National Library of Energy BETA

Sample records for rating lubricants substances

  1. Method of measuring the mass flow rate of a substance entering a cocurrent fluid stream

    DOE Patents [OSTI]

    Cochran, Jr., Henry D.

    1978-04-11

    This invention relates to an improved method of monitoring the mass flow rate of a substance entering a cocurrent fluid stream. The method very basically consists of heating equal sections of the fluid stream above and below the point of entry of the substance to be monitored, and measuring and comparing the resulting change in temperature of the sections. Advantage is taken of the difference in thermal characteristics of the fluid and the substance to be measured to correlate temperature differences in the sections above and below the substance feed point for providing an indication of the mass flow rate of the substance.

  2. Process for producing biodiesel, lubricants, and fuel and lubricant additives in a critical fluid medium

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.

    2005-05-03

    A process for producing alkyl esters useful in biofuels and lubricants by transesterifying glyceride- or esterifying free fatty acid-containing substances in a single critical phase medium is disclosed. The critical phase medium provides increased reaction rates, decreases the loss of catalyst or catalyst activity and improves the overall yield of desired product. The process involves the steps of dissolving an input glyceride- or free fatty acid-containing substance with an alcohol or water into a critical fluid medium; reacting the glyceride- or free fatty acid-containing substance with the alcohol or water input over either a solid or liquid acidic or basic catalyst and sequentially separating the products from each other and from the critical fluid medium, which critical fluid medium can then be recycled back in the process. The process significantly reduces the cost of producing additives or alternatives to automotive fuels and lubricants utilizing inexpensive glyceride- or free fatty acid-containing substances, such as animal fats, vegetable oils, rendered fats, and restaurant grease.

  3. Ionic Liquids as Novel Engine Lubricants or Lubricant Additives...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Lubricants or Lubricant Additives Ionic Liquids as Novel Engine Lubricants or Lubricant Additives Bench test results showed that compared with fully-formulated engine oils, ...

  4. Tethered Lubricants

    SciTech Connect (OSTI)

    Archer, Lynden

    2010-09-15

    We have performed extensive experimental and theoretical studies of interfacial friction, relaxation dynamics, and thermodynamics of polymer chains tethered to points, planes, and particles. A key result from our tribology studies using lateral force microscopy (LFM) measurements of polydisperse brushes of linear and branched chains densely grafted to planar substrates is that there are exceedingly low friction coefficients for these systems. Specific project achievements include: (1) Synthesis of three-tiered lubricant films containing controlled amounts of free and pendent PDMS chains, and investigated the effect of their molecular weight and volume fraction on interfacial friction. (2.) Detailed studies of a family of hairy particles termed nanoscale organic hybrid materials (NOHMs) and demonstration of their use as lubricants.

  5. Thin film deposition behavior of lubricants as a function of temperature - Lubricant stability maps

    SciTech Connect (OSTI)

    Klaus, E.E.; Wang, J.C.; Duda, J.L. )

    1992-07-01

    The relative rates of evaporation and oxidative or thermal decomposition in lubricants are investigated experimentally at elevated temperatures. Thin films of lubricant are exposed to air at high temperatures, and attention is given to the amount of solid deposit rendered and the amount of evaporated material. The effects of volatility, oxidative stability, and thermal stability are assessed with the help of stability maps for liquid lubricants. The concept of fluid-stability maps based on deposit formation as a function of temperature is shown to be effective. At 200-425 C lubricant deposit formation in the presence of air is a function of lubricant volatility, oxidation rate, the rate of thermal degradation, and the effect of the bearing surface. Some materials are listed that can mitigate the effects of oxidation on lubricant performance which can be used for a range of aerospace applications. 16 refs.

  6. Lubricants for CFC alternates

    SciTech Connect (OSTI)

    Spauschus, H.O.

    1995-12-01

    With the recent development and introduction of environmentally preferred refrigerants as substitutes for HCFC`s, a number of new classes of companion compressor lubricants also have been offered. In contrast to the former compressor lubricants which were derived from petroleum based stocks, the new lubricants are synthetic products, initially designed to provide miscibilities and solubilities similar to the CFC/mineral oil predecessors. Rather than review the classes of lubricants being evaluated and used for different types of refrigeration machinery, this paper will address longer term benefits and challenges related to the introduction of synthetic compressor lubricants such as polyesters, polyolesters, polyalkalene glycols and polycarbonates. Within these families of synthetic fluids, large selections of chemical structures are available, each with unique physical and chemical properties. Of course all of the lubricants must meet general requirements of compressor oils with respect to flammability, pour point, volatility, toxicity, etc., but beyond these minimum requirements, there are technical options for tailoring lubricant structures to optimize certain lubricant (and thus lubricant/refrigerant) properties such as vapor pressure, solubility, viscosity, viscosity index, miscibility, moisture absorption, additive response and biodegradability. Basic studies to predict lubricant/refrigerant mixture properties based on chemical structure of the components are recommended. A number of practical challenges in the selection and application of new lubricants and new working fluids will be discussed including standards for bench screening tests and compressor tests, guidelines for lubricant handling during recovery and servicing of equipment and the potential for reprocessing compressor lubricants.

  7. Top-of-Rail lubricant

    SciTech Connect (OSTI)

    Alzoubi, M. F.; Fenske, G. R.; Erck, R. A.; Boparai, A. S.

    2000-07-14

    Analysis of the volatile and semivolatile fractions collected after use of the TOR lubricant indicated that other than contaminants in the collection laboratory, no compounds on the EPA's Target Compound Lists (Tables 2 and 5) were detected in these fractions. The data of these qualitative analyses, given in the various tables in the text, indicate only the relative amounts of the tentatively identified compounds. The authors recommend that quantitative analysis be performed on the volatile and semivolatile fractions to allow confirmation of the tentatively identified compounds and to obtain absolute amounts of the detected compounds. Additionally, the semivolatile fraction should be analyzed by liquid chromatography/mass spectrometry to identify compounds that are not chromatographable under the temperature program used for determination of semivolatile compounds. Introducing the top-of-rail (TOR) lubricant into the wheel/rail interface results in a reduction of almost 60% of lateral friction force over the forces encountered under dry conditions. This reveals good potential for energy savings, as well as wear reduction, for railroad companies. In TOR lubrication, an increase in the angle of attack and axle load results in increased lateral friction and rate of lubricant consumption. The most efficient TOR lubricant quantity to be used in the wheel/rail interface must be calculated precisely according to the number of cars, axle loads, train speed, and angle of attack.

  8. High temperature lubricating process

    DOE Patents [OSTI]

    Taylor, R.W.; Shell, T.E.

    1979-10-04

    It has been difficult to provide adequate lubrication for load bearing, engine components when such engines are operating in excess of about 475/sup 0/C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface, such as in an engine being operated at temperatures in excess of about 475/sup 0/C. The process comprises contacting and maintaining the following steps: a gas phase is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant; the gas phase is contacted with the load bearing surface; the load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant; and the solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

  9. High temperature lubricating process

    DOE Patents [OSTI]

    Taylor, Robert W.; Shell, Thomas E.

    1982-01-01

    It has been difficult to provide adaquate lubrication for load bearing, engine components when such engines are operating in excess of about 475.degree. C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface (14), such as in an engine (10) being operated at temperatures in excess of about 475.degree. C. The process comprises contacting and maintaining steps. A gas phase (42) is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant. The gas phase is contacted with the load bearing surface. The load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant. The solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

  10. Foaming characteristics of refigerant/lubricant mixtures

    SciTech Connect (OSTI)

    Goswami, D.Y.; Shah, D.O.; Jotshi, C.K.; Bhagwat, S.; Leung, M.; Gregory, A.

    1997-04-01

    The air-conditioning and refrigeration industry has moved to HFC refrigerants which have zero ozone depletion and low global warming potential due to regulations on CFC and HCFC refrigerants and concerns for the environment. The change in refrigerants has prompted the switch from mineral oil and alkylbenzene lubricants to polyolester-based lubricants. This change has also brought about a desire for lubricant, refrigerant and compressor manufacturers to understand the foaming properties of alternative refrigerant/ lubricant mixtures, as well as the mechanisms which affect these properties. The objectives of this investigation are to experimentally determine the foaming absorption and desorption rates of HFC and blended refrigerants in polyolester lubricant and to define the characteristics of the foam formed when the refrigerant leaves the refrigerant/ lubricant mixture after being exposed to a pressure drop. The refrigerants being examined include baseline refrigerants: CFC-12 (R-12) and HCFC-22 (R-22); alternative refrigerants: HFC-32 (R-32), R-125, R-134a, and R-143a; and blended refrigerants: R-404A, R-407C, and R-410A. The baseline refrigerants are tested with ISO 32 (Witco 3GS) and ISO 68 (4GS) mineral oils while the alternative and blended refrigerants are tested with two ISO 68 polyolesters (Witco SL68 and ICI RL68H).

  11. Method of removing an immiscible lubricant from a refrigeration system and apparatus for same

    DOE Patents [OSTI]

    Spauschus, Hans O.; Starr, Thomas L.

    1999-01-01

    A method of separating an immiscible lubricant from a liquid refrigerant in a refrigerating system including a compressor, a condenser, an expansion device and an evaporator, wherein the expansion device is connected to the condenser by a liquid refrigerant flow line for liquid refrigerant and immiscible lubricant. The method comprising slowing the rate of flow of the liquid refrigerant and immiscible lubricant between the condenser and the expansion device such that the liquid refrigerant and the immiscible lubricant separate based upon differences in density. The method also comprises collecting the separated immiscible lubricant in a collection chamber in fluid communication with the separated immiscible lubricant. Apparatus for performing the method is also disclosed.

  12. Friction, Wear, and Lubrication Technologies | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Erck Ali Erdemir Osman Eryilmaz Aaron Greco Projects Lubricants Advanced lubrication approaches that integrate fuel-efficient lubricants, low-friction materials and coatings...

  13. Methods to improve lubricity of fuels and lubricants

    DOE Patents [OSTI]

    Erdemir, Ali

    2009-06-16

    A method for providing lubricity in fuels and lubricants includes adding a boron compound to a fuel or lubricant to provide a boron-containing fuel or lubricant. The fuel or lubricant may contain a boron compound at a concentration between about 30 ppm and about 3,000 ppm and a sulfur concentration of less than about 500 ppm. A method of powering an engine to minimize wear, by burning a fuel containing boron compounds. The boron compounds include compound that provide boric acid and/or BO.sub.3 ions or monomers to the fuel or lubricant.

  14. Power system with an integrated lubrication circuit

    DOE Patents [OSTI]

    Hoff, Brian D.; Akasam, Sivaprasad; Algrain, Marcelo C.; Johnson, Kris W.; Lane, William H.

    2009-11-10

    A power system includes an engine having a first lubrication circuit and at least one auxiliary power unit having a second lubrication circuit. The first lubrication circuit is in fluid communication with the second lubrication circuit.

  15. Synthesis of new high performance lubricants and solid lubricants

    SciTech Connect (OSTI)

    Lagow, R.J.

    1993-04-01

    Synthesis and testing was begun on a number of new classes of lubricants: perfluoropolyethers (branching effects), perfluoromethylene oxide ethers, chlorine-substituted fluorocarbon polyethers, fluorine-containing branched ether lubricants, glycerine- based perfluoropolyesters, perfluoro epoxy ether chains, etc.

  16. Fluid lubricated bearing assembly

    DOE Patents [OSTI]

    Boorse, Henry A.; Boeker, Gilbert F.; Menke, John R.

    1976-01-01

    1. A support for a loaded rotatable shaft comprising in combination on a housing having a fluid-tight cavity encasing an end portion of said shaft, a thrust bearing near the open end of said cavity for supporting the axial thrust of said shaft, said thrust bearing comprising a thrust plate mounted in said housing and a thrust collar mounted on said shaft, said thrust plate having a central opening the peripheral portion of which is hermetically sealed to said housing at the open end of said cavity, and means for supplying a fluid lubricant to said thrust bearing, said thrust bearing having a lubricant-conducting path connecting said lubricant supplying means with the space between said thrust plate and collar intermediate the peripheries thereof, the surfaces of said plate and collar being constructed and arranged to inhibit radial flow of lubricant and, on rotation of said thrust collar, to draw lubricant through said path between the bearing surfaces and to increase the pressure therebetween and in said cavity and thereby exert a supporting force on said end portion of said shaft.

  17. Fluid lubricated bearing construction

    DOE Patents [OSTI]

    Dunning, John R.; Boorse, Henry A.; Boeker, Gilbert F.

    1976-01-01

    1. A fluid lubricated thrust bearing assembly comprising, in combination, a first bearing member having a plain bearing surface, a second bearing member having a bearing surface confronting the bearing surface of said first bearing member and provided with at least one spiral groove extending inwardly from the periphery of said second bearing member, one of said bearing members having an axial fluid-tight well, a source of fluid lubricant adjacent to the periphery of said second bearing member, and means for relatively rotating said bearing members to cause said lubricant to be drawn through said groove and to flow between said bearing surfaces, whereby a sufficient pressure is built up between said bearing surfaces and in said well to tend to separate said bearing surfaces.

  18. Lubrication with boric acid additives

    DOE Patents [OSTI]

    Erdemir, Ali

    2000-01-01

    Self-lubricating resin compositions including a boric acid additive and a synthetic polymer including those thermoset materials.

  19. Metal working lubricant compositions

    SciTech Connect (OSTI)

    Andress, H.J.; Davis, R.H.; Schick, J.W.

    1981-08-11

    A lubricant concentrate for use in metal processing comprises a sulfur compound such as a sulfurized olefin or sulfurized mineral oil and an ester prepared from a fatty acid having 12 to 40 carbon atoms or the dimer thereof or a polyalkenylsuccinic acid or anhydride and a hydroxyl-containing amine.

  20. Lubricant selection criteria and the tribological system

    SciTech Connect (OSTI)

    Lauer, D.A.

    1995-07-01

    Before the proper lubricant selection can be made, the tribological system must be identified to its fullest extent. This system includes the type of motion, speeds, temperatures, loads and the environment that is specific to the application. Once these parameters are identified, lubrication engineers or tribo-engineers can use their knowledge of the different lubricant chemistries to make a lubricant selection that will optimize the performance of the application. In addition to lubricant chemistry knowledge, the lubrication engineer also must analyze the application based on the identified tribological system. This analysis includes such topics as speed factors, elastohydrodynamic lubrication, extreme pressure lubrication, emergency lubrication and various special application requirements.

  1. Lubricant characterization by molecular simulation

    SciTech Connect (OSTI)

    Moore, J.D.; Cui, S.T.; Cummings, P.T.; Cochran, H.D.

    1997-12-01

    The authors have reported the calculation of the kinematic viscosity index of squalane from nonequilibrium molecular dynamics simulations. This represents the first accurate quantitative prediction of this measure of lubricant performance by molecular simulation. Using the same general alkane potential model, this computational approach offers the possibility of predicting the performance of potential lubricants prior to synthesis. Consequently, molecular simulation is poised to become an important tool for future lubricant development.

  2. Ionic Liquids as Novel Engine Lubricants or Lubricant Additives |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Bench test results showed that compared with fully-formulated engine oils, selected low-viscosity ionic liquids, used as neat lubricants or basestock, produced significantly lower friction and engine wear PDF icon deer11_qu.pdf More Documents & Publications Ionic Liquids as Multifunctional Ashless Additives for Engine Lubrication

  3. Process for preparing lubricating oil from used waste lubricating oil

    DOE Patents [OSTI]

    Whisman, Marvin L.; Reynolds, James W.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A re-refining process is described by which high-quality finished lubricating oils are prepared from used waste lubricating and crankcase oils. The used oils are stripped of water and low-boiling contaminants by vacuum distillation and then dissolved in a solvent of 1-butanol, 2-propanol and methylethyl ketone, which precipitates a sludge containing most of the solid and liquid contaminants, unspent additives, and oxidation products present in the used oil. After separating the purified oil-solvent mixture from the sludge and recovering the solvent for recycling, the purified oil is preferably fractional vacuum-distilled, forming lubricating oil distillate fractions which are then decolorized and deodorized to prepare blending stocks. The blending stocks are blended to obtain a lubricating oil base of appropriate viscosity before being mixed with an appropriate additive package to form the finished lubricating oil product.

  4. Separate lubricating system for marine propulsion device

    SciTech Connect (OSTI)

    Matsumoto, K.

    1986-02-25

    This patent describes a lubricating system for a two-cycle internal combustion engine. This system consists of a relatively large remotely positioned lubricant storage tank a relatively small lubricant delivery tank positioned in proximity to the engine for delivering lubricant to its lubricating system and means responsive to the level of lubricant in the delivery tank for transferring lubricant to maintain a predetermined level of lubricant in the delivery tank. The improvement consists of means for providing a warning signal when the level of lubricant in the storage tank falls below a predetermined amount. The means for providing the warning signal operate further to discontinue the transfer of lubricant from the storage tank to the delivery tank. There also is a manual override for operating the means for transferring lubricant from the storage tank to the delivery tank under operator control even when the warning signal has been activated.

  5. Method of removing an immiscible lubricant from a refrigeration system and apparatus for same

    DOE Patents [OSTI]

    Spauschus, H.O.; Starr, T.L.

    1999-03-30

    A method is described for separating an immiscible lubricant from a liquid refrigerant in a refrigerating system including a compressor, a condenser, an expansion device and an evaporator, wherein the expansion device is connected to the condenser by a liquid refrigerant flow line for liquid refrigerant and immiscible lubricant. The method comprising slowing the rate of flow of the liquid refrigerant and immiscible lubricant between the condenser and the expansion device such that the liquid refrigerant and the immiscible lubricant separate based upon differences in density. The method also comprises collecting the separated immiscible lubricant in a collection chamber in fluid communication with the separated immiscible lubricant. Apparatus for performing the method is also disclosed. 3 figs.

  6. Method for lubricating contacting surfaces

    DOE Patents [OSTI]

    Dugger, Michael T.; Ohlhausen, James A.; Asay, David B.; Kim, Seong H.

    2011-12-06

    A method is provided for tribological lubrication of sliding contact surfaces, where two surfaces are in contact and in motion relative to each other, operating in a vapor-phase environment containing at least one alcohol compound at a concentration sufficiently high to provide one monolayer of coverage on at least one of the surfaces, where the alcohol compound continuously reacts at the surface to provide lubrication.

  7. Engine lubrication circuit including two pumps

    DOE Patents [OSTI]

    Lane, William H.

    2006-10-03

    A lubrication pump coupled to the engine is sized such that the it can supply the engine with a predetermined flow volume as soon as the engine reaches a peak torque engine speed. In engines that operate predominately at speeds above the peak torque engine speed, the lubrication pump is often producing lubrication fluid in excess of the predetermined flow volume that is bypassed back to a lubrication fluid source. This arguably results in wasted power. In order to more efficiently lubricate an engine, a lubrication circuit includes a lubrication pump and a variable delivery pump. The lubrication pump is operably coupled to the engine, and the variable delivery pump is in communication with a pump output controller that is operable to vary a lubrication fluid output from the variable delivery pump as a function of at least one of engine speed and lubrication flow volume or system pressure. Thus, the lubrication pump can be sized to produce the predetermined flow volume at a speed range at which the engine predominately operates while the variable delivery pump can supplement lubrication fluid delivery from the lubrication pump at engine speeds below the predominant engine speed range.

  8. 2014 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels & Lubricants Technologies 2014 Annual Merit Review Results Report - Fuels & Lubricants Technologies Merit review of DOE Vehicle Technologies research activities...

  9. Ionic Liquids as Novel Lubricants and /or Lubricant Additives

    SciTech Connect (OSTI)

    Qu, J.; Viola, M. B.

    2013-10-31

    This ORNL-GM CRADA developed ionic liquids (ILs) as novel lubricants or oil additives for engine lubrication. A new group of oil-miscible ILs have been designed and synthesized with high thermal stability, non-corrosiveness, excellent wettability, and most importantly effective anti-scuffing/anti-wear and friction reduction characteristics. Mechanistic analysis attributes the superior lubricating performance of IL additives to their physical and chemical interactions with metallic surfaces. Working with a leading lubricant formulation company, the team has successfully developed a prototype low-viscosity engine oil using a phosphonium-phosphate IL as an anti-wear additive. Tribological bench tests of the IL-additized formulated oil showed 20-33% lower friction in mixed and elastohydrodynamic lubrication and 38-92% lower wear in boundary lubrication when compared with commercial Mobil 1 and Mobil Clean 5W-30 engine oils. High-temperature, high load (HTHL) full-size engine tests confirmed the excellent anti-wear performance for the IL-additized engine oil. Sequence VID engine dynamometer tests demonstrated an improved fuel economy by >2% for this IL-additized engine oil benchmarked against the Mobil 1 5W-30 oil. In addition, accelerated catalyst aging tests suggest that the IL additive may potentially have less adverse impact on three-way catalysts compared to the conventional ZDDP. Follow-on research is needed for further development and optimization of IL chemistry and oil formulation to fully meet ILSAC GF-5 specifications and further enhance the automotive engine efficiency and durability.

  10. Influence of rheological properties of a lubricant on power consumption and heat transfer in a hydrostatic lubricating layer

    SciTech Connect (OSTI)

    Yablonskii, V.O.; Tyabin, N.V.; Yashchuk, V.M.

    1995-06-01

    The influence of rheological properties of lubricants on power consumption for pumping the lubricant in a hydrostatic lubricating layer and heat transfer of the lubricant with the supporting surfaces of a bearing is studied.

  11. Method For Testing Properties Of Corrosive Lubricants

    DOE Patents [OSTI]

    Ohi, James; De La Cruz, Jose L.; Lacey, Paul I.

    2006-01-03

    A method of testing corrosive lubricating media using a wear testing apparatus without a mechanical seal. The wear testing apparatus and methods are effective for testing volatile corrosive lubricating media under pressure and at high temperatures.

  12. Tethered Lubricants for Small Systems

    SciTech Connect (OSTI)

    Lynden A. Archer

    2006-01-09

    The objective of this research project is two-fold. First, to fundamentally understand friction and relaxation dynamics of polymer chains near surfaces; and second, to develop novel self-lubricated substrates suitable for MEMS devices. During the three-year performance period of this study the PI and his students have shown using theory and experiments that systematic introduction of disorder into tethered lubricant coatings (e.g. by using self-assembled monolayer (SAM) mixtures or SAMs with nonlinear, branched architectures) can be used to significantly reduce the friction coefficient of a surface. They have also developed a simple procedure based on dielectric spectroscopy for quantifying the effect of surface disorder on molecular relaxation in lubricant coatings. Details of research accomplishments in each area of the project are described in the body of the report.

  13. USDOE Top-of-Rail Lubricant Project

    SciTech Connect (OSTI)

    Mohumad F. Alzoubi; George R. Fenske; Robert A. Erck; Amrit S. Boparai

    2002-02-01

    Lubrication of wheel/rail systems has been recognized for the last two decades as a very important issue for railroads. Energy savings and less friction and wear can be realized if a lubricant can be used at the wheel/rail interface. On the other hand, adverse influences are seen in operating and wear conditions if improper or excessive lubrication is used. Also, inefficiencies in lubrication need to be avoided for economic and environmental reasons. The top-of-rail (TOR) lubricant concept was developed by Texaco Corporation to lubricate wheels and rails effectively and efficiently. Tranergy Corporation has been developing its SENTRAEN 2000{trademark} lubrication system for the last ten years, and this revolutionary new high-tech on-board rail lubrication system promises to dramatically improve the energy efficiency, performance, safety, and track environment of railroads. The system is fully computer-controlled and ensures that all of the lubricant is consumed as the end of the train passes. Lubricant quantity dispensed is a function of grade, speed, curve, and axle load. Tranergy also has its LA4000{trademark} wheel and rail simulator, a lubrication and traction testing apparatus. The primary task of this project was collecting and analyzing the volatile and semivolatile compounds produced as the lubricant was used. The volatile organic compounds were collected by Carbotrap cartridges and analyzed by adsorption and gas chromatography/mass spectrometry (GC/MS). The semivolatile fraction was obtained by collecting liquid that dripped from the test wheel. The collected material was also analyzed by GC/MS. Both of these analyses were qualitative. The results indicated that in the volatile fraction, the only compounds on the Environmental Protection Agency's (EPA) Superfund List of Analytes detected were contaminants either in the room air or from other potential contamination sources in the laboratory. Similarly, in the semivolatile fraction none of the detected compounds are on the EPA's Superfund List of Analytes. The major compound in the semivolatile fraction is 1,2-propanediol, which was also found as the major component of the TOR lubricant before testing. Other compounds found in trace quantities either were present in the TOR lubricant or were small fragments from the polymeric component of the TOR lubricant. The second task for Argonne in this project was to investigate the effects of axle load, angle of attack, and quantity of lubricant on lateral friction forces, as well as the consumption time of the TOR lubricant. The second task was to collect and qualitatively identify any volatile and semivolatile compounds produced upon use of the TOR lubricant.

  14. Synthesis of new high performance lubricants and solid lubricants. Progress report, April 1992--March 1993

    SciTech Connect (OSTI)

    Lagow, R.J.

    1993-04-01

    Synthesis and testing was begun on a number of new classes of lubricants: perfluoropolyethers (branching effects), perfluoromethylene oxide ethers, chlorine-substituted fluorocarbon polyethers, fluorine-containing branched ether lubricants, glycerine- based perfluoropolyesters, perfluoro epoxy ether chains, etc.

  15. Water-based lubricants for metalworking

    SciTech Connect (OSTI)

    Shukla, D.S.; Jain, V.K.

    1997-05-01

    Metalworking fluids currently constitute 17% of the total US industrial lubricant market. Market forces favor semisynthetic and synthetic formulations because they are more economical, and trends differ substantially from those of other lubricant markets as demand patterns shift. Lubricant manufacturers continue to reduce the use of mineral oil as a component in their formulations because synthetic and semisynthetic formulations are more cost-effective. The introduction of new engineering materials also has increased the demand for tailor-made lubricants in industrial applications. Synthetic and semisynthetic formulations are favored for cutting and metalworking applications because they perform better than the existing commercial product does. The literature strongly supports the development of environmentally friendly synthetic and semisynthetic metalworking lubricants that have longer useful lives, therefore decreasing the amount of fluid for disposal. Future lubricant formulations will focus on environmental issues, process compatibility, and worker health and safety. Biological control of fluids, in use and in disposal, will also draw attention.

  16. Vehicle Technologies Office: Lubricants | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Efficiency & Emissions » Vehicle Technologies Office: Lubricants Vehicle Technologies Office: Lubricants As most vehicles are on the road for more than 15 years before they are retired, investigating technologies that will improve today's vehicles is essential. Because 11.5 percent of fuel energy is consumed by engine friction, decreasing this friction through lubricants can lead to substantial improvements in the fuel economy of current vehicles, without needing to wait for the fleet

  17. Thermal reactivity of mixtures of VDDT lubricant and simulated Hanford Tank 241-SY-101 waste

    SciTech Connect (OSTI)

    Scheele, R.D.; Panisko, F.E.; Sell, R.L.

    1996-09-01

    To predict whether the Polywater G lubricant residue remaining in the velocity, density, and temperature tree (VDTT) and the waste in Tank 241-SY-101 (101SY) will be chemically compatible with wastes in 101SY when two VDTTs are removed from 101SY, the Pacific Northwest National Laboratory measured the thermal reaction sensitivity of the lubricant residue. This residue is a simulated 101SY waste containing the organic surrogate trisodium hydroxyethyl-ethylenediaminetriacetate (Na{sub 3}HEDTA) and two simulated potential waste and lubricant residue mixtures containing 10 and 90 percent lubricant residue. These studies using accelerating rate calorimetry found that the residue did not react at a rate exceeding 0.1 J/min/g mixture up to 190 degrees C with simulated 101SY waste containing Na{sub 3}HEDTA as the organic surrogate. Also, the dried lubricant residue did not decompose exothermically at a rate exceeding 0.1 J/min/g. Using guidelines used by the chemical industry, these results indicate that the lubricant residue should not react as a significant rate with the waste in 101SY when added to the waste at 60 degrees C or when the mixture cools to the waste`s temperature of 48 degrees C.

  18. Lubrication Systems Market : Mining & Mineral Processing Industry...

    Open Energy Info (EERE)

    Groeneveld Groep B.V., SKF AB, Bijur Delimon, Castrol-Lubecon, Changzhou Huali Hydraulic Lubrication Equipment Co., Ltd., Changhua Chen Ying Oil Machine Co., Ltd., Equipment...

  19. Biodiesel Impact on Engine Lubricant Oil Dilution

    Broader source: Energy.gov [DOE]

    Heavy-duty engine and light-duty vehicle experiments were conducted to investigate the potential for lubricant dilution by fuel during DPF regeneration events.

  20. Lubrication from mixture of boric acid with oils and greases

    DOE Patents [OSTI]

    Erdemir, A.

    1995-07-11

    Lubricating compositions are disclosed including crystalline boric acid and a base lubricant selected from oils, greases and the like. The lubricity of conventional oils and greases can also be improved by adding concentrates of boric acid.

  1. Lubrication from mixture of boric acid with oils and greases

    DOE Patents [OSTI]

    Erdemir, Ali

    1995-01-01

    Lubricating compositions including crystalline boric acid and a base lubricant selected from oils, greases and the like. The lubricity of conventional oils and greases can also be improved by adding concentrates of boric acid.

  2. Collaborative Lubricating Oil Study on Emissions (CLOSE Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Lung Toxicity and ...

  3. Experimental and Theoretical Investigation of Lubricant and Additive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Theoretical Investigation of Lubricant and Additive Effects on Engine Friction Experimental and Theoretical Investigation of Lubricant and Additive Effects on Engine Friction ...

  4. Lubricant Formulation and Consumption Effects on Diesel Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: 2005 Diesel Engine ...

  5. Friction Modeling for Lubricated Engine and Drivetrain Components...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modeling for Lubricated Engine and Drivetrain Components Friction Modeling for Lubricated Engine and Drivetrain Components 2010 DOE Vehicle Technologies and Hydrogen Programs...

  6. Multi-component Nanoparticle Based Lubricant Additive to Improve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanoparticle Based Lubricant Additive to Improve Efficiency and Durability in Engines Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency and ...

  7. Friction of Steel Sliding Under Boundary Lubrication Regime in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Steel Sliding Under Boundary Lubrication Regime in Commercial Gear Oils at Elevated Temperatures Friction of Steel Sliding Under Boundary Lubrication Regime in Commercial Gear ...

  8. Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet Vehicles Reviews recent studies on potential for low-viscosity lubricants and low-friction surfaces and additives ...

  9. Detailed Characterization of Lubricant-Derived Ash-Related Species...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on Crankcase Oil Properties Lubricant Formulation and Consumption ...

  10. Lubricant-infused nanoparticulate coatings assembled by layer...

    Office of Scientific and Technical Information (OSTI)

    Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition Title: Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition ...

  11. Effects of Fuel Dilution with Biodiesel on Lubricant Acidity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion ...

  12. Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel and Lubricant Technologies R&D Annual Progress Report Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies R&D Annual Progress Report This report describes the ...

  13. Collaborative Lubricating Oil Study on Emissions (CLOSE Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE Project) 2011 DOE ... More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE ...

  14. 2013 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels & Lubricants 2013 Annual Merit Review Results Report - Fuels & Lubricants Merit review of DOE Vehicle Technologies research activities 2013amr05.pdf More Documents &...

  15. Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R&D Annual Progress Report The Fuel & Lubricant Technologies subprogram supports fuels and lubricants research and development (R&D) to provide vehicle users with...

  16. Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives PDF icon nanoparticulate-basedlubricati...

  17. Smart Surface and Lubrication Engineering show Promise for Gearbox...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Smart Surface and Lubrication Engineering show Promise for Gearbox Reliability Smart Surface and Lubrication Engineering show Promise for Gearbox Reliability May 20, 2011 - 1:10pm ...

  18. Testing of nuclear grade lubricants and their effects on A540 B24 and A193 B7 bolting materials

    SciTech Connect (OSTI)

    Czajkowski, C.J.

    1985-01-01

    An investigation was performed on eleven commonly used lubricants by the nuclear power industry. The investigation included EDS analysis of the lubricants, notched-tensile constant extension rate testing of bolting materials with the lubricants, frictional testing of the lubricants and weight loss testing of a bonded solid film lubricant. The report generally concludes that there is a significant amount of variance in the mechanical properties of common bolting materials; that MoS/sub 2/ can hydrolyze to form H/sub 2/S at 100/sup 0/C and cause stress corrosion cracking (SCC) of bolting materials, and that the use of copper-containing lubricants can be potentially detrimental to high strength steels in an aqueous environment. Additionally, the testing of various lubricants disclosed that some lubricants contain potentially detrimental elements (e.g. S, Sb) which can promote SCC of the common bolting materials. One of the most significant findings of this report is the observation that both A193 B7 and A540 B24 bolting materials are susceptible to transgranular stress corrosion cracking in demineralized H/sub 2/O at 280/sup 0/C in notched tensile tests.

  19. Offshore Lubricants Market Size | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Size Home There are currently no posts in this category. Syndicate content...

  20. Offshore Lubricants Market Forecast | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Forecast Home There are currently no posts in this category. Syndicate...

  1. Global Offshore Lubricants Market | OpenEI Community

    Open Energy Info (EERE)

    Global Offshore Lubricants Market Home There are currently no posts in this category. Syndicate content...

  2. Offshore Lubricants Market Analysis | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Analysis Home There are currently no posts in this category. Syndicate...

  3. Double angle seal forming lubricant film

    DOE Patents [OSTI]

    Ernst, William D.

    1984-01-01

    A lubricated piston rod seal which inhibits gas leaking from a high pressure chamber on one side of the seal to a low pressure chamber on the other side of the seal. A liquid is supplied to the surface of the piston rod on the low pressure side of the seal. This liquid acts as lubricant for the seal and provides cooling for the rod. The seal, which can be a plastic, elastomer or other material with low elastic modulus, is designed to positively pump lubricant through the piston rod/seal interface in both directions when the piston rod is reciprocating. The capacity of the seal to pump lubricant from the low pressure side to the high pressure side is less than its capacity to pump lubricant from the high pressure side to the low pressure side which ensures that there is zero net flow of lubricant to the high pressure side of the seal. The film of lubricant between the seal and the rod minimizes any sliding contact and prevents the leakage of gas. Under static conditions gas leakage is prevented by direct contact between the seal and the rod.

  4. Laser-induced short time scale thermal chemistry of perfluoropolyether lubricant films

    SciTech Connect (OSTI)

    Heller, J.; Mate, C.J.; Poon, C.C.; Tam, A.C.

    1999-11-09

    The authors investigate the effect of heating a perfluoropolyether lubricant film in a localized area for relatively short time periods using laser irradiation versus conventional oven heating. These experiments help provide understanding on how flash temperatures generated at frictional contacts affect the thermal chemistry of lubricant films. In these experiments, a CO{sub 2} laser heats a 50 {micro}m wide area of a silicon wafer for time periods ranging from 0.1 to 60 s. The surface temperature within the heated area (up to 280 C in these experiments) is monitored with a second laser by measuring the change in reflectivity near the center of the heated area. A major difference observed for laser heating compared to oven heating is that the effective evaporation rate is orders of magnitude higher for laser heating. If the lubricant film is heated for sufficiently long enough time at high temperatures, the authors are able to observe thermal bonding of the lubricant via its alcohol end groups to the silicon oxide surface, followed by thermal decomposition of the lubricant molecules. After laser heating, the authors are able to observe the diffusion of lubricant back into the localized heated area using a combination of optical microscopy and imaging ellipsometry.

  5. Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 2

    SciTech Connect (OSTI)

    Gunsel, Selda; Pozebanchuk, Michael

    1999-04-01

    Lubrication properties of refrigeration lubricants were investigated in high pressure nonconforming contacts under different conditions of temperature, rolling speed, and refrigerant concentration. The program was based upon the recognition that the lubrication regime in refrigeration compressors is generally elastohydrodynamic or hydrodynamic, as determined by the operating conditions of the compressor and the properties of the lubricant. Depending on the compressor design, elastohydrodynamic lubrication conditions exist in many rolling and sliding elements of refrigeration compressors such as roller element bearings, gears, and rotors. The formation of an elastohydrodynamic film separating rubbing surfaces is important in preventing the wear and failure of compressor elements. It is, therefore, important to predict the elastohydrodynamic (EHD) performance of lubricants under realistic tribocontact renditions. This is, however, difficult as the lubricant properties that control film formation are critically dependent upon pressure and shear, and cannot be evaluated using conventional laboratory instruments. In this study, the elastohydrodynamic behavior of refrigeration lubricants with and without the presence of refrigerants was investigated using the ultrathin film EHD interferometry technique. This technique enables very thin films, down to less than 5 nm, to be measured accurately within an EHD contact under realistic conditions of temperature, shear, and pressure. The technique was adapted to the study of lubricant refrigerant mixtures. Film thickness measurements were obtained on refrigeration lubricants as a function of speed, temperature, and refrigerant concentration. The effects of lubricant viscosity, temperature, rolling speed, and refrigerant concentration on EHD film formation were investigated. From the film thickness measurements, effective pressure-viscosity coefficients were calculated. The lubricants studied in this project included two naphthenic mineral oils (NMO), four polyolesters (POE), and two polyvinyl ether (PVE) fluids. These fluids represented viscosity grades of ISO 32 and ISO 68 and are shown in a table. Refrigerants studied included R-22, R-134a, and R-410A. Film thickness measurements were conducted at 23 C, 45 C, and 65 C with refrigerant concentrations ranging from zero to 60% by weight.

  6. Low Reactivity SI Engine Lubricant Program | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Results showed that lubricant improvement allowed up to 4 degree improvement in spark advance at knock limited conditions resulting in potentially over 3 percent indicated efficiency improvement PDF icon deer11_alger.pdf More Documents & Publications Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report Fuel & Lubricant Technologies Ionic Liquids as Novel Engine Lubricants or Lubricant Additives

  7. Fuel & Lubricant Technologies | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    ft000_stork_2012_o.pdf More Documents & Publications Fuel & Lubricant Technologies Overview of the DOE Advanced Combustion Engine R&D Overview of DOE Advanced Combustion Engine R&D

  8. Advanced lubrication systems and materials. Final report

    SciTech Connect (OSTI)

    Hsu, S.

    1998-05-07

    This report described the work conducted at the National Institute of Standards and Technology under an interagency agreement signed in September 1992 between DOE and NIST for 5 years. The interagency agreement envisions continual funding from DOE to support the development of fuel efficient, low emission engine technologies in terms of lubrication, friction, and wear control encountered in the development of advanced transportation technologies. However, in 1994, the DOE office of transportation technologies was reorganized and the tribology program was dissolved. The work at NIST therefore continued at a low level without further funding from DOE. The work continued to support transportation technologies in the development of fuel efficient, low emission engine development. Under this program, significant progress has been made in advancing the state of the art of lubrication technology for advanced engine research and development. Some of the highlights are: (1) developed an advanced high temperature liquid lubricant capable of sustaining high temperatures in a prototype heat engine; (2) developed a novel liquid lubricant which potentially could lower the emission of heavy duty diesel engines; (3) developed lubricant chemistries for ceramics used in the heat engines; (4) developed application maps for ceramic lubricant chemistry combinations for design purpose; and (5) developed novel test methods to screen lubricant chemistries for automotive air-conditioning compressors lubricated by R-134a (Freon substitute). Most of these findings have been reported to the DOE program office through Argonne National Laboratory who manages the overall program. A list of those reports and a copy of the report submitted to the Argonne National Laboratory is attached in Appendix A. Additional reports have also been submitted separately to DOE program managers. These are attached in Appendix B.

  9. Fuel & Lubricant Technologies | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    6 addresses Malware, the Worst Passwords of 2013, and the Flat Stanley and Stop.Think.Connect. Campaign. PDF icon Cybersecurity Front Burner Newsletter Issue 16 More Documents & Publications April 2014 Cybersecurity Awareness Campaign - Malware FRONT BURNER - Issue 20

    vtpn06_fl_stork_2012_o.pdf More Documents & Publications Fuel & Lubricant Technologies Fuel & Lubricant Technologies R&D Overview of Fuels Technologies

  10. Lubricant analysis for gas turbine condition monitoring

    SciTech Connect (OSTI)

    Lukas, M.; Anderson, D.P.

    1997-10-01

    Analysis of used lubricating oil is a fast-evolving technique for predictive maintenance with any closed-loop lubricating system such as those in gas and steam turbines, diesel and gasoline engines, transmissions, gearboxes, compressors, pumps, bearings, and hydraulic systems. Based on analysis of periodic oil samples, a laboratory diagnostic report is sent to the personnel responsible for the equipment to warn of any possible problem or to make a specific maintenance recommendation. The entire process, from sample taking to the diagnostic report, should take less than 48 hours to be effective. These reports, when combined with statistical analysis and trending, can provide an insight to management personnel on the effectiveness of the program, efficiency of the maintenance department, repair status of equipment, recurring problems, and even information on the performance of different lubricants. Condition monitoring by oil analysis can be broken down into two categories: debris monitoring to measure the trace quantities of wear particles carried by the lubricant away from the wearing surfaces and lubricant condition monitoring to determine whether the lubricant itself is fit for service based on physical and chemical tests.

  11. Solubility modeling of refrigerant/lubricant mixtures

    SciTech Connect (OSTI)

    Michels, H.H.; Sienel, T.H.

    1996-12-31

    A general model for predicting the solubility properties of refrigerant/lubricant mixtures has been developed based on applicable theory for the excess Gibbs energy of non-ideal solutions. In our approach, flexible thermodynamic forms are chosen to describe the properties of both the gas and liquid phases of refrigerant/lubricant mixtures. After an extensive study of models for describing non-ideal liquid effects, the Wohl-suffix equations, which have been extensively utilized in the analysis of hydrocarbon mixtures, have been developed into a general form applicable to mixtures where one component is a POE lubricant. In the present study we have analyzed several POEs where structural and thermophysical property data were available. Data were also collected from several sources on the solubility of refrigerant/lubricant binary pairs. We have developed a computer code (NISC), based on the Wohl model, that predicts dew point or bubble point conditions over a wide range of composition and temperature. Our present analysis covers mixtures containing up to three refrigerant molecules and one lubricant. The present code can be used to analyze the properties of R-410a and R-407c in mixtures with a POE lubricant. Comparisons with other models, such as the Wilson or modified Wilson equations, indicate that the Wohl-suffix equations yield more reliable predictions for HFC/POE mixtures.

  12. Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants. Final report, Part 1

    SciTech Connect (OSTI)

    Cavestri, R.C.

    1997-07-01

    Part one of this research provides manufacturers of components of air-conditioning and refrigeration equipment with a useful list of lubricant additives, sources, functional properties and chemical species. The list in part one is comprised of domestic lubricant additive suppliers and the results of a literature search that was specifically targeted for additives reported to be useful in polyolester chemistry.

  13. Biocides for lubricant rancidity and biofouling prevention

    SciTech Connect (OSTI)

    Passman, F.J.

    1997-10-01

    Lubricant systems provide a good environment for microbial communities. Growing most abundantly on surfaces, microbes can change lubricant performance properties by selectively depleting functional additives. Moreover, microbial metabolites can stimulate corrosion and induce invert emulsion formation. The keys to microbial contamination control are good industrial hygiene, monitoring and timely treatment. There are more than 30 USEPA registered metalworking fluid biocides. Each has an application where it provides cost-effective protection. Biocides should be selected based on performance in a particular coolant and system. Most often, biocides with limited solubility in non-polar solvents work better in lubricants. Bench tests provide a relatively inexpensive method for evaluating alternative treatments. Bench test data need to be confirmed through field evaluations. Bioresistant additives that have no obvious functionality other than replacing registered biocides should be considered with care. Properly used as one component of a complete lubricant system management program, data-driven biocide use can extend lubricant life dramatically, reduce downtime and create a healthier work environment.

  14. Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Vehicle Technologies Office: 2012 Fuel and Lubricant ...

  15. Turbine engine lubricant foaming due to silicone basestock used in non-specification spline lubricant

    SciTech Connect (OSTI)

    Centers, P.W.

    1995-05-01

    Dependent upon molecular weight and distribution, concentration, temperature, air flow, and test details or field application, polydimethylsiloxane (PDMS) may be neutral, profoamant or antifoamant in polyolesters. This understanding was critical in the solution of a turbine engine lubrication system foaming problem occurring at several military locations. Suspect turbine engine-accessory gearbox assembly materials gathered from several sites were evaluated. One non-specification PDMS-based spline lubricant caused copious foaming of the lubricant at less than ten parts-per-million concentration, while a specification polymethyl-phenylsiloxane (PMPS)-based lubricant required a concentration nearly 2000 times greater to generate equivalent foam. Use of the profoamant PDMS spline lubricant was then prohibited. Since prohibition, foaming of turbine engine lubricants used in the particular application has not been reported. PMPS impact on foaming of ester lubricants is similar to a much more viscous PDMS attributed to the reduced interaction of PMPS in esters due to pendant phenyl structure of PMPS absent in PDMS. These data provide significant additional insight and methodology to investigate foaming tendencies of partially miscible silicone-ester and other fluid systems. 7 refs., 2 figs., 1 tab.

  16. EERE Success Story - Novel Engine Lubrication Anti-Wear Additives

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstrate Improved Fuel Economy | Department of Energy Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy March 14, 2016 - 1:27pm Addthis EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story -

  17. Method for reclaiming waste lubricating oils

    DOE Patents [OSTI]

    Whisman, Marvin L.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A method for purifying and reclaiming used lubricating oils containing additives such as detergents, antioxidants, corrosion inhibitors, extreme pressure agents and the like and other solid and liquid contaminants by preferably first vacuum distilling the used oil to remove water and low-boiling contaminants, and treating the dried oil with a solvent mixture of butanol, isopropanol and methylethyl ketone which causes the separation of a layer of sludge containing contaminants, unspent additives and oxidation products. After solvent recovery, the desludged oil is then subjected to conventional lubricating oil refining steps such as distillation followed by decolorization and deodorization.

  18. FY2013 Progress Report for Fuel & Lubricant Technologies

    SciTech Connect (OSTI)

    none,

    2014-02-01

    Annual progress report for Fuel & Lubricant Technologies. The Fuel & Lubricant Technologies Program supports fuels and lubricants research and development (R&D) to provide vehicle manufacturers and users with cost-competitive options that enable high fuel economy with low emissions, and contribute to petroleum displacement.

  19. Engine Lubricants: Trends and Challenges | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    This overview discusses how lubricant developers, lubricant marketers, and OEMs are working with the engine community to overcome performance challenges worldwide. PDF icon deer12_bansal.pdf More Documents & Publications Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet Vehicles Vehicle Technologies Office Merit Review 2015: Engine Friction Reduction Technologies Vehicle Technologies Office Merit Review 2014: Engine Friction Reduction Technologies

  20. Lubricants or lubricant additives composed of ionic liquids containing ammonium cations

    DOE Patents [OSTI]

    Qu, Jun (Knoxville, TN) [Knoxville, TN; Truhan, Jr.,; John J. (Cookeville, TN) [Cookeville, TN; Dai, Sheng (Knoxville, TN) [Knoxville, TN; Luo, Huimin (Knoxville, TN) [Knoxville, TN; Blau, Peter J. (Knoxville, TN) [Knoxville, TN

    2010-07-13

    A lubricant or lubricant additive is an ionic liquid alkylammonium salt. The alkylammonium salt has the structure R.sub.xNH.sub.(4-x).sup.+,[F.sub.3C(CF.sub.2).sub.yS(O).sub.2].sub.2N.sup- .- where x is 1 to 3, R is independently C.sub.1 to C.sub.12 straight chain alkyl, branched chain alkyl, cycloalkyl, alkyl substituted cycloalkyl, cycloalkyl substituted alkyl, or, optionally, when x is greater than 1, two R groups comprise a cyclic structure including the nitrogen atom and 4 to 12 carbon atoms, and y is independently 0 to 11. The lubricant is effective for the lubrication of many surfaces including aluminum and ceramics surfaces.

  1. Exploring Low Emission Lubricants for Diesel Engines

    SciTech Connect (OSTI)

    Perez, J. M.

    2000-07-06

    A workshop to explore the technological issues involved with the removal of sulfur from lubricants and the development of low emission diesel engine oils was held in Scottsdale, Arizona, January 30 through February 1, 2000. It presented an overview of the current technology by means of panel discussions and technical presentations from industry, government, and academia.

  2. Non-Newtonian temperature and pressure effects of a lubricant slurry in a rotating hydrostatic step bearing

    SciTech Connect (OSTI)

    Peterson, J.; Finn, W.E.; Dareing, D.W. |

    1994-10-01

    The purpose of this research was to investigate the pressure and temperature effects of graphite powder lubricant when added to a Newtonian carrier fluid and applied in a rotating hydrostatic step bearing. Temperature and pressure profiles were determined both analytically and experimentally. The rheological behavior of the non-Newtonian lubricant was modeled using a power law model previously shown to approximate experimental data for this fluid. Ethylene glycol was used as the Newtonian lubricant, providing a check on the test apparatus and a base line for comparison with the non-Newtonian graphite slurry. Data revealed a temperature increase with bearing rotational speed for both fluids and compared favorably with the mathematical predictions. A significantly higher temperature rise was seen in the non- Newtonian lubricant due to the higher shear rates. The pressure profile was not directly dependent on bearing rotational speed in the mathematical model, but experimental data demonstrated a reduction in pressure at higher rotation speeds. This loss was greater for the non-Newtonian lubricant and attributed to temperature dependence of power law constants. It was concluded that the effects of operating speed and temperature on a non-Newtonian lubricant should be considered as well as their greater load-carrying capacity.

  3. Full Life Wind Turbine Gearbox Lubricating Fluids

    SciTech Connect (OSTI)

    Lutz, Glenn A.; Jungk, Manfred; Bryant, Jonathan J.; Lauer, Rebecca S.; Chobot, Anthony; Mayer, Tyler; Palmer, Shane; Kauffman, Robert E.

    2012-02-28

    Industrial gear box lubricants typically are hydrocarbon based mineral oils with considerable amounts of additives to overcome the lack of base fluid properties like wear protection, oxidation stability, load carrying capacity, low temperature solidification and drop of viscosity at higher temperatures. For today's wind turbine gearboxes, the requirements are more severe and synthetic hydrocarbon oils are used to improve on this, but all such hydrocarbon based lubricants require significant amounts of Extreme Pressure (EP) additives to meet performance requirements. Perfluoropolyether (PFPE) fluids provide load carrying capacity as an inherent property. During the course of the project with the main tasks of 'Establish a Benchmark', 'Lubricant Evaluation', 'Full Scale Gearbox Trial' and 'Economic Evaluation', the PAO Reference oil exhibited significant changes after laboratory gear testing, in service operation in the field and full scale gearbox trial. Four hydrocarbon base oils were selected for comparison in the benchmarking exercise and showed variation with respect to meeting the requirements for the laboratory micro-pitting tests, while the PFPE fluid exceeded the requirements even with the material taken after the full scale gear box trial. This is remarkable for a lubricant without EP additives. Laboratory bearing tests performed on the PFPE fluids before and after the full scale gear box trial showed the results met requirements for the industry standard. The PFPE fluid successfully completed the full scale gear box test program which included baseline and progressive staged load testing. The evaluation of gears showed no micro-pitting or objectionable wear. By the final stage, lubricant film thickness had been reduced to just 21% of its original value, this was by design and resulted in a lambda ratio of well below 1. This test design scenario of a low lambda ratio is a very undesirable lubrication condition for real world but creates the ability to test the lubricating fluids performance under the most extreme conditions. The PAO Reference oil also passed its testing without any noticeable deterioration of the gear surface. However the PAO Reference oil was replaced midway through the progressive loading, as the lubricant was burned in an attempt to raise the sump temperature to the same levels as for the PFPE. Both materials experienced a decrease of viscosity during their respective run times. The viscosity index decreased for the PAO there while there was a slight increase for the PFPE. FZG laboratory gear tests and measurements of the drive motor's current during the full scale gear box trial were made to characterize the relative efficiency between the PFPE fluid and the PAO Reference oil. In the FZG laboratory efficiency test, the PFPE fluids show much higher churning losses due to their higher viscosity and density. The analysis seems to show that the efficiency correlates better to dynamic viscosity than any other of the measured metrics such as film thickness. In load stages where the load, speed and temperature are similar, the PFPE fluid has a greater film thickness and theoretical gear protection, but requires a larger current for the drive motor than the PAO. However in load stages where the film thickness is the same, the PFPE fluid's reduced dynamic viscosity gives it a slight efficiency advantage relative to the PAO reference oil. Ultimately, many factors such as temperature, rotational speed, and fluid viscosity combine in a complex fashion to influence the results. However, the PFPE's much lower change of viscosity with respect to temperature, allows variations in designing an optimum viscosity to balance efficiency versus gear protection. Economic analysis was done using Cost of Energy calculations. The results vary from 5.3% for a 'Likely Case' to 16.8% for a 'Best Case' scenario as potential cost improvement by using PFPE as the gearbox lubricating fluid. It is important to note the largest portion of savings comes in Levelized Replacement Cost, which is dictated by the assumption on gearb

  4. Use of Lubricants in the NIF

    SciTech Connect (OSTI)

    Gourdin, W; Biltoft, P

    2006-07-06

    There are two principal concerns that govern the use of lubricants in NIF: (1) Airborne molecular contaminants (AMCs)--AMCs are known to seriously degrade the performance of sol-gel coated optics. AMCs are produced by the slow outgassing of residues (non-volatile residues or ''NVRs'') of high molecular weight compounds left on surfaces. Lubricants, particularly hydrocarbon lubricants, are a primary source of such NVRs. (2) Particulates--Particulates that accumulate on optical surfaces can cause permanent physical damage when exposed to high energy density laser light. Lubricant residues exposed to high energy density light will pyrolyze or decompose and produce carbon particulates. The NIF Approved Materials Database lists several lubricants that have been tested for use in NIF environments. Many of these lubricants were tested according to MELs 99-006 (oven outgassing test) or 99-007 (vacuum outgassing test). In these tests, the change in percent transmission of light through a sol-gel coated optic placed next to the sample under evaluation is used as the diagnostic. Samples that cause less than 0.1% change in optical transmission are deemed suitable for use inside beam enclosures. This testing, however, addresses only the concern associated with AMCs. To assess the issue of particle generation, a flashlamp or ''aerosol'' test is used. In this test a sample with residues is subjected to intense light from the main amplifier flashlamps. The number density of particles per unit volume is measure after each flash. A measurement of an average of fewer than 1000 particles >0.5{micro}m in diameter produced per square foot of exposed surface per flash for each of the last ten flashes in a series of 60 flashes of light is deemed to be acceptable for polymers. A measurement of an average of fewer than 100 particles >0.5{micro}m in diameter produced per square foot of exposed surface per flash for each of the last ten flashes in a series of 60 flashes of light is deemed to be acceptable for metals.

  5. Ionic Liquids with Ammonium Cations as Lubricants or Additives

    SciTech Connect (OSTI)

    Qu, Jun; Blau, Peter Julian; Dai, Sheng; Luo, Huimin; Truhan, Jr., John J

    2006-01-01

    Friction and wear are estimated to cost 6% of the US gross national product, or around $700 billion annually. A new class of more effective lubricants could lead to huge energy savings. Limited recent literature has suggested potential for using room-temperature ionic liquids as lubricants, however only a few out of millions (or more) of species have been evaluated. Recent ORNL work discovered a new category of ionic liquids with ammonium cations that have demonstrated promising lubricating properties as net lubricants or lubricant additives, particularly in lubricating difficult-to-lubricate metals like aluminum. More than 30% friction reduction has been observed on ammonium-based ionic liquids compared to conventional hydrocarbon oils. The inherent polarity of ionic liquids is believed to provide strong adhesion to contact surfaces and form a boundary lubricating film leading to friction and wear reductions. Other advantages of ionic liquids include (1) negligible volatility, (2) high thermal stability, (3) non-flammability, and (4) better intrinsic properties that eliminate the necessity of many expensive lubricant additives. With very flexible molecular structures, this new class of lubricants, particularly ammonium-based ionic liquids, can be tailored to fit a big variety of applications including but not limited to bearings, combustion engines, MEMS, and metal forming.

  6. Yieldably mounted lubricant control assemblies for piston rods

    SciTech Connect (OSTI)

    Meijer, R.J.; Ziph, B. Godett, T.M.

    1986-04-01

    This patent describes an engine having a housing comprising a cylinder within which a piston reciprocates and a piston rod extending from the piston through a bore which extends in the housing from the cylinder to a crankcase and a lubricant control assembly which is disposed within the bore in cooperative arrangement with the piston rod and functions to separate the cylinder from the crankcase while allowing the piston rod to reciprocate axially through a lubricant control portion of the lubricant control assembly which is in forceful contact around the piston rod, the improvement which comprises a compliant housing for mounting the lubricant control assembly on the engine housing. The compliant housing is operatively disposed between the engine housing and the lubricant control portion to allow the lubricant control portion to be radially displaced with respect to the bore and thereby comply with radial displacement of the reciprocating piston rod while maintaining substantially full effectiveness of the lubricant control portion acting on the piston rod. The lubricant control assembly consists of a tubular part, means attaching the tubular part to the compliant housing such that the tubular part can comply with radial displacement of the reciprocating piston rod, and force-applying means acting between the tubular part and the lubricant control portion for urging the lubricant control portion into forceful contact around the reciprocating piston rod.

  7. NOVEL LUBRICANT ADDITIVES - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search NOVEL LUBRICANT ADDITIVES Argonne National Laboratory Contact ANL About This Technology <em>Upper, the functionalized nanostructures mixed with poly-alpha-olefin (PAO)-4 reduce friction as test temperature is raised. Lower, Friction coefficient remains unchanged at all test temperatures with PAO4 alone.&nbsp; </em><br /> Upper, the functionalized nanostructures mixed with poly-alpha-olefin (PAO)-4 reduce friction as test temperature is

  8. Characterization of Spray Lubricants for the Die Casting Process

    SciTech Connect (OSTI)

    Sabau, Adrian S

    2008-01-01

    During the die casting process, lubricants are sprayed in order to cool the dies and facilitate the ejection of the casting. The cooling effects of the die lubricant were investigated using Thermogravimetric analysis (TGA), heat flux sensors (HFS), and infrared imaging. The evolution of the heat flux and pictures taken using a high speed infrared camera revealed that lubricant application was a transient process. The short time response of the HFS allows the monitoring and data acquisition of the surface temperature and heat flux without additional data processing. A similar set of experiments was performed with deionized water in order to assess the lubricant effect. The high heat flux obtained at 300 C was attributed to the wetting and absorbant properties of the lubricant. Pictures of the spray cone and lubricant flow on the die were also used to explain the heat flux evolution.

  9. MEMS Lubrication by In-Situ Tribochemical Reactions From the Vapor Phase.

    SciTech Connect (OSTI)

    Dugger, Michael T.; Asay, David B.; Kim, Seong H.

    2008-01-01

    Vapor Phase Lubrication (VPL) of silicon surfaces with pentanol has been demonstrated. Two potential show stoppers with respect to application of this approach to real MEMS devices have been investigated. Water vapor was found to reduce the effectiveness of VPL with alcohol for a given alcohol concentration, but the basic reaction mechanism observed in water-free environments is still active, and devices operated much longer in mixed alcohol and water vapor environments than with chemisorbed monolayer lubricants alone. Complex MEMS gear trains were successfully lubricated with alcohol vapors, resulting in a factor of 104 improvement in operating life without failure. Complex devices could be made to fail if operated at much higher frequencies than previously used, and there is some evidence that the observed failure is due to accumulation of reaction products at deeply buried interfaces. However, if hypothetical reaction mechanisms involving heated surfaces are valid, then the failures observed at high frequency may not be relevant to operation at normal frequencies. Therefore, this work demonstrates that VPL is a viable approach for complex MEMS devices in conventional packages. Further study of the VPL reaction mechanisms are recommended so that the vapor composition may be optimized for low friction and for different substrate materials with potential application to conventionally fabricated, metal alloy parts in weapons systems. Reaction kinetics should be studied to define effective lubrication regimes as a function of the partial pressure of the vapor phase constituent, interfacial shear rate, substrate composition, and temperature.

  10. Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet Vehicles

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy Reviews recent studies on potential for low-viscosity lubricants and low-friction surfaces and additives to reduce fuel consumption, and impact of such approaches on other critical lubricant metrics PDF icon deer11_fenske.pdf More Documents & Publications Lubricants Activities Vehicle Technologies Office Merit Review 2014: DOE/DOD Parasitic Energy Loss Collaboration DOE/DOD Parasitic Energy Loss

  11. Collaborative Lubricating Oil Study on Emissions (CLOSE Project) |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace046_lawson_2011_o.pdf More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies R&D Annual Progress Report

  12. Collaborative Lubricating Oil Study on Emissions (CLOSE) Project |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Extensive chemical and physical characterization performed on emissions from normal and high emitting light-, medium-, and heavy-duty vehicles to evaluate relative contributions of fuel and lubricating oil on tailpipe emissions. PDF icon deer08_lawson.pdf More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE Project) The FreedomCAR & Vehicle Technologies Health

  13. Correlations Between Metallic Lubricant Additive Species in the Ring Pack

    Broader source: Energy.gov (indexed) [DOE]

    and Ash Emissions and Their Dependence on Crankcase Oil Properties | Department of Energy watson.pdf More Documents & Publications Examining Effects of Lubricant Composition in Engine Component Systems in Pursuit of Enhanced Efficiency under Environmental Constraints Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter

  14. Auto/Steel Partnership: Hydroforming Materials and Lubricant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AutoSteel Partnership: Hydroforming Materials and Lubricant Lightweight Rear Chassis ... FY 2008 Progress Report for Lightweighting Materials - 5. Automotive Metals-Steel FY 2009 ...

  15. Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Acidity, Oxidation and Corrosion Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on Crankcase Oil Properties

  16. Correlations Between Metallic Lubricant Additive Species in the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dependence on Crankcase Oil Properties Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on Crankcase Oil Properties ...

  17. Impact of Biodiesel on Ash Emissions and Lubricant Properties...

    Broader source: Energy.gov (indexed) [DOE]

    Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Development of High Performance Heavy Duty Engine Oils Performance of Biofuels and Biofuel ...

  18. Natural Oils - The Next Generation of Diesel Engine Lubricants...

    Energy Savers [EERE]

    Oils - The Next Generation of Diesel Engine Lubricants? JOE PEREZ 1 & SHAWN WHITACRE 2 1 The ... TEST PURPOSE COMMENT BOSCH INJECTOR HIGH TEMPERATURE - HIGH SHEAR BOSCH INJECTOR SHEAR ...

  19. Characteristics and Effects of Lubricant Additive Chemistry and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Service Life and Vehicle Fuel Economy Characteristics and Effects of Lubricant Additive Chemistry and Exhaust Conditions on Diesel Particulate Filter Service Life and Vehicle ...

  20. Examining Effects of Lubricant Composition in Engine Component...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (LFEEE) in Modern Internal Combustion Engines Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report Engine Friction Reduction Through ...

  1. Reducing Lubricant Ash Impact on Exhaust Aftertreatment with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Future Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly

  2. 2011 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1amr05.pdf More Documents & Publications 2010 DOE EERE Vehicle Technologies Program Merit Review - Fuels Technologies 2011 Annual Merit Review Results Report - Fuels & Lubricants...

  3. Large-Scale Manufacturing of Nanoparticulate-Based Lubrication Additives

    SciTech Connect (OSTI)

    2009-06-01

    This factsheet describes a research project whose goal is to design, develop, manufacture, and scale up boron-based nanoparticulate lubrication additives.

  4. 2011 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2amr05.pdf More Documents & Publications 2011 Annual Merit Review Results Report - Fuels & Lubricants 2010 DOE EERE Vehicle Technologies Program Merit Review - Fuels Technologies...

  5. High-Performance Renewable Base Oils for Industrial Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    When used in industrial lubricants of all types, Biosynthetic's oils achieved superior performance in many critical performance areas, including pour point, viscosity index, flash ...

  6. The Impact of Lubricant Formulation on the Performance of NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation on the Performance of NOx Adsorber Catalysts The Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts PDF icon 2005deerwhitacre.pdf More ...

  7. A Novel Lubricant Formulation Strategy for 2% Fuel Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    demonstration of temporary shear thinning On Track 3. Nanoparticles in Lubricants and Characterization GoNo-go Decision: no severe wear Completion 4. Model-Assisted Optimal...

  8. Vehicle Technologies Office Merit Review 2015: A Novel Lubricant...

    Office of Environmental Management (EM)

    through Surface Modification (Agreement ID:23284) Project ID:18518 Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together?...

  9. Natural Oils - The Next Generation of Diesel Engine Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Effect of Exhaust Gas Recirculation (EGR) on Diesel Engine Oil ...

  10. The role of polymer formation during vapor phase lubrication...

    Office of Scientific and Technical Information (OSTI)

    The lubrication of silicon surfaces with alcohol vapors has recently been demonstrated. ... The parent alcohol molecule pentanol, has molecular weight of 88amu, suggesting that ...

  11. Heat transfer of R-134a in single-tube spray evaporation including lubricant effects and enhanced surface results

    SciTech Connect (OSTI)

    Moeykens, S.A.; Huebsch, W.W.; Pate, M.B.

    1995-08-01

    Single-tube spray evaporation experimental tests were conducted in order to evaluate the average wall heat transfer coefficients for seven different commercially available tubes. Liquid film supply rates were held constant in order to evaluate the effects of the enhancement on shell-side heat transfer under similar conditions. Because the spray evaporation phenomenon is so different from pool boiling, both condensation-type and evaporation-type enhanced surfaces were evaluated. A comparison of the results for all of the tubes showed that the enhanced condensation surfaces performed better than the enhanced boiling surfaces. In addition, the 26-fpi surface tested marginally better than the 40-fpi surface. Small concentrations of a polyol-ester lubricant cause a foaming effect that increases the heat transfer performance. This tendency was seen with both 32-cs and 68-cs polyol-ester oils. The 68-cs lubricant was tested at concentrations of 0.0, 0.5, 1.0, 3.0, and 5.0 with the W-40 fpi and Tu-Cii surfaces. Results with this lubricant show the performance continues to increase through the 3% concentration for most of the heat flux range tested At the upper end of the range tested, the 1.0% mass fraction yielded the best performance. The 32-cs lubricant generated trends similar to those of the 68-cs lubricant. Lubricant concentrations of 1.0%, 2.0%, and 3.0% were evaluated with plain, W-40 fpi, and Tu-Cii surfaces. The 2.0% concentration, not the 1.0 %, generated the best performance at the highest heat flux tested. This difference must be attributed to the difference in the lubricant viscosity.

  12. Ionic Liquids as Novel Lubricants and Additives | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_qu.pdf More Documents & Publications Ionic Liquids as Novel Engine Lubricants or Lubricant Additives

  13. FY 2012 Progress Report for Fuel & Lubricant Technologies

    SciTech Connect (OSTI)

    Stork, Kevin

    2013-06-28

    Annual progress report of the Fuel & Lubricant Technologies subprogram supporting fuels and lubricants research and development (R&D) to provide vehicle users with cost-competitive options that enable high fuel economy with low emissions, and contribute to petroleum displacement.

  14. Dry film lubricant for difficult drawing applications of galvanized steels

    SciTech Connect (OSTI)

    Wakano, Shigeru; Sakane, Tadashi; Hirose, Yozou . Iron and Steel Research Lab.); Matsuda, Naomichi; Onodera, Show . Oleo Chemicals Research Lab.)

    1993-09-01

    Press formability of metals sheets is considered to depend on surface lubricity, press forming condition and mechanical properties of the metal sheets. In Zn and Zn-alloy plated steel sheets with heavy coatings, surface lubricity is the most important property. This is because the low melting temperature and low hardness of the plated layer occasionally cause microscopic galling through deformation at the beads of dies which may, consequently, result in sheet breakage. Press formability of Zn and Zn-alloy plated steel sheets with heavy coating weight has been improved by the use of a high viscosity lubricant oil and a Fe-Zn alloy flash-plating on galvannealed steel. However, the use of high viscosity lubricant oils created problems with oil staining and removal before painting. An alloy flash plating results in appreciably higher production costs. This article describes the characteristics of a thin film dry lubricant, Super S-coat, as a new countermeasure, which will overcome these problems.

  15. Tribocharging phenomena in hard disk amorphous carbon coatings with and without perfluoropolyether lubricants

    SciTech Connect (OSTI)

    van den Oetelaar, Ronald J.A.; Xu, Lei; Ogletree, D. Frank; Salmeron, Miquel; Tang, Hung; Gui, Jing

    2000-08-01

    Scanning polarization force microscopy was used to study changes in surface potential (tribocharging) caused by the contact between a tungsten carbide tip and the amorphous carbon coating of a hard disk,both when bare and when covered with Zdol-TX lubricant. The surface potential change produced by tip contact decays with time at a rate that is strongly dependent on lubricant coverage, and on the presence of oxygen and water vapor in the environment. Two different charging mechanisms are proposed. One involves chemical modification of the surface by removal of oxygen bound to the surface. This gives rise to a potential change that decays with time. Another mechanism involves trapping of charge in states within the energy gap of the insulating carbon film. The potential change due to this trapped charge does not decay over periods much greater than 1 hour.

  16. Compressible pressure compensator within closed lubricant volume of an earth boring apparatus

    SciTech Connect (OSTI)

    Saxman, W. C.; Parker, L. J.

    1985-04-09

    A compressible pressure compensating member is disposed within a sealed lubricant volume enclosing a bearing and seal system of an earth boring apparatus. Lubricant is maintained within the volume by metal face seals so that both the bearing and the seal structure are lubricated thereby. As the lubricant expands, due to thermal expansion under use, the increased pressure is accommodated by compression of the compressible member so that no lubricant is expelled through the seals. When the lubricant cools and contracts, the compensator expands to maintain the lubricant volume at the initially filled level.

  17. Renewable Fuels and Lubricants Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-08-01

    This fact sheet describes the Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve vehicle efficiency and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such as biodiesel and synthetic diesel derived from biomass. The ReFUEL Laboratory features a chassis dynamometer for vehicle performance and emissions research, two engine dynamometer test cells for advanced fuels research, and precise emissions analysis equipment. As a complement to these capabilities, detailed studies of fuel properties, with a focus on ignition quality, are performed at NREL's Fuel Chemistry Laboratory.

  18. CVD method of forming self-lubricating composites

    DOE Patents [OSTI]

    Besmann, T.M.; Blau, P.J.; Lee, W.Y.; Bae, Y.W.

    1998-12-01

    An article having a multiphase composite lubricant coating of a hard refractory matrix phase of titanium nitride dispersed with particles of a solid lubricating phase of molybdenum disulfide is prepared by heating the article to temperatures between 350 and 850 C in a reaction vessel at a reduced pressure and passing a gaseous mixture of Ti((CH{sub 3}){sub 2}N){sub 4}, MoF{sub 6}, H{sub 2}S and NH{sub 3} over the heated article forming a multiphase composite lubricant coating on the article. 1 fig.

  19. CVD method of forming self-lubricating composites

    DOE Patents [OSTI]

    Besmann, Theodore M. (Oak Ridge, TN); Blau, Peter J. (Oak Ridge, TN); Lee, Woo Y. (Knoxville, TN); Bae, Yong W. (Oak Ridge, TN)

    1998-01-01

    An article having a multiphase composite lubricant coating of a hard refractory matrix phase of titanium nitride dispersed with particles of a solid lubricating phase of molybdenum disulfide is prepared by heating the article to temperatures between 350.degree. and 850.degree. C. in a reaction vessel at a reduced pressure and passing a gaseous mixture of Ti((CH.sub.3).sub.2 N).sub.4, MoF.sub.6, H.sub.2 S and NH.sub.3 over the heated article forming a multiphase composite lubricant coating on the article.

  20. Effects of star-shape poly(alkyl methacrylate) arm uniformity on lubricant properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Robinson, Joshua W.; Qu, Jun; Erck, Robert; Cosimbescu, Lelia; Zhou, Yan

    2016-03-29

    Star-shaped poly(alkyl methacrylate)s (PAMAs) were prepared and blended into an additive-free engine oil to assess the structure property relationship between macromolecular structure and lubricant performance. These additives were designed with a comparable number of repeating units per arm and the number of arms was varied between 3 and 6. Well-defined star-shaped PAMAs were synthesized by atom transfer radical polymerization (ATRP) via a core-first strategy from multi-functional headgroups. Observations of the polymer-oil blends suggest that stars with less than four arms are favorable as a viscosity index improver (VII), and molecular weight dominates viscosity-related effects over other structural features. Star-shaped PAMAs,more » as oil additives, effectively reduce the friction coefficient in both mixed and boundary lubrication regime. Several analogs outperformed commercial VIIs in both viscosity and friction performance. Furthermore, increased wear rates were observed for these star-shaped PAMAs in the boundary lubrication regime suggesting pressure-sensitive conformations may exist.« less

  1. Ionic Liquids as Multifunctional Ashless Additives for Engine Lubrication

    Broader source: Energy.gov [DOE]

    A group of oil-miscible ionic liquids has been developed by an ORNL-GM team as candidate lubricant additives with promising physical/chemical properties and potential multiple functionalities.

  2. Ionic Liquids as Multi-Functional Lubricant Additives to Enhance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Ionic Liquids as Novel Engine ...

  3. Renewable Fuels and Lubricants (ReFUEL) Laboratory

    SciTech Connect (OSTI)

    Not Available

    2004-08-01

    Fact sheet describing NREL's Renewable Fuels and Lubricants Laboratory (ReFUEL). ReFUEL is a world-class research and testing facility dedicated to future fuels and advanced heavy-duty vehicle research, located in Denver, Colorado.

  4. Ionic Liquids as Lubricants or Additives - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Ionic Liquids as Lubricants or Additives Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryNew ionic liquids invented at ORNL show great promise as lubricants for aluminum and steel in combustion engines, bearings, and microelectromechanical systems (MEMS). The ammonium-based ionic liquids are strongly adsorbant on contact surfaces, leading to a more than 30% friction

  5. Mechanistic aspects of vapor phase lubrication of silicon. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Mechanistic aspects of vapor phase lubrication of silicon. Citation Details In-Document Search Title: Mechanistic aspects of vapor phase lubrication of silicon. No abstract prepared. Authors: Dugger, Michael Thomas ; Dirk, Shawn M. ; Ohlhausen, James Anthony Publication Date: 2010-10-01 OSTI Identifier: 1028381 Report Number(s): SAND2010-7362C TRN: US201122%%249 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for

  6. NREL: Transportation Research - Renewable Fuels and Lubricants Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Renewable Fuels and Lubricants Laboratory Photo of a heavy-duty truck being driven on a chassis dynamometer. The heavy-duty chassis dynamometer at the ReFUEL Laboratory simulates on-road driving in a controlled laboratory setting. Photo by Dennis Schroeder, NREL NREL's Renewable Fuels and Lubricants (ReFUEL) Laboratory is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development focuses on overcoming barriers to the increased use of renewable

  7. Experimental and Theoretical Investigation of Lubricant and Additive

    Broader source: Energy.gov (indexed) [DOE]

    Effects on Engine Friction | Department of Energy Combining data from motored engine friction, a theoretical engine model, a line friction contact rig, and a fired engine can provide better insight to lube oil and additive performance. PDF icon p-02_rohr.pdf More Documents & Publications Validation of a Small Engine Based Procedure for Studying Performance of Engine Lube Oils, Ionic Liquids as Lubricants and/or Lubricant Additives, Opportunities for Engine Friction Reduction and Durable

  8. Lubricant wear particle analysis by filter patch extraction

    SciTech Connect (OSTI)

    Smart, C.L.

    1996-07-01

    Lubricating Oil Analysis (LOA) has become an important part of a comprehensive Reliability Centered Maintenance (RCM) program. However, knowing the condition of the lubricant alone does not provide a complete description of equipment reliability. Condition monitoring for equipment can be accomplished through Wear Particle Analysis (WPA). This usually involves separating suspended materials and wear products from the lubricant by magnetic (ferrographic) means. This paper will present a simple, low-cost, alternate method of particle acquisition called Filter Patch Extraction (FPE). This method removes solids, regardless of their composition, from the lubricant by vacuum filtration and deposits them onto a filter for microscopic examination similar to that of analytical ferrography. A large filter pore size retains suspended materials and permits rapid filtration of large volumes of lubricant thereby increasing the accuracy of the wear and cleanliness profile that can be established for a given machine. Qualitative trending of equipment wear and lubricant system cleanliness are easily performed with FPE. Equipment condition is determined by then characterizing the metal particles which are recovered. Examined filters are easily archived in filter holders for future reference. Equipment for FPE is inexpensive and readily available. The technique is field-portable, allowing WPA to be performed on-site, eliminating delays with remote laboratories while building customer participation and support. There are numerous advantages for using FPE in a machine condition monitoring program.

  9. Effects of Water in Synthetic Lubricant Systems and Clathrate Formation: A Literature Search and Review

    SciTech Connect (OSTI)

    Rohatgi, Ngoc Dung T.

    2001-08-08

    An extensive literature search and a confidential survey were critically analyzed to determine the effects of water on the stability of hydrofluorocarbon/synthetic lubricant systems and to identify key areas requiring further investigation. Following are highlights from the analysis: Clathrate hydrates are solid solutions formed when water molecules are linked through hydrogen bonding creating cavities that can enclose various guest molecules from hydrate formers, such as hydrofluorocarbons R-32, R-125, R-134a, R-407C and R-410A. The four methods for preventing clathrate formation were drying the gas, heating it, reducing its pressure, or using inhibitors. The hydrolysis of polyolester lubricants was mostly acid-catalyzed and its reaction rate constant typically followed the Arrhenius equation of an activated process. Hydrolytic stability improved with hindered molecular structures, and with the presence of acid catcher additives and desiccants. Water vapor can effect the adsorption of long-chain fatty acids and the chemistry of formation of protective oxide film. However, these effects on lubrication can be either positive or negative. Fifty to sixty percent of the moisture injected into an air-conditioning system remained in the refrigerant and the rest mixed with the compressor oil. In an automotive air-conditioning system using R-134a, ice would form at 0 C evaporating temperature when the water content in the vapor refrigerant on the low-pressure side was more than 350 ppm. Moisture would cause the embrittlement of polyethylene terephthalate and the hydrolysis of polyesters, but would reduce the effect of amine additives on fluoroelastomer rubbers. The reactions of water with refrigerants and lubricants would cause formicary and large-pit corrosion in copper tubes, as well as copper plating and sludge formation. Moreover, blockage of capillary tubes increased rapidly in the presence of water. Twenty-four companies responded to the survey. From the responses, the water concentrations specified and expected for different refrigerant/lubricant systems varied depending on the products, their capacities and applications, and also on the companies. Among the problems associated with high moisture level, lubricant breakdown was of greatest concern, followed by acid formation, compressor failure and expansion valve sticking. The following research topics are suggested: 1. The air-conditioning and refrigeration industry needs to measure and record the water content and total acid number of the lubricant of newly installed systems as well as operating systems that are shutdown for service or repair. The reason for the shutdown needs to be documented. A database can then be established to correlate water content with type and cause of breakdown. 2. Detailed studies on the distribution of water in refrigeration and air-conditioning systems should be conducted to pinpoint problem areas associated with free water. 3. Research is needed to validate the current theories and mechanisms of formicary corrosion. Corrosion inhibitors need to be developed. 4. The conditions for clathrate formation and decomposition of other alternative refrigerants, such as R-23, R-41, R-116, R-125, R-143a, R-404A and R-507C, and water should be determined to avoid possible problems associated with tube plugging. The mechanism by which water facilitates or hinders lubrication needs to be studied.

  10. Anti-Wear Performance and Mechanism of an Oil-Miscible Ionic Liquid as a Lubricant Additive

    SciTech Connect (OSTI)

    Qu, Jun; Bansal, Dinesh G; Yu, Bo; Howe, Jane Y; Luo, Huimin; Dai, Sheng; Li, Huaqing; Blau, Peter Julian; Bunting, Bruce G; Mordukhovich, Gregory; Smolenski, Donald

    2012-01-01

    An ionic liquid (IL) trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate has been investigated as a potential anti-wear lubricant additive. Unlike most other ILs that have very low solubility in non-polar fluids, this IL is fully miscible with various hydrocarbon oils. In addition, it is thermally stable up to 347 oC, showed no corrosive attack to cast iron in ambient environment, and has excellent wettability on solid surfaces (e.g., contact angle on cast iron <8o). Most importantly, this phosphonium-based IL has demonstrated effective anti-scuffing and anti-wear characteristics when blended with lubricating oils. For example, a 5 wt.% addition into a synthetic base oil eliminated the scuffing failure experienced by the neat oil and, as a result, reduced the friction coefficient by 60% and the wear rate by three orders of magnitude. A synergistic effect on wear protection was observed with the current anti-wear additive when added into a fully-formulated engine oil. Nanostructure examination and composition analysis revealed a tribo-boundary film and subsurface plastic deformation zone for the metallic surface lubricated by the IL-containing lubricants. This protective boundary film is believed to be responsible for the IL s anti-scuffing and anti-wear functionality.

  11. Effect of lubricant on spray evaporation heat transfer performance of R-134a and R-22 in tube bundles

    SciTech Connect (OSTI)

    Moeykens, S.A.; Pate, M.B.

    1996-11-01

    This study evaluates the effects of lubricant on spray evaporation heat transfer performance. Tests were conducted with refrigerant R-134a and triangular-pitch tube bundles made from enhanced-condensation, enhanced-boiling, low-finned, and plain-surface tubes. A 340-SUS polyol-ester (POE) oil was used for the R-134a testing because this lubricant is being integrated into industry for use with this refrigerant. Refrigerant was sprayed onto the tube bundles with low-pressure-drop, wide-angle nozzles located directly above the bundle. Collector testing was conducted with both R-134a and R-22 to determine the percentage of refrigerant contacting the tue bundle. It was found that small concentrations of the polyol-ester lubricant yielded significant improvement in the heat transfer performance of R-134a. The shell-side heat transfer coefficient was more dependent on lubricant concentration than on film-feed supply rate within the range of the respective parameters evaluated in this study. As expected, pure R-22 results show higher heat transfer coefficients than those obtained with pure R-134a at the same saturation temperature of 2.0 C (35.6 F).

  12. Current issues in natural gas lubrication

    SciTech Connect (OSTI)

    Reber, J.

    1997-10-01

    Because of the ability of natural gas to burn completely relatively easily, supplying excess oxygen to promote complete reactions is a viable alternative to catalysts. Hence, lean burn technology has a natural fit for this industry. Lube oil is not adversely affected by lean burn operation. There is a slight tendency to cause more oil nitration than oxidation, but the real difference is not significant. Operators may notice somewhat more varnish (caramel color) and less sludge (black) as a result. Because the fuel is burned more completely, there is less problem with fuel-derived oil contamination. Also because of the excess air in the combustion chamber, overall cylinder temperature is lower, causing less stress on the oil. Oil life is generally lengthened. One common misconception that lean burn engines require different lubricants may stem from a change at Waukesha Engine Division--Dresser Industries. Waukesha has changed its lube oil requirements for VHP 3521, 5115, 7042, 9390 GL turbocharged and lean burn model engines. The lube oil specification for these engines is 1% to 1.7% ash with the same 0.10% zinc maximum. This change is not because of the lean burn nature of these engines, rather it is because of drastically decreased lube oil consumption. With less oil consumption, less ash is carried to the critical exhaust valve seat area to prevent valve recession.

  13. Method to improve lubricity of low-sulfur diesel and gasoline fuels

    DOE Patents [OSTI]

    Erdemir, Ali

    2004-08-31

    A method for providing lubricity in fuels and lubricants includes adding a boron compound to a fuel or lubricant to provide a boron-containing fuel or lubricant. The fuel or lubricant may contain a boron compound at a concentration between about 30 ppm and about 3,000 ppm and a sulfur concentration of less than about 500 ppm. A method of powering an engine to minimize wear, by burning a fuel containing boron compounds. The boron compounds include compound that provide boric acid and/or BO.sub.3 ions or monomers to the fuel or lubricant.

  14. CRC handbook of lubrication. Theory and practice of tribology: Volume II: Theory and design

    SciTech Connect (OSTI)

    Booser, E.R.

    1984-01-01

    This handbook covers the general area of lubrication and tribology in all its facets: friction, wear lubricants (liquid, solid, and gas), greases, lubrication principles, applications to various mechanisms, design principles of devices incorporating lubrication, maintenance, lubrication scheduling, and standardized tests; as well as environmental problems and conservation. The information contained in these two volumes will aid in achieving effective lubrication for control of friction and wear, and is another step to improve understanding of the complex factors involved in tribology. Both metric and English units are provided throughout both volumes.

  15. Performance of MOV Stem Lubricants at Elevated Temperatures

    SciTech Connect (OSTI)

    DeWall, Kevin George; Nitzel, Michael Everett; Watkins, John Clifford

    2001-07-01

    This paper documents the results of recent tests sponsored by the U. S. Nuclear Regulatory Commission (NRC) and performed by the Idaho National Engineering and Environmental Laboratory (INEEL). These tests address the effectiveness of the lubricant used on the threaded portion of the valve stem, where the stem nut turns on the stem. Recent testing indicates that an elevated temperature environment can lead to significant increases in the friction coefficient at the stem/stem-nut interface. Most valve actuator qualification tests are performed at room temperature. Similarly, in-service tests are run at ambient plant temperatures, usually 70 to 100F. Since design conditions can lead to valve operating temperatures in the 200 to 300F range, it is important to know whether a temperature-induced increase in friction at the stem/stem-nut interface will prevent the required operation of critical valves. Lubricant aging is another phenomenon that might have deleterious effects on the thrust output of a valve actuator. Laboratory experience and field experience both indicate that after long periods in elevated temperature environments, the lubricants may lose their lubrication qualities. The scope of the current test program includes testing of five different lubricants on four different valve stems. Pending completion of the testing, results of the tests conducted using two of the four stems are discussed. The test series included collection of baseline data at room temperature, single step temperature tests where the temperature of the test setup was elevated directly to 250F, and step testing where the temperature was elevated in steps to 130, 190, and 250F, then returned to 70F. All greases tested showed evidence of physical change after elevated temperature tests. Except for one particular lubricant, all of the greases tested showed increased coefficients of friction at elevated temperatures. Numerous other preliminary conclusions are presented. Recommendations for future research in the area of aged valve stem lubricant performance at elevated temperatures are also presented.

  16. Rotary seal with enhanced lubrication and contaminant flushing

    DOE Patents [OSTI]

    Dietle, Lannie L.

    2000-01-01

    A resilient, ring shaped interference-type hydrodynamic rotary seal having waves on the lubricant side which provide increased film thickness and flushing action by creating contact pressure induced angulated restrictions formed by abrupt restrictive diverters. The angulated restrictions are defined by projecting ridges, corners at the trailing edge of the waves, or simply by use of a converging shape at the trailing edge of the waves which is more abrupt than the gently converging hydrodynamic inlet shape at the leading edge of the waves. The abrupt restrictive diverter performs two functions; a restricting function and a diverting function. The angulated restrictions cause a local film thickness restriction which produces a damming effect preventing a portion of the lubricant from leaking out of the dynamic sealing interface at the trailing edge of the wave, and results in a much thicker lubricant film thickness under the waves. This contributes to more film thickness in the remainder of the dynamic sealing interface toward the environment because film thickness tends to decay gradually rather than abruptly due to the relative stiffness of the seal material. Because of the angle of the abrupt restrictive diverter relative to the relative rotation direction, in conjunction with the restriction or damming effect, a strong diverting action is produced which pumps lubricant across the dynamic sealing interface toward the environment. The lubricant diversion is caused by the component of the rotational velocity tangent to the abrupt restrictive diverter. The component of rotational velocity normal to the abrupt restrictive diverter causes a portion of the lubricant film to be pumped past the abrupt restrictive diverter, thereby assuring adequate lubrication thereof.

  17. Development of a bench scale test to evaluate lubricants for use with methanol-fueled engines

    SciTech Connect (OSTI)

    Shah, R.; Klaus, E.; Duda, J.L.

    1996-10-01

    In methanol-fueled diesel engines, the crankcase lubricant is used to lubricate both the engine and the fuel injector system. Crankcase lubricants including some designed for methanol-fueled engines are not completely compatible with the methanol fuel. In order to test the effect of methanol extraction on diesel engine lubricant performance, two extraction protocols were developed: one to simulate the fuel injector (1000 parts of methanol to one part of lubricant) and the other to simulate an extreme case of methanol contamination in the crank-case (one part of methanol to five parts of lubricant). The extracted samples of the lubricant were stripped to remove the methanol. The samples were then evaluated for changes in oxidative stability and lubricity. 12 refs., 3 figs., 8 tabs.

  18. Lubricant additives, friend or foe: What the equipment design engineer needs to know

    SciTech Connect (OSTI)

    Nixon, H.P.; Zantopulos, H.

    1995-10-01

    Lubricant formulations and lubricant additives have been slanted heavily toward protecting gear concentrated contacts from galling and wear. Much of the performance differentiation of these lubricants has been dependent on highly accelerated standardized laboratory testing. The area of contact fatigue has played a less important role in shaping lubricant formulations, but new test results for several commercially available gear lubricants suggest this area warrants a closer examination. The performance effects of fully and partially additized lubricants were studied using standard bearing industry rolling contact fatigue and wear testing procedures for tapered roller bearings. These test results indicate significant detrimental effects to wear, and fatigue life performance can occur with some additized lubricant formulations. Observations of functional surfaces, before and after testing, are made and examined for several lubricant formulations. The implications of these findings for equipment applications are discussed, and suggestions are made for ways to minimize or avoid potential detrimental performance effects. 10 refs., 11 figs., 3 tabs.

  19. Lubricant-Friendly, Superhard and Low-Friction Coatings by Design...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lubricant-Friendly, Superhard and Low-Friction Coatings by Design Lubricant-Friendly, Superhard and Low-Friction Coatings by Design Superhard and low-friction coatings and surface ...

  20. Lubricating bacteria model for the growth of bacterial colonies exposed to ultraviolet radiation

    SciTech Connect (OSTI)

    Zhang Shengli; Zhang Lei; Liang Run; Zhang Erhu; Liu Yachao; Zhao Shumin

    2005-11-01

    In this paper, we study the morphological transition of bacterial colonies exposed to ultraviolet radiation by modifying the bacteria model proposed by Delprato et al. Our model considers four factors: the lubricant fluid generated by bacterial colonies, a chemotaxis initiated by the ultraviolet radiation, the intensity of the ultraviolet radiation, and the bacteria's two-stage destruction rate with given radiation intensities. Using this modified model, we simulate the ringlike pattern formation of the bacterial colony exposed to uniform ultraviolet radiation. The following is shown. (1) Without the UV radiation the colony forms a disklike pattern and reaches a constant front velocity. (2) After the radiation is switched on, the bacterial population migrates to the edge of the colony and forms a ringlike pattern. As the intensity of the UV radiation is increased the ring forms faster and the outer velocity of the colony decreases. (3) For higher radiation intensities the total population decreases, while for lower intensities the total population increases initially at a small rate and then decreases. (4) After the UV radiation is switched off, the bacterial population grows both outward as well as into the inner region, and the colony's outer front velocity recovers to a constant value. All these results agree well with the experimental observations [Phys. Rev. Lett. 87, 158102 (2001)]. Along with the chemotaxis, we find that lubricant fluid and the two-stage destruction rate are critical to the dynamics of the growth of the bacterial colony when exposed to UV radiation, and these were not previously considered.

  1. Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies R&D

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Progress Report | Department of Energy Fuel and Lubricant Technologies R&D Annual Progress Report Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies R&D Annual Progress Report The Fuel & Lubricant Technologies subprogram supports fuels and lubricants research and development (R&D) to provide vehicle users with cost-competitive options that enable high fuel economy with low emissions, and contribute to petroleum displacement. PDF icon

  2. Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies R&D

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Progress Report | Department of Energy Fuel and Lubricant Technologies R&D Annual Progress Report Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies R&D Annual Progress Report This report describes the progress made on the research and development projects funded by the Fuel and Lubricants subprogram in the Vehicle Technologies Office, as described on the Lubricants and Alternative Fuels pages. Past year's reports are listed on the Annual Progress Reports page.

  3. Few-Layer Graphene as a Dry Lubricant | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Few-Layer Graphene as a Dry Lubricant Technology available for licensing: Graphene layers act as a two-dimensional nanomaterial and form a conformal protective coating on sliding contact interfaces. These factors facilitate shear and slow down oxidation (tribo-corrosion), thus drastically reduce wear. Functions as a dry lubricant, reducing wear four-fold and friction six-fold Cost-competitive with oil-based lubricants; may replace oil-based lubricants in some applications PDF icon

  4. Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and

    Broader source: Energy.gov (indexed) [DOE]

    Corrosion | Department of Energy In-cylinder fuel injection to produce rich exhaust for regeneration of lean NOx trap catalyst and diesel particulate filter results in substantial fuel dilution of lubricating oil cause changes of lubricating oil properties and scuffing of engine components. PDF icon deer08_watson.pdf More Documents & Publications Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear Reducing Lubricant Ash Impact on Exhaust

  5. Lubricants and greases: Properties and evaluation. (Latest citations from Fluidex). Published Search

    SciTech Connect (OSTI)

    1998-02-01

    The bibliography contains citations concerning a variety of lubricants, including synthetic oils and greases. Topics include properties characterization, additives, rheological studies, and uses. Bearing and gear lubricants are discussed, and lubricant testing methods are described. Some attention is given to specific applications in industry. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  6. Lubricants and greases: Properties and evaluation. (Latest citations from FLUIDEX data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The bibliography contains citations concerning a variety of lubricants, including synthetic oils and greases. Topics include properties characterization, additives, rheological studies, and uses. Bearing and sea lubricants are discussed, and lubricant testing methods are described. Some attention is given to specific applications in industry. (Contains 250 citations and includes a subject term index and title list.)

  7. Sliding contacts: Wear and lubrication. (Latest citations from the NTIS data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    The bibliography contains citations concerning friction wear and the behavior and properties of sliding and sliding-roll contact lubricants. Topics include lubrication mechanism descriptions, failure reduction of mechanical components for specific contacts, and lubricant performance evaluations. Both electrical and mechanical contact applications are presented. (Contains 250 citations and includes a subject term index and title list.)

  8. Frictional anisotropy under boundary lubrication: effect of surface texture.

    SciTech Connect (OSTI)

    Ajayi, O. O.; Erck, R. A.; Lorenzo-Martin, C.; Fenske, G. R.; Energy Systems

    2009-06-15

    The friction coefficient was measured under boundary lubrication with a ball-on-flat contact configuration in unidirectional sliding. The ball was smooth and hardened 52100 steel. Discs were made from case-carburized and hardened 4620, annealed 1080, and 1018 steels with directionally ground surfaces. A synthetic lubricant of stock polyalphaolefin was used for testing. During testing with each material, a frictional spike was observed whenever the ball slid parallel to the grinding ridge on the disc surface. The average friction coefficient for all tests was about 0.1, which is typical for the boundary lubrication regime. The magnitude of the frictional spikes, which reached as high as a friction coefficient of 0.25, and their persistence depended on the hardness of the disc surface. On the basis of elastohydrodynamic theory, coupled with the observation of severe plastic deformation on the ridges parallel to the sliding direction, the frictional spike could be due to localized plastic deformation on the disc surface at locations of minimal thickness for the lubricant fluid film. This hypothesis was further supported by lack of frictional spikes in tests using discs coated with a thin film of diamond-like carbon, in which plastic deformation is minimal.

  9. Fuel, lubricant and additive effects in combustion chamber deposit formation

    SciTech Connect (OSTI)

    Kelemen, S.R.; Homan, H.S.

    1996-10-01

    CCD causes octane requirement increase (ORI) and can potentially contributes to exhaust emissions and combustion chamber deposit interference (CCDI). Experiments were conducted to identify the separate fuel, lubricant and additive contributions to the amount and composition of CCD. CCD originates from multiple sources. Gasoline hydrocarbon components, gasoline additives, engine lubricant, and atmospheric nitrogen contribute to CCD in different ways. With some fuels the engine lubricant is the main contributor to CCD and this is shown by the high ash level in the CCD. For other fuels CCD is predominantly organic. Significant amounts of nitrogen were found in the CCD even when the fuel and lubricant were nitrogen free. The pyrolysis reactivity of different CCDs was studied to gain an understanding about the transformations that potentially happen over longer times and lower temperatures on the combustion chamber walls. In all cases during mild pyrolysis (375{degrees}C) there was a substantial increase in the level of aromatic carbon and a decrease in the level of organic oxygen. The largest increases in the amount of aromatic carbon occurred for CCDs that were the least aromatic.

  10. Use of Textured Surfaces to Mitigate Sliding Friction and Wear of Lubricated and Non-Lubricated Contacts

    SciTech Connect (OSTI)

    Blau, Peter Julian

    2012-03-01

    If properly employed, the placement of three-dimensional feature patterns, also referred to as textures, on relatively-moving, load-bearing surfaces can be beneficial to their friction and wear characteristics. For example, geometric patterns can function as lubricant supply channels or depressions in which to trap debris. They can also alter lubricant flow in a manner that produces thicker load-bearing films locally. Considering the area occupied by solid areas and spaces, textures also change the load distribution on surfaces. At least ten different attributes of textures can be specified, and their combinations offer wide latitude in surface engineering. By employing directional machining and grinding procedures, texturing has been used on bearings and seals for well over a half century, and the size scales of texturing vary widely. This report summarizes past work on the texturing of load-bearing surfaces, including past research on laser surface dimpling of ceramics done at ORNL. Textured surfaces generally show most pronounced effects when they are used in conformal or nearly conformal contacts, like that in face seals. Combining textures with other forms of surface modification and lubrication methods can offer additional benefits in surface engineering for tribology. As the literature and past work at ORNL shows, texturing does not always provide benefits. Rather, the selected pattern and arrangement of features must be matched to characteristics of the proposed application, bearing materials, and lubricants.

  11. Study of lubricant circulation in HVAC systems. Volume 1: Description of technical effort and results; Final technical report, March 1995--April 1996

    SciTech Connect (OSTI)

    Biancardi, F.R.; Michels, H.H.; Sienel, T.H.; Pandy, D.R.

    1996-10-01

    The purpose of this program was to conduct experimental and analytical efforts to determine lubricant circulation characteristics of new HFC/POE pairs and HFC/mineral oil pairs in a representative central residential HVAC system and to compare their behavior with the traditional HCFC-22/mineral oil (refrigerant/lubricant) pair. A dynamic test facility was designed and built to conduct the experimental efforts. This facility provided a unique capability to visually and physically measure oil circulation rates, on-line, in operating systems. A unique on-line ultraviolet-based measurement device was used to obtain detailed data on the rate and level of lubricant oil circulated within the operating heat pump system. The experimental and analytical data developed during the program are presented as a function of vapor velocity, refrigerant/lubricant viscosity, system features and equipment. Both visual observations and instrumentation were used to understand ``worst case`` oil circulation situations. This report is presented in two volumes. Volume 1 contains a complete description of the program scope, objective, test results summary, conclusions, description of test facility and recommendations for future effort. Volume 2 contains all of the program test data essentially as taken from the laboratory dynamic test facility during the sequence of runs.

  12. Self-lubricating carbon nanotube reinforced nickel matrix composites

    SciTech Connect (OSTI)

    Scharf, T. W.; Neira, A.; Hwang, J. Y.; Banerjee, R.; Tiley, J.

    2009-07-01

    Nickel (Ni)--multiwalled carbon nanotube (CNT) composites have been processed in a monolithic form using the laser-engineered net shape (LENS) processing technique. Auger electron spectroscopy maps determined that the nanotubes were well dispersed and bonded in the nickel matrix and no interfacial chemical reaction products were determined in the as-synthesized composites. Mechanisms of solid lubrication have been investigated by micro-Raman spectroscopy spatial mapping of the worn surfaces to determine the formation of tribochemical products. The Ni-CNT composites exhibit a self-lubricating behavior, forming an in situ, low interfacial shear strength graphitic film during sliding, resulting in a decrease in friction coefficient compared to pure Ni.

  13. Preliminary Results of Cleaning Process for Lubricant Contamination

    SciTech Connect (OSTI)

    Eisenmann, D.; Brasche, L.; Lopez, R.

    2006-03-06

    Fluorescent penetrant inspection (FPI) is widely used for aviation and other components for surface-breaking crack detection. As with all inspection methods, adherence to the process parameters is critical to the successful detection of defects. Prior to FPI, components are cleaned using a variety of cleaning methods which are selected based on the alloy and the soil types which must be removed. It is also important that the cleaning process not adversely affect the FPI process. There are a variety of lubricants and surface coatings used in the aviation industry which must be removed prior to FPI. To assess the effectiveness of typical cleaning processes on removal of these contaminants, a study was initiated at an airline overhaul facility. Initial results of the cleaning study for lubricant contamination in nickel, titanium and aluminum alloys will be presented.

  14. Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash

    Broader source: Energy.gov (indexed) [DOE]

    Emissions: | Department of Energy 5 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_plumley.pdf More Documents & Publications Detailed Characterization of Lubricant-Derived Ash-Related Species in Diesel Exhaust and Aftertreatment Systems Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending Filter Life Key Parameters Affecting DPF Performance Degradation and Impact on Lifetime Fuel Economy

  15. Hydrodynamically Lubricated Rotary Shaft Having Twist Resistant Geometry

    DOE Patents [OSTI]

    Dietle, Lannie; Gobeli, Jeffrey D.

    1993-07-27

    A hydrodynamically lubricated squeeze packing type rotary shaft with a cross-sectional geometry suitable for pressurized lubricant retention is provided which, in the preferred embodiment, incorporates a protuberant static sealing interface that, compared to prior art, dramatically improves the exclusionary action of the dynamic sealing interface in low pressure and unpressurized applications by achieving symmetrical deformation of the seal at the static and dynamic sealing interfaces. In abrasive environments, the improved exclusionary action results in a dramatic reduction of seal and shaft wear, compared to prior art, and provides a significant increase in seal life. The invention also increases seal life by making higher levels of initial compression possible, compared to prior art, without compromising hydrodynamic lubrication; this added compression makes the seal more tolerant of compression set, abrasive wear, mechanical misalignment, dynamic runout, and manufacturing tolerances, and also makes hydrodynamic seals with smaller cross-sections more practical. In alternate embodiments, the benefits enumerated above are achieved by cooperative configurations of the seal and the gland which achieve symmetrical deformation of the seal at the static and dynamic sealing interfaces. The seal may also be configured such that predetermined radial compression deforms it to a desired operative configuration, even through symmetrical deformation is lacking.

  16. Research into Oil-based Colloidal-Graphite Lubricants for Forging of Al-based Alloys

    SciTech Connect (OSTI)

    Petrov, A.; Petrov, P.; Petrov, M.

    2011-05-04

    The presented paper describes the topical problem in metal forging production. It deals with the choice of an optimal lubricant for forging of Al-based alloys. Within the scope of the paper, the properties of several oil-based colloidal-graphite lubricants were investigated. The physicochemical and technological properties of these lubricants are presented. It was found that physicochemical properties of lubricant compositions have an influence on friction coefficient value and quality of forgings.The ring compression method was used to estimate the friction coefficient value. Hydraulic press was used for the test. The comparative analysis of the investigated lubricants was carried out. The forging quality was estimated on the basis of production test. The practical recommendations were given to choose an optimal oil-based colloidal-graphite lubricant for isothermal forging of Al-based alloy.

  17. Overview of DOE Fuel & Lubricant Technologies R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel & Lubricant Technologies R&D Overview of DOE Fuel & Lubricant Technologies R&D 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ft000_stork_2010_o.pdf More Documents & Publications Overview of DOE Fuel Technologies R&D Overview of Fuels Technologies Fuels & Lubricants

  18. The role of polymer formation during vapor phase lubrication of silicon.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect The role of polymer formation during vapor phase lubrication of silicon. Citation Details In-Document Search Title: The role of polymer formation during vapor phase lubrication of silicon. The lubrication of silicon surfaces with alcohol vapors has recently been demonstrated. With a sufficient concentration of pentanol vapor present, sliding of a silica ball on an oxidized silicon wafer can proceed with no measurable wear. The initial results of time-of-flight

  19. Toxic Substances Control Act

    SciTech Connect (OSTI)

    Not Available

    1992-05-15

    This Reference Book contains a current copy of the Toxic Substances Control Act and those regulations that implement the statute and appear to be most relevant to DOE activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

  20. Understanding diesel engine lubrication at low temperature

    SciTech Connect (OSTI)

    Smith, M.F. Jr.

    1990-01-01

    This paper reports on oil pumpability in passenger car gasoline engines that was well-characterized by an ASTM program and by individual researchers in the 1970's and early 1980's. oil pumpability in diesel engines however, was not investigated to any significant extent until the mid-1980's. This study was initiated to define the performance of several commercial viscosity modifiers in different formulations containing 3 detergent-inhibitor (DI) additive packages and 4 basestock types. The test oils were run at {minus}18{degrees} C (0{degrees} F) in a Cummins NTC-400 diesel engine. The results, when statistically analyzed, indicated that a new, second generation olefin copolymer (OCP) viscosity modifier has better performance that a first generation OCP and, furthermore, had performance equal to a polymethacrylate (PMA) viscosity modifier. The analysis also showed that one DI/base stock combination had a significant effect on performance. The apparent shear rate of the oil in the pump inlet tube was calculated from the oil pump flow rate measured at idle speed at low temperature and the pump inlet tube diameter. The shear rate and oil viscosity were used to estimate the shear stress in the pump inlet tube. The shear stress level of the engine is 56% higher than the Mini-Rotary Viscometer (MRV). Hence, the current MRV procedure is rheologically unsuitable to predict pumpability in a large diesel engine. A new device was developed for measuring the oil film thickness in the turbocharge bearing and noting the time when a full oil film is formed. Results indicate that a full oil film occurs almost immediately, well before any oil pressure is observed at the turbocharge inlet. Residual oil remaining in the bearing after shutdown may account of this observation. The oil film maintained its thickness both before, and after the first indication of oil pressure. More work is needed to study this effect.

  1. Offshore Lubricants to Exhibit 7.07% CAGR from 2014 to 2020 Due...

    Open Energy Info (EERE)

    segmented the global offshore lubricants market into gear oil, grease, engine oil, hydraulic oil, and others (such as circulating oil, turbine oil, and compressor oil). Among...

  2. Vehicle Technologies Office Merit Review 2015: A Novel Lubricant Formulation Scheme for 2% Fuel Efficiency Improvement

    Broader source: Energy.gov [DOE]

    Presentation given by Northwestern University at 2015 DOE Hydrogen and Fuel Cells Program and vehicle technologies office annual merit review and peer evaluation meeting about a novel lubricant...

  3. Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts (Presentation)

    SciTech Connect (OSTI)

    Whitacre, S. D.

    2005-08-25

    Discusses the impact of lubricant formulation on the performance of oxides of nitrogen (NOx) Adsorber Catalysts, including background/motivation for study, experimental design, and results.

  4. The Impact of Lubricant on Emissions from a Medium-Duty Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Fuels for Advanced CIDI Engines and Fuel Cells: 2000 Annual Progress ...

  5. Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report

    Broader source: Energy.gov [DOE]

    This report describes the progress made on the research and development projects funded by the Fuel and Lubricants subprogram in the Vehicle Technologies Office in 2014.

  6. Tribological properties of self-lubricating NiAl/Mo-based composites containing AgVO{sub 3} nanowires

    SciTech Connect (OSTI)

    Liu, Eryong; Gao, Yimin; Bai, Yaping; Yi, Gewen; Wang, Wenzhen; Zeng, Zhixiang; Jia, Junhong

    2014-11-15

    Silver vanadate (AgVO{sub 3}) nanowires were synthesized by hydrothermal method and self-lubricating NiAl/Mo-AgVO{sub 3} composites were fabricated by powder metallurgy technique. The composition and microstructure of NiAl/Mo-based composites were characterized and the tribological properties were investigated from room temperature to 900 C. The results showed that NiAl/Mo-based composites were consisted of nanocrystalline B2 ordered NiAl matrix, Al{sub 2}O{sub 3}, Mo{sub 2}C, metallic Ag and vanadium oxide phase. The appearance of metallic Ag and vanadium oxide phase can be attributed to the decomposition of AgVO{sub 3} during sintering. Wear testing results confirmed that NiAl/Mo-based composites have excellent tribological properties over a wide temperature range. For example, the friction coefficient and wear rate of NiAl/Mo-based composites containing AgVO{sub 3} were significantly lower than the composites containing only metallic Mo or AgVO{sub 3} lubricant when the temperature is above 300 C, which can be attributed to the synergistic lubricating action of metallic Mo and AgVO{sub 3} lubricants. Furthermore, Raman results indicated that the composition on the worn surface of NiAl-based composites was self-adjusted after wear testing at different temperatures. For example, Ag{sub 3}VO{sub 4} and Fe{sub 3}O{sub 4} lubricants were responsible for the improvement of tribological properties at 500 C, AgVO{sub 3}, Ag{sub 3}VO{sub 4} and molybdate for 700 C, and AgVO{sub 3} and molybdate for 900 C of NiAl-based composites with the addition of metallic Mo and AgVO{sub 3}. - Highlights: NiAl/Mo-AgVO{sub 3} nanocomposites were prepared by mechanical alloying and sintering. AgVO{sub 3} decomposed to metallic Ag and vanadium oxide during the sintering process. NiAl/Mo-AgVO{sub 3} exhibited superior tribological properties at a board temperature range. Phase composition on the worn surface was varied with temperatures. Self-adjusted action was responsible for the improvement of tribological properties.

  7. Antioxidants and stabilizers for lubricants and fuels. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-05-01

    The bibliography contains citations concerning the design, manufacture, and evaluation of antioxidants and stabilizers used in lubricants and fuels. The synthesis, stability, degradation, and storage life of lubricant and fuel additives are discussed. Additives used in jet engine, turbine, natural-gas, and coal-water fuels are examined. (Contains a minimum of 129 citations and includes a subject term index and title list.)

  8. Measurement of solubility, viscosity, and density of R-410A refrigerant/lubricant mixtures

    SciTech Connect (OSTI)

    Cavestri, R.C.; Schafer, W.R.

    2000-07-01

    Measurements of the refrigerant vapor/liquid lubricant equilibrium viscosity reduction of four polyolester lubricants, viscosity grades 32 and 68 ISO VG, with the refrigerant R-410A were taken between {minus}13 F and 257 F and up to 700 psia. A high and low miscibility grade polyolester was analyzed for each viscosity. The viscosity, density, and composition of the solubilized gas mixture in solution with the lubricant was obtained with constant gas vapor composition in the viscometer head space. This refrigerant has a very small temperature glide but is considered a zeotropic blend nonetheless. The fractionation data presented were obtained from individual isothermal measurements. The isotherm for each temperature detailed the composition of the equilibrium gas fractionation of R-32 and R-125 in the lubricant, mixed vapor pressure, concentration of the total mixed blend (percent by weight) in the lubricant, and viscosity in centipoise (cP) and centistokes (cSt).

  9. Real-time determination of lubricant concentrations dissolved in alternative refrigerants

    SciTech Connect (OSTI)

    Cavestri, R.C.; Schafer, W.R.

    1999-07-01

    A methodology was developed and used to measure both polyolester lubricant concentrations in solution with R-134a and R-407C and mineral oils in solution with R-123. This method is unaffected by changes in pressure, temperature, refrigerant type, and lubricant type. The concentration of dissolved lubricant was measured in three alternative refrigerants with two different synthetic polyolesters and two different mineral oils over a temperature range of 68 F (20 C) to 140 F (60 C) and a concentration range of 0 to 6% w/w. The evaluation methods included density, viscosity, and high-pressure liquid chromatography (HPLC). Measurements of viscosity and density were performed on an oscillating body viscometer. Lubricant concentrations determined by HPLC compared favorably with the ASHRAE Standard 41.1 method (ASHRAE 1984). Circulating lubricant, miscible and immiscible, concentration in identical R-407C operating systems was also measured to demonstrate the practical application of the test method.

  10. On-Line Measurement of Lubricant Film Thickness Using Ultrasonic Reflection Coefficients

    SciTech Connect (OSTI)

    Drinkwater, B.W.; Dwyer-Joyce, R.S.; Harper, P.

    2004-02-26

    The ultrasonic reflectivity of a lubricant layer between two solid bodies depends on the ultrasonic frequency, the acoustic properties of the liquid and solid, and the layer thickness. In this paper, ultrasonic reflectivity measurements are used as a method for determining the thickness of lubricating films in bearing systems. An ultrasonic transducer is positioned on the outside of a bearing shell such that the wave is focused on the lubricant film layer. For a particular lubricant film the reflected pulse is processed to give a reflection coefficient spectrum. The lubricant film thickness is then obtained from either the layer stiffness or the resonant frequency. The method has been validated using static fluid wedges and the elastohydrodynamic film formed between a ball sliding on a flat. Film thickness values in the range 50-500 nm were recorded which agreed well with theoretical film formation predictions.

  11. Fabrics coated with lubricated nanostructures display robust omniphobicity

    SciTech Connect (OSTI)

    Shillingford, Cicely; MacCallum, Noah; Wong, Tak -Sing; Kim, Philseok; Aizenberg, Joanna

    2013-12-11

    The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.

  12. Fabrics coated with lubricated nanostructures display robust omniphobicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shillingford, Cicely; MacCallum, Noah; Wong, Tak -Sing; Kim, Philseok; Aizenberg, Joanna

    2013-12-11

    The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and whenmore » exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.« less

  13. Fabrics coated with lubricated nanostructures display robust omniphobicity

    SciTech Connect (OSTI)

    Shillingford, C; MacCallum, N; Wong, TS; Kim, P; Aizenberg, J

    2013-12-11

    The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e. g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. Herein we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.

  14. Renewable Fuels and Lubricants (ReFUEL) Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01

    This fact sheet describes the Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve vehicle efficiency and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such as biodiesel and synthetic diesel derived from biomass. The ReFUEL Laboratory features a chassis dynamometer for vehicle performance and emissions research, two engine dynamometer test cells for advanced fuels research, and precise emissions analysis equipment. As a complement to these capabilities, detailed studies of fuel properties, with a focus on ignition quality, are performed at NREL's Fuel Chemistry Laboratory.

  15. System for lubrication of a brake air compressor associated with a turbocharged internal combustion engine

    SciTech Connect (OSTI)

    Spencer, J.C.

    1992-10-13

    This patent describes a system for use with a vehicle which includes a turbocharged internal combustion engine having a lubricating system wherein lubricating oil from an engine oil reservoir is circulated within the engine and also to and from an associated brake system air compressor which supplies compressed air for operation of the vehicle air braking system. This patent describes improvement in passing supercharged air to an oil crankcase of the air compressor to cause lubricating oil to drain therefrom and return to the engine oil reservoir.

  16. Lubrication of polysilicon micromechanisms with self-assembled monolayers

    SciTech Connect (OSTI)

    Srinivasan, U.; Foster, J.D.; Habib, U.; Howe, R.T.; Maboudian, R.; Senft, D.C.; Dugger, M.T.

    1998-06-01

    Here, the authors report on the lubricating effects of self-assembled monolayers (SAMs) on MEMS by measuring static and dynamic friction with two polysilicon surface- micromachined devices. The first test structure is used to study friction between laterally sliding surfaces and with the second, friction between vertical sidewalls can be investigated. Both devices are SAM-coated following the sacrificial oxide etch and the microstructures emerge released and dry from the final water rinse. The coefficient of static friction, {mu}{sub s} was found to decrease from 2.1 {+-} 0.8 for the SiO{sub 2} coating to 0.11 {+-} 0.01 and 0.10 {+-} 0.01 for films derived from octadecyltrichloro-silane (OTS) and 1H,1H,2H,2H-perfluorodecyl-trichlorosilane (FDTS). Both OTS and FDTS SAM-coated structures exhibit dynamic coefficients of friction, {mu}{sub d} of 0.08 {+-} 0.01. These values were found to be independent of the apparent contact area, and remain unchanged after 1 million impacts at 5.6 {micro}N (17 kPa), indicating that these SAMs continue to act as boundary lubricants despite repeated impacts. Measurements during sliding friction from the sidewall friction testing structure give comparable initial {mu}{sub d} values of 0.02 at a contact pressure of 84 MPa. After 15 million wear cycles, {mu}{sub d} was found to rise to 0.27. Wear of the contacting surfaces was examined by SEM. Standard deviations in the {mu} data for SAM treatments indicate uniform coating coverage.

  17. Method and apparatus for injecting a substance into the bloodstream of a subject

    DOE Patents [OSTI]

    Lambrecht, R.M.; Bennett, G.W.; Duncan, C.C.; Ducote, L.W.

    1983-10-18

    An apparatus and method is disclosed for injecting a substance, such as a radiopharmaceutical, into the bloodstream of a subject. The apparatus comprises an injection means, such as a servo controlled syringe, a means for measuring the concentration of that substance in the subject's bloodstream, and means for controlling the injection in response to the measurement so that the concentration of the substance follows a predetermined function of time. The apparatus of the subject invention functions to inject a substance into a subject's bloodstream at a rate controlled by an error signal proportional to the difference between the concentration of the substance in the subject's bloodstream and the predetermined function. 2 figs.

  18. Method and apparatus for injecting a substance into the bloodstream of a subject

    DOE Patents [OSTI]

    Lambrecht, Richard M.; Bennett, Gerald W.; Duncan, Charles C.; Ducote, Louis W.

    1983-10-18

    An apparatus and method for injecting a substance, such as a radiopharmaceutical, into the bloodstream of a subject. The apparatus comprises an injection means, such as a servo controlled syringe, a means for measuring the concentration of that substance in the subject's bloodstream, and means for controlling the injection in response to the measurement so that the concentration of the substance follows a predetermined function of time. The apparatus of the subject invention functions to inject a substance into a subject's bloodstream at a rate controlled by an error signal proportional to the difference between the concentration of the substance in the subject's bloodstream and the predetermined function.

  19. Development of high temperature solid lubricant coatings. Final report, 15 August 1997--14 August 1998

    SciTech Connect (OSTI)

    Bhattacharya, R.S.; Keller, S.

    1999-01-29

    The primary research objective of this work was to develop a solid lubricant coating that can function over a broad temperature range. The approach investigated consisted of developing adaptive lubricant coating from materials that undergo chemical change with increasing temperature by reacting together and with the environment. To test this approach, UES and Cleveland State University have conducted experiments to form cesium oxythiotungstate, a high temperature lubricant, on Inconel 718 surface from composite coatings of cesium tungstate and tungsten sulfide. The coatings were deposited by RF sputtering and characterized by X-ray Photoelectron Spectroscopy (XPS). The results indicate that sulfur escapes from the composite coating upon exposure to temperature above 5000C in air. Thus, the desired adaptive lubricant phase, cesium oxythiotungstate could not be formed. However, cesium oxythiotungstate phase has been found to form upon annealing at high temperature in vacuum. The friction coefficients of sputtered cesium oxythiotungstate and cesium tungstate coatings have been measured.

  20. Compatibility of refrigerants and lubricants with electrical sheet insulation under retrofit conditions

    SciTech Connect (OSTI)

    Doerr, R.G.; Waite, T.D.

    1996-11-01

    To determine whether exposure to the original refrigerant/mineral oil would affect compatibility of sheet insulation with alternative refrigerant/lubricant after retrofit, sheet insulation was exposed at elevated temperature to the original refrigerant and mineral oil for 500 hours, followed by exposure to the alternative refrigerant and lubricant for 500 hours. Most of the sheet insulation materials exposed to the alternative refrigerant and lubricant (after an initial exposure to the original refrigerant and mineral oil) appeared to be compatible with the alternative refrigerant and lubricant. The only concern was delamination and blistering of the sheet insulation containing Nomex, especially after removal of absorbed refrigerant at high temperature. This was attributed to incompatibility of the adhesive and not to the Nomex itself. Embrittlement of the polyethylene terephthalate (PET) sheet was initially observed, but 2048 subsequent tests under extremely dry conditions showed that embrittlement of the PET materials was attributed to moisture present during the exposure.

  1. High temperature solid lubricant materials for heavy duty and advanced heat engines

    SciTech Connect (OSTI)

    DellaCorte, C.; Wood, J.C.

    1994-10-01

    Advanced engine designs incorporate higher mechanical and thermal loading to achieve efficiency improvements. This approach often leads to higher operating temperatures of critical sliding elements (e.g. piston ring/cylinder wall contacts and valve guides) which compromise the use of conventional and even advanced synthetic liquid lubricants. For these applications solid lubricants must be considered. Several novel solid lubricant composites and coatings designated PS/PM200 have been employed to dry and marginally oil lubricated contacts in advanced heat engines. These applications include cylinder kits of heavy duty diesels, and high temperature sterling engines, sidewall seals of rotary engines and various exhaust valve and exhaust component applications. The following paper describes the tribological and thermophysical properties of these tribomaterials and reviews the results of applying them to engine applications. Other potential tribological materials and applications are also discussed with particular emphasis to heavy duty and advanced heat engines.

  2. Federal Substance Abuse Testing Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2014-01-30

    The Order establishes the requirements and responsibilities for the DOE Federal Substance Abuse Testing Program which covers drug and alcohol testing. Supersedes DOE O 3792.3 Chg 1.

  3. Renewable Fuels and Lubricants Laboratory (Fact Sheet), NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Renewable Fuels and Lubricants Laboratory State-of-the-Art Fuel and Vehicle Testing The Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve efficiency of conventional gasoline-powered vehicles and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such

  4. Detailed Characterization of Lubricant-Derived Ash-Related Species in

    Broader source: Energy.gov (indexed) [DOE]

    Diesel Exhaust and Aftertreatment Systems | Department of Energy Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_sappok.pdf More Documents & Publications Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on

  5. Ionic Liquids as Novel Lubricants and Additives for Diesel Engine Applications

    SciTech Connect (OSTI)

    Qu, Jun; Blau, Peter Julian; Dai, Sheng; Luo, Huimin; Meyer III, Harry M

    2009-01-01

    The lubricating properties of two ionic liquids with the same anion but different cations, one ammonium IL [C8H17]3NH.Tf2N and one imidazolium IL C10mim.Tf2N, were evaluated both in neat form and as oil additives. Experiments were conducted using a standardized reciprocating sliding test using a segment of a Cr-plated diesel engine piston ring against a grey cast iron flat specimen with simulated honing marks as on the engine cylinder liner. The selected ionic liquids were benchmarked against conventional hydrocarbon oils. Substantial friction and wear reductions, up to 55% and 34%, respectively, were achieved for the neat ionic liquids compared to a fully-formulated 15W40 engine oil. Adding 5 vol% ILs into mineral oil has demonstrated significant improvement in the lubricity. One blend even outperformed the 15W40 engine oil with 9% lower friction and 34% less wear. Lubrication regime modeling, worn surface morphology examination, and surface chemical analysis were conducted to help understand the lubricating mechanisms for ionic liquids. Results suggest great potential for using ionic liquids as base lubricants or lubricant additives for diesel engine applications.

  6. Aging model for solid lubricants used in weapon stronglinks: tribological performance and hardware review

    SciTech Connect (OSTI)

    Dugger, M.T.; Peebles, D.E.; Sorroche, E.H.; Varga, K.S.; Bryan, R.M.

    1997-09-01

    The solid lubricant used most extensively in strong links throughout the enduring stockpile contains MoS{sub 2}, which is known to react with oxygen and water vapor resulting in a change in the material`s friction and wear behavior. The authors have examined the frictional behavior of this lubricant as a function of oxidation, in support of efforts to quantify the impact of changes in the material on the dynamic behavior of the MC2969 strong link. Their results show that the friction response of oxidized lubricant is strongly influenced by the amount of burnishing performed on the lubricant after deposition. Low levels of burnish leave a thick film, of which only the near surface degrades during oxidation. Rapid wear of the oxidized material leaves a surface whose properties are the same as non-oxidized material. Higher levels of burnish leave a thinner film of lubricant such that the entire film may be oxidized. The friction coefficient on this surface reaches a steady state value greater than that of non oxidized material. In addition to these fundamental differences in steady state behavior, they have shown that the initial friction coefficient on oxidized surfaces is related to the amount of sulfide converted to sulfate, regardless of the oxidation conditions used. Measurements on parts returned from the stockpile show that the friction behavior of aged hardware is consistent with the behavior observed on controlled substrates containing thin lubricant films.

  7. New Generation of MoSx Based Solid Lubricant Coatings: Recent Developments and Applications

    SciTech Connect (OSTI)

    Haider, Julfikar; Hashmi, M. S. J.

    2011-01-17

    In recent times, there is a growing interest in applying Molybdenum disulphide (MoS{sub x}) solid lubricant coatings on components to improve the tribological performance (i.e. lower friction coefficient and wear rate). The tribological performance of MoS{sub x} coating is strongly dependent on coating properties and tribological environment. MoS{sub x} coatings are highly successful in certain applications such as in space/vacuum technology, but its effectiveness is questioned in other terrestrial applications such as in cutting tool industry due to its lower hardness and poor oxidation resistance leading to shorter life. In order to circumvent this drawback, the paper identifies that current research is being concentrated on developing MoS{sub x} based coatings using three different approaches: (1) Metal or compound addition in MoS{sub x} coating (2)MoS{sub x} layer on hard coating and (3)MoS{sub x} addition in hard coating matrix. Although the primary objective is same in all three cases, the third approach is considered to be more effective in improving the tribological properties of the coating. Finally, the potential applications of MoS{sub x} based coatings in different industrial sectors have been briefly outlined.

  8. Advanced Petroleum-Based Fuels--Diesel Emissions Control Project (APBF-DEC): Lubricants Project, Phase 1 Summary, July 2004

    SciTech Connect (OSTI)

    Not Available

    2004-07-01

    The Advanced Petroleum Based Fuels-Diesel Emission Control project is a government/industry collaborative project to identify the optimal combinations of low-sulfur diesel fuels, lubricants, diesel engines, and emission control systems to meet projected emission standards for the 2004-2010 time period. This summary describes the results of the first phase of the lubricants study investigating the impact on lubricant formulation on engine-out emissions.

  9. Friction of different monolayer lubricants in MEMs interfaces.

    SciTech Connect (OSTI)

    Carpick, Robert W. (University of Wisconsin, Madison, WI); Street, Mark D.; Ashurst, William Robert; Corwin, Alex David

    2006-01-01

    This report details results from our last year of work (FY2005) on friction in MEMS as funded by the Campaign 6 program for the Microscale Friction project. We have applied different monolayers to a sensitive MEMS friction tester called the nanotractor. The nanotractor is also a useful actuator that can travel {+-}100 {micro}m in 40 nm steps, and is being considered for several MEMS applications. With this tester, we can find static and dynamic coefficients of friction. We can also quantify deviations from Amontons' and Coulomb's friction laws. Because of the huge surface-to-volume ratio at the microscale, surface properties such as adhesion and friction can dominate device performance, and therefore such deviations are important to quantify and understand. We find that static and dynamic friction depend on the monolayer lubricant applied. The friction data can be modeled with a non-zero adhesion force, which represents a deviation from Amontons' Law. Further, we show preliminary data indicating that the adhesion force depends not only on the monolayer, but also on the normal load applied. Finally, we also observe slip deflections before the transition from static to dynamic friction, and find that they depend on the monolayer.

  10. MIL-L-87177 and CLT:X-10 Lubricants Improve Electrical Connector Fretting Corrosion Behavior

    SciTech Connect (OSTI)

    AUKLAND,NEIL R.; HANLON,JAMES T.

    1999-10-12

    We have conducted a fretting research project using MIL-L-87177 and CLT: X-10 lubricants on Nano-miniature connectors. When they were fretted without lubricant, individual connectors first exceeded our 0.5 ohm failure criteria from 2,341 to 45,238 fretting cycles. With additional fretting, their contact resistance increased to more than 100,000 ohms. Unmodified MIL-L-87177 lubricant delayed the onset of first failure to between 430,000 and over 20,000,000 fretting cycles. MIL-L-87177 modified by addition of Teflon powder delayed first failure to beyond 5 million fretting cycles. Best results were obtained when Teflon was used and also when both the straight and modified lubricants were poured into and then out of the connector. CLT: X-10 lubricant delayed the onset of first failure to beyond 55 million cycles in one test where a failure was actually observed and to beyond 20 million cycles in another that was terminated without failure. CLT: X-10 recovered an unlubricated connector driven deeply into failure, with six failed pins recovering immediately and four more recovering during an additional 420 thousand fretting cycles. MIL-L-87177 was not able to recover a connector under similar conditions.

  11. Compatibility of refrigerants and lubricants with motor materials under retrofit conditions

    SciTech Connect (OSTI)

    Doerr, R.; Waite, T.

    1995-01-12

    Motor materials were exposed to original refrigerants R-11, R-12, R-22 and R-502 in the presence of mineral oil for 500 hours. These same materials were then exposed to alternative refrigerants R-123, R-134a, R-407C (R-32/R-125/R-134a) and R-404A (R-125/R-143a/R-134a), respectively, in the presence of the appropriate lubricant for 500 hours. As a control, some samples were exposed to the original refrigerant/mineral oil for a total of 1,000 hours. These tests were conducted to determine whether exposure to the original refrigerant/mineral oil would affect compatibility of the motor materials with the alternative refrigerant/lubricant after retrofit. Motor materials exposed to the alternative refrigerant and lubricant (after an initial exposure to the original refrigerant and mineral oil) appeared to be compatible with the alternative refrigerant and lubricant. The only concerns were embrittlement of the polyethylene terephthalate (PET) sheet and sleeving insulations, and delamination and blistering of the Nomex sheet insulation in the R-22, R-502, and R-12. Embrittlement of the PET materials was attributed to moisture present during the exposure. Separation of the 475 varnish from metal surfaces in the R-123 was also a concern. The sheet and sleeving insulations were affected by the original refrigerant/mineral oil to a greater extent than by the alternative refrigerant and lubricant.

  12. Compatibility of manufacturing process fluids with R-134a and polyolester lubricant. Final report

    SciTech Connect (OSTI)

    Cavestri, R.C.; Schooley, D.L.

    1996-07-01

    This report includes a broad list of processing fluids that are known to be used to manufacture air conditioning and refrigeration products. Sixty-four process fluids from this list were selected for compatibility studies with R-134a and ICI EMKARATE RL32H (32 ISO) polyolester lubricant. Solutions or suspensions of the process fluid residues in polyolester lubricant were heated for 14 days at 175{degrees}C (347{degrees}F) in evacuated sealed glass tubes containing only valve steel coupons. Miscibility tests were performed at 90 wt.% R-134a, 10 wt.% polyolester lubricant with process fluid residue contaminate and were scanned in 10{degrees}C (18{degrees}F) increments over a temperature range of ambient to -40{degrees}C (-40{degrees}F). Any sign of turbidity, haze formation or oil separation was considered the immiscibility point.

  13. Identification of tribological research and development needs for lubrication of advanced heat engines

    SciTech Connect (OSTI)

    Fehrenbacher, L.L.; Levinson, T.M.

    1985-09-01

    The continuous evolution of higher power density propulsion systems has always fueled the search for materials and lubricants with improved thermal and/or durability characteristics. Tribology of the upper cylinder region is the major technology roadblock in the path of the adiabatic diesel engine which has an energy reduction potential that exceeds that of all other engine development types. This tribology assessment resulted in the following major conclusions: a low friction and a low wear seal between the ring belt and cylinder bore are the most critical tribology functions in the diesel combustion chamber; development of solid lubrication systems will not satisfy the simultaneous low friction and low wear requirements in the upper cylinder area; development of separate upper cylinder liquid lubrication systems offers the most attractive design alternative for meeting the operational goals of future ''minimum cooled'' diesel engines.

  14. Accelerated screening methods for determining chemical and thermal stability of refrigerant-lubricant mixtures, Part II: Experimental comparison and verification of methods. Volume 2, In situ conductivity data

    SciTech Connect (OSTI)

    Kauffman, R.

    1995-09-01

    Data are presented for the accelerated screening methods for determining chemical and thermal stability of refrigerant-lubricant mixtures.

  15. Effects of temperature on desiccant catalysis of refrigerant and lubricant decomposition. Final report

    SciTech Connect (OSTI)

    Rohatgi, N.D.T.

    1998-06-01

    Accelerated aging at high temperatures (149 C) for short aging times (28 days) is effective in screening the compatibility of different materials in refrigeration systems. However, in actual applications temperatures are usually lower and operating times much longer. Therefore plots to allow for interpolation or extrapolation of experimental data to actual operating conditions are needed. In the current study, aging of refrigerant/lubricant/desiccant/metal systems was conducted at five different temperatures, and for each temperature at four different aging times. The data collected from this study provided plots relating refrigerant or lubricant decomposition to aging time, aging temperature, and type of desiccant, which can be used for interpolation or extrapolation.

  16. In situ measurement of the bonded film thickness of Z-Tetraol lubricant on magnetic recording media

    SciTech Connect (OSTI)

    Zhu Lei; Li Feng

    2010-10-15

    Currently, the bonded film thickness of perfluoropolyether lubricant on top of magnetic recording media is measured by a two-step process. First, the media disk has to be rinsed thoroughly using a fluorocarbon solvent (for instance, Vetrel) to remove the mobile lubricant. Second, the thickness of the remaining lubricant on the media surface which is regarded as the bonded lubricant thickness is then measured either by Fourier transform infrared spectroscopy (FTIR) or electron spectroscopy for chemical analysis. As the total lubricant thickness approaches single molecular dimension ({approx}10 A), current methods face tremendous challenge on the accuracy and sensitivity of the measurement. We studied the spectral characteristics responding to the lubricant bonding with the carbon overcoat by the time-of-flight secondary ion mass spectra and proposed to use the peak area ratio (C{sub 3}H{sub 2}F/C{sub 3}H{sub 5}O and C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}) to characterize the bonded Z-Tetraol lubricant that produces a direct bonded lubricant thickness measurement without the need to remove the mobile lubricant with a solvent. After taking the background signal of disks prior to bonding by UV irradiation into account, this method becomes independent of the total lubricant thickness as well as shows good correlation linearity (R{sup 2{approx}}87%) with the current FTIR method for the ratio of C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}.

  17. Simultaneous wireline operations from a floating rig with a subsea lubricator

    SciTech Connect (OSTI)

    Hopper, C.T. )

    1990-08-01

    In 1987, and extensive wireline program was completed on two subsea wells in the highlander field in the central North Sea with a subsea lubricator deployed from a drilling rig that was drilling and working over adjacent wells. This paper reports how working on two wells concurrently is a way to reduce the operating costs of a subsea development significantly.

  18. Gas-lubricated seal for sealing between a piston and a cylinder wall

    DOE Patents [OSTI]

    Hoult, David P.

    1985-01-01

    A piston-cylinder seal uses gas for a lubricant and has a runner supported on a gapless structure and placed in the space between the piston and the cylinder wall. The runner is deformed elastically under the influence of the operating pressures to follow and compensate for variations in the piston-cylinder fit and maintain a seal.

  19. Gas-lubricated seal for sealing between a piston and a cylinder wall

    DOE Patents [OSTI]

    Hoult, D.P.

    1985-09-10

    A piston-cylinder seal uses gas for a lubricant and has a runner supported on a gapless structure and placed in the space between the piston and the cylinder wall. The runner is deformed elastically under the influence of the operating pressures to follow and compensate for variations in the piston-cylinder fit and maintain a seal. 4 figs.

  20. Engine having a high pressure hydraulic system and low pressure lubricating system

    DOE Patents [OSTI]

    Bartley, Bradley E.; Blass, James R.; Gibson, Dennis H.

    2000-01-01

    An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

  1. Collaborative Lubricating Oil Study on Emissions: November 28, 2006 - March 31, 2011

    SciTech Connect (OSTI)

    Carroll, J. N.; Khalek, I. A.; Smith, L. R.; Fujita, E.; Zielinska, B.

    2011-10-01

    The Collaborative Lubricating Oil Study on Emissions (CLOSE) project was a pilot investigation of how fuels and crankcase lubricants contribute to the formation of particulate matter (PM) and semi-volatile organic compounds (SVOC) in vehicle exhaust. As limited vehicles were tested, results are not representative of the whole on-road fleet. Long-term effects were not investigated. Pairs of vehicles (one normal PM emitting, one high-PM emitting) from four categories were selected: light-duty (LD) gasoline cars, medium-duty (MD) diesel trucks, heavy-duty (HD) natural-gas-fueled buses, and HD diesel buses. HD vehicles procured did not exhibit higher PM emissions, and thus were labeled high mileage (HM). Fuels evaluated were non-ethanol gasoline (E0), 10 percent ethanol (E10), conventional low-sulfur TxLED diesel, 20% biodiesel (B20), and natural gas. Temperature effects (20 degrees F, 72 degrees F) were evaluated on LD and MD vehicles. Lubricating oil vintage effects (fresh and aged) were evaluated on all vehicles. LD and MD vehicles were operated on a dynamometer over the California Unified Driving Cycle, while HD vehicles followed the Heavy Duty Urban Dynamometer Driving Schedule. Regulated and unregulated emissions were measured. Chemical markers from the unregulated emissions measurements and a tracer were utilized to estimate the lubricant contribution to PM.

  2. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    SciTech Connect (OSTI)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a method for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.

  3. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a methodmore » for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.« less

  4. MIL-L-87177 Lubricant Bulletproofs Connectors Against Chemical and Fretting Corrosion

    SciTech Connect (OSTI)

    HANLON, JAMES T.; DE MARQUIS, VIRGINIA K.; TAYLOR, RONALD DEAN

    2002-05-01

    Electrical connectors corrode. Even our best SA and MC connectors finished with 50 to 100 microinches of gold over 50 to 100 microinches of nickel corrode. This work started because some, but not all, lots of connectors held in KC stores for a decade had been destroyed by pore corrosion (chemical corrosion). We have identified a MIL-L-87177 lubricant that absolutely stops chemical corrosion on SA connectors, even in the most severe environments. For commercial connectors which typically have thinner plating thicknesses, not only does the lubricant significantly retard effects of chemical corrosion, but also it greatly prolongs the fretting life. This report highlights the initial development history and use of the lubricant at Bell Labs and AT&T, and the Battelle studies and the USAF experience that lead to its deployment to stop dangerous connector corrosion on the F-16. We report the Sandia, HFM&T and Battelle development work, connector qualification, and material compatibility studies that demonstrate its usefulness and safety on JTA and WR systems. We will be applying MIL-L-87177 Connector Lubricant to all new connectors that go into KC stores. We recommend that it be applied to connectors on newly built cables and equipment as well as material that recycles through manufacturing locations from the field.

  5. Lubricant oil production: The proper marriage of process and catalyst technologies

    SciTech Connect (OSTI)

    Everett, G.L.; Suchanek, A.

    1996-12-01

    As the industry moves into the next millennium, higher product quality demands to meet the higher performance needs of modern engine technology and rising costs of traditional good quality lube crudes are driving lubricant base oil manufacturers to select hydroprocessing options versus traditional solvent refining techniques. This paper discusses how to properly select the best economic hydroprocessing technology necessary to produce high quality lubricant base oils and waxes. The economic success of such operations depends on the proper combination of process and catalyst technologies that maximizes yields of high quality products with minimum consumption of hydrogen resources and process utilities. This is particular true on the extreme end of the quality spectrum, namely, Very High Viscosity Index (VHVI) base oils and food grade white oils and waxes where there is no room for marginal product quality. Multiplicity of operations is also becoming more important as refiners try to upgrade their facilities with as little capital expense as possible, while at the same time, broaden their high valued product slate to recoup these expenses in the shortest possible payback period. Lyondell Licensing and Criterion Catalyst have put together an effective alliance based on years of development and commercial experience in both the process and catalyst areas to assist lubricant oil manufacturers in meeting these future challenges using as much existing equipment and infrastructure as is practical. Their experience will permit the proper fitting of the chemistry of hydroprocessing to make lubricant base oils to existing or new operations.

  6. Accelerated aging of solid lubricants for the W76-1 TSL : effects of polymer outgassing.

    SciTech Connect (OSTI)

    Dugger, Michael Thomas; Wallace, William O.; Huffman, Elizabeth M.

    2006-09-01

    The behavior of MoS{sub 2} lubricants intended for the W76-1 TSL was evaluated after 17 and 82 thermal cycles, each lasting seven days and including a low temperature of -35 C and a high temperature of 93 C, in a sealed container containing organic materials. The MoS{sub 2} was applied by tumbling with MoS{sub 2} powder and steel pins (harperized), or by spraying with a resin binder (AS Mix). Surface composition measurements indicated an uptake of carbon and silicon on the lubricant surfaces after aging. Oxidation of the MoS{sub 2} on harperized coupons, where enough MoS{sub 2} was present at the surface to result in significant Mo and S concentrations, was found to be minimal for the thermal cycles in an atmosphere of primarily nitrogen. Bare steel surfaces showed a reduction in friction for exposed coupons compared to control coupons stored in nitrogen, at least for the initial cycles of sliding until the adsorbed contaminants were worn away. Lubricated surfaces showed no more than a ten percent increase in steady-state friction coefficient after exposure. Initial coefficient of friction was up to 250 percent higher than steady-state for AS Mix films on H950 coupons after 82 thermal cycles. However, the friction coefficient exhibited by lubricated coupons was never greater than 0.25, and more often less than 0.15, even after the accelerated aging exposures.

  7. Mechanical face seals: Lubrication and wear resistance. (Latest citations from FLUIDEX data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The bibliography contains citations concerning the design, development and applications of mechanical face seals relative to antifriction behavior, improved materials, lubricant effects, and accelerated model wear tests. Performance evaluations in mining, gas turbine engines, and pumps are included. (Contains 250 citations and includes a subject term index and title list.)

  8. Performance requirements and case histories for a specialized industrial gear lubricant for use in underground coal mining

    SciTech Connect (OSTI)

    Hart, M.D.

    1993-12-31

    The recent release of a new gear lubricant specification by an original equipment manufacturer from the mining industry is an indication that the need for a new specification is recognized in other segments of the mining industry. unfortunately, this new specification appears too ambitious in at least one of it`s performance requirements and not ambitious enough in some of it`s other requirements. This new specification requires that the lubricant be able to emulsify 50% (by volume) water for at least 24 hours. It is technically difficult to achieve this goal and at the same time retain some of the other properties that are essential to the success of a specialized lubricant for underground mining applications. The ability to maintain excellent anti-wear and extreme pressure performance even when water and solid contamination is present is one such property. This effort to incorporate contamination tolerance into a gear lubricant specification should be applauded but it also needs to be recognized that any new gear lubricant specification that attempts to do so should be based on and evolved from existing specialized gear lubricants. A review of the data presented leads to the conclusion that there needs to be a better benchmark available to insure that the enclosed gear lubricants used in underground mining will provide the best service possible. It is more than a matter of upgrading the US Steel 224 lubricant specification. A new enclosed gear lubricant benchmark specification which deals with the important contamination issues that are found in the mining environment is needed.

  9. Production of Giant magnetocaloric Substances Using Commercially...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production of Giant magnetocaloric Substances Using Commercially Available Raw Materials ... To: Stacy Joiner *Name: *Email Address: Phone Number: Organization: ...

  10. Methods of contacting substances and microsystem contactors

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Rassat, Scot D [Benton City, WA; Stenkamp, Victoria S [Richland, WA

    2005-05-22

    A microchannel contactor and methods of contacting substances in microchannel apparatus are described. Some preferred embodiments are combined with microchannel heat exchange.

  11. Advanced Petroleum-Based Fuels -- Diesel Emissions Control Project (APBF-DEC): Lubricants Project, Phase 2 Final Report

    SciTech Connect (OSTI)

    Not Available

    2006-06-01

    This report summarizes the results of the second phase of a lubricants project, which investigated the impact of engine oil formulation on diesel vehicle emissions and the performance of a nitrogen oxide adsorber catalyst (NAC).

  12. Vapor-liquid equilibria for an R134a/lubricant mixture: Measurements and equation-of-state modeling

    SciTech Connect (OSTI)

    Huber, M.L.; Holcomb, C.D.; Outcalt, S.L.; Elliott, J.R.

    2000-07-01

    The authors measured bubble point pressures and coexisting liquid densities for two mixtures of R-134a and a polyolester (POE) lubricant. The mass fraction of the lubricant was approximately 9% and 12%, and the temperature ranged from 280 K to 355 K. The authors used the Elliott, Suresh, and Donohue (ESD) equation of state to model the bubble point pressure data. The bubble point pressures were represented with an average absolute deviation of 2.5%. A binary interaction parameter reduced the deviation to 1.4%. The authors also applied the ESD model to other R-134a/POE lubricant data in the literature. As the concentration of the lubricant increased, the performance of the model deteriorated markedly. However, the use of a single binary interaction parameter reduced the deviations significantly.

  13. Rate Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  14. Reliability of excess-flow check-valves in turbine lubrication systems

    SciTech Connect (OSTI)

    Dundas, R.E.

    1996-12-31

    Reliability studies on excess-flow check valves installed in a gas turbine lubrication system for prevention of spray fires subsequent to fracture or separation of lube lines were conducted. Fault-tree analyses are presented for the case of failure of a valve to close when called upon by separation of a downstream line, as well as for the case of accidental closure during normal operation, leading to interruption of lubricating oil flow to a bearing. The probabilities of either of these occurrences are evaluated. The results of a statistical analysis of accidental closure of excess-flow check valves in commercial airplanes in the period 1986--91 are also given, as well as a summary of reliability studies on the use of these valves in residential gas installations, conducted under the sponsorship of the Gas Research Institute.

  15. Lubricant return comparison of naphthenic and polyol ester oils in R-134a household refrigeration applications

    SciTech Connect (OSTI)

    Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R.

    1996-12-31

    This paper presents mineral oils and polyol esters as possible lubricant options for domestic refrigeration applications employing R-134a as the heat exchange fluid. A performance comparison, based on data presented, is made between the mineral oils and polyol esters evaluated. To more closely examine lubricant return with N-70 and R-134a and ensure that the oil is not contributing to any deterioration in efficiency due to its accumulation in evaporators, a special test unit was designed with a difficult oil return configuration and its performance carefully monitored. Oil return with a hydrofluorocarbon-miscible polyol ester, R-133-O was also evaluated in this setup and its performance results compared to those obtained with the naphthenic refrigeration oil.

  16. Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qu, Jun; Barnhill, William C.; Luo, Huimin; Meyer, III, Harry M.; Leonard, Donovan N.; Landauer, Alexander K.; Kheireddin, Bassem; Gao, Hong; Papke, Brian L; Dai, Sheng

    2015-07-14

    Unique synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the 30-70× higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.

  17. Near Zero Friction from Nanoscale Lubricants | U.S. DOE Office of Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SC) Near Zero Friction from Nanoscale Lubricants Advanced Scientific Computing Research (ASCR) ASCR Home About Research Facilities Science Highlights Benefits of ASCR Funding Opportunities Advanced Scientific Computing Advisory Committee (ASCAC) Community Resources Contact Information Advanced Scientific Computing Research U.S. Department of Energy SC-21/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-7486 F: (301) 903-4846 E: Email Us More Information »

  18. Near Zero Friction from Nanoscale Lubricants | U.S. DOE Office of Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SC) Near Zero Friction from Nanoscale Lubricants Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 10.01.15 Near Zero Friction from Nanoscale

  19. Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives

    SciTech Connect (OSTI)

    Qu, Jun; Barnhill, William C.; Luo, Huimin; Meyer, III, Harry M.; Leonard, Donovan N.; Landauer, Alexander K.; Kheireddin, Bassem; Gao, Hong; Papke, Brian L; Dai, Sheng

    2015-07-14

    Unique synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the 30-70 higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.

  20. Controlled Experiments on the Effects of Lubricant/Additive (Low-Ash,

    Broader source: Energy.gov (indexed) [DOE]

    Ashless) Characteristics on DPF Degradation | Department of Energy Effects of lubricant additive chemistries and exhaust conditions on ash properties affecting diesel particulate filter performance. Comparison of ash characteristics such as packing density and elemental composition in field and laboratory aged DPFs. PDF icon deer08_sappok.pdf More Documents & Publications Key Parameters Affecting DPF Performance Degradation and Impact on Lifetime Fuel Economy Characteristics and Effects

  1. The role of polymer formation during vapor phase lubrication of silicon.

    SciTech Connect (OSTI)

    Dugger, Michael Thomas; Dirk, Shawn M.; Ohlhausen, James Anthony

    2010-10-01

    The lubrication of silicon surfaces with alcohol vapors has recently been demonstrated. With a sufficient concentration of pentanol vapor present, sliding of a silica ball on an oxidized silicon wafer can proceed with no measurable wear. The initial results of time-of-flight secondary ion mass spectrometry (ToF-SIMS) analysis of wear surfaces revealed a reaction product having thickness on the order of a monolayer, and with an ion spectrum that included fragments having molecular weights of 200 or more that occurred only inside the wear tracks. The parent alcohol molecule pentanol, has molecular weight of 88amu, suggesting that reactions of adsorbed alcohols on the wearing surfaces allowed polymerization of the alcohols to form higher molecular weight species. In addition to pin-on-disk studies, lubrication of silicon surfaces with pentanol vapors has also been demonstrated using MicroElectroMechanical Systems (MEMS) devices. Recent investigations of the reaction mechanisms of the alcohol molecules with the oxidized silicon surfaces have shown that wearless sliding requires a concentration of the alcohol vapor that is dependent upon the contact stress during sliding, with higher stress requiring a greater concentration of alcohol. Different vapor precursors including those with acid functionality, olefins, and methyl termination also produce polymeric reaction products, and can lubricate the silica surfaces. Doping the operating environment with oxygen was found to quench the formation of the polymeric reaction product, and demonstrates that polymer formation is not necessary for wearless sliding.

  2. Post Irradiation Evaluation of Thermal Control Coatings and Solid Lubricants to Support Fission Surface Power Systems

    SciTech Connect (OSTI)

    Bowman, Cheryl L.; Jaworske, Donald A.; Stanford, Malcolm K.; Persinger, Justin A.; Khorsandi, Behrooz; Blue, Thomas E.

    2007-01-30

    The development of a nuclear power system for space missions, such as the Jupiter Icy Moons Orbiter or a lunar outpost, requires substantially more compact reactor design than conventional terrestrial systems. In order to minimize shielding requirements and hence system weight, the radiation tolerance of component materials within the power conversion and heat rejection systems must be defined. Two classes of coatings, thermal control paints and solid lubricants, were identified as material systems for which limited radiation hardness information was available. Screening studies were designed to explore candidate coatings under a predominately fast neutron spectrum. The Ohio State Research Reactor Facility staff performed irradiation in a well characterized, mixed energy spectrum and performed post irradiation analysis of representative coatings for thermal control and solid lubricant applications. Thermal control paints were evaluated for 1 MeV equivalent fluences from 1013 to 1015 n/cm2. No optical degradation was noted although some adhesive degradation was found at higher fluence levels. Solid lubricant coatings were evaluated for 1 MeV equivalent fluences from 1015 to 1016 n/cm2 with coating adhesion and flexibility used for post irradiation evaluation screening. The exposures studied did not lead to obvious property degradation indicating the coatings would have survived the radiation environment for the previously proposed Jupiter mission. The results are also applicable to space power development programs such as fission surface power for future lunar and Mars missions.

  3. Oil-Miscible and Non-Corrosive Phosphonium Ionic Liquids as Candidate Lubricant Additives

    SciTech Connect (OSTI)

    Yu, Bo; Bansal, Dinesh G; Qu, Jun; Sun, Xiaoqi; Luo, Huimin; Dai, Sheng; Blau, Peter Julian; Bunting, Bruce G; Mordukhovich, Gregory; Smolenski, Donald

    2012-01-01

    Ionic liquids (ILs) have been receiving considerable attention from the lubricants industry as potential friction and wear-reducing additives, but their solubility in oils is an issue. Unlike most ionic liquids that are insoluble in non-polar hydrocarbon oils, this study reports phosphonium-based ILs (PP-ILs) that are fully miscible with both mineral oil-based and synthetic lubricants. Both the cation and anion in quaternary structures, long alkyl chains, and capability of pairing the cation and the anion via a H-O bond are hypothesized to improve the compatibility between ions and neutral oil molecules. The measured viscosities of the oil-IL blends agree well with the Refutas equation that is for solutions containing multiple components. High thermal stability and non-corrosiveness were observed for the PP-ILs. Effective friction reduction and anti-wear functionality have been demonstrated in tribological tests when adding 5 wt% of a PP-IL into a base oil, suggesting potential applications for using the oil-miscible PP-ILs as lubricant additives.

  4. US Synthetic Corp (TRL 4 Component)- The Development of Open, Water Lubricated Polycrystalline Diamond Thrust Bearings for use in Marine Hydrokinetic (MHK) Energy Machines

    Broader source: Energy.gov [DOE]

    US Synthetic Corp (TRL 4 Component) - The Development of Open, Water Lubricated Polycrystalline Diamond Thrust Bearings for use in Marine Hydrokinetic (MHK) Energy Machines

  5. Synthesis of monodispersed ZnAl{sub 2}O{sub 4} nanoparticles and their tribology properties as lubricant additives

    SciTech Connect (OSTI)

    Song, Xiaoyun; Zheng, Shaohua; Zhang, Jun; Li, Wei; Chen, Qiang; Cao, Bingqiang

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? The preparation of ZnAl{sub 2}O{sub 4} nanoparticles was realized by hydrothermal method. ? After surface modification, ZnAl{sub 2}O{sub 4} nanoparticles of narrow size distribution can disperse in lubricating oil stably. ? The modified ZnAl{sub 2}O{sub 4} nanoparticles as lubricating oil additives exhibit good tribology properties. -- Abstract: Monodispersed spherical zinc aluminate spinel (ZnAl{sub 2}O{sub 4}) nanoparticles were synthesized via a solvothermal method and modified by oleic acid in cyclohexanol solution. The nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and infrared spectrum (IR). The dispersion ability of nanoparticles in lubricant oil was measured with optical absorbance spectrum. The results show that the modified nanoparticles are nearly monodispersed and can stably disperse in lubricant oil. The tribological properties of the ZnAl{sub 2}O{sub 4} nanoparticles as an additive in lubricant oil were evaluated with four-ball test and thrust-ring test. For comparison, ZnO and Al{sub 2}O{sub 3} nanoparticles as additive in lubricant oil were also tested respectively. The results show that ZnAl{sub 2}O{sub 4} nanoparticles exhibit better tribology properties in terms of anti-wear and anti-friction than ZnO or Al{sub 2}O{sub 3} nanoparticles. The anti-friction and anti-wear mechanisms were discussed and the lubricating effect of ZnAl{sub 2}O{sub 4} nanoparticles can be attributed to nano-bearings effect and tribo-sintering mechanism.

  6. Toxic Substances Control Act Uranium Enrichment Federal Facility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Toxic Substances Control Act Uranium Enrichment Federal Facility Compliance Agreement Toxic Substances Control Act Uranium Enrichment Federal Facility Compliance Agreement Toxic ...

  7. Materials Compatibility and Lubricants Research on CFC-refrigerant substitutes. Quarterly MCLR Program technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Szymurski, S.R.; Hourahan, G.C.; Godwin, D.S.; Amrane, K.

    1995-10-01

    The Materials Compatibility and Lubricants Research (MCLR) program supports critical research to accelerate the introduction of CFC and HCFC refrigerant substitutes. The MCLR program addresses refrigerant and lubricant properties and materials compatibility. The primary elements of the work include data collection and dissemination, materials compatibility testing, and methods development. This report summarizes the research conducted during the third quarter of calendar year 1995 on the following projects: Thermophysical properties of HCFC alternatives; Compatibility of manufacturing process fluids with HFC refrigerants and ester lubricants; Compatibility of motor materials used in air-conditioning for retrofits with alternative refrigerants and lubricants; Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants; Products of motor burnouts; Accelerated test methods for predicting the life of motor materials exposed to refrigerant-lubricant mixtures; Investigation of flushing and clean-out methods; Investigation into the fractionation of refrigerant blends; Lean flammability limits as a fundamental refrigerant property; Effect of selected contaminants in AC and R equipment; Study of foaming characteristics; Study of lubricant circulation in systems; Evaluation of HFC-245ca for commercial use in low pressure chillers; Infrared analysis of refrigerant mixtures; Refrigerant database; Refrigerant toxicity survey; Thermophysical properties of HFC-32, HFC-123, HCFC-124 and HFC-125; Thermophysical properties of HFC-143a and HFC-152a; Theoretical evaluations of R-22 alternative fluids; Chemical and thermal stability of refrigerant-lubricant mixtures with metals; Miscibility of lubricants with refrigerants; Viscosity, solubility and density measurements of refrigerant-lubricant mixtures; Electrohydrodynamic enhancement of pool and in-tube boiling of alternative refrigerants; Accelerated screening methods; and more.

  8. Biodiesel Impact on Engine Lubricant Dilution During Active Regeneration of Aftertreatment Systems

    SciTech Connect (OSTI)

    He, X.; Williams, A.; Christensen, E.; Burton, J.; McCormick, R.

    2011-12-01

    Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution. Stage two consisted of 16 hours of normal engine operation over a transient test cycle, which created an opportunity for any accumulated fuel in the oil sump to evaporate. Light duty (LD) vehicle testing was conducted on a 2010 VW Jetta equipped with DOC, DPF and a NOx storage catalyst (NSC). Vehicle testing comprised approximately 4,000 miles of operation on a mileage-accumulation dynamometer (MAD) using the U.S. Environmental Protection Agency's Highway Fuel Economy Cycle because of the relatively low engine oil and exhaust temperatures, and high DPF regeneration frequency of this cycle relative to other cycles examined. Comparison of the lube oil dilution analysis methods suggests that D3524 does not measure dilution by biodiesel. The new back-flush GC method provided analysis for both diesel and biodiesel, in a shorter time and with lower detection limit. Thus all lube oil dilution results in this paper are based on this method. Analysis of the HD lube-oil samples showed only 1.5% to 1.6% fuel dilution for both fuels during continuous operation under DPF regeneration events. During the second stage of HD testing, the ULSD lube-oil dilution levels fell from 1.5% to 0.8%, while for B20, lube-oil dilution levels fell from 1.6% to 1.0%, but the fuel in the oil was 36% biodiesel. For the LD vehicle tests, the frequency of DPF regeneration events was observed to be the same for both ULSD and B20. No significant difference between the two fuels' estimated soot loading was detected by the engine control unit (ECU), although a 23% slower rate of increase in differential pressure across DPF was observed with B20. It appears that the ECU estimated soot loading is based on the engine map, not taking advantage of the lower engine-out particulate matter from the use of biodiesel. After 4,000 miles of LD vehicle operation with ULSD, fuel dilution in the lube-oil samples showed total dilution levels of 4.1% diesel. After 4,000 miles of operation with B20, total fuel in oil dilution levels were 6.7% consisting of 3.6% diesel fuel and 3.1% biodiesel. Extrapolation to the 10,000-mile oil drain interval with B20 suggests that the total fuel content in the oil could reach 12%, compared to 5% for operation on ULSD. Analysis of the oil samples also included measurement of total acid number, total base number, viscosity, soot, metals and wear scar; however, little difference in these parameters was noted.

  9. A comparison of the heat transfer and pressure drop performance of R-134a-lubricant mixtures in different diameter smooth tubes and micro-fin tubes

    SciTech Connect (OSTI)

    Eckels, S.J.; Doerr, T.M.; Pate, M.B.

    1998-10-01

    The average heat transfer coefficients and pressure drops during evaporation and condensation are reported for mixtures of R-134a and an ester lubricant in tubes of 12.7 mm (1/2 in.) outer diameter. The objective of this paper is to evaluate the performance of the R-134a-lubricant mixtures in these tubes and determine the performance benefits of the micro-fin tube. The performance benefits of the tubes with 12.7 mm (1/2 in.) outer diameter are compared to those of smaller tubes with 9.52 mm (3/8 in.) outer diameter. The lubricant used was a 169 SUS penta erythritol ester mixed-acid lubricant. The lubricant concentration was varied from 0--5.1% in the mixture. The average heat transfer coefficients in the 12.7 mm (1/2 in.) micro-fin tube were 50--150% higher than those for the 12.7 mm (1/2 in.) smooth tube, while pressure drops in the micro-fin tube were 5% to 50% higher than in the smooth tube. The addition of lubricant degraded the average heat transfer coefficients in all cases except during evaporation at low lubricant concentrations. Pressure drops were always increased with the addition of lubricant. The experimental results also indicate that tube diameter has some effect on the performance benefits of the micro-fin tube over that of the smooth tube.

  10. Rate Schedules

    Broader source: Energy.gov [DOE]

    One of the major responsibilities of Southeastern is to design, formulate, and justify rate schedules. Repayment studies prepared by the agency determine revenue requirements and appropriate rate...

  11. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vogel, Nicolas; Belisle, Rebecca A.; Hatton, Benjamin; Wong, Tak-Sing; Aizenberg, Joanna

    2013-07-31

    A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show howmore » this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.« less

  12. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

    SciTech Connect (OSTI)

    Vogel, N; Belisle, RA; Hatton, B; Wong, TS; Aizenberg, J

    2013-07-31

    A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show how this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.

  13. Lubricants Activities

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  14. Intelligent emissions controller for substance injection in the post-primary combustion zone of fossil-fired boilers

    DOE Patents [OSTI]

    Reifman, Jaques; Feldman, Earl E.; Wei, Thomas Y. C.; Glickert, Roger W.

    2003-01-01

    The control of emissions from fossil-fired boilers wherein an injection of substances above the primary combustion zone employs multi-layer feedforward artificial neural networks for modeling static nonlinear relationships between the distribution of injected substances into the upper region of the furnace and the emissions exiting the furnace. Multivariable nonlinear constrained optimization algorithms use the mathematical expressions from the artificial neural networks to provide the optimal substance distribution that minimizes emission levels for a given total substance injection rate. Based upon the optimal operating conditions from the optimization algorithms, the incremental substance cost per unit of emissions reduction, and the open-market price per unit of emissions reduction, the intelligent emissions controller allows for the determination of whether it is more cost-effective to achieve additional increments in emission reduction through the injection of additional substance or through the purchase of emission credits on the open market. This is of particular interest to fossil-fired electrical power plant operators. The intelligent emission controller is particularly adapted for determining the economical control of such pollutants as oxides of nitrogen (NO.sub.x) and carbon monoxide (CO) emitted by fossil-fired boilers by the selective introduction of multiple inputs of substances (such as natural gas, ammonia, oil, water-oil emulsion, coal-water slurry and/or urea, and combinations of these substances) above the primary combustion zone of fossil-fired boilers.

  15. Does the Use of Diamond-Like Carbon Coating and Organophosphate Lubricant Additive Together Cause Excessive Tribochemical Material Removal?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yan; Leonard, Donovan N.; Meyer, Harry M.; Luo, Huimin; Qu, Jun

    2015-08-22

    We observe unexpected wear increase on a steel surface that rubbed against diamond-like carbon (DLC) coatings only when lubricated by phosphate-based antiwear additives. Contrary to the literature hypothesis of a competition between zinc dialkyldithiophosphate produced tribofilms and DLC-induced carbon transfer, here a new wear mechanism based on carbon-catalyzed tribochemical interactions supported by surface characterization is proposed

  16. Study of fractionation of refrigerant blends in contact with lubricants and measurement of the solubility, density, and viscosity

    SciTech Connect (OSTI)

    Cavestri, R.C.; Falconi, E.A.

    1999-07-01

    The fractionation of two refrigerant blends was studied using the gas equilibrium method. The amount of fractionation was measured by maintaining a constant composition of the refrigerant gas vapor over the lubricant, which was equal in composition to the liquid refrigerant gas blend introduced into the viscometer. Specifically, the concentration of the dissolved refrigerant gas in the lubricant ranges from 0.6% to 78% by weight in the specified temperature range of {minus}25 C to 125 C and within the highest test pressure of 500 psia (3.45 MPa). The polyolester chosen for this study was a 32 ISO VG complex branched acid pentaerythritol product. Smoothed graphical data presented were obtained from individual isothermal measurements. These individual isothermal measurement temperatures detail the composition of the equilibrium gas fractionation of R-32 and R-134a in the lubricant, mixed vapor pressure, concentration of the total mixed blend as percent by weight in the lubricant and viscosity in centipoise (cP) and centistokes (cSt). The raw data are presented in a smoothed graphical form based on a fixed vapor composition.

  17. Court decision dropping toxic substance rules stands

    SciTech Connect (OSTI)

    Bryant, C.R.

    1993-06-01

    In a somewhat surprising move, the U.S. Department of Labor has decided not to appeal a court decision essentially dropping regulations established by the Occupational Safety and Health Administration (OSHA) for about 400 hazardous substances. The decision leaves unregulated or subject to reduced standards substances that range from carbon monoxide to perchloroethylene. The Labor Department had until March 22, 1993, to appeal the court decision. On July 8, 1992, the U.S. Court of Appeals for the 11th Circuit overturned OSHA's final Air Contaminants Standard, which was promulgated in 1989. The standard established permissible exposure limits (PELs) for 428 toxic substances. In AFL-CIO vs. OSHA, the Court ruled that OSHA failed to make a separate scientific case for evaluating health risks of each chemical. Because of the decision not to appeal, PELs for more than half of the substances regulated by OSHA now are removed from the books or revert to the voluntary industry standards adopted by OSHA in 1970 and in force prior to the 1989 final rule.

  18. Development of Modified Pag (Polyalkylene Glycol) High VI High Fuel Efficient Lubricant for LDV Applications

    SciTech Connect (OSTI)

    Gangopadhyay, Arup; McWatt, D. G.; Zdrodowski, R. J.; Liu, Zak; Elie, Larry; Simko, S. J.; Erdemir, Ali; Ramirez, Giovanni; Cuthbert, J.; Hock, E. D.

    2015-09-30

    Engine oils play a critical role in friction reduction. Improvements in engine oil technology steadily improved fuel economy as the industry moved through ILSAC GF-1 to GF-5 specifications. These improvements were influenced by changes in base oil chemistry, development of new friction modifiers and their treat levels, and the total additive package consisting of various other components. However, the improvements are incremental and further fuel consumption reduction opportunities are becoming more challenging. Polyalkylene glycol (PAG) based engine oils are being explored as a step forward for significant fuel consumption reduction. Although PAG fluids are used in many industrial applications, its application as an engine oil has been explored in a limited way. The objective of this project is to deep dive in exploring the applicability of PAG technology in engine oil, understanding the benefits, and limitations, elucidating the mechanism(s) for friction benefits, if any, and finally recommending how to address any limitations. The project was designed in four steps, starting with selection of lubricant technology, followed by friction and wear evaluations in laboratory bench tests which are relatively simple and inexpensive and also served as a screener for further evaluation. Selected formulations were chosen for more complex engine component level tests i.e., motored valvetrain friction and wear, piston ring friction using a motored single cylinder, and motored engine tests. A couple of formulations were further selected based on component level tests for engine dyno tests i.e., Sequence VID (ASTM D6709) for fuel economy, Sequence IVA (ASTM D6891) for valvetrain wear, and Sequence VG (ASTM D6593) for sludge and varnish protection. These are some of the industry standard tests required for qualifying engine oils. Out of these tests, a single PAG oil was selected for chassis roll dynamometer tests for fuel economy and emission measurements using FTP (Federal Test Procedure) metro/highway cycles. Five different PAG chemistries were selected by varying the starting alcohol, the oxide monomers (ethylene oxide, propylene oxide, or butylene oxide), capped or uncapped, homopolymer or random copolymer. All formulations contained a proprietary additive package and one which contained additional antiwear and friction modifier additives. Laboratory bench tests (Pin-on-Disk, High Frequency Reciprocating Rig (HFRR), Block-on-Ring, Mini-Traction Machine (MTM) identified formulations having friction, wear, and load carrying characteristics similar to or better than baseline GF-5 SAE 5W-20 oil. Motored valvetrain and motored piston ring friction tests showed nearly 50% friction reduction for some of the PAG formulations compared to GF-5 SAE 5W-20 oil. Motored engine tests showed up to 15% friction benefit over GF-5 SAE 5W-20 oil. It was observed that friction benefits are more related to PAG base oil chemistry than their lower viscosity compared to GF-5 SAE 5W-20 oil. Analysis of wear surfaces from laboratory bench tests and bucket tappets from motored valvetrain tests confirmed the presence of PAG molecules. The adsorption of these polar molecules is believed to be reason for friction reduction. However, the wear surfaces also had thin tribo-film derived from additive components. The tribo-film consisting of phosphates, sulfides, and molybdenum disulfide (when molybdenum additive was present) were observed for both GF-5 SAE 5W-20 and PAG fluids. However, when using PAG fluids, motored valvetrain tests showed high initial wear, which is believed to be due to delay in protective tribo-film formation. After the initial wear, the wear rate of PAG fluids was comparable to GF-5 SAE 5W-20 oil. The PAG oil containing additional antiwear and friction reducing additives showed low initial wear as expected. However, when this oil was evaluated in Sequence IVA test, it showed initially low wear comparable to GF-5 oil but wear accelerated with oil aging indicating rapid deterioration of additive components. ASTM Sequence VG test showed good sludge protection capability but failed to meet varnish rating for GF-5 requirement. Chassis roll dynamometer tests with PAG oil 15-1 showed about 1% fuel economy benefit over GF-5 SAE 5W-20 oil in EPA city cycles only and when the oil was slightly aged (500 miles). No fuel economy benefits could be observed in combined EPA metro/highway cycles. Also, no fuel economy benefit could be observed with continued (500- 10000 miles) oil aging. However, the emission level was comparable to the reference oil and was within EPA limits. Analysis of the PAG oil following tests showed low iron content although additive components were significantly degraded. The results indicate that PAG fluids have significant friction reduction potential but there are challenges with wear and varnish protection capabilities. These limitations are primarily because the selected additive components were chosen to provide a fluid with no metal content that forms little or no sulphated ash. Significant development work is needed to identify additive components compatible with PAG chemistry including their solubility in PAG oil. Miscibility of PAG fluids with mineral base oil is another challenge for oil change service. There is PAG chemistry (oil soluble PAG, OSP) which is soluble in mineral oils but the formulation explored in this investigation did not show significant friction reduction in motored engine tests. Again, highlighting the need for additive development for specific PAG chemistry. The thermal oxidation behavior of these oils has not been explored in this investigation and needs attention.

  19. Lubricating system for thermal medium delivery parts in a gas turbine

    DOE Patents [OSTI]

    Mashey, Thomas Charles (Coxsackie, NY)

    2002-01-01

    Cooling steam delivery tubes extend axially along the outer rim of a gas turbine rotor for supplying cooling steam to and returning spent cooling steam from the turbine buckets. Because of the high friction forces at the interface of the tubes and supporting elements due to rotor rotation, a low coefficient of friction coating is provided at the interface of the tubes and support elements. On each surface, a first coating of a cobalt-based alloy is sprayed onto the surface at high temperature. A portion of the first coating is machined off to provide a smooth, hard surface. A second ceramic-based solid film lubricant is sprayed onto the first coating. By reducing the resistance to axial displacement of the tubes relative to the supporting elements due to thermal expansion, the service life of the tubes is substantially extended.

  20. Lubricant-infused micro/nano-structured surfaces with tunable dynamic omniphobicity at high temperatures

    SciTech Connect (OSTI)

    Daniel, D; Mankin, MN; Belisle, RA; Wong, TS; Aizenberg, J

    2013-06-10

    Omniphobic surfaces that can repel fluids at temperatures higher than 100 degrees C are rare. Most state-of-the-art liquid-repellent materials are based on the lotus effect, where a thin air layer is maintained throughout micro/nanotextures leading to high mobility of liquids. However, such behavior eventually fails at elevated temperatures when the surface tension of test liquids decreases significantly. Here, we demonstrate a class of lubricant-infused structured surfaces that can maintain a robust omniphobic state even for low-surface-tension liquids at temperatures up to at least 200 degrees C. We also demonstrate how liquid mobility on such surfaces can be tuned by a factor of 1000. (C) 2013 Author(s).

  1. Effects of self-assembled monolayer and PFPE lubricant on wear characteristics of flat silicon tips.

    SciTech Connect (OSTI)

    Kim, H. J.; Jang, C. E.; Kim, D. E.; Kim, Y. K.; Choa, S. H.; Hong, S.; Materials Science Division; Yonsei Univ.; Samsung Adv. Inst. Science and Technology; Seoul National Univ. of Technology

    2009-01-01

    The effects of self-assembled monolayer (SAM) and perfluoropolyether (PFPE) lubricant on the wear characteristics of flat silicon tips were investigated. The wear test consisted of sliding the silicon tips fabricated on a flat silicon specimen against SAM and PFPE (Z-tetraol) coated silicon (100) wafer. The tips were slid at a low speed for about 15 km under an applied load of 39.2 {micro}N. The wear volume of the tip was obtained by measuring the tip profile using an Atomic Force Microscope (AFM). It was found that the coatings were effective in reducing the wear of the tips by an order of magnitude from 10{sup -6} to 10{sup -7}.

  2. Lubricant-infused micro/nano-structured surfaces with tunable dynamic omniphobicity at high temperatures

    SciTech Connect (OSTI)

    Daniel, Daniel; Max, Mankin N.; Belisle, Rebecca A.; Wong, Tak-Sing; Aizenberg, Joanna

    2013-06-12

    Omniphobic surfaces that can repel fluids at temperatures higher than 100 #2;C are rare. Most stateof- the-art liquid-repellent materials are based on the lotus effect, where a thin air layer is maintained throughout micro/nanotextures leading to high mobility of liquids. However, such behavior eventually fails at elevated temperatures when the surface tension of test liquids decreases significantly. Here, we demonstrate a class of lubricant-infused structured surfaces that can maintain a robust omniphobic state even for low-surface-tension liquids at temperatures up to at least 200 #2;C. We also demonstrate how liquid mobility on such surfaces can be tuned by a factor of 1000.

  3. Scuffing initiation in metals sliding against copper under non-lubricated conditions

    SciTech Connect (OSTI)

    Kovalchenko, A M; Blau, Peter Julian; Qu, Jun; Danyluk, S

    2011-01-01

    Metallic components in sliding contact are sometimes subjected to high-loads with little or no lubrication. Such starved conditions can lead to a phenomenon called scuffing. Various definitions exist for this term, but in the present case, three criteria were used to signal its onset: changes in friction, vibrations, and noise, coupled with surface examination. On this basis, scuffing initiation was determined for seven technically pure metals (Al, Mo, Nb, Ta, Ti, W, Cu) and stainless steel, all rubbing against Cu. A flat-ended pin-on-disk test configuration was used with normal loads of 1-3 N, and with step-wise increases in sliding speed from 0.16 to 2.56 m/s. Al was only weakly resistant to scuffing, presumably due to its solubility in Cu, its high ductility and its relatively low elastic modulus. Niobium provided satisfactory sliding behavior at low speeds and loads, presumably due to protective oxides; however, it scuffed at higher loads when the oxide broke through. Stainless steel, Mo, and Ta had higher friction coefficients than Al and Nb, presumably because the relatively high strengths of the former prevented severe wear even when their oxide films failed. Like Al, Ti scuffs on Cu, probably because of its high relative solubility; however, Ti's higher elastic modulus resists the more severe forms of surface damage than does Al. Of all the materials slid against Cu, W displayed the least scuffing, even under maximum speed and load. Tungsten's negligible solubility in Cu may have reduced its adhesion, and W's high elastic modulus resisted shear-deformation, even at high frictional heating. Self-mated Cu couple scuffed when the speed was increased. The oxides on the Cu surface serve as solid lubricant avoiding scuffing at lower speeds.

  4. Finance & Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    all of its costs in the rates it charges customers for wholesale electricity and transmission services. The agency is committed to careful cost management consistent with its...

  5. Toxic Substances Control Act Uranium Enrichment Federal Facility Compliance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agreement | Department of Energy Toxic Substances Control Act Uranium Enrichment Federal Facility Compliance Agreement Toxic Substances Control Act Uranium Enrichment Federal Facility Compliance Agreement Toxic Substances Control Act (TSCA) Uranium Enrichment Federal Facility Compliance Agreement establishes a plan to bring DOE's Uranium Enrichment Plants (and support facilities) located in Portsmouth, Ohio and Paducah, Kentucky and DOE's former Uranium Enrichment Plant (and support

  6. Heat transfer coefficients and pressure drops for R-134a and an ester lubricant mixture in a smooth tube and a micro-fin tube

    SciTech Connect (OSTI)

    Eckels, S.J.; Doerr, T.M.; Pate, M.B.

    1998-10-01

    This paper reports average heat transfer coefficients and pressure drops during the evaporation and condensation of mixtures of R-134a and a 150 SUS penta erythritol ester branched-acid lubricant. The smooth tube and micro-fin tube tested in this study had outer diameters of 9.52 mm (3/8 in.). The micro-fin tube had 60 fins, a fin height of 0.2 mm (0.008 in), and a spiral angle of 18{degree}. The objective of this study is to evaluate the effectiveness of the micro-fin tube with R-134a and to determine the effect of circulating lubricant. The experimental results show that the micro-fin tube has distinct performance advantages over the smooth tube. For example, the average heat transfer coefficients during evaporation and condensation in the micro-fin tube were 50--200% higher than those for the smooth tube, while the average pressure drops were on average only 10--50% higher. The experimental results indicate that the presence of a lubricant degrades the average heat transfer coefficients during both evaporation and condensation at high lubricant concentrations. Pressure drops during evaporation increased with the addition of a lubricant in both tubes. For condensation, pressure drops were unaffected by the addition of a lubricant.

  7. Accelerated screening methods for determining chemical and thermal stability of refreigerant-lubricant mixtures. Part II: Experimental comparison and verification of methods. Final report, volume I

    SciTech Connect (OSTI)

    Kauffman, R.

    1995-09-01

    The research reported herein was performed to develop an accelerated screening method for determining the chemical and thermal stabilities of refrigerant/lubricant mixtures. The developed screening method was designed to be safe and to produce accelerated stability rankings that are in agreement with the rankings determined by the current test, Sealed Glass Tube Method to Test the Chemical Stability of Material for Use Within Refrigerant Systems, ANSI/ASHRAE Method 97-1989. The accelerated screening test developed was designed to be independent of refrigerant and lubricant compositions and to be used with a wide variety of construction materials. The studied refrigerants included CFC-11, CFC-12, HCFC-22, HFC-134a, and HFC-32/HFC-134a (zeotrope 30:70 by weight). The studied lubricants were selected from the chemical classes of mineral oil, alkylbenzene oil, polyglycols, and polyolesters. The work reported herein was performed in three phases. In the first phase, previously identified thermal analytical techniques were evaluated for development into an accelerated screening method for refrigerant/lubricant mixtures. The identified thermal analytical techniques used in situ measurements of color, temperature, or conductivity to monitor the degradation of the heated refrigerant/lubricant mixtures. The identified thermal analytical techniques also used catalysts such as ferric fluoride to accelerate the degradation of the heated refrigerant/lubricant mixtures. The thermal analytical technique employing in situ conductivity measurements was determined to be the most suitable for development into an accelerated screening method.

  8. Lubricant-Infused Nanoparticulate Coatings Assembled by Layer-by-Layer Deposition

    SciTech Connect (OSTI)

    Sunny, S; Vogel, N; Howell, C; Vu, TL; Aizenberg, J

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introduce sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. The LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.

  9. Rolling contact fatigue in high vacuum using ion plated nickel-copper-silver solid lubrication

    SciTech Connect (OSTI)

    Danyluk, Mike; Dhingra, Anoop

    2011-01-15

    Ion plated, nickel-copper-silver coated steel ball bearings that were tested in rolling contact fatigue (RCF) experiments in high vacuum are presented in this article. ANSI T5 ball bearings were coated with approximately 10 nm of nickel-copper followed by 100 nm of silver using a dc ion plating process. The balls were then tested for RCF in vacuum in the 10{sup -7} Torr range at 130 Hz rotational speed and at 4.1 GPa Hertzian contact stress. The significance of this work is in the extension of RCF testing to an ultrahigh vacuum (UHV) application using silver as a lubricant instead of oil. The effects of pressure and voltage on the ion plating process were also investigated using scanning electron microscopy and RCF life testing in UHV. Test results with a ball size of 5/16 in. in UHV show that deposition at voltages greater than 2.5 kV shortens the RCF life and introduces a unique failure mode. Voltage and pressure fluctuations during the deposition process result in significant thickness monitor measurement errors as well. A regulator control scheme that minimizes the process pressure overshoot is also simulated.

  10. Probing the molecular design of hyper-branched aryl polyesters towards lubricant applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Robinson, Joshua W.; Zhou, Yan; Bhattacharya, Priyanka; Erck, Robert; Qu, Jun; Bays, J. Timothy; Cosimbescu, Lelia

    2016-01-05

    We report novel polymeric materials that may be used as viscosity index improvers (VII) for lubricant applications. Our efforts included probing the comb-burst hyper-branched aryl polyester architecture for beneficial viscosity and friction behavior when utilized as an additive in a group I oil. The monomer was designed as to undergo polymerization via polycondensation within the architectural construct (AB2), typical of hyperbranched polymers. The monomer design was comprised of aliphatic arms (12 or 16 methylenes) to provide the necessary lipophilicity to achieve solubility in a non-polar medium. Once polymerized, via catalyst and heat, the surface alcohols were functionalized with fatty acidsmore » (lauric and palmitic). Controlling the aliphatic nature of the internal arms and peripheral end-groups provided four unique flexible polymer designs. Changing the reaction time and concentration provided opportunities to investigate the influence of molecular weight and branching density on oil-solubility, viscosity, and friction. Oil-solubility was found to decrease with fewer internal carbons, but the number of internal carbons appears to have little influence on the bulk solution viscosity. Increased branching and degree of polymerization, and thus molecular weight, were found to reduce the solubility of these systems in the base oil. At concentrations of 2 wt % in a group I base oil, these polymer additives demonstrated improved viscosity index and reduced friction coefficient, validating the basic approach.« less

  11. Gas chromatographic determination of residual solvents in lubricating oils and waxes

    SciTech Connect (OSTI)

    De Andrade Bruening, I.M.R.

    1983-10-01

    A direct gas-liquid chromatographic analysis of residual solvents is described, using tert-butylbenzene as an internal standard. The lube oils and waxes were prevented from contaminating the chromatographic column by injecting the samples directly into a precolumn containing a silicone stationary phase. The samples of lube oils and waxes were injected directly into the chromatographic column containing another stationary phase, 1,2,3-tris(2-cyanoethoxy)propane. (The waxy samples were dissolved in a light neutral oil). With proper operating conditions, analysis time was 7 min. The procedure has been applied in the control of a lube oil dewaxing plant; the chromatographic column showed no sign of deterioration after 1 h when the precolumn was removed. Known amounts of toluene and methylethyl ketone were added to the solvent-free lubricating oils and wax, and these mixtures were analyzed to evaluate the accuracy of the procedure. Precision and accuracy of these data are comparable to those of methods previously described. 1 figure, 1 table.

  12. Generation of defects in model lubricant monolayers and their contribution to energy dissipation in friction

    SciTech Connect (OSTI)

    Salmeron, Miquel

    2000-06-15

    The structural, mechanical (friction) and spectroscopic properties of model lubricant films made of self-assembled and Langmuir-Blodgett monolayers on quartz, mica and gold have been investigated with atomic force microscopy, surface forces apparatus and sum frequency generation. In these films, the molecules tend to form densely packed structures, with the alkane chains mostly vertical and parallel to each other. The SFG results suggest that under moderate pressures of a few tens of MPa, the methyl end group of the alkane chains is rotated to accommodate a terminal gauche distortion. The molecule,however, retains its upright close packed structure with a lattice periodicity when ordered, which can be resolved by AFM. At pressures above 0.1 GPa, changes in the form of collective molecular tilts take place that lower the height of the monolayer. Only certain angles of tilt are allowed that are explained by the interlocking of methylene units in neighboring chains. The discrete angular tilts are accompanied by increases in friction. A model based on the van derWaals attractive energy between chains is used to explain the stability of the films and to estimate the cohesive energy changes during tilt and, from that, the increases in friction force.

  13. Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition

    SciTech Connect (OSTI)

    Sunny, Steffi; Vogel, Nicolas; Howell, Caitlin; Vu, Thy L.; Aizenberg, Joanna

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introduce sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. As a result, the LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.

  14. Cold starting capabilities of petroleum and syntehetic lubricants in heavy-duty diesel engines

    SciTech Connect (OSTI)

    Margeson, M.A.; Belmesch, B.J. )

    1989-01-01

    The objective of the work described in this paper was to compare the cold weather starting ability of diesel engines lubricated with SAE 15W-40 petroleum and SAE 5W-30 synthetic motor oil. Laboratory bench tests were used to compare rhelogical features such as borderline pumping temperature and cold cranking simulator profiles. A cold box provided a well controlled environment in which cranking and starting studies were carried out on the two oils in a turbocharged diesel engine. The SAE 5W-30 synthetic exhibited higher cranking speeds, lower starter amperage draw and immediate oil pressure readings when compared to the SAE l5W-40 petroleum. The SAE 5W-30 synthetic oil was safely started at {minus} l0 {sup 0}F oil temperature without auxiliary heaters. The comparative cylinder turbocharged diesel engines representing conditions commonly found in the commercial and off-highway sectors, These studies indicate that combining high capacity cold cranking amperage batteries, high pressure ether aid injection, and SAE 5W-30 synthetic oil resulted in a system that safely starts diesel engines down to actual oil temperatures of at least {minus} 10 {sup 0}F.

  15. Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sunny, Steffi; Vogel, Nicolas; Howell, Caitlin; Vu, Thy L.; Aizenberg, Joanna

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introducemore » sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. As a result, the LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.« less

  16. Title 40 CFR 300 National Oil and Hazardous Substances Pollution...

    Open Energy Info (EERE)

    0 National Oil and Hazardous Substances Pollution Contingency Plan Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal...

  17. Toxic Substances Control Act Uranium Enrichment Federal Facilities...

    Office of Environmental Management (EM)

    Toxic Substance Control Act Uranium Enrichment Federal Facilities Compliance Agreement (TSCA-UE- FFCA), February 20, 1992 State Ohio Agreement Type Compliance Agreement Legal ...

  18. Rates Meetings and Workshops (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rate Case Workshops Other Power Rates-Related Workshops July 1, 2004 - Rates and Finances Workshop (updated June 25, 2004) (financial and rate forecasts and scenarios for FY...

  19. Mutation assays involving blood cells that metabolize toxic substances

    DOE Patents [OSTI]

    Crespi, Charles L.; Thilly, William G.

    1985-01-01

    A line of human blood cells which have high levels of oxidative activity (such as oxygenase, oxidase, peroxidase, and hydroxylase activity) is disclosed. Such cells grow in suspension culture, and are useful to determine the mutagenicity of xenobiotic substances that are metabolized into toxic or mutagenic substances. Mutation assays using these cells, and other cells with similar characteristics, are also disclosed.

  20. Method of removing and detoxifying a phosphorus-based substance

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, IL); Steindler, Martin J. (Park Forest, IL)

    1989-01-01

    A method of removing organic phosphorus-based poisonous substances from water contaminated therewith and of subsequently destroying the toxicity of the substance is disclosed. Initially, a water-immiscible organic is immobilized on a supported liquid membrane. Thereafter, the contaminated water is contacted with one side of the supported liquid membrane to selectively dissolve the phosphorus-based substance in the organic extractant. At the same time, the other side of the supported liquid membrane is contacted with a hydroxy-affording strong base to react the phosphorus-based substance dissolved by the organic extractant with a hydroxy ion. This forms a non-toxic reaction product in the base. The organic extractant can be a water-insoluble trialkyl amine, such as trilauryl amine. The phosphorus-based substance can be phosphoryl or a thiophosphoryl.

  1. Structure-Property Relationships of Polymer Brushes in Restricted Geometries and their Utilization as Ultra-Low Lubricants

    SciTech Connect (OSTI)

    Kuhl, Tonya Lynn; Faller, Roland

    2015-09-28

    Though polymer films are widely used to modify or tailor the physical, chemical and mechanical properties of interfaces in both solid and liquid systems, the rational design of interface- or surface-active polymer modifiers has been hampered by a lack of information about the behavior and structure-property relationships of this class of molecules. This is especially true for systems in which the role of the polymer is to modify the interaction between two solid surfaces in intimate contact and under load, to cause them to be mechanically coupled (e.g. to promote adhesion and wetting) or to minimize their interaction (e.g. lubrication, colloidal stabilization, etc.). Detailed structural information on these systems has largely been precluded by the many difficulties and challenges associated with direct experimental measurements of polymer structure in these geometries. As a result, many practitioners have been forced to employ indirect measurements or rely wholly on theoretical modeling. This has resulted in an incomplete understanding of the structure-property relationships, which are relied upon for the rational design of improved polymer modifiers. Over the course of this current research program, we made direct measurements of the structure of polymers at the interface between two solid surfaces under confinement and elucidated the fundamental physics behind these phenomena using atomistic and coarse grained simulations. The research has potential to lead to new lubricants and wear reducing agents to improve efficiency.

  2. Influence of steel type on the propensity for tribochemical wear in boundary lubrication with a wind turbine gear oil

    SciTech Connect (OSTI)

    Evans, Ryan D.; Doll, Gary L.; Hager, C H; Howe, Jane Y

    2010-01-01

    Tribochemical wear may occur at the interface between a surface and a lubricant as a result of chemical and mechanical interactions in a tribological contact. Understanding the onset of tribochemical wear damage on component surfaces requires the use of high resolution techniques such as transmission electron microscopy (TEM). In this study, two steel types, case carburized AISI 3310 and through-hardened AISI 52100, were wear tested using a ball-on-disk rolling/sliding contact tribometer in fully formulated commercial wind turbine gearbox oil under boundary lubrication conditions with 10% slip. With the exception of steel type, all other test conditions were held constant. Conventional tribofilm analysis in the wear tracks was performed using X-ray photoelectron spectroscopy, and no significant composition differences were detected in the tribofilms for the different steel disk types. However, TEM analysis revealed significant tribochemical wear differences between the two steel types at multiple length scales, from the near-surface material microstructure (depth < 500 nm) to the tribofilm nanostructure. Nanometer-scale interfacial cracking and surface particle detachment was observed for the AISI 52100 case, whereas the tribofilm/substrate interface was abrupt and undamaged for the AISI 3310 case. Differences in tribofilm structure, including the location and orientation of MoS{sub 2} single sheet inclusions, were observed as a function of steel type as well. It is suggested that the tribochemical wear modes observed in these experiments may be origins of macroscopic surface-initiated damage such as micropitting in bearings and gears.

  3. Method of removing and detoxifying a phosphorus-based substance

    DOE Patents [OSTI]

    Vandegrift, G.F.; Steindler, M.J.

    1985-05-21

    A method of removing a phosphorus-based poisonous substance from water contaminated is presented. In addition, the toxicity of the phosphorus-based substance is also subsequently destroyed. A water-immiscible organic solvent is first immobilized on a supported liquid membrane before the contaminated water is contacted with one side of the supported liquid membrane to absorb the phosphorus-based substance in the organic solvent. The other side of the supported liquid membrane is contacted with a hydroxy-affording strong base to react with phosphorus-based solvated species to form a non-toxic product.

  4. Current BPA Power Rates (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Workshops WP-10 Rate Case WP-07 Rate Case WP-07 Supplemental Rate Case ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial...

  5. Power Rates Announcements (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WP-10 Rate Case WP-07 Rate Case WP-07 Supplemental Rate Case ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial Choices (2003-06) Power...

  6. Toxic Substances Control Act Uranium Enrichment Federal Facilities...

    Office of Environmental Management (EM)

    Thomas L. McCall, Jr. http:www.em.doe.govffaaortsca.html 4252001 Toxic Substances Control Act Uranium Enrichment Federal Facilities Compliance Agree.. Page 12 of 26 Deputy...

  7. Mutation assays involving blood cells that metabolize toxic substances

    DOE Patents [OSTI]

    Crespi, Charles L.; Thilly, William G.

    1999-01-01

    The present invention pertains to a line of human blood cells which have high levels of oxidative activity (such as oxygenase, oxidase, peroxidase, and hydroxylase activity). Such cells grow in suspension culture, and are useful to determine the mutagenicity of xenobiotic substances that are metabolized into toxic or mutagenic substances. The invention also includes mutation assays using these cells, and other cells with similar characteristics.

  8. Mutation assays involving blood cells that metabolize toxic substances

    DOE Patents [OSTI]

    Crespi, C.L.; Thilly, W.G.

    1999-08-10

    The present invention pertains to a line of human blood cells which have high levels of oxidative activity (such as oxygenase, oxidase, peroxidase, and hydroxylase activity). Such cells grow in suspension culture, and are useful to determine the mutagenicity of xenobiotic substances that are metabolized into toxic or mutagenic substances. The invention also includes mutation assays using these cells, and other cells with similar characteristics. 3 figs.

  9. In-tube heat transfer and pressure drop of R-134a and ester lubricant mixtures in a smooth tube and a micro-fin tube. Part 1: Evaporation

    SciTech Connect (OSTI)

    Eckels, S.J.; Doerr, T.M.; Pate, M.B.

    1994-12-31

    In-tube heat transfer coefficients and pressure drops during evaporation are reported for mixtures of refrigerant R-134a and a penta erythritol ester mixed-acid lubricant. The ester lubricant was tested at viscosities of 169 SUS and 369 SUS over a lubricant concentration range of 0% to 5% in both a smooth tube and a micro-fine tube. The average saturation temperature used was 1 C (33.8 F). Measurements were taken for the refrigerant-lubricant mixture over a mass flux range of 85 kg/m{sup 2}{center_dot}s (62,700 lb/ft{sup 2}{center_dot}h) to 375 kg/m{sup 2}{center_dot}s (276,640 lb/ft{sup 2}{center_dot}h) in test tubes with an outer diameter of 9.52 mm (3/8 in.). Heat transfer coefficients during evaporation increased at low concentrations of the 169-SUS ester lubricant and then dropped off at high lubricant concentrations in both the smooth tube and the micro-fin tube. The higher viscosity 369-SUS lubricant decreased the heat transfer coefficients in both tubes over the range of lubricant concentrations tested. Pressure drops during evaporation increased in both the smooth tube and the micro-fin tube with the addition of ester lubricant of either viscosity. The heat transfer coefficients for the micro-fin tube were 100% to 50% higher than those for the smooth tube, with the higher values occurring at low mass fluxes. Pressure drops in the micro-fin tube were 10% to 20% higher than those in the smooth tube.

  10. Current Power Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  11. Current Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  12. Previous Power Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  13. Previous Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  14. Additive for lubricants and hydrocarbon fuels comprising reaction products of olefins, sulfur, hydrogen sulfide and nitrogen containing polymeric compounds

    SciTech Connect (OSTI)

    Horodysky, A.G.; Law, D.A.

    1987-04-28

    A process is described for making an additive for lubricant compositions comprising co-reacting: a monoolefin selected from the group consisting of butenes, propenes, pentenes, and mixtures of two or more thereof; sulfur; hydrogen sulfide; polymeric nitrogen-containing compound selected from the group consisting of succinimides, amides, imides, polyoxyazoline polymers and alkyl imidazoline compounds; and a catalytic amount of an amine selected from the group consisting of polyethylene amines and hydroxyl-containing amines; at a temperature between about 130/sup 0/C and about 200/sup 0/C and a pressure of about 0 psig to about 900 psig, the reactants being reacted in a molar ratio of olefin, polymeric nitrogen-containing compound, and hydrogen sulfide to sulfur of 2 to 0.5, 0.001 to 0.4, and 0.5 to 0.7, respectively, and the concentration of amine being between 0.5 and 10 percent of the total weight of reactants.

  15. Third-Party Evaluation of Petro Tex Hydrocarbons, LLC, ReGen Lubricating Oil Re-refining Process

    SciTech Connect (OSTI)

    Compere, A L; Griffith, William {Bill} L

    2009-04-01

    This report presents an assessment of market, energy impact, and utility of the PetroTex Hydrocarbons, LLC., ReGen process for re-refining used lubricating oil to produce Group I, II, and III base oils, diesel fuel, and asphalt. PetroTex Hydrocarbons, LLC., has performed extensive pilot scale evaluations, computer simulations, and market studies of this process and is presently evaluating construction of a 23 million gallon per year industrial-scale plant. PetroTex has obtained a 30 acre site in the Texas Industries RailPark in Midlothian Texas. The environmental and civil engineering assessments of the site are completed, and the company has been granted a special use permit from the City of Midlothian and air emissions permits for the Texas Commission on Environmental Quality.

  16. The Development of Open Water-lubricated Polycrystalline Diamond (PCD) Thrust Bearings for Use in Marine Hydrokinetic (MHK) Energy Machines

    SciTech Connect (OSTI)

    Cooley, Craig, H.; Khonsari, Michael,, M; Lingwall, Brent

    2012-11-28

    Polycrstalline diamond (PCD) bearings were designed, fabricated and tested for marine-hydro-kinetic (MHK) application. Bearing efficiency and life were evaluated using the US Synthetic bearing test facility. Three iterations of design, build and test were conducted to arrive at the best bearing design. In addition life testing that simulated the starting and stopping and the loading of real MHK applications were performed. Results showed polycrystalline diamond bearings are well suited for MHK applications and that diamond bearing technology is TRL4 ready. Based on life tests results bearing life is estimated to be at least 11.5 years. A calculation method for evaluating the performance of diamond bearings of round geometry was also investigated and developed. Finally, as part of this effort test bearings were supplied free of charge to the University of Alaska for further evaluation. The University of Alaska test program will subject the diamond bearings to sediment laden lubricating fluid.

  17. CHARACTERIZATION AND TRIBOLOGICAL EVALUATION OF 1-BENZYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE AS NEAT LUBRICANT AND OIL ADDITIVE

    SciTech Connect (OSTI)

    Bansal, Dinesh G; Qu, Jun; Yu, Bo; Luo, Huimin; Dai, Sheng; Bunting, Bruce G; Blau, Peter Julian; Mordukhovich, Gregory; Smolenski, Donald

    2011-01-01

    Selected physical and chemical properties and tribological data for a newly-developed, imidazolium-based ionic liquid (IL) are presented. The IL is soluble in the SAE 5W-30 oil up to a certain weight percentage, and is as a promising candidate for use in lubrication applications, either in its neat version or as an oil additive. Characterization of the IL included dynamic viscosity at different temperatures, corrosion effects on cast iron cylinder liners, and thermal stability analysis. The tribological performance was evaluated using a reciprocating ring-on-liner test arrangement. When used in neat version this IL demonstrated friction coefficient comparable to a fully formulated engine oil, and when used as an oil additive it produced less wear.

  18. Influence of lubricant oil on heat transfer performance of refrigerant flow boiling inside small diameter tubes. Part II: Correlations

    SciTech Connect (OSTI)

    Wei, Wenjian; Ding, Guoliang; Hu, Haitao; Wang, Kaijian

    2007-10-15

    The predictive ability of the available state-of-the-art heat transfer correlations of refrigerant-oil mixture is evaluated with the present experiment data of small tubes with inside diameter of 6.34 mm and 2.50 mm. Most of these correlations can be used to predict the heat transfer coefficient of 6.34 mm tube, but none of them can predict heat transfer coefficient of 2.50 mm tube satisfactorily. A new correlation of two-phase heat transfer multiplier with local properties of refrigerant-oil mixture is developed. This correlation approaches the actual physical mechanism of flow boiling heat transfer of refrigerant-oil mixture and can reflect the actual co-existing conditions of refrigerant and lubricant oil. More than 90% of the experiment data of both test tubes have less than {+-}20% deviation from the prediction values of the new correlations. (author)

  19. Large-scale Manufacturing of Nanoparticulate-based Lubrication Additives for Improved Energy Efficiency and Reduced Emissions

    SciTech Connect (OSTI)

    Erdemir, Ali

    2013-09-26

    This project was funded under the Department of Energy (DOE) Lab Call on Nanomanufacturing for Energy Efficiency and was directed toward the development of novel boron-based nanocolloidal lubrication additives for improving the friction and wear performance of machine components in a wide range of industrial and transportation applications. Argonne's research team concentrated on the scientific and technical aspects of the project, using a range of state-of-the art analytical and tribological test facilities. Argonne has extensive past experience and expertise in working with boron-based solid and liquid lubrication additives, and has intellectual property ownership of several. There were two industrial collaborators in this project: Ashland Oil (represented by its Valvoline subsidiary) and Primet Precision Materials, Inc. (a leading nanomaterials company). There was also a sub-contract with the University of Arkansas. The major objectives of the project were to develop novel boron-based nanocolloidal lubrication additives and to optimize and verify their performance under boundary-lubricated sliding conditions. The project also tackled problems related to colloidal dispersion, larger-scale manufacturing and blending of nano-additives with base carrier oils. Other important issues dealt with in the project were determination of the optimum size and concentration of the particles and compatibility with various base fluids and/or additives. Boron-based particulate additives considered in this project included boric acid (H{sub 3}BO{sub 3}), hexagonal boron nitride (h-BN), boron oxide, and borax. As part of this project, we also explored a hybrid MoS{sub 2} + boric acid formulation approach for more effective lubrication and reported the results. The major motivation behind this work was to reduce energy losses related to friction and wear in a wide spectrum of mechanical systems and thereby reduce our dependence on imported oil. Growing concern over greenhouse gas emissions was also a major reason. The transportation sector alone consumes about 13 million barrels of crude oil per day (nearly 60% of which is imported) and is responsible for about 30% of the CO{sub 2} emission. When we consider manufacturing and other energy-intensive industrial processes, the amount of petroleum being consumed due to friction and wear reaches more than 20 million barrels per day (from official energy statistics, U.S. Energy Information Administration). Frequent remanufacturing and/or replacement of worn parts due to friction-, wear-, and scuffing-related degradations also consume significant amounts of energy and give rise to additional CO{sub 2} emission. Overall, the total annual cost of friction- and wear-related energy and material losses is estimated to be rather significant (i.e., as much as 5% of the gross national products of highly industrialized nations). It is projected that more than half of the total friction- and wear-related energy losses can be recovered by developing and implementing advanced friction and wear control technologies. In transportation vehicles alone, 10% to 15% of the fuel energy is spent to overcome friction. If we can cut down the friction- and wear-related energy losses by half, then we can potentially save up to 1.5 million barrels of petroleum per day. Also, less friction and wear would mean less energy consumption as well as less carbon emissions and hazardous byproducts being generated and released to the environment. New and more robust anti-friction and -wear control technologies may thus have a significant positive impact on improving the efficiency and environmental cleanliness of the current legacy fleet and future transportation systems. Effective control of friction in other industrial sectors such as manufacturing, power generation, mining and oil exploration, and agricultural and earthmoving machinery may bring more energy savings. Therefore, this project was timely and responsive to the energy and environmental objectives of DOE and our nation. In this project, most of the boron-based materials with known and potential anti-friction and -wear properties have been manufactured as colloidal additives and tested for their effectiveness in controlling friction and wear. Unlike other anti-friction and -wear additives, which consist of zinc, molybdenum, sulfur, phosphorus, and even chlorine, lubricious boron compounds considered in this project are made of boron, oxygen, nitrogen, and hydrogen, which are more environmentally benign. Among others, boric acid is a natural mineral (known in mineralogy as "sassolite"). Based on our earlier exploratory research, it was found to offer the best overall prospect in terms of performance improvements, environmental friendliness, and ease of manufacturing and, hence, cost effectiveness. Hexagonal boron nitride and borax also offered good prospects for improving the tribological properties of lubricated sliding surfaces. Boron oxide particles were found to be rather hard and somewhat abrasive and, hence, were not considered beyond the initial screening studies. In our bench-top tribological evaluation, we also demonstrated that those additives which worked well with engine oils could work equally well with very common gear oils. When added at appropriate concentrations, such gear oils were found to provide significant resistance to micropitting and scuffing failures in bench-top tribological test systems. Their traction coefficients were also reduced substantially and their scuffing limits were improved considerably. Such impressive tribological behavior of boron-based additives may have been due to their high chemical affinities to interact with sliding contact surfaces and to form slick and protective boundary films. Indeed, our surface studies have confirmed that most of the boron-based nanoparticulate additives prepared in our project possess a strong tendency to form a boron-rich boundary film on sliding contact surfaces. It is believed that the formation of such slick and highly durable boundary films is perhaps one of the fundamental reasons for their superior anti-friction, -wear, and -scuffing performance. Boron-based additives developed under this project have shown potential to reduce or replace the uses of environmentally unsafe sulfur- and phosphorus-bearing anti-wear and friction additives, such as zinc dialkyl dithiophosphate (ZDDP) and molybdenum dialkyl dithiocarbamate (MoDTC), in current lubricating oils. Because ZDDP and MoDTC were suspected of adversely impacting the performance of after-treatment catalysts in current engines, the Environmental Protection Agency (EPA) and other regulatory agencies are demanding that the concentrations of these catalysts in current oils be curtailed drastically. The boron-based nano-additives developed in this project may help reduce the use of ZDDP and MoDTC additives and, hence, help ease the poisoning effects on after-treatment catalysts. When used as lubricity additives, these boron additives can chemically interact with sliding or contacting surfaces and form a protective and slick boundary film, which can, in turn, help reduce friction and wear and increase resistance to scuffing. In the cases of traditional anti-friction and -wear additives mentioned, such protective boundary films result from phosphorus, sulfur, and other elements in the additive package, and again they have been under increased scrutiny in recent years, mainly because of their adverse effects on after-treatment devices. Overall, the boron-based nano-additive technology of this project was shown to hold promise for a broad range of industrial and transportation applications where lower friction and higher resistance to wear and scuffing are needed. Due to more stringent operating conditions of modern machinery, rolling, rotating, and sliding components have been failing to meet the projected lifetimes, mainly because of failures related to mechanical wear, corrosion, and scuffing. The novel boron-based additive technology developed under this project may help such machine components to function reliably by cutting down the friction and wear losses and by increasing resistance to scuffing.

  20. PNCA-02 Rate Case (rates/ratecases)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proposed Adjustment to the Rate for Interchange Energy Imbalances Under the Pacific Northwest Coordination Agreement (PNCA-02 Rate Case) (updated on April 26, 2002) BPA has issued...

  1. Respiratory symptoms among glass bottle makers exposed to stannic chloride solution and other potentially hazardous substances

    SciTech Connect (OSTI)

    Levy, B.S.; Davis, F.; Johnson, B.

    1985-04-01

    Concern about upper respiratory tract irritation and other symptoms among workers at a glass bottle manufacturing plant led to an epidemiologic and an industrial hygiene survey. Questionnaire responses from 35 hot end and 53 cold end workers indicated that the incidence of wheezing, chest pain, dyspnea on exertion, and cough was significantly elevated among hot end workers. Among both smokers and nonsmokers, hot end workers reported higher, but not significantly higher, rates of wheezing and chest pain. Among smokers, hot end workers reported significantly higher rates of dyspnea on exertion and cough than did cold end workers. Data suggest that reported exposure to stannic chloride solution likely caused these symptoms. The industrial hygiene survey, conducted when stannic chloride use had been reduced, cleaning had been done, and ventilation improved, focused on measuring air contaminants that might possibly cause symptoms. Levels of hydrogen chloride, which apparently was formed by the combination of stannic chloride and water in the presence of heat, were elevated. The finding of increased prevalence of respiratory symptoms among hot end workers was consistent with this exposure. Recommendations were made to reduce hazardous exposures at this plant. Individuals responsible for occupational health should be aware that relatively benign substances, such as stannic chloride and water, can combine spontaneously to form hazardous substances.

  2. Page 9, Department of Energy Substance Abuse Testing Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 of 11 Previous Page DOE Substance Abuse Testing Program Executive Order 12564, Drug-Free Federal Workplace, states in part that "the use of illegal drugs or the use of legal drugs illegally by Federal employees impairs the efficiency of Federal Agencies, jeopardizes public health and safety, and violates the public trust." Substance abuse increases the burden on other employees who do not use illegal drugs and also is an economic problem due to lost productivity in the workplace,

  3. Process and apparatus for detecting presence of plant substances

    DOE Patents [OSTI]

    Kirby, John A.

    1991-01-01

    An apparatus and process for detecting the presence of plant substances in a particular environment which comprises the steps of: measuring the background K40 gamma ray radiation level in a particular environment with a 1.46 MeV gamma ray counter system; measuring the amount of K40 gamma ray radiation emanating from a package containing a plant substance being passed through an environment with a counter; and generating an alarm signal when the total K40 gamma ray radiation reaches a predetermined level over and above the background level.

  4. Determination of the tribological fundamentals of solid lubricated ceramics. Volume 2. Appendices A through O. Final report, 9 Sep 85-16 Sep 89

    SciTech Connect (OSTI)

    Gardos, M.N.

    1991-09-01

    The goals, structure and highlights of a recently completed multiyear/multinational research program are described. The main driving force behind this effort was the aim to advance the technology base so engineers can design, build and operate solid lubricated ceramic tribocomponents in extreme environments. Specially designed friction and wear testers were employed to perform well-defined model experiments on single crystal and polycrystalline ceramics and solid lubricants. The research led to discoveries such as (1) a lubricious oxide with the shear strength of molybdenum disulfide in vacuum, (2) CVD diamond films with low friction and extraordinarily low wear, (3) intercalated graphites with high tribothermal resistance in vacuum and in air, and (4) a wear equation for silicon nitride ceramics.

  5. Rate Case Elements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proceeding Rate Information Residential Exchange Program Surplus Power Sales Reports Rate Case Elements BPA's rate cases are decided "on the record." That is, in making a decision...

  6. Power Rate Cases (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Choices (2003-06) Power Function Review (PFR) Firstgov Power Rate Cases BPA's wholesale power rates are set to recover its costs and repay the U.S. Treasury for the Federal...

  7. Chlorite Dissolution Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Carroll, Susan

    Spreadsheets provides measured chlorite rate data from 100 to 300C at elevated CO2. Spreadsheet includes derived rate equation.

  8. Chlorite Dissolution Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Carroll, Susan

    2013-07-01

    Spreadsheets provides measured chlorite rate data from 100 to 300C at elevated CO2. Spreadsheet includes derived rate equation.

  9. Molecular structure in soil humic substances: The new view

    SciTech Connect (OSTI)

    Sutton, Rebecca; Sposito, Garrison

    2005-04-21

    A critical examination of published data obtained primarily from recent nuclear magnetic resonance spectroscopy, X-ray absorption near-edge structure spectroscopy, electrospray ionization-mass spectrometry, and pyrolysis studies reveals an evolving new view of the molecular structure of soil humic substances. According to the new view, humic substances are collections of diverse, relatively low molecular mass components forming dynamic associations stabilized by hydrophobic interactions and hydrogen bonds. These associations are capable of organizing into micellar structures in suitable aqueous environments. Humic components display contrasting molecular motional behavior and may be spatially segregated on a scale of nanometers. Within this new structural context, these components comprise any molecules intimately associated with a humic substance, such that they cannot be separated effectively by chemical or physical methods. Thus biomolecules strongly bound within humic fractions are by definition humic components, a conclusion that necessarily calls into question key biogeochemical pathways traditionally thought to be required for the formation of humic substances. Further research is needed to elucidate the intermolecular interactions that link humic components into supramolecular associations and to establish the pathways by which these associations emerge from the degradation of organic litter.

  10. On using rational enzyme redesign to improve enzyme-mediated microbial dehalogenation of recalcitrant substances in deep-subsurface environments

    SciTech Connect (OSTI)

    Ornstein, R.L.

    1993-06-01

    Heavily halogenated hydrocarbons are one of the most prevalent classes of man-made recalcitrant environmental contaminants and often make their way into subsurface environments. Biodegradation of heavily chlorinated compounds in the deep subsurface often occurs at extremely slow rates because native enzymes of indigenous microbes are unable to efficiently metabolize such synthetic substances. Cost-effective engineering solutions do not exist for dealing with disperse and recalcitrant pollutants in the deep subsurface (i.e., ground water, soils, and sediments). Timely biodegradation of heavily chlorinated compounds in the deep subsurface may be best accomplished by rational redesign of appropriate enzymes that enhance the ability of indigenous microbes to metabolize these substances. The isozyme family cytochromes P450 are catalytically very robust and are found in all aerobic life forms and may be active in may anaerobes as well. The author is attempting to demonstrate proof-of-principle rational enzyme redesign of cytochromes P450 to enhance biodehalogenation.

  11. Method for warning of radiological and chemical substances using detection paints on a vehicle surface

    DOE Patents [OSTI]

    Farmer, Joseph C.

    2012-03-13

    A system for warning of corrosion, chemical, or radiological substances. The system comprises painting a surface with a paint or coating that includes an indicator material and monitoring the surface for indications of the corrosion, chemical, or radiological substances.

  12. Before a Rate Case

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings and Workshops Customer...

  13. Rating Agency Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liabilities Financial Plan Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Residential Exchange Program Surplus Power Sales...

  14. BP-18 Rate Proceeding

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings...

  15. BP-12 Rate Case

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings...

  16. BP-16 Rate Case

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings...

  17. 2012 Transmission Rate Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2014 Transmission, Ancillary, and Control Area Service Rate Schedules and General Rate Schedule Provisions (FY 2014-2015) October 2013 United States Department of Energy...

  18. Forceful Fluid: Scientists Discover a Starchy Substance with Oily Applications

    Broader source: Energy.gov [DOE]

    Researchers at the Energy Department’s Lawrence Livermore National Laboratory (LLNL) set out to find the proper mix of fluids needed to cap the powerful flow of oil that can occur during a spill, an objective that was principally driven by the failure of the top-kill method during last year's oil spill in the Gulf of Mexico. You'll be surprised what starchy substance made the grade.

  19. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  20. Paths and ionization losses of proton energy in different substances

    SciTech Connect (OSTI)

    Vasilovskiy, I.M.; Karpov, I.I.; Petrukhin, V.I.; Prokoshkin, Yu.D.

    1986-02-14

    Ionization energy losses of charged particles in a substance are described by the well-known Bethe-Bloch formula. However, the magnitudes of the ionization potentials in region of low proton energies (E < 100 MeV) for heavy elements prove to be considerably larger than those at high energies. Thus, studies of ionization losses in the region of high energies are the main source of the experimental information necessary for the correction of the Bethe-Bloch formula and determination of magnitudes of ionization potentials I. The purpose of this work was to measure the magnitudes of ionization losses dE/ds, paths R and ionization potentials I at a proton energy of E 670 MeV. The measurements were taken by the relative method for different substances of x, and the magnitudes of q sub x=(dE/ds) sub x/(dE/ds) sub Al and px=R sub x/R sub Al were found. Quantities qx and px weakly depend on the energy E where at E=200-600 MeV, a=(2-4).10-2 for different substances. The proton energy was determined with an accuracy of 2 MeV.

  1. Influence of process parameters on rolling-contact-fatigue life of ion plated nickel-copper-silver lubrication

    SciTech Connect (OSTI)

    Danyluk, Mike; Dhingra, Anoop

    2012-05-15

    In this paper, we present a connection between argon ion flux, element-mixing, and rolling contact fatigue (RCF) life of a thin film nickel-copper-silver lubricant on ball bearings. The film is deposited on the balls using an ion plating process and tested for RCF in high vacuum. The ion flux is measured using a Langmuir probe and the plane stress within the film during deposition is calculated using a thin film model. Experiments reveal that there is an inverse relationship between ion flux and RCF life for most deposition voltage and pressure combinations tested, specifically, 15.5-18.5 mTorr and 1.5-3.5 kV. For voltages up to 2.5 kV, RCF life decreases as ion flux increases due to increased compressive stress within the film, reaching as high as 2.6 GPa. For voltages between 2.5 and 3.5 kV, interlayer mixing of nickel and copper with the silver layer reduces RCF life due to contamination, even as ion flux and corresponding film compressive stress are reduced. A Monte Carlo-based simulation tool, SRIM is used to track collision cascades of the argon ions and metal atoms within the coating layers. At process voltages above 2.5 kV we observe elemental mixing of copper and nickel with the silver layer using Auger electron spectroscopy of coated steel and Si{sub 3}N{sub 4} balls. The authors conclude that an ion flux greater than 5.0 x 10{sup 14} cm{sup -2} s{sup -1} leads to reduced RCF life due to high film stress. In addition, process voltages greater than 2.5 kV also reduce RCF life due to contamination and interlayer mixing of nickel and copper within the silver layer.

  2. Separation of a target substance from a fluid or mixture using encapsulated sorbents

    DOE Patents [OSTI]

    Aines, Roger D; Spadaccini, Christopher M; Stolaroff, Joshuah K; Bourcier, William L; Lewis, Jennifer A; Duoss, Eric B; Vericella, John J

    2014-09-16

    Method and apparatus for separating a target substance from a fluid or mixture. Capsules having a coating and stripping solvents encapsulated in the capsules are provided. The coating is permeable to the target substance. The capsules having a coating and stripping solvents encapsulated in the capsules are exposed to the fluid or mixture. The target substance migrates through the coating and is taken up by the stripping solvents. The target substance is separated from the fluid or mixture by driving off the target substance from the capsules.

  3. Oxygen Diffusion Enables Anti-Wear Boundary Film Formation on Titanium Surfaces in Zinc-Dialkyl-Dithiophosphate (ZDDP)-Containing Lubricants

    SciTech Connect (OSTI)

    Qu, Jun; Blau, Peter Julian; Howe, Jane Y; Meyer III, Harry M

    2009-01-01

    This paper reports a wear reduction by up to six orders of magnitude for Ti-6Al-4V alloy when treated by an oxygen diffusion (OD) process and subsequently tested in a zinc-dialkyl-dithiophosphate (ZDDP)-containing lubricant. In addition to case hardening, it is discovered that OD enables the formation of an anti-wear boundary film on the titanium surface. Transmission electron microscopy and surface chemical analyses revealed that this boundary film has a two-layer structure comprising an amorphous oxide interlayer and a ZDDP-based top film with complex compounds.

  4. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1986-01-01

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  5. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, F.K.

    1986-07-29

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process. 4 figs.

  6. NOVEL LUBRICANT ADDITIVES

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2013-07-16

    , JohnWiley and Sons 2008.; Matsumoto, N.,Mistry, K., Kim, J.H., Eryilmaz, O. L., Erdemir, A., Kinoshita, H. and Ohmae, N...

  7. Boundary Layer Lubrication Mechanisms

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  8. Boundary Layer Lubrication

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  9. Lubricated boride surfaces

    DOE Patents [OSTI]

    Erdemir, A.; Bindal, C.; Fenske, G.R.

    1998-11-24

    Ultralow friction properties are available through the annealation and subsequent cooling of various boron-containing substrates, articles and/or components. 16 figs.

  10. Lubricated boride surfaces

    DOE Patents [OSTI]

    Erdemir, Ali; Bindal, Cuma; Fenske, G. R.

    1998-01-01

    Ultralow friction properties available through the annealation and subsequent cooling of various boron-containing substrates, articles and/or components.

  11. Apparatus and methods for monitoring the concentrations of hazardous airborne substances, especially lead

    DOE Patents [OSTI]

    Zaromb, Solomon

    2004-07-13

    Air is sampled at a rate in excess of 100 L/min, preferably at 200-300 L/min, so as to collect therefrom a substantial fraction, i.e., at least 20%, preferably 60-100%, of airborne particulates. A substance of interest (analyte), such as lead, is rapidly solubilized from the the collected particulates into a sample of liquid extractant, and the concentration of the analyte in the extractant sample is determined. The high-rate air sampling and particulate collection may be effected with a high-throughput filter cartridge or with a recently developed portable high-throughput liquid-absorption air sampler. Rapid solubilization of lead is achieved by a liquid extractant comprising 0.1-1 M of acetic acid or acetate, preferably at a pH of 5 or less and preferably with inclusion of 1-10% of hydrogen peroxide. Rapid determination of the lead content in the liquid extractant may be effected with a colorimetric or an electroanalytical analyzer.

  12. Resonant thermonuclear reaction rate

    SciTech Connect (OSTI)

    Haubold, H.J.; Mathai, A.M.

    1986-08-01

    Basic physical principles for the resonant and nonresonant thermonuclear reaction rates are applied to find their standard representations for nuclear astrophysics. Closed-form representations for the resonant reaction rate are derived in terms of Meijer's G-italic-function. Analytic representations of the resonant and nonresonant nuclear reaction rates are compared and the appearance of Meijer's G-italic-function is discussed in physical terms.

  13. Rail Coal Transportation Rates

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Previous Data Years Year: 2013 2011 2010 2008 2002 Go Background and Methodology The data ... The initial report on coal transportation rates covered the years 2001 through 2008, ...

  14. Draft Tiered Rate Methodology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Regional Dialogue Discussion Purposes Only Pre-Decisional Draft Tiered Rates Methodology March 7, 2008 Pre-decisional, Deliberative, For Discussion Purposes Only March 7,...

  15. LCC Guidance Rates

    Broader source: Energy.gov [DOE]

    Notepad text file provides the LCC guidance rates in a numbered format for the various regions throughout the U.S.

  16. Separation of a target substance from a fluid or mixture using...

    Office of Scientific and Technical Information (OSTI)

    the fluid or mixture by driving off the target substance from the capsules. Authors: Aines, Roger D ; Spadaccini, Christopher M ; Stolaroff, Joshuah K ; Bourcier, William L ;...

  17. ION EXCHANGE SUBSTANCES BY SAPONIFICATION OF ALLYL PHOSPHATE POLYMERS

    DOE Patents [OSTI]

    Kennedy, J.

    1959-04-14

    An ion exchange resin having a relatively high adsorption capacity tor uranyl ion as compared with many common cations is reported. The resin comprises an alphyl-allyl hydrogen phosphate polymer, the alphyl group being either allyl or a lower alkyl group having up to 5 carbon atoins. The resin is prepared by polymerizing compounds such as alkyl-diallyl phosphate and triallyl phosphate in the presence of a free radical generating substance and then partially hydrolyzing the resulting polymer to cause partial replacement of organic radicals by cations. A preferred free radical gencrating agent is dibenzoyl peroxide. The partial hydrolysis is brought about by refluxing the polymer with concentrated aqueous NaOH for three or four hours.

  18. Feasibility of observing small differences in friction mean effective pressure between different lubricating oil formations using small, single-cylinder motored engine rig

    SciTech Connect (OSTI)

    Rohr, William F.; Nguyen, Ke; Bunting, Bruce G.; Qu, Jun

    2015-09-01

    Here, the feasibility of using a motored single-cylinder 517 cc diesel engine to observe small frictional differences between oil formulations is investigated. Friction mean effective pressure (FMEP) is measured and compared for an SAE 10W-30 and an SAE 5W-20 oil in three stages of production: base oil, commercial oil without a friction and wear reducing additive, and fully formulated commercial oil. In addition, a commercial SAE 5W-30 engine oil is investigated. Friction mean effective pressure is plotted versus oil dynamic viscosity to compare the lubricant FMEP at a given viscosity. Linear regressions and average friction mean effective pressure are used as a secondary means of comparing FMEP for the various oil formulations. Differences between the oils are observed with the base oil having higher friction at a given viscosity but a lower average FMEP due to the temperature distribution of the test and lower viscosities reached by the base oil. The commercial oil is shown to have both a higher FMEP at a given viscosity and a higher average FMEP than the commercial oil without a friction and wear reducing additive. The increase in friction for the oil without a friction and wear reduction additive indicates that the operational regime of the engine may be out of the bounds of the optimal regime for the additive or that the additive is more optimized for wear reduction. Results show that it is feasible to observe small differences in FMEP between lubricating oil formulations using a small, single-cylinder motored engine.

  19. Feasibility of observing small differences in friction mean effective pressure between different lubricating oil formations using small, single-cylinder motored engine rig

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rohr, William F.; Nguyen, Ke; Bunting, Bruce G.; Qu, Jun

    2015-09-01

    Here, the feasibility of using a motored single-cylinder 517 cc diesel engine to observe small frictional differences between oil formulations is investigated. Friction mean effective pressure (FMEP) is measured and compared for an SAE 10W-30 and an SAE 5W-20 oil in three stages of production: base oil, commercial oil without a friction and wear reducing additive, and fully formulated commercial oil. In addition, a commercial SAE 5W-30 engine oil is investigated. Friction mean effective pressure is plotted versus oil dynamic viscosity to compare the lubricant FMEP at a given viscosity. Linear regressions and average friction mean effective pressure are usedmore » as a secondary means of comparing FMEP for the various oil formulations. Differences between the oils are observed with the base oil having higher friction at a given viscosity but a lower average FMEP due to the temperature distribution of the test and lower viscosities reached by the base oil. The commercial oil is shown to have both a higher FMEP at a given viscosity and a higher average FMEP than the commercial oil without a friction and wear reducing additive. The increase in friction for the oil without a friction and wear reduction additive indicates that the operational regime of the engine may be out of the bounds of the optimal regime for the additive or that the additive is more optimized for wear reduction. Results show that it is feasible to observe small differences in FMEP between lubricating oil formulations using a small, single-cylinder motored engine.« less

  20. Residential Solar Valuation Rates

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Valuation Rates Karl R. Rbago Rbago Energy LLC 1 The Ideal Residential Solar Tariff Fair to the utility and non-solar customers Fair compensation to the solar ...

  1. Best Practices: Escalation Rates

    Office of Environmental Management (EM)

    Best Practices Escalation Rates Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 3-4, 2015 Houston, TX Federal Utility Partnership Working Group November 3-4, 2015 Houston, TX Federal Utility Partnership Working Group November 3-4, 2015 Houston, TX Best Practices: Escalation Rate Value of future energy savings * Provides purchasing power for implementing a robust, comprehensive and customized ECM set * Provides an option for paying back financing in the shortest possible

  2. WP-07 Power Rate Case (rates/ratecases)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Meetings & Workshops Rate Case Parties Web Site WP-07 Supplemental Rate Case ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial...

  3. 2007-2009 Power Rate Adjustments (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Function Review (PFR) Firstgov FY 2007 2009 Power Rate Adjustments BPA's 2007-2009 Wholesale Power Rate Schedules and General Rate Schedule Provisions (GRSPs) took effect on...

  4. Thin film composition with biological substance and method of making

    SciTech Connect (OSTI)

    Campbell, A.A.; Song, L.

    1999-09-28

    The invention provides a thin-film composition comprising an underlying substrate of a first material including a plurality of attachment sites; a plurality of functional groups chemically attached to the attachment sites of the underlying substrate; and a thin film of a second material deposited onto the attachment sites of the underlying substrate, and a biologically active substance deposited with the thin-film. Preferably the functional groups are attached to a self assembling monolayer attached to the underlying substrate. Preferred functional groups attached to the underlying substrate are chosen from the group consisting of carboxylates, sulfonates, phosphates, optionally substituted, linear or cyclo, alkyl, alkene, alkyne, aryl, alkylaryl, amine, hydroxyl, thiol, silyl, phosphoryl, cyano, metallocenyl, carbonyl, and polyphosphate. Preferred materials for the underlying substrate are selected from the group consisting of a metal, a metal alloy, a plastic, a polymer, a proteic film, a membrane, a glass or a ceramic. The second material is selected from the group consisting of inorganic crystalline structures, inorganic amorphous structures, organic crystalline structures, and organic amorphous structures. Preferred second materials are phosphates, especially calcium phosphates and most particularly calcium apatite. The biologically active molecule is a protein, peptide, DNA segment, RNA segment, nucleotide, polynucleotide, nucleoside, antibiotic, antimicrobial, radioisotope, chelated radioisotope, chelated metal, metal salt, anti-inflammatory, steroid, nonsteroid anti-inflammatory, analgesic, antihistamine, receptor binding agent, or chemotherapeutic agent, or other biologically active material. Preferably the biologically active molecule is an osteogenic factor consisting of the compositions listed above.

  5. Thin film composition with biological substance and method of making

    DOE Patents [OSTI]

    Campbell, Allison A.; Song, Lin

    1999-01-01

    The invention provides a thin-film composition comprising an underlying substrate of a first material including a plurality of attachment sites; a plurality of functional groups chemically attached to the attachment sites of the underlying substrate; and a thin film of a second material deposited onto the attachment sites of the underlying substrate, and a biologically active substance deposited with the thin-film. Preferably the functional groups are attached to a self assembling monolayer attached to the underlying substrate. Preferred functional groups attached to the underlying substrate are chosen from the group consisting of carboxylates, sulfonates, phosphates, optionally substituted, linear or cyclo, alkyl, alkene, alkyne, aryl, alkylaryl, amine, hydroxyl, thiol, silyl, phosphoryl, cyano, metallocenyl, carbonyl, and polyphosphate. Preferred materials for the underlying substrate are selected from the group consisting of a metal, a metal alloy, a plastic, a polymer, a proteic film, a membrane, a glass or a ceramic. The second material is selected from the group consisting of inorganic crystalline structures, inorganic amorphus structures, organic crystalline structures, and organic amorphus structures. Preferred second materials are phosphates, especially calcium phosphates and most particularly calcium apatite. The biologically active molecule is a protein, peptide, DNA segment, RNA segment, nucleotide, polynucleotide, nucleoside, antibiotic, antimicrobal, radioisotope, chelated radioisotope, chelated metal, metal salt, anti-inflamatory, steriod, nonsteriod anti-inflammatory, analgesic, antihistamine, receptor binding agent, or chemotherapeutic agent, or other biologically active material. Preferably the biologically active molecule is an osteogenic factor the compositions listed above.

  6. System and method for preconcentrating, identifying, and quantifying chemical and biological substances

    DOE Patents [OSTI]

    Yu, Conrad M. (Antioch, CA); Koo, Jackson C. (San Ramon, CA)

    2000-01-01

    A system and method for preconcentrating, identifying, and quantifying chemical and biological substances is disclosed. An input valve directs a first volume of a sample gas to a surface acoustic wave (SAW) device. The SAW device preconcentrates and detects a mass of a substance within the sample gas. An output valve receives a second volume of the sample gas containing the preconcentrated substance from the SAW device and directs the second volume to a gas chromatograph (GC). The GC identifies the preconcentrated substance within the sample gas. A shunt valve exhausts a volume of the sample gas equal to the first volume minus the second volume away from the SAW device and the GC. The method of the present invention includes the steps of opening an input valve for passing a first volume of a sample gas to a SAW device; preconcentrating and detecting a mass of a substance within the sample gas using the SAW device; opening an output valve for passing a second volume of the sample gas containing the preconcentrated substance to a gas chromatograph (GC); and then identifying the preconcentrated substance within the sample gas using the GC.

  7. Sequoia Messaging Rate Benchmark

    Energy Science and Technology Software Center (OSTI)

    2008-01-22

    The purpose of this benchmark is to measure the maximal message rate of a single compute node. The first num_cores ranks are expected to reside on the 'core' compute node for which message rate is being tested. After that, the next num_nbors ranks are neighbors for the first core rank, the next set of num_nbors ranks are neighbors for the second core rank, and so on. For example, testing an 8-core node (num_cores = 8)more » with 4 neighbors (num_nbors = 4) requires 8 + 8 * 4 - 40 ranks. The first 8 of those 40 ranks are expected to be on the 'core' node being benchmarked, while the rest of the ranks are on separate nodes.« less

  8. Rotational rate sensor

    DOE Patents [OSTI]

    Hunter, Steven L. (Livermore, CA)

    2002-01-01

    A rate sensor for angular/rotational acceleration includes a housing defining a fluid cavity essentially completely filled with an electrolyte fluid. Within the housing, such as a toroid, ions in the fluid are swept during movement from an excitation electrode toward one of two output electrodes to provide a signal for directional rotation. One or more ground electrodes within the housing serve to neutralize ions, thus preventing any effect at the other output electrode.

  9. The tribology of PS212 coatings and PM212 composites for the lubrication of titanium 6A1-4V components of a Stirling engine space power system

    SciTech Connect (OSTI)

    Sliney, H.E.; Dellacorte, C.; Lukaszewicz, V. |

    1995-07-01

    The Stirling space power machine incorporates a linear alternator to generate electrical power. The alternator is a reciprocating device that is driven by a solar or nuclear-powered Stirling engine. The power piston and cylinder are made of titanium 6A1-4V (Ti6-4) alloy, and are designed to be lubricated by a hydrodynamically-generated gas film. Rubbing occurs during starts and stops and there is a possibility of an occasional high speed rub. Since titanium is known to have a severe galling tendency in sliding contacts, a `backup,` self-lubricating coating on the cylinder and/or the piston is needed. This report describes the results of a research program to study the lubrication of Ti6-4 with the following chromium carbide based materials: plasma-sprayed PS212 coatings and sintered PM212 counterfaces. Program objectives are to achieve adherent coatings on Ti6-4 and to measure the friction and wear characteristics of the following sliding combinations under conditions simulative of the Stirling-driven space power linear alternator: Ti6-4/Ti6-4 baseline, Ti6-4/PS212 coated Ti6-4, and Ps212 coated Ti6-4/PM212

  10. Yellow affinity substance involved in the cellulolytic system of Clostridium thermocellum

    SciTech Connect (OSTI)

    Ljungdahl, L.G.; Pettersson, B.; Eriksson, K.E.; Wiegel, J.

    1983-01-01

    Clostridium thermocellum produces a yellow substance when fermenting cellulose. This substance is attached to the cellulose particles. Cellulose with the yellow substance, obtained from cultures of C. thermocellum, binds effectively endo-1,4-..beta..-glucanase produced by the bacterium and was used in an affinity column for purification of the enzyme. At the beginning of fermentation of cellulose, most of the endoglucanase was bound to the yellow cellulose. As the fermentation proceeded, the enzyme appeared free in the culture fluid. The endoglucanase bound to the yellow cellulose could be extracted by distilled water from the cellulose, but not by solutions with 5 mM or higher concentrations of salts or buffers. It is proposed that the yellow substance is involved in the cellulolytic system of C. thermocellum. 30 references, 3 figures, 3 tables.

  11. Sol-gel deposition of buffer layers on biaxially textured metal substances

    Office of Scientific and Technical Information (OSTI)

    (Patent) | SciTech Connect Sol-gel deposition of buffer layers on biaxially textured metal substances Citation Details In-Document Search Title: Sol-gel deposition of buffer layers on biaxially textured metal substances A method is disclosed for forming a biaxially textured buffer layer on a biaxially oriented metal substrate by using a sol-gel coating technique followed by pyrolyzing/annealing in a reducing atmosphere. This method is advantageous for providing substrates for depositing

  12. Nanoporous Materials Can Tune the Critical Point of a Pure Substance |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Nanoporous Materials Can Tune the Critical Point of a Pure Substance Previous Next List Braun, Efrem; Chen, Joseph J.; Schnell, Sondre K.; Lin, Li-Chiang; Reimer, Jeffrey A.; and Smit, Berend. Nanoporous Materials Can Tune the Critical Point of a Pure Substance. Angew. Chem., Int. Ed., 48, 114349-14352 (2015). DOI: 10.1002/anie.201506865 NanoporousMaterialsCanTune Abstract: Molecular simulations and NMR

  13. Writing Effective Initial Summary Ratings Initial Summary Rating (ISR)

    Energy Savers [EERE]

    Initial Summary Ratings Initial Summary Rating (ISR) At the end of the performance cycle, the rating official must prepare an ISR in ePerformance for each SES member who has completed at least 90 days on an established performance plan. Rating officials must take into account the SES member's accomplishments achieved during the performance cycle and the impact to the organization's performance. Rating officials must appraise executives realistically and fairly and avoid ratings inflation.

  14. October 1996 - September 2001 Wholesale Power Rates (rates/previous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    affecting a specific power purchase. For more specific information see: 1996 Final Wholesale Power and Transmission Rate Schedules: Power Rates (PDF, 84 pages, 188 kb) Ancillary...

  15. PULSE RATE DIVIDER

    DOE Patents [OSTI]

    McDonald, H.C. Jr.

    1962-12-18

    A compact pulse-rate divider circuit affording low impedance output and high input pulse repetition rates is described. The circuit features a single secondary emission tube having a capacitor interposed between its dynode and its control grid. An output pulse is produced at the anode of the tube each time an incoming pulse at the control grid drives the tube above cutoff and the duration of each output pulse corresponds to the charging time of the capacitor. Pulses incoming during the time the grid bias established by the discharging capacitor is sufficiently negative that the pulses are unable to drive the tube above cutoff do not produce output pulses at the anode; these pulses are lost and a dividing action is thus produced by the circuit. The time constant of the discharge path may be vanied to vary in turn the division ratio of the circuit; the time constant of the charging circuit may be varied to vary the width of the output pulses. (AEC)

  16. Energy Escalation Rate Calculator Download

    Broader source: Energy.gov [DOE]

    Energy Escalation Rate Calculator (EERC) computes an average annual escalation rate for a specified time period, which can be used as an escalation rate for contract payments in energy savings performance contracts and utility energy services contracts.

  17. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier5Rate | Open...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateEnergyRateStructureTier5Rate Jump to: navigation, search This is a property of type...

  18. Property:OpenEI/UtilityRate/DemandRateStructure/Tier1Rate | Open...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateDemandRateStructureTier1Rate Jump to: navigation, search This is a property of type...

  19. Property:OpenEI/UtilityRate/DemandRateStructure/Tier3Rate | Open...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateDemandRateStructureTier3Rate Jump to: navigation, search This is a property of type...

  20. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier3Rate | Open...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateEnergyRateStructureTier3Rate Jump to: navigation, search This is a property of type...

  1. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier4Rate | Open...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateEnergyRateStructureTier4Rate Jump to: navigation, search This is a property of type...

  2. Battery collection in municipal waste management in Japan: Challenges for hazardous substance control and safety

    SciTech Connect (OSTI)

    Terazono, Atsushi; Oguchi, Masahiro; Iino, Shigenori; Mogi, Satoshi

    2015-05-15

    Highlights: • Consumers need to pay attention to the specific collection rules for each type of battery in each municipality in Japan. • 6–10% of zinc carbon and alkaline batteries discarded in Japan currently could be regarded as containing mercury. • Despite announcements by producers and municipalities, only 2.0% of discarded cylindrical dry batteries were insulated. • Batteries made up an average of 4.6% of the total collected small WEEE under the small WEEE recycling scheme in Japan. • Exchangeable batteries were used in almost all of mobile phones, but the removal rate was as low as 22% for mobile phones. - Abstract: To clarify current collection rules of waste batteries in municipal waste management in Japan and to examine future challenges for hazardous substance control and safety, we reviewed collection rules of waste batteries in the Tokyo Metropolitan Area. We also conducted a field survey of waste batteries collected at various battery and small waste electric and electronic equipment (WEEE) collection sites in Tokyo. The different types of batteries are not collected in a uniform way in the Tokyo area, so consumers need to pay attention to the specific collection rules for each type of battery in each municipality. In areas where small WEEE recycling schemes are being operated after the enforcement of the Act on Promotion of Recycling of Small Waste Electrical and Electronic Equipment in Japan in 2013, consumers may be confused about the need for separating batteries from small WEEE (especially mobile phones). Our field survey of collected waste batteries indicated that 6–10% of zinc carbon and alkaline batteries discarded in Japan currently could be regarded as containing mercury. More than 26% of zinc carbon dry batteries currently being discarded may have a lead content above the labelling threshold of the EU Batteries Directive (2006/66/EC). In terms of safety, despite announcements by producers and municipalities about using insulation (tape) on waste batteries to prevent fires, only 2.0% of discarded cylindrical dry batteries were insulated. Our field study of small WEEE showed that batteries made up an average of 4.6% of the total collected small WEEE on a weight basis. Exchangeable batteries were used in almost all of mobile phones, digital cameras, radios, and remote controls, but the removal rate was as low as 22% for mobile phones. Given the safety issues and the rapid changes occurring with mobile phones or other types of small WEEE, discussion is needed among stakeholders to determine how to safely collect and recycle WEEE and waste batteries.

  3. Risk management of undesirable substances in feed following updated risk assessments

    SciTech Connect (OSTI)

    Verstraete, Frans

    2013-08-01

    Directive 2002/32/EC of 7 May 2002 of the European Parliament and of the Council on undesirable substances in animal feed is the framework for the EU action on undesirable substances in feed. This framework Directive provides: ?that products intended for animal feed may enter for use in the Union from third countries, be put into circulation and/or used in the Union only if they are sound, genuine and of merchantable quality and therefore when correctly used do not represent any danger to human health, animal health or to the environment or could adversely affect livestock production. ?that in order to protect animal and public health and the environment, maximum levels for specific undesirable substances shall be established where necessary. ?for mandatory consultation of a scientific body (EFSA) for all provisions which may have an effect upon public health or animal health or on the environment. ?that products intended for animal feed containing levels of an undesirable substance that exceed the established maximum level may not be mixed for dilution purposes with the same, or other, products intended for animal feed and may not be used for the production of compound feed. Based on the provisions and principles laid down in this framework Directive, maximum levels for a whole range of undesirable substances have been established at EU level. During the discussions in view of the adoption of Directive 2002/32/EC, the European Commission made the commitment to review all existing provisions on undesirable substances on the basis of updated scientific risk assessments. Following requests of the European Commission, the Panel on Contaminants in the Food Chain (CONTAM) from the European Food Safety Authority (EFSA) has completed a series of 30 risk assessments undertaken over the last 5 years on undesirable substances in animal feed reviewing the possible risks for animal and human health due to the presence of these substances in animal feed. EU legislation on undesirable substances has undergone recently several changes to take account of these most recent scientific opinions. Furthermore EFSA has assessed the risks for public and animal health following the unavoidable carry-over of coccidiostats into non target feed. Maximum levels for the unavoidable carry-over have been established for the non-target feed and the food of animal origin from non-target animal species.

  4. October 2005 - March 2006 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 30.56% non-Slice LB + FB + SN CRAC adjustment for each month of the six-month rate period. The table below...

  5. April - September 2002 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 40.77% non-Slice LB CRAC adjustment for each month of the six-month rate period. The table below is simply a...

  6. October 2004 - March 2005 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The PDF documents above provide tables of monthly Slice, PF, RL, and IP rates with the LB + FB + SN CRAC adjustments for each month of the rate period. The table below is simply...

  7. April - September 2005 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 36.93% non-Slice LB + FB + SN CRAC adjustment for each month of the six-month rate period. The table below...

  8. October 2003 - March 2004 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 43.66% non-Slice LB + FB + SN CRAC adjustment for each month of the rate period. The table below is simply a...

  9. October 2002 - March 2003 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 43.91% non-Slice LB + FB CRAC adjustment for each month of the six-month rate period. The table below is...

  10. October 2001 - March 2002 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 46% non-Slice LB CRAC adjustment for each month of the six-month rate period. The table below is simply a...

  11. April - September 2003 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 49.50% non-Slice LB + FB CRAC adjustment for each month of the six-month rate period. The table below is...

  12. April - September 2004 Power Rates (rates/previous)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above provides a table of monthly Slice, PF, RL, and IP rates with a 47.00% non-Slice LB + FB + SN CRAC adjustment for each month of the six-month rate period. The table below...

  13. FPS-96R Rate Adjustment (rates/ratecases)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Final Firm Power Products and Services (FPS-96R) Rate Adjustment In August 1999, BPA proposed to correct errors in the Firm Power Products and Services rate schedule (FPS-96), and...

  14. 2007-2009 Power Rates Quarterly Updates (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (PFR) Firstgov FY 2007 2009 Power Rates Quarterly Updates In BPAs 2007-2009 Wholesale Power Rate Case (WP-07), BPA agreed that it would post reports about BPAs power...

  15. WP-02 Power Rate Case (rates/ratecases)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WP-02 Power Rate Case (Updated on May 7, 2004) In May of 2000, the BPA Administrator signed a Record of Decision (ROD) on the 2002 Final Power Rate Proposal for the October 2001...

  16. National Utility Rate Database: Preprint

    SciTech Connect (OSTI)

    Ong, S.; McKeel, R.

    2012-08-01

    When modeling solar energy technologies and other distributed energy systems, using high-quality expansive electricity rates is essential. The National Renewable Energy Laboratory (NREL) developed a utility rate platform for entering, storing, updating, and accessing a large collection of utility rates from around the United States. This utility rate platform lives on the Open Energy Information (OpenEI) website, OpenEI.org, allowing the data to be programmatically accessed from a web browser, using an application programming interface (API). The semantic-based utility rate platform currently has record of 1,885 utility rates and covers over 85% of the electricity consumption in the United States.

  17. The hazardous priority substances in Italy: National rules and environmental quality standard in marine environment

    SciTech Connect (OSTI)

    Maggi, Chiara Onorati, Fulvio Lamberti, Claudia Virno Cicero, Anna Maria

    2008-01-15

    Article number 16 of the Water Framework Directive (Directive 2000/60/EC) lays down the community strategy for establishment of harmonised quality standards for the priority substances and other substances posing a significant risk to the aquatic environment. In order to achieve the protection objectives of the Directive 2000/60/EC, the Italian Ministry of the Environment proposed the quality standards for surface water, sediments and biota related to the priority substances listed in the decision No. 2455/2001/EC of the European Parliament and of the Council of November 20 (2001) [Decision N. 2455/2001/EC of the European Parliament and of the Council of 20 November 2001. The list of priority substances in the field of water policy and amending Directive 2000/60/EC. Official Journal of the European Communities, 15.12.2001, p. 5]. Particularly, for the protection of the marine environment, the proposed Italian rules state that, from 1 January 2021, the concentrations of the hazardous priority substances in Italian marine and lagoon waters must be near the natural background for natural substances, like metals, and near zero for the anthropogenic one. According to Directive 2000/60/EC, the Italian Ministry of Environment issued in 2003 Decree 367 in which has derived 160 Environmental Quality Standard (EQS) for water and 27 Environmental Quality Objective (EQO) for sediment of marine coastal area, lagoons and coastal ponds. Biota quality standards have still to be fixed. The paper illustrates the criteria applied for the definition of the quality standards and some comments are presented.

  18. Sol-gel deposition of buffer layers on biaxially textured metal substances

    Office of Scientific and Technical Information (OSTI)

    (Patent) | SciTech Connect Sol-gel deposition of buffer layers on biaxially textured metal substances Citation Details In-Document Search Title: Sol-gel deposition of buffer layers on biaxially textured metal substances × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy

  19. Project Definition Rating Index Workbook

    Broader source: Energy.gov [DOE]

    The Project Definition Rating Index (PDRI) Workbook is a tool that was developed to support DOE G-413.3-12A, U. S. Department of Energy Project Definition Rating Index Guide for Traditional Nuclear...

  20. Commercial Building Asset Rating Program

    Broader source: Energy.gov [DOE]

    Slides from a Commercial Building Initiative webinar outlining the Commercial Building Asset Rating Program on August 23, 2011.

  1. Self-filling and self-purging apparatus for detecting spontaneous radiation from substances in fluids

    DOE Patents [OSTI]

    Larson, I. Lauren; Chiles, Marion M.; Miller, V. Clint

    1993-01-01

    Disclosed herein is a radiation detector providing for the in situ automatic sampling of fluids containing substances emitting radiation, especially Cerenkov radiation. The detector permits sampling within well casings and is self-purging such that no additional provisions must be established for the storage and disposal of contaminated fluids.

  2. New method of determining the current carrier concentration in a substance in the state of superconductivity

    SciTech Connect (OSTI)

    Golotyuk, F.P.

    1985-08-02

    This report proposes a fundamentally new solution to the problem of determining the current carrier concentration in a substance. The basis of the corresponding experimental method is a theory that considers the electron drift energy when considering the oscillatory processes in certain circuits.

  3. Writing Effective Initial Summary Ratings Initial Summary Rating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Writing an Effective ISR (max 8000 characters including spaces) Before writing: * Read definitions of rating levels and critical element targets carefully * Review Strategic Plan ...

  4. SN-03 Rate Case Workshops (rates/meetings)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Related Link: SN-03 Power Rate Case May 1 & 13, 2003 - Debt and Liquidity Strategies workshops (on BPA Corporate web site) March 27, 2003 - SN CRAC Prescheduling...

  5. TOXIC SUBSTANCES FROM COAL COMBUSTION-A COMPREHENSIVE ASSESSMENT

    SciTech Connect (OSTI)

    C.L. Senior; F. Huggins; G.P. Huffman; N. Shah; N. Yap; J.O.L. Wendt; W. Seames; M.R. Ames; A.F. Sarofim; S. Swenson; J.S. Lighty; A. Kolker; R. Finkelman; C.A. Palmer; S.J. Mroczkowski; J.J. Helble; R. Mamani-Paco; R. Sterling; G. Dunham; S. Miller

    2001-06-30

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the National Energy Technology Laboratory (NETL), the Electric Power Research Institute, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NOx combustion systems, and new power generation plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). The work discussed in this report covers the Phase II program. Five coals were studied (three in Phase I and two new ones in Phase II). In this work UK has used XAFS and Moessbauer spectroscopies to characterize elements in project coals. For coals, the principal use was to supply direct information about certain hazardous and other key elements (iron) to complement the more complete indirect investigation of elemental modes of occurrence being carried out by colleagues at USGS. Iterative selective leaching using ammonium acetate, HCl, HF, and HNO3, used in conjunction with mineral identification/quantification, and microanalysis of individual mineral grains, has allowed USGS to delineate modes of occurrence for 44 elements. The Phase II coals show rank-dependent systematic differences in trace-element modes of occurrence. The work at UU focused on the behavior of trace metals in the combustion zone by studying vaporization from single coal particles. The coals were burned at 1700 K under a series of fuel-rich and oxygen-rich conditions. The data collected in this study will be applied to a model that accounts for the full equilibrium between carbon monoxide and carbon dioxide. The model also considers many other reactions taking place in the combustion zone, and involves the diffusion of gases into the particle and combustion products away from the particle. A comprehensive study has been conducted at UA to investigate the post-combustion partitioning of trace elements during large-scale combustion of pulverized coal combustion. For many coals, there are three distinct particle regions developed by three separate mechanisms: (1) a submicron fume, (2) a micron-sized fragmentation region, and (3) a bulk (>3 {micro}m) fly ash region. The controlling partitioning mechanisms for trace elements may be different in each of the three particle regions. A substantial majority of semi-volatile trace elements (e.g., As, Se, Sb, Cd, Zn, Pb) volatilize during combustion. The most common partitioning mechanism for semi-volatile elements is reaction with active fly ash surface sites. Experiments conducted under this program at UC focused on measuring mercury oxidation under cooling rates representative of the convective section of a coal-fired boiler to determine the extent of homogeneous mercury oxidation under these conditions. In fixed bed studies at EERC, five different test series were planned to evaluate the effects of temperature, mercury concentration, mercury species, stoichiometric ratio of combustion air, and ash source. Ash samples generated at UA and collected from full-scale power plants were evaluated. Extensive work was carried out at UK during this program to develop new methods for identification of mercury species in fly ash and sorbents. We demonstrated the usefulness of XAFS spectroscopy for the speciation of mercury captured on low-temperature sorbents from combustion flue gases and dev

  6. Wholesale Power Rate Schedules | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rate Schedules Wholesale Power Rate Schedules Wholesale Power Rate Schedules October 1, 2012 ALA-1-N Wholesale Power Rate Schedule Area: PowerSouth Energy Cooperative System:...

  7. ARM - Measurement - Radiative heating rate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsRadiative heating rate ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Radiative heating rate The heating rate due to the divergence of long and shortwave radiative flux. Categories Atmospheric State, Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a

  8. Trends in Contractor Conversion Rates

    Broader source: Energy.gov [DOE]

    Better Buildings Residential Network Workforce / Business Partners Peer Exchange Call Series: Trends in Contractor Conversion Rates, Call Slides and Discussion Summary, December 5, 2013.

  9. Rate Schedules | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Repayment studies prepared by the agency determine revenue requirements and appropriate rate levels and these studies for each of Southeastern's four power marketing systems are ...

  10. DOE Guidance-Category Rating

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... For most jobs and grade levels under category rating, the certificates of eligibles should be issued in the following order: (1) Career Transition Assistance Program (CTAP) and ...

  11. Sustainable Building Rating Systems Summary

    SciTech Connect (OSTI)

    Fowler, Kimberly M.; Rauch, Emily M.

    2006-07-01

    The purpose of this document is to offer information that could be used to compare and contrast sustainable building rating systems.

  12. Recoil-Implantation Of Multiple Radioisotopes Towards Wear Rate Measurements And Particle Tracing In Prosthetic Joints

    SciTech Connect (OSTI)

    Warner, Jacob A.; Timmers, Heiko; Smith, Paul N.; Scarvell, Jennifer M.; Gladkis, Laura

    2011-06-01

    This study demonstrates a new method of radioisotope labeling of ultra-high molecular weight polyethylene inserts in prosthetic joints for wear studies. The radioisotopes {sup 97}Ru, {sup 100}Pd, {sup 100}Rh, and {sup 101m}Rh are produced in fusion evaporation reactions induced by {sup 12}C ions in a {sup 92}Zr target foil. The fusion products recoil-implant into ultra-high molecular weight polyethylene plugs, machined to fit into the surface of the inserts. During laboratory simulations of the joint motion, a wear rate of the labeled polyethylene may be measured and the pathways of wear debris particles can be traced by detecting characteristic gamma-rays. The concentration profiles of the radioisotopes extend effectively uniformly from the polyethylene surface to a depth of about 4 {mu}m. The multiplicity of labeling and the use of several gamma-ray lines aids with avoiding systematic measurement uncertainties. Two polyethylene plugs were labeled and one was fitted into the surface of the tibial insert of a knee prosthesis, which had been worn in. Actuation over close to 100,000 cycles with a 900 N axial load and a 24 deg. flexion angle removed (14{+-}1)% of the gamma-ray activity from the plug. Most of this activity dispersed into the serum lubricant identifying this as the important debris pathway. Less than 1% activity was transferred to the femoral component of the prosthesis and the measured activity on the tibial tray was insignificant. Assuming uniform wear across the superior surface of the insert, a wear rate of (12{+-}3) mm{sup 3}/Megacycle was determined. This is consistent with wear rate measurements under similar conditions using other techniques.

  13. Fuels & Lubricants R&D

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Vehicle Technologies Plenary

  14. System And Method For Identifying, Reporting, And Evaluating Presence Of Substance

    DOE Patents [OSTI]

    Smith, Maurice; Lusby, Michael; Hook, Arthur Van; Cook, Charles J.; Wenski, Edward G.; Solyom, David

    2005-09-20

    A system and method for identifying, reporting, and evaluating a presence of a solid, liquid, gas, or other substance of interest, particularly a dangerous, hazardous, or otherwise threatening chemical, biological, or radioactive substance. The system comprises one or more substantially automated, location self-aware remote sensing units; a control unit; and one or more data processing and storage servers. Data is collected by the remote sensing units and transmitted to the control unit; the control unit generates and uploads a report incorporating the data to the servers; and thereafter the report is available for review by a hierarchy of responsive and evaluative authorities via a wide area network. The evaluative authorities include a group of relevant experts who may be widely or even globally distributed.

  15. System and method for identifying, reporting, and evaluating presence of substance

    DOE Patents [OSTI]

    Smith, Maurice; Lusby, Michael; Van Hook, Arthur; Cook, Charles J.; Wenski, Edward G.; Solyom, David

    2006-10-24

    A system and method for identifying, reporting, and evaluating a presence of a solid, liquid, gas, or other substance of interest, particularly a dangerous, hazardous, or otherwise threatening chemical, biological, or radioactive substance. The system comprises one or more substantially automated, location self-aware remote sensing units; a control unit; and one or more data processing and storage servers. Data is collected by the remote sensing units and transmitted to the control unit; the control unit generates and uploads a report incorporating the data to the servers; and thereafter the report is available for review by a hierarchy of responsive and evaluative authorities via a wide area network. The evaluative authorities include a group of relevant experts who may be widely or even globally distributed.

  16. System and method for identifying, reporting, and evaluating presence of substance

    DOE Patents [OSTI]

    Smith, Maurice; Lusby, Michael; Van Hook, Arthur; Cook, Charles J.; Wenski, Edward G.; Solyom, David

    2012-02-14

    A system and method for identifying, reporting, and evaluating a presence of a solid, liquid, gas, or other substance of interest, particularly a dangerous, hazardous, or otherwise threatening chemical, biological, or radioactive substance. The system comprises one or more substantially automated, location self-aware remote sensing units; a control unit; and one or more data processing and storage servers. Data is collected by the remote sensing units and transmitted to the control unit; the control unit generates and uploads a report incorporating the data to the servers; and thereafter the report is available for review by a hierarchy of responsive and evaluative authorities via a wide area network. The evaluative authorities include a group of relevant experts who may be widely or even globally distributed.

  17. An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities

    SciTech Connect (OSTI)

    Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L.; Koss, T.C.

    1992-10-01

    Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

  18. Toxic Substances Control Act Polychlorinated Biphenyls (PCB) Hanford Site Users Guide

    SciTech Connect (OSTI)

    PRIGNANO, A.L.

    2002-01-01

    The U.S Department of Energy, Richland Operations Office and the Office of River Protection, requested the development of an integrated and consistent approach to management of polychlorinated biphenyls on the Hanford Site. Under their respective contracts, the Hanford Site contractors are required to comply with polychlorinated biphenyl regulations under the Toxic Substances Control Act of 1976. The objective of this Toxic Substances Control Act Polychlorinated Biphenyls Hanford Site Users Guide is to establish consistent guidance for use by Hanford Site contractors for managing polychlorinated biphenyls. Polychlorinated biphenyls have been identified in some Hanford Site waste, and based on the experiences of the rest of the US. Department of Energy Complex, polychlorinated biphenyls could be expected to be found in an even wider variety of waste. Because of the unique and often cumbersome regulatory requirements that apply to management of polychlorinated biphenyls and polychlorinated biphenyl contaminated materials, the U.S. Department of Energy instructed the contractors to use a proactive approach to develop a Polychlorinated Biphenyls Hanford Site User's Guide to ensure an integrated and consistent approach to management of Toxic Substances Control Act regulated polychlorinated biphenyls in the most cost-effective and compliant manner. Implementation of Toxic Substances Control Act regulated polychlorinated biphenyl requirements on the Hanford Site is accomplished through three paths. One path is the application of the regulations as written to the management of waste contaminated with polychlorinated biphenyls. The U.S. Environmental Protection Agency provides clarification to the regulations through a series of technical references posted on their web site and via questions and answers for the regulated community.

  19. Environmental Guidance Program reference book: Toxic substances control act. Revision 7

    SciTech Connect (OSTI)

    1994-12-01

    This Reference Book contains a current copy of the Toxic Substances Control Act and those regulations that implement the statute and appear to be most relevant to DOE activities. The document is provided to DOE staff for informational purposes only and should not be interpreted as legal guidance. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

  20. Toxic Substances Control Act. Environmental Guidance Program Reference Book: Revision 6

    SciTech Connect (OSTI)

    Not Available

    1992-05-15

    This Reference Book contains a current copy of the Toxic Substances Control Act and those regulations that implement the statute and appear to be most relevant to DOE activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

  1. Toxic Substances Control Act Uranium Enrichment Federal Facilities Compliance Agreement, February 20, 1992 Summary

    Office of Environmental Management (EM)

    Toxic Substance Control Act Uranium Enrichment Federal Facilities Compliance Agreement (TSCA-UE- FFCA), February 20, 1992 State Kentucky Agreement Type Compliance Agreement Legal Driver(s) TSCA Scope Summary Establishes responsibilities and commitments for bringing DOE's former and active Uranium Enrichment Plants in Paducah, Portsmouth, and Oak Ridge into compliance with TSCA and PCB Regulations Parties DOE; U.S. EPA Date 2/20/1992 SCOPE * Establish a plan and the responsibilities and

  2. Project Definition Rating Index (PDRI)

    Broader source: Energy.gov [DOE]

    The Office of Environmental Management (EM) Project Definition Rating Index (EM-PDRI) is a modification of a commercially developed planning tool that has been tested by an EM team specifically for...

  3. Tier 2 Vintage Rate Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at a Tier 2 rate 3) Combination of the two On Nov 1, 2009, customers made their elections for how they will serve their Above-RHWM Load during the FY 2012-2014 purchase...

  4. BPA revises oversupply rate proposal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    comments until May 22, 2013. The rate-setting process will end with the administrator making a decision based on the record developed in the case. BPA expects to issue a final...

  5. Measurement of nitrogen content in a gas mixture by transforming the nitrogen into a substance detectable with nondispersive infrared detection

    DOE Patents [OSTI]

    Owen, Thomas E.; Miller, Michael A.

    2007-03-13

    A method of determining the amount of nitrogen in a gas mixture. The constituent gases of the mixture are dissociated and transformed to create a substance that may measured using nondispersive infrared adsorption techniques.

  6. Measurement of nitrogen content in a gas mixture by transforming the nitrogen into a substance detectable with nondispersive infrared detection

    DOE Patents [OSTI]

    Owen, Thomas E.; Miller, Michael A.

    2010-08-24

    A method of determining the amount of nitrogen in a gas mixture. The constituent gases of the mixture are dissociated and transformed to create a substance that may measured using nondispersive infrared adsorption techniques.

  7. BPA Power Rates (pbl/main)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rates, please see the transmission rates web site. Inactive Rate Cases Integrated Business Review (IBR) Integrated Program Review (IPR) Quarterly Business Review (QBR) Content...

  8. Final Report- National Database of Utility Rates and Rate Structure

    Broader source: Energy.gov [DOE]

    One of the key informational barriers for consumers, installers, regulators and policymakers, is the proper comparison cost of utility-supplied electricity that will be replaced with a Photovoltaic (PV) system. Oftentimes, these comparisons are made with national or statewide averages which results in inaccurate comparisons and conclusions. Illinois State University seeks to meet the need for accurate information about electricity costs and rate structure by building a national database of utility rates and rate structures. The database will build upon the excellent framework that was developed by the OpenEI.org initiative and extend it in several important ways. First, the data will be populated and monitored by a team of trained regulatory economists. Second, the database will be more comprehensive because it will be populated with data from newer competitive retail suppliers for states that have restructured their electricity markets to allow such suppliers. Third, the University and its Institute for Regulatory Policy Studies will maintain the database and ensure that it contains the most recent rate information.

  9. Coal Transportation Rate Sensitivity Analysis

    Reports and Publications (EIA)

    2005-01-01

    On December 21, 2004, the Surface Transportation Board (STB) requested that the Energy Information Administration (EIA) analyze the impact of changes in coal transportation rates on projected levels of electric power sector energy use and emissions. Specifically, the STB requested an analysis of changes in national and regional coal consumption and emissions resulting from adjustments in railroad transportation rates for Wyoming's Powder River Basin (PRB) coal using the National Energy Modeling System (NEMS). However, because NEMS operates at a relatively aggregate regional level and does not represent the costs of transporting coal over specific rail lines, this analysis reports on the impacts of interregional changes in transportation rates from those used in the Annual Energy Outlook 2005 (AEO2005) reference case.

  10. LINEAR COUNT-RATE METER

    DOE Patents [OSTI]

    Henry, J.J.

    1961-09-01

    A linear count-rate meter is designed to provide a highly linear output while receiving counting rates from one cycle per second to 100,000 cycles per second. Input pulses enter a linear discriminator and then are fed to a trigger circuit which produces positive pulses of uniform width and amplitude. The trigger circuit is connected to a one-shot multivibrator. The multivibrator output pulses have a selected width. Feedback means are provided for preventing transistor saturation in the multivibrator which improves the rise and decay times of the output pulses. The multivibrator is connected to a diode-switched, constant current metering circuit. A selected constant current is switched to an averaging circuit for each pulse received, and for a time determined by the received pulse width. The average output meter current is proportional to the product of the counting rate, the constant current, and the multivibrator output pulse width.

  11. Canadian Environmental Protection Act, strategic options for the management of toxic substances: Electric power generation (fossil fuel) sector, report of stakeholder consultations

    SciTech Connect (OSTI)

    1997-12-31

    The Electric Power Generation Sector Issue Table was formed to assess the management of toxic substances released from that sector, and more specifically, to develop (where warranted) goals, targets, and effective and efficient options for managing toxic releases in order to reduce potential risks to human health and the environment. This strategic options report sets out the recommendations of Issue Table members for the management of toxic substances. The introduction includes an industry profile and a review of the provincial management of electric power sector strategic options priority (SOP) substances. Chapter 2 discusses what substances are toxic, estimates releases of SOP substances from the sector, and reviews Issue Table approaches to risk assessment. Chapter 3 outlines Issue Table activities. Chapter 4 screens toxic substance management options, with evaluation of options against 13 groups of criteria. Chapter 5 presents toxic substances management proposals made to the Issue Table by the electric power generation industry, environmental groups, and Environment Canada.

  12. Floating Rate Agreement | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Floating Rate Agreement Floating Rate Agreement PDF icon Floating Rate Agreement More Documents & Publications Fixed Rate Agreement Energy Efficiency Loan Program Agreement Template Energy Efficiency Loan Program Agreement-Template

  13. Variable gas leak rate valve

    DOE Patents [OSTI]

    Eernisse, Errol P.; Peterson, Gary D.

    1976-01-01

    A variable gas leak rate valve which utilizes a poled piezoelectric element to control opening and closing of the valve. The gas flow may be around a cylindrical rod with a tubular piezoelectric member encircling the rod for seating thereagainst to block passage of gas and for reopening thereof upon application of suitable electrical fields.

  14. Fast repetition rate (FRR) flasher

    DOE Patents [OSTI]

    Kolber, Z.; Falkowski, P.

    1997-02-11

    A fast repetition rate (FRR) flasher is described suitable for high flash photolysis including kinetic chemical and biological analysis. The flasher includes a power supply, a discharge capacitor operably connected to be charged by the power supply, and a flash lamp for producing a series of flashes in response to discharge of the discharge capacitor. A triggering circuit operably connected to the flash lamp initially ionizes the flash lamp. A current switch is operably connected between the flash lamp and the discharge capacitor. The current switch has at least one insulated gate bipolar transistor for switching current that is operable to initiate a controllable discharge of the discharge capacitor through the flash lamp. Control means connected to the current switch for controlling the rate of discharge of the discharge capacitor thereby to effectively keep the flash lamp in an ionized state between successive discharges of the discharge capacitor. Advantageously, the control means is operable to discharge the discharge capacitor at a rate greater than 10,000 Hz and even up to a rate greater than about 250,000 Hz. 14 figs.

  15. Fast repetition rate (FRR) flasher

    DOE Patents [OSTI]

    Kolber, Zbigniew; Falkowski, Paul

    1997-02-11

    A fast repetition rate (FRR) flasher suitable for high flash photolysis including kinetic chemical and biological analysis. The flasher includes a power supply, a discharge capacitor operably connected to be charged by the power supply, and a flash lamp for producing a series of flashes in response to discharge of the discharge capacitor. A triggering circuit operably connected to the flash lamp initially ionizes the flash lamp. A current switch is operably connected between the flash lamp and the discharge capacitor. The current switch has at least one insulated gate bipolar transistor for switching current that is operable to initiate a controllable discharge of the discharge capacitor through the flash lamp. Control means connected to the current switch for controlling the rate of discharge of the discharge capacitor thereby to effectively keep the flash lamp in an ionized state between Successive discharges of the discharge capacitor. Advantageously, the control means is operable to discharge the discharge capacitor at a rate greater than 10,000 Hz and even up to a rate greater than about 250,000 Hz.

  16. Evaluation Ratings Definitions (Excluding Utilization of Small...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Excluding Utilization of Small Business) Rating Definition Note Exceptional ... Definitions (Utilization of Small Business) Rating Definition Note Exceptional ...

  17. Object Modeling for Transport of Physical Objects or Substances Across a Geograc

    Energy Science and Technology Software Center (OSTI)

    1997-02-12

    TRANSPORTNET, a suite of object classes, addresses the general problem of simulating transport of objects or substances across a geographically distributed network. This highly abstract concept supports subclassed networks of many types, including road, rail, air, and navigation transportation networks, drainage (hydrological) networks, and utility networks of various sorts, such as pipelines, transmission lines, etc. In TRANSPORTNET, transport occurs along transport links which are connected by transport nodes. The concepts of link and node aremore » also highly abstracted and subject to several topological variants (subclasses), subject to the constraint that all transport takes place along links, and links are connected at the nodes.« less

  18. 1993 Wholesale Power and Transmission Rate Schedules.

    SciTech Connect (OSTI)

    US Bonneville Power Administration

    1993-10-01

    Bonneville Power Administration 1993 Wholesale Power Rate Schedules and General Rate Schedule Provisions and 1993 Transmission Rate Schedules and General Transmission Rate Schedule Provisions, contained herein, were approved on an interim basis effective October 1, 1993. These rate schedules and provisions were approved by the Federal Energy Commission, United States Department of Energy, in September, 1993. These rate schedules and provisions supersede the Administration`s Wholesale Power Rate Schedules and General Rate Schedule Provisions and Transmission Rate Schedules and General Transmission Rate Schedule Provisions effective October 1, 1991.

  19. Sexual Functioning Among Endometrial Cancer Patients Treated With Adjuvant High-Dose-Rate Intra-Vaginal Radiation Therapy

    SciTech Connect (OSTI)

    Damast, Shari; Alektiar, Kaled M.; Goldfarb, Shari; Eaton, Anne; Patil, Sujata; Mosenkis, Jeffrey; Bennett, Antonia; Atkinson, Thomas; Jewell, Elizabeth; Leitao, Mario; Barakat, Richard; Carter, Jeanne; Basch, Ethan

    2012-10-01

    Purpose: We used the Female Sexual Function Index (FSFI) to investigate the prevalence of sexual dysfunction (SD) and factors associated with diminished sexual functioning in early stage endometrial cancer (EC) patients treated with simple hysterectomy and adjuvant brachytherapy. Methods and Materials: A cohort of 104 patients followed in a radiation oncology clinic completed questionnaires to quantify current levels of sexual functioning. The time interval between hysterectomy and questionnaire completion ranged from <6 months to >5 years. Multivariate regression was performed using the FSFI as a continuous variable (score range, 1.2-35.4). SD was defined as an FSFI score of <26, based on the published validation study. Results: SD was reported by 81% of respondents. The mean ({+-} standard deviation) domain scores in order of highest-to-lowest functioning were: satisfaction, 2.9 ({+-}2.0); orgasm, 2.5 ({+-}2.4); desire, 2.4 ({+-}1.3); arousal, 2.2 ({+-}2.0); dryness, 2.1 ({+-}2.1); and pain, 1.9 ({+-}2.3). Compared to the index population in which the FSFI cut-score was validated (healthy women ages 18-74), all scores were low. Compared to published scores of a postmenopausal population, scores were not statistically different. Multivariate analysis isolated factors associated with lower FSFI scores, including having laparotomy as opposed to minimally invasive surgery (effect size, -7.1 points; 95% CI, -11.2 to -3.1; P<.001), lack of vaginal lubricant use (effect size, -4.4 points; 95% CI, -8.7 to -0.2, P=.040), and short time interval (<6 months) from hysterectomy to questionnaire completion (effect size, -4.6 points; 95% CI, -9.3-0.2; P=.059). Conclusions: The rate of SD, as defined by an FSFI score <26, was prevalent. The postmenopausal status of EC patients alone is a known risk factor for SD. Additional factors associated with poor sexual functioning following treatment for EC included receipt of laparotomy and lack of vaginal lubricant use.

  20. What Is the Right Rate? Loan Rates and Demand | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Is the Right Rate? Loan Rates and Demand What Is the Right Rate? Loan Rates and Demand Better Buildings Neighborhood Program Financing Peer Exchange Call: "What is the Right Rate?" ...

  1. Rating fenestration for energy efficiency

    SciTech Connect (OSTI)

    Markway, R.

    1993-09-01

    The grading of windows and doors by the National Fenestration Rating Council (NFRC) opens a new era regarding the energy efficiency of fenestration products. For the first time, architects, designers, and other specifiers will find themselves on a level playing field when it comes to comparing the thermal performance of fenestration products. Although only one state, California, now requires the use of fenestration products that have gone through the NFRC's simulation and testing procedures, five other states will soon be doing so, including Washington, Alaska, Oregon, Idaho, and Wisconsin. Others will follow suit; Florida, Arizona, Texas, Louisiana, New York, Massachusetts, and Colorado have shown interest. Exactly what does this mean to architects The NFRC, which was established last year, has developed a procedure to determine accurately the U-value of fenestration products. Under the NFRC program a number of independent simulation and testing laboratories have been approved. These laboratories are charged with the responsibility of determining whether products conform to the U-values represented by the manufacturers. The rating procedure and benefits from it are described.

  2. Wholesale Power Rate Schedules | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Power Rate Schedules October 1, 2011 CBR-1-H Wholesale Power Rate Schedule Area: Big Rivers and Henderson, KY System: CU October 1, 2011 CM-1-H Wholesale Power Rate...

  3. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: electric load data Type Term Title Author Replies Last Post sort icon...

  4. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: DOE Type Term Title Author Replies Last Post sort icon Blog entry DOE...

  5. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: API Type Term Title Author Replies Last Post sort icon Blog entry API...

  6. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: EZFeed Type Term Title Author Replies Last Post sort icon Blog entry...

  7. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: Database Type Term Title Author Replies Last Post sort icon Blog entry...

  8. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: bug Type Term Title Author Replies Last Post sort icon Discussion bug...

  9. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: energy efficiency Type Term Title Author Replies Last Post sort icon...

  10. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: clean energy Type Term Title Author Replies Last Post sort icon Blog...

  11. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: datasets Type Term Title Author Replies Last Post sort icon Blog entry...

  12. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: FOA Type Term Title Author Replies Last Post sort icon Blog entry FOA...

  13. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: Illinois State University Type Term Title Author Replies Last Post sort...

  14. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: building load Type Term Title Author Replies Last Post sort icon Blog...

  15. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: building load data Type Term Title Author Replies Last Post sort icon...

  16. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: dataset Type Term Title Author Replies Last Post sort icon Blog entry...

  17. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: Energy Visions Prize Type Term Title Author Replies Last Post sort icon...

  18. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: funding Type Term Title Author Replies Last Post sort icon Blog entry...

  19. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate Home > Utility Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: EIA Type Term Title Author Replies Last Post sort icon Blog entry EIA...

  20. Plutonium Hexafluoride Thermal Decomposition Rates (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Plutonium Hexafluoride Thermal Decomposition Rates Citation Details In-Document Search Title: Plutonium Hexafluoride Thermal Decomposition Rates Uranium and plutonium may be ...

  1. LB CRAC Workshops (rates/meetings)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Load-Based (LB) CRAC Power Rate Adjustment Workshop Materials Related Links: Power Rate Adjustments > Load-Based (LB) CRAC December 13, 2006 LB CRAC Workshop Materials (updated...

  2. utility rate | OpenEI Community

    Open Energy Info (EERE)

    utility Utility Companies utility rate Utility Rates version 1 version 2 version 3 web service Smart meter After several months of development and testing, the next...

  3. Device of dispensing micro doses of aqueous solutions of substances onto a carrier and device for carrying out said method

    DOE Patents [OSTI]

    Ershow, Gennady Moiseevich; Kirillov, Evgenii Vladislavovich; Mirzabekov, Andrei Darievich

    1998-01-01

    A device for dispensing microdoses of aqueous solutions are provided, whereby the substance is transferred by the free surface end of a rodlike transferring element; the temperature of the transferring element is maintained at essentially the dew point of the ambient air during the transfer. The device may comprise a plate-like base to which are affixed a plurality of rods; the unfixed butt ends of the rods are coplanar. The device further comprises a means for maintaining the temperature of the unfixed butt ends of the rods essentially equal to the dew point of the ambient air during transfer of the aqueous substance.

  4. Analyzing health risks due to trace substance emissions from utility fossil-fired plants. Final report

    SciTech Connect (OSTI)

    1997-12-01

    EPRI has undertaken a number of project addressing a range of issues on the potential health effects due to long-term inhalation exposure to trace substances emitted from utility stacks. This report describes particular studies conducted to assess the health risks due to emissions from groups of power plants operated by individual utility companies. Researchers conducted specialized risk assessments for each of the power plants involved by incorporating utility-specific data into a modeling framework developed as part of EPRI`s Comprehensive Risk Evaluation (CORE) project to tailor the analysis for the individual utility. The results indicated the value of using more up-to-date, precise data in conducting risk assessments, rather than default assumptions. The report also describes CRAFT, the Comprehensive Risk Assessment Framework for Toxics software package, developed to perform these utility-wide air toxics risk assessments.

  5. Fixed Rate Agreement | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fixed Rate Agreement Fixed Rate Agreement PDF icon Fixed Rate Agreement More Documents & Publications Floating Rate Agreement Notice of Proposed Rulemaking (August 6, 2009) Federal Loan Guarantees for Projects that Manufacture Commercial Technology Renewable Energy Systems and Components: August 10, 2010

  6. Combined Retrieval, Microphysical Retrievals and Heating Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Feng, Zhe

    2013-02-22

    Microphysical retrievals and heating rates from the AMIE/Gan deployment using the PNNL Combined Retrieval.

  7. Combined Retrieval, Microphysical Retrievals and Heating Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Feng, Zhe

    Microphysical retrievals and heating rates from the AMIE/Gan deployment using the PNNL Combined Retrieval.

  8. Wholesale Power Rate Schedules | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rate Schedules » Wholesale Power Rate Schedules Wholesale Power Rate Schedules October 1, 2015 KP-AP-1-C Wholesale Power Rate Schedule Area: American Electric Power System: Kerr-Philpott October 1, 2015 KP-AP-2-C Wholesale Power Rate Schedule Area: American Electric Power System: Kerr-Philpott October 1, 2015 KP-AP-3-C Wholesale Power Rate Schedule Area: American Electric Power System: Kerr-Philpott October 1, 2015 CU-CC-1-J Wholesale Power Rate Schedule Area: Duke Energy Progress, Western

  9. Attachments Energy Ratings Council | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Attachments Energy Ratings Council Attachments Energy Ratings Council Attachments Energy Ratings Council Lead Performer: Window Covering Manufacturing Association - New York, NY DOE Funding: $1,600,000 Project Term: October 1, 2014 - September 30, 2018 Funding Opportunity Announcement: Certification and Rating Attachments for Fenestration Technologies DE-FOA-001000-1504 Project Objective This project is to develop an independent rating, certification, labeling, and performance verification

  10. The evaluation of an analytical protocol for the determination of substances in waste for hazard classification

    SciTech Connect (OSTI)

    Hennebert, Pierre; Papin, Arnaud; Padox, Jean-Marie; Hasebrouck, Benoît

    2013-07-15

    Highlights: • Knowledge of wastes in substances will be necessary to assess HP1–HP15 hazard properties. • A new analytical protocol is proposed for this and tested by two service laboratories on 32 samples. • Sixty-three percentage of the samples have a satisfactory analytical balance between 90% and 110%. • Eighty-four percentage of the samples were classified identically (Seveso Directive) for their hazardousness by the two laboratories. • The method, in progress, is being normalized in France and is be proposed to CEN. - Abstract: The classification of waste as hazardous could soon be assessed in Europe using largely the hazard properties of its constituents, according to the the Classification, Labelling and Packaging (CLP) regulation. Comprehensive knowledge of the component constituents of a given waste will therefore be necessary. An analytical protocol for determining waste composition is proposed, which includes using inductively coupled plasma (ICP) screening methods to identify major elements and gas chromatography/mass spectrometry (GC–MS) screening techniques to measure organic compounds. The method includes a gross or indicator measure of ‘pools’ of higher molecular weight organic substances that are taken to be less bioactive and less hazardous, and of unresolved ‘mass’ during the chromatography of volatile and semi-volatile compounds. The concentration of some elements and specific compounds that are linked to specific hazard properties and are subject to specific regulation (examples include: heavy metals, chromium(VI), cyanides, organo-halogens, and PCBs) are determined by classical quantitative analysis. To check the consistency of the analysis, the sum of the concentrations (including unresolved ‘pools’) should give a mass balance between 90% and 110%. Thirty-two laboratory samples comprising different industrial wastes (liquids and solids) were tested by two routine service laboratories, to give circa 7000 parameter results. Despite discrepancies in some parameters, a satisfactory sum of estimated or measured concentrations (analytical balance) of 90% was reached for 20 samples (63% of the overall total) during this first test exercise, with identified reasons for most of the unsatisfactory results. Regular use of this protocol (which is now included in the French legislation) has enabled service laboratories to reach a 90% mass balance for nearly all the solid samples tested, and most of liquid samples (difficulties were caused in some samples from polymers in solution and vegetable oil). The protocol is submitted to French and European normalization bodies (AFNOR and CEN) and further improvements are awaited.

  11. 2014-2015 Power Rate Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Power Rate Schedules and General Rate Schedule Provisions (FY 2014-2015) October 2013 United States Department of Energy Bonneville Power Administration 905 N.E. 11th Avenue...

  12. Energy Efficiency Interest Rate Reduction Program

    Broader source: Energy.gov [DOE]

    For new and existing home purchases that are rated 6 Star or 5 Star Plus, applicants are eligible for an interest rate reduction for the first $200,000 of the loan amount, with a blended interest...

  13. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Rate > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: American Clean Skies Foundation Type Term Title Author Replies Last Post sort icon Blog entry...

  14. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Utility Rate Home > Groups > Groups > Utility Rate Content Group Activity By term Q & A Feeds There are no feeds from external sites for this group. Groups Menu You must login in...

  15. Category:Utility Rates | Open Energy Information

    Open Energy Info (EERE)

    Rates Jump to: navigation, search Add a new Utility Rate This category currently contains no pages or media. Retrieved from "http:en.openei.orgwindex.php?titleCategory:Utility...

  16. Public Utilities Specialist (Rates) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Area Power Administration Locations Phoenix, Arizona Announcement Number ... Southwest Region, Power Marketing, Rates and Alternative Financing, Phoenix, AZ (G6100). ...

  17. Commercial Building Energy Asset Rating Workshop

    Broader source: Energy.gov [DOE]

    DOE commercial building energy asset rating program information presented to stakeholders at the workshop held in Washington, DC, December 2011

  18. Residential Solar Valuation Rates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Solar Valuation Rates Residential Solar Valuation Rates This presentation summarizes the information discussed by Rabago Energy during the Best Practices in the Design of Utility Solar Programs Webinar on Sept. 27, 2012. PDF icon utility_design_rabago_energy.pdf More Documents & Publications Austin Energy's Residential Solar Rate QER - Comment of Energy Innovation 1 QER - Comment of Energy Innovation 8

  19. Tubular structured hierarchical mesoporous titania material derived from natural cellulosic substances and application as photocatalyst for degradation of methylene blue

    SciTech Connect (OSTI)

    Huang, Haiqing; Liu, Xiaoyan; Huang, Jianguo

    2011-11-15

    Graphical abstract: Bio-inspired, tubular structured hierarchical mesoporous titania material with high photocatalytic activity under UV light was fabricated employing natural cellulosic substance (cotton) as hard template and cetyltrimethylammonium bromide (CTAB) surfactant as soft template using a one-pot sol-gel method. Highlights: {yields} Tubular structured mesoporous titania material was fabricated by sol-gel method. {yields} The titania material faithfully recorded the hierarchical structure of the template substrate (cotton). {yields} The titania material exhibited high photocatalytic activity in decomposition of methylene blue. -- Abstract: Bio-inspired, tubular structured hierarchical mesoporous titania material was designed and fabricated employing natural cellulosic substance (cotton) as hard template and cetyltrimethylammonium bromide (CTAB) surfactant as soft template by one-pot sol-gel method. The tubular structured hierarchical mesoporous titania material processes large specific surface area (40.23 m{sup 2}/g) and shows high photocatalytic activity in the photodegradation of methylene blue under UV light irradiation.

  20. Systems and methods for the detection of low-level harmful substances in a large volume of fluid

    DOE Patents [OSTI]

    Carpenter, Michael V.; Roybal, Lyle G.; Lindquist, Alan; Gallardo, Vincente

    2016-03-15

    A method and device for the detection of low-level harmful substances in a large volume of fluid comprising using a concentrator system to produce a retentate and analyzing the retentate for the presence of at least one harmful substance. The concentrator system performs a method comprising pumping at least 10 liters of fluid from a sample source through a filter. While pumping, the concentrator system diverts retentate from the filter into a container. The concentrator system also recirculates at least part of the retentate in the container again through the filter. The concentrator system controls the speed of the pump with a control system thereby maintaining a fluid pressure less than 25 psi during the pumping of the fluid; monitors the quantity of retentate within the container with a control system, and maintains a reduced volume level of retentate and a target volume of retentate.

  1. Prioritization of groups of substances for Environmental Quality Standard (EQS) development: Recent work with de-icing chemicals

    SciTech Connect (OSTI)

    Lewis, S.; Wilkinson, H.

    1995-12-31

    An estimated 100,000 chemicals are used by mankind, increasing by around 2,000 per year, each with a variety of by-products associated with their manufacture and use, degradation, or destruction. Each has the potential to be released to the environment possibly causing harmful effects, and indeed many cause localized pollution problems for the National Rivers Authority, who is responsible for pollution control. Some of the substances that cause localized pollution problems within the UK require the derivation of an Environmental Quality Standard (EQS). However, derivation of these standards is a lengthy an sometimes costly process. In order to highlight those substances that require an EQS, the National Centre for Environmental Toxicology based at WRc plc, prioritizes groups of substances for EQS development for the NRA. Over recent months, the National Centre for Environmental Toxicology has worked on fire fighting foams, polyelectrolytes, timber treatment chemicals and herbicides for use near water. Its most recent work is on de-icing chemicals. The methodology used to prioritize these pollutants and how the recommendations are used by the NRA will be presented. The process will be illustrated with the current work on de-icing chemicals and interim results will also be available for discussion.

  2. NREL: Photovoltaics Research - Photovoltaic Energy Ratings Methods

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation Photovoltaic Energy Ratings Methods Validation The Photovoltaic (PV) Engineering group at NREL validates energy ratings methods by standards committees to establish an energy rating methodology. We are evaluating techniques to account for the impact on PV performance from variations in the spectral distribution of solar radiation. Two types of methods were evaluated for correcting the short-circuit current of PV modules for variations in the solar spectrum under clear skies: (1)

  3. Introducing the Attachments Energy Ratings Council

    Broader source: Energy.gov [DOE]

    In collaboration with the U.S. Department of Energy (DOE), the Window Covering Manufacturers Association (WCMA) has launched the Attachments Energy Ratings Council (AERC).

  4. Method of controlling fusion reaction rates

    DOE Patents [OSTI]

    Kulsrud, R.M.; Furth, H.P.; Valeo, E.J.; Goldhaber, M.

    1983-05-09

    This invention relates to a method of controlling the reaction rates in a nuclear fusion reactor; and more particularly, to the use of polarized nuclear fuel.

  5. BPA issues final decision on oversupply rate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is consistent with our multiple statutory responsibilities, is rooted in the basic principles of cost causation and fairness that underlie BPA's rate directives, and...

  6. OpenEI Community - utility rate

    Open Energy Info (EERE)

    title"" >After several months of development and testing, the next generation web service for the utility rate database is finally here I encourage you to check out...

  7. BPA proposes rate increase to bolster

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    proposed a 9.6 percent average wholesale power rate increase to compensate for reduced revenue expectations from surplus power sales and to continue funding needed investments in...

  8. CM-1-H Wholesale Power Rate Schedule

    Broader source: Energy.gov [DOE]

    Availability:This rate schedule shall be available to the South Mississippi Electric Power Association, Municipal Energy Agency of Mississippi, and Mississippi Delta Energy Agency (hereinafter...

  9. Photovoltaic Degradation Rates -- An Analytical Review

    SciTech Connect (OSTI)

    Jordan, D. C.; Kurtz, S. R.

    2012-06-01

    As photovoltaic penetration of the power grid increases, accurate predictions of return on investment require accurate prediction of decreased power output over time. Degradation rates must be known in order to predict power delivery. This article reviews degradation rates of flat-plate terrestrial modules and systems reported in published literature from field testing throughout the last 40 years. Nearly 2000 degradation rates, measured on individual modules or entire systems, have been assembled from the literature, showing a median value of 0.5%/year. The review consists of three parts: a brief historical outline, an analytical summary of degradation rates, and a detailed bibliography partitioned by technology.

  10. Time-series product and substance flow analyses of end-of-life electrical and electronic equipment in China

    SciTech Connect (OSTI)

    Habuer, Nakatani, Jun; Moriguchi, Yuichi

    2014-02-15

    Highlights: We estimate the possession and obsolescence of household appliances (HAs) in China. Over 4.85.1 billion units of major HAs will be discarded in the next 20 years. We calculate the amounts of substances contained in end-of-life (EoL) TV sets. Less common metals will tend to decrease in content in generation of EoL TV sets. Precious metals will tend to increase in content in EoL TV sets in 20152030. - Abstract: Given the amounts of end-of-life electrical and electronic equipment (EoL-EEE) being generated and their contents of both harmful and valuable materials, the EoL-EEE issue should be regarded not only as an emerging environmental problem but also as a resource management strategy in China. At present, in order to provide the basis for managing EoL-EEE at both product and substance levels in China, it is necessary to carry out a quantitative analysis on EoL-EEE and to determine how much of it will be generated and how much materials and substances it contains. In this study, the possession and obsolescence amounts of five types of household appliance (HA) including television (TV) sets and the amounts of substances contained in EoL TV sets were estimated using time-series product flow analysis (PFA) and substance flow analysis (SFA). The results of PFA indicated that the total possession amounts of those five types of HAs will exceed 3.1 billion units in 2030, which will be two times higher than those in 2010. In addition, it was estimated that cumulatively over 4.85.1 billion units of these five types of EoL HA would be obsoleted between 20102030. The results of SFA on TV sets indicated that the generated amounts of most of the less common metals and a part of common metals such as copper (Cu) would tend to decrease, whereas those of other common metals such as iron (Fe) as well as precious metals would tend to increase in EoL TV sets in 20152030. The results of this study provide a quantitative basis for helping decision makers develop strategic policies for the management of EoL-EEE considering both environmental and resource aspects. Moreover, a calculation scheme of obsolete HAs presented in this study can be applied to estimate other types of EoL durable good. Meanwhile, the frameworks of this study will help not only the policy decision makers in the Chinese government but also those in developing countries that are facing similar problems.

  11. What Is the Right Rate? Loan Rates and Demand | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Is the Right Rate? Loan Rates and Demand What Is the Right Rate? Loan Rates and Demand Better Buildings Neighborhood Program Financing Peer Exchange Call: "What is the Right Rate?" call slides and discussion summary, December 1, 2011. PDF icon Call Slides and Discussion Summary More Documents & Publications Structuring Rebate and Incentive Programs for Sustainable Demand Peer Exchange Call on Financing and Revenue: Bond Funding Financing Small Business Upgrades

  12. Method of controlling fusion reaction rates

    DOE Patents [OSTI]

    Kulsrud, Russell M.; Furth, Harold P.; Valeo, Ernest J.; Goldhaber, Maurice

    1988-01-01

    A method of controlling the reaction rates of the fuel atoms in a fusion reactor comprises the step of polarizing the nuclei of the fuel atoms in a particular direction relative to the plasma confining magnetic field. Fusion reaction rates can be increased or decreased, and the direction of emission of the reaction products can be controlled, depending on the choice of polarization direction.

  13. Low rate entrainment feeder for fine solids

    SciTech Connect (OSTI)

    Scott, D.S.; Piskorz, J.

    1982-08-01

    A mechanically stirred entrainment-type feeder for fine solids has been developed which will give rates constant to +/- 5% for 1 h or more. The feeder was constructed in connection with a mini-fluidized bed flash pyrolysis project for both biomass and Canadian coals. It has been used to feed coal, sawdust and ground bark in sizes below 600 micro m at rates as low as 6 g/h. Gas to solids weight ratios obtained were from about 3:1 to 1:3. The effect on feed rates of most of the operating and geometric parameters was investigated at low feed rates. A mechanism for control of the feed rate was tested and found to be satisfactory.

  14. Revenue-stability-target rate making

    SciTech Connect (OSTI)

    Chernick, P.L.

    1983-02-17

    The commonly used rate-making approaches necessarily base themselves on assumptions, vital to their success, about future levels of utility aservice sales. But since sales are a function of random variables beyond the control of the utility as well as actions by the utility itself, the resulting rates fail to protect the utility's revenue stream and its realized rate of return. This article proposes an alternative approach which would decouple utility revenues from sales, thus stabilizing revenue streams with respect to sales fluctuations and rate design changes. Among the benefits would be a lower cost of capital for the utility, as well as decreased utility resistance to conservation by consumers and to efficient rate design.

  15. Considerations for How to Rate CPV

    SciTech Connect (OSTI)

    Kurtz, S.; Miller, M.; Marion, B.; Emery, K.; McConnell, R.; Surendran, S.; Kimber, A.

    2011-02-01

    The concentrator photovoltaic (CPV) industry is introducing multiple products into the marketplace, but, as yet, the; community has not embraced a unified method for assessing a nameplate rating. The choices of whether to use 850,; 900, or 1000 W/m2 for the direct-normal irradiance and whether to link the rating to ambient or cell temperature will; affect how CPV modules are rated and compared with other technologies. This paper explores the qualitative and; quantitative ramifications of these choices using data from two multi-junction CPV modules and two flat-plate; modules.

  16. Measuring Degradation Rates Without Irradiance Data

    SciTech Connect (OSTI)

    Pulver, S.; Cormode, D.; Cronin, A.; Jordan, D.; Kurtz, S.; Smith, R.

    2011-02-01

    A method to report PV system degradation rates without using irradiance data is demonstrated. First, a set of relative degradation rates are determined by comparing daily AC final yields from a group of PV systems relative to the average final yield of all the PV systems. Then, the difference between relative and absolute degradation rates is found from a statistical analysis. This approach is verified by comparing to methods that utilize irradiance data. This approach is significant because PV systems are often deployed without irradiance sensors, so the analysis method described here may enable measurements of degradation using data that were previously thought to be unsuitable for degradation studies.

  17. Property:OpenEI/UtilityRate/DemandRateStructure/Tier2Adjustment...

    Open Energy Info (EERE)

    search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateDemandRateStructureTier2Adjustment&oldid539746...

  18. Property:OpenEI/UtilityRate/DemandRateStructure/Tier5Max | Open...

    Open Energy Info (EERE)

    navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateDemandRateStructureTier5Max&oldid539754...

  19. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier1Max | Open...

    Open Energy Info (EERE)

    navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateEnergyRateStructureTier1Max&oldid539766...

  20. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier1Sell | Open...

    Open Energy Info (EERE)

    navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateEnergyRateStructureTier1Sell&oldid539770...

  1. Property:OpenEI/UtilityRate/DemandRateStructure/Tier6Adjustment...

    Open Energy Info (EERE)

    search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateDemandRateStructureTier6Adjustment&oldid539759...

  2. Property:OpenEI/UtilityRate/DemandRateStructure/Tier4Max | Open...

    Open Energy Info (EERE)

    navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateDemandRateStructureTier4Max&oldid539751...

  3. Property:OpenEI/UtilityRate/EnergyRateStructure/Period | Open...

    Open Energy Info (EERE)

    This is a property of type Number. The allowed values for this property are: 1 2 3 4 5 6 7 8 9 Pages using the property "OpenEIUtilityRateEnergyRateStructurePeriod" Showing...

  4. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier4Sell | Open...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateEnergyRateStructureTier4Sell Jump to: navigation, search This is a property of type...

  5. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier3Adjustment...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateEnergyRateStructureTier3Adjustment Jump to: navigation, search This is a property of type...

  6. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier5Sell | Open...

    Open Energy Info (EERE)

    Property Edit with form History Facebook icon Twitter icon Property:OpenEIUtilityRateEnergyRateStructureTier5Sell Jump to: navigation, search This is a property of type...

  7. Getting Rate Information from the utility_rates api | OpenEI...

    Open Energy Info (EERE)

    Getting Rate Information from the utilityrates api Home > Groups > Utility Rate Hello, I am trying to use the API to generate information similar to what you can see here: http:...

  8. Method of in situ retrieval of contaminants or other substances using a barrier system and leaching solutions

    DOE Patents [OSTI]

    Nickelson, Reva A.; Walsh, Stephanie; Richardson, John G.; Dick, John R.; Sloan, Paul A.

    2006-12-26

    Processes and methods relating to treating contaminants and collecting desired substances from a zone of interest using subterranean collection and containment barriers. Tubular casings having interlock structures are used to create subterranean barriers for containing and treating buried waste and its effluents. The subterranean barrier includes an effluent collection system. Treatment solutions provided to the zone of interest pass therethrough and are collected by the barrier and treated or recovered, allowing on-site remediation. Barrier components may be used to in the treatment by collecting or removing contaminants or other materials from the zone of interest.

  9. BPA Power Rates (pbl/main)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial Choices (2003-06) Power Function Review (PFR) Firstgov BPA Fuel Mix 2012 2013 2014...

  10. Minority Utility Rate Design Assessment Model

    Energy Science and Technology Software Center (OSTI)

    2003-01-20

    Econometric model simulates consumer demand response to various user-supplied, two-part tariff electricity rate designs and assesses their economic welfare impact on black, hispanic, poor and majority households.

  11. Contract and Tiered Rate Methodology Overview

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    historical demand to provide incentive to lower their peak by providing a marginal price signal on an incremental component of demand. The CDQs are calculated outside of the rate...

  12. Uncertainty Analysis for Photovoltaic Degradation Rates (Poster)

    SciTech Connect (OSTI)

    Jordan, D.; Kurtz, S.; Hansen, C.

    2014-04-01

    Dependable and predictable energy production is the key to the long-term success of the PV industry. PV systems show over the lifetime of their exposure a gradual decline that depends on many different factors such as module technology, module type, mounting configuration, climate etc. When degradation rates are determined from continuous data the statistical uncertainty is easily calculated from the regression coefficients. However, total uncertainty that includes measurement uncertainty and instrumentation drift is far more difficult to determine. A Monte Carlo simulation approach was chosen to investigate a comprehensive uncertainty analysis. The most important effect for degradation rates is to avoid instrumentation that changes over time in the field. For instance, a drifting irradiance sensor, which can be achieved through regular calibration, can lead to a substantially erroneous degradation rates. However, the accuracy of the irradiance sensor has negligible impact on degradation rate uncertainty emphasizing that precision (relative accuracy) is more important than absolute accuracy.

  13. Project Definition Rating Index Workbook Instructions

    Broader source: Energy.gov [DOE]

    This document provides instructions for use of the Project Definition Rating Index (PDRI) Workbook, a tool that automates the calculation of scores in the PDRI master spreadsheet in Appendix D,...

  14. Utility Rates | OpenEI Community

    Open Energy Info (EERE)

    Rates I'm considering removing the "Show Preview" button, since it does not work (javascript validation issue that could be fixed), and it doesn't make sense. The reason to...

  15. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    > Posts by term > Utility Rate Content Group Activity By term Q & A Feeds Term: Global Atlas Type Term Title Author Replies Last Post sort icon Blog entry Global Atlas IRENA...

  16. Utility Rate | OpenEI Community

    Open Energy Info (EERE)

    Utility Rate Home > Groups Content Group Activity By term Q & A Feeds Share your own status updates, and follow the updates & activities of others by creating your own account. Or,...

  17. Revenue instability induced by conservation rates

    SciTech Connect (OSTI)

    Chesnutt, T.W.; McSpadden, C.; Christianson, J.

    1996-01-01

    The shift toward conservation rate structures, although they may provide better incentives to use scarce water wisely, changes who pays what and can increase the variability of future revenue streams to the water agency. Though the definition of the correct rate structure varies by community, the managerial strategies necessary to cope with the uncertainty brought about by conservation rate structures apply universally. Revenue instability directly increases water supplier`s borrowing costs and adds indirect costs in the form of more complicated planning to provide for a reliable future water supply. This article describes an empirical study using data from two water agencies that have adopted conservation rate structures. The article proposes ways quantitative tools may be used to (1) measure and cope with added uncertainty and (2) make explicit the magnitude of trade-offs between revenue stability, equity, and the provision of incentives for efficient use of water resources.

  18. Historical river flow rates for dose calculations

    SciTech Connect (OSTI)

    Carlton, W.H.

    1991-06-10

    Annual average river flow rates are required input to the LADTAP Computer Code for calculating offsite doses from liquid releases of radioactive materials to the Savannah River. The source of information on annual river flow rates used in dose calculations varies, depending on whether calculations are for retrospective releases or prospective releases. Examples of these types of releases are: Retrospective - releases from routine operations (annual environmental reports) and short term release incidents that have occurred. Prospective - releases that might be expected in the future from routine or abnormal operation of existing or new facilities (EIS`s, EID`S, SAR`S, etc.). This memorandum provides historical flow rates at the downstream gauging station at Highway 301 for use in retrospective dose calculations and derives flow rate data for the Beaufort-Jasper and Port Wentworth water treatment plants.

  19. Dynamic Line Rating: Research and Policy Evaluation

    SciTech Connect (OSTI)

    Jake P. Gentle; Kurt S. Myers; Michael R. West

    2014-07-01

    Dynamic Line Rating (DLR) is a smart grid technology that allows the rating of electrical conductors to be increased based on local weather conditions. Overhead lines are conventionally given a conservative rating based on worst case scenarios. We demonstrate that observing the conditions in real time leads to additional capacity and safer operation. This paper provides a report of a pioneering scheme in the United States of America in which DLR has been applied. Thereby, we demonstrate that observing the local weather conditions in real time leads to additional capacity and safer operation. Secondly, we discuss limitations involved. In doing so, we arrive at novel insights which will inform and improve future DLR projects. Third, we provide a policy background and discussion to clarify the technology’s potential and identifies barriers to the imminent adoption of dynamic line rating systems. We provide suggestions for regulatory bodies about possible improvements in policy to encourage adoption of this beneficial technology.

  20. PSNC Energy (Gas)- Green Building Rate Discount

    Office of Energy Efficiency and Renewable Energy (EERE)

    This discounted rate is available to commercial customers whose building meets the U.S. Green Building Council’s Leadership in Energy and Environmental Design (LEED) certification or equivalent. To...

  1. Extended range radiation dose-rate monitor

    DOE Patents [OSTI]

    Valentine, Kenneth H. (Knoxville, TN)

    1988-01-01

    An extended range dose-rate monitor is provided which utilizes the pulse pileup phenomenon that occurs in conventional counting systems to alter the dynamic response of the system to extend the dose-rate counting range. The current pulses from a solid-state detector generated by radiation events are amplified and shaped prior to applying the pulses to the input of a comparator. The comparator generates one logic pulse for each input pulse which exceeds the comparator reference threshold. These pulses are integrated and applied to a meter calibrated to indicate the measured dose-rate in response to the integrator output. A portion of the output signal from the integrator is fed back to vary the comparator reference threshold in proportion to the output count rate to extend the sensitive dynamic detection range by delaying the asymptotic approach of the integrator output toward full scale as measured by the meter.

  2. DWPF Macrobatch 2 Melt Rate Tests

    SciTech Connect (OSTI)

    Stone, M.E.

    2001-01-03

    The Defense Waste Processing Facility (DWPF) canister production rate must be increased to meet canister production goals. Although a number of factors exist that could potentially increase melt rate, this study focused on two: (1) changes in frit composition and (2) changes to the feed preparation process to alter the redox of the melter feed. These two factors were investigated for Macrobatch 2 (sludge batch 1B) utilizing crucible studies and a specially designed ''melt rate'' furnace. Other potential factors that could increase melt rate include: mechanical mixing via stirring or the use of bubblers, changing the power skewing to redistribute the power input to the melter, and elimination of heat loss (e.g. air in leakage). The melt rate testing in FY00 demonstrated that melt rate can be improved by adding a different frit or producing a much more reducing glass by the addition of sugar as a reductant. The frit that melted the fastest in the melt rate testing was Frit 165. A paper stud y was performed using the Product Composition Control System (PCCS) to determine the impact on predicted glass viscosity, liquidus, durability, and operating window if the frit was changed from Frit 200 to Frit 165. PCCS indicated that the window was very similar for both frits. In addition, the predicted viscosity of the frit 165 glass was 46 poise versus 84 poise for the Frit 200 glass. As a result, a change from Frit 200 to Frit 165 is expected to increase the melt rate in DWPF without decreasing waste loading.

  3. Calibration and Rating of Photovoltaics: Preprint

    SciTech Connect (OSTI)

    Emery, K.

    2012-06-01

    Rating the performance of photovoltaic (PV) modules is critical to determining the cost per watt, and efficiency is useful to assess the relative progress among PV concepts. Procedures for determining the efficiency for PV technologies from 1-sun to low concentration to high concentration are discussed. We also discuss the state of the art in primary and secondary calibration of PV reference cells used by calibration laboratories around the world. Finally, we consider challenges to rating PV technologies and areas for improvement.

  4. Radiation Leukemogenesis at Low Dose Rates

    SciTech Connect (OSTI)

    Weil, Michael; Ullrich, Robert

    2013-09-25

    The major goals of this program were to study the efficacy of low dose rate radiation exposures for the induction of acute myeloid leukemia (AML) and to characterize the leukemias that are caused by radiation exposures at low dose rate. An irradiator facility was designed and constructed that allows large numbers of mice to be irradiated at low dose rates for protracted periods (up to their life span). To the best of our knowledge this facility is unique in the US and it was subsequently used to study radioprotectors being developed for radiological defense (PLoS One. 7(3), e33044, 2012) and is currently being used to study the role of genetic background in susceptibility to radiation-induced lung cancer. One result of the irradiation was expected; low dose rate exposures are ineffective in inducing AML. However, another result was completely unexpected; the irradiated mice had a very high incidence of hepatocellular carcinoma (HCC), approximately 50%. It was unexpected because acute exposures are ineffective in increasing HCC incidence above background. This is a potential important finding for setting exposure limits because it supports the concept of an 'inverse dose rate effect' for some tumor types. That is, for the development of some tumor types low dose rate exposures carry greater risks than acute exposures.

  5. Realization rates of the National Energy Audit

    SciTech Connect (OSTI)

    Berry, L.G.; Gettings, M.B.

    1998-11-01

    Engineering estimates of savings resulting from installation of energy conservation measures in homes are often greater than the savings actually realized. A brief review of prior studies of realization rates prefaces this study of rates from an engineering audit tool, NEAT, (developed for the Department of Energy`s Low-Income Weatherization Assistance Program) used in a New York state utility`s low-income program. Estimates of metered and predicted savings are compared for 49 homes taken from a data base of homes that participated in the first year of the utility`s program. Average realization rates ranging from 57% to 69% result, depending on the data quality. Detailed examinations of two houses using an alternate engineering method, the DOE-2 computer program (considered an industry standard), seem to indicate that the low realization rates mainly result from factors other than inaccuracies in the audit`s internal algorithms. Causes of the low realization rates are examined, showing that the strongest single factor linked to the low rates in this study is the use of secondary heating fuels that supplement the primary heating fuel. This study, like the other similar studies, concludes that engineering estimates are valuable tools in determining ranked lists of cost-effective weatherization measures, but may not be accurate substitutes for measured results in evaluating program performance.

  6. fuels and lubricants | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    may increasingly be from non-conventional sources including, but not milted to, heavy crude, oil sands, shale oil, and coal, as well as renewable resources such as biomass, ...

  7. National Agricultural-Based Lubricants (NABL) Center

    SciTech Connect (OSTI)

    Honary, Lou

    2013-09-30

    This project, while defined as a one year project from September 30, 2012 – September 30, 2013, was a continuation of a number of tasks that were defined in previous years. Those tasks were performed and were finalized in this period. The UNI-NABL Center, which has been in operation in various forms since 1991, has closed its facilities since September 2013 and will be phasing out in June 2014. This report covers the individual tasks that were identified in the previous reports and provides closure to each task in its final stage.

  8. Research on Fuels & Lubricants | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    3 DEER Conference Presentation: Penn State University, Tribology Group, Chemical Engineering Dept. PDF icon 2003deerperez.pdf More Documents & Publications Alternative Fuels ...

  9. Fuel & Lubricant Technologies R&D

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Boundary Layer Lubrication Mechanisms | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Maya Payne Smart Former Writer for Energy Empowers, EERE Constructed from 1931 to 1933, the U.S. Post Office and Courthouse in Boston created quite a buzz with its Art Deco design. A departure from the Classical Revival style popular among federal buildings of the time, its aluminum windows, unadorned granite and limestone base and stepped parapets illustrated its modernity. But over time, the building once hailed for its forward-thinking design grew weary and only an overhaul could restore its

  11. Fabrics coated with lubricated nanostructures display robust...

    Office of Scientific and Technical Information (OSTI)

    GrantContract Number: AR0000326 Type: Accepted Manuscript Journal Name: Nanotechnology (Print) Additional Journal Information: Journal Name: Nanotechnology (Print); Journal ...

  12. Fuel and Lubricant Effects | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    11 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ft001_bunting_2011_o.pdf More Documents & Publications APBF Effects on Combustion APBF Effects on Combustion Response of Oil Sands Derived Fuels in Diesel HCCI Operation

  13. CK-1-H Wholesale Power Rate Schedule | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    quantities. Document Available for Download PDF icon CK-1-H Rate Schedule More Documents & Publications CBR-1-H Wholesale Power Rate Schedule CTV-1-H Wholesale Power Rate ...

  14. Replacement-2-A Wholesale Power Rate Schedule | Department of...

    Office of Environmental Management (EM)

    2-A Wholesale Power Rate Schedule Replacement-2-A Wholesale Power Rate Schedule Area: Replacement Energy System: Kerr-Philpott This rate schedule shall be available to public...

  15. Contractor Rating and Feedback Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rating and Feedback Systems Contractor Rating and Feedback Systems Better Buildings Residential Workforce Business Partners Peer Exchange Call Series: Contractor Rating and ...

  16. Widget:UtilityRateNamingHelper | Open Energy Information

    Open Energy Info (EERE)

    UtilityRateNamingHelper Jump to: navigation, search This widget displays the utility rate database form. For example: Widget:UtilityRateNamingHelper Retrieved from "http:...

  17. Analytical Improvements in PV Degradation Rate Determination

    SciTech Connect (OSTI)

    Jordan, D. C.; Kurtz, S. R.

    2011-02-01

    As photovoltaic (PV) penetration of the power grid increases, it becomes vital to know how decreased power output may affect cost over time. In order to predict power delivery, the decline or degradation rates must be determined accurately. For non-spectrally corrected data several complete seasonal cycles (typically 3-5 years) are required to obtain reasonably accurate degradation rates. In a rapidly evolving industry such a time span is often unacceptable and the need exists to determine degradation rates accurately in a shorter period of time. Occurrence of outliers and data shifts are two examples of analytical problems leading to greater uncertainty and therefore to longer observation times. In this paper we compare three methodologies of data analysis for robustness in the presence of outliers, data shifts and shorter measurement time periods.

  18. Aqueous Corrosion Rates for Waste Package Materials

    SciTech Connect (OSTI)

    S. Arthur

    2004-10-08

    The purpose of this analysis, as directed by ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]), is to compile applicable corrosion data from the literature (journal articles, engineering documents, materials handbooks, or standards, and national laboratory reports), evaluate the quality of these data, and use these to perform statistical analyses and distributions for aqueous corrosion rates of waste package materials. The purpose of this report is not to describe the performance of engineered barriers for the TSPA-LA. Instead, the analysis provides simple statistics on aqueous corrosion rates of steels and alloys. These rates are limited by various aqueous parameters such as temperature (up to 100 C), water type (i.e., fresh versus saline), and pH. Corrosion data of materials at pH extremes (below 4 and above 9) are not included in this analysis, as materials commonly display different corrosion behaviors under these conditions. The exception is highly corrosion-resistant materials (Inconel Alloys) for which rate data from corrosion tests at a pH of approximately 3 were included. The waste package materials investigated are those from the long and short 5-DHLW waste packages, 2-MCO/2-DHLW waste package, and the 21-PWR commercial waste package. This analysis also contains rate data for some of the materials present inside the fuel canisters for the following fuel types: U-Mo (Fermi U-10%Mo), MOX (FFTF), Thorium Carbide and Th/U Carbide (Fort Saint Vrain [FSVR]), Th/U Oxide (Shippingport LWBR), U-metal (N Reactor), Intact U-Oxide (Shippingport PWR, Commercial), aluminum-based, and U-Zr-H (TRIGA). Analysis of corrosion rates for Alloy 22, spent nuclear fuel, defense high level waste (DHLW) glass, and Titanium Grade 7 can be found in other analysis or model reports.

  19. DOE - NNSA/NFO -- Rate our Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rate our Site U.S. DOE/NNSA - Nevada Field Office Rate our website The Nevada Field Office is committed to providing high-quality products and services that meet your needs. Your participation in our customer satisfaction survey will help us achieve this goal. NFO would appreciate your taking the time to complete this survey. Responses are confidential. The survey should take approximately 15 minutes or 1 minute per question. You do not have to answers all the questions. How did you feel working

  20. Front-end utility rate updates | OpenEI Community

    Open Energy Info (EERE)

    Front-end utility rate updates Home > Groups > Utility Rate Rmckeel's picture Submitted by Rmckeel(297) Contributor 13 February, 2013 - 14:28 Utility Rates A few utility rate...