of quantitative multi-scale relationships between fundamental behavior at the pore scale (where genome-scale models are appropriately applied) and observed behavior at larger scales (where predictions of reactive transport phenomena are needed).

  8. Merging high resolution geophysical and geochemical surveys to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon Merging high resolution geophysical and geochemical surveys to reduce...

  9. Proceedings of the workshop on geochemical modeling

    SciTech Connect (OSTI)

    Not Available

    1986-01-01T23:59:59.000Z

    The following collection of papers was presented at a workshop on geochemical modeling that was sponsored by the Office of Civilian Radioactive Waste Management Program at the Lawrence Livermore National Laboratory (LLNL). The LLNL Waste Management Program sponsored this conference based on their belief that geochemical modeling is particularly important to the radioactive waste disposal project because of the need to predict the consequences of long-term water-rock interactions at the proposed repository site. The papers included in this volume represent a subset of the papers presented at the Fallen Leaf Lake Conference and cover a broad spectrum of detail and breadth in a subject that reflects the diverse research interests of the conference participants. These papers provide an insightful look into the current status of geochemical modeling and illustrate how various geochemical modeling codes have been applied to problems of geochemical interest. The emphasis of these papers includes traditional geochemical modeling studies of individual geochemical systems, the mathematical and theoretical development and refinement of new modeling capabilities, and enhancements of data bases on which the computations are based. The papers in this proceedings volume have been organized into the following four areas: Geochemical Model Development, Hydrothermal and Geothermal Systems, Sedimentary and Low Temperature Environments, and Data Base Development. The participants of this symposium and a complete list of the talks presented are listed in the appendices.

  10. ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion Transport in Yttria-Stabilized Zirconia

    E-Print Network [OSTI]

    Goddard III, William A.

    through yttria-stabilized zirconia (YSZ) solid oxide fuel cell (SOFC) membranes. All parameters for ReaxReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion temperature, leading to applications as oxygen sensors and as membranes for high temperature solid oxide fuel

  11. Reactive Gliosis Reactive Oxygen Species: Superoxide

    E-Print Network [OSTI]

    . By sensing the electric signals generated by other 3368 Reactive Gliosis #12;individuals, mormyrids are alsoReactive Gliosis Glial Scar Reactive Oxygen Species: Superoxide Anions Neuroinflammation motor output. Reafferent Control in Electric Communication Reafferent Control in Electric Communication

  12. Geochemical aspects of Michigan waterfloods

    SciTech Connect (OSTI)

    Tinker, G.E.; Barnes, P.F.; Olson, E.E.; Wright, M.P.

    1983-01-01T23:59:59.000Z

    Waterflooding started in the carbonate oil reservoirs of the N. Michigan Niagaran reef trend in 1978 with Shell's Chester 18 waterflood. Ten projects had been installed by the end of 1982 so that significant operational results are available for evaluation. This study presents what is currently known and understood about the geochemistry of Michigan waterfloods. Project monitoring procedures, established to control and optimize waterflood operations, have made it possible to develop the proper approach to the geochemical disruptions. The more important items in this program are the measurement of produced and injected volumes, transient pressure analyses, injection well profile surveys, chemical analysis of the injection and production fluid samples, radioactive injection tracers, and continuous bottom-hole pressures from submersible pumps. 15 references.

  13. Geochemical, mineralogical and microbiological characteristics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and transport of redox-sensitive metals and metalloids in aquifers. To assess the mineralogy, microbiology, and redox processes that occur in these zones, we examined several...

  14. EFFECTS OF PORE STRUCTURE CHANGE AND MULTI-SCALE HETEROGENEITY ON CONTAMINANT TRANSPORT AND REACTION RATE UPSCALING

    SciTech Connect (OSTI)

    Peters, Catherine A [Princeton University] [Princeton University

    2013-05-15T23:59:59.000Z

    This project addressed the scaling of geochemical reactions to core and field scales, and the interrelationship between reaction rates and flow in porous media. We targeted reactive transport problems relevant to the Hanford site specifically the reaction of highly caustic, radioactive waste solutions with subsurface sediments, and the immobilization of 90Sr and 129I through mineral incorporation and passive flow blockage, respectively. We addressed the correlation of results for pore-scale fluid-soil interaction with field-scale fluid flow, with the specific goals of (i) predicting attenuation of radionuclide concentration; (ii) estimating changes in flow rates through changes of soil permeabilities; and (iii) estimating effective reaction rates. In supplemental work, we also simulated reactive transport systems relevant to geologic carbon sequestration. As a whole, this research generated a better understanding of reactive transport in porous media, and resulted in more accurate methods for reaction rate upscaling and improved prediction of permeability evolution. These scientific advancements will ultimately lead to better tools for management and remediation of DOE legacy waste problems.

  15. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01T23:59:59.000Z

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  16. Guidance Document Reactive Chemicals

    E-Print Network [OSTI]

    showers and chillers. Health Hazards: The reactive chemicals are grouped primarily because of the physical

  17. THE EFFECT OF WATER TABLE ELEVATION ON ACID MINE DRAINAGE FROM REACTIVE TAILINGS

    E-Print Network [OSTI]

    Aubertin, Michel

    . A free-draining control column with no sand cover was also used. The experimental results were compared with different water table elevations. Each column contained a layer of reactive tailings overlain by a sand column tests have been completed to establish the hydraulic and geochemical conditions which control

  18. Geochemical Implications of Stirring and Mixing

    E-Print Network [OSTI]

    Rudge, John

    Geochemical Implications of Stirring and Mixing in the Earth's Mantle John Frederick Rudge Trinity Sciences and Applied Mathematics, mostly in the form of papers in my rucksack as I have cycled back constrain the melting, melt mi- gration, and solid state convection that occurs in the Earth's mantle

  19. Diffusion Dominant Solute Transport Modelling In Deep Repository Under The Effect of Emplacement Media Degradation - 13285

    SciTech Connect (OSTI)

    Kwong, S. [National Nuclear Laboratory (United Kingdom)] [National Nuclear Laboratory (United Kingdom); Jivkov, A.P. [Research Centre for Radwaste and Decommissioning and Modelling and Simulation Centre, University of Manchester (United Kingdom)] [Research Centre for Radwaste and Decommissioning and Modelling and Simulation Centre, University of Manchester (United Kingdom)

    2013-07-01T23:59:59.000Z

    Deep geologic disposal of high activity and long-lived radioactive waste is being actively considered and pursued in many countries, where low permeability geological formations are used to provide long term waste contaminant with minimum impact to the environment and risk to the biosphere. A multi-barrier approach that makes use of both engineered and natural barriers (i.e. geological formations) is often used to further enhance the containment performance of the repository. As the deep repository system subjects to a variety of thermo-hydro-chemo-mechanical (THCM) effects over its long 'operational' lifespan (e.g. 0.1 to 1.0 million years, the integrity of the barrier system will decrease over time (e.g. fracturing in rock or clay)). This is broadly referred as media degradation in the present study. This modelling study examines the effects of media degradation on diffusion dominant solute transport in fractured media that are typical of deep geological environment. In particular, reactive solute transport through fractured media is studied using a 2-D model, that considers advection and diffusion, to explore the coupled effects of kinetic and equilibrium chemical processes, while the effects of degradation is studied using a pore network model that considers the media diffusivity and network changes. Model results are presented to demonstrate the use of a 3D pore-network model, using a novel architecture, to calculate macroscopic properties of the medium such as diffusivity, subject to pore space changes as the media degrade. Results from a reactive transport model of a representative geological waste disposal package are also presented to demonstrate the effect of media property change on the solute migration behaviour, illustrating the complex interplay between kinetic biogeochemical processes and diffusion dominant transport. The initial modelling results demonstrate the feasibility of a coupled modelling approach (using pore-network model and reactive transport model) to examine the long term behaviour of deep geological repositories with media property change under complex geochemical conditions. (authors)

  20. Recapitalizing EMSL: Meeting Future Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    need to be developed in microscale reactive transport, adding chemistry on top of microfluidics, to better understand geochemical and biogeochemical reactivity as well as to help...

  1. System for reactivating catalysts

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Anderson, Raymond P. (Idaho Falls, ID)

    2010-03-02T23:59:59.000Z

    A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst is provided. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

  2. Multispecies Reactive Tracer Test in a Sand and

    E-Print Network [OSTI]

    Multispecies Reactive Tracer Test in a Sand and Gravel Aquifer, Cape Cod, Massachusetts United;Multispecies Reactive Tracer Test in a Sand and Gravel Aquifer, Cape Cod, Massachusetts Part 2 Transport- effectiveness for prevention and control of pollution to air, land, water, and subsurface resources; protection

  3. Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining...

    Open Energy Info (EERE)

    Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining District, Eastern California Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  4. Trace Element Geochemical Zoning in the Roosevelt Hot Springs...

    Open Energy Info (EERE)

    Capuano. 1980. Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah. In: Transactions. GRC Annual Meeting; 09091980; Salt Lake City, UT. Salt...

  5. Merging High Resolution Geophysical and Geochemical Surveys to...

    Open Energy Info (EERE)

    Buttes, Oregon Geothermal Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Merging High Resolution Geophysical and Geochemical Surveys to Reduce...

  6. Geochemical Controls on Contaminant Uranium in Vadose Hanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controls on Contaminant Uranium in Vadose Hanford Formation Sediments at the 200 Area and 300 Area, Hanford Site, Geochemical Controls on Contaminant Uranium in Vadose Hanford...

  7. Geochemical characterization of geothermal systems in the Great...

    Open Energy Info (EERE)

    for geothermal energy in the Great Basin. In addition, understanding the geochemical evolution of these various types of systems will provide important insights into the possible...

  8. Merging high resolution geophysical and geochemical surveys to...

    Broader source: Energy.gov (indexed) [DOE]

    Merging high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon Patrick Walsh Ormat Nevada Inc. Innovative technologies May 19, 2010...

  9. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    characteristic of stable isotope enrichment. The values of !isotope ratios of sulfur in these sulfate samples demonstrated a clear enrichmentisotope ( 34 S) (Canfield, 2001). The characteristic enrichment

  10. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    and detachment of calcium and carbonate ions. Crystalactivity product of calcium and carbonate in solution, K spJ. 2012. Upscaling calcium carbonate precipitation rates

  11. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    34 S fractionation . Summary A mesoscale study of isotopicion exchange and ! 44 Ca . A mesoscale study of isotopicmodeling and ! 34 S . A mesoscale study of isotopic

  12. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    W.T. (eds. ), 1999. Bioremediation of Contaminated Soils.heterogeneity and bioremediation induced biogeochemicalK.S. 2007. In Situ Bioremediation. Advances in Applied

  13. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    Work Plan for the UMTRA Project Old Rifle Site, GJO-99-88-influent values and the UMTRA compliance limit for uraniumTailings Remediation Action (UMTRA) project, which included

  14. DNA-based methods of geochemical prospecting

    DOE Patents [OSTI]

    Ashby, Matthew (Mill Valley, CA)

    2011-12-06T23:59:59.000Z

    The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

  15. Upscaling geochemical reaction rates using pore-scale network modeling

    E-Print Network [OSTI]

    Peters, Catherine A.

    . To examine the scaling behavior of reaction kinetics, these continuum-scale rates from the network model as a valuable research tool for examining upscaling of geochemical kinetics. The pore-scale model allowsUpscaling geochemical reaction rates using pore-scale network modeling Li Li, Catherine A. Peters

  16. MINTEQ2 geochemical code: provisionary organic data base

    SciTech Connect (OSTI)

    Morrey, J.R.; Krupka, K.M.; Dove, F.H.

    1985-10-01T23:59:59.000Z

    Organic components in aqueous radioactive chemical sources, surface waters, and ground waters could substantially alter the mobility of radioactive and other important nonradioactive elements released from a defense waste disposal system. It is therefore important to be able to predict, as accurately as possible, the effects of selected organic components on the solubilities of radionuclides and important nonradioactive elements. The geochemical code MINTEQ2 can be used to assess solubilities provided that appropriate thermochemical data for organic and inorganic aqueous species and solids are available for its use. The code accepts an assemblage of gaseous and solid phases in contact with an aqueous phase and calculates the thermochemical equilibrium between these phases. Unlike typical hydrologic flow and transport codes where the data base is entirely site specific (i.e., parameters particular to the specific site), MINTEQ2 requires an additional generic thermochemical data base. This report discusses the addition of provisionary organic reactions and associated equilibrium constants to the generic data base that can be used by MINTEQ2 in scoping calculations or preliminary performance assessments.

  17. Geochemical evolution of highly alkaline and saline tank wasteplumes during seepage through vadose zone sediments

    SciTech Connect (OSTI)

    Wan, Jiamin; Tokunaga, Tetsu K.; Larsen, Joern T.; Serne, R. Jeff

    2002-12-01T23:59:59.000Z

    Leakage of highly saline and alkaline radioactive waste from storage tanks into underlying sediments is a serious environmental problem at the Hanford Site in Washington State. This study focuses on geochemical evolution of tank waste plumes resulting from interactions between the waste solution and sediment. A synthetic tank waste solution was infused into unsaturated Hanford sediment columns (0.2, 0.6, and 2 m )maintained at 70 C to simulate the field contamination process. Spatially and temporally resolved geochemical profiles of the waste plume were obtained. Thorough OH- neutralization (from an initial pH 14 down to 6.3) was observed. Three broad zones of pore solutions were identified to categorize the dominant geochemical reactions: the silicate dissolution zone (pH>10), pH-neutralized zone (pH 10 to 6.5), and displaced native sediment pore water (pH 6.5 to 8). Elevated concentrations of Si, Fe, and K in plume fluids and their depleted concentrations in plume sediments reflected dissolution of primary minerals within the silicate dissolution zone. The very high Na concentrations in the waste solution resulted in rapid and complete cation exchange, reflected in high concentrations of Ca and Mg at the plume front. The plume-sediment profiles also showed deposition of hydrated solids and carbonates. Fair correspondence was obtained between these results and analyses of field borehole samples from a waste plume at the Hanford Site. Results of this study provide a well-defined framework for understanding waste plumes in the more complex field setting and for understanding geochemical factors controlling transport of contaminant species carried in waste solutions that leaked from single-shell storage tanks in the past.

  18. Geochemical evolution of highly alkaline and saline tank waste plumes during seepage through vadose zone sediments

    SciTech Connect (OSTI)

    Wan, Jiamin; Tokunaga, Tetsu K.; Larsen, Joern T.; Serne, R JEFFREY.

    2004-02-01T23:59:59.000Z

    Leakage of highly saline and alkaline radioactive waste from storage tanks into underlying sediments is a serious environmental problem at the Hanford Site in Washington State. This study focuses on geochemical evolution of tank waste plumes resulting from interactions between the waste solution and sediment. A synthetic tank waste solution was infused into unsaturated Hanford sediment columns (0.2, 0.6, and 2 m) maintained at 70C to simulate the field contamination process. Spatially and temporally resolved geochemical profiles of the waste plume were obtained. Thorough OH neutralization (from an initial pH 14 down to 6.3) was observed. Three broad zones of pore solutions were identified to categorize the dominant geochemical reactions: the silicate dissolution zone (pH > 10), pH-neutralized zone (pH 10 to 6.5), and displaced native sediment pore water (pH 6.5 to 8). Elevated concentrations of Si, Fe, and K in plume fluids and their depleted concentrations in plume sediments reflected dissolution of primary minerals within the silicate dissolution zone. The very high Na concentrations in the waste solution resulted in rapid and complete cation exchange, reflected in high concentrations of Ca and Mg at the plume front. The plume-sediment profiles also showed deposition of hydrated solids and carbonates. Fair correspondence was obtained between these results and analyses of field borehole samples from a waste plume at the Hanford Site. Results of this study provide a well-defined framework for understanding waste plumes in the more complex field setting and for understanding geochemical factors controlling transport of contaminant species carried in waste solutions that leaked from single-shell storage tanks in the past.

  19. Geochemical Data Package for Performance Assessment Calculations Related to the Savannah River Site

    SciTech Connect (OSTI)

    Kaplan, D

    2006-02-28T23:59:59.000Z

    The Savannah River Site disposes of certain types of radioactive waste within subsurface-engineered facilities. One of the tools used to establish the capacity of a given site to safely store radioactive waste (i.e., that a site does not exceed its Waste Acceptance Criteria) is the Performance Assessment (PA). The objective of this document is to provide the geochemical values for the PA calculations. This work is being conducted as part of the on-going maintenance program that permits the PA to periodically update existing calculations when new data becomes available. Because application of values without full understanding of their original purpose may lead to misuse, this document also provides the geochemical conceptual model, approach used for selecting the values, the justification for selecting data, and the assumptions made to assure that the conceptual and numerical geochemical models are reasonably conservative (i.e., reflect conditions that will tend to predict the maximum risk to the hypothetical recipient). The geochemical parameters describe transport processes for 38 elements (>90 radioisotopes) potentially occurring within eight disposal units (Slit Trenches, Engineered Trenches, Low Activity Waste (LAW) Vault, Intermediate Level (ILV) Vaults, TRU-Pad-1, Naval Reactor Waste Pads, Components-in-Grout Trenches, and Saltstone Facility). This work builds upon well-documented work from previous PA calculations (McDowell-Boyer et al. 2000). The new geochemical concepts introduced in this data package are: (1) In the past, solubility products were used only in a few conditions (element existing in a specific environmental setting). This has been expanded to >100 conditions. (2) Radionuclide chemistry in cementitious environments is described through the use of both the Kd and apparent solubility concentration limit. Furthermore, the solid phase is assumed to age during the assessment period (thousands of years), resulting in three main types of controlling solid phases, each possessing a unique set of radionuclide sorption parameters (Kd and solubility concentration limit). (3) A large amount of recent site-specific sorption research has been conducted since the last PA (McDowell-Boyer et al. 2000). These new data have replaced previous Kd values derived from literature values, thus reducing uncertainty and improving accuracy. Finally, because this document will be used by future PA calculations and external acceptance of the document will eventually be required, this document was extensively reviewed. The review process, including the internal review, site review, and external review process is described.

  20. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  1. Geochemical Data for 95 Thermal and Nonthermal Waters of the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data for 95 Thermal and Nonthermal Waters of the Valles Caldera - Southern Jemez Mountains...

  2. Temporal Geochemical Variations In Volatile Emissions From Mount...

    Open Energy Info (EERE)

    Geochemical Variations In Volatile Emissions From Mount St Helens, Usa, 1980-1994 Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Temporal...

  3. A Reconnaissance Geochemical Study Of La Primavera Geothermal...

    Open Energy Info (EERE)

    Study Of La Primavera Geothermal Area, Jalisco, Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Reconnaissance Geochemical Study Of La...

  4. Reactive Power Compensator.

    DOE Patents [OSTI]

    El-Sharkawi, M.A.; Venkata, S.S.; Chen, M.; Andexler, G.; Huang, T.

    1992-07-28T23:59:59.000Z

    A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation. 26 figs.

  5. Reactive power compensator

    DOE Patents [OSTI]

    El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Woodinville, WA); Chen, Mingliang (Kirkland, WA); Andexler, George (Everett, WA); Huang, Tony (Seattle, WA)

    1992-01-01T23:59:59.000Z

    A system and method for determining and providing reactive power compensation for an inductive load. A reactive power compensator (50,50') monitors the voltage and current flowing through each of three distribution lines (52a, 52b, 52c), which are supplying three-phase power to one or more inductive loads. Using signals indicative of the current on each of these lines when the voltage waveform on the line crosses zero, the reactive power compensator determines a reactive power compensator capacitance that must be connected to the lines to maintain a desired VAR level, power factor, or line voltage. Alternatively, an operator can manually select a specific capacitance for connection to each line, or the capacitance can be selected based on a time schedule. The reactive power compensator produces control signals, which are coupled through optical fibers (102/106) to a switch driver (110, 110') to select specific compensation capacitors (112) for connections to each line. The switch driver develops triggering signals that are supplied to a plurality of series-connected solid state switches (350), which control charge current in one direction in respect to ground for each compensation capacitor. During each cycle, current flows from ground to charge the capacitors as the voltage on the line begins to go negative from its positive peak value. The triggering signals are applied to gate the solid state switches into a conducting state when the potential on the lines and on the capacitors reaches a negative peak value, thereby minimizing both the potential difference and across the charge current through the switches when they begin to conduct. Any harmonic distortion on the potential and current carried by the lines is filtered out from the current and potential signals used by the reactive power compensator so that it does not affect the determination of the required reactive compensation.

  6. EFFECTS OF PORE STRUCTURE CHANGE AND MULTI-SCALE HETEROGENEITY ON CONTAMINANT TRANSPORT AND REACTION RATE UPSCALING

    SciTech Connect (OSTI)

    Lindquist, W. Brent; Jones, Keith W.; Um, Wooyong; Rockhold, mark; Peters, Catherine A.; Celia, Michael A.

    2013-02-15T23:59:59.000Z

    This project addressed the scaling of geochemical reactions to core and field scales, and the interrelationship between reaction rates and flow in porous media. We targeted reactive transport problems relevant to the Hanford site ? specifically the reaction of highly caustic, radioactive waste solutions with subsurface sediments, and the immobilization of 90Sr and 129I through mineral incorporation and passive flow blockage, respectively. We addressed the correlation of results for pore-scale fluid-soil interaction with field-scale fluid flow, with the specific goals of (i) predicting attenuation of radionuclide concentration; (ii) estimating changes in flow rates through changes of soil permeabilities; and (iii) estimating effective reaction rates. In supplemental work, we also simulated reactive transport systems relevant to geologic carbon sequestration. As a whole, this research generated a better understanding of reactive transport in porous media, and resulted in more accurate methods for reaction rate upscaling and improved prediction of permeability evolution. These scientific advancements will ultimately lead to better tools for management and remediation of DOE’s legacy waste problems. We established three key issues of reactive flow upscaling, and organized this project in three corresponding thrust areas. 1) Reactive flow experiments. The combination of mineral dissolution and precipitation alters pore network structure and the subsequent flow velocities, thereby creating a complex interaction between reaction and transport. To examine this phenomenon, we conducted controlled laboratory experimentation using reactive flow-through columns. ? Results and Key Findings: Four reactive column experiments (S1, S3, S4, S5) have been completed in which simulated tank waste leachage (STWL) was reacted with pure quartz sand, with and without Aluminum. The STWL is a caustic solution that dissolves quartz. Because Al is a necessary element in the formation of secondary mineral precipitates (cancrinite), conducting experiments under conditions with and without Al allowed us to experimentally separate the conditions that lead to quartz dissolution from the conditions that lead to quartz dissolution plus cancrinite precipitation. Consistent with our expectations, in the experiments without Al, there was a substantial reduction in volume of the solid matrix. With Al there was a net increase in the volume of the solid matrix. The rate and extent of reaction was found to increase with temperature. These results demonstrate a successful effort to identify conditions that lead to increases and conditions that lead to decreases in solid matrix volume due to reactions of caustic tank wastes with quartz sands. In addition, we have begun to work with slightly larger, intermediate-scale columns packed with Hanford natural sediments and quartz. Similar dissolution and precipitation were observed in these colums. The measurements are being interpreted with reactive transport modeling using STOMP; preliminary observations are reported here. 2) Multi-Scale Imaging and Analysis. Mineral dissolution and precipitation rates within a porous medium will be different in different pores due to natural heterogeneity and the heterogeneity that is created from the reactions themselves. We used a combination of X-ray computed microtomography, backscattered electron and energy dispersive X-ray spectroscopy combined with computational image analysis to quantify pore structure, mineral distribution, structure changes and fluid-air and fluid-grain interfaces. ? Results and Key Findings: Three of the columns from the reactive flow experiments at PNNL (S1, S3, S4) were imaged using 3D X-ray computed microtomography (XCMT) at BNL and analyzed using 3DMA-rock at SUNY Stony Brook. The imaging results support the mass balance findings reported by Dr. Um’s group, regarding the substantial dissolution of quartz in column S1. An important observation is that of grain movement accompanying dissolution in the unconsolidated media. The resultant movement

  7. GEOCHEMICAL MODELING OF F AREA SEEPAGE BASIN COMPOSITION AND VARIABILITY

    SciTech Connect (OSTI)

    Millings, M.; Denham, M.; Looney, B.

    2012-05-08T23:59:59.000Z

    From the 1950s through 1989, the F Area Seepage Basins at the Savannah River Site (SRS) received low level radioactive wastes resulting from processing nuclear materials. Discharges of process wastes to the F Area Seepage Basins followed by subsequent mixing processes within the basins and eventual infiltration into the subsurface resulted in contamination of the underlying vadose zone and downgradient groundwater. For simulating contaminant behavior and subsurface transport, a quantitative understanding of the interrelated discharge-mixing-infiltration system along with the resulting chemistry of fluids entering the subsurface is needed. An example of this need emerged as the F Area Seepage Basins was selected as a key case study demonstration site for the Advanced Simulation Capability for Environmental Management (ASCEM) Program. This modeling evaluation explored the importance of the wide variability in bulk wastewater chemistry as it propagated through the basins. The results are intended to generally improve and refine the conceptualization of infiltration of chemical wastes from seepage basins receiving variable waste streams and to specifically support the ASCEM case study model for the F Area Seepage Basins. Specific goals of this work included: (1) develop a technically-based 'charge-balanced' nominal source term chemistry for water infiltrating into the subsurface during basin operations, (2) estimate the nature of short term and long term variability in infiltrating water to support scenario development for uncertainty quantification (i.e., UQ analysis), (3) identify key geochemical factors that control overall basin water chemistry and the projected variability/stability, and (4) link wastewater chemistry to the subsurface based on monitoring well data. Results from this study provide data and understanding that can be used in further modeling efforts of the F Area groundwater plume. As identified in this study, key geochemical factors affecting basin chemistry and variability included: (1) the nature or chemistry of the waste streams, (2) the open system of the basins, and (3) duration of discharge of the waste stream types. Mixing models of the archetype waste streams indicated that the overall basin system would likely remain acidic much of the time. Only an extended periods of predominantly alkaline waste discharge (e.g., >70% alkaline waste) would dramatically alter the average pH of wastewater entering the basins. Short term and long term variability were evaluated by performing multiple stepwise modeling runs to calculate the oscillation of bulk chemistry in the basins in response to short term variations in waste stream chemistry. Short term (1/2 month and 1 month) oscillations in the waste stream types only affected the chemistry in Basin 1; little variation was observed in Basin 2 and 3. As the largest basin, Basin 3 is considered the primary source to the groundwater. Modeling showed that the fluctuation in chemistry of the waste streams is not directly representative of the source term to the groundwater (i.e. Basin 3). The sequence of receiving basins and the large volume of water in Basin 3 'smooth' or nullify the short term variability in waste stream composition. As part of this study, a technically-based 'charge-balanced' nominal source term chemistry was developed for Basin 3 for a narrow range of pH (2.7 to 3.4). An example is also provided of how these data could be used to quantify uncertainty over the long term variations in waste stream chemistry and hence, Basin 3 chemistry.

  8. Power Factor Reactive Power

    E-Print Network [OSTI]

    motor power: 117.7 V x 5.1 A = 600 W? = 0.6 kW? NOT the power measured by meter #12;Page 9 PSERC: displacement power factor: angle between voltage and current = 0 degrees pf = cos(0 degrees) = 1.0 true powerPage 1 PSERC Power Factor and Reactive Power Ward Jewell Wichita State University Power Systems

  9. Reactive power compensating system

    DOE Patents [OSTI]

    Williams, Timothy J. (Redondo Beach, CA); El-Sharkawi, Mohamed A. (Renton, WA); Venkata, Subrahmanyam S. (Seattle, WA)

    1987-01-01T23:59:59.000Z

    The reactive power of an induction machine is compensated by providing fixed capacitors on each phase line for the minimum compensation required, sensing the current on one line at the time its voltage crosses zero to determine the actual compensation required for each phase, and selecting switched capacitors on each line to provide the balance of the compensation required.

  10. Reactive Power Compensating System.

    DOE Patents [OSTI]

    Williams, Timothy J.; El-Sharkawi, Mohamed A.; Venkata, Subrahmanyam S.

    1985-01-04T23:59:59.000Z

    The circuit was designed for the specific application of wind-driven induction generators. It has great potential for application in any situation where a varying reactive power load is present, such as with induction motors or generators, or for transmission network compensation.

  11. Chemically Reactive Working Fluids

    Broader source: Energy.gov (indexed) [DOE]

    Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Argonne National Laboratory Award Number: CPS25657 | April 15, 2013 | Brotzman * Thermodynamic and...

  12. Crustal melting in the Himalayan orogen : field, geochemical and geochronological studies in the Everest region, Nepal

    E-Print Network [OSTI]

    Viskupic, Karen M. (Karen Marie), 1975-

    2003-01-01T23:59:59.000Z

    A combination of field studies and geochemical techniques were used to investigate the timing and processes involved in leucogranite generation in the Everest region of the Himalayan orogen. Geochemical investigations ...

  13. PRELIMINARY RESULTS OF THE PETROLOGICAL-GEOCHEMICAL COMPONENT TO THE BATHOLITHS PROJECT

    E-Print Network [OSTI]

    Wetmore, Paul H.

    PRELIMINARY RESULTS OF THE PETROLOGICAL- GEOCHEMICAL COMPONENT TO THE BATHOLITHS PROJECT Paul H. Wetmore Theresa Kayzar Mihai Ducea P. Jonathan Patchett George Gehrels The petrologic during batholith generation. Petrologic and geochemical studies of arc-related, igneous and meta

  14. Reactive Air Aluminization

    SciTech Connect (OSTI)

    Choi, Jung-Pyung; Chou, Y. S.; Stevenson, Jeffry W.

    2011-10-28T23:59:59.000Z

    Ferritic stainless steels and other alloys are of great interest to SOFC developers for applications such as interconnects, cell frames, and balance of plant components. While these alloys offer significant advantages (e.g., low material and manufacturing cost, high thermal conductivity, and high temperature oxidation resistance), there are challenges which can hinder their utilization in SOFC systems; these challenges include Cr volatility and reactivity with glass seals. To overcome these challenges, protective coatings and surface treatments for the alloys are under development. In particular, aluminization of alloy surfaces offers the potential for mitigating both evaporation of Cr from the alloy surface and reaction of alloy constituents with glass seals. Commercial aluminization processes are available to SOFC developers, but they tend to be costly due to their use of exotic raw materials and/or processing conditions. As an alternative, PNNL has developed Reactive Air Aluminization (RAA), which offers a low-cost, simpler alternative to conventional aluminization methods.

  15. ORNL/TM-2008/083 A Tariff for Reactive Power

    E-Print Network [OSTI]

    Pennycook, Steve

    ORNL/TM-2008/083 A Tariff for Reactive Power 2008 Prepared by Christopher Tufon, Pacific Gas & Electric Company Alan G. Isemonger, California Independent System Operator Brendan Kirby, ORNL, Knowledge and Transportation Science Division A Tariff for Reactive Power Christopher Tufon Alan G. Isemonger Brendan Kirby

  16. Modeling Reactive Flows in Porous Media Peter Lichtner (lead PI), Los Alamos National Laboratory

    E-Print Network [OSTI]

    Mills, Richard

    and reactive transport in porous media. Apply it to field-scale studies of Geologic CO2 sequestrationModeling Reactive Flows in Porous Media Peter Lichtner (lead PI), Los Alamos National Laboratory NCCS Users Meeting March 28, 2007 #12;Introduction Companion to SciDAC-II project, "Modeling

  17. Geochemical and physical properties of wetland soils at the Savannah River site

    SciTech Connect (OSTI)

    Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

    1996-05-01T23:59:59.000Z

    The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

  18. Geochemical Modeling of ILAW Lysimeter Water Extracts

    SciTech Connect (OSTI)

    Cantrell, Kirk J.

    2014-12-22T23:59:59.000Z

    Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90°C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90°C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90°C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90°C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90°C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network than gibbsite under field conditions. This may be due to the availability of carbonate that exists in the Hanford sediments as calcite. A significant source of carbonate was not available in the PCTs and this may account for why this phase did not appear in the PCTs. Sepiolite was consistently highly undersaturated, suggesting that another phase controls the solubility of magnesium. For samples that were most impacted by the effects of glass corrosion, magnesite appears to control glass corrosion. For samples that show less impacts from glass corrosion, clinochlore-7A or saponite-Mg appears to control the magnesium concentrations. For zinc, it appears that zincite is a better candidate than Zn(OH)2-? for controlling zinc concentrations in the extracts; however, in some samples all zinc phases considered were highly oversaturated. As a result the phase that controls zinc concentrations in the lysimeter extracts remains uncertain.

  19. argentina mineralogical geochemical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    argentina mineralogical geochemical First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 A shocking state:...

  20. Synthesis of organic geochemical data from the Eastern Gas Shales

    SciTech Connect (OSTI)

    Zielinski, R.E.; McIver, R.D.

    1982-01-01T23:59:59.000Z

    Over 2400 core and cuttings samples of Upper Devonian shales from wells in the Appalachian, Illinois, and Michigan Basins have been characterized by organic geochemical methods to provide a basis for accelerating the exploitation of this unconventional, gas-rich resource. This work was part of a program initiated to provide industry with criteria for locating the best areas for future drilling and for the development of stimulation methods that will make recovery of the resource economically attractive. The geochemical assessment shows that the shale, in much of the Appalachian, Illinois, and Michigan Basins is source rock that is capable of generating enormous quantities of gas. In some areas the shales are also capable of generating large quantities of oil as well. The limiting factors preventing these sources from realizing most of their potential are their very low permeabilities and the paucity of potential reservoir rocks. This geochemical data synthesis gives direction to future selection of sites for stimulation research projects in the Appalachian Basin by pinpointing those areas where the greatest volumes of gas are contained in the shale matrix. Another accomplishment of the geochemical data synthesis is a new estimate of the total resource of the Appalachian Basin. The new estimate of 2500 TCF is 25 percent greater than the highest previous estimates. This gives greater incentive to government and industry to continue the search for improved stimulation methods, as well as for improved methods for locating the sites where those improved stimulation methods can be most effectively applied.

  1. Saturated Zone Colloid Transport

    SciTech Connect (OSTI)

    H. S. Viswanathan

    2004-10-07T23:59:59.000Z

    This scientific analysis provides retardation factors for colloids transporting in the saturated zone (SZ) and the unsaturated zone (UZ). These retardation factors represent the reversible chemical and physical filtration of colloids in the SZ. The value of the colloid retardation factor, R{sub col} is dependent on several factors, such as colloid size, colloid type, and geochemical conditions (e.g., pH, Eh, and ionic strength). These factors are folded into the distributions of R{sub col} that have been developed from field and experimental data collected under varying geochemical conditions with different colloid types and sizes. Attachment rate constants, k{sub att}, and detachment rate constants, k{sub det}, of colloids to the fracture surface have been measured for the fractured volcanics, and separate R{sub col} uncertainty distributions have been developed for attachment and detachment to clastic material and mineral grains in the alluvium. Radionuclides such as plutonium and americium sorb mostly (90 to 99 percent) irreversibly to colloids (BSC 2004 [DIRS 170025], Section 6.3.3.2). The colloid retardation factors developed in this analysis are needed to simulate the transport of radionuclides that are irreversibly sorbed onto colloids; this transport is discussed in the model report ''Site-Scale Saturated Zone Transport'' (BSC 2004 [DIRS 170036]). Although it is not exclusive to any particular radionuclide release scenario, this scientific analysis especially addresses those scenarios pertaining to evidence from waste-degradation experiments, which indicate that plutonium and americium may be irreversibly attached to colloids for the time scales of interest. A section of this report will also discuss the validity of using microspheres as analogs to colloids in some of the lab and field experiments used to obtain the colloid retardation factors. In addition, a small fraction of colloids travels with the groundwater without any significant retardation. Radionuclides irreversibly sorbed onto this fraction of colloids also transport without retardation. The transport times for these radionuclides will be the same as those for nonsorbing radionuclides. The fraction of nonretarding colloids developed in this analysis report is used in the abstraction of SZ and UZ transport models in support of the total system performance assessment (TSPA) for the license application (LA). This analysis report uses input from two Yucca Mountain Project (YMP) analysis reports. This analysis uses the assumption from ''Waste Form and In-Drift Colloids-Associated Radionuclide Concentrations: Abstraction and Summary'' that plutonium and americium are irreversibly sorbed to colloids generated by the waste degradation processes (BSC 2004 [DIRS 170025]). In addition, interpretations from RELAP analyses from ''Saturated Zone In-Situ Testing'' (BSC 2004 [DIRS 170010]) are used to develop the retardation factor distributions in this analysis.

  2. Geochemical Cycling of Iodine Species in Soils

    SciTech Connect (OSTI)

    Hu, Q; Moran, J E; Blackwood, V

    2007-08-23T23:59:59.000Z

    Iodine is an important element in studies of environmental protection and human health, global-scale hydrologic processes and nuclear nonproliferation. Biogeochemical cycling of iodine in soils is complex, because iodine occurs in multiple oxidation states and as inorganic and organic species that may be hydrophilic, atmophilic, and biophilic. In this study, we applied new analytical techniques to study the content and speciation of stable iodine in representative surface soils, and sorption and transport behavior of iodine species (iodide, iodate, and 4-iodoaniline) in sediments collected at numerous nuclear facilities in the United States, where anthropogenic {sup 129}I from prior nuclear fuel processing activities poses an environmental risk. The surface soil samples were chosen for their geographic locations (e.g., near the ocean or nuclear facilities) and for their differing physico-chemical characteristics (organic matter, texture, etc). Extracted solutions were analyzed by IC and ICP-MS methods to determine iodine concentrations and to examine iodine speciation (iodide, iodate, and organic iodine). In natural soils, iodine is mostly (nearly 90% of total iodine) present as organic species, while inorganic iodine becomes important (up to 50%) only in sediments with low organic matter. Results from laboratory column studies, aimed at examining transport of different iodine species, showed much greater retardation of 4-iodoaniline than iodide or iodate. Careful attention must be given to potential interconversion among species when interpreting the biogeochemical behavior of iodine in the environment. In addition to speciation, input concentration and residence time effects will influence the biogeochemical cycling of anthropogenic 129I deposited on surface soils.

  3. Investigating the potential for long-term permeable reactive barrier (PRB) monitoring from the electrical signatures associated with the reduction in reactive iron performance

    SciTech Connect (OSTI)

    Slater, Lee

    2004-06-15T23:59:59.000Z

    The objective of this project is to quantify the ability of the electrical induced polarization (IP) method to noninvasively monitor the reduction in reactive iron performance that is known to reduce the effectiveness of the permeable reactive barrier (PRB) with time. The primary scientific goals include: (A) fundamental laboratory studies to evaluate the sensitivity of the IP method to: Fe0 total surface area Fe0 surface chemistry physical/chemical changes to the Fe0 surface resulting from oxidation and precipitation; (B) monitoring of the electrical tomographic response of the Kansas City PRB over a three-year period and assessment, via correlation with aqueous geochemical data and extracted iron cores, of whether electrical signatures associated with reduced PRB performance are resolvable in field studies; (C) optimization of a three-dimensional tomographic imaging algorithm for application to highly conductive, high electrical contrast environments as represented by a PRB.

  4. Computers & Geosciences 29 (2003) 351359 A case against Kd-based transport models: natural attenuation

    E-Print Network [OSTI]

    Polly, David

    )-based transport model. The study site is a contaminated groundwater aquifer underneath a uranium mill tailings groundwater for 1600 years. The coupled model shows that groundwater­sediment interactions result in multiple. Keywords: Geochemical modeling; Contaminant; Transport; Coupled processes 1. Introduction Accurate

  5. ENVIRONMENTAL REACTIVITY OF SOLID STATE HYDRIDE MATERIALS

    SciTech Connect (OSTI)

    Gray, J; Donald Anton, D

    2009-04-23T23:59:59.000Z

    In searching for high gravimetric and volumetric density hydrogen storage systems, it is inevitable that higher energy density materials will be used. In order to make safe and commercially acceptable condensed phase hydrogen storage systems, it is important to understand quantitatively the risks involved in using and handling these materials and to develop appropriate mitigation strategies to handle potential material exposure events. A crucial aspect of the development of risk identification and mitigation strategies is the development of rigorous environmental reactivity testing standards and procedures. This will allow for the identification of potential risks and implementation of risk mitigation strategies. Modified testing procedures for shipping air and/or water sensitive materials, as codified by the United Nations, have been used to evaluate two potential hydrogen storage materials, 2LiBH{sub 4} {center_dot} MgH{sub 2} and NH{sub 3}BH{sub 3}. The modified U.N. procedures include identification of self-reactive substances, pyrophoric substances, and gas-emitting substances with water contact. The results of these tests for air and water contact sensitivity will be compared to the pure material components where appropriate (e.g. LiBH{sub 4} and MgH{sub 2}). The water contact tests are divided into two scenarios dependent on the hydride to water mole ratio and heat transport characteristics. Air contact tests were run to determine whether a substance will spontaneously react with air in a packed or dispersed form. In the case of the 2LiBH{sub 4} {center_dot} MgH{sub 2} material, the results from the hydride mixture compared to the pure materials results showed the MgH{sub 2} to be the least reactive component and LiBH{sub 4} the more reactive. The combined 2LiBH{sub 4} {center_dot} MgH{sub 2} resulted in a material having environmental reactivity between these two materials. Relative to 2LiBH{sub 4} {center_dot} MgH{sub 2}, the chemical hydride NH{sub 3}BH{sub 3} was observed to be less environmentally reactive.

  6. Influence of Reactive Transport on the Reduction of U(VI) in the Presence of Fe(III) and Nitrate: Implications for U(VI) Immobilization by Bioremediation / Biobarriers- Final Report

    SciTech Connect (OSTI)

    B.D. Wood

    2007-01-01T23:59:59.000Z

    Subsurface contamination by metals and radionuclides represent some of the most challenging remediation problems confronting the Department of Energy (DOE) complex. In situ remediation of these contaminants by dissimilatory metal reducing bacteria (DMRB) has been proposed as a potential cost effective remediation strategy. The primary focus of this research is to determine the mechanisms by which the fluxes of electron acceptors, electron donors, and other species can be controlled to maximize the transfer of reductive equivalents to the aqueous and solid phases. The proposed research is unique in the NABIR portfolio in that it focuses on (i) the role of flow and transport in the initiation of biostimulation and the successful sequestration of metals and radionuclides [specifically U(VI)], (ii) the subsequent reductive capacity and stability of the reduced sediments produced by the biostimulation process, and (iii) the potential for altering the growth of biomass in the subsurface by the addition of specific metabolic uncoupling compounds. A scientifically-based understanding of these phenomena are critical to the ability to design successful bioremediation schemes. The laboratory research will employ Shewanella putrefaciens (CN32), a facultative DMRB that can use Fe(III) oxides as a terminal electron acceptor. Sediment-packed columns will be inoculated with this organism, and the reduction of U(VI) by the DMRB will be stimulated by the addition of a carbon and energy source in the presence of Fe(III). Separate column experiments will be conducted to independently examine: (1) the importance of the abiotic reduction of U(VI) by biogenic Fe(II); (2) the influence of the transport process on Fe(III) reduction and U(VI) immobilization, with emphasis on methods for controlling the fluxes of aqueous species to maximize uranium reduction; (3) the reductive capacity of biologically-reduced sediments (with respect to re-oxidation by convective fluxes of O2 and NO3-) and the long-term stability of immobilized uranium mineral phases after bioremediation processes are complete, and (4) the ability for metabolic uncoupling compounds to maintain microbial growth while limiting biomass production. The results of the laboratory experiments will be used to develop mathematical descriptive models for the coupled transport and reduction processes.

  7. Argonne Geothermal Geochemical Database v2.0

    SciTech Connect (OSTI)

    Harto, Christopher

    2013-05-22T23:59:59.000Z

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  8. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  9. Geochemical Prospecting of Hydrocarbons in Frontier Basins of India* By

    E-Print Network [OSTI]

    B. Kumar; D. J. Patil; G. Kalpana; C. Vishnu Vardhan

    India has 26 sedimentary basins with a basinal area of approximately 1.8x 10 6 km 2 (excluding deep waters), out of which seven are producing basins and two have proven potential. Exploration efforts in other basins, called “frontier basins ” are in progress. These basins are characterized by varied geology, age, tectonics, and depositional environments. Hydrocarbon shows in many of these basins are known, and in few basins oil and gas have flowed in commercial /non-commercial quantities. Within the framework of India Hydrocarbon Vision – 2025 and New Exploration Licensing Policy, there is a continuous increase in area under active exploration. The asset management concept with multi-disciplinary teams has created a demand for synergic application of risk-reduction technologies, including surface geochemical surveys. National Geophysical Research Institute (NGRI), Hyderabad, India has initiated/planned surface geochemical surveys composed of gas chromatographic and carbon isotopic analyses in few of the frontier basins of India. The adsorbed soil gas data in one of the basins (Saurashtra basin, Gujarat) has shown varied concentrations of CH4 to C4H10. The C1 concentration varies between 3 to 766 ppb and ??C2+, 1 to 543 ppb. This basin has thin soil cover and the Mesozoic sediments (probable source rocks) are overlain by thick cover of Deccan Traps. The scope and perspective of geochemical surveys in frontier basins of India are presented here.

  10. A Tariff for Reactive Power

    SciTech Connect (OSTI)

    Kueck, John D [ORNL; Kirby, Brendan J [ORNL; Li, Fangxing [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator

    2008-07-01T23:59:59.000Z

    Two kinds of power are required to operate an electric power system: real power, measured in watts, and reactive power, measured in volt-amperes reactive or VARs. Reactive power supply is one of a class of power system reliability services collectively known as ancillary services, and is essential for the reliable operation of the bulk power system. Reactive power flows when current leads or lags behind voltage. Typically, the current in a distribution system lags behind voltage because of inductive loads such as motors. Reactive power flow wastes energy and capacity and causes voltage droop. To correct lagging power flow, leading reactive power (current leading voltage) is supplied to bring the current into phase with voltage. When the current is in phase with voltage, there is a reduction in system losses, an increase in system capacity, and a rise in voltage. Reactive power can be supplied from either static or dynamic VAR sources. Static sources are typically transmission and distribution equipment, such as capacitors at substations, and their cost has historically been included in the revenue requirement of the transmission operator (TO), and recovered through cost-of-service rates. By contrast, dynamic sources are typically generators capable of producing variable levels of reactive power by automatically controlling the generator to regulate voltage. Transmission system devices such as synchronous condensers can also provide dynamic reactive power. A class of solid state devices (called flexible AC transmission system devices or FACTs) can provide dynamic reactive power. One specific device has the unfortunate name of static VAR compensator (SVC), where 'static' refers to the solid state nature of the device (it does not include rotating equipment) and not to the production of static reactive power. Dynamic sources at the distribution level, while more costly would be very useful in helping to regulate local voltage. Local voltage regulation would reduce system losses, increase circuit capacity, increase reliability, and improve efficiency. Reactive power is theoretically available from any inverter-based equipment such as photovoltaic (PV) systems, fuel cells, microturbines, and adjustable-speed drives. However, the installation is usually only economical if reactive power supply is considered during the design and construction phase. In this report, we find that if the inverters of PV systems or the generators of combined heat and power (CHP) systems were designed with capability to supply dynamic reactive power, they could do this quite economically. In fact, on an annualized basis, these inverters and generators may be able to supply dynamic reactive power for about $5 or $6 per kVAR. The savings from the local supply of dynamic reactive power would be in reduced losses, increased capacity, and decreased transmission congestion. The net savings are estimated to be about $7 per kVAR on an annualized basis for a hypothetical circuit. Thus the distribution company could economically purchase a dynamic reactive power service from customers for perhaps $6/kVAR. This practice would provide for better voltage regulation in the distribution system and would provide an alternate revenue source to help amortize the cost of PV and CHP installations. As distribution and transmission systems are operated under rising levels of stress, the value of local dynamic reactive supply is expected to grow. Also, large power inverters, in the range of 500 kW to 1 MW, are expected to decrease in cost as they become mass produced. This report provides one data point which shows that the local supply of dynamic reactive power is marginally profitable at present for a hypothetical circuit. We expect that the trends of growing power flow on the existing system and mass production of inverters for distributed energy devices will make the dynamic supply of reactive power from customers an integral component of economical and reliable system operation in the future.

  11. Geostatistical and Stochastic Study of Flow and Transport in the Unsaturated Zone at Yucca Mountain

    SciTech Connect (OSTI)

    Ye, Ming; Pan, Feng; Hu, Xiaolong; Zhu, Jianting

    2007-08-14T23:59:59.000Z

    Yucca Mountain has been proposed by the U.S. Department of Energy as the nation’s long-term, permanent geologic repository for spent nuclear fuel or high-level radioactive waste. The potential repository would be located in Yucca Mountain’s unsaturated zone (UZ), which acts as a critical natural barrier delaying arrival of radionuclides to the water table. Since radionuclide transport in groundwater can pose serious threats to human health and the environment, it is important to understand how much and how fast water and radionuclides travel through the UZ to groundwater. The UZ system consists of multiple hydrogeologic units whose hydraulic and geochemical properties exhibit systematic and random spatial variation, or heterogeneity, at multiple scales. Predictions of radionuclide transport under such complicated conditions are uncertain, and the uncertainty complicates decision making and risk analysis. This project aims at using geostatistical and stochastic methods to assess uncertainty of unsaturated flow and radionuclide transport in the UZ at Yucca Mountain. Focus of this study is parameter uncertainty of hydraulic and transport properties of the UZ. The parametric uncertainty arises since limited parameter measurements are unable to deterministically describe spatial variability of the parameters. In this project, matrix porosity, permeability and sorption coefficient of the reactive tracer (neptunium) of the UZ are treated as random variables. Corresponding propagation of parametric uncertainty is quantitatively measured using mean, variance, 5th and 95th percentiles of simulated state variables (e.g., saturation, capillary pressure, percolation flux, and travel time). These statistics are evaluated using a Monte Carlo method, in which a three-dimensional flow and transport model implemented using the TOUGH2 code is executed with multiple parameter realizations of the random model parameters. The project specifically studies uncertainty of unsaturated flow and radionuclide transport caused by multi-scale heterogeneity at the layer and local scales. Typically, in studies of Yucca Mountain, the layer scale refers to hydrogeologic layers with layer-wise average properties, and the local scale refers to the spatial variation of hydraulic properties within a layer. While most studies of radionuclide transport in the UZ have been conducted at the layer scale, the uncertainty at the local scale within a layer is also important, since it affects flow path, velocity, and travel time of radionuclide. This report first presents the uncertainty caused by layer-scale heterogeneity of matrix permeability, porosity, and sorption coefficients of reactive tracers. Homogeneous fields of the parameters are generated at each hydrogeologic layer for Monte Carlo simulations. This study is referred to as the homogeneous case. To assess the uncertainty caused by local-scale heterogeneity, the sequential Gaussian simulator (SGSIM) of GSLIB (Deutsch and Journel, 1998) is used to generate heterogeneous parameter fields within each layer, and Monte Carlo simulations are conducted. This study is referred to as the heterogeneous cases. For the homogeneous and heterogeneous cases, the mean, variance, 5th and 95th percentiles of simulated state variables are estimated for uncertainty assessment. In addition, the statistics of the two cases are compared to investigate effect of local-scale heterogeneity on the unsaturated flow and radionuclide transport. It is found that the local-scale heterogeneity increased the predictive uncertainty of percolation flux and cumulative mass arrival for computational blocks below the footprint of proposed repository, whereas mean predictions are hardly affected. The local-scale heterogeneity significantly affects travel times to the water table for both conservative and reactive tracers. In the early simulation period, tracer mean travel times are delayed, whereas the influence of local-scale heterogeneity diminishes during the late simulation period. Simulated state variables in this project are more reali

  12. Electrocatalytic Reactivity for Oxygen Reduction of Palladium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

  13. Formation, characterization and reactivity of adsorbed oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

  14. Review of geochemical measurement techniques for a nuclear waste repository in bedded salt

    SciTech Connect (OSTI)

    Knauss, K.G.; Steinborn, T.L.

    1980-05-22T23:59:59.000Z

    A broad, general review is presented of geochemical measurement techniques that can provide data necessary for site selection and repository effectiveness assessment for a radioactive waste repository in bedded salt. The available measurement techniques are organized according to the parameter measured. The list of geochemical parameters include all those measurable geochemical properties of a sample whole values determine the geochemical characteristics or behavior of the system. For each technique, remarks are made pertaining to the operating principles of the measurement instrument and the purpose for which the technique is used. Attention is drawn to areas where further research and development are needed.

  15. Preclosure Monitoring and Performance Confirmation at Yucca Mountain: Applicability of Geophysical, Geohydrological, and Geochemical Methods

    E-Print Network [OSTI]

    Tsang, C.F.

    2010-01-01T23:59:59.000Z

    properties of rock and geochemical properties of rock andDynamic Elastic Properties of Sedimentary Rocks, Geophysics,since the elastic properties of rock are not affected

  16. Conservation of reactive electromagnetic energy in reactive time

    E-Print Network [OSTI]

    Kaiser, Gerald

    2015-01-01T23:59:59.000Z

    The complex Poynting theorem (CPT) is extended to a canonical time-scale domain $(t,s)$. Time-harmonic phasors are replaced by the positive-frequency parts of general fields, which extend analytically to complex time $t+is$, with $s>0$ interpreted as a time resolution scale. The real part of the extended CPT gives conservation in $t$ of a time-averaged field energy, and its imaginary part gives conservation in $s$ of a time-averaged reactive energy. In both cases, the averaging windows are determined by a Cauchy kernel of width $\\Delta t\\sim \\pm s$. This completes the time-harmonic CPT, whose imaginary part is generally supposed to be vaguely `related to' reactive energy without giving a conservation law, or even an expression, for the latter. The interpretation of $s$ as reactive time, tracking the leads and lags associated with stored capacitative and inductive energy, gives a simple explanation of the volt-ampere reactive (var) unit measuring reactive power: a var is simply one Joule per reactive second. T...

  17. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Underwood, Richard Paul (Allentown, PA); Makitka, III, Alexander (Hatfield, PA); Carolan, Michael Francis (Allentown, PA)

    2012-04-03T23:59:59.000Z

    An oxygen ion transport membrane process wherein a heated oxygen-containing gas having one or more contaminants is contacted with a reactive solid material to remove the one or more contaminants. The reactive solid material is provided as a deposit on a support. The one or more contaminant compounds in the heated oxygen-containing gas react with the reactive solid material. The contaminant-depleted oxygen-containing gas is contacted with a membrane, and oxygen is transported through the membrane to provide transported oxygen.

  18. Remediation of Uranium in the Hanford Vadose Zone Using Gas-Transported Reactants: Laboratory Scale Experiments in Support of the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau

    SciTech Connect (OSTI)

    Szecsody, James E.; Truex, Michael J.; Zhong, Lirong; Williams, Mark D.; Resch, Charles T.; McKinley, James P.

    2010-01-04T23:59:59.000Z

    This laboratory-scale investigation is focused on decreasing mobility of uranium in subsurface contaminated sediments in the vadose zone by in situ geochemical manipulation at low water content. This geochemical manipulation of the sediment surface phases included reduction, pH change (acidic and alkaline), and additions of chemicals (phosphate, ferric iron) to form specific precipitates. Reactants were advected into 1-D columns packed with Hanford 200 area U-contaminated sediment as a reactive gas (for CO2, NH3, H2S, SO2), with a 0.1% water content mist (for NaOH, Fe(III), HCl, PO4) and with a 1% water content foam (for PO4). Uranium is present in the sediment in multiple phases that include (in decreasing mobility): aqueous U(VI) complexes, adsorbed U, reduced U(IV) precipitates, rind-carbonates, total carbonates, oxides, silicates, phosphates, and in vanadate minerals. Geochemical changes were evaluated in the ability to change the mixture of surface U phases to less mobile forms, as defined by a series of liquid extractions that dissolve progressively less soluble phases. Although liquid extractions provide some useful information as to the generalized uranium surface phases (and are considered operational definitions of extracted phases), positive identification (by x-ray diffraction, electron microprobe, other techniques) was also used to positively identify U phases and effects of treatment. Some of the changes in U mobility directly involve U phases, whereas other changes result in precipitate coatings on U surface phases. The long-term implication of the U surface phase changes to alter U mass mobility in the vadose zone was then investigated using simulations of 1-D infiltration and downward migration of six U phases to the water table. In terms of the short-term decrease in U mobility (in decreasing order), NH3, NaOH mist, CO2, HCl mist, and Fe(III) mist showed 20% to 35% change in U surface phases. Phosphate addition (mist or foam advected) showed inconsistent change in aqueous and adsorbed U, but significant coating (likely phosphates) on U-carbonates. The two reductive gas treatments (H2S and SO2) showed little change. For long-term decrease in U reduction, mineral phases created that had low solubility (phosphates, silicates) were desired, so NH3, phosphates (mist and foam delivered), and NaOH mist showed the greatest formation of these minerals. In addition, simulations showed the greatest decrease in U mass transport time to reach groundwater (and concentration) for these silicate/phosphate minerals. Advection of reactive gasses was the easiest to implement at the laboratory scale (and presumably field scale). Both mist and foam advection show promise and need further development, but current implementation move reactants shorter distances relative to reactive gasses. Overall, the ammonia and carbon dioxide gas had the greatest overall geochemical performance and ability to implement at field scale. Corresponding mist-delivered technologies (NaOH mist for ammonia and HCl mist for carbon dioxide) performed as well or better geochemically, but are not as easily upscaled. Phosphate delivery by mist was rated slightly higher than by foam delivery simply due to the complexity of foam injection and unknown effect of U mobility by the presence of the surfactant.

  19. Fuel Temperature Coefficient of Reactivity

    SciTech Connect (OSTI)

    Loewe, W.E.

    2001-07-31T23:59:59.000Z

    A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

  20. Surface and Subsurface Geochemical Monitoring of an EOR-CO2 Field: Buracica, Brazil

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Surface and Subsurface Geochemical Monitoring of an EOR-CO2 Field: Buracica, Brazil C. Magnier1, V Monitoring of an EOR-CO2 Field: Buracica, Brazil -- This paper presents a surface and subsurface geochemical survey of the Buracica EOR-CO2 field onshore Brazil. We adopted a methodology coupling the stable

  1. MULTI-SCALE ANALYSIS OF MULTIPARAMETER GEOPHYSICAL AND GEOCHEMICAL DATA FROM

    E-Print Network [OSTI]

    Williams-Jones, Glyn

    MULTI-SCALE ANALYSIS OF MULTIPARAMETER GEOPHYSICAL AND GEOCHEMICAL DATA FROM ACTIVE VOLCANIC Name: MAURI Guillaume Degree: PhD of Science Title of Thesis: Multi-scale analysis of multiparameter geophysical and geochemical data from active volcanic systems Examining Committee: Chair: Dr John Clague

  2. Geochemical responses in peat groundwater over Attawapiskat kimberlites, James Bay Lowlands, Canada and their application to

    E-Print Network [OSTI]

    Geochemical responses in peat groundwater over Attawapiskat kimberlites, James Bay Lowlands, Canada.sader@mmg.com) ABSTRACT: Peat groundwater compositions at depths of 0.4 and 1.1 m below ground surface in the Attawapiskat on hydrogeological measurements and variations in peat groundwater geochemical parameters (pH and EC are high

  3. Hydrological and geochemical investigations of selenium behavior at Kesterson Reservoir

    SciTech Connect (OSTI)

    Benson, S.M.; Tokunaga, T.K.; Zawislanski, P.; Yee, A.W.; Daggett, J.S.; Oldfather, J.M.; Tsao, L.; Johannis, P.W.

    1990-10-01T23:59:59.000Z

    From 1985 to the present we have studied the behavior of selenium in various habitats and environments at Kesterson reservoir, shifting emphasis as remedial actions altered the physical setting. Investigations have evaluated the efficacy of several remedial alternatives, from innovative techniques relying on the complex geochemical behavior of selenium alternatives, from innovative techniques relying on the complex geochemical behavior of selenium in aquatic environments to conventional excavation schemes. Results of these studies supported two cost-effective remedial measures; drain water deliveries were terminated in 1986 and, in 1988, 1 million cubic yards of soil were imported and used to fill the low lying areas of the former Kesterson Reservoir. To date, these two actions appear to have eliminated the aquatic habitat that caused waterfowl death and deformity at Kesterson from the early 1980's to 1987. Biological, surface water and groundwater monitoring data collected by the USBR indicate that Kesterson is now a much safer environment than in past years when drainage water containing 300{mu}g/l of selenium was delivered to the Reservoir. The continued presence of a large inventory of selenium within the upper portions of unfilled areas of Kesterson Reservoir and immediately below the fill material requires that a continued awareness of the status of this inventory be maintained and improved upon. 83 refs., 130 figs., 19 tabs.

  4. GEOCENTRIFUGE STUDIES OF FLOW AND TRANSPORT IN POROUS MEDIA, FINAL REPORT FOR GRANT NUMBER DE-FG02-03ER63567 TO THE UNIVERSITY OF IDAHO (RW SMITH), ENVIRONMENTAL MANAGEMENT SCIENCE PROGRAM PROJECT NUMBER 86598, COUPLED FLOW AND REACTIVITY IN VARIABLY SATURATED POROUS MEDIA

    SciTech Connect (OSTI)

    Robert W. Smith; Carl D. Palmer; Earl D. Mattson

    2007-06-15T23:59:59.000Z

    Improved models of contaminant migration in heterogeneous, variably saturated porous media are required to better define the long-term stewardship requirements for U.S. Department of Energy (DOE) lands and to assist in the design of effective vadose-zone barriers to contaminant migrations. The development of these improved models requires field and laboratory results to evaluate their efficacy. However, controlled laboratory experiments simulating vadose conditions can require extensive period of time, and often are conducted at condition near saturation rather than the much drier conditions common in many contaminated arid vadose zone sites. Collaborative research undertaken by the Idaho National Laboratory (INL) and the University of Idaho as part of this Environmental Management Science Program project focused on the development and evaluation of geocentrifuge techniques and equipment that allows vadose zone experiments to be conducted for relevant conditions in time frames not possible in conventional bench top experiments. A key and novel aspect of the research was the use of the 2-meter radius geocentrifuge capabilities at the Idaho National Laboratory to conduct unsaturated transport experiments. Specifically, the following activities were conducted ** Reviewing of the theory of unsaturated flow in the geocentrifuge to establish the range of centrifuge accelerations/experimental conditions and the translation of centrifuge results to 1 gravity applications. ** Designing, constructing, and testing of in-flight experimental apparatus allowing the replication of traditional bench top unsaturated transport experiments on the geocentrifuge. ** Performing unsaturated 1-dimenstional column geocentrifuge experiments using conservative tracers to evaluate the effects of increased centrifugal acceleration on derived transport properties and assessing the scaling relationships for these properties. Because the application of geocentrifuge techniques to vadose transport is in its infancy experimental apparatus such as pumps, flow meters, columns, fraction collectors, etc. that would reliably function under the increased self weight experienced on the centrifuge had to be developed and tested as part of this project. Although, we initially planed to conduct experiments using reactive tracer and 2-dimensional heterogeneities, the cost and time associated with designing, building, and testing of experimental apparatus limited our experimental program to conservative tracer experiments using 1-dimensional columns. The results we obtained in this study indicate that the geocentrifuge technique is a viable experimental method for the study of subsurface processes where gravitational acceleration is important. The geocentrifuge allows experiments to be completed more quickly than tests conducted at 1-g, can be used to experimentally address important scaling issues, and permits experiments under a range of conditions that would be difficult or impossible using conventional approaches. The application of the geocentrifuge approaches and associated models developed in this project allows more meaningful investigation of DOE relevant vadose-zone issues under scalable conditions in time frames previously not obtainable.

  5. Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers

    SciTech Connect (OSTI)

    Wu, Yu-Shu; Chen, Zizhong; Kazemi, Hossein; Yin, Xiaolong; Pruess, Karsten; Oldenburg, Curt; Winterfeld, Philip; Zhang, Ronglei

    2014-09-30T23:59:59.000Z

    This report is the final scientific one for the award DE- FE0000988 entitled “Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers.” The work has been divided into six tasks. In task, “Development of a Three-Phase Non-Isothermal CO2 Flow Module,” we developed a fluid property module for brine-CO2 mixtures designed to handle all possible phase combinations of aqueous phase, sub-critical liquid and gaseous CO2, supercritical CO2, and solid salt. The thermodynamic and thermophysical properties of brine-CO2 mixtures (density, viscosity, and specific enthalpy of fluid phases; partitioning of mass components among the different phases) use the same correlations as an earlier fluid property module that does not distinguish between gaseous and liquid CO2-rich phases. We verified the fluid property module using two leakage scenarios, one that involves CO2 migration up a blind fault and subsequent accumulation in a secondary “parasitic” reservoir at shallower depth, and another investigating leakage of CO2 from a deep storage reservoir along a vertical fault zone. In task, “Development of a Rock Mechanical Module,” we developed a massively parallel reservoir simulator for modeling THM processes in porous media brine aquifers. We derived, from the fundamental equations describing deformation of porous elastic media, a momentum conservation equation relating mean stress, pressure, and temperature, and incorporated it alongside the mass and energy conservation equations from the TOUGH2 formulation, the starting point for the simulator. In addition, rock properties, namely permeability and porosity, are functions of effective stress and other variables that are obtained from the literature. We verified the simulator formulation and numerical implementation using analytical solutions and example problems from the literature. For the former, we matched a one-dimensional consolidation problem and a two-dimensional simulation of the Mandel-Cryer effect. For the latter, we obtained a good match of temperature and gas saturation profiles, and surface uplift, after injection of hot fluid into a model of a caldera structure. In task, “Incorporation of Geochemical Reactions of Selected Important Species,” we developed a novel mathematical model of THMC processes in porous and fractured saline aquifers, simulating geo-chemical reactions associated with CO2 sequestration in saline aquifers. Two computational frameworks, sequentially coupled and fully coupled, were used to simulate the reactions and transport. We verified capabilities of the THMC model to treat complex THMC processes during CO2 sequestration by analytical solutions and we constructed reactive transport models to analyze the THMC process quantitatively. Three of these are 1D reactive transport under chemical equilibrium, a batch reaction model with equilibrium chemical reactions, and a THMC model with CO2 dissolution. In task “Study of Instability in CO2 Dissolution-Diffusion-Convection Processes,” We reviewed literature related to the study of density driven convective flows and on the instability of CO2 dissolution-diffusion-convection processes. We ran simulations that model the density-driven flow instability that would occur during CO2 sequestration. CO2 diffused through the top of the system and dissolved in the aqueous phase there, increasing its density. Density fingers formed along the top boundary, and coalesced into a few prominent ones, causing convective flow that forced the fluid to the system bottom. These simulations were in two and three dimensions. We ran additional simulations of convective mixing with density contrast caused by variable dissolved CO2 concentration in saline water, modeled after laboratory experiments in which supercritical CO2 was circulated in the headspace above a brine saturated packed sand in a pressure vessel. As CO2 dissolved into the upper part of the saturated sand, liquid phase density increases causing instability and setting off convective mixing. We obtained good agreement

  6. Microbial controls on contaminant metal transport in porous media 

    E-Print Network [OSTI]

    Kapetas, Leon

    2011-11-24T23:59:59.000Z

    and IOCS materials were determined through batch adsorption experiments, providing a mechanistic explanation of the adsorption process. Reactive transport models incorporating kinetics and surface complexation are developed to describe zinc movement through...

  7. Investigating the potential for long-term permeable reactive barrier (PRB) monitoring from the electrical signatures associated with the reduction in reactive iron performance

    SciTech Connect (OSTI)

    Slater, Lee; Choi, Jaeyoung

    2003-06-01T23:59:59.000Z

    The ultimate objective of this project is to quantify the ability of the electrical induced polarization (IP) method to non-invasively monitor the reduction in reactive iron performance that is known to reduce the effectiveness of the permeable reactive barrier (PRB) with time. The primary scientific goals include: (1) fundamental laboratory studies to evaluate the sensitivity of the IP method to physical/chemical changes to the iron surface resulting from oxidation, precipitation and clogging (2) monitoring of the electrical tomographic response of an installed PRB over a three-year period and assessment, via correlation with aqueous geochemical data and extracted iron cores, of whether electrical signatures associated with reduced PRB performance are resolvable in field studies (3) optimization of a three-dimensional tomographic imaging algorithm for application to highly conductive, high electrical contrast environments as represented by a PRB IP theory and empirical data resulting from the original development of the method for mineral exploration suggests that the method is highly relevant in the study of reactive iron barriers. Laboratory and field IP studies on mineral deposits illustrate the sensitivity of IP parameters to metal concentration, particle size and metal surface chemistry. IP theory, based on electrical (Warburg) impedance associated with diffusive ion transfer to/from the electrolyte to electron exchange sites on the metal surface, provides a framework for interpreting IP signatures of PRBs as a function of redox chemistry.

  8. Investigating the Potential for Long-Term Permeable Reactive Barrier (PRB) Monitoring from the Electrical Signatures Associated with the Reduction in Reactive Iron Performance

    SciTech Connect (OSTI)

    Slater, Lee

    2003-06-01T23:59:59.000Z

    The objective of this project is to quantify the ability of the electrical induced polarization (IP) method to non-invasively monitor the reduction in reactive iron performance that is known to reduce the effectiveness of the permeable reactive barrier (PRB) with time. The primary scientific goals include: (1) fundamental laboratory studies to evaluate the sensitivity of the IP method to: Fe0 total surface area Fe0 surface chemistry physical/chemical changes to the Fe0 surface resulting from oxidation and precipitation (2) monitoring of the electrical tomographic response of the Kansas City PRB over a three-year period and assessment, via correlation with aqueous geochemical data and extracted iron cores, of whether electrical signatures associated with reduced PRB performance are resolvable in field studies (3) optimization of a three-dimensional tomographic imaging algorithm for application to highly conductive, high electrical contrast environments as represented by a PRB IP theory and empirical data resulting from the original development of the method for mineral exploration suggests that the method is highly relevant in the study of reactive iron barriers. Laboratory and field IP studies on mineral deposits illustrate the sensitivity of IP parameters to metal concentration, particle size and metal surface chemistry. IP theory, based on electrical (Warburg) impedance associated with diffusive ion transfer to/from the electrolyte to electron exchange sites on the metal surface, provides a framework for interpreting IP signatures of PRBs as a function of redox chemistry.

  9. Investigating the potential for long-term permeable reactive barrier (PRB) monitoring from the electrical signatures associated with the reduction in reactive iron performance

    SciTech Connect (OSTI)

    Slater, Lee

    2003-12-19T23:59:59.000Z

    The objective of this project is to quantify the ability of the electrical induced polarization (IP) method to noninvasively monitor the reduction in reactive iron performance that is known to reduce the effectiveness of the permeable reactive barrier (PRB) with time. The primary scientific goals include: (1) fundamental laboratory studies to evaluate the sensitivity of the IP method to: Fe0 total surface area Fe0 surface chemistry physical/chemical changes to the Fe0 surface resulting from oxidation and precipitation (2) monitoring of the electrical tomographic response of the Kansas City PRB over a three-year period and assessment, via correlation with aqueous geochemical data and extracted iron cores, of whether electrical signatures associated with reduced PRB performance are resolvable in field studies (3) optimization of a three-dimensional tomographic imaging algorithm for application to highly conductive, high electrical contrast environments as represented by a PRB IP theory and empirical data resulting from the original development of the method for mineral exploration suggests that the method is highly relevant in the study of reactive iron barriers. Laboratory and field IP studies on mineral deposits illustrate the sensitivity of IP parameters to metal concentration, particle size and metal surface chemistry. IP theory, based on electrical (Warburg) impedance associated with diffusive ion transfer to/from the electrolyte to electron exchange sites on the metal surface, provides a framework for interpreting IP signatures of PRBs as a function of redox chemistry.

  10. Investigating the potential for long-term permeable reactive barrier (PRB) monitoring from the electrical signatures associated with the reduction in reactive iron performance

    SciTech Connect (OSTI)

    Slater, Lee D.; Korte, N.; Baker, J.

    2005-12-14T23:59:59.000Z

    The objective of this work was to conduct laboratory and field experiments to determine the sensitivity of low frequency electrical measurements (resistivity and induced polarization) to the processes of corrosion and precipitation that are believed to limit permeable reactive barrier (PRB) performance. The research was divided into four sets of experiments that were each written up and submitted to a peer-reviewed journal: [1] A laboratory experiment to define the controls of aqueous chemistry (electrolyte activity; pH; valence) and total zero valent iron (Fe0) available surface area on the electrical properties of Fe0 columns. [2] A laboratory experiment to determine the impact of corrosion and precipitation on the electrical response of synthetic Fe0 columns as a result of geochemical reactions with NaSO4 and NaCO3 electrolytes. [3] Laboratory experiments on a sequence of cores retrieved from the Kansas City PRB to determine the magnitude of electrical and geochemical changes within a field active PRB after eight years of operation [4] Field-scale cross borehole resistivity and induced polarization monitoring of the Kansas City PRB to evaluate the potential of electrical imaging as a technology for non-invasive, long-term monitoring of indicators of reduced PRB performance This report first summarizes the findings of the four major experiments conducted under this research. The reader is referred to the four papers in Appendices 1-4 for a full description of each experiment, including motivation and significance, technical details, findings and implications. The deliverables of the project, including the publications, conference papers and new collaborative arrangements that have resulted are then described. Appendices 5-6 contain two technical reports written by co-PI Korte describing (1) supporting geochemical measurements, and (2) the coring procedure, conducted at the Kansas City PRB as part of this project.

  11. Transport in Porous Media 37: 327346, 1999. c 1999 Kluwer Academic Publishers. Printed in the Netherlands.

    E-Print Network [OSTI]

    Clement, Prabhakar

    Transport in Porous Media 37: 327­346, 1999. c 1999 Kluwer Academic Publishers. Printed in the Netherlands. 327 A Decomposition Method for Solving Coupled Multi-Species Reactive Transport Problems YUNWEI and transport in the subsurface. In the literature, partial differential equations describing solute transport

  12. Geochemical and geomechanical effects on wellbore cement fractures

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-01-01T23:59:59.000Z

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnection of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much lower than that of CO2-saturated brine. The study suggests that in deep geological reservoirs the geochemical and geomechanical processes have coupled effects on the wellbore cement fracture evolution and fluid flow along the fracture surfaces.

  13. Chemically Reactive Working Fluids for the Capture and Transport...

    Broader source: Energy.gov (indexed) [DOE]

    Specifically, the primary heat transfer fluid (HTF), which transmits the collected solar power to power cycle Evaluate Chemically Reacting Working Fluids (CRWFs) as HTFs...

  14. Multiple Species Reactive Chemical Transport in Groundwater: A Verification Exercise

    E-Print Network [OSTI]

    Narasimhan, T.N.

    2010-01-01T23:59:59.000Z

    Institute, under Contract EPRI RP2485-19, through U.S.tract RP2485-19. References EPRI, FASTCHEM A. package, andPower Research Institute (EPRI) has sponso_-ed the develop-

  15. The semismooth Newton method for multicomponent reactive transport with minerals

    E-Print Network [OSTI]

    Kraeutle, Serge

    is that problems containing CCs (so-called complementarity problems, CPs) are well known in the field of optimization theory. In this field, it is a well known strategy to solve CPs with the semismooth Newton method essential. The article is structured as follows. In Sec. 2.1 we introduce the mineral precipitation

  16. Reactive transport modeling for CO2 geological sequestration

    E-Print Network [OSTI]

    Xu, T.

    2013-01-01T23:59:59.000Z

    of lead and arsenic on goethite, illite, kaolinite, and9.0594E-06 Kerogen-os Goethite Assumed at equilibrium pyrite

  17. Reactive facies: An approach for parameterizing field-scale reactive transport models using geophysical methods

    E-Print Network [OSTI]

    Hubbard, Susan

    Miles.denham@srnl.doe.gov 803-725-5521 Environmental Science and Biotechnology Savannah River National National Lab 1 Cyclotron Road Mail Stop 90R1116 Berkeley, CA 94720- 8126 Susan S. Hubbard 510-486-5266 SSHubbard@lbl.gov Lawrence Berkeley National Lab 1 Cyclotron Road Mail Stop 90R1116 Berkeley, CA 94720- 8126

  18. Stochastic Analysis of Advection-diffusion-Reactive Systems with Applications to Reactive Transport in Porous Media

    SciTech Connect (OSTI)

    Tartakovsky, Daniel

    2013-08-30T23:59:59.000Z

    We developed new CDF and PDF methods for solving non-linear stochastic hyperbolic equations that does not rely on linearization approximations and allows for rigorous formulation of the boundary conditions.

  19. Reactive facies: An approach for parameterizing field-scale reactive transport models using geophysical methods

    E-Print Network [OSTI]

    Sassen, D.

    2014-01-01T23:59:59.000Z

    source rock (organic rich sedimen- tary rocks versus silicate dominated igneous and metamor- phic rocks) and to differences in sediment maturity (

  20. Local Transportation

    E-Print Network [OSTI]

    Local Transportation. Transportation from the Airport to Hotel. There are two types of taxi companies that operate at the airport: special and regular taxis (

  1. Greening Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Goal 2: Greening Transportation LANL supports and encourages employees to reduce their personal greenhouse gas emissions by offering various commuting and work...

  2. Chamber transport

    SciTech Connect (OSTI)

    OLSON,CRAIG L.

    2000-05-17T23:59:59.000Z

    Heavy ion beam transport through the containment chamber plays a crucial role in all heavy ion fusion (HIF) scenarios. Here, several parameters are used to characterize the operating space for HIF beams; transport modes are assessed in relation to evolving target/accelerator requirements; results of recent relevant experiments and simulations of HIF transport are summarized; and relevant instabilities are reviewed. All transport options still exist, including (1) vacuum ballistic transport, (2) neutralized ballistic transport, and (3) channel-like transport. Presently, the European HIF program favors vacuum ballistic transport, while the US HIF program favors neutralized ballistic transport with channel-like transport as an alternate approach. Further transport research is needed to clearly guide selection of the most attractive, integrated HIF system.

  3. The hydrogeologic-geochemical model of Cerro Prieto revisited

    SciTech Connect (OSTI)

    Lippmann, M.J.; Halfman, S.E.; Truesdell, A.H.; Manon M., A.

    1989-01-01T23:59:59.000Z

    As the exploitation of the Cerro Prieto, Mexico, geothermal field continues, there is increasing evidence that the hydrogeologic model developed by Halfman et al. (1984, 1986) presents the basic features controlling the movement of geothermal fluids in the system. At the present time the total installed capacity at Cerro Prieto is 620 MWe requiring the production of more than 10,500 tonnes/hr of a brine-steam mixture. This significant rate of fluid production has resulted in changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. After reviewing the hydrogeologic-geochemical model of Cerro Prieto, some of the changes observed in the field due to its exploitation are discussed and interpreted on the basis of the model. 21 refs., 11 figs., 1 tab.

  4. WATEQ3 geochemical model: thermodynamic data for several additional solids

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01T23:59:59.000Z

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

  5. Microbiological and Geochemical Heterogeneity in an In Situ

    E-Print Network [OSTI]

    Uranium Bioremediation; Field Site; Helen A. Vrionis; Robert T. Anderson; Irene Ortiz-bernad; Kathleen R. O’neill; Philip E. Long; Derek R. Lovley

    2005-01-01T23:59:59.000Z

    The geochemistry and microbiology of a uranium-contaminated subsurface environment that had undergone two seasons of acetate addition to stimulate microbial U(VI) reduction was examined. There were distinct horizontal and vertical geochemical gradients that could be attributed in large part to the manner in which acetate was distributed in the aquifer, with more reduction of Fe(III) and sulfate occurring at greater depths and closer to the point of acetate injection. Clone libraries of 16S rRNA genes derived from sediments and groundwater indicated an enrichment of sulfate-reducing bacteria in the order Desulfobacterales in sediment and groundwater samples. These samples were collected nearest the injection gallery where microbially reducible Fe(III) oxides were highly depleted, groundwater sulfate concentrations were low, and increases in acid volatile sulfide were observed in the sediment. Further down-gradient, metal-reducing conditions were present as indicated by intermediate Fe(II)/Fe(total) ratios, lower acid volatile sulfide values, and increased abundance of 16S rRNA gene sequences belonging to the dissimilatory Fe(III)- and U(VI)-reducing family Geobacteraceae. Maximal Fe(III) and U(VI) reduction correlated with maximal recovery of Geobacteraceae 16S rRNA gene sequences in both groundwater and sediment; however, the sites at which these maxima occurred were spatially separated within the aquifer. The substantial microbial and geochemical heterogeneity at this site demonstrates that attempts should be made to deliver acetate in a more uniform manner and that closely

  6. Reactive Ion Etch Users Guide

    E-Print Network [OSTI]

    Wager, John F.

    RIE Reactive Ion Etch Users Guide Eric Sundholm 2-22-2007 Standby Condition: be sure that the tool the chamber to remove any potential hazards before the chamber can be opened. 9. Pump Down Chamber Utilities Pump Chamber 10. Check pressure to start turbo pump Display Sensor Display a. Wait for pressure

  7. Revised Knudsen-layer reduction of fusion reactivity

    SciTech Connect (OSTI)

    Albright, B. J.; Molvig, Kim; Huang, C.-K.; Simakov, A. N.; Dodd, E. S.; Hoffman, N. M.; Kagan, G. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States); Schmit, P. F. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, New Mexico 87185-1186 (United States)] [Sandia National Laboratories, P.O. Box 5800, Albuquerque, New Mexico 87185-1186 (United States)

    2013-12-15T23:59:59.000Z

    Recent work by Molvig et al. [Phys. Rev. Lett. 109, 095001 (2012)] examined how fusion reactivity may be reduced from losses of fast ions in finite assemblies of fuel. In this paper, this problem is revisited with the addition of an asymptotic boundary-layer treatment of ion kinetic losses. This boundary solution, reminiscent of the classical Milne problem from linear transport theory, obtains a free-streaming limit of fast ion losses near the boundary, where the diffusion approximation is invalid. Thermonuclear reaction rates have been obtained for the ion distribution functions predicted by this improved model. It is found that while Molvig's “Knudsen distribution function” bounds from above the magnitude of the reactivity reduction, this more accurate treatment leads to less dramatic losses of tail ions and associated reduction of thermonuclear reaction rates for finite fuel volumes.

  8. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

    2013-12-31T23:59:59.000Z

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choose the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  9. Particle Swarm Optimization Based Reactive Power Optimization

    E-Print Network [OSTI]

    Sujin, P R; Linda, M Mary

    2010-01-01T23:59:59.000Z

    Reactive power plays an important role in supporting the real power transfer by maintaining voltage stability and system reliability. It is a critical element for a transmission operator to ensure the reliability of an electric system while minimizing the cost associated with it. The traditional objectives of reactive power dispatch are focused on the technical side of reactive support such as minimization of transmission losses. Reactive power cost compensation to a generator is based on the incurred cost of its reactive power contribution less the cost of its obligation to support the active power delivery. In this paper an efficient Particle Swarm Optimization (PSO) based reactive power optimization approach is presented. The optimal reactive power dispatch problem is a nonlinear optimization problem with several constraints. The objective of the proposed PSO is to minimize the total support cost from generators and reactive compensators. It is achieved by maintaining the whole system power loss as minimum...

  10. Migratory patterns of American shad (Alosa sapidissima) revealed by natural geochemical tags in otoliths

    E-Print Network [OSTI]

    Walther, Benjamin (Benjamin Dwaine)

    2007-01-01T23:59:59.000Z

    Geochemical signatures in the otoliths of diadromous fishes may allow for retrospective analyses of natal origins. In an assessment of river-specific signatures in American shad (Alosa sapidissima), an anadromous clupeid ...

  11. Geochemical heterogeneity in the Hawaiian plume : constraints from Hawaiian volcanoes and Emperor seamounts

    E-Print Network [OSTI]

    Huang, Shichun

    2005-01-01T23:59:59.000Z

    The 6000-km long, age-progressive linear Hawaii-Emperor Chain is one of the best defined hotspot tracks. This hotspot track plays an important role in the plume hypothesis. In this research, geochemical data on the ...

  12. Up-Scaling Geochemical Reaction Rates Accompanying Acidic CO2-Saturated Brine Flow in Sandstone Aquifers

    E-Print Network [OSTI]

    New York at Stoney Brook, State University of

    1 Up-Scaling Geochemical Reaction Rates Accompanying Acidic CO2-Saturated Brine Flow in Sandstone models. As a step toward this, network flow models were used to simulate the flow of CO2-saturated brine

  13. A Geological and Hydro-Geochemical Study of the Animas Geothermal...

    Open Energy Info (EERE)

    Hydro-Geochemical Study of the Animas Geothermal Area, Hidalgo County, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Geological...

  14. The dynamics of oceanic transform faults : constraints from geophysical, geochemical, and geodynamical modeling

    E-Print Network [OSTI]

    Gregg, Patricia Michelle Marie

    2008-01-01T23:59:59.000Z

    Segmentation and crustal accretion at oceanic transform fault systems are investigated through a combination of geophysical data analysis and geodynamical and geochemical modeling. Chapter 1 examines the effect of fault ...

  15. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geochemical Behaviour of S, Cl and Fe in Silicate MeltsGlasses Simulating Natural Magmas Monday, March 26, 2012 - 11:00am SSRL Conference Room 137-322 G. Giuli, R. Alonso-Mori, E....

  16. Geochemical evidence for possible natural migration of Marcellus Formation brine to

    E-Print Network [OSTI]

    Geochemical evidence for possible natural migration of Marcellus Formation brine to shallow possible migration of Marcellus brine through naturally occurring pathways. The occurrences of saline water, because of natural hydraulic connections to deeper formations. formation water isotopes Marcellus Shale

  17. Geochemical Data Package for the 2005 Hanford Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Serne, R JEFFREY.; Kaplan, D I.

    2004-09-30T23:59:59.000Z

    CH2M HILL Hanford Group, Inc. (CH2M HILL) is designing and assessing the performance of an integrated disposal facility (IDF) to receive low-level waste (LLW), mixed low-level waste (MLLW), immobilized low-activity waste (ILAW), and failed or decommissioned melters. The CH2M HILL project to assess the performance of this disposal facility is the Hanford IDF Performance Assessment (PA) activity. The goal of the Hanford IDF PA activity is to provide a reasonable expectation that the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require prediction of contaminant migration from the facilities. This migration is expected to occur primarily via the movement of water through the facilities, and the consequent transport of dissolved contaminants in the vadose zone to groundwater where contaminants may be re-introduced to receptors via drinking water wells or mixing in the Columbia River. Pacific Northwest National Laboratory (PNNL) assists CH2M HILL in their performance assessment activities. One of the PNNL tasks is to provide estimates of the geochemical properties of the materials comprising the IDF, the disturbed region around the facility, and the physically undisturbed sediments below the facility (including the vadose zone sediments and the aquifer sediments in the upper unconfined aquifer). The geochemical properties are expressed as parameters that quantify the adsorption of contaminants and the solubility constraints that might apply for those contaminants that may exceed solubility constraints. The common parameters used to quantify adsorption and solubility are the distribution coefficient (Kd) and the thermodynamic solubility product (Ksp), respectively. In this data package, we approximate the solubility of contaminants using a more simplified construct, called the solution concentration limit, a constant value. The Kd values and solution concentration limits for each contaminant are direct inputs to subsurface flow and transport codes used to predict the performance of the IDF system. In addition to the best-estimate Kd values, a reasonable conservative value and a range are provided. The data package does not list estimates for the range in solubility limits or their uncertainty. However, the data package does provide different values for both the Kd values and solution concentration limits for different spatial zones in the IDF system and does supply time-varying Kd values for the cement solidified waste. The Kd values and solution concentration limits presented for each contaminant were previously presented in a report prepared by Kaplan and Serne (2000) for the 2001 ILAW PA, and have been updated to include applicable data from investigations completed since the issuance of that report and improvements in our understanding of the geochemistry specific to Hanford. A discussion is also included of the evolution of the Kd values recommended from the original 1999 ILAW PA through the 2001 ILAW and 2003 Supplement PAs to the current values to be used for the 2005 IDF PA for the key contaminants of concern: Cr(VI), nitrate, 129I, 79Se, 99Tc, and U(VI). This discussion provides the rationale for why certain Kd have changed with time.

  18. X-ray microtomography characterization of porosity, permeability and reactive surface changes during dissolution

    E-Print Network [OSTI]

    Luquot, Linda

    tools for predicting reservoir properties changes triggered by CO2 underground injection. At reservoir­precipitation problem and of the feedback effects of these processes on the flow field is still challenging. The problem.V. All rights reserved. Keywords: Reactive transport Carbon storage Permeability X-ray microtomography 1

  19. A Numerical Model for Miscible Displacement of Multi-Component Reactive Species

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . Azarouala a Water Department/Groundwater and Geochemistry Modeling, BRGM (French Geological Survey) 3 of our approach. Therefore, the model may prove useful for many practical applications. 1. INTRODUCTION Demands to undertake modeling analysis of coupled groundwater ow, solute transport, and reactive water

  20. Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH

    E-Print Network [OSTI]

    Goddard III, William A.

    range transport mechanism of Al during the dissociation process. Briefly, the conventional (de to accurately predict the dynamical and reactive processes in hydrocarbons [2], sihcon/sihcon oxides [3 for hydrocarbons[5], ReaxFF has been successfully applied to study Si/Si02 interfaces[3], MgH2 systems and Al

  1. Reactive composite compositions and mat barriers

    DOE Patents [OSTI]

    Langton, Christine A. (Aiken, SC); Narasimhan, Rajendran (Evans, GA); Karraker, David G. (Aiken, SC)

    2001-01-01T23:59:59.000Z

    A hazardous material storage area has a reactive multi-layer composite mat which lines an opening into which a reactive backfill and hazardous material are placed. A water-inhibiting cap may cover the hazardous material storage area. The reactive multi-layer composite mat has a backing onto which is placed an active layer which will neutralize or stabilize hazardous waste and a fronting layer so that the active layer is between the fronting and backing layers. The reactive backfill has a reactive agent which can stabilize or neutralize hazardous material and inhibit the movement of the hazardous material through the hazardous material storage area.

  2. Low Reactivity SI Engine Lubricant Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomy andTerms LoanLos AngelesGuillermo10Reactivity SI

  3. Microbiological and geochemical characterization of fluvially deposited sulfidic mine tailings

    SciTech Connect (OSTI)

    Wielinga, B.; Lucy, J.K.; Moore, J.N.; Seastone, O.F.; Gannon, J.E. [Univ. of Montana, Missoula, MT (United States)

    1999-04-01T23:59:59.000Z

    The fluvial deposition of mine tailings generated from historic mining operations near Butte, Montana, has resulted in substantial surface and shallow groundwater contamination along Silver Bow Creek. Biogeochemical processes in the sediment and underlying hyporheic zone were studied in an attempt to characterize interactions consequential to heavy-metal contamination of shallow groundwater. Sediment cores were extracted and fractionated based on sediment stratification. Subsamples of each fraction were assayed for culturable heterotrophic microbiota, specific microbial guilds involved in metal redox transformations, and both aqueous- and solid-phase geochemistry. Populations of cultivable Fe(III)-reducing bacteria were most prominent in the anoxic, circumneutral pH regions associated with a ferricrete layer or in an oxic zone high in organic carbon and soluble iron. Sulfur- and iron-oxidizing bacteria were distributed in discrete zones throughout the tailings and were often recovered from sections at and below the anoxic groundwater interface. Sulfate-reducing bacteria were also widely distributed in the cores and often occurred in zones overlapping iron and sulfur oxidizers. Sulfate-reducing bacteria were consistently recovered from oxic zones that contained high concentrations of metals in the oxidizable fraction. Altogether, these results suggest a highly varied and complex microbial ecology within a very heterogeneous geochemical environment. Such physical and biological heterogeneity has often been overlooked when remediation strategies for metal contaminated environments are formulated.

  4. Generalized solution to multi-dimensional multi-species transport equations coupled with a first-order reaction

    E-Print Network [OSTI]

    Clement, Prabhakar

    Generalized solution to multi-dimensional multi-species transport equations coupled with a first-species reactive transport equations. The new method can be used for solving multi-species transport problems transport problem. In addition, three one-dimensional problems and two three-dimensional problems are solved

  5. Final Report: Molecular Basis for Microbial Adhesion and Geochemical Surface Reactions: A Study Across Scales

    SciTech Connect (OSTI)

    Dixon, David Adams [The University of Alabama

    2013-06-27T23:59:59.000Z

    Computational chemistry was used to help provide a molecular level description of the interactions of Gram-negative microbial membranes with subsurface materials. The goal is to develop a better understanding of the molecular processes involved in microbial metal binding, microbial attachment to mineral surfaces, and, eventually, oxidation/reduction reactions (electron transfer) that can occur at these surfaces and are mediated by the bacterial exterior surface. The project focused on the interaction of the outer microbial membrane, which is dominated by an exterior lipopolysaccharide (LPS) portion, of Pseudomonas aeruginosa with the mineral goethite and with solvated ions in the environment. This was originally a collaborative project with T.P. Straatsma and B. Lowery of the Pacific Northwest National Laboratory. The University of Alabama effort used electronic structure calculations to predict the molecular behavior of ions in solution and the behavior of the sugars which form a critical part of the LPS. The interactions of the sugars with metal ions are expected to dominate much of the microscopic structure and transport phenomena in the LPS. This work, in combination with the molecular dynamics simulations of Straatsma and the experimental electrochemistry and microscopy measurements of Lowry, both at PNNL, is providing new insights into the detailed molecular behavior of these membranes in geochemical environments. The effort at The University of Alabama has three components: solvation energies and structures of ions in solution, prediction of the acidity of the critical groups in the sugars in the LPS, and binding of metal ions to the sugar anions. An important aspect of the structure of the LPS membrane as well as ion transport in the LPS is the ability of the sugar side groups such as the carboxylic acids and the phosphates to bind positively charged ions. We are studying the acidity of the acidic side groups in order to better understand the ability of these groups to bind metal ions. We need to understand the solvation properties of the metal ions in solution and their ability to bind not only to the sugars but to proteins and to other anions. Our goal is then to be able to predict the ability of the side groups to bind metal ions. One result from the earlier molecular dynamics simulations is the exclusion of water from the inner hydrophobic part of the membrane. We thus need to investigate the binding of the cations in media with different dielectric constants.

  6. Layered reactive particles with controlled geometries, energies, and reactivities, and methods for making the same

    DOE Patents [OSTI]

    Fritz, Gregory M; Knepper, Robert Allen; Weihs, Timothy P; Gash, Alexander E; Sze, John S

    2013-04-30T23:59:59.000Z

    An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.

  7. Origin and geochemical evolution of the Michigan basin brine

    SciTech Connect (OSTI)

    Wilson, T.P.

    1989-01-01T23:59:59.000Z

    Chemical and isotopic data were collected on 126 oil field brine samples and were used to investigate the origin and geochemical evolution of water in 8 geologic formations in the Michigan basin. Two groups of brine are found in the basin, the Na-Ca-Cl brine in the upper Devonian formations, and Ca-Na-Cl brine from the lower Devonian and Silurian aged formations. Water in the upper Devonian Berea, Traverse, and Dundee formations originated from seawater concentrated into halite facies. This brine evolved by halite precipitation, dolomitization, aluminosilicate reactions, and the removal of SO{sub 4} by bacterial action or by CaSO{sub 4} precipitation. The stable isotopic composition (D, O) is thought to represent dilution of evapo-concentrated seawater by meteoric water. Water in the lower Devonian Richfield, Detroit River Group, and Niagara-Salina formations is very saline Ca-Na-Cl brine. Cl/Br suggest it originated from seawater concentrated through the halite and into the MgSO{sub 4} salt facies, with an origin linked to the Silurian and Devonian salt deposits. Dolomitization and halite precipitation increased the Ca/Na, aluminosilicate reactions removed K, and bacterial action or CaSO{sub 4} precipitation removed SO{sub 4} from this brine. Water chemistry in the Ordovician Trenton-Black River formations indicates dilution of evapo-concentrated seawater by fresh or seawater. Possible saline end-members include Ordovician seawater, present-day upper Devonian brine, or Ca-Cl brine from the deeper areas in the basin.

  8. Permeable Reactive Barriers | Department of Energy

    Energy Savers [EERE]

    in the barrier, a chemical reaction occurs with the barrier material that results in adsorption, mineral precipitation, or degradation to a harmless compound. Reactive barriers...

  9. Rejuvenating Permeable Reactive Barriers by Chemical Flushing

    Broader source: Energy.gov [DOE]

    Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

  10. UNDERGRADUATE FELLOWSHIP RECIPIENTS: Stephanie Freeman -Permanent Reactive

    E-Print Network [OSTI]

    Fay, Noah

    55 2003 UNDERGRADUATE FELLOWSHIP RECIPIENTS: Stephanie Freeman - Permanent Reactive Bio Engineering Andrew Hinnell - Improving Electrical Resistivity Tomography for Characterization of Non

  11. Comparison of Conventional Diesel and Reactivity Controlled...

    Broader source: Energy.gov (indexed) [DOE]

    DEER 10182012 Comparison of Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI) Combustion in a Light-Duty Engine Rolf D. Reitz and Sage L. Kokjohn Engine...

  12. Characterization and Reactivity of Iron Nanoparticles Prepared...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    engineered remediation systems. However, the structural characteristics of the metal additives and mechanism responsible for changes in reactivity have not been fully elucidated....

  13. Exploring the reactivity of bacterial multicomponent monooxygenases

    E-Print Network [OSTI]

    Tinberg, Christine Elaine

    2010-01-01T23:59:59.000Z

    Chapter 1. Introduction: The Reactivity of Bacterial Multicomponent Monooxygenases Bacterial multicomponent monooxygenases constitute a remarkable family of enzymes that oxidize small, inert hydrocarbon substrates using ...

  14. Demonstration/Development of Reactivity Controlled Compression...

    Broader source: Energy.gov (indexed) [DOE]

    DemonstrationDevelopment of Reactivity Controlled Compression Ignition (RCCI) Combustion for High Efficiency, Low Emissions Vehicle Applications Dr. Rolf Reitz Wisconsin Engine...

  15. Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Anderson, Raymond P. (Idaho Falls, ID)

    2008-08-05T23:59:59.000Z

    A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.

  16. Reactive and non-reactive interactions of thiophene with WS2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interactions of thiophene with WS2 fullerene-like nanoparticles: an ultra-high vacuum surface Reactive and non-reactive interactions of thiophene with WS2 fullerene-like...

  17. Internal neutronics-temperature coupling in Serpent 2 - Reactivity differences resulting from choice of material property correlations

    SciTech Connect (OSTI)

    Valtavirta, V. [VTT Technical Research Centre of Finland, P.O. Box 1000, FI-02044 VTT (Finland)

    2013-07-01T23:59:59.000Z

    This paper describes the unique way of simultaneously solving the power and temperature distributions of a nuclear system with the Monte Carlo neutron transport code Serpent 2. The coupled solution is achieved through the implementation of an internal temperature solver and material property correlations in the code. The program structure is reviewed concerning the temperature solver and the internal correlations as well as the internal coupling between these two and the neutron transport part. To estimate the reactivity differences resulting from correlation choices a simple pin-cell case has been calculated. It is established, that some correlation choices may result in difference in reactivity of approximately 100 pcm. (authors)

  18. Coupled modeling of groundwater flow solute transport, chemical reactions and microbial processes in the 'SP' island

    SciTech Connect (OSTI)

    Samper, Javier; Molinero, Jorg; Changbing, Yang; Zhang, Guoxiang

    2003-12-01T23:59:59.000Z

    The Redox Zone Experiment was carried out at the Aespoe HRL in order to study the redox behavior and the hydrochemistry of an isolated vertical fracture zone disturbed by the excavation of an access tunnel. Overall results and interpretation of the Redox Zone Project were reported by /Banwart et al, 1995/. Later, /Banwart et al, 1999/ presented a summary of the hydrochemistry of the Redox Zone Experiment. Coupled groundwater flow and reactive transport models of this experiment were carried out by /Molinero, 2000/ who proposed a revised conceptual model for the hydrogeology of the Redox Zone Experiment which could explain simultaneously measured drawdown and salinity data. The numerical model was found useful to understand the natural system. Several conclusions were drawn about the redox conditions of recharge waters, cation exchange capacity of the fracture zone and the role of mineral phases such as pyrite, calcite, hematite and goethite. This model could reproduce the measured trends of dissolved species, except for bicarbonate and sulfate which are affected by microbially-mediated processes. In order to explore the role of microbial processes, a coupled numerical model has been constructed which accounts for water flow, reactive transport and microbial processes. The results of this model is presented in this report. This model accounts for groundwater flow and reactive transport in a manner similar to that of /Molinero, 2000/ and extends the preliminary microbial model of /Zhang, 2001/ by accounting for microbially-driven organic matter fermentation and organic matter oxidation. This updated microbial model considers simultaneously the fermentation of particulate organic matter by yeast and the oxidation of dissolved organic matter, a product of fermentation. Dissolved organic matter is produced by yeast and serves also as a substrate for iron-reducing bacteria. Model results reproduce the observed increase in bicarbonate and sulfate concentration, thus adding additional evidence for the possibility of organic matter oxidation as the main source of bicarbonate. Model results indicate that pH and Eh are relatively stable. The dissolution-precipitation trends of hematite, pyrite and calcite also coincide with those indicated by the conceptual model. A thorough sensitivity analysis has been performed for the most relevant microbial parameters as well as for initial and boundary POC and DOC concentrations. The results of such analysis indicate that computed concentrations of bicarbonate, sulfate and DOC are sensitive to most of the microbial parameters, including specific growth rates, half-saturation constants, proportionality coefficients and yield coefficients. Model results, however, are less sensitive to the yield coefficient of DOC to iron-reducer bacteria. The sensitivity analysis indicates that changes in fermentation microbial parameters affect the growth of the iron-reducer, thus confirming the interconnection of both microbial processes. Computed concentrations of bicarbonate and sulfate are found to be sensitive to changes in the initial concentration of POC and the boundary concentration of DOC, but they lack sensitivity to the initial concentration of DOC and the boundary concentration of POC. The explanation for such result is related to the fact that POC has a low mobility due to its large molecular weight. DOC, however, can migrate downwards. Although a coupled hydro-bio-geochemical 1-D model can reproduce the observed ''unexpected'' increase of concentrations of bicarbonate and sulfate at a depth of 70 m, further modeling work is required in order to obtain a similar conclusion under the more realistic two dimensional conditions of the fracture zone.

  19. Computational Transportation

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    ), in-vehicle computers, and computers in the transportation infrastructure are integrated ride- sharing, real-time multi-modal routing and navigation, to autonomous/assisted driving

  20. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    SciTech Connect (OSTI)

    Zheng, L.; Spycher, N.; Xu, T.; Apps, J.; Kharaka, Y.; Birkholzer, J.T.

    2010-11-05T23:59:59.000Z

    In this study, reactive transport simulations were used to assess the mobilization and transport of organics with supercritical CO{sub 2} (SCC), and the co-injection and transport of H{sub 2}S with SCC. These processes were evaluated at conditions of typical storage reservoirs, and for cases of hypothetical leakage from a reservoir to an overlying shallower fresh water aquifer. Modeling capabilities were developed to allow the simulation of multiphase flow and transport of H{sub 2}O, CO{sub 2}, H{sub 2}S, as well as specific organic compounds (benzene), coupled with multicomponent geochemical reaction and transport. This included the development of a new simulator, TMVOC-REACT, starting from existing modules of the TOUGH2 family of codes. This work also included an extensive literature review, calculation, and testing of phase-partitioning properties for mixtures of the phases considered. The reactive transport simulations presented in this report are primarily intended to illustrate the capabilities of the new simulator. They are also intended to help evaluate and understand various processes at play, in a more qualitative than quantitative manner, and only for hypothetical scenarios. Therefore, model results are not intended as realistic assessments of groundwater quality changes for specific locations, and they certainly do not provide an exhaustive evaluation of all possible site conditions, especially given the large variability and uncertainty in hydrogeologic and geochemical parameter input into simulations. The first step in evaluating the potential mobilization and transport of organics was the identification of compounds likely to be present in deep storage formations, and likely to negatively impact freshwater aquifers if mobilized by SCC. On the basis of a literature review related to the occurrence of these organic compounds, their solubility in water and SCC, and their toxicity (as reflected by their maximum contaminant levels MCL), benzene was selected as a key compound for inclusion into numerical simulations. Note that considering additional organic compounds and/or mixtures of such compounds in the simulations was beyond the scope of this study, because of the effort required to research, calculate, and validate the phase-partitioning data necessary for simulations. The injection of CO{sub 2} into a deep saline aquifer was simulated, followed by modeling the leaching of benzene by SCC and transport of benzene to an overlying aquifer along a hypothetical leakage pathway. One- and two-dimensional models were set up for this purpose. The target storage formation was assumed to initially contain about 10{sup -4} ppm benzene. Model results indicate that: (1) SCC efficiently extracts benzene from the storage formation. (2) Assuming equilibrium, the content of benzene in SCC is roportional to the concentration of benzene in the aqueous and solid phases. (3) Benzene may co-migrate with CO{sub 2} into overlying aquifers if a leakage pathway is present. Because the aqueous solubility of benzene in contact with CO{sub 2} is lower than the aqueous solubility of CO{sub 2}, benzene is actually enriched in the CO{sub 2} phase as the plume advances. (4) For the case studied here, the resulting aqueous benzene concentration in the overlying aquifer is on the same order of magnitude as the initial concentration in the storage formation. This generic modeling study illustrates, in a semi-quantitative manner, the possible mobilization of benzene by SCC. The extent to which the mobilization of this organic compound evolves temporally and spatially depends on a large number of controlling parameters and is largely site specific. Therefore, for more 'truly' predictive work, further sensitivity studies should be conducted, and further modeling should be integrated with site-specific laboratory and/or field experimental data. The co-injection of H{sub 2}S with CO{sub 2} into a deep saline aquifer was also simulated. In addition, the model considered leakage of the supercritical CO{sub 2}+H{sub 2}S mixture along a preferential p

  1. Reactive Power Support Services in Electricity Markets

    E-Print Network [OSTI]

    Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Reactive Power Support Services in Electricity Markets Costing and Pricing of Ancillary Services Project this Project For information about this project contact: Peter W. Sauer, Project Leader Professor Electrical

  2. REACTIVE LOAD MODELINGIMPACTS ONNODAL PRICESINPOOL MODELELECTRICITYMARKETS

    E-Print Network [OSTI]

    Gross, George

    REACTIVE LOAD MODELINGIMPACTS ONNODAL PRICESINPOOL MODELELECTRICITYMARKETS EttoreBompard, Enrico of the nodal prices in competitive electricity markets based on the Pool paradigm. Such prices focus of the paper is on the explicit evaluation of the impactsof the reactive load onthenodal real

  3. REACTIVE ENVIRONMENTS AND AUGMENTED MEDIA SPACES

    E-Print Network [OSTI]

    Cooperstock, Jeremy R.

    REACTIVE ENVIRONMENTS AND AUGMENTED MEDIA SPACES by Jeremy R. Cooperstock A thesis submitted in conformity with the requirements for the degree of Doctor of Philosophy Graduate Department of Electrical and Computer Engineering University of Toronto © Copyright by Jeremy R. Cooperstock, 1996 #12;ii REACTIVE

  4. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

    2011-03-15T23:59:59.000Z

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  5. Transportation Market Distortions

    E-Print Network [OSTI]

    Litman, Todd

    2006-01-01T23:59:59.000Z

    of Highways, Volpe National Transportation Systems Center (Evaluating Criticism of Transportation Costing, VictoriaFrom Here: Evaluating Transportation Diversity, Victoria

  6. Geochemical comparison of impact glasses from lunar meteorites ALHA81005 and MAC88105 and Apollo 16 regolith 64001

    SciTech Connect (OSTI)

    Delano, J.W. (State Univ. of New York, Albany (United States))

    1991-11-01T23:59:59.000Z

    Most glasses that occur in lunar highland regolith are quenched droplets of impact melt. The chemical compositions of these glasses are equivalent, in the absence of volatile losses, to the original target materials. The compositional range of impact glasses in a regolith reflects the chemical diversity that existed throughout the region up to the time of system closure (e.g., breccia formation). Since these glasses are a product of widespread and random sampling, both in terms of space and time, they can be used for geochemical exploration of the Moon. The major-element compositions of impact glasses occurring in three samples of lunar feldspathic regolith (ALHA81005; MAC88105; Apollo 16 64001) have been determined by electron microprobe. The glass populations among these three unrelated samples are compositionally distinct. While most of the impact glasses within each of these three samples are compositionally similar to the regolith in which they are found, up to 40% of the impact glasses are different. Some of the compositionally exotic glasses were ballistically transported from other areas of the Moon and thereby provide information about the compositional range of regoliths that exist elsewhere. Since the geological setting of the Apollo 16 region is well known compared to the source areas of the lunar meteorites, the Apollo 16 glasses provide a ground truth for interpretations.

  7. Reactivity worth measurements at the IPEN/MB-01 nuclear reactor

    SciTech Connect (OSTI)

    Pinto, Leticia Negrao; Santos, Adimir dos [Nuclear Engineering Center, Nuclear and Energy Research Institute- IPEN/CNEN-SP (Brazil)

    2013-05-06T23:59:59.000Z

    Researches that aim to improve the performance of neutron transport codes and quality of nuclear cross section databases are very important to increase the accuracy of simulations and the quality of the analysis and prediction of phenomena in the nuclear field. In this context, relevant experimental data such as reactivity worth measurements are needed. The objective of this work was to perform a series of experiments of reactivity worth measurements, using a digital reactivity meter developed at IPEN. The experiments employed small metallic and ceramic samples inserted in the central region of the core of the experimental IPEN/MB-01 reactor. The theoretical analysis was performed by the MCNP-5 reactor physics code, developed and maintained by Los Alamos National Laboratory, and the ENDF/B-VII.0 nuclear data library.

  8. Reactive Support and Voltage Control Service: Key Issues and Challenges

    E-Print Network [OSTI]

    Gross, George

    reactive support and voltage control services. Keywords ­ Competitive Electricity Markets, Reactive PowerReactive Support and Voltage Control Service: Key Issues and Challenges George Gross^, Paolo Marannino° and Gianfranco Chicco* ^ Department of Electrical and Computer Engineering, University

  9. Characterization of Dual-Fuel Reactivity Controlled Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI)...

  10. Field Demonstration Of Permeable Reactive Barriers To Remove

    E-Print Network [OSTI]

    Field Demonstration Of Permeable Reactive Barriers To Remove Dissolved Uranium From Groundwater-001 November 2000 FIELD DEMONSTRATION OF PERMEABLE REACTIVE BARRIERS TO REMOVE DISSOLVED URANIUM FROM

  11. Comparison of Conventional Diesel and Reactivity Controlled Compressio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI) Combustion in a Light-Duty Engine Comparison of Conventional Diesel and Reactivity Controlled Compression...

  12. Enrichment of Functional Redox Reactive Proteins and Identification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Redox Reactive Proteins and Identification by Mass Spectrometry Results in Several Terminal Fe(III) Enrichment of Functional Redox Reactive Proteins and Identification by Mass...

  13. Microscopic Reactive Diffusion of Uranium in the Contaminated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactive Diffusion of Uranium in the Contaminated Sediments at Hanford, United States. Microscopic Reactive Diffusion of Uranium in the Contaminated Sediments at Hanford, United...

  14. Role of Point Defects on the Reactivity of Reconstructed Anatase...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Point Defects on the Reactivity of Reconstructed Anatase Titanium Dioxide (001) Surface. Role of Point Defects on the Reactivity of Reconstructed Anatase Titanium Dioxide (001)...

  15. Merging high resolution geophysical and geochemical surveys to reduce

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMay 18-19,Department of

  16. electrifyingthefuture transportation

    E-Print Network [OSTI]

    Birmingham, University of

    electrifyingthefuture transportation The UK Government's carbon reduction strategy vehicles and the new Birmingham Science City Energy Systems Integration Laboratory (ESIL) will further enhance this work. The laboratory - unique within the UK and world leading - brings together cutting edge

  17. Geochemical Evidence for an Eolian Sand Dam across the North and South Platte Rivers in Nebraska

    E-Print Network [OSTI]

    Loope, David B.

    Geochemical Evidence for an Eolian Sand Dam across the North and South Platte Rivers in Nebraska that the Nebraska Sand Hills once migrated across the North and South Platte rivers and dammed the largest tributary of the South Platte River, have compositions intermediate between the Nebraska Sand Hills (quartz

  18. AESRC 2012, Kingston March 23-25th THE "SURFACE" EXPRESSION: WHAT DO GEOCHEMICAL ANOMALIES IN

    E-Print Network [OSTI]

    IN SURFACE MEDIA AND SHALLOW SANDSTONES OVERLYING THE PHOENIX URANIUM DEPOSIT, ATHABASCA BASIN, SASKATCHEWAN to examine whether surficial geochemical anomalies exist for such a deeply buried uranium deposit. For our expression in surface media provides excellent exploration tools for deeply seated unconformity

  19. Geochemical composition and provenance discrimination of coastal sediments around Cheju Island in the southeastern Yellow Sea

    E-Print Network [OSTI]

    Yang, Shouye

    in the southeastern Yellow Sea S.Y. Yanga,b,*, D.I. Lima , H.S. Junga , B.C. Ohc a Marine Environment and Climate Change Laboratory, Korea Ocean Research and Development Institute, Ansan P.O. Box 29, Seoul 425) compositions and geochemical discrimination diagrams were revealed to be useful indices for identifying

  20. A GEOCHEMICAL MODULE FOR "AMDTreat" TO COMPUTE CAUSTIC QUANTITY, EFFLUENT QUALITY, AND SLUDGE VOLUME1

    E-Print Network [OSTI]

    of sludge produced by the treatment, a titration simulation is being developed using the geochemical program The AMDTreat computer program ( . Treatment with caustic chemicals typically is used to increase pH (6 to 8), whereas active manganese removal requires treatment to alkaline pH (~10). The treatment

  1. Measuring prehistoric mobility strategies based on obsidian geochemical and technological signatures in the Owens Valley, California

    E-Print Network [OSTI]

    Measuring prehistoric mobility strategies based on obsidian geochemical and technological; Lithic technology; LA-ICP-MS; Mobility strategies; Owens Valley 1. Introduction Obsidian studies compare the organization of obsidian flaked stone technologies in two different time periods at CA-INY-30

  2. Organic geochemical evidence for pine tar production in middle Eastern Sweden during the Roman Iron Age

    E-Print Network [OSTI]

    Organic geochemical evidence for pine tar production in middle Eastern Sweden during the Roman Iron samples were analysed for diterpenoids derived from abietic acid (mainly retene, abietic acid, dehydroa- bietic acid and methyl dehydroabietate) by Gas Chromatography-Mass Spectrometry (GC-MS) in order to test

  3. Geochemical assessment of nuclear waste isolation. Report of activities during fiscal year 1982

    SciTech Connect (OSTI)

    Not Available

    1983-07-01T23:59:59.000Z

    The status of the following investigations is reported: canister/overpack-backfill chemical interactions and mechanisms; backfill and near-field host rock chemical interactions mechanisms; far-field host rock geochemical interactions; verification and improvement of predictive algorithms for radionuclide migration; and geologic systems as analogues for long-term radioactive waste isolation.

  4. Assessing XRF for the geochemical characterization of radiolarian chert artifacts from northeastern North America

    E-Print Network [OSTI]

    Long, Bernard

    Assessing XRF for the geochemical characterization of radiolarian chert artifacts from northeastern 2012 Keywords: Chert XRF Geochemistry Non-destructive Weathering Quarries Quebec a b s t r a c-ray fluorescence (ED-XRF) as a first-order technique to determine chert whole-rock geochemistry for archaeological

  5. Paper #194973 GEOCHEMICAL CHARACTERIZATION OF THE RESERVOIR HOSTING SHALE-GAS AND OIL in

    E-Print Network [OSTI]

    Paper #194973 GEOCHEMICAL CHARACTERIZATION OF THE RESERVOIR HOSTING SHALE-GAS AND OIL a reservoir for shale-gas and oil. We examined organic-rich black shale, known as Macasty shale, of Upper SHALE-GAS AND OIL in THE SUBSURFACE OF ANTICOSTI ISLAND, CANADA Key Words: Provenance, Anticosti Island

  6. On Perturbation Components Correspondence between Diffusion and Transport

    SciTech Connect (OSTI)

    G. Palmiotti

    2012-11-01T23:59:59.000Z

    We have established a correspondence between perturbation components in diffusion and transport theory. In particular we have established the correspondence between the leakage perturbation component of the diffusion theory to that of the group self scattering in transport theory. This has been confirmed by practical applications on sodium void reactivity calculations of fast reactors. Why this is important for current investigations? Recently, there has been a renewed interest in designing fast reactors where the sodium void reactivity coefficient is minimized. In particular the ASTRID8,9 reactor concept has been optimized with this goal in mind. The correspondence on the leakage term that has been established here has a twofold implication for the design of this kind of reactors. First, this type of reactor has a radial reflector; therefore, as shown before, the sodium void reactivity coefficient calculation requires the use of transport theory. The minimization of the sodium reactivity coefficient is normally done by increasing the leakage component that has a negative sign. The correspondence established in this paper allows to directly look at this component in transport theory. The second implication is related to the uncertainty evaluation on sodium void reactivity. As it has shown before, the total sodium void reactivity effect is the result of a large compensation (opposite sign) between the scattering (called often spectral) component and the leakage one. Consequently, one has to evaluate separately the uncertainty on each separate component and then combine them statistically. If one wants to compute the cross section sensitivity coefficients of the two different components, the formulation established in this paper allows to achieve this goal by playing on the contribution to the sodium void reactivity coming from the group self scattering of the sodium cross section.

  7. Groundwater well with reactive filter pack

    DOE Patents [OSTI]

    Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

    1998-01-01T23:59:59.000Z

    A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

  8. A Tariff for Reactive Power - IEEE

    SciTech Connect (OSTI)

    Kueck, John D [ORNL; Tufon, Christopher [Pacific Gas and Electric Company; Isemonger, Alan [California Independent System Operator; Kirby, Brendan J [ORNL

    2008-11-01T23:59:59.000Z

    This paper describes a suggested tariff or payment for the local supply of reactive power from distributed energy resources. The authors consider four sample customers, and estimate the cost of supply of reactive power for each customer. The power system savings from the local supply of reactive power are also estimated for a hypothetical circuit. It is found that reactive power for local voltage regulation could be supplied to the distribution system economically by customers when new inverters are installed. The inverter would be supplied with a power factor of 0.8, and would be capable of local voltage regulation to a schedule supplied by the utility. Inverters are now installed with photovoltaic systems, fuel cells and microturbines, and adjustable-speed motor drives.

  9. Reactivity control assembly for nuclear reactor

    DOE Patents [OSTI]

    Bollinger, Lawrence R. (Schenectady, NY)

    1984-01-01T23:59:59.000Z

    Reactivity control assembly for nuclear reactor comprises supports stacked above reactor core for holding control rods. Couplers associated with the supports and a vertically movable drive shaft have lugs at their lower ends for engagement with the supports.

  10. Systematic approach for chemical reactivity evaluation

    E-Print Network [OSTI]

    Aldeeb, Abdulrehman Ahmed

    2004-09-30T23:59:59.000Z

    , to measure thermal reactivity of chemical systems. Studying all the various reaction pathways experimentally however is very expensive and time consuming. Therefore, it is essential to employ simplified screening tools and other methods to reduce the number...

  11. Groundwater well with reactive filter pack

    DOE Patents [OSTI]

    Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

    1998-09-08T23:59:59.000Z

    A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

  12. EPA/ITRC-RTDF permeable reactive barrier short course. Permeable reactive barriers: Application and deployment

    SciTech Connect (OSTI)

    Not Available

    1999-01-01T23:59:59.000Z

    This report focuses on the following: Permeable Reactive Barriers: Application and Deployment; Introduction to Permeable Reactive Barriers (PRBs) for Remediating and Managing Contaminated Groundwater in Situ; Collection and Interpretation of Design Data 1: Site Characterization for PRBs; Reactive Materials: Zero-Valent Iron; Collection and Interpretation of Design Data 2: Laboratory and Pilot Scale Tests; Design Calculations; Compliance Monitoring, Performance Monitoring and Long-Term Maintenance for PRBs; PRB Emplacement Techniques; PRB Permitting and Implementation; Treatment of Metals; Non-Metallic Reactive Materials; Economic Considerations for PRB Deployment; and Bibliography.

  13. EPA/ITRC-RTDF permeable reactive barrier short course. Permeable reactive barriers: Application and deployment

    SciTech Connect (OSTI)

    NONE

    1999-11-01T23:59:59.000Z

    This report focuses on the following: Permeable Reactive Barriers: Application and Deployment; Introduction to Permeable Reactive Barriers (PRBs) for Remediating and Managing Contaminated Groundwater in Situ; Collection and Interpretation of Design Data 1: Site Characterization for PRBs; Reactive Materials: Zero-Valent Iron; Collection and Interpretation of Design Data 2: Laboratory and Pilot Scale Tests; Design Calculations; Compliance Monitoring, Performance Monitoring and Long-Term Maintenance for PRBs; PRB Emplacement Techniques; PRB Permitting and Implementation; Treatment of Metals; Non-Metallic Reactive Materials; Economic Considerations for PRB Deployment; and Bibliography.

  14. MSIV leakage airborne iodine transport

    SciTech Connect (OSTI)

    Cline, J.E. (Cline Associates Inc., Rockville, MD (United States))

    1993-01-01T23:59:59.000Z

    Gaseous iodine deposits on surfaces exposed to vapors. Basic chemical and physical principles predict this behavior, and several laboratory and in-plant measurements demonstrate the characteristic. An empirical model was developed that describes the deposition, resuspension, and transformation of airborne radioiodine molecular species as a stream containing these forms moves along its pathway. The model uses a data base of measured values of deposition and resuspension rates in its application and describes the conversion of the more reactive inorganic iodine species I[sub 2] to the less reactive organic species CH[sub 3]I as the iodine deposits and resuspends along the path. It also considers radioactive decay and chemical surface bonding during residence on surfaces. For the 8-day [sup 131]I, decay during the airborne portion of the transport is negligible. Verification of the model included measurement tests of long gaseous-activity sampling lines of different diameters, operated at different flow rates and stream temperatures. The model was applied to the streams at a boiling water reactor nuclear power plant to describe the transport through leaking main steam isolation valves (MSIVs), following a loss-of-coolant accident.

  15. Eoeective Recognizability and Model Checking of Reactive Fioeo Automata

    E-Print Network [OSTI]

    Sutre, Grégoire

    Electre. For this, we deøne a particular behavioral model for Electre programs, Reactive Fioeo Au­ tomata speciøed with the reactive language Electre [CR95]. A reactive pro­ gram is supposed to reactEoeective Recognizability and Model Checking of Reactive Fioeo Automata G. Sutre 1 , A. Finkel 1

  16. GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS

    SciTech Connect (OSTI)

    Edwin S. Olson; Charles J. Moretti

    1999-11-01T23:59:59.000Z

    Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require ultimate disposal when it is put to use. Each task three waste was evaluated for utilization potential based on its physical properties, bulk chemical composition, and mineral composition. Only one of the thirteen materials studied might be suitable for use as a pozzolanic concrete additive. However, many wastes appeared to be suitable for other high-volume uses such as blasting grit, fine aggregate for asphalt concrete, road deicer, structural fill material, soil stabilization additives, waste stabilization additives, landfill cover material, and pavement base course construction.

  17. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  18. Origin of geochemical heterogeneity in the mantle : constraints from volcanism associated with Hawaiian and Kerguelen mantle plumes

    E-Print Network [OSTI]

    Xu, Guangping

    2007-01-01T23:59:59.000Z

    Lavas derived from long-lived mantle plumes provide important information of mantle compositions and the processes that created the geochemical heterogeneity within the mantle. Kerguelen and Hawaii are two long-lived mantle ...

  19. Transportation and its Infrastructure

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    40 pp. IEA, 2004c: Biofuels for Transport: An Internationalthe ACT Map scenario, transport biofuels production reachesestimates that biofuels’ share of transport fuel could

  20. Kinetics of Uranium(VI) Desorption from Contaminated Sediments: Effect of Geochemical Conditions and Model Evaluation

    SciTech Connect (OSTI)

    Liu, Chongxuan; Shi, Zhenqing; Zachara, John M.

    2009-09-01T23:59:59.000Z

    Stirred-flow cell experiments were performed to investigate the kinetics of uranyl [U(VI)] desorption from a contaminated sediment collected from the Hanford 300 Area at the US Department of Energy (DOE) Hanford Site, Washington. Three influent solutions of variable pH, Ca and carbonate concentrations that affected U(VI) aqueous and surface speciation were used under dynamic flow conditions to evaluate the effect of geochemical conditions on the rate of U(VI) desorption. The measured rate of U(VI) desorption varied with solution chemical composition that evolved as a result of thermodynamic and kinetic interactions between the influent solutions and sediment. The solution chemical composition that led to a lower equilibrium U(VI) sorption to the solid phase yielded a faster desorption rate. The experimental results were used to evaluate a multi-rate, surface complexation model (SCM) that has been proposed to describe U(VI) desorption kinetics in the Hanford sediment that contained complex sorbed U(VI) species in mass transfer limited domains. The model was modified and supplemented by including multi-rate, ion exchange reactions to describe the geochemical interactions between the solutions and sediment. With the same set of model parameters, the modified model reasonably well described the evolution of major ions and the rates of U(VI) desorption under variable geochemical and flow conditions, implying that the multi-rate SCM is an effective way to describe U(VI) desorption kinetics in subsurface sediments.

  1. Method For Reactivating Solid Catalysts Used For Alklation Reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Thompson, David N. (Idaho Falls, ID); Coates, Kyle (Shelley, ID); Zalewski, David J. (Proctorville, OH); Fox, Robert V. (Idaho Falls, ID)

    2005-05-03T23:59:59.000Z

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  2. Method for reactivating solid catalysts used in alkylation reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Coates, Kyle; Zalewski, David J.; Fox, Robert V.

    2003-06-17T23:59:59.000Z

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  3. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-01-21T23:59:59.000Z

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  4. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-11-25T23:59:59.000Z

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  5. NREL: Transportation Research - Transportation and Hydrogen Newsletter...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Future of Sustainable Transportation This is the January 2015 issue of the Transportation and Hydrogen Newsletter. Illustration of an electric vehicle Illustration of an...

  6. Test Pile Reactivity Loss Due to Trichloroethylene

    SciTech Connect (OSTI)

    Plumlee, K.E.

    2001-03-09T23:59:59.000Z

    The presence of trichloroethylene in the test pile caused a continual decrease in pile reactivity. A system which removed, purified, and returned 12,000 cfh helium to the pile has held contamination to a negligible level and has permitted normal pile operation.

  7. Studies on Waterborne Pathogen Reactivation after Disinfection

    E-Print Network [OSTI]

    Kaur, Jasjeet

    2013-12-09T23:59:59.000Z

    ultraviolet (LP UV) irradiation at five titanium dioxide (TiO_(2)) concentrations (1 g/L, 0.5 g/L, 0.75 g/L, and 0.1 g/L) to achieve 5 log_(10) reduction of a laboratory E. coli K-12 strain (ATCC® 10798). Regrowth and reactivation of E. coli in dark and light...

  8. Controlling uranium reactivity March 18, 2008

    E-Print Network [OSTI]

    Meyer, Karsten

    for the last decade. Most of their work involves depleted uranium, a more common form of uraniumMarch 2008 Controlling uranium reactivity March 18, 2008 Uranium is an often misunderstood metal uranium research. In reality, uranium presents a wealth of possibilities for funda- mental chemistry. Many

  9. NREL: Transportation Research - Transportation News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for Renewable Energy: Grid IntegrationReportTransmissionResearchNewsTransportation News

  10. Assessment of the Economic Potential of Microgrids for Reactive Power Supply

    E-Print Network [OSTI]

    Appen, Jan von

    2012-01-01T23:59:59.000Z

    Reactive Power from Distributed Energy”, The Electricityvoltage. Electricity consumers’ demand for reactive power ison electricity supply security, the costs of local reactive

  11. XCHEM-1D: A Heat Transfer/Chemical Kinetics Computer Program for multilayered reactive materials

    SciTech Connect (OSTI)

    Gross, R.J.; Baer, M.R.; Hobbs, M.L.

    1993-10-01T23:59:59.000Z

    An eXplosive CHEMical kinetics code, XCHEM, has been developed to solve the reactive diffusion equations associated with thermal ignition of energetic materials. This method-of-lines code uses stiff numerical methods and adaptive meshing to resolve relevant combustion physics. Solution accuracy is maintained between multilayered materials consisting of blends of reactive components and/or inert materials. Phase change and variable properties are included in one-dimensional slab, cylindrical and spherical geometries. Temperature-dependent thermal properties have been incorporated and the modification of thermal conductivities to include decomposition effects are estimated using solid/gas volume fractions determined by species fractions. Gas transport properties, including high pressure corrections, have also been included. Time varying temperature, heat flux, convective and thermal radiation boundary conditions, and layer to layer contact resistances have also been implemented.

  12. Simultaneous MS-IR Studies of Surface Formate Reactivity Under...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis Conditions on CuSiO2. Simultaneous MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis...

  13. Isotope effects in methanol synthesis and the reactivity of copper...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

  14. Parallel Web Scripting with Reactive Constraints Thibaud Hottelier

    E-Print Network [OSTI]

    Bodik, Rastisla

    Parallel Web Scripting with Reactive Constraints Thibaud Hottelier James Ide Doug Kimelman Ras Bodik Electrical Engineering and Computer Sciences University of California at Berkeley Technical Report to lists, requires prior specific permission. #12;Parallel Web Scripting with Reactive Constraints Thibaud

  15. The effects of radient heat on pain reactivity 

    E-Print Network [OSTI]

    Kallina, Charles Frank

    1994-01-01T23:59:59.000Z

    Prior research has shown that an aversive event can produce either a decrease (hypoalgesia) or an increase in pain reactivity (hyperalgesia). The present study explores the impact of a suprathreshold exposure to radiant heat on pain reactivity. Rats...

  16. Reactive Dehydration technology for Production of Fuels and Chemicals...

    Broader source: Energy.gov (indexed) [DOE]

    platform (Intensified Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based chemicals from complex aqueous mixtures. Separation...

  17. The Simulation of Synchronous Reactive Systems In Ptolemy II

    E-Print Network [OSTI]

    The Simulation of Synchronous Reactive Systems In Ptolemy II by Paul Whitaker Submitted to the Department of Electrical Engineering and Computer Sciences, University of California at Berkeley, in partial;_____________________________________________________________________ Simulation of Synchronous Reactive Systems in Ptolemy II ii Abstract The Synchronous Reactive (SR) domain

  18. Autonomic Reactive Systems via Online Learning Sanjit A. Seshia

    E-Print Network [OSTI]

    California at Irvine, University of

    Autonomic Reactive Systems via Online Learning Sanjit A. Seshia Department of Electrical@eecs.berkeley.edu Abstract-- Reactive systems are those that maintain an ongoing interaction with their environment- covering a class of reactive systems from run-time failures. This class of systems comprises those whose

  19. Towards Synthesis of Reactive & Robust Behavior Chains Amol D. Mali

    E-Print Network [OSTI]

    Mali, Amol D.

    Towards Synthesis of Reactive & Robust Behavior Chains Amol D. Mali Electrical Engg. & Computer robots need to be reactive and robust. Behavior-based robots that identify and repair the failures have of reactivity and robustness have been hitherto only informally used and have been loaded with var- ious

  20. A Synchronous Approach to Reactive System Design1 Charles Andr

    E-Print Network [OSTI]

    André, Charles

    our experience teaching discrete-event reactive systems to Electrical Engineering students. The courseA Synchronous Approach to Reactive System Design1 Charles André I3S Laboratory ­ UNSA/CNRS BP 121 This paper was presented at the 12th EAEEIE Annual Conf., 14-16 May 2001, Nancy (France). Abstract Reactive

  1. On Some Properties of Instantaneous Active and Reactive Powers

    E-Print Network [OSTI]

    Czarnecki, Leszek S.

    On Some Properties of Instantaneous Active and Reactive Powers Leszek S. CZARNECKI, Fellow IEEE Louisiana State University, USA Abstract: Some features of the instantaneous active and reactive powers p control. Also it was shown that the instantaneous reactive power q cannot be interpreted as a measure

  2. Remote Raman - laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions

    SciTech Connect (OSTI)

    Clegg, Sanuel M [Los Alamos National Laboratory; Barefield, James E [Los Alamos National Laboratory; Humphries, Seth D [Los Alamos National Laboratory; Wiens, Roger C [Los Alamos National Laboratory; Vaniman, D. T. [Los Alamos National Laboratory; Sharma, S. K. [UNIV OF HAWAII; Misra, A. K. [UNIV OF HAWAII; Dyar, M. D. [MT. HOLYOKE COLLEGE; Smrekar, S. E. [JET PROPULSION LAB.

    2010-12-13T23:59:59.000Z

    The extreme Venus surface temperatures ({approx}740 K) and atmospheric pressures ({approx}93 atm) create a challenging environment for surface missions. Scientific investigations capable of Venus geochemical observations must be completed within hours of landing before the lander will be overcome by the harsh atmosphere. A combined remote Raman - LIBS (Laser Induced Breakdown Spectroscopy) instrument is capable of accomplishing the geochemical science goals without the risks associated with collecting samples and bringing them into the lander. Wiens et al. and Sharma et al. demonstrated that both analytical techniques can be integrated into a single instrument capable of planetary missions. The focus of this paper is to explore the capability to probe geologic samples with Raman - LIBS and demonstrate quantitative analysis under Venus surface conditions. Raman and LIBS are highly complementary analytical techniques capable of detecting both the mineralogical and geochemical composition of Venus surface materials. These techniques have the potential to profoundly increase our knowledge of the Venus surface composition, which is currently limited to geochemical data from Soviet Venera and VEGA landers that collectively suggest a surface composition that is primarily tholeiitic basaltic with some potentially more evolved compositions and, in some locations, K-rich trachyandesite. These landers were not equipped to probe the surface mineralogy as can be accomplished with Raman spectroscopy. Based on the observed compositional differences and recognizing the imprecise nature of the existing data, 15 samples were chosen to constitute a Venus-analog suite for this study, including five basalts, two each of andesites, dacites, and sulfates, and single samples of a foidite, trachyandesite, rhyolite, and basaltic trachyandesite under Venus conditions. LIBS data reduction involved generating a partial least squares (PLS) model with a subset of the rock powder standards to quantitatively determine the major elemental abundance of the remaining samples. PLS analysis suggests that the major element compositions can be determined with root mean square errors ca. 5% (absolute) for SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}(total), MgO, and CaO, and ca. 2% or less for TiO{sub 2}, Cr{sub 2}O{sub 3}, MnO, K{sub 2}O, and Na{sub 2}O. Finally, the Raman experiments have been conducted under supercritical CO{sub 2} involving single-mineral and mixed-mineral samples containing talc, olivine, pyroxenes, feldspars, anhydrite, barite, and siderite. The Raman data have shown that the individual minerals can easily be identified individually or in mixtures.

  3. Reactivity control assembly for nuclear reactor. [LMFBR

    DOE Patents [OSTI]

    Bollinger, L.R.

    1982-03-17T23:59:59.000Z

    This invention, which resulted from a contact with the United States Department of Energy, relates to a control mechanism for a nuclear reactor and, more particularly, to an assembly for selectively shifting different numbers of reactivity modifying rods into and out of the core of a nuclear reactor. It has been proposed heretofore to control the reactivity of a breeder reactor by varying the depth of insertion of control rods (e.g., rods containing a fertile material such as ThO/sub 2/) in the core of the reactor, thereby varying the amount of neutron-thermalizing coolant and the amount of neutron-capturing material in the core. This invention relates to a mechanism which can advantageously be used in this type of reactor control system.

  4. Nuclear reactivity control using laser induced polarization

    DOE Patents [OSTI]

    Bowman, Charles D. (Los Alamos, NM)

    1990-01-01T23:59:59.000Z

    A control element for reactivity control of a fission source provides an atomic density of .sup.3 He in a control volume which is effective to control criticality as the .sup.3 He is spin-polarized. Spin-polarization of the .sup.3 He affects the cross section of the control volume for fission neturons and hence, the reactivity. An irradiation source is directed within the .sup.3 He for spin-polarizing the .sup.3 He. An alkali-metal vapor may be included with the .sup.3 He where a laser spin-polarizes the alkali-metal atoms which in turn, spin-couple with .sup.3 He to spin-polarize the .sup.3 He atoms.

  5. Nuclear reactivity control using laser induced polarization

    DOE Patents [OSTI]

    Bowman, Charles D. (Los Alamos, NM)

    1991-01-01T23:59:59.000Z

    A control element for reactivity control of a fission source provides an atomic density of .sup.3 He in a control volume which is effective to control criticality as the .sup.3 He is spin-polarized. Spin-polarization of the .sup.3 He affects the cross section of the control volume for fission neutrons and hence, the reactivity. An irradiation source is directed within the .sup.3 He for spin-polarizing the .sup.3 He. An alkali-metal vapor may be included with the .sup.3 He where a laser spin-polarizes the alkali-metal atoms which in turn, spin-couple with .sup.3 He to spin-polarize the .sup.3 He atoms.

  6. Design, installation, and performance of a multi-layered permeable reactive barrier, Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Kaszuba, J. P. (John P.); Longmire, P. A. (Patrick A.); Strietelmeier, E. A. (Elizabeth A.); Taylor, T. P. (Tammy P.); Den-Baars, P. S. (Peter S.)

    2004-01-01T23:59:59.000Z

    A multi-layered permeable reactive barrier (PRB) has been installed in Mortandad Canyon, on the Pajarito Plateau in the north-central part of LANL, to demonstrate in-situ treatment of a suite of contaminants with dissimilar geochemical properties. The PRB will also mitigate possible vulnerabilities from downgradient contaminant movement within alluvial and deeper perched groundwater. Mortandad Canyon was selected as the location for this demonstration project because the flow of alluvial groundwater is constrained by the geology of the canyon, a large network of monitoring wells already were installed along the canyon reach, and the hydrochemistry and contaminant history of the canyon is well-documented. The PRB uses a funnel-and-gate system with a series of four reactive media cells to immobilize or destroy contaminants present in alluvial groundwater, including strontium-90, plutonium-238,239,240, americium-241, perchlorate, and nitrate. The four cells, ordered by sequence of contact with the groundwater, consist of gravel-sized scoria (for colloid removal); phosphate rock containing apatite (for metals and radionuclides); pecan shells and cotton seed admixed with gravel (bio-barrier, to deplete dissolved oxygen and destroy potential RCRA organic compounds, nitrate and perchlorate); and limestone (pH buffering and anion adsorption). Design elements of the PRB are based on laboratory-scale treatability studies and on a field investigation of hydrologic, geochemical, and geotechnical parameters. The PRB was designed with the following criteria: 1-day residence time within the biobarrier, 10-year lifetime, minimization of surface water infiltration and erosion, optimization of hydraulic capture, and minimization of excavated material requiring disposal. Each layer has been equipped with monitoring wells or ports to allow sampling of groundwater and reactive media, and monitor wells are located immediately adjacent to the up- and down-gradient perimeter of the engineered structure. Groundwater sampling upgradient, within, and downgradient of the PRB took place from May through August 2003. Concentrations of strontium-90 have diminished by 80% and 40% within the central portion of the phosphate rock (apatite) and bio-barrier cells, respectively. Higher concentrations of this radionuclide occur in groundwater near the north and south perimeters of the two cells. The non-uniform distribution of strontium-90 may result from varying residence time and saturated thickness of pore water. Initial concentrations of nitrate (8-12 parts per million or ppm as nitrate) and perchlorate (0.035 ppm) have been reduced in the phosphate rock and bio-barrier cells to concentrations that are less than method detection limits (0.01 and 0.002 ppm, respectively). Initial microbial analyses suggest the presence of both dissimilatory perchlorate- and nitrate-reducing bacterial populations, along with production of acetate and propionate, and decreasing dissolved oxygen and pH. The dominant group of perchlorate reducers consists of members of the previously described Dechloromonas genus, in the beta subclass of the Proteobacteria, which together with the Dechlorosoma genus are considered to be the dominant genera in circum-neutral mesophilic environments. Groundwater flow through the multiple PRB is taking place at a very slow rate based on similar concentrations of nitrate, perchlorate, chlorate, and chlorite in the upgradient well MCO-4B and downgradient well MCO-5. Concentrations of these constituents also increase within the limestone cell. Decreased precipitation due to extreme drought is probably responsible for decreasing saturated thickness within both the alluvium and PRB, resulting in stagnant conditions. Varying distributions of ammonium, nitrate, sulfate, iron, and manganese within the phosphate rock, bio-barrier, and limestone cells also support this hypothesis.

  7. Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy (Culver City, CA)

    1982-01-01T23:59:59.000Z

    In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

  8. Transporting particulate material

    DOE Patents [OSTI]

    Aldred, Derek Leslie (North Hollywood, CA); Rader, Jeffrey A. (North Hollywood, CA); Saunders, Timothy W. (North Hollywood, CA)

    2011-08-30T23:59:59.000Z

    A material transporting system comprises a material transporting apparatus (100) including a material transporting apparatus hopper structure (200, 202), which comprises at least one rotary transporting apparatus; a stationary hub structure (900) constraining and assisting the at least one rotary transporting apparatus; an outlet duct configuration (700) configured to permit material to exit therefrom and comprising at least one diverging portion (702, 702'); an outlet abutment configuration (800) configured to direct material to the outlet duct configuration; an outlet valve assembly from the material transporting system venting the material transporting system; and a moving wall configuration in the material transporting apparatus capable of assisting the material transporting apparatus in transporting material in the material transporting system. Material can be moved from the material transporting apparatus hopper structure to the outlet duct configuration through the at least one rotary transporting apparatus, the outlet abutment configuration, and the outlet valve assembly.

  9. Reactive Attachment Disorder: Concepts, Treatment, and Research

    E-Print Network [OSTI]

    Walter, Uta M.; Petr, Chris

    2004-06-01T23:59:59.000Z

    Best Practices in Children’s Mental Health: A Series of Reports Summarizing the Empirical Research on Selected Topics Report #11 “Reactive Attachment Disorder: Concepts, Treatment and Research” June, 2004... Healthcare” Report #8 – October 2003, “Best Practices in Therapeutic Foster Care: Review of the Literature and Local Practices in the State of Kansas” Report #9 – December 2003, “Juveniles with Sexual Offending Behaviors” Report #10-February 2004...

  10. Transportation Security | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Security SHARE Global Threat Reduction Initiative Transportation Security Cooperation Secure Transport Operations (STOP) Box Security of radioactive material while...

  11. Performance Assessment Transport Modeling of Uranium at the Area 5 Radioactive Waste Management Site at the Nevada National Security Site

    SciTech Connect (OSTI)

    NSTec Radioactive Waste

    2010-10-12T23:59:59.000Z

    Following is a brief summary of the assumptions that are pertinent to the radioactive isotope transport in the GoldSim Performance Assessment model of the Area 5 Radioactive Waste Management Site, with special emphasis on the water-phase reactive transport of uranium, which includes depleted uranium products.

  12. Predictive modeling of reactive wetting and metal joining.

    SciTech Connect (OSTI)

    van Swol, Frank B.

    2013-09-01T23:59:59.000Z

    The performance, reproducibility and reliability of metal joints are complex functions of the detailed history of physical processes involved in their creation. Prediction and control of these processes constitutes an intrinsically challenging multi-physics problem involving heating and melting a metal alloy and reactive wetting. Understanding this process requires coupling strong molecularscale chemistry at the interface with microscopic (diffusion) and macroscopic mass transport (flow) inside the liquid followed by subsequent cooling and solidification of the new metal mixture. The final joint displays compositional heterogeneity and its resulting microstructure largely determines the success or failure of the entire component. At present there exists no computational tool at Sandia that can predict the formation and success of a braze joint, as current capabilities lack the ability to capture surface/interface reactions and their effect on interface properties. This situation precludes us from implementing a proactive strategy to deal with joining problems. Here, we describe what is needed to arrive at a predictive modeling and simulation capability for multicomponent metals with complicated phase diagrams for melting and solidification, incorporating dissolutive and composition-dependent wetting.

  13. Geochemical fluid characteristics and main achievements about tracer tests at Soultz-sous-Forts (France) 1 EC Contract SES6-CT-2003-502706

    E-Print Network [OSTI]

    Boyer, Edmond

    Geochemical fluid characteristics and main achievements about tracer tests at Soultz Related with Work Package WP1a (Short term fluid circulation tests) and WP1c (Data acquisition) GEOCHEMICAL FLUID CHARACTERISTICS AND MAIN ACHIEVEMENTS ABOUT TRACER TESTS AT SOULTZ-SOUS-FORÃ?TS (FRANCE

  14. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09T23:59:59.000Z

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  15. "Educating transportation professionals."

    E-Print Network [OSTI]

    Acton, Scott

    "Educating transportation professionals." Michael Demetsky Henry L. Kinnier Professor mjd of Virginia Charlottesville, VA 434.924.7464 Transportation Engineering & Management Research Our group works closely with the Virginia Center for Transportation Innovation and Research (VCTIR), located

  16. Predictive modeling of CO{sub 2} sequestration in deep saline sandstone reservoirs: Impacts of geochemical kinetics

    SciTech Connect (OSTI)

    Balashov, Victor N.; Guthrie, George D.; Hakala, J. Alexandra; Lopano, Christina L. J.; Rimstidt, Donald; Brantley, Susan L.

    2013-03-01T23:59:59.000Z

    One idea for mitigating the increase in fossil-fuel generated CO{sub 2} in the atmosphere is to inject CO{sub 2} into subsurface saline sandstone reservoirs. To decide whether to try such sequestration at a globally significant scale will require the ability to predict the fate of injected CO{sub 2}. Thus, models are needed to predict the rates and extents of subsurface rock-water-gas interactions. Several reactive transport models for CO{sub 2} sequestration created in the last decade predicted sequestration in sandstone reservoirs of ~17 to ~90 kg CO{sub 2} m{sup -3|. To build confidence in such models, a baseline problem including rock + water chemistry is proposed as the basis for future modeling so that both the models and the parameterizations can be compared systematically. In addition, a reactive diffusion model is used to investigate the fate of injected supercritical CO{sub 2} fluid in the proposed baseline reservoir + brine system. In the baseline problem, injected CO{sub 2} is redistributed from the supercritical (SC) free phase by dissolution into pore brine and by formation of carbonates in the sandstone. The numerical transport model incorporates a full kinetic description of mineral-water reactions under the assumption that transport is by diffusion only. Sensitivity tests were also run to understand which mineral kinetics reactions are important for CO{sub 2} trapping. The diffusion transport model shows that for the first ~20 years after CO{sub 2} diffusion initiates, CO{sub 2} is mostly consumed by dissolution into the brine to form CO{sub 2,aq} (solubility trapping). From 20-200 years, both solubility and mineral trapping are important as calcite precipitation is driven by dissolution of oligoclase. From 200 to 1000 years, mineral trapping is the most important sequestration mechanism, as smectite dissolves and calcite precipitates. Beyond 2000 years, most trapping is due to formation of aqueous HCO{sub 3}{sup -}. Ninety-seven percent of the maximum CO{sub 2} sequestration, 34.5 kg CO{sub 2} per m{sup 3} of sandstone, is attained by 4000 years even though the system does not achieve chemical equilibrium until ~25,000 years. This maximum represents about 20% CO{sub 2} dissolved as CO{sub 2},aq, 50% dissolved as HCO{sub 3}{sup -}{sub ,aq}, and 30% precipitated as calcite. The extent of sequestration as HCO{sub 3}{sup -} at equilibrium can be calculated from equilibrium thermodynamics and is roughly equivalent to the amount of Na+ in the initial sandstone in a soluble mineral (here, oligoclase). Similarly, the extent of trapping in calcite is determined by the amount of Ca2+ in the initial oligoclase and smectite. Sensitivity analyses show that the rate of CO{sub 2} sequestration is sensitive to the mineral-water reaction kinetic constants between approximately 10 and 4000 years. The sensitivity of CO{sub 2} sequestration to the rate constants decreases in magnitude respectively from oligoclase to albite to smectite.

  17. A novel reactive processing technique: using telechelic polymers to reactively compatibilize polymer blends

    SciTech Connect (OSTI)

    Ashcraft, Earl C [ORNL; Ji, Haining [ORNL; Mays, Jimmy [ORNL; Dadmun, Mark D [ORNL

    2009-01-01T23:59:59.000Z

    Difunctional reactive polymers, telechelics, were used to reactively form multiblock copolymers in situ when melt-blended with a blend of polystyrene and polyisoprene. To quantify the ability of the copolymer to compatibilize the blends, the time evolution of the domain size upon annealing was analyzed by SEM. It was found that the most effective parameter to quantify the ability of the copolymer to inhibit droplet coalescence is Kreltstable, the relative coarsening constant multiplied by the stabilization time. These results indicate that intermediate-molecular-weight telechelic pairs of both highly reactive Anhydride-PS-Anhydride/NH2-PI-NH2 and slower reacting Epoxy-PS-Epoxy/COOH-PI-COOH both effectively suppress coalescence, with the optimal molecular weight being slightly above the critical molecular weight of the homopolymer,Mc. The effects of telechelic loading were also investigated, where the optimal loading concentration for this system was 0.5 wt %, as higher concentrations exhibited a plasticizing effect due to the presence of unreacted low-molecular-weight telechelics present in the blend. A determination of the interfacial coverage of the copolymer shows that a conversion of 1.5-3.0% was required for 20% surface coverage at 5.0 wt % telechelic loading, indicating a large excess of telechelics in this system. At the optimal loading level of 0.5 wt %, a conversion of 15% was required for 20% surface coverage. The results of these experiments provide a clear understanding of the role of telechelic loading and molecular weight on its ability to reactively form interfacial modifiers in phase-separated polymer blends and provide guidelines for the development of similar reactive processing schemes that can use telechelic polymers to reactively compatibilize a broad range of polymer blends.

  18. Sustainability and Transport

    E-Print Network [OSTI]

    Gilbert, Richard

    2006-01-01T23:59:59.000Z

    2005. Integrating Sustainability into the Trans- portationTHOUGHT PIECE Sustainability and Transport by Richardof the concept of sustainability to transport planning. In

  19. Chapter 12 Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-1 November 2012 Words in bold and acronyms are defined in Chapter 32, Glossary and Acronyms. Chapter 12 Transportation This chapter describes existing transportation resources in...

  20. Transportation | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation From modeling and simulation programs to advanced electric powertrains, engines, biofuels, lubricants, and batteries, Argonne's transportation research is vital to...

  1. Transporting Hazardous Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transporting Hazardous Materials The procedures given below apply to all materials that are considered to be hazardous by the U.S. Department of Transportation (DOT). Consult your...

  2. Relative reactivities of solid benzoic acids

    E-Print Network [OSTI]

    Warwas, Edwin James

    1967-01-01T23:59:59.000Z

    REACTIVITIES OF SOLID BENZOIC ACIDS (January 1967) Edwin James Warwas B. S. , Southwest Texas State College Directed by: Dr. C. K. Hancock and Dr. E. A. Meyers The reactions of solid benzoic acid (BZAH) and nine m- or p- substituted benzoic acids (RBZAH...) with solid potassium benzoate (BZAK) and m- or p-substituted potassium benzoates (R'BZAK) have been carried out in sealed thin-walled glass capillary tubes or in 0 sealed weighing bottles at 70 For the reaction, RBZAH + R'BZAK, where R = R', the product...

  3. Preparation of reactive beta-dicalcium silicate

    DOE Patents [OSTI]

    Shen, Ming-Shing (Laramie, WY, NJ); Chen, James M. (Rahway, NJ); Yang, Ralph T. (Amherst, NY)

    1982-01-01T23:59:59.000Z

    This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane and hydrogen, at a temperature of about 850.degree.-1000.degree. C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

  4. Preparation of reactive beta-dicalcium silicate

    DOE Patents [OSTI]

    Shen, M.S.; Chen, J.M.; Yang, R.T.

    1980-02-28T23:59:59.000Z

    This invention relates to the preparation of fine particles of reactive beta-dicalcium silicate by means of a solid state process which comprises firing a mixture of calcium sulfate, silica, and a reducing additive selected from the group consisting of calcium sulfide, carbon, carbon monoxide, methane, and hydrogen, at a temperature of about 850 to 1000/sup 0/C. A carrier gas such as nitrogen or carbon dioxide may also be added, if desired. A high concentration of sulfur dioxide is a by-product of this process.

  5. Reactive sticking coefficients of silane on silicon

    SciTech Connect (OSTI)

    Buss, R.J.; Ho, P.; Breiland, W.G.; Coltrin, M.E.

    1988-09-15T23:59:59.000Z

    Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition rate measurements using molecular beam scattering and a very low pressure cold wall reactor. The RSCs have non-Arrhenius temperature dependences and decreases with increasing flux at low (710/sup 0/) temperatures. A simple model involving dissociative adsorption of silane is consistent with these results. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction.

  6. MSTS - Multiphase Subsurface Transport Simulator theory manual

    SciTech Connect (OSTI)

    White, M.D.; Nichols, W.E.

    1993-05-01T23:59:59.000Z

    The US Department of Energy, through the Yucca Mountain Site Characterization Project Office, has designated the Yucca Mountain site in Nevada for detailed study as the candidate US geologic repository for spent nuclear fuel and high-level radioactive waste. Site characterization will determine the suitability of the Yucca Mountain site for the potential waste repository. If the site is determined suitable, subsequent studies and characterization will be conducted to obtain authorization from the Nuclear Regulatory Commission to construct the potential waste repository. A principal component of the characterization and licensing processes involves numerically predicting the thermal and hydrologic response of the subsurface environment of the Yucca Mountain site to the potential repository over a 10,000-year period. The thermal and hydrologic response of the subsurface environment to the repository is anticipated to include complex processes of countercurrent vapor and liquid migration, multiple-phase heat transfer, multiple-phase transport, and geochemical reactions. Numerical simulators based on mathematical descriptions of these subsurface phenomena are required to make numerical predictions of the thermal and hydrologic response of the Yucca Mountain subsurface environment The engineering simulator called the Multiphase Subsurface Transport Simulator (MSTS) was developed at the request of the Yucca Mountain Site Characterization Project Office to produce numerical predictions of subsurface flow and transport phenomena at the potential Yucca Mountain site. This document delineates the design architecture and describes the specific computational algorithms that compose MSTS. Details for using MSTS and sample problems are given in the {open_quotes}User`s Guide and Reference{close_quotes} companion document.

  7. Age, geochemical and SrNdPb isotopic constraints for mantle source characteristics and petrogenesis of Teru Volcanics,

    E-Print Network [OSTI]

    Stern, Robert J.

    Age, geochemical and Sr­Nd­Pb isotopic constraints for mantle source characteristics and petrogenesis of Teru Volcanics, Northern Kohistan Terrane, Pakistan S.D. Khana,*, R.J. Sternb , M.I. Mantonb, University of Peshawar, Pakistan Accepted 21 April 2004 Available online 23 September 2004 Abstract

  8. Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

    SciTech Connect (OSTI)

    Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

    1985-01-01T23:59:59.000Z

    An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

  9. Oxygen is a key element for biology and the cycling of geochemical elements, and has shaped the chemical

    E-Print Network [OSTI]

    Handy, Todd C.

    Oxygen is a key element for biology and the cycling of geochemical elements, and has shaped the chemical and biological evolution of Earth. The oceans appear to be loosing oxygen due to on-going climate change, with resulting impacts on marine ecosystems and global biogeochemical cycles. As oxygen levels

  10. Geochemical evidence of a near-surface history for source rocks of the central Coast Mountains Batholith, British Columbia

    E-Print Network [OSTI]

    Wetmore, Paul H.

    Geochemical evidence of a near-surface history for source rocks of the central Coast Mountains to ,50 Ma, indicate that the source regions for these rocks were relatively uniform and typical abundance of deep crustal or upper-mantle source rocks (DePaolo 1981; Kistler 1990; Chen and Tilton 1991; De

  11. Assessment of peat quality by molecular and bulk geochemical analysis: Application to the Holocene record of the Chautagne

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Assessment of peat quality by molecular and bulk geochemical analysis: Application to the Holocene in general from a limited variety of local plants, peat is however sensitive to physicochemical changes the information on peat quality provided by various families of biochemical components (lipids, lignin, sugars

  12. Numerical modeling of time-lapse seismic data from fractured reservoirs including fluid flow and geochemical processes 

    E-Print Network [OSTI]

    Shekhar, Ravi

    2009-05-15T23:59:59.000Z

    and amplitude variation with offset (AVO) results for our example model predicts that CO2 is easier to detect than brine in the fractured reservoirs. The effects of geochemical processes on seismics are simulated by time-lapse modeling for t = 1000 years. My...

  13. Reactive power planning of large-scale systems

    SciTech Connect (OSTI)

    Burchett, R.C.; Happ, H.H.; Vierath, D.R.

    1983-01-01T23:59:59.000Z

    This paper discusses short-term operations planning applications in reactive power management involving existing equipment. Reactive power planning involves the sizing and siting of additional reactive support equipment in order to satisfy system voltage constraints (minimum and maximum limits) under both normal and contingency conditions. The use of the Optimal Power Flow (OPF) and the VARPLAN computer codes for operations planning are examined. The OPF software can be used to determine if reactive outputs from nearby generators are scheduled properly, and to confirm that parallel transformers have been properly set. A major benefit of the system planning software VARPLAN is the ability to simultaneously consider both normal and contingency conditions, while adding a minimal amount of new reactive power. Applications to long-term system planning of new reactive power sources are described.

  14. Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freight pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedes

    E-Print Network [OSTI]

    Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freight pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedestrian > Ports and waterways >>> Transportation operat

  15. Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freig pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedestr

    E-Print Network [OSTI]

    Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freig pipeline transportation > Airport planning and development > Airport maintenance > Bicycle and pedestrian > Ports and waterways >>> Transportation ope

  16. Graduate Certificate in Transportation

    E-Print Network [OSTI]

    Bertini, Robert L.

    Graduate Certificate in Transportation Nohad A. Toulan School of Urban Studies and Planning of Engineering and Computer Science integrated transportation systems. The Graduate Certificate in Transportation their capabilities. Students in the program can choose among a wide range of relevant courses in transportation

  17. TRANSPORTATION Annual Report

    E-Print Network [OSTI]

    Minnesota, University of

    2003 CENTER FOR TRANSPORTATION STUDIES Annual Report #12;Center for Transportation Studies University of Minnesota 200 Transportation and Safety Building 511 Washington Avenue S.E. Minneapolis, MN publication is a report of transportation research, education, and outreach activities for the period July

  18. Minnesota's Transportation Economic Development (TED)

    E-Print Network [OSTI]

    Minnesota, University of

    Minnesota's Transportation Economic Development (TED) Pilot Program Center for Transportation Studies Transportation Research Conference May 24-25, 2011 #12;Transportation Role in Economic Development · Carefully targeted transportation infrastructure improvements will: ­ Stimulate new economic development

  19. Introduction Transport in disordered graphene

    E-Print Network [OSTI]

    Fominov, Yakov

    Introduction Transport in disordered graphene Summary Ballistic transport in disordered graphene P, Gornyi, Mirlin Ballistic transport in disordered graphene #12;Introduction Transport in disordered graphene Summary Outline 1 Introduction Model Experimental motivation Transport in clean graphene 2

  20. Analyzing the status of oxide surface photochemical reactivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    photochemical reactivity Released: July 28, 2013 Invited review shows power of scanning tunneling microscopy to understand and control the surface photochemistry of oxide...

  1. advanced reactivity measurement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alfredo) 2011-01-01 302 High Purity Ethyl Acetate Production with a Batch Reactive Distillation Column using Dynamic Optimization Strategy CiteSeer Summary: AbstractEthyl...

  2. advanced reactivity measurement facility-1: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alfredo) 2011-01-01 306 High Purity Ethyl Acetate Production with a Batch Reactive Distillation Column using Dynamic Optimization Strategy CiteSeer Summary: AbstractEthyl...

  3. Airborne measurement of OH reactivity during INTEX-B

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

  4. Optimization Online - Reactive Power Management using Firefly and ...

    E-Print Network [OSTI]

    Ripunjoy Phukan

    2013-10-04T23:59:59.000Z

    Oct 4, 2013 ... Reactive Power Management using Firefly and Spiral Optimization under Static and Dynamic Loading Conditions. Ripunjoy Phukan (ripun000 ...

  5. Advancing Reactive Tracer Methods for Measuring Thermal Evolution...

    Open Energy Info (EERE)

    Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Geothermal Lab Call Project Jump to: navigation, search Last...

  6. Quantitative Site-specific Reactivity Profiling of S-Nitrosylation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Profiling of S-Nitrosylation in Mouse Skeletal Muscle Using Cysteinyl Peptide Enrichment Quantitative Site-specific Reactivity Profiling of S-Nitrosylation in Mouse Skeletal...

  7. Geochemical evidence for anoxic deep water in the Arabian Sea during the last glaciation

    SciTech Connect (OSTI)

    Sarkar, A.; Bhattacharya, S.K.; Sarin, M.M. (Physical Research Lab., Ahmedabad (India))

    1993-03-01T23:59:59.000Z

    Various paleoceanographic studies have indicated that the deep ocean was probably depleted in dissolved oxygen during the last glacial period ([approximately]18 kyr B.P.; [delta][sup 18]O, stage 2) compared to present time. However, direct evidence of low oxygen content in the deep waters has been lacking. Here, the authors report geochemical evidence of near anoxic conditions in the deep Arabian Sea during the entire last glacial cycle ([delta][sup 18]O; stages 2, 3, and 4). Anoxia is inferred from the concomitant enrichment of organic carbon and authigenic uranium in the glacial sections of a core from the deep eastern Arabian Sea. The anoxic conditions during the last glacial period, probably caused by a change in deep water circulation, evidently enhanced preservation of organic matter and simultaneous removal of uranium from seawater. 57 refs., 3 figs., 2 tabs.

  8. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15T23:59:59.000Z

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and competency. The results from these investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological, deep subsurface CO2 storage and sequestration.

  9. High-resolution stratigraphic correlations and geochemical analyses, Cretaceous Niobrara formation, northwestern Denver-Julesburg Basin

    SciTech Connect (OSTI)

    Rodriguez, T.E.; Pratt, L.M.

    1985-05-01T23:59:59.000Z

    The middle Santonian-lower Campanian part of the Smoky Hill Member of the Niobrara Formation represents a fourth-order regressive-transgressive cyclotherm. Studies of this interval have improved our understanding of the influence of depositional environments and structural setting on distributions of organic matter in epicontinental marine strata. Geochemical analyses of fresh quarried sections at Lyons and LaPorte, Colorado, show that, in general, C/sub org/ (organic carbon) levels are highest between mid-regression and mid-transgression. Rhythmic fluctuations of C/sub carb/ (carbonate carbon) and C/sub org/ correspond to limestone-marlstone bedding couplets at a scale of 15-20 cm (6-8 in.). Pronounced lateral variations between Lyons and LaPorte exist in C/sub org/, HI (pyrolytic hydrogen index), sediment accumulation rates, and T/sub max/ (temperature of maximum pyrolytic yield). Comparisons of geochemical averages at Lyons and LaPorte indicate an elevated thermal maturity at Lyons and depositional conditions more favorable for preservation of marine organic matter at LaPorte. In both sections, C/sub org/ and C/sub carb/ show strong negative correlations, possibly reflecting cyclic climatic controls on the development of bedding couplets. High-resolution stratigraphic correlations of 100.000-year or smaller intervals between Boulder and Owl Canyon, Colorado, based on wide-spread bentonites and bedding couplets, reveal a paleostructural high near Lyons. Shallow-water conditions and increased turbulence over this high are reflected in sediment accumulation rates only 60% of those at LaPorte. Increased amounts and hydrogen richness of organic matter at LaPorte may reflect a deeper water, more quiescent depositional setting.

  10. Chromium-Removal Processes during Groundwater Remediation by a Zerovalent Iron Permeable Reactive Barrier

    SciTech Connect (OSTI)

    Wilkin, Richard T.; Su, Chunming; Ford, Robert G.; Paul, Cynthia J. (US EPA)

    2008-06-09T23:59:59.000Z

    Solid-phase associations of chromium were examined in core materials collected from a full-scale, zerovalent iron permeable reactive barrier (PRB) at the U.S. Coast Guard Support Center located near Elizabeth City, NC. The PRB was installed in 1996 to treat groundwater contaminated with hexavalent chromium. After eight years of operation, the PRB remains effective at reducing concentrations of Cr from average values >1500 {micro}g L{sup -1} in groundwater hydraulically upgradient of the PRB to values <1 {micro}g L{sup -1} in groundwater within and hydraulically downgradient of the PRB. Chromium removal from groundwater occurs at the leading edge of the PRB and also within the aquifer immediately upgradient of the PRB. These regions also witness the greatest amount of secondary mineral formation due to steep geochemical gradients that result from the corrosion of zerovalent iron. X-ray absorption near-edge structure (XANES) spectroscopy indicated that chromium is predominantly in the trivalent oxidation state, confirming that reductive processes are responsible for Cr sequestration. XANES spectra and microscopy results suggest that Cr is, in part, associated with iron sulfide grains formed as a consequence of microbially mediated sulfate reduction in and around the PRB. Results of this study provide evidence that secondary iron-bearing mineral products may enhance the capacity of zerovalent iron systems to remediate Cr in groundwater, either through redox reactions at the mineral-water interface or by the release of Fe(II) to solution via mineral dissolution and/or metal corrosion.

  11. Ground rubber: Reactive permeable barrier sorption media

    SciTech Connect (OSTI)

    Kershaw, D.S.; Pamukcu, S. [Lehigh Univ., Bethlehem, PA (United States)

    1997-12-31T23:59:59.000Z

    The objective of this research was to examine the feasibility of using ground tire rubber as a sorbent media in reactive permeable barrier systems. Previous research by the current authors has demonstrated that tire rubber can sorb significant quantities of benzene, toluene, ethylbenzene and O-xylene from aqueous solutions. The current research was run to examine the usage rate of ground rubber in a packed bed reactor under specific contact times. In addition, desorption and repetitive sorption tests were run to determine the reversibility of the sorption process for ground tire rubber. These tests were run to determine the regeneration capacity of ground tire rubber. Results of the study show that the usage rates are greater than 50% with an empty bed contact times of 37 minutes, and minimal amounts of energy are needed to regenerate the tire rubber after use.

  12. Completing the complex Poynting theorem: Conservation of reactive energy in reactive time

    E-Print Network [OSTI]

    Gerald Kaiser

    2014-12-11T23:59:59.000Z

    The complex Poynting theorem is extended canonically to a time-scale domain $(t, s)$ by replacing the phasors of time-harmonic fields by the analytic signals $X(r, t+is)$ of fields $X(r,t)$ with general time dependence. The imaginary time $s>0$ is shown to play the role of a time resolution scale, and the extended Poynting theorem splits into two conservation laws: its real part gives the conservation in $t$ of the scale-averaged active energy at fixed $s$, and its imaginary part gives the conservation in $s$ of the scale-averaged reactive energy at fixed $t$. At coarse scales (large $s$, slow time), where the system reduces to the circuit level, this may have applications to the theory of electric power transmission and conditioning. At fine scales (small $s$, fast time) it describes reactive energy dynamics in radiating systems.

  13. Secure Transportation Management

    SciTech Connect (OSTI)

    Gibbs, P. W. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-10-15T23:59:59.000Z

    Secure Transport Management Course (STMC) course provides managers with information related to procedures and equipment used to successfully transport special nuclear material. This workshop outlines these procedures and reinforces the information presented with the aid of numerous practical examples. The course focuses on understanding the regulatory framework for secure transportation of special nuclear materials, identifying the insider and outsider threat(s) to secure transportation, organization of a secure transportation unit, management and supervision of secure transportation units, equipment and facilities required, training and qualification needed.

  14. Water Transport Within the STack: Water Transport Exploratory...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Within the STack: Water Transport Exploratory Studies Water Transport Within the STack: Water Transport Exploratory Studies Part of a 100 million fuel cell award announced by DOE...

  15. Hydrologic and geochemical controls on soluble benzene migration in sedimentary basins

    E-Print Network [OSTI]

    Polly, David

    , a coupled ground- water flow and heat transfer model computes the hydraulic head, stream function, and temperature in the basin. A coupled mass transport model simulates water washing of benzene from an oil reservoir and its miscible, advective/dispersive transport by groundwater. Benzene mass transfer at the oil­water

  16. Assessment of sequence homology and cross-reactivity

    SciTech Connect (OSTI)

    Aalberse, Rob C. [Department of Immunopathology, Sanquin Research at CLB, Plesmanlaan 125, 1066 CX Amsterdam (Netherlands) and Landsteiner Laboratory, Academic Medical Centre, 1066 CX Amsterdam (Netherlands)]. E-mail: r.aalberse@sanquin.nl

    2005-09-01T23:59:59.000Z

    Three aspects of allergenicity assessment and are discussed: IgE immunogenicity, IgE cross-reactivity and T cell cross-reactivity, all with emphasis on in-silico predictability: from amino acid sequence via 3D structure to allergenicity.(1)IgE immunogenicity depends to an overwhelming degree on factors other than the protein itself: the context and history of the protein by the time it reaches the immune system. Without specification of these two factors very few foreign proteins can be claimed to be absolutely non-allergenic. Any antigen may be allergenic, particularly if it avoids activation of TH2-suppressive mechanisms (CD8 cells, TH1 cells, other regulatory T cells and regulatory cytokines). (2)IgE cross-reactivity can be much more reliably assessed by a combination of in-silico homology searches and in vitro IgE antibody assays. The in-silico homology search is unlikely to miss potential cross-reactivity with sequenced allergens. So far, no biologically relevant cross-reactivity at the antibody level has been demonstrated between proteins without easily-demonstrable homology. (3)T cell cross-reactivity is much more difficult to predict compared to B cell cross-reactivity, and its effects are more diverse. Yet, pre-existing cross-reactive T cell activity is likely to influence the outcome not only of the immune response, but also of the effector phase of the allergic reaction.

  17. SHUSH: Reactive Transmit Power Control For Wireless MAC Protocols

    E-Print Network [OSTI]

    Han, Richard Y.

    SHUSH: Reactive Transmit Power Control For Wireless MAC Protocols Anmol Sheth and Richard Han@cs.colorado.edu Abstract-- Asymmetric transmission ranges caused due to transmit power control have the undesirable effect access. In this paper we present a new reactive power controlled MAC protocol, SHUSH, which tackles

  18. The Specification and Execution of Heterogeneous Synchronous Reactive Systems

    E-Print Network [OSTI]

    The Specification and Execution of Heterogeneous Synchronous Reactive Systems by Stephen Anthony in Engineering---Electrical Engineering and Computer Sciences in the GRADUATE DIVISION of the UNIVERSITY of Heterogeneous Synchronous Reactive Systems Copyright ã 1997 by Stephen Anthony Edwards #12; Abstract

  19. A Modified Reactive Control Framework for Cooperative Mobile Robots

    E-Print Network [OSTI]

    A Modified Reactive Control Framework for Cooperative Mobile Robots J. Salido a , J.M. Dolan a , J Dept. of Electrical & Computer Engineering, Carnegie Mellon Univ. Pittsburgh, PA 15213­3890 USA. Purely reactive approaches such as that of Brooks are efficient, but lack a mechanism for global control

  20. Reactive Sputtering of Bismuth Vanadate Photoanodes for Solar Water Splitting

    E-Print Network [OSTI]

    Javey, Ali

    Reactive Sputtering of Bismuth Vanadate Photoanodes for Solar Water Splitting Le Chen,, Esther of Electrical Engineering and Computer Sciences, University of California, Berkeley, Berkeley, California 94720 has remained relatively underexplored. Here, we report the synthesis of BiVO4 thin films by reactive

  1. Reactive Rearrangement of Parts under Sensor Inaccuracy: Particle Filter Approach

    E-Print Network [OSTI]

    Reactive Rearrangement of Parts under Sensor Inaccuracy: Particle Filter Approach Hal^uk Bayram, Electrical and Electronic Engineering Bogazici University, Bebek 34342 Istanbul Turkey Abstract-- The paper will be left undisturbed, the robot is required to employ a reactive strategy. A feedback-based event

  2. Reactive oxygen species deglycosilate glomerular a-dystroglycan

    E-Print Network [OSTI]

    Campbell, Kevin P.

    Reactive oxygen species deglycosilate glomerular a-dystroglycan NPJ Vogtla¨nder1 , WPM Tamboer1 open. Reactive oxygen species (ROS) are known to degrade and depolymerize carbohydrates, and to playDa in skeletal muscle, ranging from 120 kDa in brain to 190 kDa in the Torpedo electric organ.8

  3. Towards Interactive Timing Analysis for Designing Reactive Systems

    E-Print Network [OSTI]

    Towards Interactive Timing Analysis for Designing Reactive Systems Insa Fuhrmann David Broman Steven Smyth Reinhard von Hanxleden Electrical Engineering and Computer Sciences University of California Interactive Timing Analysis for Designing Reactive Systems Insa Fuhrmann1 , David Broman2,3 , Steven Smyth1

  4. Reactive ion etched substrates and methods of making and using

    DOE Patents [OSTI]

    Rucker, Victor C. (San Francisco, CA); Shediac, Rene (Oakland, CA); Simmons, Blake A. (San Francisco, CA); Havenstrite, Karen L. (New York, NY)

    2007-08-07T23:59:59.000Z

    Disclosed herein are substrates comprising reactive ion etched surfaces and specific binding agents immobilized thereon. The substrates may be used in methods and devices for assaying or isolating analytes in a sample. Also disclosed are methods of making the reactive ion etched surfaces.

  5. A REACTIVE APPROACH FOR MINING PROJECT EVALUATION UNDER PRICE UNCERTAINTY

    E-Print Network [OSTI]

    Duffy, Ken

    A REACTIVE APPROACH FOR MINING PROJECT EVALUATION UNDER PRICE UNCERTAINTY Meimei Zhang. This method often undervalues a mining project since it ignores future price uncertainty and does not allow on metal price. This paper also demonstrates that the "reactive" approach can estimate the mine project

  6. CLASSIFICATION AND REACTIVITY OF SECONDARY ALUMINUM PRODUCTION WASTE

    E-Print Network [OSTI]

    environment.14 Keywords: Landfills, aluminum, hydrogen, salt cake, dross, calorimeter, waste disposal15 16 17CLASSIFICATION AND REACTIVITY OF SECONDARY ALUMINUM PRODUCTION WASTE Navid H. Jafari Student Member and Reactivity of Secondary Aluminum Production Waste1 Navid H. Jafari1 , Timothy D. Stark2 and Ralph Roper3 2 3

  7. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01T23:59:59.000Z

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  8. Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures

    E-Print Network [OSTI]

    Goddard III, William A.

    Early maturation processes in coal. Part 2: Reactive dynamics simulations using the ReaxFF reactive force field on Morwell Brown coal structures Elodie Salmon a , Adri C.T. van Duin b , François Lorant Brown coal using the ReaxFF reactive force field. We find that these reactive MD simulations

  9. Vadose Zone Transport Field Study: Summary Report

    SciTech Connect (OSTI)

    Ward, Andy L.; Conrad, Mark E.; Daily, William D.; Fink, James B.; Freedman, Vicky L.; Gee, Glendon W.; Hoversten, Gary M.; Keller, Jason M.; Majer, Ernest L.; Murray, Christopher J.; White, Mark D.; Yabusaki, Steven B.; Zhang, Z. F.

    2006-07-31T23:59:59.000Z

    From FY 2000 through FY 2003, a series of vadose zone transport field experiments were conducted as part of the U.S. Department of Energy’s Groundwater/Vadose Zone Integration Project Science and Technology Project, now known as the Remediation and Closure Science Project, and managed by the Pacific Northwest National Laboratory (PNNL). The series of experiments included two major field campaigns, one at a 299-E24-11 injection test site near PUREX and a second at a clastic dike site off Army Loop Road. The goals of these experiments were to improve our understanding of vadose zone transport processes; to develop data sets to validate and calibrate vadose zone flow and transport models; and to identify advanced monitoring techniques useful for evaluating flow-and-transport mechanisms and delineating contaminant plumes in the vadose zone at the Hanford Site. This report summarizes the key findings from the field studies and demonstrates how data collected from these studies are being used to improve conceptual models and develop numerical models of flow and transport in Hanford’s vadose zone. Results of these tests have led to a better understanding of the vadose zone. Fine-scale geologic heterogeneities, including grain fabric and lamination, were observed to have a strong effect on the large-scale behavior of contaminant plumes, primarily through increased lateral spreading resulting from anisotropy. Conceptual models have been updated to include lateral spreading and numerical models of unsaturated flow and transport have revised accordingly. A new robust model based on the concept of a connectivity tensor was developed to describe saturation-dependent anisotropy in strongly heterogeneous soils and has been incorporated into PNNL’s Subsurface Transport Over Multiple Phases (STOMP) simulator. Application to field-scale transport problems have led to a better understanding plume behavior at a number of sites where lateral spreading may have dominated waste migration (e.g. BC Cribs and Trenches). The improved models have been also coupled with inverse models and newly-developed parameter scaling techniques to allow estimation of field-scale and effective transport parameters for the vadose zone. The development and utility of pedotransfer functions for describing fine-scale hydrogeochemical heterogeneity and for incorporating this heterogeneity into reactive transport models was explored. An approach based on grain-size statistics appears feasible and has been used to describe heterogeneity in hydraulic properties and sorption properties, such as the cation exchange capacity and the specific surface area of Hanford sediments. This work has also led to the development of inverse modeling capabilities for time-dependent, subsurface, reactive transport with transient flow fields using an automated optimization algorithm. In addition, a number of geophysical techniques investigated for their potential to provide detailed information on the subtle changes in lithology and bedding surfaces; plume delineation, leak detection. High-resolution resistivity is now being used for detecting saline plumes at several waste sites at Hanford, including tank farms. Results from the field studies and associated analysis have appeared in more than 46 publications generated over the past 4 years. These publications include test plans and status reports, in addition to numerous technical notes and peer reviewed papers.

  10. A three-dimensional model of microbial transport and biodegradation at the Schoolcraft, Michigan, site

    E-Print Network [OSTI]

    ; revised 3 January 2005; accepted 21 January 2005; published 13 May 2005. [1] Bioremediation can be a cost-dimensional reactive transport modeling of carbon tetrachloride (CT) bioremediation at the Schoolcraft site in western success- ful application of bioremediation has been documented at several sites containing chlorinated

  11. Transportation Infrastructure and Sustainable Development

    E-Print Network [OSTI]

    Boarnet, Marlon G.

    2008-01-01T23:59:59.000Z

    A Better Forecasting Tool for Transportation Decision-making,” Mineta Transportation Institute, San Jose Stateat the 2008 meeting of the Transportation Research Board and

  12. Transportation Analysis | Clean Energy | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Analysis SHARE Transportation Analysis Transportation Analysis efforts at Oak Ridge National Laboratory contribute to the efficient, safe, and free movement of...

  13. Transportation Investment and

    E-Print Network [OSTI]

    Levinson, David M.

    Transportation Investment and Economic Development: Has the TIED turned? David Levinson University Transportation Investments was Historically Concomitant with Land and Economic Development #12;Canals Railways Surfaced Roads Crude Oil Pipelines Gas Pipelines Telegraph 1825 1985 Proportion of Maximum Extent Growth

  14. Transportation Management Research Collection /

    E-Print Network [OSTI]

    Handy, Todd C.

    , Peterbilt Motors, and General Electric. He was a national panel member of the American Arbitration, Noise and Environmental Pollution, Transportation Co-ordination and Consolidation, Transportation -- Docket 8613 1957 Civil Aeronautics Board ­ General passenger fare investigation -- Docket 8008 et al

  15. Packaging and Transportation Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1995-09-27T23:59:59.000Z

    Establishes safety requirements for the proper packaging and transportation of offsite shipments and onsite transfers of hazardous materials andor modal transport. Cancels DOE 1540.2 and DOE 5480.3

  16. Packaging and Transportation Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1995-09-27T23:59:59.000Z

    Establishes safety requirements for the proper packaging and transportation of Department of Energy (DOE) offsite shipments and onsite transfers of hazardous materials and for modal transport. Canceled by DOE 460.1A

  17. Packaging and Transportation Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1996-10-02T23:59:59.000Z

    Establishes safety requirements for the proper packaging and transportation of Department of Energy (DOE) offsite shipments and onsite transfers of hazardous materials and for modal transport. Cancels DOE O 460.1.

  18. Biofuels and Transportation

    E-Print Network [OSTI]

    Minnesota, University of

    Biofuels and Transportation Impacts and Uncertainties Some Observations of a Reformed Ethanol and Logistics Symposium 3 Topics · Why Biofuels · Ethanol Economics · Ethanol Transportation Equipment Biofuels? · National Security · Reduce Imports of oil · Peak Oil · Replace Fossil Resources

  19. Linear Motor Powered Transportation

    E-Print Network [OSTI]

    Thornton, Richard D.

    This special issue on linear-motor powered transportation covers both supporting technologies and innovative transport systems in various parts of the World, as this technology moves from the lab to commercial operations. ...

  20. Transportation Management Workshop: Proceedings

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    This report is a compilation of discussions presented at the Transportation Management Workshop held in Gaithersburg, Maryland. Topics include waste packaging, personnel training, robotics, transportation routing, certification, containers, and waste classification.

  1. Geologic, geophysical, and geochemical aspects of site-specific studies of the geopressured-geothermal energy resource of southern Louisiana. Final report

    SciTech Connect (OSTI)

    Pilger, R.H. Jr. (ed.)

    1985-01-01T23:59:59.000Z

    The report consists of four sections dealing with progress in evaluating geologic, geochemical, and geophysical aspects of geopressured-geothermal energy resources in Louisiana. Separate abstracts have been prepared for the individual sections. (ACR)

  2. Geochemical maps showing the distribution and abundance of selected elements in stream-sediment samples, Solomon and Bendeleben 1 degree by 3 degree quadrangles, Seward Peninsula, Alaska

    SciTech Connect (OSTI)

    Smith, S.C.; King, H.D.; O'Leary, R.M.

    1989-01-01T23:59:59.000Z

    Geochemical maps showing the distribution and abundance of selected elements in stream-sediment samples, Solomon and Bendeleben 1{degree} by 3{degree} quadrangles, Seward Peninsula, Alaska is presented.

  3. Indianapolis Public Transportation Corporation

    SciTech Connect (OSTI)

    Not Available

    2004-12-01T23:59:59.000Z

    Fact sheet describes the National Renewable Energy Laboratory's evaluation of Indianapolis Public Transportation Corporation's (IndyGo's) hybrid electric buses.

  4. Lubbock Metropolitan Transportation Plan

    E-Print Network [OSTI]

    Lubbock Metropolitan Planning Organization

    2007-09-18T23:59:59.000Z

    for Users (SAFETEA-LU) and its predecessors, the Transportation Equity Act for the 21st Century (TEA-21) and the Intermodal Surface Transportation Efficiency Act (ISTEA) of 1991, specified the transportation systems on which certain federal funds can... in Chapter 5 ? Streets and Highways; Chapter 6 ? Public Transportation; Chapter 7 ? Bicycle and Pedestrian Plan; Chapter 8 ? Lubbock International Airport and Chapter 9 ? Railroads and Trucking. Federally funded transit projects were developed...

  5. Transportation and its Infrastructure

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    subsidies on fossil transport fuels, subsidies on commutingC. , 2003: Subsidies that encourage fossil fuel use in

  6. Northwestern University Transportation Center

    E-Print Network [OSTI]

    Bustamante, Fabián E.

    Northwestern University Transportation Center 2011 Business Advisory Committee NUTC #12;#12;I have the pleasure of presenting our Business Advisory Committee members--a distinguished group of transportation industry lead- ers who have partnered with the Transportation Center in advancing the state of knowledge

  7. PalladianDigest Transportation

    E-Print Network [OSTI]

    Farritor, Shane

    PalladianDigest CONNECT. EMPOWER. GROW. Tackling Transportation Challenges Nebraska has been a vital link in the nation's transportation system since the days when carts, wagons to University of Nebraska­Lincoln research. That's fine with UNL transportation researchers, said Larry Rilett

  8. TRANSPORTATION: THE POTENTIAL

    E-Print Network [OSTI]

    Minnesota, University of

    INTERMODAL TRANSPORTATION: THE POTENTIAL AND THE CHALLENGE A Summary Report 2003 #12;June 2003 To the Reader This report summarizes the second James L. Oberstar Forum on Transportation Policy and Technology. Over two days, we explored the chal- lenges and opportunities in intermodal transportation, addressing

  9. Louisiana Transportation Research Center

    E-Print Network [OSTI]

    Harms, Kyle E.

    Louisiana Transportation Research Center LTRC www.ltrc.lsu.edu 2012-13 ANNUALREPORT #12;The Louisiana Transportation Research Center (LTRC) is a research, technology transfer, and training center administered jointly by the Louisiana Department of Transportation and Development (DOTD) and Louisiana State

  10. Introduction to Transportation Planning

    E-Print Network [OSTI]

    Tipple, Brett

    Introduction to Transportation Planning CMP 4710/6710 Fall 2012 3 Credit Hours Room: ARCH 229 on a Saturday night, transportation is not an objective in and of itself, but a means to carry out the functions of daily living (i.e., it's a "derived good"). As a consequence, the transportation systems we build

  11. Rural Intelligent Transportation Systems

    E-Print Network [OSTI]

    Minnesota, University of

    Rural Intelligent Transportation Systems In a technical session at the 2011 NACE conference, Dennis Foderberg of SEH Inc. discussed intelligent transportation systems (ITS) developed by SEH in collaboration with Network Transportation Technologies, Inc. These systems address the problem of crashes on low-volume roads

  12. Preburn versus postburn mineralogical and geochemical characteristics of overburden and coal at the Hanna, Wyoming underground coal gasification site

    SciTech Connect (OSTI)

    Oliver, R.L.; Youngberg, A.D.

    1983-12-01T23:59:59.000Z

    Hundreds of mineralogic and geochemical tests were done under US Department of Energy contracts on core samples taken from the Hanna underground coal gasification site. These tests included x-ray diffraction studies of minerals in coal ash, overburden rocks, and heat-altered rocks; x-ray fluorescence analyses of oxides in coal ash and heat-altered rocks; semi-quantitative spectrographic analyses of elements in coal, overburden, and heat-altered rocks; chemical analyses of elements and compounds in coal, overburden, and heat-altered rocks and ASTM proximate and ultimate analyses of coal and heat-altered coal. These data sets were grouped, averaged, and analyzed to provide preburn and postburn mineralogic and geochemical characteristics of rock units at the site. Where possible, the changes in characteristics from the preburn to the postburn state are related to underground coal gasification processes. 11 references, 13 figures, 8 tables.

  13. GEOCHEMICAL APPROACHES TO THE STUDY OF LIFE AND DEATH OF DINOSAURS FROM THE EARLY CRETACEOUS CEDAR MOUNTAIN FORMATION, UTAH

    E-Print Network [OSTI]

    Suarez, Celina Angelica

    2010-04-22T23:59:59.000Z

    ___________________________ G.L. Macpherson ___________________________ Larry D. Martin Date defended:_______________ iii ABSTRACT Celina A. Suarez, Ph.D. Department of Geology, April 2010 University of Kansas In this dissertation, geochemical analysis..., it can be determined that the proximity of the Western Interior Seaway and the rise of the Sevier Mountains were the cause of isotopic variability and dominant control on regional climate during the Cedar Mountain Formation time. iv...

  14. Microbial distributions detected by an oligonucleotide microarray across geochemical zones associated with methane in marine sediments from the Ulleung Basin

    SciTech Connect (OSTI)

    Briggs, Brandon R.; Graw, Michael; Brodie, Eoin L.; Bahk, Jang-Jun; Kim, Sung-Han; Hyun, Jung-Ho; Kim, Ji-Hoon; Torres, Marta; Colwell, Frederick S.

    2013-11-01T23:59:59.000Z

    The biogeochemical processes that occur in marine sediments on continental margins are complex; however, from one perspective they can be considered with respect to three geochemical zones based on the presence and form of methane: sulfate–methane transition (SMTZ), gas hydrate stability zone (GHSZ), and free gas zone (FGZ). These geochemical zones may harbor distinct microbial communities that are important in biogeochemical carbon cycles. The objective of this study was to describe the microbial communities in sediments from the SMTZ, GHSZ, and FGZ using molecular ecology methods (i.e. PhyloChip microarray analysis and terminal restriction fragment length polymorphism (T-RFLP)) and examining the results in the context of non-biological parameters in the sediments. Non-metric multidimensional scaling and multi-response permutation procedures were used to determine whether microbial community compositions were significantly different in the three geochemical zones and to correlate samples with abiotic characteristics of the sediments. This analysis indicated that microbial communities from all three zones were distinct from one another and that variables such as sulfate concentration, hydrate saturation of the nearest gas hydrate layer, and depth (or unmeasured variables associated with depth e.g. temperature, pressure) were correlated to differences between the three zones. The archaeal anaerobic methanotrophs typically attributed to performing anaerobic oxidation of methane were not detected in the SMTZ; however, the marine benthic group-B, which is often found in SMTZ, was detected. Within the GHSZ, samples that were typically closer to layers that contained higher hydrate saturation had indicator sequences related to Vibrio-type taxa. These results suggest that the biogeographic patterns of microbial communities in marine sediments are distinct based on geochemical zones defined by methane.

  15. Uncertainty in the reactive transport model response to an alkaline perturbation in a clay formation

    E-Print Network [OSTI]

    Burnol, A.; Blanc, P.; Xu, T.; Spycher, N.; Gaucher, E.C.

    2006-01-01T23:59:59.000Z

    degradation of a concrete/clay interface, in Migration'05 -an alkaline plume in a clay barrier, Applied Geochemistry,AN ALKALINE PERTURBATION IN A CLAY FORMATION A. Burnol*, P.

  16. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    E-Print Network [OSTI]

    Zheng, L.

    2010-01-01T23:59:59.000Z

    experiment in Opalinus Clay for the management ofconductivity of the Opalinus clay at a regional scale:1953. Adsorption studies on clay minerals. II. A formulation

  17. Understanding the Subsurface Reactive Transport of Transuranic Contaminants at DOE Sites

    SciTech Connect (OSTI)

    Barnett, Mark O. [Auburn University] [Auburn University; Albrecht-Schmitt, Thomas E. [University of Notre Dame] [University of Notre Dame; Saiers, James E. [Yale University] [Yale University; Shuh, David K. [Lawrence Berkeley National Laboratory] [Lawrence Berkeley National Laboratory

    2013-12-20T23:59:59.000Z

    Our primary hypothesis is that actinides can interact with surfaces in fundamentally different ways than other metals, metalloids, and oxyanions and that this fundamental difference requires new approaches to studying and modeling transuranic sorption to minerals and geomedia. This project supports a key mission of the SBR program to develop sufficient scientific understanding such that DOE sites will be able to incorporate coupled physical, chemical, and biological processes into decision making for environmental management and long-term stewardship, while also supporting DOE’s commitment to education, training, and collaboration with DOE user facilities.

  18. Reactive Transport and Coupled THM Processes in Engineering Barrier Systems (EBS)

    E-Print Network [OSTI]

    Steefel, Carl

    2010-01-01T23:59:59.000Z

    Analytical Methods in Geomechanics 29, 751–787, 2005. Sato,Analytical Methods in Geomechanics, 29:751-787. Schanz, T. ,and Analytical Methods in Geomechanics, 29: 751-787. Thomas,

  19. A model for transport and agglomeration of particles in reactive ion etching plasma reactors

    E-Print Network [OSTI]

    Kushner, Mark

    drag, electrostatic, neutral drag, thermophoretic, gravitational, and self-diffusion. Ion drag forces

  20. An exponential integrator for advection-dominated reactive transport in heterogeneous porous media

    E-Print Network [OSTI]

    Lord, Gabriel

    such as dissolved minerals, colloids, or contaminants, over long distances3 through the highly heterogeneous porous contamination and sustainable use of groundwater resources, storing7 greenhouse gases (e.g, CO2) or radioactive or contaminants and long tailing at late16 time [3]. Chemical reaction rates and equilibrium constants can vary

  1. Reactive Transport and Coupled THM Processes in Engineering Barrier Systems (EBS)

    E-Print Network [OSTI]

    Steefel, Carl

    2010-01-01T23:59:59.000Z

    Pressurized Water Reactor (PWR) used nuclear fuel. The firstrepository tunnels, the PWR type of used fuel is typicallyby the length of individual PWR fuel elements and the number

  2. A sequential partly iterative approach for multicomponent reactive transport with CORE2D

    E-Print Network [OSTI]

    Samper, J.

    2009-01-01T23:59:59.000Z

    Juncosa R. , Delgado J. and Montenegro L. (2000) CORE 2D : App. Samper, J. , Yang, C. , Montenegro, L. , 2003. CORE 2DSamper, J. , Zhang, G. , Montenegro, L. , 2006a. Coupled

  3. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    E-Print Network [OSTI]

    Zheng, L.

    2010-01-01T23:59:59.000Z

    Samper, J. , Zheng, L. , Montenegro, L. , 2006c. CoupledSamper, J. , Zheng, L. , Montenegro, L. , Fernández, A.M. ,A.M. Fernández and L. Montenegro, 2008b, Inverse modeling of

  4. Geophysical monitoring and reactive transport modeling of ureolytically-driven calcium carbonate precipitation

    E-Print Network [OSTI]

    Wu, Y.

    2012-01-01T23:59:59.000Z

    F. S. ; Smith, R. W. , Calcium Carbonate Precipitation byF. , Microbially Mediated Calcium Carbonate Precipitation:through mixing of calcium and carbonate solutions in a glass

  5. Reactive Transport and Coupled THM Processes in Engineering Barrier Systems (EBS)

    E-Print Network [OSTI]

    Steefel, Carl

    2010-01-01T23:59:59.000Z

    from radioactive waste begins to heat up the near field ofbuffer, next to the heat-releasing waste canister, moistureis dominated by heat input from the waste canister with a

  6. Modeling reactive transport in deformable porous media using the theory of interacting continua.

    SciTech Connect (OSTI)

    Turner, Daniel Zack

    2012-01-01T23:59:59.000Z

    This report gives an overview of the work done as part of an Early Career LDRD aimed at modeling flow induced damage of materials involving chemical reactions, deformation of the porous matrix, and complex flow phenomena. The numerical formulation is motivated by a mixture theory or theory of interacting continua type approach to coupling the behavior of the fluid and the porous matrix. Results for the proposed method are presented for several engineering problems of interest including carbon dioxide sequestration, hydraulic fracturing, and energetic materials applications. This work is intended to create a general framework for flow induced damage that can be further developed in each of the particular areas addressed below. The results show both convincing proof of the methodologies potential and the need for further validation of the models developed.

  7. Multicomponent reactive transport modeling at the Ratones uranium mine, Cceres (Spain)

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    abandonadas puede dar lugar a impactos importantes en la calidad del agua subterránea. Por lo tanto, predecir Ratones es una mina de uranio subterránea, que fue abandonada e inundada en 1974. Gracias al ambiente

  8. Bioclogging and Permeability Alteration by L. mesenteroides in a Sandstone Reservoir: A Reactive Transport Modeling Study

    E-Print Network [OSTI]

    Hubbard, Susan

    -Enhanced- Hydrocarbon-Recovery (MEHR).2 During water flooding in secondary recovery, hydrocarbons in highly permeable systems to favorable performance conditions. Applications may include microbial-enhanced-hydrocarbon-recovery

  9. ANALYSIS OF AN EULER IMPLICIT -MIXED FINITE ELEMENT SCHEME FOR REACTIVE SOLUTE TRANSPORT IN POROUS

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    the hydraulic conductivity and z the height against the gravitational direction. The Richards equation results by using the Darcy law Q = -K(())( + z),(1.4) in the mass balance equation for water, which is assumed

  10. Advective and diffusive contributions to reactive gas transport during pyrite oxidation in the unsaturated

    E-Print Network [OSTI]

    Russell, Thomas F.

    in the unsaturated zone P. J. Binning,1 D. Postma,1 T. F. Russell,2 J. A. Wesselingh,3 and P. F. Boulin1 Received 29. F. Russell, J. A. Wesselingh, and P. F. Boulin (2007), Advective and diffusive contributions

  11. A new mobileimmobile model for reactive solute transport with scaledependent dispersion

    E-Print Network [OSTI]

    Zhan, Hongbin

    Gao,1,2 Hongbin Zhan,3 Shaoyuan Feng,2 Bojie Fu,1 Ying Ma,2 and Guanhua Huang2,4 Received 28 September

  12. An analytical solution of two-dimensional reactive solute transport in an aquifer-aquitard system

    E-Print Network [OSTI]

    Zhan, Hongbin

    Hongbin Zhan,1 Zhang Wen,2 and Guangyao Gao3 Received 27 September 2008; revised 7 May 2009; accepted 21

  13. One-dimensional solute transport in a permeable reactive barrieraquifer system

    E-Print Network [OSTI]

    Zhan, Hongbin

    and Hongbin Zhan2 Received 12 May 2008; revised 23 March 2009; accepted 30 April 2009; published 15 July 2009

  14. Reactive Transport Modeling of Natural Attenuation in Stormwater Bioretention Cells and Under Land Application of Wastewater

    E-Print Network [OSTI]

    Zhang, Jingqiu

    2014-04-29T23:59:59.000Z

    application. Due to less water and chemical input, climate patterns may lead to better removal of heavy metals. For land application of Oil and Gas Exploration and Production wastewater, five scenarios were developed to study the impact of chloride, salts...

  15. Transportation YOU 2013 DC Youth Summit WTS Transportation YOU

    E-Print Network [OSTI]

    Minnesota, University of

    Transportation YOU 2013 DC Youth Summit WTS Transportation YOU CTS Research Conference May 21, 2014 Lisa Rasmussen, WTS / Kimley-Horn and Associates, Inc #12;Transportation YOU 2013 DC Youth SummitTransportation YOU 2013 DC Youth Summit Agenda What is Transportation YOU? Transportation YOU ­ WTS Local Chapter

  16. Evidence of Reactive Aromatics As a Major Source of Peroxy Acetyl Nitrate over China

    SciTech Connect (OSTI)

    Liu, Zhen; Wang, Yuhang; Gu, Dasa; Zhao, Chun; Huey, L. G.; Stickel, Robert; Liao, Jin; Shao, Min; Zhu, T.; Zeng, Limin; Liu, Shaw C.; Chang, Chih-Chung; Amoroso, Antonio; Costabile, Francesa

    2010-09-15T23:59:59.000Z

    We analyze the observations of near-surface peroxy acetyl nitrate (PAN) and its precursors in Beijing, China in August of 2007. The levels of PAN are remarkably high (up to 14 ppbv), surpassing those measured over other urban regions in recent years. Analyses employing a 1-D version of a chemical transport model (Regional chEmical and trAnsport Model, REAM) indicate that aromatic non-methane hydrocarbons (NMHCs) are the dominant (55-75%) PAN source. The major oxidation product of aromatics that produces acetyl peroxy radicals is methylglyoxal (MGLY). PAN and O3 in the observations are correlated at daytime; aromatic NMHCs appear to play an important role in O3 photochemistry. Previous NMHC measurements indicate the presence of reactive aromatics at high levels over broad polluted regions of China. Aromatics are often ignored in global and (to a lesser degree) regional 3D photochemical transport models; their emissions over China as well as photochemistry are quite uncertain.Our findings suggest that critical assessments of aromatics emissions and chemistry (such as the yields of MGLY) are necessary to understand and assess ozone photochemistry and regional pollution export in China.

  17. Center for Intermodal Transportation Safety

    E-Print Network [OSTI]

    Fernandez, Eduardo

    Center for Intermodal Transportation Safety and Security Panagiotis Scarlatos, Ph.D., Director Transportation Safety and Security #12;Center for Intermodal Transportation Safety and Security Partners #12 evacuations · Tracking systems for hazardous materials Center for Intermodal Transportation Safety

  18. Public Works Transportation Infrastructure Study

    E-Print Network [OSTI]

    Minnesota, University of

    Public Works Transportation Infrastructure Study Minneapolis City of Lakes Minneapolis Public Works Transportation Infrastructure Study #12;Public Works Transportation Infrastructure Study Minneapolis City Works Transportation Infrastructure Study Minneapolis City of Lakes Background: · Currently, funding

  19. Synthesis, characterization, and reactivity studies of iridium complexes bearing the ligand diphenylphosphidoboratabenzene

    E-Print Network [OSTI]

    Arizpe, Luis (Luis Alfredo)

    2011-01-01T23:59:59.000Z

    The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement ...

  20. Reactivity of iron-bearing minerals and CO2 sequestration: A...

    Office of Scientific and Technical Information (OSTI)

    Reactivity of iron-bearing minerals and CO2 sequestration: A multi-disciplinary experimental approach Re-direct Destination: The reactivity of sandstones was studied under...

  1. Aging Enhances the Production of Reactive Oxygen Species andBactericid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

  2. Metal-Pyrrolide Complexes in Three-fold Symmetry: Synthesis, Structure, Reactivity and Magnetism

    E-Print Network [OSTI]

    Harman, William Hill

    2010-01-01T23:59:59.000Z

    Structure, Reactivity and Magnetism by William Hill Harman AStructure, Reactivity and Magnetism by William Hill Harmanlost time. Dave taught me magnetism and what it takes to win

  3. Effect of shape reactivity on the rod-ejection accident

    SciTech Connect (OSTI)

    Neogy, P.; Carew, J.F.

    1982-09-01T23:59:59.000Z

    The shape reactivity has a significant influence on the rod ejection accident. After the control rod is fully ejected from the core, the neutron flux undergoes a large reduction at the ejected rod location. The corresponding effect on the control reactivity is comparable in magnitude to the Doppler reactivity, and makes a significant contribution to limiting the power excursion during the transient. The neglect of this effect in point kinetics and space time synthesis analyses of the rod ejection accident may account in part for the large degree of conservatism usually associated with these analyses.

  4. Geochemical and physical properties of soils and shallow sediments at the Savannah River Site

    SciTech Connect (OSTI)

    Looney, B.B.; Eddy, C.A.; Ramdeen, M.; Pickett, J. (Savannah River Lab., Aiken, SC (USA)); Rogers, V. (Soil Conservation Service, Aiken, SC (USA). Savannah River Site Savannah River Lab., Aiken, SC (USA)); Scott, M.T.; Shirley, P.A. (Sirrine Environmental Consultants, Greenville, SC (USA))

    1990-08-31T23:59:59.000Z

    A program to characterize the geochemical and physical properties of the unimpacted soils and shallow sediments at the Savannah River Site (SRS) has been completed. The maximum, minimum, median, standard deviation, and mean values for metals, radionuclides, inorganic anions, organic compounds, and agricultural indicator parameters are summarized for six soil series that were identified as representative of the 29 soil series at SRS. The soils from unimpacted areas of SRS are typical of soils found in moderately aggressive weathering environments, including the southeastern United States. Appendix 8 organic compounds were detected in all samples. Since these constituents are not generally present in soil, this portion of the investigation was intended to assess possible laboratory artifacts. An additional objective of the SRS Soil Study was to determine if the composition of the split spoon sampler biased chemical analysis of the soils. Twenty-five duplicate samples were analyzed for a number of metals, radiological and agricultural parameters, and organics by two laboratories currently contracted with to analyze samples during waste site characterization. In all cases, the absolute values of the average differences are relatively small compared to the overall variability in the population. 31 refs., 14 figs., 48 tabs.

  5. Geophysical Monitoring of Coupled Microbial and Geochemical Processes During Stimulated Subsurface Bioremediation

    SciTech Connect (OSTI)

    Williams, Kenneth H.; Kemna, Andreas; Wilkins, Michael J.; Druhan, Jennifer L.; Arntzen, Evan V.; N'Guessan, A. Lucie; Long, Philip E.; Hubbard, Susan S.; Banfield, Jillian F.

    2009-08-05T23:59:59.000Z

    Understanding how microorganisms alter their physical and chemical environment during bioremediation is hindered by our inability to resolve subsurface microbial activity with high spatial resolution. Here we demonstrate the use of a minimally invasive geophysical technique to monitor stimulated microbial activity during acetate amendment in an aquifer near Rifle, Colorado. During electrical induced polarization (IP) measurements, spatiotemporal variations in the phase response between imposed electric current and the resultant electric field correlated with changes in groundwater geochemistry accompanying stimulated iron and sulfate reduction and sulfide mineral precipitation. The magnitude of the phase response varied with measurement frequency (0.125 and 1 Hz) andwasdependent upon the dominant metabolic process. The spectral effect was corroborated using a biostimulated column experiment containing Rifle sediments and groundwater. Fluids and sediments recovered from regions exhibiting an anomalous phase response were enriched in Fe(II), dissolved sulfide, and cell-associated FeS nanoparticles. The accumulation of mineral precipitates and electroactive ions altered the ability of pore fluids to conduct electrical charge, accounting for the anomalous IP response and revealing the usefulness of multifrequency IP measurements for monitoring mineralogical and geochemical changes accompanying stimulated subsurface bioremediation.

  6. Geochemical evaluation of oils and source rocks from the Western Siberian basin, U. S. S. R

    SciTech Connect (OSTI)

    Peters, K.E.; Huizinga, B.J. (Chevron Overseas Petroleum, Inc., San Ramon, CA (United States)); Moldowan, J.M. (Chevron Oil Field Research Co., Richmond, CA (United States)); Kontorovich, A.E.; Stasova, O. (Siberian Scientific Research Institute for Geology, Geophysics and Mineral Resources, Novobsibirsk (Russian Federation)); Demaison, G.J.

    1991-03-01T23:59:59.000Z

    Although the Western Siberian basin is among the most prolific in the world, there has been disagreement among Soviet geoscientists on the origin of the petroleum within this basin. Screening geochemical analyses were used to select several oils and potential source rocks for a preliminary study using detailed biomarker and supporting geochemistry. Possible sources for this petroleum include rocks of Middle Jurassic, Upper Jurassic, and Lower Cretaceous age. Results indicate that most of the analyzed Western Siberian oils, occurring in reservoirs from Middle Jurassic to Late Cretaceous in age, are derived from the Upper Jurassic Bazhenov Formation. The locations of the samples in the study generally correspond to the distribution of the most effective oil-generative parts of the Bazhenov Formation. Analyses show that the Bazhenov rock samples contain abundant marine algal and bacterial organic matter, preserved under anoxic depositional conditions. Biomarkers show that thermal maturities of the samples range from the early to late oil-generative window and that some are biodegraded. For example, the Salym No. 114 oil, which flowed directly from the Bazhenov Formation, shows a maturity equivalent to the late oil window. The Van-Egan no. 110 oil shows maturity equivalent to the early oil window and is biodegraded. This oil shows preferential microbial conversion of lower homologs of the 17{alpha}, 21{beta}(H)-hopanes to 25-nor-17{alpha}(H)-hopanes.

  7. Integrated geochemical and paleoecological approach to petroleum source rock evaluation, Lower Niobrara Formation (Cretaceous), Lyons, Colorado

    SciTech Connect (OSTI)

    Barlow, L.K.

    1986-10-01T23:59:59.000Z

    A detailed study of paleoecological, geochemical, and stable isotopic properties of the lower Niobrara Formation (upper Turonian to lower Coniacian) was undertaken in order to evaluate petroleum source rock potential and to gain an understanding of the processes affecting variation in organic carbon content. The highest organic carbon contents in the lower Niobrara Formation occur in the lower shale unit of the Smoky Hill Shale Member. Trends in extent of bioturbation, organic carbon contents, and oxygen isotopic ratios of carbonates suggest that paleoclimatic factors influenced bottom water environments during deposition of this unit. A shift toward a more negative oxygen isotopic ratio in the lower shale unit is interpreted to be a result of decreased surface water salinity due to increased fresh water input and possibly to climatic warming. Resultant stratification of the water column limited benthic oxygenation thereby limiting benthic activity, enhancing the preservation of marine organic matter, and increasing source rock potential for petroleum. Data from underlying and overlying units in the lower Niobrara Formation suggest more normal marine conditions with well-oxygenated bottom waters, normal levels of bioturbation, and relatively low organic carbon contents. Pyrolysis data are interpreted to reflect a principally marine source of organic matter with substantial alteration due to bioturbation and thermal evolution. Elevated thermal maturity of the sections at Lyons is inferred to be a local feature caused by local heating associated with fluid movement along fault zones or with emplacement of tertiary sills.

  8. Geochemical studies of crude oil generation, migration, and destruction in Mississippi salt basin

    SciTech Connect (OSTI)

    Sassen, R.; Moore, C.H.; Nunn, J.A.; Meendsen, F.C.; Heydari, E.

    1987-09-01T23:59:59.000Z

    The main source for crude oil in the Mississippi salt basin is the laminated lime mudstone facies of the lower Smackover. Crude oil generation and migration commenced at a level of thermal maturity equivalent to about 0.55% vitrinite reflectance. Short-range lateral migration of crude oil was focused on upper Smackover and Norphlet reservoirs, but vertical migration also charged some overlying Cotton Valley, Rodessa, lower Tuscaloosa, and Eutaw reservoirs. Following migration from the lower Smackover, thermal maturity history of reservoir rocks controls the preservation of crude oil, gas condensate, and methane. Slow thermal cracking of crude oil occurred in deep upper Smackover reservoirs, resulting in formation of gas condensate and precipitation of solid bitumen. The maximum thermal maturity for preservation of condensate is equivalent to about 1.3% vitrinite reflectance. Only methane, pyrobitumen, and nonhydrocarbon gases, including hydrogen sulfide, persist at higher levels of thermal maturity. Early destruction of methane in deep upper Smackover reservoirs near the Wiggins arch is driven by thermochemical sulfate reduction. Lesser availability of sulfate in Norphlet reservoirs could account for methane preservation at higher levels of thermal maturity. One basic geochemical strategy for further exploration of the Mississippi salt basin is to focus exploration effort on traps with reservoirs in the thermal maturity window for hydrocarbon preservation. Another strategy is to avoid drilling traps with overmature reservoir rocks.

  9. Reactive Blast Waves from Composite Charges

    SciTech Connect (OSTI)

    Kuhl, A L; Bell, J B; Beckner, V E

    2009-10-16T23:59:59.000Z

    Investigated here is the performance of composite explosives - measured in terms of the blast wave they drive into the surrounding environment. The composite charge configuration studied here was a spherical booster (1/3 charge mass), surrounded by aluminum (Al) powder (2/3 charge mass) at an initial density of {rho}{sub 0} = 0.604 g/cc. The Al powder acts as a fuel but does not detonate - thereby providing an extreme example of a 'non-ideal' explosive (where 2/3 of the charge does not detonate). Detonation of the booster charge creates a blast wave that disperses the Al powder and ignites the ensuing Al-air mixture - thereby forming a two-phase combustion cloud embedded in the explosion. Afterburning of the booster detonation products with air also enhances and promotes the Al-air combustion process. Pressure waves from such reactive blast waves have been measured in bomb calorimeter experiments. Here we describe numerical simulations of those experiments. A Heterogeneous Continuum Model was used to model the dispersion and combustion of the Al particle cloud. It combines the gasdynamic conservation laws for the gas phase with a dilute continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models of Khasainov. It incorporates a combustion model based on mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Adaptive Mesh Refinement (AMR) was used to capture the energy-bearing scales of the turbulent flow on the computational grid, and to track/resolve reaction zones. Numerical simulations of the explosion fields from 1.5-g and 10-kg composite charges were performed. Computed pressure histories (red curve) are compared with measured waveforms (black curves) in Fig. 1. Comparison of these results with a waveform for a non-combustion case in nitrogen (blue curve) demonstrates that a reactive blast wave was formed. Cross-sectional views of the temperature field at various times are presented in Fig. 2, which shows that the flow is turbulent. Initially, combustion occurs at the fuel-air interface, and the energy release rate is controlled by the rate of turbulent mixing. Eventually, oxidizer becomes distributed throughout the cloud via ballistic mixing of the particles with air; energy release then occurs in a distributed combustion mode, and Al particle kinetics controls the energy release rate. Details of the Heterogeneous Continuum Model and results of the numerical simulations of composite charge explosions will be described in the paper.

  10. automatic reactive power: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a radio signal as soon Ning, Peng 62 Active and Reactive Power Control of a DFIG for Variable Speed Wind Energy Conversion using a New Controller CiteSeer Summary: This paper...

  11. Local Control of Reactive Power by Distributed Photovoltaic Generators

    E-Print Network [OSTI]

    Turitsyn, Konstantin S; Backhaus, Scott; Chertkov, Misha

    2010-01-01T23:59:59.000Z

    High penetration levels of distributed photovoltaic (PV) generation on an electrical distribution circuit may severely degrade power quality due to voltage sags and swells caused by rapidly varying PV generation during cloud transients coupled with the slow response of existing utility compensation and regulation equipment. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We suggest a local control scheme that dispatches reactive power from each PV inverter based on local instantaneous measurements of the real and reactive components of the consumed power and the re...

  12. Reactive DC magnetron sputtering of ultrathin superconducting niobium nitride films

    E-Print Network [OSTI]

    Dane, Andrew E. (Andrew Edward)

    2015-01-01T23:59:59.000Z

    DC reactive magnetron sputtering was used to deposit few-nanometer-thick films of niobium nitride for fabrication of superconducting devices. Over 1000 samples were deposited on a variety of substrates, under various chamber ...

  13. Evaluation of Methods to Predict Reactivity of Gold Nanoparticles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    relationship to the concept of frontier molecular orbital theory. The d-band theory of Hammer and Nørskov is perhaps the most widely used predictor of reactivity on metallic...

  14. Pre-plated reactive diffusion-bonded battery electrode plaques

    DOE Patents [OSTI]

    Maskalick, Nicholas J. (Pittsburgh, PA)

    1984-01-01T23:59:59.000Z

    A high strength, metallic fiber battery plaque is made using reactive diffusion bonding techniques, where a substantial amount of the fibers are bonded together by an iron-nickel alloy.

  15. Reactive oxygen species: a breath of life or death?

    E-Print Network [OSTI]

    Fruehauf, John P; Meyskens, Frank L Jr

    2007-01-01T23:59:59.000Z

    AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

  16. Dynamic Reactive Power Control of Isolated Power Systems

    E-Print Network [OSTI]

    Falahi, Milad

    2012-10-03T23:59:59.000Z

    This dissertation presents dynamic reactive power control of isolated power systems. Isolated systems include MicroGrids in islanded mode, shipboard power systems operating offshore, or any other power system operating in islanded mode intentionally...

  17. Learning Structured Reactive Navigation Plans from Executing MDP Navigation Policies

    E-Print Network [OSTI]

    Cremers, Daniel

    Learning Structured Reactive Navigation Plans from Executing MDP Navigation Policies Michael Beetz, beetz,belker@cs.uni-bonn.de Abstract. Autonomous robots, such as robot office couriers, need navigation

  18. Conversion of carboxylate salts to carboxylic acids via reactive distillation 

    E-Print Network [OSTI]

    Williamson, Shelly Ann

    2000-01-01T23:59:59.000Z

    , municipal solid wastes, sewage sludge, and industrial biosludge. Using a proprietary technology owned by Texas A&M University the wastes are first treated with lime to enhance reactivity. Then they are converted to calcium carboxylate salts using a mixed...

  19. Evolution of Memory in Reactive Artificial Neural Networks

    E-Print Network [OSTI]

    Chung, Ji Ryang

    2012-07-16T23:59:59.000Z

    in the context of evolution: how reactive agents could have evolved into cognitive ones with internalized memory? This study strives to find an answer to the question by simulating neuroevolution on artificial neural networks, with the hypothesis...

  20. EBS Radionuclide Transport Abstraction

    SciTech Connect (OSTI)

    J. Prouty

    2006-07-14T23:59:59.000Z

    The purpose of this report is to develop and analyze the engineered barrier system (EBS) radionuclide transport abstraction model, consistent with Level I and Level II model validation, as identified in Technical Work Plan for: Near-Field Environment and Transport: Engineered Barrier System: Radionuclide Transport Abstraction Model Report Integration (BSC 2005 [DIRS 173617]). The EBS radionuclide transport abstraction (or EBS RT Abstraction) is the conceptual model used in the total system performance assessment (TSPA) to determine the rate of radionuclide releases from the EBS to the unsaturated zone (UZ). The EBS RT Abstraction conceptual model consists of two main components: a flow model and a transport model. Both models are developed mathematically from first principles in order to show explicitly what assumptions, simplifications, and approximations are incorporated into the models used in the TSPA. The flow model defines the pathways for water flow in the EBS and specifies how the flow rate is computed in each pathway. Input to this model includes the seepage flux into a drift. The seepage flux is potentially split by the drip shield, with some (or all) of the flux being diverted by the drip shield and some passing through breaches in the drip shield that might result from corrosion or seismic damage. The flux through drip shield breaches is potentially split by the waste package, with some (or all) of the flux being diverted by the waste package and some passing through waste package breaches that might result from corrosion or seismic damage. Neither the drip shield nor the waste package survives an igneous intrusion, so the flux splitting submodel is not used in the igneous scenario class. The flow model is validated in an independent model validation technical review. The drip shield and waste package flux splitting algorithms are developed and validated using experimental data. The transport model considers advective transport and diffusive transport from a breached waste package. Advective transport occurs when radionuclides that are dissolved or sorbed onto colloids (or both) are carried from the waste package by the portion of the seepage flux that passes through waste package breaches. Diffusive transport occurs as a result of a gradient in radionuclide concentration and may take place while advective transport is also occurring, as well as when no advective transport is occurring. Diffusive transport is addressed in detail because it is the sole means of transport when there is no flow through a waste package, which may dominate during the regulatory compliance period in the nominal and seismic scenarios. The advective transport rate, when it occurs, is generally greater than the diffusive transport rate. Colloid-facilitated advective and diffusive transport is also modeled and is presented in detail in Appendix B of this report.

  1. Application of the ''reactivity constraint approach'' to automatic reactor control

    SciTech Connect (OSTI)

    Bernard, J.A.; Henry, A.F.; Lanning, D.D.

    1988-02-01T23:59:59.000Z

    The ''reactivity constraint approach'' is described and demonstrated to be an effective and reliable means for the automatic control of power in nuclear reactors. This approach functions by restricting the effect of the delayed neutron populations to that which can be balanced by an induced change in the prompt population. This is done by limiting the net reactivity to the amount that can be offset by reversing the direction of motion of the automated control mechanism. The necessary reactivity constraints are obtained from the dynamic period equation, which gives the instantaneous reactor period as a function of the reactivity and the rate of change of reactivity. The derivation of this equation is described with emphasis on the recently obtained ''alternate'' formulation. Following a discussion of the behavior of each term of this alternate equation as a function of reactivity, its use in the design and operation of a nonlinear, closed-loop, digital controller for reactor power is in the design and operation of a nonlinear, closed-loop, digital controller for reactor power is described. Details of the initial experimental trials of the resulting controller are given.

  2. Geochemical information for sites contaminated with low-level radioactive wastes. III. Weldon Spring Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-02-01T23:59:59.000Z

    The Weldon Spring Storage Site (WSSS), which includes both the chemical site and the quarry, became radioactively contaminated as the result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the WSSS. This report describes the results of geochemical investigations carried out at Oak Ridge National Laboratory (ORNL) to support these activities and to help quantify various remedial action options. Soil and groundwater samples were characterized, and uranium and radium sorption ratios were measured in site soil/groundwater systems by batch contact methodology. Soil samples from various locations around the raffinate pits were found to contain major amounts of silica, along with illite as the primary clay constituent. Particle sizes of the five soil samples were variable (50% distribution point ranging from 12 to 81 ..mu..m); the surface areas varied from 13 to 62 m/sup 2//g. Elemental analysis of the samples showed them to be typical of sandy clay and silty clay soils. Groundwater samples included solution from Pit 3 and well water from Well D. Anion analyses showed significant concentrations of sulfate and nitrate (>350 and >7000 mg/L, respectively) in the solution from Pit 3. These anions were also present in the well water, but in lower concentrations. Uranium sorption ratios for four of the soil samples contacted with the solution from Pit 3 were moderate to high (approx. 300 to approx. 1000 mL/g). The fifth sample had a ratio of only 12 mL/g. Radium sorption ratios for the five samples were moderate to high (approx. 600 to approx. 1000 mL/g). These values indicate that soil at the WSSS may show favorable retardation of uranium and radium in the groundwater. 13 references, 13 figures, 10 tables.

  3. Geochemical evidence for the hydrology of a Tamarack-peat bog, Brimfield Township, Portage County, Ohio

    SciTech Connect (OSTI)

    Wilson, T.P.; Miller, L.A. (Kent State Univ., OH (United States). Dept. of Geology and Water Resources)

    1992-01-01T23:59:59.000Z

    Peat Bogs and wetlands represent unique environmental settings what are increasingly subjected to anthropogenic stresses involving inputs of water and chemicals. This study used geochemical and hydrologic monitoring to determine the inputs and fates of elements of the Kent-Brimfield bog located in Portage County, Ohio. Based on physical and chemical information collected over one year, a model is proposed here describing the hydrologic connection between a bog and shallow ground water surrounding the bog. The chemical composition of precipitation, soil water and ground water in the bog vicinity were monitored for one year. Field measurements included water levels, pH, Eh, alkalinity and temperature. Trace metal content of the peat, the pore waters, soil water and ground waters were determined by GFAA, ICP and LIC methods. This bog was found to function as part of a perched water table aquifer. Water in the upper 3 m of the bog is found to be chemically similar to precipitation, but modified by reactions involving dissolution of mineral matter and biologic processes. The chemistry of water deeper in the bog (> 3m) resembles shallow ground water surrounding the bog, modified by weathering of underlying geologic materials and sulfate reduction. This similarity, along with ground water elevations within and outside of the bog, supports that shallow ground water interacts with, and helps maintain water levels in the upper surface of the bog. From these results, a model is proposed for the seasonal variations in hydrologic processes operating in the wetland and surrounding basin, and describes how wetlands may change seasonally from being influent to effluent systems.

  4. Organic geochemical constraints on tectonic evolution of the North American Midcontinent rift

    SciTech Connect (OSTI)

    Hieshima, G.B. (Exxon Production Research Co., Houston, TX (United States)); Pratt, L.M. (Indiana Univ., Bloomington, IN (United States). Dept. of Geological Sciences)

    1992-01-01T23:59:59.000Z

    The approximately 1.1 Ga Nonesuch Formation, northern Wisconsin and Michigan, represents marine sedimentation in a failed continental rift that is part of the North American Midcontinent rift system. Indicators of thermal maturity based on solvent-extractable (bitumen) and insoluble (kerogen) organic matter suggest marginal to moderate levels of maturity with respect to zones of petroleum generation and preservation. Values of sterane 20S/(20S + 20R) ratio, hopane 22S/(22S + 22R) ratio, methylphenanthrene index, and temperature of maximum pyrolytic yield from Rock-Eval (Tmax) indicate maximum burial temperatures of around 80 C. Geologic constraints indicate maximum burial conditions for the Nonesuch of around 4 km for approximately 50 million years. Overlying sandstones buried the Nonesuch quickly. Assuming a surface temperature of around 20 C yields a geothermal gradient of 15 C/km, significantly lower than predicted based on heat flow in modern rifts. Unless burial histories are grossly inaccurate, geothermal gradients were depressed as a result of thermal insulation by non-radiogenic basalts and/or hydrologic circulation in underlying coarse-grained strata generated an anomalously low geothermal gradient. Hydrothermal circulation was a significant component of mineralization in the structurally complex White Pine deposit, lending credence to the hypothesis that hydrologic circulation caused regionally depressed geothermal gradients. In addition, regional heat flow may have been low as a result of the insulating effect of a thick accumulation of rift basalts represented by the Portage Lake Volcanics. Organic geochemical indicators of thermal alteration provide a framework for interpreting tectonic development of the North American Midcontinent rift system.

  5. Radioactive Material Transportation Practices

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2002-09-23T23:59:59.000Z

    Establishes standard transportation practices for Departmental programs to use in planning and executing offsite shipments of radioactive materials including radioactive waste. Does not cancel other directives.

  6. Alternative Fuel Transportation Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review: EPAct State and Alternative Fuel Provider Fleets "Alternative Fuel Transportation Program" Dana O'Hara, DOE Ted Sears, NREL Vehicle Technologies Program June 20,...

  7. Transportation and its Infrastructure

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Options for Liquid Biofuels Development in Ireland. SEI, 562006: Outlook for advanced biofuels. Energy Policy, 34(17),40 pp. IEA, 2004c: Biofuels for Transport: An International

  8. Transportation Energy Futures

    E-Print Network [OSTI]

    DeLuchi, Mark A.

    1989-01-01T23:59:59.000Z

    TRANSPORTATION ment of Oil Shale Technology. Washing- ton,interest and investments in oil shale, ethanol, coal liquidsbiomass materials, coal, oil shale, tar sands, natural gas,

  9. Sustainable Transportation (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-09-01T23:59:59.000Z

    This document highlights DOE's Office of Energy Efficiency and Renewable Energy's advancements in transportation technologies, alternative fuels, and fuel cell technologies.

  10. Application of Partial-Order Methods to Reactive Programs with Event Memorization

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    with event memorization. The reactive systems are specified with an asynchronous reactive language Electre, 3 (2001) 287-316" #12;2 Electre: an Asynchronous Reactive Language with Event Memorization 3 2 of a semantic model of an asyn- chronous reactive language: Electre [PRH92, CR95]. Indeed, this language

  11. 2006 TRANSPORTATION TOMORROW SURVEY JOINT PROGRAM IN TRANSPORTATION

    E-Print Network [OSTI]

    Toronto, University of

    2006 TRANSPORTATION TOMORROW SURVEY JOINT PROGRAM IN TRANSPORTATION UNIVERSITY OF TORONTO 2006 Transportation Tomorrow Survey Data Presentation #12;2006 TRANSPORTATION TOMORROW SURVEY JOINT PROGRAM IN TRANSPORTATION UNIVERSITY OF TORONTO City of Hamilton City of Kawartha Lakes City of Guelph City of Brantford

  12. Numerical Modeling of 90Sr and 137Cs Transport from a Spill in the B-Cell of the 324 Building, Hanford Site 300 Area

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Bacon, Diana H.; Freedman, Vicky L.; Lindberg, Michael J.; Clayton, Ray E.

    2012-03-19T23:59:59.000Z

    To characterize the extent of contamination under the 324 Building, a pit was excavated on the north side of the building in 2010 by Washington Closure Hanford LLC (WCH). Horizontal closed-end steel access pipes were installed under the foundation of the building from this pit and were used for measuring temperatures and exposure rates under the B-Cell. The deployed sensors measured elevated temperatures of up to 61 C (142 F) and exposure rates of up to 8,900 R/hr. WCH suspended deactivation of the facility because it recognized that building safety systems and additional characterization data might be needed for remediation of the contaminated material. The characterization work included additional field sampling, laboratory measurements, and numerical flow and transport modeling. Laboratory measurements of sediment physical, hydraulic, and geochemical properties were performed by Pacific Northwest National Laboratory (PNNL) and others. Geochemical modeling and subsurface flow and transport modeling also were performed by PNNL to evaluate the possible extent of contamination in the unsaturated sand and gravel sediments underlying the building. Historical records suggest that the concentrated 137Cs- and 90Sr-bearing liquid wastes that were spilled in B-Cell were likely from a glass-waste repository testing program associated with the Federal Republic of Germany (FRG). Incomplete estimates of the aqueous chemical composition (no anion data provided) of the FRG waste solutions were entered into a geochemical speciation model and were charge balanced with nitrate to estimate waste composition. Additional geochemical modeling was performed to evaluate reactions of the waste stream with the concrete foundation of the building prior to the stream entering the subsurface.

  13. http://tti.tamu.edu Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freight

    E-Print Network [OSTI]

    http://tti.tamu.edu Multi-modal Transportation > Highway Transportation > Trucking > Railroad transportation > Public transit > Rural transportation > Rural transit > Freight pipeline transportation >>> Transportation operat > Freight traffic > Commodities > Travel time > Travel demand > http

  14. Sampling designs for geochemical baseline studies in the Colorado oil shale region: a manual for practical application

    SciTech Connect (OSTI)

    Klusman, R. W.; Ringrose, C. D.; Candito, R. J.; Zuccaro, B.; Rutherford, D. W.; Dean, W. E.

    1980-06-01T23:59:59.000Z

    This manual presents a rationale for sampling designs, and results of geochemical baseline studies in the Colorado portion of the oil-shale region. The program consists of a systematic trace element study of soils, stream sediments, and plants carried out in a way to be conservative of human and financial resources and yield maximum information. Extension of this approach to other parameters, other locations, and to environmental baseline studies in general is a primary objective. A baseline for any geochemical parameter can be defined as the concentration of that parameter in a given medium such as soil, the range of its concentration, and the geographic scale of variability. In air quality studies, and to a lesser extent for plants, the temporal scale of variability must also be considered. In studies of soil, the temporal variablility does not become a factor until such time that a study is deemed necessary to evaluate whether or not there have been changes in baseline levels as a result of development. The manual is divided into five major parts. The first is a suggested sampling protocol which is presented in an outline form for guiding baseline studies in this area. The second section is background information on the physical features of the area of study, trace elements of significance occurring in oil shale, and the sample media used in these studies. The third section is concerned primarily with sampling design and its application to the geochemical studies of the oil shale region. The last sections, in the form of appendices, provide actual data and illustrate in a systematic manner, the calculations performed to obtain the various summary data. The last segment of the appendices is a more academic discussion of the geochemistry of trace elements and the parameters of importance influencing their behavior in natural systems.

  15. INLAND PORT TRANSPORTATION EVALUATION GUIDE

    E-Print Network [OSTI]

    Texas at Austin, University of

    INLAND PORT TRANSPORTATION EVALUATION GUIDE by Robert Harrison, Center for Transportation Research Transportation Institute, The Texas A&M University System; and Jolanda Prozzi, Center for Transportation Research, The University of Texas at Austin CENTER FOR TRANSPORTATION RESEARCH Bureau of Engineering Research

  16. MAESTRAEN TRANSPORTE ESPECIALIZACINEN

    E-Print Network [OSTI]

    Vásquez, Carlos

    investigaciones que permitan la comprensión de distintos componentes delsistema del transporte así como para Investigación de Operaciones y Redes de transporte Medidas y Administración del Tránsito Tecnologías de

  17. Packaging and Transportation Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2003-04-04T23:59:59.000Z

    To establish safety requirements for the proper packaging and transportation of Department of Energy (DOE)/National Nuclear Security Administration (NNSA) offsite shipments and onsite transfers of hazardous materials and for modal transport. Cancels DOE O 460.1A. Canceled by DOE O 460.1C.

  18. Packaging and Transportation Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-05-14T23:59:59.000Z

    The order establishes safety requirements for the proper packaging and transportation of DOE, including NNSA, offsite shipments and onsite transfers of radioactive and other hazardous materials and for modal transportation. Cancels DOE O 460.1B, 5-14-10

  19. Expert systems in transportation

    SciTech Connect (OSTI)

    O'Leary, K.P.

    1988-01-01T23:59:59.000Z

    The 5 papers in the report deal with the following areas: Knowledge representation and software selection for expert-systems design; Expert-system architecture for retaining-wall design; Development of expert-systems technology in the California Department of Transportation; Development of an expert system to assist in the interactive graphic transit system design process; Expert systems development for contingency transportation planing.

  20. GIS Regional Spatial Data from the Great Basin Center for Geothermal Energy: Geochemical, Geodesic, Geologic, Geophysical, Geothermal, and Groundwater Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Great Basin Center for Geothermal Energy, part of the University of Nevada, Reno, conducts research towards the establishment of geothermal energy as an economically viable energy source within the Great Basin. The Center specializes in collecting and synthesizing geologic, geochemical, geodetic, geophysical, and tectonic data, and using Geographic Information System (GIS) technology to view and analyze this data and to produce favorability maps of geothermal potential. The center also makes its collections of spatial data available for direct download to the public. Data are in Lambert Conformable Conic Projection.

  1. Improving Efficiency and Equity in Transportation Finance

    E-Print Network [OSTI]

    Watts, Michael

    2006-01-01T23:59:59.000Z

    Fueling Transportation Finance. ” Ian W. H. Parry andFueling Transportation Finance. ” Transportation ResearchFueling Transportation Finance: A Primer on the Gas Tax •

  2. Sandia Energy - Transportation Energy Systems Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Energy Systems Analysis Home Transportation Energy Predictive Simulation of Engines Transportation Energy Systems Analysis Transportation Energy Systems AnalysisTara...

  3. Geochemical Processes at the Carbon Steel/Bentonite Interface in Repository Conditions

    SciTech Connect (OSTI)

    Torres, Elena; Turrero, Maria Jesus; Martin, Pedro Luis [Division of Engineered and Geological Barriers, Ciemat, Avenida Complutense 22, Madrid, 28047 (Spain)

    2007-07-01T23:59:59.000Z

    The Deep Geological Repository (DGR) is currently the most accepted management option for the isolation of high level radioactive wastes. The DGR is based on a multi-barrier system, which will limit releases of mobile radionuclides to the biosphere. In the Spanish design of the repository the spent fuel is encapsulated in canisters of carbon steel. The space between the canister and the host geological formation will be filled with bentonite buffer clay. The effects of the reactions occurring in the canister/compacted bentonite interface should be understood for assessing the waste isolation. If canister failure due to corrosion occurs [1] the iron will be in contact with the bentonite affecting its properties, both in terms of the chemical evolution of the pore water and the properties of the bentonite. Iron precipitates can significantly change the properties of bentonite crucial for the migration of radionuclides such as porosity or sorption capacity. Ferrous ions can also pass through bentonite and precipitate as iron oxy-hydroxides that can form pseudocolloids with radionuclides and quickly migrate in the host rock without sorption. But, the major effect of corrosion products will probably be the change of pH and E{sub h} affecting the stability of the barrier and the release rate of radionuclides. There are a number of studies on the corrosion of metals that could be used as canister [2], also studies on the iron-bentonite interaction [3], but not as many studies are focused to the iron-compacted bentonite interaction [4,5] and the associated mineralogical, chemical and physicochemical transformations of the bentonite [6]. The experimental studies conducted by CIEMAT are focused on the iron canister corrosion products interaction with the bentonite system and are based on a series of short term and medium term experiments conceived at different scales, from conventional laboratory experiments and experiments in cylindrical cells, to those specifically designed 3D mock up experiments, the so called 'GAME (Geochemical Mock up experiments) scale'. The experiments proposed in the context of the NF-PRO project (which is focused on understanding physical and numerical modelling of the key processes in the Near-Field, and their coupling, for different host rocks and repository strategies) have two main objectives: the study of the corrosion products generated in the canister/bentonite interface at the repository conditions, and to determine how the corrosion affects the properties of the bentonite. This paper describes the first tests performed to reach the objectives proposed and presents the results on the analyses of the corrosion products from carbon steel in contact with bentonite for a period of six months and one year subjected to heating and hydration. (authors)

  4. Transportation activity analysis using smartphones

    E-Print Network [OSTI]

    Xiao, Yu

    Transportation activity surveys investigate when, where and how people travel in urban areas to provide information necessary for urban transportation planning. In Singapore, the Land Transport Authority (LTA) carries out ...

  5. Environmentally stable reactive alloy powders and method of making same

    DOE Patents [OSTI]

    Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

    1998-09-22T23:59:59.000Z

    Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

  6. Options for Control of Reactive Power by Distributed Photovoltaic Generators

    E-Print Network [OSTI]

    Sulc, Petr; Backhaus, Scott; Chertkov, Michael

    2010-01-01T23:59:59.000Z

    High penetration levels of distributed photovoltaic(PV) generation on an electrical distribution circuit present several challenges and opportunities for distribution utilities. Rapidly varying irradiance conditions may cause voltage sags and swells that cannot be compensated by slowly responding utility equipment resulting in a degradation of power quality. Although not permitted under current standards for interconnection of distributed generation, fast-reacting, VAR-capable PV inverters may provide the necessary reactive power injection or consumption to maintain voltage regulation under difficult transient conditions. As side benefit, the control of reactive power injection at each PV inverter provides an opportunity and a new tool for distribution utilities to optimize the performance of distribution circuits, e.g. by minimizing thermal losses. We discuss and compare via simulation various design options for control systems to manage the reactive power generated by these inverters. An important design de...

  7. Apparatus for making environmentally stable reactive alloy powders

    DOE Patents [OSTI]

    Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

    1996-12-31T23:59:59.000Z

    Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

  8. Transportation Economic Assistance Program (Wisconsin)

    Broader source: Energy.gov [DOE]

    The Transportation Economic Assistance Program provides state grants to private business and local governments to improve transportation to projects improving economic conditions and creating or...

  9. Transportation Resources | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Resources The following means of transportation are available for getting to Argonne. Airports Argonne is located within 25 miles of two major Chicago airports:...

  10. Sandia National Laboratories: Transportation Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E. Coli Bacteria Engineered to Eat Switchgrass and Make Transportation Fuels On December 7, 2011, in Energy, JBEI, News, Renewable Energy, Transportation Energy A milestone has...

  11. Sandia National Laboratories: Transportation Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    JBEI, News, News & Events, Partnership, Renewable Energy, Systems Analysis, Transportation Energy Biofuels hold great promise for the future of transportation energy, but...

  12. Subsurface Flow and Transport | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    subsurface related to contaminant transport, carbon cycling, enhanced oil recovery and carbon dioxide sequestration. See a complete list of Subsurface Flow and Transport...

  13. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    natural gas and liquefied petroleum gas have continued to make small contributions to transportation,transportation actions include electric power sector actions, eg coal to natural gas

  14. Superconnections and Parallel Transport

    E-Print Network [OSTI]

    Dumitrescu, Florin

    2007-01-01T23:59:59.000Z

    This note addresses the construction of a notion of parallel transport along superpaths arising from the concept of a superconnection on a vector bundle over a manifold $M$. A superpath in $M$ is, loosely speaking, a path in $M$ together with an odd vector field in $M$ along the path. We also develop a notion of parallel transport associated with a connection (a.k.a. covariant derivative) on a vector bundle over a \\emph{supermanifold} which is a direct generalization of the classical notion of parallel transport for connections over manifolds.

  15. Development and Application of a Paleomagnetic/Geochemical Method for Constraining the Timing of Burial Diagenetic and Fluid

    SciTech Connect (OSTI)

    Elmore, Richard D.; Engel, Michael H.

    2005-03-10T23:59:59.000Z

    Studies of diagenesis caused by fluid migration or other events are commonly hindered by a lack of temporal control. Our results to date demonstrate that a paleomagnetic/geochemical approach can be used to date fluid migration as well as burial diagenetic events. Our principal working hypothesis is that burial diagenetic processes (e.g., maturation of organic-rich sediments and clay diagenesis) and the migration of fluids can trigger the authigenesis of magnetic mineral phases. The ages of these events can be constrained by comparing chemical remanent magnetizations (CRMs) to independently established Apparent Polar Wander Paths. While geochemical (e.g. stable isotope and organic analyses) and petrographic studies provide important clues for establishing these relationships, the ultimate test of this hypothesis requires the application of independent dating methods to verify the paleomagnetic ages. Towards this end, we have used K-Ar dating of illitization as an alternative method for constraining the ages of magnetic mineral phases in our field areas.

  16. Geochemical characteristics of the Bulgarmarse Granite of the Fall River Pluton in the Avalonian Superterrane of southeastern New England

    SciTech Connect (OSTI)

    Mancuso, C.I.; Puffer, J.H. (Rutgers, The State Univ. of New Jersey, Newark, NJ (United States). Dept. of Geological Sciences)

    1993-03-01T23:59:59.000Z

    The 600 m.y. Bulgarmarsh Granite of the Fall River Pluton crops out along the SE margin of the Pennsylvanian-age Narragansett Basin in the Dedham terrane of the New England Avalonian Superterrane. The Bulgarmarsh is a coarse-grained, quartz-rich, very leucooratic granite, in which mafic minerals, generally less than 5--8%, occur chiefly as chlorite, biotite and garnet disequilibrium intergrowths. Most of the granite is very slightly deformed, but there are many localized zones of deformation, both brittle and plastic, that vary in degree of intensity. The Bulgarmarsh intrudes Basin margin metavolcanics similar to those of Price Neck Formation that crop out within the Basin in Newport and on Gould Island. The Bulgarmarsh Granite has many of the mineralogical and geochemical characteristics of an A-type granite. Its geochemistry places it in the post-orogenic classification of Maniar and Piccoli (1989). New major and minor element geochemical data clearly discriminate between the Bulgarmarsh Granite and the adjacent calc-alkaline Metacom Granite Gneiss. Avalonian Orogeny, occupying a place in geologic history similar to that of the Newport Granite.

  17. Preliminary delineation of natural geochemical reactions, Snake River Plain aquifer system, Idaho National Engineering Laboratory and vicinity, Idaho

    SciTech Connect (OSTI)

    Knobel, L.L.; Bartholomay, R.C.; Orr, B.R.

    1997-05-01T23:59:59.000Z

    The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, is conducting a study to determine the natural geochemistry of the Snake River Plain aquifer system at the Idaho National Engineering Laboratory (INEL), Idaho. As part of this study, a group of geochemical reactions that partially control the natural chemistry of ground water at the INEL were identified. Mineralogy of the aquifer matrix was determined using X-ray diffraction and thin-section analysis and theoretical stabilities of the minerals were used to identify potential solid-phase reactants and products of the reactions. The reactants and products that have an important contribution to the natural geochemistry include labradorite, olivine, pyroxene, smectite, calcite, ferric oxyhydroxide, and several silica phases. To further identify the reactions, analyses of 22 representative water samples from sites tapping the Snake River Plain aquifer system were used to determine the thermodynamic condition of the ground water relative to the minerals in the framework of the aquifer system. Principal reactions modifying the natural geochemical system include congruent dissolution of olivine, diopside, amorphous silica, and anhydrite; incongruent dissolution of labradorite with calcium montmorillonite as a residual product; precipitation of calcite and ferric oxyhydroxide; and oxidation of ferrous iron to ferric iron. Cation exchange reactions retard the downward movement of heavy, multivalent waste constituents where infiltration ponds are used for waste disposal.

  18. Geologic, geochemical, and geographic controls on NORM in produced water from Texas oil, gas, and geothermal reservoirs. Final report

    SciTech Connect (OSTI)

    Fisher, R.

    1995-08-01T23:59:59.000Z

    Water from Texas oil, gas, and geothermal wells contains natural radioactivity that ranges from several hundred to several thousand Picocuries per liter (pCi/L). This natural radioactivity in produced fluids and the scale that forms in producing and processing equipment can lead to increased concerns for worker safety and additional costs for handling and disposing of water and scale. Naturally occurring radioactive materials (NORM) in oil and gas operations are mainly caused by concentrations of radium-226 ({sup 226}Ra) and radium-228 ({sup 228}Ra), daughter products of uranium-238 ({sup 238}U) and thorium-232 ({sup 232}Th), respectively, in barite scale. We examined (1) the geographic distribution of high NORM levels in oil-producing and gas-processing equipment, (2) geologic controls on uranium (U), thorium (Th), and radium (Ra) in sedimentary basins and reservoirs, (3) mineralogy of NORM scale, (4) chemical variability and potential to form barite scale in Texas formation waters, (5) Ra activity in Texas formation waters, and (6) geochemical controls on Ra isotopes in formation water and barite scale to explore natural controls on radioactivity. Our approach combined extensive compilations of published data, collection and analyses of new water samples and scale material, and geochemical modeling of scale Precipitation and Ra incorporation in barite.

  19. Dielectric covered hairpin probe for its application in reactive plasmas

    SciTech Connect (OSTI)

    Gogna, G. S.; Gaman, C.; Turner, M. M. [NCPST, School of Physical Sciences, Dublin City University, Dublin 9 (Ireland); Karkari, S. K. [Institute for Plasma Research Center, Bhat Gandhinagar, Gujarat 382428 (India)

    2012-07-23T23:59:59.000Z

    The hairpin probe is a well known technique for measuring local electron density in low temperature plasmas. In reactive plasmas, the probe characteristics are affected by surface sputtering, contamination, and secondary electron emission. At higher densities, the plasma absorbs the entire electromagnetic energy of hairpin and hence limits the density measurements. These issues can be resolved by covering the hairpin surface with a thin layer of dielectric. In this letter, the dielectric contribution to the probe characteristics is incorporated in a theory which is experimentally verified. The dielectric covering improves the performance of probe and also allows the hairpin tip to survive in reactive plasma where classical electrical probes are easily damaged.

  20. Plasma & reactive ion etching to prepare ohmic contacts

    DOE Patents [OSTI]

    Gessert, Timothy A. (Conifer, CO)

    2002-01-01T23:59:59.000Z

    A method of making a low-resistance electrical contact between a metal and a layer of p-type CdTe surface by plasma etching and reactive ion etching comprising: a) placing a CdS/CdTe layer into a chamber and evacuating said chamber; b) backfilling the chamber with Argon or a reactive gas to a pressure sufficient for plasma ignition; and c) generating plasma ignition by energizing a cathode which is connected to a power supply to enable the plasma to interact argon ions alone or in the presence of a radio-frequency DC self-bias voltage with the p-CdTe surface.

  1. The relative reactivity of formic esters with aromatic amines

    E-Print Network [OSTI]

    Markley, Max C.

    1922-01-01T23:59:59.000Z

    .MARKLEY I Vies* S ma y c . l k f c V i M t s RDQOSS 38M30 PREFACE. The purpose of this thesis was to determine the relative reactivity between aromatic amines and the esters of formic acid.It was proposed to first: deter­ mine the reactivity... be given Br .Ray Q,.Brewster , the director of this work, for his help and directions for carrying out this work, and to Br.Prank B.Bains for his kind assistance in many ways. 1.Broil,Journal fur Practische Chemie,1875,vol. 12,page 208. ( 2 ) TABLE...

  2. EBS Radionuclide Transport Abstraction

    SciTech Connect (OSTI)

    J.D. Schreiber

    2005-08-25T23:59:59.000Z

    The purpose of this report is to develop and analyze the engineered barrier system (EBS) radionuclide transport abstraction model, consistent with Level I and Level II model validation, as identified in ''Technical Work Plan for: Near-Field Environment and Transport: Engineered Barrier System: Radionuclide Transport Abstraction Model Report Integration'' (BSC 2005 [DIRS 173617]). The EBS radionuclide transport abstraction (or EBS RT Abstraction) is the conceptual model used in the total system performance assessment for the license application (TSPA-LA) to determine the rate of radionuclide releases from the EBS to the unsaturated zone (UZ). The EBS RT Abstraction conceptual model consists of two main components: a flow model and a transport model. Both models are developed mathematically from first principles in order to show explicitly what assumptions, simplifications, and approximations are incorporated into the models used in the TSPA-LA. The flow model defines the pathways for water flow in the EBS and specifies how the flow rate is computed in each pathway. Input to this model includes the seepage flux into a drift. The seepage flux is potentially split by the drip shield, with some (or all) of the flux being diverted by the drip shield and some passing through breaches in the drip shield that might result from corrosion or seismic damage. The flux through drip shield breaches is potentially split by the waste package, with some (or all) of the flux being diverted by the waste package and some passing through waste package breaches that might result from corrosion or seismic damage. Neither the drip shield nor the waste package survives an igneous intrusion, so the flux splitting submodel is not used in the igneous scenario class. The flow model is validated in an independent model validation technical review. The drip shield and waste package flux splitting algorithms are developed and validated using experimental data. The transport model considers advective transport and diffusive transport from a breached waste package. Advective transport occurs when radionuclides that are dissolved or sorbed onto colloids (or both) are carried from the waste package by the portion of the seepage flux that passes through waste package breaches. Diffusive transport occurs as a result of a gradient in radionuclide concentration and may take place while advective transport is also occurring, as well as when no advective transport is occurring. Diffusive transport is addressed in detail because it is the sole means of transport when there is no flow through a waste package, which may dominate during the regulatory compliance period in the nominal and seismic scenarios. The advective transport rate, when it occurs, is generally greater than the diffusive transport rate. Colloid-facilitated advective and diffusive transport is also modeled and is presented in detail in Appendix B of this report.

  3. Transportation 2035 Longview Metropolitan Transportation Plan

    E-Print Network [OSTI]

    Longview Metropolitan Planning Organization

    2009-11-12T23:59:59.000Z

    Owen, MPO Director Melissa Bechtold, Transportation Planner Nalora Moser, Planning Technician MPO TECHNICAL COMMITTEE Karen Owen, City of Longview Fred Marquez, TXDOT-Austin Dale Spitz, TXDOT-Tyler District Debbie Sadler, City of White... Oak Will Buskell, TXDOT-Longview Area Rea Donna Jones, TXDOT-Atlanta District Margie McAllister, TCEQ-Austin Randy Redmond, TXDOT-Tyler District John Paul Jones, Harrison County Keith Bonds, City of Longview Steve Juneau, TXDOT-Marshall...

  4. NREL: Transportation Research - Transportation Secure Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for Renewable Energy: Grid IntegrationReportTransmissionResearchNewsTransportation

  5. PBA Transportation Websites

    Broader source: Energy.gov [DOE]

    PBA Transportation Websites presented to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of systems analysis in DOE Hydrogen Program.

  6. Transportation and Stationary Power

    E-Print Network [OSTI]

    ) is small. Previous feedback from industry has indicated that existing transportation fuel providers (oil for multiple fuel cell applications, including material handling equipment, backup power, and light- or heavy

  7. ELECTROCHEMICAL POWER FOR TRANSPORTATION

    E-Print Network [OSTI]

    Cairns, Elton J.

    2012-01-01T23:59:59.000Z

    be generated from coal and nuclear energy in contrast to 7%in the use of coal and nuclear energy for transportation andparticularly for coal and nuclear energy utilization, would

  8. Atmospheric Transport of Radionuclides

    SciTech Connect (OSTI)

    Crawford, T.V.

    2003-03-03T23:59:59.000Z

    The purpose of atmospheric transport and diffusion calculations is to provide estimates of concentration and surface deposition from routine and accidental releases of pollutants to the atmosphere. This paper discusses this topic.

  9. Clean Transportation Internship Description

    E-Print Network [OSTI]

    Clean Transportation Internship Description The NC Solar Center at North Carolina State University to other ongoing projects by focusing on time-sensitive tasks. While the main thrust of this internship

  10. Alternative Fuel Transportation Program

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    federal register Monday May 17, 1999 Part II Department of Energy Office of Energy Efficiency and Renewable Energy 10 CFR Part 490 Alternative Fuel Transportation Program; P-series...

  11. Accident resistant transport container

    DOE Patents [OSTI]

    Andersen, John A. (Albuquerque, NM); Cole, James K. (Albuquerque, NM)

    1980-01-01T23:59:59.000Z

    The invention relates to a container for the safe air transport of plutonium having several intermediate wood layers and a load spreader intermediate an inner container and an outer shell for mitigation of shock during a hypothetical accident.

  12. B. TRANSPORTATION, CIRCULATION AND PARKING B. TRANSPORTATION, CIRCULATION AND

    E-Print Network [OSTI]

    Mullins, Dyche

    B. TRANSPORTATION, CIRCULATION AND PARKING 231 B. TRANSPORTATION, CIRCULATION AND PARKING on transportation and connectivity issues common to UCSF as a whole. Please refer to Chapter 5, Plans for Existing characteristics specific to each individual UCSF site. DETERMINANTS OF THE 1996 LRDP The transportation

  13. Metropolitan Transportation Plan 2035

    E-Print Network [OSTI]

    Tyler Area Metropolitan Planning Organization

    2009-12-04T23:59:59.000Z

    Adopted by the Tyler Area MPO Policy Committee December 4, 2009 METROPOLITAN TRANSPORTATION PLAN 2035 Revised April 22, 2010 Adopted by the Tyler Area MPO Policy Committee December 4, 2009 Amended/Revised April 22, 2010 Prepared by: Bucher..., Willis, and Ratliff Corporation 1828 East Southeast Loop 323, Suite 202 Tyler, Texas 75701 903.581.7844 This Document Serves as an Update to the Tyler Area Metropolitan Transportation Plan 2030. Portions of that Document were Unchanged and Appear...

  14. Thermoelectric transport in superlattices

    SciTech Connect (OSTI)

    Reinecke, T.L.; Broido, D.A.

    1997-07-01T23:59:59.000Z

    The thermoelectric transport properties of superlattices have been studied using an exact solution of the Boltzmann equation. The role of heat transport along the barrier layers, of carrier tunneling through the barriers, of valley degeneracy and of the well width and energy dependences of the carrier-phonon scattering rates on the thermoelectric figure of merit are given. Calculations are given for Bi{sub 2}Te{sub 3} and for PbTe, and the results of recent experiments are discussed.

  15. Interactive Transportable Architecture

    E-Print Network [OSTI]

    Oliver Irschitz; Priam Givord; Newyork Exit Newyork; Flavia Sparacino

    Transportable architecture which embeds the means to communicate with real or imaginary digital information spaces in a natural fashion offers unprecedented opportunities to make multimedia experiences available to the public almost everywhere. This installation demonstrates an example of interactive transportable architecture which incorporates unencumebered real-time body tracking and gesture recognition to explore a 3-D cityscape and a brain-like web-based information space.

  16. Campus Village Transportation

    E-Print Network [OSTI]

    Hernandez, Emmanuel

    2014-11-19T23:59:59.000Z

    Emmanuel Hernandez THE CAMPUS V ILLAGE : TRANSPORTATION Objective The Campus Village is a new community being constructed in northwest Lawrence with a intergenerational focus in mind. The site will be equipped with housing for students, athletes..., retirement community members, and families. The overall objective of this study was to evaluate the city’s current transportation network and make recommendations on that network to better accommodate the needs of the new property. Specifically, the goal...

  17. Regional Transportation Coordination Study

    E-Print Network [OSTI]

    Golden Crescent Regional Planning Commission

    Committee for this study. ? Develop a coordination public transportation plan ? Identify resources required to develop the plan ? Provide policy guidance to lead the planning and coordination effort Golden Crescent Regional Transit 1... of Texas. This resource will be relied upon for further development of the Intermodal Transportation Terminal. ? FTA Section 5309 (Bus) Discretionary Support ? To assist in meeting the GCRPC?s capital replacement needs. This resource...

  18. Non-Energetic Reactive Armor (NERA) and Semi-Energetic Reactive Armor (SERA) FY13 Final Report

    SciTech Connect (OSTI)

    Ben Langhorst; Nikki Rasmussen; Andrew Robinson

    2013-08-01T23:59:59.000Z

    INL researchers have proposed prototypes for future lightweight armor systems that reside in a technology gap between explosive reactive armor and passive armor. The targets were designed to react under impact and throw a steel front plate into the path of the projectile, forcing the projectile to engage more of the front plate during its penetration process. These prototypes are intended to exhibit the enhanced efficiency of explosive reactive armor without the collateral damage often associated with explosive reactive armor. One of the prototype systems, Semi Energetic Reactive Armor (SERA), functions similarly to explosive reactive armor, but features a reactive material that reacts much slower than explosive reactive armor. Two different SERA test groups were built and featuring different ratios of aluminum Teflon(copyright) powders pressed into 0.5 in. thick energetic tiles and sandwiched between 0.25 in. thick RHA plates. The other prototype system, Non Energetic Reactive Armor (NERA), utilizes the strain energy in compressed rubber to launch a front flyer plate into the path of an incoming projectile. It is comprised of a 1 in. thick rubber layer sandwiched between two 0.25 in. thick RHA plates with bolt holes around the perimeter. Bolts are inserted through the entire target and tightened to compress the rubber sheet to significant strain levels (approximately 40%). A fourth group of targets was tested as a control group. It featured a 0.5 in. thick rubber sheet sandwiched between two 0.25 in. thick RHA plates, similar to the NERA test articles, but the rubber is uncompressed. The four test groups (uncompressed rubber, compressed rubber, 70/30 Al/PTFE, 50/50 Al/PTFE) were each fabricated with three identical test articles in each group. All twelve targets were subjected to ballistic testing at the National Security Test Range on July 17, 2013. They were tested with 0.5 in. diameter steel rods shot at a consistent velocity at each target. In order to characterize the energetic materials, break wires were embedded in the targets and burn velocities were measured. The residual mass method was used to compare the target performance of each group and final performance data is presented below.

  19. Effect of Number of Fractionating Trays on Reactive Distillation Performance

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

  20. Abduction with Negation as Failure for Active and Reactive Rules

    E-Print Network [OSTI]

    Toni, Francesca

    Abduction with Negation as Failure for Active and Reactive Rules Fariba Sadri and Francesca Toni suggested abductive logic programming as a suitable formalism to represent active databases and intelligent agents. In particular, abducibles in abductive logic programs can be used to repre- sent actions