National Library of Energy BETA

Sample records for rate coating technology

  1. Development of High Rate Coating Technology for Low Cost Electrochromic Dynamic Windows

    SciTech Connect (OSTI)

    Kwak, B.; Joshi, Ajey

    2013-03-31

    Objectives of the Project: The objective of this project was to develop and demonstrate the feasibility of depositing critical electrochromic layers at high rate using new novel vacuum coating sources, to develop a full electrochromic process flow by combining conventional processes with new deposition sources, to characterize, test, evaluate, and optimize the resulting coatings and devices, and, to demonstrate an electrochromic device using the new process flow and sources. As addendum objectives, this project was to develop and demonstrate direct patterning methods with novel integration schemes. The long term objective, beyond this program, is to integrate these innovations to enable production of low-cost, high-performance electrochromic windows produced on highly reliable and high yielding manufacturing equipment and systems.

  2. Surface coatings. Science and technology

    SciTech Connect (OSTI)

    Paul, S.

    1985-01-01

    This book covers the coating field from the latest industry developments to current energy and pollution regulations. It explains the composition of coatings, how they are prepared and applied and the factors that control their ultimate performance. The author discusses the synthesis of polymeric binders, industrial resins, pigments, paints and paint properties, types of coatings, and new technologies. CONTENTS: Binders: Synthesis of Polymeric Binders; Industrial Resins; Pigments; Paints and Paint Properties: Pigment Dispersion; Surface Preparation and Paint Application; Paint Properties and Their Evaluation; Types of Coatings; New Technolgies.

  3. Vehicle Technologies Office Merit Review 2014: Can hard coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Can hard coatings and lubricant anti-wear additives work together? Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together?...

  4. NETL Technology for Safer, Cleaner Corrosion-Protecting Metal Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Licensed by Pittsburgh Start-Up | Department of Energy Technology for Safer, Cleaner Corrosion-Protecting Metal Coatings Licensed by Pittsburgh Start-Up NETL Technology for Safer, Cleaner Corrosion-Protecting Metal Coatings Licensed by Pittsburgh Start-Up October 23, 2015 - 12:55pm Addthis Corrosion-related issues cost the U.S. economy $276 billion a year. The Energy Department's National Energy Technology Laboratory (NETL) teamed up with Carnegie Mellon University (CMU) to create a

  5. High removal rate laser-based coating removal system

    DOE Patents [OSTI]

    Matthews, Dennis L. (Moss Beach, CA); Celliers, Peter M. (Berkeley, CA); Hackel, Lloyd (Livermore, CA); Da Silva, Luiz B. (Danville, CA); Dane, C. Brent (Livermore, CA); Mrowka, Stanley (Richmond, CA)

    1999-11-16

    A compact laser system that removes surface coatings (such as paint, dirt, etc.) at a removal rate as high as 1000 ft.sup.2 /hr or more without damaging the surface. A high repetition rate laser with multiple amplification passes propagating through at least one optical amplifier is used, along with a delivery system consisting of a telescoping and articulating tube which also contains an evacuation system for simultaneously sweeping up the debris produced in the process. The amplified beam can be converted to an output beam by passively switching the polarization of at least one amplified beam. The system also has a personal safety system which protects against accidental exposures.

  6. The Effect of Heat Treatments and Coatings on the Outgassing Rate of Stainless Steel Chambers

    SciTech Connect (OSTI)

    Mamum, Md Abdullah A.; Elmustafa, Abdelmageed A,; Stutzman, Marcy L.; Adderley, Philip A.; Poelker, Matthew

    2014-03-01

    The outgassing rates of four nominally identical 304L stainless steel vacuum chambers were measured to determine the effect of chamber coatings and heat treatments. One chamber was coated with titanium nitride (TiN) and one with amorphous silicon (a-Si) immediately following fabrication. One chamber remained uncoated throughout, and the last chamber was first tested without any coating, and then coated with a-Si following a series of heat treatments. The outgassing rate of each chamber was measured at room temperatures between 15 and 30 deg C following bakes at temperatures between 90 and 400 deg C. Measurements for bare steel showed a significant reduction in the outgassing rate by more than a factor of 20 after a 400 deg C heat treatment (3.5 x 10{sup 12} TorrL s{sup -1}cm{sup -2} prior to heat treatment, reduced to 1.7 x 10{ sup -13} TorrL s{sup -1}cm{sup -2} following heat treatment). The chambers that were coated with a-Si showed minimal change in outgassing rates with heat treatment, though an outgassing rate reduced by heat treatments prior to a-Si coating was successfully preserved throughout a series of bakes. The TiN coated chamber exhibited remarkably low outgassing rates, up to four orders of magnitude lower than the uncoated stainless steel. An evaluation of coating composition suggests the presence of elemental titanium which could provide pumping and lead to an artificially low outgassing rate. The outgassing results are discussed in terms of diffusion-limited versus recombination-limited processes.

  7. Certification and Rating of Attachments for Fenestration Technologies

    Office of Environmental Management (EM)

    (DE-FOA-0001000) | Department of Energy Certification and Rating of Attachments for Fenestration Technologies (DE-FOA-0001000) Certification and Rating of Attachments for Fenestration Technologies (DE-FOA-0001000) November 5, 2013 - 4:43pm Addthis This funding opportunity is closed Through this Funding Opportunity Announcement (FOA) the Building Technologies Office (BTO) seeks to establish a performance rating mechanism for assessing the energy performance of fenestration attachments. DOE

  8. Development of Diffusion barrier coatings and Deposition Technologies for Mitigating Fuel Cladding Chemical Interactions (FCCI)

    SciTech Connect (OSTI)

    Sridharan, Kumar; Allen, Todd; Cole, James

    2013-02-27

    The goal of this project is to develop diffusion barrier coatings on the inner cladding surface to mitigate fuel-cladding chemical interaction (FCCI). FCCI occurs due to thermal and radiation enhanced inter-diffusion between the cladding and fuel materials, and can have the detrimental effects of reducing the effective cladding wall thickness and lowering the melting points of the fuel and cladding. The research is aimed at the Advanced Burner Reactor (ABR), a sodium-cooled fast reactor, in which higher burn-ups will exacerbate the FCCI problem. This project will study both diffusion barrier coating materials and deposition technologies. Researchers will investigate pure vanadium, zirconium, and titanium metals, along with their respective oxides, on substrates of HT-9, T91, and oxide dispersion-strengthened (ODS) steels; these materials are leading candidates for ABR fuel cladding. To test the efficacy of the coating materials, the research team will perform high-temperature diffusion couple studies using both a prototypic metallic uranium fuel and a surrogate?¢????the rare-earth element lanthanum. Ion irradiation experiments will test the stability of the coating and the coating-cladding interface. A critical technological challenge is the ability to deposit uniform coatings on the inner surface of cladding. The team will develop a promising non-line-of-sight approach that uses nanofluids . Recent research has shown the feasibility of this simple yet novel approach to deposit coatings on test flats and inside small sections of claddings. Two approaches will be investigated: 1) modified electrophoretic deposition (MEPD) and 2) boiling nanofluids. The coatings will be evaluated in the as-deposited condition and after sintering.

  9. Hafnia-Based Nanostructured Thermal Barrier Coatings for Advanced Hydrogen Turbine Technology

    SciTech Connect (OSTI)

    Ramana, Chintalapalle; Choudhuri, Ahsan

    2013-01-31

    Thermal barrier coatings (TBCs) are critical technologies for future gas turbine engines of advanced coal based power generation systems. TBCs protect engine components and allow further increase in engine temperatures for higher efficiency. In this work, nanostructured HfO{sub 2}-based coatings, namely Y{sub 2}O{sub 3}-stabilized HfO{sub 2} (YSH), Gd{sub 2}O{sub 3}-stabilized HfO{sub 2} (GSH) and Y{sub 2}O{sub 3}-stabilized ZrO{sub 2}-HfO{sub 2} (YSZH) were investigated for potential TBC applications in hydrogen turbines. Experimental efforts are aimed at creating a fundamental understanding of these TBC materials. Nanostructured ceramic coatings of YSH, GSH and YSZH were grown by physical vapor deposition methods. The effects of processing parameters and ceramic composition on the microstructural evolution of YSH, GSH and YSZH nanostructured coatings was studied using combined X-ray diffraction (XRD) and Electron microscopy analyses. Efforts were directed to derive a detailed understanding of crystal-structure, morphology, and stability of the coatings. In addition, thermal conductivity as a function of composition in YSH, YSZH and GSH coatings was determined. Laboratory experiments using accelerated test environments were used to investigate the relative importance of various thermo-mechanical and thermo-chemical failure modes of TBCs. Effects of thermal cycling, oxidation and their complex interactions were evaluated using a syngas combustor rig.

  10. Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together?

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about hard coatings...

  11. SOLID RADIOACTIVE WASTE STORAGE TECHNOLOGIES: PERFORMANCE OF A POLYMER SEALANT COATING IN AN ARCTIC MARINE ENVIRONMENT

    SciTech Connect (OSTI)

    COWGILL,M.G.; MOSKOWITZ,P.D.; CHERNAENKO,L.M.; NAZARIAN,A.; GRIFFITH,A.; DIASHEV,A.; ENGOY,T.

    2000-06-14

    This first project, under the auspices of the Arctic Military Environmental Cooperation (AMEC) forum, Project 1.4-1 Solid Radioactive Waste Storage Technologies, successfully demonstrated the feasibility of using a polymer-based coating to seal concrete and steel surfaces from permanent radioactive contamination in an Arctic marine environment. A mobile, self-sufficient spraying device, was developed to specifications provided by the Russian Ministry of Defence Northern Navy and was deployed at the RTP Atomflot site, Murmansk, Russia. Demonstration coatings of Polibrid 705 were applied to concrete surfaces exposed to conditions ranging from indoor pedestrian usage to heavy vehicle passage and container handling in a loading bay. A large steel container was also coated with the polymer, filled with solid radwaste, sealed, and left out of doors and exposed to the full 12 month Arctic weather cycle. The field tests were accompanied by a series of laboratory qualification tests carried out at the research laboratory of ICC Nuclide in St. Petersburg. During the 12-month field tests, the sealant coating showed little sign of degradation except for a few chips and gouge marks on the loading bay surface that were readily repaired. Contamination resulting from radwaste handling was easily removed and the surface was not degraded by contact with the decontamination agents. In the laboratory testing, Polibrid 705 met all the Russian qualification requirements with the exception of flammability. In this last instance, it was decided to restrict application of the coating to land-based facilities. The Russian technical experts from the Ministry of Defence quickly familiarized themselves with the equipment and were able to identify several areas of potential improvement as deployment of the equipment progressed. The prime among these was the desirability of extending the range of the equipment through enlarged gasoline tanks (to permit extended operational times) and longer material supply hoses (to increase flexibility of operation in confined spaces). Modifications designed to address these issues will be implemented as appropriate.

  12. Certification and Rating of Attachments for Fenestration Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Addthis Related Articles Apply: Solid-State Lighting Advanced Technology R&D - 2014 (DE-FOA-0000973) Request for Information: High Impact Commercial Building Technology Deployment ...

  13. Development of wear-resistant ceramic coatings for diesel engine components. Volume 1, Coating development and tribological testing: Final report: DOE/ORNL Ceramic Technology Project

    SciTech Connect (OSTI)

    Naylor, M.G.S.

    1992-06-01

    The tribological properties of a variety of advanced coating materials have been evaluated under conditions which simulate the piston ring -- cylinder liner environment near top ring reversal in a heavy duty diesel engine. Coated ``ring`` samples were tested against a conventional pearlitic grey cast iron liner material using a high temperature reciprocating wear test rig. Tests were run with a fresh CE/SF 15W40lubricant at 200 and 350{degrees}C, with a high-soot, engine-tested oil at 200{degrees}C and with no lubrication at 200{degrees}C. For lowest wear under boundary lubricated conditions, the most promising candidates to emerge from this study were high velocity oxy-fuel (HVOF) Cr{sub 3} C{sub 2} - 20% NiCr and WC - 12% Co cermets, low temperature arc vapor deposited (LTAVD) CrN and plasma sprayed chromium oxides. Also,plasma sprayed Cr{sub 2}O{sub 3} and A1{sub 2}O{sub 3}-ZrO{sub 2} materials were found to give excellent wear resistance in unlubricated tests and at extremely high temperatures (450{degrees}C) with a syntheticoil. All of these materials would offer substantial wear reductions compared to the conventional electroplated hard chromium ring facing and thermally sprayed metallic coatings, especially at high temperatures and with high-soot oils subjected to degradation in diesel environments. The LTAVD CrN coating provided the lowest lubricated wear rates of all the materials evaluated, but may be too thin (4 {mu}m) for use as a top ring facing. Most of the coatings evaluated showed higher wear rates with high-soot, engine-tested oil than with fresh oil, with increases of more than a factor of ten in some cases. Generally, metallic materials were found to be much more sensitive to soot/oil degradation than ceramic and cermet coatings. Thus, decreased ``soot sensitivity`` is a significant driving force for utilizing ceramic or cermet coatings in diesel engine wear applications.

  14. Innovative Cathode Coating Enables Faster Battery Charging, Dischargin...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative Cathode Coating Enables Faster Battery Charging, Discharging Technology available for licensing: Coating increases electrical conductivity of cathode materials Coating...

  15. Vehicle Technologies Office Merit Review 2015: Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Johnson Controls at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about significant cost improvement...

  16. Vehicle Technologies Office Merit Review 2014: Significant Cost Improvement of Li-ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Johnson Controls at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about significant cost improvement...

  17. Energy Saving Melting and Revert Reduction Technology (E-SMARRT): Development of Surface Engineered Coating Systems for Aluminum Pressure Die Casting Dies: Towards a 'Smart' Die Coating

    SciTech Connect (OSTI)

    Dr. John J. Moore; Dr. Jianliang Lin,

    2012-07-31

    The main objective of this research program was to design and develop an optimal coating system that extends die life by minimizing premature die failure. In high-pressure aluminum die-casting, the die, core pins and inserts must withstand severe processing conditions. Many of the dies and tools in the industry are being coated to improve wear-resistance and decrease down-time for maintenance. However, thermal fatigue in metal itself can still be a major problem, especially since it often leads to catastrophic failure (i.e. die breakage) as opposed to a wear-based failure (parts begin to go out of tolerance). Tooling costs remain the largest portion of production costs for many of these parts, so the ability prevent catastrophic failures would be transformative for the manufacturing industry.The technology offers energy savings through reduced energy use in the die casting process from several factors, including increased life of the tools and dies, reuse of the dies and die components, reduction/elimination of lubricants, and reduced machine down time, and reduction of Al solder sticking on the die. The use of the optimized die coating system will also reduce environmental wastes and scrap parts. Current (2012) annual energy saving estimates, based on initial dissemination to the casting industry in 2010 and market penetration of 80% by 2020, is 3.1 trillion BTU's/year. The average annual estimate of CO2 reduction per year through 2020 is 0.63 Million Metric Tons of Carbon Equivalent (MM TCE).

  18. EERE Success Story—California: Heliotrope Technologies Wins R&D 100 Award for Universal Smart Window Coating that Saves Energy and Increases Comfort

    Broader source: Energy.gov [DOE]

    EERE-funded Heliotrope Technologies, with support from EERE’s Lawrence Berkeley National Laboratory (LBNL), received a 2013 R&D 100 Award for their Universal Smart Window (USW) Coating.

  19. Topical report to Morgantown Energy Technology Center for the interfacial coatings for ceramic-matrix composites

    SciTech Connect (OSTI)

    1997-01-09

    This report summarizes the task conducted to examine various activities on interface development for ceramic-matrix composites (CMCs) intended for high-temperature applications. While several articles have been published on the subject of CMC interfaces, the purpose of this report is to describe the various ongoing efforts on interface concepts, material selection, and issues related to processing methods employed for developing interface coatings. The most exciting and new development in the field is the discovery of monazite as a potential interface material for mullite- and alumina-based composites. Monazite offers two critical properties to the CMC system; a weakly bonded layer due to its non-wetting behavior and chemical compatibility with both alumina and mullite up to very high temperatures (> 1,600 C). A description of the Department of Energy-related activities and some thoughts on processing issues, interface testing, and effects of processing on fiber strength are given.

  20. RISK REDUCTION THROUGH USE OF EXTERNAL TECHNICAL REVIEWS, TECHNOLOGY READINESS ASSESSMENTS AND TECHNICAL RISK RATINGS - 9174

    SciTech Connect (OSTI)

    Cercy, M; Steven P Schneider, S; Kurt D Gerdes, K

    2008-12-12

    The U.S. Department of Energy's Office of Environmental Management (DOE-EM) was established to achieve the safe and compliant disposition of legacy wastes and facilities from defense nuclear applications. A large majority of these wastes and facilities are 'one-of-a-kind' and unique to DOE. Many of the programs to treat these wastes have been 'first-of-a-kind' and unprecedented in scope and complexity. This has meant that many of the technologies needed to successfully disposition these wastes were not yet developed or required significant re-engineering to be adapted for DOE-EM's needs. The DOE-EM program believes strongly in reducing the technical risk of its projects and has initiated several efforts to reduce those risks: (1) Technology Readiness Assessments to reduce the risks of deployment of new technologies; (2) External Technical Reviews as one of several steps to ensure the timely resolution of engineering and technology issues; and (3) Technical Risk Ratings as a means to monitor and communicate information about technical risks. This paper will present examples of how Technology Readiness Assessments, External Technical Reviews, and Technical Risk Ratings are being used by DOE-EM to reduce technical risks.

  1. RISK REDUCTION THROUGH USE OF EXTERNAL TECHNICAL REVIEWS, TECHNOLOGY READINESS ASSESSMENTS AND TECHNICAL RISK RATINGS - 9174

    SciTech Connect (OSTI)

    Cercy, M; Steven P Schneider, S; Kurt D Gerdes, K

    2009-01-15

    The U.S. Department of Energy's Office of Environmental Management (DOE-EM) was established to achieve the safe and compliant disposition of legacy wastes and facilities from defense nuclear applications. A large majority of these wastes and facilities are 'one-of-a-kind' and unique to DOE. Many of the programs to treat these wastes have been 'first-of-a-kind' and unprecedented in scope and complexity. This has meant that many of the technologies needed to successfully disposition these wastes were not yet developed or required significant re-engineering to be adapted for DOE-EM's needs. The DOE-EM program believes strongly in reducing the technical risk of its projects and has initiated several efforts to reduce those risks: (1) Technology Readiness Assessments to reduce the risks of deployment of new technologies; (2) External Technical Reviews as one of several steps to ensure the timely resolution of engineering and technology issues; and (3) Technical Risk Ratings as a means to monitor and communicate information about technical risks. This paper will present examples of how Technology Readiness Assessments, External Technical Reviews, and Technical Risk Ratings are being used by DOE-EM to reduce technical risks.

  2. Development of Industrially Viable Battery Electrode Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies...

  3. Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  4. New Cool Roof Coatings and Affordable Cool Color Asphalt | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Cool Roof Coatings and Affordable Cool Color Asphalt New Cool Roof Coatings and Affordable Cool Color Asphalt Emerging Technologies Project for the 2013 Building Technologies...

  5. Super Hard Coating Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hard Coating Systems Super Hard Coating Systems 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon pmp_04_erdemir.pdf More Documents & Publications Low-Friction Hard Coatings Low-Friction Hard Coatings Low-Friction Hard Coatings

  6. AISI/DOE Technology Roadmap Program: A Technology of Low Coal Rate and High Productivity of RHF Ironmaking

    SciTech Connect (OSTI)

    Wei-Kao Lu

    2002-09-15

    An economical and environment-friendly ironmaking process based on heating the chemiexecy self-sufficient green balls of iron ore and coal in a hearth furnace is being developed with financial support from AISI members and DOE. DRI, which is hot (1400 C), dense (3.2 g/cm) and of high degree of metallization (95%), has been produced in laboratory and in a pilot plant in Genoa, Italy. Products of such quality have been made from American and Brazilian ores, BOF sludge, EAF dust/BOF sludge mixtures and millscale. The removal of zinc and lead from green balls by this process is essentially complete. In comparison with typical blast furnace operation, the new technology with a melter would have a lower total coal rate by 200kg.THM. The elimination of cokemaking and high temperature agglomeration steps, and a simpler gas handling system would lead to lower capital and operating costs. In comparison with commercial RHF practice it is different in atmosphere (fully oxidized at 1600 to 1650 C), in bed height (120 mm instead of 20-25 mm) and in pellet composition (much less coal but of higher VM). The combined effect leads to three times higher furnace productivity, lower coal consumption and superior DRI quality. The risk of re-oxidation (slag formation) and dusty operation are practiexecy eliminated. The process is stable, tolerant and independent of the size, shape and movement of the hearth. However, materials handling (e.g., discharge of hot DRI) and the exact energy savings have to be established in a larger furnace, straight or rotary, and in a continuous mode of operation.

  7. An evaluation of technologies for real-time measurement of rates of outdoor airflow into HVAC systems

    SciTech Connect (OSTI)

    Fisk, William J.; Faulkner, David; Sullivan, Douglas P.

    2004-09-01

    During the last few years, new technologies have been introduced for real-time continuous measurement of the flow rates of outdoor air (OA) into HVAC systems; however, an evaluation of these measurement technologies has not previously been published. This document describes a test system and protocols developed for a controlled evaluation of these measurement technologies. The results of tests of four commercially available measurement technologies and one prototype based on a new design are also summarized. The test system and protocol were judged practical and very useful. The series of tests identified three commercially available measurement technologies that should provide reasonably accurate measurements of OA flow rates as long as air velocities are maintained high enough to produce accurately measurable pressure signals. In HVAC systems with economizer controls, to maintain the required air velocities the OA intake will need to be divided into two sections in parallel, each with a separate OA damper. The errors in OA flow rates measured with the fourth commercially available measurement technology were 20% to 30% with horizontal probes but much larger with vertical probes. The new prototype measurement technology was the only one that appears suitable for measuring OA flow rates over their full range from 20% OA to 100% OA without using two separate OA dampers. All of the measurement devices had pressure drops that are likely to be judged acceptable. The influence of wind on the accuracy of these measurement technologies still needs to be evaluated.

  8. HOW THE ROCKY FLATS ENVIRONMENTAL TECHNOLOGY SITE DEVELOPED A NEW WASTE PACKAGE USING A POLYUREA COATING THAT IS SAFELY AND ECONOMICALLY ELIMINATING SIZE REDUCTION OF LARGE ITEMS

    SciTech Connect (OSTI)

    Dorr, Kent A.; Hogue, Richard S.; Kimokeo, Margaret K.

    2003-02-27

    One of the major challenges involved in closing the Rocky Flats Environmental Technology Site (RFETS) is the disposal of extremely large pieces of contaminated production equipment and building debris. Past practice has been to size reduce the equipment into pieces small enough to fit into approved, standard waste containers. Size reducing this equipment is extremely expensive, and exposes workers to high-risk tasks, including significant industrial, chemical, and radiological hazards. RFETS has developed a waste package using a Polyurea coating for shipping large contaminated objects. The cost and schedule savings have been significant.

  9. Vehicle Technologies Office Merit Review 2015: Advanced Vehicle Test Procedure Development: Hybrid System Power Rating

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced vehicle...

  10. An evaluation of three commercially available technologies forreal-time measurement of rates of outdoor airflow into HVAC systems

    SciTech Connect (OSTI)

    Fisk, William J.; Faulkner, David; Sullivan, Douglas P.

    2004-10-28

    During the last few years, new technologies have been introduced for real-time continuous measurement of the flow rates of outdoor air (OA) into HVAC systems; however, an evaluation of these measurements technologies has not previously been published. This document describes a test system and protocols developed for a controlled evaluation of these measurement technologies. The results of tests of three commercially available measurement technologies are also summarized. The test system and protocol were judged practical and very useful. The three commercially available measurement technologies should provide reasonably, e.g., 20%, accurate measurements of OA flow rates as long as air velocities are maintained high enough to produce accurately measurable pressure signals. In HVAC systems with economizer controls, to maintain the required air velocities the OA intake will need to be divided into two sections in parallel, each with a separate OA damper. All of the measurement devices had pressure drops that are likely to be judged acceptable. The influence of wind on the accuracy of these measurement technologies still needs to be evaluated.

  11. Surface modification, organometallic and polyaryl polymer coatings, and flame spray technologies for preventing corrosion of metals. Final report

    SciTech Connect (OSTI)

    Sugama, T.

    1995-07-01

    To improve adherent properties of electrogalvanized steel (EGS) to polymeric topcoats, the surfaces of EGS were modified by polyelectrolyte-modified zinc phosphating solution. The electrochemical reaction between phosphating solution and EGS led to the complete coverage with fully grown hopeite crystals after only 5 sec treatment, thereby improving adhesion to topcoating and providing protection of EGS against corrosion. To evaluate the ability of polyphenylene sulfide (PPS) polyaryl thermoplastic coatings to protect zinc phosphate (Zn{center_dot}Ph)treated steels from corrosion in a wet, harsh environment ( 1.0 wt % H{sub 2}SO{sub 4}, 3.0 wt % NaCl and 96.0 wt % water at temperatures from 25{degrees} to 200{degree}C), we exposed them in an autoclave to attempt heating-cooling cyclic fatigue tests (1 cycle = 12 hr at 200{degrees}C + 12 hr at 25{degrees}C) up to 90 times. The major chemical reaction at the interface between the PPS and Zn in the Zn-Ph layer during cycling led to the formation of ZnS reaction product, which enhanced the Zn-Ph-to-PPS adhesive bond; correspondingly, there were no signs of peeling and separation of the coating after 90 cycles. organometallosiloxane polymer (OMSP) was synthesized through the hydrolysis-condensation reaction of the mixed precursor solutions of the N-[3-(triethoxysily)propyl]-4,5,-dihydroimidazole and {Beta}-trimethoxysilylethyl-2-pyridine sols in liquor medium and the metal alkoxides and metallocene dichloride dissolved in water or tetrahydrofurane. The OMSP films (thickness, 0. 5 to 1. 0 {mu}m) deposited by simple dip-withdrawing coating methods to aluminum alloys displayed the impedance of > 10{sup 6} ohm-cm {sup 2} after exposure for 40 days in 0.5 N NaCl solution at 25{degrees}C and the 3000 hr-salt spray resistance. Using a flame spray coating process, the methacrylic acid-modified polyethylene copolymer was overlaid onto cold rolled steel surfaces.

  12. Vehicle Technologies Office Merit Review 2014: SAE J2907 Hybrid Motor Ratings Support

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about SAE J2907...

  13. COATED ALLOYS

    DOE Patents [OSTI]

    Harman, C.G.; O'Bannon, L.S.

    1958-07-15

    A coating is described for iron group metals and alloys, that is particularly suitable for use with nickel containing alloys. The coating is glassy in nature and consists of a mixture containing an alkali metal oxide, strontium oxide, and silicon oxide. When the glass coated nickel base metal is"fired'' at less than the melting point of the coating, it appears the nlckel diffuses into the vitreous coating, thus providing a closely adherent and protective cladding.

  14. Aluminide coatings

    DOE Patents [OSTI]

    Henager, Jr; Charles, H [Kennewick, WA; Shin, Yongsoon [Richland, WA; Samuels, William D [Richland, WA

    2009-08-18

    Disclosed herein are aluminide coatings. In one embodiment coatings are used as a barrier coating to protect a metal substrate, such as a steel or a superalloy, from various chemical environments, including oxidizing, reducing and/or sulfidizing conditions. In addition, the disclosed coatings can be used, for example, to prevent the substantial diffusion of various elements, such as chromium, at elevated service temperatures. Related methods for preparing protective coatings on metal substrates are also described.

  15. Vanadium Carbide Coating Process | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vanadium Carbide Coating Process Vanadium Carbide Coating Process Innovative Process Enhances Wear Resistance of Metals, Saving Energy, Waste, and Costs Traditional methods of coating steel surfaces with a layer of hard metal carbide require large capital investment, produce toxic and hazardous gases, are costly to operate, and require multiple heat-treatment steps during processing. Vanadium carbide (VC) coating technology provides a superior protective coating for steel surfaces and eliminates

  16. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A. (Orlando, FL); Campbell, Christian X. (Orlando, FL); Subramanian, Ramesh (Oviedo, FL)

    2009-06-02

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  17. Coated Gold Nanoparticles Found to be Speedy Electron Sponges...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coated Gold Nanoparticles Found to be Speedy Electron Sponges Gold-coated nanoparticles capture electrons at an unprecedented rate in solution. Gold nanoparticles demonstrate the...

  18. Spin coating apparatus

    DOE Patents [OSTI]

    Torczynski, John R.

    2000-01-01

    A spin coating apparatus requires less cleanroom air flow than prior spin coating apparatus to minimize cleanroom contamination. A shaped exhaust duct from the spin coater maintains process quality while requiring reduced cleanroom air flow. The exhaust duct can decrease in cross section as it extends from the wafer, minimizing eddy formation. The exhaust duct can conform to entrainment streamlines to minimize eddy formation and reduce interprocess contamination at minimal cleanroom air flow rates.

  19. Zero discharge organic coatings, powder paint - UV curable paint - E-coat. Volume 1. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Leal, J.; Martin, D.R.; Spadafora, S.J.; Eng, A.T.; Stark, H.

    1995-06-01

    Zero Discharge Organic Coatings project developed powder paint, Ultraviolet (UV) curable paint, and electro- coating (E-coat) paint for military Applications. These technologies offer potential for high performance coatings with little or no volatile organic compound (VOC) emissions or hazardous waste generation. The ZDOC project focused on formulating non-toxic corrosion inhibitors into these coating technologies, and the applications development of powder coatings. Non-toxic replacements for traditional lead and chromate inhibitors were selected based on a previous NAWCADWAR investigation. Once incorporated, the performance of the coatings with and without inhibitors was compared. Also, the protective mechanisms of these inhibitors were studied. The applications development for powder coatings analyzed technologies to allow powder coating of non-conductive substrates and evaluated the use of IR energy to cure powder coatings. Inhibitors were successfully incorporated into electrocoatings and powder coatings, however corrosion performance results varied with coating formulation.

  20. New Generation of MoSx Based Solid Lubricant Coatings: Recent Developments and Applications

    SciTech Connect (OSTI)

    Haider, Julfikar; Hashmi, M. S. J.

    2011-01-17

    In recent times, there is a growing interest in applying Molybdenum disulphide (MoS{sub x}) solid lubricant coatings on components to improve the tribological performance (i.e. lower friction coefficient and wear rate). The tribological performance of MoS{sub x} coating is strongly dependent on coating properties and tribological environment. MoS{sub x} coatings are highly successful in certain applications such as in space/vacuum technology, but its effectiveness is questioned in other terrestrial applications such as in cutting tool industry due to its lower hardness and poor oxidation resistance leading to shorter life. In order to circumvent this drawback, the paper identifies that current research is being concentrated on developing MoS{sub x} based coatings using three different approaches: (1) Metal or compound addition in MoS{sub x} coating (2)MoS{sub x} layer on hard coating and (3)MoS{sub x} addition in hard coating matrix. Although the primary objective is same in all three cases, the third approach is considered to be more effective in improving the tribological properties of the coating. Finally, the potential applications of MoS{sub x} based coatings in different industrial sectors have been briefly outlined.

  1. Rural biogas technology: effect of digester pressure on gas rate and composition

    SciTech Connect (OSTI)

    Hamad, M.A.; Abdel, Dayem, A.M.; El-Halwagi, M.M.

    1983-01-01

    The effect of digester pressure on gas rate and composition was studied using an experimental Chinese-type digester of 5 m/sup 3/ volume. Water buffalo dung was used as feedstock and was fermented at 40 days retention time. The increase in digester pressure was accompanied by a decrease in the amount of biogas produced. However, this decrease was partially compensated for by the increase in methane content. The latter may be attributed to the transfer of carbon dioxide from the gas phase to the liquid phase. The remainder of the noted decrease in the obtained gas amount was related to the increase of the nonconfined amount of slurry in the outlet chamber. Thus, it can be concluded that the initial amount of gas liberated was not a direct consequence of varying the digester pressure. A modified design for the outlet chamber is proposed. Such modification is anticipated to decrease the gas losses, partially stabilize the gas pressure and accordingly increase the efficiency of the digester operation as well as the gas combustion process.

  2. FinalReport for completed IPP-0110 and 0110A Projects:"High Energy Ion Technology of Interfacial Thin Film Coatings for Electronic, Optical and Industrial Applications"

    SciTech Connect (OSTI)

    Brown, Ian

    2009-09-01

    The DOE-supported IPP (Initiatives for Proliferation Prevention) Project, IPP-0110, and its accompanying 'add-on project' IPP-0110A, entitled 'High Energy Ion Technology of Interfacial Thin Film Coatings for Electronic, Optical and Industrial Applications' was a collaborative project involving the Lawrence Berkeley National Laboratory (LBNL) as the U.S. DOE lab; the US surface modification company, Phygen, Inc., as the US private company involved; and the High Current Electronics Institute (HCEI) of the Russian Academy of Sciences, Tomsk, Siberia, Russia, as the NIS Institute involved. Regular scientific research progress meetings were held to which personnel came from all participating partners. The meetings were held mostly at the Phygen facilities in Minneapolis, Minnesota (with Phygen as host) with meetings also held at Tomsk, Russia (HCEI as host), and at Berkeley, California (LBNL as host) In this way, good exposure of all researchers to the various different laboratories involved was attained. This report contains the Final Reports (final deliverables) from the Russian Institute, HCEI. The first part is that for IPP-0110A (the 'main part' of the overall project) and the second part is that for the add-on project IPP-0110A. These reports are detailed, and contain all aspects of all the research carried out. The project was successful in that all deliverables as specified in the proposals were successfully developed, tested, and delivered to Phygen. All of the plasma hardware was designed, made and tested at HCEI, and the performance was excellent. Some of the machine and performance parameters were certainly of 'world class'. The goals and requirements of the IPP Project were well satisfied. I would like to express my gratitude to the DOE IPP program for support of this project throughout its entire duration, and for the unparalleled opportunity thereby provided for all of the diverse participants in the project to join in this collaborative research. The benefits are superb, as measured in quite a number of different ways.

  3. Technolog

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research in Science and Technolog y Sandia pushes frontiers of knowledge to meet the nation's needs, today and tomorrow Sandia National Laboratories' fundamental science and technology research leads to greater understanding of how and why things work and is intrinsic to technological advances. Basic research that challenges scientific assumptions enables the nation to push scientific boundaries. Innovations and breakthroughs produced at Sandia allow it to tackle critical issues, from

  4. Nanolens Window Coatings for Daylighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanolens Window Coatings for Daylighting Nanolens Window Coatings for Daylighting Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech18_alvine_040413.pdf More Documents & Publications Dynamically Responsive Infrared Window Coatings Advanced Facades, Daylighting, and Complex Fenestration Systems Window Daylighting Demo

  5. Corrosion prevention by protective coatings, Second edition

    SciTech Connect (OSTI)

    Munger, C.G.; Vincent, L.D.

    1999-07-01

    This much-used and relied upon book has been revised and updated by Louis D. Vincent to create the second edition. The comprehensive text covers all aspects of the use of high-performance coatings, including an introduction to corrosion as related to coatings, coating characteristics, influence of substrates, organic and zinc coatings, inspection, training, and others. Two new chapters, on elastomeric linings and computer-assisted coatings project management programs, treat new technology developed since the first edition was published. The book is a comprehensive reference tool for engineers, paint superintendents, and maintenance personnel.

  6. Development of Industrially Viable Battery Electrode Coatings | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es162_tenent_2012_o.pdf More Documents & Publications Development of Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings

  7. Low-Friction Hard Coatings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon pm030_erdemir_2011_p.pdf More Documents & Publications Low-Friction Hard Coatings Super Hard Coating Systems

  8. Engine Friction Reduction Through Surface Finish and Coatings | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Friction Reduction Through Surface Finish and Coatings Engine Friction Reduction Through Surface Finish and Coatings Opportunities exist for friction reduction in piston rings and valve trains using durable, advanced material technologies, such as diamond-like carbon (DLC) coatings, and new lubricants. PDF icon deer12_gangopadhyay.pdf More Documents & Publications Low-Friction Hard Coatings Vehicle Technologies Office Merit Review 2014: Development of Modified PAG (polyalkylene

  9. Control Strategies for Centrifugal Pumps with Variable Flow Rate Requirements: Industrial Technologies Program (ITP) Pumping Systems Tip Sheet #12

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    pumping applications with variable fow rate requirements, adjustable speed drives (ASDs) are an effcient control alternative to throttling or bypass methods. ASDs save energy by varying the pump's rotational speed. In centrifugal pumping applications with no static lift, power requirements vary, as the cube of the pump speed and small decreases in speed or fow rate can signifcantly reduce energy use. For example, reducing the speed (fow rate) by 20% can lower input power requirements by

  10. Engine Friction Reduction Through Surface Finish and Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities exist for friction reduction in piston rings and valve trains using durable, advanced material technologies, such as diamond-like carbon (DLC) coatings, and new ...

  11. Vehicle Technologies Office Merit Review 2015: Electrode Coating Defect Analysis and Processing NDE for High-Energy Lithium-Ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrode...

  12. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells | Argonne National Laboratory Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide (TCO) coatings are deposited using atomic layer deposition (ALD). Provides uniform coating of complex, 3D nanostructures such as electrodes for next-generation PV cells Improved coating precision uses less material and reduces cost PDF icon

  13. Coating Active Materials for Applications in Electrochemical Devices |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Coating Active Materials for Applications in Electrochemical Devices Technology available for licensing: A process that includes suspending/dissolving an electro-active material and a carbon precursor in a solvent; and then depositing the carbon precursor on the electro-active material to form a carbon-coated electro-active material Process reduces manufacturing cost Coating process produces carbon-coated metal oxides without the problems associated with

  14. Innovative Cathode Coating Enables Faster Battery Charging, Discharging |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Innovative Cathode Coating Enables Faster Battery Charging, Discharging Technology available for licensing: Coating increases electrical conductivity of cathode materials Coating does not hinder battery performance Provides two coating processes that yield surface-treated, electro-active materials for a variety of applications, such as in a rechargeable lithium battery in both processes, and primary and secondary lithium battery applications in another process.

  15. Corrosion resistant coating

    DOE Patents [OSTI]

    Wrobleski, Debra A. (Los Alamos, NM); Benicewicz, Brian C. (Los Alamos, NM); Thompson, Karen G. (Orlando, FL); Bryan, Coleman J. (Merritt Island, FL)

    1997-01-01

    A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

  16. Corrosion resistant coating

    DOE Patents [OSTI]

    Wrobleski, D.A.; Benicewicz, B.C.; Thompson, K.G.; Bryan, C.J.

    1997-08-19

    A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

  17. Levelized Cost of Coating (LCOC) for selective absorber materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ho, Clifford K.; Pacheco, James E.

    2014-08-08

    A new metric has been developed to evaluate and compare selective absorber coatings for concentrating solar power applications. Previous metrics have typically considered the performance of the selective coating (i.e., solar absorptance and thermal emittance), but cost and durability were not considered. This report describes the development of the levelized cost of coating (LCOC), which is similar to the levelized cost of energy (LCOE) commonly used to evaluate alternative energy technologies. The LCOC is defined as the ratio of the annualized cost of the coating (and associated costs such as labor and number of heliostats required) to the average annualmore » thermal energy produced by the receiver. The baseline LCOC using Pyromark 2500 paint was found to be %240.055/MWht, and the distribution of LCOC values relative to this baseline were determined in a probabilistic analysis to range from -%241.6/MWht to %247.3/MWht, accounting for the cost of additional (or fewer) heliostats required to yield the same baseline average annual thermal energy produced by the receiver. A stepwise multiple rank regression analysis showed that the initial solar absorptance was the most significant parameter impacting the LCOC, followed by thermal emittance, degradation rate, reapplication interval, and downtime during reapplication.« less

  18. Levelized Cost of Coating (LCOC) for selective absorber materials

    SciTech Connect (OSTI)

    Ho, Clifford K.; Pacheco, James E.

    2014-08-08

    A new metric has been developed to evaluate and compare selective absorber coatings for concentrating solar power applications. Previous metrics have typically considered the performance of the selective coating (i.e., solar absorptance and thermal emittance), but cost and durability were not considered. This report describes the development of the levelized cost of coating (LCOC), which is similar to the levelized cost of energy (LCOE) commonly used to evaluate alternative energy technologies. The LCOC is defined as the ratio of the annualized cost of the coating (and associated costs such as labor and number of heliostats required) to the average annual thermal energy produced by the receiver. The baseline LCOC using Pyromark 2500 paint was found to be %240.055/MWht, and the distribution of LCOC values relative to this baseline were determined in a probabilistic analysis to range from -%241.6/MWht to %247.3/MWht, accounting for the cost of additional (or fewer) heliostats required to yield the same baseline average annual thermal energy produced by the receiver. A stepwise multiple rank regression analysis showed that the initial solar absorptance was the most significant parameter impacting the LCOC, followed by thermal emittance, degradation rate, reapplication interval, and downtime during reapplication.

  19. Dynaically Responsive IP Window Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kyle J. Alvine, kyle.alvine@pnnl.gov Pacific Northwest National Laboratory Dynamically Responsive IR Window Coatings 2014 Building Technologies Office Peer Review 2 Project Summary Timeline: Start date: 10/1/2013 (NEW PROJECT) PPG subcontract start: 1/10/2014 Planned end date: 9/30/2015 Key Milestones 1. Milestone 1 (9/30/14) - Go/No Go to demonstrate lab scale dynamic IR responsive coating with 20% NIR Δ and average (visible transmittance) VT ≥ 50%, with T switch range of 30-90°C. 2.

  20. ITP Nanomanufacturing: Nanostructured Superhydrophobic Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanomanufacturing: Nanostructured Superhydrophobic Coatings ITP Nanomanufacturing: Nanostructured Superhydrophobic Coatings nanostructuredsuperhydrophobiccoatings.pdf More...

  1. Colloidal spray method for low cost thin coating deposition

    DOE Patents [OSTI]

    Pham, Ai-Quoc; Glass, Robert S.; Lee, Tae H.

    2005-01-25

    A dense or porous coating of material is deposited onto a substrate by forcing a colloidal suspension through an ultrasonic nebulizer and spraying a fine mist of particles in a carrier medium onto a sufficiently heated substrate. The spraying rate is essentially matched to the evaporation rate of the carrier liquid from the substrate to produce a coating that is uniformly distributed over the surface of the substrate. Following deposition to a sufficient coating thickness, a single sintering step may be used to produce a dense ceramic coating. Using this method, coatings ranging in thickness from about one to several hundred microns can be obtained. By using a plurality of compounds in the colloidal suspension, coatings of mixed composition can be obtained. By using a plurality of solutions and separate pumps and a single or multiple ultrasonic nebulizer(s), and varying the individual pumping rates and/or the concentrations of the solutions, a coating of mixed and discontinuously graded (e.g., stepped) or continuously graded layers may be obtained. This method is particularly useful for depositing ceramic coatings. Dense ceramic coating materials on porous substrates are useful in providing improved electrode performance in devices such as high power density solid oxide fuel cells. Dense ceramic coatings obtained by the invention are also useful for gas turbine blade coatings, sensors, steam electrolyzers, etc. The invention has general use in preparation of systems requiring durable and chemically resistant coatings, or coatings having other specific chemical or physical properties.

  2. Colloidal spray method for low cost thin coating deposition

    DOE Patents [OSTI]

    Pham, Ai-Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA); Lee, Tae H. (Naperville, IL)

    2002-01-01

    A dense or porous coating of material is deposited onto a substrate by forcing a colloidal suspension through an ultrasonic nebulizer and spraying a fine mist of particles in a carrier medium onto a sufficiently heated substrate. The spraying rate is essentially matched to the evaporation rate of the carrier liquid from the substrate to produce a coating that is uniformly distributed over the surface of the substrate. Following deposition to a sufficient coating thickness, a single sintering step may be used to produce a dense ceramic coating. Using this method, coatings ranging in thickness from about one to several hundred microns can be obtained. By using a plurality of compounds in the colloidal suspension, coatings of mixed composition can be obtained. By using a plurality of solutions and separate pumps and a single or multiple ultrasonic nebulizer(s), and varying the individual pumping rates and/or the concentrations of the solutions, a coating of mixed and discontinuously graded (e.g., stepped) or continuously graded layers may be obtained. This method is particularly useful for depositing ceramic coatings. Dense ceramic coating materials on porous substrates are useful in providing improved electrode performance in devices such as high power density solid oxide fuel cells. Dense ceramic coatings obtained by the invention are also useful for gas turbine blade coatings, sensors, steam electrolyzers, etc. The invention has general use in preparation of systems requiring durable and chemically resistant coatings, or coatings having other specific chemical or physical properties.

  3. Mickey Leland Energy Fellowship Report: Development of Advanced Window Coatings

    SciTech Connect (OSTI)

    Bolton, Ladena A.; Alvine, Kyle J.; Schemer-Kohrn, Alan L.

    2014-08-05

    Advanced fenestration technologies for light and thermal management in building applications are of great recent research interest for improvements in energy efficiency. Of these technologies, there is specific interest in advanced window coating technologies that have tailored control over the visible and infrared (IR) scattering into a room for both static and dynamic applications. Recently, PNNL has investigated novel subwavelength nanostructured coatings for both daylighting, and IR thermal management applications. Such coatings rese still in the early stages and additional research is needed in terms of scalable manufacturing. This project investigates aspects of a potential new methodology for low-cost scalable manufacture of said subwavelength coatings.

  4. Low Cost Nanostructured Smart Window Coatings | Department of Energy

    Energy Savers [EERE]

    Low Cost Nanostructured Smart Window Coatings Low Cost Nanostructured Smart Window Coatings 1 of 3 A Heliotrope scientist prepares slot die coater for solution based deposition of electrochromic layer. Image: Heliotrope Technologies 2 of 3 A Heliotrope scientist investigates the coating quality of a slot die deposition of electrochromic layer. Image: Heliotrope Technologies 3 of 3 A Heliotrope scientist investigates the spray coater for a solution based deposition of electrochromic layer. Image:

  5. Low Cost Nanostructured Smart Window Coatings | Department of Energy

    Office of Environmental Management (EM)

    Low Cost Nanostructured Smart Window Coatings Low Cost Nanostructured Smart Window Coatings Addthis 1 of 3 A Heliotrope scientist prepares slot die coater for solution based deposition of electrochromic layer. Image: Heliotrope Technologies 2 of 3 A Heliotrope scientist investigates the coating quality of a slot die deposition of electrochromic layer. Image: Heliotrope Technologies 3 of 3 A Heliotrope scientist investigates the spray coater for a solution based deposition of electrochromic

  6. Vehicle Technologies Office Merit Review 2015: Dramatically Improve the Safety Performance of Li Ion Battery Separators and Reduce the Manufacturing Cost using Ultraviolet Curing and High Precision Coating Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Miltec UV International at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dramatically improve...

  7. Self-assembled nanolaminate coatings (SV)

    SciTech Connect (OSTI)

    Fan, H.

    2012-03-01

    Sandia National Laboratories (Sandia) and Lockheed Martin Aeronautics (LM Aero) are collaborating to develop affordable, self-assembled, nanocomposite coatings and associated fabrication processes that will be tailored to Lockheed Martin product requirements. The purpose of this project is to develop a family of self-assembled coatings with properties tailored to specific performance requirements, such as antireflective (AR) optics, using Sandia-developed self-assembled techniques. The project met its objectives by development of a simple and economic self-assembly processes to fabricate multifunctional coatings. Specifically, materials, functionalization methods, and associated coating processes for single layer and multiple layers coatings have been developed to accomplish high reflective coatings, hydrophobic coatings, and anti-reflective coatings. Associated modeling and simulations have been developed to guide the coating designs for optimum optical performance. The accomplishments result in significant advantages of reduced costs, increased manufacturing freedom/producibility, improved logistics, and the incorporation of new technology solutions not possible with conventional technologies. These self-assembled coatings with tailored properties will significantly address LMC's needs and give LMC a significant competitive lead in new engineered materials. This work complements SNL's LDRD and BES programs aimed at developing multifunctional nanomaterials for microelectronics and optics as well as structure/property investigations of self-assembled nanomaterials. In addition, this project will provide SNL with new opportunities to develop and apply self-assembled nanocomposite optical coatings for use in the wavelength ranges of 3-5 and 8-12 micrometers, ranges of vital importance to military-based sensors and weapons. The SANC technologies will be applied to multiple programs within the LM Company including the F-35, F-22, ADP (Future Strike Bomber, UAV, UCAV, etc.). The SANC technologies will establish LMA and related US manufacturing capability for commercial and military applications therefore reducing reliance on off-shore development and production of related critical technologies. If these technologies are successfully licensed, production of these coatings in manufactory will create significant technical employment opportunities.

  8. Electrocurtain coating process for coating solar mirrors

    DOE Patents [OSTI]

    Kabagambe, Benjamin; Boyd, Donald W.; Buchanan, Michael J.; Kelly, Patrick; Kutilek, Luke A.; McCamy, James W.; McPheron, Douglas A.; Orosz, Gary R.; Limbacher, Raymond D.

    2013-10-15

    An electrically conductive protective coating or film is provided over the surface of a reflective coating of a solar mirror by flowing or directing a cation containing liquid and an anion containing liquid onto the conductive surface. The cation and the anion containing liquids are spaced from, and preferably out of contact with one another on the surface of the reflective coating as an electric current is moved through the anion containing liquid, the conductive surface between the liquids and the cation containing liquid to coat the conductive surface with the electrically conductive coating.

  9. CERC-BEE Cool Roofs and Urban Heat Islands: infrastructure and anti-soiling coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ronnen Levinson, Staff Scientist, LBNL RMLevinson@LBL.gov Scott Hunter, Senior Research Scientist, ORNL HunterSR@ORNL.gov CERC-BEE Cool Roofs and Urban Heat Islands: infrastructure and anti-soiling coatings 2014 Building Technologies Office Peer Review 2 Project Summary (Cool Roof Infrastructure) Timeline: Start date: January 2011 Planned end date: December 2015 Key Milestones 1. Initiate natural exposure trials in many Chinese cities for roof product rating (6/2014) 2. Start black/white/garden

  10. Deposition of Graded Thermal Barrier Coatings for Gas Turbine Blades -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Wind Energy Wind Energy Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Deposition of Graded Thermal Barrier Coatings for Gas Turbine Blades Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (825 KB) Technology Marketing SummarySandia has developed a method and apparatus for depositing thermal barrier coatings on gas turbine

  11. Effects of alpha-zirconium phosphate on thermal degradation and flame retardancy of transparent intumescent fire protective coating

    SciTech Connect (OSTI)

    Xing, Weiyi; Zhang, Ping; Song, Lei; Wang, Xin; Hu, Yuan

    2014-01-01

    Graphical abstract: - Highlights: A transparent intumescent fire protective coating was obtained by UV-cured technology. OZrP could enhance the thermal stability and anti-oxidation of the coating. OZrP could reduce the combustion properties of the coatings. - Abstract: Organophilic alpha-zirconium phosphate (OZrP) was used to improve the thermal and fire retardant behaviors of the phenyl di(acryloyloxyethyl)phosphate (PDHA)-triglycidyl isocyanurate acrylate (TGICA)-2-phenoxyethyl acrylate (PHEA) (PDHA-TGICA-PHEA) coating. The morphology of nanocomposite coating was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The effect of OZrP on the flame retardancy, thermal stability, fireproofing time and char formation of the coatings was investigated by microscale combustion calorimeter (MCC), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), laser Raman spectroscopy (LRS) and scanning electric microscope (SEM). The results showed that by adding OZrP, the peak heat release rate and total heat of combustion were significantly reduced. The highest improvement was achieved with 0.5 wt% OZrP. XPS analysis indicated that the performance of anti-oxidation of the coating was improved with the addition of OZrP, and SEM images showed that a good synergistic effect was obtained through a ceramic-like layer produced by OZrP covered on the surface of char.

  12. Fabrication of nanogradient coatings for laser devices using the method of magnetron sputtering

    SciTech Connect (OSTI)

    Abramov, N F; Volpyan, O D; Obod, Yu A [Open Joint-Stock Company M.F. Stel'makh Polyus Research Institute, Moscow (Russian Federation); Dronskii, R V ['Fotron-Auto' Scientific Manufacture Enterprise, Moscow (Russian Federation)

    2013-09-30

    Significant advantages of the magnetron sputtering method for producing complex high-quality optical coatings for laser devices are shown. Technology aspects of efficient fabrication of such coatings are considered. The capabilities of the developed automated technological and control equipment are described. (nanogradient dielectric coatings and metamaterials)

  13. Flow coating apparatus and method of coating

    DOE Patents [OSTI]

    Hanumanthu, Ramasubrahmaniam; Neyman, Patrick; MacDonald, Niles; Brophy, Brenor; Kopczynski, Kevin; Nair, Wood

    2014-03-11

    Disclosed is a flow coating apparatus, comprising a slot that can dispense a coating material in an approximately uniform manner along a distribution blade that increases uniformity by means of surface tension and transfers the uniform flow of coating material onto an inclined substrate such as for example glass, solar panels, windows or part of an electronic display. Also disclosed is a method of flow coating a substrate using the apparatus such that the substrate is positioned correctly relative to the distribution blade, a pre-wetting step is completed where both the blade and substrate are completed wetted with a pre-wet solution prior to dispensing of the coating material onto the distribution blade from the slot and hence onto the substrate. Thereafter the substrate is removed from the distribution blade and allowed to dry, thereby forming a coating.

  14. Apparatus for coating powders

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Alford, Craig S. (Tracy, CA); McKernan, Mark A. (Livermore, CA)

    2000-01-01

    A process and apparatus for coating small particles and fibers. The process involves agitation by vibrating or tumbling the particles or fibers to promote coating uniformly, removing adsorbed gases and static charges from the particles or fibers by an initial plasma cleaning, and coating the particles or fibers with one or more coatings, a first coating being an adhesion coating, and with subsequent coatings being deposited in-situ to prevent contamination at layer interfaces. The first coating is of an adhesion forming element (i.e. W, Zr, Re, Cr, Ti) of a 100-10,000 .ANG. thickness and the second coating or final coating of a multiple (0.1-10 microns) being Cu or Ag, for example for brazing processes, or other desired materials that defines the new surface related properties of the particles. An essential feature of the coating process is the capability to deposit in-situ without interruption to prevent the formation of a contaminated interface that could adversely affect the coating adhesion. The process may include screening of the material to be coated and either continuous or intermittent vibration to prevent agglomeration of the material to be coated.

  15. Thermal Spray Coatings for Coastal Infrastructure

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, BernardS. Jr.; Cramer, S.D.; Bullard, S.J.

    1997-11-01

    Several protection strategies for coastal infrastructure using thermal-spray technology are presented from research at the Albany Research Center. Thermal-sprayed zinc coatings for anodes in impressed current cathodic protection systems are used to extend the service lives of reinforced concrete bridges along the Oregon coast. Thermal-sprayed Ti is examined as an alternative to the consumable zinc anode. Sealed thermal-sprayed Al is examined as an alternative coating to zinc dust filled polyurethane paint for steel structures.

  16. Nanofilm Coatings Improve Battery Performance - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Nanofilm Coatings Improve Battery Performance Argonne National Laboratory Contact ANL About This Technology <p> TEM 2.5-nm-thick nano-coated ultrathin film on lithium-ion cathode particle surface; coating is highly uniform, in contrast to films applied through conventional technology (for reference, bar in lower-left corner measures 5 nm)</p> TEM 2.5-nm-thick nano-coated ultrathin

  17. Atomically Bonded Transparent Superhydrophobic Coatings

    SciTech Connect (OSTI)

    Aytug, Tolga

    2015-08-01

    Maintaining clarity and avoiding the accumulation of water and dirt on optically transparent surfaces such as US military vehicle windshields, viewports, periscope optical head windows, and electronic equipment cover glasses are critical to providing a high level of visibility, improved survivability, and much-needed safety for warfighters in the field. Through a combination of physical vapor deposition techniques and the exploitation of metastable phase separation in low-alkali borosilicate, a novel technology was developed for the fabrication of optically transparent, porous nanostructured silica thin film coatings that are strongly bonded to glass platforms. The nanotextured films, initially structurally superhydrophilic, exhibit superior superhydrophobicity, hence antisoiling ability, following a simple but robust modification in surface chemistry. The surfaces yield water droplet contact angles as high as 172. Moreover, the nanostructured nature of these coatings provides increased light scattering in the UV regime and reduced reflectivity (i.e., enhanced transmission) over a broad range of the visible spectrum. In addition to these functionalities, the coatings exhibit superior mechanical resistance to abrasion and are thermally stable to temperatures approaching 500C. The overall process technology relies on industry standard equipment and inherently scalable manufacturing processes and demands only nontoxic, naturally abundant, and inexpensive base materials. Such coatings, applied to the optical components of current and future combat equipment and military vehicles will provide a significant strategic advantage for warfighters. The inherent self-cleaning properties of such superhydrophobic coatings will also mitigate biofouling of optical windows exposed to high-humidity conditions and can help decrease repair/replacement costs, reduce maintenance, and increase readiness by limiting equipment downtime.

  18. FABRICATION OF GAS-FILLED TUNGSTEN-COATED GLASS SHELLS

    SciTech Connect (OSTI)

    NIKROO,A; BAUGH,W; STEINMAN,D.A

    2003-06-01

    OAK-B135 Deuterium (D{sub 2}) filled glass shells coated with a high Z element are needed for high energy density (HED) experiments by researchers at Los Alamos National Laboratory. They report here on our initial attempt to produce such shells. Glass shells made using the drop tower technique were coated with gold, palladium or tungsten, or a mixture of two of these elements. It was found that gold and palladium coatings did not stick well to the glass and resulted in poor or delaminated films. Tungsten coatings resulted in films suitable for these targets. Bouncing of shells during coating resulted in uniform tungsten coatings, but the surface of such coatings were filled with small nodules. Proper agitation of shells using a tapping technique resulted in smooth films with minimal particulate contamination. For coating rates of {approx} 0.15 {micro}m/hr coatings with {approx} 2 nm RMS surface finish could be deposited. The surface roughness of coatings at higher rates, 0.7 {micro}m/hr, was considerably worse ({approx} 100 nm RMS). The columnar structure of the coatings allowed permeation filling of the tungsten coated glass shells with deuterium at 300 C.

  19. Fabrication of Gas-Filled Tungsten-Coated Glass Shells

    SciTech Connect (OSTI)

    Nikroo, A.; Baugh, W.; Steinman, D.A.

    2004-03-15

    Deuterium (D{sub 2}) filled glass shells coated with a high Z element are needed for high energy density (HED) experiments by researchers at Los Alamos National Laboratory. We report here on our initial attempt to produce such shells. Glass shells made using the drop tower technique were coated with gold, palladium or tungsten, or a mixture of two of these elements. It was found that gold and palladium coatings did not stick well to the glass and resulted in poor or delaminated films. Tungsten coatings resulted in films suitable for these targets. Bouncing of shells during coating resulted in uniform tungsten coatings, but the surface of such coatings were filled with small nodules. Proper agitation of shells using a tapping technique resulted in smooth films with minimal particulate contamination. For coating rates of {approx}0.15 {mu}m/hr coatings with {approx}2 nm RMS surface finish could be deposited. The surface roughness of coatings at higher rates, 0.7 {mu}m/hr, was considerably worse ({approx}100 nm RMS). The columnar structure of the coatings allowed permeation filling of the tungsten coated glass shells with deuterium at 300 deg. C.

  20. Spin coating of electrolytes

    DOE Patents [OSTI]

    Stetter, Joseph R. (Naperville, IL); Maclay, G. Jordan (Maywood, IL)

    1989-01-01

    Methods for spin coating electrolytic materials onto substrates are disclosed. More particularly, methods for depositing solid coatings of ion-conducting material onto planar substrates and onto electrodes are disclosed. These spin coating methods are employed to fabricate electrochemical sensors for use in measuring, detecting and quantifying gases and liquids.

  1. Vehicle Technologies Office Merit Review 2014: Friction Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together? An integrated surface technology for...

  2. Antibacterial polymer coatings.

    SciTech Connect (OSTI)

    Wilson, Mollye C.; Allen, Ashley N.; Barnhart, Meghan; Tucker, Mark David; Hibbs, Michael R.

    2009-09-01

    A series of poly(sulfone)s with quaternary ammonium groups and another series with aldehyde groups are synthesized and tested for biocidal activity against vegetative bacteria and spores, respectively. The polymers are sprayed onto substrates as coatings which are then exposed to aqueous suspensions of organisms. The coatings are inherently biocidal and do not release any agents into the environment. The coatings adhere well to both glass and CARC-coated coupons and they exhibit significant biotoxicity. The most effective quaternary ammonium polymers kills 99.9% of both gram negative and gram positive bacteria and the best aldehyde coating kills 81% of the spores on its surface.

  3. Nanoscale Reinforced, Polymer Derived Ceramic Matrix Coatings

    SciTech Connect (OSTI)

    Rajendra Bordia

    2009-07-31

    The goal of this project was to explore and develop a novel class of nanoscale reinforced ceramic coatings for high temperature (600-1000 C) corrosion protection of metallic components in a coal-fired environment. It was focused on developing coatings that are easy to process and low cost. The approach was to use high-yield preceramic polymers loaded with nano-size fillers. The complex interplay of the particles in the polymer, their role in controlling shrinkage and phase evolution during thermal treatment, resulting densification and microstructural evolution, mechanical properties and effectiveness as corrosion protection coatings were investigated. Fe-and Ni-based alloys currently used in coal-fired environments do not possess the requisite corrosion and oxidation resistance for next generation of advanced power systems. One example of this is the power plants that use ultra supercritical steam as the working fluid. The increase in thermal efficiency of the plant and decrease in pollutant emissions are only possible by changing the properties of steam from supercritical to ultra supercritical. However, the conditions, 650 C and 34.5 MPa, are too severe and result in higher rate of corrosion due to higher metal temperatures. Coating the metallic components with ceramics that are resistant to corrosion, oxidation and erosion, is an economical and immediate solution to this problem. Good high temperature corrosion protection ceramic coatings for metallic structures must have a set of properties that are difficult to achieve using established processing techniques. The required properties include ease of coating complex shapes, low processing temperatures, thermal expansion match with metallic structures and good mechanical and chemical properties. Nanoscale reinforced composite coatings in which the matrix is derived from preceramic polymers have the potential to meet these requirements. The research was focused on developing suitable material systems and processing techniques for these coatings. In addition, we investigated the effect of microstructure on the mechanical properties and oxidation protection ability of the coatings. Coatings were developed to provide oxidation protection to both ferritic and austentic alloys and Ni-based alloys. The coatings that we developed are based on low viscosity pre-ceramic polymers. Thus they can be easily applied to any shape by using a variety of techniques including dip-coating, spray-coating and painting. The polymers are loaded with a variety of nanoparticles. The nanoparticles have two primary roles: control of the final composition and phases (and hence the properties); and control of the shrinkage during thermal decomposition of the polymer. Thus the selection of the nanoparticles was the most critical aspect of this project. Based on the results of the processing studies, the performance of selected coatings in oxidizing conditions (both static and cyclic) was investigated.

  4. High efficiency turbine blade coatings.

    SciTech Connect (OSTI)

    Youchison, Dennis L.; Gallis, Michail A.

    2014-06-01

    The development of advanced thermal barrier coatings (TBCs) of yttria stabilized zirconia (YSZ) that exhibit lower thermal conductivity through better control of electron beam - physical vapor deposition (EB-PVD) processing is of prime interest to both the aerospace and power industries. This report summarizes the work performed under a two-year Lab-Directed Research and Development (LDRD) project (38664) to produce lower thermal conductivity, graded-layer thermal barrier coatings for turbine blades in an effort to increase the efficiency of high temperature gas turbines. This project was sponsored by the Nuclear Fuel Cycle Investment Area. Therefore, particular importance was given to the processing of the large blades required for industrial gas turbines proposed for use in the Brayton cycle of nuclear plants powered by high temperature gas-cooled reactors (HTGRs). During this modest (~1 full-time equivalent (FTE)) project, the processing technology was developed to create graded TBCs by coupling ion beam-assisted deposition (IBAD) with substrate pivoting in the alumina-YSZ system. The Electron Beam - 1200 kW (EB-1200) PVD system was used to deposit a variety of TBC coatings with micron layered microstructures and reduced thermal conductivity below 1.5 W/m.K. The use of IBAD produced fully stoichiometric coatings at a reduced substrate temperature of 600 oC and a reduced oxygen background pressure of 0.1 Pa. IBAD was also used to successfully demonstrate the transitioning of amorphous PVD-deposited alumina to the -phase alumina required as an oxygen diffusion barrier and for good adhesion to the substrate Ni2Al3 bondcoat. This process replaces the time consuming thermally grown oxide formation required before the YSZ deposition. In addition to the process technology, Direct Simulation Monte Carlo plume modeling and spectroscopic characterization of the PVD plumes were performed. The project consisted of five tasks. These included the production of layered periodic microstructures in the coating, the Direct Simulation Monte Carlo (DSMC) modeling of particle transport in the PVD plume, functional graded layer development, the deposition of all layers to form a complete coating, and materials characterization including thermal testing. Ion beam-assisted deposition, beam sharing through advanced digital rastering, substrate pivoting, hearth calorimetry, infrared imaging, fiber optic-enabled optical emission spectroscopy and careful thermal management were used to achieve all the milestones outlined in the FY02 LDRD proposal.

  5. Thick Thermal Barrier Coatings (TTBCs) for Low Emission, High Efficiency Diesel Engine Components

    SciTech Connect (OSTI)

    M. Brad Beardsley, Caterpillar Inc.; Dr. Darrell Socie, University of Illinois; Dr. Ed Redja, University of Illinois; Dr. Christopher Berndt, State University of New York at Stony Brook

    2006-03-02

    The objective of this program was to advance the fundamental understanding of thick thermal barrier coating (TTBC) systems for application to low heat rejection diesel engine combustion chambers. Previous reviews of thermal barrier coating technology concluded that the current level of understanding of coating system behavior is inadequate and the lack of fundamental understanding may impede the application of thermal barrier coating to diesel engines.(1) Areas of TTBC technology examined in this program include powder characteristics and chemistry; bond coating composition, coating design, microstructure and thickness as they affect properties, durability, and reliability; and TTBC "aging" effects (microstructural and property changes) under diesel engine operating conditions. Fifteen TTBC ceramic powders were evaluated. These powders were selected to investigate the effects of different chemistries, different manufacturing methods, lot-to-lot variations, different suppliers and varying impurity levels. Each of the fifteen materials has been sprayed using 36 parameters selected by a design of experiments (DOE) to determine the effects of primary gas (Ar and N2), primary gas flow rate, voltage, arc current, powder feed rate, carrier gas flow rate, and spraying distance. The deposition efficiency, density, and thermal conductivity of the resulting coatings were measured. A coating with a high deposition efficiency and low thermal conductivity is desired from an economic standpoint. An optimum combination of thermal conductivity and disposition efficiency was found for each lot of powder in follow-on experiments and disposition parameters were chosen for full characterization.(2) Strengths of the optimized coatings were determined using 4-point bending specimens. The tensile strength was determined using free-standing coatings made by spraying onto mild steel substrates which were subsequently removed by chemical etching. The compressive strengths of the coatings were determined using composite specimens of ceramic coated onto stainless steel substrates, tested with the coating in compression and the steel in tension. The strength of the coating was determined from an elastic bi-material analysis of the resulting failure of the coating in compression.(3) Altough initial comparisons of the materials would appear to be straight forward from these results, the results of the aging tests of the materials are necessary to insure that trends in properties remain after long term exposure to a diesel environment. Some comparisons can be made, such as the comparison between for lot-to-lot variation. An axial fatigue test to determine the high cycle fatigue behavior of TTBCs was developed at the University of Illinois under funding from this program.(4) A fatigue test apparatus has been designed and initial work performed which demonstrates the ability to provide a routine method of axial testing of coating. The test fixture replaces the normal load frame and fixtures used to transmit the hydraulic oil loading to the sample with the TTBC specimen itself. The TTBC specimen is a composite metal/coating with stainless steel ends. The coating is sprayed onto a mild steel center tube section onto which the stainless steel ends are press fit. The specimen is then machined. After machining, the specimen is placed in an acid bath which etches the mild steel away leaving the TTBC attached to the the stainless steel ends. Plugs are then installed in the ends and the composite specimen loaded in the test fixture where the hydraulic oil pressurizes each end to apply the load. Since oil transmits the load, bending loads are minimized. This test fixture has been modified to allow piston ends to be attached to the specimen which allows tensile loading as well as compressive loading of the specimen. In addition to the room temperature data, specimens have been tested at 800 Degrees C with the surprising result that at high temperature, the TTBC exhibits much higher fatigue strength. Testing of the TTBC using tension/compression cycling has been conducted using the modified test fixture. The goal of this work was to investigate the failure mechanisms of the coating and to determine if tensile and compressive fatigue damage would interact to influence the resulting life of the coating. Coating samples were run with various mean compressive loads and constant tensile loading approximately equal to 90% of the tensile strength of the coating. The results of this testing shows no interaction of failure resulting from the tensile and compressive load. The material fails in tension at the life predicted by the maximum tensile stress or in compression at the life predicted by the compressive stress. This indicates that there are two differing failure mechanisms for the TTBC in tension and compression.

  6. Corrosion behavior of magnetic ferrite coating prepared by plasma spraying

    SciTech Connect (OSTI)

    Liu, Yi; Wei, Shicheng Tong, Hui; Tian, Haoliang; Liu, Ming; Xu, Binshi

    2014-12-15

    Graphical abstract: The saturation magnetization (M{sub s}) of the ferrite coating is 34.417 emu/g while the M{sub s} value of the ferrite powder is 71.916 emu/g. It can be seen that plasma spray process causes deterioration of the room temperature soft magnetic properties. - Highlights: Spinel ferrite coatings have been prepared by plasma spraying. The coating consists of nanocrystalline grains. The saturation magnetization of the ferrite coating is 34.417 emu/g. Corrosion behavior of the ferrite coating was examined in NaCl solution. - Abstract: In this study, spray dried spinel ferrite powders were deposited on the surface of mild steel substrate through plasma spraying. The structure and morphological studies on the ferrite coatings were carried out using X-ray diffraction, scanning electron microscope and Raman spectroscopy. It was showed that spray dried process was an effective method to prepare thermal spraying powders. The coating showed spinel structure with a second phase of LaFeO{sub 3}. The magnetic property of the ferrite samples were measured by vibrating sample magnetometer. The saturation magnetization (M{sub s}) of the ferrite coating was 34.417 emu/g. The corrosion behavior of coating samples was examined by electrochemical impedance spectroscopy. EIS diagrams showed three corrosion processes as the coating immersed in 3.5 wt.% NaCl solution. The results suggested that plasma spraying was a promising technology for the production of magnetic ferrite coatings.

  7. Material Testing of Coated Alloys in a Syngas Combustion Environment...

    Office of Scientific and Technical Information (OSTI)

    Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6 - Activity 1.13 - Development of a National Center for Hydrogen Technology Citation Details In-Document ...

  8. Shirley Coates Brostmeyer: Changing the (Engineering) Game

    Broader source: Energy.gov [DOE]

    In honor of Women’s History Month, we’ve brought you the stories of several women in the energy and science industries -- past, present and future. This week we spoke with Shirley Coates Brostmeyer, co-founder, CEO and owner of Florida Turbine Technologies, to find out what it takes to run a large engineering company.

  9. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2003-10-14

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  10. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2004-08-31

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  11. Dynamically Responsive Infrared Window Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dynamically Responsive Infrared Window Coatings 2015 Building Technologies Office Peer Review Dr. Kyle J. Alvine, kyle.alvine@pnnl.gov Pacific Northwest National Laboratory 21ºC 50 μm Project Summary Timeline: Start date: 10/1/2013 Planned end date: 6/31/16 Key Milestones 1. (6/30/15) Demonstrate reversible buckling within a temperature window target of 30 C to 90 C over 5-10 cycles (buckle/unbuckle) on a 6" scale - completed February 2015 2. (8/15/15) PPG will complete initial

  12. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi

    1997-01-01

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

  13. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, T.

    1997-02-18

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

  14. Metallic Bipolar Plates with Composite Coatings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metallic Bipolar Plates with Composite Coatings Metallic Bipolar Plates with Composite Coatings Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 PDF icon mawdsley_anl_kickoff.pdf More Documents & Publications Nitrided Metallic Bipolar Plates Low Cost PEM Fuel Cell Metal Bipolar Plates 2013 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office

  15. Embedded Optical Sensors for Thermal Barrier Coatings

    SciTech Connect (OSTI)

    David R. Clarke

    2006-07-31

    The third year of this program on developing embedded optical sensors for thermal barrier coatings has been devoted to two principal topics: (i) continuing the assessment of the long-term, thermal cycle stability of the Eu{sup 3+} doped 8YSZ temperature sensor coatings, and (ii) improving the fiber-optic based luminescence detector system. Following the earlier, preliminary findings, it has been found that not only is the luminescence from the sensors not affected by prolonged thermal cycling, even after 195 hours at 1425 C, but the variation in luminescence lifetime with temperature remains unchanged. As the temperature of 1425 C is much higher than present engines attain or even planned in the foreseeable future, our findings indicate that the Eu{sup 3+} doped thermal barrier coating sensors are very robust and have the potential of being stable throughout the life of coatings. Investigation of Eu{sup 3+} doped coatings prepared by plasma-spraying exhibited the same luminescence characteristics as those prepared by electron-beam evaporation. This is of major significance since thermal barrier coatings can be prepared by both process technologies. A fiber-optic based luminescence system has been constructed in which the hottest section of fiber operates to at least 1250 C.

  16. Coated ceramic breeder materials

    DOE Patents [OSTI]

    Tam, Shiu-Wing; Johnson, Carl E.

    1987-01-01

    A breeder material for use in a breeder blanket of a nuclear reactor is disclosed. The breeder material comprises a core material of lithium containing ceramic particles which has been coated with a neutron multiplier such as Be or BeO, which coating has a higher thermal conductivity than the core material.

  17. Thermal barrier coating

    DOE Patents [OSTI]

    Bowker, Jeffrey Charles (Gibsonia, PA); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL)

    2001-01-01

    A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

  18. Thermal barrier coatings

    DOE Patents [OSTI]

    Alvin, Mary Anne (Pittsburg, PA)

    2010-06-22

    This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.

  19. Radiation control coatings installed on federal buildings at Tyndall Air Force Base. Volume 1: Pre-coating monitoring and fresh coating results

    SciTech Connect (OSTI)

    Petrie, T.W.; Childs, P.W.

    1997-02-01

    The US Department of Energy`s (DOE`s) Federal Energy Management Program (FEMP) supports efforts to reduce energy use and associated expenses in the federal sector. One such effort, the New Technology Demonstration Program (NTDP), seeks to evaluate new energy-saving US technologies and secure their more timely adoption by the US government. Through a partnership with a federal site, the utility serving the site, a manufacturer of an energy-related technology, and other organizations associated with these interests, DOE can evaluate a new technology. The results of the program give federal agency decision makers more hands-on information with which to validate a decision to utilize a new technology in their facilities. The partnership of these interests is secured through a cooperative research and development agreement (CRADA), in this case between Lockheed Martin Energy Research Corporation, the manager of the Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee, and ThermShield International, Ltd., the manufacturer of the technology. This is the first volume of a two-volume report that describes the effects of radiation control coatings installed on federal buildings at Tyndall Air Force Base (AFB) in Florida by ThermShield International. ORNL`s Buildings Technology Center (BTC) was assigned the responsibility for gathering, analyzing, and reporting on the data to describe the effects of the coatings. This volume describes the monitoring plan and its implementation, the results of pre-coating monitoring, the coating installation, results from fresh coatings compared to pre-coating results, and a plan to decommission the monitoring equipment. By including results from roofs at Tyndall AFB and from an outdoor test facility at the BTC, the data cover the range from poorly insulated to well-insulated roofs and two kinds of radiation control coatings on various roof membranes.

  20. Pentek metal coating removal system: Baseline report

    SciTech Connect (OSTI)

    1997-07-31

    The Pentek coating removal technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The Pentek coating removal system consisted of the ROTO-PEEN Scaler, CORNER-CUTTER{reg_sign}, and VAC-PAC{reg_sign}. They are designed to remove coatings from steel, concrete, brick, and wood. The Scaler uses 3M Roto Peen tungsten carbide cutters while the CORNER-CUTTER{reg_sign} uses solid needles for descaling activities. These hand tools are used with the VAC-PAC{reg_sign} vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure minimal, but noise exposure was significant. Further testing for each exposure is recommended because of the environment where the testing demonstration took place. It is feasible that the dust and noise levels will be higher in an enclosed operating environment of different construction. In addition, other areas of concern found were arm-hand vibration, whole-body, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

  1. Nanolens Window Coatings for Daylighting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    coating to redirect daylight deeper into buildings to significantly offset lighting energy. Impact of Project: A successful daylighting coating with high market penetration has ...

  2. W-Coating for MEMS

    SciTech Connect (OSTI)

    Fleming, J.G.; Mani, S.S.; Sniegowski, J.J.

    1999-07-08

    The integration of miniaturized mechanical components has spawned a new technology known as microelectromechanical systems (MEMS). Surface micromachining, defined as the fabrication of micromechanical structures from deposited thin films, is one of the core technological processes underlying MEMS. Surface micromachined structures have a large ratio of surface area to volume which makes them particularly vulnerable to adhesion to the substrate or adjacent structures during release or in use--a problem is called stiction. Since microactuators can have surfaces in normal or sliding contact, function and wear are critical issues for reliable operation of MEMS devices. Surface modifications are needed to reduce adhesion and friction in micromechanical structures. In this paper, we will present a process used to selectively coat MEMS devices with Tungsten using a CVD (Chemical Vapor Deposition) process. We will discuss the effect of wet and vapor phase cleans along with different process variables. Endurance of the W coating is important, especially in applications where wear due to repetitive contacts with the film may occur. Further, tungsten is hard and chemically inert, Tungsten CVD is used in the integrated-circuit industry, which makes this, approach manufacturable.

  3. On-line coating of glass with tin oxide by atmospheric pressure chemical vapor deposition.

    SciTech Connect (OSTI)

    Allendorf, Mark D.; Sopko, J.F. (PPF Industries, Pittsburgh, PA); Houf, William G.; Chae, Yong Kee; McDaniel, Anthony H.; Li, M. (PPF Industries, Pittsburgh, PA); McCamy, J.W.

    2006-11-01

    Atmospheric pressure chemical vapor deposition (APCVD) of tin oxide is a very important manufacturing technique used in the production of low-emissivity glass. It is also the primary method used to provide wear-resistant coatings on glass containers. The complexity of these systems, which involve chemical reactions in both the gas phase and on the deposition surface, as well as complex fluid dynamics, makes process optimization and design of new coating reactors a very difficult task. In 2001 the U.S. Dept. of Energy Industrial Technologies Program Glass Industry of the Future Team funded a project to address the need for more accurate data concerning the tin oxide APCVD process. This report presents a case study of on-line APCVD using organometallic precursors, which are the primary reactants used in industrial coating processes. Research staff at Sandia National Laboratories in Livermore, CA, and the PPG Industries Glass Technology Center in Pittsburgh, PA collaborated to produce this work. In this report, we describe a detailed investigation of the factors controlling the growth of tin oxide films. The report begins with a discussion of the basic elements of the deposition chemistry, including gas-phase thermochemistry of tin species and mechanisms of chemical reactions involved in the decomposition of tin precursors. These results provide the basis for experimental investigations in which tin oxide growth rates were measured as a function of all major process variables. The experiments focused on growth from monobutyltintrichloride (MBTC) since this is one of the two primary precursors used industrially. There are almost no reliable growth-rate data available for this precursor. Robust models describing the growth rate as a function of these variables are derived from modeling of these data. Finally, the results are used to conduct computational fluid dynamic simulations of both pilot- and full-scale coating reactors. As a result, general conclusions are reached concerning the factors affecting the growth rate in on-line APCVD reactors. In addition, a substantial body of data was generated that can be used to model many different industrial tin oxide coating processes. These data include the most extensive compilation of thermochemistry for gas-phase tin-containing species as well as kinetic expressions describing tin oxide growth rates over a wide range of temperatures, pressures, and reactant concentrations.

  4. NETL Technology for Safer, Cleaner Corrosion-Protecting Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coatings Licensed by Pittsburgh Start-Up NETL Technology for Safer, Cleaner Corrosion-Protecting Metal Coatings Licensed by Pittsburgh Start-Up October 23, 2015 - 12:55pm ...

  5. Analyzing the performance of diamond-coated micro end mills.

    SciTech Connect (OSTI)

    Torres, C. D.; Heaney, P. J.; Sumant, A. V.; Hamilton, M. A.; Carpick, R. W.; Pfefferkorn, F. E.; Univ. of Wisconsin at Madison; Univ. of Pennsylvania

    2009-06-01

    A method is presented to improve the tool life and cutting performance of 300 {micro}m diameter tungsten carbide (WC) micro end mills by applying thin (<300 nm) fine-grained diamond (FGD) and nanocrystalline diamond (NCD) coatings using the hot-filament chemical vapor deposition (HF-CVD) process. The performance of the diamond-coated tools has been evaluated by comparing their performance in dry slot milling of 6061-T6 aluminum against uncoated WC micro end mills. Tool wear, coating integrity, and chip morphology were characterized using SEM and white light interferometry. The initial test results show a dramatic improvement in the tool integrity (i.e., corners not breaking off), a lower wear rate, no observable adhesion of aluminum to the diamond-coated tool, and a significant reduction in the cutting forces (>50%). Reduction of the cutting forces is attributed to the low friction and adhesion of the diamond coating. However, approximately 80% of the tools coated with the larger FGD coatings failed during testing due to delamination. Additional machining benefits were attained for the NCD films, which was obtained by using a higher nucleation density seeding process for diamond growth. This process allowed for thinner, smaller grained diamond coatings to be deposited on the micro end mills, and enabled continued operation of the tool even after the integrity of the diamond coating had been compromised. As opposed to the FGD-coated end mills, only 40% of the NCD-tools experienced delamination issues.

  6. Vehicle Technologies Office Merit Review 2015: Development of Industrially

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Viable Battery Electrode Coatings | Department of Energy Development of Industrially Viable Battery Electrode Coatings Vehicle Technologies Office Merit Review 2015: Development of Industrially Viable Battery Electrode Coatings Presentation given by National Renewable Energy Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about development of industrially viable battery electrode coatings. PDF icon

  7. Researchers to Develop Paint-On Coating for Energy Efficient Windows

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Researchers to Develop Paint-On Coating for Energy Efficient Windows Raymond Weitekamp of Cyclotron Road will be working with Arman Shehabi and Steve Selkowitz of the Energy Technologies Area to develop a low-cost, heat-reflective paintable coating for energy efficient windows. The technology relies on a material called a bottlebrush polymer, which, as Weitekamp explains, are like gummy worms

  8. Tantalum coatings for the petrochemical industry

    SciTech Connect (OSTI)

    Hays, C.; Watson, J.L. Sr.; Walker, J.P. Jr.

    1995-12-31

    Tantalum coatings have never been a cost attractive item for the petrochemical industry but corrosion-resistant tantalum coatings have been and continue to be a very cost effective solution for many complex metallurgical applications. There are certain environments where thermally-sprayed tantalum has little or no competition from all other corrosion-resistant-alloy-coatings (CRAC). This paper reviews tantalum technology in terms of the relevant petrochemical needs and priorities. Selected properties of both tantalum (Ta) and Ta{sub 2}O{sub 5} are given along with a brief history of tantalum and Ta coatings. Some important discussion is also given about the very difficult development path that tantalum has been forced to overcome. This characterization study involves 2 different applicators and two competitive processes; i.e., plasma and high velocity oxygen flame (HVOF) spraying. Test coupons from this cooperative effort by Watson and Gartner are evaluated in terms of structure, properties and composition. Electron and optical metallography are both used with microhardness and associated methods of characterization for thermal spray coatings.

  9. Multilayer optical dielectric coating

    DOE Patents [OSTI]

    Emmett, John L. (Pleasanton, CA)

    1990-01-01

    A highly damage resistant, multilayer, optical reflective coating includes alternating layers of doped and undoped dielectric material. The doping levels are low enough that there are no distinct interfaces between the doped and undoped layers so that the coating has properties nearly identical to the undoped material. The coating is fabricated at high temperature with plasma-assisted chemical vapor deposition techniques to eliminate defects, reduce energy-absorption sites, and maintain proper chemical stoichiometry. A number of differently-doped layer pairs, each layer having a thickness equal to one-quarter of a predetermined wavelength in the material are combined to form a narrowband reflective coating for a predetermined wavelength. Broadband reflectors are made by using a number of narrowband reflectors, each covering a portion of the broadband.

  10. Aluminum phosphate coatings

    DOE Patents [OSTI]

    Sambasivan, Sankar (Chicago, IL); Steiner, Kimberly A. (Chicago, IL); Rangan, Krishnaswamy K. (Evanston, IL)

    2007-12-25

    Aluminophosphate compounds and compositions as can be used for substrate or composite films and coating to provide or enhance, without limitation, planarization, anti-biofouling and/or anti-microbial properties.

  11. Friction surfaced Stellite6 coatings

    SciTech Connect (OSTI)

    Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid; Ram, G.D. Janaki; Reddy, G. Madhusudhan; Nagalakshmi, R.

    2012-08-15

    Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material for friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.

  12. Ceramic electrolyte coating methods

    DOE Patents [OSTI]

    Seabaugh, Matthew M.; Swartz, Scott L.; Dawson, William J.; McCormick, Buddy E.

    2004-10-12

    Processes for preparing aqueous suspensions of a nanoscale ceramic electrolyte material such as yttrium-stabilized zirconia. The invention also includes a process for preparing an aqueous coating slurry of a nanoscale ceramic electrolyte material. The invention further includes a process for depositing an aqueous spray coating slurry including a ceramic electrolyte material on pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.

  13. Rate Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  14. Multilayer thermal barrier coating systems

    DOE Patents [OSTI]

    Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

    2000-01-01

    The present invention generally describes multilayer thermal barrier coating systems and methods of making the multilayer thermal barrier coating systems. The thermal barrier coating systems comprise a first ceramic layer, a second ceramic layer, a thermally grown oxide layer, a metallic bond coating layer and a substrate. The thermal barrier coating systems have improved high temperature thermal and chemical stability for use in gas turbine applications.

  15. Hybrid Polymer/Nanoparticle Multi-Functional Optical Coatings - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Hybrid Polymer/Nanoparticle Multi-Functional Optical Coatings Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (863 KB) Two R&amp;D Awards- 2007 &amp; 2010 Two R&D Awards- 2007 & 2010 Technology Marketing SummaryHybrid polymer-nanocrystal optical coatings are a platform technology in the field of multilayered films, and are seen in a variety of consumer products. The methods currently used to

  16. Bond Coating Performance of Thermal Barrier Coatings for Industrial Gas Turbines

    SciTech Connect (OSTI)

    Wright, Ian G; Pint, Bruce A

    2005-01-01

    Thermal barrier coatings are intended to work in conjunction with internal cooling schemes to reduce the metal temperature of critical hot gas path components in gas turbine engines. The thermal resistance is typically provided by a 100--250 {mu}m thick layer of ceramic (most usually zirconia stabilized with an addition of 7--8 wt% of yttria), and this is deposited on to an approximately 50 {mu} thick, metallic bond coating that is intended to anchor the ceramic to the metallic surface, to provide some degree of mechanical compliance, and to act as a reservoir of protective scale-forming elements (Al) to protect the underlying superalloy from high-temperature corrosion. A feature of importance to the durability of thermal barrier coatings is the early establishment of a continuous, protective oxide layer (preferably {alpha}-alumina) at the bond coating-ceramic interface. Because zirconia is permeable to oxygen, this oxide layer continues to grow during service. Some superalloys are inherently resistant to high-temperature oxidation, so a separate bond coating may not be needed in those cases. Thermal barrier coatings have been in service in aeroengines for a number of years, and the use of this technology for increasing the durability and/or efficiency of industrial gas turbines is currently of significant interest. The data presented were taken from an investigation of routes to optimize bond coating performance, and the focus of the paper is on the influences of reactive elements and Pt on the oxidation behaviour of NiAl-based alloys determined in studies using cast versions of bond coating compositions.

  17. Underwater Coatings for Contamination Control

    SciTech Connect (OSTI)

    Julia L. Tripp; Kip Archibald; Ann-Marie Phillips; Joseph Campbell

    2004-02-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is deactivating several fuel storage basins. Airborne contamination is a concern when the sides of the basins are exposed and allowed to dry during water removal. One way of controlling this airborne contamination is to fix the contamination in place while the pool walls are still submerged. There are many underwater coatings available on the market that are used in marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives are easily applied and adhere well to the substrates (pool wall materials) found in INEEL fuel pools. The four pools considered included 1) Test Area North (TAN-607) with epoxy painted concrete walls; 2) Idaho Nuclear Technology and Engineering Center (INTEC) (CPP-603) with bare concrete walls; 3) Materials Test Reactor (MTR) Canal with stainless steel lined concrete walls; and 4) Power Burst Facility (PBF-620) with stainless steel lined concrete walls on the bottom and epoxy painted carbon steel lined walls on the upper portions. Therefore, the four materials chosen for testing included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The typical water temperature of the pools varies from 55oF to 80oF dependent on the pool and the season. These tests were done at room temperature. The following criteria were used during this evaluation. The underwater coating must: Be easy to apply Adhere well to the four surfaces of interest Not change or have a negative impact on water chemistry or clarity Not be hazardous in final applied form Be proven in other underwater applications. In addition, it is desirable for the coating to have a high pigment or high cross-link density to prevent radiation from penetrating. This paper will detail the testing completed and the test results. A proprietary two-part, underwater epoxy owned by S. G. Pinney and Associates was selected to be applied by divers after scrubbing loose contamination off the basin walls and floors using a ship hull scrubber and vacuuming up the sludge. A special powered roller with two separate heated hoses that allowed the epoxy to mix at the roller surface was used to eliminate pot time concerns. The walls were successfully coated and water was removed from the pool with no airborne contamination problems.

  18. Coated Fiber Neutron Detector Test

    SciTech Connect (OSTI)

    Lintereur, Azaree T.; Ely, James H.; Kouzes, Richard T.; Stromswold, David C.

    2009-10-23

    Radiation portal monitors used for interdiction of illicit materials at borders include highly sensitive neutron detection systems. The main reason for having neutron detection capability is to detect fission neutrons from plutonium. The currently deployed radiation portal monitors (RPMs) from Ludlum and Science Applications International Corporation (SAIC) use neutron detectors based upon 3He-filled gas proportional counters, which are the most common large neutron detector. There is a declining supply of 3He in the world, and thus, methods to reduce the use of this gas in RPMs with minimal changes to the current system designs and sensitivity to cargo-borne neutrons are being investigated. Reported here are the results of tests of the 6Li/ZnS(Ag)-coated non-scintillating plastic fibers option. This testing measured the required performance for neutron detection efficiency and gamma ray rejection capabilities of a system manufactured by Innovative American Technology (IAT).

  19. Structurally Integrated Coatings for Wear and Corrosion

    SciTech Connect (OSTI)

    Beardsley, M. Brad; Sebright, Jason L.

    2008-11-18

    Wear and corrosion of structures cuts across industries and continues to challenge materials scientists and engineers to develop cost effective solutions. Industries typically seek mature technologies that can be implemented for production with rapid or minimal development and have little appetite for the longer-term materials research and development required to solve complex problems. The collaborative work performed in this project addressed the complexity of this problem in a multi-year program that industries would be reluctant to undertake without government partnership. This effort built upon the prior development of Advanced Abrasion Resistant Materials conduct by Caterpillar Inc. under DOE Cooperative Agreement No. DE-FC26-01NT41054. In this referenced work, coatings were developed that exhibited significant wear life improvements over standard carburized heat treated steel in abrasive wear applications. The technology used in this referenced work, arc lamp fusing of thermal spray coatings, was one of the primary technical paths in this work effort. In addition to extending the capability of the coating technology to address corrosion issues, additional competitive coating technologies were evaluated to insure that the best technology was developed to meet the goals of the program. From this, plasma transferred arc (PTA) welding was selected as the second primary technology that was investigated. Specifically, this project developed improved, cost effective surfacing materials and processes for wear and corrosion resistance in both sliding and abrasive wear applications. Materials with wear and corrosion performance improvements that are 4 to 5 times greater than heat treated steels were developed. The materials developed were based on low cost material systems utilizing ferrous substrates and stainless steel type matrix with hard particulates formed from borides and carbides. Affordability was assessed against other competing hard surfacing or coating techniques, balanced with overall materials performance. State-of-the-art design and simulation capabilities were used to guide materials and process refinement. Caterpillar was the lead of the multi-partner collaborative project. Specific tasks were performed by the partners base on their unique capabilities. The project team was selected to include leaders in the field of material development, processing, modeling, and material characterization. Specifically, industrial members include the suppliers Deloro Stellite and Powder Alloy Corporation., who provided the experimental alloys and who aided in the development of the costs for the alloys, the Missouri University of Science and Technology and Iowa State University, who provided help in the alloy development and material characterization, QuesTek Innovations, a small company specializing the microstructural modeling of materials, and the DOE laboratories, Oak Ridge National Laboratory and National Energy Technology Laboratory (Albany), who provided unique coating process capability and wear characterization testing. The technologies developed in this program are expected to yield energy savings of about 50% over existing technologies, or 110 trillion BTUs per year by 2020 when fully implemented. Primary applications by Caterpillar are to replace the surface of machine components which are currently carburized and heat treated with new cladding materials with double the wear life. The new cladding technologies will consume less energy than carburizing. Thus, nearly 50% energy savings can be expected as a result from elimination of the heat treat process and the reduce wear of the materials. Additionally, when technologies from this project are applied on titanium or other non-ferrous substrates to make lighter weight, more wear resistant, and more efficient structures, significant fuel savings can be realized. With the anticipated drastic reduction in cost for refining titanium-containing ores, the usage of titanium alloys in earthmoving and related machinery is expected to increase multiple folds in the next d

  20. Fabrics coated with lubricated nanostructures display robust omniphobicity

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Fabrics coated with lubricated nanostructures display robust omniphobicity « Prev Next » Title: Fabrics coated with lubricated nanostructures display robust omniphobicity The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are

  1. Device and Method for Fluidizing and Coating of Ultrafine Particles |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Device and Method for Fluidizing and Coating of Ultrafine Particles Technology available for licensing: An ultrathin surface coating composed of metal oxides that, when applied to granular electrode materials on a large scale, promises to solve the structural instability of electrode materials and the resulting rapid fade of cell capacity at high voltages and high temperatures in lithium-ion batteries A low-cost, scalable process for increasing structural

  2. Development of Steel Fastener Nano-Ceramic Coatings for Corrosion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Protection of Magnesium Parts (AMD-704) | Department of Energy Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium Parts (AMD-704) Development of Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium Parts (AMD-704) 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon lm052_osborne_2012_o.pdf More Documents & Publications AMD 405: Improved Automotive Suspension

  3. Stay-Clean and Durable White Elastomeric Roof Coatings (ERCs)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stay-Clean and Durable White 2014 Building Technologies Office Elastomeric Roof Coatings (ERCs) Peer Review CRADA with Dow Chemical aged Challenge: speed the development of high performance white coatings that resist soiling, last longer, and save more energy new Mohamad Sleiman MSleiman@LBL.gov Hugo Destaillats HDestaillats@LBL.gov Ronnen Levinson RMLevinson@LBL.gov Lawrence Berkeley National Laboratory Project Summary Timeline: Start date: 10/2011 Planned end date: 9/2014 Key Milestones *

  4. Workshop on coatings needs in the auto industry

    SciTech Connect (OSTI)

    Courtright, E.L.

    1993-05-01

    New lightweight materials continue to be of great interest to the automotive industry. Compared to 20 years ago, the average vehicle weight has been reduced by almost a fourth, and fuel economy has nearly doubled. While continued improvements are both desirable and possible, materials choices are narrowing and the manufacturing methods needed to produce advanced materials systems are much more costly. The incentives remain high, however; particularly in view of large payoffs associated with minimizing structural weight in electric and hybrid-type vehicles. One generic solution is to develop coatings that will enable the use of lower cost materials. A workshop on coatings needs in the auto industry was held in Detroit, Michigan on October 27 and 28, 1992 with the objective of identifying research needs where coatings could enhance the use of energy efficient lightweight materials for automotive applications. Four generic areas had previously been identified auto manufacturers and industry suppliers. These were: Wear Coatings, Hard Protective Coatings for Plastics, Solar Control Coatings, and Process Manufacturing Issues. The development of coatings and coating technologies for lightweight metals and metal matrix composites emerged as the number one research needs. This need underscores the interest in making better use of existing lightweight metals, e.g. magnesium, aluminum, and their alloys. Coatings to protect plastics and reinforced plastic composites were also identified as a major area of importance. Protection from automotive liquids and gases. Coatings that will improve mar resistance, resist UV degradation, or eliminate degradation due to moisture absorption are also needed. Accordingly, manufacturability issues associated with coating light metals, e.g. aluminum, magnesium, and metal matrix composites with wear and corrosion resistant materials, were identified as a high priority research need.

  5. METHOD OF PROTECTIVELY COATING URANIUM

    DOE Patents [OSTI]

    Eubank, L.D.; Boller, E.R.

    1959-02-01

    A method is described for protectively coating uranium with zine comprising cleaning the U for coating by pickling in concentrated HNO/sub 3/, dipping the cleaned U into a bath of molten zinc between 430 to 600 C and containing less than 0 01% each of Fe and Pb, and withdrawing and cooling to solidify the coating. The zinccoated uranium may be given a; econd coating with another metal niore resistant to the corrosive influences particularly concerned. A coating of Pb containing small proportions of Ag or Sn, or Al containing small proportions of Si may be applied over the zinc coatings by dipping in molten baths of these metals.

  6. Influence of insulating coating on aluminum wire explosions

    SciTech Connect (OSTI)

    Li, Yang; Wu, Jian; Sheng, Liang; Zhao, Jizhen; Zhang, Mei; Yuan, Yuan; Peng, Bodong; Li, Xingwen

    2014-10-15

    Single wire explosions are widely used in understanding the early stages of z-pinch experiments. This paper presents a serial of experiments conducted on the pulse power generator with ?1?kA peak current and ?10?ns rising time in Xi'an Jiao Tong University. Polyimide coated aluminum wires and uncoated ones were tested under three different voltages to analyze the effect of insulating coating. Experimental results showed that insulating coating can increase the energy deposition 10%?30% in aluminum wires by delaying the voltage collapse and raising the maximum load resistance. The substantial energy deposition resulted in about 20% faster expansion rates for coated wires. Experimental evidence that plasma channel shunts the current from the wire core was observed by streak camera and schlieren graphs. This paper also briefly discussed the influence of nonuniform coating on the morphology of wire expansion.

  7. Vehicle Technologies Office Merit Review 2015: A Novel Lubricant...

    Office of Environmental Management (EM)

    through Surface Modification (Agreement ID:23284) Project ID:18518 Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together?...

  8. Chapter 6: Innovating Clean Energy Technologies in Advanced Manufactur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Thermal sprayed metallic coatings (aluminum and zinc) are emerging technologies that could ... to mitigate corrosion of a metal by coupling it with a sacrificial anode, such as zinc. ...

  9. New Window Technology Saves Energy and the View | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    insulations. By combining vacuum insulation materials and processes with low-e coated plastic films, the new technology will boost the energy efficiency of current window...

  10. Preparation of hydrophobic coatings

    DOE Patents [OSTI]

    Branson, Eric D. (Albuquerque, NM); Shah, Pratik B. (Albuquerque, NM); Singh, Seema (Rio Rancho, NM); Brinker, C. Jeffrey (Albuquerque, NM)

    2009-02-03

    A method for preparing a hydrophobic coating by preparing a precursor sol comprising a metal alkoxide, a solvent, a basic catalyst, a fluoroalkyl compound and water, depositing the precursor sol as a film onto a surface, such as a substrate or a pipe, heating, the film and exposing the film to a hydrophobic silane compound to form a hydrophobic coating with a contact angle greater than approximately 150.degree.. The contact angle of the film can be controlled by exposure to ultraviolet radiation to reduce the contact angle and subsequent exposure to a hydrophobic silane compound to increase the contact angle.

  11. Fiber coating method

    DOE Patents [OSTI]

    Corman, Gregory Scot (Ballston Lake, NY)

    2001-01-01

    A coating is applied to reinforcing fibers arranged into a tow by coaxially aligning the tow with an adjacent separation layer and winding or wrapping the tow and separation layer onto a support structure in an interleaved manner so that the separation layer separates a wrap of the tow from an adjacent wrap of the tow. A coating can then be uniformly applied to the reinforcing fibers without defects caused by fiber tow to fiber tow contact. The separation layer can be a carbon fiber veil.

  12. Fiber coating method

    DOE Patents [OSTI]

    Corman, Gregory Scot (Ballston Lake, NY)

    2003-04-15

    A coating is applied to reinforcing fibers arranged into a tow by coaxially aligning the tow with an adjacent separation layer and winding or wrapping the tow and separation layer onto a support structure in an interleaved manner so that the separation layer separates a wrap of the tow from an adjacent wrap of the tow. A coating can then be uniformly applied to the reinforcing fibers without defects caused by fiber tow to fiber tow contact. The separation layer can be a carbon fiber veil.

  13. Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6

    Office of Scientific and Technical Information (OSTI)

    - Activity 1.13 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6 - Activity 1.13 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6 - Activity 1.13 - Development of a National Center for Hydrogen Technology Modifications were made to the inlet of

  14. Thermal barrier coating for alloy systems

    DOE Patents [OSTI]

    Seals, Roland D. (Oak Ridge, TN); White, Rickey L. (Harriman, TN); Dinwiddie, Ralph B. (Knoxville, TN)

    2000-01-01

    An alloy substrate is protected by a thermal barrier coating formed from a layer of metallic bond coat and a top coat formed from generally hollow ceramic particles dispersed in a matrix bonded to the bond coat.

  15. AntiReflection Coating D

    SciTech Connect (OSTI)

    AIKEN,DANIEL J.

    1999-09-23

    Analytical expressions used to optimize AR coatings for single junction solar cells are extended for use in monolithic, series interconnected multi-junction solar cell AR coating design. The result is an analytical expression which relates the solar cell performance (through J{sub sc}) directly to the AR coating design through the device reflectance. It is also illustrated how AR coating design be used to provide an additional degree of freedom for current matching multi-junction devices.

  16. Biodegradation of polymer coatings

    SciTech Connect (OSTI)

    Jones, W.R.; Walch, M.; Jones-Meehan, J.

    1994-12-31

    Conventional paint removal methods include chemical stripping with VOCs blasting with plastic media, and delamination with high pressure water. These methods have many limitations, in that they are labor intensive, pose human health risks, are relatively expensive and pose significant waste disposal problems. However, polymeric coatings are known to contain structural components, such as ester, amide and urea linkages, that can be degraded biologically. The authors are working to develop a stable, enzyme-based, non-toxic paint stripping strategy that will be environmentally safe and cost effective. The specific objectives are to identify and characterize microbial systems capable of degrading polymeric coatings, to develop a quantitative degradation assay and to optimize activity levels for subsequent purification and concentration of the biological products required for rapid degradation of coatings. A water-dispersed colloid of an ester-based polyurethane polymer has been used in solid growth medium to screen about 100 different bacteria for microbial degradation activity. Those with demonstrable activity have been grown in the presence of epoxy-polyamide paint- and polyester polyurethane paint-coated aluminum coupons. The authors have demonstrated delamination under certain conditions and have developed a spectrophotometric method for quantitating degradation activity as a function of dye release.

  17. Final Technical Report - Recovery Act: Organic Coatings as Encapsulants for Low Cost, High Performance PV Modules

    SciTech Connect (OSTI)

    Stuart Hellring; Jiping Shao; James Poole

    2011-12-05

    The objective of this project was to evaluate the feasibility of utilizing PPG's commercial organic coatings systems as efficient, modernized encapsulants for low cost, high performance, thin film photovoltaic modules. Our hypothesis was that the combination of an anticorrosive coating with a more traditional barrier topcoat would mitigate many electrochemical processes that are now responsible for the significant portion of photovoltaic (PV) failures, thereby nullifying the extremely high moisture barrier requirements of currently used encapsulation technology. Nine commercially available metal primer coatings and six commercially available top coatings were selected for screening. Twenty-one different primer/top coat combinations were evaluated. The primer coatings were shown to be the major contributor to corrosion inhibition, adhesion, and barrier properties. Two primer coatings and one top coating were downselected for testing on specially-fabricated test modules. The coated test modules passed initial current leakage and insulation testing. Damp Heat testing of control modules showed visible corrosion to the bus bar metal, whereas the coated modules showed none. One of the primer/top coat combinations retained solar power performance after Damp Heat testing despite showing some delamination at the EVA/solar cell interface. Thermal Cycling and Humidity Freeze testing resulted in only one test module retaining its power performance. Failure modes depended on the particular primer/top coating combination used. Overall, this study demonstrated that a relatively thin primer/top coating has the potential to replace the potting film and backsheet in crystalline silicon-based photovoltaic modules. Positive signals were received from commercially available coatings developed for applications having performance requirements different from those required for photovoltaic modules. It is likely that future work to redesign and customize these coatings would result in a coating system meeting the requirements for photovoltaic module encapsulation.

  18. Low friction and galling resistant coatings and processes for coating

    DOE Patents [OSTI]

    Johnson, Roger N. (Richland, WA)

    1987-01-01

    The present invention describes coating processes and the resultant coated articles for use in high temperature sodium environments, such as those found in liquid metal fast breeder reactors and their associated systems. The substrate to which the coating is applied may be either an iron base or nickel base alloy. The coating itself is applied to the substrate by electro-spark deposition techniques which result in metallurgical bonding between the coating and the substrate. One coating according to the present invention involves electro-spark depositing material from a cemented chromium carbide electrode and an aluminum electrode. Another coating according to the present invention involves electro-spark depositing material from a cemented chromium carbide electrode and a nickel-base hardfacing alloy electrode.

  19. Glass Coating Makes Solar Panels More Efficient | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glass Coating Makes Solar Panels More Efficient Glass Coating Makes Solar Panels More Efficient May 13, 2015 - 9:20am Addthis The new technology repels water and reduces the sunlight reflected off a glass surface. | Photo courtesy of Flickr user h080. The new technology repels water and reduces the sunlight reflected off a glass surface. | Photo courtesy of Flickr user h080. Pat Adams Pat Adams Digital Content Specialist, Office of Public Affairs Have you ever treated your windshield with Rain-X

  20. Proceedings of the 1987 coatings for advanced heat engines workshop

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    This Workshop was conducted to enhance communication among those involved in coating development for improved heat engine performance and durability. We were fortunate to have Bill Goward review the steady progress and problems encountered along the way in the use of thermal barrier coatings (TBC) in aircraft gas turbine engines. Navy contractors discussed their work toward the elusive goal of qualifying TBC for turbine airfoil applications. In the diesel community, Caterpillar and Cummins are developing TBC for combustion chamber components as part of the low heat rejection diesel engine concept. The diesel engine TBC work is based on gas turbine technology with a goal of more than twice the thickness used on gas turbine engine components. Adoption of TBC in production for diesel engines could justify a new generation of plasma spray coating equipment. Increasing interests in tribology were evident in this Workshop. Coatings have a significant role in reducing friction and wear under greater mechanical loadings at higher temperatures. The emergence of a high temperature synthetic lubricant could have an enormous impact on diesel engine design and operating conditions. The proven coating processes such as plasma spray, electron-beam physical vapor deposition, sputtering, and chemical vapor deposition have shown enhanced capabilities, particularly with microprocessor controls. Also, the newer coating schemes such as ion implantation and cathodic arc are demonstrating intriguing potential for engine applications. Coatings will play an expanding role in higher efficiency, more durable heat engines.

  1. Initial Assessment of Environmental Barrier Coatings for the Prometheus Project

    SciTech Connect (OSTI)

    M. Frederick

    2005-12-15

    Depending upon final design and materials selections, a variety of engineering solutions may need to be considered to avoid chemical degradation of components in a notional space nuclear power plant (SNPP). Coatings are one engineered approach that was considered. A comprehensive review of protective coating technology for various space-reactor structural materials is presented, including refractory metal alloys [molybdenum (Mo), tungsten (W), rhenium (Re), tantalum (Ta), and niobium (Nb)], nickel (Ni)-base superalloys, and silicon carbide (Sic). A summary description of some common deposition techniques is included. A literature survey identified coatings based on silicides or iridium/rhenium as the primary methods for environmental protection of refractory metal alloys. Modified aluminide coatings have been identified for superalloys and multilayer ceramic coatings for protection of Sic. All reviewed research focused on protecting structural materials from extreme temperatures in highly oxidizing conditions. Thermodynamic analyses indicate that some of these coatings may not be protective in the high-temperature, impure-He environment expected in a Prometheus reactor system. Further research is proposed to determine extensibility of these coating materials to less-oxidizing or neutral environments.

  2. Antithrombogenic Polymer Coating.

    DOE Patents [OSTI]

    Huang, Zhi Heng (San Ramon, CA); McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

    2003-01-21

    An article having a non-thrombogenic surface and a process for making the article are disclosed. The article is formed by (i) coating a polymeric substrate with a crosslinked chemical combination of a polymer having at least two amino substituted side chains, a crosslinking agent containing at least two crosslinking functional groups which react with amino groups on the polymer, and a linking agent containing a first functional group which reacts with a third functional group of the crosslinking agent, and (ii) contacting the coating on the substrate with an antithrombogenic agent which covalently bonds to a second functional group of the linking agent. In one example embodiment, the polymer is a polyamide having amino substituted alkyl chains on one side of the polyamide backbone, the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl, the linking agent is a polyhydrazide and the antithrombogenic agent is heparin.

  3. Rate Schedules

    Broader source: Energy.gov [DOE]

    One of the major responsibilities of Southeastern is to design, formulate, and justify rate schedules. Repayment studies prepared by the agency determine revenue requirements and appropriate rate...

  4. Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers

    DOE Patents [OSTI]

    Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

    2001-01-01

    The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

  5. Plasma-sprayed coatings

    SciTech Connect (OSTI)

    Herman, H.

    1988-09-01

    Plasma spraying is one way to apply protective coatings. The hot, high-speed flame of a plasma gun can melt a powder of almost any ceramic or metal and spray it to form a coating for protection against corrosion, wear or high temperature. The technique carries much less risk of degrading the coating and substrate than many other high-temperature processes do, because the gas in the plasma flame is chemically inert and the target can be kept fairly cool. And yet a plasma gun can be only a little more cumbersome than a paint sprayer. Investigators are applying this technique to new materials. The General Electric Company is using vacuum plasma spraying to make freestanding components: intricate aircraft engine parts formed by plasma-spraying a superalloy on a removable substrate. Other workers spray ceramic particles or fibers and metal powder simulatious wrong, stiff composite materials: the ceramic particles dispersed in a matrix of metal. The author and colleagues at the U.S. Naval Research Laboratory have fabricated a thick film of high-temperature superconductor by plasma-spraying the compound in the form of a powder. 7 figs.

  6. Customizing a VOC control technology

    SciTech Connect (OSTI)

    Enneking, J.C.

    1998-12-31

    An extremely important but very difficult element in applying an emission control device to an exhaust stream is to chose the proper technology. Once it has been determined that recovery, rather than destruction, is appropriate, there are still several process choices available. The type of process is generally dictated by the VOC concentration and total air flow rate. Adsorption is usually chosen for low concentrations and high flow rates while refrigeration is usually best for high concentrations and low flow rates. This paper describes six applications. Adsorption was applied to two of them and condensation to the other four. Solvent vapors from a tape coating operation are recovered in an activated carbon adsorption process and reused. VOC`s from soil vapor extraction operations are captured by activated carbon which is regenerated by a mobile unit. VOC`s displaced from filling tank cars at a refinery are condensed at low temperatures in a high pressure system which uses a pressure swing dryer to remove water. Two different processes were installed to prevent VOC emissions from pharmaceutical processing plants. They both use a thermal swing dryer to remove moisture and low temperature condensation to recover the solvent. With very high concentrations of solvent in an inert gas stream, indirect condensation is used to purify the nitrogen and recover the solvent for reuse. Process flow diagrams and operating results are presented.

  7. Coating and curing apparatus and methods

    DOE Patents [OSTI]

    Brophy, Brenor L; Maghsoodi, Sina; Neyman, Patrick J; Gonsalves, Peter R; Hirsch, Jeffrey G; Yang, Yu S

    2015-02-24

    Disclosed are coating apparatus including flow coating and roll-coating that may be used for uniform sol-gel coating of substrates such as glass, solar panels, windows or part of an electronic display. Also disclosed are methods for substrate preparation, flow coating and roll coating. Lastly systems and methods for skin curing sol-gel coatings deposited onto the surface of glass substrates using a high temperature air-knife are disclosed.

  8. Dense protective coatings, methods for their preparation and coated articles

    DOE Patents [OSTI]

    Tulyani, Sonia; Bhatia, Tania; Smeggil, John G.

    2015-12-29

    A method for depositing a protective coating on a complex shaped substrate includes the steps of: (1) dipping a complex shaped substrate into a slurry to form a base coat thereon, the slurry comprising an aqueous solution, at least one refractory metal oxide, and at least one transient fluid additive present in an amount of about 0.1 percent to 10 percent by weight of the slurry; (2) curing the dipped substrate; (3) dipping the substrate into a precursor solution to form a top barrier coat thereon; and (4) heat treating the dipped, cured substrate to form a protective coating.

  9. Limits of survivability and damage for optical components used in a high repetition rate visible laser

    SciTech Connect (OSTI)

    Taylor, J.R.; Stolz, C.J.; Sarginson, T.G.

    1991-10-01

    An effort is being made to understand the limits of survivability and damage for optical components exposed to a visible laser operating continuously at a high repetition rate over 4 kHz. Results of this work are reported and related to the materials and manufacturing conditions for coatings and substrates as well as defects seen at the surface under laser illumination. These results were obtained for a variety of optical coatings and conditions using lasers from the Laser Demonstration Facility, part of the Atomic Vapor Laser Isotope Separation (AVLIS) Program at LLNL. Better understanding of the reliability of optical components in this environment could lead to improvements in design and manufacture that would result in reduced size for the laser optical system and correspondingly lower costs for the facilities that can use this technology.

  10. Full Scale Coated Fiber Neutron Detector Measurements

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Ely, James H.; Erikson, Luke E.; Kernan, Warnick J.; Stromswold, David C.; Woodring, Mitchell L.

    2010-03-17

    Radiation portal monitors used for interdiction of illicit materials at borders include highly sensitive neutron detection systems. The main reason for having neutron detection capability is to detect fission neutrons from plutonium. The currently deployed radiation portal monitors (RPMs) from Ludlum and Science Applications International Corporation (SAIC) use neutron detectors based upon 3He-filled gas proportional counters, which are the most common large neutron detector. There is a declining supply of 3He in the world, and thus, methods to reduce the use of this gas in RPMs with minimal changes to the current system designs and sensitivity to cargo-borne neutrons are being investigated. Four technologies have been identified as being currently commercially available, potential alternative neutron detectors to replace the use of 3He in RPMs. These technologies are: 1) Boron trifluoride (BF3)-filled proportional counters, 2) Boron-lined proportional counters, 3) Lithium-loaded glass fibers, and 4) Coated non-scintillating plastic fibers. Reported here are the results of tests of the full-scale 6Li/ZnS(Ag)-coated non-scintillating plastic fibers option. This testing measured the required performance for neutron detection efficiency and gamma ray rejection capabilities of a system manufactured by Innovative American Technology (IAT) and Saint Gobain, and is a follow-up report to an earlier one on a smaller prototype system.

  11. Hard, infrared black coating with very low outgassing

    SciTech Connect (OSTI)

    Kuzmenko, P J; Behne, D M; Casserly, T; Boardman, W; Upadhyaya, D; Boinapally, K; Gupta, M; Cao, Y

    2008-06-02

    Infrared astronomical instruments require absorptive coatings on internal surfaces to trap scattered and stray photons. This is typically accomplished with any one of a number of black paints. Although inexpensive and simple to apply, paint has several disadvantages. Painted surfaces can be fragile, prone to shedding particles, and difficult to clean. Most importantly, the vacuum performance is poor. Recently a plasma enhanced chemical vapor deposition (PECVD) process was developed to apply thick (30 {micro}m) diamond-like carbon (DLC) based protective coatings to the interior of oil pipelines. These DLC coatings show much promise as an infrared black for an ultra high vacuum environment. The coatings are very robust with excellent cryogenic adhesion. Their total infrared reflectivity of < 10% at normal incidence approaches that of black paints. We measured outgas rates of <10{sup -12} Torr liter/sec cm{sup 2}, comparable to bare stainless steel.

  12. Graphitized Conductive Carbon Coatings for Composite Electrodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Graphitized Conductive Carbon Coatings for Composite Electrodes Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryRobert Kostecki and Marek Marcinek of Lawrence Berkeley National Laboratory have developed a method to improve the performance and operational life of composite electrodes by direct deposition of a continuous,

  13. ZrN coatings deposited by high power impulse magnetron sputtering and cathodic arc techniques

    SciTech Connect (OSTI)

    Purandare, Yashodhan Ehiasarian, Arutiun; Hovsepian, Papken; Santana, Antonio

    2014-05-15

    Zirconium nitride (ZrN) coatings were deposited on 1??m finish high speed steel and 316L stainless steel test coupons. Cathodic Arc (CA) and High Power Impulse Magnetron Sputtering (HIPIMS) + Unbalanced Magnetron Sputtering (UBM) techniques were utilized to deposit coatings. CA plasmas are known to be rich in metal and gas ions of the depositing species as well as macroparticles (droplets) emitted from the arc sports. Combining HIPIMS technique with UBM in the same deposition process facilitated increased ion bombardment on the depositing species during coating growth maintaining high deposition rate. Prior to coating deposition, substrates were pretreated with Zr{sup +} rich plasma, for both arc deposited and HIPIMS deposited coatings, which led to a very high scratch adhesion value (L{sub C2}) of 100 N. Characterization results revealed the overall thickness of the coatings in the range of 2.5??m with hardness in the range of 3040?GPa depending on the deposition technique. Cross-sectional transmission electron microscopy and tribological experiments such as dry sliding wear tests and corrosion studies have been utilized to study the effects of ion bombardment on the structure and properties of these coatings. In all the cases, HIPIMS assisted UBM deposited coating fared equal or better than the arc deposited coatings, the reasons being discussed in this paper. Thus H+U coatings provide a good alternative to arc deposited where smooth, dense coatings are required and macrodroplets cannot be tolerated.

  14. Ceramic electrolyte coating and methods

    DOE Patents [OSTI]

    Seabaugh, Matthew M. (Columbus, OH); Swartz, Scott L. (Columbus, OH); Dawson, William J. (Dublin, OH); McCormick, Buddy E. (Dublin, OH)

    2007-08-28

    Aqueous coating slurries useful in depositing a dense coating of a ceramic electrolyte material (e.g., yttrium-stabilized zirconia) onto a porous substrate of a ceramic electrode material (e.g., lanthanum strontium manganite or nickel/zirconia) and processes for preparing an aqueous suspension of a ceramic electrolyte material and an aqueous spray coating slurry including a ceramic electrolyte material. The invention also includes processes for depositing an aqueous spray coating slurry including a ceramic electrolyte material onto pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.

  15. Development of Corrosion Inhibiting E-Coat System for Body-in-White

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assemblies | Department of Energy Corrosion Inhibiting E-Coat System for Body-in-White Assemblies Development of Corrosion Inhibiting E-Coat System for Body-in-White Assemblies 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon lm053_wang_2012_o.pdf More Documents & Publications 2011 Annual Progress Report for Lightweighting Materials Vehicle Technologies Office Merit Review 2015: Upset Protrusion Joining

  16. Carbonaceous film coating

    DOE Patents [OSTI]

    Maya, Leon

    1989-01-01

    A method of making a carbonaceous film comprising heating tris(1,3,2-benzodiazaborolo)borazine or dodecahydro tris[1,3,2]diazaborine[1,2-a:1'2'-c:1"2"-e]borazine in an inert atmosphere in the presence of a substrate to a temperature at which the borazine compound decomposes, and the decomposition products deposit onto the substrate to form a thin, tenacious, highly reflective conductive coating having a narrow band gap which is susceptible of modification and a relatively low coefficient of friction.

  17. Carbonaceous film coating

    DOE Patents [OSTI]

    Maya, L.

    1988-04-27

    A method of making a carbonaceous film comprising heating tris(1,3,2-benzodiazaborolo)borazine or dodecahydro tris(1,3,2)diazaborine(1,2-a:1'2'-c:1''2''-e)borazine in an inert atmosphere in the presence of a substrate to a temperature at which the borazine compound decomposes, and the decomposition products deposit onto the substrate to form a thin, tenacious, highly reflective conductive coating having a narrow band gap which is susceptible of modification and a relatively low coefficient of friction.

  18. Advanced thermal barrier coatings for operation in high hydrogen content fueled gas turbines.

    SciTech Connect (OSTI)

    Sampath, Sanjay

    2015-04-02

    The Center for Thermal Spray Research (CTSR) at Stony Brook University in partnership with its industrial Consortium for Thermal Spray Technology is investigating science and technology related to advanced metallic alloy bond coats and ceramic thermal barrier coatings for applications in the hot section of gasified coal-based high hydrogen turbine power systems. In conjunction with our OEM partners (GE and Siemens) and through strategic partnership with Oak Ridge National Laboratory (ORNL) (materials degradation group and high temperature materials laboratory), a systems approach, considering all components of the TBC (multilayer ceramic top coat, metallic bond coat & superalloy substrate) is being taken during multi-layered coating design, process development and subsequent environmental testing. Recent advances in process science and advanced in situ thermal spray coating property measurement enabled within CTSR has been incorporated for full-field enhancement of coating and process reliability. The development of bond coat processing during this program explored various aspects of processing and microstructure and linked them to performance. The determination of the bond coat material was carried out during the initial stages of the program. Based on tests conducted both at Stony Brook University as well as those carried out at ORNL it was determined that the NiCoCrAlYHfSi (Amdry) bond coats had considerable benefits over NiCoCrAlY bond coats. Since the studies were also conducted at different cycling frequencies, thereby addressing an associated need for performance under different loading conditions, the Amdry bond coat was selected as the material of choice going forward in the program. With initial investigations focused on the fabrication of HVOF bond coats and the performance of TBC under furnace cycle tests , several processing strategies were developed. Two-layered HVOF bond coats were developed to render optimal balance of density and surface roughness and resulted in improved TBC lifetimes. Processing based approaches of identifying optimal processing regimes deploying advanced in-situ coating property measurements and in-flight diagnostic tools were used to develop process maps for bond coats. Having established a framework for the bond coat processing using the HVOF process, effort were channeled towards fabrication of APS and VPS bond coats with the same material composition. Comparative evaluation of the three deposition processes with regard to their microstrcuture , surface profiles and TBC performance were carried out and provided valuable insights into factors that require concurrent consideration for the development of bond coats for advanced TBC systems. Over the course of this program several advancements were made on the development of durable thermal barrier coatings. Process optimization techniques were utilized to identify processing regimes for both conventional YSZ as well as other TBC compositions such as Gadolinium Zirconate and other Co-doped materials. Measurement of critical properties for these formed the initial stages of the program to identify potential challenges in their implementation as part of a TBC system. High temperature thermal conductivity measurements as well as sintering behavior of both YSZ and GDZ coatings were evaluated as part of initial efforts to undersand the influence of processing on coating properties. By effectively linking fundamental coating properties of fracture toughness and elastic modulus to the cyclic performance of coatings, a durability strategy for APS YSZ coatings was developed. In order to meet the goals of fabricating a multimaterial TBC system further research was carried out on the development of a gradient thermal conductivity model and the evaluation of sintering behavior of multimaterial coatings. Layer optimization for desired properties in the multimaterial TBC was achieved by an iterative feedback approach utilizing process maps and in-situ and ex-situ coating property sensors. Addressing the challenges pertaining to the integration of th

  19. DEVELOPMENT AND ASSESSMENT OF COATINGS FOR FUTURE POWER GENERATION TURBINES

    SciTech Connect (OSTI)

    Alvin, Maryanne; Klotz, K.; McMordie, B.; Gleeson, B.; Zhu, D.; Warnes, B.; Kang, B.; Tannenbaum, J.

    2012-01-01

    The NETL-Regional University Alliance (RUA) continues to advance technology development critical to turbine manufacturer efforts for achieving DOE Fossil Energy (FE's) Advanced Turbine Program Goals. In conjunction with NETL, Coatings for Industry (CFI), the University of Pittsburgh, NASA GRC, and Corrosion Control Inc., efforts have been focused on development of composite thermal barrier coating (TBC) architectures that consist of an extreme temperature coating, a commercially applied 7-8 YSZ TBC, a reduced cost bond coat, and a diffusion barrier coating that are applied to nickel-based superalloys or single crystal airfoil substrate materials for use at temperatures >1450 C (> 2640 F). Additionally, construction of a unique, high temperature ({approx}1100 C; {approx}2010 F), bench-scale, micro-indentation, nondestructive (NDE) test facility at West Virginia University (WVU) was completed to experimentally address in-situ changes in TBC stiffness during extended cyclic oxidation exposure of coated single crystal coupons in air or steam containing environments. The efforts and technical accomplishments in these areas are presented in the following sections of this paper.

  20. XeroCoat Inc | Open Energy Information

    Open Energy Info (EERE)

    Name: XeroCoat Inc Place: California Product: US manufacturer of anti-reflective coatings for PV systems. References: XeroCoat Inc1 This article is a stub. You can help...

  1. Coating Active Materials for Applications in Electrochemical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon precursor on the electro-active material to form a carbon-coated electro-active material Process reduces manufacturing cost Coating process produces carbon-coated metal...

  2. Thin film ion conducting coating

    DOE Patents [OSTI]

    Goldner, Ronald B. (Lexington, MA); Haas, Terry (Sudbury, MA); Wong, Kwok-Keung (Watertown, MA); Seward, George (Arlington, MA)

    1989-01-01

    Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

  3. SH Coatings LP | Department of Energy

    Energy Savers [EERE]

    SH Coatings LP America's Next Top Energy Innovator Challenge 10147 likes SH Coatings LP Oak Ridge National Laboratory SH Coating protects power lines from inclement weather as well as contamination from salt deposits that often cause flashovers in coastal environments. The coating can be applied to existing power lines and equipment in any field condition. The most important application is coating power lines in ice storm threatened areas. Power lines coated with SHC prevent the ice build-up

  4. Protective coatings for sensitive materials

    DOE Patents [OSTI]

    Egert, C.M.

    1997-08-05

    An enhanced protective coating is disclosed to prevent interaction between constituents of the environment and devices that can be damaged by those constituents. This coating is provided by applying a synergistic combination of diffusion barrier and physical barrier materials. These materials can be, for example, in the form of a plurality of layers of a diffusion barrier and a physical barrier, with these barrier layers being alternated. Further protection in certain instances is provided by including at least one layer of a getter material to actually react with one or more of the deleterious constituents. The coating is illustrated by using alternating layers of an organic coating (such as Parylene-C{trademark}) as the diffusion barrier, and a metal coating (such as aluminum) as the physical barrier. For best results there needs to be more than one of at least one of the constituent layers. 4 figs.

  5. Coatings on reflective mask substrates

    DOE Patents [OSTI]

    Tong, William Man-Wai (Oakland, CA); Taylor, John S. (Livermore, CA); Hector, Scott D. (Oakland, CA); Mangat, Pawitter J. S. (Gilbert, AZ); Stivers, Alan R. (San Jose, CA); Kofron, Patrick G. (San Jose, CA); Thompson, Matthew A. (Austin, TX)

    2002-01-01

    A process for creating a mask substrate involving depositing: 1) a coating on one or both sides of a low thermal expansion material EUVL mask substrate to improve defect inspection, surface finishing, and defect levels; and 2) a high dielectric coating, on the backside to facilitate electrostatic chucking and to correct for any bowing caused by the stress imbalance imparted by either other deposited coatings or the multilayer coating of the mask substrate. An film, such as TaSi, may be deposited on the front side and/or back of the low thermal expansion material before the material coating to balance the stress. The low thermal expansion material with a silicon overlayer and a silicon and/or other conductive underlayer enables improved defect inspection and stress balancing.

  6. Protective coatings for sensitive materials

    DOE Patents [OSTI]

    Egert, Charles M. (Oak Ridge, TN)

    1997-01-01

    An enhanced protective coating to prevent interaction between constituents of the environment and devices that can be damaged by those constituents. This coating is provided by applying a synergistic combination of diffusion barrier and physical barrier materials. These materials can be, for example, in the form of a plurality of layers of a diffusion barrier and a physical barrier, with these barrier layers being alternated. Further protection in certain instances is provided by including at least one layer of a getter material to actually react with one or more of the deleterious constituents. The coating is illustrated by using alternating layers of an organic coating (such as Parylene-C.TM.) as the diffusion barrier, and a metal coating (such as aluminum) as the physical barrier. For best results there needs to be more than one of at least one of the constituent layers.

  7. Obtaining composite Zr-Al-O coating on the surface of zirconium by microplasma oxidation

    SciTech Connect (OSTI)

    Gubaidulina, Tatiana A. E-mail: ostk@mail2000ru; Kuzmin, Oleg S. E-mail: ostk@mail2000ru; Fedorischva, Marina V. E-mail: kmp1980@mail.ru; Kalashnikov, Mark P. E-mail: kmp1980@mail.ru; Sergeev, Viktor P.

    2014-11-14

    The paper describes the application of the microplasma oxidation for production of Zr-Al-O composition on the surface of zirconium. Certification of a new-type power supply for depositing oxide ceramic coatings by microplasma oxidation was also carried out. The growth rate of Zr-Al-O coating amounted around 0.2 nm/s, which around 10 times exceeds that for depositing similar coatings using the similar equipment. We have studied the change of surface morphology and the chemical composition of the formed ceramic coating by means of EVO 50 scanning electron microscope and X-ray spectral analysis.

  8. Pentek metal coating removal system: Baseline report; Greenbook (chapter)

    SciTech Connect (OSTI)

    1997-07-31

    The Pentek coating removal technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The Pentek coating removal system consisted of the ROTO-PEEN Scaler, CORNER-CUTTER{reg_sign}, and VAC-PAC{reg_sign}. They are designed to remove coatings from steel, concrete, brick, and wood. The Scaler uses 3M Roto Peen tungsten carbide cutters while the CORNER-CUTTER{reg_sign} uses solid needles for descaling activities. These hand tools are used with the VAC-PAC{reg_sign} vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure minimal, but noise exposure was significant. Further testing for each exposure is recommended because of the environment where the testing demonstration took place. It is feasible that the dust and noise levels will be higher in an enclosed operating environment of different construction. In addition, other areas of concern found were arm-hand vibration, whole-body, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

  9. Superhydrophobic Thin Film Coatings - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optical devices subject to the elements (e.g., windshields, windows) Eye glasses, sports goggles, camera lenses Durable, water repellant coatings Self-cleaning coatings More...

  10. Reduced AC losses in HTS coated conductors

    DOE Patents [OSTI]

    Ashworth, Stephen P.

    2004-10-05

    Methods for reducing hysteresis losses in superconductor coated ribbons where a flux distribution is set into the superconductor coated ribbon prior to the application of alternating current.

  11. North American Coating Laboratories | Open Energy Information

    Open Energy Info (EERE)

    Coating Laboratories Jump to: navigation, search Name: North American Coating Laboratories Address: 9450 Pineneedle Drive Place: Mentor, Ohio Zip: 44060 Sector: Services, Solar...

  12. Coated Conductors Cylinder Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ltd Jump to: navigation, search Name: Coated Conductors Cylinder Ltd. Place: Malvern, England, United Kingdom Zip: WR14 3SZ Product: Coated Conductors Consultancy Ltd. (3-Cs)...

  13. Precise Application of Transparent Conductive Oxide Coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (TCO) coatings are deposited using atomic layer deposition (ALD). Provides uniform coating of complex, 3D nanostructures such as electrodes for next-generation PV cells...

  14. Chromium Vaporization Reduction by Nickel Coatings For SOEC Interconnect Materials

    SciTech Connect (OSTI)

    Michael V. Glazoff; Sergey N. Rashkeev; J. Stephen Herring

    2014-09-01

    The vaporization of Cr-rich volatile species from interconnect materials is a major source of degradation that limits the lifetime of planar solid oxide devices systems with metallic interconnects, including Solid Oxide Electrolysis Cells, or SOECs. Some metallic coatings (Ni, Co, and Cu) significantly reduce the Cr release from interconnects and slow down the oxide scale growth on the steel substrate. To shed additional light upon the mechanisms of such protection and find a suitable coating material for ferritic stainless steel materials, we used a combination of first-principles calculations, thermodynamics, and diffusion modeling to investigate which factors determine the quality of the Ni metallic coating at stainless steel interconnector. We found that the Cr migration in Ni coating is determined by a delicate combination of the nickel oxidation, Cr diffusion, and phase transformation processes. Although the formation of Cr2O3 oxide is more exothermic than that of NiO, the kinetic rate of the chromia formation in the coating layer and its surface is significantly reduced by the low mobility of Cr in nickel oxide and in NiCr2O4 spinel. These results are in a good agreement with diffusion modeling for Cr diffusion through Ni coating layer on the ferritic 441 steel substrate.

  15. Finance & Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    all of its costs in the rates it charges customers for wholesale electricity and transmission services. The agency is committed to careful cost management consistent with its...

  16. Decision Analysis Science Modeling for Application and Fielding Selection Applied to Concrete Decontamination Technologies

    SciTech Connect (OSTI)

    Ebadian, M.A. Ross, T.L.

    1998-01-01

    Concrete surfaces contaminated with radionuclides present a significant challenge during the decontamination and decommissioning (D and D) process. As structures undergo D and D, coating layers and/or surface layers of the concrete containing the contaminants must be removed for disposal in such a way as to present little to no risk to human health or the environment. The selection of a concrete decontamination technology that is safe, efficient, and cost-effective is critical to the successful D and D of contaminated sites. To support U.S. Department of Energy (DOE) Environmental Management objectives and to assist DOE site managers in the selection of the best-suited concrete floor decontamination technology(s) for a given site, two innovative and three baseline technologies have been assessed under standard, non-nuclear conditions at the Hemispheric Center for Environmental Technology (HCET) at Florida International University (FIU). The innovative technologies assessed include the Pegasus Coating Removal System and Textron's Electro-Hydraulic Scabbling System. The three baseline technologies assessed include: the Wheelabrator Blastrac model 1-15D, the NELCO Porta Shot Blast{trademark} model GPx-1O-18 HO Rider, and the NELCO Porta Shot Blast{trademark} model EC-7-2. These decontamination technology assessments provide directly comparable performance data that have previously been available for only a limited number of technologies under restrictive site-specific constraints. Some of the performance data collected during these technology assessments include: removal capability, production rate, removal gap, primary and secondary waste volumes, and operation and maintenance requirements. The performance data generated by this project is intended to assist DOE site managers in the selection of the safest, most efficient, and cost-effective decontamination technologies to accomplish their remediation objectives.

  17. Synthesis and mechanical properties of CrMoC{sub x}N{sub 1-x} coatings deposited by a hybrid coating system

    SciTech Connect (OSTI)

    Yun, Ji Hwan; Heo, Su Jeong; Kim, Kwang Ryul; Kim, Kwang Ho

    2008-01-15

    Quaternary CrMoC{sub x}N{sub 1-x} coatings were deposited on steel substrates (AISI D2) and Si wafers by a hybrid coating system combining an arc-ion plating technique and a dc reactive magnetron sputtering technique using Cr and Mo targets in an Ar/N{sub 2}/CH{sub 4} gaseous mixture. The carbon content of CrMoC{sub x}N{sub 1-x} coatings was linearly increased with increasing CH{sub 4}/(CH{sub 4}+N{sub 2}) gas flow rate ratio. The maximum hardness of 44 GPa was obtained from the CrMoC{sub x}N{sub 1-x} coatings containing a carbon content of x=0.33 with a residual stress of -4.4 GPa. The average friction coefficient of Cr-Mo-N coatings was 0.42, and it is decreased to 0.31 after applying CrMoC{sub x}N{sub 1-x} coatings. This result was caused by the formation of a carbon-rich transfer layer that acted as a solid lubricant to reduce contact between the coating surface and steel ball. The microstructure of the coatings was investigated by x-ray diffraction, scanning electron microscopy, and x-ray photoelectron spectroscopy. In this work, the microstructure and mechanical properties of the CrMoC{sub x}N{sub 1-x} coatings were systematically investigated with the instrumental analyses.

  18. Ceramic composite coating

    DOE Patents [OSTI]

    Wicks, George G. (Aiken, SC)

    1997-01-01

    A thin, room-temperature-curing, ceramic composite for coating and patching etal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

  19. Ceramic composite coating

    DOE Patents [OSTI]

    Wicks, G.G.

    1997-01-21

    A thin, room-temperature-curing, ceramic composite for coating and patching metal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

  20. Metasurface optical antireflection coating

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Boyang; Hendrickson, Joshua; Nader, Nima; Chen, Hou -Tong; Guo, Junpeng

    2014-12-15

    Light reflection at the boundary of two different media is one of the fundamental phenomena in optics, and reduction of reflection is highly desirable in many optical systems. Traditionally, optical antireflection has been accomplished using single- or multiple-layer dielectric films and graded index surface structures in various wavelength ranges. However, these approaches either impose strict requirements on the refractive index matching and film thickness, or involve complicated fabrication processes and non-planar surfaces that are challenging for device integration. Here, we demonstrate an antireflection coating strategy, both experimentally and numerically, by using metasurfaces with designer optical properties in the mid-wave infrared.more » Our results show that the metasurface antireflection is capable of eliminating reflection and enhancing transmission over a broad spectral band and a wide incidence angle range. The demonstrated antireflection technique has no requirement on the choice of materials and is scalable to other wavelengths.« less

  1. Coated substrates and process

    DOE Patents [OSTI]

    Chu, Wei-kan; Childs, Charles B.

    1991-01-01

    Disclosed herein is a coated substrate and a process for forming films on substrates and for providing a particularly smooth film on a substrate. The method of this invention involves subjecting a surface of a substrate to contact with a stream of ions of an inert gas having sufficient force and energy to substantially change the surface characteristics of said substrate, and then exposing a film-forming material to a stream of ions of an inert gas having sufficient energy to vaporize the atoms of said film-forming material and to transmit the vaporized atoms to the substrate surface with sufficient force to form a film bonded to the substrate. This process is particularly useful commercially because it forms strong bonds at room temperature. This invention is particularly useful for adhering a gold film to diamond and forming ohmic electrodes on diamond, but also can be used to bond other films to substrates.

  2. California: Heliotrope Technologies Wins R&D 100 Award for Universal Smart

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Window Coating that Saves Energy and Increases Comfort | Department of Energy Heliotrope Technologies Wins R&D 100 Award for Universal Smart Window Coating that Saves Energy and Increases Comfort California: Heliotrope Technologies Wins R&D 100 Award for Universal Smart Window Coating that Saves Energy and Increases Comfort August 16, 2013 - 10:31am Addthis EERE-funded Heliotrope Technologies, with support from EERE's Lawrence Berkeley National Laboratory (LBNL), received a 2013

  3. Etching of Copper Coated Mylar Tubes With CF-4 Gas

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ecklund, Karl M.; Hartman, Keith W.; Hebert, Michael J.; Wojcicki, Stanley G.

    1996-04-01

    Using 5 mm diameter copper coated mylar straw tubes at a potential of 2.30 KV relative to a concentric 20 (mu)m diameter gold-plated tungsten anode, it has been observed that with very low flow rates of CF4-based gases the conductive copper cathode material may be removed entirely from the mylar surface.

  4. Sacrificial Protective Coating Materials That Can Be Regenerated In-Situ to Enable High-Performance Membranes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Protective Coating Materials ADVANCED MANUFACTURING OFFICE Protective Coating Materials Sacrificial Protective Coating Materials That Can Be Regenerated In- Situ to Enable High-Performance Membranes Membrane Technology Provides Energy-Efficient Method to Concentrate Weak Black Liquor. Among the various manufacturing processes employed across all U.S. industries, the process of concentrating weak black liquor (WBL) in the pulp and paper industry is identifed as one of the largest energy reduction

  5. California: Heliotrope Technologies Wins R&D 100 Award for Universal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    competing smart window technologies, the USW Coating can block heat-producing, near-infrared solar radiation without blocking visible light. This independent control is unique in...

  6. Radiation shielding properties of barite coated fabric by computer programme

    SciTech Connect (OSTI)

    Akarslan, F.; Molla, T.; nc, I. S.; K?l?ncarslan, S.; Akkurt, I.

    2015-03-30

    With the development of technology radiation started to be used in variety of different fields. As the radiation is hazardous for human health, it is important to keep radiation dose as low as possible. This is done mainly using shielding materials. Barite is one of the important materials in this purpose. As the barite is not used directly it can be used in some other materials such as fabric. For this purposes barite has been coated on fabric in order to improve radiation shielding properties of fabric. Determination of radiation shielding properties of coated fabric has been done by using computer program written C# language. With this program the images obtained from digital Rontgen films is used to determine radiation shielding properties in terms of image processing numerical values. Those values define radiation shielding and in this way the coated barite effect on radiation shielding properties of fabric has been obtained.

  7. Surface-Coating Regulated Lithiation Kinetics and Degradation in Silicon Nanowires for Lithium Ion Battery

    SciTech Connect (OSTI)

    Luo, Langli; Yang, Hui; Yan, Pengfei; Travis, Jonathan J.; Lee, Younghee; Liu, Nian; Piper, Daniela M.; Lee, Se-Hee; Zhao, Peng; George, Steven M.; Zhang, Jiguang; Cui, Yi; Zhang, Sulin; Ban, Chunmei; Wang, Chong M.

    2015-05-26

    Silicon (Si)-based materials hold promise as the next-generation anodes for high-energy lithium (Li)-ion batteries. Enormous research efforts have been undertaken to mitigate the chemo-mechanical failure due to the large volume changes of Si during lithiation and delithiation cycles. It has been found nanostructured Si coated with carbon or other functional materials can lead to significantly improved cyclability. However, the underlying mechanism and comparative performance of different coatings remain poorly understood. Herein, using in situ transmission electron microscopy (TEM) through a nanoscale half-cell battery, in combination with chemo-mechanical simulation, we explored the effect of thin (~5 nm) alucone and Al2O3 coatings on the lithiation kinetics of Si nanowires (SiNWs). We observed that the alucone coating leads to a V-shaped lithiation front of the SiNWs , while the Al2O3 coating yields an H-shaped lithiation front. These observations indicate that the difference between the Li surface diffusivity and bulk diffusivity of the coatings dictates lithiation induced morphological evolution in the nanowires. Our experiments also indicate that the reaction rate in the coating layer can be the limiting step for lithiation and therefore critically influences the rate performance of the battery. Further, the failure mechanism of the Al2O3 coated SiNWs was also explored. Our studies shed light on the design of high capacity, high rate and long cycle life Li-ion batteries.

  8. MHK technology developments include current

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    technology developments include current energy conversion (CEC) devices, for example, hydrokinetic turbines that extract power from water currents (riverine, tidal, and ocean) and wave energy conversion (WEC) devices that extract power from wave motion. Sandia's MHK research leverages decades of experience in engineering, design, and analysis of wind power technologies, and its vast research complex, including high- performance computing (HPC), advanced materials and coatings, nondestructive

  9. Peripheral Applications of Drug-Coated Balloons: Past, Present and Future

    SciTech Connect (OSTI)

    Krokidis, Miltiadis Spiliopoulos, Stavros Katsanos, Konstantinos Sabharwal, Tarun

    2013-04-15

    Drug-coated balloon (DCB) technologies represent the latest and hottest development in the field of endovascular treatment of peripheral arterial disease. Initial experience with paclitaxel-coated balloon use in the femoral artery has demonstrated lower mid-term restenosis and superior mid-term clinical outcomes in terms of improved wound healing and reduced repeat angioplasty rates compared with standard balloon angioplasty. Many companies are presently developing and/or improving DCB catheters and therefore ongoing, technical improvements of the already existing platforms, new drugs, and innovative carriers are expected. The ongoing basic research studies and various multicenter randomized, controlled trials that are currently in progress will offer valuable scientific insights regarding the long-term effectiveness and other crucial issues, such as efficacy in various vascular beds, optimal balloon dosage, and post angioplasty antiplatelet therapy. Future applications of these devices also could include in-stent restenosis, anastomotic stenosis of surgical bypass, and benign stenoses of the central venous system. The authors envision that DCB angioplasty will evolve to a major paradigm shift in the endovascular treatment of occlusive vascular diseases.

  10. Method of measuring metal coating adhesion

    DOE Patents [OSTI]

    Roper, John R.

    1985-01-01

    A method for measuring metal coating adhesion to a substrate material comprising the steps of preparing a test coupon of substrate material having the metal coating applied to one surface thereof, applying a second metal coating of gold or silver to opposite surfaces of the test coupon by hot hollow cathode process, applying a coating to one end of each of two pulling rod members, joining the coated ends of the pulling rod members to said opposite coated surfaces of the test coupon by a solid state bonding technique and finally applying instrumented static tensile loading to the pulling rod members until fracture of the metal coating adhesion to the substrate material occurs.

  11. Method of measuring metal coating adhesion

    DOE Patents [OSTI]

    Roper, J.R.

    A method for measuring metal coating adhesion to a substrate material comprising the steps of preparing a test coupon of substrate material having the metal coating applied to one surface thereof, applying a second metal coating of gold or silver to opposite surfaces of the test coupon by hot hollow cathode process, applying a coating to one end of each of two pulling rod members, joining the coated ends of the pulling rod members to said opposite coated surfaces of the test coupon by a solid state bonding technique and finally applying instrumented static tensile loading to the pulling rod members until fracture of the metal coating adhesion to the substrate material occurs.

  12. Paint coatings: Controlled field and chamber experiments

    SciTech Connect (OSTI)

    Edney, E.O.

    1989-04-01

    To determine the impact of pollution levels on the weathering rates of coatings, laboratory chamber experiments and controlled field exposures at North Carolina and Ohio sites were conducted in such a manner to separate the contributions due to dry deposition, wet deposition, precipitation pH, etc. The results of these studies confirm that acidic gases such as SO/sub 2/ and HNO/sub 3/, as well as acids within rain, promote the dissolution of alkaline components including CaCO/sub 3/, ZnO, and Al flake from paint films. It is unclear from these studies whether the removal of these components reduces the service life or protective properties of the paint film. Other researchers within the Coatings Effects Program are conducting subsequent analyses to determine micro-damage of these paints. The uptake of acidic gases to painted surfaces is a complex process that depends on several factors. The deposition rate of SO/sub 2/ to a wet, painted surface may be controlled by the level of oxidants such as H/sub 2/O/sub 2/.

  13. SuperhydrophobicCoatings.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Superhydrophobic Coating 1 S S S S S S S S S Su u u u u u u u u u u u u u u u u up p p p p p p p p p p p p p p p p p pe e e e e e e e e e e e e e e e e e e e e e e e e e e er r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r rh h h h h h h h h h h h h h h h h h h h h h h h h h hy y y y y y y yd d d d d d d d d dr r r r r r ro o o op p p p ph h h h h h h ho o o o o o o o o ob b b b b bi i i ic c c c C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Co o o

  14. Effect of SOFC Interconnect-Coating Interactions on Coating Properties and Performance

    SciTech Connect (OSTI)

    Jeffrey W. Fergus

    2012-09-05

    The high operating temperature of solid oxide fuel cells (SOFCs) provides good fuel flexibility which expands potential applications, but also creates materials challenges. One such challenge is the interconnect material, which was the focus of this project. In particular, the objective of the project was to understand the interaction between the interconnect alloy and ceramic coatings which are needed to minimize chromium volatilization and the associated chromium poisoning of the SOFC cathode. This project focused on coatings based on manganese cobalt oxide spinel phases (Mn,Co)3O4, which have been shown to be effective as coatings for ferritic stainless steel alloys. Analysis of diffusion couples was used to develop a model to describe the interaction between (Mn,Co)3O4 and Cr2O3 in which a two-layer reaction zone is formed. Both layers form the spinel structure, but the concentration gradients at the interface appear like a two-phase boundary suggesting that a miscibility gap is present in the spinel solid solution. A high-chromium spinel layer forms in contact with Cr2O3 and grows by diffusion of manganese and cobalt from the coating material to the Cr2O3. The effect of coating composition, including the addition of dopants, was evaluated and indicated that the reaction rate could be decreased with additions of iron, titanium, nickel and copper. Diffusion couples using stainless steel alloys (which form a chromia scale) had some similarities and some differences as compared to those with Cr2O3. The most notable difference was that the high-chromium spinel layer did not form in the diffusion couples with stainless steel alloys. This difference can be explained using the reaction model developed in this project. In particular, the chromia scale grows at the expense of the alloy, the high-chromia layer grows at the expense of chromia scale and the high-chromia layer is consumed by diffusion of chromium into the coating material. If the last process (dissolution of high-chromium spinel phase) is faster than the second process (formation of high-chromium spinel phase), the high-chromium layer may be consumed. The other important result of this mechanism is that it could result in a constant scale thickness if the scale forms at the same rate as it is consumed. This helps to explain the unexpected observation that the area specific resistance (ASR) of a SOFC with a (Mn,Co)3O4-coated ferritic stainless steel cathode becomes constant after long exposures. The project also evaluated the possibility of reducing the chromium content in a stainless steel alloy using experimental alloys. The conclusion of this evaluation is that at least 17-18% chromium is needed for good oxidation resistance is needed even if the alloy is coated with a spinel coating. Additional details on these findings are provided in a later section of this report and in the publications listed below.

  15. Corrosion resistant neutron absorbing coatings

    DOE Patents [OSTI]

    Choi, Jor-Shan; Farmer, Joseph C; Lee, Chuck K; Walker, Jeffrey; Russell, Paige; Kirkwood, Jon; Yang, Nancy; Champagne, Victor

    2013-11-12

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

  16. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1988-05-26

    A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

  17. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

    1990-01-01

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  18. Corrosion resistant neutron absorbing coatings

    DOE Patents [OSTI]

    Choi, Jor-Shan (El Cerrito, CA); Farmer, Joseph C. (Tracy, CA); Lee, Chuck K. (Hayward, CA); Walker, Jeffrey (Gaithersburg, MD); Russell, Paige (Las Vegas, NV); Kirkwood, Jon (Saint Leonard, MD); Yang, Nancy (Lafayette, CA); Champagne, Victor (Oxford, PA)

    2012-05-29

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

  19. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1990-03-13

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  20. Energy conservation potential of surface modification technologies

    SciTech Connect (OSTI)

    Le, H.K.; Horne, D.M.; Silberglitt, R.S.

    1985-09-01

    This report assesses the energy conservation impact of surface modification technologies on the metalworking industries. The energy conservation impact of surface modification technologies on the metalworking industries is assessed by estimating their friction and wear tribological sinks and the subsequent reduction in these sinks when surface modified tools are used. Ion implantation, coatings, and laser and electron beam surface modifications are considered.

  1. SH Coatings LP | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    10147 likes SH Coatings LP Oak Ridge National Laboratory SH Coating protects power lines from inclement weather as well as contamination from salt deposits that often cause flashovers in coastal environments. The coating can be applied to existing power lines and equipment in any field condition. The most important application is coating power lines in ice storm threatened areas. Power lines coated with SHC prevent the ice build-up that come with ice storms by repelling the rain that ordinarily

  2. National Utility Rate Database: Preprint

    SciTech Connect (OSTI)

    Ong, S.; McKeel, R.

    2012-08-01

    When modeling solar energy technologies and other distributed energy systems, using high-quality expansive electricity rates is essential. The National Renewable Energy Laboratory (NREL) developed a utility rate platform for entering, storing, updating, and accessing a large collection of utility rates from around the United States. This utility rate platform lives on the Open Energy Information (OpenEI) website, OpenEI.org, allowing the data to be programmatically accessed from a web browser, using an application programming interface (API). The semantic-based utility rate platform currently has record of 1,885 utility rates and covers over 85% of the electricity consumption in the United States.

  3. Vehicle Technologies Office: Technologies

    Broader source: Energy.gov [DOE]

    To support DOE's goal to provide clean and secure energy, the Vehicle Technologies Office (VTO) invests in research and development that:

  4. Electromagnetically induced transparency in paraffin-coated vapor cells

    SciTech Connect (OSTI)

    Klein, M.; Hohensee, M.; Walsworth, R. L. [Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138 (United States); Department of Physics, Harvard University, Cambridge, Massachusetts 02138 (United States); Phillips, D. F. [Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138 (United States)

    2011-01-15

    Antirelaxation coatings in atomic vapor cells allow ground-state coherent spin states to survive many collisions with the cell walls. This reduction in the ground-state decoherence rate gives rise to ultranarrow-bandwidth features in electromagnetically induced transparency (EIT) spectra, which can form the basis of, for example, long-time scale slow and stored light, sensitive magnetometers, and precise frequency standards. Here we study, both experimentally and theoretically, how Zeeman EIT contrast and width in paraffin-coated rubidium vapor cells are determined by cell and laser-beam geometry, laser intensity, and atomic density. Using a picture of Ramsey pulse sequences, where atoms alternately spend ''bright'' and ''dark'' time intervals inside and outside the laser beam, we explain the behavior of EIT features in coated cells, highlighting their unique characteristics and potential applications.

  5. SHARED TECHNOLOGY TRANSFER PROGRAM

    SciTech Connect (OSTI)

    GRIFFIN, JOHN M. HAUT, RICHARD C.

    2008-03-07

    The program established a collaborative process with domestic industries for the purpose of sharing Navy-developed technology. Private sector businesses were educated so as to increase their awareness of the vast amount of technologies that are available, with an initial focus on technology applications that are related to the Hydrogen, Fuel Cells and Infrastructure Technologies (Hydrogen) Program of the U.S. Department of Energy. Specifically, the project worked to increase industry awareness of the vast technology resources available to them that have been developed with taxpayer funding. NAVSEA-Carderock and the Houston Advanced Research Center teamed with Nicholls State University to catalog NAVSEA-Carderock unclassified technologies, rated the level of readiness of the technologies and established a web based catalog of the technologies. In particular, the catalog contains technology descriptions, including testing summaries and overviews of related presentations.

  6. Composition, morphology and mechanical properties of sputtered TiAlN coating

    SciTech Connect (OSTI)

    Budi, Esmar; Razali, M. Mohd.; Nizam, A. R. Md.

    2014-03-24

    TiAlN coating was deposited on the tungsten carbide cutting tool by using DC magnetron sputtering system to study the influence of substrate bias and nitrogen flow rate on the composition, morphology and mechanical properties. The negatively substrate bias and nitrogen flow rate was varied from about ?79 to ?221 V and 30 sccm to 72 sccm, respectively. The coating composition and roughness were characterized by using SEM/EDX and Atomic Force Microscopy (AFM), respectively. The dynamic ultra micro hardness tester was used to measure the mechanical properties. The coating hardness increases to about 10-12 GPa with an increase of the negatively substrate bias up to ? 200 V and it tend to decrease with an increase in nitrogen flow rate up to 70 sccm. The increase of hardness follows the increase of Ti and N content and rms coating roughness.

  7. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Argonne National Laboratory Contact ANL About This Technology <p align="center"> New <em>ALD reaction chamber containing 12-in x 12-in piece of plate glass</em></p> New ALD reaction

  8. Glovebox decontamination technology comparison

    SciTech Connect (OSTI)

    Quintana, D.M.; Rodriguez, J.B.; Cournoyer, M.E.

    1999-09-26

    Reconfiguration of the CMR Building and TA-55 Plutonium Facility for mission requirements will require the disposal or recycle of 200--300 gloveboxes or open front hoods. These gloveboxes and open front hoods must be decontaminated to meet discharge limits for Low Level Waste. Gloveboxes and open front hoods at CMR have been painted. One of the deliverables on this project is to identify the best method for stripping the paint from large numbers of gloveboxes. Four methods being considered are the following: conventional paint stripping, dry ice pellets, strippable coatings, and high pressure water technology. The advantages of each technology will be discussed. Last, cost comparisons between the technologies will be presented.

  9. Sputtering process and apparatus for coating powders

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Alford, Craig S. (Tracy, CA); McKernan, Mark A. (Livermore, CA)

    2002-01-01

    A process and apparatus for coating small particles and fibers. The process involves agitation by vibrating or tumbling the particles or fibers to promote coating uniformly, removing adsorbed gases and static charges from the particles or fibers by an initial plasma cleaning, and coating the particles or fibers with one or more coatings, a first coating being an adhesion coating, and with subsequent coatings being deposited in-situ to prevent contamination at layer interfaces. The first coating is of an adhesion forming element (i.e. W, Zr, Re, Cr, Ti) of a 100-10,000 .ANG. thickness and the second coating or final coating of a multiple (0.1-10 microns) being Cu or Ag, for example for brazing processes, or other desired materials that defines the new surface related properties of the particles. An essential feature of the coating process is the capability to deposit in-situ without interruption to prevent the formation of a contaminated interface that could adversely affect the coating adhesion. The process may include screening of the material to be coated and either continuous or intermittent vibration to prevent agglomeration of the material to be coated.

  10. Project Profile: Forecasting and Influencing Technological Progress...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Influencing Technological Progress in Solar Energy Project Profile: Forecasting and ... energy technologies based on estimates of future rates of progress and adoption. ...

  11. Floating Rate Agreement | Department of Energy

    Office of Environmental Management (EM)

    & Publications Fixed Rate Agreement Federal Loan Guarantees for Projects that Manufacture Commercial Technology Renewable Energy Systems and Components: August 10, 2010...

  12. Microstructure and tribological performance of nanocomposite Ti-Si-C-N coatings deposited using hexamethyldisilazane precursor

    SciTech Connect (OSTI)

    Wei Ronghua; Rincon, Christopher; Langa, Edward; Yang Qi

    2010-09-15

    Thick nanocomposite Ti-Si-C-N coatings (20-30 {mu}m) were deposited on Ti-6Al-4V substrate by magnetron sputtering of Ti in a gas mixture of Ar, N{sub 2}, and hexamethyldisilazane (HMDSN) under various deposition conditions. Microstructure and composition of the coatings were studied using scanning electron microscopy, x-ray diffraction, and energy dispersive x-ray spectroscopy, while the mechanical and tribological properties of these coatings were studied using Rc indentation, and micro- and nanoindentations, solid particle erosion testing, and ball-on-disk wear testing. It has been observed that the Si concentration of these coatings is varied from 0% (TiN) to 15% (Ti-Si-C-N), while the structure of these coatings is similar to the nanocomposite Ti-Si-N coatings and consists of nanocrystalline B1 structured Ti(C,N) in an amorphous matrix of SiC{sub x}N{sub y} with the grain size of 5->100 nm, depending on the coating preparation process. These coatings exhibit excellent adhesion when subjected to Rc indentation tests. The microhardness of these coatings varies from 1200 to 3400 HV25, while the nanohardness varies from 10 to 26 GPa. Both the microhardness and nanohardness are slightly lower than those of similar coatings prepared using trimethylsilane. However, the erosion test using a microsand erosion tester at both 30 deg. and 90 deg. incident angles shows that these coatings have very high erosion resistance and up to a few hundred times of improvement has been observed. These coatings also exhibit very high resistance to sliding wear with a low coefficient of friction of about 0.2 in dry sliding. There are a few advantages of using the HMDSN precursor to prepare the Ti-Si-C-N coatings over conventional magnetron sputtered deposition of Ti-Si-N coatings including composition uniformity, precursor handling safety, and high deposition rate. The coatings can be applied to protect gas turbine compressor blades from solid particle erosion and steam turbine blades from liquid droplet erosion, as well as other mechanical components that experience severe abrasion. These coatings may also be used in areas where both high wear resistance and low friction are required.

  13. Evaluation of End Mill Coatings

    SciTech Connect (OSTI)

    L. J. Lazarus; R. L. Hester,

    2005-08-01

    Milling tests were run on families of High Speed Steel (HSS) end mills to determine their lives while machining 304 Stainless Steel. The end mills tested were made from M7, M42 and T15-CPM High Speed Steels. The end mills were also evaluated with no coatings as well as with Titanium Nitride (TiN) and Titanium Carbo-Nitride (TiCN) coatings to determine which combination of HSS and coating provided the highest increase in end mill life while increasing the cost of the tool the least. We found end mill made from M42 gave us the largest increase in tool life with the least increase in cost. The results of this study will be used by Cutting Tool Engineering in determining which end mill descriptions will be dropped from our tool catalog.

  14. Processing-structure-property relationships in electron beam physical vapor deposited yttria stabilized zirconia coatings

    SciTech Connect (OSTI)

    Rao, D. Srinivasa; Valleti, Krishna; Joshi, S. V.; Janardhan, G. Ranga

    2011-05-15

    The physical and mechanical properties of yttria stabilized zirconia (YSZ) coatings deposited by the electron beam physical vapor deposition technique have been investigated by varying the key process variables such as vapor incidence angle and sample rotation speed. The tetragonal zirconia coatings formed under varying process conditions employed were found to have widely different surface and cross-sectional morphologies. The porosity, phase composition, planar orientation, hardness, adhesion, and surface residual stresses in the coated specimens were comprehensively evaluated to develop a correlation with the process variables. Under transverse scratch test conditions, the YSZ coatings exhibited two different crack formation modes, depending on the magnitude of residual stress. The influence of processing conditions on the coating deposition rate, column orientation angle, and adhesion strength has been established. Key relationships between porosity, hardness, and adhesion are also presented.

  15. Zirconia-coated carbonyl-iron-particle-based magnetorheological fluid for polishing optical glasses and ceramics

    SciTech Connect (OSTI)

    Shafrir, Shai N.; Romanofsky, Henry J.; Skarlinski, Michael; Wang, Mimi; Miao, Chunlin; Salzman, Sivan; Chartier, Taylor; Mici, Joni; Lambropoulos, John C.; Shen Rui; Yang Hong; Jacobs, Stephen D.

    2009-12-10

    We report on magnetorheological finishing (MRF) spotting experiments performed on glasses and ceramics using a zirconia-coated carbonyl-iron (CI)-particle-based magnetorheological (MR) fluid. The zirconia-coated magnetic CI particles were prepared via sol-gel synthesis in kilogram quantities. The coating layer was {approx}50-100 nm thick, faceted in surface structure, and well adhered. Coated particles showed long-term stability against aqueous corrosion. ''Free'' nanocrystalline zirconia polishing abrasives were cogenerated in the coating process, resulting in an abrasive-charged powder for MRF. A viable MR fluid was prepared simply by adding water. Spot polishing tests were performed on a variety of optical glasses and ceramics over a period of nearly three weeks with no signs of MR fluid degradation or corrosion. Stable material removal rates and smooth surfaces inside spots were obtained.

  16. New Cool Roof Coatings and Affordable Cool Color Asphalt

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Cool Roof Coatings and Affordable Cool Color Asphalt Shingles Meng-Dawn Cheng Oak Ridge National Laboratory chengmd@ornl.gov; 865-241-5918 April 4, 2013 PM: Andre Desjarlais PI: Meng-Dawn Cheng, Ph.D. David Graham, Ph.D. Sue Carroll Steve Allman Dawn Klingeman Susan Pfiffner, Ph.D. (FY12) Karen Cheng (FY12) Partner: Joe Rokowski (Dow) Roof Testing Facility at ORNL Building Technologies Research and Integration Center 2 | Building Technologies Office eere.energy.gov * Building accounted for

  17. Rates Meetings and Workshops (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rate Case Workshops Other Power Rates-Related Workshops July 1, 2004 - Rates and Finances Workshop (updated June 25, 2004) (financial and rate forecasts and scenarios for FY...

  18. High-Performance Nanostructured Coating

    Broader source: Energy.gov [DOE]

    The High-Performance Nanostructured Coating fact sheet details a SunShot project led by a University of California, San Diego research team working to develop a new high-temperature spectrally selective coating for receiver surfaces. These receiver surfaces, used in concentrating solar power systems, rely on high-temperature SSCs to effectively absorb solar energy without emitting much blackbody radiation.The optical properties of the SSC directly determine the efficiency and maximum attainable temperature of solar receivers, which in turn influence the power-conversion efficiency and overall system cost.

  19. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng; Wen, Jian; Chen, Jinghua; Huang, Zhongping; Wang, Dezhi

    2006-12-12

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  20. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Wen, Jian (Newton, MA); Chen, Jinghua (Chestnut Hill, MA); Huang, Zhongping (Belmont, MA); Wang, Dezhi (Wellesley, MA)

    2008-10-28

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  1. Shenzhen Institute of Nano Materials and Technology | Open Energy...

    Open Energy Info (EERE)

    Solar Product: An institute of nano technology, which could be applied in DLC film coated solar cells (diamond solar cells). Coordinates: 22.546789, 114.112556 Show Map Loading...

  2. Coated foams, preparation, uses and articles

    DOE Patents [OSTI]

    Duchane, D.V.; Barthell, B.L.

    1982-10-21

    Hydrophobic cellular material is coated with a thin hydrophilic polymer skin which stretches tightly over the foam but which does not fill the cells of the foam, thus resulting in a polymer-coated foam structure having a smoothness which was not possible in the prior art. In particular, when the hydrophobic cellular material is a specially chosen hydrophobic polymer foam and is formed into arbitrarily chosen shapes prior to the coating with hydrophilic polymer, inertial confinement fusion (ICF) targets of arbitrary shapes can be produced by subsequently coating the shapes with metal or with any other suitable material. New articles of manufacture are produced, including improved ICF targets, improved integrated circuits, and improved solar reflectors and solar collectors. In the coating method, the cell size of the hydrophobic cellular material, the viscosity of the polymer solution used to coat, and the surface tension of the polymer solution used to coat are all very important to the coating.

  3. DEVELOPMENT OF PROTECTIVE COATINGS FOR SINGLE CRYSTAL TURBINE BLADES

    SciTech Connect (OSTI)

    Amarendra K. Rai

    2006-12-04

    Turbine blades in coal derived syngas systems are subject to oxidation and corrosion due to high steam temperature and pressure. Thermal barrier coatings (TBCs) are developed to address these problems. The emphasis is on prime-reliant design and a better coating architecture, having high temperature and corrosion resistance properties for turbine blades. In Phase I, UES Inc. proposed to develop, characterize and optimize a prime reliant TBC system, having smooth and defect-free NiCoCrAlY bond layer and a defect free oxide sublayer, using a filtered arc technology. Phase I work demonstrated the deposition of highly dense, smooth and defect free NiCoCrAlY bond coat on a single crystal CMSX-4 substrate and the deposition of alpha-alumina and yttrium aluminum garnet (YAG) sublayer on top of the bond coat. Isothermal and cyclic oxidation test and pre- and post-characterization of these layers, in Phase I work, (with and without top TBC layer of commercial EB PVD YSZ) revealed significant performance enhancement.

  4. Technology Performance Exchange

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Performance Exchange TDM - Jason Koman (BTO) TDM - Dave Catarious (FEMP) William Livingood National Renewable Energy Laboratory William.Livingood@nrel.gov 303-384-7490 April 2, 2013 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem: Perceived fiscal risk associated with the installation of unfamiliar technologies impedes adoption rates for cost-effective, energy-saving products. Impact of Project: Enable end users to quickly and confidently assess

  5. Heavy Truck Friction & Wear Reduction Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Friction & Wear Reduction Technologies Heavy Truck Friction & Wear Reduction Technologies 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon vssp_20_killian.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together? Vehicle Technologies Office Merit Review 2014: Development of High Power Density

  6. Sputter coating of microspherical substrates by levitation

    DOE Patents [OSTI]

    Lowe, Arthur T.; Hosford, Charles D.

    1981-01-01

    Microspheres are substantially uniformly coated with metals or nonmetals by simultaneously levitating them and sputter coating them at total chamber pressures less than 1 torr. A collimated hole structure 12 comprising a parallel array of upwardly projecting individual gas outlets 16 is machined out to form a dimple 11. Glass microballoons, which are particularly useful in laser fusion applications, can be substantially uniformly coated using the coating method and apparatus.

  7. Sputter coating of microspherical substrates by levitation

    DOE Patents [OSTI]

    Lowe, A.T.; Hosford, C.D.

    Microspheres are substantially uniformly coated with metals or nonmetals by simltaneously levitating them and sputter coating them at total chamber pressures less than 1 torr. A collimated hole structure comprising a parallel array of upwardly projecting individual gas outlets is machined out to form a dimple. Glass microballoons,, which are particularly useful in laser fusion applications, can be substantially uniformly coated using the coating method and apparatus.

  8. Friction- and wear-reducing coating

    DOE Patents [OSTI]

    Zhu, Dong (Farmington Hills, MI); Milner, Robert (Warren, MI); Elmoursi, Alaa AbdelAzim (Troy, MI)

    2011-10-18

    A coating includes a first layer of a ceramic alloy and a second layer disposed on the first layer and including carbon. The coating has a hardness of from 10 to 20 GPa and a coefficient of friction of less than or equal to 0.12. A method of coating a substrate includes cleaning the substrate, forming the first layer on the substrate, and depositing the second layer onto the first layer to thereby coat the substrate.

  9. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  10. Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.

    SciTech Connect (OSTI)

    Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom

    2012-01-01

    We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

  11. Adhesion strength of sputtered TiAlN-coated WC insert tool

    SciTech Connect (OSTI)

    Budi, Esmar; Razali, M. Mohd.; Nizam, A. R. Md.

    2013-09-09

    The adhesion strength of TiAlN coating that deposited by using DC magnetron sputtering on WC insert tool are studied. TiAlN coating are deposited on Tungsten Carbide (WC) insert tool by varying negatively substrate bias from 79 to 221 volt and nitrogen flow rate from 30 to 72 sccm. The adhesion strength are obtained by using Rockwell indentation test method with a Brale diamond at applied load of 60,100 and 150 kgf. The lateral diameter of indentation is plotted on three different applied loads and the adhesion strength of TiAlN coating was obtained from the curved slopes at 100 and 150 kgf. The lower curve slop indicated better adhesion strength. The results shows that the adhesion strength of sputterred TiAlN coating tend to increase as the negatively substrate bias and nitrogen flow rate are increased.

  12. Insulator coating for high temperature alloys method for producing insulator coating for high temperature alloys

    DOE Patents [OSTI]

    Park, J.H.

    1998-06-23

    A method for fabricating an electrically insulating coating on a surface is disclosed comprising coating the surface with a metal, and reacting the metal coated surface with a nonmetal so as to create a film on the metal-coated surface. Alternatively, the invention provides for a method for producing a noncorrosive, electrically insulating coating on a surface saturated with a nonmetal comprising supplying a molten fluid, dissolving a metal in the molten fluid to create a mixture, and contacting the mixture with the saturated surface. Lastly, the invention provides an electrically insulative coating comprising an underlying structural substrate coated with an oxide or nitride compound. 2 figs.

  13. Effects of volatile coatings on the morphology and optical detection of combustion-generated black carbon particles.

    SciTech Connect (OSTI)

    Bambha, Ray P.; Dansson, Mark Alex; Schrader, Paul E.; Michelsen, Hope A.

    2013-09-01

    We have measured time-resolved laser-induced incandescence (LII) from combustion-generated mature soot extracted from a burner and (1) coated with oleic acid or (2) coated with oleic acid and then thermally denuded using a thermodenuder. The soot samples were size selected using a differential mobility analyser and characterized with a scanning mobility particle sizer, centrifugal particle mass analyser, and transmission electron microscope. The results demonstrate a strong influence of coatings particle morphology and on the magnitude and temporal evolution of the LII signal. For coated particles higher laser fluences are required to reach LII signal levels comparable to those of uncoated particles. This effect is predominantly attributable to the additional energy needed to vaporize the coating while heating the particle. LII signals are higher and signal decay rates are significantly slower for thermally denuded particles relative to coated or uncoated particles, particularly at low and intermediate laser fluences.

  14. UNDERWATER COATINGS FOR CONTAMINATION CONTROL

    SciTech Connect (OSTI)

    Julia L. Tripp; Kip Archibald; Ann Marie Phillips; Joseph Campbell

    2004-02-01

    The Idaho National Laboratory (INL) deactivated several aging nuclear fuel storage basins. Planners for this effort were greatly concerned that radioactive contamination present on the basin walls could become airborne as the sides of the basins became exposed during deactivation and allowed to dry after water removal. One way to control this airborne contamination was to fix the contamination in place while the pool walls were still submerged. There are many underwater coatings available on the market for marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives were easily applied and adhered well to the substrates (pool wall materials) found in INL fuel pools. Lab-scale experiments were conducted by applying fourteen different commercial underwater coatings to four substrate materials representative of the storage basin construction materials, and evaluating their performance. The coupons included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The evaluation criteria included ease of application, adherence to the four surfaces of interest, no change on water clarity or chemistry, non-hazardous in final applied form and be proven in underwater applications. A proprietary two-part, underwater epoxy owned by S. G. Pinney and Associates was selected from the underwater coatings tested for application to all four pools. Divers scrubbed loose contamination off the basin walls and floors using a ship hull scrubber and vacuumed up the sludge. The divers then applied the coating using a special powered roller with two separate heated hoses that allowed the epoxy to mix at the roller surface was used to eliminate pot time concerns. The walls were successfully coated and water was removed from the pools with no detectable airborne contamination releases.

  15. Using sputter coated glass to stabilize microstrip gas chambers

    DOE Patents [OSTI]

    Gong, Wen G. (Albany, CA)

    1997-01-01

    By sputter coating a thin-layer of low-resistive, electronically-conductive glass on various substrates (including quartz and ceramics, thin-film Pestov glass), microstrip gas chambers (MSGC) of high gain stability, low leakage current, and a high rate capability can be fabricated. This design can make the choice of substrate less important, save the cost of ion-implantation, and use less glass material.

  16. Performance of "Moth Eye" Anti-Reflective Coatings for Solar Cell Applications

    SciTech Connect (OSTI)

    Clark, E.; Kane, M.; Jiang, P.

    2011-03-14

    An inexpensive, effective anti-reflective coating (ARC) has been developed at the University of Florida to significantly enhance the absorption of light by silicon in solar cells. This coating has nano-scale features, and its microstructure mimics that of various night active insects (e.g. a moth's eye). It is a square array of pillars, each about 700 nm high and having a diameter of about 300 nm. Samples of silicon having this coating were exposed either to various combinations of either elevated temperature and humidity or to gamma irradiation ({sup 60}Co) at the Savannah River National Laboratory, or to a broad spectrum ultraviolet light and to a 532 nm laser light at the University of Florida. The anti-reflective properties of the coatings were unaffected by any of these environmental stresses, and the microstructure of the coating was also unaffected. In fact, the reflectivity of the gamma irradiated ARC became lower (advantageous for solar cell applications) at wavelengths between 400 and 1000 nm. These results show that this coating is robust and should be tested in actual systems exposed to either weather or a space environment. Structural details of the ARCs were studied to optimize their performance. Square arrays performed better than hexagonal arrays - the natural moth-eye coating is indeed a square array. The optimal depth of the templated nanopillars in the ARC was investigated. A wet etching technology for ARC formation was developed that would be less expensive and much faster than dry etching. Theoretical modeling revealed that dimple arrays should perform better than nipple arrays. A method of fabricating both dimple and nipple arrays having the same length was developed, and the dimple arrays performed better than the nipple arrays, in agreement with the modeling. The commercial viability of the technology is quite feasible, since the technology is scalable and inexpensive. This technology is also compatible with current industrial fabrication of solar cells.

  17. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka

    1997-12-31

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  18. Method for making nanoporous hydrophobic coatings

    DOE Patents [OSTI]

    Fan, Hongyou

    2013-04-23

    A simple coating method is used to form nanoporous hydrophobic films that can be used as optical coatings. The method uses evaporation-induced self-assembly of materials. The coating method starts with a homogeneous solution comprising a hydrophobic polymer and a surfactant polymer in a selective solvent. The solution is coated onto a substrate. The surfactant polymer forms micelles with the hydrophobic polymer residing in the particle core when the coating is dried. The surfactant polymer can be dissolved and selectively removed from the separated phases by washing with a polar solvent to form the nanoporous hydrophobic film.

  19. PRESERVATION OF H2 PRODUCTION ACTIVITY IN NANOPOROUS LATEX COATINGS OF RHODOPSEUDOMONAS PALUSTRIS CGA009 DURING DRY STORAGE AT AMBIENT TEMPERATURES

    SciTech Connect (OSTI)

    Milliken, C.; Piskorska, M.; Soule, T.; Gosse, J.; Flickinger, M.; Smith, G.; Yeager, C.

    2012-08-27

    To assess the applicability of latex cell coatings as an "off-the-shelf' biocatalyst, the effect of osmoprotectants, temperature, humidity and O{sub 2} on preservation of H{sub 2} production in Rhodopseudomonas palustris coatings was evaluated. Immediately following latex coating coalescence (24 h) and for up to 2 weeks of dry storage, rehydrated coatings containing different osmoprotectants displayed similar rates of H{sub 2} production. Beyond 2 weeks of storage, sorbitol- treated coatings lost all H{sub 2} production activity, whereas considerable H{sub 2} production was still detected in sucrose- and trehalose-stabilized coatings. The relative humidity level at which the coatings were stored had a significant impact on the recovery and subsequent rates of H{sub 2} production. After 4 weeks storage under air at 60% humidity, coatings produced only trace amounts of H{sub 2} (0-0.1% headspace accumulation), whereas those stored at <5% humidity retained 27-53% of their H{sub 2} production activity after 8 weeks of storage. When stored in argon at <5% humidity and room temperature, R. palustris coatings retained full H{sub 2} production activity for 3 months, implicating oxidative damage as a key factor limiting coating storage. Overall, the results demonstrate that biocatalytic latex coatings are an attractive cell immobilization platform for preservation of bioactivity in the dry state.

  20. Armor systems including coated core materials

    DOE Patents [OSTI]

    2013-10-08

    An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

  1. Armor systems including coated core materials

    DOE Patents [OSTI]

    Chu, Henry S. (Idaho Falls, ID); Lillo, Thomas M. (Idaho Falls, ID); McHugh, Kevin M. (Idaho Falls, ID)

    2012-07-31

    An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

  2. Electrical contact arrangement for a coating process

    DOE Patents [OSTI]

    Kabagambe, Benjamin; McCamy, James W; Boyd, Donald W

    2013-09-17

    A protective coating is applied to the electrically conductive surface of a reflective coating of a solar mirror by biasing a conductive member having a layer of a malleable electrically conductive material, e.g. a paste, against a portion of the conductive surface while moving an electrodepositable coating composition over the conductive surface. The moving of the electrodepositable coating composition over the conductive surface includes moving the solar mirror through a flow curtain of the electrodepositable coating composition and submerging the solar mirror in a pool of the electrodepositable coating composition. The use of the layer of a malleable electrically conductive material between the conductive member and the conductive surface compensates for irregularities in the conductive surface being contacted during the coating process thereby reducing the current density at the electrical contact area.

  3. Advanced Hot Section Materials and Coatings Test Rig

    SciTech Connect (OSTI)

    Dan Davis

    2006-09-30

    Phase I of the Hyperbaric Advanced Hot Section Materials & Coating Test Rig Program has been successfully completed. Florida Turbine Technologies has designed and planned the implementation of a laboratory rig capable of simulating the hot gas path conditions of coal gas fired industrial gas turbine engines. Potential uses of this rig include investigations into environmental attack of turbine materials and coatings exposed to syngas, erosion, and thermal-mechanical fatigue. The principle activities during Phase 1 of this project included providing several conceptual designs for the test section, evaluating various syngas-fueled rig combustor concepts, comparing the various test section concepts and then selecting a configuration for detail design. Conceptual definition and requirements of auxiliary systems and facilities were also prepared. Implementation planning also progressed, with schedules prepared and future project milestones defined. The results of these tasks continue to show rig feasibility, both technically and economically.

  4. Cathode Coating (IN-09-061) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cathode Coating (IN-09-061) Cathode Coating Enables Faster Battery Charging, Discharging Argonne National Laboratory Contact ANL About This Technology <p> <em>Charge and discharge capacity of pristine, 250&deg;C dry air and 250&deg;C He/5%H<sub>2</sub> heated Li<sub>1.12</sub>Mn<sub>0.55</sub>Ni<sub>0.145</sub>Co<sub>0.1O2</sub>, showing better performance for the material heated with reducing

  5. Oxidation Resistant, Cr Retaining, Electrically Conductive Coatings on Metallic Alloys for SOFC Interconnects

    SciTech Connect (OSTI)

    Vladimir Gorokhovsky

    2008-03-31

    This report describes significant results from an on-going, collaborative effort to enable the use of inexpensive metallic alloys as interconnects in planar solid oxide fuel cells (SOFCs) through the use of advanced coating technologies. Arcomac Surface Engineering, LLC, under the leadership of Dr. Vladimir Gorokhovsky, is investigating filtered-arc and filtered-arc plasma-assisted hybrid coating deposition technologies to promote oxidation resistance, eliminate Cr volatility, and stabilize the electrical conductivity of both standard and specialty steel alloys of interest for SOFC metallic interconnect (IC) applications. Arcomac has successfully developed technologies and processes to deposit coatings with excellent adhesion, which have demonstrated a substantial increase in high temperature oxidation resistance, stabilization of low Area Specific Resistance values and significantly decrease Cr volatility. An extensive matrix of deposition processes, coating compositions and architectures was evaluated. Technical performance of coated and uncoated sample coupons during exposures to SOFC interconnect-relevant conditions is discussed, and promising future directions are considered. Cost analyses have been prepared based on assessment of plasma processing parameters, which demonstrate the feasibility of the proposed surface engineering process for SOFC metallic IC applications.

  6. Reactor surface contamination stabilization. Innovative technology summary report

    SciTech Connect (OSTI)

    1998-11-01

    Contaminated surfaces, such as the face of a nuclear reactor, need to be stabilized (fixed) to avoid airborne contamination during decontamination and decommissioning activities, and to prepare for interim safe storage. The traditional (baseline) method of fixing the contamination has been to spray a coating on the surfaces, but ensuring complete coverage over complex shapes, such as nozzles and hoses, is difficult. The Hanford Site C Reactor Technology Demonstration Group demonstrated innovative technologies to assess stabilization properties of various coatings and to achieve complete coverage of complex surfaces on the reactor face. This demonstration was conducted in two phases: the first phase consisted of a series of laboratory assessments of various stabilization coatings on metal coupons. For the second phase, coatings that passed the laboratory tests were applied to the front face of the C Reactor and evaluated. The baseline coating (Rust-Oleum No. 769) and one of the innovative technologies did not completely cover nozzle assemblies on the reactor face, the most critical of the second-phase evaluation criteria. However, one of the innovative coating systems, consisting of a base layer of foam covered by an outer layer of a polymeric film, was successful. The baseline technology would cost approximately 33% as much as the innovative technology cost of $64,000 to stabilize an entire reactor face (196 m{sup 2} or 2116 ft{sup 2}) with 2,004 nozzle assemblies, but the baseline system failed to provide complete surface coverage.

  7. ITP Nanomanufacturing: Nanostructured Superhydrophobic Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanostructured Superhydrophobic Coatings Large-scale Implementation of Nanostructured Superhydrophobic (SH) Powders for Breakthrough Energy Savings Nanostructured superhydrophobic (SH) powders cause water to bead off of surfaces, resulting in surfaces that are non-wetting and water-repelling. Oak Ridge National Laboratory (ORNL) has developed a set of SH powders that are more water repellent and more durable than anything found in nature. Based on the extreme water repellency of uniform glass

  8. High temperature solar selective coatings

    DOE Patents [OSTI]

    Kennedy, Cheryl E

    2014-11-25

    Improved solar collectors (40) comprising glass tubing (42) attached to bellows (44) by airtight seals (56) enclose solar absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are coated with improved solar selective coatings {48} which provide higher absorbance, lower emittance and resistance to atmospheric oxidation at elevated temperatures. The coatings are multilayered structures comprising solar absorbent layers (26) applied to the meta surface of the absorber tubes (50), typically stainless steel, topped with antireflective Savers (28) comprising at least two layers 30, 32) of refractory metal or metalloid oxides (such as titania and silica) with substantially differing indices of refraction in adjacent layers. Optionally, at least one layer of a noble metal such as platinum can be included between some of the layers. The absorbent layers cars include cermet materials comprising particles of metal compounds is a matrix, which can contain oxides of refractory metals or metalloids such as silicon. Reflective layers within the coating layers can comprise refractory metal silicides and related compounds characterized by the formulas TiSi. Ti.sub.3SiC.sub.2, TiAlSi, TiAN and similar compounds for Zr and Hf. The titania can be characterized by the formulas TiO.sub.2, Ti.sub.3O.sub.5. TiOx or TiO.sub.xN.sub.1-x with x 0 to 1. The silica can be at least one of SiO.sub.2, SiO.sub.2x or SiO.sub.2xN.sub.1-x with x=0 to 1.

  9. Current BPA Power Rates (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Workshops WP-10 Rate Case WP-07 Rate Case WP-07 Supplemental Rate Case ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial...

  10. Power Rates Announcements (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WP-10 Rate Case WP-07 Rate Case WP-07 Supplemental Rate Case ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial Choices (2003-06) Power...

  11. Fuels Technologies

    Office of Environmental Management (EM)

    Fuels Technologies Program Mission To develop more energy efficient and environmentally friendly highway transportation technologies that enable America to use less petroleum. --EERE Strategic Plan, October 2002-- Kevin Stork, Team Leader Fuel Technologies & Technology Deployment Vehicle Technologies Program Energy Efficiency and Renewable Energy U.S. Department of Energy DEER 2008 August 6, 2008 Presentation Outline n Fuel Technologies Research Goals Fuels as enablers for advanced engine

  12. Pedestal substrate for coated optics

    DOE Patents [OSTI]

    Hale, Layton C.; Malsbury, Terry N.; Patterson, Steven R.

    2001-01-01

    A pedestal optical substrate that simultaneously provides high substrate dynamic stiffness, provides low surface figure sensitivity to mechanical mounting hardware inputs, and constrains surface figure changes caused by optical coatings to be primarily spherical in nature. The pedestal optical substrate includes a disk-like optic or substrate section having a top surface that is coated, a disk-like base section that provides location at which the substrate can be mounted, and a connecting cylindrical section between the base and optics or substrate sections. The connecting cylindrical section may be attached via three spaced legs or members. However, the pedestal optical substrate can be manufactured from a solid piece of material to form a monolith, thus avoiding joints between the sections, or the disk-like base can be formed separately and connected to the connecting section. By way of example, the pedestal optical substrate may be utilized in the fabrication of optics for an extreme ultraviolet (EUV) lithography imaging system, or in any optical system requiring coated optics and substrates with reduced sensitivity to mechanical mounts.

  13. Final Scientific/Technical Report "Arc Tube Coating System for Color Consistency"

    SciTech Connect (OSTI)

    Buelow, Roger; Jenson, Chris; Kazenski, Keith

    2013-03-21

    DOE has enabled the use of coating materials using low cost application methods on light sources to positively affect the output of those sources. The coatings and light source combinations have shown increased lumen output of LED fixtures (1.5%-2.0%), LED arrays (1.4%) and LED powered remote phosphor systems – Philips L-Prize lamp (0.9%). We have also demonstrated lifetime enhancements (3000 hrs vs 8000 hrs) and shifting to higher CRI (51 to 65) in metal halide high intensity discharge lamps with metal oxide coatings. The coatings on LEDs and LED products are significant as the market is moving increasingly more towards LED technology. Enhancements in LED performance are demonstrated in this work through the use of available materials and low cost application processes. EFOI used low refractive index fluoropolymers and low cost dipping processes for application of the material to surfaces related to light transmission of LEDs and LED products. Materials included Teflon AF, an amorphous fluorinated polymer and fluorinated acrylic monomers. The DOE SSL Roadmap sets goals for LED performance moving into the future. EFOI’s coating technology is a means to shift the performance curve for LEDs. This is not limited to one type of LED, but is relevant across LED technologies. The metal halide work included the use of sol-gel solutions resulting in silicon dioxide and titanium dioxide coatings on the quartz substrates of the metal halide arc tubes. The coatings were applied using low cost dipping processes.

  14. Lithium and Zinc Sulfide Coated Plastic Neutron Detector Test

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Ely, James H.

    2010-07-16

    Radiation portal monitors used for interdiction of illicit materials at borders include highly sensitive neutron detection systems. There is a declining supply of 3He in the world, and thus, methods to reduce the use of this gas in RPMs with minimal changes to the current system designs and sensitivity to cargo-borne neutrons are being investigated. Four technologies have been identified as being currently commercially available, potential alternative neutron detectors to replace the use of 3He in RPMs. In addition, a few other companies have detector technologies that might be competitive in the near term as an alternative technology. Reported here are the results of tests of 6Li/ZnS(Ag)-coated scintillator paddles. This testing measured the required performance for neutron detection efficiency and gamma ray rejection capabilities of a system manufactured by Symetrica.

  15. Ceramic Technology Project

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    The Ceramic Technology Project was developed by the USDOE Office of Transportation Systems (OTS) in Conservation and Renewable Energy. This project, part of the OTS's Materials Development Program, was developed to meet the ceramic technology requirements of the OTS's automotive technology programs. Significant accomplishments in fabricating ceramic components for the USDOE and NASA advanced heat engine programs have provided evidence that the operation of ceramic parts in high-temperature engine environments is feasible. These programs have also demonstrated that additional research is needed in materials and processing development, design methodology, and data base and life prediction before industry will have a sufficient technology base from which to produce reliable cost-effective ceramic engine components commercially. A five-year project plan was developed with extensive input from private industry. In July 1990 the original plan was updated through the estimated completion of development in 1993. The objective is to develop the industrial technology base required for reliable ceramics for application in advanced automotive heat engines. The project approach includes determining the mechanisms controlling reliability, improving processes for fabricating existing ceramics, developing new materials with increased reliability, and testing these materials in simulated engine environments to confirm reliability. Although this is a generic materials project, the focus is on the structural ceramics for advanced gas turbine and diesel engines, ceramic bearings and attachments, and ceramic coatings for thermal barrier and wear applications in these engines. To facilitate the rapid transfer of this technology to US industry, the major portion of the work is being done in the ceramic industry, with technological support from government laboratories, other industrial laboratories, and universities.

  16. Derivation of a Levelized Cost of Coating (LCOC) metric for evaluation of solar selective absorber materials

    SciTech Connect (OSTI)

    Ho, C. K.; Pacheco, J. E.

    2015-06-05

    A new metric, the Levelized Cost of Coating (LCOC), is derived in this paper to evaluate and compare alternative solar selective absorber coatings against a baseline coating (Pyromark 2500). In contrast to previous metrics that focused only on the optical performance of the coating, the LCOC includes costs, durability, and optical performance for more comprehensive comparisons among candidate materials. The LCOC is defined as the annualized marginal cost of the coating to produce a baseline annual thermal energy production. Costs include the cost of materials and labor for initial application and reapplication of the coating, as well as the cost of additional or fewer heliostats to yield the same annual thermal energy production as the baseline coating. Results show that important factors impacting the LCOC include the initial solar absorptance, thermal emittance, reapplication interval, degradation rate, reapplication cost, and downtime during reapplication. The LCOC can also be used to determine the optimal reapplication interval to minimize the levelized cost of energy production. As a result, similar methods can be applied more generally to determine the levelized cost of component for other applications and systems.

  17. Derivation of a Levelized Cost of Coating (LCOC) metric for evaluation of solar selective absorber materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ho, C. K.; Pacheco, J. E.

    2015-06-05

    A new metric, the Levelized Cost of Coating (LCOC), is derived in this paper to evaluate and compare alternative solar selective absorber coatings against a baseline coating (Pyromark 2500). In contrast to previous metrics that focused only on the optical performance of the coating, the LCOC includes costs, durability, and optical performance for more comprehensive comparisons among candidate materials. The LCOC is defined as the annualized marginal cost of the coating to produce a baseline annual thermal energy production. Costs include the cost of materials and labor for initial application and reapplication of the coating, as well as the costmore » of additional or fewer heliostats to yield the same annual thermal energy production as the baseline coating. Results show that important factors impacting the LCOC include the initial solar absorptance, thermal emittance, reapplication interval, degradation rate, reapplication cost, and downtime during reapplication. The LCOC can also be used to determine the optimal reapplication interval to minimize the levelized cost of energy production. As a result, similar methods can be applied more generally to determine the levelized cost of component for other applications and systems.« less

  18. Functioning mechanism of AlF3 coating on the Li- and Mn-rich cathode materials

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Xiao, Jie; Polzin, Bryant; Yan, Pengfei; Chen, Xilin; Wang, Chong M.; Zhang, Jiguang

    2014-11-25

    Li- and Mn-rich (LMR) material is a very promising cathode for lithium ion batteries because of their high theoretical energy density (~900 Wh kg-1) and low cost. However, their poor long-term cycling stability, voltage fade, and low rate capability are significant barriers hindered their practical applications. Surface coating, e.g. AlF3 coating, can significantly improve the capacity retention and enhance the rate capability. However, the fundamental mechanism of this improvement and the microstructural evolution related to the surface coating is still not well understood. Here, we report systematic studies of the microstructural changes of uncoated and AlF3-coated materials before and after cycling using aberration-corrected scanning/transmission electron microscopy and electron energy loss spectroscopy. The results reveal that surface coating can reduce the oxidation of electrolyte at high voltage, thus suppressing the accumulation of SEI layer on electrode particle surface. Surface coating also enhances structural stability of the surface region (especially the electrochemically transformed spinel-like phase), and protects the electrode from severe etching/corrosion by the acidic species in the electrolyte, therefore limiting the degradation of the material. Moreover, surface coating can alleviate the undesirable voltage fade by minimize layered-spinel phase transformation in the bulk region of the materials. These fundamental findings may also be widely applied to explain the functioning mechanism of other surface coatings used in a broad range of electrode materials.

  19. Exploration Technologies - Technology Needs Assessment

    SciTech Connect (OSTI)

    Greene, Amanda I.; Thorsteinsson, Hildigunnur; Reinhardt, Tim; Solomon, Samantha; James, Mallory

    2011-06-01

    This assessment is a critical component of ongoing technology roadmapping efforts, and will be used to guide the Geothermal Technology Program's research and development.

  20. NREL: Technology Transfer - Technology Partnership Agreements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ombuds. Printable Version Technology Transfer Home About Technology Transfer Technology Partnership Agreements Agreements for Commercializing Technology CRADAs Work for...

  1. High Impact Technology Catalyst: Technology Deployment Strategies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyst: Technology Deployment Strategies High Impact Technology Catalyst: Technology Deployment Strategies The Energy Department released the High Impact Technology Catalyst: ...

  2. Current Power Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  3. Current Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  4. Previous Power Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  5. Previous Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  6. Coated Metal Articles and Method of Making

    DOE Patents [OSTI]

    Boller, Ernest R.; Eubank, Lowell D.

    2004-07-06

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  7. Coated metal articles and method of making

    DOE Patents [OSTI]

    Boller, Ernest R. (Van Buren Township, IN); Eubank, Lowell D. (Wilmington, DE)

    2004-07-06

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  8. Method of identifying defective particle coatings

    DOE Patents [OSTI]

    Cohen, Mark E. (San Diego, CA); Whiting, Carlton D. (San Diego, CA)

    1986-01-01

    A method for identifying coated particles having defective coatings desig to retain therewithin a build-up of gaseous materials including: (a) Pulling a vacuum on the particles; (b) Backfilling the particles at atmospheric pressure with a liquid capable of wetting the exterior surface of the coated particles, said liquid being a compound which includes an element having an atomic number higher than the highest atomic number of any element in the composition which forms the exterior surface of the particle coating; (c) Drying the particles; and (d) Radiographing the particles. By television monitoring, examination of the radiographs is substantially enhanced.

  9. Optical coatings for laser fusion applications

    SciTech Connect (OSTI)

    Lowdermilk, W.H.; Milam, D.; Rainer, F.

    1980-04-24

    Lasers for fusion experiments use thin-film dielectric coatings for reflecting, antireflecting and polarizing surface elements. Coatings are most important to the Nd:glass laser application. The most important requirements of these coatings are accuracy of the average value of reflectance and transmission, uniformity of amplitude and phase front of the reflected or transmitted light, and laser damage threshold. Damage resistance strongly affects the laser's design and performance. The success of advanced lasers for future experiments and for reactor applications requires significant developments in damage resistant coatings for ultraviolet laser radiation.

  10. Coated woven materials and method of preparation

    DOE Patents [OSTI]

    McCreary, William J. (Los Alamos, NM); Carroll, David W. (Los Alamos, NM)

    1981-01-01

    Coating of woven materials so that not only the outer surfaces are coated has been a problem. Now, a solution to that problem is the following: Woven materials are coated with materials, for example with metals or with pyrolytic carbon, which materials are deposited in Chemical Vapor Deposition (CVD) reactions using a fluidized bed so that the porosity of the woven material is retained and so that the tiny filaments which make up the strands which are woven (including inner as well as outer filaments) are substantially uniformly coated.

  11. Metasurface optical antireflection coating (Journal Article)...

    Office of Scientific and Technical Information (OSTI)

    Search Title: Metasurface optical antireflection coating Light reflection at the boundary of two different media is one of the fundamental phenomena in optics, and...

  12. Solar Selective Absorption Coatings - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of solar selective absorber coatings that significantly improve the thermal conversion efficiency of solar units by reducing radiative energy losses from the absorbing elements. ...

  13. Gold ink coating of thermocouple sheaths

    DOE Patents [OSTI]

    Ruhl, H. Kenneth

    1992-01-01

    A method is provided for applying a gold ink coating to a thermocouple sheath which includes the steps of electropolishing and oxidizing the surface of the thermocouple sheath, then dipping the sheath into liquid gold ink, and finally heat curing the coating. The gold coating applied in this manner is highly reflective and does not degrade when used for an extended period of time in an environment having a temperature over 1000.degree. F. Depending on the application, a portion of the gold coating covering the tip of the thermocouple sheath is removed by abrasion.

  14. Boron hydride polymer coated substrates

    DOE Patents [OSTI]

    Pearson, R.K.; Bystroff, R.I.; Miller, D.E.

    1986-08-27

    A method is disclosed for coating a substrate with a uniformly smooth layer of a boron hydride polymer. The method comprises providing a reaction chamber which contains the substrate and the boron hydride plasma. A boron hydride feed stock is introduced into the chamber simultaneously with the generation of a plasma discharge within the chamber. A boron hydride plasma of ions, electrons and free radicals which is generated by the plasma discharge interacts to form a uniformly smooth boron hydride polymer which is deposited on the substrate.

  15. Boron hydride polymer coated substrates

    DOE Patents [OSTI]

    Pearson, Richard K. (Pleasanton, CA); Bystroff, Roman I. (Livermore, CA); Miller, Dale E. (Livermore, CA)

    1987-01-01

    A method is disclosed for coating a substrate with a uniformly smooth layer of a boron hydride polymer. The method comprises providing a reaction chamber which contains the substrate and the boron hydride plasma. A boron hydride feed stock is introduced into the chamber simultaneously with the generation of a plasma discharge within the chamber. A boron hydride plasma of ions, electrons and free radicals which is generated by the plasma discharge interacts to form a uniformly smooth boron hydride polymer which is deposited on the substrate.

  16. Investigation of anti-Relaxation coatings for alkali-metal vapor cells using surface science techniques

    SciTech Connect (OSTI)

    Seltzer, S. J.; Michalak, D. J.; Donaldson, M. H.; Balabas, M. V.; Barber, S. K.; Bernasek, S. L.; Bouchiat, M.-A.; Hexemer, A.; Hibberd, A. M.; Jackson Kimball, D. F.; Jaye, C.; Karaulanov, T.; Narducci, F. A.; Rangwala, S. A.; Robinson, H. G.; Shmakov, A. K.; Voronov, D. L.; Yashchuk, V. V.; Pines, A.; Budker, D.

    2010-10-11

    Many technologies based on cells containing alkali-metal atomic vapor benefit from the use of antirelaxation surface coatings in order to preserve atomic spin polarization. In particular, paraffin has been used for this purpose for several decades and has been demonstrated to allow an atom to experience up to 10?000 collisions with the walls of its container without depolarizing, but the details of its operation remain poorly understood. We apply modern surface and bulk techniques to the study of paraffin coatings in order to characterize the properties that enable the effective preservation of alkali spin polarization. These methods include Fourier transform infrared spectroscopy, differential scanning calorimetry, atomic force microscopy, near-edge x-ray absorption fine structure spectroscopy, and x-ray photoelectron spectroscopy. We also compare the light-induced atomic desorption yields of several different paraffin materials. Experimental results include the determination that crystallinity of the coating material is unnecessary, and the detection of C=C double bonds present within a particular class of effective paraffin coatings. Further study should lead to the development of more robust paraffin antirelaxation coatings, as well as the design and synthesis of new classes of coating materials.

  17. High Density Infrared (HDI) Transient Liquid Coatings for Improved Wear and Corrosion Resistance

    SciTech Connect (OSTI)

    Ronald W. Smith

    2007-07-05

    This report documents a collaborative effort between Oak Ridge National Laboratory (ORNL), Materials Resources International and an industry team of participants to develop, evaluate and understand how high density infrared heating technology could be used to improve infiltrated carbide wear coatings and/or to densify sprayed coatings. The research included HDI fusion evaluations of infiltrated carbide suspensions such (BrazeCoat S), composite suspensions with tool steel powders, thermally sprayed Ni-Cr- B-Si (self fluxing alloy) and nickel powder layers. The applied work developed practical HDI / transient liquid coating (TLC) procedures on test plates that demonstrated the ability to fuse carbide coatings for industrial applications such as agricultural blades, construction and mining vehicles. Fundamental studies helped create process models that led to improved process understanding and control. The coating of agricultural blades was demonstrated and showed the HDI process to have the ability to fuse industrial scale components. Sliding and brasive wear tests showed that high degree of wear resistance could be achieved with the addition of tool steel powders to carbide particulate composites.

  18. Final Technical Report CONDUCTIVE COATINGS FOR SOLAR CELLS USING CARBON NANOTUBES

    SciTech Connect (OSTI)

    Paul J Glatkowski; Jorma Peltola; Christopher Weeks; Mike Trottier; David Britz

    2007-09-30

    US Department of Energy (DOE) awarded a grant for Eikos Inc. to investigate the feasibility of developing and utilizing Transparent Conducting Coatings (TCCs) based on carbon nanotubes (CNT) for solar cell applications. Conventional solar cells today employ metal oxide based TCCs with both Electrical Resistivity (R) and Optical Transparency (T), commonly referred to as optoelectronic (RT) performance significantly higher than with those possible with CNT based TCCs available today. Transparent metal oxide based coatings are also inherently brittle requiring high temperature in vacuum processing and are thus expensive to manufacture. One such material is indium tin oxide (ITO). Global demand for indium has recently increased rapidly while supply has diminished causing substantial spikes in raw material cost and availability. In contrast, the raw material, carbon, needed for CNT fabrication is abundantly available. Transparent Conducting Coatings based on CNTs can overcome not only cost and availability constraints while also offering the ability to be applied by existing, low cost process technologies under ambient conditions. Processes thus can readily be designed both for rigid and flexible PV technology platforms based on mature spray or dip coatings for silicon based solar cells and continuous roll to roll coating processes for polymer solar applications.

  19. Vehicle Technologies Office - Materials Technologies

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office Materials Technologies Ed Owens Jerry Gibbs Will Joost eere.energy.gov 2 | Vehicle Technologies Program Materials Technologies Materials Technologies $36.9 M Lightweight Materials $28.0 M Values are FY14 enacted Propulsion Materials $8.9 M Properties and Manufacturing Multi-Material Enabling Modeling & Computational Mat. Sci. Engine Materials, Cast Al & Fe High Temp Alloys Exhaust Sys. Materials, Low T Catalysts Lightweight Propulsion FY13 Enacted $27.5 M

  20. PNCA-02 Rate Case (rates/ratecases)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proposed Adjustment to the Rate for Interchange Energy Imbalances Under the Pacific Northwest Coordination Agreement (PNCA-02 Rate Case) (updated on April 26, 2002) BPA has issued...

  1. Development of metal-coated ceramic anodes for molten carbonate fuel cells. Final report

    SciTech Connect (OSTI)

    Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

    1990-03-01

    This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

  2. Development of metal-coated ceramic anodes for molten carbonate fuel cells

    SciTech Connect (OSTI)

    Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

    1990-03-01

    This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

  3. Measure Guideline. Transitioning From Three-Coat Stucco to One-Coat Stucco With EPS

    SciTech Connect (OSTI)

    Brozyna, K.; Davis, G.; Rapport, A.

    2012-04-01

    This measure guideline has been developed to help builders transition from using a traditional three-coat stucco wall-cladding system to a one-coat stucco wall-cladding system with expanded polystyrene (EPS) insulated sheathing. The one-coat system maintains the look of a traditional stucco system but uses only a base layer and a finish coat over EPS insulation that achieves higher levels of energy efficiency. Potential risks associated with the installation of a one-coat stucco system are addressed in terms of design, installation, and warranty concerns such as cracking and delamination, along with mitigation strategies to reduce these risks.

  4. Cationic electrodepositable coating composition comprising lignin

    DOE Patents [OSTI]

    Fenn, David; Bowman, Mark P; Zawacky, Steven R; Van Buskirk, Ellor J; Kamarchik, Peter

    2013-07-30

    A cationic electrodepositable coating composition is disclosed. The present invention in directed to a cationic electrodepositable coating composition comprising a lignin-containing cationic salt resin, that comprises (A) the reaction product of: lignin, an amine, and a carbonyl compound; (B) the reaction product of lignin, epichlorohydrin, and an amine; or (C) combinations thereof.

  5. Available Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    application. Search Our Technologies submit Advanced Materials Advanced Materials Biotechnology Biotechnology Chemistry Chemistry Energy Energy High Performance Computing:...

  6. Licensing Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Licensing Technology Licensing Technology The primary function of Los Alamos Licensing Program is to move Los Alamos technology to the marketplace for the benefit of the U.S. economy. Our intellectual property may be licensed for commercial use, research applications, and U.S. government use. Contact thumbnail of Marcus Lucero Head of Licensing Marcus Lucero Richard P. Feynman Center for Innovation (505) 665-6569 Email Although Los Alamos's primary mission is national security, our technologies

  7. Technology Opportunities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intellectual Property » Technology Opportunities Technology Opportunities We deliver innovation through an integrated portfolio of R&D work across our key national security sponsoring agencies, enhanced by the ideas developed through our strategic internal investments. Contact Business Development Team Richard P. Feynman Center for Innovation (505) 665-9090 Email Periodically, the Laboratory notifies the public of technologies and capabilities that may be of interest. These technologies may

  8. Technology Partnering

    Energy Savers [EERE]

    on Technology Transfer and Related Technology Partnering Activities at the National Laboratories and Other Facilities Fiscal Years 2009-2013 Report to Congress May 2015 United States Department of Energy Washington, DC 20585 Message from the Secretary The Report on Technology Transfer and Related Partnering Activities at the National Laboratories and Other Facilities for Fiscal Year 2009-2013 is prepared in accordance with the requirements of the Technology Transfer and Commercialization Act of

  9. Energy Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies Our Vision National User Facilities Research Areas In Focus Global Solutions ⇒ Navigate Section Our Vision National User Facilities Research Areas In Focus Global Solutions Energy Technologies Area (ETA) Building Technology & Urban Systems Energy Analysis & Environmental Impacts Energy Storage & Distributed Resources

  10. Technology Assessment

    Energy Savers [EERE]

    - FOR OFFICIAL USE ONLY - DRAFT 1 Advanced Composites Materials and their Manufacture 1 Technology Assessment 2 Contents 3 1. Introduction to the Technology/System ................................................................................................ 2 4 2. Technology Potential and Assessment .................................................................................................. 4 5 2.1 The Potential for Advanced Composites for Clean Energy Application Areas

  11. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, Oscar H.; Curtis, Paul G.

    1992-01-01

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof.

  12. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, O.H.; Curtis, P.G.

    1992-03-31

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

  13. Multilayer coatings for solar energy control applications

    SciTech Connect (OSTI)

    Kivaisi, R.T.; Mbise, G.

    1993-12-31

    This work presents some results for window coatings that are suitable for solar control applications. Selected research results are given for metal/dielectric based coatings optimized for normal incidence. These coatings can be used to improve the performance of windows both for architectural and automobile sectors. Surface coatings which are transparent at 0.3 < {lambda} < 0.7 {micro}m can be used to solar control windows. A thin homogeneous noble metal film (eg Ag) can combine short wavelength transmittance with high long wavelength reflectance. By embedding the metal film between high refractive index dielectric layers one can optimize the transmittance in the desired spectral region. Transmittance data for multilayer stacks designed for normal and non normal incidence to the coating are presented.

  14. The HMDS Coating Flaw Removal Tool

    SciTech Connect (OSTI)

    Monticelli, M V; Nostrand, M C; Mehta, N; Kegelmeyer, L; Johnson, M A; Fair, J; Widmayer, C

    2008-10-24

    In many high energy laser systems, optics with HMDS sol gel antireflective coatings are placed in close proximity to each other making them particularly susceptible to certain types of strong optical interactions. During the coating process, halo shaped coating flaws develop around surface digs and particles. Depending on the shape and size of the flaw, the extent of laser light intensity modulation and consequent probability of damaging downstream optics may increase significantly. To prevent these defects from causing damage, a coating flaw removal tool was developed that deploys a spot of decane with a syringe and dissolves away the coating flaw. The residual liquid is evacuated leaving an uncoated circular spot approximately 1mm in diameter. The resulting uncoated region causes little light intensity modulation and thus has a low probability of causing damage in optics downstream from the mitigated flaw site.

  15. Thermal barrier characteristics of partially stabilized zirconia coatings on INCOLOY alloy 909; A controlled expansion alloy

    SciTech Connect (OSTI)

    Smith, G.D. )

    1991-01-01

    This paper reports on INCOLOY{sup 1} alloy 909 which is a low-expansion alloy used in critical seal and shaft applications within the gas turbine engine. However, because of its poor oxidation resistance at elevated temperatures, the maximum service temperature is limited. Since its coefficient of expansion is similar to that of partially stabilized zirconia for temperatures to 1200{degrees}F (649{degrees}C), it has been proposed to use this metal-ceramic combination for dimensionally critical, air-cooled jet engine components. This coating system should extend temperature limitations by reducing metal temperatures and providing oxidation resistance. The performance advantage offered by a thermal barrier coating has been investigated at temperatures up to 2000{degrees}F (1093{degrees}C) and the results are presented in this paper. Metal temperatures and heat flow rates of coated and bare specimens are compared for two air-cooling flow rates.

  16. Cavitation erosion of silver plated coating at different temperatures and pressures

    SciTech Connect (OSTI)

    Hattori, Shuji; Motoi, Yoshihiro; Kikuta, Kengo; Tomaru, Hiroshi

    2014-04-11

    Cavitation often occurs in inducer pumps used for space rockets. Silver plated coating on the inducer liner faces the damage of cavitation. Therefore, it is important to study about the cavitation erosion resistance for silver plated coating at several operating conditions in the inducer pumps. In this study, the cavitation erosion tests were carried for silver plated coating in deionized water and ethanol at several liquid temperatures (273K400K) and pressures (0.10MPa0.48MPa). The mass loss rate is evaluated in terms of thermodynamic parameter ? proposed by Brennen [9], suppression pressure pp{sub v} (p{sub v}: saturated vapor pressure) and acoustic impedance ?c (?: density and c: sound speed). Cavitation bubble behaviors depending on the thermodynamic effect and the liquid type were observed by high speed video camera. The mass loss rate is formulated by thermodynamic parameter ?, suppression pressure pp{sub v} and acoustic impedance ?c.

  17. Superhydrophobic anti-ultraviolet films by doctor blade coating

    SciTech Connect (OSTI)

    Cai, Chang-Yun; Yang, Hongta; Lin, Kun-Yi Andrew

    2014-11-17

    This article reports a scalable technology for fabricating polymer films with excellent water-repelling and anti-ultraviolet properties. A roll-to-roll compatible doctor blade coating technology is utilized to prepare silica colloidal crystal-polymer composites. The silica microspheres can then be selectively removed to create flexible self-standing macroporous polymer films with crystalline arrays of pores. The void sizes are controlled by tuning the duration of a reactive ion etching process prior to the removal of the templating silica microspheres. After surface modification, superhydrophobic surface can be achieved. This study further demonstrates that the as-prepared transparent porous films with 200?nm of pores exhibit diffraction of ultraviolet lights originated from the Bragg's diffractive of light from the three-dimensional highly ordered air cavities.

  18. Gasless sputtering: Opportunities for ultraclean metallization, coatings in space, and propulsion

    SciTech Connect (OSTI)

    Andersson, Joakim; Anders, Andre

    2008-06-02

    Pulsed magnetron sputtering was demonstrated in high vacuum: no sputter gas was used at any time. Sustained self-sputtering was initiated by multiply charged ions from a short vacuum arc. Copper ion currents to an ion collector in excess of 30 A were measured, implying a plasma density of about 6x10{sup 18} m{sup -3}. This technology may prove useful for metal coatings free of noble gas inclusions and suggests that magnetrons could operate in the vacuum of space. In addition to coating objects in space, the momentum of the sputtered atoms and ions may be utilized in space thrusters.

  19. FY05 HPCRM Annual Report: High-Performance Corrosion-Resistant Iron-Based Amorphous Metal Coatings

    SciTech Connect (OSTI)

    Farmer, J; Choi, J; Haslam, J; Day, S; Yang, N; Headley, T; Lucadamo, G; Yio, J; Chames, J; Gardea, A; Clift, M; Blue, G; Peters, W; Rivard, J; Harper, D; Swank, D; Bayles, R; Lemieux, E; Brown, R; Wolejsza, T; Aprigliano, L; Branagan, D; Marshall, M; Meacham, B; Aprigliano, L; Branagan, D; Marshall, M; Meacham, B; Lavernia, E; Schoenung, J; Ajdelsztajn, L; Dannenberg, J; Graeve, O; Lewandowski, J; Perepezko, J; Hildal, K; Kaufman, L; Boudreau, J

    2007-09-20

    New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Two Fe-based amorphous metal formulations have been found that appear to have corrosion resistance comparable to, or better than that of Ni-based Alloy C-22, based on breakdown potential and corrosion rate. Both Cr and Mo provide corrosion resistance, B enables glass formation, and Y lowers critical cooling rate (CCR). SAM1651 has yttrium added, and has a nominal critical cooling rate of only 80 Kelvin per second, while SAM2X7 (similar to SAM2X5) has no yttrium, and a relatively high critical cooling rate of 610 Kelvin per second. Both amorphous metal formulations have strengths and weaknesses. SAM1651 (yttrium added) has a low critical cooling rate (CCR), which enables it to be rendered as a completely amorphous thermal spray coating. Unfortunately, it is relatively difficult to atomize, with powders being irregular in shape. This causes the powder to be difficult to pneumatically convey during thermal spray deposition. Gas atomized SAM1651 powder has required cryogenic milling to eliminate irregularities that make flow difficult. SAM2X5 (no yttrium) has a high critical cooling rate, which has caused problems associated with devitrification. SAM2X5 can be gas atomized to produce spherical powders of SAM2X5, which enable more facile thermal spray deposition. The reference material, nickel-based Alloy C-22, is an outstanding corrosion-resistant engineering material. Even so, crevice corrosion has been observed with C-22 in hot sodium chloride environments without buffer or inhibitor. Comparable metallic alloys such as SAM2X5 and SAM1651 may also experience crevice corrosion under sufficiently harsh conditions. Accelerated crevice corrosion tests are now being conducted to intentionally induce crevice corrosion, and to determine those environmental conditions where such localized attack occurs. Such materials are extremely hard, and provide enhanced resistance to abrasion and gouges (stress risers) from backfill operations, and possibly even tunnel boring. The hardness of Type 316L Stainless Steel is approximately 150 VHN, that of Alloy C-22 is approximately 250 VHN, and that of HVOF SAM2X5 ranges from 1100-1300 VHN. These new materials provide a viable coating option for repository engineers. SAM2X5 and SAM1651 coatings can be applied with thermal spray processes without any significant loss of corrosion resistance. Both Alloy C-22 and Type 316L stainless lose their resistance to corrosion during thermal spraying. Containers for the transportation, storage and disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) with corrosion resistant coatings are envisioned. For example, an enhanced multi-purpose container (MPC) could be made with such coatings, leveraging existing experience in the fabrication of such containers. These coating materials could be used to protect the final closure weld on SNF/HLW disposal containers, eliminate need for stress mitigation. Integral drip shield could be produced by directly spraying it onto the disposal container, thereby eliminating the need for an expensive titanium drip shield. In specific areas where crevice corrosion is anticipated, such as the contact point between the disposal container and pallet, HVOF coatings could be used to buildup thickness, thereby selectively adding corrosion life where it is needed. Both SAM2X5 & SAM1651 have high boron content which enable them to absorb neutrons and therefore be used for criticality control in baskets. Alloy C-22 and 316L have no neutron absorber, and cannot be used for such functions. Borated stainless steel and G

  20. Improvement in Plasma Performance with Lithium Coatings in NSTX...

    Office of Scientific and Technical Information (OSTI)

    Improvement in Plasma Performance with Lithium Coatings in NSTX Citation Details In-Document Search Title: Improvement in Plasma Performance with Lithium Coatings in NSTX Lithium...

  1. Development of Steel Fastener Nano-Ceramic Coatings for Corrosion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium Parts (AMD-704) Development of Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium ...

  2. Table III: Technical Targets for Catalyst Coated Membranes (CCMs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    III: Technical Targets for Catalyst Coated Membranes (CCMs): Stationary Table III: Technical Targets for Catalyst Coated Membranes (CCMs): Stationary Technical targets for CCMs in ...

  3. Method for smoothing the surface of a protective coating

    DOE Patents [OSTI]

    Sangeeta, D.; Johnson, Curtis Alan; Nelson, Warren Arthur

    2001-01-01

    A method for smoothing the surface of a ceramic-based protective coating which exhibits roughness is disclosed. The method includes the steps of applying a ceramic-based slurry or gel coating to the protective coating surface; heating the slurry/gel coating to remove volatile material; and then further heating the slurry/gel coating to cure the coating and bond it to the underlying protective coating. The slurry/gel coating is often based on yttria-stabilized zirconia, and precursors of an oxide matrix. Related articles of manufacture are also described.

  4. Superhydrophobic Metal-Oxide Thin Film Coatings - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (water repellant) coatings. However, traditional superhydrophobic coatings are soft in nature, with a Teflon-like surface chemistry that results in reduced adhesion and durability,...

  5. The commercial development of water repellent coatings for high...

    Office of Scientific and Technical Information (OSTI)

    development of water repellent coatings for high voltage transmission lines Citation Details In-Document Search Title: The commercial development of water repellent coatings ...

  6. Fort Devens: Cold Climate Market-Rate Townhomes Targeting HERS Index of 40, Harvard, Massachusetts (Fact Sheet), Building America Case Study: Whole-House Solutions for New Homes, Building Technologies Office (BTO)

    Energy Savers [EERE]

    Fort Devens: Cold Climate Market-Rate Townhomes Targeting HERS Index of 40 Harvard, Massachusetts PROJECT INFORMATION Project Name: Devens Sustainable Housing Location: Harvard, MA Partners: Metric Construction www.metriccorp.com Consortium for Advanced Residential Buildings www.carb-swa.com Size: 1,300 ft 2 plus basement Price: approx. $250,000 Year Completed: 2012 Climate Zone: Cold PERFORMANCE DATA HERS Index: 39 (before renewables) Projected Annual Energy Savings: $580 Incremental Cost of

  7. Concept for lightweight spaced-based deposition technology

    SciTech Connect (OSTI)

    Fulton, Michael; Anders, Andre

    2006-02-28

    In this contribution we will describe a technology path to very high quality coatings fabricated in the vacuum of space. To accomplish the ambitious goals set out in NASA's Lunar-Mars proposal, advanced thin-film deposition technology will be required. The ability to deposit thin-film coatings in the vacuum of lunar-space could be extremely valuable for executing this new space mission. Developing lightweight space-based deposition technology (goal:<300 g, including power supply) will enable the future fabrication and repair of flexible large-area space antennae and fixed telescope mirrors for lunar-station observatories. Filtered Cathodic Arc (FCA) is a proven terrestrial energetic thin-film deposition technology that does not need any processing gas but is well suited for ultra-high vacuum operation. Recently, miniaturized cathodic arcs have already been developed and considered for space propulsion. It is proposed to combine miniaturized pulsed FCA technology and robotics to create a robust, enabling space-based deposition system for the fabrication, improvement, and repair of thin films, especially of silver and aluminum, on telescope mirrors and eventually on large area flexible substrates. Using miniature power supplies with inductive storage, the typical low-voltage supply systems used in space are adequate. It is shown that high-value, small area coatings are within the reach of existing technology, while medium and large area coatings are challenging in terms of lightweight technology and economics.

  8. Enhancement of Heat Transfer with Pool and Spray Impingement Boiling on Microporous and Nanowire Surface Coatings

    SciTech Connect (OSTI)

    Thiagarajan, S. J.; Wang, W.; Yang, R.; Narumanchi, S.; King, C.

    2010-09-01

    The DOE National Renewable Energy Laboratory (NREL) is leading a national effort to develop next-generation cooling technologies for hybrid vehicle electronics. The goal is to reduce the size, weight, and cost of power electronic modules that convert direct current from batteries to alternating current for the motor, and vice versa. Aggressive thermal management techniques help to increase power density and reduce weight and volume, while keeping chip temperatures within acceptable limits. The viability of aggressive cooling schemes such as spray and jet impingement in conjunction with enhanced surfaces is being explored. Here, we present results from a series of experiments with pool and spray boiling on enhanced surfaces, such as a microporous layer of copper and copper nanowires, using HFE-7100 as the working fluid. Spray impingement on the microporous coated surface showed an enhancement of 100%-300% in the heat transfer coefficient at a given wall superheat with respect to spray impingement on a plain surface under similar operating conditions. Critical heat flux also increased by 7%-20%, depending on flow rates.

  9. New Barrier Coating Materials for PV Module Backsheets: Preprint

    SciTech Connect (OSTI)

    Barber, G. D.; Jorgensen, G. J.; Terwilliger, K.; Glick, S. H.; Pern, J.; McMahon, T. J.

    2002-05-01

    This conference paper describes the high moisture barrier high resistivity coatings on polyethylene terepthalate (PET) have been fabricated and characterized for use in PV module back sheet applications. These thin film barriers exhibit water vapor transmission rates (WVTR) as low as 0.1 g/m2-day at 37.8 C and have shown excellent adhesion (> 10 N/mm) to both ethylene vinyl acetate (EVA) and PET even after filtered xenon arc lamp UV exposure. The WVTR and adhesion values for this construction are compared to and shown to be superior to candidate polymeric backsheet materials.

  10. Rate Case Elements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proceeding Rate Information Residential Exchange Program Surplus Power Sales Reports Rate Case Elements BPA's rate cases are decided "on the record." That is, in making a decision...

  11. Effect of Superalloy Substrate and Bond Coating on TBC Lifetime

    SciTech Connect (OSTI)

    Pint, Bruce A; Haynes, James A; Zhang, Ying

    2010-01-01

    Several different single-crystal superalloys were coated with different bond coatings to study the effect of composition on the cyclic oxidation lifetime of an yttria-stabilized zirconia (YSZ) top coating deposited by electron beam physical vapor deposition from a commercial source. Three different superalloys were coated with a 7 {micro}m Pt layer that was diffused into the surface prior to YSZ deposition. One of the superalloys, N5, was coated with a low activity, Pt-modified aluminide coating and Pt-diffusion coatings with 3 and 7 {micro}m of Pt. Three coatings of each type were furnace cycled to failure in 1 h cycles at 1150 C to assess average coating lifetime. The 7 {micro}m Pt diffusion coating on N5 had an average YSZ coating lifetime >50% higher than a Pt-modified aluminide coating on N5. Without a YSZ coating, the Pt-modified aluminide coating on N5 showed the typical surface deformation during cycling, however, the deformation was greatly reduced when constrained by the YSZ coating. The 3 {micro}m Pt diffusion coating had a similar average lifetime as the Pt-modified aluminide coating but a much wider scatter. The Pt diffusion bond coating on superalloy X4 containing Ti exhibited the shortest YSZ coating lifetime, this alloy-coating combination also showed the worst alumina scale adhesion without a YSZ coating. The third generation superalloy N6 exhibited the longest coating lifetime with a 7 {micro}m Pt diffusion coating.

  12. Calibration and Rating of Photovoltaics: Preprint

    SciTech Connect (OSTI)

    Emery, K.

    2012-06-01

    Rating the performance of photovoltaic (PV) modules is critical to determining the cost per watt, and efficiency is useful to assess the relative progress among PV concepts. Procedures for determining the efficiency for PV technologies from 1-sun to low concentration to high concentration are discussed. We also discuss the state of the art in primary and secondary calibration of PV reference cells used by calibration laboratories around the world. Finally, we consider challenges to rating PV technologies and areas for improvement.

  13. Technology '90

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The US Department of Energy (DOE) laboratories have a long history of excellence in performing research and development in a number of areas, including the basic sciences, applied-energy technology, and weapons-related technology. Although technology transfer has always been an element of DOE and laboratory activities, it has received increasing emphasis in recent years as US industrial competitiveness has eroded and efforts have increased to better utilize the research and development resources the laboratories provide. This document, Technology '90, is the latest in a series that is intended to communicate some of the many opportunities available for US industry and universities to work with the DOE and its laboratories in the vital activity of improving technology transfer to meet national needs. Technology '90 is divided into three sections: Overview, Technologies, and Laboratories. The Overview section describes the activities and accomplishments of the DOE research and development program offices. The Technologies section provides descriptions of new technologies developed at the DOE laboratories. The Laboratories section presents information on the missions, programs, and facilities of each laboratory, along with a name and telephone number of a technology transfer contact for additional information. Separate papers were prepared for appropriate sections of this report.

  14. Power Rate Cases (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Choices (2003-06) Power Function Review (PFR) Firstgov Power Rate Cases BPA's wholesale power rates are set to recover its costs and repay the U.S. Treasury for the Federal...

  15. Chlorite Dissolution Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Carroll, Susan

    2013-07-01

    Spreadsheets provides measured chlorite rate data from 100 to 300C at elevated CO2. Spreadsheet includes derived rate equation.

  16. Chlorite Dissolution Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Carroll, Susan

    Spreadsheets provides measured chlorite rate data from 100 to 300C at elevated CO2. Spreadsheet includes derived rate equation.

  17. High performance anti-reflection coatings for broadband multi-junction solar cells

    SciTech Connect (OSTI)

    AIKEN,DANIEL J.

    2000-02-23

    The success of bandgap engineering has made high efficiency broadband multi-junction solar cells possible with photo-response out to the band edge of Ge. Modeling has been conducted which suggests that current double layer anti-reflection coating technology is not adequate for these devices in certain cases. Approaches for the development of higher performance anti-reflection coatings are examined. A new AR coating structure based on the use of Herpin equivalent layers is presented. Optical modeling suggests a decrease in the solar weighted reflectance of over 2.5{percent} absolute as a result. This structure requires no additional optical material development and characterization because no new optical materials are necessary. Experimental results and a sensitivity analysis are presented.

  18. Advanced Fuels Campaign Cladding & Coatings Meeting Summary

    SciTech Connect (OSTI)

    Not Listed

    2013-03-01

    The Fuel Cycle Research and Development (FCRD) Advanced Fuels Campaign (AFC) organized a Cladding and Coatings operational meeting February 12-13, 2013, at Oak Ridge National Laboratory (ORNL). Representatives from the U.S. Department of Energy (DOE), national laboratories, industry, and universities attended the two-day meeting. The purpose of the meeting was to discuss advanced cladding and cladding coating research and development (R&D); review experimental testing capabilities for assessing accident tolerant fuels; and review industry/university plans and experience in light water reactor (LWR) cladding and coating R&D.

  19. Corrosion control of metals by organic coatings

    SciTech Connect (OSTI)

    Ooij, W.J. van; Bierwagen, G.P.; Skerry, B.S.; Mills, D.

    1999-01-01

    The authors present a comprehensive treatment of the entire field of corrosion control of metals, from mechanisms and testing procedures to modification of metal surfaces and interfaces by silanes and plasma techniques. They discuss the new, sophisticated analytical tools, such as Time-of-Flight SIMS and electrochemical impedance spectroscopy, and all materials -- metals, pretreatments, and paint systems. The contents include: (1) Corrosion under organic coatings; (2) Mechanisms of corrosion control by organic coatings; (3) Metal pretreatments; (4) Techniques to study organic coating-metal interfaces; (5) Modification of metal surfaces and interfaces; (6) corrosion testing; (7) Adhesion testing; (8) Paint systems; (9) Conclusions and prospects references.

  20. Void forming pyrolytic carbon coating process

    DOE Patents [OSTI]

    Beatty, Ronald L. (Oak Ridge, TN); Cook, Jackie L. (Oak Ridge, TN)

    2000-01-01

    A pyrolytic carbon coated nuclear fuel particle and method of making it. The fuel particle has a core composed of a refractory compound of an actinide metal. The pyrolytic carbon coating surrounds the core so as to provide a void volume therebetween. The coating has an initial density of no greater than 1.45 grams/cm.sup.3 and an anisotropy factor than 3.0 and a final density upon heat treatment above about 2000.degree. C. of greater than 1.7 grams/cm.sup.3 and an anisotropy factor greater than 5.

  1. Carbon nanotube coatings as chemical absorbers

    DOE Patents [OSTI]

    Tillotson, Thomas M.; Andresen, Brian D.; Alcaraz, Armando

    2004-06-15

    Airborne or aqueous organic compound collection using carbon nanotubes. Exposure of carbon nanotube-coated disks to controlled atmospheres of chemical warefare (CW)-related compounds provide superior extraction and retention efficiencies compared to commercially available airborne organic compound collectors. For example, the carbon nanotube-coated collectors were four (4) times more efficient toward concentrating dimethylmethyl-phosphonate (DMMP), a CW surrogate, than Carboxen, the optimized carbonized polymer for CW-related vapor collections. In addition to DMMP, the carbon nanotube-coated material possesses high collection efficiencies for the CW-related compounds diisopropylaminoethanol (DIEA), and diisopropylmethylphosphonate (DIMP).

  2. Near-infrared radiation curable multilayer coating systems and methods for applying same

    DOE Patents [OSTI]

    Bowman, Mark P; Verdun, Shelley D; Post, Gordon L

    2015-04-28

    Multilayer coating systems, methods of applying and related substrates are disclosed. The coating system may comprise a first coating comprising a near-IR absorber, and a second coating deposited on a least a portion of the first coating. Methods of applying a multilayer coating composition to a substrate may comprise applying a first coating comprising a near-IR absorber, applying a second coating over at least a portion of the first coating and curing the coating with near infrared radiation.

  3. Sandia Energy - Marine Hydrokinetics Technology: Technology Developmen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and currenttidal power devices. Areas of focus will be on coatings, composites, and molding processes. System Reliability and Survivability Similar to other early stage...

  4. Huazhong Science Technology University Yongtai Science Technology...

    Open Energy Info (EERE)

    Huazhong Science Technology University Yongtai Science Technology Co Ltd Jump to: navigation, search Name: Huazhong Science & Technology University Yongtai Science & Technology Co...

  5. Measure Guideline: Transitioning from Three-Coat Stucco to One-Coat Stucco with EPS

    SciTech Connect (OSTI)

    Brozyna, K.; Davis, G.; Rapport, A.

    2012-04-01

    This Measure Guideline has been developed to help builders transition from using a traditional three-coat stucco wall-cladding system to a one-coat stucco wall-cladding system with expanded polystyrene (EPS) insulated sheathing. The three-coat system uses a base layer, a fill layer, and a finish layer. The one-coat system maintains the look of a traditional stucco system but uses only a base layer and a finish coat over EPS insulation that achieves higher levels of energy efficiency. Potential risks associated with the installation of a one-coat stucco system are addressed in terms of design, installation, and warranty concerns such as cracking and delamination, along with mitigation strategies to reduce these risks.

  6. Taking technology to market

    SciTech Connect (OSTI)

    Ford, D.; Ryan, C.

    1981-03-01

    For many years, the concept of the product life cycle has helped managers maximize their return on product sales. But according to the authors of this article, using a technology solely in product sales is no longer enough. Today, companies face high R and D costs, competitive pressures from low-cost producers, capacity limitations, antitrust laws, financial difficulties, and foreign trade barriers. This means that they must improve the rate of return on their technology investments by marketing their technology as completely as possible during all phases of its life cycle. The technology life cycle - derived from the product life cycle - pinpoints the changing decisions companies face in selling their know-how. The authors also discuss both the competitive dangers of transferring technology to low-cost foreign producers and the growing role of intermediaries in technology sales. They stress the importance of having a highly specialized staff to plan a company's technology marketing, a responsibility that should be assigned neither to the part-time attention of top management nor simply to marketers or strategic planners.

  7. Method for improving the oxidation-resistance of metal substrates coated with thermal barrier coatings

    DOE Patents [OSTI]

    Thompson, Anthony Mark (Niskayuna, NY); Gray, Dennis Michael (Delanson, NY); Jackson, Melvin Robert (Niskayuna, NY)

    2002-01-01

    A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.

  8. NON-DESTRUCTIVE THERMAL BARRIER COATING SPALLATION PREDICTION BY A LOADBASED MICRO-INDENTATION TECHNIQUE

    SciTech Connect (OSTI)

    J. M. Tannenbaum; K. Lee; B. S.-J. Kang; M.A. Alvin

    2010-11-18

    Currently, the durability and life cycle of thermal barrier coatings (TBC) applied to gas turbine blades and combustor components are limiting the maximum temperature and subsequent efficiency at which gas turbine engines operate. The development of new materials, coating technologies and evaluation techniques is required if enhanced efficiency is to be achieved. Of the current ceramic coating materials used in gas turbine engines, yttria stabilized zirconia (YSZ) is most prevalent, its low thermal conductivity, high thermal expansion coefficient and outstanding mechanical strength make it ideal for use in TBC systems. However, residual stresses caused by coefficients of thermal expansion mismatches within the TBC system and unstable thermally grown oxides are considered the primary causes for its premature and erratic spallation failure. Through finite element simulations, it is shown that the residual stresses generated within the thermally grown oxide (TGO), bond coat (BC), YSZ and their interfaces create slight variations in indentation unloading surface stiffness response prior to spallation failure. In this research, seven air plasma sprayed and one electron beam physical vapor deposition yttria partially stabilized zirconia TBCs were subjected to isothermal and cyclic loadings at 1100C. The associated coating degradation was evaluated using a non-destructive multiple partial unloading micro-indentation procedure. The results show that the proposed non-destructive micro-indentation evaluation technique can be an effective and specimenindependent TBC failure prediction tool capable of determining the location of initial spallation failure prior to its actual occurrence.

  9. Effect of oxygen incorporation on structural and properties of Ti-Si-N nanocomposite coatings deposited by reactive unbalanced magnetron sputtering

    SciTech Connect (OSTI)

    Ding, X.Z.; Zeng, X.T.; Liu, Y.C.; Zhao, L.R.

    2006-07-15

    Ti-Si-N-O nanocomposite coatings with different contents of oxygen were deposited by a combined dc/rf reactive unbalanced magnetron sputtering process in an Ar+N{sub 2}+O{sub 2} mixture atmosphere. The composition, structure, mechanical, and tribological properties of the as-deposited coatings were analyzed by energy dispersive analysis of x-rays, x-ray diffraction (XRD), nanoindentation, and pin-on-disk tribometer experiments, respectively. It was found that in the range of lower oxygen content with atomic ratio of O/N{<=}0.72, the tribological properties of the Ti-Si-N-O coatings are evidently improved, in comparison with the coating without oxygen incorporation. At O/N=0.72, the friction coefficient and wear rate of the as-deposited coatings are reduced to 20% and 45%, respectively. Meanwhile, however, their hardness was not reduced, but, on the contrary, slightly increased. With increasing oxygen content further to O/N{>=}0.72, coating hardness decreased significantly. The friction coefficient of the as-deposited coatings decreased monotonously with the increase of oxygen content in the whole composition range investigated. The wear rate of the coatings exhibited a minimum value at around O/N=0.72. In the lower range of O/N, wear rate decreased significantly due to the lubricant effect of oxygen incorporation, while in the higher range of O/N, wear rate increased gradually due to the weakening of coating hardness. XRD patterns revealed that the as-deposited coatings were mainly crystallized in cubic TiN phase, accompanied with minority of rutile structure titania in the case of higher oxygen incorporation.

  10. Sol-gel antireflective coating on plastics

    DOE Patents [OSTI]

    Ashley, Carol S. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM)

    1990-01-01

    An antireflection film made from a reliquified sol-gel hydrolyzation, condensation polymeric reaction product of a silicon, alkoxides and/or metal alkoxides, or mixtures thereof. The film is particularly useful for coating plastics.

  11. Sol-gel antireflective coating on plastics

    DOE Patents [OSTI]

    Ashley, C.S.; Reed, S.T.

    1988-01-26

    An antireflection film made from reliquified sol-gel hydrolyzation, condensation polymeric reaction product of a silicon, alkoxides and/or metal alkoxides, or mixtures thereof. The film is particularly useful for coating plastics.

  12. Thin film-coated polymer webs

    DOE Patents [OSTI]

    Wenz, Robert P.; Weber, Michael F.; Arudi, Ravindra L.

    1992-02-04

    The present invention relates to thin film-coated polymer webs, and more particularly to thin film electronic devices supported upon a polymer web, wherein the polymer web is treated with a purifying amount of electron beam radiation.

  13. Conformal chemically resistant coatings for microflow devices

    DOE Patents [OSTI]

    Folta, James A.; Zdeblick, Mark

    2003-05-13

    A process for coating the inside surfaces of silicon microflow devices, such as electrophoresis microchannels, with a low-stress, conformal (uniform) silicon nitride film which has the ability to uniformly coat deeply-recessed cavities with, for example, aspect ratios of up to 40:1 or higher. The silicon nitride coating allows extended exposure to caustic solutions. The coating enables a microflow device fabricated in silicon to be resistant to all classes of chemicals: acids, bases, and solvents. The process involves low-pressure (vacuum) chemical vapor deposition. The ultra-low-stress silicon nitride deposition process allows 1-2 .mu.m thick films without cracks, and so enables extended chemical protection of a silicon microflow device against caustics for up to 1 year. Tests have demonstrated the resistance of the films to caustic solutions at both ambient and elevated temperatures to 65.degree. C.

  14. Neutron absorbing coating for nuclear criticality control

    DOE Patents [OSTI]

    Mizia, Ronald E.; Wright, Richard N.; Swank, William D.; Lister, Tedd E.; Pinhero, Patrick J.

    2007-10-23

    A neutron absorbing coating for use on a substrate, and which provides nuclear criticality control is described and which includes a nickel, chromium, molybdenum, and gadolinium alloy having less than about 5% boron, by weight.

  15. Nickel coated aluminum battery cell tabs

    DOE Patents [OSTI]

    Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

    2014-07-29

    A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

  16. Method for fluidizing and coating ultrafine particles, device for fluidizing and coating ultrafine particles

    DOE Patents [OSTI]

    Li, Jie; Liu, Yung Y

    2015-01-20

    The invention provides a method for dispersing particles within a reaction field, the method comprising confining the particles to the reaction field using a standing wave. The invention also provides a system for coating particles, the system comprising a reaction zone; a means for producing fluidized particles within the reaction zone; a fluid to produce a standing wave within the reaction zone; and a means for introducing coating moieties to the reaction zone. The invention also provides a method for coating particles, the method comprising fluidizing the particles, subjecting the particles to a standing wave; and contacting the subjected particles with a coating moiety.

  17. Technologies licensed | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    facilities and large sporting venues, as well as for other Department of Energy sites. Sustainable Environment Technologies, LLC (SET), licensed the Access Rate Control System...

  18. Apparatus for coating a surface with a metal utilizing a plasma source

    DOE Patents [OSTI]

    Brown, Ian G. (Berkeley, CA); MacGill, Robert A. (Richmond, CA); Galvin, James E. (Emeryville, CA)

    1991-01-01

    An apparatus and method for coating or layering a surface with a metal utilizing a metal vapor vacuum arc plasma source. The apparatus includes a trigger mechanism for actuating the metal vacuum vapor arc plasma source in a pulsed mode at a predetermined rate. The surface or substrate to be coated or layered is supported in position with the plasma source in a vacuum chamber. The surface is electrically biased for a selected period of time during the pulsed mode of operation of the plasma source. Both the pulsing of the metal vapor vacuum arc plasma source and the electrical biasing of the surface are synchronized for selected periods of time.

  19. NREL: Technology Deployment - Technology Acceleration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Acceleration NREL offers technology-specific assistance to federal and private industry to help address market barriers to sustainable energy technologies. Learn more about NREL's work in the following areas: Biopower and Waste-to-Energy Biopower and Waste-to-Energy Buildings Buildings Fuels, Vehicles, & Transportation Fuels, Vehicles, and Transportation Microgrid Design Microgrid Design Solar Solar Wind Wind Contact Us For more information on NREL's market transformation work,

  20. Thermally activated technologies: Technology Roadmap

    SciTech Connect (OSTI)

    None, None

    2003-05-01

    The purpose of this Technology Roadmap is to outline a set of actions for government and industry to develop thermally activated technologies for converting Americas wasted heat resources into a reservoir of pollution-free energy for electric power, heating, cooling, refrigeration, and humidity control. Fuel flexibility is important. The actions also cover thermally activated technologies that use fossil fuels, biomass, and ultimately hydrogen, along with waste heat.

  1. Technology Assessment

    Energy Savers [EERE]

    Roll to Roll (R2R) Processing 1 Technology Assessment 2 3 Contents 4 1. Introduction to the Technology/System ............................................................................................... 2 5 1.1. Introduction to R2R Processing..................................................................................................... 2 6 1.2. R2R Processing Mechanisms ......................................................................................................... 3 7 2.

  2. Apparatus and method for depositing coating onto porous substrate

    DOE Patents [OSTI]

    Isenberg, A.O.; Zymboly, G.E.

    1986-09-02

    Disclosed is an apparatus for forming a chemically vapor deposited coating on a porous substrate where oxygen from a first gaseous reactant containing a source of oxygen permeates through the pores of the substrate to react with a second gaseous reactant that is present on the other side of the substrate. The apparatus includes means for controlling the pressure and flow rate of each gaseous reactant, a manometer for measuring the difference in pressure between the gaseous reactants on each side of the substrate, and means for changing the difference in pressure between the gaseous reactants. Also disclosed is a method of detecting and closing cracks in the coating by reducing the pressure difference between the two gaseous reactants whenever the pressure difference falls suddenly after gradually rising, then again increasing the pressure difference on the two gases. The attack by the by-products of the reaction on the substrate are reduced by maintaining the flow rate of the first reactant through the pores of the substrate. 1 fig.

  3. Apparatus and method for depositing coating onto porous substrate

    DOE Patents [OSTI]

    Isenberg, Arnold O.; Zymboly, Gregory E.

    1986-01-01

    Disclosed is an apparatus for forming a chemically vapor deposited coating on a porous substrate where oxygen from a first gaseous reactant containing a source of oxygen permeates through the pores of the substrate to react with a second gaseous reactant that is present on the other side of the substrate. The apparatus includes means for controlling the pressure and flow rate of each gaseous reactant, a manometer for measuring the difference in pressure between the gaseous reactants on each side of the substrate, and means for changing the difference in pressure between the gaseous reactants. Also disclosed is a method of detecting and closing cracks in the coating by reducing the pressure difference between the two gaseous reactants whenever the pressure difference falls suddenly after gradually rising, then again increasing the pressure difference on the two gases. The attack by the by-products of the reaction on the substrate are reduced by maintaining the flow rate of the first reactant through the pores of the substrate.

  4. Dynamics of polymer film formation during spin coating

    SciTech Connect (OSTI)

    Mouhamad, Y.; Clarke, N.; Jones, R. A. L.; Geoghegan, M.; Mokarian-Tabari, P.

    2014-09-28

    Standard models explaining the spin coating of polymer solutions generally fail to describe the early stages of film formation, when hydrodynamic forces control the solution behavior. Using in situ light scattering alongside theoretical and semi-empirical models, it is shown that inertial forces (which initially cause a vertical gradient in the radial solvent velocity within the film) play a significant role in the rate of thinning of the solution. The development of thickness as a function of time of a solute-free liquid (toluene) and a blend of polystyrene and poly(methyl methacrylate) cast from toluene were fitted to different models as a function of toluene partial pressure. In the case of the formation of the polymer blend film, a concentration-dependent (Huggins) viscosity formula was used to account for changes in viscosity during spin coating. A semi-empirical model is introduced, which permits calculation of the solvent evaporation rate and the temporal evolution of the solute volume fraction and solution viscosity.

  5. HIGH-PERFORMANCE COATING MATERIALS

    SciTech Connect (OSTI)

    SUGAMA,T.

    2007-01-01

    Corrosion, erosion, oxidation, and fouling by scale deposits impose critical issues in selecting the metal components used at geothermal power plants operating at brine temperatures up to 300 C. Replacing these components is very costly and time consuming. Currently, components made of titanium alloy and stainless steel commonly are employed for dealing with these problems. However, another major consideration in using these metals is not only that they are considerably more expensive than carbon steel, but also the susceptibility of corrosion-preventing passive oxide layers that develop on their outermost surface sites to reactions with brine-induced scales, such as silicate, silica, and calcite. Such reactions lead to the formation of strong interfacial bonds between the scales and oxide layers, causing the accumulation of multiple layers of scales, and the impairment of the plant component's function and efficacy; furthermore, a substantial amount of time is entailed in removing them. This cleaning operation essential for reusing the components is one of the factors causing the increase in the plant's maintenance costs. If inexpensive carbon steel components could be coated and lined with cost-effective high-hydrothermal temperature stable, anti-corrosion, -oxidation, and -fouling materials, this would improve the power plant's economic factors by engendering a considerable reduction in capital investment, and a decrease in the costs of operations and maintenance through optimized maintenance schedules.

  6. Optically transparent and environmentally durable superhydrophobic coating

    Office of Scientific and Technical Information (OSTI)

    based on functionalized SiO2 nanoparticles (Journal Article) | SciTech Connect Optically transparent and environmentally durable superhydrophobic coating based on functionalized SiO2 nanoparticles Citation Details In-Document Search Title: Optically transparent and environmentally durable superhydrophobic coating based on functionalized SiO2 nanoparticles Optical surfaces such as mirrors and windows that are exposed to outdoor environmental conditions are susceptible to dust buildup and

  7. Strain-tolerant ceramic coated seal

    DOE Patents [OSTI]

    Schienle, James L. (Phoenix, AZ); Strangman, Thomas E. (Phoenix, AZ)

    1994-01-01

    A metallic regenerator seal is provided having multi-layer coating comprising a NiCrAlY bond layer, a yttria stabilized zirconia (YSZ) intermediate layer, and a ceramic high temperature solid lubricant surface layer comprising zinc oxide, calcium fluoride, and tin oxide. An array of discontinuous grooves is laser machined into the outer surface of the solid lubricant surface layer making the coating strain tolerant.

  8. Geoff Coates > Tisch University Professor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Chemical Biology > Faculty Directory > The Energy Materials Center at Cornell Geoff Coates Tisch University Professor Chemistry and Chemical Biology Research Group Webpage gc39@cornell.edu During the summer of 1997, Dr. Coates joined the faculty of Cornell University as an Assistant Professor of Chemistry. He was promoted to Associate Professor in 2001 and Professor in 2002, and is currently Associate Chair of his Department. He was an Alfred P. Sloan Research Fellow, and

  9. Metal alloy coatings and methods for applying

    DOE Patents [OSTI]

    Merz, Martin D. (Richland, WA); Knoll, Robert W. (Kennewick, WA)

    1991-01-01

    A method of coating a substrate comprises plasma spraying a prealloyed feed powder onto a substrate, where the prealloyed feed powder comprises a significant amount of an alloy of stainless steel and at least one refractory element selected from the group consisting of titanium, zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. The plasma spraying of such a feed powder is conducted in an oxygen containing atmosphere and forms an adherent, corrosion resistant, and substantially homogenous metallic refractory alloy coating on the substrate.

  10. ARCS - Access Rate Control System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARCS - Access Rate Control System Y-12 National Security Complex Contact Y12 About This Technology Publications: PDF Document Publication Fact Sheet (268 KB) PDF Document...

  11. Modelling the microstructure of thermal barrier coatings

    SciTech Connect (OSTI)

    Cirolini, S.; Marchese, M.; Jacucci, G.; Harding, J.H.; Mulheran, P.A.

    1994-12-31

    Thermal barrier coatings produced by plasma spraying have a characteristic microstructure of lamellae, pores and cracks. The lamellae are produced by the splashing of particles onto the substrate. As the coating grows, the lamellae pile on top of each other, producing an interlocking structure. In most cases the growth is rapid and chaotic. The result is a microstructure characterized by pores and cracks. The authors present an improved model for the deposition process of thermal barrier coatings. The task of modeling the coating growth is split into two parts: first the authors consider a description of the particle on arrival at the film, based on the available theoretical, numerical and experimental findings. Second they define and discuss a set of physically-based rules for combining these events to obtain the film. The splats run along the surface and are permitted to curl up (producing pores) or interlock. The computer model uses a mesh to combine these processes and build the coating. They discuss the use of the proposed model in predicting microstructures and hence in correlating the properties of these coatings with the parameters of the process used to make them.

  12. Progress to Develop an Advanced Solar-Selective Coating

    SciTech Connect (OSTI)

    Kennedy, C. E.

    2008-03-01

    The progress to develop a durable advanced solar-selective coating will be described. Experimental work has focused on modeling high-temperature, solar-selective coatings; depositing the individual layers and modeled coatings; measuring the optical, thermal, morphology, and compositional properties and using the data to validate the modeled and deposited properties; re-optimizing the coating; and testing the coating performance and durability.

  13. APS TBC Performance on Directionally-Solidified Superalloy Substrates with HVOF NiCoCrAlYHfSi Bond Coatings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lance, Michael J.; Unocic, Kinga A.; Haynes, James A.; Pint, Bruce A.

    2015-09-04

    Directionally-solidified (DS) superalloy components with advanced thermal barrier coatings (TBC) to lower the metal operating temperature have the potential to replace more expensive single crystal superalloys for large land-based turbines. In order to assess relative TBC performance, furnace cyclic testing was used with superalloys 1483, X4 and Hf-rich DS 247 substrates and high velocity oxygen fuel (HVOF)-NiCoCrAlYHfSi bond coatings at 1100 °C with 1-h cycles in air with 10% H2O. With these coating and test conditions, there was no statistically-significant effect of substrate alloy on the average lifetime of the air plasma sprayed (APS) yttria-stabilized zirconia (YSZ) top coatings onmore » small coupons. Using photo-stimulated luminescence piezospectroscopy maps at regular cycling intervals, the residual compressive stress in the α-Al2O3 scale underneath the YSZ top coating and on a bare bond coating was similar for all three substrates and delaminations occurred at roughly the same rate and frequency. X-ray fluorescence (XRF) measurements collected from the bare bond coating surface revealed higher Ti interdiffusion occurring with the 1483 substrate, which contained the highest Ti content.« less

  14. Assessment of ceramic coatings for metal fuel melting crucible

    SciTech Connect (OSTI)

    Kim, Ki-Hwan; Song, Hoon; Kim, Jong-Hwan; Oh, Seok-Jin; Kim, Hyung-Tae; Lee, Chan-Bock

    2013-07-01

    The objective of this study is to develop a coating method and material for crucibles to prevent material interactions with the U-Zr/U-TRU-Zr fuels during the manufacturing of SFR fuels. Refractory coatings were applied to niobium substrates by vacuum plasma-spray coating method. Melt dipping tests conducted were the coated rods lowered into the fuel melt at 1600 C. degrees, and withdrawn and cooled outside the crucible in the inert atmosphere of the induction furnace. Melt dipping tests of the coated Nb rods indicated that plasma-sprayed Y{sub 2}O{sub 3} coating doesn't form significant reaction layer between fuel melt and coating layer. Melt dipping tests of the coated Nb rods showed that TiC, TaC, and Y{sub 2}O{sub 3} coatings exhibited the promising performance among other ceramic coatings. These materials could be promising candidate materials for the reusable melt crucible of metal fuel for SFR. In addition, in order to develop the vacuum plasma-spray coating method for re-usable crucible of metal fuel slugs to be overcome the issue of thermal expansion mismatch between coating material and crucible, various combinations of coating conditions were investigated to find the bonding effect on the substrate in pursuit of more effective ways to withstand the thermal stresses. It is observed that most coating methods maintained sound coating state in U-Zr melt. (authors)

  15. Technology Commercialization Showcase 2008 Vehicle Technologies Program

    SciTech Connect (OSTI)

    Davis, Patrick B.

    2009-06-19

    Presentation illustrating various technology commercialization opportunities and unexploited investment gaps for the Vehicle Technologies Program.

  16. Tribological properties of CrN coatings deposited by nitro-chromizing treatment on AISI D2 steel

    SciTech Connect (OSTI)

    Durmaz, M. Abakay, E.; Sen, U.; Sen, S.; Kilinc, B.

    2015-03-30

    In this work, the wear test of uncoated and chromium nitride coated AISI D2 cold work tool steel against alumina ball realized at 0.1?m/s sliding speeds and under the loads of 2.5N, 5N and 10N. Steel samples were nitrided at 575C for 8?h in the first step of the coating process, and then chromium nitride coating was performed thermo-reactive deposition technique (TRD) in a powder mixture consisting of ferro-chromium, ammonium chloride and alumina at 1000C for 2?h. Nitro-chromized samples were characterized by X-Ray diffraction analysis (XRD), scanning electron microscopy (SEM), micro-hardness and ball on disk wear tests. The coating layer formed on the AISI D2 steel was compact and homogeneous. X-ray studies showed that the phase formed in the coated layer is Cr{sub 2}N. The depth of the layer was 8.15?m. The average hardness of the layer was 216015 HV{sub 0.025}. For uncoated and chromium nitride materials, wear rate increased with increasing load. The results of friction coefficient and wear rate of the tested materials showed that the CrN coating presents the lowest results.

  17. BP-18 Rate Proceeding

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings...

  18. BP-12 Rate Case

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings...

  19. BP-16 Rate Case

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings...

  20. Before a Rate Case

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings and Workshops Customer...

  1. Rating Agency Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liabilities Financial Plan Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Residential Exchange Program Surplus Power Sales...

  2. 2012 Transmission Rate Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2014 Transmission, Ancillary, and Control Area Service Rate Schedules and General Rate Schedule Provisions (FY 2014-2015) October 2013 United States Department of Energy...

  3. Turbine imaging technology assessment

    SciTech Connect (OSTI)

    Moursund, R. A.; Carlson, T. J.

    2004-12-01

    The goal of this project was to identify and evaluate imaging technologies for observing juvenile fish within a Kaplan turbine, and specifically that would enable scientists to determine mechanisms of fish injury within an operating turbine unit. This report documents the opportunities and constraints for observing juvenile fish at specific locations during turbine passage. These observations were used to make modifications to dam structures and operations to improve conditions for fish passage while maintaining or improving hydropower production. The physical and hydraulic environment that fish experience as they pass through the hydroelectric plants were studied and the regions with the greatest potential for injury were defined. Biological response data were also studied to determine the probable types of injuries sustained in the turbine intake and what types of injuries are detectable with imaging technologies. The study grouped injury-causing mechanisms into two categories: fluid (pressure/cavitation, shear, turbulence) and mechanical (strike/collision, grinding/pinching, scraping). The physical constraints of the environment, together with the likely types of injuries to fish, provided the parameters needed for a rigorous imaging technology evaluation. Types of technology evaluated included both tracking and imaging systems using acoustic technologies (such as sonar and acoustic tags) and optic technologies (such as pulsed-laser videography, which is high-speed videography using a laser as the flash). Criteria for determining image data quality such as frame rate, target detectability, and resolution were used to quantify the minimum requirements of an imaging sensor.

  4. Tag: technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tags

    technology<...

  5. Technology Validation

    Broader source: Energy.gov [DOE]

    To reduce solar technology risks, DOE and its partners evaluate the performance and reliability of novel photovoltaic (PV) hardware and systems through laboratory and field testing. The focus of...

  6. Corrosion protection of SiC-based ceramics with CVD mullite coatings

    SciTech Connect (OSTI)

    Sarin, V.; Mulpuri, R.; Auger, M.

    1996-04-20

    SiC based ceramics have been identified as the leading candidate materials for elevated temperature applications in harsh oxidation/corrosion environments. It has been established that a protective coating can be effectively used to avoid problems with excessive oxidation and hot corrosion. However, to date, no coating configuration has been developed that can withstand the rigorous requirements imposed by such applications. Chemical vapor deposited (CVD) mullite coatings due to their desirable properties of toughness, corrosion resistance, and good coefficient of thermal expansion match with SiC are being developed as a potential solution. Formation of mullite on ceramic substrates via chemical vapor deposition was investigated. Thermodynamic calculations performed on the AlCl{sub 3}- SiCl{sub 4}-CO{sub 2}-H{sub 2} system were used to construct equilibrium CVD phase diagrams. Through process optimization, crystalline CVD mullite coatings have been successfully grown on SiC and Si{sub 3}N{sub 4} substrates. Results from the thermodynamic analysis, process optimization, and effect of various process parameters on deposition rate and coating morphology are discussed.

  7. Robotic weld overlay coatings for erosion control. Final technical progress report, July 1992--July 1995

    SciTech Connect (OSTI)

    Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1995-10-15

    The erosion behavior of weld overlay coatings has been studied. Eleven weld overlay alloys were deposited on 1018 steel substrates using the plasma arc welding process and erosion tested at 400{degrees}C at 90{degrees} and 30{degrees} particle impact angles. The microstructure of each coating was characterized before erosion testing. A relative ranking of the coatings erosion resistance was developed by determining the steady state erosion rates. Ultimet, Inconel-625, and 316L SS coatings showed the best erosion resistance at both impact angles. It was found that weld overlays that exhibit good abrasion resistance did not show good erosion resistance. Erosion tests were also performed for selected wrought materials with chemical composition similar to weld overlays. Eroded surfaces of the wrought and weld alloys were examined by Scanning Electron Microscopy (SEM). Microhardness tests were performed on the eroded samples below the erosion surface to determine size of the plastically deformed region. It was found that one group of coatings experienced significant plastic deformation as a result of erosion while the other did not. It was also established that, in the steady state erosion regime, the size of the plastically deformed region is constant.

  8. Optical coatings of variable refractive index and high laser-resistance from physical-vapor-deposited perfluorinated amorphous polymer

    DOE Patents [OSTI]

    Chow, R.; Loomis, G.E.; Thomas, I.M.

    1999-03-16

    Variable index optical single-layers, optical multilayer, and laser-resistant coatings were made from a perfluorinated amorphous polymer material by physical vapor deposition. This was accomplished by physically vapor depositing a polymer material, such as bulk Teflon AF2400, for example, to form thin layers that have a very low refractive index (ca. 1.10--1.31) and are highly transparent from the ultra-violet through the near infrared regime, and maintain the low refractive index of the bulk material. The refractive index can be varied by simply varying one process parameter, either the deposition rate or the substrate temperature. The thus forming coatings may be utilized in anti-reflectors and graded anti-reflection coatings, as well as in optical layers for laser-resistant coatings at optical wavelengths of less than about 2000 nm. 2 figs.

  9. Optical coatings of variable refractive index and high laser-resistance from physical-vapor-deposited perfluorinated amorphous polymer

    DOE Patents [OSTI]

    Chow, Robert (Livermore, CA); Loomis, Gary E. (Livermore, CA); Thomas, Ian M. (Livermore, CA)

    1999-01-01

    Variable index optical single-layers, optical multilayer, and laser-resistant coatings were made from a perfluorinated amorphous polymer material by physical vapor deposition. This was accomplished by physically vapor depositing a polymer material, such as bulk Teflon AF2400, for example, to form thin layers that have a very low refractive index (.about.1.10-1.31) and are highly transparent from the ultra-violet through the near infrared regime, and maintain the low refractive index of the bulk material. The refractive index can be varied by simply varying one process parameter, either the deposition rate or the substrate temperature. The thus forming coatings may be utilized in anti-reflectors and graded anti-reflection coatings, as well as in optical layers for laser-resistant coatings at optical wavelengths of less than about 2000 nm.

  10. A Nanotechnology-Based, Self-Healing, Chromate-Free Conversion Coating For

    Office of Science (SC) Website

    Magnesium Alloys | U.S. DOE Office of Science (SC) A Nanotechnology-Based, Self-Healing, Chromate-Free Conversion Coating For Magnesium Alloys Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) SBIR/STTR Home About Funding Opportunity Announcements (FOAs) Applicant and Awardee Resources Commercialization Assistance Other Resources Awards SBIR/STTR Highlights Reporting Fraud Contact Information Small Business Innovation Research and Small Business

  11. Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes Sunday, January 31, 2016 Improvements in the high-voltage cycling stability of lithium ion battery cathode materials are needed to enable the wide-spread adoption of renewable energy technologies such as electric vehicles. One cathode material which exhibits significant advantages over the commonly-used commercial material LiCoO2 in terms of higher capacity, increased thermal

  12. Issues for conversion coating of aluminum alloys with hydrotalcite

    SciTech Connect (OSTI)

    Drewien, C.A.; Buchheit, R.G.

    1993-12-01

    Hydrotalcite coatings on aluminum alloys are being developed for corrosion protection of aluminum in aggressive saline environments. Coating bath composition, surface pretreatment, and alloying elements in aluminum all influence the performance of these coatings during salt spray testing. The coating bath, comprised of lithium carbonate, requires aging by dissolution of aluminum into the bath in order to grow corrosion resistant coatings. Coatings formed in non- aged baths do not perform well in salt spray testing. The alloying elements in aluminum alloys, especially copper, influence the coating growth and formation leading to thin coatings. The effect of the alloy elements is to limit the supply of aluminum to the coating/electrolyte interface and hinder growth of hydrotalcite upon aluminum alloys.

  13. Superhydrophobic Surface Coatings for Microfluidics and MEMs.

    SciTech Connect (OSTI)

    Branson, Eric D.; Singh, Seema [Sandia National Laboratories, Livermore, CA] [Sandia National Laboratories, Livermore, CA; Houston, Jack E.; van Swol, Frank B.; Brinker, C. Jeffrey

    2006-11-01

    Low solid interfacial energy and fractally rough surface topography confer to Lotus plants superhydrophobic (SH) properties like high contact angles, rolling and bouncing of liquid droplets, and self-cleaning of particle contaminants. This project exploits the porous fractal structure of a novel, synthetic SH surface for aerosol collection, its self-cleaning properties for particle concentration, and its slippery nature 3 to enhance the performance of fluidic and MEMS devices. We propose to understand fundamentally the conditions needed to cause liquid droplets to roll rather than flow/slide on a surface and how this %22rolling transition%22 influences the boundary condition describing fluid flow in a pipe or micro-channel. Rolling of droplets is important for aerosol collection strategies because it allows trapped particles to be concentrated and transported in liquid droplets with no need for a pre-defined/micromachined fluidic architecture. The fluid/solid boundary condition is important because it governs flow resistance and rheology and establishes the fluid velocity profile. Although many research groups are exploring SH surfaces, our team is the first to unambiguously determine their effects on fluid flow and rheology. SH surfaces could impact all future SNL designs of collectors, fluidic devices, MEMS, and NEMS. Interfaced with inertial focusing aerosol collectors, SH surfaces would allow size-specific particle populations to be collected, concentrated, and transported to a fluidic interface without loss. In microfluidic systems, we expect to reduce the energy/power required to pump fluids and actuate MEMS. Plug-like (rather than parabolic) velocity profiles can greatly improve resolution of chip-based separations and enable unprecedented control of concentration profiles and residence times in fluidic-based micro-reactors. Patterned SH/hydrophilic channels could induce mixing in microchannels and enable development of microflow control elements. Acknowledgements This work was funded by Sandia National Laboratory's Laboratory Directed Research & Development program (LDRD). Some coating processes were conducted in the cleanroom facility located at the University of New Mexico's Center for High Technology Materials (CHTM). SEM images were performed at UNM's Center for Micro-Engineering on equipment funded by a NSF New Mexico EPSCoR grant. 4

  14. Platelet composite coatings for tin whisker mitigation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rohwer, Lauren E. S.; Martin, James E.

    2015-09-14

    In this study, reliable methods for tin whisker mitigation are needed for applications that utilize tin-plated commercial components. Tin can grow whiskers that can lead to electrical shorting, possibly causing critical systems to fail catastrophically. The mechanisms of tin whisker growth are unclear and this makes prediction of the lifetimes of critical components uncertain. The development of robust methods for tin whisker mitigation is currently the best approach to eliminating the risk of shorting. Current mitigation methods are based on unfilled polymer coatings that are not impenetrable to tin whiskers. In this paper we report tin whisker mitigation results formore » several filled polymer coatings. The whisker-penetration resistance of the coatings was evaluated at elevated temperature and high humidity and under temperature cycling conditions. The composite coatings comprised Ni and MgF2-coated Al/Ni/Al platelets in epoxy resin or silicone rubber. In addition to improved whisker mitigation, these platelet composites have enhanced thermal conductivity and dielectric constant compared with unfilled polymers.« less

  15. Insoluble coatings for Stirling engine heat pipe condenser surfaces. Final report

    SciTech Connect (OSTI)

    Dussinger, P.M.

    1993-09-01

    The work done by Thermacore, Inc., Lancaster, Pennsylvania, for the Phase 1, 1992 SBIR National Aeronautics and Space Administration Contract, Insoluble Coatings for Stirling Engine Heat Pipe Condenser Surfaces' is described. The work was performed between January 1992 and July 1992. Stirling heat engines are being developed for electrical power generation use on manned and unmanned earth orbital and planetary missions. Dish Stirling solar systems and nuclear reactor Stirling systems are two of the most promising applications of the Stirling engine electrical power generation technology. The sources of thermal energy used to drive the Stirling engine typically are non-uniform in temperature and heat flux. Liquid metal heat pipe receivers are used as thermal transformers and isothermalizers to deliver the thermal energy at a uniform high temperature to the heat input section of the Stirling engine. The use of a heat pipe receiver greatly enhances system efficiency and potential life span. One issue that is raised during the design phase of heat pipe receivers is the potential solubility corrosion of the Stirling engine heat input section by the liquid metal working fluid. This Phase 1 effort initiated a program to evaluate and demonstrate coatings, applied to nickel based Stirling engine heater head materials, that are practically 'insoluble' in sodium, potassium, and NaK. This program initiated a study of nickel aluminide as a coating and developed and demonstrated a heat pipe test vehicle that can be used to test candidate materials and coatings. Nickel 200 and nickel aluminide coated Nickel 200 were tested for 1000 hours at 800 C at a condensation heat flux of 25 W/sq cm. Subsequent analyses of the samples showed no visible sign of solubility corrosion of either coated or uncoated samples. The analysis technique, photomicrographs at 200X, has a resolution of better than 2.5 microns (.0001 in).

  16. Analysis of Wear Mechanisms in Low Friction, Nanocomposite AlMgB14-TiB2 Coatings

    SciTech Connect (OSTI)

    Cook, Bruce A; Harringa, J; Anderegg, A; Russell, A M; Qu, Jun; Blau, Peter Julian; Higdon, Clifton; Elmoursi, Alaa A

    2010-01-01

    Recent developments in coating science and technology offer new opportunities to enhance the energy-efficiency and performance of industrial machinery such as hydraulic fluid pumps and motors. The lubricated friction and wear characteristics of two wear-resistant coatings, diamond-like carbon and a nanocomposite material based on AlMgB{sub 14}-50 vol.% TiB{sub 2}, were compared in pin-on-disk tribotests using Mobil DTE-24{trademark} oil as the lubricant. In each case, the pins were fixed 9.53 mm diameter spheres of AISI 52100 steel, the load was 10 N, and the speed 0.5 m/s in all tests. Average steady-state friction coefficient values of 0.10 and 0.08 were measured for the DLC and nanocomposite, respectively. The coatings and their 52100 steel counterfaces were analyzed after the tests by X-ray photoelectron and Auger spectroscopy for evidence of material transfer or tribo-chemical reactions. The low-friction behavior of the boride nanocomposite coating is due to the formation of lubricative boric acid, B(OH){sub 3}. In contrast, the low-friction behavior of the DLC coating is related to the relatively low dielectric constant of the oil-based lubricant, leading to desorption of surface hydrogen from the coating.

  17. Plasma sprayed and electrospark deposited zirconium metal diffusion barrier coatings

    SciTech Connect (OSTI)

    Hollis, Kendall J; Pena, Maria I

    2010-01-01

    Zirconium metal coatings applied by plasma spraying and electrospark deposition (ESD) have been investigated for use as diffusion barrier coatings on low enrichment uranium fuel for research nuclear reactors. The coatings have been applied to both stainless steel as a surrogate and to simulated nuclear fuel uranium-molybdenum alloy substrates. Deposition parameter development accompanied by coating characterization has been performed. The structure of the plasma sprayed coating was shown to vary with transferred arc current during deposition. The structure of ESD coatings was shown to vary with the capacitance of the deposition equipment.

  18. EDC-37 Deflagration Rates at Elevated Pressures

    SciTech Connect (OSTI)

    Maienschein, J L; Koerner, J G

    2008-01-31

    We report deflagration rates on EDC-37 at high pressures. Experiments are conducted using the Lawrence Livermore National Laboratory High Pressure Strand Burner (HPSB) apparatus. The HPSB contains a deflagrating sample in a small volume, high pressure chamber. The sample consists of nine, 6.35 mm diameter, 6.35 mm length cylinders stacked on end, with burn wires placed between cylinders. Sample deflagration is limited to the cross-sectional surface of the cylinder by coating the cylindrical surface of the tower with Halthane 88-2 epoxy. Sample deflagration is initiated on one end of the tower by a B/KNO{sub 3} and HNS igniter train. Simultaneous temporal pressure history and burn front time of arrival measurements yield the laminar deflagration rate for a range of pressures and provide insight into deflagration uniformity. These measurements are one indicator of overall thermal explosion violence. Specific details of the experiment and the apparatus can be found in the literature.

  19. Effects of post-LOCA conditions on a protective coating (paint) for the Nuclear Power Industry

    SciTech Connect (OSTI)

    Loyola, V.M.; Womelsduff, J.E.

    1985-03-01

    When corrosion protection of steel cannot be achieved by galvanizing due to size, use, or other restrictions, the steel is frequently protected by the application of a suitable corrosion-inhibiting paint. A widely accepted corrosion inhibiting coating is one in which finely powdered zinc metal is dispersed in an organic polymer matrix and applied to steel as a paint. This system is often used with a non-zinc bearing topcoat for enhanced protection. We have studied the oxidation of zinc in a zinc-rich coating used in the nuclear power industry and have measured the rates of hydrogen generation from these coatings due to zinc oxidation at temperatures of up to 175/sup 0/C. The results suggest that the real-time rates of hydrogen generation are considerably higher than previously believed. A second concern involves the generation of debris or solid reaction products which could cause plugging or fouling of the recirculation pumps, spray nozzles, and/or heat exchangers. Coatings are observed to fail at post-LOCA conditions which are well within the limits predicted by Design Basis Accident analysis. The failures involve cracking and/or delamination of the topcoat and production of solid corrosion products involving the zinc-rich primer. 22 refs., 10 figs., 6 tabs.

  20. Polymeric complexes of polyaniline as anticorrosion coatings

    SciTech Connect (OSTI)

    Racicot, R.J.; Yang, S.C.; Brown, R.

    1998-07-01

    During the past few years there has been a strong interest in developing conducting polymers as an alternative to the traditional anticorrosion coatings. One of the driving forces for this research comes from the need for an environmentally friendly chromate-free anticorrosion coating for high-strength light weight aluminum alloys. The possibilities for a new scratch-tolerant paint for steel prompted the development of conductive polymer anticorrosion paints. By molecular engineering, the authors have synthesized a double-strand polymeric complex of polyaniline that is suitable as an anticorrosion paint on metals in low pH environments. In this article, the authors will discuss (1) the molecular design for solubility and adhesion, (2) the effectiveness of the electroactive coating under electrochemical impedance tests, and (3) a mechanistic study of the anticorrosion mechanism by examining the polymer/metal interfacial interactions.

  1. Metallic and nonmetallic coatings for ICF targets

    SciTech Connect (OSTI)

    Hendricks, C.D.; Crane, J.K.; Hsieh, E.J.; Meyer, S.F.

    1981-04-17

    Some fusion targets designed to be driven by 0.35 to 1 ..mu..m laser light are glass spheres coated with layers of various materials such as hydrocarbons, fluorocarbons, beryllium, copper, gold, platinum, etc. The glass shell, which is filled with gas, liquid or solid deuterium-tritium fuel, must have remarkably good surface and wall thickness uniformity. Methods for depositing the various materials will be discussed. They include plasma polymerization, electro-deposition, sputtering and evaporation. Many of the difficulties encountered in the coating processes are the result of coating on free spheres with very small radii - 35 to 500 micrometers. Several means of overcoming the problems will be described and experimental results presented.

  2. Figure correction of multilayer coated optics

    DOE Patents [OSTI]

    Chapman; Henry N. (Livermore, CA), Taylor; John S. (Livermore, CA)

    2010-02-16

    A process is provided for producing near-perfect optical surfaces, for EUV and soft-x-ray optics. The method involves polishing or otherwise figuring the multilayer coating that has been deposited on an optical substrate, in order to correct for errors in the figure of the substrate and coating. A method such as ion-beam milling is used to remove material from the multilayer coating by an amount that varies in a specified way across the substrate. The phase of the EUV light that is reflected from the multilayer will be affected by the amount of multilayer material removed, but this effect will be reduced by a factor of 1-n as compared with height variations of the substrate, where n is the average refractive index of the multilayer.

  3. Method of fabricating boron containing coatings

    DOE Patents [OSTI]

    Makowiecki, D.M.; Jankowski, A.F.

    1999-04-27

    Hard coatings are fabricated from boron nitride, cubic boron nitride, and multilayer boron/cubic boron nitride, and the fabrication thereof involves magnetron sputtering in a selected atmosphere. These hard coatings may be applied to tools and engine and other parts, as well to reduce wear on tribological surfaces and electronic devices. These boron coatings contain no morphological growth features. For example, the boron is formed in an inert (e.g. argon) atmosphere, while the cubic boron nitride is formed in a reactive (e.g. nitrogen) atmosphere. The multilayer boron/cubic boron nitride, is produced by depositing alternate layers of boron and cubic boron nitride, with the alternate layers having a thickness of 1 nanometer to 1 micrometer, and at least the interfaces of the layers may be discrete or of a blended or graded composition. 3 figs.

  4. Method of fabricating boron containing coatings

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Jankowski, Alan F. (Livermore, CA)

    1999-01-01

    Hard coatings are fabricated from boron nitride, cubic boron nitride, and multilayer boron/cubic boron nitride, and the fabrication thereof involves magnetron sputtering in a selected atmosphere. These hard coatings may be applied to tools and engine and other parts, as well to reduce wear on tribological surfaces and electronic devices. These boron coatings contain no morphological growth features. For example, the boron is formed in an inert (e.g. argon) atmosphere, while the cubic boron nitride is formed in a reactive (e.g. nitrogen) atmosphere. The multilayer boron/cubic boron nitride, is produced by depositing alternate layers of boron and cubic boron nitride, with the alternate layers having a thickness of 1 nanometer to 1 micrometer, and at least the interfaces of the layers may be discrete or of a blended or graded composition.

  5. Multilayer ultra-high-temperature ceramic coatings

    DOE Patents [OSTI]

    Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

    2012-03-20

    A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

  6. Glass/ceramic coatings for implants

    DOE Patents [OSTI]

    Tomsia, Antoni P. (Pinole, CA); Saiz, Eduardo (Berkeley, CA); Gomez-Vega, Jose M. (Nagoya, JP); Marshall, Sally J. (Larkspur, CA); Marshall, Grayson W. (Larkspur, CA)

    2011-09-06

    Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

  7. Passivation coating for flexible substrate mirrors

    DOE Patents [OSTI]

    Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

    1990-01-01

    A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate before metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors. Also, the silver or other reflective metal layer on mirrors comprising thin, lightweight, flexible substrates of metal or polymer sheets coated with glassy layers can be protected with silicon nitride according to this invention.

  8. Photovoltaic Degradation Rates -- An Analytical Review

    SciTech Connect (OSTI)

    Jordan, D. C.; Kurtz, S. R.

    2012-06-01

    As photovoltaic penetration of the power grid increases, accurate predictions of return on investment require accurate prediction of decreased power output over time. Degradation rates must be known in order to predict power delivery. This article reviews degradation rates of flat-plate terrestrial modules and systems reported in published literature from field testing throughout the last 40 years. Nearly 2000 degradation rates, measured on individual modules or entire systems, have been assembled from the literature, showing a median value of 0.5%/year. The review consists of three parts: a brief historical outline, an analytical summary of degradation rates, and a detailed bibliography partitioned by technology.

  9. Technology Roadmap Analysis 2013: Assessing Automotive Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Roadmap Analysis 2013: Assessing Automotive Technology R&D Relevant to DOE Power Electronics Cost Targets Technology Roadmap Analysis 2013: Assessing Automotive Technology R&D ...

  10. National Energy Technology Laboratory Technology Marketing Summaries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Energy Technology Laboratory Technology Marketing Summaries Here you'll find marketing summaries for technologies available for licensing from the National Energy...

  11. Financial Institution Partnership Program - Commercial Technology Renewable

    Office of Environmental Management (EM)

    Energy Generation Projects Issued: October 7, 2009 | Department of Energy Financial Institution Partnership Program - Commercial Technology Renewable Energy Generation Projects Issued: October 7, 2009 Financial Institution Partnership Program - Commercial Technology Renewable Energy Generation Projects Issued: October 7, 2009 PDF icon Financial Institution Partnership Program - Commercial Technology Renewable Energy Generation Projects Issued: October 7, 2009 PDF icon Fixed Rate Agreement

  12. Production of porous coating on a prosthesis

    DOE Patents [OSTI]

    Sump, Kenneth R. (Richland, WA)

    1987-01-01

    Preselected surface areas of a prosthesis are covered by a blend of matching primary metallic particles and expendable particles. The particles are compressed and heated to assure that deformation and metallurgical bonding occurs between them and between the primary particles and the surface boundaries of the prosthesis. Porosity is achieved by removal of the expendable material. The result is a coating including discrete bonded particles separated by a network of interconnected voids presenting a homogeneous porous coating about the substrate. It has strength suitable for bone implant usage without intermediate adhesives, and adequate porosity to promote subsequent bone ingrowth.

  13. ALLOY COATINGS AND METHOD OF APPLYING

    DOE Patents [OSTI]

    Eubank, L.D.; Boller, E.R.

    1958-08-26

    A method for providing uranium articles with a pro tective coating by a single dip coating process is presented. The uranium article is dipped into a molten zinc bath containing a small percentage of aluminum. The resultant product is a uranium article covered with a thin undercoat consisting of a uranium-aluminum alloy with a small amount of zinc, and an outer layer consisting of zinc and aluminum. The article may be used as is, or aluminum sheathing may then be bonded to the aluminum zinc outer layer.

  14. Monolayer coated aerogels and method of making

    DOE Patents [OSTI]

    Zemanian, Thomas Samuel (Richland, WA); Fryxell, Glen (Kennwick, WA); Ustyugov, Oleksiy A. (Spokane, WA)

    2006-03-28

    Aerogels having a monolayer coating are described. The aerogel and a monolayer forming precursor are provided in a supercritical fluid, whereupon the aerogel and the monolayer forming precursor are reacted in said supercritical fluid to form a covalent bond between the aerogel and the monolayer forming precursor. Suitable aerogels are ceramic oxides such as silica, alumina, aluminosilicate, and combinations thereof. Suitable monolayer forming precursors include alkyl silanes, chlorosilanes, boranes, chloroboranes, germanes, and combinations thereof. The method may also include providing a surface preparation agent such as water, or hydroetching an aerogel to enhance the coating of the monolayer.

  15. Coating Surfaces with Superhydrophobic Powder - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Startup America Industrial Technologies Industrial Technologies Hydropower, Wave and Tidal Hydropower, Wave and Tidal Advanced Materials Advanced Materials Find More Like This...

  16. Superoleophilic Particles and Coatings - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Startup America Industrial Technologies Industrial Technologies Hydropower, Wave and Tidal Hydropower, Wave and Tidal Advanced Materials Advanced Materials Find More Like This...

  17. Three NETL-Developed Technologies Recognized by R&D Magazine as Among 100

    Broader source: Energy.gov (indexed) [DOE]

    Most Significant in Past Year | Department of Energy Three technologies developed by the Department of Energy's (DOE) National Energy Technology Laboratory (NETL) have been recognized by R&D Magazine as among the 100 most technologically significant products to enter the marketplace in the past year. The technologies chosen to receive the prestigious 2011 R&D 100 Awards include a software toolkit for designing next-generation power plants, a coating for interconnects in solid oxide

  18. Iron-Based Amorphous Coatings Produced by HVOF Thermal Spray Processing-Coating Structure and Properties

    SciTech Connect (OSTI)

    Beardsley, M B

    2008-03-26

    The feasibility to coat large SNF/HLW containers with a structurally amorphous material (SAM) was demonstrated on sub-scale models fabricated from Type 316L stainless steel. The sub-scale model were coated with SAM 1651 material using kerosene high velocity oxygen fuel (HVOF) torch to thicknesses ranging from 1 mm to 2 mm. The process parameters such as standoff distance, oxygen flow, and kerosene flow, were optimized in order to improve the corrosion properties of the coatings. Testing in an electrochemical cell and long-term exposure to a salt spray environment were used to guide the selection of process parameters.

  19. Method of applying coatings to substrates and the novel coatings produced thereby

    DOE Patents [OSTI]

    Hendricks, C.D.

    1987-09-15

    A method for applying novel coatings to substrates is provided. The ends of a multiplicity of rods of different materials are melted by focused beams of laser light. Individual electric fields are applied to each of the molten rod ends, thereby ejecting charged particles that include droplets, atomic clusters, molecules, and atoms. The charged particles are separately transported, by the accelerations provided by electric potentials produced by an electrode structure, to substrates where they combine and form the coatings. Layered and thickness graded coatings comprised of hitherto unavailable compositions, are provided. 2 figs.

  20. Manufacturing technologies

    SciTech Connect (OSTI)

    1995-09-01

    The Manufacturing Technologies Center is an integral part of Sandia National Laboratories, a multiprogram engineering and science laboratory, operated for the Department of Energy (DOE) with major facilities at Albuquerque, New Mexico, and Livermore, California. Our Center is at the core of Sandia`s Advanced Manufacturing effort which spans the entire product realization process.

  1. Plasma technology

    SciTech Connect (OSTI)

    Herlitz, H.G.

    1986-11-01

    This paper describes the uses of plasma technology for the thermal destruction of hazardous wastes such as PCBs, dioxins, hydrocarbons, military chemicals and biological materials; for metals recovery from steel making dusts. One advantage of the process is that destruction of wastes can be carried out on site. Systems in several countries use the excess thermal energy for district heating.

  2. (Environmental technology)

    SciTech Connect (OSTI)

    Boston, H.L.

    1990-10-12

    The traveler participated in a conference on environmental technology in Paris, sponsored by the US Embassy-Paris, US Environmental Protection Agency (EPA), the French Environmental Ministry, and others. The traveler sat on a panel for environmental aspects of energy technology and made a presentation on the potential contributions of Oak Ridge National Laboratory (ORNL) to a planned French-American Environmental Technologies Institute in Chattanooga, Tennessee, and Evry, France. This institute would provide opportunities for international cooperation on environmental issues and technology transfer related to environmental protection, monitoring, and restoration at US Department of Energy (DOE) facilities. The traveler also attended the Fourth International Conference on Environmental Contamination in Barcelona. Conference topics included environmental chemistry, land disposal of wastes, treatment of toxic wastes, micropollutants, trace organics, artificial radionuclides in the environment, and the use biomonitoring and biosystems for environmental assessment. The traveler presented a paper on The Fate of Radionuclides in Sewage Sludge Applied to Land.'' Those findings corresponded well with results from studies addressing the fate of fallout radionuclides from the Chernobyl nuclear accident. There was an exchange of new information on a number of topics of interest to DOE waste management and environmental restoration needs.

  3. Terra Sigillata: Evolution of Roman Ceramics Reflect Changes in Technology,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Life Terra Sigillata: Evolution of Roman Ceramics Reflect Changes in Technology, Life Terra Sigillata: Evolution of Roman Ceramics Reflect Changes in Technology, Life Print Wednesday, 18 March 2015 15:38 Terra sigillata ceramics were the most famous ancient tableware produced during the Roman period owing to the mass production of standardized shapes and the widespread distribution of the vessels. The beautiful ceramics were characterized by their reddish coloration, glossy coating, and the

  4. TRISO-Coated Fuel Processing to Support High Temperature Gas-Cooled Reactors

    SciTech Connect (OSTI)

    Del Cul, G.D.

    2002-10-01

    The initial objective of the work described herein was to identify potential methods and technologies needed to disassemble and dissolve graphite-encapsulated, ceramic-coated gas-cooled-reactor spent fuels so that the oxide fuel components can be separated by means of chemical processing. The purpose of this processing is to recover (1) unburned fuel for recycle, (2) long-lived actinides and fission products for transmutation, and (3) other fission products for disposal in acceptable waste forms. Follow-on objectives were to identify and select the most promising candidate flow sheets for experimental evaluation and demonstration and to address the needs to reduce technical risks of the selected technologies. High-temperature gas-cooled reactors (HTGRs) may be deployed in the next -20 years to (1) enable the use of highly efficient gas turbines for producing electricity and (2) provide high-temperature process heat for use in chemical processes, such as the production of hydrogen for use as clean-burning transportation fuel. Also, HTGR fuels are capable of significantly higher burn-up than light-water-reactor (LWR) fuels or fast-reactor (FR) fuels; thus, the HTGR fuels can be used efficiently for transmutation of fissile materials and long-lived actinides and fission products, thereby reducing the inventory of such hazardous and proliferation-prone materials. The ''deep-burn'' concept, described in this report, is an example of this capability. Processing of spent graphite-encapsulated, ceramic-coated fuels presents challenges different from those of processing spent LWR fuels. LWR fuels are processed commercially in Europe and Japan; however, similar infrastructure is not available for processing of the HTGR fuels. Laboratory studies on the processing of HTGR fuels were performed in the United States in the 1960s and 1970s, but no engineering-scale processes were demonstrated. Currently, new regulations concerning emissions will impact the technologies used in processing the fuel. Potential processing methods will be identified both by a review of the literature regarding the processing of similar fuels and by a reliance on the experience and innovation of the authors. The objective is not to generate an exhaustive list of options but rather to identify a number of potentially practical processing options. These options necessarily take into consideration the chemical characteristics of the entire fuel element and its component parts. Once the practical options are identified, a qualitative assessment of the technical merit and maturity, relative costs, and relative quantity of waste generation will be used to rank the various options. Through this form of analysis, a base-case flow sheet will be identified for further study and development. A fallback flow sheet will also be selected to reduce the overall technical risk of the development plan. To support the base-case flow sheet, a technical development plan will be used to identify the key issues for the highest-rated option(s). In this effort the technical uncertainties will be more fully articulated, and research and development activities will be recommended to reduce the technical risks.

  5. OXIDATION-RESISTANT INTERFACIAL COATINGS FOR CONTINUOUS FIBER...

    Office of Scientific and Technical Information (OSTI)

    to deposit mullite coatings on Nicalon fabrics using a sol-gel route. Conclusions FEM analysis revealed that a low modulus interfacial coating will be effective in reducing radial...

  6. MOF Coating a Promising Path to White LEDs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MOF Coating a Promising Path to White LEDs MOF Coating a Promising Path to White LEDs Print Friday, 27 February 2015 17:11 Hu et al. designed a new yellow phosphor with high...

  7. Hydrogen permeable protective coating for a catalytic surface

    DOE Patents [OSTI]

    Liu, Ping (Irvine, CA); Tracy, C. Edwin (Golen, CO); Pitts, J. Roland (Lakewood, CO); Lee, Se-Hee (Lakewood, CO)

    2007-06-19

    A protective coating for a surface comprising a layer permeable to hydrogen, said coating being deposited on a catalyst layer; wherein the catalytic activity of the catalyst layer is preserved.

  8. Apparatus for coating and impregnating filament with resin

    DOE Patents [OSTI]

    Robinson, S.C.; Pollard, R.E.

    1986-12-17

    The present invention is directed to an apparatus for evenly coating and impregnating a filament with binder material. Dimension control and repeatability of the coating and impregnating characteristics are obtained with the apparatus.

  9. The possibility of forming a sacrificial anode coating for Mg

    SciTech Connect (OSTI)

    Dudney, Nancy J; Li, Juchuan; Sacci, Robert L; Thomson, Jeffery K

    2014-01-01

    Mg is the most active engineering metal, and is often used as a sacrificial anode/coating to protect other engineering metals from corrosion attack. So far no sacrificial anode coating has been developed or considered for Mg. This study explores the possibility of forming a sacrificial coating for Mg. A lithiated carbon coating and a metaphosphated coating are applied on the Mg surface, respectively, and their open-circuit-potentials are measured in saturated Mg(OH)2 solution. They exhibit more negative potentials than bare Mg. SEM reveals that the metaphosphated coating offers more effective and uniform protection for Mg than the lithiated carbon coating. These preliminary results indicate that development of a sacrificial anode coating for Mg is indeed possible.

  10. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    SciTech Connect (OSTI)

    Mackiewicz-Ludtka, G.; Sebright, J.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for transitioning of the arc lamp processing to the industrial Participant.

  11. Max Phase Materials And Coatings For High Temperature Heat Transfer Applications

    SciTech Connect (OSTI)

    Martinez-Rodriguez, M.; Garcia-Diaz, B.; Olson, L.; Fuentes, R.; Sindelar, R.

    2015-10-19

    Molten salts have been used as heat transfer fluids in a variety of applications within proposed Gen IV nuclear designs and in advanced power system such as Concentrating Solar Power (CSP). However, operating at elevated temperatures can cause corrosion in many materials. This work developed coating technologies for MAX phase materials on Haynes-230 and characterized the corrosion of the coatings in the presence of commercial MgCl2-KCl molten salt. Cold spraying of Ti2AlC and physical vapor deposition (PVD) of Ti2AlC or Zr2AlC were tested to determine the most effective form of coating MAX phases on structural substrates. Corrosion testing at 850C for 100 hrs showed that 3.9 ?m Ti2AlC by PVD was slightly protective while 117 ?m Ti2AlC by cold spray and 3.6 ?m Zr2AlC by PVD were completely protective. None of the tests showed decomposition of the coating (Ti or Zr) into the salt

  12. A Novel Low-Temperature Fiffusion Aluminide Coating for Ultrasupercritical Coal-Fried Boiler Applications

    SciTech Connect (OSTI)

    Zhang, Ying

    2009-12-31

    An ultrasupercritical (USC) boiler with higher steam temperature and pressure is expected to increase the efficiency of the coal-fired power plant and also decrease emissions of air pollutants. Ferritic/martensitic alloys have been developed with good creep strength for the key components in coal-fired USC plants. However, they typically suffer excessive steam-side oxidation, which contributes to one of main degradation mechanisms along with the fire-side corrosion in coal-fired boilers. As the steam temperature further increases in USC boilers, oxidation of the tube internals becomes an increasing concern, and protective coatings such as aluminide-based diffusion coatings need to be considered. However, conventional aluminizing processes via pack cementation or chemical vapor deposition are typically carried out at elevated temperatures (1000-1150 C). Thermochemical treatment of ferritic/martensitic alloys at such high temperatures could severely degrade their mechanical properties, particularly the alloy's creep resistance. The research focus of this project was to develop an aluminide coating with good oxidation resistance at temperatures {le} 700 C so that the coating processing would not detrimentally alter the creep performance of the ferritic/martensitic alloys. Nevertheless, when the aluminizing temperature is lowered, brittle Al-rich intermetallic phases, such as Fe{sub 2}Al{sub 5} and FeAl{sub 3}, tend to form in the coating, which may reduce the resistance to fatigue cracking. Al-containing binary masteralloys were selected based on thermodynamic calculations to reduce the Al activity in the pack cementation process and thus to prevent the formation of brittle Al-rich intermetallic phases. Thermodynamic computations were carried out using commercial software HSC 5.0 for a series of packs containing various Cr-Al binary masteralloys. The calculation results indicate that the equilibrium partial pressures of Al halides at 700 C were a function of Al content in the Cr-Al alloys. Cr-25Al and Cr-15Al were chosen as the masteralloys in the pack cementation process. In contrast to pure Al masteralloy which led to the formation of Fe{sub 2}Al{sub 5} coatings at 650 C, a coating consisting of a thin Fe{sub 2}Al{sub 5} outer layer and an FeAl inner layer was formed at 700 C with the Cr-25Al masteralloy. By switching to the Cr-15Al masteralloy, thin FeAl coatings ({approx}12 {micro}m) containing < 50 at.% Al were achieved at 700 C. The effect of the amount of masteralloys on coating growth was also studied by employing packs containing 2NH{sub 4}Cl-x(Cr-15Al)-(98-x)Al{sub 2}O{sub 3}, where x = 10, 20, 30, 40, 50, 60, and 70 wt.%. It was noticed that when the Cr-15Al masteralloy was increased from 10 to 40 wt.% in the pack, both coating thickness and surface Al content increased, suggesting that gas phase kinetics played an important role in Al deposition. However, with further increase of the masteralloy, solid state diffusion became the rate-limiting factor. The long-term oxidation performance of the aluminide coatings synthesized at 700 C with Cr-25Al and Cr-15Al masteralloys was evaluated in the water vapor environment at 650-700 C. The low-temperature pack coatings demonstrated excellent oxidation resistance at 650 C in humid air after {approx}1.2 yr testing. Longer lifetimes can be expected for these thin coatings due to minimal interdiffusion at this testing temperature. Exposure at 700 C was conducted to accelerate coating failure via increased interdiffusion of Al with the substrate alloy. The coatings also exhibited good oxidation protection up to 6,000-8,000 h at 700 C, with longer testing needed for coating failure to occur. Furthermore, the oxidation results indicate that in addition to the Al reservoir (as determined by the Al content and coating thickness), the initial coating surface quality had a significant impact on the oxidation behavior. In addition, the effect of various pack aluminide coatings on the creep resistance of coated T91 was investigated. Three representative types of coatings with diff

  13. Dynamic Line Rating: Research and Policy Evaluation

    SciTech Connect (OSTI)

    Jake P. Gentle; Kurt S. Myers; Michael R. West

    2014-07-01

    Dynamic Line Rating (DLR) is a smart grid technology that allows the rating of electrical conductors to be increased based on local weather conditions. Overhead lines are conventionally given a conservative rating based on worst case scenarios. We demonstrate that observing the conditions in real time leads to additional capacity and safer operation. This paper provides a report of a pioneering scheme in the United States of America in which DLR has been applied. Thereby, we demonstrate that observing the local weather conditions in real time leads to additional capacity and safer operation. Secondly, we discuss limitations involved. In doing so, we arrive at novel insights which will inform and improve future DLR projects. Third, we provide a policy background and discussion to clarify the technology’s potential and identifies barriers to the imminent adoption of dynamic line rating systems. We provide suggestions for regulatory bodies about possible improvements in policy to encourage adoption of this beneficial technology.

  14. Lithium battery electrodes with ultra-thin alumina coatings

    DOE Patents [OSTI]

    Se-Hee, Lee; George, Steven M.; Cavanagh, Andrew S.; Yoon Seok, Jung; Dillon, Anne C.

    2015-11-24

    Electrodes for lithium batteries are coated via an atomic layer deposition process. The coatings can be applied to the assembled electrodes, or in some cases to particles of electrode material prior to assembling the particles into an electrode. The coatings can be as thin as 2 .ANG.ngstroms thick. The coating provides for a stable electrode. Batteries containing the electrodes tend to exhibit high cycling capacities.

  15. Project Profile: Cleanable and Hardcoat Coatings for Increased Durability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Silvered Polymeric Mirrors | Department of Energy Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors Project Profile: Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors 3M logo 3M, under the CSP R&D FOA, is developing optical coatings for solar mirrors that are durable, easily maintained, and more cost-effective. Approach Diagram of the most successful coatings identified by the research team based on the mix of

  16. Dynamically Responsive Infrared Window Coatings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dynamically Responsive Infrared Window Coatings Dynamically Responsive Infrared Window Coatings Addthis 1 of 5 An oxygen plasma etcher is used to clean test substrates for window coatings. Image: Pacific Northwest National Laboratory 2 of 5 PNNL scientist Dr. Kyle Alvine checks on the progress of the plasma etch. Image: Pacific Northwest National Laboratory 3 of 5 PNNL scientist begins fabrication of a prototype window coating. Image: Pacific Northwest National Laboratory 4 of 5 Solution is

  17. Cube-corner reflectors with interference dielectric coating

    SciTech Connect (OSTI)

    Sokolov, A L; Murashkin, V V; Akent'ev, A S; Karaseva, E A

    2013-09-30

    The cube-corner reflectors (CCRs) with a special interference dielectric coating intended for ring retroreflector systems of space vehicles with uniaxial orientation are considered. The diffraction patterns of radiation reflected from the CCRs with different face coatings are studied. It is shown that the choice of the angle between the faces, the size and the coating of CCR faces allow essential variation in the diffraction pattern, thereby providing its optimisation for solving different navigation problems. (nanogradient dielectric coatings and metamaterials)

  18. Vehicle Technologies Office: Graduate Automotive Technology Education

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (GATE) | Department of Energy Education & Workforce Development » Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) DOE established the Graduate Automotive Technology Education (GATE) Centers of Excellence to provide future generations of engineers and scientists with knowledge and skills in advanced automotive technologies. By funding curriculum development and expansion as well as

  19. Enhancement of oxidation resistance of graphite foams by polymer derived-silicon carbide coating for concentrated solar power applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, T.; Singh, D.; Singh, M.

    2015-05-01

    Graphite foam with extremely high thermal conductivity has been investigated to enhance heat transfer of latent heat thermal energy storage (LHTES) systems. However, the use of graphite foam for elevated temperature applications (>600 °C) is limited due to poor oxidation resistance of graphite. In the present study, oxidation resistance of graphite foam coated with silicon carbide (SiC) was investigated. A pre-ceramic polymer derived coating (PDC) method was used to form a SiC coating on the graphite foams. Post coating deposition, the samples were analyzed by scanning electron microscopy and energy dispersive spectroscopy. The oxidation resistance of PDC-SiC coating was quantifiedmore » by measuring the weight of the samples at several measuring points. The experiments were conducted under static argon atmosphere in a furnace. After the experiments, oxidation rates (%/hour) were calculated to predict the lifetime of the graphite foams. The experimental results showed that the PDC-SiC coating could prevent the oxidation of graphite foam under static argon atmosphere up to 900 °C.« less

  20. Enhancement of oxidation resistance of graphite foams by polymer derived-silicon carbide coating for concentrated solar power applications

    SciTech Connect (OSTI)

    Kim, T.; Singh, D.; Singh, M.

    2015-05-01

    Graphite foam with extremely high thermal conductivity has been investigated to enhance heat transfer of latent heat thermal energy storage (LHTES) systems. However, the use of graphite foam for elevated temperature applications (>600 C) is limited due to poor oxidation resistance of graphite. In the present study, oxidation resistance of graphite foam coated with silicon carbide (SiC) was investigated. A pre-ceramic polymer derived coating (PDC) method was used to form a SiC coating on the graphite foams. Post coating deposition, the samples were analyzed by scanning electron microscopy and energy dispersive spectroscopy. The oxidation resistance of PDC-SiC coating was quantified by measuring the weight of the samples at several measuring points. The experiments were conducted under static argon atmosphere in a furnace. After the experiments, oxidation rates (%/hour) were calculated to predict the lifetime of the graphite foams. The experimental results showed that the PDC-SiC coating could prevent the oxidation of graphite foam under static argon atmosphere up to 900 C.

  1. In situ monitoring of structure formation in the active layer of polymer solar cells during roll-to-roll coating

    SciTech Connect (OSTI)

    Rossander, Lea H.; Zawacka, Natalia K.; Dam, Henrik F.; Krebs, Frederik C.; Andreasen, Jens W.

    2014-08-15

    The active layer crystallization during roll-to-roll coating of organic solar cells is studied in situ. We developed an X-ray setup where the coater unit is an integrated part of the small angle X-ray scattering instrument, making it possible to control the coating process while recording scattering measurements in situ, enabling us to follow the crystal formation during drying. By varying the distance between the coating head and the point where the X-ray beam hits the film, we obtained measurements of 4 different stages of drying. For each of those stages, the scattering from as long a foil as possible is summed together, with the distance from coating head to scattering point kept constant. The results are average crystallographic properties for the active layer coated on a 30 m long foil. With this insight into the dynamics of crystallization in a roll-coated polymer film, we find that the formation of textured and untextured crystallites seems uncorrelated, and happens at widely different rates. Untextured P3HT crystallites form later in the drying process than expected which may explain previous studies speculating that untextured crystallization depends on concentration. Textured crystallites, however, begin forming much earlier and steadily increases as the film dries, showing a development similar to other in situ studies of these materials.

  2. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, G.C.; Brinker, C.J.; Doughty, D.H.; Bein, T.; Moller, K.

    1996-12-31

    Coatings and sensors are disclosed having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided. 7 figs.

  3. Organosiloxane-grafted natural polymer coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    1998-01-01

    A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation.

  4. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, G.C.; Brinker, C.J.; Doughty, D.H.; Bein, T.; Moller, K.

    1993-07-06

    Coatings and sensors are described having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided.

  5. Biocatalytic material comprising multilayer enzyme coated fiber

    DOE Patents [OSTI]

    Kim, Jungbae [Richland, WA; Kwak, Ja Hun [Richland, WA; Grate, Jay W [West Richland, WA

    2009-11-03

    The present invention relates generally to high stability, high activity biocatalytic materials and processes for using the same. The materials comprise enzyme aggregate coatings having high biocatalytic activity and stability useful in heterogeneous environment. These new materials provide a new biocatalytic immobilized enzyme system with applications in bioconversion, bioremediation, biosensors, and biofuel cells.

  6. Fiber metal interlayer improves ceramic coating performance

    SciTech Connect (OSTI)

    Jarrabet, G.P.

    1994-11-01

    This article is a review of the use of a compliant fiber metal inner layer between a ceramic coating and metal. The material used is Zirconia with phase stabilizers of magnesium oxide, calcium oxide, and yttrium oxide. Design, fabrication, and testing of the stabilized zirconia is discussed.

  7. Surface coating for prevention of crust formation

    DOE Patents [OSTI]

    Kronberg, James W. (Aiken, SC)

    1994-01-01

    A flexible surface coating which promotes the removal of deposits as they reach the surface by preventing adhesion and crust formation. Flexible layers are attached to each side of a flexible mesh substrate comprising of a plurality of zones composed of one or more neighboring cells, each zone having a different compressibility than its adjacent zones. The substrate is composed of a mesh made of strands and open cells. The cells may be filled with foam. Studs or bearings may also be positioned in the cells to increase the variation in compressibility and thus the degree of flexing of the coating. Surface loading produces varying amounts of compression from point to point causing the coating to flex as deposits reach it, breaking up any hardening deposits before a continuous crust forms. Preferably one or more additional layers are also used, such as an outer layer of a non-stick material such as TEFLON, which may be pigmented, and an inner, adhesive layer to facilitate applying the coating to a surface.

  8. Polyorganometallosiloxane-2- or -4-pyridine coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    1997-01-01

    A new family of polyorganometallosiloxane-2- or -4-pyridine compounds are provided for corrosion resistant coatings on light metals such as aluminum, magnesium, zinc, steel and their allows. The novel compounds contain backbones modified by metal alkoxides, metallocenes and metallophthalocyanates where the metal is Zr, Ti, Mo, V, Hf, Nb, Si, B and combinations thereof. Methods of making the new compounds are also provided.

  9. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, R.G.; Martinez, M.A.

    1998-05-26

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides is disclosed. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds. 1 fig.

  10. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, Rudolph G. (Albuquerque, NM); Martinez, Michael A. (Albuquerque, NM)

    1998-01-01

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds.

  11. Coated semiconductor devices for neutron detection

    DOE Patents [OSTI]

    Klann, Raymond T. (Bolingbrook, IL); McGregor, Douglas S. (Whitmore Lake, MI)

    2002-01-01

    A device for detecting neutrons includes a semi-insulated bulk semiconductor substrate having opposed polished surfaces. A blocking Schottky contact comprised of a series of metals such as Ti, Pt, Au, Ge, Pd, and Ni is formed on a first polished surface of the semiconductor substrate, while a low resistivity ("ohmic") contact comprised of metals such as Au, Ge, and Ni is formed on a second, opposed polished surface of the substrate. In one embodiment, n-type low resistivity pinout contacts comprised of an Au/Ge based eutectic alloy or multi-layered Pd/Ge/Ti/Au are also formed on the opposed polished surfaces and in contact with the Schottky and ohmic contacts. Disposed on the Schottky contact is a neutron reactive film, or coating, for detecting neutrons. The coating is comprised of a hydrogen rich polymer, such as a polyolefin or paraffin; lithium or lithium fluoride; or a heavy metal fissionable material. By varying the coating thickness and electrical settings, neutrons at specific energies can be detected. The coated neutron detector is capable of performing real-time neutron radiography in high gamma fields, digital fast neutron radiography, fissile material identification, and basic neutron detection particularly in high radiation fields.

  12. Oxidation resistant nanocrystalline MCrAl(Y) coatings and methods of forming such coatings

    DOE Patents [OSTI]

    Cheruvu, Narayana S.; Wei, Ronghua

    2014-07-29

    The present disclosure relates to an oxidation resistant nanocrystalline coating and a method of forming an oxidation resistant nanocrystalline coating. An oxidation resistant coating comprising an MCrAl(Y) alloy may be deposited on a substrate, wherein M, includes iron, nickel, cobalt, or combinations thereof present greater than 50 wt % of the MCrAl(Y) alloy, chromium is present in the range of 15 wt % to 30 wt % of the MCrAl(Y) alloy, aluminum is present in the range of 6 wt % to 12 wt % of the MCrAl(Y) alloy and yttrium, is optionally present in the range of 0.1 wt % to 0.5 wt % of the MCrAl(Y) alloy. In addition, the coating may exhibit a grain size of 200 nm or less as deposited.

  13. Investigation of damage behavior of thermally sprayed coatings depending on coating thickness

    SciTech Connect (OSTI)

    Crostack, H.A.; Beller, U.

    1995-12-31

    In order to increase the lifetime of components used for diesel engines or gas turbines surfaces are coated by ceramics. In recent years it succeeded in spraying thermal barrier coatings based on zirconia up to a thickness of a few millimeters. A comparison of the damage behavior between yttria partially stabilized zirconia coatings with different thickness will be presented. The coatings are produced by atmospheric plasma spraying. The thickness is varied from 0.5 mm up to 2 mm. In order to characterize the mechanical as well as the damage processes different methods of destructive testing (tensile, bending, and loading test) are applied. Additionally, non-destructive testing methods were used to investigate the damage processes on micro structural level. The results will be discussed according to the microstructure.

  14. Gaseous modification of MCrAlY coatings

    DOE Patents [OSTI]

    Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

    2000-01-01

    The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

  15. Sodium sulfur container with chromium/chromium oxide coating

    DOE Patents [OSTI]

    Ludwig, Frank A. (Irvine, CA); Higley, Lin R. (Santa Ana, CA)

    1981-01-01

    A coating of chromium/chromium oxide is disclosed for coating the surfaces of electrically conducting components of a sodium sulfur battery. This chromium/chromium oxide coating is placed on the surfaces of the electrically conducting components of the battery which are in contact with molten polysulfide and sulfur reactants during battery operation.

  16. Method for forming hermetic coatings for optical fibers

    DOE Patents [OSTI]

    Michalske, Terry A. (P.O. Box 1042, Cedar Crest, NM 87008); Rye, Robert R. (1304 Espanola NE., Albuquerque, NM 87110); Smith, William L. (9916 Fostoria Rd., NE., Albuquerque, NM 87111)

    1993-01-01

    A method for forming hermetic coatings on optical fibers by hot filament assisted chemical vapor deposition advantageously produces a desirable coating while maintaining the pristine strength of the pristine fiber. The hermetic coatings may be formed from a variety of substances, such as, for example, boron nitride and carbon.

  17. High temperature ceramic articles having corrosion resistant coating

    DOE Patents [OSTI]

    Stinton, David P. (Knoxville, TN); Lee, Woo Y. (Knoxville, TN)

    1997-01-01

    A ceramic article which includes a porous body of SiC fibers, Si.sub.3 N.sub.4 fibers, SiC coated fibers or Si.sub.3 N.sub.4 coated fibers, having at least one surface, the article having a coating of AlN adherently disposed throughout at least a portion of the porous body.

  18. Optimizing High-Z Coatings for Inertial Fusion Energy Shells

    SciTech Connect (OSTI)

    Stephens, Elizabeth H.; Nikroo, Abbas; Goodin, Daniel T.; Petzoldt, Ronald W.

    2003-05-15

    Inertial fusion energy (IFE) reactors require shells with a high-Z coating that is both permeable, for timely filling with deuterium-tritium, and reflective, for survival in the chamber. Previously, gold was deposited on shells while they were agitated to obtain uniform, reproducible coatings. However, these coatings were rather impermeable, resulting in unacceptably long fill times. We report here on an initial study on Pd coatings on shells in the same manner. We have found that these palladium-coated shells are substantially more permeable than gold. Pd coatings on shells remained stable on exposure to deuterium. Pd coatings had lower reflectivity compared to gold that leads to a lower working temperature, and efficiency, of the proposed fusion reactor. Seeking to combine the permeability of Pd coatings and high reflectivity of gold, AuPd-alloy coatings were produced using a cosputtering technique. These alloys demonstrated higher permeability than Au and higher reflectivity than Pd. However, these coatings were still less reflective than the gold coatings. To improve the permeability of gold's coatings, permeation experiments were performed at higher temperatures. With the parameters of composition, thickness, and temperature, we have the ability to comply with a large target design window.

  19. Evaluation of metallized paint coatings for composite spacecraft structures

    SciTech Connect (OSTI)

    Brzuskiewicz, J.E. )

    1990-04-01

    Thermal control coatings are needed to minimize temperature excursions of composite spacecraft structures in low earth orbit. Coatings prepared with combinations of metal flake and metal oxide pigments were prepared to obtain a range of solar absorptance and emittance properties. These coatings were subjected to screening tests to characterize their ultraviolet stability, atomic oxygen resistance and outgassing properties.

  20. High Temperature coatings based on {beta}-NiAI

    SciTech Connect (OSTI)

    Severs, Kevin

    2012-07-10

    High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAlTiB{sub 2} composite are explained. A novel coating process for MoNiAl alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated MoNiAl alloys is discussed.

  1. Method For Improving The Oxidation Resistance Of Metal Substrates Coated With Thermal Barrier Coatings

    DOE Patents [OSTI]

    Thompson, Anthony Mark (Niskayuna, NY); Gray, Dennis Michael (Delanson, NY); Jackson, Melvin Robert (Niskayuna, NY)

    2003-05-13

    A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described. A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.

  2. Technology disrupted

    SciTech Connect (OSTI)

    Papatheodorou, Y.

    2007-02-15

    Three years ago, the author presented a report on power generation technologies which in summary said 'no technology available today has the potential of becoming transformational or disruptive in the next five to ten years'. In 2006 the company completed another strategic view research report covering the electric power, oil, gas and unconventional energy industries and manufacturing industry. This article summarises the strategic view findings and then revisits some of the scenarios presented in 2003. The cost per megawatt-hour of the alternatives is given for plants ordered in 2005 and then in 2025. The issue of greenhouse gas regulation is dealt with through carbon sequestration and carbon allowances or an equivalent carbon tax. Results reveal substantial variability through nuclear power, hydro, wind, geothermal and biomass remain competitive through every scenario. Greenhouse gas scenario analysis shows coal still be viable, albeit less competitive against nuclear and renewable technologies. A carbon tax or allowance at $24 per metric ton has the same effect on IGCC cost as a sequestration mandate. However, the latter would hurt gas plants much more than a tax or allowance. Sequestering CO{sub 2} from a gas plant is almost as costly per megawatt-hour as for coal. 5 refs., 5 figs., 5 tabs.

  3. Building Technologies Office Overview

    SciTech Connect (OSTI)

    2013-04-01

    Building Technologies Office Overview Presentation for the 2013 Building Technologies Office's Program Peer Review

  4. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    1997-02-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  5. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains a minimum of 243 citations and includes a subject term index and title list.)

  6. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains 250 citations and includes a subject term index and title list.)

  7. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    1995-11-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  8. Science and Technology Review December 2009

    SciTech Connect (OSTI)

    Bearinger, J P

    2009-11-17

    This month's issue has the following articles: (1) Advanced Materials for Our Past, Present, and Future - Commentary by Tomas Diaz de la Rubia; (2) A Defensive 'Coat' for Materials under Attack - Amorphous metal coatings provide the strength and corrosion resistance needed to protect military vessels and spent nuclear fuel containers; (3) Too Close for Comfort - Laboratory scientists are analyzing the feasibility of using nuclear explosives to disrupt or divert asteroids on a collision course with Earth; (4) Hyperion: A Titan of High-Performance Computing Systems - Livermore is collaborating with 10 computing industry leaders to create a test bed for Linux cluster hardware and software technologies; (5) Isolating Pathogens for Speedy Identification - An automated miniature device separates viruses, bacteria, genetic material, and proteins from nasal swabs and blood and urine samples for speedy identification.

  9. Selective emission multilayer coatings for a molybdenum thermophotovoltaic radiator

    DOE Patents [OSTI]

    Cockeram, Brian Vern

    2004-01-27

    Multilayer coating designs have been developed to provide selective emission for a molybdenum thermophotovoltaic (TPV) radiator surface. These coatings increase the surface emissivity of a molybdenum TPV radiator substrate in the wavelength range that matches the bandgap of the TPV cells to increase the power density of the TPV system. Radiator emission at wavelengths greater than the bandgap energy of the TPV cells is greatly reduced through the use of these coatings, which significantly increases the efficiency of the TPV system. The use of this coating greatly improves the performance of a TPV system, and the coating can be tailored to match the bandgap of any practical TPV system.

  10. Ground plane insulating coating for proximity focused devices

    DOE Patents [OSTI]

    Power, Gary D. (Manteca, CA)

    1998-01-01

    A thin layer of alumina (aluminum oxide) is coated onto the ground plane of a microchannel plate (MCP) without covering the pores of the MCP so it does not effect the performance. The coating is sputtered onto the ground plane at a very steep angle. The addition of the thin dielectric coating of alumina greatly improves the spatial resolution of proximity focused image intensifiers using a narrow gap between the phosphor screen and the MCP. With the coating on the ground plane and the same gap the phosphor screen can be ran at 9000 volts, as compared to 3 kV without the coating.

  11. Ground plane insulating coating for proximity focused devices

    DOE Patents [OSTI]

    Power, G.D.

    1998-07-14

    A thin layer of alumina (aluminum oxide) is coated onto the ground plane of a microchannel plate (MCP) without covering the pores of the MCP so it does not effect the performance. The coating is sputtered onto the ground plane at a very steep angle. The addition of the thin dielectric coating of alumina greatly improves the spatial resolution of proximity focused image intensifiers using a narrow gap between the phosphor screen and the MCP. With the coating on the ground plane and the same gap the phosphor screen can be ran at 9000 volts, as compared to 3 kV without the coating. 3 figs.

  12. Paint selection for coating radioactive-waste drums

    SciTech Connect (OSTI)

    Briggs, J.L.

    1980-07-01

    It is concluded that although the white epoxy Paint Sample E is suitable for coating waste drums, the additional pretreated costs of grit blasting prior to paint application would preclude adoption of that paint system. The specified 10.0-mil coating thickness of that coating would also incur higher costs. The Vorac epoxy-phenolic base paint (buff or yellow) was the only other paint that exhibited suitable corrosion and impact resistance required for coating the waste drums. In addition, that paint does not require a grit-blasted substrate or other costly pretreatment prior to coating.

  13. Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation

    SciTech Connect (OSTI)

    Nitin Padture

    2011-12-31

    Ceramic thermal barrier coatings (TBCs) used in gas-turbine engines afford higher operating temperatures, resulting in enhanced efficiencies and performance. However, in the case of syngas-fired engines, fly ash particulate impurities that may be present in syngas can melt on the hotter TBC surfaces and form glassy deposits. These deposits can penetrate the TBCs leading to their failure. In experiments using lignite fly ash to simulate these conditions we show that conventional TBCs of composition 93wt% ZrO{sub 2} + 7wt% Y{sub 2}O{sub 3} (7YSZ) fabricated using the air plasma spray (APS) process are completely destroyed by the molten fly ash. The molten fly ash is found to penetrate the full thickness of the TBC. The mechanisms by which this occurs appear to be similar to those observed in degradation of 7YSZ TBCs by molten calcium-magnesium-aluminosilicate (CMAS) sand and by molten volcanic ash in aircraft engines. In contrast, APS TBCs of Gd{sub 2Zr{sub 2}O{sub 7} composition are highly resistant to attack by molten lignite fly ash under identical conditions, where the molten ash penetrates ~25% of TBC thickness. This damage mitigation appears to be due to the formation of an impervious, stable crystalline layer at the fly ash/Gd{sub 2}Zr{sub 2}O{sub 7} TBC interface arresting the penetrating moltenfly- ash front. Additionally, these TBCs were tested using a rig with thermal gradient and simultaneous accumulation of ash. Modeling using an established mechanics model has been performed to illustrate the modes of delamination, as well as further opportunities to optimize coating microstructure. Transfer of the technology was developed in this program to all interested parties.

  14. Development of wear-resistant ceramic coatings for diesel engine components

    SciTech Connect (OSTI)

    Naylor, M.G.S. )

    1992-06-01

    The tribological properties of a variety of advanced coating materials have been evaluated under conditions which simulate the piston ring -- cylinder liner environment near top ring reversal in a heavy duty diesel engine. Coated ring'' samples were tested against a conventional pearlitic grey cast iron liner material using a high temperature reciprocating wear test rig. Tests were run with a fresh CE/SF 15W40lubricant at 200 and 350{degrees}C, with a high-soot, engine-tested oil at 200{degrees}C and with no lubrication at 200{degrees}C. For lowest wear under boundary lubricated conditions, the most promising candidates to emerge from this study were high velocity oxy-fuel (HVOF) Cr{sub 3} C{sub 2} - 20% NiCr and WC - 12% Co cermets, low temperature arc vapor deposited (LTAVD) CrN and plasma sprayed chromium oxides. Also,plasma sprayed Cr{sub 2}O{sub 3} and A1{sub 2}O{sub 3}-ZrO{sub 2} materials were found to give excellent wear resistance in unlubricated tests and at extremely high temperatures (450{degrees}C) with a syntheticoil. All of these materials would offer substantial wear reductions compared to the conventional electroplated hard chromium ring facing and thermally sprayed metallic coatings, especially at high temperatures and with high-soot oils subjected to degradation in diesel environments. The LTAVD CrN coating provided the lowest lubricated wear rates of all the materials evaluated, but may be too thin (4 {mu}m) for use as a top ring facing. Most of the coatings evaluated showed higher wear rates with high-soot, engine-tested oil than with fresh oil, with increases of more than a factor of ten in some cases. Generally, metallic materials were found to be much more sensitive to soot/oil degradation than ceramic and cermet coatings. Thus, decreased soot sensitivity'' is a significant driving force for utilizing ceramic or cermet coatings in diesel engine wear applications.

  15. Resonant thermonuclear reaction rate

    SciTech Connect (OSTI)

    Haubold, H.J.; Mathai, A.M.

    1986-08-01

    Basic physical principles for the resonant and nonresonant thermonuclear reaction rates are applied to find their standard representations for nuclear astrophysics. Closed-form representations for the resonant reaction rate are derived in terms of Meijer's G-italic-function. Analytic representations of the resonant and nonresonant nuclear reaction rates are compared and the appearance of Meijer's G-italic-function is discussed in physical terms.

  16. Improving Entrainment Rate Parameterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Entrainment Rate Parameterization For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Parameterization of entrainment rate is critical for improving representation of cloud- and convection-related processes in climate models; however, much remains unclear. This work seeks to improve understanding and parameterization of entrainment rate by use of aircraft observations and large-eddy simulations of shallow cumulus clouds over

  17. Chlorofluorocarbon leak detection technology

    SciTech Connect (OSTI)

    Munday, E.B.

    1990-12-01

    There are about 590 large coolant systems located at the Portsmouth Gaseous Diffusion Plant (PORTS) and the Paducah Gaseous Diffusion Plant (PGDP) leaking nearly 800,000 lb of R-114 refrigerant annually (1989 estimate). A program is now under way to reduce the leakage to 325,000 lb/year -- an average loss of 551 lb/year (0.063 lb/h) per coolant system, some of which are as large as 800 ft. This report investigates leak detection technologies that can be used to locate leaks in the coolant systems. Included are descriptions, minimum leak detection rate levels, advantages, disadvantages, and vendor information on the following technologies: bubbling solutions; colorimetric leak testing; dyes; halogen leak detectors (coronea discharge detectors; halide torch detectors, and heated anode detectors); laser imaging; mass spectroscopy; organic vapor analyzers; odorants; pressure decay methods; solid-state electrolytic-cell gas sensors; thermal conductivity leak detectors; and ultrasonic leak detectors.

  18. Accelerated Testing of HT-9 with Zirconia Coatings Containing Gallium using Raman Spectroscopy and XPS

    SciTech Connect (OSTI)

    Windisch, Charles F.; Henager, Charles H.; Engelhard, Mark H.; Bennett, Wendy D.

    2009-12-01

    Laser Raman spectroscopy and x-ray photoelectron spectroscopy were used to study the evolution of composition of oxide films in the presence of zirconia coatings on miniature HT-9 alloy specimens subjected to elevated temperature in air. The experiments expanded on previous efforts to develop a quick-screening technique for candidate alloys for cladding materials (HT-9) and actinide-based mixed oxide fuel mixtures (represented by the zirconia coating) by investigating the effect of both coating composition and alloy pretreatment conditions on the high temperature reactions. In particular, the presence of the element Ga (a potential impurity in mixed oxide fuel) in the initial zirconia coating was found to accelerate the rate of oxide growth relative to that of yttria-stabilized zirconia studied previously. In addition, HT-9 samples that were subjected to different thermal pretreatments gave different results. The results suggest that the presence of Ga in a mixed oxide fuel will enhance the corrosion of HT-9 cladding under the conditions of this study, although the extent of enhancement is influenced by thermal pretreatment of the cladding material. The results also demonstrate the need to combine Raman spectroscopy with other techniques, particularly photoelectron spectroscopy, for optimizing composition and/or fabrication conditions of both cladding and oxide fuels for advanced nuclear reactors.

  19. LCC Guidance Rates

    Broader source: Energy.gov [DOE]

    Notepad text file provides the LCC guidance rates in a numbered format for the various regions throughout the U.S.

  20. Draft Tiered Rate Methodology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Regional Dialogue Discussion Purposes Only Pre-Decisional Draft Tiered Rates Methodology March 7, 2008 Pre-decisional, Deliberative, For Discussion Purposes Only March 7,...

  1. Microstructure, Processing, Performance Relationships for High Temperature Coatings

    SciTech Connect (OSTI)

    Thomas M. Lillo

    2011-04-01

    This work evaluates the suitability of iron aluminide coatings for use in high temperature fossil fuel combustion environments, such as boiler applications. The coatings are applied using High Velocity Oxy-Fuel (HVOF) thermal spray techniques. Iron aluminide coatings, with the nominal composition of Fe3Al, were applied to various high temperature structural materials (316 Stainless Steel, 9Cr-1Mo steel and Inconel 600) that typically lack inherent resistance to environmental degradation found in fossil fuel combustion atmospheres. Coating/substrate combinations were subjected to thermal cycling to evaluate the effect of HVOF parameters, coating thickness, substrate material and substrate surface roughness on the resistance to coating delamination and cracking. It was found that substrate surface roughness had a profound influence on the performance of a given substrate/coating system and that surface preparation techniques will need to be tailored to the specific substrate material. Also, higher particle velocity during HVOF thermal spray deposition of the iron aluminide coatings tended to result in better-performing coating/substrate systems with less delamination at the coating/substrate interface. Some combinations of HVOF parameters, coating thickness and substrate materials were found to perform extremely well even at temperatures up to 900oC. However, in some cases, substantial reactions at the interface were observed.

  2. Considerations for How to Rate CPV

    SciTech Connect (OSTI)

    Kurtz, S.; Miller, M.; Marion, B.; Emery, K.; McConnell, R.; Surendran, S.; Kimber, A.

    2011-02-01

    The concentrator photovoltaic (CPV) industry is introducing multiple products into the marketplace, but, as yet, the; community has not embraced a unified method for assessing a nameplate rating. The choices of whether to use 850,; 900, or 1000 W/m2 for the direct-normal irradiance and whether to link the rating to ambient or cell temperature will; affect how CPV modules are rated and compared with other technologies. This paper explores the qualitative and; quantitative ramifications of these choices using data from two multi-junction CPV modules and two flat-plate; modules.

  3. Injection moulding of optical functional micro structures using laser structured, PVD-coated mould inserts

    SciTech Connect (OSTI)

    Hopmann, Ch.; Weber, M.; Schngart, M.; Schfer, C.; Bobzin, K.; Bagcivan, N.; Brgelmann, T.; Thei, S.; Mnstermann, T.; Steger, M.

    2015-05-22

    Micro structured optical plastics components are intensively used i. e. in consumer electronics, for optical sensors in metrology, innovative LED-lighting or laser technology. Injection moulding has proven to be successful for the large-scale production of those parts. However, the production of those parts still causes difficulties due to challenges in the moulding and demoulding of plastics parts created with laser structured mould inserts. A complete moulding of the structures often leads to increased demoulding forces, which then cause a breaking of the structures and a clogging of the mould. An innovative approach is to combine PVD-coated (physical vapour deposition), laser structured inserts and a variothermal moulding process to create functional mic8iro structures in a one-step process. Therefore, a PVD-coating is applied after the laser structuring process in order to improve the wear resistance and the anti-adhesive properties against the plastics melt. In a series of moulding trials with polycarbonate (PC) and polymethylmethacrylate (PMMA) using different coated moulds, the mould temperature during injection was varied in the range of the glass transition and the melt temperature of the polymers. Subsequently, the surface topography of the moulded parts is evaluated by digital 3D laser-scanning microscopy. The influence of the moulding parameters and the coating of the mould insert on the moulding accuracy and the demoulding behaviour are being analysed. It is shown that micro structures created by ultra-short pulse laser ablation can be successfully replicated in a variothermal moulding process. Due to the mould coating, significant improvements could be achieved in producing micro structured optical plastics components.

  4. Radiation pressure efficiency measurements of nanoparticle coated microspheres

    SciTech Connect (OSTI)

    Kim, Soo Y.; Taylor, Joseph D.; Ladouceur, Harold D.; Hart, Sean J.; Terray, Alex

    2013-12-02

    Experimental measurements of the radiation pressure efficiency (Q{sub pr}) for several microparticles have been compared to theoretical calculations extrapolated from the Bohren-Huffman code for Mie scattering of coated particles. An increased shift of the Q{sub pr} parameter was observed for 2??m SiO{sub 2} core particles coated with nanoparticles of higher refractive indices. Coatings of 14?nm melamine particles were found to increase the Q{sub pr} parameter 135 times over similar coatings using SiO{sub 2} particles of the same size. While a coating of 100?nm polystyrene particles also showed a significant increase, they did not agree well with theoretical values. It is hypothesized that other factors such as increased scatter, drag, and finite coating coverage are no longer negligible for coatings using nanoparticles in this size regime.

  5. Coated armor system and process for making the same

    DOE Patents [OSTI]

    Chu, Henry S.; Lillo, Thomas M.; McHugh, Kevin M.

    2010-11-23

    An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

  6. Recovery Act: A Low Cost Spray Deposited Solar PV Anti-Reflection Coating Final Technical Report

    SciTech Connect (OSTI)

    Harvey, Michael D.

    2010-08-30

    PV module glass is typically low iron glass which exhibits extremely low absorption of light at solar wavelengths. However, reflection losses from typical high quality solar glass are about 4.5% of the input solar energy. By applying an antireflection coating to the cover glass of their modules, a PV module maker will gain at least a 3% increase in the light passing through the glass and being converted to electricity. Thus achieving an increase of >3% in electricity output from the modules. This Project focussed on developing a process that deposits a layer of porous silica (SiO2) on glass or plastic components, and testing the necessary subcomponents and subsystems required to demonstrate the commercial technology. This porous layer acts as a broadband single layer AR coating for glass and plastics, with the added benefit of being a hydrophilic surface for low surface soiling.

  7. Technology Name

    Energy Savers [EERE]

    Tech Fact Sheet Site Project & Identifier Tech Stage: Development DE-EM0000598 D&D KM-IT For the deployment of Information Technology for D&D knowledge management Page 1 of 2 Florida International University Florida D&D Knowledge Management Information Tool Challenge Deactivation and decommissioning (D&D) work is a high priority across the DOE Complex. The D&D community associated with the various DOE sites has gained extensive knowledge and experience over the years. To

  8. Technology Name

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tech Fact Sheet Site Project & Identifier Tech Stage: Development DE-EM0000598 D&D KM-IT For the deployment of Information Technology for D&D knowledge management Page 1 of 2 Florida International University Florida D&D Knowledge Management Information Tool Challenge Deactivation and decommissioning (D&D) work is a high priority across the DOE Complex. The D&D community associated with the various DOE sites has gained extensive knowledge and experience over the years. To

  9. TECHNOLOGY TRANSFER

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    404-NOV. 1, 2000 TECHNOLOGY TRANSFER COMMERCIALIZATION ACT OF 2000 VerDate 11-MAY-2000 04:52 Nov 16, 2000 Jkt 089139 PO 00000 Frm 00001 Fmt 6579 Sfmt 6579 E:\PUBLAW\PUBL404.106 APPS27 PsN: PUBL404 114 STAT. 1742 PUBLIC LAW 106-404-NOV. 1, 2000 Public Law 106-404 106th Congress An Act To improve the ability of Federal agencies to license federally owned inventions. Be it enacted by the Senate and House of Representatives of the United States of America in Congress assembled, SECTION 1. SHORT

  10. Balloon Coating with Rapamycin Using an On-site Coating Device

    SciTech Connect (OSTI)

    Schmehl, Joerg; Ruhr, Juergen von der; Dobratz, Markus; Kehlbach, Rainer; Braun, Isabelle; Greiner, Tim-Oliver; Claussen, Claus D.; Behnisch, Boris

    2013-06-15

    Purpose. The efficacy of drug-eluting balloons has been demonstrated in clinical trials. The drug predominantly used is paclitaxel because of its lipophilic properties and the rapid onset of action. The aim of the investigation was to evaluate the feasibility and efficacy of an alternative balloon coating with rapamycin that can be applied on site.MethodsThe balloon coating (3.0/18 and 3.0/12 mm, Cathy No. 4, Translumina GmbH) with rapamycin was conducted with a coating machine (Translumina GmbH). Concentrations were 2, 2 Multiplication-Sign 2, 3, and 4 %. Measurements regarding the amount of substance released to the vessel wall were carried out on explanted porcine coronaries by means of ultraviolet and visible-light spectroscopy. Inflation time varied between 30 and 120 s. The biological effect of the coating was evaluated in a porcine peripheral overstretch and stent implantation model. Results. The amount of rapamycin on the balloon surface ranged from 558 {+-} 108 {mu}g for the 2 % solution to 1,441 {+-} 228 {mu}g in the 4 % solution. An amount of 95 {+-} 63-193 {+-} 113 {mu}g was released into the vessel wall. The quantitative measurements of the angiographic examinations 4 weeks after treatment revealed a reduction of diameter stenosis from 20.6 {+-} 17.4 % in the control group to 11.6 {+-} 5.5 % in the drug-eluting balloon group. Conclusion. A balloon coating with rapamycin omitting an excipient is possible with a dose-adjustable coating machine. However, the biological effects are moderate, which make further optimization of the coating process and evaluation of appropriate excipients necessary.

  11. High rate buffer layer for IBAD MgO coated conductors

    DOE Patents [OSTI]

    Foltyn, Stephen R. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Arendt, Paul N. (Los Alamos, NM)

    2007-08-21

    Articles are provided including a base substrate having a layer of an oriented material thereon, and, a layer of hafnium oxide upon the layer of an oriented material. The layer of hafnium oxide can further include a secondary oxide such as cerium oxide, yttrium oxide, lanthanum oxide, scandium oxide, calcium oxide and magnesium oxide. Such articles can further include thin films of high temperature superconductive oxides such as YBCO upon the layer of hafnium oxide or layer of hafnium oxide and secondary oxide.

  12. Method of producing thermally sprayed metallic coating

    DOE Patents [OSTI]

    Byrnes, Larry Edward (Rochester Hills, MI); Kramer, Martin Stephen (Clarkston, MI); Neiser, Richard A. (Albuquerque, NM)

    2003-08-26

    The cylinder walls of light metal engine blocks are thermally spray coated with a ferrous-based coating using an HVOF device. A ferrous-based wire is fed to the HVOF device to locate a tip end of the wire in a high temperature zone of the device. Jet flows of oxygen and gaseous fuel are fed to the high temperature zone and are combusted to generate heat to melt the tip end. The oxygen is oversupplied in relation to the gaseous fuel. The excess oxygen reacts with and burns a fraction of the ferrous-based feed wire in an exothermic reaction to generate substantial supplemental heat to the HVOF device. The molten/combusted metal is sprayed by the device onto the walls of the cylinder by the jet flow of gases.

  13. Anti-stiction coating for microelectromechanical devices

    DOE Patents [OSTI]

    Hankins, Matthew G. (Albuquerque, NM); Mayer, Thomas M. (Albuquerque, NM); Wheeler, David R. (Albuquerque, NM)

    2006-05-16

    A method for depositing an anti-stiction coating on a MEMS device comprises reacting the vapor of an amino-functionalized silane precursor with a silicon surface of the MEMS device in a vacuum chamber. The method can further comprise cleaning the silicon surface of the MEMS device to form a clean hydroxylated silicon surface prior to reacting the precursor vapor with the silicon surface. The amino-functionalized silane precursor comprises at least one silicon atom, at least one reactive amino (or imine) pendant, and at least one hydrophobic pendant. The amino-functionalized silane precursor is highly reactive with the silicon surface, thereby eliminating the need for a post-process anneal step and enabling the reaction to occur at low pressure. Such vapor-phase deposition of the amino-functionalized silane coating provides a uniform surface morphology and strong adhesion to the silicon surface.

  14. Article coated with flash bonded superhydrophobic particles

    DOE Patents [OSTI]

    Simpson, John T (Clinton, TN) [Clinton, TN; Blue, Craig A (Knoxville, TN) [Knoxville, TN; Kiggans, Jr., James O [Oak Ridge, TN

    2010-07-13

    A method of making article having a superhydrophobic surface includes: providing a solid body defining at least one surface; applying to the surface a plurality of diatomaceous earth particles and/or particles characterized by particle sizes ranging from at least 100 nm to about 10 .mu.m, the particles being further characterized by a plurality of nanopores, wherein at least some of the nanopores provide flow through porosity, the particles being further characterized by a plurality of spaced apart nanostructured features that include a contiguous, protrusive material; flash bonding the particles to the surface so that the particles are adherently bonded to the surface; and applying a hydrophobic coating layer to the surface and the particles so that the hydrophobic coating layer conforms to the nanostructured features.

  15. Nanocomposite protective coatings for battery anodes

    DOE Patents [OSTI]

    Lemmon, John P; Xiao, Jie; Liu, Jun

    2014-01-21

    Modified surfaces on metal anodes for batteries can help resist formation of malfunction-inducing surface defects. The modification can include application of a protective nanocomposite coating that can inhibit formation of surface defects. such as dendrites, on the anode during charge/discharge cycles. For example, for anodes having a metal (M'), the protective coating can be characterized by products of chemical or electrochemical dissociation of a nanocomposite containing a polymer and an exfoliated compound (M.sub.a'M.sub.b''X.sub.c). The metal, M', comprises Li, Na, or Zn. The exfoliated compound comprises M' among lamella of M.sub.b''X.sub.c, wherein M'' is Fe, Mo, Ta, W, or V, and X is S, O, or Se.

  16. Laser ablated hard coating for microtools

    DOE Patents [OSTI]

    McLean, W. II; Balooch, M.; Siekhaus, W.J.

    1998-05-05

    Wear-resistant coatings composed of laser ablated hard carbon films, are deposited by pulsed laser ablation using visible light, on instruments such as microscope tips and micro-surgical tools. Hard carbon, known as diamond-like carbon (DLC), films produced by pulsed laser ablation using visible light enhances the abrasion resistance, wear characteristics, and lifetimes of small tools or instruments, such as small, sharp silicon tips used in atomic probe microscopy without significantly affecting the sharpness or size of these devices. For example, a 10--20 nm layer of diamond-like carbon on a standard silicon atomic force microscope (AFM) tip, enables the useful operating life of the tip to be increased by at least twofold. Moreover, the low inherent friction coefficient of the DLC coating leads to higher resolution for AFM tips operating in the contact mode. 12 figs.

  17. Laser ablated hard coating for microtools

    DOE Patents [OSTI]

    McLean, II, William (Oakland, CA); Balooch, Mehdi (Berkeley, CA); Siekhaus, Wigbert J. (Berkeley, CA)

    1998-05-05

    Wear-resistant coatings composed of laser ablated hard carbon films, are deposited by pulsed laser ablation using visible light, on instruments such as microscope tips and micro-surgical tools. Hard carbon, known as diamond-like carbon (DLC), films produced by pulsed laser ablation using visible light enhances the abrasion resistance, wear characteristics, and lifetimes of small tools or instruments, such as small, sharp silicon tips used in atomic probe microscopy without significantly affecting the sharpness or size of these devices. For example, a 10-20 nm layer of diamond-like carbon on a standard silicon atomic force microscope (AFM) tip, enables the useful operating life of the tip to be increased by at least twofold. Moreover, the low inherent friction coefficient of the DLC coating leads to higher resolution for AFM tips operating in the contact mode.

  18. High temperature low friction surface coating

    DOE Patents [OSTI]

    Bhushan, Bharat (Watervliet, NY)

    1980-01-01

    A high temperature, low friction, flexible coating for metal surfaces which are subject to rubbing contact includes a mixture of three parts graphite and one part cadmium oxide, ball milled in water for four hours, then mixed with thirty percent by weight of sodium silicate in water solution and a few drops of wetting agent. The mixture is sprayed 12-15 microns thick onto an electro-etched metal surface and air dried for thirty minutes, then baked for two hours at 65.degree. C. to remove the water and wetting agent, and baked for an additional eight hours at about 150.degree. C. to produce the optimum bond with the metal surface. The coating is afterwards burnished to a thickness of about 7-10 microns.

  19. Diamond coated silicon field emitter array

    SciTech Connect (OSTI)

    S. Albin; W. Fu; A. Varghese; A. C. Lavarias; G. R. Myneni

    1999-07-01

    Diamond coated silicon tip arrays, with and without a self-aligned gate, were fabricated, and current-voltage characteristics of 400 tips were measured. Diamond films were grown uniformly on Si tips using microwave plasma after nucleation with 10 nm diamond suspension and substrate bias. An emission current of 57 ?A was obtained at 5 V from the ungated array tips separated from an anode at 2 ?m. In the case of the gated arrays with 1.5 ?m aperture, an emission current of 3.4 ?A was measured at a gate voltage of 80 V for an anode separation of 200 ?m. The turn-on voltages for these two types of devices were 0.2 and 40 V, respectively. Diamond coated Si tip arrays have potential applications in field emission based low voltage vacuum electronic devices and microsensors.

  20. Sol-gel coatings for optoelectronic devices

    SciTech Connect (OSTI)

    Avellaneda, C.O.; Macedo, M.A.; Florentino, A.O.; Aegerter, M.A. [Univ. of Sao Paulo, Sao Carlos (Brazil). Inst. de Fisica e Quimica

    1994-12-31

    Nb{sub 2}O{sub 5} prepared by a sol-gel process in form of coatings and aerogels are new materials which present interesting properties: (a) The coatings present electrochromic properties and exhibit a blue coloration under Li{sup +} insertion with 100% reversible variation of the optical transmission in the visible and near infrared range between 80% and 200% and have a high chemical stability (tested up to 2,000 cycles). (b) They are semiconductor and present a photoelectric effect when illuminating in the UV region ({lambda} < 360 nm). These films are therefore very promising to be used in electrochromic devices, as electrodes for photoelectrochemical purpose and the development of nanocrystalline solar cell. (c) When prepared in aerogel form, the high BET surface area of the powders is a promising asset to use these new materials for catalytic purposes for air pollution control.

  1. EMBEDDED OPTICAL SENSORS FOR THERMAL BARRIER COATINGS

    SciTech Connect (OSTI)

    David R. Clarke

    2004-12-16

    In this first year of the program we have focused on the selection of rare-earth dopants for luminescent sensing in thermal barrier coating materials, the effect of dopant concentration on several of the luminescence characteristics and initial fabrication of one type of embedded sensor, the ''red-line'' sensor. We have initially focused on erbium as the lanthanide dopant for luminescence doping of yttria-stabilized zirconia and europium as the lanthanide for luminescence doping of gadolinium zirconate. The latter exhibits a temperature-dependent luminescence lifetime up to at least 1100 C. A buried layer, ''red-line'' sensor in an electron-beam deposited yttria-stabilized zirconia coating with erbium has been demonstrated and exhibits a temperature-dependent luminescence lifetime up to at least 400 C.

  2. Coating considerations for mirrors of CPV devices

    SciTech Connect (OSTI)

    Schmauder, Torsten; Sauer, Peter; Ickes, Gerd

    2014-09-26

    One of the different optical concepts for concentrator devices is to place a focussing primary mirror behind a transparent front plate. In addition (also in case of Fresnel-diffractive main optics), further 'secondary' reflectors may be used further along the beam path. Such mirrors are usually implemented as coating stacks of a highly reflective metal - usually silver - and protective layers. The protective layers are preferably designed as reflection enhancing interference stack. The design of such protective layer stacks yields two difficulties, which are addressed in this paper: (a) vacuum coating of three-dimensional parts will result in a thickness distribution and the optical design of the stack should thus be tolerant to layer thickness variations, and (b) different places of the mirror will have different angle-of-incidence of the sunlight under operating conditions. As result, the layer stack has a different design at different places of the mirror.

  3. biofouling studies on Sandia's marine hydrokinetic coatings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    biofouling studies on Sandia's marine hydrokinetic coatings - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense

  4. Organosiloxane-grafted natural polymer coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi

    1998-12-01

    A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation. 17 figs.

  5. METAL COATED ARTICLES AND METHOD OF MAKING

    DOE Patents [OSTI]

    Eubank, L.D.

    1958-08-26

    A method for manufacturing a solid metallic uranium body having an integral multiple layer protective coating, comprising an inner uranium-aluminum alloy firmly bonded to the metallic uranium is presented. A third layer of silver-zinc alloy is bonded to the zinc-aluiminum layer and finally a fourth layer of lead-silver alloy is firmly bonded to the silver-zinc layer.

  6. Characterization of Biocompatible Parylene-C Coatings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biocompatible Parylene-C Coatings for BIOMEMS Applications Quoc P. Nguyen a,* , Jost Goettert a , William T. Monroe b , Varshni Singh a a Center for Advanced Microstructures and Devices (CAMD), Louisiana State University, Baton Rouge, LA b Department of Biological and Agricultural Engineering, LSU, Baton Rouge, LA qnguye6@lsu.edu * Master Thesis, LSU Biological and Agricultural Engineering Summary Biological Micro-Electro-Mechanical Systems (BioMEMS) is one of the forefronts of research for

  7. Polyorganometallosiloxane-2- or -4-pyridine coatings

    DOE Patents [OSTI]

    Sugama, T.

    1997-12-30

    A new family of polyorganometallosiloxane-2- or -4-pyridine compounds are provided for corrosion resistant coatings on light metals such as aluminum, magnesium, zinc, steel and their alloys. The novel compounds contain backbones modified by metal alkoxides, metallocenes and metallophthalocyanates where the metal is Zr, Ti, Mo, V, Hf, Nb, Si, B and combinations thereof. Methods of making the new compounds are also provided. 13 figs.

  8. Development of Industrially Viable Battery Electrode Coatings

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  9. Development of Industrially Viable Battery Electrode Coatings

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Residual Stress Measurements in Thin Coatings

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  11. Surface figure control for coated optics

    DOE Patents [OSTI]

    Ray-Chaudhuri, Avijit K.; Spence, Paul A.; Kanouff, Michael P.

    2001-01-01

    A pedestal optical substrate that simultaneously provides high substrate dynamic stiffness, provides low surface figure sensitivity to mechanical mounting hardware inputs, and constrains surface figure changes caused by optical coatings to be primarily spherical in nature. The pedestal optical substrate includes a disk-like optic or substrate section having a top surface that is coated, a disk-like base section that provides location at which the substrate can be mounted, and a connecting cylindrical section between the base and optics or substrate sections. The optic section has an optical section thickness.sup.2 /optical section diameter ratio of between about 5 to 10 mm, and a thickness variation between front and back surfaces of less than about 10%. The connecting cylindrical section may be attached via three spaced legs or members. However, the pedestal optical substrate can be manufactured from a solid piece of material to form a monolith, thus avoiding joints between the sections, or the disk-like base can be formed separately and connected to the connecting section. By way of example, the pedestal optical substrate may be utilized in the fabrication of optics for an extreme ultraviolet (EUV) lithography imaging system, or in any optical system requiring coated optics and substrates with reduced sensitivity to mechanical mounts.

  12. Ceramic wash-coat for catalyst support

    DOE Patents [OSTI]

    Kulkarni, Anand A.; Subramanian, Ramesh; Sabol, Stephen M.

    2012-08-14

    Abstract A wash-coat (16) for use as a support for an active catalyst species (18) and a catalytic combustor component (10) incorporating such wash-coat. The wash-coat is a solid solution of alumina or alumina-based material (Al.sub.2O.sub.3-0-3 wt % La.sub.2O.sub.3) and a further oxide exhibiting a coefficient of thermal expansion that is lower than that exhibited by alumina. The further oxide may be silicon dioxide (2-30 wt % SiO.sub.2), zirconia silicate (2-30 wt % ZrSiO.sub.4), neodymium oxide (0-4 wt %), titania (Al.sub.2O.sub.3-3-40% TiO.sub.2) or alumina-based magnesium aluminate spinel (Al.sub.2O.sub.3-25 wt % MgO) in various embodiments. The active catalyst species may be palladium and a second metal in a concentration of 10-50% of the concentration of the palladium.

  13. Molybdenum Coatings with Filtration of Plasma Flow

    SciTech Connect (OSTI)

    Gasilin, V. V.; Nezovibat'ko, Y. N.; Shvets, O. M.; Taran, V. S.; Tereshin, V. I.; Timoshenko, A. I.; Zavaleev, V. A.

    2008-03-19

    Deposition of molybdenum coatings in arc discharge with assistance of HF one is analyzed in this paper. To avoid substrate heating to high temperature and micro-arc formation during cleaning process, the surface cleaning was carried out with HF plasma only. For reduction of droplet fraction in plasma the 'freestanding' filter was utilized. As a filter a solenoid was used, which generated a curvilinear (with the angle of 90 deg.) transportation magnetic field. The effective crosssectional area of the plasma flow at which was observed the uniform distribution of the thickness of the applied coating, was equal to 113 sm{sup 2}. The coating on the base of arc discharge, filter and HF-biasing of substrate were deposited on different substrates, including glass and stainless steel.The optical (refractive index) properties of molybdenum films are presented. The reflective characteristics of the obtained molybdenum films in the range of wavelengths from 200 to 700 nm were measured.Molybdenum films were also investigated under the effect of the plasma emission, using an ECR discharge in a simple double-mirror magnetic trap. The time varying negative potential was supplied to sample holder what provided a wide energy distribution of ions bombarded the sample surface in range 30...1500V.

  14. Method of coating the interior surface of hollow objects with a diffusion coating

    DOE Patents [OSTI]

    Knowles, Shawn D.; Senor, David J.; Forbes, Steven V.; Johnson, Roger N.; Hollenberg, Glenn W.

    2005-03-15

    A method for forming a diffusion coating on the interior of surface of a hollow object wherein a filament, extending through a hollow object and adjacent to the interior surface of the object, is provided, with a coating material, in a vacuum. An electrical current is then applied to the filament to resistively heat the filament to a temperature sufficient to transfer the coating material from the filament to the interior surface of the object. The filament is electrically isolated from the object while the filament is being resistively heated. Preferably, the filament is provided as a tungsten filament or molybdenum filament. Preferably, the coating materials are selected from the group consisting of Ag, Al, As, Au, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Dy, Er, Eu, Fe, Ga, Ge, Hg, In, K, Li, Mg, Mn, Na, Ni P, Pb, Pd, Pr, S, Sb, Sc, Se, Si, Sn, Sr, Te, Tl, Y, Yb, Zn, and combinations thereof. The invention additionally allows for the formation of nitrides, hydrides, or carbides of all the possible coating materials, where such compounds exist, by providing a partial pressure of nitrogen, hydrogen, hydrocarbons, or combination thereof, within the vacuum.

  15. NATIONAL ENERGY TECHNOLOGY LABORATORY Technology Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NETL Issues Licenses for its Arc Position Sensing Technology Success Story The U.S. Department of Energy's National Energy Technology Laboratory (NETL) has issued two licenses involving its Arc Position Sensing (APS) technology to KW Associates LLC , an Oregon-based company founded by the technology's inventors. APS technology is a patented, award- winning measurement technology developed for the specialty metals industry to identify arc distribution conditions during arc melting. The unique

  16. NREL: Technology Transfer - Technologies Available for Licensing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies Available for Licensing Photo of NREL scientist in the NREL Hydrogen Lab. NREL's scientists and engineers develop award-winning technologies available for licensing. NREL scientists and engineers produce breakthrough and award-winning renewable energy and energy efficiency technologies that are available for licensing. We have many licensing opportunities for NREL-developed technologies, including our featured LED technologies. To see all our technologies available for licensing,

  17. Distributed Energy Technology Characterization (Desiccant Technologies),

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 2004 | Department of Energy Characterization (Desiccant Technologies), January 2004 Distributed Energy Technology Characterization (Desiccant Technologies), January 2004 The purpose of this report is to characterize desiccant technology and applications, and to show how these technologies can be designed to utilize the available thermal energy from a combined heat and power (CHP) system. This technology characterization is intended to provide decision-makers and system developers

  18. High Impact Technology Catalyst: Technology Deployment Strategies |

    Energy Savers [EERE]

    Department of Energy Catalyst: Technology Deployment Strategies High Impact Technology Catalyst: Technology Deployment Strategies The Energy Department released the High Impact Technology Catalyst: Technology Deployment Strategies to serve as an overview of the HIT Catalyst program activities, including a summary of the selection process undertaken to identify, evaluate and prioritize the current HITs, descriptions of the technologies and markets for each HIT, and plans for deployment. PDF

  19. NETL Technologies Recognized for Technology Development, Transfer |

    Office of Environmental Management (EM)

    Department of Energy Recognized for Technology Development, Transfer NETL Technologies Recognized for Technology Development, Transfer October 25, 2013 - 1:31pm Addthis Did you know? The Federal Laboratory Consortium for Technology Transfer is the nationwide network of federal laboratories that provides the forum to develop strategies and opportunities for linking laboratory mission technologies and expertise with the marketplace. In consonance with the Federal Technology Transfer Act of

  20. Ceramic Technology Project semiannual progress report, October 1992--March 1993

    SciTech Connect (OSTI)

    Johnson, D.R.

    1993-09-01

    This project was developed to meet the ceramic technology requirements of the OTS`s automotive technology programs. Although progress has been made in developing reliable structural ceramics, further work is needed to reduce cost. The work described in this report is organized according to the following work breakdown structure project elements: Materials and processing (monolithics [Si nitride, carbide], ceramic composites, thermal and wear coatings, joining, cost effective ceramic machining), materials design methodology (contact interfaces, new concepts), data base and life prediction (structural qualification, time-dependent behavior, environmental effects, fracture mechanics, nondestructive evaluation development), and technology transfer.