National Library of Energy BETA

Sample records for rapid thermal processing

  1. Rapid thermal processing by stamping

    DOE Patents [OSTI]

    Stradins, Pauls; Wang, Qi

    2013-03-05

    A rapid thermal processing device and methods are provided for thermal processing of samples such as semiconductor wafers. The device has components including a stamp (35) having a stamping surface and a heater or cooler (40) to bring it to a selected processing temperature, a sample holder (20) for holding a sample (10) in position for intimate contact with the stamping surface; and positioning components (25) for moving the stamping surface and the stamp (35) in and away from intimate, substantially non-pressured contact. Methods for using and making such devices are also provided. These devices and methods allow inexpensive, efficient, easily controllable thermal processing.

  2. Rapid low-temperature processing of metal-oxide thin film transistors with combined far ultraviolet and thermal annealing

    SciTech Connect (OSTI)

    Leppniemi, J. Ojanper, K.; Kololuoma, T.; Huttunen, O.-H.; Majumdar, H.; Alastalo, A.; Dahl, J.; Tuominen, M.; Laukkanen, P.

    2014-09-15

    We propose a combined far ultraviolet (FUV) and thermal annealing method of metal-nitrate-based precursor solutions that allows efficient conversion of the precursor to metal-oxide semiconductor (indium zinc oxide, IZO, and indium oxide, In{sub 2}O{sub 3}) both at low-temperature and in short processing time. The combined annealing method enables a reduction of more than 100?C in annealing temperature when compared to thermally annealed reference thin-film transistor (TFT) devices of similar performance. Amorphous IZO films annealed at 250?C with FUV for 5?min yield enhancement-mode TFTs with saturation mobility of ?1?cm{sup 2}/(Vs). Amorphous In{sub 2}O{sub 3} films annealed for 15?min with FUV at temperatures of 180?C and 200?C yield TFTs with low-hysteresis and saturation mobility of 3.2?cm{sup 2}/(Vs) and 7.5?cm{sup 2}/(Vs), respectively. The precursor condensation process is clarified with x-ray photoelectron spectroscopy measurements. Introducing the FUV irradiation at 160?nm expedites the condensation process via in situ hydroxyl radical generation that results in the rapid formation of a continuous metal-oxygen-metal structure in the film. The results of this paper are relevant in order to upscale printed electronics fabrication to production-scale roll-to-roll environments.

  3. Rapid processing of carbon-carbon composites by forced flow-thermal gradient chemical vapor infiltration (FCVI)

    SciTech Connect (OSTI)

    Vaidyaraman, S.; Lackey, W.J.; Agrawal, P.K.; Freeman, G.B.; Langman, M.D.

    1995-10-01

    Carbon fiber-carbon matrix composites were fabricated using the forced flow-thermal gradient chemical vapor infiltration (FCVI) process. Preforms were prepared by stacking 40 layers of plain weave carbon cloth in a graphite holder. The preforms were infiltrated using propylene, propane, and methane. The present work showed that the FCVI process is well suited for fabricating carbon-carbon composites; without optimization of the process, the authors have achieved uniform and thorough densification. Composites with porosities as low as 7% were fabricated in 8--12 h. The highest deposition rate obtained in the present study was {approximately}3 {micro}m/h which is more than an order of magnitude faster than the typical value of 0.1--0.25 {micro}m/h for the isothermal process. It was also found that the use of propylene and propane as reagents resulted in faster infiltration compared to methane.

  4. Methods and compositions for rapid thermal cycling

    DOE Patents [OSTI]

    Beer, Neil Reginald; Benett, William J.; Frank, James M.; Deotte, Joshua R.; Spadaccini, Christopher

    2015-10-27

    The rapid thermal cycling of a material is targeted. A microfluidic heat exchanger with an internal porous medium is coupled to tanks containing cold fluid and hot fluid. Fluid flows alternately from the cold tank and the hot tank into the porous medium, cooling and heating samples contained in the microfluidic heat exchanger's sample wells. A valve may be coupled to the tanks and a pump, and switching the position of the valve may switch the source and direction of fluid flowing through the porous medium. A controller may control the switching of valve positions based on the temperature of the samples and determined temperature thresholds. A sample tray for containing samples to be thermally cycled may be used in conjunction with the thermal cycling system. A surface or internal electrical heater may aid in heating the samples, or may replace the necessity for the hot tank.

  5. Methods and compositions for rapid thermal cycling

    DOE Patents [OSTI]

    Beer, Neil Reginald; Benett, William J; Frank, James M; Deotte, Joshue R; Spadaccini, Christopher

    2015-11-06

    The rapid thermal cycling of a material is targeted. A microfluidic heat exchanger with an internal porous medium is coupled to tanks containing cold fluid and hot fluid. Fluid flows alternately from the cold tank and the hot tank into the porous medium, cooling and heating samples contained in the microfluidic heat exchanger's sample wells. A valve may be coupled to the tanks and a pump, and switching the position of the valve may switch the source and direction of fluid flowing through the porous medium. A controller may control the switching of valve positions based on the temperature of the samples and determined temperature thresholds. A sample tray for containing samples to be thermally cycled may be used in conjunction with the thermal cycling system. A surface or internal electrical heater may aid in heating the samples, or may replace the necessity for the hot tank.

  6. Ceramic thermal barrier coating for rapid thermal cycling applications

    DOE Patents [OSTI]

    Scharman, Alan J.; Yonushonis, Thomas M.

    1994-01-01

    A thermal barrier coating for metal articles subjected to rapid thermal cycling includes a metallic bond coat deposited on the metal article, at least one MCrAlY/ceramic layer deposited on the bond coat, and a ceramic top layer deposited on the MCrAlY/ceramic layer. The M in the MCrAlY material is Fe, Ni, Co, or a mixture of Ni and Co. The ceramic in the MCrAlY/ceramic layer is mullite or Al.sub.2 O.sub.3. The ceramic top layer includes a ceramic with a coefficient of thermal expansion less than about 5.4.times.10.sup.-6 .degree.C.sup.-1 and a thermal conductivity between about 1 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1 and about 1.7 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1.

  7. Rapid Modeling of Power Electronics Thermal Management Technologies: Preprint

    SciTech Connect (OSTI)

    Bennion, K.; Kelly, K.

    2009-08-01

    Describes a method of rapidly evaluating trade-offs associated with alternative packaging configurations and thermal management technologies for power electronics packaging.

  8. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  9. Materials Selection Considerations for Thermal Process Equipment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials Selection Considerations for Thermal Process Equipment: A BestPractices Process Heating Technical Brief Materials Selection Considerations for Thermal Process Equipment: ...

  10. Thermal synthesis apparatus and process

    DOE Patents [OSTI]

    Fincke, James R.; Detering, Brent A.

    2004-11-23

    An apparatus for thermal conversion of one or more reactants to desired end products includes an insulated reactor chamber having a high temperature heater such as a plasma torch at its inlet end and, optionally, a restrictive convergent-divergent nozzle at its outlet end. In a thermal conversion method, reactants are injected upstream from the reactor chamber and thoroughly mixed with the plasma stream before entering the reactor chamber. The reactor chamber has a reaction zone that is maintained at a substantially uniform temperature. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle, which "freezes" the desired end product(s) in the heated equilibrium reaction stage, or is discharged through an outlet pipe without the convergent-divergent nozzle. The desired end products are then separated from the gaseous stream.

  11. Rapid Solar-Thermal Conversion of Biomass to Syngas - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Rapid Solar-Thermal Conversion of Biomass to Syngas Production of synthesis gas or hydrogen by gasification or pyrolysis of biological feedstocks using solar-thermal energy. University of Colorado Contact CU About This Technology Technology Marketing Summary The invention provides processes that perform biomass gasification or pyrolysis for production of hydrogen, synthesis gas, liquid fuels, or other

  12. Investigating coupled thermal-hydrological-mechanical processes...

    Office of Scientific and Technical Information (OSTI)

    processes in geothermal reservoirs Citation Details In-Document Search Title: Investigating coupled thermal-hydrological-mechanical processes in geothermal reservoirs ...

  13. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Massachusetts Institute of Technology (MIT) - Cambridge, MA A new, continuous manufacturing ...

  14. On-line DNA analysis system with rapid thermal cycling

    DOE Patents [OSTI]

    Swerdlow, Harold P.; Wittwer, Carl T.

    1999-01-01

    An apparatus particularly suited for subjecting biological samples to any necessary sample preparation tasks, subjecting the sample to rapid thermal cycling, and then subjecting the sample to subsequent on-line analysis using one or more of a number of analytical techniques. The apparatus includes a chromatography device including an injection means, a chromatography pump, and a chromatography column. In addition, the apparatus also contains a capillary electrophoresis device consisting of a capillary electrophoresis column with an inlet and outlet end, a means of injection, and means of applying a high voltage to cause the differential migration of species of interest through the capillary column. Effluent from the liquid chromatography column passes over the inlet end of the capillary electrophoresis column through a tee structure and when the loading of the capillary electrophoresis column is desired, a voltage supply is activated at a precise voltage and polarity over a specific duration to cause sample species to be diverted from the flowing stream to the capillary electrophoresis column. A laser induced fluorescence detector preferably is used to analyze the products separated while in the electrophoresis column.

  15. On-line DNA analysis system with rapid thermal cycling

    DOE Patents [OSTI]

    Swerdlow, H.P.; Wittwer, C.T.

    1999-08-10

    This application describes an apparatus particularly suited for subjecting biological samples to any necessary sample preparation tasks, subjecting the sample to rapid thermal cycling, and then subjecting the sample to subsequent on-line analysis using one or more of a number of analytical techniques. The apparatus includes a chromatography device including an injection means, a chromatography pump, and a chromatography column. In addition, the apparatus also contains a capillary electrophoresis device consisting of a capillary electrophoresis column with an inlet and outlet end, a means of injection, and means of applying a high voltage to cause the differential migration of species of interest through the capillary column. Effluent from the liquid chromatography column passes over the inlet end of the capillary electrophoresis column through a tee structure and when the loading of the capillary electrophoresis column is desired, a voltage supply is activated at a precise voltage and polarity over a specific duration to cause sample species to be diverted from the flowing stream to the capillary electrophoresis column. A laser induced fluorescence detector preferably is used to analyze the products separated while in the electrophoresis column. 6 figs.

  16. Rapid microfluidic thermal cycler for nucleic acid amplification

    DOE Patents [OSTI]

    Beer, Neil Reginald; Vafai, Kambiz

    2015-10-27

    A system for thermal cycling a material to be thermal cycled including a microfluidic heat exchanger; a porous medium in the microfluidic heat exchanger; a microfluidic thermal cycling chamber containing the material to be thermal cycled, the microfluidic thermal cycling chamber operatively connected to the microfluidic heat exchanger; a working fluid at first temperature; a first system for transmitting the working fluid at first temperature to the microfluidic heat exchanger; a working fluid at a second temperature, a second system for transmitting the working fluid at second temperature to the microfluidic heat exchanger; a pump for flowing the working fluid at the first temperature from the first system to the microfluidic heat exchanger and through the porous medium; and flowing the working fluid at the second temperature from the second system to the heat exchanger and through the porous medium.

  17. Rapid microfluidic thermal cycler for nucleic acid amplification

    DOE Patents [OSTI]

    Beer, Neil Reginald; Vafai, Kambiz

    2015-11-06

    A system for thermal cycling a material to be thermal cycled including a microfluidic heat exchanger; a porous medium in the microfluidic heat exchanger; a microfluidic thermal cycling chamber containing the material to be thermal cycled, the microfluidic thermal cycling chamber operatively connected to the microfluidic heat exchanger; a working fluid at first temperature; a first system for transmitting the working fluid at first temperature to the microfluidic heat exchanger; a working fluid at a second temperature, a second system for transmitting the working fluid at second temperature to the microfluidic heat exchanger; a pump for flowing the working fluid at the first temperature from the first system to the microfluidic heat exchanger and through the porous medium; and flowing the working fluid at the second temperature from the second system to the heat exchanger and through the porous medium.

  18. Method and apparatus for thermal processing of semiconductor substrates

    DOE Patents [OSTI]

    Griffiths, Stewart K.; Nilson, Robert H.; Mattson, Brad S.; Savas, Stephen E.

    2002-01-01

    An improved apparatus and method for thermal processing of semiconductor wafers. The apparatus and method provide the temperature stability and uniformity of a conventional batch furnace as well as the processing speed and reduced time-at-temperature of a lamp-heated rapid thermal processor (RTP). Individual wafers are rapidly inserted into and withdrawn from a furnace cavity held at a nearly constant and isothermal temperature. The speeds of insertion and withdrawal are sufficiently large to limit thermal stresses and thereby reduce or prevent plastic deformation of the wafer as it enters and leaves the furnace. By processing the semiconductor wafer in a substantially isothermal cavity, the wafer temperature and spatial uniformity of the wafer temperature can be ensured by measuring and controlling only temperatures of the cavity walls. Further, peak power requirements are very small compared to lamp-heated RTPs because the cavity temperature is not cycled and the thermal mass of the cavity is relatively large. Increased speeds of insertion and/or removal may also be used with non-isothermal furnaces.

  19. Method and apparatus for thermal processing of semiconductor substrates

    DOE Patents [OSTI]

    Griffiths, Stewart K.; Nilson, Robert H.; Mattson, Brad S.; Savas, Stephen E.

    2000-01-01

    An improved apparatus and method for thermal processing of semiconductor wafers. The apparatus and method provide the temperature stability and uniformity of a conventional batch furnace as well as the processing speed and reduced time-at-temperature of a lamp-heated rapid thermal processor (RTP). Individual wafers are rapidly inserted into and withdrawn from a furnace cavity held at a nearly constant and isothermal temperature. The speeds of insertion and withdrawal are sufficiently large to limit thermal stresses and thereby reduce or prevent plastic deformation of the wafer as it enters and leaves the furnace. By processing the semiconductor wafer in a substantially isothermal cavity, the wafer temperature and spatial uniformity of the wafer temperature can be ensured by measuring and controlling only temperatures of the cavity walls. Further, peak power requirements are very small compared to lamp-heated RTPs because the cavity temperature is not cycled and the thermal mass of the cavity is relatively large. Increased speeds of insertion and/or removal may also be used with non-isothermal furnaces.

  20. List of Solar Thermal Process Heat Incentives | Open Energy Informatio...

    Open Energy Info (EERE)

    List of Solar Thermal Process Heat Incentives Jump to: navigation, search The following contains the list of 211 Solar Thermal Process Heat Incentives. CSV (rows 1 - 211) Incentive...

  1. Rapid Gas Hydrate Formation Process - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Find More Like This Return to Search Rapid Gas Hydrate Formation Process National Energy Technology Laboratory Contact NETL About This Technology Technology Marketing Summary The Department of Energy's National Energy Technology Laboratory (NETL) is seeking collaborative research and licensing partners interested in implementing United States Non-provisional Patent Application entitled "Rapid Gas Hydrate Formation Process." Disclosed in this application is

  2. Dumping pump and treat: rapid cleanups using thermal technology

    SciTech Connect (OSTI)

    Newmark, R.L.; Aines, R.D.

    1997-03-11

    Underground spills of volatile hydrocarbons are often difficult to clean up, especially if the contaminants are present in or below the water table as a separate liquid-organic phase. Excavating and treating the contaminated soil may not be practical or even possible if the affected zone is relatively deep. Merely pumping groundwater has proven to be ineffective because huge amounts of water must be flushed through the contaminated area to clean it; even then the contaminants may not be completely removed. Due to the low solubility of most common contaminants, such pump and treat systems can be expected to take decades to centuries to actually clean a site. Today, many sites are required to pump and treat contaminated groundwater even though there is no expectation that the site will be cleaned. In these cases, the pumps simply control the spread of the contaminant, while requiring a continuous flow of money, paperwork, and management attention. Although pump and treat systems are relatively inexpensive to operate, they represent along term cost. Most importantly, they rarely remove enough contaminant to change the property`s status. Although a pump and treat system can offer compliance in a regulatory sense, it doesn`t solve the site`s liability problem. Thermal methods promise to solve this dilemma by actually cleaning a property in a short time period, thus limiting the period of liability. This may involve cleaning a site to closure during the initial contaminant-removal phase, or removal of the majority of the contaminant so that natural processes such as bioremediation can return the site to pristine condition over a period of years, without further owner intervention. Today`s regulatory environment encourages this approach through efforts such as the brownfields initiatives. In either case, this requires a strong commitment on the part of the site owner. Most if not all the cleanup occurs within the first year or so, and nearly all the cost. In our

  3. Firearm suppressor having enhanced thermal management for rapid heat dissipation

    DOE Patents [OSTI]

    Moss, William C.; Anderson, Andrew T.

    2014-08-19

    A suppressor is disclosed for use with a weapon having a barrel through which a bullet is fired. The suppressor has an inner portion having a bore extending coaxially therethrough. The inner portion is adapted to be secured to a distal end of the barrel. A plurality of axial flow segments project radially from the inner portion and form axial flow paths through which expanding propellant gasses discharged from the barrel flow through. The axial flow segments have radially extending wall portions that define sections which may be filled with thermally conductive material, which in one example is a thermally conductive foam. The conductive foam helps to dissipate heat deposited within the suppressor during firing of the weapon.

  4. Value of solar thermal industrial process heat

    SciTech Connect (OSTI)

    Brown, D.R.; Fassbender, L.L.; Chockie, A.D.

    1986-03-01

    This study estimated the value of solar thermal-generated industrial process heat (IPH) as a function of process heat temperature. The value of solar thermal energy is equal to the cost of producing energy from conventional fuels and equipment if the energy produced from either source provides an equal level of service. This requirement put the focus of this study on defining and characterizing conventional process heat equipment and fuels. Costs (values) were estimated for 17 different design points representing different combinations of conventional technologies, temperatures, and fuels. Costs were first estimated for median or representative conditions at each design point. The cost impact of capacity factor, efficiency, fuel escalation rate, and regional fuel price differences were then evaluated by varying each of these factors within credible ranges.

  5. Method for thermal processing alumina-enriched spinel single crystals

    DOE Patents [OSTI]

    Jantzen, C.M.

    1995-05-09

    A process for age-hardening alumina-rich magnesium aluminum spinel to obtain the desired combination of characteristics of hardness, clarity, flexural strength and toughness comprises selection of the time-temperature pair for isothermal heating followed by quenching. The time-temperature pair is selected from the region wherein the precipitate groups have the characteristics sought. The single crystal spinel is isothermally heated and will, if heated long enough pass from its single phase through two pre-precipitates and two metastable precipitates to a stable secondary phase precipitate within the spinel matrix. Quenching is done slowly at first to avoid thermal shock, then rapidly. 12 figs.

  6. Method for thermal processing alumina-enriched spinel single crystals

    DOE Patents [OSTI]

    Jantzen, Carol M.

    1995-01-01

    A process for age-hardening alumina-rich magnesium aluminum spinel to obtain the desired combination of characteristics of hardness, clarity, flexural strength and toughness comprises selection of the time-temperature pair for isothermal heating followed by quenching. The time-temperature pair is selected from the region wherein the precipitate groups have the characteristics sought. The single crystal spinel is isothermally heated and will, if heated long enough pass from its single phase through two pre-precipitates and two metastable precipitates to a stable secondary phase precipitate within the spinel matrix. Quenching is done slowly at first to avoid thermal shock, then rapidly.

  7. Synthesis report on thermally driven coupled processes

    SciTech Connect (OSTI)

    Hardin, E.L.

    1997-10-15

    The main purpose of this report is to document observations and data on thermally coupled processes for conditions that are expected to occur within and around a repository at Yucca Mountain. Some attempt is made to summarize values of properties (e.g., thermal properties, hydrologic properties) that can be measured in the laboratory on intact samples of the rock matrix. Variation of these properties with temperature, or with conditions likely to be encountered at elevated temperature in the host rock, is of particular interest. However, the main emphasis of this report is on direct observation of thermally coupled processes at various scales. Direct phenomenological observations are vitally important in developing and testing conceptual models. If the mathematical implementation of a conceptual model predicts a consequence that is not observed, either (1) the parameters or the boundary conditions used in the calculation are incorrect or (2) the conceptual basis of the model does not fit the experiment; in either case, the model must be revised. For example, the effective continuum model that has been used in thermohydrology studies combines matrix and fracture flow in a way that is equivalent to an assumption that water is imbibed instantaneously from fractures into adjacent, partially saturated matrix. Based on this approximation, the continuum-flow response that is analogous to fracture flow will not occur until the effective continuum is almost completely saturated. This approximation is not entirely consistent with some of the experimental data presented in this report. This report documents laboratory work and field studies undertaken in FY96 and FY97 to investigate thermally coupled processes such as heat pipes and fracture-matrix coupling. In addition, relevant activities from past years, and work undertaken outside the Yucca Mountain project are summarized and discussed. Natural and artificial analogs are also discussed to provide a convenient source of

  8. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  9. Exploration of LOCOS-type isolation limit using SUPERSILO isolation by rapid thermal nitridation of silicon

    SciTech Connect (OSTI)

    Deleonibus, S.; Martin, F.; Pontcharra, J. du Port de; Tedesco, S. . Dept. de Microelectronique)

    1993-10-01

    The limits for overcoming shrinking localized oxidation of silicon type isolation in the subhalfmicron design rules area are considered: geometric limitations and field implant defect generation are investigated. A super sealed interface local oxidation (SUPERSILO) field isolation process using rapid thermal nitridation of silicon is characterized in terms of morphology, defect density, and electrical performance, With this isolation an encroachment lower than 100 nm is obtained in a large field area of 400 nm finished field oxide. Field oxide thinning and corner encroachment are minimized compared to other conventional isolations and make this process and better candidate for scaling down to 0.7 [mu]m active area pitch design rules. The compatibility with low gate oxide defect density for a thickness as low as 7 nm is demonstrated. Several boron p[sup +] field channel stop implant processes are investigated by characterizing three different scenarios: implanting before field oxidation (classical), through field oxide after the oxidation mask removal (field-retro), and through the poly gate material (poly-retro). In order to avoid defect generation, the retrograde scenarios will be the solution in the future. The poly-retro scenario is the one that reduces boron segregation by a factor of about 10 with respect to the classical scenario and allows high performance without affecting the sustaining voltage. The use of a 0[degree] tilt boron implant at 350 keV through the field oxide and poly gate material stack is shown to be practicable and reproducible.

  10. Tunable photoluminescence of self-assembled GeSi quantum dots by B{sup +} implantation and rapid thermal annealing

    SciTech Connect (OSTI)

    Chen, Yulu; Wu, Shan; Ma, Yinjie; Fan, Yongliang; Yang, Xinju; Zhong, Zhenyang; Jiang, Zuimin

    2014-06-21

    The layered GeSi quantum dots (QDs) are grown on (001) Si substrate by molecular beam epitaxy. The photoluminescence (PL) peak of the as-grown GeSi quantum dots has obvious blue shift and enhancement after processed by ion implantation and rapid thermal annealing. It is indicated that the blue shift is originated from the interdiffusion of Ge and Si at the interface between QDs and the surrounding matrix. The dependence of PL intensity on the excitation power shows that there are the nonradiative centers of shallow local energy levels from the point defects caused by the ion implantation, but not removed by the rapid thermal annealing. The tunable blue shift of the PL position from the 1300?nm to 1500?nm region may have significant application value in the optical communication.

  11. Rapid thermal cycling of metal-supported solid oxide fuel cellmembranes

    SciTech Connect (OSTI)

    Matus, Yuriy B.; De Jonghe, Lutgard C.; Jacobson, Craig P.; Visco, Steven J.

    2004-01-02

    Solid oxide fuel cell (SOFC) membranes were developed in which zirconia-based electrolyte thin films were supported by a composite metal/ceramic electrode, and were subjected to rapid thermal cycling between 200 and 800 C. The effects of this cycling on membrane performance were evaluated. The membranes, not yet optimized for performance, showed a peak power density of 350mW/cm2at 900 C in laboratory-sized SOFCs that was not affected by the thermal cycling. This resistance to cycling degradation is attributed to the close matching of thermal expansion coefficient of the cermet support electrode with that of the zirconia electrolyte.

  12. Thermal casting process for the preparation of membranes

    DOE Patents [OSTI]

    Caneba, G.T.M.; Soong, D.S.

    1985-07-10

    Disclosed is a method for providing anisotropic polymer membrane from a binary polymer/solvent solution using a thermal inversion process. A homogeneous binary solution is cast onto a support and cooled in such a way as to provide a differential in cooling rate across the thickness of the resulting membrane sheet. Isotropic or anisotropic structures of selected porosities can be produced, depending on the initial concentration of polymer in the selected solvent and on the extent of the differential in cooling rate. This differential results in a corresponding gradation in pore size. The method may be modified to provide a working skin by applying a rapid, high-temperature pulse to redissolve a predetermined thickness of the membrane at one of its faces and then freezing the entire structure.

  13. Fabrication of highly textured lithium cobalt oxide films by rapid thermal annealing

    DOE Patents [OSTI]

    Bates, John B.

    2003-05-13

    Systems and methods are described for fabrication of highly textured lithium cobalt oxide films by rapid thermal annealing. A method of forming a lithium cobalt oxide film includes depositing a film of lithium cobalt oxide on a substrate; rapidly heating the film of lithium cobalt oxide to a target temperature; and maintaining the film of lithium cobalt oxide at the target temperature for a target annealing time of at most, approximately 60 minutes. The systems and methods provide advantages because they require less time to implement and are, therefore less costly than previous techniques.

  14. Fabrication of highly textured lithium cobalt oxide films by rapid thermal annealing

    DOE Patents [OSTI]

    Bates, John B.

    2002-01-01

    Systems and methods are described for fabrication of highly textured lithium cobalt oxide films by rapid thermal annealing. A method of forming a lithium cobalt oxide film includes depositing a film of lithium cobalt oxide on a substrate; rapidly heating the film of lithium cobalt oxide to a target temperature; and maintaining the film of lithium cobalt oxide at the target temperature for a target annealing time of at most, approximately 60 minutes. The systems and methods provide advantages because they require less time to implement and are, therefore less costly than previous techniques.

  15. Fabrication of highly textured lithium cobalt oxide films by rapid thermal annealing

    DOE Patents [OSTI]

    Bates, John B.

    2003-04-29

    Systems and methods are described for fabrication of highly textured lithium cobalt oxide films by rapid thermal annealing. A method of forming a lithium cobalt oxide film includes depositing a film of lithium cobalt oxide on a substrate; rapidly heating the film of lithium cobalt oxide to a target temperature; and maintaining the film of lithium cobalt oxide at the target temperature for a target annealing time of at most, approximately 60 minutes. The systems and methods provide advantages because they require less time to implement and are, therefore less costly than previous techniques.

  16. Solar-Thermal Fluid-Wall Reaction Processing

    DOE Patents [OSTI]

    Weimer, A. W.; Dahl, J. K.; Lewandowski, A. A.; Bingham, C.; Raska Buechler, K. J.; Grothe, W.

    2006-04-25

    The present invention provides a method for carrying out high temperature thermal dissociation reactions requiring rapid-heating and short residence times using solar energy. In particular, the present invention provides a method for carrying out high temperature thermal reactions such as dissociation of hydrocarbon containing gases and hydrogen sulfide to produce hydrogen and dry reforming of hydrocarbon containing gases with carbon dioxide. In the methods of the invention where hydrocarbon containing gases are dissociated, fine carbon black particles are also produced. The present invention also provides solar-thermal reactors and solar-thermal reactor systems.

  17. Solar-thermal fluid-wall reaction processing

    DOE Patents [OSTI]

    Weimer, Alan W.; Dahl, Jaimee K.; Lewandowski, Allan A.; Bingham, Carl; Buechler, Karen J.; Grothe, Willy

    2006-04-25

    The present invention provides a method for carrying out high temperature thermal dissociation reactions requiring rapid-heating and short residence times using solar energy. In particular, the present invention provides a method for carrying out high temperature thermal reactions such as dissociation of hydrocarbon containing gases and hydrogen sulfide to produce hydrogen and dry reforming of hydrocarbon containing gases with carbon dioxide. In the methods of the invention where hydrocarbon containing gases are dissociated, fine carbon black particles are also produced. The present invention also provides solar-thermal reactors and solar-thermal reactor systems.

  18. Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets

    Broader source: Energy.gov [DOE]

    Project to develop and validate a continuous manufacturing process for polyethylene fibers and sheets yielding a thermal conductivity value greater than 60 W/m.K.

  19. Pulse thermal processing of functional materials using directed plasma arc

    DOE Patents [OSTI]

    Ott, Ronald D.; Blue, Craig A.; Dudney, Nancy J.; Harper, David C.

    2007-05-22

    A method of thermally processing a material includes exposing the material to at least one pulse of infrared light emitted from a directed plasma arc to thermally process the material, the pulse having a duration of no more than 10 s.

  20. Multicycle rapid thermal annealing optimization of Mg-implanted GaN: Evolution of surface, optical, and structural properties

    SciTech Connect (OSTI)

    Greenlee, Jordan D.; Feigelson, Boris N.; Anderson, Travis J.; Hite, Jennifer K.; Mastro, Michael A.; Eddy, Charles R.; Hobart, Karl D.; Kub, Francis J.; Tadjer, Marko J.

    2014-08-14

    The first step of a multi-cycle rapid thermal annealing process was systematically studied. The surface, structure, and optical properties of Mg implanted GaN thin films annealed at temperatures ranging from 900 to 1200?C were investigated by Raman spectroscopy, photoluminescence, UV-visible spectroscopy, atomic force microscopy, and Nomarski microscopy. The GaN thin films are capped with two layers of in-situ metal organic chemical vapor deposition -grown AlN and annealed in 24 bar of N{sub 2} overpressure to avoid GaN decomposition. The crystal quality of the GaN improves with increasing annealing temperature as confirmed by UV-visible spectroscopy and the full widths at half maximums of the E{sub 2} and A{sub 1} (LO) Raman modes. The crystal quality of films annealed above 1100?C exceeds the quality of the as-grown films. At 1200?C, Mg is optically activated, which is determined by photoluminescence measurements. However, at 1200?C, the GaN begins to decompose as evidenced by pit formation on the surface of the samples. Therefore, it was determined that the optimal temperature for the first step in a multi-cycle rapid thermal anneal process should be conducted at 1150?C due to crystal quality and surface morphology considerations.

  1. Thermal processing system concepts and considerations for RWMC buried waste

    SciTech Connect (OSTI)

    Eddy, T.L.; Kong, P.C.; Raivo, B.D.; Anderson, G.L.

    1992-02-01

    This report presents a preliminary determination of ex situ thermal processing system concepts and related processing considerations for application to remediation of transuranic (TRU)-contaminated buried wastes (TRUW) at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Beginning with top-level thermal treatment concepts and requirements identified in a previous Preliminary Systems Design Study (SDS), a more detailed consideration of the waste materials thermal processing problem is provided. Anticipated waste stream elements and problem characteristics are identified and considered. Final waste form performance criteria, requirements, and options are examined within the context of providing a high-integrity, low-leachability glass/ceramic, final waste form material. Thermal processing conditions required and capability of key systems components (equipment) to provide these material process conditions are considered. Information from closely related companion study reports on melter technology development needs assessment and INEL Iron-Enriched Basalt (IEB) research are considered. Five potentially practicable thermal process system design configuration concepts are defined and compared. A scenario for thermal processing of a mixed waste and soils stream with essentially no complex presorting and using a series process of incineration and high temperature melting is recommended. Recommendations for applied research and development necessary to further detail and demonstrate the final waste form, required thermal processes, and melter process equipment are provided.

  2. Method and apparatus for rapid adjustment of process gas inventory in gaseous diffusion cascades

    DOE Patents [OSTI]

    Dyer, Robert H.; Fowler, Andrew H.; Vanstrum, Paul R.

    1977-01-01

    This invention relates to an improved method and system for making relatively large and rapid adjustments in the process gas

  3. Process and apparatus for thermal enhancement

    DOE Patents [OSTI]

    Burrill, Jr., Charles E.; Smirlock, Martin E.; Krepchin, Ira P.

    1984-06-26

    Thermal treatment apparatus for downhole deployment comprising a combustion stage with an elongated hot wall combustion zone for the substantially complete combustion of the fuel-air mixture and an ignition zone immediately upstream from the combustion zone in which a mixture of atomized liquid fuel and air at or below stoichiometric ratio is ignited; together with a water injection stage immediately downstream from the combustion zone through which essentially partuculate free high temperature combustion products flow from the combustion zone and into which water is sprayed. The resulting mixture of steam and combustion products is injected into an oil formation for enhancing the speed and effectiveness of reservoir response due to physical, chemical, and/or thermal stimulation interactions.

  4. Automated Process for the Fabrication of Highly Customized Thermally

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Insulated Cladding Systems | Department of Energy Automated Process for the Fabrication of Highly Customized Thermally Insulated Cladding Systems Automated Process for the Fabrication of Highly Customized Thermally Insulated Cladding Systems 1 of 2 Resin casting prototype Image: Worcester Polytechnic Institute 2 of 2 A project member completes cuts foam insulating via a process known as computer numerically controlled (CNC) foam cutting. Image: Worcester Polytechnic Institute Lead Performer:

  5. Automated Process for the Fabrication of Highly Customized Thermally

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Insulated Cladding Systems | Department of Energy Automated Process for the Fabrication of Highly Customized Thermally Insulated Cladding Systems Automated Process for the Fabrication of Highly Customized Thermally Insulated Cladding Systems Addthis 1 of 2 Resin casting prototype Image: Worcester Polytechnic Institute 2 of 2 A project member completes cuts foam insulating via a process known as computer numerically controlled (CNC) foam cutting. Image: Worcester Polytechnic Institute

  6. The rotary zone thermal cycler: A low-power system enabling automated rapid PCR

    SciTech Connect (OSTI)

    Bartsch, Michael S.; Edwards, Harrison S.; Lee, Daniel; Moseley, Caroline E.; Tew, Karen E.; Renzi, Ronald F.; Van de Vreugde, James L.; Kim, Hanyoup; Knight, Daniel L.; Sinha, Anupama; Branda, Steven S.; Patel, Kamlesh D.; Wanunu, Meni

    2015-03-31

    In this study, advances in molecular biology, microfluidics, and laboratory automation continue to expand the accessibility and applicability of these methods beyond the confines of conventional, centralized laboratory facilities and into point of use roles in clinical, military, forensic, portable, and field-deployed applications. As a result, there is a growing need to adapt the unit operations of molecular biology such as aliquoting, centrifuging, mixing, and thermal cycling to compact, portable, low-power, and automation-ready formats. Here we present one such adaptation, the rotary zone thermal cycler (RZTC), a novel wheel-based device capable of cycling up to four different fixed-temperature blocks into contact with a stationary 4-microliter capillary-bound sample to realize 1-3 second transitions with steady state heater power of less than 10 W. We further demonstrate the utility of the RZTC for DNA amplification as part of a highly integrated rotary zone PCR (rzPCR) system using low-volume valves and syringe-based fluid handling to automate sample loading and unloading, thermal cycling, and between run cleaning functionalities in a compact, modular form factor. In addition to characterizing the performance of the RZTC and the efficacy of different online cleaning protocols, preliminary results are presented for rapid single-plex PCR, multiplex short tandem repeat (STR) amplification, and second strand cDNA synthesis.

  7. The rotary zone thermal cycler: A low-power system enabling automated rapid PCR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bartsch, Michael S.; Edwards, Harrison S.; Gas Transmission Systems, Walnut Creek, CA; Lee, Daniel; California State Univ., Los Angeles, CA; Moseley, Caroline E.; Tew, Karen E.; Utah State Univ., Logan, UT; Renzi, Ronald F.; Van de Vreugde, James L.; et al

    2015-03-31

    In this study, advances in molecular biology, microfluidics, and laboratory automation continue to expand the accessibility and applicability of these methods beyond the confines of conventional, centralized laboratory facilities and into point of use roles in clinical, military, forensic, portable, and field-deployed applications. As a result, there is a growing need to adapt the unit operations of molecular biology such as aliquoting, centrifuging, mixing, and thermal cycling to compact, portable, low-power, and automation-ready formats. Here we present one such adaptation, the rotary zone thermal cycler (RZTC), a novel wheel-based device capable of cycling up to four different fixed-temperature blocks intomore » contact with a stationary 4-microliter capillary-bound sample to realize 1-3 second transitions with steady state heater power of less than 10 W. We further demonstrate the utility of the RZTC for DNA amplification as part of a highly integrated rotary zone PCR (rzPCR) system using low-volume valves and syringe-based fluid handling to automate sample loading and unloading, thermal cycling, and between run cleaning functionalities in a compact, modular form factor. In addition to characterizing the performance of the RZTC and the efficacy of different online cleaning protocols, preliminary results are presented for rapid single-plex PCR, multiplex short tandem repeat (STR) amplification, and second strand cDNA synthesis.« less

  8. The rotary zone thermal cycler: A low-power system enabling automated rapid PCR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bartsch, Michael S.; Edwards, Harrison S.; Lee, Daniel; Moseley, Caroline E.; Tew, Karen E.; Renzi, Ronald F.; Van de Vreugde, James L.; Kim, Hanyoup; Knight, Daniel L.; Sinha, Anupama; et al

    2015-03-31

    Advances in molecular biology, microfluidics, and laboratory automation continue to expand the accessibility and applicability of these methods beyond the confines of conventional, centralized laboratory facilities and into point of use roles in clinical, military, forensic, and field-deployed applications. As a result, there is a growing need to adapt the unit operations of molecular biology (e.g., aliquoting, centrifuging, mixing, and thermal cycling) to compact, portable, low-power, and automation-ready formats. Here we present one such adaptation, the rotary zone thermal cycler (RZTC), a novel wheel-based device capable of cycling up to four different fixed-temperature blocks into contact with a stationary 4-microlitermorecapillary-bound sample to realize 1-3 second transitions with steady state heater power of less than 10 W. We demonstrate the utility of the RZTC for DNA amplification as part of a highly integrated rotary zone PCR (rzPCR) system that uses low-volume valves and syringe-based fluid handling to automate sample loading and unloading, thermal cycling, and between-run cleaning functionalities in a compact, modular form factor. In addition to characterizing the performance of the RZTC and the efficacy of different online cleaning protocols, we present preliminary results for rapid single-plex PCR, multiplex short tandem repeat (STR) amplification, and second strand cDNA synthesis.less

  9. Rapid gas hydrate formation processes: Will they work?

    SciTech Connect (OSTI)

    Brown, Thomas D.; Taylor, Charles E.; Bernardo, Mark P.

    2010-06-07

    Researchers at DOEs National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the laboratory. Numerous experiments were conducted with various high-pressure cells equipped with instrumentation to study rapid and continuous hydrate formation. The cells ranged in size from 100 mL for screening studies to proof-of-concept studies with NETLs 15-Liter Hydrate Cell. The results from this work demonstrate that the rapid and continuous formation of methane hydrate is possible at predetermined temperatures and pressures within the stability zone of a Methane Hydrate Stability Curve.

  10. Rapid gas hydrate formation processes: Will they work?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brown, Thomas D.; Taylor, Charles E.; Bernardo, Mark P.

    2010-06-07

    Researchers at DOE’s National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the laboratory. Numerous experiments were conducted with various high-pressure cells equipped with instrumentation to study rapid and continuous hydrate formation. The cells ranged in size from 100 mL for screening studies to proof-of-concept studies with NETL’s 15-Liter Hydrate Cell. The results from this work demonstrate that the rapid and continuousmore » formation of methane hydrate is possible at predetermined temperatures and pressures within the stability zone of a Methane Hydrate Stability Curve.« less

  11. Rapidly solidified ceramics: Processing, structure, and magnetic properties

    SciTech Connect (OSTI)

    Kalonji, G.M.; O'Handley, R.C.

    1985-01-01

    Since its initiation in September 1984, work under this contract has progressed in two areas: construction of a gas atomizer for rapid solidification of ceramics; and characterization of rapidly solidified materials in the SrO-Fe{sub 2}O{sub 3}, BaO-Fe{sub 2}O{sub 3}, MnFe{sub 2}O{sub 4}-SiO{sub 2}, and CoFe{sub 2}O{sub 4}-SiO{sub 2} systems. This report summarize this work.

  12. Pulse Thermal Processing of Functional Materials Using a Directed Plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Arc - Energy Innovation Portal Early Stage R&D Early Stage R&D Advanced Materials Advanced Materials Find More Like This Return to Search Pulse Thermal Processing of Functional Materials Using a Directed Plasma Arc Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryUsing pulses of high density infrared light from a directed plasma arc, ORNL researchers invented a method to thermally process thin films and other functional materials on

  13. Solar thermal aerosol flow reaction process

    DOE Patents [OSTI]

    Weimer, Alan W.; Dahl, Jaimee K.; Pitts, J. Roland; Lewandowski, Allan A.; Bingham, Carl; Tamburini, Joseph R.

    2005-03-29

    The present invention provides an environmentally beneficial process using concentrated sunlight to heat radiation absorbing particles to carry out highly endothermic gas phase chemical reactions ultimately resulting in the production of hydrogen or hydrogen synthesis gases.

  14. Thermal Systems Process and Components Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Thermal Systems Process and Components Laboratory at the Energy Systems Integration Facility. The focus of the Thermal Systems Process and Components Laboratory at NREL's Energy Systems Integration Facility (ESIF) is to research, develop, test, and evaluate new techniques for thermal energy storage systems that are relevant to utility-scale concentrating solar power plants. The laboratory holds test systems that can provide heat transfer fluids for the evaluation of heat exchangers and thermal energy storage devices. The existing system provides molten salt at temperatures up to 800 C. This unit is charged with nitrate salt rated to 600 C, but is capable of handling other heat transfer fluid compositions. Three additional test bays are available for future deployment of alternative heat transfer fluids such as hot air, carbon dioxide, or steam systems. The Thermal Systems Process and Components Laboratory performs pilot-scale thermal energy storage system testing through multiple charge and discharge cycles to evaluate heat exchanger performance and storage efficiency. The laboratory equipment can also be utilized to test instrument and sensor compatibility with hot heat transfer fluids. Future applications in the laboratory may include the evaluation of thermal energy storage systems designed to operate with supercritical heat transfer fluids such as steam or carbon dioxide. These tests will require the installation of test systems capable of providing supercritical fluids at temperatures up to 700 C.

  15. Patterned Exfoliation of GaAs Based on Masked Helium Implantation and Subsequent Rapid Thermal Annealing

    SciTech Connect (OSTI)

    Woo, H. J.; Choi, H. W.; Kim, G. D.; Hong, W.; Kim, J. K.

    2009-03-10

    A method of patterning single crystal GaAs based on ion implantation induced selective area exfoliation is suggested. Samples were implanted with 200-500 keV helium ions to a fluence range of 2-4x10{sup 16} He{sup +}/cm{sup 2} at room temperature through masks of Ni mesh (40 {mu}m opening) or stainless steel wire (50 {mu}m in diameter), and subsequent rapid thermal annealing at 350-500{open_square} resulted in expulsion of ion beam exposed material. The influences of ion energy, ion fluence, implantation temperature, subsequent annealing conditions (temperature and ramp rate), and mask pattern and its orientation with GaAs lattice on the patterned exfoliation were examined.

  16. Thermal Modeling of A Friction Bonding Process

    SciTech Connect (OSTI)

    John Dixon; Douglas Burkes; Pavel Medvedev

    2007-10-01

    A COMSOL model capable of predicting temperature evolution during nuclear fuel fabrication is being developed at the Idaho National Laboratory (INL). Fuel plates are fabricated by friction bonding (FB) uranium-molybdenum (U-Mo) alloy foils positioned between two aluminum plates. The ability to predict temperature distribution during fabrication is imperative to ensure good quality bonding without inducing an undesirable chemical reaction between U-Mo and aluminum. A three-dimensional heat transfer model of the FB process implementing shallow pin penetration for cladding monolithic nuclear fuel foils is presented. Temperature distribution during the FB process as a function of fabrication parameters such as weld speed, tool load, and tool rotational frequency are predicted. Model assumptions, settings, and equations are described in relation to standard friction stir welding. Current experimental design for validation and calibration of the model is also demonstrated. Resulting experimental data reveal the accuracy in describing asymmetrical temperature distributions about the tool face. Temperature of the bonded plate drops beneath the pin and is higher on the advancing side than the retreating side of the tool.

  17. Rapid process for producing transparent, monolithic porous glass

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA)

    2006-02-14

    A process for making transparent porous glass monoliths from gels. The glass is produced much faster and in much larger sizes than present technology for making porous glass. The process reduces the cost of making large porous glass monoliths because: 1) the process does not require solvent exchange nor additives to the gel to increase the drying rates, 2) only moderate temperatures and pressures are used so relatively inexpensive equipment is needed, an 3) net-shape glass monoliths are possible using this process. The process depends on the use of temperature to control the partial pressure of the gel solvent in a closed vessel, resulting in controlled shrinking during drying.

  18. Technical resource document for assured thermal processing of wastes

    SciTech Connect (OSTI)

    Farrow, R.L.; Fisk, G.A.; Hartwig, C.M.; Hurt, R.H.; Ringland, J.T.; Swansiger, W.A.

    1994-06-01

    This document is a concise compendium of resource material covering assured thermal processing of wastes (ATPW), an area in which Sandia aims to develop a large program. The ATPW program at Sandia is examining a wide variety of waste streams and thermal processes. Waste streams under consideration include municipal, chemical, medical, and mixed wastes. Thermal processes under consideration range from various incineration technologies to non-incineration processes such as supercritical water oxidation or molten metal technologies. Each of the chapters describes the element covered, discusses issues associated with its further development and/or utilization, presents Sandia capabilities that address these issues, and indicates important connections to other ATPW elements. The division of the field into elements was driven by the team`s desire to emphasize areas where Sandia`s capabilities can lead to major advances and is therefore somewhat unconventional. The report will be valuable to Sandians involved in further ATPW program development.

  19. A simple method for rapidly processing HEU from weapons returns

    SciTech Connect (OSTI)

    McLean, W. II; Miller, P.E.

    1994-01-01

    A method based on the use of a high temperature fluidized bed for rapidly oxidizing, homogenizing and down-blending Highly Enriched Uranium (HEU) from dismantled nuclear weapons is presented. This technology directly addresses many of the most important issues that inhibit progress in international commerce in HEU; viz., transaction verification, materials accountability, transportation and environmental safety. The equipment used to carry out the oxidation and blending is simple, inexpensive and highly portable. Mobile facilities to be used for point-of-sale blending and analysis of the product material are presented along with a phased implementation plan that addresses the conversion of HEU derived from domestic weapons and related waste streams as well as material from possible foreign sources such as South Africa or the former Soviet Union.

  20. Process for fabricating composite material having high thermal conductivity

    DOE Patents [OSTI]

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    2001-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  1. Process management using component thermal-hydraulic function classes

    DOE Patents [OSTI]

    Morman, J.A.; Wei, T.Y.C.; Reifman, J.

    1999-07-27

    A process management expert system where following malfunctioning of a component, such as a pump, for determining system realignment procedures such as for by-passing the malfunctioning component with on-line speeds to maintain operation of the process at full or partial capacity or to provide safe shut down of the system while isolating the malfunctioning component. The expert system uses thermal-hydraulic function classes at the component level for analyzing unanticipated as well as anticipated component malfunctions to provide recommended sequences of operator actions. Each component is classified according to its thermal-hydraulic function, and the generic and component-specific characteristics for that function. Using the diagnosis of the malfunctioning component and its thermal hydraulic class, the expert system analysis is carried out using generic thermal-hydraulic first principles. One aspect of the invention employs a qualitative physics-based forward search directed primarily downstream from the malfunctioning component in combination with a subsequent backward search directed primarily upstream from the serviced component. Generic classes of components are defined in the knowledge base according to the three thermal-hydraulic functions of mass, momentum and energy transfer and are used to determine possible realignment of component configurations in response to thermal-hydraulic function imbalance caused by the malfunctioning component. Each realignment to a new configuration produces the accompanying sequence of recommended operator actions. All possible new configurations are examined and a prioritized list of acceptable solutions is produced. 5 figs.

  2. Process management using component thermal-hydraulic function classes

    DOE Patents [OSTI]

    Morman, James A.; Wei, Thomas Y. C.; Reifman, Jaques

    1999-01-01

    A process management expert system where following malfunctioning of a component, such as a pump, for determining system realignment procedures such as for by-passing the malfunctioning component with on-line speeds to maintain operation of the process at full or partial capacity or to provide safe shut down of the system while isolating the malfunctioning component. The expert system uses thermal-hydraulic function classes at the component level for analyzing unanticipated as well as anticipated component malfunctions to provide recommended sequences of operator actions. Each component is classified according to its thermal-hydraulic function, and the generic and component-specific characteristics for that function. Using the diagnosis of the malfunctioning component and its thermal hydraulic class, the expert system analysis is carried out using generic thermal-hydraulic first principles. One aspect of the invention employs a qualitative physics-based forward search directed primarily downstream from the malfunctioning component in combination with a subsequent backward search directed primarily upstream from the serviced component. Generic classes of components are defined in the knowledge base according to the three thermal-hydraulic functions of mass, momentum and energy transfer and are used to determine possible realignment of component configurations in response to thermal-hydraulic function imbalance caused by the malfunctioning component. Each realignment to a new configuration produces the accompanying sequence of recommended operator actions. All possible new configurations are examined and a prioritized list of acceptable solutions is produced.

  3. Thermal acidization and recovery process for recovering viscous petroleum

    DOE Patents [OSTI]

    Poston, Robert S.

    1984-01-01

    A thermal acidization and recovery process for increasing production of heavy viscous petroleum crude oil and synthetic fuels from subterranean hydrocarbon formations containing clay particles creating adverse permeability effects is described. The method comprises injecting a thermal vapor stream through a well bore penetrating such formations to clean the formation face of hydrocarbonaceous materials which restrict the flow of fluids into the petroleum-bearing formation. Vaporized hydrogen chloride is then injected simultaneously to react with calcium and magnesium salts in the formation surrounding the bore hole to form water soluble chloride salts. Vaporized hydrogen fluoride is then injected simultaneously with its thermal vapor to dissolve water-sensitive clay particles thus increasing permeability. Thereafter, the thermal vapors are injected until the formation is sufficiently heated to permit increased recovery rates of the petroleum.

  4. Role of thermal processes in dewetting of epitaxial Ag(111) film on Si(111)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sanders, Charlotte E.; Zhang, Chendong D.; Kellogg, Gary L.; Shih, Chih-Kang

    2014-08-01

    Epitaxially grown silver (Ag) film on silicon (Si) is an optimal plasmonic device platform, but its technological utility has been limited by its tendency to dewet rapidly under ambient conditions (standard temperature and pressure). The mechanisms driving this dewetting have not heretofore been determined. In our study, scanning probe microscopy and low-energy electron microscopy are used to compare the morphological evolution of epitaxial Ag(111)/Si(111) under ambient conditions with that of similarly prepared films heated under ultra-high vacuum (UHV) conditions. Furthermore, dewetting is seen to be initiated with the formation of pinholes, which might function to relieve strain in the film.more » We find that in the UHV environment, dewetting is determined by thermal processes, and while under ambient conditions, thermal processes are not required. Finally, we conclude that dewetting in ambient conditions is triggered by some chemical process, most likely oxidation.« less

  5. Role of thermal processes in dewetting of epitaxial Ag(111) film on Si(111)

    SciTech Connect (OSTI)

    Sanders, Charlotte E.; Zhang, Chendong D.; Kellogg, Gary L.; Shih, Chih-Kang

    2014-08-01

    Epitaxially grown silver (Ag) film on silicon (Si) is an optimal plasmonic device platform, but its technological utility has been limited by its tendency to dewet rapidly under ambient conditions (standard temperature and pressure). The mechanisms driving this dewetting have not heretofore been determined. In our study, scanning probe microscopy and low-energy electron microscopy are used to compare the morphological evolution of epitaxial Ag(111)/Si(111) under ambient conditions with that of similarly prepared films heated under ultra-high vacuum (UHV) conditions. Furthermore, dewetting is seen to be initiated with the formation of pinholes, which might function to relieve strain in the film. We find that in the UHV environment, dewetting is determined by thermal processes, and while under ambient conditions, thermal processes are not required. Finally, we conclude that dewetting in ambient conditions is triggered by some chemical process, most likely oxidation.

  6. Agricultural Mixed Waster Biorefinery Using Thermal Conversion Process

    SciTech Connect (OSTI)

    2006-08-01

    This Congressionally-mandated project is supporting efforts to develop a demonstration facility that will use the patented Thermal Conversion Process (TCP) to produce fuel, power and chemicals from poultry waste and agricultural wastes such as animal and vegetable grease and wastewater sludge.

  7. Process modeling for the Integrated Thermal Treatment System (ITTS) study

    SciTech Connect (OSTI)

    Liebelt, K.H.; Brown, B.W.; Quapp, W.J.

    1995-09-01

    This report describes the process modeling done in support of the integrated thermal treatment system (ITTS) study, Phases 1 and 2. ITTS consists of an integrated systems engineering approach for uniform comparison of widely varying thermal treatment technologies proposed for treatment of the contact-handled mixed low-level wastes (MLLW) currently stored in the U.S. Department of Energy complex. In the overall study, 19 systems were evaluated. Preconceptual designs were developed that included all of the various subsystems necessary for a complete installation, from waste receiving through to primary and secondary stabilization and disposal of the processed wastes. Each system included the necessary auxiliary treatment subsystems so that all of the waste categories in the complex were fully processed. The objective of the modeling task was to perform mass and energy balances of the major material components in each system. Modeling of trace materials, such as pollutants and radioactive isotopes, were beyond the present scope. The modeling of the main and secondary thermal treatment, air pollution control, and metal melting subsystems was done using the ASPEN PLUS process simulation code, Version 9.1-3. These results were combined with calculations for the remainder of the subsystems to achieve the final results, which included offgas volumes, and mass and volume waste reduction ratios.

  8. Modelling aging effects on a thermal cycling absorption process column

    SciTech Connect (OSTI)

    Laquerbe, C.; Contreras, S.; Demoment, J.

    2008-07-15

    Palladium coated on alumina is used in hydrogen separation systems operated at CEA/Valduc, and more particularly in Thermal Cycling Absorption Process columns. With such materials, tritium decay is known to induce aging effects which have direct side effects on hydrogen isotopes absorption isotherms. Furthermore in a TCAP column, aging occurs in an heterogeneous way. The possible impacts of these intrinsic material evolutions on the separation performances are investigated here through a numerical approach. (authors)

  9. Supporting technology for enhanced oil recovery - EOR thermal processes

    SciTech Connect (OSTI)

    1995-03-01

    This report contains the results of efforts under the six tasks of the Eighth Amendment and Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section.

  10. Thermal model development and validation for rapid filling of high pressure hydrogen tanks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Terry A.; Bozinoski, Radoslav; Ye, Jianjun; Sartor, George; Zheng, Jinyang; Yang, Jian

    2015-06-30

    This paper describes the development of thermal models for the filling of high pressure hydrogen tanks with experimental validation. Two models are presented; the first uses a one-dimensional, transient, network flow analysis code developed at Sandia National Labs, and the second uses the commercially available CFD analysis tool Fluent. These models were developed to help assess the safety of Type IV high pressure hydrogen tanks during the filling process. The primary concern for these tanks is due to the increased susceptibility to fatigue failure of the liner caused by the fill process. Thus, a thorough understanding of temperature changes ofmore » the hydrogen gas and the heat transfer to the tank walls is essential. The effects of initial pressure, filling time, and fill procedure were investigated to quantify the temperature change and verify the accuracy of the models. In this paper we show that the predictions of mass averaged gas temperature for the one and three-dimensional models compare well with the experiment and both can be used to make predictions for final mass delivery. Furthermore, due to buoyancy and other three-dimensional effects, however, the maximum wall temperature cannot be predicted using one-dimensional tools alone which means that a three-dimensional analysis is required for a safety assessment of the system.« less

  11. Thermal model development and validation for rapid filling of high pressure hydrogen tanks

    SciTech Connect (OSTI)

    Johnson, Terry A.; Bozinoski, Radoslav; Ye, Jianjun; Sartor, George; Zheng, Jinyang; Yang, Jian

    2015-06-30

    This paper describes the development of thermal models for the filling of high pressure hydrogen tanks with experimental validation. Two models are presented; the first uses a one-dimensional, transient, network flow analysis code developed at Sandia National Labs, and the second uses the commercially available CFD analysis tool Fluent. These models were developed to help assess the safety of Type IV high pressure hydrogen tanks during the filling process. The primary concern for these tanks is due to the increased susceptibility to fatigue failure of the liner caused by the fill process. Thus, a thorough understanding of temperature changes of the hydrogen gas and the heat transfer to the tank walls is essential. The effects of initial pressure, filling time, and fill procedure were investigated to quantify the temperature change and verify the accuracy of the models. In this paper we show that the predictions of mass averaged gas temperature for the one and three-dimensional models compare well with the experiment and both can be used to make predictions for final mass delivery. Furthermore, due to buoyancy and other three-dimensional effects, however, the maximum wall temperature cannot be predicted using one-dimensional tools alone which means that a three-dimensional analysis is required for a safety assessment of the system.

  12. Advanced Reactors Thermal Energy Transport for Process Industries

    SciTech Connect (OSTI)

    P. Sabharwall; S.J. Yoon; M.G. McKellar; C. Stoots; George Griffith

    2014-07-01

    The operation temperature of advanced nuclear reactors is generally higher than commercial light water reactors and thermal energy from advanced nuclear reactor can be used for various purposes such as liquid fuel production, district heating, desalination, hydrogen production, and other process heat applications, etc. Some of the major technology challenges that must be overcome before the advanced reactors could be licensed on the reactor side are qualification of next generation of nuclear fuel, materials that can withstand higher temperature, improvement in power cycle thermal efficiency by going to combined cycles, SCO2 cycles, successful demonstration of advanced compact heat exchangers in the prototypical conditions, and from the process side application the challenge is to transport the thermal energy from the reactor to the process plant with maximum efficiency (i.e., with minimum temperature drop). The main focus of this study is on doing a parametric study of efficient heat transport system, with different coolants (mainly, water, He, and molten salts) to determine maximum possible distance that can be achieved.

  13. Fracture toughness of plasma-sprayed thermal barrier ceramics: Influence of processing, microstructure, and thermal aging

    SciTech Connect (OSTI)

    Dwivedi, Gopal; Viswanathan, Vaishak; Sampath, Sanjay; Shyam, Amit; Lara-Curzio, Edgar

    2014-06-09

    Fracture toughness has become one of the dominant design parameters that dictates the selection of materials and their microstructure to obtain durable thermal barrier coatings (TBCs). Much progress has been made in characterizing the fracture toughness of relevant TBC compositions in bulk form, and it has become apparent that this property is significantly affected by process-induced microstructural defects. In this investigation, a systematic study of the influence of coating microstructure on the fracture toughness of atmospheric plasma sprayed (APS) TBCs has been carried out. Yttria partially stabilized zirconia (YSZ) coatings were fabricated under different spray process conditions inducing different levels of porosity and interfacial defects. Fracture toughness was measured on free standing coatings in as-processed and thermally aged conditions using the double torsion technique. Results indicate significant variance in fracture toughness among coatings with different microstructures including changes induced by thermal aging. Comparative studies were also conducted on an alternative TBC composition, Gd2Zr2O7 (GDZ), which as anticipated shows significantly lower fracture toughness compared to YSZ. Furthermore, the results from these studies not only point towards a need for process and microstructure optimization for enhanced TBC performance but also a framework for establishing performance metrics for promising new TBC compositions.

  14. Fracture toughness of plasma-sprayed thermal barrier ceramics: Influence of processing, microstructure, and thermal aging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dwivedi, Gopal; Viswanathan, Vaishak; Sampath, Sanjay; Shyam, Amit; Lara-Curzio, Edgar

    2014-06-09

    Fracture toughness has become one of the dominant design parameters that dictates the selection of materials and their microstructure to obtain durable thermal barrier coatings (TBCs). Much progress has been made in characterizing the fracture toughness of relevant TBC compositions in bulk form, and it has become apparent that this property is significantly affected by process-induced microstructural defects. In this investigation, a systematic study of the influence of coating microstructure on the fracture toughness of atmospheric plasma sprayed (APS) TBCs has been carried out. Yttria partially stabilized zirconia (YSZ) coatings were fabricated under different spray process conditions inducing different levelsmore » of porosity and interfacial defects. Fracture toughness was measured on free standing coatings in as-processed and thermally aged conditions using the double torsion technique. Results indicate significant variance in fracture toughness among coatings with different microstructures including changes induced by thermal aging. Comparative studies were also conducted on an alternative TBC composition, Gd2Zr2O7 (GDZ), which as anticipated shows significantly lower fracture toughness compared to YSZ. Furthermore, the results from these studies not only point towards a need for process and microstructure optimization for enhanced TBC performance but also a framework for establishing performance metrics for promising new TBC compositions.« less

  15. Materials performance in prototype Thermal Cycling Absorption Process (TCAP) columns

    SciTech Connect (OSTI)

    Clark, E.A.

    1992-11-21

    Two prototype Thermal Cycling Absorption Process (TCAP) columns have been metallurgically examined after retirement, to determine the causes of failure and to evaluate the performance of the column container materials in this application. Leaking of the fluid heating and cooling subsystems caused retirement of both TCAP columns, not leaking of the main hydrogen-containing column. The aluminum block design TCAP column (ABL block TCAP) used in the Advanced Hydride Laboratory, Building 773-A, failed in one nitrogen inlet tube that was crimped during fabrication, which lead to fatigue crack growth in the tube and subsequent leaking of nitrogen from this tube. The Third Generation stainless steel design TCAP column (Third generation TCAP), operated in 773-A room C-061, failed in a braze joint between the freon heating and cooling tubes (made of copper) and the main stainless steel column. In both cases, stresses from thermal cycling and local constraint likely caused the nucleation and growth of fatigue cracks. No materials compatibility problems between palladium coated kieselguhr (the material contained in the TCAP column) and either aluminum or stainless steel column materials were observed. The aluminum-stainless steel transition junction appeared to be unaffected by service in the AHL block TCAP. Also, no evidence of cracking was observed in the AHL block TCAP in a location expected to experience the highest thermal shock fatigue in this design. It is important to limit thermal stresses caused by constraint in hydride systems designed to work by temperature variation, such as hydride storage beds and TCAP columns.

  16. Materials performance in prototype Thermal Cycling Absorption Process (TCAP) columns

    SciTech Connect (OSTI)

    Clark, E.A.

    1992-11-21

    Two prototype Thermal Cycling Absorption Process (TCAP) columns have been metallurgically examined after retirement, to determine the causes of failure and to evaluate the performance of the column container materials in this application. Leaking of the fluid heating and cooling subsystems caused retirement of both TCAP columns, not leaking of the main hydrogen-containing column. The aluminum block design TCAP column (AHL block TCAP) used in the Advanced Hydride Laboratory, Building 773-A, failed in one nitrogen inlet tube that was crimped during fabrication, which lead to fatigue crack growth in the tube and subsequent leaking of nitrogen from this tube. The Third Generation stainless steel design TCAP column (Third generation TCAP), operated in 773-A room C-061, failed in a braze joint between the freon heating and cooling tubes (made of copper) and the main stainless steel column. In both cases, stresses from thermal cycling and local constraint likely caused the nucleation and growth of fatigue cracks. No materials compatibility problems between palladium coated kieselguhr (the material contained in the TCAP column) and either aluminum or stainless steel column materials were observed. The aluminum-stainless steel transition junction appeared to be unaffected by service in the AHL block TCAP. Also, no evidence of cracking was observed in the AHL block TCAP in a location expected to experience the highest thermal shock fatigue in this design. It is important to limit thermal stresses caused by constraint in hydride systems designed to work by temperature variation, such as hydride storage beds and TCAP columns.

  17. Pulse Thermal Processing for Low Thermal Budget Integration of IGZO Thin Film Transistors

    SciTech Connect (OSTI)

    Noh, Joo Hyon; Joshi, Pooran C.; Kuruganti, Teja; Rack, Philip D.

    2014-11-26

    Pulse thermal processing (PTP) has been explored for low thermal budget integration of indium gallium zinc oxide (IGZO) thin film transistors (TFTs). The IGZO TFTs are exposed to a broadband (0.2-1.4 m) arc lamp radiation spectrum with 100 pulses of 1 msec pulse width. The impact of radiant exposure power on the TFT performance was analyzed in terms of the switching characteristics and bias stress reliability characteristics, respectively. The PTP treated IGZO TFTs with power density of 3.95 kW/cm2 and 0.1 sec total irradiation time showed comparable switching properties, at significantly lower thermal budget, to furnace annealed IGZO TFT. The typical field effect mobility FE, threshold voltage VT, and sub-threshold gate swing S.S were calculated to be 7.8 cm2/ V s, 8.1 V, and 0.22 V/ decade, respectively. The observed performance shows promise for low thermal budget TFT integration on flexible substrates exploiting the large-area, scalable PTP technology.

  18. Pulse Thermal Processing for Low Thermal Budget Integration of IGZO Thin Film Transistors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Noh, Joo Hyon; Joshi, Pooran C.; Kuruganti, Teja; Rack, Philip D.

    2014-11-26

    Pulse thermal processing (PTP) has been explored for low thermal budget integration of indium gallium zinc oxide (IGZO) thin film transistors (TFTs). The IGZO TFTs are exposed to a broadband (0.2-1.4 m) arc lamp radiation spectrum with 100 pulses of 1 msec pulse width. The impact of radiant exposure power on the TFT performance was analyzed in terms of the switching characteristics and bias stress reliability characteristics, respectively. The PTP treated IGZO TFTs with power density of 3.95 kW/cm2 and 0.1 sec total irradiation time showed comparable switching properties, at significantly lower thermal budget, to furnace annealed IGZO TFT. Themore » typical field effect mobility FE, threshold voltage VT, and sub-threshold gate swing S.S were calculated to be 7.8 cm2/ V s, 8.1 V, and 0.22 V/ decade, respectively. The observed performance shows promise for low thermal budget TFT integration on flexible substrates exploiting the large-area, scalable PTP technology.« less

  19. Thermally stable booster explosive and process for manufacture

    DOE Patents [OSTI]

    Quinlin, William T.; Thorpe, Raymond; Lightfoot, James M.

    2006-03-21

    A thermally stable booster explosive and process for the manufacture of the explosive. The product explosive is 2,4,7,9-tetranitro-10H-benzo[4,5]furo[3,2-b]indole (TNBFI). A reactant/solvent such as n-methylpyrrolidone (NMP) or dimethyl formamide (DMF) is made slightly basic. The solution is heated to reduce the water content. The solution is cooled and hexanitrostilbene is added. The solution is heated to a predetermined temperature for a specific time period, cooled, and the product is collected by filtration.

  20. Analysis of Zinc 65 Contamination after Vacuum Thermal Process

    SciTech Connect (OSTI)

    Korinko, Paul S.; Tosten, Michael H.

    2013-01-01

    Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

  1. Continuous Processing of High Thermal Conductivity Fibers and Sheets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Professor Gang Chen, Carl Richard Soderberg Professor of Power Engineering 617-253-0006 (phone), 617-324-5545 (fax) gchen2@mit.edu U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Objective  Plastics are less expensive, lighter, and require less energy to process than metals; however, they have low thermal conductivity values (~0.3 W/mK) 

  2. Three-Dimensional Thermal Tomography Advances Cancer Treatment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treatment. A recent advance in thermal imaging allows more rapid, yet still non-invasive, detection. The process, called three-dimensional thermal tomography, or 3DTT, is...

  3. Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems...

    Office of Scientific and Technical Information (OSTI)

    Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems Citation Details In-Document Search Title: Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems You ...

  4. Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems...

    Office of Scientific and Technical Information (OSTI)

    Conference: Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems Citation Details In-Document Search Title: Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas ...

  5. Effects of rapid thermal annealing on the structural and local atomic properties of ZnO: Ge nanocomposite thin films

    SciTech Connect (OSTI)

    Ceylan, Abdullah Ozcan, Sadan; Rumaiz, Abdul K.; Caliskan, Deniz; Ozbay, Ekmel; Woicik, J. C.

    2015-03-14

    We have investigated the structural and local atomic properties of Ge nanocrystals (Ge-ncs) embedded ZnO (ZnO: Ge) thin films. The films were deposited by sequential sputtering of ZnO and Ge thin film layers on z-cut quartz substrates followed by an ex-situ rapid thermal annealing (RTA) at 600 °C for 30, 60, and 90 s under forming gas atmosphere. Effects of RTA time on the evolution of Ge-ncs were investigated by x-ray diffraction (XRD), scanning electron microscopy (SEM), hard x-ray photoelectron spectroscopy (HAXPES), and extended x-ray absorption fine structure (EXAFS). XRD patterns have clearly shown that fcc diamond phase Ge-ncs of sizes ranging between 18 and 27 nm are formed upon RTA and no Ge-oxide peak has been detected. However, cross-section SEM images have clearly revealed that after RTA process, Ge layers form varying size nanoclusters composed of Ge-ncs regions. EXAFS performed at the Ge K-edge to probe the local atomic structure of the Ge-ncs has revealed that as prepared ZnO:Ge possesses Ge-oxide but subsequent RTA leads to crystalline Ge structure without the oxide layer. In order to study the occupied electronic structure, HAXPES has been utilized. The peak separation between the Zn 2p and Ge 3d shows no significant change due to RTA. This implies little change in the valence band offset due to RTA.

  6. Methods for separation/purification utilizing rapidly cycled thermal swing sorption

    DOE Patents [OSTI]

    Tonkovich, Anna Lee Y.; Monzyk, Bruce F.; Wang, Yong; VanderWiel, David P.; Perry, Steven T.; Fitzgerald, Sean P.; Simmons, Wayne W.; McDaniel, Jeffrey S.; Weller, Jr., Albert E.

    2004-11-09

    The present invention provides apparatus and methods for separating fluid components. In preferred embodiments, the apparatus and methods utilize microchannel devices with small distances for heat and mass transfer to achieve rapid cycle times and surprisingly large volumes of fluid components separated in short times using relatively compact hardware.

  7. Thermal processing of EVA encapsulants and effects of formulation additives

    SciTech Connect (OSTI)

    Pern, F.J.; Glick, S.H.

    1996-05-01

    The authors investigated the in-situ processing temperatures and effects of various formulation additives on the formation of ultraviolet (UV) excitable chromophores, in the thermal lamination and curing of ethylene-vinyl acetate (EVA) encapsulants. A programmable, microprocessor-controlled, double-bag vacuum laminator was used to study two commercial as formulated EVA films, A9918P and 15295P, and solution-cast films of Elvaxrm (EVX) impregnated with various curing agents and antioxidants. The results show that the actual measured temperatures of EVA lagged significantly behind the programmed profiles for the heating elements and were affected by the total thermal mass loaded inside the laminator chamber. The antioxidant Naugard P{trademark}, used in the two commercial EVA formulations, greatly enhances the formation of UV-excitable, short chromophores upon curing, whereas other tested antioxidants show little effect. A new curing agent chosen specifically for the EVA formulation modification produces little or no effect on chromophore formation, no bubbling problems in the glass/EVX/glass laminates, and a gel content of {approximately}80% when cured at programmed 155{degrees}C for 4 min. Also demonstrated is the greater discoloring effect with higher concentrations of curing-generated chromophores.

  8. Synthesis Gas Production by Rapid Solar Thermal Gasification of Corn Stover

    SciTech Connect (OSTI)

    Perkins, C. M.; Woodruff, B.; Andrews, L.; Lichty, P.; Lancaster, B.; Weimer, A. W.; Bingham, C.

    2008-03-01

    Biomass resources hold great promise as renewable fuel sources for the future, and there exists great interest in thermochemical methods of converting these resources into useful fuels. The novel approach taken by the authors uses concentrated solar energy to efficiently achieve temperatures where conversion and selectivity of gasification are high. Use of solar energy removes the need for a combustion fuel and upgrades the heating value of the biomass products. The syngas product of the gasification can be transformed into a variety of fuels useable with today?s infrastructure. Gasification in an aerosol reactor allows for rapid kinetics, allowing efficient utilization of the incident solar radiation and high solar efficiency.

  9. Design and operation of a rapid thermal transient component testing sodium loop

    SciTech Connect (OSTI)

    Crandall, D.L.

    1984-04-16

    A specific problem developed during the design of an on-line sampling system for the Sodium Loop Safety Facility fast breeder reactor experiments. Rapid fluctuations in the sodium temperature, caused by reactor operation and shutdown, exposed the system components to conditions that could result in fatigue failure. A component test loop was designed and built at the Idaho National Engineering Laboratory to allow experimental qualification of component integrity. This paper outlines test system requirements, describes the design and special features, presents test procedures ad relates significant operating experience.

  10. Thermal casting process for the preparation of anisotropic membranes and the resultant membrane

    DOE Patents [OSTI]

    Caneba, Gerard T. M.; Soong, David S.

    1987-01-01

    A method for providing anisotropic polymer membranes from a binary polymer/solvent solution using a thermal inversion process. A homogeneous binary solution is cast onto a support and cooled in such a way as to provide a differential in cooling rate across the thickness of the resulting membrane sheet. Isotropic or anisotropic structures of selected porosities can be produced, depending on the initial concentration of polymer in the selected solvent and on the extent of the differential in cooling rate. This differential results in a corresponding gradation in pore size. The method may be modified to provide a working skin by applying a rapid, high-temperature pulse to redissolve a predetermined thickness of the membrane at one of its faces and then freezing the entire structure.

  11. New processing technique for DEB powder for thermal batteries

    SciTech Connect (OSTI)

    Szwarc, R.; Walton, R.D.

    1980-06-01

    The purpose of this paper is to explore how material processing influences thermal battery performance, and how battery performance can be improved by changes in processing. This discussion is confined to the class of thermal batteries designed by Sandia Laboratories and built under the supervision of General Electric in St. Petersburg, Florida. The electrochemical system employed is: Ca/LiCl-KCl-CaCrO/sub 4//Fe. These batteries are primary reserve batteries which employ a pelletized cell design. Each cell consists of an electrolyte-depolarizer pellet sandwiched between an anode and a heat pellet. The anode employed may be one of two forms: sheet calcium disc, mechanically attached to an iron or steel backing; or a substrate disc of iron or steel on which 3 to 5 mils of calcium had been evaporated. The depolarizer-electrolyte, commonly referred to as DEB, is composed of CaCrO/sub 4/, LiCl-KCl eutectic and SiO/sub 2/ binder powder, which has been blended and pressed into pellets. The DEB pellet serves as electrolyte and as active cathode when the salt becomes molten upon battery activation. The heat pellet serves the dual purpose of providing the heat necessary to activate the battery and as the cathode current collector. The heat pellet is composed of iron powder and KClO/sub 4/. A battery is made up of one or more stacks of about 12 cells connected in series to produce a voltage of 28 to 32 volts. Since activated life requirements for batteries vary from seconds up to one hour, the battery must be well insulated to conserve the heat produced by the ignition of the heat pellets to maintain the electrolyte in a molten state. This insulation is also important to protect sensitive electronic components in contact with the battery case. Because the electrolyte, particularly LiCl, is hygroscopic, the batteries are hermetically sealed in stainless steel cans, and are manufactured in dryrooms maintained at 3% relative humidity or better.

  12. Rapid Thermal Annealing of HWCVD a-Si:H Films: The Effect of the Film Hydrogen Content on the Crystallization Kinetics, Surface Morphology, and Grain Growth

    SciTech Connect (OSTI)

    Mahan, A. H.; Reedy, R. C. Jr.; Ginley, D. S.; Roy, B.; Readey, D. W.

    2005-11-01

    We report the effect of the hydrogen (H) content (CH) on the crystallization kinetics, surface morphology and grain growth for Hot Wire CVD a-Si:H films containing 12.5 and 2.7 at.% H which are crystallized by rapid thermal anneal (RTA). For the high CH film we observe explosive H evolution, with a resultant destruction of the film for RTA temperatures >750 deg C. At RTA temperatures ~600 deg C, both films remain intact with similar morphologies. At this same lower RTA, the incubation and crystallization times decrease, and the grain size as measured by X-Ray Diffraction increases with decreasing film CH. SIMS measurements indicate that a similar film CH (<0.5 at.%) exists in both films when crystallization commences. The benefits of a two-step annealing process for the high CH film are documented.

  13. Supporting technology for enhanced oil recovery for thermal processes

    SciTech Connect (OSTI)

    Reid, T.B.; Bolivar, J.

    1997-12-01

    This report contains the results of efforts under the six tasks of the Ninth Amendment and Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections (for each of the 6 tasks) and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section. The tasks are numbered 62 through 67. The first, second, third, fourth fifth, sixth, seventh, eighth, and ninth reports on Annex IV, [Venezuela MEM/USA-DOE Fossil Energy Report IV-1, IV-2, IV-3, IV-4, IV-5, IV-6, IV-7, and IV-8 (DOE/BETC/SP-83/15, DOE/BC-84/6/SP, DOE/BC-86/2/SP, DOE/BC-87/2/SP, DOE/BC-90/1/SP, DOE/BC-90/1/SP) (DOE/BC-92/1/SP, DOE/BC-93/3/SP, and DOE/BC-95/3/SP)] contain the results from the first 61 tasks. Those reports are dated April 1983, August 1984, March 1986, July 1987, November 1988, October 1991, February 1993, and March 1995 respectively.

  14. Rapid Automated Dissolution and Analysis Techniques for Radionuclides in Recycle Process Streams

    SciTech Connect (OSTI)

    Sudowe, Ralf; Roman, Audrey; Dailey, Ashlee; Go, Elaine

    2013-07-18

    The analysis of process samples for radionuclide content is an important part of current procedures for material balance and accountancy in the different process streams of a recycling plant. The destructive sample analysis techniques currently available necessitate a significant amount of time. It is therefore desirable to develop new sample analysis procedures that allow for a quick turnaround time and increased sample throughput with a minimum of deviation between samples. In particular, new capabilities for rapid sample dissolution and radiochemical separation are required. Most of the radioanalytical techniques currently employed for sample analysis are based on manual laboratory procedures. Such procedures are time- and labor-intensive, and not well suited for situations in which a rapid sample analysis is required and/or large number of samples need to be analyzed. To address this issue we are currently investigating radiochemical separation methods based on extraction chromatography that have been specifically optimized for the analysis of process stream samples. The influence of potential interferences present in the process samples as well as mass loading, flow rate and resin performance is being studied. In addition, the potential to automate these procedures utilizing a robotic platform is evaluated. Initial studies have been carried out using the commercially available DGA resin. This resin shows an affinity for Am, Pu, U, and Th and is also exhibiting signs of a possible synergistic effects in the presence of iron.

  15. Monitoring of thermal enhanced oil recovery processes with electromagnetic methods

    SciTech Connect (OSTI)

    Wilt, M.

    1992-09-01

    Research in applying electromagnetic methods for imaging thermal enhanced oil recovery has progressed significantly during the past eighteen months. Working together with researchers at Lawrence Berkeley Laboratory (LBL) and supported by a group of industrial sponsors we have focused our effort on field system development and doing field surveys connected with EOR operations. Field surveys were recently completed at the Lost Hills No.3 oil field and at UC Richmond Field station. At Lost Hills, crosshole EM data sets were collected before a new phase of steam injection for EOR and again four months after the onset of steaming. The two data sets were nearly identical suggesting that very little steam had been injected into this borehole. This is in accord with the operators records which indicate injectivity problems with this particular well. At Richmond we conducted a salt water injection monitoring experiment where 50,000 gallons of salt water were injected in a shallow aquifer and crosshole EM data were collected using the injection well and several observation wells. We applied the imaging code to some of the collected data and produced an image showing that the salt water slug has propagated 8--10 m from the injector into the aquifer. This result is partially confirmed by prior calculations and well logging data. Applying the EM methods to the problem of oil field characterization essentially means extending the borehole resistivity log into the region between wells. Since the resistivity of a sedimentary environment is often directly dependent on the fluids in the rock the knowledge of the resistivity distribution within an oil field can be invaluable for finding missed or bypassed oil or for mapping the overall structure. With small modification the same methods used for mapping EOR process can be readily applied to determining the insitu resistivity structure.

  16. Experience base for Radioactive Waste Thermal Processing Systems: A preliminary survey

    SciTech Connect (OSTI)

    Mayberry, J.; Geimer, R.; Gillins, R.; Steverson, E.M.; Dalton, D.; Anderson, G.L.

    1992-04-01

    In the process of considering thermal technologies for potential treatment of the Idaho National Engineering Laboratory mixed transuranic contaminated wastes, a preliminary survey of the experience base available from Radioactive Waste Thermal Processing Systems is reported. A list of known commercial radioactive waste facilities in the United States and some international thermal treatment facilities are provided. Survey focus is upon the US Department of Energy thermal treatment facilities. A brief facility description and a preliminary summary of facility status, and problems experienced is provided for a selected subset of the DOE facilities.

  17. Effect of rapid thermal annealing temperature on the dispersion of Si nanocrystals in SiO{sub 2} matrix

    SciTech Connect (OSTI)

    Saxena, Nupur Kumar, Pragati; Gupta, Vinay

    2015-05-15

    Effect of rapid thermal annealing temperature on the dispersion of silicon nanocrystals (Si-NCs) embedded in SiO{sub 2} matrix grown by atom beam sputtering (ABS) method is reported. The dispersion of Si NCs in SiO{sub 2} is an important issue to fabricate high efficiency devices based on Si-NCs. The transmission electron microscopy studies reveal that the precipitation of excess silicon is almost uniform and the particles grow in almost uniform size upto 850 C. The size distribution of the particles broadens and becomes bimodal as the temperature is increased to 950 C. This suggests that by controlling the annealing temperature, the dispersion of Si-NCs can be controlled. The results are supported by selected area diffraction (SAED) studies and micro photoluminescence (PL) spectroscopy. The discussion of effect of particle size distribution on PL spectrum is presented based on tight binding approximation (TBA) method using Gaussian and log-normal distribution of particles. The study suggests that the dispersion and consequently emission energy varies as a function of particle size distribution and that can be controlled by annealing parameters.

  18. Process of making cryogenically cooled high thermal performance crystal optics

    DOE Patents [OSTI]

    Kuzay, T.M.

    1992-06-23

    A method is disclosed for constructing a cooled optic wherein one or more cavities are milled, drilled or formed using casting or ultrasound laser machining techniques in a single crystal base and filled with porous material having high thermal conductivity at cryogenic temperatures. A non-machined strain-free single crystal can be bonded to the base to produce superior optics. During operation of the cooled optic, N[sub 2] is pumped through the porous material at a sub-cooled cryogenic inlet temperature and with sufficient system pressure to prevent the fluid bulk temperature from reaching saturation. 7 figs.

  19. Process of making cryogenically cooled high thermal performance crystal optics

    DOE Patents [OSTI]

    Kuzay, Tuncer M.

    1992-01-01

    A method for constructing a cooled optic wherein one or more cavities are milled, drilled or formed using casting or ultrasound laser machining techniques in a single crystal base and filled with porous material having high thermal conductivity at cryogenic temperatures. A non-machined strain-free single crystal can be bonded to the base to produce superior optics. During operation of the cooled optic, N.sub.2 is pumped through the porous material at a sub-cooled cryogenic inlet temperature and with sufficient system pressure to prevent the fluid bulk temperature from reaching saturation.

  20. Thermal and Non-thermal Physiochemical Processes in Nanoscale Films of Amorphous Solid Water

    SciTech Connect (OSTI)

    Smith, R. Scott; Petrik, Nikolay G.; Kimmel, Gregory A.; Kay, Bruce D.

    2012-01-17

    Amorphous solid water (ASW) is a metastable form of water created by vapor deposition onto a cold substrate (typically less than 130 K). Since this unusual form of water only exists on earth in laboratories with highly specialized equipment, it is fair to ask why there is any interest in studying this esoteric material. Much of the scientific interest involves using ASW as a model system to explore the physical and reactive properties of liquid water and aqueous solutions. Other researchers are interested in ASW because it is believed to be the predominate form of water in the extreme cold temperatures found in many astrophysical and planetary environments. In addition, ASW is a convenient model system for studying the stability of metastable systems (glasses) and the properties of highly porous materials. A fundamental understanding of such properties has applications in a diverse range of disciplines including cryobiology, food science, pharmaceuticals, astrophysics and nuclear waste storage among others.There exist several excellent reviews on the properties of ASW and supercooled liquid water and a new comprehensive review is beyond the scope of this Account. Instead, we focus on our research over the past 15 years using molecular beams and surface science techniques to probe the thermal and non thermal properties of nanoscale films of ASW. We use molecular beams to precisely control the deposition conditions (flux, incident, energy, incident angle) to create compositionally-tailored, nanoscale films of ASW at low temperatures. To study the transport properties (viscosity, diffusivity), the amorphous films can be heated above their glass transition temperatures, Tg, at which time they transform into deeply supercooled liquids prior to crystallization. The advantage of this approach is that at temperatures near Tg the viscosity is approximately 15 orders of magnitude larger than a normal liquid, and therefore the crystallization kinetics are dramatically slowed

  1. Automated Process for the Fabrication of Highly Customized Thermally...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Image: Worcester Polytechnic Institute 2 of 2 A project member completes cuts foam insulating via a process known as computer numerically controlled (CNC) foam cutting. Image: ...

  2. Automated Process for the Fabrication of Highly Customized Thermally...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Funding Opportunity Announcement: Small Business Technology Transfer Phase I, Topic 3b ... The fragmented retrofitting process and onsite construction methods often result in wall ...

  3. Engineering process instructions and development summary MC3642 thermal battery

    SciTech Connect (OSTI)

    Jacobs, D.

    1981-06-01

    The MC3642 is a dual channel thermal battery used on the DE1010/W85 Command Disable Controller. It utilizes the CalCaCrO{sub 4} electrochemical system. The electrical requirements of this battery are as follows: RISE TIME PEAK VOLTAGE ACTIVE LIFE LOAD Channel 1 - 1.0 Sec. Max. 34 Volts 10 Sec. Min. 40.0 Ohms to 20 Volts above 20 Volts Channel 2 - .350 Sec. Max. 42 Volts 10 MSec. Min. 6.5 Ohms to 23 Volts above 23 Volts The battery consists of 14 cells connected in series (Channel 2) and 12 cells connected in series (Channel 1). Each cell is composed of an anode fabricated from a bimetallic sheet (0.005{double_prime} thick calcium on 0.005{double_prime} thick iron substrate), a depolarizer-electrolyte-binder (DEB) pellet and a heat pellet. Activation is achieved by mechanical primer. Optimum battery performance is achieved with a 35155/10 DEB pellet weighing .80g and a heat pellet, weighing 1.30 grams, of 88/12 heat powder.

  4. CFD Modeling of Thermal Effects of Nuclear Waste Vitrification Processes

    SciTech Connect (OSTI)

    Rayner, Chris; Soltani, Mehdi; Barringer, Chris; Knight, Kelly

    2006-07-01

    The Waste Treatment Plant (WTP) at Hanford, WA will vitrify nuclear waste stored at the DOE Hanford facility. The vitrification process will take place in two large concrete buildings where the glass is poured into stainless steel canisters or containers and allowed to cool. Computational Fluid Dynamics (CFD) was used extensively to calculate the effects of the heat released by molten glass as it is poured and cooled, on the HVAC system and the building structure. CFD studies of the glass cooling in these facilities were used to predict canister temperatures, HVAC air temperatures, concrete temperatures and insulation requirements, and design temperatures for canister handling equipment and instrumentation at various stages of the process. These predictions provided critical input in the design of the HVAC system, specification of insulation, the design of canister handling equipment, and the selection of instrumentation. (authors)

  5. A RAPIDLY EVOLVING REGION IN THE GALACTIC CENTER: WHY S-STARS THERMALIZE AND MORE MASSIVE STARS ARE MISSING

    SciTech Connect (OSTI)

    Chen, Xian; Amaro-Seoane, Pau E-mail: Pau.Amaro-Seoane@aei.mpg.de

    2014-05-10

    The existence of ''S-stars'' within a distance of 1'' from Sgr A* contradicts our understanding of star formation, due to Sgr A* 's forbiddingly violent environment. A suggested possibility is that they form far away and were brought in by some fast dynamical process, since they are young. Nonetheless, all conjectured mechanisms either fail to reproduce their eccentricities—without violating their young age—or cannot explain the problem of {sup i}nverse mass segregation{sup :} the fact that lighter stars (the S-stars) are closer to Sgr A* and more massive ones, Wolf-Rayet (WR) and O-stars, are farther out. In this Letter we propose that the mechanism responsible for both the distribution of the eccentricities and the paucity of massive stars is the Kozai-Lidov-like resonance induced by a sub-parsec disk recently discovered in the Galactic center. Considering that the disk probably extended to a smaller radius in the past, we show that in as short as (a few) 10{sup 6} yr, the stars populating the innermost 1'' region would redistribute in angular-momentum space and recover the observed ''super-thermal'' distribution. Meanwhile, WR and O-stars in the same region intermittently attain ample eccentricities that will lead to their tidal disruptions by the central massive black hole. Our results provide new evidences that Sgr A* was powered several millions years ago by an accretion disk as well as by tidal stellar disruptions.

  6. NREL: Process Development and Integration Laboratory - Processing in the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Processing Platform Processing in the Atmospheric Processing Platform This page provides details on processing in the Atmospheric Processing platform. Photo of a window of a glove box, showing four rubber gloves extending outward. Sample preparation glove box in the Atmospheric Processing platform. Sample Preparation Box The sample preparation box allows samples to be loaded into platens and prepared for further processing. Large-Area Rapid Thermal Processing This rapid thermal

  7. Composite material having high thermal conductivity and process for fabricating same

    DOE Patents [OSTI]

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    1998-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  8. Composite material having high thermal conductivity and process for fabricating same

    DOE Patents [OSTI]

    Colella, N.J.; Davidson, H.L.; Kerns, J.A.; Makowiecki, D.M.

    1998-07-21

    A process is disclosed for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost. 7 figs.

  9. Solar-Thermal Fluid-Wall Reaction Processing - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Solar-Thermal Fluid-Wall Reaction Processing University of Colorado National Renewable Energy Laboratory Contact CU About This Technology Technology Marketing Summary Currently most hydrogen is produced through a process of heating natural gas with water vapor called steam reforming. This process requires energy to heat the gasses and produces greenhouse gases such as CO2 as its byproducts. These conditions

  10. Rapidly solidified ceramics: Processing, structure, and magnetic properties. Progress report, September 1984--January 1985

    SciTech Connect (OSTI)

    Kalonji, G.M.; O`Handley, R.C.

    1985-12-31

    Since its initiation in September 1984, work under this contract has progressed in two areas: construction of a gas atomizer for rapid solidification of ceramics; and characterization of rapidly solidified materials in the SrO-Fe{sub 2}O{sub 3}, BaO-Fe{sub 2}O{sub 3}, MnFe{sub 2}O{sub 4}-SiO{sub 2}, and CoFe{sub 2}O{sub 4}-SiO{sub 2} systems. This report summarize this work.

  11. THERMODYNAMIC CONSIDERATIONS FOR THERMAL WATER SPLITTING PROCESSES AND HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    J. E. O'Brien

    2008-11-01

    A general thermodynamic analysis of hydrogen production based on thermal water splitting processes is presented. Results of the analysis show that the overall efficiency of any thermal water splitting process operating between two temperature limits is proportional to the Carnot efficiency. Implications of thermodynamic efficiency limits and the impacts of loss mechanisms and operating conditions are discussed as they pertain specifically to hydrogen production based on high-temperature electrolysis. Overall system performance predictions are also presented for high-temperature electrolysis plants powered by three different advanced nuclear reactor types, over their respective operating temperature ranges.

  12. Process to improve boiler operation by supplemental firing with thermally beneficiated low rank coal

    DOE Patents [OSTI]

    Sheldon, Ray W.

    2001-01-01

    The invention described is a process for improving the performance of a commercial coal or lignite fired boiler system by supplementing its normal coal supply with a controlled quantity of thermally beneficiated low rank coal, (TBLRC). This supplemental TBLRC can be delivered either to the solid fuel mill (pulverizer) or directly to the coal burner feed pipe. Specific benefits are supplied based on knowledge of equipment types that may be employed on a commercial scale to complete the process. The thermally beneficiated low rank coal can be delivered along with regular coal or intermittently with regular coal as the needs require.

  13. Impact of pulse thermal processing on the properties of inkjet printed metal and flexible sensors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Joshi, Pooran C.; Kuruganti, Teja; Killough, Stephen M.

    2015-03-11

    In this paper, we report on the low temperature processing of environmental sensors employing pulse thermal processing (PTP) technique to define a path toward flexible sensor technology on plastic, paper, and fabric substrates. Inkjet printing and pulse thermal processing technique were used to realize mask-less, additive integration of low-cost sensors on polymeric substrates with specific focus on temperature, humidity, and strain sensors. The printed metal line performance was evaluated in terms of the electrical conductivity characteristics as a function of post-deposition thermal processing conditions. The PTP processed Ag metal lines exhibited high conductivity with metal sheet resistance values below 100more » mΩ/{whitesquare} using a pulse width as short as 250 μs. The flexible temperature and relative humidity sensors were defined on flexible polyimide substrates by direct printing of Ag metal structures. The printed resistive temperature sensor and capacitive humidity sensor were characterized for their sensitivity with focus on future smart-building applications. Strain gauges were printed on polyimide substrate to determine the mechanical properties of the silver nanoparticle films. Finally, the observed electrical properties of the printed metal lines and the sensitivity of the flexible sensors show promise for the realization of a high performance print-on-demand technology exploiting low thermal-budget PTP technique.« less

  14. The origin of thermal component in the transverse momentum spectra in high energy hadronic processes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bylinkin, Alexander A.; Kharzeev, Dmitri E.; Rostovtsev, Andrei A.

    2014-12-15

    The transverse momentum spectra of hadrons produced in high energy collisions can be decomposed into two components: the exponential ("thermal") and the power ("hard") ones. Recently, the H1 Collaboration has discovered that the relative strength of these two components in Deep Inelastic Scattering (DIS) depends drastically upon the global structure of the event - namely, the exponential component is absent in the diffractive events characterized by a rapidity gap. We discuss the possible origin of this effect and speculate that it is linked to confinement. Specifically, we argue that the thermal component is due to the effective event horizon introducedmore » by the confining string, in analogy to the Hawking-Unruh effect. In diffractive events, the t-channel exchange is color-singlet and there is no fragmenting string - so the thermal component is absent. The slope of the soft component of the hadron spectrum in this picture is determined by the saturation momentum that drives the deceleration in the color field, and thus the Hawking-Unruh temperature. We analyze the data on non-diffractive pp collisions and find that the slope of the thermal component of the hadron spectrum is indeed proportional to the saturation momentum.« less

  15. The origin of thermal component in the transverse momentum spectra in high energy hadronic processes

    SciTech Connect (OSTI)

    Bylinkin, Alexander A.; Kharzeev, Dmitri E.; Rostovtsev, Andrei A.

    2014-12-15

    The transverse momentum spectra of hadrons produced in high energy collisions can be decomposed into two components: the exponential ("thermal") and the power ("hard") ones. Recently, the H1 Collaboration has discovered that the relative strength of these two components in Deep Inelastic Scattering (DIS) depends drastically upon the global structure of the event - namely, the exponential component is absent in the diffractive events characterized by a rapidity gap. We discuss the possible origin of this effect and speculate that it is linked to confinement. Specifically, we argue that the thermal component is due to the effective event horizon introduced by the confining string, in analogy to the Hawking-Unruh effect. In diffractive events, the t-channel exchange is color-singlet and there is no fragmenting string - so the thermal component is absent. The slope of the soft component of the hadron spectrum in this picture is determined by the saturation momentum that drives the deceleration in the color field, and thus the Hawking-Unruh temperature. We analyze the data on non-diffractive pp collisions and find that the slope of the thermal component of the hadron spectrum is indeed proportional to the saturation momentum.

  16. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Use of Laser Engineered Net Shaping for Rapid Manufacturing of Dies with Protective Coatings and Improved Thermal Management

    SciTech Connect (OSTI)

    Brevick, Jerald R.

    2014-06-13

    In the high pressure die casting process, molten metal is introduced into a die cavity at high pressure and velocity, enabling castings of thin wall section and complex geometry to be obtained. Traditional die materials have been hot work die steels, commonly H13. Manufacture of the dies involves machining the desired geometry from monolithic blocks of annealed tool steel, heat treating to desired hardness and toughness, and final machining, grinding and polishing. The die is fabricated with internal water cooling passages created by drilling. These materials and fabrication methods have been used for many years, however, there are limitations. Tool steels have relatively low thermal conductivity, and as a result, it takes time to remove the heat from the tool steel via the drilled internal water cooling passages. Furthermore, the low thermal conductivity generates large thermal gradients at the die cavity surfaces, which ultimately leads to thermal fatigue cracking on the surfaces of the die steel. The high die surface temperatures also promote the metallurgical bonding of the aluminum casting alloy to the surface of the die steel (soldering). In terms of process efficiency, these tooling limitations reduce the number of die castings that can be made per unit time by increasing cycle time required for cooling, and increasing downtime and cost to replace tooling which has failed either by soldering or by thermal fatigue cracking (heat checking). The objective of this research was to evaluate the feasibility of designing, fabricating, and testing high pressure die casting tooling having properties equivalent to H13 on the surface in contact with molten casting alloy - for high temperature and high velocity molten metal erosion resistance – but with the ability to conduct heat rapidly to interior water cooling passages. A layered bimetallic tool design was selected, and the design evaluated for thermal and mechanical performance via finite element analysis. H13 was

  17. MC3755 Thermal Battery Lot No. 2 production summary and engineering process instruction manual

    SciTech Connect (OSTI)

    Jacobs, D.

    1989-04-27

    Production of MC3755 Thermal Battery Lot No. 2 was performed at GE Neutron Devices (GEND) in the Power Sources Development Laboratory. This report documents the results of the production build and includes an overall review of the production process, lot performance data, and the engineering process instruction manual. The overall production yield was 92%, all performance specifications were met within significant margin. 5 figs., 4 tabs.

  18. Effects Of Thermal Exchange On Material Flow During Steel Thixoextrusion Process

    SciTech Connect (OSTI)

    Becker, Eric; Gu Guochao; Langlois, Laurent; Bigot, Regis; Pesci, Raphael

    2011-01-17

    Semisolid processing is an innovative technology for near net-shape production of components, where the metallic alloys are processed in the semisolid state. Taking advantage of the thixotropic behavior of alloys in the semisolid state, significant progress has been made in semisolid processing. However, the consequences of such behavior on the flow during thixoforming are still not completely understood. To explore and better understand the influence of the different parameters on material flow during thixoextrusion process, thixoextrusion experiments were performed using the low carbon steel C38. The billet was partially melted at high solid fraction. Effects of various process parameters including the initial billet temperature, the temperature of die, the punch speed during process and the presence of a Ceraspray layer at the interface of tool and billet were investigated through experiments and simulation. After analyzing the results thus obtained, it was identified that the aforementioned parameters mainly affect thermal exchanges between die and part. The Ceraspray layer not only plays a lubricant role, but also acts as a thermal barrier at the interface of tool and billet. Furthermore, the thermal effects can affect the material flow which is composed of various distinct zones.

  19. A low thermal impact annealing process for SiO{sub 2}-embedded Si nanocrystals with optimized interface quality

    SciTech Connect (OSTI)

    Hiller, Daniel Gutsch, Sebastian; Hartel, Andreas M.; Zacharias, Margit; Löper, Philipp; Gebel, Thoralf

    2014-04-07

    Silicon nanocrystals (Si NCs) for 3rd generation photovoltaics or optoelectronic applications can be produced by several industrially compatible physical or chemical vapor deposition technologies. A major obstacle for the integration into a fabrication process is the typical annealing to form and crystallize these Si quantum dots (QDs) which involves temperatures ≥1100  °C for 1 h. This standard annealing procedure allows for interface qualities that correspond to more than 95% dangling bond defect free Si NCs. We study the possibilities to use rapid thermal annealing (RTA) and flash lamp annealing to crystallize the Si QDs within seconds or milliseconds at high temperatures. The Si NC interface of such samples exhibits huge dangling bond defect densities which makes them inapplicable for photovoltaics or optoelectronics. However, if the RTA high temperature annealing is combined with a medium temperature inert gas post-annealing and a H{sub 2} passivation, luminescent Si NC fractions of up to 90% can be achieved with a significantly reduced thermal load. A new figure or merit, the relative dopant diffusion length, is introduced as a measure for the impact of a Si NC annealing procedure on doping profiles of device structures.

  20. Modeling of thermally driven hydrological processes in partially saturated fractured rock

    SciTech Connect (OSTI)

    Tsang, Yvonne; Birkholzer, Jens; Mukhopadhyay, Sumit

    2009-03-15

    This paper is a review of the research that led to an in-depth understanding of flow and transport processes under strong heat stimulation in fractured, porous rock. It first describes the anticipated multiple processes that come into play in a partially saturated, fractured porous volcanic tuff geological formation, when it is subject to a heat source such as that originating from the decay of radionuclides. The rationale is then given for numerical modeling being a key element in the study of multiple processes that are coupled. The paper outlines how the conceptualization and the numerical modeling of the problem evolved, progressing from the simplified to the more realistic. Examples of numerical models are presented so as to illustrate the advancement and maturation of the research over the last two decades. The most recent model applied to in situ field thermal tests is characterized by (1) incorporation of a full set of thermal-hydrological processes into a numerical simulator, (2) realistic representation of the field test geometry, in three dimensions, and (3) use of site-specific characterization data for model inputs. Model predictions were carried out prior to initiation of data collection, and the model results were compared to diverse sets of measurements. The approach of close integration between modeling and field measurements has yielded a better understanding of how coupled thermal hydrological processes produce redistribution of moisture within the rock, which affects local permeability values and subsequently the flow of liquid and gases. The fluid flow in turn will change the temperature field. We end with a note on future research opportunities, specifically those incorporating chemical, mechanical, and microbiological factors into the study of thermal and hydrological processes.

  1. Combining nanocalorimetry and dynamic transmission electron microscopy for in situ characterization of materials processes under rapid heating and cooling

    SciTech Connect (OSTI)

    Grapes, Michael D.; LaGrange, Thomas; Reed, Bryan W.; Campbell, Geoffrey H.; Friedman, Lawrence H.; LaVan, David A.; Weihs, Timothy P.

    2014-08-15

    Nanocalorimetry is a chip-based thermal analysis technique capable of analyzing endothermic and exothermic reactions at very high heating and cooling rates. Here, we couple a nanocalorimeter with an extremely fast in situ microstructural characterization tool to identify the physical origin of rapid enthalpic signals. More specifically, we describe the development of a system to enable in situ nanocalorimetry experiments in the dynamic transmission electron microscope (DTEM), a time-resolved TEM capable of generating images and electron diffraction patterns with exposure times of 30 ns500 ns. The full experimental system consists of a modified nanocalorimeter sensor, a custom-built in situ nanocalorimetry holder, a data acquisition system, and the DTEM itself, and is capable of thermodynamic and microstructural characterization of reactions over a range of heating rates (10{sup 2} K/s10{sup 5} K/s) accessible by conventional (DC) nanocalorimetry. To establish its ability to capture synchronized calorimetric and microstructural data during rapid transformations, this work describes measurements on the melting of an aluminum thin film. We were able to identify the phase transformation in both the nanocalorimetry traces and in electron diffraction patterns taken by the DTEM. Potential applications for the newly developed system are described and future system improvements are discussed.

  2. Materials Selection Considerations for Thermal Process Equipment: A BestPractices Process Heating Technical Brief

    Broader source: Energy.gov [DOE]

    This technical brief is a guide to selecting high-temperature metallic materials for use in process heating applications such as burners, electrical heating elements, material handling, load support, and heater tubes, etc.

  3. Experimental investigation for hydrogen and deuterium separation by thermal cycling absorption process

    SciTech Connect (OSTI)

    Guangda, L.; Guoqiang, J.; Cansheng, S.

    1995-10-01

    The Thermal Cycling Absorption Process (TCAP) is a semicontinuous gas chromatographic process for hydrogen isotope separation by which the experiment for hydrogen-deuterium separation has been carried out. The main operating parameters for optimum separation were obtained. On manual operation conditions the concentrations of product and raffinate gas were better than 99.5% simultaneously at a feed rate of 12.0% for a 1:1 hydrogen-deuterium mixture. Besides, TCAP is a good process for trace heavier isotope enriching from hydrogen. The concentration of deuterium can be reduced from 0.5% to less than 50ppm in hydrogen in ten cycles. 5 refs., 4 figs.

  4. Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream

    DOE Patents [OSTI]

    Li, Jian; Chai, Xin Sheng; Zhu, Junyoung

    2008-06-24

    The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

  5. Expedited Site Characterization: A rapid, cost-effective process for preremedial site characterization

    SciTech Connect (OSTI)

    Burton, J.C.; Walker, J.L.; Jennings, T.V.; Aggarwal, P.K.; Hastings, B.; Meyer, W.T.; Rose, C.M.; Rosignolo, C.L.

    1993-11-01

    Argonne National Laboratory has developed a unique, cost- and time-effective, technically innovative process for preremedial site characterization, referred to as Expedited Site Characterization (ESC). The cost of the ESC field sampling process ranges from 1/10 to 1/5 of the cost of traditional site characterization. The time required for this ESC field activity is approximately 1/30 of that for current methods. Argonne`s preremedial site investigations based on this approach have been accepted by the appropriate regulatory agencies. The ESC process is flexible and neither site nor contaminant dependent. The process has been successfully tested and applied in site investigations of multiple contaminated landfills in New Mexico (for the US Department of the Interior`s Bureau of Land Management [BLM]) and at former grain storage facilities in Nebraska and Kansas, contaminated with carbon tetrachloride (for the Department of Agriculture`s Commodity Credit Corporation [CCC/USDA]). A working demonstration of this process was sponsored by the US Department of Energy (DOE) Office of Technology Development as a model of the methodology needed to accelerate site characterizations at DOE facilities. This report describes the application of the process in New Mexico, Nebraska and Kansas.

  6. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    SciTech Connect (OSTI)

    Mackiewicz-Ludtka, G.; Sebright, J.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for

  7. Thermal wave image processing for characterization of subsurface of flaws in materials

    SciTech Connect (OSTI)

    Gopalan, K.; Gopalsami, N.

    1993-08-01

    Infrared images resulting from back-scattered thermal waves in composite materials are corrupted by instrument noise and sample heat-spread function. This paper demonstrates that homomorphic deconvolution and {open_quotes}demultiplication{close_quotes} result in enhanced image quality for characterization of subsurface flaws in Kevlar and graphics composites. The choice of processing depends on the material characteristics and the extent of noise in the original image.

  8. First demonstration of rapid shutdown using neon shattered pellet injection for thermal quench mitigation on DIII-D

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Commaux, Nicolas J. C.; Shiraki, Daisuke; Baylor, Larry R.; Hollmann, E. M.; Eidietis, N. W.; Lasnier, C. J.; Moyer, R. A.; Jernigan, T. C.; Meitner, S. J.; Combs, Stephen Kirk; et al

    2016-03-02

    Shattered pellet injection (SPI) is one of the prime candidates for the ITER disruption mitigation system because of its deeper penetration and larger particle flux than massive gas injection (MGI) (Taylor et al 1999 Phys. Plasmas 6 1872) using deuterium (Commaux et al 2010 Nucl. Fusion 50 112001, Combs et al 2010 IEEE Trans. Plasma Sci. 38 400, Baylor et al 2009 Nucl. Fusion 49 085013). The ITER disruption mitigation system will likely use mostly high Z species such as neon because of more effective thermal mitigation and pumping constraints on the maximum amount of deuterium or helium that couldmore » be injected. An upgrade of the SPI on DIII-D enables ITER relevant injection characteristics in terms of quantities and gas species. This upgraded SPI system was used on DIII-D for the first time in 2014 for a direct comparison with MGI using identical quantities of neon. This comparison enabled the measurements of density perturbations during the thermal quench (TQ) and radiated power and heat loads to the divertor. It showed that SPI using similar quantities of neon provided a faster and stronger density perturbation and neon assimilation, which resulted in a lower conducted energy to the divertor and a faster TQ onset. Radiated power data analysis shows that this was probably due to the much deeper penetration of the neon in the plasma inducing a higher core radiation than in the MGI case. This experiment shows also that the MHD activity during an SPI shutdown (especially during the TQ) is quite different compared to MGI. Furthermore, this favorable TQ energy dissipation was obtained while keeping the current quench (CQ) duration within acceptable limits when scaled to ITER.« less

  9. Thermodynamic analysis of tar reforming through auto-thermal reforming process

    SciTech Connect (OSTI)

    Nurhadi, N. Diniyati, Dahlia; Efendi, M. Ade Andriansyah; Istadi, I.

    2015-12-29

    Fixed bed gasification is a simple and suitable technology for small scale power generation. One of the disadvantages of this technology is producing tar. So far, tar is not utilized yet and being waste that should be treated into a more useful product. This paper presents a thermodynamic analysis of tar conversion into gas producer through non-catalytic auto-thermal reforming technology. Tar was converted into components, C, H, O, N and S, and then reacted with oxidant such as mixture of air or pure oxygen. Thus, this reaction occurred auto-thermally and reached chemical equilibrium. The sensitivity analysis resulted that the most promising process performance occurred at flow rate of air was reached 43% of stoichiometry while temperature of process is 1100°C, the addition of pure oxygen is 40% and preheating of oxidant flow is 250°C. The yield of the most promising process performance between 11.15-11.17 kmol/h and cold gas efficiency was between 73.8-73.9%.The results of this study indicated that thermodynamically the conversion of tar into producer gas through non-catalytic auto-thermal reformingis more promising.

  10. A NOVEL LOW THERMAL BUDGET THIN-FILM POLYSILICON FABRICATION PROCESS FOR LARGE-AREA, HIGH-THROUGHPUT SOLAR CELL PRODUCTION

    SciTech Connect (OSTI)

    Yue Kuo

    2010-08-15

    A novel thin-film poly-Si fabrication process has been demonstrated. This low thermal budget process transforms the single- and multi-layer amorphous silicon thin films into a poly-Si structure in one simple step over a pulsed rapid thermal annealing process with the enhancement of an ultrathin Ni layer. The complete poly-Si solar cell was fabricated in a short period of time without deteriorating the underneath glass substrate. The unique vertical crystallization process including the mechanism is discussed. Influences of the dopant type and process parameters on crystal structure will be revealed. The poly-Si film structure has been proved using TEM, XRD, Raman, and XPS methods. The poly-Si solar cell structure and the performance have been examined. In principle, the new process is potentially applicable to produce large-area thin-film poly-Si solar cells at a high throughput and low cost. A critical issue in this process is to prevent the excessive dopant diffusion during crystallization. Process parameters and the cell structure have to be optimized to achieve the production goal.

  11. Rapid low-temperature epitaxial growth using a hot-element assisted chemical vapor deposition process

    DOE Patents [OSTI]

    Iwancizko, Eugene; Jones, Kim M.; Crandall, Richard S.; Nelson, Brent P.; Mahan, Archie Harvin

    2001-01-01

    The invention provides a process for depositing an epitaxial layer on a crystalline substrate, comprising the steps of providing a chamber having an element capable of heating, introducing the substrate into the chamber, heating the element at a temperature sufficient to decompose a source gas, passing the source gas in contact with the element; and forming an epitaxial layer on the substrate.

  12. MC3714 Thermal Battery Lot No. 1 production summary and engineering process instruction manual

    SciTech Connect (OSTI)

    Jacobs, D.

    1990-03-01

    The MC3714 Thermal Battery provides the instrumentation power for the W82 joint test assembly (JTA). Lot No. 1 production was performed at GE Neutron Devices (GEND) by Power Sources Development Laboratory. Production started directly after the development program utilizing tooling, and processes from development. This substantially reduced preproduction activities and start up costs. Included in this report are the Engineering Process Instructions and the performance data from the build. The overall production yield was 99% and all performance requirements were met with no problems. 5 figs., 4 tabs.

  13. Substrate-dependent thermal conductivity of aluminum nitride thin-films processed at low temperature

    SciTech Connect (OSTI)

    Belkerk, B. E.; Bensalem, S.; Soussou, A.; Carette, M.; Djouadi, M. A.; Scudeller, Y.; Al Brithen, H.

    2014-12-01

    In this paper, we report on investigation concerning the substrate-dependent thermal conductivity (k) of Aluminum Nitride (AlN) thin-films processed at low temperature by reactive magnetron sputtering. The thermal conductivity of AlN films grown at low temperature (<200 °C) on single-crystal silicon (Si) and amorphous silicon nitride (SiN) with thicknesses ranging from 100 nm to 4000 nm was measured with the transient hot-strip technique. The k values for AlN films on SiN were found significantly lower than those on Silicon consistently with their microstructures revealed by X-ray diffraction, high resolution scanning electron microscopy, and transmission electron microscopy. The change in k was due to the thermal boundary resistance found to be equal to 10 × 10{sup −9} Km{sup 2}W{sup −1} on SiN against 3.5 × 10{sup −9} Km{sup 2}W{sup −1} on Si. However, the intrinsic thermal conductivity was determined with a value as high as 200 Wm{sup −1}K{sup −1} whatever the substrate.

  14. Photoluminescence spectroscopy and Rutherford backscattering channeling evaluation of various capping techniques for rapid thermal annealing of ion-implanted ZnSe

    SciTech Connect (OSTI)

    Allen, E.L.; Zach, F.X.; Yu, K.M.; Bourret, E.D.

    1994-05-01

    We report on the effectiveness of proximity caps and PECVD Si{sub 3}N{sub 4}caps during annealing of implanted ZnSe films. OMVPE ZnSe films were grown using diisopropylselenide (DIPSe) and diethylzinc (DEZn) precursors, then ion-implanted with 1 {times} 10{sup 14} cm{sup {minus}2} N (33 keV) or Ne (45 keV) at room temperature and liquid nitrogen temperature, and rapid thermal annealed at temperatures between 200C and 850C. Rutherford backscattering spectrometry in the channeling orientation was used to investigate damage recovery, and photoluminescence spectroscopy was used to investigate crystal quality and the formation of point defects. Low temperature implants were found to have better luminescence properties than room temperature implants, and results show that annealing, time and temperature may be more important than capping material in determining the optical properties. Effects of various caps, implant and annealing temperature are discussed in terms of photoluminescence spectra.

  15. Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes

    SciTech Connect (OSTI)

    Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

    2012-12-03

    Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2

  16. Energy and costs scoping study for plasma pyrolysis thermal processing system

    SciTech Connect (OSTI)

    Sherick, K.E.; Findley, J.E.

    1992-01-01

    The purpose of this study was to provide information in support of an investigation of thermal technologies as possible treatment process for buried wastes at the INEL. Material and energy balances and a cost estimate were generated for a representative plasma torch-based thermal waste treatment system operating in a pyrolysis mode. Two waste streams were selected which are representative of INEL buried wastes, large in volume, and difficult to treat by other technologies. These streams were a solidified nitrate sludge waste stream and a waste/soil mix of other buried waste components. The treatment scheme selected includes a main plasma chamber operating under pyrolyzing conditions; a plasma afterburner to provide additional residence time at high temperature to ensure complete destruction of hazardous organics; an off-gas treatment system; and a incinerator and stack to oxidize carbon monoxide to carbon dioxide and vent the clean, oxidized gases to atmosphere. The material balances generated provide materials flow and equipment duty information of sufficient accuracy to generate initial rough-order-of-magnitude (ROM) system capital and operating cost estimates for a representative plasma thermal processing system.

  17. Supporting technology for enhanced oil recovery: EOR thermal processes. Seventh Amendment and Extension to Annex 4, Enhanced oil recovery thermal processes

    SciTech Connect (OSTI)

    Reid, T B; Colonomos, P

    1993-02-01

    This report contains the results of efforts under the six tasks of the Seventh Amendment and Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections (for each of the 6 tasks) and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section. The tasks are numbered 50 through 55. The first, second, third, fourth, fifth, sixth and seventh reports on Annex IV, Venezuela MEM/USA-DOE Fossil Energy Report IV-1, IV-2, IV-3, IV-4, IV-5 and IV-6 (DOE/BETC/SP-83/15, DOE/BC-84/6/SP, DOE/BC-86/2/SP, DOE/BC-87/2/SP, DOE/BC-89/l/SP, DOE/BC-90/l/SP, and DOE/BC-92/l/SP) contain the results for the first 49 tasks. Those reports are dated April 1983, August 1984, March 1986, July 1987, November 1988, December 1989, and October 1991, respectively. Each task report has been processed separately for inclusion in the Energy Science and Technology Database.

  18. Complete characterization by Raman spectroscopy of the structural properties of thin hydrogenated diamond-like carbon films exposed to rapid thermal annealing

    SciTech Connect (OSTI)

    Rose, Franck Wang, Na; Smith, Robert; Xiao, Qi-Fan; Dai, Qing; Marchon, Bruno; Inaba, Hiroshi; Matsumura, Toru; Saito, Yoko; Matsumoto, Hiroyuki; Mangolini, Filippo; Carpick, Robert W.

    2014-09-28

    We have demonstrated that multi-wavelength Raman and photoluminescence spectroscopies are sufficient to completely characterize the structural properties of ultra-thin hydrogenated diamond-like carbon (DLC:H) films subjected to rapid thermal annealing (RTA, 1 s up to 659 °C) and to resolve the structural differences between films grown by plasma-enhanced chemical vapor deposition, facing target sputtering and filtered cathodic vacuum arc with minute variations in values of mass density, hydrogen content, and sp³ fraction. In order to distinguish unequivocally between films prepared with different density, thickness, and RTA treatment, a new method for analysis of Raman spectra was invented. This newly developed analysis method consisted of plotting the position of the Raman G band of carbon versus its full width at half maximum. Moreover, we studied the passivation of non-radiative recombination centers during RTA by performing measurements of the increase in photoluminescence in conjunction with the analysis of DLC:H networks simulated by molecular dynamics. The results show that dangling bond passivation is primarily a consequence of thermally-induced sp² clustering rather than hydrogen diffusion in the film.

  19. HYDRODYNAMIC THERMAL MODELING OF 9-CELL ILC CAVITY ELECTROPOLISHING AND IMPLICATIONS FOR IMPROVING THE EP PROCESS

    SciTech Connect (OSTI)

    Charles Reece; John Mammosser; Jun Ortega

    2008-02-12

    Multi-cell niobium cavities often obtain the highest performance levels after having been subjected to an electropolishing (EP) process. The horizontal EP process first developed at KEK/Nomura Plating for TRISTAN[1] cavities is being applied to TESLA-style cavities and other structures for the XFEL and ILC R&D. Jefferson Lab is presently carrying this activity in the US. Because the local electropolishing current density is highly temperature dependent, we have created using CFDesign a full-scale hydrodynamic model which simulates the various thermal conditions present during 9-cell cavity electropolishing. The results of these simulations are compared with exterior surface temperature data gathered during ILC cavity EP at JLab. Having benchmarked the simulation, we explore the affect of altered boundary conditions in order to evaluate potentially beneficial modifications to the current standard process.

  20. Thermal hydraulic feasibility assessment of the hot conditioning system and process

    SciTech Connect (OSTI)

    Heard, F.J.

    1996-10-10

    The Spent Nuclear Fuel Project was established to develop engineered solutions for the expedited removal, stabilization, and storage of spent nuclear fuel from the K Basins at the U.S. Department of Energy`s Hanford Site in Richland, Washington. A series of analyses have been completed investigating the thermal-hydraulic performance and feasibility of the proposed Hot Conditioning System and process for the Spent Nuclear Fuel Project. The analyses were performed using a series of thermal-hydraulic models that could respond to all process and safety-related issues that may arise pertaining to the Hot Conditioning System. The subject efforts focus on independently investigating, quantifying, and establishing the governing heat production and removal mechanisms, flow distributions within the multi-canister overpack, and performing process simulations for various purge gases under consideration for the Hot Conditioning System, as well as obtaining preliminary results for comparison with and verification of other analyses, and providing technology- based recommendations for consideration and incorporation into the Hot Conditioning System design bases.

  1. Thermal Analysis of the Divertor Primary Heat Transfer System Piping During the Gas Baking Process

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Harvey, Karen; Ferrada, Juan J

    2011-02-01

    A preliminary analysis has been performed examining the temperature distribution in the Divertor Primary Heat Transfer System (PHTS) piping and the divertor itself during the gas baking process. During gas baking, it is required that the divertor reach a temperature of 350 C. Thermal losses in the piping and from the divertor itself require that the gas supply temperature be maintained above that temperature in order to ensure that all of the divertor components reach the required temperature. The analysis described in this report was conducted in order to estimate the required supply temperature from the gas heater.

  2. Recent Advances in SRS on Hydrogen Isotope Separation Using Thermal Cycling Absorption Process

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiao, Xin; Sessions, Henry T.; Heung, L. Kit

    2015-02-01

    The recent Thermal Cycling Absorption Process (TCAP) advances at Savannah River Site (SRS) include compressor-free concept for heating/cooling, push and pull separation using an active inverse column, and compact column design. The new developments allow significantly higher throughput and better reliability from 1/10th of the current production system’s footprint while consuming 60% less energy. Various versions are derived in the meantime for external customers to be used in fusion energy projects and medical isotope production.

  3. Recent Advances in SRS on Hydrogen Isotope Separation Using Thermal Cycling Absorption Process

    SciTech Connect (OSTI)

    Xiao, Xin; Sessions, Henry T.; Heung, L. Kit

    2015-02-01

    The recent Thermal Cycling Absorption Process (TCAP) advances at Savannah River Site (SRS) include compressor-free concept for heating/cooling, push and pull separation using an active inverse column, and compact column design. The new developments allow significantly higher throughput and better reliability from 1/10th of the current production systems footprint while consuming 60% less energy. Various versions are derived in the meantime for external customers to be used in fusion energy projects and medical isotope production.

  4. Transition from cool flame to thermal flame in compression ignition process

    SciTech Connect (OSTI)

    Yamada, Hiroyuki; Suzaki, Kotaro; Goto, Yuichi; Tezaki, Atsumu

    2008-07-15

    The mechanism that initiates thermal flames in compression ignition has been studied. Experimentally, a homogeneous charge compression ignition (HCCI) engine was used with DME, n-heptane, and n-decane. Arrhenius plots of the heat release rate in the HCCI experiments showed that rates of heat release with DME, n-heptane, and n-decane exhibited a certain activation energy that is identical to that of the H{sub 2}O{sub 2} decomposition reaction. The same feature was observed in diesel engine operation using ordinary diesel fuel with advanced ignition timing to make ignition occur after the end of fuel injection. These experimental results were reproduced in nondimensional simulations using kinetic mechanisms for DME, n-heptane, and n-decane, the last being developed by extending the n-heptane mechanism. Methanol addition, which suppresses low-temperature oxidation (LTO) and delays the ignition timing, had no effect on the activation energy obtained from the Arrhenius plot of heat release rate. Nevertheless, methanol addition lowered the heat release rates during the prethermal flame process. This is because H{sub 2}O{sub 2} formation during cool flame was reduced by adding methanol. The mechanism during the transition process from cool flame to thermal flame can be explained quantitatively using thermal explosion theory, in which the rate-determining reaction is H{sub 2}O{sub 2} decomposition, assuming that heat release in this period is caused by partial oxidation of DME and HCHO initiated with the reaction with OH produced though H{sub 2}O{sub 2} decomposition. (author)

  5. Highly efficient electroluminescence from a solution-processable thermally activated delayed fluorescence emitter

    SciTech Connect (OSTI)

    Wada, Yoshimasa; Kubo, Shosei; Suzuki, Katsuaki; Kaji, Hironori; Shizu, Katsuyuki; Tanaka, Hiroyuki; Adachi, Chihaya

    2015-11-02

    We developed a thermally activated delayed fluorescence (TADF) emitter, 2,4,6-tris(4-(9,9-dimethylacridan-10-yl)phenyl)-1,3,5-triazine (3ACR-TRZ), suitable for use in solution-processed organic light-emitting diodes (OLEDs). When doped into 4,4′-bis(carbazol-9-yl)biphenyl (CBP) host at 16 wt. %, 3ACR-TRZ showed a high photoluminescence quantum yield of 98%. Transient photoluminescence decay measurements of the 16 wt. % 3ACR-TRZ:CBP film confirmed that 3ACR-TRZ exhibits efficient TADF with a triplet-to-light conversion efficiency of 96%. This high conversion efficiency makes 3ACR-TRZ attractive as an emitting dopant in OLEDs. Using 3ACR-TRZ as an emitter, we fabricated a solution-processed OLED exhibiting a maximum external quantum efficiency of 18.6%.

  6. Evaluation of gasification and novel thermal processes for the treatment of municipal solid waste

    SciTech Connect (OSTI)

    Niessen, W.R.; Marks, C.H.; Sommerlad, R.E.

    1996-08-01

    This report identifies seven developers whose gasification technologies can be used to treat the organic constituents of municipal solid waste: Energy Products of Idaho; TPS Termiska Processor AB; Proler International Corporation; Thermoselect Inc.; Battelle; Pedco Incorporated; and ThermoChem, Incorporated. Their processes recover heat directly, produce a fuel product, or produce a feedstock for chemical processes. The technologies are on the brink of commercial availability. This report evaluates, for each technology, several kinds of issues. Technical considerations were material balance, energy balance, plant thermal efficiency, and effect of feedstock contaminants. Environmental considerations were the regulatory context, and such things as composition, mass rate, and treatability of pollutants. Business issues were related to likelihood of commercialization. Finally, cost and economic issues such as capital and operating costs, and the refuse-derived fuel preparation and energy conversion costs, were considered. The final section of the report reviews and summarizes the information gathered during the study.

  7. Thermal plasma processed ferro-magnetically ordered face-centered cubic iron at room temperature

    SciTech Connect (OSTI)

    Raut, Suyog A.; Kanhe, Nilesh S.; Bhoraskar, S. V.; Mathe, V. L.; Das, A. K.

    2014-10-28

    Here, we report tailor made phase of iron nanoparticles using homogeneous gas phase condensation process via thermal plasma route. It was observed that crystal lattice of nano-crystalline iron changes as a function of operating parameters of the plasma reactor. In the present investigation iron nanoparticles have been synthesized in presence of argon at operating pressures of 1251000?Torr and fixed plasma input DC power of 6?kW. It was possible to obtain pure fcc, pure bcc as well as the mixed phases for iron nanoparticles in powder form as a function of operating pressure. The as synthesized product was characterized for understanding the structural and magnetic properties by using X-ray diffraction, vibrating sample magnetometer, and Mssbauer spectroscopy. The data reveal that fcc phase is ferromagnetically ordered with high spin state, which is unusual whereas bcc phase is found to be ferromagnetic as usual. Finally, the structural and magnetic properties are co-related.

  8. A study of the ignition processes in a center-hole-fired thermal battery

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.

    1998-04-01

    The ignition processes that take place during activation of a 16 cell, center hole fired thermal battery were examined by monitoring the voltage of each cell during activation. The average rise time of each cell to a voltage of 1.125 V was determined for the LiSi/LiCl-LiBr-LiF/FeS{sub 2} electrochemical system. The effects of heat pellet composition, center hole diameter, and the load on the activation parameters were examined for three different igniters. A large variability in individual cell performance was evident along with cell reversal, depending on the location of the cell in the stack. It was not possible to draw detailed statistical information of the relative ignition sequence due to the intrinsic large scatter in the data.

  9. Automated Thermal Image Processing for Detection and Classification of Birds and Bats - FY2012 Annual Report

    SciTech Connect (OSTI)

    Duberstein, Corey A.; Matzner, Shari; Cullinan, Valerie I.; Virden, Daniel J.; Myers, Joshua R.; Maxwell, Adam R.

    2012-09-01

    Surveying wildlife at risk from offshore wind energy development is difficult and expensive. Infrared video can be used to record birds and bats that pass through the camera view, but it is also time consuming and expensive to review video and determine what was recorded. We proposed to conduct algorithm and software development to identify and to differentiate thermally detected targets of interest that would allow automated processing of thermal image data to enumerate birds, bats, and insects. During FY2012 we developed computer code within MATLAB to identify objects recorded in video and extract attribute information that describes the objects recorded. We tested the efficiency of track identification using observer-based counts of tracks within segments of sample video. We examined object attributes, modeled the effects of random variability on attributes, and produced data smoothing techniques to limit random variation within attribute data. We also began drafting and testing methodology to identify objects recorded on video. We also recorded approximately 10 hours of infrared video of various marine birds, passerine birds, and bats near the Pacific Northwest National Laboratory (PNNL) Marine Sciences Laboratory (MSL) at Sequim, Washington. A total of 6 hours of bird video was captured overlooking Sequim Bay over a series of weeks. An additional 2 hours of video of birds was also captured during two weeks overlooking Dungeness Bay within the Strait of Juan de Fuca. Bats and passerine birds (swallows) were also recorded at dusk on the MSL campus during nine evenings. An observer noted the identity of objects viewed through the camera concurrently with recording. These video files will provide the information necessary to produce and test software developed during FY2013. The annotation will also form the basis for creation of a method to reliably identify recorded objects.

  10. Thermal Conversion of Methane to Acetylene Final Report

    SciTech Connect (OSTI)

    Fincke, J.R.; Anderson, R.P.; Hyde, T.; Wright, R.; Bewley, R.; Haggard, D.C.; Swank, W.D.

    2000-01-31

    This report describes the experimental demonstration of a process for the direct thermal conversion of methane to acetylene. The process utilizes a thermal plasma heat source to dissociation products react to form a mixture of acetylene and hydrogen. The use of a supersonic expansion of the hot gas is investigated as a method of rapidly cooling (quenching) the product stream to prevent further reaction or thermal decomposition of the acetylene which can lower the overall efficiency of the process.

  11. Supporting Technology for Enhanced Oil Recovery-EOR Thermal Processes Report IV-12

    SciTech Connect (OSTI)

    Izequeido, Alexandor

    2001-04-01

    This report contains the results of efforts under the six tasks of the Ninth Amendment and Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections (for each of the 6 tasks) and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section. The tasks are numbered 62 through 67. The first, second, third, fourth, fifth, sixth, seventh, eight, and ninth reports on Annex IV, [Venezuela MEM/USA-DOE Fossil Energy Report IV-1, IV-2, IV-3, IV-4, IV-5, IV-6, IV-7, and IV-8 (DOE/BETC/SP-83/15, DOE/BC-84/6/SP, DOE/BC-86/2/SP, DOE/BC-87/2/SP, DOE/BC-89/1/SP, DOE/BC-90/1/SP) DOE/BC-92/1/SP, DOE/BC-93/3/SP, and DOE/BC-95/3/SP] contain the results from the first 61 tasks. Those reports are dated April 1983, August 1984, March 1986, July 1! 987, November 1988, December 1989, October 1991, February 1993, and March 1995 respectively.

  12. Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof

    SciTech Connect (OSTI)

    Oswald, A.A.; Bhatia, R.N.; Mozeleski, E.J.; Glivicky, A.P.; Brueggeman, B.G.; Hooten, J.R.; Smith, C.M.; Hsu, C.S.

    1991-07-09

    This patent describes a hydroformylation-hydrogenation process comprising reacting an olefinic cracked petroleum distillate feed, produced from petroleum residue by high temperature thermal cracking, and containing C{sub 5} to C{sub 35}-1-n-alkyl olefins as the major type of olefin components, and organic sulfur compounds in concentrations exceeding 0.1% sulfur. It comprises at first with carbon monoxide and hydrogen at temperatures between about 50 and 250{degrees} C and pressures in the range of 50 to 6000 psi; in the presence of a Group VIII transition metal carbonyl complex catalyst in effective amounts to produce aldehydes of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule.

  13. Thermal spray vitrification process for the removal of lead oxide contained in organic paints

    SciTech Connect (OSTI)

    Karthikeyan, J.; Chen, J.; Bancke, G.A.; Herman, H.; Berndt, C.C.; Breslin, V.T.

    1995-12-31

    The US Environmental Protection Agency (US-EPA) regulations have necessitated the removal and containment of toxic lead from lead oxide containing paints. The Thermal Spray Vitrification Process (TSVP) is a novel technique in which a glass powder of appropriate composition is flame sprayed onto the painted surface to achieve removal and vitrification of the lead. Two different glass systems, i.e., alkali silicate and ferrous silicate, were chosen for detailed study. Appropriate amounts of raw materials were mixed, fused, quenched, ground and sieved to obtain the spray quality powders. Grit blasted mild steel coupons were used as test substrates for the spray parameter optimization studies; while those coupons with lead oxide containing organic paint were used for the lead removal experiments. The powders and deposits were investigated using Microtrac particle size analysis (for powders), optical microscopy, XRD and SEM. The remnant lead in the panel was measured using a specially prepared X-Ray Fluorescence (XRF) system. The lead leach rate was recorded as per US-EPA approved Toxicity Characteristic Leaching Procedure (TCLP). The results of this study have shown that lead oxide can be successfully removed form the paint by flame spraying a maximum of three layers of glass onto the painted surface. It is possible to obtain much higher lead removal rate with ferrous silicate glass as compared to alkali silicate glass is much higher than the ferrous silicate glass. The in situ vitrification has not been completely optimized; however, the lead containing glass coating can be remelted in situ or on site to enhance the vitrification of the lead which had been absorbed in the glass coating.

  14. On the thermal neutron transport processes in liquid H/sub 2/O-D/sub 2/O mixtures

    SciTech Connect (OSTI)

    Barnsal, R.M.; Tewari, S.P.

    1983-06-01

    Using the recently developed thermal neutron scattering kernels for water and heavy water, which incorporate both the collective and the molecular modes present in water and heavy water, the thermal neutron transport studies of asymptotic decay constants lambda/sub 0/, diffusion coefficient D/sub 0/, diffusion cooling coefficient C, and the transport mean-free-path lambda /SUB tr/ are studied for liquid H/sub 2/O-D/sub 2/O mixtures with varying molecular contents and for various assembly sizes at 21 and 5/sup 0/C. The calculated values of the physical constants, lambda/sub 0/, D/sub 0/, C, and lambda /SUB tr/ are found to be in good agreement with the corresponding experimental results. Both the collective motion and the molecular modes present in the liquid H/sub 2/O-D/sub 2/O mixtures play significant roles in the thermal neutron transport processes.

  15. EFFECT OF THERMAL PROCESSES ON COPPER-TIN ALLOYS FOR ZINC GETTERING

    SciTech Connect (OSTI)

    Korinko, P.; Golyski, M.

    2013-11-01

    A contamination mitigation plan was initiated to address the discovery of radioactive zinc‐65 in a glovebox. A near term solution was developed, installation of heated filters in the glovebox piping. This solution is effective at retaining the zinc in the currently contaminated area, but the gamma emitting contaminant is still present in a system designed for tritium beta. A project was initiated to develop a solution to contain the {sup 65}Zn in the furnace module. Copper and bronze (a Cu/Sn alloy) were found to be candidate materials to combine with zinc‐65 vapor, using thermodynamic calculations. A series of binary Cu/Sn alloys were developed (after determining that commercial alloys were unacceptable), that were found to be effective traps of zinc vapor. The task described in this report was undertaken to determine if the bronze substrates would retain their zinc gettering capability after being exposed to simulated extraction conditions with oxidizing and reducing gases. Pure copper and three bronze alloys were prepared, exposed to varying oxidation conditions from 250 to 450{degree}C, then exposed to varying reduction conditions in He-H{sub 2} from 250-450{degree}C, and finally exposed to zinc vapor at 350{degree}C for four hours. The samples were characterized using scanning electron microscopy, X-ray diffraction, differential thermal analysis, mass change, and visual observation. It was observed that the as fabricated samples and the reduced samples all retained their zinc gettering capacity while samples in the "as-oxidized" condition exhibited losses in zinc gettering capacity. Over the range of conditions tested, i.e., composition, oxidation temperature, and reduction temperature, no particular sample composition appeared better. Samples reduced at 350{degree}C exhibited the greatest zinc capacity, although there were some testing anomalies associated with these samples. This work clearly demonstrated that the zinc gettering was not adversely

  16. The effect of process parameters on the thermal conditions during moving mold ESR

    SciTech Connect (OSTI)

    Heilman, J.E.; Damkroger, B.K.

    1994-09-01

    Several experimental melts were conducted using a moving mold electroslag remelting furnace. The conditions of electrode immersion depth, slag cap thickness, and melt current were varied. Mold wall temperatures and slag pool temperatures were measured and the heat flux through the mold wall was calculated. The relationships between varying ESR melt parameters and the resultant thermal conditions were examined. The thermal profile of the mold, the heat transfer to the mold coolant total and fractional, and the formation of a slag skin were studied.

  17. Zircon and apatite fission-track evidence for an Early Permian thermal peak and relatively rapid Late Permian cooling in the Appalachian Basin

    SciTech Connect (OSTI)

    Roden, M.K. . Dept. of Earth and Environmental Science); Wintsch, R.P. . Dept. of Geological Sciences)

    1992-01-01

    New zircon fission-track ages compliment published apatite fission-track ages in the Appalachian Basin to narrowly constrain its thermal history. Geologic evidence can only constrain timing of the thermal peak to be younger than late Pennsylvanian sediments ([approximately] 300 Ma) and older than Mesozoic sediments in the Newark and Gettysburg Basins ([approximately] 210 Ma). Apatite fission-track ages as old as 246 Ma require the Alleghanian thermal peak to have been pre-Triassic. Preliminary data on reset zircon fission-track ages from middle Paleozoic sediments range from 255 to 290 Ma. Zircon fission-track apparent ages from samples younger and structurally higher than these are not reset. Thus, the oldest reset zircon fission-track age constraints the time of the Alleghanian thermal peak to be earliest Permian. Rates of post-Alleghanian cooling have not been well-constrained by geologic data and could be very slow. The difference between apatite and zircon fission-track ages for most of the samples range from 100--120 m.y. reflecting Permo-Triassic cooling of only 1 C/m.y. However, one sample with one of the oldest apatite ages, 245 Ma, yields one of the younger zircon ages of 255 Ma. This requires cooling rates of 10 C/m.y. and uplift rates of [approximately] 0.5 mm/yr. Collectively, these data support an early Permian thermal peak and a two-stage cooling history, consisting of > 100 C cooling (> 8 km denundation) in the Permian followed by relatively slow cooling and exhumation throughout the Mesozoic.

  18. Controlled etching of hexagonal ZnO architectures in an alcohol thermal process

    SciTech Connect (OSTI)

    Wu, Junshu [State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China)] [State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China); Xue, Dongfeng, E-mail: dfxue@chem.dlut.edu.cn [State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China)] [State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China)

    2010-03-15

    An alcohol thermal technique was applied to the controlled growth of hexagonal ZnO architectures via selective chemical etching. ZnO microdisks were produced first under mild alcohol thermal conditions in presence of formamide. Due to a higher surface energy/atomic density of Zn{sup 2+} {l_brace}0 0 0 1{r_brace} than that of the other faces, hexagonal ZnO microring was obtained by selectively etching positive polar surface of disk-like precursor with a high density of planar defects at the center. The selective etching of ZnO is related to its crystallographic characteristics of surface polarity and chemical activities, which opens a new opportunity for the shape-controlled synthesis of wurtzite-structured materials.

  19. Rapid formation of phase-clean 110 K (Bi-2223) powders derived via freeze-drying process

    DOE Patents [OSTI]

    Balachandran, Uthamalingam

    1996-01-01

    A process for the preparation of amorphous precursor powders for Pb-doped Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x (2223) includes a freeze-drying process incorporating a splat-freezing step. The process generally includes splat freezing a nitrate solution of Bi, Pb, Sr, Ca, and Cu to form flakes of the solution without any phase separation; grinding the frozen flakes to form a powder; freeze-drying the frozen powder; heating the dried powder to form a dry green precursor powders; denitrating the green-powders; heating the denitrated powders to form phase-clean Bi-2223 powders. The grain boundaries of the 2223 grains appear to be clean, leading to good intergrain contact between 2223 grains.

  20. Rapid formation of phase-clean 110 K (Bi-2223) powders derived via freeze-drying process

    DOE Patents [OSTI]

    Balachandran, U.

    1996-06-04

    A process for the preparation of amorphous precursor powders for Pb-doped Bi{sub 2}Sr{sub 2} Ca{sub 2}Cu{sub 3}O{sub x} (2223) includes a freeze-drying process incorporating a splat-freezing step. The process generally includes splat freezing a nitrate solution of Bi, Pb, Sr, Ca, and Cu to form flakes of the solution without any phase separation; grinding the frozen flakes to form a powder; freeze-drying the frozen powder; heating the dried powder to form a dry green precursor powders; denitrating the green-powders; heating the denitrated powders to form phase-clean Bi-2223 powders. The grain boundaries of the 2223 grains appear to be clean, leading to good intergrain contact between 2223 grains. 11 figs.

  1. HEATING THE SOLAR ATMOSPHERE BY THE SELF-ENHANCED THERMAL WAVES CAUSED BY THE DYNAMO PROCESSES

    SciTech Connect (OSTI)

    Dumin, Yurii V. E-mail: dumin@izmiran.ru

    2012-05-20

    We discuss a possible mechanism for heating the solar atmosphere by the ensemble of thermal waves, generated by the photospheric dynamo and propagating upward with increasing magnitudes. These waves are self-sustained and amplified due to the specific dependence of the efficiency of heat release by Ohmic dissipation on the ratio of the collisional to gyrofrequencies, which in its turn is determined by the temperature profile formed in the wave. In the case of sufficiently strong driving, such a mechanism can increase the plasma temperature by a few times, i.e., it may be responsible for heating the chromosphere and the base of the transition region.

  2. Solid state rapid thermocycling

    DOE Patents [OSTI]

    Beer, Neil Reginald; Spadaccini, Christopher

    2014-05-13

    The rapid thermal cycling of a material is targeted. A solid state heat exchanger with a first well and second well is coupled to a power module. A thermoelectric element is coupled to the first well, the second well, and the power module, is configured to transfer thermal energy from the first well to the second well when current from the power module flows through the thermoelectric element in a first direction, and is configured to transfer thermal energy from the second well to the first well when current from the power module flows through the thermoelectric element in a second direction. A controller may be coupled to the thermoelectric elements, and may switch the direction of current flowing through the thermoelectric element in response to a determination by sensors coupled to the wells that the amount of thermal energy in the wells falls below or exceeds a pre-determined threshold.

  3. EFFECT OF ELECTROLYZER CONFIGURATION AND PERFORMANCE ON HYBRID SULFUR PROCESS NET THERMAL EFFICIENCY

    SciTech Connect (OSTI)

    Gorensek, M

    2007-03-16

    Hybrid Sulfur cycle is gaining popularity as a possible means for massive production of hydrogen from nuclear energy. Several different ways of carrying out the SO{sub 2}-depolarized electrolysis step are being pursued by a number of researchers. These alternatives are evaluated with complete flowsheet simulations and on a common design basis using Aspen Plus{trademark}. Sensitivity analyses are performed to assess the performance potential of each configuration, and the flowsheets are optimized for energy recovery. Net thermal efficiencies are calculated for the best set of operating conditions for each flowsheet and the results compared. This will help focus attention on the most promising electrolysis alternatives. The sensitivity analyses should also help identify those features that offer the greatest potential for improvement.

  4. Nanocrystallization of LiCoO2 Cathodes for Thin Film Batteries Utilizing Pulse Thermal Processing

    SciTech Connect (OSTI)

    2009-04-01

    This factsheet describes a study whose focus is on the nanocrystallization of the LiCoO2 cathode thin films on polyimide substrates and evaluate the microstructural evolution and resistance as a function of PTP processing conditions.

  5. Controlled Thermal-Mechanical Processing of Tubes and Pipes for Enhanced Manufacturing and Performance

    SciTech Connect (OSTI)

    Kolarik, Robert V.

    2005-11-11

    The Alloy Steel Business of The Timken Company won an award for the controlled thermo-mechanical processing (CTMP) project and assembled a strong international public/private partnership to execute the project. The premise of the CTMP work was to combine Timken's product understanding with its process expertise and knowledge of metallurgical and deformation fundamentals developed during the project to build a predictive process design capability. The CTMP effort succeeded in delivering a pc-based capability in the tube optimization model, with a virtual pilot plant (VPP) feature to represent the desired tube making process to predict the resultant microstructure tailored for the desired application. Additional tasks included a system for direct, online measurement of grain size and demonstration of application of CTMP via robotically enhanced manufacturing.

  6. Benefits of rapid solidification processing of modified LaNi{sub 5} alloys by high pressure gas atomization for battery applications

    SciTech Connect (OSTI)

    Anderson, I.E.; Pecharsky, V.K.; Ting, J.; Witham, C.; Bowman, R.C.

    1997-12-31

    A high pressure gas atomization approach to rapid solidification has been employed to investigate simplified processing of Sn modified LaNi{sub 5} powders that can be used for advanced Ni/metal hydride (Ni/MH) batteries. The current industrial practice involves casting large ingots followed by annealing and grinding and utilizes a complex and costly alloy design. This investigation is an attempt to produce powders for battery cathode fabrication that can be used in an as-atomized condition without annealing or grinding. Both Ar and He atomization gas were tried to investigate rapid solidification effects. Sn alloy additions were tested to promote subambient pressure absorption/desorption of hydrogen at ambient temperature. The resulting fine, spherical powders were subject to microstructural analysis, hydrogen gas cycling, and annealing experiments to evaluate suitability for Ni/MH battery applications. The results demonstrate that a brief anneal is required to homogenize the as-solidified microstructure of both Ar and He atomized powders and to achieve a suitable hydrogen absorption behavior. The Sn addition also appears to suppress cracking during hydrogen gas phase cycling in particles smaller than about 25 {micro}m. These results suggest that direct powder processing of a LaNi{sub 5{minus}x}Sn{sub x} alloy has potential application in rechargeable Ni/MH batteries.

  7. Iron-Based Amorphous Coatings Produced by HVOF Thermal Spray Processing-Coating Structure and Properties

    SciTech Connect (OSTI)

    Beardsley, M B

    2008-03-26

    The feasibility to coat large SNF/HLW containers with a structurally amorphous material (SAM) was demonstrated on sub-scale models fabricated from Type 316L stainless steel. The sub-scale model were coated with SAM 1651 material using kerosene high velocity oxygen fuel (HVOF) torch to thicknesses ranging from 1 mm to 2 mm. The process parameters such as standoff distance, oxygen flow, and kerosene flow, were optimized in order to improve the corrosion properties of the coatings. Testing in an electrochemical cell and long-term exposure to a salt spray environment were used to guide the selection of process parameters.

  8. The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines

    SciTech Connect (OSTI)

    Lyon, Richard

    2001-08-05

    This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

  9. Thermal and mechanical stabilization process of the organic fraction of the municipal solid waste

    SciTech Connect (OSTI)

    Giudicianni, Paola; Bozza, Pio; Sorrentino, Giancarlo; Ragucci, Raffaele

    2015-10-15

    Graphical abstract: Display Omitted - Highlights: • A domestic scale prototype for the pre-treatment of OFMSW has been tested. • Two grinding techniques are compared and thermopress is used for the drying stage. • Increasing temperature up to 170 °C reduces energy consumption of the drying stage. • In the range 5–10 bar a reduction of 97% of the initial volume is obtained. • In most cases energy recovery from the dried waste matches energy consumption. - Abstract: In the present study a thermo-mechanical treatment for the disposal of the Organic Fraction of Municipal Solid Waste (OFMSW) at apartment or condominium scale is proposed. The process presents several advantages allowing to perform a significant volume and moisture reduction of the produced waste at domestic scale thus producing a material with an increased storability and improved characteristics (e.g. calorific value) that make it available for further alternative uses. The assessment of the applicability of the proposed waste pretreatment in a new scheme of waste management system requires several research steps involving different competences and application scales. In this context, a preliminary study is needed targeting to the evaluation and minimization of the energy consumption associated to the process. To this aim, in the present paper, two configurations of a domestic appliance prototype have been presented and the effect of some operating variables has been investigated in order to select the proper configuration and the best set of operating conditions capable to minimize the duration and the energy consumption of the process. The performances of the prototype have been also tested on three model mixtures representing a possible daily domestic waste and compared with an existing commercially available appliance. The results obtained show that a daily application of the process is feasible given the short treatment time required and the energy consumption comparable to the one of

  10. Study of the effect of plasma-striking atmosphere on Fe-oxidation in thermal dc arc-plasma processing

    SciTech Connect (OSTI)

    Banerjee, I.; Khollam, Y. B.; Mahapatra, S. K.; Das, A. K.; Bhoraskar, S. V.

    2010-11-15

    The effect of plasma-striking atmosphere: air and air+Ar-gas on the crystallization of Fe-oxide phases was studied using dc thermal arc-plasma processing route. The powders were characterized by x-ray diffraction, vibrating sample magnetometry, transmission electron microscopy, and Moessbauer spectroscopy techniques. At room temperature and O{sub 2} rich atmosphere, arc-evaporated Fe{sup 2+} ions oxidize into either {gamma}-Fe{sub 2}O{sub 3} or Fe{sub 3}O{sub 4} depending upon the combining ratio of Fe with molecular O{sub 2}. Fe/O ratio could be adjusted using proper flow rate of Ar gas to crystallize the pure {gamma}-Fe{sub 2}O{sub 3}.

  11. Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof

    DOE Patents [OSTI]

    Sarin, V.K.

    1990-08-21

    An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications is disclosed. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al[sub x]N[sub y]O[sub z] layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al[sub x]N[sub y]O[sub z] layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

  12. Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof

    DOE Patents [OSTI]

    Sarin, Vinod K. (Lexington, MA)

    1990-01-01

    An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al.sub.x N.sub.y O.sub.z layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al.sub.x N.sub.y O.sub.z layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

  13. Supporting technology for enhanced oil recovery: Sixth amendment and extension to Annex IV enhanced oil recovery thermal processes

    SciTech Connect (OSTI)

    Reid, T.B. ); Rivas, O. )

    1991-10-01

    This report contains the results of efforts under the six tasks of the Sixth Amendment and Extension of Annex 4, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections (for each of the 6 tasks) and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section. The tasks are numbered 44 through 49. Tasks are: DOE-SUPRI-laboratory research on steam foam, CAT-SCAN, and in-situ combustion; INTEVEP-laboratory research and field projects on steam foam; DOE-NIPER-laboratory research and field projects light oil steam flooding; INTEVEP-laboratory research and field studies on wellbore heat losses; DOE-LLNL-laboratory research and field projects on electromagnetic induction tomography; INTEVEP-laoboratory research on mechanistic studies.

  14. Coal liquefaction quenching process

    DOE Patents [OSTI]

    Thorogood, Robert M.; Yeh, Chung-Liang; Donath, Ernest E.

    1983-01-01

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  15. Surrogate formulations for thermal treatment of low-level mixed waste. Part 3: Plasma hearth process testing

    SciTech Connect (OSTI)

    Chiang, J.M.; Bostick, W.D.; Hoffman, D.P.; Hermes, W.H.; Gibson, L.V. Jr.; Richmond, A.A.

    1994-01-01

    The plasma hearth process (PHP) presented in this report has been tested at a facility at Ukiah, California, in a cooperative effort between the Department of Energy (DOE), Science Applications International Corporation, Inc., and ReTech, Inc. The electrically heated plasma gas is used to destroy organic materials and bind radionuclides and Resource Conservation and Recovery Act (RCRA) metals in the glassy slag. Proof-of-principle tests were conducted successfully using nonhazardous and non-radioactive materials placed in 30-gal steel drums. On-line analyses of the gaseous effluents indicated complete combustion; emissions of CO, NO{sub x}, and particulates were low. The process also produced highly stable solid waste forms. The experiments for the next phase have been planned employing surrogates for the hazardous and radioactive components of the simulated waste streams. Natural cerium oxide is selected to simulate the behavior of radioactive actinide and transuranium elements, while natural cesium chloride is simulated for the study of relatively volatile radioactive fission products. For RCRA organics, naphthalene and 1,2-dichlorobenzene are semivolatile compounds selected to represent significant challenges to thermal destruction, whereas chlorobenzene is selected for the study of relatively volatile organics. Salts of chromium, nickel, lead, and cadmium are chosen to represent the twelve regulated toxic metals for emission and partitioning studies. The simulated waste packages presented in the text do not necessarily represent an individual waste stream within the DOE complex; rather, they were formulated to represent the most probable components in generic waste stream categories.

  16. In-situ x-ray diffraction and resistivity analysis of CoSi{sub 2} phase formation with and without a Ti interlayer at rapid thermal annealing rates

    SciTech Connect (OSTI)

    Cabral, C. Jr.; Clevenger, L.A.; Stephenson, G.B.; Brauer, S.; Morales, G.; Ludwig, K.F. Jr.

    1995-09-01

    It has been demonstrated, using synchrotron radiation, that at rapid thermal annealing rates (3 C/s) the 2formation of CoSi{sub 2} shifts to higher temperatures when a thin Ti interlayer is placed between Co and polycrystalline Si. It has also been shown that the Ti interlayer reduces the temperature range between the start of CoSi formation and CoSi{sub 2} formation (i.e. the range over which CoSi is present). 13 nm of Co deposited by physical vapor deposition on polycrystalline Si with and without either a 2 nm or 3.4 nm interlayer of Ti was analyzed in-situ by monitoring x-ray diffraction (XRD) peak intensity as a function of temperature using monochromatic radiation from a synchrotron beam line and by monitoring resistivity as a function of temperature i a rapid thermal annealing (RTA) system. The XRD analysis indicates that the phase formation proceeds from CoSi to CoSi{sub 2} in a temperature range that decreases from about 200 C to 140 C to 115 C with pure Co, Co/2 nm Ti and Co/3.4 nm Ti films respectively. The onset of the CoSi formation increases by about 135 C and 160 C for Co/2 nm Ti and Co/3.4 nm Ti compared to pure Co. The CoSi temperature range decreases from about 75 C in pure Co to less than 50 C in Co/Ti. In-situ RTA resistance along with in-situ XRD analysis indicates that the onset formation temperatures for CoSi are about 440 C, 575 C and 600 C and the temperatures for the completion of CoSi{sub 2} formation are about 640 C, 715 C and 715 C for Co, Co/2 nm Ti and Co/3.4 nm Ti films respectively. The results are consistent with he Ti interlayer acting as a diffusion barrier during the initial stages of the Co-Si reaction.

  17. Venezuela-MEM/USA-DOE Fossil Energy Report IV-11: Supporting technology for enhanced oil recovery - EOR thermal processes

    SciTech Connect (OSTI)

    Venezuela

    2000-04-06

    This report contains the results of efforts under the six tasks of the Tenth Amendment anti Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Energy Agreement. This report is presented in sections (for each of the six Tasks) and each section contains one or more reports that were prepared to describe the results of the effort under each of the Tasks. A statement of each Task, taken from the Agreement Between Project Managers, is presented on the first page of each section. The Tasks are numbered 68 through 73. The first through tenth report on research performed under Annex IV Venezuela MEM/USA-DOE Fossil Energy Report Number IV-1, IV-2, IV-3, IV-4, IV-5, IV-6, IV-7, IV-8, IV-9, IV-10 contain the results of the first 67 Tasks. These reports are dated April 1983, August 1984, March 1986, July 1987, November 1988, December 1989, October 1991, February 1993, March 1995, and December 1997, respectively.

  18. Oxidation Behavior of In-Flight Molten Aluminum Droplets in the Twin-Wire Electric Arc Thermal Spray Process

    SciTech Connect (OSTI)

    Donna Post Guillen; Brian G. Williams

    2005-05-01

    This paper examines the in-flight oxidation of molten aluminum sprayed in air using the twin-wire electric arc (TWEA) thermal spray process. The oxidation reaction of aluminum in air is highly exothermic and is represented by a heat generation term in the energy balance. Aerodynamic shear at the droplet surface enhances the amount of in-flight oxidation by: (1) promoting entrainment and mixing of the surface oxides within the droplet, and (2) causing a continuous heat generation effect that increases droplet temperature over that of a droplet without internal circulation. This continual source of heat input keeps the droplets in a liquid state during flight. A linear rate law based on the Mott-Cabrera theory was used to estimate the growth of the surface oxide layer formed during droplet flight. The calculated oxide volume fraction of an average droplet at impact agrees well with the experimentally determined oxide content for a typical TWEA-sprayed aluminum coating, which ranges from 3.3 to 12.7%. An explanation is provided for the elevated, nearly constant surface temperature (~ 2000 oC) of the droplets during flight to the substrate and shows that the majority of oxide content in the coating is produced during flight, rather than after deposition.

  19. On rapid plasma rotation

    SciTech Connect (OSTI)

    Helander, P.

    2007-10-15

    The conditions under which rapid plasma rotation may occur in a general three-dimensional magnetic field with flux surfaces, such as that of a stellarator, are investigated. Rotation velocities comparable to the ion thermal speed are found to be attainable only in magnetic fields whose strength B depends on the arc length l along the field in approximately the same way for all field lines on each flux surface {psi}, i.e., B{approx_equal}f({psi},l). Moreover, it is shown that the rotation must be in the direction of the vector {nabla}{psi}x{nabla}B.

  20. Rapid Thermal Pyrolysis of Interferometrically Patterned Resist...

    Office of Scientific and Technical Information (OSTI)

    (SNL-NM), Albuquerque, NM (United States) Sponsoring Org: USDOE National Nuclear Security Administration (NNSA) Country of Publication: United States Language: English...

  1. Thermally Activated Martensite: Its Relationship to Non-Thermally Activated (Athermal) Martensite

    SciTech Connect (OSTI)

    Laughlin, D E; Jones, N J; Schwartz, A J; Massalski, T B

    2008-10-21

    The classification of martensitic displacive transformations into athermal, isothermal or anisothermal is discussed. Athermal does not mean 'no temperature dependence' as is often thought, but is best considered to be short for the notion of no thermal activation. Processes with no thermal activation do not depend on time, as there is no need to wait for sufficient statistical fluctuations in some specific order parameter to overcome an activation barrier to initiate the process. Clearly, this kind of process contrasts with those that are thermally activated. In the literature, thermally activated martensites are usually termed isothermal martensites, suggesting a constant temperature. Actually such martensites also typically occur with continuous cooling. The important distinctive feature of these martensites is that they are thermally activated and hence are distinguishable in principle from athermal martensites. A third type of process, anisothermal, has been introduced to account for those transformations which are thought to be thermally activated but which occur on continuous cooling. They may occur so rapidly that they do not appear to have an incubation time, and hence could be mistakenly called an athermal transformation. These designations will be reviewed and discussed in terms of activation energies and kinetic processes of the various martensitic transformations.

  2. Hydropower RAPID Toolkit | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydropower RAPID Toolkit Hydropower RAPID Toolkit Hydropower RAPID Toolkit Providing project permitting process information for hydropower developers. Navigating the complex system of federal and state regulations to secure project approvals can be one of the biggest hurdles hydropower developers face. The U.S. Department of Energy (DOE) Hydropower Regulatory and Permitting Information Desktop (RAPID) Toolkit offers a solution. The Hydropower RAPID Toolkit makes permitting information easily

  3. Numerical Study Of Melted Particles Crush Metallic Substrates And The Interaction Between Particles And A Plasma Beam In The Thermal Projection Process

    SciTech Connect (OSTI)

    Kriba, Ilhem; Djebaili, A.

    2008-09-23

    Plasma spray processes have been widely used to produce high performance coatings of a wide range of Materials (metallic, non-metallic, ceramics), offering protection from, eg. wear, extreme temperature, chemical attack and environmental corrosion. To obtain good quality coatings, spray parameters must be carefully selected. Due to the large variety in process parameters, it is difficult to optimize the process for each specific coating and substrate combinations. Furthermore modelling the spray process allows a better understanding of the process sequences during thermal spraying. Good agreement of the virtual spraying process with the real coating formation is achieved by modelling the particular process steps. The simulation of coating formation to estimate the process parameters is an important tool to develop new coating structures with defined properties. In this work, the process of plasma sprayed coating has been analyzed by numerical simulation. Commercial code is used to predict the plasma jet characteristics, plasma--particle interaction, and coating formation. Using this model we can obtain coating microstructure and characteristics which form a foundation for further improvement of an advanced ceramic coating build up model.

  4. Tungsten-rhenium composite tube fabricated by CVD for application in 1800/sup 0/C high thermal efficiency fuel processing furnace

    SciTech Connect (OSTI)

    Svedberg, R.C.; Bowen, W.W.; Buckman, R.W. Jr.

    1980-04-01

    Chemical Vapor Deposit (CVD) rhenium was selected as the muffle material for an 1800/sup 0/C high thermal efficiency fuel processing furnace. The muffle is exposed to high vacuum on the heater/insulation/instrumentation side and to a flowing argon-8 V/0 hydrogen gas mixture at one atmosphere pressure on the load volume side. During operation, the muffle cycles from room temperature to 1800/sup 0/C and back to room temperature once every 24 hours. Operational life is dependent on resistance to thermal fatigue during the high temperature exposure. For a prototypical furnace, the muffle is approximately 13 cm I.D. and 40 cm in length. A small (about one-half size) rhenium closed end tube overcoated with tungsten was used to evaluate the concept. The fabrication and testing of the composite tungsten-rhenium tube and prototypic rhenium muffle is described.

  5. Advances in rapid prototyping

    SciTech Connect (OSTI)

    Atwood, C.L.; McCarty, G.D.; Pardo, B.T.; Bryce, E.A.

    1993-12-31

    Recent advances in stereolithography and selective laser sintering have had a significant impact on the overall quality of parts produced using these rapid prototyping processes. The development and implementation of 3D System`s QuickCast{trademark} resin and software for building investment casting patterns have proven to be major steps toward fabricating highly accurate patterns with very good surface finishes. Sandia uses patterns generated from rapid prototyping processes to reduce the cycle time and cost of fabricating prototype parts in support of a Sandia National Laboratories managed program called FASTCAST. As participants in the Beta test program for QuickCast{trademark} resin and software, they experienced a steep learning curve and were able to build accurate parts in a short period of time. It is now possible, using this technology, to produce highly accurate prototype parts as well as acceptable firs article and small lots size production parts. They use the Selective Laser Sintering (SLS) process to fabricate prototype wax patterns for investment casting. DTM Corporation recently introduced the use of their polycarbonate material for fabricating investment casting patterns. The polycarbonate material is processed significantly faster, with improved strength, dimensional stability, and without a support structure during the build process. Sandia is currently changing from investment casting wax to polycarbonate for the fabrication of investment casting patterns using the SLS process. This presentation will focus on the successes with these new materials from the standpoints of application, accuracy, surface finish, and post processing. Also presented will be examples of parts manufactured by these processes.

  6. Thermal Integration of CO{sub 2} Compression Processes with Coal-Fired Power Plants Equipped with Carbon Capture

    SciTech Connect (OSTI)

    Edward Levy

    2012-06-29

    Coal-fired power plants, equipped either with oxycombustion or post-combustion CO{sub 2} capture, will require a CO{sub 2} compression system to increase the pressure of the CO{sub 2} to the level needed for sequestration. Most analyses show that CO{sub 2} compression will have a significant effect on parasitic load, will be a major capital cost, and will contribute significantly to reduced unit efficiency. This project used first principle engineering analyses and computer simulations to determine the effects of utilizing compressor waste heat to improve power plant efficiency and increase net power output of coal-fired power plants with carbon capture. This was done for units with post combustion solvent-based CO{sub 2} capture systems and for oxyfired power plants, firing bituminous, PRB and lignite coals. The thermal integration opportunities analyzed for oxycombustion capture are use of compressor waste heat to reheat recirculated flue gas, preheat boiler feedwater and predry high-moisture coals prior to pulverizing the coal. Among the thermal integration opportunities analyzed for post combustion capture systems are use of compressor waste heat and heat recovered from the stripper condenser to regenerate post-combustion CO{sub 2} capture solvent, preheat boiler feedwater and predry high-moisture coals. The overall conclusion from the oxyfuel simulations is that thermal integration of compressor heat has the potential to improve net unit heat rate by up to 8.4 percent, but the actual magnitude of the improvement will depend on the type of heat sink used and to a lesser extent, compressor design and coal rank. The simulations of a unit with a MEA post combustion capture system showed that thermal integration of either compressor heat or stripper condenser heat to preheat boiler feedwater would result in heat rate improvements from 1.20 percent to 4.19 percent. The MEA capture simulations further showed that partial drying of low rank coals, done in combination

  7. Liquid Salts as Media for Process Heat Transfer from VHTR's: Forced Convective Channel Flow Thermal Hydraulics, Materials, and Coating

    SciTech Connect (OSTI)

    Sridharan, Kumar; Anderson, Mark; Allen, Todd; Corradini, Michael

    2012-01-30

    The goal of this NERI project was to perform research on high temperature fluoride and chloride molten salts towards the long-term goal of using these salts for transferring process heat from high temperature nuclear reactor to operation of hydrogen production and chemical plants. Specifically, the research focuses on corrosion of materials in molten salts, which continues to be one of the most significant challenges in molten salts systems. Based on the earlier work performed at ORNL on salt properties for heat transfer applications, a eutectic fluoride salt FLiNaK (46.5% LiF-11.5%NaF-42.0%KF, mol.%) and a eutectic chloride salt (32%MgCl2-68%KCl, mole %) were selected for this study. Several high temperature candidate Fe-Ni-Cr and Ni-Cr alloys: Hastelloy-N, Hastelloy-X, Haynes-230, Inconel-617, and Incoloy-800H, were exposed to molten FLiNaK with the goal of understanding corrosion mechanisms and ranking these alloys for their suitability for molten fluoride salt heat exchanger and thermal storage applications. The tests were performed at 850C for 500 h in sealed graphite crucibles under an argon cover gas. Corrosion was noted to occur predominantly from dealloying of Cr from the alloys, an effect that was particularly pronounced at the grain boundaries Alloy weight-loss due to molten fluoride salt exposure correlated with the initial Cr-content of the alloys, and was consistent with the Cr-content measured in the salts after corrosion tests. The alloys weight-loss was also found to correlate to the concentration of carbon present for the nominally 20% Cr containing alloys, due to the formation of chromium carbide phases at the grain boundaries. Experiments involving molten salt exposures of Incoloy-800H in Incoloy-800H crucibles under an argon cover gas showed a significantly lower corrosion for this alloy than when tested in a graphite crucible. Graphite significantly accelerated alloy corrosion due to the reduction of Cr from solution by graphite and formation

  8. RAPID FREEFORM SHEET METAL FORMING: TECHNOLOGY DEVELOPMENT AND...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RAPID FREEFORM SHEET METAL FORMING: TECHNOLOGY DEVELOPMENT AND SYSTEM VERIFICATION RAPID ... typically required as part of the prototyping process in automotive and aerospace design. ...

  9. IDENTIFICATION OF AN {sup 84}Sr-DEPLETED CARRIER IN PRIMITIVE METEORITES AND IMPLICATIONS FOR THERMAL PROCESSING IN THE SOLAR PROTOPLANETARY DISK

    SciTech Connect (OSTI)

    Paton, Chad; Schiller, Martin; Bizzarro, Martin E-mail: schiller@snm.ku.dk

    2013-02-01

    The existence of correlated nucleosynthetic heterogeneities in solar system reservoirs is now well demonstrated for numerous nuclides. However, it has proven difficult to discriminate between the two disparate processes that can explain such correlated variability: incomplete mixing of presolar material or secondary processing of a well-mixed disk. Using stepwise acid-leaching of the Ivuna CI-chondrite, we show that unlike other nuclides such as {sup 54}Cr and {sup 50}Ti, Sr-isotope variability is the result of a carrier depleted in {sup 84}Sr. The carrier is most likely presolar SiC, which is known to have both high Sr-concentrations relative to solar abundances and extremely depleted {sup 84}Sr compositions. Thus, variability in {sup 84}Sr in meteorites and their components can be attributed to varying contributions from presolar SiC. The observed {sup 84}Sr excesses in calcium-aluminum refractory inclusions (CAIs) suggest their formation from an SiC-free gaseous reservoir, whereas the {sup 84}Sr depletions present in differentiated meteorites require their formation from material with an increased concentration of SiC relative to CI chondrites. The presence of a positive correlation between {sup 84}Sr and {sup 54}Cr, despite being hosted in carriers of negative and positive anomalies, respectively, is not compatible with incomplete mixing of presolar material but instead suggests that the solar system's nucleosynthetic heterogeneity reflects selective thermal processing of dust. Based on vaporization experiments of SiC under nebular conditions, the lack of SiC material in the CAI-forming gas inferred from our data requires that the duration of thermal processing of dust resulting in the vaporization of CAI precursors was extremely short-lived, possibly lasting only hours to days.

  10. A literature review of coupled thermal-hydrologic-mechanical-chemical processes pertinent to the proposed high-level nuclear waste repository at Yucca Mountain

    SciTech Connect (OSTI)

    Manteufel, R.D.; Ahola, M.P.; Turner, D.R.; Chowdhury, A.H.

    1993-07-01

    A literature review has been conducted to determine the state of knowledge available in the modeling of coupled thermal (T), hydrologic (H), mechanical (M), and chemical (C) processes relevant to the design and/or performance of the proposed high-level waste (HLW) repository at Yucca Mountain, Nevada. The review focuses on identifying coupling mechanisms between individual processes and assessing their importance (i.e., if the coupling is either important, potentially important, or negligible). The significance of considering THMC-coupled processes lies in whether or not the processes impact the design and/or performance objectives of the repository. A review, such as reported here, is useful in identifying which coupled effects will be important, hence which coupled effects will need to be investigated by the US Nuclear Regulatory Commission in order to assess the assumptions, data, analyses, and conclusions in the design and performance assessment of a geologic reposit``. Although this work stems from regulatory interest in the design of the geologic repository, it should be emphasized that the repository design implicitly considers all of the repository performance objectives, including those associated with the time after permanent closure. The scope of this review is considered beyond previous assessments in that it attempts with the current state-of-knowledge) to determine which couplings are important, and identify which computer codes are currently available to model coupled processes.

  11. Oxidation-resistant, solution-processed plasmonic Ni nanochain-SiO{sub x} (x < 2) selective solar thermal absorbers

    SciTech Connect (OSTI)

    Yu, Xiaobai; Wang, Xiaoxin; Liu, Jifeng; Zhang, Qinglin; Li, Juchuan

    2014-08-21

    Metal oxidation at high temperatures has long been a challenge in cermet solar thermal absorbers, which impedes the development of atmospherically stable, high-temperature, high-performance concentrated solar power (CSP) systems. In this work, we demonstrate solution-processed Ni nanochain-SiO{sub x} (x < 2) and Ni nanochain-SiO{sub 2} selective solar thermal absorbers that exhibit a strong anti-oxidation behavior up to 600 °C in air. The thermal stability is far superior to previously reported Ni nanoparticle-Al{sub 2}O{sub 3} selective solar thermal absorbers, which readily oxidize at 450 °C. The SiO{sub x} (x < 2) and SiO{sub 2} matrices are derived from hydrogen silsesquioxane and tetraethyl orthosilicate precursors, respectively, which comprise Si-O cage-like structures and Si-O networks. Fourier transform infrared spectroscopy shows that the dissociation of Si-O cage-like structures and Si-O networks at high temperatures have enabled the formation of new bonds at the Ni/SiO{sub x} interface to passivate the surface of Ni nanoparticles and prevent oxidation. X-ray photoelectron spectroscopy and Raman spectroscopy demonstrate that the excess Si in the SiO{sub x} (x < 2) matrices reacts with Ni nanostructures to form silicides at the interfaces, which further improves the anti-oxidation properties. As a result, Ni-SiO{sub x} (x < 2) systems demonstrate better anti-oxidation performance than Ni-SiO{sub 2} systems. This oxidation-resistant Ni nanochain-SiO{sub x} (x < 2) cermet coating also exhibits excellent high-temperature optical performance, with a high solar absorptance of ∼90% and a low emittance ∼18% measured at 300 °C. These results open the door towards atmospheric stable, high temperature, high-performance solar selective absorber coatings processed by low-cost solution-chemical methods for future generations of CSP systems.

  12. Low thermal budget photonic processing of highly conductive Cu interconnects based on CuO nanoinks. Potential for flexible printed electronics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rager, Matthew S.; Aytug, Tolga; Veith, Gabriel M.; Joshi, Pooran C.

    2015-12-31

    The developing field of printed electronics nanoparticle based inks such as CuO show great promise as a low-cost alternative to other metal-based counterparts (e.g., silver). In particular, CuO inks significantly eliminate the issue of particle oxidation, before and during the sintering process, that is prevalent in Cu-based formulations. We report here the scalable and low-thermal budget photonic fabrication of Cu interconnects employing a roll-to-roll compatible pulse-thermal-processing (PTP) technique that enables phase reduction and subsequent sintering of inkjet-printed CuO patterns onto flexible polymer templates. Detailed investigations of curing and sintering conditions were performed to understand the impact of PTP system conditionsmore » on the electrical performance of the Cu patterns. Specifically, the impact of energy and power of photonic pulses on print conductivity was systematically studied by varying the following key processing parameters: pulse intensity, duration and sequence. Through optimization of such parameters, highly conductive prints in < 1 s with resistivity values as low as 100 n m has been achieved. We also observed that the introduction of an initial ink-drying step in ambient atmosphere, after the printing and before sintering, leads to significant improvements in mechanical integrity and electrical performance of the printed Cu patterns. Moreover, the viability of CuO reactive inks, coupled with the PTP technology and pre ink-drying protocols, has also been demonstrated for the additive integration of a low-cost Cu temperature sensor onto a flexible polymer substrate.« less

  13. Low thermal budget photonic processing of highly conductive Cu interconnects based on CuO nanoinks. Potential for flexible printed electronics

    SciTech Connect (OSTI)

    Rager, Matthew S.; Aytug, Tolga; Veith, Gabriel M.; Joshi, Pooran C.

    2015-12-31

    The developing field of printed electronics nanoparticle based inks such as CuO show great promise as a low-cost alternative to other metal-based counterparts (e.g., silver). In particular, CuO inks significantly eliminate the issue of particle oxidation, before and during the sintering process, that is prevalent in Cu-based formulations. We report here the scalable and low-thermal budget photonic fabrication of Cu interconnects employing a roll-to-roll compatible pulse-thermal-processing (PTP) technique that enables phase reduction and subsequent sintering of inkjet-printed CuO patterns onto flexible polymer templates. Detailed investigations of curing and sintering conditions were performed to understand the impact of PTP system conditions on the electrical performance of the Cu patterns. Specifically, the impact of energy and power of photonic pulses on print conductivity was systematically studied by varying the following key processing parameters: pulse intensity, duration and sequence. Through optimization of such parameters, highly conductive prints in < 1 s with resistivity values as low as 100 n m has been achieved. We also observed that the introduction of an initial ink-drying step in ambient atmosphere, after the printing and before sintering, leads to significant improvements in mechanical integrity and electrical performance of the printed Cu patterns. Moreover, the viability of CuO reactive inks, coupled with the PTP technology and pre ink-drying protocols, has also been demonstrated for the additive integration of a low-cost Cu temperature sensor onto a flexible polymer substrate.

  14. Processing of hydroxylapatite coatings on titanium alloy bone prostheses

    DOE Patents [OSTI]

    Nastasi, M.A.; Levine, T.E.; Mayer, J.W.; Pizziconi, V.B.

    1998-10-06

    Processing of hydroxylapatite sol-gel films on titanium alloy bone prostheses. A method utilizing non-line-of-sight ion beam implantation and/or rapid thermal processing to provide improved bonding of layers of hydroxylapatite to titanium alloy substrates while encouraging bone ingrowth into the hydroxylapatite layers located away from the substrate, is described for the fabrication of prostheses. The first layer of hydroxylapatite is mixed into the substrate by the ions or rapidly thermally annealed, while subsequent layers are heat treated or densified using ion implantation to form layers of decreasing density and larger crystallization, with the outermost layers being suitable for bone ingrowth.

  15. Processing of hydroxylapatite coatings on titanium alloy bone prostheses

    DOE Patents [OSTI]

    Nastasi, Michael A.; Levine, Timothy E.; Mayer, James W.; Pizziconi, Vincent B.

    1998-01-01

    Processing of hydroxylapatite sol-gel films on titanium alloy bone prostheses. A method utilizing non-line-of-sight ion beam implantation and/or rapid thermal processing to provide improved bonding of layers of hydroxylapatite to titanium alloy substrates while encouraging bone ingrowth into the hydroxylapatite layers located away from the substrate, is described for the fabrication of prostheses. The first layer of hydroxylapatite is mixed into the substrate by the ions or rapidly thermally annealed, while subsequent layers are heat treated or densified using ion implantation to form layers of decreasing density and larger crystallization, with the outermost layers being suitable for bone ingrowth.

  16. Thermal Stability Of Formohydroxamic Acid

    SciTech Connect (OSTI)

    Fondeur, F. F.; Rudisill, T. S.

    2011-10-21

    The thermal stability of formohydroxamic acid (FHA) was evaluated to address the potential for exothermic decomposition during storage and its use in the uranium extraction process. Accelerating rate calorimetry showed rapid decomposition at a temperature above 65 {degree}?C; although, the rate of pressure rise was greater than two orders of magnitude less than the lower bound for materials which have no explosive properties with respect to transportation. FHA solutions in water and nitric acid did not reach runaway conditions until 150 {degree}?C. Analysis by differential scanning calorimetry showed that FHA melted at 67 {degree}?C and thermally decomposed at 90 {degree}?C with an enthalpy of -1924 J/g. The energics of the FHA thermal decomposition are comparable to those measured for aqueous solutions of hydroxylamine nitrate. Solid FHA should be stored in a location where the temperature does not exceed 20-25 {degree}?C. As a best practice, the solid material should be stored in a climate-controlled environment such as a refrigerator or freezer. FHA solutions in water are not susceptible to degradation by acid hydrolysis and are the preferred way to handle FHA prior to use.

  17. Thermal, tensile and rheological properties of high density polyethylene (HDPE) processed and irradiated by gamma-ray in different atmospheres

    SciTech Connect (OSTI)

    Ferreto, H. F. R. E-mail: ana-feitoza@yahoo.com.br; Oliveira, A. C. F. E-mail: ana-feitoza@yahoo.com.br; Parra, D. F. E-mail: ablugao@ipen.br; Lugo, A. B. E-mail: ablugao@ipen.br; Gaia, R.

    2014-05-15

    The aim of this paper is to investigate structural changes of high density polyethylene (HDPE) modified by ionizing radiation (gamma rays) in different atmospheres. The gamma radiation process for modification of commercial polymers is a widely applied technique to promote new physical-chemical and mechanical properties. Gamma irradiation originates free radicals which can induce chain scission or recombination, providing its annihilation, branching or crosslinking. This polymer was irradiated with gamma source of {sup 60}Co at doses of 5, 10, 20, 50 or 100 kGy at a dose rate of 5 kGy/h. The changes in molecular structure of HDPE, after gamma irradiations were evaluated using thermogravimetric analysis (TGA) and tensile machine and oscillatory rheology. The results showed the variations of the properties depending on the dose at each atmosphere.

  18. Rapid Toolkit Stakeholder Trial Demonstration

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Regulatory and Permitting Information Desktop (RAPID) Toolkit offers one location for agencies, developers, and industry stakeholders to work together on state and federal hydropower regulatory processes by using a wiki environment to share permitting guidance, regulations, contacts, and other relevant information.

  19. Rapid Diagnosis of Tuberculosis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rapid Diagnosis of Tuberculosis Rapid Diagnosis of Tuberculosis Rapid diagnosis of active tuberculosis to minimize associated mortality, and facilitate timely countermeasures A novel pathogen biomarker-based assay for the diagnosis of active tuberculosis and validated it in a blinded clinical study. Current diagnosis of active tuberculosis is inadequate, especially with HIV co-infection in endemic populations Detection of a suite of pathogen biomarkers using novel strategies Rapid, early

  20. Biomass Rapid Analysis Network (BRAN)

    SciTech Connect (OSTI)

    Not Available

    2003-10-01

    Helping the emerging biotechnology industry develop new tools and methods for real-time analysis of biomass feedstocks, process intermediates and The Biomass Rapid Analysis Network is designed to fast track the development of modern tools and methods for biomass analysis to accelerate the development of the emerging industry. The network will be led by industry and organized and coordinated through the National Renewable Energy Lab. The network will provide training and other activities of interest to BRAN members. BRAN members will share the cost and work of rapid analysis method development, validate the new methods, and work together to develop the training for the future biomass conversion workforce.

  1. Flexible thermal cycle test equipment for concentrator solar cells

    DOE Patents [OSTI]

    Hebert, Peter H.; Brandt, Randolph J.

    2012-06-19

    A system and method for performing thermal stress testing of photovoltaic solar cells is presented. The system and method allows rapid testing of photovoltaic solar cells under controllable thermal conditions. The system and method presents a means of rapidly applying thermal stresses to one or more photovoltaic solar cells in a consistent and repeatable manner.

  2. Solar-thermal reaction processing

    DOE Patents [OSTI]

    Weimer, Alan W; Dahl, Jaimee K; Lewandowski, Allan A; Bingham, Carl; Raska Buechler, Karen J; Grothe, Willy

    2014-03-18

    In an embodiment, a method of conducting a high temperature chemical reaction that produces hydrogen or synthesis gas is described. The high temperature chemical reaction is conducted in a reactor having at least two reactor shells, including an inner shell and an outer shell. Heat absorbing particles are included in a gas stream flowing in the inner shell. The reactor is heated at least in part by a source of concentrated sunlight. The inner shell is heated by the concentrated sunlight. The inner shell re-radiates from the inner wall and heats the heat absorbing particles in the gas stream flowing through the inner shell, and heat transfers from the heat absorbing particles to the first gas stream, thereby heating the reactants in the gas stream to a sufficiently high temperature so that the first gas stream undergoes the desired reaction(s), thereby producing hydrogen or synthesis gas in the gas stream.

  3. Advances in Hydrogen Isotope Separation Using Thermal Cycling...

    Office of Environmental Management (EM)

    Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Presentation ...

  4. Thermal stability of ferritic alloys for fossil-fuel processing systems. Final technical report, September 1, 1978-August 31, 1981. [at 475/sup 0/C

    SciTech Connect (OSTI)

    Polonis, D.H.; Spear, W.S.

    1981-12-31

    This research program has investigated the thermal stability of several ferritic stainless steels containing 15 to 18 weight percent chromium over the temperature range 400/sup 0/C to 550/sup 0/C where the 475/sup 0/C embrittlement reaction is of concern. A major part of the experimental work was concerned with the effect of ternary additions of up to 6 weight percent; aluminum on the kinetics and the magnitude of the embrittlement reaction. The work also included a binary Fe-18Cr alloy, a ternary Fe-18Cr-2Mo, and two commercial alloys, Armco type 430 and type 18SR. Resistometric studies of the kinetics of microstructural instability indicated that aluminum additions promote the tendency of chromium atoms to cluster at temperatures in the vicinity of 475/sup 0/C. The magnitude of embrittling reaction is intensified by the aluminum additions which are expected to restrict dislocation cross slip and increase the coherency strains associated with the alpha prime precipitates. Activation energy determinations for the decomposition reaction indicate that the rate controlling process is most likely determined by the diffusion of chromium, and the tendency of aluminum to enhance the clustering of chromium atoms is similar to the effect reported for molybdenum additions by previous workers.

  5. Room-temperature thermally induced relaxation effect in a two-dimensional cyano-bridged Cu-Mo bimetal assembly and thermodynamic analysis of the relaxation process

    SciTech Connect (OSTI)

    Umeta, Yoshikazu; Ozaki, Noriaki; Tokoro, Hiroko; Ohkoshi, Shin-ichi

    2013-04-15

    We observed a photo-switching effect in [Cu{sup II}(1,4,8,11-tetraazacyclodecane)]{sub 2}[Mo{sup IV}(CN){sub 8}]{center_dot}10H{sub 2}O by irradiation with 410-nm light around room temperature using infrared spectroscopy. This photo-switching is caused by the photo-induced charge transfer from Mo{sup IV} to Cu{sup II}. The photo-induced phase thermally relaxed to the initial phase with a half-life time of 2.7 Multiplication-Sign 10{sup 1}, 6.9 Multiplication-Sign 10{sup 1}, and 1.7 Multiplication-Sign 10{sup 2} s at 293, 283, and 273 K, respectively. The relaxation process was analyzed using Hauser's equation, k=k{sub 0}exp[-(E{sub a}+E{sub a}{sup *}{gamma}) /k{sub B}T], where k is the rate constant of relaxation, k{sub 0} is the frequency factor, E{sub a} is the activation energy, E{sub a}{sup *} is the additional activation energy due to the cooperativity, and {gamma} is the fraction of the photo-induced phase. k{sub 0}, E{sub a}, and E{sub a}{sup *} were evaluated as 1.28 Multiplication-Sign 10{sup 7}{+-} 2.6 s{sup -1}, 4002 {+-} 188 cm{sup -1}, and 546 {+-} 318 cm{sup -1}, respectively. The value of E{sub a} is much larger than that of the relaxation process for the typical light-induced spin crossover effect (E{sub a} Almost-Equal-To 1000 cm{sup -1}). Room-temperature photo-switching is an important issue in the field of optical functional materials. The present system is useful for the demonstration of high-temperature photo-switching material.

  6. Thermal Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Sciences NETL's Thermal Sciences competency provides the scientific, engineering, and technology development community with innovative and efficient approaches to measure, harness, and convert thermal energy. Research includes sensors, advanced energy concepts, and thermodynamic optimization, specifically: Sensors and Diagnostics Advanced sensor and diagnostic technology to develop and evaluate advanced methods for non-intrusive measurement and measurement in extreme environments.

  7. Method and device for predicting wavelength dependent radiation influences in thermal systems

    DOE Patents [OSTI]

    Kee, Robert J.; Ting, Aili

    1996-01-01

    A method and apparatus for predicting the spectral (wavelength-dependent) radiation transport in thermal systems including interaction by the radiation with partially transmitting medium. The predicted model of the thermal system is used to design and control the thermal system. The predictions are well suited to be implemented in design and control of rapid thermal processing (RTP) reactors. The method involves generating a spectral thermal radiation transport model of an RTP reactor. The method also involves specifying a desired wafer time dependent temperature profile. The method further involves calculating an inverse of the generated model using the desired wafer time dependent temperature to determine heating element parameters required to produce the desired profile. The method also involves controlling the heating elements of the RTP reactor in accordance with the heating element parameters to heat the wafer in accordance with the desired profile.

  8. GRAIN-SCALE FAILURE IN THERMAL SPALLATION DRILLING

    SciTech Connect (OSTI)

    Walsh, S C; Lomov, I; Roberts, J J

    2012-01-19

    Geothermal power promises clean, renewable, reliable and potentially widely-available energy, but is limited by high initial capital costs. New drilling technologies are required to make geothermal power financially competitive with other energy sources. One potential solution is offered by Thermal Spallation Drilling (TSD) - a novel drilling technique in which small particles (spalls) are released from the rock surface by rapid heating. While TSD has the potential to improve drilling rates of brittle granitic rocks, the coupled thermomechanical processes involved in TSD are poorly described, making system control and optimization difficult for this drilling technology. In this paper, we discuss results from a new modeling effort investigating thermal spallation drilling. In particular, we describe an explicit model that simulates the grain-scale mechanics of thermal spallation and use this model to examine existing theories concerning spalling mechanisms. We will report how borehole conditions influence spall production, and discuss implications for macro-scale models of drilling systems.

  9. Notices Rapides Parish Rapides Parish Library, 411 Washington...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Notices Rapides Parish Rapides Parish Library, 411 Washington St., Alexandria, 15001005 ... (NPS), has made available for public review and comment the Draft Environmental ...

  10. Rapid road repair vehicle

    DOE Patents [OSTI]

    Mara, Leo M.

    1999-01-01

    Disclosed are improvments to a rapid road repair vehicle comprising an improved cleaning device arrangement, two dispensing arrays for filling defects more rapidly and efficiently, an array of pre-heaters to heat the road way surface in order to help the repair material better bond to the repaired surface, a means for detecting, measuring, and computing the number, location and volume of each of the detected surface imperfection, and a computer means schema for controlling the operation of the plurality of vehicle subsystems. The improved vehicle is, therefore, better able to perform its intended function of filling surface imperfections while moving over those surfaces at near normal traffic speeds.

  11. Thermal disconnect for high-temperature batteries

    DOE Patents [OSTI]

    Jungst, Rudolph George; Armijo, James Rudolph; Frear, Darrel Richard

    2000-01-01

    A new type of high temperature thermal disconnect has been developed to protect electrical and mechanical equipment from damage caused by operation at extreme temperatures. These thermal disconnects allow continuous operation at temperatures ranging from 250.degree. C. to 450.degree. C., while rapidly terminating operation at temperatures 50.degree. C. to 150.degree. C. higher than the continuous operating temperature.

  12. Modelling the microstructure of thermal barrier coatings

    SciTech Connect (OSTI)

    Cirolini, S.; Marchese, M.; Jacucci, G.; Harding, J.H.; Mulheran, P.A.

    1994-12-31

    Thermal barrier coatings produced by plasma spraying have a characteristic microstructure of lamellae, pores and cracks. The lamellae are produced by the splashing of particles onto the substrate. As the coating grows, the lamellae pile on top of each other, producing an interlocking structure. In most cases the growth is rapid and chaotic. The result is a microstructure characterized by pores and cracks. The authors present an improved model for the deposition process of thermal barrier coatings. The task of modeling the coating growth is split into two parts: first the authors consider a description of the particle on arrival at the film, based on the available theoretical, numerical and experimental findings. Second they define and discuss a set of physically-based rules for combining these events to obtain the film. The splats run along the surface and are permitted to curl up (producing pores) or interlock. The computer model uses a mesh to combine these processes and build the coating. They discuss the use of the proposed model in predicting microstructures and hence in correlating the properties of these coatings with the parameters of the process used to make them.

  13. RAPID/Roadmap/18-CO-b | Open Energy Information

    Open Energy Info (EERE)

    permitting process. Because of the inherent danger of fire, explosion or evolution of toxic gases involved in thermal treatment and treatment of reactive wastes, these are...

  14. RAPID/Roadmap/7-CA-b | Open Energy Information

    Open Energy Info (EERE)

    (AFC) power plant licensing process through the Small Power Plant Exemption (SPPE) if the thermal power plant does not have unmitigated adverse impacts on the environment or energy...

  15. Realistic Financial Planning and Rapid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Realistic Financial Planning and Rapid Modification to Project Execution are Essential ... Ignition Facility Title: Realistic Financial Planning and Rapid Modification to ...

  16. Thermal synthesis apparatus

    DOE Patents [OSTI]

    Fincke, James R [Idaho Falls, ID; Detering, Brent A [Idaho Falls, ID

    2009-08-18

    An apparatus for thermal conversion of one or more reactants to desired end products includes an insulated reactor chamber having a high temperature heater such as a plasma torch at its inlet end and, optionally, a restrictive convergent-divergent nozzle at its outlet end. In a thermal conversion method, reactants are injected upstream from the reactor chamber and thoroughly mixed with the plasma stream before entering the reactor chamber. The reactor chamber has a reaction zone that is maintained at a substantially uniform temperature. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle, which "freezes" the desired end product(s) in the heated equilibrium reaction stage, or is discharged through an outlet pipe without the convergent-divergent nozzle. The desired end products are then separated from the gaseous stream.

  17. Next Generation Manufacturing Processes

    Broader source: Energy.gov [DOE]

    New process technologies can rejuvenate U.S. manufacturing. Novel processing concepts can open pathways to double net energy productivity, enabling rapid manufacture of energy-efficient, high...

  18. Calibrating thermal behavior of electronics

    DOE Patents [OSTI]

    Chainer, Timothy J.; Parida, Pritish R.; Schultz, Mark D.

    2016-05-31

    A method includes determining a relationship between indirect thermal data for a processor and a measured temperature associated with the processor, during a calibration process, obtaining the indirect thermal data for the processor during actual operation of the processor, and determining an actual significant temperature associated with the processor during the actual operation using the indirect thermal data for the processor during actual operation of the processor and the relationship.

  19. Rapid road repair vehicle

    DOE Patents [OSTI]

    Mara, L.M.

    1998-05-05

    Disclosed is a rapid road repair vehicle capable of moving over a surface to be repaired at near normal posted traffic speeds to scan for and find at the high rate of speed, imperfections in the pavement surface, prepare the surface imperfection for repair by air pressure and vacuum cleaning, applying a correct amount of the correct patching material to effect the repair, smooth the resulting repaired surface, and catalog the location and quality of the repairs for maintenance records of the road surface. The rapid road repair vehicle can repair surface imperfections at lower cost, improved quality, at a higher rate of speed than was not heretofor possible, with significantly reduced exposure to safety and health hazards associated with this kind of road repair activities in the past. 2 figs.

  20. Rapid road repair vehicle

    DOE Patents [OSTI]

    Mara, Leo M.

    1998-01-01

    Disclosed is a rapid road repair vehicle capable of moving over a surface to be repaired at near normal posted traffic speeds to scan for and find an the high rate of speed, imperfections in the pavement surface, prepare the surface imperfection for repair by air pressure and vacuum cleaning, applying a correct amount of the correct patching material to effect the repair, smooth the resulting repaired surface, and catalog the location and quality of the repairs for maintenance records of the road surface. The rapid road repair vehicle can repair surface imperfections at lower cost, improved quality, at a higher rate of speed than was was heretofor possible, with significantly reduced exposure to safety and health hazards associated with this kind of road repair activities in the past.

  1. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, R.W.

    1982-09-20

    A rapidly refuelable dual cell of an electrochemical type is described wherein a single anode cooperates with two cathodes and wherein the anode has a fixed position and the cathodes are urged toward opposite faces of the anodes at constant and uniform force. The associated cathodes are automatically retractable to permit the consumed anode remains to be removed from the housing and a new anode inserted between the two cathodes.

  2. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, Richard W. (Santa Clara, CA)

    1985-01-01

    A rapidly refuelable dual cell of an electrochemical type wherein a single anode cooperates with two cathodes and wherein the anode has a fixed position and the cathodes are urged toward opposite faces of the anodes at constant and uniform force. The associated cathodes are automatically retractable to permit the consumed anode remains to be removed from the housing and a new anode inserted between the two cathodes.

  3. Rapid Solar Mirror Characterization with Fringe Reflection Techniques -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Thermal Solar Thermal Energy Analysis Energy Analysis Find More Like This Return to Search Rapid Solar Mirror Characterization with Fringe Reflection Techniques SOFAST: Sandia Optical Fringe Analysis Slope Tool Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (834 KB) SOFAST Imaging SOFAST Imaging Technology Marketing SummaryThis technology is an automated system in which the reflection of a mirror,

  4. Vehicle Technologies Office Merit Review 2016: Commercial Vehicle Thermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Load Reduction and VTCab -- Rapid HVAC Load Estimation Tool | Department of Energy Commercial Vehicle Thermal Load Reduction and VTCab -- Rapid HVAC Load Estimation Tool Vehicle Technologies Office Merit Review 2016: Commercial Vehicle Thermal Load Reduction and VTCab -- Rapid HVAC Load Estimation Tool Presentation given by National Renewable Energy Laboratory (NREL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation

  5. Rapid prototype and test

    SciTech Connect (OSTI)

    Gregory, D.L.; Hansche, B.D.

    1996-06-01

    In order to support advanced manufacturing, Sandia has acquired the capability to produce plastic prototypes using stereolithography. Currently, these prototypes are used mainly to verify part geometry and ``fit and form`` checks. This project investigates methods for rapidly testing these plastic prototypes, and inferring from prototype test data actual metal part performance and behavior. Performances examined include static load/stress response, and structural dynamic (modal) and vibration behavior. The integration of advanced non-contacting measurement techniques including scanning laser velocimetry, laser holography, and thermoelasticity into testing of these prototypes is described. Photoelastic properties of the epoxy prototypes to reveal full field stress/strain fields are also explored.

  6. Thermal battery

    SciTech Connect (OSTI)

    Williams, M.T.; Winchester, C.S.; Jolson, J.D.

    1989-06-20

    A thermal battery is described comprising at least one electrochemical cell comprising an anode of alkali metal, alkaline earth metal or alloys thereof, a fusible salt electrolyte, a fluorocarbon polymer or fluorochlorocarbon polymer depolarizer, and means for heating the cell to melt the electrolyte.

  7. Plasma-Thermal Synthesis - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Synthesis Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL's Plasma-Thermal Synthesis process improves the conversion process for natural gas into liquid hydrocarbon fuels. Description This process provides a method and apparatus for increasing acetylene yield from the thermal conversion of natural gas. The reactants inserted into the reactor chamber are applied at a high temperature of ionized gas. At this time, the reactants are changed to

  8. rapidMCR

    Energy Science and Technology Software Center (OSTI)

    2011-11-04

    rapidMCR is a user friendly software package that includes automatic preprocessing, analysis, and viewing of hyperspectral image data sets. Currently, this software package specifically preprocesses and analyzes hyperspectral fluorescence image data sets that have been created on Sandia hyperspectral imaging microscopes; however, this software can be modified to include spectroscopic image data sets from other (non-Sandia developed) instruments as well. This software relies on using prior information about the spectroscopic image data sets by conductingmore » a rigorous characterization of the instrument. By characterizing the instrument for noise and artifacts, we can implement our algorithms to account for the effects specific to a particular instrument. This allows us to automate the data preprocessing while improving the analysis results.« less

  9. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    Smith, P.; Deo, M.; Eddings, E.; Sarofim, A.; Gueishen, K.; Hradisky, M.; Kelly, K.; Mandalaparty, P.; Zhang, H.

    2012-01-11

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coal's carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO2 sequestration.

  10. Thermal, chemical, and mass-transport processes induced in abyssal sediments by the emplacement of nuclear waste: experimental and modeling results

    SciTech Connect (OSTI)

    McVey, D.F.; Erickson, K.L.; Seyfried, W.

    1980-01-01

    This paper discusses heat and mass transport studies of marine red clay sediments being considered as a nuclear waste isolation medium. Numerical models indicate that for a maximum allowable sediment/canister interface temperature of 200 to 250/sup 0/C, the sediment can absorb about 1.5 kW initial power from waste in a 3 m long by 0.3 m dia canister buried 30 m in the sediment. Fluid displacement due to convection is found to be less than 1 m. Laboratory studies of the geochemical effects induced by heating sediment/seawater mixtures indicate that the canister and waste form must be designed to resist a hot, acid (pH 3 to 4) oxidizing environment. Since the thermally altered sediment volume of about 5.5 m/sup 3/ is small relative to the sediment volume overlying the canister, the acid and oxidizing conditions are not anticipated to effect the properties of the far field. Using sorption coefficient correlations, the migration of four nuclides /sup 239/Pu, /sup 137/Cs, /sup 129/I, and /sup 99/Tc were computer for a canister buried 30 m deep in a 60 m thick red clay sediment layer. It was found that the /sup 239/Pu and /sup 137/Cs are essentially completely contained in the sediments, while /sup 129/I and /sup 99/Tc broke through the 30 m of sediment in about 5000 years. The resultant peak injection rates of 4.6 x 10/sup -5/ ..mu..Ci/year-m/sup 2/ for /sup 129/I and 1.6 x 10/sup -2/ ..mu..Ci/year-m/sup 2/ for /sup 99/Tc were less than the natural radioactive flux of /sup 226/Ra (3.5 to 8.8 x 10/sup -4/ ..mu..Ci/year-m/sup 2/) and /sup 222/Rn (0.26 to 0.88 ..mu..Ci/year-m/sup 2/).

  11. Fastcast: Integration and application of rapid prototyping and computational simulation to investment casting

    SciTech Connect (OSTI)

    Maguire, M.C.; Baldwin, M.D.; Atwood, C.L.

    1996-09-01

    The emergence of several rapid prototyping and manufacturing (RP and M) technologies is having a dramatic impact on investment casting. While the most successful of the rapid prototyping technologies are almost a decade old, relatively recent process advances in their application have produced some remarkable success in utilizing their products as patterns for investment castings. Sandia National Laboratories has been developed highly coupled experimental and computational capabilities to examine the investment casting process with the intention of reducing the amount of time required to manufacture castings, and to increase the quality of the finished product. This presentation will begin with process aspects of RP and M pattern production and handling, shell fabrication, burnout, and casting. The emphasis will be on how the use of Stereolithography (SL) or Selective Laser Sintered (SLS) patterns differs from more traditional wax pattern processes. Aspects of computational simulation to couple design, thermal analysis, and mold filling will be discussed. Integration of these topics is probably the greatest challenge to the use of concurrent engineering principles with investment casting. Sandia has conducted several experiments aimed at calibrating computer codes and providing data for input into these simulations. Studies involving materials as diverse as stainless steel and gold have been conducted to determine liquid metal behavior in molds via real time radiography. The application of these experiments to predictive simulations will be described.

  12. 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS: ANALYTICAL RESULTS FOR TANK 48H ORGANIC DESTRUCTION - 10408

    SciTech Connect (OSTI)

    Williams, M.; Jantzen, C.; Burket, P.; Crawford, C.; Daniel, G.; Aponte, C.; Johnson, C.

    2009-12-28

    The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive contents of Tank 48H. FBSR Pilot Scaled Testing with the Tank 48H simulant has demonstrated the ability to remove greater than 98% of the nitrites and greater than 99.5% of the nitrates from the Tank 48H simulant, and to form a solid product that is primarily alkali carbonate. The alkali carbonate is soluble and, thus, amenable to pumping as a liquid to downstream facilities for processing. The FBSR technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration (ESTD) pilot scale steam reformer at the Hazen Research Inc. (HRI) facility in Golden, CO. Additional ESTD tests were completed in 2008 and in 2009 that further demonstrated the

  13. Millisecond ordering of block-copolymer films via photo-thermal gradients

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-03-12

    For the promise of self-assembly to be realized, processing techniques must be developed that simultaneously enable control of the nanoscale morphology, rapid assembly, and, ideally, the ability to pattern the nanostructure. Here, we demonstrate how photo-thermal gradients can be used to control the ordering of block-copolymer thin films. Highly localized laser heating leads to intense thermal gradients, which induce a thermophoretic force on morphological defects. This increases the ordering kinetics by at least 3 orders-of-magnitude, compared to conventional oven annealing. By simultaneously exploiting the thermal gradients to induce shear fields, we demonstrate uniaxial alignment of a block-copolymer film in lessmore » than a second. Finally, we provide examples of how control of the incident light-field can be used to generate prescribed configurations of block-copolymer nanoscale patterns.« less

  14. Millisecond ordering of block-copolymer films via photo-thermal gradients

    SciTech Connect (OSTI)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-03-12

    For the promise of self-assembly to be realized, processing techniques must be developed that simultaneously enable control of the nanoscale morphology, rapid assembly, and, ideally, the ability to pattern the nanostructure. Here, we demonstrate how photo-thermal gradients can be used to control the ordering of block-copolymer thin films. Highly localized laser heating leads to intense thermal gradients, which induce a thermophoretic force on morphological defects. This increases the ordering kinetics by at least 3 orders-of-magnitude, compared to conventional oven annealing. By simultaneously exploiting the thermal gradients to induce shear fields, we demonstrate uniaxial alignment of a block-copolymer film in less than a second. Finally, we provide examples of how control of the incident light-field can be used to generate prescribed configurations of block-copolymer nanoscale patterns.

  15. Toward understanding dynamic annealing processes in irradiated ceramics

    SciTech Connect (OSTI)

    Myers, Michael Thomas

    2013-05-01

    High energy particle irradiation inevitably generates defects in solids. The ballistic formation and thermalization of the defect creation process occur rapidly, and are believed to be reasonably well understood. However, knowledge of the evolution of defects after damage cascade thermalization, referred to as dynamic annealing, is quite limited. Unraveling the mechanisms associated with dynamic annealing is crucial since such processes play an important role in the formation of stable postirradiation disorder in ion-beam-processing of semiconductors, and determines the “radiation tolerance” of many nuclear materials. The purpose of this dissertation is to further our understanding of the processes involved in dynamic annealing. In order to achieve this, two main tasks are undertaken.

  16. Thermal dissolution of solid fossil fuels

    SciTech Connect (OSTI)

    E.G. Gorlov

    2007-10-15

    The use of oil shales and coals in the processes of thermal dissolution is considered. It is shown that thermal dissolution is a mode of liquefaction of solid fossil fuels and can be used both independently and in combination with liquefaction of coals and processing of heavy petroleum residues.

  17. RAPID/Roadmap/Coverage | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmapCoverage < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA RAPID Toolkit About Bulk Transmission...

  18. RAPID/Outreach | Open Energy Information

    Open Energy Info (EERE)

    Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Outreach Materials RAPID 2-page Flyer RAPID 2-page Flyer Last updated: 8 Apr 2014 RAPID Project...

  19. RAPID/Contact | Open Energy Information

    Open Energy Info (EERE)

    RAPIDContact < RAPID(Redirected from RAPID toolkitContact) Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission...

  20. Rapid doubling of the critical current of YBa{sub 2}Cu{sub 3}O{sub 7−δ} coated conductors for viable high-speed industrial processing

    SciTech Connect (OSTI)

    Leroux, M.; Welp, U.; Kwok, W.-K.; Kihlstrom, K. J.; Holleis, S.; Rupich, M. W.; Sathyamurthy, S.; Fleshler, S.; Sheng, H. P.; Miller, D. J.; Eley, S.; Civale, L.; Kayani, A.; Niraula, P. M.

    2015-11-09

    We demonstrate that 3.5-MeV oxygen irradiation can markedly enhance the in-field critical current of commercial second generation superconducting tapes with an exposure time of just 1 s per 0.8 cm{sup 2}. The speed demonstrated here is now at the level required for an industrial reel-to-reel post-processing. The irradiation is made on production line samples through the protective silver coating and does not require any modification of the growth process. From TEM imaging, we identify small clusters as the main source of increased vortex pinning.

  1. Rapid doubling of the critical current of Yba{sub 2}Cu{sub 3}O{sub 7-{delta}} coated conductor for viable high-speed industrial processing.

    SciTech Connect (OSTI)

    Leroux, M.; Kihlstrom, K. J.; Holleis, S.; Rupich, M. W.; Sathyamurthy, S.; Fleshler, S.; Sheng, H. P.; Miller, D. J.; Eley, S.; Civale, L.; Kayani, A.; Niraula, P. M.; Welp, U.; Kwok, W. -K.

    2015-11-09

    We demonstrate that 3.5-MeV oxygen irradiation can markedly enhance the in-field critical current of commercial 2nd generation superconducting tapes with an exposure time of just one second per 0.8 cm2. The speed demonstrated here is now at the level required for an industrial reel-to-reel post-processing. The irradiation is made on production line samples through the protective silver coating and does not require any modification of the growth process. From TEM imaging, we identify small clusters as the main source of increased vortex pinning.

  2. Thermal conductivity of thermal-battery insulations

    SciTech Connect (OSTI)

    Guidotti, R.A.; Moss, M.

    1995-08-01

    The thermal conductivities of a variety of insulating materials used in thermal batteries were measured in atmospheres of argon and helium using several techniques. (Helium was used to simulate the hydrogen atmosphere that results when a Li(Si)/FeS{sub 2} thermal battery ages.) The guarded-hot-plate method was used with the Min-K insulation because of its extremely low thermal conductivity. For comparison purposes, the thermal conductivity of the Min-K insulating board was also measured using the hot-probe method. The thermal-comparator method was used for the rigid Fiberfrax board and Fiberfrax paper. The thermal conductivity of the paper was measured under several levels of compression to simulate the conditions of the insulating wrap used on the stack in a thermal battery. The results of preliminary thermal-characterization tests with several silica aerogel materials are also presented.

  3. RAPID/Geothermal/Roadmap/Flowcharts | Open Energy Information

    Open Energy Info (EERE)

    components of the RAPID Toolkit. Existing Flowcharts by Section 0 - OverallFlow-1 01-FD-a - LandUsePlanning 01-FD-b - LandUsePlanAmendmentProcess 01AKALandUseConsiderations...

  4. High Temperature Thermal Array for Next Generation Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This ...

  5. Effects of thermal fluctuations on thermal inflation

    SciTech Connect (OSTI)

    Hiramatsu, Takashi; Miyamoto, Yuhei; Yokoyama, Jun’ichi

    2015-03-12

    The mechanism of thermal inflation, a relatively short period of accelerated expansion after primordial inflation, is a desirable ingredient for a certain class of particle physics models if they are not to be in contention with the cosmology of the early Universe. Though thermal inflation is most simply described in terms of a thermal effective potential, a thermal environment also gives rise to thermal fluctuations that must be taken into account. We numerically study the effects of these thermal fluctuations using lattice simulations. We conclude that though they do not ruin the thermal inflation scenario, the phase transition at the end of thermal inflation proceeds through phase mixing and is therefore not accompanied by the formations of bubbles nor appreciable amplitude of gravitational waves.

  6. Rapid prototyping: A paradigm shift in investment casting

    SciTech Connect (OSTI)

    Atwood, C.L.; Maguire, M.C.; Baldwin, M.D.; Pardo, B.T.

    1996-09-01

    The quest for fabricating complex metal parts rapidly and with minimal cost has brought rapid prototyping (RP) processes to the forefront of the investment casting industry. Relatively recent advances in DTM Corporation`s selective laser sintering (SLS) and 3D Systems stereolithography (SL) processes have had a significant impact on the overall quality of patterns produced using these rapid prototyping processes. Sandia National Laboratories uses patterns generated from rapid prototyping processes to reduce the cycle time and cost of fabricating prototype and small lot production parts in support of a program called FASTCAST. The SLS process is used to fabricate patterns from materials such as investment casting wax, polycarbonate, and a new material called TrueForm PM{trademark}. With the timely introduction of each of these materials, the quality of patterns fabricated has improved. The development and implementation of SL QuickCast{trademark} software has enabled this process to produce highly accurate patterns for use in investment casting. This paper focuses on the successes with these new pattern materials and the infrastructure required to cast rapid prototyping patterns successfully. In addition, a brief overview of other applications of rapid prototyping at Sandia will be discussed.

  7. Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption

    Office of Environmental Management (EM)

    Process (TCAP) | Department of Energy Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013. Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) (1.74 MB) More Documents & Publications A New Hydrogen Processing Demonstration System Initial

  8. High-speed thermal cycling system and method of use

    DOE Patents [OSTI]

    Hansen, A.D.A.; Jaklevic, J.M.

    1996-04-16

    A thermal cycling system and method of use are described. The thermal cycling system is based on the circulation of temperature-controlled water directly to the underside of thin-walled polycarbonate plates. The water flow is selected from a manifold fed by pumps from heated reservoirs. The plate wells are loaded with typically 15-20 microliters of reagent mix for the PCR process. Heat transfer through the thin polycarbonate is sufficiently rapid that the contents reach thermal equilibrium with the water in less than 15 seconds. Complete PCR amplification runs of 40 three-step cycles have been performed in as little as 14.5 minutes, with the results showing substantially enhanced specificity compared to conventional technology requiring run times in excess of 100 minutes. The plate clamping station is designed to be amenable to robotic loading and unloading of the system. It includes a heated lid, thus eliminating the need for mineral oil overlay of the reactants. The present system includes three or more plate holder stations, fed from common reservoirs but operating with independent switching cycles. The system can be modularly expanded. 13 figs.

  9. High-speed thermal cycling system and method of use

    DOE Patents [OSTI]

    Hansen, Anthony D. A.; Jaklevic, Joseph M.

    1996-01-01

    A thermal cycling system and method of use are described. The thermal cycling system is based on the-circulation of temperature-controlled water directly to the underside of thin-walled polycarbonate microtiter plates. The water flow is selected from a manifold fed by pumps from heated reservoirs. The plate wells are loaded with typically 15-20 .mu.l of reagent mix for the PCR process. Heat transfer through the thin polycarbonate is sufficiently rapid that the contents reach thermal equilibrium with the water in less than 15 seconds. Complete PCR amplification runs of 40 three-step cycles have been performed in as little as 14.5 minutes, with the results showing substantially enhanced specificity compared to conventional technology requiring run times in excess of 100 minutes. The plate clamping station is designed to be amenable to robotic loading and unloading of the system. It includes a heated lid, thus eliminating the need for mineral oil overlay of the reactants. The present system includes three or more plate holder stations, fed from common reservoirs but operating with independent switching cycles. The system can be modularly expanded.

  10. Interactive Rapid Dose Assessment Model.

    Energy Science and Technology Software Center (OSTI)

    1988-10-31

    IRDAM is a micro-computer based program for rapidly assessing the radiological impact of an accident at a nuclear power plant. The code packaged October 1988 is Version 3.

  11. Microwavable thermal energy storage material

    DOE Patents [OSTI]

    Salyer, I.O.

    1998-09-08

    A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments. 3 figs.

  12. Microwavable thermal energy storage material

    DOE Patents [OSTI]

    Salyer, Ival O.

    1998-09-08

    A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene-vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments.

  13. Selective thermal oxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz; Blatter, Fritz; Sun, Hai

    2000-01-01

    A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  14. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz; Blatter, Fritz; Sun, Hai

    2001-01-01

    A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  15. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, H.; Blatter, F.; Sun, H.

    1999-06-22

    A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

  16. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz; Blatter, Fritz; Sun, Hai

    1999-01-01

    A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  17. Thermal Control & System Integration

    Broader source: Energy.gov [DOE]

    The thermal control and system integration activity focuses on issues such as the integration of motor and power control technologies and the development of advanced thermal control technologies....

  18. Turbine Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbine Thermal Management Fact Sheets Research Team Members Key Contacts Turbine Thermal Management The gas turbine is the workhorse of power generation, and technology advances ...

  19. Superconductivity and magnetism in rapidly solidified perovskites

    SciTech Connect (OSTI)

    O'Handley, R.C.; Kalonji, G.

    1991-01-01

    The report is divided into six parts, reflecting major thrusts of our work since 1987. The six areas are: molecular orbital theory of high {Tc} superconductivity; rapid solidification processing of oxide superconductors; time dependent magnetic and superconducting properties of these inhomogeneous materials; excess Gd in Gd{sub 1+x}Ba{sub 2-x}Cu{sub 3}O{sub 7-{delta}} perovskites; rapid solidification and directional annealing to achieve high Jc; and Mossbauer studies of T = Fe, Co and Ni site selection in YBa{sub 2}(CuT){sub 3}O{sub 7-{delta}} and GdBa{sub 2}(CuT){sub 3}O{sub 7-{delta}}.

  20. Rapid scanning system for fuel drawers

    DOE Patents [OSTI]

    Caldwell, John T.; Fehlau, Paul E.; France, Stephen W.

    1981-01-01

    A nondestructive method for uniqely distinguishing among and quantifying the mass of individual fuel plates in situ in fuel drawers utilized in nuclear reactors is described. The method is both rapid and passive, eliminating the personnel hazard of the commonly used irradiation techniques which require that the analysis be performed in proximity to an intense neutron source such as a reactor. In the present technique, only normally decaying nuclei are observed. This allows the analysis to be performed anywhere. This feature, combined with rapid scanning of a given fuel drawer (in approximately 30 s), and the computer data analysis allows the processing of large numbers of fuel drawers efficiently in the event of a loss alert.

  1. Rapid scanning system for fuel drawers

    DOE Patents [OSTI]

    Caldwell, J.T.; Fehlau, P.E.; France, S.W.

    A nondestructive method for uniquely distinguishing among and quantifying the mass of individual fuel plates in situ in fuel drawers utilized in nuclear reactors is described. The method is both rapid and passive, eliminating the personnel hazard of the commonly used irradiation techniques which require that the analysis be performed in proximity to an intense neutron source such as a reactor. In the present technique, only normally decaying nuclei are observed. This allows the analysis to be performed anywhere. This feature, combined with rapid scanning of a given fuel drawer (in approximately 30 s), and the computer data analysis allows the processing of large numbers of fuel drawers efficiently in the event of a loss alert.

  2. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    conductivity polyethylene fibers and sheets will be developed to replace metals and ceramics in heat-transfer devices. Project innovations include using massively parallel...

  3. THERMAL PROCESSES GOVERNING HOT-JUPITER RADII

    SciTech Connect (OSTI)

    Spiegel, David S.; Burrows, Adam E-mail: burrows@astro.princeton.edu

    2013-07-20

    There have been many proposed explanations for the larger-than-expected radii of some transiting hot Jupiters, including either stellar or orbital energy deposition deep in the atmosphere or deep in the interior. In this paper, we explore the important influences on hot-Jupiter radius evolution of (1) additional heat sources in the high atmosphere, the deep atmosphere, and deep in the convective interior; (2) consistent cooling of the deep interior through the planetary dayside, nightside, and poles; (3) the degree of heat redistribution to the nightside; and (4) the presence of an upper atmosphere absorber inferred to produce anomalously hot upper atmospheres and inversions in some close-in giant planets. In particular, we compare the radius expansion effects of atmospheric and deep-interior heating at the same power levels and derive the power required to achieve a given radius increase when night-side cooling is incorporated. We find that models that include consistent day/night cooling are more similar to isotropically irradiated models when there is more heat redistributed from the dayside to the nightside. In addition, we consider the efficacy of ohmic heating in the atmosphere and/or convective interior in inflating hot Jupiters. Among our conclusions are that (1) the most highly irradiated planets cannot stably have uB {approx}> 10 km s{sup -1} G over a large fraction of their daysides, where u is the zonal wind speed and B is the dipolar magnetic field strength in the atmosphere, and (2) that ohmic heating cannot in and of itself lead to a runaway in planet radius.

  4. Solar Thermal Process Heat | Open Energy Information

    Open Energy Info (EERE)

    Contact needs updating Image needs updating Reference needed Missing content Broken link Other Additional Comments Cancel Submit Category: Articles with outstanding TODO tasks...

  5. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chain orientation in drawn polymer Chain orientation in amorphous polymer Polymer microstructure 1 S. Shen, A. Henry, J. Tong, R. Zheng, and G. Chen, Nat Nano 5, (4), (2010). ...

  6. Method For Brazing And Thermal Processing

    DOE Patents [OSTI]

    Milewski, John O.; Dave, Vivek R.; Christensen, Dane; Carpenter, II, Robert W.

    2005-07-12

    The present invention includes a method for brazing of two objects or heat treatment of one object. First, object or objects to be treated are selected and initial conditions establishing a relative geometry and material characteristics are determined. Then, a first design of an optical system for directing heat energy onto the object or objects is determined. The initial conditions and first design of the optical system are then input into a optical ray-tracing computer program. The program is then run to produce a representative output of the heat energy input distribution to the object or objects. The geometry of the object or objects, material characteristics, and optical system design are then adjusted until an desired heat input is determined.

  7. Materials Selection Considerations for Thermal Process Equipment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... metals such as copper and silver braze alloys, zinc, and aluminum cause problems. ... At elevated temperatures, cobalt oxide tends to be somewhat lubricious. Cobalt or alloys ...

  8. Methods and systems for rapid prototyping of high density circuits

    DOE Patents [OSTI]

    Palmer, Jeremy A.; Davis, Donald W.; Chavez, Bart D.; Gallegos, Phillip L.; Wicker, Ryan B.; Medina, Francisco R.

    2008-09-02

    A preferred embodiment provides, for example, a system and method of integrating fluid media dispensing technology such as direct-write (DW) technologies with rapid prototyping (RP) technologies such as stereolithography (SL) to provide increased micro-fabrication and micro-stereolithography. A preferred embodiment of the present invention also provides, for example, a system and method for Rapid Prototyping High Density Circuit (RPHDC) manufacturing of solderless connectors and pilot devices with terminal geometries that are compatible with DW mechanisms and reduce contact resistance where the electrical system is encapsulated within structural members and manual electrical connections are eliminated in favor of automated DW traces. A preferred embodiment further provides, for example, a method of rapid prototyping comprising: fabricating a part layer using stereolithography and depositing thermally curable media onto the part layer using a fluid dispensing apparatus.

  9. Thermal energy storage apparatus, controllers and thermal energy storage control methods

    DOE Patents [OSTI]

    Hammerstrom, Donald J.

    2016-05-03

    Thermal energy storage apparatus, controllers and thermal energy storage control methods are described. According to one aspect, a thermal energy storage apparatus controller includes processing circuitry configured to access first information which is indicative of surpluses and deficiencies of electrical energy upon an electrical power system at a plurality of moments in time, access second information which is indicative of temperature of a thermal energy storage medium at a plurality of moments in time, and use the first and second information to control an amount of electrical energy which is utilized by a heating element to heat the thermal energy storage medium at a plurality of moments in time.

  10. Analysis of thermally-degrading, confined HMX

    SciTech Connect (OSTI)

    Hobbs, M.L.; Schmitt, R.G.; Renlund, A.M.

    1996-12-01

    The response of a thermally-degrading, confined HMX pellet is analyzed using a Reactive Elastic-Plastic (REP) constitutive model which is founded on the collapse and growth of internal inclusions resulting from physical and chemical processes such as forced displacement, thermal expansion, and/or decomposition. Axial stress predictions compare adequately to data. Deficiencies in the model and future directions are discussed.

  11. Thermal Imaging Control of Furnaces and Combustors

    SciTech Connect (OSTI)

    David M. Rue; Serguei Zelepouga; Ishwar K. Puri

    2003-02-28

    The object if this project is to demonstrate and bring to commercial readiness a near-infrared thermal imaging control system for high temperature furnaces and combustors. The thermal imaging control system, including hardware, signal processing, and control software, is designed to be rugged, self-calibrating, easy to install, and relatively transparent to the furnace operator.

  12. RAPID/Tools | Open Energy Information

    Open Energy Info (EERE)

    RAPIDTools < RAPID(Redirected from RAPIDResources) Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  13. Connecticut's Health Impact Study Rapidly Increasing Weatherization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Connecticut's Health Impact Study Rapidly Increasing Weatherization Efforts Connecticut's Health Impact Study Rapidly Increasing Weatherization Efforts June 18, 2014 - 10:49am ...

  14. PROJECT PROFILE: Rapid Development of Disruptive Photovoltaic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rapid Development of Disruptive Photovoltaic Technologies PROJECT PROFILE: Rapid Development of Disruptive Photovoltaic Technologies Funding Opportunity: SuNLaMP SunShot ...

  15. RAPID/Hydropower | Open Energy Information

    Open Energy Info (EERE)

    Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History RAPIDHydropower < RAPID Jump to: navigation, search RAPID Regulatory and Permitting Information...

  16. Cedar Rapids Wind Project | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name Cedar Rapids Wind Project Facility Cedar Rapids Sector Wind energy Facility Type Community Wind Location NE Coordinates 41.562199, -98.148048...

  17. RAPID/Roadmap/11 | Open Energy Information

    Open Energy Info (EERE)

    Roadmap11 < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar...

  18. RAPID/Roadmap/6 | Open Energy Information

    Open Energy Info (EERE)

    Roadmap6 < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar...

  19. RAPID/Roadmap/4 | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap4 < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  20. RAPID/Roadmap/19 | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap19 < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  1. RAPID/Roadmap/20 | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap20 < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  2. RAPID/Roadmap/13 | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap13 < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  3. Functionalized Polyacrylamide Monolith for Rapid Bacteria Pathogen...

    Office of Scientific and Technical Information (OSTI)

    for Rapid Bacteria Pathogen Detection in Human Blood. Citation Details In-Document Search Title: Functionalized Polyacrylamide Monolith for Rapid Bacteria Pathogen ...

  4. Template:RAPID-Breadcrumb | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Description Template:RAPID-Breadcrumb is used to generate the top level breadcrumb trail for select RAPID Toolkit pages. Usage To call...

  5. RAPID/Overview | Open Energy Information

    Open Energy Info (EERE)

    RAPIDOverview < RAPID(Redirected from RAPIDAtlas) Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  6. RAPID/Contact | Open Energy Information

    Open Energy Info (EERE)

    Contact < RAPID Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute...

  7. RAPID/Tools | Open Energy Information

    Open Energy Info (EERE)

    Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History RAPIDTools < RAPID Jump to: navigation, search RAPID Regulatory and Permitting Information...

  8. RAPID/Best Practices/ | Open Energy Information

    Open Energy Info (EERE)

    < RAPID | Best Practices Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  9. RAPID/Geothermal/Roadmap | Open Energy Information

    Open Energy Info (EERE)

    Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History RAPIDGeothermalRoadmap < RAPID | Geothermal Jump to: navigation, search RAPID Regulatory...

  10. RAPID/Geothermal | Open Energy Information

    Open Energy Info (EERE)

    Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History RAPIDGeothermal < RAPID(Redirected from RAPIDRoadmapGeo) Jump to: navigation, search RAPID...

  11. RAPID/Geothermal/Roadmap | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalRoadmap < RAPID | Geothermal(Redirected from RAPIDRoadmapGeoSections) Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit...

  12. Thermal Shock-resistant Cement

    SciTech Connect (OSTI)

    Sugama T.; Pyatina, T.; Gill, S.

    2012-02-01

    We studied the effectiveness of sodium silicate-activated Class F fly ash in improving the thermal shock resistance and in extending the onset of hydration of Secar #80 refractory cement. When the dry mix cement, consisting of Secar #80, Class F fly ash, and sodium silicate, came in contact with water, NaOH derived from the dissolution of sodium silicate preferentially reacted with Class F fly ash, rather than the #80, to dissociate silicate anions from Class F fly ash. Then, these dissociated silicate ions delayed significantly the hydration of #80 possessing a rapid setting behavior. We undertook a multiple heating -water cooling quenching-cycle test to evaluate the cement’s resistance to thermal shock. In one cycle, we heated the 200 and #61616;C-autoclaved cement at 500 and #61616;C for 24 hours, and then the heated cement was rapidly immersed in water at 25 and #61616;C. This cycle was repeated five times. The phase composition of the autoclaved #80/Class F fly ash blend cements comprised four crystalline hydration products, boehmite, katoite, hydrogrossular, and hydroxysodalite, responsible for strengthening cement. After a test of 5-cycle heat-water quenching, we observed three crystalline phase-transformations in this autoclaved cement: boehmite and #61614; and #61543;-Al2O3, katoite and #61614; calcite, and hydroxysodalite and #61614; carbonated sodalite. Among those, the hydroxysodalite and #61614; carbonated sodalite transformation not only played a pivotal role in densifying the cementitious structure and in sustaining the original compressive strength developed after autoclaving, but also offered an improved resistance of the #80 cement to thermal shock. In contrast, autoclaved Class G well cement with and without Class F fly ash and quartz flour failed this cycle test, generating multiple cracks in the cement. The major reason for such impairment was the hydration of lime derived from the dehydroxylation of portlandite formed in the autoclaved

  13. Risk D&D Rapid Prototype: Scenario Documentation and Analysis Tool

    SciTech Connect (OSTI)

    Unwin, Stephen D.; Seiple, Timothy E.

    2009-05-28

    Report describes process and methodology associated with a rapid prototype tool for integrating project risk analysis and health & safety risk analysis for decontamination and decommissioning projects.

  14. Roadmap for Process Heating Technology

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Glass * Metal (ferrous and non- ferrous * Resin and plastic * Heat forming * Thermal forming * Paint and organic ... process heating into the Industries of the Future framework. ...

  15. HEATS: Thermal Energy Storage

    SciTech Connect (OSTI)

    2012-01-01

    HEATS Project: The 15 projects that make up ARPA-Es HEATS program, short for High Energy Advanced Thermal Storage, seek to develop revolutionary, cost-effective ways to store thermal energy. HEATS focuses on 3 specific areas: 1) developing high-temperature solar thermal energy storage capable of cost-effectively delivering electricity around the clock and thermal energy storage for nuclear power plants capable of cost-effectively meeting peak demand, 2) creating synthetic fuel efficiently from sunlight by converting sunlight into heat, and 3) using thermal energy storage to improve the driving range of electric vehicles (EVs) and also enable thermal management of internal combustion engine vehicles.

  16. Rapid Prototyping of Patterned Multifunctional Nanostructures

    SciTech Connect (OSTI)

    FAN,HONGYOU; LU,YUNFENG; LOPEZ,GABRIEL P.; BRINKER,C. JEFFREY

    2000-07-18

    The ability to engineer ordered arrays of objects on multiple length scales has potential for applications such as microelectronics, sensors, wave guides, and photonic lattices with tunable band gaps. Since the invention of surfactant templated mesoporous sieves in 1992, great progress has been made in controlling different mesophases in the form of powders, particles, fibers, and films. To date, although there have been several reports of patterned mesostructures, materials prepared have been limited to metal oxides with no specific functionality. For many of the envisioned applications of hierarchical materials in micro-systems, sensors, waveguides, photonics, and electronics, it is necessary to define both form and function on several length scales. In addition, the patterning strategies utilized so far require hours or even days for completion. Such slow processes are inherently difficult to implement in commercial environments. The authors present a series of new methods of producing patterns within seconds. Combining sol-gel chemistry, Evaporation-Induced Self-Assembly (EISA), and rapid prototyping techniques like pen lithography, ink-jet printing, and dip-coating on micro-contact printed substrates, they form hierarchically organized silica structures that exhibit order and function on multiple scales: on the molecular scale, functional organic moieties are positioned on pore surfaces, on the mesoscale, mono-sized pores are organized into 1-, 2-, or 3-dimensional networks, providing size-selective accessibility from the gas or liquid phase, and on the macroscale, 2-dimensional arrays and fluidic or photonic systems may be defined. These rapid patterning techniques establish for the first time a link between computer-aided design and rapid processing of self-assembled nanostructures.

  17. Adaptive Process Controls and Ultrasonics for High Temperature PEM MEA Manufacture

    SciTech Connect (OSTI)

    Walczyk, Daniel F.

    2015-08-26

    The purpose of this 5-year DOE-sponsored project was to address major process bottlenecks associated with fuel cell manufacturing. New technologies were developed to significantly reduce pressing cycle time for high temperature PEM membrane electrode assembly (MEA) through the use of novel, robust ultrasonic (U/S) bonding processes along with low temperature (<100°C) PEM MEAs. In addition, greater manufacturing uniformity and performance was achieved through (a) an investigation into the causes of excessive variation in ultrasonically and thermally bonded MEAs using more diagnostics applied during the entire fabrication and cell build process, and (b) development of rapid, yet simple quality control measurement techniques for use by industry.

  18. Rapid synthesis of beta zeolites

    DOE Patents [OSTI]

    Fan, Wei; Chang, Chun -Chih; Dornath, Paul; Wang, Zhuopeng

    2015-08-18

    The invention provides methods for rapidly synthesizing heteroatom containing zeolites including Sn-Beta, Si-Beta, Ti-Beta, Zr-Beta and Fe-Beta. The methods for synthesizing heteroatom zeolites include using well-crystalline zeolite crystals as seeds and using a fluoride-free, caustic medium in a seeded dry-gel conversion method. The Beta zeolite catalysts made by the methods of the invention catalyze both isomerization and dehydration reactions.

  19. Thermal Energy Storage

    SciTech Connect (OSTI)

    Rutberg, Michael; Hastbacka, Mildred; Cooperman, Alissa; Bouza, Antonio

    2013-06-05

    The article discusses thermal energy storage technologies. This article addresses benefits of TES at both the building site and the electricity generation source. The energy savings and market potential of thermal energy store are reviewed as well.

  20. Robotic thermal battery pellet fabrication

    SciTech Connect (OSTI)

    Kimbler, D.L.; Townsend, A.S.; Walton, R.D.; Jones, C.W.

    1985-03-01

    Thermal battery manufacturing at the General Electric Neutron Devices Department (GEND) is a sequence of operations involving materials processing, component manufacture, and assembly. These operations, for the most part, have been manually performed although some operations have been computer- or fixture-assisted. The high labor intensity and the need for process consistency in these operations made the conversion to a robotic work cell appealing in that it could increase productivity while allowing the reassignment of highly-trained workers to other duties. An Alpha robot (Microbot, Inc.) was coupled with a Hewlett-Packard HP-9816 microcomputer, and custom software was developed to control the thermal battery manufacturing process. The software provided a menu-driven main program with feedback at virtually every step to allow technicians with little or no computer experience to operate the system. Previously, one or two workers were assigned to each of several industrial presses used in the manufacture of thermal batteries. With the introduction of a robotic operator and a microcomputer process control, one worker alone could support two to three presses, thus freeing as many as five workers to be assigned to other labor intensive duties. The production rate of the robotic work cell was approximately the same as the manual method, but the consistency of production and yield showed significant improvement.

  1. thermal energy power conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Solar Thermal Test Facility Nuclear ... Climate & Earth Systems Climate Measurement & Modeling ... Tribal Energy Program Intellectual Property Current EC ...

  2. Thermal neutron detection system

    DOE Patents [OSTI]

    Peurrung, Anthony J. (Richland, WA); Stromswold, David C. (West Richland, WA)

    2000-01-01

    According to the present invention, a system for measuring a thermal neutron emission from a neutron source, has a reflector/moderator proximate the neutron source that reflects and moderates neutrons from the neutron source. The reflector/moderator further directs thermal neutrons toward an unmoderated thermal neutron detector.

  3. Thermal Performance Benchmarking (Presentation)

    SciTech Connect (OSTI)

    Moreno, G.

    2014-11-01

    This project will benchmark the thermal characteristics of automotive power electronics and electric motor thermal management systems. Recent vehicle systems will be benchmarked to establish baseline metrics, evaluate advantages and disadvantages of different thermal management systems, and identify areas of improvement to advance the state-of-the-art.

  4. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    4 Average thermal performance rating of solar thermal collectors by type shipped in 2009 ... Administration, Form EIA-63A, "Annual Solar Thermal Collector Manufacturers Survey." ...

  5. THERMAL ANNEALING OF ZNO FILMS USING HIGH-DENSITY PLASMA ARC LAMPS

    SciTech Connect (OSTI)

    Sabau, Adrian S; Dinwiddie, Ralph Barton; Xu, Jun; Angelini, Joseph Attilio; Harper, David C

    2011-01-01

    Nanostructured materials are rarely synthesized with appropriate phase and/or morphology. In this study, critical additional of as-synthesized nanostructured materials, such as annealing and/or activation of dopants, are addressed using infrared plasma arc lamps (PAL) over areas as large as 1,000 cm2. The broad spectral range of the PAL and the spectral variation of light absorption in nanostructured materials make the selection of processing parameters extremely difficult, posing a major technological barrier. In this study, the measurement of the surface temperature using various techniques for ZnO films on crystalline silicon wafers is discussed. An energy transport model for the simulation of rapid thermal processing using PAL is presented. The experimental and computational results show that the surface temperature cannot be measured directly and that computer simulation results are an effective tool for obtaining accurate data on processing temperatures.

  6. Thermal Effusivity Tomography from Pulsed Thermal Imaging

    Energy Science and Technology Software Center (OSTI)

    2006-12-01

    The software program generates 3D volume distribution of thermal effusivity within a test material from one-sided pulsed thermal imaging data. Thsi is the first software capable of accurate, fast and automated thermal tomographic imaging of inhomogeneous materials to produce 3D images similar to those obtained from 3D X-ray CT (all previous thermal-imaging software can only produce 2D results). Because thermal effusivity is an intrisic material property that is related to material constituent, density, conductivity, etc.,more » quantitative imaging of effusivity allowed direct visualization of material's internal constituent/structure and damage distributions, thereby potentially leading to quantitative prediction of other material properties such as strength. I can be therefre be used for 3D imaging of material structure in fundamental material studies, nondestructive characterization of defects/flaws in structural engineering components, health monitoring of material damage and degradation during service, and medical imaging and diagnostics. This technology is one-sided, non contact and sensitive to material's thermal property and discontinuity. One major advantage of this tomographic technology over x-ray CT and ultrasounds is its natural efficiency for 3D imaging of the volume under a large surface area. This software is implemented with a method for thermal computed tomography of thermal effusivity from one-sided pulsed thermal imaging (or thermography) data. The method is based on several solutions of the governing heat transfer equation under pulsed thermography test condition. In particular, it consists of three components. 1) It utilized the thermal effusivity as the imaging parameter to construct the 3D image. 2) It established a relationship between the space (depth) and the time, because thermography data are in the time domain. 3) It incorporated a deconvolution algorithm to solve the depth porfile of the material thermal effusivity from the measured

  7. Effects of rapid thermal annealing on properties of Ga-doped Mg{sub x}Zn{sub 1−x}O films and Ga-doped Mg{sub x}Zn{sub 1−x}O/AlGaN heterojunction diodes

    SciTech Connect (OSTI)

    Hsueh, Kuang-Po E-mail: kphsueh@mail.vnu.edu.tw; Cheng, Po-Wei

    2014-08-14

    This study investigated the thermal annealing effects of Ga-doped Mg{sub x}Zn{sub 1−x}O (GMZO) films and GMZO/AlGaN heterojunction diodes. GMZO films were deposited using a radio-frequency magnetron sputtering system with a 4-in. ZnO/MgO/Ga{sub 2}O{sub 3} target. In addition, the Hall results, X-ray diffraction, transparent performance, and X-ray photoelectron spectroscopy (XPS) spectra were measured. The as-grown GMZO film deposited in this study exhibited a high transparency with transmittances over 95% in the visible region (360–700 nm) and a sharp absorption edge in the UV region (275–350 nm). The phenomenon of phase separation in the GMZO films was investigated based on the XPS spectra, revealing that an increase in the O-Zn signal accompanied a decline in the O-Ga signal after the thermal annealing. Moreover, the current-voltage (I-V) characteristics of the GMZO/AlGaN n-p junction diodes were examined at different annealing temperatures. The light emission derived from the forward-biased junction and near-ultraviolet (near-UV) light emission was evident at all p-n junctions. The n-GMZO/p-AlGaN diode annealed at 800 °C exhibited a brighter near-UV emission compared with the other diodes. In addition, the spectrum of diode annealed at 800 °C exhibited a broad peak at 474 nm (2.62 eV) and a tail of the emission spectrum extending to 850 nm. Based on these findings, the GMZO films are suitable for forming transparent contact layers in optoelectronic devices, and the n-GMZO/p-AlGaN junction diode is a feasible alternative in near-UV light emission devices.

  8. Thermal Effusivity Tomography from Pulsed Thermal Imaging

    Energy Science and Technology Software Center (OSTI)

    2008-11-05

    The software program generates 3D volume distribution of thermal effusivity within a test material from one—sided pulsed thermal imaging data. Thsi is the first software capable of accurate, fast and automated thermal tomographic imaging of inhomogeneoirs materials to produce 3D images similar to those obtained from 3D X—ray CT (all previous thepnal—imaging software can only produce 20 results) . Because thermal effusivity is an Intrisic material property that is related to material constituent, density, conductivity,more » etc., quantitative imaging of eftusivity allowed direct visualization of material’s internal constituent/structure and damage distributions, thereby potentially leading to quantitative prediction of other material properties such as strength. I can be therefre be used for 3D imaging of material structure in fundamental material studies, nondestructive characterization of defects/flaws in structural engineering components, health monitoring of material damage and degradation during service, and medical imaging and diagnostics. This technology is one—sided, non contact and sensitive to material’s thermal property and discontinuity. One major advantage of this tomographic technology over x-ray CT and ultrasounds is its natural efficiency for 3D imaging of the volume under a large surface area. This software is implemented with a method for thermal computed tomography of thermal effusivity from one—sided pulsed thermal imaging (or thermography) data. The method is based on several solutions of the governing heat transfer equation under pulsed thermography test condition. In particular, it consists of three components. 1) It utilized the thermal effusivity as the imaging parameter to construct the 3D image. 2) It established a relationship between the space (depth) and the time, because thermography data are in the time domain. 3) It incorporated a deconvolution algorithm to solve the depth porfile of the material thermal effusivity from the

  9. Rapid starting methanol reactor system

    DOE Patents [OSTI]

    Chludzinski, Paul J.; Dantowitz, Philip; McElroy, James F.

    1984-01-01

    The invention relates to a methanol-to-hydrogen cracking reactor for use with a fuel cell vehicular power plant. The system is particularly designed for rapid start-up of the catalytic methanol cracking reactor after an extended shut-down period, i.e., after the vehicular fuel cell power plant has been inoperative overnight. Rapid system start-up is accomplished by a combination of direct and indirect heating of the cracking catalyst. Initially, liquid methanol is burned with a stoichiometric or slightly lean air mixture in the combustion chamber of the reactor assembly. The hot combustion gas travels down a flue gas chamber in heat exchange relationship with the catalytic cracking chamber transferring heat across the catalyst chamber wall to heat the catalyst indirectly. The combustion gas is then diverted back through the catalyst bed to heat the catalyst pellets directly. When the cracking reactor temperature reaches operating temperature, methanol combustion is stopped and a hot gas valve is switched to route the flue gas overboard, with methanol being fed directly to the catalytic cracking reactor. Thereafter, the burner operates on excess hydrogen from the fuel cells.

  10. Ceramic Processing

    SciTech Connect (OSTI)

    EWSUK,KEVIN G.

    1999-11-24

    Ceramics represent a unique class of materials that are distinguished from common metals and plastics by their: (1) high hardness, stiffness, and good wear properties (i.e., abrasion resistance); (2) ability to withstand high temperatures (i.e., refractoriness); (3) chemical durability; and (4) electrical properties that allow them to be electrical insulators, semiconductors, or ionic conductors. Ceramics can be broken down into two general categories, traditional and advanced ceramics. Traditional ceramics include common household products such as clay pots, tiles, pipe, and bricks, porcelain china, sinks, and electrical insulators, and thermally insulating refractory bricks for ovens and fireplaces. Advanced ceramics, also referred to as ''high-tech'' ceramics, include products such as spark plug bodies, piston rings, catalyst supports, and water pump seals for automobiles, thermally insulating tiles for the space shuttle, sodium vapor lamp tubes in streetlights, and the capacitors, resistors, transducers, and varistors in the solid-state electronics we use daily. The major differences between traditional and advanced ceramics are in the processing tolerances and cost. Traditional ceramics are manufactured with inexpensive raw materials, are relatively tolerant of minor process deviations, and are relatively inexpensive. Advanced ceramics are typically made with more refined raw materials and processing to optimize a given property or combination of properties (e.g., mechanical, electrical, dielectric, optical, thermal, physical, and/or magnetic) for a given application. Advanced ceramics generally have improved performance and reliability over traditional ceramics, but are typically more expensive. Additionally, advanced ceramics are typically more sensitive to the chemical and physical defects present in the starting raw materials, or those that are introduced during manufacturing.

  11. World NGL markets continue rapid expansion

    SciTech Connect (OSTI)

    Otto, K.; Gist, R.; Whitley, C.; Haun, R.

    1998-06-08

    The international LPG industry has expanded rapidly during the 1990s and undergone significant changes. LPG consumption has expanded at nearly twice the rate of world petroleum demand. In particular, LPG use in residential and commercial markets has more than doubled in many developing countries. Markets for LPG and other petroleum products have been opened in many countries, accelerating demand growth and creating investment opportunities in all downstream segments. This has led to an overall strengthening of global LPG pricing and the development of many new export gas-processing projects. The paper discusses world LPG demand in residential and commercial markets and in petrochemicals, world LPG supply, regional increases, international trade, the US situation in natural gas, NGL supply, and NGL demand.

  12. Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux

    DOE Patents [OSTI]

    Bowman, Charles D.

    1992-01-01

    Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux. High thermal neutron fluxes generated from the action of a high power proton accelerator on a spallation target allows the efficient burn-up of higher actinide nuclear waste by a two-step process. Additionally, rapid burn-up of fission product waste for nuclides having small thermal neutron cross sections, and the practicality of small material inventories while achieving significant throughput derive from employment of such high fluxes. Several nuclear technology problems are addressed including 1. nuclear energy production without a waste stream requiring storage on a geological timescale, 2. the burn-up of defense and commercial nuclear waste, and 3. the production of defense nuclear material. The apparatus includes an accelerator, a target for neutron production surrounded by a blanket region for transmutation, a turbine for electric power production, and a chemical processing facility. In all applications, the accelerator power may be generated internally from fission and the waste produced thereby is transmuted internally so that waste management might not be required beyond the human lifespan.

  13. Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux

    DOE Patents [OSTI]

    Bowman, C.D.

    1992-11-03

    Apparatus for nuclear transmutation and power production using an intense accelerator-generated thermal neutron flux. High thermal neutron fluxes generated from the action of a high power proton accelerator on a spallation target allows the efficient burn-up of higher actinide nuclear waste by a two-step process. Additionally, rapid burn-up of fission product waste for nuclides having small thermal neutron cross sections, and the practicality of small material inventories while achieving significant throughput derive from employment of such high fluxes. Several nuclear technology problems are addressed including 1. nuclear energy production without a waste stream requiring storage on a geological timescale, 2. the burn-up of defense and commercial nuclear waste, and 3. the production of defense nuclear material. The apparatus includes an accelerator, a target for neutron production surrounded by a blanket region for transmutation, a turbine for electric power production, and a chemical processing facility. In all applications, the accelerator power may be generated internally from fission and the waste produced thereby is transmuted internally so that waste management might not be required beyond the human lifespan.

  14. Rapid prototype extruded conductive pathways

    DOE Patents [OSTI]

    Bobbitt, III, John T.

    2016-06-21

    A process of producing electrically conductive pathways within additively manufactured parts and similar parts made by plastic extrusion nozzles. The process allows for a three-dimensional part having both conductive and non-conductive portions and allows for such parts to be manufactured in a single production step.

  15. Thermal conductivity measurements of Summit polycrystalline silicon.

    SciTech Connect (OSTI)

    Clemens, Rebecca; Kuppers, Jaron D.; Phinney, Leslie Mary

    2006-11-01

    A capability for measuring the thermal conductivity of microelectromechanical systems (MEMS) materials using a steady state resistance technique was developed and used to measure the thermal conductivities of SUMMiT{trademark} V layers. Thermal conductivities were measured over two temperature ranges: 100K to 350K and 293K to 575K in order to generate two data sets. The steady state resistance technique uses surface micromachined bridge structures fabricated using the standard SUMMiT fabrication process. Electrical resistance and resistivity data are reported for poly1-poly2 laminate, poly2, poly3, and poly4 polysilicon structural layers in the SUMMiT process from 83K to 575K. Thermal conductivity measurements for these polysilicon layers demonstrate for the first time that the thermal conductivity is a function of the particular SUMMiT layer. Also, the poly2 layer has a different variation in thermal conductivity as the temperature is decreased than the poly1-poly2 laminate, poly3, and poly4 layers. As the temperature increases above room temperature, the difference in thermal conductivity between the layers decreases.

  16. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A.; Campbell, Christian X.; Subramanian, Ramesh

    2009-06-02

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  17. RAPID/Outreach | Open Energy Information

    Open Energy Info (EERE)

    as an overview of the RAPID Toolkit and its features. File:RAPID Roadmap Overview.pptx Reading the Regulatory Roadmap This "Getting Started" presentation walks through how to read...

  18. Solid state thermal rectifier

    DOE Patents [OSTI]

    None

    2016-07-05

    Thermal rectifiers using linear nanostructures as core thermal conductors have been fabricated. A high mass density material is added preferentially to one end of the nanostructures to produce an axially non-uniform mass distribution. The resulting nanoscale system conducts heat asymmetrically with greatest heat flow in the direction of decreasing mass density. Thermal rectification has been demonstrated for linear nanostructures that are electrical insulators, such as boron nitride nanotubes, and for nanostructures that are conductive, such as carbon nanotubes.

  19. Water Based Process for Fabricating Thermoelectric Materials...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Thermal Solar Thermal Find More Like This Return to Search Water Based Process for ... Berkeley Lab scientists Rachel Segalman, Jeffrey Urban and Kevin See have invented a water ...

  20. Sandia Thermal Program

    Energy Science and Technology Software Center (OSTI)

    2005-11-23

    Thermal analysis in 1-D planar, cylindrical and spherical geometries using control volume finite element spatial discretization with 1st and 2nd order implicit time integrators.

  1. Scattering Solar Thermal Concentrators

    Office of Environmental Management (EM)

    sunshot DOEGO-102012-3669 * September 2012 MOTIVATION All thermal concentrating solar power (CSP) systems use solar tracking, which involves moving large mirror surfaces...

  2. Battery Thermal Characterization

    SciTech Connect (OSTI)

    Saxon, Aron; Powell, Mitchell; Shi, Ying

    2015-06-09

    This presentation provides an update of NREL's battery thermal characterization efforts for the 2015 U.S. Department of Energy Annual Merit Reviews.

  3. Ambient temperature thermal battery

    SciTech Connect (OSTI)

    Fletcher, A. N.; Bliss, D. E.; McManis III

    1985-11-26

    An ambient temperature thermal battery having two relatively high temperature melting electrolytes which form a low melting temperature electrolyte upon activation.

  4. Method and apparatus for thermal swing adsorption and thermally-enhanced pressure swing adsorption

    DOE Patents [OSTI]

    Wegeng, Robert S.; Rassat, Scot D.; TeGrotenhuis, Ward E.; Drost, Kevin; Vishwanathan, Vilayanur V.

    2004-06-08

    The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. In another aspect, the apparatus or methods utilize heat exchange channels of varying lengths that have volumes controlled to provide equal heat fluxes. Methods of fuel cell startup are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.

  5. Apparatus for thermal swing adsorption and thermally-enhanced pressure swing adsorption

    DOE Patents [OSTI]

    Wegeng, Robert S.; Rassat, Scot D.; Stenkamp, Victoria S.; TeGrotenhuis, Ward E.; Matson, Dean W.; Drost, M. Kevin; Viswanathan, Vilayanur V.

    2005-12-13

    The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.

  6. Method for thermal swing adsorption and thermally-enhanced pressure swing adsorption

    DOE Patents [OSTI]

    Wegeng, Robert S.; Rassat, Scot D.; Stenkamp, Victoria S.; TeGrotenhuis, Ward E.; Matson, Dean W.; Drost, M. Kevin; Viswanathan, Vilayanur V.

    2003-10-07

    The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.

  7. Variable pressure thermal insulating jacket

    DOE Patents [OSTI]

    Nelson, P.A.; Malecha, R.F.; Chilenskas, A.A.

    1994-09-20

    A device for controlled insulation of a thermal device is disclosed. The device includes a thermal jacket with a closed volume able to be evacuated to form an insulating jacket around the thermal source. A getter material is in communication with the closed volume of the thermal jacket. The getter material can absorb and desorb a control gas to control gas pressure in the volume of the thermal jacket to control thermal conductivity in the thermal jacket. 10 figs.

  8. Variable pressure thermal insulating jacket

    DOE Patents [OSTI]

    Nelson, Paul A. (Wheaton, IL); Malecha, Richard F. (Naperville, IL); Chilenskas, Albert A. (Chicago, IL)

    1994-01-01

    A device for controlled insulation of a thermal device. The device includes a thermal jacket with a closed volume able to be evacuated to form an insulating jacket around the thermal source. A getter material is in communcation with the closed volume of the thermal jacket. The getter material can absorb and desorb a control gas to control gas pressure in the volume of the thermal jacket to control thermal conductivity in the thermal jacket.

  9. Laser Assisted Crystallization of Ferromagnetic Amorphous Ribbons: A Multimodal Characterization and Thermal Model Study

    SciTech Connect (OSTI)

    Katakam, Shravana K.; Devaraj, Arun; Bowden, Mark E.; Santhanakrishnan, S.; Smith, Casey; Ramanujan, Raju; Thevuthasan, Suntharampillai; Banerjee, Rajarshi; Dahotre, Narendra B.

    2013-11-14

    This paper focuses on laser-based de-vitrification of amorphous soft magnetic Fe-Si-B ribbons and its consequent influence on the magnetic properties. Laser processing resulted in a finer scale of crystallites due to rapid heating and cooling during laser annealing compared to conventional furnace annealing process. A significant increase in saturation magnetization is observed for laser-annealed ribbons compared to both as-received and furnace annealed samples coupled with an increase in coercivity compared to as received sample. The combined effect of thermal histories and stresses developed during laser annealing results in the formation of nano-crystalline phase along the laser track. The phase evolution is traced with the aid of micro-XRD and TEM analysis. The solute partitioning and compositional variation within the phases are obtained by Local Electrode Atom probe analysis. The evolution of microstructure is rationalized using a Finite Element based heat transfer multi-physics model.

  10. W-320 Project thermal modeling

    SciTech Connect (OSTI)

    Sathyanarayana, K., Fluor Daniel Hanford

    1997-03-18

    This report summarizes the results of thermal analysis performed to provide a technical basis in support of Project W-320 to retrieve by sluicing the sludge in Tank 241-C-106 and to transfer into Tank 241-AY-102. Prior theraml evaluations in support of Project W-320 safety analysis assumed the availability of 2000 to 3000 CFM, as provided by Tank Farm Operations, for tank floor cooling channels from the secondary ventilation system. As this flow availability has no technical basis, a detailed Tank 241-AY-102 secondary ventilation and floor coating channel flow model was developed and analysis was performed. The results of the analysis show that only about 150 cfm flow is in floor cooLing channels. Tank 241-AY-102 thermal evaluation was performed to determine the necessary cooling flow for floor cooling channels using W-030 primary ventilation system for different quantities of Tank 241-C-106 sludge transfer into Tank 241-AY-102. These sludge transfers meet different options for the project along with minimum required modification of the ventilation system. Also the results of analysis for the amount of sludge transfer using the current system is presented. The effect of sludge fluffing factor, heat generation rate and its distribution between supernatant and sludge in Tank 241-AY-102 on the amount of sludge transfer from Tank 241-C-106 were evaluated and the results are discussed. Also transient thermal analysis was performed to estimate the time to reach the steady state. For a 2 feet sludge transfer, about 3 months time will be requirad to reach steady state. Therefore, for the purpose of process control, a detailed transient thermal analysis using GOTH Computer Code will be required to determine transient response of the sludge in Tank 241-AY-102. Process control considerations are also discussed to eliminate the potential for a steam bump during retrieval and storage in Tanks 241-C-106 and 241-AY-102 respectively.

  11. Thermal protection apparatus

    DOE Patents [OSTI]

    Bennett, Gloria A.; Elder, Michael G.; Kemme, Joseph E.

    1985-01-01

    An apparatus which thermally protects sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components to a heat sink such as ice.

  12. Thermally actuated wedge block

    DOE Patents [OSTI]

    Queen, Jr., Charles C.

    1980-01-01

    This invention relates to an automatically-operating wedge block for maintaining intimate structural contact over wide temperature ranges, including cryogenic use. The wedging action depends on the relative thermal expansion of two materials having very different coefficients of thermal expansion. The wedge block expands in thickness when cooled to cryogenic temperatures and contracts in thickness when returned to room temperature.

  13. Thermal protection apparatus

    DOE Patents [OSTI]

    Bennett, G.A.; Elder, M.G.; Kemme, J.E.

    1984-03-20

    The disclosure is directed to an apparatus for thermally protecting sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components such as electronics to a heat sink such as ice.

  14. An Overview of Facilities and Capabilities to Support the Development of Nuclear Thermal Propulsion

    SciTech Connect (OSTI)

    James Werner; Sam Bhattacharyya; Mike Houts

    2011-02-01

    Abstract. The future of American space exploration depends on the ability to rapidly and economically access locations of interest throughout the solar system. There is a large body of work (both in the US and the Former Soviet Union) that show that Nuclear Thermal Propulsion (NTP) is the most technically mature, advanced propulsion system that can enable this rapid and economical access by its ability to provide a step increase above what is a feasible using a traditional chemical rocket system. For an NTP system to be deployed, the earlier measurements and recent predictions of the performance of the fuel and the reactor system need to be confirmed experimentally prior to launch. Major fuel and reactor system issues to be addressed include fuel performance at temperature, hydrogen compatibility, fission product retention, and restart capability. The prime issue to be addressed for reactor system performance testing involves finding an affordable and environmentally acceptable method to test a range of engine sizes using a combination of nuclear and non-nuclear test facilities. This paper provides an assessment of some of the capabilities and facilities that are available or will be needed to develop and test the nuclear fuel, and reactor components. It will also address briefly options to take advantage of the greatly improvement in computation/simulation and materials processing capabilities that would contribute to making the development of an NTP system more affordable. Keywords: Nuclear Thermal Propulsion (NTP), Fuel fabrication, nuclear testing, test facilities.

  15. Tunable thermal link

    DOE Patents [OSTI]

    Chang, Chih-Wei; Majumdar, Arunava; Zettl, Alexander K.

    2014-07-15

    Disclosed is a device whereby the thermal conductance of a multiwalled nanostructure such as a multiwalled carbon nanotube (MWCNT) can be controllably and reversibly tuned by sliding one or more outer shells with respect to the inner core. As one example, the thermal conductance of an MWCNT dropped to 15% of the original value after extending the length of the MWCNT by 190 nm. The thermal conductivity returned when the tube was contracted. The device may comprise numbers of multiwalled nanotubes or other graphitic layers connected to a heat source and a heat drain and various means for tuning the overall thermal conductance for applications in structure heat management, heat flow in nanoscale or microscale devices and thermal logic devices.

  16. Thermal treatment wall

    DOE Patents [OSTI]

    Aines, Roger D.; Newmark, Robin L.; Knauss, Kevin G.

    2000-01-01

    A thermal treatment wall emplaced to perform in-situ destruction of contaminants in groundwater. Thermal destruction of specific contaminants occurs by hydrous pyrolysis/oxidation at temperatures achievable by existing thermal remediation techniques (electrical heating or steam injection) in the presence of oxygen or soil mineral oxidants, such as MnO.sub.2. The thermal treatment wall can be installed in a variety of configurations depending on the specific objectives, and can be used for groundwater cleanup, wherein in-situ destruction of contaminants is carried out rather than extracting contaminated fluids to the surface, where they are to be cleaned. In addition, the thermal treatment wall can be used for both plume interdiction and near-wellhead in-situ groundwater treatment. Thus, this technique can be utilized for a variety of groundwater contamination problems.

  17. Solar thermal aircraft

    DOE Patents [OSTI]

    Bennett, Charles L.

    2007-09-18

    A solar thermal powered aircraft powered by heat energy from the sun. A heat engine, such as a Stirling engine, is carried by the aircraft body for producing power for a propulsion mechanism, such as a propeller. The heat engine has a thermal battery in thermal contact with it so that heat is supplied from the thermal battery. A solar concentrator, such as reflective parabolic trough, is movably connected to an optically transparent section of the aircraft body for receiving and concentrating solar energy from within the aircraft. Concentrated solar energy is collected by a heat collection and transport conduit, and heat transported to the thermal battery. A solar tracker includes a heliostat for determining optimal alignment with the sun, and a drive motor actuating the solar concentrator into optimal alignment with the sun based on a determination by the heliostat.

  18. Thermal conductivity changes upon neutron transmutation of {sup 10}B doped diamond

    SciTech Connect (OSTI)

    Jagannadham, K., E-mail: jag-kasichainula@ncsu.edu [Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Verghese, K. [Nuclear Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Butler, J. E. [Code 6174, Naval research Laboratory, Washington, District of Columbia 20375 (United States)

    2014-08-28

    {sup 10}B doped p-type diamond samples were subjected to neutron transmutation reaction using thermal neutron flux of 0.9 10{sup 13} cm{sup ?2} s{sup ?1} and fast neutron flux of 0.09 10{sup 13} cm{sup ?2} s{sup ?1}. Another sample of epilayer grown on type IIa (110) single crystal diamond substrate was subjected to equal thermal and fast neutron flux of 10{sup 14}?cm{sup ?2} s{sup ?1}. The defects in the diamond samples were previously characterized by different methods. In the present work, thermal conductivity of these diamond samples was determined at room temperature by transient thermoreflectance method. The thermal conductivity change in the samples as a function of neutron fluence is explained by the phonon scattering from the point defects and disordered regions. The thermal conductivity of the diamond samples decreased more rapidly initially and less rapidly for larger neutron fluence. In addition, the thermal conductivity in type IIb diamond decreased less rapidly with thermal neutron fluence compared to the decrease in type IIa diamond subjected to fast neutron fluence. It is concluded that the rate of production of defects during transmutation reaction is slower when thermal neutrons are used. The thermal conductivity of epilayer of diamond subjected to high thermal and fast neutron fluence is associated with the covalent carbon network in the composite structure consisting of disordered carbon and sp{sup 2} bonded nanocrystalline regions.

  19. Rapid Syndrome Validation Project (RSVP)

    Energy Science and Technology Software Center (OSTI)

    2004-03-26

    RSVP facilitates the two-way communication between physicians (who are the “sensors” for disease in a community) and public health officials (who are the true “experts” in determining whether or not disease outbreaks are taking place in community). Currently, there is no software product that enables real-time on line reporting to local public health officials, nor timely feedback to clinicians taking care of ill patients. RSVP takes into consideration the cultural differences in the practice ofmore » medicine across the US and internationally, and provides for automated alerting of public health officials in the setting of a potentially serious disease outbreak. In addition, clinicians’ parficipation is immediately rewarded by providing information that is meaningful for the management of their patients. We envision the addition to RSVP of automated statistical analysis of data (currentty being done on a case-by-case basis by hand), including SNL technology based on neural network analysis. Integration of other SNL technology into RSVP will provide added-value, and will dramatically assist public health officials in their quest to identify disease outbreaks as early as possible in an epidemic (even before the actual level of known cases exceeds historical background) based on other parameters such as rapidity of spread of symptoms in a population. In addition, we are developing a parallel system of syndrome surveillance in animals (called "RSVP-A"), in collaboration with Kansas State University. Data from animal disease outbreaks will also be made available to physicians caring for human patients as zoonotic disease may be important in human epidemics.« less

  20. Thermally-related safety issues associated with thermal batteries.

    SciTech Connect (OSTI)

    Guidotti, Ronald Armand

    2006-06-01

    Thermal batteries can experience thermal runaway under certain usage conditions. This can lead to safety issues for personnel and cause damage to associated test equipment if the battery thermally self destructs. This report discusses a number of thermal and design related issues that can lead to catastrophic destruction of thermal batteries under certain conditions. Contributing factors are identified and mitigating actions are presented to minimize or prevent undesirable thermal runaway.

  1. Method for rapidly producing microporous and mesoporous materials

    DOE Patents [OSTI]

    Coronado, P.R.; Poco, J.F.; Hrubesh, L.W.; Hopper, R.W.

    1997-11-11

    An improved, rapid process is provided for making microporous and mesoporous materials, including aerogels and pre-ceramics. A gel or gel precursor is confined in a sealed vessel to prevent structural expansion of the gel during the heating process. This confinement allows the gelation and drying processes to be greatly accelerated, and significantly reduces the time required to produce a dried aerogel compared to conventional methods. Drying may be performed either by subcritical drying with a pressurized fluid to expel the liquid from the gel pores or by supercritical drying. The rates of heating and decompression are significantly higher than for conventional methods. 3 figs.

  2. Method for rapidly producing microporous and mesoporous materials

    DOE Patents [OSTI]

    Coronado, Paul R.; Poco, John F.; Hrubesh, Lawrence W.; Hopper, Robert W.

    1997-01-01

    An improved, rapid process is provided for making microporous and mesoporous materials, including aerogels and pre-ceramics. A gel or gel precursor is confined in a sealed vessel to prevent structural expansion of the gel during the heating process. This confinement allows the gelation and drying processes to be greatly accelerated, and significantly reduces the time required to produce a dried aerogel compared to conventional methods. Drying may be performed either by subcritical drying with a pressurized fluid to expel the liquid from the gel pores or by supercritical drying. The rates of heating and decompression are significantly higher than for conventional methods.

  3. Rapid cooling and structure of neutron stars

    SciTech Connect (OSTI)

    Van Riper, K.A.; Lattimer, J.M.

    1992-07-01

    This report discusses the following topics on neutron stars: direct URCA neutrino emission; thermal evolution models; analytic model for diffusion through the crust; and core superfluidity. (LSP).

  4. Rapid cooling and structure of neutron stars

    SciTech Connect (OSTI)

    Van Riper, K.A. ); Lattimer, J.M. . Dept. of Earth and Space Sciences)

    1992-01-01

    This report discusses the following topics on neutron stars: direct URCA neutrino emission; thermal evolution models; analytic model for diffusion through the crust; and core superfluidity. (LSP).

  5. Flashback: Rapid scanning for radiological threats

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flashback: Rapid scanning for radiological threats Flashback: Rapid scanning for radiological threats The ability to identify distinct material density enables the Multi-Mode Passive Detection System (MMPDS)to quickly detect unshielded to heavily shielded nuclear threats, as well as gamma rays, with near-zero false alarms. November 1, 2015 Decision Science Decision Science Decision Sciences' Multi-Mode Passive Detection System: Rapid scanning forradiological threats Click on headline to go to

  6. Project Profile: High-Efficiency Thermal Energy Storage System for CSP |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy High-Efficiency Thermal Energy Storage System for CSP Project Profile: High-Efficiency Thermal Energy Storage System for CSP -- This project is inactive -- ANL logo Argonne National Laboratory and project partner Ohio Aerospace Institute, under the National Laboratory R&D competitive funding opportunity, will design, develop, and test a prototype high-temperature and high-efficiency thermal energy storage (TES) system with rapid charging and discharging times. By

  7. Multilayer thermal barrier coating systems

    DOE Patents [OSTI]

    Vance, Steven J.; Goedjen, John G.; Sabol, Stephen M.; Sloan, Kelly M.

    2000-01-01

    The present invention generally describes multilayer thermal barrier coating systems and methods of making the multilayer thermal barrier coating systems. The thermal barrier coating systems comprise a first ceramic layer, a second ceramic layer, a thermally grown oxide layer, a metallic bond coating layer and a substrate. The thermal barrier coating systems have improved high temperature thermal and chemical stability for use in gas turbine applications.

  8. Category:RAPID Toolkit | Open Energy Information

    Open Energy Info (EERE)

    and Permitting RAPIDBulkTransmission RAPIDBulkTransmissionAbout RAPIDBulkTransmissionAir Quality RAPIDBulkTransmissionAlaska RAPIDBulkTransmissionArizona RAPID...

  9. RAPID/Roadmap/Geo | Open Energy Information

    Open Energy Info (EERE)

    Geo < RAPID | Roadmap Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Regulatory Roadmap GRR-logo.png Map of GRR states.jpg Since April 2012, the...

  10. RAPID/Bulk Transmission | Open Energy Information

    Open Energy Info (EERE)

    Page Edit History RAPIDBulk Transmission < RAPID(Redirected from RAPIDOverviewBulkTransmission) Redirect page Jump to: navigation, search REDIRECT RAPIDBulkTransmission...

  11. Thermal insulations using vacuum panels

    DOE Patents [OSTI]

    Glicksman, Leon R.; Burke, Melissa S.

    1991-07-16

    Thermal insulation vacuum panels are formed of an inner core of compressed low thermal conductivity powders enclosed by a ceramic/glass envelope evaluated to a low pressure.

  12. National Solar Thermal Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Solar Thermal Test Facility HomeNational Solar Thermal Test Facility Permalink Pratt Whitney Rocketdyne Testing Concentrating Solar Power, EC, Energy, Facilities, ...

  13. National Solar Thermal Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SunShot Grand Challenge: Regional Test Centers National Solar Thermal Test Facility HomeTag:National Solar Thermal Test Facility Permalink Air Force Research Laboratory Testing ...

  14. National Solar Thermal Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Solar Thermal Test Facility HomeNational Solar Thermal Test Facility Permalink High-Efficiency Solar Thermochemical Reactor for Hydrogen Production Center for ...

  15. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2 Solar thermal collector shipments by type, quantity, revenue, and average price, 2008 ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  16. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    1 Distribution of domestic solar thermal collector shipments (thousand square feet) 2008 ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  17. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Annual shipments of solar thermal collectors by type, 2000 - 2009 (thousand square feet) ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  18. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Shipments of solar thermal collectors ranked by origin and destination, 2009 Origin Top ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  19. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Annual shipments of solar thermal collectors by source, 2000 - 2009 Imports Domestically ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  20. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Annual shipments of solar thermal collectors by disposition, 2000 - 2009 (thousand square ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  1. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    7 Percent of solar thermal collector shipments by the 10 largest companies, 2000 - 2009 ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  2. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    5 Shipments of complete solar thermal collector systems, 2008 and 2009 Shipment ... Administration, Form EIA-63A, "Annual Solar Thermal Collector Manufacturers Survey."

  3. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    8 Import shipments of solar thermal collectors by country, 2008 and 2009 (square feet) ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  4. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    7 Import shipments of solar thermal collectors by type, 2000 - 2009 (thousand square feet) ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal ...

  5. Tailoring the magnetic properties of new Fe-Ni-Co-Al-(Ta,Nb)-B superelastic rapidly quenched microwires

    SciTech Connect (OSTI)

    Borza, F. Lupu, N.; Dobrea, V.; Chiriac, H.

    2015-05-07

    Ferromagnetic Fe-Ni-Co-Al-(Ta,Nb)-B microwires with diameters from 170 μm to 50 μm, which possess both superelastic and good magnetic properties, have been prepared by rapid quenching from the melt using the in rotating water spinning technique followed by cold-drawing and ageing. The cold-drawing and annealing processes lead to the initialization of premartensitic phases as confirmed by the X-ray diffraction and scanning transmission electron microscopic investigations, more significantly in the 50 μm cold-drawn microwires. An increase in the coercive field and in the saturation magnetization has been obtained by annealing, more importantly in the case of Nb-containing alloy. Ageing by thermal or current annealing led to the initialization of the superelastic effect. High values of strain of up to 1.8%, very good repeatability under successive loading, and values of superelastic effect of up to 1.2% have been achieved. The structural analysis coupled with the stress-strain data suggests that these materials annealed at 800 °C have superelastic potential at reduced ageing times. The magnetic behavior was found to be easily tailored through both thermal and thermomagnetic treatments with changes in the magnetic parameters which can be contactless detected. The results are important for future applications where both mechanical and magnetic properties matter, i.e., sensing/actuating systems.

  6. Processing of CuInSe{sub 2}-based solar cells: Characterization of deposition processes in terms of chemical reaction analyses. Phase I annual report, 6 May 1995--5 May 1996

    SciTech Connect (OSTI)

    Anderson, T.

    1997-04-01

    An interdisciplinary team of five graduate students and four faculty have made considerable progress during Phase I of this program. The objective of this initiative is to develop a high-rate processing sequence to produce device-quality thin films of CI(G)S(Se). A comprehensive CI(G)S(Se) device fabrication capability is being established that includes thermal evaporation and plasma assisted deposition of CI(G)S(Se), rapid thermal processing, DC sputtering of both undoped and doped ZnO, CBD and MOCVD of CdS, and rf sputtering of Mo. Insight into the materials processing issues is being addressed through assessment of the thermochemistry and phase equilibria of the CI(G)S(Se) system, single crystal growth studies, investigation of Na effects on the growth, and detailed materials characterization.

  7. Thermal Properties Measurement Report

    SciTech Connect (OSTI)

    Carmack, Jon; Braase, Lori; Papesch, Cynthia; Hurley, David; Tonks, Michael; Zhang, Yongfeng; Gofryk, Krzysztof; Harp, Jason; Fielding, Randy; Knight, Collin; Meyer, Mitch

    2015-08-01

    The Thermal Properties Measurement Report summarizes the research, development, installation, and initial use of significant experimental thermal property characterization capabilities at the INL in FY 2015. These new capabilities were used to characterize a U3Si2 (candidate Accident Tolerant) fuel sample fabricated at the INL. The ability to perform measurements at various length scales is important and provides additional data that is not currently in the literature. However, the real value of the data will be in accomplishing a phenomenological understanding of the thermal conductivity in fuels and the ties to predictive modeling. Thus, the MARMOT advanced modeling and simulation capability was utilized to illustrate how the microstructural data can be modeled and compared with bulk characterization data. A scientific method was established for thermal property measurement capability on irradiated nuclear fuel samples, which will be installed in the Irradiated Material Characterization Laboratory (IMCL).

  8. Underhood Thermal Performance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Underhood Thermal Performance This email address is being protected from spambots. You need JavaScript enabled to view it. - Computational Fluid Dynamics Project Leader Background As vehicle technology advances, automakers need a better understanding of underhood heat loads, especially as they relate to emissions and fuel efficiency. Manufacturers of heavy-duty vehicles and off-road machines have similar concerns. Ineffective underhood thermal management can lead to higher emissions, reduced

  9. Turbine Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbine Thermal Management Fact Sheets Research Team Members Key Contacts Turbine Thermal Management The gas turbine is the workhorse of power generation, and technology advances to current land-based turbines are directly linked to our country's economic and energy security. Technical advancement for any type of gas turbine generally implies better performance, greater efficiency, and extended component life. From the standpoint of cycle efficiency and durability, this suggests that a continual

  10. Photovoltaic-thermal collectors

    DOE Patents [OSTI]

    Cox, III, Charles H.

    1984-04-24

    A photovoltaic-thermal solar cell including a semiconductor body having antireflective top and bottom surfaces and coated on each said surface with a patterned electrode covering less than 10% of the surface area. A thermal-absorbing surface is spaced apart from the bottom surface of the semiconductor and a heat-exchange fluid is passed between the bottom surface and the heat-absorbing surface.

  11. Plates for vacuum thermal fusion

    DOE Patents [OSTI]

    Davidson, James C.; Balch, Joseph W.

    2002-01-01

    A process for effectively bonding arbitrary size or shape substrates. The process incorporates vacuum pull down techniques to ensure uniform surface contact during the bonding process. The essence of the process for bonding substrates, such as glass, plastic, or alloys, etc., which have a moderate melting point with a gradual softening point curve, involves the application of an active vacuum source to evacuate interstices between the substrates while at the same time providing a positive force to hold the parts to be bonded in contact. This enables increasing the temperature of the bonding process to ensure that the softening point has been reached and small void areas are filled and come in contact with the opposing substrate. The process is most effective where at least one of the two plates or substrates contain channels or grooves that can be used to apply vacuum between the plates or substrates during the thermal bonding cycle. Also, it is beneficial to provide a vacuum groove or channel near the perimeter of the plates or substrates to ensure bonding of the perimeter of the plates or substrates and reduce the unbonded regions inside the interior region of the plates or substrates.

  12. Category:RAPID State Permitting Properties | Open Energy Information

    Open Energy Info (EERE)

    RAPID State Permitting Properties Jump to: navigation, search These properties are used by the RAPID toolkit state level permitting forms. Pages in category "RAPID State Permitting...

  13. User:Nlangle/RAPID-Solar-Search | Open Energy Information

    Open Energy Info (EERE)

    RAPID-Solar-Search < User:Nlangle Jump to: navigation, search Total RAPID Pages: 955 Category RAPID & Category Solar: 40 RAPIDSolar RAPIDSolarAir Quality RAPIDSolarCalifornia...

  14. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, A.; Doshi, P.; Tate, J.K.; Mejia, J.; Chen, Z.

    1998-06-16

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime {tau} and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime {tau} and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO{sub x}. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure. 28 figs.

  15. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, Ajeet; Doshi, Parag; Tate, John Keith; Mejia, Jose; Chen, Zhizhang

    1998-06-16

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure.

  16. Energy accounting of apple processing operations

    SciTech Connect (OSTI)

    Romero, R.; Singh, R.P.; Brown, D.

    1981-01-01

    A thermal-energy accounting study was conducted at an apple processing plant. An analysis is given of thermal energy use and thermal efficiencies of an apple-juice single-effect evaporator and an apple-sauce cooker. 3 refs.

  17. Thermal initiation caused by fragment impact on cased explosives

    SciTech Connect (OSTI)

    Schnurr, N.M. )

    1989-01-01

    Numerical calculations have been used to predict the velocity threshold for thermal initiation of a cased explosive caused by fragment impact. A structural analysis code was used to determine temperature profiles and a thermal analysis code was used to calculate reaction rates. Results generated for the United States Air Force MK 82 bomb indicate that the velocity threshold for thermal initiation is slightly higher than that for the shock-to-detonation process. 8 refs., 5 figs., 2 tabs.

  18. Test Proposal Document for Phased Field Thermal Testing in Salt |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Test Proposal Document for Phased Field Thermal Testing in Salt Test Proposal Document for Phased Field Thermal Testing in Salt The document summarizes how a new round of staged thermal field testing will help to augment the safety case for disposal of heat generating nuclear waste in salt. The objectives of the proposed test plan are to: (1) address features, events, and processes (FEPs), (2) build scientific and public confidence, (3) foster international

  19. Enhanced superconducting properties in Bi{sub 2}Sr{sub 2}Ca{sub 1}Cu{sub 2}O{sub y} by thermal and mechanical processing

    SciTech Connect (OSTI)

    Miller, D.J.; Holesinger, T.G.; Hettinger, J.D.; Goretta, K.C.; Gray, K.E.

    1992-08-01

    The practical application of high temperature superconductors has been limited by low transport currents in bulk samples. The effect of processing on transition temperature, grain boundary coupling, and flux pinning has been examined for Bi{sub 2}Sr{sub 2}Ca{sub 1}Cu{sub 2}O{sub y}. Enhancement of {Tc} based on composition can be achieved by control of crystallization and subsequent annealing processes while thermo-mechanical processing may be used to modify weak link and flux pinning behavior. The microstructural basis for these changes are related to the composition of the superconducting phase and the presence of defects associated with deformation processing. The implications of these results on conductor development are related to the selection of alloy composition for optimum transition temperature and controlled thermo-mechanical processing which yields a uniform defect structure.

  20. Automatic rapid attachable warhead section

    DOE Patents [OSTI]

    Trennel, Anthony J.

    1994-05-10

    Disclosed are a method and apparatus for (1) automatically selecting warheads or reentry vehicles from a storage area containing a plurality of types of warheads or reentry vehicles, (2) automatically selecting weapon carriers from a storage area containing at least one type of weapon carrier, (3) manipulating and aligning the selected warheads or reentry vehicles and weapon carriers, and (4) automatically coupling the warheads or reentry vehicles with the weapon carriers such that coupling of improperly selected warheads or reentry vehicles with weapon carriers is inhibited. Such inhibition enhances safety of operations and is achieved by a number of means including computer control of the process of selection and coupling and use of connectorless interfaces capable of assuring that improperly selected items will be rejected or rendered inoperable prior to coupling. Also disclosed are a method and apparatus wherein the stated principles pertaining to selection, coupling and inhibition are extended to apply to any item-to-be-carried and any carrying assembly.

  1. Automatic rapid attachable warhead section

    DOE Patents [OSTI]

    Trennel, A.J.

    1994-05-10

    Disclosed are a method and apparatus for automatically selecting warheads or reentry vehicles from a storage area containing a plurality of types of warheads or reentry vehicles, automatically selecting weapon carriers from a storage area containing at least one type of weapon carrier, manipulating and aligning the selected warheads or reentry vehicles and weapon carriers, and automatically coupling the warheads or reentry vehicles with the weapon carriers such that coupling of improperly selected warheads or reentry vehicles with weapon carriers is inhibited. Such inhibition enhances safety of operations and is achieved by a number of means including computer control of the process of selection and coupling and use of connectorless interfaces capable of assuring that improperly selected items will be rejected or rendered inoperable prior to coupling. Also disclosed are a method and apparatus wherein the stated principles pertaining to selection, coupling and inhibition are extended to apply to any item-to-be-carried and any carrying assembly. 10 figures.

  2. RAPID SEPARATION METHOD FOR 237NP AND PU ISOTOPES IN LARGE SOIL SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.; Culligan, B.; Noyes, G.

    2010-07-26

    A new rapid method for the determination of {sup 237}Np and Pu isotopes in soil and sediment samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used for large soil samples. The new soil method utilizes an acid leaching method, iron/titanium hydroxide precipitation, a lanthanum fluoride soil matrix removal step, and a rapid column separation process with TEVA Resin. The large soil matrix is removed easily and rapidly using this two simple precipitations with high chemical recoveries and effective removal of interferences. Vacuum box technology and rapid flow rates are used to reduce analytical time.

  3. Undercooled and rapidly quenched Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Hypoeutectic, eutectic, and hypereutectic nickel-molybdenum alloys were rapidly solidified by both bulk undercooling and melt spinning techniques. Alloys were undercooled in both electromagnetic levitation and differential thermal analysis equipment. The rate of recalescence depended upon the degree of initial undercooling and the nature (faceted or nonfaceted) of the primary nucleating phase. Alloy melts were observed to undercool more in the presence of primary Beta (NiMo intermetallic) phase than in gamma (fcc solid solution) phase. Melt spinning resulted in an extension of molybdenum solid solubility in gamma nickel, from 28 to 37.5 at % Mo. Although the microstructures observed by undercooling and melt spinning were similar the microsegregation pattern across the gamma dendries was different. The range of microstructures evolved was analyzed in terms of the nature of the primary phase to nucleate, its subsequent dendritic growth, coarsening and fragmentation, and final solidification of interfenderitic liquid.

  4. Thermal barrier coating resistant to sintering

    DOE Patents [OSTI]

    Subramanian, Ramesh; Seth, Brij B.

    2004-06-29

    A device (10) is made, having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10), is not soluble with the underlying ceramic layer (16) and is applied by a process that is not an electron beam physical vapor deposition process.

  5. Pyrite cathode material for a thermal battery

    SciTech Connect (OSTI)

    Pemsler, J.P.; Litchfield, J.K.

    1991-02-07

    The present invention relates in general to a synthetic cathode material for a molten salt battery and, more particularly, to a process of providing and using synthetic pyrite for use as a cathode in a thermal battery. These batteries, which have been successfully used in a number of military applications, include iron disulfide cathode material obtained as benefacted or from natural occurring pyrite deposits, or as a byproduct of flotation concentrate from the processing of base or noble metal ores.

  6. RAPID/Geothermal/Exploration/California | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalExplorationCalifornia < RAPID | Geothermal | Exploration(Redirected from RAPIDOverviewGeothermalExplorationCalifornia) Jump to: navigation, search RAPID...

  7. RAPID/Geothermal/Exploration/California | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalExplorationCalifornia < RAPID | Geothermal | Exploration Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About...

  8. RAPID/Geothermal/Exploration/Federal | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalExplorationFederal < RAPID | Geothermal | Exploration Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About...

  9. Article for thermal energy storage

    DOE Patents [OSTI]

    Salyer, Ival O.

    2000-06-27

    A thermal energy storage composition is provided which is in the form of a gel. The composition includes a phase change material and silica particles, where the phase change material may comprise a linear alkyl hydrocarbon, water/urea, or water. The thermal energy storage composition has a high thermal conductivity, high thermal energy storage, and may be used in a variety of applications such as in thermal shipping containers and gel packs.

  10. RAPID SEPARATION METHOD FOR ACTINIDES IN EMERGENCY SOIL SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.; Culligan, B.; Noyes, G.

    2009-11-09

    A new rapid method for the determination of actinides in soil and sediment samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used for samples up to 2 grams in emergency response situations. The actinides in soil method utilizes a rapid sodium hydroxide fusion method, a lanthanum fluoride soil matrix removal step, and a streamlined column separation process with stacked TEVA, TRU and DGA Resin cartridges. Lanthanum was separated rapidly and effectively from Am and Cm on DGA Resin. Vacuum box technology and rapid flow rates are used to reduce analytical time. Alpha sources are prepared using cerium fluoride microprecipitation for counting by alpha spectrometry. The method showed high chemical recoveries and effective removal of interferences. This new procedure was applied to emergency soil samples received in the NRIP Emergency Response exercise administered by the National Institute for Standards and Technology (NIST) in April, 2009. The actinides in soil results were reported within 4-5 hours with excellent quality.

  11. RAPID SEPARATION OF ACTINIDES AND RADIOSTRONTIUM IN VEGETATION SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.

    2010-06-01

    A new rapid method for the determination of actinides and radiostrontium in vegetation samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used in emergency response situations or for routine analysis. The actinides in vegetation method utilizes a rapid sodium hydroxide fusion method, a lanthanum fluoride matrix removal step, and a streamlined column separation process with stacked TEVA, TRU and DGA Resin cartridges. Lanthanum was separated rapidly and effectively from Am and Cm on DGA Resin. Alpha emitters are prepared using rare earth microprecipitation for counting by alpha spectrometry. The purified {sup 90}Sr fractions are mounted directly on planchets and counted by gas flow proportional counting. The method showed high chemical recoveries and effective removal of interferences. The actinide and {sup 90}Sr in vegetation sample analysis can be performed in less than 8 h with excellent quality for emergency samples. The rapid fusion technique is a rugged sample digestion method that ensures that any refractory actinide particles or vegetation residue after furnace heating is effectively digested.

  12. Highly directional thermal emitter

    DOE Patents [OSTI]

    Ribaudo, Troy; Shaner, Eric A; Davids, Paul; Peters, David W

    2015-03-24

    A highly directional thermal emitter device comprises a two-dimensional periodic array of heavily doped semiconductor structures on a surface of a substrate. The array provides a highly directional thermal emission at a peak wavelength between 3 and 15 microns when the array is heated. For example, highly doped silicon (HDSi) with a plasma frequency in the mid-wave infrared was used to fabricate nearly perfect absorbing two-dimensional gratings structures that function as highly directional thermal radiators. The absorption and emission characteristics of the HDSi devices possessed a high degree of angular dependence for infrared absorption in the 10-12 micron range, while maintaining high reflectivity of solar radiation (.about.64%) at large incidence angles.

  13. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, S.E.; Arasteh, D.K.; Hartmann, J.L.

    1988-04-05

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas. 2 figs.

  14. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, Stephen E. (Piedmont, CA); Arasteh, Dariush K. (Oakland, CA); Hartmann, John L. (Seattle, WA)

    1991-01-01

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas.

  15. Thermal trim for luminaire

    DOE Patents [OSTI]

    Bazydola, Sarah; Ghiu, Camil-Daniel; Harrison, Robert; Jeswani, Anil

    2013-11-19

    A luminaire with a thermal pathway to reduce the junction temperature of the luminaire's light source, and methods for so doing, are disclosed. The luminaire includes a can, a light engine, and a trim, that define a substantially continuous thermal pathway from the light engine to a surrounding environment. The can defines a can cavity and includes a can end region. The light engine is within the can cavity and includes a light source and a heat sink, including a heat sink end region, coupled thereto. The trim is at least partially disposed within the can cavity and includes a first trim end region coupled to the heat sink end region and a second trim end region coupled to the can end region. Thermal interface material may be located between: the heat sink and the trim, the trim and the can, and/or the heat sink and the light source.

  16. Non-thermal x-ray emission from wire array z-pinches

    SciTech Connect (OSTI)

    Ampleford, David; Hansen, Stephanie B.; Jennings, Christopher Ashley; Webb, Timothy Jay; Harper-Slaboszewicz, V.; Loisel, Guillaume Pascal; Flanagan, Timothy McGuire; Bell, Kate Suzanne; Jones, Brent M.; McPherson, Leroy A.; Rochau, Gregory A.; Chittenden, Jeremy P.; Sherlock, Mark; Appelbe, Brian; Giuliani, John; Ouart, Nicholas; Seely, John

    2015-12-01

    We report on experiments demonstrating the transition from thermally-dominated K-shell line emission to non-thermal, hot-electron-driven inner-shell emission for z pinch plasmas on the Z machine. While x-ray yields from thermal K-shell emission decrease rapidly with increasing atomic number Z, we find that non-thermal emission persists with favorable Z scaling, dominating over thermal emission for Z=42 and higher (hn ≥ 17keV). Initial experiments with Mo (Z=42) and Ag (Z=47) have produced kJ-level emission in the 17-keV and 22-keV Kα lines respectively. We will discuss the electron beam properties that could excite these non - thermal lines. We also report on experiments that have attempted to control non - thermal K - shell line emission by modifying the wire array or load hardware setup.

  17. Presidential Rapid Commercialization Initiative for mixed waste solvent extraction

    SciTech Connect (OSTI)

    Honigford, L.; Dilday, D.; Cook, D.; Sattler, J.

    1997-03-01

    Recently, the Fernald Environmental Management Project (FEMP) has made some major steps in mixed waste treatment which have taken it closer to meeting final remediation goals. However, one major hurdle remains for the FEMP mixed waste treatment program, and that hurdle is tri-mixed waste. Tri-mixed is a term coined to describe low-level waste containing RCRA hazardous constituents along with polychlorinated biphenyls (PCB). The prescribed method for disposal of PCBs is incineration. In mixed waste treatment plans developed by the FEMP with public input, the FEMP committed to pursue non-thermal treatment methods and avoid the use of incineration. Through the SITE Program, the FEMP identified a non-thermal treatment technology which uses solvents to extract PCBs. The technology belongs to a small company called Terra-Kleen Response Group, Inc. A question arose as to how can this new and innovative technology be implemented by a small company at a Department of Energy (DOE) facility. The answer came in the form of the Rapid Commercialization Initiative (RCI) and the Mixed Waste Focus Area (MWFA). RCI is a program sponsored by the Department of commerce (DOC), DOE, Department of Defense (DOD), US EPA and various state agencies to aid companies to market new and innovative technologies.

  18. Microstructural Development in Al-Si Powder During Rapid Solidification

    SciTech Connect (OSTI)

    Amber Lynn Genau

    2004-12-19

    Powder metallurgy has become an increasingly important form of metal processing because of its ability to produce materials with superior mechanical properties. These properties are due in part to the unique and often desirable microstructures which arise as a result of the extreme levels of undercooling achieved, especially in the finest size powder, and the subsequent rapid solidification which occurs. A better understanding of the fundamental processes of nucleation and growth is required to further exploit the potential of rapid solidification processing. Aluminum-silicon, an alloy of significant industrial importance, was chosen as a model for simple eutectic systems displaying an unfaceted/faceted interface and skewed coupled eutectic growth zone, Al-Si powder produced by high pressure gas atomization was studied to determine the relationship between microstructure and alloy composition as a function of powder size and atomization gas. Critical experimental measurements of hypereutectic (Si-rich) compositions were used to determine undercooling and interface velocity, based on the theoretical models which are available. Solidification conditions were analyzed as a function of particle diameter and distance from nucleation site. A revised microstructural map is proposed which allows the prediction of particle morphology based on temperature and composition. It is hoped that this work, by providing enhanced understanding of the processes which govern the development of the solidification morphology of gas atomized powder, will eventually allow for better control of processing conditions so that particle microstructures can be optimized for specific applications.

  19. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

    1988-04-19

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

  20. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, Roy; Kakwani, Ramesh M.; Valdmanis, Edgars; Woods, Melvins E.

    1988-01-01

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m.degree. C. and a specific heat greater than 480 J/kg.degree. C. with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber.

  1. Rapid onsite assessment of spore viability.

    SciTech Connect (OSTI)

    Branda, Steven; Lane, Todd W.; VanderNoot, Victoria A.; Gaucher, Sara P.; Jokerst, Amanda S.

    2005-12-01

    This one year LDRD addresses problems of threat assessment and restoration of facilities following a bioterror incident like the incident that closed down mail facilities in late 2001. Facilities that are contaminated with pathogenic spores such as B. anthracis spores must be shut down while they are treated with a sporicidal agent and the effectiveness of the treatment is ascertained. This process involves measuring the viability of spore test strips, laid out in a grid throughout the facility; the CDC accepted methodologies require transporting the samples to a laboratory and carrying out a 48 hr outgrowth experiment. We proposed developing a technique that will ultimately lead to a fieldable microfluidic device that can rapidly assess (ideally less than 30 min) spore viability and effectiveness of sporicidal treatment, returning facilities to use in hours not days. The proposed method will determine viability of spores by detecting early protein synthesis after chemical germination. During this year, we established the feasibility of this approach and gathered preliminary results that should fuel a future more comprehensive effort. Such a proposal is currently under review with the NIH. Proteomic signatures of Bacillus spores and vegetative cells were assessed by both slab gel electrophoresis as well as microchip based gel electrophoresis employing sensitive laser-induced fluorescence detection. The conditions for germination using a number of chemical germinants were evaluated and optimized and the time course of protein synthesis was ascertained. Microseparations were carried out using both viable spores and spores inactivated by two different methods. A select number of the early synthesis proteins were digested into peptides for analysis by mass spectrometry.

  2. RAPID/Contribute | Open Energy Information

    Open Energy Info (EERE)

    log in to your OpenEI account. Go to the page you want to watch, select EDIT at the top, and choose WATCH THIS PAGE at the bottom the page. Contribute to the RAPID Toolkit The...

  3. RAPID/Get Involved | Open Energy Information

    Open Energy Info (EERE)

    join us as a contributor or attend one of our upcoming meetings. Be a Contributor Update.jpg RAPID OpenEI Tutorial.pdf Please feel free to log in to OpenEI and make content...

  4. RAPID/Wizard | Open Energy Information

    Open Energy Info (EERE)

    English References: NREL 1 The RAPID Roadmap Wizard is a tool designed to help you zero in on the permits needed for your project. Your answers to a few basic questions will...

  5. The Rotary Zone Thermal Cycler: A Low-Power System Enabling Rapid...

    Office of Scientific and Technical Information (OSTI)

    ... expanding collection of fast, thermostable, and ... 64 65 33, but sodium hydroxide 66 67 68 ... chambers, PCR reactors, CE separation channels, ...

  6. Retrieval/ex situ thermal treatment scoring interaction report

    SciTech Connect (OSTI)

    Raivo, B.D.; Richardson, J.G.

    1993-11-01

    A retrieval/ex situ thermal treatment technology process for the Idaho National Engineering Laboratory transuranic waste pits and trenches is present. A system performance score is calculated, and assumptions, requirements, and reference baseline technologies for all subelements are included.

  7. Connecticut's Health Impact Study Rapidly Increasing Weatherization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efforts | Department of Energy Connecticut's Health Impact Study Rapidly Increasing Weatherization Efforts Connecticut's Health Impact Study Rapidly Increasing Weatherization Efforts June 18, 2014 - 10:49am Addthis Weatherization workers are trained in the house as a system approach. The Energy Department's Weatherization Assistance Program funded technical assistance as part of Connecticut's Health Impact Assessment project. | Photo courtesy of Weatherization Assistance Program Technical

  8. Thermal Reactor Safety

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Information is presented concerning fire risk and protection; transient thermal-hydraulic analysis and experiments; class 9 accidents and containment; diagnostics and in-service inspection; risk and cost comparison of alternative electric energy sources; fuel behavior and experiments on core cooling in LOCAs; reactor event reporting analysis; equipment qualification; post facts analysis of the TMI-2 accident; and computational methods.

  9. Thermal barrier coating

    DOE Patents [OSTI]

    Bowker, Jeffrey Charles; Sabol, Stephen M.; Goedjen, John G.

    2001-01-01

    A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

  10. Ocean thermal energy conversion

    SciTech Connect (OSTI)

    Avery, W.H.

    1983-03-17

    A brief explanation of the Ocean Thermal Energy Conversion (OTEC) concept and an estimate of the amount of energy that can be produced from the ocean resource without introducing environmental concerns are presented. Use of the OTEC system to generate electric power and products which can replace fossil fuels is shown. The OTEC program status and its prospects for the future are discussed.

  11. Westinghouse thermal barrier coatings development

    SciTech Connect (OSTI)

    Goedjen, J.G.; Wagner, G.

    1995-10-01

    Westinghouse, in conjunction with the Department of Energy and Oak Ridge National Laboratory, has embarked upon a program for the development of advanced thermal barrier coatings for industrial gas turbines. Development of thermal barrier coatings (TBC`s) for industrial gas turbines has relied heavily on the transfer of technology from the aerospace industry. Significant differences in the time/temperature/stress duty cycles exist between these two coating applications. Coating systems which perform well in aerospace applications may not been optimized to meet power generation performance requirements. This program will focus on development of TBC`s to meet the specific needs of power generation applications. The program is directed at developing a state-of-the-art coating system with a minimum coating life of 25,000 hours at service temperatures required to meet increasing operating efficiency goals. Westinghouse has assembled a team of university and industry leaders to accomplish this goal. Westinghouse will coordinate the efforts of all program participants. Chromalloy Turbine Technologies, Inc. and Sermatech International, Inc. will be responsible for bond coat and TBC deposition technology. Praxair Specialty Powders, Inc. will be responsible for the fabrication of all bond coat and ceramic powders for the program. Southwest Research Institute will head the life prediction modelling effort; they will also be involved in coordinating nondestructive evaluation (NDE) efforts. Process modelling will be provided by the University of Arizona.

  12. Gas storage carbon with enhanced thermal conductivity

    DOE Patents [OSTI]

    Burchell, Timothy D.; Rogers, Michael Ray; Judkins, Roddie R.

    2000-01-01

    A carbon fiber carbon matrix hybrid adsorbent monolith with enhanced thermal conductivity for storing and releasing gas through adsorption and desorption is disclosed. The heat of adsorption of the gas species being adsorbed is sufficiently large to cause hybrid monolith heating during adsorption and hybrid monolith cooling during desorption which significantly reduces the storage capacity of the hybrid monolith, or efficiency and economics of a gas separation process. The extent of this phenomenon depends, to a large extent, on the thermal conductivity of the adsorbent hybrid monolith. This invention is a hybrid version of a carbon fiber monolith, which offers significant enhancements to thermal conductivity and potential for improved gas separation and storage systems.

  13. City of Grand Rapids Building Solar Roof Demonstration

    SciTech Connect (OSTI)

    DeClercq, Mark; Martinez, Imelda

    2012-08-31

    Grand Rapids, Michigan is striving to reduce it environmental footprint. The municipal government organization has established environmental sustainability policies with the goal of securing 100% of its energy from renewable sources by 2020. This report describes the process by which the City of Grand Rapids evaluated, selected and installed solar panels on the Water/Environmental Services Building. The solar panels are the first to be placed on a municipal building. Its new power monitoring system provides output data to assess energy efficiency and utilization. It is expected to generate enough clean solar energy to power 25 percent of the building. The benefit to the public includes the economic savings from reduced operational costs for the building; an improved environmentally sustainable area in which to live and work; and increased knowledge about the use of solar energy. It will serve as a model for future energy saving applications.

  14. Embedded Optical Sensors for Thermal Barrier Coatings

    SciTech Connect (OSTI)

    David R. Clarke

    2006-07-31

    The third year of this program on developing embedded optical sensors for thermal barrier coatings has been devoted to two principal topics: (i) continuing the assessment of the long-term, thermal cycle stability of the Eu{sup 3+} doped 8YSZ temperature sensor coatings, and (ii) improving the fiber-optic based luminescence detector system. Following the earlier, preliminary findings, it has been found that not only is the luminescence from the sensors not affected by prolonged thermal cycling, even after 195 hours at 1425 C, but the variation in luminescence lifetime with temperature remains unchanged. As the temperature of 1425 C is much higher than present engines attain or even planned in the foreseeable future, our findings indicate that the Eu{sup 3+} doped thermal barrier coating sensors are very robust and have the potential of being stable throughout the life of coatings. Investigation of Eu{sup 3+} doped coatings prepared by plasma-spraying exhibited the same luminescence characteristics as those prepared by electron-beam evaporation. This is of major significance since thermal barrier coatings can be prepared by both process technologies. A fiber-optic based luminescence system has been constructed in which the hottest section of fiber operates to at least 1250 C.

  15. Thermal hydraulics development for CASL

    SciTech Connect (OSTI)

    Lowrie, Robert B

    2010-12-07

    This talk will describe the technical direction of the Thermal-Hydraulics (T-H) Project within the Consortium for Advanced Simulation of Light Water Reactors (CASL) Department of Energy Innovation Hub. CASL is focused on developing a 'virtual reactor', that will simulate the physical processes that occur within a light-water reactor. These simulations will address several challenge problems, defined by laboratory, university, and industrial partners that make up CASL. CASL's T-H efforts are encompassed in two sub-projects: (1) Computational Fluid Dynamics (CFD), (2) Interface Treatment Methods (ITM). The CFD subproject will develop non-proprietary, scalable, verified and validated macroscale CFD simulation tools. These tools typically require closures for their turbulence and boiling models, which will be provided by the ITM sub-project, via experiments and microscale (such as DNS) simulation results. The near-term milestones and longer term plans of these two sub-projects will be discussed.

  16. Thermal shock resistance ceramic insulator

    DOE Patents [OSTI]

    Morgan, Chester S. (Oak Ridge, TN); Johnson, William R. (Maynardville, TN)

    1980-01-01

    Thermal shock resistant cermet insulators containing 0.1-20 volume % metal present as a dispersed phase. The insulators are prepared by a process comprising the steps of (a) providing a first solid phase mixture of a ceramic powder and a metal precursor; (b) heating the first solid phase mixture above the minimum decomposition temperature of the metal precursor for no longer than 30 minutes and to a temperature sufficiently above the decomposition temperature to cause the selective decomposition of the metal precursor to the metal to provide a second solid phase mixture comprising particles of ceramic having discrete metal particles adhering to their surfaces, said metal particles having a mean diameter no more than 1/2 the mean diameter of the ceramic particles, and (c) densifying the second solid phase mixture to provide a cermet insulator having 0.1-20 volume % metal present as a dispersed phase.

  17. National Solar Thermal Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SunShot Grand Challenge: Regional Test Centers National Solar Thermal Test Facility HomeTag:National Solar Thermal Test Facility Molten Nitrate Salt Initial Flow Testing is a ...

  18. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9 Companies involved in solar thermal collector related activities by type, 2008 and 2009 ... 26 32 Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal

  19. Solar Thermal Collector Manufacturing Activities

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    8 Employment in the solar thermal collector industry, 2000 - 2009 2000 284 2001 256 2002 ... Source: U.S. Energy Information Administration, Form EIA-63A, "Annual Solar Thermal

  20. Electricity storage using a thermal storage scheme

    SciTech Connect (OSTI)

    White, Alexander

    2015-01-22

    The increasing use of renewable energy technologies for electricity generation, many of which have an unpredictably intermittent nature, will inevitably lead to a greater demand for large-scale electricity storage schemes. For example, the expanding fraction of electricity produced by wind turbines will require either backup or storage capacity to cover extended periods of wind lull. This paper describes a recently proposed storage scheme, referred to here as Pumped Thermal Storage (PTS), and which is based on “sensible heat” storage in large thermal reservoirs. During the charging phase, the system effectively operates as a high temperature-ratio heat pump, extracting heat from a cold reservoir and delivering heat to a hot one. In the discharge phase the processes are reversed and it operates as a heat engine. The round-trip efficiency is limited only by process irreversibilities (as opposed to Second Law limitations on the coefficient of performance and the thermal efficiency of the heat pump and heat engine respectively). PTS is currently being developed in both France and England. In both cases, the schemes operate on the Joule-Brayton (gas turbine) cycle, using argon as the working fluid. However, the French scheme proposes the use of turbomachinery for compression and expansion, whereas for that being developed in England reciprocating devices are proposed. The current paper focuses on the impact of the various process irreversibilities on the thermodynamic round-trip efficiency of the scheme. Consideration is given to compression and expansion losses and pressure losses (in pipe-work, valves and thermal reservoirs); heat transfer related irreversibility in the thermal reservoirs is discussed but not included in the analysis. Results are presented demonstrating how the various loss parameters and operating conditions influence the overall performance.

  1. A Spectrum of Nerve Injury after Thermal Ablation: A Report of Four Cases and Review of the Literature

    SciTech Connect (OSTI)

    Philip, Asher; Gupta, Sanjay Ahrar, Kamran Tam, Alda L.

    2013-10-15

    Thermal ablation is an accepted alternative for the palliation of pain from bone metastases. Although rare, neurologic complications after thermal ablation have been reported. We present four cases, including two cases of rapid reversal of postcryoablation neurapraxia after the administration of steroid therapy, and review the literature.

  2. Thermally stable diamond brazing

    DOE Patents [OSTI]

    Radtke, Robert P.

    2009-02-10

    A cutting element and a method for forming a cutting element is described and shown. The cutting element includes a substrate, a TSP diamond layer, a metal interlayer between the substrate and the diamond layer, and a braze joint securing the diamond layer to the substrate. The thickness of the metal interlayer is determined according to a formula. The formula takes into account the thickness and modulus of elasticity of the metal interlayer and the thickness of the TSP diamond. This prevents the use of a too thin or too thick metal interlayer. A metal interlayer that is too thin is not capable of absorbing enough energy to prevent the TSP diamond from fracturing. A metal interlayer that is too thick may allow the TSP diamond to fracture by reason of bending stress. A coating may be provided between the TSP diamond layer and the metal interlayer. This coating serves as a thermal barrier and to control residual thermal stress.

  3. National Solar Thermal Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SunShot Grand Challenge: Regional Test Centers National Solar Thermal Test Facility Home/Tag:National Solar Thermal Test Facility Illuminated receiver on top of tower Permalink Gallery High-Temperature Falling Particle Receiver Reaches New Limits Concentrating Solar Power, Energy, National Solar Thermal Test Facility, News, Renewable Energy, Solar, SunShot High-Temperature Falling Particle Receiver Reaches New Limits At its National Solar Thermal Test Facility, Sandia National Laboratories

  4. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  5. Thermally actuated thermionic switch

    DOE Patents [OSTI]

    Barrus, Donald M.; Shires, Charles D.

    1988-01-01

    A thermally actuated thermionic switch which responds to an increase of temperature by changing from a high impedance to a low impedance at a predictable temperature set point. The switch has a bistable operation mode switching only on temperature increases. The thermionic material may be a metal which is liquid at the desired operation temperature and held in matrix in a graphite block reservoir, and which changes state (ionizes, for example) so as to be electrically conductive at a desired temperature.

  6. THERMAL NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Spinrad, B.I.

    1960-01-12

    A novel thermal reactor was designed in which a first reflector formed from a high atomic weight, nonmoderating material is disposed immediately adjacent to the reactor core. A second reflector composed of a moderating material is disposed outwardly of the first reflector. The advantage of this novel reflector arrangement is that the first reflector provides a high slow neutron flux in the second reflector, where irradiation experiments may be conducted with a small effect on reactor reactivity.

  7. Thermal reactor safety

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Information is presented concerning new trends in licensing; seismic considerations and system structural behavior; TMI-2 risk assessment and thermal hydraulics; statistical assessment of potential accidents and verification of computational methods; issues with respect to improved safety; human factors in nuclear power plant operation; diagnostics and activities in support of recovery; LOCA transient analysis; unresolved safety issues and other safety considerations; and fission product transport.

  8. Thermally actuated thermionic switch

    DOE Patents [OSTI]

    Barrus, D.M.; Shires, C.D.

    1982-09-30

    A thermally actuated thermionic switch which responds to an increase of temperature by changing from a high impedance to a low impedance at a predictable temperature set point. The switch has a bistable operation mode switching only on temperature increases. The thermionic material may be a metal which is liquid at the desired operation temperature and held in matrix in a graphite block reservoir, and which changes state (ionizes, for example) so as to be electrically conductive at a desired temperature.

  9. Composition and Manufacturing Effects on Electrical Properties of Li/FeS2 Thermal Battery Cathodes

    SciTech Connect (OSTI)

    Reinholz, Emilee Lolita

    2015-10-01

    The purpose of this thesis was to better understand the relationship between processing, microstructure, and electrical conductivity of LiFeS2 thermal battery cathodes.

  10. Development of an Innovative High-Thermal Conductivity UO2 Ceramic Composites Fuel Pellets with Carbon Nano-Tubes Using Spark Plasma Sintering

    SciTech Connect (OSTI)

    Subhash, Ghatu; Wu, Kuang-Hsi; Tulenko, James

    2014-03-10

    Uranium dioxide (UO2) is the most common fuel material in commercial nuclear power reactors. Despite its numerous advantages such as high melting point, good high-temperature stability, good chemical compatibility with cladding and coolant, and resistance to radiation, it suffers from low thermal conductivity that can result in large temperature gradients within the UO2 fuel pellet, causing it to crack and release fission gases. Thermal swelling of the pellets also limits the lifetime of UO2 fuel in the reactor. To mitigate these problems, we propose to develop novel UO2 fuel with uniformly distributed carbon nanotubes (CNTs) that can provide high-conductivity thermal pathways and can eliminate fuel cracking and fission gas release due to high temperatures. CNTs have been investigated extensively for the past decade to explore their unique physical properties and many potential applications. CNTs have high thermal conductivity (6600 W/mK for an individual single- walled CNT and >3000 W/mK for an individual multi-walled CNT) and high temperature stability up to 2800°C in vacuum and about 750°C in air. These properties make them attractive candidates in preparing nano-composites with new functional properties. The objective of the proposed research is to develop high thermal conductivity of UO2–CNT composites without affecting the neutronic property of UO2 significantly. The concept of this goal is to utilize a rapid sintering method (5–15 min) called spark plasma sintering (SPS) in which a mixture of CNTs and UO2 powder are used to make composites with different volume fractions of CNTs. Incorporation of these nanoscale materials plays a fundamentally critical role in controlling the performance and stability of UO2 fuel. We will use a novel in situ growth process to grow CNTs on UO2 particles for rapid sintering and develop UO2-CNT composites. This method is expected to provide a uniform distribution of CNTs at various volume fractions so that a high

  11. Solar Thermal Electric | Open Energy Information

    Open Energy Info (EERE)

    Thermal Electric Jump to: navigation, search TODO: Add description List of Solar Thermal Electric Incentives Retrieved from "http:en.openei.orgwindex.php?titleSolarThermalEl...

  12. Power Electronic Thermal System Performance and Integration ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Motor Thermal Control Thermal Stress and Reliability for Advanced Power Electronics and Electric Machines Integrated Vehicle Thermal Management

  13. Ocean Thermal Extractable Energy Visualization: Final Technical...

    Office of Environmental Management (EM)

    Ocean Thermal Extractable Energy Visualization: Final Technical Report Ocean Thermal Extractable Energy Visualization: Final Technical Report Report about the Ocean Thermal ...

  14. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, Ajeet; Chen, Zhizhang; Doshi, Parag

    1996-01-01

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. Silicon solar cell efficiencies of 16.9% have been achieved. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x.

  15. Methods of forming thermal management systems and thermal management methods

    DOE Patents [OSTI]

    Gering, Kevin L.; Haefner, Daryl R.

    2012-06-05

    A thermal management system for a vehicle includes a heat exchanger having a thermal energy storage material provided therein, a first coolant loop thermally coupled to an electrochemical storage device located within the first coolant loop and to the heat exchanger, and a second coolant loop thermally coupled to the heat exchanger. The first and second coolant loops are configured to carry distinct thermal energy transfer media. The thermal management system also includes an interface configured to facilitate transfer of heat generated by an internal combustion engine to the heat exchanger via the second coolant loop in order to selectively deliver the heat to the electrochemical storage device. Thermal management methods are also provided.

  16. Contributions of anharmonic phonon interactions to thermal boundary conductance.

    SciTech Connect (OSTI)

    Hopkins, Patrick E.; Norris, Pamela M.; Duda, John C.

    2010-05-01

    Continued reduction of characteristic dimensions in nanosystems has given rise to increasing importance of material interfaces on the overall system performance. With regard to thermal transport, this increases the need for a better fundamental understanding of the processes affecting interfacial thermal transport, as characterized by the thermal boundary conductance. When thermal boundary conductance is driven by phononic scattering events, accurate predictions of interfacial transport must account for anharmonic phononic coupling as this affects the thermal transmission. In this paper, a new model for phononic thermal boundary conductance is developed that takes into account anharonic coupling, or inelastic scattering events, at the interface between two materials. Previous models for thermal boundary conductance are first reviewed, including the Diffuse Mismatch Model, which only consdiers elastic phonon scattering events, and earlier attempts to account for inelastic phonon scattering, namely, the Maximum Transmission Model and the Higher Harmonic Inelastic model. A new model is derived, the Anharmonic Inelastic Model, which provides a more physical consideration of the effects of inelastic scattering on thermal boundary conductance. This is accomplished by considering specific ranges of phonon frequency interactions and phonon number density conservation. Thus, this model considers the contributions of anharmonic, inelastically scattered phonons to thermal boundary conductance. This new Anharmonic Inelastic Model shows excellent agreement between model predictions and experimental data at the Pb/diamond interface due to its ability to account for the temperature dependent changing phonon population in diamond, which can couple anharmonically with multiple phonons in Pb.

  17. Rapid prototyping for radio-frequency geolocation applications

    SciTech Connect (OSTI)

    Briles, S. C.; Arrowood, J. L.; Braun, T. R.; Turcotte, D.; Fiset, E.

    2004-01-01

    Previous space-to-ground, single-platform geolocation experiments exploiting time-difference-of arrival (TDOA) via interferometry were successful at separating and quantitatively characterizing interfering radio frequency (RF) signals from expected RF transmissions. Much of the success of these experiments rested on the use of embedded processors to perform the required signal processing. The experiments handled data in a 'snapshot' fashion: digitized data was collected, the data was processed via a digital signal processing (DSP) microprocessor to yield differential phase measurements, and these measurements were transmitted to the Earth for geolocation processing. With the utilization of FPGAs (field programmable gate arrays) for the intensive number-crunching algorithms, the processing of streaming real-time data is feasible for bandwidths on the order of 20 MHz. By partitioning the signal processing algorithm so there is a significant reduction in the data rate as data flows through the FPGA, a DSP microprocessor can now be employed to perform further decision-oriented processing on the FPGA output. This hybrid architecture, employing both FPGAs and DSPs, typically requires an expensive and lengthy development cycle. However, the use of graphical development environments with auto-code generation and hardware-in-the-loop testing can result in rapid prototyping for geolocation experiments, which enables adaptation to emerging signals of interest in a cost and time effective manner.

  18. Flameless thermal oxidation. Innovative technology summary report

    SciTech Connect (OSTI)

    1995-09-01

    The Flameless Thermal Oxidizer (FTO) is a commercial technology offered by Thermatrix, Inc. The FTO has been demonstrated to be an effective destructive technology for process and waste stream off-gas treatment of volatile organic compounds (VOCs), and in the treatment of VOC and chlorinated volatile organic compounds (CVOCs) off-gases generated during site remediation using either baseline or innovative in situ environmental technologies. The FTO process efficiently converts VOCs and CVOCs to carbon dioxide, water, and hydrogen chloride. When FTO is coupled with a baseline technology, such as soil vapor extraction (SVE), an efficient in situ soil remediation system is produced. The innovation is in using a simple, reliable, scalable, and robust technology for the destruction of VOC and CVOC off-gases based on a design that generates a uniform thermal reaction zone that prevents flame propagation and efficiently oxidizes off-gases without forming products of incomplete combustion (PICs).

  19. RAPID SEPARATION METHOD FOR ACTINIDES IN EMERGENCY AIR FILTER SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.; Noyes, G.; Culligan, B.

    2010-02-03

    A new rapid method for the determination of actinides and strontium in air filter samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used in emergency response situations. The actinides and strontium in air filter method utilizes a rapid acid digestion method and a streamlined column separation process with stacked TEVA, TRU and Sr Resin cartridges. Vacuum box technology and rapid flow rates are used to reduce analytical time. Alpha emitters are prepared using cerium fluoride microprecipitation for counting by alpha spectrometry. The purified {sup 90}Sr fractions are mounted directly on planchets and counted by gas flow proportional counting. The method showed high chemical recoveries and effective removal of interferences. This new procedure was applied to emergency air filter samples received in the NRIP Emergency Response exercise administered by the National Institute for Standards and Technology (NIST) in April, 2009. The actinide and {sup 90}Sr in air filter results were reported in {approx}4 hours with excellent quality.

  20. Active cooling-based surface confinement system for thermal soil treatment

    DOE Patents [OSTI]

    Aines, Roger D.; Newmark, Robin L.

    1997-01-01

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders.

  1. Active cooling-based surface confinement system for thermal soil treatment

    DOE Patents [OSTI]

    Aines, R.D.; Newmark, R.L.

    1997-10-28

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders. 1 fig.

  2. RAPID DETERMINATION OF RA-226 IN ENVIRONMENTAL SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.

    2012-01-03

    A new rapid method for the determination of {sup 226}Ra in environmental samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used for emergency response or routine sample analyses. The need for rapid analyses in the event of a Radiological Dispersive Device or Improvised Nuclear Device event is well-known. In addition, the recent accident at Fukushima Nuclear Power Plant in March, 2011 reinforces the need to have rapid analyses for radionuclides in environmental samples in the event of a nuclear accident. {sup 226}Ra (T1/2 = 1,620 years) is one of the most toxic of the long-lived alpha-emitters present in the environment due to its long life and its tendency to concentrate in bones, which increases the internal radiation dose of individuals. The new method to determine {sup 226}Ra in environmental samples utilizes a rapid sodium hydroxide fusion method for solid samples, calcium carbonate precipitation to preconcentrate Ra, and rapid column separation steps to remove interferences. The column separation process uses cation exchange resin to remove large amounts of calcium, Sr Resin to remove barium and Ln Resin as a final purification step to remove {sup 225}Ac and potential interferences. The purified {sup 226}Ra sample test sources are prepared using barium sulfate microprecipitation in the presence of isopropanol for counting by alpha spectrometry. The method showed good chemical recoveries and effective removal of interferences. The determination of {sup 226}Ra in environmental samples can be performed in less than 16 h for vegetation, concrete, brick, soil, and air filter samples with excellent quality for emergency or routine analyses. The sample preparation work takes less than 6 h. {sup 225}Ra (T1/2 = 14.9 day) tracer is used and the {sup 225}Ra progeny {sup 217}At is used to determine chemical yield via alpha spectrometry. The rapid fusion technique is a rugged sample digestion method that ensures that any

  3. Thermal control structure and garment

    DOE Patents [OSTI]

    Klett, James W.; Cameron, Christopher Stan

    2012-03-13

    A flexible thermally conductive structure. The structure generally includes a plurality of thermally conductive yarns, at least some of which are at least partially disposed adjacent to an elastomeric material. Typically, at least a portion of the plurality of thermally conductive yarns is configured as a sheet. The yarns may be constructed from graphite, metal, or similar materials. The elastomeric material may be formed from urethane or silicone foam that is at least partially collapsed, or from a similar material. A thermal management garment is provided, the garment incorporating a flexible thermally conductive structure.

  4. Method and apparatus for a combination moving bed thermal treatment reactor and moving bed filter

    SciTech Connect (OSTI)

    Badger, Phillip C.; Dunn, Jr., Kenneth J.

    2015-09-01

    A moving bed gasification/thermal treatment reactor includes a geometry in which moving bed reactor particles serve as both a moving bed filter and a heat carrier to provide thermal energy for thermal treatment reactions, such that the moving bed filter and the heat carrier are one and the same to remove solid particulates or droplets generated by thermal treatment processes or injected into the moving bed filter from other sources.

  5. Working with SRNL - Our Facilities- Rapid Fabrication Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rapid Fabrication Facility Working with SRNL Our Facilities - Rapid Fabrication Facility At SRNL's Rapid Fabrication Facility, low-cost prototypes are produced, as well as parts and complete working models

  6. Rapid Cycling Synchrotron Option for Project X (Conference) ...

    Office of Scientific and Technical Information (OSTI)

    Rapid Cycling Synchrotron Option for Project X Citation Details In-Document Search Title: Rapid Cycling Synchrotron Option for Project X This paper presents an 8 GeV Rapid Cycling ...

  7. Thermal management systems and methods

    DOE Patents [OSTI]

    Gering, Kevin L.; Haefner, Daryl R.

    2006-12-12

    A thermal management system for a vehicle includes a heat exchanger having a thermal energy storage material provided therein, a first coolant loop thermally coupled to an electrochemical storage device located within the first coolant loop and to the heat exchanger, and a second coolant loop thermally coupled to the heat exchanger. The first and second coolant loops are configured to carry distinct thermal energy transfer media. The thermal management system also includes an interface configured to facilitate transfer of heat generated by an internal combustion engine to the heat exchanger via the second coolant loop in order to selectively deliver the heat to the electrochemical storage device. Thermal management methods are also provided.

  8. RAPID/Roadmap/7-CA-a | Open Energy Information

    Open Energy Info (EERE)

    and other non-thermal plants are under local city or county jurisdiction. Concentrated solar power plants are considered thermal and are under CEC jurisdiction. Cal. Pub. Res....

  9. PyTrilinos Rapid Prototyping Package

    Energy Science and Technology Software Center (OSTI)

    2005-03-01

    PyTrilinos provides access to selected Trilinos packages from the python scripting language. This allows interactive and dynamic creation of Trilinos objects, rapid prototyping that does not require compilation, and "gluing" Trilinos scripts to other python modules, such as plotting, etc. The currently supported packages are Epetra, EpetraExt, and NOX.

  10. High precision, rapid laser hole drilling

    DOE Patents [OSTI]

    Chang, Jim J.; Friedman, Herbert W.; Comaskey, Brian J.

    2005-03-08

    A laser system produces a first laser beam for rapidly removing the bulk of material in an area to form a ragged hole. The laser system produces a second laser beam for accurately cleaning up the ragged hole so that the final hole has dimensions of high precision.

  11. High precision, rapid laser hole drilling

    DOE Patents [OSTI]

    Chang, Jim J.; Friedman, Herbert W.; Comaskey, Brian J.

    2013-04-02

    A laser system produces a first laser beam for rapidly removing the bulk of material in an area to form a ragged hole. The laser system produces a second laser beam for accurately cleaning up the ragged hole so that the final hole has dimensions of high precision.

  12. High precision, rapid laser hole drilling

    DOE Patents [OSTI]

    Chang, Jim J.; Friedman, Herbert W.; Comaskey, Brian J.

    2007-03-20

    A laser system produces a first laser beam for rapidly removing the bulk of material in an area to form a ragged hole. The laser system produces a second laser beam for accurately cleaning up the ragged hole so that the final hole has dimensions of high precision.

  13. Rapid Laser Induced Crystallization of Amorphous NiTi Films Observed by Nanosecond Dynamic Transmission Electron Microscopy (DTEM)

    SciTech Connect (OSTI)

    LaGrange, T; Campbell, G H; Browning, N D; Reed, B W; Grummon, D S

    2010-03-01

    The crystallization processes of the as-deposited, amorphous NiTi thin films have been studied in detail using techniques such as differential scanning calorimetry and, in-situ TEM. The kinetic data have been analyzed in terms of Johnson-Mehl-Avrami-Kolomogrov (JMAK) semi-empirical formula. The kinetic parameters determined from this analysis have been useful in defining process control parameters for tailoring microstructural features and shape memory properties. Due to the commercial push to shrink thin film-based devices, unique processing techniques have been developed using laser-based annealing to spatially control the microstructure evolution down to sub-micron levels. Nanosecond, pulse laser annealing is particularly attractive since it limits the amount of peripheral heating and unwanted microstructural changes to underlying or surrounding material. However, crystallization under pulsed laser irradiation can differ significantly from conventional thermal annealing, e.g., slow heating in a furnace. This is especially true for amorphous NiTi materials and relevant for shape memory thin film based microelectromechanical systems (MEMS) applications. There is little to no data on the crystallization kinetics of NiTi under pulsed laser irradiation, primarily due to the high crystallization rates intrinsic to high temperature annealing and the spatial and temporal resolution limits of standard techniques. However, with the high time and spatial resolution capabilities of the dynamic transmission electron microscope (DTEM) constructed at Lawrence Livermore National Laboratory, the rapid nucleation events occurring from pulsed laser irradiation can be directly observed and nucleation rates can be quantified. This paper briefly explains the DTEM approach and how it used to investigate the pulsed laser induced crystallization processes in NiTi and to determine kinetic parameters.

  14. RAPID RADIOCHEMICAL ANALYSES IN SUPPORT OF FUKUSHIMA NUCLEAR ACCIDENT

    SciTech Connect (OSTI)

    Maxwell, S.

    2012-11-07

    by Sr-Resin separation and gas flow proportional counting. To achieve a lower detection limit for analysis of some of the Japanese soil samples, a 10 gram aliquot of soil was taken, acid-leached and processed with similar preconcentration chemistry. The MDA using this approach was ~0.03 pCi/g (1.1 mBq/g)/, which is less than the 0.05-0.10 pCi/g {sup 90}Sr levels found in soil as a result of global fallout. The chemical yields observed for the Japanese soil samples was typically 75-80% and the laboratory control sample (LCS) and matrix spike (MS) results looked very good for this work Individual QC results were well within the ± 25% acceptable range and the average of these results does not show significant bias. Additional data for a radiostrontium in soil method for 50 gram samples will also be presented, which appears to be a significant step forward based on looking at the current literature, with higher chemical yields for even larger sample aliquots and lower MDA. Hou et al surveyed a wide range of separation methods for Pu in waters and environmental solid samples. While there are many actinide methods in the scientific literature, few would be considered rapid due to the tedious and time-consuming steps involved. For actinide analyses in soil, a new rapid method for the determination of actinide isotopes in soil samples using both alpha spectrometry and inductively-coupled plasma mass spectrometry was employed. The new rapid soil method utilizes an acid leaching method, iron/titanium hydroxide precipitation, a lanthanum fluoride soil matrix removal step, and a rapid column separation process with TEVA Resin. The large soil matrix is removed easily and rapidly using these two simple precipitations with high chemical recoveries and effective removal of interferences. Vacuum box technology and rapid flow rates were used to reduce analytical time. Challenges associated with the mineral content in the volcanic soil will be discussed. Air filter samples were

  15. Rapid Radiochemical Analyses in Support of Fukushima Nuclear Accident - 13196

    SciTech Connect (OSTI)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2013-07-01

    precipitations, followed by Sr-Resin separation and gas flow proportional counting. To achieve a lower detection limit for analysis of some of the Japanese soil samples, a 10 gram aliquot of soil was taken, acid-leached and processed with similar preconcentration chemistry. The MDA using this approach was ∼0.03 pCi/g (1.1 mBq/g)/, which is less than the 0.05-0.10 pCi/g {sup 90}Sr levels found in soil as a result of global fallout. The chemical yields observed for the Japanese soil samples was typically 75-80% and the laboratory control sample (LCS) and matrix spike (MS) results looked very good for this work Individual QC results were well within the ± 25% acceptable range and the average of these results does not show significant bias. Additional data for a radiostrontium in soil method for 50 gram samples will also be presented, which appears to be a significant step forward based on looking at the current literature, with higher chemical yields for even larger sample aliquots and lower MDA [5, 6, 7] Hou et al surveyed a wide range of separation methods for Pu in waters and environmental solid samples [8]. While there are many actinide methods in the scientific literature, few would be considered rapid due to the tedious and time-consuming steps involved. For actinide analyses in soil, a new rapid method for the determination of actinide isotopes in soil samples using both alpha spectrometry and inductively-coupled plasma mass spectrometry was employed. The new rapid soil method utilizes an acid leaching method, iron/titanium hydroxide precipitation, a lanthanum fluoride soil matrix removal step, and a rapid column separation process with TEVA Resin. The large soil matrix is removed easily and rapidly using these two simple precipitations with high chemical recoveries and effective removal of interferences. [9, 10] Vacuum box technology and rapid flow rates were used to reduce analytical time. Challenges associated with the mineral content in the volcanic soil will be

  16. RAPID/Roadmap/4-FD-b | Open Energy Information

    Open Energy Info (EERE)

    FD-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  17. RAPID/BulkTransmission/General Construction | Open Energy Information

    Open Energy Info (EERE)

    RAPIDBulkTransmissionGeneral Construction < RAPID | BulkTransmission Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk...

  18. Rapid Assessment of City Emissions (RACE): Case of Batangas City...

    Open Energy Info (EERE)

    Rapid Assessment of City Emissions (RACE): Case of Batangas City, Philippines Jump to: navigation, search Tool Summary Name: Rapid Assessment of City Emissions (RACE): Case of...

  19. Rapid Software Prototyping Into Large Scale Control Systems ...

    Office of Scientific and Technical Information (OSTI)

    Rapid Software Prototyping Into Large Scale Control Systems Citation Details In-Document Search Title: Rapid Software Prototyping Into Large Scale Control Systems Authors: Fishler, ...

  20. RAPID/Roadmap/7-FD-s | Open Energy Information

    Open Energy Info (EERE)

    7-FD-s < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  1. RAPID/Roadmap/8-NM-b | Open Energy Information

    Open Energy Info (EERE)

    b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  2. RAPID/Geothermal/Air Quality/Alaska | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalAir QualityAlaska < RAPID | Geothermal | Air Quality Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk...

  3. RAPID/Geothermal/Air Quality | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalAir Quality < RAPID | Geothermal Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  4. RAPID/BulkTransmission/Air Quality | Open Energy Information

    Open Energy Info (EERE)

    BulkTransmissionAir Quality < RAPID | BulkTransmission Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission...

  5. RAPID/Geothermal/Air Quality/Alaska | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalAir QualityAlaska < RAPID | Geothermal | Air Quality(Redirected from RAPIDOverviewGeothermalAir QualityAlaska) Jump to: navigation, search RAPID...

  6. RAPID/Solar/Land Access | Open Energy Information

    Open Energy Info (EERE)

    RAPIDSolarLand Access < RAPID | Solar(Redirected from RAPIDSolarLeasing) Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About...

  7. RAPID/Solar/Environment/California | Open Energy Information

    Open Energy Info (EERE)

    SolarEnvironmentCalifornia < RAPID | Solar | Environment Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk...

  8. RAPID/Roadmap/1-FD-a | Open Energy Information

    Open Energy Info (EERE)

    Roadmap1-FD-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar...

  9. RAPID/Roadmap/8 (1) | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap8 (1) < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  10. RAPID/Roadmap/3-HI-e | Open Energy Information

    Open Energy Info (EERE)

    HI-e < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  11. RAPID/Roadmap/8-UT-c | Open Energy Information

    Open Energy Info (EERE)

    UT-c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  12. RAPID/Roadmap/6 (1) | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap6 (1) < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  13. RAPID/Roadmap/6-CO-a | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap6-CO-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  14. RAPID/Roadmap/8-ID-e | Open Energy Information

    Open Energy Info (EERE)

    ID-e < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  15. RAPID/Roadmap/3-ID-c | Open Energy Information

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    c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  16. RAPID/Roadmap/18 (1) | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap18 (1) < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  17. RAPID/Roadmap/3-TX-c | Open Energy Information

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    c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  18. RAPID/Roadmap/3-WA-e | Open Energy Information

    Open Energy Info (EERE)

    e < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  19. RAPID/Roadmap/7-CA-f | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap7-CA-f < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  20. RAPID/Roadmap/1-FD-b | Open Energy Information

    Open Energy Info (EERE)

    FD-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  1. RAPID/Roadmap/11-FD-c | Open Energy Information

    Open Energy Info (EERE)

    FD-c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  2. RAPID/Roadmap/1-MT-a | Open Energy Information

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    RAPIDRoadmap1-MT-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  3. RAPID/Roadmap/19-CA-e | Open Energy Information

    Open Energy Info (EERE)

    e < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  4. RAPID/Roadmap/7-NV-c | Open Energy Information

    Open Energy Info (EERE)

    NV-c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  5. RAPID/Roadmap/3-CO-b | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap3-CO-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  6. RAPID/Roadmap/3-NV-e | Open Energy Information

    Open Energy Info (EERE)

    NV-e < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  7. RAPID/Roadmap/8-NV-c | Open Energy Information

    Open Energy Info (EERE)

    c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  8. RAPID/Roadmap/19-VT-a | Open Energy Information

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    RAPIDRoadmap19-VT-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  9. RAPID/Roadmap/7-NM-c | Open Energy Information

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    NM-c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  10. RAPID/Roadmap/14-AK-b | Open Energy Information

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    RAPIDRoadmap14-AK-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  11. RAPID/Roadmap/13-FD-g | Open Energy Information

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  12. RAPID/Roadmap/1 (3) | Open Energy Information

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    RAPIDRoadmap1 (3) < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  13. RAPID/Roadmap/6-NV-b | Open Energy Information

    Open Energy Info (EERE)

    NV-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  14. RAPID/Roadmap/18-CA-b | Open Energy Information

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    RAPIDRoadmap18-CA-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  15. RAPID/Roadmap/3-FD-e | Open Energy Information

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    RAPIDRoadmap3-FD-e < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  16. RAPID/Roadmap/3-AK-a | Open Energy Information

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    RAPIDRoadmap3-AK-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  17. RAPID/Roadmap/7-VT-a | Open Energy Information

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    RAPIDRoadmap7-VT-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  18. RAPID/Roadmap/13-FD-b | Open Energy Information

    Open Energy Info (EERE)

    FD-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  19. RAPID/Roadmap/7-FD-e | Open Energy Information

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    Help Apps Datasets Community Login | Sign Up Search Page Edit with form History RAPIDRoadmap7-FD-e < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and...

  20. RAPID/Roadmap/14-NM-b | Open Energy Information

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    Roadmap14-NM-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...