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1

Raman gas analyzer for determining the composition of natural gas  

Science Journals Connector (OSTI)

We describe a prototype of a Raman gas analyzer designed for measuring the composition of natural gas. Operation of the gas analyzer was tested on a real natural gas. We show that our Raman gas analyzer prototype...

M. A. Buldakov; B. V. Korolev; I. I. Matrosov…

2013-03-01T23:59:59.000Z

2

Real-TIme Raman Gas Composition Analyzer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analyzer Analyzer Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking collaborative research partners interested in implementing United States Provisional Patent Application entitled "Gas Sensing System Employing Raman Scattering". Disclosed in this application is a gas analyzing sensor that characterizes gaseous fuel, exhaust gases, or other process gas streams. The sensor reports concentrations of all majority gases at better than 0.3% accuracy in 1 second or less, and can be used for real-time gas analysis and system control. The sensor relies on novel techniques to enhance usually weak spontaneous Raman emissions from sample gases, enabling the application of Raman spectroscopy to rapid gas analysis. No commercially available sensor or sensing

3

Real-Time Raman Gas Composition Sensor.pdf  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sensor Sensor Opportunity Technology/Capability Overview Benefits to Partner Development Status Contact The NETL Real-time Raman Gas Composition Analyzer determines the composition of a flowing gaseous sample in real-time and provides the concentration of each gas in that sample. . . . ‡ Testing partners would have the opportunity to evaluate the performance of the prototype system, implement new feed-forward controls, and may help shape the commercial product configuration ‡ This sensor will greatly benefit the power industry, as well as other industries utilizing gaseous input or output streams by enabling smarter control to increase process efficiency and reduce emissions ‡ We are seeking opportunities to field test the prototype instruments in power and industrial applications, as well

4

Competition between stimulated Raman and Brillouin scattering processes in CF4 gas  

Science Journals Connector (OSTI)

CF4 gas has a relatively high Raman cross section and a relatively small Raman shift and is an excellent candidate for a gas-filled hollow-core photonic bandgap (HC-PBG)...

Yehud, Lior Ben; Belker, Daniel; Ravnitzki, Gad; Ishaaya, Amiel A

2014-01-01T23:59:59.000Z

5

Characterization of Gas Shales by X-ray Raman Spectroscopy | Stanford  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of Gas Shales by X-ray Raman Spectroscopy Characterization of Gas Shales by X-ray Raman Spectroscopy Thursday, February 23, 2012 - 10:30am SSRL Third Floor Conference Room 137-322 Drew Pomerantz, Schlumberger Unconventional hydrocarbon resources such as gas shale and oil-bearing shale have emerged recently as economically viable sources of energy, dramatically altering America's energy landscape. Despite their importance, the basic chemistry and physics of shales are not understood as well as conventional reservoirs. In particular, shales are unique in that they contain kerogen, a complex organic solid that controls factors such as the amount of hydrocarbon that can be produced from the reservoir and the rate at which the hydrocarbon is produced. The industry's current understanding of the chemical composition of kerogen is limited, preventing detailed

6

Characterization of Gas Shales by X-ray Raman Spectroscopy | Stanford  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of Gas Shales by X-ray Raman Spectroscopy Characterization of Gas Shales by X-ray Raman Spectroscopy Monday, May 14, 2012 - 3:30pm SSRL Conference Room 137-322 Drew Pomerantz, Schlumberger Unconventional hydrocarbon resources such as gas shale and oil-bearing shale have emerged recently as economically viable sources of energy, dramatically altering America's energy landscape. Despite their importance, the basic chemistry and physics of shales are not understood as well as conventional reservoirs. In particular, shales are unique in that they contain kerogen, a complex organic solid that controls factors such as the amount of hydrocarbon that can be produced from the reservoir and the rate at which the hydrocarbon is produced. The industry's current understanding of the chemical composition of kerogen is limited, preventing detailed

7

Micro-Raman Spectroscopy of Algae: Composition Analysis and Fluorescence Background Behavior  

E-Print Network [OSTI]

analysis; biodiesel Introduction To date, analysis of algae composition is a multi-staged processARTICLE Micro-Raman Spectroscopy of Algae: Composition Analysis and Fluorescence Background performed using Stokes Raman scattering for compositional analysis of algae. Two algal species, Chlorella

8

Composition for absorbing hydrogen from gas mixtures  

DOE Patents [OSTI]

A hydrogen storage composition is provided which defines a physical sol-gel matrix having an average pore size of less than 3.5 angstroms which effectively excludes gaseous metal hydride poisons while permitting hydrogen gas to enter. The composition is useful for separating hydrogen gas from diverse gas streams which may have contaminants that would otherwise render the hydrogen absorbing material inactive.

Heung, Leung K. (Aiken, SC); Wicks, George G. (Aiken, SC); Lee, Myung W. (Aiken, SC)

1999-01-01T23:59:59.000Z

9

Hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering for gas-phase temperature measurements.  

E-Print Network [OSTI]

??Hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering (fs/ps CARS) is employed for quantitative gas-phase temperature measurements in combustion processes and heated flows. In this approach, ultrafast… (more)

Miller, Joseph Daniel

2012-01-01T23:59:59.000Z

10

Measurement of Gas Hydrate by Laser Raman Spectrometry  

Science Journals Connector (OSTI)

Four types of natural sand (respectively 250–350, 180–250, 125 ... ) are used as media to synthesize methane hydrate that is measured by laser Raman spectrometry. ... show that sediment grain sizes do not influen...

Changling Liu; Qingguo Meng; Yuguang Ye

2013-01-01T23:59:59.000Z

11

Method for designing gas tag compositions  

DOE Patents [OSTI]

For use in the manufacture of gas tags such as employed in a nuclear reactor gas tagging failure detection system, a method for designing gas tagging compositions utilizes an analytical approach wherein the final composition of a first canister of tag gas as measured by a mass spectrometer is designated as node No. 1. Lattice locations of tag nodes in multi-dimensional space are then used in calculating the compositions of a node No. 2 and each subsequent node so as to maximize the distance of each node from any combination of tag components which might be indistinguishable from another tag composition in a reactor fuel assembly. Alternatively, the measured compositions of tag gas numbers 1 and 2 may be used to fix the locations of nodes 1 and 2, with the locations of nodes 3-N then calculated for optimum tag gas composition. A single sphere defining the lattice locations of the tag nodes may be used to define approximately 20 tag nodes, while concentric spheres can extend the number of tag nodes to several hundred. 5 figures.

Gross, K.C.

1995-04-11T23:59:59.000Z

12

Method for designing gas tag compositions  

DOE Patents [OSTI]

For use in the manufacture of gas tags such as employed in a nuclear reactor gas tagging failure detection system, a method for designing gas tagging compositions utilizes an analytical approach wherein the final composition of a first canister of tag gas as measured by a mass spectrometer is designated as node #1. Lattice locations of tag nodes in multi-dimensional space are then used in calculating the compositions of a node #2 and each subsequent node so as to maximize the distance of each node from any combination of tag components which might be indistinguishable from another tag composition in a reactor fuel assembly. Alternatively, the measured compositions of tag gas numbers 1 and 2 may be used to fix the locations of nodes 1 and 2, with the locations of nodes 3-N then calculated for optimum tag gas composition. A single sphere defining the lattice locations of the tag nodes may be used to define approximately 20 tag nodes, while concentric spheres can extend the number of tag nodes to several hundred.

Gross, Kenny C. (1433 Carriage La., Bolingbrook, IL 60440)

1995-01-01T23:59:59.000Z

13

Coupling of a two phase gas liquid compositional 3D Darcy flow with a 1D compositional free gas  

E-Print Network [OSTI]

Coupling of a two phase gas liquid compositional 3D Darcy flow with a 1D compositional free gas. Masson1 , L. Trenty2 , Y. Zhang1 Coupling of a two phase gas liquid compositional 3D Darcy flow #12 analysis K, Brenner1 , R. Masson1 , L. Trenty2 , Y. Zhang1 Coupling of a two phase gas liquid compositional

Ribot, Magali

14

Combined raman and IR fiber-based sensor for gas detection  

DOE Patents [OSTI]

A double-pass fiber-optic based spectroscopic gas sensor delivers Raman excitation light and infrared light to a hollow structure, such as a hollow fiber waveguide, that contains a gas sample of interest. A retro-reflector is placed at the end of this hollow structure to send the light back through the waveguide where the light is detected at the same end as the light source. This double pass retro reflector design increases the interaction path length of the light and the gas sample, and also reduces the form factor of the hollow structure.

Carter, Jerry C; Chan, James W; Trebes, James E; Angel, Stanley M; Mizaikoff, Boris

2014-06-24T23:59:59.000Z

15

Raman-dressed spin-1 spin-orbit-coupled quantum gas  

Science Journals Connector (OSTI)

The recently realized spin-orbit-coupled quantum gases [Lin et al., Nature (London) 471, 83 (2011); Wang et al., Phys. Rev. Lett. 109, 095301 (2012); Cheuk et al., Phys. Rev. Lett. 109, 095302 (2012)] mark a breakthrough in the cold atom community. In these experiments, two hyperfine states are selected from a hyperfine manifold to mimic a pseudospin-1/2 spin-orbit-coupled system by the method of Raman dressing, which is applicable to both bosonic and fermionic gases. In this paper, we show that the method used in these experiments can be generalized to create any large pseudospin spin-orbit-coupled gas if more hyperfine states are coupled equally by the Raman lasers. As an example, we study, in detail, a quantum gas with three hyperfine states coupled by the Raman lasers and show, when the state-dependent energy shifts of the three states are comparable, triple-degenerate minima will appear at the bottom of the band dispersions, thus, realizing a spin-1 spin-orbit-coupled quantum gas. A novel feature of this three-minima regime is that there can be two different kinds of stripe phases with different wavelengths, which has an interesting connection to the ferromagnetic and polar phases of spin-1 spinor Bose-Einstein condensates without spin-orbit coupling.

Zhihao Lan and Patrik Öhberg

2014-02-24T23:59:59.000Z

16

Apparatus for gas sorption measurement with integrated gas composition measurement device and gas mixing  

SciTech Connect (OSTI)

An apparatus for testing of multiple material samples includes a gas delivery control system operatively connectable to the multiple material samples and configured to provide gas to the multiple material samples. Both a gas composition measurement device and pressure measurement devices are included in the apparatus. The apparatus includes multiple selectively openable and closable valves and a series of conduits configured to selectively connect the multiple material samples individually to the gas composition device and the pressure measurement devices by operation of the valves. A mixing system is selectively connectable to the series of conduits and is operable to cause forced mixing of the gas within the series of conduits to achieve a predetermined uniformity of gas composition within the series of conduits and passages.

Micklash. II, Kenneth James; Dutton, Justin James; Kaye, Steven

2014-06-03T23:59:59.000Z

17

Variations in dissolved gas compositions of reservoir fluids...  

Open Energy Info (EERE)

A. E.; Copp, J. F. . 111991. Variations in dissolved gas compositions of reservoir fluids from the Coso geothermal field. Proceedings of () ; () : Sixteenth workshop on...

18

58 IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT, VOL. 53, NO. 1, FEBRUARY 2004 Multichannel Raman Gas Analyzer: The Data  

E-Print Network [OSTI]

with the green laser source previously used and reported in a related article. Index Terms--Air-pollution, data Raman Gas Analyzer: The Data Acquisition and Control System. Measurement Improvement With Blue Laser Albrecht, and Nikiforos G. Theofanous Abstract--In this paper, the data acquisition and control system

Athens, University of

19

Effects of gas composition on the performance and emissions of compressed natural gas engines  

Science Journals Connector (OSTI)

Natural gas is considered to be a promising alternative ... energy security. However, since the composition of natural gas fuel varies with location, climate and other ... emission characteristics and performance...

Byung Hyouk Min; Jin Taek Chung; Ho Young Kim; Simsoo Park

2002-02-01T23:59:59.000Z

20

Crystallinity and compositional changes in carbonated apatites: Evidence from {sup 31}P solid-state NMR, Raman, and AFM analysis  

SciTech Connect (OSTI)

Solid-state (magic-angle spinning) NMR spectroscopy is a useful tool for obtaining structural information on bone organic and mineral components and synthetic model minerals at the atomic-level. Raman and {sup 31}P NMR spectral parameters were investigated in a series of synthetic B-type carbonated apatites (CAps). Inverse {sup 31}P NMR linewidth and inverse Raman PO{sub 4}{sup 3?}?{sub 1} bandwidth were both correlated with powder XRD c-axis crystallinity over the 0.3–10.3 wt% CO{sub 3}{sup 2?} range investigated. Comparison with bone powder crystallinities showed agreement with values predicted by NMR and Raman calibration curves. Carbonate content was divided into two domains by the {sup 31}P NMR chemical shift frequency and the Raman phosphate ?{sub 1} band position. These parameters remain stable except for an abrupt transition at 6.5 wt% carbonate, a composition which corresponds to an average of one carbonate per unit cell. This near-binary distribution of spectroscopic properties was also found in AFM-measured particle sizes and Ca/P molar ratios by elemental analysis. We propose that this transition differentiates between two charge-balancing ion-loss mechanisms as measured by Ca/P ratios. These results define a criterion for spectroscopic characterization of B-type carbonate substitution in apatitic minerals. - Graphical abstract: Carbonated apatite shows an abrupt change in spectral (NMR, Raman) and morphological (AFM) properties at a composition of about one carbonate substitution per unit cell. Display Omitted - Highlights: • Crystallinity (XRD), particle size (AFM) of carbonated apatites and bone mineral. • Linear relationships among crystallinity, {sup 31}P NMR and Raman inverse bandwidths. • Low and high carbonated apatites use different charge-balancing ion-loss mechanism.

McElderry, John-David P.; Zhu, Peizhi [Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Mroue, Kamal H. [Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Department of Biophysics, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Xu, Jiadi [Department of Biophysics, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Pavan, Barbara [Department of Chemistry and Science of Advanced Materials Program, Central Michigan University, Mt. Pleasant, MI 48859 (United States); Fang, Ming [Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Zhao, Guisheng; McNerny, Erin; Kohn, David H.; Franceschi, Renny T. [School of Dentistry, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Holl, Mark M.Banaszak [Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Tecklenburg, Mary M.J., E-mail: mary.tecklenburg@cmich.edu [Department of Chemistry and Science of Advanced Materials Program, Central Michigan University, Mt. Pleasant, MI 48859 (United States); Ramamoorthy, Ayyalusamy [Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Department of Biophysics, University of Michigan, Ann Arbor, MI 48109-1055 (United States); Morris, Michael D. [Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055 (United States)

2013-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Effect of Natural Gas Composition on the Design of Natural Gas Liquid Demethanizers  

Science Journals Connector (OSTI)

Effect of Natural Gas Composition on the Design of Natural Gas Liquid Demethanizers ... The hydrocarbon composition of natural gas varies fairly significantly from location to location. ... The relative amounts of methane (C1) and ethane (C2) have a profound effect on the cryogenic high-pressure distillation column used to recover the C2 and heavier components as a bottoms product called “natural gas liquid” (NGL). ...

William L. Luyben

2013-04-17T23:59:59.000Z

22

Characterization of Woody and Herbaceous Biomasses Lignin Composition with 1064 nm Dispersive Multichannel Raman Spectroscopy  

Science Journals Connector (OSTI)

Biomass representing different classes of bioenergy feedstocks, including woody and herbaceous species, was measured with 1064 nm Raman spectroscopy. Pine, oak, poplar, kenaf,...

Lupoi, Jason S; Smith, Emily A

2012-01-01T23:59:59.000Z

23

Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal  

Open Energy Info (EERE)

Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal System- A Case Study Of The Geysers Geothermal Field, Usa Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal System- A Case Study Of The Geysers Geothermal Field, Usa Details Activities (1) Areas (1) Regions (0) Abstract: Hydrothermal alteration and the active vapor-dominated geothermal system at The Geysers, CA are related to a composite hypabyssal granitic pluton emplaced beneath the field 1.1 to 1.2 million years ago. Deep drill holes provide a complete transect across the thermal system and samples of the modern-day steam. The hydrothermal system was liquid-dominated prior to formation of the modern vapor-dominated regime at 0.25 to 0.28 Ma. Maximum

24

Defect Analysis of Vehicle Compressed Natural Gas Composite Cylinder  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Defect Analysis of Vehicle Defect Analysis of Vehicle Compressed Natural Gas Composite Cylinder A China Paper on Type 4 Cylinder, translated and presented by J. P. Hsu, PhD, Smart Chemistry Reason for Defect Analysis of CNG Composite Cylinder * Safety Issue - Four explosion accidents of auto used CNG composite material cylinders resulting huge personnel and vehicles loss. * Low Compliance Rate - Inspect 12119 Auto used CNG composite cylinders and only 3868 are qualified with compliance rate of 32%. Plastic CNG Composite Cylinder Process Fitting Internal Plastic Liner External Composite Layer Metal Fitting HDPE Cylinder Liner * HDPE has a high density, great stiffness, good anti-permeability and high melting point, but poor environmental stress cracking Resistance (ESCR). * The defects of cylinder liner quality can be

25

From Gas Lasers and Tunable Raman Lasers to Quantum Cascade Lasers  

Science Journals Connector (OSTI)

I will describe my involvement in lasers from 1961 to the present, ecompassing high power carbon dioxide lasers, tunable spin-flip Raman lasers, and now high power CW room temperature...

Patel, Kumar

26

CuAl{sub 2} revisited: Composition, crystal structure, chemical bonding, compressibility and Raman spectroscopy  

SciTech Connect (OSTI)

The structure of CuAl{sub 2} is usually described as a framework of base condensed tetragonal antiprisms [CuAl{sub 8/4}]. The appropriate symmetry governed periodic nodal surface (PNS) divides the space of the structure into two labyrinths. All atoms are located in one labyrinth, whereas the second labyrinth seems to be 'empty'. The bonding of the CuAl{sub 2} structure was analyzed by the electron localization function (ELF), crystal orbital Hamiltonian population (COHP) analysis and Raman spectroscopy. From the ELF representation it is seen, that the 'empty' labyrinth is in fact the place of important covalent interactions. ELF, COHP in combination with high-pressure X-ray diffraction and Raman spectroscopy show that the CuAl{sub 2} structure is described best as a network built of interpenetrating graphite-like nets of three-bonded aluminum atoms with the copper atoms inside the tetragonal-antiprismatic cavities. - Graphical abstract: Atomic interactions in the crystal structure of the intermetallic compound CuAl{sub 2}: Three-bonded aluminum atoms form interpenetrating graphite-like nets. The copper atoms are located in the channels of aluminum network by means of three-center bonds. The bonding model is in agreement with the result of polarized Raman spectroscopy and high-pressure X-ray powder diffraction.

Grin, Yuri [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany)]. E-mail: grin@cpfs.mpg.de; Wagner, Frank R. [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Armbruester, Marc [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Kohout, Miroslav [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Leithe-Jasper, Andreas [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Schwarz, Ulrich [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Wedig, Ulrich [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, 70569 Stuttgart (Germany); Georg von Schnering, Hans [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, 70569 Stuttgart (Germany)

2006-06-15T23:59:59.000Z

27

Melt Infiltrated Ceramic Composites (Hipercomp) for Gas Turbine Engine Applications  

SciTech Connect (OSTI)

This report covers work performed under the Continuous Fiber Ceramic Composites (CFCC) program by GE Global Research and its partners from 1994 through 2005. The processing of prepreg-derived, melt infiltrated (MI) composite systems based on monofilament and multifilament tow SiC fibers is described. Extensive mechanical and environmental exposure characterizations were performed on these systems, as well as on competing Ceramic Matrix Composite (CMC) systems. Although current monofilament SiC fibers have inherent oxidative stability limitations due to their carbon surface coatings, the MI CMC system based on multifilament tow (Hi-Nicalon ) proved to have excellent mechanical, thermal and time-dependent properties. The materials database generated from the material testing was used to design turbine hot gas path components, namely the shroud and combustor liner, utilizing the CMC materials. The feasibility of using such MI CMC materials in gas turbine engines was demonstrated via combustion rig testing of turbine shrouds and combustor liners, and through field engine tests of shrouds in a 2MW engine for >1000 hours. A unique combustion test facility was also developed that allowed coupons of the CMC materials to be exposed to high-pressure, high-velocity combustion gas environments for times up to {approx}4000 hours.

Gregory Corman; Krishan Luthra

2005-09-30T23:59:59.000Z

28

Acid gas scrubbing by composite solvent-swollen membranes  

DOE Patents [OSTI]

A composite immobilized liquid membrane suitable for acid gas scrubbing is disclosed. The membrane is a solvent-swollen polymer and a microporous polymeric support, the solvent being selected from a class of highly polar solvents containing at least one atom selected from nitrogen, oxygen, phosphorus and sulfur, and having a boiling point of at least 100 C and a solubility parameter of from about 7.5 to about 13.5 (cal/cm[sup 3]-atm)[sup 1/2]. Such solvents are homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. Also disclosed are methods of acid gas scrubbing of high- and low-Btu gas effluents with such solvent-swollen membranes. 3 figs.

Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

1988-04-12T23:59:59.000Z

29

Acid gas scrubbing by composite solvent-swollen membranes  

DOE Patents [OSTI]

A composite immobilized liquid membrane suitable for acid gas scrubbing is disclosed. The membrane is a solvent-swollen polymer and a microporous polymeric support, the solvent being selected from a class of highly polar solvents containing at least one atom selected from nitrogen, oxygen, phosphorous and sulfur, and having a boiling point of at least 100.degree. C. and a solubility parameter of from about 7.5 to about 13.5 (cal/cm.sup.3 -atm).sup.1/2. Such solvents are homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. Also disclosed are methods of acid gas scrubbing of high- and low-Btu gas effluents with such solvent-swollen membranes.

Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

1988-01-01T23:59:59.000Z

30

Ni(NiO)/single-walled carbon nanotubes composite: Synthesis of electro-deposition, gas sensing property for NO gas and density functional theory calculation  

SciTech Connect (OSTI)

Graphical abstract: The Ni(NiO)/semiconducting single-walled carbon nanotubes composite collected from the cathode after electro-deposition shows a high sensitivity to low-concentration NO gas at room temperature (18 °C). Display Omitted Highlights: ? Ni(NiO) nanoparticles were deposited on semiconducting SWCNTs by electro-deposition. ? Ni(NiO)/semiconducting SWCNTs film shows a high sensitivity to NO gas at 18 °C. ?Theoretical calculation reveals electron transfer from SWCNTs to NO via Ni. -- Abstract: Single-walled carbon nanotubes which contains metallic SWCNTs (m-SWCNTs) and semiconducting SWCNTs (s-SWCNTs) have been obtained under electric arc discharge. Their separation can be effectively achieved by the electro-deposition method. The Ni(NiO)/s-SWCNTs composite was found on cathode where Ni was partially oxidized to NiO at ambient condition with Ni(NiO) nanoparticles deposited uniformly on the bundles of SWCNTs. These results were confirmed by Raman spectra, transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV–vis–NIR and TG characterizations. Furthermore, investigation of the gas sensing property of Ni(NiO)/s-SWCNTs composite film to NO gas at 18 °C demonstrated the sensitivity was approximately 5% at the concentration of 97 ppb. Moreover, density functional theory (DFT) calculations were performed to explore the sensing mechanism which suggested the adsorption of NO molecules onto the composite through N–Ni interaction as well as the proposition of electron transfer mechanisms from SWCNTs to NO via the Ni medium.

Li, Li; Zhang, Guo; Chen, Lei [Key Laboratory of Chemical Engineering Process and Technology for High-efficiency Conversion, College of Heilongjiang Province, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Chemical Engineering Process and Technology for High-efficiency Conversion, College of Heilongjiang Province, Heilongjiang University, Harbin 150080 (China); Bi, Hong-Mei [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China); Shi, Ke-Ying, E-mail: shikeying2008@yahoo.cn [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)

2013-02-15T23:59:59.000Z

31

Determination of saccharides and ethanol from biomass conversion using Raman spectroscopy: Effects of pretreatment and enzyme composition  

SciTech Connect (OSTI)

This dissertation focuses on the development of facile and rapid quantitative Raman spectroscopy measurements for the determination of conversion products in producing bioethanol from corn stover. Raman spectroscopy was chosen to determine glucose, xylose and ethanol in complex hydrolysis and fermentation matrices. Chapter 1 describes the motives and main goals of this work, and includes an introduction to biomass, commonly used pretreatment methods, hydrolysis and fermentation reactions. The principles of Raman spectroscopy, its advantages and applications related to biomass analysis are also illustrated. Chapter 2 and 3 comprise two published or submitted manuscripts, and the thesis concludes with an appendix. In Chapter 2, a Raman spectroscopic protocol is described to study the efficiency of enzymatic hydrolysis of cellulose by measuring the main product in hydrolysate, glucose. Two commonly utilized pretreatment methods were investigated in order to understand their effect on glucose measurements by Raman spectroscopy. Second, a similar method was set up to determine the concentration of ethanol in fermentation broth. Both of these measurements are challenged by the presence of complex matrices. In Chapter 3, a quantitative comparison of pretreatment protocols and the effect of enzyme composition are studied using systematic methods. A multipeak fitting algorithm was developed to analyze spectra of hydrolysate containing two analytes: glucose and xylose. Chapter 4 concludes with a future perspective of this research area. An appendix describes a convenient, rapid spectrophotometric method developed to measure cadmium in water. This method requires relatively low cost instrumentation and can be used in microgravity, such as space shuttles or the International Space Station. This work was performed under the supervision of Professor Marc Porter while at Iowa State University. Research related to producing biofuel from bio-renewable resources, especially bioethanol from biomass, has grown significantly in the past decade due to the high demand and rising costs of fossil fuels. More than 3 percent of the energy consumption in the U.S. is derived from renewable biomass, mostly through industrial heat and steam production by the pulp and paper industry, and electricity generation from municipal solid waste (MSW) and forest industry residues. The utilization of food-based biomass to make fuels has been widely criticized because it may increase food shortages throughout the world and raise the cost of food. Thus, nonfood-based and plentiful lignocellulosic feedstocks, such as corn stover, perennial grass, bagasse, sorghum, wheat/rice straw, herbaceous and woody crops, have great potential to be new bio-renewable sources for energy production. Given that many varieties of biomass are available, there is need for a rapid, simple, high-throughput method to screen the conversion of many plant varieties. The most suitable species for each geographic region must be determined, as well as the optimal stage of harvest, impacts of environmental conditions (temperature, soil, pH, etc.). Various genetically modified plants should be studied in order to establish the desired biomass in bioethanol production. The main screening challenge, however, is the complexity of plant cell wall structures that make reliable and sensitive analysis difficult. To date, one of the most popular methods to produce lignocellulosic ethanol is to perform enzymatic hydrolysis followed by fermentation of the hydrolysate with yeast. There are several vital needs related to the field of chemistry that have been suggested as primary research foci needed to effectively improve lignocellulosic ethanol production. These topics include overcoming the recalcitrance of cellulosic biomass, the pervasiveness of pretreatment, advanced biological processing and better feedstocks. In this thesis, a novel approach using Raman spectroscopy has been developed to address important issues related to bioethanol generation, which will aid the research aimed to solve the topics m

Shih, Chien-Ju

2010-05-16T23:59:59.000Z

32

Backward Raman amplification in a partially ionized gas A. A. Balakin,1  

E-Print Network [OSTI]

was accessed 10,11 . The experimental success was achieved using a gas jet of propane, subse- quently ionized of propane opens up the question of coupling in a partially ionized gas. Any additional ionization during

33

Two-beam ultrabroadband coherent anti-Stokes Raman spectroscopy for high resolution gas-phase multiplex imaging  

SciTech Connect (OSTI)

We propose and develop a method for wideband coherent anti-Stokes Raman spectroscopy (CARS) in the gas phase and demonstrate the single-shot measurement of N{sub 2}, H{sub 2}, CO{sub 2}, O{sub 2}, and CH{sub 4}. Pure-rotational and vibrational O-, Q-, and S- branch spectra are collected simultaneously, with high spectral and spatial resolution, and within a single-laser-shot. The relative intensity of the rotational and vibrational signals can be tuned arbitrarily using polarization techniques. The ultrashort 7 fs pump and Stokes pulses are automatically overlapped temporally and spatially using a two-beam CARS technique, and the crossed probe beam allows for excellent spatial sectioning of the probed location.

Bohlin, Alexis; Kliewer, Christopher J., E-mail: cjkliew@sandia.gov [Combustion Research Facility, Sandia National Laboratories, Livermore, California 94550 (United States)

2014-01-20T23:59:59.000Z

34

E ects of the Driving Force on the Composition of Natural Gas Hydrates  

E-Print Network [OSTI]

E ects of the Driving Force on the Composition of Natural Gas Hydrates Odd I. Levik(1) , Jean for storage and transport of natural gas. Storage of natural gas in the form of hydrate at elevated pressure concept) (Gud- mundsson et al. 1998). Natural gas hydrate contains up to 182 Sm3 gas per m3 hydrate

Gudmundsson, Jon Steinar

35

Gas Composition and Oxygen Supply in the Root Environment of Substrates in Closed Hydroponic Systems  

E-Print Network [OSTI]

299 Gas Composition and Oxygen Supply in the Root Environment of Substrates in Closed Hydroponic Abstract The objective of this study was to get more information about the root zone, mainly the gas and ethylene, a gas sampling system was used to get gas samples from the root zone. CO2 gas samples of 20 ml

Lieth, J. Heinrich

36

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

1989-04-25T23:59:59.000Z

37

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

1989-01-01T23:59:59.000Z

38

Modeling of Multilayer Composite Fabrics for Gas Turbine Engine Containment Systems  

E-Print Network [OSTI]

Modeling of Multilayer Composite Fabrics for Gas Turbine Engine Containment Systems J. Sharda1 ; C of multilayer composite fabrics used in a gas turbine engine containment system is developed. Specifically: Tensile strength; Stress analysis; Stress strain relations; Fabrics; Composite materials; Finite element

Mobasher, Barzin

39

Variations in dissolved gas compositions of reservoir fluids from the Coso  

Open Energy Info (EERE)

Variations in dissolved gas compositions of reservoir fluids from the Coso Variations in dissolved gas compositions of reservoir fluids from the Coso geothermal field Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: Variations in dissolved gas compositions of reservoir fluids from the Coso geothermal field Details Activities (1) Areas (1) Regions (0) Abstract: Gas concentrations and ratios in 110 analyses of geothermal fluids from 47 wells in the Coso geothermal system illustrate the complexity of this two-phase reservoir in its natural state. Two geographically distinct regions of single-phase (liquid) reservoir are present and possess distinctive gas and liquid compositions. Relationships in soluble and insoluble gases preclude derivation of these waters from a common parent by boiling or condensation alone. These two regions may

40

Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal...  

Open Energy Info (EERE)

and the active vapor-dominated geothermal system at The Geysers, CA are related to a composite hypabyssal granitic pluton emplaced beneath the field 1.1 to 1.2 million years ago....

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Influence of gas composition on wafer temperature in a tungsten chemical vapor deposition reactor: Experimental measurements, model  

E-Print Network [OSTI]

Influence of gas composition on wafer temperature in a tungsten chemical vapor deposition reactor-wafer, lamp-heated chemical vapor deposition system were used to study the wafer temperature response to gas composition. A physically based simulation procedure for the process gas and wafer temperature was developed

Rubloff, Gary W.

42

Gas-phase detonation propagation in mixture composition gradients  

Science Journals Connector (OSTI)

...unconfined gas detonations in hydrocarbon-air mixtures by a sympathetic...Meeting (International) of the Combustion Institute, Bordeaux, France...and A. Linan1995Effects of heat release on triple flamesPhys...model for partially premixed hydrocarbon combustionCombust. Flame...

2012-01-01T23:59:59.000Z

43

Preparation and characterization of composite membrane for high temperature gas separation  

SciTech Connect (OSTI)

The objective of this project is to develop thin film palladium membranes for separation of hydrogen in high temperature applications. The authors plan to use electroless plating to deposit thin palladium films on microporous ceramic and silver substrates and then characterize the membrane in terms of permeability and selectivity for gas separation. To accomplish the research objective, the project requires three tasks: Development of a process for composite membrane fabrication; Characterization of composite membrane; and Development of theoretical model for hydrogen gas separation. The experimental procedures are described.

Ilias, S.; King, F.G.; Su, N.

1994-10-01T23:59:59.000Z

44

Characterization of Landfill Gas Composition at the Fresh Kills Municipal Solid-Waste Landfill  

Science Journals Connector (OSTI)

Characterization of Landfill Gas Composition at the Fresh Kills Municipal Solid-Waste Landfill ... The most common disposal method in the United States for municipal solid waste (MSW) is burial in landfills. ... Under the New Source Performance Standards and Emission Guidelines for MSW landfills, MSW operators are required to determine the nonmethane organic gas generation rate of their landfill through modeling and/or measurements. ...

Bart Eklund; Eric P. Anderson; Barry L. Walker; Don B. Burrows

1998-06-18T23:59:59.000Z

45

Secondary porosity and permeability of coal vs. gas composition and pressure  

SciTech Connect (OSTI)

We have been investigating the sequestration of atmospheric pollutants by injection into coal seams while at the same time enhancing hydrocarbon productivity by displacement of methane with pollutants. We found that changing the composition of the gas sorbed into the coal changes the porosity and permeability of the coal natural-fracture system owing to gas-content changes, which cause matrix swelling or shrinkage due to relative adsorption of different gases. We collected sufficient information to develop a method for predicting the permeability and porosity of a coalbed as a function of the secondary porosity system (SPS) pressure and the gas content and composition of the primary porosity system (PPS). The method uses data from injection/falloff tests with water and/or a weaker adsorbing gas (WAG) than CH{sub 4} and a stronger adsorbing gas (SAG) than CH{sub 4}. Estimates of effective permeability to gas and water obtained from these tests are used with an iterative computation procedure subject to constraints to solve for equivalent SPS porosity and absolute permeability at atmospheric pressure. Once calibrated, the model can be used to predict a coalbed's permeability and porosity as a function of injection pressure and injected-fluid composition, which in turn are used to predict injection performance. The model is applicable to production forecasts to account for SPS permeability and porosity changes as reservoir pressure declines with changes in gas composition. This paper describes the new model and discusses well-test procedures to obtain the data required for model calibration. Also included are coal property estimates resulting from Alberta Medicine River (Manville) coal core and test data and an example model calibration.

Mavor, M.J,; Gunter, W.D. [Tesseract Corp., San Francisco, CA (United States)

2006-04-15T23:59:59.000Z

46

The influence of fuel composition on the combustion and emission characteristics of natural gas fueled engines  

Science Journals Connector (OSTI)

Abstract As global energy demand rises, natural gas (NG) plays an important strategic role in energy supply. Natural gas is the cleanest fossil fuel that has been investigated extensively for use in spark-ignition (SI) and compression-ignition (CI) engines. This paper reviews the research on the effects of natural gas composition on combustion and emission characteristics of natural gas fueled internal combustion engines (ICEs) and reports the most achievements obtained by researchers in this field. It has been reported that the engine performance and emission are greatly affected by varying compositions of natural gas. The most important NG fuel property is the Wobbe number (WN). Generally, it was agreed by researchers that the fuels with higher hydrocarbons, higher WN, and higher energy content exhibited better fuel economy and carbon dioxide (CO2) emissions. Nitrogen oxides (NOx) emissions were also increased for gases with higher levels of higher WN, while total hydrocarbons (THCs), carbon monoxide (CO), showed some reductions for these gases. On the other hand, particulate matter (PM) emissions did not show any fuel effects. Moreover, adding of small fractions of higher alkanes, such as ethane and propane, significantly improved ignition qualities of natural gas engines. The results presented provide a good insight for researchers to pursue their future research on natural gas fueled ICEs.

Amir-Hasan Kakaee; Amin Paykani; Mostafa Ghajar

2014-01-01T23:59:59.000Z

47

Development of fiberglass composite systems for natural gas pipeline service. Final report, January 1987-March 1994  

SciTech Connect (OSTI)

Fiberglass composites suitable for use in the repair and reinforcement of natural gas transmission line pipe were developed and evaluated. Three types of composite systems were studied: (1) a nonintrusive system for on-line field of corrosion and mechanical damage, (2) line pipe reinforced with filament wound composite, and (3) low-cost systems suitable for over-the-ditch rehabilitation of long pipeline sections. Effort during this program concentrated on the first two areas. A unique fiberglass/polyester device, called Clock Spring, was developed and successfully tested both as a means of terminating rapidly propagating cracks and for on-line repair of metal loss defects. Composite reinforced pipe was produced and hydrotested, and subsequently installed in an operating pipeline to evaluate its long-term behavior in pipeline service.

Fawley, N.C.

1994-03-01T23:59:59.000Z

48

Raman Nanometrology of Graphene  

E-Print Network [OSTI]

13 Optical image of the graphene layers. . . . . .Micro-Raman Spectroscopy of Grapheneand Graphene Multi-Layers . . . . Raman Spectroscopy

Calizo, Irene Gonzales

2009-01-01T23:59:59.000Z

49

Composite wrap approved for U.S. gas-pipeline repairs  

SciTech Connect (OSTI)

The US agency that oversees pipeline safety has taken the unusual step of waiving certain natural-gas pipeline maintenance regulations and permitted a group of gas-pipeline operators to perform repairs with a patented composite wrap formerly used only on liquids lines. The waivers ar subject to conditions and to future performance evaluations. The wrap is made of polyester resin reinforced by glass filament. On installation, it is tightly wound and adhesively bonded to damaged pipe. The paper describes the 2 waivers, the development of this new technology, savings, and training required by the Dept. of Transportation.

True, W.R.

1995-10-09T23:59:59.000Z

50

,"U.S. Natural Gas Liquid Composite Price (Dollars per Million Btu)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","8/2013" Monthly","8/2013" ,"Release Date:","10/31/2013" ,"Next Release Date:","11/29/2013" ,"Excel File Name:","ngm_epg0_plc_nus_dmmbtum.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/ngm_epg0_plc_nus_dmmbtum.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/18/2013 12:22:47 PM" "Back to Contents","Data 1: U.S. Natural Gas Liquid Composite Price (Dollars per Million Btu)" "Sourcekey","NGM_EPG0_PLC_NUS_DMMBTU" "Date","U.S. Natural Gas Liquid Composite Price (Dollars per Million Btu)"

51

,"U.S. Natural Gas Liquid Composite Price (Dollars per Million Btu)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2012 Annual",2012 ,"Release Date:","10/31/2013" ,"Next Release Date:","11/29/2013" ,"Excel File Name:","ngm_epg0_plc_nus_dmmbtua.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/ngm_epg0_plc_nus_dmmbtua.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/18/2013 12:22:46 PM" "Back to Contents","Data 1: U.S. Natural Gas Liquid Composite Price (Dollars per Million Btu)" "Sourcekey","NGM_EPG0_PLC_NUS_DMMBTU" "Date","U.S. Natural Gas Liquid Composite Price (Dollars per Million Btu)"

52

Failure assessment of composite cooler tubes in a gas boosting station  

Science Journals Connector (OSTI)

The present study describes origin and failure mechanisms of air cooled heat exchangers tubes, in a gas pressure boosting station. Hydrocarbon gas was circulating within aluminum finned tubes and cooling was done by forcing ambient air over the exterior of the tubes, made of carbon steel A-214 material. The hydrocarbon gas was contained traces of H2S and substantial level of CO2. The investigation was carried out in a station located in southern part of Iran. The process involved condensation of water and hydrocarbon along the length of tubes, resulting in a wet gas multiphase flow situation. Such type of coolers is also called composite coolers. The failure of tubes was characterized on the bases of all the available evidences and metallurgical examinations, such as analysis of tube materials, feeding gas, condensate water, and the residue inside the tubes. The processing was also simulated by Hysis-3.1 software, in order to evaluate and compare various parameters such as gas flow rate, liquid water and hydrocarbon formation, in actual and design condition. The air cooled tubes showed highest corrosion rate and was experienced leakage regularly. The results indicated that, low velocity assisted sweet corrosion caused severe pitting inside the tubes, and led to failure.

Khalil Ranjbar

2011-01-01T23:59:59.000Z

53

Effects of Natural Recharge on Gas Composition in the Larderello - Castelnuovo Area  

SciTech Connect (OSTI)

A study of the temporal behaviour of gas compsition in the Larderello-Castelnuovo area shows that this behaviour varies, depending on whether the wells are affected or not by natural recharge. Where no natural recharge exists, gas composition seems to be governed by chemical equilibria. The recharge water, and the steam it produces, mix with the fluid already existing in the reservoir. At Larderello (far from absorption areas) the gas composition resulting from this mixing does not undergo further changes by chemical reaction. This is due either to a lack of reactivity where there is no liquid phase or to an ineffective fluid-rock interaction. At Castelnuovo (close to absorption areas) the H{sub 2}S and CH{sub 4} contents in the gas have gradually decreased with the increase in recharge effects. The decrease in H{sub 2}S can be attributed to dissolution in liquid water and oxidation. Various hypotheses have been forwarded for the methane. The correlation existing between CH{sub 4} and N{sub 2} concentrations, even when methane decreases in the areas affected by recharge, suggests that CH{sub 4} may be governed by more than just the Fisher-Tropsch reaction.

D'Amore, Franco; Celati, Romano; Calore, Claudio; Bertrami, Rino

1983-12-15T23:59:59.000Z

54

Multifunctional Nanowire/Film Composites-Based Bimodular Sensors for In Situ, Real-Time High Temperature Gas Detection  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Multifunctional Nanowire/Film Multifunctional Nanowire/Film Composites-Based Bimodular Sensors for In Situ, Real-Time High Temperature Gas Detection Background Real time monitoring of combustion gas composition is important for improving the efficiency of combustion processes and reducing the emission of pollutants. However, such measurement usually requires sensors to be operated at high temperatures in harsh environments. Currently, commercially available sensor technology capable of withstanding such harsh environments is extremely

55

Dependence of the surface topology and raman scattering spectra of Ge{sub x}Si{sub 1-x}/Si films on the composition variation over the layer thickness  

SciTech Connect (OSTI)

The surface topology and Raman scattering spectra of Ge{sub x}Si{sub 1-x}/Si(100) films are investigated in dependence of the composition variation over the film thickness. It is shown that the character of the Ge content variation in the Ge{sub x}Si{sub 1-x} alloy at the constant cumulative Ge fraction in the film (x{sub int} = 0.5) affects the surface morphology of the grown Ge{sub x}Si{sub 1-x}/Si layer. The heterostructures were grown by molecular-beam epitaxy.

Lunin, L. S.; Sysoev, I. A. [Russian Academy of Sciences, Southern Scientific Center (Russian Federation); Bavizhev, M. D.; Lapin, V. A., E-mail: viacheslavlapin@yandex.ru [North Caucasus Federal University (Russian Federation); Kuleshov, D. S.; Malyavin, F. F. [South Russian State Technical University (Russian Federation)

2013-05-15T23:59:59.000Z

56

Composition, preparation, and gas generation results from simulated wastes of Tank 241-SY-101  

SciTech Connect (OSTI)

This document reviews the preparation and composition of simulants that have been developed to mimic the wastes temporarily stored in Tank 241-SY-101 at Hanford. The kinetics and stoichiometry of gases that are generated using these simulants are also compared, considering the roles of hydroxide, chloride, and transition metal ions; the identities of organic constituents; and the effects of dilution, radiation, and temperature. Work described in this report was conducted for the Flammable Gas Safety Program at Pacific Northwest Laboratory, (a) whose purpose is to develop information that is necessary to mitigate potential safety hazards associated with waste tanks at the Hanford Site. The goal of this research and of related efforts at the Georgia Institute of Technology (GIT), Argonne National Laboratory (ANL), and Westinghouse Hanford Company (WHC) is to determine the thermal and thermal/radiolytic mechanisms by which flammable and other gases are produced in Hanford wastes, emphasizing those stored in Tank 241-SY-101. A variety of Tank 241-SY-101 simulants have been developed to date. The use of simulants in laboratory testing activities provides a number of advantages, including elimination of radiological risks to researchers, lower costs associated with experimentation, and the ability to systematically alter simulant compositions to study the chemical mechanisms of reactions responsible for gas generation. The earliest simulants contained the principal inorganic components of the actual waste and generally a single complexant such as N-(2-hydroxyethyl) ethylenediaminetriacetic acid (HEDTA) or ethylenediaminetriacetic acid (EDTA). Both homogeneous and heterogeneous compositional forms were developed. Aggressive core sampling and analysis activities conducted during Windows C and E provided information that was used to design new simulants that more accurately reflected major and minor inorganic components.

Bryan, S.A.; Pederson, L.R.

1994-08-01T23:59:59.000Z

57

Raman spectroscopy of solutions and interfaces containing nitrogen dioxide, water, and 1,4 dioxane: Evidence for repulsion of surface water by NO{sub 2} gas  

SciTech Connect (OSTI)

The interaction of water, 1,4 dioxane, and gaseous nitrogen dioxide, has been studied as a function of distance measured through the liquid-vapour interface by Raman spectroscopy with a narrow (<0.1 mm) laser beam directed parallel to the interface. The Raman spectra show that water is present at the surface of a dioxane-water mixture when gaseous NO{sub 2} is absent, but is virtually absent from the surface of a dioxane-water mixture when gaseous NO{sub 2} is present. This is consistent with recent theoretical calculations that show NO{sub 2} to be mildly hydrophobic.

Murdachaew, Garold [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel)] [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel); Varner, Mychel E.; Veer, Wytze E. van der [Department of Chemistry, University of California, Irvine, California 92697 (United States)] [Department of Chemistry, University of California, Irvine, California 92697 (United States); Gerber, R. Benny [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel) [Institute of Chemistry and the Fritz Haber Research Center for Molecular Dynamics, Hebrew University, Jerusalem 91904 (Israel); Department of Chemistry, University of California, Irvine, California 92697 (United States); Phillips, Leon F., E-mail: leon.phillips@canterbury.ac.nz [Department of Chemistry, University of California, Irvine, California 92697 (United States); Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch (New Zealand)

2014-05-14T23:59:59.000Z

58

Synthetic crystalline metallosilicate compositions, the preparation thereof and their use in the conversion of synthesis gas to low molecular weight hydrocarbons  

SciTech Connect (OSTI)

A method is described for the conversion of synthesis gas comprising: contacting synthesis gas which consists of hydrogen and carbon monoxide with a catalytically effective amount of a crystalline ferrometallosilicate composition represented in terms of mole ratios.

Hinnenkamp, J.A.; Walatka, V.V.

1987-06-02T23:59:59.000Z

59

Effect of steam partial pressure on gasification rate and gas composition of product gas from catalytic steam gasification of HyperCoal  

SciTech Connect (OSTI)

HyperCoal was produced from coal by a solvent extraction method. The effect of the partial pressure of steam on the gasification rate and gas composition at temperatures of 600, 650, 700, and 750{sup o}C was examined. The gasification rate decreased with decreasing steam partial pressure. The reaction order with respect to steam partial pressure was between 0.2 and 0.5. The activation energy for the K{sub 2}CO{sub 3}-catalyzed HyperCoal gasification was independent of the steam partial pressure and was about 108 kJ/mol. The gas composition changed with steam partial pressure and H{sub 2} and CO{sub 2} decreased and CO increased with decreasing steam partial pressure. By changing the partial pressure of the steam, the H{sub 2}/CO ratio of the synthesis gas can be controlled. 18 refs., 7 figs., 2 tabs.

Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

2009-09-15T23:59:59.000Z

60

Computational Fluid Dynamics Simulations of Raw Gas Composition from a Black Liquor Gasifier—Comparison with Experiments  

Science Journals Connector (OSTI)

Computational Fluid Dynamics Simulations of Raw Gas Composition from a Black Liquor Gasifier—Comparison with Experiments ... The black liquor spray was represented by 1003 discrete particles having a fitted Rosin Rammler distribution of power 2 and a characteristic size of 200 ?m. ... Additional PFR calculations were performed using different inlet gas compositions with similar results (not presented here), i.e. the Jones and Lindstedt model showed a significantly higher reformation rate of methane than GRI-Mech at gasification conditions in the medium temperature range (1150 < T < 1500 K). ...

Per Carlsson; Kristiina Iisa; Rikard Gebart

2011-07-05T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Carbon-Carbon Composites as Recuperator Material for Direct Gas Brayton Systems  

SciTech Connect (OSTI)

Of the numerous energy conversion options available for a space nuclear power plant (SNPP), one that shows promise in attaining reliable operation and high efficiency is the direct gas Brayton (GB) system. In order to increase efficiency, the GB system incorporates a recuperator that accounts for nearly half the weight of the energy conversion system (ECS). Therefore, development of a recuperator that is lighter and provides better performance than current heat exchangers could prove to be advantageous. The feasibility of a carbon-carbon (C/C) composite recuperator core has been assessed and a mass savings of 60% and volume penalty of 20% were projected. The excellent thermal properties, high-temperature capabilities, and low density of carbon-carbon materials make them attractive in the GB system, but development issues such as material compatibility with other structural materials in the system, such as refractory metals and superalloys, permeability, corrosion, joining, and fabrication must be addressed.

RA Wolf

2006-07-19T23:59:59.000Z

62

Use of Composite Pipe Materials in the Transportation of Natural Gas (INEEL/EXT-02-00992)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

992 992 Use of Composite Pipe Materials in the Transportation of Natural Gas Patrick Laney July 2002 Idaho National Engineering and Environmental Laboratory Bechtel BWXT Idaho, LLC INEEL/EXT-02-00992 Use of Composite Pipe Materials in the Transportation of Natural Gas Sponsored by Natural Gas Pipeline Infrastructure Reliability Program National Energy Technology Laboratory INEEL Field Work Proposal # 4340-70 Prepared by: Patrick Laney Idaho National Engineering and Environmental Laboratory Idaho Falls, Idaho With Contributions From: Ian Kopp Kenway Corporation Augusta, Maine July 2002 Idaho National Engineering and Environmental Laboratory Fossil Energy Technologies Department Idaho Falls, Idaho 83415 Prepared for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy

63

Raman spectra of terpenes  

Science Journals Connector (OSTI)

The available Raman spectral data on terpenic compounds are tabulated and reviewed. It is concluded that the identification of the constituents of a mixture of terpenes by Raman effect methods cannot give trus...

W. Rogie Angus

1938-11-01T23:59:59.000Z

64

Controls of coal fabric on coalbed gas production and compositional shift in both field production and canister desorption tests  

SciTech Connect (OSTI)

The production rates of coalbed gas wells commonly vary significantly, even in the same field with similar reservoir permeability and gas content. The compositional variation in produced gas is also not everywhere predictable, although in most fields produced gas becomes progressively enriched in CO, through the production life of a reservoir, such as parts of the San Juan basin. In contrast, it is generally observed that the ratio of CO{sub 2}:CH{sub 4} declines with time during field and laboratory desorption testing of coal cores. In this study, we investigate numerically the importance of coal fabric, namely cleat spacing and aperture width, on the performance of coalbed gas wells and gas compositional shifts during production. Because of the cubic relationship between fracture permeability and fracture aperture width (and thus fracture porosity) for a given cleat permeability, the production profile of coal seams varies depending on whether the permeability is distributed among closely spaced fractures (cleat) with narrower apertures or more widely spaced fractures (cleat) with wider apertures. There is a lower fracture porosity for coal with widely spaced fractures than for coal with closely spaced fractures. Therefore, the relative permeability to gas increases more rapidly for coals with more widely spaced cleats as less dewatering from fractures is required, assuming that the fractures are initially water saturated. The enrichment of CO{sub 2} in the production gas with time occurs because of the stronger adsorption of coals for CO{sub 2} than CH{sub 4}. However, during desorption of coal cores, CO{sub 2} desorbs more rapidly than methane because desorption rate is governed more by diffusion than by sorption affinity, and CO{sub 2} has much higher effective diffusivity in microporous coals than CH{sub 4}.

Cui, X.J.; Bustin, R.M. [University of British Columbia, Vancouver, BC (Canada)

2006-03-15T23:59:59.000Z

65

Vertical composition gradient effects on original hydrocarbon in place volumes and liquid recovery for volatile oil and gas condensate reservoirs  

E-Print Network [OSTI]

in Place Volumes and Liquid Recovery for Volatile Oil and Gas Condensate Reservoirs. (December 2000) Juan Manual Jaramillo Arias, B. S. , Universidad de America; B. S. , Universidad Nacional de Colombia Chair of Advisory Committee: Dr. Maria A. Barrufet... Reservoir Performance 2. 2 Equation of State Review. . 2. 3 Peng Robinson Equation of State (PR EOS). 2. 4 Vapor Liquid Equilibria. . 2. 5 Volume Translation. 2. 6 Pseudoization or Lumping. 2. 7 Heavy Fraction Characterization. . 2. 8 Compositional...

Jaramillo Arias, Juan Manuel

2012-06-07T23:59:59.000Z

66

The influence of air inflow on CH4 composition ratio in landfill gas  

Science Journals Connector (OSTI)

When landfill gas is collected, air inflow into the landfill...4 productivity. The decline of CH4 content in landfill gas (LFG) negatively affects energy projects. We...2 was an effective indicator of air inflow ...

Seung-Kyu Chun

2014-02-01T23:59:59.000Z

67

Variability in natural gas fuel composition and its effects on the performance of catalytic combustion systems. Final report for period September 18, 1998 - September 17, 2000  

SciTech Connect (OSTI)

Natural gas is composed primarily of methane with small amounts of higher hydrocarbons and diluents, which vary by region and over time. Compositions of natural gas from domestic and worldwide sources were surveyed with respect to content of higher hydrocarbons and diluents. The survey showed slight compositional variability between most of the gases, with a small fraction of them containing significantly larger contents of higher hydrocarbons than the mean. As gas-fired turbines will be used for power generation all over the world, they will need to tolerate operation with fuels with a wide variety of compositions, particularly with respect to the concentration of higher hydrocarbons and diluents. Subscale catalytic combustion modules typical of those used in gas turbine power generation with ultra low emissions of pollutants were tested in a subscale test system with natural gas alone and with added known levels of hydrocarbon compounds and diluents. The range of compositions tested contained the range observed in the survey. Test results were used to calculate the effect of composition on catalyst performance. The compositional variability is of little consequence to the catalyst for most of the gases in the survey, including nearly all of the gases delivered in the U.S. To accommodate the remaining gases, the catalyst inlet temperature must be lowered to maintain combustor durability. These results support commercial acceptance of catalytic combustion systems for use in natural gas fired turbines in distributed power generation with ultra low NO{sub x} emissions.

Ginter, David; Simchick, Chuck; Schlatter, Jim

2002-03-01T23:59:59.000Z

68

Prediction of the effects of compositional mixing in a reservoir on conversion to natural gas storage.  

E-Print Network [OSTI]

??The increased interest in the development of new Gas Storage Fields over the lastseveral decades has created some interesting challenges for the industry. Most existinggas… (more)

Brannon, Alan W.

2011-01-01T23:59:59.000Z

69

Effect of sweep gas composition on ionization chamber response in the BEATRIX-II tritium recovery experiment  

SciTech Connect (OSTI)

The BEATRIX-II irradiation experiment was an in situ tritium recovery experiment to evaluate the tritium release characteristics of fusion ceramic breeder materials and to characterize their stability under fast neutron irradiation to extended burnups. This is an International Energy Agency (IEA) sponsored experiment which is being carried out in the Materials Open Test Assembly of Fast Flux Test Facility (FFTF). The participants are Japan, Canada and the US The in situ tritium recovery experiment consisted of two individual in-reactor experimental assemblies (Phase I and Phase II) that were irradiated for 300 and 200 EFPD, respectively. Each experimental phase included two specimens: a thin annular specimen capable of temperature changes and a larger temperature-gradient specimen. In Phase I both specimens were Li{sub 2}O while for Phase II the temperature-change specimen consisted of Li{sub 2}O and the temperature-gradient specimen was a Li{sub 2}ZrO{sub 3} spherebed. Real-time measurements of the tritium release from the specimens during changing conditions (neutronics, temperature and sweep gas composition) were made using ion chambers. In order to correctly interpret the response of the ionization chambers it is necessary to understand the effect of changing sweep gas composition on the operation of the chambers. The purpose of this paper is to describe activities carried out to determine the effect of hydrogen additions to a helium sweep gas on the operation of these ionization chambers.

Slagle, O.D.; Hollenberg, G.W. [Pacific Northwest Lab., Richland, WA (United States); Baker, D.E. [Westinghouse Hanford Co., Richland, WA (United States)

1992-10-01T23:59:59.000Z

70

Effect of sweep gas composition on ionization chamber response in the BEATRIX-II tritium recovery experiment  

SciTech Connect (OSTI)

The BEATRIX-II irradiation experiment was an in situ tritium recovery experiment to evaluate the tritium release characteristics of fusion ceramic breeder materials and to characterize their stability under fast neutron irradiation to extended burnups. This is an International Energy Agency (IEA) sponsored experiment which is being carried out in the Materials Open Test Assembly of Fast Flux Test Facility (FFTF). The participants are Japan, Canada and the US The in situ tritium recovery experiment consisted of two individual in-reactor experimental assemblies (Phase I and Phase II) that were irradiated for 300 and 200 EFPD, respectively. Each experimental phase included two specimens: a thin annular specimen capable of temperature changes and a larger temperature-gradient specimen. In Phase I both specimens were Li[sub 2]O while for Phase II the temperature-change specimen consisted of Li[sub 2]O and the temperature-gradient specimen was a Li[sub 2]ZrO[sub 3] spherebed. Real-time measurements of the tritium release from the specimens during changing conditions (neutronics, temperature and sweep gas composition) were made using ion chambers. In order to correctly interpret the response of the ionization chambers it is necessary to understand the effect of changing sweep gas composition on the operation of the chambers. The purpose of this paper is to describe activities carried out to determine the effect of hydrogen additions to a helium sweep gas on the operation of these ionization chambers.

Slagle, O.D.; Hollenberg, G.W. (Pacific Northwest Lab., Richland, WA (United States)); Baker, D.E. (Westinghouse Hanford Co., Richland, WA (United States))

1992-10-01T23:59:59.000Z

71

ON THE UNUSUAL GAS COMPOSITION IN THE {beta} PICTORIS DEBRIS DISK  

SciTech Connect (OSTI)

The metallic gas associated with the {beta} Pic debris disk is not believed to be primordial, but arises from the destruction of dust grains. Recent observations have shown that carbon and oxygen in this gas are exceptionally overabundant compared to other elements, by some 400 times. We study the origin of this enrichment under two opposing hypotheses: preferential production, where the gas is produced with the observed unusual abundance (as may happen if gas is produced by photodesorption from C/O-rich icy grains), and preferential depletion, where the gas evolves to the observed state from an original solar abundance (if outgassing occurs under high-speed collisions) under a number of dynamical processes. We include in our study the following processes: radiative blowout of metallic elements, dynamical coupling between different species, and viscous accretion onto the star. We find that, if gas viscosity is sufficiently low (the conventional {alpha} parameter {approx}< 10{sup -3}), differential blowout dominates. While gas accumulates gradually in the disks, metallic elements subject to strong radiation forces, such as Na and Fe, deplete more quickly than C and O, naturally leading to the observed overabundance of C and O. On the other hand, if gas viscosity is high ({alpha} {approx}> 10{sup -1}, as expected for this largely ionized disk), gas is continuously produced and viscously accreted toward the star. This removal process does not discriminate between elements so the observed overabundance of C and O has to be explained by a preferential production that strongly favors C and O to other metallic elements. One such candidate is photodesorption off the grains. We compare our calculation against all observed elements ({approx}10) in the gas disk and find a mild preference for the second scenario, based on the abundance of Si alone. If true, {beta} Pic should still be accreting at an observable rate, well after its primordial disk has disappeared.

Xie, Ji-Wei; Wu, Yanqin [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada)] [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada); Brandeker, Alexis, E-mail: jwxie@astro.utoronto.ca, E-mail: wu@astro.utoronto.ca, E-mail: alexis@astro.su.se [Department of Astronomy, Stockholm University, SE-106 91 Stockholm (Sweden)] [Department of Astronomy, Stockholm University, SE-106 91 Stockholm (Sweden)

2013-01-10T23:59:59.000Z

72

JOURNAL OF RAMAN SPECTROSCOPY J. Raman Spectrosc. 2005; 36: 864871  

E-Print Network [OSTI]

traditionally been utilized to indicate the phase transition. Comparisons with the Raman spectra of spodumene

Downs, Robert T.

73

7 - Raman spectroscopy of graphene  

Science Journals Connector (OSTI)

Abstract: The principles of Raman scattering and the properties of phonons and electrons in graphene are reviewed. The focus is on Raman spectroscopy of mono- and bilayer graphene, particularly perturbations that have a significant influence on the Raman spectra. The distinct behaviour of Raman modes of different orders is discussed.

M. Hulman

2014-01-01T23:59:59.000Z

74

Raman scattering in crystals  

SciTech Connect (OSTI)

A tutorial presentation is given of Raman scattering in crystals. The physical concepts are emphasized rather than the detailed mathematical formalism. Starting with an introduction to the concepts of phonons and conservation laws, the effects of photon-phonon interactions are presented. This interaction concept is shown for a simple cubic crystal and is extended to a uniaxial crystal. The correlation table method is used for determining the number and symmetry of the Raman active modes. Finally, examples are given to illustrate the relative ease of using this group theoretical method and the predictions are compared with measured Raman spectra. 37 refs., 17 figs., 6 tabs.

Edwards, D.F.

1988-09-30T23:59:59.000Z

75

Calculation of geothermal reservoir temperatures and steam fractions from gas compositions  

SciTech Connect (OSTI)

This paper deals with the chemical equilibria and physical characteristics of the fluid in the reservoir (temperature, steam fraction with respect to total water, gas/steam ratio, redox conditions), which seem to be responsible for the observed concentrations of some reactive species found in the geothermal fluids (CO2, H2, H2S and CH4). Gas geochemistry is of particular interest in vapor-dominated fields where the fluid discharged consists of almost pure steam containing a limited number of volatile chemical species. Considering several geothermal systems, a good correlation has been obtained among the temperatures calculated from the gas geothermometers and the temperatures measured in the reservoir of evaluated by other physical or chemical methods. 24 refs., 5 figs.

D'Amore, F.; Truesdell, A.H.

1985-01-01T23:59:59.000Z

76

Aurichalcite – An SEM and Raman spectroscopic study  

Science Journals Connector (OSTI)

Raman spectroscopy complimented with supplementary infrared spectroscopy has been used to characterise the vibrational spectrum of aurichalcite a zinc/copper hydroxy carbonate (Zn,Cu2+)5(CO3)2(OH)6. XRD patterns of all specimens show high orientation and indicate the presence of some impurities such as rosasite and hydrozincite. However, the diffraction patterns for all samples are well correlated to the standard reference patterns. SEM images show highly crystalline and ordered structures in the form of micron long fibres and plates. EDAX analyses indicate variations in chemical composition of Cu/Zn ratios ranging from 1/1.06 to 1/2.87. The symmetry of the carbonate anion in aurichalcite is Cs and is composition dependent. This symmetry reduction results in multiple bands in both the symmetric stretching and bending regions. The intense band at 1072 cm?1 is assigned to the ?1(CO3)2? symmetric stretching mode. Three Raman bands assigned to the ?3(CO3)2? antisymmetric stretching modes are observed for aurichalcite at 1506, 1485 and 1337 cm?1. Multiple Raman bands are observed in 800–850 cm?1 and 720–750 cm?1 regions and are attributed to ?2 and ?4 bending modes confirming the reduction of the carbonate anion symmetry in the aurichalcite structure. An intense Raman band at 1060 cm?1 is attributed to the ? OH deformation mode.

Ray L. Frost; Matt C. Hales; B. Jagannadha Reddy

2007-01-01T23:59:59.000Z

77

Magmatic Gas Composition Reveals the Source Depth of Slug-Driven Strombolian Explosive Activity  

Science Journals Connector (OSTI)

...hydrothermal meteoric steam during shallow...closed- to open-system conditions...entrainment of meteoric steam from the shallow hydrothermal system. (ii) The gas slugs...prevented quantitative assessment of the slug source...is a powerful tool in such studies...

Mike Burton; Patrick Allard; Filippo Muré; Alessandro La Spina

2007-07-13T23:59:59.000Z

78

Nuclear Raman spectroscopy  

Science Journals Connector (OSTI)

An experiment is described in which the nuclear analog to Raman spectroscopy has been applied to 57Fe. The results of the experiment are given, and future applications of...

DePaola, B D; Wagal, S S; Collins, C B

1985-01-01T23:59:59.000Z

79

Influence of Heteroanion and Ammonium Cation Size on the Composition and Gas-Phase Fragmentation of Polyoxovanadates  

SciTech Connect (OSTI)

This paper describes the results of a systematic experimental investigation of the influence of different size cationic ammonium ligands and heteroanions on the composition, ionic charge state and gas-phase fragmentation pathways of anionic polyoxovanadates synthesized in solution. Four separate solutions of olyoxometalates (POMs) were prepared using all possible combinations of the tetraethylammonium [(C2H5)4N+] ligand, chloride (Cl-) heteroanion, tetrabutylammonium [(C4H9)4N+] ligand and acetate (CH3CO2-) heteroanion. Employing electrospray ionization combined with high-resolution mass spectrometry (ESI-MS) we demonstrate that POM solutions synthesized using the small [(C2H5)4N+] ligand and Cl-heteroanion are composed predominately of large doubly and triply charged chlorine containing clusters with a size distribution centered at fourteen vanadium atoms. POM solutions prepared using the Cl- anion and [(C4H9)4N+] ligand are shown to contain slightly larger clusters with fifteen and sixteen vanadium atoms, thereby indicating that the size of the cationic ammonium ligand exerts only a weak influence on the polymerization of polyoxovanadates. POM solutions prepared using (C2H5)4NCl and (C4H9)4NCl also produced peaks consistent with the attachment of one and two ammonium cations to the larger clusters. Solutions prepared using the large CH3CO2 - heteroanion, in contrast, are demonstrated to contain much smaller singly and doubly *Manuscript Click here to view linked References 2 charged clusters with a size distribution centered at six vanadium atoms. In addition, while incorporation of one and two ammonium ligands into the smaller clusters was observed, no POMs containing the CH3CO2 - heteroanion were identified. The gas-phase fragmentation pathways of representative POMs containing one and two ammonium ligands were examined using collision induced dissociation (CID) and mass spectrometry. Similar primary fragmentation pathways involving partial loss of a ligand -[(CxHy)3N+ x = 2,4; y = 5,9] were observed for clusters containing both one and two ligands largely independent of the size, composition and charge state of the precursor ion. The [(C4H9)4N+] ligand was found to exhibit stronger interactions with the core of the POMs resulting in higher abundances of fragment ions containing (C4H9) units compared to (C2H5) units from [(C2H5)4N+]. These results provide fundamental insight into the interactions between anionic metal oxide clusters, heteroanions and cationic ammonium ligands that are responsible for the size and composition controlled synthesis of POMs in solution.

Johnson, Grant E.; Al Hasan, Naila M.; Laskin, Julia

2013-11-15T23:59:59.000Z

80

Resonant Raman spectroscopy of nanotubes  

Science Journals Connector (OSTI)

...Raman spectroscopy in carbons: from nanotubes to diamond compiled by Andrea C. Ferrari...Robertson Resonant Raman spectroscopy of nanotubes Christian Thomsen 1 Stephanie Reich 2...The experimental situation in carbon nanotubes is reviewed in view of these criteria...

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

In situ Raman spectroscopy of lanthanum-strontium-cobaltite thin films  

E-Print Network [OSTI]

Raman spectroscopy is used to probe the structural change of Lanthanum Strontium Cobaltite (La1.xSrxCoO 3 -8) thin films across change in composition (0%-60% strontium) and temperature (30*C-520°C). Raman shift peaks were ...

Breucop, Justin Daniel

2012-01-01T23:59:59.000Z

82

A layered surface acoustic wave gas sensor based on a polyaniline/In2O3 nanofibre composite  

E-Print Network [OSTI]

Polyaniline/In 2 O 3 Nanofiber Composite A. Z. Sadek *1 , W.In 2 O 3 nanofiber composite based layered surface acousticIn 2 O 3 nanoparticle composite. The nanocomposite was

Sadek, A Z; Wlodarski, W; Shin, K; Kaner, Richard B; Kalantar-zadeh, K

2006-01-01T23:59:59.000Z

83

Genetic optimization of two-material composite laminates Laurent Grosset  

E-Print Network [OSTI]

the power of GAs for this application. COMPOSITE LAMINATE DESIGN Composite laminate optimization typically

Coello, Carlos A. Coello

84

Fingerprint and high-wavenumber Raman spectroscopy in a human-swine coronary xenograft in vivo  

E-Print Network [OSTI]

Intracoronary Raman spectroscopy could open new avenues for the study and management of coronary artery disease due to its potential to measure the chemical and molecular composition of coronary atherosclerotic lesions. ...

Motz, Jason T.

85

Raman accumulator as a fusion laser driver  

DOE Patents [OSTI]

Apparatus for simultaneous laser pulse amplification and compression, using multiple pass Raman scattering in one Raman cell and pulse switchout from the optical cavity through use of a dichroic device associated with the Raman cell.

George, E.V.; Swingle, J.C.

1982-03-31T23:59:59.000Z

86

Impact of natural gas fuel composition on criteria, toxic, and particle emissions from transit buses equipped with lean burn and stoichiometric engines  

Science Journals Connector (OSTI)

Abstract This study investigated the impacts of varying natural gas composition on the exhaust emissions from different technology transit buses. For this study, two CNG (compressed natural gas) buses equipped with lean burn combustion and \\{OCs\\} (oxidation catalysts), and one stoichiometric CNG bus equipped with a TWC (three-way catalyst) and EGR (exhaust gas recirculation) were tested on a chassis dynamometer over the CBD (Central Business District) cycle on six different gas blends each. The gases represented a range of compositions from gases with high levels of methane and correspondingly lower energy contents/WN (Wobbe number) to gases with higher levels of heavier hydrocarbons and correspondingly higher energy contents/WN. For the lean burn buses, gases with low methane contents exhibited higher \\{NOx\\} (nitrogen oxides) (19%–53%) and NMHC (non-methane hydrocarbon) (39%–102%) emissions, but lower emissions of THC (total hydrocarbon) (9%–24%), CH4 (methane) (23%–33%), and formaldehyde emissions (14%–45%). The stoichiometric engine bus with a TWC showed significantly reduced \\{NOx\\} and THC emissions compared to the lean burn buses, but did show higher levels of CO (carbon monoxide) and NH3 (ammonia). PM (particulate matter) mass emissions did not show any fuel effects, while PN (particle number) emissions exhibited some reductions for the higher WN gases.

Maryam Hajbabaei; Georgios Karavalakis; Kent C. Johnson; Linda Lee; Thomas D. Durbin

2013-01-01T23:59:59.000Z

87

Cladding-pumped Raman fibre laser sources.  

E-Print Network [OSTI]

??In this thesis, I investigate cladding-pumped Raman fibre lasers and amplifiers. Such devices, offering a novel way to generate Raman gain, combine the advantages of… (more)

Ji, Junhua

2011-01-01T23:59:59.000Z

88

Raman Lidar (RL) Handbook  

SciTech Connect (OSTI)

The Raman lidar at the ARM Climate Research Facility (ACRF) Southern Great Plains (SGP) Central Facility (SGPRL) is an active, ground-based laser remote sensing instrument that measures height and time resolved profiles of water vapor mixing ratio and several cloud- and aerosol-related quantities. The system is a non-commercial custom-built instrument developed by Sandia National Laboratories specifically for the ARM Program. It is fully computer automated, and will run unattended for many days following a brief (~5-minute) startup period. The self-contained system (requiring only external electrical power) is housed in a climate-controlled 8’x8’x20’ standard shipping container.

Newsom, RK

2009-03-01T23:59:59.000Z

89

Polymer Nano-composites Robert J Young FREng*  

E-Print Network [OSTI]

of Carbon Fibres 1000 1500 2000 2500 3000 0 100 200 300 P120 P100 P75 P55 P25 Intensity University #12;Contents · Advanced Composites · Carbon fibres · Raman spectroscopy · Carbon nanotubes (SWNTs) ­ Raman spectroscopy · Carbon nanotubes in epoxy composites ­ Mechanical deformation ­ Interfacial stress

Mellor-Crummey, John

90

Baseline studies of surface gas exchange and soil-gas composition in preparation for CO{sub 2} sequestration research: Teapot Dome, Wyoming  

SciTech Connect (OSTI)

A baseline determination of CO{sub 2} and CH{sub 4} fluxes and soil-gas concentrations of CO{sub 2} and CH{sub 4} was made over the Teapot Dome oil field in the Naval Petroleum Reserve 3 in Natrona County, Wyoming, United States. This was done in anticipation of the experimentation with CO{sub 2} sequestration in the Pennsylvanian Tensleep Sandstone underlying the field at a depth of 1680 m. The measurements were made in January 2004 to capture the system with minimum biological activity in the soils, resulting in a minimum CO{sub 2} flux and a maximum CH{sub 4} flux. The CO{sub 2} fluxes were measured in the field with an infrared spectroscopic method. The CH{sub 4} fluxes were determined from gas-chromatographic measurements on discrete samples from under the flux chambers. The CO{sub 2} and CH{sub 4} were determined at 30-, 60-, and 100-cm depths in soil gas by gas chromatography. A total of 40 locations had triplicate flux measurements using 1.00-m{sup 2} chambers, and soil gas was sampled at single points at each of the 40 locations. Carbon dioxide fluxes averaged 227.1 CO{sub 2} m{sup -2} day{sup -1}, a standard deviation of 186.9 mg m{sup -2} day{sup -1}, and a range of - 281.7 to 732.9 mg m{sup -2} day{sup -1}, not including one location with subsurface infrastructure contamination. Methane fluxes averaged 0.137 mg CH{sub 4} m{sup -2} day{sup -1}, standard deviation of 0.326 mg m{sup -2} day{sup -1}, and a range of -0.481 to 1.14 mg m{sup -2} day{sup -1}, not including the same contaminated location.

Klusman, R.W. [Colorado School of Mines, Golden, CO (US). Dept. of Chemistry & Geochemistry

2003-08-01T23:59:59.000Z

91

In-situ raman microscopy of individual LiNi0.8Co0.15Al0.05O2 particles in the Li-ion battery composite cathode  

E-Print Network [OSTI]

2 Particles in the Li-ion Battery Composite Cathode Jingleidegradation of various Li-ion battery systems has been the

Lei, Jinglei; McLarnon, Frank; Kostecki, Robert

2004-01-01T23:59:59.000Z

92

Mathematical models of interconnections between composition and properties of oils in the Apsheron oil-and gas-bearing region of Azerbaijan  

SciTech Connect (OSTI)

This paper reports on the example of oils in the Apsheron oil- and gas-bearing region and Apsheron archipelago located in the western part of the Southern Caspian depression, of which the authors have developed mathematical models of a group hydrocarbon composition; interconnection between oil density and content of asphalt-resin materials, benzine, and ligroin; interconnections between oil density and viscosity and temperature; and interconnections between content of asphalt-resin properties and low-temperature fractions. The models obtained enable us to extrapolate factual data on composition and properties of oils beyond the limits of fixed depths of burial of oil-saturated reservoirs both to a zone of great depths and increased temperatures where hydrocarbons were in a gaseous or oil and gaseous state, and to a zone of near-surface conditions where oils acquire the consistency of asphalts.

Buryakovsky, L.A.; Dzhevanshir, R.D. (Inst. of Deep Oil and Gas Deposits, Azerbaijan Academy of Sciences, 33 Narimanov Prospect, Baku 370143, Azerbaijan (SU))

1992-01-01T23:59:59.000Z

93

Superradiant Raman Laser Magnetometer  

E-Print Network [OSTI]

We demonstrate a proof-of-principle magnetometer that relies on the active oscillation of a cold atom Raman laser to continuously map a field-sensitive atomic phase onto the phase of the radiated light. We demonstrate wideband sensitivity during continuous active oscillation, as well as narrowband sensitivity in passive Ramsey-like mode with translation of the narrowband detection in frequency using spin-echo techniques. The sensor operates with a sensitivity of 190 pT/Hz^(1/2) at 1 kHz and effective sensing volume of 2 * 10^-3 mm^3. Fundamental quantum limits on the magnetic field sensitivity of an ideal detector are also considered.

Weiner, Joshua M; Bohnet, Justin G; Chen, Zilong; Thompson, James K

2012-01-01T23:59:59.000Z

94

Raman Spectroscopic Studies of Silicotitanates  

SciTech Connect (OSTI)

Silicotitanates are nanoporous materials that have been used as selective ion exchangers for removing cesium from waste streams and catalysts for promoting oxidation and hydroxylation reactions. The local bonding configurations and network charge distribution are known to influence the selectivity and reactivity of these compounds. We have synthesized a group of new silicotitanates using sol-gel and solid state techniques. Raman spectroscopy has been used to systematically examine the vibrational behavior of these compounds. By correlating the variations of Raman spectra with titanium coordinations of these compounds, the relationship between Raman shifts and the local bonding configurations around silicon and titanium is proposed.

Su, Yali; Balmer, Mari Lou; Bunker, Bruce C.

2000-07-19T23:59:59.000Z

95

Raman and electron microscopic studies of Si{sub 1-x}Ge{sub x} alloy nanowires grown by chemical vapor deposition  

SciTech Connect (OSTI)

Si{sub 1-x}Ge{sub x} alloy nanowires (SiGeNWs) were grown by Au-catalyzed chemical vapor deposition and studied by Raman spectroscopy, transmission electron microscopy (TEM), and energy-dispersive x-ray spectroscopy (EDS) in TEM (TEM-EDS). The relationship between the growth parameters and the structure of the SiGeNWs was clarified by systematically changing the growth conditions over a wide range. Raman and TEM-EDS results demonstrated that the SiGeNWs consist of a lower Ge composition core and a higher Ge composition shell epitaxially grown on the surface of the core. The effects of oxidation on the structure of the SiGeNWs were studied. It was found that oxidation leads to segregation of the Ge atoms at the interface between the SiGeNWs and SiO{sub 2}, which in turn results in a large inhomogeneity in Ge composition. Oxidation at a very low rate in a diluted oxygen gas atmosphere is required to avoid the formation of Ge particles and minimize the inhomogeneity.

Kawashima, Takahiro; Imamura, Goh; Fujii, Minoru; Hayashi, Shinji; Saitoh, Tohru; Komori, Kazunori [Advanced Devices Development Center, Matsushita Electric Industrial Co., Ltd., 3-1-1 Yagumo-Nakamachi, Moriguchi, Osaka 570-8501 (Japan); Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501 (Japan); Image Devices Development Center, Matsushita Electric Industrial Co., Ltd., 3-1-1 Yagumo-Nakamachi, Moriguchi, Osaka 570-8501 (Japan)

2007-12-15T23:59:59.000Z

96

Simulation of the dependence of gas composition on the conditions of the thermal treatment of oil shale  

Science Journals Connector (OSTI)

Empirical formulas for calculating the concentrations of substances such as hydrogen and carbon(II) oxide and also the smallest possible concentration of carbon(IV) oxide in gas prepared by the steam treatment of...

A. N. Ryzhov; T. A. Avakyan; L. K. Maslova; E. A. Sakharova…

2013-03-01T23:59:59.000Z

97

Raman Spectrum of Heavy Water  

Science Journals Connector (OSTI)

... . of 99.2 gm./lOO gm. D2O ( 1.1049) supplied by the Norsk Hydro-Elektrisk Kvaelstofaktieselskab. The Raman spectrum of the substance was photographed with a Hilger ...

R. ANANTHAKRISHNAN

1935-10-05T23:59:59.000Z

98

Raman Spectroscopy of Microbial Pigments  

Science Journals Connector (OSTI)

...minireview, Raman spectroscopy has several advantages for pigment and carotenoid work. The...BF01923559 . 71. Garcia-Pichel, F . 1998. Solar ultraviolet and the evolutionary history...signal strength, adaptive strategies, solar radiation, and humidity. Astrobiology...

Jan Jehli?ka; Howell G. M. Edwards; Aharon Oren

2014-03-28T23:59:59.000Z

99

UV Raman spectroscopy of hydrocarbons  

Science Journals Connector (OSTI)

...Nitrogen chemistry Petroleum Physics methods Spectrum Analysis...Grasselli, J. G. 1991 The handbook of infrared and Raman characteristic...13081313. Weast, R. C. 1977 CRC handbook of chemistry and physics, 58th edn, pp. C80C548...

2004-01-01T23:59:59.000Z

100

Raman/FTIR spectroscopy of oil shale retort gases  

SciTech Connect (OSTI)

A Raman facility was assembled in order to aid in the evaluation of the feasibility of using Raman or FTIR spectroscopy for analyzing gas mixtures of interest in oil shale. Applications considered in oil shale research included both retort monitoring and laboratory kinetic studies. Both techniques gave limits of detection between 10 and 1000 ppM for ten representative pertinent gases. Both techniques are inferior as a general analytical technique for oil shale gas analysis in comparison with mass spectroscopy, which had detection limits between 1 and 50 ppM for the same gases. The conclusion of the feasibility study was to recommend that mass spectroscopic techniques be used for analyzing gases of interest to oil shale.

Richardson, J H; Monaco, S B; Sanborn, R H; Hirschfeld, T B; Taylor, J R

1982-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Effect of fuel gas composition in chemical-looping combustion with Ni-based oxygen carriers. 1. Fate of sulfur  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) has been suggested among the best alternatives to reduce the economic cost of CO{sub 2} capture using fuel gas because CO{sub 2} is inherently separated in the process. For gaseous fuels, natural gas, refinery gas, or syngas from coal gasification can be used. These fuels may contain different amounts of sulfur compounds, such as H{sub 2}S and COS. An experimental investigation of the fate of sulfur during CH{sub 4} combustion in a 500 W{sub th} CLC prototype using a Ni-based oxygen carrier has been carried out. The effect on the oxygen carrier behavior and combustion efficiency of several operating conditions such as temperature and H{sub 2}S concentration has been analyzed. Nickel sulfide, Ni3S{sub 2}, was formed at all operating conditions in the fuel reactor, which produced an oxygen carrier deactivation and lower combustion efficiencies. However, the oxygen carrier recovered their initial reactivity after certain time without sulfur addition. The sulfides were transported to the air reactor where SO{sub 2} was produced as final gas product. Agglomeration problems derived from the sulfides formation were never detected during continuous operation. Considering both operational and environmental aspects, fuels with sulfur contents below 100 vppm H{sub 2}S seem to be adequate to be used in an industrial CLC plant.

Garcia-Labiano, F.; de Diego, L.F.; Gayan, P.; Adanez, J.; Abad, A.; Dueso, C. [CSIC, Zaragoza (Spain)

2009-03-15T23:59:59.000Z

102

Performance analysis of compositional and modified black-oil models for rich gas condensate reservoirs with vertical and horizontal wells  

E-Print Network [OSTI]

It has been known that volatile oil and gas condensate reservoirs cannot be modeled accurately with conventional black-oil models. One variation to the black-oil approach is the modified black-oil (MBO) model that allows the use of a simple...

Izgec, Bulent

2004-09-30T23:59:59.000Z

103

Dual-Remote Raman Technology for In-Situ Identification of Tank Waste - 13549  

SciTech Connect (OSTI)

A new Raman spectroscopic system for in-situ identification of the composition of solid nuclear tank waste is being developed by collaborative effort between Pacific Northwest National Laboratory (PNNL) and EIC Laboratories, Inc. The recent advancements in Raman technology allow probing the chemical composition of the tank waste without sample collection. In the newly tested configuration, the Raman probe is installed on the top of the tank riser and sends the incident laser beam to the bottom of the tank, 10 - 70 feet away. The returning light containing chemical information is collected by the Raman probe and is transmitted via fiber optic cable to the spectrometer located outside the tank farm area. This dual remote technology significantly expands currently limited options for the safe rapid in-situ identification of the solid tank waste needed for the retrieval decisions. The developed Raman system was extensively tested for acceptability prior to tank farm deployment. This testing included calibration of the system with respect of the distance between the Raman probe and the sample, incident laser beam angle, and presence of the optical interferences. The Raman system was successfully deployed on Tank C-111 at the US DOE Hanford site. As the result of this deployment, the composition of the hardpan at the bottom of C-111 tank was identified. Further development of the dual-remote Raman technology will provide a significant safety enhancement eliminating the potential of personnel radiation exposure associated with the grab sample collection and expands options of the rapid and cost-effective in-situ chemical analysis of the tank waste. (authors)

Bryan, Sam; Levitskaia, Tatiana; Lines, Amanda; Smith, Frannie; Josephson, Gary [Pacific Northwest National Laboratory, Richland WA, 99352 (United States)] [Pacific Northwest National Laboratory, Richland WA, 99352 (United States); Bello, Job [EIC, Inc., Norwood, MA 02062 (United States)] [EIC, Inc., Norwood, MA 02062 (United States)

2013-07-01T23:59:59.000Z

104

Pyrolysis Gas Chromatography Mass Spectrometry Studies to Evaluate High-Temperature Aqueous Pretreatment as a Way to Modify the Composition of Bio-Oil from Fast Pyrolysis of Wheat Straw  

Science Journals Connector (OSTI)

Pyrolysis Gas Chromatography Mass Spectrometry Studies to Evaluate High-Temperature Aqueous Pretreatment as a Way to Modify the Composition of Bio-Oil from Fast Pyrolysis of Wheat Straw ... ?-Cellulose was obtained from Sigma-Aldrich (St. Louis, Missouri). ... This evidence suggests that CHW pretreatment may produce bio-oil that is composed of a greater amount of sugars and furanics and fewer small molecules and may therefore be a viable option to modify the chemical composition of bio-oils. ...

Robert Lee Johnson; Shi-Shen Liaw; Manuel Garcia-Perez; Su Ha; Sean S.-Y. Lin; Armando G. McDonald; Shulin Chen

2009-10-07T23:59:59.000Z

105

A study on Raman Injection Laser  

E-Print Network [OSTI]

The Raman Injection Laser is a new type of laser which is based on triply resonant stimulated Raman scattering between quantum confined states within the active region of a Quantum Cascade Laser that serves as an internal optical pump. The Raman...

Liu, Debin

2005-11-01T23:59:59.000Z

106

JOURNAL OF RAMAN SPECTROSCOPY J. Raman Spectrosc. 2003; 34: 769775  

E-Print Network [OSTI]

Science (www.interscience.wiley.com). DOI: 10.1002/jrs.1051 Raman spectroscopic study of spodumene (LiAlSi2O6 spectrum of a natural specimen of the pyroxene spodumene, from its low-pressure (C2/c) to its high, was not observed. Copyright 2003 John Wiley & Sons, Ltd. KEYWORDS: spodumene; pyroxene; pressure-induced phase

Downs, Robert T.

107

Detailed compositional analysis of gas seepage at the National Carbon Storage Test Site, Teapot Dome, Wyoming, USA  

Science Journals Connector (OSTI)

A baseline determination of CO2 and CH4 fluxes and soil gas concentrations of CO2 and CH4 was made over the Teapot Dome oil field in the Naval Petroleum Reserve No. 3 (NPR-3) in Wyoming, USA. This was done in anticipation of experimentation with CO2 sequestration in the Pennsylvanian Tensleep Sandstone underlying the field at a depth of 1680 m. The baseline data were collected during the winter, 2004 in order to minimize near-surface biological activity in the soil profile. The baseline data were used to select anomalous locations that may be the result of seeping thermogenic gas, along with background locations. Five 10-m holes were drilled, 3 of which had anomalous gas microseepage, and 2 were characterized as “background.” These were equipped for nested gas sampling at depths of 10-, 5-, 3-, 2-, and 1-m depths. Methane concentrations as high as 170,000 ppmv (17%) were found, along with high concentrations of C2H6, C3H8, n-C4H10, and i-C4H10. Much smaller concentrations of C2H4 and C3H6 were observed indicating the beginning of hydrocarbon oxidation in the anomalous holes. The anomalous 10-m holes also had high concentrations of isotopically enriched CO2, indicating the oxidation of hydrocarbons. Concentrations of the gases decreased upward, as expected, indicating oxidation and transport into the atmosphere. The ancient source of the gases was confirmed by 14C determinations on CO2, with radiocarbon ages approaching 38 ka within 5 m of the surface. Modeling was used to analyze the distribution of hydrocarbons in the anomalous and background 10-m holes. Diffusion alone was not sufficient to account for the hydrocarbon concentration distributions, however the data could be fit with the addition of a consumptive reaction. First-order rate constants for methanotrophic oxidation were obtained by inverse modeling. High rates of oxidation were found, particularly near the surface in the anomalous 10-m holes, demonstrating the effectiveness of the process in the attenuation of CH4 microseepage. The results also demonstrate the importance of CH4 measurements in the planning of a monitoring and verification program for geological CO2 sequestration in sites with significant remaining hydrocarbons (i.e. spent oil reservoirs).

Ronald W. Klusman

2006-01-01T23:59:59.000Z

108

Inversion-free, noiseless Raman echoes  

E-Print Network [OSTI]

Using double optical Raman rephasing, an inversion-free resonant Raman echo is studied in an inhomogeneously broadened spin ensemble of a solid medium, where the Raman optical field-excited spin coherence has a frozen propagation vector. Unlike photon echoes whose quantum memory application is strictly limited due to \\pi rephasing pulse-induced population inversion causing quantum noises, the optical Raman field-excited spin echo is inherently silent owing to the frozen propagation vector. Thus, the doubly rephased Raman echo can be directly applied for quantum interface in a population inversion-free environment.

Byoung S. Ham

2011-11-20T23:59:59.000Z

109

Correlation of rocket propulsion fuel properties with chemical composition using comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry followed by partial least squares regression analysis  

SciTech Connect (OSTI)

There is an increased need to more fully assess and control the composition of kerosene based rocket propulsion fuels, namely RP-1 and RP-2. In particular, it is crucial to be able to make better quantitative connections between the following three attributes: (a) fuel performance, (b) fuel properties (flash point, density, kinematic viscosity, net heat of combustion, hydrogen content, etc) and (c) the chemical composition of a given fuel (i.e., specific chemical compounds and compound classes present as a result of feedstock blending and processing). Indeed, recent efforts in predicting fuel performance through modeling put greater emphasis on detailed and accurate fuel properties and fuel compositional information. In this regard, advanced distillation curve (ADC) metrology provides improved data relative to classical boiling point and volatility curve techniques. Using ADC metrology, data obtained from RP-1 and RP-2 fuels provides compositional variation information that is directly relevant to predictive modeling of fuel performance. Often, in such studies, one-dimensional gas chromatography (GC) combined with mass spectrometry (MS) is typically employed to provide chemical composition information. Building on approaches using GC-MS, but to glean substantially more chemical composition information from these complex fuels, we have recently studied the use of comprehensive two dimensional gas chromatography combined with time-of-flight mass spectrometry (GC × GC - TOFMS) to provide chemical composition data that is significantly richer than that provided by GC-MS methods. In this report, by applying multivariate data analysis techniques, referred to as chemometrics, we are able to readily model (correlate) the chemical compositional information from RP-1 and RP-2 fuels provided using GC × GC - TOFMS, to the fuel property information such as that provided by the ADC method and other specification properties. We anticipate that this new chemical analysis strategy will have broad implications for the development of high fidelity composition-property models, leading to an optimized approach to fuel formulation and specification for advanced engine cycles.

Kehimkar, Benjamin; Hoggard, Jamin C.; Marney, Luke C.; Billingsley, Matthew; Fraga, Carlos G.; Bruno, Thomas J.; Synovec, Robert E.

2014-01-31T23:59:59.000Z

110

A thermodynamic model for calculating nitrogen solubility, gas phase composition and density of the N2–H2O–NaCl system  

Science Journals Connector (OSTI)

A thermodynamic model is presented to calculate N2 solubility in pure water (273–590 K and 1–600 bar) and aqueous NaCl solutions (273–400 K, 1–600 bar and 0–6 mol kg?1) with or close to experimental accuracy. This model is based on a semi-empirical equation used to calculate gas phase composition of the H2O–N2 system and a specific particle interaction theory for liquid phase. With the parameters evaluated from N2–H2O–NaCl system and using a simple approach, the model is extended to predict the N2 solubility in seawater accurately. Liquid phase density of N2–H2O–NaCl system at phase equilibrium and the homogenization pressure of fluid inclusions containing N2–H2O–NaCl can be calculated from this model. A computer code is developed for this model and can be downloaded from the website: www.geochem-model.org/programs.htm.

Shide Mao; Zhenhao Duan

2006-01-01T23:59:59.000Z

111

Raman activity in synchronously dividing bacteria  

SciTech Connect (OSTI)

Using a spectrometer equipped with an optical-multichannel analyzer as the detector (OMA), we have observed the Stokes laser-Raman spectra of metabolically active Escherichia coli and Bacillus megaterium from 100 - 2100 cm/sup -1/. After lengthy investigation, no Raman lines attributable to the metabolic process nor the cells themselves were found. Previous Raman spectra of active bacteria cannot be used to support nonlinear theories in biology. 34 refs., 9 figs.

Layne, S.P.

1985-01-01T23:59:59.000Z

112

An Automated Raman Device for Gout Diagnosis  

Science Journals Connector (OSTI)

This study reports an automated Raman device to identify crystals in synovial aspirates from patients with gout symptoms. Combined with sample preparation, the device could diagnose...

Li, Bolan

113

Raman and XPS characterization of fuel-cladding interactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

interactions using miniature specimens. Raman and XPS characterization of fuel-cladding interactions using miniature specimens. Abstract: Laser Raman spectroscopy was...

114

Operando Raman and Theoretical Vibration Spectroscopy of Non...  

Broader source: Energy.gov (indexed) [DOE]

Operando Raman and Theoretical Vibration Spectroscopy of Non-PGM Catalysts Operando Raman and Theoretical Vibration Spectroscopy of Non-PGM Catalysts Presentation about...

115

Adiabatic Tip-Plasmon Focusing for Nano-Raman Spectroscopy. ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adiabatic Tip-Plasmon Focusing for Nano-Raman Spectroscopy. Adiabatic Tip-Plasmon Focusing for Nano-Raman Spectroscopy. Abstract: True nanoscale optical spectroscopy requires the...

116

Multiphonon Raman scattering in graphene  

Science Journals Connector (OSTI)

We report on multiphonon Raman scattering in graphene samples. Higher-order combination modes involving three and four phonons are observed in single-layer, bilayer, and few-layer graphene samples prepared by mechanical exfoliation. The intensity of the higher-order phonon modes (relative to the G peak) is highest in single-layer graphene and decreases with increasing layers. In addition, all higher-order modes are observed to upshift in frequency almost linearly with increasing graphene layers, betraying the underlying interlayer van der Waals interactions.

Rahul Rao; Derek Tishler; Jyoti Katoch; Masa Ishigami

2011-09-12T23:59:59.000Z

117

Raman scattering from sp2 carbon clusters  

Science Journals Connector (OSTI)

Raman spectra of B ion-implanted glassy carbon (GC) and hydrogenated amorphous carbon (a-C:H) films have been measured as a function of polarization direction of the scattered light and excitation wavelength. Raman bands of GC implanted heavily with a fluence of more than 5×1015 B ions/cm2 and a-C:H films show a frequency-independent depolarization ratio, suggesting the existence of sp2 carbon clusters in these samples. It was found that Raman spectra of GC implanted heavily with a fluence of more than 5×1015 B ions/cm2 varied with the excitation wavelength. From a comparative study of the heavily implanted GC and a-C:H films, the variation of the Raman spectra with the excitation wavelength observed for the heavily implanted GC is interpreted in terms of ?-?* resonant Raman scattering from sp2 carbon clusters having various sizes.

M. Yoshikawa; N. Nagai; M. Matsuki; H. Fukuda; G. Katagiri; H. Ishida; A. Ishitani; I. Nagai

1992-09-15T23:59:59.000Z

118

Raman Spectra of Polyatomic Gases  

Science Journals Connector (OSTI)

Raman spectra of gaseous CO2, N2O, NH3, CH4 and C2H4 have been photographed using the line ?2536 of mercury as the exciting radiation. Vibrational transitions have been observed in all the gases investigated, and rotational transitions in the cases of NH3 and CH4. For the frequency shifts due to the vibrational transitions, the following numerical values (in cm-1) have been found: CO2: 1264.5; 1285.1; 1387.7; 1408.4.CH4: 2914.8; 3022.1; 3071.5.N2O: 1281.8C2H4: 1342.4; 1623.3; 2880.1; 3019.3; 3240.3; 3272.3.NH3: 3333.6  Raman spectra of liquid NH3 have been photographed and found to give the two frequency shifts: 3298.4 and 3214.5. In the case of gaseous NH3, pure rotational transitions lead to a moment of inertia having the value I0=2.79×10-40. In the case of methane, the positive and negative branches of the 3022.1 band lead to the value I0=5.17×10-40. The relations between these data and infra-red absorption data are discussed.

R. G. Dickinson, R. T. Dillon, and F. Rasetti

1929-08-15T23:59:59.000Z

119

Pulsed-laser-excited Raman spectra of shock-compressed triaminotrinitrobenzene  

SciTech Connect (OSTI)

Pulsed-laser-excited Raman scattering methods have been used to examine sustained shock compression of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) at an optical window interface. Records of vibrational frequency shifts and line shape changes have been obtained under variable and well-controlled shock loading using a 63-mm-diameter compressed gas gun to provide a planar impact geometry. To facilitate interpretation of the shock data. Raman spectra of TATB samples at elevated temperatures and ambient pressure have also been acquired. Raman modes identified with the nitro and amino groups in TATB exhibit complex behavior arising from interactions associated with the extensive intra- and intermolecular hydrogen bonding network in this material. The distinct (and frequently competing) effects of pressure and temperature on these modes are discussed in relation to the known insensitivity of TATB to shock initiation. 20 refs., 9 figs.

Trott, W.M.; Renlund, A.M. (Sandia National Labs., Albuquerque, NM (USA))

1989-01-01T23:59:59.000Z

120

Gas condensate damage in hydraulically fractured wells  

E-Print Network [OSTI]

a 2D 1-phase simulator in order to help us to better understand the results of gas condensate simulation. Then during the research, gas condensate models with various gas compositions were simulated using a commercial simulator (CMG). The results...

Reza, Rostami Ravari

2004-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Landfill Gas Fueled HCCI Demonstration System  

E-Print Network [OSTI]

Journal of Engineering for Gas Turbines and Power, 121:569-operations with natural gas: Fuel composition implications,”USA ICEF2006-1578 LANDFILL GAS FUELED HCCI DEMONSTRATION

Blizman, Brandon J.; Makel, Darby B.; Mack, John Hunter; Dibble, Robert W.

2006-01-01T23:59:59.000Z

122

Inelastic neutron and low-frequency Raman scattering in a niobium-phosphate glass for Raman gain applications  

E-Print Network [OSTI]

Inelastic neutron and low-frequency Raman scattering in a niobium-phosphate glass for Raman gain: Raman scattering; Neutron scattering; Raman gain; Boson peak We present measurements of the vibrational, extracted from specific-heat or neutron scattering measurements [7,8]. Only very recently two of the present

Schirmacher, Walter

123

Natural Gas Monthly Update  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

issues Go CorrectionUpdate February 22, 2013 Two Year-To-Date values, for 2010 NGL Composite Spot Price and Natural Gas Spot Price, were incorrectly displayed in Table 3. These...

124

Acidic gas capture by diamines  

DOE Patents [OSTI]

Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

2011-05-10T23:59:59.000Z

125

Raman lidar and MPL Measurements during ALIVE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Raman lidar and MPL Measurements during ALIVE Raman lidar and MPL Measurements during ALIVE Ferrare, Richard NASA Langley Research Center Turner, David University of Wisconsin-Madison Flynn, Connor Pacific Northwest National Laboratory Petty, Diana Pacific Northwest National Laboratory Mendoza, Albert Pacific Northwest National Laboratory Clayton, Marian NASA Langley Research Center Schmid, Beat Bay Area Environmental Research Institute Category: Field Campaigns Analysis of the aerosol and water vapor data collected by the Raman lidar during the May 2003 Aerosol IOP indicated that the sensitivity of the lidar was significantly lower than when the lidar was initially deployed. This decrease in sensitivity contributed to a significant high bias of the Raman lidar aerosol extinction measurements in relation to airborne Sun

126

Raman lidar/AERI PBL Height Product  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Planetary Boundary Layer (PBL) heights have been computed using potential temperature profiles derived from Raman lidar and AERI measurements. Raman lidar measurements of the rotational Raman scattering from nitrogen and oxygen are used to derive vertical profiles of potential temperature. AERI measurements of downwelling radiance are used in a physical retrieval approach (Smith et al. 1999, Feltz et al. 1998) to derive profiles of temperature and water vapor. The Raman lidar and AERI potential temperature profiles are merged to create a single potential temperature profile for computing PBL heights. PBL heights were derived from these merged potential temperature profiles using a modified Heffter (1980) technique that was tailored to the SGP site (Della Monache et al., 2004). PBL heights were computed on an hourly basis for the period January 1, 2009 through December 31, 2011. These heights are provided as meters above ground level.

Ferrare, Richard

127

Simultaneous Neutron Scattering and Raman Scattering  

Science Journals Connector (OSTI)

The capability to make simultaneous neutron and Raman scattering measurements at temperatures between 1.5 and 450 K has been developed. The samples to be investigated are attached to...

Adams, Mark A; Parker, Stewart F; Fernandez-Alonso, Felix; Cutler, David J; Hodges, Christopher; King, Andrew

2009-01-01T23:59:59.000Z

128

Identification of minerals and meteoritic materials via Raman techniques after capture in hypervelocity impacts on aerogel  

SciTech Connect (OSTI)

For this study, an extensive suite of mineral particles analogous to components of cosmic dust were tested to determine if their Raman signatures can be recognized after hypervelocity capture in aerogel. The mineral particles were mainly of greater than 20 micrometers in size and were accelerated onto the silica aerogel by light gas gun shots. It was found that all the individual minerals captured in aerogel could be subsequently identified using Raman (or fluorescent) spectra. The beam spot size used for the laser illumination was of the order of 5 micrometers, and in some cases the captured particles were of a similar small size. In some samples fired into aerogel there was observed a shift in the wavenumbers of some of the Raman bands, a result of the trapped particles being at quite high temperatures due to heating by the laser. Temperatures of samples under laser illumination were estimated from the relative intensities of Stokes and anti-Stokes Raman bands, or, in the case of ruby particles, from the wavenumber of fluorescence bands excited by the laser. It was found that the temperature of particles in aerogel varied greatly, dependent upon laser power and the nature of the particle. In the worst case, some particles were shown to have temperatures in the 500-700 C range at a laser power of about 3 mW at the sample. However most of the mineral particles examined at this laser power had temperatures below 200 C. This is sufficiently low a temperature not to damage most materials expected to be found captured in aerogel in space. In addition, selected meteorite samples were examined to obtain Raman signatures of their constituent minerals and were then shot into aerogel. It was possible to find several Raman signatures after capture in aerogel and obtain a Raman map of a whole grain in situ in the aerogel. Finally, a Raman analysis was carried out of a particle captured in aerogel in space and carbonaceous material identified. In general therefore it is concluded that Raman analysis is indeed well suited for an in-situ analysis of micrometer sized non-terrestrial materials captured in aerogel.

Burchell, M J; Mann, J; Creighton, J A; Kearsley, A; Graham, G A; Esposito, A P; Franchi, I A; Westphal, A J; Snead, C

2004-10-04T23:59:59.000Z

129

Modeling of multiphase behavior for gas flooding simulation.  

E-Print Network [OSTI]

??Miscible gas flooding is a common method for enhanced oil recovery. Reliable design of miscible gas flooding requires compositional reservoir simulation that can accurately predict… (more)

Okuno, Ryosuke, 1974-

2011-01-01T23:59:59.000Z

130

Ultraviolet Resonant Raman Enhancements in the Detection of Explosives  

SciTech Connect (OSTI)

Raman-based spectroscopy is potentially militarily useful for standoff detection of high explosives. Normal (non-resonance) and resonance Raman spectroscopies are both light scattering techniques that use a laser to measure the vibrational spectrum of a sample. In resonance Raman, the laser is tuned to match the wavelength of a strong electronic absorbance in the molecule of interest, whereas, in normal Raman the laser is not tuned to any strong electronic absorbance bands. The selection of appropriate excitation wavelengths in resonance Raman can result in a dramatic increase in the Raman scattering efficiency of select band(s) associated with the electronic transition. Other than the excitation wavelength, however, resonance Raman is performed experimentally the same as normal Raman. In these studies, normal and resonance Raman spectral signatures of select solid high explosive (HE) samples and explosive precursors were collected at 785 nm, 244 nm and 229 nm. Solutions of PETN, TNT, and explosive precursors (DNT & PNT) in acetonitrile solvent as an internal Raman standard were quantitatively evaluated using ultraviolet resonance Raman (UVRR) microscopy and normal Raman spectroscopy as a function of power and select excitation wavelengths. Use of an internal standard allowed resonance enhancements to be estimated at 229 nm and 244 nm. Investigations demonstrated that UVRR provided {approx}2000-fold enhancement at 244 nm and {approx}800-fold improvement at 229 nm while PETN showed a maximum of {approx}25-fold at 244 nm and {approx}190-fold enhancement at 229 nm solely from resonance effects when compared to normal Raman measurements. In addition to the observed resonance enhancements, additional Raman signal enhancements are obtained with ultraviolet excitation (i.e., Raman scattering scales as !4 for measurements based on scattered photons). A model, based partly on the resonance Raman enhancement results for HE solutions, is presented for estimating Raman enhancements for solid HE samples.

Short, B J; Carter, J C; Gunter, D; Hovland, P; Jagode, H; Karavanic, K; Marin, G; Mellor-Crummey, J; Moore, S; Norris, B; Oliker, L; Olschanowsky, C; Roth, P C; Schulz, M; Shende, S; Snavely, A; Spear, W

2009-06-03T23:59:59.000Z

131

Coherent Anti-Stokes Raman Spectroscopy of Radio-Frequency Discharge Plasmas of Silane and Disilane  

Science Journals Connector (OSTI)

Coherent anti-Stokes Raman spectroscopy has been employed for the diagnosis of rf discharges of silane (SiH4) and disilane (Si2H6). The signal intensities from silane and disilane have been measured as a function of time after switching-on the rf power supplied to SiH4 and Si2H6 gas in a closed reaction chamber. From this measurement, the loss rates of silane and disilane have been determined directly as functions of the rf-power density and gas pressure for the first time. The rate of formation of SiH4 in disilane discharge plasmas has also been determined.

Nobuhiro Hata; Akihisa Matsuda; Kazunobu Tanaka

1986-01-01T23:59:59.000Z

132

Raman-resonant four-wave mixing and energy transfer  

Science Journals Connector (OSTI)

A common assumption that Raman-resonant four-wave mixing does not transfer energy between the light and the Raman medium is shown to be incorrect. The derivation of the correct...

Bobbs, Bradley; Warner, Charles

1990-01-01T23:59:59.000Z

133

Multistaged stokes injected Raman capillary waveguide amplifier  

DOE Patents [OSTI]

A multistaged Stokes injected Raman capillary waveguide amplifier for providing a high gain Stokes output signal. The amplifier uses a plurality of optically coupled capillary waveguide amplifiers and one or more regenerative amplifiers to increase Stokes gain to a level sufficient for power amplification. Power amplification is provided by a multifocused Raman gain cell or a large diameter capillary waveguide. An external source of CO.sub.2 laser radiation can be injected into each of the capillary waveguide amplifier stages to increase Raman gain. Devices for injecting external sources of CO.sub.2 radiation include: dichroic mirrors, prisms, gratings and Ge Brewster plates. Alternatively, the CO.sub.2 input radiation to the first stage can be coupled and amplified between successive stages.

Kurnit, Norman A. (Santa Fe, NM)

1980-01-01T23:59:59.000Z

134

Double resonance surface enhanced Raman scattering substrates: an intuitive coupled  

E-Print Network [OSTI]

. Westcott, L. R. Hirsch, J. L. West, and N. J. Halas, "Controlling the surface enhanced Raman effect via

135

Solar composition from the Genesis Discovery Mission  

Science Journals Connector (OSTI)

Solar composition from the Genesis Discovery Mission...gases differ in the Sun from other inner solar system objects. The N isotopic composition...discrepancies in the noble gas data from solar wind implanted in lunar soils. (ii) The...

D. S. Burnett; Genesis Science Team

2011-01-01T23:59:59.000Z

136

Raman Spectrum of Graphene and Graphene Layers  

Science Journals Connector (OSTI)

Graphene is the two-dimensional building block for carbon allotropes of every other dimensionality. We show that its electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers. The D peak second order changes in shape, width, and position for an increasing number of layers, reflecting the change in the electron bands via a double resonant Raman process. The G peak slightly down-shifts. This allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.

A. C. Ferrari; J. C. Meyer; V. Scardaci; C. Casiraghi; M. Lazzeri; F. Mauri; S. Piscanec; D. Jiang; K. S. Novoselov; S. Roth; A. K. Geim

2006-10-30T23:59:59.000Z

137

Transient Impulsive Giant Electronic Raman Redistribution  

E-Print Network [OSTI]

Resonant Raman excitation by ultrafast vacuum ultraviolet laser pulses is a powerful means to study electron dynamics in molecules, but experiments must contend with linear background ionization: frequencies high enough to reach resonant core-valence transitions will usually ionize all occupied orbitals as well, and the ionization cross sections are usually dominant. Here we show that attosecond pulses can induce a new process, transient impulsive stimulated Raman scattering, which can overwhelm valence ionization. Calculations are performed for atomic sodium, but the principal is valid for many molecular systems. This approach opens the path for high fidelity multidimensional spectroscopy with attosecond pulses.

Miyabe, S

2014-01-01T23:59:59.000Z

138

Raman approach in silicon nanostructure at 1.5 micron  

Science Journals Connector (OSTI)

In the last three years, the possibility of light generation and/or amplification in silicon, based on Raman emission, has achieved significant results. However, limitations inherent to the physics of silicon have been pointed out, too. In order to overcome ... Keywords: Raman amplifiers, Raman effect, nonlinear optics, porous silicon

L. Sirleto; M. A. Ferrara; B. Jalali; I. Rendina

2007-09-01T23:59:59.000Z

139

Vibrational Raman Spectroscopy of High-temperature Superconductors  

E-Print Network [OSTI]

Vibrational Raman Spectroscopy of High-temperature Superconductors C. Thomsen and G. Kaczmarczyk after the discovery of high- critical-temperature Tc superconductors:2 while reports on Raman scattering Wiley & Sons Ltd, Chichester, 2002 #12;Vibrational Raman Spectroscopy of High-temperature

Nabben, Reinhard

140

Special Section Guest Editorial Coherent Raman Imaging Techniques and Biomedical  

E-Print Network [OSTI]

Special Section Guest Editorial Coherent Raman Imaging Techniques and Biomedical Applications. The combination of high resolution and molecular contrast has moved Raman techniques into the biomedical spotlight on biomedical imag- ing. The spontaneous Raman interaction is weak, yielding insufficient photons for fast

Potma, Eric Olaf

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Fiber Reinforced Polymer Composite Manufacturing Workshop: Summary...  

Energy Savers [EERE]

for carbon fiber, including bio-based materials or natural gas; lower energy conversion of white fiber to carbon fiber; and composite manufacturing. Dr. Johnson then...

142

Rapid Research Note Raman Scattering in Resonance  

E-Print Network [OSTI]

-uniformity in the ternary alloy InGaN [4, 5]. However, resonance Raman scattering at bound excitons as reported for CdS doped 220 mm thick GaN film grown by hydride vapor phase epitaxy. Sapphire (0001) with a sputtered Zn

Nabben, Reinhard

143

Raman laser with controllable suppression of parasitics  

DOE Patents [OSTI]

Method and apparatus for switching energy out of a Raman laser optical cavity. Coherent radiation at both the pump and first Stokes wave frequencies are introduced into the optical cavity from the same direction, and a second Stokes wave is utilized to switch the energy out of the cavity.

George, E. Victor (Livermore, CA)

1986-01-01T23:59:59.000Z

144

Secondary ion mass spectrometry and Raman spectroscopy for tissue engineering applications  

Science Journals Connector (OSTI)

Identifying the matrix properties that permit directing stem cell fate is crucial for expanding desired cell lineages ex vivo for disease treatment. Such efforts require knowledge of matrix surface chemistry and the cell responses they elicit. Recent progress in analyzing biomaterial composition and identifying cell phenotype with two label-free chemical imaging techniques, TOF-SIMS and Raman spectroscopy are presented. TOF-SIMS is becoming indispensable for the surface characterization of biomaterial scaffolds. Developments in TOF-SIMS data analysis enable correlating surface chemistry with biological response. Advances in the interpretation of Raman spectra permit identifying the fate decisions of individual, living cells with location specificity. Here we highlight this progress and discuss further improvements that would facilitate efforts to develop artificial scaffolds for tissue regeneration.

Yelena Ilin; Mary L Kraft

2015-01-01T23:59:59.000Z

145

Raman spectroscopic studies of shock-compressed nitromethane and nitromethane-d/sub 3/  

SciTech Connect (OSTI)

Single-pulse Raman spectroscopy has been used to examine the effect of shock compression on the C-N stretching modes near 900 cm/sup /minus/1/ in a 50/50 mixture of nitromethane (NM) and perdeutero nitromethane (NM-d/sub 3/). Samples were shocked in a single step to pressures as high as 6.8 GPa using a compressed gas gun driver. Spectra up to 5.5 GPa showed he expected pressure-induced shifting of the Raman frequencies; at higher pressures the lines were significantly broadened and the frequency shift was reversed, indicating the initial stages of reaction. In no instance did we see significant isotopic exchange as would be evidenced by alteration of the relative line intensities. 6 refs., 3 figs., 1 tab.

Renlund, A.M.; Trott, W.M.

1989-01-01T23:59:59.000Z

146

Importance of aerosol composition, mixing state, and morphology for heterogeneous ice nucleation: A combined field and laboratory approach  

E-Print Network [OSTI]

In this study chemical compositions of background aerosol and ice nuclei were examined through laboratory investigations using Raman spectroscopy and field measurements by single-particle mass spectrometry. Aerosol sampling ...

Baustian, Kelly J.

147

Gas Sampling | Open Energy Information  

Open Energy Info (EERE)

Gas Sampling Gas Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Gas Sampling Details Activities (7) Areas (7) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Field Sampling Parent Exploration Technique: Field Sampling Information Provided by Technique Lithology: Stratigraphic/Structural: High flux can be indicative of conduits for fluid flow. Hydrological: Gas composition and source of fluids. Thermal: Anomalous flux is associated with active hydrothermal activity. Distinguish magmatic/mantle heat inputs. Can be used to estimate reservoir fluid temperatures. Dictionary.png Gas Sampling: Gas sampling is done to characterize the chemical, thermal, and hydrological properties of a surface or subsurface hydrothermal system.

148

Gas Atomization of Amorphous Aluminum: Part I. Thermal Behavior Calculations  

E-Print Network [OSTI]

which are summarized below: 1. Gas composition is moree?ective than gas pressure on in?uencing cooling rate for app. 210–11. 37. J.E.A. John: Gas Dynamics, Allyn and Bacon,

Zheng, Baolong; Lin, Yaojun; Zhou, Yizhang; Lavernia, Enrique J.

2009-01-01T23:59:59.000Z

149

Raman study of some melilites in crystalline and glassy states  

SciTech Connect (OSTI)

Raman spectra are reported for crystalline akermanite, hardystonite, gehlenite, sodium melilite and for glasses of corresponding compositions. The spectra of melilites are dominated by the vibrational modes of pyrosilicate units and not by the sheet-like structure formed by interconnected TMO{sub 4} tetrahedra. The frequency of {nu}{sub s}(T-O-T), the symmetric stretching mode of the bridging oxygen in the pyrosilicate unit, is directly related to the angle of the T-O-T linkage. The symmetric stretching bands of nonbridging oxygens {nu}{sub s}(T-O{sup {minus}}) appear in the spectral range characteristic of T-O{sup {minus}} stretching in pyrosilicate units. The intensity of the {nu}{sub s}(T-O{sup {minus}}) band is, however, affected by the presence of Al{sup 3+} in tetrahedral sites adjacent to the pyrosilicate units. The lowering of the intensities of nonbridging oxygen stretching bands in the spectra of Geh and SM is attributed to a change in the degree of covalency of T-O{sup {minus}} bonds in the pyrosilicate unit resulting from substitution of Al{sup 3+} for Mg{sup 2+} in the adjacent tetrahedral sites. Comparison of the spectra of crystals with glasses indicates that most Al{sup 3+} ions act as network-forming cations, whereas Mg{sup 2+}, Zn{sup 2+} and Ca{sup 2+} retain their role as network modifiers. Spectra of glasses of Ak and Har composition show SiO{sub 4}{sup 4{minus}} and Si{sub 2}O{sub 7}{sup 6{minus}} bands, indicating a redistribution of silicate species among monomer, dimer, trimer and tetramer chains. Glasses of Geh and SM compositions are more highly polymerized than their respective crystalline counterparts because of the role of Al{sup 3+} as network-forming cations in the glass structures.

Sharma, S.K.; Matson, D.W. (Hawaii Institute of Geophysics, Honolulu (USA)); Yoder, H.S. Jr. (Geophysical Lab., Washington, DC (USA))

1988-08-01T23:59:59.000Z

150

Correlated excitations and Raman scattering in glasses  

Science Journals Connector (OSTI)

The dominant Raman line in AX2 tetrahedral glasses is demonstrated to be caused by correlated symmetric stretch motions of the bridging X atoms. Using a bond-polarizability model and the central-force model of Sen and Thorpe, we derive simple analytic forms for Raman spectra. We show that correlations may cause qualitative changes in the polarized spectrum leading to a peak at the edge of a band of vibrational states, whereas the depolarized spectrum is less affected and mimics the density of states. Both features are clearly observed in GeO2 and explain features in many other glasses. The same reasoning leads to a prediction of unusual spectral features in electronic spectra of disordered solids which may be observable in angular-dependent photoemission.

Richard M. Martin and Frank L. Galeener

1981-03-15T23:59:59.000Z

151

Natural catalytic activity in a marine shale for generating natural gas  

Science Journals Connector (OSTI)

...natural catalytic activity in marine shales. Gas is generated at ambient temperatures...differences are in degree. Mowry shale generates gas compositions that are quite different...probably a major source of natural gas. Mowry shale generates gas at thermodynamic...

2010-01-01T23:59:59.000Z

152

Raman spectroscopy study of selected uranophanes  

Science Journals Connector (OSTI)

Raman spectra at 298 and 77 K of three uranophane samples from different localities are described and interpreted. The spectra are sample dependent. U–O bond lengths in uranyls are calculated from the spectra and compared with the published data of single crystal structure and EXAFS spectroscopy. Hydrogen-bonding of water molecules and silanols is discussed and the ‘proton mobility’ in uranophane sheet crystal structure is assumed.

Ray L. Frost; Ji?í ?ejka; Matt L. Weier; Wayde N. Martens

2006-01-01T23:59:59.000Z

153

Accelerated Testing of HT-9 with Zirconia Coatings Containing Gallium using Raman Spectroscopy and XPS  

SciTech Connect (OSTI)

Laser Raman spectroscopy and x-ray photoelectron spectroscopy were used to study the evolution of composition of oxide films in the presence of zirconia coatings on miniature HT-9 alloy specimens subjected to elevated temperature in air. The experiments expanded on previous efforts to develop a quick-screening technique for candidate alloys for cladding materials (HT-9) and actinide-based mixed oxide fuel mixtures (represented by the zirconia coating) by investigating the effect of both coating composition and alloy pretreatment conditions on the high temperature reactions. In particular, the presence of the element Ga (a potential impurity in mixed oxide fuel) in the initial zirconia coating was found to accelerate the rate of oxide growth relative to that of yttria-stabilized zirconia studied previously. In addition, HT-9 samples that were subjected to different thermal pretreatments gave different results. The results suggest that the presence of Ga in a mixed oxide fuel will enhance the corrosion of HT-9 cladding under the conditions of this study, although the extent of enhancement is influenced by thermal pretreatment of the cladding material. The results also demonstrate the need to combine Raman spectroscopy with other techniques, particularly photoelectron spectroscopy, for optimizing composition and/or fabrication conditions of both cladding and oxide fuels for advanced nuclear reactors.

Windisch, Charles F.; Henager, Charles H.; Engelhard, Mark H.; Bennett, Wendy D.

2009-12-01T23:59:59.000Z

154

Study of Multi-scale Transport Phenomena in Tight Gas and Shale Gas Reservoir Systems  

E-Print Network [OSTI]

. These challenges have impeded efficient economic development of shale resources. New fundamental insights and tools are needed to improve the state of shale gas development. Few attempts have been made to model the compositional behavior of fluids in shale gas...

Freeman, Craig Matthew

2013-11-25T23:59:59.000Z

155

Effect of Magnesite as Bed Material in a 100 kWth Steam?Oxygen Blown Circulating Fluidized-Bed Biomass Gasifier on Gas Composition and Tar Formation  

Science Journals Connector (OSTI)

Those issues, depending upon the type of the gasifier, are related to (1) scale of operation and availability of biomass, (2) size distribution of raw biomass, (3) operability of the gasifier with fuels containing large amounts of ash, especially if the fraction of alkali, chlorine, and sulfur is high,(2) (4) the formation of condensable higher hydrocarbons (tar), and (5) cleaning and upgrading of the gas for dedicated downstream application. ... The main characteristics of the rig are (i) reactor height, 5.5 m; (ii) riser inner diameter, 83 mm; downcomer inner diameter, 54 mm; material, stainless-steel AISI310, DIN 1.4845; (iii) fluidization medium electrical preheater (6 kW; Tmax = 400 °C; Tnom = 360 °C; Watlow, St. Louis, MO); (iv) electrical heating of the whole rig (22 kW; Tmax = 1200 °C; Tnom = 850 °C) using modular ceramic fiber heaters (ZMC Zamac, Poland); (v) high-temperature ceramic tissue candle filter unit (BWF, Germany) operating at 450 °C and a high-temperature Si?SiC ceramic candle filter (Pall-Schumacher, Germany) operating at 800 °C; (vi) feeding system with a maximum feed rate of ca. ... 200 and 470 ?m, while magnesite particle sizes are spread throughout the analysis domain; the fraction of fines in magnesite is significantly larger than in sand. ...

M. Siedlecki; R. Nieuwstraten; E. Simeone; W. de Jong; A. H. M. Verkooijen

2009-10-28T23:59:59.000Z

156

Compositions, devices and methods for SERS and LSPR  

DOE Patents [OSTI]

The present invention relates to compositions, devices and methods for detecting microorganisms (e.g., anthrax). In particular, the present invention provides portable, surface-enhanced Raman biosensors, and associated substrates, and methods of using the same, for use in rapidly detecting and identifying microorganisms (e.g., anthrax).

Van Duyne, Richard P; Zhang, Xiaoyu; Zhao, Jing; Whitney, Alyson V; Elam, Jeffrey W; Schatz, George C; Stair, Peter C; Zou, Shengli; Young, Matthew; Lyandres, Olga

2014-01-14T23:59:59.000Z

157

High-Speed Coherent Raman Fingerprint Imaging of Biological Tissues  

E-Print Network [OSTI]

We have developed a coherent Raman imaging platform using broadband coherent anti-Stokes Raman scattering (BCARS) that provides an unprecedented combination of speed, sensitivity, and spectral breadth. The system utilizes a unique configuration of laser sources that probes the Raman spectrum over 3,000 cm$^{-1}$ and generates an especially strong response in the typically weak Raman "fingerprint" region through heterodyne amplification of the anti-Stokes photons with a large nonresonant background (NRB) while maintaining high spectral resolution of $chemical imaging in two- and three-dimensional views of healthy murine liver and pancreas tissues and interfaces between xenograft brain tumors and the surrounding healthy brain matter.

Camp, Charles H; Heddleston, John M; Hartshorn, Christopher M; Walker, Angela R Hight; Rich, Jeremy N; Lathia, Justin D; Cicerone, Marcus T

2014-01-01T23:59:59.000Z

158

Graphene and its derivatives : fabrication and Raman spectroscopy study.  

E-Print Network [OSTI]

??This thesis presents results on fabrication and Raman spectroscopy studies of graphene and its derivates. The works can be divided into two parts as follows.… (more)

Cong, Chunxiao.

2012-01-01T23:59:59.000Z

159

Raman Lidar Measurements of Aerosols and Water Vapor During the...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

modifications reduced but could not eliminate these adverse effects. The Raman lidar water vapor (aerosol extinction) measurements produced by these modified algorithms were,...

160

MICROMECHANICS IN CONTINOUS GRAPHITE FIBER/EPOXY COMPOSITES DURING CREEP  

SciTech Connect (OSTI)

Micro Raman spectroscopy and classic composite shear-lag models were used to analyze the evolution with time of fiber and matrix strain/stress around fiber breaks in planar model graphite fiber-epoxy matrix composites. Impressive agreements were found between the model predictions and the experimental results. The local matrix creep leads to an increase in the load transfer length around the break under a constant load. This increases the chance of fiber breakage in the neighboring intact fibers.

C. ZHOU; ET AL

2001-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

OH/F substitution in topaz studied by Raman spectroscopy  

Science Journals Connector (OSTI)

The Raman band related to the stretching mode of hydroxyl (OH-) centered at about 3650 cm-1 is investigated in several natural specimens of topaz single crystals with a composition Al2SiO4(OHxF(1-x))2 within a wide range of OH mole fractions (x). The analysis of the OH band shape shows that its asymmetry is due to an unresolved splitting in two peaks, centered at 3639 and 3647 cm-1, labeled as OHA and OHB, respectively. Although the asymmetry is drastically different for OH-rich and OH-poor topaz, we show that this is only caused by the change of the OHA/OHB intensity ratio with the total OH concentration. In order to explain the splitting of the OH band, we suggest a model which involves a reduction of the local symmetry from D2h16 to C2v9, resulting in two types of physically nonequivalent F sites (A and B) where the OH/F substitution can occur. Both sites have C1 site symmetries and a multiplicity of 4.

M. V. B. Pinheiro; C. Fantini; K. Krambrock; A. I. C. Persiano; M. S. S. Dantas; M. A. Pimenta

2002-02-20T23:59:59.000Z

162

E-Print Network 3.0 - anti-stokes raman spectroscopic Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a coherent anti-Stokes Raman spectroscopic imaging device in which two laser pulse trains... . August 19, 2008 System and method for coherent anti-Stokes Raman scattering...

163

E-Print Network 3.0 - adeep-ultraviolet resonance raman Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Maruyama Summary: Temperature dependence of resonance Raman of single-walled carbon nanotubes Shohei Chiashi... , Mototeru Oba and Shigeo Maruyama Raman scattering from...

164

MODIFYING AN INVERTED LABORATORY MICROSCOPE FOR RAMAN Presented in Partial Fulfillment of the Requirements for  

E-Print Network [OSTI]

MODIFYING AN INVERTED LABORATORY MICROSCOPE FOR RAMAN MICROSCOPY A Thesis Presented in Partial modifications a spectroscopic imaging instrument, a Raman microscope, can be constructed from a common inverted

165

Raman Spectroscopy and Genetic Algorithms for the Classification of Wood Types  

Science Journals Connector (OSTI)

Raman spectroscopy and pattern recognition techniques are used to develop a potential method to characterize wood by type. The test data consists of 98 Raman spectra of temperate...

Lavine, B K; Davidson, C E; Moores, A J; Griffiths, P R

2001-01-01T23:59:59.000Z

166

Quantum-entanglement-initiated super Raman scattering  

SciTech Connect (OSTI)

It has now been possible to prepare a chain of ions in an entangled state and thus the question arises: How will the optical properties of a chain of entangled ions differ from say a chain of independent particles? We investigate nonlinear optical processes in such chains. Since light scattering is quite a versatile technique to probe matter, we explicitly demonstrate the possibility of entanglement-produced super Raman scattering. Our results suggest the possibility of similar enhancement factors in other nonlinear processes like four-wave mixing.

Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)

2011-02-15T23:59:59.000Z

167

Optical pumping via incoherent Raman transitions  

E-Print Network [OSTI]

A new optical pumping scheme is presented that uses incoherent Raman transitions to prepare a trapped Cesium atom in a specific Zeeman state within the 6S_{1/2}, F=3 hyperfine manifold. An important advantage of this scheme over existing optical pumping schemes is that the atom can be prepared in any of the F=3 Zeeman states. We demonstrate the scheme in the context of cavity quantum electrodynamics, but the technique is equally applicable to a wide variety of atomic systems with hyperfine ground-state structure.

A. D. Boozer; R. Miller; T. E. Northup; A. Boca; H. J. Kimble

2007-10-04T23:59:59.000Z

168

Natural Gas  

Science Journals Connector (OSTI)

30 May 1974 research-article Natural Gas C. P. Coppack This paper reviews the world's existing natural gas reserves and future expectations, together with natural gas consumption in 1972, by main geographic...

1974-01-01T23:59:59.000Z

169

Raman Measurements on Electrochemically Doped Single-Walled Carbon Nanotubes  

E-Print Network [OSTI]

Raman Measurements on Electrochemically Doped Single-Walled Carbon Nanotubes P. M. Rafailov, M and studied the Raman response of electro- chemically doped single-walled carbon nanotubes (SWNT) using different salt solutions. The fre- quency shift of the radial breathing mode (RBM) and the high-energy mode

Nabben, Reinhard

170

Shell-isolated nanoparticle-enhanced Raman spectroscopy  

E-Print Network [OSTI]

LETTERS Shell-isolated nanoparticle-enhanced Raman spectroscopy Jian Feng Li1 , Yi Fan Huang1 or in the form of nanoparticles, are required to realise a substantial SERS effect, and this has severely limited, we report an approach, which we name shell-isolated nanoparticle-enhanced Raman spectro- scopy

La Rosa, Andres H.

171

Hydrogen Raman shifts in carbon nanotubes from molecular dynamics simulation  

E-Print Network [OSTI]

Hydrogen Raman shifts in carbon nanotubes from molecular dynamics simulation S.J.V. Frankland *, D hydrogen in individual single-shell carbon nanotubes and nanotube ropes using a semiclassical model. The calculations predict that isolated hydrogen molecules inside of nanotubes have a Raman frequency that increases

Brenner, Donald W.

172

Surface Gas Sampling | Open Energy Information  

Open Energy Info (EERE)

Surface Gas Sampling Surface Gas Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Surface Gas Sampling Details Activities (12) Areas (10) Regions (1) NEPA(0) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Field Sampling Parent Exploration Technique: Gas Sampling Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Gas composition and source of fluids. Thermal: Distinguish magmatic/mantle heat inputs. Can be used to estimate reservoir fluid temperatures. Dictionary.png Surface Gas Sampling: Gas sampling is done to characterize the chemical, thermal, or hydrological properties of a surface or subsurface hydrothermal system. Other definitions:Wikipedia Reegle Introduction

173

Preparation of Ag{sub 2}S-Graphene nanocomposite from a single source precursor and its surface-enhanced Raman scattering and photoluminescent activity  

SciTech Connect (OSTI)

Ag{sub 2}S-Graphene nanocomposite was prepared via a relatively facile hydrothermal method, using a single-source molecular (silver diethyldithiocarbamate [Ag(DDTC)]) as precursor and graphene sheets as a support material. The composite was characterized by X-ray power diffraction, X-ray photoelectron spectroscopy, Field-emission scanning electron microscope, transmission electron microscopy, Fourier transform infrared, Raman spectra and fluorescence spectroscopy. The experimental results show that the Ag{sub 2}S-Graphene nanocomposite displays surface-enhanced Raman scattering (SERS) activity for graphene oxide and reveals relatively better fluorescence property compared with pure Ag{sub 2}S. Highlights: {yields} Ag{sub 2}S nanoparticles are deposited on graphene sheets via a single source precursor. {yields} Graphene oxide is reduced to graphene in the hydrothermal reaction process. {yields} Ag{sub 2}S-Graphene system displays surface-enhanced Raman scattering activity and relatively better fluorescence property.

Pan Shugang; Liu Xiaoheng, E-mail: xhliu@mail.njust.edu.cn; Wang Xin

2011-11-15T23:59:59.000Z

174

In situ Raman monitoring of He{sup 2+} irradiation induced damage in a UO{sub 2} ceramic  

SciTech Connect (OSTI)

The in situ Raman probing of a UO{sub 2} ceramic in [Ar/H{sub 2}, 95/5] gas atmosphere followed by exposure to He{sup 2+} ionic irradiation coming from a cyclotron accelerator was implemented. It was observed that the growth of Raman defect bands exhibits a unique kinetic nicely modelized by a simple direct impact model, and with an annealing rate constant of 5.6 × 10{sup ?4} ± 4 × 10{sup ?5} s{sup ?1} for an ionic flow of 50 nA and an ions-beam induced sample heating of 170 ± 10 °C. Also, it was observed that the Ar plasma induced by the ions-beam is a sensitive probe of the presence of the ions-beam.

Guimbretière, G.; Canizarès, A.; Duval, F.; Raimboux, N.; Omnée, R.; Ammar, M. R.; Simon, P. [CNRS/UPR3079 CEMHTI, 45071 Orléans Cedex 2 et Université d'Orléans, 45067 Orléans Cedex 2 (France)] [CNRS/UPR3079 CEMHTI, 45071 Orléans Cedex 2 et Université d'Orléans, 45067 Orléans Cedex 2 (France); Desgranges, L. [CEA/DEN/DEC Bat 352 Cadarache, 13108 Saint Paul lez Durance (France)] [CEA/DEN/DEC Bat 352 Cadarache, 13108 Saint Paul lez Durance (France); Caraballo, R.; Jégou, C. [CEA/DTCD/SECM/LMPA, Marcoule 30207 Bagnols Sur Ceze (France)] [CEA/DTCD/SECM/LMPA, Marcoule 30207 Bagnols Sur Ceze (France)

2013-07-22T23:59:59.000Z

175

The Importance of Geochemical Parameters and Shale Composition on Rock Mechanical Properties of Gas Shale Reservoirs: a Case Study From the Kockatea Shale and Carynginia Formation From the Perth Basin, Western Australia  

Science Journals Connector (OSTI)

Evaluation of the gas shale mechanical properties is very important screening criteria ... for hydraulic fracturing and as a result in gas shale sweet spot mapping. Young’s modulus and ... mechanical properties t...

Mohammad Mahdi Labani; Reza Rezaee

2014-06-01T23:59:59.000Z

176

Chapter 1 - Natural Gas Fundamentals  

Science Journals Connector (OSTI)

Natural gas is the most energy-efficient fossil fuel; it offers important energy-saving benefits when it is used instead of oil or coal. Although the primary use of natural gas is as a fuel, it is also a source of hydrocarbons for petrochemical feedstocks and a major source of elemental sulfur, an important industrial chemical. Its popularity as an energy source is expected to grow substantially in the future because natural gas can help achieve two important energy goals for the twenty-first century: providing the sustainable energy supplies and services needed for social and economic development and reducing adverse impacts on global climate and the environment in general. Natural gas consumption and trade have been growing steadily over the past two decades, and natural gas has strengthened its position in the world energy mix. Although natural gas demand declined in 2009, as a result of the economic slowdown, it is expected to resume growth in both emerging and traditional markets in the coming decades. Such increase in the near future will be driven because of additional demand in current uses, primarily power generation. There is yet little overlap between the use of natural gas and oil in all large markets. However, there are certain moves in the horizon, including the electrifying of transportation, that will push natural gas use to ever higher levels. This book gives the reader an introduction to natural gas by describing the origin and composition of natural gas, gas sources, phase behavior and properties, and transportation methods. Keywords: Absolute Open Flow, bulk modulus of elasticity, coal-bed methane, cricondenbar, cricondentherm, Expected Ultimate Recovery, gas deviation factor, higher heating value, Inflow Performance Relationship, kerogen, laminar flow, liquefied natural gas, primary thermogenic gas, pyrobitumen, secondary thermogenic gas, super-compressibility factor, thiol, Tubing Performance Curve, turbulent flow, unconventional gas resources, Wobbe Index, Wobbe Number.

Saeid Mokhatab; William A. Poe

2012-01-01T23:59:59.000Z

177

Detection of Physiologically Relevant Alcohol Concentrations Using Raman Spectroscopy  

E-Print Network [OSTI]

This is the first step in a series of studies to test the feasibility of using Raman Spectroscopy (RS) to non-invasively detect physiologically relevant blood alcohol concentrations. Blood tests, urine tests, and the breathalyzer are currently...

McKay, Joshua L.

2006-08-16T23:59:59.000Z

178

Quantitative biological Raman spectroscopy for non-invasive blood analysis  

E-Print Network [OSTI]

The long term goal of this project is the measurement of clinically-relevant analytes in the blood tissue matrix of human subjects using near-infrared Raman spectroscopy, with the shorter term research directed towards ...

Shih, Wei-Chuan

2007-01-01T23:59:59.000Z

179

Kinetics simulation for natural gas conversion to unsaturated C? hydrocarbons  

E-Print Network [OSTI]

value. The usual chemical composition range of natural gas is shown in Table I. l. Table 1. 1 Natural Gas Composition Component Methane Ethane Pro ane iso-Butane normal-Butane iso-Pentane normal-Pentane Hexane s lus Nitro en Carbon Dioxide... Acetylene Carbon Ethylene Hydrogen Methane Water Carbon Dioxide CHAPTER I INTRODUCTION Challenge for Natural Gas Natural Gas (NG), which is comprised priinarily of methane, is found throughout the world, burns cleanly, and processes a high caloric...

Yang, Li

2003-01-01T23:59:59.000Z

180

Gas Turbines  

Science Journals Connector (OSTI)

When the gas turbine generator was introduced to the power generation ... fossil-fueled power plant. Twenty years later, gas turbines were established as an important means of ... on utility systems. By the early...

Jeffrey M. Smith

1996-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

High conversion efficiency ultraviolet fiber Raman oscillator--amplifier system  

SciTech Connect (OSTI)

High efficiency UV frequency conversion by stimulated Raman scattering in a XeCl (lambda = 308-nm) excimer laser-pumped multimode fiber is presented. The system consists of a first piece of fiber as a Stokes generator and a second as a power amplifier. Power conversion efficiencies up to 80% have been measured. Uses of fiber Raman amplifiers in the near UV are also discussed.

Pini, R.; Salimbeni, R.; Vannini, M.; Haider, A.F.M.Y.; Lin, C.

1986-04-01T23:59:59.000Z

182

Gas Turbines  

Science Journals Connector (OSTI)

... the time to separate out the essentials and the irrelevancies in a text-book. The gas ...gasturbine ...

H. CONSTANT

1950-10-21T23:59:59.000Z

183

Development of an Integrated Raman and Turbidity Fiber Optic Sensor for the In-Situ Analysis of High Level Nuclear Waste - 13532  

SciTech Connect (OSTI)

Stored nuclear waste must be retrieved from storage, treated, separated into low- and high-level waste streams, and finally put into a disposal form that effectively encapsulates the waste and isolates it from the environment for a long period of time. Before waste retrieval can be done, waste composition needs to be characterized so that proper safety precautions can be implemented during the retrieval process. In addition, there is a need for active monitoring of the dynamic chemistry of the waste during storage since the waste composition can become highly corrosive. This work describes the development of a novel, integrated fiber optic Raman and light scattering probe for in situ use in nuclear waste solutions. The dual Raman and turbidity sensor provides simultaneous chemical identification of nuclear waste as well as information concerning the suspended particles in the waste using a common laser excitation source. (authors)

Gasbarro, Christina; Bello, Job [EIC Laboratories, Inc., 111 Downey St., Norwood, MA, 02062 (United States)] [EIC Laboratories, Inc., 111 Downey St., Norwood, MA, 02062 (United States); Bryan, Samuel; Lines, Amanda; Levitskaia, Tatiana [Pacific Northwest National Laboratory, PO Box 999, Richland, WA, 99352 (United States)] [Pacific Northwest National Laboratory, PO Box 999, Richland, WA, 99352 (United States)

2013-07-01T23:59:59.000Z

184

Electrode compositions  

DOE Patents [OSTI]

An electrode composition is described for use as an electrode in a non-aqueous battery system. The electrode composition contains an electrically active powder in a solid polymer and, as a dispersant, a C{sub 8}-C{sub 15} alkyl capped oligomer of a hexanoic acid that is electrochemically inert at 2.5--4.5 volts.

Block, J.; Fan, X.

1998-10-27T23:59:59.000Z

185

Surface-Enhanced Raman Scattering (SERS) and Surface-Enhanced Resonance Raman Scattering (SERRS) on HNO3-Roughened Copper Foil  

Science Journals Connector (OSTI)

Copper foils for a Raman study were prepared by a chemical etching method with HNO3. These foils were found to exhibit a strong SERS effect, SERS or SERRS spectra of...

Xue, Gi; Dong, Jian; Zhang, Mingsheng

1991-01-01T23:59:59.000Z

186

VOLUME 84, NUMBER 17 P H Y S I C A L R E V I E W L E T T E R S 24 APRIL 2000 Bose-Stimulated Raman Adiabatic Passage in Photoassociation  

E-Print Network [OSTI]

a degenerate molecular gas (MBEC) from an already Bose-condensed sample of atoms [4­6]. Photoassociation (PA two-color photoassociation of a Bose-Einstein condensate, focusing on stimulated Raman adiabatic element for an atomic condensate, and photoassociative STIRAP turns out to be a viable mechanism

Javanainen, Juha

187

Method of manufacturing aerogel composites  

DOE Patents [OSTI]

Disclosed herewith is a process of forming an aerogel composite which comprises introducing a gaseous material into a formed aerogel monolith or powder, and causing decomposition of said gaseous material in said aerogel in amounts sufficient to cause deposition of the decomposition products of the gas on the surfaces of the pores of the said aerogel.

Cao, W.; Hunt, A.J.

1999-03-09T23:59:59.000Z

188

Microwave Plasma Chemical Vapor Deposition of Carbon Coatings on LiNi1/3Co1/3Mn1/3O2 for Li-Ion Battery Composite Cathodes  

E-Print Network [OSTI]

O 2 for Li-ion Battery Composite Cathodes Marek L. MarcinekRaman spectroscopy. The composite LiNi 1/3 Co 1/3 Mn 1/3 O 2electronic contact within the composite cathode and does not

Doeff, M.M.

2012-01-01T23:59:59.000Z

189

Colorado Natural Gas Number of Gas and Gas Condensate Wells ...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) Colorado Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

190

California Natural Gas Number of Gas and Gas Condensate Wells...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) California Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

191

Louisiana Natural Gas Number of Gas and Gas Condensate Wells...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

192

Michigan Natural Gas Number of Gas and Gas Condensate Wells ...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) Michigan Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

193

Oklahoma Natural Gas Number of Gas and Gas Condensate Wells ...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Oklahoma Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

194

Virginia Natural Gas Number of Gas and Gas Condensate Wells ...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

195

Tennessee Natural Gas Number of Gas and Gas Condensate Wells...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Tennessee Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

196

Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

197

Arkansas Natural Gas Number of Gas and Gas Condensate Wells ...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) Arkansas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

198

Maryland Natural Gas Number of Gas and Gas Condensate Wells ...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) Maryland Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

199

Illinois Natural Gas Number of Gas and Gas Condensate Wells ...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Illinois Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

200

Missouri Natural Gas Number of Gas and Gas Condensate Wells ...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) Missouri Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Mississippi Natural Gas Number of Gas and Gas Condensate Wells...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Mississippi Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

202

Nebraska Natural Gas Number of Gas and Gas Condensate Wells ...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) Nebraska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

203

Solar composition from the Genesis Discovery Mission  

E-Print Network [OSTI]

Solar composition from the Genesis Discovery Mission D. S. Burnett1 and Genesis Science Team2: the isoto- pic compositions of O, N, and noble gases differ in the Sun from other inner solar system objects in the noble gas data from solar wind implanted in lunar soils. (ii) The most advanced analytical instruments

204

Raman scattering studies of the GaAs native oxide interface  

Science Journals Connector (OSTI)

Oxide filmsgrown by heat treatment on the 100 and 111 faces of GaAs have been studied by Raman backscattering. A spectrum consisting of the bulk LO and TO lines of GaAs and two additional lines labeled R1 and R2 is observed on all samples prepared at temperatures above 435° C. The additional modes are attributed to an interface region of perhaps several hundred angstroms thickness beneath the oxide film. This structure appears to be made unstable by chemical removal of the film. After the film is removed the spectrum is annealed (returns to that of GaAs) in a matter of weeks at room temperature and in about 1 h at 400° C whether the annealing atmosphere is N2 O2 or forming gas. One of the modes R2 appears to scatter as a scalar i.e. a diagonal Raman matrix element. Spectra by the R1 mode on the other hand appear to be largely unpolarized or possibly slightly nondiagonal in character. Some speculations about the possible nature of the interface region are presented.

J. A. Cape; W. E. Tennant; L. G. Hale

1977-01-01T23:59:59.000Z

205

Final Flue Gas Cleaning (FFGC)  

E-Print Network [OSTI]

Final Flue Gas Cleaning (FFGC) Pilot Plant. The pilot plant (FFGC-PP) will be used to test and evaluate removal of air pollution constituents from the flue gas of a 160 MW, Houston-area power plant operating on 100% petcoke. The two-week long test.... TABLE III FLUE GAS COMPOSITION PETCOKE FIRED POWER PLANT H 2 O 3.2 % O 2 4.9 % CO 2 17.7 % HCl 10 ppm SO 2 6800 ppm SO 3 300 ppm H2SO4 mist 690 ppm NOx 260 ppm...

Stinger, D. H.; Romero, M. H.

2006-01-01T23:59:59.000Z

206

Natural gas hydrates - issues for gas production and geomechanical stability  

E-Print Network [OSTI]

bearing sediments in offshore environments, I divided these data into different sections. The data included water depths, pore water salinity, gas compositions, geothermal gradients, and sedimentary properties such as sediment type, sediment mineralogy... .................................................................. 9 2.2 Hydrate patterns in sediments .................................................................... 24 3.1 Water depths and penetration for the Blake Ridge..................................... 31 3.2 Geothermal gradients measured...

Grover, Tarun

2008-10-10T23:59:59.000Z

207

Storage and Manipulation of Light Using a Raman Gradient Echo Process  

E-Print Network [OSTI]

The Gradient Echo Memory (GEM) scheme has potential to be a suitable protocol for storage and retrieval of optical quantum information. In this paper, we review the properties of the $\\Lambda$-GEM method that stores information in the ground states of three-level atomic ensembles via Raman coupling. The scheme is versatile in that it can store and re-sequence multiple pulses of light. To date, this scheme has been implemented using warm rubidium gas cells. There are different phenomena that can influence the performance of these atomic systems. We investigate the impact of atomic motion and four-wave mixing and present experiments that show how parasitic four-wave mixing can be mitigated. We also use the memory to demonstrate preservation of pulse shape and the backward retrieval of pulses.

Hosseini, M; Campbell, G T; Lam, P K; Buchler, B C

2012-01-01T23:59:59.000Z

208

NETL: Gasification Systems - Gas Separation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separation Separation Ion-Transport Membrane Oxygen Separation Modules Ion-Transport Membrane Oxygen Separation Modules Gas separation unit operations represent major cost elements in gasification plants. The gas separation technology being supported in the DOE program promises significant reduction in cost of electricity, improved thermal efficiency, and superior environmental performance. Gasification-based energy conversion systems rely on two gas separation processes: (1) separation of oxygen from air for feed to oxygen-blown gasifiers; and (2) post-gasification separation of hydrogen from carbon dioxide following (or along with) the shifting of gas composition when carbon dioxide capture is required or hydrogen is the desired product. Research efforts include development of advanced gas separation

209

Compressed natural gas measurement issues  

SciTech Connect (OSTI)

The Natural Gas Vehicle Coalition`s Measurement and Metering Task Group (MMTG) was established on July 1st, 1992 to develop suggested revisions to National Institute of Standards & Technology (NIST) Handbook 44-1992 (Specifications, Tolerances, and Other Technical Requirements for Weighing and Measuring Devices) and NIST Handbook 130-1991 (Uniform Laws & Regulations). Specifically, the suggested revisions will address the sale and measurement of compressed natural gas when sold as a motor vehicle fuel. This paper briefly discusses the activities of the MMTG and its interaction with NIST. The paper also discusses the Institute of Gas Technology`s (IGT) support of the MMTG in the area of natural gas composition, their impact on metering technology applicable to high pressure fueling stations as well as conversion factors for the establishment of ``gallon gasoline equivalent`` of natural gas. The final portion of this paper discusses IGT`s meter research activities and its meter test facility.

Blazek, C.F.; Kinast, J.A.; Freeman, P.M.

1993-12-31T23:59:59.000Z

210

Hydride compositions  

DOE Patents [OSTI]

Disclosed are a composition for use in storing hydrogen and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the H equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to H, and then heating below the softening temperature of any of the constituents. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P{sub H}{sub 2} and determining H/M from the isothermic function of the composition.

Lee, Myung, W.

1994-01-01T23:59:59.000Z

211

Hydride compositions  

DOE Patents [OSTI]

A composition for use in storing hydrogen, and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the hydrogen equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to hydrogen and then heating at a temperature below the softening temperature of any of the. constituents so that their chemical and structural integrity is preserved. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P.sub.H.sbsb.2 and determining H/M from the isothermic function of the composition.

Lee, Myung W. (North Augusta, SC)

1995-01-01T23:59:59.000Z

212

Predicted intensities for new Raman transitions in solid HD  

Science Journals Connector (OSTI)

The scattering efficiencies for the zero-phonon and phonon branches associated with predicted new Raman transitions in solid HD are calculated. These transitions arise from the interaction-induced polarizability of a pair of molecules expressed in terms of the vector separation between the centers of mass and satisfy different rotational selection rules from those of allowed Raman transitions. For single transitions in which only one molecule of the pair is excited by the incoming photon, one expects an R branch, while, for double transitions in which both molecules are excited, one expects R+S and T+S branches with progressively less intensity. A previously obtained experimental Raman spectrum of solid HD does have spectral features similar in shape and intensity to those predicted for the RR phonon branch, although this feature was tentatively assigned as a two-phonon Raman-active transition. We conclude that a new Raman study of solid HD carried out with higher sensitivity and over a greater frequency region would be of interest to determine the correct assignment of this feature and to look for other predicted transitions resulting from the interaction-induced polarizability.

M. Attia; M. Ali; R. H. Tipping; J. D. Poll

1989-11-01T23:59:59.000Z

213

Higher modulus compositions incorporating particulate rubber  

DOE Patents [OSTI]

Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figs.

Bauman, B.D.; Williams, M.A.; Bagheri, R.

1997-12-02T23:59:59.000Z

214

Higher modulus compositions incorporating particulate rubber  

DOE Patents [OSTI]

Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.

Bauman, Bernard D. (Emmaus, PA); Williams, Mark A. (Souderton, PA); Bagheri, Reza (Bethlehem, PA)

1997-12-02T23:59:59.000Z

215

Flammable gas project topical report  

SciTech Connect (OSTI)

The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-1 01 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue. Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. `Me report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods. Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue.

Johnson, G.D.

1997-01-29T23:59:59.000Z

216

Measurement of Petroleum Fuel Contamination in Water by Solid-Phase Microextraction with Direct Raman Spectroscopic Detection  

Science Journals Connector (OSTI)

A method is described for determining petroleum fuel contamination in water based on solid-phase microextraction and Raman spectroscopy (SPME/Raman). In this method, contaminants are...

Jager, Michael J; McClintic, Daniel P; Tilotta, David C

2000-01-01T23:59:59.000Z

217

The application of surface-enhanced Raman spectroscopy for the detection of excitatory amino acids  

E-Print Network [OSTI]

enhanced Raman spectroscopy (SERS) on aqueous silver colloids. This study examines methods to monitor the colloidal reactions for the calibration of the enhancement observed. Thirty second Raman spectral scans were taken utilizing a 50 mW argon laser...

O'Neal, Dennis Patrick Doucet

1999-01-01T23:59:59.000Z

218

G? band in double- and triple-walled carbon nanotubes: A Raman study  

E-Print Network [OSTI]

Double- and triple-walled carbon nanotubes are studied in detail by laser energy-dependent Raman spectroscopy in order to get a deeper understanding about the second-order G[superscript '] band Raman process, general ...

Hirschmann, Thomas Ch.

219

Noise figure and photon statistics in coherent anti-Stokes Raman scattering  

E-Print Network [OSTI]

). 11. J. Perina, "Photon statistics in Raman scattering with frequency mismatch," Optica Acta 28, 1529 (1981). 12. J. Perina, "Photon statistics in Raman scattering of intense coherent light," Optica Acta 28

Jalali. Bahram

220

Nanoscale array structures suitable for surface enhanced raman scattering and methods related thereto  

DOE Patents [OSTI]

Methods for fabricating nanoscale array structures suitable for surface enhanced Raman scattering, structures thus obtained, and methods to characterize the nanoscale array structures suitable for surface enhanced Raman scattering. Nanoscale array structures may comprise nanotrees, nanorecesses and tapered nanopillars.

Bond, Tiziana C.; Miles, Robin; Davidson, James C.; Liu, Gang Logan

2014-07-22T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Raman spectroscopy of the components of 18th-century icon painting  

Science Journals Connector (OSTI)

The method of Raman spectroscopy is employed in the analysis of lead-containing pigments in ancient Russian painting, transformed pigments, chalk, and drying oil. The Raman spectra of white lead and the mixture o...

N. N. Brandt; N. L. Rebrikova; A. Yu. Chikishev

2009-12-01T23:59:59.000Z

222

Long-Term Evaluation of Temperature Profiles Measured by an Operational Raman Lidar  

Science Journals Connector (OSTI)

This study investigates the accuracy and calibration stability of temperature profiles derived from an operational Raman lidar over a 2-yr period from 1 January 2009 to 31 December 2010. The lidar, which uses the rotational Raman technique for ...

Rob K. Newsom; David D. Turner; John E. M. Goldsmith

2013-08-01T23:59:59.000Z

223

Optical Coherence Tomography and Raman Spectroscopy of the retina  

SciTech Connect (OSTI)

Imaging the structure and correlating it with the biochemical content of the retina holds promise for fundamental research and for clinical applications. Optical coherence tomography (OCT) is commonly used to image the 3D structure of the retina and while the added functionality of biochemical analysis afforded by Raman scattering could provide critical molecular signatures for clinicians and researchers, there are many technical challenges to combining these imaging modalities. We present an ex vivo OCT microscope combined with Raman spectroscopy capable of collecting morphological and molecular information about a sample simultaneously. The combined instrument will be used to investigate remaining technical challenges to combine these imaging modalities, such as the laser power levels needed to achieve a Raman signal above the noise level without damaging the sample.

Evans, J W; Zawadzki, R J; Liu, R; Chan, J; Lane, S; Werner, J S

2009-01-16T23:59:59.000Z

224

UV resonance Raman analysis of trishomocubane and diamondoid dimers  

SciTech Connect (OSTI)

We present resonance Raman measurements of crystalline trishomocubane and diamantane dimers containing a C=C double bond. Raman spectra were recorded with excitation energies between 2.33 eV and 5.42 eV. The strongest enhancement is observed for the C=C stretch vibration and a bending mode involving the two carbon atoms of the C=C bond, corresponding to the B{sub 2g} wagging mode of ethylene. This is associated with the localization of the ?-HOMO and LUMO and the elongation of the C=C bond length and a pyramidalization of the two sp{sup 2}-hybridized carbon atoms at the optical excitation. The observed Raman resonance energies of the trishomocubane and diamantane dimers are significantly lower than the HOMO-LUMO gaps of the corresponding unmodified diamondoids.

Meinke, Reinhard, E-mail: rene@physik.tu-berlin.de; Thomsen, Christian; Maultzsch, Janina [Institut für Festkörperphysik, Technische Universität Berlin, Hardenbergstr. 36, D-10623 Berlin (Germany)] [Institut für Festkörperphysik, Technische Universität Berlin, Hardenbergstr. 36, D-10623 Berlin (Germany); Richter, Robert; Merli, Andrea [Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstr. 36, D-10623 Berlin (Germany)] [Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstr. 36, D-10623 Berlin (Germany); Fokin, Andrey A. [Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen (Germany) [Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen (Germany); Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056 Kiev (Ukraine); Koso, Tetyana V.; Schreiner, Peter R. [Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen (Germany)] [Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen (Germany); Rodionov, Vladimir N. [Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056 Kiev (Ukraine)] [Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056 Kiev (Ukraine)

2014-01-21T23:59:59.000Z

225

Phosphorescent compositions, methods of making the compositions, and methods of using the compositions  

SciTech Connect (OSTI)

Compositions, methods of making compositions, materials including compositions, crayons including compositions, paint including compositions, ink including compositions, waxes including compositions, polymers including compositions, vesicles including the compositions, methods of making each, and the like are disclosed.

Jia, Weiyi; Wang, Xiaojun; Jia, George D.; Lewis, Linda; Yen, Laurel C.

2014-06-24T23:59:59.000Z

226

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

,366 ,366 95,493 1.08 0 0.00 1 0.03 29,406 0.56 1,206 0.04 20,328 0.64 146,434 0.73 - Natural Gas 1996 Million Percent of Million Percent of Cu. Feet National Total Cu. Feet National Total Net Interstate Movements: Industrial: Marketed Production: Vehicle Fuel: Deliveries to Consumers: Electric Residential: Utilities: Commercial: Total: South Carolina South Carolina 88. Summary Statistics for Natural Gas South Carolina, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ...........................................

227

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

0,216 0,216 50,022 0.56 135 0.00 49 1.67 85,533 1.63 8,455 0.31 45,842 1.45 189,901 0.95 - Natural Gas 1996 Million Percent of Million Percent of Cu. Feet National Total Cu. Feet National Total Net Interstate Movements: Industrial: Marketed Production: Vehicle Fuel: Deliveries to Consumers: Electric Residential: Utilities: Commercial: Total: M a r y l a n d Maryland 68. Summary Statistics for Natural Gas Maryland, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... NA NA NA NA NA Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 9 7 7 7 8 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 33 28 26 22 135 From Oil Wells ...........................................

228

Raman fibre lasers based on heavily GeO{sub 2}-doped fibres  

SciTech Connect (OSTI)

Amplification of radiation due to stimulated Raman scattering in an optical fibre with a heavily GeO{sub 2}-doped core and a fused silica cladding is studied. The applications of such fibres in Raman lasers are demonstrated. A Raman fibre laser emitting 10 W at a fibre length of only 3 m and Raman lasers emitting at 1.73, 1.85, 2.06, and 2.2 {mu}m are fabricated for the first time. (fibre lasers)

Dianov, Evgenii M; Bufetov, Igor' A; Mashinsky, V M; Shubin, Aleksei V; Medvedkov, O I; Rakitin, A E; Mel'kumov, Mikhail A [Fiber Optics Research Center, Russian Academy of Sciences, Moscow (Russian Federation); Khopin, V F; Gur'yanov, A N [Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, Nizhnii Novgorod (Russian Federation)

2005-05-31T23:59:59.000Z

229

Summary report of FY 1995 Raman spectroscopy technology development  

SciTech Connect (OSTI)

US DOE is sponsoring development of remote, fiber-optic Raman spectroscopy for rapid chemical characterization of Hanford high-level radioactive tank waste. Deployment targets for this technology are analytical hot cells and, via the Light-Duty Utility Arm and cone penetrometer, the waste tanks themselves. Perceived benefits of fiber-optic Raman spectroscopy are (1) rapid generation of tank-waste safety-related data, (2) reduced personnel exposure to highly radioactive waste, (3) reduced tank-waste sampling and analysis costs, and (4) reduced radioactive analytical waste. This document presents the results from the investigation of two dispersive, transmission-grating Raman systems and four fiber-optic Raman probe designs with non-radioactive tank waste simulants. One Raman system used a 532-nm, 400 mW, solid-state laser; the other used a 785-nm, 500 mW, solid-state diode laser. We found (1) the transmission-grating systems had better wavelength stability than previously tried Czerny-Turner-Based systems and (2) the 785-nm system`s specie detection limits in the spectral fingerprint regiion were at least as good as those for the 532-nm system. Based on these results, and the fact that some tank wastes luminesce with 514.5nm excitation, we selected the 785-nm system for hot-cell use. Of the four probes tested, three had a ``six-around-on`` fiber probe design; the fourth probe was a one-fiber-in-one-fiber-out, diffuse-relectance design. Comparison of the four probes` signal-to-noise rations, rations, transmission/collection efficiencies, and probe-silica Raman backgrounds showed that the best probe for use with Hanford-Site tank waste should (1) be filtered as close to the probe tip as possible to reduce the probe-silica Raman background and (2) have multiple collection fibers. The responses of all the probes tested showed a strong dependence on probe-sample distance, and the presence of a probe window appeared to increase the probe`s silica Raman background.

Douglas, J.G.

1995-11-01T23:59:59.000Z

230

Infrared divergence of the resonant Raman-Compton scattering  

Science Journals Connector (OSTI)

The infrared divergence of the resonant Raman-Compton scattering has been studied in collisions of photons on atomic L electrons in the intermediate-momentum-transfer regime. Low-energy continua emitted by Zr atoms, excited, in the vicinity of the K edge, by the monochromatized x rays delivered by the LURE Synchrotron Radiation Facility, have been observed on vary thin targets and compared with the theoretically predicted infrared divergence of the Raman scattering. The characteristic change in shape of these continua has been studied on a wide energy range below the Zr K edge.

J. P. Briand; A. Simionovici; P. Chevallier; P. Indelicato

1989-05-01T23:59:59.000Z

231

Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions  

SciTech Connect (OSTI)

U.S. natural gas composition is expected to be more variable in the future. Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Unconventional gas supplies, like coal-bed methane, are also expected to grow. As a result of these anticipated changes, the composition of fuel sources may vary significantly from existing domestic natural gas supplies. To allow the greatest use of gas supplies, end-use equipment should be able to accommodate the widest possible gas composition. For this reason, the effect of gas composition on combustion behavior is of interest. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 589K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx emissions. These results vary from data reported in the literature for some engine applications and potential reasons for these differences are discussed.

D. Straub; D. Ferguson; K. Casleton; G. Richards

2006-03-01T23:59:59.000Z

232

Raman scattering in carbon nanotubes revisited J. Maultzsch, S. Reich, and C. Thomsen  

E-Print Network [OSTI]

of whether the high-energy Raman spectrum in carbon nanotubes is also dominated by processes that allow for understanding the high-energy modes in carbon nanotubes attribute the ob- served Raman peaks to -pointRaman scattering in carbon nanotubes revisited J. Maultzsch, S. Reich, and C. Thomsen Institut fu

Nabben, Reinhard

233

Variable temperature Raman microscopy as a nanometrology tool for graphene layers and graphene-based devices  

E-Print Network [OSTI]

Variable temperature Raman microscopy as a nanometrology tool for graphene layers and graphene; accepted 24 July 2007; published online 15 August 2007 Raman microscopy of graphene was carried out over-band frequencies extracted from Raman spectra of the single-layer graphene are - 1.6±0.2 10-2 cm-1 /K and - 3

234

Raman response of magnetic excitations in cuprate ladders and planes K. P. Schmidt*  

E-Print Network [OSTI]

by inelastic neutron scattering,10­14 the quantitative un- derstanding of the two-magnon line shape is heavily debated. Two-magnon Raman scattering has been proven to be a powerful tool to study quantum as two-triplon Raman scattering. On the one hand, one may expect that the Raman re- sponse is dominated

Nabben, Reinhard

235

,"Missouri Natural Gas Summary"  

U.S. Energy Information Administration (EIA) Indexed Site

Gas Wells (MMcf)","Missouri Natural Gas Gross Withdrawals from Oil Wells (MMcf)","Missouri Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)","Missouri Natural...

236

Transformation Composition  

E-Print Network [OSTI]

Proc. AGTIVE'99, to appear in LNCS Graph Transformation Modules and their Composition ? Frank,knirsch,kreo,kuskeg@informatik.uni-bremen.de Abstract. In this paper, we investigate the notion of transformation modules as a structuring principle. Based on the notion of transformation units, a concept that allows to specify binary relations on graphs

Drewes, Frank

237

Neural net controlled tag gas sampling system for nuclear reactors  

DOE Patents [OSTI]

A method and system for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod.

Gross, Kenneth C. (Bolingbrook, IL); Laug, Matthew T. (Idaho Fall, ID); Lambert, John D. B. (Wheaton, IL); Herzog, James P. (Downers Grove, IL)

1997-01-01T23:59:59.000Z

238

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

68,747 68,747 34,577 0.39 0 0.00 34 1.16 14,941 0.29 0 0.00 11,506 0.36 61,058 0.31 I d a h o Idaho 60. Summary Statistics for Natural Gas Idaho, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation.......................... 0 0 0 0 0 Vented

239

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

0 0 0 0.00 0 0.00 0 0.00 540 0.01 0 0.00 2,132 0.07 2,672 0.01 H a w a i i Hawaii 59. Summary Statistics for Natural Gas Hawaii, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation.......................... 0 0 0 0 0 Vented and Flared

240

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

483,052 483,052 136,722 1.54 6,006 0.03 88 3.00 16,293 0.31 283,557 10.38 41,810 1.32 478,471 2.39 F l o r i d a Florida 57. Summary Statistics for Natural Gas Florida, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 47 50 98 92 96 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 7,584 8,011 8,468 7,133 6,706 Total.............................................................. 7,584 8,011 8,468 7,133 6,706 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ...............

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

291,898 291,898 113,995 1.29 0 0.00 4 0.14 88,078 1.68 3,491 0.13 54,571 1.73 260,140 1.30 I o w a Iowa 63. Summary Statistics for Natural Gas Iowa, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation.......................... 0 0 0

242

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

Vehicle Fuel: Vehicle Fuel: Deliveries to Consumers: Electric Residential: Utilities: Commercial: Total: New England New England 36. Summary Statistics for Natural Gas New England, 1992-1996 Table 691,089 167,354 1.89 0 0.00 40 1.36 187,469 3.58 80,592 2.95 160,761 5.09 596,215 2.98 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................

243

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

29,693 29,693 0 0.00 0 0.00 6 0.20 17,290 0.33 0 0.00 16,347 0.52 33,644 0.17 District of Columbia District of Columbia 56. Summary Statistics for Natural Gas District of Columbia, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation..........................

244

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

42,980 42,980 14,164 0.16 0 0.00 1 0.03 9,791 0.19 23,370 0.86 6,694 0.21 54,020 0.27 D e l a w a r e Delaware 55. Summary Statistics for Natural Gas Delaware, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation..........................

245

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

-49,536 -49,536 7,911 0.09 49,674 0.25 15 0.51 12,591 0.24 3 0.00 12,150 0.38 32,670 0.16 North Dakota North Dakota 82. Summary Statistics for Natural Gas North Dakota, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 496 525 507 463 462 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 104 101 104 99 108 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 12,461 18,892 19,592 16,914 16,810 From Oil Wells ........................................... 47,518 46,059 43,640 39,760 38,906 Total.............................................................. 59,979 64,951 63,232 56,674 55,716 Repressuring ................................................

246

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

21,547 21,547 4,916 0.06 0 0.00 0 0.00 7,012 0.13 3 0.00 7,099 0.22 19,031 0.10 N e w H a m p s h i r e New Hampshire 77. Summary Statistics for Natural Gas New Hampshire, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation..........................

247

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

139,881 139,881 26,979 0.30 463 0.00 115 3.92 27,709 0.53 19,248 0.70 28,987 0.92 103,037 0.52 A r i z o n a Arizona 50. Summary Statistics for Natural Gas Arizona, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... NA NA NA NA NA Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 6 6 6 7 7 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 721 508 711 470 417 From Oil Wells ........................................... 72 110 48 88 47 Total.............................................................. 794 618 759 558 464 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease

248

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

Middle Middle Atlantic Middle Atlantic 37. Summary Statistics for Natural Gas Middle Atlantic, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 1,857 1,981 2,042 1,679 1,928 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 36,906 36,857 26,180 37,159 38,000 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 161,372 152,717 140,444 128,677 152,494 From Oil Wells ........................................... 824 610 539 723 641 Total.............................................................. 162,196 153,327 140,982 129,400 153,134 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed

249

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

386,690 386,690 102,471 1.16 0 0.00 43 1.47 142,319 2.72 5,301 0.19 98,537 3.12 348,671 1.74 M i n n e s o t a Minnesota 71. Summary Statistics for Natural Gas Minnesota, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation..........................

250

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

1,108,583 1,108,583 322,275 3.63 298 0.00 32 1.09 538,749 10.28 25,863 0.95 218,054 6.90 1,104,972 5.52 I l l i n o i s Illinois 61. Summary Statistics for Natural Gas Illinois, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... NA NA NA NA NA Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 382 385 390 372 370 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 337 330 323 325 289 From Oil Wells ........................................... 10 10 10 10 9 Total.............................................................. 347 340 333 335 298 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ...............

251

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

286,485 286,485 71,533 0.81 25 0.00 31 1.06 137,225 2.62 5,223 0.19 72,802 2.31 286,814 1.43 M i s s o u r i Missouri 73. Summary Statistics for Natural Gas Missouri, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... NA NA NA NA NA Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 5 8 12 15 24 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 27 14 8 16 25 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 27 14 8 16 25 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation..........................

252

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

411,951 411,951 100,015 1.13 0 0.00 5 0.17 114,365 2.18 45,037 1.65 96,187 3.05 355,609 1.78 Massachusetts Massachusetts 69. Summary Statistics for Natural Gas Massachusetts, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation..........................

253

Gas vesicles.  

Science Journals Connector (OSTI)

...in the suspending water, of concentration...MPa and balances the atmospheric pressure. Note that...versely, liquid water could not form by condensation inside the gas vesicle...presumably surrounded by water on all sides. At...

A E Walsby

1994-03-01T23:59:59.000Z

254

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

226,798 226,798 104,124 1.17 0 0.00 0 0.00 58,812 1.12 2,381 0.09 40,467 1.28 205,783 1.03 North Carolina North Carolina 81. Summary Statistics for Natural Gas North Carolina, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 0 0 0 0 0 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 0 0 0 0 0 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 0 0 0 0 0 Repressuring ................................................ 0 0 0 0 0 Nonhydrocarbon Gases Removed ............... 0 0 0 0 0 Wet After Lease Separation..........................

255

Diagnosis of sources of current inefficiency in industrial molten salt electrolysis cells by Raman spectroscopy: A topical report on chlorides: Topical report, June 1982-June 1987  

SciTech Connect (OSTI)

Molten salt electrolysis, a very energy-intensive process, is used in the extraction of light metals. Aluminum production by the Hall process and magnesium production in the Dow and I.G. Farbenindustrie cells constitute the major commercial applications of metal electrowinning from molten-salt media at present. The energy input into the electrolysis cell is in the form of direct current, and the energy efficiencies in the magnesium or aluminum processes are only in the 30 to 40% range. Major energy reductions are achieved by reducing the cell voltage or by increasing the current efficiency. Goal of the research is to identify the sources of the current losses occurring in molten salt electrolysis. This research worked on the systems of I.G. Farben magnesium chloride and Alcoa smelting aluminum chloride processes. Raman spectra were measured and analyzed for each component or their mixtures of the electrolyte for magnesium and aluminum reduction in chloride melts. Raman measurements were also conducted on the melts of industrial composition for aluminum and magnesium electrolysis. In laboratory-scale cells which imitated industrial practice, Raman spectra were measured in situ during electrolysis in attempts to identify the streamers, coloration of electrolyte, and any subvalent species. They were known to occur only during electrolysis, and they have been reported to be possible current losses. Cyclic voltammetry was conducted to obtain information about the generation of subvalent species which were not detected by Raman measurement. These were thought to be kinetic entities present only during electrolysis. Results of Raman spectroscopy and electrochemistry of magnesium and aluminum reduction from molten chloride bath are presented. The results would be useful to establish the basis for the study of electrolysis of aluminum from molten fluoride media. 119 refs., 66 figs.

Sadoway, D. R.

1987-06-01T23:59:59.000Z

256

Shell-isolated nanoparticle-enhanced Raman spectroscopy  

Science Journals Connector (OSTI)

... However, generally substrates based on metals such as Ag, Au and Cu, either with roughened surfaces or in the form of nanoparticles, are required to realise a substantial SERS ... attributed to the Pt–H stretching vibration mode according to the previous reports on highly roughened Pt surfaces. In addition, we collected Raman signals on Pt(111) under the ...

Jian Feng Li; Yi Fan Huang; Yong Ding; Zhi Lin Yang; Song Bo Li; Xiao Shun Zhou; Feng Ru Fan; Wei Zhang; Zhi You Zhou; De Yin Wu; Bin Ren; Zhong Lin Wang; Zhong Qun Tian

2010-03-18T23:59:59.000Z

257

Surface-enhanced Raman scattering from silver electrodes  

SciTech Connect (OSTI)

The chemical and physical origins of the anomalously large enhancement of the Raman scattering cross section for molecules adsorbed on silver electrodes in an electrochemical cell were investigated. The effect of the chemical reactions which occur during the anodization/activation procedure were studied using the Ag-CN system. It was shown that the function of the anodization process is to roughen the electrode surface and create an activated site for bonding to the cyanide. A new nonelectrochemical technique for activating the silver surface, along with a study of the enhanced cyanide Raman scattering in different background electrolytes, showed that the Raman active entity on the surface must be a silver-cyanide complex. In order to study the physical mechanism of the enhancement, the angular dependence of the scattered radiation was measured from pyridine adsorbed on an evaporated silver electrode. Both polycrystalline and single crystalline silver films were used. The angular dependence of the scattered radiation from these films showed that the metal surface was controlling the directional properties of the scattered radiation, and not the polarizability tensor of the adsorbate. Based on these experimental results, it was concluded that for weakly roughened silver electrodes the source of the anomalous enhancement is due to a resonant Raman scattering process.

Trott, G.R.

1982-01-01T23:59:59.000Z

258

Electrochemical and Raman measurements on single-walled carbon nanotubes  

E-Print Network [OSTI]

Electrochemical and Raman measurements on single-walled carbon nanotubes M. Stoll a,*, P performed on a carbon nanotube mat as a working electrode using different salt solutions. The gravimetric capacitance of the nanotube material was estimated and its effective surface area was de- termined in a purely

Nabben, Reinhard

259

Raman Scattering in Carbon Nanotubes Christian Thomsen1  

E-Print Network [OSTI]

energy [4]. Theoretically, the electronic dispersion of nanotubes may be described by an- alyticRaman Scattering in Carbon Nanotubes Christian Thomsen1 and Stephanie Reich2 1 Institut f¨ur Festk of single-walled carbon nanotubes reflect the electron and phonon confinement as well as the cylindrical

Nabben, Reinhard

260

Single-pulse Raman scattering studies of heterogeneous explosive materials  

SciTech Connect (OSTI)

Raman scattering from ambient and shock-loaded heterogeneous (compressed pure polycrystalline) explosive materials has been examined using single-pulse laser excitation. In the case of triamino-trinitrobenzene (TATB), intense nonlinear scattering at 1170 cm/sup -1/ has been observed.

Trott, W.M.; Renlund, A.M.

1985-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Stimulated Raman scattering in an ethanol core microstructured optical fiber  

E-Print Network [OSTI]

Delaye, Anne Rouvie, Jordi Chinaud, Robert Frey, Gérald Roosen Laboratoire Charles Fabry de l'Institut d" Phys. Rev. Lett. 9, 455 (1962) 2. Y.R. Shen "The principles of nonlinear optics" (John Wiley and Sons, New York, 1994). 4. R.Frey, F. Pradère "Powerful tunable infrared generation by stimulated Raman

Paris-Sud XI, Université de

262

Raman Amplification of Laser Pulses in Microcapillary Plasmas  

E-Print Network [OSTI]

of overcoming the power limit of current chirped-pulse-amplification (CPA) CP641, X-Ray Lasers 2002: 8th International Conference on X-Ray Lasers, edited by J. J. Rocca et al. > 2002American Institute of Physics 0 of the optics. Such Raman amplifiers can be useful to produce ultra-intense laser pulses for pumping soft x-ray

263

hal00276997, Raman spectra of misoriented bilayer graphene  

E-Print Network [OSTI]

hal­00276997, version 1 ­ 5 May 2008 Raman spectra of misoriented bilayer graphene P. Poncharal 1 spectra from single layer graphene with a bilayer in which the two layers are arbitrarily misoriented to the similarity of the electronic structures of single layer graphene and misoriented bilayer graphene. Another

Paris-Sud XI, Université de

264

Raman spectroscopy on simple molecular systems at very high density  

SciTech Connect (OSTI)

We present an overview of how Raman spectroscopy is done on simple molecular substances at high pressures. Raman spectroscopy is one of the most powerful tools for studying these substances. It is often the quickest means to explore changes in crystal and molecular structures, changes in bond strength, and the formation of new chemical species. Raman measurements have been made at pressures up to 200 GPa (2 Mbar). Even more astonishing is the range of temperatures (4-5200/degree/K) achieved in various static and dynamic (shock-wave) pressure experiments. One point we particularly wish to emphasize is the need for a good theoretical understanding to properly interpret and use experimental results. This is particularly true at ultra-high pressures, where strong crystal field effects can be misinterpreted as incipient insulator-metal transitions. We have tried to point out apparatus, techniques, and results that we feel are particularly noteworthy. We have also included some of the /open quotes/oral tradition/close quotes/ of high pressure Raman spectroscopy -- useful little things that rarely or never appear in print. Because this field is rapidly expanding, we discuss a number of exciting new techniques that have been informally communicated to us, especially those that seem to open new possibilities. 58 refs., 18 figs.

Schiferl, D.; LeSar, R.S.; Moore, D.S.

1988-01-01T23:59:59.000Z

265

Postdoc Position in Microfluidics and Single Cell Raman Spectroscopy  

E-Print Network [OSTI]

Postdoc Position in Microfluidics and Single Cell Raman Spectroscopy Department of Microbial and Environmental Microfluidics Group (http://web.mit.edu/romanstocker) Department of Civil & Environmental (junior or senior) with strong expertise in microfluidics and an interest in applying it to microbial

Horn, Matthias

266

Laser Raman Spectroscopy in studies of corrosion and electrocatalysis  

SciTech Connect (OSTI)

Laser Raman Spectroscopy (LRS) has become an important tool for the in-situ structural study of electrochemical systems and processes in recent years. Following a brief introduction of the experimental techniques involved in applying LRS to electrochemical systems, we survey the literature for examples of studies in the inhibition of electrode reactions by surface films (e.g., corrosion and passivation phenomena) as well as the acceleration of reactions by electro-sorbates (electrocatalysis). We deal mostly with both normal and resonance Raman effects on fairly thick surface films in contrast to surface-enhanced Raman investigations of monolayer adsorbates, which is covered in another lecture. Laser Raman spectroelectrochemical studies of corrosion and film formation on such metals as Pb, Ag, Fe, Ni, Co, Cr, Au, stainless steel, etc. in various solution conditions are discussed. Further extension of the technique to studies in high-temperature and high-pressure aqueous environments is demonstrated. Results of studies of the structure of corrosion inhibitors are also presented. As applications of the LRS technique in the area of electrocatalysis, we cite studies of the structure of transition metal macrocyclic compounds, i.e., phthalocyanines and porphyrins, used for catalysis of the oxygen reduction reaction. 104 refs., 20 figs.

Melendres, C.A.

1988-01-01T23:59:59.000Z

267

Single Molecule Tip Enhanced Raman Spectroscopy NSF Grant # 1121262  

E-Print Network [OSTI]

MRSEC Single Molecule Tip Enhanced Raman Spectroscopy NSF Grant # 1121262 Matthew D. Sonntag1, it can "see" one single molecule at a time, this was carried out by studying the vibrational signature fingerprint that allows molecule identification. J. Phys. Chem. C, 2012, 116 (1), pp 478­483 · R6G-d4 · R6G-d0

Shahriar, Selim

268

Diamond-Silicon Carbide Composite And Method For Preparation Thereof  

DOE Patents [OSTI]

Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5-8 GPa, T=1400K-2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa.multidot.m.sup.1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.

Qian, Jiang (Los Alamos, NM); Zhao, Yusheng (Los Alamos, NM)

2005-09-06T23:59:59.000Z

269

Raman spectroscopic studies of chemical speciation in calcium chloride melts  

SciTech Connect (OSTI)

Raman spectroscopy was applied to CaCl2 melts at 900 degrees C under both non-electrolyzed and electrolyzed conditions. The later used titania cathodes supplied by TIMET, Inc. and graphite anodes. Use of pulse-gating to collect the Raman spectra successfully eliminated any interference from black-body radiation and other stray light. The spectrum of molten CaCl2 exhibited no distinct, resolvable bands that could be correlated with a calcium chloride complex similar to MgCl42- in MgCl2 melts. Rather, the low frequency region of the spectrum was dominated by a broad “tail” arising from collective oscillations of both charge and mass in the molten salt “network.” Additions of both CaO and Ca at concentrations of a percent or two resulted in no new features in the spectra. Addition of CO2, both chemically and via electrolysis at concentrations dictated by stability and solubility at 900 degrees C and 1 bar pressure, also produced no new bands that could be correlated with either dissolved CO2 or the carbonate ion. These results indicated that Raman spectroscopy, at least under the conditions evaluated in the research, was not well suited for following the reactions and coordination chemistry of calcium ions, nor species such as dissolved metallic Ca and CO2 that are suspected to impact current efficiency in titanium electrolysis cells using molten CaCl2. Raman spectra of TIMET titania electrodes were successfully obtained as a function of temperature up to 900 degrees C, both in air and in-situ in CaCl2 melts. However, spectra of these electrodes could only be obtained when the material was in the unreduced state. When reduced, either with hydrogen or within an electrolysis cell, the resulting electrodes exhibited no measurable Raman bands under the conditions used in this work.

Windisch, Charles F.; Lavender, Curt A.

2005-02-01T23:59:59.000Z

270

Graphene as a Substrate To Suppress Fluorescence in Resonance Raman Spectroscopy  

E-Print Network [OSTI]

Resonance Raman spectroscopy (RRS), which can enhance Raman signal by 107 times than normal Raman spectroscopy, is a powerful approach to characterize structures of chemicals (especially biomolecules) at low concentrations.1-4 However, fluorescence (FL) background is a major obstacle in RRS because the FL cross section (?10-16 cm2) is much larger than the RRS cross section (?10-22 cm2).3 Several approaches, such as ultraviolet RRS (UV-RRS),1 time-resolved Raman detection,5,6 femtosecond broadband stimu-lated Raman spectroscopy (FSRS),7 and coherent anti-Stokes Raman spectroscopy (CARS),8 have been used to suppress or reject FL background in RRS. However, these approaches need expensive and complex equipments and have other limitations, such as sample degradation in UV-RRS. Surface-enhanced Raman spectroscopy (SERS) is another powerful approach to characterize structures of chemicals at extremely low concentrations or even at the single

Liming Xie; Xi Ling; Yuan Fang; Jin Zhang; Zhongfan Liu

2009-01-01T23:59:59.000Z

271

Chapter 5 - Coal Composition and Reservoir Characterization  

Science Journals Connector (OSTI)

Abstract Coal consists of organic and mineral matter. Fixed carbon from organic matter measures the energy output of coal during combustion. Mineral matter determines how coal responds to combustion and affects reservoir porosity and permeability. Minerals infill pores, cleats, or fractures and replace the organic composition of coal. Organic composition is grouped into maceral association as microlithotypes and macrolithotypes, the latter for megascopic field descriptions (e.g. coal cores and mine face). Coal composition controls reservoir properties such as gas adsorption capacity, gas content, porosity, and permeability. Permeability is important to gas transport from coal matrix pores to the production well. Coal permeability is a function of the width, length, and height of cleats or fractures as well as the aperture, spacing, frequency or density, and connectivity of cleats or fractures. Coal cleats or fractures formed during burial, compaction, and coalification (endogenetic) and after coalification during deformation, uplift, and erosion of the basin of deposition.

Romeo M. Flores

2014-01-01T23:59:59.000Z

272

Nondestructive imaging of an ultracold lattice gas  

E-Print Network [OSTI]

We demonstrate the nondestructive imaging of a lattice gas of ultracold bosons. Atomic fluorescence is induced in the simultaneous presence of degenerate Raman sideband cooling. The combined influence of these processes controllably cycles an atom between a dark state and a fluorescing state while eliminating heating and loss. Through spatially resolved sideband spectroscopy following the imaging sequence, we demonstrate the efficacy of this imaging technique in various regimes of lattice depth and fluorescence acquisition rate. Our work provides an important extension of quantum gas imaging to the nondestructive detection, control and manipulation of atoms in optical lattices. In addition, our technique can also be extended to atomic species that are less amenable to molasses-based lattice imaging.

Y. S. Patil; L. M. Aycock; S. Chakram; M. Vengalattore

2014-04-22T23:59:59.000Z

273

E-Print Network 3.0 - aluminide matrix composites Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Composites by Laser... -particle-reinforced titanium aluminide-matrix composites using TiC and gas-atomized Ti-48Al-2Cr-2Nb powders as the feedstock... been made to fabricate...

274

Ground Gas Handbook  

Science Journals Connector (OSTI)

...pathways of least resistance to gas transport, and applications are discussed, such as migrating landfill gas emissions, also from leaking landfill gas collection systems, as well as natural gas and oil-field gas leakage from abandoned production...

Allen W Hatheway

275

Gas Delivered  

Gasoline and Diesel Fuel Update (EIA)

. Average . Average Price of Natural Gas Delivered to Residential Consumers, 1980-1996 Figure 1980 1982 1984 1986 1988 1990 1992 1994 1996 0 2 4 6 8 10 0 40 80 120 160 200 240 280 320 Dollars per Thousand Cubic Feet Dollars per Thousand Cubic Meters Nominal Dollars Constant Dollars Sources: Nominal dollars: Energy Information Administration (EIA), Form EIA-176, "Annual Report of Natural and Supplemental Gas Supply and Disposition." Constant dollars: Prices were converted to 1995 dollars using the chain-type price indexes for Gross Domestic Product (1992 = 1.0) as published by the U. S. Department of Commerce, Bureau of Economic Analysis. Residential: Prices in this publication for the residential sector cover nearly all of the volumes of gas delivered. Commercial and Industrial: Prices for the commercial and industrial sectors are often associated with

276

TOWARDS AFFECTIVE ALGORITHMIC COMPOSITION  

E-Print Network [OSTI]

TOWARDS AFFECTIVE ALGORITHMIC COMPOSITION Duncan Williams* , Alexis Kirke* , Eduardo Reck Miranda are driving an emerging field: affective algorithmic composition. Strate- gies for algorithmic composition within the last decade) implementing systems for algorithmic composition with the intention of targeting

Miranda, Eduardo Reck

277

Novel Composite Materials Demonstrate Ultra-sensitivity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2, Issue 25 2, Issue 25 Novel Composite Materials Demonstrate Ultra-sensitivity Gold nanowires on graphite templates used in gas sensing application page 2 Coronary Stent Wins Technology Transfer Award page 4 University of Oregon Team Wins Competition for Commercializing NETL Technology page 5 the ENERGY lab NATIONAL ENERGY TECHNOLOGY LABORATORY 2 Novel Composite Materials Demonstrate Ultra-sensitivity-Gold nanowires on graphite templates used in gas sensing applications ____________________2 Coronary Stent Wins Technology Transfer Award ________4 University of Oregon Team Wins Competition for Commercializing NETL Technology __________________5 NETL & WVU Researchers Design New Catalysts for CO 2 Management ___________________________________6 Structurally Dynamic MOF Sorbent Selectively Adsorbs

278

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

73,669 73,669 141,300 1.59 221,822 1.12 3 0.10 46,289 0.88 33,988 1.24 31,006 0.98 252,585 1.26 A r k a n s a s Arkansas 51. Summary Statistics for Natural Gas Arkansas, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 1,750 1,552 1,607 1,563 1,470 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 3,500 3,500 3,500 3,988 4,020 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 171,543 166,273 161,967 161,390 182,895 From Oil Wells ........................................... 39,364 38,279 33,446 33,979 41,551 Total.............................................................. 210,906 204,552 195,413 195,369 224,446 Repressuring ................................................

279

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

-1,080,240 -1,080,240 201,024 2.27 1,734,887 8.78 133 4.54 76,629 1.46 136,436 4.99 46,152 1.46 460,373 2.30 O k l a h o m a Oklahoma 84. Summary Statistics for Natural Gas Oklahoma, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 13,926 13,289 13,487 13,438 13,074 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 28,902 29,118 29,121 29,733 29,733 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 1,674,405 1,732,997 1,626,858 1,521,857 1,467,695 From Oil Wells ........................................... 342,950 316,945 308,006 289,877 267,192 Total.............................................................. 2,017,356 2,049,942 1,934,864

280

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

7,038,115 7,038,115 3,528,911 39.78 13,646,477 69.09 183 6.24 408,861 7.80 1,461,718 53.49 281,452 8.91 5,681,125 28.40 West South Central West South Central 42. Summary Statistics for Natural Gas West South Central, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 87,198 84,777 88,034 88,734 62,357 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 92,212 95,288 94,233 102,525 102,864 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 11,599,913 11,749,649 11,959,444 11,824,788 12,116,665 From Oil Wells ........................................... 2,313,831 2,368,395 2,308,634 2,217,752 2,151,247 Total..............................................................

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

77,379 77,379 94,481 1.07 81,435 0.41 8 0.27 70,232 1.34 1,836 0.07 40,972 1.30 207,529 1.04 K e n t u c k y Kentucky 65. Summary Statistics for Natural Gas Kentucky, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 1,084 1,003 969 1,044 983 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 12,483 12,836 13,036 13,311 13,501 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 79,690 86,966 73,081 74,754 81,435 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. 79,690 86,966 73,081 74,754 81,435 Repressuring ................................................

282

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

-67,648 -67,648 75,616 0.85 480,828 2.43 0 0.00 16,720 0.32 31,767 1.16 29,447 0.93 153,549 0.77 Pacific Noncontiguous Pacific Noncontiguous 45. Summary Statistics for Natural Gas Pacific Noncontiguous, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 9,638 9,907 9,733 9,497 9,294 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 112 113 104 100 102 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 198,603 190,139 180,639 179,470 183,747 From Oil Wells ........................................... 2,427,110 2,588,202 2,905,261 3,190,433 3,189,837 Total.............................................................. 2,625,713 2,778,341

283

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

-310,913 -310,913 110,294 1.24 712,796 3.61 2 0.07 85,376 1.63 22,607 0.83 57,229 1.81 275,508 1.38 K a n s a s Kansas 64. Summary Statistics for Natural Gas Kansas, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 9,681 9,348 9,156 8,571 7,694 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 18,400 19,472 19,365 22,020 21,388 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 580,572 605,578 628,900 636,582 629,755 From Oil Wells ........................................... 79,169 82,579 85,759 86,807 85,876 Total.............................................................. 659,741 688,157 714,659 723,389 715,631 Repressuring ................................................

284

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

819,046 819,046 347,043 3.91 245,740 1.24 40 1.36 399,522 7.62 32,559 1.19 201,390 6.38 980,555 4.90 M i c h i g a n Michigan 70. Summary Statistics for Natural Gas Michigan, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 1,223 1,160 1,323 1,294 2,061 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 3,257 5,500 6,000 5,258 5,826 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 120,287 126,179 136,989 146,320 201,123 From Oil Wells ........................................... 80,192 84,119 91,332 97,547 50,281 Total.............................................................. 200,479 210,299 228,321 243,867 251,404 Repressuring ................................................

285

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

W W y o m i n g -775,410 50,253 0.57 666,036 3.37 14 0.48 13,534 0.26 87 0.00 9,721 0.31 73,609 0.37 Wyoming 98. Summary Statistics for Natural Gas Wyoming, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 10,826 10,933 10,879 12,166 12,320 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 3,111 3,615 3,942 4,196 4,510 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 751,693 880,596 949,343 988,671 981,115 From Oil Wells ........................................... 285,125 142,006 121,519 111,442 109,434 Total.............................................................. 1,036,817 1,022,602 1,070,862 1,100,113 1,090,549 Repressuring

286

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

-67,648 -67,648 75,616 0.85 480,828 2.43 0 0.00 16,179 0.31 31,767 1.16 27,315 0.86 150,877 0.75 A l a s k a Alaska 49. Summary Statistics for Natural Gas Alaska, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 9,638 9,907 9,733 9,497 9,294 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 112 113 104 100 102 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 198,603 190,139 180,639 179,470 183,747 From Oil Wells ........................................... 2,427,110 2,588,202 2,905,261 3,190,433 3,189,837 Total.............................................................. 2,625,713 2,778,341 3,085,900 3,369,904 3,373,584 Repressuring

287

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

628,189 628,189 449,511 5.07 765,699 3.88 100 3.41 528,662 10.09 39,700 1.45 347,721 11.01 1,365,694 6.83 West North Central West North Central 39. Summary Statistics for Natural Gas West North Central, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 10,177 9,873 9,663 9,034 8,156 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 18,569 19,687 19,623 22,277 21,669 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 594,551 626,728 651,594 655,917 648,822 From Oil Wells ........................................... 133,335 135,565 136,468 134,776 133,390 Total.............................................................. 727,886 762,293

288

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

1,048,760 1,048,760 322,661 3.64 18,131 0.09 54 1.84 403,264 7.69 142,688 5.22 253,075 8.01 1,121,742 5.61 N e w Y o r k New York 80. Summary Statistics for Natural Gas New York, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 329 264 242 197 232 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 5,906 5,757 5,884 6,134 6,208 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 22,697 20,587 19,937 17,677 17,494 From Oil Wells ........................................... 824 610 539 723 641 Total.............................................................. 23,521 21,197 20,476 18,400 18,134 Repressuring ................................................

289

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

1,554,530 1,554,530 311,229 3.51 3,094,431 15.67 442 15.08 299,923 5.72 105,479 3.86 210,381 6.66 927,454 4.64 Mountain Mountain 43. Summary Statistics for Natural Gas Mountain, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 38,711 38,987 37,366 39,275 38,944 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 30,965 34,975 38,539 38,775 41,236 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 2,352,729 2,723,393 3,046,159 3,131,205 3,166,689 From Oil Wells ........................................... 677,771 535,884 472,397 503,986 505,903 Total.............................................................. 3,030,499 3,259,277 3,518,556

290

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

1,592,465 1,592,465 716,648 8.08 239,415 1.21 182 6.21 457,792 8.73 334,123 12.23 320,153 10.14 1,828,898 9.14 South Atlantic South Atlantic 40. Summary Statistics for Natural Gas South Atlantic, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 3,307 3,811 4,496 4,427 4,729 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 39,412 35,149 41,307 37,822 36,827 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 206,766 208,892 234,058 236,072 233,409 From Oil Wells ........................................... 7,584 8,011 8,468 7,133 6,706 Total.............................................................. 214,349 216,903 242,526 243,204 240,115

291

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

1,999,161 1,999,161 895,529 10.10 287,933 1.46 1,402 47.82 569,235 10.86 338,640 12.39 308,804 9.78 2,113,610 10.57 Pacific Contiguous Pacific Contiguous 44. Summary Statistics for Natural Gas Pacific Contiguous, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 3,896 3,781 3,572 3,508 2,082 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 1,142 1,110 1,280 1,014 996 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... 156,635 124,207 117,725 96,329 88,173 From Oil Wells ........................................... 294,800 285,162 282,227 289,430 313,581 Total.............................................................. 451,435 409,370

292

Natural Gas  

Gasoline and Diesel Fuel Update (EIA)

-122,394 -122,394 49,997 0.56 178,984 0.91 5 0.17 37,390 0.71 205 0.01 28,025 0.89 115,622 0.58 West Virginia West Virginia 96. Summary Statistics for Natural Gas West Virginia, 1992-1996 Table 1992 1993 1994 1995 1996 Reserves (billion cubic feet) Estimated Proved Reserves (dry) as of December 31 ....................................... 2,356 2,439 2,565 2,499 2,703 Number of Gas and Gas Condensate Wells Producing at End of Year.............................. 38,250 33,716 39,830 36,144 35,148 Production (million cubic feet) Gross Withdrawals From Gas Wells ......................................... E 182,000 171,024 183,773 186,231 178,984 From Oil Wells ........................................... 0 0 0 0 0 Total.............................................................. E 182,000 171,024 183,773 186,231 178,984 Repressuring ................................................

293

Gas vesicles.  

Science Journals Connector (OSTI)

...the gas vesicles simply reduce their sinking rates and...remaining suspended in the water column. A microorganism...phenomena as stratification, water- bloom formation, and...the many proteins that make up the phycobilisome (73...flagellate bacteria in natural waters. The natural selection...

A E Walsby

1994-03-01T23:59:59.000Z

294

Gas vesicles.  

Science Journals Connector (OSTI)

...these costs can be compared is in units of energy expenditure per time (joules per second...requires 7.24 x 10-18 kg of Gvp. The energy cost of making this protein, Eg, is...Eg = 2.84 x 101- o J. The rate of energy expenditure in gas vesicle synthesis then...

A E Walsby

1994-03-01T23:59:59.000Z

295

Gas sensor  

DOE Patents [OSTI]

A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

2014-09-09T23:59:59.000Z

296

Raman scheme for adjustable-bandwidth quantum memory  

SciTech Connect (OSTI)

We propose a scenario of quantum memory for light based on Raman scattering. The storage medium is a vapor and the different spectral components of the input pulse are stored in different atomic velocity classes. One uses appropriate pulses to reverse the resulting Doppler phase shift and to regenerate the input pulse, without distortion, in the backward direction. The different stages of the protocol are detailed and the recovery efficiency is calculated in the semiclassical picture. Since the memory bandwidth is determined by the Raman transition Doppler width, it can be adjusted by changing the angle between the input pulse wave vector and the control beams. The optical depth also depends on the beam angle. As a consequence the available optical depth can be optimized depending on the needed bandwidth. The predicted recovery efficiency is close to 100% for large optical depth.

Le Goueet, J.-L.; Berman, P. R. [Laboratoire Aime Cotton, CNRS UPR3321, Universite Paris Sud, Batiment 505, Campus Universitaire, 91405 Orsay (France); Department of Physics and Michigan Center for Theoretical Physics, University of Michigan, Ann Arbor, Michigan 48109-1040 (United States)

2009-07-15T23:59:59.000Z

297

Theory of Raman scattering in coupled electron-phonon systems  

Science Journals Connector (OSTI)

The Raman spectrum is calculated for a coupled conduction-electron–phonon system in the zero-momentum-transfer limit. The Raman scattering is due to electron-hole excitations and phonons as well. The phonons of those branches that contribute to the electron self-energy and the correction of the electron-phonon vertex are assumed to have flat energy dispersion (the Einstein phonons). The effect of electron-impurity scattering is also incorporated. Both the electron-phonon interaction and the electron-impurity interaction cause the fluctuation of the electron distribution between different parts of the Fermi surface, which results in overdamped zero-sound modes of various symmetries. The scattering cross section is obtained by solving the Bethe-Salpeter equation. The spectrum shows a lower threshold at the smallest Einstein phonon energy when only the electron-phonon interaction is taken into consideration. When impurities are also taken into consideration, the threshold disappears.

K. Itai

1992-01-01T23:59:59.000Z

298

Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets  

Science Journals Connector (OSTI)

Konstantin N. Kudin ,† Bulent Ozbas ,‡ Hannes C. Schniepp ,‡ Robert K. Prud'homme ,‡ Ilhan A. Aksay ,‡ and Roberto Car *† ... 25 Theoretical evaluation of the Raman spectra requires first-, second-, and third-order energy derivatives, among which the most demanding are the second-order derivatives of the energy with respect to the atomic positions (force constants)26 and the third-order polarizability derivatives, twice with respect to the electric field (yielding polarizability) and once with respect to the atomic positions (Raman intensity tensors). ... and the described stable structural isomers (obtained by 2-atom transformations), the ?-orbital energy levels, ?-electron populations, bond orders, and delocalization (resonance) energies were obtained in Hueckel and approx.-SCF ...

Konstantin N. Kudin; Bulent Ozbas; Hannes C. Schniepp; Robert K. Prud'homme; Ilhan A. Aksay; Roberto Car

2007-12-22T23:59:59.000Z

299

X-ray Raman scattering study of aligned polyfluorene  

E-Print Network [OSTI]

We present a non-resonant inelastic x-ray scattering study at the carbon K-edge on aligned poly[9,9-bis(2-ethylhexyl)-fluorene-2,7-diyl] and show that the x-ray Raman scattering technique can be used as a practical alternative to x-ray absorption measurements. We demonstrate that this novel method can be applied to studies on aligned $\\pi$-conjugated polymers complementing diffraction and optical studies. Combining the experimental data and a very recently proposed theoretical scheme we demonstrate a unique property of x-ray Raman scattering by performing the symmetry decomposition on the density of unoccupied electronic states into $s$- and $p$-type symmetry contributions.

S. Galambosi; M. Knaapila; J. A. Soininen; K. Nyg\\aard; S. Huotari; F. Galbrecht; U. Scherf; A. P. Monkman; K. Hämäläinen

2006-08-29T23:59:59.000Z

300

E-Print Network 3.0 - advanced flue gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(WTERT) Collection: Renewable Energy 5 INNOVATIVE TECHNOLOGY FOR THE CONTROL OF AIR POLLUTION AT WASTE-TO-ENERGY Summary: -Beam process is applied to flue gas compositions...

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

E-Print Network 3.0 - atmospheric pressure gas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3... . Gas % Composition ... Source: Prestwich, Ken - Biology Department, College of the Holy Cross Collection: Environmental Sciences and Ecology ; Biology and Medicine 2 Bio390...

302

Multi mode nano scale Raman echo quantum memory  

E-Print Network [OSTI]

Low loss magnetic surface plasmon polariton (SPP) modes characterized by enhanced electrical field component and subwavelength confinement on the dielectric and negative-index metamaterial interface are presented. We demonstrate a possibility of storage and perfect retrieval of the low loss magnetic SPP fields by using a photon echo quantum memory on Raman atomic transition. We describe specific properties of the proposed technique which opens a possibility for efficient nano scale multi-mode quantum memory.

S. A. Moiseev; E. S. Moiseev

2010-01-31T23:59:59.000Z

303

Liquid Natural Gas  

Science Journals Connector (OSTI)

Liquid Natural Gas ... IN A new technique for storing natural gas at the East Ohio Gas Co. plant, Cleveland, Ohio, the gas is liquefied before passing to the gas holders. ... Natural gas contains moisture and carbon dioxide, both of which liquefy before the natural gas and are somewhat of a nuisance because upon solidification they clog the pipes. ...

W. F. SCHAPHORST

1941-04-25T23:59:59.000Z

304

Gas treating alternatives for LNG plants  

SciTech Connect (OSTI)

This paper covers the various gas treating processes available for treating sour natural gas to specifications required for LNG production. The LNG product specification requires that the total sulfur level be less than 30--40 ppmv, the CO{sub 2} level be less than 50 ppmv and the water level be less than 100 ppmv to prevent freezing problems in the LNG cryogenic column. A wide variety of natural gas compositions are encountered in the various fields and the gas treating process selection is dependent on the type of impurities present in the gas, namely, levels of H{sub 2}S, CO{sub 2}, mercaptans and other organic sulfur compounds. This paper discusses the implications various components in the feed to the LNG plant can have on process selection, and the various treating processes that are available to condition the gas. Process selection criteria, design and operating philosophies are discussed. An economic comparison for two treating schemes is provided.

Clarke, D.S.; Sibal, P.W. [Mobil Technology Co., Dallas, TX (United States)

1998-12-31T23:59:59.000Z

305

Charge transfer effects in surface?enhanced Raman scatteringa)  

Science Journals Connector (OSTI)

Surface?enhanced Raman scattering(SERS) due to charge?transferinteractions between the adsorbed molecule and the metal surface is analyzed using the semiempirical Wolfsberg–Helmholz method to relate the molecule–surface interactions and the resulting charge?transfer states to the overlap integrals between the metal conduction?band orbitals and an acceptor or donor molecular orbital of the molecule. Calculations for the model system of ethylene adsorbed on silver with charge?transfer excitation of an electron from the metal to the antibonding etylene ? orbital show that charge?transfer Raman enhancements of the order of 10 to 1000 are possible if the charge?transfer band is partially resonant with the exciting radiation. Symmetric vibrations usually will be enhanced substantially more than nonsymmetric ones by this mechanism because the vibrational coupling is primarily Franck–Condon rather than Herzberg–Teller. The presence of overtone and combination bands in charge?transfer?enhanced Raman spectra is also possible.

Frank J. Adrian

1982-01-01T23:59:59.000Z

306

Fiber Reinforced Polymer Composite Manufacturing Workshop  

Office of Energy Efficiency and Renewable Energy (EERE)

A workshop on Fiber Reinforced Polymer (FRP) Composite Manufacturing (held January 13, 2014, in Arlington, VA) brought together stakeholders from industry and academia to discuss manufacturing of composites. The workshop explored emerging FRP composite market applications in clean energy and barriers to the development and widespread commercial use of these lightweight, high-strength and high-stiffness materials. Improving the manufacturing speed and quality-and reducing their manufacturing costs-could accelerate their use in automotive, wind, compressed gas storage and other clean energy and industrial applications.

307

Characterization of polysilicon films by Raman spectroscopy and transmission electron microscopy: A comparative study  

SciTech Connect (OSTI)

Samples of chemically-vapor-deposited micrometer and sub-micrometer-thick films of polysilicon were analyzed by transmission electron microscopy (TEM) in cross-section and by Raman spectroscopy with illumination at their surface. TEM and Raman spectroscopy both find varying amounts of polycrystalline and amorphous silicon in the wafers. Raman spectra obtained using blue, green and red excitation wavelengths to vary the Raman sampling depth are compared with TEM cross-sections of these films. Films showing crystalline columnar structures in their TEM micrographs have Raman spectra with a band near 497 cm{sup {minus}1} in addition to the dominant polycrystalline silicon band (521 cm{sup {minus}1}). The TEM micrographs of these films have numerous faulted regions and fringes indicative of nanometer-scale silicon structures, which are believed to correspond to the 497cm{sup {minus}1} Raman band.

Tallant, D.R.; Headley, T.J.; Medernach, J.W. [Sandia National Labs., Albuquerque, NM (United States); Geyling, F. [SEMATECH, Austin, TX (United States)

1993-11-12T23:59:59.000Z

308

NATURAL GAS MARKET ASSESSMENT  

E-Print Network [OSTI]

CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

309

,"Missouri Natural Gas Summary"  

U.S. Energy Information Administration (EIA) Indexed Site

Gas Sold to Commercial Consumers (Dollars per Thousand Cubic Feet)","Missouri Natural Gas Industrial Price (Dollars per Thousand Cubic Feet)","Missouri Natural Gas Price Sold to...

310

Natural Gas Weekly Update  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

natural gas production output. Rigs Natural Gas Transportation Update Tennessee Gas Pipeline Company yesterday (August 4) said it is mobilizing equipment and manpower for...

311

UV-Raman spectroscopy, X-ray photoelectron spectroscopy, and temperature programmed desorption studies of model and bulk heterogeneous catalysts  

SciTech Connect (OSTI)

X-ray photoelectron spectroscopy (XPS) and Temperature Programmed Desorption (TPD) have been used to investigate the surface structure of model heterogeneous catalysts in ultra-high vacuum (UHV). UV-Raman spectroscopy has been used to probe the structure of bulk model catalysts in ambient and reaction conditions. The structural information obtained through UV-Raman spectroscopy has been correlated with both the UHV surface analysis and reaction results. The present day propylene and ethylene polymerization catalysts (Ziegler-Natta catalysts) are prepared by deposition of TiCl{sub 4} and a Al(Et){sub 3} co-catalyst on a microporous Mg-ethoxide support that is prepared from MgCl{sub 2} and ethanol. A model thin film catalyst is prepared by depositing metallic Mg on a Au foil in a UHV chamber in a background of TiCl{sub 4} in the gas phase. XPS results indicate that the Mg is completely oxidized to MgCl{sub 2} by TiCl{sub 4} resulting in a thin film of MgCl{sub 2}/TiCl{sub x}, where x = 2, 3, and 4. To prepare an active catalyst, the thin film of MgCl{sub 2}/TiCl{sub x} on Au foil is enclosed in a high pressure cell contained within the UHV chamber and exposed to {approx}1 Torr of Al(Et){sub 3}.

Tewell, Craig R.

2002-08-19T23:59:59.000Z

312

Shale gas is natural gas trapped inside  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary rocks that can be rich sources of petroleum and natural gas. Just a few years ago, much of...

313

Gas Chromatography  

Science Journals Connector (OSTI)

Researchers from the University of Missouri and ICx Nomadics have reported on the use of a optofluidic ring resonator (OFRR) sensor for on-column detection ?. ... Although substantial differences were noted between fresh and aged (or oxidized) oils, many of the compounds in the oxidized oil went unidentified due to lack of library mass spectral data. ... A high resolution MEMS based gas chromatography column for the analysis of benzene and toluene gaseous mixtures ...

Frank L. Dorman; Joshua J. Whiting; Jack W. Cochran; Jorge Gardea-Torresdey

2010-05-26T23:59:59.000Z

314

Development of a time-gated system for Raman spectroscopy of biological samples  

Science Journals Connector (OSTI)

A time gating system has been constructed that is capable of recording high quality Raman spectra of highly fluorescing biological samples while operating below the photodamage...

Knorr, Florian; Smith, Zachary J; Wachsmann-Hogiu, Sebastian

2010-01-01T23:59:59.000Z

315

Looking Inside Catalyst Extrudates with Time-Resolved Surface-Enhanced Raman Spectroscopy (TR-SERS)  

Science Journals Connector (OSTI)

Raman spectroscopy is one of the major characterization methods employed over the last few decades as a nondestructive technique for the study of heterogeneous catalysts and related...

Harvey, Clare E; Petterson, Ingeborg E Iping; Weckhuysen, Bert M; Gooijer, Cees; Ariese, Freek; Mank, Arjan J G

2012-01-01T23:59:59.000Z

316

Liquid absorbent solutions for separating nitrogen from natural gas  

DOE Patents [OSTI]

Nitrogen-absorbing and -desorbing compositions, novel ligands and transition metal complexes, and methods of using the same, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Redmond, OR); Lyon, David K. (Bend, OR); Miller, Warren K. (Bend, OR)

2000-01-01T23:59:59.000Z

317

Feasibility of waterflooding Soku E7000 gas-condensate reservoir  

E-Print Network [OSTI]

We performed a simple 3D compositional reservoir simulation study to examine the possibility of waterflooding the Soku E7 gas-condensate reservoir. This study shows that water injection results in higher condensate recovery than natural depletion...

Ajayi, Arashi

2012-06-07T23:59:59.000Z

318

Processing and Gas Barrier Behavior of Multilayer Thin Nanocomposite Films  

E-Print Network [OSTI]

barrier for goods requiring long shelf life. Current gas barrier technologies like plasma-enhanced vapor deposition (PECVD) often create high barrier metal oxide films, which are prone to cracking when flexed. Bulk composites composed of polymer...

Yang, You-Hao

2012-10-19T23:59:59.000Z

319

Studies of local degradation phenomena in composite cathodes for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Studies of local degradation phenomena in composite cathodes for Studies of local degradation phenomena in composite cathodes for lithium-ion batteries Title Studies of local degradation phenomena in composite cathodes for lithium-ion batteries Publication Type Journal Article Year of Publication 2007 Authors Kerlau, Marie, Marek Marcinek, Venkat Srinivasan, and Robert Kostecki Journal Electrochimica Acta Volume 52 Pagination 5422-5429 Keywords cathode, degradation, li-ion battery, raman microscopy Abstract LiNi0.8Co0.15Al0.05O2 and LiNi1/3Co1/3Mn1/3O2 composite cathodes were cycled in model cells to study interfacial phenomena that could lead to electrode degradation. Ex situ spectroscopic analysis of the tested cathodes, which suffered substantial power and capacity loss, showed that the state of charge (SOC) of oxide particles on the cathode surface was highly non-uniform despite the deep discharge of the Li-ion cell at the end of the test. The inconsistent kinetic behavior of individual oxide particles was attributed to the degradation of electronic pathways within the composite cathodes. A simple theoretical model based on a distributed network showed that an increase of the contact resistance between composite electrode particles may be responsible for non-uniform local kinetic behavior of individual oxide particles and the overall degradation of electrochemical performance of composite electrodes.

320

Gas Sampling Considerations  

Science Journals Connector (OSTI)

Gas sampling is carried out to measure the quality of a gas. Gas samples are sometimes acquired by in situ observation within the main gas body by using remote or visual observation for specific properties. A mor...

Alvin Lieberman

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Georgia Tech Dangerous Gas  

E-Print Network [OSTI]

1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

Sherrill, David

322

Method and apparatus for manufacturing gas tags  

DOE Patents [OSTI]

For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases.

Gross, Kenny C. (Bolingbrook, IL); Laug, Matthew T. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

323

Method and apparatus for manufacturing gas tags  

DOE Patents [OSTI]

For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases. 4 figs.

Gross, K.C.; Laug, M.T.

1996-12-17T23:59:59.000Z

324

Market Digest: Natural Gas  

Reports and Publications (EIA)

The Energy Information Administration's Natural Gas Market Digest provides information and analyses on all aspects of natural gas markets.

2014-01-01T23:59:59.000Z

325

Gas Chromatography  

Science Journals Connector (OSTI)

He received his B.S. degree in 1970 from Rhodes College in Memphis, TN, his M.S. degree in 1973 from the University of Missouri, Columbia, MO, and his Ph.D. degree in 1975 from Dalhousie University, Halifax, Nova Scotia, Canada. ... A review (with 145 references) on the role of carrier gases on the separation process (A4) demonstrates that carrier gas interactions are integral to the chromatographic process. ... In another report, activity coefficients for refrigerants were evaluated with a polyol ester oil stationary phase (C22). ...

Gary A. Eiceman; Herbert H. Hill, Jr.; Jorge Gardea-Torresdey

2000-04-25T23:59:59.000Z

326

Diamond/aluminium nitride composites for efficient thermal management applications  

SciTech Connect (OSTI)

Synthetic diamond/AlN composite materials have been fabricated by a combination of microwave plasma-assisted chemical vapor deposition and molecular beam epitaxy. These wide band gap semiconductor heterojunctions show promises for many applications, including thermal management, deep ultraviolet light emitting devices, and high power and high temperature electronics. Here, we report results of an interface study of polycrystalline diamond layers grown on single crystal AlN(0001). High resolution transmission microscopy revealed atomically sharp interfaces between diamond and AlN. Temperature dependent Raman spectroscopy measurements showed reduced thermal resistance on diamond-coated AlN substrates compared to uncoated AlN at temperatures above 330 K.

Cervenka, J.; Dontschuk, N.; Prawer, S. [School of Physics, University of Melbourne, VIC (Australia); Ladouceur, F. [School of Electrical Engineering and Telecommunications, University of New South Wales, Sydney, NSW (Australia); Duvall, S. G. [Silanna Semiconductor Pty Ltd., Sydney, NSW (Australia)

2012-07-30T23:59:59.000Z

327

NETL: Novel Inorganic/Polymer Composite Membranes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Novel Inorganic/Polymer Composite Membranes Novel Inorganic/Polymer Composite Membranes Project No.: DE-FE0007632 Ohio State University is developing a cost-effective design and manufacturing process for new membrane modules that capture carbon dioxide (CO2) from flue gas. The membranes consist of a thin, selective inorganic layer, embedded in a polymer structure so that it can be made in a continuous manufacturing process. They will be incorporated in spiral-wound modules for bench-scale tests using coal-fired flue gas. Preliminary cost calculations show that a single-stage membrane process is economically unfavorable, primarily because of the low concentration of CO2 (~14 percent) in the flue gas stream. A two-stage process is more economical, but requires plant operation with a CO2-enriched recycle stream.

328

RtS>-l-2437 Utilization of the Isotoplc Composition of  

E-Print Network [OSTI]

131+Xe132. This conversion is of importance in the calculation of the total Xe generation duringRtS«>-l»-2437 3*- if, -. Utilization of the Isotoplc Composition of Xe and Kr in Fission Gas 4* #12;RIS�-M-2437 UTILIZATION OF THE ISOTOPIC COMPOSITION OF Xe AND Kr IN FISSION GAS RELEASE

329

Sol-gel synthesis of mesoporous CaCu{sub 3}Ti{sub 4}O{sub 12} thin films and their gas sensing response  

SciTech Connect (OSTI)

A new sol-gel synthesis procedure of stable calcium copper titanate (CaCu{sub 3}Ti{sub 4}O{sub 12}-CCTO) precursor sols for the fabrication of porous films was developed. The composition of the sol was selected in order to avoid the precipitation of undesired phases; ethanol was used as solvent, acetic acid as modifier and poly(ethyleneglycol) as a linker agent. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 {sup o}C. The main phase present in the samples, as detected by X-ray diffraction and Raman spectroscopy, was CaCu{sub 3}Ti{sub 4}O{sub 12}. Scanning electron microscopy analysis showed that mesoporous structures, with thicknesses between 200 and 400 nm, were developed as a result of the processing conditions. The films were tested regarding their sensibility towards oxygen and nitrogen at atmospheric pressure using working temperatures from 200 to 290 {sup o}C. The samples exhibited n-type conductivity, high sensitivity and short response times. These characteristics indicate that CCTO mesoporous structures obtained by sol-gel are suitable for application in gas sensing. - Graphical abstract: A sol-gel synthesis procedure toward stable CaCu{sub 3}Ti{sub 4}O{sub 12}-precursor sols avoiding the precipitation of undesired compounds is proposed. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 {sup o}C. The thickness varied between 200 and 400 nm depending on sol composition. The films, tested as gas sensors for O{sub 2}, showed n-type conductivity, good sensitivity and short response times.

Parra, R., E-mail: rparra@fi.mdp.edu.a [Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA), CONICET-UNMdP, J. B. Justo 4302, B7608FDQ Mar del Plata (Argentina); Savu, R. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Ramajo, L.A.; Ponce, M.A. [Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA), CONICET-UNMdP, J. B. Justo 4302, B7608FDQ Mar del Plata (Argentina); Varela, J.A. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Castro, M.S. [Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA), CONICET-UNMdP, J. B. Justo 4302, B7608FDQ Mar del Plata (Argentina); Bueno, P.R. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Joanni, E. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Centro de Tecnologia da Informacao Renato Archer, Rodovia Dom Pedro I (SP-65) km 143, 6, 13069-901 Campinas, SP (Brazil)

2010-06-15T23:59:59.000Z

330

Raman Microscopy and Mapping as a Probe for Photodegradation in Surface Relief Gratings Recorded on Layer-by-Layer Films of Congo Red/Polyelectrolyte  

Science Journals Connector (OSTI)

Raman microscopy, mapping, and surface-enhanced Raman scattering techniques have been applied to investigate the degradation of Congo Red (CR) in a surface relief grating (SRG)...

Constantino, C J L; Aroca, R F; He, J -A; Zucolotto, V; Li, L; Oliveira, O N; Kumar, J; Tripathy, S K

2002-01-01T23:59:59.000Z

331

Raman microscopy and x-ray fluorescence analysis of pigments on medieval and Renaissance Italian manuscript cuttings  

Science Journals Connector (OSTI)

...are the predominant elements with small amounts of arsenic and mercury (Fig. 4, top). Medieval...syntheses . J Raman Spectrosc 30 : 355 – 360 . 38 de Faria DLA Venauncio Silva S de Oliveira MT ( 1997 ) Raman microspectroscopy...

Lucia Burgio; Robin J. H. Clark; Richard R. Hark

2010-01-01T23:59:59.000Z

332

Raman scattering and X-ray diffraction study of the thermal decomposition of an ettringite-group crystal  

Science Journals Connector (OSTI)

...?A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal is presented. Raman spectra, ... previous studies that reported higher temperatur...

S. K. Deb; M. H. Manghnani; K. Ross; R. A. Livingston…

2003-02-01T23:59:59.000Z

333

Raman spectroscopy of selected arsenates—implications for soil remediation  

Science Journals Connector (OSTI)

The contamination of soils with heavy metals such as As, Cr and Cu is of great importance; the remediation of such soils even more so. Arsenic compounds are prevalent in soils either through leaching of mine tailings, the use of Cu/Cr/As as a wood preservative or through the use of arsenic in cattle dips. The arsenic compounds in soils and leachates can be highly reactive and mobile, resulting in the formation of metal arsenate compounds. Of these compounds, one such set of minerals that can be formed is the vivianite arsenate minerals. Raman spectroscopy has been used to characterise the vivianite arsenates and to identify arsenic contaminants in a soil.

Ray L. Frost; Theo Kloprogge; Matthew L. Weier; Wayde N. Martens; Z. Ding; Howell G.H. Edwards

2003-01-01T23:59:59.000Z

334

Geometrical constraints on plasma couplers for Raman compression  

SciTech Connect (OSTI)

Backward Raman compression in plasma is based on a 3-wave resonant interaction, which includes two counter-propagating laser pulses (pump and seed pulses) and an electron plasma wave (Langmuir wave). The resonant interaction can be ensured in nearly homogeneous plasmas. However, for high-power, large-aperture experiments, the homogeneous region becomes pancake-shaped and would likely be surrounded by thicker regions of inhomogeneous plasma. When these inhomogeneous plasma regions are extensive, significant inverse bremsstrahlung and seed dispersion may impede the compression effect. These deleterious effects may, however, be mitigated by chirping the seed and pump pulses.

Toroker, Z. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Malkin, V. M. [Department of Astrophysical Sciences, Princeton University, Princeton, New Jersey 08544 (United States); Balakin, A. A.; Fraiman, G. M. [Institute of Applied Physics RAS, Nizhnii Novgorod 603950 (Russian Federation); Fisch, N. J. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Department of Astrophysical Sciences, Princeton University, Princeton, New Jersey 08544 (United States)

2012-08-15T23:59:59.000Z

335

Composite coatings improve engines  

SciTech Connect (OSTI)

About 40% of the power loss in engine systems is attributed to the adverse effects of friction in reciprocating engine components. Over half of this power loss is caused by friction between pistons, piston rings, and cylinder bores. In addition, engine parts may be attacked by corrosive gasoline substitutes such as liquid propane gas and alcohol/gasoline mixtures. To solve both friction and corrosion problems, Nihon Parkerizing Co. has improved the nickel-phosphorus based ceramic composite (NCC) plating technology that was developed for cylinder bores and pistons by Suzuki Motor Co. in the mid 1970s. Iron and nickel-based composite plating technologies have been investigated since the early 1970s, and a few have been used on small two-stroke motorcycle, outboard marine, snowmobile, and some luxury passenger car engine components. Both nickel- and iron-base plating processes are used on cylinders and pistons because they offer excellent wear and corrosion resistance. Nickel-base films have higher corrosion resistance than those based on iron, and are capable of withstanding the corrosive conditions characteristic of high methanol fuels. Unfortunately, they experience a decrease in hardness as operating temperatures increase. However, NCC coatings with phosphorus additions have high hardness even under severe operating conditions, and hardness increases upon exposure to elevated temperatures. In addition to high hardness and corrosion resistance, NCC coatings provide a low friction coefficient, which contributes to the reduction of friction losses between sliding components. When used in low-quality or alcohol fuels, the corrosion resistance of NCC coatings is far higher than that of Fe-P plating. Additionally, the coatings reduce wall and piston temperature, wear of ring groove and skirt, and carbon deposit formation, and they improve output power and torque. These advantages all contribute to the development of light and efficient engines with better fuel mileage.

Funatani, K.; Kurosawa, K. (Nihon Parkerizing Co. Ltd., Nagoya (Japan))

1994-12-01T23:59:59.000Z

336

Stability of natural gas in the deep subsurface  

SciTech Connect (OSTI)

Natural gas is becoming increasingly important as a fuel because of its widespread occurrence and because it has a less significant environmental impact than oil. Many of the known gas accumulations were discovered by accident during exploration for oil, but with increasing demand for gas, successful exploration will require a clearer understanding of the factors that control gas distribution and gas composition. Natural gas is generated by three main processes. In oxygen-deficient, sulfate-free, shallow (few thousand feet) environments bacteria generate biogenic gas that is essentially pure methane with no higher hydrocarbons ({open_quotes}dry gas{close_quotes}). Gas is also formed from organic matter ({open_quotes}kerogen{close_quotes}), either as the initial product from the thermal breakdown of Type III, woody kerogens, or as the final hydrocarbon product from all kerogen types. In addition, gas can be formed by the thermal cracking of crude oil in the deep subsurface. The generation of gas from kerogen requires higher temperatures than the generation of oil. Also, the cracking of oil to gas requires high temperatures, so that there is a general trend from oil to gas with increasing depth. This produces a well-defined {open_quotes}floor for oil{close_quotes}, below which crude oil is not thermally stable. The possibility of a {open_quotes}floor for gas{close_quotes} is less well documented and understanding the limits on natural gas occurrence was one of the main objectives of this research.

Barker, C.

1996-07-01T23:59:59.000Z

337

Chemical and Isotopic Composition and Gas Concentrations of Ground Water and Surface Water from Selected Sites At and Near the Idaho National Engineering and Environmental Laboratory, Idaho, 1994-97  

SciTech Connect (OSTI)

>From May 1994 through May 1997, the US Geological Survey, in cooperation with the US Department of Energy, collected water samples from 86 wells completed in the Snake River Plain aquifer at and near the Idaho National Engineering and Environmental Laboratory. The samples were analyzed for a variety of chemical constituents including all major elements and 22 trace elements. Concentrations of scandium, yttrium, and the lanthanide series were measured in samples from 11 wells and 1 hot spring. The data will be used to determine the fraction of young water in the ground water. The fraction of young water must be known to calculate the ages of ground water using chlorofluorocarbons. The concentrations of the isotopes deuterium, oxygen-18, carbon-13, carbon-14, and tritium were measured in many ground water, surface-water and spring samples. The isotopic composition will provide clues to the origin and sources of water in the Snake River Plain aquifer. Concentrations ! of helium-3 , helium-4, total helium, and neon were measured in most groundwater samples, and the results will be used to determine the recharge temperature, and to date the ground waters.

E. Busenberg; L. N. Plummer; M. W. Doughten; P. K. Widman; R. C. Bartholomay (USGS)

2000-05-30T23:59:59.000Z

338

SeZnSb alloy and its nano tubes, graphene composites properties  

SciTech Connect (OSTI)

Composite can alter the individual element physical property, could be useful to define the specific use of the material. Therefore, work demonstrates the synthesis of a new composition Se{sub 96}-Zn{sub 2}-Sb{sub 2} and its composites with 0.05% multi-walled carbon nano tubes and 0.05% bilayer graphene, in the glassy form. The diffused amorphous structure of the multi walled carbon nano tubes and bilayer gaphene in the Se{sub 96}-Zn{sub 2}-Sb{sub 2} alloy have been analyzed by using the Raman, X-ray photoluminescence spectroscopy, Furrier transmission infrared spectra, photoluminescence, UV/visible absorption spectroscopic measurements. The diffused prime Raman bands (G and D) have been appeared for the multi walled carbon nano tubes and graphene composites, while the X-ray photoluminescence core energy levels peak shifts have been observed for the composite materials. Subsequently the photoluminescence property at room temperature and a drastic enhancement (upto 80%) in infrared transmission percentage has been obtained for the bilayer graphene composite, along with optical energy band gaps for these materials have been evaluated 1.37, 1.39 and 1.41 eV.

Singh, Abhay Kumar [Department of Physics, Indian Institute of Physics, Bangalore-560012 (India)

2013-04-15T23:59:59.000Z

339

Laser-Scanning Coherent Anti-Stokes Raman Scattering Microscopy and Applications to Cell Biology  

E-Print Network [OSTI]

Laser-Scanning Coherent Anti-Stokes Raman Scattering Microscopy and Applications to Cell Biology Ji 11747-3157 USA ABSTRACT Laser-scanning coherent anti-Stokes Raman scattering (CARS) microscopy with fast., 1990). Duncan et al. constructed the first CARS microscope by use of two dye laser beams

Xie, Xiaoliang Sunney

340

Chapter 14 Treatise on Geochemistry Raman and Nuclear Resonant Spectroscopy in Geosciences  

E-Print Network [OSTI]

Chapter 14 Treatise on Geochemistry 1 Raman and Nuclear Resonant Spectroscopy in Geosciences Jung Advanced Photon Source, Argonne National Laboratory, Argonne, IL, USA Alexander F. Goncharov Geophysical technical advances in Raman and nuclear resonance spectroscopy (both Mössbauer spectroscopy and nuclear

Lin, Jung-Fu "Afu"

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Raman studies of corrosion layers formed on archaeological irons in various media  

E-Print Network [OSTI]

147 Raman studies of corrosion layers formed on archaeological irons in various media Ludovic mandana.saheb@cea.fr, f philippe.dillmann@cea.fr Keywords: Raman spectroscopy, iron corrosion, ancient artefact, imaging. Abstract. The description and identification of corrosion products formed

342

Raman excitation profiles for the (n1, n2) assignment in carbon nanotubes  

E-Print Network [OSTI]

Raman excitation profiles for the (n1, n2) assignment in carbon nanotubes H. Telg , J. Maultzsch indices n1 and n2 in semiconducting and metallic nanotubes was performed comparing resonance Raman nanotube families. Ever since the discovery of how to keep isolated nanotubes from rebundeling in solu

Nabben, Reinhard

343

10.1098/rsta.2004.1444 Resonant Raman spectroscopy of nanotubes  

E-Print Network [OSTI]

10.1098/rsta.2004.1444 Resonant Raman spectroscopy of nanotubes By Christian Thomsen1 , Stephanie. The experimental situation in carbon nanotubes is reviewed in view of these criteria. The evidence for the D mode for the application of Raman scattering to the characterization of nanotubes are discussed. Keywords: carbon nanotubes

Nabben, Reinhard

344

POLARIZED RAMAN MEASUREMENTS IN ZEOLITE-GROWN SINGLE-WALL CARBON NANOTUBES  

E-Print Network [OSTI]

POLARIZED RAMAN MEASUREMENTS IN ZEOLITE-GROWN SINGLE-WALL CARBON NANOTUBES J. Maultzsch*, P. M, Hardenbergstr. 36, D-10623 Berlin, E-Mail: janina@physik.tu-berlin.de The Raman spectra of carbon nanotubes able to grow carbon nanotubes inside the channels of an AlPO4 zeolite crystal [1]. The directions

Nabben, Reinhard

345

Raman characterization of boron-doped multiwalled carbon nanotubes J. Maultzsch,a)  

E-Print Network [OSTI]

. We interpret this result as an indication that the high-energy mode in carbon nanotubes is defectRaman characterization of boron-doped multiwalled carbon nanotubes J. Maultzsch,a) S. Reich, and C of boron-doped multiwalled carbon nanotubes. The Raman intensities are analyzed as a function

Nabben, Reinhard

346

Raman scattering in carbon nanotubes Technische Universitat Berlin, Hardenbergstrasse 36, 10623 Berlin, Germany  

E-Print Network [OSTI]

in carbon nanotubes is the strong excitation-energy dependent Raman shift of the socalled D-mode, which for instance for metallic nanotubes near the K-point. For a given incident photon energy, there is an incomingRaman scattering in carbon nanotubes C. Thomsen Technische Universit¨at Berlin, Hardenbergstrasse

Nabben, Reinhard

347

Origin of the high-energy Raman modes in single-wall carbon nanotubes  

E-Print Network [OSTI]

Origin of the high-energy Raman modes in single-wall carbon nanotubes J. Maultzsch, C. Thomsen, S nanotubes. Similar to the disorder-induced D mode, the high-energy modes are deter- mined by double of the first-order high-energy Raman modes in carbon nanotubes has been a puzzling question since the first

Nabben, Reinhard

348

Raman spectroscopy on single and multi-walled nanotubes under high pressure  

E-Print Network [OSTI]

dependence of the high-energy Raman modes in single and multi-walled carbon nanotubes was measuredRaman spectroscopy on single and multi-walled nanotubes under high pressure C. Thomsen, S. Reich, H properties of carbon nanotubes have become of scienti c interest since it was recognized that the low atomic

Nabben, Reinhard

349

Raman intensity measurements of single-walled carbon nanotube suspensions as a quantitative technique  

E-Print Network [OSTI]

Raman intensity measurements of single-walled carbon nanotube suspensions as a quantitative, Biological and Materials Engineering, Carbon Nanotube Technology Center (CANTEC), University of Oklahoma, 100 the purity of single-walled carbon nanotube (SWCNT) bulk samples based on Raman spectroscopy is reported

Resasco, Daniel

350

RAMAN SPECTROSCOPY OF MACROSCALE FIBERS COMPRISED OF CARBON NANOTUBES OF DIFFERENT  

E-Print Network [OSTI]

RAMAN SPECTROSCOPY OF MACROSCALE FIBERS COMPRISED OF CARBON NANOTUBES OF DIFFERENT LENGTHS UNDER University Carbon nanotube (CNT) fibers are considered an excellent material for high performance engineering) Fibers Raman Spectroscopy of Macroscopic Fibers Spun from Carbon Nanotubes under Tensile Strain D

Mellor-Crummey, John

351

Sulfates on Mars: A systematic Raman spectroscopic study of hydration states of magnesium sulfates  

E-Print Network [OSTI]

Sulfates on Mars: A systematic Raman spectroscopic study of hydration states of magnesium sulfates of magnesium sulfates on the martian surface. In situ identification of the hydration states of magnesium of magnesium sulfate. Characteristic and distinct Raman spectral patterns were observed for each of the 11

352

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates*  

E-Print Network [OSTI]

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates samples, such as petroleum and coal, or for man-made samples, such as coal liquids, a major desire- nique for studying coal-liquid samples. 1-4 We demon- strated that the Raman spectra of polycyclic

Asher, Sanford A.

353

Micro-Raman spectroscopy of refractive index microstructures in silicone-based hydrogel  

E-Print Network [OSTI]

Micro-Raman spectroscopy of refractive index microstructures in silicone-based hydrogel polymers 26, 2009 (Doc. ID 102944); published March 3, 2009 Micro-Raman spectroscopy was used to study transparent hydro- gel polymer materials through a high (or medium) nu- merical aperture (NA) objective

Novotny, Lukas

354

Demonstration of stimulated Raman scattering in the evanescent field of a tapered nanofiber  

E-Print Network [OSTI]

in the following figure the modal Raman gain for a nanofiber immersed in a mixture of toluene and ethanol ; ethanol is used to reduce the refractive index below the one of silica. Fig. 1: Raman gain experienced by the guided mode versus the nanofiber radius and the fraction volume of toluene in a mixture of toluene-ethanol

Boyer, Edmond

355

Forward Raman compression via photonic band gap in metals or warm dense matter  

SciTech Connect (OSTI)

The group velocity of a light pulse in photonic band gap material could considerably deviate from the speed of light in vacuum. A forward stoke and a pump pulse of different speeds would enable the Raman compression in metals or the warm dense matter. A small window of the parameter regime, where the compression is feasible via the forward Raman scattering, is identified.

Son, S. [18 Caleb Lane, Princeton, New Jersey 08540 (United States); Moon, Sung Joon [Program in Applied and Computational Mathematics, Princeton University, Princeton, New Jersey 08544 (United States)

2011-08-15T23:59:59.000Z

356

Thermogenic and secondary biogenic gases, San Juan Basin, Colorado and New Mexico - Implications for coalbed gas producibility  

SciTech Connect (OSTI)

The objectives of this paper are to (1) describe the types and the major components of coalbed gases, (2) evaluate the variability of Fruitland coalbed gas composition across the basin, (3) assess factors affecting coalbed gas origin and composition, (4) determine the timing and extent of gas migration and entrapment, and (5) suggest application of these results to coalbed gas producibility. Data from more than 750 Fruitland coalbed gas wells were used to make gas-composition maps and to evaluate factors controlling gas origin. The gas data were divided into overpressured, underpressured, and transitional categories based on regional pressure regime. Also, [delta][sup 13]C isotopic values from 41 methane, 7 ethane and propane, 13 carbon dioxide, and 10 formation-water bicarbonate samples were evaluated to interpret gas origin. The data suggests that only 25-50% of the gas produced in the high-productivity fairway was generated in situ during coalification. 82 refs., 14 figs., 3 tabs.

Scott, A.R.; Kaiser, W.R. (Univ. of Texas, Austin, TX (United States)); Ayers, W.B. Jr. (Taurus Exploration, Inc., Birmingham, AL (United States))

1994-08-01T23:59:59.000Z

357

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

358

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

359

Evaluation of the 3D-furnace simulation code AIOLOS by comparing CFD predictions of gas compositions with in-furnace measurements in a 210MW coal-fired utility boiler  

Science Journals Connector (OSTI)

The furnace of a pulverised coal-fired utility boiler with a thermal output of 210MW, with dimensions of 8m x 8m x 29m and 12 burners located on three levels, is considered. Coal combustion is described by a five-step-reaction scheme. The model covers two heterogeneous reactions for pyrolysis and char combustion and three gas phase reactions for the oxidation of volatile matter. A standard k, ?-model is used for the description of turbulence. The interaction of turbulence and chemistry is modelled using the Eddy Dissipation Concept (EDC). The transport equations for mass, momentum, enthalpy and species are formulated in general curvilinear co-ordinates enabling an accurate treatment of boundaries and a very good control over the distribution of the grid lines. The discretisation is based on a non-staggered finite-volume approach and the coupling of velocities and pressure is achieved by the SIMPLEC method. Numerical diffusion is minimised by the use of the higher-order discretisation scheme MLU. The accuracy of the predictions is demonstrated by comparing the computational results with in-furnace measurements of carbon monoxide, carbon dioxide and oxygen concentrations and of temperatures.

Hermann Knaus; Uwe Schnell; Klaus R.G. Hein

2001-01-01T23:59:59.000Z

360

Propagation of light in low pressure gas  

E-Print Network [OSTI]

The criticism by W. E. Lamb, W. Schleich, M. Scully, C. Townes of a simplified quantum electrodynamics which represents the photon as a true particle is illustrated. Collisions being absent in low-pressure gas, exchanges of energy are radiative and coherent. Thin shells of plasma containing atoms in a model introduced by Str\\"omgren are superradiant, seen as circles possibly dotted. Spectral radiance of novae has magnitude of laser radiance, and column densities are large in nebulae: Superradiance, multiphoton effects, etc., work in astrophysics. The superradiant beams induce multiphotonic scatterings of light emitted by the stars, brightening the limbs of plasma bubbles and darkening the stars. In excited atomic hydrogen, impulsive Raman scatterings shift frequencies of light. Microwaves exchanged with the Pioneer probes are blueshifted, simulating anomalous accelerations. Substituting coherence for wrong calculations in astrophysical papers, improves results, avoids "new physics".

Jacques Moret-Bailly

2012-04-13T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Fuel gas conditioning process  

DOE Patents [OSTI]

A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

Lokhandwala, Kaaeid A. (Union City, CA)

2000-01-01T23:59:59.000Z

362

Detection and quantitative analysis of ferrocyanide and ferricyanide: FY 93 Florida State University Raman spectroscopy report  

SciTech Connect (OSTI)

This report provides a summary of work to develop and investigate the feasibility of using Raman spectroscopy with tank waste materials. It contains Raman spectra from organics, such as ethylenediaminetetraacetic acid (EDTA), hydroxyethylenediaminetetraacteic acid (HEDTA), imino diacetic acid (IDA), kerosene, tributyl phosphate (TBP), acetone and butanol, anticipated to be present in tank wastes and spectra from T-107 real and BY-104 simulant materials. The results of investigating Raman for determining moisture content in tank materials are also presented. A description of software algorithms developed to process Raman spectra from a dispersive grating spectrometer system and an in initial design for a data base to support qualitative and quantitative application of remote Raman sensing with tank wastes.

Mann, C.K.; Vickers, T.J. [Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry

1994-10-11T23:59:59.000Z

363

The effect of fuel composition on flame dynamics  

SciTech Connect (OSTI)

As fuel sources diversify, the gas turbine industry is under increasing pressure to develop fuel-flexible plants, able to use fuels with a variety of compositions from a large range of sources. However, the dynamic characteristics vary considerably with composition, in many cases altering the thermoacoustic stability of the combustor. We compare the flame dynamics, or the response in heat release rate of the flame to acoustic perturbations, of the three major constituents of natural gas: methane, ethane, and propane. The heat release rate is quantified using OH* chemiluminescence and product gas temperature. Gas temperature is measured by tracking the absorption of two high-temperature water lines, via Tunable Diode Laser Absorption Spectroscopy. The flame dynamics of the three fuels differ significantly. The changes in flame dynamics due to variations in fuel composition have the potential to have a large effect on the thermoacoustic stability of the combustor. (author)

Hendricks, Adam G.; Vandsburger, Uri [Department of Mechanical Engineering - 0238, Virginia Tech, Blacksburg, VA 24061 (United States)

2007-10-15T23:59:59.000Z

364

New C-H Stretching Vibrational Spectral Features in the Raman Spectra of Gaseous and Liquid Ethanol  

E-Print Network [OSTI]

New C-H Stretching Vibrational Spectral Features in the Raman Spectra of Gaseous and Liquid Ethanol Traditionally, the Raman spectrum of ethanol in the C-H vibrational stretching region between 2800 cm-1 and 3100, and the -CH3 antisymmetric stretching. In this report, new Raman spectral features were observed for ethanol

Liu, Shilin

365

The effect of substrates on the Raman spectrum of graphene: Graphene-on-sapphire and graphene-on-glass  

E-Print Network [OSTI]

The effect of substrates on the Raman spectrum of graphene: Graphene- on-sapphire and graphene The authors investigated the influence of substrates on Raman scattering spectrum from graphene. The room-temperature Raman signatures from graphene layers on GaAs, sapphire, and glass substrates were compared with those

366

Pump side scattering in ultrapowerful backward Raman amplifiers A. A. Solodov, V. M. Malkin, and N. J. Fisch  

E-Print Network [OSTI]

Pump side scattering in ultrapowerful backward Raman amplifiers A. A. Solodov, V. M. Malkin, and N of a laser pump by plasma noise might be suppressed by an appropriate detuning of the Raman resonance, even scattering of laser pumps by plasma noise in backward Raman amplifiers. Though its growth rate is smaller

367

Welding of cast A359/SiC/10p metal matrix composites  

E-Print Network [OSTI]

arc welding GTAW Gas tungsten arc welding HAZ Heat affected zone HF High frequency MMC Metal matrix composite MMCs Metal matrix composites NDE Non-destructive examination SAW Submerged arc welding SMAW Shielded metal arc... limited their applications. Further, the use of composite materials requires us to stay from the established processes and areas of practice that were relevant to more conventional engineering materials. Except for gas tungsten arc welding (GTAW...

Kothari, Mitul Arvind

2005-11-01T23:59:59.000Z

368

Raman scattering induced by carbon vacancies in TiCx  

Science Journals Connector (OSTI)

Carbon vacancies in cubic TiCx induce a first-order Raman spectrum, the three independent components of which have been studied for x=0.97, 0.90, and 0.80. The spectra mimic, approximately, the calculated phonon density of states with some lowering of the upper edge of the gap between the acoustical- and optical-phonon regions and with some filling in of the valleys between prominent peaks for lower values of x. There is a tendency towards saturation of the integrated spectra with increasing vacancy concentration. Expressions are derived for the efficiency of light scattering from a disordered metal crystal. They agree with the corresponding results for transparent crystals when corrected for geometric and propagation effects. Analysis of the data using a Raman sum rule indicates that the mean-square polarizability derivative induced by carbon vacancies on carbon and titanium atoms is about the same; the large magnitudes observed here are evidence for resonant enhancement. The probabilities for clustering of vacancies are discussed, and it is concluded that clustering is so likely, even for x=0.97, that the experimental results cannot be interpreted as characteristic of isolated vacancies.

M. V. Klein, John A. Holy, and W. S. Williams

1978-02-15T23:59:59.000Z

369

Exhaust gas treatment by an atmospheric pressure microwave plasma  

Science Journals Connector (OSTI)

A microwave process for treating exhaust gases from internal combustion engines is presented. The exhaust gases are ionised by microwave energy at 2.45 GHz and the resultant plasma jet discharges into ambient air and exhaust gas environment. A gas analyser was used to measure the change in exhaust gas composition due to the influence of the plasma. Large decreases in CO2, CO and hydrocarbon levels, accompanied by an increase in NO levels, were found.

Carlos A. Destefani; Elias Siores

2002-01-01T23:59:59.000Z

370

In situ apparatus for the study of clathrate hydrates relevant to solar system bodies using synchrotron X-ray diffraction and Raman spectroscopy  

E-Print Network [OSTI]

Clathrate hydrates are believed to play a significant role in various solar system environments, e.g. comets, and the surfaces and interiors of icy satellites, however the structural factors governing their formation and dissociation are poorly understood. We demonstrate the use of a high pressure gas cell, combined with variable temperature cooling and time-resolved data collection, to the in situ study of clathrate hydrates under conditions relevant to solar system environments. Clathrates formed and processed within the cell are monitored in situ using synchrotron X-ray powder diffraction and Raman spectroscopy. X-ray diffraction allows the formation of clathrate hydrates to be observed as CO2 gas is applied to ice formed within the cell. Complete conversion is obtained by annealing at temperatures just below the ice melting point. A subsequent rise in the quantity of clathrate is observed as the cell is thermally cycled. Four regions between 100-5000cm-1 are present in the Raman spectra that carry feature...

Day, Sarah J; Evans, Aneurin; Parker, Julia E

2015-01-01T23:59:59.000Z

371

Notch sensitivity of fatigue life in a Sylramic TM composite at elevated temperature  

E-Print Network [OSTI]

sensitivity; Fatigue; SiC composite; Embrittlement 1. Introduction Continuous-fiber ceramic composites (CFCCs in advanced gas turbine engines. The motivation for this activity is the desire to increase operating are expelled during unloading and the oxidizing atmosphere drawn into the composite through matrix cracks

Zok, Frank

372

Remediation of Risks in Natural Gas Storage Produced Waters: The Potential Use of Constructed Wetland Treatment Systems.  

E-Print Network [OSTI]

??Natural gas storage produced waters (NGSPWs) are generated in large volumes, vary in composition, and often contain constituents in concentrations and forms that are toxic… (more)

Johnson, Brenda

2006-01-01T23:59:59.000Z

373

Microcracking in fibrous composites  

E-Print Network [OSTI]

are conducted on a unidirectional graphite fiber-reinforced epoxy in order to determine some aspects of nonlinear behavior, and the results of microcracking. The nature. of the microstructure of composites and the microcracking that occurs in composites... of microscopy samples. 53 21. Graphite composite surfaces, as received (top, 60X) and as prepared (bottom, 100X) ~ 56 22, Graphite composite surfaces after peeling (1000X). 58 23. Scotchply surfaces after peeling (1000X). 60 24. Graphite composite damaged...

Conrad, Nicholas

2012-06-07T23:59:59.000Z

374

Influence of Mixing and Fuel Composition on Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixing and Fuel Composition Mixing and Fuel Composition on Emissions * Lean premixed combustion is effective for emission reduction More sensitive to perturbations including fuel gas composition variability * UC Irvine developed model relating fuel/air mixing and fuel composition to emissions Altering fuel distribution is a strategy to accommodate fuel composition changes * Results were used by 3 OEM's, 1 combustion technology developer and 1 user to help make decisions on how to handle the impact of LNG on combustor stability, and in the case of California installations, on how to respond to regulatory issues * As LNG is used in increasing quantities from more sources the variability of fuel gas should be more widespread, and manufacturers are likely to use this data in redesigning

375

Neutron Gas  

Science Journals Connector (OSTI)

We assume that the neutron-neutron potential is well-behaved and velocity-dependent. We can then apply perturbation theory to find the energy per particle of a neutron gas, in the range of Fermi wave numbers 0.5

J. S. Levinger and L. M. Simmons

1961-11-01T23:59:59.000Z

376

Concentration polarization in gas permeation  

SciTech Connect (OSTI)

It was verified that the selectivity of very thin (1 {mu}m thick) PDMS (polydimethylsiloxane) composite membranes for gaseous binary mixtures, like nitrogen and a hydrocarbon (HC), is as much as five times smaller than for the same mixture using a thick membrane (15 {mu}m-thick). This phenomenon is due to the build-up of the less permeable gas on the retentate side over the membrane and is known as the concentration polarization effect. In this paper we present a model for the gas concentration polarization effect based in the film theory and compare with the experimental results for the nitrogen-pentane separation using a PDMS membrane. 8 refs., 6 figs.

Mendes, A.M.M. [Univ. of Porto (Portugal); Alpers, A.; Peinemann, K.V.; Ohlrogge, K. [GKSS-Research Centre, Geesthacht (Germany)

1996-12-31T23:59:59.000Z

377

Natural Gas Hydrates  

Science Journals Connector (OSTI)

Natural Gas Hydrates ... Formation Characteristics of Synthesized Natural Gas Hydrates in Meso- and Macroporous Silica Gels ... Formation Characteristics of Synthesized Natural Gas Hydrates in Meso- and Macroporous Silica Gels ...

Willard I. Wilcox; D. B. Carson; D. L. Katz

1941-01-01T23:59:59.000Z

378

Gas Kick Mechanistic Model  

E-Print Network [OSTI]

Gas kicks occur during drilling when the formation pressure is greater than the wellbore pressure causing influx of gas into the wellbore. Uncontrolled gas kicks could result in blowout of the rig causing major financial loss and possible injury...

Zubairy, Raheel

2014-04-18T23:59:59.000Z

379

Program solves for gas well inflow performance  

SciTech Connect (OSTI)

A Windows-based program, GasIPR, can solve for the gas well inflow performance relationship (IPR). The program calculates gas producing rates at various pressures and is applicable for both turbulent and non-turbulent flow. It also has the following capabilities: computes PVT properties {gamma}{sub g}, P{sub c}, T{sub c}, heating value, Z, {mu}{sub g}, B{sub g}, and {rho}{sub g} from input gas composition data; calculates the Reynolds number (N{sub Re}) and shows the gas flow rates at the sandface at which the turbulence effect must be considered; helps the user to optimize the net perforation interval (h{sub p}) so that the turbulence effect can be minimized; and helps the user to evaluate the sensitivity of formation permeability on gas flow rate for a new play. IPR is a critical component in forecasting gas well deliverability. IPRs are used for sizing optimum tubing configurations and compressors, designing gravel packs, and solving gas well loading problems. IPR is the key reference for nodal analysis.

Engineer, R. [AERA Energy LLC, Bakersfield, CA (United States); Grillete, G. [Bechtel Petroleum Operations Inc., Tupman, CA (United States)

1997-10-20T23:59:59.000Z

380

Activated carbon fiber composite material and method of making  

DOE Patents [OSTI]

An activated carbon fiber composite for separation and purification, or catalytic processing of fluids is described. The activated composite comprises carbon fibers rigidly bonded to form an open, permeable, rigid monolith capable of being formed to near-net-shape. Separation and purification of gases are effected by means of a controlled pore structure that is developed in the carbon fibers contained in the composite. The open, permeable structure allows the free flow of gases through the monolith accompanied by high rates of adsorption. By modification of the pore structure and bulk density the composite can be rendered suitable for applications such as gas storage, catalysis, and liquid phase processing.

Burchell, Timothy D. (Oak Ridge, TN); Weaver, Charles E. (Knoxville, TN); Chilcoat, Bill R. (Knoxville, TN); Derbyshire, Frank (Lexington, KY); Jagtoyen, Marit (Lexington, KY)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Activated carbon fiber composite material and method of making  

DOE Patents [OSTI]

An activated carbon fiber composite for separation and purification, or catalytic processing of fluids is described. The activated composite comprises carbon fibers rigidly bonded to form an open, permeable, rigid monolith capable of being formed to near-net-shape. Separation and purification of gases are effected by means of a controlled pore structure that is developed in the carbon fibers contained in the composite. The open, permeable structure allows the free flow of gases through the monolith accompanied by high rates of adsorption. By modification of the pore structure and bulk density the composite can be rendered suitable for applications such as gas storage, catalysis, and liquid phase processing.

Burchell, Timothy D. (Oak Ridge, TN); Weaver, Charles E. (Knoxville, TN); Chilcoat, Bill R. (Knoxville, TN); Derbyshire, Frank (Lexington, KY); Jagtoyen, Marit (Lexington, KY)

2000-01-01T23:59:59.000Z

382

Method And System For Examining Biological Materials Using Low Power Cw Excitation Raman Spectroscopy.  

DOE Patents [OSTI]

A method and system for examining biological materials using low-power cw excitation Raman spectroscopy. A low-power continuous wave (cw) pump laser beam and a low-power cw Stokes (or anti-Stokes) probe laser beam simultaneously illuminate a biological material and traverse the biological material in collinearity. The pump beam, whose frequency is varied, is used to induce Raman emission from the biological material. The intensity of the probe beam, whose frequency is kept constant, is monitored as it leaves the biological material. When the difference between the pump and probe excitation frequencies is equal to a Raman vibrational mode frequency of the biological material, the weak probe signal becomes amplified by one or more orders of magnitude (typically up to about 10.sup.4 -10.sup.6) due to the Raman emission from the pump beam. In this manner, by monitoring the intensity of the probe beam emitted from the biological material as the pump beam is varied in frequency, one can obtain an excitation Raman spectrum for the biological material tested. The present invention may be applied to in the in vivo and/or in vitro diagnosis of diabetes, heart disease, hepatitis, cancers and other diseases by measuring the characteristic excitation Raman lines of blood glucose, cholesterol, serum glutamic oxalacetic transaminase (SGOT)/serum glutamic pyruvic transaminase (SGPT), tissues and other corresponding Raman-active body constituents, respectively.

Alfano, Robert R. (Bronx, NY); Wang, Wubao (Flushing, NY)

2003-05-06T23:59:59.000Z

383

Operating Regime for a Backward Raman Laser Amplifier in Preformed Plasma  

SciTech Connect (OSTI)

A critical issue in the generation of ultra-intense, ultra-short laser pulses by backward Raman scattering in plasma is the stability of the pumping pulse to premature backscatter from thermal fluctuations in the preformed plasma. Malkin et al. [V.M. Malkin, et al., Phys. Rev. Lett. 84 (6):1208-1211, 2000] demonstrated that density gradients may be used to detune the Raman resonance in such a way that backscatter of the pump from thermal noise can be stabilized while useful Raman amplification persists. Here plasma conditions for which the pump is stable to thermal Raman backscatter in a homogeneous plasma and the density gradients necessary to stabilize the pump for other plasma conditions are quantified. Other ancillary constraints on a Raman amplifier are also considered to determine a specific region in the Te-he plane where Raman amplification is feasible. By determining an operability region, the degree of uncertainty in density or temperature tolerable for an experimental Raman amplifier is thus also identified. The fluid code F3D, which includes the effects of thermal fluctuations, is used to verify these analytic estimates.

Daniel S. Clark; Nathaniel J. Fisch

2003-02-06T23:59:59.000Z

384

NITROGEN REMOVAL FROM NATURAL GAS  

SciTech Connect (OSTI)

The objective of this project was to develop a membrane process for the denitrogenation of natural gas. Large proven reserves in the Lower-48 states cannot be produced because of the presence of nitrogen. To exploit these reserves, cost-effective, simple technology able to reduce the nitrogen content of the gas to 4-5% is required. Technology applicable to treatment of small gas streams (below 10 MMscfd) is particularly needed. In this project membranes that selectively permeate methane and reject nitrogen in the gas were developed. Preliminary calculations show that a membrane with a methane/nitrogen selectivity of 3 to 5 is required to make the process economically viable. A number of polymer materials likely to have the required selectivities were evaluated as composite membranes. Polyacetylenes such as poly(1-trimethylsilyl-1-propyne) [PTMSP] and poly(4-methyl-2-pentyne) [PMP] had high selectivities and fluxes, but membranes prepared from these polymers were not stable, showing decreasing flux and selectivity during tests lasting only a few hours. Parel, a poly(propylene oxide allyl glycidyl ether) had a selectivity of 3 at ambient temperatures and 4 or more at temperatures of {minus}20 C. However, Parel is no longer commercially available, and we were unable to find an equivalent material in the time available. Therefore, most of our experimental work focused on silicone rubber membranes, which have a selectivity of 2.5 at ambient temperatures, increasing to 3-4 at low temperatures. Silicone rubber composite membranes were evaluated in bench-scale module tests and with commercial-scale, 4-inch-diameter modules in a small pilot plant. Over six days of continuous operation at a feed gas temperature of {minus}5 to {minus}10 C, the membrane maintained a methane/nitrogen selectivity of about 3.3. Based on the pilot plant performance data, an analysis of the economic potential of the process was prepared. We conclude that a stand-alone membrane process is the lowest-cost technology for small gas streams containing less than 10% nitrogen. The membrane process can recover more than 60-70% of the hydrocarbon content of the gas at a cost of $0.60-0.70/Mscfd. The capital cost of the process is about $100-200/Mscf. A number of small operators appear to be ready to use the technology if these costs can be demonstrated in the field. A second, and perhaps better, application of the technology is to combine the membrane process with a cryogenic process to treat large gas streams containing 10-20% nitrogen. The combination process achieves significant synergies. The membrane process performs a bulk separation of the gas, after which the cryogenic process treats the membrane residue (nitrogen-enriched) gas to recover more methane. Overall, hydrocarbon recoveries are greater than 95%. The capital cost of the combination process is lower than that of either process used alone and the processing costs are in the range $0.30-0.40/Mscf. This operating cost would be attractive to many gas producers. MTR is collaborating with a producer of cryogenic systems to further develop the combination process. A number of innovations in membrane process designs were made during the project; four U.S. patents covering various aspects of the technology were filed and issued.

K.A. Lokhandwala; M.B. Ringer; T.T. Su; Z. He; I. Pinnau; J.G. Wijmans; A. Morisato; K. Amo; A. DaCosta; R.W. Baker; R. Olsen; H. Hassani; T. Rathkamp

1999-12-31T23:59:59.000Z

385

Historical Natural Gas Annual  

U.S. Energy Information Administration (EIA) Indexed Site

8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

386

Historical Natural Gas Annual  

U.S. Energy Information Administration (EIA) Indexed Site

6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

387

Historical Natural Gas Annual  

U.S. Energy Information Administration (EIA) Indexed Site

7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

388

Future of Natural Gas  

Office of Environmental Management (EM)

technology is improving - Producers are drilling in liquids rich gas and crude oil shale plays due to lower returns on dry gas production - Improved well completion time...

389

Natural Gas Industrial Price  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Power Price Gross Withdrawals Gross Withdrawals From Gas Wells Gross Withdrawals From Oil Wells Gross Withdrawals From Shale Gas Wells Gross Withdrawals From Coalbed Wells...

390

Method And System For Examining Biological Materials Using Low Power Cw Excitation Raman Spectroscopy.  

DOE Patents [OSTI]

A method and system for examining biological materials using low-power cw excitation Raman spectroscopy. In accordance with the teachings of the invention, a low-power continuous wave (cw) pump laser beam and a low-power cw Stokes (or anti-Stokes) probe laser beam simultaneously illuminate a biological material and traverse the biological material in collinearity. The pump beam, whose frequency is varied, is used to induce Raman emission from the biological material. The intensity of the probe beam, whose frequency is kept constant, is monitored as it leaves the biological material. When the difference between the pump and probe excitation frequencies is equal to a Raman vibrational mode frequency of the biological material, the weak probe signal becomes amplified by one or more orders of magnitude (typically up to about 10.sup.4 -10.sup.6) due to the Raman emission from the pump beam. In this manner, by monitoring the intensity of the probe beam emitted from the biological material as the pump beam is varied in frequency, one can obtain an excitation Raman spectrum for the biological material tested. The present invention may be applied to in the in vivo and/or in vitro diagnosis of diabetes, heart disease, hepatitis, cancers and other diseases by measuring the characteristic excitation Raman lines of blood glucose, cholesterol, serum glutamic oxalacetic transaminase (SGOT)/serum glutamic pyruvic tansaminase (SGPT), tissues and other corresponding Raman-active body constituents, respectively. For example, it may also be used to diagnose diseases associated with the concentration of Raman-active constituents in urine, lymph and saliva It may be used to identify cancer in the breast, cervix, uterus, ovaries and the like by measuring the fingerprint excitation Raman spectra of these tissues. It may also be used to reveal the growing of tumors or cancers by measuring the levels of nitric oxide in tissue.

Alfano, Robert R. (Bronx, NY); Wang, Wubao (Flushing, NY)

2000-11-21T23:59:59.000Z

391

Conductive ceramic composition and method of preparation  

DOE Patents [OSTI]

A ceramic anode composition is formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The anode is prepared as a non-stoichiometric crystalline structure by reaction and conditioning in a hydrogen gas cover containing minor proportions of carbon dioxide and water vapor. The structure exhibits a single phase and substantially enhanced electrical conductivity over that of the corresponding stoichiometric structure. Unexpectedly, such oxides and oxygenates are found to be stable in the reducing anode fuel gas of a molten carbonate fuel cell. 4 figures.

Smith, J.L.; Kucera, E.H.

1991-04-16T23:59:59.000Z

392

A Network Model for The Genesis and Migration of Gas Phase  

E-Print Network [OSTI]

1 A Network Model for The Genesis and Migration of Gas Phase Koukung Alex Chang and W. Brent, of a compositional fluid consisting of water with a dissolved hydrocarbon gas. The model captures both single phase 99% of the (effectively) stored CO2 resides in the liquid phase. Key Words: network model, gas

New York at Stoney Brook, State University of

393

Q-branch Raman scattering and modern kinetic thoery  

SciTech Connect (OSTI)

The program is an extension of previous APL work whose general aim was to calculate line shapes of nearly resonant isolated line transitions with solutions of a popular quantum kinetic equation-the Waldmann-Snider equation-using well known advanced solution techniques developed for the classical Boltzmann equation. The advanced techniques explored have been a BGK type approximation, which is termed the Generalized Hess Method (GHM), and conversion of the collision operator to a block diagonal matrix of symmetric collision kernels which then can be approximated by discrete ordinate methods. The latter method, which is termed the Collision Kernel method (CC), is capable of the highest accuracy and has been used quite successfully for Q-branch Raman scattering. The GHM method, not quite as accurate, is applicable over a wider range of pressures and has proven quite useful.

Monchick, L. [The Johns Hopkins Univ., Laurel, MD (United States)

1993-12-01T23:59:59.000Z

394

Detection of volatile organic compounds using surface enhanced Raman scattering  

SciTech Connect (OSTI)

The authors present the detection of volatile organic compounds directly in their vapor phase by surface-enhanced Raman scattering (SERS) substrates based on lithographically-defined two-dimensional rectangular array of nanopillars. The type of nanopillars is known as the tapered pillars. For the tapered pillars, SERS enhancement arises from the nanofocusing effect due to the sharp tip on top. SERS experiments were carried out on these substrates using various concentrations of toluene vapor. The results show that SERS signal from a toluene vapor concentration of ppm level can be achieved, and the toluene vapor can be detected within minutes of exposing the SERS substrate to the vapor. A simple adsorption model is developed which gives results matching the experimental data. The results also show promising potential for the use of these substrates in environmental monitoring of gases and vapors.

Chang, A S; Maiti, A; Ileri, N; Bora, M; Larson, C C; Britten, J A; Bond, T C

2012-03-22T23:59:59.000Z

395

Time?resolved anisotropic coherent anti?Stokes Raman scattering: A new probe of reorientational dynamics  

E-Print Network [OSTI]

anti-Stokes Raman scattering (TRA CARS) and spontaneous Raman (TRA Raman) as probes of rota­ tional motion. II. THEORY When a sample system is illuminated by three laser beams at frequencies (Uo, (UI, and (U2, the incident fields induce a third... is described by a nonlinear sus­ ceptibility tensor containing three independent compo­ nents in the L=O subspace and six independent compo­ nents in the L = 2 subspace. First we write the molecular susceptibility MU11(0) iIi terms of the direct product...

Wan, Chaozhi; Johnson, Carey K.

1993-09-01T23:59:59.000Z

396

Surface enhanced Raman scattering of aged graphene: Effects of annealing in vacuum  

SciTech Connect (OSTI)

In this paper, we report a simple method to recover the surface enhanced Raman scattering activity of aged graphene. The Raman signals of Rhodamine molecules absorbed on aged graphene are dramatically increased after vacuum annealing and comparable to those on fresh graphene. Atomic force microscopy measurements indicate that residues on aged graphene surface can efficiently be removed by vacuum annealing, which makes target molecule closely contact with graphene. We also find that the hole doping in graphene will facilitate charge transfer between graphene and molecule. These results confirm the strong Raman enhancement of target molecule absorbed on graphene is due to the charge transfer mechanism.

Wang Yingying; Li Aizhi; Qu Shiliang [Department of Optoelectronic Science, Harbin Institute of Technology at Weihai, Weihai 264209 (China); Ni Zhenhua; Zafar, Zainab; Qiu Teng [Department of Physics, Southeast University, Nanjing 211189 (China); Zhang Yan; Ni Zhonghua [Jiangsu Key Laboratory for Design and Fabrication of Micro-Nano Biomedical Instruments, School of Mechanical Engineering, Southeast University, Nanjing 211189 (China); Yu Ting; Shen Zexiang [Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 (Singapore)

2011-12-05T23:59:59.000Z

397

Continuous-wave solid-state two-Stokes Raman laser  

SciTech Connect (OSTI)

We report an experimental study of the first cw solid-state Raman laser operating simultaneously at the frequencies of the first and second Stokes components. Simultaneous generation is ensured by a cavity with an enhanced finesse at both Stokes frequencies. The threshold pump powers for the first (3.4 W) and second (3.67 W) Stokes components suggest that the second Stokes generation follows a cascade mechanism. We demonstrate for the first time Raman conversion with intensity stability exceeding the pump radiation stability and show that this approach may find application in Raman spectroscopy. (special issue devoted to the 80th birthday of S.A. Akhmanov)

Grabchikov, A S; Lisinetskii, V A; Orlovich, V A [B.I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk (Belarus); Schmitt, M; Schluecker, S; Kuestner, B; Kiefer, W [Institut fuer Physikalische Chemie, Universitat Wuerzburg, Wuerzburg (Germany)

2009-07-31T23:59:59.000Z

398

Third harmonic stimulated Raman backscattering of laser in a magnetized plasma  

SciTech Connect (OSTI)

This article studies the nonlinear Raman shifted third harmonic backscattering of an intense extraordinary laser wave through a homogenous transversely magnetized cold plasma. Due to the relativistic nonlinearity, the plasma dynamic is modified in the presence of transversely magnetic field, and this can generate the third harmonic scattered wave and an electrostatic upper hybrid wave via the Raman scattering process. Using the nonlinear wave equation, the mechanism of nonlinear third harmonic Raman scattering is discussed in detail to obtain the maximum growth rate of instability in the mildly relativistic regime. The growth rate decreases as the static magnetic field increases. It also increases with the pump wave amplitude.

Paknezhad, Alireza [Physics Department, Shabestar Branch, Islamic Azad University, Shabestar (Iran, Islamic Republic of)] [Physics Department, Shabestar Branch, Islamic Azad University, Shabestar (Iran, Islamic Republic of); Dorranian, Davoud [Laser Lab., Plasma Physics Research Center, Science and Research Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of)] [Laser Lab., Plasma Physics Research Center, Science and Research Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of)

2013-09-15T23:59:59.000Z

399

Definition: Gas Sampling | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Gas Sampling Jump to: navigation, search Dictionary.png Gas Sampling Gas sampling is done to characterize the chemical, thermal, and hydrological properties of a surface or subsurface hydrothermal system. Various methods are applied to obtain samples used for determination of the composition of gases present in soils or hydrothermal discharges. The flux of volatile gases emitted from a hydrothermal system can also be determined by measuring the flow of gases at specific locations and comparing it to average background emissions. Anomalously high gas flux can provide an indication of hydrothermal activity at depth that is otherwise not apparent. Ret LikeLike UnlikeLike You like this.Sign Up to see what your friends like.

400

NATURAL GAS RESOURCES IN DEEP SEDIMENTARY BASINS  

SciTech Connect (OSTI)

From a geological perspective, deep natural gas resources are generally defined as resources occurring in reservoirs at or below 15,000 feet, whereas ultra-deep gas occurs below 25,000 feet. From an operational point of view, ''deep'' is often thought of in a relative sense based on the geologic and engineering knowledge of gas (and oil) resources in a particular area. Deep gas can be found in either conventionally-trapped or unconventional basin-center accumulations that are essentially large single fields having spatial dimensions often exceeding those of conventional fields. Exploration for deep conventional and unconventional basin-center natural gas resources deserves special attention because these resources are widespread and occur in diverse geologic environments. In 1995, the U.S. Geological Survey estimated that 939 TCF of technically recoverable natural gas remained to be discovered or was part of reserve appreciation from known fields in the onshore areas and State waters of the United. Of this USGS resource, nearly 114 trillion cubic feet (Tcf) of technically-recoverable gas remains to be discovered from deep sedimentary basins. Worldwide estimates of deep gas are also high. The U.S. Geological Survey World Petroleum Assessment 2000 Project recently estimated a world mean undiscovered conventional gas resource outside the U.S. of 844 Tcf below 4.5 km (about 15,000 feet). Less is known about the origins of deep gas than about the origins of gas at shallower depths because fewer wells have been drilled into the deeper portions of many basins. Some of the many factors contributing to the origin of deep gas include the thermal stability of methane, the role of water and non-hydrocarbon gases in natural gas generation, porosity loss with increasing thermal maturity, the kinetics of deep gas generation, thermal cracking of oil to gas, and source rock potential based on thermal maturity and kerogen type. Recent experimental simulations using laboratory pyrolysis methods have provided much information on the origins of deep gas. Technologic problems are one of the greatest challenges to deep drilling. Problems associated with overcoming hostile drilling environments (e.g. high temperatures and pressures, and acid gases such as CO{sub 2} and H{sub 2}S) for successful well completion, present the greatest obstacles to drilling, evaluating, and developing deep gas fields. Even though the overall success ratio for deep wells is about 50 percent, a lack of geological and geophysical information such as reservoir quality, trap development, and gas composition continues to be a major barrier to deep gas exploration. Results of recent finding-cost studies by depth interval for the onshore U.S. indicate that, on average, deep wells cost nearly 10 times more to drill than shallow wells, but well costs and gas recoveries vary widely among different gas plays in different basins. Based on an analysis of natural gas assessments, many topical areas hold significant promise for future exploration and development. One such area involves re-evaluating and assessing hypothetical unconventional basin-center gas plays. Poorly-understood basin-center gas plays could contain significant deep undiscovered technically-recoverable gas resources.

Thaddeus S. Dyman; Troy Cook; Robert A. Crovelli; Allison A. Henry; Timothy C. Hester; Ronald C. Johnson; Michael D. Lewan; Vito F. Nuccio; James W. Schmoker; Dennis B. Riggin; Christopher J. Schenk

2002-02-05T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Composition, apparatus, and process, for sorption of gaseous compounds of group II-VII elements  

DOE Patents [OSTI]

Scavenger compositions are disclosed, which have utility for effecting the sorptive removal of hazardous gases containing Group II-VII elements of the Periodic Table, such as are widely encountered in the manufacture of semiconducting materials and semiconductor devices. Gas sorption processes including the contacting of Group II-VII gaseous compounds with such scavenger compositions are likewise disclosed, together with critical space velocity contacting conditions pertaining thereto. Further described are gas contacting apparatus, including mesh structures which may be deployed in gas contacting vessels containing such scavenger compositions, to prevent solids from being introduced to or discharged from the contacting vessel in the gas stream undergoing treatment. A reticulate heat transfer structure also is disclosed, for dampening localized exothermic reaction fronts when gas mixtures comprising Group II-VII constituents are contacted with the scavenger compositions in bulk sorption contacting vessels according to the invention.

Tom, Glenn M. (New Milford, CT); McManus, James V. (Danbury, CT); Luxon, Bruce A. (Stamford, CT)

1991-08-06T23:59:59.000Z

402

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE  

SciTech Connect (OSTI)

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

2004-08-01T23:59:59.000Z

403

Composite production riser assessment  

E-Print Network [OSTI]

The performance of a deep water composite production riser from a system perspective is presented, and its advantages are articulated through comparisons with a typical steel riser under identical service conditions. The composite riser joints...

Kim, Won Ki

2007-09-17T23:59:59.000Z

404

Heteroporphyrin nanotubes and composites  

DOE Patents [OSTI]

Heteroporphyrin nanotubes, metal nanostructures, and metal/porphyrin-nanotube composite nanostructures formed using the nanotubes as photocatalysts and structural templates, and the methods for forming the nanotubes and composites.

Shelnutt, John A. (Tijeras, NM); Medforth, Craig J. (Winters, CA); Wang, Zhongchun (Albuquerque, NM)

2007-05-29T23:59:59.000Z

405

Flexible Composite Radiation Detector  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Flexible Composite Radiation Detector Flexible Composite Radiation Detector Flexible Composite Radiation Detector A flexible composite scintillator was prepared by mixing fast, bright, dense rare-earth doped powdered oxyorthosilicate (such as LSO:Ce, LSO:Sm, and GSO:Ce) scintillator with a polymer binder. Available for thumbnail of Feynman Center (505) 665-9090 Email Flexible Composite Radiation Detector A flexible composite scintillator was prepared by mixing fast, bright, dense rare-earth doped powdered oxyorthosilicate (such as LSO:Ce, LSO:Sm, and GSO:Ce) scintillator with a polymer binder. The binder is transparent to the scintillator emission. The composite is seamless and can be made large and in a wide variety of shapes. Importantly, the composite can be tailored to emit light in a spectral region that matches the optimum

406

Noble gas magnetic resonator  

DOE Patents [OSTI]

Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

2014-04-15T23:59:59.000Z

407

OIL & GAS INSTITUTE Introduction  

E-Print Network [OSTI]

OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

Mottram, Nigel

408

Composite bipolar plate for electrochemical cells  

DOE Patents [OSTI]

A bipolar separator plate for fuel cells consists of a molded mixture of a vinyl ester resin and graphite powder. The plate serves as a current collector and may contain fluid flow fields for the distribution of reactant gases. The material is inexpensive, electrically conductive, lightweight, strong, corrosion resistant, easily mass produced, and relatively impermeable to hydrogen gas. The addition of certain fiber reinforcements and other additives can improve the properties of the composite material without significantly increasing its overall cost.

Wilson, Mahlon S. (Los Alamos, NM); Busick, Deanna N. (Los Alamos, NM)

2001-01-01T23:59:59.000Z

409

Vibrational Damping of Composite Materials  

E-Print Network [OSTI]

on the Damping of Composite Laminates”, SPIE Proceedings onpublication to Journal of Composite Materials Biggerstaff,submitted for publication to Composites, Part A Biggerstaff,

Biggerstaff, Janet M.

2006-01-01T23:59:59.000Z

410

Picosecond transient coherent anti-Stokes Raman spectroscopy of Rhodamine 560 in ethanol  

Science Journals Connector (OSTI)

Results of picosecond Raman scattering of the excited state of Rhodamine 560 are reported. Both two-and three-color transient spectroscopy are accomplished with a time resolution of...

Payne, Stephen A; Hochstrasser, R M

1986-01-01T23:59:59.000Z

411

Vlasov simulations of kinetic enhancement of Raman backscatter in laser fusion plasmas  

E-Print Network [OSTI]

Stimulated Raman scattering (SRS) is studied in plasmas relevant to inertial confinement fusion (ICF). The Eulerian Vlasov-Maxwell code ELVIS was developed and run for this purpose. Plasma waves are heavily Landau damped ...

Strozzi, D. J. (David J.)

2006-01-01T23:59:59.000Z

412

Solar Energy Materials & Solar Cells 71 (2002) 511522 In situ Raman spectroscopy of the  

E-Print Network [OSTI]

Solar Energy Materials & Solar Cells 71 (2002) 511­522 In situ Raman spectroscopy. In this situation, a low energy excitation (e.g. visible light) is needed to excite an electron to a neighboring

Nabben, Reinhard

413

Enhancement of Raman Scattering for Silver Nanoparticles Located on Electrolessly Roughened Silicon  

Science Journals Connector (OSTI)

To study the effect of roughness of a supporting substrate to Raman enhancement, silver nanoparticles (AgNPs) were prepared on Si with different degrees of roughness. To roughen the...

Liou, Yen-Chen Maggie; Chen, Jiann-Yeu; Yang, Jyisy

2014-01-01T23:59:59.000Z

414

A study of heavy oil fractions by Fourier-transform near-infrared Raman spectroscopy  

Science Journals Connector (OSTI)

Oil fractions with a boiling-point step size of 20°C (300 to 560°C) for six different crude oils of Western Siberia have been studied by Fourier-transform Raman and Fourier-transform IR spectroscopy. Weak band...

A. Kh. Kuptsov; T. V. Arbuzova

2011-05-01T23:59:59.000Z

415

Isotope effect of the phonons mean free path in graphene by micro-Raman measurement  

Science Journals Connector (OSTI)

The isotope labeled graphene was synthesized in the concentration of 13C carbon atom in 1%, 25%, 50%, 75% and 99%. The isotope effect on the phonon behavior in graphene was investigated based on the micro-Raman a...

CanKun Zhang; QiongYu Li; Bo Tian…

2014-10-01T23:59:59.000Z

416

Raman excitation profile of the G band in single-chirality carbon nanotubes  

E-Print Network [OSTI]

We present in this work measurements of the Raman excitation profile of the high-energy phonons (G band) in single-chirality (n,m) semiconducting single-wall carbon nanotubes using more than 70 laser excitation energies, ...

Moura, L. G.

417

Resonance Raman spectroscopy in Si and C ion-implanted double-wall carbon nanotubes  

E-Print Network [OSTI]

The effect of 170 keV Si and 100 keV C ion bombardment on the structure and properties of highly pure, double-wall carbon nanotubes has been investigated using resonance Raman spectroscopy. The implantations were performed ...

Dresselhaus, Mildred

418

Spectral Collection of Polyethylene Pellets at nearly Cryogenic Temperature to Improve Selectivity of Raman Measurement  

SciTech Connect (OSTI)

Raman spectroscopy has been extensively used for analysis of diverse polymer samples. Normally, Raman spectral collection of samples is routinely performed at room temperature for convenience. However, the feasibility of improving spectral selectivity and the resulting quantitative accuracy, when samples are measured at nearly cryogenic temperature, has not been investigated. For this purpose, we attempted to measure the density of polyethylene (PE) pellets at cryogenic temperatures and the resulting accuracies were compared with that from room temperature measurement. Initially, each of 25 PE sample was allowed to cool down to cryogenic temperature and the corresponding Raman spectra were continuously collected while the temperature of sample increased. When the temperature of sample was at cryogenic temperature, the resulting band widths were narrower compared to those at room temperature, thereby improving the accuracy of density measurement. In overall, the proposed Raman scheme is simple and efficient; therefore, it could be further applied for analysis of other polymers.

Kim, Saetbyeol; Lee, Sanguk; Hwang, Jinyoung; Chung, Hoeil [Analytical Spectroscopy Lab, Department of Chemistry, Hanyang University, Seoul, 133-791 (Korea, Republic of)

2010-08-06T23:59:59.000Z

419

Infrared and Raman Spectra of a Sulfur-resistant Methanation Catalyst  

Science Journals Connector (OSTI)

The infrared and Raman spectra of a sulfur-resistant NiO/Cr2O3/MgSiO3 methanation catalyst are presented and compared to the spectra of the catalyst...

Stencel, J M; Bradley, E B; Brown, Fred R

1980-01-01T23:59:59.000Z

420

Surface-enhanced Raman spectroscopy at single-molecule scale and its implications in biology  

Science Journals Connector (OSTI)

...applications constituting areas in medicine, biology, environment and agriculture...surface-enhanced Raman spectroscopy|nanotechnology|hot spot|biological sciences...environmental science, basic sciences and medicine. The sensitivity of SM-SERS...

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

The use of Surface Enhanced Raman Spectroscopy (SERS) for biomedical applications  

E-Print Network [OSTI]

Recent advances in nanotechnology and the biotechnology revolution have created an immense opportunity for the use of noble metal nanoparticles as Surface Enhanced Raman Spectroscopy (SERS) substrates for biological sensing and diagnostics...

Chowdhury, Mustafa Habib

2007-04-25T23:59:59.000Z

422

Raman spectroscopy study of heat-treated and boron-doped double wall carbon nanotubes  

E-Print Network [OSTI]

We performed Raman spectroscopy experiments on undoped and boron-doped double walled carbon nanotubes (DWNTs) that exhibit the “coalescence inducing mode” as these DWNTs are heat treated to temperatures between 1200 °C ...

Villalpando Paez, Federico

423

Zone folding effect in Raman G-band intensity of twisted bilayer graphene  

E-Print Network [OSTI]

The G-band Raman intensity is calculated for twisted bilayer graphene as a function of laser excitation energy based on the extended tight binding method. Here we explicitly consider the electron-photon and electron-phonon ...

Dresselhaus, Mildred

424

Mapping residual stress fields from Vickers hardness indents using Raman microprobe spectroscopy  

SciTech Connect (OSTI)

Micro-Raman spectroscopy is used to map the residual stress fields in the vicinity of Vickers hardness indents. Both 514.5 and 488.0 nm, light is used to excite the effect and the resulting shifted and broadened Raman peaks are analyzed using computer deconvolution. Half-wave plates are used to vary the orientation of the incident later light`s polarization state with respect to crystal orientation. The Raman scattered light is then analyzed for polarization dependences which are indicative of the various components of the Raman scattering tensor. Such studies can yield valuable information about the orientation of stress components in a well known stress field. The results can then be applied to the determination of stress components in machined semiconductor materials.

Sparks, R.G.; Enloe, W.S.; Paesler, M.A.

1988-12-01T23:59:59.000Z

425

Multivariate analysis of Raman spectra for the identification of sulfates: Implications for ExoMars  

Science Journals Connector (OSTI)

...quantitative| Introduction Laser Raman spectroscopy...the quality of biodiesel fuels (Ghesti et al...Natural Sciences and Engineering Research Council...quantification of biodiesel in a progressive...methods. Energy and Fuels, 21, 2475-2480...

Guillermo Lopez-Reyes; Pablo Sobron; Catherine Lefebvre; Fernando Rull

426

Coherent anti-Stokes Raman scattering microscopy for quantitative characterization of mixing and flow in microfluidics  

Science Journals Connector (OSTI)

We present an optical, noninvasive and label-free approach to characterize flow profiles in microfluidic devices. Coherent anti-Stokes Raman scattering signals were used to map the...

Schafer, Dawn; Müller, Michiel; Bonn, Mischa; Marr, David W M; van Maarseveen, Jan; Squier, Jeff

2009-01-01T23:59:59.000Z

427

Raman spectra of size-selected silicon clusters and comparison with calculated structures  

Science Journals Connector (OSTI)

... ) and the agreement with experiment is much poorer. Other possible isomers with C3D and C2u symmetry6 8J2 are much higher in energy and also have many more Raman allowed lines ...

E. C. Honea; A. Ogura; C. A. Murray; Krishnan Raghavachari; W. O. Sprenger; M. F. Jarrold; W. L. Brown

1993-11-04T23:59:59.000Z

428

UV Resonance Raman Spectroscopy Using a New cw Laser Source: Convenience and Experimental Simplicity  

E-Print Network [OSTI]

into the spectrometer. We dem- onstrate the ability of this laser to excite Raman spectra of solid samples such as coal-liquid- alytical applications. Examples include studies of PAHs in coal-derived liquids4-~and in petroleum

Asher, Sanford A.

429

An infrared and Raman spectroscopy study of the corrosion products on carbon steel and weathering steel  

Science Journals Connector (OSTI)

Infrared and Raman spectroscopy are two analytical tools which have recently been applied to the study of corrosion products formed on metal surfaces. The two techniques are complementary and giv...

P. Fabis; C. Brown; T. Rockett; R. Heidersbach

1981-12-01T23:59:59.000Z

430

Stimulated Raman scattering from individual water and ethanol droplets at morphology-dependent resonances  

Science Journals Connector (OSTI)

Stimulated Raman scattering (SRS) from an individual liquid droplet (?30-?m radius) has been observed for H2O, D2O, and ethanol. The occurrence of a series of...

Snow, Judith B; Qian, Shi-Xiong; Chang, Richard K

1985-01-01T23:59:59.000Z

431

Fluid Phase Equilibria of Ethanol and Carbon Dioxide Mixtures with Concentration Measurements by Raman Spectroscopy  

Science Journals Connector (OSTI)

Phase equilibria data for the system ethanol/carbon dioxide for T = 313.15 K and pressures up to p = 7.9 MPa are presented. The measurements were made by Raman...

Stratmann, A; Schweiger, G

2002-01-01T23:59:59.000Z

432

Potential and limits of Raman spectroscopy for carotenoid detection in microorganisms: implications for astrobiology  

Science Journals Connector (OSTI)

...for a few cases where the current Raman spectroscopic approach does not allow discriminating structurally very similar carotenoids...S Liaaen-Jensen, and H Pfander (eds). 2004 Carotenoids handbook. Basel, Switzerland: Birkhauser. 5 Frank, HA , V Chynwat...

2014-01-01T23:59:59.000Z

433

Resonant stimulation of Raman scattering from single-crystal thiophene/phenylene co-oligomers  

SciTech Connect (OSTI)

Amplified Raman scattering was observed from single crystals of thiophene/phenylene co-oligomers (TPCOs). Under ns-pulsed excitation, the TPCO crystals exhibited amplified spontaneous emission (ASE) at resonant absorption wavelengths. With increasing excitation wavelength to the 0-0 absorption edge, the stimulated resonant Raman peaks appeared both in the 0-1 and 0-2 ASE band regions. When the excitation wavelength coincided with the 0-1 ASE band energy, the Raman peaks selectively appeared in the 0-2 ASE band. Such unusual enhancement of the 0-2 Raman scattering was ascribed to resonant stimulation via vibronic coupling with electronic transitions in the uniaxially oriented TPCO molecules.

Yanagi, Hisao, E-mail: yanagi@ms.naist.jp; Marutani, Yusuke; Matsuoka, Naoki; Hiramatsu, Toru; Ishizumi, Atsushi [Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma, Nara 630-0192 (Japan)] [Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma, Nara 630-0192 (Japan); Sasaki, Fumio [Electronics and Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan)] [Electronics and Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan); Hotta, Shu [Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585 (Japan)] [Department of Macromolecular Science and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585 (Japan)

2013-12-09T23:59:59.000Z

434

Composition and temperature-induced effects on the phonon spectra of narrow-band-gap Hg1-xCdxTe  

Science Journals Connector (OSTI)

Compositional and temperature-dependent Raman and infrared spectroscopies on the narrow-band-gap II-VI alloy, Hg1-xCdxTe (0?x?0.29), are reported in this paper. Raman measurements over this composition range confirm the two-mode behavior of the optical phonons in the alloy, with the frequency positions exhibiting a monotonic change with the alloy composition x. A resonant enhancement of the HgTe-like forbidden longitudinal-optic mode is observed near the E1 band gap of the alloy. Alloy induced perturbations on the electronic states lead to a smearing and a weakening of the resonance with increasing alloy composition. The optical phonons in this small band-gap alloy exhibit anomalous frequency shifts as a function of temperature vis-à-vis normal wide-band-gap semiconductors. This anomaly is attributed to the strong electron-phonon interaction in narrow-band-gap systems, which overshadows the dominant anharmonic (phonon-phonon) interaction in usual semiconductors. A detailed compositional dependent second-order Raman spectra is also reported.

Shyama Rath, K. P. Jain, S. C. Abbi, C. Julien, and M. Balkanski

1995-12-15T23:59:59.000Z

435

Raman-Active Lattice Vibrations of the Commensurate Superlattic in 2H-TaSe2  

Science Journals Connector (OSTI)

Raman spectra have been obtained on 2H-TaSe2 at room temperature and in the commensurate charge-density-wave, superlattice state. At low temperatures six new low frequency modes are seen having symmetries consistent only with a symmetric, three-charge-density wave. A microscopic model of the lattice dynamics of this state is fitted to the four strongest new Raman lines. These are assigned to amplitude and phase modes of the charge-density wave.

John A. Holy, Miles V. Klein, W. L. McMillan, and S. F. Meyer

1976-10-25T23:59:59.000Z

436

Raman spectroscopy for characterization of annealing of ion-implanted InP  

SciTech Connect (OSTI)

Raman spectroscopy has been used as a noncontacting, nondestructive tool to evaluate the properties of Si/sup +/- and Be/sup +/- implanted InP samples annealed at temperatures ranging from 600 to 750C using phosphosilicate glass (PSG) as the encapsulant. Carrier activation, carrier mobility and recovery of damage as a function of anneal temperature obtained from analysis of Raman data agree very well with independent electrical measurements.

Myers, D.R.; Gourley, P.L.; Vaidyanathan, K.V.; Dunlap, H.L.

1982-01-01T23:59:59.000Z

437

X-ray Raman compression via two-stream instability in dense plasmas  

E-Print Network [OSTI]

A Raman compression scheme suitable for x-rays, where the Langmuir wave is created by an intense beam rather than the pondermotive potential between the seed and pump pulses, is proposed. The required intensity of the seed and pump pulses enabling the compression could be mitigated by more than a factor of 100, compared to conventionally available other Raman compression schemes. The relevant wavelength of x-rays ranges from 1 to 10 nm.

S. Son; Sung Joon Moon

2011-03-27T23:59:59.000Z

438

Summary of raman cone penetrometer probe waste tank radiation and chemical environment test  

SciTech Connect (OSTI)

This report summarizes the results of testing Raman sapphire windows that were braze mounted into a mockup Raman probe head and stainless steel coupons in a simulated tank waste environment. The simulated environment was created by exposing sapphire window components, immersed in a tank simulant, in a gamma pit. This work was completed for the U.S. Department of Energy (DOE) Office of Environmental Management (EM-50) for Technical Task Proposal RL4-6-WT-21.

Reich, F.R.

1996-09-27T23:59:59.000Z

439

Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy  

SciTech Connect (OSTI)

Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2009-03-15T23:59:59.000Z

440

Application of composite repair for pipeline anomalies  

SciTech Connect (OSTI)

The cost of maintaining the structural integrity of the 650,000 kilometer high-pressure gas gathering and transmission pipeline network is a significant part of the operating budget of the US pipeline industry. To help in controlling thee costs, the Gas Research institute (GRI) has supported research resulting in the development of Clock Spring{reg_sign}, a low-cost fiberglass composite alternative to conventional steel sleeves for transmission line pipe reinforcement and repair. Investigation and development of engineering guidelines have been completed. Field validation of laboratory research on application of Clock Spring as a repair for corrosion and mechanical damage defects is in progress. This paper presents an overview of composite repair technology for pipeline corrosion and mechanical damage defects. It summarizes the results and conclusions of modeling and experiments on reinforcement and repair of both corrosion and mechanical damage (i.e., dent and gouge) pipeline defects. These investigations provide quantitative results on the operating envelope of composite reinforcements and installation requirements that ensure sound and reliable repair of pipeline defects. The paper further summarizes the work to date on field installation in verification of composite repair performance.

Stephens, D.R. [Battelle, Columbus, OH (United States); Lindholm, U.S. [Southwest Research Inst., San Antonio, TX (United States); Hill, V.L. [Gas Research Inst., Chicago, IL (United States); Block, N. [Clock Spring Co., Houston, TX (United States)

1996-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Natural Gas: Dry Wells Yield Gas  

Science Journals Connector (OSTI)

... THE Gas Council and Home Oil of Canada have announced plans for developing two ... Council and Home Oil of Canada have announced plans for developing two natural ...

1969-04-26T23:59:59.000Z

442

A critical review of methods used in the estimation of natural gas reserves: Natural gas reserves in the state of Texas. Some educational prerequisites in the field of petroleum economics and evaluation.  

E-Print Network [OSTI]

-Associated Gas Reserves Volumetr ic Method Discussion of the Factors in tne Volumetri. Formula The Decline Curve Method 7 7 12 Ie Methods of Estimating Associated Gas Reserves Methods of Estimatmg Dissolved Gas Reserves Water Drive Constant Voluxne... Bibliography 58 TABLE of ILLUSTRATIONS ~Pa e A CRITICAI REVIEW OF METHODS USED IN THE ESTIMATION OF NATURAL GAS RESERVES Curves Curve No Curves Showing Change in the Compressi- bility Factor with Depth and Composition of the Wet Gas. Z4-A Curve No...

Crichton, John Alston

2012-06-07T23:59:59.000Z

443

Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions  

SciTech Connect (OSTI)

Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

2007-03-01T23:59:59.000Z

444

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite  

E-Print Network [OSTI]

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite · C-C supplied in two forms · T300: C-C composite containing continuous PAN T300 fibers · SWB: Chopped Fiber Composite containing SWB fibers Crush strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine

Rollins, Andrew M.

445

Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

446

South Dakota Natural Gas Number of Gas and Gas Condensate Wells...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) South Dakota Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

447

Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

448

Montana Natural Gas Number of Gas and Gas Condensate Wells (Number...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) Montana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

449

Arizona Natural Gas Number of Gas and Gas Condensate Wells (Number...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Arizona Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

450

Texas Natural Gas Number of Gas and Gas Condensate Wells (Number...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Texas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

451

New York Natural Gas Number of Gas and Gas Condensate Wells ...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) New York Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

452

West Virginia Natural Gas Number of Gas and Gas Condensate Wells...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) West Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

453

North Dakota Natural Gas Number of Gas and Gas Condensate Wells...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) North Dakota Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

454

Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

455

U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

456

Utah Natural Gas Number of Gas and Gas Condensate Wells (Number...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas and Gas Condensate Wells (Number of Elements) Utah Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

457

Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

458

Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

459

Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

460

Kansas Natural Gas Number of Gas and Gas Condensate Wells (Number...  

U.S. Energy Information Administration (EIA) Indexed Site

Gas and Gas Condensate Wells (Number of Elements) Kansas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number...  

Gasoline and Diesel Fuel Update (EIA)

Gas and Gas Condensate Wells (Number of Elements) Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

462

No more gas from Egypt? Modeling offshore discoveries and import uncertainty of natural gas in Israel  

Science Journals Connector (OSTI)

Abstract Israel depends on natural gas imports from Egypt for about 40% of its domestic needs, with the remaining met from domestic production. Gas supplies from Egypt have been erratic since their initiation: disruptions have increased after the 2011 revolution in Egypt and have been further ignited by public discontent. Despite these developments, Israeli policy makers have viewed the Egyptian gas deal as a positive factor in preserving peace with Egypt and have had no better alternatives than relying upon it. This has changed, however, after recent discoveries of three major offshore fields that are expected to satisfy domestic demand for an indefinite period and to provide gas for exports. We use an extended global CGE modeling framework that incorporates multiple households and factor ownership to investigate the effects of reduced gas imports from Egypt and the evolvement of domestic gas production as an alternative. In case of reduced gas imports from Egypt, the Israeli economy would slightly retract mainly due to lower production in energy intensive sectors. Poor households would be the most negatively affected, due to the strongest relative decline in income and the strongest increase of their consumer price index. In the case of increasing domestic gas production, Israeli GDP and domestic absorption would rise by about 0.2% and 0.4%, respectively. Poor households would be more positively affected than rich ones due to their composition of factor income and their higher expenditure shares for energy intensive commodities.

Khalid Siddig; Harald Grethe

2014-01-01T23:59:59.000Z

463

Gas mixing system for imaging of nanomaterials under dynamic environments by environmental transmission electron microscopy  

SciTech Connect (OSTI)

A gas mixing manifold system that is capable of delivering a stable pressure stream of a desired composition of gases into an environmental transmission electron microscope has been developed. The system is designed to provide a stable imaging environment upon changes of either the composition of the gas mixture or upon switching from one gas to another. The design of the system is described and the response of the pressure inside the microscope, the sample temperature, and sample drift in response to flow and composition changes of the system are reported.

Akatay, M. Cem [School of Materials Engineering and Birck Nanotechnology Center, Purdue University, West Lafayette, Indiana 47907 (United States)] [School of Materials Engineering and Birck Nanotechnology Center, Purdue University, West Lafayette, Indiana 47907 (United States); Zvinevich, Yury; Ribeiro, Fabio H., E-mail: fabio@purdue.edu, E-mail: estach@bnl.gov [Forney Hall of Chemical Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); Baumann, Philipp [Computer Sciences, University of Applied Sciences of Northeastern Switzerland, 4132 Muttenz, Switzerland and Department of Physics, Yeshiva University, New York, New York 10016 (United States)] [Computer Sciences, University of Applied Sciences of Northeastern Switzerland, 4132 Muttenz, Switzerland and Department of Physics, Yeshiva University, New York, New York 10016 (United States); Stach, Eric A., E-mail: fabio@purdue.edu, E-mail: estach@bnl.gov [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973 (United States)

2014-03-15T23:59:59.000Z

464

Problems: Gas Laws & Solubility 1. You accept a position in a laboratory that is located on ground level on the planet Mars.  

E-Print Network [OSTI]

Problems: Gas Laws & Solubility 1. You accept a position. Gas % Composition Partial Pressure Oxygen 70 CO2 3 Nitrogen Argon 2. Calculate how much humidifier holds the water vapor tension within the chamber at 10 mm Hg

Prestwich, Ken

465

Chapter Nine - Gas Sweetening  

Science Journals Connector (OSTI)

Abstract This chapter begins by reviewing the processing of natural gas to meet gas sales contract specifications. It then describes acid gas limitations for pipelines and gas plants, before detailing the most common acid gas removal processes, such as solid-bed, chemical solvent processes, physical solvent processes, direct conversion processes, distillation process, and gas permeation processes. The chapter discusses the selection of the appropriate removal process for a given situation, and it provides a detailed design procedure for a solid-bed and chemical solvent process. The chapter ends by supplying a sample design for a solid-bed and chemical solvent process.

Maurice I. Stewart Jr.

2014-01-01T23:59:59.000Z

466

Measuring depth profiles of residual stress with Raman spectroscopy  

SciTech Connect (OSTI)

Knowledge of the variation of residual stress is a very important factor in understanding the properties of machined surfaces. The nature of the residual stress can determine a part`s susceptibility to wear deformation, and cracking. Raman spectroscopy is known to be a very useful technique for measuring residual stress in many materials. These measurements are routinely made with a lateral resolution of 1{mu}m and an accuracy of 0.1 kbar. The variation of stress with depth; however, has not received much attention in the past. A novel technique has been developed that allows quantitative measurement of the variation of the residual stress with depth with an accuracy of 10nm in the z direction. Qualitative techniques for determining whether the stress is varying with depth are presented. It is also demonstrated that when the stress is changing over the volume sampled, errors can be introduced if the variation of the stress with depth is ignored. Computer aided data analysis is used to determine the depth dependence of the residual stress.

Enloe, W.S.; Sparks, R.G.; Paesler, M.A.

1988-12-01T23:59:59.000Z

467

Doppler effects in resonant x-ray Raman scattering  

Science Journals Connector (OSTI)

Theory for Doppler effects in resonant x-ray Raman scattering (RXS) is presented. It is shown that the “electron” Doppler effect is important in nonradiative RXS for decay transitions between continuum nuclear states lying above the dissociation threshold, and that the averaging of the RXS cross section over molecular orientations can lead to strong non-Lorentzian broadenings of the atomiclike resonances. The Doppler effect is found to give a unique possibility to distinguish dissociating identical atoms, because different peaks correspond to atoms with opposite Doppler shifts. Spectral features of the atomiclike profile are predicted and analyzed. Strong oscillations of the RXS cross section will occur as a consequence of the interference of the Auger electrons. Due to the Doppler effect and the interference, the atomiclike profile can be associated with supernarrow spectral features, the width of which goes below the lifetime broadening and is practically independent of the spectral distribution of the incident radiation. As another consequence of the oscillations and strong anisotropy caused by the interference, we predict parity selection rules for Auger decay transitions in both bound and dissociative systems. The corresponding experiments can be realized by measurements of resonant Auger of surface adsorbed molecules and for molecules by the electron-ion coincidence technique.

Faris Gel’mukhanov; Hans Ågren; Pawe? Sa?ek

1998-04-01T23:59:59.000Z

468

Chuaria circularis from the early Mesoproterozoic Suket Shale, Vindhyan Supergroup, India: Insights from light and electron microscopy and pyrolysis-gas chromatography  

Science Journals Connector (OSTI)

Chuaria circularis (Walcott 1899) from the Suket Shale of the Vindhyan Supergroup (central India) ... composition using biostatistics, electron microscopy and pyrolysis-gas chromatography. Morpho...

Suryendu Dutta; Michael Steiner; Santanu Banerjee…

2006-02-01T23:59:59.000Z

469

EIA - Natural Gas Pipeline Network - Natural Gas Pipeline Compressor...  

Gasoline and Diesel Fuel Update (EIA)

Compressor Stations Illustration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates U.S. Natural Gas Pipeline...

470

Enhanced membrane gas separations  

SciTech Connect (OSTI)

An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

Prasad, R.

1993-07-13T23:59:59.000Z

471

Method for nonlinear optimization for gas tagging and other systems  

DOE Patents [OSTI]

A method and system are disclosed for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established. 6 figs.

Chen, T.; Gross, K.C.; Wegerich, S.

1998-01-06T23:59:59.000Z

472

Method for nonlinear optimization for gas tagging and other systems  

DOE Patents [OSTI]

A method and system for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established.

Chen, Ting (Chicago, IL); Gross, Kenny C. (Bolingbrook, IL); Wegerich, Stephan (Glendale Heights, IL)

1998-01-01T23:59:59.000Z

473

Characterization of Crude Oil Products Using Data Fusion of Process Raman, Infrared, and Nuclear Magnetic Resonance (NMR) Spectra  

Science Journals Connector (OSTI)

Process Raman, infrared (IR), and nuclear magnetic resonance (NMR) analyses are currently being performed in industrial settings for the monitoring of large scale reactions. These...

Dearing, Thomas I; Thompson, Wesley J; Rechsteiner, Carl E; Marquardt, Brian J

2011-01-01T23:59:59.000Z

474

Micro-Raman spectroscopic study of nanolaminated Ti{sub 5}Al{sub 2}C{sub 3}  

SciTech Connect (OSTI)

Micro-Raman spectroscopic study and lattice dynamics calculations were conducted to study a recently identified layered ternary carbide, Ti{sub 5}Al{sub 2}C{sub 3}. The experimental Raman shifts were remarkably consistent with the calculated values. Polarized Raman spectrum was collected in the polycrystalline sample, which confirmed the theoretical symmetry assignment of the Raman modes. In addition, the atomic vibrations of the peaks at 192?cm{sup ?1}, 311?cm{sup ?1}, and 660?cm{sup ?1} were identified to be the combination of the counterparts in Ti{sub 2}AlC and Ti{sub 3}AlC{sub 2}.

Zhang, H.; Li, Z. J. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Wang, X. H. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016 (China); Xiang, H. M.; Zhou, Y. C, E-mail: yczhou714@gmail.com [Science and Technology of Advanced Functional Composite Laboratory, ARIMPT, No.1 South Dahongmen Road, Beijing 100076 (China)

2014-03-31T23:59:59.000Z

475

Ozone Measurements at Geesthacht (53.4° N, 10.4° E) with an Advanced Raman Lidar  

Science Journals Connector (OSTI)

An advanced Raman lidar, which measures ozone, water vapor, aerosol backscatter, and extinction profiles simoultaneously and independently, has been in routine operation at Geesthacht since February 1995. Results...

Marcus Seiwazi; Jens Reichardt…

1997-01-01T23:59:59.000Z

476

Mixed Semiconductor Nanocrystal Compositions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixed Semiconductor Nanocrystal Compositions Mixed Semiconductor Nanocrystal Compositions Mixed Semiconductor Nanocrystal Compositions Composition comprising one or more energy donors and one or more energy acceptors. Available for thumbnail of Feynman Center (505) 665-9090 Email Mixed Semiconductor Nanocrystal Compositions Composition comprising one or more energy donors and one or more energy acceptors, wherein energy is transferred from the energy donor to the energy acceptor and wherein: the energy acceptor is a colloidal nanocrystal having a lower band gap energy than the energy donor; the energy donor and the energy acceptor are separated by a distance of 40 nm or less; wherein the average peak absorption energy of the acceptor is at least 20 meV greater than the average peak emission energy of the energy donor; and

477

Raman spectroscopic and mass spectrometric investigations of the hydrogen isotopes and isotopically labelled methane  

SciTech Connect (OSTI)

Suitable analytical methods must be tested and developed for monitoring the individual process steps within the fuel cycle of a fusion reactor and for tritium accountability. The utility of laser-Raman spectroscopy accompanied by mass spectrometry with an Omegatron was investigated using the analysis of all hydrogen isotopes and isotopically labeled methanes as an example. The Omegatron is useful for analyzing all hydrogen isotopes mixed with the stable helium isotopes. The application of this mass spectrometer were demonstrated by analyzing mixtures of deuterated methanes. In addition, it was employed to study the radiochemical Witzbach exchange reaction between tritium and methanes. A laser-Raman spectrometer was designed for analysis of tritium-containing gases and was built from individual components. A tritium-compatible, metal-sealed Raman cuvette having windows with good optical properties and additional means for measuring the stray light was first used successfully in this work. The Raman spectra of the hydrogen isotopes were acquired in the pure rotation mode and in the rotation-vibration mode and were used for on. The deuterated methanes were measured by Raman spectroscopy, the wavenumbers determined were assigned to the corresponding vibrations, and the wavenumbers for the rotational fine-structure were summarized in tables. The fundamental Vibrations of the deuterated methanes produced Witzbach reactions were detected and assigned. The fundamental vibrations of the molecules were obtained with Raman spectroscopy for the first time in this work. The @-Raman spectrometer assembled is well suited for the analysis of tritium- containing gases and is practical in combination with mass spectrometry using an Omegatron, for studying gases used in fusion.

Jewett, J.R., Fluor Daniel Hanford

1997-02-24T23:59:59.000Z

478

Nanocomposite thin films for optical gas sensing  

SciTech Connect (OSTI)

The disclosure relates to a plasmon resonance-based method for gas sensing in a gas stream utilizing a gas sensing material. In an embodiment the gas stream has a temperature greater than about 500.degree. C. The gas sensing material is comprised of gold nanoparticles having an average nanoparticle diameter of less than about 100 nanometers dispersed in an inert matrix having a bandgap greater than or equal to 5 eV, and an oxygen ion conductivity less than approximately 10.sup.-7 S/cm at a temperature of 700.degree. C. Exemplary inert matrix materials include SiO.sub.2, Al.sub.2O.sub.3, and Si.sub.3N.sub.4 as well as modifications to modify the effective refractive indices through combinations and/or doping of such materials. Changes in the chemical composition of the gas stream are detected by changes in the plasmon resonance peak. The method disclosed offers significant advantage over active and reducible matrix materials typically utilized, such as yttria-stabilized zirconia (YSZ) or TiO.sub.2.

Ohodnicki, Paul R; Brown, Thomas D

2014-06-03T23:59:59.000Z

479

Natural Gas Annual, 2001  

Gasoline and Diesel Fuel Update (EIA)

1 1 EIA Home > Natural Gas > Natural Gas Data Publications Natural Gas Annual, 2001 The Natural Gas Annual, 2001 provides information on the supply and disposition of natural gas in the United States. Production, transmission, storage, deliveries, and price data are published by State for 2001. Summary data are presented for each State for 1997 to 2001. The data that appear in the tables of the Natural Gas Annual, 2001 are available as self-extracting executable files in ASCII TXT or CSV file format. This volume emphasizes information for 2001, although some tables show a five-year history. Please read the file entitled README.V1 for a description and documentation of information included in this file. Also available are files containing the following data: Summary Statistics - Natural Gas in the United States, 1997-2001 (Table 1) ASCII TXT, and Natural Gas Supply and Disposition by State, 2001 (Table 2) ASCII TXT.

480

Oil and Gas Exploration  

E-Print Network [OSTI]

Metals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada, oil and gas, and geothermal activities and accomplishments in Nevada: production statistics, exploration and development including drilling for petroleum and geothermal resources, discoveries of ore

Tingley, Joseph V.

Note: This page contains sample records for the topic "raman gas composition" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

,"Mississippi Natural Gas Summary"  

U.S. Energy Information Administration (EIA) Indexed Site

"N3050MS3","N3010MS3","N3020MS3","N3035MS3","NA1570SMS3","N3045MS3" "Date","Mississippi Natural Gas Wellhead Price (Dollars per Thousand Cubic Feet)","Mississippi Natural Gas...

482

Natural Gas Monthly  

Reports and Publications (EIA)

Highlights activities, events, and analyses associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer related activities and underground storage data are also reported.

2014-01-01T23:59:59.000Z

483

Microminiature gas chromatograph  

DOE Patents [OSTI]

A microminiature gas chromatograph (.mu.GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode.

Yu, Conrad M. (Antioch, CA)

1996-01-01T23:59:59.000Z

484

Natural gas annual 1996  

SciTech Connect (OSTI)

This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

NONE

1997-09-01T23:59:59.000Z

485

Gas Turbine Plants  

Science Journals Connector (OSTI)

In a cycle process of a gas turbine, the compressor load, as well as ... from the expansion of the hot pressurized flue gas. Either turbine, compressor and driven assembly are joined by ... shaft is thus divided,...

1992-01-01T23:59:59.000Z

486

Gas-Turbine Cycles  

Science Journals Connector (OSTI)

This book focuses on the design of regenerators for high-performance regenerative gas turbines. The ways in which gas-turbine regenerators can be designed for high system performance can be understood by studying...

Douglas Stephen Beck; David Gordon Wilson

1996-01-01T23:59:59.000Z

487

Natural Gas Weekly Update  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

of 1 Tcf from the 1994 estimate of 51 Tcf. Ultimate potential for natural gas is a science-based estimate of the total amount of conventional gas in the province and is an...

488

,"Connecticut Natural Gas Summary"  

U.S. Energy Information Administration (EIA) Indexed Site

3","N3010CT3","N3020CT3","N3035CT3","N3045CT3" "Date","Natural Gas Citygate Price in Connecticut (Dollars per Thousand Cubic Feet)","Connecticut Price of Natural Gas Delivered to...

489

Natural Gas in Britain  

Science Journals Connector (OSTI)

... AT a recent meeting of the Institution of Gas Engineers, Sir Harold Smith, chairman ofthe ... Engineers, Sir Harold Smith, chairman ofthe Gas Council, stated that an intensive, large-scale search for ...

1953-06-13T23:59:59.000Z

490

Natural Gas Weekly Update  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Gas Rotary Rig Count Rises to Highest Level since February 2009. The natural gas rotary rig count was 992 as of Friday, August 13, according to data released by Baker...

491

Recirculating rotary gas compressor  

DOE Patents [OSTI]

A positive displacement, recirculating Roots-type rotary gas compressor is described which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits which return compressed discharge gas to the compressor housing, where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor. 12 figs.

Weinbrecht, J.F.

1992-02-25T23:59:59.000Z

492

Recirculating rotary gas compressor  

DOE Patents [OSTI]

A positive displacement, recirculating Roots-type rotary gas compressor which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits (24 and 26) which return compressed discharge gas to the compressor housing (14), where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers (10 and 12) and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor.

Weinbrecht, John F. (601 Oakwood Loop, NE., Albuquerque, NM 87123)

1992-01-01T23:59:59.000Z

493

Continuous Fiber Ceramic Composites  

SciTech Connect (OSTI)

Fiber-reinforced ceramic composites demonstrate the high-temperature stability of ceramics--with an increased fracture toughness resulting from the fiber reinforcement of the composite. The material optimization performed under the continuous fiber ceramic composites (CFCC) included a series of systematic optimizations. The overall goals were to define the processing window, to increase the robustinous of the process, to increase process yield while reducing costs, and to define the complexity of parts that could be fabricated.

None

2002-09-01T23:59:59.000Z

494

Compressed Gas Cylinder Policy  

E-Print Network [OSTI]

storage rack, a wall mounted cylinder rack, anchored to a fixed bench top, vented gas cabinet, or other

495

Natural Gas Weekly Update  

Gasoline and Diesel Fuel Update (EIA)

. Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels | Prices | States | International | Country Analysis...

496

Natural gas annual 1994  

SciTech Connect (OSTI)

The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1994 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1990 to 1994 for each Census Division and each State. Annual historical data are shown at the national level.

NONE

1995-11-17T23:59:59.000Z

497

Natural gas annual 1995  

SciTech Connect (OSTI)

The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

NONE

1996-11-01T23:59:59.000Z

498

Residual gas analysis device  

DOE Patents [OSTI]

A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

Thornberg, Steven M. (Peralta, NM)

2012-07-31T23:59:59.000Z

499

Composite Thermoelectric Devices  

Broader source: Energy.gov [DOE]

Composite thermoelectric devices incorporating common conductors laminated between P- and N-type thermoelectric plates demonstrate internal ohmic loss reduction and enhanced performance

500

Composites of Carbon Nanotubes.  

E-Print Network [OSTI]

??The purpose of this research was to study various methods of incorporation of single-walled carbon nanotubes (SWNT) with polymers for producing electrically conductive polystyrene composites.… (more)

Tchoul, Maxim N.

2008-01-01T23:59:59.000Z