National Library of Energy BETA

Sample records for raw steel production

  1. Continuous steel production and apparatus

    DOE Patents [OSTI]

    Peaslee, Kent D.; Peter, Jorg J.; Robertson, David G. C.; Thomas, Brian G.; Zhang, Lifeng

    2009-11-17

    A process for continuous refining of steel via multiple distinct reaction vessels for melting, oxidation, reduction, and refining for delivery of steel continuously to, for example, a tundish of a continuous caster system, and associated apparatus.

  2. Largest Producer of Steel Products in the United States Achieves...

    Office of Environmental Management (EM)

    Largest Producer of Steel Products in the United States Achieves Significant Energy Savings at its Minntac Plant Largest Producer of Steel Products in the United States Achieves ...

  3. Residuals in steel products -- Impacts on properties and measures to minimize them

    SciTech Connect (OSTI)

    Emi, Toshihiko; Wijk, O.

    1996-12-31

    The effect of major residual elements on the properties of steel products is summarized. Measures to minimize these elements are discussed including the pretreatment of raw materials, innovative refining processes and environmental issues. This paper addresses (1) scrap situation, (2) upper limit of residual concentrations acceptable for processing and product quality, (3) possible means to reduce the residuals, and (4) consideration on the practicable measures to solve the residuals problem in a systematic way. 52 refs.

  4. Integrating Steel Production with Mineral Carbon Sequestration

    SciTech Connect (OSTI)

    Klaus Lackner; Paul Doby; Tuncel Yegulalp; Samuel Krevor; Christopher Graves

    2008-05-01

    The objectives of the project were (i) to develop a combination iron oxide production and carbon sequestration plant that will use serpentine ores as the source of iron and the extraction tailings as the storage element for CO2 disposal, (ii) the identification of locations within the US where this process may be implemented and (iii) to create a standardized process to characterize the serpentine deposits in terms of carbon disposal capacity and iron and steel production capacity. The first objective was not accomplished. The research failed to identify a technique to accelerate direct aqueous mineral carbonation, the limiting step in the integration of steel production and carbon sequestration. Objective (ii) was accomplished. It was found that the sequestration potential of the ultramafic resource surfaces in the US and Puerto Rico is approximately 4,647 Gt of CO2 or over 500 years of current US production of CO2. Lastly, a computer model was developed to investigate the impact of various system parameters (recoveries and efficiencies and capacities of different system components) and serpentinite quality as well as incorporation of CO2 from sources outside the steel industry.

  5. High productivity injection practices at Rouge Steel

    SciTech Connect (OSTI)

    Barker, D.H.; Hegler, G.L.; Falls, C.E.

    1995-12-01

    Rouge Steel Company, located in Dearborn, Michigan, operates two blast furnaces. The smaller of the pair, ``B`` Furnace, has a hearth diameter of 20 feet and 12 tuyeres. It has averaged 2,290 NTHM (net ton of hot metal) per day of 8.2 NTHM per 100 cubic feet of working volume. ``C`` Furnace has a hearth diameter of 29 feet and 20 tuyeres. Both of these furnaces are single tap hole furnaces. Prior to its reline in 1991, ``C`` Furnace was producing at a rate of 3,300 NTHM/day or about 6.25 NTHM/100 cfwv. In November, 1994 it averaged 5,106 NTHM/day or 9.6 NTHM/100 cfwv. This paper discusses how the current production rates were achieved. Also, the areas that needed to be addressed as production increased will be described. These areas include casthouse arrangement and workload, hot metal ladle capacity, slag pot capacity and charging capability. Coupled with the high blast temperature capability, the furnace was provided with a new natural gas injection system that injected the gas through the blowpipes and a natural gas injection system to enrich the stove gas. Following the furnace reline, natural gas has been used in three ways: tuyere level control; combination injection; and stove gas enrichment. Coke consumption rate has also decreased per NTHM.

  6. Steel catenary risers for semisubmersible based floating production systems

    SciTech Connect (OSTI)

    Hays, P.R.

    1996-12-31

    The DeepStar production riser committee has investigated the feasibility of using steel catenary risers (SCRs) in water depths of 3,000--6,000 ft. Using Sonat`s George Richardson as the base semisubmersible, DeepStar has examined both extreme event response and fatigue life of an SCR made of pipe sections welded end-to-end. Concepts using alternative materials were investigated. This included steel, steel with titanium and titanium catenary risers. The pros and cons of frequency domain versus time domain analysis were investigated with a commercially available analysis package. A second study outlined a definitive analysis procedure which optimized the analysis time requirements. Analyses showed that steel catenary risers are feasible for semisubmersible based floating production systems. For the DeepStar Gulf of Mexico design criteria, alternative materials are not required. The greatest fatigue damage occurs in the touchdown region of the riser. Mild sea states contribute most to fatigue damage near riser touchdown. Wave drift and wind forces provide a significant contribution to touchdown area fatigue damage. Estimated fatigue lives are unacceptable. Although the rotations of the upper end of the riser are large relative to an SCR attached to a TLP, the rotation required can probably be accommodated with existing technology. For the case of product export, steel catenary risers provide very cost effective and readily installable deep water riser alternatives.

  7. Largest Producer of Steel Products in the United States Achieves...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Iron on the Mesabi Iron Range in northern Minnesota, the U. S. Steel Minntac plant ... Significant Energy Savings at its Minntac Plant U. S. Steel's Taconite Pellet ...

  8. RawSolar | Open Energy Information

    Open Energy Info (EERE)

    RawSolar Jump to: navigation, search Name: RawSolar Place: Berkeley, California Sector: Solar Product: California-based startup aiming to commercialise concentrating solar thermal...

  9. Full PWA Report: An Assessment of Energy, Waste, and Productivity Improvements for North Star Steel Iowa

    SciTech Connect (OSTI)

    2010-06-25

    North Star Steel's Wilton, Iowa plant (NSSI) was awarded a subcontract through a competitive process to use Department of Energy/OIT funding to examine potential processes and technologies that could save energy, reduce waste, and increase productivity.

  10. India's iron and steel industry: Productivity, energy efficiency and carbon emissions

    SciTech Connect (OSTI)

    Schumacher, Katja; Sathaye, Jayant

    1998-10-01

    Historical estimates of productivity growth in India's iron and steel sector vary from indicating an improvement to a decline in the sector's productivity. The variance may be traced to the time period of study, source of data for analysis, and type of indices and econometric specifications used for reporting productivity growth. The authors derive both growth accounting and econometric estimates of productivity growth for this sector. Their results show that over the observed period from 1973--74 to 1993--94 productivity declined by 1.71{percent} as indicated by the Translog index. Calculations of the Kendrick and Solow indices support this finding. Using a translog specification the econometric analysis reveals that technical progress in India's iron and steel sector has been biased towards the use of energy and material, while it has been capital and labor saving. The decline in productivity was caused largely by the protective policy regarding price and distribution of iron and steel as well as by large inefficiencies in public sector integrated steel plants. Will these trends continue into the future, particularly where energy use is concerned? Most likely they will not. The authors examine the current changes in structure and energy efficiency undergoing in the sector. Their analysis shows that with the liberalization of the iron and steel sector, the industry is rapidly moving towards world-best technology, which will result in fewer carbon emissions and more efficient energy use in existing and future plants.

  11. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    SciTech Connect (OSTI)

    Hasanbeigi, Ali; Price, Lynn; Aden, Nathaniel; Chunxia, Zhang; Xiuping, Li; Fangqin, Shangguan

    2011-06-15

    Production of iron and steel is an energy-intensive manufacturing process. In 2006, the iron and steel industry accounted for 13.6% and 1.4% of primary energy consumption in China and the U.S., respectively (U.S. DOE/EIA, 2010a; Zhang et al., 2010). The energy efficiency of steel production has a direct impact on overall energy consumption and related carbon dioxide (CO2) emissions. The goal of this study is to develop a methodology for making an accurate comparison of the energy intensity (energy use per unit of steel produced) of steel production. The methodology is applied to the steel industry in China and the U.S. The methodology addresses issues related to boundary definitions, conversion factors, and indicators in order to develop a common framework for comparing steel industry energy use. This study uses a bottom-up, physical-based method to compare the energy intensity of China and U.S. crude steel production in 2006. This year was chosen in order to maximize the availability of comparable steel-sector data. However, data published in China and the U.S. are not always consistent in terms of analytical scope, conversion factors, and information on adoption of energy-saving technologies. This study is primarily based on published annual data from the China Iron & Steel Association and National Bureau of Statistics in China and the Energy Information Agency in the U.S. This report found that the energy intensity of steel production is lower in the United States than China primarily due to structural differences in the steel industry in these two countries. In order to understand the differences in energy intensity of steel production in both countries, this report identified key determinants of sector energy use in both countries. Five determinants analyzed in this report include: share of electric arc furnaces in total steel production, sector penetration of energy-efficiency technologies, scale of production equipment, fuel shares in the iron and steel

  12. Spatial distribution of crystalline corrosion products formed during corrosion of stainless steel in concrete

    SciTech Connect (OSTI)

    Serdar, Marijana; Meral, Cagla; Kunz, Martin; Bjegovic, Dubravka; Wenk, Hans-Rudolf; Monteiro, Paulo J.M.

    2015-05-15

    The mineralogy and spatial distribution of nano-crystalline corrosion products that form in the steel/concrete interface were characterized using synchrotron X-ray micro-diffraction (μ-XRD). Two types of low-nickel high-chromium reinforcing steels embedded into mortar and exposed to NaCl solution were investigated. Corrosion in the samples was confirmed by electrochemical impedance spectroscopy (EIS). μ-XRD revealed that goethite (α-FeOOH) and akaganeite (β-FeOOH) are the main iron oxide–hydroxides formed during the chloride-induced corrosion of stainless steel in concrete. Goethite is formed closer to the surface of the steel due to the presence of chromium in the steel, while akaganeite is formed further away from the surface due to the presence of chloride ions. Detailed microstructural analysis is shown and discussed on one sample of each type of steel. - Highlights: • Synchrotron micro-diffraction used to map the distribution of crystalline phases. • Goethite and akaganeite are the main corrosion products during chloride induced corrosion in mortar. • Layers of goethite and akaganeite are negatively correlated. • EDS showed Cr present in corrosion products identified by SEM.

  13. Energy use and carbon dioxide emissions from steel production in China

    SciTech Connect (OSTI)

    Price, Lynn; Sinton, Jonathan; Worrell, Ernst; Phylipsen, Dian; Xiulian, Hu; Ji, Li

    2004-01-01

    In 1996, China manufactured just over 100 Mt of steel and became the world s largest steel producer. Official Chinese energy consumption statistics for the steel industry include activities not directly associated with the production of steel, double-count some coal-based energy consumption, and do not cover the entire Chinese steelmaking industry. In this paper, we make adjustments to the reported statistical data in order to provide energy use values for steel production in China that are comparable to statistics used internationally. We find that for 1996, official statistics need to be reduced by 1365 PJ to account for non-steel production activities and double-counting. Official statistics also need to be increased by 415 PJ in order to include steelmaking energy use of small plants not included in official statistics. This leads to an overall reduction of 950 PJ for steelmaking in China in 1996. Thus, the official final energy use value of 4018 PJ drops to 3067 PJ. In primary energy terms, the official primary energy use value of 4555 PJ is reduced to 3582 PJ when these adjustments are made.

  14. Process for making a martensitic steel alloy fuel cladding product

    DOE Patents [OSTI]

    Johnson, Gerald D.; Lobsinger, Ralph J.; Hamilton, Margaret L.; Gelles, David S.

    1990-01-01

    This is a very narrowly defined martensitic steel alloy fuel cladding material for liquid metal cooled reactors, and a process for making such a martensitic steel alloy material. The alloy contains about 10.6 wt. % chromium, about 1.5 wt. % molybdenum, about 0.85 wt. % manganese, about 0.2 wt. % niobium, about 0.37 wt. % silicon, about 0.2 wt. % carbon, about 0.2 wt. % vanadium, 0.05 maximum wt. % nickel, about 0.015 wt. % nitrogen, about 0.015 wt. % sulfur, about 0.05 wt. % copper, about 0.007 wt. % boron, about 0.007 wt. % phosphorous, and with the remainder being essentially iron. The process utilizes preparing such an alloy and homogenizing said alloy at about 1000.degree. C. for 16 hours; annealing said homogenized alloy at 1150.degree. C. for 15 minutes; and tempering said annealed alloy at 700.degree. C. for 2 hours. The material exhibits good high temperature strength (especially long stress rupture life) at elevated temperature (500.degree.-760.degree. C.).

  15. Bioaccumulation and food chain transfer of corrosion products from radioactive stainless steel

    SciTech Connect (OSTI)

    Young, J.S.

    1986-07-01

    Two sets of experiments were conducted to determine if corrosion products from radioactive Type 347 stainless steel could be biologically transferred from sediment through a marine food chain, and whether corrosion products dissolved in seawater could be bioaccumulated and then eliminated. Corrosion products containing /sup 60/Co and /sup 63/Ni from the radioactive stainless steel were introduced into marine sediments. Infaunal polychaete worms exposed to these sediments bioaccumulated the radionuclides. The feeding of these worms to shrimp and fish resulted in a trophic transfer of the radioactive products across a one-step food chain. The magnitude of the transfers are described in terms of transfer factors. Dissolved corrosion products as measured by the radionuclides were also bioaccumulated by shrimp and fish concentrating more than fish. Concentration factors were calculated.

  16. Production of high quality steels using the scrap/electric arc furnace route

    SciTech Connect (OSTI)

    Houpert, C.; Lanteri, V.; Jolivet, J.M.; Guttmann, M.; Birat, J.P.; Jallon, M.; Confente, M.

    1996-12-31

    Europe, after North America, is increasing the share of electric arc furnace steelmaking at the expense of integrated steel production and the trend appears to be long term. The driving forces for this change are strong: availability of scrap, social pressure to recycle materials and economic benefits to be reaped from the small structure associated with this short and slim production route. The increasing use of scrap does raise some problems however, in terms of the tramp element build up within the scrap deposit over time. Scrap pretreatment, which aims at separating steel from non-ferrous material during preparation, is thus attracting a lot of attention. The purpose of the present work was to investigate quantitatively the potential problems related to increased levels in tramp elements, with two objectives: identify, on a case by case basis, the currently existing practical limits and devise countermeasures to further extend these limits by better controlling process parameters for instance.

  17. Steelmaker Matches Recovery Act Funds to Save Energy & Reduce Steel Production Costs

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steelmaker Matches Recovery Act Funds to Save Energy & Reduce Steel Production Costs ArcelorMittal Indiana Harbor Energy Recovery & Reuse 504 Boiler constructed and installed with DOE Recovery Act Funding The Advanced Manufacturing Office (AMO) at the U.S. Department of Energy provided $31.6 million in American Recovery & Reinvestment Act (ARRA) funding to construct and install an energy-efficient boiler and upgrade ArcelorMittal Indiana Harbor steelmaking complex facilities. One of

  18. Scrap recycling and production of high quality steel grades in Europe

    SciTech Connect (OSTI)

    Marique, C.

    1996-12-31

    The possible deleterious effects of higher contents in tramp elements on steel properties must be well defined in order to keep them within acceptable limits. No industrial technique is presently available to remove tramp elements from steel melts. Only a strict control on the metallic input and on the scrap composition is feasible. In this matter, scrap preparation which aims at a better separation between iron and other nonferrous components, is getting more attention. A large multinational project has been initiated in Europe under the sponsorship of ECSC and of the Steel Industry to better identify the effects of residuals on steel properties and to examine potential techniques able to control tramp elements during steelmaking operations. The project has been supported and orientated by a preliminary study, reviewing the relevant published data on the tramp element influence for long and flat products. The present report is devoted to overview available information on the effects of tramp elements and to describe the targets and the content of the European megaproject on scrap recycling.

  19. A new direct steel making process based upon the blast furnace (Including scrap processing with recovery of tramp elements)

    SciTech Connect (OSTI)

    Nabi, G.

    1996-12-31

    Steel is produced from raw materials containing iron and alloying elements with direct elimination of oxygen and impurities in the blast furnace process. The blast furnace shaft is modified to take off load from the liquid bath and carbon is prevented from going into the liquid steel. In the gas purification system sulphur and CO{sub 2} removal facilities are included and purified reducing gases so obtained are combusted in the hearth with oxygen to produce heat for smelting. Scrap can be charged as raw material with the recovery of tramp elements with continuous production of liquid steel.

  20. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J.; Gross, M.

    1995-12-01

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  1. Material report in support to RCC-MRX code 2010 stainless steel parts and products

    SciTech Connect (OSTI)

    Ancelet, Olivier; Lebarbe, Thierry; Dubiez-Le Goff, Sophie; Bonne, Dominique; Gelineau, Odile

    2012-07-01

    This paper presents the Material Report dedicated to stainless steels parts and products issued by AFCEN (Association Francaise pour les regles de Conception et de Construction des Materiels des Chaudieres Electro-Nucleaires) in support to RCC-MRx 2010 Code. The RCC-MRx Code is the result of the merger of the RCC-MX 2008, developed in the context of the research reactor Jules Horowitz Reactor project, in the RCC-MR 2007, which set up rules applicable to the design of components operating at high temperature and to the Vacuum Vessel of ITER (a presentation of RCC-MRx 2010 Code is the subject of another paper proposed in this Congress; it explains in particular the status of this Code). This Material Report is part of a set of Criteria of RCC-MRx (this set of Criteria is under construction). The Criteria aim at explaining the design and construction rules of the Code. They cover analyses rules as well as part procurement, welding, methods of tests and examination and fabrication rules. The Material Report particularly provides justifications and explanations on requirements and features dealing with parts and products proposed in the Code. The Material Report contains the following information: Introduction of the grade(s): codes and standards and Reference Procurement Specifications covering parts and products, applications and experience gained, - Physical properties, - Mechanical properties used for design calculations (base metal and welds): basic mechanical properties, creep mechanical properties, irradiated mechanical properties, - Fabrication: experience gained, metallurgy, - Welding: weldability, experience gained during welding and repair procedure qualifications, - Non-destructive examination, - In-service behaviour. In the article, examples of data supplied in the Material Report dedicated to stainless steels will be exposed. (authors)

  2. Profiles in garbage: Steel cans

    SciTech Connect (OSTI)

    Miller, C.

    1998-02-01

    Steel mills are the largest market for steel cans. Integrated mills use the basic oxygen process to manufacture tinplate, appliances, car bodies, and steel framing. Electric arc furnaces use 100% scrap to produce steel shapes such as railroad ties and bridge spans. Electric arc furnaces are more geographically diverse and tend to have smaller capacities than basic oxygen furnaces. Detinners remove the tin from steel cans for resale to tin using industries. With less tin use in steel cans, the importance of the detinning market has declined substantially. Foundries use scrap as a raw material in making castings and molds for industrial users.

  3. Baotou Iron and Steel Group Baotou Steel | Open Energy Information

    Open Energy Info (EERE)

    search Name: Baotou Iron and Steel Group (Baotou Steel) Place: Baotou, Inner Mongolia Autonomous Region, China Product: Baotou-based iron and steel maker as well as a rare...

  4. Dezincing of steel scrap

    SciTech Connect (OSTI)

    Rij, P.W. van; Campenon, B.; Mooij, J.N.

    1997-04-01

    Scrap is an important raw material in the steel industry. Depending on the type of steelmaking process, the composition of the scrap may vary. Market research in Europe shows that there will be a shortage of zinc-free scrap in the future. An alkaline dezincing process for galvanized steel has been developed. A description of a pilot plant based on alkaline dezincing technology is presented.

  5. Transformation process for production of ultrahigh carbon steels and new alloys

    DOE Patents [OSTI]

    Strum, Michael J.; Goldberg, Alfred; Sherby, Oleg D.; Landingham, Richard L.

    1995-01-01

    Ultrahigh carbon steels with superplastic properties are produced by heating a steel containing ferrite and carbide phases to a soaking temperature approximately 50.degree. C. above the A.sub.1 transformation temperature, soaking the steel above the A.sub.1 temperature for a sufficient time that the major portion of the carbides dissolve into the austenite matrix, and then cooling the steel in a controlled manner within predetermined limits of cooling rate or transformation temperature, to obtain a steel having substantially spheroidal carbides. New alloy compositions contain aluminum and solute additions which promote the formation of a fine grain size and improve the resistance of the carbides to coarsening at the forming temperature.

  6. Transformation process for production of ultrahigh carbon steels and new alloys

    DOE Patents [OSTI]

    Strum, M.J.; Goldberg, A.; Sherby, O.D.; Landingham, R.L.

    1995-08-29

    Ultrahigh carbon steels with superplastic properties are produced by heating a steel containing ferrite and carbide phases to a soaking temperature approximately 50 C above the A{sub 1} transformation temperature, soaking the steel above the A{sub 1} temperature for a sufficient time that the major portion of the carbides dissolve into the austenite matrix, and then cooling the steel in a controlled manner within predetermined limits of cooling rate or transformation temperature, to obtain a steel having substantially spheroidal carbides. New alloy compositions contain aluminum and solute additions which promote the formation of a fine grain size and improve the resistance of the carbides to coarsening at the forming temperature. 9 figs.

  7. Steel Industry Profile

    Broader source: Energy.gov [DOE]

    The steel industry is critical to the U.S. economy. Steel is the material of choice for many elements of manufacturing, construction, transportation, and various consumer products. Traditionally...

  8. Quantify the energy and environmental benefits of implementing energy-efficiency measures in China’s iron and steel production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ma, Ding; Chen, Wenying; Xu, Tengfang

    2015-08-21

    As one of the most energy-, emission- and pollution-intensive industries, iron and steel production is responsible for significant emissions of greenhouse gas (GHG) and air pollutants. Although many energy-efficiency measures have been proposed by the Chinese government to mitigate GHG emissions and to improve air quality, lacking full understanding of the costs and benefits has created barriers against implementing these measures widely. This paper sets out to advance the understanding by addressing the knowledge gap in costs, benefits, and cost-effectiveness of energy-efficiency measures in iron and steel production. Specifically, we build a new evaluation framework to quantify energy benefits andmore » environmental benefits (i.e., CO2 emission reduction, air-pollutants emission reduction and water savings) associated with 36 energy-efficiency measures. Results show that inclusion of benefits from CO2 and air-pollutants emission reduction affects the cost-effectiveness of energy-efficiency measures significantly, while impacts from water-savings benefits are moderate but notable when compared to the effects by considering energy benefits alone. The new information resulted from this study should be used to augment future programs and efforts in reducing energy use and environmental impacts associated with steel production.« less

  9. Quantify the energy and environmental benefits of implementing energy-efficiency measures in China’s iron and steel production

    SciTech Connect (OSTI)

    Ma, Ding; Chen, Wenying; Xu, Tengfang

    2015-08-21

    As one of the most energy-, emission- and pollution-intensive industries, iron and steel production is responsible for significant emissions of greenhouse gas (GHG) and air pollutants. Although many energy-efficiency measures have been proposed by the Chinese government to mitigate GHG emissions and to improve air quality, lacking full understanding of the costs and benefits has created barriers against implementing these measures widely. This paper sets out to advance the understanding by addressing the knowledge gap in costs, benefits, and cost-effectiveness of energy-efficiency measures in iron and steel production. Specifically, we build a new evaluation framework to quantify energy benefits and environmental benefits (i.e., CO2 emission reduction, air-pollutants emission reduction and water savings) associated with 36 energy-efficiency measures. Results show that inclusion of benefits from CO2 and air-pollutants emission reduction affects the cost-effectiveness of energy-efficiency measures significantly, while impacts from water-savings benefits are moderate but notable when compared to the effects by considering energy benefits alone. The new information resulted from this study should be used to augment future programs and efforts in reducing energy use and environmental impacts associated with steel production.

  10. Cronifer 1925 hMo: A promising high-alloy steel for shelf oil and gas production

    SciTech Connect (OSTI)

    Rockel, M.; Jasner, M.

    1995-02-01

    The Cronifer 1925 hMo steel, which is known as a superaustenitic steel, possesses a high resistance toward pitting corrosion (PC), crevice corrosion (CC), and toward corrosion cracking (CoC) in media with a high chloride content and in hydrogen-sulfide-containing gases and condensates. The nominal chemical composition of Cronifer 1925 hMo is (%): < 0.02 C, 24.5-25.5 Ni, 20.0-21.0 Cr, < 1.0 Mn, < 0.5 Si, 0.8-1.0 Cu, 6.0-6.8 Mo, 0.18-0.20 N, < 0.005 S, and < 0.03 P. As a result of the high chromium and molybdenum content, the pitting resistance equivalent (PRE) is equal, according to the PRE equation to PRE = % Cr + 3.3% Mo - 30% N = 74%. A stainless steel is considered as corrosion-resisting in sea water at PRE {ge} 35%. The increased nickel content makes Cronifer 1925 hMo also resistant toward CoC under stress in sea water and in other media with high chloride contents, a well as in gas condensates which contain hydrogen sulfide. All this makes the steel effective for use in marine conditions and in media encountered in the shelf production of oil and gas. The addition of nickel preserves the austenitic structure and improves the passivation properties. Copper improves the resistance of the steel toward general corrosion in reducing media; however, too high a copper content is harmful when the steel is used in neutral chloride-containing solutions and must be limited (not higher than 1%). Cronifer 1925 hMo can be used in hydrocarbon production on the shelf in the following equipment: in fire-extinguishing systems which use fresh and sea water; in pipe systems which return the separated water and gases (with high chloride contents at high pressures and elevated temperatures) to the well in order to fill cavities or to maintain pressure; in separating and cooling equipment of gas and oil production platforms and in oil and gas refineries; and in underwater installations, collectors, and pipe systems, operating under pressure.

  11. Carbonation of steel slag for CO{sub 2} sequestration: leaching of products and reaction mechanisms

    SciTech Connect (OSTI)

    Wouter J.J. Huijgen; Rob N.J. Comans

    2006-04-15

    Carbonation of industrial alkaline residues can be used as a CO{sub 2} sequestration technology to reduce carbon dioxide emissions. In this study, steel slag samples were carbonated to a varying extent. Leaching experiments and geochemical modeling were used to identify solubility-controlling processes of major and trace elements, both with regard to carbonation mechanisms and the environmental properties of the (carbonated) steel slag. Carbonation was shown to reduce the leaching of alkaline earth metals (except Mg) by conversion of Ca-phases, such as portlandite, ettringite, and Ca-(Fe)-silicates into calcite, possibly containing traces of Ba and Sr. The leaching of vanadium increased substantially upon carbonation, probably due to the dissolution of a Ca-vanadate. The reactive surface area of Al- and Fe-(hydr)oxides increased with the carbonation degree, which tends to reduce the leaching of sorption-controlled trace elements. Sorption on Mn-(hydr)oxides was found to be required to adequately model the leaching of divalent cations, but was not influenced by carbonation. Consideration of these three distinct reactive surfaces and possible (surface) precipitation reactions resulted in adequate modeling predictions of oxyanion and trace metal leaching from (carbonated) steel slag. Hence, these surfaces exert a major influence on the environmental properties of both fresh and carbonated steel slag. 24 refs., 1 fig., 2 tabs.

  12. Energy and materials flows in the iron and steel industry

    SciTech Connect (OSTI)

    Sparrow, F.T.

    1983-06-01

    Past energy-consumption trends and future energy-conservation opportunities are investigated for the nation's iron and steel industry. It is estimated that, in 1980, the industry directly consumed approximately 2.46 x 10/sup 15/ Btu of energy (roughly 3% of total US energy consumption) to produce 111 million tons of raw steel and to ship 84 million tons of steel products. Direct plus indirect consumption is estimated to be about 3.1 x 10/sup 15/ Btu. Of the set of conservation technologies identified, most are judged to be ready for commercialization if and when the industry's capital formation and profitability problems are solved and the gradual predicted increase in energy prices reduces the payback periods to acceptable levels.

  13. JFE Steel Corp | Open Energy Information

    Open Energy Info (EERE)

    Corp Jump to: navigation, search Name: JFE Steel Corp Place: Tokyo, Tokyo, Japan Zip: 100-0011 Product: Japanese steel manufacturer; manufactures metallurgical silicon and plans to...

  14. Kobe Steel Ltd Kobelco | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Kobe Steel Ltd (Kobelco) Place: Kobe-shi, Hyogo, Japan Zip: 651-8585 Sector: Solar Product: Japanese steel manufacturer; manufactures PV...

  15. Energy Saving Melting and Revert Reduction Technology (Energy-SMARRT): Clean Steel Casting Production

    SciTech Connect (OSTI)

    Kuyucak, Selcuk; Li, Delin

    2013-12-31

    Inclusions in steel castings can cause rework, scrap, poor machining, and reduced casting performance, which can obviously result in excess energy consumption. Significant progress in understanding inclusion source, formation and control has been made. Inclusions can be defined as non-metallic materials such as refractory, sand, slag, or coatings, embedded in a metallic matrix. This research project has focused on the mold filling aspects to examine the effects of pouring methods and gating designs on the steel casting cleanliness through water modeling, computer modeling, and melting/casting experiments. Early in the research project, comprehensive studies of bottom-pouring water modeling and low-alloy steel casting experiments were completed. The extent of air entrainment in bottom-poured large castings was demonstrated by water modeling. Current gating systems are designed to prevent air aspiration. However, air entrainment is equally harmful and no prevention measures are in current practice. In this study, new basin designs included a basin dam, submerged nozzle, and nozzle extension. The entrained air and inclusions from the gating system were significantly reduced using the new basin method. Near the end of the project, there has been close collaboration with Wescast Industries Inc., a company manufacturing automotive exhaust components. Both computer modeling using Magma software and melting/casting experiments on thin wall turbo-housing stainless steel castings were completed in this short period of time. Six gating designs were created, including the current gating on the pattern, non-pressurized, partially pressurized, naturally pressurized, naturally pressurized without filter, and radial choke gating without filter, for Magma modeling. The melt filling velocity and temperature were determined from the modeling. Based on the simulation results, three gating designs were chosen for further melting and casting experiments on the same casting pattern using

  16. Final Report: No{sub x} Emissions from By Product Fuel Combustion in Steel Making, September 15, 1996 - October 15, 1999

    SciTech Connect (OSTI)

    Pershing, David W.; Lighty, JoAnn S.; Eddings, Eric G.; Cacciatore, David A.

    1999-01-28

    Exhaust gases from the primary operations in the steel making process are almost exclusively utilized as supplemental fuels within the steel plant. These by-product fuels include blast furnace gas (BFG) and coke oven gas (COG) which contain mixtures of H{sub 2}, CO, CH{sub 4} and trace amounts of some heavier hydrocarbons and the impurities NH{sub 3} and HCN. These fuels are burned alone or in combination with natural gas to fire the coke ovens, blast furnace stoves utility boilers and metal working furnaces. The utilization of these by-product fuels reduces the waste gas emissions at the steel mill and reduces the requirements for outside fuel sources. However, as with primary fuel sources, the combustion of these by-product fuel blends does produce hazardous pollutants, in particular nitrogen oxides, and because these are atypical fuel blends of varying composition, the pollutant formation is not well understood. The objective of this research was to develop an understanding of the mechanisms controlling NO{sub x} formation from the combustion of by-product fuels from the steel industry and investigate control and design options to minimize emissions. The minimization strategies investigated were constrained by limits on CO and hydrocarbon emissions, both of which increased under fuel-rich combustion scenarios that resulted in reduced NO{sub x} emissions. Also, the minimization strategies were constrained by the need for reasonable heat generation rates in the furnaces that employ these by-product fuels, so that product steel quality is not adversely affected.

  17. Conversion of raw carbonaceous fuels

    DOE Patents [OSTI]

    Cooper, John F.

    2007-08-07

    Three configurations for an electrochemical cell are utilized to generate electric power from the reaction of oxygen or air with porous plates or particulates of carbon, arranged such that waste heat from the electrochemical cells is allowed to flow upwards through a storage chamber or port containing raw carbonaceous fuel. These configurations allow combining the separate processes of devolatilization, pyrolysis and electrochemical conversion of carbon to electric power into a single unit process, fed with raw fuel and exhausting high BTU gases, electric power, and substantially pure CO.sub.2 during operation.

  18. CRADA No. NFE-10-02715 Assessment of AFA Stainless Steels for Tube Products in Chemical Processing and Energy Production Applications

    SciTech Connect (OSTI)

    Brady, Michael P; Yamamoto, Yukinori; Epler, Mario; Magee, John H

    2011-09-01

    Oak Ridge National Laboratory (ORNL) and Carpenter Technology Corporation (Carpenter) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation Program to assess material properties of several potential AFA family grades and explore the feasibility of producing alumina-forming austenitic (AFA) stainless steels in tubular form needed for many power generation and chemical process applications. Carpenter's Research Laboratory successfully vacuum melted 30 lb heats of seven candidate AFA alloy compositions representing a wide range of alloy content and intended application temperatures. These compositions were evaluated by ORNL and Carpenter R&D for microstructure, tensile properties, creep properties, and oxidation resistance. In parallel, additional work was directed toward an initial tube manufacture demonstration of a baseline AFA alloy. Carpenter successfully manufactured a 10,000 lb production heat and delivered appropriate billets to a partner for extrusion evaluation. Tube product was successfully manufactured from the baseline AFA alloy, indicating good potential for commercially produced AFA tubular form material.

  19. Austenite stabilization and high strength-elongation product of a low silicon aluminum-free hot-rolled directly quenched and dynamically partitioned steel

    SciTech Connect (OSTI)

    Tan, Xiao-Dong; Xu, Yun-Bo; Yang, Xiao-Long; Hu, Zhi-Ping; Peng, Fei; Ju, Xiao-Wei; Wu, Di

    2015-06-15

    Microstructures composed of lath martensite and retained austenite with volume fraction between 8.0 vol.% and 12.0 vol.% were obtained in a low-C low-Si Al-free steel through hot-rolling direct quenching and dynamical partitioning (HDQ&DP) processes. The austenite stabilization mechanism in the low-C low-Si Al-free steel under the special dynamical partitioning processes is investigated by analyzing the carbon partition behavior from martensite to austenite and the carbide precipitation-coarsening behavior in martensite laths combining with the possible hot rolling deformation inheritance. Results show that the satisfying retained austenite amount in currently studied low-Si Al-free HDQ&DP steel is caused by the high-efficiency carbon enrichment in the 30–80 nm thick regions of austenite near the interfaces in the hot-rolled ultra-fast cooled structure and the avoidance of serious carbides coarsening during the continuous cooling procedures. The excellent strength-elongation product reaching up to 26,000 MPa% shows that the involved HDQ&DP process is a promising method to develop a new generation of advanced high strength steel. - Highlights: • HDQ&DP processes were applied to a low-C low-Si Al-free steel. • Effective partitioning time during the continuous cooling processes is 1–220 s. • Retained austenite with volume fraction between 8.0 vol. % and 12.0 vol. % has been obtained. • The special austenite stabilization mechanism has been expounded.

  20. Tokyo Steel Manufacturing Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Co Ltd Jump to: navigation, search Name: Tokyo Steel Manufacturing Co, Ltd Place: Japan Zip: 100-0013 Product: Tokyo Steel is involved in the manufacture and sale of steel...

  1. Korea Iron Steel Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Steel Co Ltd Jump to: navigation, search Name: Korea Iron & Steel Co Ltd Place: Changwon, South Gyeongsang, Korea (Republic) Zip: 641 370 Product: Korea-based manufacturer of steel...

  2. Largest Producer of Steel Products in the United States Achieves Significant Energy Savings at its Minntac Plant

    SciTech Connect (OSTI)

    2008-09-01

    The U. S. Steel Minntac plant in Mt. Iron, MN, achieved annual savings of $760,000 and 95,000 MMBtu after receiving a DOE Save Energy Now energy assessment and implementing recommendations to improve the efficiency of its process heating system.

  3. The industrial ecology of steel

    SciTech Connect (OSTI)

    Considine, Timothy J.; Jablonowski, Christopher; Considine, Donita M.M.; Rao, Prasad G.

    2001-03-26

    This study performs an integrated assessment of new technology adoption in the steel industry. New coke, iron, and steel production technologies are discussed, and their economic and environmental characteristics are compared. Based upon detailed plant level data on cost and physical input-output relations by process, this study develops a simple mathematical optimization model of steel process choice. This model is then expanded to a life cycle context, accounting for environmental emissions generated during the production and transportation of energy and material inputs into steelmaking. This life-cycle optimization model provides a basis for evaluating the environmental impacts of existing and new iron and steel technologies. Five different plant configurations are examined, from conventional integrated steel production to completely scrap-based operations. Two cost criteria are used to evaluate technology choice: private and social cost, with the latter including the environmental damages associated with emissions. While scrap-based technologies clearly generate lower emissions in mass terms, their emissions of sulfur dioxide and nitrogen oxides are significantly higher. Using conventional damage cost estimates reported in the literature suggests that the social costs associated with scrap-based steel production are slightly higher than with integrated steel production. This suggests that adopting a life-cycle viewpoint can substantially affect environmental assessment of new technologies. Finally, this study also examines the impacts of carbon taxes on steel production costs and technology choice.

  4. Development of New Stainless Steel

    SciTech Connect (OSTI)

    Robert F. Buck

    2005-08-30

    A new family of innovative martensitic stainless steels, 521-A, 521-B, and 521-C has been developed by Advanced Steel Technology, LLC (Trafford, PA) as high strength fastener (bolt) materials for use at moderate temperatures in turbine engines, including steam turbines, gas turbines, and aircraft engines. The primary objective of the development program was to create a martensitic stainless steel with high strength at moderate temperatures, and which could replace the expensive nickel-based superalloy IN 718 in some fasteners applications. A secondary objective was to replace conventional 12Cr steels such as AISI 422 used as blades, buckets and shafts that operate at intermediate temperatures in turbine engines with stronger steel. The composition of the new alloys was specifically designed to produce excellent mechanical properties while integrating heat treatment steps into production to reduce energy consumption during manufacturing. As a result, production costs and energy consumption during production of rolled bar products is significantly lower than conventional materials. Successful commercialization of the new alloys would permit the installed cost of certain turbine engines to be reduced without sacrificing high availability or operational flexibility, thereby enhancing the global competitiveness of U.S. turbine engine manufacturers. Moreover, the domestic specialty steel industry would also benefit through increased productivity and reduced operating costs, while increasing their share of the international market for turbine engine fasteners, blades, buckets and shafts.

  5. Steel: Material for the 21. century

    SciTech Connect (OSTI)

    1996-01-01

    In spite of inroads by a range of competing materials, steel is still the primary structural material because of its outstanding strength, ductility, fracture toughness, repairability, and recyclability. Over the past ten years, advances in steelmaking and processing technologies have enabled the development of a wide range of new steel products with improved properties. For example, combinations of closely controlled chemical composition, rolling practices, and cooling rates now permit the production of steels with enhanced fracture toughness and lower susceptibility to hydrogen cracking.

  6. The impact of environmental constraints on productivity improvement and energy efficiency in integrated paper and steel plants

    SciTech Connect (OSTI)

    Boyd, G.A.; McClelland, J.

    1996-12-31

    This paper presents a methodology and results for assessing the impact of production and energy efficiency, environmental regulation, and abatement capital expenditure constraints (e.g. capital rationing) on the productivity of energy and pollution intensive sectors. Energy is treated like any other production input when examining evidence of inefficiency. We find that capital rationing and environmental regulations do contribute to productivity and energy efficiency losses, but do not explain all of the production and energy inefficiencies observed in the paper industry. A summary of the energy source of production inefficiency found in the paper industry, is presented.. Each source is derived as the incremental contribution., i.e. the first is constraints on capital, the second in environmental regulation not accounted for by the first, and the final component is production inefficiency that is not accounted for my any of the- environmental analysis. While the methods are very data intensive, they reveal much more that analysis of aggregate data, 1835 since the only plant level data can provide the estimates of inefficiency that this methodology employs.

  7. Stainless Steel Permeability

    SciTech Connect (OSTI)

    Buchenauer, Dean A.; Karnesky, Richard A.

    2015-09-01

    An understanding of the behavior of hydrogen isotopes in materials is critical to predicting tritium transport in structural metals (at high pressure), estimating tritium losses during production (fission environment), and predicting in-vessel inventory for future fusion devices (plasma driven permeation). Current models often assume equilibrium diffusivity and solubility for a class of materials (e.g. stainless steels or aluminum alloys), neglecting trapping effects or, at best, considering a single population of trapping sites. Permeation and trapping studies of the particular castings and forgings enable greater confidence and reduced margins in the models. For FY15, we have continued our investigation of the role of ferrite in permeation for steels of interest to GTS, through measurements of the duplex steel 2507. We also initiated an investigation of the permeability in work hardened materials, to follow up on earlier observations of unusual permeability in a particular region of 304L forgings. Samples were prepared and characterized for ferrite content and coated with palladium to prevent oxidation. Issues with the poor reproducibility of measurements at low permeability were overcome, although the techniques in use are tedious. Funding through TPBAR and GTS were secured for a research grade quadrupole mass spectrometer (QMS) and replacement turbo pumps, which should improve the fidelity and throughput of measurements in FY16.

  8. Iron and Steel Sector (NAICS 3311 and 3312) Energy and GHG Combustion Emissions Profile, November 2012

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    99 2.6 IRON AND STEEL SECTOR (NAICS 3311, 3312) 2.6.1. Overview of the Iron and Steel Manufacturing Sector The iron and steel sector is an essential part of the U.S. manufacturing sector, providing the necessary raw material for the extensive industrial supply chain. U.S. infrastructure is heavily reliant on the U.S. iron and steel sector, as it provides the foundation for construction (bridges, buildings), transportation systems (railroads, cars, trucks), utility systems (municipal water

  9. Advanced steel reheat furnace

    SciTech Connect (OSTI)

    Moyeda, D.; Sheldon, M.; Koppang, R.; Lanyi, M.; Li, X.; Eleazer, B.

    1997-10-01

    Energy and Environmental Research Corp. (EER) under a contract from the Department of Energy is pursuing the development and demonstration of an Advanced Steel Reheating Furnace. This paper reports the results of Phase 1, Research, which has evaluated an advanced furnace concept incorporating two proven and commercialized technologies previously applied to other high temperature combustion applications: EER`s gas reburn technology (GR) for post combustion NOx control; and Air Product`s oxy-fuel enrichment air (OEA) for improved flame heat transfer in the heating zones of the furnace. The combined technologies feature greater production throughput with associated furnace efficiency improvements; lowered NOx emissions; and better control over the furnace atmosphere, whether oxidizing or reducing, leading to better control over surface finish.

  10. Raw material preparation for ultra high production rate sintering

    SciTech Connect (OSTI)

    Kortmann, H.A.; Ritz, V.J.; Cappel, F.; Weisel, H.; Richter, G.

    1995-12-01

    An R and D program in pot grate sintering showed, that an intensive preparation of ores, additives and coke breeze improves the sintering capacity. The tests were conducted using an ore mixture composed of typical ores imported to Europe. The highest capacities were attained up to 63.8 t/m{sup 2} {times} 24 h maximum for a sinter which well fulfills the high requirements on chemical, physical and metallurgical properties.

  11. ITP Steel: Theoretical Minimum Energies to Produce Steel for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Theoretical Minimum Energies to Produce Steel for Selected Conditions, March 2000 ITP Steel: Theoretical Minimum Energies to Produce Steel for Selected Conditions, March 2000 ...

  12. Stainless steel 4003 in the transportation industry

    SciTech Connect (OSTI)

    Kovacs, H.; Stoeckl, M.

    1998-12-31

    The world today sees a dramatic increase in the number of people and the quantities of articles and products which are to be transported. This results in an ever-increasing demand in the steels used in the transportation industry. Key factors are environmental regulations, safety, and life expectancy and product cost in determining which types steel to use. Especially the ferritic 12% chromium stainless steels has seen a significant development and usage in recent years. Compared to typical carbon steels high strength/low alloy steels and structural steels the 12% chromium steels offers improvement in corrosion and wear resistance and weldability outlining advantages in light weight construction and an overall saving. The paper presents the chemical composition and mechanical properties of grade 4003 which is increasingly used worldwide in areas of public transportation, rail transportation, mining industry and sugar industry, among others. The impact of corrosion and abrasion of this stainless steel versus the standard carbon grades and cost efficiency are discussed.

  13. Microstructural characterization in dissimilar friction stir welding between 304 stainless steel and st37 steel

    SciTech Connect (OSTI)

    Jafarzadegan, M.; State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin ; Feng, A.H.; Abdollah-zadeh, A.; Saeid, T.; Shen, J.; Assadi, H.

    2012-12-15

    In the present study, 3 mm-thick plates of 304 stainless steel and st37 steel were welded together by friction stir welding at a welding speed of 50 mm/min and tool rotational speed of 400 and 800 rpm. X-ray diffraction test was carried out to study the phases which might be formed in the welds. Metallographic examinations, and tensile and microhardness tests were used to analyze the microstructure and mechanical properties of the joint. Four different zones were found in the weld area except the base metals. In the stir zone of the 304 stainless steel, a refined grain structure with some features of dynamic recrystallization was evidenced. A thermomechanically-affected zone was characterized on the 304 steel side with features of dynamic recovery. In the other side of the stir zone, the hot deformation of the st37 steel in the austenite region produced small austenite grains and these grains transformed to fine ferrite and pearlite and some products of displacive transformations such as Widmanstatten ferrite and martensite by cooling the material after friction stir welding. The heat-affected zone in the st37 steel side showed partially and fully refined microstructures like fusion welding processes. The recrystallization in the 304 steel and the transformations in the st37 steel enhanced the hardness of the weld area and therefore, improved the tensile properties of the joint. - Highlights: Black-Right-Pointing-Pointer FSW produced sound welds between st37 low carbon steel and 304 stainless steel. Black-Right-Pointing-Pointer The SZ of the st37 steel contained some products of allotropic transformation. Black-Right-Pointing-Pointer The material in the SZ of the 304 steel showed features of dynamic recrystallization. Black-Right-Pointing-Pointer The finer microstructure in the SZ increased the hardness and tensile strength.

  14. Ultrahigh carbon steels, Damascus steels, and superplasticity

    SciTech Connect (OSTI)

    Sherby, O.D.; Wadsworth, J.

    1997-04-01

    The processing properties of ultrahigh carbon steels (UHCSs) have been studied at Stanford University over the past twenty years. These studies have shown that such steels (1 to 2.1% C) can be made superplastic at elevated temperature and can have remarkable mechanical properties at room temperature. It was the investigation of these UHCSs that eventually brought us to study the myths, magic, and metallurgy of ancient Damascus steels, which in fact, were also ultrahigh carbon steels. These steels were made in India as castings, known as wootz, possibly as far back as the time of Alexander the Great. The best swords are believed to have been forged in Persia from Indian wootz. This paper centers on recent work on superplastic UHCSs and on their relation to Damascus steels. 32 refs., 6 figs.

  15. Using Coke Oven Gas in a Blast Furnace Saves Over $6 Million Annually at a Steel Mill (U.S. Steel Edgar Thompson Plant)

    SciTech Connect (OSTI)

    2000-12-01

    Like most steel companies, U.S. Steel (USS) had been using coke oven gas (COG), a by-product of coke manufacturing, as a fuel in their coke ovens, boilers, and reheat furnaces.

  16. Weldability of nitrogen-enhanced HSLA steels

    SciTech Connect (OSTI)

    Liao, F.C.; Liu, S.; Olson, D.L.

    1993-12-31

    Light microscopy, electron microscopy and Charpy-V-Notch (CVN) testing were used to characterize two Ti-V microalloyed steels which contained 130 and 30 ppm of nitrogen with respect to weldability. Particular emphasis has been placed on the understanding of the heat input-microstructure-toughness relationship in the high nitrogen HSLA steel. Within the 1 to 3 kJ/mm heat input range, the high nitrogen steel exhibited coarse grained heat affected zone (CGHAZ) toughness superior to that of the low nitrogen steel. The transition temperatures (measured at 50 ft-lb impact energy) were, in average, 15 to 60 C lower than those presented by the low nitrogen steel. Quantitative metallography results showed that high nitrogen steel CGHAZs have smaller austenite grain size and larger amount of grain boundary ferrite. Combining the microstructural information and toughness data, it was concluded that for the high nitrogen steel to exhibit superior properties than the low nitrogen steel, the final HAZ microstructure must contain at least 60% of lathy (bainitic) phases, balanced with ferritic products.

  17. Supporting steel

    SciTech Connect (OSTI)

    Badra, C.

    1995-10-01

    The US Department of Energy (DOE) and the American Iron and Steel Institute (AISI) have just completed a pilot program on the technical and economic viability of direct ironmaking by a process based on bath smelting. In this process, oxygen, prereduced iron ore pellets, coal, and flux are charged into a molten slag bath containing a high percentage of carbon. The carbon removes oxygen from the iron ore and generates carbon monoxide and liquid iron. Oxygen is then injected to burn some of the carbon monoxide gas before it leaves the smelting vessel. The partially combusted gas is sued to preheat and prereduced the ore before it is injected into the bath. There are several competing cokeless ironmaking processes in various stages of development around the world. A brief comparison of these processes provides a useful perspective with which to gauge the progress and objectives of the AISI-DOE research initiative. The principal competing foreign technologies include the Corex process, DIOS, HIsmelt, and Jupiter. The advantages of the direct ironmaking process examined by AISI-DOE were not sufficiently demonstrated to justify commercialization without further research. However, enough knowledge was gained from laboratory and pilot testing to teach researchers how to optimize the direct ironmaking process and to provide the foundation for future research. Researchers now better understand issues such as the dissolution of materials, reduction mechanisms and rates, slag foaming and control, the behavior of sulfur, dust generation, and the entire question of energy efficiency--including post combustion and the role of coal/volatile matter.

  18. ITP Steel: Energy and Environmental Profile fo the U.S. Iron and Steel Industry

    Office of Energy Efficiency and Renewable Energy (EERE)

    DOE's Office of Industrial Technologes has formed a partnership with the U.S. iron and steel industry to accelerate development of technologies and processes that will improve the industry's production and energy efficiency and environmental performance.

  19. Automated Steel Cleanliness Analysis Tool (ASCAT)

    SciTech Connect (OSTI)

    Gary Casuccio; Michael Potter; Fred Schwerer; Dr. Richard J. Fruehan; Dr. Scott Story

    2005-12-30

    The objective of this study was to develop the Automated Steel Cleanliness Analysis Tool (ASCATTM) to permit steelmakers to evaluate the quality of the steel through the analysis of individual inclusions. By characterizing individual inclusions, determinations can be made as to the cleanliness of the steel. Understanding the complicating effects of inclusions in the steelmaking process and on the resulting properties of steel allows the steel producer to increase throughput, better control the process, reduce remelts, and improve the quality of the product. The ASCAT (Figure 1) is a steel-smart inclusion analysis tool developed around a customized next-generation computer controlled scanning electron microscopy (NG-CCSEM) hardware platform that permits acquisition of inclusion size and composition data at a rate never before possible in SEM-based instruments. With built-in customized ''intelligent'' software, the inclusion data is automatically sorted into clusters representing different inclusion types to define the characteristics of a particular heat (Figure 2). The ASCAT represents an innovative new tool for the collection of statistically meaningful data on inclusions, and provides a means of understanding the complicated effects of inclusions in the steel making process and on the resulting properties of steel. Research conducted by RJLG with AISI (American Iron and Steel Institute) and SMA (Steel Manufactures of America) members indicates that the ASCAT has application in high-grade bar, sheet, plate, tin products, pipes, SBQ, tire cord, welding rod, and specialty steels and alloys where control of inclusions, whether natural or engineered, are crucial to their specification for a given end-use. Example applications include castability of calcium treated steel; interstitial free (IF) degasser grade slag conditioning practice; tundish clogging and erosion minimization; degasser circulation and optimization; quality assessment/steel cleanliness; slab, billet

  20. Comminuting irradiated ferritic steel

    DOE Patents [OSTI]

    Bauer, Roger E.; Straalsund, Jerry L.; Chin, Bryan A.

    1985-01-01

    Disclosed is a method of comminuting irradiated ferritic steel by placing the steel in a solution of a compound selected from the group consisting of sulfamic acid, bisulfate, and mixtures thereof. The ferritic steel is used as cladding on nuclear fuel rods or other irradiated components.

  1. Process for mitigating corrosion and increasing the conductivity of steel studs in soderberg anodes of aluminum reduction cells

    DOE Patents [OSTI]

    Oden, Laurance L.; White, Jack C.; Ramsey, James A.

    1994-01-01

    A corrosion resistant electrically conductive coating on steel anode studs used in the production of aluminum by electrolysis.

  2. Methods of forming steel

    DOE Patents [OSTI]

    Branagan, Daniel J.; Burch, Joseph V.

    2001-01-01

    In one aspect, the invention encompasses a method of forming a steel. A metallic glass is formed and at least a portion of the glass is converted to a crystalline steel material having a nanocrystalline scale grain size. In another aspect, the invention encompasses another method of forming a steel. A molten alloy is formed and cooled the alloy at a rate which forms a metallic glass. The metallic glass is devitrified to convert the glass to a crystalline steel material having a nanocrystalline scale grain size. In yet another aspect, the invention encompasses another method of forming a steel. A first metallic glass steel substrate is provided, and a molten alloy is formed over the first metallic glass steel substrate to heat and devitrify at least some of the underlying metallic glass of the substrate.

  3. Development of Next Generation Heating System for Scale Free Steel Reheating

    SciTech Connect (OSTI)

    Dr. Arvind C. Thekdi

    2011-01-27

    The work carried out under this project includes development and design of components, controls, and economic modeling tools that would enable the steel industry to reduce energy intensity through reduction of scale formation during the steel reheating process. Application of scale free reheating offers savings in energy used for production of steel that is lost as scale, and increase in product yield for the global steel industry. The technology can be applied to a new furnace application as well as retrofit design for conversion of existing steel reheating furnaces. The development work has resulted in the knowledge base that will enable the steel industry and steel forging industry us to reheat steel with 75% to 95% reduction in scale formation and associated energy savings during the reheating process. Scale reduction also results in additional energy savings associated with higher yield from reheat furnaces. Energy used for steel production ranges from 9 MM Btu/ton to 16.6 MM Btu/ton or the industry average of approximately 13 MM Btu/ton. Hence, reduction in scale at reheating stage would represent a substantial energy reduction for the steel industry. Potential energy savings for the US steel industry could be in excess of 25 Trillion Btu/year when the technology is applied to all reheating processes. The development work has resulted in new design of reheating process and the required burners and control systems that would allow use of this technology for steel reheating in steel as well as steel forging industries.

  4. 1. What is the problem? Lack of secure supply chains for some raw materials cri

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . What is the problem? Lack of secure supply chains for some raw materials critical to clean energy technologies hinders U.S. manufacturing and energy security. These critical materials (a) provide essential and specialized properties to advanced engineered products or systems for which there are no easy substitutes and (b) are subject to supply risk. Rare-earth elements, with essential roles in high-efficiency motors and advanced lighting, are the most prominent of the critical materials today.

  5. Lightweight Steel Solutions for Automotive Industry

    SciTech Connect (OSTI)

    Lee, Hong Woo; Kim, Gyosung; Park, Sung Ho

    2010-06-15

    Recently, improvement in fuel efficiency and safety has become the biggest issue in worldwide automotive industry. Although the regulation of environment and safety has been tightened up more and more, the majority of vehicle bodies are still manufactured from stamped steel components. This means that the optimized steel solutions enable to demonstrate its ability to reduce body weight with high crashworthiness performance instead of expensive light weight materials such as Al, Mg and composites. To provide the innovative steel solutions for automotive industry, POSCO has developed AHSS and its application technologies, which is directly connected to EVI activities. EVI is a technical cooperation program with customer covering all stages of new car project from design to mass production. Integrated light weight solutions through new forming technologies such as TWB, hydroforming and HPF are continuously developed and provided for EVI activities. This paper will discuss the detailed status of these technologies especially light weight steel solutions based on innovative technologies.

  6. X-ray Photoelectron Spectroscopic Analyses of Corrosion Products Formed on Rock Bolt Carbon Steel in Chloride Media with Bicarbonate and Silicate Ions

    SciTech Connect (OSTI)

    Deodeshmukh, Vinay; Venugopal, A; Chandra, Dhanesh; Yilmaz, Ahmet; Daemen, Jack; Jones, D A.; Lea, Alan S.; Engelhard, Mark H.

    2004-11-01

    The passivation behavior of Yucca Mountain Repository rock bolt carbon steel in deaerated 3.5% NaCl solution containing SiO{sub 3}{sup 2} and HCO{sub 3} ions was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopic methods. Polarization results indicate that combinations of silicate and bicarbonate anions decrease the passive current density and raise the pitting potential. XPS results indicate the enrichment of silica at passive potentials and the formation of mixed FeCO{sub 3} and silica film at lower potentials. This change in film composition was responsible for the changes in corrosion rate at lower and higher potentials. XPS results also support the thermodynamic data with regard to the occurrence of second oxidation peak observed in the polarization curves to be due to the oxidation of FeCO{sub 3} to Fe{sub 2}O{sub 3}.

  7. Steelmaker Matches Recovery Act Funds to Save Energy & Reduce Steel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Costs | Department of Energy Steelmaker Matches Recovery Act Funds to Save Energy & Reduce Steel Production Costs Steelmaker Matches Recovery Act Funds to Save Energy & Reduce Steel Production Costs March 17, 2014 - 2:24pm Addthis Steelmaker Matches Recovery Act Funds to Save Energy & Reduce Steel Production Costs One-page factsheet describing how ArcelorMittal Indiana Harbor Energy Recovery & Reuse 504 Boiler was constructed and installed with DOE Recovery Act

  8. Automotive frames of stainless steel

    SciTech Connect (OSTI)

    Emmons, J.B.; Douthett, J.

    1996-08-01

    A lightweight, stainless steel vehicle modular frame that meets the requirements of the Partnership for a New Generation of Vehicles (PNGV) is being jointly developed by Armco and Autokinetics. Reaching the long-term goal of the program known as the Supercar will require technology that is capable of significantly reducing mass, while holding the cost of the finished vehicle to current levels. The structure should reduce mass by at least 50%, and must be high in performance, practical to manufacture, and conceptually simple compared to current practice. Another key PNGV goal is the development of a manufacturing infrastructure to attain cost and production levels consistent with auto industry norms. A third goal is to spin off as much of the resulting advanced technology as possible to conventional vehicles, enabling them to benefit from advances in mass reduction, aerodynamics, and materials technologies. All of these benefits can be realized with the stainless steel modular frame.

  9. Success Story: Harrison Steel

    Broader source: Energy.gov [DOE]

    This case study highlights how Harrison Steel leveraged both EPA's ENERGY STAR program and DOE resources to enhance energy efficiency efforts and multiply captured energy savings.

  10. Auto/Steel Partnership: Advanced High-Strength Steel Research...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications AutoSteel Partnership: AHSS Stamping, Strain Rate Characterization, Sheet Steel Fatigue, AHSS Joining FY 2008 Progress Report for Lightweighting ...

  11. ITP Steel: Steel Industry Marginal Opportunity Study September...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Marginal Opportunity Study September 2005 ITP Steel: Steel Industry Marginal Opportunity Study September 2005 steelmarginalopportunity.pdf (346.86 KB) More Documents & Publications ...

  12. Clean engineered steels -- Progress at the end of the twentieth century

    SciTech Connect (OSTI)

    Eckel, J.A.; Glaws, P.C.; Wolfe, J.O.; Zorc, B.J.

    1999-07-01

    The Timken Company, a manufacturer of alloy steel and bearings, has developed a 15 MHz ultrasonic inspection method that correlates steel cleanness to bearing fatigue performance. It is used to qualify worldwide bearing steel suppliers for cleanness requirements, to monitor their compliance and qualify process changes. This method has permitted the appropriate steel cleanness to be selected for bearing applications. Through Continuous Improvement (CI) methodology, steelmaking productivity advancements have occurred along with advancement in steel cleanness. These efforts have led to 4 orders of magnitude steel cleanness improvement, and nearly 20 times bearing performance improvement over the past 15 years.

  13. http://www.c-p-c.com/products/B-25.html

    National Nuclear Security Administration (NNSA)

    Latches Carbon Steel, Aluminum, Stainless Steel Copyright 2006 | All rights reserved. Wilmington Web Site Design by Port City Digital Container Products Corp. 112 North College ...

  14. Improvement of productivity of sintering plant at Nagoya Works of NSC

    SciTech Connect (OSTI)

    Yoshida, Hitoshi; Iida, Hiroyuki; Kabuto, Shigehisa; Suzuki, Haruhisa

    1996-12-31

    It is well known that in the sintering process generally, the state of charging raw materials into the sintering machine and whether or not its stability is good significantly influence the productivity, quality and cost of this process. At the Nagoya sintering plant, therefore, the peripheral of the slit bar-type segregation charging equipment developed by Nippon Steel were improved in 1994. The main improvements were: the improvement of the raw materials charging control mode, the introduction of fluffer bar to improve permeability and the addition of equipment for removal of lumps from sinter mix. After these measures were taken, the state of segregation of the raw materials and carbon between the upper and lower portions of the sinter bed was improved, the charging stability was also improved and the charging density was decreased, making it possible to achieve productivity improvement and cost reduction as originally intended. This report described the outline and concept of the equipment improvement measures and the operation results of the actual machine.

  15. Steel Industry Technology Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steel Industry Technology Roadmap Steel Industry Technology Roadmap Table of Contents Introduction Process Improvement 2.1 Cokemaking 2.2 Ironmaking 2.3 Basic Oxygen Furnace (BOF) Steelmaking 2.4 Electric Arc Furnace (EAF) Steelmaking 2.5 Ladle Refining 2.6 Casting 2.7 Rolling and Finishing 2.8 Refractories Iron Recycling Unit 3.1 By-products 3.2 Obsolete Scrap Environment 4.1 Cokemaking 4.2 Ironmaking 4.3 Steelmaking - Basic Oxygen Furnace (BOF) 4.4 Steelmaking - Electric Arc Furnace (EAF) 4.5

  16. Catalytic glycerol steam reforming for hydrogen production

    SciTech Connect (OSTI)

    Dan, Monica Mihet, Maria Lazar, Mihaela D.

    2015-12-23

    Hydrogen production from glycerol by steam reforming combine two major advantages: (i) using glycerol as raw material add value to this by product of bio-diesel production which is obtained in large quantities around the world and have a very limited utilization now, and (ii) by implication of water molecules in the reaction the efficiency of hydrogen generation is increased as each mol of glycerol produces 7 mol of H{sub 2}. In this work we present the results obtained in the process of steam reforming of glycerol on Ni/Al{sub 2}O{sub 3}. The catalyst was prepared by wet impregnation method and characterized through different methods: N{sub 2} adsorption-desorption, XRD, TPR. The catalytic study was performed in a stainless steel tubular reactor at atmospheric pressure by varying the reaction conditions: steam/carbon ratio (1-9), gas flow (35 ml/min -133 ml/min), temperature (450-650°C). The gaseous fraction of the reaction products contain: H{sub 2}, CH{sub 4}, CO, CO{sub 2}. The optimum reaction conditions as resulted from this study are: temperature 550°C, Gly:H{sub 2}O ratio 9:1 and Ar flow 133 ml/min. In these conditions the glycerol conversion to gaseous products was 43% and the hydrogen yield was 30%.

  17. Glass Stronger than Steel

    DOE R&D Accomplishments [OSTI]

    Yarris, Lynn

    2011-03-28

    A new type of damage-tolerant metallic glass, demonstrating a strength and toughness beyond that of steel or any other known material, has been developed and tested by a collaboration of researchers from Berkeley Lab and Caltech.

  18. ORPC RivGen controller performance raw data - Igiugig 2015

    SciTech Connect (OSTI)

    Jarlath McEntee

    2015-12-18

    Contains raw data for operations of Ocean Renewable Power Company (ORPC) RivGen Power System in Igiugig 2015 in Matlab data file format. Two data files capture the data and timestamps for data, including power in, voltage, rotation rate, and velocity.

  19. Microalloying of steels. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The bibliography contains citations concerning production techniques, performance, and applications of microalloyed steels. Various microalloying materials are examined including niobium, vanadium, titanium, niobium/vanadium, aluminum, boron, molybdenum, and zirconium. Microalloying effects on the mechanical properties, corrosion resistance, metallurgical properties, and hot plasticity of steels are presented. Applications of microalloyed steels in the construction steel industry, physical properties of microalloyed steels, low-temperature service behavior, weldability, formability, and resistance to corrosion are discussed. (Contains a minimum of 190 citations and includes a subject term index and title list.)

  20. Microalloying of steels. (Latest citations from the Compendex database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    The bibliography contains citations concerning production techniques, performance, and applications of microalloyed steels. Various microalloying materials are examined including niobium, vanadium, titanium, niobium/vanadium, aluminum, boron, molybdenum, and zirconium. Microalloying effects on the mechanical properties, corrosion resistance, metallurgical properties, and hot plasticity of steels are presented. Applications of microalloyed steels in the construction steel industry, physical properties of microalloyed steels, low-temperature service behavior, weldability, formability, and resistance to corrosion are discussed. (Contains a minimum of 186 citations and includes a subject term index and title list.)

  1. Microalloying of steels. (Latest citations from the EI compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The bibliography contains citations concerning production techniques, performance, and applications of microalloyed steels. Various microalloying materials are examined including niobium, vanadium, titanium, niobium/vanadium, aluminum, boron, molybdenum, and zirconium. Microalloying effects on the mechanical properties, corrosion resistance, metallurgical properties, and hot plasticity of steels are presented. Applications of microalloyed steels in the construction steel industry, physical properties of microalloyed steels, low-temperature service behavior, weldability, formability, and resistance to corrosion are discussed. (Contains a minimum of 193 citations and includes a subject term index and title list.)

  2. Microalloying of steels. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    1996-03-01

    The bibliography contains citations concerning production techniques, performance, and applications of microalloyed steels. Various microalloying materials are examined including niobium, vanadium, titanium, niobium/vanadium, aluminum, boron, molybdenum, and zirconium. Microalloying effects on the mechanical properties, corrosion resistance, metallurgical properties, and hot plasticity of steels are presented. Applications of microalloyed steels in the construction steel industry, physical properties of microalloyed steels, low-temperature service behavior, weldability, formability, and resistance to corrosion are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  3. ITP Steel: Steel Industry Energy Bandwidth Study October 2004

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Steel can be hot or cold rolled; with hot rolling, the steel either is reheated or directly charged after casting. Reheating is the major energy consumer in the rolling process. ...

  4. ITP Steel: Steel Industry Marginal Opportunity Study September 2005

    Office of Energy Efficiency and Renewable Energy (EERE)

    The objective of this study is to generate a marginal opportunity curve for the ITP steel subprogram showing the location of the current portfolio compared against all opportunities for steel manufacturing.

  5. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of cultivation systems.

  6. Energy use and carbon dioxide emissions in the steel sector in key developing countries

    SciTech Connect (OSTI)

    Price, L.K.; Phylipsen, G.J.M.; Worrell, E.

    2001-04-01

    Iron and steel production consumes enormous quantities of energy, especially in developing countries where outdated, inefficient technologies are still used to produce iron and steel. Carbon dioxide emissions from steel production, which range between 5 and 15% of total country emissions in key developing countries (Brazil, China, India, Mexico, and South Africa), will continue to grow as these countries develop and as demand for steel products such as materials, automobiles, and appliances increases. In this report, we describe the key steel processes, discuss typical energy-intensity values for these processes, review historical trends in iron and steel production by process in five key developing countries, describe the steel industry in each of the five key developing countries, present international comparisons of energy use and carbon dioxide emissions among these countries, and provide our assessment of the technical potential to reduce these emissions based on best-practice benchmarking. Using a best practice benchmark, we find that significant savings, in the range of 33% to 49% of total primary energy used to produce steel, are technically possible in these countries. Similarly, we find that the technical potential for reducing intensities of carbon dioxide emissions ranges between 26% and 49% of total carbon dioxide emissions from steel production in these countries.

  7. Process to Continuously Melt, Refine and Cast High Quality Steel

    SciTech Connect (OSTI)

    2005-09-01

    The purpose of this project is to conduct research and development targeted at designing a revolutionary steelmaking process. This process will deliver high quality steel from scrap to the casting mold in one continuous process and will be safer, more productive, and less capital intensive to build and operate than conventional steelmaking. The new process will produce higher quality steel faster than traditional batch processes while consuming less energy and other resources.

  8. ITP Steel: Energy Use in the U.S. Steel Industry: An Historical Perspective

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Future Opportunities, September 2000 | Department of Energy Use in the U.S. Steel Industry: An Historical Perspective and Future Opportunities, September 2000 ITP Steel: Energy Use in the U.S. Steel Industry: An Historical Perspective and Future Opportunities, September 2000 steel_energy_use.pdf (431.85 KB) More Documents & Publications ITP Steel: Steel Industry Marginal Opportunity Study September 2005 ITP Steel: Steel Industry Energy Bandwidth Study October 2004 ITP Steel: Energy

  9. Analysis of the raw data of sample plots in NFIMAP Cycle IV ...

    Open Energy Info (EERE)

    raw data of sample plots in NFIMAP Cycle IV (English version) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Analysis of the raw data of sample plots in NFIMAP Cycle IV...

  10. OSTIblog Articles in the raw data Topic | OSTI, US Dept of Energy...

    Office of Scientific and Technical Information (OSTI)

    raw data Topic Open Science: the Case for Preserving Raw Data by Dr. Jeffrey Salmon 12 Jul, 2011 in Technology Everyone speaks well of the idea that the results of scientific ...

  11. Steel Creek fish, L-Lake/Steel Creek Biological Monitoring Program, January 1986--December 1991

    SciTech Connect (OSTI)

    Sayers, R.E. Jr.; Mealing, H.G. III

    1992-04-01

    The Savannah River Site (SRS) encompasses 300 sq mi of the Atlantic Coastal plain in west-central South Carolina. The Savannah River forms the western boundary of the site. Five major tributaries of the Savannah River -- Upper Three Runs Creek, Four Mile Creek, Pen Branch, Steel Creek, and Lower Three Runs Creek -- drain the site. All but Upper Three Runs Creek receive, or in the past received, thermal effluents from nuclear production reactors. In 1985, L Lake, a 400-hectare cooling reservoir, was built on the upper reaches of Steel Creek to receive effluent from the restart of L-Reactor, and protect the lower reaches from thermal impacts. The lake has an average width of approximately 600 m and extends along the Steel Creek valley approximately 7000 m from the dam to the headwaters. Water level is maintained at a normal pool elevation of 58 m above mean sea level by overflow into a vertical intake tower that has multilevel discharge gates. The intake tower is connected to a horizontal conduit that passes through the dam and releases water into Steel Creek. The Steel Creek Biological Monitoring Program was designed to meet environmental regulatory requirements associated with the restart of L-Reactor and complements the Biological Monitoring Program for L Lake. This extensive program was implemented to address portions of Section 316(a) of the Clean Water Act. The Department of Energy (DOE) must demonstrate that the operation of L-Reactor will not significantly alter the established aquatic ecosystems.

  12. An overview of bar and seamless tubular microalloyed steels for structural application

    SciTech Connect (OSTI)

    Aloi, N.E. Jr.; Luksa, J.E.

    1995-12-31

    Medium-carbon (0.15 to 0.40 wt.% C) vanadium microalloyed steels produced as large-diameter bar and seamless tubular long products have been successfully applied to structural applications. Microalloyed steels such as WMA-65 and WMA-80 are designed to replace either quenched-and-tempered or hot-rolled carbon steels. Incentives for converting to microalloyed steels include reduced material and processing costs or allowance for smaller, lighter components through increased strength realized through microalloying. Structural steels that require good weldability are restricted to lower carbon and alloy levels and thus are excellent candidates for microalloyed steels. Processing of high-strength vanadium-carbonitride precipitation-strengthened ferrite/pearlite microalloyed steel long products includes controlling bar rolling of sizes from 50 mm (2 in.) to 305 mm (12 in.) OD, or tube piercing of sizes from 38 mm (1.5 in.) to 320 mm (12.5 in.) OD, and air cooling at the steel mill. Bar products may be subsequently forged where controlled processing must also be performed to meet the desired properties. Both bar and tubing products are described. Chemical composition, mechanical properties, and weldability of the processed microalloyed steels are also discussed.

  13. The Romelt Process -- Prospects for pig iron production in North America

    SciTech Connect (OSTI)

    Thompson, M.W.; Weston, T.R.

    1997-12-31

    The iron and steel industry in North America is undergoing dramatic changes and is being driven by three factors. First, the introduction of new technologies and pace of innovation has placed North America at the forefront of commercializing new technologies. Second, new technologies have changed the market for steelmaking raw materials and stimulated an industry-wide discussion of the ``value in use`` of scrap and scrap substitutes. Finally, an increase in environmental costs has fundamentally changed management`s view toward the environmental impact of iron and steelmaking, particularly in the integrated steel industry. This paper discusses the Romelt Process, an emerging ironmaking technology developed by the Moscow Institute for Steels and Alloys, in the context of these industry trends. ICF Kaiser, a worldwide licensee to the Romelt technology, believes that the current North American climate is probably the most conducive of all steelmaking regions to the commercialization of new technologies. Liquid or cast pig iron, the product of the Romelt Process, is the highest value feed for both the EAF and BOF steelmaking processes. In terms of environmental benefits, Romelt uses non-coking coals for its fuel and reductant, and has a proven large scale pilot plant track record in smelting both low grade fine ores and iron bearing wastes from the integrated works.

  14. Steel Market Development Institute Awards "Community Hero" Award...

    Broader source: Energy.gov (indexed) [DOE]

    Steel Market Development Institute Men and Women of Steel Awardees Steel Market Development Institute Men and Women of Steel Awardees At the 2016 North American International Auto ...

  15. RECOVERY OF URANIUM VALUES FROM URANIUM BEARING RAW MATERIALS

    DOE Patents [OSTI]

    Michal, E.J.; Porter, R.R.

    1959-06-16

    Uranium leaching from ground uranium-bearing raw materials using MnO/sub 2/ in H/sub 2/SO/sub 4/ is described. The MnO/sub 2/ oxidizes U to the leachable hexavalent state. The MnO/sub 2/ does not replace Fe normally added, because the Fe complexes P and catalyzes the MnO/sub 2/ reaction. Three examples of continuous processes are given, but batch operation is also possible. The use of MnO/sub 2/ makes possible recovery of very low U values. (T.R.H.)

  16. Ferritic steel melt and FLiBe/steel experiment : melting ferritic steel.

    SciTech Connect (OSTI)

    Troncosa, Kenneth P.; Smith, Brandon M.; Tanaka, Tina Joan

    2004-11-01

    In preparation for developing a Z-pinch IFE power plant, the interaction of ferritic steel with the coolant, FLiBe, must be explored. Sandia National Laboratories Fusion Technology Department was asked to drop molten ferritic steel and FLiBe in a vacuum system and determine the gas byproducts and ability to recycle the steel. We tried various methods of resistive heating of ferritic steel using available power supplies and easily obtained heaters. Although we could melt the steel, we could not cause a drop to fall. This report describes the various experiments that were performed and includes some suggestions and materials needed to be successful. Although the steel was easily melted, it was not possible to drip the molten steel into a FLiBe pool Levitation melting of the drop is likely to be more successful.

  17. History of ultrahigh carbon steels

    SciTech Connect (OSTI)

    Wadsworth, J.; Sherby, O.D.

    1997-06-20

    The history and development of ultrahigh carbon steels (i.e., steels containing between 1 and 2.l percent C and now known as UHCS) are described. The early use of steel compositions containing carbon contents above the eutectoid level is found in ancient weapons from around the world. For example, both Damascus and Japanese sword steels are hypereutectoid steels. Their manufacture and processing is of interest in understanding the role of carbon content in the development of modern steels. Although sporadic examples of UHCS compositions are found in steels examined in the early part of this century, it was not until the mid-1970s that the modern study began. This study had its origin in the development of superplastic behavior in steels and the recognition that increasing the carbon content was of importance in developing that property. The compositions that were optimal for superplasticity involved the development of steels that contained higher carbon contents than conventional modern steels. It was discovered, however, that the room temperature properties of these compositions were of interest in their own right. Following this discovery, a period of intense work began on understanding their manufacture, processing, and properties for both superplastic forming and room temperature applications. The development of superplastic cast irons and iron carbides, as well as those of laminated composites containing UHCS, was an important part of this history.

  18. High-performance steels

    SciTech Connect (OSTI)

    Barsom, J.M.

    1996-03-01

    Steel is the material of choice in structures such as storage tanks, gas and oil distribution pipelines, high-rise buildings, and bridges because of its strength, ductility, and fracture toughness, as well as its repairability and recyclability. Furthermore, these properties are continually being improved via advances in steelmaking, casting, rolling, and chemistry. Developments in steelmaking have led to alloys having low sulfur, sulfide shape control, and low hydrogen. They provide reduced chemical segregation, higher fracture toughness, better through-thickness and weld heat-affected zone properties, and lower susceptibility to hydrogen cracking. Processing has moved beyond traditional practices to designed combinations of controlled rolling and cooling known as thermomechanical control processes (TMCP). In fact, chemical composition control and TMCP now enable such precise adjustment of final properties that these alloys are now known as high-performance steels (HPS), engineered materials having properties tailored for specific applications.

  19. High-Alloy Ferritic Steels: Semi-Austenitic Stainless Steels...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    however, have low fracture toughness in high strength conditions and at low (subzero) temperature. ... Stainless Steels 1700 - 3 4.2 Heat treatment These alloys typically employ ...

  20. Chlorine induced corrosion of steels in fossil fuel power plants

    SciTech Connect (OSTI)

    Spiegel, M.; Grabke, H.J.

    1998-12-31

    The corrosion of steels in power plants (coal combustion, waste incineration) is mainly due to condensed chlorides in the ash deposited on the boiler tubes. These chlorides are stabilized by HCl in the combustion gas. In the case of coal as a fuel, chlorine is present as chloride minerals in the raw material which is converted to HCl during the combustion process. Corrosion of steels in chlorine containing environments occurs by the active oxidation mechanism, which is a self-sustaining accelerated oxidation process, catalyzed by chlorine. This study shows that solid chlorides react with the oxide scale of the steels to form chlorine, which initiates active oxidation. In order to prevent chlorine induced corrosion, the deposition of chlorides on the tubes within the coal ash must be avoided. This is possible by the presence of SO{sub 2}, which is present in the combustion gas, converting the chlorides to sulfates in the gas phase. The paper presents an example of a failure case in a coal fired plant in Germany. In this plant, chlorine induced corrosion was observed after effective removal of SO{sub 2} by additions of CaO. From thermodynamic calculations it can be shown that a certain amount of SO{sub 2} is necessary in order to avoid deposition of chlorides and to prevent corrosion.

  1. Fillability of Thin-Wall Steel Castings

    SciTech Connect (OSTI)

    Robert C. Voigt; Joseph Bertoletti; Andrew Kaley; Sandi Ricotta; Travis Sunday

    2002-07-30

    The use of steel components is being challenged by lighter nonferrous or cast iron components. The development of techniques for enhancing and ensuring the filability of thin-wall mold cavities is most critical for thinner wall cast steel production. The purpose of this research was to develop thin-wall casting techniques that can be used to reliably produce thin-wall castings from traditional gravity poured sand casting processes. The focus of the research was to enhance the filling behavior to prevent misrunds. Experiments were conducted to investigate the influence of various foundry variables on the filling of thin section steel castings. These variables include casting design, heat transfer, gating design, and metal fluidity. Wall thickness and pouring temperature have the greatest effect on casting fill. As wall thickness increases the volume to surface area of the casting increases, which increases the solidification time, allowing the metal to flow further in thicker sect ions. Pouring time is another significant variable affecting casting fill. Increases or decreases of 20% in the pouring time were found to have a significant effect on the filling of thin-wall production castings. Gating variables, including venting, pouring head height, and mold tilting also significantly affected thin-wall casting fill. Filters offer less turbulent, steadier flow, which is appropriate for thicker castings, but they do not enhance thin-wall casting fill.

  2. Possibilities of production of smokeless fuel via carbonization of Czech coals

    SciTech Connect (OSTI)

    Buchtele, J.; Straka, P.

    1995-12-01

    It was consumed 48 -51 % of hard coal (total output 28 - 30 Mt/year) in a long period for the production of coke. It appears to be anomaly in comparison with other coke producers in Europe and in the world, it was predeterminated by {open_quotes}steel conception{close_quotes} of state`s economics. The production of coke reached 10-11 Mt/year in former Czechoslovakia in the period 1970-1990. A considerable quantity 1.2 - 1.7 Mt/year of produced coke was utilized for heating. In comparison, 7-5.4 Mt coke/year was it in Poland for the heating. Al coke production is realized on the basis of Czech hard coals mined in the southern part of Upper Silesian Coal District. The coke production is operated in multi-chamber system with full recovery of chemical products (gas, raw tar, raw benzene, amonium etc.). The future trend of smokeless fuel production in Czech Republic makes for to the non-recovery coke oven, it means to two-product processes (coke + reduction gas, coke + electricity and so on). Jewell--Thompson coke oven (hard coal) and Salem oven (ignites) represent nonrecovery nowadays. The possibility of it`s application in Czech Republic are discussed. Jumbo coking reactor system (European project No. 500 to the Eureka programme) produces primarily metallurgical coke. The strong Clean Air Act suspends the production of smokeless fuel in multi-chamber system also in Czech Republic for the future period 2010-2020.

  3. The future of energy efficiency in the steel industry

    SciTech Connect (OSTI)

    Lakshminarayana, B.

    1997-07-01

    Steel is present in every aspect of life, in all industrial, transportation sectors as well as in households in US. The American steel industry today can be counted among the most productive, efficient and technologically advanced in the world. Steel combines low cost with attractive engineering properties and is the most recycled of all materials. Despite these appealing characteristics of steel, the steel industry has confronted significant challenges from other competitive materials. To keep abreast with the competition it faces, pursuit of research and development activities is an absolute necessity. This competition has forced the steel industry to address many issues that here to fore were deemed unimportant. One of these areas is energy efficiency. Steelmaking energy costs comprise over 15 percent of the manufacturing cost of steel. This compares to less than five percent for most other manufacturing industries. The US steel industry, which accounts for about nine percent (1.8 quads/year) of the US industrial energy use, has made considerable progress in the area of energy efficiency. Over the past 20 years, the US steel industry has reduced its energy intensity by 43 percent. The impact of energy usage on environmental and the results of government regulations have made the industry concentrate more and more on the issues of energy efficiency. In addition, a possible energy shortage could become a global phenomenon in the 21st century if steps to conserve energy are not taken. The risk in researching and adapting new technologies is greater in the steel industry than in many other manufacturing industries. Steelmaking is capital intensive in both equipment and processes. Government/industry partnerships can help reduce such risks. The Department of Energy's Office of Industrial Technologies (DOE/OIT) has been supporting energy efficient research relevant to the steel industry. Salient features of some of the projects will be explored in this paper. These

  4. MECS 2006- Iron and Steel

    Office of Energy Efficiency and Renewable Energy (EERE)

    Manufacturing Energy and Carbon Footprint for Iron and Steel Sector (NAICS 3311, 3312) with Total Energy Input, October 2012 (MECS 2006)

  5. Process for dezincing galvanized steel

    DOE Patents [OSTI]

    Morgan, William A.; Dudek, Frederick J.; Daniels, Edward J.

    1998-01-01

    A process for removing zinc from galvanized steel. The galvanized steel is immersed in an electrolyte containing at least about 15% by weight of sodium or potassium hydroxide and having a temperature of at least about 75.degree. C. and the zinc is galvanically corroded from the surface of the galvanized steel. The material serving as the cathode is principally a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series. The corrosion rate may be accelerated by (i) increasing the number density of corrosion sites in the galvanized steel by mechanically abrading or deforming the galvanized steel, (ii) heating the galvanized steel to form an alloy of zinc on the surface of the galvanized steel, (iii) mixing the galvanized steel with a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series, or (iv) moving the galvanized steel relative to itself and to the electrolyte while immersed in the electrolyte.

  6. High strength, tough alloy steel

    DOE Patents [OSTI]

    Thomas, Gareth; Rao, Bangaru V. N.

    1979-01-01

    A high strength, tough alloy steel is formed by heating the steel to a temperature in the austenite range (1000.degree.-1100.degree. C.) to form a homogeneous austenite phase and then cooling the steel to form a microstructure of uniformly dispersed dislocated martensite separated by continuous thin boundary films of stabilized retained austenite. The steel includes 0.2-0.35 weight % carbon, at least 1% and preferably 3-4.5% chromium, and at least one other substitutional alloying element, preferably manganese or nickel. The austenite film is stable to subsequent heat treatment as by tempering (below 300.degree. C.) and reforms to a stable film after austenite grain refinement.

  7. Process for dezincing galvanized steel

    DOE Patents [OSTI]

    Morgan, W.A.; Dudek, F.J.; Daniels, E.J.

    1998-07-14

    A process is described for removing zinc from galvanized steel. The galvanized steel is immersed in an electrolyte containing at least about 15% by weight of sodium or potassium hydroxide and having a temperature of at least about 75 C and the zinc is galvanically corroded from the surface of the galvanized steel. The material serving as the cathode is principally a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series. The corrosion rate may be accelerated by (1) increasing the number density of corrosion sites in the galvanized steel by mechanically abrading or deforming the galvanized steel, (2) heating the galvanized steel to form an alloy of zinc on the surface of the galvanized steel, (3) mixing the galvanized steel with a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series, or (4) moving the galvanized steel relative to itself and to the electrolyte while immersed in the electrolyte. 1 fig.

  8. Phase I privatization - raw and potable water design requirements document

    SciTech Connect (OSTI)

    Parazin, R.J.

    1996-09-30

    The U.S. Department of Energy has chosen to accomplish the Tank Waste Remediation System disposal mission via privatization. The disposal mission has been divided into two phases. Phase I, a `proof of concept` phase, will establish and demonstrate the technical, commercial, and procurement capabilities necessary for privatization to proceed. Once established on this relatively small scale, privatization will be expanded, through a second competition, in the form of a second phase (Phase II) to dispose of the remainder of the tank waste. The Phase I privatization site will be located in the former Grout Disposal Site area. To prepare the site for use for the private contractors, utilities must be extended from the 200 East Area infrastructure. This document describes the design requirements for the prime water services; i.e raw, fire suppression and sanitary (potable) to be provided to the private contractors. These requirements will be used in directing the conceptual design of these proposed water services.

  9. Improved Martensitic Steel for High Temperature Applications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improved Martensitic Steel for High Temperature Applications A stainless steel composition and heat treatment process for a high-temperature, titanium alloyed 9 Cr-1 molybdenum ...

  10. Mr. Frank Iannizzara Engineering Department Copperweld Steel...

    Office of Legacy Management (LM)

    Frank Iannizzara Engineering Department Copperweld Steel Company 4000 Mahoning Street ... (ORNL) performed a of the Copperweld Steel Company facility in Warren, Ohio. copy of ...

  11. Successful development and application of high performance plate steels

    SciTech Connect (OSTI)

    Wilson, A.D.

    1995-12-31

    New high performance plate steels (HPPS) are developed in reaction to customer requirements and the availability of essential steelmaking facilities. In this decade significant improvements to steelmaking equipment has made possible the development and production of a variety of new HPPS. Four case studies are presented reviewing the key metallurgical needs and the innovative steel processing that was required. These applications include: (1) Hydrogen Induced Cracking Resistant A516 C-Mn pressure vessel steel with ultra low sulfur and controlled carbon equivalent levels, (2) Temper Embrittlement Resistant A387 Cr-Mo alloy steels for high temperature pressure vessels with low phosphorus, J Factor and sulfur levels with high toughness, (3) formable, weldable, 400HB abrasion resistant alloy steels, which are produced with extra low sulfur levels, reduced carbon and carbon equivalent levels and rigorous heat treatment controls, and (4) weldable, high strength structural steels with low carbon levels, based on Cu-Ni precipitation hardening and A710. Future opportunities for HPPS will result with the installation of additional new steelmaking facilities.

  12. Accelerated corrosion of stainless steel in thiocyanate-containing solutions

    SciTech Connect (OSTI)

    Pistorius, P Chris; Li, Wen

    2012-09-19

    (visible as a black corrosion product) forms during anodic dissolution. The sulfide is electronically conductive, and gives an increase of several orders of magnitude in the electrode capacitance; the sulfide also causes anodic activation to persist after the pure metals and steels were removed from the thiocyanate-containing electrolyte and transferred to a thiocyanate-free electrolyte. The main practical implications of this work are that low concentrations of reduced sulfur compounds strongly affect anodic dissolution of stainless steels, and that selecting steels with elevated concentrations of chromium, nickel or molybdenum would serve to limit the anodic dissolution rate in the presence of reduced sulfur compounds.

  13. Recovery of iron, carbon and zinc from steel plant waste oxides using the AISI-DOE postcombustion smelting technology

    SciTech Connect (OSTI)

    Sarma, B.; Downing, K.B.; Aukrust, E.

    1996-09-01

    This report describes a process to recover steel plant waste oxides to be used in the production of hot metal. The process flowsheet used at the pilot plant. Coal/coke breeze and iron ore pellets/waste oxides are charged into the smelting reactor. The waste oxides are either agglomerated into briquettes (1 inch) using a binder or micro-agglomerated into pellets (1/4 inch) without the use of a binder. The iron oxides dissolve in the slag and are reduced by carbon to produce molten iron. The gangue oxides present in the raw materials report to the slag. Coal charged to the smelter is both the fuel as well as the reductant. Carbon present in the waste oxides is also used as the fuel/reductant resulting in a decrease in the coal requirement. Oxygen is top blown through a central, water-cooled, dual circuit lance. Nitrogen is injected through tuyeres at the bottom of the reactor for stirring purposes. The hot metal and slag produced in the smelting reactor are tapped at regular intervals through a single taphole using a mudgun and drill system. The energy requirements of the process are provided by (i) the combustion of carbon to carbon monoxide, referred to as primary combustion and (ii) the combustion of CO and H{sub 2} to CO{sub 2} and H{sub 2}O, known as postcombustion.

  14. Petrochemical feedstock from basic oxygen steel furnace

    SciTech Connect (OSTI)

    Greenwood, C.W.; Hardwick, W.E.

    1983-10-01

    Iron bath gasification in which coal, lime, steam and oxygen are injected into a bath of molten iron for the production of a medium-Btu gas is described. The process has its origin in basic oxygen steelmaking. It operates at high temperatures and is thus not restrictive on the type of coal used. The ash is retained in the slag. The process is also very efficient. The authors suggest that in the present economic climate in the iron and steel industry, such a plant could be sited where existing coal-handling, oxygen and steelmaking equipment are available.

  15. Apparatus and method for production of methanethiol

    DOE Patents [OSTI]

    Agarwal, Pradeep K.; Linjewile, Temi M.; Hull, Ashley S.; Chen, Zumao

    2006-02-07

    A method for the production of methyl mercaptan is provided. The method comprises providing raw feed gases consisting of methane and hydrogen sulfide, introducing the raw feed gases into a non-thermal pulsed plasma corona reactor, and reacting the raw feed gases within the non-thermal pulsed plasma corona reactor with the reaction CH4+H2S.fwdarw.CH3SH+H2. An apparatus for the production of methyl mercaptan using a non-thermal pulsed plasma corona reactor is also provided.

  16. High-Alloy Ferritic Steels: Martensitic Stainless Steels, Precipitatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Metall Trans 12A (1981) 2138-2141. 7. LW Tsay, WC Lee, RK Shiue and JK Wu. Notch tensile properties of laser-surface-annealed 17-4 PH stainless steel in hydrogen-related ...

  17. 2169 steel waveform experiments.

    SciTech Connect (OSTI)

    Furnish, Michael David; Alexander, C. Scott; Reinhart, William Dodd; Brown, Justin L.

    2012-11-01

    In support of LLNL efforts to develop multiscale models of a variety of materials, we have performed a set of eight gas gun impact experiments on 2169 steel (21% Cr, 6% Ni, 9% Mn, balance predominantly Fe). These experiments provided carefully controlled shock, reshock and release velocimetry data, with initial shock stresses ranging from 10 to 50 GPa (particle velocities from 0.25 to 1.05 km/s). Both windowed and free-surface measurements were included in this experiment set to increase the utility of the data set, as were samples ranging in thickness from 1 to 5 mm. Target physical phenomena included the elastic/plastic transition (Hugoniot elastic limit), the Hugoniot, any phase transition phenomena, and the release path (windowed and free-surface). The Hugoniot was found to be nearly linear, with no indications of the Fe - phase transition. Releases were non-hysteretic, and relatively consistent between 3- and 5-mm-thick samples (the 3 mm samples giving slightly lower wavespeeds on release). Reshock tests with explosively welded impactors produced clean results; those with glue bonds showed transient releases prior to the arrival of the reshock, reducing their usefulness for deriving strength information. The free-surface samples, which were steps on a single piece of steel, showed lower wavespeeds for thin (1 mm) samples than for thicker (2 or 4 mm) samples. A configuration used for the last three shots allows release information to be determined from these free surface samples. The sample strength appears to increase with stress from ~1 GPa to ~ 3 GPa over this range, consistent with other recent work but about 40% above the Steinberg model.

  18. Winter urban air particles from Rome (Italy): Effects on the monocytic-macrophagic RAW 264.7 cell line

    SciTech Connect (OSTI)

    Pozzi, Roberta . E-mail: pozzi@iss.it; De Berardis, Barbara; Paoletti, Luigi; Guastadisegni, Cecilia

    2005-11-15

    Epidemiological data show an association between exposure to elevated levels of particulate matter (PM), in particular the fine fraction (<2.5{mu}m in diameter), and an increase in cardiovascular mortality and respiratory symptoms. The aim of this study was to compare the in vitro toxicity of coarse and fine particulate matter collected with a cascade impactor during winter in an urban area of Rome in relation to their physicochemical characterization (size distribution and chemical composition) as assessed by analytical electron microscopy (SEM/EDX). The X-ray microanalysis data of single particles of coarse and fine matter were analyzed by hierarchical cluster analysis to determine the principal component of the two granulometric fractions. The main chemical difference between the two fractions was the greater abundance of carbonaceous particles in the fine fraction. We compared the ability of coarse and fine fractions, carbon black (CB), and residual oil fly ash (ROFA) to induce arachidonic acid release and tumor necrosis factor-{alpha} (TNF-{alpha}) production in the monocytic-macrophagic RAW 264.7 cell line at concentrations of 30 and 120{mu}g/mL. Our results showed that CB and ROFA were consistently less effective than both fractions of urban particles at inducing an inflammatory reaction in RAW 264.7 cells. Both PM fractions dose-dependently increased TNF-{alpha} production in RAW 264.7 cells after 5 and 24h of incubation, and only the TNF-{alpha} production induced by coarse particles at 30{mu}g/mL decreased significantly (P<0.01) after 24h of treatment. In our in vitro model the winter fine fraction was more reactive than the winter coarse fraction, in contrast to a previously examined summer sample. In the summer sample, coarse particles produced higher levels of inflammatory mediators than fine particles and the CB was consistently less effective than the urban particles. The different behaviors between summer and winter urban fractions may be due to

  19. Recovery Act: Waste Energy Project at AK Steel Corporation Middletown

    SciTech Connect (OSTI)

    Joyce, Jeffrey

    2012-06-30

    In 2008, Air Products and Chemicals, Inc. (Air Products) began development of a project to beneficially utilize waste blast furnace topgas generated in the course of the iron-making process at AK Steel Corporations Middletown, Ohio works. In early 2010, Air Products was awarded DOE Assistance Agreement DE-EE002736 to further develop and build the combined-cycle power generation facility. In June 2012, Air Products and AK Steel Corporation terminated work when it was determined that the project would not be economically viable at that time nor in the foreseeable future. The project would have achieved the FOA-0000044 Statement of Project Objectives by demonstrating, at a commercial scale, the technology to capture, treat, and convert blast furnace topgas into electric power and thermal energy.

  20. ITP Steel: Energy Use in the U.S. Steel Industry: An Historical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Use in the U.S. Steel Industry: An Historical Perspective and Future Opportunities, September 2000 ITP Steel: Energy Use in the U.S. Steel Industry: An Historical ...

  1. ITP Steel: Hydrogen and Nitrogen Control in Ladle and Casting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ITP Steel: Hydrogen and Nitrogen Control in Ladle and Casting Operations castingops.pdf (875.11 KB) More Documents & Publications Steel Industry Technology Roadmap ITP Steel: ...

  2. Nano-composite stainless steel (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Nano-composite stainless steel Citation Details In-Document Search Title: Nano-composite stainless steel A composite stainless steel composition is composed essentially of, ...

  3. Auto/Steel Partnership: AHSS Stamping, Strain Rate Characterization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AHSS Stamping, Strain Rate Characterization, Sheet Steel Fatigue, AHSS Joining AutoSteel ... More Documents & Publications AutoSteel Partnership: Fatigue of AHSS Strain Rate ...

  4. Auto/Steel Partnership: Hydroforming Materials and Lubricant...

    Broader source: Energy.gov (indexed) [DOE]

    FY 2008 Progress Report for Lightweighting Materials - 5. Automotive Metals-Steel FY 2009 Progress Report for Lightweighting Materials - 5. Automotive Metals - Steel AutoSteel ...

  5. Hydrogen Embrittlement in Pipeline Steels

    Broader source: Energy.gov (indexed) [DOE]

    Division Material Measurement Laboratory Cheaper vs Safe?: Does it have to be choice * Steel is sold by the ton * X80 costs about the same as a X42ton * Use less X80, therefore ...

  6. Great Lakes Steel -- PCI facility

    SciTech Connect (OSTI)

    Eichinger, F.T.; Dake, S.H.; Wagner, E.D.; Brown, G.S.

    1997-12-31

    This paper discusses the planning, design, and start-up of the 90 tph PCI facility for National Steel`s Great Lakes Steel Division in River Rouge, MI. This project is owned and operated by Edison Energy Services, and was implemented on a fast-track basis by Raytheon Engineers and Constructors, Babcock Material Handling, and Babcock and Wilcox. This paper presents important process issues, basic design criteria, an the challenges of engineering and building a state-of-the-art PCI facility in two existing plants. Pulverized coal is prepared at the River Rouge Power Plant of Detroit Edison, is pneumatically conveyed 6,000 feet to a storage silo at Great Lakes Steel, and is injected into three blast furnaces.

  7. Electrochemical Dezincing of Steel Scrap

    Office of Energy Efficiency and Renewable Energy (EERE)

    Half of the steel produced in the United States is derived from scrap. With zinc-coated prompt scrap increasing fivefold since 1980, steelmakers are feeling the effect of increased contaminant...

  8. Dry film lubricant for difficult drawing applications of galvanized steels

    SciTech Connect (OSTI)

    Wakano, Shigeru; Sakane, Tadashi; Hirose, Yozou . Iron and Steel Research Lab.); Matsuda, Naomichi; Onodera, Show . Oleo Chemicals Research Lab.)

    1993-09-01

    Press formability of metals sheets is considered to depend on surface lubricity, press forming condition and mechanical properties of the metal sheets. In Zn and Zn-alloy plated steel sheets with heavy coatings, surface lubricity is the most important property. This is because the low melting temperature and low hardness of the plated layer occasionally cause microscopic galling through deformation at the beads of dies which may, consequently, result in sheet breakage. Press formability of Zn and Zn-alloy plated steel sheets with heavy coating weight has been improved by the use of a high viscosity lubricant oil and a Fe-Zn alloy flash-plating on galvannealed steel. However, the use of high viscosity lubricant oils created problems with oil staining and removal before painting. An alloy flash plating results in appreciably higher production costs. This article describes the characteristics of a thin film dry lubricant, Super S-coat, as a new countermeasure, which will overcome these problems.

  9. Hydrogen embrittlement of structural steels.

    SciTech Connect (OSTI)

    Somerday, Brian P.

    2010-06-01

    Carbon-manganese steels are candidates for the structural materials in hydrogen gas pipelines, however it is well known that these steels are susceptible to hydrogen embrittlement. Decades of research and industrial experience have established that hydrogen embrittlement compromises the structural integrity of steel components. This experience has also helped identify the failure modes that can operate in hydrogen containment structures. As a result, there are tangible ideas for managing hydrogen embrittement in steels and quantifying safety margins for steel hydrogen containment structures. For example, fatigue crack growth aided by hydrogen embrittlement is a key failure mode for steel hydrogen containment structures subjected to pressure cycling. Applying appropriate structural integrity models coupled with measurement of relevant material properties allows quantification of safety margins against fatigue crack growth in hydrogen containment structures. Furthermore, application of these structural integrity models is aided by the development of micromechanics models, which provide important insights such as the hydrogen distribution near defects in steel structures. The principal objective of this project is to enable application of structural integrity models to steel hydrogen pipelines. The new American Society of Mechanical Engineers (ASME) B31.12 design code for hydrogen pipelines includes a fracture mechanics-based design option, which requires material property inputs such as the threshold for rapid cracking and fatigue crack growth rate under cyclic loading. Thus, one focus of this project is to measure the rapid-cracking thresholds and fatigue crack growth rates of line pipe steels in high-pressure hydrogen gas. These properties must be measured for the base materials but more importantly for the welds, which are likely to be most vulnerable to hydrogen embrittlement. The measured properties can be evaluated by predicting the performance of the pipeline

  10. 2012 ACCOMPLISHMENTS - TRITIUM AGING STUDIES ON STAINLESS STEELS

    SciTech Connect (OSTI)

    Morgan, M.

    2013-01-31

    This report summarizes the research and development accomplishments during FY12 for the tritium effects on materials program. The tritium effects on materials program is designed to measure the long-term effects of tritium and its radioactive decay product, helium-3, on the structural properties of forged stainless steels which are used as the materials of construction for tritium reservoirs. The FY12 R&D accomplishments include: (1) Fabricated and Thermally-Charged 150 Forged Stainless Steel Samples with Tritium for Future Aging Studies; (2) Developed an Experimental Plan for Measuring Cracking Thresholds of Tritium-Charged-and-Aged Steels in High Pressure Hydrogen Gas; (3) Calculated Sample Tritium Contents For Laboratory Inventory Requirements and Environmental Release Estimates; (4) Published report on Cracking Thresholds and Fracture Toughness Properties of Tritium-Charged-and-Aged Stainless Steels; and, (5) Published report on The Effects of Hydrogen, Tritium, and Heat Treatment on the Deformation and Fracture Toughness Properties of Stainless Steels. These accomplishments are highlighted here and references given to additional reports for more detailed information.

  11. Advanced steel reheat furnaces: Research and development. Final report

    SciTech Connect (OSTI)

    Nguyen, Q.; Koppang, R.; Maly, P.; Moyeda, D.; Li, X.

    1999-01-14

    The purpose of this report is to present the results of two phases of a three-phase project to develop and evaluate an Advanced Steel Reheat Furnace (SSRF) concept which incorporates two proven and commercialized technologies, oxy-fuel enriched air (OEA) combustion and gas reburning (GR). The combined technologies aim to improve furnace productivity with higher flame radiant heat transfer in the heating zones of a steel reheat furnace while controlling potentially higher NOx emissions from these zones. The project was conducted under a contract sponsored by the Department of Energy (DOE). Specifically, this report summarizes the results of a modeling study and an experimental study to define and evaluate the issues which affect the integration and performance of the combined technologies. Section 2.0 of the report describes the technical approach uses in the development and evaluation of the advanced steel reheat furnace. Section 3.0 presents results of the modeling study applied to a model steel furnace. Experimental validation of the modeling results obtained from EER`s Fuel Evaluation Facility (FEF) pilot-scale furnace discussed in Section 4.0. Section 5.0 provides an economic evaluation on the cost effectiveness of the advanced reheat furnace concept. Section 6.0 concludes the report with recommendations on the applicability of the combined technologies of steel reheat furnaces.

  12. Micro-alloying of steels. February 1977-April 1989 (Citations from the COMPENDEX data base). Report for February 1977-April 1989

    SciTech Connect (OSTI)

    Not Available

    1989-04-01

    This bibliography contains citations concerning production techniques, performance, and applications of microalloyed steels. Various microalloying materials are examined including niobium, vanadium, titanium, niobium/vanadium, aluminum, boron, molybdenum, and zirconium. Microalloying effects on the mechanical properties, corrosion resistance, metallurgical properties, and hot plasticity of steels are presented. Applications of microalloyed steels in the construction-steel industry, physical properties of microalloyed steels, low-temperature service behavior, weldability, formability, and resistance to corrosion are discussed. (Contains 81 citations fully indexed and including a title list.)

  13. Validation of Innovative Exploration Technologies for Newberry Volcano: Seismic data - raw taken by Apex Hipoint for 1st test 2012

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jaffe, Todd

    2012-01-01

    Validation of Innovative Exploration Technologies for Newberry Volcano: Seismic data - raw taken by Apex Hipoint for 1st test 2012

  14. Validation of Innovative Exploration Technologies for Newberry Volcano: Seismic data - raw taken by Apex Hipoint for 1st test 2012

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jaffe, Todd

    Validation of Innovative Exploration Technologies for Newberry Volcano: Seismic data - raw taken by Apex Hipoint for 1st test 2012

  15. Validation of Innovative Exploration Technologies for Newberry Volcano: Raw data used to prepare the Gravity Report by Zonge 2012

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jaffe, Todd

    Validation of Innovative Exploration Technologies for Newberry Volcano: Raw data used to prepare the Gravity Report by Zonge 2012

  16. Validation of Innovative Exploration Technologies for Newberry Volcano: Raw data used to prepare the Gravity Report by Zonge 2012

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jaffe, Todd

    2012-01-01

    Validation of Innovative Exploration Technologies for Newberry Volcano: Raw data used to prepare the Gravity Report by Zonge 2012

  17. H-Series Cast Austenitic Stainless Steels

    Broader source: Energy.gov [DOE]

    Cast H-Series austenitic steels are used extensively in several industries for a broad range of high-temperature applications. The H-Series stainless steels have evolved over many years of complex...

  18. CORROSIVITY AND COMPOSITION OF RAW AND TREATED PYROLYSIS OILS

    SciTech Connect (OSTI)

    Keiser, Jim; Howell, Michael; Connatser, Raynella M.; Lewis, Sam; Elliott, Douglas C.

    2012-10-14

    Fast pyrolysis offers a relatively low cost method of processing biomass to produce a liquid product that has the potential for conversion to several types of liquid fuels. The liquid product of fast pyrolysis, known as pyrolysis oil or bio-oil, contains a high oxygen content primarily in the form of water, carboxylic acids, phenols, ketones and aldehydes. These oils are typically very acidic with a Total Acid Number that is often in the range of 50 to 100, and previous studies have shown this material to be quite corrosive to common structural materials. Removal of at least some of the oxygen and conversion of this oil to a more useful product that is considerably less corrosive can be accomplished through a hydrogenation process. The product of such a treatment is considered to have the potential for blending with crude oil for processing in petroleum refineries. Corrosion studies and chemical analyses have been conducted using as produced bio-oil samples as well as samples that have been subjected to different levels of oxygen removal. Chemical analyses show treatment affected the concentrations of carboxylic acids contained in the oil, and corrosion studies showed a positive benefit of the oxygen removal. Results of these studies will be presented in this paper.

  19. OSTIblog Articles in the raw data Topic | OSTI, US Dept of Energy Office of

    Office of Scientific and Technical Information (OSTI)

    Scientific and Technical Information raw data Topic Open Science: the Case for Preserving Raw Data by Dr. Jeffrey Salmon 12 Jul, 2011 in Technology Everyone speaks well of the idea that the results of scientific research should be open for all to see, although there are obvious caveats to complete openness: Proprietary research, human subjects research, preliminary results, the pace and timing for releasing results, all come to mind. But when it comes to research funded by the taxpayer, open

  20. Cast CF8C-Plus Stainless Steel for Turbocharger Applications

    SciTech Connect (OSTI)

    Maziasz, P.J.; Shyam, A.; Evans, N.D.; Pattabiraman, K. (Honeywell Turbo Technologies

    2010-06-30

    The purpose of this Cooperative Research and Development Agreement (CRADA) project is to provide the critical test data needed to qualify CF8C-Plus cast stainless steel for commercial production and use for turbocharger housings with upgraded performance and durability relative to standard commercial cast irons or stainless steels. The turbocharger technologies include, but are not limited to, heavy-duty highway diesel engines, and passenger vehicle diesel and gasoline engines. This CRADA provides additional critical high-temperature mechanical properties testing and data analysis needed to quality the new CF8C-Plus steels for turbocharger housing applications.

  1. Mechanism of biocorrosion of low-alloy steel in a thionic bacteria medium

    SciTech Connect (OSTI)

    Baru, R.L.; Starosvetskaya, Z.O.; Timonin, V.A.

    1986-07-01

    This paper models the process of biocorrosion of Armco iron,low alloy steel 10KhSND (0.69 mass % Ni, 0.7 Cr, 0.55 Cu), and also alloys of Armco iron with chromium, copper, and nickel in concentrations corresponding to the level of their content in steel (of order 0.7%) in a medium of the thionic bacteria of the form Thiobacillus thiooxidans. Biocorrosion of metals inflicts losses on systems of water supply and recirculation in industrial plants, in the oil and gas industry, and in hydraulic structures. Investigations of the surface composition of the steel with the aid of a Cameca scanning electron microanalyzer and analysis of the corrosion products by the atomic absorption method revealed that, in contrast with the model, in the culture liquid the surface of steel 10KhSND and its corrosion products are depleted of nickel.

  2. ITP Steel: Steel Industry Marginal Opportunity Study September 2005

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steel Industry Marginal Opportunity Study Energetics, Inc. for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Industrial Technologies Program September 2005 1 Table of Contents Introduction.....................................................................................................................- 1 - Ore-Based Steelmaking: Bandwidth and Opportunities................................................- 3 - EAF Steelmaking: Bandwidth and

  3. Relationship between Material Properties and Local Formability of DP980 Steels

    SciTech Connect (OSTI)

    Choi, Kyoo Sil; Soulami, Ayoub; Li, Dongsheng; Sun, Xin; Khaleel, Mohammad A.; Xu, Le; Barlat, Frederic

    2012-04-24

    A noticeable degree of inconsistent forming behaviors has been observed for the 1st generation advanced high strength steels (AHSS) in production, and they appear to be associated with the inherent microstructural-level inhomogeneities for various AHSS. This indicates that the basic material property requirements and screening methods currently used for the mild steels and high strength low alloys (HSLA) are no longer sufficient for qualifying today’s AHSS. In order to establish more relevant material acceptance criteria for AHSS, the fundamental understandings on key mechanical properties and microstructural features influencing the local formability of AHSS need to be developed. For this purpose, in this study, DP980 was selected as model steels and eight different types of DP980 sheet steels were acquired from various steel suppliers. Various experiments were then performed on the eight different DP980 steels such as chemical composition analysis, static tensile test, hole expansion test, channel forming test. Scanning electron microscope (SEM) pictures of the DP980 steels were also obtained, and image processing tools were then adopted to those SEM pictures in order to quantify their various microstructural features. The results show that all DP980 steels show large discrepancy in their performance and that the tensile properties and hole expansion properties of these steels do not correlate with their local formability. According to the results up to date, it is not possible to correlate the microstructural features alone to the macroscopically measured deformation behaviors. In addition to image analysis, other experiments (i.e., nano-indentation test) are also planned to quantify the individual phase properties of the various DP steels.

  4. Bearing steels 20/20 -- A steelmaker`s view point -- A look back 20 years and a look forward 20 years

    SciTech Connect (OSTI)

    Glasgal, B.M.

    1998-12-31

    Historically, bearing steels have been manufactured using clean steel technology to produce a product that has reduced levels of non-metallic inclusions. Included in this review are the key steel production practices that have evolved over time to make steels with superior cleanliness. The evolution of steelmaking practices over the past twenty years has also given rise to more discriminating test and evaluation methods. The types of testing reviewed here include microscopic examination, oxygen analysis, and various types of fatigue testing. Further improvements in steelmaking technology in the future, such as the increased usage of continuous casting, are expected to result in further quality improvements.

  5. Today`s steel technology

    SciTech Connect (OSTI)

    1996-01-01

    AISI members have made significant advances in steelmaking technology over the past several years. This report details the alloy developments and processes that have made steel an engineered material suitable for an expanding range of applications. Improved processes involve casting, rolling, welding, forging, chemical composition and computerized control. Applications cover a broad range including automobile, buildings and bridges.

  6. Wrought Cr--W--V bainitic/ferritic steel compositions

    DOE Patents [OSTI]

    Klueh, Ronald L.; Maziasz, Philip J.; Sikka, Vinod Kumar; Santella, Michael L.; Babu, Sudarsanam Suresh; Jawad, Maan H.

    2006-07-11

    A high-strength, high-toughness steel alloy includes, generally, about 2.5% to about 4% chromium, about 1.5% to about 3.5% tungsten, about 0.1% to about 0.5% vanadium, and about 0.05% to 0.25% carbon with the balance iron, wherein the percentages are by total weight of the composition, wherein the alloy is heated to an austenitizing temperature and then cooled to produce an austenite transformation product.

  7. Assessing Steel Pipeline and Weld Susceptibility to Hydrogen Embrittlement Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessing Steel Pipeline and Weld Susceptibility to Hydrogen Embrittlement U.S. Department of Energy Fuel Cell Technologies Office January 12 th , 2016 Presenters: Joe Ronevich (presenter) and Brian Somerday Sandia National Laboratories DOE Host: Neha Rustagi - Technology Manager, Hydrogen Production and Delivery Program 2 | Fuel Cell Technologies Office eere.energy.gov Question and Answer * Please type your questions into the question box 2 3 | Fuel Cell Technologies Office eere.energy.gov

  8. Weirton Steel Corporation logistics and integrated scheduling. Final report

    SciTech Connect (OSTI)

    Guzzetta, M.B.

    1996-06-01

    In order to remain competitive in the changing steel market, US steel producers restructured by taking on foreign and domestic partners, closing facilities and/or trimming work forces, and modernizing their steel making facilities. However, very little was done to develop production management technology to complement these changes. The Logistics and Integrated Scheduling program (LIS) was undertaken to address this issue. LIS is an information management system that delivers better customer service, better quality materials, and a just-in-time delivery system. It involves three major components: (1) material marking and sensing: advanced R&D applied to determining cost effective, feasible solutions to passive inventory; (2) material inventory and tracking: advanced technology applied to managing inventory movement; (3) planning and scheduling: beginning with annual production plans, order management, and operational constraints, the ability to build integrated schedules capable of pull through and push through scheduling for various plant capability levels and location configurations with rapid turnaround capability. LIS provides accurate, automated tracking of material flows throughout the mill, the collection and analysis of production data, and automated schedule optimization.

  9. EIA's Natural Gas Production Data

    Reports and Publications (EIA)

    2009-01-01

    This special report examines the stages of natural gas processing from the wellhead to the pipeline network through which the raw product becomes ready for transportation and eventual consumption, and how this sequence is reflected in the data published by the Energy Information Administration (EIA).

  10. Final Scientific Report - "Novel Steels for High Temperature Carburizing"

    SciTech Connect (OSTI)

    McKimpson, Marvin G.; Liu, Tianjun; Maniruzzaman, Md

    2012-07-27

    This program was undertaken to develop a microalloy-modified grade of standard carburizing steel that can successfully exploit the high temperature carburizing capabilities of current commercial low pressure (i.e. 'vacuum') carburizing systems. Such steels can lower the amount of energy required for commercial carburizing operations by reducing the time required for deep-case carburizing operations. The specific technical objective of the work was to demonstrate a carburizing steel composition capable of maintaining a prior austenite grain size no larger than ASTM grain size number 5 after exposure to simulated carburizing conditions of 1050 C for 8 hr. Such thermal exposure should be adequate for producing carburized case depths up to about 2 mm. Such carburizing steels are expected to be attractive for use across a wide range of industries, including the petroleum, chemical, forest products, automotive, mining and industrial equipment industries. They have potential for reducing energy usage during low pressure carburizing by more than 25%, as well as reducing cycle times and process costs substantially. They also have potential for reducing greenhouse gas emissions from existing low pressure carburizing furnaces by more than 25%. High temperature carburizing can be done in most modern low pressure carburizing systems with no additional capital investment. Accordingly, implementing this technology on carburizing furnaces will provide a return on investment significantly greater than 10%. If disseminated throughout the domestic carburizing community, the technology has potential for saving on the order of 23 to 34 trillion BTU/year in industrial energy usage. Under the program, two compositions of microalloyed, coarsening-resistant low alloy carburizing steels were developed, produced and evaluated. After vacuum annealing at 1050oC for 8 hrs and high pressure gas quenching, both steels exhibited a prior austenite ASTM grain size number of 5.0 or finer. For

  11. DOE - Office of Legacy Management -- Sutton Steele and Steele Co - TX 09

    Office of Legacy Management (LM)

    Sutton Steele and Steele Co - TX 09 FUSRAP Considered Sites Site: SUTTON, STEELE & STEELE CO. (TX.09) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Sutton, Steele & Steele, Inc. TX.09-1 Location: Dallas , Texas TX.09-1 Evaluation Year: 1993 TX.09-2 Site Operations: Conducted operations to separate Uranium shot by means of air float tables and conducted research to air classify C-Liner and C-Special materials. TX.09-1 TX.09-3 TX.09-4 TX.09-5

  12. Steel project fact sheet: Steel reheating for further processing

    SciTech Connect (OSTI)

    1998-04-01

    Steel reheating is an energy-intensive process requiring uniform temperature distribution within reheating furnaces. Historically, recuperators have ben used to preheat combustion air, thereby conserving energy. More recent innovations include oxygen enrichment and the use of regenerative burners, which provide higher preheat air temperatures than recuperators. These processes have limitations such as equipment deterioration, decreasing energy efficiency over time, high maintenance costs, and increased NO{sub x} emissions with increased air preheat temperature, unless special equipment is used. Praxair, Inc., supplier of oxygen and other industrial gases to the steel industry, proposes to introduce an innovative oxy-fuel burner technology (using 100% oxygen) to the steel reheating industry. Oxy-fuel combustion reduces or eliminates nitrogen in combustion air and substantially reduces waste heat carried out with flue gas. Based on technology currently used in the glass, hazardous waste, and aluminum industries, Praxair has developed and patented low temperature, oxy-fuel burners that can be used in high temperature industrial furnaces where temperature uniformity is critical and extremely low NO{sub x} emissions are desired. The technical goal of the project is to demonstrate the use of oxy-fuel burners in a slab reheat furnace while reducing energy consumption by 45% and NO{sub x} emissions by 90% within the converted furnace zones. Successful implementation of this technology also will eliminate the need to periodically replace recuperators and install NO{sub x} removal equipment.

  13. Steel Industry Energy Bandwidth Study

    SciTech Connect (OSTI)

    none,

    2004-10-01

    ITP conducted a study on energy use and potential savings, or "bandwidth" study, in major steelmaking processes. Intended to provide a realistic estimate of the potential amount of energy that can be saved in an industrial process, the "bandwidth" refers to the difference between the amount of energy that would be consumed in a process using commercially available technology versus the minimum amount of energy needed to achieve those same results based on the 2nd law of thermodynamics. The Steel Industry Energy Bandwidth Study (PDF133 KB) also estimates steel industry energy use in the year 2010, and uses that value as a basis for comparison against the minimum requirements. This energy savings opportunity for 2010 will aid focus on longer term R&D.

  14. Characterization of modified 9 Cr-1 Mo steel extruded pipe

    SciTech Connect (OSTI)

    Sikka, V.K.; Hart, M.D.

    1985-04-01

    The fabrication of hot-extruded pipe of modified 9 Cr-1 Mo steel at Cameron Iron Works is described. The report also deals with the tempering response; tensile, Charpy impact, and creep properties; and microstructure of the hot-extruded pipe. The tensile properties of the pipe are compared with the average and average -1.65 standard error of estimate curves for various product forms of several commercial heats of this alloy. The creep-rupture properties are compared with the average curve for various product forms of the commercial heats.

  15. Nano-composite stainless steel

    SciTech Connect (OSTI)

    Dehoff, Ryan R.; Blue, Craig A.; Peter, William H.; Chen, Wei; Aprigliano, Louis F.

    2015-07-14

    A composite stainless steel composition is composed essentially of, in terms of wt. % ranges: 25 to 28 Cr; 11 to 13 Ni; 7 to 8 W; 3.5 to 4 Mo; 3 to 3.5 B; 2 to 2.5 Mn; 1 to 1.5 Si; 0.3 to 1.7 C; up to 2 O; balance Fe. The composition has an austenitic matrix phase and a particulate, crystalline dispersed phase.

  16. Steel Industry Marginal Opportunity Analysis

    SciTech Connect (OSTI)

    none,

    2005-09-01

    The Steel Industry Marginal Opportunity Analysis (PDF347 KB) identifies opportunities for developing advanced technologies and estimates both the necessary funding and the potential payoff. This analysis determines what portion of the energy bandwidth can be captured through the adoption of state-of-the-art technology and practices. R&D opportunities for addressing the remainder of the bandwidth are characterized and plotted on a marginal opportunity curve.

  17. Corrosion of chromium-coated steel in sodium polysulfide environments. Final report

    SciTech Connect (OSTI)

    Wicker, A.

    1983-03-01

    This project had the broad objective of evaluating the behavior of certain chromium-rich coatings on low-carbon steel in sodium polysulfide environments typical of those found in sodium-sulfur cells. Raw materials were characterized before coating, and three values of carbon content were chosen: 0.013% (Armco iron), 0.088% (XC10 steel) and 0.22% (XC12 steel). Three types of coating were examined (i) chromized in three thicknesses (30, 60 and 90 ..mu..m), (ii) chromium electroplating in three thicknesses (50, 100 and 200 ..mu..m) and (iii) chromium electroplating followed by a diffusion step at higher temperature (around 1000/sup 0/C) in three thicknesses (50, 100 and 200 ..mu..m). The various coatings were characterized with regards to microstructure, hardness, and concentration profile of chromium. A corrosion cell for static test was designed consisting of the sulfur compartment of a large Na-S cell. Five test furnaces at different temperature were used (300 - 325 - 350 - 400 and 440/sup 0/C). Test durations were in the range of 3 to 12 months. Dynamic tests were made using sodium-sulfur cells and special cells without a polysulfide environment. All the above tests have shown that chromizing is suitable for working temperatures below 350/sup 0/C. For higher temperatures, chromium electroplating followed by a diffusion step exhibits satisfactory behavior.

  18. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L.

    1995-12-01

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  19. Corrosion behavior of stainless steel-zirconium alloy waste forms.

    SciTech Connect (OSTI)

    Abraham, D. P.

    1999-01-13

    Stainless steel-zirconium (SS-Zr) alloys are being considered as waste forms for the disposal of metallic waste generated during the electrometallurgical treatment of spent nuclear fuel. The baseline waste form for spent fuels from the EBR-II reactor is a stainless steel-15 wt.% zirconium (SS-15Zr) alloy. This article briefly reviews the microstructure of various SS-Zr waste form alloys and presents results of immersion corrosion and electrochemical corrosion tests performed on these alloys. The electrochemical tests show that the corrosion behavior of SS-Zr alloys is comparable to those of other alloys being considered for the Yucca Mountain geologic repository. The immersion tests demonstrate that the SS-Zr alloys are resistant to selective leaching of fission product elements and, hence, suitable as candidates for high-level nuclear waste forms.

  20. Distribution of radionuclides during melting of carbon steel

    SciTech Connect (OSTI)

    Thurber, W.C.; MacKinney, J.

    1997-02-01

    During the melting of steel with radioactive contamination, radionuclides may be distributed among the metal product, the home scrap, the slag, the furnace lining and the off-gas collection system. In addition, some radionuclides will pass through the furnace system and vent to the atmosphere. To estimate radiological impacts of recycling radioactive scrap steel, it is essential to understand how radionuclides are distributed within the furnace system. For example, an isotope of a gaseous element (e.g., radon) will exhaust directly from the furnace system into the atmosphere while a relatively non-volatile element (e.g., manganese) can be distributed among all the other possible media. This distribution of radioactive contaminants is a complex process that can be influenced by numerous chemical and physical factors, including composition of the steel bath, chemistry of the slag, vapor pressure of the particular element of interest, solubility of the element in molten iron, density of the oxide(s), steel melting temperature and melting practice (e.g., furnace type and size, melting time, method of carbon adjustment and method of alloy additions). This paper discusses the distribution of various elements with particular reference to electric arc furnace steelmaking. The first two sections consider the calculation of partition ratios for elements between metal and slag based on thermodynamic considerations. The third section presents laboratory and production measurements of the distribution of various elements among slag, metal, and the off-gas collection system; and the final section provides recommendations for the assumed distribution of each element of interest.

  1. Auto industry steel project to boost efficiency, safety

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Auto industry steel project to boost efficiency, safety Auto industry steel project to boost efficiency, safety Higher-strength, lighter-weight steels could be coming to a car near ...

  2. Reliability study: raw and make-up water system, Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Peterman, S.M.; Wiehle, W.E.; Walder, A.; Houk, T.C.; West, R.M.

    1981-09-01

    A reliability study for determining the ability of the raw and make-up water system to provide reliable and adequate service through the year 2000 has been completed. This study includes an evaluation of the well fields, X-608 Raw Water Pump House, X-605 Booster Station Complex, X-611 Water Treatment Complex, and the associated piping. The raw and make-up water system is in good overall condition, but to maintain this condition, the reliability study team made the following recommendations: (1) increase well field capacity; (2) replace certain speed reducers at X-611; (3) repair deteriorated poles, crossarms, and accessories on F-2 and W-1 feeders; (4) stabilize the landslide in vicinity of the 48 in. raw water main; and (5) initiate further investigation, testing, or engineering studies to correct deficiencies in the supervisory control system between well fields, pump house, and X-611, determine if the 2400 volt underground cables to X-608A wells should be replaced.

  3. Blast furnace gas fired boiler for Eregli Iron and Steel Works (Erdemir), Turkey

    SciTech Connect (OSTI)

    Green, J.; Strickland, A.; Kimsesiz, E.; Temucin, I.

    1996-11-01

    Eregli Demir ve Celik Fabriklari T.A.S. (Eregli Iron and Steel Works Inc.), known as Erdemir, is a modern integrated iron and steel works on the Black Sea coast of Turkey, producing flat steel plate. Facilities include two blast furnaces, coke ovens, and hot and cold rolling mills, with a full supporting infrastructure. Four oil- and gas-fired steam boilers provide steam for electric power generation, and to drive steam turbine driven fans for Blast Furnace process air. Two of these boilers (Babcock and Wilcox Type FH) were first put into operation in 1965, and still reliably produce 100 tons/hour of steam at a pressure of 44 bar and a temperature of 410 C. In 1989 Erdemir initiated a Capacity Increase and Modernization Project to increase the steel production capability from two million to three million tons annually. This project also incorporates technology to improve the product quality. Its goals include a reduction in energy expenses to improve Erdemir`s competitiveness. The project`s scheduled completion is in late 1995. The by-product gases of the blast furnaces, coke ovens, and basic oxygen furnaces represent a considerable share of the consumed energy in an integrated iron and steel works. Efficient use of these fuels is an important factor in improving the overall efficiency of the operation.

  4. Iron and Steel (2010 MECS) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Iron and Steel (2010 MECS) Iron and Steel (2010 MECS) Manufacturing Energy and Carbon Footprint for Iron and Steel Sector (NAICS 3311, 3312) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014 View footprints for other sectors here. Manufacturing Energy and Carbon Footprint Iron and Steel (125.81 KB) More Documents & Publications MECS 2006 - Iron and Steel Manufacturing Energy and Carbon Footprint - Sector: Iron and Steel (NAICS 3311, 3312), October

  5. Lessons Learned from Raw Treatment in the Slovak Republic - Minimization for Final Disposal

    SciTech Connect (OSTI)

    Hanusik, V.; Hladky, E.; Krajc, T.; Pekar, A.; Stubna, M.; Urbanec, M. [Milan Zatkulak, VUJE, a.s., Trnava (Slovakia); Ehn, L.; Kover, M.; Remias, V.; Slezak, M. [JAVYS, a.s., Bohunice (Slovakia)

    2008-07-01

    This paper is referring about the utilization of technologies for the treatment and conditioning of low and intermediate level RAW from operation and decommissioning of nuclear facilities in Slovakia. This experience represents more than 116 reactor years of NPP operation, mainly of NPPs equipped with VVER 440 reactors, 30 years of decommissioning activities, 27 years of development and operation of technologies for the treatment and conditioning of RAW and 7 years of LLW and ILW final repository operation. These technologies are located in two localities: Jaslovske Bohunice and Mochovce. The complex treatment and conditioning center (cementation, bituminization, incineration, vitrification, fragmentation and compacting) for almost all types of radioactive waste is located in Jaslovske Bohunice NPP site. The treatment and conditioning center for liquid radioactive waste (cementation and bituminization) and the surface type repository for LLW and ILW final disposal are located in Mochovce area. The treated waste forms are disposed to repository in cubical Fiber Reinforced Concrete (FRC) containers. The experience from the phase of technology development and the phase of technology modifications for various types of RAW, the experience from long term operation of technologies and the experience from transportation of original and packed wastes are described in this paper. The method of optimally combined technology utilization in order to maximize the radionuclide inventory at the same time with respect of disposal safety limitations of repository is described, too. The significant RAW volume reduction for final disposal was achieved through mediation of the combination of treatment and conditioning technologies. The disposal of treated RAW in cubic FRC containers allowed the optimal utilization of volume and radiological capacity of LLW and ILW repository in Mochovce and the fulfillment of determined safety requirements at the same time. (authors)

  6. Multi-component Cu-Strengthened Steel Welding Simulations: Atom...

    Office of Scientific and Technical Information (OSTI)

    Steel Welding Simulations: Atom Probe Tomography and Synchrotron X-ray Diffraction Analyses Citation Details In-Document Search Title: Multi-component Cu-Strengthened Steel Welding ...

  7. NanoComposite Stainless Steel Powder Technologies (Technical...

    Office of Scientific and Technical Information (OSTI)

    NanoComposite Stainless Steel Powder Technologies Citation Details In-Document Search Title: NanoComposite Stainless Steel Powder Technologies You are accessing a document from ...

  8. Post-Test Metallurgical Evaluation Results for Steel Containment...

    Office of Scientific and Technical Information (OSTI)

    Results for Steel Containment Vessel (SCV) High Pressure Test Citation Details In-Document Search Title: Post-Test Metallurgical Evaluation Results for Steel Containment ...

  9. Hydrogen Assisted Fracture of Stainless Steels (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Hydrogen Assisted Fracture of Stainless Steels Citation Details In-Document Search Title: Hydrogen Assisted Fracture of Stainless Steels You are accessing a ...

  10. 2169 steel waveform experiments. (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: 2169 steel waveform experiments. Citation Details In-Document Search Title: 2169 steel waveform experiments. In support of LLNL efforts to develop multiscale ...

  11. Steele Hot Springs Pool & Spa Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Hot Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Steele Hot Springs Pool & Spa Low Temperature Geothermal Facility Facility Steele Hot...

  12. Hydrogen Assisted Fracture of Stainless Steels (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Hydrogen Assisted Fracture of Stainless Steels Citation Details In-Document Search Title: Hydrogen Assisted Fracture of Stainless Steels Abstract not provided. Authors: Somerday,...

  13. Hydrogen Assisted Fracture of Stainless Steels (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Hydrogen Assisted Fracture of Stainless Steels Citation Details In-Document Search Title: Hydrogen Assisted Fracture of Stainless Steels You are accessing a document from the...

  14. DOE - Office of Legacy Management -- American Steel Foundries...

    Office of Legacy Management (LM)

    Steel Foundries Elmes-King Div - OH 36 FUSRAP Considered Sites Site: American Steel Foundries Elmes-King Div (OH.36 ) Eliminated from consideration under FUSRAP Designated Name: ...

  15. DOE - Office of Legacy Management -- Wyckoff Steel Co - NJ 20

    Office of Legacy Management (LM)

    Steel Co - NJ 20 FUSRAP Considered Sites Site: Wyckoff Steel Co (NJ 20) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: ...

  16. Auto/Steel Partnership: Fatigue of AHSS Strain Rate Characterization...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications AutoSteel Partnership: AHSS Stamping, Strain Rate Characterization, Sheet Steel Fatigue, AHSS Joining FY 2009 Progress Report for Lightweighting ...

  17. DOE - Office of Legacy Management -- Copperweld Steel Co - OH...

    Office of Legacy Management (LM)

    Copperweld Steel Co - OH 33 FUSRAP Considered Sites Site: COPPERWELD STEEL CO. (OH.33 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate ...

  18. Decorative Steel Composition with a Crystalline Surface - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Decorative Steel Composition with a Crystalline ... Technology Marketing SummaryA method for producing a new decorative steel with a ...

  19. COLLOQUIUM: How Trenton Iron and Steel Innovations Reshaped America...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MBG Auditorium COLLOQUIUM: How Trenton Iron and Steel Innovations Reshaped America Mr. Clifford Zink Independent Historian Iron and steel innovations in Trenton helped transform ...

  20. DOE - Office of Legacy Management -- Carpenter Steel Co - PA...

    Office of Legacy Management (LM)

    Carpenter Steel Co - PA 12 FUSRAP Considered Sites Site: Carpenter Steel Co. (PA.12 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate ...

  1. SURVEY OF ROLLING MILL USED BY BETHLEHEM STEEL CORPORATION LACKAWANNA...

    Office of Legacy Management (LM)

    SURVEY OF ROLLING MILL USED BY BETHLEHEM STEEL CORPORATION LACKAWANNA, NEW YORK Work ... SURVEY OF ROLLING MILL USED BY BETHLEHEM STEEL CORPORATION LACKAWANNA, NEW YORK A ...

  2. Stainless Steel Hotplate Heater for Long Objects --- Inventor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stainless Steel Hotplate Heater for Long Objects --- Inventor(s): Stephan Jurczynski and ... High electrical current is passed through a stainless steel plate longer and slightly ...

  3. DOE - Office of Legacy Management -- Bethlehem Steel Corporation...

    Office of Legacy Management (LM)

    Bethlehem Steel Corporation - NY 02 FUSRAP Considered Sites Site: BETHLEHEM STEEL CORPORATION (NY.02 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated ...

  4. DOE - Office of Legacy Management -- Jessop Steel Co - PA 17

    Office of Legacy Management (LM)

    Jessop Steel Co - PA 17 FUSRAP Considered Sites Site: JESSOP STEEL CO. (PA.17 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: ...

  5. PRELIMINARY SURVEY OF AL-TECH SPECIALTY STEEL CORPORATION WATERVLIET...

    Office of Legacy Management (LM)

    . PRELIMINARY SURVEY OF AL-TECH SPECIALTY STEEL CORPORATION WATERVLIET, NEW YORK Work ... I . . . .*l-..l- . ..-.-- - - - - .-- AL-TECH SPECIALTY STEEL CORPORATION ...

  6. Assessing Steel Pipeline and Weld Susceptibility to Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    Office webinar "Assessing Steel Pipeline and Weld Susceptibility to Hydrogen Embrittlement" held on January 12, 2016. Assessing Steel Pipeline and Weld Susceptibility to ...

  7. Post Irradiation Examination of Stainless Steel Cladding from...

    Office of Environmental Management (EM)

    Post Irradiation Examination of Stainless Steel Cladding from In-Reactor Permeation Experiment Post Irradiation Examination of Stainless Steel Cladding from In-Reactor Permeation ...

  8. Corrosion Testing of Carbon Steel in Acid Cleaning Solutions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technical Report: Corrosion Testing of Carbon Steel in Acid Cleaning Solutions Citation Details In-Document Search Title: Corrosion Testing of Carbon Steel in Acid Cleaning ...

  9. Improved Processing of High Alloy Steels for Wear Components...

    Office of Scientific and Technical Information (OSTI)

    Steels for Wear Components in Energy Generation Systems, Transportation and ... Title: Improved Processing of High Alloy Steels for Wear Components in Energy Generation ...

  10. A review and update of advancements in clean cast steel technology

    SciTech Connect (OSTI)

    Blair, M.; Monroe, R.W.; Griffin, J.A.

    1999-07-01

    The Steel Founders' Society of America Quality Assurance Task Force identified oxide macroinclusions as a universal problem experienced by users of steel castings. SFSA along with the Department of Commerce and the Department of Energy have sponsored research directed at reducing the occurrence of macroinclusions in steel castings. The Clean Cast Steel Technology program has investigated melting practice, pouring practice, gating practice, ladle treatment, and special devices such as filtration and analog simulation of mold pouring and filling. In-plant trials have demonstrated a dramatic improvement in casting quality with submerged pouring of steel castings. Research is currently underway in optimizing foundry melting practice to reduce macroinclusions. A 30--50% reduction in macroinclusion occurrence has been observed in production castings at the foundries participating in the trials. Analog simulation and in-plant trials of pouring practices have demonstrated that poor gating practice can increase air entrainment and oxide inclusions. Ladle treatments such as calcium wire injection has been demonstrated in plant trials to significantly reduce oxide defects in steel castings. Experiments have been conducted at participating foundries to examine the benefits of filtration on casting quality. Filtration has been shown to reduce rework and scrap by 70% in some cases.

  11. Clean steel technology -- Fundamental to the development of high performance steels

    SciTech Connect (OSTI)

    Wilson, A.D.

    1999-07-01

    The use of clean steel technology (low sulfur with calcium treatment for inclusion shape control) is a fundamental building block in the development of high performance plate steels. A brief review will be presented of the benefits of calcium treatment and its effect on non-metallic inclusions (sulfides and oxides) and reducing sulfur levels. During the past thirty years the requirements for low sulfur levels have been reduced from 0.010% maximum to 0.001% maximum. The effects of clean steel practices on specific properties will be reviewed including tensile ductility, Charpy V-notch and fracture toughness, fatigue crack propagation and hydrogen-induced-cracking resistance. Traditional low sulfur plate steel applications have included pressure vessels. offshore platforms, plastic injection molds and line-pipe skelp. More recent applications will be discussed including bridge steels, high strength structural steels to 130 ksi (897 MPa) minimum yield strength, 9% nickel steels for cryogenic applications, and military armor.

  12. METHOD FOR JOINING ALUMINUM TO STAINLESS STEEL

    DOE Patents [OSTI]

    Lemon, L.C.

    1960-05-24

    Aluminum may be joined to stainless steel without the use of flux by tinning the aluminum with a tin solder containing 1% silver and 1% lead, tinning the stainless steel with a 50% lead 50% tin solder, and then sweating the tinned surfaces together.

  13. Low Mn alloy steel for cryogenic service

    DOE Patents [OSTI]

    Morris, J.W. Jr.; Niikura, M.

    A ferritic cryogenic steel which has a relatively low (about 4 to 6%) manganese content and which has been made suitable for use at cryogenic temperatures by a thermal cycling treatment followed by a final tempering. The steel includes 4 to 6% manganese, 0.02 to 0.06% carbon, 0.1 to 0.4% molybdenum and 0 to 3% nickel.

  14. Method for welding chromium molybdenum steels

    DOE Patents [OSTI]

    Sikka, Vinod K.

    1986-01-01

    Chromium-molybdenum steels exhibit a weakening after welding in an area adjacent to the weld. This invention is an improved method for welding to eliminate the weakness by subjecting normalized steel to a partial temper prior to welding and subsequently fully tempering the welded article for optimum strength and ductility.

  15. Optimization and testing results of Zr-bearing ferritic steels

    SciTech Connect (OSTI)

    Tan, Lizhen; Yang, Ying; Tyburska-Puschel, Beata; Sridharan, K.

    2014-09-01

    The mission of the Nuclear Energy Enabling Technologies (NEET) program is to develop crosscutting technologies for nuclear energy applications. Advanced structural materials with superior performance at elevated temperatures are always desired for nuclear reactors, which can improve reactor economics, safety margins, and design flexibility. They benefit not only new reactors, including advanced light water reactors (LWRs) and fast reactors such as sodium-cooled fast reactor (SFR) that is primarily designed for management of high-level wastes, but also life extension of the existing fleet when component exchange is needed. Developing and utilizing the modern materials science tools (experimental, theoretical, and computational tools) is an important path to more efficient alloy development and process optimization. Ferritic-martensitic (FM) steels are important structural materials for nuclear reactors due to their advantages over other applicable materials like austenitic stainless steels, notably their resistance to void swelling, low thermal expansion coefficients, and higher thermal conductivity. However, traditional FM steels exhibit a noticeable yield strength reduction at elevated temperatures above ~500°C, which limits their applications in advanced nuclear reactors which target operating temperatures at 650°C or higher. Although oxide-dispersion-strengthened (ODS) ferritic steels have shown excellent high-temperature performance, their extremely high cost, limited size and fabricability of products, as well as the great difficulty with welding and joining, have limited or precluded their commercial applications. Zirconium has shown many benefits to Fe-base alloys such as grain refinement, improved phase stability, and reduced radiation-induced segregation. The ultimate goal of this project is, with the aid of computational modeling tools, to accelerate the development of a new generation of Zr-bearing ferritic alloys to be fabricated using conventional

  16. Evaluation of geological formations of Eastern Europe countries for raw disposal and elaboration of joint R&D programmes

    SciTech Connect (OSTI)

    Khrushchov, D.P.; Nigmatullin, N.S.; Balla, Z.

    1995-12-01

    The development of national R&D programmes on RAW management in the countries of East Europe is inevitably due to the fact that some of them (Ukraine, Russia, Slovakia, Bulgaria, Romania), have rather developed nuclear power industries, whereas some others are planning their development (Poland, Byelarus, Lithuania, etc.). The majority of East European countries have their own R&D programmes. The territories of these countries are situated within the limits of the East European geological platforms. As to RAW disposal these geological areas and consequently, the geological regions of East European countries are in very different condition. However, all the countries making use of nuclear power and other industries producing RAW, are facing a need to solve the problem of RAW disposal and to develop their own national programmes. Thus, the different geological environments for RAW disposal, which are extremely unfavorable in some countries, may be considered as a reason for joint R&D programmes initiation. The aim of these programmes is a detailed evaluation of geological formations and geological structure of East European countries as to RAW isolation in order to unite the efforts and to increase the efficiency of national R&D programmes as well as to ground subsequent joint actions related to RAW disposal.

  17. Final Scientific Report Steel Foundry Refractory Lining Optimization

    SciTech Connect (OSTI)

    Smith, J.D.; Peaslee, K.D.

    2002-12-02

    reductions are realized through changes within the ladle transfer portion of the process, through modified ladle pre-heat and refractory insulation. Reductions in clean room energy usage proved very difficult to track, and some questions as to just how much impact refractory related inclusions have on the degree of welding and grinding required for completion of a casting, remain. Post-mortem analysis of casting defects did identify refractory derived inclusions but the greatest concentration of inclusions related to steel reoxidation issue. In almost every instance, the suggested refractory/process modifications were proven to be both technically and economically feasible. The difficulty in implementation of the proposed changes relates to the ''up front'' expense and the learning curve associated with any process modification. These two issues were compounded by production slow downs that are too common in the current market. Such slow downs normally result in less energy efficient processing coupled with reductions in capital or ''up front'' expenditures. A return to historical norms should allow foundries to implement the suggested modifications and then evaluate the overall benefit.

  18. Tritiated Water Interaction with Stainless Steel

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2007-05-01

    Experiments conducted to study tritium permeation of stainless steel at ambient and elevated temperatures revealed that HT converts relatively quickly to HTO. Further, the HTO partial pressure contributes essentially equally with elemental tritium gas in driving permeation through the stainless steel. Such permeation appears to be due to dissociation of the water molecule on the hot stainless steel surface. There is an equilibrium concentration of HTO vapor above adsorbed gas on the walls of the experimental apparatus evident from freezing transients. The uptake process of tritium from the carrier gas involves both surface adsorption and isotopic exchange with surface bound water.

  19. Geneva Steel blast furnace improvements

    SciTech Connect (OSTI)

    Fowles, R.D.; Hills, L.S.

    1993-01-01

    Geneva Steel is located in Utah and is situated near the western edge of the Rocky Mountains adjacent to the Wasatch Front. Geneva's No. 1, 2 and 3 are the only remaining operating blast furnaces in the United States west of the Mississippi River. They were originally constructed in 1943 to support steelmaking during World War II. During the early 60's all three furnaces were enlarged to their current working volume. Very few major improvements were made until recently. This discussion includes a brief historical perspective of operating difficulties associated with practice, design and equipment deficiencies. Also included is an overview of blast furnace improvements at Geneva found necessary to meet the demands of modern steelmaking. Particular emphasis will be placed on casthouse improvements.

  20. HRC steel mill project. Volume 2. Final report. Export trade information

    SciTech Connect (OSTI)

    1995-08-01

    The initial step in developing the design for a steel producing facility is the selection of the major processes to be used. This study investigated five steelmaking processes to determine the one(s) best suited for Grasim based on technical and cost performance. The processes were: Electric Arc Furnace; Induction Furnace/BOF; KS Furnace; Cupola; and Submerged Arc. This investigation determined that the electric arc furnace (EAF) was the most suitable melting process for the production of steel using DRI feed stock.

  1. Field weldability of high strength pipeline steels

    SciTech Connect (OSTI)

    Noble, D.N.; Pargeter, R.J.

    1988-01-01

    This project has studied the small-scale SMA weldability of two X80 grade pipeline steels and conducted mechanical and fracture toughness tests on full-size SMA and GMA welds in both pipes.

  2. High performance corrosion-resistant structural steels

    SciTech Connect (OSTI)

    Fletcher, F.B.; Ferry, B.N.; Beblo, D.G.

    1995-12-31

    A new corrosion-resistant structural steel named Duracorr was developed for low maintenance when compared to conventional structural steels. The new stainless steel is a dual phase composition between the established 12% Cr, ferritic T409 and martensitic T410 grades. Attractive combinations of hardness, strength, toughness, weldability and formability are derived from a microstructure that is a dual phase mixture of ferrite and martensite. The Duracorr composition, UNS S41003, provides for a microstructure of ferrite and austenite to be present throughout the hot rolling process. Cooling to room temperature causes transformation of the austenite to martensite. Subsequent tempering of the steel creates minimum mechanical properties of 275 MPa (40 ksi) yield strength and 455 MPa (66 ksi) tensile strength with room temperature longitudinal Charpy impact values typically greater than 34 J (25 ft-lbs).

  3. Case hardenable nickel-cobalt steel

    SciTech Connect (OSTI)

    Qian, Yana; Olson, Gregory B.

    2012-04-17

    An advanced secondary hardening carburized Ni--Co steel achieves an improved case hardness of about 68-69 Rc together with nominal core hardness of about 50 Rc.

  4. Hydrogen compatibility handbook for stainless steels

    SciTech Connect (OSTI)

    Caskey, G.R. Jr.

    1983-06-01

    This handbook compiles data on the effects of hydrogen on the mechanical properties of stainless steels and discusses this data within the context of current understanding of hydrogen compatibility of metals. All of the tabulated data derives from continuing studies of hydrogen effects on materials that have been conducted at the Savannah River Laboratory over the past fifteen years. Supplementary data from other sources are included in the discussion. Austenitic, ferritic, martensitic, and precipitation hardenable stainless steels have been studied. Damage caused by helium generated from decay of tritium is a distinctive effect that occurs in addition to the hydrogen isotopes protium and deuterium. The handbook defines the scope of our current knowledge of hydrogen effects in stainless steels and serves as a guide to selection of stainless steels for service in hydrogen.

  5. Stainless Steel to Titanium Bimetallic Transitions

    SciTech Connect (OSTI)

    Kaluzny, J. A.; Grimm, C.; Passarelli, D.

    2015-01-01

    In order to use stainless steel piping in an LCLS-II (Linac Coherent Light Source Upgrade) cryomodule, stainless steel to titanium bimetallic transitions are needed to connect the stainless steel piping to the titanium cavity helium vessel. Explosion bonded stainless steel to titanium transition pieces and bimetallic transition material samples have been tested. A sample transition tube was subjected to tests and x-ray examinations between tests. Samples of the bonded joint material were impact and tensile tested at room temperature as well as liquid helium temperature. The joint has been used successfully in horizontal tests of LCLS-II cavity helium vessels and is planned to be used in LCLS-II cryomodules. Results of material sample and transition tube tests will be presented.

  6. Mr. Thomas Mahl Granite City Steel Company

    Office of Legacy Management (LM)

    8&v Mr. Thomas Mahl Granite City Steel Company 20th and State Streets Granite City, IL 62040 Dear Mr. Mahl: This is to notify you that the U.S. Department of Energy (DOE) has ...

  7. Precise carbon control of fabricated stainless steel

    DOE Patents [OSTI]

    Nilsen, R.J.

    1975-12-01

    A process is described for controlling the carbon content of fabricated stainless steel components including the steps of heat treating the component in hydrogen atmospheres of varying dewpoints and carbon potentials.

  8. A STUDY OF CORROSION AND STRESS CORROSION CRACKING OF CARBON STEEL NUCLEAR WASTE STORAGE TANKS

    SciTech Connect (OSTI)

    BOOMER, K.D.

    2007-08-21

    The Hanford reservation Tank Farms in Washington State has 177 underground storage tanks that contain approximately 50 million gallons of liquid legacy radioactive waste from cold war plutonium production. These tanks will continue to store waste until it is treated and disposed. These nuclear wastes were converted to highly alkaline pH wastes to protect the carbon steel storage tanks from corrosion. However, the carbon steel is still susceptible to localized corrosion and stress corrosion cracking. The waste chemistry varies from tank to tank, and contains various combinations of hydroxide, nitrate, nitrite, chloride, carbonate, aluminate and other species. The effect of each of these species and any synergistic effects on localized corrosion and stress corrosion cracking of carbon steel have been investigated with electrochemical polarization, slow strain rate, and crack growth rate testing. The effect of solution chemistry, pH, temperature and applied potential are all considered and their role in the corrosion behavior will be discussed.

  9. Controlled rolling process for dual phase steels and application to rod, wire, sheet and other shapes

    DOE Patents [OSTI]

    Thomas, G.; Ahn, J.H.; Kim, N.J.

    1986-10-28

    An improved, energy efficient, hot rolling method for direct production of cold formable dual-phase steel is provided. The steel is heated to completely austenitize it and then continuously hot rolled and cooled down into the ferrite-austenite two phase region to a temperature which is just below the effective Ar[sub 3] temperature. The hot rolled steel is then rapidly quenched to provide an alloy containing strong, tough lath martensite (fibers) in a ductile soft ferrite matrix. The method is particularly useful for providing rods in which form the alloy is capable of being drawn into high strength wire or the like in a cold drawing operation without any intermediate annealing or patenting, and has excellent strength, ductility and fatigue characteristics. 3 figs.

  10. Controlled rolling process for dual phase steels and application to rod, wire, sheet and other shapes

    DOE Patents [OSTI]

    Thomas, Gareth; Ahn, Jae-Hwan; Kim, Nack-Joon

    1986-01-01

    An improved, energy efficient, hot rolling method for direct production of cold formable dual-phase steel is provided. The steel is heated to completely austenitize it and then continuously hot rolled and cooled down into the ferrite-austenite two phase region to a temperature which is just below the effective Ar.sub.3 temperature. The hot rolled steel is then rapidly quenched to provide an alloy containing strong, tough lath martensite (fibers) in a ductile soft ferrite matrix. The method is particularly useful for providing rods in which form the alloy is capable of being drawn into high strength wire or the like in a cold drawing operation without any intermediate annealing or patenting, and has excellent strength, ductility and fatigue characteristics.

  11. Development of Stronger and More Reliable Cast Austenitic Stainless Steels (H-Series) Based on Scientific and Design Methodology

    SciTech Connect (OSTI)

    Pankiw, Roman I; Muralidharan, G.; Sikka, Vinod K.

    2006-06-30

    The goal of this project was to increase the high-temperature strength of the H-Series of cast austenitic stainless steels by 50% and the upper use temperature by 86 to 140 degrees fahrenheit (30 to 60 degrees celsius). Meeting this goal is expected to result in energy savings of 35 trillion Btu/year by 2020 and energy cost savings of approximately $230 million/year. The higher-strength H-Series cast stainless steels (HK and HP type) have applications for the production of ethylene in the chemical industry, for radiant burner tubes and transfer rolls for secondary processing of steel in the steel industry, and for many applications in the heat treating industry, including radiant burner tubes. The project was led by Duraloy Technologies, Inc., with research participation by Oak Ridge National Laboratory (ORNL) and industrial participation by a diverse group of companies.

  12. High strength and high toughness steel

    DOE Patents [OSTI]

    Parker, Earl R.; Zackay, Victor F.

    1979-01-01

    A structural steel which possess both high strength and high toughness and has particular application of cryogenic uses. The steel is produced by the utilization of thermally induced phase transformation following heating in a three-phase field in iron-rich alloys of the Fe-Ni-Ti system, with a preferred composition of 12% nickel, 0.5% titanium, the remainder being iron.

  13. High strength, high ductility low carbon steel

    DOE Patents [OSTI]

    Koo, Jayoung; Thomas, Gareth

    1978-01-01

    A high strength, high ductility low carbon steel consisting essentially of iron, 0.05-0.15 wt% carbon, and 1-3 wt% silicon. Minor amounts of other constituents may be present. The steel is characterized by a duplex ferrite-martensite microstructure in a fibrous morphology. The microstructure is developed by heat treatment consisting of initial austenitizing treatment followed by annealing in the (.alpha. + .gamma.) range with intermediate quenching.

  14. The Underground Corrosion of Selected Type 300 Stainless Steels After 34 Years

    SciTech Connect (OSTI)

    T. S. Yoder; M. K. Adler Flitton

    2009-03-01

    Recently, interest in long-term underground corrosion has greatly increased because of the ongoing need to dispose of nuclear waste. Additionally, the Nuclear Waste Policy Act of 1982 requires disposal of high-level nuclear waste in an underground repository. Current contaminant release and transport models use limited available short-term underground corrosion rates when considering container and waste form degradation. Consequently, the resulting models oversimplify the complex mechanisms of underground metal corrosion. The complexity of stainless steel corrosion mechanisms and the processes by which corrosion products migrate from their source are not well depicted by a corrosion rate based on general attack. The research presented here is the analysis of austenitic stainless steels after 33 years of burial. In this research, the corrosion specimens were analyzed using applicable ASTM standards as well as microscopic and X-ray examination to determine the mechanisms of underground stainless steel corrosion. As presented, the differences in the corrosion mechanisms vary with the type of stainless steel and the treatment of the samples. The uniqueness of the long sampling time allows for further understanding of the actual stainless steel corrosion mechanisms, and when applied back into predictive models, will assist in reduction of the uncertainty in parameters for predicting long-term fate and transport.

  15. Development of Steel Foam Materials and Structures

    SciTech Connect (OSTI)

    Kenneth Kremer; Anthony Liszkiewicz; James Adkins

    2004-10-20

    In the past few years there has been a growing interest in lightweight metal foams. Demands for weight reduction, improved fuel efficiency, and increased passenger safety in automobiles now has manufacturers seriously considering the use of metal foams, in contrast to a few years ago, when the same materials would have been ruled out for technical or economical reasons. The objective of this program was to advance the development and use of steel foam materials, by demonstrating the advantages of these novel lightweight materials in selected generic applications. Progress was made in defining materials and process parameters; characterization of physical and mechanical properties; and fabrication and testing of generic steel foam-filled shapes with compositions from 2.5 wt.% to 0.7 wt.% carbon. A means of producing steel foam shapes with uniform long range porosity levels of 50 to 60 percent was demonstrated and verified with NDE methods. Steel foam integrated beams, cylinders and plates were mechanically tested and demonstrated advantages in bend stiffness, bend resistance, and crush energy absorption. Methods of joining by welding, adhesive bonding, and mechanical fastening were investigated. It is important to keep in mind that steel foam is a conventional material in an unconventional form. A substantial amount of physical and mechanical properties are presented throughout the report and in a properties database at the end of the report to support designer's in applying steel foam in unconventional ways.

  16. Microstructural studies of advanced austenitic steels

    SciTech Connect (OSTI)

    Todd, J. A.; Ren, Jyh-Ching

    1989-11-15

    This report presents the first complete microstructural and analytical electron microscopy study of Alloy AX5, one of a series of advanced austenitic steels developed by Maziasz and co-workers at Oak Ridge National Laboratory, for their potential application as reheater and superheater materials in power plants that will reach the end of their design lives in the 1990's. The advanced steels are modified with carbide forming elements such as titanium, niobium and vanadium. When combined with optimized thermo-mechanical treatments, the advanced steels exhibit significantly improved creep rupture properties compared to commercially available 316 stainless steels, 17--14 Cu--Mo and 800 H steels. The importance of microstructure in controlling these improvements has been demonstrated for selected alloys, using stress relaxation testing as an accelerated test method. The microstructural features responsible for the improved creep strengths have been identified by studying the thermal aging kinetics of one of the 16Ni--14Cr advanced steels, Alloy AX5, in both the solution annealed and the solution annealed plus cold worked conditions. Time-temperature-precipitation diagrams have been developed for the temperature range 600 C to 900 C and for times from 1 h to 3000 h. 226 refs., 88 figs., 10 tabs.

  17. Irradiation Assisted Grain Boundary Segregation in Steels

    SciTech Connect (OSTI)

    Lu, Zheng; Faulkner, Roy G.

    2008-07-01

    The understanding of radiation-induced grain boundary segregation (RIS) has considerably improved over the past decade. New models have been introduced and much effort has been devoted to obtaining comprehensive information on segregation from the literature. Analytical techniques have also improved so that chemical analysis of layers 1 nm thick is almost routine. This invited paper will review the major methods used currently for RIS prediction: namely, Rate Theory, Inverse Kirkendall, and Solute Drag approaches. A summary is made of the available data on phosphorus RIS in reactor pressure vessel (RPV) steels. This will be discussed in the light of the predictions of the various models in an effort to show which models are the most reliable and easy to use for forecasting P segregation behaviour in steels. A consequence of RIS in RPV steels is a radiation induced shift in the ductile to brittle transition temperature (DBTT). It will be shown how it is possible to relate radiation-induced P segregation levels to DBTT shift. Examples of this exercise will be given for RPV steels and for ferritic steels being considered for first wall fusion applications. Cr RIS in high alloy stainless steels and associated irradiation-assisted stress corrosion cracking (IASCC) will be briefly discussed. (authors)

  18. Tensile-property characterization of thermally aged cast stainless steels

    SciTech Connect (OSTI)

    Michaud, W.F.; Toben, P.T.; Soppet, W.K.; Chopra, O.K.

    1994-02-01

    The effect of thermal aging on tensile properties of cast stainless steels during service in light water reactors has been evaluated. Tensile data for several experimental and commercial heats of cast stainless steels are presented. Thermal aging increases the tensile strength of these steels. The high-C Mo-bearing CF-8M steels are more susceptible to thermal aging than the Mo-free CF-3 or CF-8 steels. A procedure and correlations are presented for predicting the change in tensile flow and yield stresses and engineering stress-vs.-strain curve of cast stainless steel as a function of time and temperature of service. The tensile properties of aged cast stainless steel are estimated from known material information, i.e., chemical composition and the initial tensile strength of the steel. The correlations described in this report may be used for assessing thermal embrittlement of cast stainless steel components.

  19. ITP Steel: Theoretical Minimum Energies to Produce Steel for Selected Conditions, March 2000

    Broader source: Energy.gov [DOE]

    The absolute theoretical minimum energies to produce liquid steel from idealized scrap (100% Fe) and ore (100% Fe2O3) are much lower than consumed in practice, as are the theoretical minimum energies to roll the steel into its final shape.

  20. High Mn austenitic stainless steel

    DOE Patents [OSTI]

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  1. Further development of the cleanable steel HEPA filter, cost/benefit analysis, and comparison with competing technologies

    SciTech Connect (OSTI)

    Bergman, W.; Lopez, R.; Wilson, K.

    1997-08-01

    We have made further progress in developing a cleanable steel fiber HEPA filter. We fabricated a pleated cylindrical cartridge using commercially available steel fiber media that is made with 1 {mu}m stainless steel fibers and sintered into a sheet form. Test results at the Department of Energy (DOE) Filter Test Station at Oak Ridge show the prototype filter cartridge has 99.99% efficiency for 0.3 {mu}m dioctyl phthalate (DOP) aerosols and a pressure drop of 1.5 inches. Filter loading and cleaning tests using AC Fine dust showed the filter could be repeatedly cleaned using reverse air pulses. Our analysis of commercially optimized filters suggest that cleanable steel HEPA filters need to be made from steel fibers less than 1{mu}m, and preferably 0.5 {mu}m, to meet the standard HEPA filter requirements in production units. We have demonstrated that 0.5 {mu}m steel fibers can be produced using the fiber bundling and drawing process. The 0.5 {mu}m steel fibers are then sintered into small filter samples and tested for efficiency and pressure drop. Test results on the sample showed a penetration of 0.0015 % at 0.3 {mu}m and a pressure drop of 1.15 inches at 6.9 ft/min (3.5 cm/s) velocity. Based on these results, steel fiber media can easily meet the requirements of 0.03 % penetration and 1.0 inch of pressure drop by using less fibers in the media. A cost analysis of the cleanable steel HEPA filter shows that, although the steel HEPA filter costs much more than the standard glass fiber HEPA filter, it has the potential to be very cost effective because of the high disposal costs of contaminated HEPA filters. We estimate that the steel HEPA filter will save an average of $16,000 over its 30 year life. The additional savings from the clean-up costs resulting from ruptured glass HEPA filters during accidents was not included but makes the steel HEPA filter even more cost effective. 33 refs., 28 figs., 1 tab.

  2. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  3. Microstructural evolution in fast-neutron-irradiated austenitic stainless steels

    SciTech Connect (OSTI)

    Stoller, R.E.

    1987-12-01

    The present work has focused on the specific problem of fast-neutron-induced radiation damage to austenitic stainless steels. These steels are used as structural materials in current fast fission reactors and are proposed for use in future fusion reactors. Two primary components of the radiation damage are atomic displacements (in units of displacements per atom, or dpa) and the generation of helium by nuclear transmutation reactions. The radiation environment can be characterized by the ratio of helium to displacement production, the so-called He/dpa ratio. Radiation damage is evidenced microscopically by a complex microstructural evolution and macroscopically by density changes and altered mechanical properties. The purpose of this work was to provide additional understanding about mechanisms that determine microstructural evolution in current fast reactor environments and to identify the sensitivity of this evolution to changes in the He/dpa ratio. This latter sensitivity is of interest because the He/dpa ratio in a fusion reactor first wall will be about 30 times that in fast reactor fuel cladding. The approach followed in the present work was to use a combination of theoretical and experimental analysis. The experimental component of the work primarily involved the examination by transmission electron microscopy of specimens of a model austenitic alloy that had been irradiated in the Oak Ridge Research Reactor. A major aspect of the theoretical work was the development of a comprehensive model of microstructural evolution. This included explicit models for the evolution of the major extended defects observed in neutron irradiated steels: cavities, Frank faulted loops and the dislocation network. 340 refs., 95 figs., 18 tabs.

  4. New trends in industrial energy efficiency in the Mexico iron and steel industry

    SciTech Connect (OSTI)

    Ozawa, Leticia; Martin, Nathan; Worrell, Ernst; Price, Lynn; Sheinbaum, Claudia

    1999-07-31

    Energy use in the Mexican industrial sector experienced important changes in the last decade related to changes in the Mexican economy. In previous studies, we have shown that a real change in energy-intensity was the most important factor in the overall decline of energy use and CO2 emissions in the Mexican industrial sector. Real changes in energy intensity were explained by different factors, depending on the industrial sub-sector. In this paper, we analyze the factors that influenced energy use in the Mexican iron and steel industry, the largest energy consuming and energy-intensive industry in the country. To understand the trends in this industry we used a decomposition analysis based on physical indicators to decompose the changes in intra-sectoral structural changes and efficiency improvements. Also, we use a structure-efficiency analysis for international comparisons, considering industrial structure and the best available technology. In 1995, Mexican iron and steel industry consumed 17.7 percent of the industrial energy consumption. Between 1970 and 1995, the steel production has increased with an annual growth rate of 4.7 percent, while the specific energy consumption (SEC) has decreased from 28.4 to 23.8 GJ/tonne of crude steel. This reduction was due to energy efficiency improvements (disappearance of the open hearth production, increase of the share of the continuous casting) and to structural changes as well (increase of the share of scrap input in the steelmaking).

  5. Mechanical properties of irradiated 9Cr-2WVTa steel

    SciTech Connect (OSTI)

    Klueh, R.L.; Alexander, D.J.; Rieth, M.

    1998-09-01

    An Fe-9Cr-2W-0.25V-0.07Ta-0.1C (9Cr-2WVTa) steel has excellent strength and impact toughness before and after irradiation in the Fast Flux Test Facility and the High Flux Reactor (HFR). The ductile-brittle transition temperature (DBTT) increased only 32 C after 28 dpa at 365 C in FFTF, compared to a shift of {approx}60 C for a 9Cr-2WV steel--the same as the 9Cr-2WVTa steel but without tantalum. This difference occurred despite the two steels having similar tensile but without tantalum. This difference occurred despite the two steels having similar tensile properties before and after irradiation. The 9Cr-2WVTa steel has a smaller prior-austenite grain size, but otherwise microstructures are similar before irradiation and show similar changes during irradiation. The irradiation behavior of the 9Cr-2WVTa steel differs from the 9Cr-2WV steel and other similar steels in two ways: (1) the shift in DBTT of the 9Cr-2WVTa steel irradiated in FFTF does not saturate with fluence by {approx}28 dpa, whereas for the 9Cr-2WV steel and most similar steels, saturation occurs at <10 dpa, and (2) the shift in DBTT for 9Cr-2WVTa steel irradiated in FFTF and HFR increased with irradiation temperature, whereas it decreased for the 9Cr-2WV steel, as it does for most similar steels. The improved properties of the 9Cr-2WVTa steel and the differences with other steels were attributed to tantalum in solution.

  6. Process development of thin strip steel casting

    SciTech Connect (OSTI)

    Sussman, R.C.; Williams, R.S.

    1990-12-01

    An important new frontier is being opened in steel processing with the emergence of thin strip casting. Casting steel directly to thin strip has enormous benefits in energy savings by potentially eliminating the need for hot reduction in a hot strip mill. This has been the driving force for numerous current research efforts into the direct strip casting of steel. The US Department of Energy initiated a program to evaluate the development of thin strip casting in the steel industry. In earlier phases of this program, planar flow casting on an experimental caster was studied by a team of engineers from Westinghouse Electric corporation and Armco Inc. A subsequent research program was designed as a fundamental and developmental study of both planar and melt overflow casting processes. This study was arranged as several separate and distinct tasks which were often completed by different teams of researchers. An early task was to design and build a water model to study fluid flow through different designs of planar flow casting nozzles. Another important task was mathematically modeling of melt overflow casting process. A mathematical solidification model for the formation of the strip in the melt overflow process was written. A study of the material and conditioning of casting substrates was made on the small wheel caster using the melt overflow casting process. This report discusses work on the development of thin steel casting.

  7. Superplastic forming of stainless steel automotive components

    SciTech Connect (OSTI)

    Bridges, B.; Elmer, J.; Carol, L.

    1997-02-06

    Exhaust emission standards are governmentally controlled standards, which are increasingly stringent, forcing alternate strategies to meet these standards. One approach to improve the efficiency of the exhaust emission equipment is to decrease the time required to get the catalytic converter to optimum operating temperature. To accomplish this, automotive manufacturers are using double wall stainless steel exhaust manifolds to reduce heat loss of the exhaust gases to the converter. The current method to manufacture double wall stainless steel exhaust components is to use a low-cost alloy with good forming properties and extensively form, cut, assemble, and weld the pieces. Superplastic forming (SPF) technology along with alloy improvements has potential at making this process more cost effective. Lockheed Martin Energy Systems (LMES), Lawrence Livermore National Laboratory (LLNL) and USCAR Low Emission Partnership (LEP) worked under a Cooperative Research And Development Agreement (CRADA) to evaluate material properties, SPF behavior, and welding behavior of duplex stainless steel alloy for automotive component manufacturing. Battelle Pacific Northwest National Laboratory (PNNL) has a separate CRADA with the LEP to use SPF technology to manufacture a double wall stainless steel exhaust component. As a team these CRADAs developed and demonstrated a technical plan to accomplish making double wall stainless steel exhaust manifolds.

  8. Progress in the R and D Project on Oxide Dispersion Strengthened and Precipitation Hardened Ferritic Steels for Sodium Cooled Fast Breeder Reactor Fuels

    SciTech Connect (OSTI)

    Kaito, Takeji; Ohtsuka, Satoshi; Inoue, Masaki

    2007-07-01

    High burnup capability of sodium cooled fast breeder reactor (SFR) fuels depends significantly on irradiation performance of their component materials. Japan Atomic Energy Agency (JAEA) has been developing oxide dispersion strengthened (ODS) ferritic steels and a precipitation hardened (PH) ferritic steel as the most prospective materials for fuel pin cladding and duct tubes, respectively. Technology for small-scale manufacturing is already established, and several hundreds of ODS steel cladding tubes and dozens of PH steel duct tubes were successfully produced. We will step forward to develop manufacturing technology for mass production to supply these steels for future SFR fuels. Mechanical properties of the products were examined by out-of-pile and in-pile tests including material irradiation tests in the experimental fast reactor JOYO and foreign fast reactors. The material strength standards (MSSs) were tentatively compiled in 2005 for ODS steels and in 1993 for PH steel. In order to upgrade the MSSs and to demonstrate high burnup capability of the materials, we will perform a series of irradiation tests in BOR-60 and JOYO until 2015 and contribute to design study for a demonstration SFR of which operation is expected after 2025. (authors)

  9. The design of steel for high strength line pipe requiring excellent notch toughness and corrosion properties for arctic applications

    SciTech Connect (OSTI)

    DeCaux, G.; Golini, F.; Rayner, T.J.

    1998-12-31

    Due to the cold climate and environmental requirements of Alaska`s North Slope and Western Canada`s oil production areas, line pipe steels intended for use in these areas must display not only high strength as required, but superior toughness. Additionally,if the line pipe is to be used in aggressive sour gas (i.e., H{sub 2}S containing) environments it must also have excellent resistance to hydrogen induced cracking (HIC). Such a steel has been designed, through selective chemistry, clean steel-making practices, nonmetallic inclusion control, and hot mill process control, that is capable of meeting stringent line pipe specifications covering X65 grade line pipe in Arctic service temperatures. This paper also examined the effect that hot rolling finishing temperature had on notch toughness. Steel-making knowledge developed for lower strength, HIC resistant X52 grade steel has been employed for the development of a X65 grade steel. Results of trial heats will be presented.

  10. Study, Development, and Design of Replaceable Shear Yielding Steel Panel Damper

    SciTech Connect (OSTI)

    Murakami, Katsuhide; Keii, Michio

    2008-07-08

    For middle-high rise buildings, vibration controlled structures to reduce the damage of main frames are recently becoming general in Japan. A steel material damper is low price and excellent in the energy absorption efficiency at a large earthquake. Though the exchange of the dampers are necessary when an excessive accumulation of plasticity deformation occurs, a steel material damping system, which received an excessive accumulation of plasticity deformation after a large earthquake, can recover a seismic-proof performance and property value of the building after the replacement. In the paper, shear yielding steel panel dampers installed in the web of a beam connected with high tension bolt joint is introduced. This damper is made of low-yield point steel, and the advantages of this system are low cost, easy-production and easy-replacement. For this steel panel damper, the finite element method (FEM) analysis using the shell element model adjusted to 1/2 of 6.4 m beam span is executed to make the design most effective. Yielding property of the beam installing this damper, shape of the splice plate and the bolt orientation for the connecting are examined in this analysis. As a result, we found that the plastic strain extends uniformly to the entire damping panel when making the splice plate a trapezoidal shape. The basic performance confirmation examination was also done using the real scale examination model besides the FEM analysis, and the performance of the system was confirmed. In addition, design of a high rise building in which the steel shear-yielding panel dampers and oil dampers were adopted without disturbing an architectural plan is also introduced.

  11. Z Group Steel Holding Zelezarny Veseli | Open Energy Information

    Open Energy Info (EERE)

    Z Group Steel Holding Zelezarny Veseli Jump to: navigation, search Name: Z-Group Steel Holding - Zelezarny Veseli Place: Veseli nad Moravou, Czech Republic Zip: 698 12 Sector: Wind...

  12. Stainless steel 304 cladding mechanical properties and limitations...

    Office of Scientific and Technical Information (OSTI)

    steel 304 cladding mechanical properties and limitations during steady state operation of U-ZrH TRIGA type fuel. Citation Details In-Document Search Title: Stainless steel 304 ...

  13. DOE - Office of Legacy Management -- Wyckoff Drawn Steel Co ...

    Office of Legacy Management (LM)

    Drawn Steel Co - IL 0-09 FUSRAP Considered Sites Site: Wyckoff Drawn Steel Co (IL 0-09) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: ...

  14. How Trenton Iron and Steel Innovations Reshaped America Clifford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trenton Iron and Steel Innovations Reshaped America Clifford Zink Independent Historian ... DeParTmenT of energy faciliTy Iron and steel innovations in Trenton helped transform ...

  15. First Structural Steel Erected at NSLS-II

    ScienceCinema (OSTI)

    None

    2010-01-08

    Ten steel columns were incorporated into the ever-growing framework for the National Synchrotron Light Source II last week, the first structural steel erected for the future 400,000-square-foot facility.

  16. DOE - Office of Legacy Management -- Allegheny-Ludlum Steel Corp...

    Office of Legacy Management (LM)

    Site: ALLEGHENY-LUDLUM STEEL CORP. (NY.0-02 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Al-Tech Specialty Steel NY.0-02-1 Location: ...

  17. First Structural Steel Erected at NSLS-II

    SciTech Connect (OSTI)

    2009-09-14

    Ten steel columns were incorporated into the ever-growing framework for the National Synchrotron Light Source II last week, the first structural steel erected for the future 400,000-square-foot facility.

  18. Friction Stir Spot Welding of Advanced High Strength Steels II...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Friction Stir Spot Welding of Advanced High Strength Steels II Friction Stir Spot Welding of Advanced High Strength Steels II 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle ...

  19. Comments of Steele-Waseca Cooperative Electric | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steele-Waseca Cooperative Electric Comments of Steele-Waseca Cooperative Electric Comments of Steele-Waseca Cooperative Electric onImplementing the National Broadband Plan by Studying the Communications Requirements of Electric Utilities to Inform Federal Smart Grid Policy Comments of Steele-Waseca Cooperative Electric (65.64 KB) More Documents & Publications NBP RFI: Communications Requirements- Comments of Great River Energy Communications Requirements of Smart Grid Technologies Final

  20. Enhanced Incluison Removal from Steel in the Tundish

    SciTech Connect (OSTI)

    R.C. Bradt; M.A.R. Sharif

    2009-09-25

    The objective of this project was to develop an effective chemical filtering system for significantly reducing the content of inclusion particles in the steel melts exiting the tundish for continuous casting. This project combined a multi-process approach that aimed to make significant progress towards an "inclusion free" steel by incorporating several interdependent concepts to reduce the content of inclusions in the molten steel exiting the tundish for the caster. The goal is to produce "cleaner" steel.

  1. Enhanced Inclusion Removal from Steel in the Tundish

    SciTech Connect (OSTI)

    R. C. Bradt; M.A.R. Sharif

    2009-09-25

    The objective of this project was to develop an effective chemical filtering system for significantly reducing the content of inclusion particles in the steel melts exiting the tundish for continuous casting. This project combined a multi-process approach that aimed to make significant progress towards an "inclusion free" steel by incorporating several interdependent concepts to reduce the content of inclusions in the molten steel exiting the tundish for the caster. The goal is to produce "cleaner" steel.

  2. CERTIFICATION DOCKET FOR AL-TECH SPECIALTY STEEL CORPORATION

    Office of Legacy Management (LM)

    NY. 0 -02-3 CERTIFICATION DOCKET FOR AL-TECH SPECIALTY STEEL CORPORATION (THE F01umz ALLEGHENY-LUDLUM STEEL CORPORATION) WATERVLIET, NEW YORK, AND OFFSITE PROPERTY IN DUNKIRK, NEW YORK Department of Energy Office of Nuclear Energy Office of Terminal Waste Disposal and Remedial Action Division of Remedial Action Projects CONTENTS Introduction to the Certification Docket for the Al-Tech Specialty Steel Corporation, (the Former Allegheny-Ludlum Steel Corporation) Watervliet, New York, and Offsite

  3. CERTIFICATION DOCKET FOR BETHLEHEM STEEL CORPORATION LACKAWANNA, NEW YORK

    Office of Legacy Management (LM)

    BETHLEHEM STEEL CORPORATION LACKAWANNA, NEW YORK Department of Energy Office of Nuclear Energy Office of Terminal Waste Disposal and Remedial Action Division of Remedial Action Projects CONTENTS Introduction to the Certification Docket for Bethlehem Steel Corporation, Lackawanna, New York Purpose Docket Contents Exhibit I: Summary of Activities at the Bethlehem Steel Corporation, Lackawanna, New York Exhibit II: Documents Supporting the Certification of the Bethlehem Steel Corporation,

  4. Neutron Irradiation Resistance of RAFM Steels

    SciTech Connect (OSTI)

    Gaganidze, Ermile; Dafferner, Bernhard; Aktaa, Jarir

    2008-07-01

    The neutron irradiation resistance of the reduced-activation ferritic/martensitic (RAFM) steel EUROFER97 and international reference steels (F82H-mod, OPTIFER-Ia, GA3X and MANET-I) have been investigated after irradiation in the Petten High Flux Reactor up to 16.3 dpa at different irradiation temperatures (250-450 deg. C). The embrittlement behavior and hardening are investigated by instrumented Charpy-V tests with sub-size specimens. Neutron irradiation-induced embrittlement and hardening of EUROFER97 was studied under different heat treatment conditions. Embrittlement and hardening of as-delivered EUROFER97 steel are comparable to those of reference steels. Heat treatment of EUROFER97 at a higher austenitizing temperature substantially improves the embrittlement behaviour at low irradiation temperatures. Analysis of embrittlement vs. hardening behavior of RAFM steels within a proper model in terms of the parameter C={delta}DBTT/{delta}{sigma} indicates hardening-dominated embrittlement at irradiation temperatures below 350 deg. C with 0.17 {<=} C {<=} 0.53 deg. C/MPa. Scattering of C at irradiation temperatures above 400 deg. C indicates non hardening embrittlement. A role of He in a process of embrittlement is investigated in EUROFER97 based steels, that are doped with different contents of natural B and the separated {sup 10}B-isotope (0.008-0.112 wt.%). Testing on small scale fracture mechanical specimens for determination of quasi-static fracture toughness will be also presented in a view of future irradiation campaigns. (authors)

  5. Modern steels at atomic and nanometre scales

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Caballero, F. G.; Garcia-Mateo, C.; Miller, M. K.

    2014-10-10

    Processing bulk nanocrystalline materials for structural applications still poses a difficult challenge, particularly in achieving an industrially viable process. Recent work in ferritic steels has proved that it is possible to move from ultrafine to nanoscale by exploiting the bainite reaction without the use of severe deformation, rapid heat treatment or mechanical processing. This new generation of steels has been designed in which transformation at low temperature leads to a nanoscale structure consisting of extremely fine, 20–40 nm thick plates of bainitic ferrite and films of retained austenite. Finally, a description of the characteristics and significance of this remarkable microstructuremore » is provided here.« less

  6. Stainless Steel Microstructure and Mechanical Properties Evaluation

    SciTech Connect (OSTI)

    Switzner, Nathan T

    2010-06-01

    A nitrogen strengthened 21-6-9 stainless steel plate was spinformed into hemispherical test shapes. A battery of laboratory tests was used to characterize the hemispheres. The laboratory tests show that near the pole (axis) of a spinformed hemisphere the yield strength is the lowest because this area endures the least “cold-work” strengthening, i.e., the least deformation. The characterization indicated that stress-relief annealing spinformed stainless steel hemispheres does not degrade mechanical properties. Stress-relief annealing reduces residual stresses while maintaining relatively high mechanical properties. Full annealing completely eliminates residual stresses, but reduces yield strength by about 30%.

  7. Helium damage in austenitic stainless steels

    SciTech Connect (OSTI)

    Caskey, G.R. Jr.; Mezzanotte, D.A. Jr.; Rawl, D.E. Jr.

    1983-01-01

    Helium produced by tritium decay was first shown to embrittle austenitic stainless steel at ambient temperature in tensile specimens of Nitronic-40 steel (Armco, Inc.). A long-term study was initiated to study this form of helium damage in five austenitic alloys. Results from this study have been analyzed by the J-integral technique and show a decrease in ductile fracture toughness with increasing He-3 concentration. Sustained-load cracking tests indicate that the stress intensity required to initiate and propagate a crack also decreases with increasing He-3 concentration. 9 figures, 3 tables.

  8. Use of differential pulse polarography to study corrosion of galvanized steel in aqueous lithium bromide solution

    SciTech Connect (OSTI)

    Garcia-Anton, J.; Perez-Herranz, V.; Guinon, J.L. . Dept. de Ingenieria Quimica y Nuclear); Lacoste, G. )

    1994-02-01

    Static and dynamic corrosion of galvanized steel in 4.6 M lithium bromide (LiBr) solution at 20 C and at 70 C was studied using a new polarographic method for the determination of zinc (Zn) in LiBr solution. Static and dynamic corrosion of galvanize steel at 20 C and 70 C followed a linear tendency with exposure time. However, a change in the slope of dynamic corrosion was observed at 20 C. The corrosion product was studied using energy dispersive x-ray analysis (EDXA) and x-ray diffractometry and was considered to be a mixture of zinc hydroxide Zn(OH)[sub 2] and oxides. The corrosion product morphology was amorphous and gelatinous at 20 C and crystalline at 70 C.

  9. DOE - Office of Legacy Management -- Guterl Specialty Steel - NY 12

    Office of Legacy Management (LM)

    Guterl Specialty Steel - NY 12 FUSRAP Considered Sites Guterl Specialty Steel, NY Alternate Name(s): Simonds Saw and Steel Co. Guterl Steel Allegheny Ludlum Steel Corp. NY.12-1 NY.12-2 Location: Ohio Street and Route 95, Lockport, New York NY.12-12 Historical Operations: Performed rolling mill operations on natural uranium and thorium metal. NY.12-6 NY.12-7 Eligibility Determination: NY.12-11 Radiological Survey(s): Assessment Surveys NY.12-1 NY.12-4 NY.12-8 NY.12-9 NY.12-12 Site Status: Cleanup

  10. Weldment for austenitic stainless steel and method

    DOE Patents [OSTI]

    Bagnall, Christopher; McBride, Marvin A.

    1985-01-01

    For making defect-free welds for joining two austenitic stainless steel mers, using gas tungsten-arc welding, a thin foil-like iron member is placed between the two steel members to be joined, prior to making the weld, with the foil-like iron member having a higher melting point than the stainless steel members. When the weld is formed, there results a weld nugget comprising melted and then solidified portions of the joined members with small portions of the foil-like iron member projecting into the solidified weld nugget. The portions of the weld nugget proximate the small portions of the foil-like iron member which project into the weld nugget are relatively rich in iron. This causes these iron-rich nugget portions to display substantial delta ferrite during solidification of the weld nugget which eliminates weld defects which could otherwise occur. This is especially useful for joining austenitic steel members which, when just below the solidus temperature, include at most only a very minor proportion of delta ferrite.

  11. Up-grade of process control system, U.S. Steel Fairfield No. 8 blast furnace

    SciTech Connect (OSTI)

    Camlic, R.L. [U.S. Steel, Fairfield, AL (United States). Fairfield Works; Goodman, N.J. [Kvaerner Davy, Pittsburgh, PA (United States)

    1997-12-31

    The No. 8 blast furnace at US Steel`s Fairfield, AL facility is the only blast furnace remaining in operating at the plant. The blast furnace has a production capacity of 5,500 tons per day of hot metal and provides 100% of the iron requirements for the steel plant that has an annual production capacity of 2,200,000 tons of steel. Therefore, any outage on No. 8 blast furnace has a major impact on the operation of the total Fairfield facility. During the planning stages of the latest reline outage of No. 8 blast furnace, significant measures were taken to insure that maximum production of iron was maintained before and immediately after the outage. A significant portion of the reline activity was centered on the total replacement of the existing process control system. The scope of replacement was so extensive that it was determined that if all areas of the process control system were replaced during the reline outage, then the installation and commissioning of the new system would have been the critical path on the project. In addition, the requirements for training and start-up of the new process control system would have imposed risks to obtaining maximum production after the reline outage, as operators experienced the learning curve of the new system. It was therefore decided that the critical areas of the new process control system would be installed before the reline outage. In addition, all training and start-up activities would take place on the new working system while it was operating in a `shadow` mode in parallel with the existing system. This would provide a proven process control system for blast furnace operations before the reline outage, and eliminate the learning curve after the outage. The reline outage is described.

  12. Another step towards zero waste, using pollution control residuals to make steel

    SciTech Connect (OSTI)

    Easterly, T.W.; Berquist, W.G.; Lynn, J.D.

    1997-12-31

    Environmental legislation and regulations plus the economies of disposal are directing the steel industry to look for ways of minimizing the generation of waste and to maximize the recycling of collected materials. Further, the increasing use and efficiency of end of pipe pollution controls capture ever increasing amounts of materials that were previously discharged to the environment. These newly captured pollution control dusts and sludges often have chemical or physical properties that may prevent their direct recycle into the iron and steelmaking process. This paper describes how Bethlehem Steel`s Burns Harbor Division is using a variety of material handling and recycling technologies in an integrated pollution control dust and sludge management program to recycle its daily generation of pollution control dusts and sludges. This program has been designed to be consistent with the operating requirements of the iron and steelmaking processes while insuring conformance with all environmental requirements. When fully operational, this program will reuse over 90% of the plant`s pollution control dusts and sludges to make the product steel.

  13. The effect of iron dilution on strength of nickel/steel and Monel/steel welds

    SciTech Connect (OSTI)

    Fout, S.L.; Wamsley, S.D.

    1983-03-28

    The weld strength, as a function of iron content, for nickel/steel and Monel/steel welds was determined. Samples were prepared using a Gas Metal Arc (GMAW) automatic process to weld steel plate together with nickel or Monel to produce a range of iron contents typical of weld compositions. Tensile specimens of each iron content were tested to obtain strength and ductility measurements for that weld composition. Data indicate that at iron contents of less than 20% iron in a nickel/steel weld, the weld fails at the weld interface, due to a lack of fusion. Between 20% and 35% iron, the highest iron dilution that could be achieved in a nickel weld, the welds were stronger than the steel base metal. This indicates that a minimum amount of iron dilution (20%) is necessary for good fusion and optimum strength. On the other hand for Monel/steel welds, test results showed that the welds had good strength and integrity between 10% and 27% iron in the weld. Above 35% iron, the welds have less strength and are more brittle. The 35% iron content also corresponds to the iron dilution in Monel welds that has been shown to produce an increase in corrosion rate. This indicates that the iron dilution in Monel welds should be kept below 35% iron to maximize both the strength and corrosion resistance. 2 refs., 6 figs., 3 tabs.

  14. Friction and wear in hot forging of steels

    SciTech Connect (OSTI)

    Daouben, E.; Dubar, L.; Dubar, M.; Deltombe, R.; Dubois, A.; Truong-Dinh, N.; Lazzarotto, L.

    2007-04-07

    In the field of hot forging of steels, the mastering of wear phenomena enables to save cost production, especially concerning tools. Surfaces of tools are protected thanks to graphite. The existing lubrication processes are not very well known: amount and quality of lubricant, lubrication techniques have to be strongly optimized to delay wear phenomena occurrence. This optimization is linked with hot forging processes, the lubricant layers must be tested according to representative friction conditions. This paper presents the first part of a global study focused on wear phenomena encountered in hot forging of steels. The goal is the identification of reliable parameters, in order to bring knowledge and models of wear. A prototype testing stand developed in the authors' laboratory is involved in this experimental analysis. This test is called Warm and Hot Upsetting Sliding Test (WHUST). The stand is composed of a heating induction system and a servo-hydraulic system. Workpieces taken from production can be heated until 1200 deg. C. A nitrided contactor representing the tool is heated at 200 deg. C. The contactor is then coated with graphite and rubs against the workpiece, leaving a residual track on it. Friction coefficient and surface parameters on the contactor and the workpiece are the most representative test results. The surface parameters are mainly the sliding length before defects occurrence, and the amplitude of surface profile of the contactor. The developed methodology will be first presented followed by the different parts of the experimental prototype. The results of experiment show clearly different levels of performance according to different lubricants.

  15. Crack stability analysis of low alloy steel primary coolant pipe

    SciTech Connect (OSTI)

    Tanaka, T.; Kameyama, M.; Urabe, Y.

    1997-04-01

    At present, cast duplex stainless steel has been used for the primary coolant piping of PWRs in Japan and joints of dissimilar material have been applied for welding to reactor vessels and steam generators. For the primary coolant piping of the next APWR plants, application of low alloy steel that results in designing main loops with the same material is being studied. It means that there is no need to weld low alloy steel with stainless steel and that makes it possible to reduce the welding length. Attenuation of Ultra Sonic Wave Intensity is lower for low alloy steel than for stainless steel and they have advantageous inspection characteristics. In addition to that, the thermal expansion rate is smaller for low alloy steel than for stainless steel. In consideration of the above features of low alloy steel, the overall reliability of primary coolant piping is expected to be improved. Therefore, for the evaluation of crack stability of low alloy steel piping to be applied for primary loops, elastic-plastic future mechanics analysis was performed by means of a three-dimensioned FEM. The evaluation results for the low alloy steel pipings show that cracks will not grow into unstable fractures under maximum design load conditions, even when such a circumferential crack is assumed to be 6 times the size of the wall thickness.

  16. Clean cast steel technology. Final report

    SciTech Connect (OSTI)

    Bates, C.E.; Griffin, J.A.

    1998-06-01

    This report documents the results obtained from the Clean Cast Steel Technology Program financially supported by the DOE Metal Casting Competitiveness Research Program and industry. The primary objective of this program is to develop technology for delivering steel free of oxide macroinclusions to mold cavities. The overall objective is to improve the quality of cast steel by developing and demonstrating the technology for substantially reducing surface and sub-surface oxide inclusions. Two approaches are discussed here. A total of 23 castings were produced by submerge pouring along with sixty conventionally poured castings. The submerged poured castings contained, on average, 96% fewer observable surface inclusions (11.9 vs 0.4) compared to the conventionally poured cast parts. The variation in the population of surface inclusions also decreased by 88% from 5.5 to 0.7. The machinability of the casting was also improved by submerged pouring. The submerge poured castings required fewer cutting tool changes and less operator intervention during machining. Subsequent to these trials, the foundry has decided to purchase more shrouds for continued experimentation on other problem castings where submerge pouring is possible. An examination of melting and pouring practices in four foundries has been carried out. Three of the four foundries showed significant improvement in casting quality by manipulating the melting practice. These melting practice variables can be grouped into two separate categories. The first category is the pouring and filling practice. The second category concerns the concentration of oxidizable elements contained in the steel. Silicon, manganese, and aluminum concentrations were important factors in all four foundries. Clean heats can consistently be produced through improved melting practice and reducing exposure of the steel to atmospheric oxygen during pouring and filling.

  17. Rapid heating tensile tests of hydrogen-charged high-energy-rate-forged 316L stainless steel

    SciTech Connect (OSTI)

    Mosley, W.C.

    1989-05-19

    316L stainless steel is a candidate material for construction of equipment that will be exposed to tritium. Proper design of the equipment will require an understanding of how tritium and its decay product helium affect mechanical properties. This memorandum describes results of rapid heating tensile testing of hydrogen-charged specimens of high-energy-rate-forged (HERF) 316L stainless steel. These results provide a data base for comparison with uncharged and tritium-charged-and-aged specimens to distinguish the effects of hydrogen and helium. Details of the experimental equipment and procedures and results for uncharged specimens were reported previously. 3 refs., 10 figs.

  18. Reduction in Energy Consumption & Variability in Steel Foundry Operations

    SciTech Connect (OSTI)

    Frank Peters

    2005-05-04

    This project worked to improve the efficiency of the steel casting industry by reducing the variability that occurs because of process and product variation. The project focused on the post shakeout operations since roughly half of the production costs are in this area. These improvements will reduce the amount of variability, making it easier to manage the operation and improve the competitiveness. The reduction in variability will also reduce the need for many rework operations, which will result in a direct reduction of energy usage, particularly by the reduction of repeated heat treatment operations. Further energy savings will be realized from the reduction of scrap and reduced handling. Field studies were conducted at ten steel foundries that represented the U.S. steel casting industry, for a total of over 100 weeks of production observation. These studies quantified the amount of variability, and looked toward determining the source. A focus of the data collected was the grinding operations since this is a major effort in the cleaning room, and it represents the overall casting quality. The grinding was divided into two categories, expected and unexpected. Expected grinding is that in which the location of the effort is known prior to making the casting, such as smoothing parting lines, gates, and riser contacts. Unexpected grinding, which was approximately 80% of the effort, was done to improve the surfaces at weld repair locations, to rectify burnt on sand, and other surface anomalies at random locations. Unexpected grinding represents about 80% of the grinding effort. By quantifying this effort, the project raised awareness within the industry and the industry is continuing to make improvements. The field studies showed that the amount of variation of grinding operations (normalized because of the diverse set of parts studied) was very consistent across the industry. The field studies identified several specific sources that individually contributed to

  19. Clean Steel: Advancing the State of the Art (TRP 0003)

    SciTech Connect (OSTI)

    Sridhar Seetharaman; Alan W. Cramb

    2004-05-19

    This project had 3 objectives: (1) to determine the kinetic factors governing inclusion removal from liquid steels at a slag metal interface; (2) to develop a methodology to enable steels of less than 1 ppm total oxygen to be produced with an average inclusion diameter of less than 5 {micro}m; and, (3) to determine the slag-metal interface conditions necessary for ultra clean steels. In objectives 1, and 3, the major finding was that dissolution rates of solid particles in slags were found to be significant in both ladle and tundish slags and must be included in a model to predict steel cleanliness. The work towards objective 2 indicated that liquid steel temperature was a very significant factor in our understanding of clean steel potential and that undercooled steels equilibrated with low oxygen potential inert gases have the potential to be significantly cleaner than current steels. Other work indicated that solidification front velocity could be used to push particles to produce clean steels and that reoxidation must be severely curtailed to allow the potential for clean steels to be realized.

  20. Riverside Technologies Inc | Open Energy Information

    Open Energy Info (EERE)

    Zip: 92131 Region: Southern CA Area Product: Uses scrap tires as the raw material in the production of SynBlack oil, gas, and steel Website: www.rtiworldwide.com Coordinates:...

  1. Austenitic stainless steel and drill collar

    SciTech Connect (OSTI)

    Cordea, J. N.; Jasper, J. C.; Sheth, H. V.

    1985-03-05

    A non-magnetic austenitic stainless steel, and a drill collar fabricated therefrom solely by hot forging, the steel having a 0.2% yield strength of at least 85 ksi in the hot worked condition, high stress corrosion cracking resistance, good ductility, and low magnetic permeability even if cold worked, and consisting essentially of, in weight percent, from 0.12% to 0.20% carbon, 11% to 14% manganese, about 16% to about 19% chromium, 1.5% to 2.7% nickel, 0.30% to 0.45% nitrogen, 0.5% to 1.0% copper, about 0.75% maximum molybdenum, about 0.80% maximum silicon, about 0.04% maximum phosphorus, about 0.025% maximum sulfur, and balance essentially iron, with the carbon:nitrogen ratio not greater than 0.6:1.

  2. Phase Transformation in Cast Superaustenitic Stainless Steels

    SciTech Connect (OSTI)

    Nathaniel Steven Lee Phillips

    2006-12-12

    Superaustenitic stainless steels constitute a group of Fe-based alloys that are compositionally balanced to have a purely austenitic matrix and exhibit favorable pitting and crevice corrosion resistant properties and mechanical strength. However, intermetallic precipitates such as sigma and Laves can form during casting or exposure to high-temperature processing, which degrade the corrosion and mechanical properties of the material. The goal of this study was to accurately characterize the solid-solid phase transformations seen in cast superaustenitic stainless steels. Heat treatments were performed to understand the time and temperature ranges for intermetallic phase formations in alloys CN3MN and CK3MCuN. Microstructures were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy and wavelength dispersive spectroscopy (EDS, WDS). The equilibrium microstructures, composed primarily of sigma and Laves within purely austenitic matrices, showed slow transformation kinetics. Factors that determine the extent of transformation, including diffusion, nucleation, and growth, are discussed.

  3. Welding high-molybdenum superaustenitic stainless steel

    SciTech Connect (OSTI)

    Ogawa, T.; Koseki, T.

    1996-02-01

    A high-molybdenum, nitrogen-enriched, nickel-based filler metal was developed for welding superaustenitic stainless steels. The beneficial effects of high Ni content and nitrogen addition in reducing the solute microsegregation and the precipitation of intermetallic phases were used to design the filler alloy. The weld had a precipitate-free, fully austenitic microstructure and exhibited excellent mechanical properties, and reduced hot-cracking susceptibility and high-chloride pitting-corrosion resistance.

  4. Pitting corrosion resistant austenite stainless steel

    DOE Patents [OSTI]

    van Rooyen, D.; Bandy, R.

    A pitting corrosion resistant austenite stainless steel comprises 17 to 28 wt. % chromium, 15 to 26 wt. % nickel, 5 to 8 wt. % molybdenum, and 0.3 to 0.5 wt. % nitrogen, the balance being iron, unavoidable impurities, minor additions made in the normal course of melting and casting alloys of this type, and may optionally include up to 10 wt. % of manganese, up to 5 wt. % of silicon, and up to 0.08 wt. % of carbon.

  5. Heat Treatment Procedure Qualification for Steel Castings

    SciTech Connect (OSTI)

    Mariol Charles; Nicholas Deskevich; Vipin Varkey; Robert Voigt; Angela Wollenburg

    2004-04-29

    Heat treatment practices used by steel foundries have been carefully studied as part of comprehensive heat treatment procedure qualification development trials. These studies highlight the relationships between critical heat treatment process control parameters and heat treatment success. Foundry heat treatment trials to develop heat treatment procedure qualifications have shed light on the relationship between heat treatment theory and current practices. Furnace load time-temperature profiles in steel foundries exhibit significant differences depending on heat treatment equipment, furnace loading practice, and furnace maintenance. Time-temperature profiles of furnace control thermocouples can be very different from the time-temperature profiles observed at the center of casting loads in the furnace. Typical austenitization temperatures and holding times used by steel foundries far exceed what is required for transformation to austenite. Quenching and hardenability concepts were also investigated. Heat treatment procedure qualification (HTPQ) schema to demonstrate heat treatment success and to pre-qualify other alloys and section sizes requiring lesser hardenability have been developed. Tempering success is dependent on both tempering time and temperature. As such, furnace temperature uniformity and control of furnace loading during tempering is critical to obtain the desired mechanical properties. The ramp-up time in the furnace prior to the establishment of steady state heat treatment conditions contributes to the extent of heat treatment performed. This influence of ramp-up to temperature during tempering has been quantified.

  6. Cast Stainless Steel Ferrite and Grain Structure

    SciTech Connect (OSTI)

    Ruud, Clayton O.; Ramuhalli, Pradeep; Meyer, Ryan M.; Mathews, Royce; Diaz, Aaron A.; Anderson, Michael T.

    2012-09-01

    In-service inspection requirements dictate that piping welds in the primary pressure boundary of light-water reactors be subject to a volumetric examination based on the rules contained within the American Society of Mechanical Engineers Boiler and Pressure Vessel Code, Section XI. The purpose of the inspection is the reliable detection and accurate sizing of service-induced degradation and/or material flaws introduced during fabrication. The volumetric inspection is usually carried out using ultrasonic testing (UT) methods. However, the varied metallurgical macrostructures and microstructures of cast austenitic stainless steel piping and fittings, including statically cast stainless steel and centrifugally cast stainless steel (CCSS), introduce significant variations in the propagation and attenuation of ultrasonic energy. These variations complicate interpretation of the UT responses and may compromise the reliability of UT inspection. A review of the literature indicated that a correlation may exist between the microstructure and the delta ferrite content of the casting alloy. This paper discusses the results of a recent study where the goal was to determine if a correlation existed between measured and/or calculated ferrite content and grain structure in CCSS pipe.

  7. Raman Lidar Profiles–Temperature (RLPROFTEMP) Value-Added Product

    SciTech Connect (OSTI)

    Newsom, RK; Sivaraman, C; McFarlane, SA

    2012-10-31

    The purpose of this document is to describe the Raman Lidar Profiles–Temperature (RLPROFTEMP) value-added product (VAP) and the procedures used to derive atmospheric temperature profiles from the raw RL measurements. Sections 2 and 4 describe the input and output variables, respectively. Section 3 discusses the theory behind the measurement and the details of the algorithm, including calibration and overlap correction.

  8. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H.

    1996-12-31

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  9. Safety analysis report for packaging (onsite) steel drum

    SciTech Connect (OSTI)

    McCormick, W.A.

    1998-09-29

    This Safety Analysis Report for Packaging (SARP) provides the analyses and evaluations necessary to demonstrate that the steel drum packaging system meets the transportation safety requirements of HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments, for an onsite packaging containing Type B quantities of solid and liquid radioactive materials. The basic component of the steel drum packaging system is the 208 L (55-gal) steel drum.

  10. Cast Stainless Steel Aging Research Plan | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cast Stainless Steel Aging Research Plan Cast Stainless Steel Aging Research Plan This work plan proposes to build a systematic knowledge base for the thermal aging behavior of cast stainless steels (CASSs) within a limited time of five years. The final output of execution of the plan is expected to provide conclusive predictions for the integrity of the CASS components of LWR power plants during the extended service life up to and beyond 60 years. Mechanical and microstructural data obtained

  11. DOE - Office of Legacy Management -- Superior Steel Co - PA 03

    Office of Legacy Management (LM)

    Superior Steel Co - PA 03 FUSRAP Considered Sites Superior Steel, PA Alternate Name(s): Copper Weld, Inc. Superbolt Location: Carnegie, Pennsylvania PA.03-1 Historical Operations: Milled uranium metal for AEC. PA.03-4 Eligibility Determination: Eligible Radiological Survey(s): Assessment Survey PA.03-4 Site Status: Cleanup in progress by U.S. Army Corps of Engineers. USACE Website Long-term Care Requirements: To be determined upon completion. Also see Documents Related to Superior Steel, PA

  12. CERTIFICATION DOCKET FOR AL-TECHSPECIALTY STEEL CORPORATION

    Office of Legacy Management (LM)

    AL-TECHSPECIALTY STEEL CORPORATION (THEFoRMERALLEGHENY-LUDLUMSTEELCORPORATION) WATERVLIET,NEWYORK,ANDOFFSITEPROPER?YIN DUNKIRK,NEWYORK Department of Energy Office of Nuciear Energy Office of Terminal Waste Disposal and Remedial Action Division of Remedial Action Projects CONTENTS Page Introduction to the Certification Docket for the Al-Tech Specialty Steel Corporation, (the Former Allegheny-Ludlum Steel Corporation) Watervliet, New York, and Offsite Property in Dunkirk, New York Purpose Docket

  13. After record sales and production, international met markets plummet

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2009-03-15

    After surging in 2007 and most of 2008, both the demand and the pricing for coal collapsed in 2008's final quarter. The article discusses last year's market and gives some predictions on 2009's production and prices. The National Mining Association predicts that production of coking coal will fall 11% due to plunging demand for steel. 4 photos.

  14. Aging Management Program for Stainless Steel Dry Storage System Canisters

    SciTech Connect (OSTI)

    Dunn, Darrell S.; Lin, Bruce P.; Meyer, Ryan M.; Anderson, Michael T.

    2015-06-01

    This is a conference paper presenting an aging management program for stainless steel dry storage system canisters. NRC is lead author of paper. PNNL provided input.

  15. Post-Test Metallurgical Evaluation Results for Steel Containment...

    Office of Scientific and Technical Information (OSTI)

    Post-Test Metallurgical Evaluation Results for Steel Containment Vessel (SCV) High Pressure Test Citation Details In-Document Search Title: Post-Test Metallurgical Evaluation ...

  16. Formability Characterization of a New Generation High Strength Steels

    SciTech Connect (OSTI)

    Sriram Sadagopan; Dennis Urban; Chris Wong; Mai Huang; Benda Yan

    2003-05-16

    Advanced high strength steels (AHSS) are being progressively explored by the automotive industry all around the world for cost-effective solutions to accomplish vehicle lightweighting, improve fuel economy, and consequently reduce greenhouse emissions. Because of their inherent high strength, attractive crash energy management properties, and good formability, the effective use of AHSS such as Duel Phase and TRIP (Transformation Induced Plasticity) steels, will significantly contribute to vehicle lightweighting and fuel economy. To further the application of these steels in automotive body and structural parts, a good knowledge and experience base must be developed regarding the press formability of these materials. This project provides data on relevant intrinsic mechanical behavior, splitting limits, and springback behavior of several lots of mild steel, conventional high strength steel (HSS), advanced high strength steel (AHSS) and ultra-high strength steel (UHSS), supplied by the member companies of the Automotive Applications Committee (AAC) of the American Iron and Steel Institute (AISI). Two lots of TRIP600, which were supplied by ThyssenKrupp Stahl, were also included in the study. Since sheet metal forming encompasses a very diverse range of forming processes and deformation modes, a number of simulative tests were used to characterize the forming behavior of these steel grades. In general, it was found that formability, as determined by the different tests, decreased with increased tensile strength. Consistant with previous findings, the formability of TRIP600 was found to be exceptionally good for its tensile strength.

  17. Steele County, North Dakota: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    North Dakota M Power LLC Places in Steele County, North Dakota Finley, North Dakota Hope, North Dakota Luverne, North Dakota Sharon, North Dakota Retrieved from "http:...

  18. Bandwidth Study U.S. Advanced High Strength Steel Manufacturing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The study examines energy consumption and potential energy savings opportunities in advanced high strength steel manufacturing in the U.S. The study relies on multiple sources to ...

  19. Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation...

    Broader source: Energy.gov (indexed) [DOE]

    Barriers: Hydrogen embrittlement of pipelines and remediation (mixing with water vapor?) ... Enable a Carbon-Neutral Energy Economy Hydrogen Embrittlement of Pipeline Steels: Causes ...

  20. Wear-Resistant, Nano-Composite Steel Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wear-Resistant, Nano-Composite Steel Coatings Laser Processing Techniques Used for the ... wear resistant nano-composite coatings and components for a wide range of applications. ...

  1. Development of 3rd Generation Advanced High Strength Steels ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an Integrated Experimental and Simulation Approach QUENCHING AND PARTITIONING PROCESS DEVELOPMENT TO REPLACE HOT STAMPING OF HIGH STRENGTH AUTOMOTIVE STEEL Vehicle Technologies ...

  2. Predicting sigma formation in mo-bearing stainless steels. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Title: Predicting sigma formation in mo-bearing stainless steels. No abstract prepared. Authors: Perricone, Matthew ; Dupont, John Neuman ; Anderson, T. D. 1 ; Robino, Charles ...

  3. Results of Stainless Steel Canister Corrosion Studies and Environmenta...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Data Report on Corrosion Testing of Stainless Steel SNF Storage Canisters Status Report: Characterization of Weld Residual Stresses on Full Diameter ...

  4. Study of Caustic Corrosion of Carbon Steel Waste Tanks (Conference...

    Office of Scientific and Technical Information (OSTI)

    Because the total test period for start up is relatively short, penetration will not ... In summary, the test results indicate that the corrosion rates for steel are acceptable ...

  5. Fuel from farms: a guide to small-scale ethanol production

    SciTech Connect (OSTI)

    1980-02-01

    A guide on fermentation processes with emphasis on small-scale production of ethanol using farm crops as a source of raw material is published. The current status of on-farm ethanol production as well as an overview of some of the technical and economic factors is presented. Decision and planning worksheets and a sample business plan for use in decision making are included. Specifics in production including information on the raw materials, system components, and operational requirements are also provided. Diagrams of fermentors and distilling apparatus are included. (DC)

  6. Bioconversion of waste biomass to useful products

    DOE Patents [OSTI]

    Grady, James L.; Chen, Guang Jiong

    1998-01-01

    A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, bacillus smithii ATCC No. 55404.

  7. Bioconversion of waste biomass to useful products

    DOE Patents [OSTI]

    Grady, J.L.; Chen, G.J.

    1998-10-13

    A process is provided for converting waste biomass to useful products by gasifying the biomass to produce synthesis gas and converting the synthesis gas substrate to one or more useful products. The present invention is directed to the conversion of biomass wastes including municipal solid waste, sewage sludge, plastic, tires, agricultural residues and the like, as well as coal, to useful products such as hydrogen, ethanol and acetic acid. The overall process includes the steps of gasifying the waste biomass to produce raw synthesis gas, cooling the synthesis gas, converting the synthesis gas to the desired product or products using anaerobic bioconversion, and then recovering the product or products. In accordance with a particular embodiment of the present invention, waste biomass is converted to synthesis gas containing carbon monoxide and, then, the carbon monoxide is converted to hydrogen by an anaerobic microorganism ERIH2, Bacillus smithii ATCC No. 55404. 82 figs.

  8. ITP Steel: Energy and Environmental Profile fo the U.S. Iron...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy and Environmental Profile fo the U.S. Iron and Steel Industry ITP Steel: Energy and Environmental Profile fo the U.S. Iron and Steel Industry steelprofile.pdf (581.28 KB) ...

  9. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    SciTech Connect (OSTI)

    Worrell, Ernst; Blinde, Paul; Neelis, Maarten; Blomen, Eliane; Masanet, Eric

    2010-10-21

    Energy is an important cost factor in the U.S iron and steel industry. Energy efficiency improvement is an important way to reduce these costs and to increase predictable earnings, especially in times of high energy price volatility. There are a variety of opportunities available at individual plants in the U.S. iron and steel industry to reduce energy consumption in a cost-effective manner. This Energy Guide discusses energy efficiency practices and energy-efficient technologies that can be implemented at the component, process, facility, and organizational levels. A discussion of the structure, production trends, energy consumption, and greenhouse gas emissions of the iron and steel industry is provided along with a description of the major process technologies used within the industry. Next, a wide variety of energy efficiency measures are described. Many measure descriptions include expected savings in energy and energy-related costs, based on case study data from real-world applications in the steel and related industries worldwide. Typical measure payback periods and references to further information in the technical literature are also provided, when available. The information in this Energy Guide is intended to help energy and plant managers in the U.S. iron and steel industry reduce energy consumption and greenhouse gas emissions in a cost-effective manner while maintaining the quality of products manufactured. Further research on the economics of all measures?and on their applicability to different production practices?is needed to assess their cost effectiveness at individual plants.

  10. Steel Market Development Institute Awards "Community Hero" Award to the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office | Department of Energy Steel Market Development Institute Awards "Community Hero" Award to the Vehicle Technologies Office Steel Market Development Institute Awards "Community Hero" Award to the Vehicle Technologies Office February 11, 2016 - 4:24pm Addthis Steel Market Development Institute Men and Women of Steel Awardees Steel Market Development Institute Men and Women of Steel Awardees At the 2016 North American International Auto Show in

  11. Development of Advanced 9Cr Ferritic-Martensitic Steels and Austenitic Stainless Steels for Sodium-Cooled Fast Reactor

    SciTech Connect (OSTI)

    Sham, Sam; Tan, Lizhen; Yamamoto, Yukinori

    2013-01-01

    Ferritic-martensitic (FM) steel Grade 92, with or without thermomechanical treatment (TMT), and austenitic stainless steels HT-UPS (high-temperature ultrafine precipitate strengthening) and NF709 were selected as potential candidate structural materials in the U.S. Sodium-cooled Fast Reactor (SFR) program. The objective is to develop advanced steels with improved properties as compared with reference materials such as Grade 91 and Type 316H steels that are currently in nuclear design codes. Composition modification and/or processing optimization (e.g., TMT and cold-work) were performed to improve properties such as resistance to thermal aging, creep, creep-fatigue, fracture, and sodium corrosion. Testings to characterize these properties for the advanced steels were conducted by the Idaho National Laboratory, the Argonne National Laboratory and the Oak Ridge National Laboratory under the U.S. SFR program. This paper focuses on the resistance to thermal aging and creep of the advanced steels. The advanced steels exhibited up to two orders of magnitude increase in creep life compared to the reference materials. Preliminary results on the weldment performance of the advanced steels are also presented. The superior performance of the advanced steels would improve reactor design flexibility, safety margins and economics.

  12. Energy Saving Melting and Revert Reduction (E-SMARRT): Precision Casting of Steel

    SciTech Connect (OSTI)

    Dr. Von L. Richards

    2011-09-30

    This project addresses improvements in metal casting processes by reducing scrap and reducing the cost of production, due to scrap reduction from investment casting and yield improvement offered by lost foam casting as compared to no-bake or green sand molding. The objectives for the investment casting portion of the subtask are to improve knowledge of fracture toughness of mold shells and the sources of strength limiting flaws and to understand the effects of wax reclamation procedures on wax properties. Applying 'clean steel' approaches to pouring technology and cleanliness in investment casting of steel are anticipated to improve incoming materials inspection procedures as they affect the microstructure and toughness of the shell. This project focused on two areas of study in the production of steel castings to reduce scrap and save energy: (1) Reducing the amount of shell cracking in investment cast steel production; (2) Investigate the potential of lost foam steel casting The basic findings regarding investment casting shell cracking were: (1) In the case of post pouring cracking, this could be related to phase changes in silica upon cooling and could be delayed by pouring arrangement strategies that maintained the shell surface at temperature for longer time. Employing this delay resulted in less adherent oxidation of castings since the casting was cooler at the time o fair exposure. (2) A model for heat transfer through water saturated shell materials under steam pressure was developed. (3) Initial modeling result of autoclave de-waxing indicated the higher pressure and temperature in the autoclave would impose a steeper temperature gradient on the wax pattern, causing some melt flow prior to bulk expansion and decreasing the stress on the green shell. Basic findings regarding lost foam casting of steel at atmospheric pressure: (1) EPS foam generally decomposes by the collapse mode in steel casting. (2) There is an accumulation of carbon pick-up at the end

  13. Further development of the cleanable steel HEPA filter, cost/benefit analysis, and comparison with competing technologies

    SciTech Connect (OSTI)

    Bergman, W.; Larsen, G.; Lopez, R.; Wilson, K.; Witherell, C.; McGregor, M.

    1997-01-01

    We have made further progress in developing a cleanable steel fiber HEPA filter. We fabricated a pleated cylindrical cartridge using commercially available steel fiber media that is made with 1 {mu}m stainless steel fibers and sintered into a sheet form. Test results at the Department of Energy (DOE) Filter Test Station at Oak Ridge show the prototype filter cartridge has 99.99% efficiency for 0.3 {mu}m dioctyl phthalate (DOP) aerosols and a pressure drop of 1.5 inches. Filter loading and cleaning tests using AC Fine dust showed the filter could be repeatedly cleaned using reverse air pulses. Our analysis of commercially optimized filters suggest that cleanable steel HEPA filters need to be made from steel fibers less than 1 {mu}m, and preferably 0.5 {mu}m, to meet the standard HEPA filter requirements in production units. We have demonstrated that 0.5 {mu}m steel fibers can be produced using the fiber bundling and drawing process. The 0.5 {mu}m steel fibers are then sintered into small filter samples and tested for efficiency and pressure drop. Test results on the sample showed a penetration of 0.0015% at 0.3 {mu}m and a pressure drop of 1.15 inches at 6.9 ft/min (3.5 cm/s) velocity. Based on these results, steel fiber media can easily meet the requirements of 0.03% penetration and 1.0 inch of pressure drop by using less fibers in the media. A cost analysis of the cleanable steel HEPA filter shows that, although the steel HEPA filter costs much more than the standard glass fiber HEPA filter, it has the potential to be very cost effective because of the high disposal costs of contaminated HEPA filters. We estimate that the steel HEPA filter will save an average of $16,000 over its 30 year life. The additional savings from the clean-up costs resulting from ruptured glass HEPA filters during accidents was not included but makes the steel HEPA filter even more cost effective. We also present the results of our evaluation of competing technologies with metallic and

  14. Weldability of an abrasion-resistant steel

    SciTech Connect (OSTI)

    Adonyi, Y.; Domis, W.F.; Chen, C.C.

    1995-12-31

    The welding performance of a low-carbon-equivalent, abrasion-resistant steel newly developed for the mining industry was studied using a combination of simulative and actual weldability tests. The susceptibility to hydrogen-induced cracking in the weld-metal and heat-affected zones (HAZ), as well as the potential loss of strength and toughness in the HAZ, were evaluated. Simulative testing included the use of the Gleeble 1500 thermomechanical simulator to produce single and multiple-pass weld HAZ microstructures on CVN-size specimens. The effects of heat input, interpass temperature, and post-weld heat treatment (PWHT) on the HAZ microstructure and properties were determined. Additionally, a computer software was used to predict theoretical HAZ hardnesses and volume fraction of phases as a function of cooling rates. The actual welding tests included the Gapped Bead-on-Plate and the Y-groove tests to determine the weld-metal and HAZ susceptibility to hydrogen-induced cracking. Three heat inputs, two diffusible hydrogen and two weld-metal yield-strength levels were used for the actual welding stage. Good correlation was found between microstructure predictions, physical simulations, and actual weld testing results. The new steel was found to be highly weldable because of the low preheat required to avoid HAZ hydrogen induced cracking. All aspects of weld-metal and HAZ cracking behavior had to be addressed for a complete weldability characterization. It was also found that use of excessive heat inputs and PWHT should be avoided when welding this type of steels.

  15. Reduction of VOC emissions from metal dip coating applications -- Canam Steel Corporation Point of Rocks, MD case study

    SciTech Connect (OSTI)

    Monfet, J.P.

    1997-12-31

    The reduction of VOC emissions from metal dip coating applications is not an environmental constraint, it is an economic opportunity. This case study shows how the industry can reap economic benefits from VOC reductions while improving air quality. The Canam Steel Corporation plant located in Point of Rocks, MD operates dip tanks for primer application on fabricated steel joists and joist girders. This process is presently subject to a regulation that limits the paint VOC content to 3.5 pounds per gallon of coating less water. As a result of the high paint viscosity associated with that regulation, the paint thickness of the dipped steel is thicker than the customers` specifications. Most of the VOC emissions can therefore be associated with the excess of paint applied to the products rather than to the required thickness of the coating. The higher paint usage rate has more than environmental consequences, it increases the cost of the applied coating. The project is to reduce the paint usage by controlling the viscosity of the coating in the tank. Experimental results as well as actual mass balance calculations show that using a higher VOC content paint would reduce the overall VOC emissions. The author explained the project to the Maryland Department of the Environment (MDE) Air and Radiation Management Administration. First, the MDE agreed to develop a new RACT determination for fabricated steel dipping operations. The new regulation would limit the amount of VOC than can be emitted to dip coat a ton of fabricated steel. Second, the MDE agreed to allow experimentation of the higher VOC content paint as a pilot project for the new regulation. This paper demonstrates the need for a RACT determination specific to fabricated steel dipping operations.

  16. SOLID STATE JOINING OF MAGNESIUM TO STEEL

    SciTech Connect (OSTI)

    Jana, Saumyadeep; Hovanski, Yuri; Pilli, Siva Prasad; Field, David P.; Yu, Hao; Pan, Tsung-Yu; Santella, M. L.

    2012-06-04

    Friction stir welding and ultrasonic welding techniques were applied to join automotive magnesium alloys to steel sheet. The effect of tooling and process parameters on the post-weld microstructure, texture and mechanical properties was investigated. Static and dynamic loading were utilized to investigate the joint strength of both cast and wrought magnesium alloys including their susceptibility and degradation under corrosive media. The conditions required to produce joint strengths in excess of 75% of the base metal strength were determined, and the effects of surface coatings, tooling and weld parameters on weld properties are presented.

  17. Automated inspection of hot steel slabs

    DOE Patents [OSTI]

    Martin, R.J.

    1985-12-24

    The disclosure relates to a real time digital image enhancement system for performing the image enhancement segmentation processing required for a real time automated system for detecting and classifying surface imperfections in hot steel slabs. The system provides for simultaneous execution of edge detection processing and intensity threshold processing in parallel on the same image data produced by a sensor device such as a scanning camera. The results of each process are utilized to validate the results of the other process and a resulting image is generated that contains only corresponding segmentation that is produced by both processes. 5 figs.

  18. Automated inspection of hot steel slabs

    DOE Patents [OSTI]

    Martin, Ronald J.

    1985-01-01

    The disclosure relates to a real time digital image enhancement system for performing the image enhancement segmentation processing required for a real time automated system for detecting and classifying surface imperfections in hot steel slabs. The system provides for simultaneous execution of edge detection processing and intensity threshold processing in parallel on the same image data produced by a sensor device such as a scanning camera. The results of each process are utilized to validate the results of the other process and a resulting image is generated that contains only corresponding segmentation that is produced by both processes.

  19. Method for machining steel with diamond tools

    DOE Patents [OSTI]

    Casstevens, J.M.

    1984-01-01

    The present invention is directed to a method for machine optical quality finishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

  20. Method for machining steel with diamond tools

    DOE Patents [OSTI]

    Casstevens, John M.

    1986-01-01

    The present invention is directed to a method for machining optical quality inishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

  1. Clean Cast Steel Technology - Machinability and Technology Transfer

    SciTech Connect (OSTI)

    C. E. Bates; J. A. Griffin

    2000-05-01

    There were two main tasks in the Clean Cast Steel Technology - Machinability and Technology Transfer Project. These were (1) determine the processing facts that control the machinability of cast steel and (2) determine the ability of ladle stirring to homogenize ladle temperature, reduce the tap and pouring temperatures, and reduce casting scrap.

  2. The limit of strength and toughness of steel

    SciTech Connect (OSTI)

    Guo, Zhen

    2001-12-17

    The ideal structural steel combines high strength with high fracture toughness. This dissertation discusses the governing principles of strength and toughness, along with the approaches that can be used to improve these properties and the inherent limits to how strong and tough a steel can be.

  3. Steamside Oxidation Behavior of Experimental 9%Cr Steels

    SciTech Connect (OSTI)

    Dogan, O.N.; Holcomb, G.R.; Alman, D.E.; Jablonski, P.D.

    2007-10-01

    Reducing emissions and increasing economic competitiveness require more efficient steam power plants that utilize fossil fuels. One of the major challenges in designing these plants is the availability of materials that can stand the supercritical and ultra-supercritical steam conditions at a competitive cost. There are several programs around the world developing new ferritic and austenitic steels for superheater and reheater tubes exposed to the advanced steam conditions. The new steels must possess properties better than current steels in terms of creep strength, steamside oxidation resistance, fireside corrosion resistance, and thermal fatigue resistance. This paper introduces a series of experimental 9%Cr steels containing Cu, Co, and Ti. Stability of the phases in the new steels is discussed and compared to the phases in the commercially available materials. The steels were tested under both the dry and moist conditions at 650C for their cyclical oxidation resistance. Results of oxidation tests are presented. Under the moist conditions, the experimental steels exhibited significantly less mass gain compared to the commercial P91 steel. Microstructural characterization of the scale revealed different oxide compositions.

  4. Corrosion protection of steel in ammonia/water heat pumps

    DOE Patents [OSTI]

    Mansfeld, Florian B.; Sun, Zhaoli

    2003-10-14

    Corrosion of steel surfaces in a heat pump is inhibited by adding a rare earth metal salt to the heat pump's ammonia/water working fluid. In preferred embodiments, the rare earth metal salt includes cerium, and the steel surfaces are cerated to enhance the corrosion-inhibiting effects.

  5. Theoretical minimum energies to produce steel for selected conditions

    SciTech Connect (OSTI)

    Fruehan, R. J.; Fortini, O.; Paxton, H. W.; Brindle, R.

    2000-03-01

    An ITP study has determined the theoretical minimum energy requirements for producing steel from ore, scrap, and direct reduced iron. Dr. Richard Fruehan's report, Theoretical Minimum Energies to Produce Steel for Selected Conditions, provides insight into the potential energy savings (and associated reductions in carbon dioxide emissions) for ironmaking, steelmaking, and rolling processes (PDF459 KB).

  6. Influence of Cooling Rate on Phase Formationin Spray-Formed H13 Tool Steel

    SciTech Connect (OSTI)

    K. M. Mchugh; Y. Lin; Y. Zhou; E. J. Lavernia

    2006-04-01

    Spray forming is an effective way to process many tool steels into near-net-shape molds, dies and related tooling. The general approach involves depositing atomized droplets onto a refractory pattern in order to image the patterns features. The pattern is removed and the die is fitted into a standard holding fixture. This approach results in significant cost and lead-time savings compared to conventional machining, Spray-formed dies perform well in many industrial forming operations, oftentimes exhibiting extended die life over conventional dies. Care must be exercised when spray forming tool steel dies to minimize porosity and control the nature and distribution of phases and residual stresses. Selection of post-deposition heat treatment is important to tailor the dies properties (hardness, strength, impact energy, etc.) for a particular application. This paper examines how the cooling rate and other processing parameters during spray processing and heat treatment of H13 tool steel influence phase formation. Results of case studies on spray-formed die performance in forging, extrusion and die casting, conducted by industry during production runs, will be described.

  7. Simulation of Distortion and Residual Stress Development During Heat Treatment of Steel Castings

    SciTech Connect (OSTI)

    Beckermann, Christoph; Carlson, Kent

    2011-07-22

    Heat treatment and associated processing, such as quenching, are critical during high strength steel casting production. These processes must be managed closely to prevent thermal and residual stresses that may result in distortion, cracking (particularly after machining), re-work, and weld repair. The risk of casting distortion limits aggressive quenching that can be beneficial to the process and yield an improved outcome. As a result of these distortions, adjustments must be made to the casting or pattern design, or tie bars must be added. Straightening castings after heat treatments can be both time-consuming and expensive. Residual stresses may reduce a casting's overall service performance, possibly resulting in catastrophic failure. Stress relieving may help, but expends additional energy in the process. Casting software is very limited in predicting distortions during heat treatment, so corrective measures most often involve a tedious trial-and-error procedure. An extensive review of existing heat treatment residual stress and distortion modeling revealed that it is vital to predict the phase transformations and microstructure of the steel along with the thermal stress development during heat treatment. After reviewing the state-of-the-art in heat treatment residual stress and distortion modeling, an existing commercial code was selected because of its advanced capabilities in predicting phase transformations, the evolving microstructure and related properties along with thermal stress development during heat treatment. However, this software was developed for small parts created from forgings or machined stock, and not for steel castings. Therefore, its predictive capabilities for heat treatment of steel castings were investigated. Available experimental steel casting heat treatment data was determined to be of insufficient detail and breadth, and so new heat treatment experiments were designed and performed, casting and heat treating modified versions of

  8. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    SciTech Connect (OSTI)

    Hasanbeigi, Ali; Morrow, William; Sathaye, Jayant; Masanet, Eric; Xu, Tengfang

    2012-05-15

    China’s annual crude steel production in 2010 was 638.7 Mt accounting for nearly half of the world’s annual crude steel production in the same year. Around 461 TWh of electricity and 14,872 PJ of fuel were consumed to produce this quantity of steel in 2010. We identified and analyzed 23 energy efficiency technologies and measures applicable to the processes in the iron and steel industry. The Conservation Supply Curve (CSC) used in this study is an analytical tool that captures both the engineering and the economic perspectives of energy conservation. Using a bottom-up electricity CSC model, the cumulative cost-effective electricity savings potential for the Chinese iron and steel industry for 2010-2030 is estimated to be 251 TWh, and the total technical electricity saving potential is 416 TWh. The CO2 emissions reduction associated with cost-effective electricity savings is 139 Mt CO2 and the CO2 emission reduction associated with technical electricity saving potential is 237 Mt CO2. The FCSC model for the iron and steel industry shows cumulative cost-effective fuel savings potential of 11,999 PJ, and the total technical fuel saving potential is 12,139. The CO2 emissions reduction associated with cost-effective and technical fuel savings is 1,191 Mt CO2 and 1,205 Mt CO2, respectively. In addition, a sensitivity analysis with respect to the discount rate used is conducted to assess the effect of changes in this parameter on the results. The result of this study gives a comprehensive and easy to understand perspective to the Chinese iron and steel industry and policy makers about the energy efficiency potential and its associated cost.

  9. Cast alumina forming austenitic stainless steels

    DOE Patents [OSTI]

    Muralidharan, Govindarajan; Yamamoto, Yukinori; Brady, Michael P

    2013-04-30

    An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.

  10. Wrought stainless steels -- Dual marking and corrosion evaluation

    SciTech Connect (OSTI)

    Kobrin, G.; Lilly, J.; MacDiarmid, J.; Moniz, B.

    1999-10-01

    Prior to the 1980s, the commonly used type 300 austenitic series stainless steels (SS) in the chemical process industry were available in two grades: those with regular carbon content (straight grades) and those with extra-low carbon content (L-grades). When welding the straight grades, it was possible to sensitize the base metal adjacent to the weld. The carbon combines with the chromium at the grain boundaries, leaving a zone depleted of chromium, below the minimum required for SS, adjacent to the grain boundaries. Even a relatively mild corrosive environment then is able to selectively attack this region along grain boundaries. The dual-marked grades (types 304/304L and 316/316L) appeared, with the carbon content of an L-grade and the strength of a straight grade. Initially, there was no national code acceptance for dual marked grades. Designers were obliged to use L-grade stress values. To get around this, people were known to grind off the unacceptable part of the dual marking designation and deliver whatever grade was initially specified. ASME International now has formally stated that dual-marked grades may be used at straight grade stresses for all product forms and piping to 1,000 F (540 C).

  11. Pitting of iron and carbon steel in mixtures of methanol-water

    SciTech Connect (OSTI)

    Pischik, L.M.; Novitskii, V.S.; Lysak, T.A.

    1987-01-01

    Since the technological media used for the production of methanol contains dissolved carbon dioxide and trace quantities of formic acid, pit formation on Armco iron (State Standard (GOST) 3836-73) and carbon steel St 3 (GOST 390-71) was studied in pure mixtures of rectified methanol and water in the presence of CO/sub 2/ at 30/sup 0/ and 60/sup 0/. This was done in order to determine the nature and concentration of active components and also to see what were the effects of water (5-30% by mass), metal purity, and temperature on the kinetic parameters of pit formation.

  12. Residual Stresses in 21-6-9 Stainless Steel Warm Forgings

    SciTech Connect (OSTI)

    Everhart, Wesley A.; Lee, Jordan D.; Broecker, Daniel J.; Bartow, John P.; McQueen, Jamie M.; Switzner, Nathan T.; Neidt, Tod M.; Sisneros, Thomas A.; Brown, Donald W.

    2012-11-14

    Forging residual stresses are detrimental to the production and performance of derived machined parts due to machining distortions, corrosion drivers and fatigue crack drivers. Residual strains in a 21-6-9 stainless steel warm High Energy Rate Forging (HERF) were measured via neutron diffraction. The finite element analysis (FEA) method was used to predict the residual stresses that occur during forging and water quenching. The experimentally measured residual strains were used to calibrate simulations of the three-dimensional residual stress state of the forging. ABAQUS simulation tools predicted residual strains that tend to match with experimental results when varying yield strength is considered.

  13. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J.

    1995-12-01

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  14. INHIBITION OF STRESS CORROSION CRACKING OF CARBON STEEL STORAGE TANKS AT HANFORD

    SciTech Connect (OSTI)

    BOOMER, K.D.

    2007-01-31

    The stress corrosion cracking (SCC) behavior of A537 tank steel was investigated in a series of environments designed to simulate the chemistry of legacy nuclear weapons production waste. Tests consisted of both slow strain rate tests using tensile specimens and constant load tests using compact tension specimens. Based on the tests conducted, nitrite was found to be a strong SCC inhibitor. Based on the test performed and the tank waste chemistry changes that are predicted to occur over time, the risk for SCC appears to be decreasing since the concentration of nitrate will decrease and nitrite will increase.

  15. The recycling of waste oxides at Great Lakes Division, National Steel Corporation

    SciTech Connect (OSTI)

    Landow, M.P.; Martinez, M.; Barnett, T.

    1997-12-31

    This paper describes the design, construction, and startup operations of a briquetting plant to recycle the revert dust, sludges and other materials generated from the iron and steelmaking processes. The specific plant constructed for National Steel Corporation`s Great Lakes Division was designed to recycle 273,000 metric tons (300,000 net tons) of integrated steel plant revert materials, such as BOP dust, blast furnace flue dust and sludge, and mill scale. The majority of the briquette plant production, about 80 percent, will recycle through the blast furnace and the remaining 20 percent through the steelmaking furnaces. This paper discusses the criteria used for plant design, construction, and startup. The plant design and construction period was 12 months with construction during the last 33 week period. The startup of the plant proceeded extremely well with the ramping up of production rates faster than the proposed startup plan. In addition, the blast furnace production was initiated using a newly developed blast furnace binder.

  16. Project W-519 CDR supplement: Raw water and electrical services for privatization contractor, AP tank farm operations

    SciTech Connect (OSTI)

    Parazin, R.J.

    1998-07-31

    This supplement to the Project W-519 Conceptual Design will identify a means to provide RW and Electrical services to serve the needs of the TWRS Privatization Contractor (PC) at AP Tank Farm as directed by DOE-RL. The RW will serve the fire suppression and untreated process water requirements for the PC. The purpose of this CDR supplement is to identify Raw Water (RW) and Electrical service line routes to the TWRS Privatization Contractor (PC) feed delivery tanks, AP-106 and/or AP-108, and establish associated cost impacts to the Project W-519 baseline.

  17. Phase Transformations in Cast Duplex Stainless Steels

    SciTech Connect (OSTI)

    Yoon-Jun Kim

    2004-12-19

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  18. Hydrostatic Microextrusion of Steel and Copper

    SciTech Connect (OSTI)

    Berti, Guido; Monti, Manuel; D'Angelo, Luciano

    2011-05-04

    The paper presents an experimental investigation based on hydrostatic micro extrusion of billets in low carbon steel and commercially pure copper, and the relevant results. The starting billets have a diameter of 0.3 mm and are 5 mm long; a high pressure generator consisting of a manually operated piston screw pump is used to pressurize the fluid up to 4200 bar, the screw pump is connected through a 3-way distribution block to the extrusion die and to a strain gauge high pressure sensor. The sensor has a full scale of 5000 bar and the extrusion pressure is acquired at a sampling rate of 2 kHz by means of an acquisition program written in the LabVIEW environment. Tests have been conducted at room temperature and a lubricant for wire drawing (Chemetall Gardolube DO 338) acts both as the pressurizing fluid and lubricant too. In addition, billets were graphite coated. Different fluid pressures and process durations have been adopted, resulting in different extrusion lengths. The required extrusion pressure is much higher than in non-micro forming operations (this effect is more evident for steel). On the cross section of the extruded parts, hardness and grain size distribution have been measured, the former through Vickers micro hardness (10 g load) tests. In the case of the extrusion of copper, the material behaves as in microdrawing process. In the case of the extrusion of steel, the hardness increases from the core to the surface as in the drawing process, but with lower values. The analysis evidenced the presence of the external layer, but its thickness is about 1/3 of the external layer in the drawn wire and the grains appear smaller than in the layer of the drawn wire. The extruding force required along the extruding direction is higher (22-24 N) than the drawing force along the same direction (12 N): being the material, the reduction ratio, the die sliding length the same in both cases, the higher extrusion force should be caused by a higher tangential friction

  19. Corrosion resistance of transmission structures fabricated from weathering steel

    SciTech Connect (OSTI)

    Goodwin, E.J. ); Pohlman, J.C.

    1993-01-01

    Introduced to utilities in the late 1960's, weathering steel' appeared to offer a way to reduce structure weight and maintenance of lattice towers through the application of bare, high strength steel that had natural corrosion resistance. Weathering steel found wide application in lattice and tubular transmission structures. Through its service life, however, the weathering steel showed evidence of continuing corrosion rather than the expected protection from corrosion. A consortium of utilities was formed to investigate the impact on structure reliability of the continuing corrosion of the steel beyond initial expectations. Through the completion of field surveys and laboratory tests, projected lifetime corrosion rates, structural integrity and potential sealer/penetrant systems were evaluated. The investigation has shown that existing lattice and tubular structures fabricated from weathering steel will provide continued reliable service with minimal maintenance programs. Weathering Steel remains practical for new lattice and tubular structures provided steps are taken during the design process to minimize the retention and collection of moisture between and around metal contact surfaces and during the operation of the line to minimize vegetation encroachment around structures.

  20. Rapid analysis of steels using laser-based techniques

    SciTech Connect (OSTI)

    Cremers, D.A.; Archuleta, F.L.; Dilworth, H.C.

    1985-01-01

    Based on the data obtained by this study, we conclude that laser-based techniques can be used to provide at least semi-quantitative information about the elemental composition of molten steel. Of the two techniques investigated here, the Sample-Only method appears preferable to the LIBS (laser-induced breakdown spectroscopy) method because of its superior analytical performance. In addition, the Sample-Only method would probably be easier to incorporate into a steel plant environment. However, before either technique can be applied to steel monitoring, additional research is needed.

  1. Friction Stir Spot Welding of Advanced High Strength Steels

    SciTech Connect (OSTI)

    Hovanski, Yuri; Grant, Glenn J.; Santella, M. L.

    2009-11-13

    Friction stir spot welding techniques were developed to successfully join several advanced high strength steels. Two distinct tool materials were evaluated to determine the effect of tool materials on the process parameters and joint properties. Welds were characterized primarily via lap shear, microhardness, and optical microscopy. Friction stir spot welds were compared to the resistance spot welds in similar strength alloys by using the AWS standard for resistance spot welding high strength steels. As further comparison, a primitive cost comparison between the two joining processes was developed, which included an evaluation of the future cost prospects of friction stir spot welding in advanced high strength steels.

  2. Diode laser welding of aluminum to steel

    SciTech Connect (OSTI)

    Santo, Loredana; Quadrini, Fabrizio; Trovalusci, Federica [University of Rome Tor Vergata, Department of Mechanical Engineering, Via del Politecnico 1, 00133 Rome (Italy)

    2011-05-04

    Laser welding of dissimilar materials was carried out by using a high power diode laser to join aluminum to steel in a butt-joint configuration. During testing, the laser scan rate was changed as well as the laser power: at low values of fluence (i.e. the ratio between laser power and scan rate), poor joining was observed; instead at high values of fluence, an excess in the material melting affected the joint integrity. Between these limiting values, a good aesthetics was obtained; further investigations were carried out by means of tensile tests and SEM analyses. Unfortunately, a brittle behavior was observed for all the joints and a maximum rupture stress about 40 MPa was measured. Apart from the formation of intermeltallic phases, poor mechanical performances also depended on the chosen joining configuration, particularly because of the thickness reduction of the seam in comparison with the base material.

  3. Creep resistant high temperature martensitic steel

    DOE Patents [OSTI]

    Hawk, Jeffrey A.; Jablonski, Paul D.; Cowen, Christopher J.

    2015-11-13

    The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M.sub.23C.sub.6 carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650.degree. C.

  4. Radiation resistant austenitic stainless steel alloys

    DOE Patents [OSTI]

    Maziasz, P.J.; Braski, D.N.; Rowcliffe, A.F.

    1987-02-11

    An austenitic stainless steel alloy, with improved resistance to radiation-induced swelling and helium embrittlement, and improved resistance to thermal creep at high temperatures, consisting essentially of, by weight percent: from 16 to 18% nickel; from 13 to 17% chromium; from 2 to 3% molybdenum; from 1.5 to 2.5% manganese; from 0.01 to 0.5% silicon; from 0.2 to 0.4% titanium; from 0.1 to 0.2% niobium; from 0.1 to 0.6% vanadium; from 0.06 to 0.12% carbon; from 0.01 to 0.03% nitrogen; from 0.03 to 0.08% phosphorus; from 0.005 to 0.01% boron; and the balance iron, and wherein the alloy may be thermomechanically treated to enhance physical and mechanical properties. 4 figs.

  5. Radiation resistant austenitic stainless steel alloys

    DOE Patents [OSTI]

    Maziasz, Philip J.; Braski, David N.; Rowcliffe, Arthur F.

    1989-01-01

    An austenitic stainless steel alloy, with improved resistance to radiation-induced swelling and helium embrittlement, and improved resistance to thermal creep at high temperatures, consisting essentially of, by weight percent: from 16 to 18% nickel; from 13 to 17% chromium; from 2 to 3% molybdenum; from 1.5 to 2.5% manganese; from 0.01 to 0.5% silicon; from 0.2 to 0.4% titanium; from 0.1 to 0.2% niobium; from 0.1 to 0.6% vanadium; from 0.06 to 0.12% carbon; from 0.01% to 0.03% nitrogen; from 0.03 to 0.08% phosphorus; from 0.005 to 0.01% boron; and the balance iron, and wherein the alloy may be thermomechanically treated to enhance physical and mechanical properties.

  6. Reactor Materials Program - Baseline Material Property Handbook - Mechanical Properties of 1950's Vintage Stainless Steel Weldment Components, Task Number 89-23-A-1

    SciTech Connect (OSTI)

    Stoner, K.J.

    1999-11-05

    The Process Water System (primary coolant) piping of the nuclear production reactors constructed in the 1950''s at Savannah River Site is comprised primarily of Type 304 stainless steel with Type 308 stainless steel weld filler. A program to measure the mechanical properties of archival PWS piping and weld materials (having approximately six years of service at temperatures between 25 and 100 degrees C) has been completed. The results from the mechanical testing has been synthesized to provide a mechanical properties database for structural analyses of the SRS piping.

  7. Stainless steel anodes for alkaline water electrolysis and methods of making

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev

    2014-01-21

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  8. Raw neutron scattering data for strain measurement of hydraulically loaded granite and marble samples in triaxial stress state

    SciTech Connect (OSTI)

    Polsky, Yarom

    2014-05-23

    This entry contains raw data files from experiments performed on the Vulcan beamline at the Spallation Neutron Source at Oak Ridge National Laboratory using a pressure cell. Cylindrical granite and marble samples were subjected to confining pressures of either 0 psi or approximately 2500 psi and internal pressures of either 0 psi, 1500 psi or 2500 psi through a blind axial hole at the center of one end of the sample. The sample diameters were 1.5" and the sample lengths were 6". The blind hole was 0.25" in diameter and 3" deep. One set of experiments measured strains at points located circumferentially around the center of the sample with identical radii to determine if there was strain variability (this would not be expected for a homogeneous material based on the symmetry of loading). Another set of experiments measured load variation across the radius of the sample at a fixed axial and circumferential location. Raw neutron diffraction intensity files and experimental parameter descriptions are included.

  9. Raw neutron scattering data for strain measurement of hydraulically loaded granite and marble samples in triaxial stress state

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Polsky, Yarom

    This entry contains raw data files from experiments performed on the Vulcan beamline at the Spallation Neutron Source at Oak Ridge National Laboratory using a pressure cell. Cylindrical granite and marble samples were subjected to confining pressures of either 0 psi or approximately 2500 psi and internal pressures of either 0 psi, 1500 psi or 2500 psi through a blind axial hole at the center of one end of the sample. The sample diameters were 1.5" and the sample lengths were 6". The blind hole was 0.25" in diameter and 3" deep. One set of experiments measured strains at points located circumferentially around the center of the sample with identical radii to determine if there was strain variability (this would not be expected for a homogeneous material based on the symmetry of loading). Another set of experiments measured load variation across the radius of the sample at a fixed axial and circumferential location. Raw neutron diffraction intensity files and experimental parameter descriptions are included.

  10. A new copper borophosphate with novel polymeric chains and its structural correlation with raw materials in molten hydrated flux synthesis

    SciTech Connect (OSTI)

    Duan, Ruijing; Liu, Wei Cao, Lixin; Su, Ge; Xu, Hongmei; Zhao, Chenggong

    2014-02-15

    A novel copper borophosphate, Cu{sub 3}[B{sub 2}P{sub 3}O{sub 12}(OH){sub 3}] has been prepared by the molten hydrated flux method. Its crystal structure was determined by the single-crystal X-ray diffraction (monoclinic, Cc, a=6.1895 Å, b=13.6209 Å, c=11.9373 Å, β=97.62°, V=997.5 Å{sup 3}, Z=4). The three-dimensional framework of the titled compound, is composed by two kinds of polymeric chains and isolated PO{sub 4} tetrahedral. One novel 4-membered tetrahedral rings has been observed in borophosphates. Magnetic measurements indicate that the title compound exits antiferromagnetic interactions. Due to the special reaction medium created by the molten hydrated flux method, a possible structural correlation between the final solids and the raw materials has been noted. - Graphical abstract: The 3D structure consists of a framework composed of CuO{sub x} polyhedra, BO{sub 4} and PO{sub 4} tetrahedra. A intersection angle between the metal chains and borophosphate chains can be noted. Display Omitted - Highlights: • A novel copper borophosphate has been prepared by the molten hydrated flux method. • One novel 4-membered tetrahedral ring has been observed firstly in borophosphates. • A possible structural correlation between the final solids and the raw materials has been noted.

  11. Experimental results of core-concrete interactions using molten steel with zirconium

    SciTech Connect (OSTI)

    Copus, E.R.; Blose, R.E.; Brockmann, J.E.; Gomez, R.D.; Lucero, D.A. )

    1990-07-01

    Four inductively sustained experiments, QT-D, QT-E, SURC-3, and SURC-3A, were performed in order to investigate the additional effects of zirconium metal oxidation on core debris-concrete interactions using molten stainless steel as the core debris simulant. The QT-D experiment ablated 18 cm of concrete axially during 50 minutes of interaction on limestone-common sand concrete using a 10 kg charge of 304 stainless steel to which 2 kg of zirconium metal was added subsequent to the onset of erosion. The QT-E experiment ablated 10 cm of limestone-common sand concrete axially and 10 cm radially during 35 minutes of sustained interaction using 50 kg of stainless steel and 10 kg of zirconium. The SURC-3 experiment had a 45 kg charge of stainless steel to which 1.1 kg of zirconium was subsequently added. SURC-3 axially eroded 33 cm of limestone concrete during two hours of interaction. The fourth experiment, SURC-3A, eroded 25 cm of limestone concrete axially and 9 cm radially during 90 minutes of sustained interaction. It utilized 40 kg of stainless steel and 2.2 kg of added zirconium as the charge material. All four experiments showed in a large increase in erosion rate, gas production, and aerosol release following the addition of Zr metal to the melt. In the SURC-3 and SURC-3A tests the measured erosion rates increased from 14 cm/hr to 27 cm/hr, gas release increased from 50 slpm to 100 slpm, and aerosol release increased from .02 q/sec to .04 q/sec. The effluent gas was composed of 80% CO, 10% CO{sub 2}, and 2% H{sub 2} before Zr addition and 92% CO, 4% CO{sub 2}, 4% H{sub 2} during the Zr interactions which lasted 10--20 minutes. Addition measurements indicated that the melt pool temperature ranged from 1600{degree}C--1800{degree} and that the aerosols produced were comprised primarily of Te and Fe oxides. 21 refs., 120 figs., 51 tabs.

  12. Low Temperature Irradiation Embrittlement of Reactor Pressure Vessel Steels

    SciTech Connect (OSTI)

    Wang, Jy-An John

    2015-08-01

    The embrittlement trend curve development project for HFIR reactor pressure vessel (RPV) steels was carried out with three major tasks. Which are (1) data collection to match that used in HFIR steel embrittlement trend published in 1994 Journal Nuclear Material by Remec et. al, (2) new embrittlement data of A212B steel that are not included in earlier HFIR RPV trend curve, and (3) the adjustment of nil-ductility-transition temperature (NDTT) shift data with the consideration of the irradiation temperature effect. An updated HFIR RPV steel embrittlement trend curve was developed, as described below. NDTT( C) = 23.85 log(x) + 203.3 log (x) + 434.7, with 2- uncertainty of 34.6 C, where parameter x is referred to total dpa. The developed update HFIR RPV embrittlement trend curve has higher embrittlement rate compared to that of the trend curve developed in 1994.

  13. FATIGUE LIFE PREDICTION FOR STEELS IN PULSATING IRRADIATED SYSTEMS...

    Office of Scientific and Technical Information (OSTI)

    Title: FATIGUE LIFE PREDICTION FOR STEELS IN PULSATING IRRADIATED SYSTEMS Authors: Farmer, J C ; Kramer, K J ; Williams, D J Publication Date: 2012-04-29 OSTI Identifier: 1082417 ...

  14. Low temperature type new TMCP steel plate for LPG carriers

    SciTech Connect (OSTI)

    Suzuki, Shuichi; Bessyo, Kiyoshi; Arimochi, Kazushige; Yajima, Hiroshi; Tada, Masuo; Sakai, Daisuke

    1994-12-31

    New Thermo-Mechanical Control Process (TMCP) steel plate for LPG carriers of completely liquefied type was developed with non-nickel chemistry. The new steel plate has a capability to arrest a long running brittle crack at {minus}46 C (which is the design temperature of the liquefied LPG tanks). A high heat-input one-pass welding can be applied to this steel despite its nickel-less chemistry. These capabilities were enabled by microalloying technology with low aluminum-medium nitrogen-boron, as well as by the advanced Thermo-Mechanical Control Process. This paper describes the new concept of utilizing the trace elements and the evaluation test results as the steel plate for the LPG tank and hull, especially from the standpoints of the fracture safe reliability at high heat input welding and from that of the shop workability.

  15. Optimization of Composition and Heat Treating of Die Steels for...

    Office of Scientific and Technical Information (OSTI)

    Optimization of Composition and Heat Treating of Die Steels for Extended Lifetime Citation ... A die used in making die cast aluminum engine blocks can cost well over one million ...

  16. Optimization of Composition and Heat Treating of Die Steels for...

    Office of Scientific and Technical Information (OSTI)

    and Heat Treating of Die Steels for Extended Lifetime An ''average'' die casting die costs fifty thousand dollars. A die used in making die cast aluminum engine blocks can ...

  17. Structural characteristics and hydration kinetics of modified steel slag

    SciTech Connect (OSTI)

    Li Jianxin; Yu Qijun; Wei Jiangxiong Zhang Tongsheng

    2011-03-15

    This study investigates the structural characteristics and hydration kinetics of modified basic oxygen furnace steel slag. The basic oxygen furnace steel slag (BOFS) was mixed with electric arc furnace steel slag (EAFS) in appropriate ratios and heated again at high temperature in the laboratory. The mineralogical and structural characteristics of both BOFS and modified steel slag (MSS) were characterized by X-ray diffraction, optical microscopy, scanning electron microscopy, Raman and Fourier transform infrared spectroscopies. The results show that modification increases alite content in MSS and decreases alite crystal size with the formation of C{sub 6}AF{sub 2}. One more obvious heat evolution peak appears in MSS's heat-flow rate curves in comparison to BOFS, becoming similar to that of typical Portland cement paste. As a result, its cementitious activity is much improved.

  18. Technology Roadmap Research Program for the Steel Industry

    SciTech Connect (OSTI)

    Joseph R. Vehec

    2010-12-30

    The steel industry's Technology Roadmap Program (TRP) is a collaborative R&D effort jointly sponsored by the steel industry and the United States Department of Energy. The TRP program was designed to develop new technologies to save energy , increase competitiveness, and improve the environment. TRP ran from July, 1997 to December, 2008, with a total program budget of $38 million dollars. During that period 47 R&D projects were performed by 28 unique research organizations; co-funding was provided by DOE and 60 industry partners. The projects benefited all areas of steelmaking and much know-how was developed and transferred to industry. The American Iron and Steel Institute is the owner of all intellectual property developed under TRP and licenses it at commercial rates to all steelmakers. TRP technologies are in widespread use in the steel industry as participants received royalty-free use of intellectual property in return for taking the risk of funding this research.

  19. HotEye® Steel Surface Inspection System

    Broader source: Energy.gov [DOE]

    A new inspection system, the HotEye® Rolled Steel Bar (RSB) System, has been developed and demonstrated by OG Technologies (OGT) Inc., with the help of both a NICE3 grant and a project under the...

  20. Eddy sensors for small diameter stainless steel tubes.

    SciTech Connect (OSTI)

    Skinner, Jack L.; Morales, Alfredo Martin; Grant, J. Brian; Korellis, Henry James; LaFord, Marianne Elizabeth; Van Blarigan, Benjamin; Andersen, Lisa E.

    2011-08-01

    The goal of this project was to develop non-destructive, minimally disruptive eddy sensors to inspect small diameter stainless steel metal tubes. Modifications to Sandia's Emphasis/EIGER code allowed for the modeling of eddy current bobbin sensors near or around 1/8-inch outer diameter stainless steel tubing. Modeling results indicated that an eddy sensor based on a single axial coil could effectively detect changes in the inner diameter of a stainless steel tubing. Based on the modeling results, sensor coils capable of detecting small changes in the inner diameter of a stainless steel tube were designed, built and tested. The observed sensor response agreed with the results of the modeling and with eddy sensor theory. A separate limited distribution SAND report is being issued demonstrating the application of this sensor.

  1. Method of making high strength, tough alloy steel

    DOE Patents [OSTI]

    Thomas, Gareth; Rao, Bangaru V. N.

    1979-01-01

    A high strength, tough alloy steel, particularly suitable for the mining industry, is formed by heating the steel to a temperature in the austenite range (1000.degree.-1100.degree. C.) to form a homogeneous austenite phase and then cooling the steel to form a microstructure of uniformly dispersed dislocated martensite separated by continuous thin boundary films of stabilized retained austenite. The steel includes 0.2-0.35 weight % carbon, at least 1% and preferably 3-4.5% chromium, and at least one other subsitutional alloying element, preferably manganese or nickel. The austenite film is stable to subsequent heat treatment as by tempering (below 300.degree. C.) and reforms to a stable film after austenite grain refinement.

  2. Process to Continuously Melt, Refine, and Cast High Quality Steel

    Broader source: Energy.gov [DOE]

    This factsheet describes a project to conduct research and development targeted at designing an innovative steelmaking process to produce higher quality steel faster than traditional batch processes while consuming less energy and other resources.

  3. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  4. Mr. Joseph M. Fallon Director, Engineering Services Slater Steels...

    Office of Legacy Management (LM)

    ... Stainless Steels --. - - -. .. . . - .-.- - . . --- .. .- , UNITED STATES ENERGY i?EsEAECH AND DEVELOPuEftT ADMINISTRATION CIA' . HIDGF OPERkTiO?> P. 0. BOX E OAK SlDGf. ...

  5. Surface modified stainless steels for PEM fuel cell bipolar plates

    DOE Patents [OSTI]

    Brady, Michael P [Oak Ridge, TN; Wang, Heli [Littleton, CO; Turner, John A [Littleton, CO

    2007-07-24

    A nitridation treated stainless steel article (such as a bipolar plate for a proton exchange membrane fuel cell) having lower interfacial contact electrical resistance and better corrosion resistance than an untreated stainless steel article is disclosed. The treated stainless steel article has a surface layer including nitrogen-modified chromium-base oxide and precipitates of chromium nitride formed during nitridation wherein oxygen is present in the surface layer at a greater concentration than nitrogen. The surface layer may further include precipitates of titanium nitride and/or aluminum oxide. The surface layer in the treated article is chemically heterogeneous surface rather than a uniform or semi-uniform surface layer exclusively rich in chromium, titanium or aluminum. The precipitates of titanium nitride and/or aluminum oxide are formed by the nitriding treatment wherein titanium and/or aluminum in the stainless steel are segregated to the surface layer in forms that exhibit a low contact resistance and good corrosion resistance.

  6. The very high cycle fatigue behavior of tool steel materials...

    Office of Scientific and Technical Information (OSTI)

    Title: The very high cycle fatigue behavior of tool steel materials Authors: Shyam, Amit 1 ; Blau, Peter Julian 1 ; Jordan, Tyson L 1 ; Yang, Nan 2 ; Pollard, Michael J 3 ...

  7. Assessing Steel Pipeline and Weld Susceptibility to Hydrogen Embrittlement Webinar

    Broader source: Energy.gov [DOE]

    Access the recording and download the presentation slides from the Fuel Cell Technologies Office webinar "Assessing Steel Pipeline and Weld Susceptibility to Hydrogen Embrittlement" held on January 12, 2016.

  8. Low-Temperature Colossal Supersaturation of Stainless Steels

    Broader source: Energy.gov [DOE]

    Austenitic stainless steels in the 300 Series are the primary materials used for a very broad range of applications when corrosion resistance is needed in aqueous solutions at ambient temperatures....

  9. DOE - Office of Legacy Management -- Birdsboro Steel and Foundry...

    Office of Legacy Management (LM)

    of Birdsboro Steel & Foundry; October 28, 1987 PA.31-3 - AEC Memorandum; Malone to Smith; Subject: Monthly Progress Report for January; January 24, 1952 PA.31-4 - DOE Letter; ...

  10. Mechanical Properties of Structural Steels in Hydrogen | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Mechanical Properties of Structural Steels in Hydrogen Mechanical Properties of Structural Steels in Hydrogen Presented at the DOE Hydrogen Pipeline Working Group Meeting, Aiken, SC, September 25-26, 2007 pipeline_group_somerday_ms.pdf (2.72 MB) More Documents & Publications Materials Compatibility Evalutation of Natural Gas Pipeline Materials and Infrastructure for Hydrogen/Mixed Gas Service Hydrogen-Assisted Fracture: Materials Testing and Variables Governing Fracture

  11. Safety Analysis Report for packaging (onsite) steel waste package

    SciTech Connect (OSTI)

    BOEHNKE, W.M.

    2000-07-13

    The steel waste package is used primarily for the shipment of remote-handled radioactive waste from the 324 Building to the 200 Area for interim storage. The steel waste package is authorized for shipment of transuranic isotopes. The maximum allowable radioactive material that is authorized is 500,000 Ci. This exceeds the highway route controlled quantity (3,000 A{sub 2}s) and is a type B packaging.

  12. High Strength Nano-Structured Steel - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Return to Search High Strength Nano-Structured Steel Idaho National Laboratory Success Story Details Partner Location Agreement Type Publication Date Nanosteel, Inc. Providence, Rhode Island License Work for Others (WFO) June 4, 2013 Video Bulk Materials Nanotechnology Summary The NanoSteel Company Complex modern challenges are driving new industrial market demands for metal alloys with properties and performance capabilities outside the known boundaries of

  13. Procedure for flaw detection in cast stainless steel

    DOE Patents [OSTI]

    Kupperman, David S.

    1988-01-01

    A method of ultrasonic flaw detection in cast stainless steel components incorporating the steps of determining the nature of the microstructure of the cast stainless steel at the site of the flaw detection measurements by ultrasonic elements independent of the component thickness at the site; choosing from a plurality of flaw detection techniques, one such technique appropriate to the nature of the microstructure as determined and detecting flaws by use of the chosen technique.

  14. Steel-SiC Metal Matrix Composite Development

    SciTech Connect (OSTI)

    Smith, Don D.

    2005-07-17

    The goal of this project is to develop a method for fabricating SiC-reinforced high-strength steel. We are developing a metal-matrix composite (MMC) in which SiC fibers are be embedded within a metal matrix of steel, with adequate interfacial bonding to deliver the full benefit of the tensile strength of the SiC fibers in the composite.

  15. Measurement of intergranular attack in stainless steel using ultrasonic energy

    DOE Patents [OSTI]

    Mott, Gerry; Attaar, Mustan; Rishel, Rick D.

    1989-08-08

    Ultrasonic test methods are used to measure the depth of intergranular attack (IGA) in a stainless steel specimen. The ultrasonic test methods include a pitch-catch surface wave technique and a through-wall pulse-echo technique. When used in combination, these techniques can establish the extent of IGA on both the front and back surfaces of a stainless steel specimen from measurements made on only one surface.

  16. Used Fuel Disposition Stainless Steel Canister Challenges Steve Marschman

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stainless Steel Canister Challenges Steve Marschman Field Demonstration Lead Idaho National Laboratory NEET ASI Review Meeting September 17, 2014 Used Fuel Disposition Date 2 Overview n Chloride-Induced Stress Corrosion Cracking (CISCC) has been identified by the NRC as a potential degradation mechanism for welded, stainless steel used fuel canisters (not bare fuel storage casks). n Systems are difficult to inspect and monitor n Three in-service inspections have been performed - Results

  17. AISI/DOE Technology Roadmap Program: Development of Appropriate Resistance Spot Welding Practice for Transformation-Hardened Steels

    SciTech Connect (OSTI)

    Wayne Chuko; Jerry Gould

    2002-07-08

    This report describes work accomplished in the project, titled ''Development of Appropriate Resistance Spot Welding Practice for Transformation-Hardened Steels.'' The Phase 1 of the program involved development of in-situ temper diagrams for two gauges of representative dual-phase and martensitic grades of steels. The results showed that tempering is an effective way of reducing hold-time sensitivity (HTS) in hardenable high-strength sheet steels. In Phase 2, post-weld cooling rate techniques, incorporating tempering, were evaluated to reduce HTS for the same four steels. Three alternative methods, viz., post-heating, downsloping, and spike tempering, for HTS reduction were investigated. Downsloping was selected for detailed additional study, as it appeared to be the most promising of the cooling rate control methods. The downsloping maps for each of the candidate steels were used to locate the conditions necessary for the peak response. Three specific downslope conditions (at a fix ed final current for each material, timed for a zero-, medium-, and full-softening response) were chosen for further metallurgical and mechanical testing. Representative samples, were inspected metallographically, examining both local hardness variations and microstructures. The resulting downslope diagrams were found to consist largely of a C-curve. The softening observed in these curves, however, was not supported by subsequent metallography, which showed that all welds made, regardless of material and downslope condition, were essentially martensitic. CCT/TTT diagrams, generated based on microstructural modeling done at Oak Ridge National Laboratories, showed that minimum downslope times of 2 and 10 s for the martensitic and dual-phase grades of steels, respectively, were required to avoid martensite formation. These times, however, were beyond those examined in this study. These results show that downsloping is not an effective means of reducing HTS for production resistance spot

  18. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  19. The properties and weldability of low activation ferritic steels

    SciTech Connect (OSTI)

    Chin, B.A.

    1990-05-11

    A series of ferritic steels patterned on the chromium-molybdenum alloys, 2 1/4Cr--1Mo, 9Cr--1MoVNb and 12Cr--1MoVW, were tested for weldability. These steels are being developed as candidates for the first wall and blanket structures of fusion reactors. Use of these materials will minimize the long term radioactive hazards associated with disposal after service. In these low activation alloys, elements which become activated during irradiation with long half lives (Mo and Nb) are replaced. The major changes include the replacement of molybdenum with tungsten, the addition of vanadium in 2 1/4% Cr steels, and the replacement of niobium in the 9% Cr steel with tantalum. These replacement elements radically modify both the mechanical properties and weldability of the alloys. In this study, the effect of the alloy modifications on the microstructure and the mechanical properties of the welds are presented. Bainitic steels (2 1/4 Cr%) usually exhibit good weldability, while the martensitic steels (5, 9 and 12 Cr%) are suspectable to embrittlement in the heat affected zone (HAZ). The objective of this study was to characterize the welded microstructure and mechanical properties of these low activation alloys. Autogeneous bead-on-plate welds were produced using the gas tungsten arc welding (GTAW) process. Microstructure, microhardness, weld bend and tensile test results are reported for the base metal, heat affected zone and fusion zone of the weld. 46 refs., 36 figs., 14 tabs.

  20. Ancient Blacksmiths, The Iron Age, Damascus Steels, and Modern Metallurgy

    SciTech Connect (OSTI)

    Sherby, O.D.; Wadsworth, J.

    2000-09-11

    The history of iron and Damascus steels is described through the eyes of ancient blacksmiths. For example, evidence is presented that questions why the Iron Age could not have begun at about the same time as the early Bronze Age (i.e. approximately 7000 B.C.). It is also clear that ancient blacksmiths had enough information from their forging work, together with their observation of color changes during heating and their estimate of hardness by scratch tests, to have determined some key parts of the present-day iron-carbon phase diagram. The blacksmiths' greatest artistic accomplishments were the Damascus and Japanese steel swords. The Damascus sword was famous not only for its exceptional cutting edge and toughness, but also for its beautiful surface markings. Damascus steels are ultrahigh carbon steels (UHCSs) that contain from 1.0 to 2.1%. carbon. The modern metallurgical understanding of UHCSs has revealed that remarkable properties can be obtained in these hypereutectoid steels. The results achieved in UHCSs are attributed to the ability to place the carbon, in excess of the eutectoid composition, to do useful work that enhances the high temperature processing of carbon steels and that improves the low and intermediate temperature mechanical properties.

  1. Morphological and microstructural studies on aluminizing coating of carbon steel

    SciTech Connect (OSTI)

    Samsu, Zaifol; Othman, Norinsan Kamil; Daud, Abd Razak; Hussein, Hishammuddin

    2013-11-27

    Hot dip aluminizing is one of the most effective methods of surface protection for steels and is gradually gaining popularity. The morphology and microstructure of an inter-metallic layer form on the surface of low carbon steel by hot dip aluminization treatment had been studied in detail. This effect has been investigated using optical and scanning electron microscopy, and X-ray diffraction. The result shows that the reaction between the steel and the molten aluminium leads to the formation of Fe–Al inter-metallic compounds on the steel surface. X-ray diffraction and electron microscopic studies showed that a two layer coating was formed consisting of an external Al layer and a (Fe{sub 2}Al{sub 5}) inter metallic on top of the substrate after hot dip aluminizing process. The inter-metallic layer is ‘thick’ and exhibits a finger-like growth into the steel. Microhardness testing shown that the intermetallic layer has high hardness followed by steel substrate and the lowest hardness was Al layer.

  2. Corrosion resistance of stainless steels during thermal cycling in alkali nitrate molten salts.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.; Goods, Steven Howard

    2001-09-01

    The corrosion behavior of three austenitic stainless steels was evaluated during thermal cycling in molten salt mixtures consisting of NaNO{sub 3} and KNO{sub 3}. Corrosion tests were conducted with Types 316, 316L and 304 stainless steels for more than 4000 hours and 500 thermal cycles at a maximum temperature of 565 C. Corrosion rates were determined by chemically descaling coupons. Metal losses ranged from 5 to 16 microns and thermal cycling resulted in moderately higher corrosion rates compared to isothermal conditions. Type 316 SS was somewhat more corrosion resistant than Type 304 SS in these tests. The effect of carbon content on corrosion resistance was small, as 316L SS corroded only slightly slower than 316 SS. The corrosion rates increased as the dissolved chloride content of the molten salt mixtures increased. Chloride concentrations approximating 1 wt.%, coupled with thermal cycling, resulted in linear weight loss kinetics, rather than parabolic kinetics, which described corrosion rates for all other conditions. Optical microscopy and electron microprobe analysis revealed that the corrosion products consisted of iron-chromium spinel, magnetite, and sodium ferrite, organized as separate layers. Microanalysis of the elemental composition of the corrosion products further demonstrated that the chromium content of the iron-chromium spinel layer was relatively high for conditions in which parabolic kinetics were observed. However, linear kinetics were observed when the spinel layer contained relatively little chromium.

  3. Corrosion of high Ni-Cr alloys and Type 304L stainless steel in HNO/sub 3/-HF

    SciTech Connect (OSTI)

    Ondrejcin, R.S.; McLaughlin, B.D.

    1980-04-01

    Nineteen alloys were evaluated as possible materials of construction for steam heating coils, the dissolver vessel, and the off-gas system of proposed facilities to process thorium and uranium fuels. Commercially available alloys were found that are satisfactory for all applications. With thorium fuel, which requires HNO/sub 3/-HF for dissolution, the best alloy for service at 130/sup 0/C when complexing agents for fluoride are used is Inconel 690; with no complexing agents at 130/sup 0/C, Inconel 671 is best. At 95/sup 0/C, six other alloys tested would be adequate: Haynes 25, Ferralium, Inconel 625, Type 304L stainless steel, Incoloy 825, and Haynes 20 (in order of decreasing preference); based on composition, six untested alloys would also be adequate. The ions most effective in reducing fluoride corrosion were the complexing agents Zr/sup 4 +/ and Th/sup 4 +/; Al/sup 3 +/ was less effective. With uranium fuel, modestly priced Type 304L stainless steel is adequate. Corrosion will be most severe in HNO/sub 3/-HF used occasionally for flushing and in solutions of HNO/sub 3/ and corrosion products (ferric and dichromate ions). HF corrosion can be minimized by complexing the fluoride ion and by passivation of the steel with strong nitric acid. Corrosion caused by corrosion products can be minimized by operating at lower temperatures.

  4. Yield Improvement in Steel Casting (Yield II)

    SciTech Connect (OSTI)

    Richard A. Hardin; Christoph Beckermann; Tim Hays

    2002-02-18

    This report presents work conducted on the following main projects tasks undertaken in the Yield Improvement in Steel Casting research program: Improvement of Conventional Feeding and Risering Methods, Use of Unconventional Yield Improvement Techniques, and Case Studies in Yield Improvement. Casting trials were conducted and then simulated using the precise casting conditions as recorded by the participating SFSA foundries. These results present a statistically meaningful set of experimental data on soundness versus feeding length. Comparisons between these casting trials and casting trials performed more than forty years ago by Pellini and the SFSA are quite good and appear reasonable. Comparisons between the current SFSA feeding rules and feeding rules based on the minimum Niyama criterion reveal that the Niyama-based rules are generally less conservative. The niyama-based rules also agree better with both the trials presented here, and the casting trails performed by Pellini an d the SFSA years ago. Furthermore, the use of the Niyama criterion to predict centerline shrinkage for horizontally fed plate sections has a theoretical basis according to the casting literature reviewed here. These results strongly support the use of improved feeding rules for horizontal plate sections based on the Niyama criterion, which can be tailored to the casting conditions for a given alloy and to a desired level of soundness. The reliability and repeatability of ASTM shrinkage x-ray ratings was investigated in a statistical study performed on 128 x-rays, each of which were rated seven different times. A manual ''Feeding and Risering Guidelines for Steel Castings' is given in this final report. Results of casting trials performed to test unconventional techniques for improving casting yield are presented. These use a stacked arrangement of castings and riser pressurization to increase the casting yield. Riser pressurization was demonstrated to feed a casting up to four time s the

  5. Greenhouse Gas Mitigation Options in ISEEM Global Energy Model: 2010-2050 Scenario Analysis for Least-Cost Carbon Reduction in Iron and Steel Sector

    SciTech Connect (OSTI)

    Karali, Nihan; Xu, Tengfang; Sathaye, Jayant

    2013-12-01

    The goal of the modeling work carried out in this project was to quantify long-term scenarios for the future emission reduction potentials in the iron and steel sector. The main focus of the project is to examine the impacts of carbon reduction options in the U.S. iron and steel sector under a set of selected scenarios. In order to advance the understanding of carbon emission reduction potential on the national and global scales, and to evaluate the regional impacts of potential U.S. mitigation strategies (e.g., commodity and carbon trading), we also included and examined the carbon reduction scenarios in China’s and India’s iron and steel sectors in this project. For this purpose, a new bottom-up energy modeling framework, the Industrial Sector Energy Efficiency Modeling (ISEEM), (Karali et al. 2012) was used to provide detailed annual projections starting from 2010 through 2050. We used the ISEEM modeling framework to carry out detailed analysis, on a country-by-country basis, for the U.S., China’s, and India’s iron and steel sectors. The ISEEM model applicable to iron and steel section, called ISEEM-IS, is developed to estimate and evaluate carbon emissions scenarios under several alternative mitigation options - including policies (e.g., carbon caps), commodity trading, and carbon trading. The projections will help us to better understand emission reduction potentials with technological and economic implications. The database for input of ISEEM-IS model consists of data and information compiled from various resources such as World Steel Association (WSA), the U.S. Geological Survey (USGS), China Steel Year Books, India Bureau of Mines (IBM), Energy Information Administration (EIA), and recent LBNL studies on bottom-up techno-economic analysis of energy efficiency measures in the iron and steel sector of the U.S., China, and India, including long-term steel production in China. In the ISEEM-IS model, production technology and manufacturing details are

  6. Manufacturing Cost Analysis of Novel Steel/Concrete Composite Vessel for Stationary Storage of High-Pressure Hydrogen

    SciTech Connect (OSTI)

    Feng, Zhili; Zhang, Wei; Wang, Jy-An John; Ren, Fei

    2012-09-01

    A novel, low-cost, high-pressure, steel/concrete composite vessel (SCCV) technology for stationary storage of compressed gaseous hydrogen (CGH2) is currently under development at Oak Ridge National Laboratory (ORNL) sponsored by DOE s Fuel Cell Technologies (FCT) Program. The SCCV technology uses commodity materials including structural steels and concretes for achieving cost, durability and safety requirements. In particular, the hydrogen embrittlement of high-strength low-alloy steels, a major safety and durability issue for current industry-standard pressure vessel technology, is mitigated through the use of a unique layered steel shell structure. This report presents the cost analysis results of the novel SCCV technology. A high-fidelity cost analysis tool is developed, based on a detailed, bottom-up approach which takes into account the material and labor costs involved in each of the vessel manufacturing steps. A thorough cost study is performed to understand the SCCV cost as a function of the key vessel design parameters, including hydrogen pressure, vessel dimensions, and load-carrying ratio. The major conclusions include: The SCCV technology can meet the technical/cost targets set forth by DOE s FCT Program for FY2015 and FY2020 for all three pressure levels (i.e., 160, 430 and 860 bar) relevant to the hydrogen production and delivery infrastructure. Further vessel cost reduction can benefit from the development of advanced vessel fabrication technologies such as the highly automated friction stir welding (FSW). The ORNL-patented multi-layer, multi-pass FSW can not only reduce the amount of labor needed for assembling and welding the layered steel vessel, but also make it possible to use even higher strength steels for further cost reductions and improvement of vessel structural integrity. It is noted the cost analysis results demonstrate the significant cost advantage attainable by the SCCV technology for different pressure levels when compared to the

  7. PySpline: A Modern, Cross-Platform Program for the Processing of Raw Averaged XAS Edge and EXAFS Data

    SciTech Connect (OSTI)

    Tenderholt, A.; Hedman, B.; Hodgson, K.O.

    2007-01-08

    PySpline is a modern computer program for processing raw averaged XAS and EXAFS data using an intuitive approach which allows the user to see the immediate effect of various processing parameters on the resulting k- and R-space data. The Python scripting language and Qt and Qwt widget libraries were chosen to meet the design requirement that it be cross-platform (i.e. versions for Windows, Mac OS X, and Linux). PySpline supports polynomial pre- and post-edge background subtraction, splining of the EXAFS region with a multi-segment polynomial spline, and Fast Fourier Transform (FFT) of the resulting k{sup 3}-weighted EXAFS data.

  8. Characterization of raw and burnt oil shale from Dotternhausen: Petrographical and mineralogical evolution with temperature

    SciTech Connect (OSTI)

    Thiéry, Vincent; Bourdot, Alexandra; Bulteel, David

    2015-08-15

    The Toarcian Posidonia shale from Dotternhausen, Germany, is quarried and burnt in a fluidized bed reactor to produce electricity. The combustion residue, namely burnt oil shale (BOS), is used in the adjacent cement work as an additive in blended cements. The starting material is a typical laminated oil shale with an organic matter content ranging from 6 to 18%. Mineral matter consists principally of quartz, feldspar, pyrite and clays. After calcination in the range, the resulting product, burnt oil shale, keeps the macroscopic layered texture however with different mineralogy (anhydrite, lime, iron oxides) and the formation of an amorphous phase. This one, studied under STEM, reveals a typical texture of incipient partial melting due to a long retention time (ca. 30 min) and quenching. An in-situ high temperature X-ray diffraction (HTXRD) allowed studying precisely the mineralogical changes associated with the temperature increase. - Highlights: • We present oil shale/burnt oil shale characterization. • The Posidonia Shale is burnt in a fluidized bed. • Mineralogical evolution with temperature is complex. • The burnt oil shale is used in composite cements.

  9. Weldable, age hardenable, austenitic stainless steel

    DOE Patents [OSTI]

    Brooks, J.A.; Krenzer, R.W.

    1975-07-22

    An age hardenable, austenitic stainless steel having superior weldability properties as well as resistance to degradation of properties in a hydrogen atmosphere is described. It has a composition of from about 24.0 to about 34.0 weight percent (w/o) nickel, from about 13.5 to about 16.0 w/o chromium, from about 1.9 to about 2.3 w/o titanium, from about 1.0 to about 1.5 w/ o molybdenum, from about 0.01 to about 0.05 w/o carbon, from about 0 to about 0.25 w/o manganese, from about 0 to about 0.01 w/o phosphorous and preferably about 0.005 w/o maximum, from about 0 to about 0.010 w/o sulfur and preferably about 0.005 w/o maximum, from about 0 to about 0.25 w/o silicon, from about 0.1 to about 0.35 w/o aluminum, from about 0.10 to about 0.50 w/o vanadium, from about 0 to about 0.0015 w/o boron, and the balance essentially iron. (auth)

  10. Welding Behavior of Free Machining Stainless Steel

    SciTech Connect (OSTI)

    BROOKS,JOHN A.; ROBINO,CHARLES V.; HEADLEY,THOMAS J.; MICHAEL,JOSEPH R.

    2000-07-24

    The weld solidification and cracking behavior of sulfur bearing free machining austenitic stainless steel was investigated for both gas-tungsten arc (GTA) and pulsed laser beam weld processes. The GTA weld solidification was consistent with those predicted with existing solidification diagrams and the cracking response was controlled primarily by solidification mode. The solidification behavior of the pulsed laser welds was complex, and often contained regions of primary ferrite and primary austenite solidification, although in all cases the welds were found to be completely austenite at room temperature. Electron backscattered diffraction (EBSD) pattern analysis indicated that the nature of the base metal at the time of solidification plays a primary role in initial solidification. The solid state transformation of austenite to ferrite at the fusion zone boundary, and ferrite to austenite on cooling may both be massive in nature. A range of alloy compositions that exhibited good resistance to solidification cracking and was compatible with both welding processes was identified. The compositional range is bounded by laser weldability at lower Cr{sub eq}/Ni{sub eq} ratios and by the GTA weldability at higher ratios. It was found with both processes that the limiting ratios were somewhat dependent upon sulfur content.

  11. NanoComposite Stainless Steel Powder Technologies

    SciTech Connect (OSTI)

    DeHoff, R.; Glasgow, C.

    2012-07-25

    Oak Ridge National Laboratory has been investigating a new class of Fe-based amorphous material stemming from a DARPA, Defense Advanced Research Projects Agency initiative in structural amorphous metals. Further engineering of the original SAM materials such as chemistry modifications and manufacturing processes, has led to the development of a class of Fe based amorphous materials that upon processing, devitrify into a nearly homogeneous distribution of nano sized complex metal carbides and borides. The powder material is produced through the gas atomization process and subsequently utilized by several methods; laser fusing as a coating to existing components or bulk consolidated into new components through various powder metallurgy techniques (vacuum hot pressing, Dynaforge, and hot isostatic pressing). The unique fine scale distribution of microstructural features yields a material with high hardness and wear resistance compared to material produced through conventional processing techniques such as casting while maintaining adequate fracture toughness. Several compositions have been examined including those specifically designed for high hardness and wear resistance and a composition specifically tailored to devitrify into an austenitic matrix (similar to a stainless steel) which poses improved corrosion behavior.

  12. Austenitic stainless steel for high temperature applications

    DOE Patents [OSTI]

    Johnson, Gerald D.; Powell, Roger W.

    1985-01-01

    This invention describes a composition for an austenitic stainless steel which has been found to exhibit improved high temperature stress rupture properties. The composition of this alloy is about (in wt. %): 12.5 to 14.5 Cr; 14.5 to 16.5 Ni; 1.5 to 2.5 Mo; 1.5 to 2.5 Mn; 0.1 to 0.4 Ti; 0.02 to 0.08 C; 0.5 to 1.0 Si; 0.01 maximum, N; 0.02 to 0.08 P; 0.002 to 0.008 B; 0.004-0.010 S; 0.02-0.05 Nb; 0.01-0.05 V; 0.005-0.02 Ta; 0.02-0.05 Al; 0.01-0.04 Cu; 0.02-0.05 Co; 0.03 maximum, As; 0.01 maximum, O; 0.01 maximum, Zr; and with the balance of the alloy being essentially iron. The carbon content of the alloy is adjusted such that wt. % Ti/(wt. % C+wt. % N) is between 4 and 6, and most preferably about 5. In addition the sum of the wt. % P+wt. % B+wt. % S is at least 0.03 wt. %. This alloy is believed to be particularly well suited for use as fast breeder reactor fuel element cladding.

  13. Impact on thin steel plates by tumbling projectiles

    SciTech Connect (OSTI)

    Li, K.; Goldsmith, W.

    1995-12-31

    An experimental, analytical, and numerical investigation into the effects of tumbling projectiles on the impact response of thin 4130 steel target plates was performed. Deformation patterns and failure phenomena as well as the final velocities and trajectories of the projectiles are correlated with initial conditions such as the initial velocity and impact angle (or yaw angle with a zero oblique angle) of the projectile and plate thickness. In the experiments, tumbling motion of the projectiles was induced by impact of a portion of the front face of the projectile with the edge of a massive block placed along the trajectory. Cylinders with a diameter of 12.7 mm, a length of 38.1 mm, and a hardness of R{sub c} 54 were fired at velocities from 400 m/s - 800 m/s. The forward speed of the projectile after tumbling production ranged from 300 m/s-700 m/s. Rotational speeds ranged from 0 rad/s - 3000 rad/s and concomitant impact angles varied from 0{degrees} to 60{degrees}. These parameters were determined from high speed photographic records. The targets were 1.6 mm and 3.2 mm thick. An analytical model developed for thin aluminum target plates was employed in the present study. The model divides the penetration process into three stages: (1) plugging; (2) hole enlargement; and (3) frontal petaling. The processes are quantified using energy dissipation descriptions of the various deformation mechanisms. Numerical simulations of the penetration processes were performed by employment of the program DYNA3D, a nonlinear, three-dimensional finite element code. The material of the target was modeled as elasto-plastic with failure, while the projectile was assumed to be undeformable. The failure criterion of the target is based on the ultimate tensile strain.

  14. Rolling bearing life models and steel internal cleanliness

    SciTech Connect (OSTI)

    Beswick, J.; Gabelli, A.; Ioannides, S.; Tripp, J.H.; Voskamp, A.P.

    1999-07-01

    The most widely used steel grade for rolling bearings is based on a steel composition first used almost a hundred years ago, the so-called 1C-1.5Cr steel. This steel is used either in a selective surface induction hardened conditions or in a through hardened heat treated condition, both yielding exceptional structural and contact fatigue properties. The Lundberg and Palmgren rolling bearing life prediction model, published in 1947, was the first analytical approach to bearing performance prediction, subsequently becoming a widely accepted basis for rolling bearing life calculations. At that time the fatigue life of rolling bearings was dominated by the classical sub-surface initiated failure mode. This mode results from the accumulation of micro-plastic strain at the depth of maximum Hertzian stress and is accelerated by the stress concentrations occurring at the micro internal defects. In common with all fatigue processes, rolling bearing failure is a statistical process: the failures of bearings with high inclusion content tested at high stress levels belong to the well-known family of Weibull distributions. Steady improvements in bearing steel cleanliness due, amongst other things, to the introduction of secondary metallurgy steel making techniques, have resulted in a significantly increased rolling bearing life and load carrying capacity. In recognition of this, in 1985 Ioannides and Harris introduced a new fatigue life model for rolling bearings, comprising a more widely applicable approach to the modeling of bearing life based on the relevant failure mode. Subsequently this has been extended to include effects of hardness and of micro-inclusion distributions in state-of-the-art clean bearing steel.

  15. Use of selective oxidation of petroleum residue for production of low-sulfur coke

    SciTech Connect (OSTI)

    Hairudinov, I.R.; Kul`chitskaya, O.V.; Imashev, U.B.

    1995-12-10

    The chemical nature of liquid-phase oxidation of sulfurous petroleum residues by cumene hydroperoxide was studied by a tracer technique. Sulfur compounds are selectively oxidized in the presence of catalytic additives of molybdenum salts. Desulfurization of distillate products and coke during coking of preoxidized raw materials was revealed.

  16. Heavy reflector experiments in the IPEN/MB-01 reactor: Stainless steel, carbon steel and nickel

    SciTech Connect (OSTI)

    Santos, Adimir dos; Andrade e Silva, Graciete Simoes de; Jerez, Rogerio; Liambos Mura, Luis Felipe; Fuga, Rinaldo

    2013-05-06

    New experiments devoted to the measurements of physical parameters of a light water core surrounded by a heavy reflector were performed in the IPEN/MB-01 research reactor facility. These experiments comprise three sets of heavy reflector (SS-304, Carbon Steel, and Nickel) in a form of laminates around 3 mm thick. Each set was introduced individually in the west face of the core of the IPEN/MB-01 reactor. The aim here is to provide high quality experimental data for the interpretation and validation of the SS-304 heavy reflector calculation methods. The experiments of Carbon Steel, which is composed mainly of iron, and Nickel were performed to provide a consistent and an interpretative check for the SS-304 reflector experiment. The experimental results comprise critical control bank positions, temperatures and reactivities as a function of the number of the plates. Particularly to the case of Nickel, the experimental data are unique of its kind. The theoretical analysis was performed by MCNP-5 with the nuclear data library ENDF/B-VII.0. It was shown that this nuclear data library has a very good performance up to thirteen plates and overestimates the reactivity for higher number of plates independently of the type of the reflector.

  17. Active wear and failure mechanisms of TiN-coated high speed steel and TiN-coated cemented carbide tools when machining powder metallurgically made stainless steels

    SciTech Connect (OSTI)

    Jiang, L.; Haenninen, H.; Paro, J.; Kauppinen, V.

    1996-09-01

    In this study, active wear and failure mechanisms of both TiN-coated high speed steel and TiN-coated cemented carbide tools when machining stainless steels made by powder metallurgy in low and high cutting speed ranges, respectively, have been investigated. Abrasive wear mechanisms, fatigue-induced failure, and adhesive and diffusion wear mechanisms mainly affected the tool life of TiN-coated high speed steel tools at cutting speeds below 35 m/min, between 35 and 45 m/min, and over 45 m/min, respectively. Additionally, fatigue-induced failure was active at cutting speeds over 45 m/min in the low cutting speed range when machining powder metallurgically made duplex stainless steel 2205 and austenitic stainless steel 316L. In the high cutting speed range, from 100 to 250 m/min, fatigue-induced failure together with diffusion wear mechanism, affected the tool life of TiN-coated cemented carbide tools when machining both 316L and 2205 stainless steels. It was noticed that the tool life of TiN-coated high speed steel tools used in the low cutting speed range when machining 2205 steel was longer than that when machining 316L steel, whereas the tool life of TiN-coated cemented carbide tools used in the high cutting speed range when machining 316L steel was longer than that when machining 2205 steel.

  18. Shielding gas selection for increased weld penetration and productivity in GTA welding

    SciTech Connect (OSTI)

    Leinonen, J.I.

    1996-12-31

    The effects of hydrogen and helium additions to the argon shielding gas on GTA weld pool profiles in the case of two austenitic stainless steel sheets 3 mm thick are investigated here in detail. One of the test steels shows good weldability, with a relatively deep, narrow weld pool profile, but the other is poorly weldable, with a shallow, wide weld pool when argon shielding gas is used. Bead-on-plate test welds were produced with arc shields of argon, argon with hydrogen additions of 2 to 18.2% and argon with helium additions of 20 to 80%. The hydrogen additions increases the depth of weld penetration in both test steels, but productivity with respect to maximum welding speed can be improved to an accepted level only with steel sheets of good weldability in terms of a relatively high depth/width (D/W) ratio. The depth of penetration in the test steel of good weldability increased somewhat with helium additions and the D/W ratio remained unchanged, while these parameters increased markedly in the poorly weldable steel when a He-20% Ar shielding gas was used and resembled those of the more weldable steel.

  19. High productivity in Australian blast furnaces

    SciTech Connect (OSTI)

    Nightingale, R.J.; Mellor, D.G.; Jelenich, L.; Ward, R.F.

    1995-12-01

    Since the emergence of the Australian domestic economy from recession in 1992, the productivity of BHP`s blast furnace has increased significantly to meet the demands of both domestic and export markets. BHP Steel operates six blast furnaces at its three Australian integrated plants. These furnaces vary widely in their size, feed, technology and current campaign status. This paper reviews the principal issues associated with productivity improvements over recent years. These gains have been achieved through activities associated with a wide range of process, equipment and human resource based issues.

  20. Weldability Comparison of Tritium-Charged-and -Aged 304 and 316LN Stainless Steels

    SciTech Connect (OSTI)

    Tosten, M.H.

    2003-06-10

    Measurement of the effects of helium (from tritium decay) on the weldability of Types 304 and ITER Grade 316LN stainless steel demonstrated the inherent complexities in designing and conducting an experimental program using tritium-charged-and-aged materials to simulate the effects of irradiation-induced helium on weld behavior. Differences in microstructure, surface condition and alloy chemistry are known to play key roles in tritium absorption and distribution and thus have direct effects on the subsequent 3He production and distribution. The helium embrittlement cracking produced in 0.5 in. (12.7 mm) thick 304 and 316LN plates that were tritium-charged in the same container and subsequently welded with gas metal arc, low heat input weld overlays and gas tungsten arc stringer beads, varied markedly. For example, the porosity in the weld beads was much higher in the 304 plate than in the 316LN plate. Additionally, crack measurements from weld cross-sections revealed more extensive intergranular cracking in the heat-affected zones of welds on the 304 plate when compared to the 316LN plate. However, the differences between the two types of stainless steel may not be a result of differences in the resistance to helium embrittlement cracking, but may be due to initial tritium concentration differences developed in the as-charged plates. Further work is necessary to identify the reasons for the apparent plate to plate variation in tritium/helium content and to demonstrate the similarities (or differences) between Types 304 and ITER grade 316LN stainless steel.

  1. Sulfide stress cracking resistance of low-alloy nickel steels

    SciTech Connect (OSTI)

    Yoshino, Y.; Minozaki, Y.

    1986-04-01

    The sulfide stress cracking (SSC) resistance of Ni-containing low-alloy steels was studied using laboratory and commercial heats over the range of 600 to 800 MPa yield strength (700 to 900 MPa tensile strength). The results were interpreted with regard to observations by metallurgical and electrochemical analyses. In steel containing 1% Cr and 0.5% Mo, the SSC resistance is not affected by up to 2% Ni. A commercial steel with 3.7% Ni-1.8% Cr-0.4% Mo exhibits the same K/sub ISSC/ and Ni-free steels. The cracking resistance begins to deteriorate when fresh martensite exceeds 5 vol%. The lattice diffusion of hydrogen is decreased by the additional Ni, whereas the subsurface hydrogen concentration remains constant in 5% NaCl solution and decreases in NACE TM-01-77 solution up to 5% Ni. Thus, nickel has no harmful effect in terms of hydrogen absorption and diffusion. However, nickel enhances the formation of surface trenches in acidified solutions. This is intensified in the anodically polarized slow extension rate test, which results in loss in elongation. Consequently, nickel per se has no effect on the propagation of SSC unless its addition results in the formation of fresh martensite. However, it may or may not enhance crack initiation, depending on a specific combination of solution and steel, by forming surface trenches that subsequently trigger hydrogen cracking from their bottom.

  2. Woodgrain defect on tinned steel Flandres foil

    SciTech Connect (OSTI)

    Sarkis, A.M.; Robin, A. Souza, V.A.; Suzuki, P.A.

    2011-06-15

    Tin electrocoated steel strip, also referred to as Flandres foil, is largely used for manufacturing food containers. Tinplates must have good corrosion resistance, workability, weldability, as well as a bright appearance. The woodgrain defect, a not yet fully understood defect that occurs on tinplates and accounts for their high scrap rate, consists of alternate bands of bright/dull reflectivity and resembles longitudinally cut wood. Observations of the woodgrain defect by scanning electron microscopy showed that the molten tin spreads irregularly during both the melting and solidification stages. X-ray diffraction analyses showed that the metallic tin tended to crystallize in the (200) direction for coupons with and without the woodgrain defect. Nevertheless, the preferential orientation degree decreased for coupons with the woodgrain defect. The rocking curves, also known as omega-scan, showed that the tin grains were uniformly aligned parallel to the strip surface for coupons with no defects, whereas for tinplates with woodgrain, the tin grains were not uniformly oriented, probably due to the misalignment of the grains in relation to the surface. - Graphical abstract: The woodgrain defect occurs on Flandres tinplates and consists in the formation of alternate bands of different reflectivity (bright/dull), which looks like longitudinally cut wood. X-ray diffractometry showed that the typical bright surface of tinplate is associated to the uniform distribution of aligned (200) Sn grains, whereas in tinplate with the woodgrain defect, the Sn grains were not uniformly oriented, due to the misalignment of the (200) Sn planes relative to the surface. Research highlights: {yields} The bright surface of tinplate is associated to the uniform distribution of aligned (200) Sn grains. {yields} The woodgrain defect on tinplate consists in alternate bands of bright/dull appearance. {yields} In tinplate with the woodgrain defect, the Sn grains were not uniformly oriented, due

  3. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    SciTech Connect (OSTI)

    Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-08-31

    This Department of Energy National Energy Technology Laboratory sponsored project developed carbon products, using mildly hydrogenated solvents to extract the organic portion of coal to create synthetic pitches, cokes, carbon foam and carbon fibers. The focus of this effort was on development of lower cost solvents, milder hydrogenation conditions and improved yield in order to enable practical production of these products. This technology is needed because of the long-term decline in production of domestic feedstocks such as petroleum pitch and coal tar pitch. Currently, carbon products represents a market of roughly 5 million tons domestically, and 19 million tons worldwide. Carbon products are mainly derived from feedstocks such as petroleum pitch and coal tar pitch. The domestic supply of petroleum pitch is declining because of the rising price of liquid fuels, which has caused US refineries to maximize liquid fuel production. As a consequence, the long term trend has a decline in production of petroleum pitch over the past 20 years. The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. In this industry, modern metcoke facilities are recycling coal tar as fuel in order to enhance energy efficiency and minimize environmental emissions. Metcoke production itself is dependent upon the production requirements for domestic steel. Hence, several metcoke ovens have been decommissioned over the past two decades and have not been replaced. As a consequence sources of coal tar are being taken off line and are not being replaced. The long-term trend is a reduction in coal tar pitch production. Thus import of feedstocks, mainly from Eastern Europe and China, is on the rise despite the relatively large transportation cost. To reverse this trend, a new process for producing carbon products is needed. The process must be

  4. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Madhavi Nallani-Chakravartula; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2006-03-27

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of continuous processes for hydrogenation as well as continuous production of carbon foam and coke.

  5. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-06-08

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of continuous processes for hydrogenation as well as continuous production of carbon foam and coke.

  6. Bright X-ray Stainless Steel K-shell Source Development at the...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Bright X-ray Stainless Steel K-shell Source Development at the National Ignition Facility Citation Details In-Document Search Title: Bright X-ray Stainless Steel K...

  7. ITP Steel: Hydrogen and Nitrogen Control in Ladle and Casting Operations

    Office of Energy Efficiency and Renewable Energy (EERE)

    In recent years there has been an increasing demand to reduce and control the amount of dissolved gases in steel. Hydrogen and nitrogen are two of the most important gases which when dissolved in liquid steel affect its properties significantly

  8. DOE - Office of Legacy Management -- U S Steel Co National Tube...

    Office of Legacy Management (LM)

    Steel Co National Tube Div Christy Park Works - PA 35 FUSRAP Considered Sites Site: U. S. STEEL CO., NATIONAL TUBE DIV., CHRISTY PARK WORKS (PA.35) Eliminated from further ...

  9. Long-lived activation products in reactor materials

    SciTech Connect (OSTI)

    Evans, J.C.; Lepel, E.L.; Sanders, R.W.; Wilkerson, C.L.; Silker, W.; Thomas, C.W.; Abel, K.H.; Robertson, D.R.

    1984-08-01

    The purpose of this program was to assess the problems posed to reactor decommissioning by long-lived activation products in reactor construction materials. Samples of stainless steel, vessel steel, concrete, and concrete ingredients were analyzed for up to 52 elements in order to develop a data base of activatable major, minor, and trace elements. Large compositional variations were noted for some elements. Cobalt and niobium concentrations in stainless steel, for example, were found to vary by more than an order of magnitude. A thorough evaluation was made of all possible nuclear reactions that could lead to long lived activation products. It was concluded that all major activation products have been satisfactorily accounted for in decommissioning planning studies completed to date. A detailed series of calculations was carried out using average values of the measured compositions of the appropriate materials to predict the levels of activation products expected in reactor internals, vessel walls, and bioshield materials for PWR and BWR geometries. A comparison is made between calculated activation levels and regulatory guidelines for shallow land disposal according to 10 CFR 61. This analysis shows that PWR and BWR shroud material exceeds the Class C limits and is, therefore, generally unsuitable for near-surface disposal. The PWR core barrel material approaches the Class C limits. Most of the remaining massive components qualify as either Class A or B waste with the bioshield clearly Class A, even at the highest point of activation. Selected samples of activated steel and concrete were subjected to a limited radiochemical analysis program as a verification of the computer model. Reasonably good agreement with the calculations was obtained where comparison was possible. In particular, the presence of /sup 94/Nb in activated stainless steel at or somewhat above expected levels was confirmed.

  10. Recycling of the product of thermal inertization of cement-asbestos for various industrial applications

    SciTech Connect (OSTI)

    Gualtieri, Alessandro F.; Giacobbe, Carlotta; Sardisco, Lorenza; Saraceno, Michele; Lassinantti Gualtieri, Magdalena; Cavenati, Cinzia; Zanatto, Ivano

    2011-01-15

    Recycling of secondary raw materials is a priority of waste handling in the countries of the European community. A potentially important secondary raw material is the product of the thermal transformation of cement-asbestos, produced by prolonged annealing at 1200-1300 {sup o}C. The product is chemically comparable to a Mg-rich clinker. Previous work has assured the reliability of the transformation process. The current challenge is to find potential applications as secondary raw material. Recycling of thermally treated asbestos-containing material (named KRY.AS) in traditional ceramics has already been studied with successful results. The results presented here are the outcome of a long termed project started in 2005 and devoted to the recycling of this secondary raw materials in various industrial applications. KRY.AS can be added in medium-high percentages (10-40 wt%) to commercial mixtures for the production of clay bricks, rock-wool glasses for insulation as well as Ca-based frits and glass-ceramics for the production of ceramic tiles. The secondary raw material was also used for the synthesis of two ceramic pigments; a green uvarovite-based pigment [Ca{sub 3}Cr{sub 2}(SiO{sub 4}){sub 3}] and a pink malayaite-based pigment [Ca(Sn,Cr)SiO{sub 5}]. The latter is especially interesting as a substitute for cadmium-based pigments. This work also shows that KRY.AS can replace standard fillers in polypropylene plastics without altering the properties of the final product. For each application, a description and relevant results are presented and discussed.

  11. Effect of stainless steel weld overlay cladding on the structural integrity of flawed steel plates in bending. Series 1

    SciTech Connect (OSTI)

    Corwin, W.R.; Robinson, G.C.; Nanstad, R.K.; Merkle, J.G.; Berggren, R.G.; Goodwin, G.M.; Swain, R.L.; Owings, T.D.

    1985-04-01

    The Heavy-Section Steel Technology (HSST) Stainless Steel Cladding Evaluations were undertaken to study the interaction of stainless steel cladding on the inside surface of a reactor pressure vessel with flaws initiating and propagating in base metal. With the more recent focus of safety studies on overcooling type transients, for which the behavior of small flaws is important, stainless steel cladding may have a key role in controlling the propagation and/or arrest of propagating flaws. A complicating factor in understanding the role of stainless steel cladding in this setting is the scarcity of data on its fracture toughness as a function of radiation dose and the fabrication process. The initial phase of the HSST evaluations addresses this question by testing the response of 51-mm-thick flawed plates clad with single-wire, submerged-arc weld overlays of different toughness levels. The tests completed indicate that cladding of moderate toughness had a limited ability to enhance the structural arrest toughness of a beam in bending. The specimen design and fabrication techniques employed for this first completed series of tests resulted in flaw and specimen configurations that prevented adequate control of the stress state at pop-in of the hydrogen-charged electron-beam welds. As a result, analyses of the tests by two approximate techniques and by the ORMGEN-ADINA-ORVIRT finite-element programs were not completely consistent.

  12. Friction Stir Welding of ODS and RAFM Steels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Zhenzhen; Feng, Zhili; Hoelzer, David; Tan, Lizhen; Sokolov, Mikhail A.

    2015-09-14

    Advanced structural materials such as oxide dispersion strengthened steels and reduced-activation ferritic/martensitic steels are desired in fusion reactors as primary candidate materials for first wall and blanket structures, due to their excellent radiation and high-temperature creep resistance. However, their poor fusion weldability has been the major technical challenge limiting practical applications. For this reason, solid-state friction stir welding (FSW) has been considered for such applications. In this paper, the effect of FSW parameters on joining similar and dissimilar advanced structural steels was investigated. Scanning electron microscopy and electron backscatter diffraction methods were used to reveal the effects of FSW onmore » grain size, micro-texture distribution, and phase stability. Hardness mapping was performed to evaluate mechanical properties. Finally, post weld heat treatment was also performed to tailor the microstructure in the welds in order to match the weld zone mechanical properties to the base material.« less

  13. Practical handbook of stainless steels and nickel alloys

    SciTech Connect (OSTI)

    Lamb, S.

    1999-07-01

    This new handbook is an up-to-date technical guide to the grades, properties, fabrication characteristics, and applications of stainless steels and nickel alloys. The individual chapters were written by industry experts and focus on the key properties and alloy characteristics important in material selection and specification as well as the practical factors that influence the development and application of these materials. The contents include: alloy grades and their welding and fabrication characteristics and their application; monel metal; iron-based and nickel-based alloys; ferritic, austenitic, superaustenitic, and martensitic stainless steels; hastelloys; alloys 20, G, and 825; AOD and new refining technology; duplex stainless steels; 6-Mo alloys; corrosion-resistant castings; specification cross-reference tables; trade names; hardness conversions; list of common abbreviations.

  14. Friction Stir Welding of ODS and RAFM Steels

    SciTech Connect (OSTI)

    Yu, Zhenzhen; Feng, Zhili; Hoelzer, David; Tan, Lizhen; Sokolov, Mikhail A.

    2015-09-14

    Advanced structural materials such as oxide dispersion strengthened steels and reduced-activation ferritic/martensitic steels are desired in fusion reactors as primary candidate materials for first wall and blanket structures, due to their excellent radiation and high-temperature creep resistance. However, their poor fusion weldability has been the major technical challenge limiting practical applications. For this reason, solid-state friction stir welding (FSW) has been considered for such applications. In this paper, the effect of FSW parameters on joining similar and dissimilar advanced structural steels was investigated. Scanning electron microscopy and electron backscatter diffraction methods were used to reveal the effects of FSW on grain size, micro-texture distribution, and phase stability. Hardness mapping was performed to evaluate mechanical properties. Finally, post weld heat treatment was also performed to tailor the microstructure in the welds in order to match the weld zone mechanical properties to the base material.

  15. Cyclic corrosion crack resistance curves of certain vessel steels

    SciTech Connect (OSTI)

    Panasyuk, V.V.; Fedorova, V.A.; Pusyak, S.A.; Ratych, L.V.; Timofeev, L.V.; Zuezdin, Y.I.

    1985-11-01

    Results are presented of investigations of 15Kh2MFA and 15Kh2NMFA steels. In the first stage of the investigations, the cyclic corrosion crack resistance characteristics were determined with limiting values of the various factors: loading frequency, loading cycle stress ratio, temperature and length of service. An intense flow of ionizing radiation may markedly change the mechanical properties in 30-40 years; this acts on the reactor vessel. The experimental data for strength categories KP-45 and KP-90 of both vessel steels lies in a quite narrow band of spread, which provides a basis for representing it by a single generalized curve, presented here. The result of cyclic corrosion crack resistance tests of disk specimens of 15Kh2MFA and 15Kh2NMFA vessel steels in boric acid controlled reactor water solution in distilled water with the addition of KOH to pH 8 was established.

  16. Metallic sheathing for protection of steel in seawater

    SciTech Connect (OSTI)

    Kirk, W.W.

    1987-09-01

    A review of 37 years of experience with metallic sheathing to protect the splash and tidal zones of structural steel in seawater is presented. Variations in the corrosivity of the environment from zone to zone on a vertical structure and the interdependence among them are discussed. Corrosion-resistant alloys for sheathing include Monel (NiCu) Alloy 400, copper-nickel alloys, and stainless steel. The advantages and disadvantages of these noble alloys are compared with those of other protective materials such as paint coatings, concrete, polymers, and steel itself. Adequate protection of hot risers is critical and quite easily provided through proper design and sheathing attachment. The use of 90:10 copper-nickel Alloy C70600 is gaining visibility with progressive technology to provide biofouling control as well as corrosion protection.

  17. Electrical resistance tomography from measurements inside a steel cased borehole

    DOE Patents [OSTI]

    Daily, William D.; Schenkel, Clifford; Ramirez, Abelardo L.

    2000-01-01

    Electrical resistance tomography (ERT) produced from measurements taken inside a steel cased borehole. A tomographic inversion of electrical resistance measurements made within a steel casing was then made for the purpose of imaging the electrical resistivity distribution in the formation remotely from the borehole. The ERT method involves combining electrical resistance measurements made inside a steel casing of a borehole to determine the electrical resistivity in the formation adjacent to the borehole; and the inversion of electrical resistance measurements made from a borehole not cased with an electrically conducting casing to determine the electrical resistivity distribution remotely from a borehole. It has been demonstrated that by using these combined techniques, highly accurate current injection and voltage measurements, made at appropriate points within the casing, can be tomographically inverted to yield useful information outside the borehole casing.

  18. Multi analysis of the effect of grain size on the dynamic behavior of microalloyed steels

    SciTech Connect (OSTI)

    Zurek, Anna K; Muszka, K; Majta, J; Wielgus, M

    2009-01-01

    This study presents some aspects of multiscale analysis and modeling of variously structured materials behavior in quasi-static and dynamic loading conditions. The investigation was performed for two different materials of common application: high strength microalloyed steel (HSLA, X65), and as a reference more ductile material, Ti-IF steel. The MaxStrain technique and one pass hot rolling processes were used to produce ultrafine-grained and coarse-grained materials. The efficiency and inhomogeneity of microstructure refinement were examined because of their important role in work hardening and the initiation and growth of fracture under tensile stresses. It is shown that the combination of microstructures characterized by their different features contributes to the dynamic behavior and final properties of the product. In particular, the role of solute segregation at grain boundaries as well as precipitation of carbonitrides in coarse and ultrafine-grained structures is assessed. The predicted mechanical response of ultrafine-grained structures, using modified KHL model is in reasonable agreement with the experiments. This is a result of proper representation of the role of dislocation structure and the grain boundary and their multiscale effects included in this model.

  19. Corrosion experiments on stainless steels used in dry storage canisters of spent nuclear fuel

    SciTech Connect (OSTI)

    Ryskamp, J.M.; Adams, J.P.; Faw, E.M.; Anderson, P.A.

    1996-09-01

    Nonradioactive (cold) experiments have been set up in the Idaho Chemical Processing Plant (ICPP)-1634, and radioactive (hot) experiments have been set up in the Irradiated Fuel Storage Facility (IFSF) at ICPP. The objective of these experiments is to provide information on the interactions (corrosion) between the spent nuclear fuel currently stored at the ICPP and the dry storage canisters and containment materials in which this spent fuel will be stored for the next several decades. This information will be used to help select canister materials that will retain structural integrity over this period within economic, criticality, and other constraints. The two purposes for Dual Purpose Canisters (DPCs) are for interim storage of spent nuclear fuel and for shipment to a final geological repository. Information on how corrosion products, sediments, and degraded spent nuclear fuel may corrode DPCs will be required before the DPCs will be allowed to be shipped out of the State of Idaho. The information will also be required by the Nuclear Regulatory Commission (NRC) to support the licensing of DPCs. Stainless steels 304L and 316L are the most likely materials for dry interim storage canisters. Welded stainless steel coupons are used to represent the canisters in both hot and cold experiments.

  20. Development of Stronger and More Reliable Cast Austenitic Stainless Steels (H-Series) Based on Scientific Design Methodology

    SciTech Connect (OSTI)

    Muralidharan, G.; Sikka, V.K.; Pankiw, R.I.

    2006-04-15

    The goal of this program was to increase the high-temperature strength of the H-Series of cast austenitic stainless steels by 50% and upper use temperature by 86 to 140 F (30 to 60 C). Meeting this goal is expected to result in energy savings of 38 trillion Btu/year by 2020 and energy cost savings of $185 million/year. The higher strength H-Series of cast stainless steels (HK and HP type) have applications for the production of ethylene in the chemical industry, for radiant burner tubes and transfer rolls for secondary processing of steel in the steel industry, and for many applications in the heat-treating industry. The project was led by Duraloy Technologies, Inc. with research participation by the Oak Ridge National Laboratory (ORNL) and industrial participation by a diverse group of companies. Energy Industries of Ohio (EIO) was also a partner in this project. Each team partner had well-defined roles. Duraloy Technologies led the team by identifying the base alloys that were to be improved from this research. Duraloy Technologies also provided an extensive creep data base on current alloys, provided creep-tested specimens of certain commercial alloys, and carried out centrifugal casting and component fabrication of newly designed alloys. Nucor Steel was the first partner company that installed the radiant burner tube assembly in their heat-treating furnace. Other steel companies participated in project review meetings and are currently working with Duraloy Technologies to obtain components of the new alloys. EIO is promoting the enhanced performance of the newly designed alloys to Ohio-based companies. The Timken Company is one of the Ohio companies being promoted by EIO. The project management and coordination plan is shown in Fig. 1.1. A related project at University of Texas-Arlington (UT-A) is described in Development of Semi-Stochastic Algorithm for Optimizing Alloy Composition of High-Temperature Austenitic Stainless Steels (H-Series) for Desired

  1. Wear-Resistant NanoCompositeStainless Steel Coatings and Bits

    Broader source: Energy.gov [DOE]

    Project objective: To develop ultra-hard and wear resistant nanocompositestainless steel coatings and bulk components for geothermal drilling applications.

  2. Manufacturing Energy and Carbon Footprint- Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006)

    Office of Energy Efficiency and Renewable Energy (EERE)

    Manufacturing Energy and Carbon Footprint for Iron and Steel Sector (NAICS 3311, 3312) with Total Energy Input

  3. Bandwidth Study U.S. Iron and Steel Manufacturing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Iron and Steel Manufacturing Bandwidth Study U.S. Iron and Steel Manufacturing Bandwidth Study U.S. Iron and Steel Manufacturing Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. iron and steel manufacturing. The study relies on multiple sources to estimate the energy used in

  4. Effect of neutron irradiation on mechanical properties of ferritic steels

    SciTech Connect (OSTI)

    Kass, S.B.; Murty, K.L.

    1995-12-31

    Effect of neutron radiation exposure was investigated in various ferritic steels with the main emphasis being the effects of thermal neutrons on radiation hardening. Pure iron of varied grain sizes was also used for characterizing the grain size effects on the source hardening before and after neutron irradiation. While many steels are considered in the overall study, the results on 1020, A516 and A588 steels are emphasized. Radiation hardening due to fast neutrons was seen to be sensitive to the composition of the steels with A354 being the least resistant and A490 the least sensitive. Majority of the radiation hardening stems from friction hardening, and source hardening term decreased with exposure to neutron radiation apparently due to the interaction of interstitial impurities with radiation produced defects. Inclusion of thermal neutrons along with fast resulted in further decrease in the source hardening with a slight increase in the friction hardening which revealed a critical grain size below which exposure to total (fast and thermal) neutron spectrum resulted in a slight reduction in the yield stress compared to the exposure to only fast neutrons. This is the first time such a grain size effect is reported and this is shown to be consistent with known radiation effects on friction and source hardening terms along with the observation that low energy neutrons have a nonnegligible effect on the mechanical properties of steels. In ferritic steels, however, despite their small grain size, exposure to total neutron spectrum yielded higher strengths than exposure to only fast neutrons. This behavior is consistent with the fact that the source hardening is small in these alloys and radiation effect is due only to friction stress.

  5. Surface cracking in resistance seam welding of coated steels

    SciTech Connect (OSTI)

    Adonyi, Y.; Kimchi, M.

    1994-12-31

    In this experimental work, the focus was on the understanding the electrode-wheel/coated steel surface phenomena by building operational lobes and by correlating the weld quality with static-and dynamic-contact-resistance variation during welding. Conventional AC, DC, and electrode-wire resistance-seam weldability of printed zinc-coated and hot-dipped tin-coated steel was performed in this work, as compared with traditional lead-tin (terne) coating used as reference material. Variables included steel substrate type, welding equipment type, electrode-wheel cleaning practice, and electrode-wire geometry. Optic and electron microscopy were used for the evaluation of specimens extracted from longitudinal cross-sections of representative welds. The size and morphology of surface cracks was characterized and correlated with variations in the above-mentioned parameters. It was found that the tin-coated (unpainted) steel sheet had a superior all-together performance to the zinc-coated steel and terne-coated steel, both in terms of wider weldability lobes and lesser surface cracking. The extent of surface cracking was greatly reduced by using the electrode-wire seam welding process using a longitudinally grooved wire profile, which also widened the corresponding weldability lobes. It was also found that the extent of cracking depended on the electrode knurl geometry, substrate type, and the presence of conductive paint applied on top of the metallic coating. An attempt was made to characterize the specific mechanisms governing the LME phenomenon for the lead-, zinc and tin-based coating systems and to assess the potential for crack propagation in the welds. The dynamic contact resistance was found to be a good measure of the welding process stability and an indicator of defect formation. It was found that the ratio between the static and dynamic contact resistances of the tin-coated sheet was considerably lower than similar ratios for bare and zinc-coated sheet.

  6. Reliability-based condition assessment of steel containment and liners

    SciTech Connect (OSTI)

    Ellingwood, B.; Bhattacharya, B.; Zheng, R.

    1996-11-01

    Steel containments and liners in nuclear power plants may be exposed to aggressive environments that may cause their strength and stiffness to decrease during the plant service life. Among the factors recognized as having the potential to cause structural deterioration are uniform, pitting or crevice corrosion; fatigue, including crack initiation and propagation to fracture; elevated temperature; and irradiation. The evaluation of steel containments and liners for continued service must provide assurance that they are able to withstand future extreme loads during the service period with a level of reliability that is sufficient for public safety. Rational methodologies to provide such assurances can be developed using modern structural reliability analysis principles that take uncertainties in loading, strength, and degradation resulting from environmental factors into account. The research described in this report is in support of the Steel Containments and Liners Program being conducted for the US Nuclear Regulatory Commission by the Oak Ridge National Laboratory. The research demonstrates the feasibility of using reliability analysis as a tool for performing condition assessments and service life predictions of steel containments and liners. Mathematical models that describe time-dependent changes in steel due to aggressive environmental factors are identified, and statistical data supporting the use of these models in time-dependent reliability analysis are summarized. The analysis of steel containment fragility is described, and simple illustrations of the impact on reliability of structural degradation are provided. The role of nondestructive evaluation in time-dependent reliability analysis, both in terms of defect detection and sizing, is examined. A Markov model provides a tool for accounting for time-dependent changes in damage condition of a structural component or system. 151 refs.

  7. Metabolic Noise, Vestigial Metabolites or the Raw Material of Ecological Adaptation? Opportunitistic Enzymes, Catalytic Promiscuity and the Evolution of chemodiversity in Nature (2010 JGI User Meeting)

    ScienceCinema (OSTI)

    Noel, Joseph

    2011-04-25

    Joseph Noel from the Salk Institute on "Metabolic Noise, Vestigial Metabolites or the Raw Material of Ecological Adaptation? Enzymes, Catalytic Promiscuity and the Evolution of Chemodiversity in Nature" on March 26, 2010 at the 5th Annual DOE JGI User Meeting

  8. THE SENSITIVITY OF CARBON STEELS' SUSCEPTIBILITY TO LOCALIZED CORROSION TO THE PH OF NITRATE BASED NUCLEAR WASTES

    SciTech Connect (OSTI)

    BOOMER KD

    2010-01-14

    The Hanford tank reservation contains approximately 50 million gallons of liquid legacy radioactive waste from cold war weapons production, which is stored in 177 underground storage tanks. The tanks will be in use until waste processing operations are completed. The wastes tend to be high pH (over 10) and nitrate based. Under these alkaline conditions carbon steels tend to be passive and undergo relatively slow uniform corrosion. However, the presence of nitrate and other aggressive species, can lead to pitting and stress corrosion cracking. This work is a continuation of previous work that investigated the propensity of steels to suffer pitting and stress corrosion cracking in various waste simulants. The focus of this work is an investigation of the sensitivity of the steels' pitting and stress corrosion cracking susceptibility tosimulant pH. Previous work demonstrated that wastes that are high in aggressive nitrate and low in inhibitory nitrite are susceptible to localized corrosion. However, the previous work involved wastes with pH 12 or higher. The current work involves wastes with lower pH of 10 or 11. It is expected that at these lower pHs that a higher nitrite-to-nitrate ratio will be necessary to ensure tank integrity. This experimental work involved both electrochemical testing, and slow strain rate testing at either the free corrosion potential or under anodic polarization. The results of the current work will be discussed, and compared to work previously presented.

  9. Comparison of precipitate behaviors in ultra-low carbon, titanium-stabilized interstitial free steel sheets under different annealing processes

    SciTech Connect (OSTI)

    Shi, J.; Wang, X.

    1999-12-01

    Ultra-low carbon, titanium-stabilized interstitial free (ULC Ti-IF) steel sheets are widely used in the automobile industry because of excellent deep drawability. The annealing process is critical to their final property, and there are two different annealing processes used in industrial production of interstitial free (IF) steel sheets, namely batch annealing and continuous annealing. In this study, precipitation behaviors of titanium IF steels, that is, TiN, TiS, Ti{sub 4}(CS){sub 2}, and TiC, the size and dispersion of TiN, TiS, and Ti{sub 4}(CS){sub 2} remained almost unchanged after either annealing process. Conversely, the average size of a TiC particle increased substantially after both annealing processes, while TiC after continuous annealing was larger than that after batch annealing due to the higher heating temperature of continuous annealing. Two new particles, FeTiP and (Ti, Mn)S, were also observed in the batch annealing process but not in continuous annealing. The structure of FeTiP and (Ti, Mn)S were studied, and furthermore the evolution of FeTiP precipitation was found to be closely related to recrystallization in batch annealing. Finally, the interrelation among processing parameters, precipitation behaviors, and final property was studied.

  10. Mr. Frank Archer President Niagara Cold Drawn Steel Corporation

    Office of Legacy Management (LM)

    Department of Energy Washington, DC 20585 FEB 2 1 1991 ' i-. 1,; ' -, f ' + \ 1 : , .J p- * c - Mr. Frank Archer President Niagara Cold Drawn Steel Corporation 110 Hopkins Street P.O. Box 399 Buffalo, NY 14240 Dear Mr. Archer: I have executed the consent forms for the performance of a radiological survey of the Niagara Cold Drawn Steel Corporation's property under the Formerly Utilized Sites Remedial Action Program (FUSRAP) of the U.S. Department of Energy (DOE). I enclose a copy of the consent

  11. Friction Stir Spot Welding of Advanced High Strength Steels

    SciTech Connect (OSTI)

    Hovanski, Yuri; Santella, M. L.; Grant, Glenn J.

    2009-12-28

    Friction stir spot welding was used to join two advanced high-strength steels using polycrystalline cubic boron nitride tooling. Numerous tool designs were employed to study the influence of tool geometry on weld joints produced in both DP780 and a hot-stamp boron steel. Tool designs included conventional, concave shouldered pin tools with several pin configurations; a number of shoulderless designs; and a convex, scrolled shoulder tool. Weld quality was assessed based on lap shear strength, microstructure, microhardness, and bonded area. Mechanical properties were functionally related to bonded area and joint microstructure, demonstrating the necessity to characterize processing windows based on tool geometry.

  12. Phase transformations in steels: Processing, microstructure, and performance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gibbs, Paul J.

    2014-04-03

    In this study, contemporary steel research is revealing new processing avenues to tailor microstructure and properties that, until recently, were only imaginable. Much of the technological versatility facilitating this development is provided by the understanding and utilization of the complex phase transformation sequences available in ferrous alloys. Today we have the opportunity to explore the diverse phenomena displayed by steels with specialized analytical and experimental tools. Advances in multi-scale characterization techniques provide a fresh perspective into microstructural relationships at the macro- and micro-scale, enabling a fundamental understanding of the role of phase transformations during processing and subsequent deformation.

  13. Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 2005 HYDROGEN EMBRITTLEMENT OF PIPELINE STEELS: CAUSES AND REMEDIATION P. Sofronis, I. Robertson, D. Johnson University of Illinois at Urbana-Champaign Hydrogen Pipeline R&D Project Review Meeting Oak Ridge National Laboratory, Oak Ridge TN January 5-6, 2005 2 January 2005 Hydrogen Embrittlement: Long History M.L. Cailletet (1868) in Comptes Rendus, 68, 847-850 W. H. Johnson (1875) On some remarkable changes produced in iron and steels by the action of hydrogen acids. Proc. R. Soc.

  14. TRP 9904 - Constitutive Behavior of High Strength Multiphase Sheel Steel Under High Strain Rate Deformation

    SciTech Connect (OSTI)

    David Matlock; John Speer

    2005-03-31

    The focus of the research project was to systematically assess the strain rate dependence of strengthening mechanisms in new advanced high strength sheet steels. Data were obtained on specially designed and produced Duel Phase and TRIP steels and compared to the properties of automotive steels currently in use.

  15. Preparation of delisting petition for SRS (Savannah River Site) raw materials waste sludge---Mixed F006 waste

    SciTech Connect (OSTI)

    Langton, C.A.

    1989-01-01

    Waste sludge from the raw materials manufacturing facility at the Savannah River Site contains both hazardous and low-level radioactive components. This waste, which contains electroplating sludge and depleted uranium, is classified as a mixed waste. The objective of the delisting petition is to demonstrate that this waste can be treated/solidified in a cement-based material and disposed of in concrete vaults so that drinking water standards will not be exceeded. Sampling and analytical data which support this petition will be presented. Results show that when the data are applied to the EPA Vertical and Horizontal Spread Model, health-based standards for all hazardous waste constituents will not be exceeded during worst case operating and environmental conditions. Disposal of stabilized sludge in concrete vaults will also meet the requirements of DOE Order 5820.2A and the March 9, 1988 DOE Record of Decision which outline criteria for low-level radioactive waste disposal at the Savannah River Site. 9 refs., 2 figs., 3 tabs.

  16. Creep of A508/533 Pressure Vessel Steel

    SciTech Connect (OSTI)

    Richard Wright

    2014-08-01

    ABSTRACT Evaluation of potential Reactor Pressure Vessel (RPV) steels has been carried out as part of the pre-conceptual Very High Temperature Reactor (VHTR) design studies. These design studies have generally focused on American Society of Mechanical Engineers (ASME) Code status of the steels, temperature limits, and allowable stresses. Initially, three candidate materials were identified by this process: conventional light water reactor (LWR) RPV steels A508 and A533, 2¼Cr-1Mo in the annealed condition, and Grade 91 steel. The low strength of 2¼Cr-1Mo at elevated temperature has eliminated this steel from serious consideration as the VHTR RPV candidate material. Discussions with the very few vendors that can potentially produce large forgings for nuclear pressure vessels indicate a strong preference for conventional LWR steels. This preference is based in part on extensive experience with forging these steels for nuclear components. It is also based on the inability to cast large ingots of the Grade 91 steel due to segregation during ingot solidification, thus restricting the possible mass of forging components and increasing the amount of welding required for completion of the RPV. Grade 91 steel is also prone to weld cracking and must be post-weld heat treated to ensure adequate high-temperature strength. There are also questions about the ability to produce, and very importantly, verify the through thickness properties of thick sections of Grade 91 material. The availability of large components, ease of fabrication, and nuclear service experience with the A508 and A533 steels strongly favor their use in the RPV for the VHTR. Lowering the gas outlet temperature for the VHTR to 750°C from 950 to 1000°C, proposed in early concept studies, further strengthens the justification for this material selection. This steel is allowed in the ASME Boiler and Pressure Vessel Code for nuclear service up to 371°C (700°F); certain excursions above that temperature are

  17. Low Temperature Surface Carburization of Stainless Steels

    SciTech Connect (OSTI)

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  18. Ferrite Measurement in Austenitic and Duplex Stainless Steel Castings - Final Report

    SciTech Connect (OSTI)

    Lundin, C.D.; Zhou, G.; Ruprecht, W.

    1999-08-01

    The ability to determine ferrite rapidly, accurately and directly on a finished casting, in the solution annealed condition, can enhance the acceptance, save on manufacturing costs and ultimately improve service performance of duplex stainless steel cast products. If the suitability of a non-destructive ferrite determination methodology can be demonstrated for standard industrial measurement instruments, the production of cast secondary standards for calibration of these instruments is a necessity. With these concepts in mind, a series of experiments were carried out to demonstrate, in a non-destructive manner, the proper methodology for determining ferrite content. The literature was reviewed, with regard to measurement techniques and vagaries, an industrial ferrite measurement round-robin was conducted, the effects of casting surface finish, preparation of the casting surface for accurate measurement and the evaluation of suitable means for the production of cast secondary standards for calibration were systematically investigated. The data obtained from this research program provide recommendations to ensure accurate, repeatable, and reproducible ferrite measurement and qualifies the Feritscope for field use on production castings.

  19. DEVELOPMENT OF ELECTROMAGNETIC TECHNIQUES FOR HYDROGEN CONTENT ASSESSMENT IN COATED LINEPIPE STEEL

    SciTech Connect (OSTI)

    Lasseigne-Jackson, A. N.; Anton, J.; Jackson, J. E.; Olson, D. L.; Mishra, B.

    2008-02-28

    With the introduction of new higher strength steels operating at higher pressure, the need for characterization of hydrogen content in high strength steel pipelines is timely for the pipeline industry. The higher-strength steel pipelines have higher susceptibility to hydrogen damage. Through the use of low-frequency induced current impedance measurements, a new non-contact sensor has been developed for real-time determination of diffusible hydrogen content in coated pipeline steel. A measurement scheme to separate variables associated with pipelines is discussed. This electromagnetic technique allows for a rapid, non-destructive assessment of hydrogen accumulation in coated steel line pipe and thus an evaluation of the pipeline integrity.

  20. Stress-corrosion cracking of sensitized stainless steel by sulfur-containing compounds

    SciTech Connect (OSTI)

    Isaacs, H.S.; Vyas, B.; Kendig, M.W.

    1981-01-01

    The stress corrosion cracking (SCC) of sensitized Type 304 stainless steel in thiosulfate solutions has been studied using constant extension rate tests. Very low concentrations of about 6.10/sup -7/M Na/sub 2/S/sub 2/O/sub 3/ (0.1ppm) gave cracking. With boric acid added, higher concentrations (1ppm) were required. The SCC was shown to be electrochemically controlled. Below -0.5v/sub SCE/ (-0.75/sub SHE/) no SCC took place; above this potential the rate of SCC increased with potential. An induction period was required before SCC continued above -0.5v if the potential was held at or below this value for extended times. This period was associated with the build up of an aggressive solution of thiosulfate decomposition products within the crack. The cracking process has been considered to be controlled by rupture of a salt layer and not a passivating oxide.

  1. Field weldability of high strength pipeline steels: Final report

    SciTech Connect (OSTI)

    Noble, D.N.; Pargeter, R.J.

    1988-03-04

    This document reports on small scale weldability tests on two X80 grade steels and presents mechanical property data on full-size circumferential girth welds. This publication is available from the American Gas Association Order Processing Department, 1515 Wilson Boulevard, Arlington, Virginia 22209-2470 (703/841-8558). 6 refs. (JL)

  2. Mechanical properties of four RSP stainless steel alloys

    SciTech Connect (OSTI)

    Korth, G.E.

    1996-12-01

    Four austenitic stainless steel alloys were processed by consolidating rapidly solidified gas atomized power using hot extrusion. These materials were characterized by measuring grain growth, hardness, tensile properties from 24 to 800{degrees}C, and creep-rupture at 600{degrees}C.

  3. Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Barriers: Hydrogen embrittlement of pipelines and remediation (mixing with water vapor?) hpwgw_embrittlementsteels_sofronis.pdf (675.35 KB) More Documents & Publications Webinar: I2CNER: An International Collaboration to Enable a Carbon-Neutral Energy Economy Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation Hydrogen permeability and Integrity of hydrogen transfer pipelines

  4. Oscillation and chaos in pitting corrosion of steel

    SciTech Connect (OSTI)

    Hernandez, M.A.; Rodriguez, F.J.; Garcia, E.; Boerio, F.J.

    1999-11-01

    The potential and current oscillations during pitting corrosion of steel in NaCl solution were studied. Detailed analysis using numerical diagnostics developed to characterize complex time series clearly shows that the irregularity in these time series corresponds to deterministic chaos, rather than to random noise. The chaotic oscillations were characterized by power spectral densities, phase space and Lyapunov exponents.

  5. Electrical resistance tomography using steel cased boreholes as long electrodes

    SciTech Connect (OSTI)

    Daily, W; Newmark, R L; Ramirez, A

    1999-07-20

    Electrical resistance tomography (ERT) using multiple electrodes installed in boreholes has been shown to be useful for both site characterization and process monitoring. In some cases, however, installing multiple downhole electrodes is too costly (e.g., deep targets) or risky (e.g., contaminated sites). For these cases we have examined the possibility of using the steel casings of existing boreholes as electrodes. Several possibilities can be considered. The first case we investigated uses an array of steel casings as electrodes. This results in very few data and thus requires additional constraints to limit the domain of possible inverse solutions. Simulations indicate that the spatial resolution and sensitivity are understandably low but it is possible to coarsely map the lateral extent of subsurface processes such as steam floods. The second case uses an array of traditional point borehole electrodes combined with long-conductor electrodes (steel casings). Although this arrangement provides more data, in many cases it results in poor reconstructions of test targets. Results indicate that this method may hold promise for low resolution imaging where steel casings can be used as electrodes but the merits depend strongly on details of each application. Field tests using these configurations are currently being conducted.

  6. Electrical resistance tomography using steel cased boreholes as electrodes

    SciTech Connect (OSTI)

    Newmark, R L; Daily, W; Ramirez, A

    1999-03-22

    Electrical resistance tomography (ERT) using multiple electrodes installed in boreholes has been shown to be useful for both site characterization and process monitoring. In some cases, however, installing multiple downhole electrodes is too costly (e.g., deep targets) or risky (e.g., contaminated sites). For these cases we have examined the possibility of using the steel casings of existing boreholes as electrodes. The first case we investigated used an array of steel casings as electrodes. This results in very few data and thus requires additional constraints to limit the domain of possible inverse solutions. Simulations indicate that the spatial resolution and sensitivity are understandably low but it is possible to coarsely map the lateral extent of subsurface processes such as steam floods. A hybrid case uses traditional point electrode arrays combined with long-conductor electrodes (steel casings). Although this arrangement provides more data, in many cases it results in poor reconstructions of test targets. Results indicate that this method may hold promise for low resolution imaging where steel casings can be used as electrodes.

  7. Carbon distribution in bainitic steel subjected to deformation

    SciTech Connect (OSTI)

    Ivanov, Yu. F.; Nikitina, E. N. Gromov, V. E.

    2015-10-27

    Analysis of the formation and evolution of carbide phase in medium carbon steel with a bainitic structure during compressive deformation was performed by means of transmission electron diffraction microscopy. Qualitative transformations in carbide phase medium size particles, their density and volume concentration depended on the degree of deformation.

  8. Electrical resistance tomography using steel cased boreholes as electrodes

    DOE Patents [OSTI]

    Daily, W.D.; Ramirez, A.L.

    1999-06-22

    An electrical resistance tomography method is described which uses steel cased boreholes as electrodes. The method enables mapping the electrical resistivity distribution in the subsurface from measurements of electrical potential caused by electrical currents injected into an array of electrodes in the subsurface. By use of current injection and potential measurement electrodes to generate data about the subsurface resistivity distribution, which data is then used in an inverse calculation, a model of the electrical resistivity distribution can be obtained. The inverse model may be constrained by independent data to better define an inverse solution. The method utilizes pairs of electrically conductive (steel) borehole casings as current injection electrodes and as potential measurement electrodes. The greater the number of steel cased boreholes in an array, the greater the amount of data is obtained. The steel cased boreholes may be utilized for either current injection or potential measurement electrodes. The subsurface model produced by this method can be 2 or 3 dimensional in resistivity depending on the detail desired in the calculated resistivity distribution and the amount of data to constrain the models. 2 figs.

  9. Battery and fuel cell electrodes containing stainless steel charging additive

    DOE Patents [OSTI]

    Zuckerbrod, David; Gibney, Ann

    1984-01-01

    An electrode for use in electrochemical energy cells is made, comprising a hydrophilic layer and a hydrophobic layer, where the hydrophilic layer comprises a hydrophilic composite which includes: (i) carbon particles; (ii) stainless steel particles; (iii) a nonwetting agent; and (iv) a catalyst, where at least one current collector contacts said composite.

  10. Electrical resistance tomography using steel cased boreholes as electrodes

    DOE Patents [OSTI]

    Daily, William D.; Ramirez, Abelardo L.

    1999-01-01

    An electrical resistance tomography method using steel cased boreholes as electrodes. The method enables mapping the electrical resistivity distribution in the subsurface from measurements of electrical potential caused by electrical currents injected into an array of electrodes in the subsurface. By use of current injection and potential measurement electrodes to generate data about the subsurface resistivity distribution, which data is then used in an inverse calculation, a model of the electrical resistivity distribution can be obtained. The inverse model may be constrained by independent data to better define an inverse solution. The method utilizes pairs of electrically conductive (steel) borehole casings as current injection electrodes and as potential measurement electrodes. The greater the number of steel cased boreholes in an array, the greater the amount of data is obtained. The steel cased boreholes may be utilized for either current injection or potential measurement electrodes. The subsurface model produced by this method can be 2 or 3 dimensional in resistivity depending on the detail desired in the calculated resistivity distribution and the amount of data to constain the models.

  11. Factory Brings Solar Energy Jobs to Former Steel Town

    Broader source: Energy.gov [DOE]

    Fairless Hills, like many Pennsylvania towns, has a long history with manufacturing. It is home to the Keystone Industrial Port Complex, a manufacturing and industrial site that was once the location of a U.S. Steel plant. So when AE Polysilicon was looking for a site suitable for its polycrystalline silicon plant, the Port Complex seemed like a natural choice.

  12. Superplastic Forming of Duplex Stainless Steel for Aerospace Part

    SciTech Connect (OSTI)

    Lee, Ho-Sung; Yoon, Jong-Hoon; Yoo, Joon-Tae; Yi, Young-Moo

    2011-08-22

    In this study, the high temperature forming behavior of duplex stainless steel has been characterized and the outer shell of a combustion chamber was fabricated with pressure difference of hot gas. It consists of two parts which are the outer skin made of stainless steel to sustain the internal pressure and the inner shell made of copper alloy for regenerative cooling channels. Two outer skins partitioned to half with respect to the symmetric axis was prepared by hot gas forming process with a maximum pressure of 7 MPa following to FEM analysis. For inner layer, copper alloy was machined for cooling channels and then placed in the gas pressure welding fixture. It is shown that the optimum condition of gas pressure welding is 7 MPa at 890 deg. C, for one hour. EDX analysis and scanning electron microscope micrograph confirm the atomic diffusion process is observed at the interface and copper atoms diffuse into steel, while iron and chrome atoms diffuse into copper. The result shows that the manufacturing method with superplastic forming and gas pressure welding of steel and copper alloy has been successful for near net shape manufacturing of scaled combustion chamber of launch vehicle.

  13. Study on tempering behaviour of AISI 410 stainless steel

    SciTech Connect (OSTI)

    Chakraborty, Gopa; Das, C.R.; Albert, S.K.; Bhaduri, A.K.; Thomas Paul, V.; Panneerselvam, G.; Dasgupta, Arup

    2015-02-15

    Martensitic stainless steels find extensive applications due to their optimum combination of strength, hardness and wear-resistance in tempered condition. However, this class of steels is susceptible to embrittlement during tempering if it is carried out in a specific temperature range resulting in significant reduction in toughness. Embrittlement of as-normalised AISI 410 martensitic stainless steel, subjected to tempering treatment in the temperature range of 673–923 K was studied using Charpy impact tests followed by metallurgical investigations using field emission scanning electron and transmission electron microscopes. Carbides precipitated during tempering were extracted by electrochemical dissolution of the matrix and identified by X-ray diffraction. Studies indicated that temper embrittlement is highest when the steel is tempered at 823 K. Mostly iron rich carbides are present in the steel subjected to tempering at low temperatures of around 723 K, whereas chromium rich carbides (M{sub 23}C{sub 6}) dominate precipitation at high temperature tempering. The range 773–823 K is the transition temperature range for the precipitates, with both Fe{sub 2}C and M{sub 23}C{sub 6} types of carbides coexisting in the material. The nucleation of Fe{sub 2}C within the martensite lath, during low temperature tempering, has a definite role in the embrittlement of this steel. Embrittlement is not observed at high temperature tempering because of precipitation of M{sub 23}C{sub 6} carbides, instead of Fe{sub 2}C, preferentially along the lath and prior austenite boundaries. Segregation of S and P, which is widely reported as one of the causes for temper embrittlement, could not be detected in the material even through Auger electron spectroscopy studies. - Highlights: • Tempering behaviour of AISI 410 steel is studied within 673–923 K temperature range. • Temperature regime of maximum embrittlement is identified as 773–848 K. • Results show that type of

  14. Bulk Nanostructured FCC Steels With Enhanced Radiation Tolerance

    SciTech Connect (OSTI)

    Zhang, Xinghang; Hartwig, K. Ted; Allen, Todd; Yang, Yong

    2012-10-27

    The objective of this project is to increase radiation tolerance in austenitic steels through optimization of grain size and grain boundary (GB) characteristics. The focus will be on nanocrystalline austenitic Fe-Cr-Ni alloys with an fcc crystal structure. The long-term goal is to design and develop bulk nanostructured austenitic steels with enhanced void swelling resistance and substantial ductility, and to enhance their creep resistance at elevated temperatures via GB engineering. The combination of grain refinement and grain boundary engineering approaches allows us to tailor the material strength, ductility, and resistance to swelling by 1) changing the sink strength for point defects, 2) by increasing the nucleation barriers for bubble formation at GBs, and 3) by changing the precipitate distributions at boundaries. Compared to ferritic/martensitic steels, austenitic stainless steels (SS) possess good creep and fatigue resistance at elevated temperatures, and better toughness at low temperature. However, a major disadvantage of austenitic SS is that they are vulnerable to significant void swelling in nuclear reactors, especially at the temperatures and doses anticipated in the Advanced Burner Reactor. The lack of resistance to void swelling in austenitic alloys led to the switch to ferritic/martensitic steels as the preferred material for the fast reactor cladding application. Recently a type of austenitic stainless steel, HT-UPS, was developed at ORNL, and is expected to show enhanced void swelling resistance through the trapping of point defects at nanometersized carbides. Reducing the grain size and increasing the fraction of low energy grain boundaries should reduce the available radiation-produced point defects (due to the increased sink area of the grain boundaries), should make bubble nucleation at the boundaries less likely (by reducing the fraction of high-energy boundaries), and improve the strength and ductility under radiation by producing a higher

  15. CLEAN CAST STEEL TECHNOLOGY: DETERMINATION OF TRANSFORMATION DIAGRAMS FOR DUPLEX STAINLESS STEEL.

    SciTech Connect (OSTI)

    Chumbley. L., S.

    2005-09-18

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma (???????????????¯??????????????????????????????³) and chi (???????????????¯??????????????????????????????£) can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling- transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe 22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (???????????????¯??????????????????????????????³ + ???????????????¯??????????????????????????????£) formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations, The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents

  16. HSLA-100 steels: Influence of aging heat treatment on microstructure and properties

    SciTech Connect (OSTI)

    Mujahid, M.; Lis, A.K.; Garcia, C.I.; deArdo, A.J.

    1998-04-01

    The structural steels used in critical construction applications have traditionally been heat-treated low-alloy steels. These normalized and/or quenched and tempered steels derive strength from their carbon contents. Carbon is a very efficient and cost-effective element for increasing strength in ferrite-pearlite or tempered martensitic structures, but it is associated with poor notch toughness. Furthermore, it is well known that both the overall weldability and weldment toughness are inversely related to the carbon equivalent values, especially at high carbon contents. The stringent control needed for the welding of these traditional steels is one of the major causes of high fabrication costs. In order to reduce fabrication cost while simultaneously improving the quality of structural steels, a new family of high-strength low-alloy steels with copper additions (HSLA-100) has been developed. The alloy design philosophy of the new steels includes a reduction in the carbon content, which improves toughness and weldability.

  17. Evolution of carbides in cold-work tool steels

    SciTech Connect (OSTI)

    Kim, Hoyoung; Kang, Jun-Yun; Son, Dongmin; Lee, Tae-Ho; Cho, Kyung-Mox

    2015-09-15

    This study aimed to present the complete history of carbide evolution in a cold-work tool steel along its full processing route for fabrication and application. A sequence of processes from cast to final hardening heat treatment was conducted on an 8% Cr-steel to reproduce a typical commercial processing route in a small scale. The carbides found at each process step were then identified by electron diffraction with energy dispersive spectroscopy in a scanning or transmission electron microscope. After solidification, MC, M{sub 7}C{sub 3} and M{sub 2}C carbides were identified and the last one dissolved during hot compression at 1180 °C. In a subsequent annealing at 870 °C followed by slow cooling, M{sub 6}C and M{sub 23}C{sub 6} were added, while they were dissolved in the following austenitization at 1030 °C. After the final tempering at 520 °C, fine M{sub 23}C{sub 6} precipitated again, thus the final microstructure was the tempered martensite with MC, M{sub 7}C{sub 3} and M{sub 23}C{sub 6} carbide. The transient M{sub 2}C and M{sub 6}C originated from the segregation of Mo and finally disappeared due to attenuated segregation and the consequent thermodynamic instability. - Highlights: • The full processing route of a cold-work tool steel was simulated in a small scale. • The carbides in the tool steel were identified by chemical–crystallographic analyses. • MC, M{sub 7}C{sub 3}, M{sub 2}C, M{sub 6}C and M{sub 23}C{sub 6} carbides were found during the processing of the steel. • M{sub 2}C and M{sub 6}C finally disappeared due to thermodynamic instability.

  18. Coiled tubing helps gas production

    SciTech Connect (OSTI)

    Matheny, S.L. Jr.

    1980-08-11

    To boost production from its gas fields in Lake Erie, Consumers' Gas Co., Toronto, used a giant reel holding a 33,000-ft coil of 1-in. polypropylene-coated steel tubing to lay about 44 miles of control lines that now service 20 wells 17 miles offshore. As the forward motion of the boat unwound the tubing, the reel rig's hydraulic motor served as a brake to maintain the proper tension. This innovative method of laying the lines eliminated more than 80% of the pipe joints, correspondingly reduced the installation labor time, and improved the system's reliability. The two hydraulic-control lines that were laid actuate the gas-gathering line valves, while a hydrate-control line injects each well with methyl alcohol to inhibit hydrate formation.

  19. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, Milton; Cook, Glenn M.

    1988-01-01

    Apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  20. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1988-05-17

    Apparatus is described for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom. 2 figs.

  1. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1985-05-21

    Disclosed is an apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  2. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction

  3. FINAL REPORT: Reduction in Energy Consumption and Variability in Steel Foundry Operations

    SciTech Connect (OSTI)

    F. Peters

    2005-05-24

    This project worked to improve the efficiency of the steel casting industry by reducing the variability that occurs because of process and product variation. The project focused on the post shakeout operations since roughly half of the production costs are in this area. These improvements will reduce the amount of variability, making it easier to manage the operation and improve the competitiveness. The reduction in variability will also reduce the need for many rework operations, which will result in a direct reduction of energy usage, particularly by the reduction of repeated heat treatment operations. Further energy savings will be realized from the reduction of scrap and reduced handling. Field studies were conducted at ten steel foundries that represented the U.S. steel casting industry, for a total of over 100 weeks of production observation. These studies quantified the amount of variability, and looked toward determining the source. A focus of the data collected was the grinding operations since this is a major effort in the cleaning room, and it represents the overall casting quality. The grinding was divided into two categories, expected and unexpected. Expected grinding is that in which the location of the effort is known prior to making the casting, such as smoothing parting lines, gates, and riser contacts. Unexpected grinding, which was approximately 80% of the effort, was done to improve the surfaces at weld repair locations, to rectify burnt on sand, and other surface anomalies at random locations. Unexpected grinding represents about 80% of the grinding effort. By quantifying this effort, the project raised awareness within the industry and the industry is continuing to make improvements. The field studies showed that the amount of variation of grinding operations (normalized because of the diverse set of parts studied) was very consistent across the industry. The field studies identified several specific sources that individually contributed to

  4. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-08-11

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the facility modifications for continuous hydrotreating, as well as developing improved protocols for producing synthetic pitches.

  5. Estimation of breast percent density in raw and processed full field digital mammography images via adaptive fuzzy c-means clustering and support vector machine segmentation

    SciTech Connect (OSTI)

    Keller, Brad M.; Nathan, Diane L.; Wang Yan; Zheng Yuanjie; Gee, James C.; Conant, Emily F.; Kontos, Despina

    2012-08-15

    Purpose: The amount of fibroglandular tissue content in the breast as estimated mammographically, commonly referred to as breast percent density (PD%), is one of the most significant risk factors for developing breast cancer. Approaches to quantify breast density commonly focus on either semiautomated methods or visual assessment, both of which are highly subjective. Furthermore, most studies published to date investigating computer-aided assessment of breast PD% have been performed using digitized screen-film mammograms, while digital mammography is increasingly replacing screen-film mammography in breast cancer screening protocols. Digital mammography imaging generates two types of images for analysis, raw (i.e., 'FOR PROCESSING') and vendor postprocessed (i.e., 'FOR PRESENTATION'), of which postprocessed images are commonly used in clinical practice. Development of an algorithm which effectively estimates breast PD% in both raw and postprocessed digital mammography images would be beneficial in terms of direct clinical application and retrospective analysis. Methods: This work proposes a new algorithm for fully automated quantification of breast PD% based on adaptive multiclass fuzzy c-means (FCM) clustering and support vector machine (SVM) classification, optimized for the imaging characteristics of both raw and processed digital mammography images as well as for individual patient and image characteristics. Our algorithm first delineates the breast region within the mammogram via an automated thresholding scheme to identify background air followed by a straight line Hough transform to extract the pectoral muscle region. The algorithm then applies adaptive FCM clustering based on an optimal number of clusters derived from image properties of the specific mammogram to subdivide the breast into regions of similar gray-level intensity. Finally, a SVM classifier is trained to identify which clusters within the breast tissue are likely fibroglandular, which are then

  6. Hydrogen Production

    SciTech Connect (OSTI)

    2014-09-01

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produce hydrogen. It includes an overview of research goals as well as “quick facts” about hydrogen energy resources and production technologies.

  7. Isotopes Products

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotopes Products Isotopes Products Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Products stress and rest Stress and rest Rb-82 PET images in a patient with dipyridamole stress-inducible lateral wall and apical ischemia. (http://www.fac.org.ar/scvc/llave/image/machac/machaci.htm#f2,3,4) Strontium-82 is supplied to our customers for use in Sr-82/Rb-82 generator technologies. The generators in turn are supplied to

  8. Production summary for extended barrel module fabrication at Argonne for the ATLAS tile calorimeter.

    SciTech Connect (OSTI)

    Guarino, V.; Hill, N.; Petereit, E.; Skrzecz, F.; Wood, K.; Proudfoot, J.; Anderson, S.; Caird, A.; Keyser, C.; Kocenko, L.; Matijas, Z.; Nephew, T.; Stanek, R.; Franchini, F.; High Energy Physics

    2007-11-14

    for installation, with a design gap between submodules on the girder of 0.3mm. During production we relaxed this tolerance to +0.3, -1.5mm. The height summary for submodules used at Argonne is shown in Appendix I. About 10 submodules fell outside the positive height envelope (due to the raw plate thickness being out of specification) and we constructed some custom short submodules to allow their use in module assembly. The structural girders were produced commercially following the Quality Control plan agreed to with the Tile Calorimeter collaboration and shipped to Argonne. The crucial tolerances on the girder are the key into which submodules are placed as well as the flatness of the key surface which are used in aligning submodules such that the azimuthal surface lies wholly an envelope of +0.75mm from nominal [6]. Another important characteristic of the girder are clearance holes through which the wavelength shift fibers pass to couple the light to photomultipliers located inside the girder, as described in [2]. Since these fiber bundles must be located to high precision, rather than position the holes in the steel to this precision, tooling was developed by which the precision pieces are glued into the girder [7]. This is shown in figure 3. More details on the pieces used to accomplish this interface to the readout electronics are discussed in [2].

  9. Evaluation of zircon brick for steel ladle slag lines

    SciTech Connect (OSTI)

    Brezny, B.; Engel, R.

    1984-07-01

    Six zircon-containing brick were evaluated for steel ladle slag line application. The following physical properties were studied: density, porosity, creep, slag resistance, thermal expansion, thermal shock resistance and thermal conductivity, and compared to a high-purity 70% Al/sub 2/O/sub 3/ containing ladle brick. The data, in particular a zircon refractory's resistance to slag erosion, indicated they should give better performance than the presently used 70% Al/sub 2/O/sub 3/ refractories. Two field trials were run in steel ladle slag lines. Inspections of the ladles during and after service showed no difference in performance between zircon and 70% Al/sub 2/O/sub 3/-containing refractories.

  10. Monitoring microstructural evolution in irradiated steel with second harmonic generation

    SciTech Connect (OSTI)

    Matlack, Kathryn H.; Kim, Jin-Yeon; Jacobs, Laurence J.; Wall, James J.; Qu, Jianmin

    2015-03-31

    Material damage in structural components is driven by microstructural evolution that occurs at low length scales and begins early in component life. In metals, these microstructural features are known to cause measurable changes in the acoustic nonlinearity parameter. Physically, the interaction of a monochromatic ultrasonic wave with microstructural features such as dislocations, precipitates, and vacancies, generates a second harmonic wave that is proportional to the acoustic nonlinearity parameter. These nonlinear ultrasonic techniques thus have the capability to evaluate initial material damage, particularly before crack initiation and propagation occur. This paper discusses how the nonlinear ultrasonic technique of second harmonic generation can be used as a nondestructive evaluation tool to monitor microstructural changes in steel, focusing on characterizing neutron radiation embrittlement in nuclear reactor pressure vessel steels. Current experimental evidence and analytical models linking microstructural evolution with changes in the acoustic nonlinearity parameter are summarized.

  11. Technique to eliminate helium induced weld cracking in stainless steels

    SciTech Connect (OSTI)

    Chin-An Wang; Chin, B.A.; Grossbeck, M.L.

    1992-12-31

    Experiments have shown that Type 316 stainless steel is susceptible to heat-affected-zone (HAZ) cracking upon cooling when welded using the gas tungsten arc (GTA) process under lateral constraint. The cracking has been hypothesized to be caused by stress-assisted helium bubble growth and rupture at grain boundaries. This study utilized an experimental welding setup which enabled different compressive stresses to be applied to the plates during welding. Autogenous GTA welds were produced in Type 316 stainless steel doped with 256 appm helium. The application of a compressive stress, 55 Mpa, during welding suppressed the previously observed catastrophic cracking. Detailed examinations conducted after welding showed a dramatic change in helium bubble morphology. Grain boundary bubble growth along directions parallel to the weld was suppressed. Results suggest that stress-modified welding techniques may be used to suppress or eliminate helium-induced cracking during joining of irradiated materials.

  12. Electrochemical Corrosion Testing of Borated Stainless Steel Alloys

    SciTech Connect (OSTI)

    lister, tedd e; Mizia, Ronald E

    2007-05-01

    The Department of Energy Office of Civilian Radioactive Waste Management has specified borated stainless steel manufactured to the requirements of ASTM A 887-89, Grade A, UNS S30464, to be the material used for the fabrication of the fuel basket internals of the preliminary transportation, aging, and disposal canister system preliminary design. The long-term corrosion resistance performance of this class of borated materials must be verified when exposed to expected YMP repository conditions after a waste package breach. Electrochemical corrosion tests were performed on crevice corrosion coupons of Type 304 B4 and Type 304 B5 borated stainless steels exposed to single postulated in-package chemistry at 60C. The results show low corrosion rates for the test period

  13. Guidelines for Stretch Flanging Advanced High Strength Steels

    SciTech Connect (OSTI)

    Sriram, S.; Chintamani, J.

    2005-08-05

    Advanced High Strength Steels (AHSS) are currently being considered for use in closure and structural panels in the automotive industry because of their high potential for affordable weight reduction and improved performance. AHSS such as dual phase steels are currently being used in some vehicle platforms. From a manufacturing perspective, stretch flanging during stamping is an important deformation mode requiring careful consideration of geometry and the die process. This paper presents some geometric and process guidelines for stretch flanging AHSS. Hole expansion experiments were conducted to determine the failure limit for a sheared edge condition. Effects of punching clearance, prestrain and prior strain path on hole expansion were explored in these experiments. In addition, dynamic explicit FE calculations using LS-DYNA were also conducted for a typical stretch flange by varying some key geometric parameters. The experimental and FEA results were then analyzed to yield process and geometric guidelines to enable successful stretch flanging of AHSS.

  14. Investigation of Laser Peening Effects on Hydrogen Charged Stainless Steels

    SciTech Connect (OSTI)

    Zaleski, T M

    2008-10-23

    Hydrogen-rich environments such as fuel cell reactors can exhibit damage caused by hydrogen permeation in the form of corrosion cracking by lowering tensile strength and decreasing material ductility. Coatings and liners have been investigated, but there were few shot-peening or laser peening studies referenced in the literature with respect to preventing hydrogen embrittlement. The surface compressive residual stress induced by laser peening had shown success in preventing stress corrosion cracking (SCC) for stainless steels in power plants. The question arose if the residual stresses induced by laser peening could delay the effects of hydrogen in a material. This study investigated the effect of laser peening on hydrogen penetration into metal alloys. Three areas were studied: laser peening, hydrogenation, and hydrogen detection. This study demonstrated that laser peening does not reduce the hydrogen permeation into a stainless steel surface nor does it prevent hydrogen embrittlement. The effect of laser peening to reduce hydrogen-assisted fatigue was unclear.

  15. Brooklyn Union develops tool for replacing steel, cast iron mains

    SciTech Connect (OSTI)

    Marazzo, J.J. )

    1994-12-01

    Over the last 10 years, Brooklyn Union Gas Co. has undergone significant changes in the methods it has used to install gas service and gas main systems. Recently, Brooklyn Union engineers developed a user friendly method of replacing steel and cast iron gas mains and service lines with same size or larger polyethylene pipe without using conventional trench excavation. The system, known as the ''Bullet'' pipe replacement system, involves splitting steel and cast iron pipe using a series of rolling cutter wheels. After consecutive cutting wheels completely penetrate both pipe and fittings, both pipe and soil are spread with an expander and new polyethylene pipe is inserted. The ''Bullet'' pipe splitting system for 1[1/4] in. (32 mm) through 6 in. (150 mm) diameter has been developed.

  16. Aluminium Electroplating on Steel from a Fused Bromide Electrolyte

    SciTech Connect (OSTI)

    Prabhat Tripathy; Laura Wurth; Eric Dufek; Toni Y. Gutknecht; Natalie Gese; Paula Hahn; Steven Frank; Guy Fredrickson; J Stephen Herring

    2014-08-01

    A quaternary bromide bath (LiBr-KBr-CsBr-AlBr3) was used to electro-coat aluminium on steel substrates. The electrolyte was prepared by the addition of AlBr3 into the eutectic LiBr-KBr-CsBr melt. A smooth, thick, adherent and shiny aluminium coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminium coverage. Both salt immersion and open circuit potential measurement suggest that the coatings did display good corrosion-resistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminium coating in preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminium coating on both ferrous and non-ferrous metals, including complex surfaces/geometries.

  17. Secondary hardening steel having improved combination of hardness and toughness

    DOE Patents [OSTI]

    Parker, Earl R.; Zackay, Victor F.; Bhat, Manjeshwar S.; Garrison, Jr., Warren M.

    1979-01-01

    A secondary hardening alloy steel composition consisting essentially of about 0.25-0.5% carbon, about 0.5-1.0% manganese, about 1.5-3.0% nickel, about 0-1.0% chromium, about 1.75-2.5% molybdenum, about 0-0.4% vanadium, and an additive selected from about 1-3% aluminum and a combination of at least about 1% aluminum and at least about 1% silicon for a combined Al+Si content of about 2-4%, the balance being iron and impurity elements. The present steel composition has the following characteristics: it exhibits a flat tempering response, it is hardenable upon tempering to a Rockwell C hardness of at least 50, and it has an improved combination of hardness vs. toughness properties after tempering in the secondary hardening range. A method of preparation is also described.

  18. Aluminum electroplating on steel from a fused bromide electrolyte

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Laura A. Wurth; Eric J. Dufek; Toni Y. Gutknecht; Natalie J. Gese; Paula Hahn; Steven M. Frank; Guy L. Frederickson; J. Stephen Herring

    2014-08-01

    A quaternary bromide bath (LiBrKBrCsBrAlBr3) was used to electro-coat aluminum on steel substrates. The electrolytewas prepared by the addition of AlBr3 into the eutectic LiBrKBrCsBr melt. A smooth, thick, adherent and shiny aluminum coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminum coverage. Both salt immersion and open circuit potential measurement suggested that the coatings did display a good corrosionresistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminum coating in preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminumcoating on both ferrous and non-ferrous metals, including complex surfaces/geometries.

  19. Pulsed Magnetic Welding for Advanced Core and Cladding Steel

    SciTech Connect (OSTI)

    Cao, Guoping; Yang, Yong

    2013-12-19

    To investigate a solid-state joining method, pulsed magnetic welding (PMW), for welding the advanced core and cladding steels to be used in Generation IV systems, with a specific application for fuel pin end-plug welding. As another alternative solid state welding technique, pulsed magnetic welding (PMW) has not been extensively explored on the advanced steels. The resultant weld can be free from microstructure defects (pores, non-matallic inclusions, segregation of alloying elements). More specifically, the following objectives are to be achieved, 1) To design a suitable welding apparatus fixture, and optimize welding parameters for repeatable and acceptable joining of the fuel pin end-plug. The welding will be evaluated using tensile tests for lap joint weldments and helium leak tests for the fuel pin end-plug. 2) investigate the microstructural and mechanical properties changes in PMW weldments of proposed advanced core and cladding alloys. 3) Simulate the irradiation effects on the PWM weldments using ion irradiation.

  20. STAINLESS STEEL INTERACTIONS WITH SALT CONTAINING PLUTONIUM OXIDES

    SciTech Connect (OSTI)

    Nelson, Z.; Chandler, G.; Dunn, K.; Stefek, T.; Summer, M.

    2010-02-01

    Salt containing plutonium oxide materials are treated, packaged and stored within nested, stainless steel containers based on requirements established in the DOE 3013 Standard. The moisture limit for the stored materials is less than 0.5 weight %. Surveillance activities which are conducted to assess the condition of the containers and assure continuing 3013 container integrity include the destructive examination of a select number of containers to determine whether corrosion attack has occurred as a result of stainless steel interactions with salt containing plutonium oxides. To date, some corrosion has been observed on the innermost containers, however, no corrosion has been noted on the outer containers and the integrity of the 3013 container systems is not expected to be compromised over a 50 year storage lifetime.

  1. Sensitization and IGSCC susceptibility prediction in stainless steel pipe weldments

    SciTech Connect (OSTI)

    Atteridge, D.G.; Simmons, J.W.; Li, Ming ); Bruemmer, S.M. )

    1991-11-01

    An analytical model, based on prediction of chromium depletion, has been developed for predicting thermomechanical effects on austenitic stainless steel intergranular stress corrosion cracking (IGSCC) susceptibility. Model development and validation is based on sensitization development analysis of over 30 Type 316 and 304 stainless steel heats. The data base included analysis of deformation effects on resultant sensitization development. Continuous Cooling sensitization behavior is examined and modelled with and without strain. Gas tungsten are (GTA) girth pipe weldments are also characterized by experimental measurements of heat affected zone (HAZ) temperatures, strains and sensitization during/after each pass; pass by pass thermal histories are also predicted. The model is then used to assess pipe chemistry changes on IGSCC resistance.

  2. Preliminary Economics for the Production of Pyrolysis Oil from Lignin in a Cellulosic Ethanol Biorefinery

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua

    2009-04-01

    Cellulosic ethanol biorefinery economics can be potentially improved by converting by-product lignin into high valued products. Cellulosic biomass is composed mainly of cellulose, hemicellulose and lignin. In a cellulosic ethanol biorefinery, cellulose and hemicellullose are converted to ethanol via fermentation. The raw lignin portion is the partially dewatered stream that is separated from the product ethanol and contains lignin, unconverted feed and other by-products. It can be burned as fuel for the plant or can be diverted into higher-value products. One such higher-valued product is pyrolysis oil, a fuel that can be further upgraded into motor gasoline fuels. While pyrolysis of pure lignin is not a good source of pyrolysis liquids, raw lignin containing unconverted feed and by-products may have potential as a feedstock. This report considers only the production of the pyrolysis oil and does not estimate the cost of upgrading that oil into synthetic crude oil or finished gasoline and diesel. A techno-economic analysis for the production of pyrolysis oil from raw lignin was conducted. comparing two cellulosic ethanol fermentation based biorefineries. The base case is the NREL 2002 cellulosic ethanol design report case where 2000 MTPD of corn stover is fermented to ethanol (NREL 2002). In the base case, lignin is separated from the ethanol product, dewatered, and burned to produce steam and power. The alternate case considered in this report dries the lignin, and then uses fast pyrolysis to generate a bio-oil product. Steam and power are generated in this alternate case by burning some of the corn stover feed, rather than fermenting it. This reduces the annual ethanol production rate from 69 to 54 million gallons/year. Assuming a pyrolysis oil value similar to Btu-adjusted residual oil, the estimated ethanol selling price ranges from $1.40 to $1.48 (2007 $) depending upon the yield of pyrolysis oil. This is considerably above the target minimum ethanol selling

  3. Alumina-Forming Austenitics: A New Approach to Thermal and Degradation Resistant Stainless Steels for Industrial Use

    SciTech Connect (OSTI)

    David A Helmick; John H Magee; Michael P Brady

    2012-05-31

    A series of developmental AFA alloys was selected for study based on: 25 Ni wt.% (alloys A-F), 20 wt% Ni (alloys G-H), and 12 Ni wt.% (alloys I-L). An emphasis in this work was placed on the lower alloy content direction for AFA alloys to reduce alloy raw material cost, rather than more highly alloyed and costly AFA alloys for higher temperature performance. Alloys A-D explored the effects of Al (3-4 wt.%) and C (0.05-0.2 wt.%) in the Fe-25Ni-14Cr-2Mn-2Mo-1W-1Nb wt.% base range; alloys E and F explored the effects of removing costly Mo and W additions in a Fe-25Ni-14Cr-4Al-2.5Nb-2Mn-0.2C base, alloys G and H examined Nb (1-2.5wt.%) and removal of Mo, W in a Fe-20Ni-14Cr-3Al-2Mn-0.2 C wt.% base; and alloys I-L examined effects of C (0.1-0.2 wt.%) and Mn (5-10 wt.%) on a low cost Fe-14Cr-12Ni-3Cu-2.5Al wt.% base (no Mo, W additions). Creep testing resulted in elemental trends that included the beneficial effect of higher carbon and lower niobium in 20-25%Ni AFA alloys and, the beneficial of lower Mn in 12%Ni AFA alloys. Corrosion tests in steam and sulfidation-oxidation environments showed, in general, these alloys were capable of a ten-fold improvement in performance when compared to conventional austenitic stainless steels. Also, corrosion test results in metal-dusting environments were promising and, warrant further investigation.

  4. Manganese-stabilized austenitic stainless steels for fusion applications

    DOE Patents [OSTI]

    Klueh, Ronald L.; Maziasz, Philip J.

    1990-08-07

    An austenitic stainless steel that is comprised of Fe, Cr, Mn, C but no Ni or Nb and minimum N. To enhance strength and fabricability minor alloying additions of Ti, W, V, B and P are made. The resulting alloy is one that can be used in fusion reactor environments because the half-lives of the elements are sufficiently short to allow for handling and disposal.

  5. Sulfide stress cracking resistance of nitrogen-strengthened stainless steel

    SciTech Connect (OSTI)

    Gaugh, R.R.

    1981-01-01

    The paper describes sulfide stress cracking tests performed on a number of these alloys. Most were found to be somewhat susceptible to cracking, depending on the stress level. It was determined that this was due to their high manganese content. The mechanism responsible for cracking was not firmly established. One commercial nitrogen-strengthened stainless steel, XM19, was highly resistant to sulfide stress cracking despite a manganese content of 5%. This difference is attributed to the superior corrosion resistance of the alloy.

  6. Highly alloyed stainless steels for sea water applications

    SciTech Connect (OSTI)

    Audouard, J.P.; Verneau, M.

    1996-10-01

    Natural sea water is known as a very aggressive environment which generates pitting and crevice corrosion on stainless steels. High chromium grades with sufficient molybdenum and nitrogen additions (PREN > 40) are generally recognized as resistant materials in natural sea water bu the material selection criteria must be improved to take into account the effect of climatic conditions and of biocide treatments which are widely used as anti-fouling agents in sea water circuits. The paper deals with the localized corrosion properties of conventional stainless steels (SS), duplex and superaustenitic alloys. The results of laboratory investigations conducted in more or less oxidizing chloride containing media are discussed. Then, immersion tests carried out in natural sea waters in different climatic conditions are presented and discussed. Finally, the effect of biocide addition on fouling and its consequences on corrosion is investigated. The results are interpreted taking into account the chemical composition of the stainless steels and biofilm criteria. The results showed the Mediterranean Sea to be slightly more aggressive than other European seas but a PREN value higher than 40 is sufficient for stainless steels to withstand localized corrosion in European natural sea waters. A residual chlorine level around 0.3--0.4 ppm was found to be very effective to limit the fouling and to avoid localized corrosion on SS. Nevertheless, due to difficulties in monitoring chlorine addition, PREN values higher than 50 are recommended to withstand localized corrosion in treated sea waters. As an example, the new super-austenitic grade 25Cr-22Ni-5.8Mo-1.5Cu-2W-0.45N with a PRENW value of 54 was found to be perfectly resistant to crevice corrosion with 0.5 ppm free chlorine at ambient temperature.

  7. Versatility of superaustenitic stainless steels in marine applications

    SciTech Connect (OSTI)

    Latha, G.; Rajeswari, S.

    1996-10-01

    Corrosion of construction materials in marine applications is a major problem. The frequent variations in chloride ion concentration and temperature experienced by a system pose a serious threat. This investigation evaluated the performance of superaustenitic stainless steels in marine applications by potentiodynamic anodic polarization studies. The concentrations of metal ions such as iron, chromium, and nickel at different impressed potentials were analyzed by inductively coupled plasma spectrometry, which revealed little tendency for leaching of metal ions.

  8. Manganese-stabilized austenitic stainless steels for fusion applications

    DOE Patents [OSTI]

    Klueh, Ronald L.; Maziasz, Philip J.

    1990-01-01

    An austenitic stainless steel that is comprised of Fe, Cr, Mn, C but no Ni or Nb and minimum N. To enhance strength and fabricability minor alloying additions of Ti, W, V, B and P are made. The resulting alloy is one that can be used in fusion reactor environments because the half-lives of the elements are sufficiently short to allow for handling and disposal.

  9. Corrosion Testing of Stainless Steel Fuel Cell Hardware

    SciTech Connect (OSTI)

    Wilson, M.S.; Zawodzinski, C.; Gottesfeld, S.

    1998-11-01

    Metal hardware is gaining increasing interest in polymer electrolyte fuel cell (PEFC) development as a possible alternative to machined graphite hardware because of its potential for low-cost manufacturing combined with its intrinsic high conductivity, minimal permeability and advantageous mechanical properties. A major barrier to more widespread use of metal hardware has been the susceptibility of various metals to corrosion. Few pure metals can withstand the relatively aggressive environment of a fuel cell and thus the choices for hardware are quite limited. Precious metals such as platinum or gold are prohibitively expensive and so tend to be utilized as coatings on inexpensive substrates such as aluminum or stainless steel. The main challenge with coatings has been to achieve pin-hole free surfaces that will remain so after years of use. Titanium has been used to some extent and though it is very corrosion-resistant, it is also relatively expensive and often still requires some manner of surface coating to prevent the formation of a poorly conducting oxide layer. In contrast, metal alloys may hold promise as potentially low-cost, corrosion-resistant materials for bipolar plates. The dozens of commercially available stainless steel and nickel based alloys have been specifically formulated to offer a particular advantage depending upon their application. In the case of austenitic stainless steels, for example, 316 SS contains molybdenum and a higher chromium content than its more common counterpart, 304 SS, that makes it more noble and increases its corrosion resistance. Likewise, 316L SS contains less carbon than 316 SS to make it easier to weld. A number of promising corrosion-resistant, highly noble alloys such as Hastelloy{trademark} or Duplex{trademark} (a stainless steel developed for seawater service) are available commercially, but are expensive and difficult to obtain in various forms (i.e. wire screen, foil, etc.) or in small amounts for R and D

  10. Sodium sulfide slagging for removing copper from scrap steel

    SciTech Connect (OSTI)

    Leis, J.R.; Sanghvi, S.M.; Steinberg, R.M.

    1982-10-01

    Fundamental studies of sodium sulfide slagging for removing copper from scrap steel indicate that the copper distribution coefficient is 10, and that if 30 wt % FeS exists in the slag phase, no iron will be transferred to the slag from the metal phase. This process can be used commercially as an added fluxing step with minimal modifications to current electric-furnace steelmaking operations. Preliminary economic analysis shows an incremental return on investment equal to 100% per year.

  11. Attack polish for nickel-base alloys and stainless steels

    DOE Patents [OSTI]

    Steeves, Arthur F.; Buono, Donald P.

    1983-01-01

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels. The chemical attack polish comprises Fe(NO.sub.3).sub.3, concentrated CH.sub.3 COOH, concentrated H.sub.2 SO.sub.4 and H.sub.2 O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  12. Attack polish for nickel-base alloys and stainless steels

    DOE Patents [OSTI]

    Not Available

    1980-05-28

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels is described. The chemical attack polich comprises FeNO/sub 3/, concentrated CH/sub 3/COOH, concentrated H/sub 2/SO/sub 4/ and H/sub 2/O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  13. Hydrogen trapping, diffusion, and recombination in austenitic stainless steels

    SciTech Connect (OSTI)

    Langley, R.A.

    1984-01-01

    Trapping, diffusion, and recombination of hydrogen in austenitic stainless steels are reviewed. It is suggested that since all of these processes are strongly interdependent and since the measured recombination rates are found to vary four orders of magnitude at any temperature, the data analysis techniques used to date are insufficient. A two-region diffusion model with surface recombination is proposed in which the surface layer is characterized by a smaller diffusion coefficient than the bulk.

  14. Acoustic emission monitoring for assessment of steel bridge details

    SciTech Connect (OSTI)

    Kosnik, D. E.; Corr, D. J.; Hopwood, T.

    2011-06-23

    Acoustic emission (AE) testing was deployed on details of two large steel Interstate Highway bridges: one cantilever through-truss and one trapezoidal box girder bridge. Quantitative measurements of activity levels at known and suspected crack locations were made by monitoring AE under normal service loads (e.g., live traffic and wind). AE indications were used to direct application of radiography, resulting in identification of a previously unknown flaw, and to inform selection of a retrofit detail.

  15. Monolithic torpedo bottle lining at Weirton Steel Corporation

    SciTech Connect (OSTI)

    Baker, R.; Griffith, E.

    1996-12-31

    In late 1992 and early 1993 Weirton Steel burned through three torpedo bottles in a three-month period. To determine the cause of the burn throughs, a thorough review of bottle maintenance practices was initiated. Upon identification of contributing factors, changes in operating practices were made. In an effort to increase bottle reliability, lining trials were initiated. Among the trials, a monolithic lining was installed and this paper will discuss results of the lining to date.

  16. Evaluation of steel furnace slags as cement additives

    SciTech Connect (OSTI)

    Tuefekci, M.; Demirbas, A.; Genc, H.

    1997-11-01

    Chemical and physical properties and strength development have been studied for six granulated steel furnace slags from the normal steelmaking process. This paper reports results of research performed to develop cement mixture proportions using these slags. The influence of slag proportions, specific surface, and water demand on compressive strength and bulk density of cement blends are presented in this paper. The different test results, which were compared with the Turkish Standards, in general, were found to be within the limits.

  17. Method of polishing nickel-base alloys and stainless steels

    DOE Patents [OSTI]

    Steeves, Arthur F.; Buono, Donald P.

    1981-01-01

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels. The chemical attack polish comprises Fe(NO.sub.3).sub.3, concentrated CH.sub.3 COOH, concentrated H.sub.2 SO.sub.4 and H.sub.2 O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  18. Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Embrittlement of Pipeline Steels: Causes and Remediation P. Sofronis, I. M. Robertson, D. D. Johnson University of Illinois at Urbana-Champaign Hydrogen Pipeline Working Group Workshop Augusta, GA, August 30, 2005 Funding and Duration * Timeline - Project start date: 7/20/05 - Project end date: 7/19/09 - Percent complete: 0.1% * Budget: Total project funding: 300k/yr * DOE share: 75% * Contractor share: 25% * Barriers - Hydrogen embrittlement of pipelines and remediation (mixing with water

  19. The retention of iodine in stainless steel sample lines

    SciTech Connect (OSTI)

    Evans, G.J.; Deir, C.; Ball, J.M.

    1995-02-01

    Following an accident in a multi-unit CANDU nuclear generating station, decontamination of air vented from containment would play a critical role in minimizing the release of iodine to the environment. The concentration of gas phase iodine in containment air would be measured using the post accident radiation monitoring system, requiring that air samples be passed through a considerable length of tubing to a remote location where the desired measurements could safely be made. A significant loss of iodine, due to adsorption on the sample line surfaces, could greatly distort the measurement. In this study, the retention of I{sub 2}(g) on stainless steel was evaluated in bench scale experiments in order to evaluate, and if possible minimise, the extent of any such line losses. Experiments at the University of Toronto were performed using 6 inch lengths of 1/4 inch stainless steel tubing. Air, containing I-131 labelled I{sub 2}(g), ranging in concentration from 10{sup {minus}10} to 10{sup {minus}6} mol/dm{sup 3} and relative humidity (:RH) from 20 to 90 %, was passed through tubing samples maintained at temperatures ranging from 25 to 90{degrees}C. Adsorption at low gas phase iodine concentrations differed substantially from that at higher concentrations. The rate of deposition was proportional to the gas phase concentration, giving support to the concept of a first order deposition velocity. The surface loading increased with increasing relative humidity, particularly at low RH values, while the deposition rate decreased with increasing temperature. Surface water on the steel may play an important role in the deposition process. The chemisorbed iodine was located primarily in areas of corrosion. Furthermore, water used to wash the steel contained Fe, Mn and iodine in the form of iodide, suggesting that I{sub 2} reacted to form metal iodides. The deposition of I{sub 2} was also found to depend on the initial surface condition.

  20. Forest Products

    Broader source: Energy.gov [DOE]

    Purchased energy remains the third largest manufacturing cost for the forest products industry–despite its extensive use of highly efficient co-generation technology. The industry has worked with...

  1. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  2. Joining of zirconia ceramic to stainless steel and to itself using Ag{sub 57}Cu{sub 38}Ti{sub 5} filler metal

    SciTech Connect (OSTI)

    Hao, H.; Wang, Y.; Jin, Z.; Wang, X.

    1995-08-01

    The brazing of ZrO{sub 2} ceramic to 1Cr18Ni9Ti stainless steel and to itself was performed using Ag{sub 57}Cu{sub 38}Ti{sub 5} filler metal under a vacuum of t {times} 10{sup {minus}3} Pa. The effects o9f interlayer copper on the ceramic to stainless steel joint strength, and the brazing temperature (1,073 to 1,323 K) and holding time (0 to 60 min) on ceramic to ceramic joint strength were investigated. The joint strength was evaluated by shear testing. An interfacial reaction layer between the ceramic and the filler metal was found, and the reaction products were {delta}-TiO and {gamma}-AgTi{sub 3}. The joint strength of ZrO{sub 2} ceramic to stainless steel was improved by using a layer of copper of a suitable thickness. The brazing temperature and holding time had a strong influence on the joint strength of ceramic time had a strong influence on the joint strength of ceramic to ceramic, and the joint strength was mainly controlled by reaction layer thickness and the properties of the reaction products. The maximum shear strength was obtained for brazing at 1,123 K for 30 min and an interfacial reaction layer thickness of {approximately}4.4 {micro}m.

  3. Development of a thin steel strip casting process. Final report

    SciTech Connect (OSTI)

    Williams, R.S.

    1994-04-01

    This is a comprehensive effort to develop direct strip casting to the point where a pilot scale program for casting carbon steel strip could be initiated. All important aspects of the technology were being investigated, however the program was terminated early due to a change in the business strategy of the primary contractor, Armco Inc. (focus to be directed at specialty steels, not low carbon steel). At termination, the project was on target on all milestones and under budget. Major part was casting of strip at the experiment casting facility. A new caster, capable of producing direct cast strip of up to 12 in. wide in heats of 1000 and 3000 lb, was used. A total of 81 1000-1200 lb heats were cast as well as one test heat of 3000 lb. Most produced strip of from 0.016 to 0.085 in. thick. Process reliability was excellent for short casting times; quality was generally poor from modern hot strip mill standards, but the practices necessary for good surface quality were identified.

  4. Welding techniques for high alloy austenitic stainless steel

    SciTech Connect (OSTI)

    Gooch, T.G.; Woollin, P.

    1996-11-01

    Factors controlling corrosion resistance of weldments in high alloy austenitic stainless steel are described, with emphasis on microsegregation, intermetallic phase precipitation and nitrogen loss from the molten pool. The application is considered of a range of welding processes, both fusion and solid state. Autogenous fusion weldments have corrosion resistance below that of the parent, but low arc energy, high travel speed and use of N{sub 2}-bearing shielding gas are recommended for best properties. Conventional fusion welding practice is to use an overalloyed nickel-base filler metal to avoid preferential weld metal corrosion, and attention is given to the effects of consumable composition and level of weldpool dilution by base steel. With non-matching consumables, overall joint corrosion resistance may be limited by the presence of a fusion boundary unmixed zone: better performance may be obtained using solid state friction welding, given appropriate component geometry. Overall, the effects of welding on superaustenitic steels are understood, and the materials have given excellent service in welded fabrications. The paper summarizes recommendations on preferred welding procedure.

  5. Laser beam surface melting of high alloy austenitic stainless steel

    SciTech Connect (OSTI)

    Woollin, P.

    1996-12-31

    The welding of high alloy austenitic stainless steels is generally accompanied by a substantial reduction in pitting corrosion resistance relative to the parent, due to microsegregation of Mo and Cr. This prevents the exploitation of the full potential of these steels. Processing to achieve remelting and rapid solidification offers a means of reducing microsegregation levels and improving corrosion resistance. Surface melting of parent UNS S31254 steel by laser beam has been demonstrated as a successful means of producing fine, as-solidified structures with pitting resistance similar to that of the parent, provided that an appropriate minimum beam travel speed is exceeded. The use of N{sub 2} laser trail gas increased the pitting resistance of the surface melted layer. Application of the technique to gas tungsten arc (GTA) melt runs has shown the ability to raise the pitting resistance significantly. Indeed, the use of optimized beam conditions, N{sub 2} trail gas and appropriate surface preparation prior to laser treatment increased the pitting resistance of GTA melt runs to a level approaching that of the parent material.

  6. Waste streams that preferentially corrode 55-gallon steel storage drums

    SciTech Connect (OSTI)

    Zirker, L.R.; Beitel, G.A.; Reece, C.M.

    1995-06-01

    When 55-gal steel drum waste containers fail in service, i.e., leak, corrode or breach, the standard fix has been to overpack the drum. When a drum fails and is overpacked into an 83-gal overpack drum, there are several negative consequences. Identifying waste streams that preferentially corrode steel drums is essential to the pollution prevention philosophy that ``an ounce of prevention is worth a pound of cure.`` It is essential that facilities perform pollution prevention measures at the front end of processes to reduce pollution on the back end. If these waste streams can be identified before they are packaged, the initial drum packaging system could be fortified or increased to eliminate future drum failures, breaches, clean-ups, and the plethora of other consequences. Therefore, a survey was conducted throughout the US Department of Energy complex for information concerning waste streams that have demonstrated preferential corrosion of 55-gal steel drums. From 21 site contacts, 21 waste streams were so identified. The major components of these waste streams include acids, salts, and solvent liquids, sludges, and still bottoms. The solvent-based waste streams typically had the shortest time to failure, 0.5 to 2 years. This report provides the results of this survey and research.

  7. TENSILE TESTING OF CARBON STEEL IN HIGH PRESSURE HYDROGEN

    SciTech Connect (OSTI)

    Duncan, A; Thad Adams, T; Ps Lam, P

    2007-05-02

    An infrastructure of new and existing pipelines and systems will be required to carry and to deliver hydrogen as an alternative energy source under the hydrogen economy. Carbon and low alloy steels of moderate strength are currently used in hydrogen delivery systems as well as in the existing natural gas systems. It is critical to understand the material response of these standard pipeline materials when they are subjected to pressurized hydrogen environments. The methods and results from a testing program to quantify hydrogen effects on mechanical properties of carbon steel pipeline and pipeline weld materials are provided. Tensile properties of one type of steel (A106 Grade B) in base metal, welded and heat affected zone conditions were tested at room temperature in air and high pressure (10.34 MPa or 1500 psig) hydrogen. A general reduction in the materials ability to plastically deform was noted in this material when specimens were tested in hydrogen. Furthermore, the primary mode of fracture was changed from ductile rupture in air to cleavage with secondary tearing in hydrogen. The mechanical test results will be applied in future analyses to evaluate service life of the pipelines. The results are also envisioned to be part of the bases for construction codes and structural integrity demonstrations for hydrogen service pipeline and vessels.

  8. MECHANICAL TESTING OF CARBON STEEL IN HIGH PRESSURE HYDROGEN

    SciTech Connect (OSTI)

    Duncan, A

    2006-05-11

    The methods and interim results from a testing program to quantify hydrogen effects on mechanical properties of carbon steel pipeline and pipeline weld materials are provided. The scope is carbon steels commonly used for natural gas pipelines in the United States that are candidates for hydrogen service in the hydrogen economy. The mechanical test results will be applied in future analyses to evaluate service life of the pipelines. The results are also envisioned to be part of the bases for construction codes and structural integrity demonstrations for hydrogen service pipeline and vessels. Tensile properties of one type of steel (A106 Grade B) in base metal, welded and heat affected zone conditions were tested at room temperature in air and high pressure (1500 psig) hydrogen. A general reduction in the materials ability to plastically deform was noted in this material when specimens were tested in 1500 psig hydrogen. Furthermore, the primary mode of fracture was changed from ductile rupture in air to cleavage with secondary tearing in hydrogen. The mechanical test program will continue with tests to quantify the fracture behavior in terms of J-R curves for these materials at air and hydrogen pressure conditions.

  9. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    SciTech Connect (OSTI)

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2015-11-12

    We used cast stainless steels (CASSs)for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr-rich alpha-phase by Spinodal decomposition of delta-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR-relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. Moreover, an approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, an equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program, and the results are used to describe the precipitation behaviors in duplex stainless steels. Our results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  10. Kinetics of steel slag leaching: Batch tests and modeling

    SciTech Connect (OSTI)

    De Windt, Laurent; Chaurand, Perrine; Rose, Jerome

    2011-02-15

    Reusing steel slag as an aggregate for road construction requires to characterize the leaching kinetics and metal releases. In this study, basic oxygen furnace (BOF) steel slag were subjected to batch leaching tests at liquid to solid ratios (L/S) of 10 and 100 over 30 days; the leachate chemistry being regularly sampled in time. A geochemical model of the steel slag is developed and validated from experimental data, particularly the evolution with leaching of mineralogical composition of the slag and trace element speciation. Kinetics is necessary for modeling the primary phase leaching, whereas a simple thermodynamic equilibrium approach can be used for secondary phase precipitation. The proposed model simulates the kinetically-controlled dissolution (hydrolysis) of primary phases, the precipitation of secondary phases (C-S-H, hydroxide and spinel), the pH and redox conditions, and the progressive release of major elements as well as the metals Cr and V. Modeling indicates that the dilution effect of the L/S ratio is often coupled to solubility-controlled processes, which are sensitive to both the pH and the redox potential. A sensitivity analysis of kinetic uncertainties on the modeling of element releases is performed.

  11. Processing and mechanical behavior of hypereutectoid steel wires

    SciTech Connect (OSTI)

    Lesuer, D.R.; Syn, C.K.; Sherby, O.D.; Kim, D.K.

    1996-06-25

    Hypereutectoid steels have the potential for dramatically increasing the strength of wire used in tire cord and in other high strength wire applications. The basis for this possible breakthrough is the elimination of a brittle proeutectoid network that can form along grain boundaries if appropriate processing procedures and alloy additions are used. A review is made of work done by Japanese and other researchers on eutectoid and mildly hypereutectoid wires. A linear extrapolation of the tensile strength of fine wires predicts higher strengths at higher carbon contents. The influence of processing, alloy additions and carbon content in optimizing the strength, ductility and fracture behavior of hypereutectoid steels is presented. It is proposed that the tensile strength of pearlitic wires is dictated by the fracture strength of the carbide lamella at grain boundary locations in the carbide. Methods to improve the strength of carbide grain boundaries and to decrease the carbide plate thickness will contribute to enhancing the ultrahigh strength obtainable in hypereutectoid steel wires. 23 refs., 13 figs., 1 tab.

  12. Impact Testing of Stainless Steel Material at Cold Temperatures

    SciTech Connect (OSTI)

    Spencer D. Snow; D. Keith Morton; Robert K. Blandford

    2008-07-01

    Stainless steels are used for the construction of numerous spent nuclear fuel or radioactive material containers that may be subjected to high strains and moderate strain rates during accidental drop events. Mechanical characteristics of these base materials and their welds under dynamic loads in the strain rate range of concern are not well documented. However, a previous paper [1] reported on impact testing and analysis results performed at the Idaho National Laboratory using 304/304L and 316/316L stainless steel base material specimens at room and elevated temperatures. The goal of the work presented herein is to add recently completed impact tensile testing results at -20 degrees F conditions for dual-marked 304/304L and 316/316L stainless steel material specimens (hereafter referred to as 304L and 316L, respectively). Recently completed welded material impact testing at -20 degrees F, room, 300 degrees F, and 600 degrees F is also reported. Utilizing a drop-weight impact test machine and 1/4-inch to 1/2-inch thick dog-bone shaped test specimens, the impact tests achieved strain rates in the 4 to 40 per second range, depending upon the material temperature. Elevated true stress-strain curves for these materials reflecting varying strain rates and temperatures are presented herein.

  13. Radiation effects in the stainless steel primary coolant supply adapter

    SciTech Connect (OSTI)

    Farrell, K.

    1995-09-01

    The primary coolant supply adapter (PCSA) is a flanged, cylindrical collar of 316NG stainless steel that is part of the primary pressure boundary of the Advanced Neutron Source. The radiation fluxes on the PCSA are dominated by thermal neutrons. During its intended 40-year service life, the PCSA will receive a thermal neutron fluence of 1.8 {times} 10{sup 26} m{sup {minus}2} in its upper sections at a temperature of <1OO{degree}C. The PCSA will suffer radiation damage, caused primarily by the interaction of thermal neutrons with the 14% nickel in the steel, which will generate helium by the sequential reactions {sup 58}Ni (n,y){sup 59}Ni (n,{alpha}){sup 56}Fe and will concurrently produce significant atomic displacements per atom (dpa) from the {sup 59}Ni (n,{alpha}){sup 56}Fe recoils. It is estimated that the helium concentration and total atomic displacements in the upper parts of the PCSA will be about 430 atomic parts per million and 1 dpa, respectively. From newly compiled trend curves of tensile properties and fracture toughness data versus atomic displacements for 316 steel, it is deduced that the irradiated PCSA will retain at least 20% uniform tensile elongation and a fracture toughness of more than 200 Mpa{radical}m, which are judged adequate to resist brittle failure. Tberefore, employment of a neutron shield around the PCSA is unnecessary.

  14. Electrochemical and microelectrode studies of stainless steel ennoblement

    SciTech Connect (OSTI)

    Dickinson, W.; Lewandowski, Z.

    1995-12-01

    Ennobled open-circuit potential (E{sub corr}) for stainless steel exposed to fresh river water is investigated using microelectrodes to measure dissolved oxygen, hydrogen peroxide, and local E{sub corr} within the biofilm. Results indicate the biofilm is uniformly aerobic and does not contain elevated levels of cathodic depolarizers. Development of ennobled potential is observed to correlate with E{sub corr} near beginning of exposure and occurs on surfaces exhibiting as little as 20% biofilm coverage. Galvanostatic measurements of coupon capacitance reveal a strong correlation between capacitance and E{sub corr} as the latter increases during microbial colonization. Cathodic reduction measurements indicate that an increase in surface Fe{sub 2}O{sub 3} content occurs for stainless steel samples that develop ennobled potential. Results suggest an ennoblement mechanism involving modifications of the metal-oxide surface. A new interpretation of cathodic polarization behavior for ennobled stainless steel is given based on proposed changes in cathodic reaction rates that occur on the microbially modified oxide surface during polarization.

  15. POLYETHERSULFONE COATING FOR MITIGATING CORROSION OF STEEL IN GEOTHERMAL ENVIRONMENT.

    SciTech Connect (OSTI)

    SUGAMA, T.

    2005-06-01

    Emphasis was directed toward evaluating the usefulness of a polyethersulfone (PES)-dissolved N-methyl pyrrolidone (NMP) solvent precursor as a low-temperature film-forming anti-corrosion coating for carbon steel in simulated geothermal environments at brine temperatures up to 300 C. A {approx} 75 {micro}m thick PES coating performed well in protecting the steel against corrosion in brine at 200 C. However, at {>=} 250 C, the PES underwent severe hydrothermal oxidation that caused the cleavage of sulfone- and ether-linkages, and the opening of phenyl rings. These, in turn, led to sulfone {yields} benzosulfonic acid and ether {yields} benzophenol-type oxidation derivative transformations, and the formation of carbonyl-attached open rings, thereby resulting in the incorporation of the functional groups, hydroxyl and carbonyl, into the coating. The presence of these functional groups raised concerns about the diminutions in water-shedding and water-repellent properties that are important properties of the anti-corrosion coatings; such changes were reflected in an enhancement of the magnitude of susceptibility of the coatings surfaces to moisture. Consequently, the disintegration of the PES structure by hydrothermal oxidation was detrimental to the maximum efficacy of the coating in protecting the steel against corrosion, allowing the corrosive electrolytes to infiltrate easily through it.

  16. Interaction of titanium-chromium diboride with carbon steels under glos discharge conditions

    SciTech Connect (OSTI)

    Globa, L.V.; Serebryakova, T.I.; Mukha, I.M.; Kholoptseva, T.V.

    1986-08-01

    This report is a continuation of the cycle of work on studying the conditions and processes of formation of the structures and phase composition in the zones of diffusion interaction of transition metal borides with carbon steels. An attempt was made to establish the rules of occurrence of diffusion processes in the zones of titanium-chromium diboride-carbon steels in a glow discharge. In connection with the significant difficulties in studying the structural and phase transformations in the thin layers of refractory coatings with the matrix the investigation was made of the zones of interaction of compact boride specimens with the corresponding steels, iron, and Armco iron. An analysis of the microstructures and the width of the zones of diffusion interaction of the titanium-chromium boride with the carbons steels and also the relationship of the microhardnesses in the (Ti, Cr) B/sub 2/-steel contact zone to the carbon content in the steel is shown.

  17. Creep resistant, precipitation-dispersion-strengthened, martensitic stainless steel and method thereof

    DOE Patents [OSTI]

    Buck, R.F.

    1994-05-10

    An iron-based, corrosion-resistant, precipitation strengthened, martensitic steel essentially free of delta ferrite for use at high temperatures has a nominal composition of 0.05--0.1 C, 8--12 Cr, 1--5 Co, 0.5--2.0 Ni, 0.41--1.0 Mo, 0.1--0.5 Ti, and the balance iron. This steel is different from other corrosion-resistant martensitic steels because its microstructure consists of a uniform dispersion of fine particles, which are very closely spaced, and which do not coarsen at high temperatures. Thus at high temperatures this steel combines the excellent creep strength of dispersion-strengthened steels, with the ease of fabricability afforded by precipitation hardenable steels. 2 figures.

  18. Creep resistant, precipitation-dispersion-strengthened, martensitic stainless steel and method thereof

    DOE Patents [OSTI]

    Buck, Robert F.

    1994-01-01

    An iron-based, corrosion-resistant, precipitation strengthened, martensitic steel essentially free of delta ferrite for use at high temperatures has a nominal composition of 0.05-0.1 C, 8-12 Cr, 1-5 Co, 0.5-2.0 Ni, 0.41-1.0 Mo, 0.1-0.5 Ti, and the balance iron. This steel is different from other corrosion-resistant martensitic steels because its microstructure consists of a uniform dispersion of fine particles, which are very closely spaced, and which do not coarsen at high temperatures. Thus at high temperatures this steel combines the excellent creep strength of dispersion-strengthened steels, with the ease of fabricability afforded by precipitation hardenable steels.

  19. Production, Energy, and Carbon Emissions: A Data Profile of the Iron and Steel Industry

    Reports and Publications (EIA)

    2000-01-01

    Energy-related carbon emissions in manufacturing analysis and issues related to the energy use, energy efficiency, and carbon emission indicators.

  20. Steelmaker Matches Recovery Act Funds to Save Energy & Reduce Steel Production Costs

    Broader source: Energy.gov [DOE]

    ArcelorMittal Indiana Harbor Energy Recovery & Reuse 504 Boiler constructed and installed with DOE Recovery Act Funding